FA-2633_29602_CA_MRP_20231012

East Coast Environmental, P.A.
3815 Junction Boulevard Raleigh, NC 27603
[phone]
Eastcoastenv.com

October 12, 2023

Mr. Ken Currie
NC-DEQ UST Section
Fayetteville Regional Office
Systel Building Suite 714
225 Green Street
Fayetteville, NC 28301

Re: Groundwater Monitoring Report prepared for
The Grocery Bag
Highway 42 Clayton, North Carolina (Site)
Incident # 29602

Dear Mr. Currie,

This correspondence is to present to you one copy of the attached Groundwater Monitoring Report for
your review.

Should you have any questions, comments, or require additional information, please feel free to contact
me at your earliest opportunity.

Cordially,
East Coast Environmental, P.A.
Tom Will
Project Manager

attachment

East Coast Environmental, P.A.
3815 Junction Boulevard Raleigh, NC 27603
[phone]
Eastcoastenv.com

REPORT FOR GROUNDWATER MONITORING
GROCERY BAG
4879-A HIGHWAY 42 EAST
CLAYTON, JOHNSTON COUNTY, NORTH CAROLINA
FACILITY I.D. 0-032284
GROUNDWATER INCIDENT NUMBER: 29602

October 12, 2023

Responsible Party:
Grocery Bag CITGO
c/o Donna Fitzgerald
4879-A Highway 42 East
Clayton, North Carolina 27520
[phone]

Current Property Owner:
Percy Flowers Store, LLC
4880 NC 42 East
Clayton, NC 27520
[phone]

Consultant:
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone]

Release Discovery Date: September 2009
Cause of Release: Leaking flex pipe connector in 12,000 UST sump
UST Sizes and Contents: (2) 8,000-Gallon Gasoline USTs,
(1) 12,000-Gallon Gasoline UST
Latitude: 35o 39.247’, Longitude: 78o 20.674’
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
2
Groundwater Monitoring Report
A Title Page
A.1 Site Identification
Date of Report: October 12, 2023
Facility I.D.: 0-032284 UST Incident Number: 29602
Site Name: The Grocery Bag
Site Address: 4879-A Highway 42 East
Nearest City/Town: Clayton County: Johnston
Location Method: Topographic Maps/GPS
Latitude: 35 39.247’ Longitude: 78 20.674’

A.2 Contact Information
UST Owner: The Grocery Bag CITGO c/o Donna Fitzgerald
Address: 4879-A Highway 42 East, Clayton, NC 27520 Phone: [phone]

UST Operator: The Grocery Bag CITGO c/o Donna Fitzgerald
Address: 4879-A Highway 42 East, Clayton, NC 27520 Phone: [phone]

Property Owner: Percy Flowers Store, LLC
Address: 4880 NC 42 East, Clayton, NC 27520 Phone: [phone]

Property Occupants: The Grocery Bag CITGO c/o Tommy Fitzgerald
Address: 4879-A Highway 42 East, Clayton, NC 27520 Phone: [phone]

Consultant/Contractor: East Coast Environmental, P.A.
Address: 3815 Junction Blvd., Raleigh, NC 27603 Phone: [phone] ______

Analytical Laboratory: Environmental Conservation Laboratories
Address: 102-A Woodwinds Industrial Court, Cary, NC 27511 Phone: [phone] ______

A.3 Release Information
Date Discovered: September 2009
Estimated Quantity of Release: unknown
Cause of Release: Leaking flex pipe connector in 12,000 UST sump
Source of Release (e.g., Piping/UST): Piping
Sizes and contents of UST system(s) from which the release occurred): (1) 12,000-gallon gasoline

I, Thomas R. Will a Licensed Geologist for East Coast Environmental, P.A. do certify that the information
contained in this report is correct and accurate to the best of my knowledge.
East Coast Environmental, P.A. is licensed to practice geology in North Carolina. The certification number for East Coast Environmental,
P.A. is C-136

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
3

Table of Contents
A TITLE PAGE ..............................................................................................................2
A.1 SITE IDENTIFICATION ..................................................................................................2
A.2 CONTACT INFORMATION .............................................................................................2
A.3 RELEASE INFORMATION ..............................................................................................2
1.0 INTRODUCTION....................................................................................................5
1.1 PREVIOUS GROUNDWATER SAMPLING EVENTS ..........................................................6
1.1.1 Comprehensive Site Assessment ..........................................................................6
JUNE 2016 GROUNDWATER MONITORING EVENT .................................................................8
MARCH 2022 GROUNDWATER MONITORING EVENT .............................................................9
JUNE 2023 GROUNDWATER MONITORING EVENT ...............................................................10
1.2.1 Groundwater Sampling Event – September 18, 2023 .......................................10
1.2.2 Well Gauging ....................................................................................................10
1.2.3.2 Well Purging ..................................................................................................10
1.2.3.3 Groundwater Sample Collection ....................................................................11
1.2.3.4 Sample Storage and Transport .......................................................................11
1.2.3.6 Analytical Methodology ................................................................................11
1.2.2 Analytical Results – Groundwater Samples (September 18, 2023) ..................12
1.2.2.1 SM6200B ......................................................................................................12
1.2.2.2 Surface Water Sampling Results ..................................................................13
1.3 CURRENT PLUME INFORMATION ...............................................................................13
1.4 PROPOSED REMEDIAL ACTIONS ................................................................................13
1.5 GROUNDWATER CONDITIONS ...................................................................................14
1.5.1 Proximity to Potential Receptors ......................................................................14
1.5.2 Groundwater Flow ............................................................................................14
2.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................15

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
4

APPENDICES
Section A Figures
Section B Tables and Charts
Section C Analytical Data- September 2023 groundwater sampling event

LIST OF FIGURES

Figure 1 Topographic Site Location Map
Figure 2 Benzene Isoconcentration Map (µg/L) – September 2023
Figure 3 Naphthalene Isoconcentration Map (µg/L) – September 2023
Figure 4 Groundwater Hydraulic Gradient Map (ft.) – September 2023

LIST OF TABLES

Table 1 Analytical Data-Groundwater (µg/l) – September 2023
Table 2 Historical Analytical Data for Groundwater Samples
Table 3 Groundwater Level Measurements (ft) – September 2023
Time vs. Contamination Charts (MW-1, MW-2, MW-5)

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
5
1.0 INTRODUCTION

At the request of Donna Fitzgerald of the Grocery Bag, and in accordance with the provisions of North
Carolina Administrative Code, Title 15A, Subchapter 2L, Section .0110 (Monitoring), East Coast
Environmental, P.A. (ECE), of Raleigh, North Carolina, has prepared this “Report for Groundwater
Monitoring” for petroleum contaminated groundwater on and adjacent to the Grocery Bag (Facility ID #
0-032284); hereinafter, referred to as the Site, located at 4879-A Highway 42 East, Clayton, Wake
County, North Carolina (Section A, Figure 1). A Site map (Section A, Figure 2) shows the location of
the Site & the locations of all monitoring wells associated with the Site, as well as the UST locations.

The Site contains three petroleum Underground Storage Tank (UST) systems that were installed for the
retail sale of gasoline. The Site’s UST systems were installed during 1993 and included two 8,000-
gallon gasoline tanks and one 12,000-gallon gasoline tank that are currently registered as being owned
by the Grocery Bag. See Section A, Figure 2 for the Site map indicating UST system locations.

ECE mobilized to the Site on September 3, 2009 for the purpose of performing a Site check. The
suspected release was located on top of the 12,000-gallon tank and therefore it was determined that
groundwater samples should be collected in areas as close to the tank as possible in lieu of the collection
of samples adjacent to the product lines and dispensers.

Analytical results for the groundwater samples submitted by ECE for laboratory analysis by EPA
method 6200B detected targeted volatile organic compounds at concentrations more than their
maximum allowable levels in groundwater as set forth in 15A NCAC 2L .0202. The presence of
petroleum related contaminants at elevated levels indicated that a petroleum release had occurred.
However, the source of the petroleum release (leaking flex connector in 12,000-gallon UST sump) was
identified and repaired.

After the Site Check, the Grocery Bag contracted ECE to complete a Phase I Limited Site Assessment
(Phase II LSA) Report (dated December 18, 2009). The North Carolina Department of Environment
and Natural Resources-Fayetteville Regional Office (NCDENR-FaRO) issued a September 29, 2014
Notice of Regulatory Requirements (NORR) letter to Mr. Tommy Fitzgerald of the Grocery Bag to
comply with the requirements of 15A NCAC 2N .0706, 15A NCAC 2L .0106(c) and 2L .0106(g).

Mr. Fitzgerald responded by directing ECE to complete a Comprehensive Site Assessment (CSA) report
(dated December 14, 2015) that was subsequently reviewed and approved by the NC-DEQ-FaRO. After
review, the NC-DEQ-FaRO requested that Mr. Fitzgerald perform a Report for Groundwater Monitoring
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
6
that was completed during 2016. This most recent 2023 groundwater monitoring event was requested
by Mr. Ken Curry of the NC-DEQ Fayetteville Regional Office in a Notice of Regulatory Requirement
letter issued to Donna Fitzgerald on August 23, 2023.

Currently the Site is classified as “intermediate risk” due to the presence of surface water bodies located
within 500-feet of the Site in two directions.

1.1 Previous Groundwater Sampling Events

1.1.1 Comprehensive Site Assessment

Historical groundwater sampling events occurred between March and October 2015 after the NC-DENR
instructed Mr. Fitzgerald to complete a CSA. ECE mobilized to the Site on March 12-13, 2015 to install
four additional permanent monitoring wells designated as MW-2, MW-3, MW-4, and MW-5 all of
which were located on-Site. A summary of the well construction details is included in Section B Table
3. ECE returned to the Site on March 18, 2015 to sample the five monitoring wells installed to date for
inclusion in this CSA. The groundwater samples collected from the monitoring wells were submitted
for analysis by EPA Methods 6200B (volatile organic compounds), 504.1 (EDB), 3030c (total lead) and
the MADEP-VPH methods.

Data for the groundwater samples revealed the presence of targeted compounds in the samples collected
from all five groundwater monitoring wells. Samples collected from these wells were also found to
contain one or more targeted contaminants at levels above their maximum allowable concentrations in
groundwater as defined by 15A NCAC 2L .0202.

May 17, 2015 Groundwater Monitoring Event

The next phase of groundwater sampling was conducted during May 2015 for completion of the CSA
and included the installation of additional monitoring wells MW-6 and MW-7 at on-Site locations. A
summary of the well construction details is included in Section B Table 3. These wells were required
after reviewing the results for the March 2015 monitoring event which revealed that the groundwater
contaminant plume may have migrated offsite and under NC 42 to the south. Therefore, to complete
the CSA groundwater samples were subsequently collected from monitoring wells MW-6 and MW-7
after their installation. The groundwater samples collected from the monitoring wells were submitted
for analysis by EPA Methods 6200B (volatile organic compounds), 504.1 (EDB), 3030c (total lead) and
the MADEP-VPH method. Analytical results for the samples collected from MW-6 showed no
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
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contaminants targeted by any of these test methods while the samples collected from MW-7 showed
numerous targeted contaminants at levels above their maximum allowable concentrations in
groundwater as defined by 15A NCAC 2L .0202. The analytical results for this sampling event confirm
that the groundwater contaminant plume has migrated offsite and under NC 42 to the south and defined
its extent to the east.

In summary, as of May 2015 data for the groundwater samples obtained from wells MW-1, MW-3,
MW-4, MW-5, and MW-7 showed the presence of targeted volatile organic compounds in these samples
at levels above their maximum allowable concentrations in groundwater as defined by 15A NCAC 2L
.0202. Analytical results for the samples collected from MW-2 and MW-6 were all below their
maximum allowable concentrations in groundwater as defined by 15A NCAC 2L .0202.

September/October 2015 Groundwater Monitoring Event

Th next phase of groundwater sampling was conducted during September and October 2015 for
completion of the CSA and included the installation of shallow wells MW-8, MW-9 and MW-10 and
deep profile well DW-1. MW-8 was installed on-Site to define the western extent of groundwater
contamination while MW-9 and MW-10 were installed off-Site and south of NC 42 to define the
downgradient extent of groundwater contamination. Finally, DW-1 was installed on-Site and adjacent
to MW-7 at the location indicated in Figure 2 to define the horizontal and vertical extent of groundwater
contamination. Therefore, to complete the CSA groundwater samples were subsequently collected from
monitoring wells MW-8, MW-9, MW-10, and DW-1. The groundwater samples collected from these
monitoring wells were submitted for analysis by EPA Methods 6200B (volatile organic compounds),
504.1 (EDB), 3030c (total lead) and the MADEP-VPH method. Analytical results for the groundwater
samples obtained from wells MW-8 and MW-9 showed the presence of targeted volatile organic
compounds in these samples at levels above their maximum allowable concentrations in groundwater as
defined by 15A NCAC 2L .0202.

In summary, data for the groundwater samples obtained from wells MW-1, MW-3, MW-4, MW-5, MW-
7, MW-8, and MW-9 showed the presence of volatile organic compounds in these samples at levels
above their maximum allowable concentrations in groundwater as defined by 15A NCAC 2L .0202 and
10 times the 15A NCAC 2B Standards.

Section B, Table 2 is a summary of the combined groundwater analytical results for all historical
sampling events.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
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Upon review of the data obtained by the CSA activities described above, it was evident that the
horizontal and vertical extent of the groundwater contaminant plume was adequately defined to the 15A
NCAC 2L standards for groundwater and 10 times the surface water standards wet forth at 15A NCAC
2B. The NC-DEQ followed up with a request to complete a monitoring event which included all the
wells installed to date be performed during June 2016.

June 2016 Groundwater Monitoring Event

Groundwater samples were collected from monitoring wells MW-1, 3, 4, 5, 6, 7, 8, 9, 10, and DW-1 on
June 13, 2016. All samples were collected using disposable PE bailers after the monitoring wells were
purged of either a minimum of three volumes of water calculated to be standing in the wells or purged to
dryness (whichever occurred first). Samples collected from all wells were submitted for chemical
analysis by SM6200B.

Results of chemical testing by SM6200B for groundwater samples collected from the monitoring wells
located on and around the Site showed the presence of targeted compounds in samples retained from
monitoring wells MW-1, MW-3, MW-4, MW-5, MW-7, MW-8, MW-9, and DW-1.

Numerous compounds were detected at levels more than their respective Maximum Allowable
Concentrations:

• Benzene was present in samples from wells MW-1, MW-3, MW-4, MW-5, MW-7, MW-8, MW-
9 and DW-1 at concentrations of 62, 83, 11, 520, 1,500, 3,600, 35 and 1.8 µg/L respectively,
• Ethylbenzene was found in samples from well MW-7 (1,500 µg/L),
• Isopropyl benzene was shown in well MW-7 at a level of 86 µg/L,
• MTBE was indicated in samples from MW-1 and MW-7 at concentrations of 30 and 120 µg/L,
• n-Propyl benzene was shown in wells MW-7 and MW-8 (360 and 140 ug/L),
• Naphthalene was found in samples from wells MW-1, MW-3, MW-5, MW-7, MW-8 and MW-9
at levels of 99, 16, 150, 660, 380 and 57 µg/L, respectively,
• Toluene was detected in MW-7 at a level of 1,000 ug/l,
• 1,3,5-Trimethylbenzene was shown present in well MW-7 (800 ug/l),
• 1,2,4-Trimethylbenzene was indicated in wells MW-7 and MW-8 (3,100 and 410 ug/l),
• Total Xylenes were detected in the sample from MW-7 at a level of 9,200 µg/l.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
9
March 2022 Groundwater Monitoring Event

The March 2022 groundwater monitoring event was requested by Mr. Ken Curry of the NC-DEQ
Fayetteville Regional Office in a Notice of Regulatory Requirement letter issued to Donna Fitzgerald on
February 25, 2022. In response, groundwater samples were collected from monitoring wells MW-1, 2, 3,
4, 5, 7, 9 and 10 on March 14, 2022. Monitoring wells MW-6, MW-8 and DW-1 were not included
because these wells had been destroyed as the result of recent road widening activities in front of the
store building. The remaining wells that could be included in the sampling event were sampled using
disposable PE bailers after the monitoring wells were purged of either a minimum of three volumes of
water calculated to be standing in the wells or purged to dryness (whichever occurred first). Samples
collected from all wells were submitted for chemical analysis by SM6200B.

Results of chemical testing by SM6200B for groundwater samples collected from the monitoring wells
located on and around the Site showed the presence of targeted compounds in samples retained from
monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-7, MW-8, and MW-9.

Numerous compounds were detected at levels more than their respective Maximum Allowable
Concentrations:

• Benzene was present in samples from wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-7, and
MW-9 at concentrations of 890, 45, 11, 1.8, 200, and 360 µg/L respectively;
• Ethylbenzene was found in the sample from well MW-7 (1,300 µg/L);
• Isopropyl-benzene was shown in well MW-7 at a level of 87 µg/L;
• MTBE was indicated in the sample from MW-7 at a concentration of 22 µg/L;
• n-Propylbenzene was shown in well MW-7 (260 ug/L);
• Naphthalene was found in samples from wells MW-1, MW-3, MW-4, MW-5, MW-7, and MW-9
at levels of 170, 20, 11, 150, 780 and 60 µg/L, respectively;
• 1,2,4-Trimethylbenzene was indicated in well MW-7 at 1,600 ug/l;
• Total Xylenes were detected in the sample from MW-7 at a level of 4,200 µg/L;
• Tert-amyl Alcohol was found in samples from wells MW-1, MW-3, MW-4, MW-5, and MW-9
at levels of 1,000, 390, 820, 760, and 94 µg/L, respectively.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
10
June 2023 Groundwater Monitoring Event

1.2.1 Groundwater Sampling Event – September 18, 2023

As discussed previously this most recent September 2023 groundwater monitoring event was requested
by Mr. Ken Curry of the NC-DEQ Fayetteville Regional Office in a Notice of Regulatory Requirement
letter issued to Donna Fitzgerald on August 23, 2023. In response, groundwater samples were collected
from monitoring wells MW-1, 2, 5, 9 and 10 on September 18, 2023. Monitoring wells MW-3, MW-4,
MW-6, MW-7, MW-8, and DW-1 were not included because these wells had been destroyed as the
result of recent road widening activities in front of the store building. The remaining wells that could be
included in the sampling event were sampled using disposable PE bailers after the monitoring wells
were purged of either a minimum of three volumes of water calculated to be standing in the wells or
purged to dryness (whichever occurred first). Samples collected from all wells were submitted for
chemical analysis by SM6200B.

1.2.2 Well Gauging

Well gauging was performed to determine the groundwater elevation within each well, and for the
calculation of appropriate purge volume(s) for each well prior to sampling. After decontamination
utilizing an Alconox® and deionized water solution, an electronic water level indicator was lowered into
each well to determine the depth to groundwater beneath the top of casing (TOC) of each well. Each
well associated with the Site was gauged on September 18, 2023. Depths to groundwater ranged from
2.05 feet (ft) in MW-1 to 3.08 ft in MW-5. Based on gauged of the wells, groundwater was determined
to flow from the north to the south through the Site, with a slight westerly component. Figure 4 depicts
the gradient based on the September 2023 gauging event. This flow direction is in general agreement
with the groundwater flow direction established during the 2015, 2016 and 2022 monitoring events

1.2.3.2 Well Purging

The groundwater within each well included in this sampling event was purged of a pre-determined
volume to allow for infiltration of representative groundwater, and thus collection of representative
groundwater samples. All wells were purged of a minimum of three well volumes prior to sampling,
unless the well was purged to a dry state prior to the removal of three volumes of water. After purging,
the groundwater level within each well was allowed to recharge to within 80% of the static level initially
observed before sampling of the well(s) was performed. Purging of each well was accomplished using
separate disposable polyethylene (PE) bailers.
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
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1.2.3.3 Groundwater Sample Collection

Representative groundwater samples were collected from each well targeted for sampling after proper
purging and recharge of the wells. The collection of groundwater samples was performed in accordance
with established EPA and North Carolina Division of Waste Management (NC-DWM) protocols for the
collection of groundwater samples. ECE modeled the sampling procedures after those set forth in the
“Underground Storage Tank Section Guidelines for Site Checks, Tank Closure, and Initial Response and
Abatement” prepared by the NC-DEQ-UST Section.

1.2.3.4 Sample Storage and Transport

All samples collected during this sampling event were properly contained in pre-washed, laboratory
grade sample containers. The sample containers utilized in this sampling event were provided by
Environmental Conservation Laboratories, Inc. (ENCO), a licensed analytical laboratory located in
Cary, NC (NC-DWQ certification# 591).

Samples collected for volatile organic analyses (SM6200B) were enclosed in 40-ml "VOAs", pre-
preserved with 1:1 hydrochloric acid (HCL). The headspace was removed from the samples prior to
capping.

After the collection of each sample, all containers were properly labeled with the sample designation,
sample date and time, and analysis requested. Information was recorded on a chain-of-custody form,
identifying each sample, and the analysis (or analyses) requested for the sample(s). The samples were
then placed in a cooler on ice pending delivery to the laboratory.

The samples collected on September 18, 2023 were relinquished to the lab courier on September 19,
2023 with all appropriate chain-of-custody documentation.

1.2.3.6 Analytical Methodology

Groundwater samples collected from the monitoring wells located on and adjacent to the Site were
analyzed for petroleum hydrocarbons and related petroleum additives. Samples collected from
monitoring wells sampled during the September 2023 sampling event were analyzed by SM6200B, a US
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
12
EPA approved method for testing of groundwater samples. SM6200B targets low-boiling-point volatile
petroleum hydrocarbons, such as those typical of gasoline and other light hydrocarbons. Samples
retained from the pond across NC Highway 42 were also analyzed by SM6200B. The pond sample
location is included in Figure 2.

1.2.2 Analytical Results – Groundwater Samples (September 18, 2023)

1.2.2.1 SM6200B

Results of chemical testing by SM6200B for groundwater samples collected from the monitoring wells
located on and around the Site showed the presence of targeted compounds in samples retained from
monitoring wells MW-1, MW-2, MW-5, and MW-9 (Table 1).

Numerous compounds were detected at levels more than their respective Maximum Allowable
Concentrations:

• Benzene was present in samples from wells MW-1, MW-2, and MW-5 at concentrations of
2,870, 927 and 113 µg/L respectively;
• Isopropyl-ether was shown in well MW-1 at a level of 98.7 µg/L;
• Naphthalene was found in samples from wells MW-1, MW-2, MW-5, and MW-9 at levels of
154, 13.5, 107 and 27.7 µg/L, respectively;
• Tert-amyl Alcohol was found in samples from wells MW-1 and MW-5 at levels of 809 and 236
µg/L, respectively.

Data for several samples also revealed the presence of targeted compounds at levels beneath their
respective Maximum Allowable Concentrations:

• Ethylbenzene - shown in MW-1, MW-2, and MW-5;
• Isopropyl-benzene - found MW-5;
• MTBE found in MW-5,
• Toluene – found in MW-2, MW-5, and MW-9;
• n-Propylbenzene - present in MW-1, MW-5, and MW-9;
• Xylenes - detected in MW-1, MW-2, MW-5, and MW-9;
• Tert-Butyl Alcohol shown in MW-5;

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
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Figures 2, and 3 show the estimated extents of benzene and naphthalene in groundwater based on the
September 2023 sampling event.

The laboratory analytical reports for this sampling event are presented as an attachment in Section C
while a summary of the laboratory results can be found in Section B, Table 1. Section B, Table 2
includes a summary of historical analytical results for all monitoring wells associated with the Site.

Three time vs. historical analytical data charts have been prepared for groundwater monitoring wells
MW-1, MW-2, and MW-5. Except for the chart for MW-5, the charts for MW-1 and MW-2 indicate
that overall contaminant concentrations for the September 2023 monitoring event have increased when
compared to historical groundwater monitoring events completed during 2015, 2016 and 2022. The data
charts are included in the back of Section B.

1.2.2.2 Surface Water Sampling Results

No sample was collected from the pond located across Highway 42 for this groundwater monitoring
event.

1.3 Current Plume Information

Based on analytical data for the September 2023 groundwater sampling event levels of one or more
compounds were present in samples collected from MW-1, MW-2, and MW-5 at levels more than their
Maximum Allowable Concentrations defined by the 2L Standards. The estimated area encompassed by
the extent of 2L Standard violations in the surficial aquifer based on the September 2023 groundwater
data measured as much as 56,600 square feet, or 1.3 acres. Figures 2 and 3 depict the approximate
lateral extent of 2L Standard violations on and in the vicinity of the Site based on the September 2023
sampling event. Contaminant concentrations detected in the wells related to the release at the site are
generally are lower than those from the 2015 and 2016 sampling events.

1.4 Proposed Remedial Actions

At this time there has been no Corrective Action Plan (CAP) prepared for remediation of soils and
groundwater at the Site.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
14
1.5 Groundwater Conditions

1.5.1 Proximity to Potential Receptors

There are no longer any water supply wells located within a 1,000-foot radius of the Site. However, the
Site is currently classified as “intermediate risk” due to the presence of surface water bodies located
within 500-feet of the Site in two directions. See Section A, Figure 1.

1.5.2 Groundwater Flow

Groundwater elevation data obtained during the September 2023 sampling event showed that
groundwater flows through and off the Site from north to south. This data also demonstrates that
groundwater flow is generally consistent with local topography and flowing towards the pond located
across NC 42 and to the southeast, south, and southwest. The gradient as modeled based on
groundwater elevation measurements obtained on September 18, 2023 is depicted on Figure 4.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
15

2.0 CONCLUSIONS AND RECOMMENDATIONS

The results of the analytical data for the September 2023 groundwater sampling event show the
continued presence of targeted compounds at levels exceeding their respective Maximum Allowable
Concentrations in select wells located on the Site. These compounds included:

• Benzene was present in samples from wells MW-1, MW-2, and MW-5 at concentrations of
2,870, 927 and 113 µg/L respectively;
• Isopropyl-ether was shown in well MW-1 at a level of 98.7 µg/L;
• Naphthalene was found in samples from wells MW-1, MW-2, MW-5, and MW-9 at levels of
154, 13.5, 107 and 27.7 µg/L, respectively;
• Tert-amyl Alcohol was found in samples from wells MW-1 and MW-5 at levels of 809 and 236
µg/L, respectively.

The estimated area encompassed by the extent of 2L Standard violations in the surficial aquifer based on
the September 2023 groundwater data measured as much as 56,600 square feet, or 1.3 acres. Figures 2
and 3 depict the approximate lateral extent of 2L Standard violations on and in the vicinity of the Site
based on the September 2023 sampling event. Contaminant concentrations detected in the wells related
to the release at the site are generally are lower than those from the 2015 and 2016 sampling events.

Three time vs. historical analytical data charts have been prepared for groundwater monitoring wells
MW-1, MW-2, and MW-5. Except for the chart for MW-5, the charts for MW-1 and MW-2 indicate
that overall contaminant concentrations for the September 2023 monitoring event have increased when
compared to historical groundwater monitoring events completed during 2015, 2016 and 2022. The data
charts are included in the back of Section B.

Groundwater elevation data obtained during the June 2016, March 2022 and September 2023 sampling
events show that groundwater flows through and off the Site from north to south, with a slight easterly
component. This data also demonstrates that groundwater flow is generally consistent with local
topography.

Recommendations

Based on the results of the September 2023 sampling event ECE recommends that monitoring continue
to take place on an annual basis. ECE also recommends replacing monitoring wells MW-4, MW-7 and
MW-8 if the NC-DEQ considers the incident to be high enough risk.

Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
16

The next groundwater sampling event should be scheduled for September 2024. ECE appreciates the
opportunity to be of assistance with this project. ECE recommends that a copy of this monitoring report
be submitted to the North Carolina Department of Environment and Natural Resources, Division of
Water Quality, Fayetteville Regional Office to the attention of Mr. Ken Currie.
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
17

Section A

Figures
East Coast
Environmental, P.A.
3815 Junction Boulevard
Raleigh, North Carolina 27603
[phone] Fax: [phone]
Figure 1
Site Location Map
Grocery Bag
4879-A Highway 42 East
Clayton, NC
Scale:Prep. By:Rev. By:Date:
NTS TRW TRW 3/31/2022
N
Product Dispenser
Grocery Bag

East CoastEnvironmental, P.A.3815 Junction BoulevardRaleigh, North Carolina 27603(919) 772-0268 Scale:Prep. By:Rev. By:Date:1”=40'TRWTRW10/12/2023Figure 2
N
0'
100'Figure 2Benzene Groundwater Contaminant MapGrocery Bag 4879-A NC 42 Clayton, North CarolinaProduct Dispenser Locations
Pond Sample
Location
MW-4
MW-1
1 ug/lMW-3
MW-2
MW-5
Buf
f
al
oe RoadUST Locations
MW-7
NT
NT
NT
113 ug/l
2,870 ug/l
MW-8
MW-9
N C 4 2
NT
NT
ND
927 ug/l
ND
MW-6
1 ug/l
MW-10
East CoastEnvironmental, P.A.3815 Junction BoulevardRaleigh, North Carolina 27603(919) 772-0268 Scale:Prep. By:Rev. By:Date:1”=40'TRWTRW10/13023Figure 3
N
0'
100'Figure 3Naphthalene Groundwater Contaminant MapGrocery Bag 4879-A NC 42 Clayton, North CarolinaProduct Dispenser Locations
MW-10
MW-4
MW-1
MW-6
MW-3
MW-2
MW-5
Buf
f
al
oe RoadUST Locations
MW-7
NT
6 ug/lNT
107 ug/l
154 ug/l
MW-8
MW-9
N C 4 2
NT
NT
27.7 ug/l
13.5
ND
NT6 ug/
l
East CoastEnvironmental, P.A.3815 Junction BoulevardRaleigh, North Carolina 27603(919) 772-0268 Scale:Prep. By:Rev. By:Date:1”=40'TRWTRW10/13/2023Figure 5
N
0'
100'Figure 4Groundwater Hydraulic Gradient Map9-18-2023Grocery Bag NC 42 Clayton, North CarolinaProduct Dispenser Locations
MW-10
MW-4
MW-1
MW-6
MW-3
MW-2
MW-5
Buf
f
al
oe RoadUST Locations
DW-1
NM
NM
NM
91.02
92.23
MW-8
MW-9
N C 4 2
NM
NM
90.02
90.06
MW-7
Grou
nd
w
ater Flo
w
92.95
93.00
91.00
93.00
92.00
90.00
90.00
NMGroundwater FlowGr
oundwa
t
er Fl
ow92.00
91.00
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
18

Section B

Tables and Charts
Table 1
Analytical Data for Groundwater Samples - 9/18/2023
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina

Well ID Sample
Date Sample ID
BenzeneIsopropyl EtherEthylbenzeneIsopropyl BenzeneMTBE4 isopropy toluenen-Propyl BenzeneNaphthaleneToluene1,2,4 Trimethylbenzene1,3,5 Trimethylbenzene Total XylenesSec Butyl BenzeneMW-1 9/18/2023 MW-1 2,870 98.7 165 39.8J ND ND 62.1 154 ND ND ND 383 ND
MW-2 9/18/2023 MW-2 927 24.9 61.6 ND ND ND ND 13.5J 305 ND ND 301 ND
MW-3 NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-4 NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-5 9/18/2023 MW-5 113 ND 24.5 22.1 5.2 ND 33.2 107 2.92J ND ND 9.42 2.62J
MW-6 NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-7 NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-8 NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-9 9/18/2023 MW-9 ND ND ND 5.59J ND ND 4.66J 27.7 0.94 ND ND 1.9 ND
MW-10 9/18/2023 MW-10 ND ND ND ND ND ND ND ND ND ND ND ND 1.6
DW-1 NT NT NT NT NT NT NT NT NT NT NT NT NT
Pond NT NT NT NT NT NT NT NT NT NT NT NT NT
1 70 600 70 20 25 70 6 600 400 400 500 70
5,000 70,000 84,500 25,000 20,000 11,700 30,000 6,000 260,000 28,500 24,100 85,500 8800
2L Standard (ug/l)
SM6200B
Compound NameAnalytical Method >
GCL (ug/l)
BOLD Values Exceed NC 2L Standard for Compound Shown
All data shown in µg/L
ND = Not Detected
J = Estimated Concentration
D = Sample Diluted for Analysis
Table 1
Analytical Data for Groundwater Samples - 9/18/2023
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina

Well ID Sample
Date Sample ID
Tert-Amyl Alcohol Tert Butyl Alcohol Tert Butyl Ethyl EtherTert Amyl Methyl EtherMW-1 9/18/2023 MW-1 809J ND ND ND
MW-2 9/18/2023 MW-2 ND ND ND ND
MW-3 NT NT NT NT
MW-4 NT NT ND ND
MW-5 9/18/2023 MW-5 236 328 ND ND
MW-6 NT NT NT NT
MW-7 NT NT NT NT
MW-8 NT NT NT NT
MW-9 9/18/2023 MW-9 ND ND ND ND
MW-10 9/18/2023 MW-10 ND ND ND ND
DW-1 NT NT NT NT
Pond 3/14/2022 Pond ND ND ND
40 NRS NRS
40,000 NRS NRS
Analytical Method >SM6200B
Compound Name
D = Sample Diluted for Analysis
BOLD Values Exceed NC 2L Standard for Compound Shown
2L Standard (ug/l)
GCL (ug/l)
All data shown in µg/L
ND = Not Detected
J = Estimated Concentration
Table 2
Historical Analytical Data for Groundwater Samples
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina
EPA 504.1 EPA-
3030C
Well ID Sample Date Sample ID
1,2-DibromoethaneBenzene1,2-DichloroethaneEthylbenzeneIsopropyl BenzeneMTBE4-isopropyltolueneN-Butylbenzenen-Propyl BenzeneNaphthaleneToluene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneTotal XylenesChloroformTotal LeadC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics3/18/2015 MW-1 ND 99 ND 84 16 46 ND ND 35 200 5.8 2.5 22 41 ND ND 270 1,260 ND
6/13/2016 NT 62 ND 47 7.5 30 ND ND ND 99 11 2.2 15 ND ND ND NT NT NT
3/14/2022 NT 890 ND 43 44 11 ND ND 64 170 15 16 1.8 31 ND NT NT NT NT
9/18/2023 NT 2870 ND 165 39.8J ND ND ND 62.1 154 ND ND ND 383 ND NT NT NT NT
3/18/2015 ND 0.83 ND 1.4 0.7 5 ND ND 0.65 6 0.56 1.8 10 12 ND ND 30.3 46.4 11
6/13/2016 NT ND ND ND ND 4.9 ND ND ND ND ND 0.56 2.6 ND ND ND NT NT NT
3/14/2022 ND 45 ND 16 1.3 1.5 ND ND 1.2 1.3 1.2 2.3 3.9 33 ND NT NT NT NT
9/18/2023 ND 927 ND 61.6 ND ND ND ND ND 13.5J 305 ND ND 301 ND NT NT NT NT
3/18/2015 ND 160 ND 51 4.3 18 ND ND 2.6 14 2.9 9.8 52 420 ND ND 359 751 56
6/13/2016 NT 83 ND 31 ND 14 ND ND 2.4 16 ND 4.8 19 70 ND ND NT NT NT
3/14/2022 NT 45 ND 3 0.68 7.8 ND ND ND 20 ND 0.62 1.9 3.2 ND NT NT NT NT
9/18/2023 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
3/18/2015 ND 17 ND ND ND 7.6 ND ND ND 2.6 ND 4.8 22 300 ND ND 340 470 30
6/13/2015 NT 11 ND 1.7 1.1 7.2 ND ND ND 5.8 0.65 ND ND 18 ND ND NT NT NT
3/14/2022 NT 1.8 ND ND 1.1 ND ND ND ND 11 ND ND ND 1.4 ND NT NT NT NT
9/18/2023 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
3/18/2015 ND 1,200 ND ND 130 43 ND ND 290 360 1,500 540 2,400 6,700 ND ND 5,400 19,400 3,600
6/13/2016 NT 520 ND 380 30 19 ND ND 75 150 49 72 320 410 ND ND NT NT NT
3/14/2022 NT 200 ND 68 42 7.7 2.5 ND 78 150 14 6 26 67 ND NT NT NT NT
9/18/2023 NT 113 ND 24.5 22.1 5.2 ND ND 33.2 107 2.92J ND ND 9.42 ND NT NT NT NT
MW-2 MW-2
MW-4
MW-5
MW-3MW-3
MW-4
MW-5
MADEP-VPH
Compound Name
Analytical Method >
MW-1
Table 2
Historical Analytical Data for Groundwater Samples
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina
Well ID Sample Date Sample ID
1,2-DibromoethaneBenzene1,2-DichloroethaneEthylbenzeneIsopropyl BenzeneMTBE4-isopropyltolueneN-Butylbenzenen-Propyl BenzeneNaphthaleneToluene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneTotal XylenesChloroformTotal LeadC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics5/17/2015 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
6/13/2016 NT ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT NT NT
3/14/2022 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
9/18/2023 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
5/17/2015 ND 680 ND 1,700 140 84 ND ND 440 830 1,400 1,300 4,500 12,000 ND ND 4,490 18,900 14,000
6/13/2016 NT 1,500 ND 1,500 86 120 ND ND 360 660 1,000 800 3,100 9,200 ND ND NT NT NT
3/14/2022 NT 360 ND 1,300 87 22 ND ND 260 780 350 380 1,600 4,200 ND NT NT NT NT
9/18/2023 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
9/9/2015 ND 3,200 ND 540 49 930 ND ND 110 450 59 130 480 620 ND ND 176 201 530
6/13/2016 NT 3,600 ND 480 38 ND ND ND 140 380 54 94 410 470 ND ND NT NT NT
3/14/2022 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
9/18/2023 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
9/9/2015 ND 8.5 ND 2 20 16 ND ND 33 120 2.7 3.6 ND 16 ND ND 6,040 2,070 2,200
6/13/2016 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT
3/14/2022 NT ND ND 0.73 8.2 4.3 ND ND 10 60 0.94 ND ND 1.9 ND NT NT NT NT
9/18/2023 NT ND ND ND 5.59J ND ND ND 4.66J 27.7 ND ND ND ND ND NT NT NT NT
9/9/2015 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.6
6/13/2016 NT ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT NT NT
3/14/2022 NT ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT NT NT NT
9/18/2023 NT ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT NT NT NT
10/29/2015 ND ND ND ND ND ND ND ND ND ND ND ND 0.43 ND ND ND ND ND ND
6/13/2016 ND 1.8 ND ND 0.49 0.59 ND ND ND 2.4 ND ND 1.1 0.47 ND ND NT NT NT
3/14/2022 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT
MW-10
MW-7
MW-9
MW-7
MW-6
MW-8
DW-1 DW-1
MW-9
MW-6
MW-8
MW-10
Table 2
Historical Analytical Data for Groundwater Samples
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina
Well ID Sample Date Sample ID
1,2-DibromoethaneBenzene1,2-DichloroethaneEthylbenzeneIsopropyl BenzeneMTBE4-isopropyltolueneN-Butylbenzenen-Propyl BenzeneNaphthaleneToluene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneTotal XylenesChloroformTotal LeadC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics10/29/2015 NT ND ND ND ND ND ND ND ND ND ND ND ND ND ND NT NT NT NT
6/13/2016 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
3/14/2022 NT ND ND ND ND ND ND ND ND ND ND ND ND ND 0.93 J NT NT NT NT
0.02 1 0.4 600 70 20 25 70 70 6 600 400 400 500 70 15 400 700 200
50 5,000 400 84,500 25,000 20,000 11,700 6,900 30,000 6,000 260,000 25,000 28,500 85,500 70000 15000 NRS NRS NRS
NRS Denotes "No Regulatory Standard Established
Shaded Values Exceed NCGross Contaminant Concentration for Compound Shown
D = Sample Diluted for Analysis
NT = Not Tested
J = Estimated Concentration
BOLD Values Exceed NC 2L Standard for Compound Shown
All data shown in µg/L
ND = Not Detected
2L Standard (ug/l)
Pond
GCL (ug/l)
Pond
Table 3
Groundwater Elevations - September 18, 2023
Grocery Bag
NC-DEQ Incident # 29602
4879-A Highway 42 East
Clayton, Johnston County, North Carolina
Well ID Date Installed Well Casing
Depth (ft)
Screened
Interval (ft)
Well Depth
(ft)
Top of Casing
Elevation(ft)Depth to Water (ft)Groundwater Elevation
(ft)
MW-1 11/2/2009 0-3 3 - 10 -10 94.28 2.05 92.23
MW-2 3/17/2015 0-5 5 - 15 -15 95.08 2.2 92.95
MW-3 3/17/2015 0-5 5 - 15 -15 92.68 92.68
MW-4 3/18/2015 0-5 5 - 15 -15 93.42 93.42
MW-5 3/18/2015 0-5 5 - 15 -15 94.82 3.8 91.02
MW-6 5/17/2015 0-5 5 - 15 -15 93.16 93.16
MW-7 5/17/2015 0-3 3 - 13 -13 94.48 94.48
MW-8 9/2/2015 0-5 5 - 15 -15 94.13 94.13
MW-9 9/2/2015 0-3 3 - 13 -13 92.8 2.78 90.02
MW-10 9/2/2015 0-3 3 - 13 -13 92.46 2.4 90.06
DW-1 10/22/2015 0-30 3 0- 40 -40 94.46 94.46
276
150
990
3,414
0
500
1,000
1,500
2,000
2,500
3,000
3,500
4,000
3/18/2015 6/13/2016 3/14/2022 9/18/2023Concentration (ug/l)Sample Date
Grocery Bag
Total BTEX + MTBE Concentrations MW-1
652
198
85
1594
0
200
400
600
800
1,000
1,200
1,400
1,600
1,800
3/18/2015 6/13/2016 3/14/2022 9/18/2023Concentration (ug/l)Sample Date
Grocery Bag
Total BTEX + MTBE Concentrations MW-2
10,543
1378
357 154
0
2,000
4,000
6,000
8,000
10,000
12,000
3/18/2015 6/13/2016 3/14/2022 9/18/2023Concentration (ug/l)Sample Date
Grocery Bag
Total BTEX + MTBE Concentrations MW-5
Report for Groundwater Monitoring
Grocery Bag Clayton, North Carolina
East Coast Environmental, P.A.
3815 Junction Blvd.
Raleigh, North Carolina 27603
[phone] Fax: [phone]
19

Section C

Analytical Data

September 2023
Groundwater Sampling Event

ANALYTICAL REPORT
PREPARED FOR
Attn: Tom Will
East Coast Environmental
3815 Junction Blvd
Raleigh, North Carolina 27603
Generated 10/6/2023 9:30:09 AM
JOB DESCRIPTION
Grocery Bag
JOB NUMBER
752-11689-1
See page two for job notes and contact information.
Cary NC 27511
102-A Woodwinds Industrial Court
Eurofins Raleigh
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Eurofins Raleigh
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
10/6/2023 9:30:09 AM
Authorized for release by
John Andros, Project Manager I
[e-mail]
[phone]
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Table of Contents
Client: East Coast Environmental
Project/Site: Grocery Bag
Laboratory Job ID: 752-11689-1
Page 3 of 31 Eurofins Raleigh10/6/2023
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31
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Definitions/Glossary
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Raleigh
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Case Narrative
Client: East Coast Environmental Job ID: 752-11689-1
Project/Site: Grocery Bag
Job ID: 752-11689-1
Laboratory: Eurofins Raleigh
Narrative
Job Narrative
752-11689-1
Receipt
The samples were received on 9/19/2023 1:20 PM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 1.8°C
GC/MS VOA
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Eurofins RaleighPage 5 of 31 10/6/2023
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Detection Summary
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Client Sample ID: MW-1 Lab Sample ID: 752-11689-1
Isopropyl ether
RL
50.0 ug/L
MDL
10.5
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA5098.7 SM6200-B
Benzene 50.0 ug/L2.50 Total/NA502870SM6200-B
Ethylbenzene 50.0 ug/L5.00 Total/NA50165SM6200-B
m,p-Xylenes 100 ug/L9.00 Total/NA50300SM6200-B
o-Xylene 50.0 ug/L4.40 Total/NA5083.0 SM6200-B
N-Propylbenzene 50.0 ug/L3.65 Total/NA5062.1 SM6200-B
Isopropylbenzene 50.0 ug/L6.50 Total/NA5039.8 J SM6200-B
Xylenes, Total 50.0 ug/L11.0 Total/NA50383SM6200-B
Naphthalene 50.0 ug/L4.30 Total/NA50154SM6200-B
tert-Amyl alcohol 1000 ug/L125 Total/NA50809JSM6200-B
Client Sample ID: MW-2 Lab Sample ID: 752-11689-2
Isopropyl ether
RL
20.0 ug/L
MDL
4.20
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA2024.9 SM6200-B
Benzene 20.0 ug/L1.00 Total/NA20927SM6200-B
Toluene 20.0 ug/L1.06 Total/NA20305SM6200-B
Ethylbenzene 20.0 ug/L2.00 Total/NA2061.6 SM6200-B
m,p-Xylenes 40.0 ug/L3.60 Total/NA20181SM6200-B
o-Xylene 20.0 ug/L1.76 Total/NA20120SM6200-B
Xylenes, Total 20.0 ug/L4.40 Total/NA20301SM6200-B
Naphthalene 20.0 ug/L1.72 Total/NA2013.5 J SM6200-B
Client Sample ID: MW-5 Lab Sample ID: 752-11689-3
Methyl tert-butyl ether
RL
5.00 ug/L
MDL
0.600
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA55.20 SM6200-B
Benzene 5.00 ug/L0.250 Total/NA5113SM6200-B
Toluene 5.00 ug/L0.265 Total/NA52.92 J SM6200-B
Ethylbenzene 5.00 ug/L0.500 Total/NA524.5 SM6200-B
m,p-Xylenes 10.0 ug/L0.900 Total/NA59.42 J SM6200-B
N-Propylbenzene 5.00 ug/L0.365 Total/NA533.2 SM6200-B
sec-Butylbenzene 5.00 ug/L0.265 Total/NA52.62 J SM6200-B
Isopropylbenzene 5.00 ug/L0.650 Total/NA522.1 SM6200-B
Xylenes, Total 5.00 ug/L1.10 Total/NA59.42 SM6200-B
Naphthalene 5.00 ug/L0.430 Total/NA5107SM6200-B
tert-Amyl alcohol 100 ug/L12.5 Total/NA5236SM6200-B
tert-Butyl alcohol 100 ug/L17.0 Total/NA5328SM6200-B
Client Sample ID: MW-9 Lab Sample ID: 752-11689-4
N-Propylbenzene
RL
10.0 ug/L
MDL
0.730
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10J4.66 SM6200-B
Isopropylbenzene 10.0 ug/L1.30 Total/NA105.59 J SM6200-B
Naphthalene 10.0 ug/L0.860 Total/NA1027.7 SM6200-B
tert-Amyl alcohol 200 ug/L25.0 Total/NA1096.9 J SM6200-B
Client Sample ID: MW-10 Lab Sample ID: 752-11689-5
No Detections.
Eurofins Raleigh
This Detection Summary does not include radiochemical test results.
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-1Client Sample ID: MW-1
Matrix: WaterDate Collected: 09/18/23 15:00
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds
RL MDL
ND 50.0 4.55 ug/L 10/02/23 19:50 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Dichlorodifluoromethane
50.0 2.50 ug/L 10/02/23 19:50 50NDChloromethane
50.0 4.15 ug/L 10/02/23 19:50 50NDVinyl chloride
50.0 14.0 ug/L 10/02/23 19:50 50NDBromomethane
50.0 9.00 ug/L 10/02/23 19:50 50NDChloroethane
50.0 7.50 ug/L 10/02/23 19:50 50NDTrichlorofluoromethane
50.0 7.50 ug/L 10/02/23 19:50 50ND1,1-Dichloroethene
100 3.50 ug/L 10/02/23 19:50 50NDMethylene Chloride
50.0 6.00 ug/L 10/02/23 19:50 50NDMethyl tert-butyl ether
50.0 5.50 ug/L 10/02/23 19:50 50NDtrans-1,2-Dichloroethene
50.0 2.50 ug/L 10/02/23 19:50 50ND1,1-Dichloroethane
50.0 10.5 ug/L 10/02/23 19:50 5098.7Isopropyl ether
50.0 3.75 ug/L 10/02/23 19:50 50NDcis-1,2-Dichloroethene
50.0 6.00 ug/L 10/02/23 19:50 50ND2,2-Dichloropropane
50.0 5.50 ug/L 10/02/23 19:50 50NDBromochloromethane
50.0 4.15 ug/L 10/02/23 19:50 50NDChloroform
50.0 7.50 ug/L 10/02/23 19:50 50ND1,1,1-Trichloroethane
50.0 3.15 ug/L 10/02/23 19:50 50ND1,1-Dichloropropene
50.0 4.10 ug/L 10/02/23 19:50 50NDCarbon tetrachloride
50.0 4.10 ug/L 10/02/23 19:50 50ND1,2-Dichloroethane
50.0 2.50 ug/L 10/02/23 19:50 502870Benzene
50.0 6.50 ug/L 10/02/23 19:50 50NDTrichloroethene
50.0 4.90 ug/L 10/02/23 19:50 50ND1,2-Dichloropropane
50.0 6.50 ug/L 10/02/23 19:50 50NDDibromomethane
50.0 5.00 ug/L 10/02/23 19:50 50NDBromodichloromethane
50.0 3.65 ug/L 10/02/23 19:50 50NDcis-1,3-Dichloropropene
50.0 2.65 ug/L 10/02/23 19:50 50NDToluene
50.0 4.00 ug/L 10/02/23 19:50 50NDtrans-1,3-Dichloropropene
50.0 3.40 ug/L 10/02/23 19:50 50ND1,1,2-Trichloroethane
50.0 7.50 ug/L 10/02/23 19:50 50ND1,3-Dichloropropane
50.0 4.95 ug/L 10/02/23 19:50 50NDTetrachloroethene
50.0 3.35 ug/L 10/02/23 19:50 50NDDibromochloromethane
50.0 21.0 ug/L 10/02/23 19:50 50ND1,2-Dibromoethane
50.0 3.45 ug/L 10/02/23 19:50 50NDChlorobenzene
50.0 4.55 ug/L 10/02/23 19:50 50ND1,1,1,2-Tetrachloroethane
5000 1300 ug/L 10/02/23 19:50 50NDEthanol
50.0 5.00 ug/L 10/02/23 19:50 50165Ethylbenzene
50.0 17.5 ug/L 10/02/23 19:50 50NDFreon 113
100 9.00 ug/L 10/02/23 19:50 50300m,p-Xylenes
50.0 4.40 ug/L 10/02/23 19:50 5083.0o-Xylene
50.0 4.10 ug/L 10/02/23 19:50 50NDStyrene
50.0 10.0 ug/L 10/02/23 19:50 50NDBromoform
50.0 3.30 ug/L 10/02/23 19:50 50ND4-Isopropyltoluene
50.0 4.25 ug/L 10/02/23 19:50 50ND1,1,2,2-Tetrachloroethane
50.0 6.50 ug/L 10/02/23 19:50 50NDBromobenzene
50.0 7.50 ug/L 10/02/23 19:50 50ND1,2,3-Trichloropropane
50.0 3.65 ug/L 10/02/23 19:50 5062.1N-Propylbenzene
50.0 5.00 ug/L 10/02/23 19:50 50ND2-Chlorotoluene
50.0 5.00 ug/L 10/02/23 19:50 50ND1,3,5-Trimethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-1Client Sample ID: MW-1
Matrix: WaterDate Collected: 09/18/23 15:00
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
ND 50.0 5.00 ug/L 10/02/23 19:50 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
4-Chlorotoluene
50.0 4.70 ug/L 10/02/23 19:50 50NDtert-Butylbenzene
50.0 3.35 ug/L 10/02/23 19:50 50ND1,2,4-Trimethylbenzene
50.0 2.65 ug/L 10/02/23 19:50 50NDsec-Butylbenzene
50.0 4.60 ug/L 10/02/23 19:50 50ND1,3-Dichlorobenzene
50.0 6.50 ug/L 10/02/23 19:50 5039.8 JIsopropylbenzene
50.0 5.00 ug/L 10/02/23 19:50 50ND1,4-Dichlorobenzene
50.0 3.70 ug/L 10/02/23 19:50 50NDn-Butylbenzene
50.0 2.60 ug/L 10/02/23 19:50 50ND1,2-Dichlorobenzene
50.0 24.0 ug/L 10/02/23 19:50 50ND1,2-Dibromo-3-Chloropropane
50.0 4.85 ug/L 10/02/23 19:50 50ND1,2,4-Trichlorobenzene
50.0 7.50 ug/L 10/02/23 19:50 50NDHexachlorobutadiene
50.0 11.0 ug/L 10/02/23 19:50 50383Xylenes, Total
50.0 12.5 ug/L 10/02/23 19:50 50ND1,2,3-Trichlorobenzene
50.0 4.30 ug/L 10/02/23 19:50 50154Naphthalene
250 16.0 ug/L 10/02/23 19:50 50NDtert-Butyl Formate
50.0 18.5 ug/L 10/02/23 19:50 50NDTert-butyl ethyl ether
500 10.5 ug/L 10/02/23 19:50 50NDTert-amyl methyl ether
1000 125 ug/L 10/02/23 19:50 50809Jtert-Amyl alcohol
1000 170 ug/L 10/02/23 19:50 50NDtert-Butyl alcohol
Toluene-d8 (Surr)102 70-130 10/02/23 19:50 50
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)103 10/02/23 19:50 5070-130
Dibromofluoromethane (Surr)98 10/02/23 19:50 5070-130
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-2Client Sample ID: MW-2
Matrix: WaterDate Collected: 09/18/23 15:15
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds
RL MDL
ND 20.0 1.82 ug/L 10/02/23 20:20 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Dichlorodifluoromethane
20.0 1.00 ug/L 10/02/23 20:20 20NDChloromethane
20.0 1.66 ug/L 10/02/23 20:20 20NDVinyl chloride
20.0 5.60 ug/L 10/02/23 20:20 20NDBromomethane
20.0 3.60 ug/L 10/02/23 20:20 20NDChloroethane
20.0 3.00 ug/L 10/02/23 20:20 20NDTrichlorofluoromethane
20.0 3.00 ug/L 10/02/23 20:20 20ND1,1-Dichloroethene
40.0 1.40 ug/L 10/02/23 20:20 20NDMethylene Chloride
20.0 2.40 ug/L 10/02/23 20:20 20NDMethyl tert-butyl ether
20.0 2.20 ug/L 10/02/23 20:20 20NDtrans-1,2-Dichloroethene
20.0 1.00 ug/L 10/02/23 20:20 20ND1,1-Dichloroethane
20.0 4.20 ug/L 10/02/23 20:20 2024.9Isopropyl ether
20.0 1.50 ug/L 10/02/23 20:20 20NDcis-1,2-Dichloroethene
20.0 2.40 ug/L 10/02/23 20:20 20ND2,2-Dichloropropane
20.0 2.20 ug/L 10/02/23 20:20 20NDBromochloromethane
20.0 1.66 ug/L 10/02/23 20:20 20NDChloroform
20.0 3.00 ug/L 10/02/23 20:20 20ND1,1,1-Trichloroethane
20.0 1.26 ug/L 10/02/23 20:20 20ND1,1-Dichloropropene
20.0 1.64 ug/L 10/02/23 20:20 20NDCarbon tetrachloride
20.0 1.64 ug/L 10/02/23 20:20 20ND1,2-Dichloroethane
20.0 1.00 ug/L 10/02/23 20:20 20927Benzene
20.0 2.60 ug/L 10/02/23 20:20 20NDTrichloroethene
20.0 1.96 ug/L 10/02/23 20:20 20ND1,2-Dichloropropane
20.0 2.60 ug/L 10/02/23 20:20 20NDDibromomethane
20.0 2.00 ug/L 10/02/23 20:20 20NDBromodichloromethane
20.0 1.46 ug/L 10/02/23 20:20 20NDcis-1,3-Dichloropropene
20.0 1.06 ug/L 10/02/23 20:20 20305Toluene
20.0 1.60 ug/L 10/02/23 20:20 20NDtrans-1,3-Dichloropropene
20.0 1.36 ug/L 10/02/23 20:20 20ND1,1,2-Trichloroethane
20.0 3.00 ug/L 10/02/23 20:20 20ND1,3-Dichloropropane
20.0 1.98 ug/L 10/02/23 20:20 20NDTetrachloroethene
20.0 1.34 ug/L 10/02/23 20:20 20NDDibromochloromethane
20.0 8.40 ug/L 10/02/23 20:20 20ND1,2-Dibromoethane
20.0 1.38 ug/L 10/02/23 20:20 20NDChlorobenzene
20.0 1.82 ug/L 10/02/23 20:20 20ND1,1,1,2-Tetrachloroethane
2000 520 ug/L 10/02/23 20:20 20NDEthanol
20.0 2.00 ug/L 10/02/23 20:20 2061.6Ethylbenzene
20.0 7.00 ug/L 10/02/23 20:20 20NDFreon 113
40.0 3.60 ug/L 10/02/23 20:20 20181m,p-Xylenes
20.0 1.76 ug/L 10/02/23 20:20 20120o-Xylene
20.0 1.64 ug/L 10/02/23 20:20 20NDStyrene
20.0 4.00 ug/L 10/02/23 20:20 20NDBromoform
20.0 1.32 ug/L 10/02/23 20:20 20ND4-Isopropyltoluene
20.0 1.70 ug/L 10/02/23 20:20 20ND1,1,2,2-Tetrachloroethane
20.0 2.60 ug/L 10/02/23 20:20 20NDBromobenzene
20.0 3.00 ug/L 10/02/23 20:20 20ND1,2,3-Trichloropropane
20.0 1.46 ug/L 10/02/23 20:20 20NDN-Propylbenzene
20.0 2.00 ug/L 10/02/23 20:20 20ND2-Chlorotoluene
20.0 2.00 ug/L 10/02/23 20:20 20ND1,3,5-Trimethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-2Client Sample ID: MW-2
Matrix: WaterDate Collected: 09/18/23 15:15
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
ND 20.0 2.00 ug/L 10/02/23 20:20 20
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
4-Chlorotoluene
20.0 1.88 ug/L 10/02/23 20:20 20NDtert-Butylbenzene
20.0 1.34 ug/L 10/02/23 20:20 20ND1,2,4-Trimethylbenzene
20.0 1.06 ug/L 10/02/23 20:20 20NDsec-Butylbenzene
20.0 1.84 ug/L 10/02/23 20:20 20ND1,3-Dichlorobenzene
20.0 2.60 ug/L 10/02/23 20:20 20NDIsopropylbenzene
20.0 2.00 ug/L 10/02/23 20:20 20ND1,4-Dichlorobenzene
20.0 1.48 ug/L 10/02/23 20:20 20NDn-Butylbenzene
20.0 1.04 ug/L 10/02/23 20:20 20ND1,2-Dichlorobenzene
20.0 9.60 ug/L 10/02/23 20:20 20ND1,2-Dibromo-3-Chloropropane
20.0 1.94 ug/L 10/02/23 20:20 20ND1,2,4-Trichlorobenzene
20.0 3.00 ug/L 10/02/23 20:20 20NDHexachlorobutadiene
20.0 4.40 ug/L 10/02/23 20:20 20301Xylenes, Total
20.0 5.00 ug/L 10/02/23 20:20 20ND1,2,3-Trichlorobenzene
20.0 1.72 ug/L 10/02/23 20:20 2013.5 JNaphthalene
100 6.40 ug/L 10/02/23 20:20 20NDtert-Butyl Formate
20.0 7.40 ug/L 10/02/23 20:20 20NDTert-butyl ethyl ether
200 4.20 ug/L 10/02/23 20:20 20NDTert-amyl methyl ether
400 50.0 ug/L 10/02/23 20:20 20NDtert-Amyl alcohol
400 68.0 ug/L 10/02/23 20:20 20NDtert-Butyl alcohol
Toluene-d8 (Surr)96 70-130 10/02/23 20:20 20
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)104 10/02/23 20:20 2070-130
Dibromofluoromethane (Surr)99 10/02/23 20:20 2070-130
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-3Client Sample ID: MW-5
Matrix: WaterDate Collected: 09/18/23 15:30
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds
RL MDL
ND 5.00 0.455 ug/L 10/02/23 20:49 5
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Dichlorodifluoromethane
5.00 0.250 ug/L 10/02/23 20:49 5NDChloromethane
5.00 0.415 ug/L 10/02/23 20:49 5NDVinyl chloride
5.00 1.40 ug/L 10/02/23 20:49 5NDBromomethane
5.00 0.900 ug/L 10/02/23 20:49 5NDChloroethane
5.00 0.750 ug/L 10/02/23 20:49 5NDTrichlorofluoromethane
5.00 0.750 ug/L 10/02/23 20:49 5ND1,1-Dichloroethene
10.0 0.350 ug/L 10/02/23 20:49 5NDMethylene Chloride
5.00 0.600 ug/L 10/02/23 20:49 55.20Methyl tert-butyl ether
5.00 0.550 ug/L 10/02/23 20:49 5NDtrans-1,2-Dichloroethene
5.00 0.250 ug/L 10/02/23 20:49 5ND1,1-Dichloroethane
5.00 1.05 ug/L 10/02/23 20:49 5NDIsopropyl ether
5.00 0.375 ug/L 10/02/23 20:49 5NDcis-1,2-Dichloroethene
5.00 0.600 ug/L 10/02/23 20:49 5ND2,2-Dichloropropane
5.00 0.550 ug/L 10/02/23 20:49 5NDBromochloromethane
5.00 0.415 ug/L 10/02/23 20:49 5NDChloroform
5.00 0.750 ug/L 10/02/23 20:49 5ND1,1,1-Trichloroethane
5.00 0.315 ug/L 10/02/23 20:49 5ND1,1-Dichloropropene
5.00 0.410 ug/L 10/02/23 20:49 5NDCarbon tetrachloride
5.00 0.410 ug/L 10/02/23 20:49 5ND1,2-Dichloroethane
5.00 0.250 ug/L 10/02/23 20:49 5113Benzene
5.00 0.650 ug/L 10/02/23 20:49 5NDTrichloroethene
5.00 0.490 ug/L 10/02/23 20:49 5ND1,2-Dichloropropane
5.00 0.650 ug/L 10/02/23 20:49 5NDDibromomethane
5.00 0.500 ug/L 10/02/23 20:49 5NDBromodichloromethane
5.00 0.365 ug/L 10/02/23 20:49 5NDcis-1,3-Dichloropropene
5.00 0.265 ug/L 10/02/23 20:49 52.92 JToluene
5.00 0.400 ug/L 10/02/23 20:49 5NDtrans-1,3-Dichloropropene
5.00 0.340 ug/L 10/02/23 20:49 5ND1,1,2-Trichloroethane
5.00 0.750 ug/L 10/02/23 20:49 5ND1,3-Dichloropropane
5.00 0.495 ug/L 10/02/23 20:49 5NDTetrachloroethene
5.00 0.335 ug/L 10/02/23 20:49 5NDDibromochloromethane
5.00 2.10 ug/L 10/02/23 20:49 5ND1,2-Dibromoethane
5.00 0.345 ug/L 10/02/23 20:49 5NDChlorobenzene
5.00 0.455 ug/L 10/02/23 20:49 5ND1,1,1,2-Tetrachloroethane
500 130 ug/L 10/02/23 20:49 5NDEthanol
5.00 0.500 ug/L 10/02/23 20:49 524.5Ethylbenzene
5.00 1.75 ug/L 10/02/23 20:49 5NDFreon 113
10.0 0.900 ug/L 10/02/23 20:49 59.42 Jm,p-Xylenes
5.00 0.440 ug/L 10/02/23 20:49 5NDo-Xylene
5.00 0.410 ug/L 10/02/23 20:49 5NDStyrene
5.00 1.00 ug/L 10/02/23 20:49 5NDBromoform
5.00 0.330 ug/L 10/02/23 20:49 5ND4-Isopropyltoluene
5.00 0.425 ug/L 10/02/23 20:49 5ND1,1,2,2-Tetrachloroethane
5.00 0.650 ug/L 10/02/23 20:49 5NDBromobenzene
5.00 0.750 ug/L 10/02/23 20:49 5ND1,2,3-Trichloropropane
5.00 0.365 ug/L 10/02/23 20:49 533.2N-Propylbenzene
5.00 0.500 ug/L 10/02/23 20:49 5ND2-Chlorotoluene
5.00 0.500 ug/L 10/02/23 20:49 5ND1,3,5-Trimethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-3Client Sample ID: MW-5
Matrix: WaterDate Collected: 09/18/23 15:30
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
ND 5.00 0.500 ug/L 10/02/23 20:49 5
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
4-Chlorotoluene
5.00 0.470 ug/L 10/02/23 20:49 5NDtert-Butylbenzene
5.00 0.335 ug/L 10/02/23 20:49 5ND1,2,4-Trimethylbenzene
5.00 0.265 ug/L 10/02/23 20:49 52.62 Jsec-Butylbenzene
5.00 0.460 ug/L 10/02/23 20:49 5ND1,3-Dichlorobenzene
5.00 0.650 ug/L 10/02/23 20:49 522.1Isopropylbenzene
5.00 0.500 ug/L 10/02/23 20:49 5ND1,4-Dichlorobenzene
5.00 0.370 ug/L 10/02/23 20:49 5NDn-Butylbenzene
5.00 0.260 ug/L 10/02/23 20:49 5ND1,2-Dichlorobenzene
5.00 2.40 ug/L 10/02/23 20:49 5ND1,2-Dibromo-3-Chloropropane
5.00 0.485 ug/L 10/02/23 20:49 5ND1,2,4-Trichlorobenzene
5.00 0.750 ug/L 10/02/23 20:49 5NDHexachlorobutadiene
5.00 1.10 ug/L 10/02/23 20:49 59.42Xylenes, Total
5.00 1.25 ug/L 10/02/23 20:49 5ND1,2,3-Trichlorobenzene
5.00 0.430 ug/L 10/02/23 20:49 5107Naphthalene
25.0 1.60 ug/L 10/02/23 20:49 5NDtert-Butyl Formate
5.00 1.85 ug/L 10/02/23 20:49 5NDTert-butyl ethyl ether
50.0 1.05 ug/L 10/02/23 20:49 5NDTert-amyl methyl ether
100 12.5 ug/L 10/02/23 20:49 5236tert-Amyl alcohol
100 17.0 ug/L 10/02/23 20:49 5328tert-Butyl alcohol
Toluene-d8 (Surr)101 70-130 10/02/23 20:49 5
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)105 10/02/23 20:49 570-130
Dibromofluoromethane (Surr)101 10/02/23 20:49 570-130
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-4Client Sample ID: MW-9
Matrix: WaterDate Collected: 09/18/23 13:45
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds
RL MDL
ND 10.0 0.910 ug/L 10/02/23 21:19 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Dichlorodifluoromethane
10.0 0.500 ug/L 10/02/23 21:19 10NDChloromethane
10.0 0.830 ug/L 10/02/23 21:19 10NDVinyl chloride
10.0 2.80 ug/L 10/02/23 21:19 10NDBromomethane
10.0 1.80 ug/L 10/02/23 21:19 10NDChloroethane
10.0 1.50 ug/L 10/02/23 21:19 10NDTrichlorofluoromethane
10.0 1.50 ug/L 10/02/23 21:19 10ND1,1-Dichloroethene
20.0 0.700 ug/L 10/02/23 21:19 10NDMethylene Chloride
10.0 1.20 ug/L 10/02/23 21:19 10NDMethyl tert-butyl ether
10.0 1.10 ug/L 10/02/23 21:19 10NDtrans-1,2-Dichloroethene
10.0 0.500 ug/L 10/02/23 21:19 10ND1,1-Dichloroethane
10.0 2.10 ug/L 10/02/23 21:19 10NDIsopropyl ether
10.0 0.750 ug/L 10/02/23 21:19 10NDcis-1,2-Dichloroethene
10.0 1.20 ug/L 10/02/23 21:19 10ND2,2-Dichloropropane
10.0 1.10 ug/L 10/02/23 21:19 10NDBromochloromethane
10.0 0.830 ug/L 10/02/23 21:19 10NDChloroform
10.0 1.50 ug/L 10/02/23 21:19 10ND1,1,1-Trichloroethane
10.0 0.630 ug/L 10/02/23 21:19 10ND1,1-Dichloropropene
10.0 0.820 ug/L 10/02/23 21:19 10NDCarbon tetrachloride
10.0 0.820 ug/L 10/02/23 21:19 10ND1,2-Dichloroethane
10.0 0.500 ug/L 10/02/23 21:19 10NDBenzene
10.0 1.30 ug/L 10/02/23 21:19 10NDTrichloroethene
10.0 0.980 ug/L 10/02/23 21:19 10ND1,2-Dichloropropane
10.0 1.30 ug/L 10/02/23 21:19 10NDDibromomethane
10.0 1.00 ug/L 10/02/23 21:19 10NDBromodichloromethane
10.0 0.730 ug/L 10/02/23 21:19 10NDcis-1,3-Dichloropropene
10.0 0.530 ug/L 10/02/23 21:19 10NDToluene
10.0 0.800 ug/L 10/02/23 21:19 10NDtrans-1,3-Dichloropropene
10.0 0.680 ug/L 10/02/23 21:19 10ND1,1,2-Trichloroethane
10.0 1.50 ug/L 10/02/23 21:19 10ND1,3-Dichloropropane
10.0 0.990 ug/L 10/02/23 21:19 10NDTetrachloroethene
10.0 0.670 ug/L 10/02/23 21:19 10NDDibromochloromethane
10.0 4.20 ug/L 10/02/23 21:19 10ND1,2-Dibromoethane
10.0 0.690 ug/L 10/02/23 21:19 10NDChlorobenzene
10.0 0.910 ug/L 10/02/23 21:19 10ND1,1,1,2-Tetrachloroethane
1000 260 ug/L 10/02/23 21:19 10NDEthanol
10.0 1.00 ug/L 10/02/23 21:19 10NDEthylbenzene
10.0 3.50 ug/L 10/02/23 21:19 10NDFreon 113
20.0 1.80 ug/L 10/02/23 21:19 10NDm,p-Xylenes
10.0 0.880 ug/L 10/02/23 21:19 10NDo-Xylene
10.0 0.820 ug/L 10/02/23 21:19 10NDStyrene
10.0 2.00 ug/L 10/02/23 21:19 10NDBromoform
10.0 0.660 ug/L 10/02/23 21:19 10ND4-Isopropyltoluene
10.0 0.850 ug/L 10/02/23 21:19 10ND1,1,2,2-Tetrachloroethane
10.0 1.30 ug/L 10/02/23 21:19 10NDBromobenzene
10.0 1.50 ug/L 10/02/23 21:19 10ND1,2,3-Trichloropropane
10.0 0.730 ug/L 10/02/23 21:19 104.66 JN-Propylbenzene
10.0 1.00 ug/L 10/02/23 21:19 10ND2-Chlorotoluene
10.0 1.00 ug/L 10/02/23 21:19 10ND1,3,5-Trimethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-4Client Sample ID: MW-9
Matrix: WaterDate Collected: 09/18/23 13:45
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
ND 10.0 1.00 ug/L 10/02/23 21:19 10
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
4-Chlorotoluene
10.0 0.940 ug/L 10/02/23 21:19 10NDtert-Butylbenzene
10.0 0.670 ug/L 10/02/23 21:19 10ND1,2,4-Trimethylbenzene
10.0 0.530 ug/L 10/02/23 21:19 10NDsec-Butylbenzene
10.0 0.920 ug/L 10/02/23 21:19 10ND1,3-Dichlorobenzene
10.0 1.30 ug/L 10/02/23 21:19 105.59 JIsopropylbenzene
10.0 1.00 ug/L 10/02/23 21:19 10ND1,4-Dichlorobenzene
10.0 0.740 ug/L 10/02/23 21:19 10NDn-Butylbenzene
10.0 0.520 ug/L 10/02/23 21:19 10ND1,2-Dichlorobenzene
10.0 4.80 ug/L 10/02/23 21:19 10ND1,2-Dibromo-3-Chloropropane
10.0 0.970 ug/L 10/02/23 21:19 10ND1,2,4-Trichlorobenzene
10.0 1.50 ug/L 10/02/23 21:19 10NDHexachlorobutadiene
10.0 2.20 ug/L 10/02/23 21:19 10NDXylenes, Total
10.0 2.50 ug/L 10/02/23 21:19 10ND1,2,3-Trichlorobenzene
10.0 0.860 ug/L 10/02/23 21:19 1027.7Naphthalene
50.0 3.20 ug/L 10/02/23 21:19 10NDtert-Butyl Formate
10.0 3.70 ug/L 10/02/23 21:19 10NDTert-butyl ethyl ether
100 2.10 ug/L 10/02/23 21:19 10NDTert-amyl methyl ether
200 25.0 ug/L 10/02/23 21:19 1096.9 Jtert-Amyl alcohol
200 34.0 ug/L 10/02/23 21:19 10NDtert-Butyl alcohol
Toluene-d8 (Surr)94 70-130 10/02/23 21:19 10
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)104 10/02/23 21:19 1070-130
Dibromofluoromethane (Surr)106 10/02/23 21:19 1070-130
Eurofins Raleigh
Page 14 of 31 10/6/2023
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-5Client Sample ID: MW-10
Matrix: WaterDate Collected: 09/18/23 14:00
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds
RL MDL
ND 1.00 0.0910 ug/L 10/02/23 19:21 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Dichlorodifluoromethane
1.00 0.0500 ug/L 10/02/23 19:21 1NDChloromethane
1.00 0.0830 ug/L 10/02/23 19:21 1NDVinyl chloride
1.00 0.280 ug/L 10/02/23 19:21 1NDBromomethane
1.00 0.180 ug/L 10/02/23 19:21 1NDChloroethane
1.00 0.150 ug/L 10/02/23 19:21 1NDTrichlorofluoromethane
1.00 0.150 ug/L 10/02/23 19:21 1ND1,1-Dichloroethene
2.00 0.0700 ug/L 10/02/23 19:21 1NDMethylene Chloride
1.00 0.120 ug/L 10/02/23 19:21 1NDMethyl tert-butyl ether
1.00 0.110 ug/L 10/02/23 19:21 1NDtrans-1,2-Dichloroethene
1.00 0.0500 ug/L 10/02/23 19:21 1ND1,1-Dichloroethane
1.00 0.210 ug/L 10/02/23 19:21 1NDIsopropyl ether
1.00 0.0750 ug/L 10/02/23 19:21 1NDcis-1,2-Dichloroethene
1.00 0.120 ug/L 10/02/23 19:21 1ND2,2-Dichloropropane
1.00 0.110 ug/L 10/02/23 19:21 1NDBromochloromethane
1.00 0.0830 ug/L 10/02/23 19:21 1NDChloroform
1.00 0.150 ug/L 10/02/23 19:21 1ND1,1,1-Trichloroethane
1.00 0.0630 ug/L 10/02/23 19:21 1ND1,1-Dichloropropene
1.00 0.0820 ug/L 10/02/23 19:21 1NDCarbon tetrachloride
1.00 0.0820 ug/L 10/02/23 19:21 1ND1,2-Dichloroethane
1.00 0.0500 ug/L 10/02/23 19:21 1NDBenzene
1.00 0.130 ug/L 10/02/23 19:21 1NDTrichloroethene
1.00 0.0980 ug/L 10/02/23 19:21 1ND1,2-Dichloropropane
1.00 0.130 ug/L 10/02/23 19:21 1NDDibromomethane
1.00 0.100 ug/L 10/02/23 19:21 1NDBromodichloromethane
1.00 0.0730 ug/L 10/02/23 19:21 1NDcis-1,3-Dichloropropene
1.00 0.0530 ug/L 10/02/23 19:21 1NDToluene
1.00 0.0800 ug/L 10/02/23 19:21 1NDtrans-1,3-Dichloropropene
1.00 0.0680 ug/L 10/02/23 19:21 1ND1,1,2-Trichloroethane
1.00 0.150 ug/L 10/02/23 19:21 1ND1,3-Dichloropropane
1.00 0.0990 ug/L 10/02/23 19:21 1NDTetrachloroethene
1.00 0.0670 ug/L 10/02/23 19:21 1NDDibromochloromethane
1.00 0.420 ug/L 10/02/23 19:21 1ND1,2-Dibromoethane
1.00 0.0690 ug/L 10/02/23 19:21 1NDChlorobenzene
1.00 0.0910 ug/L 10/02/23 19:21 1ND1,1,1,2-Tetrachloroethane
100 26.0 ug/L 10/02/23 19:21 1NDEthanol
1.00 0.100 ug/L 10/02/23 19:21 1NDEthylbenzene
1.00 0.350 ug/L 10/02/23 19:21 1NDFreon 113
2.00 0.180 ug/L 10/02/23 19:21 1NDm,p-Xylenes
1.00 0.0880 ug/L 10/02/23 19:21 1NDo-Xylene
1.00 0.0820 ug/L 10/02/23 19:21 1NDStyrene
1.00 0.200 ug/L 10/02/23 19:21 1NDBromoform
1.00 0.0660 ug/L 10/02/23 19:21 1ND4-Isopropyltoluene
1.00 0.0850 ug/L 10/02/23 19:21 1ND1,1,2,2-Tetrachloroethane
1.00 0.130 ug/L 10/02/23 19:21 1NDBromobenzene
1.00 0.150 ug/L 10/02/23 19:21 1ND1,2,3-Trichloropropane
1.00 0.0730 ug/L 10/02/23 19:21 1NDN-Propylbenzene
1.00 0.100 ug/L 10/02/23 19:21 1ND2-Chlorotoluene
1.00 0.100 ug/L 10/02/23 19:21 1ND1,3,5-Trimethylbenzene
Eurofins Raleigh
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Client Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Lab Sample ID: 752-11689-5Client Sample ID: MW-10
Matrix: WaterDate Collected: 09/18/23 14:00
Date Received: 09/19/23 13:20
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
ND 1.00 0.100 ug/L 10/02/23 19:21 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
4-Chlorotoluene
1.00 0.0940 ug/L 10/02/23 19:21 1NDtert-Butylbenzene
1.00 0.0670 ug/L 10/02/23 19:21 1ND1,2,4-Trimethylbenzene
1.00 0.0530 ug/L 10/02/23 19:21 1NDsec-Butylbenzene
1.00 0.0920 ug/L 10/02/23 19:21 1ND1,3-Dichlorobenzene
1.00 0.130 ug/L 10/02/23 19:21 1NDIsopropylbenzene
1.00 0.100 ug/L 10/02/23 19:21 1ND1,4-Dichlorobenzene
1.00 0.0740 ug/L 10/02/23 19:21 1NDn-Butylbenzene
1.00 0.0520 ug/L 10/02/23 19:21 1ND1,2-Dichlorobenzene
1.00 0.480 ug/L 10/02/23 19:21 1ND1,2-Dibromo-3-Chloropropane
1.00 0.0970 ug/L 10/02/23 19:21 1ND1,2,4-Trichlorobenzene
1.00 0.150 ug/L 10/02/23 19:21 1NDHexachlorobutadiene
1.00 0.220 ug/L 10/02/23 19:21 1NDXylenes, Total
1.00 0.250 ug/L 10/02/23 19:21 1ND1,2,3-Trichlorobenzene
1.00 0.0860 ug/L 10/02/23 19:21 1NDNaphthalene
5.00 0.320 ug/L 10/02/23 19:21 1NDtert-Butyl Formate
1.00 0.370 ug/L 10/02/23 19:21 1NDTert-butyl ethyl ether
10.0 0.210 ug/L 10/02/23 19:21 1NDTert-amyl methyl ether
20.0 2.50 ug/L 10/02/23 19:21 1NDtert-Amyl alcohol
20.0 3.40 ug/L 10/02/23 19:21 1NDtert-Butyl alcohol
Toluene-d8 (Surr)98 70-130 10/02/23 19:21 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)104 10/02/23 19:21 170-130
Dibromofluoromethane (Surr)102 10/02/23 19:21 170-130
Eurofins Raleigh
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Surrogate Summary
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130)(70-130)(70-130)
TOL BFB DBFM
102 103 98752-11689-1
Percent Surrogate Recovery (Acceptance Limits)
MW-1
96 104 99752-11689-2 MW-2
101 105 101752-11689-3 MW-5
94 104 106752-11689-4 MW-9
98 104 102752-11689-5 MW-10
98 101 109LCS 752-4657/6 Lab Control Sample
95 101 99LCS 752-4657/8 Lab Control Sample
96 102 99LCSD 752-4657/7 Lab Control Sample Dup
100 99 103MB 752-4657/10 Method Blank
98 102 103MRL 752-4657/17 Lab Control Sample
98 106 105MRL 752-4657/5 Lab Control Sample
Surrogate Legend
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
DBFM = Dibromofluoromethane (Surr)
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 752-4657/10
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
RL MDL
Dichlorodifluoromethane ND 1.00 0.0910 ug/L 10/02/23 18:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.05001.00 ug/L 10/02/23 18:51 1Chloromethane
ND 0.08301.00 ug/L 10/02/23 18:51 1Vinyl chloride
ND 0.2801.00 ug/L 10/02/23 18:51 1Bromomethane
ND 0.1801.00 ug/L 10/02/23 18:51 1Chloroethane
ND 0.1501.00 ug/L 10/02/23 18:51 1Trichlorofluoromethane
ND 0.1501.00 ug/L 10/02/23 18:51 11,1-Dichloroethene
0.1148 J 0.07002.00 ug/L 10/02/23 18:51 1Methylene Chloride
ND 0.1201.00 ug/L 10/02/23 18:51 1Methyl tert-butyl ether
ND 0.1101.00 ug/L 10/02/23 18:51 1trans-1,2-Dichloroethene
ND 0.05001.00 ug/L 10/02/23 18:51 11,1-Dichloroethane
ND 0.2101.00 ug/L 10/02/23 18:51 1Isopropyl ether
ND 0.07501.00 ug/L 10/02/23 18:51 1cis-1,2-Dichloroethene
ND 0.1201.00 ug/L 10/02/23 18:51 12,2-Dichloropropane
ND 0.1101.00 ug/L 10/02/23 18:51 1Bromochloromethane
ND 0.08301.00 ug/L 10/02/23 18:51 1Chloroform
ND 0.1501.00 ug/L 10/02/23 18:51 11,1,1-Trichloroethane
ND 0.06301.00 ug/L 10/02/23 18:51 11,1-Dichloropropene
ND 0.08201.00 ug/L 10/02/23 18:51 1Carbon tetrachloride
ND 0.08201.00 ug/L 10/02/23 18:51 11,2-Dichloroethane
ND 0.05001.00 ug/L 10/02/23 18:51 1Benzene
ND 0.1301.00 ug/L 10/02/23 18:51 1Trichloroethene
ND 0.09801.00 ug/L 10/02/23 18:51 11,2-Dichloropropane
ND 0.1301.00 ug/L 10/02/23 18:51 1Dibromomethane
ND 0.1001.00 ug/L 10/02/23 18:51 1Bromodichloromethane
ND 0.07301.00 ug/L 10/02/23 18:51 1cis-1,3-Dichloropropene
ND 0.05301.00 ug/L 10/02/23 18:51 1Toluene
ND 0.08001.00 ug/L 10/02/23 18:51 1trans-1,3-Dichloropropene
ND 0.06801.00 ug/L 10/02/23 18:51 11,1,2-Trichloroethane
ND 0.1501.00 ug/L 10/02/23 18:51 11,3-Dichloropropane
ND 0.09901.00 ug/L 10/02/23 18:51 1Tetrachloroethene
ND 0.06701.00 ug/L 10/02/23 18:51 1Dibromochloromethane
ND 0.4201.00 ug/L 10/02/23 18:51 11,2-Dibromoethane
ND 0.06901.00 ug/L 10/02/23 18:51 1Chlorobenzene
ND 0.09101.00 ug/L 10/02/23 18:51 11,1,1,2-Tetrachloroethane
ND 26.0100 ug/L 10/02/23 18:51 1Ethanol
ND 0.1001.00 ug/L 10/02/23 18:51 1Ethylbenzene
ND 0.3501.00 ug/L 10/02/23 18:51 1Freon 113
ND 0.1802.00 ug/L 10/02/23 18:51 1m,p-Xylenes
ND 0.08801.00 ug/L 10/02/23 18:51 1o-Xylene
ND 0.08201.00 ug/L 10/02/23 18:51 1Styrene
ND 0.2001.00 ug/L 10/02/23 18:51 1Bromoform
ND 0.06601.00 ug/L 10/02/23 18:51 14-Isopropyltoluene
ND 0.08501.00 ug/L 10/02/23 18:51 11,1,2,2-Tetrachloroethane
ND 0.1301.00 ug/L 10/02/23 18:51 1Bromobenzene
ND 0.1501.00 ug/L 10/02/23 18:51 11,2,3-Trichloropropane
ND 0.07301.00 ug/L 10/02/23 18:51 1N-Propylbenzene
ND 0.1001.00 ug/L 10/02/23 18:51 12-Chlorotoluene
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 752-4657/10
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
RL MDL
1,3,5-Trimethylbenzene ND 1.00 0.100 ug/L 10/02/23 18:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.1001.00 ug/L 10/02/23 18:51 14-Chlorotoluene
ND 0.09401.00 ug/L 10/02/23 18:51 1tert-Butylbenzene
ND 0.06701.00 ug/L 10/02/23 18:51 11,2,4-Trimethylbenzene
ND 0.05301.00 ug/L 10/02/23 18:51 1sec-Butylbenzene
ND 0.09201.00 ug/L 10/02/23 18:51 11,3-Dichlorobenzene
ND 0.1301.00 ug/L 10/02/23 18:51 1Isopropylbenzene
ND 0.1001.00 ug/L 10/02/23 18:51 11,4-Dichlorobenzene
ND 0.07401.00 ug/L 10/02/23 18:51 1n-Butylbenzene
ND 0.05201.00 ug/L 10/02/23 18:51 11,2-Dichlorobenzene
ND 0.4801.00 ug/L 10/02/23 18:51 11,2-Dibromo-3-Chloropropane
ND 0.09701.00 ug/L 10/02/23 18:51 11,2,4-Trichlorobenzene
ND 0.1501.00 ug/L 10/02/23 18:51 1Hexachlorobutadiene
ND 0.2201.00 ug/L 10/02/23 18:51 1Xylenes, Total
ND 0.2501.00 ug/L 10/02/23 18:51 11,2,3-Trichlorobenzene
ND 0.08601.00 ug/L 10/02/23 18:51 1Naphthalene
ND 0.3205.00 ug/L 10/02/23 18:51 1tert-Butyl Formate
ND 0.3701.00 ug/L 10/02/23 18:51 1Tert-butyl ethyl ether
ND 0.21010.0 ug/L 10/02/23 18:51 1Tert-amyl methyl ether
ND 2.5020.0 ug/L 10/02/23 18:51 1tert-Amyl alcohol
ND 3.4020.0 ug/L 10/02/23 18:51 1tert-Butyl alcohol
Toluene-d8 (Surr)100 70-130 10/02/23 18:51 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
99 10/02/23 18:51 14-Bromofluorobenzene (Surr)70-130
103 10/02/23 18:51 1Dibromofluoromethane (Surr)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-4657/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
Dichlorodifluoromethane 20.0 22.54 ug/L 113 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Chloromethane 20.0 18.55 ug/L 93 60 -140
Vinyl chloride 20.0 17.84 ug/L 89 60 -140
Bromomethane 20.0 16.15 ug/L 81 60 -140
Chloroethane 20.0 20.14 ug/L 101 60 -140
Trichlorofluoromethane 20.0 23.33 ug/L 117 60 -140
1,1-Dichloroethene 20.0 20.68 ug/L 103 70 -130
Methylene Chloride 20.0 20.97 ug/L 105 70 -130
Methyl tert-butyl ether 20.0 20.71 ug/L 104 70 -130
trans-1,2-Dichloroethene 20.0 20.18 ug/L 101 70 -130
1,1-Dichloroethane 20.0 20.28 ug/L 101 70 -130
Isopropyl ether 20.0 21.41 ug/L 107 70 -130
cis-1,2-Dichloroethene 20.0 20.37 ug/L 102 70 -130
2,2-Dichloropropane 20.0 21.28 ug/L 106 70 -130
Bromochloromethane 20.0 19.56 ug/L 98 70 -130
Chloroform 20.0 18.92 ug/L 95 70 -130
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-4657/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
1,1,1-Trichloroethane 20.0 20.58 ug/L 103 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1-Dichloropropene 20.0 19.32 ug/L 97 70 -130
Carbon tetrachloride 20.0 20.15 ug/L 101 70 -130
1,2-Dichloroethane 20.0 18.40 ug/L 92 70 -130
Benzene 20.0 18.70 ug/L 94 70 -130
Trichloroethene 20.0 17.63 ug/L 88 70 -130
1,2-Dichloropropane 20.0 19.54 ug/L 98 70 -130
Dibromomethane 20.0 18.01 ug/L 90 70 -130
Bromodichloromethane 20.0 19.23 ug/L 96 70 -130
cis-1,3-Dichloropropene 20.0 18.45 ug/L 92 70 -130
Toluene 20.0 17.73 ug/L 89 70 -130
trans-1,3-Dichloropropene 20.0 19.86 ug/L 99 70 -130
1,1,2-Trichloroethane 20.0 17.59 ug/L 88 70 -130
1,3-Dichloropropane 20.0 17.66 ug/L 88 70 -130
Tetrachloroethene 20.0 19.03 ug/L 95 70 -130
Dibromochloromethane 20.0 18.47 ug/L 92 70 -130
1,2-Dibromoethane 20.0 18.15 ug/L 91 70 -130
Chlorobenzene 20.0 18.46 ug/L 92 70 -130
1,1,1,2-Tetrachloroethane 20.0 20.58 ug/L 103 70 -130
Ethanol 100 100.9 ug/L 101 70 -130
Ethylbenzene 20.0 17.58 ug/L 88 70 -130
Freon 113 40.0 45.91 ug/L 115 70 -130
m,p-Xylenes 40.0 36.42 ug/L 91 70 -130
o-Xylene 20.0 17.67 ug/L 88 70 -130
Styrene 20.0 17.86 ug/L 89 70 -130
Bromoform 20.0 21.26 ug/L 106 70 -130
4-Isopropyltoluene 20.0 19.38 ug/L 97 70 -130
1,1,2,2-Tetrachloroethane 20.0 18.75 ug/L 94 70 -130
Bromobenzene 20.0 16.68 ug/L 83 70 -130
1,2,3-Trichloropropane 20.0 18.49 ug/L 92 70 -130
N-Propylbenzene 20.0 18.15 ug/L 91 70 -130
2-Chlorotoluene 20.0 18.27 ug/L 91 70 -130
1,3,5-Trimethylbenzene 20.0 17.89 ug/L 89 70 -130
4-Chlorotoluene 20.0 18.89 ug/L 94 70 -130
tert-Butylbenzene 20.0 19.89 ug/L 99 70 -130
1,2,4-Trimethylbenzene 20.0 19.35 ug/L 97 70 -130
sec-Butylbenzene 20.0 19.33 ug/L 97 70 -130
1,3-Dichlorobenzene 20.0 18.38 ug/L 92 70 -130
Isopropylbenzene 20.0 18.16 ug/L 91 70 -130
1,4-Dichlorobenzene 20.0 19.34 ug/L 97 70 -130
n-Butylbenzene 20.0 18.12 ug/L 91 70 -130
1,2-Dichlorobenzene 20.0 19.05 ug/L 95 70 -130
1,2-Dibromo-3-Chloropropane 20.0 20.22 ug/L 101 70 -130
1,2,4-Trichlorobenzene 20.0 18.43 ug/L 92 70 -130
Hexachlorobutadiene 20.0 16.33 ug/L 82 70 -130
Xylenes, Total 60.0 54.09 ug/L 90 70 -130
1,2,3-Trichlorobenzene 20.0 18.67 ug/L 93 70 -130
Naphthalene 20.0 18.83 ug/L 94 70 -130
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-4657/6
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
Toluene-d8 (Surr)70 -130
Surrogate
98
LCS LCS
Qualifier Limits%Recovery
1014-Bromofluorobenzene (Surr)70 -130
109Dibromofluoromethane (Surr)70 -130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 752-4657/8
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
tert-Butyl Formate 20.0 23.69 ug/L 118 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Tert-butyl ethyl ether 20.0 17.74 ug/L 89 70 -130
Tert-amyl methyl ether 20.0 18.15 ug/L 91 70 -130
tert-Amyl alcohol 200 157.0 ug/L 78 70 -130
tert-Butyl alcohol 200 158.2 ug/L 79 70 -130
Toluene-d8 (Surr)70 -130
Surrogate
95
LCS LCS
Qualifier Limits%Recovery
1014-Bromofluorobenzene (Surr)70 -130
99Dibromofluoromethane (Surr)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-4657/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
Dichlorodifluoromethane 20.0 20.18 ug/L 101 60 -140 11
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Chloromethane 20.0 16.53 ug/L 83 60 -140 12
Vinyl chloride 20.0 17.48 ug/L 87 60 -140 2
Bromomethane 20.0 15.98 ug/L 80 60 -140 1
Chloroethane 20.0 19.08 ug/L 95 60 -140 5
Trichlorofluoromethane 20.0 21.98 ug/L 110 60 -140 6
1,1-Dichloroethene 20.0 19.19 ug/L 96 70 -130 7
Methylene Chloride 20.0 19.88 ug/L 99 70 -130 5
Methyl tert-butyl ether 20.0 20.37 ug/L 102 70 -130 2
trans-1,2-Dichloroethene 20.0 18.85 ug/L 94 70 -130 7
1,1-Dichloroethane 20.0 18.37 ug/L 92 70 -130 10
Isopropyl ether 20.0 20.81 ug/L 104 70 -130 3
cis-1,2-Dichloroethene 20.0 19.35 ug/L 97 70 -130 5
2,2-Dichloropropane 20.0 18.60 ug/L 93 70 -130 13
Bromochloromethane 20.0 19.94 ug/L 100 70 -130 2
Chloroform 20.0 18.89 ug/L 94 70 -130 0
1,1,1-Trichloroethane 20.0 18.73 ug/L 94 70 -130 9
1,1-Dichloropropene 20.0 18.90 ug/L 95 70 -130 2
Carbon tetrachloride 20.0 18.29 ug/L 91 70 -130 10
1,2-Dichloroethane 20.0 19.25 ug/L 96 70 -130 5
Benzene 20.0 18.30 ug/L 92 70 -130 2
Trichloroethene 20.0 17.79 ug/L 89 70 -130 1
1,2-Dichloropropane 20.0 19.47 ug/L 97 70 -130 0
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 752-4657/7
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
Dibromomethane 20.0 18.66 ug/L 93 70 -130 4
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Bromodichloromethane 20.0 17.77 ug/L 89 70 -130 8
cis-1,3-Dichloropropene 20.0 19.08 ug/L 95 70 -130 3
Toluene 20.0 16.57 ug/L 83 70 -130 7
trans-1,3-Dichloropropene 20.0 18.46 ug/L 92 70 -130 7
1,1,2-Trichloroethane 20.0 16.18 ug/L 81 70 -130 8
1,3-Dichloropropane 20.0 17.27 ug/L 86 70 -130 2
Tetrachloroethene 20.0 16.81 ug/L 84 70 -130 12
Dibromochloromethane 20.0 17.89 ug/L 89 70 -130 3
1,2-Dibromoethane 20.0 17.45 ug/L 87 70 -130 4
Chlorobenzene 20.0 17.19 ug/L 86 70 -130 7
1,1,1,2-Tetrachloroethane 20.0 17.18 ug/L 86 70 -130 18
Ethanol 100 116.5 ug/L 117 70 -130 14
Ethylbenzene 20.0 16.97 ug/L 85 70 -130 4
Freon 113 40.0 43.79 ug/L 109 70 -130 5
m,p-Xylenes 40.0 34.90 ug/L 87 70 -130 4
o-Xylene 20.0 16.76 ug/L 84 70 -130 5
Styrene 20.0 16.92 ug/L 85 70 -130 5
Bromoform 20.0 20.77 ug/L 104 70 -130 2
4-Isopropyltoluene 20.0 19.55 ug/L 98 70 -130 1
1,1,2,2-Tetrachloroethane 20.0 17.48 ug/L 87 70 -130 7
Bromobenzene 20.0 16.46 ug/L 82 70 -130 1
1,2,3-Trichloropropane 20.0 16.15 ug/L 81 70 -130 14
N-Propylbenzene 20.0 17.15 ug/L 86 70 -130 6
2-Chlorotoluene 20.0 18.55 ug/L 93 70 -130 2
1,3,5-Trimethylbenzene 20.0 17.08 ug/L 85 70 -130 5
4-Chlorotoluene 20.0 17.25 ug/L 86 70 -130 9
tert-Butylbenzene 20.0 20.93 ug/L 105 70 -130 5
1,2,4-Trimethylbenzene 20.0 18.40 ug/L 92 70 -130 5
sec-Butylbenzene 20.0 18.70 ug/L 94 70 -130 3
1,3-Dichlorobenzene 20.0 18.80 ug/L 94 70 -130 2
Isopropylbenzene 20.0 16.61 ug/L 83 70 -130 9
1,4-Dichlorobenzene 20.0 18.89 ug/L 94 70 -130 2
n-Butylbenzene 20.0 17.15 ug/L 86 70 -130 6
1,2-Dichlorobenzene 20.0 19.04 ug/L 95 70 -130 0
1,2-Dibromo-3-Chloropropane 20.0 18.35 ug/L 92 70 -130 10
1,2,4-Trichlorobenzene 20.0 19.09 ug/L 95 70 -130 4
Hexachlorobutadiene 20.0 17.56 ug/L 88 70 -130 7
Xylenes, Total 60.0 51.66 ug/L 86 70 -130 5
1,2,3-Trichlorobenzene 20.0 18.33 ug/L 92 70 -130 2
Naphthalene 20.0 19.14 ug/L 96 70 -130 2
Toluene-d8 (Surr)70 -130
Surrogate
96
LCSD LCSD
Qualifier Limits%Recovery
1024-Bromofluorobenzene (Surr)70 -130
99Dibromofluoromethane (Surr)70 -130
Eurofins Raleigh
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-4657/17
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
tert-Butyl Formate 1.00 1.339 J ug/L 134
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Tert-butyl ethyl ether 1.00 0.9889 J ug/L 99
Tert-amyl methyl ether 1.00 0.8696 J ug/L 87
tert-Amyl alcohol 10.0 3.590 J ug/L 36
tert-Butyl alcohol 10.0 8.885 J ug/L 89
Toluene-d8 (Surr)70 -130
Surrogate
98
MRL MRL
Qualifier Limits%Recovery
1024-Bromofluorobenzene (Surr)70 -130
103Dibromofluoromethane (Surr)70 -130
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-4657/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
Dichlorodifluoromethane 1.00 ND ug/L 0
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Chloromethane 1.00 0.2676 J ug/L 27
Vinyl chloride 1.00 0.4366 J ug/L 44
Bromomethane 1.00 0.3322 J ug/L 33
Chloroethane 1.00 0.3095 J ug/L 31
Trichlorofluoromethane 1.00 0.5594 J ug/L 56
1,1-Dichloroethene 1.00 1.083 ug/L 108
Methylene Chloride 1.00 0.7448 J ug/L 74
Methyl tert-butyl ether 1.00 1.134 ug/L 113
trans-1,2-Dichloroethene 1.00 0.4670 J ug/L 47
1,1-Dichloroethane 1.00 1.099 ug/L 110
Isopropyl ether 1.00 1.218 ug/L 122
cis-1,2-Dichloroethene 1.00 1.156 ug/L 116
2,2-Dichloropropane 1.00 1.664 ug/L 166
Bromochloromethane 1.00 0.9298 J ug/L 93
Chloroform 1.00 1.010 ug/L 101
1,1,1-Trichloroethane 1.00 1.167 ug/L 117
1,1-Dichloropropene 1.00 1.089 ug/L 109
Carbon tetrachloride 1.00 0.7652 J ug/L 77
1,2-Dichloroethane 1.00 0.8183 J ug/L 82
Benzene 1.00 1.097 ug/L 110
Trichloroethene 1.00 1.386 ug/L 139
1,2-Dichloropropane 1.00 1.129 ug/L 113
Dibromomethane 1.00 1.284 ug/L 128
Bromodichloromethane 1.00 0.7803 J ug/L 78
cis-1,3-Dichloropropene 1.00 1.152 ug/L 115
Toluene 1.00 1.064 ug/L 106
trans-1,3-Dichloropropene 1.00 0.9698 J ug/L 97
1,1,2-Trichloroethane 1.00 1.126 ug/L 113
1,3-Dichloropropane 1.00 1.315 ug/L 132
Tetrachloroethene 1.00 0.8893 J ug/L 89
Dibromochloromethane 1.00 0.6990 J ug/L 70
Eurofins Raleigh
Page 23 of 31 10/6/2023
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QC Sample Results
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: MRL 752-4657/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 4657
1,2-Dibromoethane 1.00 1.166 ug/L 117
Analyte
MRL MRL
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Chlorobenzene 1.00 0.9994 J ug/L 100
1,1,1,2-Tetrachloroethane 1.00 1.002 ug/L 100
Ethanol 20.0 41.53 J ug/L 208
Ethylbenzene 1.00 0.9230 J ug/L 92
Freon 113 1.00 1.503 ug/L 150
m,p-Xylenes 2.00 2.169 ug/L 108
o-Xylene 1.00 0.9597 J ug/L 96
Styrene 1.00 1.021 ug/L 102
Bromoform 1.00 1.176 ug/L 118
4-Isopropyltoluene 1.00 0.9235 J ug/L 92
1,1,2,2-Tetrachloroethane 1.00 1.020 ug/L 102
Bromobenzene 1.00 0.9978 J ug/L 100
1,2,3-Trichloropropane 1.00 0.4417 J ug/L 44
N-Propylbenzene 1.00 1.060 ug/L 106
2-Chlorotoluene 1.00 1.082 ug/L 108
1,3,5-Trimethylbenzene 1.00 0.7768 J ug/L 78
4-Chlorotoluene 1.00 1.256 ug/L 126
tert-Butylbenzene 1.00 1.029 ug/L 103
1,2,4-Trimethylbenzene 1.00 1.008 ug/L 101
sec-Butylbenzene 1.00 0.8660 J ug/L 87
1,3-Dichlorobenzene 1.00 0.9078 J ug/L 91
Isopropylbenzene 1.00 1.025 ug/L 102
1,4-Dichlorobenzene 1.00 1.154 ug/L 115
n-Butylbenzene 1.00 0.8077 J ug/L 81
1,2-Dichlorobenzene 1.00 1.017 ug/L 102
1,2-Dibromo-3-Chloropropane 1.00 1.282 ug/L 128
1,2,4-Trichlorobenzene 1.00 1.406 ug/L 141
Hexachlorobutadiene 1.00 1.236 ug/L 124
Xylenes, Total 3.00 3.129 ug/L 104
1,2,3-Trichlorobenzene 1.00 1.099 ug/L 110
Naphthalene 1.00 1.039 ug/L 104
Toluene-d8 (Surr)70 -130
Surrogate
98
MRL MRL
Qualifier Limits%Recovery
1064-Bromofluorobenzene (Surr)70 -130
105Dibromofluoromethane (Surr)70 -130
Eurofins Raleigh
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QC Association Summary
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
GC/MS VOA
Analysis Batch: 4657
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B752-11689-1 MW-1 Total/NA
Water SM6200-B752-11689-2 MW-2 Total/NA
Water SM6200-B752-11689-3 MW-5 Total/NA
Water SM6200-B752-11689-4 MW-9 Total/NA
Water SM6200-B752-11689-5 MW-10 Total/NA
Water SM6200-BMB 752-4657/10 Method Blank Total/NA
Water SM6200-BLCS 752-4657/6 Lab Control Sample Total/NA
Water SM6200-BLCS 752-4657/8 Lab Control Sample Total/NA
Water SM6200-BLCSD 752-4657/7 Lab Control Sample Dup Total/NA
Water SM6200-BMRL 752-4657/17 Lab Control Sample Total/NA
Water SM6200-BMRL 752-4657/5 Lab Control Sample Total/NA
Eurofins Raleigh
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Lab Chronicle
Client: East Coast Environmental Job ID: 752-11689-1
Project/Site: Grocery Bag
Client Sample ID: MW-1 Lab Sample ID: 752-11689-1
Matrix: WaterDate Collected: 09/18/23 15:00
Date Received: 09/19/23 13:20
Analysis SM6200-B RY10/02/23 19:5050 EET ESC4657
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Instrument ID:CVGCMS4
Client Sample ID: MW-2 Lab Sample ID: 752-11689-2
Matrix: WaterDate Collected: 09/18/23 15:15
Date Received: 09/19/23 13:20
Analysis SM6200-B RY10/02/23 20:2020 EET ESC4657
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Instrument ID:CVGCMS4
Client Sample ID: MW-5 Lab Sample ID: 752-11689-3
Matrix: WaterDate Collected: 09/18/23 15:30
Date Received: 09/19/23 13:20
Analysis SM6200-B RY10/02/23 20:495 EET ESC4657
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Instrument ID:CVGCMS4
Client Sample ID: MW-9 Lab Sample ID: 752-11689-4
Matrix: WaterDate Collected: 09/18/23 13:45
Date Received: 09/19/23 13:20
Analysis SM6200-B RY10/02/23 21:1910 EET ESC4657
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Instrument ID:CVGCMS4
Client Sample ID: MW-10 Lab Sample ID: 752-11689-5
Matrix: WaterDate Collected: 09/18/23 14:00
Date Received: 09/19/23 13:20
Analysis SM6200-B RY10/02/23 19:211 EET ESC4657
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Instrument ID:CVGCMS4
Laboratory References:
EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL [phone]
Eurofins Raleigh
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Accreditation/Certification Summary
Client: East Coast Environmental Job ID: 752-11689-1
Project/Site: Grocery Bag
Laboratory: Eurofins Raleigh
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 591 12-31-23
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
SM6200-B Water Freon 113
SM6200-B Water tert-Amyl alcohol
SM6200-B Water Tert-amyl methyl ether
SM6200-B Water tert-Butyl alcohol
SM6200-B Water Tert-butyl ethyl ether
SM6200-B Water tert-Butyl Formate
Eurofins Raleigh
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Method Summary
Job ID: 752-11689-1Client: East Coast Environmental
Project/Site: Grocery Bag
Method Method Description LaboratoryProtocol
SMSM6200-B Volatile Organic Compounds EET ESC
SMSM6200-B Purge and Trap EET ESC
Protocol References:
SM = "Standard Methods For The Examination Of Water And Wastewater"
Laboratory References:
EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL [phone]
Eurofins Raleigh
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Sample Summary
Client: East Coast Environmental Job ID: 752-11689-1
Project/Site: Grocery Bag
Lab Sample ID Client Sample ID Matrix Collected Received
752-11689-1 MW-1 Water 09/18/23 15:00 09/19/23 13:20
752-11689-2 MW-2 Water 09/18/23 15:15 09/19/23 13:20
752-11689-3 MW-5 Water 09/18/23 15:30 09/19/23 13:20
752-11689-4 MW-9 Water 09/18/23 13:45 09/19/23 13:20
752-11689-5 MW-10 Water 09/18/23 14:00 09/19/23 13:20
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Login Sample Receipt Checklist
Client: East Coast Environmental Job Number: 752-11689-1
SDG Number:
Login Number: 11689
Question Answer Comment
Creator: Yonish, Rachel
List Source: Eurofins Raleigh
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Raleigh
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