AS-3650_28785_CA_MRP_20230412

Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina

ACTIVE REMEDIATION MONITORING
REPORT

For
BILTMORE OIL COMPANY
EBLEN SHORT STOP #2
217 Amboy Road Asheville, North Carolina 28806 Incident No. 28785
PROJECT # SEI-1318

PREPARED FOR: Biltmore Oil Company 191 Amboy Road Asheville, NC 28806

PREPARED BY:
Singleton Environmental, Inc.
PO Box 604
Fletcher, NC 28732
[phone] April 12, 2023

Singleton Environmental, Inc
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
GROUNDWATER MONITORING REPORT April 12, 2023 Site Name: Eblen Short Stop #2 217 Amboy Road Asheville, NC 28806 Buncombe County Incident Number: 28785 Risk Classification: Intermediate Responsible Party (UST): Biltmore Oil Company
Attn: Mr. Rick Perkins 191 Amboy Road Asheville, NC 28806
Property Owner: SANISCO, LLC PO Box 2805
Asheville, NC 28802 Report Prepared By: Singleton Environmental, Inc PO Box 604 Fletcher, North Carolina, 28732 [phone] Release Location: 35.567029 / -82.573258
Signature and Seal of the Certifying Licensed Geologist:
I, Christopher D. Singleton, a North Carolina Licensed Geologist, do certify that the information contained in this report is correct and accurate to the best of my knowledge.
___________________________________ Christopher D. Singleton, P.G. #1928

Singleton Environmental, Inc. is licensed to practice geology in North Carolina. The corporate license number is C-443.
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
Table of Contents
Introduction ................................................................................................................................1
Site History…......................…………......................................... .................................................1 Monitoring Well Replacement…......................…………......................................... .....................3 Free Phase Product…......................…………......................................... ......................................3 Groundwater Monitoring…......................…………......................................... .............................4
Conclusions and Recommendations…..................…………......................................... ................5 Tables Table 1: Monitoring Well Construction Details Table 2: Groundwater Elevation Data
Table 3: Groundwater Quality Data-Volatile Organic Compounds Table 4: Groundwater Quality Data-Semi-volatile Organic Compounds Table 5: Groundwater Quality Data-MADEP VPH/EPH Figures Figure 1: Site Vicinity Map Figure 2: Site Map
Figure 3: Free Product/LNAPL Isoconcentration Contour Map Figure 4: Groundwater Elevation Map Figure 5: Groundwater Quality Map Figure 6: BTEX Isoconcentration Contour Map Figure 7: Naphthalene Isoconcentration Contour Map
Appendices Appendix A: Laboratory Analytical Report
Appendix B: Disposal Manifest
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
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Introduction
Singleton Environmental, Inc. is presenting a summary of groundwater monitoring activities related to a release from the underground storage tank (UST) system at the Eblen Short Stop #2 located at 217
Amboy Road in Asheville, NC. The monitoring event was conducted on February 16, 2023. Figure 1 is a portion of the 2017 Lidar Hillshade with topographic contours and depicts the site location and vicinity
with relevant topographic features. Figure 2 is a site map showing the UST field and monitoring well locations on a 2019 aerial image basemap. The site is located on the north side of Amboy Road in an area of commercial and residential development. Site History
During a routine site inspection conducted in 2009, a release from the diesel dispenser was detected. Soil samples collected indicated total petroleum hydrocarbons as diesel and gasoline range organics (TPH-DRO/GRO) at a concentration of 669 milligrams per kilogram (mg/kg) and 374 mg/kg, respectively. The
Site Check Report was submitted (by others) to The North Carolina Department of Environmental Quality (NCDEQ) in December 2009. Impacted soil associated with the diesel fuel dispenser was subsequently excavated in August 2011 and post excavation samples indicated no analytes in excess of
the soil to water maximum contaminant concentrations (MSCCs). The Initial Abatement Action Report was submitted to NCDEQ in October 2011. In September 2011 a leak was detected in the 8,000-gallon gasoline underground storage tank (UST). As part of the initial abatement activities, the UST was pumped out and repaired. Subsequent assessment activities included the installation of on-site monitoring wells and sampling. Monitoring wells MW-1, MW-3, and MW-5 historically contained free phase product and four aggressive fluid vapor recovery events (AFVR) were conducted between December 2012 and May 2013 removing approximately 1,742-gallons of product. The following assessment reports have been submitted (by others) to NCDEQ in relation to the gasoline release at the Eblen Short Stop #2
• 20-Day Report – October 2011
• Initial Abatement Action Report (IAAR) – June 2014
• Limited Site Assessment Report (LSA) – August 2014
• Comprehensive Site Assessment Report (CSA) – October 2016
• Groundwater Monitoring Report – April 10, 2019
• Groundwater Monitoring Report – November 13, 2019
• Groundwater Monitoring Report – April 13, 2020
• Groundwater Monitoring Report – November 30, 2020
• Groundwater Monitoring Report – August 23, 2022
On July 24, 2019 a Notice of Violation letter was issued by NCDEQ indicating that the diesel dispenser (9/10) did not have a proper spill containment bucket installed. Therefore, Biltmore Oil Company
contracted Mountain Environmental to perform site check activities. On August 6, 2019, Mountain Environmental personnel visited the subject site with Biltmore Oil
personnel in order to perform site check soil sampling activities. According to Biltmore Oil personnel, dispenser 9/10, which did not contain proper spill containment, was the stand-alone diesel fuel dispenser. One soil sample (DISP-1) was collected immediately underneath the fuel dispenser utilizing a stainless steel hand auger. The soil sample was collected at approximately 1.5-2 feet below ground surface (bgs)
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
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and submitted to Pace Analytical for analysis of total petroleum hydrocarbons – gasoline range organics (GRO) and diesel range organics (DRO). Laboratory results indicate that the sample contained TPH-DRO
at a concentration of 741 mg/kg and TPH-GRO at a concentration of 464 mg/kg. Both the TPH-DRO and TPH-GRO concentrations exceed the NCDEQ Cleanup Level of 100 mg/kg and 50 mg/kg, respectively indicating a reportable release has occurred. On October 17, 2019 Mountain Environmental Services, Inc. performed additional site check activities. Due to the elevated TPH-DRO/GRO levels, an additional soil sample was collected underneath the stand-alone diesel dispenser in the same location as the August 2019 sampling. The additional soil sample D-1 was submitted to Pace Analytical for analysis of Risk-Based Parameters. This included volatile organic compounds (VOCs) by EPA Method 8260, semi-volatile organic compounds (SVOCs) by EPA Method 8270, and MADEP Methods for extractable and volatile petroleum hydrocarbons (MADEP-EPH/VPH).
According to the laboratory analytical report total C9-C22 aromatics exceeded the soil-to-groundwater maximum contaminant concentrations (MSCCs). No analytes exceeded the residential or industrial/commercial MSCCs. The Site Check Report was submitted to NCDEQ on November 13, 2019.
The following table summarizes information about USTs at this site:
Tank No. Volume (gallons)
Contents (i.e., gasoline, diesel, kerosene, heating oil, waste oil, etc.)
Use (resale, heating building, distribution, farm or residential, etc.)
Date last used
Indicate whether UST has been removed or closed in place
Date of permanent closure (if applicable)
Was a release detected from this UST system? If yes, give date. 1 6,000 Diesel resale current current n/a yes
2 8,000 Gasoline resale current repaired-current n/a yes
3 8,000 Gasoline resale current current n/a no
4 3,000 Gasoline resale current current n/a no
5 2,000 Kerosene resale current current n/a no
6 1,000 Diesel resale current current n/a no

The following table summarizes information about ASTs at this site:
Tank No. Volume (gallons)
Contents (i.e., gasoline, diesel, kerosene, heating oil, waste oil, etc.)
Use (resale, heating building, distribution, farm or residential, etc.)
Date last used
Indicate whether UST has been removed or closed in place
Date of permanent closure (if applicable)
Was a release detected from this UST system? If yes, give date. 1 2,000 Biodiesel resale current current n/a no

Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
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Monitoring Well Replacement
On March 9, 2022, NCDEQ issued a Notice of Regulatory Requirements requesting the replacement of monitoring wells MW-1, MW-4, and MW-7 which had been lost and not sampled since approximately
2016, the replacement of MW-2 which had a damaged casing, and the proper surface completion of existing wells MW-3 and MW-5. On June 6-7, 2022, Mountain Environmental replaced monitoring wells
MW-1, MW-2, MW-4, and MW-7 and replaced the surface manhole covers on MW-3 and MW-5. The location of the newly installed monitoring wells are depicted in Figure 2 and summarized on Table 1. All monitoring wells were completed per the 15A NCAC 2C.0108 standards.
Free Phase Product
Monitoring wells MW-1, MW-3, and MW-5 historically contained free phase product and four aggressive fluid vapor recovery events (AFVR) were conducted between December 2012 and October 2019
removing approximately 1,767-gallons of product. The most recent AFVR event was performed on October 30, 2019. Monitoring wells MW-1, MW-3, and MW-5 were gauged prior to commencement of the AFVR event. MW-1 did not contain measurable free phase product; however, MW-3 and MW-5 contained approximately 0.16 feet and 0.28 feet, respectively. Upon completion of the October 2019 AFVR event no measurable free phase product was detected in MW-3 or MW-5; however, a heavy sheen was observed. The AFVR event recovered a total of 450 gallons of mixed product and water. It is estimated that approximately 25 gallons of free product was removed. During the August 2022 sampling event, free product was detected in monitoring wells MW-1 and MW-5 at a thickness of 0.10 feet and 0.11 feet, respectively. Approximately 2-gallons of product and liquid was bailed from each monitoring well (MW-1 and MW-5) and absorbent socks were subsequently placed in
each well. The product was transported to Mountain Environmental for bulk disposal. As part of the February 2023 sampling event, free product was detected in monitoring wells MW-1 and
MW-5 at a thickness of 0.21 feet and 0.43 feet, respectively. Approximately 2-gallons of product and liquid were bailed from each monitoring well (MW-1 and MW-5) and absorbent socks were subsequently replaced in each well. The product was transported to Mountain Environmental for bulk disposal –
Appendix B. Figure 3 depicts the estimated free product/LNAPL isoconcentration contours.
Groundwater Monitoring
Monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, and MW-7 were gauged as part of the monitoring event on February 16, 2023. Based on groundwater elevation data, groundwater flow appears
to be directed to the southwest toward Moore Branch. This is consistent with historical observations. Groundwater elevation data is summarized in Table 2 and a groundwater elevation map indicating
groundwater flow direction is included as Figure 4. Monitoring wells MW-2, MW-3, MW-4, MW-6, and MW-7 were sampled as part of the monitoring event on February 16, 2023. Monitoring wells MW-1 and MW-5 contained approximately 0.21 feet and 0.43 feet of free product, respectively. Groundwater samples were submitted to Pace Analytical in Asheville, NC for analysis of volatile organic compounds (VOCs) by EPA Method 6200 and semi-volatile organic
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
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compounds (SVOCs) by EPA Method 625. Laboratory analytical results indicate the following VOCs in excess of the NCAC 2L Standards:

• Benzene: MW-3 (5,960 ug/l).
• Toluene: MW-3 (5,060 ug.l).
• Ethylbenzene: MW-3 (1,410 ug/l).
• Total xylenes: MW-2 (1,009 ug/l) and MW-3 (6,100 ug/l).

• Naphthalene (6200): MW-2 (61.2 ug/l) and MW-3 (339 ug/l).
• N-Propylbenzene: MW-3 (147 ug/l).

• Isopropylbenzene: MW-3 (59 ug/l).
• 1,2,4-Trimethylbenzene: MW-2 (1,220 ug/l) and MW-3 (1,390 ug/l).
• 1,2,3-Trichloropropane: MW-2 (8.8 ug/l).
• Bromodichloromethane: MW-4 (1.9 ug/l) Additionally, benzene exceeded the GCL in MW-3. Laboratory analytical results indicate the following SVOCs in excess of the NCAC 2L Standards:

• Naphthalene (625): MW-2 (25.4 ug/l) and MW-3 (193 ug/l).
• Bis(2-Ethylhexyl)phthalate: MW-3 (6.9 ug/l). VOC groundwater quality data is included in Table 3. SVOC groundwater quality data is included as Table 4 and historical VPH/EPH groundwater quality data is included as Table 5. Groundwater quality
data is included as Figure 5, a total BTEX isoconcentration contour map, is included as Figure 6 and a naphthalene isoconcentration contour map is included as Figure 7. The laboratory analytical report is included as Appendix A. Conclusions and Recommendations Based on the February 2023 monitoring event, laboratory results indicate that VOCs and SVOCs exceed the NCAC 2L Standards in MW-2, MW-3, and MW-4. The analyte benzene exceeded the corresponding GCL in MW-3. Free product was detected in MW-1 and MW-5 at a thickness of 0.21 feet and 0.43 feet, respectively. At this time, Singleton Environmental, Inc. proposes to continue pre-CAP monitoring activities with the next groundwater monitoring event to be conducted August 2023. Additionally, free product levels will
Groundwater Monitoring Report Eblen Short Stop #2 Asheville, North Carolina
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be gauged and bailed in monitoring wells MW-1 and MW-5 for the month of August with absorbent socks replaced as necessary.

Tables
Well Well Type Date
Installed
TOC
Elevation1
(ft)
Well Diameter
(inches)Total Depth2
(ft)
MW-1 Type II 06/06/22 98.06 2"5.00 -15.00 15.00
MW-2 Type II 06/06/22 100.54 2"5.00 -15.00 15.00
MW-3 Type II 02/15/13 96.53 2"6.00 -16.00 16.00
MW-4 Type II 06/06/22 95.83 2"5.00 -15.00 15.00
MW-5 Type II 05/08/13 96.51 2"6.00 -16.00 16.00
MW-6 Type II 10/01/16 91.24 2"1.50 -4.00 4.00
MW-7 Type II 06/07/22 100.86 2"5.00 -15.00 15.00
NOTES:
1. TOC = Top Of Casing. Elevation is based on a relative datum, not elevation above sea level.
2. Depth measured from top of well casing.
Screened
Interval (ft)
Table 1
Monitoring Well Construction Details
Eblen Short Stop #2
Asheville, North Carolina
Well ID Date
TOC
Elevation1
(ft)
Depth to
NAPL2
(ft)
Depth to
Water3
(ft)
Product
Thickness4
(ft)
Groundwater
Elevation5 (ft)
10/2/2016 11.38 11.57 0.19 86.64
3/25/2019 NM 10.88 NM 89.12
10/17/2019 NM 10.97 NM 89.03
4/2/2020 NM NM NM NM
11/4/2020 NM NM NM NM
2/8/2022 NM NM NM NM
8/10/2022 9.19 9.29 0.10 88.85
2/16/2023 9.01 9.22 0.21 89.01
10/2/2016 NM 11.74 NM 88.80
3/25/2019 NM 10.96 NM 89.58
10/17/2019 NM 11.25 NM 89.23
4/2/2020 NM 11.03 NM 89.45
11/4/2020 NM 11.01 NM 89.47
2/8/2022 NM 10.45 NM 90.03
8/10/2022 NM 11.50 NM 89.04
2/16/2023 NM 10.41 NM 90.13
10/2/2016 NM 8.15 NM 88.38
3/25/2019 NM 8.01 NM 88.52
10/17/2019 9.45 9.61 0.16 87.05
4/2/2020 NM 9.11 NM 87.42
11/4/2020 NM 9.05 NM 87.48
2/8/2022 NM 7.27 NM 89.26
8/10/2022 NM 8.45 NM 88.08
2/16/2023 NM 7.31 NM 89.22
10/2/2016 NM 7.84 NM 87.99
3/25/2019 NM NM NM NM
10/17/2019 NM NM NM NM
4/2/2020 NM NM NM NM
11/4/2020 NM NM NM NM
2/8/2022 NM NM NM NM
8/10/2022 NM 8.81 NM 87.02
2/16/2023 NM 9.92 NM 85.91
NOTES:
1. TOC = Top Of Casing. Elevation is based on a relative datum, not elevation above sea level.
2. NAPL = Non aqueous petroeum liquid (free product).
3. Depth to NAPL/water reported in feet below top of casing.
4. NM=Not Measured.
5. Groundwater elevation is corrected using the groundwater elevation equation for free-product:
(TOC Elevation-DTW)+(0.80x(product thickness)
Table 2
Groundwater Elevation Data
Eblen Short Stop #2
Asheville, North Carolina
98.06
100.54
MW-3 96.53
MW-4 95.83
MW-1
MW-2
6. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed.
on June 6-7, 2022.
Well ID Date
TOC
Elevation1
(ft)
Depth to
NAPL2
(ft)
Depth to
Water3
(ft)
Product
Thickness4
(ft)
Groundwater
Elevation5 (ft)
10/2/2016 NM 8.18 NM 88.33
3/25/2019 NM 8.05 NM 88.46
10/17/2019 9.33 9.61 0.28 87.12
4/2/2020 9.22 9.23 0.01 87.29
11/4/2020 NM 9.95 NM 86.56
2/8/2022 7.05 7.15 0.10 89.44
8/10/2022 8.29 8.40 0.11 88.20
2/16/2023 8.01 8.44 0.43 88.41
10/2/2016 NM 3.03 NM 88.21
3/25/2019 NM 2.90 NM 88.34
10/17/2019 NM 2.81 NM 88.43
4/2/2020 NM 1.06 NM 90.18
11/4/2020 NM 1.00 NM 90.24
2/8/2022 NM 0.95 NM 89.29
8/10/2022 NM 0.88 NM 90.36
2/16/2023 NM 0.55 NM 90.69
10/2/2016 NM 10.70 NM 90.16
3/25/2019 NM NM NM NM
10/17/2019 NM NM NM NM
4/2/2020 NM NM NM NM
11/4/2020 NM NM NM NM
2/8/2022 NM NM NM NM
8/10/2022 NM 11.99 NM 88.87
2/16/2023 NM 10.22 NM 90.64
NOTES:
1. TOC = Top Of Casing. Elevation is based on a relative datum, not elevation above sea level.
2. NAPL = Non aqueous petroeum liquid (free product).
3. Depth to NAPL/water reported in feet below top of casing.
4. NM=Not Measured.
5. Groundwater elevation is corrected using the groundwater elevation equation for free-product:
(TOC Elevation-DTW)+(0.80x(product thickness)
6. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed.
on June 6-7, 2022.
96.51
91.24
MW-7 100.86
Table 2
Groundwater Elevation Data
Eblen Short Stop #2
Asheville, North Carolina
MW-5
MW-6
Table 3 Groundwater Quality Data Volatile Organic Compounds
Eblen Short Stop #2
Asheville, North Carolina
Monitoring
Well Sample
Date µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l
2L Standard 1 600 70 600 500 6 70 70 400 400 NE 20
GCL 5,000 260,000 5,900 80,000 50,000 6,000 26,100 30,500 28,500 24,100 NE 20,000
10/15/2011
1/18/2012 23,700 38,900 --3,500 20,050 ------------1,370
12/1/2012
5/1/2013
3/25/2014 16,900 38,200 --3,140 18,100 ------------24
10/2/2016
3/25/2019 6,310 42,000 <125 4,270 22,730 <500 --130 2,440 584 --<125
10/17/2019 <25.0 430 <25.0 996 12,570 528 <25.0 113 3,290 <25.0 <25.0
4/2/2020
11/4/2020
2/8/2022
8/10/2022
2/16/2023
12/1/2012
3/25/2014 165 5,460 --810 4,700 ------------<1
10/2/2016 <25 6,400 269 1,940 16,730 ----<25 3,630 998 --<25
3/25/2019 <12.5 700 <12.5 1,550 12,540 481 --124 4,220 1,270 --<12.5
10/17/2019 115 1,910 <25.0 1,090 12,090 434 256 88.6 2,920 793 --<25.0
4/2/2020 <10.0 217 <10.0 536 6,720 289 <10.0 67.3 2,740 <10.0 --<10.0
11/4/2020 <5.0 21.2 <5.0 131 1,924 120 <5.0 23 1,230 <5.0 --<5.0
2/8/2022 <6.2 <6.2 <6.2 26 945 89.1 93 48.7 1,760 519 12.6 <6.2
8/10/2022 <6.2 <6.2 <6.2 7.6 383 57.8 75.6 40.7 1,840 546 12.9 <6.2
2/16/2023 <5.0 <5.0 16.2 45.2 1,009 61.2 36.3 20.6 1,220 388 8.8 <5.0
12/1/2012
5/1/2013
3/25/2014
10/2/2016
3/25/2019 10,400 18,300 <62.5 3,030 17,440 492 --118 2,490 572 --66.7
10/17/2019
4/2/2020 10,400 10,400 <50.0 1,920 10,090 524 <50.0 70.7 1,890 <50.0 --<50.0
11/4/2020 10,700 8,680 <50.0 2,080 9,360 659 <50.0 83.9 2,200 <50.0 --<50.0
2/8/2022 10,300 7,100 <50 2,270 10,220 576 337 121 2,880 758 <50 <50.0
8/10/2022 17,000 13,800 <50 2,620 10,830 654 361 121 3,120 827 <50 90.2
2/16/2023 5,960 5,060 <25 1,410 6,100 339 147 59.0 1,390 354 <25 <25
NOTES:
1. μg/L - micrograms per liter
2. ND - Not Detected
3. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed on
June 6-7, 2022
MW-3
0.5" Free product
Free product bailed during sampling
--
Isopropylbenzene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,3-Trichloropropane MTBEXylenes
7" Free product
2.5" Free product
MW-1
MW-2
Naphthalene (EPA 6200)n-Propylbenzene
48" Free product
1" Free product
3" Free product
2" Free product
Could not locate
Could not locate
Could not locate
0.10' Free Product-Bailed during sampling and absorbent socks placed in well
0.21' Free Product-Bailed during sampling and absorbent socks placed in well
Benzene Toluene n-butylbenzene Ethylbenzene
8" Free product
Table 3 Groundwater Quality Data Volatile Organic Compounds Eblen Short Stop #2 Asheville, North Carolina
Monitoring
Well Sample
Date µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l
2L Standard 1 600 70 600 500 6 70 70 400 400 NE 20 70 NE
GCL 5,000 260,000 5,900 80,000 50,000 6,000 26,100 30,500 28,500 24,100 NE 20,000 70,000 NE
3/25/2014 <1 14 --2 13 ------------<1 ----
10/2/2016 <1 <1 <1 <1 <2 ----<1 <1 <1 --<1 ----
3/25/2019
10/17/2019
4/2/2020
11/4/2020
2/8/2022
8/10/2022 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 6.3 2.3 <0.50 0.86 <0.50 <0.50
2/16/2023 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 15.1 1.9
5/1/2013
3/25/2014
10/2/2016
3/25/2019 7,620 6,530 143 2,250 9,730 587 --136 3,090 807 --<25 ----
10/17/2019
4/2/2020
11/4/2020 2,780 694 <20 1,700 4,394 485 342 101 2,290 534 --<20 ----
2/8/2022
8/10/2022
2/16/2023
10/2/2016 20 1 --1 5 ----1 6 1 --2 ----
3/25/2019 169 234 <2.5 299 2,161 275 --40.6 1,500 348 --52.1 ----
10/17/2019 <12.5 187 <12.5 530 6,390 272 <12.5 68.2 1,880 552 --<12.5 ----
4/2/2020 298 1.7 <1.2 1.3 6.8 <5.0 1.9 <1.2 1.4 <1.2 --47 ----
11/4/2020 8.2 45.7 <2.0 60.2 296.1 123 <2.0 6.7 228 56.7 --<2.0 ----
2/8/2022 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 ----
8/10/2022 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 76.3 4.8
2/16/2023 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
10/2/2016 <1 <1 <1 <1 <2 --<1 <1 <1 --<1 ----
3/25/2019
10/17/2019
4/2/2020
11/4/2020
11/5/2020
8/10/2022 <0.50 <0.50 <0.50 <0.50 <1.5 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 3.4 <0.50
2/16/2023 <0.50 <0.50 0.87 <0.50 <1.5 <2.0 <0.50 <0.50 1.0 <0.50 <0.50 <0.50 2.8 <0.50
Moore Branch 10/2/2016 <1 <1 <1 <1 <2 ----<1 <1 <1 --<1 ----
NOTES:
1. μg/L - micrograms per liter
2. ND - Not Detected
3. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed on
June 6-7, 2022
MW-6
MW-7
Benzene Toluene n-butylbenzene
MW-4
Could not locate
Could not locate
Could not locate
Could not locate
Could not locate
0.25" Free product
Free product bailed during sampling
2.8" Free Product
SHEEN
1.0" Free Product
Could not locate
Could not locate
Could not locate
0.5" Free product
MW-5
0.11" Free Product-Bailed during sampling and absorbent socks placed in well
0.43" Free Product-Bailed during sampling and absorbent socks placed in well
Chloroform Bromodichloromethanen-Propylbenzene
Could not locate
Could not locate
Ethylbenzene Xylenes Naphthalene (EPA 6200)Isopropylbenzene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,3-Trichloropropane MTBE
Table 4 Groundwater Quality Data Semi-Volatile Organic Compounds Eblen Short Stop #2 Asheville, North Carolina
Monitoring
Well Sample
Date µg/l µg/l µg/l µg/l µg/l
2L Standard 100 6 300 30 200
GCL 100,000 6,000 990 30,000 410
3/25/2014 ----------
10/2/2016 ----------
3/25/2019
10/17/2019
4/2/2020
11/4/2020
2/8/2022
8/10/2022 <8.3 <4.2 <4.2 <4.2 <4.2
2/16/2023 <8.3 <4.2 <4.2 <4.2 <4.2
5/1/2013
3/25/2014
10/2/2016
3/25/2019 <100 508 509 510
10/17/2019
4/2/2020
11/4/2020 <50.0 820 <25.0 <25.0 <25.0
2/8/2022
8/10/2022
2/16/2023
10/2/2016 ----------
3/25/2019 <100 208 209 --210
10/17/2019 <10.0 195 <5.0 --<5.0
4/2/2020 <10.0 <5.0 <5.0 8.4 <5.0
11/4/2020 <50.0 105 <25.0 <25.0 <25.0
2/8/2022 <9.1 <4.5 <4.5 <4.5 <4.5
8/10/2022 <10 <5.0 <5.0 <5.0 <5.0
2/16/2023 <8.3 <4.2 <4.2 <4.2 <4.2
10/2/2016 --------
3/25/2019
10/17/2019
4/2/2020
11/4/2020
2/8/2022
8/10/2022 <9.1 <4.5 <4.5 <4.5 <4.5
2/16/2023 <8.3 <4.2 <4.2 <4.2 <4.2
Moore Branch 10/2/2016 ----------
NOTES:
1. μg/L - micrograms per liter
2. ND - Not Detected
3. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed on
June 6-7, 2022
Could not locate
Could not locate
MW-5
MW-6
MW-7
1.0" Free Product
0.11'Free product-Bailed during sampling and absorbent socks placed in well
Could not locate
Could not locate
Could not locate
0.5" Free product
0.25" Free product
Free product bailed during sampling
2.8" Free Product
Sheen
MW-4
0.43' Free product-Bailed during sampling and absorbent socks placed in well
2,4-Dimethylphenol Naphthalene (EPA 625)Flourene Phenol Phenanthrene
Could not locate
Could not locate
Could not locate
Could not locate
Could not locate
Table 5 Groundwater Quality Data
MADEP VPH/EPH Eblen Short Stop #2
Asheville, North Carolina
Monitoring
Well Sample
Date µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l
2L Standard 400 ----700 --10,000 --200
GCL ----------------
10/2/2016
3/25/2019 129,000 112,000 2,150 114,150 54,100 <392 271 271
10/17/2019 21,000 61,000 2,470 63,470 31,100 <240 1,310 32,410
4/2/2020
11/4/2020
2/8/2022
8/10/2022
10/2/2016 NS NS NS NS NS NS NS NS
3/25/2019 95,000 184,000 582 184,582 103,000 <98 218 103,218
10/17/2019 54,800 97,400 45,400 142,800 44,100 <4,900 12,100 56,200
4/2/2020 NS NS NS NS NS NS NS NS
11/4/2020 1,090 3,620 635 4,255 2,740 <100 116 2,856
2/8/2022 5,970 3,620 430 4,050 4,410 120 470 4,880
8/10/2022 7,630 2,340 855 3,195 4,560 <100 930 5,490
10/2/2016
3/25/2019 118,000 231,000 400,000 631,000 116,000 <49,000 35,100 151,100
10/17/2019
4/2/2020 NS NS NS NS NS NS NS NS
11/4/2020 36,600 21,300 55,600 76,900 10,200 <10,000 21,000 31,200
2/8/2022 101,000 29,700 3,900 33,600 12,700 110 1,800 14,500
8/10/2022 210,000 30,000 43,100 73,100 13,700 <2,500 6,090 19,790
NOTES:
1. μg/L - micrograms per liter
2. ND - Not Detected
3. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed on
June 6-7, 2022
C11-C22
Aromatics
TOTAL C9-C22
Aromatics
C5-C8
Aliphatics
MW-1
MW-2
C9-C12
Aliphatics
C9-C18
Aliphatics
Total C9-C18
Aliphatics
C9-C10
Aromatics
C19-C36
Aliphatics
MW-3
2" Free product
Could not locate
Could not locate
Could not locate
0.10" Free product-Bailed during sampling and absorbent socks placed in well
Free product bailed during sampling
1.6" Free Product
Table 5 Groundwater Quality Data
MADEP VPH/EPH Eblen Short Stop #2 Asheville, North Carolina
Monitoring
Well Sample
Date µg/l µg/l µg/l µg/l µg/l µg/l µg/l µg/l
2L Standard 400 ----700 --10,000 --200
GCL ----------------
10/2/2016 NS NS NS NS NS NS NS NS
3/25/2019
10/17/2019
4/2/2020
11/4/2020
2/8/2022
8/10/2022 193 <50 817 817 65.2 <200 <200 65.2
10/2/2016
3/25/2019 47,200 87,700 145,000 232,700 48,100 <19,600 19,400 67,500
10/17/2019
4/2/2020
11/4/2020 5,450 7,830 54,300 62,130 6,170 <10,000 13,800 19,970
2/8/2022
8/10/2022
10/2/2016 53 <50 NS <50 <50 NS NS <50
3/25/2019 1,600 12,500 4,210 16,710 7,740 <490 975 8,715
10/17/2019 15,600 48,400 9,470 57,870 23,000 <962 2,830 25,830
4/2/2020 NS NS NS NS NS NS NS NS
11/4/2020 <100 284 3,720 4,004 430 <400 856 1,286
2/8/2022 <50 <50 <96 <50 <50 <96 <96 <50
8/10/2022 <50 <50 <100 <150 <50 <100 <100 <150
10/2/2016 <50 <50 NS <50 <50 NS NS <50
3/25/2019
10/17/2019
4/2/2020
11/4/2020
2/8/2022
8/10/2022 <50 <50 288 288 <50 <200 <200 <200
Moore Branch 10/2/2016 NS NS NS NS NS NS NS NS
NOTES:
1. μg/L - micrograms per liter
2. ND - Not Detected
3. Monitoring wells MW-1, MW-2, MW-4, and MW-7 were replaced and re-surveyed on
June 6-7, 2022
MW-7
Could not locate
Could not locate
Could not locate
Could not locate
Could not locate
C19-C36 AliphaticsC5-C8 Aliphatics
MW-4
MW-5
MW-6
C11-C22 Aromatics TOTAL C9-C22 Aromatics
Sheen
1.0" Free Product
0.11" Free product-Bailed during sampling and absorbent socks placed in well
Could not locate
Could not locate
Could not locate
Could not locate
Could not locate
Free product bailed during sampling
2.8" Free Product
C9-C12 Aliphatics C9-C18 Aliphatics Total C9-C18 Aliphatics C9-C10 Aromatics

Figures
Contour interval 40 feet.
Site
Figure 1
SITE LOCATION MAP
Biltmore Oil-Eblen Short Stop #2
217 Amboy Road Asheville, NC
General location
Figure 2
Site Map
Eblen Short Stop #2
217 Amboy Road
Asheville, NC
Basemap is 2019 Aerial Imagery
MW-5
MW-6
MW-3
MW-1
MW-2
MW-7State St.Joyner Ave.
Amboy Rd.
C-Store
UST
Basin
MW-4
Canopy
Approximate
NotesState St.Joyner Ave.
A mboy Rd.
C-Store
UST
Basin
Canopy
Figure 4
Free Product/LNAPL Isoconcentration Contour
Map Eblen Short Stop #2
217 Amboy Road
Asheville, NC
1.Monitoring wells were gauged and sampled onFebruary 16, 2023
2.--- - - Free Product/LNAPL IsoconcentrationContour Line.
3
Figure 4
Groundwater Elevation Map
Eblen Short Stop #2
217 Amboy Road
Asheville, NC
Notes1.Monitoring wells were gauged and sampled onFebruary 16, 2023.2.Monitoring well MW-6 was not used to calculate
groundwater flow direction.State St.Joyn er Ave.
Amboy Rd.
C-Store
UST
Basin
Canopy
MW-5
MW-6
MW-3
MW-1
MW-2 MW-790.13 90.64
89.01
89.22
88.41
90.69
85.91
90.00
90.50
87.00
88.00
89.00
86.00
MW-4
Figure 5
Groundwater Quality Map
Eblen Short Stop #2
217 Amboy Road Asheville, NC
Notes1.Monitoring wells were gauged and sampled onFebruary 16, 2023.2.Analytes listed represent NCDEQ Exceedence.State St.Joyne r Ave.
Amboy Rd.
C-Store
UST
Basin
Canopy
MW-10.21’ free product gauged. Product was bailed
and absorbent socks placed in well.
MW-2Naphthalene (6200)-61.2 ug/lTotal Xylenes-1,009 ug/l1,2,4-Trimethylbenzene-1,220 ug/l1,2,3-Trichloropropane-8.8 ug/l
Naphthalene (625)-25.4ug/l
MW-3
Benzene-5,960 ug/l
Toluene-5,060 ug/l
Ethylbenzene-1,410ug/l
Total Xylenes-6,100 ug/l
Naphthalene (6200)-339ug/l
n-Propylbenzene-147 ug/l
Isopropylbenzene-59 ug/l
1,2,4-Trimethylbenzene-1,390 ug/l
Naphthalene (625)-193 ug/lbis(2-Ethylhexyl)phthalate-6.9 ug/l
MW-7
No Exceedances
MW-5
0.43’ Free product gauged.
Product was bailed and
absorbent socks placed in
well.
MW-4Bromodichloromethane-1.9 ug/l
MW-6No Exceedances
State St.Joyner Ave.
Amboy Rd.
C-Store
UST
Basin
Canopy
Figure 6
BTEX Isoconcentration Contour Map
Eblen Short Stop #2
217 Amboy Road
Asheville, NC
Notes
Monitoring wells were gauged and sampled on February 16, 2023.
(18,530)-BTEX Concentration in ug/l (ppb).
--- - - - BTEX Isoconcentration Contour in ug/l (ppb).
1,000 ug/l10,000 ug/lLNAPL
State St.Joyner Ave.
Amboy Rd.
C-Store
UST
Basin
Canopy
Figure 7
Naphthalene Isoconcentration Contour Map
Eblen Short Stop #2
217 Amboy Road
Asheville, NC
Notes
Monitoring wells were gauged and sampled on February 16, 2023.
(528)-Naphthalene Concentration in ug/l (ppb).
--- - - - Naphthalene Isoconcentration Contour in ug/l (ppb).
10 ug/l
100 ug/lLNAPL
1 ug/l

Appendix A
Laboratory Analytical Report

#=CL#
February 27, 2023
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92652903
92652903
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
BILTMORE OIL- AMBOY ROAD
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
[phone]
Enclosures
cc:Briam Bauer, Singleton Environmental
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 38
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 38
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92652903001 MW-2 EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
92652903002 MW-3 EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
92652903003 MW-4 EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
92652903004 MW-6 EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
92652903005 MW-7 EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-2 Lab ID:92652903001 Collected:02/16/23 08:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/23/23 12:50 83-32-902/22/23 14:175.0 1
Acenaphthylene ND ug/L 02/23/23 12:50 208-96-802/22/23 14:175.0 1
Anthracene ND ug/L 02/23/23 12:50 120-12-702/22/23 14:175.0 1
Benzo(a)anthracene ND ug/L 02/23/23 12:50 56-55-302/22/23 14:175.0 1
Benzo(a)pyrene ND ug/L 02/23/23 12:50 50-32-802/22/23 14:175.0 1
Benzo(b)fluoranthene ND ug/L 02/23/23 12:50 205-99-202/22/23 14:175.0 1
Benzo(g,h,i)perylene ND ug/L 02/23/23 12:50 191-24-202/22/23 14:175.0 1
Benzo(k)fluoranthene ND ug/L 02/23/23 12:50 207-08-902/22/23 14:175.0 1
4-Bromophenylphenyl ether ND ug/L 02/23/23 12:50 101-55-302/22/23 14:175.0 1
Butylbenzylphthalate ND ug/L 02/23/23 12:50 85-68-702/22/23 14:175.0 1
4-Chloro-3-methylphenol ND ug/L 02/23/23 12:50 59-50-702/22/23 14:175.0 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/23 12:50 111-91-102/22/23 14:1710.0 1
bis(2-Chloroethyl) ether ND ug/L 02/23/23 12:50 111-44-402/22/23 14:175.0 1
2-Chloronaphthalene ND ug/L 02/23/23 12:50 91-58-702/22/23 14:175.0 1
2-Chlorophenol ND ug/L 02/23/23 12:50 95-57-802/22/23 14:175.0 1
4-Chlorophenylphenyl ether ND ug/L 02/23/23 12:50 7005-72-302/22/23 14:175.0 1
Chrysene ND ug/L 02/23/23 12:50 218-01-902/22/23 14:175.0 1
Dibenz(a,h)anthracene ND ug/L 02/23/23 12:50 53-70-302/22/23 14:175.0 1
3,3'-Dichlorobenzidine ND ug/L 02/23/23 12:50 91-94-102/22/23 14:1710.0 1
2,4-Dichlorophenol ND ug/L 02/23/23 12:50 120-83-202/22/23 14:175.0 1
Diethylphthalate ND ug/L 02/23/23 12:50 84-66-2 L102/22/23 14:175.0 1
2,4-Dimethylphenol ND ug/L 02/23/23 12:50 105-67-9 L102/22/23 14:1710.0 1
Dimethylphthalate ND ug/L 02/23/23 12:50 131-11-3 L102/22/23 14:175.0 1
Di-n-butylphthalate ND ug/L 02/23/23 12:50 84-74-2 L102/22/23 14:175.0 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/23 12:50 534-52-102/22/23 14:1710.0 1
2,4-Dinitrophenol ND ug/L 02/23/23 12:50 51-28-502/22/23 14:1750.0 1
2,4-Dinitrotoluene ND ug/L 02/23/23 12:50 121-14-202/22/23 14:175.0 1
2,6-Dinitrotoluene ND ug/L 02/23/23 12:50 606-20-202/22/23 14:175.0 1
Di-n-octylphthalate ND ug/L 02/23/23 12:50 117-84-002/22/23 14:175.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/23 12:50 117-81-702/22/23 14:175.0 1
Fluoranthene ND ug/L 02/23/23 12:50 206-44-002/22/23 14:175.0 1
Fluorene ND ug/L 02/23/23 12:50 86-73-702/22/23 14:175.0 1
Hexachloro-1,3-butadiene ND ug/L 02/23/23 12:50 87-68-302/22/23 14:175.0 1
Hexachlorobenzene ND ug/L 02/23/23 12:50 118-74-102/22/23 14:175.0 1
Hexachlorocyclopentadiene ND ug/L 02/23/23 12:50 77-47-402/22/23 14:1710.0 1
Hexachloroethane ND ug/L 02/23/23 12:50 67-72-102/22/23 14:175.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/23 12:50 193-39-502/22/23 14:175.0 1
Isophorone ND ug/L 02/23/23 12:50 78-59-102/22/23 14:1710.0 1
Naphthalene 25.4 ug/L 02/23/23 12:50 91-20-302/22/23 14:175.0 1
Nitrobenzene ND ug/L 02/23/23 12:50 98-95-302/22/23 14:175.0 1
2-Nitrophenol ND ug/L 02/23/23 12:50 88-75-502/22/23 14:175.0 1
4-Nitrophenol ND ug/L 02/23/23 12:50 100-02-702/22/23 14:1710.0 1
N-Nitrosodimethylamine ND ug/L 02/23/23 12:50 62-75-902/22/23 14:175.0 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/23 12:50 621-64-702/22/23 14:175.0 1
N-Nitrosodiphenylamine ND ug/L 02/23/23 12:50 86-30-602/22/23 14:1710.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/23/23 12:50 108-60-102/22/23 14:175.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-2 Lab ID:92652903001 Collected:02/16/23 08:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 02/23/23 12:50 87-86-502/22/23 14:1710.0 1
Phenanthrene ND ug/L 02/23/23 12:50 85-01-802/22/23 14:175.0 1
Phenol ND ug/L 02/23/23 12:50 108-95-202/22/23 14:175.0 1
Pyrene ND ug/L 02/23/23 12:50 129-00-0 L102/22/23 14:175.0 1
1,2,4-Trichlorobenzene ND ug/L 02/23/23 12:50 120-82-102/22/23 14:175.0 1
2,4,6-Trichlorophenol ND ug/L 02/23/23 12:50 88-06-202/22/23 14:1710.0 1
Surrogates
Nitrobenzene-d5 (S)77 %02/23/23 12:50 4165-60-002/22/23 14:1710-120 1
2-Fluorobiphenyl (S)62 %02/23/23 12:50 321-60-802/22/23 14:1715-120 1
Terphenyl-d14 (S)79 %02/23/23 12:50 1718-51-002/22/23 14:1711-131 1
Phenol-d6 (S)42 %02/23/23 12:50 13127-88-302/22/23 14:1710-120 1
2-Fluorophenol (S)48 %02/23/23 12:50 367-12-402/22/23 14:1710-120 1
2,4,6-Tribromophenol (S)68 %02/23/23 12:50 118-79-602/22/23 14:1710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 02/21/23 17:43 71-43-25.0 10
Bromobenzene ND ug/L 02/21/23 17:43 108-86-15.0 10
Bromochloromethane ND ug/L 02/21/23 17:43 74-97-55.0 10
Bromodichloromethane ND ug/L 02/21/23 17:43 75-27-45.0 10
Bromoform ND ug/L 02/21/23 17:43 75-25-25.0 10
Bromomethane ND ug/L 02/21/23 17:43 74-83-950.0 10
n-Butylbenzene 16.2 ug/L 02/21/23 17:43 104-51-85.0 10
sec-Butylbenzene ND ug/L 02/21/23 17:43 135-98-85.0 10
tert-Butylbenzene ND ug/L 02/21/23 17:43 98-06-65.0 10
Carbon tetrachloride ND ug/L 02/21/23 17:43 56-23-55.0 10
Chlorobenzene ND ug/L 02/21/23 17:43 108-90-75.0 10
Chloroethane ND ug/L 02/21/23 17:43 75-00-310.0 10
Chloroform ND ug/L 02/21/23 17:43 67-66-35.0 10
Chloromethane ND ug/L 02/21/23 17:43 74-87-310.0 10
2-Chlorotoluene ND ug/L 02/21/23 17:43 95-49-85.0 10
4-Chlorotoluene ND ug/L 02/21/23 17:43 106-43-45.0 10
1,2-Dibromo-3-chloropropane ND ug/L 02/21/23 17:43 96-12-810.0 10
Dibromochloromethane ND ug/L 02/21/23 17:43 124-48-15.0 10
1,2-Dibromoethane (EDB)ND ug/L 02/21/23 17:43 106-93-45.0 10
Dibromomethane ND ug/L 02/21/23 17:43 74-95-35.0 10
1,2-Dichlorobenzene ND ug/L 02/21/23 17:43 95-50-15.0 10
1,3-Dichlorobenzene ND ug/L 02/21/23 17:43 541-73-15.0 10
1,4-Dichlorobenzene ND ug/L 02/21/23 17:43 106-46-75.0 10
Dichlorodifluoromethane ND ug/L 02/21/23 17:43 75-71-85.0 10
1,1-Dichloroethane ND ug/L 02/21/23 17:43 75-34-35.0 10
1,2-Dichloroethane ND ug/L 02/21/23 17:43 107-06-25.0 10
1,1-Dichloroethene ND ug/L 02/21/23 17:43 75-35-45.0 10
cis-1,2-Dichloroethene ND ug/L 02/21/23 17:43 156-59-25.0 10
trans-1,2-Dichloroethene ND ug/L 02/21/23 17:43 156-60-55.0 10
1,2-Dichloropropane ND ug/L 02/21/23 17:43 78-87-55.0 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-2 Lab ID:92652903001 Collected:02/16/23 08:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 02/21/23 17:43 142-28-95.0 10
2,2-Dichloropropane ND ug/L 02/21/23 17:43 594-20-75.0 10
1,1-Dichloropropene ND ug/L 02/21/23 17:43 563-58-65.0 10
cis-1,3-Dichloropropene ND ug/L 02/21/23 17:43 10061-01-55.0 10
trans-1,3-Dichloropropene ND ug/L 02/21/23 17:43 10061-02-65.0 10
Diisopropyl ether ND ug/L 02/21/23 17:43 108-20-35.0 10
Ethylbenzene 45.2 ug/L 02/21/23 17:43 100-41-45.0 10
Hexachloro-1,3-butadiene ND ug/L 02/21/23 17:43 87-68-320.0 10
Isopropylbenzene (Cumene)20.6 ug/L 02/21/23 17:43 98-82-85.0 10
Methylene Chloride ND ug/L 02/21/23 17:43 75-09-220.0 10
Methyl-tert-butyl ether ND ug/L 02/21/23 17:43 1634-04-45.0 10
Naphthalene 61.2 ug/L 02/21/23 17:43 91-20-320.0 10
n-Propylbenzene 36.3 ug/L 02/21/23 17:43 103-65-15.0 10
Styrene ND ug/L 02/21/23 17:43 100-42-55.0 10
1,1,1,2-Tetrachloroethane ND ug/L 02/21/23 17:43 630-20-65.0 10
1,1,2,2-Tetrachloroethane ND ug/L 02/21/23 17:43 79-34-55.0 10
Tetrachloroethene ND ug/L 02/21/23 17:43 127-18-45.0 10
Toluene ND ug/L 02/21/23 17:43 108-88-35.0 10
1,2,3-Trichlorobenzene ND ug/L 02/21/23 17:43 87-61-620.0 10
1,2,4-Trichlorobenzene ND ug/L 02/21/23 17:43 120-82-120.0 10
1,1,1-Trichloroethane ND ug/L 02/21/23 17:43 71-55-65.0 10
1,1,2-Trichloroethane ND ug/L 02/21/23 17:43 79-00-55.0 10
Trichloroethene ND ug/L 02/21/23 17:43 79-01-65.0 10
Trichlorofluoromethane ND ug/L 02/21/23 17:43 75-69-410.0 10
1,2,3-Trichloropropane 8.8 ug/L 02/21/23 17:43 96-18-45.0 10
1,2,4-Trimethylbenzene 1220 ug/L 02/21/23 17:43 95-63-65.0 10
1,3,5-Trimethylbenzene 388 ug/L 02/21/23 17:43 108-67-85.0 10
Vinyl chloride ND ug/L 02/21/23 17:43 75-01-410.0 10
m&p-Xylene 640 ug/L 02/21/23 17:43 179601-23-110.0 10
o-Xylene 369 ug/L 02/21/23 17:43 95-47-65.0 10
Surrogates
1,2-Dichloroethane-d4 (S)90 %02/21/23 17:43 17060-07-070-130 10
4-Bromofluorobenzene (S)96 %02/21/23 17:43 460-00-470-130 10
Toluene-d8 (S)99 %02/21/23 17:43 2037-26-570-130 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-3 Lab ID:92652903002 Collected:02/16/23 11:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/23/23 13:41 83-32-902/22/23 14:175.0 1
Acenaphthylene ND ug/L 02/23/23 13:41 208-96-802/22/23 14:175.0 1
Anthracene ND ug/L 02/23/23 13:41 120-12-702/22/23 14:175.0 1
Benzo(a)anthracene ND ug/L 02/23/23 13:41 56-55-302/22/23 14:175.0 1
Benzo(a)pyrene ND ug/L 02/23/23 13:41 50-32-802/22/23 14:175.0 1
Benzo(b)fluoranthene ND ug/L 02/23/23 13:41 205-99-202/22/23 14:175.0 1
Benzo(g,h,i)perylene ND ug/L 02/23/23 13:41 191-24-202/22/23 14:175.0 1
Benzo(k)fluoranthene ND ug/L 02/23/23 13:41 207-08-902/22/23 14:175.0 1
4-Bromophenylphenyl ether ND ug/L 02/23/23 13:41 101-55-302/22/23 14:175.0 1
Butylbenzylphthalate ND ug/L 02/23/23 13:41 85-68-702/22/23 14:175.0 1
4-Chloro-3-methylphenol ND ug/L 02/23/23 13:41 59-50-702/22/23 14:175.0 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/23 13:41 111-91-102/22/23 14:1710.0 1
bis(2-Chloroethyl) ether ND ug/L 02/23/23 13:41 111-44-402/22/23 14:175.0 1
2-Chloronaphthalene ND ug/L 02/23/23 13:41 91-58-702/22/23 14:175.0 1
2-Chlorophenol ND ug/L 02/23/23 13:41 95-57-802/22/23 14:175.0 1
4-Chlorophenylphenyl ether ND ug/L 02/23/23 13:41 7005-72-302/22/23 14:175.0 1
Chrysene ND ug/L 02/23/23 13:41 218-01-902/22/23 14:175.0 1
Dibenz(a,h)anthracene ND ug/L 02/23/23 13:41 53-70-302/22/23 14:175.0 1
3,3'-Dichlorobenzidine ND ug/L 02/23/23 13:41 91-94-102/22/23 14:1710.0 1
2,4-Dichlorophenol ND ug/L 02/23/23 13:41 120-83-202/22/23 14:175.0 1
Diethylphthalate ND ug/L 02/23/23 13:41 84-66-2 L102/22/23 14:175.0 1
2,4-Dimethylphenol 54.5 ug/L 02/23/23 13:41 105-67-9 L102/22/23 14:1710.0 1
Dimethylphthalate ND ug/L 02/23/23 13:41 131-11-3 L102/22/23 14:175.0 1
Di-n-butylphthalate ND ug/L 02/23/23 13:41 84-74-2 L102/22/23 14:175.0 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/23 13:41 534-52-102/22/23 14:1710.0 1
2,4-Dinitrophenol ND ug/L 02/23/23 13:41 51-28-502/22/23 14:1750.0 1
2,4-Dinitrotoluene ND ug/L 02/23/23 13:41 121-14-202/22/23 14:175.0 1
2,6-Dinitrotoluene ND ug/L 02/23/23 13:41 606-20-202/22/23 14:175.0 1
Di-n-octylphthalate ND ug/L 02/23/23 13:41 117-84-002/22/23 14:175.0 1
bis(2-Ethylhexyl)phthalate 6.9 ug/L 02/23/23 13:41 117-81-702/22/23 14:175.0 1
Fluoranthene ND ug/L 02/23/23 13:41 206-44-002/22/23 14:175.0 1
Fluorene ND ug/L 02/23/23 13:41 86-73-702/22/23 14:175.0 1
Hexachloro-1,3-butadiene ND ug/L 02/23/23 13:41 87-68-302/22/23 14:175.0 1
Hexachlorobenzene ND ug/L 02/23/23 13:41 118-74-102/22/23 14:175.0 1
Hexachlorocyclopentadiene ND ug/L 02/23/23 13:41 77-47-402/22/23 14:1710.0 1
Hexachloroethane ND ug/L 02/23/23 13:41 67-72-102/22/23 14:175.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/23 13:41 193-39-502/22/23 14:175.0 1
Isophorone ND ug/L 02/23/23 13:41 78-59-102/22/23 14:1710.0 1
Naphthalene 193 ug/L 02/23/23 17:30 91-20-302/22/23 14:1710.0 2
Nitrobenzene ND ug/L 02/23/23 13:41 98-95-302/22/23 14:175.0 1
2-Nitrophenol ND ug/L 02/23/23 13:41 88-75-502/22/23 14:175.0 1
4-Nitrophenol ND ug/L 02/23/23 13:41 100-02-702/22/23 14:1710.0 1
N-Nitrosodimethylamine ND ug/L 02/23/23 13:41 62-75-902/22/23 14:175.0 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/23 13:41 621-64-702/22/23 14:175.0 1
N-Nitrosodiphenylamine ND ug/L 02/23/23 13:41 86-30-602/22/23 14:1710.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/23/23 13:41 108-60-102/22/23 14:175.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-3 Lab ID:92652903002 Collected:02/16/23 11:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 02/23/23 13:41 87-86-502/22/23 14:1710.0 1
Phenanthrene ND ug/L 02/23/23 13:41 85-01-802/22/23 14:175.0 1
Phenol 27.3 ug/L 02/23/23 13:41 108-95-202/22/23 14:175.0 1
Pyrene ND ug/L 02/23/23 13:41 129-00-0 L102/22/23 14:175.0 1
1,2,4-Trichlorobenzene ND ug/L 02/23/23 13:41 120-82-102/22/23 14:175.0 1
2,4,6-Trichlorophenol ND ug/L 02/23/23 13:41 88-06-202/22/23 14:1710.0 1
Surrogates
Nitrobenzene-d5 (S)115 %02/23/23 13:41 4165-60-0 1g02/22/23 14:1710-120 1
2-Fluorobiphenyl (S)91 %02/23/23 13:41 321-60-802/22/23 14:1715-120 1
Terphenyl-d14 (S)110 %02/23/23 13:41 1718-51-002/22/23 14:1711-131 1
Phenol-d6 (S)56 %02/23/23 13:41 13127-88-302/22/23 14:1710-120 1
2-Fluorophenol (S)64 %02/23/23 13:41 367-12-402/22/23 14:1710-120 1
2,4,6-Tribromophenol (S)101 %02/23/23 13:41 118-79-602/22/23 14:1710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 5960 ug/L 02/20/23 16:23 71-43-225.0 50
Bromobenzene ND ug/L 02/20/23 16:23 108-86-125.0 50
Bromochloromethane ND ug/L 02/20/23 16:23 74-97-525.0 50
Bromodichloromethane ND ug/L 02/20/23 16:23 75-27-425.0 50
Bromoform ND ug/L 02/20/23 16:23 75-25-225.0 50
Bromomethane ND ug/L 02/20/23 16:23 74-83-925050
n-Butylbenzene ND ug/L 02/20/23 16:23 104-51-825.0 50
sec-Butylbenzene ND ug/L 02/20/23 16:23 135-98-825.0 50
tert-Butylbenzene ND ug/L 02/20/23 16:23 98-06-625.0 50
Carbon tetrachloride ND ug/L 02/20/23 16:23 56-23-525.0 50
Chlorobenzene ND ug/L 02/20/23 16:23 108-90-725.0 50
Chloroethane ND ug/L 02/20/23 16:23 75-00-350.0 50
Chloroform ND ug/L 02/20/23 16:23 67-66-325.0 50
Chloromethane ND ug/L 02/20/23 16:23 74-87-350.0 50
2-Chlorotoluene ND ug/L 02/20/23 16:23 95-49-825.0 50
4-Chlorotoluene ND ug/L 02/20/23 16:23 106-43-425.0 50
1,2-Dibromo-3-chloropropane ND ug/L 02/20/23 16:23 96-12-850.0 50
Dibromochloromethane ND ug/L 02/20/23 16:23 124-48-125.0 50
1,2-Dibromoethane (EDB)ND ug/L 02/20/23 16:23 106-93-425.0 50
Dibromomethane ND ug/L 02/20/23 16:23 74-95-325.0 50
1,2-Dichlorobenzene ND ug/L 02/20/23 16:23 95-50-125.0 50
1,3-Dichlorobenzene ND ug/L 02/20/23 16:23 541-73-125.0 50
1,4-Dichlorobenzene ND ug/L 02/20/23 16:23 106-46-725.0 50
Dichlorodifluoromethane ND ug/L 02/20/23 16:23 75-71-825.0 50
1,1-Dichloroethane ND ug/L 02/20/23 16:23 75-34-325.0 50
1,2-Dichloroethane ND ug/L 02/20/23 16:23 107-06-225.0 50
1,1-Dichloroethene ND ug/L 02/20/23 16:23 75-35-425.0 50
cis-1,2-Dichloroethene ND ug/L 02/20/23 16:23 156-59-225.0 50
trans-1,2-Dichloroethene ND ug/L 02/20/23 16:23 156-60-525.0 50
1,2-Dichloropropane ND ug/L 02/20/23 16:23 78-87-525.0 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-3 Lab ID:92652903002 Collected:02/16/23 11:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 02/20/23 16:23 142-28-925.0 50
2,2-Dichloropropane ND ug/L 02/20/23 16:23 594-20-725.0 50
1,1-Dichloropropene ND ug/L 02/20/23 16:23 563-58-625.0 50
cis-1,3-Dichloropropene ND ug/L 02/20/23 16:23 10061-01-525.0 50
trans-1,3-Dichloropropene ND ug/L 02/20/23 16:23 10061-02-625.0 50
Diisopropyl ether ND ug/L 02/20/23 16:23 108-20-325.0 50
Ethylbenzene 1410 ug/L 02/20/23 16:23 100-41-425.0 50
Hexachloro-1,3-butadiene ND ug/L 02/20/23 16:23 87-68-310050
Isopropylbenzene (Cumene)59.0 ug/L 02/20/23 16:23 98-82-825.0 50
Methylene Chloride ND ug/L 02/20/23 16:23 75-09-210050
Methyl-tert-butyl ether ND ug/L 02/20/23 16:23 1634-04-425.0 50
Naphthalene 339 ug/L 02/20/23 16:23 91-20-310050
n-Propylbenzene 147 ug/L 02/20/23 16:23 103-65-125.0 50
Styrene ND ug/L 02/20/23 16:23 100-42-525.0 50
1,1,1,2-Tetrachloroethane ND ug/L 02/20/23 16:23 630-20-625.0 50
1,1,2,2-Tetrachloroethane ND ug/L 02/20/23 16:23 79-34-525.0 50
Tetrachloroethene ND ug/L 02/20/23 16:23 127-18-425.0 50
Toluene 5060 ug/L 02/20/23 16:23 108-88-325.0 50
1,2,3-Trichlorobenzene ND ug/L 02/20/23 16:23 87-61-610050
1,2,4-Trichlorobenzene ND ug/L 02/20/23 16:23 120-82-110050
1,1,1-Trichloroethane ND ug/L 02/20/23 16:23 71-55-625.0 50
1,1,2-Trichloroethane ND ug/L 02/20/23 16:23 79-00-525.0 50
Trichloroethene ND ug/L 02/20/23 16:23 79-01-625.0 50
Trichlorofluoromethane ND ug/L 02/20/23 16:23 75-69-450.0 50
1,2,3-Trichloropropane ND ug/L 02/20/23 16:23 96-18-425.0 50
1,2,4-Trimethylbenzene 1390 ug/L 02/20/23 16:23 95-63-625.0 50
1,3,5-Trimethylbenzene 354 ug/L 02/20/23 16:23 108-67-825.0 50
Vinyl chloride ND ug/L 02/20/23 16:23 75-01-450.0 50
m&p-Xylene 4920 ug/L 02/20/23 16:23 179601-23-150.0 50
o-Xylene 1180 ug/L 02/20/23 16:23 95-47-625.0 50
Surrogates
1,2-Dichloroethane-d4 (S)95 %02/20/23 16:23 17060-07-070-130 50
4-Bromofluorobenzene (S)96 %02/20/23 16:23 460-00-470-130 50
Toluene-d8 (S)97 %02/20/23 16:23 2037-26-570-130 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-4 Lab ID:92652903003 Collected:02/16/23 09:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/23/23 14:06 83-32-902/22/23 14:174.2 1
Acenaphthylene ND ug/L 02/23/23 14:06 208-96-802/22/23 14:174.2 1
Anthracene ND ug/L 02/23/23 14:06 120-12-702/22/23 14:174.2 1
Benzo(a)anthracene ND ug/L 02/23/23 14:06 56-55-302/22/23 14:174.2 1
Benzo(a)pyrene ND ug/L 02/23/23 14:06 50-32-802/22/23 14:174.2 1
Benzo(b)fluoranthene ND ug/L 02/23/23 14:06 205-99-202/22/23 14:174.2 1
Benzo(g,h,i)perylene ND ug/L 02/23/23 14:06 191-24-202/22/23 14:174.2 1
Benzo(k)fluoranthene ND ug/L 02/23/23 14:06 207-08-902/22/23 14:174.2 1
4-Bromophenylphenyl ether ND ug/L 02/23/23 14:06 101-55-302/22/23 14:174.2 1
Butylbenzylphthalate ND ug/L 02/23/23 14:06 85-68-702/22/23 14:174.2 1
4-Chloro-3-methylphenol ND ug/L 02/23/23 14:06 59-50-702/22/23 14:174.2 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/23 14:06 111-91-102/22/23 14:178.3 1
bis(2-Chloroethyl) ether ND ug/L 02/23/23 14:06 111-44-402/22/23 14:174.2 1
2-Chloronaphthalene ND ug/L 02/23/23 14:06 91-58-702/22/23 14:174.2 1
2-Chlorophenol ND ug/L 02/23/23 14:06 95-57-802/22/23 14:174.2 1
4-Chlorophenylphenyl ether ND ug/L 02/23/23 14:06 7005-72-302/22/23 14:174.2 1
Chrysene ND ug/L 02/23/23 14:06 218-01-902/22/23 14:174.2 1
Dibenz(a,h)anthracene ND ug/L 02/23/23 14:06 53-70-302/22/23 14:174.2 1
3,3'-Dichlorobenzidine ND ug/L 02/23/23 14:06 91-94-102/22/23 14:178.3 1
2,4-Dichlorophenol ND ug/L 02/23/23 14:06 120-83-202/22/23 14:174.2 1
Diethylphthalate ND ug/L 02/23/23 14:06 84-66-2 L102/22/23 14:174.2 1
2,4-Dimethylphenol ND ug/L 02/23/23 14:06 105-67-9 L102/22/23 14:178.3 1
Dimethylphthalate ND ug/L 02/23/23 14:06 131-11-3 L102/22/23 14:174.2 1
Di-n-butylphthalate ND ug/L 02/23/23 14:06 84-74-2 L102/22/23 14:174.2 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/23 14:06 534-52-102/22/23 14:178.3 1
2,4-Dinitrophenol ND ug/L 02/23/23 14:06 51-28-502/22/23 14:1741.7 1
2,4-Dinitrotoluene ND ug/L 02/23/23 14:06 121-14-202/22/23 14:174.2 1
2,6-Dinitrotoluene ND ug/L 02/23/23 14:06 606-20-202/22/23 14:174.2 1
Di-n-octylphthalate ND ug/L 02/23/23 14:06 117-84-002/22/23 14:174.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/23 14:06 117-81-702/22/23 14:174.2 1
Fluoranthene ND ug/L 02/23/23 14:06 206-44-002/22/23 14:174.2 1
Fluorene ND ug/L 02/23/23 14:06 86-73-702/22/23 14:174.2 1
Hexachloro-1,3-butadiene ND ug/L 02/23/23 14:06 87-68-302/22/23 14:174.2 1
Hexachlorobenzene ND ug/L 02/23/23 14:06 118-74-102/22/23 14:174.2 1
Hexachlorocyclopentadiene ND ug/L 02/23/23 14:06 77-47-402/22/23 14:178.3 1
Hexachloroethane ND ug/L 02/23/23 14:06 67-72-102/22/23 14:174.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/23 14:06 193-39-502/22/23 14:174.2 1
Isophorone ND ug/L 02/23/23 14:06 78-59-102/22/23 14:178.3 1
Naphthalene ND ug/L 02/23/23 14:06 91-20-302/22/23 14:174.2 1
Nitrobenzene ND ug/L 02/23/23 14:06 98-95-302/22/23 14:174.2 1
2-Nitrophenol ND ug/L 02/23/23 14:06 88-75-502/22/23 14:174.2 1
4-Nitrophenol ND ug/L 02/23/23 14:06 100-02-702/22/23 14:178.3 1
N-Nitrosodimethylamine ND ug/L 02/23/23 14:06 62-75-902/22/23 14:174.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/23 14:06 621-64-702/22/23 14:174.2 1
N-Nitrosodiphenylamine ND ug/L 02/23/23 14:06 86-30-602/22/23 14:178.3 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/23/23 14:06 108-60-102/22/23 14:174.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-4 Lab ID:92652903003 Collected:02/16/23 09:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 02/23/23 14:06 87-86-502/22/23 14:178.3 1
Phenanthrene ND ug/L 02/23/23 14:06 85-01-802/22/23 14:174.2 1
Phenol ND ug/L 02/23/23 14:06 108-95-202/22/23 14:174.2 1
Pyrene ND ug/L 02/23/23 14:06 129-00-0 L102/22/23 14:174.2 1
1,2,4-Trichlorobenzene ND ug/L 02/23/23 14:06 120-82-102/22/23 14:174.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/23 14:06 88-06-202/22/23 14:178.3 1
Surrogates
Nitrobenzene-d5 (S)119 %02/23/23 14:06 4165-60-002/22/23 14:1710-120 1
2-Fluorobiphenyl (S)91 %02/23/23 14:06 321-60-802/22/23 14:1715-120 1
Terphenyl-d14 (S)115 %02/23/23 14:06 1718-51-002/22/23 14:1711-131 1
Phenol-d6 (S)64 %02/23/23 14:06 13127-88-302/22/23 14:1710-120 1
2-Fluorophenol (S)81 %02/23/23 14:06 367-12-402/22/23 14:1710-120 1
2,4,6-Tribromophenol (S)99 %02/23/23 14:06 118-79-602/22/23 14:1710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 02/21/23 16:31 71-43-20.50 1
Bromobenzene ND ug/L 02/21/23 16:31 108-86-10.50 1
Bromochloromethane ND ug/L 02/21/23 16:31 74-97-50.50 1
Bromodichloromethane 1.9 ug/L 02/21/23 16:31 75-27-40.50 1
Bromoform ND ug/L 02/21/23 16:31 75-25-20.50 1
Bromomethane ND ug/L 02/21/23 16:31 74-83-95.0 1
n-Butylbenzene ND ug/L 02/21/23 16:31 104-51-80.50 1
sec-Butylbenzene ND ug/L 02/21/23 16:31 135-98-80.50 1
tert-Butylbenzene ND ug/L 02/21/23 16:31 98-06-60.50 1
Carbon tetrachloride ND ug/L 02/21/23 16:31 56-23-50.50 1
Chlorobenzene ND ug/L 02/21/23 16:31 108-90-70.50 1
Chloroethane ND ug/L 02/21/23 16:31 75-00-31.0 1
Chloroform 15.1 ug/L 02/21/23 16:31 67-66-30.50 1
Chloromethane ND ug/L 02/21/23 16:31 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/21/23 16:31 95-49-80.50 1
4-Chlorotoluene ND ug/L 02/21/23 16:31 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/23 16:31 96-12-81.0 1
Dibromochloromethane ND ug/L 02/21/23 16:31 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/23 16:31 106-93-40.50 1
Dibromomethane ND ug/L 02/21/23 16:31 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 02/21/23 16:31 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 02/21/23 16:31 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 02/21/23 16:31 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 02/21/23 16:31 75-71-80.50 1
1,1-Dichloroethane ND ug/L 02/21/23 16:31 75-34-30.50 1
1,2-Dichloroethane ND ug/L 02/21/23 16:31 107-06-20.50 1
1,1-Dichloroethene ND ug/L 02/21/23 16:31 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 02/21/23 16:31 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 02/21/23 16:31 156-60-50.50 1
1,2-Dichloropropane ND ug/L 02/21/23 16:31 78-87-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
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[phone]
Page 11 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-4 Lab ID:92652903003 Collected:02/16/23 09:30 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 02/21/23 16:31 142-28-90.50 1
2,2-Dichloropropane ND ug/L 02/21/23 16:31 594-20-70.50 1
1,1-Dichloropropene ND ug/L 02/21/23 16:31 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 02/21/23 16:31 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 02/21/23 16:31 10061-02-60.50 1
Diisopropyl ether ND ug/L 02/21/23 16:31 108-20-30.50 1
Ethylbenzene ND ug/L 02/21/23 16:31 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 02/21/23 16:31 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 02/21/23 16:31 98-82-80.50 1
Methylene Chloride ND ug/L 02/21/23 16:31 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 02/21/23 16:31 1634-04-40.50 1
Naphthalene ND ug/L 02/21/23 16:31 91-20-32.0 1
n-Propylbenzene ND ug/L 02/21/23 16:31 103-65-10.50 1
Styrene ND ug/L 02/21/23 16:31 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/23 16:31 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/23 16:31 79-34-50.50 1
Tetrachloroethene ND ug/L 02/21/23 16:31 127-18-40.50 1
Toluene ND ug/L 02/21/23 16:31 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 02/21/23 16:31 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 02/21/23 16:31 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 02/21/23 16:31 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 02/21/23 16:31 79-00-50.50 1
Trichloroethene ND ug/L 02/21/23 16:31 79-01-60.50 1
Trichlorofluoromethane ND ug/L 02/21/23 16:31 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/21/23 16:31 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 02/21/23 16:31 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 02/21/23 16:31 108-67-80.50 1
Vinyl chloride ND ug/L 02/21/23 16:31 75-01-41.0 1
m&p-Xylene ND ug/L 02/21/23 16:31 179601-23-11.0 1
o-Xylene ND ug/L 02/21/23 16:31 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)91 %02/21/23 16:31 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %02/21/23 16:31 460-00-470-130 1
Toluene-d8 (S)101 %02/21/23 16:31 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-6 Lab ID:92652903004 Collected:02/16/23 10:18 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/23/23 14:32 83-32-902/22/23 14:174.2 1
Acenaphthylene ND ug/L 02/23/23 14:32 208-96-802/22/23 14:174.2 1
Anthracene ND ug/L 02/23/23 14:32 120-12-702/22/23 14:174.2 1
Benzo(a)anthracene ND ug/L 02/23/23 14:32 56-55-302/22/23 14:174.2 1
Benzo(a)pyrene ND ug/L 02/23/23 14:32 50-32-802/22/23 14:174.2 1
Benzo(b)fluoranthene ND ug/L 02/23/23 14:32 205-99-202/22/23 14:174.2 1
Benzo(g,h,i)perylene ND ug/L 02/23/23 14:32 191-24-202/22/23 14:174.2 1
Benzo(k)fluoranthene ND ug/L 02/23/23 14:32 207-08-902/22/23 14:174.2 1
4-Bromophenylphenyl ether ND ug/L 02/23/23 14:32 101-55-302/22/23 14:174.2 1
Butylbenzylphthalate ND ug/L 02/23/23 14:32 85-68-702/22/23 14:174.2 1
4-Chloro-3-methylphenol ND ug/L 02/23/23 14:32 59-50-702/22/23 14:174.2 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/23 14:32 111-91-102/22/23 14:178.3 1
bis(2-Chloroethyl) ether ND ug/L 02/23/23 14:32 111-44-402/22/23 14:174.2 1
2-Chloronaphthalene ND ug/L 02/23/23 14:32 91-58-702/22/23 14:174.2 1
2-Chlorophenol ND ug/L 02/23/23 14:32 95-57-802/22/23 14:174.2 1
4-Chlorophenylphenyl ether ND ug/L 02/23/23 14:32 7005-72-302/22/23 14:174.2 1
Chrysene ND ug/L 02/23/23 14:32 218-01-902/22/23 14:174.2 1
Dibenz(a,h)anthracene ND ug/L 02/23/23 14:32 53-70-302/22/23 14:174.2 1
3,3'-Dichlorobenzidine ND ug/L 02/23/23 14:32 91-94-102/22/23 14:178.3 1
2,4-Dichlorophenol ND ug/L 02/23/23 14:32 120-83-202/22/23 14:174.2 1
Diethylphthalate ND ug/L 02/23/23 14:32 84-66-2 L102/22/23 14:174.2 1
2,4-Dimethylphenol ND ug/L 02/23/23 14:32 105-67-9 L102/22/23 14:178.3 1
Dimethylphthalate ND ug/L 02/23/23 14:32 131-11-3 L102/22/23 14:174.2 1
Di-n-butylphthalate ND ug/L 02/23/23 14:32 84-74-2 L102/22/23 14:174.2 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/23 14:32 534-52-102/22/23 14:178.3 1
2,4-Dinitrophenol ND ug/L 02/23/23 14:32 51-28-502/22/23 14:1741.7 1
2,4-Dinitrotoluene ND ug/L 02/23/23 14:32 121-14-202/22/23 14:174.2 1
2,6-Dinitrotoluene ND ug/L 02/23/23 14:32 606-20-202/22/23 14:174.2 1
Di-n-octylphthalate ND ug/L 02/23/23 14:32 117-84-002/22/23 14:174.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/23 14:32 117-81-702/22/23 14:174.2 1
Fluoranthene ND ug/L 02/23/23 14:32 206-44-002/22/23 14:174.2 1
Fluorene ND ug/L 02/23/23 14:32 86-73-702/22/23 14:174.2 1
Hexachloro-1,3-butadiene ND ug/L 02/23/23 14:32 87-68-302/22/23 14:174.2 1
Hexachlorobenzene ND ug/L 02/23/23 14:32 118-74-102/22/23 14:174.2 1
Hexachlorocyclopentadiene ND ug/L 02/23/23 14:32 77-47-402/22/23 14:178.3 1
Hexachloroethane ND ug/L 02/23/23 14:32 67-72-102/22/23 14:174.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/23 14:32 193-39-502/22/23 14:174.2 1
Isophorone ND ug/L 02/23/23 14:32 78-59-102/22/23 14:178.3 1
Naphthalene ND ug/L 02/23/23 14:32 91-20-302/22/23 14:174.2 1
Nitrobenzene ND ug/L 02/23/23 14:32 98-95-302/22/23 14:174.2 1
2-Nitrophenol ND ug/L 02/23/23 14:32 88-75-502/22/23 14:174.2 1
4-Nitrophenol ND ug/L 02/23/23 14:32 100-02-702/22/23 14:178.3 1
N-Nitrosodimethylamine ND ug/L 02/23/23 14:32 62-75-902/22/23 14:174.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/23 14:32 621-64-702/22/23 14:174.2 1
N-Nitrosodiphenylamine ND ug/L 02/23/23 14:32 86-30-602/22/23 14:178.3 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/23/23 14:32 108-60-102/22/23 14:174.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-6 Lab ID:92652903004 Collected:02/16/23 10:18 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 02/23/23 14:32 87-86-502/22/23 14:178.3 1
Phenanthrene ND ug/L 02/23/23 14:32 85-01-802/22/23 14:174.2 1
Phenol ND ug/L 02/23/23 14:32 108-95-202/22/23 14:174.2 1
Pyrene ND ug/L 02/23/23 14:32 129-00-0 L102/22/23 14:174.2 1
1,2,4-Trichlorobenzene ND ug/L 02/23/23 14:32 120-82-102/22/23 14:174.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/23 14:32 88-06-202/22/23 14:178.3 1
Surrogates
Nitrobenzene-d5 (S)121 %02/23/23 14:32 4165-60-0 S302/22/23 14:1710-120 1
2-Fluorobiphenyl (S)95 %02/23/23 14:32 321-60-802/22/23 14:1715-120 1
Terphenyl-d14 (S)117 %02/23/23 14:32 1718-51-002/22/23 14:1711-131 1
Phenol-d6 (S)68 %02/23/23 14:32 13127-88-302/22/23 14:1710-120 1
2-Fluorophenol (S)76 %02/23/23 14:32 367-12-402/22/23 14:1710-120 1
2,4,6-Tribromophenol (S)104 %02/23/23 14:32 118-79-602/22/23 14:1710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 02/21/23 15:56 71-43-20.50 1
Bromobenzene ND ug/L 02/21/23 15:56 108-86-10.50 1
Bromochloromethane ND ug/L 02/21/23 15:56 74-97-50.50 1
Bromodichloromethane ND ug/L 02/21/23 15:56 75-27-40.50 1
Bromoform ND ug/L 02/21/23 15:56 75-25-20.50 1
Bromomethane ND ug/L 02/21/23 15:56 74-83-95.0 1
n-Butylbenzene ND ug/L 02/21/23 15:56 104-51-80.50 1
sec-Butylbenzene ND ug/L 02/21/23 15:56 135-98-80.50 1
tert-Butylbenzene ND ug/L 02/21/23 15:56 98-06-60.50 1
Carbon tetrachloride ND ug/L 02/21/23 15:56 56-23-50.50 1
Chlorobenzene ND ug/L 02/21/23 15:56 108-90-70.50 1
Chloroethane ND ug/L 02/21/23 15:56 75-00-31.0 1
Chloroform ND ug/L 02/21/23 15:56 67-66-30.50 1
Chloromethane ND ug/L 02/21/23 15:56 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/21/23 15:56 95-49-80.50 1
4-Chlorotoluene ND ug/L 02/21/23 15:56 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/23 15:56 96-12-81.0 1
Dibromochloromethane ND ug/L 02/21/23 15:56 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/23 15:56 106-93-40.50 1
Dibromomethane ND ug/L 02/21/23 15:56 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 02/21/23 15:56 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 02/21/23 15:56 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 02/21/23 15:56 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 02/21/23 15:56 75-71-80.50 1
1,1-Dichloroethane ND ug/L 02/21/23 15:56 75-34-30.50 1
1,2-Dichloroethane ND ug/L 02/21/23 15:56 107-06-20.50 1
1,1-Dichloroethene ND ug/L 02/21/23 15:56 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 02/21/23 15:56 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 02/21/23 15:56 156-60-50.50 1
1,2-Dichloropropane ND ug/L 02/21/23 15:56 78-87-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-6 Lab ID:92652903004 Collected:02/16/23 10:18 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 02/21/23 15:56 142-28-90.50 1
2,2-Dichloropropane ND ug/L 02/21/23 15:56 594-20-70.50 1
1,1-Dichloropropene ND ug/L 02/21/23 15:56 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 02/21/23 15:56 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 02/21/23 15:56 10061-02-60.50 1
Diisopropyl ether ND ug/L 02/21/23 15:56 108-20-30.50 1
Ethylbenzene ND ug/L 02/21/23 15:56 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 02/21/23 15:56 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 02/21/23 15:56 98-82-80.50 1
Methylene Chloride ND ug/L 02/21/23 15:56 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 02/21/23 15:56 1634-04-40.50 1
Naphthalene ND ug/L 02/21/23 15:56 91-20-32.0 1
n-Propylbenzene ND ug/L 02/21/23 15:56 103-65-10.50 1
Styrene ND ug/L 02/21/23 15:56 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/23 15:56 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/23 15:56 79-34-50.50 1
Tetrachloroethene ND ug/L 02/21/23 15:56 127-18-40.50 1
Toluene ND ug/L 02/21/23 15:56 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 02/21/23 15:56 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 02/21/23 15:56 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 02/21/23 15:56 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 02/21/23 15:56 79-00-50.50 1
Trichloroethene ND ug/L 02/21/23 15:56 79-01-60.50 1
Trichlorofluoromethane ND ug/L 02/21/23 15:56 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/21/23 15:56 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 02/21/23 15:56 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 02/21/23 15:56 108-67-80.50 1
Vinyl chloride ND ug/L 02/21/23 15:56 75-01-41.0 1
m&p-Xylene ND ug/L 02/21/23 15:56 179601-23-11.0 1
o-Xylene ND ug/L 02/21/23 15:56 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)91 %02/21/23 15:56 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %02/21/23 15:56 460-00-470-130 1
Toluene-d8 (S)100 %02/21/23 15:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-7 Lab ID:92652903005 Collected:02/16/23 08:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/23/23 14:57 83-32-902/22/23 14:174.2 1
Acenaphthylene ND ug/L 02/23/23 14:57 208-96-802/22/23 14:174.2 1
Anthracene ND ug/L 02/23/23 14:57 120-12-702/22/23 14:174.2 1
Benzo(a)anthracene ND ug/L 02/23/23 14:57 56-55-302/22/23 14:174.2 1
Benzo(a)pyrene ND ug/L 02/23/23 14:57 50-32-802/22/23 14:174.2 1
Benzo(b)fluoranthene ND ug/L 02/23/23 14:57 205-99-202/22/23 14:174.2 1
Benzo(g,h,i)perylene ND ug/L 02/23/23 14:57 191-24-202/22/23 14:174.2 1
Benzo(k)fluoranthene ND ug/L 02/23/23 14:57 207-08-902/22/23 14:174.2 1
4-Bromophenylphenyl ether ND ug/L 02/23/23 14:57 101-55-302/22/23 14:174.2 1
Butylbenzylphthalate ND ug/L 02/23/23 14:57 85-68-702/22/23 14:174.2 1
4-Chloro-3-methylphenol ND ug/L 02/23/23 14:57 59-50-702/22/23 14:174.2 1
bis(2-Chloroethoxy)methane ND ug/L 02/23/23 14:57 111-91-102/22/23 14:178.3 1
bis(2-Chloroethyl) ether ND ug/L 02/23/23 14:57 111-44-402/22/23 14:174.2 1
2-Chloronaphthalene ND ug/L 02/23/23 14:57 91-58-702/22/23 14:174.2 1
2-Chlorophenol ND ug/L 02/23/23 14:57 95-57-802/22/23 14:174.2 1
4-Chlorophenylphenyl ether ND ug/L 02/23/23 14:57 7005-72-302/22/23 14:174.2 1
Chrysene ND ug/L 02/23/23 14:57 218-01-902/22/23 14:174.2 1
Dibenz(a,h)anthracene ND ug/L 02/23/23 14:57 53-70-302/22/23 14:174.2 1
3,3'-Dichlorobenzidine ND ug/L 02/23/23 14:57 91-94-102/22/23 14:178.3 1
2,4-Dichlorophenol ND ug/L 02/23/23 14:57 120-83-202/22/23 14:174.2 1
Diethylphthalate ND ug/L 02/23/23 14:57 84-66-2 L102/22/23 14:174.2 1
2,4-Dimethylphenol ND ug/L 02/23/23 14:57 105-67-9 L102/22/23 14:178.3 1
Dimethylphthalate ND ug/L 02/23/23 14:57 131-11-3 L102/22/23 14:174.2 1
Di-n-butylphthalate ND ug/L 02/23/23 14:57 84-74-2 L102/22/23 14:174.2 1
4,6-Dinitro-2-methylphenol ND ug/L 02/23/23 14:57 534-52-102/22/23 14:178.3 1
2,4-Dinitrophenol ND ug/L 02/23/23 14:57 51-28-502/22/23 14:1741.7 1
2,4-Dinitrotoluene ND ug/L 02/23/23 14:57 121-14-202/22/23 14:174.2 1
2,6-Dinitrotoluene ND ug/L 02/23/23 14:57 606-20-202/22/23 14:174.2 1
Di-n-octylphthalate ND ug/L 02/23/23 14:57 117-84-002/22/23 14:174.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/23/23 14:57 117-81-702/22/23 14:174.2 1
Fluoranthene ND ug/L 02/23/23 14:57 206-44-002/22/23 14:174.2 1
Fluorene ND ug/L 02/23/23 14:57 86-73-702/22/23 14:174.2 1
Hexachloro-1,3-butadiene ND ug/L 02/23/23 14:57 87-68-302/22/23 14:174.2 1
Hexachlorobenzene ND ug/L 02/23/23 14:57 118-74-102/22/23 14:174.2 1
Hexachlorocyclopentadiene ND ug/L 02/23/23 14:57 77-47-402/22/23 14:178.3 1
Hexachloroethane ND ug/L 02/23/23 14:57 67-72-102/22/23 14:174.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/23/23 14:57 193-39-502/22/23 14:174.2 1
Isophorone ND ug/L 02/23/23 14:57 78-59-102/22/23 14:178.3 1
Naphthalene ND ug/L 02/23/23 14:57 91-20-302/22/23 14:174.2 1
Nitrobenzene ND ug/L 02/23/23 14:57 98-95-302/22/23 14:174.2 1
2-Nitrophenol ND ug/L 02/23/23 14:57 88-75-502/22/23 14:174.2 1
4-Nitrophenol ND ug/L 02/23/23 14:57 100-02-702/22/23 14:178.3 1
N-Nitrosodimethylamine ND ug/L 02/23/23 14:57 62-75-902/22/23 14:174.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/23/23 14:57 621-64-702/22/23 14:174.2 1
N-Nitrosodiphenylamine ND ug/L 02/23/23 14:57 86-30-602/22/23 14:178.3 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/23/23 14:57 108-60-102/22/23 14:174.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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Page 16 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-7 Lab ID:92652903005 Collected:02/16/23 08:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Pentachlorophenol ND ug/L 02/23/23 14:57 87-86-502/22/23 14:178.3 1
Phenanthrene ND ug/L 02/23/23 14:57 85-01-802/22/23 14:174.2 1
Phenol ND ug/L 02/23/23 14:57 108-95-202/22/23 14:174.2 1
Pyrene ND ug/L 02/23/23 14:57 129-00-0 L102/22/23 14:174.2 1
1,2,4-Trichlorobenzene ND ug/L 02/23/23 14:57 120-82-102/22/23 14:174.2 1
2,4,6-Trichlorophenol ND ug/L 02/23/23 14:57 88-06-202/22/23 14:178.3 1
Surrogates
Nitrobenzene-d5 (S)120 %02/23/23 14:57 4165-60-002/22/23 14:1710-120 1
2-Fluorobiphenyl (S)94 %02/23/23 14:57 321-60-802/22/23 14:1715-120 1
Terphenyl-d14 (S)107 %02/23/23 14:57 1718-51-002/22/23 14:1711-131 1
Phenol-d6 (S)67 %02/23/23 14:57 13127-88-302/22/23 14:1710-120 1
2-Fluorophenol (S)76 %02/23/23 14:57 367-12-402/22/23 14:1710-120 1
2,4,6-Tribromophenol (S)105 %02/23/23 14:57 118-79-602/22/23 14:1710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 02/21/23 16:14 71-43-20.50 1
Bromobenzene ND ug/L 02/21/23 16:14 108-86-10.50 1
Bromochloromethane ND ug/L 02/21/23 16:14 74-97-50.50 1
Bromodichloromethane ND ug/L 02/21/23 16:14 75-27-40.50 1
Bromoform ND ug/L 02/21/23 16:14 75-25-20.50 1
Bromomethane ND ug/L 02/21/23 16:14 74-83-95.0 1
n-Butylbenzene 0.87 ug/L 02/21/23 16:14 104-51-80.50 1
sec-Butylbenzene ND ug/L 02/21/23 16:14 135-98-80.50 1
tert-Butylbenzene ND ug/L 02/21/23 16:14 98-06-60.50 1
Carbon tetrachloride ND ug/L 02/21/23 16:14 56-23-50.50 1
Chlorobenzene ND ug/L 02/21/23 16:14 108-90-70.50 1
Chloroethane ND ug/L 02/21/23 16:14 75-00-31.0 1
Chloroform 2.8 ug/L 02/21/23 16:14 67-66-30.50 1
Chloromethane ND ug/L 02/21/23 16:14 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/21/23 16:14 95-49-80.50 1
4-Chlorotoluene ND ug/L 02/21/23 16:14 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/23 16:14 96-12-81.0 1
Dibromochloromethane ND ug/L 02/21/23 16:14 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/23 16:14 106-93-40.50 1
Dibromomethane ND ug/L 02/21/23 16:14 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 02/21/23 16:14 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 02/21/23 16:14 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 02/21/23 16:14 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 02/21/23 16:14 75-71-80.50 1
1,1-Dichloroethane ND ug/L 02/21/23 16:14 75-34-30.50 1
1,2-Dichloroethane ND ug/L 02/21/23 16:14 107-06-20.50 1
1,1-Dichloroethene ND ug/L 02/21/23 16:14 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 02/21/23 16:14 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 02/21/23 16:14 156-60-50.50 1
1,2-Dichloropropane ND ug/L 02/21/23 16:14 78-87-50.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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[phone]
Page 17 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Sample:MW-7 Lab ID:92652903005 Collected:02/16/23 08:00 Received:02/17/23 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,3-Dichloropropane ND ug/L 02/21/23 16:14 142-28-90.50 1
2,2-Dichloropropane ND ug/L 02/21/23 16:14 594-20-70.50 1
1,1-Dichloropropene ND ug/L 02/21/23 16:14 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 02/21/23 16:14 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 02/21/23 16:14 10061-02-60.50 1
Diisopropyl ether ND ug/L 02/21/23 16:14 108-20-30.50 1
Ethylbenzene ND ug/L 02/21/23 16:14 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 02/21/23 16:14 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 02/21/23 16:14 98-82-80.50 1
Methylene Chloride ND ug/L 02/21/23 16:14 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 02/21/23 16:14 1634-04-40.50 1
Naphthalene ND ug/L 02/21/23 16:14 91-20-32.0 1
n-Propylbenzene ND ug/L 02/21/23 16:14 103-65-10.50 1
Styrene ND ug/L 02/21/23 16:14 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/23 16:14 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/23 16:14 79-34-50.50 1
Tetrachloroethene ND ug/L 02/21/23 16:14 127-18-40.50 1
Toluene ND ug/L 02/21/23 16:14 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 02/21/23 16:14 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 02/21/23 16:14 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 02/21/23 16:14 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 02/21/23 16:14 79-00-50.50 1
Trichloroethene ND ug/L 02/21/23 16:14 79-01-60.50 1
Trichlorofluoromethane ND ug/L 02/21/23 16:14 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/21/23 16:14 96-18-40.50 1
1,2,4-Trimethylbenzene 1.0 ug/L 02/21/23 16:14 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 02/21/23 16:14 108-67-80.50 1
Vinyl chloride ND ug/L 02/21/23 16:14 75-01-41.0 1
m&p-Xylene ND ug/L 02/21/23 16:14 179601-23-11.0 1
o-Xylene ND ug/L 02/21/23 16:14 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %02/21/23 16:14 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %02/21/23 16:14 460-00-470-130 1
Toluene-d8 (S)105 %02/21/23 16:14 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
756934
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92652903002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3932440
Associated Lab Samples:92652903002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/20/23 12:31
1,1,1-Trichloroethane ug/L ND 0.50 02/20/23 12:31
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/20/23 12:31
1,1,2-Trichloroethane ug/L ND 0.50 02/20/23 12:31
1,1-Dichloroethane ug/L ND 0.50 02/20/23 12:31
1,1-Dichloroethene ug/L ND 0.50 02/20/23 12:31
1,1-Dichloropropene ug/L ND 0.50 02/20/23 12:31
1,2,3-Trichlorobenzene ug/L ND 2.0 02/20/23 12:31
1,2,3-Trichloropropane ug/L ND 0.50 02/20/23 12:31
1,2,4-Trichlorobenzene ug/L ND 2.0 02/20/23 12:31
1,2,4-Trimethylbenzene ug/L ND 0.50 02/20/23 12:31
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/20/23 12:31
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/20/23 12:31
1,2-Dichlorobenzene ug/L ND 0.50 02/20/23 12:31
1,2-Dichloroethane ug/L ND 0.50 02/20/23 12:31
1,2-Dichloropropane ug/L ND 0.50 02/20/23 12:31
1,3,5-Trimethylbenzene ug/L ND 0.50 02/20/23 12:31
1,3-Dichlorobenzene ug/L ND 0.50 02/20/23 12:31
1,3-Dichloropropane ug/L ND 0.50 02/20/23 12:31
1,4-Dichlorobenzene ug/L ND 0.50 02/20/23 12:31
2,2-Dichloropropane ug/L ND 0.50 02/20/23 12:31
2-Chlorotoluene ug/L ND 0.50 02/20/23 12:31
4-Chlorotoluene ug/L ND 0.50 02/20/23 12:31
Benzene ug/L ND 0.50 02/20/23 12:31
Bromobenzene ug/L ND 0.50 02/20/23 12:31
Bromochloromethane ug/L ND 0.50 02/20/23 12:31
Bromodichloromethane ug/L ND 0.50 02/20/23 12:31
Bromoform ug/L ND 0.50 02/20/23 12:31
Bromomethane ug/L ND 5.0 02/20/23 12:31
Carbon tetrachloride ug/L ND 0.50 02/20/23 12:31
Chlorobenzene ug/L ND 0.50 02/20/23 12:31
Chloroethane ug/L ND 1.0 02/20/23 12:31
Chloroform ug/L ND 0.50 02/20/23 12:31
Chloromethane ug/L ND 1.0 02/20/23 12:31
cis-1,2-Dichloroethene ug/L ND 0.50 02/20/23 12:31
cis-1,3-Dichloropropene ug/L ND 0.50 02/20/23 12:31
Dibromochloromethane ug/L ND 0.50 02/20/23 12:31
Dibromomethane ug/L ND 0.50 02/20/23 12:31
Dichlorodifluoromethane ug/L ND 0.50 02/20/23 12:31
Diisopropyl ether ug/L ND 0.50 02/20/23 12:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3932440
Associated Lab Samples:92652903002
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 02/20/23 12:31
Hexachloro-1,3-butadiene ug/L ND 2.0 02/20/23 12:31
Isopropylbenzene (Cumene)ug/L ND 0.50 02/20/23 12:31
m&p-Xylene ug/L ND 1.0 02/20/23 12:31
Methyl-tert-butyl ether ug/L ND 0.50 02/20/23 12:31
Methylene Chloride ug/L ND 2.0 02/20/23 12:31
n-Butylbenzene ug/L ND 0.50 02/20/23 12:31
n-Propylbenzene ug/L ND 0.50 02/20/23 12:31
Naphthalene ug/L ND 2.0 02/20/23 12:31
o-Xylene ug/L ND 0.50 02/20/23 12:31
sec-Butylbenzene ug/L ND 0.50 02/20/23 12:31
Styrene ug/L ND 0.50 02/20/23 12:31
tert-Butylbenzene ug/L ND 0.50 02/20/23 12:31
Tetrachloroethene ug/L ND 0.50 02/20/23 12:31
Toluene ug/L ND 0.50 02/20/23 12:31
trans-1,2-Dichloroethene ug/L ND 0.50 02/20/23 12:31
trans-1,3-Dichloropropene ug/L ND 0.50 02/20/23 12:31
Trichloroethene ug/L ND 0.50 02/20/23 12:31
Trichlorofluoromethane ug/L ND 1.0 02/20/23 12:31
Vinyl chloride ug/L ND 1.0 02/20/23 12:31
1,2-Dichloroethane-d4 (S)%93 70-130 02/20/23 12:31
4-Bromofluorobenzene (S)%97 70-130 02/20/23 12:31
Toluene-d8 (S)%102 70-130 02/20/23 12:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3932441LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.620 98 60-140
1,1,1-Trichloroethane ug/L 16.620 83 60-140
1,1,2,2-Tetrachloroethane ug/L 19.720 98 60-140
1,1,2-Trichloroethane ug/L 17.520 87 60-140
1,1-Dichloroethane ug/L 16.220 81 60-140
1,1-Dichloroethene ug/L 17.520 87 60-140
1,1-Dichloropropene ug/L 18.320 91 60-140
1,2,3-Trichlorobenzene ug/L 20.120 100 60-140
1,2,3-Trichloropropane ug/L 18.520 92 60-140
1,2,4-Trichlorobenzene ug/L 20.720 104 60-140
1,2,4-Trimethylbenzene ug/L 19.820 99 60-140
1,2-Dibromo-3-chloropropane ug/L 19.120 95 60-140
1,2-Dibromoethane (EDB)ug/L 19.020 95 60-140
1,2-Dichlorobenzene ug/L 20.520 103 60-140
1,2-Dichloroethane ug/L 16.720 84 60-140
1,2-Dichloropropane ug/L 17.720 89 60-140
1,3,5-Trimethylbenzene ug/L 20.520 103 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3932441LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.720 103 60-140
1,3-Dichloropropane ug/L 19.820 99 60-140
1,4-Dichlorobenzene ug/L 19.620 98 60-140
2,2-Dichloropropane ug/L 16.920 85 60-140
2-Chlorotoluene ug/L 20.320 101 60-140
4-Chlorotoluene ug/L 20.420 102 60-140
Benzene ug/L 16.620 83 60-140
Bromobenzene ug/L 19.920 100 60-140
Bromochloromethane ug/L 16.620 83 60-140
Bromodichloromethane ug/L 17.420 87 60-140
Bromoform ug/L 18.520 92 60-140
Bromomethane ug/L 13.520 67 60-140
Carbon tetrachloride ug/L 18.020 90 60-140
Chlorobenzene ug/L 19.420 97 60-140
Chloroethane ug/L 18.520 93 60-140
Chloroform ug/L 16.420 82 60-140
Chloromethane ug/L 16.420 82 60-140
cis-1,2-Dichloroethene ug/L 16.820 84 60-140
cis-1,3-Dichloropropene ug/L 18.320 91 60-140
Dibromochloromethane ug/L 19.120 96 60-140
Dibromomethane ug/L 17.120 86 60-140
Dichlorodifluoromethane ug/L 14.620 73 60-140
Diisopropyl ether ug/L 17.220 86 60-140
Ethylbenzene ug/L 19.420 97 60-140
Hexachloro-1,3-butadiene ug/L 20.220 101 60-140
Isopropylbenzene (Cumene)ug/L 19.120 95 60-140
m&p-Xylene ug/L 39.140 98 60-140
Methyl-tert-butyl ether ug/L 15.920 80 60-140
Methylene Chloride ug/L 16.920 85 60-140
n-Butylbenzene ug/L 21.220 106 60-140
n-Propylbenzene ug/L 20.220 101 60-140
Naphthalene ug/L 20.920 105 60-140
o-Xylene ug/L 19.420 97 60-140
sec-Butylbenzene ug/L 20.920 104 60-140
Styrene ug/L 19.320 96 60-140
tert-Butylbenzene ug/L 16.920 85 60-140
Tetrachloroethene ug/L 18.120 91 60-140
Toluene ug/L 16.820 84 60-140
trans-1,2-Dichloroethene ug/L 17.520 88 60-140
trans-1,3-Dichloropropene ug/L 17.520 88 60-140
Trichloroethene ug/L 18.420 92 60-140
Trichlorofluoromethane ug/L 16.320 82 60-140
Vinyl chloride ug/L 17.320 86 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
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[phone]
Page 21 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3932442MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92652832007
3932443
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 113 60-14096 1620ND22.6 19.2
1,1,1-Trichloroethane ug/L 20 106 60-14090 1720ND21.2 18.0
1,1,2,2-Tetrachloroethane ug/L 20 112 60-14094 1720ND22.4 18.8
1,1,2-Trichloroethane ug/L 20 104 60-14091 1320ND20.7 18.2
1,1-Dichloroethane ug/L 20 103 60-14091 1320ND20.7 18.2
1,1-Dichloroethene ug/L 20 110 60-14098 1220ND21.9 19.5
1,1-Dichloropropene ug/L 20 111 60-14095 1620ND22.3 18.9
1,2,3-Trichlorobenzene ug/L 20 135 60-140107 2320ND27.1 21.5
1,2,3-Trichloropropane ug/L 20 108 60-14091 1720ND21.6 18.2
1,2,4-Trichlorobenzene ug/L 20 139 60-140116 1820ND27.8 23.2
1,2,4-Trimethylbenzene ug/L 20 125 60-140106 1720ND25.0 21.1
1,2-Dibromo-3-chloropropane ug/L 20 105 60-14089 1720ND21.1 17.8
1,2-Dibromoethane (EDB)ug/L 20 110 60-14095 1520ND22.0 19.0
1,2-Dichlorobenzene ug/L 20 121 60-140103 1620ND24.2 20.7
1,2-Dichloroethane ug/L 20 101 60-14086 1520ND20.2 17.3
1,2-Dichloropropane ug/L 20 109 60-14094 1520ND21.9 18.8
1,3,5-Trimethylbenzene ug/L 20 132 60-140109 1920ND26.4 21.9
1,3-Dichlorobenzene ug/L 20 126 60-140105 1820ND25.2 21.0
1,3-Dichloropropane ug/L 20 113 60-14096 1620ND22.6 19.2
1,4-Dichlorobenzene ug/L 20 121 60-140101 1820ND24.2 20.2
2,2-Dichloropropane ug/L 20 105 60-14091 1520ND21.1 18.1
2-Chlorotoluene ug/L 20 123 60-140104 1720ND24.5 20.7
4-Chlorotoluene ug/L 20 126 60-140107 1620ND25.2 21.4
Benzene ug/L 20 106 60-14091 1520ND21.1 18.2
Bromobenzene ug/L 20 116 60-140100 1520ND23.2 20.0
Bromochloromethane ug/L 20 102 60-14087 1620ND20.3 17.3
Bromodichloromethane ug/L 20 104 60-14092 1220ND20.8 18.4
Bromoform ug/L 20 104 60-14087 1820ND20.8 17.3
Bromomethane ug/L 20 87 60-14080 920ND17.4 16.0
Carbon tetrachloride ug/L 20 115 60-14098 1520ND23.0 19.7
Chlorobenzene ug/L 20 116 60-140100 1520ND23.2 20.0
Chloroethane ug/L 20 124 60-140109 1320ND24.8 21.9
Chloroform ug/L 20 100 60-14087 1420ND20.1 17.5
Chloromethane ug/L 20 104 60-14090 1420ND20.8 18.1
cis-1,2-Dichloroethene ug/L 20 106 60-14091 1520ND21.1 18.1
cis-1,3-Dichloropropene ug/L 20 107 60-14091 1620ND21.3 18.1
Dibromochloromethane ug/L 20 109 60-14093 1620ND21.7 18.6
Dibromomethane ug/L 20 103 60-14089 1520ND20.6 17.8
Dichlorodifluoromethane ug/L 20 78 60-14070 1120ND15.6 14.0
Diisopropyl ether ug/L 20 103 60-14085 1920ND20.5 16.9
Ethylbenzene ug/L 20 119 60-140101 1720ND23.9 20.1
Hexachloro-1,3-butadiene ug/L M12017660-140141 2220ND35.3 28.3
Isopropylbenzene (Cumene)ug/L 20 122 60-140102 1720ND24.3 20.5
m&p-Xylene ug/L 40 118 60-140100 1740ND47.4 40.0
Methyl-tert-butyl ether ug/L 20 102 60-14087 13205.4 25.8 22.7
Methylene Chloride ug/L 20 102 60-14089 1420ND20.4 17.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3932442MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92652832007
3932443
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M12015960-140132 1920ND31.8 26.4
n-Propylbenzene ug/L 20 129 60-140109 1720ND25.8 21.7
Naphthalene ug/L 20 119 60-14098 1920ND23.8 19.7
o-Xylene ug/L 20 119 60-140100 1720ND23.8 20.0
sec-Butylbenzene ug/L M12014760-140123 1820ND29.4 24.5
Styrene ug/L 20 116 60-140100 1520ND23.3 20.0
tert-Butylbenzene ug/L 20 114 60-14093 2020ND22.8 18.7
Tetrachloroethene ug/L 20 111 60-14092 1820ND22.1 18.4
Toluene ug/L 20 103 60-14091 1320ND20.6 18.2
trans-1,2-Dichloroethene ug/L 20 113 60-14095 1720ND22.5 19.0
trans-1,3-Dichloropropene ug/L 20 103 60-14090 1320ND20.6 18.1
Trichloroethene ug/L 20 114 60-14099 1320ND22.7 19.9
Trichlorofluoromethane ug/L 20 105 60-14092 1420ND21.0 18.3
Vinyl chloride ug/L 20 110 60-14098 1120ND22.0 19.7
1,2-Dichloroethane-d4 (S)%95 70-13092
4-Bromofluorobenzene (S)%97 70-13096
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
757145
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92652903001, 92652903003, 92652903004, 92652903005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3933266
Associated Lab Samples:92652903001, 92652903003, 92652903004, 92652903005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/21/23 11:11
1,1,1-Trichloroethane ug/L ND 0.50 02/21/23 11:11
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/21/23 11:11
1,1,2-Trichloroethane ug/L ND 0.50 02/21/23 11:11
1,1-Dichloroethane ug/L ND 0.50 02/21/23 11:11
1,1-Dichloroethene ug/L ND 0.50 02/21/23 11:11
1,1-Dichloropropene ug/L ND 0.50 02/21/23 11:11
1,2,3-Trichlorobenzene ug/L ND 2.0 02/21/23 11:11
1,2,3-Trichloropropane ug/L ND 0.50 02/21/23 11:11
1,2,4-Trichlorobenzene ug/L ND 2.0 02/21/23 11:11
1,2,4-Trimethylbenzene ug/L ND 0.50 02/21/23 11:11
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/21/23 11:11
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/21/23 11:11
1,2-Dichlorobenzene ug/L ND 0.50 02/21/23 11:11
1,2-Dichloroethane ug/L ND 0.50 02/21/23 11:11
1,2-Dichloropropane ug/L ND 0.50 02/21/23 11:11
1,3,5-Trimethylbenzene ug/L ND 0.50 02/21/23 11:11
1,3-Dichlorobenzene ug/L ND 0.50 02/21/23 11:11
1,3-Dichloropropane ug/L ND 0.50 02/21/23 11:11
1,4-Dichlorobenzene ug/L ND 0.50 02/21/23 11:11
2,2-Dichloropropane ug/L ND 0.50 02/21/23 11:11
2-Chlorotoluene ug/L ND 0.50 02/21/23 11:11
4-Chlorotoluene ug/L ND 0.50 02/21/23 11:11
Benzene ug/L ND 0.50 02/21/23 11:11
Bromobenzene ug/L ND 0.50 02/21/23 11:11
Bromochloromethane ug/L ND 0.50 02/21/23 11:11
Bromodichloromethane ug/L ND 0.50 02/21/23 11:11
Bromoform ug/L ND 0.50 02/21/23 11:11
Bromomethane ug/L ND 5.0 02/21/23 11:11
Carbon tetrachloride ug/L ND 0.50 02/21/23 11:11
Chlorobenzene ug/L ND 0.50 02/21/23 11:11
Chloroethane ug/L ND 1.0 02/21/23 11:11
Chloroform ug/L ND 0.50 02/21/23 11:11
Chloromethane ug/L ND 1.0 02/21/23 11:11
cis-1,2-Dichloroethene ug/L ND 0.50 02/21/23 11:11
cis-1,3-Dichloropropene ug/L ND 0.50 02/21/23 11:11
Dibromochloromethane ug/L ND 0.50 02/21/23 11:11
Dibromomethane ug/L ND 0.50 02/21/23 11:11
Dichlorodifluoromethane ug/L ND 0.50 02/21/23 11:11
Diisopropyl ether ug/L ND 0.50 02/21/23 11:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3933266
Associated Lab Samples:92652903001, 92652903003, 92652903004, 92652903005
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 02/21/23 11:11
Hexachloro-1,3-butadiene ug/L ND 2.0 02/21/23 11:11
Isopropylbenzene (Cumene)ug/L ND 0.50 02/21/23 11:11
m&p-Xylene ug/L ND 1.0 02/21/23 11:11
Methyl-tert-butyl ether ug/L ND 0.50 02/21/23 11:11
Methylene Chloride ug/L ND 2.0 02/21/23 11:11
n-Butylbenzene ug/L ND 0.50 02/21/23 11:11
n-Propylbenzene ug/L ND 0.50 02/21/23 11:11
Naphthalene ug/L ND 2.0 02/21/23 11:11
o-Xylene ug/L ND 0.50 02/21/23 11:11
sec-Butylbenzene ug/L ND 0.50 02/21/23 11:11
Styrene ug/L ND 0.50 02/21/23 11:11
tert-Butylbenzene ug/L ND 0.50 02/21/23 11:11
Tetrachloroethene ug/L ND 0.50 02/21/23 11:11
Toluene ug/L ND 0.50 02/21/23 11:11
trans-1,2-Dichloroethene ug/L ND 0.50 02/21/23 11:11
trans-1,3-Dichloropropene ug/L ND 0.50 02/21/23 11:11
Trichloroethene ug/L ND 0.50 02/21/23 11:11
Trichlorofluoromethane ug/L ND 1.0 02/21/23 11:11
Vinyl chloride ug/L ND 1.0 02/21/23 11:11
1,2-Dichloroethane-d4 (S)%91 70-130 02/21/23 11:11
4-Bromofluorobenzene (S)%98 70-130 02/21/23 11:11
Toluene-d8 (S)%102 70-130 02/21/23 11:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3933267LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 18.420 92 60-140
1,1,1-Trichloroethane ug/L 17.420 87 60-140
1,1,2,2-Tetrachloroethane ug/L 19.020 95 60-140
1,1,2-Trichloroethane ug/L 17.520 87 60-140
1,1-Dichloroethane ug/L 17.520 87 60-140
1,1-Dichloroethene ug/L 19.020 95 60-140
1,1-Dichloropropene ug/L 18.520 93 60-140
1,2,3-Trichlorobenzene ug/L 19.320 96 60-140
1,2,3-Trichloropropane ug/L 18.220 91 60-140
1,2,4-Trichlorobenzene ug/L 19.720 98 60-140
1,2,4-Trimethylbenzene ug/L 19.620 98 60-140
1,2-Dibromo-3-chloropropane ug/L 18.320 92 60-140
1,2-Dibromoethane (EDB)ug/L 18.920 94 60-140
1,2-Dichlorobenzene ug/L 20.020 100 60-140
1,2-Dichloroethane ug/L 17.220 86 60-140
1,2-Dichloropropane ug/L 18.720 94 60-140
1,3,5-Trimethylbenzene ug/L 20.120 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 25 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3933267LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 20.220 101 60-140
1,3-Dichloropropane ug/L 19.020 95 60-140
1,4-Dichlorobenzene ug/L 19.220 96 60-140
2,2-Dichloropropane ug/L 17.320 87 60-140
2-Chlorotoluene ug/L 19.520 97 60-140
4-Chlorotoluene ug/L 19.920 99 60-140
Benzene ug/L 17.820 89 60-140
Bromobenzene ug/L 19.520 97 60-140
Bromochloromethane ug/L 17.420 87 60-140
Bromodichloromethane ug/L 17.620 88 60-140
Bromoform ug/L 17.420 87 60-140
Bromomethane ug/L 16.220 81 60-140
Carbon tetrachloride ug/L 18.720 93 60-140
Chlorobenzene ug/L 19.220 96 60-140
Chloroethane ug/L 21.320 106 60-140
Chloroform ug/L 16.920 84 60-140
Chloromethane ug/L 19.520 98 60-140
cis-1,2-Dichloroethene ug/L 17.720 88 60-140
cis-1,3-Dichloropropene ug/L 18.220 91 60-140
Dibromochloromethane ug/L 18.320 91 60-140
Dibromomethane ug/L 17.520 88 60-140
Dichlorodifluoromethane ug/L 17.820 89 60-140
Diisopropyl ether ug/L 17.120 86 60-140
Ethylbenzene ug/L 19.320 97 60-140
Hexachloro-1,3-butadiene ug/L 19.920 99 60-140
Isopropylbenzene (Cumene)ug/L 18.820 94 60-140
m&p-Xylene ug/L 38.540 96 60-140
Methyl-tert-butyl ether ug/L 16.320 82 60-140
Methylene Chloride ug/L 17.920 89 60-140
n-Butylbenzene ug/L 20.920 104 60-140
n-Propylbenzene ug/L 19.920 99 60-140
Naphthalene ug/L 19.620 98 60-140
o-Xylene ug/L 19.520 97 60-140
sec-Butylbenzene ug/L 20.520 103 60-140
Styrene ug/L 19.320 96 60-140
tert-Butylbenzene ug/L 16.520 83 60-140
Tetrachloroethene ug/L 18.020 90 60-140
Toluene ug/L 17.320 87 60-140
trans-1,2-Dichloroethene ug/L 18.420 92 60-140
trans-1,3-Dichloropropene ug/L 17.820 89 60-140
Trichloroethene ug/L 19.320 97 60-140
Trichlorofluoromethane ug/L 17.920 89 60-140
Vinyl chloride ug/L 19.620 98 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 26 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3933268MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92652899001
3933269
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 113 60-140119 520ND22.7 23.9
1,1,1-Trichloroethane ug/L 20 121 60-140120 120ND24.2 24.0
1,1,2,2-Tetrachloroethane ug/L 20 110 60-140112 220ND22.1 22.5
1,1,2-Trichloroethane ug/L 20 114 60-140110 320ND22.8 22.1
1,1-Dichloroethane ug/L 20 119 60-140115 420ND23.7 22.9
1,1-Dichloroethene ug/L 20 124 60-140124 020ND24.8 24.8
1,1-Dichloropropene ug/L 20 129 60-140126 220ND25.7 25.2
1,2,3-Trichlorobenzene ug/L 20 113 60-140120 520ND22.7 23.9
1,2,3-Trichloropropane ug/L 20 108 60-140109 120ND21.7 21.9
1,2,4-Trichlorobenzene ug/L 20 112 60-140119 520ND22.5 23.7
1,2,4-Trimethylbenzene ug/L 20 114 60-140116 220ND22.7 23.2
1,2-Dibromo-3-chloropropane ug/L 20 111 60-140114 320ND22.2 22.9
1,2-Dibromoethane (EDB)ug/L 20 116 60-140114 220ND23.2 22.8
1,2-Dichlorobenzene ug/L 20 115 60-140115 020ND23.0 23.0
1,2-Dichloroethane ug/L 20 121 60-140119 120ND24.2 23.9
1,2-Dichloropropane ug/L 20 118 60-140118 020ND23.6 23.6
1,3,5-Trimethylbenzene ug/L 20 116 60-140118 120ND23.2 23.5
1,3-Dichlorobenzene ug/L 20 113 60-140116 320ND22.5 23.1
1,3-Dichloropropane ug/L 20 112 60-140115 320ND22.4 23.0
1,4-Dichlorobenzene ug/L 20 109 60-140111 220ND21.7 22.1
2,2-Dichloropropane ug/L 20 122 60-140120 220ND24.4 24.0
2-Chlorotoluene ug/L 20 113 60-140117 320ND22.7 23.3
4-Chlorotoluene ug/L 20 114 60-140117 320ND22.8 23.5
Benzene ug/L 20 117 60-140115 220ND23.3 22.9
Bromobenzene ug/L 20 113 60-140115 120ND22.7 23.0
Bromochloromethane ug/L 20 121 60-140117 320ND24.2 23.5
Bromodichloromethane ug/L 20 108 60-140108 0201.4 23.0 23.1
Bromoform ug/L 20 111 60-140116 420ND22.2 23.1
Bromomethane ug/L 20 96 60-140101 520ND19.2 20.3
Carbon tetrachloride ug/L 20 119 60-140118 020ND23.7 23.6
Chlorobenzene ug/L 20 111 60-140113 220ND22.1 22.6
Chloroethane ug/L 20 106 60-140121 1320ND21.2 24.3
Chloroform ug/L 20 68 60-14063 42011.3 24.9 23.9
Chloromethane ug/L 20 115 60-140107 720ND23.0 21.4
cis-1,2-Dichloroethene ug/L 20 120 60-140120 020ND24.1 24.0
cis-1,3-Dichloropropene ug/L 20 121 60-140117 320ND24.2 23.4
Dibromochloromethane ug/L 20 111 60-140115 420ND22.2 23.0
Dibromomethane ug/L 20 116 60-140115 120ND23.2 23.0
Dichlorodifluoromethane ug/L 20 84 60-14079 620ND16.7 15.7
Diisopropyl ether ug/L 20 113 60-140115 220ND22.6 23.0
Ethylbenzene ug/L 20 113 60-140116 220ND22.6 23.1
Hexachloro-1,3-butadiene ug/L 20 119 60-140121 120ND23.9 24.2
Isopropylbenzene (Cumene)ug/L 20 112 60-140115 320ND22.3 23.1
m&p-Xylene ug/L 40 114 60-140115 140ND45.6 45.8
Methyl-tert-butyl ether ug/L 20 112 60-140110 220ND22.5 22.1
Methylene Chloride ug/L 20 116 60-140112 320ND23.2 22.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 27 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3933268MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92652899001
3933269
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 119 60-140122 320ND23.7 24.5
n-Propylbenzene ug/L 20 115 60-140117 220ND23.0 23.3
Naphthalene ug/L 20 111 60-140119 720ND22.2 23.7
o-Xylene ug/L 20 113 60-140114 020ND22.7 22.8
sec-Butylbenzene ug/L 20 117 60-140121 420ND23.4 24.2
Styrene ug/L 20 115 60-140117 220ND23.0 23.4
tert-Butylbenzene ug/L 20 97 60-14099 220ND19.3 19.8
Tetrachloroethene ug/L 20 108 60-140112 420ND21.6 22.4
Toluene ug/L 20 112 60-140108 320ND22.3 21.7
trans-1,2-Dichloroethene ug/L 20 124 60-140122 220ND24.8 24.3
trans-1,3-Dichloropropene ug/L 20 118 60-140117 120ND23.7 23.4
Trichloroethene ug/L 20 119 60-140117 220ND23.7 23.3
Trichlorofluoromethane ug/L 20 106 60-140110 420ND21.1 22.1
Vinyl chloride ug/L 20 114 60-140106 720ND22.7 21.3
1,2-Dichloroethane-d4 (S)%98 70-13097
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%100 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 28 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
757251
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92652903001, 92652903002, 92652903003, 92652903004, 92652903005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3934004
Associated Lab Samples:92652903001, 92652903002, 92652903003, 92652903004, 92652903005
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 02/22/23 09:40
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 02/22/23 09:40
2,4,6-Trichlorophenol ug/L ND 10.0 02/22/23 09:40
2,4-Dichlorophenol ug/L ND 5.0 02/22/23 09:40
2,4-Dimethylphenol ug/L ND 10.0 02/22/23 09:40
2,4-Dinitrophenol ug/L ND 50.0 02/22/23 09:40
2,4-Dinitrotoluene ug/L ND 5.0 02/22/23 09:40
2,6-Dinitrotoluene ug/L ND 5.0 02/22/23 09:40
2-Chloronaphthalene ug/L ND 5.0 02/22/23 09:40
2-Chlorophenol ug/L ND 5.0 02/22/23 09:40
2-Nitrophenol ug/L ND 5.0 02/22/23 09:40
3,3'-Dichlorobenzidine ug/L ND 10.0 02/22/23 09:40
4,6-Dinitro-2-methylphenol ug/L ND 10.0 02/22/23 09:40
4-Bromophenylphenyl ether ug/L ND 5.0 02/22/23 09:40
4-Chloro-3-methylphenol ug/L ND 5.0 02/22/23 09:40
4-Chlorophenylphenyl ether ug/L ND 5.0 02/22/23 09:40
4-Nitrophenol ug/L ND 10.0 02/22/23 09:40
Acenaphthene ug/L ND 5.0 02/22/23 09:40
Acenaphthylene ug/L ND 5.0 02/22/23 09:40
Anthracene ug/L ND 5.0 02/22/23 09:40
Benzo(a)anthracene ug/L ND 5.0 02/22/23 09:40
Benzo(a)pyrene ug/L ND 5.0 02/22/23 09:40
Benzo(b)fluoranthene ug/L ND 5.0 02/22/23 09:40
Benzo(g,h,i)perylene ug/L ND 5.0 02/22/23 09:40
Benzo(k)fluoranthene ug/L ND 5.0 02/22/23 09:40
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/22/23 09:40
bis(2-Chloroethyl) ether ug/L ND 5.0 02/22/23 09:40
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 02/22/23 09:40
Butylbenzylphthalate ug/L ND 5.0 02/22/23 09:40
Chrysene ug/L ND 5.0 02/22/23 09:40
Di-n-butylphthalate ug/L ND 5.0 02/22/23 09:40
Di-n-octylphthalate ug/L ND 5.0 02/22/23 09:40
Dibenz(a,h)anthracene ug/L ND 5.0 02/22/23 09:40
Diethylphthalate ug/L ND 5.0 02/22/23 09:40
Dimethylphthalate ug/L ND 5.0 02/22/23 09:40
Fluoranthene ug/L ND 5.0 02/22/23 09:40
Fluorene ug/L ND 5.0 02/22/23 09:40
Hexachloro-1,3-butadiene ug/L ND 5.0 02/22/23 09:40
Hexachlorobenzene ug/L ND 5.0 02/22/23 09:40
Hexachlorocyclopentadiene ug/L ND 10.0 02/22/23 09:40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3934004
Associated Lab Samples:92652903001, 92652903002, 92652903003, 92652903004, 92652903005
Matrix:Water
Analyzed
Hexachloroethane ug/L ND 5.0 02/22/23 09:40
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 02/22/23 09:40
Isophorone ug/L ND 10.0 02/22/23 09:40
N-Nitroso-di-n-propylamine ug/L ND 5.0 02/22/23 09:40
N-Nitrosodimethylamine ug/L ND 5.0 02/22/23 09:40
N-Nitrosodiphenylamine ug/L ND 10.0 02/22/23 09:40
Naphthalene ug/L ND 5.0 02/22/23 09:40
Nitrobenzene ug/L ND 5.0 02/22/23 09:40
Pentachlorophenol ug/L ND 10.0 02/22/23 09:40
Phenanthrene ug/L ND 5.0 02/22/23 09:40
Phenol ug/L ND 5.0 02/22/23 09:40
Pyrene ug/L ND 5.0 02/22/23 09:40
2,4,6-Tribromophenol (S)%113 10-137 02/22/23 09:40
2-Fluorobiphenyl (S)%93 15-120 02/22/23 09:40
2-Fluorophenol (S)%78 10-120 02/22/23 09:40
Nitrobenzene-d5 (S)%117 10-120 02/22/23 09:40
Phenol-d6 (S)%70 10-120 02/22/23 09:40
Terphenyl-d14 (S)%123 11-131 02/22/23 09:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3934005LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 37.750 75 44-142
2,2'-Oxybis(1-chloropropane)ug/L 63.250 126 36-166
2,4,6-Trichlorophenol ug/L 60.550 121 37-144
2,4-Dichlorophenol ug/L 59.550 119 1-191
2,4-Dimethylphenol ug/L 77.1 L15015432-119
2,4-Dinitrophenol ug/L 363250 145 1-181
2,4-Dinitrotoluene ug/L 59.150 118 39-139
2,6-Dinitrotoluene ug/L 61.250 122 50-158
2-Chloronaphthalene ug/L 47.050 94 60-118
2-Chlorophenol ug/L 54.450 109 23-134
2-Nitrophenol ug/L 66.450 133 29-182
3,3'-Dichlorobenzidine ug/L 109100 109 1-262
4,6-Dinitro-2-methylphenol ug/L 153100 153 1-181
4-Bromophenylphenyl ether ug/L 55.550 111 53-127
4-Chloro-3-methylphenol ug/L 127100 127 22-147
4-Chlorophenylphenyl ether ug/L 51.850 104 25-158
4-Nitrophenol ug/L 184250 74 1-132
Acenaphthene ug/L 53.550 107 47-145
Acenaphthylene ug/L 54.050 108 33-145
Anthracene ug/L 52.150 104 1-166
Benzo(a)anthracene ug/L 57.050 114 33-143
Benzo(a)pyrene ug/L 55.650 111 17-163
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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Page 30 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3934005LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 58.050 116 24-159
Benzo(g,h,i)perylene ug/L 48.450 97 1-219
Benzo(k)fluoranthene ug/L 55.950 112 11-162
bis(2-Chloroethoxy)methane ug/L 64.050 128 33-184
bis(2-Chloroethyl) ether ug/L 63.150 126 12-158
bis(2-Ethylhexyl)phthalate ug/L 68.750 137 8-158
Butylbenzylphthalate ug/L 74.750 149 1-152
Chrysene ug/L 54.550 109 17-168
Di-n-butylphthalate ug/L 62.6 L1501251-118
Di-n-octylphthalate ug/L 72.650 145 4-146
Dibenz(a,h)anthracene ug/L 49.550 99 1-227
Diethylphthalate ug/L 60.0 L1501201-114
Dimethylphthalate ug/L 56.9 L1501141-112
Fluoranthene ug/L 54.650 109 26-137
Fluorene ug/L 52.750 105 59-121
Hexachloro-1,3-butadiene ug/L 35.150 70 24-116
Hexachlorobenzene ug/L 51.350 103 1-152
Hexachlorocyclopentadiene ug/L 40.650 81 25-150
Hexachloroethane ug/L 32.250 64 40-113
Indeno(1,2,3-cd)pyrene ug/L 49.750 99 1-171
Isophorone ug/L 68.350 137 21-196
N-Nitroso-di-n-propylamine ug/L 73.650 147 1-230
N-Nitrosodimethylamine ug/L 71.250 142 25-150
N-Nitrosodiphenylamine ug/L 59.050 118 25-150
Naphthalene ug/L 49.750 99 21-133
Nitrobenzene ug/L 59.250 118 35-180
Pentachlorophenol ug/L 117100 117 14-176
Phenanthrene ug/L 55.350 111 54-120
Phenol ug/L 42.050 84 5-112
Pyrene ug/L 63.3 L15012752-115
2,4,6-Tribromophenol (S)%92 10-137
2-Fluorobiphenyl (S)%87 15-120
2-Fluorophenol (S)%72 10-120
Nitrobenzene-d5 (S)%103 10-120
Phenol-d6 (S)%63 10-120
Terphenyl-d14 (S)%99 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3934017MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35780595001
3934018
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L M1503644-14232508.6U 18.2J 15.8J
2,2'-Oxybis(1-chloropropane)ug/L 50 52 36-16654 3505.8U 26.1 26.9
2,4,6-Trichlorophenol ug/L 50 64 37-14461507.8U 31.9J 30.3J
2,4-Dichlorophenol ug/L 50 57 1-19153 7507.0U 28.7 26.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 31 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3934017MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35780595001
3934018
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
2,4-Dimethylphenol ug/L 50 82 32-11978508.5U 41J 38.9J
2,4-Dinitrophenol ug/L 250 63 1-18163250130U157J158J
2,4-Dinitrotoluene ug/L 50 70 39-13967 6508.1U 35.2 33.3
2,6-Dinitrotoluene ug/L 50 62 50-15861 2508.6U 31.2 30.6
2-Chloronaphthalene ug/L M1505460-11850 8508.6U 27.2 25.1
2-Chlorophenol ug/L 50 47 23-13446506.0U 23.6J 22.9J
2-Nitrophenol ug/L 50 59 29-18258 2507.0U 29.6 29.1
3,3'-Dichlorobenzidine ug/L 100 42 1-2623710040.6U 42J ND
4,6-Dinitro-2-methylphenol ug/L 100 80 1-18172 1110038.9U 79.8 71.8
4-Bromophenylphenyl ether ug/L 50 61 53-12759 4508.8U 30.7 29.5
4-Chloro-3-methylphenol ug/L 100 71 22-14770 210016.7U 71.1 69.9
4-Chlorophenylphenyl ether ug/L 50 55 25-15853 35010.0U 27.3 26.4
4-Nitrophenol ug/L 250 46 1-13241 1225033.0U 116 103
Acenaphthene ug/L 50 59 47-14553 95010.0U 29.3 26.7
Acenaphthylene ug/L 50 57 33-14550509.8U 28.3 24.9J
Anthracene ug/L 50 62 1-16659 55011.6U 31.0 29.4
Benzo(a)anthracene ug/L 50 73 33-14370 45013.4U 36.5 35.0
Benzo(a)pyrene ug/L 50 67 17-16368 15013.9U 33.4 33.8
Benzo(b)fluoranthene ug/L 50 69 24-15975 85013.0U 34.5 37.3
Benzo(g,h,i)perylene ug/L 50 59 1-21963 65014.2U 29.6 31.3
Benzo(k)fluoranthene ug/L 50 71 11-16264 105013.6U 35.4 32.2
bis(2-Chloroethoxy)methane ug/L 50 59 33-18455509.1U 29.7J 27.5J
bis(2-Chloroethyl) ether ug/L 50 54 12-15852 4509.6U 27.1 26.1
bis(2-Ethylhexyl)phthalate ug/L 50 87 8-15884 35018.6U 43.6 42.2
Butylbenzylphthalate ug/L 50 96 1-15297 15015.7U 47.9 48.5
Chrysene ug/L 50 71 17-16865 85013.8U 35.3 32.7
Di-n-butylphthalate ug/L 50 83 1-11886 35011.0U 41.7 42.9
Di-n-octylphthalate ug/L 50 88 4-14683 75019.6U 44.2 41.3
Dibenz(a,h)anthracene ug/L 50 56 1-22761 85014.8U 28.2 30.5
Diethylphthalate ug/L 50 69 1-11471 25010.2U 34.6 35.5
Dimethylphthalate ug/L 50 57 1-11254 55010.6U 28.7 27.2
Fluoranthene ug/L 50 68 26-13764 75011.0U 34.1 31.9
Fluorene ug/L M1505759-12154 65010.4U 28.5 26.8
Hexachloro-1,3-butadiene ug/L M1503024-11621508.8U 15J 10.7J
Hexachlorobenzene ug/L 50 59 1-15258 15010.8U 29.3 29.0
Hexachlorocyclopentadiene ug/L M150025-15028508.0U ND 14J
Hexachloroethane ug/L M150040-11314506.9U ND ND
Indeno(1,2,3-cd)pyrene ug/L 50 61 1-17161 05014.4U 30.5 30.6
Isophorone ug/L 50 64 21-19662508.3U 31.8J 31.1J
N-Nitroso-di-n-propylamine ug/L M15001-23066506.6U ND 33.1
N-Nitrosodimethylamine ug/L M150025-15046509.4U ND 23.1J
N-Nitrosodiphenylamine ug/L 50 71 25-150675015.0U 35.5J 33.5J
Naphthalene ug/L 50 45 21-133375010.4U 22.7J 18.4J
Nitrobenzene ug/L 50 60 35-18060 1509.4U 29.9 30.1
Pentachlorophenol ug/L 100 64 14-17666 210018.8U 64.5 65.6
Phenanthrene ug/L 50 68 54-12067 25010.0U 33.8 33.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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[phone]
Page 32 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3934017MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35780595001
3934018
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phenol ug/L 50 25 5-11237 155024.4J 37.1 43.1
Pyrene ug/L 50 82 52-11577 75011.0U 41.0 38.3
2,4,6-Tribromophenol (S)%67 10-13761
2-Fluorobiphenyl (S)%48 15-12039
2-Fluorophenol (S)%41 10-12034
Nitrobenzene-d5 (S)%D35710-12054
Phenol-d6 (S)%39 10-12040
Terphenyl-d14 (S)%77 11-13171
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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[phone]
Page 33 of 38
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Re-extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.1g
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associatedsamples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92652903
BILTMORE OIL- AMBOY ROAD
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92652903001 757251 757388MW-2 EPA 625.1 EPA 625.1
92652903002 757251 757388MW-3 EPA 625.1 EPA 625.1
92652903003 757251 757388MW-4 EPA 625.1 EPA 625.1
92652903004 757251 757388MW-6 EPA 625.1 EPA 625.1
92652903005 757251 757388MW-7 EPA 625.1 EPA 625.1
92652903001 757145MW-2 SM 6200B
92652903002 756934MW-3 SM 6200B
92652903003 757145MW-4 SM 6200B
92652903004 757145MW-6 SM 6200B
92652903005 757145MW-7 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2023 11:52 AM
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Page 35 of 38
Page 36 of 38
Page 37 of 38
Page 38 of 38

Appendix B
Manifest

NON-HAZARDOUS 11.Generator ID Number 12.Page 1 of 13.Emergency Response Phone 14. Waste Tl'acking Number :C WASTE MANIFEST ,, 5. Generator's Name and Mailing Address Generator's Site Address (if different than mailing address)
t
Generator's Phone: I 6. Transporter 1 Company Name U.S. EPA ID Number I 7. Transporter 2 Company Name U.S. EPA ID Number
•·I 8. Designated Facility Name and Site Address U.S. EPA ID Number '
Facilit 's Phone: I I 1 O. Containers 11. Total 12.Unit 9. Waste Shipping Name and Description No. Type Quantity Wt.Nol.1.
w z 2.
·. 3.
4.
13. Special Handling Instructions and Additional Information
14. GENERATOR'S/OFFEROR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked and labeled/placarded, and are in all respects in proper condition for transport according to applicable international and national governmental regulations. Generator's/Offeror's Printed/Typed Name Signature Month Day Year ,, I I I
..J 15. International Shipments D Import to U.S. D Export from U.S . Port of entry/exit: Transporter Sianature (for exoorts onlv): Date leavina U.S.:
a: 16. Transporter Acknowledgment of Receipt of Materialsw Transporter 1 Printed/Typed Name Signature Month Day Year a: I I I I z Transporter 2 Printed/Typed Name Signature Month Day Year a: I I I II-I 17. Discrepancy17a. Discrepancy Indication Space D Quantity □Type D Residue D Partial Rejection D Full Rejection
Manifest Reference Number: >-17b. Alternate Facility (or Generator) U.S. EPA ID Number
I rt Facility's Phone:C 17c. Signature of Alternate Facility (or Generator) Month Day Year w I I I Iz .. .. ·· : .•· w C l ... ''· .. · ·. .··.· 18. Designated Facility Owner or Operator: Certification of receipt of materials covered by the manifest except as noted in Item 17aPrinted/Typed Name Signature Month Day Year I I I I
169-BLC-O 5 11977 (Rev. 9/09)
Brian Bauer
Brian Bauer
Brian Bauer (as agent)Brian Bauer 2 I 16 23
Brian Bauer