AS-3505_28649_CA_CSA_20101031

COMPREHENSIVE SITE ASSESSMENT
Former Cajah’s Mountain Superette
1990 Connelly Springs Road
Lenoir, Caldwell County, North Carolina
ATC Project No. 89.03451.1018
NCDENR Incident No. 28649
NCDENR Facility ID No. 0-004593
Risk Classification: H190D
Latitude: 35.83749120˚ N
Longitude: 81.5387323˚ W
TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................1
1.0 INTRODUCTION...................................................................................................7
2.0 SITE HISTORY AND SOURCE CHARACTERIZATION...................................................8
2.1 Area of Investigation..................................................................................8
2.2 Site History and Operation..........................................................................8
2.3 Previous Investigations...............................................................................8
3.0 RISK CHARACTERIZATION AND RECEPTOR INFORMATION ..................................... 11
3.1 Water Supply Wells.................................................................................. 11
3.2 Public Water Supplies............................................................................... 12
3.3 Surface Water ......................................................................................... 12
3.4 Wellhead Protection Areas ........................................................................ 12
3.5 Deep Aquifers in the Coastal Plain.............................................................. 12
3.6 Subsurface Structures.............................................................................. 12
4.0 LAND USE......................................................................................................... 14
4.1 Land Use ................................................................................................ 14
4.2 Property Owners and Occupants................................................................ 14
4.3 Sensitive Land Use Features ..................................................................... 15
5.0 SOIL SAMPLING RESULTS................................................................................... 16
5.1 UST Closure Sampling.............................................................................. 16
5.2 Limited Site Assessment (LSA) Soil Sampling.............................................. 17
5.3 Comprehensive Site Assessment Soil Sampling ........................................... 17
5.4 Soil Sampling Results............................................................................... 19
6.0 GROUNDWATER SAMPLING RESULTS................................................................... 20
6.1 Limited Site Assessment Sampling............................................................. 20
6.2 Comprehensive Site Assessment Sampling ................................................. 20
7.0 FREE PRODUCT INVESTIGATION AND RECOVERY .................................................. 25
7.1 Free Product ........................................................................................... 25
8.0 GEOLOGY AND HYDROGEOLOGY ......................................................................... 26
8.1 Regional Geology..................................................................................... 26
8.2 Site Geology ........................................................................................... 26
8.3 Regional Hydrogeology............................................................................. 27
8.4 Site Hydrogeology ................................................................................... 28
9.0 DISCUSSION..................................................................................................... 32
9.1 Extent of Impacted Soil ............................................................................ 32
9.2 Extent of Impacted Groundwater............................................................... 32
10.0 CONCLUSIONS AND RECOMMENDATIONS ............................................................ 34
11.0 PUBLIC NOTICE ................................................................................................. 37
12.0 REFERENCES..................................................................................................... 38
TABLES

TABLE 1 UST System and Release Information
TABLE 2 UST Owner/Operator and Responsible Party Information
TABLE 3 Public and Private Water Supply Well Information and Other Receptor
Information
TABLE 4 Property Ownership and Land Use Information
TABLE 5 Well Construction and Groundwater Elevation Data
TABLE 6 Summary of UST Closure and Over-Excavation Soil Sampling Data
TABLE 7 Summary of LSA Soil Sampling Data
TABLE 8 Summary of CSA Soil Sampling Data
TABLE 9 Summary of Groundwater Analytical Data (LSA and CSA Phases)
TABLE 10 Aquifer Characteristics

FIGURES

FIGURE 1 Topographic Map
FIGURE 2 Site Map
FIGURE 3 Site Vicinity Map
FIGURE 4A Dispenser Area & UST Basin Area Sampling and Excavation Map
FIGURE 4B Petroleum Impact in Soil Map
FIGURE 5 Groundwater Elevation and Flow Map
FIGURE 6 Cross Section Location Map
FIGURE 7 Geologic Cross-Section A-A’
FIGURE 8 Geologic Cross-Section B-B’
FIGURE 9 Dissolved Impact in Groundwater Map
FIGURE 10 Benzene Isoconcentration Map
FIGURE 11 Toluene Isoconcentration Map
FIGURE 12 Ethylbenzene Isoconcentration Map
FIGURE 13 Total Xylenes Isoconcentration Map
FIGURE 14 Total BTEX Isoconcentration Contour Map
FIGURE 15 MTBE Isoconcentration Map
FIGURE 16 Naphthalene Isoconcentration Map
FIGURE 17 EDB Isoconcentration Map
FIGURE 18 Site and Vicinity Map Showing Estimated Vertical Maximum Extent of
Petroleum Constituents Detected in Groundwater
FIGURE 19 Recommended Pre-CAP Monitoring Activities Map

APPENDICES

APPENDIX A: Notice of Regulatory Requirement and Pre-Approval Task Authorizations
APPENDIX B: Returned Water Supply Well Information Forms
APPENDIX C: Standard Operating Procedures
APPENDIX D: Soil Boring Logs and Well Construction Records
APPENDIX E: Laboratory Analytical Reports
APPENDIX F: Slug Test and Bioscreen Modeling Data
APPENDIX G: Health and Safety Plan
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
1
EXECUTIVE SUMMARY

ATC Associates of North Carolina, P.C. (ATC) was retained by Cary Oil Company (Cary Oil)
to conduct a Comprehensive Site Assessment (CSA) at the Former Cajah’s Mountain
Superette facility located at 1990 Connelly Springs Road, Lenoir, Caldwell County, North
Carolina. Figure 1 shows part of a USGS, 7.5 Minute Topographic Quadrangle Map
depicting the location of the facility and surroundings. The site vicinity contains residential
and commercial properties and lies along the west side of Connelly Springs Road (NC State
Road 1101), between the communities of Baton, to the south, and Cajah’s Mountain, to the
north. Figure 2 provides information on the physical features of the immediate site
investigation area, including environmental assessment locations associated with the site
release incident, and Figure 3 indicates the site on an aerial photography overlay of the
area with property boundaries, roads, and nearby water supply wells.

The project site, which currently operates as a catering service, previously operated as gas
station/convenience store. The underground storage tank (UST) system was reportedly
installed in the early 1980s and operated as Cajah's Mountain Superette until December 24,
2007, which was the last day of UST operation. Based on Caldwell County tax parcel data,
the property owner is identified Mary Lindsay and the Caldwell County Property
Identification Number (PIN) is 2746795343. Prior to UST closure activities in August 2008,
two fuel oil above ground storage tanks (ASTs) were removed from a concrete platform
located west of the tank basin. Table 1 indicates the site UST/AST system and other
release information, and Table 2 provides UST/AST owner/operator and other responsible
party information.

During the removal of the USTs in August 2008, no free product or groundwater were
encountered in the tank pit excavation. Analytical results from soil samples collected during
tank closure activities indicated petroleum constituent concentrations exceeding applicable
North Carolina Department of Environment and Natural Resources (NCDENR) action levels,
and ATC submitted a 24-Hour Release Report to NCDENR on August 29, 2008, on behalf of
Cary Oil, to fulfill NCDENR reporting requirements. The former Cajah’s Mountain Superette
store has a half-basement, but indications of petroleum impact to the basement air quality
were not apparent.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
2
ATC excavated 418.12 tons of petroleum hydrocarbon impacted soil from the UST basin and
adjoining dispenser island area, and areas on the western side of the former UST system were
successfully over-excavated. However, over-excavation of soil in the tank basin and under
parts of the dispenser island were limited due to a storm sewer line, a water main, four fiber
optic cable lines abutting the east side of the tank basin, and the site water supply line and
the property boundary abutting the north side of the tank basin. Over-excavation was
conducted five feet beyond the tank basin/dispenser area to the west and south, two feet to
the east, and to sixteen feet below surface level. Laboratory analyses of soil samples
collected from the extent of the over excavated walls and base indicated petroleum impacted
soils that exceeded the Soil-to-Groundwater Maximum Soil Contaminant Concentration (MSCC)
standards in the area of the former gasoline USTs and at one of the former dispensers
(Dispenser 1) (Figure 4A). Initial abatement efforts did not appear to be necessary for the on-
site structure’s basement, based on impact being removed via over-excavation from the west
side of the tank basin adjacent to the store. Sufficient depth to impacted groundwater would
also limit impact to site and vicinity structures that have basements, to the extent of
dangerous buildup of potentially explosive gasses would be unlikely.

NCDENR issued a Notice of Regulatory Requirements (NORR) dated November 6, 2008,
indicating the requirement for a Phase I Limited Site Assessment (LSA), based on review of the
October 20, 2008, 20-Day Report and the Initial Abatement Action Report, which was received
on November 4, 2008. The IAAR confirmed soil contamination from a release or discharge from
a petroleum UST system exceeded the Soil-to-Groundwater MSCC standards.

On behalf of Cary Oil, ATC provided a Phase I & II (LSA) Report to the North Carolina
Department of Environment and Natural Resources (NCDENR) on May 9, 2009. As part of
the LSA, four soil borings were advanced and completed as monitoring wells (MW-1, MW-2,
MW-3 and MW-4). The results of the investigation indicated petroleum constituents in the
groundwater at concentrations greater than 10 times the 15A NCAC 2L .0202 Standards (2L
standards). The receptor survey information from the LSA report also identified seventeen
(17) water supply wells within 1,500 feet of the release source area. Based on the findings
of the LSA Report, the site met the criteria for a high risk classification and required the
completion of a Comprehensive Site Assessment (CSA) to further delineate the impacted
groundwater and soil at the site.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
3
To assess the horizontal and vertical extent of impacted soil during the CSA, eighteen (18)
soil borings were advanced (MW-5, MW-8, MW-11, and SB-1 through SB-15). Table 8
summarizes soil screening data from these borings and analytical results from thirteen soil
samples (SB-1 through SB-5, SB-10 through SB-12, SB-14, SB-15, MW-5, MW-8, and MW-
11). Figure 4B shows the defined area of soil that is impacted with petroleum in excess of
the NCDENR MSCC Soil-to-Groundwater standards.

To assess the horizontal and vertical extent of impacted groundwater, ATC initially installed
four additional shallow Type II monitoring wells (MW-5 through MW-8) and one deep Type
III monitoring well (DMW-1). Local water supply wells were also used in the assessment
(PW-15 and PW-16), as discussed below. After the first and second rounds of these well
installations in November 2009 and March 2010, the monitoring groundwater elevation and
flow mapping strongly suggested, in accordance with local topographic and visual
estimations, that the prevalent flow direction from the source area would be westward.
Impact to water supply wells, to the west of the site, whose owners allowed sampling in
November 2009 concurred with this hypothesis.

After considerable effort, including by the UST Section of the Asheville Regional Office and
ATC, nearby property owners to the east and west-southwest granted access that ostensibly
would have completed the groundwater assessment. ATC sampled water supply wells to the
west, southwest, and northeast; installed and monitored a well pair on the southwestern
part of the site (MW-9 and DMW-2), and installed and monitored two shallow monitor wells
across Connelly Springs Road from the site (MW-11 and MW-12). ATC also closed a gap in
shallow monitor well coverage on the south side of the site with installation of MW-10.

Based on data collected on July 28, 2010, Figure 5 displays the direction of shallow
groundwater flow at the site as radially outward from monitoring wells MW-1 and MW-8,
near the former tank basin. ATC’s findings thereby indicate that the source area was located
on a hydrogeographic knoll, and the high point was unexpected, given the sharp drop in
land surface to the west on the project site and relatively level topography to the east
across Connelly Springs Road.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
4
ATC conducted the latest round of groundwater monitoring on July 28, 2010, at the
conclusion of the CSA field activities, and the monitoring results provided the following
general findings:
 Free-phase petroleum product (free product) has not been identified in monitoring
wells at the site.
 Concentrations of volatiles organic compounds (VOCs) above 2L standards were
detected in water samples from monitoring wells MW-1, MW-2, MW-5 through MW-8,
MW-11, and both deep wells.
 Benzene concentrations in monitoring well MW-11 exceeded UST Section gross
contamination levels (GCLs).
 Volatile petroleum hydrocarbon (VPH) C5-C8 chain aliphatics, C9-C12 chain aliphatics,
or C9-C10 chain aromatics were detected above 2L standards in monitoring wells
MW-1, MW-2, MW-5 through MW-8, MW-11, and deep well DMW-1.
 Lead concentrations were detected above 2L standards in monitoring wells MW-1
through MW-4, MW-6, MW-9, MW-11 and MW-12; however, concentrations of
unfiltered lead may be attributable to natural background variation and not related to
the petroleum release.
During the CSA, five (5) water supply wells in the vicinity of the site were sampled on July
26, 2010: PW-1 (Beane, currently inoperative), PW-2 (operative, use by more than one
household), PW-15 (Correll; operative, used as potable water), PW-16 (Icenhour; currently
inoperative), and PW-18 (Beane; recently identified and currently inoperative). Based on
analytical results for potable well samples, the following was determined:
 PW-2, 450 feet to the northeast of the source area and apparently used for more
than one household, contains detectable concentrations of chloroform, methyl-tert-
butyl ether (MTBE), 1,2-dichloroethane (1,2-DCA), naphthalene, and benzene, at
concentrations below North Carolina 2L Groundwater Standards.
 A concentration of benzene above the 2L standard was detected for inactive PW-16
(Although not analyzed during the July 2010 assessment, prior analyses on
November 17, 2009, found VPH C5-C8 chain aliphatics and C9-C10 chain aromatics
above established 2L standards)
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
5
 Detectable concentrations (below 2L standards) of chloroform and naphthalene were
detected in potable well PW-15.
Based on these data, a re-curved plume of petroleum-impacted groundwater in the shallow
aquifer extends west, southwest, south and southeast of the source area and is defined by
MW-3, MW-4 MW-9, MW-10, and MW-12. The plume of impacted groundwater in the
shallow aquifer remains undefined northeast beyond monitoring wells MW-5 and MW-8, and
east beyond monitoring well MW-11, which was expected to define the plume to the east
based on prior findings and apparent topographic conditions. Conditions in the deeper water
bearing zones (partially weathered rock of deep aquifer monitor wells and apparent bedrock
of the water supply wells) provide extent information for the petroleum plume in the deeper
aquifer. The marginal exceedences of 2L standards in downgradient DMW-2 provide useful
near-edge of plume information for a discreet interval and indicate that significant migration
of impact has yet to occur in the deeper water bearing zones of the western part of the site.
Groundwater sampling results are summarized in Table 9 and depicted on Figure 9.
Figure 18 provides a site vicinity view of the estimated vertical maximum extent of
detected petroleum impact associated with the Cajah’s Mountain Superette release.

Evaluation of aquifer flow and contaminant transport conditions has provided sufficient
information to establish general impact migration expectations. ATC expects that impact will
continue to migrate further to outlying areas northeast, east, west and southwest of the
existing plume extent and that impact concentrations in water supply wells with petroleum
detections will continue to increase in those areas (PW-1, PW-2, PW-15, and PW-16).
Active water supply wells PW-15 (Corell) and PW-2 did not have impact above 2L
groundwater standards, but ATC expects that migration of impact will continue until those
wells have impact above standards. Inactive water supply wells that have not been
monitored, including PW-3, PW-4, and PW-17, as well as inactive PW-18, which recently had
no detected impact, are at risk for migration of impact from plume migration. More
importantly, the recent findings of severe impact to MW-11 and trace detection in PW-2
suggest that a cluster of active wells to the east-northeast and approximately 800 to 1000
feet from the source area could be at risk for impact.

Based on the CSA findings and data analysis, ATC recommends the following activities to be
performed within the pre-CAP monitoring framework:
 Evaluation of nearby structures for soil vapor intrusion, especially for structures with
basements;
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
6
 Water supply wells with detection of petroleum constituents or proximity to the plume
extent should be abandoned and those locations with active wells should be connected
to municipal supply. Such wells include PW-1 through PW-4 and PW-15 through PW-18.
 Water supply wells to the east-northeast of the of the site (PW-6 through PW-9) should
be monitored for petroleum constituents. Connection to municipal supply, followed by
abandonment, of any impacted, or imminently threatened, wells in that grouping
should be pursued.
 Assessment of shallow groundwater to the east and northeast of the site should be
conducted. We recommend collection of temporary well samples in an estimated 8
locations to confirm extent of migration, followed by installation of up to six additional
shallow zone monitoring wells to the east-northeast of the site, to define extent and
internal shallow zone plume geometry.
 Assessment of the deeper parts of the shallow aquifer (partially weathered rock – PWR)
and the bedrock aquifer should be expanded by pairing a bedrock well with DMW-2 and
installation of paired wells in the PWR and bedrock to the northeast of the site adjacent
to a shallow well that is used to establish internal plume geometry in that area.
 The entire monitoring well network and available water supply wells should be
monitored at the completion of the assessment.
 Observation of local apparent wet-weather drainages to establish actual flow conditions
and monitoring of any drainages that are found to contain flowing water. Stream
branches to the east, southeast, west and southwest of the site are candidates for
evaluation and potential monitoring.
 Expansion of the receptor survey to areas beyond the 1500 foot radius, principally
northeast/east and west/southwest. If necessary based on the receptor investigations,
performance of more sophisticated groundwater modeling to assess threats farther
from the source area should be considered.

Based on the pre-CAP monitoring findings, ATC recommends completion of a corrective
action plan (CAP) appropriate to receptor conditions that exist after the pre-CAP efforts.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
7
1.0 INTRODUCTION

ATC Associates of North Carolina, P.C. (ATC) was retained by Cary Oil Company (Cary Oil) to
conduct a CSA at the site. The investigation was conducted in general conformance with the
North Carolina Administrative Code (NCAC) Title 15A, Subchapter 2L and Subchapter 2N.
The purpose of the Comprehensive Site Assessment (CSA) was to characterize impact
magnitude and extent of petroleum hydrocarbons in the subsurface associated with release
from UST system at the Former Cajah’s Mountain Superette facility located at 1990 Connelly
Springs Road in Lenoir, Caldwell County, North Carolina. The objectives and scope included:

 Identification and description of information pertinent to the sources of the released
contaminant;
 Summarization of the need for and extent of initial abatement actions and
provisional water supply;
 Evaluation of environmental impact, including soil and groundwater assessment for
the nature and extent of impact, estimation of migration potential and rates, and
determination of potential effects on receptors including groundwater and surface
water;
 Characterization of the affected area’s geology and hydrogeology;
 Indication of risk classification and its means of determination;
 Remedial objectives for impact reduction to various media affected by the release;
 Identification of efforts that could reduce risk classification and the preliminary
identification of remedial actions that might be appropriate, given various degrees
of success in reducing the risk classifications.

ATC prepared the CSA report for submittal to the Asheville Regional Office of the North
Carolina Department of Environment and Natural Resources (NCDENR) and appropriate local
authorities, in general conformance with objectives and scope.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
8
2.0 SITE HISTORY AND SOURCE CHARACTERIZATION

2.1 Area of Investigation

The site is located at 1990 Connelly Springs Road in Lenoir, North Carolina. The site is
surrounded by residential and commercial properties and can be accessed by Connelly
Springs Road from the east. A USGS topographic map indicating the site location is
included as Figure 1. A site map depicting the site investigation area is included as
Figure 2.

2.2 Site History and Operation

The site, which currently operates as a catering service, previously operated as gas
station/convenience store. Reportedly, the UST system was installed in the early 1980s and
operated as Cajah's Mountain Superette until December 24, 2007, which was the last day of
UST operation. Based on Caldwell County tax parcel data, the property owner is identified
as Mary Lindsay, and the Caldwell County Property Identification Number (PIN) is
2746795343. At the time of the tank closure in August 2008, the facility was not operating.
Prior to tank closure activities in August 2008, two fuel oil ASTs were removed from a
concrete platform located west of the tank basin. The UST system included two 8,000-
gallon gasoline USTs and one 4,000-gallon gasoline UST, which were situated in one tank
basin located on the northeast side of the site, and gasoline product lines and three
dispensers that were located adjacent to the south of the tank basin (See Figure 2). The
UST system, including dispensers and associated product lines, was removed on August 13
through 15, 2008. Table 1 indicates UST/AST System and Other Release Information, and
Table 2 provides UST/AST Owner/Operator and Other Responsible Party Information.

2.3 Previous Investigations

During the removal of the USTs in August 2008, no free product or groundwater was
identified in the tank basin excavation. Based on analytical results from soil samples
collected during tank closure activities, petroleum constituent concentrations exceeding
applicable NCDENR action levels were detected. To fulfill the NCDENR requirements, a 24-
Hour Release Report was submitted to NCDENR on August 29, 2008.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
9
Over-excavation of soil in the tank basin and under the dispensers was limited due to a
storm sewer line, four fiber optic cable lines, and a water line abutting the east side of the
tank basin; a water line and the property line along the north side of the tank basin, and the
extent of equipment reach. Over-excavation was conducted five feet beyond the tank basin
to the southwest and west, two feet to the south, and to sixteen feet below ground surface.
Approximately 418.12 tons of petroleum hydrocarbon impacted soil was removed from the
site. Laboratory analyses of soil samples collected from the extent of the over-excavated walls
and base indicated petroleum impacted soils exceeded the UST Section, Soil-to-Groundwater
Maximum Contaminant Concentrations (MSCCs) in the area of the former gasoline USTs and
one of the former dispensers (Dispenser 1). The remaining impact was generally adjacent to
areas with subsurface infrastructure that prevented removal or the impact was beyond the
depth of excavator reach (Figure 4A).

An NORR, dated November 6, 2008, was issued by the NCDENR indicating the requirement for
a Phase I LSA, because the results of a 20-Day Report received on October 20, 2008, and an
Initial Abatement Action Report received on November 4, 2008, confirmed soil contamination
from a release or discharge from a petroleum UST system that exceeded the Soil-to-
Groundwater MSCCs.

A Phase I & II Limited Site Assessment (LSA) report was submitted to the NCDENR, dated
May 9, 2009. As part of the LSA, four soil borings were completed as monitoring wells MW-
1, MW-2, MW-3 and MW-4. The results of the investigation indicated petroleum
concentrations in the groundwater greater than 10 times the 2L Standards. The LSA Report
also identified seventeen (17) water supply wells within 1,500 feet of the release source
area (Figure 3). Based on the findings of the LSA Report, the site met the criteria for a
high risk classification, and the completion of a CSA was required to further delineate the
impacted groundwater and soil at the site.

The NCDENR issued a directive letter on May 28, 2009, requesting preparation of a CSA. A
copy of the NORR is provided in Appendix A. Pre-Approval for the CSA was received from
the NCDENR on July 14, 2009. A copy of the Pre-Approval Task Authorization (PATA) No
28649-1 is included in Appendix A along with Change Order PATA No. 28649-2 that was
received from NCENR on February 5, 2009, Change Order PATA 28649-2A that was received
from NCDENR on August 3, 2010, and Change Order PATA 28649-2B that was received from
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
10
NCENR on August 17, 2010. CSA site investigation work was performed under a Health and
Safety Plan (HASP), a copy of which is provided in Appendix G.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
11
3.0 RISK CHARACTERIZATION AND RECEPTOR INFORMATION

The LSA, which included a risk characterization and receptor survey, was completed by ATC in
May 2009. The site has been ranked as H190D, and land use has been characterized as
commercial and residential. The proximity of active water supply wells was the primary reason
for high risk classification.

3.1 Water Supply Wells

ATC performed a survey to identify water supply wells within 1,500 feet of the site during the
LSA and updated the survey during the CSA. The survey was performed by visually observing
the area for the presence of water supply wells, sending surveys to residents within 500 feet of
the source area, and when possible, contacting area residents to confirm water usage. An
additional potable well (PW-18) was identified during the CSA. Potable well PW-18 is not in
operation, not used, and is located approximately 240 feet southwest of the source area.
Based on this review, eighteen (18) water supply wells were identified within approximately
1,500 feet of the site. Five (5) potable wells were located within 500 feet of the source area,
and two of the wells, PW-15 and PW-2 are operational and used as a source for drinking water.
Potable well information for the area is summarized in Table 3, and their locations relative to
the source area are depicted on Figure 3. Properties within 500 feet of the site were provided
a water supply well survey form. See Appendix B for the Water Supply Well Information
surveys.

Public water supplied by Baton Water is provided to the site and surrounding area. A map
depicting the local water provider distribution for the area is shown on the site vicinity map
(Figure 3). Potable wells located beyond the local water provider distribution area are
assumed to be used as a source of drinking water due to lack of public water. These and other
water supply wells identified during the survey within 1,500 feet of the site are indicated on
Figure 3 and summarized in Table 3. Based on Table 3, the closest potable wells from the
source area are PW-17 (located approximately 200 feet north), PW-18 (located approximately
240 feet southwest), PW-16 (located approximately 400 feet west-southwest), PW-1 (located
approximately 400 feet southwest), and PW-2 (located approximately 450 feet northeast).
Reportedly, potable well PW-17, which is not in use, is not accessible. Potable well PW-15 to
the west-southwest and potable well PW-2 to the northeast were identified as the nearest
active supply wells from the source area.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
12
3.2 Public Water Supplies

ATC contacted the local water provided for the area, Baton Water Corporation to identify public
water sources and water lines in the area. The Baton Water Corporation confirmed that public
water is available in the site and the site vicinity. A map depicting the local water provider
distribution for the area is provided as Figure 3.

3.3 Surface Water

ATC reviewed the USGS 7.5-Minute Hudson Quadrangle Topographic Map, dated 1995
(Figure 1) to identify surface water bodies in the site vicinity. In addition, ATC conducted a
visual reconnaissance for surface water bodies in the area. Based on this evaluation, the
perennial surface water body in the closest proximity to the site is Stafford Creek located
approximately 2,000 feet to the southwest of the site. A branch of Little Gunpowder Creek
lies approximately 2,500 feet to the east of the site.

3.4 Wellhead Protection Areas

According the Division of Water Quality Wellhead Protection Website
(http://204.211.89.92/wellhead/new/VIEW1_list.asp), the site is not located within the area
of a wellhead protection program.

3.5 Deep Aquifers in the Coastal Plain

The risk classification criteria specified in Title 15A NCAC 2L .0115(d) requires an evaluation for
the presence of unconfined or semi-confined deep aquifers in the Coastal Plain region which
may be used as a source of drinking water. The site is not located in the Coastal Plain region.

3.6 Subsurface Structures

Subsurface utility lines at the site include water lines, sewer pipes, and fiber optic cable
lines. Utility line locations are depicted on the site map in Figure 2. The water supply lines
provided to the area by Baton Water are depicted on the site vicinity map attached
(Figure 3).

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
13
The successful removal of soil impact above MSCCs adjacent to the site building resulted in
reduction of potential for hazardous atmospheric conditions in the building’s half-basement
(the rear of the basement is at ground level, while the sides and front of the structure are
below grade). No significant indications of vapor intrusion that would cause a safety hazard
were apparent within the structure; however, our recommendations include vapor intrusion
sampling for this and other nearby structures. No other structures were located within the area
of soil impact defined by the CSA.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
14
4.0 LAND USE
4.1 Land Use

The subject site is located in Caldwell County, North Carolina, in an area characterized by rural
residential development. The site formerly operated as a convenience store, which included a
UST system that was removed in August 2008. The site also includes a concrete building
with store-front windows and a half-basement, asphalt parking areas on the east and south
side, grassy areas on the north and west side, propane AST located to the northwest of the
onsite building, and a septic system further west of the onsite building. The site is accessible
from Connelly Springs Road to the east.

Properties within 1,500 feet of the site include commercial and residential land use. The
closest residences are located adjacent to the north of the property, across Connelly Springs
Road to the east, and to the west and southwest several hundred feet distant from the source
area. The closest location which could be construed as a place of public assembly would be the
Frosty Frez restaurant to the immediate south of the former Cajah’s site. The Frosty Frez is
located on the same tax parcel as the release incident but is approximately 80 feet distant
from the source area and at least 50 feet distant from the area of defined soil impact.

The site is zoned as B-1 (Business). The immediate surrounding areas are zoned as B-1, R-20
(Residential), and RA-20 (Residential). Land use and zoning information for the site and site
vicinity is included in Table 4.

4.2 Property Owners and Occupants

Based on Caldwell County tax parcel data, the property owner is identified as Mary Lindsay.
The immediate adjacent area includes commercial and residential land uses. Property
ownership information is summarized in Table 4 and adjacent properties are indicated on
Figure 3.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
15
4.3 Sensitive Land Use Features

Sensitive land use features, in this case restaurants, as places of public assembly, were
identified within 1,500 feet of the release. A restaurant, Frosty Frez, is located south and
adjacent to site. In addition, two other restaurants located further to the south are within
1,000 feet of the source area. An apartment complex to the east-northeast of the facility
appears to have a community water supply well and potential for impact to the well exists, but
has not yet been defined. No schools, day cares, churches or other places of public assembly
appear to be within the area of subsurface impact.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
16
5.0 SOIL SAMPLING RESULTS

5.1 UST Closure Sampling

The former UST system included two 8,000-gallon gasoline USTs and one 4,000-gallon
gasoline UST that were situated in one tank basin located on the northeast side of the site,
and gasoline product lines and one island with three dispensers that were located adjacent
to the south of the tank basin. The tank basin overlapped with the footprint of the
dispensers. On August 13 through 15, 2008, the UST system was removed during tank
closure activities. ATC collected soil samples from beneath the gasoline USTs and the gasoline
dispensers for analysis of gasoline range total petroleum hydrocarbons (TPH-GRO). Field
indications for over-excavation were observed.

Closure samples were also collected after over-excavation in the tank basin and in the area at
dispenser 1. Vertical and horizontal over-excavation was physically limited due to a storm
sewer line, four fiber optic cable lines, and a water line abutting the east side of the tank
basin; a water line and the property line along the north side of the tank basin; the extent
of available equipment reach; and contact with suspect clean soil via field screening methods.
Over-excavation was conducted five feet beyond the tank basin to the southwest and west,
two feet to the south, and to 16 feet below land surface (ft bls). Over excavation was also
conducted in to eight ft bls in the dispenser area.

Over-excavation soil samples were submitted for laboratory analysis of volatile organic
compounds (VOCs) by Method 8260 and volatile petroleum hydrocarbons (VPH) by the
MADEP Method. Samples selected for laboratory analysis were entered into formal chain-of-
custody control, placed in laboratory-supplied glass containers, and shipped in an ice-packed
cooler via overnight delivery to Southern Petroleum Laboratories (SPL) in Scott, Louisiana for
analysis. The results of the laboratory analysis indicated TPH-GRO above the NCDENR Action
Level of 10 milligrams per kilogram (mg/kg) for soil collected from beneath the tank basin and
the dispenser area. Laboratory results indicated concentrations in excess of the MSCC Soil-
to-Groundwater standards for the post excavation samples collected from the sidewalls and
bottom of the dispenser excavation and excavated tank basin. The laboratory analytical report
and chain-of-custody documentation are included in Appendix E. Soil sampling results for
closure sampling and over-excavation sampling are summarized in Table 6, and sample
locations are depicted in Figure 4A.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
17
5.2 Limited Site Assessment (LSA) Soil Sampling

As part of the LSA activities, monitoring well MW-1 was installed on December 4, 2008, in the
area of soil impact detected during the August 2008 tank closure activities. The boring for
monitoring well MW-1 was advanced by Environmental Drilling and Probing Services (EDPS)
personnel through the use of hollow stem auger drilling. Split spoon soil samples were
collected from boring MW-1 continuously from ground surface to the water table. Four soil
samples were submitted for laboratory analysis from boring MW-1 at 8-10 ft bls, 18-20 ft
bls, 28-30 ft bls, and 38-40 ft bls to comply with LSA requirements. Samples selected for
laboratory analysis were managed in accordance to the procedures outlined above in Section
6.1. Soil samples from MW-1 at 8-10 ft bls and MW-1 at 38-40 ft bls were analyzed for
VOCs by EPA Method 8260/5035 and the Massachusetts Department of Environmental
Protection – Volatile Petroleum Hydrocarbon (MAVPH) Method. Soil samples from MW-1 at
18-20 ft bls and MW-1 at 28-30 ft bls were analyzed for VPH only. Laboratory analytical
results indicated benzene concentrations above MSCC Soil-to-Groundwater standards. A
summary of the LSA soil analytical data is presented in Table 7.

5.3 Comprehensive Site Assessment Soil Sampling

On November 4 and 5, 2009, nine borings (SB-1 through SB-5, MW-6, MW-7, MW-8, and
DMW-1) were installed by EDPS personnel via a track rig equipped with Geoprobe direct-
push and hollow stem auger capability. The locations of soil borings are depicted in
Figure 4B. Direct-push continuous sampling was completed using a 48-inch long and two-
inch diameter steel probe with a non-reactive plastic liner, except for soil boring MW-8,
which was collected using split spoons through augers. Termination depth of the soil borings
SB-1 through SB-5 was dependent on the subsurface material. The soil samples were
characterized and screened with a photo-ionization detector (PID), and the sample above
the water table that exhibited the highest reading was submitted for laboratory analysis.
After completion of soil sampling, borings SB-1 through SB-5 were filled with bentonite and
finished to surface grade with a concrete or asphalt patch.

Split spoon soil samples were collected from boring MW-8 every five feet from ground
surface to the water table. Split spoon samples were screened in the field using a PID, and
the sample above the water table that exhibited the highest reading was submitted for
laboratory analysis. Boring logs, including PID screening results, are included in
Appendix D.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
18

Based on the PID screening, soil samples were collected for laboratory analysis from borings
SB-1 at 28-30 ft bls, SB-2 at 18-20 ft bls, SB-3 at 30-34 ft bls, SB-4 at 25-30 ft bls, SB-5 at
33-35 ft bls, and MW-8 at 25-30 ft bls. Samples were managed by methods described
above. Soil samples were analyzed for VOCs and petroleum hydrocarbons by EPA Method
8260 and MADEP-VPH, respectively.

Because analytical results from soil samples collected on November 4 and 5, 2009, indicated
target analyte concentrations in excess of MSCCs, additional borings were installed and soil
samples collected to further define the horizontal extent of the petroleum hydrocarbons in
soil at the site. Between July 26-28, 2010, eleven borings (SB-6 through SB-15, and MW-
11) were installed by Geologic Exploration personnel via a track rig equipped with
Geoprobe direct-push and hollow stem auger capability or by air rotary drilling with split
spoon sampling capabilities. The locations of soil borings are depicted on the attached
Figure 4B. Direct-push continuous sampling was completed using a 48-inch long and two-
inch diameter steel probe with a non-reactive plastic liner, except for soil boring MW-11.
Termination depth of the soil borings SB-6 through SB-15 was dependent on the subsurface
material. The soil samples were characterized and screened with a PID, and the sample
above the water table that exhibited the highest reading was submitted for laboratory
analysis. After completion of soil sampling, borings SB-6 through SB-15 were filled with
bentonite and finished to surface grade with a concrete or asphalt patch.

Split spoon soil samples were collected from boring MW-11 every five feet from ground
surface to the water table. Split spoon samples were screened in the field using a PID and
the sample above the water table that exhibited the highest reading was submitted for
laboratory analysis. Boring logs, including PID screening results, are included in
Appendix D.

Based on the PID screening, soil samples were collected for laboratory analysis from borings
SB-10 at 20 ft bls, SB-11 at 25 ft bls, SB-12 at 15 ft bls, SB-14 at 25 ft bls, SB-15 at 25 ft
bls, and MW-11 at 25 ft bls. Samples were managed as described above. Soil samples were
analyzed for VOCs and petroleum hydrocarbons by EPA Method 8260 and MADEP-VPH,
respectively. The laboratory analytical report and chain-of-custody documentation are
included in Appendix E. Soil analytical results are summarized in Table 8.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
19
5.4 Soil Sampling Results

Based on these data the extent of petroleum impacted soil has been defined for the gasoline
release at the former Cajah’s Mountain Superette. During the CSA, concentrations of
petroleum in soil at levels above the MSCC soil-to-groundwater standards were identified in
soil samples collected from borings SB-1, SB-2, SB-3, SB-5, MW-1, and MW-8. The area of
soil impacted with petroleum in excess of the MSCC Soil-to-Groundwater standards is
depicted on Figure 4B and in cross sections in Figure 7 and Figure 8.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
20

6.0 GROUNDWATER SAMPLING RESULTS

6.1 Limited Site Assessment Sampling

Monitoring well MW-1 was installed on December 4, 2008 as part of the LSA activities. On
March 10, 2009, monitoring wells MW-3 and MW-4 were installed as downgradient shallow
wells, and monitoring well MW-2 was installed as an upgradient/sidegradient shallow
monitoring well as part of LSA activities. Monitoring wells MW-1, MW-2, MW-3, and MW-4
were completed by a North Carolina-licensed well driller to depths of 48 ft bls, 46 ft bls, 35 ft
bls, and 40 ft bls, respectively. The monitoring wells were constructed of 2-inch diameter PVC
pipe with 15 feet of 0.010-inch slotted well screen. The wells were constructed with annular
materials consisting of filter sand surrounding the wells screen, a one to two foot bentonite
seal above the sand pack, and a bentonite-infused grout to land surface. The wells were
completed in flush mounted concrete well pads with small manhole covers and locking
compression caps on the tops of casing. Well construction details are summarized in Table 5.

A groundwater sampling event was conducted on December 10, 2008, from monitoring well
MW-1 and on March 13, 2009, from monitoring wells MW-2, MW-3, and MW-4.
Groundwater samples collected on both dates were placed in laboratory supplied glass
containers and shipped in an ice-packed cooler via overnight delivery to SPL in Scott, Louisiana
for analysis by EPA Method 6200B including IPE and MTBE; EDB by EPA Method 504.1;
carbon fraction classes by MADEP-VPH; and lead by EPA Method 3030C. Laboratory
analytical results indicated the presence of petroleum hydrocarbons above 2L Standards in
monitoring wells MW-1 and MW-2. Compounds detected above 2L Standards included
bromodichloromethane, chloromethane, MTBE, benzene, C5-C8 chain aliphatics, and lead.
Free phase petroleum product was not detected in sampled monitoring wells.

6.2 Comprehensive Site Assessment Sampling

Ten monitoring wells (MW-5 through MW-12, DMW-1, and DMW-2) were installed at the site
(see Figure 2) as part of the CSA activities. With relation to extent and direction of the known
petroleum plume at that time, monitoring well MW-5 was installed as a shallow upgradient
well, monitoring wells MW-6, MW-9, and MW-10 were installed as a downgradient wells, and
monitoring wells MW-7, MW-8, MW-11, and MW-12 were installed as sidegradient wells.
Monitoring wells MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, and MW-12 were
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
21
completed to depths of 45 ft bls, 45 ft bls, 44 ft bls, 44 ft bls, 30 ft bls, 40 ft bls, 40 ft bls, and
40 ft bls, respectively. Monitoring wells MW-5, and MW-7 through MW-12 were constructed of
2-inch diameter PVC pipe with 15 feet of 0.010-inch slotted well screen. Monitoring well MW-6
was constructed of 2-inch diameter PVC pipe with 20 feet of 0.010-slotted well screen.
Monitoring well DMW-1 was installed as a vertical extent monitoring well and was located near
MW-1 and the petroleum source area. Monitoring well DMW-1 was completed by installing an
outer casing to 65 ft bls with an exterior grout seal to isolate the well from the shallow zone
water. After the grout hardened on the outer casing, the well was continued to a total depth of
75 ft bls and constructed of 2-inch diameter PVC pipe with 5 feet of 0.010-inch slotted well
screen from 70 to 75 ft bls. After installation of deep monitoring well DMW-1, deep monitoring
wells DMW-2 was installed downgradient of the source area between MW-1 and potable well
PW-15 (Correll well). Potable well PW-15 is an active, operating water supply well used for
drinking water that is located approximately 600 feet west-southwest of the source area.
Monitoring well DMW-2 was completed to a depth of 95 feet bls with a 85 foot bls protective
outer casing and constructed of 2-inch diameter PVC pipe with 5 feet of 0.010 slotted well
screen. The annular materials and surface finish were conducted as described for the LSA
wells. Well construction details are summarized in Table 5, and Appendix D contains the well
construction forms and subsurface exploration log documentation.

As part of the CSA investigation, a groundwater sampling event for monitoring wells MW-1
through MW-8 and DMW-1 was conducted on November 17, 2009, and a second groundwater
sampling event was conducted for previously installed monitoring wells and for MW-9 through
MW-12 and DMW-2 on July 28, 2010. Groundwater samples collected on both dates were
entered into chain-of-custody control, placed in laboratory supplied glass containers, and
shipped in an ice-packed cooler via overnight delivery to SPL in Scott, Louisiana for analysis by
EPA Method 6200B including IPE and MTBE, EDB by EPA Method 504.1, carbon fraction classes
by MADEP-VPH, and lead by EPA Method 3030C.

Groundwater sampling procedures are summarized in Appendix C. The laboratory analytical
report and chain-of-custody documentation are included in Appendix E. Groundwater
analytical results are summarized in Table 9.

In addition, water supply wells PW-15 and PW-16 were sampled on November 17, 2009 and
analyzed for VOCs by EPA 6200B including IPE and MTBE and VPH. Potable well PW-16 was
also analyzed for EDB by EPA Method 504.1. Analytical results for water collected from PW-15
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
22
on November 17, 2009 indicated no detectable levels of target analytes. Water collected on
November 17, 2010 from potable well PW-16 indicated concentrations of benzene, C5-C8 chain
aliphatics, and C9-C10 chain aromatics above established 2L standards and trace concentrations
(below 2L standards) of toluene, ethylbenzene, total xylenes, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, isopropylbenzene, n-propylbenzene, styrene, naphthalene, and C9-C12 chain
aliphatics.

As analytical results from PW-16, which is not in use, indicated target analyte concentrations in
excess of established 2L standards, and due to the proximity of PW-16 to PW-15, which is used
as a source of drinking water, these potable wells were resampled on July 26, 2010. In
addition, potable wells PW-1, PW-2, and PW-18 were sampled on July 26, 2010. Prior to
sampling, potable wells PW-1, PW-16, and PW-18 were purged of three well volumes using a
submersible pump. The taps connected to PW-15 and PW-2 were allowed to purge for five
minutes prior to sample collection. The water samples from PW-1, PW-2, PW-15, PW-16, and
PW18 were analyzed by EPA Method 6200B including IPE and MTBE, and EDB by EPA Method
504.1.

Based on review of the July 26, 2010 analytical results, the following findings were
observed:
 Groundwater samples from monitoring wells MW-1, MW-2, MW-5, MW-6, MW-7,
MW-8, MW-11, DMW-1, and DMW-2 contained petroleum target analyte
concentrations above established 2L standards, which included
1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, isopropyl benzene, MTBE, 1,2-DCA,
n-propylbenzene, isopropyl ether (IPE), trichloroethylene (TCE), perchloroethylene
(PCE), styrene, naphthalene, benzene, toluene, ethylbenzene, total xylenes, EDB,
C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and lead.
 Water samples from potable wells PW-1, PW-2, PW-15, and PW-16 contained trace
concentrations (below 2L standards) of petroleum constituents. In addition,
analytical results for PW-16 indicated concentrations of petroleum constituents above
established 2L standards.
 The highest concentrations of total BTEX (benzene, toluene, ethylbenzene, and total
xylenes) were detected in monitoring well MW-11 at 68,900 ug/L.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
23
 Benzene exceeded above GCLs in MW-11; however, no other constituents and no
other wells had GCL exceedances.
 Analytical results from both deep wells indicated concentrations of benzene above 2L
standards; however, the benzene exceedance in DMW-2 was only slightly above 2L
standards. Concentrations of MTBE, C5-C8 chain aliphatics, and C9-C10 chain
aromatics were detected above 2L standards in deep well DMW-1.
 EDB concentrations above established 2L standards were detected in sampled
groundwater from monitoring wells MW-8 and MW-11.
 Concentrations of perchloroethene and trichloroethene were detected in monitoring
well MW-8 above 2L standards, and the source of the impact is uncertain, although
utility lines run adjacent to the well. No other locations detected the chlorinated
solvents.
 Concentrations of petroleum constituents below established 2L standards were
detected in water samples from monitoring wells MW-3, MW-4, MW-10, and MW12.
 Concentrations of unfiltered lead above established 2L standards were detected in
groundwater samples from monitoring wells MW-1 through MW-4, MW-6, MW-9,
MW-11, and MW-12. The concentrations of lead could be due to natural occurrence
and be unrelated to the petroleum release, especially give that the locations where the
detections occur do consistently correspond with the area of petroleum impact.
 Water samples collected on July 26, 2010, from potable wells PW-1 and PW-2,
indicated detectable concentrations of target analytes, which including benzene, total
xylenes, naphthalene, 1,2-dichloroethane, MTBE, and chloroform.
 Water samples collected on July 26, 2010, from potable well PW-16 (Icenhour well),
which is not in use, indicated detectable concentrations of target analytes, which
included benzene, toluene, and total xylenes. The benzene concentration was above
the established 2L standard.
 November 17, 2009, analytical results from water collected from potable well PW-15
(Correll well), which is in use as a source for drinking water approximately 600 ft
downgradient of the source area, did not indicate detectable levels of target analyte
concentrations. However, the analytical results for water sampled from PW-15 on
July 26, 2010, indicated trace concentrations of chloroform and benzene.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
24

Analytical data for groundwater samples and potable well water samples is summarized in
Table 9 and on Figure 9, a dissolved petroleum constituents in groundwater map.
Isoconcentration maps for benzene, toluene, ethylbenzene, total xylenes, total BTEX, MTBE,
naphthalene, and EDB are included as Figures 10 through Figure 17, respectively.
Figure 18 shows an estimated vertical maximum extent of petroleum impact in
groundwater and includes information from potable wells to establish the findings.
Laboratory analytical reports are included in Appendix E.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
25

7.0 FREE PRODUCT INVESTIGATION AND RECOVERY

7.1 Free Product

An oil/water interface probe was used to evaluate the project monitoring well network for
free product. To date, no free product has been detected in the monitoring well network.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
26

8.0 GEOLOGY AND HYDROGEOLOGY

8.1 Regional Geology

According to the Geologic Map of North Carolina (1985), the project site is located within the
Inner Piedmont Physiographic Province. The site lies in an area of metamorphosed rock that
includes biotite gneiss/schist, mica schist, and small masses of granitic rock in closely
interlayered and gradational relationships. The Geologic Map shows large scale, east-west
interfingering of biotite gneiss/schist and mica gneiss in the site vicinity. The rocks of the
Piedmont weather to residual soils, or regolith, of various textures and thicknesses, so that the
land surface only occasionally has outcrops. A weathering profile often includes relatively
unstructured residuum in shallow zones, saprolite with some residual rock structure in deeper
zones, and partially weathered rock (PWR) above the bedrock. The depth to bedrock varies
from near land surface adjacent to the occasional outcrops to depths of over 100 feet bls in
areas with readily weathered rock.

According to the soil data for Caldwell County, North Carolina, as provided on the NRCS
Websoil website, the soils underlying the project site are Clifford sandy loam, on 2 to 8 percent
slopes, and is moderately eroded (CmB2). The Clifford sandy loam consists of well-drained
soils found on summits and interfluves of Piedmont uplands, which form a convex down-slope
or across-slope shape. The parent material is saprolite from granite and gneiss and/or schist.
The soils have a moderate available water capacity. According to the Websoil information, the
surface layer of Clifford sandy loam is red and orange sandy loam about 6 inches thick. The
subsoil is yellowish-red and red sandy clayey loam about 6 to 15 inches thick that trends to
clay about 15 to 40 inches thick. The clay layer then generally trends to clayey loam about 40
to 52 inches thick and then sandy loam again about 52 to 80 inches thick. Depth to bedrock
is more than 60 inches bls. The seasonal high water table is typically greater than 6 feet bls as
has been found at the site.

8.2 Site Geology

As part of the CSA investigation, ten borings were advanced with a Geoprobe®, four borings
were advanced with hollow-stem auger methods, and eleven borings were advanced with air
rotary methods. A lithologic description of each soil sample was described in accordance with
the Unified Soil Classification System. Soils encountered during drilling activities consisted of
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
27
primarily red, tan, brown, and orange silt with varying percentages of sand and clay. Partially
weathered rock was frequently encountered in the soil borings. Soil boring logs for LSA and
CSA activities, are included as Appendix D. Competent bedrock was not encountered above
65 ft bls and then as lenses within PWR, which appeared to extend from perhaps 40 ft bls to
depths approaching 100 ft bgs.

ATC prepared two geologic cross-sections that depict the subsurface soil lithology across the
site. A geologic cross-section map, showing the location of cross-sections A-A’ and B-B,’ is
included as Figure 6. Cross-sections A-A’ and B-B’ are included as Figure 7 and Figure 8,
respectively. Soil boring logs with lithologic descriptions are included in Appendix D.

8.3 Regional Hydrogeology

According to the website maintained by the NCDENR - Division of Water Resources (DWR)
(www.ncwater.org/Data_and_Modeling/Ground_Water_Databases/), no formal aquifer
system designation has been provided for the regional site vicinity. However, groundwater
in the Piedmont is often first encountered as a water table in pores within the overburden
saprolite/residuum or alluvium. Permeability varies with lithology, and is typically relatively
low in the many residual soils with higher permeability in saprolite or PWR due to relict rock
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Findings from the CSA suggest that most of the unconsolidated subsurface materials exhibit
high permeability for the Piedmont and probably can best be described as saprolite or PWR.
Groundwater becomes increasingly confined to fractures and other structural features as
rock integrity increases at depth.

The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and
rivers to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont.
Water in the alluvium or unconsolidated residual material, including saprolite and PWR,
usually behaves as an unconfined, or water table, aquifer and will yield water with head
elevation equivalent to the first elevation where water was encountered. Saprolite or alluvial
groundwater flow is usually in rough concurrence with local topographic conditions and is
toward local drainage features. For sites in the Piedmont, when gradient conditions are
discussed, upgradient sites are in locations which could, based on topographic analysis,
have shallow groundwater migration from them toward the project site. Sidegradient sites
are nearby sites with equivalent elevation to the project site, which would be unlikely to
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
28
have groundwater migration from them toward the project site, and downgradient sites are
nearby sites which likely receive groundwater migration from beneath the project property.
The bedrock fractures or other planar features generally constitute the bedrock aquifer, with
the surrounding rock material being effectively impermeable. Along with fractures, the
contact between rock bodies probably constitutes areas of significant groundwater
occurrence in the bedrock. The surrounding material and overlying residuum tend to make
the bedrock aquifer a semi-confined aquifer; that is, the overlying water and soil weight
normally results in pressure that causes water in a borehole which intersects a fracture or
other feature to rise above the elevation of the fracture or feature. Such features may not
occur on predicable trends, at the same elevations, or even be present or directly connected
in separate boreholes. In areas adjacent to creeks the bedrock groundwater generally
discharges to the residuum or alluvium and then into the surface water. In areas away from
surface water drainages, the bedrock aquifer is generally recharged by downward infiltration
of residuum or alluvial aquifer water at locations where fractures intersect the bedrock
surface. Most modern groundwater wells are completed as open rock wells in the bedrock,
with a surface casing being installed to the top of bedrock to seal off the unconsolidated
vadose zone and shallow aquifer. Bedrock groundwater from the Piedmont is usually of high
quality when not environmentally impacted, and well yields are highly variable, depending
upon the individual fractures and features that the borehole intersects.

8.4 Site Hydrogeology

Twelve groundwater monitoring wells (MW-1 through MW-12) have been installed as water
table monitoring wells part of the site investigation. Well locations are depicted on the site
map included as Figure 2. Two monitoring well (DMW-1 and DMW-2) were installed as a
vertical extent monitoring wells. Monitoring well construction records are included in
Appendix D. Well construction details are summarized in Table 5.

Monitoring wells were surveyed to obtain top of casing elevations using an arbitrary
benchmark elevation (100 feet above mean sea level) at the MW-1 top of casing. Depth to
groundwater measurements were collected from monitoring wells MW-1, MW-4 through
MW-12, DMW-1, and DMW-2 July 28, 2010. Due to vehicular obstructions over the
monitoring wells at the time of gauging, groundwater measurements were not collected for
monitoring wells MW-2 and MW-3; however, comparisons between those wells and nearby
wells for previous gauging events allowed relatively accurate indication of contour line
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
29
locations in those areas. Groundwater elevation data is included in Table 5. The depths to
water measured in the monitoring wells ranged 24.17 feet bls in MW-9 to 32.50 feet bls in
MW-1 when gauged on July 28, 2010. Based on data collected on July 28, 2010,
groundwater flows radially outward from the area of monitoring well MW-8 near the former
UST basin, which appears to be situated near a local hydrogeographic high point. A
groundwater elevation contour map with flow lines is included as Figure 5.

ATC conducted evaluation of hydraulic conditions using the gradient conditions from the flow
map. Horizontal gradient conditions appear to vary as calculated along flow paths from a
high gradient of 0.045 towards the east from the source area (generally from MW-8 toward
MW-11) to a low gradient of 0.0068, along a flow path that follows the “ridge” of higher
groundwater elevations toward the southwest. Whether groundwater would stay on that
path is debatable, but the ridge and the plume geometry have unusually close
correspondence, with the plume perhaps being slightly off-center of the ridge to the
southeast and south along its curved plan view aspect. A simple mean of horizontal
gradient conditions yields an average gradient of 0.026. Vertical gradients as calculated
using midpoint of the screens for the deeper wells and the midpoint of the water column for
the shallow wells yielded a downward vertical gradient of 0.012 between DMW-1 and MW-1
and a downward vertical gradient of 0.0081 between DMW-2 and MW-09. The lessening of
the vertical gradient in the second well pair is consistent with the location being closer to
the headwaters of stream branches to the west and northwest of the site. That is,
downward vertical gradients on upland areas, such as the site and nearby locations, reflect
recharge, whereas conditions tend to change to upward vertical gradients as distance to
surface water features decreases. A rough evaluation of deeper zone horizontal gradient as
estimated from a flow path roughly concurrent with the shallow flow paths between the
vicinity of DMW-1 and the vicinity of DMW-2 suggests a PWR horizontal gradient of
approximately 0.004.

ATC conducted slug testing conducted on two shallow zone monitor wells (MW-5 and MW-6)
and one of the deeper zone monitor wells (DMW-1). The data for slug in and slug out
testing were analyzed with AQTESOLV using the Horslov (1951) and Bouwer and Rice
(1976) solutions appropriate to unconfined aquifers. Consistent results from the various
methods were obtained. Both shallow zone wells had a hydraulic conductivity of 1.6 ft per
day, which of course is unusually consistent, and we expect that hydraulic conductivity in
the upper shallow aquifer would vary by a minimum of several feet per day and up to
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
30
perhaps an order of magnitude. The both solutions for the MW-1 slug testing yielded similar
results, with a simple mean of 27 ft per day.

By combining gradient information, the estimated hydraulic conductivities, and an assumed
effective porosity for both zones of 25 percent, ATC calculated the following advective
groundwater flow rates:
 Shallow zone flow rates ranging from approximately 0.045 ft per day (16 ft per year)
to approximately 0.30 ft per day (110 ft per year). The actual ranges may be from
less than 10 feet per year to greater than 150 ft per year.
 A deeper zone flow rate of 0.44 ft per day (160 ft per year). The actual ranges may
be from less than 50 feet per year to greater than 200 feet per year.
Of course other factors beyond direct groundwater flow affect contaminant fate and
transport, and ATC conducted modeling using the Bioscreen model from the US EPA and US
Air Force Center For Environmental Excellence. Bioscreen uses a Domenico analytical
solution to provide estimates of advective transport with dispersion and absorption, as well
as lumped parameter, first order decay evaluations of biodegradation. Source area
concentrations are then used to drive the mass-balance fate and transport output. ATC ran
several simulations to assess both upper and deeper shallow aquifer zones, with
assumptions of the lower flow rates for pathways to the southwest of the site. Calibrations
to dispersion and the first order decay lumped variable provided close agreement to existing
conditions, using an assumed 15 year transport time (thus an assumed initial significant
petroleum release from the Cajah’s UST system in the mid 1990s) and similar-to-current
source area conditions. ATC only modeled benzene during the evaluation because benzene
has the highest risk profile of impact at the site given the low 2L standard and high detected
concentrations, as well as benzene’s highly mobile character.

ATC then applied the model to longer time periods in transport to the southwest in both
zones and found that the impact might migrate an additional 50 to 100 feet in the next 15
years in the upper shallow zone, while varying input for various parameters (elapsed times,
source concentration, dispersion, retardation, and biological decay constants) provided little
change over time for the deeper shallow zone. Apparently, the high flow rates in the deeper
zone provide a mass-balance dampening for the model, which does not match the recent
observed increases in concentrations for this zone. A more complex model would be needed
to accurately evaluate the deeper shallow aquifer. The deeper model was also calibrated
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
31
using vertical maximums so that the bedrock aquifer detections at the maximum extent
were modeled.

Application of the model to existing conditions (the 15 year assumption and higher source
concentrations) for migration to the east, past MW-11, suggested that in the upper shallow
zone the plume may currently extend roughly 850 feet from the source area, and could
extend to approximately 1,100 feet, or 250 more feet, in another 15 years. For the deeper
zone, the model suggested that the plume may currently extend almost 1000 feet from the
source area, based on higher source concentrations and area on this side of the plume.
Changes in model variables again did not produce expansion of the plume through time in
the deeper shallow aquifer. With observed recent expansion to the southwest in the deeper
shallow aquifer, the model’s accuracy for the deeper shallow zone is questionable. The
model does suggest that water supply wells to the east-northeast could currently be
affected by the release.

Appendix F provides the slug out data for Bouwer and Rice for the shallow zone wells and
both solutions for DMW-1. Example run printouts of the Bioscreen Model are also provided
in Appendix F. Table 10A summarizes the deeper shallow aquifer hydraulic characteristics,
and Table 10B contains the shallow zone hydraulic information.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
32
9.0 DISCUSSION

9.1 Extent of Impacted Soil

The extent of impacted soil has been defined during the CSA activities. The footprint of the
soil impact extends between the site building and Connelly Springs Road, from south of the
site building northward to the middle of the yard of the adjacent property. That elongated
extent in plan view suggests that the utility excavations between the road and the former
tank basin may have acted as a conduit of higher permeability material that allowed some
horizontal migration. The impact was defined by petroleum hydrocarbons concentrations
being non-detected or detected below established soil-to-groundwater MSCC standards in
soil borings SB-4, SB10, SB-11, SB-14, SB-15, MW-5, and MW-11. The findings in SB-14
and SB-15 indicate that the impact did not follow the lines to the south and southwest or to
the north beyond the indicated limits of impact. Figure 4B shows the approximate extent of
soil impacted with petroleum hydrocarbons above the soil-to-groundwater MSCCs is
depicted.

9.2 Extent of Impacted Groundwater

The monitoring wells were installed in a phased approach to characterize the extent and
magnitude of dissolved phase petroleum hydrocarbons. Monitoring wells MW-1 through MW-4
were installed during the LSA investigations. Based on detection of petroleum contaminants
above 2L standards in monitoring wells MW-1 through MW-4, additional monitoring wells were
installed as part of the CSA. Monitoring wells MW-5 through MW-12 were installed to further
delineate the horizontal extent of impacted groundwater. Subsequent sampling of the new
monitoring wells indicated petroleum concentrations above 2L standards in monitoring wells
MW-1, MW-2, MW-5, MW-6, MW-7, MW-8, and MW-11. The dissolved petroleum constituents
in groundwater are shown in Figure 9.

Monitoring wells MW-1 and MW-8 are located in the source area, and based on groundwater
elevations indicate that the source area is located near a hydrogeographic high point. Thus, the
expected upgradient location of MW-11 actually represents an unexpected downgradient
condition, so that apparent groundwater impact to the northeast and east are not defined.
Partial bedrock groundwater delineation can be estimated in the vicinity of PW-2, due to trace
detections of impact. Conversely, areas to the northwest, west, southwest, south and
southeast have been defined in the upper shallow aquifer by the existing well network. The
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
33
deeper shallow aquifer had moderate impact in the source area, and DMW-2 provides virtual
definition of that zone’s impact to the southwest. A cluster of apparent bedrock water supply
wells (PW-1, PW-15, PW-16, and PW-18) to the south and southwest of the source area
provide information on the extent of bedrock impact in those directions.

Analytical data from the water sample collected from inactive water supply well PW-16 on
July 26, 2010, indicated petroleum constituents above 2L standards at approximately 400 feet
to the west-southwest from the source area. In addition, detectable concentrations (below 2L
standards) of petroleum constituents were identified in active water supply well PW-2, which is
located approximately 450 feet northeast of the source area, and active water supply well PW-
15, which is located approximately 600 feet west-southwest from the source area.
Furthermore, November 17, 2009, analytical results from water collected from PW-15 did not
indicate detectable levels of target analyte concentrations. Active pumping of PW-15 and PW-2
have likely provided drawdown induced increase in gradient conditions which accentuated
impact migration.

Concentrations of benzene, toluene, ethylbenzene, total xylenes, MTBE, naphthalene, and EDB
in groundwater are illustrated in Figures 10 through Figure 17, respectively. Figure 18
indicates the estimated vertical maximum extent of groundwater impact associated with the
site. The extent of petroleum impact in groundwater is also shown on the cross sections A-A’
and B-B’ attached as Figure 7 and Figure 8, respectively.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
34
10.0 CONCLUSIONS AND RECOMMENDATIONS

Based on the results of the CSA, ATC presents the following conclusions:
 The site meets the NCDENR criteria for a high-risk classification and is ranked as
H190D. Eighteen water supply wells have been identified within 1,500 feet of the site.
Five (5) potable wells were identified within 500 feet of the source area, of which one
(PW-2) in use as a drinking water source. One of these potable wells (PW-17) is
reportedly not in use and not accessible. Public water service is available and used at
most locations in the site and site vicinity. The nearest apparent surface water bodies
to the site are Stafford Creek located approximately 2,000 feet to the southwest of
the release area and unnamed branch of Little Gunpowder Creek approximately
2,500 feet to the east.
 Free phase petroleum product has not been detected at the site.
 The extent of petroleum-impacted soil has been defined and lies along Connelly
Springs Road to the north and south of the source area for approximately 140 feet
and extends from near the store to the road.
 Groundwater samples collected at the site during the LSA investigation contained
benzene, chloromethane, C5-C8 aliphatic hydrocarbons, and lead above 2L
Standards. Groundwater samples collected at the site during the CSA investigation
contained 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, IPE, isopropyl benzene,
MTBE, n-propylbenzene, 1,2-DCA, TCE, PCE, styrene, naphthalene, benzene,
toluene, ethylbenzene, total xylenes, EDB, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10
aromatics, and lead above 2L standards.
Based on these analytical results, a plume of impacted groundwater extends from the
former dispensers and tank pit to the south, southwest, north, east, and northeast.
The vertical maximum extent of the petroleum plume has been fully defined to the
northwest, west, southwest, south, and southeast, by using data from the monitoring
well network and water supply well data. Both the shallow and bedrock aquifer remain
largely undefined in to the east and northeast.
 Water samples from potable wells potable wells PW-1, PW-2, PW-15, PW-16, and
PW-18 contained detectable concentrations of petroleum constituents. In addition,
analytical results for PW-16 indicated concentrations of petroleum constituents above
established 2L standards.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
35
 Bioscreen modeling of plume migration indicates that impact may extend eastward in
the upper shallow zone to roughly 850 feet from the source area, and that expansion of
the plume over time in the upper shallow zone would be expected to the southwest and
to the east-northeast. The high flow characteristics of the deeper zone appeared to
adversely affected the model’s ability to accurately predict future migration, given
known plume migration to the southwest, at least when compared to the bedrock
aquifer conditions. However, the model could calibrate the overall distance-impact
conditions for vertical maximum impact to the southwest. When the model was applied
to eastward migration, given higher source conditions in that direction, current
migration of approximately 1,000 feet was indicated.
Because municipal water supply is available in the site vicinity, the potential exists to
reduce the risk classification of the site by connecting potentially affected locations with
active wells to municipal supply and abandoning the wells. Thorough modeling and
evaluation of site conditions and surface water assessment as discussed below might
also show potential for impact migration to surface water as unlikely. Additionally, vapor
intrusion monitoring of nearby basements and other parts of site buildings could
eliminate that exposure pathway as a potential risk. If those conditions were met, long-
period monitored attenuation of the impact, once fully assessed, might be possible
without further active remedial efforts.
Given status quo conditions of risk or even modest reduction of potential receptors,
including abandoning less than the full complement of potentially affected wells,
reduction impact would be needed by active remediation. Specifically, reduction of soil
impact below soil-to-groundwater MSCCs, and reduction of groundwater impact in
outlying plume areas would, at a minimum, be required. Soil vacuum extraction
combined with remedial injection of chemical oxidants in select areas might best affect
the soil impact, while a combined approach targeted to certain parts of the groundwater
plume might be required for effective remediation. Such techniques could include air
sparge and injection of chemical oxidation or biochemical enhancement agents, and
even advective control through groundwater pumping and treatment should be
evaluated as remedial alternatives.
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
36
Based on the CSA findings and data analysis, ATC recommends the following activities to be
performed within the pre-CAP monitoring framework:
 Evaluation of nearby structures for soil vapor intrusion, especially for structures with
basements;
 Water supply wells with detection of petroleum constituents or proximity to the plume
extent should be abandoned and those locations with active wells should be connected
to municipal supply. Such wells include PW-1 through PW-4 and PW-15 through PW-18.
 Water supply wells to the east-northeast of the site (PW-6 through PW-9) should be
monitored for petroleum constituents. Connection to municipal supply, followed by
abandonment, of any impacted, or imminently threatened, wells in that grouping
should be pursued.
 Assessment of shallow groundwater to the east and northeast of the site should be
conducted. We recommend collection of temporary well samples in an estimated 8
locations to confirm extent of migration, followed by installation of up to six additional
shallow zone monitoring wells to the east-northeast of the site, to define extent and
internal shallow zone plume geometry.
 Assessment of the deeper parts of the shallow aquifer (partially weathered rock – PWR)
and the bedrock aquifer should be expanded by pairing a bedrock well with DMW-2 and
installation of paired wells in the PWR and bedrock to the northeast of the site adjacent
to a shallow well that is used to establish internal plume geometry in that area.
 The entire monitoring well network and available water supply wells should be
monitored at the completion of the assessment.
 Observation of local apparent wet-weather drainages to establish actual flow conditions
and monitoring of any drainages that are found to contain flowing water. Stream
branches to the east, southeast, west and southwest of the site are candidates for
evaluation and potential monitoring.
 Expansion of the receptor survey to areas beyond the 1,500 foot radius, principally
northeast/east and west/southwest. If necessary based on the receptor investigations,
performance of more sophisticated groundwater modeling to assess threats farther
from the source area should be considered.
Based on the pre-CAP monitoring findings, ATC recommends completion of a corrective
action plan (CAP) appropriate to receptor conditions that exist after the pre-CAP efforts.

Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
37
11.0 PUBLIC NOTICE

Concentration of petroleum compounds above the 2L Standards have been detected at the
site. Pursuant to NCDENR guidelines, a copy of the CSA will be forwarded to:

Mr. Bobby White
Caldwell County Manager
P.O. Box 2200
Lenoir, North Carolina, 28645

and;

Ms. Denise Michaud
Health Director
Caldwell County Health Department
P.O. Box 2200
Lenoir, North Carolina, 28645
Former Cajah’s Mountain Superette (Incident No. 28649) ATC Associates of North Carolina, P.C.
CSA Report October 30, 2010
38
12.0 REFERENCES

Brown, P.M. and others. 1985. Geologic Map of North Carolina. North Carolina Geological
Survey.

Dawson, Karen J. and Istok, Jonathan D. Aquifer Testing. Boca Raton, Florida: CRC Press, LLC.

Driscoll, Fletcher G. 1986, Groundwater and Wells. Saint Paul, Minnesota: Johnson Division.

Fetter, C.W. 1994. Applied Hydrogeology. New York: Macmillan College Publishing Company.

Freeze, R. Allan and Cherry, John A. 1979. Groundwater. Prentice-Hall, Inc.

North Carolina Department of Environment and Natural Resources, Division of Waste
Management, Underground Storage Tank Section. August 15, 2008. Guidelines for
Assessment and Corrective Action.

North Carolina Department of Environment and Natural Resources - Division of Water
Resources www.ncwater.org/Data_and_Modeling/Ground_Water_Databases.

United States Department of Agriculture, Websoil website.

USGS 7.5-Minute Drexel Quadrangle Topographic Map, 1993.

TABLES
Table 1
UST System and Release Information
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
1 Gasoline None 4,000 Fiberglass 24'X64" Fiberglass Reinforced Plastic Early 1980s Removed 8/14/08 Yes
2 Gasoline None 8,000 Fiberglass 8'X21.4" Fiberglass Reinforced Plastic Early 1980s Removed 8/14/08 Yes
3 Gasoline None 8,000 Fiberglass 8'X21.4" Fiberglass Reinforced Plastic Early 1980s Removed 8/14/08 Yes
UST ID Number
Date of Release
8/14/08
Previous Content
Incident Number
28649
Material Released
Gasoline
Capacity (gallons)Current/Last
Content
Release confirmed during 8/08 excavation
Date Tank
Installed Status of Tank
Was Release
Associated With UST
System?
Tank DimensionsConstruction Details Description of Associated
Piping and Pumps
Description of Release
Table 2
UST Owner/Operator and Responsible Party Information
Cajah's Mountain Superette
1990 Conelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
Zip Telephone Number
27512 [phone]
Incident
Number 28649
Zip Telephone Number
27512 [phone]
Incident Number 28649
(m/dd/yy)
Street Address
City State Zip Telephone Number
Cary NC
Street Address
PO Box 5189, Cary, North Carolina 27512
City State
Facility ID Number
Name of Operator Dates of Operation / (m/dd/yy) to (m/dd/yy)
Cary Oil Company 4/2005-> 8-14-08
Cary Oil Company 4/2005-> 8-14-08
N/A
City State
Cary NC
Name of Other Responsible Party
Dates of Release(s)
UST ID Number(s)
UST ID Number(s) Facility ID Number
1, 2, and 3 0-004593
Street Address
PO Box 5189, Cary, North Carolina 27512
1, 2, and 3 0-004593
Name of Owner Dates of Ownership [(m/dd/yy) to (m/dd/yy)
Table 3
Public and Private Water Supply Well and Other Receptor Information
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
PW-1 Jimmie & Louise Beane / 1511 Bradshaw Terrace 1511 Bradshaw Terrace Lenoir 828-728-9368 Not in use Unknown Unknown 400 Downgradient
PW-2 Max & Brenda Lakey / P O Box 412, Rhodhiss, NC 1433 Brandon Road Lenoir 828-728-4677 Assumed used for potable water Unknown Unknown 450 Downgradient Well reportedly services more than one residence
PW-3 Henry Johnson / 1535 Bradshaw Terrace, Lenoir, NC 1535 Bradshaw Terrace Lenoir 828-728-5256 Not in use Unknown Unknown 775 Downgradient Not accessible - According to Mr. Johnson - well has been filled over the years with
sticks and rocks, and water is not accessible
PW-4 NC PIN Number 2746694262
Unknown; no owner information provided
Unknown; No address
information provided Lenoir NA Not in use Unknown Unknown 1,100 Likley in separate drainage
basin
PW-5 Maude Land / 1497 Land Street, Lenoir, NC 1497 Land Street Lenoir 728-9407 Not in use Unknown Unknown 1,000 Likley in separate drainage
basin
PW-6 Ryan Rozzelle / 186 Mountain Oak Lane, Hickory, NC 1418 Brandon Road Lenoir 495-3456 Assumed used for potable water Unknown Unknown 850 Likley in separate drainage
basin
PW-7 Helen Sullivan / 422 Hibriten Drive SE, Lenoir, NC Justin Lane (No address number) Lenoir NA Not in use Unknown Unknown 1,200 Likley in separate drainage
basin
PW-8 Brandon Apartments / 1415 N. Catwaba Church Avenue, Lenoir, NC 3715 Panda Lane Lenoir 728-9167 Assumed used for potable water Unknown Unknown 1,000 Likley in separate drainage
basin
PW-9 Randy Kestner / 4953 Horseshow Bend Road, Lenoir, NC 4953 Horseshoe Bend Road Lenoir NA Assumed used for potable water Unknown Unknown 1,100 Likley in separate drainage
basin
PW-10 Berry Kaylor / 3965 Greenwood Drive, Lenoir, NC 3965 Greenwood Drive Lenoir 728-6946 Not in use Unknown Unknown 1,475 Likley in separate drainage
basin
PW-11 Sherri Barnwell / 1499 Union Grove Road, Lenoir, NC 1499 Union Grove Road Lenoir 728-3412 Not in use Unknown Unknown 1,300 Likley in separate drainage
basin
PW-12 Roger Triplett / 1740 Taylorsville Road SE, Lenoir, NC 1512 Union Grove Road Lenoir NA Not in use Unknown Unknown 1,100 Likley in separate drainage
basin
PW-13 William Rudicil / 1520 Union Grove Road, Lenoir, NC 1520 Union Grove Road Lenoir NA Not in use Unknown Unknown 1,190 Likley in separate drainage
basin
PW-14 Karen Sanders / 1522 Union Grove Road, Lenoir, NC 1522 Union Grove Road Lenoir 726-1420 Not in use Unknown Unknown 1,210 Likley in separate drainage
basin
PW-15 Arnold & Wanda Correll / 1528 Bradshaw Terrace 1528 Bradshaw Terrace Lenoir 828-728-7497 In use Approx.90*** Unknown 600 Downgradient
PW-16 Stephen Icenhour ** 1518 Bradshaw Terrace Lenoir 828-572-1338 Assumed not in use Approx. 176**** Unknown 400 Downgradient Property provided municipal water by Baton Water
PW-17 Cecil Lindsay / 1980 Connelly Springs Road 1980 Connelly Springs Road Lenoir 828-728-2674 Not in use Unknown Unknown 200 Likley in separate drainage
basin
Well installed in 1961; Mary Lindsay (subject property owner) is POA; well is
beneath house and not accessible
PW-18 Jimmie & Louise Beane*** / 1511 Bradshaw Terrace 1514 Bradshaw Terrace Lenoir NA Not in use Unknown Unknown 240 Downgradient Property provided municipal water by Baton Water
N/A East N/A N/A Surface water 700 Downgradient Stream was not identified on USGS topgraphic map, but was depicted on Caldwell
County geographic Information website.
N/A West N/A N/A Surface water 500 Downgradient Stream was not identified on USGS topgraphic map, but was depicted on Caldwell
County Geographic Information website.
* assumed hydraulic gradient based on interpretation of topographic quadrangle map
Available phone numbers were for area code 828.
** residential property is currently leased; Stephen Icenhour is Real Estate agent for the residential property
** residential property is currently leased; The Beane's are the owner for the residential property
*** Depth of PW-15 was estimated by Mr. Correll.
**** On 7/26/10, due to difficulty encountered gauging depth of the two foot diameter well with an o/w interface meter, it was estimated that depth of Icenhour water supply well (PW-16) was approximately 176 ft bgs, as the meter appeared to "lay flat" at that depth.
N/A = Not Applicable
Unnamed intermittent stream
Unnamed intermittent stream
Description Phone Number Usage
Phone Number Well Screen Interval
(ft)Well Use
CommentApprox. distance from
source area of release (ft)
Up/Down/ or
Crossgradient*
Approx. distance from
source area of release (ft)
Up/Down/Crossgradient/Ot
her*CommentPotable Well ID Well Depth
(ft bgs)
Receptor ID Location Contact
Property Owner Contact Information Property Address City
Table 4
Property Owners/Occupants and Land Use Information
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
Site Mary Lindsay R-20 / Convenience Store (former gas station)
2746795343 1990 Connelly Springs Road 127 Dell Circle, Hudson, NCenor,
Adjacent to North Cecil and Ruth Lindsay, Mary Lindsay (POA) R-20 / Residence
2746794580 1980 Connelly Springs Road
eno r,
Adjacent Northeast (opposite Connelly Springs Road)Philip Yott RA-20 / Residence
2746890460 1989 Connelly Springs Road
eno r,
Adjacent East (opposite Connelly Springs Road)Chuck Triplett RA-20 / Residence
2646799380 1995 Connelly Springs Road 1130 Rosedale Lane SW, Lenoir, NC
eno r,
Adjacent Southeast (opposite Connelly Springs Road)Cajah's Mountain Park RA-20 / Mobile Home Park
2746890106 2003 Connelly Springs Road P O Box 114, Hudson, NCenor,
Adjacent to South Frosty Frez (c/o Mary Lindsay)onne y pr ngs oa e rc e,u son,
2746795237 Lenoir, NC
Adjacent to West Jimm e eane RA-20 / Residence
2746793289 1514 Bradshaw Terrace 1511 Bradshaw Terrace, Lenoir, NCenor,
Modified as of 12-2008.
R-20 and RA-20 refer to residential zoning
B-1 refers to business zoning
B-1 /Frosty Frez Restaurant and separate associated
office building
Tax Parcel Pin # (and well ID # if applicable) Property Location and Address Owner's Name and Address (if different) Zoning/Land Use
Table 5
Monitoring Well Construction and Groundwater Elevation Information
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
Well ID Date of
Installation
Date Liquid
Gauged
Well Diameter
(inches)
Screen Slot
(inches)
Total Depth (ft) Screened Interval
(feet)
Top of Casing
Elevation (feet)
Depth to
Groundwater (ft)
Depth To
Product (ft)
Prodcut
Thickness (ft)
Groundwater
Elevation (ft)
3/13/2008 36.00 --- --- 64.00
7/28/2010 32.50 --- --- 67.50
3/13/2009 35.66 --- --- 63.90
7/28/2010 NM --- --- N/A
3/13/2009 26.92 --- --- 63.27
7/28/2010 NM --- --- N/A
3/13/2009 27.85 --- --- 64.32
7/28/2010 24.65 --- --- 67.52
11/16/2009 36.05 --- --- 64.13
7/28/2010 32.58 --- --- 67.60
11/16/2009 35.85 --- --- 63.86
7/28/2010 32.30 --- --- 67.41
11/16/2009 34.86 --- --- 63.64
7/28/2010 31.20 --- --- 67.30
11/16/2009 34.60 --- --- 63.86
7/28/2010 30.10 --- --- 68.36
MW-9 7/27/2010 7/28/2010 2 0.010 30 15-30 90.82 24.17 --- --- 66.65
MW-10 7/27/2010 7/28/2010 2.00 0.010 40 25-40 98.34 32.16 --- --- 66.18
MW-11 7/27/2010 7/28/2010 2.00 0.010 40 25-40 97.76 31.27 --- --- 66.49
MW-12 7/27/2010 7/28/2010 2 0.010 40 25-40 97.33 31.59 --- --- 65.74
11/16/2009 36.24 --- --- 63.97
7/28/2010 33.10 --- --- 67.11
DMW-2 7/26-27/2010 7/28/2010 2 0.010 95 90-95 90.85 24.73 --- --- 66.12
Note:
MW-1 assumed to be 100 feet for top of casing survey
"---" means no measurable product detected
NM on 7-28-10 Monitring well was not accessible
N/A = Not applicable
211/4-5/09 100.2170-75750.010
11/5/2009
11/4/2009
11/5/2009
11/5/2009 44
44
45
45
92.1725-40
2
2
2
2
0.010
0.010
0.010
0.010
25-45 99.71
100.1830-45
29-44 98.46
98.5029-44
3/10/2009 2
400.01023/10/2009
90.1920-35350.010
460.01023/10/2009
MW-8
DMW-1
12/4/2008 100.0033-48480.0102
99.5631-46
MW-1
MW-7
MW-5
MW-4
MW-3
MW-2
MW-6
Table 6
Summary of UST Closure and Over-Excavation Soil Sampling Data
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, Caldwell County, North Carolina
Facility ID Number: 0-004593Incident Number: 28649
VPH 8260 COMPOUNDS REPORTED ABOVE METHOD DETECTION LIMITS
SA
M
P
L
E

L
O
C
A
T
I
O
N
SA
M
P
L
E

D
E
P
T
H

(
f
t
)
SA
M
P
L
E

D
A
T
E
FI
E
L
D

S
C
R
E
E
N
I
N
G

R
E
S
U
L
T
S
GR
O
C5
-
C
8
C9
-
C
1
0
C9
-
C
1
2
BE
N
Z
E
N
E
TO
L
U
E
N
E
ET
H
Y
L
B
E
N
E
Z
E
N
E
TO
T
A
L

X
Y
L
E
N
E
S
MT
B
E
CA
R
B
O
N

D
I
S
U
L
F
I
D
E
ME
K

(

2
-
B
U
T
A
N
O
N
E
)
AC
E
T
O
N
E
DI
I
S
O
P
R
O
P
Y
L

E
T
H
E
R
2-
H
E
X
A
N
O
N
E

N/A 10
Soil to Groundwater MSCC 72 34 3255 0.0056 7.3 4.6 5 0.92 4.3 17 2.8 0.37 1.9
Residential MSCC 939 469 9386 18 3,200 1,560 3,129 213 1,564 9,385 1,564 156 625
Industrial MSCC 24528 12264 245280 164 82,000 40,000 81,760 1,908 40,880 245,280 40,880 4,088 16,352
T1-A GASOLINE UST-1 10 08/13/08 1556 1500 --- --- --- --- --- --- --- --- --- --- --- --- ---
T1-B GASOLINE UST-1 10 08/13/08 1129 1700 --- --- --- --- --- --- --- --- --- --- --- --- ---
T1-C GASOLINE UST-1 10 08/13/08 1101 110 --- --- --- --- --- --- --- --- --- --- --- --- ---
T2-A GASOLINE UST-2 12 08/14/08 1493 440 --- --- --- --- --- --- --- --- --- --- --- --- ---
T2-B GASOLINE UST-2 12 08/14/08 1246 390 --- --- --- --- --- --- --- --- --- --- --- --- ---
T2-C GASOLINE UST-2 12 08/14/08 83 0.78 --- --- --- --- --- --- --- --- --- --- --- --- ---
T3-A GASOLINE UST-3 12 08/14/08 1400 630 --- --- --- --- --- --- --- --- --- --- --- --- ---
T3-B GASOLINE UST-3 12 08/14/08 1220 100 --- --- --- --- --- --- --- --- --- --- --- --- ---
T3-C GASOLINE UST-3 12 08/14/08 100 0.35 --- --- --- --- --- --- --- --- --- --- --- --- ---
D1 GASOLINE DISPENSER-1 2.5 08/13/08 1500 45 --- --- --- --- --- --- --- --- --- --- --- --- ---
D2 GASOLINE DISPENSER-2 2.5 08/13/08 8 1.3 --- --- --- --- --- --- --- --- --- --- --- --- ---
D3 GASOLINE DISPENSER-3 2.5 08/13/08 10 <0.12 --- --- --- --- --- --- --- --- --- --- --- --- ---
TP-SW-1 TANK PIT SIDEWALL 10 08/14/08 50 --- <13 3.8 <6.5 <0.0012 <0.0061 <0.0061 <0.0061 <0.0012 <0.0061 <0.025 <0.12 <0.0061 <0.012
TP-SW-2 TANK PIT SIDEWALL 10 08/14/08 50 --- <14 <2.1 <7.1 0.0067 0.0062 0.056 0.272 0.059 <0.0065 <0.026 <0.13 <0.0065 0.056
TP-SW-3 TANK PIT SIDEWALL 10 08/14/08 <1 --- <13 4.1 <6.4 0.0021 0.016 <0.006 0.014 <0.0012 <0.06 <0.024 <0.14 <0.006 <0.012
TP-SW-4 TANK PIT SIDEWALL 16 08/14/08 136 --- <13 <2 <6.7 0.005 0.0077 <0.0072 0.0013 0.0053 0.011 <0.029 <0.14 <0.0072 <0.014
TP-B TANK PIT BASE 16 08/14/08 1497 --- 68 99 130 <0.039 0.57 1.5 7.8 <0.078 <0.39 <1.6 <7.8 <0.39 <0.78
D1-SW-1 DISPENSER-1 SIDEWALL 8 08/15/08 1000 --- <12 3.3 <5.8 <0.0011 <0.0056 <0.0056 0.016 <0.0011 0.028 <0.022 <0.14 <0.0056 <0.011
D1-SW-2 DISPENSER-1 SIDEWALL 8 08/15/08 1492 --- <13 6.4 10 0.29 0.23 1 5 0.29 0.0071 0.021 0.1 0.007 0.01
D1-SW-3 DISPENSER-1 SIDEWALL 8 08/15/08 14 --- <11 <1.7 <5.7 0.010 0.0097 0.026 0.194 <0.0012 0.013 <0.023 <0.12 <0.0058 <0.012
D1-SW-4 DISPENSER-1 SIDEWALL 8 08/15/08 50 --- <11 3.4 <5.5 <0.027 0.33 1.9 9.2 <0.054 <0.27 <1.1 <5.4 <0.27 <0.54
D1-B DISPENSER-1 BASE 8 08/15/08 1377 --- <15 <2.2 <7.5 0.015 <0.0082 <0.0082 0.015 0.24 <0.0082 <0.033 <0.16 <0.0082 <0.016
STOCKPILE N/A 08/14/08 1500 200 --- --- --- --- --- --- --- --- --- --- --- --- ---
STOCKPILE N/A 08/14/08 1730 810 --- --- --- --- --- --- --- --- --- --- --- --- ---
STOCKPILE N/A 08/15/08 900 24 --- --- --- --- --- --- --- --- --- --- --- --- ---
NOTES:
Analytical units are in mg/kg (parts per million-ppm).
Gasoline Range Organics (GRO) were analyzed by EPA Method 8015B.
--- = Not Analyzed for specified parameter
N/A = Not Applicable
Concentrations in bold exceed established state action levels
MSCC - Maximium Soil Contaminant Concentration
S1
S2
S3
SA
M
P
L
E

I
D

NCDENR Action Levels
CL
O
S
U
R
E

S
A
M
P
L
E
S
OV
E
R
-
E
X
C
A
V
A
T
I
O
N

S
A
M
P
L
E
S
Table 7
Summary of LSA Soil Sampling Data
Cajah's Mountain Superette
1990 Conelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
VPH
SA
M
P
L
E

L
O
C
A
T
I
O
N
SA
M
P
L
E

D
E
P
T
H

(
f
t
)
SA
M
P
L
E

D
A
T
E
FI
E
L
D

S
C
R
E
E
N
I
N
G

R
E
S
U
L
T
S
C5
-
C
8
C9
-
C
1
0
C9
-
C
1
2
Ac
e
t
o
n
e
Ca
r
b
o
n

D
i
s
u
l
f
i
d
e
MT
B
E
Be
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
l
u
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Soil to Groundwater 72 34 3,255 2.8 4.3 0.92 0.0056 4.6 7.3 5
Residential MSCC 939 469 9,386 1564 1564 213 18 1560 782 3129
Industrial MSCC 24,528 12,264 245,280 40880 40880 1908 164 40000 20440 81760
MW-1 8'-10' 8-10 12/04/08 298 <3.4 2.3 <3.9 0.23 0.01 0.16 0.1 0.025 0.0048 0.0767
MW-1 18'-20' 18-20 12/04/08 105 <3.5 <1.2 <4.1 NA NA NA NA NA NA NA
MW-1 28'-30' 28-30 12/04/08 99 <3.1 <1 <3.6 NA NA NA NA NA NA NA
MW-1 38'-40' 38-40 12/04/08 19 <4.2 <1.4 <5 <6.8 <0.34 <0.068 0.036 <0.068 <0.068 <0.068
NOTES:
Analytical units are in mg/kg (parts per million-ppm).
N/A = Not Applicable
Concentrations in bold and hi-lited exceed established state action levels
MSCC - Maximium Soil Contaminant Concentration
ND - Not detected above method detection limits
SA
M
P
L
E

I
D

8260 COMPOUNDS REPORTED ABOVE METHOD DETECTION LIMITS
FORMER GASOLINE
DISPENSER AREA
Table 8
ummary o o amp ng ata
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593ncenumer:
VPH
SA
M
P
L
E

D
A
T
E
SA
M
P
L
E

L
O
C
A
T
I
O
N
SA
M
P
L
E

D
E
P
T
H

(
f
t
)
FI
E
L
D

S
C
R
E
E
N
I
N
G

R
E
S
U
L
T
S
C5
-
C
8
C9
-
C
1
0
C9
-
C
1
2
Ac
e
t
o
n
e
2-
B
u
t
a
n
o
n
e

(
M
E
K
)
2-
H
e
x
a
n
o
n
e
4-
M
e
t
h
y
l
-
2
-
P
e
n
t
a
n
o
n
e
Ca
r
b
o
n

D
i
s
u
l
f
i
d
e
Na
p
h
t
h
a
l
e
n
e
MT
B
E
Be
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
To
l
u
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Soil to Groundwater 72 34 3,255 2.8 17 1.9 NE 4.3 0.16 0.92 0.0056 4.6 7.3 5
Residential MSCC 939 469 9,386 1,564 9,385 625 NE 1,564 313 213 18 1,560 782 3,129
Industrial MSCC 24,528 12,264 245,280 40,880 245,280 16,352 NE 40,880 8,176 1,908 164 40,000 20,440 81,760
MW-1 8'-10' 12/04/08 8-10 298 <3.4 2.3 <3.9 0.23 <0.024 <0.012 <0.012 0.01 NA 0.16 0.1 0.025 0.0048 0.0767
MW-1 18'-20' 12/04/08 18-20 105 <3.5 <1.2 <4.1 NA NA NA NA NA NA NA NA NA NA NA
MW-1 28'-30' 12/04/08 28-30 99 <3.1 <1 <3.6 NA NA NA NA NA NA NA NA NA NA NA
MW-1 38'-40' 12/04/08 38-40 19 <4.2 <1.4 <5 <6.8 <1.4 <0.68 <0.68 <0.34 NA <0.068 0.036 <0.068 <0.068 <0.068
SB-1 11/04/09
SOUTHEAST AND ADJACENT TO
DMW-1 28-30 139 <4.9 <1.6 <5.7 <0.12 0.035 0.033 0.018 <0.059 NA 0.046 0.0093 <0.059 <0.059 <0.059
SB-2 11/04/09
SOUTH AND ADJACENT TO MW-
1 18-20 169 <3.9 <1.3 <4.6 0.18 0.17 0.099 0.041 <0.0064 NA 0.062 0.012 <0.0064 <0.0064 <0.0064
SB-3 11/05/09 BETWEEN MW-1 AND MW-8 30-34 2599 39 250 270 <5.9 <1.2 <0.59 <0.59 <0.29 NA <0.29 <0.29 10 6.7 52
SB-4 11/05/09
FORMER TANK PIT AT STORE
CORNER 25-30 176 <3.8 <1.3 <4.4 0.21 0.029 <0.012 <0.012 <0.006 NA <0.006 <0.006 <0.006 <0.006 <0.006
SB-5 11/05/09
CENTRAL AREA OF FORMER
TANK PIT 33-35 1,905 <3.9 17 21 <6.5 <1.3 <0.65 <0.65 <0.32 NA <0.32 <0.32 1.1 0.56 5.9
MW-5 11/05/09
NORTH EDGE OF FORMER TANK
PIT AND SITE 25-30 45.5 <3.7 <1.2 <4.3 0.12 <0.024 <0.012 <0.012 <0.006 NA <0.006 <0.006 <0.006 <0.006 <0.00597
MW-8 11/05/09 EAST SIDE OF SITE 25-30 3,278 33 170 190 <1.1 <2.3 <1.1 <1.1 <0.57 NA <0.57 <0.57 24 25 123
MW-11 07/27/10 TRIPLETT PROPERTY 25' 13.3 <0.38 <0.64 6.5 NA NA NA NA NA <0.0076 <0.0076 <0.0015 <0.0015 <0.0076 <0.0029
SB-10 20' 07/27/10 NW OF MW-7 20' 23.0 <4 <0.67 <4.7 NA NA NA NA NA <0.0058 <0.0058 <0.0012 <0.0012 <0.0058 <0.0012
SB-11 25' 07/27/10 SE OF MW-6 25' 15.2 <3.8 1.2 4.9 NA NA NA NA NA <0.0062 <0.0062 <0.0012 <0.0012 <0.0062 <0.0012
SB-12 15' 07/27/10 S OF MW-3 15' 0.4 <4.1 <0.68 <4.7 NA NA NA NA NA <0.0066 <0.0066 <0.0013 <0.0013 <0.0066 <0.0013
SB-14 25' 07/27/10 SE OF SB-11 25' 10.7 <4.1 <0.68 <4.7 NA NA NA NA NA <0.0069 <0.0069 <0.0014 <0.0014 <0.0069 <0.0014
SB-15 25' 07/28/10
NORTH ADJ. PROPERTY -
LYNDSAY 25' 23.9 <4.1 <0.69 <4.8 NA NA NA NA NA <0.0073 <0.0073 0.002 <0.0015 <0.0073 0.012
NOTES:
nalytical units are in mg/kg (parts per million-ppm).
N/A = Not Applicableoncenraonsnbo an -e excee es a s e s a eac on eves
MSCC - Maximium Soil Contaminant Concentration ND - Not detected above method detection limits
NA = Not Analyzed for specified parameter
SA
M
P
L
E

I
D

FORMER GASOLINE DISPENSER
AREA
8260 COMPOUNDS REPORTED ABOVE METHOD DETECTION LIMITS
Table 9
Summary of Groundwater Analytical Data (LSA and CSA Phases)
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
EPA
Method
EPA
Method
C5-C8
Aliphatics
Carbon
Fraction Class
C9-C22
Aliphatics
Carbon
Fraction Class
C
5
-
C
8
C
9
-
C
1
0
B
r
o
m
o
d
i
c
h
l
o
r
o
m
e
t
h
a
n
e
n
-
B
u
t
y
l
b
e
n
z
e
n
e
s
e
c
-
B
u
t
y
l
b
e
n
z
e
n
e
C
h
l
o
r
o
f
o
r
m
C
h
l
o
r
o
m
e
t
h
a
n
e
1
,
1
-
D
i
c
h
l
o
r
o
e
t
h
a
n
e
1
,
2
,
-
D
i
c
h
l
o
r
o
e
t
h
a
n
e
I
s
p
r
o
p
y
l
b
e
n
z
e
n
e
I
s
o
p
r
o
p
y
l

E
t
h
e
r
p
-
I
s
o
p
r
o
p
y
l
t
o
l
u
e
n
e
M
T
B
E
N
a
p
h
t
h
a
l
e
n
e
n
-
P
r
o
p
y
l
b
e
n
z
e
n
e
S
t
y
r
e
n
e
T
e
t
r
a
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(
P
C
E
)
T
r
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e

(
T
C
E
)
1
,
2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1
,
3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
B
e
n
z
e
n
e
T
o
l
u
e
n
e
E
t
h
y
l
b
e
n
z
e
n
e
T
o
t
a
l

X
y
l
e
n
e
s
T
o
t
a
l

B
T
E
X
E
D
B
L
e
a
d
12/10/2008 180 1.6 42 178.4 0.65 0.4 <0.1 11 3.3 <0.1 <0.2 0.34 0.24 <0.1 65 <0.1 0.63 <0.1 <0.2 <0.1 3.1 1.6 10 2.5 1.2 3.3 17 <0.022 110
11/17//09 1,300 35 61 1,265 <0.1 0.69 <0.1 13 <0.1 <0.1 <0.2 0.46 <0.1 0.53 18 <0.1 0.83 <0.1 <0.2 <0.1 2.9 2.1 17 5.1 0.75 9.5 32.4 <0.022 149
3/13/2009 605 540 <100 65 1.8 1.1 <0.50 16.2 <1.0 <0.5 <0.50 1.7 2.8 <0.50 72.1 <0.50 3.7 <0.50 <0.50 <0.50 29.3 10.7 151 80.8 11.6 116.1 359.5 <0.02 22.7
11/17//09 2,600 460 660 2,140 <0.1 <0.1 <0.1 16 <0.1 <0.1 0.74 3.9 11 3.2 340 3.8 6.3 <0.1 <0.2 <0.1 110 38 630 170 16 320 1,136 <0.023 22.4
3/13/2009 <100 <100 <100 ND <0.50 <0.50 <0.50 0.68 <1.0 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --- <0.02 19.5
11/17//09 <30 <10 <35 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 --- <0.022 165
3/13/2009 <100 <100 <100 ND <0.50 <0.50 <0.50 <0.50 <1.0 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.60 <0.50 <0.50 0.6 <0.02 25.9
11/17//09 <30 <10 <35 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 0.54 <0.2 0.41 0.95 <0.022 185
MW-5 11/17//09 800 50 130 750 <0.1 <0.1 <0.1 7.7 <0.1 <0.1 <0.2 0.87 <0.1 <0.1 1.7 1.1 1.4 <0.1 <0.2 <0.1 12 3.7 35 88 9.9 61 193.9 <0.022 <10
MW-6 11/17//09 1,200 990 410 210 <0.1 0.79 0.89 <0.1 <0.1 <0.1 0.34 3.7 3 1.9 130 1.2 7.2 <0.1 <0.2 <0.1 23 4 370 180 39 168 757 <0.023 45.2
MW-7 11/17//09 4,200 550 1,000 3,650 <0.1 3.2 <0.1 12 <0.1 <0.1 1.4 7.4 12 2.6 290 5.4 9.3 0.58 <0.2 <0.1 100 31 920 890 78 520 2,408 <0.023 <10
MW-8 11/17//09 31,000 4,100 8,700 26,900 <5 <5 <5 <5 <5 <0.5 39 25 <5 <5 <10 130 61 29 27 27 580 130 1,900 17,000 900 4,600 24,400 2.8 <10
MW-9 7/28/2010 <30 <35 <5 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.2 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 --- <0.021 23.7
MW-10 7/28/2010 <30 <35 <5 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.2 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 0.12 1.4 <0.1 0.29 1.8 <0.021 <10
MW-11 7/28/2010 75,000 5,700 24,000 69,300 <50 <50 <50 <50 <50 <50 <100 110 190 <50 5,600 700 270 84 <100 <50 1,800 520 15,000 37,000 2,800 14,100 68,900 3.1 19.3
MW-12 7/28/2010 <30 <35 <5 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.2 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 2.7 2.7 <0.021 15.2
DMW-1 11/17//09 1,300 180 230 1,120 <0.1 1.2 <0.1 7.9 <0.1 <0.1 <0.2 2.6 2.3 2.1 450 3.4 3.2 <0.1 <0.2 <0.1 41 <0.1 140 0.41 3.4 56 199.8 <0.022 <10
DMW-2 7/28/2010 <30 <35 <5 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.2 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 1.4 2 <0.1 3.1 6.5 <0.021 <10
PW-1 (BEANE1)7/26/2010 NA NA NA N/A <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.2 <0.2 <0.1 <0.1 <0.2 0.84 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 0.12 <0.1 <0.1 2.7 2.8 <0.023 NA
PW-2 7/26/2010 NA NA NA N/A <0.1 <0.1 <0.1 0.31 <0.2 0.1 <0.2 <0.2 <0.1 <10 6 0.34 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 0.1 <0.021 NA
11/17//09 <30 <10 <35 ND <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 --- <0.022 NA
7/26/2010 NA NA NA N/A <0.1 <0.1 <0.1 1.3 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 1.2 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 --- <0.022 NA
11/17//09 440 80 220 360 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 0.5 <0.1 <0.1 <0.1 2.7 1.1 0.46 <0.2 <0.1 9.6 2.2 12 170 16 81 279 <0.022 NA
7/26/2010 NA NA NA N/A <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 1.4 4.3 <0.2 3.9 9.6 <0.021 NA
PW-18
(BEANE2)7/26/2010 NA NA NA N/A <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.2 <0.1 --- <0.022 NA
400 N/A 200 700 0.6 70 70 70 3 6 0.4 70 70 NE 20 6 70 70 0.7 3 400 400 1 600 600 500 N/A 0.02 15
NE N/A NE NE NE 6,900 8,500 70,000 2,600 6,000 380 25,000 70,000 NE 20,000 15,500 30,000 100,000 700 2,800 28,500 25,000 5,000 257,500 84,500 87,500 N/A 50 15,000
NE N/A NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE 51 520 # 11 780 # N/A NE NE
1. All measurements are in micrograms per liter (ug/L).
2. NC 2L GW Standard = Title 15A NCAC 2L .0202 Groundwater Standard. (Amended Effective January 1, 2010) 11. Groundwater samples were analyzed by MADEP-VPH; and EPA Method 6200 for volatiles (including MTBE and IPE), except EDB, which was analyzed by EPA Method 504.1
3. "<" or "---" = Not detected above method detection limit. 12. Analytical table indicates target analyte concentrations reported above method detection limits.
4. GCL = Gross Contaminant Level established by NCDENR. 13. NA = Not Analyzed for specified parameter
5. Target analyte concentrations detected above 2L Groundwater Standards are bolded. 14. Beane 1) and 2) refer to two separate water supply wells, each located on different parcels from each other, but owned by the same entity.
6. Target analyte concentrations detected above GCLs are bolded and italicized. 15. Methylene chloride, a known laboratory contaminant, was reported at 0.2 ug/L for water collected from PW-16 on July 26, 2010.
7. (#) Surface water quality standard based on North Carolina NC General Permit NCG510000 Technical Bulletin September 2 16. N/A = Not Applicable
8. MTBE = Methyl-tert-butyl ether 17. EDB = Ethylene dibromide
9. NE = Not Established. 18. C9-C18 Aliphatic Carbon Farction Class = C9-C10 chain aliphatics - C9-C12 chain aliphatics
C9-C18
Aromatics
Carbon
Fraction Class

C
9
-
C
1
2
EPA METHOD 6200B
(Target analytes reported above method detection limits)
VPH
GCLs
NC 2L GW Standards
MW-3
MW-4
PW-15
(CORRELL)
PW-16
(ICENHOUR)
NC 2B Standard
BORING I.D. DATE SAMPLED
MW-1
MW-2
Table 10A
Aquifer Charcteristics
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
DMW-1 (Bouwer Rice)
DMW-1 (Hvorslev)
Geometric Mea
Calculated Values
Average Hydraulic Conductivity (feet/day) 27.49
Aquifer Thickness (feet) 41.92
Average Groundwater Flow Velocity (feet/day) 0.44
Average Vertical Groundwater Gradient 0.010
Average Horizontal Groundwater Gradient (feet/foot) 0.0040
Effective Porosity (dimensionless) 0.25
Depth to Groundwater 33.08
27.49
Paramete
Well Identification Hydraulic Conductivity (feet per day)
26.39
28.64
Table 10B
Aquifer Charcteristics
Cajah's Mountain Superette
1990 Connelly Springs Road
Lenoir, North Carolina
Facility ID Number- 0-004593
Incident Number: 28649
MW-5 (Bouwer Rice)
MW-6 (Bouwer Rice)
Geometric Mean
Upper Shallow Aquifer - Highest Estimated Flow Velocity
Calculated Values
Average Hydraulic Conductivity (feet/day) 1.645
Aquifer Thickness (feet) 42.20
Maximum Groundwater Flow Velocity (feet/day) 0.2961
Maximum Groundwater Flow Velocity (feet/year) 108.08
Average Vertical Groundwater Gradient 0.010
Maximum Horizontal Groundwater Gradient (feet/foot) 0.045
Effective Porosity (dimensionless) 0.25
Upper Shallow Aquifer - Lowest Estimated Flow Velocity
Calculated Values
Average Hydraulic Conductivity (feet/day) 1.645
Aquifer Thickness (feet) 42.20
Minimium Groundwater Flow Velocity (feet/day) 0.0447
Minimium Groundwater Flow Velocity (feet/year) 16.33
Average Vertical Groundwater Gradient 0.010
Minimum Horizontal Groundwater Gradient (feet/foot) 0.0068
Effective Porosity (dimensionless) 0.25
Upper Shallow Aquifer - Median Estimated Flow Velocity
Calculated Values
Average Hydraulic Conductivity (feet/day) 1.645
Aquifer Thickness (feet) 42.20
Average Groundwater Flow Velocity (feet/day) 0.1711
Average Groundwater Flow Velocity (feet/year) 62.44
Average Vertical Groundwater Gradient 0.010
Average Horizontal Groundwater Gradient (feet/foot) 0.026
Effective Porosity (dimensionless) 0.25
Parameter
1.645
Parameter
Well Identification Hydraulic Conductivity (feet per day)
1.647
Parameter
1.643

FIGURES
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
SITE
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TIT
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TI
T
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E
PR
O
J
E
C
T

N
O
.
NO
T
E
S
:
DA
T
E
TIT
L
E
SC
A
L
E
RE
V
.

B
Y
PR
E
P
.

B
Y
CA
D

F
I
L
E

APPENDIX A

NOTICE OF REGULATORY REQUIREMENTS AND
PRE-APPROVAL TASK AUTHORIZATIONS

APPENDIX B

RETURNED WATER SUPPLY WELL INFORMATION FORMS

APPENDIX C

STANDARD OPERATING PROCEDURES

METHODS
Monitoring Well Installation

During this CSA, Type II monitoring well installations were completed using hollow-stem auger
methods or air rotary methods in accordance with ASTM: D1452. Type III monitoring well installations
were completed using air rotary methods in accordance with ASTM: D1452. Type II and Type III
monitoring wells were completed with varying amounts of 2-inch diameter PVC well casing and 2-inch
diameter machine-slotted well screen. The wells were developed using an electric pump.

Groundwater Levels

During the CSA, groundwater level measurements were obtained by using an electronic
sounding/interface detection device which registers when a probe makes contact with petroleum
product and/or water. Depth to groundwater measurements were obtained by lowering the device into
the well until it indicated that the water surface had been encountered, at which point a measurement
was taken at the top of the well casing. Measurements were recorded to the nearest 0.01 foot.

Groundwater Sampling

During this CSA, groundwater samples were collected using new, dedicated plastic bailers at each
monitoring well. Before obtaining a sample, a minimum of three well volumes of groundwater were
evacuated to ensure collection of a sample representative of the in-situ groundwater conditions.
Samples were collected using dedicated bailers, transferred to containers supplied by the laboratory,
and placed in an ice filled cooler.

Chemical Analysis

During this CSA, samples were shipped by overnight courier under chain-of-custody to Southern
Petroleum Laboratory in Scott, Louisiana. One or more collected soil samples were analyzed for
volatile organics by EPA Method 8260 including MTBE by 5035 preparation and carbon fraction
classes by MADEP VPH. The soil sample collected from boring MW-8 was analyzed for volatile
organics by EPA Method 8260 including MTBE. Groundwater samples were collected for analysis of
purgeable halocarbons and aromatics by combined EPA Method 6200B including IPE and MTBE; EDB
by EPA Method 504.1; carbon fraction classes by MADEP-VPH; and lead by EPA Method 3030C.

APPENDIX D

SOIL BORING LOGS AND WELL CONSTRUCTION RECORDS
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:SB-1
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/4/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3.0
4.0
3-5 2640 5.0
6.0
7.0
8.0 Red SILT; dry to moist
9.0
8-10 125 10.0
11.0
12.0
13.0 Brick red, white, and tan micaceous SILT; dry to moist
14.0
13-15 38.6 15.0
16.0
17.0
18.0
19.0 Pink, white, and tan micaceous SILT; moist
18-20 25.0 20.0
21.0
22.0
23.0
24.0
23-25 52.0 25.0
26.0
27.0
28.0 Tan, yellow, white, and ornage micaceous SILT; moist
29.0
*28-30*139 30.0
31.0
32.0
33.0
34.0 Brown and orange micaceous SILT with compressed layer of mica flakes (PWR)
33-35 18.1 35.0
Terminated boring at 35' (refusal at 35')
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: 2' SS
REMARKS: Total boring depth: 35' bgs; surface to 5' bgs post-holed
Dark brown, black, and dark gray Clayey SILT and some clay; moist
BENTONITE
BENTONITE
DRILLING METHODS
SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
*SAMPLE COLLECTED
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:SB-2
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/4/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3.0
4.0
3-5 22.0 5.0
6.0
7.0
8.0 Red SILT; dry to moist
9.0
8-10 65.8 10.0
11.0
12.0
13.0 Brick red, white, and tan micaceous SILT; dry to moist
14.0
13-15 20.3 15.0
16.0
17.0
18.0
19.0
*18-20*169 20.0 Pink, white, and tan micaceous SILT; moist
21.0
22.0
23.0
24.0
23-25 22.0 25.0 SSA; moist to wet
26.0
27.0
28.0
29.0
28-30 7.0 30.0
31.0
32.0
33.0
34.0 Light orange, tan, and white micaceous SILT; moist to wet
33-35 17.3 35.0
Terminated boring at 35'
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
Red and brown Clayey SILT; moist
SAMPLING METHOD/INTERVAL: 2' SS
REMARKS: Total boring depth: 35' bgs; surface to 5' bgs post-holed
BENTONITE
BENTONITE
DRILLING METHODS
SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
*SAMPLE COLLECTED
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:SB-3
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/5/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Geoprobe/HSA
BORING DIAMETER: 2.5 inches (DPT); 4.25" HSA
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and gray Silty CLAY and clay; moist to wet
2.0
3.0 Red, orange and gray Clayey SILT; moist to wet
4.0
0.4-5 18.0 5.0
6.0
7.0
8.0 Orange and yellow micaceous SILT, moist
9.0
5-10 53.6 10.0
11.0
12.0
13.0
14.0 Red, orange, and yellow micaceous SILT; moist
10-15 30.9 15.0
16.0
17.0
18.0 Yellow, orange, and tan micaceous SILT; moist
19.0
15-20 127 20.0
21.0
22.0
23.0 SSA; moist
24.0
20-25 219 25.0
26.0
27.0
28.0 SAA
29.0
*25-30*2,811 30.0
31.0
32.0
33.0 Pink, white, red, yellow, light orange micaceous SILT; moist to wet
*30-34*2,599 34.0
35 2,110 35.0 Yellow, white, and gold micaceous SILT; wet
Terminated boring at 35'
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: 5 foot DPT macrocore
REMARKS: Total boring depth: 35' bgs; surface to 5' bgs post-holed
Red, orange, and brown Clayey SILT
BENTONITE
BENTONITE
DRILLING METHODS
SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
*SAMPLE COLLECTED
PWR - PARTIALLY-WEATHERED ROCK
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:SB-4
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/5/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Geoprobe/HSA
BORING DIAMETER: 2.5 inches (DPT); 4.25" HSA
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and gray Silty CLAY and clay; moist to wet
2.0
3.0 Red and gray Silty CLAY and clay; moist to wet
4.0
0.4-5 0 5.0
6.0
7.0
8.0 SSA; moist to wet
9.0
5-10 2.2 10.0
11.0
12.0
13.0 SAA trending to red, yellow, and orange micaceous Clayey SILT; dry to moist
14.0
10-15 14.7 15.0
16.0
17.0
18.0 Red, yellow, and orange micaceous SILT; dry to moist
19.0
15-20 7.8 20.0
21.0
22.0
23.0 SSA trending to PWR and quartz fragments; dry to moist
24.0
20-25 62.7 25.0
26.0
27.0
28.0
29.0
*25-30*176 30.0
31.0 PWR and yellow, white, red, and orange micaceous SILT
32.0
33.0
34.0
30-35 39.6 35.0
Terminated boring at 35'
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: 5 foot DPT macrocore
REMARKS: Total boring depth: 35' bgs; surface to 5' bgs post-holed
BENTONITE
BENTONITE
DRILLING METHODS
SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
*SAMPLE COLLECTED
PWR - PARTIALLY-WEATHERED ROCK
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:SB-5
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/4/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3.0
4.0
3-5 111 5.0
6.0
7.0
8.0 Backfill; dry to moist
9.0
8-10 256 10.0
11.0
12.0
13.0 Backfill to white, pink, and red micaceous SILT; moist
14.0
13-15 1645 15.0
16.0
17.0
18.0
19.0
*18-20*2266 20.0 White pink, and red micaceous SILT; moist
21.0
22.0
23.0
24.0
23-25 1242 25.0
26.0
27.0
28.0
29.0 Light orange and white micaceous Clayey SILT and some sand; moist
28-30 1956 30.0
31.0
32.0
33.0
34.0 White, orange, and brown micacoeus SILT; moist
*33-35*1902 35.0
Terminated boring at 35'
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
Backfill; moist
SAMPLING METHOD/INTERVAL: 2' SS
REMARKS: Total boring depth: 35' bgs; surface to 5' bgs post-holed
BENTONITE
BENTONITE
DRILLING METHODS
SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
*SAMPLE COLLECTED
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
6
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-6
(Page 1 of 1)
Date(s) Drilled : July 26, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Air Rotary
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.0
0.0
17.6
188
183
119
Elevation:
Well: SB-6
Grout
Bentonite
ML
SM
ML
ML
ML
Asphalt
Red, brown clayey SILT, mica
Red, burgundy silty SAND, some white fine grain sand
Brown, tan SILT, some mica
Brown, tan sandy SILT, fine to medium grain sand, white and
black
Tan, white sandy SILT, fine grain sand, wet
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
7
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 25 feet bgs.
BORING LOG: SB-7
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Air Rotary
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.9
0.7
0.8
9.2
20.1
39.2
Elevation:
Well: SB-7
Grout
Bentonite
ML
ML
Asphalt
Red, brown clayey SILT
Red, brown clayey SILT, wet
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
8
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-8
(Page 1 of 1)
Date(s) Drilled : July 26, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Air Rotary
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.0
0.0
0.0
10.0
26.9
75.5
Elevation:
Well: SB-8
Grout
Bentonite
ML
SM
SM
Asphalt
Red, brown clayey SILT, mica
Red, burgundy silty SAND, some white and black fine grain sand
Red, brown, white, black silty SAND, fine to medium grain sand
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
s
\
S
B
-
9
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
BORING LOG: SB-9
(Page 1 of 1)
Date(s) Drilled : July 26, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Air Rotary
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
ML
SM
ML
SM
SM
GR
A
P
H
I
C
DESCRIPTION
Asphalt
Brown, red sandy SILT
Red, burgundy silty SAND, some white and black spots
Brown, tan sandy SILT
Red, burgandy silty SAND, some gravel
Brown, red, white silty SAND, some coarse grain white sand,
mostly fine grain sand
PI
D
94
NR
131
352
258
425
Elevation:
Well: SB-9
Grout
Bentonite
Boring terminated at 30 feet bgs.
NR = No Recovery
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
1
0
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-10
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.9
0.5
1.7
1.7
23
8.5
5.6
Elevation:
Well: SB-10
Grout
Bentonite
ML
ML
ML
Asphalt
Red, brown clayey SILT, mica
Brown, tan sandy SILT, fine grain sand
Brown, tan sandy SILT, coarse grain sand, wet
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
1
1
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-11
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.6
1.2
11.7
8.9
3.3
15.2
5.4
Elevation:
Well: SB-11
Grout
Bentonite
CL
ML
Asphalt
Red, brown silty CLAY, mica
Red, orange clayey SILT, lots of mica
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
s
\
S
B
-
1
2
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 15 feet bgs.
BORING LOG: SB-12
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
US
C
S
CG
ML
ML
GR
A
P
H
I
C
DESCRIPTION
Gravel
Red, brown clayey SILT
Red, orange clayey SILT, mica, some sand, brown and white spots
PI
D
0.9
0.9
0.8
0.4
Elevation:
Well: SB-12
Grout
Bentonite
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
s
\
S
B
-
1
3
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-13
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.3
0.1
0.2
12.8
70.7
205
1046
Elevation:
Well: SB-13
Grout
Bentonite
CG
ML
SM
Gravel
Red, brown clayey SILT, white and brown speckling throughout
Brown, tan silty SAND, black speckling
08
-
3
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
-
1
4
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-14
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
ML
ML
GR
A
P
H
I
C
DESCRIPTION
Asphalt
Brown, tan sandy clayey SILT, fine grain sand, white and red, and
some black
Brown, red clayey SILT some sand, mica, wet
PI
D
0.2
0.4
0.1
1.2
2.3
10.7
14.9
Elevation:
Well: SB-14
Grout
Bentonite
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
S
B
s
\
S
B
-
1
5
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 30 feet bgs.
BORING LOG: SB-15
(Page 1 of 1)
Date(s) Drilled : July 28, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Direct Push
Boring Diameter : 2 Inches
Sampling Method : Macro Core
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.2
0.5
4.1
6.3
20.1
23.9
2.6
Elevation:
Well: SB-15
Grout
Bentonite
ML
ML
ML
ML
Grass and roots
Red, brown clayey SILT
White, brown, clayey SILT
Brown, tan, some white clayey SILT
medium grained,Brown, red clayey SILT, white speckling and trace sand
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 1
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 12/4/2008
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: HSA
BORING DIAMETER: 4.25" (ID)
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 2)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt cover to approximately 4" then fill
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
*8-10 298 10.0
11.0
12.0
13.0
14.0
13-15 15 15.0
16.0
17.0
18.0
19.0
*18-20 105 20.0
21.0
22.0
23.0
24.0
23-25 29 25.0
26.0
27.0
28.0
29.0
*28-30 99 30.0
31.0
32.0
33.0
34.0
33-35 118 35.0
36.0
37.0
38.0
39.0
*38-40 19 ▼40.0
41.0
42.0
43-45 43.0
44.0
45.0
46.0
47.0
48.0 Boring terminated at 48 feet bgs
49.0
50.0
51.0
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
* Samples collection interval PHC = Petroleum hrdocarbon odor SAA - Same as abov
USCS
SAMPLING METHOD/INTERVAL: Split Spoon
REMARKS: Total boring depth: 48' bgs; screened from 33'-48' bgs
Fill
Red and orange micaceous Clayey SILT
PWR (partially-weathered rock)
Black, white, light orange, tan Sandy SILT; moist to wet
Same as above, saturated
Light orange, tan, and white micaceous Clayey SILT
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON AIR - AIR ROTARY CFA - CONTINUOUS FLIGHT AUGER DC - DRIVEN CASING HA - HAND AUGER
HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS
GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 2
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 3/10/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: Geologic Exploration
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6" (ID)
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 2)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Sandy SILT
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
6.8 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
15.1 20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
1.5 30.0
31.0
32.0
33.0
34.0
35.0
36.0
37.0
38.0
▼39.0
11.9 40.0
41.0
42.0
43.0
44.0
45.0
46.0 Boring terminated at 46' bgs
47.0
48.0
49.0
50.0
51.0
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: Drill cutings
Brown, red, and orange Sandy Clayey SILT; dry to moist
REMARKS: Total boring depth: 46' bgs; screened from 31-46' bgs;surface to
5' bgs post holed
Orange and red micaceous Clayey SILT
Tan micaceous Sandy SILT and PWR (partially weathered rock)
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING
HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 3
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 3/10/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: Geologic Exploration
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6" (ID)
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 2)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Grass cover then Red Clayey SILT
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
0 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
0 20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
12.5 ▼30.0
31.0
32.0
33.0
34.0
35.0 Boring terminated at 35' bgs
36.0
37.0
38.0
39.0
40.0
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
49.0
50.0
51.0
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
REMARKS: Total boring depth: 35' bgs; screened from 20-35' bgs;surface to 5'
bgs post holed
Red, tan, and orange Clayey SILT; dry to moist
USCS
SAMPLING METHOD/INTERVAL: Drill cutings
Orange and red micaceous Clayey SILT
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 4
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 3/10/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: Geologic Exploration
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6" (ID)
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 2)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Grass and gravel cover then light orange and orange micaceous Sandy SILT
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
0 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
0 20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
12.5 30.0
▼31.0
32.0
33.0
34.0
35.0
36.0
37.0
38.0
39.0
15.5 40.0 Boring terminated at 40' bgs
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
49.0
50.0
51.0
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: Drill cutings
Tan micaceous Sandy SILT
Light orange and orange micaceous Sandy SILT
Red micaceous SILT
REMARKS: Total boring depth: 40' bgs; screened from 25-40' bgs;surface to 5'
bgs post holed
Light brown micaceous Sandy Clayey SILT
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 5
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/5/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Track Rig - HSA
BORING DIAMETER: 4"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then fill
2.0
3.0
4.0
0.4-5 -5.0
6.0
7.0
8.0
9.0
5-10 -10.0
11.0
12.0
13.0
14.0
10-15 -15.0
16.0
17.0
18.0
19.0
15-20 10.5 20.0
21.0
22.0 White, red, yellow, and orange micaceous SILT, some PWR; moist
23.0
24.0
20-25 6.9 25.0
26.0
27.0 SSA; moist
28.0
29.0
*25-30*45.5 30.0
31.0
32.0 Red, dark brown, orange, yellow, whiet, and black micaceous SILT; moist to wet
33.0
34.0
30- 35 14.7 35.0
▼36.0
37.0
38.0
39.0
40.0 Orange, pink, white, and gold micaceous SILT; moist to wet
41.0
42.0
43.0
44.0
45.0
46.0 Boring terminated at 45' bgs
47.0
48.0
49.0
50.0
51.0
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: Macrocore
REMARKS: Total boring depth: 45' bgs; screened from 30-45' bgs;surface to 5' bgs
post-holed
Fill
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING
HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 6
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/4/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3 0.7 3.0
4.0
5.0
6.0
7.0
8.0
9.0
10 2.2 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20 0.0 20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30 0.0 30.0
31.0
32.0
33.0
34.0 Red micaceous SILT; moist
35.0
▼36.0
37.0
38.0
39.0
40 0.0 40.0
41.0
42.0
43.0 Light brown and orange micaceous SILT and some sand; moist
44.0
45.0
Boring terminated at 45' bgs
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
SAMPLING METHOD/INTERVAL: Drill cutings
Red and orange Clayey SILT; moist
REMARKS: Total boring depth: 45' bgs; screened from 25-45' bgs;surface to
5' bgs post-holed
Tan Silty fine SAND; moist
USCS
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING
HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 7
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/5/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3 1.5 3.0
4.0
5.0 Red and orange Clayey SILT; moist
6.0
7.0
8.0
9.0
10 2.1 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20 2.7 20.0
21.0
22.0 Red and orange micaceous SILT; moist
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30 0.9 30.0
31.0
32.0
33.0
34.0
▼35.0
36.0
37.0
38.0
39.0
40 8.2 40.0 Tan and brown micaceous SILT; saturated
41.0
42.0
43.0
44.0
Boring terminated at 44' bgs

bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: Drill cutings
REMARKS: Total boring depth: 44' bgs; screened from 29-44' bgs;surface to
5' bgs post-holed
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING
HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
SOIL BORING LOG
PROJECT NAME:Former Cajah's Mountain Superette BORING I.D.:MW- 8
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/5/2009
PROJECT LOCATION:1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Track Rig - HSA
BORING DIAMETER: 4"
CLIENT: Cary Oil Company
LOGGED BY:DL

DESCRIPTIVE LOG (page 1 of 1)
SAMPLE PID/FID GRAPHIC DEPTH
INTERVAL (ppm)COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3.0
4.0
0.4-5 3.4 5.0 Red and orange Clayey SILT and some micaceous; dry to moist
6.0
7.0
8.0
9.0
5-10 23.7 10.0
11.0
12.0 White, pink, yellow, light orange, and gold micaceous SILT; moist
13.0
14.0
10-15 79.1 15.0
16.0
17.0 SAA with compressed mica flakes
18.0
19.0
15-20 37.2 20.0
21.0
22.0
23.0
24.0 Pink, tan, gold, and white micaceous SILT; moist
20-25 381 25.0
26.0
27.0
28.0
29.0
*25-30*3,278 30.0
31.0
32.0 SAA; moist to wet
30- 33 2,739 33.0
▼34.0
33-35 3,064 35.0
36.0
37.0
38.0 White, yellow, and gold micaceous SILT; wet
39.0
40.0
41.0
42.0
43.0
44.0
Boring terminated at 44' bgs

bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA= SAME AS ABOVE
USCS
SAMPLING METHOD/INTERVAL: Macrocore
REMARKS: Total boring depth: 44' bgs; screened from 29-44' bgs;surface to
5' bgs post-holed
BENTONITE
BENTONITE
DRILLING METHODS SS-SPLIT SPOON
AIR - AIR ROTARY
CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING
HA - HAND AUGER HSA - HOLLOW STEM AUGER
MD - MUD DRILLING
RC - ROCK CORING
WR - WATER ROTARY
SAMPLING METHODS GP-GEOPROBE
SPLIT SPOON
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTONITE
BENTONITE
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
m
w
-
9
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
BORING LOG: MW-9
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : HSA
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.0
0.0
Elevation: 90.82
Well: MW-9
Grout
Bentonite
Sand Pack
2" PVC Casing
2" PVC Screen
ML
Gravel
Brown, tan clayey SILT, some sand
Boring terminated at 30 feet bgs. Set one 2" well at boring terminus with 15 feet
of screen.
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
m
w
-
1
0
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 40 feet bgs. Set one 2" well at boring terminus with 15 feet
of screen.
BORING LOG: MW-10
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : HSA
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
US
C
S
GR
A
P
H
I
C
DESCRIPTION
PI
D
0.0
0.0
0.0
Elevation: 98.34
Well: MW-10
Grout
Bentonite
Sand Pack
2" PVC Casing
2" PVC Screen
ML
ML
Asphalt
Red, brown clayey SILT
Brown, tan clayey SILT, some sand
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
M
W
s
\
m
w
-
1
1
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
BORING LOG: MW-11
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : HSA
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
US
C
S
ML
CL
SM
GR
A
P
H
I
C
DESCRIPTION
Grass and Gravel
Red, brown clayey SILT, mica
Red, orange silty CLAY
Brown, tan silty SAND with white and black fine grain sand, mic
PI
D
1.2
0.9
NR
2.1
5.3
13.3
12.3
Elevation: 97.76
Well: MW-11
Grout
Bentonite
Sand Pack
2" PVC Casing
2" PVC Screen
Boring terminated at 40 feet bgs. Set one 2" well at boring terminus with 15 feet
of screen.
NR = No Recovery
09
-
0
1
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
m
w
-
1
2
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Boring terminated at 40 feet bgs. Set one 2" well at boring terminus with 15 feet
of screen.
BORING LOG: MW-12
(Page 1 of 1)
Date(s) Drilled : July 27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : HSA
Boring Diameter : 6 Inches
Sampling Method : Split Spoons
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
US
C
S
ML
ML
ML
GR
A
P
H
I
C
DESCRIPTION
Grass and Gravel
Red, brown clayey SILT
Brown with a little red clayey SILT, lots of mica
Brown, tan clayey SILT, some mica
moist at 35'
PI
D
Elevation: 97.33
Well: MW-12
Grout
Bentonite
Sand Pack
2" PVC Casing
2" PVC Screen
0.8
0.4
0.4
SOIL BORING LOG
PROJECT NAME: Former Cajah's Mountain Superette BORING I.D.:DMW- 1
PROJECT NO.: 89.03451.1018 DATE(S) DRILLED: 11/4-5/2009
PROJECT LOCATION: 1990 Connelly Springs Road DRILLING CONTR.: EDPS
Lenoir, NC DRILL METHOD: Air Rotary
BORING DIAMETER: 6"
CLIENT: Cary Oil Company
LOGGED BY:DL
DESCRIPTIVE LOG (page 1 of 1)
SAMPLE GRAPHIC DEPTH
INTERVAL COLUMN (FT)DESCRIPTION OF MATERIAL
1.0 Asphalt covered to 4" then red and orange Clayey SILT
2.0
3 3.0
4.0
5.0
6.0
7.0
8.0
9.0
10 10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20 20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30 30.0
31.0
32.0
33.0
34.0 Light orange and brown micaceaous SILT; moist
35.0 Rock layer encountered - PWR
▼36.0
37.0
38.039.0
40 40.0
41.0
42.0
43.0
44.0 Light brown and brown micaceous SILT; moist
45.0
46.0
47.0
48.0
49.0
50 50.0
51.0
52.0
53.0
54.0
55.0
56.0 Light brown and brown micaceous SILT and some clayey silt; moist
57.0
58.0
59.0
60 60.0
61.0
62.0
63.0 Rock layer encountered - PWR
64.0
65.0 Set Outer Casing at 65'
66.0
67.0
68.0
69.0
70.0
71.0
72.0
73.0
74.0
75.0
Terminated drilling at 75' and set well
bgs= BELOW GROUND SURFACE
GRAPHIC COLUMN▼DEPTH TO WATER
GROUT
SCREEN
PHC = PETROLEM HYDROCARBON ODOR SAA=SAME AS ABOVE
Tan and orange SILT; moist
USCS
SAMPLING METHOD/INTERVAL: Drill cutings
Red and orange Clayey SILT; moist
REMARKS: Total boring depth: 75' bgs; outer casing set at 65'; screened from 70'-
75';surface to 5' bgs post-holed
PID/FID
(ppm)
0.1
0.2
3.1
4.1
0.6
0.0
0.0
BENTO
DRILLING METHODS
SS-SPLIT SPOON AIR - AIR ROTARY CFA - CONTINUOUS FLIGHT AUGER
DC - DRIVEN CASING HA - HAND AUGER
HSA - HOLLOW STEM AUGER MD - MUD DRILLING RC - ROCK CORING
WR - WATER ROTARY SAMPLING METHODS
GP-GEOPROBE SPLIT SPOON
PWR - PARTIALLY WEATHERED ROCK
GROUT
SAND
3417-A Trade Park Court
Charlotte, North Carolina 28217
BENTO
GROUT
SAND
4020 Old Pineville Road
Charlotte, North Carolina 28217
10
-
1
9
-
2
0
1
0

S
:
\
C
a
r
y

O
i
l

C
o
\
C
a
j
a
h

M
o
u
n
t
a
i
n
\
B
o
r
i
n
g

L
o
g
s
\
M
W
s
\
D
M
W
-
2
.
b
o
r
Client: Cary Oil
ATC Project No. 89.03451.1018
Lenoir, NC
1990 Connelly Springs Road
Cajah Mountain
Set outer casing at 85 feet bgs. Completed drill out to 95 feet bgs. Set one 2"
well at 95 feet bgs with 5 feet of screen.
BORING LOG: DMW-2
(Page 1 of 1)
Date(s) Drilled : July 26-27, 2010
Drilling Contractor : Geologic Exploration
Drilling Method : Air Rotary
Boring Diameter : 8 Inches
Sampling Interval : Continuous
Logged By : DL
De
p
t
h

I
n

F
e
e
t
0
2
4
6
8
10
12
1416
18
20
22
24
26
28
30
32
34
3638
40
42
44
46
48
5052
5456
5860
62
64
66
68
70
7274
76
78
80
82
84
86
88
9092
94
US
C
S
ML
ML
ML
SM
GR
A
P
H
I
C
DESCRIPTION
Gravel
Red SILT with mica
Brown SILT with mica, wet
Saturated tan SILT
ROCK
Brown, tan silty SAND, white, black, and red coarse sand
PI
D
Elevation: 90.85
Well: DMW-2
Grout
BentoniteSand Pack
SurfaceCasing
2" PVC Casing
2" PVC Screen
0.0
0.0
0.0
0.0

APPENDIX E

LABORATORY ANALYTICAL REPORTS
Case Narrative for:
08120551
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
DIANA LANIER
Date Reported:12/23/2008
Project Name:89.03451.1018
PO Number:
Site:CAJAH MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
[phone]ph:fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to
check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may
be applicable to other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the
sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample
(LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and
the MS/MSD to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for
MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch
and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the
parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample
weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above
Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative
of the samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
TOTAL NUMBER OF PAGES IN THIS REPORT: ________ PAGES
DateAmy K. Jackson
12/23/2008
Project Manager
08120551 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
08120551
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
[phone]
DIANA LANIER
Date Reported:12/23/2008
Project Name:89.03451.1018
PO Number:
Site:CAJAH MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
08120551-01 12/12/2008 9:45:00 AMMW-1 12/10/2008 11:30:00 AMWater 273208
Date
Laboratory Director
Quality Assurance Officer
Amy K. Jackson
08120551 Page 2
12/23/2008
12/23/2008 4:02:09 PM
Project Manager
Ron Benjamin
Tristan Davis
Client Sample ID MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120551-01
Dil. Factor Analyst
Collected:12/10/2008 11:30
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 12/16/08 2:000.022 1ND DF 2901848
Surr: 1-Chloro-2-fluorobenzene 12/16/08 2:00% 33-151 172.6 DF 2901848
Prep Method Prep Date Prep Initials Prep Factor
12/15/2008 15:46 JTE504 1.12
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 12/15/08 21:550.01 10.11 SVW 2899511
Prep Method Prep Date Prep Initials Prep Factor
12/12/2008 14:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/23/2008 4:02:11 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120551 Page 3
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120551-01
Dil. Factor Analyst
Collected:12/10/2008 11:30
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 12/16/08 14:330.1 1ND TDD 2901454
1,1,1-Trichloroethane 12/16/08 14:330.1 1ND TDD 2901454
1,1,2,2-Tetrachloroethane 12/16/08 14:330.1 1ND TDD 2901454
1,1,2-Trichloroethane 12/16/08 14:330.1 1ND TDD 2901454
1,1-Dichloroethane 12/16/08 14:330.1 1ND TDD 2901454
1,1-Dichloroethene 12/16/08 14:330.1 1ND TDD 2901454
1,1-Dichloropropene 12/16/08 14:330.1 1ND TDD 2901454
1,2,3-Trichlorobenzene 12/16/08 14:330.2 1ND TDD 2901454
1,2,3-Trichloropropane 12/16/08 14:330.1 1ND TDD 2901454
1,2,4-Trichlorobenzene 12/16/08 14:330.1 1ND TDD 2901454
1,2,4-Trimethylbenzene 12/16/08 14:330.1 13.1 TDD 2901454
1,2-Dibromo-3-chloropropane 12/16/08 14:330.5 1ND TDD 2901454
1,2-Dibromoethane 12/16/08 14:330.1 1ND TDD 2901454
1,2-Dichlorobenzene 12/16/08 14:330.1 1ND TDD 2901454
1,2-Dichloroethane 12/16/08 14:330.2 1ND TDD 2901454
1,2-Dichloropropane 12/16/08 14:330.1 1ND TDD 2901454
1,3,5-Trimethylbenzene 12/16/08 14:330.1 11.6 TDD 2901454
1,3-Dichlorobenzene 12/16/08 14:330.1 1ND TDD 2901454
1,3-Dichloropropane 12/16/08 14:330.1 1ND TDD 2901454
1,4-Dichlorobenzene 12/16/08 14:330.1 1ND TDD 2901454
2,2-Dichloropropane 12/16/08 14:330.1 1ND TDD 2901454
2-Chlorotoluene 12/16/08 14:330.2 1ND TDD 2901454
4-Chlorotoluene 12/16/08 14:330.1 1ND TDD 2901454
Benzene 12/16/08 14:330.1 110 TDD 2901454
Bromobenzene 12/16/08 14:330.1 1ND TDD 2901454
Bromochloromethane 12/16/08 14:330.1 1ND TDD 2901454
Bromodichloromethane 12/16/08 14:330.1 10.65 TDD 2901454
Bromoform 12/16/08 14:330.1 1ND TDD 2901454
Bromomethane 12/16/08 14:330.1 1ND TDD 2901454
Carbon tetrachloride 12/16/08 14:330.1 1ND TDD 2901454
Chlorobenzene 12/16/08 14:330.1 1ND TDD 2901454
Chloroethane 12/16/08 14:330.2 1ND TDD 2901454
Chloroform 12/16/08 14:330.1 111 TDD 2901454
Chloromethane 12/16/08 14:330.1 13.3 TDD 2901454
cis-1,2-Dichloroethene 12/16/08 14:330.1 1ND TDD 2901454
Dibromochloromethane 12/16/08 14:330.1 1ND TDD 2901454
Dibromomethane 12/16/08 14:330.1 1ND TDD 2901454
Dichlorodifluoromethane 12/16/08 14:330.1 1ND TDD 2901454
Ethylbenzene 12/16/08 14:330.1 11.2 TDD 2901454
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/23/2008 4:02:11 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120551 Page 4
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120551-01
Dil. Factor Analyst
Collected:12/10/2008 11:30
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 12/16/08 14:330.2 1ND TDD 2901454
Isopropyl ether 12/16/08 14:330.1 10.24 TDD 2901454
Isopropylbenzene 12/16/08 14:330.2 10.34 TDD 2901454
m & p-Xylene 12/16/08 14:330.1 13.3 TDD 2901454
Methyl tert-butyl ether 12/16/08 14:330.2 165 TDD 2901454
Methylene chloride 12/16/08 14:330.2 1ND TDD 2901454
Naphthalene 12/16/08 14:330.1 1ND TDD 2901454
n-Butylbenzene 12/16/08 14:330.1 10.4 TDD 2901454
n-Propylbenzene 12/16/08 14:330.1 10.63 TDD 2901454
o-Xylene 12/16/08 14:330.1 13.1 TDD 2901454
p-Isopropyltoluene 12/16/08 14:330.1 1ND TDD 2901454
sec-Butylbenzene 12/16/08 14:330.1 1ND TDD 2901454
Styrene 12/16/08 14:330.1 1ND TDD 2901454
tert-Butylbenzene 12/16/08 14:330.1 1ND TDD 2901454
Tetrachloroethene 12/16/08 14:330.2 1ND TDD 2901454
Toluene 12/16/08 14:330.1 12.5 TDD 2901454
trans-1,2-Dichloroethene 12/16/08 14:330.1 1ND TDD 2901454
Trichloroethene 12/16/08 14:330.1 1ND TDD 2901454
Trichlorofluoromethane 12/16/08 14:330.1 1ND TDD 2901454
Vinyl chloride 12/16/08 14:330.1 1ND TDD 2901454
Surr: 1,2-Dichloroethane-d4 12/16/08 14:33% 60-140 195.7 TDD 2901454
Surr: 4-Bromofluorobenzene 12/16/08 14:33% 60-140 195.6 TDD 2901454
Surr: Toluene-d8 12/16/08 14:33% 60-140 199.2 TDD 2901454
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 12/19/08 23:17601180 JAP 2905626
C9-C10 Aromatics 12/19/08 23:1720142 JAP 2905615
C9-C12 Aliphatics 12/19/08 23:17701ND JAP 2905626
Surr: 2,5-Dibromotoluene 12/19/08 23:17% 70-130 1107 JAP 2905615
Surr: 2,5-Dibromotoluene 12/19/08 23:17% 70-130 1104 JAP 2905626
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/23/2008 4:02:11 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120551 Page 5
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Documentation
12/23/2008 4:02:12 PM
08120551 Page 6
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:75691
WorkOrder:08120551
Method:E504.1
Analysis:METHOD 504.1
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/15/2008 23:05
Preparation Date:12/15/2008 15:46
Analyst:DF
Prep By:JT MethodE504
RunID:PCBB_081215B-2901839 Units:ug/L
1,2-Dibromoethane 0.570 0.574 101 60 1400.570 0.555 97.4 3.3 30
Surr: 1-Chloro-2-fluorobenzene 143 156 109 33 1511431511053.7 30
Analyte Result Rep Limit
Method Blank
Analysis Date:12/15/2008 22:45
Preparation Date:12/15/2008 15:46
Analyst:DF
RunID:PCBB_081215B-2901838 Units:ug/L
Prep By:JT MethodE504
1,2-Dibromoethane 0.020ND
Surr: 1-Chloro-2-fluorobenzene 33-151106.6
08120551-01B MW-1
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 7
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194810
WorkOrder:08120551
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/19/2008 11:22 Analyst:JAP
RunID:HPCC_081219D-2905608 Units:ug/L
C9-C10 Aromatics 80.0 70.4 88.0 70 13080.0 71.2 89.1 1.1 20
Surr: 2,5-Dibromotoluene 200 208 104 70 1302002001003.7 30
Analyte Result Rep Limit
Method Blank
Analysis Date:12/19/2008 9:53 Analyst:JAP
RunID:HPCC_081219D-2905607 Units:ug/L
C9-C10 Aromatics 20ND
Surr: 2,5-Dibromotoluene 70-130103.9
08120551-01C MW-1
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 8
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194811
WorkOrder:08120551
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/19/2008 11:22 Analyst:JAP
RunID:HPCC_081219E-2905619 Units:ug/L
C5-C8 Aliphatics 300 268 89.4 70 13030026889.3 0.0 20
C9-C12 Aliphatics 280 223 79.5 70 13028023082.3 3.4 20
Surr: 2,5-Dibromotoluene 200 207 103 70 13020019697.9 5.5 30
Analyte Result Rep Limit
Method Blank
Analysis Date:12/19/2008 9:53 Analyst:JAP
RunID:HPCC_081219E-2905618 Units:ug/L
C5-C8 Aliphatics 60ND
C9-C12 Aliphatics 70ND
Surr: 2,5-Dibromotoluene 70-130100.6
08120551-01C MW-1
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 9
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:75649
WorkOrder:08120551
Method:SW6010B
Analysis:Total Metals by Method 6010B - water
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte MS
Spike
Added
MSD
Result
MSD %
Recovery
RPD RPD
Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
Sample
Result
Low
Limit
High
Limit
MS
Result
MS %
Recovery
Sample Spiked:08120551-01
MSD
Spike
Added
Analysis Date:12/15/2008 22:04
Preparation Date:12/12/2008 14:15
Analyst:SVW
Prep By:SA MethodM3030-C
RunID:ICPDV_081215B-2899513 Units:mg/L
Lead 1 1.020 91.00 75 1250.1102 200.40831.024 91.42 1
Analyte Spike
Added
Result Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample (LCS)
Analysis Date:12/15/2008 21:50
Preparation Date:12/12/2008 14:15
Analyst:SVW
Prep By:SA MethodM3030-C
RunID:ICPDV_081215B-2899510 Units:mg/L
Lead 1.000 1.034 103.4 80 120
Analyte Result Rep Limit
Method Blank
Analysis Date:12/15/2008 21:45
Preparation Date:12/12/2008 14:15
Analyst:SVW
RunID:ICPDV_081215B-2899509 Units:mg/L
Prep By:SA MethodM3030-C
Lead 0.01ND
08120551-01D MW-1
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 10
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194575
WorkOrder:08120551
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:12/16/2008 13:51
Preparation Date:12/16/2008 13:51
Analyst:TDD
RunID:IA_081216B-2901453 Units:ug/L
Prep By:MethodSW5035
1,1,1,2-Tetrachloroethane 0.10ND
1,1,1-Trichloroethane 0.10ND
1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND
1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND
1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND
1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.10ND
1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 0.50ND
1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND
1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.10ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.10ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.10ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.10ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.10ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
08120551-01A MW-1
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 11
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194575
WorkOrder:08120551
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/16/2008 11:47 Analyst:TDD
RunID:IA_081216B-2901451 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 17.5 87.3 60 14020.0 17.7 88.6 1.5 20
1,1,1-Trichloroethane 20.0 20.3 102 60 14020.0 20.4 102 0.4 20
1,1,2,2-Tetrachloroethane 20.0 15.9 79.7 60 14020.0 16.7 83.6 4.8 20
1,1,2-Trichloroethane 20.0 16.9 84.6 60 14020.0 17.4 86.9 2.6 20
1,1-Dichloroethane 20.0 19.7 98.5 60 14020.0 18.8 94.1 4.6 20
1,1-Dichloroethene 20.0 20.1 100 60 14020.0 19.5 97.7 2.8 20
1,1-Dichloropropene 20.0 19.6 97.9 60 14020.0 19.7 98.5 0.6 20
1,2,3-Trichlorobenzene 20.0 18.9 94.4 60 14020.0 18.8 94.2 0.2 20
1,2,3-Trichloropropane 20.0 18.3 91.7 60 14020.0 18.5 92.6 0.9 20
1,2,4-Trichlorobenzene 20.0 18.6 93.2 60 14020.0 18.8 93.9 0.8 20
1,2,4-Trimethylbenzene 20.0 19.9 99.7 60 14020.0 20.0 100 0.3 20
1,2-Dibromo-3-chloropropane 20.0 17.9 89.4 60 14020.0 18.7 93.3 4.3 20
Analyte Result Rep Limit
Method Blank
Analysis Date:12/16/2008 13:51
Preparation Date:12/16/2008 13:51
Analyst:TDD
RunID:IA_081216B-2901453 Units:ug/L
Prep By:MethodSW5035
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10ND
o-Xylene 0.10ND
p-Isopropyltoluene 0.10ND
sec-Butylbenzene 0.10ND
Styrene 0.10ND
tert-Butylbenzene 0.10ND
Tetrachloroethene 0.20ND
Toluene 0.10ND
trans-1,2-Dichloroethene 0.10ND
Trichloroethene 0.10ND
Trichlorofluoromethane 0.10ND
Vinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14093.5
Surr: 4-Bromofluorobenzene 60-14095.4
Surr: Toluene-d8 60-140100.7
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 12
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194575
WorkOrder:08120551
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/16/2008 11:47 Analyst:TDD
RunID:IA_081216B-2901451 Units:ug/L
1,2-Dibromoethane 20.0 17.3 86.5 60 14020.0 18.2 91.1 5.2 20
1,2-Dichlorobenzene 20.0 18.2 91.2 60 14020.0 18.3 91.5 0.3 20
1,2-Dichloroethane 20.0 18.5 92.3 60 14020.0 19.3 96.7 4.6 20
1,2-Dichloropropane 20.0 18.4 91.9 60 14020.0 18.8 94.2 2.5 20
1,3,5-Trimethylbenzene 20.0 20.2 101 60 14020.0 20.4 102 1.0 20
1,3-Dichlorobenzene 20.0 18.4 92.2 60 14020.0 18.6 92.8 0.6 20
1,3-Dichloropropane 20.0 17.8 89.2 60 14020.0 17.7 88.7 0.5 20
1,4-Dichlorobenzene 20.0 18.7 93.7 60 14020.0 18.7 93.5 0.2 20
2,2-Dichloropropane 20.0 20.5 102 60 14020.0 20.1 101 1.5 20
2-Chlorotoluene 20.0 19.5 97.7 60 14020.0 20.0 100 2.5 20
4-Chlorotoluene 20.0 20.3 102 60 14020.0 20.3 102 0.2 20
Benzene 20.0 19.4 96.8 60 14020.0 20.0 100 3.3 20
Bromobenzene 20.0 18.5 92.6 60 14020.0 18.2 91.1 1.6 20
Bromochloromethane 20.0 19.0 95.0 60 14020.0 19.8 99.0 4.1 20
Bromodichloromethane 20.0 18.8 93.8 60 14020.0 19.4 96.8 3.1 20
Bromoform 20.0 17.9 89.5 60 14020.0 17.9 89.3 0.2 20
Bromomethane 20.0 20.2 101 60 14020.0 20.0 100 1.0 20
Carbon tetrachloride 20.0 17.9 89.4 60 14020.0 17.9 89.7 0.3 20
Chlorobenzene 20.0 18.4 91.9 60 14020.0 18.5 92.6 0.8 20
Chloroethane 20.0 16.7 83.7 60 14020.0 16.6 82.9 0.9 20
Chloroform 20.0 18.8 94.2 60 14020.0 19.5 97.7 3.6 20
Chloromethane 20.0 18.8 94.1 60 14020.0 19.4 96.8 2.8 20
cis-1,2-Dichloroethene 20.0 19.5 97.7 60 14020.0 19.9 99.7 2.0 20
Dibromochloromethane 20.0 18.8 93.9 60 14020.0 19.0 95.0 1.2 20
Dibromomethane 20.0 17.0 85.1 60 14020.0 17.6 88.2 3.6 20
Dichlorodifluoromethane 20.0 19.2 95.8 60 14020.0 18.9 94.4 1.5 20
Ethylbenzene 20.0 18.8 94.0 60 14020.0 18.7 93.7 0.3 20
Hexachlorobutadiene 20.0 20.6 103 60 14020.0 20.0 100 2.7 20
Isopropyl ether 20.0 18.3 91.4 60 14020.0 17.2 86.2 5.8 20
Isopropylbenzene 20.0 19.4 96.8 60 14020.0 19.5 97.3 0.6 20
m & p-Xylene 40.0 38.6 96.4 60 14040.0 38.7 96.8 0.4 20
Methyl tert-butyl ether 20.0 16.4 81.9 60 14020.0 16.0 80.1 2.2 20
Methylene chloride 20.0 17.7 88.4 60 14020.0 17.6 87.9 0.6 20
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 13
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194575
WorkOrder:08120551
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike
Added
LCS
Result
LCS
Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike
Added
LCSD
Result
LCSD
Percent
Recovery
RPD RPD
Limit
Analysis Date:12/16/2008 11:47 Analyst:TDD
RunID:IA_081216B-2901451 Units:ug/L
Naphthalene 20.0 17.8 89.2 60 14020.0 18.2 91.0 2.0 20
n-Butylbenzene 20.0 19.9 99.6 60 14020.0 19.6 98.2 1.4 20
n-Propylbenzene 20.0 20.5 103 60 14020.0 20.8 104 1.3 20
o-Xylene 20.0 18.7 93.5 60 14020.0 19.1 95.4 2.0 20
p-Isopropyltoluene 20.0 20.4 102 60 14020.0 20.4 102 0.1 20
sec-Butylbenzene 20.0 20.4 102 60 14020.0 20.3 102 0.2 20
Styrene 20.0 19.3 96.5 60 14020.0 19.6 97.9 1.4 20
tert-Butylbenzene 20.0 20.2 101 60 14020.0 20.1 100 0.4 20
Tetrachloroethene 20.0 18.9 94.5 60 14020.0 18.8 93.9 0.7 20
Toluene 20.0 18.3 91.7 60 14020.0 18.6 92.8 1.2 20
trans-1,2-Dichloroethene 20.0 19.4 96.9 60 14020.0 19.1 95.6 1.3 20
Trichloroethene 20.0 18.5 92.5 60 14020.0 18.7 93.6 1.2 20
Trichlorofluoromethane 20.0 20.6 103 60 14020.0 20.5 102 0.4 20
Vinyl chloride 20.0 19.0 95.0 60 14020.0 19.5 97.6 2.8 20
Surr: 1,2-Dichloroethane-d4 10.0 9.41 94.1 60 14010.0 9.57 95.7 1.7 20
Surr: 4-Bromofluorobenzene 10.0 9.64 96.4 60 14010.0 9.51 95.1 1.4 20
Surr: Toluene-d8 10.0 10.0 100 60 14010.0 10.2 102 2.0 20
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/23/2008 4:02:13 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120551 Page 14
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Chain of Custody
And
Sample Receipt Checklist
12/23/2008 4:02:14 PM
08120551 Page 15
Sample Receipt Checklist
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:08120551
Date and Time Received:12/12/2008 9:45:00 AM Carrier name:FedEx-Pri 1 Day AM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:4°C
Received By:JCB
SPL Representative:
Non Conformance
Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
12/23/2008 4:02:14 PM
08120551 Page 16
Case Narrative for:
08120220
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
DIANA LANIER
Date Reported:1/12/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAH MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
[phone]ph:fax:
NOTE: THIS REPORT HAS BEEN AMENDED FROM THE ORIGINAL. THIS REPORT REPLACES IN ITS ENTIRETY THE COPY PREVIOUSLY SUBMITTED 12/18/08. Target analytes Toluene, Tetrachloroethene and Trichloroethene are reported in this corrected report.
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to
other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD
to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality
control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent
sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
TOTAL NUMBER OF PAGES IN THIS REPORT: ________ PAGES
DateAmy K. Jackson
1/12/2009
Project Manager
08120220 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
08120220
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
[phone]
DIANA LANIER
Date Reported:1/12/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAH MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
08120220-01 12/5/2008 10:30:00 AMMW-1 8-10 12/4/2008 10:45:00 AMSoil 268746
08120220-02 12/5/2008 10:30:00 AMMW-1 18-20 12/4/2008 11:00:00 AMSoil 268746
08120220-03 12/5/2008 10:30:00 AMMW-1 28-30 12/4/2008 11:15:00 AMSoil 268746
08120220-04 12/5/2008 10:30:00 AMMW-1 38-40 12/4/2008 11:40:00 AMSoil 268746
Date
Laboratory Director
Quality Assurance Officer
Amy K. Jackson
08120220 Page 2
1/12/2009
1/12/2009 3:29:43 PM
Project Manager
Ron Benjamin
Tristan Davis
Client Sample ID:MW-1 8-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-01
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 10:45
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 12/08/08 17:280.1 119 RDH 2890460
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:46 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 3
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 8-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-01
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 10:45
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 12/08/08 17:290.006 1ND TDD 2891453
1,1,2,2-Tetrachloroethane 12/08/08 17:290.006 1ND TDD 2891453
1,1,2-Trichloroethane 12/08/08 17:290.006 1ND TDD 2891453
1,1-Dichloroethane 12/08/08 17:290.006 1ND TDD 2891453
1,1-Dichloroethene 12/08/08 17:290.006 1ND TDD 2891453
1,2-Dichloroethane 12/08/08 17:290.006 1ND TDD 2891453
1,2-Dichloropropane 12/08/08 17:290.006 1ND TDD 2891453
2-Butanone 12/08/08 17:290.024 1ND TDD 2891453
2-Hexanone 12/08/08 17:290.012 1ND TDD 2891453
4-Methyl-2-pentanone 12/08/08 17:290.012 1ND TDD 2891453
Acetone 12/08/08 17:290.12 10.23 TDD 2891453
Benzene 12/08/08 17:290.0012 10.1 TDD 2891453
Bromodichloromethane 12/08/08 17:290.006 1ND TDD 2891453
Bromoform 12/08/08 17:290.006 1ND TDD 2891453
Bromomethane 12/08/08 17:290.012 1ND TDD 2891453
Carbon disulfide 12/08/08 17:290.006 10.014 TDD 2891453
Carbon tetrachloride 12/08/08 17:290.006 1ND TDD 2891453
Chlorobenzene 12/08/08 17:290.006 1ND TDD 2891453
Chloroethane 12/08/08 17:290.012 1ND TDD 2891453
Chloroform 12/08/08 17:290.006 1ND TDD 2891453
Chloromethane 12/08/08 17:290.006 1ND TDD 2891453
cis-1,3-Dichloropropene 12/08/08 17:290.006 1ND TDD 2891453
Dibromochloromethane 12/08/08 17:290.006 1ND TDD 2891453
Diisopropyl ether 12/08/08 17:290.006 1ND TDD 2891453
Ethylbenzene 12/08/08 17:290.0012 10.025 TDD 2891453
Methyl tert-butyl ether 12/08/08 17:290.006 10.16 TDD 2891453
Methylene chloride 12/08/08 17:290.012 1ND TDD 2891453
Styrene 12/08/08 17:290.006 1ND TDD 2891453
Tetrachloroethene 12/08/08 17:290.006 1ND TDD 2891453
Toluene 12/08/08 17:290.0012 10.0048 TDD 2891453
trans-1,3-Dichloropropene 12/08/08 17:290.006 1ND TDD 2891453
Trichloroethene 12/08/08 17:290.006 1ND TDD 2891453
Trichlorofluoromethane 12/08/08 17:290.006 1ND TDD 2891453
Vinyl acetate 12/08/08 17:290.012 1ND TDD 2891453
Vinyl chloride 12/08/08 17:290.012 1ND TDD 2891453
cis-1,2-Dichloroethene 12/08/08 17:290.006 1ND TDD 2891453
m,p-Xylene 12/08/08 17:290.0024 10.073 TDD 2891453
o-Xylene 12/08/08 17:290.0012 10.0037 TDD 2891453
trans-1,2-Dichloroethene 12/08/08 17:290.006 1ND TDD 2891453
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:47 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 4
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 8-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-01
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 10:45
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)12/08/08 17:290.006 1ND TDD 2891453
Xylenes,Total 12/08/08 17:290.00121 10.0767 TDD 2891453
Surr: 1,2-Dichloroethane-d4 12/08/08 17:29% 67-158 1111 TDD 2891453
Surr: 4-Bromofluorobenzene 12/08/08 17:29% 84-112 1102 TDD 2891453
Surr: Toluene-d8 12/08/08 17:29% 89-112 198.1 TDD 2891453
Prep Method Prep Date Prep Initials Prep Factor
12/04/2008 10:45 FieldSW5035 0.98
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 12/15/08 11:373.4 50ND JAP 2898482
C9-C10 Aromatics 12/15/08 11:371.1 502.3 JAP 2898446
C9-C12 Aliphatics 12/15/08 11:373.9 50ND JAP 2898482
Surr: 2,5-Dibromotoluene 12/15/08 11:37% 70-130 5097.7 JAP 2898446
Surr: 2,5-Dibromotoluene 12/15/08 11:37% 70-130 5095.9 JAP 2898482
Prep Method Prep Date Prep Initials Prep Factor
12/04/2008 10:45 FieldSW8015B 0.91
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:47 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 5
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 18-20
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-02
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 11:00
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 12/08/08 17:280.1 117 RDH 2890461
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 12/15/08 12:063.5 50ND JAP 2898484
C9-C10 Aromatics 12/15/08 12:061.2 50ND JAP 2898447
C9-C12 Aliphatics 12/15/08 12:064.1 50ND JAP 2898484
Surr: 2,5-Dibromotoluene 12/15/08 12:06% 70-130 50107 JAP 2898447
Surr: 2,5-Dibromotoluene 12/15/08 12:06% 70-130 50100 JAP 2898484
Prep Method Prep Date Prep Initials Prep Factor
12/04/2008 11:00 FieldSW8015B 0.98
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:48 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 6
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 28-30
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-03
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 11:15
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 12/08/08 17:280.1 115 RDH 2890462
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 12/15/08 12:353.1 50ND JAP 2898486
C9-C10 Aromatics 12/15/08 12:35150ND JAP 2898448
C9-C12 Aliphatics 12/15/08 12:353.6 50ND JAP 2898486
Surr: 2,5-Dibromotoluene 12/15/08 12:35% 70-130 50108 JAP 2898448
Surr: 2,5-Dibromotoluene 12/15/08 12:35% 70-130 50103 JAP 2898486
Prep Method Prep Date Prep Initials Prep Factor
12/04/2008 11:15 FieldSW8015B 0.88
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:48 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 7
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 38-40
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-04
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 11:40
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 12/08/08 17:280.1 116 RDH 2890463
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:49 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 8
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 38-40
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-04
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 11:40
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 12/12/08 5:100.34 50ND NDG 2895402
1,1,2,2-Tetrachloroethane 12/12/08 5:100.34 50ND NDG 2895402
1,1,2-Trichloroethane 12/12/08 5:100.34 50ND NDG 2895402
1,1-Dichloroethane 12/12/08 5:100.34 50ND NDG 2895402
1,1-Dichloroethene 12/12/08 5:100.34 50ND NDG 2895402
1,2-Dichloroethane 12/12/08 5:100.34 50ND NDG 2895402
1,2-Dichloropropane 12/12/08 5:100.34 50ND NDG 2895402
2-Butanone 12/12/08 5:101.4 50ND NDG 2895402
2-Hexanone 12/12/08 5:100.68 50ND NDG 2895402
4-Methyl-2-pentanone 12/12/08 5:100.68 50ND NDG 2895402
Acetone 12/12/08 5:106.8 50ND NDG 2895402
Benzene 12/12/08 5:100.034 500.036 NDG 2895402
Bromodichloromethane 12/12/08 5:100.34 50ND NDG 2895402
Bromoform 12/12/08 5:100.34 50ND NDG 2895402
Bromomethane 12/12/08 5:100.68 50ND NDG 2895402
Carbon disulfide 12/12/08 5:100.34 50ND NDG 2895402
Carbon tetrachloride 12/12/08 5:100.34 50ND NDG 2895402
Chlorobenzene 12/12/08 5:100.34 50ND NDG 2895402
Chloroethane 12/12/08 5:100.68 50ND NDG 2895402
Chloroform 12/12/08 5:100.34 50ND NDG 2895402
Chloromethane 12/12/08 5:100.34 50ND NDG 2895402
cis-1,3-Dichloropropene 12/12/08 5:100.34 50ND NDG 2895402
Dibromochloromethane 12/12/08 5:100.34 50ND NDG 2895402
Diisopropyl ether 12/12/08 5:100.34 50ND NDG 2895402
Ethylbenzene 12/12/08 5:100.068 50ND NDG 2895402
Methyl tert-butyl ether 12/12/08 5:100.068 50ND NDG 2895402
Methylene chloride 12/12/08 5:100.68 50ND NDG 2895402
Styrene 12/12/08 5:100.34 50ND NDG 2895402
Tetrachloroethene 12/12/08 5:100.34 50ND NDG 2895402
Toluene 12/12/08 5:100.068 50ND NDG 2895402
trans-1,3-Dichloropropene 12/12/08 5:100.34 50ND NDG 2895402
Trichloroethene 12/12/08 5:100.34 50ND NDG 2895402
Trichlorofluoromethane 12/12/08 5:100.34 50ND NDG 2895402
Vinyl acetate 12/12/08 5:100.68 50ND NDG 2895402
Vinyl chloride 12/12/08 5:100.68 50ND NDG 2895402
cis-1,2-Dichloroethene 12/12/08 5:100.34 50ND NDG 2895402
m,p-Xylene 12/12/08 5:100.14 50ND NDG 2895402
o-Xylene 12/12/08 5:100.068 50ND NDG 2895402
trans-1,2-Dichloroethene 12/12/08 5:100.34 50ND NDG 2895402
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:49 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 9
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1 38-40
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:08120220-04
Dil. Factor AnalystQUAL Seq. #
Collected:12/04/2008 11:40
Site:CAJAH MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)12/12/08 5:100.34 50ND NDG 2895402
Xylenes,Total 12/12/08 5:100.068 50ND NDG 2895402
Surr: 1,2-Dichloroethane-d4 12/12/08 5:10% 62-134 5083.5 NDG 2895402
Surr: 4-Bromofluorobenzene 12/12/08 5:10% 75-128 5099.0 NDG 2895402
Surr: Toluene-d8 12/12/08 5:10% 78-120 50102 NDG 2895402
Prep Method Prep Date Prep Initials Prep Factor
12/08/2008 15:55 CDPSW5035 1.14
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 12/15/08 13:044.2 50ND JAP 2898489
C9-C10 Aromatics 12/15/08 13:041.4 50ND JAP 2898449
C9-C12 Aliphatics 12/15/08 13:04550ND JAP 2898489
Surr: 2,5-Dibromotoluene 12/15/08 13:04% 70-130 50110 JAP 2898449
Surr: 2,5-Dibromotoluene 12/15/08 13:04% 70-130 50105 JAP 2898489
Prep Method Prep Date Prep Initials Prep Factor
12/08/2008 15:56 CDPSW8015B 1.19
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
1/12/2009 3:29:50 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
08120220 Page 10
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Documentation
1/12/2009 3:29:50 PM
08120220 Page 11
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R193905
WorkOrder:08120220
Method:D2216
Analysis:PERCENT MOISTURE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Sample
Result
DUP
Result
RPD RPD
Limit
Sample Duplicate
Original Sample:08120220-04
Analysis Date: 12/08/2008 17:28 Analyst:RDH
RunID:WET_081209A-2890463 Units:wt%
Percent Moisture 16.516 4.3 20
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
08120220-01A MW-1 8-10
08120220-02A MW-1 18-20
08120220-03A MW-1 28-30
08120220-04A MW-1 38-40
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:52 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 12
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194389
WorkOrder:08120220
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/15/2008 4:42 Analyst:JAP
RunID:HPCC_081213E-2898443 Units:mg/Kg
C9-C10 Aromatics 0.0800 0.0698 87.2 70 1300.0800 0.0681 85.1 2.5 20
Surr: 2,5-Dibromotoluene 200 238 119 70 1302002351181.1 30
Analyte Result Rep Limit
Method Blank
Analysis Date:12/15/2008 3:15 Analyst:JAP
RunID:HPCC_081213E-2898442 Units:mg/Kg
C9-C10 Aromatics 0.020ND
Surr: 2,5-Dibromotoluene 70-130119.9
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
08120220-01A MW-1 8-10
08120220-02A MW-1 18-20
08120220-03A MW-1 28-30
08120220-04A MW-1 38-40
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:53 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 13
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194392
WorkOrder:08120220
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/15/2008 4:42 Analyst:JAP
RunID:HPCC_081213F-2898476 Units:mg/Kg
C5-C8 Aliphatics 0.300 0.312 104 70 1300.300 0.311 104 0.3 20
C9-C12 Aliphatics 0.280 0.251 89.7 70 1300.280 0.250 89.2 0.6 20
Surr: 2,5-Dibromotoluene 200 234 117 70 1302002331170.4 30
Analyte Result Rep Limit
Method Blank
Analysis Date:12/15/2008 3:15 Analyst:JAP
RunID:HPCC_081213F-2898475 Units:mg/Kg
C5-C8 Aliphatics 0.060ND
C9-C12 Aliphatics 0.070ND Surr: 2,5-Dibromotoluene 70-130118.3
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
08120220-01A MW-1 8-10
08120220-02A MW-1 18-20
08120220-03A MW-1 28-30
08120220-04A MW-1 38-40
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:53 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 14
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:120808A2
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:12/08/2008 11:25
Preparation Date:12/08/2008 11:25
Analyst:TDD
RunID:HB_081208A-2891440 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.0050ND
1,1,2,2-Tetrachloroethane 0.0050ND1,1,2-Trichloroethane 0.0050ND
1,1-Dichloroethane 0.0050ND1,1-Dichloroethene 0.0050ND
1,2-Dichloroethane 0.0050ND1,2-Dichloropropane 0.0050ND
2-Butanone 0.020ND2-Hexanone 0.010ND
4-Methyl-2-pentanone 0.010NDAcetone0.10ND
Benzene 0.0010NDBromodichloromethane0.0050ND
Bromoform 0.0050NDBromomethane0.010ND
Carbon disulfide 0.0050ND
Carbon tetrachloride 0.0050ND
Chlorobenzene 0.0050ND
Chloroethane 0.010ND
Chloroform 0.0050ND
Chloromethane 0.0050ND
cis-1,3-Dichloropropene 0.0050ND
Dibromochloromethane 0.0050ND
Diisopropyl ether 0.0050ND
Ethylbenzene 0.0010ND
Methyl tert-butyl ether 0.0050ND
Methylene chloride 0.010ND
Styrene 0.0050ND
Tetrachloroethene 0.0050ND
Toluene 0.0010ND
trans-1,3-Dichloropropene 0.0050ND
Trichloroethene 0.0050ND
Trichlorofluoromethane 0.0050ND
Vinyl acetate 0.010ND
Vinyl chloride 0.010ND
cis-1,2-Dichloroethene 0.0050ND
m,p-Xylene 0.0020ND
o-Xylene 0.0010ND
trans-1,2-Dichloroethene 0.0050ND
1,2-Dichloroethene (total)0.0050ND
Xylenes,Total 0.0010ND
Surr: 1,2-Dichloroethane-d4 67-158109.0
Surr: 4-Bromofluorobenzene 84-112101.7
Surr: Toluene-d8 89-11299.2
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
08120220-01A MW-1 8-10
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:53 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 15
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:120808A2
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/08/2008 10:02
Preparation Date:12/08/2008 10:02
Analyst:TDD
Prep By:MethodSW5035
RunID:HB_081208A-2891438 Units:mg/Kg
1,1,1-Trichloroethane 0.0500 0.0531 106 72 1290.0500 0.0537 107 1.3 30
1,1,2,2-Tetrachloroethane 0.0500 0.0531 106 69 1400.0500 0.0545 109 2.5 30
1,1,2-Trichloroethane 0.0500 0.0548 110 73 1340.0500 0.0550 110 0.3 30
1,1-Dichloroethane 0.0500 0.0502 100 77 1270.0500 0.0524 105 4.1 30
1,1-Dichloroethene 0.0500 0.0500 100 70 1280.0500 0.0514 103 2.7 25
1,2-Dichloroethane 0.0500 0.0511 102 75 1280.0500 0.0521 104 2.0 30
1,2-Dichloropropane 0.0500 0.0473 94.6 79 1260.0500 0.0488 97.5 3.0 30
2-Butanone 0.125 0.128 102 64 1410.125 0.130 104 1.9 30
2-Hexanone 0.125 0.128 103 59 1480.125 0.127 101 1.4 30
4-Methyl-2-pentanone 0.125 0.140 112 66 1460.125 0.139 111 1.4 30
Acetone 0.125 0.124 99.0 69 1400.125 0.125 100 1.3 30
Benzene 0.0500 0.0501 100 77 1210.0500 0.0526 105 4.9 21
Bromodichloromethane 0.0500 0.0543 109 80 1280.0500 0.0558 112 2.8 30
Bromoform 0.0500 0.0540 108 62 1190.0500 0.0558 112 3.2 30
Bromomethane 0.0500 0.0376 75.3 66 1410.0500 0.0364 72.9 3.2 30
Carbon disulfide 0.0500 0.0501 100 63 1300.0500 0.0518 104 3.4 30
Carbon tetrachloride 0.0500 0.0512 102 75 1370.0500 0.0521 104 1.9 30
Chlorobenzene 0.0500 0.0508 102 72 1320.0500 0.0522 104 2.7 20
Chloroethane 0.0500 0.0406 81.2 75 1320.0500 0.0412 82.4 1.4 30
Chloroform 0.0500 0.0511 102 75 1270.0500 0.0525 105 2.8 30
Chloromethane 0.0500 0.0429 85.8 70 1280.0500 0.0446 89.1 3.8 30
cis-1,3-Dichloropropene 0.0500 0.0526 105 81 1350.0500 0.0541 108 2.9 30
Dibromochloromethane 0.0500 0.0523 105 72 1340.0500 0.0535 107 2.3 30
Diisopropyl ether 0.0500 0.0530 106 86 1260.0500 0.0546 109 3.0 30
Ethylbenzene 0.0500 0.0499 99.7 67 1350.0500 0.0513 103 2.9 30
Methyl tert-butyl ether 0.0500 0.0533 107 80 1290.0500 0.0527 105 1.0 30
Methylene chloride 0.0500 0.0604 121 74 1430.0500 0.0604 121 0.1 30
Styrene 0.0500 0.0506 101 69 1390.0500 0.0507 101 0.3 30
Tetrachloroethene 0.0500 0.0517 103 68 1390.0500 0.0533 107 2.9 30
Toluene 0.0500 0.0471 94.2 79 1230.0500 0.0489 97.7 3.6 20
trans-1,3-Dichloropropene 0.0500 0.0585 117 75 1410.0500 0.0577 115 1.3 30
Trichloroethene 0.0500 0.0525 105 82 1280.0500 0.0545 109 3.6 23
Trichlorofluoromethane 0.0500 0.0444 88.7 70 1340.0500 0.0458 91.6 3.2 30
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:54 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 16
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:120808A2
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/08/2008 10:02
Preparation Date:12/08/2008 10:02
Analyst:TDD
Prep By:MethodSW5035
RunID:HB_081208A-2891438 Units:mg/Kg
Vinyl acetate 0.0500 0.0605 121 47 1550.0500 0.0607 121 0.4 30
Vinyl chloride 0.0500 0.0449 89.8 72 1310.0500 0.0462 92.3 2.8 30
cis-1,2-Dichloroethene 0.0500 0.0523 105 83 1240.0500 0.0528 106 0.9 30
m,p-Xylene 0.100 0.0991 99.1 66 1330.100 0.102 102 2.7 30
o-Xylene 0.0500 0.0501 100 71 1340.0500 0.0516 103 2.9 30
trans-1,2-Dichloroethene 0.0500 0.0513 103 78 1270.0500 0.0531 106 3.5 30
1,2-Dichloroethene (total)0.1000 0.1036 103.6 78 1260.1000 0.1059 105.9 2.2 30
Xylenes,Total 0.1500 0.1492 99.49 0.1500 0.1536 102.3 2.8 30
Surr: 1,2-Dichloroethane-d4 50.0 50.3 101 67 15850.0 50.2 100 0.2 30
Surr: 4-Bromofluorobenzene 50.0 49.3 98.5 84 11250.0 49.6 99.3 0.7 30
Surr: Toluene-d8 50.0 49.1 98.3 89 11250.0 49.3 98.7 0.4 30
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:54 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 17
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:12/11/2008 22:53
Preparation Date:12/11/2008 22:53
Analyst:NDG
RunID:GB_081211D-2895388 Units:ug/L
Prep By:MethodSW5035
1,1,1-Trichloroethane 5.0ND
1,1,2,2-Tetrachloroethane 5.0ND1,1,2-Trichloroethane 5.0ND
1,1-Dichloroethane 5.0ND1,1-Dichloroethene 5.0ND
1,2-Dichloroethane 5.0ND1,2-Dichloropropane 5.0ND
2-Butanone 20ND2-Hexanone 10ND
4-Methyl-2-pentanone 10NDAcetone100ND
Benzene 0.50NDBromodichloromethane5.0ND
Bromoform 5.0NDBromomethane10ND
Carbon disulfide 5.0ND
Carbon tetrachloride 5.0ND
Chlorobenzene 5.0ND
Chloroethane 10ND
Chloroform 5.0ND
Chloromethane 5.0ND
cis-1,3-Dichloropropene 5.0ND
Dibromochloromethane 5.0ND
Diisopropyl ether 5.0ND
Ethylbenzene 1.0ND
Methyl tert-butyl ether 1.0ND
Methylene chloride 10ND
Styrene 5.0ND
Tetrachloroethene 5.0ND
Toluene 1.0ND
trans-1,3-Dichloropropene 5.0ND
Trichloroethene 5.0ND
Trichlorofluoromethane 5.0ND
Vinyl acetate 10ND
Vinyl chloride 10ND
cis-1,2-Dichloroethene 5.0ND
m,p-Xylene 2.0ND
o-Xylene 1.0ND
trans-1,2-Dichloroethene 5.0ND
1,2-Dichloroethene (total)5.0ND
Xylenes,Total 1.0ND
Surr: 1,2-Dichloroethane-d4 74-13392.9
Surr: 4-Bromofluorobenzene 74-116101.5
Surr: Toluene-d8 84-112100.6
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
08120220-04A MW-1 38-40
Methanolic Preparation Blank
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:54 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 18
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Analyte Result Rep Limit
Analysis Date:12/11/2008 23:20
Preparation Date:12/11/2008 23:20
Analyst:NDG
RunID:GB_081211D-2895389 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.25ND1,1,2,2-Tetrachloroethane 0.25ND
1,1,2-Trichloroethane 0.25ND1,1-Dichloroethane 0.25ND
1,1-Dichloroethene 0.25ND1,2-Dichloroethane 0.25ND
1,2-Dichloropropane 0.25ND2-Butanone 1ND
2-Hexanone 0.5ND4-Methyl-2-pentanone 0.5ND
Acetone 5NDBenzene0.25ND
Bromodichloromethane 0.25NDBromoform0.25ND
Bromomethane 0.5NDCarbon disulfide 0.25ND
Carbon tetrachloride 0.25ND
Chlorobenzene 0.25ND
Chloroethane 0.5ND
Chloroform 0.25ND
Chloromethane 0.25ND
cis-1,3-Dichloropropene 0.25ND
Dibromochloromethane 0.25ND
Diisopropyl ether 0.25ND
Ethylbenzene 0.25ND
Methyl tert-butyl ether 0.25ND
Methylene chloride 0.5ND
Styrene 0.25ND
Tetrachloroethene 0.25ND
Toluene 0.25ND
trans-1,3-Dichloropropene 0.25ND
Trichloroethene 0.25ND
Trichlorofluoromethane 0.25ND
Vinyl acetate 0.5ND
Vinyl chloride 0.5ND
cis-1,2-Dichloroethene 0.25ND
m,p-Xylene 0.25ND
o-Xylene 0.25ND
trans-1,2-Dichloroethene 0.25ND
1,2-Dichloroethene (total)0.25ND
Xylenes,Total 0.25ND
Surr: 1,2-Dichloroethane-d4 62-13477.4
Surr: 4-Bromofluorobenzene 75-128101.1
Surr: Toluene-d8 78-120102.3
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:55 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 19
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/11/2008 21:33 Analyst:NDG
RunID:GB_081211D-2895386 Units:ug/L
1,1,1-Trichloroethane 50.0 51.1 102 67 13250.0 53.9 108 5.5 26
1,1,2,2-Tetrachloroethane 50.0 53.2 106 73 12750.0 52.7 105 1.0 26
1,1,2-Trichloroethane 50.0 51.0 102 81 12150.0 52.1 104 2.2 20
1,1-Dichloroethane 50.0 50.5 101 80 12450.0 52.4 105 3.8 23
1,1-Dichloroethene 50.0 51.4 103 74 12450.0 53.5 107 3.9 23
1,2-Dichloroethane 50.0 51.1 102 73 13450.0 54.3 109 6.0 21
1,2-Dichloropropane 50.0 52.4 105 78 12250.0 54.4 109 3.7 27
2-Butanone 125 141 113 51 1491251381102.2 50
2-Hexanone 125 144 115 59 1391251421141.0 55
4-Methyl-2-pentanone 125 142 114 74 1261251421140.3 30
Acetone 125 135 108 22 1921251371091.2 58
Benzene 50.0 49.9 99.7 79 12450.0 51.3 103 2.9 23
Bromodichloromethane 50.0 50.9 102 70 13350.0 53.6 107 5.1 21
Bromoform 50.0 44.8 89.5 57 11450.0 45.0 89.9 0.4 27
Bromomethane 50.0 50.5 101 51 13950.0 56.1 112 10.6 28
Carbon disulfide 50.0 48.5 97.0 64 13850.0 50.8 102 4.6 23
Carbon tetrachloride 50.0 46.9 93.9 65 13650.0 49.0 98.1 4.4 35
Chlorobenzene 50.0 50.1 100 80 12250.0 51.2 102 2.1 19
Chloroethane 50.0 49.0 98.0 52 14850.0 50.7 101 3.4 26
Chloroform 50.0 48.2 96.4 76 12250.0 50.7 101 5.1 42
Chloromethane 50.0 47.8 95.7 67 12950.0 56.8 114 17.2 28
cis-1,3-Dichloropropene 50.0 48.5 97.0 70 13050.0 50.3 101 3.6 20
Dibromochloromethane 50.0 47.2 94.3 71 11850.0 48.5 96.9 2.7 20
Diisopropyl ether 50.0 50.8 102 79 12750.0 52.8 106 3.8 21
Ethylbenzene 50.0 48.8 97.7 79 12550.0 50.5 101 3.3 16
Methyl tert-butyl ether 50.0 53.9 108 77 12550.0 55.1 110 2.2 23
Methylene chloride 50.0 52.8 106 76 13950.0 55.7 111 5.3 22
Styrene 50.0 52.5 105 76 12850.0 53.5 107 1.8 19
Tetrachloroethene 50.0 49.4 98.8 76 12350.0 49.0 98.1 0.7 20
Toluene 50.0 48.7 97.4 79 12450.0 50.8 102 4.1 21
trans-1,3-Dichloropropene 50.0 53.8 108 65 12650.0 54.6 109 1.5 20
Trichloroethene 50.0 52.8 106 77 12150.0 53.5 107 1.4 20
Trichlorofluoromethane 50.0 52.8 106 61 14850.0 54.1 108 2.4 25
Vinyl acetate 50.0 50.5 101 18 18050.0 50.4 101 0.2 59
Vinyl chloride 50.0 52.9 106 63 13750.0 57.0 114 7.3 20
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:55 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 20
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:12/11/2008 21:33 Analyst:NDG
RunID:GB_081211D-2895386 Units:ug/L
cis-1,2-Dichloroethene 50.0 50.2 100 80 12150.0 52.7 105 5.0 28
m,p-Xylene 100 103 103 77 1321001061062.7 20
o-Xylene 50.0 51.2 102 76 12750.0 52.7 105 3.0 17
trans-1,2-Dichloroethene 50.0 51.5 103 75 12850.0 53.8 108 4.4 22
1,2-Dichloroethene (total)100.0 101.7 101.7 81 122100.0 106.5 106.5 4.7 28
Xylenes,Total 150.0 154.2 103.0 76 130150.0 158.7 106.0 2.8 20
Surr: 1,2-Dichloroethane-d4 50.0 47.9 95.8 74 13350.0 49.4 98.8 3.0 30
Surr: 4-Bromofluorobenzene 50.0 49.8 99.7 74 11650.0 49.2 98.3 1.4 30
Surr: Toluene-d8 50.0 50.5 101 84 11250.0 50.7 101 0.5 30
Analyte MS Spike
Added
MSDResult MSD % Recovery RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult Low Limit High LimitMSResultMS % Recovery
Sample Spiked:08110453-06
MSD Spike
Added
Analysis Date: 12/12/2008 6:04 Analyst:NDG
RunID:GB_081211D-2896156 Units:mg/L
1,1,1-Trichloroethane 0.05 0.0489 97.9 50 150ND260.5070.0487 97.4 0.05
1,1,2,2-Tetrachloroethane 0.05 0.0565 113 50 150ND260.3110.0564 113 0.05
1,1,2-Trichloroethane 0.05 0.0521 104 50 150ND201.650.0513 103 0.05
1,1-Dichloroethane 0.05 0.0511 102 50 150ND231.450.0518 104 0.05
1,1-Dichloroethene 0.05 0.0483 96.6 69 150ND231.620.0475 95.0 0.05
1,2-Dichloroethane 0.05 0.0514 103 50 150ND214.170.0535 107 0.05
1,2-Dichloropropane 0.05 0.0519 104 50 150ND270.6680.0522 104 0.05
2-Butanone 0.125 0.128 102 50 150ND500.3420.127 102 0.125
2-Hexanone 0.125 0.133 106 50 150ND550.5660.132 106 0.125
4-Methyl-2-pentanone 0.125 0.140 112 50 150ND302.470.144 115 0.125
Acetone 0.125 0.0977 78.2 50 150ND583.410.0945 75.6 0.125
Benzene 0.05 0.0481 96.3 77 127ND231.680.0490 97.9 0.05
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:55 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 21
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte MS
Spike Added
MSD
Result
MSD %
Recovery
RPD RPD
Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
Sample
Result
Low
Limit
High
Limit
MS
Result
MS %
Recovery
Sample Spiked:08110453-06
MSD
Spike Added
Analysis Date: 12/12/2008 6:04 Analyst:NDG
RunID:GB_081211D-2896156 Units:mg/L
Bromodichloromethane 0.05 0.0508 102 50 150ND212.660.0495 99.0 0.05
Bromoform 0.05 0.0416 83.3 50 150ND274.590.0398 79.6 0.05
Bromomethane 0.05 0.0405 81.1 50 150ND2820.50.0330 66.0 0.05
Carbon disulfide 0.05 0.0445 89.1 50 150ND232.780.0458 91.6 0.05
Carbon tetrachloride 0.05 0.0437 87.4 50 150ND357.640.0405 81.0 0.05
Chlorobenzene 0.05 0.0486 97.2 75 120ND191.310.0493 98.5 0.05
Chloroethane 0.05 0.0449 89.8 50 150ND260.5380.0446 89.3 0.05
Chloroform 0.05 0.0490 98.1 50 150ND421.200.0496 99.2 0.05
Chloromethane 0.05 0.0519 104 50 150ND281.960.0509 102 0.05
cis-1,3-Dichloropropene 0.05 0.0453 90.5 50 150ND200.4770.0455 91.0 0.05
Dibromochloromethane 0.05 0.0451 90.2 50 150ND202.250.0441 88.2 0.05
Diisopropyl ether 0.05 0.0511 102 50 150ND210.4540.0514 103 0.05
Ethylbenzene 0.05 0.0466 93.2 50 150ND160.3820.0464 92.8 0.05
Methyl tert-butyl ether 0.05 0.0542 108 50 150ND230.7030.0546 109 0.05
Methylene chloride 0.05 0.0485 96.9 50 150ND221.980.0494 98.8 0.05
Styrene 0.05 0.0508 102 50 150ND197.470.0471 94.2 0.05
Tetrachloroethene 0.05 0.0481 91.7 50 150ND201.380.0488 93.1 0.05
Toluene 0.05 0.0473 94.7 71 135ND211.030.0469 93.7 0.05
trans-1,3-Dichloropropene 0.05 0.0495 99.0 50 150ND200.01430.0495 99.1 0.05
Trichloroethene 0.05 0.0477 95.5 74 129ND200.8270.0481 96.3 0.05
Trichlorofluoromethane 0.05 0.0470 94.0 50 150ND252.320.0481 96.2 0.05
Vinyl acetate 0.05 0.0514 103 50 150ND590.9930.0519 104 0.05
Vinyl chloride 0.05 0.0489 97.7 50 150ND200.2040.0488 97.5 0.05
cis-1,2-Dichloroethene 0.05 0.0503 101 50 150ND284.080.0524 105 0.05
m,p-Xylene 0.1 0.0979 97.9 50 150ND201.940.0960 96.0 0.1
o-Xylene 0.05 0.0495 99.0 50 150ND171.850.0486 97.2 0.05
trans-1,2-Dichloroethene 0.05 0.0489 97.8 50 150ND220.5410.0486 97.3 0.05
1,2-Dichloroethene (total)0.1 0.0992 99.2 50 150ND281.830.101 101 0.1
Xylenes,Total 0.15 0.1474 98.28 50 150ND201.9120.1446 96.42 0.15
Surr: 1,2-Dichloroethane-d4 50 49.4 98.8 74 133ND300.24749.3 98.6 50
Surr: 4-Bromofluorobenzene 50 50.2 100 74 116ND300.3355010050
Surr: Toluene-d8 50 50.4 101 84 112ND300.87350.8 102 50
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:55 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 22
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R194185
WorkOrder:08120220
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
1/12/2009 3:29:56 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
08120220 Page 23
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Attachment 2
VPH Laboratory Reporting Form
Calibration and QA/QC Information
Initial Calibration Date
Calibration Ranges and Limits
Range MDL ML RL
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
NOTE: Please include units as appropriate
Method of Quantitation (check one): Curve or Average Response Factor
Calibration Concentration Levels
Range Levels
%RSD
CCC
60
120
240
600
1200
2400
3600
6000
70
140
280
700
1400
2800
4200
7000
20
40
80
200
400
800
1200
2000
C5 - C8
Aliphatics
C9 - C12
Aliphatics
C9 - C10
Aromatics
NOTE: Please include units as appropriate
Calibration Check Date
Calibration Check
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
600
700
200
9.8
20.1
13.6
MDL = Method Detection Limit
ML = Minimum Limit
RL = Reportable Limit
RPD = Relative Percent Difference
%RSD = Percent Relative Standard Deviation
CCC = Correlation Coefficient of Curve
revision 4/5/05
11.01
10.28
12.98
12/15/2008
29.9245ug/Kg-dry
17.9792ug/Kg-dry
2.8608ug/Kg-dry
60ug/Kg-dry
70ug/Kg-dry
20ug/Kg-dry
60ug/Kg-dry
70ug/Kg-dry
20ug/Kg-dry
12/05/08
Range Level RPD
VPH (Aliphatics/Aromatics) Laboratory Reporting Form Continued
Client Name
Site Location
INCLUDE APPROPRIATE UNITS:
Sample Information and Analytical Results
Sample Identification MW-1 8-10 MW-1 18-20 MW-1 28-30 MW-1 38-40
Sample Matrix
Date Collected
Date Received
Date Extracted
Date Analyzed
Dry Weight
Dilution Factor
C5 - C8 Aliphatics*
C9 - C12 Aliphatics*
C9 - C10 Aromatics*
Surrogate % Recovery - PID
Surrogate % Recovery - FID
*Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
Percent Recovery - Fortified Blank (Spike) - PID
Relative Percent Difference - PID Duplicate
C5 -C8
Aliphatic
C9 -C12
Aliphatic
C9 -C10
Aromatic
SOIL
12/4/2008
12/4/2008
12/5/2008
12/15/2008
N/A
50
ND
ND
2.3
97.7
95.9
SOIL SOIL SOIL
12/4/2008 12/4/2008 12/4/2008
12/4/2008 12/4/2008 12/4/2008
12/5/2008 12/5/2008 12/5/2008
12/15/2008 12/15/2008 12/15/2008
N/A N/A N/A
50 50 50
ND ND ND
ND ND ND
ND ND ND
107 108 110
100 103 105
N/A
N/A
N/A 85.1
N/A 2.5
Project Name
ATC ASSOCIATES, INC.
89.03451.1018
CAJAH MOUNTAIN SUPERETTE
Laboratory Name Southern Petroleum Laboratories
NC Certification # (Lab)187
revision 4/5/05
Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. Encore) Option 3 = Field weight of soil
Percent Recovery - Fortified Blank (Spike) - FID 104 89.2 N/A
Relative Percent Difference - FID Duplicate 0.3 0.6 N/A
Percent Recovery - Matrix (Spike) - PID N/A N/A 87.2
Percent Recovery - Matrix (Spike) - FID 104 89.7 N/A
Lab ID 08120220-01A 08120220-02A 08120220-03A 08120220-04A
NC= Not calculated (Sample exceeds spike by factor of 4 or more)
Chain of Custody
And
Sample Receipt Checklist
1/12/2009 3:29:56 PM
08120220 Page 24
Sample Receipt Checklist
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:08120220
Date and Time Received:12/5/2008 10:30:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:3°C
Received By:COM
SPL Representative:
Non Conformance Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
1/12/2009 3:29:57 PM
08120220 Page 25
Case Narrative for:
09110396
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
DIANA LANIER
Date Reported:11/20/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample
(LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above
Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateAmy K. Jackson
11/20/2009
Project Manager
09110396 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
09110396
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
[phone]
DIANA LANIER
Date Reported:11/20/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
09110396-01 11/10/2009 9:30:00 AMSB-1 (28-30)11/4/2009 5:45:00 PMSoil 297227
09110396-02 11/10/2009 9:30:00 AMSB-2 (18-20')11/4/2009 4:30:00 PMSoil 297227
09110396-03 11/10/2009 9:30:00 AMSB-3 (30-34')11/5/2009 11:30:00 AMSoil 297227
09110396-04 11/10/2009 9:30:00 AMSB-4 (25-30')11/5/2009 10:00:00 AMSoil 297227
09110396-05 11/10/2009 9:30:00 AMSB-5 (33-35')11/4/2009 3:00:00 PMSoil 297227
09110396-06 11/10/2009 9:30:00 AMMW-5 (25-30')11/5/2009 3:00:00 PMSoil 297227
09110396-07 11/10/2009 9:30:00 AMMW-8 (25-30')11/5/2009 5:30:00 PMSoil 297227
Date
Laboratory Director
Quality Assurance Officer
Amy K. Jackson
09110396 Page 2
11/20/2009
11/20/2009 4:08:41 PM
Project Manager
Ron Benjamin
Tristan Davis
Client Sample ID:SB-1 (28-30)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 17:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 113 JNY 3339970
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:53 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 3
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-1 (28-30)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 17:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/13/09 21:380.0059 1ND TDD 3340488
1,1,2,2-Tetrachloroethane 11/13/09 21:380.0059 1ND TDD 3340488
1,1,2-Trichloroethane 11/13/09 21:380.0059 1ND TDD 3340488
1,1-Dichloroethane 11/13/09 21:380.0059 1ND TDD 3340488
1,1-Dichloroethene 11/13/09 21:380.0059 1ND TDD 3340488
1,2-Dichloroethane 11/13/09 21:380.0059 1ND TDD 3340488
1,2-Dichloropropane 11/13/09 21:380.0059 1ND TDD 3340488
2-Butanone 11/13/09 21:380.023 10.035 TDD 3340488
2-Hexanone 11/13/09 21:380.012 10.033 TDD 3340488
4-Methyl-2-pentanone 11/13/09 21:380.012 10.018 TDD 3340488
Acetone 11/13/09 21:380.12 1ND TDD 3340488
Benzene 11/13/09 21:380.0059 10.0093 TDD 3340488
Bromodichloromethane 11/13/09 21:380.0059 1ND TDD 3340488
Bromoform 11/13/09 21:380.0059 1ND TDD 3340488
Bromomethane 11/13/09 21:380.012 1ND TDD 3340488
Carbon disulfide 11/13/09 21:380.0059 1ND TDD 3340488
Carbon tetrachloride 11/13/09 21:380.0059 1ND TDD 3340488
Chlorobenzene 11/13/09 21:380.0059 1ND TDD 3340488
Chloroethane 11/13/09 21:380.012 1ND TDD 3340488
Chloroform 11/13/09 21:380.0059 1ND TDD 3340488
Chloromethane 11/13/09 21:380.0059 1ND TDD 3340488
cis-1,3-Dichloropropene 11/13/09 21:380.0059 1ND TDD 3340488
Dibromochloromethane 11/13/09 21:380.0059 1ND TDD 3340488
Diisopropyl ether 11/13/09 21:380.0059 1ND TDD 3340488
Ethylbenzene 11/13/09 21:380.0059 1ND TDD 3340488
Methyl tert-butyl ether 11/13/09 21:380.0059 10.046 TDD 3340488
Methylene chloride 11/13/09 21:380.012 1ND TDD 3340488
Styrene 11/13/09 21:380.0059 1ND TDD 3340488
Tetrachloroethene 11/13/09 21:380.0059 1ND TDD 3340488
Toluene 11/13/09 21:380.0059 1ND TDD 3340488
trans-1,3-Dichloropropene 11/13/09 21:380.0059 1ND TDD 3340488
Trichloroethene 11/13/09 21:380.0059 1ND TDD 3340488
Trichlorofluoromethane 11/13/09 21:380.0059 1ND TDD 3340488
Vinyl acetate 11/13/09 21:380.012 1ND TDD 3340488
Vinyl chloride 11/13/09 21:380.012 1ND TDD 3340488
cis-1,2-Dichloroethene 11/13/09 21:380.0059 1ND TDD 3340488
m,p-Xylene 11/13/09 21:380.0059 1ND TDD 3340488
o-Xylene 11/13/09 21:380.0059 1ND TDD 3340488
trans-1,2-Dichloroethene 11/13/09 21:380.0059 1ND TDD 3340488
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:53 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 4
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-1 (28-30)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 17:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/13/09 21:380.0059 1ND TDD 3340488
Xylenes,Total 11/13/09 21:380.0059 1ND TDD 3340488
Surr: 1,2-Dichloroethane-d4 11/13/09 21:38% 50-166 1114 TDD 3340488
Surr: 4-Bromofluorobenzene 11/13/09 21:38% 79-123 1101 TDD 3340488
Surr: Toluene-d8 11/13/09 21:38% 62-146 195.6 TDD 3340488
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 17:45 FieldSW5035 1.02
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/19/09 21:394.9 100ND SRA 3349335
C9-C10 Aromatics 11/19/09 21:391.6 100ND SRA 3349301
C9-C12 Aliphatics 11/19/09 21:395.7 100ND SRA 3349335
Surr: 2,5-Dibromotoluene 11/19/09 21:39% 70-130 100106 SRA 3349335
Surr: 2,5-Dibromotoluene 11/19/09 21:39% 70-130 100101 SRA 3349301
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 17:45 FieldMA_VPH 1.43
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:54 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 5
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-2 (18-20')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 119 JNY 3339971
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:54 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 6
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-2 (18-20')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/13/09 22:090.0064 1ND TDD 3340489
1,1,2,2-Tetrachloroethane 11/13/09 22:090.0064 1ND TDD 3340489
1,1,2-Trichloroethane 11/13/09 22:090.0064 1ND TDD 3340489
1,1-Dichloroethane 11/13/09 22:090.0064 1ND TDD 3340489
1,1-Dichloroethene 11/13/09 22:090.0064 1ND TDD 3340489
1,2-Dichloroethane 11/13/09 22:090.0064 1ND TDD 3340489
1,2-Dichloropropane 11/13/09 22:090.0064 1ND TDD 3340489
2-Butanone 11/13/09 22:090.026 10.17 TDD 3340489
2-Hexanone 11/13/09 22:090.013 10.099 TDD 3340489
4-Methyl-2-pentanone 11/13/09 22:090.013 10.041 TDD 3340489
Acetone 11/13/09 22:090.13 10.18 TDD 3340489
Benzene 11/13/09 22:090.0064 10.012 TDD 3340489
Bromodichloromethane 11/13/09 22:090.0064 1ND TDD 3340489
Bromoform 11/13/09 22:090.0064 1ND TDD 3340489
Bromomethane 11/13/09 22:090.013 1ND TDD 3340489
Carbon disulfide 11/13/09 22:090.0064 1ND TDD 3340489
Carbon tetrachloride 11/13/09 22:090.0064 1ND TDD 3340489
Chlorobenzene 11/13/09 22:090.0064 1ND TDD 3340489
Chloroethane 11/13/09 22:090.013 1ND TDD 3340489
Chloroform 11/13/09 22:090.0064 1ND TDD 3340489
Chloromethane 11/13/09 22:090.0064 1ND TDD 3340489
cis-1,3-Dichloropropene 11/13/09 22:090.0064 1ND TDD 3340489
Dibromochloromethane 11/13/09 22:090.0064 1ND TDD 3340489
Diisopropyl ether 11/13/09 22:090.0064 1ND TDD 3340489
Ethylbenzene 11/13/09 22:090.0064 1ND TDD 3340489
Methyl tert-butyl ether 11/13/09 22:090.0064 10.062 TDD 3340489
Methylene chloride 11/13/09 22:090.013 1ND TDD 3340489
Styrene 11/13/09 22:090.0064 1ND TDD 3340489
Tetrachloroethene 11/13/09 22:090.0064 1ND TDD 3340489
Toluene 11/13/09 22:090.0064 1ND TDD 3340489
trans-1,3-Dichloropropene 11/13/09 22:090.0064 1ND TDD 3340489
Trichloroethene 11/13/09 22:090.0064 1ND TDD 3340489
Trichlorofluoromethane 11/13/09 22:090.0064 1ND TDD 3340489
Vinyl acetate 11/13/09 22:090.013 1ND TDD 3340489
Vinyl chloride 11/13/09 22:090.013 1ND TDD 3340489
cis-1,2-Dichloroethene 11/13/09 22:090.0064 1ND TDD 3340489
m,p-Xylene 11/13/09 22:090.0064 1ND TDD 3340489
o-Xylene 11/13/09 22:090.0064 1ND TDD 3340489
trans-1,2-Dichloroethene 11/13/09 22:090.0064 1ND TDD 3340489
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:55 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 7
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-2 (18-20')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/13/09 22:090.0064 1ND TDD 3340489
Xylenes,Total 11/13/09 22:090.0064 1ND TDD 3340489
Surr: 1,2-Dichloroethane-d4 11/13/09 22:09% 50-166 1113 TDD 3340489
Surr: 4-Bromofluorobenzene 11/13/09 22:09% 79-123 1104 TDD 3340489
Surr: Toluene-d8 11/13/09 22:09% 62-146 195.9 TDD 3340489
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 16:30 FieldSW5035 1.04
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/20/09 13:433.9 100ND SRA 3351064
C9-C10 Aromatics 11/20/09 13:431.3 100ND SRA 3351055
C9-C12 Aliphatics 11/20/09 13:434.6 100ND SRA 3351064
Surr: 2,5-Dibromotoluene 11/20/09 13:43% 70-130 100114 SRA 3351064
Surr: 2,5-Dibromotoluene 11/20/09 13:43% 70-130 100109 SRA 3351055
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 16:30 FieldMA_VPH 1.06
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:56 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 8
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-3 (30-34')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 121 JNY 3339972
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:56 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 9
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-3 (30-34')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/14/09 15:330.29 50ND RPJ 3341618
1,1,2,2-Tetrachloroethane 11/14/09 15:330.29 50ND RPJ 3341618
1,1,2-Trichloroethane 11/14/09 15:330.29 50ND RPJ 3341618
1,1-Dichloroethane 11/14/09 15:330.29 50ND RPJ 3341618
1,1-Dichloroethene 11/14/09 15:330.29 50ND RPJ 3341618
1,2-Dichloroethane 11/14/09 15:330.29 50ND RPJ 3341618
1,2-Dichloropropane 11/14/09 15:330.29 50ND RPJ 3341618
2-Butanone 11/14/09 15:331.2 50ND RPJ 3341618
2-Hexanone 11/14/09 15:330.59 50ND RPJ 3341618
4-Methyl-2-pentanone 11/14/09 15:330.59 50ND RPJ 3341618
Acetone 11/14/09 15:335.9 50ND RPJ 3341618
Benzene 11/14/09 15:330.29 50ND RPJ 3341618
Bromodichloromethane 11/14/09 15:330.29 50ND RPJ 3341618
Bromoform 11/14/09 15:330.29 50ND RPJ 3341618
Bromomethane 11/14/09 15:330.59 50ND RPJ 3341618
Carbon disulfide 11/14/09 15:330.29 50ND RPJ 3341618
Carbon tetrachloride 11/14/09 15:330.29 50ND RPJ 3341618
Chlorobenzene 11/14/09 15:330.29 50ND RPJ 3341618
Chloroethane 11/14/09 15:330.59 50ND RPJ 3341618
Chloroform 11/14/09 15:330.29 50ND RPJ 3341618
Chloromethane 11/14/09 15:330.29 50ND RPJ 3341618
cis-1,3-Dichloropropene 11/14/09 15:330.29 50ND RPJ 3341618
Dibromochloromethane 11/14/09 15:330.29 50ND RPJ 3341618
Diisopropyl ether 11/14/09 15:330.29 50ND RPJ 3341618
Ethylbenzene 11/14/09 15:330.29 5010 RPJ 3341618
Methyl tert-butyl ether 11/14/09 15:330.29 50ND RPJ 3341618
Methylene chloride 11/14/09 15:330.59 50ND RPJ 3341618
Styrene 11/14/09 15:330.29 50ND RPJ 3341618
Tetrachloroethene 11/14/09 15:330.29 50ND RPJ 3341618
Toluene 11/14/09 15:330.29 506.7 RPJ 3341618
trans-1,3-Dichloropropene 11/14/09 15:330.29 50ND RPJ 3341618
Trichloroethene 11/14/09 15:330.29 50ND RPJ 3341618
Trichlorofluoromethane 11/14/09 15:330.29 50ND RPJ 3341618
Vinyl acetate 11/14/09 15:330.59 50ND RPJ 3341618
Vinyl chloride 11/14/09 15:330.59 50ND RPJ 3341618
cis-1,2-Dichloroethene 11/14/09 15:330.29 50ND RPJ 3341618
m,p-Xylene 11/14/09 15:330.29 5036 RPJ 3341618
o-Xylene 11/14/09 15:330.29 5016 RPJ 3341618
trans-1,2-Dichloroethene 11/14/09 15:330.29 50ND RPJ 3341618
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:57 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 10
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-3 (30-34')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/14/09 15:330.29 50ND RPJ 3341618
Xylenes,Total 11/14/09 15:330.29 5052 RPJ 3341618
Surr: 1,2-Dichloroethane-d4 11/14/09 15:33% 62-134 50109 RPJ 3341618
Surr: 4-Bromofluorobenzene 11/14/09 15:33% 75-128 50102 RPJ 3341618
Surr: Toluene-d8 11/14/09 15:33% 78-120 5094.2 RPJ 3341618
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 11:30 FieldSW5035 0.93
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/20/09 14:161850039 SRA 3351065
C9-C10 Aromatics 11/20/09 14:165.9 500250 SRA 3351056
C9-C12 Aliphatics 11/20/09 14:1621500270 SRA 3351065
Surr: 2,5-Dibromotoluene 11/20/09 14:16% 70-130 500108 SRA 3351065
Surr: 2,5-Dibromotoluene 11/20/09 14:16% 70-130 500107 SRA 3351056
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 11:30 FieldMA_VPH 0.93
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:58 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 11
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-4 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 10:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 118 JNY 3339973
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:58 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 12
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-4 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 10:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/13/09 22:400.006 1ND TDD 3340490
1,1,2,2-Tetrachloroethane 11/13/09 22:400.006 1ND TDD 3340490
1,1,2-Trichloroethane 11/13/09 22:400.006 1ND TDD 3340490
1,1-Dichloroethane 11/13/09 22:400.006 1ND TDD 3340490
1,1-Dichloroethene 11/13/09 22:400.006 1ND TDD 3340490
1,2-Dichloroethane 11/13/09 22:400.006 1ND TDD 3340490
1,2-Dichloropropane 11/13/09 22:400.006 1ND TDD 3340490
2-Butanone 11/13/09 22:400.024 10.029 TDD 3340490
2-Hexanone 11/13/09 22:400.012 1ND TDD 3340490
4-Methyl-2-pentanone 11/13/09 22:400.012 1ND TDD 3340490
Acetone 11/13/09 22:400.12 10.21 TDD 3340490
Benzene 11/13/09 22:400.006 1ND TDD 3340490
Bromodichloromethane 11/13/09 22:400.006 1ND TDD 3340490
Bromoform 11/13/09 22:400.006 1ND TDD 3340490
Bromomethane 11/13/09 22:400.012 1ND TDD 3340490
Carbon disulfide 11/13/09 22:400.006 1ND TDD 3340490
Carbon tetrachloride 11/13/09 22:400.006 1ND TDD 3340490
Chlorobenzene 11/13/09 22:400.006 1ND TDD 3340490
Chloroethane 11/13/09 22:400.012 1ND TDD 3340490
Chloroform 11/13/09 22:400.006 1ND TDD 3340490
Chloromethane 11/13/09 22:400.006 1ND TDD 3340490
cis-1,3-Dichloropropene 11/13/09 22:400.006 1ND TDD 3340490
Dibromochloromethane 11/13/09 22:400.006 1ND TDD 3340490
Diisopropyl ether 11/13/09 22:400.006 1ND TDD 3340490
Ethylbenzene 11/13/09 22:400.006 1ND TDD 3340490
Methyl tert-butyl ether 11/13/09 22:400.006 1ND TDD 3340490
Methylene chloride 11/13/09 22:400.012 1ND TDD 3340490
Styrene 11/13/09 22:400.006 1ND TDD 3340490
Tetrachloroethene 11/13/09 22:400.006 1ND TDD 3340490
Toluene 11/13/09 22:400.006 1ND TDD 3340490
trans-1,3-Dichloropropene 11/13/09 22:400.006 1ND TDD 3340490
Trichloroethene 11/13/09 22:400.006 1ND TDD 3340490
Trichlorofluoromethane 11/13/09 22:400.006 1ND TDD 3340490
Vinyl acetate 11/13/09 22:400.012 1ND TDD 3340490
Vinyl chloride 11/13/09 22:400.012 1ND TDD 3340490
cis-1,2-Dichloroethene 11/13/09 22:400.006 1ND TDD 3340490
m,p-Xylene 11/13/09 22:400.006 1ND TDD 3340490
o-Xylene 11/13/09 22:400.006 1ND TDD 3340490
trans-1,2-Dichloroethene 11/13/09 22:400.006 1ND TDD 3340490
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:08:59 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 13
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-4 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 10:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/13/09 22:400.006 1ND TDD 3340490
Xylenes,Total 11/13/09 22:400.006 1ND TDD 3340490
Surr: 1,2-Dichloroethane-d4 11/13/09 22:40% 50-166 1113 TDD 3340490
Surr: 4-Bromofluorobenzene 11/13/09 22:40% 79-123 1100 TDD 3340490
Surr: Toluene-d8 11/13/09 22:40% 62-146 197.7 TDD 3340490
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 10:00 FieldSW5035 0.98
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/19/09 20:323.8 100ND SRA 3349333
C9-C10 Aromatics 11/19/09 20:321.3 100ND SRA 3349299
C9-C12 Aliphatics 11/19/09 20:324.4 100ND SRA 3349333
Surr: 2,5-Dibromotoluene 11/19/09 20:32% 70-130 100102 SRA 3349333
Surr: 2,5-Dibromotoluene 11/19/09 20:32% 70-130 10099.3 SRA 3349299
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 10:00 FieldMA_VPH 1.04
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:00 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 14
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-5 (33-35')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 123 JNY 3339974
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:00 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 15
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-5 (33-35')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/14/09 15:020.32 50ND RPJ 3341617
1,1,2,2-Tetrachloroethane 11/14/09 15:020.32 50ND RPJ 3341617
1,1,2-Trichloroethane 11/14/09 15:020.32 50ND RPJ 3341617
1,1-Dichloroethane 11/14/09 15:020.32 50ND RPJ 3341617
1,1-Dichloroethene 11/14/09 15:020.32 50ND RPJ 3341617
1,2-Dichloroethane 11/14/09 15:020.32 50ND RPJ 3341617
1,2-Dichloropropane 11/14/09 15:020.32 50ND RPJ 3341617
2-Butanone 11/14/09 15:021.3 50ND RPJ 3341617
2-Hexanone 11/14/09 15:020.65 50ND RPJ 3341617
4-Methyl-2-pentanone 11/14/09 15:020.65 50ND RPJ 3341617
Acetone 11/14/09 15:026.5 50ND RPJ 3341617
Benzene 11/14/09 15:020.32 50ND RPJ 3341617
Bromodichloromethane 11/14/09 15:020.32 50ND RPJ 3341617
Bromoform 11/14/09 15:020.32 50ND RPJ 3341617
Bromomethane 11/14/09 15:020.65 50ND RPJ 3341617
Carbon disulfide 11/14/09 15:020.32 50ND RPJ 3341617
Carbon tetrachloride 11/14/09 15:020.32 50ND RPJ 3341617
Chlorobenzene 11/14/09 15:020.32 50ND RPJ 3341617
Chloroethane 11/14/09 15:020.65 50ND RPJ 3341617
Chloroform 11/14/09 15:020.32 50ND RPJ 3341617
Chloromethane 11/14/09 15:020.32 50ND RPJ 3341617
cis-1,3-Dichloropropene 11/14/09 15:020.32 50ND RPJ 3341617
Dibromochloromethane 11/14/09 15:020.32 50ND RPJ 3341617
Diisopropyl ether 11/14/09 15:020.32 50ND RPJ 3341617
Ethylbenzene 11/14/09 15:020.32 501.1 RPJ 3341617
Methyl tert-butyl ether 11/14/09 15:020.32 50ND RPJ 3341617
Methylene chloride 11/14/09 15:020.65 50ND RPJ 3341617
Styrene 11/14/09 15:020.32 50ND RPJ 3341617
Tetrachloroethene 11/14/09 15:020.32 50ND RPJ 3341617
Toluene 11/14/09 15:020.32 500.56 RPJ 3341617
trans-1,3-Dichloropropene 11/14/09 15:020.32 50ND RPJ 3341617
Trichloroethene 11/14/09 15:020.32 50ND RPJ 3341617
Trichlorofluoromethane 11/14/09 15:020.32 50ND RPJ 3341617
Vinyl acetate 11/14/09 15:020.65 50ND RPJ 3341617
Vinyl chloride 11/14/09 15:020.65 50ND RPJ 3341617
cis-1,2-Dichloroethene 11/14/09 15:020.32 50ND RPJ 3341617
m,p-Xylene 11/14/09 15:020.32 504 RPJ 3341617
o-Xylene 11/14/09 15:020.32 501.9 RPJ 3341617
trans-1,2-Dichloroethene 11/14/09 15:020.32 50ND RPJ 3341617
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:01 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 16
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-5 (33-35')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/04/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/14/09 15:020.32 50ND RPJ 3341617
Xylenes,Total 11/14/09 15:020.32 505.9 RPJ 3341617
Surr: 1,2-Dichloroethane-d4 11/14/09 15:02% 62-134 50114 RPJ 3341617
Surr: 4-Bromofluorobenzene 11/14/09 15:02% 75-128 50102 RPJ 3341617
Surr: Toluene-d8 11/14/09 15:02% 78-120 50102 RPJ 3341617
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 15:00 FieldSW5035 1.00
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/20/09 14:493.9 100ND SRA 3351066
C9-C10 Aromatics 11/20/09 14:491.3 10017 SRA 3351057
C9-C12 Aliphatics 11/20/09 14:494.5 10021 SRA 3351066
Surr: 2,5-Dibromotoluene 11/20/09 14:49% 70-130 100126 SRA 3351066
Surr: 2,5-Dibromotoluene 11/20/09 14:49% 70-130 100119 SRA 3351057
Prep Method Prep Date Prep Initials Prep Factor
11/04/2009 15:00 FieldMA_VPH 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:01 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 17
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 121 JNY 3339975
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:02 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 18
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/16/09 13:310.006 1ND TDD 3344213
1,1,2,2-Tetrachloroethane 11/16/09 13:310.006 1ND TDD 3344213
1,1,2-Trichloroethane 11/16/09 13:310.006 1ND TDD 3344213
1,1-Dichloroethane 11/16/09 13:310.006 1ND TDD 3344213
1,1-Dichloroethene 11/16/09 13:310.006 1ND TDD 3344213
1,2-Dichloroethane 11/16/09 13:310.006 1ND TDD 3344213
1,2-Dichloropropane 11/16/09 13:310.006 1ND TDD 3344213
2-Butanone 11/16/09 13:310.024 1ND TDD 3344213
2-Hexanone 11/16/09 13:310.012 1ND TDD 3344213
4-Methyl-2-pentanone 11/16/09 13:310.012 1ND TDD 3344213
Acetone 11/16/09 13:310.12 10.12 TDD 3344213
Benzene 11/16/09 13:310.006 1ND TDD 3344213
Bromodichloromethane 11/16/09 13:310.006 1ND TDD 3344213
Bromoform 11/16/09 13:310.006 1ND TDD 3344213
Bromomethane 11/16/09 13:310.012 1ND TDD 3344213
Carbon disulfide 11/16/09 13:310.006 1ND TDD 3344213
Carbon tetrachloride 11/16/09 13:310.006 1ND TDD 3344213
Chlorobenzene 11/16/09 13:310.006 1ND TDD 3344213
Chloroethane 11/16/09 13:310.012 1ND TDD 3344213
Chloroform 11/16/09 13:310.006 1ND TDD 3344213
Chloromethane 11/16/09 13:310.006 1ND TDD 3344213
cis-1,3-Dichloropropene 11/16/09 13:310.006 1ND TDD 3344213
Dibromochloromethane 11/16/09 13:310.006 1ND TDD 3344213
Diisopropyl ether 11/16/09 13:310.006 1ND TDD 3344213
Ethylbenzene 11/16/09 13:310.006 1ND TDD 3344213
Methyl tert-butyl ether 11/16/09 13:310.006 1ND TDD 3344213
Methylene chloride 11/16/09 13:310.012 1ND TDD 3344213
Styrene 11/16/09 13:310.006 1ND TDD 3344213
Tetrachloroethene 11/16/09 13:310.006 1ND TDD 3344213
Toluene 11/16/09 13:310.006 1ND TDD 3344213
trans-1,3-Dichloropropene 11/16/09 13:310.006 1ND TDD 3344213
Trichloroethene 11/16/09 13:310.006 1ND TDD 3344213
Trichlorofluoromethane 11/16/09 13:310.006 1ND TDD 3344213
Vinyl acetate 11/16/09 13:310.012 1ND TDD 3344213
Vinyl chloride 11/16/09 13:310.012 1ND TDD 3344213
cis-1,2-Dichloroethene 11/16/09 13:310.006 1ND TDD 3344213
m,p-Xylene 11/16/09 13:310.006 1ND TDD 3344213
o-Xylene 11/16/09 13:310.006 1ND TDD 3344213
trans-1,2-Dichloroethene 11/16/09 13:310.006 1ND TDD 3344213
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:03 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 19
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/16/09 13:310.006 1ND TDD 3344213
Xylenes,Total 11/16/09 13:310.00597 1ND TDD 3344213
Surr: 1,2-Dichloroethane-d4 11/16/09 13:31% 50-166 1120 TDD 3344213
Surr: 4-Bromofluorobenzene 11/16/09 13:31% 79-123 1108 TDD 3344213
Surr: Toluene-d8 11/16/09 13:31% 62-146 1103 TDD 3344213
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 15:00 FieldSW5035 0.94
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/19/09 21:063.7 100ND SRA 3349334
C9-C10 Aromatics 11/19/09 21:061.2 100ND SRA 3349300
C9-C12 Aliphatics 11/19/09 21:064.3 100ND SRA 3349334
Surr: 2,5-Dibromotoluene 11/19/09 21:06% 70-130 10094.7 SRA 3349300
Surr: 2,5-Dibromotoluene 11/19/09 21:06% 70-130 10087.2 SRA 3349334
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 15:00 FieldMA_VPH 0.98
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:03 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 20
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 11/13/09 14:110.1 117 JNY 3339976
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:04 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 21
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
1,1,1-Trichloroethane 11/16/09 16:200.57 100ND TDD 3344308
1,1,2,2-Tetrachloroethane 11/16/09 16:200.57 100ND TDD 3344308
1,1,2-Trichloroethane 11/16/09 16:200.57 100ND TDD 3344308
1,1-Dichloroethane 11/16/09 16:200.57 100ND TDD 3344308
1,1-Dichloroethene 11/16/09 16:200.57 100ND TDD 3344308
1,2-Dichloroethane 11/16/09 16:200.57 100ND TDD 3344308
1,2-Dichloropropane 11/16/09 16:200.57 100ND TDD 3344308
2-Butanone 11/16/09 16:202.3 100ND TDD 3344308
2-Hexanone 11/16/09 16:201.1 100ND TDD 3344308
4-Methyl-2-pentanone 11/16/09 16:201.1 100ND TDD 3344308
Acetone 11/16/09 16:2011100ND TDD 3344308
Benzene 11/16/09 16:200.57 100ND TDD 3344308
Bromodichloromethane 11/16/09 16:200.57 100ND TDD 3344308
Bromoform 11/16/09 16:200.57 100ND TDD 3344308
Bromomethane 11/16/09 16:201.1 100ND TDD 3344308
Carbon disulfide 11/16/09 16:200.57 100ND TDD 3344308
Carbon tetrachloride 11/16/09 16:200.57 100ND TDD 3344308
Chlorobenzene 11/16/09 16:200.57 100ND TDD 3344308
Chloroethane 11/16/09 16:201.1 100ND TDD 3344308
Chloroform 11/16/09 16:200.57 100ND TDD 3344308
Chloromethane 11/16/09 16:200.57 100ND TDD 3344308
cis-1,3-Dichloropropene 11/16/09 16:200.57 100ND TDD 3344308
Dibromochloromethane 11/16/09 16:200.57 100ND TDD 3344308
Diisopropyl ether 11/16/09 16:200.57 100ND TDD 3344308
Ethylbenzene 11/16/09 16:200.57 10024 TDD 3344308
Methyl tert-butyl ether 11/16/09 16:200.57 100ND TDD 3344308
Methylene chloride 11/16/09 16:201.1 100ND TDD 3344308
Styrene 11/16/09 16:200.57 100ND TDD 3344308
Tetrachloroethene 11/16/09 16:200.57 100ND TDD 3344308
Toluene 11/16/09 16:200.57 10025 TDD 3344308
trans-1,3-Dichloropropene 11/16/09 16:200.57 100ND TDD 3344308
Trichloroethene 11/16/09 16:200.57 100ND TDD 3344308
Trichlorofluoromethane 11/16/09 16:200.57 100ND TDD 3344308
Vinyl acetate 11/16/09 16:201.1 100ND TDD 3344308
Vinyl chloride 11/16/09 16:201.1 100ND TDD 3344308
cis-1,2-Dichloroethene 11/16/09 16:200.57 100ND TDD 3344308
m,p-Xylene 11/16/09 16:200.57 10084 TDD 3344308
o-Xylene 11/16/09 16:200.57 10039 TDD 3344308
trans-1,2-Dichloroethene 11/16/09 16:200.57 100ND TDD 3344308
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:04 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 22
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8 (25-30')
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110396-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/05/2009 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
1,2-Dichloroethene (total)11/16/09 16:200.57 100ND TDD 3344308
Xylenes,Total 11/16/09 16:200.57 100123 TDD 3344308
Surr: 1,2-Dichloroethane-d4 11/16/09 16:20% 62-134 100102 TDD 3344308
Surr: 4-Bromofluorobenzene 11/16/09 16:20% 75-128 10099.3 TDD 3344308
Surr: Toluene-d8 11/16/09 16:20% 78-120 10099.3 TDD 3344308
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 17:30 FieldSW5035 0.94
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 11/20/09 13:091750033 SRA 3351063
C9-C10 Aromatics 11/20/09 13:095.7 500170 SRA 3351054
C9-C12 Aliphatics 11/20/09 13:0920500190 SRA 3351063
Surr: 2,5-Dibromotoluene 11/20/09 13:09% 70-130 500111 SRA 3351063
Surr: 2,5-Dibromotoluene 11/20/09 13:09% 70-130 500108 SRA 3351054
Prep Method Prep Date Prep Initials Prep Factor
11/05/2009 17:30 FieldMA_VPH 0.94
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
11/20/2009 4:09:05 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110396 Page 23
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Documentation
11/20/2009 4:09:05 PM
09110396 Page 24
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220571
WorkOrder:09110396
Method:D2216
Analysis:PERCENT MOISTURE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Sample Result DUP Result RPD RPD Limit
Sample Duplicate
Original Sample: 09110585-03
Analysis Date: 11/13/2009 14:11 Analyst:JNY
RunID:WET_091113W-3339978 Units:wt%
Percent Moisture 18.619 0.43 20
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-01A SB-1 (28-30)
09110396-02A SB-2 (18-20')
09110396-03A SB-3 (30-34')
09110396-04A SB-4 (25-30')
09110396-05A SB-5 (33-35')
09110396-06A MW-5 (25-30')
09110396-07A MW-8 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:09 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 25
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221117
WorkOrder:09110396
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/19/2009 17:12 Analyst:SRA
RunID:HPCC_091119A-3349293 Units:mg/Kg
C9-C10 Aromatics 0.0800 0.0619 77.3 70 1300.0800 0.0680 85.0 9.4 20
Surr: 2,5-Dibromotoluene 200 160 80.0 70 13020020710325.5 30
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/19/2009 16:39 Analyst:SRA
RunID:HPCC_091119A-3349292 Units:mg/Kg
C9-C10 Aromatics 0.010ND
Surr: 2,5-Dibromotoluene 70-13088.5
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-01A SB-1 (28-30)
09110396-04A SB-4 (25-30')
09110396-06A MW-5 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:10 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 26
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221118
WorkOrder:09110396
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/19/2009 17:12 Analyst:SRA
RunID:HPCC_091119B-3349327 Units:mg/Kg
C5-C8 Aliphatics 0.300 0.271 90.2 70 1300.300 0.289 96.4 6.6 20
C9-C12 Aliphatics 0.280 0.224 79.8 70 1300.280 0.248 88.5 10.4 20
Surr: 2,5-Dibromotoluene 200 171 85.6 70 13020021010520.3 30
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/19/2009 16:39 Analyst:SRA
RunID:HPCC_091119B-3349326 Units:mg/Kg
C5-C8 Aliphatics 0.030ND
C9-C12 Aliphatics 0.035ND
Surr: 2,5-Dibromotoluene 70-13090.5
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-01A SB-1 (28-30)
09110396-04A SB-4 (25-30')
09110396-06A MW-5 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:10 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 27
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221202
WorkOrder:09110396
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/20/2009 11:30 Analyst:SRA
RunID:HPCC_091119C-3351052 Units:mg/Kg
C9-C10 Aromatics 0.0800 0.0621 77.6 70 1300.0800 0.0651 81.4 4.9 20
Surr: 2,5-Dibromotoluene 200 169 84.6 70 13020015175.3 11.6 30
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/20/2009 10:57 Analyst:SRA
RunID:HPCC_091119C-3351051 Units:mg/Kg
C9-C10 Aromatics 0.010ND
Surr: 2,5-Dibromotoluene 70-13085.7
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-02A SB-2 (18-20')
09110396-03A SB-3 (30-34')
09110396-05A SB-5 (33-35')
09110396-07A MW-8 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:10 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 28
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221203
WorkOrder:09110396
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/20/2009 11:30 Analyst:SRA
RunID:HPCC_091119D-3351061 Units:mg/Kg
C5-C8 Aliphatics 0.300 0.269 89.6 70 1300.300 0.279 93.1 3.8 20
C9-C12 Aliphatics 0.280 0.232 82.7 70 1300.280 0.243 86.9 5.0 20
Surr: 2,5-Dibromotoluene 200 172 86.2 70 13020016281.2 6.0 30
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/20/2009 10:57 Analyst:SRA
RunID:HPCC_091119D-3351060 Units:mg/Kg
C5-C8 Aliphatics 0.030ND
C9-C12 Aliphatics 0.035ND
Surr: 2,5-Dibromotoluene 70-13087.6
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-02A SB-2 (18-20')
09110396-03A SB-3 (30-34')
09110396-05A SB-5 (33-35')
09110396-07A MW-8 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:11 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 29
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220602
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/13/2009 15:56
Preparation Date: 11/13/2009 15:56
Analyst:TDD
RunID:XB_091113A-3340477 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.0050ND
1,1,2,2-Tetrachloroethane 0.0050ND
1,1,2-Trichloroethane 0.0050ND
1,1-Dichloroethane 0.0050ND
1,1-Dichloroethene 0.0050ND
1,2-Dichloroethane 0.0050ND
1,2-Dichloropropane 0.0050ND
2-Butanone 0.020ND
2-Hexanone 0.010ND
4-Methyl-2-pentanone 0.010ND
Acetone 0.10ND
Benzene 0.0050ND
Bromodichloromethane 0.0050ND
Bromoform 0.0050ND
Bromomethane 0.010ND
Carbon disulfide 0.0050ND
Carbon tetrachloride 0.0050ND
Chlorobenzene 0.0050ND
Chloroethane 0.010ND
Chloroform 0.0050ND
Chloromethane 0.0050ND
cis-1,3-Dichloropropene 0.0050ND
Dibromochloromethane 0.0050ND
Diisopropyl ether 0.0050ND
Ethylbenzene 0.0050ND
Methyl tert-butyl ether 0.0050ND
Methylene chloride 0.010ND
Styrene 0.0050ND
Tetrachloroethene 0.0050ND
Toluene 0.0050ND
trans-1,3-Dichloropropene 0.0050ND
Trichloroethene 0.0050ND
Trichlorofluoromethane 0.0050ND
Vinyl acetate 0.010ND
Vinyl chloride 0.010ND
cis-1,2-Dichloroethene 0.0050ND
m,p-Xylene 0.0050ND
o-Xylene 0.0050ND
trans-1,2-Dichloroethene 0.0050ND
1,2-Dichloroethene (total)0.0050ND
Xylenes,Total 0.0050ND
Surr: 1,2-Dichloroethane-d4 50-166117.2
Surr: 4-Bromofluorobenzene 79-123100.3
Surr: Toluene-d8 62-14699.1
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-01A SB-1 (28-30)
09110396-02A SB-2 (18-20')
09110396-04A SB-4 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:11 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 30
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220602
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/13/2009 14:22
Preparation Date: 11/13/2009 14:22
Analyst:TDD
Prep By:MethodSW5035
RunID:XB_091113A-3340475 Units:mg/Kg
1,1,1-Trichloroethane 0.0500 0.0519 104 72 1270.0500 0.0498 99.5 4.3 30
1,1,2,2-Tetrachloroethane 0.0500 0.0490 98.0 85 1200.0500 0.0488 97.6 0.3 30
1,1,2-Trichloroethane 0.0500 0.0511 102 86 1200.0500 0.0487 97.4 4.8 30
1,1-Dichloroethane 0.0500 0.0511 102 77 1250.0500 0.0501 100 2.0 30
1,1-Dichloroethene 0.0500 0.0525 105 77 1260.0500 0.0510 102 2.9 25
1,2-Dichloroethane 0.0500 0.0501 100 81 1210.0500 0.0492 98.4 1.8 30
1,2-Dichloropropane 0.0500 0.0505 101 77 1200.0500 0.0489 97.7 3.2 30
2-Butanone 0.125 0.127 101 71 1240.125 0.128 102 1.1 30
2-Hexanone 0.125 0.121 97.0 74 1290.125 0.119 95.5 1.5 30
4-Methyl-2-pentanone 0.125 0.125 99.7 76 1320.125 0.121 96.7 3.1 30
Acetone 0.125 0.129 103 64 1290.125 0.123 98.4 4.9 30
Benzene 0.0500 0.0551 110 77 1230.0500 0.0507 101 8.4 21
Bromodichloromethane 0.0500 0.0515 103 81 1240.0500 0.0512 102 0.5 30
Bromoform 0.0500 0.0498 99.7 77 1280.0500 0.0476 95.1 4.7 30
Bromomethane 0.0500 0.0591 118 42 1480.0500 0.0582 116 1.6 30
Carbon disulfide 0.0500 0.0521 104 69 1320.0500 0.0499 99.8 4.4 30
Carbon tetrachloride 0.0500 0.0507 101 67 1310.0500 0.0508 102 0.1 30
Chlorobenzene 0.0500 0.0498 99.5 82 1190.0500 0.0474 94.9 4.8 20
Chloroethane 0.0500 0.0563 113 54 1440.0500 0.0529 106 6.2 30
Chloroform 0.0500 0.0517 103 76 1220.0500 0.0506 101 2.2 30
Chloromethane 0.0500 0.0513 103 55 1290.0500 0.0488 97.6 5.0 30
cis-1,3-Dichloropropene 0.0500 0.0533 107 85 1210.0500 0.0512 102 4.0 30
Dibromochloromethane 0.0500 0.0531 106 80 1280.0500 0.0523 105 1.5 30
Diisopropyl ether 0.0500 0.0514 103 73 1290.0500 0.0504 101 2.0 30
Ethylbenzene 0.0500 0.0498 99.6 77 1210.0500 0.0464 92.9 7.0 30
Methyl tert-butyl ether 0.0500 0.0512 102 79 1280.0500 0.0517 103 1.0 30
Methylene chloride 0.0500 0.0565 113 59 1540.0500 0.0546 109 3.3 30
Styrene 0.0500 0.0517 103 74 1250.0500 0.0489 97.8 5.6 30
Tetrachloroethene 0.0500 0.0499 99.9 78 1270.0500 0.0462 92.4 7.8 30
Toluene 0.0500 0.0524 105 79 1200.0500 0.0489 97.9 6.7 20
trans-1,3-Dichloropropene 0.0500 0.0511 102 84 1260.0500 0.0500 100 2.1 30
Trichloroethene 0.0500 0.0521 104 79 1250.0500 0.0486 97.1 7.0 23
Trichlorofluoromethane 0.0500 0.0541 108 68 1310.0500 0.0534 107 1.3 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:11 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 31
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220602
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/13/2009 14:22
Preparation Date: 11/13/2009 14:22
Analyst:TDD
Prep By:MethodSW5035
RunID:XB_091113A-3340475 Units:mg/Kg
Vinyl acetate 0.0500 0.0579 116 60 1500.0500 0.0546 109 5.8 30
Vinyl chloride 0.0500 0.0528 106 61 1300.0500 0.0515 103 2.5 30
cis-1,2-Dichloroethene 0.0500 0.0519 104 77 1230.0500 0.0503 101 3.1 30
m,p-Xylene 0.100 0.102 102 78 1250.100 0.0931 93.1 8.8 30
o-Xylene 0.0500 0.0515 103 78 1210.0500 0.0483 96.6 6.5 30
trans-1,2-Dichloroethene 0.0500 0.0532 106 73 1270.0500 0.0499 99.8 6.3 30
1,2-Dichloroethene (total)0.1000 0.1051 105.1 76 1240.1000 0.1002 100.2 4.7 30
Xylenes,Total 0.1500 0.1535 102.1 61 1300.1500 0.1414 94.28 8.0 30
Surr: 1,2-Dichloroethane-d4 50.0 48.6 97.2 50 16650.0 48.6 97.1 0.1 30
Surr: 4-Bromofluorobenzene 50.0 49.4 98.9 79 12350.0 49.3 98.7 0.2 30
Surr: Toluene-d8 50.0 49.7 99.5 62 14650.0 49.5 99.0 0.5 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:11 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 32
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220622
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/14/2009 12:28 Analyst:RPJ
RunID:XA_091114A-3340886 Units:ug/L
1,1,1-Trichloroethane 5.0ND
1,1,2,2-Tetrachloroethane 5.0ND
1,1,2-Trichloroethane 5.0ND
1,1-Dichloroethane 5.0ND
1,1-Dichloroethene 5.0ND
1,2-Dichloroethane 5.0ND
1,2-Dichloropropane 5.0ND
2-Butanone 20ND
2-Hexanone 10ND
4-Methyl-2-pentanone 10ND
Acetone 100ND
Benzene 5.0ND
Bromodichloromethane 5.0ND
Bromoform 5.0ND
Bromomethane 10ND
Carbon disulfide 5.0ND
Carbon tetrachloride 5.0ND
Chlorobenzene 5.0ND
Chloroethane 10ND
Chloroform 5.0ND
Chloromethane 5.0ND
cis-1,3-Dichloropropene 5.0ND
Dibromochloromethane 5.0ND
Diisopropyl ether 5.0ND
Ethylbenzene 5.0ND
Methyl tert-butyl ether 5.0ND
Methylene chloride 10ND
Styrene 5.0ND
Tetrachloroethene 5.0ND
Toluene 5.0ND
trans-1,3-Dichloropropene 5.0ND
Trichloroethene 5.0ND
Trichlorofluoromethane 5.0ND
Vinyl acetate 10ND
Vinyl chloride 10ND
cis-1,2-Dichloroethene 5.0ND
m,p-Xylene 5.0ND
o-Xylene 5.0ND
trans-1,2-Dichloroethene 5.0ND
1,2-Dichloroethene (total)5.0ND
Xylenes,Total 5.0ND
Surr: 1,2-Dichloroethane-d4 75-12091.4
Surr: 4-Bromofluorobenzene 89-10995.2
Surr: Toluene-d8 89-11096.4
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-03A SB-3 (30-34')
09110396-05A SB-5 (33-35')
Methanolic Preparation Blank
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:12 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 33
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220622
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Analyte Result Rep Limit
Analysis Date: 11/14/2009 12:58
Preparation Date: 11/14/2009 12:58
Analyst:RPJ
RunID:XA_091114A-3340887 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.25ND
1,1,2,2-Tetrachloroethane 0.25ND
1,1,2-Trichloroethane 0.25ND
1,1-Dichloroethane 0.25ND
1,1-Dichloroethene 0.25ND
1,2-Dichloroethane 0.25ND
1,2-Dichloropropane 0.25ND
2-Butanone 1ND
2-Hexanone 0.5ND
4-Methyl-2-pentanone 0.5ND
Acetone 5ND
Benzene 0.25ND
Bromodichloromethane 0.25ND
Bromoform 0.25ND
Bromomethane 0.5ND
Carbon disulfide 0.25ND
Carbon tetrachloride 0.25ND
Chlorobenzene 0.25ND
Chloroethane 0.5ND
Chloroform 0.25ND
Chloromethane 0.25ND
cis-1,3-Dichloropropene 0.25ND
Dibromochloromethane 0.25ND
Diisopropyl ether 0.25ND
Ethylbenzene 0.25ND
Methyl tert-butyl ether 0.25ND
Methylene chloride 0.5ND
Styrene 0.25ND
Tetrachloroethene 0.25ND
Toluene 0.25ND
trans-1,3-Dichloropropene 0.25ND
Trichloroethene 0.25ND
Trichlorofluoromethane 0.25ND
Vinyl acetate 0.5ND
Vinyl chloride 0.5ND
cis-1,2-Dichloroethene 0.25ND
m,p-Xylene 0.25ND
o-Xylene 0.25ND
trans-1,2-Dichloroethene 0.25ND
1,2-Dichloroethene (total)0.25ND
Xylenes,Total 0.25ND
Surr: 1,2-Dichloroethane-d4 62-134104.1
Surr: 4-Bromofluorobenzene 75-12895.9
Surr: Toluene-d8 78-120101.1
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:12 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 34
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220622
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper LimitLCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/14/2009 10:55 Analyst:RPJ
RunID:XA_091114A-3340884 Units:ug/L
1,1,1-Trichloroethane 50.0 49.8 99.6 79 12750.0 51.4 103 3.2 26
1,1,2,2-Tetrachloroethane 50.0 48.9 97.8 73 12850.0 48.5 97.0 0.8 26
1,1,2-Trichloroethane 50.0 50.4 101 84 12150.0 49.9 99.8 1.0 20
1,1-Dichloroethane 50.0 46.1 92.3 79 12550.0 47.8 95.6 3.6 23
1,1-Dichloroethene 50.0 46.5 93.0 84 12350.0 46.6 93.3 0.3 23
1,2-Dichloroethane 50.0 48.0 96.0 80 12450.0 48.1 96.1 0.1 21
1,2-Dichloropropane 50.0 46.4 92.8 82 12150.0 47.1 94.2 1.6 27
2-Butanone 125 113 90.0 45 14412511994.9 5.3 50
2-Hexanone 125 128 102 53 1411251291030.8 55
4-Methyl-2-pentanone 125 109 87.2 63 13412511088.1 1.0 30
Acetone 125 122 97.7 11 1921251271024.0 58
Benzene 50.0 50.0 100 88 11750.0 51.0 102 2.0 23
Bromodichloromethane 50.0 50.6 101 82 12550.0 49.1 98.1 3.0 21
Bromoform 50.0 47.3 94.6 60 12650.0 47.6 95.2 0.6 27
Bromomethane 50.0 54.8 110 56 15350.0 48.7 97.5 11.8 28
Carbon disulfide 50.0 49.2 98.4 70 13050.0 49.3 98.5 0.2 23
Carbon tetrachloride 50.0 47.9 95.8 77 12350.0 48.7 97.5 1.8 35
Chlorobenzene 50.0 50.9 102 87 11950.0 51.5 103 1.1 19
Chloroethane 50.0 62.0 124 69 13450.0 63.9 128 2.9 26
Chloroform 50.0 47.2 94.4 79 12350.0 47.4 94.9 0.5 42
Chloromethane 50.0 43.2 86.4 62 13750.0 44.2 88.5 2.4 28
cis-1,3-Dichloropropene 50.0 49.7 99.5 79 12650.0 50.5 101 1.5 20
Dibromochloromethane 50.0 52.8 106 74 12250.0 52.7 105 0.1 20
Diisopropyl ether 50.0 48.4 96.8 79 13350.0 48.4 96.9 0.1 21
Ethylbenzene 50.0 53.1 106 90 11450.0 52.7 105 0.8 16
Methyl tert-butyl ether 50.0 47.1 94.2 80 12450.0 47.0 94.0 0.1 23
Methylene chloride 50.0 46.0 92.0 77 12450.0 45.9 91.8 0.2 22
Styrene 50.0 51.0 102 87 11950.0 52.9 106 3.7 19
Tetrachloroethene 50.0 54.2 108 81 12550.0 52.8 106 2.6 20
Toluene 50.0 52.3 105 84 11850.0 52.8 106 0.8 21
trans-1,3-Dichloropropene 50.0 52.5 105 79 12850.0 52.7 105 0.5 20
Trichloroethene 50.0 49.5 99.1 84 12450.0 52.1 104 5.0 20
Trichlorofluoromethane 50.0 52.5 105 78 13250.0 54.8 110 4.3 25
Vinyl acetate 50.0 49.5 99.0 62 14250.0 49.1 98.3 0.7 59
Vinyl chloride 50.0 43.9 87.7 71 13050.0 45.5 91.0 3.7 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:12 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 35
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220622
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/14/2009 10:55 Analyst:RPJ
RunID:XA_091114A-3340884 Units:ug/L
cis-1,2-Dichloroethene 50.0 46.3 92.6 81 12350.0 46.5 92.9 0.4 28
m,p-Xylene 100 102 102 86 1141001041041.7 20
o-Xylene 50.0 51.2 102 87 11750.0 50.7 101 1.0 17
trans-1,2-Dichloroethene 50.0 46.7 93.5 80 12350.0 47.0 93.9 0.5 22
1,2-Dichloroethene (total)100 93 93 82 12210094930.4 28
Xylenes,Total 150.0 153.2 102.3 86 117150.0 154.7 103.1 0.8 20
Surr: 1,2-Dichloroethane-d4 50.0 46.8 93.6 75 12050.0 49.1 98.2 4.8 30
Surr: 4-Bromofluorobenzene 50.0 49.5 98.9 89 10950.0 50.1 100 1.2 30
Surr: Toluene-d8 50.0 47.3 94.7 89 11050.0 48.0 96.1 1.5 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:12 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 36
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220812
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/16/2009 11:27
Preparation Date: 11/16/2009 11:27
Analyst:TDD
RunID:XB_091116A-3344209 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.0050ND
1,1,2,2-Tetrachloroethane 0.0050ND
1,1,2-Trichloroethane 0.0050ND
1,1-Dichloroethane 0.0050ND
1,1-Dichloroethene 0.0050ND
1,2-Dichloroethane 0.0050ND
1,2-Dichloropropane 0.0050ND
2-Butanone 0.020ND
2-Hexanone 0.010ND
4-Methyl-2-pentanone 0.010ND
Acetone 0.10ND
Benzene 0.0050ND
Bromodichloromethane 0.0050ND
Bromoform 0.0050ND
Bromomethane 0.010ND
Carbon disulfide 0.0050ND
Carbon tetrachloride 0.0050ND
Chlorobenzene 0.0050ND
Chloroethane 0.010ND
Chloroform 0.0050ND
Chloromethane 0.0050ND
cis-1,3-Dichloropropene 0.0050ND
Dibromochloromethane 0.0050ND
Diisopropyl ether 0.0050ND
Ethylbenzene 0.0050ND
Methyl tert-butyl ether 0.0050ND
Methylene chloride 0.010ND
Styrene 0.0050ND
Tetrachloroethene 0.0050ND
Toluene 0.0050ND
trans-1,3-Dichloropropene 0.0050ND
Trichloroethene 0.0050ND
Trichlorofluoromethane 0.0050ND
Vinyl acetate 0.010ND
Vinyl chloride 0.010ND
cis-1,2-Dichloroethene 0.0050ND
m,p-Xylene 0.0050ND
o-Xylene 0.0050ND
trans-1,2-Dichloroethene 0.0050ND
1,2-Dichloroethene (total)0.0050ND
Xylenes,Total 0.0050ND
Surr: 1,2-Dichloroethane-d4 50-166113.7
Surr: 4-Bromofluorobenzene 79-123103.9
Surr: Toluene-d8 62-14698.0
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-06A MW-5 (25-30')
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:13 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 37
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220812
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/16/2009 9:54
Preparation Date: 11/16/2009 9:54
Analyst:TDD
Prep By:MethodSW5035
RunID:XB_091116A-3344207 Units:mg/Kg
1,1,1-Trichloroethane 0.0500 0.0538 108 72 1270.0500 0.0530 106 1.3 30
1,1,2,2-Tetrachloroethane 0.0500 0.0444 88.8 85 1200.0500 0.0436 87.1 1.9 30
1,1,2-Trichloroethane 0.0500 0.0457 91.5 86 1200.0500 0.0450 90.1 1.5 30
1,1-Dichloroethane 0.0500 0.0485 96.9 77 1250.0500 0.0488 97.7 0.8 30
1,1-Dichloroethene 0.0500 0.0524 105 77 1260.0500 0.0527 105 0.7 25
1,2-Dichloroethane 0.0500 0.0474 94.8 81 1210.0500 0.0475 95.0 0.3 30
1,2-Dichloropropane 0.0500 0.0462 92.4 77 1200.0500 0.0469 93.9 1.6 30
2-Butanone 0.125 0.121 96.6 71 1240.125 0.117 93.4 3.4 30
2-Hexanone 0.125 0.104 83.1 74 1290.125 0.106 84.6 1.7 30
4-Methyl-2-pentanone 0.125 0.115 92.2 76 1320.125 0.114 91.5 0.7 30
Acetone 0.125 0.114 91.5 64 1290.125 0.114 91.3 0.2 30
Benzene 0.0500 0.0507 101 77 1230.0500 0.0507 101 0.0 21
Bromodichloromethane 0.0500 0.0509 102 81 1240.0500 0.0512 102 0.7 30
Bromoform 0.0500 0.0470 94.0 77 1280.0500 0.0456 91.3 2.9 30
Bromomethane 0.0500 0.0399 79.8 42 1480.0500 0.0427 85.5 6.9 30
Carbon disulfide 0.0500 0.0525 105 69 1320.0500 0.0523 105 0.2 30
Carbon tetrachloride 0.0500 0.0562 112 67 1310.0500 0.0544 109 3.2 30
Chlorobenzene 0.0500 0.0463 92.6 82 1190.0500 0.0453 90.6 2.1 20
Chloroethane 0.0500 0.0529 106 54 1440.0500 0.0496 99.3 6.4 30
Chloroform 0.0500 0.0515 103 76 1220.0500 0.0506 101 1.7 30
Chloromethane 0.0500 0.0410 82.1 55 1290.0500 0.0399 79.7 2.9 30
cis-1,3-Dichloropropene 0.0500 0.0497 99.3 85 1210.0500 0.0502 100 1.1 30
Dibromochloromethane 0.0500 0.0499 99.8 80 1280.0500 0.0490 97.9 1.9 30
Diisopropyl ether 0.0500 0.0488 97.6 73 1290.0500 0.0489 97.7 0.1 30
Ethylbenzene 0.0500 0.0456 91.1 77 1210.0500 0.0442 88.4 3.1 30
Methyl tert-butyl ether 0.0500 0.0497 99.5 79 1280.0500 0.0490 98.1 1.4 30
Methylene chloride 0.0500 0.0544 109 59 1540.0500 0.0525 105 3.5 30
Styrene 0.0500 0.0471 94.1 74 1250.0500 0.0466 93.3 0.9 30
Tetrachloroethene 0.0500 0.0487 97.5 78 1270.0500 0.0464 92.8 4.9 30
Toluene 0.0500 0.0480 96.0 79 1200.0500 0.0465 92.9 3.3 20
trans-1,3-Dichloropropene 0.0500 0.0470 94.1 84 1260.0500 0.0453 90.7 3.7 30
Trichloroethene 0.0500 0.0509 102 79 1250.0500 0.0506 101 0.6 23
Trichlorofluoromethane 0.0500 0.0574 115 68 1310.0500 0.0555 111 3.3 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:13 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 38
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220812
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/16/2009 9:54
Preparation Date: 11/16/2009 9:54
Analyst:TDD
Prep By:MethodSW5035
RunID:XB_091116A-3344207 Units:mg/Kg
Vinyl acetate 0.0500 0.0580 116 60 1500.0500 0.0531 106 8.8 30
Vinyl chloride 0.0500 0.0500 100 61 1300.0500 0.0482 96.3 3.8 30
cis-1,2-Dichloroethene 0.0500 0.0507 101 77 1230.0500 0.0505 101 0.3 30
m,p-Xylene 0.100 0.0919 91.9 78 1250.100 0.0902 90.2 1.8 30
o-Xylene 0.0500 0.0465 92.9 78 1210.0500 0.0454 90.9 2.2 30
trans-1,2-Dichloroethene 0.0500 0.0515 103 73 1270.0500 0.0497 99.5 3.4 30
1,2-Dichloroethene (total)0.1000 0.1022 102.1 76 1240.1000 0.1002 100.2 1.9 30
Xylenes,Total 0.1500 0.1384 92.22 61 1300.1500 0.1356 90.44 2.0 30
Surr: 1,2-Dichloroethane-d4 50.0 47.2 94.3 50 16650.0 47.2 94.4 0.1 30
Surr: 4-Bromofluorobenzene 50.0 50.0 99.9 79 12350.0 50.1 100 0.2 30
Surr: Toluene-d8 50.0 49.6 99.2 62 14650.0 50.0 100 0.8 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:13 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 39
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220823
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date: 11/16/2009 11:11 Analyst:TDD
RunID:XA_091116C-3344304 Units:ug/L
1,1,1-Trichloroethane 5.0ND
1,1,2,2-Tetrachloroethane 5.0ND
1,1,2-Trichloroethane 5.0ND
1,1-Dichloroethane 5.0ND
1,1-Dichloroethene 5.0ND
1,2-Dichloroethane 5.0ND
1,2-Dichloropropane 5.0ND
2-Butanone 20ND
2-Hexanone 10ND
4-Methyl-2-pentanone 10ND
Acetone 100ND
Benzene 5.0ND
Bromodichloromethane 5.0ND
Bromoform 5.0ND
Bromomethane 10ND
Carbon disulfide 5.0ND
Carbon tetrachloride 5.0ND
Chlorobenzene 5.0ND
Chloroethane 10ND
Chloroform 5.0ND
Chloromethane 5.0ND
cis-1,3-Dichloropropene 5.0ND
Dibromochloromethane 5.0ND
Diisopropyl ether 5.0ND
Ethylbenzene 5.0ND
Methyl tert-butyl ether 5.0ND
Methylene chloride 10ND
Styrene 5.0ND
Tetrachloroethene 5.0ND
Toluene 5.0ND
trans-1,3-Dichloropropene 5.0ND
Trichloroethene 5.0ND
Trichlorofluoromethane 5.0ND
Vinyl acetate 10ND
Vinyl chloride 10ND
cis-1,2-Dichloroethene 5.0ND
m,p-Xylene 5.0ND
o-Xylene 5.0ND
trans-1,2-Dichloroethene 5.0ND
1,2-Dichloroethene (total)5.0ND
Xylenes,Total 5.0ND
Surr: 1,2-Dichloroethane-d4 75-12092.1
Surr: 4-Bromofluorobenzene 89-10997.1
Surr: Toluene-d8 89-11094.7
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110396-07A MW-8 (25-30')
Methanolic Preparation Blank
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:13 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 40
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220823
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
Analyte Result Rep Limit
Analysis Date: 11/16/2009 11:42
Preparation Date: 11/16/2009 11:42
Analyst:TDD
RunID:XA_091116C-3344305 Units:mg/Kg
Prep By:MethodSW5035
1,1,1-Trichloroethane 0.25ND
1,1,2,2-Tetrachloroethane 0.25ND
1,1,2-Trichloroethane 0.25ND
1,1-Dichloroethane 0.25ND
1,1-Dichloroethene 0.25ND
1,2-Dichloroethane 0.25ND
1,2-Dichloropropane 0.25ND
2-Butanone 1ND
2-Hexanone 0.5ND
4-Methyl-2-pentanone 0.5ND
Acetone 5ND
Benzene 0.25ND
Bromodichloromethane 0.25ND
Bromoform 0.25ND
Bromomethane 0.5ND
Carbon disulfide 0.25ND
Carbon tetrachloride 0.25ND
Chlorobenzene 0.25ND
Chloroethane 0.5ND
Chloroform 0.25ND
Chloromethane 0.25ND
cis-1,3-Dichloropropene 0.25ND
Dibromochloromethane 0.25ND
Diisopropyl ether 0.25ND
Ethylbenzene 0.25ND
Methyl tert-butyl ether 0.25ND
Methylene chloride 0.5ND
Styrene 0.25ND
Tetrachloroethene 0.25ND
Toluene 0.25ND
trans-1,3-Dichloropropene 0.25ND
Trichloroethene 0.25ND
Trichlorofluoromethane 0.25ND
Vinyl acetate 0.5ND
Vinyl chloride 0.5ND
cis-1,2-Dichloroethene 0.25ND
m,p-Xylene 0.25ND
o-Xylene 0.25ND
trans-1,2-Dichloroethene 0.25ND
1,2-Dichloroethene (total)0.25ND
Xylenes,Total 0.25ND
Surr: 1,2-Dichloroethane-d4 62-134101.5
Surr: 4-Bromofluorobenzene 75-12898.6
Surr: Toluene-d8 78-120100.9
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:14 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 41
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220823
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper LimitLCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/16/2009 9:36 Analyst:TDD
RunID:XA_091116C-3344302 Units:ug/L
1,1,1-Trichloroethane 50.0 49.4 98.8 79 12750.0 49.9 99.8 1.0 26
1,1,2,2-Tetrachloroethane 50.0 49.2 98.5 73 12850.0 48.3 96.7 1.8 26
1,1,2-Trichloroethane 50.0 50.2 100 84 12150.0 49.2 98.4 2.0 20
1,1-Dichloroethane 50.0 45.5 91.1 79 12550.0 45.5 90.9 0.2 23
1,1-Dichloroethene 50.0 46.5 93.0 84 12350.0 47.5 95.0 2.1 23
1,2-Dichloroethane 50.0 45.9 91.9 80 12450.0 46.2 92.3 0.5 21
1,2-Dichloropropane 50.0 44.9 89.7 82 12150.0 45.3 90.5 0.9 27
2-Butanone 125 115 91.8 45 14412511894.3 2.6 50
2-Hexanone 125 127 102 53 1411251291031.3 55
4-Methyl-2-pentanone 125 110 88.2 63 13412511188.9 0.8 30
Acetone 125 131 104 11 1921251311040.0 58
Benzene 50.0 47.2 94.5 88 11750.0 46.1 92.3 2.4 23
Bromodichloromethane 50.0 49.7 99.5 82 12550.0 49.2 98.5 1.0 21
Bromoform 50.0 49.6 99.2 60 12650.0 48.6 97.1 2.1 27
Bromomethane 50.0 56.6 113 56 15350.0 54.0 108 4.7 28
Carbon disulfide 50.0 47.9 95.8 70 13050.0 48.0 95.9 0.1 23
Carbon tetrachloride 50.0 48.6 97.2 77 12350.0 48.0 96.0 1.3 35
Chlorobenzene 50.0 52.1 104 87 11950.0 51.5 103 1.2 19
Chloroethane 50.0 59.2 118 69 13450.0 58.4 117 1.3 26
Chloroform 50.0 47.1 94.2 79 12350.0 46.6 93.2 1.0 42
Chloromethane 50.0 44.4 88.8 62 13750.0 44.9 89.7 1.0 28
cis-1,3-Dichloropropene 50.0 48.3 96.7 79 12650.0 48.6 97.2 0.5 20
Dibromochloromethane 50.0 54.5 109 74 12250.0 53.9 108 1.2 20
Diisopropyl ether 50.0 46.6 93.3 79 13350.0 46.8 93.5 0.3 21
Ethylbenzene 50.0 52.9 106 90 11450.0 51.4 103 2.9 16
Methyl tert-butyl ether 50.0 46.7 93.4 80 12450.0 47.5 95.1 1.8 23
Methylene chloride 50.0 44.6 89.2 77 12450.0 43.6 87.1 2.3 22
Styrene 50.0 51.4 103 87 11950.0 51.4 103 0.0 19
Tetrachloroethene 50.0 52.6 105 81 12550.0 51.4 103 2.3 20
Toluene 50.0 50.7 101 84 11850.0 49.7 99.4 2.0 21
trans-1,3-Dichloropropene 50.0 51.3 103 79 12850.0 51.0 102 0.5 20
Trichloroethene 50.0 50.3 101 84 12450.0 49.4 98.7 1.9 20
Trichlorofluoromethane 50.0 53.2 106 78 13250.0 51.6 103 3.2 25
Vinyl acetate 50.0 48.9 97.8 62 14250.0 49.1 98.3 0.5 59
Vinyl chloride 50.0 44.2 88.4 71 13050.0 41.8 83.6 5.6 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:14 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 42
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R220823
WorkOrder:09110396
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 11/16/2009 9:36 Analyst:TDD
RunID:XA_091116C-3344302 Units:ug/L
cis-1,2-Dichloroethene 50.0 45.4 90.8 81 12350.0 45.2 90.3 0.5 28
m,p-Xylene 100 103 103 86 11410099.8 99.8 2.9 20
o-Xylene 50.0 51.0 102 87 11750.0 50.1 100 1.9 17
trans-1,2-Dichloroethene 50.0 45.4 90.7 80 12350.0 47.5 94.9 4.6 22
1,2-Dichloroethene (total)100 90.8 90.7 82 12210092.7 92.6 2.1 28
Xylenes,Total 150 154 102 86 11715015099.9 2.5 20
Surr: 1,2-Dichloroethane-d4 50.0 45.2 90.3 75 12050.0 48.0 96.1 6.2 30
Surr: 4-Bromofluorobenzene 50.0 50.1 100 89 10950.0 48.1 96.2 4.1 30
Surr: Toluene-d8 50.0 48.2 96.4 89 11050.0 47.3 94.7 1.8 30
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
11/20/2009 4:09:14 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110396 Page 43
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Chain of Custody
And
Sample Receipt Checklist
11/20/2009 4:09:14 PM
09110396 Page 44
Sample Receipt Checklist
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:09110396
Date and Time Received:11/10/2009 9:30:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:4.5°C
Received By:COM
SPL Representative:
Non Conformance
Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
11/20/2009 4:09:15 PM
09110396 Page 45
Case Narrative for:
09110761
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
DIANA LANIER
Date Reported:12/1/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to
other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD
to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a
result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of
Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateAmy K. Jackson
12/1/2009
Project Manager
09110761 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
09110761
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
3417-A TRADE PARK CT.
CHARLOTTE
NC
28217-
[phone]
DIANA LANIER
Date Reported:12/1/2009
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
09110761-01 11/18/2009 9:30:00 AMMW-1 11/17/2009 1:30:00 PMWater 296675
09110761-02 11/18/2009 9:30:00 AMMW-2 11/17/2009 2:15:00 PMWater 296675
09110761-03 11/18/2009 9:30:00 AMMW-3 11/17/2009 10:30:00 AMWater 296675
09110761-04 11/18/2009 9:30:00 AMMW-4 11/17/2009 10:45:00 AMWater 296675
09110761-05 11/18/2009 9:30:00 AMMW-5 11/17/2009 1:00:00 PMWater 296675
09110761-06 11/18/2009 9:30:00 AMMW-6 11/17/2009 11:00:00 AMWater 296675
09110761-07 11/18/2009 9:30:00 AMMW-7 11/17/2009 12:20:00 PMWater 296675
09110761-08 11/18/2009 9:30:00 AMMW-8 11/17/2009 2:30:00 PMWater 296675
09110761-09 11/18/2009 9:30:00 AMDMW-1 11/17/2009 11:30:00 AMWater 296675
09110761-10 11/18/2009 9:30:00 AMPW-15 (CORRELL)11/17/2009 3:25:00 PMWater 296675
09110761-11 11/18/2009 9:30:00 AMPW-16 (CEN HOUR)11/17/2009 3:40:00 PMWater 296675
Date
Laboratory Director
Quality Assurance Officer
Amy K. Jackson
09110761 Page 2
12/1/2009
12/1/2009 2:20:29 PM
Project Manager
Ron Benjamin
Tristan Davis
Client Sample ID:MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 21:170.022 1ND DF 3355566
Surr: 1-Chloro-2-fluorobenzene 11/23/09 21:17% 33-151 1138 DF 3355566
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.12
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 19:570.01 10.149 SVW 3350881
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:51 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 3
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/28/09 11:550.2 1ND RPJ 3358208
1,1,1-Trichloroethane 11/28/09 11:550.1 1ND RPJ 3358208
1,1,2,2-Tetrachloroethane 11/28/09 11:550.1 1ND RPJ 3358208
1,1,2-Trichloroethane 11/28/09 11:550.1 1ND RPJ 3358208
1,1-Dichloroethane 11/28/09 11:550.1 1ND RPJ 3358208
1,1-Dichloroethene 11/28/09 11:550.1 1ND RPJ 3358208
1,1-Dichloropropene 11/28/09 11:550.1 1ND RPJ 3358208
1,2,3-Trichlorobenzene 11/28/09 11:550.2 1ND RPJ 3358208
1,2,3-Trichloropropane 11/28/09 11:550.1 1ND RPJ 3358208
1,2,4-Trichlorobenzene 11/28/09 11:550.2 1ND RPJ 3358208
1,2,4-Trimethylbenzene 11/28/09 11:550.1 12.9 RPJ 3358208
1,2-Dibromo-3-chloropropane 11/28/09 11:550.5 1ND RPJ 3358208
1,2-Dibromoethane 11/28/09 11:550.1 1ND RPJ 3358208
1,2-Dichlorobenzene 11/28/09 11:550.1 1ND RPJ 3358208
1,2-Dichloroethane 11/28/09 11:550.2 1ND RPJ 3358208
1,2-Dichloropropane 11/28/09 11:550.1 1ND RPJ 3358208
1,3,5-Trimethylbenzene 11/28/09 11:550.1 12.1 RPJ 3358208
1,3-Dichlorobenzene 11/28/09 11:550.2 1ND RPJ 3358208
1,3-Dichloropropane 11/28/09 11:550.1 1ND RPJ 3358208
1,4-Dichlorobenzene 11/28/09 11:550.2 1ND RPJ 3358208
2,2-Dichloropropane 11/28/09 11:550.1 1ND RPJ 3358208
2-Chlorotoluene 11/28/09 11:550.2 1ND RPJ 3358208
4-Chlorotoluene 11/28/09 11:550.2 1ND RPJ 3358208
Benzene 11/28/09 11:550.1 117 RPJ 3358208
Bromobenzene 11/28/09 11:550.1 1ND RPJ 3358208
Bromochloromethane 11/28/09 11:550.1 1ND RPJ 3358208
Bromodichloromethane 11/28/09 11:550.1 1ND RPJ 3358208
Bromoform 11/28/09 11:550.1 1ND RPJ 3358208
Bromomethane 11/28/09 11:550.1 1ND RPJ 3358208
Carbon tetrachloride 11/28/09 11:550.1 1ND RPJ 3358208
Chlorobenzene 11/28/09 11:550.2 1ND RPJ 3358208
Chloroethane 11/28/09 11:550.2 1ND RPJ 3358208
Chloroform 11/28/09 11:550.1 113 RPJ 3358208
Chloromethane 11/28/09 11:550.1 1ND RPJ 3358208
cis-1,2-Dichloroethene 11/28/09 11:550.1 1ND RPJ 3358208
Dibromochloromethane 11/28/09 11:550.1 1ND RPJ 3358208
Dibromomethane 11/28/09 11:550.1 1ND RPJ 3358208
Dichlorodifluoromethane 11/28/09 11:550.1 1ND RPJ 3358208
Ethylbenzene 11/28/09 11:550.2 10.75 RPJ 3358208
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:51 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 4
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/28/09 11:550.2 1ND RPJ 3358208
Isopropyl ether 11/28/09 11:550.1 1ND RPJ 3358208
Isopropylbenzene 11/28/09 11:550.2 10.46 RPJ 3358208
m & p-Xylene 11/28/09 11:550.1 17.1 RPJ 3358208
Methyl tert-butyl ether 11/28/09 11:550.2 118 RPJ 3358208
Methylene chloride 11/28/09 11:550.2 1ND RPJ 3358208
Naphthalene 11/28/09 11:550.1 1ND RPJ 3358208
n-Butylbenzene 11/28/09 11:550.1 10.69 RPJ 3358208
n-Propylbenzene 11/28/09 11:550.1 10.83 RPJ 3358208
o-Xylene 11/28/09 11:550.1 12.4 RPJ 3358208
p-Isopropyltoluene 11/28/09 11:550.1 10.53 RPJ 3358208
sec-Butylbenzene 11/28/09 11:550.1 1ND RPJ 3358208
Styrene 11/28/09 11:550.1 1ND RPJ 3358208
tert-Butylbenzene 11/28/09 11:550.1 1ND RPJ 3358208
Tetrachloroethene 11/28/09 11:550.2 1ND RPJ 3358208
Toluene 11/28/09 11:550.1 15.1 RPJ 3358208
trans-1,2-Dichloroethene 11/28/09 11:550.1 1ND RPJ 3358208
Trichloroethene 11/28/09 11:550.1 1ND RPJ 3358208
Trichlorofluoromethane 11/28/09 11:550.1 1ND RPJ 3358208
Vinyl chloride 11/28/09 11:550.1 1ND RPJ 3358208
Surr: 1,2-Dichloroethane-d4 11/28/09 11:55% 60-140 189.8 RPJ 3358208
Surr: 4-Bromofluorobenzene 11/28/09 11:55% 60-140 197.7 RPJ 3358208
Surr: Toluene-d8 11/28/09 11:55% 60-140 199.8 RPJ 3358208
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 9:583011300 SRA 3358886
C9-C10 Aromatics 11/26/09 9:5810135 SRA 3358866
C9-C12 Aliphatics 11/26/09 9:5835161 SRA 3358886
Surr: 2,5-Dibromotoluene 11/26/09 9:58% 70-130 191.0 SRA 3358886
Surr: 2,5-Dibromotoluene 11/26/09 9:58% 70-130 188.8 SRA 3358866
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:52 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 5
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:15
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 21:370.023 1ND DF 3355567
Surr: 1-Chloro-2-fluorobenzene 11/23/09 21:37% 33-151 1110 DF 3355567
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.13
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 20:450.01 10.0224 SVW 3350890
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:53 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 6
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:15
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/28/09 15:490.2 1ND RPJ 3358214
1,1,1-Trichloroethane 11/28/09 15:490.1 1ND RPJ 3358214
1,1,2,2-Tetrachloroethane 11/28/09 15:490.1 1ND RPJ 3358214
1,1,2-Trichloroethane 11/28/09 15:490.1 1ND RPJ 3358214
1,1-Dichloroethane 11/28/09 15:490.1 1ND RPJ 3358214
1,1-Dichloroethene 11/28/09 15:490.1 1ND RPJ 3358214
1,1-Dichloropropene 11/28/09 15:490.1 1ND RPJ 3358214
1,2,3-Trichlorobenzene 11/28/09 15:490.2 1ND RPJ 3358214
1,2,3-Trichloropropane 11/28/09 15:490.1 1ND RPJ 3358214
1,2,4-Trichlorobenzene 11/28/09 15:490.2 1ND RPJ 3358214
1,2,4-Trimethylbenzene 11/28/09 15:490.1 1110 RPJ 3358214
1,2-Dibromo-3-chloropropane 11/28/09 15:490.5 1ND RPJ 3358214
1,2-Dibromoethane 11/28/09 15:490.1 1ND RPJ 3358214
1,2-Dichlorobenzene 11/28/09 15:490.1 1ND RPJ 3358214
1,2-Dichloroethane 11/28/09 15:490.2 10.74 RPJ 3358214
1,2-Dichloropropane 11/28/09 15:490.1 1ND RPJ 3358214
1,3,5-Trimethylbenzene 11/28/09 15:490.1 138 RPJ 3358214
1,3-Dichlorobenzene 11/28/09 15:490.2 1ND RPJ 3358214
1,3-Dichloropropane 11/28/09 15:490.1 1ND RPJ 3358214
1,4-Dichlorobenzene 11/28/09 15:490.2 1ND RPJ 3358214
2,2-Dichloropropane 11/28/09 15:490.1 1ND RPJ 3358214
2-Chlorotoluene 11/28/09 15:490.2 1ND RPJ 3358214
4-Chlorotoluene 11/28/09 15:490.2 1ND RPJ 3358214
Benzene 11/28/09 14:310.5 5630 RPJ 3358212
Bromobenzene 11/28/09 15:490.1 1ND RPJ 3358214
Bromochloromethane 11/28/09 15:490.1 1ND RPJ 3358214
Bromodichloromethane 11/28/09 15:490.1 1ND RPJ 3358214
Bromoform 11/28/09 15:490.1 1ND RPJ 3358214
Bromomethane 11/28/09 15:490.1 1ND RPJ 3358214
Carbon tetrachloride 11/28/09 15:490.1 1ND RPJ 3358214
Chlorobenzene 11/28/09 15:490.2 1ND RPJ 3358214
Chloroethane 11/28/09 15:490.2 1ND RPJ 3358214
Chloroform 11/28/09 15:490.1 116 RPJ 3358214
Chloromethane 11/28/09 15:490.1 1ND RPJ 3358214
cis-1,2-Dichloroethene 11/28/09 15:490.1 1ND RPJ 3358214
Dibromochloromethane 11/28/09 15:490.1 1ND RPJ 3358214
Dibromomethane 11/28/09 15:490.1 1ND RPJ 3358214
Dichlorodifluoromethane 11/28/09 15:490.1 1ND RPJ 3358214
Ethylbenzene 11/28/09 15:490.2 116 RPJ 3358214
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:54 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 7
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:15
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/28/09 15:490.2 1ND RPJ 3358214
Isopropyl ether 11/28/09 15:490.1 111 RPJ 3358214
Isopropylbenzene 11/28/09 15:490.2 13.9 RPJ 3358214
m & p-Xylene 11/28/09 15:490.1 1200 RPJ 3358214
Methyl tert-butyl ether 11/28/09 14:3115340 RPJ 3358212
Methylene chloride 11/28/09 15:490.2 1ND RPJ 3358214
Naphthalene 11/28/09 15:490.1 13.8 RPJ 3358214
n-Butylbenzene 11/28/09 15:490.1 1ND RPJ 3358214
n-Propylbenzene 11/28/09 15:490.1 16.3 RPJ 3358214
o-Xylene 11/28/09 15:490.1 1120 RPJ 3358214
p-Isopropyltoluene 11/28/09 15:490.1 13.2 RPJ 3358214
sec-Butylbenzene 11/28/09 15:490.1 1ND RPJ 3358214
Styrene 11/28/09 15:490.1 1ND RPJ 3358214
tert-Butylbenzene 11/28/09 15:490.1 1ND RPJ 3358214
Tetrachloroethene 11/28/09 15:490.2 1ND RPJ 3358214
Toluene 11/28/09 15:490.1 1170 RPJ 3358214
trans-1,2-Dichloroethene 11/28/09 15:490.1 1ND RPJ 3358214
Trichloroethene 11/28/09 15:490.1 1ND RPJ 3358214
Trichlorofluoromethane 11/28/09 15:490.1 1ND RPJ 3358214
Vinyl chloride 11/28/09 15:490.1 1ND RPJ 3358214
Surr: 1,2-Dichloroethane-d4 11/28/09 15:49% 60-140 193.3 RPJ 3358214
Surr: 1,2-Dichloroethane-d4 11/28/09 14:31% 60-140 589.7 RPJ 3358212
Surr: 4-Bromofluorobenzene 11/28/09 15:49% 60-140 199.1 RPJ 3358214
Surr: 4-Bromofluorobenzene 11/28/09 14:31% 60-140 599.2 RPJ 3358212
Surr: Toluene-d8 11/28/09 15:49% 60-140 199.4 RPJ 3358214
Surr: Toluene-d8 11/28/09 14:31% 60-140 5103 RPJ 3358212
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 8:503012600 SRA 3358884
C9-C10 Aromatics 11/26/09 8:50101460 SRA 3358864
C9-C12 Aliphatics 11/26/09 8:50351660 SRA 3358884
Surr: 2,5-Dibromotoluene 11/26/09 8:50% 70-130 1105 SRA 3358884
Surr: 2,5-Dibromotoluene 11/26/09 8:50% 70-130 1103 SRA 3358864
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:55 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 8
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-3
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 21:580.022 1ND DF 3355568
Surr: 1-Chloro-2-fluorobenzene 11/23/09 21:58% 33-151 171.9 DF 3355568
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.09
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 20:510.01 10.165 SVW 3350891
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:55 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 9
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-3
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/26/09 9:310.2 1ND RPJ 3357418
1,1,1-Trichloroethane 11/26/09 9:310.1 1ND RPJ 3357418
1,1,2,2-Tetrachloroethane 11/26/09 9:310.1 1ND RPJ 3357418
1,1,2-Trichloroethane 11/26/09 9:310.1 1ND RPJ 3357418
1,1-Dichloroethane 11/26/09 9:310.1 1ND RPJ 3357418
1,1-Dichloroethene 11/26/09 9:310.1 1ND RPJ 3357418
1,1-Dichloropropene 11/26/09 9:310.1 1ND RPJ 3357418
1,2,3-Trichlorobenzene 11/26/09 9:310.2 1ND RPJ 3357418
1,2,3-Trichloropropane 11/26/09 9:310.1 1ND RPJ 3357418
1,2,4-Trichlorobenzene 11/26/09 9:310.2 1ND RPJ 3357418
1,2,4-Trimethylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
1,2-Dibromo-3-chloropropane 11/26/09 9:310.5 1ND RPJ 3357418
1,2-Dibromoethane 11/26/09 9:310.1 1ND RPJ 3357418
1,2-Dichlorobenzene 11/26/09 9:310.1 1ND RPJ 3357418
1,2-Dichloroethane 11/26/09 9:310.2 1ND RPJ 3357418
1,2-Dichloropropane 11/26/09 9:310.1 1ND RPJ 3357418
1,3,5-Trimethylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
1,3-Dichlorobenzene 11/26/09 9:310.2 1ND RPJ 3357418
1,3-Dichloropropane 11/26/09 9:310.1 1ND RPJ 3357418
1,4-Dichlorobenzene 11/26/09 9:310.2 1ND RPJ 3357418
2,2-Dichloropropane 11/26/09 9:310.1 1ND RPJ 3357418
2-Chlorotoluene 11/26/09 9:310.2 1ND RPJ 3357418
4-Chlorotoluene 11/26/09 9:310.2 1ND RPJ 3357418
Benzene 11/26/09 9:310.1 1ND RPJ 3357418
Bromobenzene 11/26/09 9:310.1 1ND RPJ 3357418
Bromochloromethane 11/26/09 9:310.1 1ND RPJ 3357418
Bromodichloromethane 11/26/09 9:310.1 1ND RPJ 3357418
Bromoform 11/26/09 9:310.1 1ND RPJ 3357418
Bromomethane 11/26/09 9:310.1 1ND RPJ 3357418
Carbon tetrachloride 11/26/09 9:310.1 1ND RPJ 3357418
Chlorobenzene 11/26/09 9:310.2 1ND RPJ 3357418
Chloroethane 11/26/09 9:310.2 1ND RPJ 3357418
Chloroform 11/26/09 9:310.1 1ND RPJ 3357418
Chloromethane 11/26/09 9:310.1 1ND RPJ 3357418
cis-1,2-Dichloroethene 11/26/09 9:310.1 1ND RPJ 3357418
Dibromochloromethane 11/26/09 9:310.1 1ND RPJ 3357418
Dibromomethane 11/26/09 9:310.1 1ND RPJ 3357418
Dichlorodifluoromethane 11/26/09 9:310.1 1ND RPJ 3357418
Ethylbenzene 11/26/09 9:310.2 1ND RPJ 3357418
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:56 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 10
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-3
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/26/09 9:310.2 1ND RPJ 3357418
Isopropyl ether 11/26/09 9:310.1 1ND RPJ 3357418
Isopropylbenzene 11/26/09 9:310.2 1ND RPJ 3357418
m & p-Xylene 11/26/09 9:310.1 1ND RPJ 3357418
Methyl tert-butyl ether 11/26/09 9:310.2 1ND RPJ 3357418
Methylene chloride 11/26/09 9:310.2 1ND RPJ 3357418
Naphthalene 11/26/09 9:310.1 1ND RPJ 3357418
n-Butylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
n-Propylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
o-Xylene 11/26/09 9:310.1 1ND RPJ 3357418
p-Isopropyltoluene 11/26/09 9:310.1 1ND RPJ 3357418
sec-Butylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
Styrene 11/26/09 9:310.1 1ND RPJ 3357418
tert-Butylbenzene 11/26/09 9:310.1 1ND RPJ 3357418
Tetrachloroethene 11/26/09 9:310.2 1ND RPJ 3357418
Toluene 11/26/09 9:310.1 1ND RPJ 3357418
trans-1,2-Dichloroethene 11/26/09 9:310.1 1ND RPJ 3357418
Trichloroethene 11/26/09 9:310.1 1ND RPJ 3357418
Trichlorofluoromethane 11/26/09 9:310.1 1ND RPJ 3357418
Vinyl chloride 11/26/09 9:310.1 1ND RPJ 3357418
Surr: 1,2-Dichloroethane-d4 11/26/09 9:31% 60-140 190.1 RPJ 3357418
Surr: 4-Bromofluorobenzene 11/26/09 9:31% 60-140 197.0 RPJ 3357418
Surr: Toluene-d8 11/26/09 9:31% 60-140 1100 RPJ 3357418
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 4:16301ND SRA 3358876
C9-C10 Aromatics 11/26/09 4:16101ND SRA 3358856
C9-C12 Aliphatics 11/26/09 4:16351ND SRA 3358876
Surr: 2,5-Dibromotoluene 11/26/09 4:16% 70-130 1110 SRA 3358876
Surr: 2,5-Dibromotoluene 11/26/09 4:16% 70-130 1109 SRA 3358856
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:57 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 11
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-4
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 22:180.022 1ND DF 3355569
Surr: 1-Chloro-2-fluorobenzene 11/23/09 22:18% 33-151 1122 DF 3355569
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.11
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 20:560.01 10.185 SVW 3350892
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:58 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 12
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-4
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/27/09 20:590.2 1ND RPJ 3357455
1,1,1-Trichloroethane 11/27/09 20:590.1 1ND RPJ 3357455
1,1,2,2-Tetrachloroethane 11/27/09 20:590.1 1ND RPJ 3357455
1,1,2-Trichloroethane 11/27/09 20:590.1 1ND RPJ 3357455
1,1-Dichloroethane 11/27/09 20:590.1 1ND RPJ 3357455
1,1-Dichloroethene 11/27/09 20:590.1 1ND RPJ 3357455
1,1-Dichloropropene 11/27/09 20:590.1 1ND RPJ 3357455
1,2,3-Trichlorobenzene 11/27/09 20:590.2 1ND RPJ 3357455
1,2,3-Trichloropropane 11/27/09 20:590.1 1ND RPJ 3357455
1,2,4-Trichlorobenzene 11/27/09 20:590.2 1ND RPJ 3357455
1,2,4-Trimethylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
1,2-Dibromo-3-chloropropane 11/27/09 20:590.5 1ND RPJ 3357455
1,2-Dibromoethane 11/27/09 20:590.1 1ND RPJ 3357455
1,2-Dichlorobenzene 11/27/09 20:590.1 1ND RPJ 3357455
1,2-Dichloroethane 11/27/09 20:590.2 1ND RPJ 3357455
1,2-Dichloropropane 11/27/09 20:590.1 1ND RPJ 3357455
1,3,5-Trimethylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
1,3-Dichlorobenzene 11/27/09 20:590.2 1ND RPJ 3357455
1,3-Dichloropropane 11/27/09 20:590.1 1ND RPJ 3357455
1,4-Dichlorobenzene 11/27/09 20:590.2 1ND RPJ 3357455
2,2-Dichloropropane 11/27/09 20:590.1 1ND RPJ 3357455
2-Chlorotoluene 11/27/09 20:590.2 1ND RPJ 3357455
4-Chlorotoluene 11/27/09 20:590.2 1ND RPJ 3357455
Benzene 11/27/09 20:590.1 1ND RPJ 3357455
Bromobenzene 11/27/09 20:590.1 1ND RPJ 3357455
Bromochloromethane 11/27/09 20:590.1 1ND RPJ 3357455
Bromodichloromethane 11/27/09 20:590.1 1ND RPJ 3357455
Bromoform 11/27/09 20:590.1 1ND RPJ 3357455
Bromomethane 11/27/09 20:590.1 1ND RPJ 3357455
Carbon tetrachloride 11/27/09 20:590.1 1ND RPJ 3357455
Chlorobenzene 11/27/09 20:590.2 1ND RPJ 3357455
Chloroethane 11/27/09 20:590.2 1ND RPJ 3357455
Chloroform 11/27/09 20:590.1 1ND RPJ 3357455
Chloromethane 11/27/09 20:590.1 1ND RPJ 3357455
cis-1,2-Dichloroethene 11/27/09 20:590.1 1ND RPJ 3357455
Dibromochloromethane 11/27/09 20:590.1 1ND RPJ 3357455
Dibromomethane 11/27/09 20:590.1 1ND RPJ 3357455
Dichlorodifluoromethane 11/27/09 20:590.1 1ND RPJ 3357455
Ethylbenzene 11/27/09 20:590.2 1ND RPJ 3357455
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:58 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 13
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-4
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 10:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/27/09 20:590.2 1ND RPJ 3357455
Isopropyl ether 11/27/09 20:590.1 1ND RPJ 3357455
Isopropylbenzene 11/27/09 20:590.2 1ND RPJ 3357455
m & p-Xylene 11/27/09 20:590.1 10.28 RPJ 3357455
Methyl tert-butyl ether 11/27/09 20:590.2 1ND RPJ 3357455
Methylene chloride 11/27/09 20:590.2 1ND RPJ 3357455
Naphthalene 11/27/09 20:590.1 1ND RPJ 3357455
n-Butylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
n-Propylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
o-Xylene 11/27/09 20:590.1 10.13 RPJ 3357455
p-Isopropyltoluene 11/27/09 20:590.1 1ND RPJ 3357455
sec-Butylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
Styrene 11/27/09 20:590.1 1ND RPJ 3357455
tert-Butylbenzene 11/27/09 20:590.1 1ND RPJ 3357455
Tetrachloroethene 11/27/09 20:590.2 1ND RPJ 3357455
Toluene 11/27/09 20:590.1 10.54 RPJ 3357455
trans-1,2-Dichloroethene 11/27/09 20:590.1 1ND RPJ 3357455
Trichloroethene 11/27/09 20:590.1 1ND RPJ 3357455
Trichlorofluoromethane 11/27/09 20:590.1 1ND RPJ 3357455
Vinyl chloride 11/27/09 20:590.1 1ND RPJ 3357455
Surr: 1,2-Dichloroethane-d4 11/27/09 20:59% 60-140 188.9 RPJ 3357455
Surr: 4-Bromofluorobenzene 11/27/09 20:59% 60-140 196.8 RPJ 3357455
Surr: Toluene-d8 11/27/09 20:59% 60-140 1100 RPJ 3357455
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 4:51301ND SRA 3358877
C9-C10 Aromatics 11/26/09 4:51101ND SRA 3358857
C9-C12 Aliphatics 11/26/09 4:51351ND SRA 3358877
Surr: 2,5-Dibromotoluene 11/26/09 4:51% 70-130 1112 SRA 3358877
Surr: 2,5-Dibromotoluene 11/26/09 4:51% 70-130 1110 SRA 3358857
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:20:59 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 14
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 22:380.022 1ND DF 3355570
Surr: 1-Chloro-2-fluorobenzene 11/23/09 22:38% 33-151 1119 DF 3355570
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.11
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 21:010.01 1ND SVW 3350893
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:00 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 15
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/27/09 21:370.2 1ND RPJ 3357456
1,1,1-Trichloroethane 11/27/09 21:370.1 1ND RPJ 3357456
1,1,2,2-Tetrachloroethane 11/27/09 21:370.1 1ND RPJ 3357456
1,1,2-Trichloroethane 11/27/09 21:370.1 1ND RPJ 3357456
1,1-Dichloroethane 11/27/09 21:370.1 1ND RPJ 3357456
1,1-Dichloroethene 11/27/09 21:370.1 1ND RPJ 3357456
1,1-Dichloropropene 11/27/09 21:370.1 1ND RPJ 3357456
1,2,3-Trichlorobenzene 11/27/09 21:370.2 1ND RPJ 3357456
1,2,3-Trichloropropane 11/27/09 21:370.1 1ND RPJ 3357456
1,2,4-Trichlorobenzene 11/27/09 21:370.2 1ND RPJ 3357456
1,2,4-Trimethylbenzene 11/27/09 21:370.1 112 RPJ 3357456
1,2-Dibromo-3-chloropropane 11/27/09 21:370.5 1ND RPJ 3357456
1,2-Dibromoethane 11/27/09 21:370.1 1ND RPJ 3357456
1,2-Dichlorobenzene 11/27/09 21:370.1 1ND RPJ 3357456
1,2-Dichloroethane 11/27/09 21:370.2 1ND RPJ 3357456
1,2-Dichloropropane 11/27/09 21:370.1 1ND RPJ 3357456
1,3,5-Trimethylbenzene 11/27/09 21:370.1 13.7 RPJ 3357456
1,3-Dichlorobenzene 11/27/09 21:370.2 1ND RPJ 3357456
1,3-Dichloropropane 11/27/09 21:370.1 1ND RPJ 3357456
1,4-Dichlorobenzene 11/27/09 21:370.2 1ND RPJ 3357456
2,2-Dichloropropane 11/27/09 21:370.1 1ND RPJ 3357456
2-Chlorotoluene 11/27/09 21:370.2 1ND RPJ 3357456
4-Chlorotoluene 11/27/09 21:370.2 1ND RPJ 3357456
Benzene 11/27/09 21:370.1 135 RPJ 3357456
Bromobenzene 11/27/09 21:370.1 1ND RPJ 3357456
Bromochloromethane 11/27/09 21:370.1 1ND RPJ 3357456
Bromodichloromethane 11/27/09 21:370.1 1ND RPJ 3357456
Bromoform 11/27/09 21:370.1 1ND RPJ 3357456
Bromomethane 11/27/09 21:370.1 1ND RPJ 3357456
Carbon tetrachloride 11/27/09 21:370.1 1ND RPJ 3357456
Chlorobenzene 11/27/09 21:370.2 1ND RPJ 3357456
Chloroethane 11/27/09 21:370.2 1ND RPJ 3357456
Chloroform 11/27/09 21:370.1 17.7 RPJ 3357456
Chloromethane 11/27/09 21:370.1 1ND RPJ 3357456
cis-1,2-Dichloroethene 11/27/09 21:370.1 1ND RPJ 3357456
Dibromochloromethane 11/27/09 21:370.1 1ND RPJ 3357456
Dibromomethane 11/27/09 21:370.1 1ND RPJ 3357456
Dichlorodifluoromethane 11/27/09 21:370.1 1ND RPJ 3357456
Ethylbenzene 11/27/09 21:370.2 19.9 RPJ 3357456
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:01 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 16
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-5
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 13:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/27/09 21:370.2 1ND RPJ 3357456
Isopropyl ether 11/27/09 21:370.1 1ND RPJ 3357456
Isopropylbenzene 11/27/09 21:370.2 10.87 RPJ 3357456
m & p-Xylene 11/27/09 21:370.1 145 RPJ 3357456
Methyl tert-butyl ether 11/27/09 21:370.2 11.7 RPJ 3357456
Methylene chloride 11/27/09 21:370.2 1ND RPJ 3357456
Naphthalene 11/27/09 21:370.1 11.1 RPJ 3357456
n-Butylbenzene 11/27/09 21:370.1 1ND RPJ 3357456
n-Propylbenzene 11/27/09 21:370.1 11.4 RPJ 3357456
o-Xylene 11/27/09 21:370.1 116 RPJ 3357456
p-Isopropyltoluene 11/27/09 21:370.1 1ND RPJ 3357456
sec-Butylbenzene 11/27/09 21:370.1 1ND RPJ 3357456
Styrene 11/27/09 21:370.1 1ND RPJ 3357456
tert-Butylbenzene 11/27/09 21:370.1 1ND RPJ 3357456
Tetrachloroethene 11/27/09 21:370.2 1ND RPJ 3357456
Toluene 11/27/09 21:370.1 188 RPJ 3357456
trans-1,2-Dichloroethene 11/27/09 21:370.1 1ND RPJ 3357456
Trichloroethene 11/27/09 21:370.1 1ND RPJ 3357456
Trichlorofluoromethane 11/27/09 21:370.1 1ND RPJ 3357456
Vinyl chloride 11/27/09 21:370.1 1ND RPJ 3357456
Surr: 1,2-Dichloroethane-d4 11/27/09 21:37% 60-140 186.8 RPJ 3357456
Surr: 4-Bromofluorobenzene 11/27/09 21:37% 60-140 198.8 RPJ 3357456
Surr: Toluene-d8 11/27/09 21:37% 60-140 199.7 RPJ 3357456
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 5:25301800 SRA 3358878
C9-C10 Aromatics 11/26/09 5:2510150 SRA 3358858
C9-C12 Aliphatics 11/26/09 5:25351130 SRA 3358878
Surr: 2,5-Dibromotoluene 11/26/09 5:25% 70-130 1104 SRA 3358878
Surr: 2,5-Dibromotoluene 11/26/09 5:25% 70-130 1102 SRA 3358858
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:02 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 17
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-6
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 22:580.023 1ND DF 3355571
Surr: 1-Chloro-2-fluorobenzene 11/23/09 22:58% 33-151 1122 DF 3355571
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.14
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 21:070.01 10.0452 SVW 3350894
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:03 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 18
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-6
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/28/09 12:340.2 1ND RPJ 3358209
1,1,1-Trichloroethane 11/28/09 12:340.1 1ND RPJ 3358209
1,1,2,2-Tetrachloroethane 11/28/09 12:340.1 1ND RPJ 3358209
1,1,2-Trichloroethane 11/28/09 12:340.1 1ND RPJ 3358209
1,1-Dichloroethane 11/28/09 12:340.1 1ND RPJ 3358209
1,1-Dichloroethene 11/28/09 12:340.1 1ND RPJ 3358209
1,1-Dichloropropene 11/28/09 12:340.1 1ND RPJ 3358209
1,2,3-Trichlorobenzene 11/28/09 12:340.2 1ND RPJ 3358209
1,2,3-Trichloropropane 11/28/09 12:340.1 1ND RPJ 3358209
1,2,4-Trichlorobenzene 11/28/09 12:340.2 1ND RPJ 3358209
1,2,4-Trimethylbenzene 11/28/09 12:340.1 123 RPJ 3358209
1,2-Dibromo-3-chloropropane 11/28/09 12:340.5 1ND RPJ 3358209
1,2-Dibromoethane 11/28/09 12:340.1 1ND RPJ 3358209
1,2-Dichlorobenzene 11/28/09 12:340.1 1ND RPJ 3358209
1,2-Dichloroethane 11/28/09 12:340.2 10.34 RPJ 3358209
1,2-Dichloropropane 11/28/09 12:340.1 1ND RPJ 3358209
1,3,5-Trimethylbenzene 11/28/09 12:340.1 14 RPJ 3358209
1,3-Dichlorobenzene 11/28/09 12:340.2 1ND RPJ 3358209
1,3-Dichloropropane 11/28/09 12:340.1 1ND RPJ 3358209
1,4-Dichlorobenzene 11/28/09 12:340.2 1ND RPJ 3358209
2,2-Dichloropropane 11/28/09 12:340.1 1ND RPJ 3358209
2-Chlorotoluene 11/28/09 12:340.2 1ND RPJ 3358209
4-Chlorotoluene 11/28/09 12:340.2 1ND RPJ 3358209
Benzene 12/01/09 1:450.5 5370 NDG 3360232
Bromobenzene 11/28/09 12:340.1 1ND RPJ 3358209
Bromochloromethane 11/28/09 12:340.1 1ND RPJ 3358209
Bromodichloromethane 11/28/09 12:340.1 1ND RPJ 3358209
Bromoform 11/28/09 12:340.1 1ND RPJ 3358209
Bromomethane 11/28/09 12:340.1 1ND RPJ 3358209
Carbon tetrachloride 11/28/09 12:340.1 1ND RPJ 3358209
Chlorobenzene 11/28/09 12:340.2 1ND RPJ 3358209
Chloroethane 11/28/09 12:340.2 1ND RPJ 3358209
Chloroform 11/28/09 12:340.1 1ND RPJ 3358209
Chloromethane 11/28/09 12:340.1 1ND RPJ 3358209
cis-1,2-Dichloroethene 11/28/09 12:340.1 1ND RPJ 3358209
Dibromochloromethane 11/28/09 12:340.1 1ND RPJ 3358209
Dibromomethane 11/28/09 12:340.1 1ND RPJ 3358209
Dichlorodifluoromethane 11/28/09 12:340.1 1ND RPJ 3358209
Ethylbenzene 11/28/09 12:340.2 139 RPJ 3358209
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:04 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 19
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-6
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/28/09 12:340.2 1ND RPJ 3358209
Isopropyl ether 11/28/09 12:340.1 13 RPJ 3358209
Isopropylbenzene 11/28/09 12:340.2 13.7 RPJ 3358209
m & p-Xylene 11/28/09 12:340.1 1120 RPJ 3358209
Methyl tert-butyl ether 11/28/09 12:340.2 1130 RPJ 3358209
Methylene chloride 11/28/09 12:340.2 1ND RPJ 3358209
Naphthalene 11/28/09 12:340.1 11.2 RPJ 3358209
n-Butylbenzene 11/28/09 12:340.1 10.79 RPJ 3358209
n-Propylbenzene 11/28/09 12:340.1 17.2 RPJ 3358209
o-Xylene 11/28/09 12:340.1 148 RPJ 3358209
p-Isopropyltoluene 11/28/09 12:340.1 11.9 RPJ 3358209
sec-Butylbenzene 11/28/09 12:340.1 10.89 RPJ 3358209
Styrene 11/28/09 12:340.1 1ND RPJ 3358209
tert-Butylbenzene 11/28/09 12:340.1 1ND RPJ 3358209
Tetrachloroethene 11/28/09 12:340.2 1ND RPJ 3358209
Toluene 11/28/09 12:340.1 1180 RPJ 3358209
trans-1,2-Dichloroethene 11/28/09 12:340.1 1ND RPJ 3358209
Trichloroethene 11/28/09 12:340.1 1ND RPJ 3358209
Trichlorofluoromethane 11/28/09 12:340.1 1ND RPJ 3358209
Vinyl chloride 11/28/09 12:340.1 1ND RPJ 3358209
Surr: 1,2-Dichloroethane-d4 11/28/09 12:34% 60-140 190.0 RPJ 3358209
Surr: 1,2-Dichloroethane-d4 12/01/09 1:45% 60-140 5104 NDG 3360232
Surr: 4-Bromofluorobenzene 11/28/09 12:34% 60-140 1101 RPJ 3358209
Surr: 4-Bromofluorobenzene 12/01/09 1:45% 60-140 598.0 NDG 3360232
Surr: Toluene-d8 11/28/09 12:34% 60-140 1105 RPJ 3358209
Surr: Toluene-d8 12/01/09 1:45% 60-140 5104 NDG 3360232
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 9:263011200 SRA 3358885
C9-C10 Aromatics 11/26/09 9:26101990 SRA 3358865
C9-C12 Aliphatics 11/26/09 9:26351410 SRA 3358885
Surr: 2,5-Dibromotoluene 11/26/09 9:26% 70-130 1109 SRA 3358885
Surr: 2,5-Dibromotoluene 11/26/09 9:26% 70-130 1106 SRA 3358865
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:05 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 20
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-7
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 12:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/23/09 23:190.023 1ND DF 3355572
Surr: 1-Chloro-2-fluorobenzene 11/23/09 23:19% 33-151 196.9 DF 3355572
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.14
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 21:120.01 1ND SVW 3350895
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:06 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 21
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-7
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 12:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/26/09 7:340.2 1ND RPJ 3357415
1,1,1-Trichloroethane 11/26/09 7:340.1 1ND RPJ 3357415
1,1,2,2-Tetrachloroethane 11/26/09 7:340.1 1ND RPJ 3357415
1,1,2-Trichloroethane 11/26/09 7:340.1 1ND RPJ 3357415
1,1-Dichloroethane 11/26/09 7:340.1 1ND RPJ 3357415
1,1-Dichloroethene 11/26/09 7:340.1 1ND RPJ 3357415
1,1-Dichloropropene 11/26/09 7:340.1 1ND RPJ 3357415
1,2,3-Trichlorobenzene 11/26/09 7:340.2 1ND RPJ 3357415
1,2,3-Trichloropropane 11/26/09 7:340.1 1ND RPJ 3357415
1,2,4-Trichlorobenzene 11/26/09 7:340.2 1ND RPJ 3357415
1,2,4-Trimethylbenzene 11/26/09 7:340.1 1100 RPJ 3357415
1,2-Dibromo-3-chloropropane 11/26/09 7:340.5 1ND RPJ 3357415
1,2-Dibromoethane 11/26/09 7:340.1 1ND RPJ 3357415
1,2-Dichlorobenzene 11/26/09 7:340.1 1ND RPJ 3357415
1,2-Dichloroethane 11/26/09 7:340.2 11.4 RPJ 3357415
1,2-Dichloropropane 11/26/09 7:340.1 1ND RPJ 3357415
1,3,5-Trimethylbenzene 11/26/09 7:340.1 131 RPJ 3357415
1,3-Dichlorobenzene 11/26/09 7:340.2 1ND RPJ 3357415
1,3-Dichloropropane 11/26/09 7:340.1 1ND RPJ 3357415
1,4-Dichlorobenzene 11/26/09 7:340.2 1ND RPJ 3357415
2,2-Dichloropropane 11/26/09 7:340.1 1ND RPJ 3357415
2-Chlorotoluene 11/26/09 7:340.2 1ND RPJ 3357415
4-Chlorotoluene 11/26/09 7:340.2 1ND RPJ 3357415
Benzene 11/27/09 22:56110920 RPJ 3357458
Bromobenzene 11/26/09 7:340.1 1ND RPJ 3357415
Bromochloromethane 11/26/09 7:340.1 1ND RPJ 3357415
Bromodichloromethane 11/26/09 7:340.1 1ND RPJ 3357415
Bromoform 11/26/09 7:340.1 1ND RPJ 3357415
Bromomethane 11/26/09 7:340.1 1ND RPJ 3357415
Carbon tetrachloride 11/26/09 7:340.1 1ND RPJ 3357415
Chlorobenzene 11/26/09 7:340.2 1ND RPJ 3357415
Chloroethane 11/26/09 7:340.2 1ND RPJ 3357415
Chloroform 11/26/09 7:340.1 112 RPJ 3357415
Chloromethane 11/26/09 7:340.1 1ND RPJ 3357415
cis-1,2-Dichloroethene 11/26/09 7:340.1 1ND RPJ 3357415
Dibromochloromethane 11/26/09 7:340.1 1ND RPJ 3357415
Dibromomethane 11/26/09 7:340.1 1ND RPJ 3357415
Dichlorodifluoromethane 11/26/09 7:340.1 1ND RPJ 3357415
Ethylbenzene 11/26/09 7:340.2 178 RPJ 3357415
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:06 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 22
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-7
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 12:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/26/09 7:340.2 1ND RPJ 3357415
Isopropyl ether 11/26/09 7:340.1 112 RPJ 3357415
Isopropylbenzene 11/26/09 7:340.2 17.4 RPJ 3357415
m & p-Xylene 11/26/09 7:340.1 1370 RPJ 3357415
Methyl tert-butyl ether 11/27/09 22:56210290 RPJ 3357458
Methylene chloride 11/26/09 7:340.2 1ND RPJ 3357415
Naphthalene 11/26/09 7:340.1 15.4 RPJ 3357415
n-Butylbenzene 11/26/09 7:340.1 13.2 RPJ 3357415
n-Propylbenzene 11/26/09 7:340.1 19.3 RPJ 3357415
o-Xylene 11/26/09 7:340.1 1150 RPJ 3357415
p-Isopropyltoluene 11/26/09 7:340.1 12.6 RPJ 3357415
sec-Butylbenzene 11/26/09 7:340.1 1ND RPJ 3357415
Styrene 11/26/09 7:340.1 10.58 RPJ 3357415
tert-Butylbenzene 11/26/09 7:340.1 1ND RPJ 3357415
Tetrachloroethene 11/26/09 7:340.2 1ND RPJ 3357415
Toluene 11/27/09 22:56110890 RPJ 3357458
trans-1,2-Dichloroethene 11/26/09 7:340.1 1ND RPJ 3357415
Trichloroethene 11/26/09 7:340.1 1ND RPJ 3357415
Trichlorofluoromethane 11/26/09 7:340.1 1ND RPJ 3357415
Vinyl chloride 11/26/09 7:340.1 1ND RPJ 3357415
Surr: 1,2-Dichloroethane-d4 11/26/09 7:34% 60-140 194.6 RPJ 3357415
Surr: 1,2-Dichloroethane-d4 11/27/09 22:56% 60-140 1086.3 RPJ 3357458
Surr: 4-Bromofluorobenzene 11/26/09 7:34% 60-140 1101 RPJ 3357415
Surr: 4-Bromofluorobenzene 11/27/09 22:56% 60-140 1097.8 RPJ 3357458
Surr: Toluene-d8 11/26/09 7:34% 60-140 197.6 RPJ 3357415
Surr: Toluene-d8 11/27/09 22:56% 60-140 1099.2 RPJ 3357458
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/29/09 4:4815054200 SRA 3359223
C9-C10 Aromatics 11/26/09 6:36101550 SRA 3358860
C9-C12 Aliphatics 11/26/09 6:363511000 SRA 3358880
Surr: 2,5-Dibromotoluene 11/29/09 4:48% 70-130 588.6 SRA 3359223
Surr: 2,5-Dibromotoluene 11/26/09 6:36% 70-130 1104 SRA 3358880
Surr: 2,5-Dibromotoluene 11/26/09 6:36% 70-130 1103 SRA 3358860
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:07 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 23
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-08
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/24/09 0:000.022 12.8 DF 3355634
Surr: 1-Chloro-2-fluorobenzene 11/24/09 0:00% 33-151 198.6 DF 3355634
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.11
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 21:170.01 1ND SVW 3350896
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:08 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 24
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-08
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/26/09 12:081050ND RPJ 3357422
1,1,1-Trichloroethane 11/26/09 12:08550ND RPJ 3357422
1,1,2,2-Tetrachloroethane 11/26/09 12:08550ND RPJ 3357422
1,1,2-Trichloroethane 11/26/09 12:08550ND RPJ 3357422
1,1-Dichloroethane 11/26/09 12:08550ND RPJ 3357422
1,1-Dichloroethene 11/26/09 12:08550ND RPJ 3357422
1,1-Dichloropropene 11/26/09 12:08550ND RPJ 3357422
1,2,3-Trichlorobenzene 11/26/09 12:081050ND RPJ 3357422
1,2,3-Trichloropropane 11/26/09 12:08550ND RPJ 3357422
1,2,4-Trichlorobenzene 11/26/09 12:081050ND RPJ 3357422
1,2,4-Trimethylbenzene 11/26/09 12:08550580 RPJ 3357422
1,2-Dibromo-3-chloropropane 11/26/09 12:082550ND RPJ 3357422
1,2-Dibromoethane 11/26/09 12:08550ND RPJ 3357422
1,2-Dichlorobenzene 11/26/09 12:08550ND RPJ 3357422
1,2-Dichloroethane 11/26/09 12:08105039 RPJ 3357422
1,2-Dichloropropane 11/26/09 12:08550ND RPJ 3357422
1,3,5-Trimethylbenzene 11/26/09 12:08550130 RPJ 3357422
1,3-Dichlorobenzene 11/26/09 12:081050ND RPJ 3357422
1,3-Dichloropropane 11/26/09 12:08550ND RPJ 3357422
1,4-Dichlorobenzene 11/26/09 12:081050ND RPJ 3357422
2,2-Dichloropropane 11/26/09 12:08550ND RPJ 3357422
2-Chlorotoluene 11/26/09 12:081050ND RPJ 3357422
4-Chlorotoluene 11/26/09 12:081050ND RPJ 3357422
Benzene 11/26/09 12:085501900 RPJ 3357422
Bromobenzene 11/26/09 12:08550ND RPJ 3357422
Bromochloromethane 11/26/09 12:08550ND RPJ 3357422
Bromodichloromethane 11/26/09 12:08550ND RPJ 3357422
Bromoform 11/26/09 12:08550ND RPJ 3357422
Bromomethane 11/26/09 12:08550ND RPJ 3357422
Carbon tetrachloride 11/26/09 12:08550ND RPJ 3357422
Chlorobenzene 11/26/09 12:081050ND RPJ 3357422
Chloroethane 11/26/09 12:081050ND RPJ 3357422
Chloroform 11/26/09 12:08550ND RPJ 3357422
Chloromethane 11/26/09 12:08550ND RPJ 3357422
cis-1,2-Dichloroethene 11/26/09 12:08550ND RPJ 3357422
Dibromochloromethane 11/26/09 12:08550ND RPJ 3357422
Dibromomethane 11/26/09 12:08550ND RPJ 3357422
Dichlorodifluoromethane 11/26/09 12:08550ND RPJ 3357422
Ethylbenzene 11/26/09 12:081050900 RPJ 3357422
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:09 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 25
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-8
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-08
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 14:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/26/09 12:081050ND RPJ 3357422
Isopropyl ether 11/26/09 12:08550ND RPJ 3357422
Isopropylbenzene 11/26/09 12:08105025 RPJ 3357422
m & p-Xylene 11/26/09 12:085503000 RPJ 3357422
Methyl tert-butyl ether 11/26/09 12:081050ND RPJ 3357422
Methylene chloride 11/26/09 12:081050ND RPJ 3357422
Naphthalene 11/26/09 12:08550130 RPJ 3357422
n-Butylbenzene 11/26/09 12:08550ND RPJ 3357422
n-Propylbenzene 11/26/09 12:0855061 RPJ 3357422
o-Xylene 11/26/09 12:085501600 RPJ 3357422
p-Isopropyltoluene 11/26/09 12:08550ND RPJ 3357422
sec-Butylbenzene 11/26/09 12:08550ND RPJ 3357422
Styrene 11/26/09 12:0855029 RPJ 3357422
tert-Butylbenzene 11/26/09 12:08550ND RPJ 3357422
Tetrachloroethene 11/26/09 12:08105027 RPJ 3357422
Toluene 11/28/09 0:142020017000 RPJ 3357460
trans-1,2-Dichloroethene 11/26/09 12:08550ND RPJ 3357422
Trichloroethene 11/26/09 12:0855027 RPJ 3357422
Trichlorofluoromethane 11/26/09 12:08550ND RPJ 3357422
Vinyl chloride 11/26/09 12:08550ND RPJ 3357422
Surr: 1,2-Dichloroethane-d4 11/26/09 12:08% 60-140 5089.8 RPJ 3357422
Surr: 1,2-Dichloroethane-d4 11/28/09 0:14% 60-140 20087.2 RPJ 3357460
Surr: 4-Bromofluorobenzene 11/26/09 12:08% 60-140 5097.2 RPJ 3357422
Surr: 4-Bromofluorobenzene 11/28/09 0:14% 60-140 20099.1 RPJ 3357460
Surr: Toluene-d8 11/26/09 12:08% 60-140 50102 RPJ 3357422
Surr: Toluene-d8 11/28/09 0:14% 60-140 200105 RPJ 3357460
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/29/09 5:553001031000 SRA 3359225
C9-C10 Aromatics 11/29/09 5:215054100 SRA 3359216
C9-C12 Aliphatics 11/29/09 5:2118058700 SRA 3359224
Surr: 2,5-Dibromotoluene 11/29/09 5:55% 70-130 10104 SRA 3359225
Surr: 2,5-Dibromotoluene 11/29/09 5:21% 70-130 597.2 SRA 3359224
Surr: 2,5-Dibromotoluene 11/29/09 5:21% 70-130 594.8 SRA 3359216
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:09 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 26
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-09
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/24/09 0:210.022 1ND DF 3355575
Surr: 1-Chloro-2-fluorobenzene 11/24/09 0:21% 33-151 183.3 DF 3355575
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.09
TOTAL METALS BY METHOD 6010B - WATER SW6010B mg/LUnits:MCL
Lead 11/19/09 21:220.01 1ND SVW 3350897
Prep Method Prep Date Prep Initials Prep Factor
11/18/2009 15:15 SAM3030-C 1.00
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:10 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 27
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-09
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/26/09 10:490.2 1ND RPJ 3357420
1,1,1-Trichloroethane 11/26/09 10:490.1 1ND RPJ 3357420
1,1,2,2-Tetrachloroethane 11/26/09 10:490.1 1ND RPJ 3357420
1,1,2-Trichloroethane 11/26/09 10:490.1 1ND RPJ 3357420
1,1-Dichloroethane 11/26/09 10:490.1 1ND RPJ 3357420
1,1-Dichloroethene 11/26/09 10:490.1 1ND RPJ 3357420
1,1-Dichloropropene 11/26/09 10:490.1 1ND RPJ 3357420
1,2,3-Trichlorobenzene 11/26/09 10:490.2 1ND RPJ 3357420
1,2,3-Trichloropropane 11/26/09 10:490.1 1ND RPJ 3357420
1,2,4-Trichlorobenzene 11/26/09 10:490.2 1ND RPJ 3357420
1,2,4-Trimethylbenzene 11/26/09 10:490.1 141 RPJ 3357420
1,2-Dibromo-3-chloropropane 11/26/09 10:490.5 1ND RPJ 3357420
1,2-Dibromoethane 11/26/09 10:490.1 1ND RPJ 3357420
1,2-Dichlorobenzene 11/26/09 10:490.1 1ND RPJ 3357420
1,2-Dichloroethane 11/26/09 10:490.2 1ND RPJ 3357420
1,2-Dichloropropane 11/26/09 10:490.1 1ND RPJ 3357420
1,3,5-Trimethylbenzene 11/26/09 10:490.1 1ND RPJ 3357420
1,3-Dichlorobenzene 11/26/09 10:490.2 1ND RPJ 3357420
1,3-Dichloropropane 11/26/09 10:490.1 1ND RPJ 3357420
1,4-Dichlorobenzene 11/26/09 10:490.2 1ND RPJ 3357420
2,2-Dichloropropane 11/26/09 10:490.1 1ND RPJ 3357420
2-Chlorotoluene 11/26/09 10:490.2 1ND RPJ 3357420
4-Chlorotoluene 11/26/09 10:490.2 1ND RPJ 3357420
Benzene 11/26/09 10:490.1 1140 RPJ 3357420
Bromobenzene 11/26/09 10:490.1 1ND RPJ 3357420
Bromochloromethane 11/26/09 10:490.1 1ND RPJ 3357420
Bromodichloromethane 11/26/09 10:490.1 1ND RPJ 3357420
Bromoform 11/26/09 10:490.1 1ND RPJ 3357420
Bromomethane 11/26/09 10:490.1 1ND RPJ 3357420
Carbon tetrachloride 11/26/09 10:490.1 1ND RPJ 3357420
Chlorobenzene 11/26/09 10:490.2 1ND RPJ 3357420
Chloroethane 11/26/09 10:490.2 1ND RPJ 3357420
Chloroform 11/26/09 10:490.1 17.9 RPJ 3357420
Chloromethane 11/26/09 10:490.1 1ND RPJ 3357420
cis-1,2-Dichloroethene 11/26/09 10:490.1 1ND RPJ 3357420
Dibromochloromethane 11/26/09 10:490.1 1ND RPJ 3357420
Dibromomethane 11/26/09 10:490.1 1ND RPJ 3357420
Dichlorodifluoromethane 11/26/09 10:490.1 1ND RPJ 3357420
Ethylbenzene 11/26/09 10:490.2 13.4 RPJ 3357420
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:11 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 28
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-09
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 11:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/26/09 10:490.2 1ND RPJ 3357420
Isopropyl ether 11/26/09 10:490.1 12.3 RPJ 3357420
Isopropylbenzene 11/26/09 10:490.2 12.6 RPJ 3357420
m & p-Xylene 11/26/09 10:490.1 138 RPJ 3357420
Methyl tert-butyl ether 12/01/09 0:2615450 NDG 3360231
Methylene chloride 11/26/09 10:490.2 1ND RPJ 3357420
Naphthalene 11/26/09 10:490.1 13.4 RPJ 3357420
n-Butylbenzene 11/26/09 10:490.1 11.2 RPJ 3357420
n-Propylbenzene 11/26/09 10:490.1 13.2 RPJ 3357420
o-Xylene 11/26/09 10:490.1 118 RPJ 3357420
p-Isopropyltoluene 11/26/09 10:490.1 12.1 RPJ 3357420
sec-Butylbenzene 11/26/09 10:490.1 1ND RPJ 3357420
Styrene 11/26/09 10:490.1 1ND RPJ 3357420
tert-Butylbenzene 11/26/09 10:490.1 1ND RPJ 3357420
Tetrachloroethene 11/26/09 10:490.2 1ND RPJ 3357420
Toluene 11/26/09 10:490.1 10.41 RPJ 3357420
trans-1,2-Dichloroethene 11/26/09 10:490.1 1ND RPJ 3357420
Trichloroethene 11/26/09 10:490.1 1ND RPJ 3357420
Trichlorofluoromethane 11/26/09 10:490.1 1ND RPJ 3357420
Vinyl chloride 11/26/09 10:490.1 1ND RPJ 3357420
Surr: 1,2-Dichloroethane-d4 11/26/09 10:49% 60-140 188.1 RPJ 3357420
Surr: 1,2-Dichloroethane-d4 12/01/09 0:26% 60-140 5102 NDG 3360231
Surr: 4-Bromofluorobenzene 11/26/09 10:49% 60-140 196.0 RPJ 3357420
Surr: 4-Bromofluorobenzene 12/01/09 0:26% 60-140 597.0 NDG 3360231
Surr: Toluene-d8 11/26/09 10:49% 60-140 197.8 RPJ 3357420
Surr: Toluene-d8 12/01/09 0:26% 60-140 5103 NDG 3360231
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 7:133011300 SRA 3358881
C9-C10 Aromatics 11/26/09 7:13101180 SRA 3358861
C9-C12 Aliphatics 11/26/09 7:13351230 SRA 3358881
Surr: 2,5-Dibromotoluene 11/26/09 7:13% 70-130 1105 SRA 3358881
Surr: 2,5-Dibromotoluene 11/26/09 7:13% 70-130 1103 SRA 3358861
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:12 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 29
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15 (CORRELL)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-10
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:25
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/24/09 0:410.022 1ND DF 3355576
Surr: 1-Chloro-2-fluorobenzene 11/24/09 0:41% 33-151 1103 DF 3355576
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.10
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:12 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 30
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15 (CORRELL)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-10
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:25
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/26/09 10:100.2 1ND RPJ 3357419
1,1,1-Trichloroethane 11/26/09 10:100.1 1ND RPJ 3357419
1,1,2,2-Tetrachloroethane 11/26/09 10:100.1 1ND RPJ 3357419
1,1,2-Trichloroethane 11/26/09 10:100.1 1ND RPJ 3357419
1,1-Dichloroethane 11/26/09 10:100.1 1ND RPJ 3357419
1,1-Dichloroethene 11/26/09 10:100.1 1ND RPJ 3357419
1,1-Dichloropropene 11/26/09 10:100.1 1ND RPJ 3357419
1,2,3-Trichlorobenzene 11/26/09 10:100.2 1ND RPJ 3357419
1,2,3-Trichloropropane 11/26/09 10:100.1 1ND RPJ 3357419
1,2,4-Trichlorobenzene 11/26/09 10:100.2 1ND RPJ 3357419
1,2,4-Trimethylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
1,2-Dibromo-3-chloropropane 11/26/09 10:100.5 1ND RPJ 3357419
1,2-Dibromoethane 11/26/09 10:100.1 1ND RPJ 3357419
1,2-Dichlorobenzene 11/26/09 10:100.1 1ND RPJ 3357419
1,2-Dichloroethane 11/26/09 10:100.2 1ND RPJ 3357419
1,2-Dichloropropane 11/26/09 10:100.1 1ND RPJ 3357419
1,3,5-Trimethylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
1,3-Dichlorobenzene 11/26/09 10:100.2 1ND RPJ 3357419
1,3-Dichloropropane 11/26/09 10:100.1 1ND RPJ 3357419
1,4-Dichlorobenzene 11/26/09 10:100.2 1ND RPJ 3357419
2,2-Dichloropropane 11/26/09 10:100.1 1ND RPJ 3357419
2-Chlorotoluene 11/26/09 10:100.2 1ND RPJ 3357419
4-Chlorotoluene 11/26/09 10:100.2 1ND RPJ 3357419
Benzene 11/26/09 10:100.1 1ND RPJ 3357419
Bromobenzene 11/26/09 10:100.1 1ND RPJ 3357419
Bromochloromethane 11/26/09 10:100.1 1ND RPJ 3357419
Bromodichloromethane 11/26/09 10:100.1 1ND RPJ 3357419
Bromoform 11/26/09 10:100.1 1ND RPJ 3357419
Bromomethane 11/26/09 10:100.1 1ND RPJ 3357419
Carbon tetrachloride 11/26/09 10:100.1 1ND RPJ 3357419
Chlorobenzene 11/26/09 10:100.2 1ND RPJ 3357419
Chloroethane 11/26/09 10:100.2 1ND RPJ 3357419
Chloroform 11/26/09 10:100.1 1ND RPJ 3357419
Chloromethane 11/26/09 10:100.1 1ND RPJ 3357419
cis-1,2-Dichloroethene 11/26/09 10:100.1 1ND RPJ 3357419
Dibromochloromethane 11/26/09 10:100.1 1ND RPJ 3357419
Dibromomethane 11/26/09 10:100.1 1ND RPJ 3357419
Dichlorodifluoromethane 11/26/09 10:100.1 1ND RPJ 3357419
Ethylbenzene 11/26/09 10:100.2 1ND RPJ 3357419
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:13 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 31
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15 (CORRELL)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-10
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:25
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/26/09 10:100.2 1ND RPJ 3357419
Isopropyl ether 11/26/09 10:100.1 1ND RPJ 3357419
Isopropylbenzene 11/26/09 10:100.2 1ND RPJ 3357419
m & p-Xylene 11/26/09 10:100.1 1ND RPJ 3357419
Methyl tert-butyl ether 11/26/09 10:100.2 1ND RPJ 3357419
Methylene chloride 11/26/09 10:100.2 1ND RPJ 3357419
Naphthalene 11/26/09 10:100.1 1ND RPJ 3357419
n-Butylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
n-Propylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
o-Xylene 11/26/09 10:100.1 1ND RPJ 3357419
p-Isopropyltoluene 11/26/09 10:100.1 1ND RPJ 3357419
sec-Butylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
Styrene 11/26/09 10:100.1 1ND RPJ 3357419
tert-Butylbenzene 11/26/09 10:100.1 1ND RPJ 3357419
Tetrachloroethene 11/26/09 10:100.2 1ND RPJ 3357419
Toluene 11/26/09 10:100.1 1ND RPJ 3357419
trans-1,2-Dichloroethene 11/26/09 10:100.1 1ND RPJ 3357419
Trichloroethene 11/26/09 10:100.1 1ND RPJ 3357419
Trichlorofluoromethane 11/26/09 10:100.1 1ND RPJ 3357419
Vinyl chloride 11/26/09 10:100.1 1ND RPJ 3357419
Surr: 1,2-Dichloroethane-d4 11/26/09 10:10% 60-140 193.1 RPJ 3357419
Surr: 4-Bromofluorobenzene 11/26/09 10:10% 60-140 198.7 RPJ 3357419
Surr: Toluene-d8 11/26/09 10:10% 60-140 198.2 RPJ 3357419
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 7:44301ND SRA 3358882
C9-C10 Aromatics 11/26/09 7:44101ND SRA 3358862
C9-C12 Aliphatics 11/26/09 7:44351ND SRA 3358882
Surr: 2,5-Dibromotoluene 11/26/09 7:44% 70-130 1105 SRA 3358882
Surr: 2,5-Dibromotoluene 11/26/09 7:44% 70-130 1103 SRA 3358862
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:14 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 32
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16 (CEN HOUR)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-11
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:40
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 11/24/09 1:010.022 1ND DF 3355577
Surr: 1-Chloro-2-fluorobenzene 11/24/09 1:01% 33-151 1114 DF 3355577
Prep Method Prep Date Prep Initials Prep Factor
11/23/2009 19:08 JTE504 1.10
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:15 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 33
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16 (CEN HOUR)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-11
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:40
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 11/30/09 23:470.2 1ND NDG 3360230
1,1,1-Trichloroethane 11/30/09 23:470.1 1ND NDG 3360230
1,1,2,2-Tetrachloroethane 11/30/09 23:470.1 1ND NDG 3360230
1,1,2-Trichloroethane 11/30/09 23:470.1 1ND NDG 3360230
1,1-Dichloroethane 11/30/09 23:470.1 1ND NDG 3360230
1,1-Dichloroethene 11/30/09 23:470.1 1ND NDG 3360230
1,1-Dichloropropene 11/30/09 23:470.1 1ND NDG 3360230
1,2,3-Trichlorobenzene 11/30/09 23:470.2 1ND NDG 3360230
1,2,3-Trichloropropane 11/30/09 23:470.1 1ND NDG 3360230
1,2,4-Trichlorobenzene 11/30/09 23:470.2 1ND NDG 3360230
1,2,4-Trimethylbenzene 11/30/09 23:470.1 19.6 NDG 3360230
1,2-Dibromo-3-chloropropane 11/30/09 23:470.5 1ND NDG 3360230
1,2-Dibromoethane 11/30/09 23:470.1 1ND NDG 3360230
1,2-Dichlorobenzene 11/30/09 23:470.1 1ND NDG 3360230
1,2-Dichloroethane 11/30/09 23:470.2 1ND NDG 3360230
1,2-Dichloropropane 11/30/09 23:470.1 1ND NDG 3360230
1,3,5-Trimethylbenzene 11/30/09 23:470.1 12.2 NDG 3360230
1,3-Dichlorobenzene 11/30/09 23:470.2 1ND NDG 3360230
1,3-Dichloropropane 11/30/09 23:470.1 1ND NDG 3360230
1,4-Dichlorobenzene 11/30/09 23:470.2 1ND NDG 3360230
2,2-Dichloropropane 11/30/09 23:470.1 1ND NDG 3360230
2-Chlorotoluene 11/30/09 23:470.2 1ND NDG 3360230
4-Chlorotoluene 11/30/09 23:470.2 1ND NDG 3360230
Benzene 11/30/09 23:470.1 112 NDG 3360230
Bromobenzene 11/30/09 23:470.1 1ND NDG 3360230
Bromochloromethane 11/30/09 23:470.1 1ND NDG 3360230
Bromodichloromethane 11/30/09 23:470.1 1ND NDG 3360230
Bromoform 11/30/09 23:470.1 1ND NDG 3360230
Bromomethane 11/30/09 23:470.1 1ND NDG 3360230
Carbon tetrachloride 11/30/09 23:470.1 1ND NDG 3360230
Chlorobenzene 11/30/09 23:470.2 1ND NDG 3360230
Chloroethane 11/30/09 23:470.2 1ND NDG 3360230
Chloroform 11/30/09 23:470.1 1ND NDG 3360230
Chloromethane 11/30/09 23:470.1 1ND NDG 3360230
cis-1,2-Dichloroethene 11/30/09 23:470.1 1ND NDG 3360230
Dibromochloromethane 11/30/09 23:470.1 1ND NDG 3360230
Dibromomethane 11/30/09 23:470.1 1ND NDG 3360230
Dichlorodifluoromethane 11/30/09 23:470.1 1ND NDG 3360230
Ethylbenzene 11/30/09 23:470.2 116 NDG 3360230
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:15 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 34
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16 (CEN HOUR)
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:09110761-11
Dil. Factor AnalystQUAL Seq. #
Collected:11/17/2009 15:40
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 11/30/09 23:470.2 1ND NDG 3360230
Isopropyl ether 11/30/09 23:470.1 1ND NDG 3360230
Isopropylbenzene 11/30/09 23:470.2 10.5 NDG 3360230
m & p-Xylene 11/30/09 23:470.1 154 NDG 3360230
Methyl tert-butyl ether 11/30/09 23:470.2 1ND NDG 3360230
Methylene chloride 11/30/09 23:470.2 1ND NDG 3360230
Naphthalene 11/30/09 23:470.1 12.7 NDG 3360230
n-Butylbenzene 11/30/09 23:470.1 1ND NDG 3360230
n-Propylbenzene 11/30/09 23:470.1 11.1 NDG 3360230
o-Xylene 11/30/09 23:470.1 127 NDG 3360230
p-Isopropyltoluene 11/30/09 23:470.1 1ND NDG 3360230
sec-Butylbenzene 11/30/09 23:470.1 1ND NDG 3360230
Styrene 11/30/09 23:470.1 10.46 NDG 3360230
tert-Butylbenzene 11/30/09 23:470.1 1ND NDG 3360230
Tetrachloroethene 11/30/09 23:470.2 1ND NDG 3360230
Toluene 11/30/09 23:470.1 1170 NDG 3360230
trans-1,2-Dichloroethene 11/30/09 23:470.1 1ND NDG 3360230
Trichloroethene 11/30/09 23:470.1 1ND NDG 3360230
Trichlorofluoromethane 11/30/09 23:470.1 1ND NDG 3360230
Vinyl chloride 11/30/09 23:470.1 1ND NDG 3360230
Surr: 1,2-Dichloroethane-d4 11/30/09 23:47% 60-140 1101 NDG 3360230
Surr: 4-Bromofluorobenzene 11/30/09 23:47% 60-140 1100 NDG 3360230
Surr: Toluene-d8 11/30/09 23:47% 60-140 1104 NDG 3360230
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 11/26/09 8:19301440 SRA 3358883
C9-C10 Aromatics 11/26/09 8:1910180 SRA 3358863
C9-C12 Aliphatics 11/26/09 8:19351220 SRA 3358883
Surr: 2,5-Dibromotoluene 11/26/09 8:19% 70-130 1115 SRA 3358883
Surr: 2,5-Dibromotoluene 11/26/09 8:19% 70-130 1112 SRA 3358863
Qualifiers:
B/V - Analyte detected in the associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/1/2009 2:21:16 PM
J - Estimated Value between MDL and PQL
MI - Matrix Interference
09110761 Page 35
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Documentation
12/1/2009 2:21:16 PM
09110761 Page 36
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:85111
WorkOrder:09110761
Method:E504.1
Analysis:METHOD 504.1
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/23/2009 20:36
Preparation Date:11/23/2009 12:08
Analyst:DF
Prep By:JT Method:E504
RunID:PCBB_091123B-3355564 Units:ug/L
1,2-Dibromoethane 0.570 0.639 112 60 1400.570 0.585 103 8.8 30
Surr: 1-Chloro-2-fluorobenzene 143 178 124 33 1511431611139.8 30
Analyte Result Rep Limit
Method Blank
Analysis Date:11/23/2009 20:16
Preparation Date:11/23/2009 12:08
Analyst:DF
RunID:PCBB_091123B-3355563 Units:ug/L
Prep By:JT Method:E504
1,2-Dibromoethane 0.020ND
Surr: 1-Chloro-2-fluorobenzene 33-15197.3
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-01B MW-1
09110761-02B MW-2
09110761-03B MW-3
09110761-04B MW-4
09110761-05B MW-5
09110761-06B MW-6
09110761-07B MW-7
09110761-08B MW-8
09110761-09B DMW-1
09110761-10B PW-15 (CORRELL)
09110761-11B PW-16 (CEN HOUR)
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:22 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 37
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221671
WorkOrder:09110761
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/25/2009 22:30 Analyst:SRA
RunID:HPEE_091125B-3358850 Units:ug/L
C9-C10 Aromatics 80.0 69.4 86.7 70 13080.0 61.7 77.1 11.7 20
Surr: 2,5-Dibromotoluene 200 211 105 70 13020018190.3 15.5 30
Analyte Result Rep Limit
Method Blank
Analysis Date:11/25/2009 21:21 Analyst:SRA
RunID:HPEE_091125B-3358849 Units:ug/L
C9-C10 Aromatics 10ND
Surr: 2,5-Dibromotoluene 70-13098.7
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-01A MW-1
09110761-02A MW-2
09110761-03A MW-3
09110761-04A MW-4
09110761-05A MW-5
09110761-06A MW-6
09110761-07A MW-7
09110761-09A DMW-1
09110761-10A PW-15 (CORRELL)
09110761-11A PW-16 (CEN HOUR)
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:22 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 38
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221672
WorkOrder:09110761
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/25/2009 22:30 Analyst:SRA
RunID:HPEE_091125C-3358870 Units:ug/L
C5-C8 Aliphatics 300 265 88.4 70 13030025886.0 2.7 20
C9-C12 Aliphatics 280 241 86.2 70 13028023684.2 2.3 20
Surr: 2,5-Dibromotoluene 200 212 106 70 13020018291.2 15.2 30
Analyte Result Rep Limit
Method Blank
Analysis Date:11/25/2009 21:21 Analyst:SRA
RunID:HPEE_091125C-3358869 Units:ug/L
C5-C8 Aliphatics 30ND
C9-C12 Aliphatics 35ND Surr: 2,5-Dibromotoluene 70-13099.4
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-01A MW-1
09110761-02A MW-2
09110761-03A MW-3
09110761-04A MW-4
09110761-05A MW-5
09110761-06A MW-6
09110761-07A MW-7
09110761-09A DMW-1
09110761-10A PW-15 (CORRELL)
09110761-11A PW-16 (CEN HOUR)
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:23 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 39
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221691
WorkOrder:09110761
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/29/2009 2:32 Analyst:SRA
RunID:HPEE_091128A-3359213 Units:ug/L
C9-C10 Aromatics 80.0 64.8 81.0 70 13080.0 73.1 91.4 12.1 20
Surr: 2,5-Dibromotoluene 200 177 88.6 70 13020020110012.4 30
Analyte Result Rep Limit
Method Blank
Analysis Date:11/29/2009 1:21 Analyst:SRA
RunID:HPEE_091128A-3359212 Units:ug/L
C9-C10 Aromatics 10ND
Surr: 2,5-Dibromotoluene 70-130108.5
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-08A MW-8
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:23 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 40
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221692
WorkOrder:09110761
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/29/2009 2:32 Analyst:SRA
RunID:HPEE_091128B-3359220 Units:ug/L
C5-C8 Aliphatics 300 279 93.1 70 13030028996.4 3.5 20
C9-C12 Aliphatics 280 234 83.5 70 13028024487.0 4.2 20
Surr: 2,5-Dibromotoluene 200 180 90.2 70 13020020410212.3 30
Analyte Result Rep Limit
Method Blank
Analysis Date:11/29/2009 1:21 Analyst:SRA
RunID:HPEE_091128B-3359219 Units:ug/L
C5-C8 Aliphatics 30ND
C9-C12 Aliphatics 35ND Surr: 2,5-Dibromotoluene 70-130109.2
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-07A MW-7
09110761-08A MW-8
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:24 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 41
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:84990
WorkOrder:09110761
Method:SW6010B
Analysis:Total Metals by Method 6010B - water
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte MS Spike
Added
MSDResult MSD % Recovery RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult Low Limit High LimitMSResultMS % Recovery
Sample Spiked:09110761-01
MSD Spike
Added
Analysis Date:11/19/2009 20:08
Preparation Date:11/18/2009 15:15
Analyst:SVW
Prep By:SA Method:M3030-C
RunID:ICPDV_091119E-3350883 Units:mg/L
Lead 1 1.096 94.75 75 1250.1488 200.58131.090 94.11 1
Analyte Spike
Added
Result Percent
Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample (LCS)
Analysis Date:11/19/2009 19:52
Preparation Date:11/18/2009 15:15
Analyst:SVW
Prep By:SA Method:M3030-C
RunID:ICPDV_091119E-3350880 Units:mg/L
Lead 1.000 0.9880 98.80 80 120
Analyte Result Rep Limit
Method Blank
Analysis Date:11/19/2009 19:46
Preparation Date:11/18/2009 15:15
Analyst:SVW
RunID:ICPDV_091119E-3350879 Units:mg/L
Prep By:SA Method:M3030-C
Lead 0.01ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-01C MW-1
09110761-02C MW-2
09110761-03C MW-3
09110761-04C MW-4
09110761-05C MW-5
09110761-06C MW-6
09110761-07C MW-7
09110761-08C MW-8
09110761-09C DMW-1
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:24 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 42
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221590
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:11/26/2009 4:19 Analyst:RPJ
RunID:IA_091125B-3357410 Units:ug/L
1,1,1,2-Tetrachloroethane 0.20ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.20ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 0.50ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.20ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.20ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.20ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.20ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.20ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-03A MW-3
09110761-07A MW-7
09110761-08A MW-8
09110761-09A DMW-1
09110761-10A PW-15 (CORRELL)
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:25 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 43
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221590
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/26/2009 2:22 Analyst:RPJ
RunID:IA_091125B-3357408 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 20.4 102 60 14020.0 19.3 96.7 5.5 20
1,1,1-Trichloroethane 20.0 20.9 104 60 14020.0 19.5 97.3 6.9 20
1,1,2,2-Tetrachloroethane 20.0 22.0 110 60 14020.0 21.1 106 3.9 20
1,1,2-Trichloroethane 20.0 22.1 111 60 14020.0 20.9 105 5.6 20
1,1-Dichloroethane 20.0 22.4 112 60 14020.0 21.2 106 5.7 20
1,1-Dichloroethene 20.0 22.9 114 60 14020.0 21.6 108 5.7 20
1,1-Dichloropropene 20.0 21.5 108 60 14020.0 20.3 101 6.0 20
1,2,3-Trichlorobenzene 20.0 22.8 114 60 14020.0 21.7 108 4.9 20
1,2,3-Trichloropropane 20.0 20.7 104 60 14020.0 20.6 103 0.5 20
1,2,4-Trichlorobenzene 20.0 21.8 109 60 14020.0 20.5 103 6.1 20
1,2,4-Trimethylbenzene 20.0 23.7 119 60 14020.0 22.2 111 6.7 20
1,2-Dibromo-3-chloropropane 20.0 18.4 92.2 60 14020.0 17.9 89.4 3.1 20
Analyte Result Rep Limit
Method Blank
Analysis Date:11/26/2009 4:19 Analyst:RPJ
RunID:IA_091125B-3357410 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14095.2 Surr: 4-Bromofluorobenzene 60-14098.5
Surr: Toluene-d8 60-140100.9
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:25 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 44
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221590
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/26/2009 2:22 Analyst:RPJ
RunID:IA_091125B-3357408 Units:ug/L
1,2-Dibromoethane 20.0 21.8 109 60 14020.0 21.5 108 1.4 20
1,2-Dichlorobenzene 20.0 21.2 106 60 14020.0 19.9 99.5 6.3 20
1,2-Dichloroethane 20.0 20.6 103 60 14020.0 19.9 99.6 3.6 20
1,2-Dichloropropane 20.0 20.3 101 60 14020.0 19.4 96.8 4.5 20
1,3,5-Trimethylbenzene 20.0 23.2 116 60 14020.0 21.5 108 7.5 20
1,3-Dichlorobenzene 20.0 22.0 110 60 14020.0 20.4 102 7.6 20
1,3-Dichloropropane 20.0 20.8 104 60 14020.0 20.1 100 3.6 20
1,4-Dichlorobenzene 20.0 21.3 106 60 14020.0 20.0 100 6.1 20
2,2-Dichloropropane 20.0 17.1 85.6 60 14020.0 16.0 80.2 6.6 20
2-Chlorotoluene 20.0 21.1 105 60 14020.0 19.6 98.2 7.0 20
4-Chlorotoluene 20.0 22.2 111 60 14020.0 20.2 101 9.8 20
Benzene 20.0 21.6 108 60 14020.0 20.6 103 4.7 20
Bromobenzene 20.0 21.3 107 60 14020.0 20.4 102 4.3 20
Bromochloromethane 20.0 21.0 105 60 14020.0 19.8 99.1 5.9 20
Bromodichloromethane 20.0 21.0 105 60 14020.0 19.9 99.4 5.3 20
Bromoform 20.0 23.0 115 60 14020.0 22.0 110 4.6 20
Bromomethane 20.0 21.1 105 60 14020.0 20.7 103 1.8 20
Carbon tetrachloride 20.0 21.1 105 60 14020.0 19.4 97.1 8.2 20
Chlorobenzene 20.0 20.0 100 60 14020.0 19.4 96.8 3.5 20
Chloroethane 20.0 14.8 74.0 60 14020.0 15.0 74.9 1.2 20
Chloroform 20.0 20.9 104 60 14020.0 19.7 98.6 5.7 20
Chloromethane 20.0 20.7 103 60 14020.0 18.9 94.6 8.9 20
cis-1,2-Dichloroethene 20.0 21.2 106 60 14020.0 19.6 97.9 8.0 20
Dibromochloromethane 20.0 22.4 112 60 14020.0 21.7 108 3.4 20
Dibromomethane 20.0 20.8 104 60 14020.0 19.7 98.7 5.2 20
Dichlorodifluoromethane 20.0 18.7 93.4 60 14020.0 17.6 88.1 5.9 20
Ethylbenzene 20.0 20.5 102 60 14020.0 19.6 98.1 4.2 20
Hexachlorobutadiene 20.0 22.6 113 60 14020.0 20.8 104 8.1 20
Isopropyl ether 20.0 21.6 108 60 14020.0 20.3 102 6.1 20
Isopropylbenzene 20.0 21.1 106 60 14020.0 20.2 101 4.4 20
m & p-Xylene 40.0 40.7 102 60 14040.0 38.8 97.1 4.6 20
Methyl tert-butyl ether 20.0 18.0 89.8 60 14020.0 17.5 87.6 2.5 20
Methylene chloride 20.0 20.9 105 60 14020.0 20.1 100 4.1 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:25 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 45
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221590
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/26/2009 2:22 Analyst:RPJ
RunID:IA_091125B-3357408 Units:ug/L
Naphthalene 20.0 22.2 111 60 14020.0 20.7 103 7.2 20
n-Butylbenzene 20.0 21.9 109 60 14020.0 20.4 102 7.1 20
n-Propylbenzene 20.0 21.9 110 60 14020.0 20.6 103 6.0 20
o-Xylene 20.0 21.3 107 60 14020.0 20.6 103 3.5 20
p-Isopropyltoluene 20.0 22.1 110 60 14020.0 20.8 104 6.0 20
sec-Butylbenzene 20.0 22.2 111 60 14020.0 20.5 103 7.8 20
Styrene 20.0 21.3 107 60 14020.0 20.4 102 4.6 20
tert-Butylbenzene 20.0 22.2 111 60 14020.0 20.9 105 5.7 20
Tetrachloroethene 20.0 21.8 109 60 14020.0 21.2 106 3.2 20
Toluene 20.0 21.5 108 60 14020.0 20.7 103 3.9 20
trans-1,2-Dichloroethene 20.0 22.4 112 60 14020.0 20.6 103 8.5 20
Trichloroethene 20.0 21.4 107 60 14020.0 20.6 103 3.6 20
Trichlorofluoromethane 20.0 20.4 102 60 14020.0 19.1 95.5 6.5 20
Vinyl chloride 20.0 19.5 97.3 60 14020.0 19.2 95.9 1.4 20
Surr: 1,2-Dichloroethane-d4 10.0 9.26 92.6 60 14010.0 9.55 95.5 3.1 20
Surr: 4-Bromofluorobenzene 10.0 9.82 98.2 60 14010.0 10.1 101 2.5 20
Surr: Toluene-d8 10.0 10.0 100 60 14010.0 10.2 102 1.6 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:25 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 46
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221592
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:11/27/2009 19:02 Analyst:RPJ
RunID:IA_091127A-3357452 Units:ug/L
1,1,1,2-Tetrachloroethane 0.20ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.20ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 0.50ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.20ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.20ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.20ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.20ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.20ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-04A MW-4
09110761-05A MW-5
09110761-07A MW-7
09110761-08A MW-8
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:26 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 47
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221592
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/27/2009 17:05 Analyst:RPJ
RunID:IA_091127A-3357450 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 18.4 92.2 60 14020.0 19.6 97.9 6.0 20
1,1,1-Trichloroethane 20.0 18.1 90.4 60 14020.0 20.2 101 10.9 20
1,1,2,2-Tetrachloroethane 20.0 18.2 91.1 60 14020.0 19.2 95.8 5.0 20
1,1,2-Trichloroethane 20.0 18.8 93.8 60 14020.0 20.3 102 8.0 20
1,1-Dichloroethane 20.0 18.9 94.6 60 14020.0 21.2 106 11.6 20
1,1-Dichloroethene 20.0 19.8 98.8 60 14020.0 22.2 111 11.7 20
1,1-Dichloropropene 20.0 18.5 92.6 60 14020.0 21.0 105 12.6 20
1,2,3-Trichlorobenzene 20.0 19.5 97.7 60 14020.0 20.4 102 4.6 20
1,2,3-Trichloropropane 20.0 17.6 87.9 60 14020.0 18.4 92.0 4.6 20
1,2,4-Trichlorobenzene 20.0 19.5 97.3 60 14020.0 20.3 101 4.0 20
1,2,4-Trimethylbenzene 20.0 21.6 108 60 14020.0 23.1 115 6.4 20
1,2-Dibromo-3-chloropropane 20.0 15.4 77.1 60 14020.0 15.6 78.0 1.1 20
Analyte Result Rep Limit
Method Blank
Analysis Date:11/27/2009 19:02 Analyst:RPJ
RunID:IA_091127A-3357452 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14085.8 Surr: 4-Bromofluorobenzene 60-14097.2
Surr: Toluene-d8 60-14099.0
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:26 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 48
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221592
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/27/2009 17:05 Analyst:RPJ
RunID:IA_091127A-3357450 Units:ug/L
1,2-Dibromoethane 20.0 19.4 97.0 60 14020.0 20.7 104 6.7 20
1,2-Dichlorobenzene 20.0 18.8 94.1 60 14020.0 20.0 99.8 5.8 20
1,2-Dichloroethane 20.0 17.5 87.4 60 14020.0 18.6 92.8 6.1 20
1,2-Dichloropropane 20.0 17.5 87.7 60 14020.0 19.0 95.1 8.2 20
1,3,5-Trimethylbenzene 20.0 21.0 105 60 14020.0 22.9 114 8.4 20
1,3-Dichlorobenzene 20.0 19.5 97.3 60 14020.0 20.8 104 6.9 20
1,3-Dichloropropane 20.0 18.3 91.6 60 14020.0 20.0 99.9 8.7 20
1,4-Dichlorobenzene 20.0 19.0 95.2 60 14020.0 20.4 102 6.8 20
2,2-Dichloropropane 20.0 18.8 94.2 60 14020.0 21.1 105 11.1 20
2-Chlorotoluene 20.0 19.2 95.8 60 14020.0 20.7 103 7.5 20
4-Chlorotoluene 20.0 19.7 98.3 60 14020.0 21.1 105 7.0 20
Benzene 20.0 19.8 98.8 60 14020.0 21.3 107 7.7 20
Bromobenzene 20.0 19.3 96.3 60 14020.0 20.4 102 5.8 20
Bromochloromethane 20.0 17.2 85.9 60 14020.0 18.9 94.6 9.6 20
Bromodichloromethane 20.0 18.1 90.5 60 14020.0 19.1 95.3 5.1 20
Bromoform 20.0 19.7 98.7 60 14020.0 21.1 106 6.8 20
Bromomethane 20.0 17.5 87.7 60 14020.0 20.3 102 14.8 20
Carbon tetrachloride 20.0 18.1 90.4 60 14020.0 20.2 101 11.3 20
Chlorobenzene 20.0 18.6 92.9 60 14020.0 20.4 102 9.4 20
Chloroethane 20.0 12.7 63.4 60 14020.0 15.3 76.4 18.7 20
Chloroform 20.0 17.9 89.5 60 14020.0 20.0 100 11.1 20
Chloromethane 20.0 17.3 86.7 60 14020.0 19.2 96.0 10.2 20
cis-1,2-Dichloroethene 20.0 18.4 92.0 60 14020.0 20.3 102 9.9 20
Dibromochloromethane 20.0 19.7 98.4 60 14020.0 21.2 106 7.2 20
Dibromomethane 20.0 17.7 88.5 60 14020.0 18.5 92.5 4.4 20
Dichlorodifluoromethane 20.0 14.5 72.7 60 14020.0 16.6 82.8 13.0 20
Ethylbenzene 20.0 19.1 95.5 60 14020.0 20.8 104 8.6 20
Hexachlorobutadiene 20.0 22.2 111 60 14020.0 23.3 116 4.8 20
Isopropyl ether 20.0 17.6 87.8 60 14020.0 19.2 95.9 8.8 20
Isopropylbenzene 20.0 19.8 98.8 60 14020.0 21.7 108 9.1 20
m & p-Xylene 40.0 38.5 96.3 60 14040.0 41.4 103 7.2 20
Methyl tert-butyl ether 20.0 21.0 105 60 14020.0 22.6 113 7.6 20
Methylene chloride 20.0 17.4 87.1 60 14020.0 19.5 97.6 11.4 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:26 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 49
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221592
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/27/2009 17:05 Analyst:RPJ
RunID:IA_091127A-3357450 Units:ug/L
Naphthalene 20.0 18.6 92.8 60 14020.0 19.1 95.5 2.9 20
n-Butylbenzene 20.0 20.0 100 60 14020.0 22.0 110 9.6 20
n-Propylbenzene 20.0 20.1 100 60 14020.0 21.9 110 8.7 20
o-Xylene 20.0 19.6 97.8 60 14020.0 21.2 106 8.0 20
p-Isopropyltoluene 20.0 20.1 101 60 14020.0 21.8 109 8.0 20
sec-Butylbenzene 20.0 20.6 103 60 14020.0 21.9 110 6.4 20
Styrene 20.0 19.3 96.6 60 14020.0 21.1 105 8.7 20
tert-Butylbenzene 20.0 20.4 102 60 14020.0 22.1 110 7.7 20
Tetrachloroethene 20.0 21.5 107 60 14020.0 23.2 116 7.5 20
Toluene 20.0 20.2 101 60 14020.0 22.0 110 8.5 20
trans-1,2-Dichloroethene 20.0 19.0 95.1 60 14020.0 21.4 107 11.7 20
Trichloroethene 20.0 20.0 99.9 60 14020.0 21.8 109 8.5 20
Trichlorofluoromethane 20.0 16.3 81.3 60 14020.0 18.6 92.8 13.2 20
Vinyl chloride 20.0 16.0 80.1 60 14020.0 18.6 92.8 14.6 20
Surr: 1,2-Dichloroethane-d4 10.0 8.23 82.3 60 14010.0 8.22 82.2 0.1 20
Surr: 4-Bromofluorobenzene 10.0 9.98 99.8 60 14010.0 10.2 102 1.8 20
Surr: Toluene-d8 10.0 10.1 101 60 14010.0 9.70 97.0 3.9 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:26 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 50
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221608
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:11/28/2009 8:01 Analyst:RPJ
RunID:IA_091127B-3358203 Units:ug/L
1,1,1,2-Tetrachloroethane 0.20ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.20ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 0.50ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.20ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.20ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.20ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.20ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.20ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-01A MW-1
09110761-02A MW-2
09110761-06A MW-6
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:27 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 51
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221608
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/28/2009 6:05 Analyst:RPJ
RunID:IA_091127B-3358201 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 20.4 102 60 14020.0 19.6 97.8 4.1 20
1,1,1-Trichloroethane 20.0 21.8 109 60 14020.0 20.2 101 7.9 20
1,1,2,2-Tetrachloroethane 20.0 20.0 99.9 60 14020.0 19.5 97.4 2.6 20
1,1,2-Trichloroethane 20.0 21.4 107 60 14020.0 21.1 105 1.5 20
1,1-Dichloroethane 20.0 23.6 118 60 14020.0 22.2 111 6.1 20
1,1-Dichloroethene 20.0 23.5 117 60 14020.0 22.6 113 4.0 20
1,1-Dichloropropene 20.0 22.3 111 60 14020.0 21.2 106 4.7 20
1,2,3-Trichlorobenzene 20.0 22.2 111 60 14020.0 21.6 108 3.0 20
1,2,3-Trichloropropane 20.0 19.8 98.9 60 14020.0 19.5 97.7 1.3 20
1,2,4-Trichlorobenzene 20.0 21.5 107 60 14020.0 20.5 102 4.8 20
1,2,4-Trimethylbenzene 20.0 24.4 122 60 14020.0 23.3 117 4.6 20
1,2-Dibromo-3-chloropropane 20.0 18.4 91.9 60 14020.0 16.8 83.8 9.3 20
Analyte Result Rep Limit
Method Blank
Analysis Date:11/28/2009 8:01 Analyst:RPJ
RunID:IA_091127B-3358203 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14090.6 Surr: 4-Bromofluorobenzene 60-14097.9
Surr: Toluene-d8 60-140101.3
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:27 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 52
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221608
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/28/2009 6:05 Analyst:RPJ
RunID:IA_091127B-3358201 Units:ug/L
1,2-Dibromoethane 20.0 21.6 108 60 14020.0 21.0 105 3.2 20
1,2-Dichlorobenzene 20.0 20.8 104 60 14020.0 20.2 101 2.7 20
1,2-Dichloroethane 20.0 20.7 103 60 14020.0 20.2 101 2.6 20
1,2-Dichloropropane 20.0 21.1 105 60 14020.0 20.1 101 4.6 20
1,3,5-Trimethylbenzene 20.0 23.8 119 60 14020.0 22.8 114 4.4 20
1,3-Dichlorobenzene 20.0 21.9 109 60 14020.0 21.0 105 4.0 20
1,3-Dichloropropane 20.0 20.7 104 60 14020.0 20.0 100 3.3 20
1,4-Dichlorobenzene 20.0 21.0 105 60 14020.0 20.6 103 2.1 20
2,2-Dichloropropane 20.0 16.7 83.7 60 14020.0 15.3 76.3 9.3 20
2-Chlorotoluene 20.0 21.6 108 60 14020.0 20.7 103 4.5 20
4-Chlorotoluene 20.0 21.9 110 60 14020.0 21.5 108 2.0 20
Benzene 20.0 22.9 115 60 14020.0 21.8 109 4.9 20
Bromobenzene 20.0 21.4 107 60 14020.0 20.5 103 4.0 20
Bromochloromethane 20.0 20.8 104 60 14020.0 20.4 102 1.7 20
Bromodichloromethane 20.0 20.8 104 60 14020.0 20.1 101 3.2 20
Bromoform 20.0 21.6 108 60 14020.0 21.0 105 3.0 20
Bromomethane 20.0 22.4 112 60 14020.0 20.7 104 7.8 20
Carbon tetrachloride 20.0 21.6 108 60 14020.0 20.4 102 5.7 20
Chlorobenzene 20.0 20.8 104 60 14020.0 20.0 99.8 4.3 20
Chloroethane 20.0 17.1 85.4 60 14020.0 15.9 79.4 7.3 20
Chloroform 20.0 21.6 108 60 14020.0 20.6 103 4.8 20
Chloromethane 20.0 22.0 110 60 14020.0 20.2 101 8.2 20
cis-1,2-Dichloroethene 20.0 22.3 112 60 14020.0 20.8 104 6.9 20
Dibromochloromethane 20.0 22.1 111 60 14020.0 21.5 107 3.1 20
Dibromomethane 20.0 20.4 102 60 14020.0 19.9 99.4 2.5 20
Dichlorodifluoromethane 20.0 17.9 89.3 60 14020.0 17.1 85.6 4.2 20
Ethylbenzene 20.0 21.6 108 60 14020.0 20.4 102 5.6 20
Hexachlorobutadiene 20.0 24.3 122 60 14020.0 22.7 114 6.8 20
Isopropyl ether 20.0 21.5 108 60 14020.0 20.8 104 3.3 20
Isopropylbenzene 20.0 22.0 110 60 14020.0 21.0 105 5.0 20
m & p-Xylene 40.0 42.8 107 60 14040.0 40.2 101 6.2 20
Methyl tert-butyl ether 20.0 25.5 127 60 14020.0 24.7 123 3.2 20
Methylene chloride 20.0 22.0 110 60 14020.0 21.3 106 3.4 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:27 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 53
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221608
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/28/2009 6:05 Analyst:RPJ
RunID:IA_091127B-3358201 Units:ug/L
Naphthalene 20.0 20.8 104 60 14020.0 20.5 102 1.6 20
n-Butylbenzene 20.0 22.5 112 60 14020.0 21.4 107 5.1 20
n-Propylbenzene 20.0 22.6 113 60 14020.0 21.8 109 3.4 20
o-Xylene 20.0 21.9 110 60 14020.0 20.6 103 6.3 20
p-Isopropyltoluene 20.0 22.4 112 60 14020.0 21.7 108 3.3 20
sec-Butylbenzene 20.0 22.9 114 60 14020.0 22.1 110 3.4 20
Styrene 20.0 21.7 109 60 14020.0 20.7 103 5.1 20
tert-Butylbenzene 20.0 23.1 115 60 14020.0 21.7 108 6.3 20
Tetrachloroethene 20.0 23.0 115 60 14020.0 22.0 110 4.4 20
Toluene 20.0 22.4 112 60 14020.0 21.4 107 4.7 20
trans-1,2-Dichloroethene 20.0 23.9 120 60 14020.0 22.2 111 7.5 20
Trichloroethene 20.0 22.7 114 60 14020.0 21.4 107 6.0 20
Trichlorofluoromethane 20.0 20.5 102 60 14020.0 18.9 94.3 8.3 20
Vinyl chloride 20.0 20.0 100 60 14020.0 19.5 97.7 2.4 20
Surr: 1,2-Dichloroethane-d4 10.0 8.54 85.4 60 14010.0 8.97 89.7 4.9 20
Surr: 4-Bromofluorobenzene 10.0 9.81 98.1 60 14010.0 10.1 101 3.3 20
Surr: Toluene-d8 10.0 10.2 102 60 14010.0 10.2 102 0.4 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:27 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 54
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221752
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:11/30/2009 21:11 Analyst:NDG
RunID:IA_091130B-3360227 Units:ug/L
1,1,1,2-Tetrachloroethane 0.20ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.20ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 0.50ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.20ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.20ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.20ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.20ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.20ND
Hexachlorobutadiene 0.200.66
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
09110761-06A MW-6
09110761-09A DMW-1
09110761-11A PW-16 (CEN HOUR)
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:28 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 55
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221752
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/30/2009 19:13 Analyst:NDG
RunID:IA_091130B-3360225 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 17.7 88.3 60 14020.0 16.9 84.3 4.7 20
1,1,1-Trichloroethane 20.0 20.7 104 60 14020.0 19.9 99.6 3.9 20
1,1,2,2-Tetrachloroethane 20.0 18.8 93.9 60 14020.0 18.0 89.8 4.4 20
1,1,2-Trichloroethane 20.0 19.3 96.3 60 14020.0 18.7 93.3 3.2 20
1,1-Dichloroethane 20.0 23.2 116 60 14020.0 22.4 112 3.6 20
1,1-Dichloroethene 20.0 23.8 119 60 14020.0 22.1 110 7.6 20
1,1-Dichloropropene 20.0 21.9 110 60 14020.0 21.1 106 3.8 20
1,2,3-Trichlorobenzene 20.0 19.9 99.7 60 14020.0 19.5 97.3 2.4 20
1,2,3-Trichloropropane 20.0 18.8 93.9 60 14020.0 18.1 90.4 3.9 20
1,2,4-Trichlorobenzene 20.0 19.3 96.3 60 14020.0 18.8 94.0 2.3 20
1,2,4-Trimethylbenzene 20.0 22.0 110 60 14020.0 20.9 104 5.3 20
1,2-Dibromo-3-chloropropane 20.0 16.5 82.7 60 14020.0 16.7 83.6 1.1 20
Analyte Result Rep Limit
Method Blank
Analysis Date:11/30/2009 21:11 Analyst:NDG
RunID:IA_091130B-3360227 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-140103.7 Surr: 4-Bromofluorobenzene 60-14095.8
Surr: Toluene-d8 60-140102.4
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:28 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 56
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221752
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/30/2009 19:13 Analyst:NDG
RunID:IA_091130B-3360225 Units:ug/L
1,2-Dibromoethane 20.0 19.2 96.1 60 14020.0 18.4 92.1 4.3 20
1,2-Dichlorobenzene 20.0 18.9 94.5 60 14020.0 18.4 92.2 2.5 20
1,2-Dichloroethane 20.0 20.5 103 60 14020.0 20.1 100 2.2 20
1,2-Dichloropropane 20.0 20.7 103 60 14020.0 20.2 101 2.3 20
1,3,5-Trimethylbenzene 20.0 21.4 107 60 14020.0 20.8 104 3.1 20
1,3-Dichlorobenzene 20.0 19.8 98.9 60 14020.0 19.0 94.8 4.3 20
1,3-Dichloropropane 20.0 19.3 96.6 60 14020.0 17.7 88.6 8.7 20
1,4-Dichlorobenzene 20.0 19.1 95.5 60 14020.0 18.3 91.5 4.2 20
2,2-Dichloropropane 20.0 20.8 104 60 14020.0 19.6 97.9 6.1 20
2-Chlorotoluene 20.0 19.2 95.8 60 14020.0 18.0 90.2 6.0 20
4-Chlorotoluene 20.0 19.8 98.8 60 14020.0 19.2 96.1 2.7 20
Benzene 20.0 21.7 109 60 14020.0 20.9 104 4.0 20
Bromobenzene 20.0 18.7 93.3 60 14020.0 17.4 86.9 7.2 20
Bromochloromethane 20.0 21.1 106 60 14020.0 21.0 105 0.5 20
Bromodichloromethane 20.0 20.3 101 60 14020.0 19.4 97.2 4.2 20
Bromoform 20.0 19.4 96.9 60 14020.0 18.7 93.4 3.6 20
Bromomethane 20.0 22.6 113 60 14020.0 22.5 112 0.7 20
Carbon tetrachloride 20.0 20.6 103 60 14020.0 19.8 99.2 3.6 20
Chlorobenzene 20.0 18.5 92.4 60 14020.0 17.3 86.4 6.7 20
Chloroethane 20.0 17.2 86.0 60 14020.0 16.6 82.8 3.7 20
Chloroform 20.0 20.4 102 60 14020.0 19.9 99.6 2.5 20
Chloromethane 20.0 22.5 112 60 14020.0 21.2 106 5.8 20
cis-1,2-Dichloroethene 20.0 20.2 101 60 14020.0 19.6 97.8 3.4 20
Dibromochloromethane 20.0 19.0 95.0 60 14020.0 18.5 92.4 2.9 20
Dibromomethane 20.0 19.5 97.3 60 14020.0 19.0 95.2 2.3 20
Dichlorodifluoromethane 20.0 19.9 99.6 60 14020.0 20.0 100 0.4 20
Ethylbenzene 20.0 19.4 97.1 60 14020.0 18.2 91.2 6.3 20
Hexachlorobutadiene 20.0 21.8 109 60 14020.0 20.6 103 5.7 20
Isopropyl ether 20.0 21.8 109 60 14020.0 21.1 105 3.3 20
Isopropylbenzene 20.0 19.2 96.0 60 14020.0 18.3 91.4 4.9 20
m & p-Xylene 40.0 38.3 95.9 60 14040.0 35.9 89.6 6.7 20
Methyl tert-butyl ether 20.0 17.0 84.9 60 14020.0 16.8 83.9 1.2 20
Methylene chloride 20.0 21.6 108 60 14020.0 20.8 104 3.7 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:28 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 57
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID: R221752
WorkOrder:09110761
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/30/2009 19:13 Analyst:NDG
RunID:IA_091130B-3360225 Units:ug/L
Naphthalene 20.0 18.4 92.1 60 14020.0 17.8 89.0 3.5 20
n-Butylbenzene 20.0 21.1 105 60 14020.0 20.1 101 4.7 20
n-Propylbenzene 20.0 20.5 102 60 14020.0 19.6 97.8 4.6 20
o-Xylene 20.0 19.6 98.1 60 14020.0 18.6 93.2 5.1 20
p-Isopropyltoluene 20.0 20.7 104 60 14020.0 20.0 99.8 3.8 20
sec-Butylbenzene 20.0 20.7 104 60 14020.0 19.8 98.8 4.7 20
Styrene 20.0 19.0 95.2 60 14020.0 18.0 90.0 5.6 20
tert-Butylbenzene 20.0 20.7 103 60 14020.0 19.7 98.5 4.7 20
Tetrachloroethene 20.0 20.5 103 60 14020.0 19.2 95.9 6.9 20
Toluene 20.0 19.6 98.1 60 14020.0 18.5 92.4 6.0 20
trans-1,2-Dichloroethene 20.0 22.5 112 60 14020.0 21.9 109 2.7 20
Trichloroethene 20.0 20.9 104 60 14020.0 20.1 100 3.9 20
Trichlorofluoromethane 20.0 20.3 101 60 14020.0 19.8 99.1 2.2 20
Vinyl chloride 20.0 21.1 106 60 14020.0 20.4 102 3.3 20
Surr: 1,2-Dichloroethane-d4 10.0 9.73 97.3 60 14010.0 9.68 96.8 0.5 20
Surr: 4-Bromofluorobenzene 10.0 9.94 99.4 60 14010.0 9.60 96.0 3.5 20
Surr: Toluene-d8 10.0 10.5 105 60 14010.0 10.3 103 1.3 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/1/2009 2:21:28 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
09110761 Page 58
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Chain of Custody
And
Sample Receipt Checklist
12/1/2009 2:21:28 PM
09110761 Page 59
Sample Receipt Checklist
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:09110761
Date and Time Received:11/18/2009 9:30:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:4°C
Received By:S_P
SPL Representative:
Non Conformance Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
12/1/2009 2:21:29 PM
09110761 Page 60
Case Narrative for:
10071130
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
4020 OLD PINEVILLE ROAD
CHARLOTTE
NC
28217-
DIANA LANIER
Date Reported:8/25/2010
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
NOTE: THIS REPORT HAS BEEN AMENDED FROM THE ORIGINAL. THIS REPORT REPLACES IN ITS ENTIRETY ANY PREVIOUSLY SUBMITTED COPY. MW-19 has been corrected to MW-9. Field samples MW-10 and MW-12 were re-analzyed by method 6010 at 2x dilutions
for lead to achieve reporting limits within NC 2L requirements.
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for
possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike
purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS)
and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory
Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of
Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the
samples submitted for testing.
SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateAmy K. Jackson
8/25/2010
Project Manager
10071130 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
10071130
Certificate of Analysis Number:
ATC ASSOCIATES, INC.
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ATC ASSOCIATES, INC.
4020 OLD PINEVILLE ROAD
CHARLOTTE
NC
28217-
[phone]
DIANA LANIER
Date Reported:8/25/2010
Project Name:89.03451.1018
PO Number:
Site:CAJAHS MOUNTAIN SUPERETTE
State:North Carolina
State Cert. No.:487
Report To:
Site Address:
NCLENOIR
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
10071130-01 7/29/2010 9:15:00 AMMW-11 @ 25`07/27/2010 11:45Soil 316111
10071130-02 7/29/2010 9:15:00 AMSB-10 @ 20`07/27/2010 15:00Soil 316111
10071130-03 7/29/2010 9:15:00 AMSB-11 @ 25`07/27/2010 15:05Soil 316111
10071130-04 7/29/2010 9:15:00 AMSB-12 @ 15`07/27/2010 16:15Soil 316111
10071130-05 7/29/2010 9:15:00 AMSB-14 @ 25`07/27/2010 16:25Soil 316111
10071130-06 7/29/2010 9:15:00 AMSB-15 @ 25`07/28/2010 10:20Soil 316111
10071130-07 7/29/2010 9:15:00 AMMW-9 07/28/2010 14:20Water 316111
10071130-08 7/29/2010 9:15:00 AMMW-10 07/28/2010 14:45Water 316111
10071130-09 7/29/2010 9:15:00 AMMW-11 07/28/2010 11:20Water 316111
10071130-10 7/29/2010 9:15:00 AMMW-12 07/28/2010 12:00Water 316111
10071130-11 7/29/2010 9:15:00 AMDMW-2 07/28/2010 13:45Water 316111
10071130-12 7/29/2010 9:15:00 AMPW-1 07/26/2010 17:30Water 316111
10071130-13 7/29/2010 9:15:00 AMPW-2 07/26/2010 15:00Water 316111
10071130-14 7/29/2010 9:15:00 AMPW-15 07/26/2010 16:10Water 316111
10071130-15 7/29/2010 9:15:00 AMPW-16 07/26/2010 15:45Water 316111
10071130-16 7/29/2010 9:15:00 AMPW-18 07/26/2010 16:30Water 316111
Date
Laboratory Director
Quality Assurance Officer
Amy K. Jackson
10071130 Page 2
8/25/2010
8/25/2010 9:37:43 AM
Project Manager
Ron Benjamin
Tristan Davis
Client Sample ID:MW-11 @ 25`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-01
Dil. Factor AnalystQUAL Seq. #
Collected:07/27/2010 11:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 130 CCT 3681592
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 3:340.0015 1ND CDP 3688357
Diisopropyl ether 08/05/10 3:340.0076 1ND CDP 3688357
Ethylbenzene 08/05/10 3:340.0015 1ND CDP 3688357
Methyl tert-butyl ether 08/05/10 3:340.0076 1ND CDP 3688357
Naphthalene 08/05/10 3:340.0076 1ND CDP 3688357
Toluene 08/05/10 3:340.0076 1ND CDP 3688357
m,p-Xylene 08/05/10 3:340.003 1ND CDP 3688357
o-Xylene 08/05/10 3:340.0015 10.0029 CDP 3688357
Xylenes,Total 08/05/10 3:340.0015 10.0029 CDP 3688357
Surr: 1,2-Dichloroethane-d4 08/05/10 3:34% 50-166 1109 CDP 3688357
Surr: 4-Bromofluorobenzene 08/05/10 3:34% 79-123 199.7 CDP 3688357
Surr: Toluene-d8 08/05/10 3:34% 62-146 199.6 CDP 3688357
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 16:18 sjaSW5035 1.06
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 17:063.8 100ND SJA 3680394
C9-C10 Aromatics 07/29/10 17:060.64 100ND SJA 3680374
C9-C12 Aliphatics 07/29/10 17:064.5 1006.5 SJA 3680394
Surr: 2,5-Dibromotoluene 07/29/10 17:06% 70-130 100104 SJA 3680374
Surr: 2,5-Dibromotoluene 07/29/10 17:06% 70-130 100102 SJA 3680394
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 11:45 FieldMA_VPH 0.89
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:28 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 3
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-10 @ 20`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-02
Dil. Factor AnalystQUAL Seq. #
Collected:07/27/2010 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 122 CCT 3681593
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 4:020.0012 1ND CDP 3688358
Diisopropyl ether 08/05/10 4:020.0058 1ND CDP 3688358
Ethylbenzene 08/05/10 4:020.0012 1ND CDP 3688358
Methyl tert-butyl ether 08/05/10 4:020.0058 1ND CDP 3688358
Naphthalene 08/05/10 4:020.0058 1ND CDP 3688358
Toluene 08/05/10 4:020.0058 1ND CDP 3688358
m,p-Xylene 08/05/10 4:020.0023 1ND CDP 3688358
o-Xylene 08/05/10 4:020.0012 1ND CDP 3688358
Xylenes,Total 08/05/10 4:020.0012 1ND CDP 3688358
Surr: 1,2-Dichloroethane-d4 08/05/10 4:02% 50-166 1110 CDP 3688358
Surr: 4-Bromofluorobenzene 08/05/10 4:02% 79-123 199.8 CDP 3688358
Surr: Toluene-d8 08/05/10 4:02% 62-146 199.8 CDP 3688358
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 15:00 FieldSW5035 0.91
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 17:394100ND SJA 3680395
C9-C10 Aromatics 07/29/10 17:390.67 100ND SJA 3680375
C9-C12 Aliphatics 07/29/10 17:394.7 100ND SJA 3680395
Surr: 2,5-Dibromotoluene 07/29/10 17:39% 70-130 100100 SJA 3680375
Surr: 2,5-Dibromotoluene 07/29/10 17:39% 70-130 10098.7 SJA 3680395
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 15:00 FieldMA_VPH 1.04
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:29 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 4
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-11 @ 25`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-03
Dil. Factor AnalystQUAL Seq. #
Collected:07/27/2010 15:05
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 119 CCT 3681594
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 4:300.0012 1ND CDP 3688359
Diisopropyl ether 08/05/10 4:300.0062 1ND CDP 3688359
Ethylbenzene 08/05/10 4:300.0012 1ND CDP 3688359
Methyl tert-butyl ether 08/05/10 4:300.0062 1ND CDP 3688359
Naphthalene 08/05/10 4:300.0062 1ND CDP 3688359
Toluene 08/05/10 4:300.0062 1ND CDP 3688359
m,p-Xylene 08/05/10 4:300.0025 1ND CDP 3688359
o-Xylene 08/05/10 4:300.0012 1ND CDP 3688359
Xylenes,Total 08/05/10 4:300.0012 1ND CDP 3688359
Surr: 1,2-Dichloroethane-d4 08/05/10 4:30% 50-166 1117 CDP 3688359
Surr: 4-Bromofluorobenzene 08/05/10 4:30% 79-123 199.0 CDP 3688359
Surr: Toluene-d8 08/05/10 4:30% 62-146 1101 CDP 3688359
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 15:05 FieldMA_VPH 1.00
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 18:113.8 100ND SJA 3680396
C9-C10 Aromatics 07/29/10 18:110.63 1001.2 SJA 3680376
C9-C12 Aliphatics 07/29/10 18:114.4 1004.9 SJA 3680396
Surr: 2,5-Dibromotoluene 07/29/10 18:11% 70-130 10094.5 SJA 3680376
Surr: 2,5-Dibromotoluene 07/29/10 18:11% 70-130 10093.6 SJA 3680396
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 15:05 FieldMA_VPH 1.02
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:31 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 5
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-12 @ 15`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-04
Dil. Factor AnalystQUAL Seq. #
Collected:07/27/2010 16:15
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 126 CCT 3681595
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 4:580.0013 1ND CDP 3688360
Diisopropyl ether 08/05/10 4:580.0066 1ND CDP 3688360
Ethylbenzene 08/05/10 4:580.0013 1ND CDP 3688360
Methyl tert-butyl ether 08/05/10 4:580.0066 1ND CDP 3688360
Naphthalene 08/05/10 4:580.0066 1ND CDP 3688360
Toluene 08/05/10 4:580.0066 1ND CDP 3688360
m,p-Xylene 08/05/10 4:580.0026 1ND CDP 3688360
o-Xylene 08/05/10 4:580.0013 1ND CDP 3688360
Xylenes,Total 08/05/10 4:580.0013 1ND CDP 3688360
Surr: 1,2-Dichloroethane-d4 08/05/10 4:58% 50-166 1111 CDP 3688360
Surr: 4-Bromofluorobenzene 08/05/10 4:58% 79-123 199.3 CDP 3688360
Surr: Toluene-d8 08/05/10 4:58% 62-146 1108 CDP 3688360
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 16:15 FieldSW5035 0.98
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 18:434.1 100ND SJA 3680397
C9-C10 Aromatics 07/29/10 18:430.68 100ND SJA 3680377
C9-C12 Aliphatics 07/29/10 18:434.7 100ND SJA 3680397
Surr: 2,5-Dibromotoluene 07/29/10 18:43% 70-130 10094.0 SJA 3680397
Surr: 2,5-Dibromotoluene 07/29/10 18:43% 70-130 10093.7 SJA 3680377
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 16:15 FieldMA_VPH 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:32 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 6
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-14 @ 25`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-05
Dil. Factor AnalystQUAL Seq. #
Collected:07/27/2010 16:25
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 118 CCT 3681596
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 5:260.0014 1ND CDP 3688361
Diisopropyl ether 08/05/10 5:260.0069 1ND CDP 3688361
Ethylbenzene 08/05/10 5:260.0014 1ND CDP 3688361
Methyl tert-butyl ether 08/05/10 5:260.0069 1ND CDP 3688361
Naphthalene 08/05/10 5:260.0069 1ND CDP 3688361
Toluene 08/05/10 5:260.0069 1ND CDP 3688361
m,p-Xylene 08/05/10 5:260.0028 1ND CDP 3688361
o-Xylene 08/05/10 5:260.0014 1ND CDP 3688361
Xylenes,Total 08/05/10 5:260.0014 1ND CDP 3688361
Surr: 1,2-Dichloroethane-d4 08/05/10 5:26% 50-166 1108 CDP 3688361
Surr: 4-Bromofluorobenzene 08/05/10 5:26% 79-123 1100 CDP 3688361
Surr: Toluene-d8 08/05/10 5:26% 62-146 198.8 CDP 3688361
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 16:25 FieldSW5035 1.14
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 19:154.1 100ND SJA 3680398
C9-C10 Aromatics 07/29/10 19:150.68 100ND SJA 3680378
C9-C12 Aliphatics 07/29/10 19:154.7 100ND SJA 3680398
Surr: 2,5-Dibromotoluene 07/29/10 19:15% 70-130 10092.7 SJA 3680398
Surr: 2,5-Dibromotoluene 07/29/10 19:15% 70-130 10092.3 SJA 3680378
Prep Method Prep Date Prep Initials Prep Factor
07/27/2010 16:25 FieldMA_VPH 1.11
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:34 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 7
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:SB-15 @ 25`
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-06
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 10:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
PERCENT MOISTURE D2216 wt%Units:MCL
Percent Moisture 07/30/10 7:530.1 129 CCT 3681597
VOLATILE ORGANICS METHOD 8260B SW8260B mg/Kg-dryUnits:MCL
Benzene 08/05/10 5:540.0015 10.002 CDP 3688362
Diisopropyl ether 08/05/10 5:540.0073 1ND CDP 3688362
Ethylbenzene 08/05/10 5:540.0015 1ND CDP 3688362
Methyl tert-butyl ether 08/05/10 5:540.0073 1ND CDP 3688362
Naphthalene 08/05/10 5:540.0073 1ND CDP 3688362
Toluene 08/05/10 5:540.0073 1ND CDP 3688362
m,p-Xylene 08/05/10 5:540.0029 1ND CDP 3688362
o-Xylene 08/05/10 5:540.0015 10.012 CDP 3688362
Xylenes,Total 08/05/10 5:540.0015 10.012 CDP 3688362
Surr: 1,2-Dichloroethane-d4 08/05/10 5:54% 50-166 1125 CDP 3688362
Surr: 4-Bromofluorobenzene 08/05/10 5:54% 79-123 1103 CDP 3688362
Surr: Toluene-d8 08/05/10 5:54% 62-146 1101 CDP 3688362
Prep Method Prep Date Prep Initials Prep Factor
07/28/2010 10:20 FieldSW5035 1.04
VOLATILE PETROLEUM HYDROCARBONS (SOIL)MA_VPH_EPH mg/Kg-dryUnits:MCL
C5-C8 Aliphatics 07/29/10 19:464.1 100ND SJA 3680399
C9-C10 Aromatics 07/29/10 19:460.69 100ND SJA 3680379
C9-C12 Aliphatics 07/29/10 19:464.8 100ND SJA 3680399
Surr: 2,5-Dibromotoluene 07/29/10 19:46% 70-130 10090.5 SJA 3680399
Surr: 2,5-Dibromotoluene 07/29/10 19:46% 70-130 10090.1 SJA 3680379
Prep Method Prep Date Prep Initials Prep Factor
07/28/2010 10:20 FieldMA_VPH 0.98
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:35 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 8
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-9
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-07
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 18:080.021 1ND RAH 3683668
Surr: 1-Chloro-2-fluorobenzene 07/30/10 18:08% 33-151 1115 RAH 3683668
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.06
TOTAL METALS BY METHOD 6010B - WATER SW6010B ug/LUnits:MCL
Lead 07/30/10 13:0110123.7 SVW 3681669
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 14:00 SAM3030-C 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:37 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 9
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-9
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-07
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 16:570.1 1ND TDD 3688642
1,1,1-Trichloroethane 08/05/10 16:570.1 1ND TDD 3688642
1,1,2,2-Tetrachloroethane 08/05/10 16:570.1 1ND TDD 3688642
1,1,2-Trichloroethane 08/05/10 16:570.1 1ND TDD 3688642
1,1-Dichloroethane 08/05/10 16:570.1 1ND TDD 3688642
1,1-Dichloroethene 08/05/10 16:570.1 1ND TDD 3688642
1,1-Dichloropropene 08/05/10 16:570.1 1ND TDD 3688642
1,2,3-Trichlorobenzene 08/05/10 16:570.2 1ND TDD 3688642
1,2,3-Trichloropropane 08/05/10 16:570.1 1ND TDD 3688642
1,2,4-Trichlorobenzene 08/05/10 16:570.1 1ND TDD 3688642
1,2,4-Trimethylbenzene 08/05/10 16:570.1 1ND TDD 3688642
1,2-Dibromo-3-chloropropane 08/05/10 16:5711ND TDD 3688642
1,2-Dibromoethane 08/05/10 16:570.1 1ND TDD 3688642
1,2-Dichlorobenzene 08/05/10 16:570.1 1ND TDD 3688642
1,2-Dichloroethane 08/05/10 16:570.2 1ND TDD 3688642
1,2-Dichloropropane 08/05/10 16:570.1 1ND TDD 3688642
1,3,5-Trimethylbenzene 08/05/10 16:570.1 1ND TDD 3688642
1,3-Dichlorobenzene 08/05/10 16:570.1 1ND TDD 3688642
1,3-Dichloropropane 08/05/10 16:570.1 1ND TDD 3688642
1,4-Dichlorobenzene 08/05/10 16:570.1 1ND TDD 3688642
2,2-Dichloropropane 08/05/10 16:570.1 1ND TDD 3688642
2-Chlorotoluene 08/05/10 16:570.2 1ND TDD 3688642
4-Chlorotoluene 08/05/10 16:570.1 1ND TDD 3688642
Benzene 08/05/10 16:570.1 1ND TDD 3688642
Bromobenzene 08/05/10 16:570.1 1ND TDD 3688642
Bromochloromethane 08/05/10 16:570.1 1ND TDD 3688642
Bromodichloromethane 08/05/10 16:570.1 1ND TDD 3688642
Bromoform 08/05/10 16:570.1 1ND TDD 3688642
Bromomethane 08/05/10 16:570.2 1ND TDD 3688642
Carbon tetrachloride 08/05/10 16:570.1 1ND TDD 3688642
Chlorobenzene 08/05/10 16:570.1 1ND TDD 3688642
Chloroethane 08/05/10 16:570.2 1ND TDD 3688642
Chloroform 08/05/10 16:570.1 1ND TDD 3688642
Chloromethane 08/05/10 16:570.1 1ND TDD 3688642
cis-1,2-Dichloroethene 08/05/10 16:570.1 1ND TDD 3688642
Dibromochloromethane 08/05/10 16:570.1 1ND TDD 3688642
Dibromomethane 08/05/10 16:570.1 1ND TDD 3688642
Dichlorodifluoromethane 08/05/10 16:570.1 1ND TDD 3688642
Ethylbenzene 08/05/10 16:570.1 1ND TDD 3688642
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:38 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 10
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-9
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-07
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 16:570.2 1ND TDD 3688642
Isopropyl ether 08/05/10 16:570.1 1ND TDD 3688642
Isopropylbenzene 08/05/10 16:570.2 1ND TDD 3688642
m & p-Xylene 08/05/10 16:570.1 1ND TDD 3688642
Methyl tert-butyl ether 08/05/10 16:570.2 1ND TDD 3688642
Methylene chloride 08/05/10 16:570.2 1ND TDD 3688642
Naphthalene 08/05/10 16:570.1 1ND TDD 3688642
n-Butylbenzene 08/05/10 16:570.1 1ND TDD 3688642
n-Propylbenzene 08/05/10 16:570.1 1ND TDD 3688642
o-Xylene 08/05/10 16:570.1 1ND TDD 3688642
p-Isopropyltoluene 08/05/10 16:570.1 1ND TDD 3688642
sec-Butylbenzene 08/05/10 16:570.1 1ND TDD 3688642
Styrene 08/05/10 16:570.1 1ND TDD 3688642
tert-Butylbenzene 08/05/10 16:570.1 1ND TDD 3688642
Tetrachloroethene 08/05/10 16:570.2 1ND TDD 3688642
Toluene 08/05/10 16:570.1 1ND TDD 3688642
trans-1,2-Dichloroethene 08/05/10 16:570.1 1ND TDD 3688642
Trichloroethene 08/05/10 16:570.1 1ND TDD 3688642
Trichlorofluoromethane 08/05/10 16:570.1 1ND TDD 3688642
Vinyl chloride 08/05/10 16:570.1 1ND TDD 3688642
Surr: 1,2-Dichloroethane-d4 08/05/10 16:57% 60-140 197.5 TDD 3688642
Surr: 4-Bromofluorobenzene 08/05/10 16:57% 60-140 197.5 TDD 3688642
Surr: Toluene-d8 08/05/10 16:57% 60-140 192.9 TDD 3688642
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 07/30/10 13:39301ND SJA 3682867
C9-C10 Aromatics 07/30/10 13:3951ND SJA 3682856
C9-C12 Aliphatics 07/30/10 13:39351ND SJA 3682867
Surr: 2,5-Dibromotoluene 07/30/10 13:39% 70-130 1101 SJA 3682856
Surr: 2,5-Dibromotoluene 07/30/10 13:39% 70-130 197.6 SJA 3682867
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:39 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 11
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-08
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 18:290.021 1ND RAH 3683669
Surr: 1-Chloro-2-fluorobenzene 07/30/10 18:29% 33-151 176.9 RAH 3683669
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.04
TOTAL METALS BY METHOD 6010B - WATER SW6010B ug/LUnits:MCL
Lead 08/24/10 13:56102ND SVW 3715187
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 14:00 SAM3030-C 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:41 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 12
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-08
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 17:370.1 1ND TDD 3688643
1,1,1-Trichloroethane 08/05/10 17:370.1 1ND TDD 3688643
1,1,2,2-Tetrachloroethane 08/05/10 17:370.1 1ND TDD 3688643
1,1,2-Trichloroethane 08/05/10 17:370.1 1ND TDD 3688643
1,1-Dichloroethane 08/05/10 17:370.1 1ND TDD 3688643
1,1-Dichloroethene 08/05/10 17:370.1 1ND TDD 3688643
1,1-Dichloropropene 08/05/10 17:370.1 1ND TDD 3688643
1,2,3-Trichlorobenzene 08/05/10 17:370.2 1ND TDD 3688643
1,2,3-Trichloropropane 08/05/10 17:370.1 1ND TDD 3688643
1,2,4-Trichlorobenzene 08/05/10 17:370.1 1ND TDD 3688643
1,2,4-Trimethylbenzene 08/05/10 17:370.1 1ND TDD 3688643
1,2-Dibromo-3-chloropropane 08/05/10 17:3711ND TDD 3688643
1,2-Dibromoethane 08/05/10 17:370.1 1ND TDD 3688643
1,2-Dichlorobenzene 08/05/10 17:370.1 1ND TDD 3688643
1,2-Dichloroethane 08/05/10 17:370.2 1ND TDD 3688643
1,2-Dichloropropane 08/05/10 17:370.1 1ND TDD 3688643
1,3,5-Trimethylbenzene 08/05/10 17:370.1 1ND TDD 3688643
1,3-Dichlorobenzene 08/05/10 17:370.1 1ND TDD 3688643
1,3-Dichloropropane 08/05/10 17:370.1 1ND TDD 3688643
1,4-Dichlorobenzene 08/05/10 17:370.1 1ND TDD 3688643
2,2-Dichloropropane 08/05/10 17:370.1 1ND TDD 3688643
2-Chlorotoluene 08/05/10 17:370.2 1ND TDD 3688643
4-Chlorotoluene 08/05/10 17:370.1 1ND TDD 3688643
Benzene 08/05/10 17:370.1 10.12 TDD 3688643
Bromobenzene 08/05/10 17:370.1 1ND TDD 3688643
Bromochloromethane 08/05/10 17:370.1 1ND TDD 3688643
Bromodichloromethane 08/05/10 17:370.1 1ND TDD 3688643
Bromoform 08/05/10 17:370.1 1ND TDD 3688643
Bromomethane 08/05/10 17:370.2 1ND TDD 3688643
Carbon tetrachloride 08/05/10 17:370.1 1ND TDD 3688643
Chlorobenzene 08/05/10 17:370.1 1ND TDD 3688643
Chloroethane 08/05/10 17:370.2 1ND TDD 3688643
Chloroform 08/05/10 17:370.1 1ND TDD 3688643
Chloromethane 08/05/10 17:370.1 1ND TDD 3688643
cis-1,2-Dichloroethene 08/05/10 17:370.1 1ND TDD 3688643
Dibromochloromethane 08/05/10 17:370.1 1ND TDD 3688643
Dibromomethane 08/05/10 17:370.1 1ND TDD 3688643
Dichlorodifluoromethane 08/05/10 17:370.1 1ND TDD 3688643
Ethylbenzene 08/05/10 17:370.1 1ND TDD 3688643
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:42 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 13
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-10
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-08
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 14:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 17:370.2 1ND TDD 3688643
Isopropyl ether 08/05/10 17:370.1 1ND TDD 3688643
Isopropylbenzene 08/05/10 17:370.2 1ND TDD 3688643
m & p-Xylene 08/05/10 17:370.1 10.19 TDD 3688643
Methyl tert-butyl ether 08/05/10 17:370.2 1ND TDD 3688643
Methylene chloride 08/05/10 17:370.2 1ND TDD 3688643
Naphthalene 08/05/10 17:370.1 1ND TDD 3688643
n-Butylbenzene 08/05/10 17:370.1 1ND TDD 3688643
n-Propylbenzene 08/05/10 17:370.1 1ND TDD 3688643
o-Xylene 08/05/10 17:370.1 10.1 TDD 3688643
p-Isopropyltoluene 08/05/10 17:370.1 1ND TDD 3688643
sec-Butylbenzene 08/05/10 17:370.1 1ND TDD 3688643
Styrene 08/05/10 17:370.1 1ND TDD 3688643
tert-Butylbenzene 08/05/10 17:370.1 1ND TDD 3688643
Tetrachloroethene 08/05/10 17:370.2 1ND TDD 3688643
Toluene 08/05/10 17:370.1 11.4 TDD 3688643
trans-1,2-Dichloroethene 08/05/10 17:370.1 1ND TDD 3688643
Trichloroethene 08/05/10 17:370.1 1ND TDD 3688643
Trichlorofluoromethane 08/05/10 17:370.1 1ND TDD 3688643
Vinyl chloride 08/05/10 17:370.1 1ND TDD 3688643
Surr: 1,2-Dichloroethane-d4 08/05/10 17:37% 60-140 198.6 TDD 3688643
Surr: 4-Bromofluorobenzene 08/05/10 17:37% 60-140 1101 TDD 3688643
Surr: Toluene-d8 08/05/10 17:37% 60-140 193.9 TDD 3688643
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 07/30/10 14:14301ND SJA 3682868
C9-C10 Aromatics 07/30/10 14:1451ND SJA 3682857
C9-C12 Aliphatics 07/30/10 14:14351ND SJA 3682868
Surr: 2,5-Dibromotoluene 07/30/10 14:14% 70-130 1102 SJA 3682857
Surr: 2,5-Dibromotoluene 07/30/10 14:14% 70-130 1101 SJA 3682868
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:43 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 14
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-11
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-09
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 11:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 18:490.022 13.1 RAH 3683670
Surr: 1-Chloro-2-fluorobenzene 07/30/10 18:49% 33-151 1246 RAHMI 3683670
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.08
TOTAL METALS BY METHOD 6010B - WATER SW6010B ug/LUnits:MCL
Lead 07/30/10 13:1710119.3 SVW 3681678
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 14:00 SAM3030-C 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:44 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 15
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-11
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-09
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 11:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/06/10 14:3550500ND RPJ 3690092
1,1,1-Trichloroethane 08/06/10 14:3550500ND RPJ 3690092
1,1,2,2-Tetrachloroethane 08/06/10 14:3550500ND RPJ 3690092
1,1,2-Trichloroethane 08/06/10 14:3550500ND RPJ 3690092
1,1-Dichloroethane 08/06/10 14:3550500ND RPJ 3690092
1,1-Dichloroethene 08/06/10 14:3550500ND RPJ 3690092
1,1-Dichloropropene 08/06/10 14:3550500ND RPJ 3690092
1,2,3-Trichlorobenzene 08/06/10 14:35100500ND RPJ 3690092
1,2,3-Trichloropropane 08/06/10 14:3550500ND RPJ 3690092
1,2,4-Trichlorobenzene 08/06/10 14:3550500ND RPJ 3690092
1,2,4-Trimethylbenzene 08/06/10 14:35505001800 RPJ 3690092
1,2-Dibromo-3-chloropropane 08/06/10 14:35500500ND RPJ 3690092
1,2-Dibromoethane 08/06/10 14:3550500ND RPJ 3690092
1,2-Dichlorobenzene 08/06/10 14:3550500ND RPJ 3690092
1,2-Dichloroethane 08/06/10 14:35100500ND RPJ 3690092
1,2-Dichloropropane 08/06/10 14:3550500ND RPJ 3690092
1,3,5-Trimethylbenzene 08/06/10 14:3550500520 RPJ 3690092
1,3-Dichlorobenzene 08/06/10 14:3550500ND RPJ 3690092
1,3-Dichloropropane 08/06/10 14:3550500ND RPJ 3690092
1,4-Dichlorobenzene 08/06/10 14:3550500ND RPJ 3690092
2,2-Dichloropropane 08/06/10 14:3550500ND RPJ 3690092
2-Chlorotoluene 08/06/10 14:35100500ND RPJ 3690092
4-Chlorotoluene 08/06/10 14:3550500ND RPJ 3690092
Benzene 08/06/10 14:355050015000 RPJ 3690092
Bromobenzene 08/06/10 14:3550500ND RPJ 3690092
Bromochloromethane 08/06/10 14:3550500ND RPJ 3690092
Bromodichloromethane 08/06/10 14:3550500ND RPJ 3690092
Bromoform 08/06/10 14:3550500ND RPJ 3690092
Bromomethane 08/06/10 14:3550500ND RPJ 3690092
Carbon tetrachloride 08/06/10 14:3550500ND RPJ 3690092
Chlorobenzene 08/06/10 14:3550500ND RPJ 3690092
Chloroethane 08/06/10 14:35100500ND RPJ 3690092
Chloroform 08/06/10 14:3550500ND RPJ 3690092
Chloromethane 08/06/10 14:3550500ND RPJ 3690092
cis-1,2-Dichloroethene 08/06/10 14:3550500ND RPJ 3690092
Dibromochloromethane 08/06/10 14:3550500ND RPJ 3690092
Dibromomethane 08/06/10 14:3550500ND RPJ 3690092
Dichlorodifluoromethane 08/06/10 14:3550500ND RPJ 3690092
Ethylbenzene 08/06/10 14:35505002800 RPJ 3690092
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:45 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 16
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-11
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-09
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 11:20
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/06/10 14:35100500ND RPJ 3690092
Isopropyl ether 08/06/10 14:3550500190 RPJ 3690092
Isopropylbenzene 08/06/10 14:35100500110 RPJ 3690092
m & p-Xylene 08/06/10 14:35505009300 RPJ 3690092
Methyl tert-butyl ether 08/06/10 14:351005005600 RPJ 3690092
Methylene chloride 08/06/10 14:35100500ND RPJ 3690092
Naphthalene 08/06/10 14:3550500700 RPJ 3690092
n-Butylbenzene 08/06/10 14:3550500ND RPJ 3690092
n-Propylbenzene 08/06/10 14:3550500270 RPJ 3690092
o-Xylene 08/06/10 14:35505004800 RPJ 3690092
p-Isopropyltoluene 08/06/10 14:3550500ND RPJ 3690092
sec-Butylbenzene 08/06/10 14:3550500ND RPJ 3690092
Styrene 08/06/10 14:355050084 RPJ 3690092
tert-Butylbenzene 08/06/10 14:3550500ND RPJ 3690092
Tetrachloroethene 08/06/10 14:35100500ND RPJ 3690092
Toluene 08/06/10 14:355050037000 RPJ 3690092
trans-1,2-Dichloroethene 08/06/10 14:3550500ND RPJ 3690092
Trichloroethene 08/06/10 14:3550500ND RPJ 3690092
Trichlorofluoromethane 08/06/10 14:3550500ND RPJ 3690092
Vinyl chloride 08/06/10 14:3550500ND RPJ 3690092
Surr: 1,2-Dichloroethane-d4 08/06/10 14:35% 60-140 50093.4 RPJ 3690092
Surr: 4-Bromofluorobenzene 08/06/10 14:35% 60-140 50098.8 RPJ 3690092
Surr: Toluene-d8 08/06/10 14:35% 60-140 50096.2 RPJ 3690092
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 07/30/10 17:3715005075000 SJA 3682871
C9-C10 Aromatics 07/30/10 13:03100205700 SJA 3682855
C9-C12 Aliphatics 07/30/10 13:037002024000 SJA 3682866
Surr: 2,5-Dibromotoluene 07/30/10 17:37% 70-130 50107 SJA 3682871
Surr: 2,5-Dibromotoluene 07/30/10 13:03% 70-130 20104 SJA 3682855
Surr: 2,5-Dibromotoluene 07/30/10 13:03% 70-130 20100 SJA 3682866
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:47 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 17
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-12
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-10
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 12:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 19:100.021 1ND RAH 3683671
Surr: 1-Chloro-2-fluorobenzene 07/30/10 19:10% 33-151 1101 RAH 3683671
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.06
TOTAL METALS BY METHOD 6010B - WATER SW6010B ug/LUnits:MCL
Lead 08/24/10 13:5710215.2 SVW 3715188
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 14:00 SAM3030-C 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:48 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 18
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-12
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-10
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 12:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/06/10 15:560.1 1ND RPJ 3692741
1,1,1-Trichloroethane 08/06/10 15:560.1 1ND RPJ 3692741
1,1,2,2-Tetrachloroethane 08/06/10 15:560.1 1ND RPJ 3692741
1,1,2-Trichloroethane 08/06/10 15:560.1 1ND RPJ 3692741
1,1-Dichloroethane 08/06/10 15:560.1 1ND RPJ 3692741
1,1-Dichloroethene 08/06/10 15:560.1 1ND RPJ 3692741
1,1-Dichloropropene 08/06/10 15:560.1 1ND RPJ 3692741
1,2,3-Trichlorobenzene 08/06/10 15:560.2 1ND RPJ 3692741
1,2,3-Trichloropropane 08/06/10 15:560.1 1ND RPJ 3692741
1,2,4-Trichlorobenzene 08/06/10 15:560.1 1ND RPJ 3692741
1,2,4-Trimethylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
1,2-Dibromo-3-chloropropane 08/06/10 15:5611ND RPJ 3692741
1,2-Dibromoethane 08/06/10 15:560.1 1ND RPJ 3692741
1,2-Dichlorobenzene 08/06/10 15:560.1 1ND RPJ 3692741
1,2-Dichloroethane 08/06/10 15:560.2 1ND RPJ 3692741
1,2-Dichloropropane 08/06/10 15:560.1 1ND RPJ 3692741
1,3,5-Trimethylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
1,3-Dichlorobenzene 08/06/10 15:560.1 1ND RPJ 3692741
1,3-Dichloropropane 08/06/10 15:560.1 1ND RPJ 3692741
1,4-Dichlorobenzene 08/06/10 15:560.1 1ND RPJ 3692741
2,2-Dichloropropane 08/06/10 15:560.1 1ND RPJ 3692741
2-Chlorotoluene 08/06/10 15:560.2 1ND RPJ 3692741
4-Chlorotoluene 08/06/10 15:560.1 1ND RPJ 3692741
Benzene 08/06/10 15:560.1 1ND RPJ 3692741
Bromobenzene 08/06/10 15:560.1 1ND RPJ 3692741
Bromochloromethane 08/06/10 15:560.1 1ND RPJ 3692741
Bromodichloromethane 08/06/10 15:560.1 1ND RPJ 3692741
Bromoform 08/06/10 15:560.1 1ND RPJ 3692741
Bromomethane 08/06/10 15:560.1 1ND RPJ 3692741
Carbon tetrachloride 08/06/10 15:560.1 1ND RPJ 3692741
Chlorobenzene 08/06/10 15:560.1 1ND RPJ 3692741
Chloroethane 08/06/10 15:560.2 1ND RPJ 3692741
Chloroform 08/06/10 15:560.1 1ND RPJ 3692741
Chloromethane 08/06/10 15:560.1 1ND RPJ 3692741
cis-1,2-Dichloroethene 08/06/10 15:560.1 1ND RPJ 3692741
Dibromochloromethane 08/06/10 15:560.1 1ND RPJ 3692741
Dibromomethane 08/06/10 15:560.1 1ND RPJ 3692741
Dichlorodifluoromethane 08/06/10 15:560.1 1ND RPJ 3692741
Ethylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:49 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 19
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:MW-12
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-10
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 12:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/06/10 15:560.2 1ND RPJ 3692741
Isopropyl ether 08/06/10 15:560.1 1ND RPJ 3692741
Isopropylbenzene 08/06/10 15:560.2 1ND RPJ 3692741
m & p-Xylene 08/06/10 15:560.1 12.7 RPJ 3692741
Methyl tert-butyl ether 08/06/10 15:560.2 1ND RPJ 3692741
Methylene chloride 08/06/10 15:560.2 1ND RPJ 3692741
Naphthalene 08/06/10 15:560.1 1ND RPJ 3692741
n-Butylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
n-Propylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
o-Xylene 08/06/10 15:560.1 1ND RPJ 3692741
p-Isopropyltoluene 08/06/10 15:560.1 1ND RPJ 3692741
sec-Butylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
Styrene 08/06/10 15:560.1 1ND RPJ 3692741
tert-Butylbenzene 08/06/10 15:560.1 1ND RPJ 3692741
Tetrachloroethene 08/06/10 15:560.2 1ND RPJ 3692741
Toluene 08/06/10 15:560.1 1ND RPJ 3692741
trans-1,2-Dichloroethene 08/06/10 15:560.1 1ND RPJ 3692741
Trichloroethene 08/06/10 15:560.1 1ND RPJ 3692741
Trichlorofluoromethane 08/06/10 15:560.1 1ND RPJ 3692741
Vinyl chloride 08/06/10 15:560.1 1ND RPJ 3692741
Surr: 1,2-Dichloroethane-d4 08/06/10 15:56% 60-140 1145 RPJ*3692741
Surr: 4-Bromofluorobenzene 08/06/10 15:56% 60-140 1104 RPJ 3692741
Surr: Toluene-d8 08/06/10 15:56% 60-140 195.7 RPJ 3692741
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 07/30/10 15:17301ND SJA 3682869
C9-C10 Aromatics 07/30/10 15:1751ND SJA 3682858
C9-C12 Aliphatics 07/30/10 15:17351ND SJA 3682869
Surr: 2,5-Dibromotoluene 07/30/10 15:17% 70-130 1114 SJA 3682858
Surr: 2,5-Dibromotoluene 07/30/10 15:17% 70-130 1110 SJA 3682869
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:50 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 20
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-11
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 13:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 19:310.021 1ND RAH 3683672
Surr: 1-Chloro-2-fluorobenzene 07/30/10 19:31% 33-151 193.7 RAH 3683672
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.06
TOTAL METALS BY METHOD 6010B - WATER SW6010B ug/LUnits:MCL
Lead 07/30/10 13:20101ND SVW 3681679
Prep Method Prep Date Prep Initials Prep Factor
07/29/2010 14:00 SAM3030-C 1.00
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:52 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 21
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-11
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 13:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/06/10 16:340.1 1ND RPJ 3692742
1,1,1-Trichloroethane 08/06/10 16:340.1 1ND RPJ 3692742
1,1,2,2-Tetrachloroethane 08/06/10 16:340.1 1ND RPJ 3692742
1,1,2-Trichloroethane 08/06/10 16:340.1 1ND RPJ 3692742
1,1-Dichloroethane 08/06/10 16:340.1 1ND RPJ 3692742
1,1-Dichloroethene 08/06/10 16:340.1 1ND RPJ 3692742
1,1-Dichloropropene 08/06/10 16:340.1 1ND RPJ 3692742
1,2,3-Trichlorobenzene 08/06/10 16:340.2 1ND RPJ 3692742
1,2,3-Trichloropropane 08/06/10 16:340.1 1ND RPJ 3692742
1,2,4-Trichlorobenzene 08/06/10 16:340.1 1ND RPJ 3692742
1,2,4-Trimethylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
1,2-Dibromo-3-chloropropane 08/06/10 16:3411ND RPJ 3692742
1,2-Dibromoethane 08/06/10 16:340.1 1ND RPJ 3692742
1,2-Dichlorobenzene 08/06/10 16:340.1 1ND RPJ 3692742
1,2-Dichloroethane 08/06/10 16:340.2 1ND RPJ 3692742
1,2-Dichloropropane 08/06/10 16:340.1 1ND RPJ 3692742
1,3,5-Trimethylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
1,3-Dichlorobenzene 08/06/10 16:340.1 1ND RPJ 3692742
1,3-Dichloropropane 08/06/10 16:340.1 1ND RPJ 3692742
1,4-Dichlorobenzene 08/06/10 16:340.1 1ND RPJ 3692742
2,2-Dichloropropane 08/06/10 16:340.1 1ND RPJ 3692742
2-Chlorotoluene 08/06/10 16:340.2 1ND RPJ 3692742
4-Chlorotoluene 08/06/10 16:340.1 1ND RPJ 3692742
Benzene 08/06/10 16:340.1 11.4 RPJ 3692742
Bromobenzene 08/06/10 16:340.1 1ND RPJ 3692742
Bromochloromethane 08/06/10 16:340.1 1ND RPJ 3692742
Bromodichloromethane 08/06/10 16:340.1 1ND RPJ 3692742
Bromoform 08/06/10 16:340.1 1ND RPJ 3692742
Bromomethane 08/06/10 16:340.1 1ND RPJ 3692742
Carbon tetrachloride 08/06/10 16:340.1 1ND RPJ 3692742
Chlorobenzene 08/06/10 16:340.1 1ND RPJ 3692742
Chloroethane 08/06/10 16:340.2 1ND RPJ 3692742
Chloroform 08/06/10 16:340.1 1ND RPJ 3692742
Chloromethane 08/06/10 16:340.1 1ND RPJ 3692742
cis-1,2-Dichloroethene 08/06/10 16:340.1 1ND RPJ 3692742
Dibromochloromethane 08/06/10 16:340.1 1ND RPJ 3692742
Dibromomethane 08/06/10 16:340.1 1ND RPJ 3692742
Dichlorodifluoromethane 08/06/10 16:340.1 1ND RPJ 3692742
Ethylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:53 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 22
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:DMW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-11
Dil. Factor AnalystQUAL Seq. #
Collected:07/28/2010 13:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/06/10 16:340.2 1ND RPJ 3692742
Isopropyl ether 08/06/10 16:340.1 1ND RPJ 3692742
Isopropylbenzene 08/06/10 16:340.2 1ND RPJ 3692742
m & p-Xylene 08/06/10 16:340.1 13.1 RPJ 3692742
Methyl tert-butyl ether 08/06/10 16:340.2 1ND RPJ 3692742
Methylene chloride 08/06/10 16:340.2 1ND RPJ 3692742
Naphthalene 08/06/10 16:340.1 1ND RPJ 3692742
n-Butylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
n-Propylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
o-Xylene 08/06/10 16:340.1 1ND RPJ 3692742
p-Isopropyltoluene 08/06/10 16:340.1 1ND RPJ 3692742
sec-Butylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
Styrene 08/06/10 16:340.1 1ND RPJ 3692742
tert-Butylbenzene 08/06/10 16:340.1 1ND RPJ 3692742
Tetrachloroethene 08/06/10 16:340.2 1ND RPJ 3692742
Toluene 08/06/10 16:340.1 12 RPJ 3692742
trans-1,2-Dichloroethene 08/06/10 16:340.1 1ND RPJ 3692742
Trichloroethene 08/06/10 16:340.1 1ND RPJ 3692742
Trichlorofluoromethane 08/06/10 16:340.1 1ND RPJ 3692742
Vinyl chloride 08/06/10 16:340.1 1ND RPJ 3692742
Surr: 1,2-Dichloroethane-d4 08/06/10 16:34% 60-140 1147 RPJ*3692742
Surr: 4-Bromofluorobenzene 08/06/10 16:34% 60-140 1105 RPJ 3692742
Surr: Toluene-d8 08/06/10 16:34% 60-140 196.9 RPJ 3692742
VOLATILE PETROLEUM HYDROCARBONS (WATER)MA_VPH_EPH ug/LUnits:MCL
C5-C8 Aliphatics 07/30/10 16:44301ND SJA 3682870
C9-C10 Aromatics 07/30/10 16:4451ND SJA 3682859
C9-C12 Aliphatics 07/30/10 16:44351ND SJA 3682870
Surr: 2,5-Dibromotoluene 07/30/10 16:44% 70-130 1116 SJA 3682859
Surr: 2,5-Dibromotoluene 07/30/10 16:44% 70-130 1112 SJA 3682870
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:54 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 23
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-12
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 19:510.023 1ND RAH 3683673
Surr: 1-Chloro-2-fluorobenzene 07/30/10 19:51% 33-151 1121 RAH 3683673
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.13
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:55 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 24
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-12
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 17:120.1 1ND TDD 3688715
1,1,1-Trichloroethane 08/05/10 17:120.1 1ND TDD 3688715
1,1,2,2-Tetrachloroethane 08/05/10 17:120.1 1ND TDD 3688715
1,1,2-Trichloroethane 08/05/10 17:120.1 1ND TDD 3688715
1,1-Dichloroethane 08/05/10 17:120.1 1ND TDD 3688715
1,1-Dichloroethene 08/05/10 17:120.1 1ND TDD 3688715
1,1-Dichloropropene 08/05/10 17:120.1 1ND TDD 3688715
1,2,3-Trichlorobenzene 08/05/10 17:120.2 1ND TDD 3688715
1,2,3-Trichloropropane 08/05/10 17:120.1 1ND TDD 3688715
1,2,4-Trichlorobenzene 08/05/10 17:120.1 1ND TDD 3688715
1,2,4-Trimethylbenzene 08/05/10 17:120.1 1ND TDD 3688715
1,2-Dibromo-3-chloropropane 08/05/10 17:1211ND TDD 3688715
1,2-Dibromoethane 08/05/10 17:120.1 1ND TDD 3688715
1,2-Dichlorobenzene 08/05/10 17:120.1 1ND TDD 3688715
1,2-Dichloroethane 08/05/10 17:120.2 1ND TDD 3688715
1,2-Dichloropropane 08/05/10 17:120.1 1ND TDD 3688715
1,3,5-Trimethylbenzene 08/05/10 17:120.1 1ND TDD 3688715
1,3-Dichlorobenzene 08/05/10 17:120.1 1ND TDD 3688715
1,3-Dichloropropane 08/05/10 17:120.1 1ND TDD 3688715
1,4-Dichlorobenzene 08/05/10 17:120.1 1ND TDD 3688715
2,2-Dichloropropane 08/05/10 17:120.1 1ND TDD 3688715
2-Chlorotoluene 08/05/10 17:120.2 1ND TDD 3688715
4-Chlorotoluene 08/05/10 17:120.1 1ND TDD 3688715
Benzene 08/05/10 17:120.1 10.12 TDD 3688715
Bromobenzene 08/05/10 17:120.1 1ND TDD 3688715
Bromochloromethane 08/05/10 17:120.1 1ND TDD 3688715
Bromodichloromethane 08/05/10 17:120.1 1ND TDD 3688715
Bromoform 08/05/10 17:120.2 1ND TDD 3688715
Bromomethane 08/05/10 17:120.1 1ND TDD 3688715
Carbon tetrachloride 08/05/10 17:120.1 1ND TDD 3688715
Chlorobenzene 08/05/10 17:120.1 1ND TDD 3688715
Chloroethane 08/05/10 17:120.2 1ND TDD 3688715
Chloroform 08/05/10 17:120.1 1ND TDD 3688715
Chloromethane 08/05/10 17:120.1 1ND TDD 3688715
cis-1,2-Dichloroethene 08/05/10 17:120.1 1ND TDD 3688715
Dibromochloromethane 08/05/10 17:120.1 1ND TDD 3688715
Dibromomethane 08/05/10 17:120.1 1ND TDD 3688715
Dichlorodifluoromethane 08/05/10 17:120.1 1ND TDD 3688715
Ethylbenzene 08/05/10 17:120.1 1ND TDD 3688715
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:57 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 25
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-1
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-12
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 17:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 17:120.2 1ND TDD 3688715
Isopropyl ether 08/05/10 17:120.1 1ND TDD 3688715
Isopropylbenzene 08/05/10 17:120.2 1ND TDD 3688715
m & p-Xylene 08/05/10 17:120.1 12.7 TDD 3688715
Methyl tert-butyl ether 08/05/10 17:120.2 1ND TDD 3688715
Methylene chloride 08/05/10 17:120.2 1ND TDD 3688715
Naphthalene 08/05/10 17:120.1 10.84 TDD 3688715
n-Butylbenzene 08/05/10 17:120.1 1ND TDD 3688715
n-Propylbenzene 08/05/10 17:120.1 1ND TDD 3688715
o-Xylene 08/05/10 17:120.1 1ND TDD 3688715
p-Isopropyltoluene 08/05/10 17:120.1 1ND TDD 3688715
sec-Butylbenzene 08/05/10 17:120.1 1ND TDD 3688715
Styrene 08/05/10 17:120.1 1ND TDD 3688715
tert-Butylbenzene 08/05/10 17:120.1 1ND TDD 3688715
Tetrachloroethene 08/05/10 17:120.2 1ND TDD 3688715
Toluene 08/05/10 17:120.1 1ND TDD 3688715
trans-1,2-Dichloroethene 08/05/10 17:120.1 1ND TDD 3688715
Trichloroethene 08/05/10 17:120.1 1ND TDD 3688715
Trichlorofluoromethane 08/05/10 17:120.1 1ND TDD 3688715
Vinyl chloride 08/05/10 17:120.1 1ND TDD 3688715
Surr: 1,2-Dichloroethane-d4 08/05/10 17:12% 60-140 196.0 TDD 3688715
Surr: 4-Bromofluorobenzene 08/05/10 17:12% 60-140 197.3 TDD 3688715
Surr: Toluene-d8 08/05/10 17:12% 60-140 196.0 TDD 3688715
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:57 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 26
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-13
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 20:120.021 1ND RAH 3683674
Surr: 1-Chloro-2-fluorobenzene 07/30/10 20:12% 33-151 1115 RAH 3683674
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.06
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:38:59 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 27
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-13
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 17:510.1 1ND TDD 3688716
1,1,1-Trichloroethane 08/05/10 17:510.1 1ND TDD 3688716
1,1,2,2-Tetrachloroethane 08/05/10 17:510.1 1ND TDD 3688716
1,1,2-Trichloroethane 08/05/10 17:510.1 1ND TDD 3688716
1,1-Dichloroethane 08/05/10 17:510.1 10.12 TDD 3688716
1,1-Dichloroethene 08/05/10 17:510.1 1ND TDD 3688716
1,1-Dichloropropene 08/05/10 17:510.1 1ND TDD 3688716
1,2,3-Trichlorobenzene 08/05/10 17:510.2 1ND TDD 3688716
1,2,3-Trichloropropane 08/05/10 17:510.1 1ND TDD 3688716
1,2,4-Trichlorobenzene 08/05/10 17:510.1 1ND TDD 3688716
1,2,4-Trimethylbenzene 08/05/10 17:510.1 1ND TDD 3688716
1,2-Dibromo-3-chloropropane 08/05/10 17:5111ND TDD 3688716
1,2-Dibromoethane 08/05/10 17:510.1 1ND TDD 3688716
1,2-Dichlorobenzene 08/05/10 17:510.1 1ND TDD 3688716
1,2-Dichloroethane 08/05/10 17:510.2 1ND TDD 3688716
1,2-Dichloropropane 08/05/10 17:510.1 1ND TDD 3688716
1,3,5-Trimethylbenzene 08/05/10 17:510.1 1ND TDD 3688716
1,3-Dichlorobenzene 08/05/10 17:510.1 1ND TDD 3688716
1,3-Dichloropropane 08/05/10 17:510.1 1ND TDD 3688716
1,4-Dichlorobenzene 08/05/10 17:510.1 1ND TDD 3688716
2,2-Dichloropropane 08/05/10 17:510.1 1ND TDD 3688716
2-Chlorotoluene 08/05/10 17:510.2 1ND TDD 3688716
4-Chlorotoluene 08/05/10 17:510.1 1ND TDD 3688716
Benzene 08/05/10 17:510.1 1ND TDD 3688716
Bromobenzene 08/05/10 17:510.1 1ND TDD 3688716
Bromochloromethane 08/05/10 17:510.1 1ND TDD 3688716
Bromodichloromethane 08/05/10 17:510.1 1ND TDD 3688716
Bromoform 08/05/10 17:510.2 1ND TDD 3688716
Bromomethane 08/05/10 17:510.1 1ND TDD 3688716
Carbon tetrachloride 08/05/10 17:510.1 1ND TDD 3688716
Chlorobenzene 08/05/10 17:510.1 1ND TDD 3688716
Chloroethane 08/05/10 17:510.2 1ND TDD 3688716
Chloroform 08/05/10 17:510.1 10.31 TDD 3688716
Chloromethane 08/05/10 17:510.1 1ND TDD 3688716
cis-1,2-Dichloroethene 08/05/10 17:510.1 1ND TDD 3688716
Dibromochloromethane 08/05/10 17:510.1 1ND TDD 3688716
Dibromomethane 08/05/10 17:510.1 1ND TDD 3688716
Dichlorodifluoromethane 08/05/10 17:510.1 1ND TDD 3688716
Ethylbenzene 08/05/10 17:510.1 1ND TDD 3688716
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:00 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 28
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-2
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-13
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:00
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 17:510.2 1ND TDD 3688716
Isopropyl ether 08/05/10 17:510.1 1ND TDD 3688716
Isopropylbenzene 08/05/10 17:510.2 1ND TDD 3688716
m & p-Xylene 08/05/10 17:510.1 1ND TDD 3688716
Methyl tert-butyl ether 08/05/10 17:510.2 16 TDD 3688716
Methylene chloride 08/05/10 17:510.2 1ND TDD 3688716
Naphthalene 08/05/10 17:510.1 10.34 TDD 3688716
n-Butylbenzene 08/05/10 17:510.1 1ND TDD 3688716
n-Propylbenzene 08/05/10 17:510.1 1ND TDD 3688716
o-Xylene 08/05/10 17:510.1 1ND TDD 3688716
p-Isopropyltoluene 08/05/10 17:510.1 1ND TDD 3688716
sec-Butylbenzene 08/05/10 17:510.1 1ND TDD 3688716
Styrene 08/05/10 17:510.1 1ND TDD 3688716
tert-Butylbenzene 08/05/10 17:510.1 1ND TDD 3688716
Tetrachloroethene 08/05/10 17:510.2 1ND TDD 3688716
Toluene 08/05/10 17:510.1 1ND TDD 3688716
trans-1,2-Dichloroethene 08/05/10 17:510.1 1ND TDD 3688716
Trichloroethene 08/05/10 17:510.1 1ND TDD 3688716
Trichlorofluoromethane 08/05/10 17:510.1 1ND TDD 3688716
Vinyl chloride 08/05/10 17:510.1 1ND TDD 3688716
Surr: 1,2-Dichloroethane-d4 08/05/10 17:51% 60-140 193.4 TDD 3688716
Surr: 4-Bromofluorobenzene 08/05/10 17:51% 60-140 196.9 TDD 3688716
Surr: Toluene-d8 08/05/10 17:51% 60-140 191.8 TDD 3688716
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:00 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 29
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-14
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:10
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 20:530.022 1ND RAH 3683676
Surr: 1-Chloro-2-fluorobenzene 07/30/10 20:53% 33-151 197.5 RAH 3683676
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.08
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:02 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 30
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-14
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:10
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 18:300.1 1ND TDD 3688717
1,1,1-Trichloroethane 08/05/10 18:300.1 1ND TDD 3688717
1,1,2,2-Tetrachloroethane 08/05/10 18:300.1 1ND TDD 3688717
1,1,2-Trichloroethane 08/05/10 18:300.1 1ND TDD 3688717
1,1-Dichloroethane 08/05/10 18:300.1 1ND TDD 3688717
1,1-Dichloroethene 08/05/10 18:300.1 1ND TDD 3688717
1,1-Dichloropropene 08/05/10 18:300.1 1ND TDD 3688717
1,2,3-Trichlorobenzene 08/05/10 18:300.2 1ND TDD 3688717
1,2,3-Trichloropropane 08/05/10 18:300.1 1ND TDD 3688717
1,2,4-Trichlorobenzene 08/05/10 18:300.1 1ND TDD 3688717
1,2,4-Trimethylbenzene 08/05/10 18:300.1 1ND TDD 3688717
1,2-Dibromo-3-chloropropane 08/05/10 18:3011ND TDD 3688717
1,2-Dibromoethane 08/05/10 18:300.1 1ND TDD 3688717
1,2-Dichlorobenzene 08/05/10 18:300.1 1ND TDD 3688717
1,2-Dichloroethane 08/05/10 18:300.2 1ND TDD 3688717
1,2-Dichloropropane 08/05/10 18:300.1 1ND TDD 3688717
1,3,5-Trimethylbenzene 08/05/10 18:300.1 1ND TDD 3688717
1,3-Dichlorobenzene 08/05/10 18:300.1 1ND TDD 3688717
1,3-Dichloropropane 08/05/10 18:300.1 1ND TDD 3688717
1,4-Dichlorobenzene 08/05/10 18:300.1 1ND TDD 3688717
2,2-Dichloropropane 08/05/10 18:300.1 1ND TDD 3688717
2-Chlorotoluene 08/05/10 18:300.2 1ND TDD 3688717
4-Chlorotoluene 08/05/10 18:300.1 1ND TDD 3688717
Benzene 08/05/10 18:300.1 1ND TDD 3688717
Bromobenzene 08/05/10 18:300.1 1ND TDD 3688717
Bromochloromethane 08/05/10 18:300.1 1ND TDD 3688717
Bromodichloromethane 08/05/10 18:300.1 1ND TDD 3688717
Bromoform 08/05/10 18:300.2 1ND TDD 3688717
Bromomethane 08/05/10 18:300.1 1ND TDD 3688717
Carbon tetrachloride 08/05/10 18:300.1 1ND TDD 3688717
Chlorobenzene 08/05/10 18:300.1 1ND TDD 3688717
Chloroethane 08/05/10 18:300.2 1ND TDD 3688717
Chloroform 08/05/10 18:300.1 11.3 TDD 3688717
Chloromethane 08/05/10 18:300.1 1ND TDD 3688717
cis-1,2-Dichloroethene 08/05/10 18:300.1 1ND TDD 3688717
Dibromochloromethane 08/05/10 18:300.1 1ND TDD 3688717
Dibromomethane 08/05/10 18:300.1 1ND TDD 3688717
Dichlorodifluoromethane 08/05/10 18:300.1 1ND TDD 3688717
Ethylbenzene 08/05/10 18:300.1 1ND TDD 3688717
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:03 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 31
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-15
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-14
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:10
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 18:300.2 1ND TDD 3688717
Isopropyl ether 08/05/10 18:300.1 1ND TDD 3688717
Isopropylbenzene 08/05/10 18:300.2 1ND TDD 3688717
m & p-Xylene 08/05/10 18:300.1 1ND TDD 3688717
Methyl tert-butyl ether 08/05/10 18:300.2 1ND TDD 3688717
Methylene chloride 08/05/10 18:300.2 1ND TDD 3688717
Naphthalene 08/05/10 18:300.1 11.2 TDD 3688717
n-Butylbenzene 08/05/10 18:300.1 1ND TDD 3688717
n-Propylbenzene 08/05/10 18:300.1 1ND TDD 3688717
o-Xylene 08/05/10 18:300.1 1ND TDD 3688717
p-Isopropyltoluene 08/05/10 18:300.1 1ND TDD 3688717
sec-Butylbenzene 08/05/10 18:300.1 1ND TDD 3688717
Styrene 08/05/10 18:300.1 1ND TDD 3688717
tert-Butylbenzene 08/05/10 18:300.1 1ND TDD 3688717
Tetrachloroethene 08/05/10 18:300.2 1ND TDD 3688717
Toluene 08/05/10 18:300.1 1ND TDD 3688717
trans-1,2-Dichloroethene 08/05/10 18:300.1 1ND TDD 3688717
Trichloroethene 08/05/10 18:300.1 1ND TDD 3688717
Trichlorofluoromethane 08/05/10 18:300.1 1ND TDD 3688717
Vinyl chloride 08/05/10 18:300.1 1ND TDD 3688717
Surr: 1,2-Dichloroethane-d4 08/05/10 18:30% 60-140 193.6 TDD 3688717
Surr: 4-Bromofluorobenzene 08/05/10 18:30% 60-140 196.9 TDD 3688717
Surr: Toluene-d8 08/05/10 18:30% 60-140 196.0 TDD 3688717
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:04 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 32
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-15
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 21:140.021 1ND RAH 3683677
Surr: 1-Chloro-2-fluorobenzene 07/30/10 21:14% 33-151 197.0 RAH 3683677
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.07
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:05 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 33
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-15
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/05/10 19:090.1 1ND TDD 3688718
1,1,1-Trichloroethane 08/05/10 19:090.1 1ND TDD 3688718
1,1,2,2-Tetrachloroethane 08/05/10 19:090.1 1ND TDD 3688718
1,1,2-Trichloroethane 08/05/10 19:090.1 1ND TDD 3688718
1,1-Dichloroethane 08/05/10 19:090.1 1ND TDD 3688718
1,1-Dichloroethene 08/05/10 19:090.1 1ND TDD 3688718
1,1-Dichloropropene 08/05/10 19:090.1 1ND TDD 3688718
1,2,3-Trichlorobenzene 08/05/10 19:090.2 1ND TDD 3688718
1,2,3-Trichloropropane 08/05/10 19:090.1 1ND TDD 3688718
1,2,4-Trichlorobenzene 08/05/10 19:090.1 1ND TDD 3688718
1,2,4-Trimethylbenzene 08/05/10 19:090.1 1ND TDD 3688718
1,2-Dibromo-3-chloropropane 08/05/10 19:0911ND TDD 3688718
1,2-Dibromoethane 08/05/10 19:090.1 1ND TDD 3688718
1,2-Dichlorobenzene 08/05/10 19:090.1 1ND TDD 3688718
1,2-Dichloroethane 08/05/10 19:090.2 1ND TDD 3688718
1,2-Dichloropropane 08/05/10 19:090.1 1ND TDD 3688718
1,3,5-Trimethylbenzene 08/05/10 19:090.1 1ND TDD 3688718
1,3-Dichlorobenzene 08/05/10 19:090.1 1ND TDD 3688718
1,3-Dichloropropane 08/05/10 19:090.1 1ND TDD 3688718
1,4-Dichlorobenzene 08/05/10 19:090.1 1ND TDD 3688718
2,2-Dichloropropane 08/05/10 19:090.1 1ND TDD 3688718
2-Chlorotoluene 08/05/10 19:090.2 1ND TDD 3688718
4-Chlorotoluene 08/05/10 19:090.1 1ND TDD 3688718
Benzene 08/05/10 19:090.1 11.4 TDD 3688718
Bromobenzene 08/05/10 19:090.1 1ND TDD 3688718
Bromochloromethane 08/05/10 19:090.1 1ND TDD 3688718
Bromodichloromethane 08/05/10 19:090.1 1ND TDD 3688718
Bromoform 08/05/10 19:090.2 1ND TDD 3688718
Bromomethane 08/05/10 19:090.1 1ND TDD 3688718
Carbon tetrachloride 08/05/10 19:090.1 1ND TDD 3688718
Chlorobenzene 08/05/10 19:090.1 1ND TDD 3688718
Chloroethane 08/05/10 19:090.2 1ND TDD 3688718
Chloroform 08/05/10 19:090.1 1ND TDD 3688718
Chloromethane 08/05/10 19:090.1 1ND TDD 3688718
cis-1,2-Dichloroethene 08/05/10 19:090.1 1ND TDD 3688718
Dibromochloromethane 08/05/10 19:090.1 1ND TDD 3688718
Dibromomethane 08/05/10 19:090.1 1ND TDD 3688718
Dichlorodifluoromethane 08/05/10 19:090.1 1ND TDD 3688718
Ethylbenzene 08/05/10 19:090.1 1ND TDD 3688718
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:06 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 34
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-16
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-15
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 15:45
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/05/10 19:090.2 1ND TDD 3688718
Isopropyl ether 08/05/10 19:090.1 1ND TDD 3688718
Isopropylbenzene 08/05/10 19:090.2 1ND TDD 3688718
m & p-Xylene 08/05/10 19:090.1 13.9 TDD 3688718
Methyl tert-butyl ether 08/05/10 19:090.2 1ND TDD 3688718
Methylene chloride 08/05/10 19:090.2 10.2 TDD 3688718
Naphthalene 08/05/10 19:090.1 1ND TDD 3688718
n-Butylbenzene 08/05/10 19:090.1 1ND TDD 3688718
n-Propylbenzene 08/05/10 19:090.1 1ND TDD 3688718
o-Xylene 08/05/10 19:090.1 1ND TDD 3688718
p-Isopropyltoluene 08/05/10 19:090.1 1ND TDD 3688718
sec-Butylbenzene 08/05/10 19:090.1 1ND TDD 3688718
Styrene 08/05/10 19:090.1 1ND TDD 3688718
tert-Butylbenzene 08/05/10 19:090.1 1ND TDD 3688718
Tetrachloroethene 08/05/10 19:090.2 1ND TDD 3688718
Toluene 08/05/10 19:090.1 14.3 TDD 3688718
trans-1,2-Dichloroethene 08/05/10 19:090.1 1ND TDD 3688718
Trichloroethene 08/05/10 19:090.1 1ND TDD 3688718
Trichlorofluoromethane 08/05/10 19:090.1 1ND TDD 3688718
Vinyl chloride 08/05/10 19:090.1 1ND TDD 3688718
Surr: 1,2-Dichloroethane-d4 08/05/10 19:09% 60-140 191.8 TDD 3688718
Surr: 4-Bromofluorobenzene 08/05/10 19:09% 60-140 199.4 TDD 3688718
Surr: Toluene-d8 08/05/10 19:09% 60-140 196.1 TDD 3688718
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:07 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 35
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-18
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-16
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
METHOD 504.1 E504.1 ug/LUnits:MCL
1,2-Dibromoethane 07/30/10 21:340.022 1ND RAH 3683678
Surr: 1-Chloro-2-fluorobenzene 07/30/10 21:34% 33-151 190.4 RAH 3683678
Prep Method Prep Date Prep Initials Prep Factor
07/30/2010 8:00 JDFE504 1.10
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:08 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 36
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-18
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-16
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY GCMS: SM6200 B SM6200 B ug/LUnits:MCL
1,1,1,2-Tetrachloroethane 08/06/10 13:570.1 1ND RPJ 3690091
1,1,1-Trichloroethane 08/06/10 13:570.1 1ND RPJ 3690091
1,1,2,2-Tetrachloroethane 08/06/10 13:570.1 1ND RPJ 3690091
1,1,2-Trichloroethane 08/06/10 13:570.1 1ND RPJ 3690091
1,1-Dichloroethane 08/06/10 13:570.1 1ND RPJ 3690091
1,1-Dichloroethene 08/06/10 13:570.1 1ND RPJ 3690091
1,1-Dichloropropene 08/06/10 13:570.1 1ND RPJ 3690091
1,2,3-Trichlorobenzene 08/06/10 13:570.2 1ND RPJ 3690091
1,2,3-Trichloropropane 08/06/10 13:570.1 1ND RPJ 3690091
1,2,4-Trichlorobenzene 08/06/10 13:570.1 1ND RPJ 3690091
1,2,4-Trimethylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
1,2-Dibromo-3-chloropropane 08/06/10 13:5711ND RPJ 3690091
1,2-Dibromoethane 08/06/10 13:570.1 1ND RPJ 3690091
1,2-Dichlorobenzene 08/06/10 13:570.1 1ND RPJ 3690091
1,2-Dichloroethane 08/06/10 13:570.2 1ND RPJ 3690091
1,2-Dichloropropane 08/06/10 13:570.1 1ND RPJ 3690091
1,3,5-Trimethylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
1,3-Dichlorobenzene 08/06/10 13:570.1 1ND RPJ 3690091
1,3-Dichloropropane 08/06/10 13:570.1 1ND RPJ 3690091
1,4-Dichlorobenzene 08/06/10 13:570.1 1ND RPJ 3690091
2,2-Dichloropropane 08/06/10 13:570.1 1ND RPJ 3690091
2-Chlorotoluene 08/06/10 13:570.2 1ND RPJ 3690091
4-Chlorotoluene 08/06/10 13:570.1 1ND RPJ 3690091
Benzene 08/06/10 13:570.1 1ND RPJ 3690091
Bromobenzene 08/06/10 13:570.1 1ND RPJ 3690091
Bromochloromethane 08/06/10 13:570.1 1ND RPJ 3690091
Bromodichloromethane 08/06/10 13:570.1 1ND RPJ 3690091
Bromoform 08/06/10 13:570.1 1ND RPJ 3690091
Bromomethane 08/06/10 13:570.1 1ND RPJ 3690091
Carbon tetrachloride 08/06/10 13:570.1 1ND RPJ 3690091
Chlorobenzene 08/06/10 13:570.1 1ND RPJ 3690091
Chloroethane 08/06/10 13:570.2 1ND RPJ 3690091
Chloroform 08/06/10 13:570.1 1ND RPJ 3690091
Chloromethane 08/06/10 13:570.1 1ND RPJ 3690091
cis-1,2-Dichloroethene 08/06/10 13:570.1 1ND RPJ 3690091
Dibromochloromethane 08/06/10 13:570.1 1ND RPJ 3690091
Dibromomethane 08/06/10 13:570.1 1ND RPJ 3690091
Dichlorodifluoromethane 08/06/10 13:570.1 1ND RPJ 3690091
Ethylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:09 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 37
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Client Sample ID:PW-18
Analyses/Method Result Date AnalyzedRep.Limit
SPL Sample ID:10071130-16
Dil. Factor AnalystQUAL Seq. #
Collected:07/26/2010 16:30
Site:CAJAHS MOUNTAIN SUPERETTE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Hexachlorobutadiene 08/06/10 13:570.2 1ND RPJ 3690091
Isopropyl ether 08/06/10 13:570.1 1ND RPJ 3690091
Isopropylbenzene 08/06/10 13:570.2 1ND RPJ 3690091
m & p-Xylene 08/06/10 13:570.1 1ND RPJ 3690091
Methyl tert-butyl ether 08/06/10 13:570.2 1ND RPJ 3690091
Methylene chloride 08/06/10 13:570.2 1ND RPJ 3690091
Naphthalene 08/06/10 13:570.1 1ND RPJ 3690091
n-Butylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
n-Propylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
o-Xylene 08/06/10 13:570.1 1ND RPJ 3690091
p-Isopropyltoluene 08/06/10 13:570.1 1ND RPJ 3690091
sec-Butylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
Styrene 08/06/10 13:570.1 1ND RPJ 3690091
tert-Butylbenzene 08/06/10 13:570.1 1ND RPJ 3690091
Tetrachloroethene 08/06/10 13:570.2 1ND RPJ 3690091
Toluene 08/06/10 13:570.1 1ND RPJ 3690091
trans-1,2-Dichloroethene 08/06/10 13:570.1 1ND RPJ 3690091
Trichloroethene 08/06/10 13:570.1 1ND RPJ 3690091
Trichlorofluoromethane 08/06/10 13:570.1 1ND RPJ 3690091
Vinyl chloride 08/06/10 13:570.1 1ND RPJ 3690091
Surr: 1,2-Dichloroethane-d4 08/06/10 13:57% 60-140 196.3 RPJ 3690091
Surr: 4-Bromofluorobenzene 08/06/10 13:57% 60-140 199.1 RPJ 3690091
Surr: Toluene-d8 08/06/10 13:57% 60-140 193.2 RPJ 3690091
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
8/25/2010 9:39:10 AM
J - Estimated value between MDL and PQL
MI - Matrix Interference
10071130 Page 38
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Documentation
8/25/2010 9:39:11 AM
10071130 Page 39
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240503
WorkOrder:10071130
Method:D2216
Analysis:PERCENT MOISTURE
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Sample
Result
DUP
Result
RPD RPD
Limit
Sample Duplicate
Original Sample:10071130-06
Analysis Date: 07/30/2010 7:53 Analyst:CCT
RunID:WET_100730I-3681597 Units:wt%
Percent Moisture 28.729 0 20
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-01A MW-11 @ 25`
10071130-02A SB-10 @ 20`
10071130-03A SB-11 @ 25`
10071130-04A SB-12 @ 15`
10071130-05A SB-14 @ 25`
10071130-06A SB-15 @ 25`
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:18 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 40
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:92218
WorkOrder:10071130
Method:E504.1
Analysis:METHOD 504.1
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:07/30/2010 17:26
Preparation Date:07/30/2010 16:03
Analyst:RAH
Prep By:JDFMethodE504
RunID:PCBB_100730A-3683666 Units:ug/L
1,2-Dibromoethane 0.570 0.610 107 60 1400.570 0.501 87.9 19.6 30
Surr: 1-Chloro-2-fluorobenzene 143 145 101 33 15114312386.0 16.4 30
Analyte Result Rep Limit
Method Blank
Analysis Date:07/30/2010 17:06
Preparation Date:07/30/2010 16:03
Analyst:RAH
RunID:PCBB_100730A-3683665 Units:ug/L
Prep By:JDFMethodE504
1,2-Dibromoethane 0.020ND
Surr: 1-Chloro-2-fluorobenzene 33-15174.1
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-07B MW-9
10071130-08B MW-10
10071130-09B MW-11
10071130-10B MW-12
10071130-11B DMW-2
10071130-12B PW-1
10071130-13B PW-2
10071130-14B PW-15
10071130-15B PW-16
10071130-16B PW-18
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:19 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 41
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240428
WorkOrder:10071130
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:07/29/2010 9:24 Analyst:SJA
RunID:HPEE_100728A-3680370 Units:mg/Kg
C9-C10 Aromatics 0.0400 0.0355 88.8 70 1300.0400 0.0366 91.4 2.9 20
Surr: 2,5-Dibromotoluene 200 207 104 70 1302002191105.7 30
Analyte Result Rep Limit
Method Blank
Analysis Date:07/29/2010 7:46 Analyst:SJA
RunID:HPEE_100728A-3680369 Units:mg/Kg
C9-C10 Aromatics 0.0050ND
Surr: 2,5-Dibromotoluene 70-13099.0
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-01A MW-11 @ 25`
10071130-02A SB-10 @ 20`
10071130-03A SB-11 @ 25`
10071130-04A SB-12 @ 15`
10071130-05A SB-14 @ 25`
10071130-06A SB-15 @ 25`
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:19 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 42
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240430
WorkOrder:10071130
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (soil)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:07/29/2010 9:24 Analyst:SJA
RunID:HPEE_100728B-3680390 Units:mg/Kg
C5-C8 Aliphatics 0.300 0.300 100 70 1300.300 0.301 100 0.2 20
C9-C12 Aliphatics 0.280 0.232 82.8 70 1300.280 0.232 82.9 0.1 20
Surr: 2,5-Dibromotoluene 200 206 103 70 1302002181095.6 30
Analyte Result Rep Limit
Method Blank
Analysis Date:07/29/2010 7:46 Analyst:SJA
RunID:HPEE_100728B-3680389 Units:mg/Kg
C5-C8 Aliphatics 0.030ND
C9-C12 Aliphatics 0.035ND Surr: 2,5-Dibromotoluene 70-130100.5
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-01A MW-11 @ 25`
10071130-02A SB-10 @ 20`
10071130-03A SB-11 @ 25`
10071130-04A SB-12 @ 15`
10071130-05A SB-14 @ 25`
10071130-06A SB-15 @ 25`
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:20 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 43
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240579
WorkOrder:10071130
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:07/30/2010 11:53 Analyst:SJA
RunID:HPEE_100728J-3682853 Units:ug/L
C9-C10 Aromatics 40.0 36.7 91.7 70 13040.0 36.2 90.4 1.4 20
Surr: 2,5-Dibromotoluene 200 240 120 70 13020021710810.0 30
Analyte Result Rep Limit
Method Blank
Analysis Date:07/30/2010 11:12 Analyst:SJA
RunID:HPEE_100728J-3682852 Units:ug/L
C9-C10 Aromatics 5.0ND
Surr: 2,5-Dibromotoluene 70-130104.7
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-07A MW-9
10071130-08A MW-10
10071130-09A MW-11
10071130-10A MW-12
10071130-11A DMW-2
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:21 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 44
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240580
WorkOrder:10071130
Method:MA_VPH_EPH
Analysis:Volatile Petroleum Hydrocarbons (water)
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:07/30/2010 11:53 Analyst:SJA
RunID:HPEE_100728K-3682864 Units:ug/L
C5-C8 Aliphatics 300 326 109 70 1303003281090.7 20
C9-C12 Aliphatics 280 249 89.0 70 13028024988.8 0.2 20
Surr: 2,5-Dibromotoluene 200 229 114 70 1302002111058.2 30
Analyte Result Rep Limit
Method Blank
Analysis Date:07/30/2010 11:12 Analyst:SJA
RunID:HPEE_100728K-3682863 Units:ug/L
C5-C8 Aliphatics 30ND
C9-C12 Aliphatics 35ND Surr: 2,5-Dibromotoluene 70-130102.7
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-07A MW-9
10071130-08A MW-10
10071130-09A MW-11
10071130-10A MW-12
10071130-11A DMW-2
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:21 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 45
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:92206
WorkOrder:10071130
Method:SW6010B
Analysis:Total Metals by Method 6010B - water
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte MS Spike Added
MSDResult MSD % Recovery RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult Low Limit High LimitMSResultMS % Recovery
Sample Spiked:10071130-07
MSD Spike Added
Analysis Date: 07/30/2010 13:03
Preparation Date:07/29/2010 14:00
Analyst:SVW
Prep By:SA MethodM3030-C
RunID:ICP7300DV_100730A-3681 Units:ug/L
Lead 1000 952.8 92.91 75 12523.75 203.777989.5 96.58 1000
Analyte Spike Added Result Percent Recovery Lower Limit Upper Limit
Laboratory Control Sample (LCS)
Analysis Date:07/30/2010 12:59
Preparation Date:07/29/2010 14:00
Analyst:SVW
Prep By:SA MethodM3030-C
RunID:ICP7300DV_100730A-3681 Units:ug/L
Lead 1000 982.8 98.28 80 120
Analyte Result Rep Limit
Method Blank
Analysis Date:07/30/2010 12:57
Preparation Date:07/29/2010 14:00
Analyst:SVW
RunID:ICP7300DV_100730A-3681667 Units:ug/L
Prep By:SA MethodM3030-C
Lead 5ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-07C MW-9
10071130-08C MW-10
10071130-09C MW-11
10071130-10C MW-12
10071130-11C DMW-2
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:22 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 46
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:080410A1
WorkOrder:10071130
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/04/2010 23:50
Preparation Date:08/04/2010 23:50
Analyst:CDP
Prep By:MethodSW5035
RunID:HB_100804C-3688349 Units:mg/Kg
Benzene 0.0500 0.0555 111 77 1230.0500 0.0478 95.6 15.0 21
Diisopropyl ether 0.0500 0.0546 109 73 1290.0500 0.0477 95.4 13.5 30
Ethylbenzene 0.0500 0.0527 105 77 1210.0500 0.0458 91.5 14.0 30
Methyl tert-butyl ether 0.0500 0.0527 105 79 1280.0500 0.0435 87.1 19.0 30
Naphthalene 0.0500 0.0519 104 79 1310.0500 0.0449 89.8 14.5 30
Toluene 0.0500 0.0561 112 79 1200.0500 0.0481 96.2 15.4 20
m,p-Xylene 0.100 0.120 120 78 1250.100 0.102 102 16.1 30
o-Xylene 0.0500 0.0523 105 78 1210.0500 0.0453 90.6 14.3 30
Xylenes,Total 0.1500 0.1723 114.6 61 1300.1500 0.1473 98.11 15.5 30
Surr: 1,2-Dichloroethane-d4 50.0 49.1 98.3 50 16650.0 48.1 96.1 2.2 30
Surr: 4-Bromofluorobenzene 50.0 49.8 99.6 79 12350.0 50.0 100 0.4 30
Surr: Toluene-d8 50.0 50.4 101 62 14650.0 49.8 99.6 1.1 30
Analyte Result Rep Limit
Method Blank
Analysis Date:08/05/2010 1:14
Preparation Date:08/05/2010 1:14
Analyst:CDP
RunID:HB_100804C-3688352 Units:mg/Kg
Prep By:MethodSW5035
Benzene 0.0010ND
Diisopropyl ether 0.0050NDEthylbenzene0.0010ND
Methyl tert-butyl ether 0.0050NDNaphthalene0.0050ND
Toluene 0.0050NDm,p-Xylene 0.0020ND
o-Xylene 0.0010NDXylenes,Total 0.0010ND
Surr: 1,2-Dichloroethane-d4 50-166113.3 Surr: 4-Bromofluorobenzene 79-123100.0
Surr: Toluene-d8 62-14698.1
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-01A MW-11 @ 25`
10071130-02A SB-10 @ 20`
10071130-03A SB-11 @ 25`
10071130-04A SB-12 @ 15`
10071130-05A SB-14 @ 25`
10071130-06A SB-15 @ 25`
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:23 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 47
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:080410A1
WorkOrder:10071130
Method:SW8260B
Analysis:Volatile Organics Method 8260B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:23 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 48
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240977
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:08/05/2010 13:02 Analyst:TDD
RunID:XA_100805B-3688638 Units:ug/L
1,1,1,2-Tetrachloroethane 0.10ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.10ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 1.0ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.10ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.10ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.10ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.20ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.10ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.10ND
Hexachlorobutadiene 0.200.21
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-07A MW-9
10071130-08A MW-10
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:23 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 49
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240977
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:05 Analyst:TDD
RunID:XA_100805B-3688636 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 20.6 103 60 14020.0 20.1 101 2.3 20
1,1,1-Trichloroethane 20.0 21.5 107 60 14020.0 23.0 115 6.8 20
1,1,2,2-Tetrachloroethane 20.0 21.0 105 60 14020.0 19.9 99.5 5.5 20
1,1,2-Trichloroethane 20.0 21.2 106 60 14020.0 20.1 100 5.6 20
1,1-Dichloroethane 20.0 18.8 93.9 60 14020.0 19.8 98.9 5.3 20
1,1-Dichloroethene 20.0 18.4 92.2 60 14020.0 21.0 105 12.8 20
1,1-Dichloropropene 20.0 22.0 110 60 14020.0 23.3 116 5.4 20
1,2,3-Trichlorobenzene 20.0 22.8 114 60 14020.0 22.2 111 2.5 20
1,2,3-Trichloropropane 20.0 16.2 80.8 60 14020.0 15.6 78.2 3.3 20
1,2,4-Trichlorobenzene 20.0 22.2 111 60 14020.0 21.5 108 3.2 20
1,2,4-Trimethylbenzene 20.0 19.8 99.2 60 14020.0 20.3 102 2.3 20
1,2-Dibromo-3-chloropropane 20.0 20.2 101 60 14020.0 21.2 106 4.7 20
Analyte Result Rep Limit
Method Blank
Analysis Date:08/05/2010 13:02 Analyst:TDD
RunID:XA_100805B-3688638 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14097.8 Surr: 4-Bromofluorobenzene 60-14098.5
Surr: Toluene-d8 60-14097.2
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:24 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 50
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240977
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:05 Analyst:TDD
RunID:XA_100805B-3688636 Units:ug/L
1,2-Dibromoethane 20.0 20.2 101 60 14020.0 19.5 97.3 4.0 20
1,2-Dichlorobenzene 20.0 20.4 102 60 14020.0 21.3 106 4.4 20
1,2-Dichloroethane 20.0 20.3 102 60 14020.0 21.0 105 3.4 20
1,2-Dichloropropane 20.0 19.1 95.5 60 14020.0 19.6 98.1 2.6 20
1,3,5-Trimethylbenzene 20.0 20.3 102 60 14020.0 20.9 104 2.6 20
1,3-Dichlorobenzene 20.0 19.8 99.0 60 14020.0 20.3 101 2.3 20
1,3-Dichloropropane 20.0 19.9 99.7 60 14020.0 19.8 98.9 0.8 20
1,4-Dichlorobenzene 20.0 20.0 100 60 14020.0 21.0 105 4.5 20
2,2-Dichloropropane 20.0 23.8 119 60 14020.0 25.3 127 6.1 20
2-Chlorotoluene 20.0 19.8 98.9 60 14020.0 20.5 102 3.6 20
4-Chlorotoluene 20.0 20.1 100 60 14020.0 20.9 104 4.0 20
Benzene 20.0 19.9 99.6 60 14020.0 21.0 105 5.5 20
Bromobenzene 20.0 21.2 106 60 14020.0 21.4 107 1.1 20
Bromochloromethane 20.0 23.4 117 60 14020.0 19.1 95.3 20.3 * 20
Bromodichloromethane 20.0 20.5 103 60 14020.0 20.7 103 0.6 20
Bromoform 20.0 22.0 110 60 14020.0 20.7 104 6.2 20
Bromomethane 20.0 19.3 96.5 60 14020.0 21.6 108 11.3 20
Carbon tetrachloride 20.0 22.2 111 60 14020.0 21.8 109 1.8 20
Chlorobenzene 20.0 20.3 102 60 14020.0 20.2 101 0.9 20
Chloroethane 20.0 17.1 85.3 60 14020.0 21.6 108 23.5 * 20
Chloroform 20.0 19.4 96.9 60 14020.0 20.1 100 3.5 20
Chloromethane 20.0 19.3 96.6 60 14020.0 21.7 108 11.4 20
cis-1,2-Dichloroethene 20.0 18.7 93.6 60 14020.0 19.9 99.6 6.2 20
Dibromochloromethane 20.0 22.5 112 60 14020.0 22.0 110 1.8 20
Dibromomethane 20.0 20.0 99.9 60 14020.0 20.1 101 0.6 20
Dichlorodifluoromethane 20.0 23.7 119 60 14020.0 27.1 135 13.3 20
Ethylbenzene 20.0 20.5 102 60 14020.0 19.8 99.2 3.1 20
Hexachlorobutadiene 20.0 23.5 118 60 14020.0 22.8 114 3.1 20
Isopropyl ether 20.0 17.6 88.2 60 14020.0 18.9 94.4 6.8 20
Isopropylbenzene 20.0 22.3 112 60 14020.0 21.5 107 3.8 20
m & p-Xylene 40.0 39.3 98.3 60 14040.0 38.8 97.0 1.3 20
Methyl tert-butyl ether 20.0 17.6 88.0 60 14020.0 19.4 96.9 9.7 20
Methylene chloride 20.0 17.5 87.6 60 14020.0 19.3 96.4 9.5 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:24 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 51
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240977
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:05 Analyst:TDD
RunID:XA_100805B-3688636 Units:ug/L
Naphthalene 20.0 22.3 112 60 14020.0 21.3 106 4.7 20
n-Butylbenzene 20.0 21.2 106 60 14020.0 22.5 112 5.7 20
n-Propylbenzene 20.0 21.6 108 60 14020.0 22.3 112 3.4 20
o-Xylene 20.0 19.8 99.1 60 14020.0 20.2 101 1.9 20
p-Isopropyltoluene 20.0 21.4 107 60 14020.0 21.8 109 1.8 20
sec-Butylbenzene 20.0 21.2 106 60 14020.0 21.6 108 1.9 20
Styrene 20.0 20.8 104 60 14020.0 20.5 103 1.5 20
tert-Butylbenzene 20.0 21.4 107 60 14020.0 21.8 109 1.8 20
Tetrachloroethene 20.0 22.7 114 60 14020.0 21.7 109 4.3 20
Toluene 20.0 20.8 104 60 14020.0 20.7 103 0.8 20
trans-1,2-Dichloroethene 20.0 17.4 87.2 60 14020.0 19.4 96.9 10.6 20
Trichloroethene 20.0 21.6 108 60 14020.0 22.3 112 3.2 20
Trichlorofluoromethane 20.0 22.2 111 60 14020.0 24.6 123 10.5 20
Vinyl chloride 20.0 19.6 98.0 60 14020.0 22.4 112 13.2 20
Surr: 1,2-Dichloroethane-d4 10.0 9.70 97.0 60 14010.0 9.89 98.9 1.9 20
Surr: 4-Bromofluorobenzene 10.0 10.4 104 60 14010.0 9.82 98.2 6.0 20
Surr: Toluene-d8 10.0 9.61 96.1 60 14010.0 10.4 104 7.9 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:24 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 52
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240982
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:08/05/2010 13:56 Analyst:TDD
RunID:XB_100805B-3688711 Units:ug/L
1,1,1,2-Tetrachloroethane 0.10ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.10ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 1.0ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.10ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.10ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.10ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.20ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.10ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.10ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-12A PW-1
10071130-13A PW-2
10071130-14A PW-15
10071130-15A PW-16
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:25 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 53
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240982
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:58 Analyst:TDD
RunID:XB_100805B-3688709 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 21.5 107 60 14020.0 22.5 112 4.6 20
1,1,1-Trichloroethane 20.0 20.5 102 60 14020.0 21.2 106 3.8 20
1,1,2,2-Tetrachloroethane 20.0 20.2 101 60 14020.0 21.2 106 5.1 20
1,1,2-Trichloroethane 20.0 18.8 94.2 60 14020.0 20.1 101 6.5 20
1,1-Dichloroethane 20.0 20.1 100 60 14020.0 21.3 106 5.9 20
1,1-Dichloroethene 20.0 19.7 98.6 60 14020.0 20.6 103 4.2 20
1,1-Dichloropropene 20.0 21.0 105 60 14020.0 22.0 110 4.6 20
1,2,3-Trichlorobenzene 20.0 20.2 101 60 14020.0 20.3 101 0.7 20
1,2,3-Trichloropropane 20.0 20.2 101 60 14020.0 19.4 96.8 4.3 20
1,2,4-Trichlorobenzene 20.0 21.6 108 60 14020.0 21.5 107 0.6 20
1,2,4-Trimethylbenzene 20.0 20.5 102 60 14020.0 20.9 105 2.2 20
1,2-Dibromo-3-chloropropane 20.0 19.7 98.4 60 14020.0 20.2 101 2.6 20
Analyte Result Rep Limit
Method Blank
Analysis Date:08/05/2010 13:56 Analyst:TDD
RunID:XB_100805B-3688711 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14094.5 Surr: 4-Bromofluorobenzene 60-14097.6
Surr: Toluene-d8 60-14095.1
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:25 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 54
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240982
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:58 Analyst:TDD
RunID:XB_100805B-3688709 Units:ug/L
1,2-Dibromoethane 20.0 19.8 99.0 60 14020.0 20.9 105 5.6 20
1,2-Dichlorobenzene 20.0 21.3 107 60 14020.0 21.6 108 1.2 20
1,2-Dichloroethane 20.0 20.2 101 60 14020.0 21.3 107 5.6 20
1,2-Dichloropropane 20.0 19.4 97.1 60 14020.0 20.4 102 5.1 20
1,3,5-Trimethylbenzene 20.0 20.8 104 60 14020.0 21.5 107 3.3 20
1,3-Dichlorobenzene 20.0 20.7 104 60 14020.0 21.2 106 2.2 20
1,3-Dichloropropane 20.0 20.3 102 60 14020.0 20.9 105 2.9 20
1,4-Dichlorobenzene 20.0 19.9 99.6 60 14020.0 20.3 102 2.1 20
2,2-Dichloropropane 20.0 21.9 109 60 14020.0 22.7 113 3.7 20
2-Chlorotoluene 20.0 21.0 105 60 14020.0 21.9 109 3.9 20
4-Chlorotoluene 20.0 21.7 109 60 14020.0 22.1 110 1.5 20
Benzene 20.0 20.6 103 60 14020.0 21.6 108 4.7 20
Bromobenzene 20.0 20.4 102 60 14020.0 21.5 107 5.1 20
Bromochloromethane 20.0 18.2 90.8 60 14020.0 20.2 101 10.4 20
Bromodichloromethane 20.0 20.2 101 60 14020.0 20.6 103 2.0 20
Bromoform 20.0 20.1 100 60 14020.0 20.3 102 1.4 20
Bromomethane 20.0 18.3 91.4 60 14020.0 19.8 99.0 7.9 20
Carbon tetrachloride 20.0 19.8 98.9 60 14020.0 19.2 96.0 3.0 20
Chlorobenzene 20.0 20.5 103 60 14020.0 21.4 107 4.1 20
Chloroethane 20.0 19.0 94.9 60 14020.0 20.6 103 8.3 20
Chloroform 20.0 20.9 105 60 14020.0 22.3 112 6.4 20
Chloromethane 20.0 18.5 92.4 60 14020.0 20.0 100 8.0 20
cis-1,2-Dichloroethene 20.0 20.4 102 60 14020.0 21.4 107 4.9 20
Dibromochloromethane 20.0 21.0 105 60 14020.0 22.2 111 5.4 20
Dibromomethane 20.0 19.2 96.2 60 14020.0 20.5 103 6.5 20
Dichlorodifluoromethane 20.0 23.7 119 60 14020.0 24.7 123 4.0 20
Ethylbenzene 20.0 19.8 99.1 60 14020.0 21.1 106 6.3 20
Hexachlorobutadiene 20.0 20.3 102 60 14020.0 20.5 102 0.5 20
Isopropyl ether 20.0 19.3 96.3 60 14020.0 20.4 102 6.0 20
Isopropylbenzene 20.0 21.0 105 60 14020.0 22.0 110 4.8 20
m & p-Xylene 40.0 33.1 82.6 60 14040.0 34.9 87.2 5.4 20
Methyl tert-butyl ether 20.0 20.4 102 60 14020.0 20.9 105 2.7 20
Methylene chloride 20.0 17.8 89.1 60 14020.0 19.3 96.3 7.8 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:25 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 55
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R240982
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/05/2010 11:58 Analyst:TDD
RunID:XB_100805B-3688709 Units:ug/L
Naphthalene 20.0 20.1 100 60 14020.0 19.5 97.7 2.8 20
n-Butylbenzene 20.0 21.9 109 60 14020.0 22.3 111 1.8 20
n-Propylbenzene 20.0 21.0 105 60 14020.0 21.2 106 1.1 20
o-Xylene 20.0 19.9 99.5 60 14020.0 20.9 104 4.8 20
p-Isopropyltoluene 20.0 21.8 109 60 14020.0 22.4 112 2.6 20
sec-Butylbenzene 20.0 21.6 108 60 14020.0 22.0 110 2.1 20
Styrene 20.0 21.3 107 60 14020.0 22.5 113 5.4 20
tert-Butylbenzene 20.0 21.3 106 60 14020.0 21.9 109 2.6 20
Tetrachloroethene 20.0 21.4 107 60 14020.0 21.9 109 2.3 20
Toluene 20.0 20.0 100 60 14020.0 21.1 105 5.2 20
trans-1,2-Dichloroethene 20.0 20.2 101 60 14020.0 21.1 106 4.7 20
Trichloroethene 20.0 20.6 103 60 14020.0 21.6 108 4.7 20
Trichlorofluoromethane 20.0 20.8 104 60 14020.0 22.1 110 5.8 20
Vinyl chloride 20.0 20.5 102 60 14020.0 21.8 109 6.1 20
Surr: 1,2-Dichloroethane-d4 10.0 9.51 95.1 60 14010.0 9.52 95.2 0.1 20
Surr: 4-Bromofluorobenzene 10.0 10.0 100 60 14010.0 10.3 103 3.2 20
Surr: Toluene-d8 10.0 9.75 97.5 60 14010.0 10.1 101 3.1 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:26 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 56
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R241068
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte Result Rep Limit
Method Blank
Analysis Date:08/06/2010 13:18 Analyst:RPJ
RunID:XB_100806A-3690090 Units:ug/L
1,1,1,2-Tetrachloroethane 0.10ND
1,1,1-Trichloroethane 0.10ND1,1,2,2-Tetrachloroethane 0.10ND
1,1,2-Trichloroethane 0.10ND1,1-Dichloroethane 0.10ND
1,1-Dichloroethene 0.10ND1,1-Dichloropropene 0.10ND
1,2,3-Trichlorobenzene 0.20ND1,2,3-Trichloropropane 0.10ND
1,2,4-Trichlorobenzene 0.10ND1,2,4-Trimethylbenzene 0.10ND
1,2-Dibromo-3-chloropropane 1.0ND1,2-Dibromoethane 0.10ND
1,2-Dichlorobenzene 0.10ND1,2-Dichloroethane 0.20ND
1,2-Dichloropropane 0.10ND
1,3,5-Trimethylbenzene 0.10ND
1,3-Dichlorobenzene 0.10ND
1,3-Dichloropropane 0.10ND
1,4-Dichlorobenzene 0.10ND
2,2-Dichloropropane 0.10ND
2-Chlorotoluene 0.20ND
4-Chlorotoluene 0.10ND
Benzene 0.10ND
Bromobenzene 0.10ND
Bromochloromethane 0.10ND
Bromodichloromethane 0.10ND
Bromoform 0.10ND
Bromomethane 0.10ND
Carbon tetrachloride 0.10ND
Chlorobenzene 0.10ND
Chloroethane 0.20ND
Chloroform 0.10ND
Chloromethane 0.10ND
cis-1,2-Dichloroethene 0.10ND
Dibromochloromethane 0.10ND
Dibromomethane 0.10ND
Dichlorodifluoromethane 0.10ND
Ethylbenzene 0.10ND
Hexachlorobutadiene 0.20ND
Isopropyl ether 0.10ND
Isopropylbenzene 0.20ND
m & p-Xylene 0.10ND
Methyl tert-butyl ether 0.20ND
Methylene chloride 0.20ND
Naphthalene 0.10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
10071130-09A MW-11
10071130-10A MW-12
10071130-11A DMW-2
10071130-16A PW-18
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:26 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 57
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R241068
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/06/2010 11:21 Analyst:RPJ
RunID:XB_100806A-3690087 Units:ug/L
1,1,1,2-Tetrachloroethane 20.0 21.3 107 60 14020.0 21.2 106 0.7 20
1,1,1-Trichloroethane 20.0 19.8 99.2 60 14020.0 20.2 101 1.7 20
1,1,2,2-Tetrachloroethane 20.0 20.8 104 60 14020.0 20.2 101 3.3 20
1,1,2-Trichloroethane 20.0 19.6 98.2 60 14020.0 18.5 92.7 5.8 20
1,1-Dichloroethane 20.0 20.2 101 60 14020.0 20.2 101 0.4 20
1,1-Dichloroethene 20.0 20.3 102 60 14020.0 20.2 101 0.4 20
1,1-Dichloropropene 20.0 20.5 102 60 14020.0 20.4 102 0.4 20
1,2,3-Trichlorobenzene 20.0 20.6 103 60 14020.0 19.6 98.1 4.8 20
1,2,3-Trichloropropane 20.0 19.8 99.1 60 14020.0 20.1 101 1.6 20
1,2,4-Trichlorobenzene 20.0 21.5 107 60 14020.0 20.5 102 4.9 20
1,2,4-Trimethylbenzene 20.0 20.4 102 60 14020.0 19.7 98.3 3.8 20
1,2-Dibromo-3-chloropropane 20.0 21.1 106 60 14020.0 19.5 97.4 8.2 20
Analyte Result Rep Limit
Method Blank
Analysis Date:08/06/2010 13:18 Analyst:RPJ
RunID:XB_100806A-3690090 Units:ug/L
n-Butylbenzene 0.10ND
n-Propylbenzene 0.10NDo-Xylene 0.10ND
p-Isopropyltoluene 0.10NDsec-Butylbenzene 0.10ND
Styrene 0.10NDtert-Butylbenzene 0.10ND
Tetrachloroethene 0.20NDToluene0.10ND
trans-1,2-Dichloroethene 0.10NDTrichloroethene0.10ND
Trichlorofluoromethane 0.10NDVinyl chloride 0.10ND
Surr: 1,2-Dichloroethane-d4 60-14092.1 Surr: 4-Bromofluorobenzene 60-14098.3
Surr: Toluene-d8 60-14098.7
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:26 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 58
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R241068
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/06/2010 11:21 Analyst:RPJ
RunID:XB_100806A-3690087 Units:ug/L
1,2-Dibromoethane 20.0 20.3 102 60 14020.0 19.8 98.9 2.6 20
1,2-Dichlorobenzene 20.0 21.7 108 60 14020.0 21.0 105 3.0 20
1,2-Dichloroethane 20.0 20.1 100 60 14020.0 19.8 98.8 1.6 20
1,2-Dichloropropane 20.0 19.9 99.7 60 14020.0 19.7 98.6 1.1 20
1,3,5-Trimethylbenzene 20.0 20.4 102 60 14020.0 19.9 99.4 2.7 20
1,3-Dichlorobenzene 20.0 20.8 104 60 14020.0 20.7 104 0.3 20
1,3-Dichloropropane 20.0 20.7 103 60 14020.0 20.2 101 2.4 20
1,4-Dichlorobenzene 20.0 20.1 100 60 14020.0 19.5 97.5 2.8 20
2,2-Dichloropropane 20.0 21.4 107 60 14020.0 21.8 109 1.9 20
2-Chlorotoluene 20.0 21.2 106 60 14020.0 20.2 101 4.8 20
4-Chlorotoluene 20.0 21.4 107 60 14020.0 20.7 103 3.5 20
Benzene 20.0 21.0 105 60 14020.0 21.2 106 0.6 20
Bromobenzene 20.0 21.0 105 60 14020.0 21.1 105 0.1 20
Bromochloromethane 20.0 17.4 86.9 60 14020.0 21.4 107 20.9 * 20
Bromodichloromethane 20.0 19.9 99.3 60 14020.0 19.8 98.9 0.4 20
Bromoform 20.0 20.5 103 60 14020.0 19.9 99.5 3.1 20
Bromomethane 20.0 18.3 91.3 60 14020.0 18.9 94.6 3.6 20
Carbon tetrachloride 20.0 18.1 90.4 60 14020.0 17.9 89.4 1.2 20
Chlorobenzene 20.0 20.8 104 60 14020.0 21.0 105 0.8 20
Chloroethane 20.0 19.4 97.2 60 14020.0 19.4 97.0 0.1 20
Chloroform 20.0 20.5 102 60 14020.0 21.0 105 2.3 20
Chloromethane 20.0 18.4 92.0 60 14020.0 19.3 96.3 4.6 20
cis-1,2-Dichloroethene 20.0 20.8 104 60 14020.0 20.9 104 0.2 20
Dibromochloromethane 20.0 21.7 109 60 14020.0 21.8 109 0.2 20
Dibromomethane 20.0 20.1 100 60 14020.0 20.7 103 2.7 20
Dichlorodifluoromethane 20.0 21.7 108 60 14020.0 20.9 104 3.8 20
Ethylbenzene 20.0 20.2 101 60 14020.0 20.2 101 0.1 20
Hexachlorobutadiene 20.0 19.3 96.5 60 14020.0 18.0 89.9 7.1 20
Isopropyl ether 20.0 20.1 100 60 14020.0 19.8 99.2 1.3 20
Isopropylbenzene 20.0 20.9 104 60 14020.0 20.9 104 0.2 20
m & p-Xylene 40.0 33.5 83.8 60 14040.0 33.4 83.6 0.3 20
Methyl tert-butyl ether 20.0 21.3 107 60 14020.0 21.3 107 0.0 20
Methylene chloride 20.0 18.6 93.0 60 14020.0 19.1 95.6 2.7 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:27 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 59
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Quality Control Report
ATC ASSOCIATES, INC.
89.03451.1018
Lab Batch ID:R241068
WorkOrder:10071130
Method:SM6200 B
Analysis:Volatile Organics by GCMS: SM6200 B
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:08/06/2010 11:21 Analyst:RPJ
RunID:XB_100806A-3690087 Units:ug/L
Naphthalene 20.0 20.1 101 60 14020.0 19.3 96.7 4.1 20
n-Butylbenzene 20.0 20.7 103 60 14020.0 20.3 101 2.1 20
n-Propylbenzene 20.0 20.7 103 60 14020.0 20.7 103 0.0 20
o-Xylene 20.0 19.9 99.3 60 14020.0 20.1 101 1.3 20
p-Isopropyltoluene 20.0 21.1 106 60 14020.0 20.5 103 3.0 20
sec-Butylbenzene 20.0 20.8 104 60 14020.0 19.9 99.6 4.1 20
Styrene 20.0 21.7 108 60 14020.0 21.8 109 0.6 20
tert-Butylbenzene 20.0 21.0 105 60 14020.0 20.2 101 3.9 20
Tetrachloroethene 20.0 21.8 109 60 14020.0 21.7 108 0.3 20
Toluene 20.0 20.2 101 60 14020.0 20.1 100 0.7 20
trans-1,2-Dichloroethene 20.0 20.9 104 60 14020.0 21.2 106 1.3 20
Trichloroethene 20.0 21.7 108 60 14020.0 21.2 106 2.2 20
Trichlorofluoromethane 20.0 20.8 104 60 14020.0 20.3 102 2.3 20
Vinyl chloride 20.0 20.7 103 60 14020.0 20.6 103 0.4 20
Surr: 1,2-Dichloroethane-d4 10.0 9.42 94.2 60 14010.0 9.32 93.2 1.1 20
Surr: 4-Bromofluorobenzene 10.0 10.1 101 60 14010.0 10.0 100 0.4 20
Surr: Toluene-d8 10.0 9.72 97.2 60 14010.0 9.81 98.1 0.9 20
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
8/25/2010 9:39:27 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
10071130 Page 60
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Chain of Custody
And
Sample Receipt Checklist
8/25/2010 9:39:27 AM
10071130 Page 61
Sample Receipt Checklist
LAFAYETTE LABORATORY
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:10071130
Date and Time Received:7/29/2010 9:15:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:2.5°C
Received By:SRS
SPL Representative:
Non Conformance Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
8/25/2010 9:39:28 AM
10071130 Page 62
VP
H (Ali
phatics
/Aromatics
) Labo
ratory Repo
rting Fo
rm
Continu
ed
Cli
en
t
Na
me
Site Lo
cation
INCLUD
E APP
ROPRIATE UN
ITS:
Sample Inform
ation and Analytical
Res
ults
Sample Identification
MW-9
MW-10
MW-11
MW-12
DMW-2
Sample Matrix
Da
te Co
ll
ected
Da
te Re
ceived
Da
te Extracted
Da
te Ana
lyz
ed
Dry
Wei
ght
Dil
ution
F
actor
C5
- C8
Ali
ph
a
tics*
C9 - C1
2
Ali
ph
a
tics*
C9
- C1
0
Ar
omatics*
Surr
og
a
te % Re
covery
- PID
Surr
og
a
te % Re
covery
- F
I
D
*U
nadju
sted valu
e.
Should exclu
d
e t
he concentration of any surr
ogate(s),
in
ternal standards, an
d
/or concentrations of other rang
es t
hat
elu
te within
t
he specified rang
e.
Perc
en
t
Re
covery - F
ortified
Blan
k (S
pike) - PID
Re
lative Perc
ent Diff
eren
ce - PID Du
p
li
cate

C5
-C8

Ali
p
h
atic

C9
-C1
2

Ali
p
h
atic

C9
-C1
0

Aroma
tic
WATER
7/28
/20
1
0
7/28
/20
1
0
7/29
/20
1
0
7/30
/20
1
0
NA 1 ND ND ND
10
1
97.6
WATER
WATER
WATER
WATER
7/28
/20
1
0
7/28
/20
1
0
7/28
/20
10
7/28
/20
1
0
7/28
/20
1
0
7/28
/20
1
0
7/28
/20
10
7/28
/20
1
0
7/29
/20
1
0
7/29
/20
1
0
7/29
/20
10
7/29
/20
1
0
7/30
/20
1
0
7/30
/20
1
0
7/30
/20
10
7/30
/20
1
0
NA
NA
NA
NA
1
20
/50
1
1
ND
75
0
0
ND
ND
ND
24
0
0
0
ND
ND
ND
57
0
0
ND
ND
10
2
10
4
11
4
11
6
10
1
100/10
7
11
0
11
2
NANA
NA
91
.7
NA
1.4
Pr
oject
Na
me
ATC ASSOCIATES
,
I
NC
.
89
.03
451.1018
CAJ
AHS MOUN
TAIN SUPE
RETT
E
La
b
oratory Na
me
Sou
the
rn Petroleum Labo
ratories
NC
Ce
rtification
# (La
b
)18
7
revision 4/5/05
Option 1 = Establ
i
shed fill line on
vial

Option 2 = Sampl
i
n
g
Device (in
d
i
cate brand, e.g. Encore)

Option 3 = F
ield
weig
h
t
of soil
Perc
en
t
Re
covery - F
ortified
Blan
k (S
pike) - F
I
D
10
9
89
.0
NA
Re
lative Perc
ent Diff
eren
ce - F
I
D Du
p
li
cate
0.7
0.2
NA
Perc
en
t
Re
covery - Matrix (S
pike) - PID
NA
NA
NA
Perc
en
t
Re
covery - Matrix (S
pike) - F
I
D
NA
NA
NA
La
b
I
D
10
0
7
1
1
3
0
-07
10
0
7
1
1
3
0
-08
10
0
71130-09
10
0
7
1
1
3
0
-10
10
0
7
1
1
3
0
-11
NC
=

N
ot
calc
ulated
(Sample exceeds spike by f
actor of
4 or more)
Attachment 2
VPH Laboratory Reporting Form
Calibration and QA/QC Information
Initial Calibration Date
Calibration Ranges and Limits
Range MDL ML RL
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
NOTE: Please include units as appropriate
Method of Quantitation (check one): Curve or Average Response Factor
Calibration Concentration Levels
Range Levels
%RSD
CCC
6
30
120
240
600
1200
2400
3600
7
35
140
280
700
1400
2800
4200
1
5
20
40
100
200
400
600
C5 - C8
Aliphatics
C9 - C12
Aliphatics
C9 - C10
Aromatics
NOTE: Please include units as appropriate
Calibration Check Date
Calibration Check
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
600
700
100
10.4
1.5
2.0
MDL = Method Detection Limit
ML = Minimum Limit
RL = Reportable Limit
RPD = Relative Percent Difference
%RSD = Percent Relative Standard Deviation
CCC = Correlation Coefficient of Curve
revision 4/5/05
6.46
17.30
22.93
7/30/2010
10.323 ug/L
8.1734 ug/L
2.9269 ug/L
30 ug/L
35 ug/L
5 ug/L
30 ug/L
35 ug/L
5 ug/L
07/29/10
Range Level RPD
VP
H (Ali
phatics
/Aromatics
) Labo
ratory Repo
rting Fo
rm
Continu
ed
Cli
en
t
Na
me
Site Lo
cation
INCLUD
E APP
ROPRIATE UN
ITS:
Sample Inform
ation and Analytical
Res
ults
Sample Identification
MW-11
@

25
'
SB-10 @

20
'
SB
-
11
@

25
'
SB
-
12
@

15
'
SB
-
14
@

25
'
SB
-
15
@

25
'
Sample Matrix
Da
te Co
ll
ected
Da
te Re
ceived
Da
te Extracted
Da
te Ana
lyz
ed
Dry
Wei
ght
Dil
ution
F
actor
C5
- C8
Ali
ph
a
tics*
C9 - C1
2
Ali
ph
a
tics*
C9
- C1
0
Ar
omatics*
Surr
og
a
te % Re
covery
- PID
Surr
og
a
te % Re
covery
- F
I
D
*U
nadju
sted valu
e.
Should exclu
d
e t
he concentration of any surr
ogate(s),
in
ternal standards, an
d
/or concentrations of other rang
es t
hat
elu
te within
t
he specified rang
e.
Perc
en
t
Re
covery - F
ortified
Blan
k (S
pike) - PID
Re
lative Perc
ent Diff
eren
ce - PID Du
p
li
cate

C5
-C8

Ali
p
h
atic

C9
-C1
2

Ali
p
h
atic

C9
-C1
0

Aroma
tic
SOI
L
7/27
/20
1
0
7/27
/20
1
0
7/29
/20
1
0
7/29
/20
1
0
69
.73
10
0
ND
4.5 ND
10
4
10
2
SOIL
SOI
L
SOI
L
SOIL
SOI
L
7/27
/20
1
0
7/27
/20
1
0
7/27
/20
10
7/27
/20
1
0
7/28
/20
1
0
7/27
/20
1
0
7/27
/20
1
0
7/27
/20
10
7/27
/20
1
0
7/28
/20
1
0
7/29
/20
1
0
7/29
/20
1
0
7/29
/20
10
7/29
/20
1
0
7/29
/20
1
0
7/29
/20
1
0
7/29
/20
1
0
7/29
/20
10
7/29
/20
1
0
7/29
/20
1
0
78
81
.3
74
.43
82
.3
71
.33
10
0
10
0
10
0
10
0
10
0
ND
ND
ND
ND
ND
ND
4
ND
ND
ND
ND
0.99
ND
ND
ND
10
0
94
.5
93
.7
92
.3
90
.1
98
.7
93
.6
94
.0
92
.7
90
.5
NANA
NA
88
.8
NA
2.9
Pr
oject
Na
me
ATC ASSOCIATES
,
I
NC
.
89
.03
451.1018
CAJ
AHS MOUN
TAIN SUPE
RETT
E
La
b
oratory Na
me
Sou
the
rn Petroleum Labo
ratories
NC
Ce
rtification
# (La
b
)18
7
revision 4/5/05
Option 1 = Establ
i
shed fill line on
vial

Option 2 = Sampl
i
n
g
Device (in
d
i
cate brand, e.g. Encore)

Option 3 = F
ield
weig
h
t
of soil
Perc
en
t
Re
covery - F
ortified
Blan
k (S
pike) - F
I
D
10
0
82
.8
NA
Re
lative Perc
ent Diff
eren
ce - F
I
D Du
p
li
cate
0.2
0.1
NA
Perc
en
t
Re
covery - Matrix (S
pike) - PID
NA
NA
NA
Perc
en
t
Re
covery - Matrix (S
pike) - F
I
D
NA
NA
NA
La
b
I
D
10
0
7
1
1
3
0
-01
10
0
7
1
1
3
0
-02
10
0
71130-03
10
0
7
1
1
3
0
-04
10
0
7
1
1
3
0
-05
10
0
71130-06
NC
=

N
ot
calc
ulated
(Sample exceeds spike by f
actor of
4 or more)
Attachment 2
VPH Laboratory Reporting Form
Calibration and QA/QC Information
Initial Calibration Date
Calibration Ranges and Limits
Range MDL ML RL
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
NOTE: Please include units as appropriate
Method of Quantitation (check one): Curve or Average Response Factor
Calibration Concentration Levels
Range Levels
%RSD
CCC
6
30
120
240
600
1200
2400
3600
7
35
140
280
700
1400
2800
4200
1
5
20
40
100
200
400
600
C5 - C8
Aliphatics
C9 - C12
Aliphatics
C9 - C10
Aromatics
NOTE: Please include units as appropriate
Calibration Check Date
Calibration Check
C5 - C8 Aliphatics
C9 - C12 Aliphatics
C9 - C10 Aromatics
600
700
100
13.2
4.6
5.2
MDL = Method Detection Limit
ML = Minimum Limit
RL = Reportable Limit
RPD = Relative Percent Difference
%RSD = Percent Relative Standard Deviation
CCC = Correlation Coefficient of Curve
revision 4/5/05
6.46
17.30
22.93
7/29/2010
29.9245 ug/Kg
17.9792 ug/Kg
2.8608 ug/Kg
30 ug/Kg
35 ug/Kg
5 ug/Kg
30 ug/Kg
35 ug/Kg
5 ug/Kg
07/29/10
Range Level RPD

APPENDIX F

AQUIFER SLUG TEST DATA AND BIOSCREEN MODEL RUNS
0. 8. 16. 24. 32. 40.
0.001
0.01
0.1
1.
Time (min)
Di
s
p
l
a
c
e
m
e
n
t

(
f
t
)
WELL TEST ANALYSIS
Data Set: S:\...\MW-6 Slug Out Bouwer-Rice - Final.aqt
Date: 10/29/10 Time: 17:22:38
PROJECT INFORMATION
Company: ATC Associates
Client: Cajah's
Project: 89.03451.1018
Location: Lenoir, NC
Test Well: MW-6
Test Date: 3-15-10
AQUIFER DATA
Saturated Thickness: 42.08 ft Anisotropy Ratio (Kz/Kr): 1.
WELL DATA (MW-6)
Initial Displacement: 0.928 ft Static Water Column Height: 12.08 ft
Total Well Penetration Depth: 12.08 ft Screen Length: 12.08 ft
Casing Radius: 0.344 ft Well Radius: 0.083 ft
Gravel Pack Porosity: 0.35
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 1.643 ft/day y0 = 0.09452 ft
AQTESOLV for Windows
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-6 Slug Out Bouwer-Rice - Final.aqtDate: 10/29/10Time: 17:21:55
PROJECT INFORMATION
Company: ATC AssociatesClient: Cajah'sProject: 89.03451.1018Location: Lenoir, NCTest Date: 3-15-10Test Well: MW-6
AQUIFER DATA
Saturated Thickness: 42.08 ftAnisotropy Ratio (Kz/Kr): 1.
SLUG TEST WELL DATA
Test Well: MW-6
X Location: 0. ftY Location: 0. ft
Initial Displacement: 0.928 ftStatic Water Column Height: 12.08 ftCasing Radius: 0.344 ftWell Radius: 0.083 ftWell Skin Radius: 0.083 ftScreen Length: 12.08 ftTotal Well Penetration Depth: 12.08 ftCorrected Casing Radius (Bouwer-Rice Method): 0.2817 ftGravel Pack Porosity: 0.35
No. of Observations: 98
Observation DataTime (min)Displacement (ft)Time (min)Displacement (ft)0.01667 0.333 1.933 0.0810.01667 0.062 2.05 0.080.03333 0.092 2.183 0.0770.03333 0.121 2.317 0.0770.05 0.109 2.45 0.0750.05 0.125 2.6 0.0750.06667 0.108 2.767 0.0710.08333 0.109 2.917 0.0730.1 0.104 3.1 0.070.1167 0.105 3.3 0.0670.1333 0.104 3.5 0.0680.15 0.105 3.7 0.0650.1667 0.104 3.917 0.0630.1833 0.103 4.167 0.0610.2 0.105 4.417 0.0610.2167 0.102 4.667 0.0570.2333 0.101 4.95 0.0560.25 0.101 5.25 0.0550.2833 0.1 5.567 0.0530.3 0.098 5.9 0.0530.3167 0.099 6.25 0.0520.3333 0.098 6.617 0.0470.3667 0.098 7.017 0.0460.3833 0.098 7.45 0.0440.4167 0.096 7.883 0.0420.45 0.098 8.35 0.040.4667 0.096 8.85 0.0370.5 0.095 9.383 0.035
10/29/10 1 17:21:55
AQTESOLV for Windows
Time (min)Displacement (ft)Time (min)Displacement (ft)0.5333 0.095 9.95 0.0350.5667 0.094 10.55 0.0330.6167 0.096 11.15 0.0290.65 0.091 11.85 0.0290.7 0.095 12.55 0.0280.7333 0.092 13.25 0.0260.7833 0.093 14.05 0.0230.8333 0.091 14.95 0.0230.8833 0.092 15.75 0.0210.95 0.091 16.75 0.0191. 0.09 17.75 0.0161.067 0.089 18.75 0.0151.133 0.089 19.85 0.0151.2 0.087 21.05 0.0121.267 0.086 22.35 0.0111.35 0.086 23.65 0.0121.45 0.085 25.05 0.011.517 0.085 26.55 0.0071.617 0.083 28.15 0.0081.717 0.083 29.75 0.0051.817 0.081 31.55 0.005
SOLUTION
Slug TestAquifer Model: UnconfinedSolution Method: Bouwer-Riceln(Re/rw): 3.393
VISUAL ESTIMATION RESULTS
Estimated Parameters
Parameter EstimateK 1.643 ft/dayy0 0.09452 ft
K = 0.0005796 cm/secT = K*b = 69.14 ft²/day (0.7434 sq. cm/sec)
10/29/10 2 17:21:55
0. 12. 24. 36. 48. 60.
0.001
0.01
0.1
1.
Time (min)
Di
s
p
l
a
c
e
m
e
n
t

(
f
t
)
WELL TEST ANALYSIS
Data Set: S:\...\MW-5 Slug Out Bouwer-Rice-Final.aqt
Date: 10/29/10 Time: 17:23:53
PROJECT INFORMATION
Company: ATC Associates
Client: Cajah's
Project: 89.03451.1018
Location: Lenoir, NC
Test Well: MW-5
Test Date: 3-15-10
AQUIFER DATA
Saturated Thickness: 42.39 ft Anisotropy Ratio (Kz/Kr): 1.
WELL DATA (MW-5)
Initial Displacement: 1.217 ft Static Water Column Height: 12.39 ft
Total Well Penetration Depth: 12.39 ft Screen Length: 12.39 ft
Casing Radius: 0.344 ft Well Radius: 0.083 ft
Gravel Pack Porosity: 0.35
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 1.647 ft/day y0 = 0.2709 ft
AQTESOLV for Windows
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-5 Slug Out Bouwer-Rice-Final.aqtDate: 10/29/10Time: 17:28:40
PROJECT INFORMATION
Company: ATC AssociatesClient: Cajah'sProject: 89.03451.1018Location: Lenoir, NCTest Date: 3-15-10Test Well: MW-5
AQUIFER DATA
Saturated Thickness: 42.39 ftAnisotropy Ratio (Kz/Kr): 1.
SLUG TEST WELL DATA
Test Well: MW-5
X Location: 0. ftY Location: 0. ft
Initial Displacement: 1.217 ftStatic Water Column Height: 12.39 ftCasing Radius: 0.344 ftWell Radius: 0.083 ftWell Skin Radius: 0.083 ftScreen Length: 12.39 ftTotal Well Penetration Depth: 12.39 ftCorrected Casing Radius (Bouwer-Rice Method): 0.2817 ftGravel Pack Porosity: 0.35
No. of Observations: 102
Observation DataTime (min)Displacement (ft)Time (min)Displacement (ft)0.01667 0.267 3.05 0.2020.03333 0.865 3.233 0.1980.05 0.779 3.433 0.1930.06667 0.739 3.65 0.1870.08333 0.669 3.867 0.1820.1 0.635 4.1 0.1750.1167 0.563 4.35 0.1720.1333 0.532 4.617 0.170.15 0.5 4.9 0.1620.1667 0.472 5.2 0.1560.1833 0.45 5.5 0.150.2 0.429 5.85 0.1460.2167 0.412 6.2 0.1390.2333 0.399 6.567 0.1320.2667 0.389 6.967 0.1290.2833 0.379 7.383 0.1210.3167 0.372 7.833 0.110.3333 0.362 8.3 0.1080.3667 0.355 8.8 0.1060.3833 0.349 9.333 0.0990.4167 0.344 9.883 0.0930.45 0.339 10.5 0.080.4833 0.333 11.08 0.0840.5167 0.325 11.78 0.0770.55 0.322 12.48 0.0720.6 0.317 13.18 0.0670.6333 0.31 13.98 0.0620.6833 0.307 14.88 0.061
10/29/10 1 17:28:40
AQTESOLV for Windows
Time (min)Displacement (ft)Time (min)Displacement (ft)0.7333 0.302 15.68 0.0560.7833 0.295 16.68 0.050.8333 0.292 17.68 0.0450.8833 0.285 18.68 0.0420.95 0.283 19.78 0.0371. 0.275 20.98 0.0321.083 0.272 22.28 0.031.15 0.268 23.58 0.0271.217 0.264 24.98 0.0261.3 0.26 26.48 0.0221.383 0.261 28.08 0.021.467 0.253 29.68 0.0171.567 0.249 31.48 0.0181.667 0.245 33.38 0.0151.767 0.241 35.38 0.0151.883 0.238 37.48 0.0122. 0.233 39.68 0.0112.133 0.231 42.08 0.0132.25 0.225 44.58 0.0092.4 0.218 47.18 0.0082.55 0.214 49.98 0.0112.7 0.211 52.98 0.012.867 0.207 56.08 0.006
SOLUTION
Slug TestAquifer Model: UnconfinedSolution Method: Bouwer-Riceln(Re/rw): 3.415
VISUAL ESTIMATION RESULTS
Estimated Parameters
Parameter EstimateK 1.647 ft/dayy0 0.2709 ft
K = 0.0005809 cm/secT = K*b = 69.8 ft²/day (0.7505 sq. cm/sec)
10/29/10 2 17:28:40
0. 4. 8. 12. 16. 20.
0.001
0.01
0.1
1.
Time (min)
Di
s
p
l
a
c
e
m
e
n
t

(
f
t
)
WELL TEST ANALYSIS
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-1D Slug Out Bouwer-Rice.aqt
Date: 10/29/10 Time: 17:29:55
PROJECT INFORMATION
Company: ATC Associates
Client: Cajah's
Project: 89.03451.1018
Location: Lenoir, NC
Test Well: MW-1D
Test Date: 3-15-10
AQUIFER DATA
Saturated Thickness: 41.92 ft Anisotropy Ratio (Kz/Kr): 1.
WELL DATA (MW-1D)
Initial Displacement: 0.927 ft Static Water Column Height: 41.92 ft
Total Well Penetration Depth: 41.92 ft Screen Length: 5. ft
Casing Radius: 0.344 ft Well Radius: 0.083 ft
Gravel Pack Porosity: 0.35
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 26.39 ft/day y0 = 0.2034 ft
AQTESOLV for Windows
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-1D Slug Out Bouwer-Rice.aqtDate: 10/29/10Time: 17:30:08
PROJECT INFORMATION
Company: ATC AssociatesClient: Cajah'sProject: 89.03451.1018Location: Lenoir, NCTest Date: 3-15-10Test Well: MW-1D
AQUIFER DATA
Saturated Thickness: 41.92 ftAnisotropy Ratio (Kz/Kr): 1.
SLUG TEST WELL DATA
Test Well: MW-1D
X Location: 0. ftY Location: 0. ft
Initial Displacement: 0.927 ftStatic Water Column Height: 41.92 ftCasing Radius: 0.344 ftWell Radius: 0.083 ftWell Skin Radius: 0.083 ftScreen Length: 5. ftTotal Well Penetration Depth: 41.92 ftCorrected Casing Radius (Bouwer-Rice Method): 0.2817 ftGravel Pack Porosity: 0.35
No. of Observations: 76
Observation DataTime (min)Displacement (ft)Time (min)Displacement (ft)0.01667 0.903 1.533 0.1620.03333 0.869 1.633 0.1470.05 0.84 1.733 0.1350.06667 0.825 1.85 0.1240.08333 0.809 1.967 0.1110.1 0.796 2.1 0.0980.1167 0.779 2.233 0.0880.1333 0.747 2.367 0.080.15 0.731 2.517 0.0720.1667 0.717 2.683 0.0620.2 0.699 2.833 0.0540.2167 0.682 3.017 0.0470.2333 0.664 3.217 0.0430.25 0.645 3.417 0.0370.2833 0.626 3.617 0.0320.3 0.609 3.833 0.030.3333 0.59 4.083 0.0230.3667 0.571 4.333 0.020.3833 0.551 4.583 0.0170.4167 0.532 4.867 0.0150.45 0.511 5.167 0.0140.4833 0.492 5.483 0.0110.5333 0.472 5.817 0.0110.5667 0.45 6.167 0.0090.6167 0.427 6.533 0.0060.65 0.406 6.933 0.0060.7 0.388 7.367 0.0070.75 0.367 7.8 0.004
10/29/10 1 17:30:08
AQTESOLV for Windows
Time (min)Displacement (ft)Time (min)Displacement (ft)0.8 0.347 8.267 0.0040.8667 0.328 8.767 0.0040.9167 0.307 9.3 0.0050.9833 0.286 9.867 0.0031.05 0.268 10.47 0.0041.117 0.247 11.07 0.0041.183 0.23 11.77 0.0031.267 0.211 12.47 0.0011.367 0.194 13.17 0.0031.433 0.181 13.97 0.002
SOLUTION
Slug TestAquifer Model: UnconfinedSolution Method: Bouwer-Riceln(Re/rw): 4.415
VISUAL ESTIMATION RESULTS
Estimated Parameters
Parameter EstimateK 26.39 ft/dayy0 0.2034 ft
K = 0.009311 cm/secT = K*b = 1106.4 ft²/day (11.9 sq. cm/sec)
10/29/10 2 17:30:08
0. 4. 8. 12. 16. 20.
0.001
0.01
0.1
1.
Time (min)
Di
s
p
l
a
c
e
m
e
n
t

(
f
t
)
WELL TEST ANALYSIS
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-1D Slug Out Hvorslev.aqt
Date: 10/29/10 Time: 17:31:11
PROJECT INFORMATION
Company: ATC Associates
Client: Cajah's
Project: 89.03451.1018
Location: Lenoir, NC
Test Well: MW-1D
Test Date: 3-15-10
AQUIFER DATA
Saturated Thickness: 41.92 ft Anisotropy Ratio (Kz/Kr): 1.
WELL DATA (MW-1D)
Initial Displacement: 0.927 ft Static Water Column Height: 41.92 ft
Total Well Penetration Depth: 41.92 ft Screen Length: 5. ft
Casing Radius: 0.344 ft Well Radius: 0.083 ft
Gravel Pack Porosity: 0.35
SOLUTION
Aquifer Model: Unconfined Solution Method: Hvorslev
K = 28.64 ft/day y0 = 0.2034 ft
AQTESOLV for Windows
Data Set: S:\Cary Oil Co\Cajah Mountain\CSA\SlugTest\Revisions\MW-1D Slug Out Hvorslev.aqtDate: 10/29/10Time: 17:31:24
PROJECT INFORMATION
Company: ATC AssociatesClient: Cajah'sProject: 89.03451.1018Location: Lenoir, NCTest Date: 3-15-10Test Well: MW-1D
AQUIFER DATA
Saturated Thickness: 41.92 ftAnisotropy Ratio (Kz/Kr): 1.
SLUG TEST WELL DATA
Test Well: MW-1D
X Location: 0. ftY Location: 0. ft
Initial Displacement: 0.927 ftStatic Water Column Height: 41.92 ftCasing Radius: 0.344 ftWell Radius: 0.083 ftWell Skin Radius: 0.083 ftScreen Length: 5. ftTotal Well Penetration Depth: 41.92 ftCorrected Casing Radius (Bouwer-Rice Method): 0.2817 ftGravel Pack Porosity: 0.35
No. of Observations: 76
Observation DataTime (min)Displacement (ft)Time (min)Displacement (ft)0.01667 0.903 1.533 0.1620.03333 0.869 1.633 0.1470.05 0.84 1.733 0.1350.06667 0.825 1.85 0.1240.08333 0.809 1.967 0.1110.1 0.796 2.1 0.0980.1167 0.779 2.233 0.0880.1333 0.747 2.367 0.080.15 0.731 2.517 0.0720.1667 0.717 2.683 0.0620.2 0.699 2.833 0.0540.2167 0.682 3.017 0.0470.2333 0.664 3.217 0.0430.25 0.645 3.417 0.0370.2833 0.626 3.617 0.0320.3 0.609 3.833 0.030.3333 0.59 4.083 0.0230.3667 0.571 4.333 0.020.3833 0.551 4.583 0.0170.4167 0.532 4.867 0.0150.45 0.511 5.167 0.0140.4833 0.492 5.483 0.0110.5333 0.472 5.817 0.0110.5667 0.45 6.167 0.0090.6167 0.427 6.533 0.0060.65 0.406 6.933 0.0060.7 0.388 7.367 0.0070.75 0.367 7.8 0.004
10/29/10 1 17:31:24
AQTESOLV for Windows
Time (min)Displacement (ft)Time (min)Displacement (ft)0.8 0.347 8.267 0.0040.8667 0.328 8.767 0.0040.9167 0.307 9.3 0.0050.9833 0.286 9.867 0.0031.05 0.268 10.47 0.0041.117 0.247 11.07 0.0041.183 0.23 11.77 0.0031.267 0.211 12.47 0.0011.367 0.194 13.17 0.0031.433 0.181 13.97 0.002
SOLUTION
Slug TestAquifer Model: UnconfinedSolution Method: HvorslevLog Factor: 0.2087
VISUAL ESTIMATION RESULTS
Estimated Parameters
Parameter EstimateK 28.64 ft/dayy0 0.2034 ft
K = 0.0101 cm/secT = K*b = 1200.6 ft²/day (12.91 sq. cm/sec)
10/29/10 2 17:31:24

APPENDIX G

HEALTH AND SAFETY PLAN

ATC ASSOCIATES INC.

ENVIRONMENTAL SITE SAFETY PLAN

CAJA MOUNTAIN
1990 Connelly Springs Road
Lenoir, North Carolina
NC DENR Fac ID # 0.004593
Project No. 89.03451.10018

1 S:\\MISCPROJ\97-7093_H&SPLAN.DOC

ENVIRONMENTAL SITE SAFETY PLAN
FOR PETROLEUM FACILITIES

Important: Please forward one copy of completed document to the reviewer three (3) working days prior to project start up and maintain a copy
on site. Place signed copy in project file.
Items marked with "1910.120..." are required by 29 CFR 1910.120 in the paragraph noted.

A. GENERAL INFORMATION (1910.120(c)(4))

Project Name: Caja Mountain Limited Phase II ESA Project Number: 89.03451.1018
Location: 2990 Connelly Springs, Lenoir, NC
Client Name: Cary Oil
Plan Prepared by: Diana Lanier Date: February 11, 2008
Plan Approved by: Date:
Project Start Date: February 12, 2008
Installation Start Date: N/A

B. SITE DESCRIPTION (1910.120(c)(4))
Facility History: A retail gasoline station is currently in operation on the site

Number of Tank(s): 3 USTs
Volume of Tank(s): Unknown at this time.
Approx. Volume of Material in Tank(s): Unknown at this time.
General Site Description: Retail gasoline dispensing station.

2 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
C. PROJECT OBJECTIVE(S) (1910.120(b)(3))
(Description of work area activities planned)

Hollow Stem Auger or DPT soil and groundwater sampling.

D. PROJECT ORGANIZATION (1910.120(b)(2))

Team Member Responsibility Type of Training
Bill McGuinness Project Manager A B
Gordon Little Project Manager A B
Kurt Ness Project Manager A B
Richard Karpinski Project Manager A B
Diana Lanier Staff Scientist A B
JD Taylor Staff Scientist A B
Diana Lanier Staff Scientist A B
Natalie Corbin Staff Scientist A B
Nathan Roberts Staff Scientist A B
A = 8 hr. OSHA Refresher
C = CPR Training
B = 40 hr. OSHA Training
D = First Aid Training

E. CHEMICAL HAZARD ANALYSIS (1910.120(b)(4))

Contaminant %
LEL/UEL
FLASH
POINT
Routes of Exposure Primary
Constituents
OSHA PEL/
NIOSH REL*
IDLH
Gasoline 1.4/7.6 -45ºF INH, ABS, ING,
CON
Benzene 0.1 ppm/
1 ppm
500 ppm
Toluene 100 ppm/
200 ppm
500 ppm
Ethylbenzene 100 ppm/
100 ppm
800 ppm
Xylenes 100 ppm/
100 ppm
900 ppm

Diesel Fuel

1.3/6

110ºF
INH, ABS, ING,
CON
Naphthalene 10 ppm/
10 ppm
250 ppm
Xylenes 100 ppm/
100 ppm
900 ppm
Isopropyl 2/12.7 53ºF INH, ING, CON Isopropyl Alcohol 400 ppm/ 2,000 ppm
Alcohol 400ppm
Liquinox - - ING, DERM - - 12,000 ppm

Notes :
1. Material Safety Data Sheets attached for gasoline and diesel fuel.
2. * = Time weighted average.

3 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
F. OTHER HAZARDS

Heat Stress: X Yes no. If yes, please specify precautions to be taken:
Drink plenty of fluids; rest in shaded areas or in air-conditioned store; take a break every hour.
Do not rely on soft drinks for hydration, instead consume water and gatorade.

Cold Stress: X Yes no. If yes, please specify precautions to be taken:
Dress in several thin layers; take rest breaks in warm areas as necessary; bring extra clothing for
a “change out” if existing clothing becomes wet.

Excessive Noise: X Yes no. If yes, please specify precautions to be taken:
Ear protection as required around heavy equipment and saw cutting operations. Ear protection is
mandatory around the drill rig.

Confined Space Entry: Yes X no. If yes, please attach copy of Confined Space Entry permit.
Open Excavations: Yes X no. If yes, is entry into excavation required?
Yes X no. If so, specify precautions to be taken:

Welding and/or Cutting: X Yes no.
Eye protection as required.

Heavy Equipment Operation: X Yes no.
Experienced equipment operators only.
Wear hard hat and steel-toed safety shoes at all times; wear safety glasses when appropriate; wear ear plugs
as required.
Slip, Trip, Fall Hazards: X Yes no. If yes, please specify type, location, and precautions to be taken:
Police area often; close and/or cover all soil borings and monitoring wells as soon as possible after
completion.

4 S:\\MISCPROJ\97-7093_H&SPLAN.DOC

Presence of Underground Utilities: X yes no
Utility Location Service ID#:Utility markout requested by ATC
Name of Contact: ULOCO (NC Utility Location Company)
Phone Number: 1-800-632-4949
Precautions to be taken: Observe locator’s marks. (red = power; orange = telephone/cable;
blue = water; green = sewer; yellow = gas)
Presence of Overhead Utilities: yes X no
Specify exact location: Field personnel will specify onsite. Maintain minimum 20 foot distance

Precautions to be taken: Drill rig should be clear of utility lines; use hand auger or posthole dig

Other Hazards: (Specify)

G. SITE CONTROL (1910.120(d))
Work Zones have been established as shown on the attached Site Diagram.
Site Security: Security on site will be maintained by:
X Temporary barricades and/or warning tape
Security fence
24-Hour security guard
X other (specify) On-site supervisor during working hours.

5 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
H. PERSONAL PROTECTIVE EQUIPMENT (1910.120(b)(4))

Based on evaluation of potential hazards, the following levels of personal protection have been designated
for the applicable work zones:

Work Zone Level of Protection Required Protective Equipment
(specify exact type, [e.g., nitrile gloves])
Exclusion Zone Level D Respirator N/A
Filters/Cartridges: N/A
Boots: Steel toed/rubber sole
Inner Gloves: Latex
Outer Gloves Nitrile, if needed
Protective Coverall: Tyvek Suit, if needed
Hard Hat: Yes
Eye Protection: Safety glasses/goggles
Other: Work gloves
Contamination
Reduction Zone Level D Respirator N/A
Filters/Cartridges: N/A
Boots: Steel toed/shank; rubber sole
Inner Gloves: N/A
Outer Gloves Work/Leather
Protective Coverall: N/A
Hard Hat: Yes
Eye Protection: Safety glasses
Other: Work gloves

Exceptions and Modifications: Respiratory protection is not expected to be required because exposures
will be below the PEL. This will be reevaluated as necessary.

6 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
I. DECONTAMINATION (1910.120(k))

Personnel Decontamination Procedures
All personnel entering the Exclusion Zone will undergo decontamination prior to leaving the site. Personnel
will proceed through the following decontamination stations:

STATION 1: Personnel Decontamination
Equipment Required Remove and contain all PPE

Decontamination Solution

STATION 2: Drilling materials and equipment, drill rig, hand auger
Equipment Required

Decontamination Solution Liquinox and tap water

STATION 3: Sampling and monitoring equipment
Equipment Required Bailer brush and bail

Decontamination Solution Distilled water, Liquinox, and Isopropyl Alcohol

STATION 4:
Equipment Required

Decontamination Solution

STATION 5:
Equipment Required

Decontamination Solution

7 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
Equipment Decontamination

Gross Removal By:
Hand scrubbing X
Cold high pressure wash
Hot high pressure wash
Steam cleaning X
Other (specify) Brush
Clean rinse Hot water
Decon solution (specify) Liquinox and water

Decontamination Wastewater
Collection (specify how) Collected in plastic-lined decontamination area (if required).
Then stored in a 55-gallon drum for later disposal (if required) otherwise spread on ground.
Direct Discharge (specify how and where) Direct discharge to ground (if required)

Pre-treatment (specify) Granular activated carbon (GAC) drums (if required).

Disposal (specify how and where) Surface discharge within 90 days of collection and following
Pretreatment (if required) .

J. AMBIENT AIR MONITORING (1910.120(b)(4))

Activity Instruments Action Level Frequency
Drilling/DPT HNU/OVA 10 ppm As needed
MSA CGM 10% LEL As needed
Dreager Tubes (at Breathing Zone) As needed

Comments:

8 S:\\MISCPROJ\97-7093_H&SPLAN.DOC

K. PERSONNEL AIR MONITORING (1910.120(h))

Activity/Location Contaminant(s) NIOSH/OSHA Protocol
N/A See Section J

L. CONTINGENCY PLAN (1910.120(l))

Emergency Communication Signal(s) (specify): Hand signals, automobile horn, or other means to be
determined on site.

Emergency Escape Route(s) (specify and indicate on site diagram): Attached for specific site
activities; may change during each phase determined on site. Specify meeting place in case of on-site
emergency.

Emergency Equipment On Site (specify location):
First Aid Kit and Bloodborne Pathogen Kit: ATC Vehicle / drill rig
Fire Extinguishers ATC Vehicle / drill rig /DPT dig
Telephone: ATC Vehicle / drill rig / DPT rig/ on-site pay phone
Eye Wash/Safety Shower: First Aid Kit or garden hose on-site
Others (specify): Regulate pressure to avoid eye damage (regular water hose)

Re-entry to the Exclusion Zone following an on-site emergency shall not be permitted until the following
conditions are satisfied:
1) The conditions resulting in an emergency have been corrected.
2) The hazards have been re-evaluated.
3) The Site Safety Plan has been reviewed and determined adequate for the hazards
encountered.
4) All site personnel have been instructed in any new hazards and changes to the Site Safety
Plan.

M. OTHER REQUIRED INFORMATION

In order to comply with OSHA standards, the following documents MUST be maintained on site:

1) Hazard Communication Manual (1910.1200)

9 S:\\MISCPROJ\97-7093_H&SPLAN.DOC

2) Chemical List and Material Safety Data Sheets for all chemicals (1910.1200)

3) Respirator fit test records for all employees who will be required to wear respirators (1910.134)

4) Copy of ATC's Respirator Program (1910.134)

5) Latest medical summary for all personnel (1910.120)
6)
** E M E R G E N C Y P H O N E N U M B E R S **

---- Post in Full View ----

ATC Director of Health and Safety ..........................................................................................[phone] x1422

Chemtrec.................................................................................................................................................[phone]

DOT Hotline...........................................................................................................................................[phone]
Materials Transportation Bureau

Centers for Disease Control and Prevention..........................................................................................[phone]
(Emergency Only)

Solid Waste and Emergency Response..................................................................................................[phone]
Office of Emergency and Remedial Response

TSCA Assistance Information Services Hotline ...................................................................................[phone]

Continuum Healthcare (ATC Medical Director)...................................................................................[phone]
--24 hour hotline

HOSPITAL: (Name): Caldwell Memorial Hospital
(Address): 321 Mulberry St SW, Lenoir, NC
(Phone): [phone]
(Travel Time): 6.4 mi – about 14 mins
(Directions): SEE ATTACHED MAP
(Map Attached): Yes
PARAMEDICS: (Name): EMS
(Phone): 911
FIRE DEPT: (Name): Lenoir Fire Dept.
(Phone): 828-728-8327
LOCAL POLICE: (Name): Lenoir Police Dept.
(Phone): 828-757-2100
UTILITIES: (Markout): ULOCO [phone]
(Electric): Duke Power (704-364-3120)
(Gas): Piedmont Natural Gas [phone]
(Water): City of Lenoir (828-757-2175)
CLIENT: (Name): Cary Oil Co.

10 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
(Phone): 832-379-6417 (Office) 713-818-1510 (Cell)

11 S:\\MISCPROJ\97-7093_H&SPLAN.DOC
All personnel have read the above plan and are familiar with its provisions. All personnel have received medical
surveillance and training in compliance with the ATC Health and Safety Policy.
NAME SIGNATURE

Bill McGuinness
Gordon Little
Kurt Ness
Richard Karpinski
Diana Lanier
JD Taylor
Diana Lanier
Natalie Corbin
Nathan Roberts

SUBCONTRACTORS

Start 1990 Connelly Springs Rd
Lenoir, NC 28645
End 321 Mulberry St SW
Lenoir, NC 28645
Travel 6.4 mi – about 14 mins
These directions are for planning purposes only. You may find that
construction projects, traffic, or other events may cause road conditions to
differ from the map results.
Map data ©2008 NAVTEQ™
1990 Connelly Springs Rd
Lenoir, NC 28645
321 Mulberry St SW
Lenoir, NC 28645
1. Head north on Connelly Springs Rd toward
Brandon Rd
4.3 mi
9 mins
2. Turn left at Norwood St SW/US-321-ALT 1.5 mi
3 mins
3. Turn left at Morganton Blvd SW/US-321-ALT/US-
64
0.2 mi
1 min
4. Turn right at Mulberry St SW/US-321-ALT 0.4 mi
1 min
Drive: 6.4 mi – about 14 mins
Map data ©2008 NAVTEQ™
Overview
Start
End
Page 1 of 11990 Connelly Springs Rd, Lenoir, NC 28645 to 321 Mulberry St SW, Lenoir, NC 28645...
2/11/2008http://www.google.com/maps?q=321+Mulberry+St+SW,+Lenoir,+NC&gl=US&daddr=32...
AMERADA HESS -- REGULAR UNLEADED GASOLINE
MATERIAL SAFETY DATA SHEET
NSN: 913000N023616
Manufacturer's CAGE: 4N717
Part No. Indicator: A
Part Number/Trade Name: REGULAR UNLEADED GASOLINE
==================================================================
General Information
===================================================================
Company's Name: AMERADA HESS CORP
Company's Street: 1 HESS PLAZA
Company's City: WOODBRIDGE
Company's State: NJ
Company's Country: US
Company's Zip Code: 07095
Company's Emerg Ph #: 800-424-9300(CHEMTREC)
Company's Info Ph #: 201-750-6000
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 13JAN89
Safety Data Review Date: 08JAN92
MSDS Serial Number: BLZXH
Hazard Characteristic Code: F2
Page 1 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
===================================================================
Ingredients/Identity Information
===================================================================
Proprietary: NO
Ingredient: GASOLINE
Ingredient Sequence Number: 01
Percent: 100
NIOSH (RTECS) Number: LX3300000
CAS Number: 8006-61-9
OSHA PEL: 300 PPM;500 PPM STEL
ACGIH TLV: 300 PPM;500 PPM STEL
-------------------------------------
Proprietary: NO
Ingredient: TERT-AMYL METHYL ETHER (BLEND OF ING 2&3 FOR A TOTAL OF 15% OF
PRODUCT)
Ingredient Sequence Number: 02
Percent: MIX
NIOSH (RTECS) Number: 1007422AM
CAS Number: 994-05-8
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ETHER,TERT-BUTYL METHYL; (METHYL TERT-BUTYL ETHER)
Ingredient Sequence Number: 03
Page 2 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Percent: MIX
NIOSH (RTECS) Number: KNS525000
CAS Number: 1634-04-4
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: TOLUENE
Ingredient Sequence Number: 04
Percent: 6-<3015
NIOSH (RTECS) Number: XS5250000
CAS Number: 108-88-3
OSHA PEL: 200 PPM/150 STEL
ACGIH TLV: 50 PPM; 9293
-------------------------------------
Proprietary: NO
Ingredient: XYLENE
Ingredient Sequence Number: 05
Percent: 8.5-<15
NIOSH (RTECS) Number: ZE2100000
CAS Number: 1330-20-7
OSHA PEL: 100 PPM;150 PPM STEL
ACGIH TLV: 100 PPM;150 PPM STE
-------------------------------------
Proprietary: NO
Page 3 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Ingredient: BENZENE
Ingredient Sequence Number: 06
Percent: 0.1-<5
NIOSH (RTECS) Number: CY1400000
CAS Number: 71-43-2
OSHA PEL: 1 PPM; 5 STEL (MFR)
ACGIH TLV: 10 PPM
-------------------------------------
Proprietary: NO
Ingredient: BENZENE, ETHYL; (ETHYL BENZENE)
Ingredient Sequence Number: 07
Percent: <3
NIOSH (RTECS) Number: DA0700000
CAS Number: 100-41-4
OSHA PEL: 100 PPM;125 PPM STEL
ACGIH TLV: 100 PPM;125 PPM STEL
-------------------------------------
Proprietary: NO
Ingredient: BENZENE,1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE)
Ingredient Sequence Number: 08
NIOSH (RTECS) Number: DC3325000
CAS Number: 95-63-6
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Page 4 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Proprietary: NO
Ingredient: SUPPORT DATA:IN AIR. HEAVIER/AIR VAPOR CAN FLOW ALONG SURFACES TO
DISTANT SOURCES OF IGNITION AND FLASHBACK. FLOW GASOLINE CAN BE (ING 10)
Ingredient Sequence Number: 09
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 9:IGNITED BY SELF-GENERATED STATIC ELECTRICITY RUNOFF TO
SEWERS MAY CREATE FIRE &/OR EXPLOSION HAZARD
Ingredient Sequence Number: 10
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: EFFECTS OF OVEREXPOSURE:WILL FATIGUE OLFACTORY SENSES.
IMMEDIATELY DANGEROUS TO HEALTH/LIFE IS REPRESENTED BY 2 THOUSANDS(2000)
PPM. (ING 12)
Ingredient Sequence Number: 11
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 11:INGESTION/INHALATION OF LIQUID &/OR EXCESS VAPOR CAN HAVE
Page 5 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
AN ANESTHETIZING EFFECT, CAUSING VERTIGO, BLURRED VISION, VOMIT & (ING 13)
Ingredient Sequence Number: 12
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 12:CYANOSIS. OVEREXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION.
Ingredient Sequence Number: 13
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: SPILL PROCEDURES :ACQUATIC LIFE. CAUTION-EVACUATE ALL NON-
ESSENTIAL PERSONNEL SPILLED MATERIAL MAY CAUSE SLIPPERY CONDITION. OPEN
(ING 15)
Ingredient Sequence Number: 14
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 14:SPILLS MAY EMIT FLAMMABLE VAPOR APPROACH FROM UPWIND IF
POSSIBLE. AVOID BREATHING EMITTED VAPOR WEAR SCBA IF REQUIRED TO PREVENT
(ING 16)
Page 6 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Ingredient Sequence Number: 15
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 15:INHAL OF VAPORS.
Ingredient Sequence Number: 16
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: WASTE DISPOSAL METHOD:FLAMMABLE, VAPORS.
Ingredient Sequence Number: 17
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: HANDLING/STORAGE PRECAUTIONS :BONDED/GROUNDED TO PREVENT
POTENTIAL ACCUMULATION OF STATIC ELECTRICITY. NO SMOKING IN AREAS OF
HANDLING/STORAGE (ING 19)
Ingredient Sequence Number: 18
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
Page 7 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 18:STORAGE SHOULD BE TIGHTLY CLOSED CONTAINER IN
COOL/DRY/ISOLATED & WELL VENTED AREA AWAY FROM POTENTIAL SOURCES OF
IGNITION.
Ingredient Sequence Number: 19
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: OTHER PRECAUTIONS :REGULAR/FREQUENT BASIS. VENTALATION MUST BE
SUFFICIENT TO PREVENT ACCUMULATION OF TOXIC/FLAMMABLE CONCENTRATION
OF VAPOR IN AIR. (ING 21)
Ingredient Sequence Number: 20
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: ING 20:EMPTY CONTAINER MAY CONTAIN TOXIC/FLAM/MABLE COMBUSTION
RESIDUE/VAPOR. DO NOT CUT/GRIND/DRILL/WELD OR REUSE CONTAINER UNLESS
ADEQUATE (ING 22)
Ingredient Sequence Number: 21
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Page 8 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
-------------------------------------
Proprietary: NO
Ingredient: ING 21:PRECAUTIONS AGAINST THESE HAZARDS ARE TAKEN.
Ingredient Sequence Number: 22
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
-------------------------------------
Proprietary: NO
Ingredient: HYGIENE PRACTICES: UPPWIND OF VAPOR OR MIST RELEASE, SPILL OR
LEAK.
Ingredient Sequence Number: 23
NIOSH (RTECS) Number: 9999999ZZ
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
===================================================================
Physical/Chemical Characteristics
===================================================================
Appearance And Odor: CLEAR LIQUID W/STRONG AROMATIC HYDROCARBON ODOR. MAY
BE DYED CHARACTERISTIC(SUPDAT)
Boiling Point: 85.0F,29.4C
Vapor Pressure (MM Hg/70 F): SUPP DATA
Vapor Density (Air=1): 3.0-4.0
Specific Gravity: 0.76
Evaporation Rate And Ref: 10-11(BUTYL ACETATE=1)
Page 9 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Solubility In Water: SLIGHT
Percent Volatiles By Volume: 100
===================================================================
Fire and Explosion Hazard Data
==================================================================
Flash Point: -40F,-40C
Flash Point Method: TCC
Lower Explosive Limit: 1.4%
Upper Explosive Limit: 7.4%
Extinguishing Media: ANY APPROVED EXTINGUISHING AGENT FOR CLASS B FIRES/DRY
CHEM/FOAM/CO*2 OR HALON. H*2O IS NOT ORDINARILY EFFECTIVE HOWEVER, H*2O
FOG(SUPP DATA)
Special Fire Fighting Proc: NIOSH/MSHA APPRVD SCBA & FULL PROTECTION EQUIPMENT
(FPN). AVOID INHALATION OF VAPOR. H*2O SHOULD BE USED TO KEEP EXPOSURE
CONTROL COOL. APPROACH FROM UPWIND IF POSSIBLE.
Unusual Fire And Expl Hazrds: CLASS 1A FLAMMABLE LIQUID. KEEP AWAY FROM
HEAT/SOURCES OF IGNITION/OXIDIZERS. BURN MAY CAUSE EMISSION OF TOXIC
PRODUCTION OF COMBUSTION.
EMPTY PRODUCT CONTROL/VESSELS MAY CONTAIN (SUPP DATA)
===================================================================
Reactivity Data
===================================================================
Stability: YES
Cond To Avoid (Stability): AVOID HANDLING OR STORING NEAR HEAT, SPARKS OR
OPEN FLAME.
Materials To Avoid: OXIDIZING AGENTS. COMBUSTION OF NITRIC AND SULFURIC
ACIDS.
Hazardous Decomp Products: CONTACT W/NITRIC & SULFURIC ACIDS WILL FORM
Page 10 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
NITROCRESOLS THAT CAN DECOMPOSE VIOLENTLY.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT.
===================================================================
Health Hazard Data
===================================================================
LD50-LC50 Mixture: LD50:ORAL(RBT)5 ML/KG
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: ACUTE/CHRONIC:HARMFUL/FATAL IF SWALLOW/
ASPIRATED. LONG TERM EXPOS TO VAP HAS CAUSED CANCER IN SOME LAB ANIMALS.
INGEST MAY CAUSE GI DISTURB. ASPIR INTO LUNGS MAY CAUSE PNEUMONIA
PROLONGED CONTACT W/SKIN MAY RESULT IN DEFAT/RED/ITCH/INFLAM/CRACK &
POSS SECONDARY INFECTION.
HAS LOW ORDER OF ACUTE ORAL TOXICITY IF (EFFECTS OF OVEREXPOSURE)
Carcinogenicity - NTP: YES
Carcinogenicity - IARC: YES
Carcinogenicity - OSHA: YES
Explanation Carcinogenicity: GASOLINE - IARC 2B; BENZENE, A CONSTITUENT OF
GASOLINE:OSHA REGULATED, GROUP 1 (IARC,NTP).
Signs/Symptoms Of Overexp: HEALTH HAZARD :INGESTED, BUT MINIMUM AMOUNT ASPIR
DURING SUCH INGEST MAY CAUSE DEATH. HIGH PRESS SKIN INJECTIONS ARE SERIOUS
MEDICAL EMERGENCY REPEATED/PROLONGED EXPOSURE TO VAPOR CONTAIN HIGH
CONCENTRATION OF BENZENE MAY CAUSE ANEMIA &
OTHER BLOOD DISEASES, INCLUDING LEUKEMIA. INHALATION TO 100PPM MAY CAUSE
SLIGHT DROWSINESS/HEADACHE. 100-200PPM MAY CAUSE FATIGUE/NAUSEA/ITCH &
(ING 11)
Medical Conditions Aggravated By Exposure: OPEN WOUNDS, SKIN DISORDERS, CHRONIC
RESPIRATORY DISEASE OR PRE-EXISTING CENTRAL NERVOUS SYSTEM DISEASE.
Page 11 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Emergency/First Aid Proc: INHALATION :REMOVE TO FRESH AIR, PROVIDE O*2 THERAPY
&/OR RESUSCITATION AS INDICATED. SKIN: REMOVE CONTAMINATED CLOTHING AND
FLUSH WITH SOAP AND WATER. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
INGEST: RINSE MOUTH WITH WATER. KEEP CALM AND WARM. DO NOT INDUCE VOMIT!
ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE CHEMICAL PNEUMONIA. CALL
PHYSICIAN IMMEDIATELY
===================================================================
Precautions for Safe Handling and Use
===================================================================
Steps If Matl Released/Spill: CONTAIN ALL SPILLS. ABSORB ALL FREE LIQUID. REMOVE ALL
IGNITION SOURCES/SAFELY STOP FLOW OF SPILL. PREVENT FROM ENTER ALL BODIES
OF H*2O. COMPLY W/ALL APPLICABLE LAWS/REGS. ABSORBENT
MATERIAL/PADS/SAND/EARTH MAY BE USED. CONTAMINATED H*2O/SOIL MAY BE
HAZARD TO ANIMAL/ (ING 14)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DISPOSE OF PRODUCT/CONTAMINATED MATERIAL AS EPA
"IGNITABLE HAZARDOUS WASTE". USE ONLY APPROVED TREATMENT TRANSPORTERS
& DISPOSAL SITES IN COMPLIANCE W/ALL APPLICABLE FEDERAL/STATE/LOCAL
REGULATIONS MAINTAIN SURVEILLANCE OF ABSORBED MATERIAL UNTIL FINAL
DISPOSAL TO OBSERVE FOR EMISSION OF VOLATILE, (ING 17)
Precautions-Handling/Storing: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME. AVOID
BREATHING VAPOR/MIST. AVOID SKIN/EYE CONTACT. KEEP CONTAINER CLOSED &
PLAINLY LABELED.
TRANSFER LINES MUST BE (ING 17)
Other Precautions: USE ONLY AS MOTOR FUEL. HANDLE/TRANSPORT/STORE IN
ACCORDANCE W/APPLICABLE LAWS/REGULAITONS. ELECTRICAL EQUIPMENT SHOULD
BE APPROVED FOR CLASSIFIED AREA. REMOVE SOILED CLTHG/LAUNDER BEFORE RE-
USE. DISCARD OIL SOAKED SHOES. WEAR FULL
LENGTH CLOTHING/LAUNDER ON (ING 18)
===================================================================
Control Measures
===================================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED SCBA IN CONFINED SPACES OR
WHEN EXPOSED TO HEAVY MIST.
Page 12 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
Ventilation: LOCAL EXHAUST:GENERALLY NOT REQUIRED. MECHANICAL (GENERAL):
EXPLOSION PROOF(APPROVED FOR CLASSIFIED AREA).
Protective Gloves: IMERVIOUS GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: IMPERVIOUS CLOTHING, EYEWASH/BATH.
Work Hygienic Practices: WASH SKIN THOROUGHLY W/SOAP/H*2O BEFORE
EAT/DRINK/SMOKING. VENTILATION MAY BE USED TO CONTROL/REDUCE AIRBORNE
CONCENTRATIONS STAND (ING 23)
Suppl. Safety & Health Data: VP: 275-475@68F. APPEAR/ODOR:COLOR FOR
IDENTIFICATION(CLEAR RED/BRONZE/YELLOW ARE TYPICAL). EXTINGUISHING
MEDIA:MAY BE USED BY EXPERIENCED FIRE FIGHTER FOR INTENSITY CONTROL/TO
COOL EXPOSED AREAS.
EXPLOSION HAZARD:EXPLOSIVE VAPOR DO NOT PRESSURIZE/CUT/HEAT/WELD/EXPOSE
SUCH CONTROL OR VESSELS TO SOURCES OF IGNITION. VAPOR CAN READILY FORM
EXPLOSIVE MIXTURE(ING 9)
===================================================================
Transportation Data
===================================================================
Trans Data Review Date: 92072
DOT PSN Code: GTN
DOT Proper Shipping Name: GASOLINE
DOT Class: 3
DOT ID Number: UN1203
DOT Pack Group: II
DOT Label: FLAMMABLE LIQUID
IMO PSN Code: HRV
IMO Proper Shipping Name: GASOLINE
IMO Regulations Page Number: 3141
Page 13 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
IMO UN Number: 1203
IMO UN Class: 3.1
IMO Subsidiary Risk Label: -
IATA PSN Code: RMF
IATA UN ID Number: 1203
IATA Proper Shipping Name: MOTOR SPIRIT
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
AFI PSN Code: MUC
AFI Prop. Shipping Name: GASOLINE
AFI Class: 3
AFI ID Number: UN1203
AFI Pack Group: II
AFI Basic Pac Ref: 7-7
===================================================================
Disposal Data
===================================================================
===================================================================
Label Data
===================================================================
Label Required: YES
Label Status: G
Common Name: REGULAR UNLEADED GASOLINE
Special Hazard Precautions: ACUTE/CHRONIC:HARMFUL/FATAL IF SWALLOW/
ASPIRATED. LONG TERM EXPOSURE TO VAPOR HAS CAUSED CANCER IN SOME LAB
Page 14 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
ANIMALS. INGESTION MAY CAUSE GI DISTURBANCE. ASPIRATE INTO LUNGS MAY
CAUSE PNEUMONIA PROLONG CONTACT W/SKIN MAY RESULT IN
DEFAT/RED/ITCH/INFLAM/CRACK & POSSIBLY SECONDARY INFECTION.
HAS LOW ORDER OF ACUTE ORAL TOXICITY IF (EFFECTS OF OVEREXPOSURE) HEALTH
HAZARD: INGESTED, BUT MINIMUM AMOUNT ASPIRATED DURING SUCH INGEST MAY
CAUSE DEATH. HIGH PRESS SKIN INJECTIONS ARE SERIOUS MEDICAL EMERGENCOES
REPEATED/PROLONGED EXPOSURE TO VAPOR CONTAINING HIGH CONCENTRATION OF
BENZENE MAY CAUSE ANEMIA & OTHER BLOOD DISEASES, INCLUDING LEUKEMIA.
INHALATION TO 100PPM MAY CAUSE SLIGHT DROWSINESS/HEADACHE. 100-200PPM
MAY CAUSE FATIGUE/NAUSEA/ ITCH & (ING 11)
Label Name: AMERADA HESS CORP
Label Street: 1 HESS PLAZA
Label City: WOODBRIDGE
Label State: NJ
Label Zip Code: 07095
Label Country: US
Label Emergency Number: 00-424-9300(CHEMTREC)

Page 15 of 15UNLEADED GASOLINE MSDS
1/31/2008http://www.umb.edu/administration_finance/ehs/unleadmsds.html
MSDS SUMMARY SHEET

Manufacturer:
Name: PHILLIPS PETROLEUM COMPANY
Address 1:
Address 2:
Address 3:
CSZ: BARTLESVILLE State: OK Zipcode: 74004
Emergency phone: [phone]
Business phone: [phone]

Product:

Ferndale MSDS#: 1354 Version # : 6
Manufacturer MSDS#: 0041
Current? : 2002
Name:
NO. 2 DIESEL FUEL
Synonyms:
CARB Diesel TF3
CARB Diesel
CARB Diesel 10%
Diesel Fuel Oil
EPA Low Sulfur Diesel Fuel
EPA Low Sulfur Diesel Fuel – Dyed
EPA Off Road High Sulfur Diesel – Dyed
Fuel Oil No. 2 – CAS # 68476-30-2
No. 2 Diesel Fuel Oil
No. 2 Fuel Oil – Non Hiway – Dyed
No. 2 High Sulfur Diesel – Dyed
No. 2 Low Sulfur Diesel - Dyed
No. 2 Low Sulfur Diesel - Undyed
Crude column 3rd IR
Crude column 3rd side cut
Atmospheric tower 3rd side cut
Ultra Low Sulfur Diesel No. 2
Finished Diesel
DHT Reactor Feed
Straight Run Diesel
Diesel
Middle Distillate
Product/Catalog Numbers:
MSDS Date: 01/01/2002 (received: 01/14/2002)

NFPA codes:
Health: 0 Flammability: 2 Reactivity: 0

No. 2 Diesel Fuel (MSDS #0041) Page 2 of 9

MATERIAL SAFETY DATA SHEET
No. 2 Diesel Fuel

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: No. 2 Diesel Fuel
Product Code: Multiple
SAP Code:
Synonyms: 1354
CARB Diesel TF3
CARB Diesel
CARB Diesel 10%
Diesel Fuel Oil
EPA Low Sulfur Diesel Fuel
EPA Low Sulfur Diesel Fuel – Dyed
EPA Off Road High Sulfur Diesel – Dyed
Fuel Oil No. 2 – CAS # 68476-30-2
No. 2 Diesel Fuel Oil
No. 2 Fuel Oil – Non Hiway – Dyed
No. 2 High Sulfur Diesel – Dyed
No. 2 Low Sulfur Diesel - Dyed
No. 2 Low Sulfur Diesel – Undyed
No. 2 Ultra Low Sulfur Diesel – Dyed
No. 2 Ultra Low Sulfur Diesel - Undyed
Intended Use: Fuel
Chemical Family:
Responsible Party: Phillip’s Petroleum Company
Bartlesville, Oklahoma 74004
For Additional MSDSs: 800-762-0942
Technical Information:

The intended use of this product is indicated above. If any additional use is known, please contact us at the
Technical Information number listed.

EMERGENCY OVERVIEW

24 Hour Emergency Telephone Numbers:
Spill, Leak, Fire or Accident California Poison Control System: 800-356-3120
Call CHEMTREC
North America: [phone]
Others: [phone] (collect)

Health Hazards/Precautionary Measures: Causes severe skin irritation. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Do not
taste or swallow. Wash thoroughly after handling.

Physical Hazards/Precautionary Measures: Flammable liquid and vapor. Keep away from heat, sparks, flames,
static electricity or other sources of ignition.

Appearance: Straw-colored to dyed red
Physical Form: Liquid
Odor: Characteristic petroleum

No. 2 Diesel Fuel (MSDS #0041) Page 3 of 9

HFPA Hazard Class: HMIS Hazard Class
Health: 0 (Least) Not Evaluated
Flammability: 2 (Moderate)
Reactivity: 0 (Least)

2. COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS COMPONENTS % VOLUME EXPOSURE GUIDELINE
Limits Agency Type
Diesel Fuel No. 2 100 100* mg/m3 ACGIH TWA-SKIN
CAS# 68476-34-6

Naphthalene <1 10ppm ACGIH TWA
CAS# 91-20-3 15ppm ACGIH STEL
10ppm OSHA TWA
250ppm NIOSH IDLH

All components are listed on the TSCA inventory

Tosco Low Sulfur No. 2 Diesel meets the specifications of 40 CFR 60.41 for low sulfur diesel fuel.

Note: State, local or other agencies or advisory groups may have established more stringent limits.
Consult an industrial hygienist or similar professional, or your local agencies, for further information.

*Proposed ACGIH (1999)

3. HAZARDS IDENTIFICATION

Potential Health Effects:

Eye: Contact may cause mild eye irritation including stinging, watering, and redness.

Skin: Severe skin irritant. Contact may cause redness, itching, burning, and severe skin damage. Prolonged or
repeated contact can worsen irritation by causing drying and cracking of the skin, leading to dermatitis
(inflammation). Not actually toxic by skin absorption, but prolonged or repeated skin contact may be harmful (see
Section 11).

Inhalation (Breathing): No information available. Studies by other exposure routes suggest a low degree of
toxicity by inhalation.

Ingestion (Swallowing): Low degree of toxicity by ingestion. ASPIRATION HAZARD – This material can enter
lungs during swallowing or vomiting and cause lung inflammation and damage.

Signs and Symptoms: Effects of overexposure may include irritation of the nose and throat, irritation of the
digestive tract, nausea, diarrhea and transient excitation followed by signs of nervous system depression (e.g.,
headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue).

Cancer: Possible skin cancer hazard (see Sections 11 and 14).

Target Organs: There is limited evidence from animal studies that overexposure may cause injury to the kidney
(see Section 11).

Developmental: Inadequate data available for this material.

Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders and kidney
disorders.

No. 2 Diesel Fuel (MSDS #0041) Page 4 of 9

4. FIRST AID MEASURES

Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean
water. If symptoms persist, seek medical attention.

Skin: Immediately remove contaminated shoes, clothing, and constrictive jewelry and flush affected area(s) with
large amounts of water. If skin surface is damaged, apply a clean dressing and seek immediate medical
attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap
and water. If irritation or redness develops, seek immediate medical attention.

Inhalation (Breathing): If respiratory symptoms develop, move victim away from source of exposure and into
fresh air. If symptoms persist, seek medical attention. If victim is not breathing, clear airway and
immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by
qualified personnel. Seek immediate medical attention.

Ingestion (Swallowing): Aspiration hazard; Do not induce vomiting or give anything by mouth because this
material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and
vomiting, place on the left side with the head down. If possible, do not leave victim unattended and
observe closely for adequacy of breathing. Seek medical attention.

5. FIRE FIGHTING MEASURES

Flammable Properties: Flash Point: >125°F/>52°
OSHA Flammability Class: Combustible liquid
LEL %: 0.3 / UEL %; 10.0
Autoignition Temperature: 500°F/260°C

Unusual Fire & Explosion Hazards: This material is flammable and can be ignited by heat, sparks, flames, or
other sources of ignition (e.g., static electricity, pilot lights, or mechanical/electrical equipment, and electronic
devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically
safe). Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or
explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. Vapors are
heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of
a fire.

Extinguishing Media: Dry chemical, carbon dioxide, or foam is recommended. Water spray is recommended to
cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying
carbon dioxide in confined spaces. Water may be ineffective for extinguishment, unless used under favorable
conditions by experienced fire fighters.

Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard
area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces,
or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear
other appropriate protective equipment as conditions warrant (see Section 8).

Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with
minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk.

Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment
exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used
for cooling purposes.

No. 2 Diesel Fuel (MSDS #0041) Page 5 of 9

6. ACCIDENTAL RELEASE MEASURES

Flammable. Keep all sources of ignition and hot metal surfaces away from spill/release. The use of explosion-proof
equipment is recommended.

Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard
area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear
appropriate protective equipment including respiratory protection as conditions warrant (see Section 8).

Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural
waterways. Dike far ahead of spill for later recovery or disposal. Use foam on spills to minimize vapors (see
Section 5). Spilled material may be absorbed into an appropriate material.

Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is
recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining
shorelines, notify the National Response Center (phone number 800-424-8802).

7. HANDLING AND STORAGE

Handling: Open container slowly to relieve any pressure. Bond and ground all equipment when transferring from
one vessel to another. Can accumulate static charge by flow or agitation. Can be ignited by static discharged. The
use of explosion-proof equipment is recommended and may be required (see appropriate fire codes). Refer to
NFPA-704 and/or API RP 2003 for specific bonding/grounding requirements.

Do not enter confined spaces such as tanks or pits without following proper entry procedures such ASTM
D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed
any established exposure limits (see Sections 2 and 8).

Do not wear contaminated clothing or shoes. Keep contaminated clothing away from sources of ignition such as
sparks or open flames. Use good personal hygiene practices.

High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious
consequences even though no symptoms or injury may be apparent. This can happen accidentally when using high
pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in tubing or
high pressure hydraulic oil equipment.

“Empty” containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or
death. “Empty” drums should be completely drained, properly bunged, and promptly shipped to the supplier or a
drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with
governmental regulations.

Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSIZ49.1
and other references pertaining to cleaning, repairing, welding, or other contemplated operations.

Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from
heat, direct sunlight, hot metal surfaces, and all sources of ignition. Post area “No Smoking or Open Flame.” Store
only in approved containers. Keep away from incompatible material (see Section 10). Protect container(s) against
physical damage. Outdoor or detached storage is preferred. Indoor storage should meet OSHA standards and
appropriate fire codes.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls: If current ventilation practices are not adequate to maintain airborne concentration below
the established exposure limits (see Section 2), additional ventilation or exhaust systems may be required. Where
explosive mixtures may be present, electrical systems safe for such locations must be used (see appropriate electrical
codes).
No. 2 Diesel Fuel (MSDS #0041) Page 6 of 9

Personal Protective Equipment (PPE):
Respiratory: A NIOSH certified air purifying respirator with an organic vapor cartridge maybe used under
conditions where airborne concentrations are expected to exceed exposure limits (see Section 2).

Protection provided by air purifying respirators is limited (see manufacturer’s respirator selection guide).
Use a positive pressure air supplied respirator if there is a potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying respirators may not provide adequate
protection.

A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrants a respirator’s use.

Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact, possible
irritation and skin damage (see glove manufacturer literature for information on permeability). Depending
on conditions of use, apron and/or arm covers may be necessary.

Eyes/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is
recommended. Depending on conditions of use, a face shield may be necessary.

Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area.
Thoroughly clean shoes and wash contaminated clothing before reuse. It is recommended that impervious
clothing be worn when skin contact is possible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1atm).

Appearance: Straw-colored to dyed red
Physical State: Liquid
Odor: Characteristic petroleum
pH: unavailable
Vapor Pressure (mm Hg): 0.40
Vapor Densisty (air=1):>3
Boiling Point/Range: 320-700°F /160-371°C
Freezing/Melting Point: No Data
Solubility in Water: Negligible
Specific Gravity: 0.81-0.88 @ 60°F
Percent Volatile: Negligible
Evaporation Rate (nBuAc=1): <1
Viscosity: 32.6-40.0 SUS @ 100°F
Bulk Density: 7.08 lbs/gal
Flash Point: >125°F / >52°C
Flammable/Expolsive Limits (%): LEL: 0.3 / UEL: 10.0

10. STABILITY AND REACTIVITY

Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
Flammable liquid and vapor. Vapor can cause flash fire.

Conditions To Avoid: Avoid all possible sources of ignition (see Sections 5 and 7).

Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidants such as liquid chlorine,
concentrated oxygen, sodium hypochlorite, calcium hypochlorite, etc.

No. 2 Diesel Fuel (MSDS #0041) Page 7 of 9

Hazardous Decomposition Products: The use of hydrocarbon fuels in an area without adequate ventilation may
result in hazardous levels of combustion products (e.g., oxides of carbon, sulfur and nitrogen, benzene and other
hydrocarbons) and/or dangerously low oxygen levels. ACGIH has included a TLV of 0.05 mg/m3 TWA for
diesel exhaust particulate on its 1999 Notice of Intended Changes. See Section 11 for additional information on
hazards of engine exhaust.

Hazardous Polymerization: Will not occur.

11. TOXICOLOGICAL INFORMATION

Diesel Fuel No. 2 (CAS# 68476-34-6)

Carcinogenicity: Chronic dermal application of certain middle distillate streams contained in diesel fuel No. 2
resulted in an increased incidence of skin tumors in mice. This material has not been identified as carcinogen by
NTP, IARC, or OSHA. Diesel exhaust is a probable cancer hazard based on tests with laboratory animals.

Target Organ(s): Limited evidence of renal impairment has been noted from a few case reports involving
excessive exposure to diesel fuel No. 2.

Naphthalene (CAS# 91-20-3)

Carcinogenicity: Naphthalene has been evaluated in two year inhalation studies in both rats and mice. The National
Toxicology Program (NTP) concluded that there is clear evidence of carcinogenicity in male and female rats based
on increased incidences of respiratory epithelial adenomas and olfactory epithelial neuroblastomas of the nose. NTP
found some evidence of carcinogenicity in female mice (alveolar adenomas) and no evidence of carcinogenicity in
male mice. Naphthalene has not been identified as a carcinogen by IARC or OSHA.

12. ECOLOGICAL INFORMATION

Not evaluated at this time

13. DISPOSAL CONSIDERATIONS

This material, if discarded as produced, would be a RCRA “characteristic” hazardous waste due to the
characteristic(s) of ignitability (D001) and benzene (D018). If the material is spilled to soil or water, characteristic
testing of the contaminated materials is recommended. Further, this material, once it becomes a waste, is subject to
the land disposal restrictions in 40 CFR 268.40 and may require treatment prior to disposal to meet specific
standards. Consult state and local regulations to determine whether they are more stringent then the federal
requirements.

Container contents should be completely used and containers should be emptied prior to discard. Container ?insate?
could be considered a RCRA hazardous waste and must be disposed of with care and in compliance with federal,
state and local regulations. Large empty containers, such as drums, should be returned to the distributor or to a drum
reconditioner. To assure proper disposal of smaller containers, consult with state and local regulations and disposal
authorities.

14. TRANSPORT INFORMATION

DOT Shipping Description: Diesel Fuel, NA1983
Non-Bulk Package Marking: Diesel Fuel, 3, NA 1993, III

No. 2 Diesel Fuel (MSDS #0041) Page 8 of 9

15. REGULATORY INFORMATION

EPA SARA 311/312 (Title III Hazard Categories):
Acute Health: Yes
Chronic Health: Yes
Fire Hazard: Yes
Pressure Hazard: No
Reactive Hazard: No

SARA 313 and 40 CFR 372:
This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372:

Component CAS Number Weight %

-- None known --

California Proposition 65:
Warning: This material contains the following chemicals which are known to the state of California to cause
cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65
(CA Health & Safety Code Section 25249.5):

Component Effect
Benzene Cancer, Developmental and Reproductive Toxicant
Toluene Developmental Toxicant
Diesel engine exhaust, while not a component of this material, is on the Proposition 65 list of chemicals known to
the State of California to cause cancer.

Carcinogen Identification:
This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for carcinogenicity
information of individual components, if any. Diesel exhaust is a probable cancer hazard based on tests in laboratory
animals. It has been identified as carcinogen by IARC.

EPA (CERCLA Reportable Quantity: None

16. OTHER INFORMATION

Issue Date: 01/01/02
Previous Issue Date: 05/15/01
Product Code: Multiple
Revised Sections: None
Previous Product Code: Multiple
MSDS Number: 0041

Disclaimer of Expressed and Implied Warranties:

The information presented in this Material Data Safety Sheet is based on data believed to be accurate as of the date this Material Data
Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR
ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF
THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR
THE PRODUCT, THE SAFETY OF THE PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for
any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided
above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the
suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no
authorization is given nor implied to practice any patented invention without a license.

No. 2 Diesel Fuel (MSDS #0041) Page 9 of 9

Tosco Refining Company Ferndale Refinery
UltraLow Sulfur Diesel Product Specification
Ferndale Product Code:34380xx (5) Product Code: ULSD2
(COMETS)

Specification Unit Limit Test Procedure Typical
Appearance
Water & Sediment
Color
Haze Rating

Vol %
Number
Rating

0.05 Max
3.0 Max
2 Max

D 2709
D 1500
D 4176

Composition
Carbon Residue (Ramsbottom)

Wt %

0.35 Max

D 524, D 189

Volatility
90% Recovered

Flash Point
Gravity

Deg; F
Deg; F
Deg; F
API

540 Min
640 Min
125 Min (1)
30 Min

D 86
D 86
D 93
D 287, D4052

130 F
Fluidity
Pour Point
Cloud Point
Viscosity @ 104F

Lubricity, SLBOCLE

Lubricity, HFRR

Deg; F
Deg; F
cSt
cSt

grams

mm

See Season Table (6)
See Season Table (6)
1.9 Min
4.1 Max

3100 Min

.45

D 97
D 2500
D 445
D 445

D 6078

D 6079

10 F

3300gm
Combustion
Cetane Index or Cetane Number
(3,4)

Number

40.0 Min

D 976, D613

47.0
Corrosion
Copper Strip, 3hr @ 50 deg C

Number

3 Max (2)

D 130

Aromatics (4) Vol % 35 Max D 1319 25 %
Contaminants
Total Sulfur
Water & Sediment
Ash

PPM
Vol %
Wt %

30 Max
0.05 Max
0.01 Max

D 2622, D4294
D 1796
D 482

15-20ppm
Additives
Cetane Improver
Dye

Lb/MBbl

675 Max
Undyed

1. Minimum release specification is 125 deg. F. The refinery should target 135 deg. F.
2. Test result reported as a number and letter (e.g. 1a). Any letter is allowable as long as the number meets the spec
shown.
3. Either specification must be met.
4. Either cetane index minimum or aromatics maximum must be met.
5. Winter cloud and pour specifications may be relaxed to the summer specifications by agreement with the customer.
6. Season Table

Month Product Code Pour Point Cloud Point
Jan, Feb, Nov, Dec WI 0 max (5) 14 max (5)
Mar - Oct SU 15 max 24 max

MSDS Number: I8840 * * * * * Effective Date: 05/04/07 * * * * * Supercedes: 08/27/04

ISOPROPYL ALCOHOL (90 - 100%)
1. Product Identification
Synonyms: 2-Propanol; sec-propyl alcohol; isopropanol; sec-propanol; dimethylcarbinol
CAS No.: 67-63-0
Molecular Weight: 60.10
Chemical Formula: (CH3)2 CHOH
Product Codes:
J.T. Baker: 0562, 5082, 9037, 9080, U298
Mallinckrodt: 0562, 3027, 3031, 3032, 3035, 3037, 3043, 4359, 6569, H604, H982, V555,
V566, V681
2. Composition/Information on Ingredients

Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------

Isopropyl Alcohol 67-63-0 90 - 100% Yes
Water 7732-18-5 0 - 10% No

3. Hazards Identification
Page 1 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
Emergency Overview
--------------------------
WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED
OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT.
AFFECTS CENTRAL NERVOUS SYSTEM. MAY BE HARMFUL IF ABSORBED
THROUGH SKIN. MAY CAUSE IRRITATION TO SKIN.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate
Flammability Rating: 3 - Severe (Flammable)
Reactivity Rating: 2 - Moderate
Contact Rating: 3 - Severe
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD;
PROPER GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
Inhalation of vapors irritates the respiratory tract. Exposure to high concentrations has a
narcotic effect, producing symptoms of dizziness, drowsiness, headache, staggering,
unconsciousness and possibly death.
Ingestion:
Can cause drowsiness, unconsciousness, and death. Gastrointestinal pain, cramps, nausea,
vomiting, and diarrhea may also result. The single lethal dose for a human adult = about
250 mls (8 ounces).
Skin Contact:
May cause irritation with redness and pain. May be absorbed through the skin with possible
systemic effects.
Eye Contact:
Vapors cause eye irritation. Splashes cause severe irritation, possible corneal burns and eye
damage.
Chronic Exposure:
Chronic exposure may cause skin effects.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or impaired liver, kidney, or pulmonary function
may be more susceptible to the effects of this agent.
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion:
Give large amounts of water to drink. Never give anything by mouth to an unconscious
Page 2 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
person. Get medical attention.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if
irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper
eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire:
Flash point: 12C (54F) CC
Autoignition temperature: 399C (750F)
Flammable limits in air % by volume:
lel: 2.0; uel: 12.7
Listed fire data is for Pure Isopropyl Alcohol.
Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above.
Contact with strong oxidizers may cause fire or explosion. Vapors can flow along surfaces
to distant ignition source and flash back. Sensitive to static discharge.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide. Water spray may be used to
keep fire exposed containers cool, dilute spills to nonflammable mixtures, protect personnel
attempting to stop leak and disperse vapors.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other positive
pressure mode.
6. Accidental Release Measures
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal
protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and
unprotected personnel from entering. Contain and recover liquid when possible. Use non-
sparking tools and equipment. Collect liquid in an appropriate container or absorb with an
inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container.
Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill
has not ignited, use water spray to disperse the vapors, to protect personnel attempting to
stop leak, and to flush spills away from exposures.

J. T. Baker SOLUSORB® solvent adsorbent is recommended for spills of this product.
Page 3 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
7. Handling and Storage
Protect against physical damage. Store in a cool, dry well-ventilated location, away from
any area where the fire hazard may be acute. Outside or detached storage is preferred.
Separate from incompatibles. Containers should be bonded and grounded for transfers to
avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking
type tools and equipment, including explosion proof ventilation. Containers of this material
may be hazardous when empty since they retain product residues (vapors, liquid); observe
all warnings and precautions listed for the product. Small quantities of peroxides can form
on prolonged storage. Exposure to light and/or air significantly increases the rate of
peroxide formation. If evaporated to a residue, the mixture of peroxides and isopropanol
may explode when exposed to heat or shock.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
For Isopropyl Alcohol (2-Propanol):
-OSHA Permissible Exposure Limit (PEL):
400 ppm (TWA)

-ACGIH Threshold Limit Value (TLV):
200 ppm (TWA), 400 ppm (STEL), A4 - not classifiable as a human carcinogen.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures
below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred
because it can control the emissions of the contaminant at its source, preventing dispersion
of it into the general work area. Please refer to the ACGIH document, Industrial
Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge
may be worn up to 50 times the exposure limit or the maximum use concentration specified
by the appropriate regulatory agency or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece
positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not
protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact. Neoprene and nitrile rubber are recommended
materials.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain
eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Page 4 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
Appearance:
Clear, colorless liquid.
Odor:
Rubbing alcohol.
Solubility:
Miscible in water.
Specific Gravity:
0.79 @ 20C/4C
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
82C (180F)
Melting Point:
-89C (-128F)
Vapor Density (Air=1):
2.1
Vapor Pressure (mm Hg):
44 @ 25C (77F)
Evaporation Rate (BuAc=1):
2.83
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage. Heat and sunlight can contribute to
instability.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Heat, flame, strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, hydrogen-
palladium combination, hydrogen peroxide-sulfuric acid combination, potassium tert-
butoxide, hypochlorous acid, isocyanates, nitroform, phosgene, aluminum, oleum and
perchloric acid.
Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.
11. Toxicological Information

Oral rat LD50: 5045 mg/kg; skin rabbit LD50: 12.8 gm/kg; inhalation rat LC50: 16,000
ppm/8-hour; investigated as a tumorigen, mutagen, reproductive effector.
Page 5 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Isopropyl Alcohol (67-63-0) No No 3
Water (7732-18-5) No No None
12. Ecological Information
Environmental Fate:
When released into the soil, this material is expected to quickly evaporate. When released
into the soil, this material may leach into groundwater. When released into the soil, this
material may biodegrade to a moderate extent. When released to water, this material is
expected to quickly evaporate. When released into the water, this material is expected to
have a half-life between 1 and 10 days. When released into water, this material may
biodegrade to a moderate extent. This material is not expected to significantly
bioaccumulate. When released into the air, this material is expected to be readily degraded
by reaction with photochemically produced hydroxyl radicals. When released into the air,
this material is expected to have a half-life between 1 and 10 days. When released into the
air, this material may be removed from the atmosphere to a moderate extent by wet
deposition.
Environmental Toxicity:
The LC50/96-hour values for fish are over 100 mg/l. This material is not expected to be
toxic to aquatic life.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste
and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility.
Processing, use or contamination of this product may change the waste management
options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local
requirements.
14. Transport Information
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: ISOPROPANOL
Hazard Class: 3
UN/NA: UN1219
Packing Group: II
Information reported for product/size: 200L

Page 6 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: ISOPROPANOL
Hazard Class: 3
UN/NA: UN1219
Packing Group: II
Information reported for product/size: 200L

15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Isopropyl Alcohol (67-63-0) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes

--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Isopropyl Alcohol (67-63-0) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes

--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Isopropyl Alcohol (67-63-0) No No Yes No
Water (7732-18-5) No No No No

--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Isopropyl Alcohol (67-63-0) No No No
Water (7732-18-5) No No No

Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity: No (Mixture / Liquid)

Australian Hazchem Code: 2[S]2
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
Page 7 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
16. Other Information
NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0
Label Hazard Warning:
WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR
INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. AFFECTS
CENTRAL NERVOUS SYSTEM. MAY BE HARMFUL IF ABSORBED THROUGH
SKIN. MAY CAUSE IRRITATION TO SKIN.
Label Precautions:
Keep away from heat, sparks and flame.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Avoid breathing vapor or mist.
Avoid contact with eyes, skin and clothing.
Label First Aid:
If swallowed, give large amounts of water to drink. Never give anything by mouth to an
unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes
or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and
shoes. Wash clothing before reuse. In all cases, get medical attention.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
Disclaimer:
*******************************************************************************

Mallinckrodt Baker, Inc. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by
a properly trained person using this product. Individuals receiving the information
must exercise their independent judgment in determining its appropriateness for a
particular purpose. MALLINCKRODT BAKER, INC. MAKES NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT
TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT
BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING
FROM USE OF OR RELIANCE UPON THIS INFORMATION.
*******************************************************************************

Prepared by: Environmental Health & Safety
Phone Number: [phone] (U.S.A.)
Page 8 of 8ISOPROPYL ALCOHOL (90 - 100%)
2/11/2008http://www.jtbaker.com/msds/englishhtml/i8840.htm
msds_liquinox_english_ansi
MS 01.40.01.01.06.1 Page 1 of 5
LIQUINOX MSDS
Section 1 : PRODUCT AND COMPANY IDENTIFICATION
Chemical family:Detergent.
Manufacturer:Alconox, Inc.
30 Glenn St.
Suite 309
White Plains, NY 10603.
Manufacturer emergency
phone number:
800-255-3924.
813-248-0585 (outside of the United States).
Supplier:Same as manufacturer.
Product name:Liquinox
Section 2 : INGREDIENT INFORMATION
C.A.S.CONCENTRATION
%Ingredient Name T.L.V.LD/50 LC/50
25155-
30-0
10-30 SODIUM
DODECYLBENZENESULFONATE
NOT
AVAILABLE
438
MG/KG
RAT
ORAL
1330
MG/KG
MOUSE
ORAL
NOT
AVAILABLE
Section 3 : HAZARD IDENTIFICATION
Route of entry:Skin contact, eye contact, inhalation and ingestion.
Effects of acute
exposure
Eye contact:May cause irritation.
Skin contact:Prolonged and repeated contact may cause irritation.
Inhalation:May cause headache and nausea.
Ingestion:May cause vomiting and diarrhea.
May cause gastric distress.
Effects of chronic
exposure:See effects of acute exposure.
Section 4 : FIRST AID MEASURES
Skin contact:Remove contaminated clothing.
Wash thoroughly with soap and water.
Seek medical attention if irritation persists.
Eye contact:Check for and remove contact lenses.
Flush eyes with clear, running water for 15 minutes while holding
eyelids open: if irritation persists, consult a physician.
Inhalation:Remove victim to fresh air.
If irritation persists, seek medical attention.
msds_liquinox_english_ansi
MS 01.40.01.01.06.1 Page 2 of 5
Ingestion:Do not induce vomiting, seek medical attention.
Dilute with two glasses of water.
Never give anything by mouth to an unconscious person.
Section 5 : FIRE FIGHTING MEASURES
Flammability:Not flammable.
Conditions of
flammability:Surrounding fire.
Extinguishing media:Carbon dioxide, dry chemical, foam.
Water
Water fog.
Special procedures:Self-contained breathing apparatus required.
Firefighters should wear the usual protective gear.
Use water spray to cool fire exposed containers.
Auto-ignition
temperature:Not available.
Flash point (°C),
method:None
Lower flammability
limit (% vol):Not applicable.
Upper flammability
limit (% vol):Not applicable.
Explosion Data
Sensitivity to static
discharge:Not available.
Sensitivity to mechanical
impact:Not available.
Hazardous combustion
products:
Oxides of carbon (COx).
Hydrocarbons.
Rate of burning:Not available.
Explosive power:Containers may rupture if exposed to heat or fire.
Section 6 : ACCIDENTAL RELEASE MEASURES
Leak/Spill:Contain the spill.
Prevent entry into drains, sewers, and other waterways.
Wear appropriate protective equipment.
Small amounts may be flushed to sewer with water.
Soak up with an absorbent material.
Place in appropriate container for disposal.
Notify the appropriate authorities as required.
Section 7 : HANDLING AND STORAGE
Handling procedures and
equipment:
Protect against physical damage.
Avoid breathing vapors/mists.
Wear personal protective equipment appropriate to task.
Wash thoroughly after handling.
Keep out of reach of children.
Avoid contact with skin, eyes and clothing.
Avoid extreme temperatures.
Launder contaminated clothing prior to reuse.
Storage requirements:Store away from incompatible materials.
Keep containers closed when not in use.
msds_liquinox_english_ansi
MS 01.40.01.01.06.1 Page 3 of 5
Section 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION
Precautionary Measures
Gloves/Type:
Wear appropriate gloves.
Respiratory/Type:None required under normal use.
Eye/Type:
Safety glasses recommended.
Footwear/Type:Safety shoes per local regulations.
Clothing/Type:As required to prevent skin contact.
Other/Type:Eye wash facility should be in close proximity.
Emergency shower should be in close proximity.
Ventilation
requirements:Local exhaust at points of emission.
Exposure limit of
material:Not available.
Section 9 : PHYSICAL AND CHEMICAL PROPERTIES
Physical state:Liquid.
Appearance & odor:Odourless.
Pale yellow.
Odor threshold (ppm):Not available.
Vapour pressure
(mmHg):
@ 20°C (68°F).
17
Vapour density (air=1):>1
Volatiles (%)
By volume:Not available.
Evaporation rate
(butyl acetate = 1):< 1.
Boiling point (°C):100 (212F)
Freezing point (°C):Not available.
pH:8.5
Specific gravity @ 20 °C:(water = 1).
1.083
Solubility in water (%):Complete.
Coefficient of water\oil
dist.:Not available.
VOC:None
Chemical family:Detergent.
Section 10 : STABILITY AND REACTIVITY
Chemical stability:Product is stable under normal handling and storage conditions.
Conditions of instability:Extreme temperatures.
msds_liquinox_english_ansi
MS 01.40.01.01.06.1 Page 4 of 5
Hazardous
polymerization:Will not occur.
Incompatible
substances:
Strong acids.
Strong oxidizing agents.
Hazardous
decomposition products:See hazardous combustion products.
Section 11 : TOXICOLOGICAL INFORMATION
LD50 of product, species
& route:> 5000 mg/kg rat oral.
LC50 of product, species
& route:Not available.
Sensitization to product:Not available.
Carcinogenic effects:Not listed as a carcinogen.
Reproductive effects:Not available.
Teratogenicity:Not available.
Mutagenicity:Not available.
Synergistic materials:Not available.
Section 12 : ECOLOGICAL INFORMATION
Environmental toxicity:No data at this time.
Environmental fate:No data at this time.
Section 13 : DISPOSAL CONSIDERATIONS
Waste disposal:In accordance with local and federal regulations.
Section 14 : TRANSPORT INFORMATION
D.O.T. CLASSIFICATION:Not regulated.
Special shipping
information:Not regulated.
Section 15 : REGULATORY INFORMATION
Canadian Regulatory
Information
WHMIS classification:Not controlled.
DSL status:Not available.
USA Regulatory
Information
SARA hazard catagories
sections 311/312:
Immediate (Acute) Health Hazard: No.
Delayed (Chronic) Health Hazard: No.
Fire Hazard: No.
Sudden Release of Pressure: No.
Reactive: No.
SARA Section 313:None
TSCA inventory:All components of this product are listed on the TSCA inventory.
msds_liquinox_english_ansi
MS 01.40.01.01.06.1 Page 5 of 5
NFPA
Health Hazard:1
Flammability:0
Reactivity:0
HMIS
Health Hazard:1
Flammability:0
Physical hazard:0
PPE:A
Section 16 : OTHER INFORMATION
Supplier MSDS date:2006/07/14
Data prepared by:Global Safety Management
3340 Peachtree Road, #1800
Atlanta, GA 30326
Phone: [phone]
Fax: [phone]
Web: www.globalsafetynet.com
Email: [e-mail].
General note:This material safety data sheet was prepared from information
obtained from various sources, including product suppliers and
the Canadian Center for Occupational Health and Safety.