Loading...
HomeMy WebLinkAboutAS-3132_28327_CA_MRP_20200204 February 4, 2020 Mr. Dan Murphy North Carolina Department of Environmental Quality Division of Waste Management Underground Storage Tank Section 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: GROUNDWATER MONITORING REPORT GPM 3089 (FORMER SCOTCHMAN #89) 3045 TYNECASTLE HIGHWAY BANNER ELK, AVERY COUNTY, NORTH CAROLINA UST INCIDENT NO.: 28327 Dear Mr. Murphy: On behalf of GPM Southeast, LLC, CES of NC, PLLC is providing the enclosed Groundwater Monitoring Report for the above referenced site. If you have any questions, please contact us at (540)-343-6256. Sincerely, CES of NC, PLLC Daniel Fisher, PMP Allison E. Streams Director of Mid-Atlantic Operations Project Manager CC: Mr. Rolfe Lann, GPM Southeast, LLC GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089-D (Former Scotchman #89) GROUNDWATER MONITORING REPORT DECEMBER 2019 GPM 3089-D (FORMER SCOTCHMAN NO. 89) 3045 TYNECASTLE HIGHWAY BANNER ELK, NORTH CAROLINA UST INCIDENT NO.: 28327 CES OF NC, PLLC PROJECT NUMBER: 9.0411 FEBRUARY 04, 2020 PREPARED BY: CES OF NC, PLLC 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 Phone: 980-819-9333; Fax: 540-343-6259 PREPARED FOR: GPM SOUTHEAST, LLC Mr. Rolfe Lann Director of Environmental 8565 Magellan Parkway, Suite 400 Richmond, Virginia 23227 NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY Mr. Dan Murphy Division of Waste Management Underground Storage Tank Section Corrective Action Branch 2090 US 70 Highway Swannanoa, North Carolina 28788 GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT i GROUNDWATER MONITORING REPORT SITE INFORMATION Site Identification Date of Report: February 4, 2020 Site Name: GPM 3089-D (Former Scotchman #89) 3045 Tynecastle Highway Banner Elk, Avery County, North Carolina Facility I.D.: 24878 UST Incident Number: 28327 Risk Rank: High (H375D) Latitude: 36.134278 Longitude: -81.848694 Source: UST Database Site Contact Information UST Owner and Operator: GPM Southeast, LLC 8565 Magellan Parkway, Suite 400 Richmond, Virginia 23227 +1 804 730 1568 Property Property Owner: Norwood Family Limited Partnership Occupant: Sugar Creek Gem Mine 4370 Woodbourne Drive 3045 Tynecastle Highway Clemmons, NC 27012 Banner Elk, North Carolina Consultant: CES of NC, PLLC 6201 Fairview Road, Suite 210 Charlotte, NC 28210 +1 540 343 6256 Analytical State Laboratory: Pace Analytical Certification No. 5342 Address: 9800 Kincey Ave., Suite 100 Huntersville, NC +1 704 875 9092 Release Information Date Discovered: 6/20/2005 Estimated Quantity of Release: Undetermined Cause of Release: UST systems and surface spill Source of Release: Former gasoline UST systems UST Information: Formerly three gasoline, one diesel, and one kerosene USTs GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT iii EXECUTIVE SUMMARY As required, the following executive summary provides the most pertinent information for this assessment. For additions information please refer to subsequent sections of this report. • CES of NC, PLLC (CES) was retained by GPM Southeast, LLC (GPM) to complete a groundwater monitoring event in December 2019. The activities were requested in a “Notice of Regulatory Requirements” dated February 12, 2019 issued by the North Carolina Department of Environmental Quality (NCDEQ). The services were provided in general accordance with the NCDEQ “Guidelines for Assessment and Corrective Action for UST Releases” and approved task authorization 28327-29. • Historical site assessments include a Limited Site Assessment, Comprehensive Site Assessment and multiple groundwater monitoring events. Most recently, a monitoring event completed in December 2018 indicated groundwater contamination in excess of groundwater quality standards in monitoring wells MW-3R and MW-6. • CES personnel mobilized to the site on December 4, 2019 for completion of a comprehensive groundwater monitoring event. Monitoring wells MW-1, MW-1D, MW-2, MW-3R and MW-6 were gauged and sampled for volatile organic compounds including oxygenates by Standard Methods 6200B and for Lead using Method 6010B. Water supply wells WSW-1, WSW-3 and WSW-4 were also sampled. • Groundwater samples collected from site monitoring wells indicated groundwater impacts in excess of groundwater quality standards, however no detections were reported above GCLs. Free product was not encountered in site monitoring wells. Groundwater samples collected from the water supply wells indicated no contaminant impacts above groundwater quality standards. • Shallow groundwater flow direction was interpreted to trend over all to the north-west. • In conclusion, CES recommends a groundwater monitoring event to include geochemical parameters for natural attenuation. Results of the monitoring event should be utilized to develop a groundwater fate and transport model to predict any potential impacts to receptors. If the modeling indicates favorable conditions under natural attenuation, the incident should be considered for closure. GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT iv TABLE OF CONTENTS Site Information .......................................................................................................................... i Report Certification .................................................................................................................... ii Executive Summary .................................................................................................................. iii List of Figures ........................................................................................................................... iv List of Tables ............................................................................................................................ iv List of Appendices .................................................................................................................... iv 1.0 Background Information ................................................................................................. 1 1.1 Site Location .................................................................................................................1 1.2 Site History ...................................................................................................................1 2.0 Potential Receptor Information ....................................................................................... 1 2.1 Water Supply and Surface Water...................................................................................2 2.2 Description of Subsurface Geology ...............................................................................2 2.3 Subsurface Structures ....................................................................................................3 2.4 Surrounding Land Use ..................................................................................................3 3.0 Recent Activities ............................................................................................................ 3 3.1 Groundwater Sampling .................................................................................................3 3.2 Groundwater Occurrence and Flow Direction................................................................3 3.3 Laboratory Results ........................................................................................................4 4.0 Conclusions and Recommendations ................................................................................ 4 4.1 Conclusions ..................................................................................................................4 4.2 Recommendations .........................................................................................................4 LIST OF FIGURES Figure 1 Site Location Map Figure 2 Site Map Figure 3 Potentiometric Map – 12/4/2019 Figure 4 Estimated Extent of NCAC 2L Exceedances in Groundwater – 12/4/2019 Figure 5 1500ft Radius Water Supply Well Map LIST OF TABLES Table 1 UST System and Other Release Information Table 2 Water Supply Well Information Table 3 Groundwater Elevation Data Table 4 Groundwater Analytical Data Table 5 Additional Water Supply Well Information LIST OF APPENDICES Appendix A Recent Correspondence Appendix B Groundwater Sampling Logs Appendix C Laboratory Report(s) and Chain of Custody Documentation GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT 1 1.0 BACKGROUND INFORMATION The following provides background information pertaining to the site location, characteristics, and history regarding assessment for the release from the former UST system. 1.1 SITE LOCATION The GPM 3089 facility (Former Scotchman #89), herein referred to as the site, is located at 3045 Tynecastle Highway, Banner Elk, Avery County, North Carolina. Figure 1 is a topographic vicinity map of the surrounding area and Figure 2 is a site map depicting pertinent site features. The property is owned by the Norwood Family Limited Partnership and currently operates as Sugar Creek Gem Mine. Historically the site was owned and operated by Worsley Companies, Inc. as a retail service station from 1983 until 2005. Worsley operated five underground storage tanks (UST) including: three 6,000-gallon gasoline USTs, one 4,000-gallon kerosene UST, and one 4,000-gallon diesel UST; the USTs were removed in 2005. The history of the former underground storage tank (UST) systems is summarized in Table 1. 1.2 SITE HISTORY Detailed site history has been provided in previous reports submitted to the NCDEQ. During UST closure assessment activities in June 2005, it was determined that a gasoline release had occurred. Consequently, the NCDEQ requested that a Phase I Limited Site Assessment (LSA) be performed for the site. LSA activities were initiated by Geological Resources, Inc. (GRI) of Charlotte, North Carolina, on July 11, 2007, with the installation of one source area monitoring well (MW-1). The LSA indicated the presence of petroleum compounds above the North Carolina groundwater quality standards as defined in North Carolina Administrative Code Title 15A Chapter 2L .0202 (2L Standards). On February 18, 2008, Best Geologic and Environmental Consulting, P.A. (Best) advanced five soil probes to define the extent of impacted soil. Best installed four new 2-inch diameter Type II monitoring wells (MW-2, MW-3, MW-4, and MW-5) on March 13 and 14, 2008, to complete the horizontal delineation of the petroleum compounds in groundwater. One Type III groundwater monitoring well (MW-1D) was installed to determine the vertical extent of impacted groundwater. One additional monitoring well (MW-6) was installed by Best on June 5, 2008 to further define the extent of impacted groundwater. Laboratory analyses of the groundwater sample collected from MW-6 indicated that the horizontal delineation of groundwater impact had been completed. On June 16, 2010, Best installed a 2-inch Type II monitoring well (MW-3R) to replace MW-3 which was damaged beyond repair during parking lot improvement activities. In addition to the installation of MW-3R, the manways for monitoring wells MW-1 and MW-5 were replaced. A total of seven groundwater monitoring wells have been installed at the site to assess the release. Most recently, CES personnel performed a groundwater monitoring event in December 2018. Groundwater samples collected from site monitoring wells indicated groundwater impacts in excess of groundwater quality standards, however no detections were reported above GCLs. Free product was not encountered in site monitoring wells. Groundwater samples collected from the water supply wells indicated no contaminant impacts above groundwater quality standards. 2.0 POTENTIAL RECEPTOR INFORMATION CES evaluated receptors based on historically available information and current site conditions as discussed below. GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT 2 2.1 WATER SUPPLY AND SURFACE WATER As part of the Comprehensive Site Assessment (CSA) reported August 18, 2008, Best updated the receptor survey by walking the area within 500 feet of the subject site to identify any water supply wells. In addition, Best mailed a Water Supply Well Survey to each property owner within 500 feet of the source area. Thirty- one water supply wells have been identified within 1,500 feet of the source area, and 21 water supply wells have been identified within 1,000 feet of the source area. Two water wells have been identified within 250 feet of the source area. These wells are used as sources of potable water but are situated up gradient of the source area. The locations of the identified water supply wells are shown on Figure 5, and the owner information for the sampled wells WSW-1, WSW-3, and WSW-4 is included in Table 2. Carolina Water of North Carolina (Carolina Water) provides potable water to the subject site and the area west and northwest of the subject site. Water service is not available east of the subject site or south along Tynecastle Highway. Carolina Water obtains water from 23 fractured bedrock wells. Carolina Water operates a community well on behalf of the Ski Country development. This well is located 785 feet northwest of the source area. According to the North Carolina Division of Water Quality Wellhead Protection website, the source area is not located within a designated wellhead protection area as defined in 42 USC 300h-7(e) and is not located in the Coastal Plain physiographic region. CES reviewed a United States Geological Survey (USGS) 7.5 Minute Quadrangle Topographic Map (Figure 1) to identify possible surface water bodies in the vicinity of the site. Two surface water bodies are present within 500 feet of the source area. The nearest surface water body is an unnamed tributary of the Elk River located approximately 25 feet north of the source area. A pond is located 150 feet northeast of the source area. The Elk River is classified as B and C waters and designated as public trout waters. 2.2 DESCRIPTION OF SUBSURFACE GEOLOGY As reported by previous consultants, the subject site is located along the northern margin of the Grandfather Mountain Window in the Blue Ridge Tectonic province. The site is underlain by Grandfather Mountain Formation. The site is located immediately south of a perennial stream near its confluence with the Elk River. The site is subject to flooding and was severely impacted in 2004 when the remnants of a hurricane passed through the area. The source area is covered by asphalt pavement and slopes from east to west. The grade of the site appears to have been raised by the placement of fill material. Fill material described as poorly sorted boulders, cobbles, gravel, wood within a matrix of clayey sandy silt was encountered from the ground surface to depths ranging from eight to 15 feet below the ground surface. Beneath the fill material, alluvial soils consisting of cobbles, gravel and sandy silt were encountered. Partially weathered rock was encountered at a depth of 28 feet and competent rock was encountered at a depth of 40 feet during the drilling of vertical extent well MW-1D. The groundwater flow appears to be influenced by the poorly sorted fill material and the proximity to the stream. The hydraulic gradient at the source area was estimated at 0.093 feet per foot, while the hydraulic gradient on the western part of the site was 0.125 feet per foot (as reported in the August 18, 2008 CSA). On March 14, 2008, slug tests were performed on wells MW-2 and MW-4 to estimate the hydraulic conductivity (K) of the regolith aquifer. Prior to the start of the test, the static water level of each well was measured. A slug of water was removed using a new disposable bailer. The recovery of the well water over time was recorded. The estimated hydraulic conductivity and the hydraulic gradient were used to estimate GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT 3 an average linear groundwater velocity of 4.92 feet per year at the source area and 60.23 feet per foot on the western part of the site. 2.3 SUBSURFACE STRUCTURES An underground natural gas line is present immediately north and northwest of the source area. A storm water culvert is situated 60 feet west of the source area. It does not appear that these structures have influenced contaminant migration. 2.4 SURROUNDING LAND USE The subject site is zoned for highway business. Land use for the surrounding area is primarily commercial along Tynecastle Highway. The majority of the land to the north and east is single-family residential. The land to the west across Tynecastle Highway is part of the Sugar Mountain ski area. The nearest residence is a single-family dwelling located approximately 160 feet east of the source area. The nearest public gathering place is the Banner Elk Church of Christ located 550 feet west of the source area. 3.0 RECENT ACTIVITIES CES performed a groundwater monitoring event in accordance with the NCDEQ approved pre-approval task authorization (PATA) 28327-29. A copy of the approved PATA form is included in Appendix A. 3.1 GROUNDWATER SAMPLING On December 4, 2019 CES collected groundwater samples from monitoring wells MW-1, MW-1D, MW-2, MW-3R and MW-6, and from water supply wells WSW-1, WSW-3 and WSW-4. Please note that during the December 2019 sampling event MW-1D was misidentified as MW-5 on the well sampling form and in the analytical report. Monitoring wells MW-4 and MW-5 were unable to be located and believed to be under a gem mining exhibit on the site. The monitoring wells were located, accessed and gauged for depth to water and total well depth through the use of an electronic oil-water interface probe after allowing the water levels in the wells time to equilibrate at atmospheric pressure. At this time, free product was not detected at the site. A summary of well construction and recent gauging data is included in Table 3. Following gauging, each monitoring well was purged of at least three well volumes, or until dry, using dedicated disposable bailers. To reduce the potential of cross contamination, new, clean, disposable nitrile gloves were worn during all phases of sample handling. Groundwater sampling logs indicating purge volumes, sample times, and physical parameters recorded at the time of sampling by a calibrated groundwater quality multi-parameter meter are included in Appendix B. Samples were placed into laboratory supplied containers pre-filled with appropriate preservatives and labeled with indelible ink. Following collection, samples were immediately placed on wet ice in laboratory supplied coolers and transported to Pace Analytical Services, LLC (Pace) located in Huntersville, NC, a North Carolina certified laboratory, for chemical analysis. The samples were analyzed for volatile organic compounds (VOCs) including ethanol and the five oxygenates by Standard Methods 6200B and for Lead using Method 3030C. 3.2 GROUNDWATER OCCURRENCE AND FLOW DIRECTION Depth to groundwater ranged from 6.22 (MW-6) to 13.52 (MW-2) feet below top of casing (TOC) during the groundwater sampling event completed on December 4, 2019. Liquid phase hydrocarbons (LPH) were not were detected during the December 4, 2019 sampling event. Table 3 presents historical groundwater elevation data. Figure 3 presents a Groundwater Elevation Contour Map constructed using data from the GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT 4 December 2019 sampling event. According to the data, groundwater flows to the northwest at the subject site. 3.3 LABORATORY RESULTS Benzene was detected above the NCAC 2L Standard of 1 ug/L in MW-3R (13.1 ug/L), MTBE was detected above the NCAC 2L Standard of 20 ug/L in MW-3R (25.6 ug/L), Tert-Butyl Alcohol (TBA) was detected above the NCAC 2L Standard of 10 ug/L in MW-3R (53.1 ug/L) and Lead was detected above the NCAC 2L Standard of 15 ug/L in MW-1, MW-2, MW-3R and W-6 with a maximum concentration of 286 ug/L in MW-1. None of the analytes tested for were detected above NCAC 2L Standards in WSW-1, WSW-3 or WSW-4. Free product was not detected during the December 4, 2019 groundwater monitoring event. Analytical results are provided in Table 4 and presented on Figure 4. Chain-of-custody documentation and laboratory data reports area included as Appendix C. 4.0 CONCLUSIONS AND RECOMMENDATIONS 4.1 CONCLUSIONS The following conclusions are provided based upon the information and data collected during the December 2019 sampling event and evaluated by CES; • Free product was not detected during the December 4, 2019 groundwater monitoring event. • Benzene, MTBE and TBA were detected above the NCAC 2L Standards in MW-3R and Lead was detected above the NCAC 2L Standards in MW-1, MW-2, MW-3R and MW-6. • Detections of Lead may be attributed to turbidity in the samples and/or elevated natural background concentrations. • None of the analytes tested for were detected above NCAC 2L Standards in water supply wells WSW-1, WSW-3 or WSW-4. • CES was unable to locate MW-4, and MW-5 during the December 4, 2019 groundwater monitoring event. 4.2 RECOMMENDATIONS Based on the data collected during groundwater monitoring activities, CES recommends a comprehensive groundwater monitoring event with inclusion of geochemical parameters for natural attenuation from select monitoring wells. Due to the lack of impact at receptors to date and the apparent stability of the plume, results from the monitoring event should be utilized in groundwater fate and transport modeling to determine any potential future impact to receptors under natural attenuation as a path to incident closure. Groundwater samples should be collected from monitoring wells MW-1, MW-1D, MW-2, MW-3R, MW- 4, MW-5, MW-6, and from water supply wells WSW-1, WSW-3, and WSW-4 for analysis of lead and EPA Method 602 compounds including benzene, toluene, ethylbenzene, total xylenes, methyl tert-butyl ether, diisopropyl ether, and naphthalene. Additionally, a surface water sample should be collected from the creek downgradient of the source area and analyzed as above. CES will make reasonable efforts to locate and sample MW-4 and MW-5. Lead was detected above the NCAC 2L Standard in MW-1, MW-2, MW-3R and MW-6 during the December 2019 sampling event. The June 2013 Groundwater Monitoring Report submitted by Best (dated July 29, 2013) suggests lead exceedances detected at the site may be naturally occurring and stated they do not correspond to their understanding of the gasoline plume. Further testing for metals should be conducted via low flow sampling GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT 5 techniques to determine if the lead exceedances are due to turbidity and to evaluate concentrations of lead suspended in and moving within the aquifer. 5.0 REMARKS The recommendations contained in this report represent CES of NC, PLLC’s professional opinions based upon the currently available information and are arrived at in accordance with currently accepted professional standards. This report is based upon a specific scope of work requested by the client. The contract between CES of NC, PLLC and its client outlines the scope of work, and only those tasks specifically authorized by that contract or outlined in this report were performed. This report is intended only for the use of CES of NC, PLLC’s client and anyone else specifically identified in writing by CES of NC, PLLC as a user of this report. CES of NC, PLLC will not and cannot be liable for unauthorized reliance by any other third party. Other than as contained in this paragraph, CES of NC, PLLC makes no express or implied warranty as to the contents of this report. 6.0 REFERENCES • Geologic Map of North Carolina, September 29, 2015 - North Carolina Geological Survey • North Carolina Division of Water Resources website: https://deq.nc.gov/about/divisions/water-resources • Comprehensive Site Assessment, August 18, 2008 - Best Geologic and Environmental Consulting, P.A. • Groundwater Monitoring Report, July 29, 2013 – Best Geologic and Environmental Consulting, P.A. GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT FIGURES 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (office) 540-343-6259 (fax) FIGURE 1 Site Location Map GPM 3089-D 3045 Tynecastle Highway Banner Elk, North Carolina Banner Elk, North Carolina Project: Client: GPM Southeast, LLC CES NC Job #: 9.0411 Date: 1/16/2020 Latitude: 36°08'08.5"N Longitude: 81°50'42.3"W Site Location 2019 Annual Groundwater Monitoring Report U.S.G.S Topographic Map of the Valle Crucis Quadrangle, North Carolina, 7.5 Minute Series (revised 2016) Scale: 1:24,000 Contour Interval: 40 Feet Source: National Geodetic Vertical Datum 1988 Horizontal Datum:North American Datum 1983 Vertical Datum: Project No: Date: Revision: Project Manager: Drawn By: Checked By: 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) CLIENT: LOCATION: GPM 3089-D Site Map Figure 23045 Tynecastle Highway, Banner Elk, NC GPM Southeast, LLC DJF RAR 2019 Groundwater Monitoring Report 9.0411 01/16/20 0 Incident #: 28327 0 40'80'160' 1 inch equals 80 feet Water Supply Well (WSW) Location WSW-4 Legend Monitoring Well (MW) Location WSW-1 WSW-3 MW-5 MW-1/1D MW-3R MW-6 MW-2 MW-4 Project No: Date: Revision: Project Manager: Drawn By: Checked By: 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) CLIENT: LOCATION: GPM 3089-D Potentiometric Map (12/4/2019) Figure 33045 Tynecastle Highway, Banner Elk, NC GPM Southeast, LLC DJF RAR 2019 Groundwater Monitoring Report 9.0411 01/16/20 0 Incident #: 28327 Water Supply Well (WSW) Location 0 40'80'160' 1 inch equals 80 feet WSW-4 Legend Monitoring Well (MW) Location WSW-1 WSW-3 MW-5 MW-1/1D 93.01' MW-6 94.66' MW-2 84.47' 94.00' 92.00' 90.00' 88.00' 86.00' Groundwater Contour Line Groundwater Flow Direction MW-3R 89.36' MW-4 Project No: Date: Revision: Project Manager: Drawn By: Checked By: 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) CLIENT: LOCATION: GPM 3089-D NCAC 2L Standard Exceedances Map (12/4/2019) Figure 43045 Tynecastle Highway, Banner Elk, NC GPM Southeast, LLC DJF RAR 2019 Annual Groundwater Monitoring Report 9.0411 01/31/20 0 Incident #: 28327 Water Supply Well (WSW) Location 0 40'80'160' 1 inch equals 80 feet WSW-4 Legend Monitoring Well (MW) Location WSW-1 WSW-3 MW-5 MW-3R Benzene: 13.1 MTBE: 25.6 Lead: 29.6 MW-2 Lead: 25.7 Lead > 15 Contour Line Benzene > 1 Contour Line All concentrations in ug/L MW-1 MTBE: 10.4 Lead: 286 MW-6 Lead: 81.3 MW-4 MTBE > 20 Contour Line Project No: Date: Revision: Project Manager: Drawn By: Checked By: 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) CLIENT: LOCATION: GPM 3089 WSWs within 1500 ft Radius Map Figure #3045 Tynecastle Highway, Banner Elk, NC GPM Investments Inc. DJF RAR 2019 Groundwater Monitoring Report 9.0411 01/31/20 0 Incident #: 28327 Water Supply Well (WSW) Location 0 250'500'1,000' 1 inch equals 500 feet Legend WSW-1 WSW-4 WSW-3 WSW-23 WSW-25 WSW-31 WSW-18 WSW-7 WSW-8 WSW-9 WSW-13 WSW-11 WSW-19 WSW-30WSW-18WSW-17 WSW locations approximate Figure adapted from: 2008 CSA Figure 2 - Water Wells GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT TABLES Table 1 UST/AST SYSTEM AND OTHER RELEASE INFORMATION GPM 3089 (Scotchman #89) Banner Elk, Avery County, North Carolina Incident No. 28327 UST ID Number Current/Last Contents (in Construction Details Associated Piping and Date Tank Installed Status of UST associated with 1 Gasoline 6000 Single-Walled Steel Double-Walled Steel, pressurized 4/16/1983 Removal Yes 2 Gasoline 6000 Single-Walled Steel Other, pressurized 4/16/1983 Removal Yes 3 Gasoline 6000 Single-Walled Steel Other, pressurized 4/16/1983 Removal Yes 4 Kerosene 4000 Single-Walled Steel Other, suction 4/16/1983 Removal No 5 Diesel 4000 Single-Walled Steel Double-Walled Steel, pressurized 4/16/1983 Removal No Incident Number Discovered Released 28327 6/20/2005 Gasoline Notes: - UST information provided by NCDEQ Registered Tanks Database Discovery of Release UST closures Map ID/ Well Number Property Location Owner Address Property Owner Well Use Connected To Municipal Water System Well Depth (ft. BGS) Type of Well Well Casing Depth (ft. BGS) Approximate Distance of Well from Source Area of Release (ft.) WSW-1 65 Arnett Road Banner Elk, NC 28604 55 Paupers Ridge Road Banner Elk, NC 28604 Norwood Family Limited Partnership Potable No Unknown Unknown Unknown 250 East WSW-3 55 Paupers Ridge Road Banner Elk, NC 28604 55 Paupers Ridge Road Banner Elk, NC 28604 Bettie Norwood Potable No Unknown Drilled Unknown 420 Northwest WSW-4 3071 Tynecastle Hwy Banner Elk, NC 28604 PO Box 1175 Banner Elk, NC 28604 Banner Elk Sports Properties, LLC Potable No Unknown Drilled Unknown 250 Southeast TABLE 2 SAMPLED WATER SUPPLY WELL INFORMATION GPM 3089 (Former Scotchman #89) 3045 Tynecastle Highway, Banner Elk, NC Incident No. 28327 Page 2 of 7 Well ID Date Elevation1 from TOC Groundwater Depth Interval 6/5/2008 99.58 7.44 92.14 19 4-19 6/25/2013 99.58 5.39 94.19 19 4-19 12/8/14 99.58 7.30 92.28 19 4-19 1/26/2016 99.58 7.05 92.53 19 4-19 10/19/2017 99.58 6.72 92.86 19 4-19 12/6/2018 99.58 6.40 93.18 19 4-19 12/4/2019 99.58 6.57 93.01 19 4-19 6/5/2008 99.11 7.28 91.83 40 35-40 12/8/14 99.11 6.75 92.36 40 35-40 1/26/2016 99.11 6.31 92.80 40 35-40 12/6/2018 99.11 N/A N/A 40 35-40 12/4/2019 99.11 7.03 92.08 40 35-40 6/5/2008 97.99 13.41 84.58 20 5-20 1/26/2013 97.99 13.06 84.93 20 5-20 12/8/14 97.99 13.25 84.74 20 5-20 1/26/2016 97.99 13.45 84.54 20 5-20 10/19/2017 97.99 13.55 84.44 20 5-20 12/6/2018 97.99 13.34 84.65 20 5-20 12/4/2019 97.99 13.52 84.47 20 5-20 MW-3 6/5/2008 100.00 8.81 91.19 14 4-14 6/25/2013 96.31 5.74 90.57 14 4-14 12/8/14 96.31 6.00 90.31 14 4-14 1/26/2016 96.31 6.60 89.71 14 4-14 10/19/2017 96.31 6.55 89.76 14 4-14 12/6/2018 96.31 6.86 89.45 14 4-14 12/4/2019 96.31 6.95 89.36 14 4-14 6/5/2008 99.68 6.30 93.38 20 5-20 12/4/2019 6/5/2008 98.70 7.65 91.05 20 5-20 6/25/2013 98.70 7.45 91.25 20 5-20 12/8/14 98.70 7.80 90.90 20 5-20 1/26/2016 98.70 7.50 91.20 20 5-20 12/4/2019 6/5/2008 100.88 6.11 94.77 15 5-15 6/25/2013 100.88 6.38 94.50 15 5-15 12/8/14 100.88 6.81 94.07 15 5-15 1/26/2016 100.88 6.43 94.45 15 5-15 10/19/2017 100.88 6.62 94.26 15 5-15 12/6/2018 100.88 6.35 94.53 15 5-15 12/4/2019 100.88 6.22 94.66 15 5-15 Notes Top-of-casing (TOC) elevations are based on an arbitrary benchmark elevation of 100.00 feet above mean sea level. GPM 3089 (Former Scotchman #89) GROUNDWATER ELEVATION DATA TABLE 3 Incident No. 28327 3045 Tynecastle Highway, Banner Elk, NC MW-1 MW-1D MW-2 MW-3R MW-4 MW-5 MW-6 Page 3 of 7 Well ID Date Benzene (μg/L)Toluene (μg/L)Ethylbenzene (μg/L)Total Xylenes (μg/L) Methy Tert-Butyl Ether (μg/L) Di-Isopropyl Ether(μg/L)Naphthalene (μg/L)Lead (μg/L)Ethanol (μg/L)Tert-Amyl Alcohol (μg/L) Tert-Amylmethyl Ether (μg/L) Tert-Butyl Alcohol (μg/L)Tert-Butyl Formate (μg/L)Ethyl Tert-Butyl Ether (μg/L) 1 600 600 500 20 70 6 15 NSE 40 128 10 40 47 5,000 260,000 84,500 85,500 20,000 25,000 6,000 15,000 NSE 40,000 12,800 10,000 40,000 47,000 7/11/2007 9.3 5.45 38.1 49.3 974 6.03 N/A 221 N/A N/A N/A N/A N/A N/A 6/25/2013 <1 <5 <1 NA 14 <1 N/A 190 N/A N/A N/A N/A N/A N/A 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U 34.2 NA N/A 58.8 N/A N/A N/A N/A N/A N/A 1/26/2016 0.390 J < 0.0570 U < 0.0920 U < 0.122 U 44.1 0.430 J N/A NA N/A N/A N/A N/A N/A N/A 10/19/2017 0.31 J < 0.17 < 0.13 < 0.39 23 0.23 J N/A 66 N/A N/A N/A N/A N/A N/A 12/6/2018 <.5 <.5 <.5 <1 10.4 <.5 N/A 8.7 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 10.4 <1.0 <2.0 286 <200 <100 <10.0 <20.0 <20.0 <10.0 3/14/2008 <1 <1 <1 <2 <1 <1 N/A 10.7 N/A N/A N/A N/A N/A N/A 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A < 3.30 U N/A N/A N/A N/A N/A N/A 1/26/2016 < 0.119 U < 0.0570 U < 0.0920 U < 0.122 U < 0.169 U < 0.0920 U N/A NA N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <2.0 <5.0 <200 <100 <10.0 <20.0 <20.0 <10.0 3/13/2008 1.9 <1 1.5 16.7 5.2 <1 N/A 527 N/A N/A N/A N/A N/A N/A 6/25/2013 <1 <5 <1 NA <1 <1 N/A 28 N/A N/A N/A N/A N/A N/A 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A 14 N/A N/A N/A N/A N/A N/A 1/26/2016 < 0.119 U < 0.0570 U < 0.0920 U < 0.122 U < 0.169 U < 0.0920 U N/A NA N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 < 0.17 < 0.13 < 0.39 < 0.090 < 0.18 N/A 60 N/A N/A N/A N/A N/A N/A 12/6/2018 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 N/A 5.4 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <2.0 25.7 <200 <100 <10.0 <20.0 <20.0 <10.0 MW-3 3/13/2008 424 2,220 492 3,050 1,760 <100 N/A 134 N/A N/A N/A N/A N/A N/A 6/25/2013 36 <25 65 NA 250 13 N/A 180 N/A N/A N/A N/A N/A N/A 12/8/2014 3.77 J < 0.268 U 6.08 6.37 31.2 NA N/A 11 N/A N/A N/A N/A N/A N/A 1/26/2016 1.30 0.100 J 2.18 1.11 30.1 8.91 N/A NA N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 < 0.17 0.17 1.9 2.6 2.8 N/A 22 N/A N/A N/A N/A N/A N/A 12/6/2018 1.3 <0.17 0.72 <1 8.2 <.50 N/A 5.4 N/A N/A N/A N/A N/A N/A 12/4/2019 13.1 <1.0 18.6 <3.0 25.6 4.9 2.2 29.6 <200 <100 <10.0 53.1 <20.0 <10.0 3/13/2008 <2.5 <2.5 <2.5 16.7 <2.5 <2.5 N/A 157 N/A N/A N/A N/A N/A N/A 3/13/2008 <1 <1 <1 <2 <1 <1 N/A 157 N/A N/A N/A N/A N/A N/A 6/24/2009 <1 <1 <1 <2 <1 <1 N/A 41.2 N/A N/A N/A N/A N/A N/A 9/10/2009 <1 <1 <1 <2 <1 <1 N/A 147 N/A N/A N/A N/A N/A N/A 12/16/2009 <1 <1 <1 <2 1 <2 N/A 72.1 N/A N/A N/A N/A N/A N/A 3/1/2010 <1 <1 <1 <2 1 <1 N/A 203 N/A N/A N/A N/A N/A N/A 6/23/2010 <1 <1 <1 <3 <1 <1 N/A 309 N/A N/A N/A N/A N/A N/A 12/20/2010 <1 <5 <1 <3 1 <1 N/A 160 N/A N/A N/A N/A N/A N/A 6/21/2011 <1 <5 <1 <3 2 <1 N/A 740 N/A N/A N/A N/A N/A N/A 12/12/2011 <1 <5 <1 <3 <1 <1 N/A 780 N/A N/A N/A N/A N/A N/A 6/28/2012 <1 <5 <1 <3 <1 <1 N/A 220 N/A N/A N/A N/A N/A N/A 9/26/2012 <1 <5 <1 <3 <1 <1 N/A 220 N/A N/A N/A N/A N/A N/A 12/19/2012 <1 <5 <1 <3 <1 <1 N/A <5 N/A N/A N/A N/A N/A N/A 12/4/2019 3/14/2008 <1 2.3 <1 2.3 3.1 <1 N/A 1390 N/A N/A N/A N/A N/A N/A 6/24/2009 <1 <1 <1 <2 10.5 <1 N/A 8 N/A N/A N/A N/A N/A N/A 9/10/2009 <1 <1 <1 <2 22.9 <1 N/A 28.7 N/A N/A N/A N/A N/A N/A 12/16/2009 <1 <1 <1 <2 9 <2 N/A 30 N/A N/A N/A N/A N/A N/A 6/23/2010 <1 <1 <1 <3 1.8 <1 N/A 154 N/A N/A N/A N/A N/A N/A 9/30/2010 <1 <5 <1 <3 <1 <1 N/A 160 N/A N/A N/A N/A N/A N/A 12/20/2010 <1 <5 <1 <3 6 <1 N/A 76 N/A N/A N/A N/A N/A N/A 3/23/2011 <1 <5 <1 <3 2.6 <1 N/A 82 N/A N/A N/A N/A N/A N/A 6/21/2011 <1 <5 <1 <3 <1 <1 N/A 97 N/A N/A N/A N/A N/A N/A 9/27/2011 <1 <5 <1 <3 2.8 <1 N/A 51 N/A N/A N/A N/A N/A N/A 12/12/2011 <1 <5 <1 <3 <1 <1 N/A 53 N/A N/A N/A N/A N/A N/A 3/15/2012 <1 <5 <1 <3 <1 <1 N/A 46 N/A N/A N/A N/A N/A N/A 6/28/2012 <1 <5 <1 <3 2.2 <1 N/A 17 N/A N/A N/A N/A N/A N/A 9/26/2012 <1 <1 <1 <3 2.3 <1 N/A 75.4 N/A N/A N/A N/A N/A N/A 12/19/2012 <1 <1 <1 <3 <1 <1 N/A <5 N/A N/A N/A N/A N/A N/A 6/25/2013 <1 <1 <1 <3 <1 <1 N/A 25 N/A N/A N/A N/A N/A N/A 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A 10.9 N/A N/A N/A N/A N/A N/A 1/26/2016 < 0.119 U < 0.0570 U < 0.0920 U < 0.122 U 1.59 < 0.0920 U N/A NA N/A N/A N/A N/A N/A N/A 12/4/2019 MW-1 MW-1D MW-2 MW-3R MW-4 Could not locate well - No sample collected MW-5 Page 4 of 7 Well ID Date Benzene (μg/L)Toluene (μg/L)Ethylbenzene (μg/L)Total Xylenes (μg/L) Methy Tert-Butyl Ether (μg/L) Di-Isopropyl Ether(μg/L)Naphthalene (μg/L)Lead (μg/L)Ethanol (μg/L)Tert-Amyl Alcohol (μg/L) Tert-Amylmethyl Ether (μg/L) Tert-Butyl Alcohol (μg/L)Tert-Butyl Formate (μg/L)Ethyl Tert-Butyl Ether (μg/L) 1 600 600 500 20 70 6 15 NSE 40 128 10 40 47 5,000 260,000 84,500 85,500 20,000 25,000 6,000 15,000 NSE 40,000 12,800 10,000 40,000 47,000 6/5/2008 <1 8.4 5 38.9 <1 <1 N/A 448 N/A N/A N/A N/A N/A N/A 6/24/2009 <1 <1 <1 <2 <1 <1 N/A 47.5 N/A N/A N/A N/A N/A N/A 9/10/2009 <1 <1 <1 <2 <1 <1 N/A 187 N/A N/A N/A N/A N/A N/A 12/16/2009 <1 <1 <1 <2 <1 <1 N/A 74.3 N/A N/A N/A N/A N/A N/A 6/23/2010 <1 <1 <1 <3 <1 <1 N/A 304 N/A N/A N/A N/A N/A N/A 12/20/2010 <1 <5 <1 <3 <1 <1 N/A 200 N/A N/A N/A N/A N/A N/A 6/21/2011 <1 <5 <1 <3 <1 <1 N/A 940 N/A N/A N/A N/A N/A N/A 12/12/2011 <1 <5 <1 <3 <1 <1 N/A 240 N/A N/A N/A N/A N/A N/A 6/28/2012 <1 <5 <1 <3 <1 <1 N/A 110 N/A N/A N/A N/A N/A N/A 12/19/2012 <1 <5 <1 <3 <1 <1 N/A 6.5 N/A N/A N/A N/A N/A N/A 6/25/2013 <1 <5 <1 <3 <1 <1 N/A 430 N/A N/A N/A N/A N/A N/A 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A 42.1 N/A N/A N/A N/A N/A N/A 1/26/2016 < 0.119 U < 0.0570 U < 0.0920 U < 0.122 U < 0.169 U < 0.0920 U N/A NA N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 < 0.17 < 0.13 < 0.39 < 0.090 < 0.18 N/A 37 N/A N/A N/A N/A N/A N/A 12/6/2018 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 N/A 59.6 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <2.0 81.3 <200 <100 <10.0 <20.0 <20.0 <10.0 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A < 3.30 U N/A N/A N/A N/A N/A N/A 6/22/2016 < 0.119 U < 0.0570 U < 0.0920 U <0.180 U < 0.169 U < 0.0920 U N/A <3.30 U N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 0.45 J < 0.13 < 0.39 < 0.090 < 0.18 N/A < 4.4 N/A N/A N/A N/A N/A N/A 12/6/2018 <0.12 <0.5 <0.13 <1.5 <0.090 <0.18 N/A <4.4 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 0.40 J <1.0 <3.0 <1.0 <1.0 <2.0 <5.0 <200 <100 <10.0 <20.0 <20.0 <10.0 6/22/2016 < 0.119 U < 0.0570 U < 0.0920 U <0.180 U < 0.169 U < 0.0920 U N/A <3.30 U N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 < 0.17 < 0.13 < 0.39 < 0.090 < 0.18 N/A < 4.4 N/A N/A N/A N/A N/A N/A 12/6/2018 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 N/A <4.4 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <2.0 <5.0 <200 <100 <10.0 <20.0 <20.0 <10.0 12/8/2014 < 0.0204 U < 0.268 U < 0.0221 U < 0.149 U < 1.22 U NA N/A < 3.30 U N/A N/A N/A N/A N/A N/A 1/26/2016 < 0.119 U < 0.0570 U < 0.0920 U < 0.122 U < 0.169 U < 0.0980 U N/A NA N/A N/A N/A N/A N/A N/A 10/19/2017 < 0.12 < 0.17 < 0.13 < 0.39 < 0.090 < 0.18 N/A < 4.4 N/A N/A N/A N/A N/A N/A 12/6/2018 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 N/A <4.4 N/A N/A N/A N/A N/A N/A 12/4/2019 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <2.0 <5.0 <200 <100 <10.0 <20.0 <20.0 <10.0 NotesBold/Highlighted - Concentration exceeds applicable groundwater quality standard2L Standard - North Carolina Administrative Code 2L Groundwater Quality StandardGCL - Gross Contamination Levels for Groundwater (NCDEQ Guidelines for Assessment and Corrective Action for UST Releases) < - Denotes analytical result below laboratory method detection limit ug/L - Micrograms per liter J - Indicates estimated concentration between laboratory report limit and method detection limit U - Concentration is below laboratory method detection limit WSW-4 MW-6 WSW-1 WSW-3 Page 5 of 7 Well #Well Owner Owner Address Well Use Connected to Public Water? Well Depth (ft BGS) Type of Well Well Casing Depth (ft BGS) Well Screen Interval (ft BGS)source area of 1 Norwood Family Limited Partnership 55 Paupers Ridge Road, Banner Elk, NC 28605 Potable No NA NA NA NA 250 East 2 Norwood Family Limited Partnership 55 Paupers Ridge Road, Banner Elk, NC 28605 Potable No 105 Drilled NA NA 400 Northeast 3 Bettie Norwood Potable No NA NA NA NA 420 northwest 4 Sugar View Real Estate Investors, LLC PO Box 2496, Banner Elk, NC 28609 Potable No NA Drilled NA NA 250 Southeast 5 Cari Ashbaugh Potable No NA Drilled NA NA 560 East 6 Harry Dean Gwyn 84 Arnett Road Banner Elk, NC 28605 Potable No NA NA NA NA 440 Southeast 7 Frank Ruppard Potable No NA NA NA NA 780 East 8 Serenity Day Spa 72 Arnett Road Banner Elk, NC 28605 Potable No NA Drilled NA NA 950 East 9 Lena Owens 34 Cynthia Lane Banner Elk, NC 28605 Potable No NA NA NA NA 650 Northeast 10 Buster Ruppard Potable No NA NA NA NA 900 Northeast 11 Gary Elimelech Potable No NA NA NA NA 950 Northeast 12 Mack Ruppard PO Box 2496, Banner Elk, NC 28605 Potable No NA NA NA NA 700 Southeast 13 Lawrence Hendricks 9024 Boyd Drive Matthews, NC 28 I05 Potable No NA NA NA NA 825 Northeast 14 Davis Hickok PO Box 517, Banner Elk, NC 28604 Potable No NA NA NA NA 1,050 Northeast 15 Floyd Townsend 84 Cynthia Lane, Banner Elk, NC 28604 Potable No NA NA NA NA 1,050 Northeast TABLE 5 ADDITIONAL WATER SUPPLY WELL INFORMATION GPM 3089 (Former Scotchman #89) 3045 Tynecastle Highway, Banner Elk, NC Incident No. 28327 Well #Well Owner Owner Address Well Use Connected to Public Water? Well Depth (ft BGS) Type of Well Well Casing Depth (ft BGS) Well Screen Interval (ft BGS)source area of 16 M. Scott Zoellner PO Box 66, Jensen Beach, FL 34598 Potable No NA NA NA NA 550 Northwest 17 Charles Eggers PO Box 699, Banner Elk, NC 28604 Potable No NA NA NA NA 1,200 Northeast 18 Betty Jo Gwyn 84 Arnett Road Banner Elk, NC 28604 Potable No NA NA NA NA 1,100 Northeast 19 Carroll Roney PO Box 341, Banner Elk, NC 28604 Potable No NA NA NA NA 1,200 Northeast 20 Zbigniew Ryniak Potable No NA NA NA NA 1,200 North 21 Village of Sugar Mountain PO Box 1135, Banner Elk, NC 28604 Irrigation No NA NA NA NA 1,450 Southwest 22 Carolina Water Service of NC 259 Dell Road, Banner Elk, NC 28604 Potable No NA NA NA NA 785 Northwest 23 Banner Elk Church of Christ PO Box 1719, Banner Elk, NC 28604 Unknown Yes NA NA NA NA 600 Southwest 24 William H. Cannon PO Box 369, Banner Elk, NC 28604 Unknown No NA NA NA NA 600 South 25 Paul and Edna Townsend Unknown No NA NA NA NA I, 150 Southwest 26 Alpine Recreation, Inc.Potable No NA NA NA NA 950 South 27 William H. Cannon PO Box 369, Banner Elk, NC 28604 Unknown No NA NA NA NA 800 South 28 William H. Cannon PO Box 369, Banner Elk, NC 28604 Unknown No NA NA NA NA 950 South 29 William H. Cannon PO Box 369, Banner Elk, NC 28604 Unknown No NA NA NA NA 1,100 South 30 Gonzalo Sanabria Potable No NA NA NA NA 1,350 Northeast 31 Larry Padgett Potable No NA NA NA NA 700 Southeast GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT APPENDIX A RECENT CORRESPONDENCE GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT APPENDIX B GROUNDWATER SAMPLING LOGS Scanned with CamScanner Scanned with CamScanner Scanned with CamScanner Scanned with CamScanner Scanned with CamScanner GROUNDWATER MONITORING REPORT GPM 3089-D (FORMER SCOTCHMAN #89) BANNER ELK, NORTH CAROLINA INCIDENT # 28327 GPM 3089 (SCOTCHMAN #89): GROUNDWATER MONITORING REPORT APPENDIX C LABORATORY REPORT(S) AND CHAIN OF CUSTODY DOCUMENTATION #=CL# January 08, 2020 LIMS USE: FR - AARON WILLIAMSON LIMS OBJECT ID: 92456248 92456248 Project: Pace Project No.: RE: Aaron Williamson Crawford Environmental 5104 Reagan Dr Suite 7 Charlotte, NC 28206 GPM 3089 Dear Aaron Williamson: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 24 #=CP# CERTIFICATIONS Pace Project No.: Project: 92456248 GPM 3089 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 24 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92456248 GPM 3089 Lab ID Sample ID Matrix Date Collected Date Received 92456248001 MW-1 Water 12/04/19 10:45 12/05/19 13:07 92456248002 MW-2 Water 12/04/19 11:45 12/05/19 13:07 92456248003 MW-3R Water 12/04/19 10:20 12/05/19 13:07 92456248004 MW-5 Water 12/04/19 11:15 12/05/19 13:07 92456248005 MW-6 Water 12/04/19 10:05 12/05/19 13:07 92456248006 WSW-1 Water 12/04/19 14:40 12/05/19 13:07 92456248007 WSW-3 Water 12/04/19 15:00 12/05/19 13:07 92456248008 WSW-4 Water 12/04/19 13:15 12/05/19 13:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 24 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92456248 GPM 3089 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92456248001 MW-1 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248002 MW-2 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248003 MW-3R EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248004 MW-5 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248005 MW-6 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248006 WSW-1 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248007 WSW-3 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL 92456248008 WSW-4 EPA 6010D 1 PASI-AKQ SM 6200B 11 PASI-CCL SM 6200B 9 PASI-CCL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:MW-1 Lab ID:92456248001 Collected:12/04/19 10:45 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead 286 ug/L 12/11/19 03:19 7439-92-112/07/19 01:4825.0 8.0 5 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/16/19 13:39 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/16/19 13:39 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/16/19 13:39 100-41-41.0 0.24 1 Methyl-tert-butyl ether 10.4 ug/L 12/16/19 13:39 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/16/19 13:39 91-20-32.0 0.66 1 Toluene ND ug/L 12/16/19 13:39 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/16/19 13:39 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/16/19 13:39 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)97 %12/16/19 13:39 460-00-470-130 1 1,2-Dichloroethane-d4 (S)95 %12/16/19 13:39 17060-07-070-130 1 Toluene-d8 (S)102 %12/16/19 13:39 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/16/19 13:39 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/16/19 13:39 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/16/19 13:39 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/16/19 13:39 762-75-420.0 17.8 1 Ethanol ND ug/L 12/16/19 13:39 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/16/19 13:39 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)95 %12/16/19 13:39 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %12/16/19 13:39 460-00-470-130 1 Toluene-d8 (S)102 %12/16/19 13:39 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:MW-2 Lab ID:92456248002 Collected:12/04/19 11:45 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead 25.7 ug/L 12/10/19 23:20 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/16/19 13:57 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/16/19 13:57 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/16/19 13:57 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/16/19 13:57 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/16/19 13:57 91-20-32.0 0.66 1 Toluene ND ug/L 12/16/19 13:57 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/16/19 13:57 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/16/19 13:57 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)97 %12/16/19 13:57 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %12/16/19 13:57 17060-07-070-130 1 Toluene-d8 (S)103 %12/16/19 13:57 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/16/19 13:57 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/16/19 13:57 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/16/19 13:57 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/16/19 13:57 762-75-420.0 17.8 1 Ethanol ND ug/L 12/16/19 13:57 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/16/19 13:57 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)93 %12/16/19 13:57 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %12/16/19 13:57 460-00-470-130 1 Toluene-d8 (S)103 %12/16/19 13:57 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:MW-3R Lab ID:92456248003 Collected:12/04/19 10:20 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead 29.6 ug/L 12/10/19 23:38 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene 13.1 ug/L 12/16/19 14:15 71-43-21.0 0.24 1 Diisopropyl ether 4.9 ug/L 12/16/19 14:15 108-20-31.0 0.33 1 Ethylbenzene 18.6 ug/L 12/16/19 14:15 100-41-41.0 0.24 1 Methyl-tert-butyl ether 25.6 ug/L 12/16/19 14:15 1634-04-41.0 0.44 1 Naphthalene 2.2 ug/L 12/16/19 14:15 91-20-32.0 0.66 1 Toluene ND ug/L 12/16/19 14:15 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/16/19 14:15 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/16/19 14:15 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)98 %12/16/19 14:15 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %12/16/19 14:15 17060-07-070-130 1 Toluene-d8 (S)103 %12/16/19 14:15 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/16/19 14:15 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/16/19 14:15 994-05-810.0 3.0 1 tert-Butyl Alcohol 53.1 ug/L 12/16/19 14:15 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/16/19 14:15 762-75-420.0 17.8 1 Ethanol ND ug/L 12/16/19 14:15 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/16/19 14:15 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)100 %12/16/19 14:15 17060-07-070-130 1 4-Bromofluorobenzene (S)98 %12/16/19 14:15 460-00-470-130 1 Toluene-d8 (S)103 %12/16/19 14:15 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:MW-5 Lab ID:92456248004 Collected:12/04/19 11:15 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead ND ug/L 12/10/19 23:42 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/16/19 14:33 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/16/19 14:33 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/16/19 14:33 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/16/19 14:33 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/16/19 14:33 91-20-32.0 0.66 1 Toluene ND ug/L 12/16/19 14:33 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/16/19 14:33 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/16/19 14:33 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)97 %12/16/19 14:33 460-00-470-130 1 1,2-Dichloroethane-d4 (S)96 %12/16/19 14:33 17060-07-070-130 1 Toluene-d8 (S)103 %12/16/19 14:33 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/16/19 14:33 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/16/19 14:33 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/16/19 14:33 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/16/19 14:33 762-75-420.0 17.8 1 Ethanol ND ug/L 12/16/19 14:33 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/16/19 14:33 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)96 %12/16/19 14:33 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %12/16/19 14:33 460-00-470-130 1 Toluene-d8 (S)103 %12/16/19 14:33 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:MW-6 Lab ID:92456248005 Collected:12/04/19 10:05 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead 81.3 ug/L 12/10/19 23:45 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/16/19 14:51 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/16/19 14:51 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/16/19 14:51 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/16/19 14:51 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/16/19 14:51 91-20-32.0 0.66 1 Toluene ND ug/L 12/16/19 14:51 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/16/19 14:51 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/16/19 14:51 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)99 %12/16/19 14:51 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %12/16/19 14:51 17060-07-070-130 1 Toluene-d8 (S)103 %12/16/19 14:51 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/16/19 14:51 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/16/19 14:51 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/16/19 14:51 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/16/19 14:51 762-75-420.0 17.8 1 Ethanol ND ug/L 12/16/19 14:51 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/16/19 14:51 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)99 %12/16/19 14:51 17060-07-070-130 1 4-Bromofluorobenzene (S)99 %12/16/19 14:51 460-00-470-130 1 Toluene-d8 (S)103 %12/16/19 14:51 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:WSW-1 Lab ID:92456248006 Collected:12/04/19 14:40 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead ND ug/L 12/10/19 23:48 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/13/19 17:29 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/13/19 17:29 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/13/19 17:29 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/13/19 17:29 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/13/19 17:29 91-20-32.0 0.66 1 Toluene 0.40J ug/L 12/13/19 17:29 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/13/19 17:29 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/13/19 17:29 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)97 %12/13/19 17:29 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %12/13/19 17:29 17060-07-070-130 1 Toluene-d8 (S)102 %12/13/19 17:29 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/13/19 17:29 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/13/19 17:29 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/13/19 17:29 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/13/19 17:29 762-75-420.0 17.8 1 Ethanol ND ug/L 12/13/19 17:29 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/13/19 17:29 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)93 %12/13/19 17:29 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %12/13/19 17:29 460-00-470-130 1 Toluene-d8 (S)102 %12/13/19 17:29 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:WSW-3 Lab ID:92456248007 Collected:12/04/19 15:00 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead ND ug/L 12/10/19 23:51 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/13/19 17:47 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/13/19 17:47 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/13/19 17:47 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/13/19 17:47 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/13/19 17:47 91-20-32.0 0.66 1 Toluene ND ug/L 12/13/19 17:47 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/13/19 17:47 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/13/19 17:47 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)98 %12/13/19 17:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)93 %12/13/19 17:47 17060-07-070-130 1 Toluene-d8 (S)102 %12/13/19 17:47 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/13/19 17:47 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/13/19 17:47 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/13/19 17:47 75-65-020.0 17.6 1 tert-Butyl Formate ND ug/L 12/13/19 17:47 762-75-420.0 17.8 1 Ethanol ND ug/L 12/13/19 17:47 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/13/19 17:47 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)93 %12/13/19 17:47 17060-07-070-130 1 4-Bromofluorobenzene (S)98 %12/13/19 17:47 460-00-470-130 1 Toluene-d8 (S)102 %12/13/19 17:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 24 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92456248 GPM 3089 Sample:WSW-4 Lab ID:92456248008 Collected:12/04/19 13:15 Received:12/05/19 13:07 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP Lead ND ug/L 12/10/19 23:54 7439-92-112/10/19 02:115.0 1.6 1 Analytical Method: SM 6200B602 Volatiles by Method 6200 Benzene ND ug/L 12/13/19 18:05 71-43-21.0 0.24 1 Diisopropyl ether ND ug/L 12/13/19 18:05 108-20-31.0 0.33 1 Ethylbenzene ND ug/L 12/13/19 18:05 100-41-41.0 0.24 1 Methyl-tert-butyl ether ND ug/L 12/13/19 18:05 1634-04-41.0 0.44 1 Naphthalene ND ug/L 12/13/19 18:05 91-20-32.0 0.66 1 Toluene ND ug/L 12/13/19 18:05 108-88-31.0 0.23 1 m&p-Xylene ND ug/L 12/13/19 18:05 179601-23-12.0 0.44 1 o-Xylene ND ug/L 12/13/19 18:05 95-47-61.0 0.24 1 Surrogates 4-Bromofluorobenzene (S)97 %12/13/19 18:05 460-00-470-130 1 1,2-Dichloroethane-d4 (S)89 %12/13/19 18:05 17060-07-070-130 1 Toluene-d8 (S)104 %12/13/19 18:05 2037-26-570-130 1 Analytical Method: SM 6200B6200B MSV tert-Amyl Alcohol ND ug/L 12/13/19 18:05 75-85-410040.5 1 tert-Amylmethyl ether ND ug/L 12/13/19 18:05 994-05-810.0 3.0 1 tert-Butyl Alcohol ND ug/L 12/13/19 18:05 75-65-0 M120.0 17.6 1 tert-Butyl Formate ND ug/L 12/13/19 18:05 762-75-4 M120.0 17.8 1 Ethanol ND ug/L 12/13/19 18:05 64-17-520098.9 1 Ethyl-tert-butyl ether ND ug/L 12/13/19 18:05 637-92-310.0 3.8 1 Surrogates 1,2-Dichloroethane-d4 (S)89 %12/13/19 18:05 17060-07-070-130 1 4-Bromofluorobenzene (S)97 %12/13/19 18:05 460-00-470-130 1 Toluene-d8 (S)104 %12/13/19 18:05 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 513514 EPA 3010A EPA 6010D 6010 MET Associated Lab Samples:92456248001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2752982 Associated Lab Samples:92456248001 Matrix:Water AnalyzedMDL Lead ug/L ND 5.0 12/10/19 02:151.6 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2752983LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 472500 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2752984MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456139003 2752985 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 500 95 75-12595 0 205001.6J 478 478 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 513826 EPA 3010A EPA 6010D 6010 MET Associated Lab Samples:92456248002, 92456248003, 92456248004, 92456248005, 92456248006, 92456248007, 92456248008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2754305 Associated Lab Samples:92456248002, 92456248003, 92456248004, 92456248005, 92456248006, 92456248007, 92456248008 Matrix:Water AnalyzedMDL Lead ug/L ND 5.0 12/10/19 23:131.6 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2754306LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 483500 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2754307MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456248002 2754308 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 500 93 75-12591 2 2050025.7 490 482 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 514737 SM 6200B SM 6200B 602 by 6200B Associated Lab Samples:92456248006, 92456248007, 92456248008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2758777 Associated Lab Samples:92456248006, 92456248007, 92456248008 Matrix:Water AnalyzedMDL Benzene ug/L ND 1.0 12/13/19 17:110.24 Diisopropyl ether ug/L ND 1.0 12/13/19 17:110.33 Ethylbenzene ug/L ND 1.0 12/13/19 17:110.24 m&p-Xylene ug/L ND 2.0 12/13/19 17:110.44 Methyl-tert-butyl ether ug/L ND 1.0 12/13/19 17:110.44 Naphthalene ug/L ND 2.0 12/13/19 17:110.66 o-Xylene ug/L ND 1.0 12/13/19 17:110.24 Toluene ug/L ND 1.0 12/13/19 17:110.23 1,2-Dichloroethane-d4 (S)%92 70-130 12/13/19 17:11 4-Bromofluorobenzene (S)%97 70-130 12/13/19 17:11 Toluene-d8 (S)%104 70-130 12/13/19 17:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2758778LABORATORY CONTROL SAMPLE: LCSSpike Benzene ug/L 52.150 104 60-140 Diisopropyl ether ug/L 48.150 96 60-140 Ethylbenzene ug/L 50.850 102 60-140 m&p-Xylene ug/L 104100 104 60-140 Methyl-tert-butyl ether ug/L 49.950 100 60-140 Naphthalene ug/L 56.650 113 60-140 o-Xylene ug/L 51.650 103 60-140 Toluene ug/L 51.250 102 60-140 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2758779MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456248008 2758780 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Benzene ug/L 20 109 60-14095 14 3020ND21.8 18.9 Diisopropyl ether ug/L 20 95 60-14083 13 3020ND18.9 16.6 Ethylbenzene ug/L 20 107 60-14091 16 3020ND21.4 18.3 m&p-Xylene ug/L 40 108 60-14093 15 3040ND43.2 37.3 Methyl-tert-butyl ether ug/L 20 100 60-14087 14 3020ND20.0 17.3 Naphthalene ug/L 20 111 60-14093 17 3020ND22.1 18.7 o-Xylene ug/L 20 108 60-14092 16 3020ND21.5 18.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2758779MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456248008 2758780 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Toluene ug/L 20 108 60-14093 15 3020ND21.6 18.6 1,2-Dichloroethane-d4 (S)%92 70-13096 4-Bromofluorobenzene (S)%99 70-130100 Toluene-d8 (S)%100 70-130100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 515013 SM 6200B SM 6200B 602 by 6200B Associated Lab Samples:92456248001, 92456248002, 92456248003, 92456248004, 92456248005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2760056 Associated Lab Samples:92456248001, 92456248002, 92456248003, 92456248004, 92456248005 Matrix:Water AnalyzedMDL Benzene ug/L ND 1.0 12/16/19 11:520.24 Diisopropyl ether ug/L ND 1.0 12/16/19 11:520.33 Ethylbenzene ug/L ND 1.0 12/16/19 11:520.24 m&p-Xylene ug/L ND 2.0 12/16/19 11:520.44 Methyl-tert-butyl ether ug/L ND 1.0 12/16/19 11:520.44 Naphthalene ug/L ND 2.0 12/16/19 11:520.66 o-Xylene ug/L ND 1.0 12/16/19 11:520.24 Toluene ug/L ND 1.0 12/16/19 11:520.23 1,2-Dichloroethane-d4 (S)%96 70-130 12/16/19 11:52 4-Bromofluorobenzene (S)%98 70-130 12/16/19 11:52 Toluene-d8 (S)%104 70-130 12/16/19 11:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2760057LABORATORY CONTROL SAMPLE: LCSSpike Benzene ug/L 50.250 100 60-140 Diisopropyl ether ug/L 49.150 98 60-140 Ethylbenzene ug/L 49.450 99 60-140 m&p-Xylene ug/L 101100 101 60-140 Methyl-tert-butyl ether ug/L 52.750 105 60-140 Naphthalene ug/L 55.450 111 60-140 o-Xylene ug/L 50.150 100 60-140 Toluene ug/L 47.950 96 60-140 1,2-Dichloroethane-d4 (S)%97 70-130 4-Bromofluorobenzene (S)%99 70-130 Toluene-d8 (S)%98 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2760058MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456132004 2760059 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Benzene ug/L 500 127 60-140107 3 30500271033503250 Diisopropyl ether ug/L 500 103 60-140100 3 30500141656639 Ethylbenzene ug/L 500 117 60-140113 2 30500311896878 m&p-Xylene ug/L 1000 117 60-140112 4 30100051.2 1220 1170 Methyl-tert-butyl ether ug/L 500 118 60-140107 7 30500262851795 Naphthalene ug/L 500 132 60-140118 6 3050053011901120 o-Xylene ug/L 500 117 60-140112 4 30500ND584561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2760058MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456132004 2760059 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Toluene ug/L 500 115 60-140109 5 305007.0J 580 551 1,2-Dichloroethane-d4 (S)%95 70-13098 4-Bromofluorobenzene (S)%99 70-13099 Toluene-d8 (S)%99 70-130100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 24 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92456248 GPM 3089 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 518306 SM 6200B SM 6200B 6200B MSV Associated Lab Samples:92456248001, 92456248002, 92456248003, 92456248004, 92456248005, 92456248006, 92456248007, 92456248008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2774527 Associated Lab Samples:92456248001, 92456248002, 92456248003, 92456248004, 92456248005, 92456248006, 92456248007, 92456248008 Matrix:Water AnalyzedMDL Ethanol ug/L ND 200 12/13/19 17:1198.9 Ethyl-tert-butyl ether ug/L ND 10.0 12/13/19 17:113.8 tert-Amyl Alcohol ug/L ND 100 12/13/19 17:1140.5 tert-Amylmethyl ether ug/L ND 10.0 12/13/19 17:113.0 tert-Butyl Alcohol ug/L ND 20.0 12/13/19 17:1117.6 tert-Butyl Formate ug/L ND 20.0 12/13/19 17:1117.8 1,2-Dichloroethane-d4 (S)%92 70-130 12/13/19 17:11 4-Bromofluorobenzene (S)%97 70-130 12/13/19 17:11 Toluene-d8 (S)%104 70-130 12/13/19 17:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2774528LABORATORY CONTROL SAMPLE: LCSSpike Ethanol ug/L 18002000 90 60-140 Ethyl-tert-butyl ether ug/L 89.7100 90 60-140 tert-Amyl Alcohol ug/L 9641000 96 60-140 tert-Amylmethyl ether ug/L 95.2100 95 60-140 tert-Butyl Alcohol ug/L 466500 93 60-140 tert-Butyl Formate ug/L 468400 117 60-140 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2774529MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92456248008 2774530 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Ethanol ug/L 800 87 60-14067 26 30800ND695536 Ethyl-tert-butyl ether ug/L 40 91 60-14079 15 3040ND36.4 31.5 tert-Amyl Alcohol ug/L 400 98 60-14086 12 30400ND391346 tert-Amylmethyl ether ug/L 40 99 60-14083 17 3040ND39.6 33.4 tert-Butyl Alcohol ug/L M120015360-140134 13 30200ND307268 tert-Butyl Formate ug/L M1160060-1400 30160NDNDND 1,2-Dichloroethane-d4 (S)%92 70-13096 4-Bromofluorobenzene (S)%99 70-130100 Toluene-d8 (S)%100 70-130100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 24 #=QL# QUALIFIERS Pace Project No.: Project: 92456248 GPM 3089 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 24 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92456248 GPM 3089 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92456248001 513514 513537MW-1 EPA 3010A EPA 6010D 92456248002 513826 513837MW-2 EPA 3010A EPA 6010D 92456248003 513826 513837MW-3R EPA 3010A EPA 6010D 92456248004 513826 513837MW-5 EPA 3010A EPA 6010D 92456248005 513826 513837MW-6 EPA 3010A EPA 6010D 92456248006 513826 513837WSW-1 EPA 3010A EPA 6010D 92456248007 513826 513837WSW-3 EPA 3010A EPA 6010D 92456248008 513826 513837WSW-4 EPA 3010A EPA 6010D 92456248001 515013MW-1 SM 6200B 92456248002 515013MW-2 SM 6200B 92456248003 515013MW-3R SM 6200B 92456248004 515013MW-5 SM 6200B 92456248005 515013MW-6 SM 6200B 92456248006 514737WSW-1 SM 6200B 92456248007 514737WSW-3 SM 6200B 92456248008 514737WSW-4 SM 6200B 92456248001 518306MW-1 SM 6200B 92456248002 518306MW-2 SM 6200B 92456248003 518306MW-3R SM 6200B 92456248004 518306MW-5 SM 6200B 92456248005 518306MW-6 SM 6200B 92456248006 518306WSW-1 SM 6200B 92456248007 518306WSW-3 SM 6200B 92456248008 518306WSW-4 SM 6200B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/08/2020 12:00 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 24 Page 22 of 24 Page 23 of 24 Page 24 of 24