AS-3030_28254_CA_MRP_20231030

Via Email

October 30, 2023

NC Department of Environmental Quality
Division of Waste Management - Underground Storage Tanks
2090 U.S. 70 Highway
Swannanoa, NC 28778

Attention: Ms. Katie Bernal, PG

Re: Groundwater Monitoring Report
NC DOT- Robbinsville Maintenance Facility
40 State Shed Road
Robbinsville, North Carolina
DEQ Incident No. 28254
H&H Job No. DOT-476

Dear Katie,

On behalf of the NC DOT, please find the attached Groundwater Monitoring Report for the NC
DOT Maintenance Facility located at 40 State Shed Road in Robbinsville, Graham County,
North Carolina. If you have any questions, please do not hesitate to contact us.

Sincerely,

Hart & Hickman, PC
David Graham, PG Matt Bramblett, PE
Senior Project Geologist Principal

Attachment

Cc: Mr. Jeff Walston, NC DOT (via email)
Ms. Jennifer Parish, NC DOT (via email)
#C-1269 Engineering
#-245 Geology

Groundwater Monitoring Report

NC DOT Maintenance Facility
Robbinsville, North Carolina

NC DEQ Incident Number: 28254
H&H Job No. DOT-476
October 30, 2023

Assessment Report Information

Site Location:

NC DOT Maintenance Facility
40 State Shed Road
Robbinsville, North Carolina 28771

Property Owner:

North Carolina Department of Transportation
4809 Beryl Road
Raleigh, North Carolina 27606

Attn: Mr. Jeff Walston, PE
[phone]

Consultant Information:

Hart & Hickman, PC
2923 South Tryon Street, Suite 100
Charlotte, North Carolina 28203

Attn: Mr. David Graham, PG - Senior Project Geologist
[phone]

General Site Information:

NC DEQ Incident Number: 28254
Facility ID Number: 0-024661
NC DEQ Risk Classification: Intermediate
Latitude/Longitude: 35o 19’13” / 83o 48’ 05” (Approximate)
Release Discovery Date(s): August 26, 2004
Estimated Quantity of Release: Approximately 1,000 gallons
Cause/Source of Release: One 5,700-gallon gasoline UST and one 5,700-gallon diesel UST

i

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
Groundwater Monitoring Report
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476

Table of Contents

Section Page No.
1.0 Introduction ............................................................................................................................ 1 
2.0 Site History ............................................................................................................................. 2 
3.0 Receptor Survey Information ............................................................................................... 6 
4.0 Geology and Hydrogeology ................................................................................................... 7 
4.1 Regional Geology and Hydrogeology ...................................................................................7 
4.2 Site Geology and Hydrogeology ...........................................................................................8 
5.0 Groundwater Monitoring ...................................................................................................... 9 
5.1 Monitoring Wells and Water Levels .....................................................................................9 
5.2 Sample Collection Procedures and Analyses ........................................................................9 
5.3 Groundwater Sampling and Results ......................................................................................9 
6.0 Surface Water Sampling ..................................................................................................... 11 
6.1 Sample Collection Procedures and Analyses ......................................................................11 
6.2 Surface Water Analytical Results ........................................................................................11 
7.0 Summary and Certification ................................................................................................ 12 

List of Tables

Table 1 Summary of Adjacent Property Owner and Water Supply Well Information
Table 2 Summary of Monitoring Well Construction Data and Water Level Elevations
Table 3 Summary of Groundwater Analytical Results
Table 4 Natural Attenuation Parameters - September 2023
Table 5 Summary of Surface Water Analytical Results

ii

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
List of Figures

Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Receptor Survey Map
Figure 4 Shallow Groundwater Potentiometric Map
Figure 5 Groundwater Sample Locations and Analytical Data
Figure 6 Surface Water Sample Locations and Analytical Data

List of Appendices

Appendix A Laboratory Analytical Data Sheets
Appendix B Groundwater Sampling Forms

1

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
Groundwater Monitoring Report
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476

1.0 Introduction

This monitoring report documents groundwater and surface water sampling performed by Hart &
Hickman, PC (H&H) at the North Carolina Department of Transportation (NC DOT)
maintenance facility located at 40 State Shed Road in Robbinsville, Graham County, North
Carolina. Due to failing cathodic protection monitoring tests, a 5,700-gallon gasoline
underground storage tank (UST) and a 5,700-gallon diesel UST were removed from the site by
NC DOT on August 31, 2004. During excavation activities, the diesel product line leading to the
dispenser island was broken and approximately 1,000 gallons of diesel fuel were released in the
UST basin area. Approximately 3,900 gallons of fuel and water were then pumped from the
UST basin. A site location map is provided as Figure 1, and a site map is included as Figure 2.

Due to the presence of a surface water body (Tulula Creek) within 500 ft of the site and
previously detected concentrations of petroleum constituents in groundwater that exceeded 10
times the 15A NCAC 2B Water Quality Standards for Surface Waters (2B Standards), the North
Carolina Department of Environmental Quality (NC DEQ) risk classification for this incident is
Intermediate (95D). The DEQ incident number is #28254.

The environmental assessment work described in this report was conducted for NC DOT and
included the following tasks:
 Locating and gauging monitoring wells
 Sampling monitoring wells MW-1 through MW-5 and DW-1
 Sampling of Tulula Creek (Upstream, Edge of Bank, and Downstream)
 Data Evaluation and Reporting
2

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
2.0 Site History

Due to failing cathodic protection monitoring tests, a 5,700-gallon gasoline UST and a 5,700-
gallon diesel UST were removed from the site by NC DOT on August 31, 2004. During
excavation activities on August 26, 2004, the diesel product line leading to the dispenser island
was broken and approximately 1,000 gallons of diesel fuel were released. Approximately 3,900
gallons of fuel and water were then pumped from the UST basin using two 4-inch diameter basin
wells.

Nine soil samples (SS-1 through SS-9) were collected by NC DOT from the excavation
sidewalls, adjacent to the dispenser line, and under the dispensers after UST removal activities
on August 31, 2004. Due to the presence of shallow groundwater, soil samples were collected at
depths ranging from 2.5 feet (ft) to 4 ft below ground surface (bgs). Bedrock was encountered in
the former UST basin at a depth of approximately 12 ft bgs. Petroleum-related constituents
were detected in UST closure soil samples above Soil to Water and/or Residential Maximum
Soil Contaminant Concentrations (MSCCs). Petroleum-related constituents were also reported
in a groundwater sample collected from the UST basin.

Based on the results of UST closure activities, Limited Site Assessment (LSA) sampling
activities were conducted at the site by H&H in 2005. Five Type II monitoring wells (MW-1
through MW-5) and one Type III monitoring well (DW-1) were installed during LSA activities.
Concentrations of petroleum constituents above the NC DEQ 15A NCAC 2L.0202 Groundwater
Quality Standards (2L Standards) were detected in the monitoring wells. As noted above,
concentrations of petroleum constituents detected in groundwater samples collected at the site
also exceeded 10 times the 2B Standards.

In a NC DEQ Notice of Regulatory Requirements (NORR) letter dated January 19, 2021 and a
follow up email request dated June 30, 2022, NC DEQ requested a comprehensive groundwater
sampling event and an updated receptor survey be conducted to evaluate current risks associated
with the site. No assessment activities had been conducted at the site since completion of the
LSA in 2005. Per NC DEQ’s request, H&H conducted an updated receptor survey and
comprehensive groundwater sampling event in September 2022. Concentrations of benzene and
3

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
naphthalene were detected above NC 2L standards in MW-1 but did not exceed 10 times the 2B
Surface Water standards. No other volatile organic compounds (VOCs) or semi-VOCs (SVOCs)
were detected above the 2L Standards or 10 times Surface Water standards in groundwater
samples collected from monitoring wells at the site. Groundwater concentrations have decreased
significantly in monitoring wells MW-1 through MW-4 and DW-1 since the 2005 sampling
event. Results of the September 2022 sampling event are documented in H&H’s Groundwater
Monitoring Report dated December 19, 2022.

Although target concentrations were low in September 2022, only two groundwater sampling
events had been conducted at the site. Based on the groundwater sampling results, H&H
recommended one additional sampling event be completed at the site in March 2023. NC DEQ
agreed with H&H’s recommendations in an Acknowledgement of Report Receipt letter dated
January 10, 2023. Depending on the March 2023 sampling results (above 2L Standards and
below 10 times Surface Water standards), DEQ indicated that the Robbinsville Maintenance
facility Incident may be eligible for risk-based closure by filing a Notice of Residual Petroleum
(NRP) on the deed for the property. A groundwater use restriction would be required on the
NRP. NC DEQ also indicated a residential land use restriction would be required on the NRP
because soil impacts previously exceeded the Residential MSCCs. To achieve unrestricted
closure for the site (no NRP for land use and/or groundwater), groundwater impacts would need
to be below the 2L Standards and soil impacts would need to be less than Residential MSCCs.

Based on conversations between H&H and NC DOT, a groundwater use restriction is acceptable
if a NRP is required for Incident closure. However, H&H understands that NC DOT would like
to close out the site without a residential land use restriction on the NRP, if possible. Based on
discussions between H&H and Ms. Katie Bernal, NC DEQ Incident Manager for the NC DOT
Robbinsville Maintenance facility, additional soil sampling activities would be required to
achieve incident closure without a residential land use restriction on the NRP. H&H reviewed
the soil analytical data in the 2005 LSA which indicated the presence of Massachusetts
Department of Environmental Protection (MADEP) volatile petroleum hydrocarbons (VPH) and
extractable petroleum hydrocarbons (EPH) and/or naphthalene above the Residential MSCCs at
previous soil sample locations SS-8 (3.5 ft) and SS-9 (3.5 ft). The unrestricted use standard for
4

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
soil is the Residential MSCCs. Based on the above historical soil results, H&H conducted soil
sampling activities in March 2023 to evaluate if soil impacts near SS-8 and SS-9 remain above
Residential screening levels.

Concentrations of target petroleum constituents were detected in the soil samples collected
adjacent to former sample locations SS-8 and SS-9 in March 2023. Concentrations of total C9-
C22 Aromatics and naphthalene were detected above the Residential MSCCs in soil sample SS-
9. Concentrations of other target petroleum constituents were also detected in SS-8 and SS-9
above the Soil-to-Water MSCCs.

Analytical results of groundwater samples collected from monitoring wells in March 2023
indicated concentrations of benzene, naphthalene, and MADEP EPH and VPH in MW-1 above
the 2L Standards. Low-level concentrations of other petroleum-related VOCs and/or SVOCs
were also detected in MW-1, MW-2, MW-3, and MW-4 below 2L Standards. Concentrations of
VOCs and SVOCs remained relatively stable between the September 2022 and March 2023
sampling events. However, a concentration of 1-methylnaphthalene was detected in MW-1
above 10 times surface water criteria.

The concentration of 1-methylnaphthalene was detected in MW-1, which is located upgradient
and approximately 230 ft away from Tulula Creek. No concentrations of 1-methylnapthalene
were detected in monitoring wells MW-3 and MW-4 located downgradient of MW-1 and
approximately 60 to 70 ft upgradient of the stream in March 2023. Although the site may qualify
as high risk, H&H requested that NC DEQ consider Incident closure because water supply wells
are approximately 900 ft away and Tulula Creek is approximately 200 to 250 ft away from
groundwater impacts above standards. H&H recommended completing an NRP for incident
closure in accordance with NC DEQ guidelines. Because soil concentrations are above
Residential MSCCs, a residential land use restriction would be required on the NRP to obtain a
No Further Action (NFA) requested letter. The NRP would consist of language specifying
perpetual land use restrictions that restrict both residential use and groundwater use at the site.

In NC DEQ NORR letter dated June 13, 2023, NC DEQ requested a comprehensive groundwater
5

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
sampling event be conducted in September 2023. In addition to the groundwater sampling, NC
DEQ requested that surface water samples be collected from Tulula Creek to evaluate the
potential for surface water impacts due to the concentration of 1-methylnaphthalene above 10
times surface water criteria in MW-1. The September 2023 groundwater and surface water
sampling activities are described below.

6

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
3.0 Receptor Survey Information

No water supply wells were identified within a 1,500 ft radius of the site during LSA activities in
2005. Municipal water is supplied to occupied properties within the site area including the
subject property. H&H identified one surface water body (Tulula Creek) located adjacent to the
site, approximately 200 ft west of the former dispenser area and 250 ft west of the former UST
basin area. Tulula Creek is classified as a Water Supply Class III (WS-III) and Trout Water (Tr).

On September 8, 2022, H&H conducted an updated receptor survey for surrounding properties
within 1,500 ft of the source area at the site. Prior to conducting the survey, H&H contacted the
Town of Robbinsville water department to verify water usage in the area. H&H confirmed that
municipal water is available to properties within a 1,500 ft radius of the site.

As part of the receptor survey update, H&H performed driving and walking reconnaissance of
the site area to observe for evidence of water supply wells. H&H also distributed approximately
18 NC DEQ Request for Water Supply Well Information forms to property owners within a 500
ft radius of the release area via hand delivery and/or via US Mail. During the receptor survey,
H&H spoke with a neighbor of the property owner at 209 Old Tallulah Road located
approximately 900 ft southeast of the site. The neighbor indicated a water supply well may be
located on the 209 Old Tallulah Road property. H&H hand delivered the Request for Water
Supply Well Information form to the 209 Old Tallulah Road address. The form was returned to
H&H and indicated that two water supply wells (WS-1 and WS-2) were installed approximately
five years ago and provide water to three residences at 209 and 240 Old Tallulah Road. The
wells are also used for livestock. H&H did not observe the water supply wells during the
receptor survey and was not able to contact the owner to confirm the well locations. As such, the
well locations are estimated at the two property addresses noted above (see Figure 3).

Six NC DEQ Request for Water Supply Well Information forms were returned to H&H and did
not indicate the presence of water supply wells. Other than WS-1 and WS-2, water supply wells
were not identified during the receptor survey update. Adjacent property owners and water
supply wells owner in the area are included in Table 1.
7

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
4.0 Geology and Hydrogeology

4.1 Regional Geology and Hydrogeology

According to the North Carolina Geological Survey 1985 Geologic Map of North Carolina, the
site area is located in the Blue Ridge Belt of the Blue Ridge Physiographic Province of North
Carolina. According to the geologic map, the basement rocks in the site area are composed of
metasandstone, metagraywacke, metasiltstone, and mica schist.

In the Blue Ridge, bedrock is overlain by a mantle of weathered rock or saprolite. The saprolite
consists of unconsolidated clay, silt, and sand with lesser amounts of rock fragments. Due to the
range of parent rock types and their variable susceptibility to weathering, the saprolite ranges
widely in color, texture, and thickness. Generally, the saprolite is thickest near interstream
divides and thins toward stream beds. In profile, the saprolite normally grades from clayey soils
near the land surface to highly weathered rock above competent bedrock.

The occurrence and movement of groundwater in the Blue Ridge is within two separate but
interconnected water-bearing zones. A shallow water-bearing zone occurs within the saprolite,
and a deeper water-bearing zone occurs within the underlying bedrock.

Groundwater in the shallow saprolite zone occurs in the interstitial pore spaces between the
grains comprising the saprolite soils. Groundwater in this zone is typically under water table or
unconfined conditions. Groundwater movement is generally lateral from recharge areas to small
streams which serve as localized discharge points.

The occurrence and movement of groundwater in underlying bedrock is controlled by secondary
joints, fractures, and faults within the bedrock. On a regional scale, the direction of groundwater
flow is typically from uplands to major streams and groundwater sinks. The saprolite has a
higher porosity than the bedrock and serves as a reservoir which supplies water to a network of
fractures in the bedrock.

8

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
4.2 Site Geology and Hydrogeology

Based on field observations during LSA activities by H&H in 2005, the site is generally
composed of surficial fill and alluvial soils consisting of tan-brown to brownish red sandy silts
and silty clays. Metasandstone bedrock was encountered below the soils at approximately 11 to
13 ft bgs. An alluvial layer of well-rounded pebbles and cobbles with abundant groundwater is
present just above bedrock. The pebbles and cobbles are assumed to be present from previous
meanders of Tulula Creek. Larger mica schist boulders were also encountered above the
bedrock. The boulders were encountered at depths ranging from three to eight ft below ground
surface.

H&H installed five shallow monitoring wells (MW-1 through MW-5) and one deeper monitoring
well (DW-1) at the site during LSA activities in January 2005. After installation, the top of
casing elevations of the monitoring wells were referenced to a common, but arbitrary, datum
using surveying techniques. These same wells were gauged and sampled in September 2023.
The depth to groundwater at the site is approximately 5 ft bgs. H&H prepared a potentiometric
map based on groundwater elevations referencing an arbitrary datum. Based on the
potentiometric map, the shallow groundwater flow direction is generally to the west towards
Tulula Creek (Figure 4).

9

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc

5.0 Groundwater Monitoring

5.1 Monitoring Wells and Water Levels

Six monitoring wells (MW-1 through MW-5 and DW-1) were sampled on September 18 and 19,
2023. The monitoring wells appeared to be in good condition. Monitoring well construction
information is provided in Table 2.

An electronic water level indicator was used to record the static water levels in the six existing
monitoring wells. The depths to water in shallow monitoring wells ranged from 5.10 ft (MW-5)
to 5.74 ft (MW-1) below the monitoring well top of casings. The estimated potentiometric
surface from September 2023 is depicted on Figure 4. As shown on Figure 4, the potentiometric
surface slopes to the west towards Tulula Creek.

5.2 Sample Collection Procedures and Analyses

Laboratory supplied sample containers were used for sample collection. A chain-of-custody
record was completed for samples collected and included sample description, date collected, time
collected, matrix, sample container information, and analyses required. The sample containers
were placed in a cooler with ice and submitted to Waypoint Analytical (Waypoint) for laboratory
analysis of VOCs by Standard Method for the Examination of Water and Wastewater 6200B and
SVOCs by EPA Method 625 (base/neutral and acid extractables) Laboratory analytical data
sheets are provided in Appendix A, and analytical results are summarized in Table 3.

5.3 Groundwater Sampling and Results

After monitoring wells were gauged for depth to water, the wells were sampled using low-flow
sampling techniques with a peristaltic pump. During well purging, measurements of pH,
conductivity, temperature, dissolved oxygen (DO), oxidation reduction potential (ORP), and
turbidity were collected. The wells were purged until field parameters stabilized, and turbidity
levels were below 10 Nephelometric Turbidity Units (NTUs), if possible. Upon stabilization, a
groundwater sample was collected for laboratory analysis. Field parameter data are provided in
10

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
Table 4. Groundwater sampling forms are included in Appendix B.

Based on laboratory analytical results, concentrations of benzene (5.07 ug/L), naphthalene (9.69
ug/L), and 1-methylnaphthalene (7.53 ug/L) were detected in MW-1 above the 2L Standards of
1.0 ug/L, 6.0 ug/L and 1.0 ug/L, respectively. Low-level concentrations of other petroleum-
related VOCs and SVOCs were also detected in MW-1 and MW-4 below the 2L Standards.

The groundwater concentrations noted above were also compared to the 2B Standards. The
nearest groundwater discharge is to Tulula Creek which is classified as a Water Supply Class III
(WS-III) and a Trout Water (Tr) surface water. Based on the classification of the receiving water
body downgradient of the site, concentrations detected in groundwater were compared to the
lower criteria applicable for WS III/Tr or Class C (All Water) surface water. Per NC Division of
Water Resources (DWR) guidance (NC DWR Surface Water Quality Standards, Criteria & In-
Stream Target Values table, July 2021), if no 2B Standards exist for certain compounds,
concentrations were also compared to the lower of the EPA National Recommended Water
Quality Criteria or NC In-Stream Target Values. Based on this comparison, no compounds were
detected at a concentration 10 times the surface water criteria during the most recent sampling
event.

Concentrations of VOCs and/or SVOCs have significantly decreased in monitoring wells MW-1
through MW-4 and DW-1 since the 2005 sampling event. For example, benzene decreased from
320 µg/L in 2005 to 5.07 µg/L in 2023 in MW-1. VOCs and/or SVOCs previously detected in
wells MW-2 through MW-4 and DW-1 were not detected or were detected at concentrations
below their respective 2L Standards. The absence of impacts has remained consistent in
upgradient monitoring well MW-5 over time. Historical groundwater monitoring data are
provided in Table 3. Key contaminant concentrations in groundwater are depicted on Figure 5.
11

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc

6.0 Surface Water Sampling

6.1 Sample Collection Procedures and Analyses

H&H collected three surface water samples from Tulula Creek located to the west and
downgradient of the site. At NC DEQ’s request, the surface water samples were collected at one
upstream location (Upstream), one edge of bank location (Edge of Bank) and one downstream
location (Downstream). The Edge of Bank sample was between the Upstream and Downstream
sample locations. NC DEQ also requested that samples be collected near seeps flowing from the
site if identified in Tulula Creek. No potential flowing seeps were identified by H&H during the
surface water sampling activities. Surface water sample locations are shown on Figure 6.

Surface water samples were collected using a decontaminated stainless-steel scoop in a manner
to avoid re-suspension of bottom deposits. At each location, surface water quality parameters
including temperature, pH, conductivity, DO, ORP, and turbidity were measured. Geochemical
field parameters are included in Table 4.

Surface water samples were placed directly into dedicated laboratory-supplied sample bottles,
labeled, and placed on ice in an insulated cooler. A chain-of-custody record was completed and
included sample description, analyses required, matrix, sample container information, and date
and time of sample collection. The sample containers were submitted to Waypoint for laboratory
analysis of VOCs and SVOCs. The laboratory analytical report and chain-of-custody record are
provided in Appendix A, and analytical results are summarized in Table 5.

6.2 Surface Water Analytical Results

Based on laboratory analytical results, no VOCs or SVOCs were detected above the laboratory
method detection limits in the surface water samples collected from Tulula Creek.

12

https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW
Report/Report/AS_3030_28254_MRP_20231030_Monitoring Report.doc
7.0 Summary and Certification

Groundwater and surface water sampling activities were conducted at the NC DOT Maintenance
Facility in Robbinsville, North Carolina in September 2023. The findings are summarized
below.

 Analytical results of groundwater samples collected from monitoring wells at the site
indicate concentrations of benzene, naphthalene, and 1-methylnapthalene above 2L
Standards in MW-1. Low-level concentrations of other petroleum-related VOCs and/or
SVOCs were also detected in MW-1 and MW-4 below the 2L Standards. Concentrations
of VOCs and SVOCs have significantly decreased in monitoring wells MW-1 through
MW-4 and DW-1 since the 2005 sampling event and have remained relatively stable or
decreased since the September 2022 sampling event. No groundwater concentrations
exceed 10 times surface water criteria.

 No VOCS or SVOCs were detected in the three surface water samples collected from
Tulula Creek located to the west and downgradient of the site.

H&H recommends one additional semi-annual sampling event for monitoring wells at the site in
March 2024. Incident closure should be considered if target petroleum constituents are below 10
times surface water criteria in monitoring wells at the site for two consecutive monitoring events.

If DEQ is willing to close the incident, H&H recommends completing the NRP for incident
closure in accordance with NC DEQ guidelines. Because soil concentrations have been detected
above Residential MSCCs, a residential land use restriction will be required on the NRP to
obtain a No Further Action (NFA) requested letter. The NRP will consist of language specifying
perpetual land use restrictions that restrict both residential use and groundwater use at the site.

Table 1 (Page 1 of 1)
Summary of Adjacent Property Owner and Water Supply Well Information
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Depth Use
568100EX0004 Site 40 State Shed Road NC Dept of Transportation 1275 Old Sweetwater Rd
Robbinsville, NC 28771 NA NA NA NA NA NA NA
568100000004PT A 92 Five Point Road Southeast Bulk, LLC 7014 A.C. Skinner Parkway
Jacksonville, FL 32256 Northeast NA NA NA NA NA NA
NA B State Shed Road NC Dept of Transportation 1275 Old Sweetwater Rd
Robbinsville, NC 28771 East NA NA NA NA NA NA
5588000014600T C 88 State Shed Road Adams Contracting P.O. Box 1157
Robbinsville, NC 28771 South NA NA NA NA NA NA
56601620000201 D 77 Tallulah Road Colvard Family Trust 420 Snug Harbor Dr
Meritt Island Fl, 32953 Southwest NA NA NA NA NA NA
5660162000021/
559800005290 E Tallulah Road/32 Five Point Rd Tony Cody & William Adams P.O. Box 218
Robbinsville, NC 28771 West/Northwest NA NA NA NA NA NA
566016200001 F HWY 129 Five Point Rd Adams Contracting Co.P.O. Box 1157
Robbinsville, NC 28771 North NA NA NA NA NA NA
557900030010/
557900030006*NA 209/240 Old Tallulah Road Richard & Nancy Brooks 209 Old Tallulah Rd
Robbinsville, NC 28771 Southeast WS-1/WS-2 340 ft Drinking/
Livestock Yes
Supplies water to three
residences
at 209 and 240 Old Tallulah Rd
900 ft
Notes:
* = The property owner provided information that indicated WS-1 and WS-2 supplies water to three residences located at 209 and 240 Old Tallulah Road.
The locations of WS-1 and WS-2 are unknown and are esitmated on 209 and 240 Tallulah Road, respectively (Figure 3).
NA = not applicable
Confirmed Well Usage
(September 2022)
Additional Well
Information
Approximate Distance
of Well From Source Area of
Release (ft)
Well Details
Parcel ID No.
Map No.
(Adjacent
Parcel)
Property Address Owner Owner Mailing Address Direction From Site Water Supply
Well ID
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW Report/Tables/GW Tables
10/24/2023
Table 1 (Page 1 of 1)
Hart & Hickman, PC
Table 2 (Page 1 of 1)
Summary of Monitoring Well Construction Data and Water Level Elevations
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Well ID Sampling Date Top of Casing Elevation
(ft)
Depth To Water
(ft below TOC)
Groundwater Elevation
(ft)
Well Casing Diameter
(inches)
Screen Interval
(ft bgs)
Depth of Well
(ft bgs)
1/20/2005 5.27 93.70
9/6/2022 5.21 93.76
3/20/2023 4.60 94.37
9/18/2023 5.74 93.23
1/20/2005 4.62 94.01
9/6/2022 4.71 93.92
3/20/2023 4.07 94.56
9/18/2023 5.18 93.45
1/20/2005 5.07 93.34
9/6/2022 5.29 93.12
3/20/2023 4.85 93.56
9/18/2023 5.68 92.73
1/20/2005 4.57 93.07
9/6/2022 4.70 92.94
3/20/2023 4.39 93.25
9/18/2023 5.22 92.42
1/20/2005 4.37 95.43
9/6/2022 4.53 95.27
3/20/2023 3.45 96.35
9/18/2023 5.10 94.70
1/20/2005 5.25 94.02
9/6/2022 5.31 93.96
3/20/2023 4.65 94.62
9/18/2023 5.91 93.36
Notes:
Top of casing (TOC) elevations referenced from an arbitrary benchmark of 100 ft.
Wells installed by H&H on January 18 and 19, 2005.
ft bgs = feet below ground surface
* DW-1 is a Type III monitoring well with surface casing to 28 ft.
MW-5
DW-1*
MW-1 98.97
MW-2
MW-3
MW-4
98.63
98.41
97.64
99.80
99.27 50
2-12
2-12
2-12
2-12
2-12
40-50
12
12
12
12
12
2
2
2
2
2
2
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW Report/Tables/GW Tables
10/24/2023
Table 2 (Page 1 of 1)
Hart & Hickman, PC
Table 3 (Page 1 of 1)
Summary of Groundwater Analytical Results
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Ac
e
t
o
n
e
Be
n
z
e
n
e
n-B
u
t
y
l
b
e
n
z
e
n
e
se
c
-
B
u
t
y
l
b
e
n
z
e
n
e
Et
h
y
l
b
e
n
z
e
n
e
Is
o
p
r
o
p
y
l
b
e
n
z
e
n
e

(C
u
m
e
n
e
)
Is
o
p
r
o
p
y
l

E
t
h
e
r

(
I
P
E
)
Me
t
h
y
l

t
e
r
t
-
b
u
t
y
l

e
t
h
e
r

(M
T
B
E
)
4-M
e
t
h
y
l
-
2
-
P
e
n
t
a
n
o
n
e
Me
t
h
y
l
e
n
e

C
h
l
o
r
i
d
e
Na
p
h
t
h
a
l
e
n
e
n-P
r
o
p
y
l
b
e
n
z
e
n
e
To
l
u
e
n
e
Tr
i
c
h
l
o
r
o
e
t
h
y
l
e
n
e
1,2
,
4
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
1,3
,
5
-
T
r
i
m
e
t
h
y
l
b
e
n
z
e
n
e
To
t
a
l

X
y
l
e
n
e
s
Ac
e
n
a
p
h
t
h
e
n
e
Be
n
z
o
i
c

A
c
i
d
Bis
(
2
-
e
t
h
y
l
h
e
x
y
l
)
p
h
t
h
a
l
a
t
e
Bu
t
y
l
b
e
n
z
y
l
p
h
t
h
a
l
a
t
e
Dib
e
n
z
o
f
u
r
a
n
Die
t
h
y
l

p
h
t
h
a
l
a
t
e
Flu
o
r
e
n
e
1-M
e
t
h
y
l
n
a
p
h
t
h
a
l
e
n
e
2-M
e
t
h
y
l
n
a
p
h
t
h
a
l
e
n
e
Na
p
h
t
h
a
l
e
n
e
Ph
e
n
a
n
t
h
r
e
n
e
VP
H

C
5
-
C
8

A
l
i
p
h
a
t
i
c
s
VP
H

C
9
-
C
1
2

A
l
i
p
h
a
t
i
c
s
EP
H

C
9
-
C
1
8

A
l
i
p
h
a
t
i
c
s
To
t
a
l

C
9
-
C
1
8

A
l
i
p
h
a
t
i
c
s
EP
H

C
1
9
-
C
3
6

A
l
i
p
h
a
t
i
c
s
VP
H

C
9
-
C
1
0

A
r
o
m
a
t
i
c
s
EP
H

C
1
1
-
C
2
2

A
r
o
m
a
t
i
c
s
To
t
a
l

C
9
-
C
2
2

A
r
o
m
a
t
i
c
s
1/20/2005 NA 320 34 8.4 150 27 32 690 NA <20 100 91 300 <5.0 79 22 370 <1.8 NA <9.7 <9.7 <2.1 <9.7 5.4 J NA <1.7 75 3.7 J 1,400 280 100 380 <31 1,300 1,000 2,300
9/7/2022 <1.80 11.7 7.18 7.74 1.95 12.5 2.52 <0.140 <0.078 <0.330 21.2 32.7 0.488 J <0.180 <0.190 <0.180 2.25 J <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <18.0 8.36 10.7 10.7 3.38 J 14.5 <5.00 <1.40 <0.780 <3.30 30.3 42.5 <2.20 <1.80 <1.90 <1.80 <2.1 1.39 J <1.11 <3.49 <1.84 1.30 J <0.749 3.68 16.1 9.94 12.7 2.70 758 512 70.5 J 582.5 J <124 229 728 957
9/19/2023 <1.80 5.07 4.66 6.74 0.607 8.75 0.730 <0.140 <0.078 0.568 J 9.69 21.4 0.338 J <0.180 <0.190 <0.180 1.31 J 0.887 J <1.10 <3.46 <1.83 <0.856 <0.745 2.06 7.53 2.27 3.27 1.81 J NA NA NA NA NA NA NA NA
1/20/2005 NA 25 4.4 1.3 5.0 4.4 1.9 32 NA <2.0 38 11 2.4 <0.5 0.58 <0.50 1.88 <1.8 NA <9.7 <9.7 <2.1 <9.7 3.3 J NA <1.7 34 3.0 J 83 J 110 510 620 <31 150 770 920
9/7/2022 1.82 J <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
9/7/2022 (Dup)<1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 NA <11.5 NA NA NA <9.35 NA NA NA NA NA NA NA NA NA NA NA NA NA
3/21/2023 <1.80 0.848 <0.180 0.325 J <0.170 0.988 <0.500 <0.140 <0.078 <0.330 <0.470 1.97 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <1.11 <3.49 <1.84 <0.861 <0.749 <0.811 <1.15 <0.669 <0.731 <0.430 <11.5 34.6 J <28.2 34.6 J <124 <4.02 61.2 J 61.2 J
9/19/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.453 <1.65 <5.19 <2.75 <1.28 4.26 J <1.21 <1.71 <0.999 <1.09 <0.642 NA NA NA NA NA NA NA NA
1/20/2005 NA 0.95 2.1 0.59 <0.5 <0.5 1.3 37 NA <2.0 <0.5 0.58 <0.5 <0.5 1.5 0.96 3.0 <1.8 NA <9.7 <9.7 <2.1 <9.7 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/7/2022 <1.80 <0.180 <0.180 0.456 J <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <1.80 <0.180 <0.180 1.21 <0.170 <0.180 1.10 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 0.562 J <1.11 <3.49 <1.84 <0.861 <0.749 0.921 J <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
9/18/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.302 <1.10 <3.46 <1.83 <0.856 3.54 J <0.807 <1.14 <0.666 <0.728 <0.428 NA NA NA NA NA NA NA NA
1/20/2005 NA 5.6 7.6 0.96 5.5 1.4 6.3 34 NA <2.0 8.9 5.4 3.0 <0.5 9.5 6.2 28.8 <3.7 NA 120 15 J <4.3 <19 <19 NA <3.5 17 J 4.9 J <75 <70 550 550 9,700 180 2,600 2,780
9/7/2022 1.90 J <0.180 <0.180 0.376 J <0.170 <0.180 0.614 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/20/2023 <1.80 <0.180 <0.180 0.428 J <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 0.602 J <1.11 <3.49 <1.84 <0.861 <0.749 <0.811 <1.15 <0.669 <0.731 <0.430 41.8 J 47.4 J 29.3 J 76.7 J <124 9.91 J 139 J 148.91 J
9/18/2023 <1.80 <0.180 <0.180 0.242 J <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 0.591 J 4.54 J <3.46 <1.83 <0.856 2.49 J <0.807 <1.14 <0.666 <0.728 <0.428 NA NA NA NA NA NA NA NA
1/20/2005 NA <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NA <2.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1.5 <1.8 NA <9.7 <9.7 <2.1 <9.7 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/6/2022 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/20/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <1.11 <3.49 <1.84 <0.861 <0.749 <0.811 <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
9/18/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.302 <1.10 <3.46 <1.83 <0.856 5.15 <0.807 <1.14 <0.666 <0.728 <0.428 NA NA NA NA NA NA NA NA
1/20/2005 NA <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NA <2.0 <0.5 <0.5 <0.5 1.9 <0.5 <0.5 <1.5 <1.8 NA <9.7 <9.7 <2.1 <9.7 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/7/2022 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 0.712 J <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <11.5 <8.80 <4.53 <5.08 <9.35 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <1.11 <3.49 <1.84 <0.861 <0.749 <0.811 <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
9/19/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.330 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.302 <1.10 <3.46 <1.83 <0.856 11.9 <0.807 <1.14 <0.666 <0.728 <0.428 NA NA NA NA NA NA NA NA
6,000 1 70 70 600 70 70 20 100 5 6 70 600 3 400 400 500 80 30,000 3 1,000 28 6,000 300 1 30 6 200 400 NS NS 700 10,000 NS NS 200
6,000,000 5,000 5,900 8,800 80,000 30,500 70,000 20,000 100,000 5,000 6,000 26,100 260,000 3,000 28,500 24,100 50,000 1,950 1,700,000 135 NS 1,550 NS 845 1,000 12,000 6,000 550 NS NS NS NS NS NS NS NS
20,000 11.9 39 NS 680 2,500 200,000 190 28,000 200 120 800 3.6 25 3,900 1,300 4,500 290 900,000 3.2 1 NS 6,000 300 8 850 120 3 1,250 1,800 1,800 1,800 2,100 NS NS NS
Notes:
1) North Carolina Department of Environmental Quality (NC DEQ) 15A NCAC 02L.0202 Groundwater Quality Standards (2L Standards) dated April 2022. Groundwater Interim Maximum Allowable Concentration (IMAC) (dated November 2022) used if 2L Standard not available.
2) NC DEQ Gross Contamination Levels (GCL) for Groundwater dated September 2022.
3) NC 15A NCAC 02B.0202 Surface Water Quality Standards (2B Standards) for Class WS III/Tr or Class C (All waters) surface waters dated July 2021. If no standard exists, the lower of EPA Recommended Water Quality Criteria for Aquatic Life & Human Health or NC In-Stream Target Values for Surface Water - Class WS III/Tr or Class C (All waters) (July 2021) was used.
The nearest discharge is to a Class WS III/Tr surface water body (Tulula Creek). Based on the classification of the receiving water body, surface water standards and criteria are based on Class WS III/Tr or Class C (All waters) surface water standards.
Bold indicates above 2L Standard.
Underline exceeds 10 X Surface Water Criteria.
Only those compounds detected in at least one sample shown above.
µg/L = micrograms per liter; Dup = duplicate
VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; NA = not analyzed; ND = not detected; NS = not specified
VPH = volatile petroleum hydrocarbons; EPH = extractable petroleum hydrocarbons; MADEP = Massachusetts Department of Environmental Protection
Laboratory analytical methods are shown in parentheses.
J = Estimated value between the laboratory reporting limit and the method detection limit.
MW-5
2L Standard (1)
10 X Surface Water Criteria (3)
GCL (2)
DW-1
VPH/EPH (MADEP)
µg/L
SVOCs (625.1)
µg/L
VOCs (6200B)
MW-3
MW-4
Sa
m
p
l
e

I
D
Sa
m
p
l
e

D
a
t
e
µg/L
MW-1
MW-2
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW Report/Tables/GW Tables
10/27/2023
Table 3 (Page 1 of 1)
Hart & Hickman, PC
Table 4 (Page 1 of 1)
Natural Attenuation Parameters - September 2023
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Sample ID pH
(SU)
Conductivity
(µS/cm)Temperature (ºC)ORP
(mV)
Dissolved Oxygen
(mg/L)
Turbidity
(NTU)
MW-1 6.60 527 25.3 -123.3 0.15 0.78
MW-2 5.76 221.1 22.2 108.4 1.16 0.97
MW-3 6.32 326.3 22.5 -79.2 0.13 1.34
MW-4 6.06 589.0 24.3 -68.2 0.15 0.50
MW-5 6.02 349.1 25.5 5.1 0.13 0.49
DW-1 7.51 205.4 21.5 -181.6 0.16 2.41
Upstream 7.17 32.1 16.7 -19.3 7.62 2.68
Edge of Bank 7.26 32.5 16.1 -18.4 7.42 2.33
Downstream 7.30 34.1 16.5 -43.2 8.91 4.12
Notes:
SU = Standard Units
µS/cm = microsiemens per centimeter
ºC = degrees Celsius
mg/L = milligrams per liter
ORP = oxidation-reduction potential
mV = millivolts
NTU = nephelometric turbidity units
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW Report/Tables/GW Tables
10/24/2023
Table 4 (Page 1 of 1)
Hart & Hickman, PC
Table 5 (Page 1 of 1)
Summary of Surface Water Analytical Results
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Surface Water
Sample ID Upstream Edge of Bank Downstream
Sample Date 9/19/2023 9/19/2023 9/19/2023
Units
VOCs (6200B)BDL BDL BDL -- --
SVOCs (625.1)BDL BDL BDL -- --
Notes:
1) North Carolina 15A NCAC 02B.0202 Surface Water Quality Standards (2B Standards) for Class WS III/Tr or Class C (All waters) surface waters dated July 2021.
2) Lower of EPA National Recommended Water Quality Criteria for Aquatic Life & Human Health or NC In-Stream Target Values for Surface Waters - Class WS III/Tr or Class C (All waters) (July 2021).
Laboratory analytical methods are shown in parentheses.
VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; -- = not applicable
BDL = All compounds are below laboratory detection limit.
µg/L
Tulula Creek (West of Site Property Boundary) Screening Criteria
NC 2B Standards (1)Water Quality Criteria (2)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 - 09 GW Report/Tables/GW Tables
10/27/2023
Table 5 (Page 1 of 1)
Hart & Hickman, PC
USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed April, 2023.
SITE LOCATION MAP
NC DOT MAINTENANCE FACILITY40 STATE SHED ROADROBBINSVILLE, NORTH CAROLINA
DATE: 10-16-23
JOB NO: DOT-476
REVISION NO: 0
FIGURE NO: 1
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
TITLE
PROJECT
0 2,000 4,000
SCALE IN FEET
SITE
Pa
t
h
:

S
:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
F
i
g
u
r
e
s
\
F
i
g
u
r
e

1
.
m
x
d
N
U.S.G.S. QUADRANGLE MAP
ROBBINSVILLE, NORTH CAROLINA 2022
QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC)
ST
A
T
E

S
H
E
D

R
O
A
D
FIVE POINTS ROA
D
OFFICE
FO
R
M
E
R

1
0
,
0
0
0

G
A
L

A
S
T
s
MAINTENAN
C
E
SHOP
TRUCK
STORAG
E
SHED
GRAVEL
PARKING
SOUTHEAST
ENERGY
(BULK FACILITY)
SW
E
E
T
G
U
M

R
D
.

(
O
L
D

T
A
L
L
U
L
A
H

R
D
.
)
VACANT/UNOCCUPIED
EQUIPME
N
T
STORAGE
NC DOT ADDITIONAL
STORAGE YARD
GRAVEL
STOCKPILE
GRAVEL
STOCKPILE
MW-4
MW-3
MW-1
DW-1
MW-5
FORMER LOCATION
OF LIQUID ASPHALT
AST
FORMER LIQUID
ASPHALT AST
OIL/WATER
SEPARATOR
WASH PAD
SALT
SPREADER
STORAGE
RACK
MW-2
TU
L
U
L
A

C
R
E
E
K
STORAGE UNITS
TA
L
L
U
L
A
H

R
O
A
D

(
H
W
Y

1
2
9
)
EQUIPMENT
STORAGE AREA
CANOPY
W-2
FORMER 5,700-GAL GASOLINE
UST AND 5,700-GAL DIESEL UST
BASIN
SALT
SPREADER
HANG RACK
FORMER
PRODUCT
PIPING
REVISION NO. 1
JOB NO. DOT-476
DATE: 10-16-23
FIGURE NO. 2
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SITE MAP
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
FORMER USED OIL UST
FORMER AST FUEL DISPENSERS
SHALLOW MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
2.UST = UNDERGROUND STORAGE TANK
AST = ABOVEGROUND STORAGE TANK
S:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
R
e
p
o
r
t
s
\
2
0
2
3

-

0
9

G
W

R
e
p
o
r
t
\
F
i
g
u
r
e
s
\
D
O
T
-
4
7
6
_
2
0
2
3
1
0
0
5
.
d
w
g
,

F
I
G

2
,

1
0
/
2
4
/
2
0
2
3

7
:
5
2
:
5
8

A
M
,

s
h
a
y
n
e
s
REVISION NO. 0
JOB NO. DOT-476
DATE: 10-16-23
FIGURE NO. 3
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
RECEPTOR SURVEY MAP
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
TULULA CREEK
PROPERTY IDENTIFICATION
WATER SUPPLY WELL LOCATION
GROUNDWATER FLOW DIRECTION
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
NOTES:
1.AERIAL IMAGERY OBTAINED FROM NCONEMAP, 2022.
2.BASE DATA OBTAINED FROM NCONEMAP, 2023.
SW
E
E
T
G
U
M

R
D
.

(
O
L
D

T
A
L
L
U
L
A
H

R
D
.
)
TA
L
L
U
L
A
H

R
D
.

(
H
W
Y

1
2
9
)
ST
A
T
E

S
H
E
D

R
D
.
FIVE P
O
I
N
T
S

R
D
.
W. FO
R
T

H
I
L
L

R
D
.
OL
D

M
O
T
H
E
R

C
H
U
R
C
H

R
D
.
E. M
A
I
N

S
T
.
FOR
D

S
T
.
500 FT RADIUS
1,500 FT RADIUS
WS-1
WS-2
S:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
R
e
p
o
r
t
s
\
2
0
2
3

-

0
9

G
W

R
e
p
o
r
t
\
F
i
g
u
r
e
s
\
D
O
T
-
4
7
6
_
2
0
2
3
1
0
1
6
.
d
w
g
,

F
I
G

3
,

1
0
/
1
6
/
2
0
2
3

2
:
2
5
:
4
5

P
M
,

d
r
a
b
u
r
n
ST
A
T
E

S
H
E
D

R
O
A
D
FIVE POINTS ROA
D
OFFICE
FO
R
M
E
R

1
0
,
0
0
0

G
A
L

A
S
T
s
MAINTENAN
C
E
SHOP
TRUCK
STORAG
E
SHED
GRAVEL
PARKING
SOUTHEAST
ENERGY
(BULK FACILITY)
SW
E
E
T
G
U
M

R
D
.

(
O
L
D

T
A
L
L
U
L
A
H

R
D
.
)
VACANT/UNOCCUPIED
EQUIPME
N
T
STORAGE
NC DOT ADDITIONAL
STORAGE YARD
GRAVEL
STOCKPILE
GRAVEL
STOCKPILE
MW-4
MW-3
MW-1
DW-1
MW-5
FORMER LOCATION
OF LIQUID ASPHALT
AST
FORMER LIQUID
ASPHALT AST
OIL/WATER
SEPARATOR
WASH PAD
SALT
SPREADER
STORAGE
RACK
MW-2
TU
L
U
L
A

C
R
E
E
K
STORAGE UNITS
TA
L
L
U
L
A
H

R
O
A
D

(
H
W
Y

1
2
9
)
EQUIPMENT
STORAGE AREA
CANOPY
W-2
FORMER 5,700-GAL GASOLINE
UST AND 5,700-GAL DIESEL UST
BASIN
SALT
SPREADER
HANG RACK
(94.70)
(92.73)
(93.45)
(93.23)
(92.42)
93 93
.
5
93
93
.
5
94
.
5
94
.
5
FORMER
PRODUCT
PIPING
92.
5
92
.
5
94
94
REVISION NO. 1
JOB NO. DOT-476
DATE: 10-16-23
FIGURE NO. 4
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SHALLOW GROUNDWATER
POTENTIOMETRIC MAP
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
2.ALL SITE WELLS GAUGED BY H&H ON SEPTEMBER 18, 2023.
3.UST = UNDERGROUND STORAGE TANK
AST = ABOVEGROUND STORAGE TANK
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
FORMER USED OIL UST
FORMER AST FUEL DISPENSER
SHALLOW MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
GROUNDWATER ELEVATION (FT)
ESTIMATED SHALLOW GROUNDWATER
CONTOUR LINE
ESTIMATED GROUNDWATER FLOW
DIRECTION
(93.23)
94
S:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
R
e
p
o
r
t
s
\
2
0
2
3

-

0
9

G
W

R
e
p
o
r
t
\
F
i
g
u
r
e
s
\
D
O
T
-
4
7
6
_
2
0
2
3
1
0
0
5
.
d
w
g
,

F
I
G

4
,

1
0
/
2
4
/
2
0
2
3

8
:
3
0
:
1
8

A
M
,

s
h
a
y
n
e
s
ST
A
T
E

S
H
E
D

R
O
A
D
FIVE POINTS ROA
D
OFFICE
FO
R
M
E
R

1
0
,
0
0
0

G
A
L

A
S
T
s
MAINTENAN
C
E
SHOP
TRUCK
STORAG
E
SHED
GRAVEL
PARKING
SOUTHEAST
ENERGY
(BULK FACILITY)
SW
E
E
T
G
U
M

R
D
.

(
O
L
D

T
A
L
L
U
L
A
H

R
D
.
)
VACANT/UNOCCUPIED
EQUIPME
N
T
STORAGE
NC DOT ADDITIONAL
STORAGE YARD
GRAVEL
STOCKPILE
GRAVEL
STOCKPILE
MW-4
MW-3
MW-1
DW-1
MW-5
FORMER LOCATION
OF LIQUID ASPHALT
AST
FORMER LIQUID
ASPHALT AST
OIL/WATER
SEPARATOR
WASH PAD
SALT
SPREADER
STORAGE
RACK
MW-2
TU
L
U
L
A

C
R
E
E
K
STORAGE UNITS
TA
L
L
U
L
A
H

R
O
A
D

(
H
W
Y

1
2
9
)
EQUIPMENT
STORAGE AREA
CANOPY
W-2
FORMER 5,700-GAL GASOLINE
UST AND 5,700-GAL DIESEL UST
BASIN
SALT
SPREADER
HANG RACK
FORMER
PRODUCT
PIPING
MW-3 1/20/2005 9/7/2022 3/21/2023 9/18/2023
MTBE 37 <0.140 <0.140 <0.140
REVISION NO. 1
JOB NO. DOT-476
DATE: 10-16-23
FIGURE NO. 5
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
GROUNDWATER SAMPLE LOCATIONS AND
ANALYTICAL DATA
NOTES:
1.ONLY CONSTITUENTS DETECTED ABOVE 2L STANDARDS OR 10X
THE SURFACE WATER CRITERIA ARE SHOWN. REFER TO TABLE 3
FOR ALL DETECTED CONSTITUENTS.
2.BOLD CONCENTRATIONS EXCEED THE NC 2L STANDARDS.
3.UNDERLINE EXCEEDS 10X THE SURFACE WATER CRITERIA.
4.MTBE = METHYL TERT-BUTYL ETHER
NA = NOT ANALYZED
BDL = ALL COMPOUNDS BELOW LABORATORY DETECTION LIMITS
ND = NO PETROLEUM COMPOUNDS DETECTED
UST = UNDERGROUND STORAGE TANK
AST = ABOVEGROUND STORAGE TANK
µg/L = MICROGRAMS PER LITER
5.J FLAG DENOTES ESTIMATED CONCENTRATION BETWEEN
LABORATORY REPORTING LIMIT AND METHOD DETECTION LIMIT.
6.SEE TABLE 3 FOR MASSACHUSETTS DEPARTMENT OF
ENVIRONMENTAL PROTECTION (MADEP), EXTRACTABLE
PETROLEUM HYDROCARBON (EPH), AND VOLATILE PETROLUEM
HYDROCARBON (VPH) ANALYTICAL DATA.
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
FORMER USED OIL UST
FORMER AST FUEL DISPENSER
SHALLOW MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
MW-1 1/20/2005 9/7/2022 3/21/2023 9/19/2023
BENZENE 320 11.7 8.36 5.07
MTBE 690 <0.140 <1.40 <0.140
NAPHTHALENE 100 21.2 30.3 9.69
n-PROPYLBENZENE 91 32.7 42.5 21.4
TOLUENE 300 0.488 J <2.20 0.338 J
1-METHYLNAPHTHALENE NA NA 16.1 7.53
PHENANTHRENE 3.7 J <6.34 2.70 1.81 J
MW-2 1/20/2005 9/7/2022 3/21/2023 9/19/2023
BENZENE 25 <0.180 0.848 <0.180
MTBE 32 <0.140 <0.140 <0.140
NAPHTHALENE 38 <0.470 <0.470 <0.470
MW-3 1/20/2005 9/7/2022 3/21/2023 9/18/2023
MTBE 37 <0.140 <0.140 <0.140
MW-4 1/20/2005 9/7/2022 3/20/2023 9/18/2023
BENZENE 5.6 <0.180 <0.180 <0.180
MTBE 34 <0.140 <0.140 <0.140
NAPHTHALENE 17 J <0.470 <0.470 <0.470
BIS(2-ETHYLHEXYL) PHTHALATE 120 <8.80 <3.49 <3.46
BUTYLBENZYLPHTHALATE 15 J <4.53 <1.84 <1.83
PHENANTHRENE 4.9 J <6.34 <0.430 <0.428
MW-5
1/20/2005 9/6/2022 3/20/2023 9/18/2023
BDL
CONSTITUENT
SAMPLE ID
CONCENTRATION
(µg/L)
SAMPLE DATE
DW-1
1/20/2005 9/7/2022 3/21/2023 9/19/2023
ND
S:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
R
e
p
o
r
t
s
\
2
0
2
3

-

0
9

G
W

R
e
p
o
r
t
\
F
i
g
u
r
e
s
\
D
O
T
-
4
7
6
_
2
0
2
3
1
0
0
5
.
d
w
g
,

F
I
G

5
,

1
0
/
2
4
/
2
0
2
3

4
:
0
7
:
1
5

P
M
,

s
h
a
y
n
e
s
ST
A
T
E

S
H
E
D

R
O
A
D
FIVE POINTS ROA
D
OFFICE
FO
R
M
E
R

1
0
,
0
0
0

G
A
L

A
S
T
s
MAINTENAN
C
E
SHOP
TRUCK
STORAG
E
SHED
GRAVEL
PARKING
SOUTHEAST
ENERGY
(BULK FACILITY)
SW
E
E
T
G
U
M

R
D
.

(
O
L
D

T
A
L
L
U
L
A
H

R
D
.
)
VACANT/UNOCCUPIED
EQUIPME
N
T
STORAGE
NC DOT ADDITIONAL
STORAGE YARD
GRAVEL
STOCKPILE
GRAVEL
STOCKPILE
MW-4
MW-3
MW-1
DW-1
MW-5
FORMER LOCATION
OF LIQUID ASPHALT
AST
FORMER LIQUID
ASPHALT AST
OIL/WATER
SEPARATOR
WASH PAD
SALT
SPREADER
STORAGE
RACK
MW-2
TU
L
U
L
A

C
R
E
E
K
STORAGE UNITS
TA
L
L
U
L
A
H

R
O
A
D

(
H
W
Y

1
2
9
)
EQUIPMENT
STORAGE AREA
CANOPY
W-2
FORMER 5,700-GAL GASOLINE
UST AND 5,700-GAL DIESEL UST
BASIN
SALT
SPREADER
HANG RACK
FORMER
PRODUCT
PIPING
DOWNSTREAM
9/19/2023
BDL
REVISION NO. 1
JOB NO. DOT-476
DATE: 10-16-23
FIGURE NO. 6
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SURFACE WATER SAMPLE LOCATIONS AND
ANALYTICAL DATA
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
2.BDL = BELOW LABORATORY DETECTION LIMITS
UST = UNDERGROUND STORAGE TANK
AST = ABOVE GROUND STORAGE TANK
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
FORMER USED OIL UST
FORMER AST FUEL DISPENSER
SHALLOW MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
SURFACE WATER SAMPLE LOCATION
SAMPLE ID
CONCENTRATION
(µg/L)
SAMPLE DATE
UPSTREAM
9/19/2023
BDL
EDGE OF BANK
9/19/2023
BDL
DOWNSTREAM
9/19/2023
BDL
S:
\
A
A
A
-
M
a
s
t
e
r

P
r
o
j
e
c
t
s
\
N
C

D
O
T

-
D
O
T
\
D
O
T
-
4
7
6

R
o
b
b
i
n
s
v
i
l
l
e
\
R
e
p
o
r
t
s
\
2
0
2
3

-

0
9

G
W

R
e
p
o
r
t
\
F
i
g
u
r
e
s
\
D
O
T
-
4
7
6
_
2
0
2
3
1
0
0
5
.
d
w
g
,

F
I
G

6
,

1
0
/
2
4
/
2
0
2
3

4
:
0
8
:
1
6

P
M
,

s
h
a
y
n
e
s

Appendix A

Laboratory Analytical Data Sheets

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

9/29/2023
Hart & Hickman (Charlotte) David Graham
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Lab Report Number: 23-263-0010 Client Project Description: DOT-476
Dear David Graham:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 9/20/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 102
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/23-263-0010
Page 2 of 102
Report Number:
Sample Summary Table
Client Project Description:
23-263-0010
DOT-476
Lab No Client Sample ID Matrix Date Collected Date Received
09/19/2023 11:25Aqueous 95675 MW-1 09/20/2023
09/19/2023 09:30Aqueous 95676 MW-2 09/20/2023
09/18/2023 16:20Aqueous 95677 MW-3 09/20/2023
09/18/2023 15:30Aqueous 95678 MW-4 09/20/2023
09/18/2023 14:15Aqueous 95679 MW-5 09/20/2023
09/19/2023 10:30Aqueous 95680 DW-1 09/20/2023
09/19/2023 12:45Aqueous 95681 UPSTREAM 09/20/2023
09/19/2023 12:25Aqueous 95682 Edge of Bank 09/20/2023
09/19/2023 12:05Aqueous 95683 Downstream 09/20/2023
Page 3 of 102
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-263-0010
Report Limit
Project:DOT-476
V 95675MW-1
5.07 09/27/2023 15:086200BBenzeneµg/L 0.180
4.66 09/27/2023 15:086200Bn-Butylbenzene µg/L 0.180
6.74 09/27/2023 15:086200Bsec-Butyl benzene µg/L 0.200
0.730 09/27/2023 15:086200BDi-Isopropyl Ether (DIPE)µg/L 0.500
0.607 09/27/2023 15:086200BEthylbenzeneµg/L 0.170
8.75 09/27/2023 15:086200BIsopropylbenzeneµg/L 0.180
J0.568 09/27/2023 15:086200BMethylene Chloride µg/L 0.330
9.69 09/27/2023 15:086200BNaphthaleneµg/L 0.470
21.4 09/27/2023 15:086200Bn-Propylbenzene µg/L 0.190
J0.338 09/27/2023 15:086200BTolueneµg/L 0.220
J0.225 09/27/2023 15:086200Bo-Xylene µg/L 0.210
1.08 09/27/2023 15:086200Bm,p-Xylene µg/L 0.420
J1.31 09/27/2023 15:086200BXylene (Total)µg/L 0.210
J0.887 09/26/2023 20:47625.1 Acenaphthene µg/L 0.302
2.06 09/26/2023 20:47625.1 Fluorene µg/L 0.807
7.53 09/26/2023 20:47625.1 1-Methylnaphthalene µg/L 1.14
2.27 09/26/2023 20:47625.1 2-Methylnaphthalene µg/L 0.666
3.27 09/26/2023 20:47625.1 Naphthalene µg/L 0.728
J1.81 09/26/2023 20:47625.1 Phenanthrene µg/L 0.428
V 95676MW-2
J4.26 09/25/2023 20:52625.1 Diethyl phthalate µg/L 1.12
V 95677MW-3
J3.54 09/25/2023 20:28625.1 Diethyl phthalate µg/L 0.745
V 95678MW-4
J0.242 09/26/2023 18:136200Bsec-Butyl benzene µg/L 0.200
J0.591 09/25/2023 20:05625.1 Acenaphthene µg/L 0.302
J4.54 09/25/2023 20:05625.1 Benzoic Acid µg/L 1.10
J2.49 09/25/2023 20:05625.1 Diethyl phthalate µg/L 0.745
V 95679MW-5
5.15 09/25/2023 19:42625.1 Diethyl phthalate µg/L 0.745
V 95680DW-1
11.9 09/26/2023 20:23625.1 Diethyl phthalate µg/L 0.745
Page 4 of 102

Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: DOT-476 Lab Report Number: 23-263-0010
Date: 9/28/2023
625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 QC Batch No: V38372/V38350 LCSD was surrogated twice. All surrogates fall within acceptance criteria.
Analyte: Benzidine
QC Batch No: V38300/V38350 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Analyte: Benzidine
QC Batch No: V38300/V38350 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzidine
QC Batch No: V38372/V38350 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzidine
QC Batch No: V38372/V38350 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V38378/V38455
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 1,2,3-Trichlorobenzene QC Batch No: V38416/V38455
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichlorobenzene QC Batch No: V38456/V38455
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,4-Trichlorobenzene QC Batch No: V38378/V38455
Page 5 of 102

Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 1,2,4-Trichlorobenzene
QC Batch No: V38416/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 1,2,4-Trichlorobenzene
QC Batch No: V38456/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 2,2-Dichloropropane
QC Batch No: V38416/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Carbon Tetrachloride QC Batch No: V38378/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Carbon Tetrachloride QC Batch No: V38416/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Carbon Tetrachloride
QC Batch No: V38456/V38455 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Chloromethane
QC Batch No: V38416/V38455 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Analyte: Chloromethane QC Batch No: V38456/V38455 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Analyte: Dichlorodifluoromethane
Page 6 of 102

QC Batch No: V38416/V38455
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Analyte: Dichlorodifluoromethane QC Batch No: V38456/V38455
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Analyte: Hexachlorobutadiene QC Batch No: V38416/V38455
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Hexachlorobutadiene QC Batch No: V38456/V38455
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Analyte: Vinyl acetate QC Batch No: V38378/V38455
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Vinyl chloride QC Batch No: V38416/V38455 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.

Page 7 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/27/23 15:08 V38456MSA
5.07 µg/L 0.180 0.500Benzene 1 09/27/23 15:08 V38456MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/27/23 15:08 V38456MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/27/23 15:08 V38456MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/27/23 15:08 V38456MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/27/23 15:08 V38456MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/27/23 15:08 V38456MSA
4.66 µg/L 0.180 0.500n-Butylbenzene 1 09/27/23 15:08 V38456MSA
6.74 µg/L 0.200 0.500sec-Butyl benzene 1 09/27/23 15:08 V38456MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/27/23 15:08 V38456MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/27/23 15:08 V38456MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/27/23 15:08 V38456MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/27/23 15:08 V38456MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/27/23 15:08 V38456MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/27/23 15:08 V38456MSA
<0.220 M µg/L 0.220 0.500Chloromethane 1 09/27/23 15:08 V38456MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/27/23 15:08 V38456MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/27/23 15:08 V38456MSA
0.730 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/27/23 15:08 V38456MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/27/23 15:08 V38456MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/27/23 15:08 V38456MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/27/23 15:08 V38456MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 8 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/27/23 15:08 V38456MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/27/23 15:08 V38456MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/27/23 15:08 V38456MSA
<1.20 M µg/L 1.20 5.00Dichlorodifluoromethane 1 09/27/23 15:08 V38456MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/27/23 15:08 V38456MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/27/23 15:08 V38456MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/27/23 15:08 V38456MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/27/23 15:08 V38456MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/27/23 15:08 V38456MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/27/23 15:08 V38456MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/27/23 15:08 V38456MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/27/23 15:08 V38456MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/27/23 15:08 V38456MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/27/23 15:08 V38456MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/27/23 15:08 V38456MSA
<42.0 µg/L 42.0 200Ethanol 1 09/27/23 15:08 V38456MSA
0.607 µg/L 0.170 0.500Ethylbenzene 1 09/27/23 15:08 V38456MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/27/23 15:08 V38456MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/27/23 15:08 V38456MSA
8.75 µg/L 0.180 0.500Isopropylbenzene 1 09/27/23 15:08 V38456MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/27/23 15:08 V38456MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/27/23 15:08 V38456MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 9 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/27/23 15:08 V38456MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/27/23 15:08 V38456MSA
0.568 J µg/L 0.330 2.00Methylene Chloride 1 09/27/23 15:08 V38456MSA
9.69 µg/L 0.470 1.00Naphthalene 1 09/27/23 15:08 V38456MSA
21.4 µg/L 0.190 0.500n-Propylbenzene 1 09/27/23 15:08 V38456MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/27/23 15:08 V38456MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/27/23 15:08 V38456MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/27/23 15:08 V38456MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/27/23 15:08 V38456MSA
0.338 J µg/L 0.220 0.500Toluene 1 09/27/23 15:08 V38456MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/27/23 15:08 V38456MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/27/23 15:08 V38456MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/27/23 15:08 V38456MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/27/23 15:08 V38456MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/27/23 15:08 V38456MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/27/23 15:08 V38456MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/27/23 15:08 V38456MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/27/23 15:08 V38456MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/27/23 15:08 V38456MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/27/23 15:08 V38456MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/27/23 15:08 V38456MSA
0.225 J µg/L 0.210 0.500o-Xylene 1 09/27/23 15:08 V38456MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38455 09/27/23 09:00
1.08 µg/L 0.420 1.00m,p-Xylene 1 09/27/23 15:08 V38456MSA
1.31 J µg/L 0.210 0.500Xylene (Total)1 09/27/23 15:08 V38456
Surrogate: 4-Bromofluorobenzene 91.2 Limits: 70-130%09/27/23 15:081 MSA V38456
Surrogate: Dibromofluoromethane 100 Limits: 70-130%09/27/23 15:081 MSA V38456
Surrogate: 1,2-Dichloroethane - d4 111 Limits: 70-130%09/27/23 15:081 MSA V38456
Surrogate: Toluene-d8 96.2 Limits: 70-130%09/27/23 15:081 MSA V38456
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
0.887 J µg/L 0.302 2.00Acenaphthene 1 09/26/23 20:47 V38372AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/26/23 20:47 V38372AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/26/23 20:47 V38372AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/26/23 20:47 V38372AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/26/23 20:47 V38372AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/26/23 20:47 V38372AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/26/23 20:47 V38372AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/26/23 20:47 V38372AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/26/23 20:47 V38372AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/26/23 20:47 V38372AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/26/23 20:47 V38372AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/26/23 20:47 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/26/23 20:47 V38372AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/26/23 20:47 V38372AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/26/23 20:47 V38372AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/26/23 20:47 V38372AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/26/23 20:47 V38372AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/26/23 20:47 V38372AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/26/23 20:47 V38372AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/26/23 20:47 V38372AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/26/23 20:47 V38372AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/26/23 20:47 V38372AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/26/23 20:47 V38372AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/26/23 20:47 V38372AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/26/23 20:47 V38372AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/26/23 20:47 V38372AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/26/23 20:47 V38372AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/26/23 20:47 V38372AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/26/23 20:47 V38372AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/26/23 20:47 V38372AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/26/23 20:47 V38372AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/26/23 20:47 V38372AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/26/23 20:47 V38372AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/26/23 20:47 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/26/23 20:47 V38372AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/26/23 20:47 V38372AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/26/23 20:47 V38372AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/26/23 20:47 V38372AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/26/23 20:47 V38372AMP
2.06 µg/L 0.807 2.00Fluorene 1 09/26/23 20:47 V38372AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/26/23 20:47 V38372AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/26/23 20:47 V38372AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/26/23 20:47 V38372AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/26/23 20:47 V38372AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/26/23 20:47 V38372AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/26/23 20:47 V38372AMP
7.53 µg/L 1.14 2.001-Methylnaphthalene 1 09/26/23 20:47 V38372AMP
2.27 µg/L 0.666 2.002-Methylnaphthalene 1 09/26/23 20:47 V38372AMP
3.27 µg/L 0.728 2.00Naphthalene 1 09/26/23 20:47 V38372AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/26/23 20:47 V38372AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/26/23 20:47 V38372AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/26/23 20:47 V38372AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/26/23 20:47 V38372AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/26/23 20:47 V38372AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/26/23 20:47 V38372AMP
1.81 J µg/L 0.428 2.00Phenanthrene 1 09/26/23 20:47 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-1
95675 Matrix:
9/19/2023 11:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.651 µg/L 0.651 5.00Phenol 1 09/26/23 20:47 V38372AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/26/23 20:47 V38372AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/26/23 20:47 V38372AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/26/23 20:47 V38372AMP
625.1Surrogate: Phenol-d5 25.0 Limits: 10-63%09/26/23 20:471 AMP
Surrogate: 2-Fluorobiphenyl 58.4 Limits: 49-118%09/26/23 20:471 AMP V38372
Surrogate: 2-Fluorophenol 37.6 Limits: 22-84%09/26/23 20:471 AMP V38372
Surrogate: Nitrobenzene-d5 51.6 Limits: 43-123%09/26/23 20:471 AMP V38372
Surrogate: 4-Terphenyl-d14 69.8 Limits: 49-151%09/26/23 20:471 AMP V38372
Surrogate: 2,4,6-Tribromophenol 71.9 Limits: 31-144%09/26/23 20:471 AMP V38372
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 04:28 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 04:28 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 04:28 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 04:28 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 04:28 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 04:28 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 04:28 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 04:28 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 04:28 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 04:28 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 04:28 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 04:28 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 04:28 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 04:28 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 04:28 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 04:28 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 04:28 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 04:28 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 04:28 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 04:28 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 04:28 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 04:28 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 04:28 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 04:28 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 04:28 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 04:28 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 04:28 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 04:28 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 04:28 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 04:28 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 04:28 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 04:28 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 04:28 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 04:28 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 04:28 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 04:28 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 04:28 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 04:28 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 04:28 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 04:28 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 04:28 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 04:28 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 04:28 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 04:28 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 04:28 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 04:28 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 04:28 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 04:28 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 04:28 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 04:28 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 04:28 V38378
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%09/26/23 04:281 MSA V38378
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%09/26/23 04:281 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 107 Limits: 70-130%09/26/23 04:281 MSA V38378
Surrogate: Toluene-d8 99.8 Limits: 70-130%09/26/23 04:281 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.453 µg/L 0.453 3.00Acenaphthene 1 09/25/23 20:52 V38300AMP
<0.445 µg/L 0.445 3.00Acenaphthylene 1 09/25/23 20:52 V38300AMP
<1.25 µg/L 1.25 3.00Anthracene 1 09/25/23 20:52 V38300AMP
<1.98 M µg/L 1.98 15.0Benzidine 1 09/25/23 20:52 V38300AMP
<0.955 µg/L 0.955 3.00Benzo(a)anthracene 1 09/25/23 20:52 V38300AMP
<1.53 µg/L 1.53 3.00Benzo(a)pyrene 1 09/25/23 20:52 V38300AMP
<3.74 µg/L 3.74 7.50Benzo(b)fluoranthene 1 09/25/23 20:52 V38300AMP
<1.52 µg/L 1.52 7.50Benzo(g,h,i)perylene 1 09/25/23 20:52 V38300AMP
<2.99 µg/L 2.99 7.50Benzo(k)fluoranthene 1 09/25/23 20:52 V38300AMP
<1.65 µg/L 1.65 15.0Benzoic Acid 1 09/25/23 20:52 V38300AMP
<1.03 µg/L 1.03 7.50Benzyl alcohol 1 09/25/23 20:52 V38300AMP
<0.702 µg/L 0.702 7.50Bis(2-Chloroethoxy)methane 1 09/25/23 20:52 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.56 µg/L 1.56 7.50Bis(2-Chloroethyl)ether 1 09/25/23 20:52 V38300AMP
<1.62 µg/L 1.62 7.50Bis(2-Chloroisopropyl)ether 1 09/25/23 20:52 V38300AMP
<5.19 µg/L 5.19 15.0Bis(2-ethylhexyl)phthalate 1 09/25/23 20:52 V38300AMP
<1.67 µg/L 1.67 7.504-Bromophenyl phenyl ether 1 09/25/23 20:52 V38300AMP
<2.75 µg/L 2.75 7.50Butyl benzyl phthalate 1 09/25/23 20:52 V38300AMP
<1.77 µg/L 1.77 7.504-Chloro-3-methylphenol 1 09/25/23 20:52 V38300AMP
<11.1 µg/L 11.1 30.02-Chloronaphthalene 1 09/25/23 20:52 V38300AMP
<1.41 µg/L 1.41 15.02-Chlorophenol 1 09/25/23 20:52 V38300AMP
<2.57 µg/L 2.57 7.504-Chlorophenyl phenyl ether 1 09/25/23 20:52 V38300AMP
<0.607 µg/L 0.607 3.00Chrysene 1 09/25/23 20:52 V38300AMP
<0.651 µg/L 0.651 3.00Dibenz(a,h)anthracene 1 09/25/23 20:52 V38300AMP
<1.28 µg/L 1.28 7.50Dibenzofuran 1 09/25/23 20:52 V38300AMP
<3.00 µg/L 3.00 7.501,2-Dichlorobenzene 1 09/25/23 20:52 V38300AMP
<3.00 µg/L 3.00 7.501,3-Dichlorobenzene 1 09/25/23 20:52 V38300AMP
<3.08 µg/L 3.08 7.501,4-Dichlorobenzene 1 09/25/23 20:52 V38300AMP
<2.84 µg/L 2.84 7.503,3'-Dichlorobenzidine 1 09/25/23 20:52 V38300AMP
<2.19 µg/L 2.19 15.02,4-Dichlorophenol 1 09/25/23 20:52 V38300AMP
4.26 J µg/L 1.12 7.50Diethyl phthalate 1 09/25/23 20:52 V38300AMP
<1.41 µg/L 1.41 7.50Dimethyl phthalate 1 09/25/23 20:52 V38300AMP
<2.36 µg/L 2.36 30.02,4-Dimethylphenol 1 09/25/23 20:52 V38300AMP
<3.09 µg/L 3.09 7.50Di-n-butyl phthalate 1 09/25/23 20:52 V38300AMP
<3.11 µg/L 3.11 15.04,6-Dinitro-2-methylphenol 1 09/25/23 20:52 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<2.88 µg/L 2.88 15.02,4-Dinitrophenol 1 09/25/23 20:52 V38300AMP
<1.67 µg/L 1.67 7.502,4-Dinitrotoluene 1 09/25/23 20:52 V38300AMP
<1.21 µg/L 1.21 7.502,6-Dinitrotoluene 1 09/25/23 20:52 V38300AMP
<2.48 µg/L 2.48 7.50Di-n-Octyl Phthalate 1 09/25/23 20:52 V38300AMP
<0.375 µg/L 0.375 3.00Fluoranthene 1 09/25/23 20:52 V38300AMP
<1.21 µg/L 1.21 3.00Fluorene 1 09/25/23 20:52 V38300AMP
<1.47 µg/L 1.47 7.50Hexachlorobenzene 1 09/25/23 20:52 V38300AMP
<4.10 µg/L 4.10 7.50Hexachlorobutadiene 1 09/25/23 20:52 V38300AMP
<3.08 µg/L 3.08 7.50Hexachlorocyclopentadiene 1 09/25/23 20:52 V38300AMP
<2.64 µg/L 2.64 7.50Hexachloroethane 1 09/25/23 20:52 V38300AMP
<0.715 µg/L 0.715 3.00Indeno(1,2,3-cd)pyrene 1 09/25/23 20:52 V38300AMP
<0.666 µg/L 0.666 7.50Isophorone 1 09/25/23 20:52 V38300AMP
<1.71 µg/L 1.71 3.001-Methylnaphthalene 1 09/25/23 20:52 V38300AMP
<0.999 µg/L 0.999 3.002-Methylnaphthalene 1 09/25/23 20:52 V38300AMP
<1.09 µg/L 1.09 3.00Naphthalene 1 09/25/23 20:52 V38300AMP
<1.36 µg/L 1.36 7.50Nitrobenzene 1 09/25/23 20:52 V38300AMP
<0.739 µg/L 0.739 7.502-Nitrophenol 1 09/25/23 20:52 V38300AMP
<1.85 µg/L 1.85 15.04-Nitrophenol 1 09/25/23 20:52 V38300AMP
<1.65 µg/L 1.65 7.50N-Nitrosodiphenylamine 1 09/25/23 20:52 V38300AMP
<0.961 µg/L 0.961 7.50N-Nitroso-di-n-propylamine 1 09/25/23 20:52 V38300AMP
<2.15 µg/L 2.15 7.50Pentachlorophenol 1 09/25/23 20:52 V38300AMP
<0.642 µg/L 0.642 3.00Phenanthrene 1 09/25/23 20:52 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-2
95676 Matrix:
9/19/2023 9:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.976 µg/L 0.976 7.50Phenol 1 09/25/23 20:52 V38300AMP
<0.651 µg/L 0.651 3.00Pyrene 1 09/25/23 20:52 V38300AMP
<3.32 µg/L 3.32 7.501,2,4-Trichlorobenzene 1 09/25/23 20:52 V38300AMP
<1.98 µg/L 1.98 7.502,4,6-Trichlorophenol 1 09/25/23 20:52 V38300AMP
625.1Surrogate: Phenol-d5 28.8 Limits: 10-63%09/25/23 20:521 AMP
Surrogate: 2-Fluorobiphenyl 83.8 Limits: 49-118%09/25/23 20:521 AMP V38300
Surrogate: 2-Fluorophenol 43.6 Limits: 22-84%09/25/23 20:521 AMP V38300
Surrogate: Nitrobenzene-d5 84.8 Limits: 43-123%09/25/23 20:521 AMP V38300
Surrogate: 4-Terphenyl-d14 103 Limits: 49-151%09/25/23 20:521 AMP V38300
Surrogate: 2,4,6-Tribromophenol 97.7 Limits: 31-144%09/25/23 20:521 AMP V38300
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 07:46 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 07:46 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 07:46 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 07:46 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 07:46 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 07:46 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 07:46 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 07:46 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 07:46 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 07:46 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 07:46 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 07:46 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 07:46 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 07:46 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 07:46 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 07:46 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 07:46 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 07:46 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 07:46 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 07:46 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 07:46 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 07:46 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 07:46 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 07:46 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 07:46 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 07:46 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 07:46 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 07:46 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 07:46 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 07:46 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 07:46 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 07:46 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 07:46 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 07:46 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 07:46 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 07:46 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 07:46 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 07:46 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 07:46 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 07:46 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 07:46 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 07:46 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 07:46 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 07:46 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 07:46 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 07:46 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 07:46 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 07:46 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 07:46 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 07:46 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 07:46 V38378
Surrogate: 4-Bromofluorobenzene 89.8 Limits: 70-130%09/26/23 07:461 MSA V38378
Surrogate: Dibromofluoromethane 100 Limits: 70-130%09/26/23 07:461 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 110 Limits: 70-130%09/26/23 07:461 MSA V38378
Surrogate: Toluene-d8 95.4 Limits: 70-130%09/26/23 07:461 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/25/23 20:28 V38300AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/25/23 20:28 V38300AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/25/23 20:28 V38300AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/25/23 20:28 V38300AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/25/23 20:28 V38300AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/25/23 20:28 V38300AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/25/23 20:28 V38300AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/25/23 20:28 V38300AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/25/23 20:28 V38300AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/25/23 20:28 V38300AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/25/23 20:28 V38300AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/25/23 20:28 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/25/23 20:28 V38300AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/25/23 20:28 V38300AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/25/23 20:28 V38300AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/25/23 20:28 V38300AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/25/23 20:28 V38300AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/25/23 20:28 V38300AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/25/23 20:28 V38300AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/25/23 20:28 V38300AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/25/23 20:28 V38300AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/25/23 20:28 V38300AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/25/23 20:28 V38300AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/25/23 20:28 V38300AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/25/23 20:28 V38300AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/25/23 20:28 V38300AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/25/23 20:28 V38300AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/25/23 20:28 V38300AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/25/23 20:28 V38300AMP
3.54 J µg/L 0.745 5.00Diethyl phthalate 1 09/25/23 20:28 V38300AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/25/23 20:28 V38300AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/25/23 20:28 V38300AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/25/23 20:28 V38300AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/25/23 20:28 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/25/23 20:28 V38300AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/25/23 20:28 V38300AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/25/23 20:28 V38300AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/25/23 20:28 V38300AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/25/23 20:28 V38300AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/25/23 20:28 V38300AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/25/23 20:28 V38300AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/25/23 20:28 V38300AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/25/23 20:28 V38300AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/25/23 20:28 V38300AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/25/23 20:28 V38300AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/25/23 20:28 V38300AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/25/23 20:28 V38300AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/25/23 20:28 V38300AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/25/23 20:28 V38300AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/25/23 20:28 V38300AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/25/23 20:28 V38300AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/25/23 20:28 V38300AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/25/23 20:28 V38300AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/25/23 20:28 V38300AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/25/23 20:28 V38300AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/25/23 20:28 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-3
95677 Matrix:
9/18/2023 16:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.651 µg/L 0.651 5.00Phenol 1 09/25/23 20:28 V38300AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/25/23 20:28 V38300AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/25/23 20:28 V38300AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/25/23 20:28 V38300AMP
625.1Surrogate: Phenol-d5 14.2 Limits: 10-63%09/25/23 20:281 AMP
Surrogate: 2-Fluorobiphenyl 64.4 Limits: 49-118%09/25/23 20:281 AMP V38300
Surrogate: 2-Fluorophenol 22.7 Limits: 22-84%09/25/23 20:281 AMP V38300
Surrogate: Nitrobenzene-d5 63.2 Limits: 43-123%09/25/23 20:281 AMP V38300
Surrogate: 4-Terphenyl-d14 81.4 Limits: 49-151%09/25/23 20:281 AMP V38300
Surrogate: 2,4,6-Tribromophenol 81.0 Limits: 31-144%09/25/23 20:281 AMP V38300
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38414 09/26/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 18:13 V38416ENM
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 18:13 V38416ENM
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 18:13 V38416ENM
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 18:13 V38416ENM
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 18:13 V38416ENM
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 18:13 V38416ENM
0.242 J µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 18:13 V38416ENM
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 18:13 V38416ENM
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 18:13 V38416ENM
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 18:13 V38416ENM
<0.220 M µg/L 0.220 0.500Chloromethane 1 09/26/23 18:13 V38416ENM
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 18:13 V38416ENM
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 18:13 V38416ENM
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 18:13 V38416ENM
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 18:13 V38416ENM
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 18:13 V38416ENM
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 18:13 V38416ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38414 09/26/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 18:13 V38416ENM
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 18:13 V38416ENM
<1.20 M µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 18:13 V38416ENM
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 18:13 V38416ENM
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 18:13 V38416ENM
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 18:13 V38416ENM
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 18:13 V38416ENM
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 18:13 V38416ENM
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 18:13 V38416ENM
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 18:13 V38416ENM
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 18:13 V38416ENM
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 18:13 V38416ENM
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 18:13 V38416ENM
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 18:13 V38416ENM
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 18:13 V38416ENM
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 18:13 V38416ENM
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 18:13 V38416ENM
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 18:13 V38416ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38414 09/26/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 18:13 V38416ENM
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 18:13 V38416ENM
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 18:13 V38416ENM
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 18:13 V38416ENM
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 18:13 V38416ENM
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 18:13 V38416ENM
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 18:13 V38416ENM
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 18:13 V38416ENM
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 18:13 V38416ENM
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 18:13 V38416ENM
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 18:13 V38416ENM
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 18:13 V38416ENM
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 18:13 V38416ENM
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 18:13 V38416ENM
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 18:13 V38416ENM
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 18:13 V38416ENM
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 18:13 V38416ENM
<0.170 M µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 18:13 V38416ENM
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 18:13 V38416ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38414 09/26/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 18:13 V38416ENM
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 18:13 V38416
Surrogate: 4-Bromofluorobenzene 91.2 Limits: 70-130%09/26/23 18:131 ENM V38416
Surrogate: Dibromofluoromethane 102 Limits: 70-130%09/26/23 18:131 ENM V38416
Surrogate: 1,2-Dichloroethane - d4 113 Limits: 70-130%09/26/23 18:131 ENM V38416
Surrogate: Toluene-d8 98.4 Limits: 70-130%09/26/23 18:131 ENM V38416
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
0.591 J µg/L 0.302 2.00Acenaphthene 1 09/25/23 20:05 V38300AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/25/23 20:05 V38300AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/25/23 20:05 V38300AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/25/23 20:05 V38300AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/25/23 20:05 V38300AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/25/23 20:05 V38300AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/25/23 20:05 V38300AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/25/23 20:05 V38300AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/25/23 20:05 V38300AMP
4.54 J µg/L 1.10 10.0Benzoic Acid 1 09/25/23 20:05 V38300AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/25/23 20:05 V38300AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/25/23 20:05 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/25/23 20:05 V38300AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/25/23 20:05 V38300AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/25/23 20:05 V38300AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/25/23 20:05 V38300AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/25/23 20:05 V38300AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/25/23 20:05 V38300AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/25/23 20:05 V38300AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/25/23 20:05 V38300AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/25/23 20:05 V38300AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/25/23 20:05 V38300AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/25/23 20:05 V38300AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/25/23 20:05 V38300AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/25/23 20:05 V38300AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/25/23 20:05 V38300AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/25/23 20:05 V38300AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/25/23 20:05 V38300AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/25/23 20:05 V38300AMP
2.49 J µg/L 0.745 5.00Diethyl phthalate 1 09/25/23 20:05 V38300AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/25/23 20:05 V38300AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/25/23 20:05 V38300AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/25/23 20:05 V38300AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/25/23 20:05 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 33 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/25/23 20:05 V38300AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/25/23 20:05 V38300AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/25/23 20:05 V38300AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/25/23 20:05 V38300AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/25/23 20:05 V38300AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/25/23 20:05 V38300AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/25/23 20:05 V38300AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/25/23 20:05 V38300AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/25/23 20:05 V38300AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/25/23 20:05 V38300AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/25/23 20:05 V38300AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/25/23 20:05 V38300AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/25/23 20:05 V38300AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/25/23 20:05 V38300AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/25/23 20:05 V38300AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/25/23 20:05 V38300AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/25/23 20:05 V38300AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/25/23 20:05 V38300AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/25/23 20:05 V38300AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/25/23 20:05 V38300AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/25/23 20:05 V38300AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/25/23 20:05 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 34 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-4
95678 Matrix:
9/18/2023 15:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.651 µg/L 0.651 5.00Phenol 1 09/25/23 20:05 V38300AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/25/23 20:05 V38300AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/25/23 20:05 V38300AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/25/23 20:05 V38300AMP
625.1Surrogate: Phenol-d5 19.1 Limits: 10-63%09/25/23 20:051 AMP
Surrogate: 2-Fluorobiphenyl 57.2 Limits: 49-118%09/25/23 20:051 AMP V38300
Surrogate: 2-Fluorophenol 27.1 Limits: 22-84%09/25/23 20:051 AMP V38300
Surrogate: Nitrobenzene-d5 55.6 Limits: 43-123%09/25/23 20:051 AMP V38300
Surrogate: 4-Terphenyl-d14 81.2 Limits: 49-151%09/25/23 20:051 AMP V38300
Surrogate: 2,4,6-Tribromophenol 78.3 Limits: 31-144%09/25/23 20:051 AMP V38300
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 35 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 04:53 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 04:53 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 04:53 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 04:53 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 04:53 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 04:53 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 04:53 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 04:53 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 04:53 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 04:53 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 04:53 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 04:53 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 04:53 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 36 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 04:53 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 04:53 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 04:53 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 04:53 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 04:53 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 04:53 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 04:53 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 04:53 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 04:53 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 04:53 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 04:53 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 04:53 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 04:53 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 04:53 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 04:53 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 04:53 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 04:53 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 37 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 04:53 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 04:53 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 04:53 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 04:53 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 04:53 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 04:53 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 04:53 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 04:53 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 04:53 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 04:53 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 04:53 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 04:53 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 04:53 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 04:53 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 04:53 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 04:53 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 04:53 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 04:53 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 04:53 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 38 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 04:53 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 04:53 V38378
Surrogate: 4-Bromofluorobenzene 90.6 Limits: 70-130%09/26/23 04:531 MSA V38378
Surrogate: Dibromofluoromethane 104 Limits: 70-130%09/26/23 04:531 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 112 Limits: 70-130%09/26/23 04:531 MSA V38378
Surrogate: Toluene-d8 97.6 Limits: 70-130%09/26/23 04:531 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/25/23 19:42 V38300AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/25/23 19:42 V38300AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/25/23 19:42 V38300AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/25/23 19:42 V38300AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/25/23 19:42 V38300AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/25/23 19:42 V38300AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/25/23 19:42 V38300AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/25/23 19:42 V38300AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/25/23 19:42 V38300AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/25/23 19:42 V38300AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/25/23 19:42 V38300AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/25/23 19:42 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 39 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/25/23 19:42 V38300AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/25/23 19:42 V38300AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/25/23 19:42 V38300AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/25/23 19:42 V38300AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/25/23 19:42 V38300AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/25/23 19:42 V38300AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/25/23 19:42 V38300AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/25/23 19:42 V38300AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/25/23 19:42 V38300AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/25/23 19:42 V38300AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/25/23 19:42 V38300AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/25/23 19:42 V38300AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/25/23 19:42 V38300AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/25/23 19:42 V38300AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/25/23 19:42 V38300AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/25/23 19:42 V38300AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/25/23 19:42 V38300AMP
5.15 µg/L 0.745 5.00Diethyl phthalate 1 09/25/23 19:42 V38300AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/25/23 19:42 V38300AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/25/23 19:42 V38300AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/25/23 19:42 V38300AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/25/23 19:42 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 40 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/25/23 19:42 V38300AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/25/23 19:42 V38300AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/25/23 19:42 V38300AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/25/23 19:42 V38300AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/25/23 19:42 V38300AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/25/23 19:42 V38300AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/25/23 19:42 V38300AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/25/23 19:42 V38300AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/25/23 19:42 V38300AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/25/23 19:42 V38300AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/25/23 19:42 V38300AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/25/23 19:42 V38300AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/25/23 19:42 V38300AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/25/23 19:42 V38300AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/25/23 19:42 V38300AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/25/23 19:42 V38300AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/25/23 19:42 V38300AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/25/23 19:42 V38300AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/25/23 19:42 V38300AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/25/23 19:42 V38300AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/25/23 19:42 V38300AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/25/23 19:42 V38300AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 41 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:MW-5
95679 Matrix:
9/18/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38276 09/25/23 10:51
<0.651 µg/L 0.651 5.00Phenol 1 09/25/23 19:42 V38300AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/25/23 19:42 V38300AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/25/23 19:42 V38300AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/25/23 19:42 V38300AMP
625.1Surrogate: Phenol-d5 17.7 Limits: 10-63%09/25/23 19:421 AMP
Surrogate: 2-Fluorobiphenyl 52.8 Limits: 49-118%09/25/23 19:421 AMP V38300
Surrogate: 2-Fluorophenol 26.1 Limits: 22-84%09/25/23 19:421 AMP V38300
Surrogate: Nitrobenzene-d5 53.8 Limits: 43-123%09/25/23 19:421 AMP V38300
Surrogate: 4-Terphenyl-d14 71.0 Limits: 49-151%09/25/23 19:421 AMP V38300
Surrogate: 2,4,6-Tribromophenol 71.1 Limits: 31-144%09/25/23 19:421 AMP V38300
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 42 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 08:11 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 08:11 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 08:11 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 08:11 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 08:11 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 08:11 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 08:11 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 08:11 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 08:11 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 08:11 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 08:11 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 08:11 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 08:11 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 43 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 08:11 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 08:11 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 08:11 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 08:11 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 08:11 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 08:11 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 08:11 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 08:11 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 08:11 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 08:11 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 08:11 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 08:11 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 08:11 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 08:11 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 08:11 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 08:11 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 08:11 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 44 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 08:11 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 08:11 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 08:11 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 08:11 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 08:11 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 08:11 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 08:11 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 08:11 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 08:11 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 08:11 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 08:11 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 08:11 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 08:11 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 08:11 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 08:11 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 08:11 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 08:11 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 08:11 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 08:11 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 45 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 08:11 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 08:11 V38378
Surrogate: 4-Bromofluorobenzene 94.2 Limits: 70-130%09/26/23 08:111 MSA V38378
Surrogate: Dibromofluoromethane 104 Limits: 70-130%09/26/23 08:111 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 113 Limits: 70-130%09/26/23 08:111 MSA V38378
Surrogate: Toluene-d8 99.0 Limits: 70-130%09/26/23 08:111 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/26/23 20:23 V38372AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/26/23 20:23 V38372AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/26/23 20:23 V38372AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/26/23 20:23 V38372AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/26/23 20:23 V38372AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/26/23 20:23 V38372AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/26/23 20:23 V38372AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/26/23 20:23 V38372AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/26/23 20:23 V38372AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/26/23 20:23 V38372AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/26/23 20:23 V38372AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/26/23 20:23 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 46 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/26/23 20:23 V38372AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/26/23 20:23 V38372AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/26/23 20:23 V38372AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/26/23 20:23 V38372AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/26/23 20:23 V38372AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/26/23 20:23 V38372AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/26/23 20:23 V38372AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/26/23 20:23 V38372AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/26/23 20:23 V38372AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/26/23 20:23 V38372AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/26/23 20:23 V38372AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/26/23 20:23 V38372AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/26/23 20:23 V38372AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/26/23 20:23 V38372AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/26/23 20:23 V38372AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/26/23 20:23 V38372AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/26/23 20:23 V38372AMP
11.9 µg/L 0.745 5.00Diethyl phthalate 1 09/26/23 20:23 V38372AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/26/23 20:23 V38372AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/26/23 20:23 V38372AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/26/23 20:23 V38372AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/26/23 20:23 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 47 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/26/23 20:23 V38372AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/26/23 20:23 V38372AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/26/23 20:23 V38372AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/26/23 20:23 V38372AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/26/23 20:23 V38372AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/26/23 20:23 V38372AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/26/23 20:23 V38372AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/26/23 20:23 V38372AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/26/23 20:23 V38372AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/26/23 20:23 V38372AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/26/23 20:23 V38372AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/26/23 20:23 V38372AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/26/23 20:23 V38372AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/26/23 20:23 V38372AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/26/23 20:23 V38372AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/26/23 20:23 V38372AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/26/23 20:23 V38372AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/26/23 20:23 V38372AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/26/23 20:23 V38372AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/26/23 20:23 V38372AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/26/23 20:23 V38372AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/26/23 20:23 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 48 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:DW-1
95680 Matrix:
9/19/2023 10:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.651 µg/L 0.651 5.00Phenol 1 09/26/23 20:23 V38372AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/26/23 20:23 V38372AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/26/23 20:23 V38372AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/26/23 20:23 V38372AMP
625.1Surrogate: Phenol-d5 24.9 Limits: 10-63%09/26/23 20:231 AMP
Surrogate: 2-Fluorobiphenyl 57.4 Limits: 49-118%09/26/23 20:231 AMP V38372
Surrogate: 2-Fluorophenol 36.5 Limits: 22-84%09/26/23 20:231 AMP V38372
Surrogate: Nitrobenzene-d5 52.0 Limits: 43-123%09/26/23 20:231 AMP V38372
Surrogate: 4-Terphenyl-d14 69.8 Limits: 49-151%09/26/23 20:231 AMP V38372
Surrogate: 2,4,6-Tribromophenol 71.0 Limits: 31-144%09/26/23 20:231 AMP V38372
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 49 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 05:17 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 05:17 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 05:17 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 05:17 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 05:17 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 05:17 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 05:17 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 05:17 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 05:17 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 05:17 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 05:17 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 05:17 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 05:17 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 50 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 05:17 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 05:17 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 05:17 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 05:17 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 05:17 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 05:17 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 05:17 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 05:17 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 05:17 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 05:17 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 05:17 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 05:17 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 05:17 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 05:17 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 05:17 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 05:17 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 05:17 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 51 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 05:17 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 05:17 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 05:17 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 05:17 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 05:17 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 05:17 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 05:17 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 05:17 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 05:17 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 05:17 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 05:17 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 05:17 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 05:17 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 05:17 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 05:17 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 05:17 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 05:17 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 05:17 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 05:17 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 52 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 05:17 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 05:17 V38378
Surrogate: 4-Bromofluorobenzene 92.2 Limits: 70-130%09/26/23 05:171 MSA V38378
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%09/26/23 05:171 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 113 Limits: 70-130%09/26/23 05:171 MSA V38378
Surrogate: Toluene-d8 96.4 Limits: 70-130%09/26/23 05:171 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/26/23 21:56 V38372AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/26/23 21:56 V38372AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/26/23 21:56 V38372AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/26/23 21:56 V38372AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/26/23 21:56 V38372AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/26/23 21:56 V38372AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/26/23 21:56 V38372AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/26/23 21:56 V38372AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/26/23 21:56 V38372AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/26/23 21:56 V38372AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/26/23 21:56 V38372AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/26/23 21:56 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 53 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/26/23 21:56 V38372AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/26/23 21:56 V38372AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/26/23 21:56 V38372AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/26/23 21:56 V38372AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/26/23 21:56 V38372AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/26/23 21:56 V38372AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/26/23 21:56 V38372AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/26/23 21:56 V38372AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/26/23 21:56 V38372AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/26/23 21:56 V38372AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/26/23 21:56 V38372AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/26/23 21:56 V38372AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/26/23 21:56 V38372AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/26/23 21:56 V38372AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/26/23 21:56 V38372AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/26/23 21:56 V38372AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/26/23 21:56 V38372AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/26/23 21:56 V38372AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/26/23 21:56 V38372AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/26/23 21:56 V38372AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/26/23 21:56 V38372AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/26/23 21:56 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 54 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/26/23 21:56 V38372AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/26/23 21:56 V38372AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/26/23 21:56 V38372AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/26/23 21:56 V38372AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/26/23 21:56 V38372AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/26/23 21:56 V38372AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/26/23 21:56 V38372AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/26/23 21:56 V38372AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/26/23 21:56 V38372AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/26/23 21:56 V38372AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/26/23 21:56 V38372AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/26/23 21:56 V38372AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/26/23 21:56 V38372AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/26/23 21:56 V38372AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/26/23 21:56 V38372AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/26/23 21:56 V38372AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/26/23 21:56 V38372AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/26/23 21:56 V38372AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/26/23 21:56 V38372AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/26/23 21:56 V38372AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/26/23 21:56 V38372AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/26/23 21:56 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 55 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:UPSTREAM
95681 Matrix:
9/19/2023 12:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.651 µg/L 0.651 5.00Phenol 1 09/26/23 21:56 V38372AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/26/23 21:56 V38372AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/26/23 21:56 V38372AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/26/23 21:56 V38372AMP
625.1Surrogate: Phenol-d5 25.2 Limits: 10-63%09/26/23 21:561 AMP
Surrogate: 2-Fluorobiphenyl 68.2 Limits: 49-118%09/26/23 21:561 AMP V38372
Surrogate: 2-Fluorophenol 39.6 Limits: 22-84%09/26/23 21:561 AMP V38372
Surrogate: Nitrobenzene-d5 64.2 Limits: 43-123%09/26/23 21:561 AMP V38372
Surrogate: 4-Terphenyl-d14 80.4 Limits: 49-151%09/26/23 21:561 AMP V38372
Surrogate: 2,4,6-Tribromophenol 76.2 Limits: 31-144%09/26/23 21:561 AMP V38372
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 56 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 05:42 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 05:42 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 05:42 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 05:42 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 05:42 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 05:42 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 05:42 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 05:42 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 05:42 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 05:42 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 05:42 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 05:42 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 05:42 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 57 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 05:42 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 05:42 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 05:42 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 05:42 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 05:42 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 05:42 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 05:42 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 05:42 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 05:42 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 05:42 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 05:42 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 05:42 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 05:42 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 05:42 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 05:42 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 05:42 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 05:42 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 58 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 05:42 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 05:42 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 05:42 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 05:42 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 05:42 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 05:42 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 05:42 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 05:42 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 05:42 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 05:42 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 05:42 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 05:42 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 05:42 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 05:42 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 05:42 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 05:42 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 05:42 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 05:42 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 05:42 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 59 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 05:42 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 05:42 V38378
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%09/26/23 05:421 MSA V38378
Surrogate: Dibromofluoromethane 106 Limits: 70-130%09/26/23 05:421 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 114 Limits: 70-130%09/26/23 05:421 MSA V38378
Surrogate: Toluene-d8 97.8 Limits: 70-130%09/26/23 05:421 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/26/23 21:33 V38372AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/26/23 21:33 V38372AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/26/23 21:33 V38372AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/26/23 21:33 V38372AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/26/23 21:33 V38372AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/26/23 21:33 V38372AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/26/23 21:33 V38372AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/26/23 21:33 V38372AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/26/23 21:33 V38372AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/26/23 21:33 V38372AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/26/23 21:33 V38372AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/26/23 21:33 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 60 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/26/23 21:33 V38372AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/26/23 21:33 V38372AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/26/23 21:33 V38372AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/26/23 21:33 V38372AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/26/23 21:33 V38372AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/26/23 21:33 V38372AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/26/23 21:33 V38372AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/26/23 21:33 V38372AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/26/23 21:33 V38372AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/26/23 21:33 V38372AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/26/23 21:33 V38372AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/26/23 21:33 V38372AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/26/23 21:33 V38372AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/26/23 21:33 V38372AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/26/23 21:33 V38372AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/26/23 21:33 V38372AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/26/23 21:33 V38372AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/26/23 21:33 V38372AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/26/23 21:33 V38372AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/26/23 21:33 V38372AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/26/23 21:33 V38372AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/26/23 21:33 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 61 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/26/23 21:33 V38372AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/26/23 21:33 V38372AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/26/23 21:33 V38372AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/26/23 21:33 V38372AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/26/23 21:33 V38372AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/26/23 21:33 V38372AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/26/23 21:33 V38372AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/26/23 21:33 V38372AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/26/23 21:33 V38372AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/26/23 21:33 V38372AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/26/23 21:33 V38372AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/26/23 21:33 V38372AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/26/23 21:33 V38372AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/26/23 21:33 V38372AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/26/23 21:33 V38372AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/26/23 21:33 V38372AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/26/23 21:33 V38372AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/26/23 21:33 V38372AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/26/23 21:33 V38372AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/26/23 21:33 V38372AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/26/23 21:33 V38372AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/26/23 21:33 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 62 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Edge of Bank
95682 Matrix:
9/19/2023 12:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.651 µg/L 0.651 5.00Phenol 1 09/26/23 21:33 V38372AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/26/23 21:33 V38372AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/26/23 21:33 V38372AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/26/23 21:33 V38372AMP
625.1Surrogate: Phenol-d5 26.4 Limits: 10-63%09/26/23 21:331 AMP
Surrogate: 2-Fluorobiphenyl 62.0 Limits: 49-118%09/26/23 21:331 AMP V38372
Surrogate: 2-Fluorophenol 40.6 Limits: 22-84%09/26/23 21:331 AMP V38372
Surrogate: Nitrobenzene-d5 58.2 Limits: 43-123%09/26/23 21:331 AMP V38372
Surrogate: 4-Terphenyl-d14 75.8 Limits: 49-151%09/26/23 21:331 AMP V38372
Surrogate: 2,4,6-Tribromophenol 72.4 Limits: 31-144%09/26/23 21:331 AMP V38372
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 63 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<1.80 µg/L 1.80 10.0Acetone 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500Benzene 1 09/26/23 06:07 V38378MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/26/23 06:07 V38378MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/26/23 06:07 V38378MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/26/23 06:07 V38378MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/26/23 06:07 V38378MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 09/26/23 06:07 V38378MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/26/23 06:07 V38378MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/26/23 06:07 V38378MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/26/23 06:07 V38378MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/26/23 06:07 V38378MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/26/23 06:07 V38378MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/26/23 06:07 V38378MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/26/23 06:07 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 64 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/26/23 06:07 V38378MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/26/23 06:07 V38378MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/26/23 06:07 V38378MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/26/23 06:07 V38378MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/26/23 06:07 V38378MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/26/23 06:07 V38378MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/26/23 06:07 V38378MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/26/23 06:07 V38378MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/26/23 06:07 V38378MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/26/23 06:07 V38378MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/26/23 06:07 V38378MSA
<42.0 µg/L 42.0 200Ethanol 1 09/26/23 06:07 V38378MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/26/23 06:07 V38378MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/26/23 06:07 V38378MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/26/23 06:07 V38378MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/26/23 06:07 V38378MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/26/23 06:07 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 65 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/26/23 06:07 V38378MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/26/23 06:07 V38378MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/26/23 06:07 V38378MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/26/23 06:07 V38378MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/26/23 06:07 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/26/23 06:07 V38378MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/26/23 06:07 V38378MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/26/23 06:07 V38378MSA
<0.220 µg/L 0.220 0.500Toluene 1 09/26/23 06:07 V38378MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/26/23 06:07 V38378MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/26/23 06:07 V38378MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/26/23 06:07 V38378MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/26/23 06:07 V38378MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/26/23 06:07 V38378MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/26/23 06:07 V38378MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/26/23 06:07 V38378MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/26/23 06:07 V38378MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/26/23 06:07 V38378MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 09/26/23 06:07 V38378MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 66 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38377 09/25/23 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/26/23 06:07 V38378MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/26/23 06:07 V38378
Surrogate: 4-Bromofluorobenzene 91.2 Limits: 70-130%09/26/23 06:071 MSA V38378
Surrogate: Dibromofluoromethane 101 Limits: 70-130%09/26/23 06:071 MSA V38378
Surrogate: 1,2-Dichloroethane - d4 109 Limits: 70-130%09/26/23 06:071 MSA V38378
Surrogate: Toluene-d8 97.6 Limits: 70-130%09/26/23 06:071 MSA V38378
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/26/23 21:10 V38372AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/26/23 21:10 V38372AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/26/23 21:10 V38372AMP
<1.32 M µg/L 1.32 10.0Benzidine 1 09/26/23 21:10 V38372AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/26/23 21:10 V38372AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/26/23 21:10 V38372AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/26/23 21:10 V38372AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/26/23 21:10 V38372AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/26/23 21:10 V38372AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/26/23 21:10 V38372AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/26/23 21:10 V38372AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/26/23 21:10 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 67 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/26/23 21:10 V38372AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/26/23 21:10 V38372AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/26/23 21:10 V38372AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/26/23 21:10 V38372AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/26/23 21:10 V38372AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/26/23 21:10 V38372AMP
<7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/26/23 21:10 V38372AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/26/23 21:10 V38372AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/26/23 21:10 V38372AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/26/23 21:10 V38372AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/26/23 21:10 V38372AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/26/23 21:10 V38372AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/26/23 21:10 V38372AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/26/23 21:10 V38372AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/26/23 21:10 V38372AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/26/23 21:10 V38372AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/26/23 21:10 V38372AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/26/23 21:10 V38372AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/26/23 21:10 V38372AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/26/23 21:10 V38372AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/26/23 21:10 V38372AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/26/23 21:10 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 68 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/26/23 21:10 V38372AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/26/23 21:10 V38372AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/26/23 21:10 V38372AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/26/23 21:10 V38372AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/26/23 21:10 V38372AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/26/23 21:10 V38372AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/26/23 21:10 V38372AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/26/23 21:10 V38372AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/26/23 21:10 V38372AMP
<1.76 µg/L 1.76 5.00Hexachloroethane 1 09/26/23 21:10 V38372AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/26/23 21:10 V38372AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/26/23 21:10 V38372AMP
<1.14 µg/L 1.14 2.001-Methylnaphthalene 1 09/26/23 21:10 V38372AMP
<0.666 µg/L 0.666 2.002-Methylnaphthalene 1 09/26/23 21:10 V38372AMP
<0.728 µg/L 0.728 2.00Naphthalene 1 09/26/23 21:10 V38372AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/26/23 21:10 V38372AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/26/23 21:10 V38372AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/26/23 21:10 V38372AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/26/23 21:10 V38372AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/26/23 21:10 V38372AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/26/23 21:10 V38372AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/26/23 21:10 V38372AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 69 of 102
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-263-0010
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 09/20/2023
DOT-476
Report Date : 09/29/2023
Sample ID :
Lab No :
Sampled:Downstream
95683 Matrix:
9/19/2023 12:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V38350 09/26/23 11:13
<0.651 µg/L 0.651 5.00Phenol 1 09/26/23 21:10 V38372AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/26/23 21:10 V38372AMP
<2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/26/23 21:10 V38372AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/26/23 21:10 V38372AMP
625.1Surrogate: Phenol-d5 26.8 Limits: 10-63%09/26/23 21:101 AMP
Surrogate: 2-Fluorobiphenyl 63.6 Limits: 49-118%09/26/23 21:101 AMP V38372
Surrogate: 2-Fluorophenol 41.8 Limits: 22-84%09/26/23 21:101 AMP V38372
Surrogate: Nitrobenzene-d5 62.4 Limits: 43-123%09/26/23 21:101 AMP V38372
Surrogate: 4-Terphenyl-d14 80.0 Limits: 49-151%09/26/23 21:101 AMP V38372
Surrogate: 2,4,6-Tribromophenol 75.5 Limits: 31-144%09/26/23 21:101 AMP V38372
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 70 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
Associated Lab Samples: 95676, 95677, 95679, 95680, 95681, 95682, 95683
LRB-V38377 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 02:4910.01.80<1.80µg/LAcetone
09/26/23 02:490.5000.180<0.180µg/LBenzene
09/26/23 02:490.5000.210<0.210µg/LBromobenzene
09/26/23 02:491.000.420<0.420µg/LBromochloromethane
09/26/23 02:490.5000.160<0.160µg/LBromodichloromethane
09/26/23 02:495.001.50<1.50µg/LBromoform
09/26/23 02:491.000.280<0.280µg/LBromomethane
09/26/23 02:490.5000.180<0.180µg/Ln-Butylbenzene
09/26/23 02:490.5000.200<0.200µg/Lsec-Butyl benzene
09/26/23 02:492.000.920<0.920µg/Ltert-Butyl benzene
09/26/23 02:490.5000.180<0.180µg/LCarbon Tetrachloride
09/26/23 02:490.5000.190<0.190µg/LChlorobenzene
09/26/23 02:490.5000.190<0.190µg/LChlorodibromomethane
09/26/23 02:491.000.430<0.430µg/LChloroethane
09/26/23 02:490.5000.220<0.220µg/LChloroform
09/26/23 02:490.5000.220<0.220µg/LChloromethane
09/26/23 02:490.5000.200<0.200µg/L2-Chlorotoluene
09/26/23 02:490.5000.200<0.200µg/L4-Chlorotoluene
09/26/23 02:490.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/26/23 02:492.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/26/23 02:490.5000.200<0.200µg/L1,2-Dibromoethane
09/26/23 02:490.5000.230<0.230µg/LDibromomethane
09/26/23 02:490.5000.220<0.220µg/L1,2-Dichlorobenzene
09/26/23 02:490.5000.190<0.190µg/L1,3-Dichlorobenzene
09/26/23 02:490.5000.210<0.210µg/L1,4-Dichlorobenzene
09/26/23 02:495.001.20<1.20µg/LDichlorodifluoromethane
09/26/23 02:490.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 30Date:09/29/2023 08:35 AM
Page 71 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
Associated Lab Samples: 95676, 95677, 95679, 95680, 95681, 95682, 95683
LRB-V38377 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 02:490.5000.150<0.150µg/L1,2-Dichloroethane
09/26/23 02:490.5000.150<0.150µg/L1,1-Dichloroethene
09/26/23 02:490.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/26/23 02:490.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/26/23 02:490.5000.190<0.190µg/L1,2-Dichloropropane
09/26/23 02:490.5000.130<0.130µg/L1,3-Dichloropropane
09/26/23 02:492.000.210<0.210µg/L2,2-Dichloropropane
09/26/23 02:490.5000.200<0.200µg/L1,1-Dichloropropene
09/26/23 02:490.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/26/23 02:490.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/26/23 02:4920042.0<42.0µg/LEthanol
09/26/23 02:490.5000.170<0.170µg/LEthylbenzene
09/26/23 02:493.000.350<0.350µg/LHexachlorobutadiene
09/26/23 02:491.000.380<0.380µg/L2-Hexanone
09/26/23 02:490.5000.180<0.180µg/LIsopropylbenzene
09/26/23 02:490.5000.089<0.089µg/L4-Isopropyl toluene
09/26/23 02:495.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/26/23 02:491.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/26/23 02:491.000.078<0.078µg/L4-Methyl-2-Pentanone
09/26/23 02:492.000.330<0.330µg/LMethylene Chloride
09/26/23 02:491.000.470<0.470µg/LNaphthalene
09/26/23 02:490.5000.190<0.190µg/Ln-Propylbenzene
09/26/23 02:490.5000.220<0.220µg/LStyrene
09/26/23 02:490.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/26/23 02:490.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/26/23 02:490.5000.220<0.220µg/LTetrachloroethene
09/26/23 02:490.5000.220<0.220µg/LToluene
Page 2 of 30Date:09/29/2023 08:35 AM
Page 72 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
Associated Lab Samples: 95676, 95677, 95679, 95680, 95681, 95682, 95683
LRB-V38377 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 02:490.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/26/23 02:490.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/26/23 02:490.5000.160<0.160µg/L1,1,1-Trichloroethane
09/26/23 02:490.5000.096<0.096µg/L1,1,2-Trichloroethane
09/26/23 02:490.5000.180<0.180µg/LTrichloroethene
09/26/23 02:490.5000.180<0.180µg/LTrichlorofluoromethane
09/26/23 02:490.5000.270<0.270µg/L1,2,3-Trichloropropane
09/26/23 02:490.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/26/23 02:490.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/26/23 02:495.001.00<1.00µg/LVinyl Acetate
09/26/23 02:490.5000.170<0.170µg/LVinyl Chloride
09/26/23 02:490.5000.210<0.210µg/Lo-Xylene
09/26/23 02:491.000.420<0.420µg/Lm,p-Xylene
09/26/23 02:494-Bromofluorobenzene (S)91.0 70-130
09/26/23 02:49Dibromofluoromethane (S)100 70-130
09/26/23 02:491,2-Dichloroethane - d4 (S)106 70-130
09/26/23 02:49Toluene-d8 (S)98.6 70-130
LCS-V38377Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
134*26.820.0µg/LCarbon Tetrachloride 70-130
Page 3 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 73 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
LCS-V38377 LCSD-V38377Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
38.5 96.296.738.740.0µg/LAcetone 40-160 0.5 20.0
19.7 98.598.519.720.0µg/LBenzene 70-130 0.0 20.0
20.5 10310020.020.0µg/LBromobenzene 70-130 2.4 20.0
22.5 11311122.120.0µg/LBromochloromethane 70-130 1.7 20.0
22.1 11110721.320.0µg/LBromodichloromethane 70-130 3.6 20.0
24.0 12011723.320.0µg/LBromoform 70-130 2.9 20.0
21.7 10996.519.320.0µg/LBromomethane 60-140 11.7 20.0
20.7 10410220.420.0µg/Ln-Butylbenzene 70-130 1.4 20.0
20.4 10210120.220.0µg/Lsec-Butyl benzene 70-130 0.9 20.0
21.7 10910520.920.0µg/Ltert-Butyl benzene 70-130 3.7 20.0
21.9 11010721.420.0µg/LChlorobenzene 70-130 2.3 20.0
24.1 12111422.720.0µg/LChlorodibromomethane 70-130 5.9 20.0
14.3 71.573.014.620.0µg/LChloroethane 60-140 2.0 20.0
21.3 10711021.920.0µg/LChloroform 70-130 2.7 20.0
13.0 65.061.012.220.0µg/LChloromethane 60-140 6.3 20.0
19.4 97.097.019.420.0µg/L2-Chlorotoluene 70-130 0.0 20.0
20.4 10210120.220.0µg/L4-Chlorotoluene 70-130 0.9 20.0
16.5 82.578.515.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 4.9 20.0
22.5 11311122.220.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.3 20.0
19.9 99.510220.420.0µg/L1,2-Dibromoethane 70-130 2.4 20.0
23.0 11510220.420.0µg/LDibromomethane 70-130 11.9 20.0
22.0 11011122.220.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
22.1 11110921.720.0µg/L1,3-Dichlorobenzene 70-130 1.8 20.0
21.1 10610821.620.0µg/L1,4-Dichlorobenzene 70-130 2.3 20.0
12.9 64.563.512.720.0µg/LDichlorodifluoromethane 60-140 1.5 20.0
19.1 95.596.519.320.0µg/L1,1-Dichloroethane 70-130 1.0 20.0
Page 4 of 30Date:09/29/2023 08:35 AM
Page 74 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
LCS-V38377 LCSD-V38377Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.7 11411422.820.0µg/L1,2-Dichloroethane 70-130 0.4 20.0
22.2 11198.019.620.0µg/L1,1-Dichloroethene 70-130 12.4 20.0
19.8 99.099.519.920.0µg/Lcis-1,2-Dichloroethene 70-130 0.5 20.0
19.6 98.010020.020.0µg/Ltrans-1,2-Dichloroethene 70-130 2.0 20.0
16.6 83.084.016.820.0µg/L1,2-Dichloropropane 70-130 1.1 20.0
19.7 98.597.019.420.0µg/L1,3-Dichloropropane 70-130 1.5 20.0
20.3 10210520.920.0µg/L2,2-Dichloropropane 70-130 2.9 20.0
22.6 11311122.120.0µg/L1,1-Dichloropropene 70-130 2.2 20.0
19.6 98.096.019.220.0µg/Lcis-1,3-Dichloropropene 70-130 2.0 20.0
20.9 10510520.920.0µg/Ltrans-1,3-Dichloropropene 70-130 0.0 20.0
440 88.079.2396500µg/LEthanol 60-140 10.5 20.0
20.6 10310120.120.0µg/LEthylbenzene 70-130 2.4 20.0
24.7 12412023.920.0µg/LHexachlorobutadiene 70-130 3.2 20.0
17.2 86.090.018.020.0µg/L2-Hexanone 60-140 4.5 20.0
22.2 11110821.620.0µg/LIsopropylbenzene 70-130 2.7 20.0
22.2 11111122.220.0µg/L4-Isopropyl toluene 70-130 0.0 20.0
16.9 84.579.515.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.0 20.0
21.9 11010821.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.8 20.0
16.4 82.078.515.720.0µg/L4-Methyl-2-Pentanone 60-140 4.3 20.0
16.8 84.082.016.420.0µg/LMethylene Chloride 70-130 2.4 20.0
22.3 11211823.620.0µg/LNaphthalene 70-130 5.6 20.0
19.9 99.599.519.920.0µg/Ln-Propylbenzene 70-130 0.0 20.0
22.5 11310821.620.0µg/LStyrene 70-130 4.0 20.0
24.6 12311322.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 8.4 20.0
17.5 87.583.516.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.6 20.0
23.5 11811923.720.0µg/LTetrachloroethene 70-130 0.8 20.0
Page 5 of 30Date:09/29/2023 08:35 AM
Page 75 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38377
LCS-V38377 LCSD-V38377Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310120.220.0µg/LToluene 70-130 1.9 20.0
24.8 124143*28.520.0µg/L1,2,3-Trichlorobenzene 70-130 13.8 20.0
26.2 131*12825.620.0µg/L1,2,4-Trichlorobenzene 70-130 2.3 20.0
24.2 12112024.020.0µg/L1,1,1-Trichloroethane 70-130 0.8 20.0
20.8 10497.519.520.0µg/L1,1,2-Trichloroethane 70-130 6.4 20.0
23.1 11611222.420.0µg/LTrichloroethene 70-130 3.0 20.0
24.0 12012424.720.0µg/LTrichlorofluoromethane 60-140 2.8 20.0
20.7 10410220.320.0µg/L1,2,3-Trichloropropane 70-130 1.9 20.0
21.8 10910821.520.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0
21.4 10710721.420.0µg/L1,3,5-Trimethylbenzene 70-130 0.0 20.0
19.8 99.078.515.720.0µg/LVinyl Acetate 60-140 23.0*20.0
13.3 66.567.513.520.0µg/LVinyl Chloride 60-140 1.4 20.0
21.1 10610420.720.0µg/Lo-Xylene 70-130 1.9 20.0
45.5 11411144.540.0µg/Lm,p-Xylene 70-130 2.2 20.0
91.090.04-Bromofluorobenzene (S)70-130
106101Dibromofluoromethane (S)70-130
1081091,2-Dichloroethane - d4 (S)70-130
99.4100Toluene-d8 (S)70-130
Page 6 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 76 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
Associated Lab Samples: 95678
LRB-V38414 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 16:5910.01.80<1.80µg/LAcetone
09/26/23 16:590.5000.180<0.180µg/LBenzene
09/26/23 16:590.5000.210<0.210µg/LBromobenzene
09/26/23 16:591.000.420<0.420µg/LBromochloromethane
09/26/23 16:590.5000.160<0.160µg/LBromodichloromethane
09/26/23 16:595.001.50<1.50µg/LBromoform
09/26/23 16:591.000.280<0.280µg/LBromomethane
09/26/23 16:590.5000.180<0.180µg/Ln-Butylbenzene
09/26/23 16:590.5000.200<0.200µg/Lsec-Butyl benzene
09/26/23 16:592.000.920<0.920µg/Ltert-Butyl benzene
09/26/23 16:590.5000.180<0.180µg/LCarbon Tetrachloride
09/26/23 16:590.5000.190<0.190µg/LChlorobenzene
09/26/23 16:590.5000.190<0.190µg/LChlorodibromomethane
09/26/23 16:591.000.430<0.430µg/LChloroethane
09/26/23 16:590.5000.220<0.220µg/LChloroform
09/26/23 16:590.5000.220<0.220µg/LChloromethane
09/26/23 16:590.5000.200<0.200µg/L2-Chlorotoluene
09/26/23 16:590.5000.200<0.200µg/L4-Chlorotoluene
09/26/23 16:590.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/26/23 16:592.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/26/23 16:590.5000.200<0.200µg/L1,2-Dibromoethane
09/26/23 16:590.5000.230<0.230µg/LDibromomethane
09/26/23 16:590.5000.220<0.220µg/L1,2-Dichlorobenzene
09/26/23 16:590.5000.190<0.190µg/L1,3-Dichlorobenzene
09/26/23 16:590.5000.210<0.210µg/L1,4-Dichlorobenzene
09/26/23 16:595.001.20<1.20µg/LDichlorodifluoromethane
09/26/23 16:590.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 30Date:09/29/2023 08:35 AM
Page 77 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
Associated Lab Samples: 95678
LRB-V38414 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 16:590.5000.150<0.150µg/L1,2-Dichloroethane
09/26/23 16:590.5000.150<0.150µg/L1,1-Dichloroethene
09/26/23 16:590.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/26/23 16:590.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/26/23 16:590.5000.190<0.190µg/L1,2-Dichloropropane
09/26/23 16:590.5000.130<0.130µg/L1,3-Dichloropropane
09/26/23 16:592.000.210<0.210µg/L2,2-Dichloropropane
09/26/23 16:590.5000.200<0.200µg/L1,1-Dichloropropene
09/26/23 16:590.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/26/23 16:590.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/26/23 16:5920042.0<42.0µg/LEthanol
09/26/23 16:590.5000.170<0.170µg/LEthylbenzene
09/26/23 16:593.000.350<0.350µg/LHexachlorobutadiene
09/26/23 16:591.000.380<0.380µg/L2-Hexanone
09/26/23 16:590.5000.180<0.180µg/LIsopropylbenzene
09/26/23 16:590.5000.089<0.089µg/L4-Isopropyl toluene
09/26/23 16:595.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/26/23 16:591.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/26/23 16:591.000.078<0.078µg/L4-Methyl-2-Pentanone
09/26/23 16:592.000.330<0.330µg/LMethylene Chloride
09/26/23 16:591.000.470<0.470µg/LNaphthalene
09/26/23 16:590.5000.190<0.190µg/Ln-Propylbenzene
09/26/23 16:590.5000.220<0.220µg/LStyrene
09/26/23 16:590.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/26/23 16:590.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/26/23 16:590.5000.220<0.220µg/LTetrachloroethene
09/26/23 16:590.5000.220<0.220µg/LToluene
Page 8 of 30Date:09/29/2023 08:35 AM
Page 78 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
Associated Lab Samples: 95678
LRB-V38414 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 16:590.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/26/23 16:590.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/26/23 16:590.5000.160<0.160µg/L1,1,1-Trichloroethane
09/26/23 16:590.5000.096<0.096µg/L1,1,2-Trichloroethane
09/26/23 16:590.5000.180<0.180µg/LTrichloroethene
09/26/23 16:590.5000.180<0.180µg/LTrichlorofluoromethane
09/26/23 16:590.5000.270<0.270µg/L1,2,3-Trichloropropane
09/26/23 16:590.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/26/23 16:590.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/26/23 16:595.001.00<1.00µg/LVinyl Acetate
09/26/23 16:590.5000.170<0.170µg/LVinyl Chloride
09/26/23 16:590.5000.210<0.210µg/Lo-Xylene
09/26/23 16:591.000.420<0.420µg/Lm,p-Xylene
09/26/23 16:594-Bromofluorobenzene (S)92.8 70-130
09/26/23 16:59Dibromofluoromethane (S)100 70-130
09/26/23 16:591,2-Dichloroethane - d4 (S)106 70-130
09/26/23 16:59Toluene-d8 (S)98.4 70-130
LCS-V38414 LCSD-V38414Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.0 10011345.140.0µg/LAcetone 40-160 11.9 20.0
18.8 94.096.519.320.0µg/LBenzene 70-130 2.6 20.0
20.1 10199.519.920.0µg/LBromobenzene 70-130 1.0 20.0
21.1 10611422.820.0µg/LBromochloromethane 70-130 7.7 20.0
20.8 10411222.420.0µg/LBromodichloromethane 70-130 7.4 20.0
Page 9 of 30Date:09/29/2023 08:35 AM
Page 79 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
LCS-V38414 LCSD-V38414Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.5 11812725.320.0µg/LBromoform 70-130 7.3 20.0
18.2 91.099.519.920.0µg/LBromomethane 60-140 8.9 20.0
21.6 10810721.420.0µg/Ln-Butylbenzene 70-130 0.9 20.0
20.5 10310520.920.0µg/Lsec-Butyl benzene 70-130 1.9 20.0
21.5 10811021.920.0µg/Ltert-Butyl benzene 70-130 1.8 20.0
26.6 133*139*27.820.0µg/LCarbon Tetrachloride 70-130 4.4 20.0
21.3 10711222.420.0µg/LChlorobenzene 70-130 5.0 20.0
22.4 11212124.120.0µg/LChlorodibromomethane 70-130 7.3 20.0
13.1 65.565.513.120.0µg/LChloroethane 60-140 0.0 20.0
20.7 10411122.120.0µg/LChloroform 70-130 6.5 20.0
10.7 53.5*58.0*11.620.0µg/LChloromethane 60-140 8.0 20.0
19.9 99.598.519.720.0µg/L2-Chlorotoluene 70-130 1.0 20.0
20.1 10110320.520.0µg/L4-Chlorotoluene 70-130 1.9 20.0
14.7 73.578.515.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 6.5 20.0
24.3 12212024.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.2 20.0
19.6 98.010520.920.0µg/L1,2-Dibromoethane 70-130 6.4 20.0
21.0 10511322.520.0µg/LDibromomethane 70-130 6.8 20.0
21.9 11011623.120.0µg/L1,2-Dichlorobenzene 70-130 5.3 20.0
22.2 11111623.120.0µg/L1,3-Dichlorobenzene 70-130 3.9 20.0
21.5 10810921.820.0µg/L1,4-Dichlorobenzene 70-130 1.3 20.0
11.9 59.5*59.0*11.820.0µg/LDichlorodifluoromethane 60-140 0.8 20.0
18.0 90.096.519.320.0µg/L1,1-Dichloroethane 70-130 6.9 20.0
22.0 11011823.520.0µg/L1,2-Dichloroethane 70-130 6.5 20.0
20.4 10210420.720.0µg/L1,1-Dichloroethene 70-130 1.4 20.0
19.5 97.599.519.920.0µg/Lcis-1,2-Dichloroethene 70-130 2.0 20.0
18.4 92.010120.120.0µg/Ltrans-1,2-Dichloroethene 70-130 8.8 20.0
Page 10 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 80 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
LCS-V38414 LCSD-V38414Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
15.5 77.584.016.820.0µg/L1,2-Dichloropropane 70-130 8.0 20.0
18.9 94.596.519.320.0µg/L1,3-Dichloropropane 70-130 2.0 20.0
24.3 122135*26.920.0µg/L2,2-Dichloropropane 70-130 10.1 20.0
21.1 10611623.220.0µg/L1,1-Dichloropropene 70-130 9.4 20.0
19.2 96.010120.120.0µg/Lcis-1,3-Dichloropropene 70-130 4.5 20.0
20.6 10311222.420.0µg/Ltrans-1,3-Dichloropropene 70-130 8.3 20.0
316 63.270.4352500µg/LEthanol 60-140 10.7 20.0
19.9 99.510220.420.0µg/LEthylbenzene 70-130 2.4 20.0
27.0 135*132*26.320.0µg/LHexachlorobutadiene 70-130 2.6 20.0
17.0 85.099.519.920.0µg/L2-Hexanone 60-140 15.7 20.0
21.9 11011122.120.0µg/LIsopropylbenzene 70-130 0.9 20.0
22.8 11411723.420.0µg/L4-Isopropyl toluene 70-130 2.5 20.0
16.0 80.085.517.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.6 20.0
20.5 10310921.720.0µg/LMethyl tert-butyl ether (MTBE)70-130 5.6 20.0
15.2 76.086.017.220.0µg/L4-Methyl-2-Pentanone 60-140 12.3 20.0
14.9 74.578.515.720.0µg/LMethylene Chloride 70-130 5.2 20.0
22.2 11112625.220.0µg/LNaphthalene 70-130 12.6 20.0
20.0 10010320.520.0µg/Ln-Propylbenzene 70-130 2.4 20.0
21.5 10810921.820.0µg/LStyrene 70-130 1.3 20.0
22.3 11211823.520.0µg/L1,1,1,2-Tetrachloroethane 70-130 5.2 20.0
16.9 84.594.018.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 10.6 20.0
23.2 11612023.920.0µg/LTetrachloroethene 70-130 2.9 20.0
19.4 97.010220.420.0µg/LToluene 70-130 5.0 20.0
27.0 135*158*31.620.0µg/L1,2,3-Trichlorobenzene 70-130 15.6 20.0
26.8 134*142*28.320.0µg/L1,2,4-Trichlorobenzene 70-130 5.4 20.0
24.4 12212525.020.0µg/L1,1,1-Trichloroethane 70-130 2.4 20.0
Page 11 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 81 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38416QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38414
LCS-V38414 LCSD-V38414Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.2 96.010120.120.0µg/L1,1,2-Trichloroethane 70-130 4.5 20.0
21.9 11011222.320.0µg/LTrichloroethene 70-130 1.8 20.0
24.5 12312424.820.0µg/LTrichlorofluoromethane 60-140 1.2 20.0
18.6 93.099.019.820.0µg/L1,2,3-Trichloropropane 70-130 6.2 20.0
22.2 11111322.520.0µg/L1,2,4-Trimethylbenzene 70-130 1.3 20.0
21.5 10811022.020.0µg/L1,3,5-Trimethylbenzene 70-130 2.2 20.0
22.9 11513226.420.0µg/LVinyl Acetate 60-140 14.1 20.0
11.7 58.5*60.512.120.0µg/LVinyl Chloride 60-140 3.3 20.0
20.7 10410721.420.0µg/Lo-Xylene 70-130 3.3 20.0
44.7 11211445.740.0µg/Lm,p-Xylene 70-130 2.2 20.0
91.891.44-Bromofluorobenzene (S)70-130
103102Dibromofluoromethane (S)70-130
1101101,2-Dichloroethane - d4 (S)70-130
97.697.8Toluene-d8 (S)70-130
Page 12 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 82 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95675
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/27/23 13:3010.01.80<1.80µg/LAcetone
09/27/23 13:300.5000.180<0.180µg/LBenzene
09/27/23 13:300.5000.210<0.210µg/LBromobenzene
09/27/23 13:301.000.420<0.420µg/LBromochloromethane
09/27/23 13:300.5000.160<0.160µg/LBromodichloromethane
09/27/23 13:305.001.50<1.50µg/LBromoform
09/27/23 13:301.000.280<0.280µg/LBromomethane
09/27/23 13:300.5000.180<0.180µg/Ln-Butylbenzene
09/27/23 13:300.5000.200<0.200µg/Lsec-Butyl benzene
09/27/23 13:302.000.920<0.920µg/Ltert-Butyl benzene
09/27/23 13:300.5000.180<0.180µg/LCarbon Tetrachloride
09/27/23 13:300.5000.190<0.190µg/LChlorobenzene
09/27/23 13:300.5000.190<0.190µg/LChlorodibromomethane
09/27/23 13:301.000.430<0.430µg/LChloroethane
09/27/23 13:300.5000.220<0.220µg/LChloroform
09/27/23 13:300.5000.220<0.220µg/LChloromethane
09/27/23 13:300.5000.200<0.200µg/L2-Chlorotoluene
09/27/23 13:300.5000.200<0.200µg/L4-Chlorotoluene
09/27/23 13:300.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/27/23 13:302.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/27/23 13:300.5000.200<0.200µg/L1,2-Dibromoethane
09/27/23 13:300.5000.230<0.230µg/LDibromomethane
09/27/23 13:300.5000.220<0.220µg/L1,2-Dichlorobenzene
09/27/23 13:300.5000.190<0.190µg/L1,3-Dichlorobenzene
09/27/23 13:300.5000.210<0.210µg/L1,4-Dichlorobenzene
09/27/23 13:305.001.20<1.20µg/LDichlorodifluoromethane
09/27/23 13:300.5000.240<0.240µg/L1,1-Dichloroethane
Page 13 of 30Date:09/29/2023 08:35 AM
Page 83 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95675
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/27/23 13:300.5000.150<0.150µg/L1,2-Dichloroethane
09/27/23 13:300.5000.150<0.150µg/L1,1-Dichloroethene
09/27/23 13:300.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/27/23 13:300.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/27/23 13:300.5000.190<0.190µg/L1,2-Dichloropropane
09/27/23 13:300.5000.130<0.130µg/L1,3-Dichloropropane
09/27/23 13:302.000.210<0.210µg/L2,2-Dichloropropane
09/27/23 13:300.5000.200<0.200µg/L1,1-Dichloropropene
09/27/23 13:300.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/27/23 13:300.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/27/23 13:3020042.0<42.0µg/LEthanol
09/27/23 13:300.5000.170<0.170µg/LEthylbenzene
09/27/23 13:303.000.350<0.350µg/LHexachlorobutadiene
09/27/23 13:301.000.380<0.380µg/L2-Hexanone
09/27/23 13:300.5000.180<0.180µg/LIsopropylbenzene
09/27/23 13:300.5000.089<0.089µg/L4-Isopropyl toluene
09/27/23 13:305.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/27/23 13:301.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/27/23 13:301.000.078<0.078µg/L4-Methyl-2-Pentanone
09/27/23 13:302.000.330<0.330µg/LMethylene Chloride
09/27/23 13:301.000.470<0.470µg/LNaphthalene
09/27/23 13:300.5000.190<0.190µg/Ln-Propylbenzene
09/27/23 13:300.5000.220<0.220µg/LStyrene
09/27/23 13:300.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/27/23 13:300.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/27/23 13:300.5000.220<0.220µg/LTetrachloroethene
09/27/23 13:300.5000.220<0.220µg/LToluene
Page 14 of 30Date:09/29/2023 08:35 AM
Page 84 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
Associated Lab Samples: 95675
LRB-V38455 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/27/23 13:300.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/27/23 13:300.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/27/23 13:300.5000.160<0.160µg/L1,1,1-Trichloroethane
09/27/23 13:300.5000.096<0.096µg/L1,1,2-Trichloroethane
09/27/23 13:300.5000.180<0.180µg/LTrichloroethene
09/27/23 13:300.5000.180<0.180µg/LTrichlorofluoromethane
09/27/23 13:300.5000.270<0.270µg/L1,2,3-Trichloropropane
09/27/23 13:300.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/27/23 13:300.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/27/23 13:305.001.00<1.00µg/LVinyl Acetate
09/27/23 13:300.5000.170<0.170µg/LVinyl Chloride
09/27/23 13:300.5000.210<0.210µg/Lo-Xylene
09/27/23 13:301.000.420<0.420µg/Lm,p-Xylene
09/27/23 13:304-Bromofluorobenzene (S)91.0 70-130
09/27/23 13:30Dibromofluoromethane (S)101 70-130
09/27/23 13:301,2-Dichloroethane - d4 (S)110 70-130
09/27/23 13:30Toluene-d8 (S)96.8 70-130
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.5 10110642.340.0µg/LAcetone 40-160 4.3 20.0
19.3 96.598.019.620.0µg/LBenzene 70-130 1.5 20.0
20.8 10410420.820.0µg/LBromobenzene 70-130 0.0 20.0
21.7 10910621.220.0µg/LBromochloromethane 70-130 2.3 20.0
21.2 10610821.620.0µg/LBromodichloromethane 70-130 1.8 20.0
Page 15 of 30Date:09/29/2023 08:35 AM
Page 85 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.8 11411823.620.0µg/LBromoform 70-130 3.4 20.0
19.3 96.593.518.720.0µg/LBromomethane 60-140 3.1 20.0
21.9 11011122.120.0µg/Ln-Butylbenzene 70-130 0.9 20.0
21.0 10510921.720.0µg/Lsec-Butyl benzene 70-130 3.2 20.0
21.6 10811022.020.0µg/Ltert-Butyl benzene 70-130 1.8 20.0
26.7 134*132*26.420.0µg/LCarbon Tetrachloride 70-130 1.1 20.0
22.3 11210821.520.0µg/LChlorobenzene 70-130 3.6 20.0
23.5 11812024.020.0µg/LChlorodibromomethane 70-130 2.1 20.0
14.5 72.567.513.520.0µg/LChloroethane 60-140 7.1 20.0
21.0 10510921.720.0µg/LChloroform 70-130 3.2 20.0
11.4 57.0*57.0*11.420.0µg/LChloromethane 60-140 0.0 20.0
19.9 99.510220.420.0µg/L2-Chlorotoluene 70-130 2.4 20.0
20.4 10210521.020.0µg/L4-Chlorotoluene 70-130 2.8 20.0
15.2 76.077.515.520.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.9 20.0
21.6 10811923.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 9.6 20.0
18.7 93.597.519.520.0µg/L1,2-Dibromoethane 70-130 4.1 20.0
20.5 10310821.520.0µg/LDibromomethane 70-130 4.7 20.0
22.0 11011222.420.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
22.1 11111623.120.0µg/L1,3-Dichlorobenzene 70-130 4.4 20.0
22.0 11011022.020.0µg/L1,4-Dichlorobenzene 70-130 0.0 20.0
10.9 54.5*52.5*10.520.0µg/LDichlorodifluoromethane 60-140 3.7 20.0
19.4 97.096.519.320.0µg/L1,1-Dichloroethane 70-130 0.5 20.0
21.8 10911021.920.0µg/L1,2-Dichloroethane 70-130 0.4 20.0
20.3 10210520.920.0µg/L1,1-Dichloroethene 70-130 2.9 20.0
18.9 94.598.519.720.0µg/Lcis-1,2-Dichloroethene 70-130 4.1 20.0
19.8 99.010220.320.0µg/Ltrans-1,2-Dichloroethene 70-130 2.4 20.0
Page 16 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 86 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
15.8 79.084.016.820.0µg/L1,2-Dichloropropane 70-130 6.1 20.0
18.7 93.596.519.320.0µg/L1,3-Dichloropropane 70-130 3.1 20.0
24.7 12412124.220.0µg/L2,2-Dichloropropane 70-130 2.0 20.0
22.2 11111322.520.0µg/L1,1-Dichloropropene 70-130 1.3 20.0
19.8 99.010120.220.0µg/Lcis-1,3-Dichloropropene 70-130 2.0 20.0
21.2 10610721.420.0µg/Ltrans-1,3-Dichloropropene 70-130 0.9 20.0
366 73.283.6418500µg/LEthanol 60-140 13.2 20.0
20.7 10410520.920.0µg/LEthylbenzene 70-130 0.9 20.0
26.7 134*13026.020.0µg/LHexachlorobutadiene 70-130 2.6 20.0
19.2 96.089.517.920.0µg/L2-Hexanone 60-140 7.0 20.0
22.6 11311322.620.0µg/LIsopropylbenzene 70-130 0.0 20.0
23.2 11611723.320.0µg/L4-Isopropyl toluene 70-130 0.4 20.0
16.9 84.590.018.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.3 20.0
19.8 99.010721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 7.7 20.0
15.9 79.580.516.120.0µg/L4-Methyl-2-Pentanone 60-140 1.2 20.0
15.3 76.583.016.620.0µg/LMethylene Chloride 70-130 8.1 20.0
22.8 11411522.920.0µg/LNaphthalene 70-130 0.4 20.0
20.8 10410420.820.0µg/Ln-Propylbenzene 70-130 0.0 20.0
21.9 11011222.420.0µg/LStyrene 70-130 2.2 20.0
23.9 12011322.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 5.5 20.0
17.9 89.592.518.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.2 20.0
24.0 12011422.820.0µg/LTetrachloroethene 70-130 5.1 20.0
19.6 98.010220.420.0µg/LToluene 70-130 4.0 20.0
29.8 149*135*27.020.0µg/L1,2,3-Trichlorobenzene 70-130 9.8 20.0
26.7 134*132*26.320.0µg/L1,2,4-Trichlorobenzene 70-130 1.5 20.0
23.2 11612224.320.0µg/L1,1,1-Trichloroethane 70-130 4.6 20.0
Page 17 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 87 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38456QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38455
LCS-V38455 LCSD-V38455Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.6 98.098.019.620.0µg/L1,1,2-Trichloroethane 70-130 0.0 20.0
21.5 10810520.920.0µg/LTrichloroethene 70-130 2.8 20.0
23.3 11711823.620.0µg/LTrichlorofluoromethane 60-140 1.2 20.0
20.4 10210621.120.0µg/L1,2,3-Trichloropropane 70-130 3.3 20.0
22.3 11211222.420.0µg/L1,2,4-Trimethylbenzene 70-130 0.4 20.0
22.3 11211523.020.0µg/L1,3,5-Trimethylbenzene 70-130 3.0 20.0
23.9 12014028.020.0µg/LVinyl Acetate 60-140 15.7 20.0
12.5 62.560.512.120.0µg/LVinyl Chloride 60-140 3.2 20.0
21.1 10610521.020.0µg/Lo-Xylene 70-130 0.4 20.0
46.0 11511345.040.0µg/Lm,p-Xylene 70-130 2.1 20.0
92.892.24-Bromofluorobenzene (S)70-130
97.699.2Dibromofluoromethane (S)70-130
1041091,2-Dichloroethane - d4 (S)70-130
98.898.0Toluene-d8 (S)70-130
Page 18 of 30Date:09/29/2023 08:35 AM
Page 88 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
Associated Lab Samples: 95676, 95677, 95678, 95679
LRB-V38276 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 15:422.000.302<0.302µg/LAcenaphthene
09/26/23 15:422.000.297<0.297µg/LAcenaphthylene
09/26/23 15:422.000.836<0.836µg/LAnthracene
09/26/23 15:4210.01.32<1.32µg/LBenzidine
09/26/23 15:422.000.637<0.637µg/LBenzo(a)anthracene
09/26/23 15:422.001.02<1.02µg/LBenzo(a)pyrene
09/26/23 15:425.002.49<2.49µg/LBenzo(b)fluoranthene
09/26/23 15:425.001.01<1.01µg/LBenzo(g,h,i)perylene
09/26/23 15:425.001.99<1.99µg/LBenzo(k)fluoranthene
09/26/23 15:4210.01.10<1.10µg/LBenzoic Acid
09/26/23 15:425.000.684<0.684µg/LBenzyl alcohol
09/26/23 15:425.000.468<0.468µg/LBis(2-Chloroethoxy)methane
09/26/23 15:425.001.04<1.04µg/LBis(2-Chloroethyl)ether
09/26/23 15:425.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
09/26/23 15:4210.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
09/26/23 15:425.001.11<1.11µg/L4-Bromophenyl phenyl ether
09/26/23 15:425.001.83<1.83µg/LButyl benzyl phthalate
09/26/23 15:425.001.18<1.18µg/L4-Chloro-3-methylphenol
09/26/23 15:4220.07.38<7.38µg/L2-Chloronaphthalene
09/26/23 15:4210.00.938<0.938µg/L2-Chlorophenol
09/26/23 15:425.001.71<1.71µg/L4-Chlorophenyl phenyl ether
09/26/23 15:422.000.405<0.405µg/LChrysene
09/26/23 15:422.000.434<0.434µg/LDibenz(a,h)anthracene
09/26/23 15:425.000.856<0.856µg/LDibenzofuran
09/26/23 15:425.002.00<2.00µg/L1,2-Dichlorobenzene
09/26/23 15:425.002.00<2.00µg/L1,3-Dichlorobenzene
09/26/23 15:425.002.05<2.05µg/L1,4-Dichlorobenzene
Page 19 of 30Date:09/29/2023 08:35 AM
Page 89 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
Associated Lab Samples: 95676, 95677, 95678, 95679
LRB-V38276 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 15:425.001.89<1.89µg/L3,3'-Dichlorobenzidine
09/26/23 15:4210.01.46<1.46µg/L2,4-Dichlorophenol
09/26/23 15:425.000.745<0.745µg/LDiethyl phthalate
09/26/23 15:425.000.939<0.939µg/LDimethyl phthalate
09/26/23 15:4220.01.57<1.57µg/L2,4-Dimethylphenol
09/26/23 15:425.002.06<2.06µg/LDi-n-butyl phthalate
09/26/23 15:4210.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
09/26/23 15:4210.01.92<1.92µg/L2,4-Dinitrophenol
09/26/23 15:425.001.11<1.11µg/L2,4-Dinitrotoluene
09/26/23 15:425.000.809<0.809µg/L2,6-Dinitrotoluene
09/26/23 15:425.001.65<1.65µg/LDi-n-Octyl Phthalate
09/26/23 15:422.000.250<0.250µg/LFluoranthene
09/26/23 15:422.000.807<0.807µg/LFluorene
09/26/23 15:425.000.979<0.979µg/LHexachlorobenzene
09/26/23 15:425.002.73<2.73µg/LHexachlorobutadiene
09/26/23 15:425.002.05<2.05µg/LHexachlorocyclopentadiene
09/26/23 15:425.001.76<1.76µg/LHexachloroethane
09/26/23 15:422.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
09/26/23 15:425.000.444<0.444µg/LIsophorone
09/26/23 15:422.001.14<1.14µg/L1-Methylnaphthalene
09/26/23 15:422.000.666<0.666µg/L2-Methylnaphthalene
09/26/23 15:422.000.728<0.728µg/LNaphthalene
09/26/23 15:425.000.905<0.905µg/LNitrobenzene
09/26/23 15:425.000.493<0.493µg/L2-Nitrophenol
09/26/23 15:4210.01.23<1.23µg/L4-Nitrophenol
09/26/23 15:425.001.10<1.10µg/LN-Nitrosodiphenylamine
09/26/23 15:425.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 20 of 30Date:09/29/2023 08:35 AM
Page 90 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
Associated Lab Samples: 95676, 95677, 95678, 95679
LRB-V38276 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 15:425.001.43<1.43µg/LPentachlorophenol
09/26/23 15:422.000.428<0.428µg/LPhenanthrene
09/26/23 15:425.000.651<0.651µg/LPhenol
09/26/23 15:422.000.434<0.434µg/LPyrene
09/26/23 15:425.002.21<2.21µg/L1,2,4-Trichlorobenzene
09/26/23 15:425.001.32<1.32µg/L2,4,6-Trichlorophenol
09/26/23 15:422-Fluorobiphenyl (S)70.2 49-118
09/26/23 15:422-Fluorophenol (S)37.3 22-84
09/26/23 15:42Nitrobenzene-d5 (S)66.4 43-123
09/26/23 15:424-Terphenyl-d14 (S)84.8 49-151
09/26/23 15:422,4,6-Tribromophenol (S)68.3 31-144
09/26/23 15:42Phenol-d5 (S)24.1 10-63
LCS-V38276 LCSD-V38276Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.4 64.866.233.150.0µg/LAcenaphthene 47-145 2.1 20.0
33.6 67.268.834.450.0µg/LAcenaphthylene 33-145 2.3 20.0
41.3 82.682.641.350.0µg/LAnthracene 27-133 0.0 20.0
15.3 30.614.2*7.1250.0µg/LBenzidine 15-150 72.9*20.0
40.6 81.280.440.250.0µg/LBenzo(a)anthracene 33-143 0.9 20.0
44.7 89.489.844.950.0µg/LBenzo(a)pyrene 17-163 0.4 20.0
42.8 85.686.243.150.0µg/LBenzo(b)fluoranthene 24-159 0.6 20.0
38.7 77.477.438.750.0µg/LBenzo(g,h,i)perylene 10-219 0.0 20.0
41.0 82.082.441.250.0µg/LBenzo(k)fluoranthene 11-162 0.4 20.0
15.2 30.428.214.150.0µg/LBenzoic Acid 10-125 7.5 20.0
Page 21 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 91 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
LCS-V38276 LCSD-V38276Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.8 63.661.230.650.0µg/LBenzyl alcohol 16-107 3.8 20.0
33.1 66.264.032.050.0µg/LBis(2-Chloroethoxy)methane 33-184 3.3 20.0
31.8 63.664.032.050.0µg/LBis(2-Chloroethyl)ether 12-158 0.6 20.0
31.0 62.064.032.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 3.1 20.0
41.0 82.081.840.950.0µg/LBis(2-ethylhexyl)phthalate 10-158 0.2 20.0
37.6 75.275.237.650.0µg/L4-Bromophenyl phenyl ether 53-127 0.0 20.0
42.1 84.282.841.450.0µg/LButyl benzyl phthalate 10-152 1.6 20.0
33.1 66.264.032.050.0µg/L4-Chloro-3-methylphenol 22-147 3.3 20.0
31.8 63.664.832.450.0µg/L2-Chloronaphthalene 60-118 1.8 20.0
31.1 62.261.430.750.0µg/L2-Chlorophenol 23-134 1.2 20.0
35.2 70.472.236.150.0µg/L4-Chlorophenyl phenyl ether 25-158 2.5 20.0
40.9 81.881.840.950.0µg/LChrysene 17-168 0.0 20.0
29.7 59.461.430.750.0µg/LDibenz(a,h)anthracene 10-227 3.3 20.0
33.7 67.469.234.650.0µg/LDibenzofuran 39-114 2.6 20.0
24.4 48.850.225.150.0µg/L1,2-Dichlorobenzene 32-129 2.8 20.0
23.4 46.847.423.750.0µg/L1,3-Dichlorobenzene 20-124 1.2 20.0
23.8 47.647.823.950.0µg/L1,4-Dichlorobenzene 20-124 0.4 20.0
41.7 83.481.840.950.0µg/L3,3'-Dichlorobenzidine 10-262 1.9 20.0
35.1 70.268.634.350.0µg/L2,4-Dichlorophenol 39-135 2.3 20.0
39.8 79.680.440.250.0µg/LDiethyl phthalate 10-114 1.0 20.0
40.0 80.081.040.550.0µg/LDimethyl phthalate 10-112 1.2 20.0
42.3 84.676.838.450.0µg/L2,4-Dimethylphenol 32-119 9.6 20.0
44.6 89.289.844.950.0µg/LDi-n-butyl phthalate 10-118 0.6 20.0
43.6 87.285.442.750.0µg/L4,6-Dinitro-2-methylphenol 10-181 2.0 20.0
40.6 81.275.637.850.0µg/L2,4-Dinitrophenol 10-191 7.1 20.0
40.1 80.281.040.550.0µg/L2,4-Dinitrotoluene 39-139 0.9 20.0
Page 22 of 30Date:09/29/2023 08:35 AM
Page 92 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
LCS-V38276 LCSD-V38276Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.0 80.081.040.550.0µg/L2,6-Dinitrotoluene 50-158 1.2 20.0
43.1 86.285.842.950.0µg/LDi-n-Octyl Phthalate 10-146 0.4 20.0
38.7 77.477.438.750.0µg/LFluoranthene 26-137 0.0 20.0
36.1 72.273.636.850.0µg/LFluorene 59-121 1.9 20.0
38.8 77.678.239.150.0µg/LHexachlorobenzene 10-152 0.7 20.0
22.7 45.446.023.050.0µg/LHexachlorobutadiene 24-116 1.3 20.0
26.4 52.853.226.650.0µg/LHexachlorocyclopentadiene 32-117 0.7 20.0
21.9 43.845.022.550.0µg/LHexachloroethane 40-113 2.7 20.0
38.6 77.278.639.350.0µg/LIndeno(1,2,3-cd)pyrene 10-171 1.7 20.0
30.8 61.660.430.250.0µg/LIsophorone 21-196 1.9 20.0
25.4 50.850.825.450.0µg/L1-Methylnaphthalene 40-135 0.0 20.0
25.2 50.450.625.350.0µg/L2-Methylnaphthalene 18-121 0.3 20.0
25.4 50.850.425.250.0µg/LNaphthalene 21-133 0.7 20.0
27.8 55.654.227.150.0µg/LNitrobenzene 35-180 2.5 20.0
30.2 60.459.829.950.0µg/L2-Nitrophenol 29-182 0.9 20.0
18.1 36.236.618.350.0µg/L4-Nitrophenol 10-132 1.0 20.0
48.5 97.096.248.150.0µg/LN-Nitrosodiphenylamine 69-152 0.8 20.0
33.7 67.467.633.850.0µg/LN-Nitroso-di-n-propylamine 10-230 0.2 20.0
49.6 99.299.649.850.0µg/LPentachlorophenol 14-176 0.4 20.0
39.3 78.679.039.550.0µg/LPhenanthrene 54-120 0.5 20.0
14.8 29.628.614.350.0µg/LPhenol 10-112 3.4 20.0
40.1 80.280.240.150.0µg/LPyrene 52-115 0.0 20.0
23.1 46.246.023.050.0µg/L1,2,4-Trichlorobenzene 44-142 0.4 20.0
37.4 74.876.238.150.0µg/L2,4,6-Trichlorophenol 37-144 1.8 20.0
69.271.62-Fluorobiphenyl (S)49-118
33.633.92-Fluorophenol (S)22-84
Page 23 of 30Date:09/29/2023 08:35 AM
Page 93 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38276
LCS-V38276 LCSD-V38276Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
56.256.6Nitrobenzene-d5 (S)43-123
80.681.84-Terphenyl-d14 (S)49-151
71.274.52,4,6-Tribromophenol (S)31-144
22.322.3Phenol-d5 (S)10-63
Page 24 of 30Date:09/29/2023 08:35 AM
Page 94 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
Associated Lab Samples: 95675, 95680, 95681, 95682, 95683
LRB-V38350 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 18:512.000.302<0.302µg/LAcenaphthene
09/26/23 18:512.000.297<0.297µg/LAcenaphthylene
09/26/23 18:512.000.836<0.836µg/LAnthracene
09/26/23 18:5110.01.32<1.32µg/LBenzidine
09/26/23 18:512.000.637<0.637µg/LBenzo(a)anthracene
09/26/23 18:512.001.02<1.02µg/LBenzo(a)pyrene
09/26/23 18:515.002.49<2.49µg/LBenzo(b)fluoranthene
09/26/23 18:515.001.01<1.01µg/LBenzo(g,h,i)perylene
09/26/23 18:515.001.99<1.99µg/LBenzo(k)fluoranthene
09/26/23 18:5110.01.10<1.10µg/LBenzoic Acid
09/26/23 18:515.000.684<0.684µg/LBenzyl alcohol
09/26/23 18:515.000.468<0.468µg/LBis(2-Chloroethoxy)methane
09/26/23 18:515.001.04<1.04µg/LBis(2-Chloroethyl)ether
09/26/23 18:515.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
09/26/23 18:5110.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
09/26/23 18:515.001.11<1.11µg/L4-Bromophenyl phenyl ether
09/26/23 18:515.001.83<1.83µg/LButyl benzyl phthalate
09/26/23 18:515.001.18<1.18µg/L4-Chloro-3-methylphenol
09/26/23 18:5120.07.38<7.38µg/L2-Chloronaphthalene
09/26/23 18:5110.00.938<0.938µg/L2-Chlorophenol
09/26/23 18:515.001.71<1.71µg/L4-Chlorophenyl phenyl ether
09/26/23 18:512.000.405<0.405µg/LChrysene
09/26/23 18:512.000.434<0.434µg/LDibenz(a,h)anthracene
09/26/23 18:515.000.856<0.856µg/LDibenzofuran
09/26/23 18:515.002.00<2.00µg/L1,2-Dichlorobenzene
09/26/23 18:515.002.00<2.00µg/L1,3-Dichlorobenzene
09/26/23 18:515.002.05<2.05µg/L1,4-Dichlorobenzene
Page 25 of 30Date:09/29/2023 08:35 AM
Page 95 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
Associated Lab Samples: 95675, 95680, 95681, 95682, 95683
LRB-V38350 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 18:515.001.89<1.89µg/L3,3'-Dichlorobenzidine
09/26/23 18:5110.01.46<1.46µg/L2,4-Dichlorophenol
09/26/23 18:515.000.745<0.745µg/LDiethyl phthalate
09/26/23 18:515.000.939<0.939µg/LDimethyl phthalate
09/26/23 18:5120.01.57<1.57µg/L2,4-Dimethylphenol
09/26/23 18:515.002.06<2.06µg/LDi-n-butyl phthalate
09/26/23 18:5110.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
09/26/23 18:5110.01.92<1.92µg/L2,4-Dinitrophenol
09/26/23 18:515.001.11<1.11µg/L2,4-Dinitrotoluene
09/26/23 18:515.000.809<0.809µg/L2,6-Dinitrotoluene
09/26/23 18:515.001.65<1.65µg/LDi-n-Octyl Phthalate
09/26/23 18:512.000.250<0.250µg/LFluoranthene
09/26/23 18:512.000.807<0.807µg/LFluorene
09/26/23 18:515.000.979<0.979µg/LHexachlorobenzene
09/26/23 18:515.002.73<2.73µg/LHexachlorobutadiene
09/26/23 18:515.002.05<2.05µg/LHexachlorocyclopentadiene
09/26/23 18:515.001.76<1.76µg/LHexachloroethane
09/26/23 18:512.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
09/26/23 18:515.000.444<0.444µg/LIsophorone
09/26/23 18:512.001.14<1.14µg/L1-Methylnaphthalene
09/26/23 18:512.000.666<0.666µg/L2-Methylnaphthalene
09/26/23 18:512.000.728<0.728µg/LNaphthalene
09/26/23 18:515.000.905<0.905µg/LNitrobenzene
09/26/23 18:515.000.493<0.493µg/L2-Nitrophenol
09/26/23 18:5110.01.23<1.23µg/L4-Nitrophenol
09/26/23 18:515.001.10<1.10µg/LN-Nitrosodiphenylamine
09/26/23 18:515.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 26 of 30Date:09/29/2023 08:35 AM
Page 96 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
Associated Lab Samples: 95675, 95680, 95681, 95682, 95683
LRB-V38350 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/23 18:515.001.43<1.43µg/LPentachlorophenol
09/26/23 18:512.000.428<0.428µg/LPhenanthrene
09/26/23 18:515.000.651<0.651µg/LPhenol
09/26/23 18:512.000.434<0.434µg/LPyrene
09/26/23 18:515.002.21<2.21µg/L1,2,4-Trichlorobenzene
09/26/23 18:515.001.32<1.32µg/L2,4,6-Trichlorophenol
09/26/23 18:512-Fluorobiphenyl (S)70.8 49-118
09/26/23 18:512-Fluorophenol (S)48.5 22-84
09/26/23 18:51Nitrobenzene-d5 (S)67.6 43-123
09/26/23 18:514-Terphenyl-d14 (S)84.8 49-151
09/26/23 18:512,4,6-Tribromophenol (S)80.4 31-144
09/26/23 18:51Phenol-d5 (S)31.1 10-63
LCS-V38350 LCSD-V38350Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.1 72.272.036.050.0µg/LAcenaphthene 47-145 0.2 20.0
36.6 73.271.835.950.0µg/LAcenaphthylene 33-145 1.9 20.0
39.8 79.681.240.650.0µg/LAnthracene 27-133 1.9 20.0
4.36 8.7*12.7*6.3750.0µg/LBenzidine 15-150 37.4*20.0
38.9 77.879.639.850.0µg/LBenzo(a)anthracene 33-143 2.2 20.0
43.5 87.087.843.950.0µg/LBenzo(a)pyrene 17-163 0.9 20.0
38.0 76.077.638.850.0µg/LBenzo(b)fluoranthene 24-159 2.0 20.0
40.1 80.280.440.250.0µg/LBenzo(g,h,i)perylene 10-219 0.2 20.0
42.9 85.886.443.250.0µg/LBenzo(k)fluoranthene 11-162 0.6 20.0
16.2 32.433.816.950.0µg/LBenzoic Acid 10-125 4.2 20.0
Page 27 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 97 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
LCS-V38350 LCSD-V38350Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
35.0 70.071.235.650.0µg/LBenzyl alcohol 16-107 1.6 20.0
34.9 69.871.235.650.0µg/LBis(2-Chloroethoxy)methane 33-184 1.9 20.0
29.8 59.661.030.550.0µg/LBis(2-Chloroethyl)ether 12-158 2.3 20.0
31.3 62.664.032.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 2.2 20.0
42.9 85.884.642.350.0µg/LBis(2-ethylhexyl)phthalate 10-158 1.4 20.0
36.5 73.071.835.950.0µg/L4-Bromophenyl phenyl ether 53-127 1.6 20.0
43.1 86.287.443.750.0µg/LButyl benzyl phthalate 10-152 1.3 20.0
38.1 76.275.637.850.0µg/L4-Chloro-3-methylphenol 22-147 0.7 20.0
36.7 73.473.636.850.0µg/L2-Chloronaphthalene 60-118 0.2 20.0
32.1 64.265.632.850.0µg/L2-Chlorophenol 23-134 2.1 20.0
36.4 72.871.835.950.0µg/L4-Chlorophenyl phenyl ether 25-158 1.3 20.0
39.7 79.480.640.350.0µg/LChrysene 17-168 1.5 20.0
31.9 63.877.038.550.0µg/LDibenz(a,h)anthracene 10-227 18.7 20.0
38.5 77.075.637.850.0µg/LDibenzofuran 39-114 1.8 20.0
26.8 53.655.827.950.0µg/L1,2-Dichlorobenzene 32-129 4.0 20.0
25.8 51.654.427.250.0µg/L1,3-Dichlorobenzene 20-124 5.2 20.0
24.8 49.651.825.950.0µg/L1,4-Dichlorobenzene 20-124 4.3 20.0
33.7 67.470.835.450.0µg/L3,3'-Dichlorobenzidine 10-262 4.9 20.0
36.4 72.874.437.250.0µg/L2,4-Dichlorophenol 39-135 2.1 20.0
40.4 80.880.240.150.0µg/LDiethyl phthalate 10-114 0.7 20.0
41.0 82.079.439.750.0µg/LDimethyl phthalate 10-112 3.2 20.0
48.3 96.696.048.050.0µg/L2,4-Dimethylphenol 32-119 0.6 20.0
43.3 86.688.044.050.0µg/LDi-n-butyl phthalate 10-118 1.6 20.0
35.8 71.673.036.550.0µg/L4,6-Dinitro-2-methylphenol 10-181 1.9 20.0
37.8 75.672.836.450.0µg/L2,4-Dinitrophenol 10-191 3.7 20.0
43.3 86.683.241.650.0µg/L2,4-Dinitrotoluene 39-139 4.0 20.0
Page 28 of 30Date:09/29/2023 08:35 AM
Page 98 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
LCS-V38350 LCSD-V38350Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.9 87.884.842.450.0µg/L2,6-Dinitrotoluene 50-158 3.4 20.0
43.3 86.687.443.750.0µg/LDi-n-Octyl Phthalate 10-146 0.9 20.0
40.4 80.881.240.650.0µg/LFluoranthene 26-137 0.4 20.0
38.4 76.877.238.650.0µg/LFluorene 59-121 0.5 20.0
40.5 81.080.040.050.0µg/LHexachlorobenzene 10-152 1.2 20.0
30.6 61.263.031.550.0µg/LHexachlorobutadiene 24-116 2.8 20.0
21.0 42.044.422.250.0µg/LHexachlorocyclopentadiene 32-117 5.5 20.0
25.4 50.852.626.350.0µg/LHexachloroethane 40-113 3.4 20.0
38.8 77.677.238.650.0µg/LIndeno(1,2,3-cd)pyrene 10-171 0.5 20.0
33.7 67.467.633.850.0µg/LIsophorone 21-196 0.2 20.0
31.5 63.067.433.750.0µg/L1-Methylnaphthalene 40-135 6.7 20.0
31.4 62.866.433.250.0µg/L2-Methylnaphthalene 18-121 5.5 20.0
30.3 60.663.231.650.0µg/LNaphthalene 21-133 4.2 20.0
33.2 66.467.833.950.0µg/LNitrobenzene 35-180 2.0 20.0
33.3 66.668.834.450.0µg/L2-Nitrophenol 29-182 3.2 20.0
21.8 43.645.222.650.0µg/L4-Nitrophenol 10-132 3.6 20.0
46.1 92.293.646.850.0µg/LN-Nitrosodiphenylamine 69-152 1.5 20.0
36.3 72.673.236.650.0µg/LN-Nitroso-di-n-propylamine 10-230 0.8 20.0
39.8 79.686.643.350.0µg/LPentachlorophenol 14-176 8.4 20.0
39.8 79.680.240.150.0µg/LPhenanthrene 54-120 0.7 20.0
14.7 29.429.214.650.0µg/LPhenol 10-112 0.6 20.0
40.1 80.281.240.650.0µg/LPyrene 52-115 1.2 20.0
28.9 57.860.430.250.0µg/L1,2,4-Trichlorobenzene 44-142 4.3 20.0
37.7 75.474.237.150.0µg/L2,4,6-Trichlorophenol 37-144 1.6 20.0
142*71.42-Fluorobiphenyl (S)49-118
86.4*43.82-Fluorophenol (S)22-84
Page 29 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 99 of 102
Quality Control Data
23-263-0010Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V38372QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V38350
LCS-V38350 LCSD-V38350Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
124*63.6Nitrobenzene-d5 (S)43-123
151*75.44-Terphenyl-d14 (S)49-151
164*80.82,4,6-Tribromophenol (S)31-144
55.828.8Phenol-d5 (S)10-63
Page 30 of 30* QC Fail Date:09/29/2023 08:35 AM
Page 100 of 102
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-263-0010
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:09/20/2023 14:39:18
Special precautions or instructions included?
Comments:
Page 101 of 102
Page 102 of 102

Appendix B

Groundwater Sampling Forms

Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
15:30
Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
Stabilization Criteria
LOW-FLOW GROUNDWATER
SAMPLING RECORD
R PARAMETERS
Maintenance
DOT Robbinsville Maintenance Facility
DOT Robbinsville Maintenance Facility
DOT Robbinsville Maintenance Facility