AS-3030_28254_CA_MRP_20230606_SAR

Via Email

June 6, 2023

NC Department of Environmental Quality
Div. of Waste Management - Underground Storage Tanks
2090 U.S. 70 Highway
Swannanoa, NC 28778

Attention: Ms. Katie Bernal, PG

Re: Soil and Groundwater Assessment Report
NC DOT- Robbinsville Maintenance Facility
40 State Shed Road
Robbinsville, North Carolina
DEQ Incident No. 28254
H&H Job No. DOT-476

Dear Katie,

On behalf of the NC DOT, please find the attached Soil and Groundwater Assessment Report for
the NC DOT Maintenance Facility located at 40 State Shed Road in Robbinsville, Graham
County, North Carolina. If you have any questions, please do not hesitate to contact us.

Sincerely,

Hart & Hickman, PC
David Graham, PG Matt Bramblett, PE
Senior Project Geologist Principal

Attachment

Cc: Mr. Jeff Walston, NC DOT (via email)
Ms. Jennifer Parish, NC DOT (via email)
#C-1269 Engineering
#-245 Geology

Soil and Groundwater
Assessment Report

NC DOT Maintenance Facility
Robbinsville, North Carolina

NC DEQ Incident Number: 28254
H&H Job No. DOT-476
June 6, 2023

Assessment Report Information

Site Location:

NC DOT Maintenance Facility
40 State Shed Road
Robbinsville, North Carolina 28771

Property Owner:

North Carolina Department of Transportation
4809 Beryl Road
Raleigh, North Carolina 27606

Attn: Mr. Jeff Walston, PE
[phone]

Consultant Information:

Hart & Hickman, PC
2923 South Tryon Street, Suite 100
Charlotte, North Carolina 28203

Attn: Mr. David Graham, PG - Senior Project Geologist
[phone]

General Site Information:

NC DEQ Incident Number: 28254
Facility ID Number: 0-024661
NC DEQ Risk Classification: Intermediate prior to this report
Latitude/Longitude: 35o 19’13”/83o 48’ 05” (Approximate)
Release Discovery Date(s): August 26, 2004
Estimated Quantity of Release: Approximately 1,000 gallons
Cause/Source of Release: One 5,700-gallon gasoline UST and one 5,700-gallon diesel UST

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Soil and Groundwater Assessment Report
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476

Table of Contents

Section Page No.
1.0 Introduction ............................................................................................................................ 1 
2.0 Site History ............................................................................................................................. 2 
3.0 Receptor Survey Information ................................................................................................ 5 
4.0 Geology and Hydrogeology .................................................................................................... 6 
4.1 Regional Geology and Hydrogeology ..........................................................................6 
4.2 Site Geology and Hydrogeology ...................................................................................7 
5.0 Soil Assessment Activities ...................................................................................................... 8 
5.1 Soil Sampling Activities ...............................................................................................8 
5.2 Soil Analytical Results ..................................................................................................9 
6.0 Groundwater Monitoring .................................................................................................... 10 
6.1 Monitoring Wells and Water Levels ...........................................................................10 
6.2 Sample Collection Procedures and Analyses ..............................................................10 
6.3 Groundwater Sampling and Results ............................................................................10 
7.0 Summary and Certification ................................................................................................ 13 

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List of Tables

Table 1 Summary of Adjacent Property Owner and Water Supply Well Information
Table 2 Summary of Soil Analytical Results
Table 3 Summary of Monitoring Well Construction Data and Water Level Elevations
Table 4 Summary of Groundwater Analytical Results
Table 5 Natural Attenuation Parameters – March 2023

List of Figures

Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Receptor Survey Map
Figure 4 Shallow Groundwater Potentiometric Map
Figure 5 Soil Boring Locations and Analytical Data
Figure 6 Groundwater Sample Locations and Analytical Data

List of Appendices

Appendix A Boring Logs
Appendix B Laboratory Analytical Data Sheets
Appendix C Groundwater Sampling Forms

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Soil and Groundwater Assessment Report
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476

1.0 Introduction

This assessment report documents soil and groundwater sampling performed at the
North Carolina Department of Transportation (NC DOT) maintenance facility located at 40 State
Shed Road in Robbinsville, Graham County, North Carolina. Due to failing cathodic protection
monitoring tests, a 5,700-gallon gasoline underground storage tank (UST) and a 5,700-gallon
diesel UST were removed from the Site by NC DOT on August 31, 2004. During excavation
activities, the diesel product line leading to the dispenser island was broken and approximately
1,000-gallons of diesel fuel were released in the UST basin area. Approximately 3,900-gallons
of fuel and water were pumped from the UST basin. A Site location map is provided as Figure
1, and a Site map is included as Figure 2.

Due to the presence of a surface water body (Tulula Creek) within 500 ft of the site and
previously detected concentrations of petroleum constituents in groundwater that exceed 10
times the 2B Surface Water Standards, the North Carolina Department of Environmental Quality
(NC DEQ) risk classification for this incident is Intermediate (95D). The DEQ incident number
is #28254.

The environmental assessment work described in this report was conducted for NC DOT and
included the following tasks:
 Soil assessment near previous UST closure soil sample locations SS-8 and SS-9
 Locating and gauging monitoring wells
 Sampling monitoring wells MW-1 through MW-5 and DW-1
 Data Evaluation and Reporting
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2.0 Site History

Due to failing cathodic protection monitoring tests, a 5,700-gallon gasoline UST and a 5,700-
gallon diesel UST were removed from the Site by NC DOT on August 31, 2004. During
excavation activities on August 26, 2004, the diesel product line leading to the dispenser island
was broken and approximately 1,000-gallons of diesel fuel were released. Approximately 3,900-
gallons of fuel and water were pumped from the UST basin using two 4-inch diameter basin
wells.

Nine soil samples (SS-1 through SS-9) were collected by NC DOT from the excavation sidewalls
and adjacent to the dispenser line and dispensers after UST removal activities on August 31,
2004. Due to the presence of shallow groundwater, soil samples were collected at depths
ranging from 2.5 feet (ft) to 4 ft below ground surface (bgs). Bedrock was encountered in the
former UST basin at a depth of approximately 12 ft bgs. Petroleum-related constituents were
detected in UST closure soil samples above Soil to Water and/or Residential Maximum Soil
Contaminant Concentrations (MSCCs). Petroleum-related constituents were also reported in a
groundwater sample collected from the UST basin.

Based on the results of UST closure activities, Limited Site Assessment (LSA) sampling
activities were conducted at the Site by H&H in 2005. Five Type II monitoring wells (MW-1
through MW-5) and one Type III monitoring well (DW-1) were installed during LSA activities.
Concentrations of petroleum constituents above the NC 2L Groundwater Standards were
detected in the monitoring wells. As noted above, concentrations of petroleum constituents
detected in groundwater samples collected at the site also exceeded 10 times the 2B Surface
Water Standards.

No water supply wells were identified within a 1,500 ft radius of the site during LSA activities in
2005. However, a named surface water body (Tulula Creek) is located approximately 200 ft
west of the former dispenser area and 250 ft west of the former UST basin area. Tulula Creek is
classified as a Water Supply Class III (WS-III) and a Trout Water (Tr). The site and surrounding
properties utilize municipal water.

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In a NC DEQ Notice of Regulatory Requirements (NORR) letter dated January 19, 2021, and a
follow up email request dated June 30, 2022, NC DEQ requested a comprehensive groundwater
sampling event and an updated receptor survey be conducted to evaluate current risks associated
with the site. No assessment activities had been conducted at the site since completion of the
LSA in 2005. Per NC DEQ’s request, H&H conducted an updated receptor survey and
comprehensive groundwater sampling event in September 2022. Concentrations of benzene and
naphthalene were detected above NC 2L standards in MW-1 but did not exceed 10 times the 2B
Surface Water standards. No other VOCs or SVOCs were detected above the 2L Standards or 10
times Surface Water standards in groundwater samples collected from monitoring wells at the
site. Groundwater concentrations decreased significantly in monitoring wells MW-1 through
MW-4 and DW-1 since the 2005 sampling event. Results of the most recent sampling event are
documented in H&H’s Groundwater Monitoring Report dated December 19, 2022.

Although target concentrations were low in September 2022, only two groundwater sampling
events had been conducted at the site. Based on the groundwater sampling results, H&H
recommended one additional sampling event be completed at the site in March 2023. NC DEQ
agreed with H&H’s recommendations in an Acknowledgement of Report Receipt letter dated
January 10, 2023. Depending on the March 2023 sampling results (above 2L Standards and
below 10 times Surface Water standards), DEQ indicated that the Robbinsville Maintenance
facility Incident may be eligible for risk-based closure by filing a Notice of Residual Petroleum
(NRP) on the deed for the property. A groundwater use restriction would be required on the
NRP. NC DEQ also indicated a residential land use restriction would be required on the NRP
because soil impacts previously exceeded the Residential MSCCs. To achieve unrestricted
closure for the site (no NRP for land use and/or groundwater), groundwater impacts would need
to be below the 2L standards and soil impacts will need to be less than Residential MSCCs.

Based on conversations between H&H and NC DOT, a groundwater use restriction is acceptable
if a NRP is required for Incident closure. However, H&H understands that NC DOT would like
to close out the site without a residential land use restriction on the NRP, if possible. Based on
discussions between H&H and Ms. Katei Bernal, NC DEQ Incident Manager for the NC DOT
Robbinsville Maintenance facility, additional soil sampling activities would be required to
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achieve incident closure without a residential land use restriction on the NRP. H&H reviewed
the soil analytical data in the 2005 LSA which indicated that concentrations of Massachusetts
Department of Environmental Protection (MADEP) volatile petroleum hydrocarbons (VPH) and
extractable petroleum hydrocarbons (EPH) and/or naphthalene above the Residential MSCCs at
previous soil sample locations SS-8 (3.5 ft) and SS-9 (3.5 ft). The unrestricted use standard for
soil is the Residential MSCCs. Based on the above historical soil results, H&H conducted soil
sampling activities to evaluate if soil impacts near SS-8 and SS-9 remain above Residential
screening levels. The March 2023 soil assessment and groundwater monitoring activities are
described below.

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3.0 Receptor Survey Information

No water supply wells were identified within a 1,500 ft radius of the site during LSA activities in
2005. Municipal water is supplied to occupied properties within the site area including the
subject property. H&H identified one surface water body (Tulula Creek) located adjacent to the
site, approximately 200 ft west of the former dispenser area and 250 ft west of the former UST
basin area. Tulula Creek is classified as a Water Supply Class III (WS-III) and Trout Water (Tr).

On September 8, 2022, H&H conducted a receptor survey update for surrounding properties
within 1,500 ft of the source area at the site. Prior to conducting the survey, H&H contacted the
Town of Robbinsville water department to verify water usage in the area. H&H confirmed that
municipal water is available to properties within a 1,500 ft radius of the site.

As part of the receptor survey update, H&H performed driving and walking reconnaissance of
the site area to look for evidence of water supply wells. H&H also distributed approximately 18
NC DEQ Request for Water Supply Well Information forms to property owners within a 500 ft
radius of the release area via hand delivery and/or via US Mail. During the receptor survey,
H&H spoke with a neighbor of the property owner at 209 Old Tallulah Road located
approximately 900 ft southeast of the site. The neighbor indicated a water supply well may be
located on the 209 Old Tallulah Road property. H&H hand delivered the Request for Water
Supply Well Information form to the 209 Old Tallulah Road address. The form was returned to
H&H and indicated that two water supply wells (WS-1 and WS-2) were installed approximately
five years ago and provide water to three residences at 209 and 240 Old Tallulah Road. The
wells are also used for livestock. H&H did not observe the water supply wells during the
receptor survey and was not able to contact the owner to confirm the well locations. As such, the
well locations are estimated at the two property addresses noted above (see Figure 3).

Six NC DEQ Request for Water Supply Well Information forms were returned to H&H and did
not indicate the presence of water supply wells. Other than WS-1 and WS-2, water supply wells
were not identified during the receptor survey update. Adjacent property owners and water
supply wells owner in the area are included in Table 1.
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4.0 Geology and Hydrogeology

4.1 Regional Geology and Hydrogeology

According to the North Carolina Geological Survey 1985 Geologic Map of North Carolina, the
site area is located in the Blue Ridge Belt of the Blue Ridge Physiographic Province of North
Carolina. According to the geologic map, the basement rocks in the site area are composed of
metasandstone, metagraywacke, metasiltstone, and mica schist.

In the Blue Ridge, bedrock is overlain by a mantle of weathered rock or saprolite. The saprolite
consists of unconsolidated clay, silt, and sand with lesser amounts of rock fragments. Due to the
range of parent rock types and their variable susceptibility to weathering, the saprolite ranges
widely in color, texture, and thickness. Generally, the saprolite is thickest near interstream
divides and thins toward stream beds. In profile, the saprolite normally grades from clayey soils
near the land surface to highly weathered rock above competent bedrock.

The occurrence and movement of groundwater in the Blue Ridge is within two separate but
interconnected water-bearing zones. A shallow water-bearing zone occurs within the saprolite,
and a deeper water-bearing zone occurs within the underlying bedrock.

Groundwater in the shallow saprolite zone occurs in the interstitial pore spaces between the
grains comprising the saprolite soils. Groundwater in this zone is typically under water table or
unconfined conditions. Groundwater movement is generally lateral from recharge areas to small
streams which serve as localized discharge points.

The occurrence and movement of groundwater in underlying bedrock is controlled by secondary
joints, fractures, and faults within the bedrock. On a regional scale, the direction of groundwater
flow is typically from uplands to major streams and groundwater sinks. The saprolite has a
higher porosity than the bedrock and serves as a reservoir which supplies water to a network of
fractures in the bedrock.

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4.2 Site Geology and Hydrogeology

Based on field observations during LSA activities by H&H in 2005, the site is generally
composed of surficial fill and alluvial soils consisting of tan-brown to brownish red sandy silts
and silty clays. Metasandstone bedrock was encountered below the soils at approximately 11 to
13 ft bgs. An alluvial layer of well-rounded pebbles and cobbles with abundant groundwater is
present just above bedrock. The pebbles and cobbles are assumed to be present from previous
meanders of Tulula Creek. Larger mica schist boulders were also encountered above the
bedrock. The boulders were encountered at depths ranging from three to eight ft below ground
surface.

H&H installed five shallow (MW-1 through MW-5) and one deeper monitoring well (DW-1) at
the site during LSA activities in January 2005. After installation, the top of casing elevations of
the monitoring wells were referenced to a common, but arbitrary, datum using surveying
techniques. These same wells were gauged and sampled in March 2023. The depth to
groundwater at the site is approximately 3.5 to 5 ft below grade. H&H prepared a potentiometric
map based on groundwater elevations referencing an arbitrary datum. Based on the
potentiometric map, the shallow groundwater flow direction is generally to the west and toward
Tulula Creek (Figure 4).
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5.0 Soil Assessment Activities

5.1 Soil Sampling Activities

Prior to conducting soil assessment activities, H&H contacted North Carolina 811, the public
utility locator, to mark subsurface utilities located at the site. H&H also contracted with a private
utility locator to screen proposed soil boring locations for subgrade utilities not marked by the
public locator. The private utility locator utilized electromagnetic and ground penetrating radar
(GPR) technology to identify subgrade utilities.

On March 21, 2023, H&H advanced two soil borings adjacent to two previous soil boring
locations SS-8 and SS-9, which are located near the former product line (Figure 5). H&H
contracted with Penhall Company to core through the asphalt at each boring location. Soil
borings were advanced to approximate depths of 4 ft bgs using a stainless-steel hand auger.
Previous soil samples were collected at 3.5 ft bgs in each boring location. During boring
advancement, soil samples were collected at one ft intervals. H&H recorded soil lithology and
screened the soil samples for the presence of odors, staining, and/or organic vapors using a
photoionization detector (PID). Additionally, H&H observed the soil for visual and olfactory
indications of impacts. Based on field screening results, there were indications of potential
impacts in each soil boring. Soil samples were collected at the approximate depth interval (3 ft
to 4 ft bgs), which bracket the previous sample depths. Soil boring logs are included in
Appendix A.

The soil samples were submitted to Waypoint Analytical, a NC certified laboratory, under chain-
of-custody protocol. Based on previous soil impacts above Residential MSCCs, the soil samples
collected near SS-8 and SS-9 were analyzed for parameters previously present above Residential
MSCCs which included EPH and VPH by the MADEP Methods. Due to the prior presence of
naphthalene above the Residential MSCC, the soil sample collected near SS-9 was also analyzed
for polynuclear aromatic hydrocarbons (PAHs), including naphthalene, by EPA Method 8270.

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5.2 Soil Analytical Results

Concentrations of target petroleum constituents were detected in both of the soil samples
collected at the site. Concentrations of total C9-C22 Aromatics (689 mg/kg) and naphthalene
(9.26 mg/kg) were detected above the Residential MSCCs in soil sample SS-9. Concentrations
of other target MADEP EPH and VPH constituents and/or PAHs were also detected in SS-8 and
SS-9 above the Soil-to-Water MSCCs. Analytical results are summarized in Table 2. Historical
soil analytical data are also included in Table 2. Soil boring locations and analytical results are
shown on Figure 5. The analytical laboratory report is included in Appendix B.

Upon completion of sampling activities, soil borings were backfilled with bentonite and patched
with asphalt to match the existing ground surface.
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6.0 Groundwater Monitoring

6.1 Monitoring Wells and Water Levels

Six monitoring wells (MW-1 through MW-5 and DW-1) were sampled on March 20 and 21,
2023. The monitoring wells appeared to be in good condition. Monitoring well construction
information is provided in Table 3.

An electronic water level indicator was used to record the static water levels in the six existing
monitoring wells. The depths to water in shallow monitoring wells ranged from 3.45 ft (MW-5)
to 4.85 ft (MW-3) below the monitoring well top of casings. The estimated potentiometric
surface from March 2023 is depicted on Figure 4. As shown on Figure 4, the potentiometric
surface generally slopes to the west towards Tulula Creek.

6.2 Sample Collection Procedures and Analyses

Laboratory supplied sample containers were used for sample collection. A chain-of-custody
record was completed for samples collected and included sample description, date collected, time
collected, matrix, sample container information, and analyses required. The sample containers
were placed in a cooler with ice and submitted to Waypoint Analytical for laboratory analysis of
volatile organic compounds (VOCs) by Standard Method for the Examination of Water and
Wastewater 6200B and semi-VOCs by EPA Method 625 (base/neutral and acid extractables).
Because MADEP EPH and VPH concentrations in groundwater samples collected from MW-1,
MW-2, and MW-4 exceeded their respective 2L Standards during LSA activities in 2005, NC
DEQ requested that samples from these wells also be analyzed for EPH and VPH during the
sampling event to evaluate current EPH and VPH concentrations. Laboratory analytical data
sheets are provided in Appendix B, and analytical results are summarized in Table 4.

6.3 Groundwater Sampling and Results

After monitoring wells were gauged for depth to water, the wells were sampled using low-flow
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sampling techniques with a peristaltic pump. During well purging, measurements of pH,
conductivity, temperature, dissolved oxygen, and turbidity were collected. The wells were
purged until field parameters stabilized, and turbidity levels were below 10 Nephelometric
Turbidity Units (NTUs). Upon stabilization, a groundwater sample was collected for laboratory
analysis. Field parameter data are provided in Table 5. Groundwater sampling forms are
included in Appendix C.

Based on laboratory analytical results, concentrations of benzene (8.36 ug/L) and naphthalene
(30.3 ug/L) were detected in MW-1 above the 2L Standards of 1.0 ug/L and 6.0 ug/L,
respectively. Concentrations of C5-C8 Aliphatics (758 ug/L) and Total C9-C22 Aromatics (957
ug/L) were also detected in MW-1 above the 2L Standard of 400 ug/L and 200 ug/L,
respectively. Low-level concentrations of other petroleum-related VOCs, SVOCs and/or
MADEP EPH and VPH were also detected in MW-1, MW-2, MW-3, and MW-4 below the 2L
Standards.

The groundwater concentrations noted above were also compared to the NC Water Quality
Standards for Surface Water (2B Standards). The nearest groundwater discharge is to a Water
Supply Class III (WS-III) and a Trout Water (Tr) surface water body (Tulula Creek). Based on
the classification of the receiving water body downgradient of the site, concentrations detected in
groundwater were compared to the lower criteria applicable for WS III/Tr or Class C (All Water)
surface water. Per NC Division of Water Resources (DWR) guidance (NC DWR Surface Water
Quality Standards, Criteria & In-Stream Target Values table, July 2021), if no 2B Standards exist
for certain compounds, concentrations were also compared to the lower of the EPA National
Recommended Water Quality Criteria or NC In-Stream Target Values. Based on this
comparison, 1-Methylnaphthalene (16.1 ug/L) was detected at a concentration 10 times the
surface water criteria in MW-1. Please note that 1-methylnaphthalene was not previously
reported by the laboratory for the 2005 or 2022 groundwater sampling events.

Concentrations of VOCs and/or SVOCs have significantly decreased in monitoring wells MW-1
through MW-4 and DW-1 since the 2005 sampling event. For example, benzene decreased from
320 µg/L in 2005 to 8.36 µg/L in 2023 in MW-1. VOCs and/or SVOCs previously detected in
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wells MW-2 through MW-4 and DW-1 were not detected or were detected at concentrations
below their respective 2L Standards. The absence of impacts has remained consistent in
monitoring well MW-5 over time. Concentrations of MADEP EPH and VPH have generally
decreased in MW-1, MW-2, and MW-4 since 2005. Historical groundwater monitoring data are
provided in Table 4. Key contaminant concentrations in groundwater are depicted on Figure 6.

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7.0 Summary and Certification

Soil assessment and groundwater monitoring activities were conducted at the NC DOT
Maintenance Facility in Robbinsville, North Carolina in March 2023. The findings are
summarized below.

 The updated water supply well survey identified two water supply wells located
approximately 900 ft cross-gradient of the Site which were installed in the time since the
last receptor survey was completed during the LSA. Because these water wells are
within 1,000 ft radius, DEQ may choose to modify the risk level to high, although these
wells are not likely to be impacted based on their distance and hydrologic position.

 Analytical results of soil samples collected by H&H indicate concentrations of target
petroleum constituents above the Residential MSCCs in one of the two soil samples
recently collected.

 Analytical results of groundwater samples collected from monitoring wells at the site
indicate concentrations of benzene, naphthalene and MADEP EPH and VPH in MW-1
above the NC 2L Standards. Low-level concentrations of other petroleum-related VOCs
and/or SVOCs were also detected in MW-1, MW-2, MW-3, and MW-4 below the 2L
Standards. Concentrations of VOCs and SVOCs have significantly decreased in
monitoring wells MW-1 through MW-4 and DW-1 since the 2005 sampling event and
have remained stable since the 2022 sampling event. A concentration of 1-
methylnaphthalene was detected in MW-1 above 10 times the applicable surface water
criteria.

With the exception of the concentration of 1-methylnaphthalene detected in MW-1 (above 10
times the applicable surface water criteria), detected groundwater concentrations are similar to
groundwater concentrations detected at the site in September 2022. The concentration of 1-
methylnaphthalene was detected in MW-1, which is located upgradient and approximately 230 ft
away from the stream. No concentrations of 1-methylnapthalene were detected in monitoring
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wells MW-3 and MW-4 located downgradient of MW-1 and approximately 60 to 70 ft from the
stream. Although the site may qualify as high risk, H&H requests that DEQ consider incident
closure because the water supply wells are approximately 900 ft away and the stream is
approximately 200 to 250 ft away from groundwater impacts above standards.

If DEQ is willing to close the incident, H&H recommends completing the NRP for incident
closure in accordance with NC DEQ guidelines. Because soil concentrations are above
Residential MSCCs, a residential land use restriction will be required on the NRP to obtain a No
Further Action (NFA) requested letter. The NRP will consist of language specifying perpetual
land use restrictions that restrict both residential use and groundwater use at the site.

Table 1
Summary of Adjacent Property Owner and Water Supply Well Information
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Parcel ID No.
Map No.
(Adjacent
Parcel)
Property Address Owner Owner Mailing Address Direction From Site Water Supply
Well ID
Confirmed Well
Usage
(September 2022)
Additional Well
Information
Approximate
Distance of Well
From Source Area of
Release (ft)
Depth Use
568100EX0004 Site 40 State Shed Road NC Dept of
Transportation
1275 Old Sweetwater Rd
Robbinsville, NC 28771 NA NA NA NA NA NA NA
568100000004PT A 92 Five Point Road Southeast Bulk, LLC 7014 A.C. Skinner Parkway
Jacksonville, FL 32256 Northeast NA NA NA NA NA NA
NA B State Shed Road NC Dept of
Transportation
1275 Old Sweetwater Rd
Robbinsville, NC 28771 East NA NA NA NA NA NA
5588000014600T C 88 State Shed Road Adams Contracting P.O. Box 1157
Robbinsville, NC 28771 South NA NA NA NA NA NA
56601620000201 D 77 Tallulah Road Colvard Family Trust 420 Snug Harbor Dr
Meritt Island Fl, 32953 Southwest NA NA NA NA NA NA
5660162000021/
559800005290 E Tallulah Road/32 Five
Point Rd
Tony Cody & William
Adams
P.O. Box 218
Robbinsville, NC 28771 West/Northwest NA NA NA NA NA NA
566016200001 F HWY 129 Five Point Rd Adams Contracting Co.P.O. Box 1157
Robbinsville, NC 28771 North NA NA NA NA NA NA
* 557900030010/
557900030006 NA 209/240 Old Tallulah Road Richard & Nancy Brooks 209 Old Tallulah Rd
Robbinsville, NC 28771 Southeast WS-1/WS-2 340 ft Drinking/
Livestock Yes
Supplies water to three
residences at 209 and
240 Old Tallulah Rd
900 ft
Notes:
* = The property owner provided information that indicated WS-1 and WS-2 supplies water to three residences located at 209 and 240 Old Tallulah Road.
The locations of WS-1 and WS-2 are unknown and are esitmated on 209 and 240 Tallulah Road, respectively (Figure 3).
NA = Not Applicable
Well Details
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 Soil & GW Report/Tables/GW Tables
4/27/2023
Table 1 (Page 1 of 1)
Hart & Hickman, PC
Table 2 (Page 1 of 1)
Summary of Soil Analytical Results
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Sample ID: SS-1 SS-2 SS-3 SS-4 SS-5 SS-6 SS-7
Depth (feet): 4 4 4 4 4 3 2.5 3.5 3-4 3.5 3-4
Sample Date: 8/31/2004 8/31/2004 8/31/2004 8/31/2004 8/31/2004 8/31/2004 8/31/2004 8/31/2004 3/21/2023 8/31/2004 3/21/2023
Location: Sidewall/Line Basin Sidewall Basin Sidewall Basin Sidewall Basin Sidewall Dispenser Dispenser
VPH/EPH (MADEP)
VPH C5-C8 Aliphatics 12.2 <10 <10 11.5 <10 11.7 20.1 226 56.4 486 287 68 625 9,340
VPH C9-C12 Aliphatics 51.8 11.4 <10 <10 <10 <10 117 470 191 532 319 NS NS NS
EPH C9-C18 Aliphatics 136 119 <100 <10 252 <10 <100 1,800 142 688 647 NS NS NS
Total C9-C18 Aliphatics 187.8 130.4 ND ND 252 ND 117 2,270 333 1,220 966 540 1,560 23,300
EPH C19-C36 Aliphatics <100 113 <100 <10 <100 <10 <100 262 28.3 J 173 103 J >100% 31,200 467,000
VPH C9-C10 Aromatics 29.0 <10 <10 <10 <10 <10 68.6 249 88.3 272 176 NS NS NS
EPH C11-C22 Aromatics 429 220 142 13.2 159 12.7 156 872 122 247 513 NS NS NS
Total C9-C22 Aromatics 458 220 142 13.2 159 12.7 224.6 1,121 210.3 519 689 31 469 7,000
VOCs (8260)
Benzene ND ND ND ND ND ND ND ND NA 1.12 NA 0.0072 12 59.4
n-Butylbenzene ND ND ND ND ND ND ND 2.25 NA 4.46 NA 2.4 782 11,600
Ethylbenzene ND ND ND ND ND ND ND 5.77 NA 26.1 NA 8 60.3 297
n-Propylbenzene ND ND ND ND ND ND ND 2.52 NA 12.9 NA 1.4 1,560 23,300
p-Isopropyltoluene ND ND ND ND ND ND ND ND NA 2.77 NA 0.12 1,560 23,300
Naphthalene ND ND ND ND ND ND ND ND NA 18.3 NA 0.2 5.5 27
Bromomethane ND ND ND 0.227 0.318 0.208 ND ND NA ND NA 0.047 21 327
Chloroethane ND ND ND ND ND ND 0.129 ND NA 7.86 NA NS NS NS
Chloromethane ND ND 0.963 1.14 1.47 0.959 0.561 3.33 NA ND NA 0.014 51 251
SVOCs (8270)
Fluorene ND ND ND ND ND ND ND 1.14 NA ND 0.805 J 55 625 9,340
1-Methylnaphthalene N/A N/A N/A N/A N/A N/A N/A N/A NA N/A 7.56 0.054 22.8 112
2-Methylnaphthalene ND ND ND ND ND ND ND 13.7 NA 12 14.1 1.5 62.5 934
Naphthalene ND ND ND ND ND ND ND 3.95 NA 6.36 9.26 0.2 5.5 27
n-Nitrosodiphenylamine ND ND ND ND ND ND ND 1.19 NA ND NA NS NS NS
Phenanthrene ND ND ND ND ND ND ND 1.97 NA 1.59 1.62 J 64 469 7,000
Notes:
1) Analytical results compared to North Carolina UST Maximum Soil Contaminant Concentration levels (MSCCs), dated September 2022.
All values shown are reported in mg/kg.
Soil samples from 2004 were collected by NC DOT.
EPA Method number follows parameter in parenthesis.
Bold indicates concentration exceeds Soil to Groundwater MSCCs.
Underline indicates concentration exceeds Residential MSCCs.
VOC = Volatile Organic Compound; SVOC = Semi-Volatile Organic Compound; NA = Not Analyzed; NS = Not Specified; ND = Not Detected
VPH = Volatile Petroleum Hydrocarbons; EPH = Extractable Petroleum Hydrocarbons
MADEP = Massachusetts Department of Environmental Protection
N/A = 2004 lab report not available to confirm if compound was analyzed.

Product Line
Commercial /
Industrial
MSCC(1)
Soil to GW
MSCC(1)
Residential
MSCC(1)
SS-8 SS-9
Product Line
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 Soil & GW Report/Tables/Soil Tables
Table 2 (1 of 1)
Hart & Hickman, PC
Table 3 (Page 1 of 1)
Summary of Monitoring Well Construction Data and Water Level Elevations
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Well ID Sampling Date
(mm/dd/yy)
Top of Casing
Elevation (ft)
Depth To Water (ft below
TOC)
Groundwater
Elevation (ft)
Well Casing
Diameter
(inches)
Screen
Interval
(ft bgs)
Depth of Well
(ft bgs)
1/20/2005 5.27 93.70
9/6/2022 5.21 93.76
3/20/2023 4.60 94.37
1/20/2005 4.62 94.01
9/6/2022 4.71 93.92
3/20/2023 4.07 94.56
1/20/2005 5.07 93.34
9/6/2022 5.29 93.12
3/20/2023 4.85 93.56
1/20/2005 4.57 93.07
9/6/2022 4.70 92.94
3/20/2023 4.39 93.25
1/20/2005 4.37 95.43
9/6/2022 4.53 95.27
3/20/2023 3.45 96.35
1/20/2005 5.25 94.02
9/6/2022 5.31 93.96
3/20/2023 4.65 94.62
Notes:
Top of casing (TOC) elevations referenced from an arbitrary benchmark of 100 ft.
Wells installed by H&H on January 18 and 19, 2005.
ft bgs = feet below ground surface
* DW-1 is a Type III monitoring well with surface casing to 28 ft.
2
2
2
2
2
2
50
2-12
2-12
2-12
2-12
2-12
40-50
12
12
12
12
12MW-5
DW-1*
MW-1 98.97
MW-2
MW-3
MW-4
98.63
98.41
97.64
99.80
99.27
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 Soil & GW Report/Tables/GW Tables4/27/2023
Table 3 (Page 1 of 1)
Hart & Hickman, PC
Table 4 (Page 1 of 1)
Summary of Groundwater Analytical Results
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
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1/20/2005 NA 320 34 8.4 150 27 32 690 NA 100 91 300 <5.0 79 22 370 <1.8 <9.7 <9.7 <2.1 5.4 J NA <1.7 75 3.7 J 1,400 280 100 380 <31 1,300 1,000 2,300
9/7/2022 <1.80 11.7 7.18 7.74 1.95 12.5 2.52 <0.140 <0.078 21.2 32.7 0.488 J <0.180 <0.190 <0.180 2.25 J <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <18.0 8.36 10.7 10.7 3.38 J 14.5 <5.00 <1.40 <0.780 30.3 42.5 <2.20 <1.80 <1.90 <1.80 <2.1 1.39 J <3.49 <1.84 1.30 J 3.68 16.1 9.94 12.7 2.70 758 512 70.5 J 582.5 J <124 229 728 957
1/20/2005 NA 25 4.4 1.3 5.0 4.4 1.9 32 NA 38 11 2.4 <0.5 0.58 <0.50 1.88 <1.8 <9.7 <9.7 <2.1 3.3 J NA <1.7 34 3.0 J 83 J 110 510 620 <31 150 770 920
9/7/2022 1.82 J <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
9/7/2022 Dup <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
3/21/2023 <1.80 0.848 <0.180 0.325 J <0.170 0.988 <0.500 <0.140 <0.078 <0.470 1.97 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <3.49 <1.84 <0.861 <0.811 <1.15 <0.669 <0.731 <0.430 <11.5 34.6 J <28.2 34.6 J <124 <4.02 61.2 J 61.2 J
1/20/2005 NA 0.95 2.1 0.59 <0.5 <0.5 1.3 37 NA <0.5 0.58 <0.5 <0.5 1.5 0.96 3.0 <1.8 <9.7 <9.7 <2.1 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/7/2022 <1.80 <0.180 <0.180 0.456 J <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <1.80 <0.180 <0.180 1.21 <0.170 <0.180 1.10 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 0.562 J <3.49 <1.84 <0.861 0.921 J <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
1/20/2005 NA 5.6 7.6 0.96 5.5 1.4 6.3 34 NA 8.9 5.4 3.0 <0.5 9.5 6.2 28.8 <3.7 120 15 J <4.3 <19 NA <3.5 17 J 4.9 J <75 <70 550 550 9,700 180 2,600 2,780
9/7/2022 1.90 J <0.180 <0.180 0.376 J <0.170 <0.180 0.614 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/20/2023 <1.80 <0.180 <0.180 0.428 J <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 0.602 J <3.49 <1.84 <0.861 <0.811 <1.15 <0.669 <0.731 <0.430 41.8 J 47.4 J 29.3 J 76.7 J <124 9.91 J 139 J 148.91 J
1/20/2005 NA <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NA <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1.5 <1.8 <9.7 <9.7 <2.1 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/6/2022 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/20/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <3.49 <1.84 <0.861 <0.811 <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
1/20/2005 NA <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NA <0.5 <0.5 <0.5 1.9 <0.5 <0.5 <1.5 <1.8 <9.7 <9.7 <2.1 <9.7 NA <1.7 <9.7 <9.7 <75 <70 <75 ND <31 <35 <71 ND
9/7/2022 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 0.712 J <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <7.12 <8.80 <4.53 <5.08 <7.27 NA NA <7.88 <6.34 NA NA NA NA NA NA NA NA
3/21/2023 <1.80 <0.180 <0.180 <0.200 <0.170 <0.180 <0.500 <0.140 <0.078 <0.470 <0.190 <0.220 <0.180 <0.190 <0.180 <0.21 <0.303 <3.49 <1.84 <0.861 <0.811 <1.15 <0.669 <0.731 <0.430 NA NA NA NA NA NA NA NA
6,000 1 70 70 600 70 70 20 100 6 70 600 3 400 400 500 80 3 1,000 28 300 1 30 6 200 400 NS NS 700 10,000 NS NS 200
6,000,000 5,000 5,900 8,800 80,000 30,500 70,000 20,000 100,000 6,000 26,100 260,000 3,000 28,500 24,100 50,000 1,950 135 NS 1,550 845 1,000 12,000 6,000 550 NS NS NS NS NS NS NS NS
20,000 11.9 39 NS 680 2,500 200,000 190 28,000 120 800 3.6 25 3,900 1,300 4,500 290 3.2 1 NS 300 8 850 120 3 1,250 1,800 1,800 1,800 2,100 NS NS 8,300
Notes:
1) Analytical results compared to North Carolina 2L (NC2L) Groundwater Standards or Interim Maximum Allowable Concentrations, April 2022.
2) Analytical results compared to North Carolina Gross Contamination Levels (GCL) for Groundwater, September 2022.
3) NC Water Quality Standards for Surface Water (2B Standards). If no standard exists, the lower of EPA Recommended Water Quality Criteria for Aquatic Life & Human Health - Class WS III/Tr or Class C (All waters) or NC In-Stream Target Values for Surface Water - Class WS III/Tr or Class C (All waters) (July 2021) was used.
The nearest discharge is to a Class WS III/Tr surface water body (Tulula Creek). Based on the classification of the receiving water body, surface water standards and criteria are based on Class WS III/Tr or Class C (All waters) surface water standards.
Bold indicates above 2L Standard.
Underline exceeds Surface Water Criteria.
Only those compounds detected in at least one sample shown above.
µg/L = micrograms per liter; Dup = Duplicate
VOCs = volatile organic compounds; SVOCs = semi-volatile organic compounds; NA = Not Analyzed; ND = Not Detected; NS = Not Specified.
VPH = Volatile Petroleum Hydrocarbons; EPH = Extractable Petroleum Hydrocarbons; MADEP = Massachusetts Department of Environmental Protection
EPA Method number follows parameter in parenthesis.
J = Estimated value between the laboratory reporting limit and the method detection limit.
VPH/EPH (MADEP)
µg/L
MW-2
MW-3
MW-4
SVOCs (625)
µg/L
VOCs (6200B)
Sa
m
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e

I
D
Sa
m
p
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e

D
a
t
e
µg/L
MW-1
MW-5
NC2L1
10 X Surface Water Criteria3
GCL2
DW-1
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 Soil & GW Report/Tables/GW Tables4/27/2023
Table 4 (Page 1 of 1)
Hart & Hickman, PC
Table 5
Natural Attenuation Parameters - March 2023
NC DOT Maintenance Facility
Robbinsville, North Carolina
H&H Job No. DOT-476
Well pH
(SU)
Conductivity
(µS/cm)
Temperature
(ºC)ORP (mV)Dissolved Oxygen
(mg/L)
Turbidity
(NTU)
MW-1 6.97 513.3 16.4 -101.0 1.21 0.26
MW-2 5.90 249.1 15.9 65.6 1.80 0.40
MW-3 6.50 383.9 14.1 -78.9 2.14 2.80
MW-4 6.14 673.0 14.5 -11.8 2.46 0.37
MW-5 5.91 602.1 12.6 182.8 5.40 0.68
DW-1 7.65 212.1 14.4 -135.4 0.57 1.21
Notes:
SU = Standard Units
µS/cm = microsiemens per centimeter
mg/L = milligrams per liter
ORP = Oxidation-Reduction Potential
mV = millivolts
NTU = Nephelometric Turbidity Units
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/NC DOT -DOT/DOT-476 Robbinsville/Reports/2023 Soil & GW Report/Tables/GW Tables
Table 5 (Page 1 of 1)
Hart & Hickman, PC
USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset, andNational Transportation Dataset; USGS Global Ecosystems; U.S. CensusBureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.Department of State Humanitarian Information Unit; and NOAA NationalCenters for Environmental Information, U.S. Coastal Relief Model. Datarefreshed June, 2022.
SITE LOCATION MAP
NC DOT MAINTENANCE FACILITY40 STATE SHED ROADROBBINSVILLE, NORTH CAROLINA
DATE: 12-15-2022
JOB NO: DOT-476
REVISION NO: 0
FIGURE NO: 1
2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology
TITLE
PROJECT
0 2,000 4,000
SCALE IN FEET
SITE
Path: S:\AAA-Master Projects\NC DOT -DOT\DOT-476 Robbinsville\Figures\Figure-1.mxd
N
U.S.G.S. QUADRANGLE MAP
ROBBINSVILLE, NORTH CAROLINA 2022
QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC)
MW-4
MW-3
MW-1
DW-1
MW-5
MW-2
W-2
REVISION NO. 1
JOB NO. DOT-476
DATE: 4-24-23
FIGURE NO. 2
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SITE MAP
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
USED OIL UNDERGROUND STORAGE
TANK
FORMER AST FUEL DISPENSERS
MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
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REVISION NO. 0
JOB NO. DOT-476
DATE: 4-24-23
FIGURE NO. 3
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
RECEPTOR SURVEY MAP
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY
TULULA CREEK
PROPERTY IDENTIFICATION
WATER SUPPLY WELL LOCATION
GROUNDWATER FLOW DIRECTION
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
NOTES:
1.AERIAL IMAGERY OBTAINED FROM NCONEMAP, 2022.
2.BASE DATA OBTAINED FROM NCONEMAP, 2023.
SW
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MW-4
MW-3
MW-1
DW-1
MW-5
MW-2
W-2
REVISION NO. 1
JOB NO. DOT-476
DATE: 4-26-23
FIGURE NO. 4
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SHALLOW GROUNDWATER
POTENTIOMETRIC MAP
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
USED OIL UNDERGROUND STORAGE
TANK
FORMER AST FUEL DISPENSER
MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
GROUNDWATER ELEVATION (FT)
(3/20/23)
ESTIMATED SHALLOW GROUNDWATER
CONTOUR LINE
ESTIMATED GROUNDWATER FLOW
DIRECTION
(93.25)
95
(96.35)
(93.56)
(94.56)
(94.37)
(93.25)
94 95
94
95
96
96
S:
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MW-4
MW-3
MW-1
DW-1
MW-5
MW-2
W-2
SS-7SS-6
SS-9
SS-8
SS-1 SS-2
SS-5
SS-4
SS-3
SS-8 8/31/2004 3/21/2023
DEPTH 3.5 3-4
TOTAL C9-C18 ALIPHATICS 2,270 333
TOTAL C9-C22 AROMATICS 1,121 210.3
REVISION NO. 1
JOB NO. DOT-476
DATE: 4-24-23
FIGURE NO. 5
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
SOIL BORING LOCATIONS AND
ANALYTICAL DATA
NOTES:
1.PARCEL DATA OBTAINED FROM GRAHAM COUNTY GIS,
2023.
2.UST SAMPLES COLLECTED BY DOT (08/31/04).
3.ONLY COMPOUNDS THAT WERE DETECTED ABOVE
RESIDENTIAL MSCCs ARE SHOWN. REFER TO TABLE 2
FOR ALL DETECTED COMPOUNDS.
4.BOLD EXCEEDS SOIL-TO-WATER MSCCs.
5.UNDERLINE EXCEEDS RESIDENTIAL MSCCs.
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
USED OIL UNDERGROUND STORAGE
TANK
FORMER AST FUEL DISPENSERS
MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
APPROXIMATE SOIL SAMPLE LOCATION
SS-8 8/31/2004 3/21/2023
DEPTH 3.5 3-4
TOTAL C9-C18 ALIPHATICS 2,270 333
TOTAL C9-C22 AROMATICS 1,121 210.3
CONSTITUENT
SAMPLE ID SAMPLE DATE
SS-9 8/31/2004 3/21/2023
DEPTH 3.5 3-4
TOTAL C9-C22 AROMATICS 519 689
NAPHTHALENE (VIA 8260)18.3 NA
NAPHTHALENE (VIA 8270)6.36 9.26
CONCENTRATION
(mg/kg)
S:
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MW-4
MW-3
MW-1
DW-1
MW-5
MW-2
W-2
MW-3 1/20/2005 9/7/2022 3/21/2023
MTBE 37 <0.140 <0.140
REVISION NO. 1
JOB NO. DOT-476
DATE: 4-26-23
FIGURE NO. 6
NC DOT MAINTENANCE FACILITY
40 STATE SHED ROAD
ROBBINSVILLE, NORTH CAROLINA
GROUNDWATER SAMPLE LOCATIONS AND
ANALYTICAL DATA
NOTES:
1.BOLD CONCENTRATIONS EXCEED THE NC 2L STANDARDS.
2.UNDERLINE EXCEEDS 10X SURFACE WATER CRITERIA.
3.MTBE = METHYL TERT-BUTYL ETHER
NA = NOT ANALYZED
ND = NO PETROLEUM COMPOUNDS DETECTED
BDL = BELOW LABORATORY DETECTION LIMITS
4.J FLAG DENOTES ESTIMATED CONCENTRATION BETWEEN
LABORATORY REPORTING LIMIT AND METHOD DETECTION
LIMIT.
5.SEE TABLE 4 FOR MADEP EPH AND VPH ANALYTICAL DATA.
2923 South Tryon Street-Suite 100
Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f)
License # C-1269 / #C-245 Geology
LEGEND
SITE PROPERTY BOUNDARY
PARCEL BOUNDARY LINE
SURFACE WATER FEATURE
FENCE
WATER LINE
SEWER LINE
SEWER MANHOLE
USED OIL UNDERGROUND STORAGE
TANK
FORMER AST FUEL DISPENSER
MONITORING WELL
DEEP MONITORING WELL
UST OBSERVATION WELL
MW-1 1/20/2005 9/7/2022 3/21/2023
BENZENE 320 11.7 8.36
MTBE 690 <0.140 <1.40
NAPHTHALENE 100 21.2 30.3
n-PROYLBENZENE 91 32.7 42.5
TOLUENE 300 0.488 J <2.20
1-METHYLNAPHTHALENE NA NA 16.1
PHENANTHRENE 3.7 J <6.34 2.70
MW-2 1/20/2005 9/7/2022 3/21/2023
BENZENE 25 <0.180 0.848
MTBE 32 <0.140 <1.40
NAPHTHALENE 38 <0.470 <0.470
MW-3 1/20/2005 9/7/2022 3/21/2023
MTBE 37 <0.140 <0.140
MW-4 1/20/2005 9/7/2022 3/20/2023
BENZENE 5.6 <0.180 <0.180
MTBE 34 <0.140 <0.140
NAPHTHALENE 17 J <0.470 <0.470
BIS(2-ETHYLHEXYL)
PHTHALATE 120 <8.80 <3.49
BUTYLBENZYLPHTHALATE 15 J <4.53 <1.84
PHENANTHRENE 4.9 J <6.34 <0.430
MW-5
1/20/2005 9/6/2022 3/20/2023
BDL
CONSTITUENT
SAMPLE ID
CONCENTRATION
(µg/L)
SAMPLE DATE
DW-1
1/20/2005 9/7/2022 3/21/2023
ND
S:
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Appendix A

Boring Logs

NOTES: Borehole cored by Penhall Company using a core drill to remove asphalt.
generated using GroundLogs.online
Client:
Project:
Address:
NC DOT
DOT-476
40 State Shed Road, Robbinsville,NC
BORING LOG
Boring No.
Page:
SS-8
1 of 1
Drilling Start Date:
Drilling End Date:
Drilling Company:
Drilling Method:
Drilling Equipment:
Driller:
Logged By:
03/21/23
03/21/23
Hart and Hickman, PC
Hand Auger
Hand Auger
DJH
DJH
Boring Depth (ft):
Boring Diameter (in):
Sampling Method(s):
DTW During Drilling (ft):
DTW After Drilling (ft):
Ground Surface Elev. (ft):
Location (X,Y):
4.0
3.25
DE
P
T
H
(
f
t
)
LI
T
H
O
L
O
G
Y
WA
T
E
R
L
EV
E
L
BO
R
I
N
G
CO
M
P
L
E
T
I
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N
COLLECT
Sa
m
p
l
e
T
y
p
e
Ti
m
e
Bl
o
w
C
ou
n
t
s
Re
c
o
v
e
ry

(
f
t
)
SOIL/ROCK VISUAL DESCRIPTION
MEASURE
PI
D
(
p
pm
)
La
b
S
am
p
l
e
DE
P
T
H
(
f
t
)
0
1
2
3
4
5
(0') Asphalt
(0.5') Fill: Gravel
(1') Sandy CLAY (CH); high plasticity, soft, wet, gray, strong odor
(3') Silty SAND (SM); loose, wet, brownish gray, strong odor
(4') Boring terminated
394.3
397.5
437.8 SS-8(3-4)
0
1
2
3
4
5
Grab
GR 4.00
NOTES: Borehole cored by Penhall Company using a core drill to remove asphalt.
generated using GroundLogs.online
Client:
Project:
Address:
NC DOT
DOT-476
40 State Shed Road, Robbinsville,NC
BORING LOG
Boring No.
Page:
SS-9
1 of 1
Drilling Start Date:
Drilling End Date:
Drilling Company:
Drilling Method:
Drilling Equipment:
Driller:
Logged By:
03/21/23
03/21/23
Hart and Hickman, PC
Hand Auger
Hand Auger
DJH
DJH
Boring Depth (ft):
Boring Diameter (in):
Sampling Method(s):
DTW During Drilling (ft):
DTW After Drilling (ft):
Ground Surface Elev. (ft):
Location (X,Y):
4.0
Grab
DE
P
T
H

(
f
t
)
LI
T
H
O
L
O
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Y
WA
T
E
R

L
E
V
E
L
BO
R
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G
CO
M
P
L
E
T
I
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N
COLLECT
Sa
m
p
l
e

T
y
p
e
Ti
m
e
Bl
o
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C
o
u
n
t
s
Re
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r
y

(
f
t
)
SOIL/ROCK VISUAL DESCRIPTION
MEASURE
PI
D

(
p
p
m
)
La
b

S
a
m
p
l
e
DE
P
T
H

(
f
t
)
0
1
2
3
4
5
GR 4.00 (0') Asphalt
(1') Sandy CLAY (CH); high plasticity, soft, moist, gray, strong odor
(2') Sandy CLAY (CH); little fine-coarse sand, high plasticity, soft, wet, gray/brown,
strong odor
(3') Sandy CLAY (CH); few silt, high plasticity, soft, moist, gray, strong odor
(4') Boring terminated
72.5
1,439
1,258 SS-9(3-4)
0
1
2
3
4
5
3.25

Appendix B

Laboratory Analytical Data Sheets

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/3/2023
Hart & Hickman (Charlotte) David Graham
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Lab Report Number: 23-081-0101 Client Project Description: DOT-476
Dear David Graham:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/22/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 18
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-081-0101
Page 2 of 18
Report Number:
Sample Summary Table
Client Project Description:
23-081-0101
DOT-476
Lab No Client Sample ID Matrix Date Collected Date Received
03/21/2023 13:05Solids 91868 SS-8(3-4)03/22/2023 12:15
03/21/2023 12:20Solids 91869 SS-9(3-4)03/22/2023 12:15
Page 3 of 18
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-081-0101
Report Limit
Project:DOT-476
V 91868SS-8(3-4)
142 03/31/2023 23:37MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 10.8
J28.3 03/31/2023 23:37MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 14.3
122 03/31/2023 23:37MADEP-EPH Aromatic C11-C22 mg/Kg - dry 16.6
56.4 03/28/2023 16:34MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 1.43
191 03/28/2023 16:34MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 5.35
88.3 03/28/2023 16:34MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.731
14.7 03/28/2023 15:31SW-DRYWT Moisture %
V 91869SS-9(3-4)
J0.805 03/29/2023 02:508270EFluorenemg/Kg - dry 0.629
7.56 03/29/2023 02:508270E1-Methylnaphthalene mg/Kg - dry 0.521
14.1 03/29/2023 02:508270E2-Methylnaphthalene mg/Kg - dry 0.492
9.26 03/29/2023 02:508270ENaphthalenemg/Kg - dry 0.708
J1.62 03/29/2023 02:508270EPhenanthrenemg/Kg - dry 1.02
647 04/01/2023 12:14MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 45.0
J10304/01/2023 12:14MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 59.8
513 04/01/2023 12:14MADEP-EPH Aromatic C11-C22 mg/Kg - dry 69.5
287 03/28/2023 17:21MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 1.50
319 03/28/2023 17:21MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 5.61
176 03/28/2023 17:21MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.767
18.7 03/27/2023 15:51SW-DRYWT Moisture %
Page 4 of 18

Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: DOT-476 Lab Report Number: 23-081-0101
Date: 4/3/2023
Massachusetts EPH Method MADEP-EPH Sample 91869 (SS-9(3-4)) QC Batch No: V31501
Sample requires dilution due to high levels of target and/or non-target analytes.
Analyte: 2-Bromonaphthalene QC Batch No: V31501/V31319
Fractionation surrogate 2-Bromonaphthalene running high in entire batch due to concentrated standard. The other fractionation surrogate 2-Fluorobiphenyl is performing as expected. This still proves that the fractionation process
is working. Semivolatile Organic Compounds - GC/MS Method 8270E Sample 91869 (SS-9(3-4))
QC Batch No: V31378/V31269 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.

Page 5 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0101
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/03/2023
Sample ID :
Lab No :
Sampled:SS-8(3-4)
91868 Matrix:
3/21/2023 13:05
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
14.7 %Moisture 1 03/28/23 15:31 SW-DRYWTPEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQL
Page 6 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0101
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/03/2023
Sample ID :
Lab No :
Sampled:SS-8(3-4)
91868 Matrix:
3/21/2023 13:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31319 03/28/23 11:00
142 mg/Kg - dry 10.8 58.7Aliphatic C9-C18 1 03/31/23 23:37 V31501AMP
28.3 J mg/Kg - dry 14.3 58.7Aliphatic C19-C36 1 03/31/23 23:37 V31501AMP
122 mg/Kg - dry 16.6 58.7Aromatic C11-C22 1 03/31/23 23:37 V31501AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%03/31/23 23:371 AMP
MADEP-EPHSurrogate: Chlorooctadecane 80.7 Limits: 40-140%03/31/23 23:371 AMP
MADEP-EPHSurrogate: OTP Surrogate 95.3 Limits: 40-140%03/31/23 23:371 AMP
Surrogate: 2-Fluorobiphenyl 105 Limits: 40-140%03/31/23 23:371 AMP V31501
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31296 03/28/23 08:00
56.4 mg/Kg - dry 1.43 9.38Aliphatic C5-C8 100 03/28/23 16:34 V31297TBL
191 mg/Kg - dry 5.35 9.38Aliphatic C9-C12 100 03/28/23 16:34 V31297TBL
88.3 mg/Kg - dry 0.731 9.38Aromatic C9-C10 100 03/28/23 16:34 V31297TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)112 Limits: 70-130%03/28/23 16:34100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)125 Limits: 70-130%03/28/23 16:34100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQL
Page 7 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0101
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/03/2023
Sample ID :
Lab No :
Sampled:SS-9(3-4)
91869 Matrix:
3/21/2023 12:20
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
18.7 %Moisture 1 03/27/23 15:51 SW-DRYWTPEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQL
Page 8 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0101
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/03/2023
Sample ID :
Lab No :
Sampled:SS-9(3-4)
91869 Matrix:
3/21/2023 12:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V31269 03/28/23 09:15
<0.570 mg/Kg - dry 0.570 3.25Acenaphthene 4 03/29/23 02:50 V31378ANG
<0.516 mg/Kg - dry 0.516 3.25Acenaphthylene 4 03/29/23 02:50 V31378ANG
<0.703 mg/Kg - dry 0.703 3.25Anthracene 4 03/29/23 02:50 V31378ANG
<0.683 mg/Kg - dry 0.683 3.25Benzo(a)anthracene 4 03/29/23 02:50 V31378ANG
<0.723 mg/Kg - dry 0.723 3.25Benzo(a)pyrene 4 03/29/23 02:50 V31378ANG
<0.718 mg/Kg - dry 0.718 3.25Benzo(b)fluoranthene 4 03/29/23 02:50 V31378ANG
<0.669 mg/Kg - dry 0.669 3.25Benzo(g,h,i)perylene 4 03/29/23 02:50 V31378ANG
<0.674 mg/Kg - dry 0.674 3.25Benzo(k)fluoranthene 4 03/29/23 02:50 V31378ANG
<0.698 mg/Kg - dry 0.698 3.25Chrysene 4 03/29/23 02:50 V31378ANG
<1.13 mg/Kg - dry 1.13 3.25Dibenz(a,h)anthracene 4 03/29/23 02:50 V31378ANG
<0.605 mg/Kg - dry 0.605 3.25Fluoranthene 4 03/29/23 02:50 V31378ANG
0.805 J mg/Kg - dry 0.629 3.25Fluorene 4 03/29/23 02:50 V31378ANG
<0.880 mg/Kg - dry 0.880 3.25Indeno(1,2,3-cd)pyrene 4 03/29/23 02:50 V31378ANG
7.56 mg/Kg - dry 0.521 3.251-Methylnaphthalene 4 03/29/23 02:50 V31378ANG
14.1 mg/Kg - dry 0.492 3.252-Methylnaphthalene 4 03/29/23 02:50 V31378ANG
9.26 mg/Kg - dry 0.708 3.25Naphthalene 4 03/29/23 02:50 V31378ANG
1.62 J mg/Kg - dry 1.02 3.25Phenanthrene 4 03/29/23 02:50 V31378ANG
<0.659 mg/Kg - dry 0.659 3.25Pyrene 4 03/29/23 02:50 V31378ANG
Surrogate: 2-Fluorobiphenyl 102 Limits: 44-115%03/29/23 02:504 ANG V31378
Surrogate: Nitrobenzene-d5 109 Limits: 37-122%03/29/23 02:504 ANG V31378
Surrogate: 4-Terphenyl-d14 116 Limits: 54-127%03/29/23 02:504 ANG V31378
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQL
Page 9 of 18
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0101
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/03/2023
Sample ID :
Lab No :
Sampled:SS-9(3-4)
91869 Matrix:
3/21/2023 12:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31319 03/28/23 11:00
647 mg/Kg - dry 45.0 245Aliphatic C9-C18 4 04/01/23 12:14 V31501AMP
103 J mg/Kg - dry 59.8 245Aliphatic C19-C36 4 04/01/23 12:14 V31501AMP
513 mg/Kg - dry 69.5 245Aromatic C11-C22 4 04/01/23 12:14 V31501AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%04/01/23 12:144 AMP
MADEP-EPHSurrogate: Chlorooctadecane 71.5 Limits: 40-140%04/01/23 12:144 AMP
MADEP-EPHSurrogate: OTP Surrogate 81.3 Limits: 40-140%04/01/23 12:144 AMP
Surrogate: 2-Fluorobiphenyl 105 Limits: 40-140%04/01/23 12:144 AMP V31501
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31296 03/28/23 08:00
287 mg/Kg - dry 1.50 9.84Aliphatic C5-C8 100 03/28/23 17:21 V31297TBL
319 mg/Kg - dry 5.61 9.84Aliphatic C9-C12 100 03/28/23 17:21 V31297TBL
176 mg/Kg - dry 0.767 9.84Aromatic C9-C10 100 03/28/23 17:21 V31297TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)85.7 Limits: 70-130%03/28/23 17:21100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)101 Limits: 70-130%03/28/23 17:21100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQL
Page 10 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V31378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V31269
Associated Lab Samples: 91869
LRB-V31269 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/28/23 16:470.6600.116<0.116mg/KgAcenaphthene
03/28/23 16:470.6600.105<0.105mg/KgAcenaphthylene
03/28/23 16:470.6600.143<0.143mg/KgAnthracene
03/28/23 16:470.6600.139<0.139mg/KgBenzo(a)anthracene
03/28/23 16:470.6600.147<0.147mg/KgBenzo(a)pyrene
03/28/23 16:470.6600.146<0.146mg/KgBenzo(b)fluoranthene
03/28/23 16:470.6600.136<0.136mg/KgBenzo(g,h,i)perylene
03/28/23 16:470.6600.137<0.137mg/KgBenzo(k)fluoranthene
03/28/23 16:470.6600.142<0.142mg/KgChrysene
03/28/23 16:470.6600.230<0.230mg/KgDibenz(a,h)anthracene
03/28/23 16:470.6600.123<0.123mg/KgFluoranthene
03/28/23 16:470.6600.128<0.128mg/KgFluorene
03/28/23 16:470.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
03/28/23 16:470.6600.106<0.106mg/Kg1-Methylnaphthalene
03/28/23 16:470.6600.100<0.100mg/Kg2-Methylnaphthalene
03/28/23 16:470.6600.144<0.144mg/KgNaphthalene
03/28/23 16:470.6600.208<0.208mg/KgPhenanthrene
03/28/23 16:470.6600.134<0.134mg/KgPyrene
03/28/23 16:472-Fluorobiphenyl (S)101 44-115
03/28/23 16:472-Fluorophenol (S)86.4 35-115
03/28/23 16:47Nitrobenzene-d5 (S)91.0 37-122
03/28/23 16:474-Terphenyl-d14 (S)116 54-127
03/28/23 16:472,4,6-Tribromophenol (S)80.4 39-132
03/28/23 16:47Phenol-d5 (S)79.2 34-121
Page 1 of 6Date:04/03/2023 11:22 AM
Page 11 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V31378QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V31269
LCS-V31269 LCSD-V31269Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1.66 99.495.21.591.67mg/KgAcenaphthene 40-123 4.3 20
1.72 10397.61.631.67mg/KgAcenaphthylene 32-132 5.3 20
2.03 1221041.731.67mg/KgAnthracene 47-123 15.9 20
1.81 1081051.761.67mg/KgBenzo(a)anthracene 49-126 2.8 20
1.94 1161141.901.67mg/KgBenzo(a)pyrene 45-129 2.0 20
1.78 1071031.721.67mg/KgBenzo(b)fluoranthene 45-132 3.4 20
1.69 10199.41.661.67mg/KgBenzo(g,h,i)perylene 43-134 1.7 20
1.82 1091021.701.67mg/KgBenzo(k)fluoranthene 47-132 6.8 20
1.76 1051021.701.67mg/KgChrysene 50-124 3.4 20
1.80 1081051.751.67mg/KgDibenz(a,h)anthracene 45-134 2.8 20
1.67 10098.21.641.67mg/KgFluoranthene 50-127 1.8 20
1.78 10797.61.631.67mg/KgFluorene 43-125 8.7 20
1.72 1031011.681.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 2.3 20
1.51 90.486.81.451.67mg/Kg1-Methylnaphthalene 40-119 4.0 20
1.58 94.685.61.431.67mg/Kg2-Methylnaphthalene 38-122 9.9 20
1.78 10788.61.481.67mg/KgNaphthalene 35-123 18.4 20
1.83 1101001.671.67mg/KgPhenanthrene 50-121 9.1 20
1.83 1101041.731.67mg/KgPyrene 47-127 5.6 20
1051042-Fluorobiphenyl (S)44-115
87.382.82-Fluorophenol (S)35-115
90.490.4Nitrobenzene-d5 (S)37-122
1151164-Terphenyl-d14 (S)54-127
81.081.62,4,6-Tribromophenol (S)39-132
80.776.8Phenol-d5 (S)34-121
Page 2 of 6Date:04/03/2023 11:22 AM
Page 12 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V31501QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V31319
Associated Lab Samples: 91868, 91869
LRB-V31319 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/31/23 18:4650.09.20<9.20mg/KgAliphatic C9-C18
03/31/23 18:4650.012.2<12.2mg/KgAliphatic C19-C36
03/31/23 18:4650.014.2<14.2mg/KgAromatic C11-C22
03/31/23 18:462-Fluorobiphenyl (S)105 40-140
03/31/23 18:462-Bromonaphthalene (S)I 40-140
03/31/23 18:46Chlorooctadecane (S)77.8 40-140
03/31/23 18:46OTP Surrogate (S)92.8 40-140
LCS-V31319 LCSD-V31319Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
35.4 59.060.636.460.0mg/KgAliphatic C9-C18 40-140 2.7 50
64.5 80.680.564.480.0mg/KgAliphatic C19-C36 40-140 0.1 50
166 97.691.7156170mg/KgAromatic C11-C22 40-140 6.2 50
1051002-Fluorobiphenyl (S)40-140
I*I*2-Bromonaphthalene (S)40-140
83.083.7Chlorooctadecane (S)40-140
90.386.2OTP Surrogate (S)40-140
Page 3 of 6* QC Fail Date:04/03/2023 11:22 AM
Page 13 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V31297QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V31296
Associated Lab Samples: 91868, 91869
LRB-V31296 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/28/23 10:418.001.22<1.22mg/KgAliphatic C5-C8
03/28/23 10:418.004.56<4.56mg/KgAliphatic C9-C12
03/28/23 10:418.000.624<0.624mg/KgAromatic C9-C10
03/28/23 10:412,5-Dibromotoluene (FID) (S)101 70-130
03/28/23 10:412,5-Dibromotoluene (PID) (S)113 70-130
LCS-V31296 LCSD-V31296Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
29.1 90.991.829.432.0mg/KgAliphatic C5-C8 70-130 1.0 50
36.4 11412138.732.0mg/KgAliphatic C9-C12 70-130 6.1 50
12.5 11711412.210.7mg/KgAromatic C9-C10 70-130 2.4 50
10298.12,5-Dibromotoluene (FID) (S)70-130
1151182,5-Dibromotoluene (PID) (S)70-130
Page 4 of 6Date:04/03/2023 11:22 AM
Page 14 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
Dry Weight Determination
SW-DRYWT
V31240QC Analytical Batch:
Analysis Method:
Analysis Description:
V 91768-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/27/23 15:511.519.219.5%Moisture
V 91869-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/27/23 15:510.518.818.7%Moisture
Page 5 of 6Date:04/03/2023 11:22 AM
Page 15 of 18
Quality Control Data
23-081-0101Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
Dry Weight Determination
SW-DRYWT
V31307QC Analytical Batch:
Analysis Method:
Analysis Description:
V 91868-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/28/23 15:311.314.514.7%Moisture
V 92036-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 03/28/23 15:314.718.519.4%Moisture
Page 6 of 6Date:04/03/2023 11:22 AM
Page 16 of 18
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-081-0101
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 4.1 C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angela D Overcash Date & Time:03/22/2023 13:43:45
Special precautions or instructions included?
Comments:
Page 17 of 18
Page 18 of 18

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/7/2023
Hart & Hickman (Charlotte) David Graham
2923 South Tryon St. Ste 100 Charlotte, NC, 28203
Ref: Analytical Testing
Lab Report Number: 23-081-0100 Client Project Description: DOT-476
Dear David Graham:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/22/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 91
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-081-0100
Page 2 of 91
Report Number:
Sample Summary Table
Client Project Description:
23-081-0100
DOT-476
Lab No Client Sample ID Matrix Date Collected Date Received
03/21/2023 14:10Aqueous 91859 MW-1 03/22/2023 12:15
03/21/2023 15:25Aqueous 91860 MW-2 03/22/2023 12:15
03/21/2023 09:35Aqueous 91861 MW-3 03/22/2023 12:15
03/20/2023 16:10Aqueous 91862 MW-4 03/22/2023 12:15
03/20/2023 15:05Aqueous 91863 MW-5 03/22/2023 12:15
03/21/2023 10:35Aqueous 91864 DW-1 03/22/2023 12:15
Page 3 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-081-0100
Report Limit
Project:DOT-476
V 91859MW-1
8.36 03/31/2023 02:236200BBenzeneµg/L 1.80
10.7 03/31/2023 02:236200Bn-Butylbenzene µg/L 1.80
10.7 03/31/2023 02:236200Bsec-Butyl benzene µg/L 2.00
J3.38 03/31/2023 02:236200BEthylbenzeneµg/L 1.70
14.5 03/31/2023 02:236200BIsopropylbenzeneµg/L 1.80
30.3 03/31/2023 02:236200BNaphthaleneµg/L 4.70
42.5 03/31/2023 02:236200Bn-Propylbenzene µg/L 1.90
J1.39 03/29/2023 21:19625.1 Acenaphthene µg/L 0.303
J1.30 03/29/2023 21:19625.1 Dibenzofuran µg/L 0.861
3.68 03/29/2023 21:19625.1 Fluorene µg/L 0.811
16.1 03/29/2023 21:19625.1 1-Methylnaphthalene µg/L 1.15
9.94 03/29/2023 21:19625.1 2-Methylnaphthalene µg/L 0.669
12.7 03/29/2023 21:19625.1 Naphthalene µg/L 0.731
2.70 03/29/2023 21:19625.1 Phenanthrene µg/L 0.430
J70.5 04/03/2023 14:44MADEP-EPH Aliphatic C9-C18 µg/L 28.2
728 04/03/2023 14:44MADEP-EPH Aromatic C11-C22 µg/L 61.2
758 03/25/2023 12:08MADEP-VPH Aliphatic C5-C8 µg/L 11.5
512 03/25/2023 12:08MADEP-VPH Aliphatic C9-C12 µg/L 25.8
229 03/25/2023 12:08MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 91860MW-2
0.848 03/30/2023 23:126200BBenzeneµg/L 0.180
J0.325 03/30/2023 23:126200Bsec-Butyl benzene µg/L 0.200
0.988 03/30/2023 23:126200BIsopropylbenzeneµg/L 0.180
1.97 03/30/2023 23:126200Bn-Propylbenzene µg/L 0.190
J61.2 04/03/2023 15:20MADEP-EPH Aromatic C11-C22 µg/L 61.2
J34.6 03/25/2023 02:17MADEP-VPH Aliphatic C9-C12 µg/L 25.8
V 91861MW-3
1.21 03/30/2023 23:396200Bsec-Butyl benzene µg/L 0.200
1.10 03/30/2023 23:396200BDi-Isopropyl Ether (DIPE)µg/L 0.500
J0.562 03/29/2023 00:08625.1 Acenaphthene µg/L 0.303
J0.921 03/29/2023 00:08625.1 Fluorene µg/L 0.811
V 91862MW-4
J0.428 03/31/2023 00:066200Bsec-Butyl benzene µg/L 0.200
J0.602 03/28/2023 23:44625.1 Acenaphthene µg/L 0.303
J29.3 04/03/2023 15:56MADEP-EPH Aliphatic C9-C18 µg/L 28.2
Page 4 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-081-0100
Report Limit
Project:DOT-476
V 91862MW-4
J13904/03/2023 15:56MADEP-EPH Aromatic C11-C22 µg/L 61.2
J41.8 03/25/2023 12:31MADEP-VPH Aliphatic C5-C8 µg/L 11.5
J47.4 03/25/2023 12:31MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J9.91 03/25/2023 12:31MADEP-VPH Aromatic C9-C10 µg/L 4.02
Page 5 of 91

Client: Hart & Hickman (Charlotte) CASE NARRATIVE
Project: DOT-476 Lab Report Number: 23-081-0100
Date: 4/7/2023
625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Analyte: 1,2,4-Trichlorobenzene QC Batch No: V31390/V31295
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias. No hits in samples. No further action taken.
Analyte: 2-Chloronaphthalene
QC Batch No: V31390/V31295 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
No hits in samples. No further action taken.
Analyte: 3,3`-Dichlorobenzidine QC Batch No: V31390/V31295
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 4,6-Dinitro-2-methylphenol QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 4-Nitrophenol QC Batch No: V31390/V31295
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzo(a)anthracene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzo(a)pyrene QC Batch No: V31390/V31295
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Benzo(b)fluoranthene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzo(g,h,i)perylene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Benzo(k)fluoranthene QC Batch No: V31390/V31295
Page 6 of 91

Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzoic Acid
QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Bis(2-ethylhexyl)phthalate
QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Chrysene
QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Dibenz(a,h)anthracene
QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Di-n-octyl phthalate
QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Hexachloroethane QC Batch No: V31390/V31295 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
No hits in samples. No further action taken. Analyte: Indeno(1,2,3-cd)pyrene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Pentachlorophenol QC Batch No: V31390/V31295
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Phenanthrene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Pyrene QC Batch No: V31390/V31295 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Massachusetts EPH Method MADEP-EPH QC Batch No: V31552 LCS/LCSD ranges are above the accepted range. Reporting non-detects and reprepping hits. Sample 91859 (MW-1) QC Batch No: V31552 Out-of-hold reprep confirms original. Reprep had failing QC (low surrogate in LRB and LCS as well as low ALI C9-C18 range in LCS and LCSD).
Page 7 of 91

Sample 91860 (MW-2) QC Batch No: V31552
Out-of-hold reprep confirms original. Reprep had failing QC (low surrogate in LRB and LCS as well as low ALI C9-C18 range in LCS and LCSD).
Sample 91862 (MW-4)
QC Batch No: V31552 Out-of-hold reprep confirms original. Reprep had failing QC (low surrogate in LRB and LCS as well as low ALI C9-
C18 range in LCS and LCSD).
Analyte: 2-Bromonaphthalene QC Batch No: V31552/V31458
Fractionation surrogate 2-Bromonaphthalene is running high in entire batch due to concentrated standard. The other fractionation surrogate 2-Fluorobiphenyl is performing as expected which proved the fractionation process is
working.
Analyte: 2-Bromonaphthalene QC Batch No: V31552/V31458
Surrogate Out Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,1,1-Trichloroethane QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 1,1-Dichloroethane QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: 1,1-Dichloroethene
QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,1-Dichloropropene
QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichlorobenzene QC Batch No: V31449/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichlorobenzene
Page 8 of 91

QC Batch No: V31534/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2,3-Trichloropropane QC Batch No: V31534/V31446
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 1,2,4-Trichlorobenzene QC Batch No: V31449/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2,4-Trichlorobenzene QC Batch No: V31534/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 2,2-Dichloropropane QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 2-Butanone QC Batch No: V31534/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: 2-Chlorotoluene QC Batch No: V31449/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Analyte: Acetone QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Bromochloromethane QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Bromoform QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Page 9 of 91

Analyte: Bromoform
QC Batch No: V31598/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Bromomethane
QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Carbon Tetrachloride
QC Batch No: V31449/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Carbon Tetrachloride
QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Chloroform QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Chloromethane QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: cis-1,2-Dichloroethene
QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Ethanol QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Hexachlorobutadiene QC Batch No: V31449/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Hexachlorobutadiene QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Page 10 of 91

Analyte: Hexachlorobutadiene QC Batch No: V31598/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Methyl tert-butyl ether (MTBE) QC Batch No: V31598/V31446
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Methylene chloride QC Batch No: V31598/V31446
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: n-Butylbenzene QC Batch No: V31598/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: n-Propylbenzene QC Batch No: V31534/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: trans-1,2-Dichloroethene QC Batch No: V31534/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: trans-1,3-Dichloropropene QC Batch No: V31449/V31446
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Analyte: trans-1,3-Dichloropropene QC Batch No: V31534/V31446 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Analyte: Trichlorofluoromethane QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Vinyl acetate QC Batch No: V31598/V31446 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Vinyl chloride QC Batch No: V31598/V31446
Page 11 of 91

Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 12 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<18.0 µg/L 18.0 100Acetone 10 03/31/23 02:23 V31449MSA
8.36 µg/L 1.80 5.00Benzene 10 03/31/23 02:23 V31449MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 03/31/23 02:23 V31449MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 03/31/23 02:23 V31449MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 03/31/23 02:23 V31449MSA
<15.0 µg/L 15.0 50.0Bromoform 10 03/31/23 02:23 V31449MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 03/31/23 02:23 V31449MSA
10.7 µg/L 1.80 5.00n-Butylbenzene 10 03/31/23 02:23 V31449MSA
10.7 µg/L 2.00 5.00sec-Butyl benzene 10 03/31/23 02:23 V31449MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 03/31/23 02:23 V31449MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 03/31/23 02:23 V31449MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 03/31/23 02:23 V31449MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 03/31/23 02:23 V31449MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 03/31/23 02:23 V31449MSA
<2.20 µg/L 2.20 5.00Chloroform 10 03/31/23 02:23 V31449MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 03/31/23 02:23 V31449MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 03/31/23 02:23 V31449MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 03/31/23 02:23 V31449MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 03/31/23 02:23 V31449MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 03/31/23 02:23 V31449MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 03/31/23 02:23 V31449MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 03/31/23 02:23 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 13 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 03/31/23 02:23 V31449MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 03/31/23 02:23 V31449MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 03/31/23 02:23 V31449MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 03/31/23 02:23 V31449MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 03/31/23 02:23 V31449MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 03/31/23 02:23 V31449MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 03/31/23 02:23 V31449MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 03/31/23 02:23 V31449MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 03/31/23 02:23 V31449MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 03/31/23 02:23 V31449MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 03/31/23 02:23 V31449MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 03/31/23 02:23 V31449MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 03/31/23 02:23 V31449MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 03/31/23 02:23 V31449MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 03/31/23 02:23 V31449MSA
<420 µg/L 420 2000Ethanol 10 03/31/23 02:23 V31449MSA
3.38 J µg/L 1.70 5.00Ethylbenzene 10 03/31/23 02:23 V31449MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 03/31/23 02:23 V31449MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 03/31/23 02:23 V31449MSA
14.5 µg/L 1.80 5.00Isopropylbenzene 10 03/31/23 02:23 V31449MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 03/31/23 02:23 V31449MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 03/31/23 02:23 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 14 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 03/31/23 02:23 V31449MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 03/31/23 02:23 V31449MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 03/31/23 02:23 V31449MSA
30.3 µg/L 4.70 10.0Naphthalene 10 03/31/23 02:23 V31449MSA
42.5 µg/L 1.90 5.00n-Propylbenzene 10 03/31/23 02:23 V31449MSA
<2.20 µg/L 2.20 5.00Styrene 10 03/31/23 02:23 V31449MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 03/31/23 02:23 V31449MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 03/31/23 02:23 V31449MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 03/31/23 02:23 V31449MSA
<2.20 µg/L 2.20 5.00Toluene 10 03/31/23 02:23 V31449MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 03/31/23 02:23 V31449MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 03/31/23 02:23 V31449MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 03/31/23 02:23 V31449MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 03/31/23 02:23 V31449MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 03/31/23 02:23 V31449MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 03/31/23 02:23 V31449MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 03/31/23 02:23 V31449MSA
<1.90 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 03/31/23 02:23 V31449MSA
<1.80 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 03/31/23 02:23 V31449MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 03/31/23 02:23 V31449MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 03/31/23 02:23 V31449MSA
<2.10 µg/L 2.10 5.00o-Xylene 10 03/31/23 02:23 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 15 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<4.20 µg/L 4.20 10.0m,p-Xylene 10 03/31/23 02:23 V31449MSA
<2.1 µg/L 2.10 5.00Xylene (Total)10 03/31/23 02:23 V31449
Surrogate: 4-Bromofluorobenzene 98.6 Limits: 70-130%03/31/23 02:2310 MSA V31449
Surrogate: Dibromofluoromethane 102 Limits: 70-130%03/31/23 02:2310 MSA V31449
Surrogate: 1,2-Dichloroethane - d4 108 Limits: 70-130%03/31/23 02:2310 MSA V31449
Surrogate: Toluene-d8 102 Limits: 70-130%03/31/23 02:2310 MSA V31449
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
1.39 J µg/L 0.303 2.01Acenaphthene 1 03/29/23 21:19 V31440JMV
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/29/23 21:19 V31440JMV
<0.840 µg/L 0.840 2.01Anthracene 1 03/29/23 21:19 V31440JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/29/23 21:19 V31440JMV
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/29/23 21:19 V31440JMV
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/29/23 21:19 V31440JMV
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/29/23 21:19 V31440JMV
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/29/23 21:19 V31440JMV
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/29/23 21:19 V31440JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/29/23 21:19 V31440JMV
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/29/23 21:19 V31440JMV
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/29/23 21:19 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 16 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/29/23 21:19 V31440JMV
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/29/23 21:19 V31440JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/29/23 21:19 V31440JMV
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/29/23 21:19 V31440JMV
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/29/23 21:19 V31440JMV
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/29/23 21:19 V31440JMV
<7.42 µg/L 7.42 20.12-Chloronaphthalene 1 03/29/23 21:19 V31440JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/29/23 21:19 V31440JMV
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/29/23 21:19 V31440JMV
<0.407 µg/L 0.407 2.01Chrysene 1 03/29/23 21:19 V31440JMV
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/29/23 21:19 V31440JMV
1.30 J µg/L 0.861 5.03Dibenzofuran 1 03/29/23 21:19 V31440JMV
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/29/23 21:19 V31440JMV
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/29/23 21:19 V31440JMV
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/29/23 21:19 V31440JMV
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/29/23 21:19 V31440JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/29/23 21:19 V31440JMV
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/29/23 21:19 V31440JMV
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/29/23 21:19 V31440JMV
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/29/23 21:19 V31440JMV
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/29/23 21:19 V31440JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/29/23 21:19 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 17 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/29/23 21:19 V31440JMV
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/29/23 21:19 V31440JMV
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/29/23 21:19 V31440JMV
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/29/23 21:19 V31440JMV
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/29/23 21:19 V31440JMV
3.68 µg/L 0.811 2.01Fluorene 1 03/29/23 21:19 V31440JMV
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/29/23 21:19 V31440JMV
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/29/23 21:19 V31440JMV
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/29/23 21:19 V31440JMV
<1.77 µg/L 1.77 5.03Hexachloroethane 1 03/29/23 21:19 V31440JMV
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/29/23 21:19 V31440JMV
<0.446 µg/L 0.446 5.03Isophorone 1 03/29/23 21:19 V31440JMV
16.1 µg/L 1.15 2.011-Methylnaphthalene 1 03/29/23 21:19 V31440JMV
9.94 µg/L 0.669 2.012-Methylnaphthalene 1 03/29/23 21:19 V31440JMV
12.7 µg/L 0.731 2.01Naphthalene 1 03/29/23 21:19 V31440JMV
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/29/23 21:19 V31440JMV
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/29/23 21:19 V31440JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/29/23 21:19 V31440JMV
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/29/23 21:19 V31440JMV
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/29/23 21:19 V31440JMV
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/29/23 21:19 V31440JMV
2.70 µg/L 0.430 2.01Phenanthrene 1 03/29/23 21:19 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 18 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<0.654 µg/L 0.654 5.03Phenol 1 03/29/23 21:19 V31440JMV
<0.436 µg/L 0.436 2.01Pyrene 1 03/29/23 21:19 V31440JMV
<2.22 µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/29/23 21:19 V31440JMV
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/29/23 21:19 V31440JMV
625.1Surrogate: Phenol-d5 22.3 Limits: 10-63%03/29/23 21:191 JMV
Surrogate: 2-Fluorobiphenyl 73.6 Limits: 49-118%03/29/23 21:191 JMV V31440
Surrogate: 2-Fluorophenol 34.6 Limits: 22-84%03/29/23 21:191 JMV V31440
Surrogate: Nitrobenzene-d5 64.8 Limits: 43-123%03/29/23 21:191 JMV V31440
Surrogate: 4-Terphenyl-d14 88.3 Limits: 49-151%03/29/23 21:191 JMV V31440
Surrogate: 2,4,6-Tribromophenol 56.9 Limits: 31-144%03/29/23 21:191 JMV V31440
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 19 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
91859 Matrix:
3/21/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31458 03/31/23 12:50
70.5 J µg/L 28.2 350Aliphatic C9-C18 1 04/03/23 14:44 V31552AMP
<124 µg/L 124 500Aliphatic C19-C36 1 04/03/23 14:44 V31552AMP
728 µg/L 61.2 250Aromatic C11-C22 1 04/03/23 14:44 V31552AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%04/03/23 14:441 AMP
MADEP-EPHSurrogate: Chlorooctadecane 71.9 Limits: 40-140%04/03/23 14:441 AMP
MADEP-EPHSurrogate: OTP Surrogate 80.9 Limits: 40-140%04/03/23 14:441 AMP
Surrogate: 2-Fluorobiphenyl 99.8 Limits: 40-140%04/03/23 14:441 AMP V31552
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31197 03/24/23 08:00
758 µg/L 11.5 50.0Aliphatic C5-C8 1 03/25/23 12:08 V31198TBL
512 µg/L 25.8 50.0Aliphatic C9-C12 1 03/25/23 12:08 V31198TBL
229 µg/L 4.02 50.0Aromatic C9-C10 1 03/25/23 12:08 V31198TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)114 Limits: 70-130%03/25/23 12:081 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)98.5 Limits: 70-130%03/25/23 12:081 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 20 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/30/23 23:12 V31449MSA
0.848 µg/L 0.180 0.500Benzene 1 03/30/23 23:12 V31449MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/30/23 23:12 V31449MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/30/23 23:12 V31449MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/30/23 23:12 V31449MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/30/23 23:12 V31449MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/30/23 23:12 V31449MSA
0.325 J µg/L 0.200 0.500sec-Butyl benzene 1 03/30/23 23:12 V31449MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/30/23 23:12 V31449MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/30/23 23:12 V31449MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/30/23 23:12 V31449MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/30/23 23:12 V31449MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/30/23 23:12 V31449MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/30/23 23:12 V31449MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/30/23 23:12 V31449MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/30/23 23:12 V31449MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/30/23 23:12 V31449MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/30/23 23:12 V31449MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 03/30/23 23:12 V31449MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/30/23 23:12 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 21 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/30/23 23:12 V31449MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/30/23 23:12 V31449MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/30/23 23:12 V31449MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/30/23 23:12 V31449MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/30/23 23:12 V31449MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/30/23 23:12 V31449MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/30/23 23:12 V31449MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/30/23 23:12 V31449MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/30/23 23:12 V31449MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/30/23 23:12 V31449MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/30/23 23:12 V31449MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/30/23 23:12 V31449MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/30/23 23:12 V31449MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/30/23 23:12 V31449MSA
<42.0 µg/L 42.0 200Ethanol 1 03/30/23 23:12 V31449MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/30/23 23:12 V31449MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/30/23 23:12 V31449MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/30/23 23:12 V31449MSA
0.988 µg/L 0.180 0.500Isopropylbenzene 1 03/30/23 23:12 V31449MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/30/23 23:12 V31449MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/30/23 23:12 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 22 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/30/23 23:12 V31449MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/30/23 23:12 V31449MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/30/23 23:12 V31449MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 03/30/23 23:12 V31449MSA
1.97 µg/L 0.190 0.500n-Propylbenzene 1 03/30/23 23:12 V31449MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/30/23 23:12 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/30/23 23:12 V31449MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/30/23 23:12 V31449MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/30/23 23:12 V31449MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/30/23 23:12 V31449MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/30/23 23:12 V31449MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/30/23 23:12 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/30/23 23:12 V31449MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/30/23 23:12 V31449MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/30/23 23:12 V31449MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/30/23 23:12 V31449MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/30/23 23:12 V31449MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/30/23 23:12 V31449MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/30/23 23:12 V31449MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/30/23 23:12 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 23 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/30/23 23:12 V31449MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/30/23 23:12 V31449
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%03/30/23 23:121 MSA V31449
Surrogate: Dibromofluoromethane 89.4 Limits: 70-130%03/30/23 23:121 MSA V31449
Surrogate: 1,2-Dichloroethane - d4 111 Limits: 70-130%03/30/23 23:121 MSA V31449
Surrogate: Toluene-d8 113 Limits: 70-130%03/30/23 23:121 MSA V31449
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<0.303 µg/L 0.303 2.01Acenaphthene 1 03/29/23 21:42 V31440JMV
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/29/23 21:42 V31440JMV
<0.840 µg/L 0.840 2.01Anthracene 1 03/29/23 21:42 V31440JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/29/23 21:42 V31440JMV
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/29/23 21:42 V31440JMV
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/29/23 21:42 V31440JMV
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/29/23 21:42 V31440JMV
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/29/23 21:42 V31440JMV
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/29/23 21:42 V31440JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/29/23 21:42 V31440JMV
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/29/23 21:42 V31440JMV
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/29/23 21:42 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 24 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/29/23 21:42 V31440JMV
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/29/23 21:42 V31440JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/29/23 21:42 V31440JMV
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/29/23 21:42 V31440JMV
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/29/23 21:42 V31440JMV
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/29/23 21:42 V31440JMV
<7.42 µg/L 7.42 20.12-Chloronaphthalene 1 03/29/23 21:42 V31440JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/29/23 21:42 V31440JMV
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/29/23 21:42 V31440JMV
<0.407 µg/L 0.407 2.01Chrysene 1 03/29/23 21:42 V31440JMV
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/29/23 21:42 V31440JMV
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/29/23 21:42 V31440JMV
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/29/23 21:42 V31440JMV
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/29/23 21:42 V31440JMV
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/29/23 21:42 V31440JMV
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/29/23 21:42 V31440JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/29/23 21:42 V31440JMV
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/29/23 21:42 V31440JMV
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/29/23 21:42 V31440JMV
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/29/23 21:42 V31440JMV
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/29/23 21:42 V31440JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/29/23 21:42 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 25 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/29/23 21:42 V31440JMV
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/29/23 21:42 V31440JMV
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/29/23 21:42 V31440JMV
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/29/23 21:42 V31440JMV
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/29/23 21:42 V31440JMV
<0.811 µg/L 0.811 2.01Fluorene 1 03/29/23 21:42 V31440JMV
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/29/23 21:42 V31440JMV
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/29/23 21:42 V31440JMV
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/29/23 21:42 V31440JMV
<1.77 µg/L 1.77 5.03Hexachloroethane 1 03/29/23 21:42 V31440JMV
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/29/23 21:42 V31440JMV
<0.446 µg/L 0.446 5.03Isophorone 1 03/29/23 21:42 V31440JMV
<1.15 µg/L 1.15 2.011-Methylnaphthalene 1 03/29/23 21:42 V31440JMV
<0.669 µg/L 0.669 2.012-Methylnaphthalene 1 03/29/23 21:42 V31440JMV
<0.731 µg/L 0.731 2.01Naphthalene 1 03/29/23 21:42 V31440JMV
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/29/23 21:42 V31440JMV
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/29/23 21:42 V31440JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/29/23 21:42 V31440JMV
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/29/23 21:42 V31440JMV
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/29/23 21:42 V31440JMV
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/29/23 21:42 V31440JMV
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/29/23 21:42 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 26 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<0.654 µg/L 0.654 5.03Phenol 1 03/29/23 21:42 V31440JMV
<0.436 µg/L 0.436 2.01Pyrene 1 03/29/23 21:42 V31440JMV
<2.22 µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/29/23 21:42 V31440JMV
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/29/23 21:42 V31440JMV
625.1Surrogate: Phenol-d5 21.6 Limits: 10-63%03/29/23 21:421 JMV
Surrogate: 2-Fluorobiphenyl 71.8 Limits: 49-118%03/29/23 21:421 JMV V31440
Surrogate: 2-Fluorophenol 34.9 Limits: 22-84%03/29/23 21:421 JMV V31440
Surrogate: Nitrobenzene-d5 64.4 Limits: 43-123%03/29/23 21:421 JMV V31440
Surrogate: 4-Terphenyl-d14 87.3 Limits: 49-151%03/29/23 21:421 JMV V31440
Surrogate: 2,4,6-Tribromophenol 53.4 Limits: 31-144%03/29/23 21:421 JMV V31440
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 27 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
91860 Matrix:
3/21/2023 15:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31458 03/31/23 12:50
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 04/03/23 15:20 V31552AMP
<124 µg/L 124 500Aliphatic C19-C36 1 04/03/23 15:20 V31552AMP
61.2 J µg/L 61.2 250Aromatic C11-C22 1 04/03/23 15:20 V31552AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%04/03/23 15:201 AMP
MADEP-EPHSurrogate: Chlorooctadecane 68.4 Limits: 40-140%04/03/23 15:201 AMP
MADEP-EPHSurrogate: OTP Surrogate 79.4 Limits: 40-140%04/03/23 15:201 AMP
Surrogate: 2-Fluorobiphenyl 102 Limits: 40-140%04/03/23 15:201 AMP V31552
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31197 03/24/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 03/25/23 02:17 V31198TBL
34.6 J µg/L 25.8 50.0Aliphatic C9-C12 1 03/25/23 02:17 V31198TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 03/25/23 02:17 V31198TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.9 Limits: 70-130%03/25/23 02:171 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)75.4 Limits: 70-130%03/25/23 02:171 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 28 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/30/23 23:39 V31449MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/30/23 23:39 V31449MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/30/23 23:39 V31449MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/30/23 23:39 V31449MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/30/23 23:39 V31449MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/30/23 23:39 V31449MSA
1.21 µg/L 0.200 0.500sec-Butyl benzene 1 03/30/23 23:39 V31449MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/30/23 23:39 V31449MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/30/23 23:39 V31449MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/30/23 23:39 V31449MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/30/23 23:39 V31449MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/30/23 23:39 V31449MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/30/23 23:39 V31449MSA
1.10 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/30/23 23:39 V31449MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/30/23 23:39 V31449MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 03/30/23 23:39 V31449MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/30/23 23:39 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 29 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/30/23 23:39 V31449MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/30/23 23:39 V31449MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/30/23 23:39 V31449MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/30/23 23:39 V31449MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/30/23 23:39 V31449MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/30/23 23:39 V31449MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/30/23 23:39 V31449MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/30/23 23:39 V31449MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/30/23 23:39 V31449MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/30/23 23:39 V31449MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/30/23 23:39 V31449MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/30/23 23:39 V31449MSA
<42.0 µg/L 42.0 200Ethanol 1 03/30/23 23:39 V31449MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/30/23 23:39 V31449MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/30/23 23:39 V31449MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/30/23 23:39 V31449MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/30/23 23:39 V31449MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/30/23 23:39 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 30 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/30/23 23:39 V31449MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/30/23 23:39 V31449MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/30/23 23:39 V31449MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/30/23 23:39 V31449MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/30/23 23:39 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/30/23 23:39 V31449MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/30/23 23:39 V31449MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/30/23 23:39 V31449MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/30/23 23:39 V31449MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/30/23 23:39 V31449MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/30/23 23:39 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/30/23 23:39 V31449MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/30/23 23:39 V31449MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/30/23 23:39 V31449MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/30/23 23:39 V31449MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/30/23 23:39 V31449MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/30/23 23:39 V31449MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/30/23 23:39 V31449MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/30/23 23:39 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 31 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/30/23 23:39 V31449MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/30/23 23:39 V31449
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%03/30/23 23:391 MSA V31449
Surrogate: Dibromofluoromethane 93.4 Limits: 70-130%03/30/23 23:391 MSA V31449
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%03/30/23 23:391 MSA V31449
Surrogate: Toluene-d8 104 Limits: 70-130%03/30/23 23:391 MSA V31449
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
0.562 J µg/L 0.303 2.01Acenaphthene 1 03/29/23 00:08 V31390ANG
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/29/23 00:08 V31390ANG
<0.840 µg/L 0.840 2.01Anthracene 1 03/29/23 00:08 V31390ANG
<1.33 µg/L 1.33 10.1Benzidine 1 03/29/23 00:08 V31390ANG
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/29/23 00:08 V31390ANG
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/29/23 00:08 V31390ANG
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/29/23 00:08 V31390ANG
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/29/23 00:08 V31390ANG
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/29/23 00:08 V31390ANG
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/29/23 00:08 V31390ANG
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/29/23 00:08 V31390ANG
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/29/23 00:08 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 32 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/29/23 00:08 V31390ANG
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/29/23 00:08 V31390ANG
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/29/23 00:08 V31390ANG
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/29/23 00:08 V31390ANG
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/29/23 00:08 V31390ANG
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/29/23 00:08 V31390ANG
<7.42 M µg/L 7.42 20.12-Chloronaphthalene 1 03/29/23 00:08 V31390ANG
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/29/23 00:08 V31390ANG
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/29/23 00:08 V31390ANG
<0.407 µg/L 0.407 2.01Chrysene 1 03/29/23 00:08 V31390ANG
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/29/23 00:08 V31390ANG
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/29/23 00:08 V31390ANG
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/29/23 00:08 V31390ANG
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/29/23 00:08 V31390ANG
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/29/23 00:08 V31390ANG
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/29/23 00:08 V31390ANG
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/29/23 00:08 V31390ANG
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/29/23 00:08 V31390ANG
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/29/23 00:08 V31390ANG
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/29/23 00:08 V31390ANG
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/29/23 00:08 V31390ANG
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/29/23 00:08 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 33 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/29/23 00:08 V31390ANG
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/29/23 00:08 V31390ANG
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/29/23 00:08 V31390ANG
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/29/23 00:08 V31390ANG
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/29/23 00:08 V31390ANG
0.921 J µg/L 0.811 2.01Fluorene 1 03/29/23 00:08 V31390ANG
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/29/23 00:08 V31390ANG
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/29/23 00:08 V31390ANG
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/29/23 00:08 V31390ANG
<1.77 M µg/L 1.77 5.03Hexachloroethane 1 03/29/23 00:08 V31390ANG
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/29/23 00:08 V31390ANG
<0.446 µg/L 0.446 5.03Isophorone 1 03/29/23 00:08 V31390ANG
<1.15 µg/L 1.15 2.011-Methylnaphthalene 1 03/29/23 00:08 V31390ANG
<0.669 µg/L 0.669 2.012-Methylnaphthalene 1 03/29/23 00:08 V31390ANG
<0.731 µg/L 0.731 2.01Naphthalene 1 03/29/23 00:08 V31390ANG
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/29/23 00:08 V31390ANG
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/29/23 00:08 V31390ANG
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/29/23 00:08 V31390ANG
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/29/23 00:08 V31390ANG
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/29/23 00:08 V31390ANG
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/29/23 00:08 V31390ANG
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/29/23 00:08 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 34 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
91861 Matrix:
3/21/2023 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<0.654 µg/L 0.654 5.03Phenol 1 03/29/23 00:08 V31390ANG
<0.436 µg/L 0.436 2.01Pyrene 1 03/29/23 00:08 V31390ANG
<2.22 M µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/29/23 00:08 V31390ANG
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/29/23 00:08 V31390ANG
625.1Surrogate: Phenol-d5 26.3 Limits: 10-63%03/29/23 00:081 ANG
Surrogate: 2-Fluorobiphenyl 84.3 Limits: 49-118%03/29/23 00:081 ANG V31390
Surrogate: 2-Fluorophenol 39.1 Limits: 22-84%03/29/23 00:081 ANG V31390
Surrogate: Nitrobenzene-d5 72.0 Limits: 43-123%03/29/23 00:081 ANG V31390
Surrogate: 4-Terphenyl-d14 99.0 Limits: 49-151%03/29/23 00:081 ANG V31390
Surrogate: 2,4,6-Tribromophenol 64.3 Limits: 31-144%03/29/23 00:081 ANG V31390
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 35 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/31/23 00:06 V31449MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/31/23 00:06 V31449MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/31/23 00:06 V31449MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/31/23 00:06 V31449MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/31/23 00:06 V31449MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/31/23 00:06 V31449MSA
0.428 J µg/L 0.200 0.500sec-Butyl benzene 1 03/31/23 00:06 V31449MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/31/23 00:06 V31449MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/31/23 00:06 V31449MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/31/23 00:06 V31449MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/31/23 00:06 V31449MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/31/23 00:06 V31449MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/31/23 00:06 V31449MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/31/23 00:06 V31449MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/31/23 00:06 V31449MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 03/31/23 00:06 V31449MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/31/23 00:06 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 36 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/31/23 00:06 V31449MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/31/23 00:06 V31449MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/31/23 00:06 V31449MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/31/23 00:06 V31449MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/31/23 00:06 V31449MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/31/23 00:06 V31449MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/31/23 00:06 V31449MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/31/23 00:06 V31449MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/31/23 00:06 V31449MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/31/23 00:06 V31449MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/31/23 00:06 V31449MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/31/23 00:06 V31449MSA
<42.0 µg/L 42.0 200Ethanol 1 03/31/23 00:06 V31449MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/31/23 00:06 V31449MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/31/23 00:06 V31449MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/31/23 00:06 V31449MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/31/23 00:06 V31449MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/31/23 00:06 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 37 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/31/23 00:06 V31449MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/31/23 00:06 V31449MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/31/23 00:06 V31449MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/31/23 00:06 V31449MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/31/23 00:06 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/31/23 00:06 V31449MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/31/23 00:06 V31449MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/31/23 00:06 V31449MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/31/23 00:06 V31449MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/31/23 00:06 V31449MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/31/23 00:06 V31449MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/31/23 00:06 V31449MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/31/23 00:06 V31449MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/31/23 00:06 V31449MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/31/23 00:06 V31449MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/31/23 00:06 V31449MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/31/23 00:06 V31449MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/31/23 00:06 V31449MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/31/23 00:06 V31449MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 38 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31446 03/30/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/31/23 00:06 V31449MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/31/23 00:06 V31449
Surrogate: 4-Bromofluorobenzene 117 Limits: 70-130%03/31/23 00:061 MSA V31449
Surrogate: Dibromofluoromethane 106 Limits: 70-130%03/31/23 00:061 MSA V31449
Surrogate: 1,2-Dichloroethane - d4 115 Limits: 70-130%03/31/23 00:061 MSA V31449
Surrogate: Toluene-d8 98.4 Limits: 70-130%03/31/23 00:061 MSA V31449
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
0.602 J µg/L 0.303 2.01Acenaphthene 1 03/28/23 23:44 V31390ANG
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/28/23 23:44 V31390ANG
<0.840 µg/L 0.840 2.01Anthracene 1 03/28/23 23:44 V31390ANG
<1.33 µg/L 1.33 10.1Benzidine 1 03/28/23 23:44 V31390ANG
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/28/23 23:44 V31390ANG
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/28/23 23:44 V31390ANG
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/28/23 23:44 V31390ANG
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/28/23 23:44 V31390ANG
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/28/23 23:44 V31390ANG
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/28/23 23:44 V31390ANG
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/28/23 23:44 V31390ANG
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/28/23 23:44 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 39 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/28/23 23:44 V31390ANG
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/28/23 23:44 V31390ANG
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/28/23 23:44 V31390ANG
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/28/23 23:44 V31390ANG
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/28/23 23:44 V31390ANG
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/28/23 23:44 V31390ANG
<7.42 M µg/L 7.42 20.12-Chloronaphthalene 1 03/28/23 23:44 V31390ANG
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/28/23 23:44 V31390ANG
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/28/23 23:44 V31390ANG
<0.407 µg/L 0.407 2.01Chrysene 1 03/28/23 23:44 V31390ANG
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/28/23 23:44 V31390ANG
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/28/23 23:44 V31390ANG
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/28/23 23:44 V31390ANG
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/28/23 23:44 V31390ANG
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/28/23 23:44 V31390ANG
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/28/23 23:44 V31390ANG
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/28/23 23:44 V31390ANG
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/28/23 23:44 V31390ANG
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/28/23 23:44 V31390ANG
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/28/23 23:44 V31390ANG
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/28/23 23:44 V31390ANG
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/28/23 23:44 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 40 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/28/23 23:44 V31390ANG
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/28/23 23:44 V31390ANG
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/28/23 23:44 V31390ANG
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/28/23 23:44 V31390ANG
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/28/23 23:44 V31390ANG
<0.811 µg/L 0.811 2.01Fluorene 1 03/28/23 23:44 V31390ANG
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/28/23 23:44 V31390ANG
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/28/23 23:44 V31390ANG
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/28/23 23:44 V31390ANG
<1.77 M µg/L 1.77 5.03Hexachloroethane 1 03/28/23 23:44 V31390ANG
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/28/23 23:44 V31390ANG
<0.446 µg/L 0.446 5.03Isophorone 1 03/28/23 23:44 V31390ANG
<1.15 µg/L 1.15 2.011-Methylnaphthalene 1 03/28/23 23:44 V31390ANG
<0.669 µg/L 0.669 2.012-Methylnaphthalene 1 03/28/23 23:44 V31390ANG
<0.731 µg/L 0.731 2.01Naphthalene 1 03/28/23 23:44 V31390ANG
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/28/23 23:44 V31390ANG
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/28/23 23:44 V31390ANG
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/28/23 23:44 V31390ANG
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/28/23 23:44 V31390ANG
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/28/23 23:44 V31390ANG
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/28/23 23:44 V31390ANG
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/28/23 23:44 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 41 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<0.654 µg/L 0.654 5.03Phenol 1 03/28/23 23:44 V31390ANG
<0.436 µg/L 0.436 2.01Pyrene 1 03/28/23 23:44 V31390ANG
<2.22 M µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/28/23 23:44 V31390ANG
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/28/23 23:44 V31390ANG
625.1Surrogate: Phenol-d5 23.6 Limits: 10-63%03/28/23 23:441 ANG
Surrogate: 2-Fluorobiphenyl 76.3 Limits: 49-118%03/28/23 23:441 ANG V31390
Surrogate: 2-Fluorophenol 37.6 Limits: 22-84%03/28/23 23:441 ANG V31390
Surrogate: Nitrobenzene-d5 66.2 Limits: 43-123%03/28/23 23:441 ANG V31390
Surrogate: 4-Terphenyl-d14 88.3 Limits: 49-151%03/28/23 23:441 ANG V31390
Surrogate: 2,4,6-Tribromophenol 61.5 Limits: 31-144%03/28/23 23:441 ANG V31390
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 42 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-4
91862 Matrix:
3/20/2023 16:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31458 03/31/23 12:50
29.3 J µg/L 28.2 350Aliphatic C9-C18 1 04/03/23 15:56 V31552AMP
<124 µg/L 124 500Aliphatic C19-C36 1 04/03/23 15:56 V31552AMP
139 J µg/L 61.2 250Aromatic C11-C22 1 04/03/23 15:56 V31552AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene I *Limits: 40-140%04/03/23 15:561 AMP
MADEP-EPHSurrogate: Chlorooctadecane 68.0 Limits: 40-140%04/03/23 15:561 AMP
MADEP-EPHSurrogate: OTP Surrogate 73.0 Limits: 40-140%04/03/23 15:561 AMP
Surrogate: 2-Fluorobiphenyl 102 Limits: 40-140%04/03/23 15:561 AMP V31552
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31197 03/24/23 08:00
41.8 J µg/L 11.5 50.0Aliphatic C5-C8 1 03/25/23 12:31 V31198TBL
47.4 J µg/L 25.8 50.0Aliphatic C9-C12 1 03/25/23 12:31 V31198TBL
9.91 J µg/L 4.02 50.0Aromatic C9-C10 1 03/25/23 12:31 V31198TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.6 Limits: 70-130%03/25/23 12:311 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)82.1 Limits: 70-130%03/25/23 12:311 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 43 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31533 03/31/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500Benzene 1 03/31/23 15:21 V31534MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 03/31/23 15:21 V31534MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 03/31/23 15:21 V31534MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 03/31/23 15:21 V31534MSA
<1.50 µg/L 1.50 5.00Bromoform 1 03/31/23 15:21 V31534MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 03/31/23 15:21 V31534MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 03/31/23 15:21 V31534MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 03/31/23 15:21 V31534MSA
<0.220 µg/L 0.220 0.500Chloroform 1 03/31/23 15:21 V31534MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 03/31/23 15:21 V31534MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 03/31/23 15:21 V31534MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 03/31/23 15:21 V31534MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 03/31/23 15:21 V31534MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 44 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31533 03/31/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 03/31/23 15:21 V31534MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 03/31/23 15:21 V31534MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 03/31/23 15:21 V31534MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 03/31/23 15:21 V31534MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 03/31/23 15:21 V31534MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 03/31/23 15:21 V31534MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 03/31/23 15:21 V31534MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 03/31/23 15:21 V31534MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 03/31/23 15:21 V31534MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 03/31/23 15:21 V31534MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 03/31/23 15:21 V31534MSA
<42.0 µg/L 42.0 200Ethanol 1 03/31/23 15:21 V31534MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 03/31/23 15:21 V31534MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 03/31/23 15:21 V31534MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 03/31/23 15:21 V31534MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 03/31/23 15:21 V31534MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 03/31/23 15:21 V31534MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 45 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31533 03/31/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 03/31/23 15:21 V31534MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 03/31/23 15:21 V31534MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 03/31/23 15:21 V31534MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 03/31/23 15:21 V31534MSA
<0.220 µg/L 0.220 0.500Styrene 1 03/31/23 15:21 V31534MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 03/31/23 15:21 V31534MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 03/31/23 15:21 V31534MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 03/31/23 15:21 V31534MSA
<0.220 µg/L 0.220 0.500Toluene 1 03/31/23 15:21 V31534MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 03/31/23 15:21 V31534MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 03/31/23 15:21 V31534MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 03/31/23 15:21 V31534MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 03/31/23 15:21 V31534MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 03/31/23 15:21 V31534MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 03/31/23 15:21 V31534MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 03/31/23 15:21 V31534MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 03/31/23 15:21 V31534MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 03/31/23 15:21 V31534MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 03/31/23 15:21 V31534MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 46 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31533 03/31/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 03/31/23 15:21 V31534MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 03/31/23 15:21 V31534
Surrogate: 4-Bromofluorobenzene 116 Limits: 70-130%03/31/23 15:211 MSA V31534
Surrogate: Dibromofluoromethane 105 Limits: 70-130%03/31/23 15:211 MSA V31534
Surrogate: 1,2-Dichloroethane - d4 117 Limits: 70-130%03/31/23 15:211 MSA V31534
Surrogate: Toluene-d8 97.4 Limits: 70-130%03/31/23 15:211 MSA V31534
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<0.303 µg/L 0.303 2.01Acenaphthene 1 03/28/23 23:21 V31390ANG
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/28/23 23:21 V31390ANG
<0.840 µg/L 0.840 2.01Anthracene 1 03/28/23 23:21 V31390ANG
<1.33 µg/L 1.33 10.1Benzidine 1 03/28/23 23:21 V31390ANG
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/28/23 23:21 V31390ANG
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/28/23 23:21 V31390ANG
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/28/23 23:21 V31390ANG
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/28/23 23:21 V31390ANG
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/28/23 23:21 V31390ANG
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/28/23 23:21 V31390ANG
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/28/23 23:21 V31390ANG
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/28/23 23:21 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 47 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/28/23 23:21 V31390ANG
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/28/23 23:21 V31390ANG
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/28/23 23:21 V31390ANG
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/28/23 23:21 V31390ANG
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/28/23 23:21 V31390ANG
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/28/23 23:21 V31390ANG
<7.42 M µg/L 7.42 20.12-Chloronaphthalene 1 03/28/23 23:21 V31390ANG
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/28/23 23:21 V31390ANG
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/28/23 23:21 V31390ANG
<0.407 µg/L 0.407 2.01Chrysene 1 03/28/23 23:21 V31390ANG
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/28/23 23:21 V31390ANG
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/28/23 23:21 V31390ANG
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/28/23 23:21 V31390ANG
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/28/23 23:21 V31390ANG
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/28/23 23:21 V31390ANG
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/28/23 23:21 V31390ANG
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/28/23 23:21 V31390ANG
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/28/23 23:21 V31390ANG
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/28/23 23:21 V31390ANG
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/28/23 23:21 V31390ANG
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/28/23 23:21 V31390ANG
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/28/23 23:21 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 48 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/28/23 23:21 V31390ANG
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/28/23 23:21 V31390ANG
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/28/23 23:21 V31390ANG
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/28/23 23:21 V31390ANG
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/28/23 23:21 V31390ANG
<0.811 µg/L 0.811 2.01Fluorene 1 03/28/23 23:21 V31390ANG
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/28/23 23:21 V31390ANG
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/28/23 23:21 V31390ANG
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/28/23 23:21 V31390ANG
<1.77 M µg/L 1.77 5.03Hexachloroethane 1 03/28/23 23:21 V31390ANG
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/28/23 23:21 V31390ANG
<0.446 µg/L 0.446 5.03Isophorone 1 03/28/23 23:21 V31390ANG
<1.15 µg/L 1.15 2.011-Methylnaphthalene 1 03/28/23 23:21 V31390ANG
<0.669 µg/L 0.669 2.012-Methylnaphthalene 1 03/28/23 23:21 V31390ANG
<0.731 µg/L 0.731 2.01Naphthalene 1 03/28/23 23:21 V31390ANG
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/28/23 23:21 V31390ANG
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/28/23 23:21 V31390ANG
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/28/23 23:21 V31390ANG
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/28/23 23:21 V31390ANG
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/28/23 23:21 V31390ANG
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/28/23 23:21 V31390ANG
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/28/23 23:21 V31390ANG
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 49 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-5
91863 Matrix:
3/20/2023 15:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31217 03/27/23 11:43
<0.654 µg/L 0.654 5.03Phenol 1 03/28/23 23:21 V31390ANG
<0.436 µg/L 0.436 2.01Pyrene 1 03/28/23 23:21 V31390ANG
<2.22 M µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/28/23 23:21 V31390ANG
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/28/23 23:21 V31390ANG
625.1Surrogate: Phenol-d5 23.7 Limits: 10-63%03/28/23 23:211 ANG
Surrogate: 2-Fluorobiphenyl 77.7 Limits: 49-118%03/28/23 23:211 ANG V31390
Surrogate: 2-Fluorophenol 34.1 Limits: 22-84%03/28/23 23:211 ANG V31390
Surrogate: Nitrobenzene-d5 65.6 Limits: 43-123%03/28/23 23:211 ANG V31390
Surrogate: 4-Terphenyl-d14 96.6 Limits: 49-151%03/28/23 23:211 ANG V31390
Surrogate: 2,4,6-Tribromophenol 64.7 Limits: 31-144%03/28/23 23:211 ANG V31390
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 50 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31596 04/03/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500Benzene 1 04/03/23 14:40 V31598MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 04/03/23 14:40 V31598MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 04/03/23 14:40 V31598MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 04/03/23 14:40 V31598MSA
<1.50 µg/L 1.50 5.00Bromoform 1 04/03/23 14:40 V31598MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 04/03/23 14:40 V31598MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 04/03/23 14:40 V31598MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 04/03/23 14:40 V31598MSA
<0.220 µg/L 0.220 0.500Chloroform 1 04/03/23 14:40 V31598MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 04/03/23 14:40 V31598MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 04/03/23 14:40 V31598MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 04/03/23 14:40 V31598MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 04/03/23 14:40 V31598MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 51 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31596 04/03/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 04/03/23 14:40 V31598MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 04/03/23 14:40 V31598MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 04/03/23 14:40 V31598MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 04/03/23 14:40 V31598MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 04/03/23 14:40 V31598MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 04/03/23 14:40 V31598MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 04/03/23 14:40 V31598MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 04/03/23 14:40 V31598MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 04/03/23 14:40 V31598MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 04/03/23 14:40 V31598MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 04/03/23 14:40 V31598MSA
<42.0 µg/L 42.0 200Ethanol 1 04/03/23 14:40 V31598MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 04/03/23 14:40 V31598MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 04/03/23 14:40 V31598MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 04/03/23 14:40 V31598MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 04/03/23 14:40 V31598MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 04/03/23 14:40 V31598MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 52 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31596 04/03/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 04/03/23 14:40 V31598MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 04/03/23 14:40 V31598MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 04/03/23 14:40 V31598MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 04/03/23 14:40 V31598MSA
<0.220 µg/L 0.220 0.500Styrene 1 04/03/23 14:40 V31598MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 04/03/23 14:40 V31598MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 04/03/23 14:40 V31598MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 04/03/23 14:40 V31598MSA
<0.220 µg/L 0.220 0.500Toluene 1 04/03/23 14:40 V31598MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 04/03/23 14:40 V31598MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 04/03/23 14:40 V31598MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 04/03/23 14:40 V31598MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 04/03/23 14:40 V31598MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 04/03/23 14:40 V31598MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 04/03/23 14:40 V31598MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 04/03/23 14:40 V31598MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 04/03/23 14:40 V31598MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 04/03/23 14:40 V31598MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 04/03/23 14:40 V31598MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 53 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V31596 04/03/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 04/03/23 14:40 V31598MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 04/03/23 14:40 V31598
Surrogate: 4-Bromofluorobenzene 113 Limits: 70-130%04/03/23 14:401 MSA V31598
Surrogate: Dibromofluoromethane 98.0 Limits: 70-130%04/03/23 14:401 MSA V31598
Surrogate: 1,2-Dichloroethane - d4 111 Limits: 70-130%04/03/23 14:401 MSA V31598
Surrogate: Toluene-d8 108 Limits: 70-130%04/03/23 14:401 MSA V31598
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<0.303 µg/L 0.303 2.01Acenaphthene 1 03/29/23 20:56 V31440JMV
<0.298 µg/L 0.298 2.01Acenaphthylene 1 03/29/23 20:56 V31440JMV
<0.840 µg/L 0.840 2.01Anthracene 1 03/29/23 20:56 V31440JMV
<1.33 µg/L 1.33 10.1Benzidine 1 03/29/23 20:56 V31440JMV
<0.640 µg/L 0.640 2.01Benzo(a)anthracene 1 03/29/23 20:56 V31440JMV
<1.03 µg/L 1.03 2.01Benzo(a)pyrene 1 03/29/23 20:56 V31440JMV
<2.50 µg/L 2.50 5.03Benzo(b)fluoranthene 1 03/29/23 20:56 V31440JMV
<1.02 µg/L 1.02 5.03Benzo(g,h,i)perylene 1 03/29/23 20:56 V31440JMV
<2.00 µg/L 2.00 5.03Benzo(k)fluoranthene 1 03/29/23 20:56 V31440JMV
<1.11 µg/L 1.11 10.1Benzoic Acid 1 03/29/23 20:56 V31440JMV
<0.688 µg/L 0.688 5.03Benzyl alcohol 1 03/29/23 20:56 V31440JMV
<0.470 µg/L 0.470 5.03Bis(2-Chloroethoxy)methane 1 03/29/23 20:56 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 54 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.05 µg/L 1.05 5.03Bis(2-Chloroethyl)ether 1 03/29/23 20:56 V31440JMV
<1.09 µg/L 1.09 5.03Bis(2-Chloroisopropyl)ether 1 03/29/23 20:56 V31440JMV
<3.49 µg/L 3.49 10.1Bis(2-ethylhexyl)phthalate 1 03/29/23 20:56 V31440JMV
<1.12 µg/L 1.12 5.034-Bromophenyl phenyl ether 1 03/29/23 20:56 V31440JMV
<1.84 µg/L 1.84 5.03Butyl benzyl phthalate 1 03/29/23 20:56 V31440JMV
<1.19 µg/L 1.19 5.034-Chloro-3-methylphenol 1 03/29/23 20:56 V31440JMV
<7.42 µg/L 7.42 20.12-Chloronaphthalene 1 03/29/23 20:56 V31440JMV
<0.947 µg/L 0.947 10.12-Chlorophenol 1 03/29/23 20:56 V31440JMV
<1.72 µg/L 1.72 5.034-Chlorophenyl phenyl ether 1 03/29/23 20:56 V31440JMV
<0.407 µg/L 0.407 2.01Chrysene 1 03/29/23 20:56 V31440JMV
<0.436 µg/L 0.436 2.01Dibenz(a,h)anthracene 1 03/29/23 20:56 V31440JMV
<0.861 µg/L 0.861 5.03Dibenzofuran 1 03/29/23 20:56 V31440JMV
<2.01 µg/L 2.01 5.031,2-Dichlorobenzene 1 03/29/23 20:56 V31440JMV
<2.01 µg/L 2.01 5.031,3-Dichlorobenzene 1 03/29/23 20:56 V31440JMV
<2.06 µg/L 2.06 5.031,4-Dichlorobenzene 1 03/29/23 20:56 V31440JMV
<1.90 µg/L 1.90 5.033,3'-Dichlorobenzidine 1 03/29/23 20:56 V31440JMV
<1.47 µg/L 1.47 10.12,4-Dichlorophenol 1 03/29/23 20:56 V31440JMV
<0.749 µg/L 0.749 5.03Diethyl phthalate 1 03/29/23 20:56 V31440JMV
<0.944 µg/L 0.944 5.03Dimethyl phthalate 1 03/29/23 20:56 V31440JMV
<1.58 µg/L 1.58 20.12,4-Dimethylphenol 1 03/29/23 20:56 V31440JMV
<2.07 µg/L 2.07 5.03Di-n-butyl phthalate 1 03/29/23 20:56 V31440JMV
<2.09 µg/L 2.09 10.14,6-Dinitro-2-methylphenol 1 03/29/23 20:56 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 55 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<1.94 µg/L 1.94 10.12,4-Dinitrophenol 1 03/29/23 20:56 V31440JMV
<1.12 µg/L 1.12 5.032,4-Dinitrotoluene 1 03/29/23 20:56 V31440JMV
<0.813 µg/L 0.813 5.032,6-Dinitrotoluene 1 03/29/23 20:56 V31440JMV
<1.66 µg/L 1.66 5.03Di-n-Octyl Phthalate 1 03/29/23 20:56 V31440JMV
<0.251 µg/L 0.251 2.01Fluoranthene 1 03/29/23 20:56 V31440JMV
<0.811 µg/L 0.811 2.01Fluorene 1 03/29/23 20:56 V31440JMV
<0.984 µg/L 0.984 5.03Hexachlorobenzene 1 03/29/23 20:56 V31440JMV
<2.75 µg/L 2.75 5.03Hexachlorobutadiene 1 03/29/23 20:56 V31440JMV
<2.06 µg/L 2.06 5.03Hexachlorocyclopentadiene 1 03/29/23 20:56 V31440JMV
<1.77 µg/L 1.77 5.03Hexachloroethane 1 03/29/23 20:56 V31440JMV
<0.479 µg/L 0.479 2.01Indeno(1,2,3-cd)pyrene 1 03/29/23 20:56 V31440JMV
<0.446 µg/L 0.446 5.03Isophorone 1 03/29/23 20:56 V31440JMV
<1.15 µg/L 1.15 2.011-Methylnaphthalene 1 03/29/23 20:56 V31440JMV
<0.669 µg/L 0.669 2.012-Methylnaphthalene 1 03/29/23 20:56 V31440JMV
<0.731 µg/L 0.731 2.01Naphthalene 1 03/29/23 20:56 V31440JMV
<0.910 µg/L 0.910 5.03Nitrobenzene 1 03/29/23 20:56 V31440JMV
<0.495 µg/L 0.495 5.032-Nitrophenol 1 03/29/23 20:56 V31440JMV
<1.24 µg/L 1.24 10.14-Nitrophenol 1 03/29/23 20:56 V31440JMV
<1.11 µg/L 1.11 5.03N-Nitrosodiphenylamine 1 03/29/23 20:56 V31440JMV
<0.644 µg/L 0.644 5.03N-Nitroso-di-n-propylamine 1 03/29/23 20:56 V31440JMV
<1.44 µg/L 1.44 5.03Pentachlorophenol 1 03/29/23 20:56 V31440JMV
<0.430 µg/L 0.430 2.01Phenanthrene 1 03/29/23 20:56 V31440JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Method Quantitation LimitMQLMinimum valueM
Page 56 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28203
23-081-0100
01102
Hart & Hickman (Charlotte)
2923 South Tryon St. Ste 100
David Graham
Charlotte
Received : 03/22/2023
DOT-476
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:DW-1
91864 Matrix:
3/21/2023 10:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V31295 03/28/23 09:04
<0.654 µg/L 0.654 5.03Phenol 1 03/29/23 20:56 V31440JMV
<0.436 µg/L 0.436 2.01Pyrene 1 03/29/23 20:56 V31440JMV
<2.22 µg/L 2.22 5.031,2,4-Trichlorobenzene 1 03/29/23 20:56 V31440JMV
<1.33 µg/L 1.33 5.032,4,6-Trichlorophenol 1 03/29/23 20:56 V31440JMV
625.1Surrogate: Phenol-d5 19.7 Limits: 10-63%03/29/23 20:561 JMV
Surrogate: 2-Fluorobiphenyl 65.0 Limits: 49-118%03/29/23 20:561 JMV V31440
Surrogate: 2-Fluorophenol 32.1 Limits: 22-84%03/29/23 20:561 JMV V31440
Surrogate: Nitrobenzene-d5 57.3 Limits: 43-123%03/29/23 20:561 JMV V31440
Surrogate: 4-Terphenyl-d14 77.5 Limits: 49-151%03/29/23 20:561 JMV V31440
Surrogate: 2,4,6-Tribromophenol 50.4 Limits: 31-144%03/29/23 20:561 JMV V31440
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Estimated valueJRecovery out of rangeI
Page 57 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
Associated Lab Samples: 91859, 91860, 91861, 91862
LRB-V31446 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/30/23 17:4510.01.80<1.80µg/LAcetone
03/30/23 17:450.5000.180<0.180µg/LBenzene
03/30/23 17:450.5000.210<0.210µg/LBromobenzene
03/30/23 17:451.000.420<0.420µg/LBromochloromethane
03/30/23 17:450.5000.160<0.160µg/LBromodichloromethane
03/30/23 17:455.001.50<1.50µg/LBromoform
03/30/23 17:451.000.280<0.280µg/LBromomethane
03/30/23 17:450.5000.180<0.180µg/Ln-Butylbenzene
03/30/23 17:450.5000.200<0.200µg/Lsec-Butyl benzene
03/30/23 17:452.000.920<0.920µg/Ltert-Butyl benzene
03/30/23 17:450.5000.180<0.180µg/LCarbon Tetrachloride
03/30/23 17:450.5000.190<0.190µg/LChlorobenzene
03/30/23 17:450.5000.190<0.190µg/LChlorodibromomethane
03/30/23 17:451.000.430<0.430µg/LChloroethane
03/30/23 17:450.5000.220<0.220µg/LChloroform
03/30/23 17:450.5000.220<0.220µg/LChloromethane
03/30/23 17:450.5000.200<0.200µg/L2-Chlorotoluene
03/30/23 17:450.5000.200<0.200µg/L4-Chlorotoluene
03/30/23 17:450.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
03/30/23 17:452.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
03/30/23 17:450.5000.200<0.200µg/L1,2-Dibromoethane
03/30/23 17:450.5000.230<0.230µg/LDibromomethane
03/30/23 17:450.5000.220<0.220µg/L1,2-Dichlorobenzene
03/30/23 17:450.5000.190<0.190µg/L1,3-Dichlorobenzene
03/30/23 17:450.5000.210<0.210µg/L1,4-Dichlorobenzene
03/30/23 17:455.001.20<1.20µg/LDichlorodifluoromethane
03/30/23 17:450.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 32Date:04/07/2023 04:51 PM
Page 58 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
Associated Lab Samples: 91859, 91860, 91861, 91862
LRB-V31446 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/30/23 17:450.5000.150<0.150µg/L1,2-Dichloroethane
03/30/23 17:450.5000.150<0.150µg/L1,1-Dichloroethene
03/30/23 17:450.5000.200<0.200µg/Lcis-1,2-Dichloroethene
03/30/23 17:450.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
03/30/23 17:450.5000.190<0.190µg/L1,2-Dichloropropane
03/30/23 17:450.5000.130<0.130µg/L1,3-Dichloropropane
03/30/23 17:452.000.210<0.210µg/L2,2-Dichloropropane
03/30/23 17:450.5000.200<0.200µg/L1,1-Dichloropropene
03/30/23 17:450.5000.210<0.210µg/Lcis-1,3-Dichloropropene
03/30/23 17:450.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
03/30/23 17:4520042.0<42.0µg/LEthanol
03/30/23 17:450.5000.170<0.170µg/LEthylbenzene
03/30/23 17:453.000.350<0.350µg/LHexachlorobutadiene
03/30/23 17:451.000.380<0.380µg/L2-Hexanone
03/30/23 17:450.5000.180<0.180µg/LIsopropylbenzene
03/30/23 17:450.5000.089<0.089µg/L4-Isopropyl toluene
03/30/23 17:455.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
03/30/23 17:451.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
03/30/23 17:451.000.078<0.078µg/L4-Methyl-2-Pentanone
03/30/23 17:452.000.330<0.330µg/LMethylene Chloride
03/30/23 17:451.000.470<0.470µg/LNaphthalene
03/30/23 17:450.5000.190<0.190µg/Ln-Propylbenzene
03/30/23 17:450.5000.220<0.220µg/LStyrene
03/30/23 17:450.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
03/30/23 17:450.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
03/30/23 17:450.5000.220<0.220µg/LTetrachloroethene
03/30/23 17:450.5000.220<0.220µg/LToluene
Page 2 of 32Date:04/07/2023 04:51 PM
Page 59 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
Associated Lab Samples: 91859, 91860, 91861, 91862
LRB-V31446 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/30/23 17:450.5000.380<0.380µg/L1,2,3-Trichlorobenzene
03/30/23 17:450.5000.310<0.310µg/L1,2,4-Trichlorobenzene
03/30/23 17:450.5000.160<0.160µg/L1,1,1-Trichloroethane
03/30/23 17:450.5000.096<0.096µg/L1,1,2-Trichloroethane
03/30/23 17:450.5000.180<0.180µg/LTrichloroethene
03/30/23 17:450.5000.180<0.180µg/LTrichlorofluoromethane
03/30/23 17:450.5000.270<0.270µg/L1,2,3-Trichloropropane
03/30/23 17:450.5000.190<0.190µg/L1,2,4-Trimethylbenzene
03/30/23 17:450.5000.180<0.180µg/L1,3,5-Trimethylbenzene
03/30/23 17:455.001.00<1.00µg/LVinyl Acetate
03/30/23 17:450.5000.170<0.170µg/LVinyl Chloride
03/30/23 17:450.5000.210<0.210µg/Lo-Xylene
03/30/23 17:451.000.420<0.420µg/Lm,p-Xylene
03/30/23 17:454-Bromofluorobenzene (S)85.8 70-130
03/30/23 17:45Dibromofluoromethane (S)104 70-130
03/30/23 17:451,2-Dichloroethane - d4 (S)116 70-130
03/30/23 17:45Toluene-d8 (S)92.4 70-130
LCS-V31446 LCSD-V31446Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.6 99.010441.440.0µg/LAcetone 40-160 4.4 20.0
18.2 91.093.018.620.0µg/LBenzene 70-130 2.1 20.0
25.3 12712124.220.0µg/LBromobenzene 70-130 4.4 20.0
20.6 10311623.120.0µg/LBromochloromethane 70-130 11.4 20.0
24.9 12511422.720.0µg/LBromodichloromethane 70-130 9.2 20.0
Page 3 of 32Date:04/07/2023 04:51 PM
Page 60 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
LCS-V31446 LCSD-V31446Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.3 11711222.420.0µg/LBromoform 70-130 3.9 20.0
24.0 12011523.020.0µg/LBromomethane 60-140 4.2 20.0
24.4 12211322.520.0µg/Ln-Butylbenzene 70-130 8.1 20.0
22.8 11410721.420.0µg/Lsec-Butyl benzene 70-130 6.3 20.0
25.2 12610821.620.0µg/Ltert-Butyl benzene 70-130 15.3 20.0
21.3 10710420.820.0µg/LChlorobenzene 70-130 2.3 20.0
23.1 11610521.020.0µg/LChlorodibromomethane 70-130 9.5 20.0
18.7 93.510120.220.0µg/LChloroethane 60-140 7.7 20.0
20.6 10311222.320.0µg/LChloroform 70-130 7.9 20.0
17.3 86.586.517.320.0µg/LChloromethane 60-140 0.0 20.0
24.9 12511823.520.0µg/L4-Chlorotoluene 70-130 5.7 20.0
18.2 91.090.018.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.1 20.0
22.2 11111022.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 0.9 20.0
22.4 11210821.620.0µg/L1,2-Dibromoethane 70-130 3.6 20.0
24.7 12410621.220.0µg/LDibromomethane 70-130 15.2 20.0
22.7 11410621.220.0µg/L1,2-Dichlorobenzene 70-130 6.8 20.0
23.5 11810621.120.0µg/L1,3-Dichlorobenzene 70-130 10.7 20.0
22.3 11210821.620.0µg/L1,4-Dichlorobenzene 70-130 3.1 20.0
19.9 99.511021.920.0µg/LDichlorodifluoromethane 60-140 9.5 20.0
19.8 99.097.019.420.0µg/L1,1-Dichloroethane 70-130 2.0 20.0
22.6 11311723.320.0µg/L1,2-Dichloroethane 70-130 3.0 20.0
20.4 10210821.620.0µg/L1,1-Dichloroethene 70-130 5.7 20.0
20.4 10210821.620.0µg/Lcis-1,2-Dichloroethene 70-130 5.7 20.0
20.3 10210220.420.0µg/Ltrans-1,2-Dichloroethene 70-130 0.4 20.0
23.0 11598.019.620.0µg/L1,2-Dichloropropane 70-130 15.9 20.0
21.0 10598.019.620.0µg/L1,3-Dichloropropane 70-130 6.8 20.0
Page 4 of 32Date:04/07/2023 04:51 PM
Page 61 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
LCS-V31446 LCSD-V31446Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.3 11711723.420.0µg/L2,2-Dichloropropane 70-130 0.4 20.0
22.3 11211422.720.0µg/L1,1-Dichloropropene 70-130 1.7 20.0
24.8 12410921.820.0µg/Lcis-1,3-Dichloropropene 70-130 12.8 20.0
26.7 134*136*27.220.0µg/Ltrans-1,3-Dichloropropene 70-130 1.8 20.0
517 103109543500µg/LEthanol 60-140 4.9 20.0
21.1 10698.019.620.0µg/LEthylbenzene 70-130 7.3 20.0
22.1 11191.018.220.0µg/L2-Hexanone 60-140 19.3 20.0
24.7 12412324.520.0µg/LIsopropylbenzene 70-130 0.8 20.0
24.2 12111422.820.0µg/L4-Isopropyl toluene 70-130 5.9 20.0
17.6 88.081.516.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 7.6 20.0
19.8 99.010521.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 5.8 20.0
24.6 12311422.720.0µg/L4-Methyl-2-Pentanone 60-140 8.0 20.0
21.1 10610621.220.0µg/LMethylene Chloride 70-130 0.4 20.0
22.8 11412825.620.0µg/LNaphthalene 70-130 11.5 20.0
24.3 12211723.420.0µg/Ln-Propylbenzene 70-130 3.7 20.0
21.8 10911022.020.0µg/LStyrene 70-130 0.9 20.0
23.3 11711222.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 3.9 20.0
24.0 12011322.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 6.4 20.0
23.5 11810721.320.0µg/LTetrachloroethene 70-130 9.8 20.0
24.0 12010020.020.0µg/LToluene 70-130 18.1 20.0
22.5 11311723.320.0µg/L1,1,1-Trichloroethane 70-130 3.4 20.0
23.5 11812424.720.0µg/L1,1,2-Trichloroethane 70-130 4.9 20.0
23.2 11610521.020.0µg/LTrichloroethene 70-130 9.9 20.0
22.6 11312023.920.0µg/LTrichlorofluoromethane 60-140 5.5 20.0
24.3 12212024.020.0µg/L1,2,3-Trichloropropane 70-130 1.2 20.0
22.3 11210821.520.0µg/L1,2,4-Trimethylbenzene 70-130 3.6 20.0
Page 5 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 62 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31446
LCS-V31446 LCSD-V31446Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
25.8 12912424.720.0µg/L1,3,5-Trimethylbenzene 70-130 4.3 20.0
19.3 96.584.516.920.0µg/LVinyl Acetate 60-140 13.2 20.0
18.8 94.010220.320.0µg/LVinyl Chloride 60-140 7.6 20.0
22.0 11010621.120.0µg/Lo-Xylene 70-130 4.1 20.0
46.1 11510843.240.0µg/Lm,p-Xylene 70-130 6.4 20.0
1111154-Bromofluorobenzene (S)70-130
93.8105Dibromofluoromethane (S)70-130
1051151,2-Dichloroethane - d4 (S)70-130
99.881.6Toluene-d8 (S)70-130
Page 6 of 32Date:04/07/2023 04:51 PM
Page 63 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
Associated Lab Samples: 91863
LRB-V31533 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/31/23 14:2710.01.80<1.80µg/LAcetone
03/31/23 14:270.5000.180<0.180µg/LBenzene
03/31/23 14:270.5000.210<0.210µg/LBromobenzene
03/31/23 14:271.000.420<0.420µg/LBromochloromethane
03/31/23 14:270.5000.160<0.160µg/LBromodichloromethane
03/31/23 14:275.001.50<1.50µg/LBromoform
03/31/23 14:271.000.280<0.280µg/LBromomethane
03/31/23 14:270.5000.180<0.180µg/Ln-Butylbenzene
03/31/23 14:270.5000.200<0.200µg/Lsec-Butyl benzene
03/31/23 14:272.000.920<0.920µg/Ltert-Butyl benzene
03/31/23 14:270.5000.180<0.180µg/LCarbon Tetrachloride
03/31/23 14:270.5000.190<0.190µg/LChlorobenzene
03/31/23 14:270.5000.190<0.190µg/LChlorodibromomethane
03/31/23 14:271.000.430<0.430µg/LChloroethane
03/31/23 14:270.5000.220<0.220µg/LChloroform
03/31/23 14:270.5000.220<0.220µg/LChloromethane
03/31/23 14:270.5000.200<0.200µg/L2-Chlorotoluene
03/31/23 14:270.5000.200<0.200µg/L4-Chlorotoluene
03/31/23 14:270.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
03/31/23 14:272.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
03/31/23 14:270.5000.200<0.200µg/L1,2-Dibromoethane
03/31/23 14:270.5000.230<0.230µg/LDibromomethane
03/31/23 14:270.5000.220<0.220µg/L1,2-Dichlorobenzene
03/31/23 14:270.5000.190<0.190µg/L1,3-Dichlorobenzene
03/31/23 14:270.5000.210<0.210µg/L1,4-Dichlorobenzene
03/31/23 14:275.001.20<1.20µg/LDichlorodifluoromethane
03/31/23 14:270.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 32Date:04/07/2023 04:51 PM
Page 64 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
Associated Lab Samples: 91863
LRB-V31533 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/31/23 14:270.5000.150<0.150µg/L1,2-Dichloroethane
03/31/23 14:270.5000.150<0.150µg/L1,1-Dichloroethene
03/31/23 14:270.5000.200<0.200µg/Lcis-1,2-Dichloroethene
03/31/23 14:270.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
03/31/23 14:270.5000.190<0.190µg/L1,2-Dichloropropane
03/31/23 14:270.5000.130<0.130µg/L1,3-Dichloropropane
03/31/23 14:272.000.210<0.210µg/L2,2-Dichloropropane
03/31/23 14:270.5000.200<0.200µg/L1,1-Dichloropropene
03/31/23 14:270.5000.210<0.210µg/Lcis-1,3-Dichloropropene
03/31/23 14:270.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
03/31/23 14:2720042.0<42.0µg/LEthanol
03/31/23 14:270.5000.170<0.170µg/LEthylbenzene
03/31/23 14:273.000.350<0.350µg/LHexachlorobutadiene
03/31/23 14:271.000.380<0.380µg/L2-Hexanone
03/31/23 14:270.5000.180<0.180µg/LIsopropylbenzene
03/31/23 14:270.5000.089<0.089µg/L4-Isopropyl toluene
03/31/23 14:275.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
03/31/23 14:271.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
03/31/23 14:271.000.078<0.078µg/L4-Methyl-2-Pentanone
03/31/23 14:272.000.330<0.330µg/LMethylene Chloride
03/31/23 14:271.000.470<0.470µg/LNaphthalene
03/31/23 14:270.5000.190<0.190µg/Ln-Propylbenzene
03/31/23 14:270.5000.220<0.220µg/LStyrene
03/31/23 14:270.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
03/31/23 14:270.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
03/31/23 14:270.5000.220<0.220µg/LTetrachloroethene
03/31/23 14:270.5000.220<0.220µg/LToluene
Page 8 of 32Date:04/07/2023 04:51 PM
Page 65 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
Associated Lab Samples: 91863
LRB-V31533 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/31/23 14:270.5000.380<0.380µg/L1,2,3-Trichlorobenzene
03/31/23 14:270.5000.310<0.310µg/L1,2,4-Trichlorobenzene
03/31/23 14:270.5000.160<0.160µg/L1,1,1-Trichloroethane
03/31/23 14:270.5000.096<0.096µg/L1,1,2-Trichloroethane
03/31/23 14:270.5000.180<0.180µg/LTrichloroethene
03/31/23 14:270.5000.180<0.180µg/LTrichlorofluoromethane
03/31/23 14:270.5000.270<0.270µg/L1,2,3-Trichloropropane
03/31/23 14:270.5000.190<0.190µg/L1,2,4-Trimethylbenzene
03/31/23 14:270.5000.180<0.180µg/L1,3,5-Trimethylbenzene
03/31/23 14:275.001.00<1.00µg/LVinyl Acetate
03/31/23 14:270.5000.170<0.170µg/LVinyl Chloride
03/31/23 14:270.5000.210<0.210µg/Lo-Xylene
03/31/23 14:271.000.420<0.420µg/Lm,p-Xylene
03/31/23 14:274-Bromofluorobenzene (S)98.4 70-130
03/31/23 14:27Dibromofluoromethane (S)104 70-130
03/31/23 14:271,2-Dichloroethane - d4 (S)114 70-130
03/31/23 14:27Toluene-d8 (S)92.2 70-130
LCS-V31533Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11422.720.0µg/LBromochloromethane 70-130
10921.720.0µg/LBromoform 70-130
11222.420.0µg/LChloroform 70-130
11823.520.0µg/L1,1-Dichloroethane 70-130
11222.420.0µg/Lcis-1,2-Dichloroethene 70-130
12424.820.0µg/L2,2-Dichloropropane 70-130
Page 9 of 32Date:04/07/2023 04:51 PM
Page 66 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
LCS-V31533Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11623.220.0µg/L1,1-Dichloropropene 70-130
12725.320.0µg/L1,1,1-Trichloroethane 70-130
LCS-V31533 LCSD-V31533Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
48.1 12011546.140.0µg/LAcetone 40-160 4.2 20.0
24.3 12210120.120.0µg/LBenzene 70-130 18.9 20.0
26.0 13010721.320.0µg/LBromobenzene 70-130 19.8 20.0
23.2 11611623.120.0µg/LBromodichloromethane 70-130 0.4 20.0
23.4 11711222.420.0µg/LBromomethane 60-140 4.3 20.0
23.9 12011523.020.0µg/Ln-Butylbenzene 70-130 3.8 20.0
24.1 12110921.720.0µg/Lsec-Butyl benzene 70-130 10.4 20.0
25.1 12611021.920.0µg/Ltert-Butyl benzene 70-130 13.6 20.0
22.0 11011122.120.0µg/LChlorobenzene 70-130 0.4 20.0
22.6 11310721.420.0µg/LChlorodibromomethane 70-130 5.4 20.0
21.5 10895.519.120.0µg/LChloroethane 60-140 11.8 20.0
17.6 88.085.017.020.0µg/LChloromethane 60-140 3.4 20.0
25.6 12811623.120.0µg/L2-Chlorotoluene 70-130 10.2 20.0
24.9 12510621.220.0µg/L4-Chlorotoluene 70-130 16.0 20.0
25.0 12511222.420.0µg/LDi-Isopropyl Ether (DIPE)70-130 10.9 20.0
22.2 11111122.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 0.4 20.0
22.5 11311222.420.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
23.5 11810621.120.0µg/LDibromomethane 70-130 10.7 20.0
21.8 10911222.420.0µg/L1,2-Dichlorobenzene 70-130 2.7 20.0
23.3 11710721.320.0µg/L1,3-Dichlorobenzene 70-130 8.9 20.0
Page 10 of 32Date:04/07/2023 04:51 PM
Page 67 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
LCS-V31533 LCSD-V31533Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.5 10811022.020.0µg/L1,4-Dichlorobenzene 70-130 2.2 20.0
19.3 96.595.019.020.0µg/LDichlorodifluoromethane 60-140 1.5 20.0
25.5 12812224.420.0µg/L1,2-Dichloroethane 70-130 4.4 20.0
19.5 97.598.519.720.0µg/L1,2-Dichloropropane 70-130 1.0 20.0
21.1 10690.518.120.0µg/L1,3-Dichloropropane 70-130 15.3 20.0
22.1 11112625.120.0µg/Lcis-1,3-Dichloropropene 70-130 12.7 20.0
24.3 122137*27.420.0µg/Ltrans-1,3-Dichloropropene 70-130 11.9 20.0
687 137123614500µg/LEthanol 60-140 11.2 20.0
20.6 10310520.920.0µg/LEthylbenzene 70-130 1.4 20.0
18.8 94.096.519.320.0µg/L2-Hexanone 60-140 2.6 20.0
25.2 12612023.920.0µg/LIsopropylbenzene 70-130 5.2 20.0
25.7 12911522.920.0µg/L4-Isopropyl toluene 70-130 11.5 20.0
20.7 10483.516.720.0µg/LMethyl Ethyl Ketone (MEK)60-140 21.3*20.0
25.3 12712625.120.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.7 20.0
20.7 10411122.220.0µg/L4-Methyl-2-Pentanone 60-140 6.9 20.0
25.7 12912825.520.0µg/LMethylene Chloride 70-130 0.7 20.0
25.0 12511723.420.0µg/LNaphthalene 70-130 6.6 20.0
25.2 12610120.120.0µg/Ln-Propylbenzene 70-130 22.5*20.0
24.5 12310921.720.0µg/LStyrene 70-130 12.1 20.0
25.6 12811623.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 9.8 20.0
24.6 12310220.420.0µg/L1,1,2,2-Tetrachloroethane 70-130 18.6 20.0
23.1 11611522.920.0µg/LTetrachloroethene 70-130 0.8 20.0
22.3 11212524.920.0µg/LToluene 70-130 11.0 20.0
22.5 11312925.720.0µg/L1,1,2-Trichloroethane 70-130 13.2 20.0
23.5 11811222.320.0µg/LTrichloroethene 70-130 5.2 20.0
24.2 12112124.120.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
Page 11 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 68 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31534QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31533
LCS-V31533 LCSD-V31533Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.5 12393.518.720.0µg/L1,2,3-Trichloropropane 70-130 26.8*20.0
23.7 11910921.820.0µg/L1,2,4-Trimethylbenzene 70-130 8.3 20.0
25.5 12810721.420.0µg/L1,3,5-Trimethylbenzene 70-130 17.4 20.0
24.4 12210220.420.0µg/LVinyl Acetate 60-140 17.8 20.0
19.7 98.510420.720.0µg/LVinyl Chloride 60-140 4.9 20.0
24.4 12210521.020.0µg/Lo-Xylene 70-130 14.9 20.0
45.6 11411144.240.0µg/Lm,p-Xylene 70-130 3.1 20.0
1171014-Bromofluorobenzene (S)70-130
124104Dibromofluoromethane (S)70-130
1261121,2-Dichloroethane - d4 (S)70-130
97.296.6Toluene-d8 (S)70-130
Page 12 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 69 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
Associated Lab Samples: 91864
LRB-V31596 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/03/23 14:1210.01.80<1.80µg/LAcetone
04/03/23 14:120.5000.180<0.180µg/LBenzene
04/03/23 14:120.5000.210<0.210µg/LBromobenzene
04/03/23 14:121.000.420<0.420µg/LBromochloromethane
04/03/23 14:120.5000.160<0.160µg/LBromodichloromethane
04/03/23 14:125.001.50<1.50µg/LBromoform
04/03/23 14:121.000.280<0.280µg/LBromomethane
04/03/23 14:120.5000.180<0.180µg/Ln-Butylbenzene
04/03/23 14:120.5000.200<0.200µg/Lsec-Butyl benzene
04/03/23 14:122.000.920<0.920µg/Ltert-Butyl benzene
04/03/23 14:120.5000.180<0.180µg/LCarbon Tetrachloride
04/03/23 14:120.5000.190<0.190µg/LChlorobenzene
04/03/23 14:120.5000.190<0.190µg/LChlorodibromomethane
04/03/23 14:121.000.430<0.430µg/LChloroethane
04/03/23 14:120.5000.220<0.220µg/LChloroform
04/03/23 14:120.5000.220<0.220µg/LChloromethane
04/03/23 14:120.5000.200<0.200µg/L2-Chlorotoluene
04/03/23 14:120.5000.200<0.200µg/L4-Chlorotoluene
04/03/23 14:120.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
04/03/23 14:122.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
04/03/23 14:120.5000.200<0.200µg/L1,2-Dibromoethane
04/03/23 14:120.5000.230<0.230µg/LDibromomethane
04/03/23 14:120.5000.220<0.220µg/L1,2-Dichlorobenzene
04/03/23 14:120.5000.190<0.190µg/L1,3-Dichlorobenzene
04/03/23 14:120.5000.210<0.210µg/L1,4-Dichlorobenzene
04/03/23 14:125.001.20<1.20µg/LDichlorodifluoromethane
04/03/23 14:120.5000.240<0.240µg/L1,1-Dichloroethane
Page 13 of 32Date:04/07/2023 04:51 PM
Page 70 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
Associated Lab Samples: 91864
LRB-V31596 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/03/23 14:120.5000.150<0.150µg/L1,2-Dichloroethane
04/03/23 14:120.5000.150<0.150µg/L1,1-Dichloroethene
04/03/23 14:120.5000.200<0.200µg/Lcis-1,2-Dichloroethene
04/03/23 14:120.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
04/03/23 14:120.5000.190<0.190µg/L1,2-Dichloropropane
04/03/23 14:120.5000.130<0.130µg/L1,3-Dichloropropane
04/03/23 14:122.000.210<0.210µg/L2,2-Dichloropropane
04/03/23 14:120.5000.200<0.200µg/L1,1-Dichloropropene
04/03/23 14:120.5000.210<0.210µg/Lcis-1,3-Dichloropropene
04/03/23 14:120.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
04/03/23 14:1220042.0<42.0µg/LEthanol
04/03/23 14:120.5000.170<0.170µg/LEthylbenzene
04/03/23 14:123.000.350<0.350µg/LHexachlorobutadiene
04/03/23 14:121.000.380<0.380µg/L2-Hexanone
04/03/23 14:120.5000.180<0.180µg/LIsopropylbenzene
04/03/23 14:120.5000.089<0.089µg/L4-Isopropyl toluene
04/03/23 14:125.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
04/03/23 14:121.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
04/03/23 14:121.000.078<0.078µg/L4-Methyl-2-Pentanone
04/03/23 14:122.000.330<0.330µg/LMethylene Chloride
04/03/23 14:121.000.470<0.470µg/LNaphthalene
04/03/23 14:120.5000.190<0.190µg/Ln-Propylbenzene
04/03/23 14:120.5000.220<0.220µg/LStyrene
04/03/23 14:120.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
04/03/23 14:120.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
04/03/23 14:120.5000.220<0.220µg/LTetrachloroethene
04/03/23 14:120.5000.220<0.220µg/LToluene
Page 14 of 32Date:04/07/2023 04:51 PM
Page 71 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
Associated Lab Samples: 91864
LRB-V31596 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/03/23 14:120.5000.380<0.380µg/L1,2,3-Trichlorobenzene
04/03/23 14:120.5000.310<0.310µg/L1,2,4-Trichlorobenzene
04/03/23 14:120.5000.160<0.160µg/L1,1,1-Trichloroethane
04/03/23 14:120.5000.096<0.096µg/L1,1,2-Trichloroethane
04/03/23 14:120.5000.180<0.180µg/LTrichloroethene
04/03/23 14:120.5000.180<0.180µg/LTrichlorofluoromethane
04/03/23 14:120.5000.270<0.270µg/L1,2,3-Trichloropropane
04/03/23 14:120.5000.190<0.190µg/L1,2,4-Trimethylbenzene
04/03/23 14:120.5000.180<0.180µg/L1,3,5-Trimethylbenzene
04/03/23 14:125.001.00<1.00µg/LVinyl Acetate
04/03/23 14:120.5000.170<0.170µg/LVinyl Chloride
04/03/23 14:120.5000.210<0.210µg/Lo-Xylene
04/03/23 14:121.000.420<0.420µg/Lm,p-Xylene
04/03/23 14:124-Bromofluorobenzene (S)103 70-130
04/03/23 14:12Dibromofluoromethane (S)99.6 70-130
04/03/23 14:121,2-Dichloroethane - d4 (S)112 70-130
04/03/23 14:12Toluene-d8 (S)85.8 70-130
LCS-V31596 LCSD-V31596Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
41.1 10380.532.240.0µg/LAcetone 40-160 24.2*20.0
19.6 98.095.019.020.0µg/LBenzene 70-130 3.1 20.0
21.9 11010621.120.0µg/LBromobenzene 70-130 3.7 20.0
21.9 11010621.120.0µg/LBromochloromethane 70-130 3.7 20.0
22.6 11310721.320.0µg/LBromodichloromethane 70-130 5.9 20.0
Page 15 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 72 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
LCS-V31596 LCSD-V31596Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.9 89.568.013.620.0µg/LBromomethane 60-140 27.3*20.0
24.6 12311823.520.0µg/Ln-Butylbenzene 70-130 4.5 20.0
21.1 10610821.620.0µg/Lsec-Butyl benzene 70-130 2.3 20.0
22.3 11211021.920.0µg/Ltert-Butyl benzene 70-130 1.8 20.0
23.8 11912625.220.0µg/LCarbon Tetrachloride 70-130 5.7 20.0
20.8 10410621.120.0µg/LChlorobenzene 70-130 1.4 20.0
19.6 98.010821.620.0µg/LChlorodibromomethane 70-130 9.7 20.0
21.5 10898.519.720.0µg/LChloroethane 60-140 8.7 20.0
21.6 10810521.020.0µg/LChloroform 70-130 2.8 20.0
17.3 86.570.514.120.0µg/LChloromethane 60-140 20.3*20.0
23.0 11512024.020.0µg/L2-Chlorotoluene 70-130 4.2 20.0
20.5 10310420.820.0µg/L4-Chlorotoluene 70-130 1.4 20.0
19.8 99.084.516.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 15.8 20.0
23.1 11697.519.520.0µg/L1,2-Dibromo-3-Chloropropane 70-130 16.9 20.0
18.6 93.010220.420.0µg/L1,2-Dibromoethane 70-130 9.2 20.0
23.3 11710721.420.0µg/LDibromomethane 70-130 8.5 20.0
25.4 12710821.620.0µg/L1,2-Dichlorobenzene 70-130 16.1 20.0
21.7 10911122.120.0µg/L1,3-Dichlorobenzene 70-130 1.8 20.0
21.2 10610420.720.0µg/L1,4-Dichlorobenzene 70-130 2.3 20.0
20.6 10389.517.920.0µg/LDichlorodifluoromethane 60-140 14.0 20.0
20.3 10287.017.420.0µg/L1,1-Dichloroethane 70-130 15.3 20.0
22.7 11411723.420.0µg/L1,2-Dichloroethane 70-130 3.0 20.0
24.0 12010521.020.0µg/L1,1-Dichloroethene 70-130 13.3 20.0
21.3 10794.018.820.0µg/Lcis-1,2-Dichloroethene 70-130 12.4 20.0
21.5 10889.517.920.0µg/Ltrans-1,2-Dichloroethene 70-130 18.2 20.0
20.2 10195.019.020.0µg/L1,2-Dichloropropane 70-130 6.1 20.0
Page 16 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 73 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
LCS-V31596 LCSD-V31596Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.2 91.097.519.520.0µg/L1,3-Dichloropropane 70-130 6.8 20.0
24.3 12212023.920.0µg/L2,2-Dichloropropane 70-130 1.6 20.0
24.0 12011422.820.0µg/L1,1-Dichloropropene 70-130 5.1 20.0
23.1 11699.019.820.0µg/Lcis-1,3-Dichloropropene 70-130 15.3 20.0
20.0 10010721.320.0µg/Ltrans-1,3-Dichloropropene 70-130 6.2 20.0
519 10496.2481500µg/LEthanol 60-140 7.6 20.0
20.0 10097.519.520.0µg/LEthylbenzene 70-130 2.5 20.0
27.9 140*133*26.620.0µg/LHexachlorobutadiene 70-130 4.7 20.0
17.8 89.090.018.020.0µg/L2-Hexanone 60-140 1.1 20.0
23.1 11611022.020.0µg/LIsopropylbenzene 70-130 4.8 20.0
24.0 12011723.420.0µg/L4-Isopropyl toluene 70-130 2.5 20.0
16.4 82.087.017.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 5.9 20.0
23.1 11693.018.620.0µg/LMethyl tert-butyl ether (MTBE)70-130 21.5*20.0
17.3 86.589.017.820.0µg/L4-Methyl-2-Pentanone 60-140 2.8 20.0
21.1 10683.516.720.0µg/LMethylene Chloride 70-130 23.2*20.0
18.8 94.089.017.820.0µg/LNaphthalene 70-130 5.4 20.0
20.2 10110520.920.0µg/Ln-Propylbenzene 70-130 3.4 20.0
21.4 10712725.320.0µg/LStyrene 70-130 16.7 20.0
23.9 12011422.820.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.7 20.0
18.6 93.090.518.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.7 20.0
21.9 11012625.120.0µg/LTetrachloroethene 70-130 13.6 20.0
21.0 10595.019.020.0µg/LToluene 70-130 10.0 20.0
24.0 12012023.920.0µg/L1,2,3-Trichlorobenzene 70-130 0.4 20.0
23.3 11711823.520.0µg/L1,2,4-Trichlorobenzene 70-130 0.8 20.0
25.7 12912124.120.0µg/L1,1,1-Trichloroethane 70-130 6.4 20.0
17.9 89.587.517.520.0µg/L1,1,2-Trichloroethane 70-130 2.2 20.0
Page 17 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 74 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31598QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31596
LCS-V31596 LCSD-V31596Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.5 11311222.320.0µg/LTrichloroethene 70-130 0.8 20.0
24.9 12510220.320.0µg/LTrichlorofluoromethane 60-140 20.3*20.0
19.2 96.093.018.620.0µg/L1,2,3-Trichloropropane 70-130 3.1 20.0
21.7 10910921.820.0µg/L1,2,4-Trimethylbenzene 70-130 0.4 20.0
21.8 10911122.220.0µg/L1,3,5-Trimethylbenzene 70-130 1.8 20.0
21.7 10970.014.020.0µg/LVinyl Acetate 60-140 43.1*20.0
20.2 10179.515.920.0µg/LVinyl Chloride 60-140 23.8*20.0
21.6 10812324.520.0µg/Lo-Xylene 70-130 12.5 20.0
43.6 10911144.440.0µg/Lm,p-Xylene 70-130 1.8 20.0
10599.24-Bromofluorobenzene (S)70-130
100102Dibromofluoromethane (S)70-130
1091061,2-Dichloroethane - d4 (S)70-130
100106Toluene-d8 (S)70-130
Page 18 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 75 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
Associated Lab Samples: 91861, 91862, 91863
LRB-V31217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/28/23 15:382.000.302<0.302µg/LAcenaphthene
03/28/23 15:382.000.297<0.297µg/LAcenaphthylene
03/28/23 15:382.000.836<0.836µg/LAnthracene
03/28/23 15:3810.01.32<1.32µg/LBenzidine
03/28/23 15:382.000.637<0.637µg/LBenzo(a)anthracene
03/28/23 15:382.001.02<1.02µg/LBenzo(a)pyrene
03/28/23 15:385.002.49<2.49µg/LBenzo(b)fluoranthene
03/28/23 15:385.001.01<1.01µg/LBenzo(g,h,i)perylene
03/28/23 15:385.001.99<1.99µg/LBenzo(k)fluoranthene
03/28/23 15:3810.01.10<1.10µg/LBenzoic Acid
03/28/23 15:385.000.684<0.684µg/LBenzyl alcohol
03/28/23 15:385.000.468<0.468µg/LBis(2-Chloroethoxy)methane
03/28/23 15:385.001.04<1.04µg/LBis(2-Chloroethyl)ether
03/28/23 15:385.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
03/28/23 15:3810.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
03/28/23 15:385.001.11<1.11µg/L4-Bromophenyl phenyl ether
03/28/23 15:385.001.83<1.83µg/LButyl benzyl phthalate
03/28/23 15:385.001.18<1.18µg/L4-Chloro-3-methylphenol
03/28/23 15:3820.07.38<7.38µg/L2-Chloronaphthalene
03/28/23 15:3810.00.938<0.938µg/L2-Chlorophenol
03/28/23 15:385.001.71<1.71µg/L4-Chlorophenyl phenyl ether
03/28/23 15:382.000.405<0.405µg/LChrysene
03/28/23 15:382.000.434<0.434µg/LDibenz(a,h)anthracene
03/28/23 15:385.000.856<0.856µg/LDibenzofuran
03/28/23 15:385.002.00<2.00µg/L1,2-Dichlorobenzene
03/28/23 15:385.002.00<2.00µg/L1,3-Dichlorobenzene
03/28/23 15:385.002.05<2.05µg/L1,4-Dichlorobenzene
Page 19 of 32Date:04/07/2023 04:51 PM
Page 76 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
Associated Lab Samples: 91861, 91862, 91863
LRB-V31217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/28/23 15:385.001.89<1.89µg/L3,3'-Dichlorobenzidine
03/28/23 15:3810.01.46<1.46µg/L2,4-Dichlorophenol
03/28/23 15:385.000.745<0.745µg/LDiethyl phthalate
03/28/23 15:385.000.939<0.939µg/LDimethyl phthalate
03/28/23 15:3820.01.57<1.57µg/L2,4-Dimethylphenol
03/28/23 15:385.002.06<2.06µg/LDi-n-butyl phthalate
03/28/23 15:3810.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
03/28/23 15:3810.01.92<1.92µg/L2,4-Dinitrophenol
03/28/23 15:385.001.11<1.11µg/L2,4-Dinitrotoluene
03/28/23 15:385.000.809<0.809µg/L2,6-Dinitrotoluene
03/28/23 15:385.001.65<1.65µg/LDi-n-Octyl Phthalate
03/28/23 15:382.000.250<0.250µg/LFluoranthene
03/28/23 15:382.000.807<0.807µg/LFluorene
03/28/23 15:385.000.979<0.979µg/LHexachlorobenzene
03/28/23 15:385.002.73<2.73µg/LHexachlorobutadiene
03/28/23 15:385.002.05<2.05µg/LHexachlorocyclopentadiene
03/28/23 15:385.001.76<1.76µg/LHexachloroethane
03/28/23 15:382.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
03/28/23 15:385.000.444<0.444µg/LIsophorone
03/28/23 15:382.001.14<1.14µg/L1-Methylnaphthalene
03/28/23 15:382.000.666<0.666µg/L2-Methylnaphthalene
03/28/23 15:382.000.728<0.728µg/LNaphthalene
03/28/23 15:385.000.905<0.905µg/LNitrobenzene
03/28/23 15:385.000.493<0.493µg/L2-Nitrophenol
03/28/23 15:3810.01.23<1.23µg/L4-Nitrophenol
03/28/23 15:385.001.10<1.10µg/LN-Nitrosodiphenylamine
03/28/23 15:385.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 20 of 32Date:04/07/2023 04:51 PM
Page 77 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
Associated Lab Samples: 91861, 91862, 91863
LRB-V31217 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/28/23 15:385.001.43<1.43µg/LPentachlorophenol
03/28/23 15:382.000.428<0.428µg/LPhenanthrene
03/28/23 15:385.000.651<0.651µg/LPhenol
03/28/23 15:382.000.434<0.434µg/LPyrene
03/28/23 15:385.002.21<2.21µg/L1,2,4-Trichlorobenzene
03/28/23 15:385.001.32<1.32µg/L2,4,6-Trichlorophenol
03/28/23 15:382-Fluorobiphenyl (S)80.0 49-118
03/28/23 15:382-Fluorophenol (S)38.7 22-84
03/28/23 15:38Nitrobenzene-d5 (S)73.2 43-123
03/28/23 15:384-Terphenyl-d14 (S)101 49-151
03/28/23 15:382,4,6-Tribromophenol (S)64.8 31-144
03/28/23 15:38Phenol-d5 (S)25.0 10-63
LCS-V31217 LCSD-V31217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.2 66.455.227.650.0µg/LAcenaphthene 47-145 18.4 20.0
34.0 68.057.828.950.0µg/LAcenaphthylene 33-145 16.2 20.0
43.6 87.272.036.050.0µg/LAnthracene 27-133 19.0 20.0
9.14 18.217.68.8250.0µg/LBenzidine 15-150 3.5 20.0
42.9 85.869.234.650.0µg/LBenzo(a)anthracene 33-143 21.4*20.0
45.8 91.673.836.950.0µg/LBenzo(a)pyrene 17-163 21.5*20.0
42.7 85.468.034.050.0µg/LBenzo(b)fluoranthene 24-159 22.6*20.0
39.7 79.464.032.050.0µg/LBenzo(g,h,i)perylene 10-219 21.4*20.0
42.4 84.867.433.750.0µg/LBenzo(k)fluoranthene 11-162 22.8*20.0
16.4 32.826.413.250.0µg/LBenzoic Acid 10-125 21.6*20.0
Page 21 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 78 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
LCS-V31217 LCSD-V31217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
27.5 55.048.424.250.0µg/LBenzyl alcohol 16-107 12.7 20.0
33.6 67.259.629.850.0µg/LBis(2-Chloroethoxy)methane 33-184 11.9 20.0
26.7 53.446.823.450.0µg/LBis(2-Chloroethyl)ether 12-158 13.1 20.0
26.5 53.046.223.150.0µg/LBis(2-Chloroisopropyl)ether 36-166 13.7 20.0
46.5 93.074.437.250.0µg/LBis(2-ethylhexyl)phthalate 10-158 22.2*20.0
38.2 76.464.632.350.0µg/L4-Bromophenyl phenyl ether 53-127 16.7 20.0
46.9 93.876.838.450.0µg/LButyl benzyl phthalate 10-152 19.9 20.0
35.3 70.660.030.050.0µg/L4-Chloro-3-methylphenol 22-147 16.2 20.0
30.1 60.251.8*25.950.0µg/L2-Chloronaphthalene 60-118 15.0 20.0
26.4 52.847.023.550.0µg/L2-Chlorophenol 23-134 11.6 20.0
35.0 70.060.230.150.0µg/L4-Chlorophenyl phenyl ether 25-158 15.0 20.0
42.4 84.869.234.650.0µg/LChrysene 17-168 20.2*20.0
42.0 84.068.434.250.0µg/LDibenz(a,h)anthracene 10-227 20.4*20.0
34.8 69.658.429.250.0µg/LDibenzofuran 39-114 17.5 20.0
22.6 45.238.019.050.0µg/L1,2-Dichlorobenzene 32-129 17.3 20.0
21.8 43.637.018.550.0µg/L1,3-Dichlorobenzene 20-124 16.3 20.0
21.6 43.238.219.150.0µg/L1,4-Dichlorobenzene 20-124 12.2 20.0
41.5 83.065.832.950.0µg/L3,3'-Dichlorobenzidine 10-262 23.1*20.0
33.2 66.457.828.950.0µg/L2,4-Dichlorophenol 39-135 13.8 20.0
39.6 79.267.033.550.0µg/LDiethyl phthalate 10-114 16.6 20.0
39.2 78.466.033.050.0µg/LDimethyl phthalate 10-112 17.1 20.0
42.5 85.071.235.650.0µg/L2,4-Dimethylphenol 32-119 17.6 20.0
48.6 97.280.240.150.0µg/LDi-n-butyl phthalate 10-118 19.1 20.0
42.0 84.067.433.750.0µg/L4,6-Dinitro-2-methylphenol 10-181 21.9*20.0
38.0 76.065.232.650.0µg/L2,4-Dinitrophenol 10-191 15.2 20.0
39.3 78.665.632.850.0µg/L2,4-Dinitrotoluene 39-139 18.0 20.0
Page 22 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 79 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
LCS-V31217 LCSD-V31217Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
38.6 77.263.831.950.0µg/L2,6-Dinitrotoluene 50-158 19.0 20.0
47.1 94.275.237.650.0µg/LDi-n-Octyl Phthalate 10-146 22.4*20.0
40.7 81.466.833.450.0µg/LFluoranthene 26-137 19.7 20.0
36.9 73.861.030.550.0µg/LFluorene 59-121 18.9 20.0
36.7 73.461.630.850.0µg/LHexachlorobenzene 10-152 17.4 20.0
25.0 50.041.020.550.0µg/LHexachlorobutadiene 24-116 19.7 20.0
25.4 50.842.821.450.0µg/LHexachlorocyclopentadiene 32-117 17.0 20.0
21.5 43.035.4*17.750.0µg/LHexachloroethane 40-113 19.3 20.0
40.7 81.465.432.750.0µg/LIndeno(1,2,3-cd)pyrene 10-171 21.7*20.0
31.4 62.855.627.850.0µg/LIsophorone 21-196 12.1 20.0
26.9 53.846.823.450.0µg/L1-Methylnaphthalene 40-135 13.9 20.0
27.3 54.646.623.350.0µg/L2-Methylnaphthalene 18-121 15.8 20.0
26.6 53.246.623.350.0µg/LNaphthalene 21-133 13.2 20.0
29.0 58.050.825.450.0µg/LNitrobenzene 35-180 13.2 20.0
30.0 60.051.225.650.0µg/L2-Nitrophenol 29-182 15.8 20.0
20.4 40.832.616.350.0µg/L4-Nitrophenol 10-132 22.3*20.0
47.3 94.680.440.250.0µg/LN-Nitrosodiphenylamine 69-152 16.2 20.0
31.8 63.655.627.850.0µg/LN-Nitroso-di-n-propylamine 10-230 13.4 20.0
46.9 93.875.437.750.0µg/LPentachlorophenol 14-176 21.7*20.0
41.7 83.468.034.050.0µg/LPhenanthrene 54-120 20.3*20.0
13.4 26.823.411.750.0µg/LPhenol 10-112 13.5 20.0
43.5 87.071.035.550.0µg/LPyrene 52-115 20.2*20.0
24.3 48.641.2*20.650.0µg/L1,2,4-Trichlorobenzene 44-142 16.4 20.0
34.6 69.258.029.050.0µg/L2,4,6-Trichlorophenol 37-144 17.6 20.0
69.662.62-Fluorobiphenyl (S)49-118
31.427.42-Fluorophenol (S)22-84
Page 23 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 80 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31390QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31217
LCS-V31217 LCSD-V31217Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
59.854.4Nitrobenzene-d5 (S)43-123
92.475.24-Terphenyl-d14 (S)49-151
61.052.62,4,6-Tribromophenol (S)31-144
20.918.1Phenol-d5 (S)10-63
Page 24 of 32Date:04/07/2023 04:51 PM
Page 81 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
Associated Lab Samples: 91859, 91860, 91864
LRB-V31295 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/29/23 16:182.000.302<0.302µg/LAcenaphthene
03/29/23 16:182.000.297<0.297µg/LAcenaphthylene
03/29/23 16:182.000.836<0.836µg/LAnthracene
03/29/23 16:1810.01.32<1.32µg/LBenzidine
03/29/23 16:182.000.637<0.637µg/LBenzo(a)anthracene
03/29/23 16:182.001.02<1.02µg/LBenzo(a)pyrene
03/29/23 16:185.002.49<2.49µg/LBenzo(b)fluoranthene
03/29/23 16:185.001.01<1.01µg/LBenzo(g,h,i)perylene
03/29/23 16:185.001.99<1.99µg/LBenzo(k)fluoranthene
03/29/23 16:1810.01.10<1.10µg/LBenzoic Acid
03/29/23 16:185.000.684<0.684µg/LBenzyl alcohol
03/29/23 16:185.000.468<0.468µg/LBis(2-Chloroethoxy)methane
03/29/23 16:185.001.04<1.04µg/LBis(2-Chloroethyl)ether
03/29/23 16:185.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
03/29/23 16:1810.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
03/29/23 16:185.001.11<1.11µg/L4-Bromophenyl phenyl ether
03/29/23 16:185.001.83<1.83µg/LButyl benzyl phthalate
03/29/23 16:185.001.18<1.18µg/L4-Chloro-3-methylphenol
03/29/23 16:1820.07.38<7.38µg/L2-Chloronaphthalene
03/29/23 16:1810.00.938<0.938µg/L2-Chlorophenol
03/29/23 16:185.001.71<1.71µg/L4-Chlorophenyl phenyl ether
03/29/23 16:182.000.405<0.405µg/LChrysene
03/29/23 16:182.000.434<0.434µg/LDibenz(a,h)anthracene
03/29/23 16:185.000.856<0.856µg/LDibenzofuran
03/29/23 16:185.002.00<2.00µg/L1,2-Dichlorobenzene
03/29/23 16:185.002.00<2.00µg/L1,3-Dichlorobenzene
03/29/23 16:185.002.05<2.05µg/L1,4-Dichlorobenzene
Page 25 of 32Date:04/07/2023 04:51 PM
Page 82 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
Associated Lab Samples: 91859, 91860, 91864
LRB-V31295 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/29/23 16:185.001.89<1.89µg/L3,3'-Dichlorobenzidine
03/29/23 16:1810.01.46<1.46µg/L2,4-Dichlorophenol
03/29/23 16:185.000.745<0.745µg/LDiethyl phthalate
03/29/23 16:185.000.939<0.939µg/LDimethyl phthalate
03/29/23 16:1820.01.57<1.57µg/L2,4-Dimethylphenol
03/29/23 16:185.002.06<2.06µg/LDi-n-butyl phthalate
03/29/23 16:1810.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
03/29/23 16:1810.01.92<1.92µg/L2,4-Dinitrophenol
03/29/23 16:185.001.11<1.11µg/L2,4-Dinitrotoluene
03/29/23 16:185.000.809<0.809µg/L2,6-Dinitrotoluene
03/29/23 16:185.001.65<1.65µg/LDi-n-Octyl Phthalate
03/29/23 16:182.000.250<0.250µg/LFluoranthene
03/29/23 16:182.000.807<0.807µg/LFluorene
03/29/23 16:185.000.979<0.979µg/LHexachlorobenzene
03/29/23 16:185.002.73<2.73µg/LHexachlorobutadiene
03/29/23 16:185.002.05<2.05µg/LHexachlorocyclopentadiene
03/29/23 16:185.001.76<1.76µg/LHexachloroethane
03/29/23 16:182.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
03/29/23 16:185.000.444<0.444µg/LIsophorone
03/29/23 16:182.001.14<1.14µg/L1-Methylnaphthalene
03/29/23 16:182.000.666<0.666µg/L2-Methylnaphthalene
03/29/23 16:182.000.728<0.728µg/LNaphthalene
03/29/23 16:185.000.905<0.905µg/LNitrobenzene
03/29/23 16:185.000.493<0.493µg/L2-Nitrophenol
03/29/23 16:1810.01.23<1.23µg/L4-Nitrophenol
03/29/23 16:185.001.10<1.10µg/LN-Nitrosodiphenylamine
03/29/23 16:185.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 26 of 32Date:04/07/2023 04:51 PM
Page 83 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
Associated Lab Samples: 91859, 91860, 91864
LRB-V31295 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/29/23 16:185.001.43<1.43µg/LPentachlorophenol
03/29/23 16:182.000.428<0.428µg/LPhenanthrene
03/29/23 16:185.000.651<0.651µg/LPhenol
03/29/23 16:182.000.434<0.434µg/LPyrene
03/29/23 16:185.002.21<2.21µg/L1,2,4-Trichlorobenzene
03/29/23 16:185.001.32<1.32µg/L2,4,6-Trichlorophenol
03/29/23 16:182-Fluorobiphenyl (S)81.4 49-118
03/29/23 16:182-Fluorophenol (S)38.5 22-84
03/29/23 16:18Nitrobenzene-d5 (S)72.0 43-123
03/29/23 16:184-Terphenyl-d14 (S)102 49-151
03/29/23 16:182,4,6-Tribromophenol (S)63.1 31-144
03/29/23 16:18Phenol-d5 (S)25.1 10-63
LCS-V31295 LCSD-V31295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.6 79.280.840.450.0µg/LAcenaphthene 47-145 2.0 20.0
40.2 80.484.242.150.0µg/LAcenaphthylene 33-145 4.6 20.0
47.5 95.098.249.150.0µg/LAnthracene 27-133 3.3 20.0
17.7 35.435.817.950.0µg/LBenzidine 15-150 1.1 20.0
44.6 89.292.246.150.0µg/LBenzo(a)anthracene 33-143 3.3 20.0
48.9 97.810150.450.0µg/LBenzo(a)pyrene 17-163 3.0 20.0
43.8 87.690.445.250.0µg/LBenzo(b)fluoranthene 24-159 3.1 20.0
42.0 84.087.243.650.0µg/LBenzo(g,h,i)perylene 10-219 3.7 20.0
45.1 90.297.048.550.0µg/LBenzo(k)fluoranthene 11-162 7.2 20.0
18.5 37.035.817.950.0µg/LBenzoic Acid 10-125 3.2 20.0
Page 27 of 32Date:04/07/2023 04:51 PM
Page 84 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
LCS-V31295 LCSD-V31295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
35.2 70.471.835.950.0µg/LBenzyl alcohol 16-107 1.9 20.0
40.7 81.484.442.250.0µg/LBis(2-Chloroethoxy)methane 33-184 3.6 20.0
34.4 68.871.035.550.0µg/LBis(2-Chloroethyl)ether 12-158 3.1 20.0
35.4 70.872.036.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 1.6 20.0
49.4 98.810351.550.0µg/LBis(2-ethylhexyl)phthalate 10-158 4.1 20.0
41.7 83.486.843.450.0µg/L4-Bromophenyl phenyl ether 53-127 3.9 20.0
51.9 10410954.450.0µg/LButyl benzyl phthalate 10-152 4.7 20.0
40.2 80.482.241.150.0µg/L4-Chloro-3-methylphenol 22-147 2.2 20.0
37.2 74.477.438.750.0µg/L2-Chloronaphthalene 60-118 3.9 20.0
34.2 68.469.634.850.0µg/L2-Chlorophenol 23-134 1.7 20.0
40.0 80.083.241.650.0µg/L4-Chlorophenyl phenyl ether 25-158 3.9 20.0
43.7 87.491.845.950.0µg/LChrysene 17-168 4.9 20.0
44.2 88.492.846.450.0µg/LDibenz(a,h)anthracene 10-227 4.8 20.0
40.6 81.283.841.950.0µg/LDibenzofuran 39-114 3.1 20.0
28.0 56.057.828.950.0µg/L1,2-Dichlorobenzene 32-129 3.1 20.0
27.4 54.855.027.550.0µg/L1,3-Dichlorobenzene 20-124 0.3 20.0
28.0 56.055.627.850.0µg/L1,4-Dichlorobenzene 20-124 0.7 20.0
42.8 85.688.444.250.0µg/L3,3'-Dichlorobenzidine 10-262 3.2 20.0
39.5 79.081.840.950.0µg/L2,4-Dichlorophenol 39-135 3.4 20.0
45.2 90.493.046.550.0µg/LDiethyl phthalate 10-114 2.8 20.0
44.2 88.491.845.950.0µg/LDimethyl phthalate 10-112 3.7 20.0
50.0 10010452.050.0µg/L2,4-Dimethylphenol 32-119 3.9 20.0
52.2 10410753.650.0µg/LDi-n-butyl phthalate 10-118 2.6 20.0
45.0 90.094.247.150.0µg/L4,6-Dinitro-2-methylphenol 10-181 4.5 20.0
43.1 86.292.046.050.0µg/L2,4-Dinitrophenol 10-191 6.5 20.0
43.7 87.492.246.150.0µg/L2,4-Dinitrotoluene 39-139 5.3 20.0
Page 28 of 32Date:04/07/2023 04:51 PM
Page 85 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
LCS-V31295 LCSD-V31295Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
42.6 85.288.644.350.0µg/L2,6-Dinitrotoluene 50-158 3.9 20.0
51.2 10210853.950.0µg/LDi-n-Octyl Phthalate 10-146 5.1 20.0
42.8 85.687.643.850.0µg/LFluoranthene 26-137 2.3 20.0
42.6 85.288.844.450.0µg/LFluorene 59-121 4.1 20.0
38.8 77.680.440.250.0µg/LHexachlorobenzene 10-152 3.5 20.0
29.5 59.059.229.650.0µg/LHexachlorobutadiene 24-116 0.3 20.0
31.4 62.863.231.650.0µg/LHexachlorocyclopentadiene 32-117 0.6 20.0
27.1 54.255.427.750.0µg/LHexachloroethane 40-113 2.1 20.0
41.5 83.086.243.150.0µg/LIndeno(1,2,3-cd)pyrene 10-171 3.7 20.0
38.3 76.678.839.450.0µg/LIsophorone 21-196 2.8 20.0
32.2 64.466.833.450.0µg/L1-Methylnaphthalene 40-135 3.6 20.0
32.6 65.268.234.150.0µg/L2-Methylnaphthalene 18-121 4.4 20.0
32.7 65.467.233.650.0µg/LNaphthalene 21-133 2.7 20.0
36.5 73.074.237.150.0µg/LNitrobenzene 35-180 1.6 20.0
36.3 72.676.438.250.0µg/L2-Nitrophenol 29-182 5.1 20.0
23.1 46.247.223.650.0µg/L4-Nitrophenol 10-132 2.1 20.0
53.4 10710954.750.0µg/LN-Nitrosodiphenylamine 69-152 2.4 20.0
40.3 80.680.840.450.0µg/LN-Nitroso-di-n-propylamine 10-230 0.2 20.0
49.7 99.410351.750.0µg/LPentachlorophenol 14-176 3.9 20.0
45.1 90.292.246.150.0µg/LPhenanthrene 54-120 2.1 20.0
16.7 33.433.016.550.0µg/LPhenol 10-112 1.2 20.0
45.6 91.295.847.950.0µg/LPyrene 52-115 4.9 20.0
29.3 58.659.829.950.0µg/L1,2,4-Trichlorobenzene 44-142 2.0 20.0
39.8 79.682.441.250.0µg/L2,4,6-Trichlorophenol 37-144 3.4 20.0
83.689.82-Fluorobiphenyl (S)49-118
40.041.62-Fluorophenol (S)22-84
Page 29 of 32Date:04/07/2023 04:51 PM
Page 86 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V31440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V31295
LCS-V31295 LCSD-V31295Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
75.280.2Nitrobenzene-d5 (S)43-123
95.21024-Terphenyl-d14 (S)49-151
66.668.52,4,6-Tribromophenol (S)31-144
25.826.3Phenol-d5 (S)10-63
Page 30 of 32Date:04/07/2023 04:51 PM
Page 87 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V31552QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V31458
Associated Lab Samples: 91859, 91860, 91862
LRB-V31458 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/03/23 10:2935028.2<28.2µg/LAliphatic C9-C18
04/03/23 10:29500124<124µg/LAliphatic C19-C36
04/03/23 10:2925061.2<61.2µg/LAromatic C11-C22
04/03/23 10:292-Fluorobiphenyl (S)102 40-140
04/03/23 10:292-Bromonaphthalene (S)I 40-140
04/03/23 10:29Chlorooctadecane (S)103 40-140
04/03/23 10:29OTP Surrogate (S)105 40-140
LCS-V31458 LCSD-V31458Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1930 322*277*1660600µg/LAliphatic C9-C18 40-140 15.0 50.0
4400 550*473*3780800µg/LAliphatic C19-C36 40-140 15.1 50.0
2410 142*261*44301700µg/LAromatic C11-C22 40-140 59.0*50.0
90.784.72-Fluorobiphenyl (S)40-140
191*181*2-Bromonaphthalene (S)40-140
78.364.6Chlorooctadecane (S)40-140
73.667.5OTP Surrogate (S)40-140
Page 31 of 32* QC Fail Date:04/07/2023 04:51 PM
Page 88 of 91
Quality Control Data
23-081-0100Report No:
Project Description:
Client ID:Hart & Hickman (Charlotte)
DOT-476
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V31198QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V31197
Associated Lab Samples: 91859, 91860, 91862
LRB-V31197 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
03/24/23 19:1350.011.5<11.5µg/LAliphatic C5-C8
03/24/23 19:1350.025.8<25.8µg/LAliphatic C9-C12
03/24/23 19:1350.04.02<4.02µg/LAromatic C9-C10
03/24/23 19:132,5-Dibromotoluene (FID) (S)91.0 70-130
03/24/23 19:132,5-Dibromotoluene (PID) (S)79.6 70-130
LCS-V31197 LCSD-V31197Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
303 101102306300µg/LAliphatic C5-C8 70-130 0.9 50.0
358 119116349300µg/LAliphatic C9-C12 70-130 2.5 50.0
103 103104104100µg/LAromatic C9-C10 70-130 0.9 50.0
85.476.92,5-Dibromotoluene (FID) (S)70-130
80.776.92,5-Dibromotoluene (PID) (S)70-130
Page 32 of 32Date:04/07/2023 04:51 PM
Page 89 of 91
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-081-0100
Hart & Hickman (Charlotte)
01102
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 4.1 C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angela D Overcash Date & Time:03/22/2023 13:35:10
Special precautions or instructions included?
Comments:
Page 90 of 91
Page 91 of 91

Appendix C

Groundwater Sampling Forms

6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/21/23
98.97
12
DJH
7
Sunny, 55 F Be in um in at 1340
13:45
13:50
13:55
14:00
14:05
14:10
4.90
4.95
4.97
4.99
5.00
5.00
1 L
2 L
3 L
4 L
5 L
6 L
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
2.45
1.74
1.54
1.38
1.30
1.21
16.7
16.6
16.5
16.5
16.4
16.4
513.0
515.6
516.1
513.8
513.0
513.3
6.98
6.97
6.94
6.93
6.94
6.97
-48.0
-73.3
-82.9
-92.1
-97.3
-101.0
0.63
0.69
0.46
0.18
0.16
0.26
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
x3 40 mL VOAs MADEP VPH , and x2 1-L ambers MADEP EPH
Peristaltic
PVC
2 inch
14:10
Wa oint
MW-1
2 12
Pol eth lene
TOC
4.60 3/20/23TOCTOC
gallons
6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/21/23
98.63
12
DJH
7
Sunny, 57 F Be in um in at 1455
15:00
15:05
15:10
15:15
15:20
15:25
4.25
4.25
4.25
4.25
4.25
4.25
1 L
2 L
3 L
4 L
5 L
6 L
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
1.43
1.30
1.30
1.66
1.80
1.80
16.2
16.0
15.9
15.9
15.9
15.9
255.2
251.2
247.4
248.4
249.2
249.1
6.03
5.93
5.91
5.90
5.91
5.90
72.2
77.4
76.8
72.7
67.5
65.6
0.51
0.62
0.41
0.36
0.64
0.40
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
x3 40 mL VOAs MADEP VPH , and x2 1-L ambers MADEP EPH
Peristaltic
PVC
2 inch
15:25
Wa oint
MW-2
2 12
Pol eth lene
TOC
4.07 3/20/23TOCTOC
gallons
6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/21/23
98.41
12
DJH
7
Sunny, 20s F Be in um in at 0855
09:00
09:05
09:10
09:15
09:20
09:25
09:30
09:35
4.95
4.95
4.95
4.95
4.95
4.95
4.95
4.95
1 L
2 L
3 L
4 L
5 L
6 L
7 L
8 L
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
1.41
0.97
0.56
0.82
1.67
2.25
2.26
2.14
11.9
13.0
13.2
13.5
13.7
13.9
13.8
14.1
384.3
386.9
386.5
385.3
385.3
384.8
384.1
383.9
6.43
6.59
6.55
6.53
6.51
6.51
6.51
6.50
15.4
-41.0
-54.2
-63.6
-69.3
-74.5
-76.8
-78.9
18.40
10.00
8.51
8.15
8.90
5.83
5.21
2.80
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
Peristaltic
PVC
2 inch
09:35
Wa oint
MW-3
2 12
Pol eth lene
TOC
4.85 3/20/23TOCTOC
gallons
6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/21/23
97.64
12
DJH
7
Sunny, 49 F Be in um in at 15:35
15:40
15:45
15:50
15:55
16:00
16:05
16:10
4.43
4.43
4.43
4.44
4.44
4.44
4.44
1 L
2 L
3 L
4 L
5 L
6 L
7 L
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
0.81
0.43
0.55
1.89
2.38
2.52
2.46
14.9
14.8
14.6
14.6
14.4
14.5
14.5
672.0
673.0
672.0
671.0
672.0
672.0
673.0
6.16
6.15
6.12
6.17
6.17
6.17
6.14
45.6
18.8
5.1
-1.1
-4.8
-9.1
-11.8
0.85
0.70
0.56
2.09
0.71
0.78
0.37
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
x3 40 mL VOAs MADEP VPH , and x2 1-L ambers MADEP EPH
Peristaltic
PVC
2 inch
16:10
Wa oint
MW-4
2 12
Pol eth lene
TOC
4.39 3/20/23TOCTOC
gallons
6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/20/23
99.80
12
DJH
7
Sunny, 49 F Be in um in at 14:40
14:45
14:50
14:55
15:00
15:05
3.50
3.50
3.50
3.50
3.50
1 L
2 L
3 L
4 L
5 L
200 mL/min
200 mL/min
200 mL/min
200 mL/min
200 mL/min
6.05
5.75
5.43
5.45
5.40
12.7
12.7
12.7
12.6
12.6
588.3
592.2
598.4
602.2
602.1
6.65
6.02
5.92
5.93
5.91
156.7
175.6
181.5
183.0
182.8
1.20
1.08
0.87
0.63
0.68
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
Peristaltic
PVC
2 inch
15:05
Wa oint
MW-5
2 12
Pol eth lene
TOC
3.45 3/20/23TOCTOC
gallons
6?%%%0DVWHU7HPSODWHV?)RUPV)RUPV?/RZ)ORZ*URXQGZDWHU6DPSOLQJ)RUPSGI
/DVW8SGDWHG
Job No:
Well ID:
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time Level Pumped Rate (mg/l)(oC)(PS/cm)(SU)(mV)(NTU)
Stabilization Criteria
3ULPDU\6HFRQGDU\
LOW-FLOW GROUNDWATER
Other Sample Parameters:___________________________________________________________________________________________________
Sampled at:____________________________Parameters taken with:
Sample Delivered to:________________________________ by ______________________________________ at ____________________________.
Field Filtration: )Yes  No If yes, which sample parameters were field filtered:_____________________________________________
Sample Parameter Containers (Types, Number of Containers, Preservatives):
SAMPLING RECORDWell Location:
Facility Name:Date:
Top of Casing Elevation (ft msl):_______________ Casing Material:_______________ Volume of Water Per Well Volume:
Total Well Depth (ft:________________Depth to Water (ft :___________________________Well Diameter:
Sampling Personnel:___________________________BBBBBBBBBBBBBBBBBBBBBBBBBB6FUHHQ,QWHUYDOIW BBBBBBBBBBBBBBBBBBBBBBBBBBB
Type of Pump:____________________________ Tubing Material:____________________________ Pump/Tubing set at:_______________ft
Weather Conditions:_______________________________________________________NOTES:
*5281':$7(R SAMPLING PARAMETERS
6WDELOL]DWLRQFULWHULDJXLGHOLQHVIURPWKH(3$6(6'2SHUDWLQJ
3URFHGXUHIRU*URXQGZDWHU6DPSOLQJGDWHG$SULO
7XUE178VIRUPHWDOV
:DWHU/HYHOVOLJKWRUVWDEOH
GUDZGRZQGXULQJSXUJLQJ 
S+XQLW
6&RQG253P9
'2PJ/DOT-476
DOT Maintenance Facilit
Robbinsville, NC
3/21/23
99.27
50
DJH
45
Sunny, 40 F Be in um in at 10:00
10:05
10:10
10:15
10:20
10:25
10:30
10:35
5.55
6.12
6.49
6.71
6.98
7.15
7.26
1 L
2 L
2.5 L
3.0 L
3.5 L
4.0 L
4.5 L
200 mL/min
200 mL/min
100 mL/min
100 mL/min
100 mL/min
100 mL/min
100 mL/min
5.34
2.04
1.13
0.85
0.70
0.61
0.57
15.4
15.8
15.1
14.7
15.0
14.3
14.4
215.2
218.9
217.1
216.3
215.3
210.9
212.1
7.20
7.47
7.66
7.73
7.73
7.71
7.65
-52.9
-92.1
-119.8
-130.9
-135.2
-136.3
-135.4
8.18
5.49
7.17
5.05
1.48
1.45
1.21
N/A
YSI-003 and HACH-003
x3 40 mL VOAs 6200 VOCs , x2 1-L ambers SVOCs 625 ,
Peristaltic
PVC
2 inch
10:35
Wa oint
DW-1
40 50
Pol eth lene
TOC
4.65 3/20/23TOCTOC
gallons