AS-3030_28254_CA_LSA_20050303

~ > "' ;a; ;;:: lr.iJ s ~ J> ~:~ ::er ~ ,,_,--"' c=;-:J :-,-~~ "
STATE OF NORTH CAROLINA
DEPAR1MENT OF TRANSPORTATION
z::::;
?<!
C,
~ ~ =
""5 ~ n ~ liw ' 1501 MAILSERVICECENTER,RALEIGH,N.C. 27699-1501 = MICHAELF. EASLEY
GOVERNOR' SECRETARY
Mr. Dan Murphy
Division of Waste Management
2090 US Hwy 70 .
Swannanoa, North Carolina 28778
RE: LSA Report
NCDOT -Robbinsville
Incident # 28254
Dear Mr. Murphy:
March 3, 2005
Enclosed is the LSA report for the incident at the subject site. According to the report,
there are no supply wells within 1000 feet of the release. However, there is a creek
bordering the site. The site should be classified as intermediate. We are currently
looking for state-owned property available for land application of the stockpile. Since the
stockpile is mostly gravel from the tank pit, we may request a thicker application rate. If
you have questions, please call me at [phone].
Sincerely,
Eric Motzno, LG
Environmental Engineer
Encl
Cc: Kenneth Burrell
Equipment Superintendent
Equipment and Inventory Control Uni~ 4809 Beryl Road, Raleigh, NC 27606
Telephone [phone] FAX [phone]
' I
I ' '
I
I [
I I
I /
I I
I
, · · art & Hickman
Hart & Hickman, PC
2923 SouthTryon Street
Suite 100
Charlotte, NC 28203
704.586.0007
Fax [phone]
Phase II Limited Site Assessment
NC DOT -Maintenance Yard
40 State Shed Road
Robbinsville, North Carolina
H&H Job No. DOT-215
March 1, 2005
s:: )>
::0
.....,
"" = = u,
co
=
~
Su
=
~
M -------~
Phase II Limited Site Assessment Information
Site Location:
NC DOT Maintenance Yard
40 State Shed Road
Robbinsville, North Carolina 28771
Site Owner:
North Carolina Department of Transportation
4809 Beryl Road
Raleigh, North Carolina 27606
UST Owner & Operator:
North Carolina Department of Transportation
4809 Beryl Road
Raleigh, North Carolina 27606
Phone: [phone]
Contact: Mr. Eric Motzno, LG
General Site Information:
Facility ID Number: 0-024661
NC DENR Incident Number: 28254
Site Priority Ranking: Anticipate Intermediate
Land Use Category: Anticipate Industrial/Commercial
Latitude/Longitude: N35° 19' 13", W83° 48 5"
Release Discovery Date: August 2004
Estimated Quantity of Release: Unknown
Cause/Source of Release: Former gasoline and diesel fuel UST systems
Hart & Hickman, PC
Table of Contents
Section Page No.
: I
1.0 Executive Summary and Recommendation ........................................................................... !
2.0 Introduction and Site History ............................................................................................... .4
--1 3.0 Receptor Information and Risk Characterization ................................................................ 5
3.1 Water Supply Wells .............................................................................................................. .5
3.2 Surface Water ....................................................................................................................... .5
3.3 Subsurface Structures ............................................................................................................ 6
3 .4 Property Owners and Land Use ............................................................................................. 6
4.0 Geology and Hydrogeology .................................................................................................... 7
4.1 Regional Geology and Hydrogeology .................................................................................... 7
4.2 Site Geology .......................................................................................................................... 8
4.3 Site Hydro geology ................................................................................................................. 8
5.0 Sampling and Results .............................................................................................................. 9
5 .1 Previous Soil Sampling Results ............................................................................................. 9
5.2 Monitoring Well Installation and Ground Water Sampling .................................................. 9
5.3 Ground Water Sampling Results ......................................................................................... 11
s:\aaa-mastet projccts\nc dot\dot-215 robbiruvillc\tcxt\ph.ii Isa report.doc I Hart & Hickman, PC
' I
Table 1
Table 2
Table 3
Table4
Figure 1
Figure 2
Figure 3
Figure4
Figure 5
Figure 6
Appendix A
Appendix B
Appendix C
List of Tables
Summary of August 2004 Soil Sample Results
Adjacent Property Owner Information
Well Specifications and Water Level Elevations
Ground Water Analytical Detections
Site Location Map
Site Area Map
List of Figures
Site and Adjacent Properties Map
Shallow Ground Water Potentiometric Map
Benzene Isoconcentration Map
Total C9-C22 Aromatics Isoconcentration Map
List of Appendices
Risk Classification and Land Use Form
Boring Log and Well Construction Records
Laboratory Analytical Data Sheets
s:\aaa-master prop!ts\nc dol\dot-215 robbinsville\text\ph.ii Isa report.doc ii Hart & Hickman, PC
Phase II Limited Site Assessment
NC DOT Maintenance Yard
40 State Shed Road
Robbinsville, North Carolina
H&H Job No. DOT-215
1.0 Executive Summary and Recommendation
Hart & Hickman, PC (H&H) has completed a Phase II Limited Site Assessment (LSA) at the NC
DOT Maintenance Yard located at 40 State Shed Road in Robbinsville, Graham County, North
Carolina (Figure 1). Due to failing cathodic protection monitoring tests, a 5,700-gallon gasoline and
a 5,700-gallon diesel underground storage tank (UST) were removed by NC DOT on August 31,
2004. During excavation activities on August 26, 2004, the diesel product line leading to the
dispenser island was broken and approximately 1,000-gallons of diesel fuel was released.
Approximately 3,900-gallons of product and water were pumped from the UST basin using two 4-
inch diameter basin wells.
Nine soil samples (SS-1 through SS-9) were collected by NC DOT from the excavation sidewalls
and adjacent to the dispenser line and dispensers after UST removal activities on August 31, 2004.
Due to the presence of shallow ground water, soil samples were collected at depths ranging from 2.5
ft to 4 ft below grade. Bedrock was encountered in the former UST basin at a depth of
approximately 12 ft below grade. Each soil sample was submitted for analysis of extractable and
volatile petroleum hydrocarbons (EPHNPH), volatile organic compounds (VOCs), and semi­
volatile organic compounds (SVOCs). A water sample collected from the UST basin was submitted
for analysis of VOCs, SVOCs, lead, and VPH/EPH. Soil and water impacts were detected. This
LSA report was conducted to address the identified impacts resulting from the former gasoline and
diesel USTs and product lines.
Risk Characterization and Land Use
No drinking water wells were identified within 1,000 ft of the subject UST system. In addition,
ground water at the subject property is not impacted above DENR~defined Gross Contamination
1
s:\aaa-master pro,Xis\nc dot\dot•215 robbinsvilk\text\ph.ii ls.a report.doc
Hart & Hickman, PC
Levels (GCLs). One surface water body, Tulula Creek, is located approximately 200 ft west and
topographically downgradient of the source area. Since the creek is located less than 500 ft from the
source area, and select ground water constituents exceed 10 times surface water quality
standards/criteria, the site appears to qualify for an intermediate risk classification.
The site is located in an area containing light industrial, commercial, and residential properties. The
site and adjacent properties are used for light industrial and commercial purposes. According to
Graham County employees, there is no zoning within the county. Based on this information, the site
qualifies for a commercial/industrial land use classification.
LSA Results
Soil Results
Due to the shallow depth of ground water, no additional soil samples were collected during Phase
LSA activities. Impacts were detected in the UST basin sidewalls, near the dispensers, and along
the product pipeline. Risk-based soil samples collected at the time of UST closure .indicate the
presence of soil impacts above Soil-to-Ground Water and Residential Maximum Soil Contaminant
Concentrations (MSCCs). No impacts were detected above Industrial MSCCs.
Ground Water Results
As part of LSA activities, H&R constructed five shallow Type II monitor wells (MW-1 through
MW-5) and one deeper Type ill monitoring well (DW-1) at the. site. Monitoring wells MW-1 and
DW-1 were installed adjacent to the former UST basin; MW-2 was installed adjacent to the fuel
dispenser lines and fuel dispensers; MW-3 and MW-4 were installed topographically downgradient
of the source areas near the site property corners; and MW-5 was installed topographically
upgradient of the source areas.
Ground water samples were collected from each well and submitted for laboratory analysis of
VOCs, SVOCs including tentatively identified compounds (TICs), lead, and EPH/VPH. Select
VOCs including benzene, ethylbenzene, methyl tert-butyl ether (MTBE), n-propylbenzene, and
naphthalene exceeded their respective North Carolina ground water standards in monitoring wells
MW-I, MW-3 and MW-4. SVOCs including naphthalene in MW-I and MW-2, and bis(2-
2
s:\aaa-rnaster proj;;cts\nc doL\dol-21S robbinwille\t.ext\ph.ii Isa report.doc
Hart & Hickman, PC
ethylhexyl)phthalate in MW-4 exceeded their respective ground water standards. VPH as C5-C8
aliphatics exceeded the ground water standard in MW-1, and total C9-C22 aromatics exceeded the
ground water standard in MW-1, MW-2, and MW-4. None of the concentrations detected in site
ground water exceed DENR-defined GCLs. Free product was not detected during the LSA.
However, the ground water concentrations of benzene, toluene, n-butylbenzene, bis(2-
ethylhexyl)phthalate, and total C9-C22 aromatics exceed 10 times the surface water quality
standards for Tulula Creek.
Recommendation
Based on· the risk classification and land use survey, it appears the site qualifies for an intermediate
risk, industrial/commercial classification. As an intermediate risk site, the incident is not eligible
for closure. In accordance with DENR guidance, H&H recommends a Comprehensive Site
Assessment (CSA) be conducted to further assess the site.
3
s:\aaa-mastet proj;!cts\nc dot\dot-21S robbinsville\text\ph.il Isa report.doc
Hart & Hickman, PC
: '
2.0 Introduction and Site History
This Phase II LSA report documents assessment activities due to a release from a former diesel and
gasoline UST system at 40 State Shed Road in Robbinsville, Graham County, North Carolina. A
site location map is provided as Figure 1, and a site area map is included as Figure 2. The subject
property is approximately 1 acre and is occupied by the NC DOT Maintenance Yard for Graham
County. This report was prepared on behalf of the NC DOT.
Due to failing cathodic protection monitoring tests, a 5,700-gallon gasoline and a 5,700-gallon
diesel UST were removed by NC DOT on August 31, 2004. During excavation activities on August
26, 2004, the diesel product line leading to the dispenser island was broken and approximately
1,000-gallons of diesel fuel was released. Approximately 3,900-gallons of product and water were
pumped from the UST basin using two 4-inch diameter basin wells. One of these 4-inch wells
remains in the basin and is labeled W-1 (Figure 3). Another UST observation well (W-2) is located
on the property near a used oil UST (Figure 3).
Nine soil samples (SS-1 through SS-9) were collected by NC DOT from the excavation sidewalls
and adjacent to the dispenser line and dispensers after UST removal activities on August 31, 2004.
Due to the presence of shallow ground water, soil samples were collected at depths ranging from 2.5
ft to 4 ft below grade. Bedrock was encountered in the former UST basin at a depth of
approximately 12 ft below grade. Each soil sample was submitted for analysis ofEPH/VPH, VOCs,
and SVOCs. A water sample collected from the UST basin was submitted for analysis of VOCs,
SVOCs, lead, and VPH/EPH. Soil and water impacts were detected. This LSA report was
conducted to address the identified impacts resulting from the former gasoline and diesel USTs and
product lines.
4
s:\aaa•ma.'lter prop:L'l\nc dot\dot-215 mbbinsville\!eJ1t\ph.il Isa report.doc
Hart & Hickman, PC
3.0 Receptor Information and Risk Characterization
A LSA Risk Classification and Land Use Form is provided in Appendix A. A discussion of
potential receptors and land use is provided below.
3.1 Water Supply Wells
H&H conducted a water supply well survey for the area within a 1,500-ft radius of the source area.
The survey was conducted by performing drive-by reconnaissance, interviews with site occupants, and
interviews with City of Robbinsville municipal water department personnel concerning municipal
water availability to the site and surrounding area.
During the drive-by reconnaissance of the area, no water supply wells were observed, and evidence of
municipal supplied water (water meters and meter boxes, fire hydrants, etc.) was observed throughout
the search radius. Based on interviews with City of Robbinsville water department personnel,
municipal water is available to the site and surrounding areas. City of Robbinsville water department
personnel also stated that municipal water is supplied all occupied properties within the site area,
including the subject property. NC DOT site personnel confirmed that the site is supplied with
municipal water and that no water supply wells exist at the site.
According to the water department, the City of Robbinsville obtains water from two surface water
sources: Long Creek, which is located approximately 1 mile west of the site and hydraulically
separated from the subject property, and Cheoah River/Sweetwater Creek, which is located
approximately ¾ mile north and downstream of the subject property. Long Creek is the primary
water supply source, and Cheoah River/Sweetwater Creek is used as a backup source.
3.2 Surface Water
H&H reviewed the USGS topographic map and surveyed the area for surface water bodies. The
closest surface water body to the UST area is Tulula Creek, which borders the subject site and is
located approximately 200 west of the dispenser area and 250 ft west of the former UST basin
(Figure 3). According to Mr. Jeff Manning of the Surface Water Protection Section of DENR,
5
s:\aaa•ma~ter projecL~UlC doL\dot-215 robbinsville\tcxt\ph.ii Isa repon.doc
Hart & Hickman, PC
Tulula Creek is designated as Water Supply Class III (WS-III) and a Trout Water (Tr). As noted in
Section 5.0, ground water concentrations exceed surface water standards/criteria by a factor more
than 10 which qualify the site as intermediate risk. The constituents that exceed 10 times the
surface water standards/criteria include benzene, toluene, n-butylbenzene, bis(2-
ethylhexyl)phthalate, and total C9-C22 aromatics.
3.3 Subsurface Structures
Visual observations were made for potential subsurface contamination conduits in the vicinity of the
former UST system that are large enough for worker entry and may provide a place for
accumulation of petroleum vapors. As indicated in Figure 3, subsurface utilities located in the
vicinity of the source areas include sanitary sewer, water, electric (from office building to dispensers
only), and petroleum aboveground storage tank (AST) dispenser lines.' However, most of these
utilities are located upgradient of the former UST system. The only subsurface utilities in the
vicinity of the source areas are the electrical lines to the dispensers and the AST product lines.
Based on this information, no potential subsurface conduits of concern were identified.
3.4 Property Owners and Land Use
The site and adjacent properties are occupied by industrial/commercial facilities with some
residential properties located beyond. The closest residences are located approximately 400 ft north
and approximately 400 ft southeast of the source areas. According to Graham County Tax
Assessors office, there is no zoning in Graham County. A list of adjacent property owners is
provided as Table 2, and locations are referenced on Figure 2. Access to the site is limited due to
perimeter fencing and a lockable gate.
6
s:\aaa-master project.'l\nc dot\dot-215 robbin.sville\text\ph.ii lsa report.doc
Hart & Hickman, PC
4.0 Geology and Hydrogeology
4.1 Regional Geology and Hydrogeology
According to the North Carolina Geological Survey 1985 Geologic Map of North Carolina, the
site area is located in the Blue Ridge Belt of the Blue Ridge Physiographic Province of North
Carolina. According to the geologic map, the basement rocks in the site area are composed of
metasandstone, metagraywacke, metasiltsone, and mica schist.
In the Blue Ridge, bedrock is overlain by a mantle of weathered rock or saprolite. The saprolite
consists of unconsolidated clay, silt, and sand with lesser amounts of rock fragments. Due to the
range of parent rock types and their variable susceptibility to weathering, the saprolite ranges
widely in color, texture, and thickness. Generally, the saprolite is thickest near interstream
divides and thins toward stream beds. In profile, the saprolite normally grades from clayey soils
near the land surface to highly weathered rock above competent bedrock.
The occurrence and movement of ground water in the Blue Ridge is within two separate but
interconnected water-bearing zones. A shallow water-bearing zone occurs within the saprolite,
and a deeper water-bearing zone occurs within the underlying bedrock.
Ground water in the shallow saprolite zone occurs in the interstitial pore spaces between the
grains comprising the saprolite soils. Ground water in this zone is typically under water table or
unconfined conditions. Ground water movement is generally lateral from recharge areas to small
streams which serve as localized discharge points.
The occurrence and movement of ground water in underlying bedrock is controlled by secondary
joints, fractures, and faults within the bedrock. On a regional scale, the direction of ground water
flow is typically from uplands to major streams and ground water sinks. The saprolite has a
higher porosity than the bedrock and serves as a reservoir which supplies water to a network of
fractures in the bedrock.
7
s:\aaa-mastcr proj;:cts\nc dot\dot-21S robbinsville\lext\ph.ii Isa report.doc
Hart & Hickman, PC
4.2 Site Geology
Based on field observations during drilling and well installation for this LSA, the site is generally
composed of surficial fill and alluvial soils consisting of tan-brown to brownish red sandy silts
and silty clays. Metasandstone bedrock was encountered below the soils at approximately 11 to
13 ft below ground surface (bgs). An alluvial layer of well-rounded pebbles and Gobbles with
abundant ground water is present just above bedrock. The pebbles and cobbles are assumed to be
present from previous meanders of Tulula Creek. Larger micaschist boulders were also
encountered above the bedrock. The boulders were encountered at depths ranging from three to
eight ft below ground surface. Boring logs and well construction records are provided in
AppendixB.
4.3 Site Hydrogeology
H&H installed five shallow (MW-1 through MW-5) and one deeper monitoring well (DW-1) at
the site during LSA activities in January 2005. After installation, the top of casing elevations of
the monitoring wells were referenced to a common datum using surveying techniques. The depth
to ground water at the site is approximately 4 to 5 ft below grade. Well specifications and water
levels are provided in Table 3. Based on the potentiometric map of the site, the shallow ground
water flow direction is generally to the west and toward Tulula Creek (Figure 4).
8
s:\aaa-master projects\nc dot\dnl-215 robbinsvill::\texl\ph.ii Isa repon.doc
Hart & Hickman, PC
5.0 Sampling and Results
Due to the shallow rock depths in the source areas, no additional soil samples were collected as
part of LSA activities. The soil samples collected by NC DOT as part of the UST removal
activities are discussed below.
5.1 Previous Soil Sampling Results
Due to the shallow depth to ground water, no additional soil samples were collected during the
LSA activities; however, nine soil samples (SS-1 through SS-9) were collected by NC DOT
during UST closure activities. Soil samples SS-2 through SS-5 were collected from the UST
basin excavation sidewalls; samples SS-6 and SS-7 were collected adjacent to the fuel
dispensers; and samples SS-8 and SS-9 were collected adjacent to the product line between the
former USTs and the dispensers (Figure 3). Sample SS-1 was collected at the UST basin
excavation sidewall where the product lines exit the excavation. Each soil.sample was submitted
for analysis of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, and VPH/EPH by
MADEP Methods.
Soil impacts were detected in each of the UST closure samples. The soil constituents detected
above Soil to Ground Water MSCCs included VPH as C5-C8 aliphatics (up to 486 mg/kg), total
C9-C22 aromatics (up to 1,121 mg/kg), benzene (up to 1.12 mg/kg), ethylbenzene (up to 26.1
mg/kg), n-propylbenzene (up to 12.9 mg/kg), naphthalene (up to 18.3 mg/kg), chloromethane (up
to 3.3 mg/kg), and 2-methylnaphthalene (up to 13.7 mg/kg) (Table 1). Although total C9-C22
aromatics exceeded the Residential MSCC in one sample, no soil constituent concentrations
exceeded Industrial/Commercial MSCCs.
5.2 Monitoring Well Installation and Ground Water Sampling
During the LSA activities on January 18 and 19, 2005, five shallow Type II monitoring wells
(MW-I through MW-5) and one deeper Type III monitoring well (DW-1) were installed using
9
s:\.1aa-master prop;ts\nc dot\dot-21S robbinsrlllc\text\ph.ii Isa report.doc
Hart & Hickman, PC
hollow-stem auger and air rotary drilling methods. It is noted that the cobbles and boulders made
monitoring well installations difficult.
Two source area wells were installed including monitoring well MW-1 at the former UST basin
and MW-2 near the fuel dispensers and dispenser lines. These two wells were installed at the
locations where the highest soil impacts were previously detected (i.e., SS-8 and SS-9).
Monitoring wells MW-3 and MW-4 are located topographically downgradient of the source
areas, and MW-5 is located topographically upgradient of the source areas on NC DOT property
across State Shed Road (Figure 4). Deeper well DW-1 is located adjacent to MW-1 and in
between the former UST basin and the fueling dispensers. Each of the shallow Type II
monitoring wells were installed to a depth of 12 ft below ground surface (bgs) with 10 ft sections
of well screen placed to bracket the water table surface. The deeper Type Ill well was completed
with a 6-inch diameter surface casing that extended into bedrock to a depth of 28 ft bgs. DW-1
was then advanced to a total depth of 50 ft bgs with a 10 ft section of well screen. Boring logs
and well completion records are included in Appendix B.
On January 20, 2005, H&R sampled monitoring wells MW-1 through MW-5 and DW-1. Prior
to sample collection, monitoring wells were purged using disposal bailers until pH, temperature,
and conductivity stabilized. Ground water samples were submitted for analysis of VOCs
(including IPE, MTBE and EDB) by EPA Method 6230D, SVOCs including tentatively
identified compounds (TICs) by EPA Method 625, VPH and EPH by MADEP Method, and total
lead by Method 6010/3030C.
Laboratory-supplied sample containers were used for sample collection. A chain-of-custody
record was completed for samples collected and included sample description, date collected, time
collected, matrix, sample container information, and analyses required. The chain-of-custody
, --. was signed by H&H prior to placement in an iced cooler for hand delivery to Prism Laboratories,
Inc., a North Carolina certified laboratory. Laboratory analytical data sheets are provided in
Appendix C.
10
s:\aaa•ma~ter projects\nc dol\dol-21S robbinsville\text\ph.ii Isa report.doc
Hart & Hickman, PC
5.3 Ground Water Sampling Results
The ground water analytical results indicate constituents exceeding ground water standards in
~, source area shallow monitoring wells MW-1 and MW-2 and in downgradient shallow well MW-
4 (Table 4). Target compounds were not detected above ground water standards in source area
deep well DW-1, upgradient shallow well MW-5, or downgradient shallow well MW-3. Free
product was not encountered in the newly installed monitoring wells or in the existing UST basin
observation well. H&H used an interface probe to check for the presence of free product.
Ground water constituents that exceeded their respective ground water standards included
benzene (up to 320 µg/1), ethylbenzene (up to 150 µg/1), MTBE (up to 690 µg/1), n­
propylbenzene (up to 91 µg/1), naphthalene (up to 100 µg/1), bis(2-ethylhexyl)phthalate (up to
120 µg/1), VPH as C5-C8 aliphatics (up to 1,400 µg/1), and total C9-C22 aromatics (up to 2,780
µg/1). None of the ground water detections exceed DENR-defined GCLs. The ground water
concentrations of benzene and total C9-C22 aromatics are depicted on Figures 5 and 6,
respectively.
The concentrations of heavier EPH fractions, bis(2-ethyhexyl)phthalate (BEHP), and other
compounds detected in monitoring well MW-4 may not represent actual ground water conditions.
After purging and prior to sampling monitoring well MW-4, a DOT employee inadvertently
allowed surface wash water to enter the well. Prior to site cleaning, H&H observed a dark oily
sheen from site vehicles on the nearby asphalt surface. After the wash water entered the well,
H&H re-developed the well by removing 10 well bore volumes; however, the concentrations of
heavier EPH fractions and the presence of BEHP suggest that the wash water may have affected
this sample.
11
s:\aaa•master projects\nc dot\dot-21S robhirlsville\texl\ph.H ls.a repon.doc
Hart & Hickman, PC
Sample ID: SS-1 SS-2 SS-3
Depth (feet), 4 4 4
Location: Sidewall/ Line Basin Sidewall Basin Sidewall
YPHIEPH
VPH CS-C8 Aliphatics 12.2 <10 <10
VPH C9-Cl2 Aliphatics 51.8 11.4 <10
EPH C9-Cl8 Aliphatics 136 119 <100
Total C9-Cl8 Aliphatics 187.8 130.4 ND
EPH C19-C36 Aliphatics <100 113 <100
VPH C9-Cl0 Aromatics 29.0 <10 <10
EPH Cll-C22 Aromatics 429 220 142
Total C9-C22 Aromatics 458 220 142
VOCs (8260B)
Benzene ND ND ND
n-Butylbenzene ND ND ND
Ethyl benzene ND ND ND
n-Propylbenzene ND ND ND
p-Isopropyltoluene ND ND ND
Naphthalene ND ND ND
Bromomethane ND ND ND
Cbloroethane ND ND ND
Cbloromethane ND ND 0.963
SVOCs (8270C)
Fluorene ND ND ND
2-Methylnaphthalene ND ND ND
Naphthalene ND ND ND
n-Nitrosodiphenylamine ND ND ND
Phenanthrene ND ND ND
Notes:
All values shown in mg/kg
Soil samples collected by NC DOT.
Table 1
Summary of August 2004 Soil Sample Results
Former UST Basin/Dispenser Lines and Dispensers
NC DOT Maintenance Yard
Robbinsville, North Carolina
H&H Job No. DOT-21S
SS-4 SS-5 SS-6 SS-7
4 4 3 2.5
Basin Sidewall Basin Sidewall o: ..... -~ .. r Dimem:er
11.5 <10 11.7 20.1
<10 <10 <IO 117
<10 252 <10 <100
ND 252 ND 117
<10 <100 <10 <100
<IO <10 <10 68.6
13.2 159 12.7 156
13.2 159 12.7 224.6
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND ND
0.227 0.318 0208 ND
ND ND ND 0.129
1.14 1.47 0.959 0.561
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND ND
EPA Method nwnber follows parameter in parenthesis; Bold indicates concentration exceeds soil to ground water or residential MSCC
VOC = Volatile Organic Compound; NS = Not Specified; ND c:i Not Detected
MSCC = Maximwn Soil Contaminant Concentration; GW = Ground Water
VPH = Volatile Petroleum Hydrocarbons; EPH = Extractable Petroleum Hydrocarbons
File:Tables,UST Soll Data
Date:2/25/2005
SS-8 SS-9 Commercial/ Residential Soil to GW 35 3.5 Industrial MSCC MSCC Product line Product line MSCC
226 486 24,528 939 72
470 532 NS NS NS
1,800 688 245.280 9,386 3,255
2.270 1.220 245,280 9,386 3,255
262 173 >100% 93,860 Immobile
249 272 NS NS NS
872 247 NS NS NS
1,121 519 12,264 469 34
ND 1.12 200 22 0.0056
225 4.46 4,088 156 4
5.77 26.1 4,088 156 3
2.52 12.9 4,088 156 2
ND 2.77 NS NS NS
ND 18.3 1,635 63 0.58
ND ND NS NS NS
ND 7.86 NS NS NS
3.33 ND 440 49 0.02
1.14 ND 16,400 620 44
13.7 12 1,635 63 3
3.95 6.36 1,635 63 0.58
!.19 ND NS NS NS
1.97 1.59 12.264 469 60
Map No. Property Occupied
Parcel ID No. by:
Exempt Site NCDOT
568100000004PT A Veach-Wilson Oil
Company
Exempt B NCDOT
5588000014600T C Lovin Contractors,
Inc.
566016200002 D Sawyer Home Care
566016200001 E Vacant/DOT
parking
Notes:
Information provided by Graham County Tax Assessors office
Adjacent properties are shown on Figure 2
Table 2
Adjacent Property Owner Information
NC DOT Maintenance Yard
Robbinsville, North Carolina
H&H Job No. DOT-215
Property Street Owner Location
40 State Shed Rd State ofNorth Carolina
92 Five Points Rd. Pervestco, In.
State Shed Rd. State of North Carolina
88 State Shed Rd. Brandon K & Haley W Lovin
77 TululaRd John J. Colvard
Five Points Road Harold & Juanita Rogers, and Bo &
Helen Collins
Owner Address Direction
From Site
Raleigh, NC NA
PO Box 485, Robbinsville, NC 28771 Northeast
Raleigh,NC East
PO Box 758, Robbinsville, NC 28771 South
PO Box 233, Robbinsville, NC 28771 West
PO Box 212 Robbinsville, NC 28771 North
Table3
Well Specifications and Water Level Elevations
NC DOT Maintenance Yard
Robbinsville, North Carolina
H&R Job No. DOT-215
Total Screen January 20, 2005
Monitoring Depth Top of Ground Top of Casing Interval Depth to Well ID (ft) Elevation (ft) Elevation (ft) (ft) Water (ft)
MW-1 12 99.24 98.97 2-12 5.27
MW-2 12 98.85 98.63 2-12 4.62
MW-3 12 98.70 98.41 2-12 5.07
MW-4 12 97.86 97.64 2-12 4.57
MW-5 12 100.00 99.80 2-12 4.37
DW-1* 50 99.47 99.27 40-50 5.25
Notes:
Top of manhole (ground) and top of casing elevations referenced from arbitrary benchmark ofl 00 ft.
Wells installed by H&H on January 18 and 19, 2005.
NA = Not Applicable
* DW-1 is a Type ill monitoring well with surface casing to 28 ft.
Ground
Water
Elevation
93.70
94.01
93.34
93.07
95.43
94.02
Sample ID: MW-I
Sample Date: 01/20/05
voes (6210»1
Benzene 320
Ethylbenzene 150
Toluene 300
Isopropyl ether (!PE) 32
Methyl tert-butyl ether (MTBE) 690
Total xylenes 370
1,2,4-Trimethylbenzene 79
1,3,5-Trimethylbenzene 22
Isopropylbenzene 27
n-Butylbenzene 34
sec-Butylbenzene 8.4
n-Propylbenzene 91
Naphthalene 100
Trichloroethene <5.0
SVOCs(625!
Fluorene 5.4'
Naphthalene 75
Phenanthrene 3.7'
Bis(2-ethylhexyl)phthalate <9.7
Butylbenzylphthalate <9.7
Maximum TIC 120
VPHIEPH (MADEP!
VPH C5-C8 Aliphatics 1,400
_VPH C9-Cl2 Aliphatics 280
EPH C9-Cl8 Aliphatics 100
Total C9-Cl8 Aliphatic, 380
EPH Cl 9-C36 Aliphatics <JOO
EPH Cl l-C22 Aromatics 1,000
VPH C9-CI O Aromatics 1,300
Total C9-C22 Aromatics 2,300
Metals
Lead (6010/3030C) <5
Notes:
All values shown in µg/1
voes c Volatile Organic Compounds
Table4
Ground Water Analytical Detections
NC DOT Maintenance Yard
Robbinsville, North Carolina
H&H Job No. DOT-215
MW-2 MW-3 MW-4 MW-5
01/20/05 01/20/05 01/20/05 01/20/05
25 0.95 5.6 <0.5
5.0 <0.5 5.5 <0.5
2.4 <0.5 3.0 <0.5
1.9 1.3 6.3 <0.5
32 37 34 <0.5
1.88 3.0 28.8 <;1.5
0.58 1.5 9.5 <0.5
<0.50 0.96 6.2 <0.5
4.4 <0.5 1.4 <0.5
4.4 2.1 7.6 <0.5
1.3 0.59 0.96 <0.5
II 0.58 5.4 <0.5
38 <0.5 8,9 <0.5
<0.5 <0.5 <0.5 <0.5
3.3' <9.7 <19 <9.7
34 <9.7 11' <9,7
3.01 <9.7 4.9' <9.7
<9,7 <9.7 120 <9.7
<9.7 <9.7 151 <9.7
48 16 120 ND
83' <100 <100 <100
110 <JOO <100 <100
510 <100 550 <100
620 <200 550 <200
<100 <JOO 9,700 <JOO
770 <100 2,600 <100
150 <100 180 <100
920 <200 2,780 <200
<5 I.8' 2.4' <5
DW-1
01/20/05
<0.5
<0.5
<0.5
<0.5
<0.5
<1.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0,5
1.9
<9.7
<9.7
<9.7
<9.7
<9.7
ND
<100
<100
<100
<200
<100
<100
<100
<200
<5
ND= Not Detected
NA• Not Analyzed
NS = Not Specified
NCGW
Standard
I
29
1,000
70
200
530
350
350
70 -
70 ,.
70 \ '·
70
21
2,8
280
21
210
3
NS
NS
420
NS
NS
4,200
42,000
NS
NS
210
15
GCL = Gross Contamination Level
GW = Ground Water
NCGCL's
5,000
29,000
257,500
70,000
200,000
87,500
28,500
28,500
25,000
6,900
8,500
3(r,000
15,500
2,800
950
15,500
410
3,000
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
15,000
VPH = Volatile Petroleum Hydrocarbons
EPH""' Extractable Petroleum Hydrocarbons
SVOCs = Semi-Volatile Organic Compowids
ND == Not Detected Bold indicates exceeds ground water standard
TIC"" Tenatively Identified Compounds.
1""' Estimated value between Laboratory reporting limit and method detection limit
BDL = Below Laboratory Detection Limit
7
\
_-~\~r­.. ~:11' "' .,f ~;;; . wJVr -. !,i!/1, '-:J-.-c-c.:--,.-,,:,;~?,'1,ol · . :,-, ,,. ;
~
., .
'1.! ;\· 1~ -
. -~ i:-\.)
' -.,
0
APPROXIMATE
.2000
. SCALlrlN FEET -
U.S.G.S. QUADRANGLEMAP
ROBBiNSVILLE, NC: 1940 ·
-REVl$ED/INSPECTED 1990
QUADRANGLE
·7_5 MINUTE·SER.IES (TOPOGRAP'HIC)
4000
TITLE
. PROJ~cr·
SITE LO.CATION MAP
".·bot.MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
~ .
· . · · -2923 South Tiyon Si:rcct-Suitc 100 H--· ·&H' km-_ -_ -----art IC . an Chi<lott<; Notth C,rolin;2a20, · .
: . ._, · A P.R1?F1ci:i:~rcNA1,, t;:o~PO~TI□N 704-58~07 (p) 70;4-~86-0~73 _(fJ . _
DATE:. 1-~'05 REVl~ION NO: :o
-JOB NO: . DOT-215 FIGURE--NO;. 1
FORD ST.
I Will:!ll
----SITE PROPEITTY BOUNDARY
A PROPERlY ID NUMBER (SEE TABLE 2)
NOTE:
BASE MAP PROVIDED BY GRAHAM COUNlY MAPPING/LAND RECORDS
@
APPROXIMATE
0 500
SCALE IN FEE1'
W. FORT
Hill. RD.
OLD MOTHER
CHURCH RD.
1,000
SITE AREA MAP
NC DOT MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
~art & Hickman 2923 Somb T,yonS=t-Suitc 100 l""9 !]; Charlotte, North Carolina 28203
A F'RCF~SSICNAL CcRpgR ... TICN 7{)4.586-0Q07(p) 704-586-0373(£)
DATE: 1-17-05 REVISION NO. 0
JOB NO: DOT-215 FIGURE NO. 2
FORMER LOCATION
OF LIQUID
ASPHALT AST
EQUIPMENT
STORAGE AREA
♦ MW-4
FIVE POINiS ROAD
-------
SS-7
SS-6
SEWER
MANHOLE
LOCATION
OF FORMER
UST BASIN
~ ~ \· ~~ \·
~
~· ~ ~
SAND
STOCKPILE
STOCKPILED
SOIL FROM
UST REMOVAL
NC DOT ADDITIONAL
STORAGE YARD
_ss--ss
_ss_ss
GRAVEL
STOCKPILE
GRAVEL
STOCKPILE
LEruill
------PROPERTY BOUNDARY
--FENCE
--w --WATER LINE
--ss --SEWER LINE
LIQUID
ASPHALT AST
PRESSURE
WASHER
OIL/WATER
SEPARATOR
-ELECTRIC LINE
♦ MONITORING WELL
'-DEEPER MONITORING WELL
Q UST OBSERVATION WELL
® APPROXIMATE SOIL
SAMPLE LOCATION
BY DOT (8/31/04)
H-------WASH PAD
SALT
SPREADER
STORAGE
RACK
0
APPROXIMATE
50
SCALE IN FEET
100
SITE MAP AND ADJACENT PROPERTIES
NC DOT MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
mart & Hickman 2923 Sowh T,yon 5"':'-Sui"' 100 Charlotte, North Carolliu 28203
A PROP-EBBIONAL. CORPCIRATlt:IN 704-586-00Q7(p) 704-586-0JJJ(I)
DATE: 1-17-05 REVISION NO. 0
JOB NO: DOT-215 FIGURE ND. 3
Wlflill
------PROPERTY BOUNDARY
___ •. --FENCE
♦ SHALLOW MONITORING WELL
<ii DEEPER MONITORING WELL
(93.70) WATER TABLE ELEVATION
(FT) ON 1 /20/05
9..,__ _ 94 ESTIMATED SHALLOW GROUND
WATER CONTOUR
--➔-ESTIMATED GROUND WATER
FLOW DIRECTION
FIVE poJNTS ROAD
93.5
I -----1--------I
\ ♦ts~.oi) /
FORMER LOCATION
OF LIQUID
ASPHALT AST
,W-3
(93.34)
I
\
\
MW-2 94.01)
-MW-~y----
(93.70) '\ <ii I DW-1 \
..-..... -------
SEWER
MANHOLE
LOCATION
OF FORMER
UST BASIN
SAND
STOCKPILE
STOCKPILED
SOIL FROM
UST REMOVAL
NC DOT ADDmONAL
STORAGE YARD
LIQUID
ASPHALT AST
PRESSURE
WASHER
OIL/WATER
SEPARATOR
H------WASH PAD
SALT
SPREADER
STORAGE
RACK
0
APPROXIMAiE
50
SCALE IN FEET
SHALLOW GROUND WATER
POTENTIOMETRIC MAP
100
NC DOT MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
fllart & Hickman 2923 South T,yon St=t-Swte 100 Charlotte, North Carolin.a 28203
.._.. A PRon:,u11C1NAL CCRPCIRATICIN 704-586--0007(p) 704-586-0373(£)
DATE: 1-17-05 REVISION NO. 0
JOB NO: DOT-215 FIGURE NO. 4
LElEMQ
------PROPERTY ·BOUNDARY
--, --FENCE
--w --WATER LINE
--ss -.-SEWER LINE
-• -• -ELECTRIC LINE
♦ MONITORING WELL
Q DEEPER MONITORING WELL
(320) BENZENE CONCENTRATION
(µg/1)
--ESTIMATED EXTENT OF IMPACTS
(µg/1)
FORMER LOCATION
OF LIQUID
ASPHALT AST
EQUIPMENT
STORAGE AREA
F\\/E POINTS ROAD
/
I 10
\
'---
-1----
USED
OIL UST LOCATION
OF FORMER
UST BASIN
------------.
MW-5
(<0.5)
SAND
STOCKPILE
STOCKPILED
SOIL FROM
UST REMOVAL
NC DOT ADDITIONAL
STORAGE YARD
LIQUID
ASPHALT AST
PRESSURE
WASHER
OIL/WATER
SEPARATOR
M-----WASH PAD
SALT
SPREADER
STORAGE
RACK
0
APPROXIMATE
50
SCALE IN FEET
100
BENZENE ISOCONCENTRATION MAP
NC DOT MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
art & mckman 2923 South T"°n s-t-Sui" 100
Charlotte, North Carolina 28203
A F'RCIFUBlCINAL CORPCIR ... TTCIN 704-586-0007(p) 7()4..586-0373(£)
DATE: 2-4-05 REVISION NO. 0
· JOB NO: DOT-215 FIGURE NO. 5
W1EtID
------PROPERTY BOUNDARY
--FENCE
--w --WATER LINE
--ss --SEWER LINE
-• -• -ELECTRIC LINE
♦ MONITORING WELL
Q DEEPER MONITORING WELL
(920) TOTAL C9-C22 AROMATICS
CONCENTRATION (.ug/1)
--200--ESTIMATED EXTENT OF IMPACTS
(.ug/1)
• SOURCE UNKNOWN; POTENTIALLY
DUE TO SURFACE WASH WATER
ENTERING WELL
FORMER LOCATION
OF LIQUID
ASPHALT AST
EQUIPMENT
STORAGE AREA
MW-4 ♦(2,780)*
FIVE pQ\NTS ROAD
__.----'_.
2 ,,,----MW-2 ...........
(920) -2,000 ♦ ✓---­---f.lw-1♦ 'x--
\
(2,300) I '
USED
OIL UST
g ' DW-1 I
..(:,200)
LOCATION
OF FORMER
UST BASIN
MW-5
♦ (<200)
SAND
STOCKPILE
STOCKPILED
SOIL FROM
UST REMOVAL
NC DOT ADDITIONAL
STORAGE YARD
GRAVEL
STOCKPILE
PROJ£Cl
LIQUID
ASPHALT AST
PRESSURE
WASHER
OIL/WATER
SEPARATOR
WASH PAD
SALT
SPREADER
STORAGE
RACK @
APPROXIMATE
0 50
SCALE IN FEET
TOTAL C9-C22 AROMATI.CS
ISOCONCENTRATION MAP
100
NC DOT MAINTENANCE YARD
ROBBINSVILLE, NORTH CAROLINA
mart & Hickman 2923 Souili Tryon Stn,'.t-Swte 100 Charlotte, North Carolina 28203
--A PRCIFEBSl<:iNAI. CORPCRATICIN 704-586-0007(p) 704-586-0J?J(f)
DATE: 2-4-05 REVISION NO. 0
JOB NO: DOT-215 FIGURE NO. 6
Appendix A
Risk Classification and Land Use Form
s:\aaa-mastet projects\nc dot\dot-215 robbinsville\text\ph,ii Isa report.doc
I
' ''
! I
I '
' '
i ' '
' I I
Limited Site Assessment Risk Classification and Land Use Form
Part I -Groundwater/Surface WaterNapor Impacts
High Risk
1. Has the discharge or release contaminated any water supply well including any
used for non-drinking purposes?
No.
2. Is a water supply well used for drinking water located within 1000 feet of the
source area of the discharge or release?
No water supply wells were identified within 1,000 ft of the source area.
3. Is a water supply well used for any purpose ( e.g., irrigation, washing cars,
industrial cooling water, filling swimming pools) located within 250 feet of the
source area of the release or discharge?
No water supply wells used for any purpose were identified within 250 feet of the
source area of the release or discharge.
4. Does groundwater within 500 feet of the source area of the discharge or release
have the potential for future use in that there is no other source of water supply
other than the groundwater?
Municipal water is available and supplied to the site and properties located
within 500 ft of the source area.
5. Do vapors from the discharge or release pose a threat of explosion because of
accumulation of the vapors in a confined space, or pose any other serious threat to
public health, public safety or the environment?
Vapors from the discharge or release do not appear to be a threat of explosion or
a threat to public health, safety or the environment.
6. Are there any other factors that would cause the discharge or release to pose an
imminent danger to public health, public safety, or the environment?
There are no known factors that would pose an imminent danger to public health,
public safety, or the environment.
S:\AAA•Masta Projeds\NC DO'N>OT-21S Robbinrville\ier.t\wi.d Use Form.doe 1
,--
' '
'
Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the
discharge or release?
Yes, Tutu/a Creek (classified as Water Supply III and Trout Water) borders the
site property and is located approximately 200 ft west of the source area.
8. Is the source area of the discharge or release located within a designated
wellhead protection area as defined in 42 USC 300h-7( e)?
The source area is not located within a designated wellhead protection area.
9. Is the discharge or release located in the Coastal Plain physiographic region as
designated on a map entitled "Geology of North Carolina" published by the
Department in 1985? If yes, is the source area of the discharge or release located
in an area in which there is recharge to an unconfined or semi-confined deeper
aquifer that is being used or may be used as a source of drinking water?
The discharge or release is not located in the Coastal Plain physiographic region.
10. Do the levels of groundwater contamination for any contaminant exceed the
gross contamination levels established (see Table 3) by the Department?
Ground water impacts do not exceed gross contamination levels.
Part II -Land Use
Property Containing Source Area of Discharge or Release
1. Does the property contain one or more primary or secondary residences
(permanent or temporary)?
No, the property and adjacent properties are light industrial or commercial. The
subject property is an active NC DOT Maintenance Yard.
2. Does the property contain a school, daycare center, hospital, playground park,
recreation area, church, nursing home, or other place of public assembly?
The property does not contain a place of public assembly.
$;\AM-MUie, Projects\NC DOl'l>OT•llS Robbinsvillelul:!\Land Use Pomu1oc 2
3. Does the property contain a commercial ( e.g., retail, warehouse,
office/business space, etc.) or industrial ( e.g., manufacturing, utilities, industrial
research and development, chemicaVpetroleum bulk storage, etc.) enterprise, an
inactive commercial or industrial enterprise, or is the land undeveloped?
As stated above, the property contains a NC DOT Maintenance Yard.
4. Do children visit the property?
No, the site is an active NC DOT Maintenance Yard.
5. Is access to the property reliably restricted consistent with its use ( e.g., by
fences, security personnel or both)?
Perimeter fencing restricts access to the property.
6. Do pavement, buildings, or other structures cap the contaminated soil?
The source area(s) are capped by an asphalt surface.
7. What is the zoning status of the property?
No zoning exists in the site area, or elsewhere in Graham County.
8. Is the use of the property likely to change in the next 20 years?
The property is not likely to change in the next 20 years.
Property Surrounding Source Area of Discharge or Release
The questions below pertain to the area within 1500 feet of the source area of the
discharge or release (excludes property containing source area of the release):
9. What is the distance from the source area of the release to the nearest primary
or secondary residence (permanent or temporary)?
S:\AAA-Mutcr Projcas\NC 001'00T-2IS Rabbillmllc'uxt\Lwl Use Ponn.doc 3
,--I
There are two residences: one to the north (topographically cross-gradient) and
one to the southeast (topographically upgradient), both approximately 400 ft from
the source.
10. What is the distance from the source area of the release to the nearest school,
daycare center, hospital, playground, park, recreation area, church, nursing home
or other place of public assembly?
The closest observed area of public assembly is Old Mother Church (labeled as
Cheoah Church on Figure 1), which is located approximately 1,000 ft southeast
of the source area.
11. What is the zoning status of properties in the surrounding area?
According to Graham County personnel, there is no zoning in Graham County.
12. Briefly characterize the use and activities of the land in the surrounding area.
The property is an active NC DOT Maintenance Yard, with adjoining properties
either light industrial or commercial. Properties located beyond are a mix of
residential, commercial and light industrial.
S:\AAA-Mastcr Proj«u\NC 001\DOT•l i, Robbinsvil!c\latll.and Use Feno.doc 4
AppendixB
Boring Log and Well Construction Records
s:\aaa-rnastet projects\nc dot\dot-215 robbinsville\text\pll.ii Isa report.doc
. ' . ·-t_." Wt ··ttt Sheet_/ of/ ','/ ~ Hart & Hickman ,,,,,.,,,,,.,,,., ...... "' LOG OF BORING: M. \,/ -J ~ Charlotte, Nortll.Cuollu A Professional Cozporation (704)S86-0007 (704)5&S-OJ73-f.u:
l~e-/ ,J°9".,.~. """"'--
Project: 'P £> T-(Z.., hb ,...,,.., ,-,'Ile:__ Surtoce Elev: 9 9, ;,.I{ 3 J -/-' . e,a ,ir'-, Top of Cos,ng El,~ , 8. 'J ii e / Job No;p!) /-21 F Drilling Rig/Method: t!,.~-f.,,,,,.._ '7 ,-,, ~; t'" /',,,-1,,r✓ (,,, ~
Location: ~ bb,..,__,,,.; L/e .t,fc_ Sampling Method: e,..,.,.#1 ~ q /Zn-,-.,_, .
fl) ~ ... 0
Q) ... :c 0 1-11 Q) Q) a. -Q) a .0 E re -'-E c::-a. "' ~ Q) MATERIAL DESCRIPTION SPT, Blow Counts a. WELL DIAGRAM 0 £ '-> ~ :;:; ... 0 (The stratification· lines represent approximate a a. " 0 ~-> " a. VJ " boundaries, The transition may be gradual.) " 0 E t) a,: (!) 0 a.. GJ VJ :::; a :::, "" ;J; VJ m r ' b 0 .,.7 -= ,;;) D I/ ,i ., ,, . /5 lb-<_ ' ~ --=---L ~7 I--':'!:::~
--l>C, i,..-,.,..._., --' "'.1 s.r-r, e-/J ----··· , --~ I
,, ;I> 7'/ --' ---
' -✓ ........ L -5 --. --I-:::-----' -<=-JZ,..,t;.... Lr,,;,..._ . .,~-,..+.) ~ ... Ji:Ltr ·--., . --,
~ ' --. -
~
' .
~ ---· -. ,__ --' 1-10---L.-'--... -. ' "'-:... -, ...
~ . TOe. I z-'
~ -
L..15--
--I
--
--
... -
1-20--... -' ... -'
~ -'
~ -'
1-25--
Completion Depth: / 2 ~marks: I!:, · ~}) Date Boring Started: ,1 /59/oJ-.Pl-,-,: C, d bl)P" Date Boring Completed: 1/✓T/~
Engineer /Geologist: e .A.~,•
Drilling Contractor: e;i,._\.,:on,i -:5',.,,,,..,...0..,.j 'J:i,-:i,j,'-• -J?',,,.,J •· ~.71.:.' Revision DrawnBy Date Checked Approved -, ,
02/15/2005 _10: 51
C --,-.; -"
· 70487.6-9948; . . . -. . ' '
pAGE 08
. WELL CONSTRUCTION Rl:CO~D
North Carolina • bapar\111~0~ <\f in~fon1mmt and Natural Rosource,{,:.bivi$lon of Water Qu~fJly.-'Grnunc!Mit~, Section " ' -~ -·.-,. '1' ' -,-• -. ' . . ' "" . -. . . '
. . . t,v,v~a us~ (9heck Appli~~ble e~: . ~-';F;,.1.;;,;;ti~l ~. Munli;Jp•J/Publl< ;'.. " -. Industrial~ -->Aefn~nu~t:__'._
:/ · · Moriit9fimriX..a. Recovery·_____ { -~ ' Heat Punt~ Water-Ini~oo ___ , Other ___ -ff off!ef liai use~~~~-~ ~ ·. -.:. -_-•._ r<_·;~ -' ' ,. , . • , . ,; ' ' . -·-·• --, l WfilL LOCATION; (Show &ketch ofjhe l~qn below)
. •--Nearest 'rowfi_:·. Robbins_villE Qqu~ ,_,G,,.ta,,,h,,a,cm'---c~~~
-• -'!, • . . -.~ ~ ..
. 11 1 , • , ,: ~~ '. ;(RQc6'4,C'il~!Y.·orsirbdhl-'lOnd:!ldtiitNC1t) " --·--,,e
~-, ·1i -_,\ "._~t:~ , .~; 1-~~~e~1:~e,:boi Maint~nan~ Fae;i~',, -~ ~~~ :-~~
· ,: · > . --·'f.D\Jflf:s~_,.iostatesnoo Rd.
~~ " .' ' ' ,. . ;.., -(S~e!l)l'.J{odi!!No.)
·~ ~· .. ~ ':f ,"Robbins\'rn~ -_NC .
.,0 -·~or TOY.Ti. :: • . ~ble_ , ~ ~_5!11 -· . , .. "
·; ~..,
· ·-' From·\-·, ,o.3
... __ -~~\} :-~0~5,
1~?t~~~1'::· -Depth , ,:F,rom :-•. ·,_2, To '·From ; __ ,, _ , -rQ · . .f'rom.--,,_., :ro
· 16.' SANDiG~V~-L PAC~ -f
From \ "-1.S· _>°,~lh
•• ·:,;~:""~ ·:. ' tt
-? ~,,o,runeter. _ F1'···,-2,,
~~~--••!•
~~-Ft.
--~--~-~Size
-~.e12,_--~fl.'/•,.. #2 -
~lot Sli<o"
-010·
-.Material
Sand.
' ;M·a·1e· .;_,,al, f; If ,"L'.' :rsvc
'·Froin' ·-.,,\ _ ·: To
,,-•c ' --'--~~ l;L ~=-~~-~--~~
16. REMARKS:, .• ' MW'1 .,
,M\VC1
_ ~rip-·ograptiit;:ati_l..and Settirlg
' ' ~* Riagf /~ ~IOJ)e ......:NS:i~y"' ~ fl_a_t-
. la{int:qe110,n9itude • -· -
LOCATIONSKETE:1/. "
($h!M'. d~~1on and· distil:~CEI _rroJ11 at kra~ two·sta~e
R cads; cir' other ~ag rer~_rt¢.'?. PD!ntB)
' -, ~ "-,--
129
• ~-_.f~tlmountWa11in~allad_10·~:vahiclet~s _ _ _
'"; : · )t~P:: n~E!3; .cERTl~Y°THAT WEL_(w~ ·cbNstRiJcreo:11.,; A~·~o~OANfE\o/JJfl:1~ ~q-~c .. WELL coNsmucn,.91{
. '.'--~~DARPs,ANQ,T , co· Q ~TH!~tR~O~pHASBEENPROvtDEC:HOJHEWelJ,c_OWNER
' f
N CONSTRU _ .TING THE; ElL
-_-01/19/05
'!;)ATE
:", :; -, Sheet/ of/ ~ Hart & Hickman ,,,,,. .. ,,,.,,,,.., •• , .. LOG OF BORING: M.\,/ ~ Cbadotte,NorthCarolma -L A Professional Corporation [phone] (70f}5M-OJ73-6..:
= ~ • ..,,,.,,_1-.. .Su~ .ti-.'.
Project: 'P t>T-e.o h !:, , .,., ,.. ,'l J ~ Surface E!eY. 9 B. BS" 1 /Ze..J f • . q ,vc... Top of Cosing Elev: 9 B .1,3 Job No1)c, /-21 F DrHHng Rig/Melhod,' .a,_7......-a. L,/'r,:, /,4. ,-/:,rc,7 I,..,, ..41'.a-,._,, ir' Location: ~ bb,-..s., i L/e ,t/r_ Sampling Method: ~,y, ~ , ~ ;1.-,,,.J
"'
. -(!? -u
OJ -:c 0 II<: O> OJ "' -O> e .0 E
c; -E b "' (!I O> MATERIAL DESCRIPTION SPT, Blow Counts "' WELL DIAGRAM 0 .2 ~ ~ > ~
+' -o (The stratification· lines represent approximate C "' O> u ~. > O> ci 1/) O> boundaries. The transition may be gradual.) OJ Cl E u "' ci 0 0. w 1/) l C :::, "' 1/) CD I -I A I ,. ' 0
//~ ,1,,,/-/-/.!J-t,,,e_
,__ p .. 1 ,~~ I., '}' • -, -.,,. -----
' I
--F', .-,;,cr.,c_ b ,.,.,,.., -s~/•'J '-,e,J ,-..
--,:;, '#J/C/47 -) --
-··· ' -~ -------
!lo,e, -
t).O . --e--"--
~ ---
e-5 -' --,
w ... :r ' --; .., -' --fc,__e-, M7"L<1. -51>J.,";6~ f$.,, id.tr) ~ -,.. -.., -< -' -.., ---, .., -' -----,
r-10-' ---1---.., -----,--·
e--'De_ I 2-I -
e--
i-15--
e--
r ---r -
r -
r-20--
r -
.., -
.., -
.., --
1--25--
Completion Depth: / ~ _,,,, ~marks: ~ e',,, d 2Ji" .. /?}}) Date Boring Started: ' 1-9/e,!i
Date Boring Completed: ,j/l/o} P7:n.
Engineer /Geologist: e.A. s...,,~'-/k
Drilling Contractor: e ~\,: o,-B "5','W'\,_ 0.., ~ °'!)l'r\'1 ,,,,. a .-.. P'L,,.,J,, ?J,.1£:.., Revision DrawnBy Date Checked Approved
-, ,
,764875;!948 ,
r
•4•lt .~ Sheet/ of/
~ Hart & Hickman ,.,,,_,,,..,_..,.,., LOG OF BORING: M. \J _,3, ~ • Charlottc,NOllhCuolma A Professional Corporabon (70C}S86-0007 ('roOS&W73-fu
{? ::,jjf~ o-:/' /,,-,.,£.J
Project: 'Pt> T-e., .bb ,,,.., ,-,'IJ c...._ Surtace Elev: 9 fl,, 7 " j (Z ,.,f f. .s,., l""'I' · c.,..,,. <r
Job No;po 1-2.J F Top of Casing Elev: '7' 8. 'I I .c: 1
,.. ~ Ir~ ~. I Dri!Hng Rig/Method: t'...., ,.t-Y>~ / &, • ,I. ,._
Location: ~ bb,....,.:;v; L/e_. J[c_ Sampling Method: ~ .b(:.,. fL-/,.---,-,-.r.
"
. C!? -u
0) -:c 0 II<: 0) -0) a. E 0) 0 _.,
c -L E c'.' a. "' 0) MATERIAL DESCRIPTION SPT, Blow Counts a. WELL DIAGRAM 0 .c ~ > ~
:;:; -L 0 (The stratificotiorr lines represent approximate 0 a. " u ~-> " ci. 1/) 0) boundaries. The transition moy be gradual.) 0) Cl E 0 "' ci 0 (l. w 1/) :::;
0 :::, "' u'i 1/) a, , -, h
0 • "t -I ,, I
/J $.A£.. l'f-I sh,, . ! l ---.
t=:.irJ-Pr fl//,-✓,'.../ JA el -~,.. <,rn
-. -.
-.
--;? ' . . -,.,~ -✓,.,... s-,,.d > $, /;I--.. ---. . --,,J --· /), i -. -. --. '--. -. . -L --5 --. --< . --
~ . ---. . -. ---.
?e-/~ -----(.e,,,.,.. e, ... ~ . ---'JZ,, t,.,C,. -. ---. --.
-10-. --• C ------. --
7De .I.ti . --
. --
-15--
. --
--
. --.,, .
. --
-20--
. --
--
--
--
-25--
Completion Depth: /Z.. 'A ~ ~marks: I!,_ , . f1b Date Boring Started: ' 'I~ ~ r' f'Yl·n ,' C,. el ~p II
Dote Boring Completed:1/J o/'b~
Engineer /Geologist: e. A.~.~
Drilling Contractor: e17-\.,:~ ,s',...,_ o-,.'l "3:il":'\IJ,--.. -J&,,.,J,. ~.1/,::., Revision DrawnBy Date Checked Approved -, ,
'1'li{;{b(21'11:l!l,. rn:51--: ·.71'148'i'699~8o · '•':. · iRSIJ, 1'(8,;;;
{ • ' ', ,,· ,; . ~ .,,i•" . • \. ' -,._ . " •
e;-~'.· •. ~~ .~\ "';, ·. ,,__,""r,,,_,
';·-· -1;' ~-'.; · -, ·-;,,i.·~ ·--.. _·; ·~-~1-~· 1·, __ ' ~ ~;-,,;:;':~ .. :-'!>~~:t~~• ..... ,; __ '--~:•~~;·~ll':·~~~N.S!RU~~0
1
N:~E~-~~D; -~-~-:. , ,. _, _', ~~c:, ~-•
',. ,. , '!'faith c,/~ma -~artrne,I( ol.lr\1'1lronment.~iid:t,ialurid t{esou~: Ol,/lslon·<lfV\iatei'Quality0 Groundwati,,sectroi\, ;·<·•,t, •:;_<~-~--~---~---;:_/•" '·\\'/"·(·t1~.:~. ·~'. :·_'!:/\''', · ,.,, ·,-·,,,,:,~:, -" , ·'t'.,,.·i -· ;., •. • ~"-
,'' ~--t"f,, . ;'., , • '!VEu:c;QNTRAc_TOR(fN})l"1Q~)'~E, ··•> .Randyflrlllh?!• ,-",1; ', __ •. ::f· q'ER11ElQ!\rf6N#:~ , 2209·: ,.-,;~~.;
_,.1_ ·,;-~<~:,:.~-·-~:;~,-.~,~ · wetc.cotffMt@'CO-MPANY~• .. 1trctiSri:f"s1mmMs:011~1";19-• 0::>•' PH~Ne! [phone], _ ,. ,. __
•,·,y---~ ,~ .• ; _$IA~·ViE~kC.Q~~,:lpN""pi:~,,ri!t#.1 • ',t~.'-,_ 'c .. "'. A... ;.;"\,. .-A~OC~A.TEO.WQF!EJ™[ni ',. '·--".,' C ··-~--';, -·:·
:;;r',•, -., . ~~ \.~. ''.L: . .(itep"pRcable}.~ :_ ;.__1<. ::.·.·-~--;-~_'.""-_il -'(lf~peucabl")l' y ,,r_,' -\~'ff'
:~: \::i>:~;i'--:'j:t~;"'f~LL~~~~~~AfJ~~;~/ -~·;_,~:-~~!~~~ ~~ :~~n~~ic~ .• j,i;,.-•· :• :-fn<i~~--~ ';:t~-~~k.!lt!f131~, :.\·< ·; ~ _· "' ~
~. 1-, .,-~.~ -;c_... , Mcinlfuring1:)t:,. 't:.R_,8,0(:l~--:....t,,.;,' ,,,/_~ ! :\. · ! ·: ;t·t ·'HeattumP'Water:lojectjon~ -~ /: 1 '9th~·-:i ..... Jfottier'Jish1se·, .. _ •_,;t ".r' ·, .'\.·.~.-.·
\,C"''.J"•/r ~1-."-,t= ••/" J,, ><~••,~ • ••.,>,'\d; •~, \' ,'-a"••••••'/'"• -f,,_ ,)'-; r L ,r •, ,1•; -' •••·•• r
.:,J. ~ ·~· , ·_ !
1 ~~: · z WEu.; 1::0bATioN: (ShC.WsketCh ~tfta·~ b~)::.:c'"·, h~'• · .'~ ::: :t .,' ,_ ·1 :\~;.:~-, _-:·~ 1 , /~ • r.,w~:1~;;>-, :,; _ ,-•.;.,/,.' ·\·~. ;;.i_ t .
' ... ,_ ·· ~,· ,'",', ·-·~i:r,-·•_.,, __ Robbin--villE~ ty··'Gfatiaiti -... •"~··, ·i:"-!;,,.'•~ l .r•.;c:: ·•:.~J ~•ro, '/' To~lCS\ltaridSelting,,: ,:'~ '., ·" :{~~{:} ;-~i;);{;_·::.'.~·:~~;{;;t:,~;; ti;•:;;f '.:~'{:~i;;}(~~/~;~ 0Ii /:;;f ~f: \: \t;):;, -~~ft('i', -,:~.~~ i'~ani~3c.~; .. ~_~•~y,-,": .
. •~U--'.e~.:--.-}-: : )'s:_s,"~QVJNf;.R::Nc·oorMlint .. enanclfff'acJity.~ -~-::;, .:. __ ·_ -~.:.: '.; n;,,,.._' ;::, --::·--~;;.,.·.h , '~~,. :r--1 \~,'· . --}' , , , ,-;\ ·-:· ~allongi!udo .:-3-k-,t, '"" -' .-,. _
,-_ .... ,-,. , ~.-; .. _ ...
,i, 0,~--
~ 0 ~.'.• -,-, 'l~ •
' ... ,~ ,.
•·
I_
!~ Sheet) of (
~ Hart & :Hickman '"'"""""0'=•'""100 LOG OF BORING: M.\./-~ ~ Charlom:, NorthCaroliu A Professional Cozporation (704)S86-0007 (704}586-(1373-fu
0 If 1,1 /J,-.=-'-C. . I>-/,, le~.{' Uk
Project: p t> T-(Z., .b b ,.,;., .-, 'l I c.__ Surface Bev: 97. 81r .,-.,.,.vt" Sl-,t.-8 e,,::,,.,_.)
Top of Casing Elev: 97. (. ~t.c,,}4-#,.}~c....
Job Nol) I:> I -2..J _y Drilling Rig/Method: ~ ...... 1~,...,_ ¥51> /IJ,'r (l,,-h,r'/ /L'' )/....-.,&-) Location: ~ bb,..,..5.,; L/1' ;./r Sampling Method: e,-11,•,., /?ctvr-,J 4 / t-1/,-#$,..
V>
. ~ -.!l 0) -.c 0 ll<: 0) 0) Q. -0) 0 .a E
c -~ E i:-Q. " ?,-0) MATERIAL DESCRIPTION SPT, Blow Counts 0. WELL DIAGRAM 0 .c > ~
+' -~ 0 (The stratification· lines represent approximate 0 0. 0) u ~-> 0) a. U) 0) boundaries. The transition may be gradual.) 0) 0 E 0 a: ci 0 a. w U) ~ 0 :::, " U) CD U) -
I 1
0 = A. .L t.J. /s./.-,e.. --------. ··;, . ---=--=-= --t:.·J/ /JIJ.-.,,,,./ 7,...., · b,;;,,-.-, ,..,,_ ---&c-n,,& ,i,✓-~z.:«,,_d;, ~,-j:,1---. ' . --,~/~~Ii) cl"> ,·, 1,..__...,: Jt. ,,,c1. ---. . . . -OJ) ,,1 -. ----. ..JL ·-.
-----s -. . --. ;-,./~;,; ~-J..-,-, .$ Q ?"I -. -. . --j?.,u:. f',.._.J,_,,._iJ/J{ (!.,>,, .,,, ..L) ;t, Tl:, -' . -'I -. .
-Iv ,,,f-• ,:f, f..-,-,/,--ti c..-. -. ' -. . -. sJv-e -,... . J2,vV wo, L... . ' , ----I . . ,... . ' --. . I , . --10-. -,/ . -. . ,... . -. -. -'i...-· -~ ---. 77:>e ;2-/
-. .
i--15-.
-. .
-.
-. .
-.
-20--
I I I ,... .
-.
,... ---
1--25-.
Completion Depth: ,1.z.. ~marks: /!,_ ~j) Date Boring Started: '11/?Ar -m.-~ : ,.,, d '2,1, p a
Date Boring Completed: ;#.,~
Engineer /Geologist: e .A. ~I·
Drilling Contractor: e11-'>,: o,-.,;I '5',,.,,-o ~ J ')),-ri,/ ,,.,. o. -R'fl ,..,,1 ,, .?,l,.11. ;., Revision DrawnBy Date Checked Approved
-, ,
I I
PAGE 05
••WELL cd~s~RliCTm~:k~bJ~o
.'':• ;: "-; ' " • < ~ ' . -. ,_. ,. -... • : '. •
t\fOrth· _CaroJina -bepatirrfenf'm,~tirQ[J}nfint'and NaluraH~~oiJ~ ~•oM~ion Of·WaterQ·va1ify, ... !3·ro'u~dwat~r_S~tiDJ1 -' . ---. --' -,-. . . . '
·,wea..,bokrRAcTOR·(INDIVIDUAL} NAME' _cERTiFlCA.TioN#._ _ _ ,2209 ;,Wiilli CbNT'RACTOR cQMpAfN ~E-A =,;c-~P'="""c....~~~-~~---,--'-~-~~pl-!ONe t1. • ~-J7Gf)_~ffi9949,
,~!\~¥~~ONsmucT10N_PE~M1_T#; """'-----=-~~--~-A,ssoc1ATEDWC!PERM1t=
,: .. :.:, _>-.(ifeppJl~at>le). _ ·_ · ___ ._ -.. :f (;faptilfeabre), · ~"'-~-----'-c"------.,
'.' • 1,WELh USE (CheckAppficableB~:,
· ' ', ~onitol'ing~_ Recoveryr_ ' .. :~ .
/.;.[{e5idt.mtfaJ~ M~nicipa1pyb11e: _,,;._.:){~-'
· ' ". Heat Pump Water rnjection _. _ ., ' ;.,:
lnduatriaf Ag~cu1tura1
Other _ If O~~r,ri8(use_· ----~
·'15, ;scRE~i-i:· ,:. _, '
::; ,"~~~-~<_-~/d·;~·-·
• i Frbin ·~,--~~~­
', . ' '·Fro"! ,.,.,·c..-=-'­~-• r: :.:: , ~
' 18• SAN0/GRAVEL PACK:.· .
__ :.··:,: ~--t~:_:": .~ ., -~\ '?8PI~ i,.f~ .:_ '"--1.s -t T~ ·From·•:. , T<\
Slot'siio '. '
''. ;010 , ·'
16'. RE'-½RKS: · MW-4
. -, ' .. '·. __ ' Flmhmotmt,We!l'lnstarla1i w ;~ whicle ~Cte$$
. ' ,,,;.t~~., .,
PVC'·"
NIW-4 .
, 'J'Dpogi,aphicalll.aiid Satling -', ,,.,-'.,,.
:.St$16~e '_:-~ Vtil1ey : ;,at ' -·-·-..,.,.., ', -.. ,
Ls_tlltu_d'e/longitode . -, ,-· 1/,.
""""~-~...,,...~-'-'-~
",, j;~"'""~i}~~~,J!:~f~"f~··~~;,;;'
. tocAT1hksr<ETcH
(Silo,_;; dlr6ctlo11 and d[etan~ -fi6m:a_t 18.aat'two St~le
-Ro.ad!il; or othai" ,nilp-refei6nce pollJIS) • ., . " -... . .. -.. '.'. ·• ~, -_ ' .. -·.: . ., ..
□'•·.:. ,.,
.. <t
,.1,2a
sd
_;i, :-·;.·t,o:~eBY--ol!RTlffY THl\i'~EL~:w)s~c9N$1iuc_~o 1N_Acc_oRoANCEWtrti' 15.A:NcAc; 2c. WELi.coNSTRuc110N-J. : : ,·,st 'C .. s AND-1l-iATA'C-OPY::oi.TH1S·REC6Rot1ASBEENP.RovioED-To,13t1rWELLOWNE;~; ~ ' .. ' :_.; .• ;ic.t;;·:·. ·--• .. ' --c,· . • -• ---.. ~---. -" •
. , ' ' , '01/19/05
TI;fEWeµ.-·· ·o~TE
~--, ·-.,,:t ". j~'
'-
. ' ,, { .... ... "~ . .,,.~;j
,, ·,' • •:·;.,,, •• r·
-'. '
''~ . . "·•.~)-'•.t.
', ;\,!,: '
., -.....
'v
I I
Sheet/ of ;
~ Hart & Hickman """'""'""'''""''"'"'00 :Arrr,.~ . Cwlotte,NonhCUolilll. LOG OF BORING: /'I\ \J -.r r ~ A Professional Coq,oranon [phone] (704)S86-0373-&r:
Project: p D T-(Z."' hb •'i-' ,,.,'l)c:-___
Job Nol=> C> I -2.I y
Ae,. •~J
Surface ~ev: I O • • • • I (le.I + ad. -t,. ~ .s. '1-, u""' 1::,,, T • ':-..,¢ r ~--1u .. ~.,_,.... ~1r· !'.c,:.,,.
Top of Cosing Elev: 9 '9 .. 8, o .) a. ...c,...
Location: ~ hb,-..,,::;.,,; i/e. J[,.
DrilHng Rig/Method:Ca,. ~ re. 4'> ..:>
Sampling Method: 4,-,,/,;.,n (?,.:./-,,,.-,., .S •
-C) -C) C) -~ " o .c "' -· 0 . a. > QI
QI a w
0
f--
----
~ f-.
-5 -
f-.
--
f-.
--
-10-
--
-
--
--
-15-
--
--
--
--
-20-
--
--
--
--
-25-
" .!1 .c 0 a. e .a
c., E ~ L
QI a. VJ
E u VJ 0 ::::, VJ
-
~
1:-C) > 0 u
QI "'
.
MATERIAL DESCRIPTION
(The stratification-lines represent approximate
bound'!ries. The transition may be gradual.)
SPT, Blow Counts
I
L,,
WELL DIAGRAM
A • -I> ---~ ~ -. -'--
, L..-. .
. -. , . . . . l.--• . , -,,
, e
~ , . ,, -. . , . , -, --.
✓ ,, , -, -' -. ,: ,
,, ·-,
, --. T . -. ...,. ,,_ . ,
Completion Dept~: I f, /, -
Date Boring Started: '// 9 11> _,
~marks: /? 1
: ::ll..J n .-,,, : K. c, tl 2,1; P ,.
Date Boring Completed: 1// 91)
Engineer /Geologist: le-. A. ~,~7,-.._
~· ,
3/'
.
.
-
.
.
.
.
-
.
-
.
.
-
..
.
-
Drilling Controctor: e';i:..1,:~ 'S', .......... o ... 3 -::p,..:i,j,. ___ .IZ'L!,,,,J,. ?h.1/.:., Revision DrawnBy Dote Checked Approved ,
,
'·
'
~ Hart & Hickman ~:::=:.J::="!"1i&i ~ A Professional Corporation (704)S85-0007 C,04)S86-037Uu:
Project:~tT-12'1) 'l.br,,.sv:Hc.
Job No: :OT>,-2 IS­
Location:~ bbt, ,:i,;;I(~ lfl'
Surtace a,~ 9 9, L/ 7 ") f! ..f .,.j. 1 Top of Cas;ng aev: 9 9. 2-"7-) ~
Dnmng Rig/Method: Ca-..te.,,.-..._
SampOng Method:.('_. #.· ,t;.,,l,,,-~ _
"' -u
Q) " :c ~ a. Q) 0 -~ C: "' :8 .c ~ -Q) 0 a. a. > Q)
Q) Cl E w 0 111
0
r--
f--
r--
f-.-~ r-5 --f--
r--
f--
r--
r---:10-
r--
f--
r--
r--
· r-15-
r----
r----
-20---------
-25---------
-30---------
-JS---------
-40----. -----
-45---------
0 .0 E >. V)
V) u V) ::,
~i---
1-:'" ,.:-
r=.__~ .. ~
~ Y,f
Qlll.
Ill. a.
d
:J.
}l,,
.
MATERIAL DESCRIPTION
(The stratification lines represent approximate
boundaries. The transition may be gradual.)
, .
,C.41, f}a,~ b,,..,._, -3 ,-/ 3 .' /25, "'o/
::s l~.\.4,r
.e,~dro,-.,L.
/0-.f clcrlC 1i,r11w.i mo!,,--ks._ds-/,,,c,_
br~
~ -5,,...,.,,11 r..-~'-',fV""t:' e-?t-1 -61,~';JJ..:l-~.-:s-li,,"'"'-
JPd TP
' Completion Depth: °' u. _
Dote Boring Started: ,fi~A~r
Date Boring Completed: -4,?, u 1 Engineer/Geologist: j2. A .s,.,,.-h-.
DrillinQ Contractor: ;;,_ .1..A/.J ~i"'rn-o-~
V'
SPT, Blow Counts
~ E a. a. ~
n.O/t.8
Sheet/of/
WELL DIAGRAM
1 "-t> ~ =
.,
0 I.,
rD
,
0
p ,,
,-
f ) iJ
( d ·, ,-
t
b .
-.
---t " ~ -✓I. J,_ ~ i----'-·.' -. -.
' ~--' -" -. ~ ., --. -~· .
F' ID -
Checked Approved
Appendix C
Laboratory Analytical Data Sheets
s:\aaa•master projects\nc dot\dot-21S robbinsville\teiu\ph.ii Isa report doc
I
Case Narrative
Date: 2/2/05
Company: North Carolina Dept ofTransportation
rJo Hart & Hickman
Contact: Roger Smith
Address: 2923 S. Tryon St. Ste 100
Charlotte, NC 28203
,
Client Project ID: _DOT-215
Prism COC Group No: G0105571
The attached Laboratory Report contains the analytical results for the project Identified above and includes Quality Control Data and a
Chain-of-Custody copy.
Data qualifiers are flagged individually on each sample. A Key Reference for the data qualifiers appears at the bottom of this page.
Quality control statements and/or sample specific remarks are included in the sample comments section iif the
laboratory report for each sample affected.
Note: S!lmples for 625 were added, after sample receipt to the prep patch that was started at 8:oo· am on 1/21/05.
Please call if you have any questions relating to this analytical report.
Data Reviewed by: Paula A. Gilleland
Signature: :R,,0, \ J · jj; DD,~ t,O,
Project Manager: ~ela D. Overcash • · ·
Slgn_ature~ ¼, ,D. \ J .. d, pq,u for Angela Overcash
Approval Date: 2/2/05 Review Date: .=2/:..:2/:..:0c:.5 ______ _
Data Qualifier Key Reference:
#: Result outside of QC Limits
B: Compound also detected in the method blank
DO: Compound diluted out
E: Estimated concentration, calibration range exceeded
------------
J: The analyte was positively identified but the value is estimated below the reporting limit·
JH: Estimated concentration with a high bias
JL: Estimated concentration with a low bias
M: A matrix e(fect js present
T: Tentatively Identified compound." The concentration is estimated.
Note: This report should not be reproduced, except in ils entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road, P. 0. Box 240543, Charlotte, NC 28224-0403
Phone: [phone] Toll Free: 800/529-6364 Fax: [phone]
F:\common\casenarrative Revised 4/20/04 Revised 4/20/04
NC Certification No. 402 Laboratory Report SC Certification No. 9901_2
NC Drinking Waler Cert. No. 37735 2/2/05
Full Some. Anal)'tleaf & Environmental SOiutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: DW-1
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109241
Attn: Roger Smith Sample·Matrix: Water CDC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 12:30
2923 South Tryon St Ste 100 · Time Submitted: 01/21/05 8:05
Chartotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Ar:omatlc aod Halogeaated lfolatiles hll GClelD-ELCD
1, 1, 1,2-Tetrachloroethane BRL µg/L 0.50 0:11 6230D 01/26/05 5:06 erussell 002550
1, 1, 1-Trichloroethane BRL µg/L 0.50 0.080 6230D 01/26/05 5:06 erussell 002550
1, 1,2,2-Telrachloroelhane BRL µg/L 0.50 0.11 6230D 01/26/05 5:06 erusse/1 002550
1, 1,2-Trichloroethane BRL µg/L 0.50 0.080 6230D 01/26/05 5:06 erusse/1 002550
1, 1-Dichloroethane BRL µg/L 0.50 0.11 1-6230D 01/26/05 5:06 erussell 002550
1, 1-Dlchloroethene BRL µg/L 0.50 0.13 1 6230D 01/26/05 5:06 erussell 002550
1, 1-Dlchloropropene BRL µg/L 0.50 0.090 1 6230D 01/26/05 5:06 . erussel/ 002550
1,2,3-TMchlorobenzene BRL µg/L 0.50 0.12 1 6230D 01/26/05 5:06 erussell 002550
1,2,3-Trfchloropropane BRL µg/L 0.50 0.11 6230D 01/26/05 5:06 erussel! 002550
1,2,4-Trichlorobenzene BRL µg/L 0.50 0.040 6230D 01/26/05 5:06 erussell 002550
1,2,4-Trimethylbenzene BRL µg/L 0.50 0.10 1 6230D 01/26/05 5:06 erussell 002550
1,2-Dibromo-3-chloropropane BRL µg/L 0.50 0.14 1 6230D 01/26/05 5:06 erussel/ 002550
1,2-Dlbromoethane (EDB) BRL µg/L 0.50 0.12 1 6230D 01/26/0S-5:06 erussell 002550
1,2-0lchlorobenzene BRL µg/L 0.50 0.12 1 6230D 01/26/05 5:06 erussell 002550
1,2-Dlchloroethane BRL .µg/L 0.50 0.070 6230D 01/26105 5:06 erussell 002550
1,2-Dichl9ropropane BRL µg/L 0.50 0.12 6230D 01/26/05 5:06 erussell 002550
1,3,5-Trimethylbenzene BRL µg/L ·a.so 0.10 1. 6230D 01/26/05 5:06 eruSsell 002550
1,3-Dlch/orobenzene BRL µg/L 0.50 0.050 6230D 01/26/05 5:06 erussell 002550
1,3-Dlchloropropane BRL µg/L 0.50 0.070 1 6230D 01/26/05 5:06 erussell 002550
1,4-0lchlorobenzene BRL µg/L 0.50 0.060 1 6230D 01/26105 5:06 erussell 002550
2,2-Dichloropropane BRL µg/L 0.50 0.13 6230D 01/26105 5:06 erussell 002550
2-Chlorotoluene BRL µg/L 0.50 0.21 6230D 01/26/05 5:06 erussell 002550
4-Chlorotoluene BRL µg/L 0.50 0.090 1 6230D 01/26/05 5:06 erussell 002550
Benzene BRL µg/L 0.50 0.060 1 6230D 01/26/05 5:06 erussell 002550
Bromobenzene BRL µg/L 0.50 0.13 1 6230D 01/26105 5:06 erussell 002550
Bromochloromethane -BRL µg/L 0.50 0.090 6230D 01/26105 5:06 erusse!I 002550
Bromodichloromethane BRL µg/L 0.50 0.090 6230D 01/26/05 5:06. erussell 002550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 1 of 40
NC Certiflcatlon No. 402 Laboratory Report SC Certificatlon No. 99012
NC Drinking Waler Cert. No. 3TT35 2/2/05
Full Sarvlco Anlllytlcal & Environmental SalUtlon. FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: DW-1
Transportation Project No.: WBS#30173.126 Prism Sample ID: 109241
Attn: Roger Smith Sample Matrix: Water COC Group: 00105571
c/o Hart and Hickman Time Collected: 01/20/05 12:30
2923 South Tryon St Ste 100 Time Submitted: . 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Dateffime ID
Bromofonn BRL µg/L 0.50 0.050 1 62300 01/26105 5:06 erussefl Q02550
Bromomethane BRL µg/L 0.50 0.27 1 62300 01/26105 5:06 erussell Q02550
Carbon Teirachloride BRL µg/L 0.50 0.060 1 62300 01/26105 5:06 erussell Q02550
Chlorobenzene BRL µg/L 0.50 0.17 62300 01/26/05 5:06 erussell Q02550
Chloroethane BRL µg/L 0.50 0.41 62300 01/26105 5:06 erussell Q02550
Chloroform BRL µg/L 0.50 0.060 62300 01/26/05 5:06 erussell Q02550
Chloromethane BRL µg/L 0.50 0.14 6230D 01/26105 5:06 erussell 002550
cls• 1,2-Dlchloroethene BRL µg/L 0.50 0.13 1 62300 01/26/05 5:06 erussell Q02550 .
cis-1,3-Dlchloropropene BRL µg/L 0.50 0.14 1 6230D 01/26105 5:06 erusse/1 Q02550
Dlbromochloromethane BRL µg/L 0.50 0.080 1 6230D 01/26/05 5:06 erussell Q02550
Dlbromomethane BRL µg/L 0.50 0.13 6230D 01/26105 5:06 erussell Q02550
Dlchlorodlfluoromethane BRL µg/L 0.50 0.14 62300 01/26105 5:06 erussell Q02550
Ethylbenzene BRL µg/L 0.50 0.16 1 6230D 01/26105 5:06 erussell Q02550
Hexachlorob·utadiene BRL µg/L 0.50 0.17 1 6230D 01/26105 5:06 el'Ussell Q02550
lsopropyl ether (IPE) BRL µg/L 0.50 0.24 1 6230D 01/26105 5:06 erusse/1 Q02550
lsopropylbenzene BRL µg/L 0.50 0.10 1 6230D 01/26105 5:06 erussell Q02550
m,p-Xylenes BRL µg/L 1.0 0.43 1 6230D 01/26105 5:06 erussell Q02550
Methyl !-butyl ether (MTBE) BRL µg/L 0,50 0.14 6230D 01/26/05 5:06 erusse!/ Q02550
Methylene chloride BRL µg/L 2.0 0.75 1 6230D 01/26105 5:06 erussell Q02550
n-Butylbenzene BRL µg/L 0.50 0.19 1 6230D 01/26105 5:06 erussell Q02550
n-Propylbenzene BRL µg/L 0.50 0.10 1 6230D 01/26105 5:06 erusseU Q02550
Naphthalene BRL µg/L 0.50 0.10 1 6230D 01/26/05 5:06 erussell Q02550
a-Xylene BRL µg/L 0.50 0.16 6230D 01/26105 5:06 erussell Q02550
p-lsopropyltoluene BRL µg/L 0.50 0.17 1 6230D 01/26105 5:06 erussell Q02550
sec-Butylbenzene BRL µg/L ·o.so 0.12 1 6230D 01/26105 5:06 erusse!l Q02550
Styrene BRL µg/L 0.50 0.050 1 6230D 01/26/05 5:06 erussel! Q02550
lert-Butylbenzene BRL µg/L 0.50 0.13 1 6230D 01/26105 5:06 erussell Q02550
Tetrachloroethene BRL µg/L 0.50 0.11 1 6230D 01/26/05 5:06 erussell 002550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 2 of40
' '
I
'
I !
NC Certification No. 402 Laboratory Report SC CertificaHon No. 99012
NC Drinking Water Cert. No. 3TT35 2/2/05
FIID Sorvleo Analytical & Environmental Solutions FL CertificaUon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: DW-1
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109241
Attn: Roger Smith Sample Matrix: Water COC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 12:30
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Toluene BRL µg/L 0.50 0.11 1 6230D 01/26/05 5:06 erussell Q02550
trans-1,2-Dichloroethena BRL µg/L 0.50 0.27 1 6230D 01/26/05 /5:06 erussell Q02550
trans-1,3-Dlchloropropena BRL µg/L Q.50 0.070 6230D 01/26/05 5:06 erussell Q02550
Trlchloroalhane 1.9 µg/L 0.50 0.10 6230D 01/26/05 5:06 e~ssell aoi550
Trfchlorofluoromethane BRL µg/L 0.50 0.19 6230D 01/26/05 5:06 erussell Q02550
Vinyl chloride BRL µg/L 0.50 0.24 62300 01/26/05 5:06 erusse/1 Q02550
Surrogate % Recovery Control Limits
BromOchlorobenzene-ELCD 85 60 -144
1,4-Difluorobenzene-PID 101 50 -141
S~mlvolatlle Organic Com~ouods bi_GC[MS
1,2,4-Trlchlorobenzene
1,2~Dlchlorobenzene
1,3-D!chlorobenzene
1,4-Dlchlorobenzene
2,4,5-Trtchlorophenol
2,4,6-Trlchlorophenol
2,4-Dlchlorophenol
2,4-Dlmethylphenol
2,4-Dlnltrophenol
2,4-Dlnltrotoluena
2.6-Dlnltrotoluene
2-Chloronaphlhalene
2-Chlorophenol
2-Methylnaphlhalene
2-Methylphenol
2-Nltrophenol
BRL µg/L 9.7 2.4 625 01/22/05 9:01
BRL µg/L 9.7 2.6 625 01/22/05 9:01
BRL µg/L 9.7 1.8 625 01/22/05 9:01
BRL µg/L 9.7 2.3 1 625 01/22/05 9:01
BRL µg/L 9.7 2.5 1 625 01/22/05 9:01
BRL µg/L 9.7 1.7 1 625 01/22/05 9:01
BRL µg/L 9.7 1.8 1 625 01/22/05 9:01
BRL µg/L 9.7 0.65 1 625 01/22/05 9:01
BRL µg/L 49 0.65 625 01/22/05 9:01
BRL µg/L . 9.7 0.82 625 01/22/05 9:01
BRL µg/L 9.7 1.6 625 01/22/05 9:01
BRL µg/L 9.7 2.1 625 01/22/05 9:01
BRL µg/L 9.7 2.1 1 625 01/22/05 9:01
BRl µg/L 9.7 1.7 625 01/22/05 9:01
BRL µg/L 9.7 2.7 625 01/22/05 9:01
BRL µg/L 9.7 2.2 625 01/22/05 9:01
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone]
kellfot Q02493
kel/lot Q02493
kell!ot Q02493
kelliot Q02493
kelllot Q02493
kelllot .002493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
Page· 3· of 40
NC Certificatlon No. 402 Laboratory Report SC Certiflcatlon No. 99012
NC Drinking Water Cert No. 3TT35 2/2/05
FIii! SelYlca Analytleal & Emtronm1111t:al Solutions FL Certiflcatlon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: DW-1
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109241
Attn: Roger Smith Sample Matrix: Water COC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 12:30
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Diluti.on Method Analysis Analyst Batch
Limit Factor Date/Time ID
3&4-Melhylphenol BRL µg/L 9.7 3.6 1 625 01/22/05 9:01 kelllot Q02493
3,3"-Dichlorobenzidlne BRL µgli. 49 9.1 1 625 01/22/05 9:01 kelliot Q02493
4,6-Dlnltro-2-melhylphenol BRL µg/L 52 0.91 1 625 01/22/05 9:P1 kellfot Q02493
4-Bromophenylphenylelher BRL µg/L 9.7 1.9 1 625 01/22/05 9:01 keUJot Q02493
4-Chloro-3-melhylphenol BRL µg/1. 9.7 1.7 . 1 625 01/22/05 9:01 kell!ot Q0249~
4-Chlorophenylphenylelher BRL µg/L 9.7 1.6 1 625 01/22/05 9:01 kelllot Q02493
4-Nilrophenol BRL µg/L 49 0.58 1 625 01/22/05 9:01 kelllot Q02493
Acenaphlhene BRL µg/L 9.7 1.8 1 625 01/22/05 9:01 kellfot Q02493
Acenaphlhylene BRL µg/L 9.7 2.0 1 625 01/22/05 9:01 kelllot Q02493
Anthracene BRL µg/L 9.7 · 0.95 1 625 01/22/05 9:01 kelliot Q02493
Benzo(a}anthrat:ene BRL µg/L 9.7 0.91 1 625 01/22/05 9:01 kelliot Q02493
Benzo(a)pyrene BRL µg/L 9.7 0.97 1 625 01/22/05 9:01 kelfiot Q02493
Benzo(b)ffuoranthene BRL µg/L 9.7 1.7 1 625 01/22/05 9:01 kelliot Q02493
Benzo(g,h,l)perylene BRL µg/L 9.7 2.0 1 625 01/22/05 9:01 kelliot Q02493
Benzo(k)fluoranlhene BRL µg/L 9.7 1.8 1 625 01/22/05 9:01 kellfot Q02493
Bls(2-chloroelhoxy)melhane BRL µg/L 10 2.3 1 625 01/22/05 9:01 kelllot Q02493
Bls(2-chloroelhyl)elher BRL µg/L 9.7 2.0 1 625 01/22/05 9:01 kelliot Q02493
B1s(2-chlorolsopropyl)elher BRL µg/L 10 2.5 1 625 01/22/05 9:01 kelllot Q02493
i Bls(2-elhylhexyl)phlhalate BRL µg/L 9.7 0.69 1 625 01/22/05 9:01 kelliot Q02493
Butylbenzylphlhalate BRL µg/L 9.7 0.68 1 625 01/22/05 9:01 kelllot Q02493
Chrysene BRL µg/L 9.7 0.55 1 625 01/22/05 9:01 kelliot Q02493
Dl-n-butylphlhalate BRL µg/L 9.7 1.4 1 625 01/22/05 9:01 keUlot Q02493
Dl-n-octylphlhalate BRL µg/L 9.7 . 2.1 1 625 01/22/05 9:01 kelllot Q02493
Dlbenzo(a,h)anlhracene BRL µg/L 9.7 1.1 1 625 01/22/05 9:01 kelllot Q02493
Dlbenzofuran BRL µg/L 9.7 2.1 1 625 01/22/05 9:01 kelllot Q02493
Dlelhylphlhalate BRL µg/L 9.7 1.1 1 625 01/22/05 9:01 kelliot Q02493
Dlmelhylphlhalate BRL µg/L 9.7 1.4 1 625 01/22/05 9:01 ke!Hot Q02493
Fluoranthene BRL µg/L 9.7 0.91 1 625 01/22/05 9:01 kelllol Q02493
449 Springbrook Road • P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone] Page4 of40
I '·
Full lmvleo Analyt!Cill & Envfrvnmolltal Solutlans
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
N-Nltrosodl-n-propylamlne
Naphthalene
Nltrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert No. 37735
FL Certification No. E87519
Project ID: DOT-215
Result
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
Project No.: WBS# 30173.126
Sample Matrix: Water
Units
µg/L
µg/L
µg/L
µg/1.
µg/L·
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
Report MDL
Limit
9.7 · 1A
9.7 1.3
9.7 2.1
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
2.3
1.7
1.7
1.6
2.1
2.1
1.8
1.7
9.7 0.87
9.7 0.87
9.7 0.88
Dilution
Factor
1
1
1
1
1
1
1
1
1
Method
625
625
625
625
625
625
625
625
625
625
625
625
625
625
Laboratory Report
2/2/05
Client Sample ID: DW-1
Prism Sample ID: 109241
COC Group: G0105571
Time Collected: 01/20/05 12:30
Time Submitted: 01/21/05 8:05
Analysis
Dateffime
Analyst Batch
ID
01/22/05 9:01
01/22/05 9:01
01/22/05 9_:01
kelllot Q02493
kelllot Q02493
kelllot Q02493
01/22/05 9:01 kelllot
01/22/05 9:01 kelliot
01/22/05 9:01 kelllot
01/22/05 9:01 kelllot
01/22/05 9:01 kel/lot
01/22/05 9:01 kelliot
01/22/05 9:01 ketnot
01/22/05 9:01 kelliot
01/22/05 9:01 kelliot
01/22/05 9:01 kelllot
01/22/05 9:01 kel/lot
Q02493
Q02493
Q02493
Q02493
Q02493
qo2493
Q02493
Q02493
Q02493
Q02493
Q02493
No TIC's were detected.
Sample Prepar:a,tion:
Extractable Petroleym Hydrocarbons by GC~FJD
C11-C22 Aromatics BRL µg/L
C19-c36 Allphatics
C9-C18 Allphatics
BRL
BRL
µg/L
µg/L
1030 mL / 1 mL 625 01/21/05 8:00 smanlvanh P11635
100
100
100
71
31
75
Surrogate
Terphenyl.<f14
Phenol.<f5
Nltrobenzene-d5
2-Fluorophenol
2-Fluoroblphenyl
2,4,6-Tribromophenol
%Recovery
106
16
70
29
85
116
Control Limits
10 • 154
10-48
22 -103
10-59
29-112
27-125
MADEP EPH 01/26105 12:02 grappaccloll Q02665
1 MADEP EPH 01/26/05 12:02 grappaccloll Q02665
MADEP EPH 01/26/05 12:02 grappaccloll Q02665
449 Springbrook Road • P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 • Fax: [phone] Page 5 of40
:
i •
-;
I
'_,
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert No. 3TT35 2/2/05
FWI Strvlca Analytical & Enrilonmental Solutions FL Certification No. EB7519
North Carolina Department of Project ID: DOT-215 Client Sample ID: DW-1
Transportatlon Project No.: WBS# 30173.126 Prism Sample ID: 109241
Attn: Roger Smith Sample Matrix: Water _COCGroup: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 12:30
2923 South Tryon SL Ste 100 Time Submitted: 01/21/05 8:05
Chartotte, NC 28203_
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Sample Preparation: 1000 ml / 2 ml EPH 01/25/05 7:00 smanlvanh P11658
Surrogate %Recovery Control Limits
o-Terphenyl 93 40 -140
2-Fluorobiphenyl 108 40-140
2-Bromonaphthalene 99 40-140
1-Chloro-odadecane 73 40 -140
Metals b3t: ICP
Lead BRL mg/L 0.0050 0.0011 1 6010B 01/31/05 14:19 mcampbell Q02688
Sample Preparation: 50 mL /
Volatlle eetcoleum l::f3t:drocamoos by: GC-f[DlEID
CS-CB Allphatics BRL µg/L 100 75
C9-C1 O Aromatics BRL µg/L 100 35
C9-C12 Allphattcs BRL µg/L 100 70
Sample Comment(s):
All results are reported on a wet-weight basis
50 ml SM3030 C
1 MADEPVPH
MADEPVPH
1 MADEPVPH
Surrogate
2,5-Dlbromotoluene-PID
2,5-Dibromotoluene-FIO
01/21/05 14:25
01/27/05 7:01
01/27/05 7:01
01/27/05 7:01
% Recovery
82
86
cnguyen P11637
erussell Q02486
erussell Q02486
erussell Q02486
Control Limits
70-130
70 -130
I I BRL = Below Reporting llmlt
-I
J = Esllmated value between the Reporting llmit and the MDL
Angela D. Overcash, V.P. Laboratory Services
449 Springbrook Road • P ,0. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1·800/529•6364 • Fax: [phone] Page 6 of40
I '
• I
,1 i
i :
L
I ,
L
I '
FuQ Service Anafytle&I & Envlf?llmantal SDM!ons
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter
NC Certification No. 402
SC CertificaUon No. 99012
NC Drinking Water Cert No. 3TT35
FL CertificaUon No. E87519
Project ID: DOT-215
Project No.: WBS#30173.126
Sample Matrix: Water
Result Units Report MDL Dilution Method
Limit Factor
Laboratory Report
2/2/05
Client Sample ID: MW-1
Prism Sample ID: 109242
COC Group: . G0105571
Time Collected: 01/20/05 13:15
Time Submitted: 01/21/05 8:05
Analysis
Datemme
Analyst Batch
ID
Ar~matfc and Halogenated Vo(atlles by GC(PID-ELCD
1,1,1,2-Tetrachloroelhane BRL · µg/L 5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
1.7
0.80
1.1
0.80
1.1
1.3
0.90
1.2
1.1
0.40
1.0
1.4
1.2
1.2
0.70
1.2
1.0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
62300
62300
62300
62300
62300
62300
62301;)
6230D
62300
62300
62300
6230D
62300
6230D
62300
62300
6230D
62300 ·
62300
6230D
62300
62300
62300
62300
6230D
62300
62300
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erusseU
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42· erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
01/26/05 19:42 erussell
1, 1, 1-Trichloroelhane
1, 1,2,2-Tetrachloroelhane
1, 1,2-Trichloroelhane
1, 1-DichlOroethane
1, 1-Dlchloroethene
1, 1-Dlchloropropene
1,2,3-TrichlorobE!nzene
1,2,3-Trichloropropane
1,2_,4-Trichlorobenzene
1,2,4-Trimelhylbenzene
1,2-Dlbromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dlchloroethane
1,2-Dlchloropropane
1,3,5-Trimethylbenzene
1,3-0ichlorobenzene
1,3-0lchloropropane
1,4-Dichlorobenzene
2,2-Dlchloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Brom a benzene
Bromochloromethane
' ' Bromodlchloromethane
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
79.
BRL
BRL
BRL
BRL
BRL
22
BRL
BRL
BRL
BRL
BRL
BRL
320
BRL
BRL
BRL
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
5.0 0.50
5.0 0.70
5.0 0.60
5.0
5.0
1.3
2.1
5.0 0.90
5.0 0.60
5.0 1.3
5.0 0.90
5.0 0.90
449 Springbrook Road -P:o. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Page 7 of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012 A NC Drinking Water Cert. No. 37735 2/2/05 e FL Certification No. E87519 Full Service Analytfcaf & Envfronrnental Solutlomi
I
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-1
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109242
Attn: Roger Smith Sample Matrix: Water COCGroup: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 13:15
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
r ' Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch ' I Limit · Factor Datemme ID
Bromoform BRL µg/L 5.0 0.50 10 6230D 01/26/05 19:42 erussell Q02550
I Bromofflethane BRL µg/L 5.0 2.7 10 6230D 01/26/05 19:42 erussell Q02550
I I
Carbon Tetrachloride BRL µg/L 5.0 0.60 10 6230D 01/26/05 19:42 erusseli Q02550
r Chlorobenzene BRL µg/L 5.0 1.7 10 6230D 01/26/05 19:42 erussell Q02550
Chloroeth8ne BRL µg/L 5.0 4.1 10 6230D 01/26/05 19:42 erussell Q02550
Chloroform BRl µg/L 5.0 0.60 10 6230D 01/26/05 19:42 erussell Q02550
I
Chloromethane BRL µg/L 5.0 1.4 10 6230D 01/26/05 19:42 erussell Q02550
cls-1,2-Dlchloroethene BRL µg/L 5.0 1.3 10 6230D 01/26/05 19:42 erussell Q02550
cis• 1,3-0ichloropropene BRL µg/L 5.0 1.4 10 6230D 01/26/05 19:42. erussell . Q02550
Dlbromochloromethane BRL µg/L 5.0 0.80 10 6230D 01/26/05 19:42 erussell Q02550
Dlbromomethane BRL µg/L 5.0 1.3 10 6230D 01/26/05 19:42 erussell Q02550
Oichlorodlfluoromethane BRL µg/L 5.0 1.4 10 6230D 01/26/05 19:42 erussell Q02550
Ethylbenzene 150 µg/L 5.0 1.6 10 6230D 01/26/05 19:42 erussell Q02550
Hexachlorobutadiene BRL µg/L 5.0 1.7 10 6230D 01/26/05 19:42 erussell . Q02550
lsopropyl ether (!PE) 32 µg/L 5.0 2.4 10 6230D 01/26/05 19:42 erussell Q02550
lsopropyfbenzene 27 µg/L 5.0 1.0 10 6230D 01/26/05 19:42 erussell Q02550
m ,p-Xylenes 220 µg/L 10 4.3 10 6230D 01/26/05 '19:42 erusse/1 Q02550
Methyl !-butyl ether (MTBE) 690 µg/L 5.0 1.4 10 6230D 01/26/05 19:42 er'ussell Q02550
Methylene chloride BRL µg/L 20 7.5 10 6230D 01/26/05 19:42 erussell Q02550
r-n-Butylbenzene 34 µg/L 5.0 1.9 10 6230D 01/26/05 19:42 erussell Q02550
I I ! n-Propylbenzene 91 µg/L 5.0 1.0 10 6230D 01/26/05 19:42 erussell Q02550
Naphthalene 100 µg/L 5.0 1.0 10 6230D 01/26/05 19:42 erussell Q02550
a-Xylene 150 µg/L 5.0 1.6 10 6230D 01/26/05 19:42 erussell Q02550
p-lsopropyltoluene BRL µg/L 5.0 1.7 10 6230D 01/26/05 19:42 erussell Q02550
sec-81:,1tylbenzene BA µg/L 5.0 1.2 10 6230D 01/26/05 19:42 erussell Q02550
Styrene BRL µg/L 5.0 0.50 10 6230D 01/26/05 19:42 erussell Q02550
tert-Butylbenzene BRL µg/L 5.0 1.3 10 6230D 01/26/05 19:42 erussell Q02550
Tetrachloroethene BRL µg/L 5.0 1.1 10 6230D 01/26/05 19:42 erussell Q02550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 • Fax: [phone] Page8 of 40
I I
' I '
r I '
'
I '
I I
'
·-I ' I
'
I
I
I
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert No. 3TT35
Full Somce Anatylfcal & £nvfronlnmtal Sotidlon11 FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample. ID: Transportation Project No.: · WBS# 30173.126 Prism Sample ID: Attn: Roger Smith Sample Matrix: Water COC Group: c/o Hart and Hickman Time Collected: 2923 South Tryon St Ste 100 Time Submitted:
Chartotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis
Limit Factor' Datemme
Toluene 300 pg/L 5.0 1.1 · 10 62300 01/26/05 19:42
trans-1,2-Dichloroethene BRL pg/L 5.0 2.7 10 62300 01/26/05 19:42
trans-1.3-Dlchloropropene BRL pg/L 5.0 0.70 10 62300 01/26/05 19:42
Trichloroethene BRL pg/L 5.0 1.0 10 62300 01/26/05 19:42
Trichlorofluoromethane BRL pg/L 5.0 1.9 10 6230D 01/26/05 19:42
Vinyl chloride BRL pg/L 5.0 2.4 10 62300 01/26/05 19:42
Surrogate % Recovery
Bromochlorobenzene-ELCD 113
1 ;4-Difluorobenzene-PID 111
Sem(volatlle Orgaalc Com~OY!Jds bl£ GClMS
1,2,4-Trichlorobenzene BRL pg/L 9.7 2.4 1 625 01/22/05 9:51
1,2-Dichlorobenzene BRL pg/L 9.7 2.6 1 625 01/22/05 9:51
1,3-Dichlorobenzene BRL pg/L 9.7 1.8 625 01/22/05 9:51
1,4-0ichlorobenzen8 BRL pg/L 9.7 2.3 1 625 01/22/05 9:51
2,4,5-Trichlorophenol BRL pg/L 9.7 2.5 625 01/22/05 9:51
2,4,ll-Trichlorophenol BRL pg/L 9.7 1.7 1 625 01/22/05 9:51
2,4-Dlchlorophenol BRL pg/L 9.7 1.8 625 01/22/05 9:51
2,4-Dlmethylphenol BRL pg/L 9.7 0.65 1 625 01/22/05 9:51
2,4-Dinltrophenol BRL pg/L 49 0.65 1 625 01/22/05 9:51
2,4-Dlnltrotoluene BRL pg/L 9.7 0.82 625 01/22/05 9:51
2,6-Dlnltrotoluene BRL pg/L 9.7 1.6 1 625 01/22/05 9:51
2-Chloronaphthalene BRL pg/L 9.7 2.1 625 01/22/05 9:51
2-Chlorophenol BRL pg/L 9.7 2.1 625 01/22/05 9:51
2-Methylnaphthalene BRL pg/L 9.7 1.7 1 625 01/22/05 9:51
2-Methylphenol BRL pg/L 9.7 2.7 1 625 01/22/05 9:51
2,Nitrophenol BRL pg/L 9.7 2.2 625 01/22/05 9:51
449 Springbrook Road • P.D. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
2/2/05
MW-1
109242
G0105571
01/20/05 13:15
01/21/05 8:05
Analyst Batch
ID
erussell ·002550
erussell 002550
erussell 002550
erussell 002550
erussell 002550
erussell 002550
Control Limits•
60 -144
50 -141
kelliot 002493
kelllot 002493
kell/ot 002493
kelllot 002493
kelliot 002493
kelllot 002493
keltlot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelliot 002493
kelllot 002493
kelllot 002493
kelllot 002493
Page 9 of40
NC Certification Na. 402 Laboratory Report SC Certificatlan Na. 99012
NC Drinking Water Cert. Na. 37735 2/2/05
Full Sorvl~ AMlytlcaJ & Errvlronmtlltl/ Salutlo1111 · FL CertifiaaUon No. E87519
North Carolina Department of Project lb: DOT-215 Client Sample ID: MW-1
Transportation Project No.: WBS#30173.126 Prism Sample ID: 109242
i l A\111: Roger Smith
'
Sample Matrix: Water COC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 13:15
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
!
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
3&4-Melhylphenal BRL µg/L 9.7 3.6 1 625 01122/05 9:51 kellfot 002493
3,3"-Dlchlarobenzidlne BRL µg/L 49 9.1 625 01122/05 9:51 kelllot 002493
4,6-Dlnltro-2-melhylphenol BRL µg/L 52 0.91 625 01/22/05 9:51 kelllot 002493
~
4-Bromophenylphenylether BRL µg/L 9.7 1.9 1 . 625 01122/05 9:51 kel/lot 002493
4-Chlaro-3-melhylphenol BRL µg/L 9.7 1.7 1 · 625 01122/05 9:51 ke/llot 002493
4-Chlarophenylphenylether BRL µg/L 9.7 1.6 625 · 01/22/05 9:51 kell/ot 002493
4-Nltrophenal BRL µg/L 49 0.58 625 01122/05 9:51 kellfot 002493
Acenaphthene . BRL µg/L 9.7 1.8 625 01122/05 9:51 kelllot 002493
Acenaphthylene BRL µg/L 9.7 2.0 1 625 01122/05 9:51 kelllot 002493
Anthracene BRL µg/L 9.7 0.95 1 625 01122/05 9:51 kelllot 002493
Benzo{a)anthracene BRL µg/L 9.7 0.91 625 01122/05 9:51 kel/lot 002493
Benza(a)pyrene BRL µg/L 9.7 0.97 1 625 01/22/05 9:51 ke/llot 002493
Benzo(b)fluoranthen_e BRL µg/L 9.7 1.7 1 625 01122/05 9:51 kelllot 002493
I ' Benza(g,h,l)perylene BRL µg/L 9.7 2.0 625 01122/05 9:51 kelllot 002493
Benza(k)fiuaranlhene BRL µg/L 9.7 1.8 1 625 01122/05 9:51 kel/lot 002493
Bls(2-chlaroethaxy)methane BRL µg/L 10 2.2 1 625 01122/05 9:51 kel/lot 002493
Bis(2-chlaraethyl)elher BRL µg/L 9.7 2.0 1 625 01/22/05 9:51 ke!Uot 002493
Bls(2-chlarolsaprapyl)ether BRL µg/L 10 2.4 625 01122/05 9:51 kelllot 002493
Bis(2-elhylhexyl)phlhalate BRL µg/L 9.7 0.69 625 01122/05 9:51 kelllot 002493
Butylbenzylphthalate BRL µg/L 9.7 0.68 1 625 01122/05 9:51 kelliot 002493
Chrysene BRL µg/L 9.7 0.55 625 01122/05 9:51 kelliot 002493
Di-n-butylphthalate BRL µg/L 9.7 1.4 625 01122/05 9:51 kellfot 002493
D1-n-<>ctylphthalate BRL µg/L 9.7 2.1 1 625 01122/05 9:51 kelllot 002493
Dibenza(a,h)anlhracene BRL µg/L 9.7 1.1 -1 625 01/22/05 9:51 kelllot 002493
Dibenzofuran BRL µg/L 9.7 2.1 625 01/22/05 9:51 kelHot 002493
Dlethylphthalate BRL µg/L 9.7 1.1 1 625 01122/05 9:51 kelllot 002493
Dlmethylphthalate BRL µg/L 9.7 1.4 625 01122/05 9:51 kelliot 002493
Fluoranthene BRL µg/L 9.7 0.91 625 01/22/05 9:51 kelllot 002493
449 Sprl.ngbroak Road -P.O. Bax 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Tall Free Number: 1•800/529-6364 -Fax: [phone] Page 10 of40
I '
1 I
NC Certlflcatlon No. 402 Laboratory Report SC Certlficatlon No. 99012
NC Drinking Water Cert No. 37735
FuU Slll'Ylcti Anlllytlcaf & Environmental Solutlon1 ·FL Certlficatlon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID:
Transportation
Attn: Roger Smith
do Hart and Hickman
2923 South Tryon St. Ste 100
Charlotte, NC 28203
Parameter
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocycfopentadlene
Hexachloroethane
lndeno( 1,2.3-cd)pyrene
lsophorone
N-Nltrosodl-n-propylamlne
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Project No.: WBS# 30173.126 Prism Sample ID:
Sample Matrix: Water COC Group:
Time Collected:
Time Submitted:
Result Units Report MDL DIiution Method Analysis
Limit Factor Datemme
5.4J µg/L 9.7 1.4 1 625 01/22/05 9:51
BRL µg/L 9.7 1.3 1 625 01/22/05 9:51
BRL µg/L 9.7 2.1 1 625 01/22/05 9:51
BRL µg/L 9.7 2.3 625 01/22/05 9:51
BRL· µg/L 9.7 1.7 1 625 01/22/05 9:51
BRL µg/L 9.7 1.7 625 01/22/05 9:51
BRL µg/L 9,7 1.6 625 01/22/05 9:51
BRL µg/L 9.7 2.1 625 01/22/05 9:51
75 µg/L 9.7 2.1 1 625 01/22/05 9:51
BRL µg/L 9.7 1.8 625 01/22/05 9:51
BRL µg/L 9.7 1.7 625 01/22/05 9:51
3.7J· µg/L 9.7 0.87 1 625 01/22/05 9:51
BRL µg/L 9.7 0.87 625 01/22/05 9:51
BRL µg/L 0:1 0.88 625 01/22/05 9:51
449 Springbrook Road -P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone]
2/2/05
MW-1
109242
G0105571
01/20/05 13:15
01/21/05 8:05
Anal~st Batch
ID
kelllot Q02493
kel/lot Q02493
kelllot Q02493
kelllot Q02493
kelllot . Q02493
kellfot Q02493
kelllot Q02493
kEllllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kell/ot 002493
kelllot Q02493
Page 11 of40
, __
NC CertlficaUon No. 402
SC CertlflcaUon No. 99012
NC Drtnklng Water Cert No. 37735
FL CertlflcaUon No. E87519
Laboratory Report
2/2/05
Fuf! Sarvlc, Analytli:a.l & Envfronmont:il Solutlomi
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St. Ste 100
Chartotte, NC 28203 ·
Parameter Result
TICS for 109242 Method 625
TIC: 2-Methylnaphthalene
TIC: Toluene
TIC: Ethylbenzene
TIC: Benzene, dimethyl
TIC: p-Xylene
TIC: Benzene, propyl
TIC: Benzene, ethyl-2-methyl
TIC: Benzene, trimethyl
TIC: Unknown
TIC: Inclan, methyl
Sample Preparation:
~
Extractable Petroleum l:::b':drocarbons hll GC-EID
C11-C22 Aromatics 1000
C19-G36 AllphaUcs BRL
C9-G18 Allphatics 100
Sample Preparation:
Metals b3t: Jee
Project ID:
Project No.:
Sample Matrix:
Units Report
Limit
50 ug/L Est.
DOT-215
WBS# 30173.126
Water
MDL Dilution
Factor
Client Sample ID:
Prism Sample ID:
CDC Group:
Time Collected:
Time Submitted:
Method Analysis
Datemme
113 ug/L Est.
79 ug/L Est.
120 ug/L Est.
67 ug/L Est.
55 ug/L Est.
56 ug/L Est.
62 ug/L Est.
59 ug/L Est.
71 ug/L Est.
1030 mL / 1 mL 625 01/21/05 8:00
Surrog3te ¾ Recovery
Terphenyt-d14 104
Phenol-d5 19
Nitrobenzene-d5 70
2-Fluorophenol 29
2-Fluoroblphenyt 95
2,4,6-Trtbromophenol 115
µg/L 100 71 1 MAOEPEPH 01/25/05 23:04
µg/L 100 31 MAOEPEPH 01/25/05 23:04
µg/L 100 75 MADEP EPH 01/25/05 23:04
1000 mL 2 mL EPH 01/25105 7:00
Surrogate % Recovery
o-Terphenyt 92
2-Fluoroblphenyt 111
2-Bromonaphthalene 122
1-Chloro"-octadecane 45
MW-1
109242
G0105571
01/20/05 13:15
01/21/05 8:05
Analyst Batch
ID
smanlvanh P11635
Control Limits
10 -154
10-48
22-103
10-59
29 -112
27 -125
grappaccfoll Q02665
g'rappacctoll Q02665
grappaccloll Q02665
smanlvanh P11658
Control Limits
40-140
·40-140
40 -140
40 -140
Lead BRL mg/L 0.0050 0.0011 6010B 01/31/05 14:15 mcampbell Q02688
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1·800/52~-6364 • Fax: [phone] Page 12 of40
i '
NC CertlficaUon No. 402
SC Certification No. 99012
Full Sorvlc.a Antlytlcal a Ell'lironm•ntal SIIM!ons
NC Drinking Waler Cert. No. 37735
FL Certificatlon No. E87519
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Cha~otte, NC 28203
Parameter
Sample Preparatioll:
Result
Volatile ·eetro(eum tf~dtocarbons b~ Gc-eiDlEID
C5-C8 AliphaUcs 1400
C9-C10 Aromatics 1300
C9-C12 Aliphatlcs 280
Sample Comment(s):
All results are report~d on a wet-weight basis
BRL = Below Reporting Limit
Project ID:
Project No.:
Sample Matrix:
Units . Report
Limit
50
µg/L 100
µg/L 100
µg/L 100
J == Estimated value ~etween the Reporting Umit and the MDL
Angela D. Overcash, V.P. Laboratory Services
Laboratory Report
2/2/05
DOT-215 Clierit Sample ID:
WBS# 30173.126
Water
Prism Sample ID:
CQCGroup:
MDL
mL /
75
. 35
70
Time Collected:
Time Submitted:
Dilution Method
Factor
50 mL SM3030C
1 MADEPVPH
MADEPVPH
1 MADEPVPH
Surrogate
2,5-Dibromololuene-PID
2,5-Dibromotoluen~FID
Analysis
Datemme
01/21/05 14:25
01/27/05 17:21
01/27/05 17:21
01/27/05 17:21
% Recovery
109
10T
MW-1
109242
G0105571
01/20/05 13:15
01/21/05 8:05
Analyst Batch
ID
cnguyen P11637
erussell Q02486
erussell Q02486
erussel/ Q02486
Control Limits
70-130
70-130
449 Springbrook Road • P ,0. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6384 • Fax: [phone] Page 13 of40
.. ; -I
I ;
-NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Waler Cert No. 3TT35 2/2/05
Full SoMc:a Analytl'ed & Envlronmontal SolutlGIIS FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-2 Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109243 Attn: Roger Smith Sample _Matrix: Water COG Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:30 2923 South Tryon Sl Ste 100 Time S_ubmltted: 01/21/05 8:05 Chariotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Aromi!tlc i!Dd Halogeaateg l£olat!les b~ GClflD-J;;LCO
1, 1.1,2-Tetrachloroelhane BRL µg/L 0.50 0.17 1 6230D 01/26/05 16:16 erussell 002550
1, 1, 1-Trichloroelhane BRL µg/L 0.50 0.080 6230D 01/26/05 16:16 erussell 002550
1, 1.2,2-Tetrachloroethane BRL µg/L 0.50 0.11 1 6230D 01/26/05 16:16 erussell 002550
1, 1,2-Trichloroethane BRL µg/L 0.50 0.080 6230D 01/26/05 16:16 erusse!I 002550
1, 1-Dlchloroelhane BRL µg/L 0.50 0.11 1 6230D 01/26/05 16:16 erussell 002550
1, 1-Dichloroethene BRL µg/L 0.50 0.13 6230D 01/26/05 16:16 erussell 002550
1, 1-Dlchloropropene BRL µg/L 0.50 0.090 1 6230D 01/26/05 16:16 erussell 002550
1,2,3-Trichlorobenzene BRL µg/L 0.50 0.12 1 6230D 01/26/05 16:16 erussell 002550
1,2,3-Trichloropropane BRL µg/L 0.50 0.11 1 6230D 01/26/05 16:16 erussell 002550
1,2,4-Trichlorobenzene BRL µg/L 0.50 0.040 6230D 01/26/05 16:16 erussell 002550
1,2,4-Trimelhylbenzeno 0.58 µg/L 0,50 0.10 1 6230D 01/26/05 16:16 e/'Ussell 002550
1,2-Dibramo-3-chloropropane BRL µg/L 0.50 0.14 1 6230D 01/26/05 16:16 erussell 002550
1,2-Dibromoelhane (EDB) BRL µg/L 0.50 0.12 1 62300 01/26/05 16:16 erussell 002550
1,2-Dichloroben~ene BRL µg/L 0.50 0.12 1 6230D 01/26/05 16:16 erusse!I 002550
1,2-Dlchloroelhane BRL µg/L 0.50 0.070 1 62300 01/26/05 16:16 erussell 002550
1,2-Dlchloropropano BRL µg/L 0.50 0.12 6230D 01/26/05 16:16 erussell 002550
1,3,5-Trimelhylbenzeno BRL µg/L 0.50 0.10 6230D 01/26/05 16:16 erussell 002550
1,3-Dlchlorobenzene BRL µg/L 0.50 0.050 6230D 01/26/05 16:16 erussell 002550
1,3-Dlchlorojlropane BRL µg/L 0.50 0.070 1 6230D 01/26/05 16:16 erussell 002550
1,4-Dlchlarobenzene BRL µg/L 0.50 0.060 1 6230D 01/26/05 16:16 erussell 002550
2,2-Dlchloropropane BRL µg/L 0.50 0.13 6230D 01/26/05 16:16 eruSSell 002550
2-Chlorotoluene BRL µg/L 0.50 0.21 6230D 01/26/05 16:16 erusseU 002550
4-Chlorotoluene BRL µg/L 0.50 0.090 6230D 01/26/05 16:16 erussell 002550
Benzene 25 µg/L 0.50 0.060 6230D 01/26/05 16:16 erussell 002550
Bromobenzene BRL µg/L 0.50 0.13 1 6230D 01/26/05 16:16 erussell 002550
Bromochloromethane BRL µg/L 0.50 0.090 6230D 01/26/05 16:16 erussell 002550.
Bromodlchloromethane BRL µg/L 0.50 0.090 6230D 01/26/05 16:16 erussell 002550
449 Springbrook Road • P.O. Box 240543 -Cha~otto, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 14of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
FuQ Smvlc• Analytleal & Envlronrrtlmt116olutlons FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-2 Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109243 Attn: Roger Smith Sample Matrix: Water CDC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:30 2923 South Tryon St. Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL DIiution Method Analysis Analyst Batch
Limit Factor Dateffime ID
Bromoform BRL µg/L 0.50 0.050 1 6230D 01/26105 16:16 erussell Q02550
Bromomethane BRL µg/L 0.50 0.27 6230D 01/26105· 16:16 erussell Q02550
Carbon Tetrachloride BRL µg/L 0.50 0.060 1 6230D 01/26105 16:16 enJssell Q02550
Chlol'Obenzene BRL µg/L 0.50 0.17 1 6230D 01/26105 16:16 erussell . Q02550
Chloroethane BRL µg/L 0.50 0:41 6230D 01/26/05 16:16 erusse/1 . Q02550
Chlorofonn BRL µg/L 0.50 0.060 1 6230D 01/26105 16:16 erussell Q02550
Chloromethane BRL µg/L 0.50 0.14 6230D 01/26105 16:16 erussel/ Q02550
cls-1,2-Dlchloroeth ene BRL µg/L 0.50 0.13 1 6230D 01/26105 16:16 erussell Q02550
cls-1,3-Dlchloropropene BRL µg/L 0.50 0.14 1 6230D 01/26105 16:16 erussell Q02550
Dibromochloromethane BRL · µg/L 0.50 0.080 6230D 01/26/05 16:16 erusse11 Q02550
Dlbromomethane BRL µg/L 0.50 0.13 1 6230D 01/26/05 16:16 erussell Q02550
-' Dlchlorodlfluoromethane BRL µg/L 0.50 0.14 6230D . 01/26105 16:16 erussel/ Q02550
E:thylbenzene 5.0 µg/L 0.50 0.16 1 6230D 01/26105 16:16 erussell Q02550
Hexachlorobutadlene BRL µg/L 0.50 0.17 6230D 01/26105 16:16 erussell Q02550
lsopropyl ether (IPE) 1.9 µg/L 0.50 0.24 6230D 01/26105 16:16 erussell Q02550
lsopropylbenzene 4.4 µg/L 0.50 0.10 1 6230D 01/26/05 16:16 erussell Q02550
m,p-Xyfenes 1.1 µg/L 1.0 0.43 6230D 01/2si05 16:16 erussell Q02550
Methyl !-butyl ether (MTBE) 32 µg/L 0.50 0.14 1 6230D 01/26/05 16:16 erusse/1 Q02550
Methylene chloride BRL µg/L 2.0 0.75 1 6230D 01/26/05 16:16 erussell Q02550
n-Butylbenzene 4.4 µg/L 0.50 0.19 1 6230D 01/26/05 16:16 erussel/ Q02550
n-Propyfbenzene 11 µg/L 0.50 0.10 1 6230D 01/26/05 16:16 erussell Q02550
Naphthalene 38 µg/L 0.50 0.10 6230D 01/26/05 16:16 erussell Q02550
o-Xylene 0.78 µg/L 0.50 0.16 1 6230D 01/26/05 16:16 erussell Q02550
p-lsopropylloluene BRL µg/L 0.50 0.17 6230D 01/26105 16:16 erussell Q02550
sec-Butylbenzene 1.3 µg/L 0.50 0.12 1 6230D 01/26/05 16:16· erussell Q02550
Styrene BRL µg/L 0.50 0.050 6230D 01/26105 16:16 erussell Q02550
lert-Butylbenzene BRL µg/L 0.50 0.13 1 6230D 01/26105 16:16 erussell Q02550
Tetrachloroethene BRL µg/L 0.50 0.11 6230D 01/26105 16:16 erussell Q02550
449 Springbrook Road • P .o. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1·800/529-6364 • Fax: [phone] Page 15 of40
NC CertificaUon No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full Service ArialytfcaJ & Envltonmtntlll Solutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-2 Transportation . Project No.: WBS# 30173.126 Prism Sample ID: 109243 Attn: Roger Smith Sample Matrix: Water CDC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:30 2923 South Tryon Sl Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Toluene 2.4 µg/L 0.50 0.11 6230D 01/26105 16:16 erussell Q02550
trans-1,2-Dlchloroethene BRL µg/L 0.50 0.27 1 6230D 01/26/05 16:16 erussell Q02550
trans-1,3-Dlchloropiopene BRL µg/L 0.50 0.070 6230D 01/26105 16:16 erussell Q02550
Trichloroelhene BRL µg/L 0.50 0.10 6230D 01/26105 16:16 erussell Q02550
Trlchlorofluoromethane BRL µg/L 0.50 0.19 6230D 01/26105 16:16 erussell Q02550
Vinyl chloride BRL µg/L 0.50 0.24 6230D 01/26105 16:16 erussell Q02550
Surrogate % Recovery Control Limits
Bromochlorobenzene-ELCD 123 60 -144
1,4-Difluorobenzene-PID 107 50 -141
Semlvolatl(e Ocganlc Com12ounds bl£ GClMS
1,2,4-Trichlorobenzene BRL µg/L 9.7 2.4 625 01/22/05 10:42 kelllot Q02493
1,2-Dichlorobenzene BRL µg/L 9.7 2.6 625 01/22/05 10:42 kelllot Q02493
1,3-Dlchlorobenzene BRL µg/L 9.7 1.8 625 01/22/05 10:42 kellfot Q02493
1,4-Dlchlorobenzene BRL µg/L 9.7 2.3 625 01/22/05 10:42 kel/lot Q02493
2,4,5-Trichlorophenol BRL µg/L 9.7 2.5 625 01/22/05 10:42 kelllot Q02493
2,4,6-Trichlorophenol BRL µg/L 9.7 1.7 1 625' 01/22/05 10:42 kell!ot Q02493
2;4-Dichlorophenol BRL µg/L 9.7 1.8 625 01/22/05 10:42 kelllot Q02493
2,4-Dimelhylphenol BRL µg/L 9.7 0.65 625 01/22/05 10:42 kelllot Q02493
2,4-Dlnitrophenol BRL µg/L 49 0.65 625 01/22/05 10:42 kelllot Q02493
2,4-Dinitrotoluene BRL µg/L 9.7 0.82 1 625 01/22/05 10:42 kelllot Q02493
2,6-Dinitrotoluene BRL µg/L 9.7 1.6 625 01/22/05 10:42 kelliot Q02493
2-Chloronaphlhalene BRL µg/L 9.7 2.1 625 01/22/05 10:42 kelllot Q02493
2-Chlorophenol BRL µg/L 9.7 2.1 625 01/22/05 10:42 kelllot Q02493
2-Melhylnaphlhalene BRL µg/L 9.7 1.7 1 625 01/22/05 10:42 ·kelllot Q02493
2-Melhylphenol BRL µg/L 9.7 2.7 625 01/22/05 10:42 kelHot Q02493
2-Nltrophenol BRL µg/L 9.7 2.2 625 01/22/05 10:42 kelllot Q02493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone] Page 16 of 40
NC Certification No. 402 Laboratory Report SC Certificatlon No. 99012
NC Drinking Water Cert No. 3TT35 2/2/05
FuO Servi.co Analytlcal & Envlronm.ntil SoMlons FL Certifioatlon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-2 Transportation Project No.: WBS#30173.126 Prism Sample ID: 109243 Attn: Roger Smith Sample Matrix: Water COCGroup: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:30 2923 South Tryon St. Ste 100 Time Submitted: 01/21/05 8:05' Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
3&4-Methylphenol BRL µg/L 9.7 3.6 1 625 01/22/05 10:42 kelllol 002493
3,3'-Dlchlorobenzldlno BRL µg/L 49 9.1 1 625 01/22/05 10:42 kelllot 002493
4,6-Dlnltro-2-methyfphenol BRL µg/L 52 0.91 1 625 01/22/05 10:42 kelllbt 002493
4-Bromophenyfphenylether BRL µg/L 9.7 1.9 1 625 01/22/05 10:42 kelllol 002493
4-Chioro-3-methyfphenol BRL µg/L 9.7 1.7 1 625 01/22/05 10:42 kelllot 002493
4-Chlorophenyfphenyfether BRL µg/L 9.7 1.6 1 625 01/22/05 10:42 kelllot 002493
4-Nllrophenol BRL µg/L 49 0.58 1 625 01/22/05 10:42 kelllol 002493
Acenaphthene BRL µg/L 9.7 1.8 1 625 01/22/05 10:42 kelllol 002493
Acenaphthylene BRL µg/L 9.7 2.0 1 625 01/22/05 10:42 kelllot 002493
Anthracene BRL µg/L 9.7 0.95 1 625 01/22/05 10:42 kelllot 002493
Benzo(a)anthracene BRL µg/L 9.7 Q.91 1 625 01/22/05 10:42 kelllot 002493
Benzo(a)pyrene BRL µg/L 9.7 0.97 1 625 01/22/05 10:42 kelllot 002493
Benzo(b)fluoranthene BRL µg/l 9.7 1.7 1 625 01/22/05 10:42 kelUot 002493
Benzo(g,h,l)perylene BRL µg/L 9.7 2.0 1 625 01/22/05 10:42 kelllot 002493
Benzo(k)fiuoranthene BRL µg/L 9.7 1.8 1 625 01/22/05 10:42 kelllot 002493
Bis(2-chloroethoxy)111ethane BRL µg/L 10 2.3 1 625 01/22/05 10:42 kelllot 002493
Bls(2-chloroethyl)ether BRL µg/L 9.7 2.0 1 625 01/22/05 10:42 kelllot 002493
Bls(2-chlorolsopropyf)ether BRL µg/L 10 2.5 1 625 01/22/05 10:42 kelllot 002493
Bls(2-ethyfhexyl)phthalate BRL µg/L 9.7 0.69 1 625 01/22/05 10:42 kelllot 002493
Butylbenzyfphthalate BRL µg/L 9.7 0.68 1 625 01/22/05 10:42 kelllot 002493
Chrysene BRL µg/L 9.7 0.55 1 625 01/22/05 10:42 kelllot 002493
Dl-n-bulylphthalate BRL µg/L 9.7 1.4 1 625 01/22/05 10:42 kelllot 002493
Dl-n-oclylphthalate BRL µg/L 9.7 2.1 1 625 01/22/05 10:42 kelllot 002493
Dlbenzo(a,h)anthracene BRL µg/L 9.7 1;1 1 625 01/22/05 10:42. ketllot 002493
Dibenzofuran BRL µg/L 9.7 2.1 1 625 01/22/05 10:42 kelllot 002493.
Dlethyfphthalate BRL µg/L 9.7 1.1 1 625 01/22/05 10:42 kelllot 002493
Dimethyfphthalate BRL µg/L 9.7 1.4 1 625' 01/22/05 10:42· kelllot 002493
Fluoranthene BRL µg/L 9.7 0.91 1 625 01/22/05 10:42 kelllot 002493
449 Springbrook Road • P.O. Boie 240543 • Charlotte, NC 28224-0543
Phone: 704/529•6364 • Toll Free Number: 1·800/529-631,4 • Fax: [phone] Page 17 of 40
~
'-· '
-,
I !
, I
L i
: ,I
A NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735
"Full Semco Aruilytlca! & Envllonmentzl Solut!oml FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: Transportation Project No.: WBS# 30173.126 Prism S,!mple ·ID: Attn: Roger Smith Sample Matrix: Water COCGroup: c/o Hart and Hickman Time Collected:
2923 South Tryon Sl Ste 100 Time Submitted: Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis
Limit Factor Datemme
Fluorene 3.3J µg/L 9.7 1.4 1 625 01/22/05 10:42
Hexachlorobenzene BRL µg/L 9.7 1.3 1 625 01/22/05 10:42
Hexachlorobutadlene BRL µg/L 9.7 2.1 1 625 01/22/05 10:42
Hexachlorocyclopentadlene BRL. µg/L 9.7 2.3 625 01/22/05 10:42
Hexachloroethane BRL µg/L 9.7 1.7 1 625· 01/22/05 10:42
lndeno(1,2.3-cd)pyrene BRL µg/L 9.7 1.7 1 625 01/22/05 10:42
lsophorone BRL µg/L 9,7 1.6 1 625 01/22/05 10:42
N-Nltrosodi-n-propylamlne BRL µg/L 9.7 2.1 625 01/22/05 10:42
Naphthalene 34 µg/L 9.7 2.1 1 625 01/22/05 10:42
Nitro benzene BRL µg/L 9,7 1.8 1 625 01/22/05 10:42
Pentachlorophenol BRL µg/L 9.1 1.7 1 625 01/22/05 10:42
Phenanthrene 3.0J µg/L 9.7 0.87 1 625 01/22/05 10:42
Phenol BRL µg/L 9.7 0.87 625 01/22/05 10:42
Pyrene BRL, µg/L 9.7 0.88 1 625 01/22/05 10:42
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
212/05
MW-2
109243
G0105571
01/20/05 13:30
01/21/05 8:05
Analyst Batch
ID
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kell!ot Q02493
ketnot Q02493
kelllot Q02493
kelllot Q02493
kelllot Q02493
kel/iot ·002493
kelliot Q02493
kelllot Q02493
Page 18of40
: I
I '
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert. No. 37735
FIIIIScirtrcttAnllytlcal&Envrronl!llllfalSofutlon1 FL Certification No. E87519
Laboratory Report
2/2/05
North Carolina Department of
Trarisportatlon
Attn: Roger Smith
Project ID:
Project No.:
DOT~215
WBS#30173.126
Client Sample ID: MW-2
Prism Sample ID: 109243
do Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter Result
TICs for ·109243 Method 625
TIC: Unknown
TIC: Unknown
TIC: Dodecane, trimethyl
TIC: Naphthalene, dimethyl
TIC: Naphthalene, dimethyl
TIC: Hexadecane
TIC: Naphthalene, trimethyl
TIC Pentadecane, tetramethyl
TIC Naphthalene, dimethyl
TIC Naphthalene, 2-methyl·
Sample Preparation:
Extractable eotroleum f:hldrocarbons b}! GC-EID
C11-C22 Aromatics 770
C19-C36 Aliphatlcs BRL
C9-C18 Aliphatlcs 510
Sample Preparation:
Metals by ICP
Lead BRL
Sample Matrix: Water
Units Report MDL
Limit
32 ug/L Est.
22 ug/L Est.
. 21 ug/L Est .
31 ug/L Est,
31 ug/L Est.
·35 ug/L Est.
23 ug/L Est, · 48 ug/L Est.
21 ug/L Est.
32 ug/L Est.
1030 ml /
µg/L 100 71
µg/L 100 31
µg/L 100 75
1000 ml I
mg/L 0.0050 0.0011
COG Group: G0105571
Time Collected: 01/20/05 13:30
Time Submitted: 01/21/05 8:05
Dilution Method Analysis Analyst Batch
Factor Datemme ID
1 ml 625 01/21/05 8:00 smanivanh P11635
Surrogate % Recovery Control Limits
Terphenyf-d14 94 10-154
Phenol-d5 20 10-48
Nltrobenzene-dS BB 22 -103
2-Fluorophenol 33 10-59
2-Fluorobiphenyf 101 29-112
2,4,6-Tribromophenol 118 27 -125
MADEP EPH 01/26/05 2:31 , grappaccloll Q02665
1 MADEP EPH 01/26/05 2:31 grappaccJoll Q02665
MADEPEPH 01/26/05 2:31 grappaccioll Q02665
2 ml EPH 01/25/05 7:00 smanivanh P11658
Surrogate % Recovery Control Limits
o-Terphenyf 97 40-140
2-Fluoroblphenyf 102 40 -140
2-Bromonaphthalene• 112 40-140
1-Chloro-octadecane 64 40-140
1 6010B 01/31/05 13:28 mcampbell Q02688
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 19 of 40
i
I
I
I __ I
NC Certiflcatlon No. 402
SC Certiflcatlon No. 99012
NC Drinking Waler Cert. No. 37735
FuQ &!rvlc, Analytlu! & Envltonmontal Solullons FL.Certiflcatlon No. E87519
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon SL Ste 100
Charlotte, NC 28203
Parameter Result
Sample Preparation:
~olatl!e ee!roleym H~d[OCarboas ~ GC-elDlEID
C5-C8 Allphatlcs 83J
C9-C10 Aromatlcs 150
C9-C12 Allphattcs 110
Sa.mple Comment(s):
All results are reported on a wet-wf)ight basis
BRL = Below Reporting Umit
Project ID:
Project No.:
. Sample Matrix:
Units Report
Limit
50
µg/L 100
µg/L 100
µg/L 100
J = Estimated value between the Reporting Um/I and tha MDL
Angela D. OVercash, V.P. Laboratory Services
Laboratory Report
212/05
DOT-215 Client Sample ID: WN>/·2
WBS# 30173.126 Prism Sample ID: 109243
Water
MDL
mL I
75
35
70
COC Group:
Time Collected:
Time Submitted:
DIiution Method Analysis
Factor Datemme
50 mL SM3030C 01/21/05 14:25
1 MADEPVPH 01/27/05 7:53
MADEPVPH 01/27/05 7:53
1 MADEPVPH 01/27/05 7:53
Surrogate %Recovery
2,5-Dibromotoluene-PID
2,5-Dlbromotoluene-FID
82
102
G0105571
01/20/05 13:30
01/21/05 8:05
Analyst Batch
ID
cnguyen P11637
erussell Q02486
erussell Q02486
erussell 002486
Control Limits
70 -130
70-130
449 Springbrook Road • P,o. !lox 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 20 of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 3TT35 2/2/05
' Full SON!ee Analytlpil & Envlromn~ Solu!laM FL Certification No. E87519
' ',
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-3
TransP.ortation Project No.: WBS# 30173.126 Prism Sample ID: 109244
Attn: Roger Smith Sample Matrix: Water COC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 13:50
2923 South Tryon St. Ste 100 · Time Submitted: 01/21/05 8:05
Chariotte, NC 28203
Parameter Result Units Report MDL DIiution Method Analysis Analyst Batch
Limit Factor Datemme ID
A[omat[c amt Hal.ogem:i~ed Vo(atl(es b~ GClflD-ELCD
1, 1, 1,2-Tetrachloroelhane BRL µg/L 0.50 0.17 1 6230D 01/26105 5:59 . erussell Q02550
1, 1, 1-Tnchloroethane BRL µg/L 0.50 0.080 6230D 01/26105 5:59 erussell Q02550
1, 1,2,2-Tetrachloroelhane BRL µg/L 0.50 0.11 1 6230D 01/26/05 5:59 eru~ell Q02550
1, 1,2-Trichloroethane BRL µg/L 0.50 0.080 1 6230D 01/26105 5:59 erussell Q02550
1,1-Dlchloroelhane BRL µg/L 0.50 0.11 1 6230D 01/26105 5:59 erussel/ Q02550
1, 1-Dlchloroethene BRL µg/L 0.50 0.13 6230D 01/26105 5:59 erussel/ Q02550
1, 1-Dlchloropropene BRL µg/L 0.50 0.090 1 6230D 01/26105 5:59 erussell Q02550
1,2,3-Trichlorobenzene BRL µg/L 0.50 0.1_2 6230D 01/26105 5:59 erussell Q02550
1,2,3-Trichloropropane BRL µg/L 0.50 0.11 6230D 01/26105 5:59 erussell Q02550
1,2,4-Trichlorobenzene BRL µg/L 0.50 0.040 · 6230D 01/26105 5:59 erussell Q02550
1,2,4--Trimethylbenzene 1.5 µg/L 0.50 0.10 1 6230D 01/26105 _5:59 erussell Q02550
1,2-Dibromo-3-chloropropane BRL µg/L 0.50 0.14 6230D 01/26105 5:59 erussell Q02550
1,2-Dibromoethane (EDB) BRL µg/L o.~o 0.12 6230D 01/26105 5:59 erussell Q02550
1,2-Dlchlorobenzene BRL µg/L 0.50 0.12 1 6230D 01/26/05 5:59 erussell Q02550
1,2-Dlchloroelhane BRL µg/L 0.50 0.070 6230D 01/26105 5:59 erusse/1 Q02550
1,2-Dichloropropane BRL µg/L 0.50 0.12 6230D 01/26/05 5:59 erussell Q02550
1,3,5. Trimethyfbenzene 0.96 µg/L 0.50 0.10 6230D 01/26/05 5:59 erussell Q02550
1,3-Dichlorobenzene BRL µg/L 0.50 0.050 1 6230D 01/26105 5:59 erussell Q02550
1,3-Dichloropropane BRL µg/L 0.50 0.070 6230D 01/26/05 5:59 erussell q02550
1,4-Dichlorobenzene BRL µg/L 0.50 0.060 6230D 01/26/05 5:59 erussell Q02550
2,2-Dlchloropropane BRL µg/L 0.50 0.13 1 6230D 01/26/05 5:59 erusseU Q02550
2-Chlorotoluene BRL µg/L 0.50 0.21 6230D 01/26105 5:59 erussell · Q02550
4-Clilorotoluene BRL µg/L 0.50 0.090 1 6230D 01/26/05 5:59 erussell Q02550
Benzene 0.95 µg/L 0.50 0,060 6230D 01/26/05 5:59 erussel/ Q02550
Bromobenzene BRL µg/L 0.50 0.13 6230D 01/26105 5:59 erussell Q02550
Bromochloromethane BRL µg/L 0.50 0.090 1 6230D 01/26105 5:59 erussell Q02550
Bromodichloromethane BRL µg/L 0.50 0.090 6230D _01/26105 5:59 erussel/ Q02550
I '
449 Springbrook Road -P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 21 of 40
I
I J----NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Waler Cert. No. 37735 2/2/05
Fun SCNJca Analytlc.al & Enwonmanlil Solutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-3 Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109244 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:50 2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Bromoform BRL µg/L 0.50 0.050 1 6230D 01/26105 5:59 erussell 002550
Bromomethane BRL µg/L 0.50 0.27 1 6230D 01/26/05 5:59 erussell Q02550
Carbon Tetrachloride BRL µg/L 0.50 0.060 1 6230D 01/26105 5:59 erusseU Q02550
·chlorobenzene BRL µg/L 0.50 0.17 1 6230D 01/26/05 5:59 erussell Q02550
· Chloroethane BRL µg/L 0.50 0.41 1 6230D 01/26105 5:59 erussell Q02550
Chloroform BRL µg/L 0.50 0.060 1 6230D 01/26/05 5:59 erussell Q02550
Chloromethane BRL µg/L 0.50 0.14 1 6230D 01/26105 5:59 erussell Q02550
cis-1,2-Dlchloroethene BRL µg/L 0.50 0.13 1 6230D 01/26105 5:59 erussell Q02550
cis-1,3-Dlchloropropene BRL µg/L 0.50 0.14 1 6230D 01/26/05 5:59 erussell Q02550
Dibromochloromethane BRL µg/L 0.50 0.080 1 '6230D 01/26105 5:59 erussell Q02550
Olbromomethane BRL µg/L 0.50 0.13 1 6230D 01/26/05 5:59 erussell Q02550
Dichlorodifluoromethane BRL µg/L 0.50 0.14 1 6230D 01/26/05 5:59 erussell Q02550
Ethylbenzene BRL µg/L 0.50 0.16 1 6230D 01/26/05 5:59 erussell Q02550
Hexachlorobutadiene BRL µg/L 0.50 ·.0.17 1 6230D 01/26/05 5:59 erussell Q02550
lsopropyl ether (IPE) 1.3 µg/L 0.50 0.24 1 6230D 01/26/05 5:59 erussell Q02550
lsopropylbenzene BRL µg/L 0.50 0.10 1 6230D 01/26105 5:59 erussell Q02550
,:n,p-Xylenes 1.6. µg/L 1.0 0.43 1 6230D 01/26/05 5:59 erussel/ Q02550
Methyl I-butyl ether (MTBE) 37 µg/L 0.50 0.14 1 6230D 01/26105 5:59 erussell Q02550
Methylene chloride BRL µg/L 2.0 0.75 1 6230D 01/26105 5:59 erussell Q02550
n-Butylbenzene 2.1 µg/L 0.50 0.19 1 6230D 01/26/05 5:59 erussell Q02550
n-Propylbenzene 0.58 µg/L 0.50 0.10 1 6230D 01/26105 5:59 erussell Q02550
Naphthalene BRL µg/L 0.50 0.10 1 6230D 01/26/05 5:59 erussell Q02550
a-Xylene 1.4 µg/L 0.50 0.16 1 6230D 01/26105 5:59 erussell Q02550
p-lsopropyltoluene BRL µg/L 0.50 0.17 1 6230D 01/26/05 ·5:59 erussell Q02550
sec.Butylbenzene 0.59 µg/L 0.50 0.12 1 6230D 01/26/05 5:59 erussell Q02550
Styrene BRL µg/L 0.50 0.050 1 6230D 01/26/05 5:59 erussell Q02550
tert-Butylbenzene BRL µg/L 0.50 0 .. 13 1 6230D 01/26/05 5:59 erussel/ Q02550
Tetrachlaroethene BRL µg/L 0.50 0.11 1 6230D 01/26/05 5:59 erussell Q02550
449 Springbrook Road -P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page22 of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full Senieo AnalylluA & Envlronmantal Solutlon1 FL Certification No. E87519 1
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-3 Transportation . Project No.: WBS# 30173.126 Prism Sample ID: 109244 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:50 2923 South Tryon Sl Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Toluene BRL µg/L 0.50 0.11 1 6230D 01/26/05 5:59 erussell Q02550
trans-1,2-Dlchloroethene BRL µg/L 0.50 0.27 6230D 01/26/05 5:59 erussell Q02550
trans-1,J..Dlchloropropene BRL µg/L 0.50 0.070 1 6230D 01/26/05 5:59 erussell Q02550
Trfchloroethene BRL µg/L 0.50 0.10 1 6230D 01/26/05 5:59 erusse!I Q02550
Trlchlorofluoromethane BRL µg/L 0.50 0.19 1 6230D 01/26/05 5:59 erussell Q02550 .
Vinyl chloride BRL µg/L 0.50 0.24 1 6230D 01/26/05 5:59 erussell Q02550
Surrogate %Recovery Control Limits
Bromochlor0benzene-ELCD 97 60 -1'44
1,4-Difluorobenzene-PID 102 50-141
Semlvolallle Organic Comnouods by: GC[MS
1,2,4-Trichlorobenzene BRL µg/L 9.7· 2.4 625 01/22/05 11:33 kel!lot Q02493
1,2-Dlchlorobenzene BRL µg/L 9.7 2.6 1 625 01/22/05 11 :33 kelllot Q02493
1,3-Dlchlorobenzene BRL µg/L 9,7 1.8 625 01/22/05 11 :33 kellfot Q02493
1,4-Dlchlorobenzene BRL µg/L 9.7 2.3 625 01/22/05 11:33 kelllot Q02493
2,4,5--Trichlorophenol BRL µg/L 9.7 2.5 1 625 01/22/05 11 :33 kelllot Q02493
2,4,6-Tr!chlorophenol BRL µg/L 9.7 1.7 625 01/22/05 11:33 kelllot Q02493
2,4-Dichlorophenol BRL µg/L 9,7 1.8 1 625 01/22/Q5 11:33 kelllot Q02493
2,4-Dlmethylphenol BRL µg/L 9.7 0.65 625 01/22/05 11 :33 kell!ot Q02493
2,4-Dlnltrophenol BRL µg/L 49 0.65 625 01/22/05 11:33 kell/ot Q02493
2,4-Dlnltrotoluene BRL µg/L 9.7 0.82 1 625 01/22/05 11 :33 kelllot Q02493
2,6-Dinltrotoluen~ BRL µg/L 9.7 1.6 625 01/22/05 11:33 kelliot Q02493
2-Chloronaphthalene BRL µg/L 9.7 2.1 1 625 01/22/05 11 :33 kell!ot Q02493
2-Chlorophenol BRL µg/L 9.7 2.1 625 01/22/05 11:33 kelliot Q02493
2-Methylnaphthalene BRL µg/L 9,7 1.7 625 01/22/05 11:33 kelllot Q02493
2-Methylphenol BRL µg/L 9.7 2.7 625 01/22/05 11:33 kelllot Q02493
2-Nitrophenol BRL µg/L 9.7 2.2 625 01/22/05 11:33 kellfot Q02493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1·800/529-6364 -Fax: [phone] Page23 of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full SelVlca An11ytlcal & Envlronmc11t1i' Solutforn FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-3
Transportation Project No.: WBS#30173.126 Prism Sample ID: 109244 Attn:. Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:50 2923 South Tryon SL Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis· Analyst Batch
Limit Factor Datemme ID
3&4-Melhylphenol BRL µg/L 9.7 3.6 1 625 01/22/05 11:33 keUlot Q02493
I '
' 3,3· ~Dlchlorob~nzldine BRL µg/L 49 9.1 625 01/22/05 11:33 kelllot Q02493
4,6-Dlnltro-2-melhylphenol BRL µg/L 50 0.88 625 01/22/05 11:33 kE!lliOt Q02493
4-Bromophenylphenylelher BRL µg/L 9.7 1.9 .1 625 01/22/05 11:33 kelllot Q02493
4-Chloro-3-melhylphenol BRL µg/L 9.7 1.7 1 625 01/22/05 11 :33 kelllot Q02493
4-Chlorophe_nylphenylelher BRL µg/L 9.7 1.6 625 01/22/05 11:33 kelllot Q02493
4-Nitrophenol BRL µg/L 49 0.58 625 01/22/05 11 :33 kel!lot Q02493
Acenaphthene BRL µg/L 9.7 1.8 1 625 01/22/05 11:33 kelliot Q02493
Acenaphthylene BRL µg/L 9.7 2.0 625 01/22/05 11:33 kelliot Q02493
Anthracene BRL µg/L 9.7 0.95 1 625 01/22/05 11 :33 kelliot Q02493
Benzo(a)anlhracene BRL µg/L 9.7 0.91 625 01/22/05 11:33 kelUot 002493
Benzo(a)pyrene BRL µg/L 9.7 0.97 1 625 01/22/05 11 :33 kelllot Q02493
Benzo(b}fluoranthene BRL µg/L 9.7 1.7 625 01/22/05 11:33 kelliot Q02493
Benzo(g,h,l)perylene BRL µg/L 9.7 2.0 1 625 01/22/05 11:33 kelliot Q02493
Benzo(k)fluoranthene BRL µg/L 9.7 1.8 625 01/22/05 11:33 kelllot Q02493
Bls(2-chloroelhoxy)melhane BRL µg/L 10 2.2 1 625 01/22/05 11:33 kelliOt Q02493
Bis(2-chloroelhyl)elher BRL µg/L 9.7 2.0 625 01/22/05 11 :33 kelllot' Q02493
Bls(2-chlorolsopropyl)ether BRL µg/L 10 2.4 1 625 01/22/05 11:33 kelliot Q02493
Bls(2-elhylhexyl)phlhalate BRL µg/L 9.7 0.69 625 01/22/05 11:33 ke/Hot Q02493
Butylbenzylphlhalate BRL µg/L 9.7 0.68 1 625 01/22/05 11:33 kelllot Q02493
Chrysene BRL µg/L 9.7 0.55 625 01/22/05 11:33 kelllot Q02493
Dl-n-butylphlhalale BRL µg/L 9.7 1.4 1 625 01/22/05 11 :33 kelllot Q02493
Dl-n-octylphlhalate BRL µg/L 9.7 2.1 . 625 01/22/05 11:33 kelllot Q02493
Dlbenzo(a.h)anlhracene BRL µg/L 9.7 1.1 625 01/22/05 11:33 kellfot Q02493
Dlbenzofuran BRL µg/L 9.7 2.1 62? 01/22/05 11:33 kelliot Q02493
Dlelhylphlhalate BRL µg/L 9.7 1.1 625 01/22/05 11:33 kelliot Q02493
Dlmelhylphlhalate BRL µg/L 9.7. 1.4 1 625 01/22/05 11:33 kelllot 002493
Fluaranthene BRL µg/L 9.7 0.91 625 01/22/05 11:33 kelliot Q02493
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6384 -Fax: [phone] Page24 of40
I '
,~
I I
Full Sanrlee Analy!lcal & Enwonmentd Salu!!Oltl
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter
fluorene
Hexachlorobenzene
Hexachlorobutad/ene
Hexachlorocydopentadiene ·
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
N-Nitrosodl-n-propylamlne
Naphthalene
NitrobenzE!ne
Penta9hlorophenol
Phenanthrene
Phenol
Pyrene
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert. No. 3TT35
F~ Certification No. E87519
Result
Project ID:
Project No.:.
Sample Matrix:
□nits Report
Limit
9.7
9,7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
DOT-215
WBS# 30173.126
Water
MDL
1.4
1.3'
2.1
2.3
1.7
1.7
1.6
2.1
2.1
1.8
1.7
Dilution
Factor
1
1
1
1
1
1
1
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/l
µg/L
µg/l
µg/l
µg/L
µg/l
µg/L
9.7 0.87 1
9.7 0.87
9.7 0.88
Method
625
625
625
625
625
625
625
625
625
625
625
625
625
625
TICS for 109244 Method 625
TIC: Phenol, dirnethylethyl 16 ug/L Est.
Sample Preparation:
Extractable Petroleum Hydrocarbons by GC~EID
1030 ml / 1 ml 625
Surrogate
Terphenyl-d14
Phenol-d5
Nitrobenzene.:ct5
2-Fluorophenol
2-Fluoroblphenyl
2,4,6-Trlbromophenol
Laboratory Report
212/05
Client Sample ID: MW-3
Prism Sample ID:. 109244
coc Group: G0105571
Time Collected: 01/20/05 13:50
Time Submitted: 01/21/05 8:05
Analysis Analyst Batch
ID Datemme
·01/22/05 11:33 kelllol
01/22/05 11:33 kelllol
01/22/05 11.:33 kelllot
01/22/05 11 :33, kelllol
01/22/05 11 :33 kelllol
01/22/05 11:33 ke/liot
01/22/05 11:33 kelllot
01/22/05 11 :33 kelllot
01/22/05 11 :33 kelllol
01/22/05 11 :33 kelllot
01/22/05 11:33 kelllot
01/22/05 11:33 kelllol
01/22/05 11:33 kelliot
01/22/05 11 :33 kelllot
Q02493
Q02493
Q02493
·002493
Q02493
Q02493
Q02493
Q02493
Q02493
Q02493
Q02493
Q02493
Q02493
Q02493
01/21/05 8:00 smanlvanh P11635
%Recovery
93
19
73
30·
89
118
Control Limits
10 -154
10-48
22-103
10-59
29-112
27 -125
C11-C22 Aromatics BRl µg/l 100
100
100
71
31
75
1 MADEP EPH 01/26/05 4:15 grappaccloll Q02665
C19-C36 Allphatics
C9-C18 Allphatics
BRl
BRL
µg/l
µg/l
MADEP EPH 01/26/05 4:15 grappaccloll Q02665
1 MADEP EPH 01/26/05 4:15 grappaccloll Q02665
449 Springbrook Road • P .0. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone] Page25of40
I
' I
'
' '
NC Certification No. 402 Laboratory Report SC CertiflcaHon No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full Servlco Analylleal 6 EnvlronmantaJ Solutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client.Sample ID: MW-3 Transportation Project No.: WBS# 30173.126 Prism Sample JD: 109244 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 13:50 2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Sample Preparatic~>n: 1000 mL / 2 mL EPH 01/25/05 7:00 smanlvanh P11658
Surrogate %Recovery Control Limits
Metals by: ICP
Lead 0.0018 J
S~mple Preparation:
Vola!l!e P!:!!troleum l:t!ldrocarQons by: GC-P(Dlf(D
C5-C8 Aliphalics BRL
C9-C10 Aromatics BRL
C9-C12 Aliphatics BRL
Sample Comment(s):
All results are reported on a wet-weight basis
BRL = Below Reporting Um/I
mg/L
µg/L
µg/L
µg/L
J = Estimated value between the Reporting Um/I and the MDL
Angela D. Overcash, V.P. Laboratory Services
0.0050 0.0011
50 mL /
100 75
100 35
100 70
o-Te'l'henyl
2-Fluoro~lphenyl
2-Bromonaphthalene
1-Chloro-octadecane
6010B
50 mL SM3030C
1 MADEPVPH
MADEPVPH
1 MADEPVPH
Surrogate
2,5-Dibromotoluene-PID
. 2,5-Dlbromotoluene-FID
89
104
102
40
01/31/05 13:52
01/21/05 14:25
01/27/05 8:46
01/27/05 8:46
01/27/05 8:46
% Recovery
76
81
449 Springbrook Road • P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone]
40-140
40-140
40 -140
40-140
mcampbell Q02688
cnguyen P11637
erussel/ Q02486
erussell Q02486
erussell Q02486
Control Limits
70 -130
70 -130
Page 26 of40
NC Certification No. 402 Laboratory Report · sc Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full Bcrvlcn Analytk:a! & Envfronmontaf SolUU-FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-4 Transportation Project No.: WBS#30173.126 Prism Sample ID: 109245 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman
Time Collected: 01/20/05 14:10 2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
&omatlc and Halogenated Volatlles b~ GClf:JD-ELCD
1, 1, 1,2-Tetrachloroethane BRL µg/L 0.50 0.17 .. 1 6230D 01/26105 17:59 erussell Q02550
1, 1,1-Trtchloroethane BRL µg/L 0.50 0.080 1 6230D 01/26/05 17:59 erusse/1 Q02550
1, 1,2,2-Tetrachloroethane BRL µg/L 0.50 0,11 6230D 01/26105 17:59 erussell Q02550
1, 1,2-Trtchloroethane BRL µg/L 0.50 0.080 1 6230D 01/26105 17:59 erussell Q02550
1; 1-Dichloroethane BRL µg/L 0.50 0.11 6230D 01/26105 17:59 erussell Q02550
1, 1-Dlchloroethene BRL µg/L 0.50 _D.13 6230D 01/26/05 17:59 erussell Q02550
1, 1-Dlchloropropene BRL µg/L 0.50 0.090 1 6230D 01/26105 17:59 erussell Q02550
1,2,3-Trichlorobenzene BRL µg/L 0.50 0.12 6230D 01/26/05 17:59 erussell Q02550
1,2,3-Trtchloropropane BRL µg/L 0.50 0.11 6230D 01/26105 17:59 erussell Q02550
1,2,4-Trichlorobenzene BRL µg/L 0.50 0.040 6230D 01/26/05 17:59 erussell Q02550
1,2,4-Trtmethylbenzene 9.5 µg/L 0.50 0.10 6230D 01/26/05 17:59 erusse!I Q02550
1,2-Dlbromo-3-chloropropana BRL µg/L 0.50 0.14 1 6230D 01/26105 17:59 erussell Q02550
1,2-Dibromoelhane (EDB) · BRL µg/L 0.50 0.12 6230D 01/26/05 17:59 erussell Q02550
f ,2-Dichlorobenzene BRL µg/L 0.50 0.12 6230D 01/26/05 17:59 erussell Q02550
1,2-Dichloroelhane BRL µg/L 0.50 0.070 6230D 01/26105 17:59 erussell Q02550
1.2-Dlchloropropane BRL µg/L 0.50 0.12 6230D 01/26/05 17:59 erussell Q02550
1,3,5-Trimethylbenzene 6.2 µg/L 0.50 0.10 1 6230D 01/26/05 17:59 erussell Q02550
1,3-Dlc;hlorobenzene BRL µg/L 0.50 0.050 1 6230D 01/26/05 17:59 erussell Q02550
1,3-Dlchloropropane BRL µg/L 0.50 0.070 6230D 01/26105 17:59 erussell Q02550
1,4-Dlchlorobenzene BRL µg/L 0.50 0.060 6230D 01/26105 17:59 erussell Q02550
2,2-Dlchloropropane BRL µg/L 0.50 0.13 6230D 01/26105 17:59 erussell Q02550
2-Chlorotoluene BRL µg/L 0.50 0.21 6230D 01/26105 17:59 erussell Q02550
4-Chlorotoluene BRL µg/L 0.50 0.090 6230D 01/26105 17:59 erussell · Q02550
Benzene 5.6 µg/L 0.50 0.060 6230D 01/26/05 17:59 erussell Q02550
Bromobenzene BRL µg/L 0.50 0.13 6230D 01/26105 17:59 erussell Q02550
Bromochloromethane BRL µg/L 0.5Q 0.090 6230D 01/26/05 17:59 erussell Q02550
Bromodichloromethane BRL µg/L 0.50 0.090 6230D 01/26105 17:59 erussell Q02550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 27 of40
NC Certification No. 402 Laboratpry Report SC Certification No. 99012
NC Drinking Water Cert No. 37735 '2/2/05
Full Scrvlc. Ari:alyt!ca! & Envlronmonbl Solutlons FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-4 Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109245 Attn: Roger Smith Sample Matrix: Water COC Group: 00105571 c/o Hart and Hickman Time Collected: 01/20/05 14:10
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05 Charlotte, NC 28203
Parameter Result Units Report MDL DIiution Method Analysis Analyst Batch
Limit Factor Datemme ID
Bromofonn BRL µg/L 0.50 0.050 62300 01/26/05 17:59 !'!russell 002550
Bromomethane BRL µg/L 0.50 0.27 1 62300 01/26/05 17:59 erussell 002550
Carbon Tetrachloride BRL µg/L 0.50 0.060 6230D 01/26/05 17:59 erussell 002550
Chlorobenzene BRL µg/L 0.50 0.17 62300 01/26/05 17:59 erussell 002550
Chloroethane BRL µg/L 0,50 0.41 1 6230D 01/26/05 17:59 erussell 002550
Chloroform BRL µg/L 0.50 0.060 6230D 01/26/05 17:59 erussell 002550
Chloromethane BRL µg/L 0.50 0.14 6230D 01/26/05 17:59 erussell 002550
clss1 ,2-Dlchloroelhene BRL µg/L 0.50 0.13 62300 01/26/05 17:59 erussell 002550
cis-1,3-blchloropropene BRL µg/L 0.50 0.14 6230D 01/26/05 17:59 erusse/1 002550
Dibromochloromethane BRL µg/L 0.50 0.080 62300-01/26/05 17:59 erussell 002550
Dlbromomethane BRL µg/L 0.50 0.13 6230D 01/26/05 17:59 erussell 002550
Dichlorodifluoromethane BRL µg/L 0.50 0.14 6230D 01/26/05 17:59 erussell 002550
Ethylbenzene 5.5 pg/L 0.50 0.16 62300 01/26/05 17:59 erussell 002550
Hexachlorobutadiene BRL pg/L 0.50 0.17 62300 · 01/26/05 17:59 erussell 002550
lsopropyl ether (IPE) 6.3 µg/l . 0.50 0.24 62300 01/26/05 17:59 erussell 002550
lsopropylbenzene 1.4 µg/L 0.50 0.10 6230D 01/26/05 17:59 erussell 002550
m,p-Xylenes 19 µg/L 1.0 0.43 6230D 01/26/05 17:59 erussell 002550
Methyl t-butyl elher (MTBE) 34 µg/L 0.50 0.14 1 6230D 01/26/05 17:59 erussell 002550
Methylene chloride BRL µg/L 2.0 0.75 62300 01/26/05 17:59 erussell 002550
n-Butylbenzene 7,6 µg/L 0.50 0.19 1 62300 01/26/05 17:59 erussel/ 002550
n-Propylbenzene 5.4 µg/L 0.50 0.10 62300 01/26/05 17:59 erussell 002550
Naphthalene 8.9 µg/L 0.50 0.10 6230D 01/26/05 17:59 erussell 002550
a-Xylene 9.8 µg/L ,0.50 0.16 1 62300 01/26/05 17:59 erussell 002550
p-lsopropyltoluene BRL µg/L 0.50 0.17 1 62300 01/26/05 17:59 erussell 002550
sec-Butylbenzene 0.96 µg/L 0.50 0.12 6230D 01/26/05 17:59 erusse11 002550
Styrene BRL µg/L 0.50 0,050 6230D 01/26/05 17:59 erussell 002550
tert~Butylbenzene BRL µg/L 0.50 0.13 1 6230D 01/26/05 17:59 erussell 002550
Tetrachloroethene BRL µg/L 0.50 0.11 62300 01/26/05 17:59 erussell 002550
449 Springbrook Road • P.O. Box 24Q543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-BQ0/529-6364 -Fax: [phone] Page28 of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Fllll Sarvlce Aruil)'ti'cal A Em1roo111antal SolutlOIIS FL Certlflcatlon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-4
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109245 Attn: Roger Smith Sample Matrix: Wat~r coc Group: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 14:10 2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch.
Limit Factor Datemme ID
Toluene 3.0 µg/L 0.50 0.11 6230D 01/26/05 17:59 erussell Q02550
trans:1 ,2-Dlchloroethene BRL µg/L 0.50 0.27 62300 01/26/05 17:59 erussell Q02550
trans-1,3-Dlchloropropene BRL µg/L 0.50 0.070 1 6230D 01/26/05 17:59 erussell Q02550
Trichloroethane BRL µg/L 0.50 0.10 6230D 01/26/05 17:59 erusse/1 Q02550
Trfchlorofluoromethane BRL µg/L 0.50 0.19 62300 01/26/05 17:59 erussell Q02550
Vinyl chloride BRL µg/L 0.50 0.24 1 62300 01/26/05 17:59 erussell Q02550
Surrogate ¾Recovery Control Limits
Bromochlorobenzene-ELCD 121 60-144
1,4-Dlfluorabenzene-PID 106 50 -141
Semlvolatlle Organic Comgouads b3£ GClMS
1,2.4-Trichlorobenzene BRL µg/L 19 ·4.9 2 625 01/24/05 12:02 keU/ot Q02493
1,2-Dichlorobenzene BRL µg/L 19 5.2 2 625 01/24/05 12:02 kelllot Q02493
1,3-Dichlarobenzene BRL µg/L 19 3.7 2 625 01/24/05 12:02 kelllot Q02493
1,4-Dichlorobenzene BRL µg/L 19 4.7 2 625 01/24/05 12:02 kelllot Q02493
2,4,5-Trichlorophenol BRL µg/L 19 5.0 2 625 01/24/05 12:02 kelllot Q02493
2,4,6-Trichlorophenol BRL µg/L 19 3.5 2 625 01/24/05 12:02 kelllot Q02493
2,4-Dlchlorophenol BRL µg/L 19 3.7 2 625 01/24/05 12:02 kelllot Q02493
2,4-Dlmethyfphenol BRL µg/L 19 1.3 2 625 01/24/05 12:02 kelllot Q02493
2.4-Dlnitrophenol BRL µg/L 97 1.3 2 625 01/24/05 12:02 kell!ot Q02493
2,4-Dinitrotoluene BRL µg/L 19 1.6 2 625 01/24/05 12:02 kell!ot Q02493
2,6-Dlnitrotoluene BRL µg/L 19 3.1 2 625 01/24/05 12:02 kelllot Q02493
2-Chloronaphthalene BRL µg/L 19 4.3 2 625 01/24/05 12:02 kelllot Q02493
2-Chlorophenol BRL µg/L 19 4.3 2 625 01/24/05 12:02 keinot Q02493
2-Methyfnaphthalene BRL µg/L 19 3.5 2 625 01/24/05 12:02 kelllot Q02493
2-Methyfphenol BRL µg/L 19 5.4 2 625 01/24/05 12:02 kelllot Q02493
2-Nitrophenol BRL µg/L 19 4.5 2 625 01/24/05 12:02 kellfot Q02493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 29 of 40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drtnklng Water Cert No. 37735 2/2/05
Full setv1co Anatytleat & Envlrorun&ntzl Solutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-4 Transportation Project No.: WBS#30173.126 Prism Sample ID: 109245 Attn: Roger Smith Sample Matrix: Water COCGroup: G0105571 c/o Hart and Hickman Time Collected: 01/20/05 14:10
2923 South Tryon St. Ste 100 Time Submitted: 01/21/05 8:05 Chartotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batcti
Limit Facior Datemme ID
3&4-Methylphenol BRL pg/L 19 7.2 2 625 01/24/05 12:02 kelllot Q02493
3,3"-Dlchlorobenzidlne BRL pg/L 97 18 2 625 01/24/05 12:02 kellfot Q02493
4,6-Dinltro-2-methylphenol BRL pg/L 100 · 1.8 2 625 01/24/05 12:02 kelllot Q02493
4-Bromophenylphenylether BRL pg/L 19 3.9 2 625 01/24/05 12:02 kelllot Q02493
4-Chloro-3-methylphenol BRL pg/L 19 3.3 2. 625 01/24/05 12:02 kelllot Q02493
4-Chiorophenylphenylether BRL pg/L 19 3.1 2 625 01/24/05 12:02 kellfot Q02493
4-Nitrophenol BRL pg/L 97 1.2 2 625 01/24/05 12:02 kemot Q02493
Acenaphthene BRL µg/L 19 3.7 2 625 01/24/05 12:02 kelllot Q02493
Acenaphthylene BRL pg/L 19 4.1 2 625 01/24/05 12:02 .,kelllot Q02493
Anthracene BRL µg/L 19 1.9 2 625 01/24/05 12:02 kelllot Q02493
Benzo(a)anthracene BRL µg/L 19 1.8 2 625 01/24/05 12:02 keJliot Q02493
Benzo(a)pyrene BRL µg/L 19 1.9 2 625 01/24/05 12:02 kelllot Q02493
Benzo(b)fluoranthene BRL pg/L 19 3.3 2 625 . 01/24/05 12:02 kelllot Q02493
Benzo(g,h,l)perylene BRL µg/L 19 4.1 2. 625 01/24/05 12:02 kel/iot Q02493
Benzo{k)fluoranthene BRL µg/L 19 3.7 2 625 01/24/05 12:02 kelllot ·002493
Bis{2-chloroethoxy)methane BRL µg/L 21 4.4 2 625 01/24/05 12:02 keUlot Q02493
Bis(2-d1loroelhyl)ether BRL µg/L 19 4.1 2 625 01/24/05 12:02 kelllot Q02493
. Bls(2-d1lorolsopropyi)ether BRL µg/L 21 4.9 2 625 01/24/05 12:02 kelllot Q02493
Bls(2;ethyihexyl)phthalate 120 µg/L 19 1.4 2 625 01/24/05 12:02 kelllot Q02493
Butylbenzylphthalate 15J pg/L .19 1.4 2 625 01/24/05 12:02 kelliot Q02493
Chrysene BRL µg/L 19 1.1 2 625 01/24/05 12:02 kelliot Q02493
Dl-n-butylphthalate BRL µg/L 19 2.7 2 625 01/24/05 12:02 kelllot Q02493
D1-n-octylphthalate BRL pg/L 19 4.3 2 625 01/24/05 12:02 kelllot Q02493
Dlbenzo(a,h)anthracene BRL pg/L 19 2.1 2 625 01/24/05 12:02 kelllot Q02493
Dlbenzofuran BRL µg/L 19 4.3 2 625 01/24/05 12:02 kelliot Q02493
Dlethylphthalale BRL pg/L 19 2.1 2 625 01/24/05 12:02 kell!ot Q02493
Dlmethylphthalate BRL pg/L 19 2.7 2 625 01/24/05 12:02 kelliot Q02493
Fluoranthene BRL µg/L 19 1.8 2 625 .01/24/05 12:02 kelliot Q02493
449 Sprtngbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 30 of40
; I
· NC Certification No. 402 Laboratory Report· SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/0.5
Full Berm• Anllyllcat & Envlnmrn1ntzl .Solutlom FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-4
Transportation Project No.: WBS#30173.126 Prism Sample ID: 109245 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571 c/o Hart and Hickman llme Collected: 01/20/05 14:10
2923 South Tryon St Ste 100 llme Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Fluorehe BRL µg/L 19 2.7 2 625 01/24/05 12:02 kelllot Q02493
Hexachlorobenzene BRL µg/L 19 2.5 2 625 01/24/05 12:02 keUiot Q02493
Hexachlorobutadiene BRL µg/L 19 4.3 2 625 01/24/05 12:02 kelllot Q02493
Hexachlorocyclopentadlene BRL µg/L 19 4.7 2 625 01/24/05 12:02 kelllot Q02493
Hexachloroethane BRL µg/L 19 3.5 2 625 01/24/05 12:02 kelllot Q02493
lndeno(1,2,3-cd)pyrene BRL µg/L 19 3.3 2 625 01/24/05 12:02 kellfot Q0249~
lsophorone BRL. µg/L 19 3.1 2 625 01/24/05 12:02 keUiot Q02493
N-Nitrosodi--n-propylamlne BRL µg/L 19 4.3 2 625 01/24/05 12:02 kelliot Q02493
Naphthalene 17 J µg/L 19 4.3 2 625 01/24/05 12:02 kell!ot '-· Q02493
Nltrobenzene BRL µg/L 19 3.7 2 625 01/24/05 12:02 kelliot Q02493
Pentachlorophenol BRL µg/L 19 3.3 2 625 01/24/05 12:02 kelllot Q02493
Phenanthrene 4.9J µg/L 19 1.7 2. 625 01/24/05 12:02 kelllot Q02493
Phenol BRL µg/L 19 1.7 2 625 01/24/05 12:02 kelllot Q02493
A-yrene BRL µg/L 19 1.8 2 625 01/24/05 12:02 ~kelllot Q02493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 31 of 40
' I
Full Ser.ice Antlyllc.tl & Envlronrnomzl Sotutlom
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert. No. 37735
FL Certification No. E87519
North Carolina Department of
Transportatlon Project ID: DOT-215
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Project No.: WBS#30173.126
Sample Matrix: Water
Parameter Result Units Report MDL Dilution Method
TICS for 109245 Method 625.
TIC: Benzene, trirnethyl
TIC: Decane
TIC: Benzene, ethyl-4-methyl
TIC: Benzene, methyl-propyl
TIC: Undeca_ne
TIC: Dodecane
TIC: Tetradecan~
TIC: Nonadecane
TIC: Eicosane
TIC: Naphthalene, 2-methyl
Sample Preparation:
Limit Factor
120 ug/L Est.
64 ug/L Est.
67 ug/L Est.
82 ug/L Est.
73 ug/L Est.
110 ug/L Est.
80. ug/L Est.
68 ug/L Est.
64 ug/L Est.
25 ug/L Est.
1030 mL / 1 mL 625
surrogate
Terphenyl-d14
Phenol-d5
Nltrobenzene-d5
2-Fluorophenol
2-Fluoroblphenyl
2,4,6-Tribromophenol
Extractable Petroleum Hydrocarbons by GC-FID
Laboratory Report
· 2/2/05
Client Sample ID: MW-4
Prism Sample ID: 109245
coc Group: G0105571
Time Collected: ·01/20/05 14:10
Time Submitted: 01/21/05 8:05
Analysis
Datemme
Analyst Batch
ID
01/21/05 8:00 smanlvanh P11635
¾Recovery Contrcil Limits
131 10 -154
13 10-48
74 22 -103
19 10-59
83 29-112
64 27 -125
C11-C22 Aromatics 2600 µg/L 100 71 1 MADEPEPH 01/26/05 7:43 grappaccloli Q02665
C19-C36 Aliphatics 9700 µg/L 100 31 MADEPEPH 01/26/05 7:43 grappaccloll Q02665
C9-C18 AllphaUcs 550 µg/L 100 75 MADEP EPH 01/26/05 7:43 grappaccioli Q02665
Sample Preparation: 1000 mL I 2 mL EPH 01/25/05 7:00 smanlvanh P11658
Surrogate % Recovery Control Limits
o-Terphenyl 121 · 40 -140
2-Fluoroblphenyl 91 40-140
2-Bromonaphthalene 112 40-140
1-Chloro-octadecane 42 40 -140
Metals by Ic·p
Lead 0.0024 J mg/L 0.0050 0.0011 6010B 01/31/05 14:00 mcampbell Q02688
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone] Page 32 of40
NC Certification No. 402 ·
SC Certification No. 99012
NC Drinking WaterCert No. 37735
FL Certification No. E87519
Laboratory Report
2/2/05
Full Serrlce Analy!fcal & Environmental Solu!IO!!S
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon Sl Ste 100
Charlotte, NC 28203
Parameter
Sample Preparation:
Result
Volatile eetroleum l::lidtoca[hons ~i GC-elDlEID
C5-C8 Allphatlcs BRL
· C9-C10 Aromatics 180
cs,c12 Aliphatics BRL
Sample Comment(s):
All results ~f6 reported on a wet-weight bas/~
BRL = Below Reporting Umlt
Project ID: DOT-215 Client Sample ID:
Project No.: WBS# 30173.126 Prism Sample ID:
Sample Matr1x: Water
Units Report MDL
Limit
50 mL I
µg/L 100 75
µg/L 100 35
µg/L 100 70
COC Group:
Time Collected:
Time Submitted:
DIiution Method Analysis
Factor Datemme
50 mL SM3030C 01121105 14:25
MADEPVPH 01/27105 18:14
. 1 MADEPVPH 01/27105 18:14
MADEPVPH 01/27105 18:14
Surrogate %Recovery
215-Pibromotoluene-PID
2,5-Dibromotoluene-FID
73
86
J = EsUmated value between the Reporting Umit and the MDL
Angela D. Overcash, V.P. Laboratory Services
449 Springbrook Road -P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-8001529-6364 -Fax: [phone]
MW-4
109245
Go105571
01/20/05 14:10
01/21/05 8:05
Analyst Batch
ID
cnguyen P11637
erussell Q02486
erusse!I Q02486
erussell Q02486
. Control Limits
70 -130
70 -130
Page 33 of40
NC CertificaHon No. 402 Laboratory Report SC CertificaHon No. 99012
NC Drinking Water Cert. No. 37735
Fun Servlc, Anatytlcal & Envltonmontal Solutlomi FL CertificaHon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID:
Transportation Project No.: WBS# 30173.126 Prism Sample ID:
Attn: Roger Smith Sample Matrix: Water COCGroup:
c/o Hart and Hickman Time Collected:
2923 South Tryon SL Ste 100 Time Submitted:
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis
Limit Factor Datemme
,AromaUc aad Halogenated Volatlles bl£ GClelD-ELCD
1, 1, 1,2-Teirachloroethane
1, 1, 1-TrlchloroeU,ane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trlchloroethane
1, 1-DlchloroeU,ane
1, 1-DlchloroeHiene
1, 1-Dlchloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trlchlorobenzene
1,2,4-TrlmeHiylbenzene
1,2-Dibromo-3-chloropropane
1,2-DibrompeU,ane (EDB)
1,2-Dichlorobenzene
1,2-Dlchloroethane
1,2-Dlchloropropane
1,3,5-Trlmethylbenzene
1,3-Dlchlorobenzene
1,3-Dlchloropropane
1,4-Dlchlorobenzene
2:2-0lchloropropane
2-Chlorotoluene
4-Chlorololuene
Benzene
Bromobenzene
Bromochloromethane
Bromodlchloromethane
BRL µg/1:. 0.50 0.17 62300 01/26105 6:50
BRL. µg/L 0.50 0.080 62300 01/26105 6:50
BRL µg/L 0.50 0.11 62300 01/26105 6:50
BRL µg/L 0.50 0.080 1 62300 01/26105 6:50
BRL µg/L 0.50 0.11 1 62300 01/26105 6:50
BRL µg/L 0.50 0.13 62300· 01/26/05 6:50
BRL µg/L 0.50 0.090 1 62300 01/26/05 6:50
BRL µg/L 0.50 0.12 1 62300 01/26/05 6:50
BRL µg/L 0.50 0.11 62300 01/26105 6:50
BRL µg/L 0.50 0.040 62300 01/26/05 6:50
BRL µg/L 0.50 0.10 1 62300 01/26/05 6:50
BRL' µQfL 0.50 0.14 1 62300 01/26/05 6:50
BRL µg/L 0.50 0.12 62300 01/26105 6:50
BRL µg/L 0.50 0.12 62300 01/26105 6:50
BRL µg/L 0.50 0.070 1 62300 01/26/05 6:50.
BRL µg/L 0.50 0.12 1 62300 01/26105 6:50
BRL µg/L 0.50 0.10 62300 01/26105 6:50
BRL µg/L 0.50 0.050 62300 01/26105 6:50
BRL µg/L 0.50 0.070 62300 01/26/05 6:50
BRL µg/L 0.50 0.060 1 62300 01/26/05 6:50
BRL µg/L 0.50 0.13 1 62300 01/26105 6:50
BRL µg/L 0.50 0.21 62300 01/26105 6:50
BRL µg/L 0.50 0.090 62300 01/26105 6:50
BRL µg/L 0.50 0.060 62300 01/26/05 6:50
BRL µg/L 0.50 0.13 62300 01/26/05 6:50
BRL µg/L 0.50 0.090 62300 01/26105 6:50
BRL µg/L 0.50 0.090 62300 01/26/05 6:50
449 Springbrook Road -P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
2/2/05
MW-5
109246
G0105571
01/20/05 15:15
01/21/05 8:05
Analyst Batch
ID
erusse!I Q02550
erussell Q02550
erussell Q02550
erussell Q02550
eruss1;1II Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussf!II Q02550
erussell Q02550
erussell Q02550
erussel/ Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erusseU Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussell Q02550
erussel/ Q02550
erusseU Q02550
Page 34 of40
NC Certification No. 402 Laboratory Report SC Certiflcatlon No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Furl Service Analytical & Envlronmontal Solutions FL Certiflcatlon No. E87519
North Carolina Department of Project ID: DOT-215 · Client Sample ID: MW-5
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109246
Attn: Roger Smith Sample Matrix: Water COCGroup: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 15:15
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL. Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Bromoform BRL µg/L 0.50 0.050 1 6230D 01/26105 6:50 erussell 002550
Bromomethane BRL µg/L 0.50 0.27 6230D 01/26105 6:50 erusse/1 002550
Carbon Tetrachloride BRL µg/L 0.50 0.060 6230D 01/26/05 6:50 erussell 002550
Chlorobenzene BRL µg/L 0.50 0.17 1 6230D 01/26/05 6:50 erussell 002550
Chloroethane BRL µg/L 0.50 0.41 6230D 01/26105 6:50 erussell -002550
Chloroform BRL µg/L a.so 0.060 6230D 01/26105 6:50 erusse/1 002550
Chloromethane BRL µg/L 0.50 0.14 1 6230D 01/26/05 6:50 eiusst;,:11 002550
els-1,2-Dichloroethene BRL µg/L 0.50 0.13 1 6230D .. 01/26105 6:50 erussell 002550
cls-1,3-Dlchloropropene BRL µg/L 0.50 0.14 6230D 01/26/05 6:50 erussell 002550
Dlbromochloromethane BRL µg/L a.so 0.080 6230D 01/26/05 6:50 erussell 002550
Dlbromomethane BRL µg/L 0.50 0.13 6230D 01/26/05 6:50 erussell 002550
Dlchlorodifluoromethane BRL µg/L 0.50 0.14 · 1 6230D 01/26105 6:50 erussell 002550
Ethylbenzene BRL µg/L 0.50 0.16 6230D 01/26/05 6:50 erussell 002550
Hexachlorobutadlene· .. BRL µg/L 0.50 0.17 6230D 01/26/05 6:50 erussel/ 002550
lsopropyl ether {IPE) BRL µg/L 0.50 0.24 6230D 01/26/05 6:50 erussell 002550
lsopropylbenzen~ BRL µg/L a.so 0.10 6230D 01/26/05 6:50 erussell 002550
m,p-Xylenes BRL µg/L 1.0 0.43 6230D 01/26/05 6:50 erussell 002550
Methyl t-blJlyl ether (MTBE) BRL µg/L 0.50 0.14 6230D 01/26105 6:50 erussell 002550
Methylene chloride BRL µg/L 2.0 0.75 6230D 01/26105 6:50 erussell 002550
n-Butylbenzene BRL µg/L. 0.50 0.19 6230D 01/26/05 6:50 erussell 002550
n-Propylbenzene BRL µg/L 0.50 0.10 6230D 01/26/05 6:50 erussell ·002550
Naphthalene BRL µg/L a.so 0.10 1. 6230D 01/26/05 6:50 erussell 002550
a-Xylene BRL µg/L a.so 0.16 6230D 01/26105 6:50 erussell 002550
p-lsopropyltoluene BRL µg/L a.so 0.17 1 6230D 01/26/05 6:50 erussell 002550
seo-Butylbenzene BRL µg/L a.so 0.12 6230D 01/26/05 6:50 erussell 002550
Styrene BRL µg/L a.so 0.050 6230D 01/26/05 6:50 erussell 002550
' --tert-Butylbenzene BRL µg/L 0.50 0.13 6230D 01/26/05 6:50 erussell 002550
Tetrachloroethene BRL µg/L 0.50 0.11 1 6230D 01/26/05 ,6:50 erussel/ 002550
' ' 449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 35 of40
'
NC Certification No.-402 Laboratory Report SC Certlflcatlon No. 99012
NC Drinking Wat.er Cert. No. 3TT35 2/2/05
Full Sorvlea Analydczl & Envtronm1rrtal Solutlall!I FL Certiflcatlon No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-5
TransportaUon Project No.: WBS# 30173.126 Prism Sample ID: 109246
Attn: Roger Smith Sample Matrix: Water COC Grou~: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 15:15
2923 South Tryon St Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Toluene BRL µg/L 0.50 0.11 1 6230D 01/26/05 6:50 erussell 002550
trans-1,2-Dlchloroelhene BRL µg/L 0.50 0.27 6230D 01/26/05 6:50 81'4SS8II 002550
trans-1,3-Dlchloropropene BRL µg/L 0.50 0.070 6230D 01/26/05 6:50 erussell 002550
Trichloroethene BRL µg/L 0.50 0.10 6230D 01/26/05 6:50 erussell 002550
Trfchlorofluoromethane BRL µg/L 0.50 0.19 1 6230D 01/26/05 6:50 erussell 002550
Vinyl chloride BRL µg/L 0.50 0.24 1 6230D 01/26/05 6:50 erussell 002550
Surrogate % Recovery Control Limits
Bromochlorobenzene-ELCD 91 60 -144
1,4-Dlfluorobenzene-PID 106 50 -141
Semivolatlle Organic ComRounds bl£ GC[MS
1,2,4-Trichlorobenzene
1,2-Dlchlorobenzene ' 1,3-Dlchlorobenzene
1,4-Dichlorobenzene
2,4,5-Trichlorophenol
2.4,6-Trichlorophenol
2,4-Dlchlorophenol
2,4-Dlmethylphenol
2,4-Dlnitrophenol
2,4-Dlnltrotoluene
2,6-Dlnltrotoluene
2-Chloronaphlhalene
2-Chlorophenol
2-Methylnaphlhalene
2-Melhylphenol
2-Nitrophenol
BRL. µg/L 9.7 2-4 625 01/22/05 12:24
BRL µg/L 9.7 2.6 625 01/22/05 12:24
BRL µg/L 9.7 1.8 1 625 01/22/05 12:24
BRL µg/L 9,7 .2.3 625 01/22/05 12:24
BRL µg/L 9.7 2.5 625 01/22/05 12:24
BRL µg/L 9,7 1.7 625 01/22/05 12:24
BRL µg/L 9.7 1.8 625 01/22/05 12:24
-BRL µg/L 9.7 0.65 1 625 01/22/05 12:24
BRL µg/L 49 0.65 625 01/22/05 12:24
BRL µg/L 9.7 0.82 625 01/22/05 12:24
BRL µg/L 9.7 1.6 625 01/22/05 12:24
BRL µg/L 9.7 2.1 625 01/22/05 12:24
BRL µg/L 9.7 2.1 625 01/22/05 12:24
BRL µg/L 9.7 1.7 1 625 01/22/05 12:24
BRL µg/L 9.7 2.7 1 625 01/22/05 12:24
BRL µg/L 9.7 2.2 1 625 01/22/05 12:24
449 Springbrook Road -P.O. Box 240543_ -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
.kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
kelllot 002493
Page 36of40
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drtnklng Water Cert No. 37735 2/2/05
Fun Service AnaJytlcal & Environmental Salulfona FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-5
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109246
Attn: Roger Smith Sample Matrix: Water COC Group: G0105571
c/o Hart and Hickman Time Collected: 01/20/05 15:15 . ' 2923 South Tryon St. Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
' ' Limit Factor Datemme ID
3&4-Methy!phenol BRL µg/L 9.7. 3.6 625 01/22/05 12:24 kelllot 002493
3,3 '-Dlchlorobenzldlne BRL µg/L 49 9.1 625 01/22/05 12:24 kelllot 002493
4,6-Dlnltro-2-methy!phenol BRL Jig/L 49 0.85 1 625 01/22/05 12:24 kelllot 002493
4-Brdmopheny!phenylether BRL µg/L 9.7 1;9 1 625 01/22/05 12:24 kelllot 002493
4-Chloro-3-methy!phenol BRL µg/L 9.7 1.7 625 01/22/05 12:24 . kelllot 002493.
4-Chloropheny!pheny!ether BRL µg/L 9.7 1.6 1 625 01/22/05 12:24 kelllot 002493
4-Nitrophenol BRL µg/L 49 0.58 1 625 01/22/05 12:24 kell!ot 002493
Acenaphthene BRL µg/L 9.7 1.8 625 01/22/05 12:24 ke!llot 002493
( Acenaphthylene BRL µg/L 9.7 2.0 625 01/22/05 12:24 kelllot 002493 '
Anthracene BRL µg/L 9.7 0.95 625 01/22/05 12:24 kelliot 002493
" ' Benzo(a)anthracene BRL µg/L 9.7 0.91 1 625 01/22/05 12:24 kelllot 002493
Benzo(a)pyrene BRL µg/L 9.7 0.97 625 01/22/05 12:24 ke!lfot 002493
Benzo(b)fluoranthene BRL µg/L 9.7 1.7 625 01/22/05 12:24 kel!lot 002493
Benzo(g.h.l)perylene BRL µg/L 9.7 2.0 625 01/22/05 12:24 kelllot 002493
Benzo(k)fluoranthene BRL µg/L 9.7 1.8 625 01/22/05 12:24 kelllot 002493
Bis(2~1oroethoxy)methane BRL µg/L 10 2.2 625 01/22/05 12:24 kellfot po2493
Bls{2-chloroethy!)ether BRL µg/L 9.7 2.0 625 01/22/05 12:24 kelllot 002493
Bls(2-chlorolsopropyl)ether BRL µg/L 10 2.4 625 01/22/05 12:24 kell!ot 002493
' ' Bls{2-ethylhexy!)phthalate BRL µg/L 9.7 0.69 625 01/22/05 12:24 kelHot 002493
Butylbenzy!phthalate BRL µg/L 9.7 0.68 625 01/22/05 12:24 ke!liot 002493
Chrysene BRL µg/L 9.7 0.55 625 01/22/05 12:24 kefllot 002493
D1-n-butylphlhalate BRL µg/L 9.7 1.4 625 01/22/05 12:24 kell!ot 002493
l _: D1-n-octylphthalate BRL µg/L 9.7 2.1 1 625 01/22/05 12:24 kellfot 002493
Dibenio(a,h)anthracene BRL µg/L 9.7 1.1 625 01/22/05 12:24 kelllot 002493
Dibenzofuran BRL µg/L 9,7 2.1 625 01/22/05 12:24 kelllot 002493
Diethy!phthalate BRL µg/L 9,7 1.1 625 01/22/05 12:24 kelllot 002493
I Dimethy!phthalate BRL µg/L 9.7 1.4 625 01/22/05 12:24 kelllot 002493
Fluoranthene BRL µg/L 9.7 0.91 1 625 01/22/05 12:24 kelHot 002493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 37 of40
' I
-I
Full Snrvlc, Aiu:lytlt.i a Envlronm1111at Solu1lons
North Carolina Deparbnent of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter
Fluorene
HeXBchlorobenzene.
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexacftloroethane
I ndeno( 1,2,3-cd)pyrene
lsophorone
N-Nltrosodl-n-propylamlne
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
NC Certificatlon No. 402
SC Certificatlqn No. 99012
NC Drinking Water Cert. No. 37735
FL Certificatlon No. E87519
Project ID: DOT-215
Project No.: · WBS# 30173.126
Sample Matrix: Water
Result
BRL
BRL
BRL
Units
µg/L
µg/L
µg/L
BRL µg/L
BRL µg/L
BRL µg/L
BRL µg/L
BRL µg/L
BRL _,_, µg/L
BRL
BRL
BRL
BRL
-.' BRL
µg/L
µg/L
µg/L
µg/L
µg/L
Report
Limit
9,7
9,7
9.7
9.7
9.7
9.7
9.7
9.7
9.7
MDL
1.4
1.3
2.1
2.3
1.7
1.7
1.6
2.1
2.1
9.7 1.8
9.7 1.7
9.7 0.87
9,7 0.87
9.7 0.88
Dilution
Factor
1
1
. 1
1
1
1
1
1
1
Method
625
625
625
625
625.
625
625
625
625
625
625
625
625
625
Laboratory Report
2/2/05
Client Sampl~ ID: MW-5
Prism Sample ID:
COG Group:
Time Collected:
109246
G0105571"
01/20/05
Time Submitted: 01/21/05
Analysis
Datemme
Analyst
01122/05 12:24 kelllot
01/22/05 12:24 kelllot
01/22/05 12:24 kelliot
01122/05 12:24 kelllot
01/22/05 12:24 kelllot
01122/05 12:24 kelllot
01/22/05 12:24 kelllot
01/22/05 12:24 kelllol
01/22/05 12:24 kelllot
01/22/05 12:24 kelllot
01/22/05 12:24 kelllot
01122/05 12:24 kelllot
01/22/05 12:24 kelllot
01/22/05 12:24 kelllot
15:15
8:05
Batch
ID
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
No TIC 1s were detected.
Sample Preparation:
Extractable petroleum Hydrocarbons by GC-FID
C11-C22 Aromatics BRL µg/L
C19-C36 Allphatlcs
C9-C18 Aliphatlcs
BRL
BRL
µg/L
µg/L
1030 ml / 1 mL 625 01/21/05 8:00 smanlvanh P11635
100
100
100
71
31
75
Surrogate
Terphenyl-<114
Phenol-d5
Nllrobenzene-d5
2-Fluorophenol
2-Fluoroblphenyl
2,4,6-Tribromophenol
% Recovery
110
20
73
35
89
113
Control Limits
10-154
10-48
22-103
10-59
29-112
27 -125
1 MADEP EPH 01/26/05 5:59 grappaccloll 002665
MADEP EPH 01/26/05 5:59 grappacc!oll 002665
MADEP EPH 01/26105 5:59 grappaccloll 002665
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone] Page 38of40
I
! I
I '
_I
NC Certification No. 402 Laboratory Report SC Certification No. 99012
NC Drlnklng Water Cert No. 37735 2/2/05
Full Sorvlc. Analytical & Envfronrnont:al Solutions FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 Client Sample ID: MW-5
Transportation Project No.: WBS# 30173.126 Prism Sample ID: 109246 Attn: Roger Smith Sample Matrix: Water COC Group: G0105571
c/o Hart ancj Hickman Time Collected: 01/20/05 15:15
2923 South Tryon St. Ste 100 Time Submitted: 01/21/05 8:05
Charlotte, NC 28203
Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Datemme ID
Sample PreparaUon: 1000 mL / 2 mL EPH 01/25/05 7:00 smanlvanh P11658
Surrogate % Recovery Control Limits
Metals b~ ICP
Lead BRL
Sample Preparation:
Volatile Petroleum l::ht:drocarbons bi GC-PID1EID
CS-CB Allphatics BRL
C9-C1.0 Aromatics BRL
C9-C12 Aliphatics BRL
Sample Comment(s):
All results are reported on a wet-weight basis
BRL = Below Reporting Umit
mg/L
µg/L
µg/L
µglL
J = Estimated value between the Reporting Umit and the MDL
Angela D. Overcash, V.P. Laboratory Services
0.0050 0.0011
50 mL /
100 75
100 35
100 70
o-Terphenyt 75
2-Ftuoroblphenyt 104
2-Bromonaphthalene 89
1-Chloro-octadecane 40
1 60108 01/31/05 14:07
50 mL SM3030C 01/21/05 14:25
1 MADEPVPH 01/27/05 10:31
1 . MADEPVPH 01/27/05 10:31
MADEPVPH 01/27/05 10:31
Surrogate . % Recovery
2,5-Dibromotoluene-PID 73
2,5-Dlbromotoluene-FID . 77
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529·6364 -Fax: [phone]
40-140
40-140
40 -140
40 -140
mcampbell Q02888.
cnguyen P11637
erussell· Q02488
erussell Q02486
erussell Q02486
Control Limits
70-130
70 -130
Page 39of40
,-­
' '
I I I
I
i ' ' '
Full Scrvlco Analytleal & Envlronmonbt Solutions
North Carolina Department of
Transportation
NC Certification No. 402
SC Certification No. 99012
NC Drinking WaW Cert No. 37735
FL Certification No. E87519
Project ID:
Project No.:
DOT-215
WBS# 30173.126
Laboratory Report
2/2/05
Client Sample ID: TRIP BLANK
Prism Sample ID: 109247
Attn: Roger Smith
c/o Hart and Hickman
Sample Matrix: Water COC Group: G0105571
2923 South Tryon St Ste 100
Charlotte, NC 28203
Parameter Result
Volatlle Petroleum l::lidroca[boos bi !JC-PIDlFID
CS.CB Aliphatics BRL
C9-C10 Aromatics BRL'
. C9-C12 Aliphatics BRL
Sample Comment(s):
All results are reported oh ~ wet-weight basis
BRL ~ Below Reporting Um/I
Units
µg/L
µg/L
µg/L
J = Estimated value between the Reporting Umit and the MDL
Angela D. Overcash, V.P. Laboratory Services
Report MDL
Limit
100 75
100 _35
100 70
Time Collected: 01/20/05
Time Submitted: 01/21/05 8:05
Dilution Method
Factor
MADEPVPH
1 MADEPVPH
1 MADEPVPH
Surrogate
2,5-Dibromotoluene-PID
2,5-Dibromotoluene-FID
Analysis
Datemme
01/27/05 11 :24
01/27/05 11 :24
01/27/05 11:24
%Recovery
75
82
Analyst Batch
ID
erussell Q02486
erussell 002486.
erussell Q02486
Control Limits
70 -130
70-130
449 Springbrook Road -P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-8001529-6364 -Fax: [phone] Page 40 of40
NC CertlficaUon No. 402
SC CertlficaUon No. 09012
NC Drinking Water Cert. No. 37735
FuHSaM~Analytlcal&EnvlronmardalSolutlon1 FL Certification No. E87519
North Carolina Department of
Transportation
Attn: Roger Smith
rlo Hart and Hickman
2923 South Tryon St Ste 100
Project ID:
Project No.:
DOT-215
WBS# 30173.126
Aromatic and Halogenated Volatiles by GC/PID-ELCD, method 6230D
Method Blank
1, 1; 1,2-Tetrachloroelhane
1, 1, 1-Trlchloroelhane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trlchloroethane
1, 1-Dlc:hloroethane
1, 1-Dlchloroelhene
1, 1-Dlchloropropene
1,2,3-Trfchlorobenzene
1,2,3-Trfchloropropane
1,2,4-Trfchlorobenzene
1,2,4-Trimethylbenzene
1,2-Dlbromo-3-chloropropane
1,2-Dlbromoelhane (EDB)
1,2-Dlchlorobenzene
1,2-Dlchloroethane
1,2-Dichloropropane
1,3,5--Trfmethylbenzene
1,3-Dlchlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromachloromethane
Bromodlchlorometha□e
Bromoforrn
s·romomethane
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cls-1,2-Dlchloroethene
cls-1,3-Dlchloropropene
Dlbromochloromethane
Dlbromomethane
Dlchforodifluoromethane
Elhylbenzene
Hexachlorobutadlene
lsopropyl ether (IPE)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
RL
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
o:5
0.5
0.5
0.5
0.5
0.5
·0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Control
Limit Units
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 pg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 pg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 · µg/L
<0.25 µg/L
<0.25 pg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µ!Jlls
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<p.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 . µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
<0.25 µg/L
Level II QC Report
2/2/05
coc Group Number: G0105571
Date/Time Submitted: 1/21/05· 8:05
QC Batch
ID
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
· Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
Q02550
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-800/529-6364 • Fax: [phone] Page 1 of 14
NC CertiflC'!tiOn Na. 402 Level II QC Report SC Certification No. 99012 •
NC Drinking Water Cert. No. 37735 . 2/2/05
Full Service k\alytlul & Environmental SolutlolUI FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571
Transportation Project No.: WBS# 30173.126 Attn: Roger Smith Datemme Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon St Ste 100
Method Blank Con'"" QCBatdi Result RL Umlt Units ID
lsopropylbenzene ·No . 0.5 <0.25 µg/1. Q02550
m,p-Xylenes ND <0,5 µg/1. Q02550
Methyl !-butyl ether (MTBE) ND 0,5 <0.25 µg/1. Q02550
Methylene chloride ND 2 <1 µg/1. Q02550
n-Butylbenzene ND 0.5 <0.25 µg/1. 002550
n-Propylbenzene ND 0.5 <0.25 µg/1. Q02550
Naphthalene f-!D 0,5 <0.25 µg/1. Q02550
a-Xylene ND 0.5 <0.25· µg/1. Q02550
p-lsopropyltoluene ND 0.5 <0.25 ~g/1. Q02550
sec-Butylbenzene ND 0.5 <0.25 µg/1. Q02550
Styrene ND 0.5 <0.25 µg/1. Q02550
tert-Butylbenzene ND 0.5 <0.25 µg/1. Q02550
Tetrachloroethene ND 0.5 <0.25 µg/1. Q02550
Toluene ND 0.5 <0.25 µg/1. Q02550
trans-1,2-Dichloroethene .ND 0.5 <0.25 µg/1. Q02550
tranS-1,3-Dichloropropene ND 0.5 <0.25 µg/1. Q02550
Trlchloroethene ND 0.5 <0.25 µg/1. Q02550
Trichlorofluoromethane ND 0.5 <0.25 µg/1. Q02550
Vinyl chloride ND 0.5 <0.25 µg/1. Q02550
Laboratory C9ntrol Sample Reowe,y Spike Reowe,y Range QC
Result Amount Units % % Batch ID
1, 1, 1,2-Tetrachloroethane 22.5 20 µg/1. 112 70-139 Q02550
1, 1, 1-Trichloroethane 22.6 20 µg/1. 113 60-140 Q02550
1, 1,2,2-Tetrachloroe~ane 22.0 20 µg/1. 110 60-140 Q02550
1, 1,2-Trichloroethane 23.8 20 µg/1. 119 60-140 Q02550
·1, 1-Dichloroethane 23.7 20 µg/1. 118 60-140 Q02550
1, 1-Dichloroethene 21.1 20 µg/1. 106 60 -140 Q02550
1, 1-Dlchloropropene 22.4 20 µg/1. 112 62-140 Q02550
1,2,3-Trichlorobenzene 19.4 20 µg/1. 97 72-119 Q02550
1,2,3-Trichloropropane 22.6 20 µg/1. 113 68-131 Q02550
1,2.4-Trlchlorobenzene 14.8 20 µg/1. 74 58-133 Q02550
1,2,4-Trimethylbenzene 17.7 20 µg/1. 89 72 -125 Q02550
1,2-Dlbromo-3-chloropropane 11.4 20 µg/1. 57 50-135 Q02550
1,2-Dibromoethane (EDB) 22.3 20 µg/1. 111 66-130 Q02550
1,2-Dlchlorobenzene 17.8 20 µg/1. 89 64-137 Q02550
1,2-Dichloroethane 25.6 20 ~g/1. 128 72-137 Q02550
1,2-Dichlaropropane 2~.4 20 µg/1. 117 70-139 Q02550
1,3,5-T rirnethylbenzene 17.8 20 ~g/1. 89 73-124 Q02550
1,3-Dk:hlorobenzene 17.6 20 µg/1. 88 60-137 Q02550
1,3-Dlchloropropane 22.5 20 µg/1. 112 67 -131 Q02550
1,4-Dlchlorobenzene 17.2 20 µg/1. 86 64-139 Q02550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 2 of 14
I
NC CertlflcaUon No. 402 Level II QC Report SC CertlflcaUon No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
FIii/ Sl!IVlee AnaJyt!cal I Envltonmental SofuUOM FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 coc Group Number: G0105571
Transportation Project No.: WBS# 30173.126 Attn: Roger Smith Datemme Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923. South Tryon Sl Ste 100
--·-Laboratory Control Sample -Spike Re""'81y Range QC
Result Amount Units " " Ba!ch ID
2,2-Dlchloropropane 24.1 20 µg/L 120 62-138 Q02550
2-Chlorotoluene 17.1 20 µg/L 85 59-140 Q02550
4-Chlorotoluene 22.8 20 µg/L 114 67-140 Q02550
Benzene 22.4 20 µg/L 112 68-130 Q02550
Brom a benzene 19.9 20 µg/L 99 62-133 Q02550
Bromochloromethane 24.5 20 µg/L 122 69-131 Q02550
Bromodlch/oromethane 21.3 20 µg/L 107 72-13_0 Q02550
Bromoforrn 19.4 20 µg/L 97 59-126 Q02550
Bromomethane 26.4 20 µg/L 132 55-138 Q02550
Carbon Tetrachloride 17.6 20 µg/L 88 70-144 Q02550
Chlorribenzene 18.5 20 µg/L 93 75-122 Q02550
Chloroethane 24.4 20 µg/L 122 63 -145 Q02550
Chloroform 23.7 20 µgll 118 71 -137 002550
Chloromethane 23.3 20 µ,it. 116 50-144 002550
cis-1,2-Dlchloroethene 24.0 20 µg/L 120 62 -138 Q02550
cls-1,3-Dlchloropropene 24.9 20 µg/L 125 67 -133 002550
Dlbromochforomethane 23.0 20 µg/L 115 65 -133 002550
Dlbromomethane 25.0 20 µg/L 125 71-133 002550
Dlchforodlfluoromethane 20.8 20 µg/L 104 52-152 Q02550
Ethyfbenzene 18.0 20 µg/L 90 74 -130 002550
Hexachlorobutadiene 19.1 20 µg/L 95 52-149 Q02550
lsopropyl ether (IPE) 23.1 20 µg/L 115 70 -121 002550
lsopropylbenzene 17.9 20 µg/L 89 71 -130 Q02550
m,p-Xylenes 36.1 40 µg/L 90 74-128 Q02550
Methyl t-liutyl ether (MTBE) 22.8 20 µg/L 114 75-119 Q02550
Methylene chloride 26.3 20 µg/L 131 68-133 002550
n-Buty(benzene 17.3 20 µg/L 87 70-135 Q02550
n-Propylbenzene 18.9 20 µg/L 95 75,128 Q02550
Naphthalene 19.0 20 pg/L· 95 71-114 Q02550
a-Xylene 20.7 20 µg/L 104 65-130 002550
p-lsopropyltoluene 17.7 20 µg/L 88 59-138 Q02550
sec-Butylbenzene 17.1 20 µg/L 85 66-136 002550
Styrene 17.5 20 µg/L 88 78-122 Q02550
tert•Butylbenzene 17.8 20 µg/L 89 65-133 Q02550
Tetrachloroethene 17.8 20 ~g/L 89 66-145 Q02550
Toluene 19,6 20 µg/L 98 69-129 Q02550
trans-1;2-Dlchloroethene 21.3 20 µg/L 106 59-144 Q02550
trans-1,3-Dlchloropropene 22.2 20 µg/L 111 67-130 Q02550
Trichl_oroethene 20.1 20 µg/L 100 52-152 Q02550
Trfchlorofluoromethane 21.1 20 µglL 105 52-153 Q02550
Vinyl chloride 21.9 20 µglL 109 46-144 002550
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 3 of 14
.,. NC Certification No. 402 Level II QC Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2105
F11U Servlce Anllyti'caf 6 Envlronmehb/ S~u1lo111 FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number. G0105571 Transportation Project No.: WBS# 30173.126 Attn: Roger Smith Datemme Submitted: 1/21/05 8:05 c/o Hart and Hickman
2923 South Tryon St Ste 100
Matrix Spike Recove,y
Spike Re\r""' Range QC Sample ID: ae,w1 Amounl Units % Batch ID
109369 1, 1.1,2-Telrachloroethane 93.1 80 µg/1. 116 60-134 002550
10101-Trichloroethane 94.5 80 µg/1. 118 60-133 002550
1, 112,2-Tetrachloroethane 93.7 80 µg/1. 117 58-143 002550
1.1,2-Trichloroethane 98.7 80 µg/1. 123 58-138 002550
1, 1-Dlchloroethahe 96.0 80 µg/1. 120 57-131 002550
1, 1-Dlchloroethene 87.0 80 µg/1. 109 53-141 002550
1, 1-Dlchloropropene 96.2 80 µg/1. 120 53-135 002550
1,2,3-Trfchlorobenzene 81.3 80 µg/1. 102 53 -129 002550
1,2,3-Trichloropropane 93.1 80 µg/1. 116 63-135 002550
1,2,4-T richlorobeni:ene 64.0 80 µg/1. 80 51 -129 002550
1,2,4-Trimethylbenzene 77.6 80 µg/1. 97 70 -121 002550
1,2-Dib,:omo-3-chloropropane 44.7 80 µg/1. 56 46-137 002550
1,2-Dlbromoethane (EDB) 92.1 80 µg/1. 115 60 -133 002550
1,2.;DJchlorobenzene 76.4 80 µg/1. 95 64-130 002550
1,2-Dlchloroethane 104 80 µg/1. 130 66-136 002550
1,2-Dlchloropropane 96.3 80 µg/1. 120 64-133 002550
1,3,5-T rimethylbenzene 78.5 80 µg/1. 98 66-121 002550
1,3-Dlchlorobenzene 76.1 80 µg/1. 95 58-130 002550
1,3-Dlchloropropane 95.5 80 µg/1. 119 62 -130 002550
1,4-Dlchlorobenzene 74.6 80 µg/1. 93 59-136 002550
2,2-Dichloropropane 97.2 80 µg/1. 121 58-127 002550
2-Chlorototuene 78.7 80 µg/1. 98 56-134 002550
4-Chlorotoluene 87.8 80 µg/1. 110 56-141 002550
Benzene 95.0 80 µg/1. 119 69-122 002550
Bromobenzene 84.6 80 µg/1. 106 · 61-128 002550
Bromochloromethane 99.1 80 µg/1. 124. 62-128 002550
Bromodlchloromethane 86.5 80 µg/1. 108 63-127 002550
Bromofonn 79.4 80 µg/1. 99 56-127 002550
Bromomethane 103 80 µg/1. 129 57 -134 002550
carbon Tetrachloride 80.3 80 µg/1. 100 64-133 002550
Chlorobenzene 80.6 80 µg/1. 101 72-117 002550
Chloroethane 99.9 80 µg/1. 125 57-143 002550
Chlorofonn 97.8 80 µg/1. 122 65-133 002550
Chloromethane 96.5 80 µg/1. 121 45-142 002550
cls-1,2-Dlchloroethene 100 80 µg/1. 126 58-127 002550
cls-1,3-Dlchloropropene 97.3 80 µg/1. 122 62-129 002550
O!bromochloromethane ·94_5 80 µg/1. 118 59-132 002550
Dibromomethane 85.2 80 µg/1. 106 64-134 002550
Dlchlorodlfluoromethane 92.8 80 µg/1. 116 52-138 002550
Ethylbenz_ene 77.4 80 µg/1. 97. 71 -122 002550
Hexachlorobutadlene 88.7 80 µg/1. 111 54-134 002550
lsopropyl ether (!PE) 87.6 80 µg/1. 110 73-115 002550
lsopropylbenzene 78.6 80 µg/1. 98 69-121 002550
m,p-Xylenes 157 160 µg/1. 98 69-122 002550
Methyl I-butyl ether (MTBE) 90.8 80 µg/1. 114 75-116 002550
449 Springbrook Road -P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-B00/529-6364 -Fax: [phone] Page 4 of 14
NC Certlflcatlon No. 402 Level II QC Report SC Certlflcatlon No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
FuQ Service AnalydCII & Env/ronmenul Solllflan, FL Certlflcatlon No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571
Transportation Project No.: WBS# 30173.126
Attn: Roger Smith Date/rime Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon SL Ste 100
Matrix Spike ae__,
Spike Re~ery Range QC
_ Sample/0: Result Arnoont Units " Batch ID
Methylene chloride 106 80 µg/1. 132 58-137 002550
n-Butylbenzene 76.7 80 µg/L 96 71 -·121 002550
n-Propylbenzene 83.0 80 µg/L 104 73-119 002550
Naphthalene 78.9 80 µg/1. 99 64-118 002550
a-Xylene 92.9 80 µg/L 116 66-124 002550
p-lsopropyltoluene 78.4 80 µg/L 98 61-127 002550
sec-Buty[benzene 76.0 80 µg/L 95 65-126 002550
Styrene 72.6 80 µg/L 91 64-124 002550
tert-Butylbenzene 78.2 80 µg/L 98 63 -·123 002550
Tetrachloroethene 77.4 80 µg/L 97 62 -135 002550
Toluene 84.0 80 µg/1. 105 71-120 002550
trans-1, 2-Dichloroethene 89.9 80 µg/L 112 62 -133 002550
trans-1,3-0ic:hloropropene 76.1 80 µg/L 95 58-129 002550
Trichloroethane 84.2 80 µg/L 105 56-128 002550
Trichforofluoromethane 91.5 80 µg/L 114 49-147 002550
Vinyl chloride 95.7 80 µg/L 120 53-135 002550
Matrix Spike Duplicate Recovesy RPO
Spika. ae__, Range_ RPO "'"'" QC
Sample ID: Result Amount Units % ¾ % % Batch ID
109369 1, 1, 1,2-Tetrachloroethane 93.0 80 µg/L 116 60-134 0 0-20 002550
1, 1, 1-Trichloroelhane 92.0 80 µg/1. 115 60-133 3 0-20 002550
1, 1,2,2-Tetrachloroelhane 93.5 80 µg/L 117 58-143 0 0'20 002550
1, 1,2-Trlchloroe!llane 97.0 80 µg/L 121 58-138 2 0-20 002550
1, 1-Dichloroethane 93.5 .80 µg/L 117 57-131 3 0-20 002550
1, 1-Dlchloroethene 83.7 80 µg/L 105 53-141 4 0-20 002550
1,1-Dlchloropropene · 91.5 80 µg/L 114 53-135 5 0-20 002550
1,2,3-Trlchlorobenzene 83.9 80 µg/1. 105 53-129 3 0-20 002550
1,2,3-Trlchloropropane 93.5 80 µg/L 117 63-135 o o -20 002550
1,2,4-Trichlorobenzene 62.8 80 µg/L 79 51-129 2 0-20 002550
1,2,4-Trlmelhylbenzene 75.2 80 µg/L 94 70-121 3 0-20 002550
1,2-Dlbromo-3-chloropropane 45.4 80 µg/L 57 46-137 2 0-20 002550
1,2-Dlbromoethane (EDB) 91.5 80 µg/L 114 60-133 1 0-20 002550
1,2-Dichlorobenzene 74.7 80 µg/L 93 64-130 2 0-20 002550
1,2-Dlchloroethane. 101 80 µg/L 127 66-136 3 Q-20 _002550
1,2-Dlchloropropane 95,2 ·so µg/L 119 64-133 1 0-20 002550
1,3,5-Trlmelhylbenzene 75.3 80 -µg/L 94 66-121 4 0-20 002550
1,3-Dlchlorobenzene 74.7 80 µg/L 93 58-130 2 0-20 002550
1,3-Dichloropropane 91.8 80 µg/L 115 62-130 4 0-20 002550
1,4-Dlchlorobenzene 73.1 80 µg/1. 91 59-136 2 0-20 002550
2,2-Dlchloropropane 93.8 80 µg/L 117 58-127 4 0-20 002550
2-Chlorotoluene 74.6 80 µg/L 93 56-134 5 0-20 002550
4-Chlorotoluene 96.1 80 µg/L 120 56 -141 9 0-20 002550
449 Springbrook Road -P .o. Box 240543 '. Charlotte, NC 28224-0543
Page5 of14 Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
' NC Certification No. 402 Level II QC Report SC Certification No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Fllll Service Anllrtfcal & Envlronmentd 8olutfans FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571
TransportaUon Project No.: WBS# 30173.126 Attn: Roger Smith Daiemme Submitted: -1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon Sl Ste 100
Matrix Spike Duplicate -RPD
Spike Recovery Range RPD Range QC
Sample ID: ·Result Amount Unlls % % % %' Batch ID
Benzene 90.9 80 µg/L 114 69 -122 4 0-20 Q02550
Bromobenzene 84.1 80 µg/L 105 61-128 1 0-20 Q02550
Bromochloromethane 96.3 80 µg/L 120 62-128 3 0-20 Q02550
Bromod'lchloromethane 83.4 80 (Jg/L 104 63 ° 127 4 0-20 Q02550
Bromoform 77.0 80 µg/L 96 56-127 3 0-20 Q02550
Bromomethane 96.4 80 µg/L 121 57-134 6 0-20 Q02550
Carbon Tetrachloride 76.5 80 µgJL 96 64-133 5 0-20 Q02550
Chlorobenzene 77.0 80 (Jg/L 96 72-117 5 0-20 Q02550
Chloroethane 93.0 80 µg/L 116 57"-143 7 0-20 Q02550
Chloroform 95.8 80 µg/L 120 65-133 2 0-20 Q02550
Chloi"omethane 88.6 80 µg/L 111 45-142 8 0-20 Q02550
cls-1,2-Dichloroethene 96,8 80 µg/L 121 58-127 4 0-20 Q02550
cls-1,3-Dlchloropropene 95.1 80 µg/L 119 62-129 2 0-20 Q02550
Dibromochloromethane 91.2 80 µg/L 114 59-132 4 0-20 Q02550
Dibromomethane 87.1 80 µg/L 109 64-134 2 0-20 Q02550
Dlchlorodlffuoromethane 86.1 80 µg/L 108 52-138 7 0-20 Q02550
Ethylbenzene 76.1 80 . JJg/L 95 71 -122 2 0-20 Q02550
Hexachlorobutadiene 87.3 80 µg/L 109 54-134 2 0-20 Q02550
lsopropyl ether (IPE) 90.3 80 (Jg/L 113 73 -115 3 0-20 Q02550
/sopropylbenzene 75.9 80 (Jg/L 95 69 -121 3 0 -20 Q02550
m,p--Xylenes 152 160 µg/L 95 69 -122 4 0-20 Q02550
Methyl I-butyl ether (MTBE) 85.5 80 µg/L 107 75 -116 6 0-20 Q02550
Methylene chloride 101 80 µg/L 127 58 -137 4 0-20 Q02550
n-Butylbenzene 74.2 80 µg/L 93 71 -121 3 0-20 Q02550
n-Propyfbe,:izene 80.0 80 (Jg/L 100 • 73-119 4 0-20 Q02550
Naphthalene 78._4 80 µg/L 98 64-118 1 0-20 Q02550
a-Xylene 85.2 80 µg/L 106 66-124 9 0-20 Q02550
p-lsopropyltoluene 76.1 80 µg/L 95 61 -127 3 0-20 Q02550
sec-Butyfbenzene 73.0 80 µg/L 91 65 -126 4 0-20 Q02550
Styrene 72.7 80 . µg/L 91 64-124 0 0-2.0 Q02550
tert-Butylbenzene 75.0 80 µg/L 94 63 -123 4 0.-20 Q02550
Telrachloroethene 72.8 80 µg/L 91 62 -135 6 0-20 Q02550
Toluene 80.8 80 µg/L 101 71 -120 4 0-20 Q02550
trans-1, 2-0lchloroethen e 86.2 80 µg/L 108 62 -133 4 0-20 Q02550
lrans-1,3-0lchloropropene 87.2 80 µg/L 109 58 -129 14 0-20 Q02550
Trichloroethane 80.5 80 µg/L 101 56 -128 4 0-20 Q02550
Trichlorofluoromethane 87.7 80 µg/L 110 49 -147 4 0-20 Q02550
Vinyl chloride 90.3 80 (Jg/L 113 53 -135 6 0-20 Q02550
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529•6364 -Fax: [phone] Page 6 of 14
' ' I I '
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert. No. 37735
Full Service Analytical &.Envlronrnontal SoMlolUI FL Certification No. E87519
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Project ID: DOT-215
Project No.: WBS# 30173.126
Semlvolat(le Organic Compounds by GC/MS, method 625
Method Blank
1,2,4-Trichlorobenzene
1,2-Dlchlorobenzene
1,3-0lchlorobenzene
1,4-DlchlorobenzE!ne
2,4,5-Trtchlorophenot
2,4,6-Trtchlorophenol
2,4-Dlchlorophenol
2,4-Dlmethylphenol
2,4-Dlnltrophenol
2,4-Dinltrotoluene
2,6-Dinltrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphlhalene
2-Melhylphenol
2-Nitrophenol
3&4-Methyiphenol
3 ,3 '-Dlchlorobenzldlne
4,6-Dinitro-2-melhylphenol
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chlorophenylphenylelher
4-Nitrophenol
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranlhene
Benzo(g,h,l)perylene
Benzo(k)fiuoranlhene
Bls(2-chloroelhoxy)melhane
Bls(2-chloroelhyl)elher
Bls(2-chlorolsopropyl)elher
Bls(2-elhylhexyl)phthalate
Butylbenzylphthalate
Chrysene
D1-n-butylphthalate
Dl-n-octylphthalate
Dlbenzo(a,h)anthracene
Dlbenzofuran
Dlelhyfphthalate
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Control
RL Umlt Units
10
10
10
10
10
10
10
10
50
<5 µg/1.
<5 µg/1.
<5 µg/1.
<5 µg/1.
<5 µg/L
<5 µg/1.
<5 µg/1.
<5 µg/1.
<25 µg/1.
10 <5
10 · <5
10 <5
10 <5
10 <5
10 <5
10 <5
10 <5
50 <25
50 <25
10 <5
10 <5
10 <5
50 <25
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
<5
<5
<5
<5
<5.
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
µg/1.
Level II QC Report
2/2/05
COC Group Number: G0105571
Daterrlme Submitted: 1/21/05 8:05
QC Batch
ID
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
Q02493
002493
002493
002493'
002493
002493
002493
002493
002493
002493·
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
002493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 7 of14
NC CertlflcaUon No. 402 Level II QC Report SC CertlflcaUon No. 99012
NC Drinking Water Cert. No. 37735 2/2/05
Full &arvleo An1tylfeal a. Environmental SoMIOIUI FL CertlflcaUon No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571 Transportation Project No.: WBS# 30173.126
! ' Attn: Roger Smith D~teffime Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon St. Ste 100
Method Blank Control QC Batch Result RL Urfllt Units ID
Dlmethylphthalate ND 10 <5 µg/L Q02493
Fluoranthene ND 10 <5 µg/L Q02493
Fluorene ND 10 <5 µg/L Q02493
Hexachlorobenzene ND i ' 10 <5 µg/L Q02493
Hexachlorobutad/ene ND 10 <5 µg/L Q02493
Hexachlorocyclopentadlene ND 10 <5 µg/L Q02493
Hexachloroethane ND 10 <5 µg/L Q02493
lndeno(1,2,3-cd)pyrene ND 10 <5 µg/L Q02493
lsophorone ND 10 <5 µg/L Q02493
N-Nltrosodi'n-propylamlne · ND 10 <5 µg/L Q02493
Naphthalene ND 10 <5 µg/L Q02493
Nitrobenzene ND 10 <5 µg/L Q02493
Pentachlorophenol ND 10 <5 µg/L Q02493
Phenanthrene ND 10 <5 µg/L Q02493
Phenol ND 10 <5 µg/L Q02493
Pyrene ND 10 <5 µg/L Q02493
Laboratory Control Sample Recovery Spike Rooo,e,y -·· QC Result Amaml Units % % Batch ID
1·,2,4-Trfchlorobenzene 61.7 100 µg/1. 62 44-142 Q02493
1,2-Dichlorobenzene 65.4 100 µg/L 65 32 -129 Q02493
1,3-Dlchlorobenzene 59.6 100 µg/L 60 20 -124 Q02493
1,4-Dlchlorobenzene 61.4 100 µg/L 61 20-124 Q02493
2,4,6-Trichlorophenol 87.2 100 µg/L 87 37-144 Q02493
2,4-Dichlorophenol 82.6 100 µg/L 83 39-135 Q02493
2,4-Dlmethylphenol 75.1 100 µg/L 75 32 -119 Q02493
2,4-Dlnltrophenol 93.9 100 µg/L · 94 10 -191 Q02493
2,4-Dlnltrotoluene 102 100 µg/L 102 39. -139 Q02493
2,6-Dlnltrotoluene 102 100 µg/L 102 50 -158 Q02493
2-Chloronaphthalene 86.3 100 µg/L 86 60 -118 Q02493
2-Chlorophenol 72.3 100 µg/L 72 23-134 Q02493
2-Nitrophenol 83.5 100 µg/L 83 ·29-182 Q02493
3,3' -Dlchlorobenzldlne 115 100 µg/L 115 10-262 Q02493
4-Bromophenylphenylether 89.9 100 µg/L 90 53 -127 Q02493
4-Chloro-3-methylphenol 74.9 100 µg/L 75 22 -147 Q02493
4-Chlorophenylphenylether 88.7 100 µg/L 89 25 -158 Q02493
4-Nltrophenol 33.4 100 µg/L 33 10-132 Q02493
Acenaphthene 85.0 100 µg/L 85 47 -145 Q02493
Acenaphthylene 87.4 100 µg/L 87 33 -145 Q02493
Anthracene 88.5 100 µg/L. 88 27 -133 Q02493
Benzo(a)anthracene 80.0 ·100 µg/L 80 33-143 Q02493
Benzo(a)pyrene 91.3 100 µg/1. 91 17 -163 Q02493
'-,
449 Springbrook Road -P .0. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 8 of 14
~-NC Certlficatlon No. 402 Level II QC Report SC Certlflcatlon No. 99012
NC Drinking Water Cert No. 37735 2/2/05 . .,,
FL Certification No. E87519 Full Service Analytical l Envlron.~nfal Saluti!llll
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571
I i Transportation Project No.: WBS#30173.126
Attn: Roger Smith Date/rime Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon St. Ste 100
Laboratory Control Sample -Spike Recove,y Range QC
Result Amount Uolts % % Batch ID
Benzo(b)ffuoranlhene 96.7 100 µg/1. 97 24-159 Q02493
Benzo(g,h,l)perylene 90.9 100 µg/1. 91 10 -219 Q02493
Benzo(k}fluoranthene 72.7 100 µg/1. 73 11-162 Q02493
Bls(2-chloroethyl)ether 76.6 100 µg/1. 77 12-158 Q02493
Bls(2..,thylhexyl)phthalate 101 100 µg/1. 101 10-158 Q02493
Butylbenzylphlhalate 104 100 µg/1. 104 10-152 Q02493
Chrysene 75.2 100 µg/1. 75 17-168 Q02493
Di-n-butylphlhalate 90.7 100 µg/1. 91 10-118 Q02493
D1-n-octylphthalate 102 100 µg/1. 102 10-146 Q02493
I Dlbenzo(a,h)anlhracene 93.7 100 µg/1. 94 10-227 Q02493
Dlelhylphthalate 93.1 100 µg/1. 93 10-114 Q02493
Dlmelhylphlhalate 92.7 100 µg/1. 93 10-112 Q02493
Fluoranthene 86.7 100 µg/1. 87 26-137 Q02493
Fluorene 87.9 100 µg/1. 88 59-121 Q02493
Hexachlorobenzene 87.6 100 µg/1. 88 10-152 Q02493
Hexachlorobutadi~ne 56.9 100 µg/1. 57 24-116 Q02493
Hexachloroethane 55.2 100 µg/1. 55 40 -113 Q02493
Jndeno( 1,2 ,3-od)pyrene 101 100. µg/1. 101 10-171 Q02493
lsophorone 84.2 100 µg/1. 84 21 -196 Q02493
N-Nitrosodi-n-propylamlne 83.7 100 µg/1. 84 10-230 Q02493
Naphthalene 69.9 100 µg/1. 70 21 -133 Q02493
Nltrobenzene ·81.7 100 µg/1. 82 35-180 Q02493
Pentachlorophenol 117 100 µg/1. 117 14-176 Q02493
Phenanthrene 88.1 100 µg/1. 88 54-120 Q02493
Phenol 28.3 100 µg/1. 28 10 -112 Q02493
Pyrene 98.2 100 µg/1. 98 52-115 Q02493
Matrix Spike Recovery
Spike Rewery Range QC
Sample ID: ""'" Amou"t Units "' Batch ID
109032 1,2,4-Trichlorobenzene 152 200 µg/1. 76 44-142 Q02493
1,2-Dlchlorobenzene 147 200 µg/1. 73 32-129 Q02493
1,3--Dlchlorobenzene 138 200 µg/1. 69 20-124 Q02493
1,4-Dlchlorobenzene 141 200 µg/1. 71 20-124 Q02493
2,4,6-Trichlorophenol 175 200 µg/1. 87 37 -144 Q02493
2,4-Dlchlorophenol 171 200 µg/1. 85 39-135 Q02493
2,4-Dlmethylphenol 161 200 µg/1. 81 32-119 Q02493
2,4-Dlnltrophenol 152 200 _µgJL 76 10 -191 Q02493
2,4-Dlnltrotoluene 210 200 µg/1. 105 39, -139 Q02493
2,6-Dlnltrotoluene 214 200 µg/1. 107 50-158 Q02493
2-Chloronaphlhalene 181 200 µg/1. 91 60-118 Q02493
2-Chlorophenol 155 200 µg/1. 78 23-134 Q02493
2-Nltrophenol 179 200 µg/1. 90 29-182 Q02493
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: 704/529,6364 -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 9 of 14
1-1
NC Certification No. 402 Level II QC Report SC Certification.No. 99012
NC Drlnklng Water Cert. No. 37735 212105
Fllfl Service Artllytlcaf & Envlronmontd So/utl11ns FL Certification No. E87519
North Carolina Department of Project ID: DOT-215 COG Group Number: G0105571 Transportation Project No.: WBS# 30173.126 Attn: Roger Smith Dateffime Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon St. Ste 100
Matrix Spike Recovery
Spike. Re~ry Range QC Same.!_e ID: Result Amouot Units " Batch ID
3,3 • -Dlchlorobenzldine 233 200 µg/L 117 10-262 002493
4-Bromophenylphenylelher 194 200 µg/L 97 53-127 002493
4-Chloro-3-methylphenol 170 200 µg/L 85 22 -147 002493
4-Chlorophenylphenylether 177 200 µg/L 89 25-158 002493
4-Nltrophenol 76.3 200 µg/L 38 10-132 002493
Acenaphthene 182 200 µg/L 91 47 -145 002493
Acenaphthylene 184 200 µl)IL 92 33-145 002493
Anthracene 180 200 µg/L 90 27-133 002493
Benzo(a)antfiracene 191 200 µg/L 95 33 -143 002493
Benzo(a)pyrene 188 200 µg/L 94 17-163 002493
Ben·zo(b)ffuoranthene 182 200 µg/L 91 24-159' 002493
Benzo(g,h,l)perylene 181 200 µg/L 91 10 -219 002493
Ben~(k)fluoranthene 179 200 µg/L 89 11-162 002493
Bls(2-chloroelhyl)elher 161 200 µg/L 80 12-158 002493
Bls(2-elhylhexyl)phlhalate 190 · 200 µ_g/L 95 10 -158 002493
Butylbenzylphlhalale 196 200 µg/L 98 10-152 002493
Chrysene 181 200 µg/L 91 17-168 002493
Di-n-bulylphlhalale 192 200 µg/L 96 10-118 002493
Di-n-octyfphthalate 196 200 µg/L 98 10 -146 002493
Oibenzo(a,h)anthracene 186 200 µg/L 93 10-227 002493
Dlelhylphlhalale 189 200 µg/L 94 10-114 · 002493
Dlmethylphlhalale 189 200 µg/L 95 10-112 002493
Fluoranthene 187 200 µg/L 93 26-137 002493
Fluorene 182 200 µg/L 91 59-121 002493
Hexachlorobenzene 195 200 µg/L 97 10-152 ,002493
Hexachlorobutadlene 153 200 µg/L 76 24-116 002493
Hexachloroeth8ne 142 200 µg/L 71 40-113 002493
lndeno(1,2,3-cd)pyrene 194 200 µg/L 97 10-171 002493
lsophorone 185 200 µg/L 92 21-196 002493
N-Nltrosodl-n-propylamlne 182 200 µg/L 91 10-230 002493
Naphthalene 161 200 µg/L 80 21-133 002493
Nltrobenzene 178 200 µg/L 89 35-180 002493
Penlachlorophenol 247 200 µg/L 123 14-176 002493
Phenanthrene 187 200 µg/L 93 54-120 002493
Phenol 83.5 200 µg/L 42 10-112 002493
Pyrene 184 200 µg/L 92 52-115 002493
Matrix Spike Duplicate Reoove<)I RPO
Spike Recovery Range RPO Range QC Sample ID: ""'"" Amount Units % % ... % Batch ID
109032 1,2,4-Trlchlorobenzene 143 200 µglL 71 44-142 6 0-36 002493
1,2-Dlchlorobenzene 130 200 µg/L 65 32-129 12 0-41 002493
1,3-Dlchlorobenzene 126 200 µg/L 63 20 -124 9 0-41 002493
449 Springbrook Road -P.O. Box 240543 -Cha~otte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 10 of 14
NC Certification No. 402 Level II QC Report SC CertlficaUon No. 99012
NC Drinking Water Cert No. 3TT35 2/2/05
Full Sl!J\/1~• An.alytfcaf & Envll'OIIIMlltal Solutfon, FL CertlflcaUon No. E87519
North Carolina Department of Project ID: DOT-215 COC Group Number: G0105571 Transportation Project No.: WBS# 30173.126 Attn: Roger Smith DatefTime Submitted: 1/21/05 8:05
c/o Hart and Hickman
2923 South Tryon St Ste 100
Matrix Spike Duplicate R,a,,e,y RPO Spika """'"""' Range RPO Range QC Sample ID: Result Amouot Units % % % % Batch ID
1,4-Dichlorobenzehe 131 200 µg/1. 65 20-124 8 0-42 Q02493
2,4,6-Tnchlorophenol 161 200 µg/L 81 37 -144 8 0-29 Q02493
2,4-Dlchlorophenol 160 200 µg/1. 80 39 -135 7 0033 Q02493
2,4-Dlmethyfphenol 145 200 µg/1. 73 32-119 10 0-37 Q02493
2,4-Dlnllrophenol 150 200 µg/1. 75 10 -191 1 0-54 Q02493
2,4-Dlnltrotoluene 201 200 µg/1. 101 39-139 4 0-22 Q02493
2,6-Dinltrotoluene 206 200 µg/1. 104 50-158 3 0-25 Q02493
2-Chloronaphthalene 171 200 µg/1. 85 60 -118 6 0-34 Q02493
2-Chlorophenol 140 200" µg/1. 70 23-134 10 0-36 Q02493
2-Nitrophenol 163 200 µg/L 82 29-182 9 0-33 Q02493
3,3'-Dichlorobenzldlne 226 200 µg/L 113 10 -262 3 · 0-50 Q02493
4-Bromophenyfphenyfether 179 200 µg/L 90 53-127 8 0-25 Q02493
4-Chloro-3-melhyfphenol 165 200 µg/1. 83 22-147 3 0-28 Q02493
4-Chloropheny/phenylether 177 200 µg/L 88 25 -158 0 0 -29 Q02493
4-Nitrophenol 75.6 200 µg/L 38 10-132 1 0-48 Q02493
IA.cenaphthene 170 200 µg/1. 85 47 -145 7 0-34 Q02493
Acenaphthylene 171 200 µg/1. 86 33-145 7 0-33 Q02493
Anthracene 180 200 µg/L 90 27 -133 0 0-18 Q02493
Benzo{a)anthracene 178 200 µg/L 89 33 -143 7 0-25 Q02493
Benzo(a)pyrene 191 200 µg/1. 96 17-163 2 0 -21 Q02493
Benzo(b)fluoranthene 188 200 . µg/L 94 24-159 3 0-28 Q02493
Benzo(g,h,l)perylene 170 200 µg/L 85 10 -219 7 0-31 Q02493
Benzo(k)fluoranthene 187 200 µg/L 93 11-162 4 0-36 Q02493
Bis(2-chloroelhyl)ether 143 200 µg/L 71 12-158 12 0-44 Q02493
Bis(2-ethyfhexyf)phlhalate 186 200 µg/L '93 10-158 3 0-24 Q02493
Butylbenzylphlhalate 196 200 µg/1. 98 10-152 0 0-26 002493
Chrysene 171 200 µg/L 85 17-168 6 0-27 Q02493
D1-n-butylphlhalate 188 200 µg/L 94 10-118 2 0-21 Q02493
Di-n-octylphthalate 183 200 µg/L 91 10-146 7 0-38 Q02493
Dibenzo(a,h)anthracene 174 200 µg/L 87 10-227 7 0-33 Q02493
Dlethylphlhalate 185 200 µg/1. 93 10-114 2 0-22 Q02493
Dlmelhyfphlhalale 184 200 µg/L 92 10-112 3 0-24 Q02493
Fluoranthene 182 200 µg/L 91 26-137 2 0-22 Q02493
Fluorene 179 200 µg/L 89 59-121 2 0-27 Q02493
· Hexachlorobenzene 180 200 µg/L 90 10-152 8 0-20 Q02493
Hexachlorobutadlene 142 200 µg/L 71 24-116 7 0-40 Q02493
Hexachloroethane 122 200 µg/L 61 40-113 15 0-40 Q02493
lndeno(1,2,3-cd)pyrene 178 200 µg/L 89 10 -171 8 0-31 Q02493
lsophorone 163 200 µg/L 81 21 -196 13 0-38 Q02493
N-Nltrosodl-<1-propylamlne 151 200 µg/L 76 10-230 18 0-38 Q02493
Naphthalene 146 200 µg/L 73 21 -133 10 0-36 Q024.93
Nllrobenzene 147 200 µg/L 74 35-180 19 0-26 Q02493
Pentachlorophenol 231 200 µg/L 115 14-176 7 0-26 Q02493
Phenanthrene 180 200 µg/L 90 54-120 4 0-19 Q02493
449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543
Phone: [phone] • Toll Free Number: 1-B00/529-6364 -Fax: [phone] Page 11 of14
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert. No. 37735
Level II QC Report
2/2/05
FullSttvlco.\nafytle&II. Envlrom11,ntal8alutlon, FL CertiflcaUon No. E87519
North Carolina Department of
Transportation
Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Metals by (CP. method 6010B
Method Blank
Lead
Laboratory Control Sample
Matrix Spike
Sample ID:
Lead
109243 Lead
Matrix Spike Duplicate
Sample JD:
109243 Lead
Project ID: DOT-215 COC Group Number: G0105571
Project No.: WBS# 30173.126
Date/Time Submitted: 1/21/05 8:05
Result
-0.0006
Result
0.226
"""' 0.239
Result
0.242
Rl
Control
Limit Uni1S
0.005 <0.0025 mg/L
""'""'">' Spike Recovery Range
Amount Units % %
0.25 mg/L ·go 80 -120
-Spike Recovery Range
Amount· Units % %
0.25 mg/L 96 75-125
Recovery
Spike Recovery Range RPO
Amount Units % % %
0.25 mg/L 97 75 -125 1
RPO
Range
%
0-20
449 Springbrook Road -P.O. Box 240543 -Charlotte. NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone]
QC Batch
ID
Q02688
QC
Batch ID
Q02688
QC
Batch ID
Q02688
QC
Balch ID
Q02688
Page 13 of 14
NC Certification No. 402
SC Certification No. 99012
NC Drinking Water Cert No. 37735
Fu!1Svvlc1klalytfcal&EnvlronrnentalSolu1lon1 FL CertlficaUon No. E87519
Project ID: DOT-215 North Carolina Department of
Transportation Project No.: WBS# 30173.126 Attn: Roger Smith
c/o Hart and Hickman
2923 South Tryon St Ste 100
Volatlfe Petroleum. Hydrocarbons by GC-PIO/FID, method MADEP VPH
Method Blank Coalrol
Result RL Umlt units
C5-C8 Aliphatics ND 100 <50 µg/L
C9-C1 o Aromatics ND 100 <50 µg/L
C9-C12 Allphatics ND 100 <50 µgll.
Laboratory Control Sample -Spike Recovery Range
Result Amoual Uru~ % %
C5-C8 Allphatics 152 150 µgll. 101 70 -130
C9-C10 Aromatics 51.2 50 µg/L 102 70-130
C9-C12 Al/phatlcs 148 150 µgll. 99 70 -130
Matrix Spike Recovery
Spike .. .,.,,,, Range
Sample ID: """'' Amouat Units % ..
109246 C5-C8 Allphatics 185 150 µg/l. 124 70-130
C9-C10 Aromatics 56.5 50 µgll. 113 70 -130
C9-C12 Allphatics 193 150 µgll. 129 70 -130
Matrix Spike Duplicate -Spike Recovery Range
Sample ID: Result Amount Units % %
109246 C5-C8 Allphatics 168 150 µgll. 112 70-130
C9-C10 Aromatics 50.2 50 µgll. 100 70 -130
C9-C12 Allphatics 179 150 µg/l. 120 70 -130
Level II QC Report
2/2/05
COC Group Number: G0105571
Date!Tlme Submitted: 1/21/05 8:05
QC Batch
ID
Q02486
Q02486
Q02486
QC.
Batch ID
Q02486
Q02486
Q02486
QC
Balch ID
Q02486
Q02486
Q02486
RPO
RPO Range ac
% % Balch ID
10 0-25 .Q02486
12 0.25 Q02486
7 0-25 Q02486
449 Springbrook Road -P.O. Box 240543 -Charlotte, NC 28224-0543
Phone: [phone] -Toll Free Number: 1-800/529-6364 -Fax: [phone] Page 14 of 14
VPH {Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman
Project Name "'D'""O"""T'---""2""'15:;._ __________ _
Laboratory Name Prism Laboratories, Inc.
Site Location Robbinsville NC NC Certification# (Lab) ...:4""02"----------------
Sample Matrix Water -'--'====='--------------'-'-=-'---"'------------
Sample Information and Analytical Results
Method for Ranges: MADEP VPH Sample Identification 109241
Collection Ootion !for soill* NA
VPH Surrogate Standards Date Collected 1/20/05 '°'.
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05 --~
Aromatic: 2,5-Dibromotoluene Date Extracted NA
Date AnaIV7ed 1/27/05
% D~Sollds ' NA
Dilution Factor .,, .• ,. 1
Sample
Hvdrocarbon Ranges Units of Measure MDL RL Blank Results
C5 -CB Aliohatics-ua/L 75 100 < 100 < 100
C9 -C12 Aliphatics-ug/L 70 100 < 100 < 100
C9 -C1 O Aromatics-ug/L 35 100 < 100 < 100
Sample Surrogate Acceotance Range ·:, '~170-130% 70-130%
Allohatic Surrogate % Recoven1 -FID . ·::;-. ... 73% 86%
Aromatic Surrogate % Recoverv --PIO 73% 82%
• Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
•• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrafions of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher (indicate-type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
Page1 of7VPH
~No -Details Attached
~Yes -Details Attached
VPH (Aliphatic~/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc.
Project Name .=D:..::O'-'Tc.;-2=.1:..:5:__ __________ _ NC Certification# (Lab) ..:4..:;;02=-------------
Site Location Robbinsville, NC Sample Matrix Water --'-'-='---------------
Sample Information and Analytical Results
Method for Ranges: MADEP VPH Samole Identification 109242
Collection Option {for soil)* NA
VPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05
Aromatic: 2,5-Dibromotoluene Date Extracted NA
Date Analvzed 1/27/05
% Orv Solids NA
Dilution Factor 1
Sample
Hydrocarbon Ranaes Units of Measure MDL RL Blank Results
cs -CB Aliphatics** . ug/L 75 100 < 100 1400
C9 -C12 AliPhatics** ug/L 70 100 < 100 280
C9 -C1 O Aromatics"* ug/L 35 100. < 100 1300
Sample Surrogate Acceptance Range 70-130% 70-130%
Aliphatic Surro11ate % Recoverv -FID 73% 107%
Aromatic Surroaate % Recoverv -PIO 73% 109%
• Option 1 = Established fill line on vial Option 2 = Sampling Device 0ndicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
** Unadjusted value. Should exclude the concentration of any surrogate{s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher 0ndicate type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?·
Were any significant modifications to the VPH method made?
Page 2 of 7 VPH
C::=_Y_e~s---:::_::::>No -Details Attached C No :::::>ves -Details Attached
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman
Project Name "'D""O"'"T"---=2'-'-15-=-=-----------­
Site Location Robbinsville NC
Laboratory Name Prism Laboratories, Inc.
NC Certification# (Lab) ..:4:,:::0:.2 ___________ _
Sample Matrix ..;W:.=at::e::...r ___________ _
Sample Information and Analytical Results
Method for Ranges: MADEP VPH _ Samole Identification. 109243
Collection Ootion /for solll* NA
VPH Surrogate Standards Date Collected ., 1/20/05
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05
Aromatic: 2,5-Dlbromotoluene Date Extracted NA
Date Analvzed 1/27/05
% DrvSolids NA
Dilution Factor 1
Sample
Hvdrocarbon Ranges Units of Measure MDL RL Blank Results
CS • CB Aliphatics** 111:1/L 75 100 < 100 -83 J
C9 • C12 Aliphatics** ug/L 70 100 < 100 110
C9 • C10 Aromatics** ug/L 35 100 < 100 150
Sample Surrogate Acceotance Ranae 70-130% 70-130%
AliPhatic Surroaate % Recoverv • FID 73% 102%
Aromatic Surrogate % Recoverv • PID 73% 82%
• Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
-Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations ofother ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher (indicate type)
VPH rev: 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
J-Estimated value between the reporting limit and the MDL
Page 3 of 7 VPH
~No-Details Attached
~Yes. Details Attached
-
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc.
Project Name -=D:.c:Oa..;T'--2=-1.:.;:5'-'-----------­
Site Location Robbinsville NC
NC Certification# (Lab) "'°'4~02""-------------
Sample Matrix Water -=~-------------
Sample Information and Analytical Results
Method for Ranges: MADEP VPH . Samole Identification 109244
Collection Option (for soil)* NA
VPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05
Aromatic: 2,5-Dlbromotoluene Date Extracted NA
Date Analyzed 1/27/05
% Orv Solids NA
Dilution Factor 1
Sample
Hydrocarbon Ranges Units of Measure MDL RL Blank Results
cs -CB Aliphatics** ua/L 75,, -•J•" 100 < 100 < 100
C9 -C12 Aliphatics** ug/L 70, 100 < 100 < 100
C9 -C10 Aromatics** ug/L 35 100 < 100 < 100
Sample Surrogate Acceptance Range 70-130% 70-130%
Aliohatic Surroqate % Recoverv -FID 73% 81%
Aromatic Surroaate % Recoverv -PIO 73% 76%
• Option 1 = Established fill line on vial Option 2 = Sampling Device Qndicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
•• Unadjusted value. Should exclude the concentration of anysurrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified,range.
MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank or Trip Blank whichever is higher (indicate type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
Page4 of7VPH
~No -Details Attached
~Yes .. Details Attached
-
Client Name Hart & Hickman
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Project Name _,D::.:O::.T.,_-.::2.,_,15::...,.,..-,------------
Laboratory Name Prism Laboratories, Inc.
Site Location _,R-"o:::b:::b:::.in:.::s::.:v:.::il:::le"--'-N:..::C::._ _________ _
NC Certification# (Lab) _.,4,;;0=-2 ____________ _
Sample M_atrix ..:W"'"'ataae;:..r ____________ _
Sample Information and Analvtical Results
Method for Ranges: MADEP VPH Samole Identification 109245
Collection Option (for soill* NA
VPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05
Aromatic: 2,5-Dibromotoluene Date Extracted NA
Date Analvzed 1/27/05
% Orv Solids NA
DIiution Factor 1
Sample
Hvdrocarbon Ranaes Units of Measure MDL RL Blank Results
CS -CB Aliphatics** untL 75 100 < 100 < 100
C9 -C12 Aliphatics** ug/L 70 100 < 100 < 100
C9 -C1 O Aromatics** ug/L 35 100 < 100 180
Sample Surrogate Acceptance Ranae 70-130% 70-130%
Aliphatic Surronate % Recoverv • FID 73% 86%
Aromatic Surroaate % Recovel'.lf • PIO 73% 73% • Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
-Unadjusted value. Should exclude the concentrallon of any surrogate(s), internal standards. and/or concentrallons of other ranges that elute within the specified range. MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher (indicate type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
Page 5 of 7 VPH
~No• Details Attached
~Yes• Details Attached
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc.
Project Name ..:D:..:O::cT=--2=-1.:..:5:..-__________ _ NC _Certification# (Lab) -'4c.=.02=---------------
Site Location Robbinsville NC Sample Matrix Water -'-"='--------------
Sample Information and Analvtical Results
Method for Ranges: MADEP VPH Samnle Identification 109246
Collection Ootion (for soill* NA
VPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 2,6-Dibromotoluene Date Received 1/21/05
Aromatic: 2,6-Dibromotoluene Date Extracted NA
Date Analvzed 1/27/05
% DrvSolids NA
Dilution Factor 1
Samole
Hydrocarbon Ranges Units of Measure MDL RL Blank Results
C6 -CS Aliphatics** ug/L 75 100 < 100 < 100
C9 -C12 Aliohatics** ua/L 70 100 < 100 < 100
C9 -C1 O Aromatics** ug/L 35 100 < 100 < 100
Samole Surroaate Acceotance Ranae 70-130% 70-130%
Aliohatlc Surroaate % Recoverv -FID 73% 77%'
Aromatic Surrogate % Recoverv -PID 73% 73%
• Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
** Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher Qndicate type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
Page 6 of7 VPH
C Yes ::::>No• Details Attached C No =:>Yes • Details Attached
Client Name Hart & Hickman
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Project Name ..::D:-"O":-T=:---:==-21-'-'5'-:::-----:,=---------­
Site Location Robbinsville, NC
Laboratory Name Prism Laboratories, Inc.
NC Certification# (Lab) 74::;0=,2 ___________ _
Sample Matrix ...aW.:.a=t=e=--r ___________ _
Sample Information and Analvtical Results
Method for Ranges: MADEP VPH Sample Identification 109247
Collection Ontion (for solll* Trip Blank
VPH Surrogate standards Date Collected 1/20/05
Aliphatic: 2,5-Dibromotoluene Date Received 1/21/05
Aromatic: 2,5-Dlbromotoluene Date Extracted NA
Date Anal•~ed 1/27/05
% Orv Solids NA
Dilution Factor 1
Hvdrocarbon Ranaes Units of Measure MDL . RL Blank Results
CS -CB Aliphatics** ug/L 75 100 < 100 < 100
C9 -C12 Aliphatics** ug/L 70 100 < 100 < 100
C9 -C10 Aromatics** U!l/L 35 100 < 100 < 100
Sample Surrogate Acceotance Ranae 70-130% 70-130%
Aliohatic Surroaate % Recoverv • FID 73% 82%
Aromatic Surroaate % Recoverv • PIO 73% 75%
• Option 1 = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCoreTM) Option 3 = Field weight of soil
** Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank or Trip Blank whichever is higher (indicate type)
VPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Were any significant modifications to the VPH method made?
Page 7 of7 VPH
C -Yes ~No• Details Attached
C No =:)Yes -Details Attached
-
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc
Project Name ..cD""O __ T~-=2~15....,,. ______________ _ NC Certification# (Lab) _4_02~------------
Site Location Robbinsville, NC Sample Matrix Water ---------------
Sample Information and Analvtical Results
Method for Ranges: MADEP EPH Sample Identification 109241
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Analyzed 1/26/05 .
#1: 2-Bromonaphthalene % Drv Solids NA
#2: 2-Fluorobiphenyl Dilution Factor 1
Sample
Hvdrocarbon Ranges Units of Measure MDL RL Blank Results
C9 -C18 Aliphatics* ug/L 75 100 < 100 < 100
C19 -C36 Aliphatics* ug/L 31 100 < 100 < 100
C11 -C22 Aromatics* ug/L 71 100 < 100 < 100
Sample Surrogate Acceptance Range 40-140% 40-140%
Aliohatic Surroaate ·% Recoverv 52% 73%
Aromatic Surrogate % Recoverv 97% 93%
Fractionation Surrogate Acceptance Range 40-140% 40-140%
Fractionation Surrooate #1 % Recovery 105% 99%
Fractionation Surroaate #2 % Recoverv 114% 108%
• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank= Laboratory Method Blank
EPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method ?
Were any significant modifications to the EPH method made?
Page 1 of 6 EPH
~ No -Details Attached
Yes Gu
C]0 Yes -Details Attached
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman
Project Name --'D'-O=-T-'-•-=2'-'-1-=---5 _____________ _
Laboratory Name Prism Laboratories, Inc
Site Location Robbinsville, NC
NC Certification# (Lab) 74::c'0=-2 __________ _
Sample Matrix Water -'-'="--------------
Sample Information and Analytical Results
Method for Ranges: MADEP EPH Samole Identification 109242
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Analvzed 1/25/05
#1: 2-Bromonaphthalene % DrvSolids NA
#2: 2-Fluorobiphenyl Dilution Factor 1
Sample
Hydrocarbon Ranges Units of Measure MDL RL Blank Results
C9 -C18 Aliphatics* ug/L 75 100 < 100 100
C19 -C36 Aliphatics* ug/L 31 100 < 100 < 100
C11 -C22 Aromatics* ug/L 71 100 < 100 1000
Sample Surrogate Acceptance Range 40-140% 40-140%
Aliohatic Surronate % Recoven, 52% 45%
Aromatic SurroAate % Recoverv 97% 92%
Fractionation Surrogate Acceptance Range 40-140% 40-140%
Fractionation Surroaate #1 % Recovery 105% 122%
Fractionation SurroAate #2 % Recoverv 114% · 1-11%
* Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL= Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank
EPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method 7
Were any significant modifications to the EPH method made?
Page 2 of 6 EPH
~ No -Details Attached
Yes Gu
~ Yes -Details Attached
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc
Project Name -=Dc.:O=.T:..·=2..:.15~-------------­
Site Location Robbinsville NC
NC Certification# (Lab) 402 --------------Sam p I e Matrix ..:W..:.a:::;t=e=-r ___________ _
Sample Information and Analytical Results
Method for Ranges: MADEP EPH Sample Identification 109243
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Anal""ed 1/26/05
#1: 2-Bromonaphthalene % .Drv Solids NA
#2: 2-Fluorobiphenyl Dilution Factor 1
Samole
Hvdrocarbon Ranges Units of Measure MDL RL Blank Results
C9 -C18 Allohatics* U0/1 75 100 < 100 510
C19 -C36 Aliohatics* ua/L 31 100 < 100 < 100
C11 -C22 Aromatics* ug/L 71 100 < 100 770
Sample Surrogate Acceptance Range 40-140% 40-140%
Aliohatic Surroaate % Recoverv 52% 64%
Aromatic Surrogate % Recoverv 97% 97%
Fractionation Surrogate Acceptance Ranae 40-140% 40-140%
Fractionation Surrogate #1 % Recoverv 105% 112%
Fractionation Surroaate #2 % Recoverv 114% 102%
• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank
EPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method ?
Were any significant modifications to the EPH method made?
Page 3 of 6 EPH
~ No -Details Attached
Yes ~
~ Yes -Details Attached
-i
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman Laboratory Name Prism Laboratories, Inc
Project Name .:D:..;;O:..;Tcc-2;:.1:..;;5;.... ____________ _ NC Certification# (Lab) ..:4.;:;02=-------------
Site Location Robbinsville NC Sample Matrix Water ---------------
Sample Information and Analytical Results
Method for Ranges: MADEP EPH Samele Identification 109244
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Analvzed 1/26/05
#1: 2-Bromonaphthalene % Orv Solids NA
#2: 2-Fluorobiphenyl Dilution Factor 1
Sample
Hvdrocarbon Ranaes Units of Measure MDL RL Blank Results
C9 -C18 Allphatlcs* ug/L 75 100 < 100 < 100
C19 • C36 Aliphatics* ug/L 31 100 < 100 < 100
C11 -C22 Aromatics* ug/L 71 100 < 100 < 100
Sample Surrogate Acceptance Ranae 40-140% 40-140%
Aliphatic Surrogate % Recoverv 52% 40%
Aromatic Surroaate % Recoverv 97% 89%
Fractionation Surroaate Acceptance Ranae 40-140%. 40-140%
Fractionation Surrogate #1 % Recoverv 105% 102%
Fractionation Surroaate #2 % Recoverv 114% 104%
• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank
EPH rev. 11/00
Were all performance/acceptance standards for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method ?
Were any significant modifications to the EPH method made?
Page 4 of 6 EPH
@:) No • Details Attached
Yes Gu
C]0 Yes -Details Attached
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman
Project Name DOT-215
Laboratory Name Prism Laboratories, Inc
-,,-'-'----'""--,---c:-------------S it e Location Robbinsville NC
NC Certification# (Lab) .,.4:"'."02-,--__________ _
Sample Matrix ..aW.:..:a::.:te"'r'-------------
Sample Information and Analytical Results
Method for Ranges: MADEP EPH Sample Identification to9245
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Analvzed 1/26/05
#1: 2-Bromonaphthalene % Orv Solids NA
#2: 2-Fluorobiphenyl Dilution Factor 1
Sample
Hydrocarbon Ranaes Units of Measure MDL RL Blank Results
C9 -C18 Aliphatics* ug/L 75 100 < 100 550
C19 -C36 Aliphatics* ug/L 31 100 < 100 9700
C11 -C22 Aromatics* ua/L 71 100 < 100 2600
Sample Surrogate Acceptance Range 40-140% 40-140%
AliPhatic Surroaate % Recoverv 52% 42%
Aromatic Surroaate % Recoven1 97% 121%
Fractionation Surrogate Acceotance Range 40-140% 40-140%
Fractionation Surroaate #1 % Recoven1 105% 112%
Fractionation Surroaate #2 % Recoverv 114% 91%
• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank
EPH rev. 11/00
Were all perfonnance/acceptance standards for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method ?
Were any significant modifications to the EPH method made?
Page 5 of6 EPH
~ No -Details Attached
Yes Gu
~ Yes -Details Attached
EPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name Hart & Hickman 'Laboratory Name Prism Laboratories, Inc
Project Name ..;;D:;.;O=.T.:..--=2"'-15=--------------­
Site Location Robbinsville NC
NC Certification# (Lab) -'4"'02=--------------
Sample Matrix Water -""'='-------------
Sample Information and Analytical Results
Method for Ranges: MADEP EPH Samole Identification 109246
EPH Surrogate Standards Date Collected 1/20/05
Aliphatic: 1-Chloro-octadecane Date Received 1/21/05
Aromatic: o-Terphenyl Date Extracted 1/25/05
EPH Fractionation Surrogates Date Anal=ed 1/26/05
#1: 2-Bromonaphthalene % DrvSollds NA
#2: 2-Fluorobiphenyl Dilution Factor 1
~ Samole
Hydrocarbon Ranges Units of Measure MDL RL Blank Results
C9 -C18 Aliphatics* ug/L 75 100 < 100 < 100
C19 -C36 Aliphatics* ug/L 31 100 < 100 < 100
C11 -C22 Aromatics* ug/L 71 100 < 100 < 100
Sample Surroaate Acceotance Range 40-140% 40-140%
Aliphatic Surroaate % Recovery 52% 40%
Aromatic Surroaate % Recoverv 97% 75%
Fractionation Surroaate Acceotance Ranae 40-140% 40-140%
Fractionation Surrogate #1 % Recoverv 105% 89%
Fractionation Surroaate #2 % Recoverv 114% 104%
• Unadjusted value. Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range.
MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank
EPH rev. 11/00
Were all performance/acceptance standards-for required QA/QC procedures achieved?
Was blank correction applied as a significant modification of the method ?
Were any significant modifications to the EPH method made?
Page 6 of 6 EPH
~ No -Details Attached
Yes Gi::)
~ Yes -Details Attached
FUii Service Analytical & Environmental Solutions
449 Springbrook Road• P.O. Box 240543 • Charlotte, NC 28224--0543
Phone: [phone] • Fax: [phone]
Client Company Name: 1-J.,,t-J-1-1;~ k,..,...,.;,. PC..
Report To/Contact Name: 12ut"cS:"';-I:!,
Reporting Address: Z. 'i' 2 J :S". 7Fv "'1 SI. . ) DC,
Ci,acl..-ik .iJ c Z92-t>3 '
-CHAIN OF CUSTODY RECORD
PAGEL OF ..L. QUOTE, TO ENSURE PROPER BILLING:, ______ _
ProjeclName: Z>DJ' :2. i=f"
Short Hold Analysis:~ (No) UST Project:~(No)
. •Please ATTACH any project specific reporting (QC LEVEL lfil))l IV)
: proy~sions and/or QC Req~reJJ1ents
Invoice To: .IJ C. ]) D I
Address: ----=--c--~=.,...-,,-,----------D !> "T \,I 13 5 =ii= .3' C> 17 :3. 12.1,,
Phone: 2°'1 fl"/.·0 •0 7 Fax (Yesl"(Nol:)'-_----­
•Em~~mall Address -:$~dow
EDD Type: __ · PDI' __ Excel __ Other .
Purchase Order NoJBilling Refl:!rence _________ _
Requested Due Date □ 1 Day □ 2 Days □ 3 D!3,ys O 4 Days l?f'50ays
TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL /
Certification: NELAC __ USACE __ .. FL __ NC_✓_
Site Location Name: DbT· lwbJ,;:,,,.:,~,'J/L "Worldn~ Days" □ 6-9 Days O Standard 1 O days
Samples re~lved after 15:00 will be processed next business day. . . .
Turnaround time is based on busl_ness da.ys, _excluding weekends an~ holldQ~;.,Q
. SC __ OTHER ,,-N/A __ _
Water Chlorinated: YES NO ,7' ✓.::: Site Location·Physlcal Address: J::,.l,b;..,~yj Uc, JJ C (SEE REVERSE FOR TERMS & CONDmONS REGARDING SERVICES ,J/_,/'
RENDERED'By PRISM LABORATORIES, INC. TO CLIENT} _ ~-fi Sample Iced Upon Collection: YES_ NO_
TIME MATRI~ SAMPLE CONTAINER
CLIENT
SAMPl.;E D~SCRIPTION
vw-1
M _,
Sampler's Sign8.ture
DATE
COLLECTED
) z,/. .>
1/wJ,1
'/;.~ e,.>
½.P!or
')z.,,Jo;
'ho,/4r
COLLECTED
MILITARY
HOURS
rz ':JP
/3).r'
3'3t>
I 3:S'"c
)'// 0 ..,
J.>/j
(SOIL,
WATER OR 'TYPE
SLUDGE) SEE BELOW NO.-
V
)/
I (
).,/
w
~(!;. .3
Sampled By (Print Name)
Method O ipment: NOTE: ALL PLE coo S SHOULD E TAPED SHUT WI USTODY S FOR
SAMPLES ARE NOT AqCEPTED AND VERIRED AGAINST CCC UNTIL RECEIVED AT THE
SIZE -1.t-..... 1
~EQU~ED
PRESERVA-~ i} ~
TIVES ~ "" '9 0 t,\1)~~ '1',~Q. z,
2 3 I
'3 2. z :5 )
,} 2, 2 3 I
3 2.. 2. 3 I
3 2-2.. 3 J
3 2.., .z. ' .:> .i ..
3
Affiliation //.
0 Fed Ex O UPS ~--delivered O Prism Field Serv!ce □ Other Go, Q , ,
NPDES: I U~· I GROUNDWATER: I DRINKING WATER: I S0LIDWASTE: I RC~A: CERCLA I LANDFILL I OTHER:. □NC □sc t:rNC □SC □NC □sc □NC □SC □NC □SC □NC □SC □NC □SC □NC □SC □NC □SC
□ □ , □------□ . □---,---□ □----□---□---*CONTAINER TYPE cooE&. A;; Amber C;; Clear G;; Glass p;; Plastic: TL= TAflnn-1 inJ:>rl r.0 ... \/nl,. -\1,.., ... a .. f"\---1--·--L--•-,... '• ' -
REMARKS
PRISM
LAB
JDNO.
PRESS DOWN FIRMLY • 3 COPIES
SEE REVERSE FOR
TERMS & CONDITIONS
OAlr.lM.111