2002_CherokeeCoMSWLF_October2023GWMR_FID1827635_20240202

Semi-Annual Water Quality Monitoring Report-October 2023 Cherokee County Lined Landfill Page 1
Introduction
On behalf of Cherokee County, Municipal Engineering, Inc. is pleased to present this Semi-Annual
Water Quality Monitoring Report for an event performed at the Cherokee County Lined Landfill (SWS
Permit No. 20-02) on October 3,4 &6, 2023. The site is located at 10160 US Hwy 19/74/129, Marble,
Cherokee County, North Carolina.

North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Section (SWS) Rules at
Title 15A, North Carolina Administrative Code, Subchapter 13B (15A NCAC 13B) .1630 through .1637
require that Cherokee County provide this monitoring report to the SWS on a semi-annual basis. This
report contains a description of sampling procedures, field and laboratory results, ground and surface
water characterization results, and discussion of an assessment downgradient of MW-4, submitted in
general accordance with 15A NCAC 13B.1632(i), the SWS Environmental Monitoring Report Form and
SWS memorandums. Detection tables, a potentiometric map, field parameters, laboratory analytical
reports with quality assurance/quality control data, chains-of-custody (COC) are also included in this
report.

Benzene and cobalt were detected above their respective NC Groundwater Quality Standards located at
15A NCAC 2L .0200 (2L Standard) in samples collected from MW-4 and MW-7, respectively. Various
constituents were detected in raw leachate samples, including 1,4-dioxane. No constituents were detected
above allowable Standards in surface water samples collected from the Valley River, which serves as the
local discharge feature.

Water samples were also collected and tested for Per and Polyfluoroalkyl Substances (PFAS) from
monitor well locations MW-4, MW-6S, and the raw leachate. PFAS constituents were detected in each
sample.
Background
The site operates as an active lined municipal solid waste landfill (MSWLF) which encompasses
approximately 17 acres. Contiguous Phases (1, 2 & 5 with vertical expansions Phase 3 & 4) make up this
lined landfill; therefore, they are combined and treated as a single unit in this report. Water quality
monitoring has been consistently performed at least semi-annually prior to commencing operations in
2000. The site has been under assessment monitoring since February 2008 in response to detections of
volatile organic compound (VOC) in samples collected from MW-6S, MW-6D and MW-7. Assessment
monitoring of MW-4 was also initiated in October 2022 in response to observed impacts. MESCO
requested that 1,4-Dioxane be only targeted at samples MW-4 and leachate on April 14, 2023
(DIN:1792187) which was approved by the SWS on May 11, 2023 (DIN:1795180).
Sampling Locations
The currently approved water quality monitoring network includes 18 locations; thirteen downgradient
monitoring wells (MW-2, MW-3, MW-4, MW-5, MW-6S, MW-6D, MW-7, MW-8, MW-9, P-17, P-18,
P-19 and P-21) an upgradient background monitoring well (MW-BG), influent to a wastewater holding
lagoon (LEACHATE), three downstream surface water locations (SW-2, SW-4, SW-5) and one upstream
surface water point (SW-1). Quality control measures included analysis of an equipment blank (EB) and
field blank (FB). All locations listed in the WQMP were sampled during this event.

Semi-Annual Water Quality Monitoring Report-October 2023 Cherokee County Lined Landfill Page 2

Water quality monitoring locations are depicted on Figure 1. A summary detailing the construction of
the water quality monitoring wells is presented on Table 1.
Sampling and Laboratory Procedures
Sampling was conducted utilizing portable methodology outlined in the NCDEQ SWS guidance
document Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised
April 2008. The function and integrity of all monitoring locations were visually evaluated with a few
improvements made as documented on Table 2. The depth to water in each well was electronically gaged
prior to purging to quantify the static water level elevation. Bailing or submersible pumping was used to
purge the wells a minimum of three times the volume of standing water in the well or until dry. Samples
were collected up to 24 hours following purging. Surface water samples were dipped from the Valley
River at previously designated locations. Samples were then placed into laboratory-prepared, pre-
preserved containers. Samples were kept on ice and transported to a NC-certified laboratory under proper
chain of custody (C-O-C) protocol within the specified hold times for each analysis.

Field Parameter Data
Stabilized field parameters were recorded prior to water sample collection, which included pH, specific
conductance, temperature, hardness (for surface water samples only) and turbidity. A summary of the
field parameter data is presented in Table 3 and field data sheets are in Appendix A. In general field
parameter results remain consistent with previously reported events.

Laboratory Results
Pace Analytical Services, LLC (PACE) network of labs (NC Certs. #12, 40375, 667) performed all the
laboratory analysis except for leachate BOD which was tested by Earth Environmental (NC Cert. #352).
All groundwater samples were tested for constituents listed in 40 CFR 258 Appendix I, mercury, 1.4-
dioxane and tetrahydrofuran except for MW-5. Pace reportedly misplaced the VOC samples collected
from MW-5. Surface waters were tested for parameters listed in Appendix I, 1,4-dioxane and
tetrahydrofuran. The leachate samples were tested for the SWS required list of parameters and low level
1,4-dioxane. Additionally, 3 groundwater wells, the lagoon leachate and the EB were tested for 40 PFAS
compounds using draft EPA Method 1633. A sampling and analysis table summarizing the locations,
targeted constituents and methods is presented as Table 4. Laboratory results and C-O-Cs are presented
in Appendix B.

Water samples were analyzed to the laboratory-established Method Detection Limits (MDL) and any
value between the MDL and laboratory-established Reporting Limit (RL) is qualified by the laboratory as
with a "J" which indicates an estimated concentration. "J-qualified" concentrations are considered non-
quantifiable and discretion should be made prior to making decisions based on a value that the laboratory
considers an estimate. Table 5 summarizes constituents detected in groundwater and QC samples
compared to the 2L Standards effective April 1, 2022. Detected concentrations were also compared to the
Maximum Contaminant Level (MCL) commonly referenced as the Federal “Drinking Water Standard”
which are not recognized by NCDEQ as compliance Standards for these particular samples. Table 6 lists
the constituents detected in surface water samples compared to values in the current version of the
Division of Water Resources (DWR) Surface Water Quality Tables. Figure 1 shows the spatial

Semi-Annual Water Quality Monitoring Report-October 2023 Cherokee County Lined Landfill Page 3
distribution of the constituents detected in excess of established compliance Standards. Table 7
summarizes the sample locations where PFAS constituents were detected. It should be noted that there
are no compliance Standards currently established for PFAS constituents applicable to groundwater or
surface waters in North Carolina.
Quality Control Samples
A low “J” qualified concentration of copper was detected in the EB sample Although the artifact
contaminant was identified, MESCO believes the validity of the data-set is not affected since the
concentration of copper was detected at just above the MDL. No other constituents were detected in either
the EB or FB.
Groundwater Samples Above Standards
Metals
Cobalt was only detected in sample MW-7 (32.8 ug/L) above its 2L Standard (1.0 ug/L). This is a
significant change from the previous monitoring event where 6 additional locations reported the detection
of cobalt above the 2L Standard.

VOCs
Sample MW-4 contained concentrations of benzene at 2.4 ug/L, above its respective 2L Standards of 1.0
ug/L.
Surface Water Samples Above Standards
No constituents were detected in surface water samples above allowable Standards.
Leachate Samples
Quantifiable concentrations of 2 metals and 1 VOC were detected in the raw leachate samples
(LEACHATE) collected from the inlet to the lined holding lagoon. The BOD and COD levels were low
and BOD/COD ratio (0.09) was high compared to typical domestic wastewater. BOD/COD ratio above
0.5 may indicate that the majority of organic matter is easily treated biologically1.
PFAS
Each of the 3 groundwater samples contained quantifiable concentrations of between 10 and 16 PFAS
constituents out of 40. PFAS was found in all groundwater samples collected downgradient of this unit.
The highest concentrations for a PFAS constituent were for PFHxA, detected in 2 of the 3 wells at
concentrations ranging from 170 ng/L in MW-4 nanograms per liter (ng/L) to 310 ng/L in MW-7.
The leachate sample reported the detection of 19 PFAS constituents, the highest of which was for the
constituent 5:3FTCA. Individual PFAS constituents’ concentrations detected in groundwater, and the
leachate sample are summarized in Table 7.

https://cgi.tu-harburg.de/~awwweb/wbt/emwater/lessons/lesson_a1/lm_pg_1068.html

Semi-Annual Water Quality Monitoring Report-October 2023 Cherokee County Lined Landfill Page 4
Groundwater and Surface Water Characterization
A potentiometric map from groundwater elevations of the uppermost aquifer recorded during this event is
shown on Figure 1. Groundwater flow rates and directions were calculated and are included on Table 8.
Groundwater flows in a general southerly direction towards the Valley River discharge feature with rates
ranging from about 16 feet/year (MW-BG) to 1,781 feet/year (MW-5), averaging approximately 295
feet/year. The flow directions and gradients are generally consistent with historical observations.
The Valley River was visually observed to have moderate volume, moderate flow and low turbidity which
is typical for the Fall season.

Findings
During this event all detections were within their own respective identified. range with the exception of
benzene in samples from MW-4. Cobalt was only detected above the allowable 2L Standard in MW-7.
The source of metals observed in MW-7 are believed to originate from dissolution of sediment entrained
in the sample containers.

Metals, including cobalt, are naturally inherent in the groundwater at the site with several lines of
substantiating evidenced contained in an ASD-Total Metals drafted by MESCO dated July 26, 2017. The
NC SWS concurred that metals may originate from erosion of natural deposits, but would not recognize
the background concentrations since turbidity values were absent. An ASD -Addendum
Workplan/Timeline-Metals was approved by the SWS and data continues to be collected to determine the
natural background concentrations. An ASD-Add will be drafted if the data supports this approach. In
the interim, it's understood that assessment monitoring in response to observed metal exceedances, in and
of themselves, will not be self-implemented.

The lack of VOCs in concentrations in excess of applicable standards in samples collected from shallow
wells P-17, P-18, P-19, and P-21 during this event continues to support the assertion that the horizontal
and vertical extent of VOC migration identified south of the landfill remains within the compliance
boundary. There are no potential downgradient groundwater receptors between the landfill and the
Valley River discharge feature. Surface water monitoring results indicate the discharge feature also
remains unimpaired.

The source of VOCs as observed in sample MW-4 is likely evidence of a leachate release. Cherokee
County self-implemented assessment activities per Rule 15A NCAC 13B .1634. in response to previous
detections of contaminates (benzene, 1,4-dioxane, cobalt) in May 2023. A temporary well (HAB-1),
located downgradient of MW-4 did not contain benzene or 1,4-dioxane, however cobalt was detected
slightly above the 2L but significantly lower than MW-4. The lack of VOCs, suggests the impacts to the
uppermost aquifer have not migrated to the Valley River discharge feature which is within the compliance
boundary. No further assessment activities or corrective actions are recommended at this time.
The detection of PFAS was not unanticipated due to the prevalence of PFAS in the environment as
documented in literature.
Closing
Semi-Annual water quality monitoring is planned to continue in the Spring of 2024.
Figure
1690167017001660
1
6
80
1660SWSWSWSW1650
16401650163016401660
SWMWGWE=1635.11MW-2MWGWE1654.84MW-3MWGWE=1644.96MW-4MWGWE=1628.49MW-5MWGWE=1644.72MW-6SMWGWE=1628.62MW-7MWGWE=1628.59MW-8MWGWE=1638.89MW-9P-4Not VisitedMWGWE=1626.01P-17MWGWE=1626.78P-18MWGWE=1627.42P-19GWE=1625.52P-20SMWGWE=1625.26P-21MWGWE=1631.70*MW-6DP-18DGWE=1626.07(Not Tested)*P-20DMWGWE=1653.70MW-BG1680FIGURE 1PHASE LIMITS LINED MSWFACILITY PROPERTY BOUNDARYEXISTING TOPOGRAPHIC CONTOURSCOMPLIANCE BOUNDARYOBSERVATION WELL/PIEZOMETERMONITORING WELL - IN NETWORKTEMPORARY MONITORING WELL- ABANDONED (MAY 4, 2023)ROADSTREE LINESTREAM/CREEKSURFACE WATER SAMPLING LOCATIONEQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (OCT 3-4, 2023)GROUNDWATER POTENTIOMETRIC ELEVATION*NOTE: DEEP WELLS NOT USED FOR CONTOURSLEGENDSW-SWMWGWE = 2626.85*MW-INACTIVE PHASE 1 over 3INACTIVE PHASE 2 over 4LAGOONSW-1 (970' UP STREAM)SW-2SW-5SW-4NOTES:THIS MAP WAS GENERATED FROM AERIAL PHOTOS FLOWN ON2-10-94 BY TRIANGLE AERIAL MAPPING, SUPPLEMENTED BY GROUNDSURVEYS BY MUNICIPAL ENGINEERING SERVICES CO., PA.MW-4Benzene - 2.5 ug/LVALLEY RIVERVAL
L
E
Y
R
I
V
ER WETLANDSACTIVE PHASE 5MW-7Cobalt - 32.8 ug/LDATEDRAWING NO.SHEET NO.SCALE:DATE:DRWN. BY:CHKD. BY:PROJECT NUMBERBY REV.DESCRIPTION
68 Shipwash Drive, Garner, NC 27529 - Phone: [phone]
P.O. Box 349, Boone, NC 28607 - Phone: [phone]
License Numbers: F-0812 & C-586
Municipal Engineering, inc. MU N I C IP
A
LENG
INE E R INGSUBTITLE D LINED
LANDFILL
CHEROKEE COUNTY
MARBLE, NORTH CAROLINASINGLE EVENT POTENTIOMETRIC MAP
WITH WATER QUALITY STANDARD VIOLATIONS HAB-1No VOCs May 2023MWSMWSPRINGSW-ACLOSED LF(MONITORED SEPARATELY)No VOCs May 2023VOCs Not Tested Oct 2023
Tables
Table 1
Groundwater Monitoring Well Construction Table
October 3-4, 2023
Well
Diameter
Total Well
Depth
Top of
Screen
Depth
Screen
Length
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
(inches)(ft bgs)(ft bgs)(ft)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
MW-BG 4/27/19 2 41.48 26.48 15 Sandy Silt 1688.31 1688.85 1653.70 34.61 35.182100 -83.908300
MW-2 10/6/97 2 58 43 15 PWR 1691.36 1688.48 1635.11 56.25 35.180694 -83.907753
MW-3 10/7/97 2 38.5 23.5 15 Silt 1689.41 1687.15 1654.84 34.57 35.180375 -83.908472
MW-4 2/3/97 2 27 12 15 Sandy Silt 1663.34 1660.58 1644.96 18.38 35.179919 -83.908356
MW-5 10/10/97 2 10.9 5.9 5 Silty Sand 1638.14 1636.30 1628.49 9.65 35.179011 -83.907569
MW-6S 10/8/97 2 20 5 15 Gneiss 1661.17 1658.67 1644.72 16.45 35.178281 -83.908381
MW-6D 10/8/97 2 50 35 15 Gneiss 1658.12 1656.14 1631.70 26.42 35.178281 -83.908381
MW-7 10/3/97 2 25 10 15 Sandy Silt 1651.65 1647.17 1628.62 23.03 35.178394 -83.909811
MW-8 5/26/04 2 15 5 10 PWR 1642.02 1639.02 1628.59 13.43 35.178219 -83.910833
MW-9 4/18/02 2 30 15 15 Silt 1664.88 1662.37 1638.89 25.99 35.178242 -83.911844
P-17 1/19/06 2 12.28 5.28 8 Weathered Rock 1638.09 1635.64 1626.01 12.08 35.177872 -83.908669
P-18 1/17/06 1 16.6 6.6 10 Rock 1636.98 1634.06 1626.78 10.20 35.177925 -83.908144
P-18D 6/23/10 2 54.43 44.43 10 Competent Rock 1637.08 1633.44 --35.177925 -83.908144
P-19 1/18/06 2 11.9 7.9 4 Rock 1636.29 1633.19 1627.42 8.87 35.178253 -83.907889
P-20S 6/15/10 2 20.43 5.43 15 Weathered Rock 1638.61 1635.59 1625.52 13.09 35.178078 -83.909794
P-20D 8/30/10 2 42.92 32.92 10 Rock 1638.25 1635.93 1626.07 12.18 35.178078 -83.909794
P-21 6/22/10 2 20.2 7.2 13 Weathered Rock 1637.15 1634.13 1625.26 11.89 35.177972 -83.909783
P-4 5/24/94 2 56 ??Sandy Silt 1679.20 1676.90 ---35.179319 -83.913572
NOTE:
bgs = below ground surface
amsl= above mean sea level
btoc = below top of casing (PVC well casing)
Monitoring
Well
Date
Installed
Geology of
Screened
Interval
Latitude Longitude
Cherokee County Lined MSWLF Page 1 of 1
Table 2
Field Observations of Monitoring Locations
October 3-4, 2023
Monitoring
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Locked Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface Pad
Appears
Effective
Comments
MW-BG Yes Yes Yes Yes Yes Yes Installed 4/27/19. Background well
MW-2 Yes Yes Yes Yes Yes Yes
MW-3 Yes Yes Yes Yes Yes ?Pad covered which is typical, poor path
MW-4 Yes Yes Yes Yes Yes ?Pad covered which is typical, poor path
MW-5 Yes Yes Yes Yes Yes Yes
MW-6S Yes Yes Yes Yes Yes Yes
MW-6D Yes Yes Yes Yes Yes Yes Slight constriction at ground level
MW-7 Yes Yes Yes Yes Yes Yes PVC exposed top of metal case, overgrown vegetation
MW-8 Yes Yes Yes Yes Yes Yes
MW-9 Yes Yes Yes Yes Yes Yes
P-17 Yes Yes Yes Yes Yes Yes Fast Recharge
P-18 Yes Yes Yes Yes Yes Yes 1 inch well
P-18D Yes Yes Yes Yes Yes Yes
P-19 Yes Yes Yes Yes Yes ?Pad covered which is typical.
P-20S Yes Yes Yes Yes Yes Yes
P-20D Yes Yes Yes Yes Yes Yes
P-21 Yes Yes Yes Yes Yes Yes
HAB-1 Yes -----Temporary abandoned well for MW-4 assessment
SW-1 Yes -----Low volume, velocity & clear turbidity
SW-2 Yes -----Low volume, velocity & clear turbidity
SW-4 Yes -----Low volume, velocity & clear turbidity
SW-5 Yes -----Low volume, velocity & clear turbidity
Any unusual field conditions, observations, or events:MW-9 constriction was repaired & re-developed by J. Pfohl (MESCO) NCCWC #3301-A in April 2020.
MW-7 stickup extended 2.03 ft., locking case replaced, redeveloped & elevation resurveyed prior to September 2020 event.MW-4 sediment continues to accumulate around well from erosion of adjacent slope.
Stormwater retained in basins on river bank.
Cherokee County Lined Landfill Page 1 of 1
Table 3
Field Parameter Data SummaryOctober 3-4 & 6, 2023
Depth to
Water
Water
Elevation
TOC
Elevation Temp.pH
Specific
Conductance Hardness
Turbidity
of Metal
Sample
Units ft (btoc)ft (amsl)ft (amsl) C SU цs/cm mg/L NTU
MW-BG 34.61 1653.70 1688.31 16.7 6.2 166 NR 9.31
MW-2 56.25 1635.11 1691.36 16.8 6.1 196 NR NR
MW-3 34.57 1654.84 1689.41 17.1 6.5 19 NR NR
MW-4 18.38 1644.96 1663.34 16.4 6.3 407 NR NR
MW-5 9.65 1628.49 1638.14 17.2 7.0 473 NR NR
MW-6S 16.45 1644.72 1661.17 16.9 7.2 622 NR NR
MW-6D 26.42 1631.70 1658.12 17.0 7.2 403 NR NR
MW-7 23.03 1628.62 1651.65 16.3 6.4 525 NR NR
MW-8 13.43 1628.59 1642.02 17.1 6.4 119 NR NR
MW-9 25.99 1638.89 1664.88 16.7 6.5 137 NR NR
P-17 12.08 1626.01 1638.09 16.9 5.9 230 NR NR
P-18 10.20 1626.78 1636.98 17.3 6.3 221 NR NR
P-18D NR -1637.08 NR NR NR NR NR
P-19 8.87 1627.42 1636.29 16.8 6.4 271 NR NR
P-20S 13.09 1625.52 1638.61 NR NR NR NR NR
P-20D 12.18 1626.07 1638.25 NR NR NR NR NR
P-21 11.89 1625.26 1637.15 18.3 5.8 77 NR NR
P-4 NR -1679.20 NR NR NR NR NR
Minimum 8.87 1625.26 1636.29 16.3 5.8 19 NR -
Average 20.44 1634.17 1655.00 17.0 6.4 276 NR -
Maximum 56.25 1654.84 1691.36 18.3 7.2 622 NR -
SW-1 ---15.0 6.9 41 34.2 NR
SW-2 ---13.8 6.9 51 34.2 NR
SW-4 ---14.8 7.0 47 34.2 NR
SW-5 ---14.5 6.9 62 34.2 NR
Minimum ---13.8 6.9 41 34.2 -
Average ---14.5 6.9 50 34.2 -
Maximum ---15.0 7.0 62 34.2 -
NR = No Reading Attempted
Cherokee County Lined Landfill Page 1 of 1
Table 4
Sampling and Analysis Summary
October 3-4 & 6, 2023
VOCs Total Metals THFMercuryPFAS1,4-DioxaneTemperatureDpeth to WaterConductivityHardnesspHTurbiditySulfidePhosphorusBOD, 5 dayCODNitrateLab EPA 8260D Lab EPA 6000/7000Lab EPA 8260DLab EPA 7470Lab EPA Draft 1633Lab EPA 8260DField MeterField MeterField MeterField KitField MeterField MeterLab EPA 300.0Lab EPA365.4Lab SM 5210BLab SM 5220DLab EPA 300.1MW-BG x x x x x x x x x x
MW-2 x x x x x x x x x
MW-3 x x x x x x x x x
MW-4 x x x x x x x x x x
MW-5 x x x x x
MW-6S x x x x x x x x x x
MW-6D x x x x x x x x x
MW-7 x x x x x x x x x x
MW-8 x x x x x x x x x
MW-9 x x x x x x x x x
P-17 x x x x x x x x x
P-18 x x x x x x x x x
P-18D
P-19 x x x x x x x x x
P-20S x
P-20D x
P-21 x x x x x x x x x
LEACHATE x x x x x x x x x x x x
SW-1 x x x x x x x x
SW-2 x x x x x x x x
SW-4 x x x x x x x x
SW-5 x x x x x x x x
EB x x x x
FB x x x
App I = List from current 40 CFR 258
App. I Field Parameters LeachateOther
Cherokee County Lined Landfill Page 1 of 1
Table 5
Groundwater, Leachate and QC Sample Detections
October 3-6, 2023
2LStandard MW-BG MW-2 MW-3 MW-4 MW-5 MW-6S MW-6D MW-7 MW-8 MW-9 P-17 P-18 P-19 P-21 LEACHATE EB FBIMAC*BG S S S S S S S S S S S S S Leachate QC QC
Barium, total 0.5 1 700 2000 30.7 119 18.4 39 29.6 138 2.3 J 22.6 1.9 J 4.7 J 7.1 J 40.3 12.9 14.3 461 --Beryllium, total 0.17 4 4 4 0.25 J 0.18 J 1.1 J 0.66 J 0.29 J 0.56 J --Cadmium, total 0.33 1 2 5 0.46 J 0.45 J 1.2 0.34 J 0.8 J 1.6 0.76 J --Chromium, total 0.38 1 10 100 6 2.2 J 2.7 J 3.5 J 4.7 J --Cobalt, total 12500 25000 1 NE 1.9 J 1.6 J 1.2 J 7.3 J 4.8 J 1.3 J 32.8 4 J 6.2 J 3.1 J --
Copper, total 0.42 1 1000 1300 3.9 J 67.2 0.44 J --
Lead, total 2.1 10 15 15 4.1 J 8.2 J --
Nickel, total 1 5 100 NE 5 J 2.3 J 5 J 5.2 7.3 6 --
Silver, total 1 5 20 NE 1.2 J 1.6 J 1 J --
Vanadium, total 1 10 7 NE 9 J 1.9 J 1.3 J 2.1 J 1.3 J 1.3 J 6.1 J --
Zinc, total 11 20 1000 NE 37.4 123 --
1,4-Dichlorobenzene 0.33 1 6 75 0.77 J --2.9 2.2
1,4-Dioxane 0.597/38.7 3/150 3 NE <38.7 <38.7 <38.7 1.58 J --<38.7 <38.7 <38.7 <38.7 <38.7 <38.7 <38.7 <38.7 <38.7 13 <38.7 <38.7
Acetone 5.1 25 6000 NE --24.6 J
Benzene 0.34 1 1 5 2.5 --Chlorobenzene 1.7 5 50 100 2.5 --1.1 0.53 J 0.44 Jcis-1,2-Dichloroethene 0.96 10 70 70 0.41 J --0.96 J 1.2 1.3Tetrahydrofuran3.5 10 2000*NE 7.3 J --
BOD, 5 day 2000 2000 NE NE ----------------------------9500 ----Nitrate 20 20 10,000 45,000 ----------------------------30 ----COD 0.28 1 NE NE ----------------------------110000 ----Phosphorus 25 50 NE NE ----------------------------71 ----pH, Field (SU)0.1 0.1 <6.5 or >8.5 NE ----------------------------6.57 ----Notes:
BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample.
Bold Above RL and established 2L STD (Regulatory Compliance Standard)
Highlighted Above Established MCL Drinking Water Std. (No regulatory significance)
MDL = Method Detection Limit established by the laboratory.
2L = NC 2L groundwater Standard 15A NCAC 02L .0202
MCL = Maximum Contaminant Level for drinking water established by the USEPA.
IMAC = Interim Maximum Allowable Concentration established via 15A NCAC 02L .0202
J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit".
Preliminary source of violations are believed to be anthropogenic with leachate and/or landfill gas as suspected transport mechanism. A definitive source of the detections was not determined as part of this report.
RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix."
Units ug/L. Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established
MCLRL
Leachate Parameters
Outside Historically Identified Range
Parameter Name MDL
Metals (Targeted 40CFR 258 Appendix I)
VOCs (Targeted 40CFR 258 Appendix I & 1,4-Dioxane)
Cherokee County Lined Landfill Page 1 of 1
Table 6
Surface Water Sample Detections
October 6, 2023
SW-1 SW-2 SW-4 SW-5
Upstream Downstream Downstream Downstream
Barium, total 3.5 5 NE NE 21,000 2,000 7.2 6.9 7 7.1
Copper, total 0.24 1 3.58C, 4.89A NE NE 1300 0.5 J
Hardness 17,100 NE NE NE NE 34,200 34,200 34,200 34,200
Notes:
J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit".
Red Bold Above RL and Applicable Established 2B Std.
Above Established Federal MCL Primary Drinking Water Std.
MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation.
Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation.
1 NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes.
2B Standards from Class C. Some metals calculated from measured hardness values.
2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health.
Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses
3 NC ISTV= North Carolina In-Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DWR staff for further information.
4 MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes.
MCL4
Units ug/L. Blank cells means Not Detected, NE means Standard Not Established
RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a
Parameter Name MDL RL NC 2B STD1 EPA
NRWQC2 NC ISTV3
specific analyte in a specific matrix."
Receiving surface waters is Valley River (12-108-20) Class C
Hardness as CaCo3 (Field Measured)
Targeted 40CFR 258 Appendix I
Cherokee County Lined Landfill Page 1 of 1
Table 7
PFAS Detections in Groundwater, Leachate and Quality Control Samples
October 3-4, 2023
2LStandard MW-4 MW-6S MW-7 LEACHATE EB
IMAC S S S Leachate QC2-(N-methyl perfluorooctanesulfonamido) acetic acid variable variable NE NE 0.72 J 18
2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA)variable variable NE NE 63 1000
3-Perfluoroheptyl propanoic acid (7:3FTCA)variable variable NE NE 50 J
3-Perfluoropropyl propanoic acid (3:3FTCA)variable variable NE NE 6.1 60
N-ethyl perfluorooctanesulfonamidoacetic acid variable variable NE NE 45
Perfluoro-3-methoxypropanoic acid (PFMPA)variable variable NE NE 1.3 J
Perfluorobutanesulfonic acid (PFBS) variable variable NE NE 10 2.1 8.2 36
Perfluorobutanoic Acid variable variable NE NE 50 7.3 38 230
Perfluorodecanoic acid (PFDA) variable variable NE NE 0.22 J 3.7 J
Perfluoroheptane Sulfonate (PFHPS) variable variable NE NE 0.37 J
Perfluoroheptanoic acid (PFHpA) variable variable NE NE 32 6.6 25 130
Perfluorohexanesulfonic acid (PFHxS) variable variable NE NE 32 1.5 3.2 120
Perfluorohexanoic acid (PFHxA) variable variable NE NE 170 14 310 660
Perfluorononanoic acid (PFNA) variable variable NE NE 2.3 0.67 J 8
Perfluorooctanesulfonic acid (PFOS) variable variable NE NE 3.7 0.9 J 1.7 17
Perfluorooctanoic acid (PFOA) variable variable NE NE 66 3.2 29 230
Perfluoropentanesulfonic Acid (PFPeS) variable variable NE NE 1.8 0.41 J 0.79 J 4.9 J
Perfluoropentanoic Acid (PFPeA) variable variable NE NE 55 11 110 200
Sodium 1H,1H,2H,2H-Perfluorodecane Sulfonate (8:2) variable variable NE NE 11 J
Sodium 1H,1H,2H,2H-Perfluorohexane Sulfonate (4:2) variable variable NE NE 0.83 J
Sodium 1H,1H,2H,2H-Perfluorooctane Sulfonate (6:2) variable variable NE NE 13 47
506 48 527 2872 0Notes:
QC = Quality Control Sample, D = Downgradient/Downstream Sample
MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation.
Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation.
2L = NC 2L Groundater Standard 15A NCAC 02L .0202. All detections are a 2L violation if no standard established.
IMAC = Interim Maximum Allowable Concentration established via 15A NCAC 02L .0202
MCL = Maximum Contaminant Level for drinking water established by the USEPA.
J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit".
Units ng/L unless shown otherwise, Blank cells means not detected, NE means not established.
RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix."
TOTAL
Parameter Name MDL RL MCL
Cherokee County Lined Landfill Page 1 of 1
Table 8
Hydrologic Properties at Monitoring Well Locations
October 3-4, 2023
Monitoring
Well
Hydraulic
Conductivity
(cm/sec)
Effective
Porosity
(%)
Hydraulic
Gradient
(ft/ft)
Flow
Rate
(ft/yr)
Flow
Direction
Depth to
Water (ft)
Groundwater
Elevation
(ft amsl)
Screened Interval
Lithology
MW-BG 2.27E-05 14 0.10 16 N82E 34.61 1653.70 Sandy Silt
MW-2 1.97E-04 16 0.10 130 S59E 56.25 1635.11 PWR
MW-3 1.18E-04 10 0.17 207 S64E 34.57 1654.84 Silt
MW-4 1.71E-04 16 0.18 194 N63E 18.38 1644.96 Sandy Silt
MW-5 1.66E-03 15 0.16 1781 S84E 9.65 1628.49 Silty Sand
MW-6S 4.15E-05 15 0.09 25 S15E 16.45 1644.72 Gneiss
MW-7 5.80E-05 16 0.14 51 S08W 23.03 1628.62 Sandy Silt
MW-8 1.27E-04 14 0.05 48 S11E 13.43 1628.59 PWR
MW-9 2.84E-04 14 0.10 205 S16E 25.99 1638.89 Silt
Minimum 2.27E-05 10 0.05 16 -9.65 1628.49 -
Average 2.98E-04 14 0.12 295 -25.82 1639.77 -
Maximum 1.66E-03 16 0.18 1781 -56.25 1654.84 -
NOTE:Effective porosity values derived from the Design Hydrogeologic Studies for the Cherokee Co. MSWLF, except for MW-5 and MW-6S.
Effective Porosity value for MW-5 & MW-6S obtained from table in Applied Hydrogeology of Fractured Rocks, Singhal & Gupta ( 1999).
Hydraulic Conductivities were derived from slug tests previously performed by Municipal Engineering Services.
Wells screened in deeper aquifer were not utilized for flow directions/gradients.
Hydrologic Gradient calculated from water levels measured on October 3-4, 2023.
Flow rate (Q ) is defined by modified Darcy's equation:
where
K = hydraulic conductivity
ne = effective porosity
dh = head difference
dl = horizontal distance
Q=−K
ne
⋅dh
dl
Cherokee County Lined MSWLF Page 1 of 1
Appendix A
Field Sampling Parameter Data Sheet(s)
Appendix B
Laboratory Analysis Reports
Chains of Custody
#=CL#
October 25, 2023
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92692736
92692736
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
CHEROKEE LINED MSWLF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 10, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
704-977-0968
Enclosures
cc:Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 56
#=CP#
CERTIFICATIONS
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Project:
92692736
CHEROKEE LINED MSWLF
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Utah Certification #: TN00003
Vermont Dept. of Health: ID# VT-2006
REPORT OF LABORATORY ANALYSIS
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Pace Analytical Services National
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Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
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Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
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REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Lab ID Sample ID Matrix Date Collected Date Received
92692736001 MW-BG Water 10/04/23 16:55 10/10/23 09:00
92692736002 MW-2 Water 10/04/23 15:00 10/10/23 09:00
92692736003 MW-3 Water 10/04/23 15:20 10/10/23 09:00
92692736004 MW-5 Water 10/03/23 14:08 10/10/23 09:00
92692736005 MW-6S Water 10/03/23 17:20 10/10/23 09:00
92692736006 MW-6D Water 10/03/23 17:00 10/10/23 09:00
92692736007 MW-7 Water 10/04/23 16:16 10/10/23 09:00
92692736008 MW-8 Water 10/03/23 14:50 10/10/23 09:00
92692736009 MW-9 Water 10/03/23 14:38 10/10/23 09:00
92692736010 P-17 Water 10/03/23 15:16 10/10/23 09:00
92692736011 P-18 Water 10/03/23 00:00 10/10/23 09:00
92692736012 MW-4 Water 10/04/23 00:00 10/10/23 09:00
92692736013 P-19 Water 10/03/23 00:00 10/10/23 09:00
92692736014 P-21 Water 10/03/23 00:00 10/10/23 09:00
92692736015 LEACHATE Water 10/03/23 00:00 10/10/23 09:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 4 of 56
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92692736001 MW-BG EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736002 MW-2 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736003 MW-3 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736004 MW-5 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
92692736005 MW-6S EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736006 MW-6D EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736007 MW-7 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736008 MW-8 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736009 MW-9 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736010 P-17 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736011 P-18 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736012 MW-4 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D by SIM 2 PANDWR
EPA 8260D 50 PASI-CLMB
92692736013 P-19 EPA 6010 15 PASI-OAAM1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 5 of 56
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736014 P-21 EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D 50 PASI-CLMB
92692736015 LEACHATE EPA 6010 15 PASI-OAAM1
EPA 7470 1 PASI-OJNK
EPA 8260D by SIM 2 PANAV
EPA 8260D 50 PASI-CLMB
SM 4500-S2D-2011 1 PASI-AJP1
EPA 365.1 Rev 2.0 1993 1 PASI-AZJP
SM 5220D-2011 1 PASI-AJP1
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 6 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-BG Lab ID:92692736001 Collected:10/04/23 16:55 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:37 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:37 7440-38-210/18/23 01:1810.0 3.4 1
Barium 30.7 ug/L 10/18/23 12:37 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 0.25J ug/L 10/18/23 12:37 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 12:37 7440-43-910/18/23 01:181.0 0.33 1
Chromium 6.0 ug/L 10/18/23 12:37 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 1.9J ug/L 10/18/23 12:37 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 12:37 7440-50-810/18/23 01:185.0 2.6 1
Lead 4.1J ug/L 10/18/23 12:37 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 5.0J ug/L 10/18/23 12:37 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:37 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 12:37 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:37 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 9.0J ug/L 10/18/23 12:37 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:37 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 11:57 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 14:10 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 14:10 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 14:10 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 14:10 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 14:10 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 14:10 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 14:10 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 14:10 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 14:10 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 14:10 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 14:10 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 14:10 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 14:10 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 14:10 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 14:10 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 14:10 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 14:10 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 14:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 14:10 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 14:10 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 14:10 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 14:10 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 14:10 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
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Page 7 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-BG Lab ID:92692736001 Collected:10/04/23 16:55 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 14:10 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 14:10 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 14:10 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 14:10 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 14:10 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 14:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 14:10 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 14:10 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 14:10 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 14:10 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 14:10 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 14:10 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 14:10 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 14:10 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 14:10 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 14:10 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 14:10 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 14:10 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 14:10 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 14:10 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 14:10 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 14:10 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 14:10 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 14:10 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %10/12/23 14:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 14:10 17060-07-070-130 1
Toluene-d8 (S)98 %10/12/23 14:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-2 Lab ID:92692736002 Collected:10/04/23 15:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:40 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:40 7440-38-210/18/23 01:1810.0 3.4 1
Barium 119 ug/L 10/18/23 12:40 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 12:40 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 12:40 7440-43-910/18/23 01:181.0 0.33 1
Chromium 2.2J ug/L 10/18/23 12:40 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 1.6J ug/L 10/18/23 12:40 7440-48-410/18/23 01:1810.0 0.96 1
Copper 3.9J ug/L 10/18/23 12:40 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 12:40 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 2.3J ug/L 10/18/23 12:40 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:40 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 12:40 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:40 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 1.9J ug/L 10/18/23 12:40 7440-62-210/18/23 01:1810.0 1.0 1
Zinc 37.4 ug/L 10/18/23 12:40 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 11:59 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 14:28 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 14:28 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 14:28 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 14:28 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 14:28 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 14:28 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 14:28 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 14:28 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 14:28 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 14:28 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 14:28 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 14:28 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 14:28 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 14:28 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 14:28 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 14:28 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 14:28 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 14:28 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 14:28 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 14:28 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 14:28 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 14:28 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 14:28 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-2 Lab ID:92692736002 Collected:10/04/23 15:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 14:28 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 14:28 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 14:28 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 14:28 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 14:28 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 14:28 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 14:28 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 14:28 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 14:28 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 14:28 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 14:28 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 14:28 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 14:28 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 14:28 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 14:28 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 14:28 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 14:28 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 14:28 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 14:28 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 14:28 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 14:28 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 14:28 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 14:28 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 14:28 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)100 %10/12/23 14:28 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 14:28 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 14:28 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-3 Lab ID:92692736003 Collected:10/04/23 15:20 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:44 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:44 7440-38-210/18/23 01:1810.0 3.4 1
Barium 18.4 ug/L 10/18/23 12:44 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 12:44 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 12:44 7440-43-910/18/23 01:181.0 0.33 1
Chromium 2.7J ug/L 10/18/23 12:44 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 1.2J ug/L 10/18/23 12:44 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 12:44 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 12:44 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 12:44 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:44 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 12:44 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:44 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 1.3J ug/L 10/18/23 12:44 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:44 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:02 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 14:46 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 14:46 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 14:46 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 14:46 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 14:46 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 14:46 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 14:46 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 14:46 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 14:46 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 14:46 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 14:46 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 14:46 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 14:46 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 14:46 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 14:46 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 14:46 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 14:46 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 14:46 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 14:46 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 14:46 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 14:46 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 14:46 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 14:46 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-3 Lab ID:92692736003 Collected:10/04/23 15:20 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 14:46 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 14:46 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 14:46 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 14:46 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 14:46 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 14:46 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 14:46 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 14:46 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 14:46 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 14:46 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 14:46 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 14:46 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 14:46 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 14:46 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 14:46 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 14:46 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 14:46 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 14:46 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 14:46 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 14:46 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 14:46 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 14:46 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 14:46 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 14:46 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)96 %10/12/23 14:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 14:46 17060-07-070-130 1
Toluene-d8 (S)101 %10/12/23 14:46 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-5 Lab ID:92692736004 Collected:10/03/23 14:08 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:48 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:48 7440-38-210/18/23 01:1810.0 3.4 1
Barium 29.6 ug/L 10/18/23 12:48 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 12:48 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 0.45J ug/L 10/18/23 12:48 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 12:48 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 4.8J ug/L 10/18/23 12:48 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 12:48 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 12:48 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 5.2 ug/L 10/18/23 12:48 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:48 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 12:48 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:48 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 1.3J ug/L 10/18/23 12:48 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:48 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:04 7439-97-610/23/23 15:310.20 0.14 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-6S Lab ID:92692736005 Collected:10/03/23 17:20 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:52 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:52 7440-38-210/18/23 01:1810.0 3.4 1
Barium 138 ug/L 10/18/23 12:52 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 1.1J ug/L 10/18/23 12:52 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 1.2 ug/L 10/18/23 12:52 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 12:52 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 1.3J ug/L 10/18/23 12:52 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/24/23 09:40 7440-50-8 D310/18/23 01:1810.0 5.2 2
Lead ND ug/L 10/18/23 12:52 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 12:52 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:52 7782-49-210/18/23 01:1815.0 3.9 1
Silver 1.2J ug/L 10/18/23 12:52 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:52 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 12:52 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:52 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:06 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 15:04 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 15:04 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 15:04 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 15:04 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 15:04 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 15:04 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 15:04 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 15:04 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 15:04 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 15:04 56-23-51.0 0.33 1
Chlorobenzene 1.1 ug/L 10/12/23 15:04 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 15:04 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 15:04 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 15:04 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 15:04 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 15:04 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 15:04 95-50-11.0 0.34 1
1,4-Dichlorobenzene 2.9 ug/L 10/12/23 15:04 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 15:04 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 15:04 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 15:04 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 15:04 75-35-41.0 0.35 1
cis-1,2-Dichloroethene 0.96J ug/L 10/12/23 15:04 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-6S Lab ID:92692736005 Collected:10/03/23 17:20 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 15:04 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 15:04 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 15:04 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 15:04 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 15:04 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 15:04 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 15:04 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 15:04 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 15:04 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 15:04 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 15:04 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 15:04 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 15:04 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 15:04 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 15:04 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 15:04 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 15:04 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 15:04 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 15:04 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 15:04 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 15:04 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 15:04 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 15:04 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 15:04 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %10/12/23 15:04 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %10/12/23 15:04 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 15:04 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-6D Lab ID:92692736006 Collected:10/03/23 17:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:55 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:55 7440-38-210/18/23 01:1810.0 3.4 1
Barium 2.3J ug/L 10/18/23 12:55 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 12:55 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 0.34J ug/L 10/18/23 12:55 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 12:55 7440-47-310/18/23 01:185.0 1.7 1
Cobalt ND ug/L 10/18/23 12:55 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 12:55 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 12:55 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 12:55 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:55 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 12:55 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:55 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 12:55 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:55 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:13 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 15:21 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 15:21 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 15:21 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 15:21 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 15:21 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 15:21 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 15:21 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 15:21 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 15:21 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 15:21 56-23-51.0 0.33 1
Chlorobenzene 0.53J ug/L 10/12/23 15:21 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 15:21 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 15:21 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 15:21 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 15:21 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 15:21 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 15:21 95-50-11.0 0.34 1
1,4-Dichlorobenzene 2.2 ug/L 10/12/23 15:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 15:21 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 15:21 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 15:21 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 15:21 75-35-41.0 0.35 1
cis-1,2-Dichloroethene 1.2 ug/L 10/12/23 15:21 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-6D Lab ID:92692736006 Collected:10/03/23 17:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 15:21 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 15:21 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 15:21 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 15:21 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 15:21 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 15:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 15:21 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 15:21 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 15:21 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 15:21 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 15:21 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 15:21 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 15:21 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 15:21 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 15:21 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 15:21 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 15:21 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 15:21 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 15:21 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 15:21 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 15:21 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 15:21 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 15:21 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 15:21 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %10/12/23 15:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %10/12/23 15:21 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 15:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-7 Lab ID:92692736007 Collected:10/04/23 16:16 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 12:59 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 12:59 7440-38-210/18/23 01:1810.0 3.4 1
Barium 22.6 ug/L 10/18/23 12:59 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 0.66J ug/L 10/18/23 12:59 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 0.80J ug/L 10/18/23 12:59 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 12:59 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 32.8 ug/L 10/18/23 12:59 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 12:59 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 12:59 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 12:59 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 12:59 7782-49-210/18/23 01:1815.0 3.9 1
Silver 1.6J ug/L 10/18/23 12:59 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 12:59 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 12:59 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 12:59 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:15 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone 24.6J ug/L 10/12/23 15:39 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 15:39 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 15:39 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 15:39 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 15:39 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 15:39 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 15:39 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 15:39 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 15:39 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 15:39 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 15:39 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 15:39 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 15:39 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 15:39 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 15:39 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 15:39 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 15:39 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 15:39 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 15:39 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 15:39 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 15:39 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 15:39 75-35-41.0 0.35 1
cis-1,2-Dichloroethene 1.3 ug/L 10/12/23 15:39 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-7 Lab ID:92692736007 Collected:10/04/23 16:16 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 15:39 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 15:39 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 15:39 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 15:39 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 15:39 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 15:39 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 15:39 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 15:39 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 15:39 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 15:39 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 15:39 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 15:39 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 15:39 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 15:39 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 15:39 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 15:39 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 15:39 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 15:39 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 15:39 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 15:39 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 15:39 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 15:39 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 15:39 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 15:39 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)100 %10/12/23 15:39 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %10/12/23 15:39 17060-07-070-130 1
Toluene-d8 (S)99 %10/12/23 15:39 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-8 Lab ID:92692736008 Collected:10/03/23 14:50 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:03 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:03 7440-38-210/18/23 01:1810.0 3.4 1
Barium 1.9J ug/L 10/18/23 13:03 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 13:03 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 13:03 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:03 7440-47-310/18/23 01:185.0 1.7 1
Cobalt ND ug/L 10/18/23 13:03 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:03 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:03 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 13:03 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:03 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:03 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:03 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 1.3J ug/L 10/18/23 13:03 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:03 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:18 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 15:57 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 15:57 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 15:57 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 15:57 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 15:57 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 15:57 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 15:57 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 15:57 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 15:57 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 15:57 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 15:57 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 15:57 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 15:57 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 15:57 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 15:57 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 15:57 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 15:57 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 15:57 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 15:57 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 15:57 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 15:57 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 15:57 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 15:57 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-8 Lab ID:92692736008 Collected:10/03/23 14:50 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 15:57 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 15:57 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 15:57 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 15:57 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 15:57 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 15:57 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 15:57 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 15:57 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 15:57 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 15:57 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 15:57 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 15:57 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 15:57 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 15:57 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 15:57 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 15:57 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 15:57 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 15:57 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 15:57 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 15:57 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 15:57 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 15:57 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 15:57 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 15:57 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %10/12/23 15:57 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 15:57 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 15:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-9 Lab ID:92692736009 Collected:10/03/23 14:38 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:07 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:07 7440-38-210/18/23 01:1810.0 3.4 1
Barium 4.7J ug/L 10/18/23 13:07 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 13:07 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 13:07 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:07 7440-47-310/18/23 01:185.0 1.7 1
Cobalt ND ug/L 10/18/23 13:07 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:07 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:07 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 13:07 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:07 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:07 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:07 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 13:07 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:07 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:20 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 16:14 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 16:14 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 16:14 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 16:14 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 16:14 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 16:14 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 16:14 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 16:14 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 16:14 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 16:14 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 16:14 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 16:14 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 16:14 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 16:14 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 16:14 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 16:14 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 16:14 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 16:14 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 16:14 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 16:14 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 16:14 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 16:14 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 16:14 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-9 Lab ID:92692736009 Collected:10/03/23 14:38 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 16:14 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 16:14 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 16:14 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 16:14 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 16:14 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 16:14 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 16:14 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 16:14 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 16:14 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 16:14 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 16:14 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 16:14 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 16:14 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 16:14 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 16:14 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 16:14 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 16:14 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 16:14 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 16:14 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 16:14 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 16:14 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 16:14 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 16:14 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 16:14 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)99 %10/12/23 16:14 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %10/12/23 16:14 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 16:14 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-17 Lab ID:92692736010 Collected:10/03/23 15:16 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:10 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:10 7440-38-210/18/23 01:1810.0 3.4 1
Barium 7.1J ug/L 10/18/23 13:10 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 13:10 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 13:10 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:10 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 4.0J ug/L 10/18/23 13:10 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:10 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:10 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 13:10 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:10 7782-49-210/18/23 01:1815.0 3.9 1
Silver 1.0J ug/L 10/18/23 13:10 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:10 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 13:10 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:10 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:22 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 16:32 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 16:32 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 16:32 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 16:32 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 16:32 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 16:32 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 16:32 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 16:32 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 16:32 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 16:32 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 16:32 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 16:32 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 16:32 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 16:32 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 16:32 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 16:32 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 16:32 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 16:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 16:32 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 16:32 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 16:32 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 16:32 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 16:32 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-17 Lab ID:92692736010 Collected:10/03/23 15:16 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 16:32 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 16:32 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 16:32 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 16:32 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 16:32 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 16:32 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 16:32 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 16:32 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 16:32 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 16:32 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 16:32 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 16:32 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 16:32 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 16:32 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 16:32 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 16:32 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 16:32 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 16:32 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 16:32 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 16:32 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 16:32 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 16:32 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 16:32 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 16:32 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %10/12/23 16:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %10/12/23 16:32 17060-07-070-130 1
Toluene-d8 (S)98 %10/12/23 16:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-18 Lab ID:92692736011 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:22 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:22 7440-38-210/18/23 01:1810.0 3.4 1
Barium 40.3 ug/L 10/18/23 13:22 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 0.29J ug/L 10/18/23 13:22 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 1.6 ug/L 10/18/23 13:22 7440-43-910/18/23 01:181.0 0.33 1
Chromium 4.7J ug/L 10/18/23 13:22 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 6.2J ug/L 10/18/23 13:22 7440-48-410/18/23 01:1810.0 0.96 1
Copper 67.2 ug/L 10/18/23 13:22 7440-50-810/18/23 01:185.0 2.6 1
Lead 8.2J ug/L 10/18/23 13:22 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 7.3 ug/L 10/18/23 13:22 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:22 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:22 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:22 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 6.1J ug/L 10/18/23 13:22 7440-62-210/18/23 01:1810.0 1.0 1
Zinc 123 ug/L 10/18/23 13:22 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:25 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 16:50 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 16:50 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 16:50 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 16:50 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 16:50 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 16:50 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 16:50 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 16:50 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 16:50 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 16:50 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 16:50 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 16:50 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 16:50 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 16:50 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 16:50 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 16:50 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 16:50 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 16:50 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 16:50 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 16:50 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 16:50 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 16:50 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 16:50 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-18 Lab ID:92692736011 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 16:50 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 16:50 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 16:50 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 16:50 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 16:50 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 16:50 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 16:50 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 16:50 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 16:50 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 16:50 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 16:50 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 16:50 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 16:50 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 16:50 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 16:50 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 16:50 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 16:50 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 16:50 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 16:50 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 16:50 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 16:50 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 16:50 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 16:50 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 16:50 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %10/12/23 16:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 16:50 17060-07-070-130 1
Toluene-d8 (S)101 %10/12/23 16:50 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-4 Lab ID:92692736012 Collected:10/04/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:26 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:26 7440-38-210/18/23 01:1810.0 3.4 1
Barium 39.0 ug/L 10/18/23 13:26 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 0.18J ug/L 10/18/23 13:26 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 0.46J ug/L 10/18/23 13:26 7440-43-910/18/23 01:181.0 0.33 1
Chromium 3.5J ug/L 10/18/23 13:26 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 7.3J ug/L 10/18/23 13:26 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:26 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:26 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 5.0J ug/L 10/18/23 13:26 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:26 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:26 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:26 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium 2.1J ug/L 10/18/23 13:26 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:26 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:27 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)1.58J ug/L 10/20/23 21:27 123-91-1 H3,J10/20/23 21:273.00 0.597 1
Surrogates
Toluene-d8 (S)98.0 %10/20/23 21:27 2037-26-510/20/23 21:2777.0-127 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 17:08 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 17:08 107-13-110.0 1.8 1
Benzene 2.5 ug/L 10/12/23 17:08 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 17:08 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 17:08 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 17:08 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 17:08 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 17:08 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 17:08 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 17:08 56-23-51.0 0.33 1
Chlorobenzene 2.5 ug/L 10/12/23 17:08 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 17:08 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 17:08 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 17:08 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 17:08 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 17:08 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 17:08 95-50-11.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:MW-4 Lab ID:92692736012 Collected:10/04/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dichlorobenzene 0.77J ug/L 10/12/23 17:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 17:08 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 17:08 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 17:08 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 17:08 75-35-41.0 0.35 1
cis-1,2-Dichloroethene 0.41J ug/L 10/12/23 17:08 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/12/23 17:08 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 17:08 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 17:08 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 17:08 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 17:08 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 17:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 17:08 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 17:08 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 17:08 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 17:08 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 17:08 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 17:08 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 17:08 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 17:08 127-18-41.0 0.29 1
Tetrahydrofuran 7.3J ug/L 10/12/23 17:08 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 17:08 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 17:08 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 17:08 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 17:08 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 17:08 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 17:08 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 17:08 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 17:08 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 17:08 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %10/12/23 17:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %10/12/23 17:08 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 17:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-19 Lab ID:92692736013 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:29 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:29 7440-38-210/18/23 01:1810.0 3.4 1
Barium 12.9 ug/L 10/18/23 13:29 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 13:29 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 13:29 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:29 7440-47-310/18/23 01:185.0 1.7 1
Cobalt 3.1J ug/L 10/18/23 13:29 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:29 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:29 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 13:29 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:29 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:29 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:29 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 13:29 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:29 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:29 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 17:26 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 17:26 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 17:26 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 17:26 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 17:26 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 17:26 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 17:26 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 17:26 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 17:26 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 17:26 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 17:26 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 17:26 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 17:26 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 17:26 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 17:26 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 17:26 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 17:26 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 17:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 17:26 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 17:26 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 17:26 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 17:26 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 17:26 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-19 Lab ID:92692736013 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 17:26 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 17:26 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 17:26 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 17:26 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 17:26 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 17:26 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 17:26 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 17:26 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 17:26 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 17:26 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 17:26 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 17:26 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 17:26 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 17:26 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 17:26 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 17:26 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 17:26 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 17:26 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 17:26 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 17:26 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 17:26 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 17:26 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 17:26 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 17:26 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)98 %10/12/23 17:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %10/12/23 17:26 17060-07-070-130 1
Toluene-d8 (S)101 %10/12/23 17:26 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-21 Lab ID:92692736014 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:33 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:33 7440-38-210/18/23 01:1810.0 3.4 1
Barium 14.3 ug/L 10/18/23 13:33 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium ND ug/L 10/18/23 13:33 7440-41-710/18/23 01:184.0 0.17 1
Cadmium ND ug/L 10/18/23 13:33 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:33 7440-47-310/18/23 01:185.0 1.7 1
Cobalt ND ug/L 10/18/23 13:33 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:33 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:33 7439-92-110/18/23 01:1810.0 2.1 1
Nickel ND ug/L 10/18/23 13:33 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:33 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:33 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:33 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 13:33 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:33 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:31 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 17:43 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 17:43 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 17:43 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 17:43 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 17:43 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 17:43 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 17:43 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 17:43 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 17:43 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 17:43 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/12/23 17:43 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 17:43 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 17:43 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 17:43 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 17:43 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 17:43 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 17:43 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/12/23 17:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 17:43 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 17:43 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 17:43 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 17:43 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 17:43 156-59-21.0 0.38 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:P-21 Lab ID:92692736014 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
trans-1,2-Dichloroethene ND ug/L 10/12/23 17:43 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 17:43 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 17:43 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 17:43 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 17:43 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 17:43 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 17:43 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 17:43 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 17:43 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 17:43 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 17:43 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 17:43 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 17:43 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 17:43 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 17:43 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 17:43 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 17:43 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 17:43 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 17:43 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 17:43 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 17:43 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 17:43 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 17:43 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 17:43 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)100 %10/12/23 17:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %10/12/23 17:43 17060-07-070-130 1
Toluene-d8 (S)99 %10/12/23 17:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:LEACHATE Lab ID:92692736015 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6010 MET ICP
Antimony ND ug/L 10/18/23 13:37 7440-36-010/18/23 01:1815.0 5.5 1
Arsenic ND ug/L 10/18/23 13:37 7440-38-210/18/23 01:1810.0 3.4 1
Barium 461 ug/L 10/18/23 13:37 7440-39-310/18/23 01:1810.0 0.84 1
Beryllium 0.56J ug/L 10/18/23 13:37 7440-41-710/18/23 01:184.0 0.17 1
Cadmium 0.76J ug/L 10/18/23 13:37 7440-43-910/18/23 01:181.0 0.33 1
Chromium ND ug/L 10/18/23 13:37 7440-47-310/18/23 01:185.0 1.7 1
Cobalt ND ug/L 10/18/23 13:37 7440-48-410/18/23 01:1810.0 0.96 1
Copper ND ug/L 10/18/23 13:37 7440-50-810/18/23 01:185.0 2.6 1
Lead ND ug/L 10/18/23 13:37 7439-92-110/18/23 01:1810.0 2.1 1
Nickel 6.0 ug/L 10/18/23 13:37 7440-02-010/18/23 01:185.0 1.0 1
Selenium ND ug/L 10/18/23 13:37 7782-49-210/18/23 01:1815.0 3.9 1
Silver ND ug/L 10/18/23 13:37 7440-22-410/18/23 01:185.0 1.0 1
Thallium ND ug/L 10/18/23 13:37 7440-28-010/18/23 01:1815.0 2.9 1
Vanadium ND ug/L 10/18/23 13:37 7440-62-210/18/23 01:1810.0 1.0 1
Zinc ND ug/L 10/18/23 13:37 7440-66-610/18/23 01:1820.0 11.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Pace Analytical Services - Ormond Beach
7470 Mercury
Mercury ND ug/L 10/24/23 12:34 7439-97-610/23/23 15:310.20 0.14 1
Analytical Method: EPA 8260D by SIM Preparation Method: 8260D-SIM
Pace National - Mt. Juliet
VOA (GC/MS) 8260D-SIM
1,4-Dioxane (p-Dioxane)13.0 ug/L 10/17/23 11:52 123-91-110/17/23 11:523.00 0.597 1
Surrogates
Toluene-d8 (S)103 %10/17/23 11:52 2037-26-510/17/23 11:5277.0-127 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/12/23 18:01 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/12/23 18:01 107-13-110.0 1.8 1
Benzene ND ug/L 10/12/23 18:01 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/12/23 18:01 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/12/23 18:01 75-27-41.0 0.31 1
Bromoform ND ug/L 10/12/23 18:01 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/12/23 18:01 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/12/23 18:01 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/12/23 18:01 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/12/23 18:01 56-23-51.0 0.33 1
Chlorobenzene 0.44J ug/L 10/12/23 18:01 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/12/23 18:01 75-00-31.0 0.65 1
Chloroform ND ug/L 10/12/23 18:01 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/12/23 18:01 74-87-3 v21.0 0.54 1
Dibromochloromethane ND ug/L 10/12/23 18:01 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/12/23 18:01 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/12/23 18:01 95-50-11.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:LEACHATE Lab ID:92692736015 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dichlorobenzene ND ug/L 10/12/23 18:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/12/23 18:01 110-57-6 IH,v21.0 0.56 1
1,1-Dichloroethane ND ug/L 10/12/23 18:01 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/12/23 18:01 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/12/23 18:01 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/12/23 18:01 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/12/23 18:01 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/12/23 18:01 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/12/23 18:01 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/12/23 18:01 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/12/23 18:01 123-91-115038.7 1
Ethylbenzene ND ug/L 10/12/23 18:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/12/23 18:01 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/12/23 18:01 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/12/23 18:01 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/12/23 18:01 108-10-15.0 2.7 1
Styrene ND ug/L 10/12/23 18:01 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/12/23 18:01 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/12/23 18:01 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/12/23 18:01 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/12/23 18:01 109-99-910.0 3.5 1
Toluene ND ug/L 10/12/23 18:01 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/12/23 18:01 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/12/23 18:01 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/12/23 18:01 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/12/23 18:01 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/12/23 18:01 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/12/23 18:01 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/12/23 18:01 75-01-4 v21.0 0.39 1
Xylene (Total)ND ug/L 10/12/23 18:01 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)101 %10/12/23 18:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %10/12/23 18:01 17060-07-070-130 1
Toluene-d8 (S)100 %10/12/23 18:01 2037-26-570-130 1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services - Asheville
4500S2D Sulfide Water
Sulfide ND mg/L 10/13/23 02:59 18496-25-8 H10.10 0.022 1
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
365.1 Phosphorus, Total
Phosphorus 0.071 mg/L 10/23/23 14:22 7723-14-010/20/23 18:470.050 0.025 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Sample:LEACHATE Lab ID:92692736015 Collected:10/03/23 00:00 Received:10/10/23 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services - Asheville
5220D COD
Chemical Oxygen Demand 110 mg/L 10/19/23 23:5710/19/23 03:1925.0 12.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
960352
EPA 7470
EPA 7470
7470 Mercury
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736004, 92692736005, 92692736006, 92692736007,
92692736008, 92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014,
92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5281530
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736004, 92692736005, 92692736006, 92692736007,
92692736008, 92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014,
92692736015
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 10/24/23 11:320.14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5281531LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 1.92 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5281532MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35833402002
5281533
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2 94 75-12594 0 2020.14U 1.9 1.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
958938
EPA 3010
EPA 6010
6010 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736004, 92692736005, 92692736006, 92692736007,
92692736008, 92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014,
92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5273616
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736004, 92692736005, 92692736006, 92692736007,
92692736008, 92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014,
92692736015
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 15.0 10/18/23 11:515.5
Arsenic ug/L ND 10.0 10/18/23 11:513.4
Barium ug/L ND 10.0 10/18/23 11:510.84
Beryllium ug/L ND 4.0 10/18/23 11:510.17
Cadmium ug/L ND 1.0 10/18/23 11:510.33
Chromium ug/L ND 5.0 10/18/23 11:511.7
Cobalt ug/L ND 10.0 10/18/23 11:510.96
Copper ug/L ND 5.0 10/18/23 11:512.6
Lead ug/L ND 10.0 10/18/23 11:512.1
Nickel ug/L ND 5.0 10/18/23 11:511.0
Selenium ug/L ND 15.0 10/18/23 11:513.9
Silver ug/L ND 5.0 10/18/23 11:511.0
Thallium ug/L ND 15.0 10/18/23 11:512.9
Vanadium ug/L ND 10.0 10/18/23 11:511.0
Zinc ug/L ND 20.0 10/18/23 11:5111.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5273617LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 255250 102 80-120
Arsenic ug/L 242250 97 80-120
Barium ug/L 253250 101 80-120
Beryllium ug/L 24.625 98 80-120
Cadmium ug/L 25.725 103 80-120
Chromium ug/L 252250 101 80-120
Cobalt ug/L 255250 102 80-120
Copper ug/L 246250 98 80-120
Lead ug/L 259250 103 80-120
Nickel ug/L 260250 104 80-120
Selenium ug/L 257250 103 80-120
Silver ug/L 25.025 100 80-120
Thallium ug/L 261250 104 80-120
Vanadium ug/L 249250 100 80-120
Zinc ug/L 12901250 103 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5273618MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35834137025
5273619
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 250 100 75-125101 1 202505.5U 252 253
Arsenic ug/L 250 97 75-12597 0 202503.4U 245 245
Barium ug/L 250 101 75-125102 0 2025026.7 280 281
Beryllium ug/L 25 98 75-12598 0 20250.17U 24.5 24.6
Cadmium ug/L 25 103 75-125104 0 20250.33U 25.9 26.0
Chromium ug/L 250 100 75-125101 0 202502.1J 252 253
Cobalt ug/L 250 102 75-125102 0 202500.96U 255 256
Copper ug/L 250 98 75-12598 0 2025011.9 256 257
Lead ug/L 250 103 75-125103 0 202502.1U 258 258
Nickel ug/L 250 103 75-125103 0 202501.0J 259 260
Selenium ug/L 250 100 75-125101 1 202503.9U 251 253
Silver ug/L 25 98 75-12598 0 20251.0U 24.6 24.5
Thallium ug/L 250 103 75-125103 1 202502.9U 259 256
Vanadium ug/L 250 99 75-125100 1 202501.1J 250 251
Zinc ug/L 1250 102 75-125103 0 20125088.7 1370 1370
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2152651
8260B-SIM
EPA 8260D by SIM
VOA (GC/MS) 8260D-SIM
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3987363-3
Associated Lab Samples:92692736015
Matrix:Water
AnalyzedMDL
1,4-Dioxane (p-Dioxane)ug/L ND 3.00 10/17/23 11:310.597
Toluene-d8 (S)%97.4 77.0-127 10/17/23 11:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3987363-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3987363-2
1,4-Dioxane (p-Dioxane)ug/L 47.750.0 95.4 55.0-13893.646.8 1.90 24
Toluene-d8 (S)%97.9 77.0-12797.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R3987363-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1663807-01
R3987363-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 50.0 110 13.0-160111 1.09 3150.0ND 54.9 55.5
Toluene-d8 (S)%97.7 77.0-12797.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2155244
8260B-SIM
EPA 8260D by SIM
VOA (GC/MS) 8260D-SIM
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92692736012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3989912-3
Associated Lab Samples:92692736012
Matrix:Water
AnalyzedMDL
1,4-Dioxane (p-Dioxane)ug/L ND 3.00 10/20/23 14:120.597
Toluene-d8 (S)%99.6 77.0-127 10/20/23 14:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3989912-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3989912-2
1,4-Dioxane (p-Dioxane)ug/L 46.950.0 93.8 55.0-13888.244.1 6.15 24
Toluene-d8 (S)%98.9 77.0-12798.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R3989912-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
L1667585-05
R3989912-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,4-Dioxane (p-Dioxane)ug/L 50.0 99.2 13.0-16097.8 1.42 3150.0ND 49.6 48.9
Toluene-d8 (S)%97.8 77.0-12798.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 41 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
805863
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736005, 92692736006, 92692736007, 92692736008,
92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014, 92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4172976
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736005, 92692736006, 92692736007, 92692736008,
92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014, 92692736015
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 10/12/23 12:240.31
1,1,1-Trichloroethane ug/L ND 1.0 10/12/23 12:240.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 10/12/23 12:240.22
1,1,2-Trichloroethane ug/L ND 1.0 10/12/23 12:240.32
1,1-Dichloroethane ug/L ND 1.0 10/12/23 12:240.37
1,1-Dichloroethene ug/L ND 1.0 10/12/23 12:240.35
1,2,3-Trichloropropane ug/L ND 1.0 10/12/23 12:240.26
1,2-Dichlorobenzene ug/L ND 1.0 10/12/23 12:240.34
1,2-Dichloroethane ug/L ND 1.0 10/12/23 12:240.32
1,2-Dichloropropane ug/L ND 1.0 10/12/23 12:240.36
1,4-Dichlorobenzene ug/L ND 1.0 10/12/23 12:240.33
1,4-Dioxane (p-Dioxane)ug/L ND 150 10/12/23 12:2438.7
2-Butanone (MEK)ug/L ND 5.0 10/12/23 12:244.0
2-Hexanone ug/L ND 5.0 10/12/23 12:240.48
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 10/12/23 12:242.7
Acetone ug/L ND 25.0 10/12/23 12:245.1
Acrylonitrile ug/L ND 10.0 10/12/23 12:241.8
Benzene ug/L ND 1.0 10/12/23 12:240.34
Bromochloromethane ug/L ND 1.0 10/12/23 12:240.47
Bromodichloromethane ug/L ND 1.0 10/12/23 12:240.31
Bromoform ug/L ND 1.0 10/12/23 12:240.34
Bromomethane ug/L ND 2.0 v210/12/23 12:241.7
Carbon disulfide ug/L ND 2.0 10/12/23 12:240.36
Carbon tetrachloride ug/L ND 1.0 10/12/23 12:240.33
Chlorobenzene ug/L ND 1.0 10/12/23 12:240.28
Chloroethane ug/L ND 1.0 10/12/23 12:240.65
Chloroform ug/L ND 1.0 10/12/23 12:240.43
Chloromethane ug/L ND 1.0 v210/12/23 12:240.54
cis-1,2-Dichloroethene ug/L ND 1.0 10/12/23 12:240.38
cis-1,3-Dichloropropene ug/L ND 1.0 10/12/23 12:240.36
Dibromochloromethane ug/L ND 1.0 10/12/23 12:240.36
Dibromomethane ug/L ND 1.0 10/12/23 12:240.39
Ethylbenzene ug/L ND 1.0 10/12/23 12:240.30
Iodomethane ug/L ND 20.0 10/12/23 12:249.7
Methylene Chloride ug/L ND 5.0 10/12/23 12:242.0
Styrene ug/L ND 1.0 10/12/23 12:240.29
Tetrachloroethene ug/L ND 1.0 10/12/23 12:240.29
Tetrahydrofuran ug/L ND 10.0 10/12/23 12:243.5
Toluene ug/L ND 1.0 10/12/23 12:240.24
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 42 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4172976
Associated Lab Samples:92692736001, 92692736002, 92692736003, 92692736005, 92692736006, 92692736007, 92692736008,
92692736009, 92692736010, 92692736011, 92692736012, 92692736013, 92692736014, 92692736015
Matrix:Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 1.0 10/12/23 12:240.40
trans-1,3-Dichloropropene ug/L ND 1.0 10/12/23 12:240.36
trans-1,4-Dichloro-2-butene ug/L ND 1.0 IH,v210/12/23 12:240.56
Trichloroethene ug/L ND 1.0 10/12/23 12:240.38
Trichlorofluoromethane ug/L ND 1.0 10/12/23 12:240.30
Vinyl acetate ug/L ND 2.0 10/12/23 12:241.3
Vinyl chloride ug/L ND 1.0 v210/12/23 12:240.39
Xylene (Total)ug/L ND 1.0 10/12/23 12:240.34
1,2-Dichloroethane-d4 (S)%101 70-130 10/12/23 12:24
4-Bromofluorobenzene (S)%99 70-130 10/12/23 12:24
Toluene-d8 (S)%99 70-130 10/12/23 12:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4172977LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 18.820 94 70-130
1,1,1-Trichloroethane ug/L 18.820 94 70-130
1,1,2,2-Tetrachloroethane ug/L 18.820 94 70-130
1,1,2-Trichloroethane ug/L 18.620 93 70-130
1,1-Dichloroethane ug/L 17.620 88 70-130
1,1-Dichloroethene ug/L 18.220 91 69-131
1,2,3-Trichloropropane ug/L 17.520 87 70-130
1,2-Dichlorobenzene ug/L 19.420 97 70-130
1,2-Dichloroethane ug/L 18.520 92 70-130
1,2-Dichloropropane ug/L 17.920 90 70-130
1,4-Dichlorobenzene ug/L 18.420 92 70-130
1,4-Dioxane (p-Dioxane)ug/L 359400 90 70-132
2-Butanone (MEK)ug/L 34.540 86 67-133
2-Hexanone ug/L 37.540 94 70-133
4-Methyl-2-pentanone (MIBK)ug/L 36.340 91 70-130
Acetone ug/L 36.840 92 67-130
Acrylonitrile ug/L 85.9100 86 70-130
Benzene ug/L 17.820 89 70-130
Bromochloromethane ug/L 17.920 89 70-130
Bromodichloromethane ug/L 18.620 93 70-130
Bromoform ug/L 18.420 92 70-133
Bromomethane ug/L 12.3 v3206241-148
Carbon disulfide ug/L 16.620 83 70-131
Carbon tetrachloride ug/L 19.320 96 70-130
Chlorobenzene ug/L 18.220 91 70-130
Chloroethane ug/L 16.420 82 41-157
Chloroform ug/L 18.720 93 70-130
Chloromethane ug/L 15.7 v3207859-141
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4172977LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 17.620 88 70-130
cis-1,3-Dichloropropene ug/L 17.620 88 70-130
Dibromochloromethane ug/L 17.420 87 70-130
Dibromomethane ug/L 18.220 91 70-130
Ethylbenzene ug/L 18.520 93 70-130
Iodomethane ug/L 34.240 86 57-140
Methylene Chloride ug/L 17.820 89 62-130
Styrene ug/L 19.020 95 70-130
Tetrachloroethene ug/L 18.020 90 70-130
Tetrahydrofuran ug/L 171200 86 70-131
Toluene ug/L 18.020 90 70-130
trans-1,2-Dichloroethene ug/L 17.820 89 70-130
trans-1,3-Dichloropropene ug/L 18.420 92 70-130
trans-1,4-Dichloro-2-butene ug/L 15.1 IH,v3207657-149
Trichloroethene ug/L 18.520 93 70-130
Trichlorofluoromethane ug/L 18.720 93 57-130
Vinyl acetate ug/L 34.840 87 70-141
Vinyl chloride ug/L 14.4 v3207266-140
Xylene (Total)ug/L 56.860 95 70-130
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4172978MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692736001
4172979
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 107 70-146112 4 3020ND21.4 22.4
1,1,1-Trichloroethane ug/L 20 118 70-150119 2 3020ND23.5 23.9
1,1,2,2-Tetrachloroethane ug/L 20 105 66-144106 1 3020ND21.0 21.1
1,1,2-Trichloroethane ug/L 20 107 70-142114 7 3020ND21.3 22.8
1,1-Dichloroethane ug/L 20 107 68-150109 2 3020ND21.3 21.8
1,1-Dichloroethene ug/L 20 114 64-162116 1 3020ND22.9 23.2
1,2,3-Trichloropropane ug/L 20 99 66-144104 5 3020ND19.9 20.8
1,2-Dichlorobenzene ug/L 20 110 70-142110 0 3020ND22.0 22.0
1,2-Dichloroethane ug/L 20 109 68-145111 2 3020ND21.7 22.2
1,2-Dichloropropane ug/L 20 108 70-144113 5 3020ND21.6 22.7
1,4-Dichlorobenzene ug/L 20 104 70-140107 2 3020ND20.8 21.3
1,4-Dioxane (p-Dioxane)ug/L 400 108 66-151109 2 30400ND430438
2-Butanone (MEK)ug/L 40 103 57-156102 0 3040ND41.1 41.0
2-Hexanone ug/L 40 108 62-153109 2 3040ND43.1 43.7
4-Methyl-2-pentanone(MIBK)ug/L 40 108 65-144109 1 3040ND43.1 43.4
Acetone ug/L 40 102 49-162101 0 3040ND40.7 40.6
Acrylonitrile ug/L 100 101 59-155105 4 30100ND101105
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4172978MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692736001
4172979
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 107 68-144110 3 3020ND21.4 22.0
Bromochloromethane ug/L 20 108 70-148111 3 3020ND21.5 22.2
Bromodichloromethane ug/L 20 108 70-141113 4 3020ND21.7 22.6
Bromoform ug/L 20 106 59-144106 0 3020ND21.3 21.2
Bromomethane ug/L v3208423-19092 8 3020ND16.9 18.4
Carbon disulfide ug/L 20 108 64-160109 0 3020ND21.7 21.7
Carbon tetrachloride ug/L 20 127 70-147129 2 3020ND25.3 25.7
Chlorobenzene ug/L 20 107 70-143109 2 3020ND21.4 21.9
Chloroethane ug/L 20 100 55-190102 2 3020ND20.1 20.5
Chloroform ug/L 20 111 67-148115 4 3020ND22.1 23.0
Chloromethane ug/L 20 95 38-18095 0 3020ND19.0 19.0
cis-1,2-Dichloroethene ug/L 20 108 67-151108 0 3020ND21.6 21.6
cis-1,3-Dichloropropene ug/L 20 107 70-142110 3 3020ND21.4 22.0
Dibromochloromethane ug/L 20 107 68-140107 0 3020ND21.4 21.3
Dibromomethane ug/L 20 107 70-142116 9 3020ND21.3 23.3
Ethylbenzene ug/L 20 105 70-145109 4 3020ND20.9 21.7
Iodomethane ug/L 40 103 37-160102 1 3040ND41.1 40.8
Methylene Chloride ug/L 20 104 54-149107 3 3020ND20.8 21.5
Styrene ug/L 20 106 70-147108 2 3020ND21.3 21.6
Tetrachloroethene ug/L 20 111 70-145113 1 3020ND22.3 22.5
Tetrahydrofuran ug/L 200 103 48-160103 0 30200ND207206
Toluene ug/L 20 108 65-146109 1 3020ND21.6 21.8
trans-1,2-Dichloroethene ug/L 20 110 69-155110 0 3020ND22.0 22.1
trans-1,3-Dichloropropene ug/L 20 111 70-142117 4 3020ND22.3 23.3
trans-1,4-Dichloro-2-butene ug/L IH2010939-149109 0 3020ND21.9 21.8
Trichloroethene ug/L 20 115 70-152117 2 3020ND22.9 23.3
Trichlorofluoromethane ug/L 20 117 60-158118 1 3020ND23.5 23.7
Vinyl acetate ug/L 40 106 56-157108 3 3040ND42.2 43.3
Vinyl chloride ug/L 20 89 51-17892 3 3020ND17.8 18.4
Xylene (Total)ug/L 60 109 70-146110 1 3060ND65.5 65.9
1,2-Dichloroethane-d4 (S)%102 70-130106
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%102 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
806052
SM 4500-S2D-2011
SM 4500-S2D-2011
4500S2D Sulfide Water
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4174295
Associated Lab Samples:92692736015
Matrix:Water
AnalyzedMDL
Sulfide mg/L ND 0.10 10/13/23 02:580.022
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4174296LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.520.5 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4174297MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692818001
4174298
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L 0.5 104 80-120104 0 100.5ND 0.53 0.53
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4174299MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692818002
4174300
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L 0.5 105 80-120106 1 100.5ND 0.53 0.53
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
807870
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
365.1 Phosphorus, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4183303
Associated Lab Samples:92692736015
Matrix:Water
AnalyzedMDL
Phosphorus mg/L ND 0.050 10/23/23 14:110.025
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4183304LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus mg/L 2.62.5 106 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4183305MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692482001
4183306
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/L M12.5 -99 90-110-68 1 102.554.5 52.1 52.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4183307MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692482002
4183308
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/L M12.5 -23 90-11016 2 102.541.6 41.0 42.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
807436
SM 5220D-2011
SM 5220D-2011
5220D COD
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92692736015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4181121
Associated Lab Samples:92692736015
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand mg/L ND 25.0 10/19/23 23:5412.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4181122LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand mg/L 774750 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4181123MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692434001
4181124
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand mg/L R11009790-110102 4 310029.6 127 132
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4181125MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92692903004
4181126
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand mg/L M1,R11006490-11071 5 310065.1 129 136
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 56
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analysis conducted outside the EPA method holding time.H1
Sample was received or analysis requested beyond the recognized method holding time.H3
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs.J
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in theassociated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 56
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92692736001 958938 958947MW-BG EPA 3010 EPA 6010
92692736002 958938 958947MW-2 EPA 3010 EPA 6010
92692736003 958938 958947MW-3 EPA 3010 EPA 6010
92692736004 958938 958947MW-5 EPA 3010 EPA 6010
92692736005 958938 958947MW-6S EPA 3010 EPA 6010
92692736006 958938 958947MW-6D EPA 3010 EPA 6010
92692736007 958938 958947MW-7 EPA 3010 EPA 6010
92692736008 958938 958947MW-8 EPA 3010 EPA 6010
92692736009 958938 958947MW-9 EPA 3010 EPA 6010
92692736010 958938 958947P-17 EPA 3010 EPA 6010
92692736011 958938 958947P-18 EPA 3010 EPA 6010
92692736012 958938 958947MW-4 EPA 3010 EPA 6010
92692736013 958938 958947P-19 EPA 3010 EPA 6010
92692736014 958938 958947P-21 EPA 3010 EPA 6010
92692736015 958938 958947LEACHATEEPA 3010 EPA 6010
92692736001 960352 960427MW-BG EPA 7470 EPA 7470
92692736002 960352 960427MW-2 EPA 7470 EPA 7470
92692736003 960352 960427MW-3 EPA 7470 EPA 7470
92692736004 960352 960427MW-5 EPA 7470 EPA 7470
92692736005 960352 960427MW-6S EPA 7470 EPA 7470
92692736006 960352 960427MW-6D EPA 7470 EPA 7470
92692736007 960352 960427MW-7 EPA 7470 EPA 7470
92692736008 960352 960427MW-8 EPA 7470 EPA 7470
92692736009 960352 960427MW-9 EPA 7470 EPA 7470
92692736010 960352 960427P-17 EPA 7470 EPA 7470
92692736011 960352 960427P-18 EPA 7470 EPA 7470
92692736012 960352 960427MW-4 EPA 7470 EPA 7470
92692736013 960352 960427P-19 EPA 7470 EPA 7470
92692736014 960352 960427P-21 EPA 7470 EPA 7470
92692736015 960352 960427LEACHATEEPA 7470 EPA 7470
92692736012 2155244 2155244MW-4 8260D-SIM EPA 8260D by SIM
92692736015 2152651 2152651LEACHATE8260D-SIM EPA 8260D by SIM
92692736001 805863MW-BG EPA 8260D
92692736002 805863MW-2 EPA 8260D
92692736003 805863MW-3 EPA 8260D
92692736005 805863MW-6S EPA 8260D
92692736006 805863MW-6D EPA 8260D
92692736007 805863MW-7 EPA 8260D
92692736008 805863MW-8 EPA 8260D
92692736009 805863MW-9 EPA 8260D
92692736010 805863P-17 EPA 8260D
92692736011 805863P-18 EPA 8260D
92692736012 805863MW-4 EPA 8260D
92692736013 805863P-19 EPA 8260D
92692736014 805863P-21 EPA 8260D
92692736015 805863LEACHATEEPA 8260D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 56
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92692736
CHEROKEE LINED MSWLF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92692736015 806052LEACHATESM 4500-S2D-2011
92692736015 807870 808140LEACHATEEPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993
92692736015 807436 807722LEACHATESM 5220D-2011 SM 5220D-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/25/2023 09:40 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 56
Page 52 of 56
Page 53 of 56
Page 54 of 56
Page 55 of 56
Page 56 of 56
#=CL#
October 26, 2023
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92693361
92693361
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
CHEROKEE LF SW_BANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 13, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
704-977-0968
Enclosures
cc:Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 28
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
DoD-ANAB #:ADE-3199
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 28
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Lab ID Sample ID Matrix Date Collected Date Received
92693361001 SW-1 Water 10/06/23 09:30 10/13/23 15:45
92693361002 SW-2 Water 10/06/23 09:55 10/13/23 15:45
92693361003 SW-4 Water 10/06/23 11:00 10/13/23 15:45
92693361004 SW-5 Water 10/06/23 11:40 10/13/23 15:45
92693361005 EB Water 10/06/23 12:00 10/13/23 15:45
92693361006 FB Water 10/06/23 12:10 10/13/23 15:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 28
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92693361001 SW-1 EPA 6020 15 PASI-OEAP
EPA 8260D 50 PASI-CLMB
92693361002 SW-2 EPA 6020 15 PASI-OEAP
EPA 8260D 50 PASI-CLMB
92693361003 SW-4 EPA 6020 15 PASI-OEAP
EPA 8260D 50 PASI-CLMB
92693361004 SW-5 EPA 6020 15 PASI-OEAP
EPA 8260D 50 PASI-CLMB
92693361005 EB EPA 6020 15 PASI-OEAP
EPA 8260D 50 PASI-CLMB
92693361006 FB EPA 8260D 50 PASI-CLMB
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-1 Lab ID:92693361001 Collected:10/06/23 09:30 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Antimony ND ug/L 10/25/23 14:34 7440-36-010/25/23 04:401.0 0.50 1
Arsenic ND ug/L 10/25/23 14:34 7440-38-210/25/23 04:401.0 0.50 1
Barium 7.2 ug/L 10/25/23 14:34 7440-39-310/25/23 04:401.0 0.50 1
Beryllium ND ug/L 10/25/23 14:34 7440-41-710/25/23 04:400.10 0.033 1
Cadmium ND ug/L 10/25/23 14:34 7440-43-910/25/23 04:400.10 0.067 1
Chromium ND ug/L 10/25/23 14:34 7440-47-310/25/23 04:401.0 0.50 1
Cobalt ND ug/L 10/25/23 14:34 7440-48-410/25/23 04:401.0 0.24 1
Copper ND ug/L 10/25/23 14:34 7440-50-810/25/23 04:401.0 0.42 1
Lead ND ug/L 10/25/23 14:34 7439-92-110/25/23 04:401.0 0.22 1
Nickel ND ug/L 10/25/23 14:34 7440-02-010/25/23 04:401.0 0.26 1
Selenium ND ug/L 10/25/23 14:34 7782-49-210/25/23 04:402.0 0.20 1
Silver ND ug/L 10/25/23 14:34 7440-22-410/25/23 04:400.50 0.028 1
Thallium ND ug/L 10/25/23 14:34 7440-28-010/25/23 04:401.0 0.11 1
Vanadium ND ug/L 10/25/23 14:34 7440-62-210/25/23 04:401.0 0.91 1
Zinc ND ug/L 10/25/23 14:34 7440-66-610/25/23 04:4010.0 6.7 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 23:01 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 23:01 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 23:01 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 23:01 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 23:01 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 23:01 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 23:01 74-83-9 v32.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 23:01 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 23:01 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 23:01 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 23:01 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 23:01 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 23:01 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 23:01 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 23:01 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 23:01 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 23:01 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 23:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 23:01 110-57-6 M11.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 23:01 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 23:01 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 23:01 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 23:01 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 23:01 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 23:01 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 23:01 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 23:01 10061-02-61.0 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-1 Lab ID:92693361001 Collected:10/06/23 09:30 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 23:01 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 23:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 23:01 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 23:01 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 23:01 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 23:01 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 23:01 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 23:01 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 23:01 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 23:01 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 23:01 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 23:01 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 23:01 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 23:01 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 23:01 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 23:01 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 23:01 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 23:01 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/16/23 23:01 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 23:01 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)95 %10/16/23 23:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/16/23 23:01 17060-07-070-130 1
Toluene-d8 (S)99 %10/16/23 23:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-2 Lab ID:92693361002 Collected:10/06/23 09:55 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Antimony ND ug/L 10/25/23 14:51 7440-36-010/25/23 04:401.0 0.50 1
Arsenic ND ug/L 10/25/23 14:51 7440-38-210/25/23 04:401.0 0.50 1
Barium 6.9 ug/L 10/25/23 14:51 7440-39-310/25/23 04:401.0 0.50 1
Beryllium ND ug/L 10/25/23 14:51 7440-41-710/25/23 04:400.10 0.033 1
Cadmium ND ug/L 10/25/23 14:51 7440-43-910/25/23 04:400.10 0.067 1
Chromium ND ug/L 10/25/23 14:51 7440-47-310/25/23 04:401.0 0.50 1
Cobalt ND ug/L 10/25/23 14:51 7440-48-410/25/23 04:401.0 0.24 1
Copper ND ug/L 10/25/23 14:51 7440-50-810/25/23 04:401.0 0.42 1
Lead ND ug/L 10/25/23 14:51 7439-92-110/25/23 04:401.0 0.22 1
Nickel ND ug/L 10/25/23 14:51 7440-02-010/25/23 04:401.0 0.26 1
Selenium ND ug/L 10/25/23 14:51 7782-49-210/25/23 04:402.0 0.20 1
Silver ND ug/L 10/25/23 14:51 7440-22-410/25/23 04:400.50 0.028 1
Thallium ND ug/L 10/25/23 14:51 7440-28-010/25/23 04:401.0 0.11 1
Vanadium ND ug/L 10/25/23 14:51 7440-62-210/25/23 04:401.0 0.91 1
Zinc ND ug/L 10/25/23 14:51 7440-66-610/25/23 04:4010.0 6.7 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 23:19 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 23:19 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 23:19 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 23:19 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 23:19 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 23:19 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 23:19 74-83-9 v22.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 23:19 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 23:19 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 23:19 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 23:19 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 23:19 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 23:19 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 23:19 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 23:19 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 23:19 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 23:19 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 23:19 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 23:19 110-57-61.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 23:19 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 23:19 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 23:19 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 23:19 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 23:19 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 23:19 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 23:19 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 23:19 10061-02-61.0 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-2 Lab ID:92693361002 Collected:10/06/23 09:55 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 23:19 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 23:19 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 23:19 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 23:19 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 23:19 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 23:19 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 23:19 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 23:19 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 23:19 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 23:19 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 23:19 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 23:19 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 23:19 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 23:19 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 23:19 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 23:19 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 23:19 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 23:19 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/16/23 23:19 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 23:19 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)96 %10/16/23 23:19 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %10/16/23 23:19 17060-07-070-130 1
Toluene-d8 (S)100 %10/16/23 23:19 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-4 Lab ID:92693361003 Collected:10/06/23 11:00 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Antimony ND ug/L 10/25/23 14:55 7440-36-010/25/23 04:401.0 0.50 1
Arsenic ND ug/L 10/25/23 14:55 7440-38-210/25/23 04:401.0 0.50 1
Barium 7.0 ug/L 10/25/23 14:55 7440-39-310/25/23 04:401.0 0.50 1
Beryllium ND ug/L 10/25/23 14:55 7440-41-710/25/23 04:400.10 0.033 1
Cadmium ND ug/L 10/25/23 14:55 7440-43-910/25/23 04:400.10 0.067 1
Chromium ND ug/L 10/25/23 14:55 7440-47-310/25/23 04:401.0 0.50 1
Cobalt ND ug/L 10/25/23 14:55 7440-48-410/25/23 04:401.0 0.24 1
Copper ND ug/L 10/25/23 14:55 7440-50-810/25/23 04:401.0 0.42 1
Lead ND ug/L 10/25/23 14:55 7439-92-110/25/23 04:401.0 0.22 1
Nickel ND ug/L 10/25/23 14:55 7440-02-010/25/23 04:401.0 0.26 1
Selenium ND ug/L 10/25/23 14:55 7782-49-210/25/23 04:402.0 0.20 1
Silver ND ug/L 10/25/23 14:55 7440-22-410/25/23 04:400.50 0.028 1
Thallium ND ug/L 10/25/23 14:55 7440-28-010/25/23 04:401.0 0.11 1
Vanadium ND ug/L 10/25/23 14:55 7440-62-210/25/23 04:401.0 0.91 1
Zinc ND ug/L 10/25/23 14:55 7440-66-610/25/23 04:4010.0 6.7 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 23:38 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 23:38 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 23:38 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 23:38 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 23:38 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 23:38 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 23:38 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 23:38 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 23:38 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 23:38 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 23:38 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 23:38 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 23:38 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 23:38 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 23:38 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 23:38 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 23:38 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 23:38 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 23:38 110-57-61.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 23:38 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 23:38 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 23:38 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 23:38 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 23:38 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 23:38 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 23:38 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 23:38 10061-02-61.0 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-4 Lab ID:92693361003 Collected:10/06/23 11:00 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 23:38 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 23:38 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 23:38 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 23:38 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 23:38 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 23:38 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 23:38 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 23:38 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 23:38 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 23:38 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 23:38 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 23:38 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 23:38 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 23:38 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 23:38 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 23:38 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 23:38 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 23:38 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/16/23 23:38 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 23:38 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)95 %10/16/23 23:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %10/16/23 23:38 17060-07-070-130 1
Toluene-d8 (S)100 %10/16/23 23:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-5 Lab ID:92693361004 Collected:10/06/23 11:40 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Antimony ND ug/L 10/25/23 15:00 7440-36-010/25/23 04:401.0 0.50 1
Arsenic ND ug/L 10/25/23 15:00 7440-38-210/25/23 04:401.0 0.50 1
Barium 7.1 ug/L 10/25/23 15:00 7440-39-310/25/23 04:401.0 0.50 1
Beryllium ND ug/L 10/25/23 15:00 7440-41-710/25/23 04:400.10 0.033 1
Cadmium ND ug/L 10/25/23 15:00 7440-43-910/25/23 04:400.10 0.067 1
Chromium ND ug/L 10/25/23 15:00 7440-47-310/25/23 04:401.0 0.50 1
Cobalt ND ug/L 10/25/23 15:00 7440-48-410/25/23 04:401.0 0.24 1
Copper 0.50J ug/L 10/25/23 15:00 7440-50-810/25/23 04:401.0 0.42 1
Lead ND ug/L 10/25/23 15:00 7439-92-110/25/23 04:401.0 0.22 1
Nickel ND ug/L 10/25/23 15:00 7440-02-010/25/23 04:401.0 0.26 1
Selenium ND ug/L 10/25/23 15:00 7782-49-210/25/23 04:402.0 0.20 1
Silver ND ug/L 10/25/23 15:00 7440-22-410/25/23 04:400.50 0.028 1
Thallium ND ug/L 10/25/23 15:00 7440-28-010/25/23 04:401.0 0.11 1
Vanadium ND ug/L 10/25/23 15:00 7440-62-210/25/23 04:401.0 0.91 1
Zinc ND ug/L 10/25/23 15:00 7440-66-610/25/23 04:4010.0 6.7 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 23:56 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 23:56 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 23:56 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 23:56 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 23:56 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 23:56 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 23:56 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 23:56 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 23:56 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 23:56 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 23:56 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 23:56 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 23:56 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 23:56 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 23:56 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 23:56 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 23:56 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 23:56 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 23:56 110-57-61.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 23:56 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 23:56 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 23:56 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 23:56 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 23:56 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 23:56 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 23:56 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 23:56 10061-02-61.0 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:SW-5 Lab ID:92693361004 Collected:10/06/23 11:40 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 23:56 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 23:56 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 23:56 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 23:56 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 23:56 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 23:56 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 23:56 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 23:56 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 23:56 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 23:56 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 23:56 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 23:56 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 23:56 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 23:56 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 23:56 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 23:56 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 23:56 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 23:56 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/16/23 23:56 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 23:56 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)97 %10/16/23 23:56 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %10/16/23 23:56 17060-07-070-130 1
Toluene-d8 (S)100 %10/16/23 23:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:EB Lab ID:92693361005 Collected:10/06/23 12:00 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Antimony ND ug/L 10/25/23 15:04 7440-36-010/25/23 04:401.0 0.50 1
Arsenic ND ug/L 10/25/23 15:04 7440-38-210/25/23 04:401.0 0.50 1
Barium ND ug/L 10/25/23 15:04 7440-39-310/25/23 04:401.0 0.50 1
Beryllium ND ug/L 10/25/23 15:04 7440-41-710/25/23 04:400.10 0.033 1
Cadmium ND ug/L 10/25/23 15:04 7440-43-910/25/23 04:400.10 0.067 1
Chromium ND ug/L 10/25/23 15:04 7440-47-310/25/23 04:401.0 0.50 1
Cobalt ND ug/L 10/25/23 15:04 7440-48-410/25/23 04:401.0 0.24 1
Copper 0.44J ug/L 10/25/23 15:04 7440-50-810/25/23 04:401.0 0.42 1
Lead ND ug/L 10/25/23 15:04 7439-92-110/25/23 04:401.0 0.22 1
Nickel ND ug/L 10/25/23 15:04 7440-02-010/25/23 04:401.0 0.26 1
Selenium ND ug/L 10/25/23 15:04 7782-49-210/25/23 04:402.0 0.20 1
Silver ND ug/L 10/25/23 15:04 7440-22-410/25/23 04:400.50 0.028 1
Thallium ND ug/L 10/25/23 15:04 7440-28-010/25/23 04:401.0 0.11 1
Vanadium ND ug/L 10/25/23 15:04 7440-62-210/25/23 04:401.0 0.91 1
Zinc ND ug/L 10/25/23 15:04 7440-66-610/25/23 04:4010.0 6.7 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 22:24 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 22:24 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 22:24 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 22:24 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 22:24 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 22:24 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 22:24 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 22:24 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 22:24 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 22:24 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 22:24 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 22:24 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 22:24 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 22:24 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 22:24 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 22:24 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 22:24 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 22:24 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 22:24 110-57-61.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 22:24 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 22:24 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 22:24 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 22:24 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 22:24 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 22:24 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 22:24 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 22:24 10061-02-61.0 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:EB Lab ID:92693361005 Collected:10/06/23 12:00 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 22:24 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 22:24 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 22:24 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 22:24 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 22:24 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 22:24 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 22:24 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 22:24 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 22:24 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 22:24 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 22:24 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 22:24 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 22:24 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 22:24 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 22:24 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 22:24 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 22:24 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 22:24 108-05-42.0 1.3 1
Vinyl chloride ND ug/L 10/16/23 22:24 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 22:24 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)95 %10/16/23 22:24 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %10/16/23 22:24 17060-07-070-130 1
Toluene-d8 (S)100 %10/16/23 22:24 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:FB Lab ID:92693361006 Collected:10/06/23 12:10 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Acetone ND ug/L 10/16/23 22:42 67-64-125.0 5.1 1
Acrylonitrile ND ug/L 10/16/23 22:42 107-13-110.0 1.8 1
Benzene ND ug/L 10/16/23 22:42 71-43-21.0 0.34 1
Bromochloromethane ND ug/L 10/16/23 22:42 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 10/16/23 22:42 75-27-41.0 0.31 1
Bromoform ND ug/L 10/16/23 22:42 75-25-21.0 0.34 1
Bromomethane ND ug/L 10/16/23 22:42 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 10/16/23 22:42 78-93-35.0 4.0 1
Carbon disulfide ND ug/L 10/16/23 22:42 75-15-02.0 0.36 1
Carbon tetrachloride ND ug/L 10/16/23 22:42 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 10/16/23 22:42 108-90-71.0 0.28 1
Chloroethane ND ug/L 10/16/23 22:42 75-00-31.0 0.65 1
Chloroform ND ug/L 10/16/23 22:42 67-66-31.0 0.43 1
Chloromethane ND ug/L 10/16/23 22:42 74-87-31.0 0.54 1
Dibromochloromethane ND ug/L 10/16/23 22:42 124-48-11.0 0.36 1
Dibromomethane ND ug/L 10/16/23 22:42 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 10/16/23 22:42 95-50-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 10/16/23 22:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 10/16/23 22:42 110-57-61.0 0.56 1
1,1-Dichloroethane ND ug/L 10/16/23 22:42 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 10/16/23 22:42 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 10/16/23 22:42 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/16/23 22:42 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/16/23 22:42 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 10/16/23 22:42 78-87-51.0 0.36 1
cis-1,3-Dichloropropene ND ug/L 10/16/23 22:42 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/16/23 22:42 10061-02-61.0 0.36 1
1,4-Dioxane (p-Dioxane)ND ug/L 10/16/23 22:42 123-91-115038.7 1
Ethylbenzene ND ug/L 10/16/23 22:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 10/16/23 22:42 591-78-65.0 0.48 1
Iodomethane ND ug/L 10/16/23 22:42 74-88-420.0 9.7 1
Methylene Chloride ND ug/L 10/16/23 22:42 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 10/16/23 22:42 108-10-15.0 2.7 1
Styrene ND ug/L 10/16/23 22:42 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/16/23 22:42 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/16/23 22:42 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 10/16/23 22:42 127-18-41.0 0.29 1
Tetrahydrofuran ND ug/L 10/16/23 22:42 109-99-910.0 3.5 1
Toluene ND ug/L 10/16/23 22:42 108-88-31.0 0.24 1
1,1,1-Trichloroethane ND ug/L 10/16/23 22:42 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 10/16/23 22:42 79-00-51.0 0.32 1
Trichloroethene ND ug/L 10/16/23 22:42 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 10/16/23 22:42 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/16/23 22:42 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 10/16/23 22:42 108-05-42.0 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Sample:FB Lab ID:92693361006 Collected:10/06/23 12:10 Received:10/13/23 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level Landfill
Vinyl chloride ND ug/L 10/16/23 22:42 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 10/16/23 22:42 1330-20-71.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)94 %10/16/23 22:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %10/16/23 22:42 17060-07-070-130 1
Toluene-d8 (S)100 %10/16/23 22:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
960806
EPA 3010
EPA 6020
6020 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92693361001, 92693361002, 92693361003, 92693361004, 92693361005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5284180
Associated Lab Samples:92693361001, 92693361002, 92693361003, 92693361004, 92693361005
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 1.0 10/25/23 14:250.50
Arsenic ug/L ND 1.0 10/25/23 14:250.50
Barium ug/L ND 1.0 10/25/23 14:250.50
Beryllium ug/L ND 0.10 10/25/23 14:250.033
Cadmium ug/L ND 0.10 10/25/23 14:250.067
Chromium ug/L ND 1.0 10/25/23 14:250.50
Cobalt ug/L ND 1.0 10/25/23 14:250.24
Copper ug/L ND 1.0 10/25/23 14:250.42
Lead ug/L ND 1.0 10/25/23 14:250.22
Nickel ug/L ND 1.0 10/25/23 14:250.26
Selenium ug/L ND 2.0 10/25/23 14:250.20
Silver ug/L ND 0.50 10/25/23 14:250.028
Thallium ug/L ND 1.0 10/25/23 14:250.11
Vanadium ug/L ND 1.0 10/25/23 14:250.91
Zinc ug/L ND 10.0 10/25/23 14:256.7
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5284181LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 49.150 98 80-120
Arsenic ug/L 47.950 96 80-120
Barium ug/L 47.250 94 80-120
Beryllium ug/L 4.85 95 80-120
Cadmium ug/L 4.85 95 80-120
Chromium ug/L 47.950 96 80-120
Cobalt ug/L 48.650 97 80-120
Copper ug/L 48.650 97 80-120
Lead ug/L 48.450 97 80-120
Nickel ug/L 49.150 98 80-120
Selenium ug/L 49.950 100 80-120
Silver ug/L 4.95 97 80-120
Thallium ug/L 50.050 100 80-120
Vanadium ug/L 47.550 95 80-120
Zinc ug/L 245250 98 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5284182MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92693361001
5284183
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 50 97 75-12597 0 2050ND48.5 48.7
Arsenic ug/L 50 94 75-12595 1 2050ND47.1 47.5
Barium ug/L 50 94 75-12593 1 20507.2 54.2 53.6
Beryllium ug/L 5 97 75-12596 1 205ND4.8 4.8
Cadmium ug/L 5 98 75-12595 3 205ND4.9 4.7
Chromium ug/L 50 98 75-12597 0 2050ND49.1 48.9
Cobalt ug/L 50 96 75-12597 0 2050ND48.1 48.3
Copper ug/L 50 96 75-12596 1 2050ND48.6 48.3
Lead ug/L 50 96 75-12597 1 2050ND47.9 48.4
Nickel ug/L 50 97 75-12596 1 2050ND48.6 48.0
Selenium ug/L 50 98 75-12598 0 2050ND49.2 49.0
Silver ug/L 5 98 75-12597 1 205ND4.9 4.8
Thallium ug/L 50 98 75-12598 1 2050ND49.0 49.3
Vanadium ug/L 50 97 75-12596 1 2050ND48.7 48.4
Zinc ug/L 250 95 75-12596 1 20250ND239240
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
806694
EPA 8260D
EPA 8260D
8260D MSV Low Level Landfill
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92693361001, 92693361002, 92693361003, 92693361004, 92693361005, 92693361006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4177218
Associated Lab Samples:92693361001, 92693361002, 92693361003, 92693361004, 92693361005, 92693361006
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 10/16/23 21:470.31
1,1,1-Trichloroethane ug/L ND 1.0 10/16/23 21:470.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 10/16/23 21:470.22
1,1,2-Trichloroethane ug/L ND 1.0 10/16/23 21:470.32
1,1-Dichloroethane ug/L ND 1.0 10/16/23 21:470.37
1,1-Dichloroethene ug/L ND 1.0 10/16/23 21:470.35
1,2,3-Trichloropropane ug/L ND 1.0 10/16/23 21:470.26
1,2-Dichlorobenzene ug/L ND 1.0 10/16/23 21:470.34
1,2-Dichloroethane ug/L ND 1.0 10/16/23 21:470.32
1,2-Dichloropropane ug/L ND 1.0 10/16/23 21:470.36
1,4-Dichlorobenzene ug/L ND 1.0 10/16/23 21:470.33
1,4-Dioxane (p-Dioxane)ug/L ND 150 10/16/23 21:4738.7
2-Butanone (MEK)ug/L ND 5.0 10/16/23 21:474.0
2-Hexanone ug/L ND 5.0 10/16/23 21:470.48
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 10/16/23 21:472.7
Acetone ug/L ND 25.0 10/16/23 21:475.1
Acrylonitrile ug/L ND 10.0 10/16/23 21:471.8
Benzene ug/L ND 1.0 10/16/23 21:470.34
Bromochloromethane ug/L ND 1.0 10/16/23 21:470.47
Bromodichloromethane ug/L ND 1.0 10/16/23 21:470.31
Bromoform ug/L ND 1.0 10/16/23 21:470.34
Bromomethane ug/L ND 2.0 10/16/23 21:471.7
Carbon disulfide ug/L ND 2.0 10/16/23 21:470.36
Carbon tetrachloride ug/L ND 1.0 10/16/23 21:470.33
Chlorobenzene ug/L ND 1.0 10/16/23 21:470.28
Chloroethane ug/L ND 1.0 10/16/23 21:470.65
Chloroform ug/L ND 1.0 10/16/23 21:470.43
Chloromethane ug/L ND 1.0 10/16/23 21:470.54
cis-1,2-Dichloroethene ug/L ND 1.0 10/16/23 21:470.38
cis-1,3-Dichloropropene ug/L ND 1.0 10/16/23 21:470.36
Dibromochloromethane ug/L ND 1.0 10/16/23 21:470.36
Dibromomethane ug/L ND 1.0 10/16/23 21:470.39
Ethylbenzene ug/L ND 1.0 10/16/23 21:470.30
Iodomethane ug/L ND 20.0 10/16/23 21:479.7
Methylene Chloride ug/L ND 5.0 10/16/23 21:472.0
Styrene ug/L ND 1.0 10/16/23 21:470.29
Tetrachloroethene ug/L ND 1.0 10/16/23 21:470.29
Tetrahydrofuran ug/L ND 10.0 10/16/23 21:473.5
Toluene ug/L ND 1.0 10/16/23 21:470.24
trans-1,2-Dichloroethene ug/L ND 1.0 10/16/23 21:470.40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4177218
Associated Lab Samples:92693361001, 92693361002, 92693361003, 92693361004, 92693361005, 92693361006
Matrix:Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 10/16/23 21:470.36
trans-1,4-Dichloro-2-butene ug/L ND 1.0 10/16/23 21:470.56
Trichloroethene ug/L ND 1.0 10/16/23 21:470.38
Trichlorofluoromethane ug/L ND 1.0 10/16/23 21:470.30
Vinyl acetate ug/L ND 2.0 10/16/23 21:471.3
Vinyl chloride ug/L ND 1.0 10/16/23 21:470.39
Xylene (Total)ug/L ND 1.0 10/16/23 21:470.34
1,2-Dichloroethane-d4 (S)%99 70-130 10/16/23 21:47
4-Bromofluorobenzene (S)%95 70-130 10/16/23 21:47
Toluene-d8 (S)%100 70-130 10/16/23 21:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4177219LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130
1,1,1-Trichloroethane ug/L 19.620 98 70-130
1,1,2,2-Tetrachloroethane ug/L 19.020 95 70-130
1,1,2-Trichloroethane ug/L 19.820 99 70-130
1,1-Dichloroethane ug/L 20.220 101 70-130
1,1-Dichloroethene ug/L 21.620 108 69-131
1,2,3-Trichloropropane ug/L 18.520 93 70-130
1,2-Dichlorobenzene ug/L 19.620 98 70-130
1,2-Dichloroethane ug/L 19.720 99 70-130
1,2-Dichloropropane ug/L 19.720 98 70-130
1,4-Dichlorobenzene ug/L 19.720 98 70-130
1,4-Dioxane (p-Dioxane)ug/L 356400 89 70-132
2-Butanone (MEK)ug/L 36.640 92 67-133
2-Hexanone ug/L 35.540 89 70-133
4-Methyl-2-pentanone (MIBK)ug/L 36.140 90 70-130
Acetone ug/L 35.540 89 67-130
Acrylonitrile ug/L 94.9100 95 70-130
Benzene ug/L 19.820 99 70-130
Bromochloromethane ug/L 19.820 99 70-130
Bromodichloromethane ug/L 19.520 97 70-130
Bromoform ug/L 19.120 95 70-133
Bromomethane ug/L 17.020 85 41-148
Carbon disulfide ug/L 21.920 109 70-131
Carbon tetrachloride ug/L 20.020 100 70-130
Chlorobenzene ug/L 19.620 98 70-130
Chloroethane ug/L 22.820 114 41-157
Chloroform ug/L 19.720 99 70-130
Chloromethane ug/L 22.820 114 59-141
cis-1,2-Dichloroethene ug/L 19.420 97 70-130
cis-1,3-Dichloropropene ug/L 19.820 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 20 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4177219LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 18.820 94 70-130
Dibromomethane ug/L 19.220 96 70-130
Ethylbenzene ug/L 19.420 97 70-130
Iodomethane ug/L 40.740 102 57-140
Methylene Chloride ug/L 20.420 102 62-130
Styrene ug/L 19.620 98 70-130
Tetrachloroethene ug/L 18.920 95 70-130
Tetrahydrofuran ug/L 183200 91 70-131
Toluene ug/L 19.620 98 70-130
trans-1,2-Dichloroethene ug/L 20.020 100 70-130
trans-1,3-Dichloropropene ug/L 19.520 98 70-130
trans-1,4-Dichloro-2-butene ug/L 22.620 113 57-149
Trichloroethene ug/L 20.120 100 70-130
Trichlorofluoromethane ug/L 22.620 113 57-130
Vinyl acetate ug/L 40.240 101 70-141
Vinyl chloride ug/L 20.920 104 66-140
Xylene (Total)ug/L 58.160 97 70-130
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4177220MATRIX SPIKE SAMPLE:
MSSpike
Result
92693361001
1,1,1,2-Tetrachloroethane ug/L 22.220 111 70-146ND
1,1,1-Trichloroethane ug/L 22.320 111 70-150ND
1,1,2,2-Tetrachloroethane ug/L 20.920 104 66-144ND
1,1,2-Trichloroethane ug/L 21.120 106 70-142ND
1,1-Dichloroethane ug/L 22.320 111 68-150ND
1,1-Dichloroethene ug/L 24.120 120 64-162ND
1,2,3-Trichloropropane ug/L 20.020 100 66-144ND
1,2-Dichlorobenzene ug/L 21.820 109 70-142ND
1,2-Dichloroethane ug/L 20.920 105 68-145ND
1,2-Dichloropropane ug/L 21.820 109 70-144ND
1,4-Dichlorobenzene ug/L 22.120 111 70-140ND
1,4-Dioxane (p-Dioxane)ug/L 371400 93 66-151ND
2-Butanone (MEK)ug/L 37.740 94 57-156ND
2-Hexanone ug/L 38.540 96 62-153ND
4-Methyl-2-pentanone (MIBK)ug/L 38.140 95 65-144ND
Acetone ug/L 35.840 90 49-162ND
Acrylonitrile ug/L 96.6100 97 59-155ND
Benzene ug/L 22.220 111 68-144ND
Bromochloromethane ug/L 21.820 109 70-148ND
Bromodichloromethane ug/L 21.620 108 70-141ND
Bromoform ug/L 20.920 105 59-144ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
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[phone]
Page 21 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
4177220MATRIX SPIKE SAMPLE:
MSSpike
Result
92693361001
Bromomethane ug/L 23.9 v32012023-190ND
Carbon disulfide ug/L 25.020 125 64-160ND
Carbon tetrachloride ug/L 23.020 115 70-147ND
Chlorobenzene ug/L 22.320 112 70-143ND
Chloroethane ug/L 25.920 130 55-190ND
Chloroform ug/L 21.720 108 67-148ND
Chloromethane ug/L 25.720 129 38-180ND
cis-1,2-Dichloroethene ug/L 22.320 112 67-151ND
cis-1,3-Dichloropropene ug/L 21.520 107 70-142ND
Dibromochloromethane ug/L 21.620 108 68-140ND
Dibromomethane ug/L 21.120 105 70-142ND
Ethylbenzene ug/L 22.420 112 70-145ND
Iodomethane ug/L 45.240 113 37-160ND
Methylene Chloride ug/L 21.220 106 54-149ND
Styrene ug/L 22.920 114 70-147ND
Tetrachloroethene ug/L 22.420 112 70-145ND
Tetrahydrofuran ug/L 189200 95 48-160ND
Toluene ug/L 21.920 109 65-146ND
trans-1,2-Dichloroethene ug/L 22.420 112 69-155ND
trans-1,3-Dichloropropene ug/L 21.720 108 70-142ND
trans-1,4-Dichloro-2-butene ug/L 30.8 M12015439-149ND
Trichloroethene ug/L 22.820 114 70-152ND
Trichlorofluoromethane ug/L 25.920 130 60-158ND
Vinyl acetate ug/L 42.740 107 56-157ND
Vinyl chloride ug/L 24.620 123 51-178ND
Xylene (Total)ug/L 67.060 112 70-146ND
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92693361002
4177221SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
1,4-Dioxane (p-Dioxane)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92693361002
4177221SAMPLE DUPLICATE:
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND v230ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%99101
4-Bromofluorobenzene (S)%9996
Toluene-d8 (S)%100100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 28
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 28
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92693361
CHEROKEE LF SW_BANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92693361001 960806 960879SW-1 EPA 3010 EPA 6020
92693361002 960806 960879SW-2 EPA 3010 EPA 6020
92693361003 960806 960879SW-4 EPA 3010 EPA 6020
92693361004 960806 960879SW-5 EPA 3010 EPA 6020
92693361005 960806 960879EBEPA 3010 EPA 6020
92693361001 806694SW-1 EPA 8260D
92693361002 806694SW-2 EPA 8260D
92693361003 806694SW-4 EPA 8260D
92693361004 806694SW-5 EPA 8260D
92693361005 806694EBEPA 8260D
92693361006 806694FBEPA 8260D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/26/2023 11:20 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 28
Page 26 of 28
Page 27 of 28
Page 28 of 28
#=CL#
December 28, 2023
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92692753
92692753
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
CHEROKEE LINED PFAS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on October 09, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
704-977-0968
Enclosures
cc:Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 34
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92692753
CHEROKEE LINED PFAS
Lab ID Sample ID Matrix Date Collected Date Received
92692753001 MW-4 Water 10/09/33 00:00 10/09/23 08:40
92692753002 MW-6S Water 10/09/33 00:00 10/09/23 08:40
92692753003 MW-7 Water 10/09/33 00:00 10/09/23 08:40
92692753004 LEACHATE Water 10/09/33 00:00 10/09/23 08:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 34
Page 3 of 34
Page 4 of 34
Page 5 of 34
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced,except in its entirety,without the written approval of Pace Analytical Services,LLC.
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Report of Analysis
Pace Analytical Services,Inc.
9800 Kincey Avenue
Suite 100
Huntersville,NC 28078
Attention:Bonnie Vang
Project Name:Cherokee Lined PFAS
Project Number:92692753
Lot Number:YJ16031
Date Completed:12/26/2023
12/28/2023 11:28 AM
Approved and released by:
Project Coordinator 1:Jenna S.Holliday
Page 1 of 29
Page 6 of 34
PACE ANALYTICAL SERVICES,LLC
SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No:5639
Pace Analytical Services,LLC (formerly Shealy Environmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax [phone] www.pacelabs.com
Case Narrative
Pace Analytical Services,Inc.
Lot Number:YJ16031
This Report of Analysis contains the analytical result(s)for the sample(s)listed on the Sample Summary
following this Case Narrative.The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.Where
sampling is conducted by the client,results relate to the accuracy of the information provided,and as the
samples are received.
Sample receipt,sample analysis,and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI)standards,the Pace Analytical Services,LLC ("Pace")
Laboratory Quality Manual,standard operating procedures (SOPs),and Pace policies.Any exceptions to
the TNI standards,the Laboratory Quality Manual,SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory;however,the following analyses are currently not listed on our TNI
scope of accreditation:E.coli and Total coliforms SM 9223 B-2004,Solid Chemical Material:TOC
Walkley-Black,Biological Tissue:All,Non-Potable Water:SGT-HEM EPA 1664B,Silica EPA 200.7,
Boron,Calcium,Silicon,Strontium EPA 200.8,Bicarbonate,Carbonate,and Hydroxide Alkalinity SM
2320 B-2011,SM 9221 C E-2006 &SM 9222D-2006,Strontium SW-846 6010D,VOC SM 6200 B-2011,
Fecal Coliform Colilert-18.If you have any questions regarding this report,please contact the Pace
Project Manager listed on the cover page.
PFAS Analysis
Surrogate recovery for samples YJ16031-002 and -003 were outside the acceptance limits.Evidence of
matrix interference is present;therefore,re-extraction and/or re-analysis was not performed.
Page 2 of 29
Page 7 of 34
PACE ANALYTICAL SERVICES, LLC
Sample Summary
Pace Analytical Services, Inc.
Lot Number: YJ16031

Project Name: Cherokee Lined PFAS
Project Number: 92692753
Sample Number Sample ID Matrix Date Sampled Date Received
001 10/09/2023MW-4 Aqueous 10/14/2023
002 10/09/2023MW-6S Aqueous 10/14/2023
003 10/09/2023MW-7 Aqueous 10/14/2023
004 10/09/2023LEACHATEAqueous 10/14/2023
(4 samples)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 3 of 29
Page 8 of 34
PACE ANALYTICAL SERVICES, LLC
Detection Summary
Pace Analytical Services, Inc.
Lot Number: YJ16031

Project Name: Cherokee Lined PFAS
Project Number: 92692753
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 MW-4 Aqueous 4:2FTS 1633 0.83 J ng/L 6
001 MW-4 Aqueous 6:2FTS 1633 13 ng/L 6
001 MW-4 Aqueous 5:3FTCA 1633 63 ng/L 6
001 MW-4 Aqueous PFBS 1633 10 ng/L 6
001 MW-4 Aqueous PFBA 1633 50 ng/L 6
001 MW-4 Aqueous PFDA 1633 0.22 J ng/L 6
001 MW-4 Aqueous PFHpS 1633 0.37 J ng/L 6
001 MW-4 Aqueous PFHpA 1633 32 ng/L 6
001 MW-4 Aqueous PFHxS 1633 32 ng/L 6
001 MW-4 Aqueous PFHxA 1633 170 ng/L 6
001 MW-4 Aqueous PFNA 1633 2.3 ng/L 6
001 MW-4 Aqueous PFOS 1633 3.7 ng/L 6
001 MW-4 Aqueous PFOA 1633 66 ng/L 6
001 MW-4 Aqueous PFPeS 1633 1.8 ng/L 6
001 MW-4 Aqueous PFPeA 1633 55 ng/L 6
001 MW-4 Aqueous 3:3FTCA 1633 6.1 ng/L 6
002 MW-6S Aqueous NMeFOSAA 1633 0.72 J ng/L 8
002 MW-6S Aqueous PFBS 1633 2.1 ng/L 8
002 MW-6S Aqueous PFBA 1633 7.3 ng/L 8
002 MW-6S Aqueous PFHpA 1633 6.6 ng/L 8
002 MW-6S Aqueous PFHxS 1633 1.5 ng/L 8
002 MW-6S Aqueous PFHxA 1633 14 ng/L 8
002 MW-6S Aqueous PFOS 1633 0.90 J ng/L 8
002 MW-6S Aqueous PFOA 1633 3.2 ng/L 8
002 MW-6S Aqueous PFPeS 1633 0.41 J ng/L 8
002 MW-6S Aqueous PFPeA 1633 11 ng/L 8
003 MW-7 Aqueous PFBS 1633 8.2 ng/L 10
003 MW-7 Aqueous PFBA 1633 38 ng/L 10
003 MW-7 Aqueous PFHpA 1633 25 ng/L 10
003 MW-7 Aqueous PFHxS 1633 3.2 ng/L 10
003 MW-7 Aqueous PFHxA 1633 310 ng/L 10
003 MW-7 Aqueous PFNA 1633 0.67 J ng/L 10
003 MW-7 Aqueous PFOS 1633 1.7 ng/L 10
003 MW-7 Aqueous PFOA 1633 29 ng/L 10
003 MW-7 Aqueous PFPeS 1633 0.79 J ng/L 10
003 MW-7 Aqueous PFPeA 1633 110 ng/L 10
004 LEACHATE Aqueous 8:2FTS 1633 11 J ng/L 12
004 LEACHATE Aqueous 6:2FTS 1633 47 ng/L 12
004 LEACHATE Aqueous 5:3FTCA 1633 1000 ng/L 12
004 LEACHATE Aqueous NEtFOSAA 1633 45 ng/L 12
004 LEACHATE Aqueous NMeFOSAA 1633 18 ng/L 12
004 LEACHATE Aqueous PFMPA 1633 1.3 J ng/L 12
004 LEACHATE Aqueous PFBS 1633 36 ng/L 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 4 of 29
Page 9 of 34
Detection Summary (Continued)
Lot Number: YJ16031
Sample Sample ID Matrix Parameter Method Result Q Units Page
004 LEACHATE Aqueous PFBA 1633 230 ng/L 12
004 LEACHATE Aqueous PFDA 1633 3.7 J ng/L 12
004 LEACHATE Aqueous PFHpA 1633 130 ng/L 12
004 LEACHATE Aqueous 7:3FTCA 1633 50 J ng/L 12
004 LEACHATE Aqueous PFHxS 1633 120 ng/L 12
004 LEACHATE Aqueous PFHxA 1633 660 ng/L 12
004 LEACHATE Aqueous PFNA 1633 8.0 ng/L 12
004 LEACHATE Aqueous PFOS 1633 17 ng/L 12
004 LEACHATE Aqueous PFOA 1633 230 ng/L 12
004 LEACHATE Aqueous PFPeS 1633 4.9 J ng/L 12
004 LEACHATE Aqueous PFPeA 1633 200 ng/L 12
004 LEACHATE Aqueous 3:3FTCA 1633 60 ng/L 12
(55 detections)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 5 of 29
Page 10 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-4
YJ16031-001
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1633 1633 1 11/07/2023 1737 ALM 11/06/2023 1514 89295
AnalyticalCAS
Parameter Number Method Result Q LOQ Units Run DL
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3...)763051-92-9 1633 ND 1ng/L0.803.7
9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid (9Cl-PF3ONS)756426-58-1 1633 ND 1ng/L0.613.7
4,8-Dioxa-3H-perfluorononanoic acid (ADONA)919005-14-4 1633 ND 1ng/L0.613.7
1H,1H,2H,2H-Perfluorodecane sulfonic acid (8:2FTS)39108-34-4 1633 ND 1ng/L0.563.7
1H,1H,2H,2H-Perfluorohexane sulfonic acid (4:2FTS)757124-72-4 1633 0.83 J 1ng/L0.363.7
1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2FTS)27619-97-2 1633 13 1ng/L1.84.6
2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA)914637-49-3 1633 63 1ng/L3.923
Hexafluoropropylene oxide dimer acid (HFPO-DA)13252-13-6 1633 ND 1ng/L0.913.7
N-ethyl perfluorooctanesulfonamide (NEtFOSA)4151-50-2 1633 ND 1ng/L0.120.91
N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA)2991-50-6 1633 ND 1ng/L0.270.91
N-ethyl perfluorooctanesulfonamidoethanol (NEtFOSE)1691-99-2 1633 ND 1ng/L0.569.1
N-methyl perfluorooctanesulfonamide (NMeFOSA)31506-32-8 1633 ND 1ng/L0.200.91
N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA)2355-31-9 1633 ND 1ng/L0.270.91
N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE)24448-09-7 1633 ND 1ng/L0.589.1
Nonafluoro-3,6-dioxaheptanoic acid (NFDHA)151772-58-6 1633 ND 1ng/L0.531.8
Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA)113507-82-7 1633 ND 1ng/L0.331.8
Perfluoro-3-methoxypropanoic acid (PFMPA)377-73-1 1633 ND 1ng/L0.171.8
Perfluoro-4-methoxybutanoic acid (PFMBA)863090-89-5 1633 ND 1ng/L0.361.8
Perfluorobutanesulfonic acid (PFBS)375-73-5 1633 10 1ng/L0.0860.91
Perfluorobutanoic acid (PFBA)375-22-4 1633 50 1ng/L0.473.7
Perfluorodecanesulfonic acid (PFDS)335-77-3 1633 ND 1ng/L0.150.91
Perfluorodecanoic acid (PFDA)335-76-2 1633 0.22 J 1ng/L0.120.91
Perfluorododecanesulfonic acid (PFDoS)79780-39-5 1633 ND 1ng/L0.140.91
Perfluorododecanoic acid (PFDoA)307-55-1 1633 ND 1ng/L0.0980.91
Perfluoroheptanesulfonic acid (PFHpS)375-92-8 1633 0.37 J 1ng/L0.170.91
Perfluoroheptanoic acid (PFHpA)375-85-9 1633 32 1ng/L0.190.91
3-Perfluoroheptyl propanoic acid (7:3FTCA)812-70-4 1633 ND 1ng/L3.823
Perfluorohexanesulfonic acid (PFHxS)355-46-4 1633 32 1ng/L0.170.91
Perfluorohexanoic acid (PFHxA)307-24-4 1633 170 1ng/L0.130.91
Perfluorononanesulfonic acid (PFNS)68259-12-1 1633 ND 1ng/L0.130.91
Perfluorononanoic acid (PFNA)375-95-1 1633 2.3 1ng/L0.0940.91
Perfluorooctanesulfonamide (PFOSA)754-91-6 1633 ND 1ng/L0.180.91
Perfluorooctanesulfonic acid (PFOS)1763-23-1 1633 3.7 1ng/L0.230.91
Perfluorooctanoic acid (PFOA)335-67-1 1633 66 1ng/L0.190.91
Perfluoropentanesulfonic acid (PFPeS)2706-91-4 1633 1.8 1ng/L0.240.91
Perfluoropentanoic acid (PFPeA)2706-90-3 1633 55 1ng/L0.171.8
3-Perfluoropropyl propanoic acid (3:3FTCA)356-02-5 1633 6.1 1ng/L0.544.6
Perfluorotetradecanoic acid (PFTeDA)376-06-7 1633 ND 1ng/L0.250.91
Perfluorotridecanoic acid (PFTrDA)72629-94-8 1633 ND 1ng/L0.180.91
Perfluoroundecanoic acid (PFUnA)2058-94-8 1633 ND 1ng/L0.230.91
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 6 of 29
Page 11 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-4
YJ16031-001
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
AcceptanceRun 1
Surrogate Q % Recovery Limits
13C2-4:2FTS 104 20-150
13C2-6:2FTS 108 20-150
13C2-8:2FTS 73 20-150
13C2-PFDoA 53 20-150
13C2-PFTeDA 45 20-150
13C3-HFPO-DA 82 20-150
13C3-PFBS 80 20-150
13C3-PFHxS 82 20-150
13C4-PFBA 84 20-150
13C4-PFHpA 86 20-150
13C5-PFHxA 81 20-150
13C5-PFPeA 85 20-150
13C6-PFDA 66 20-150
13C7-PFUnA 55 20-150
13C8-PFOA 80 20-150
13C8-PFOS 65 20-150
13C8-PFOSA 63 20-150
13C9-PFNA 74 20-150
D3-NMeFOSA 42 20-150
D3-NMeFOSAA 58 20-150
D5-NEtFOSA 36 20-150
D5-NEtFOSAA 55 20-150
D7-NMeFOSE 44 20-150
D9-NEtFOSE 39 20-150
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 7 of 29
Page 12 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-6S
YJ16031-002
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1633 1633 1 11/07/2023 1746 ALM 11/06/2023 1514 89295
AnalyticalCAS
Parameter Number Method Result Q LOQ Units Run DL
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3...)763051-92-9 1633 ND 1ng/L0.803.6
9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid (9Cl-PF3ONS)756426-58-1 1633 ND 1ng/L0.613.6
4,8-Dioxa-3H-perfluorononanoic acid (ADONA)919005-14-4 1633 ND 1ng/L0.613.6
1H,1H,2H,2H-Perfluorodecane sulfonic acid (8:2FTS)39108-34-4 1633 ND 1ng/L0.563.6
1H,1H,2H,2H-Perfluorohexane sulfonic acid (4:2FTS)757124-72-4 1633 ND 1ng/L0.363.6
1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2FTS)27619-97-2 1633 ND 1ng/L1.84.6
2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA)914637-49-3 1633 ND 1ng/L3.923
Hexafluoropropylene oxide dimer acid (HFPO-DA)13252-13-6 1633 ND 1ng/L0.913.6
N-ethyl perfluorooctanesulfonamide (NEtFOSA)4151-50-2 1633 ND 1ng/L0.120.91
N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA)2991-50-6 1633 ND 1ng/L0.270.91
N-ethyl perfluorooctanesulfonamidoethanol (NEtFOSE)1691-99-2 1633 ND Q 1ng/L0.569.1
N-methyl perfluorooctanesulfonamide (NMeFOSA)31506-32-8 1633 ND 1ng/L0.200.91
N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA)2355-31-9 1633 0.72 J 1ng/L0.270.91
N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE)24448-09-7 1633 ND 1ng/L0.589.1
Nonafluoro-3,6-dioxaheptanoic acid (NFDHA)151772-58-6 1633 ND 1ng/L0.531.8
Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA)113507-82-7 1633 ND 1ng/L0.331.8
Perfluoro-3-methoxypropanoic acid (PFMPA)377-73-1 1633 ND 1ng/L0.171.8
Perfluoro-4-methoxybutanoic acid (PFMBA)863090-89-5 1633 ND 1ng/L0.351.8
Perfluorobutanesulfonic acid (PFBS)375-73-5 1633 2.1 1ng/L0.0860.91
Perfluorobutanoic acid (PFBA)375-22-4 1633 7.3 1ng/L0.473.6
Perfluorodecanesulfonic acid (PFDS)335-77-3 1633 ND 1ng/L0.150.91
Perfluorodecanoic acid (PFDA)335-76-2 1633 ND 1ng/L0.120.91
Perfluorododecanesulfonic acid (PFDoS)79780-39-5 1633 ND 1ng/L0.140.91
Perfluorododecanoic acid (PFDoA)307-55-1 1633 ND 1ng/L0.0970.91
Perfluoroheptanesulfonic acid (PFHpS)375-92-8 1633 ND 1ng/L0.170.91
Perfluoroheptanoic acid (PFHpA)375-85-9 1633 6.6 1ng/L0.190.91
3-Perfluoroheptyl propanoic acid (7:3FTCA)812-70-4 1633 ND 1ng/L3.823
Perfluorohexanesulfonic acid (PFHxS)355-46-4 1633 1.5 1ng/L0.170.91
Perfluorohexanoic acid (PFHxA)307-24-4 1633 14 1ng/L0.130.91
Perfluorononanesulfonic acid (PFNS)68259-12-1 1633 ND 1ng/L0.130.91
Perfluorononanoic acid (PFNA)375-95-1 1633 ND 1ng/L0.0940.91
Perfluorooctanesulfonamide (PFOSA)754-91-6 1633 ND 1ng/L0.180.91
Perfluorooctanesulfonic acid (PFOS)1763-23-1 1633 0.90 J 1ng/L0.230.91
Perfluorooctanoic acid (PFOA)335-67-1 1633 3.2 1ng/L0.190.91
Perfluoropentanesulfonic acid (PFPeS)2706-91-4 1633 0.41 J 1ng/L0.230.91
Perfluoropentanoic acid (PFPeA)2706-90-3 1633 11 1ng/L0.171.8
3-Perfluoropropyl propanoic acid (3:3FTCA)356-02-5 1633 ND 1ng/L0.544.6
Perfluorotetradecanoic acid (PFTeDA)376-06-7 1633 ND 1ng/L0.250.91
Perfluorotridecanoic acid (PFTrDA)72629-94-8 1633 ND 1ng/L0.180.91
Perfluoroundecanoic acid (PFUnA)2058-94-8 1633 ND 1ng/L0.230.91
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 8 of 29
Page 13 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-6S
YJ16031-002
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
AcceptanceRun 1
Surrogate Q % Recovery Limits
13C2-4:2FTS 70 20-150
13C2-6:2FTS 70 20-150
13C2-8:2FTS 50 20-150
13C2-PFDoA 37 20-150
13C2-PFTeDA 29 20-150
13C3-HFPO-DA 67 20-150
13C3-PFBS 63 20-150
13C3-PFHxS 63 20-150
13C4-PFBA 69 20-150
13C4-PFHpA 61 20-150
13C5-PFHxA 66 20-150
13C5-PFPeA 66 20-150
13C6-PFDA 60 20-150
13C7-PFUnA 52 20-150
13C8-PFOA 66 20-150
13C8-PFOS 64 20-150
13C8-PFOSA 60 20-150
13C9-PFNA 63 20-150
D3-NMeFOSA 38 20-150
D3-NMeFOSAA 45 20-150
D5-NEtFOSA 31 20-150
D5-NEtFOSAA 43 20-150
D7-NMeFOSE 21 20-150
D9-NEtFOSE N 5.0 20-150
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 9 of 29
Page 14 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-7
YJ16031-003
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1633 1633 1 11/07/2023 1755 ALM 11/06/2023 1514 89295
AnalyticalCAS
Parameter Number Method Result Q LOQ Units Run DL
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3...)763051-92-9 1633 ND 1ng/L0.803.6
9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid (9Cl-PF3ONS)756426-58-1 1633 ND 1ng/L0.613.6
4,8-Dioxa-3H-perfluorononanoic acid (ADONA)919005-14-4 1633 ND 1ng/L0.603.6
1H,1H,2H,2H-Perfluorodecane sulfonic acid (8:2FTS)39108-34-4 1633 ND 1ng/L0.553.6
1H,1H,2H,2H-Perfluorohexane sulfonic acid (4:2FTS)757124-72-4 1633 ND 1ng/L0.363.6
1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2FTS)27619-97-2 1633 ND 1ng/L1.84.5
2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA)914637-49-3 1633 ND 1ng/L3.923
Hexafluoropropylene oxide dimer acid (HFPO-DA)13252-13-6 1633 ND 1ng/L0.903.6
N-ethyl perfluorooctanesulfonamide (NEtFOSA)4151-50-2 1633 ND 1ng/L0.120.91
N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA)2991-50-6 1633 ND 1ng/L0.260.91
N-ethyl perfluorooctanesulfonamidoethanol (NEtFOSE)1691-99-2 1633 ND Q 1ng/L0.569.1
N-methyl perfluorooctanesulfonamide (NMeFOSA)31506-32-8 1633 ND 1ng/L0.200.91
N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA)2355-31-9 1633 ND 1ng/L0.270.91
N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE)24448-09-7 1633 ND 1ng/L0.579.1
Nonafluoro-3,6-dioxaheptanoic acid (NFDHA)151772-58-6 1633 ND 1ng/L0.521.8
Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA)113507-82-7 1633 ND 1ng/L0.331.8
Perfluoro-3-methoxypropanoic acid (PFMPA)377-73-1 1633 ND 1ng/L0.171.8
Perfluoro-4-methoxybutanoic acid (PFMBA)863090-89-5 1633 ND 1ng/L0.351.8
Perfluorobutanesulfonic acid (PFBS)375-73-5 1633 8.2 1ng/L0.0850.91
Perfluorobutanoic acid (PFBA)375-22-4 1633 38 1ng/L0.463.6
Perfluorodecanesulfonic acid (PFDS)335-77-3 1633 ND 1ng/L0.150.91
Perfluorodecanoic acid (PFDA)335-76-2 1633 ND 1ng/L0.120.91
Perfluorododecanesulfonic acid (PFDoS)79780-39-5 1633 ND 1ng/L0.140.91
Perfluorododecanoic acid (PFDoA)307-55-1 1633 ND 1ng/L0.0970.91
Perfluoroheptanesulfonic acid (PFHpS)375-92-8 1633 ND 1ng/L0.170.91
Perfluoroheptanoic acid (PFHpA)375-85-9 1633 25 1ng/L0.190.91
3-Perfluoroheptyl propanoic acid (7:3FTCA)812-70-4 1633 ND 1ng/L3.823
Perfluorohexanesulfonic acid (PFHxS)355-46-4 1633 3.2 1ng/L0.170.91
Perfluorohexanoic acid (PFHxA)307-24-4 1633 310 1ng/L0.130.91
Perfluorononanesulfonic acid (PFNS)68259-12-1 1633 ND 1ng/L0.130.91
Perfluorononanoic acid (PFNA)375-95-1 1633 0.67 J 1ng/L0.0940.91
Perfluorooctanesulfonamide (PFOSA)754-91-6 1633 ND 1ng/L0.180.91
Perfluorooctanesulfonic acid (PFOS)1763-23-1 1633 1.7 1ng/L0.220.91
Perfluorooctanoic acid (PFOA)335-67-1 1633 29 1ng/L0.190.91
Perfluoropentanesulfonic acid (PFPeS)2706-91-4 1633 0.79 J 1ng/L0.230.91
Perfluoropentanoic acid (PFPeA)2706-90-3 1633 110 1ng/L0.171.8
3-Perfluoropropyl propanoic acid (3:3FTCA)356-02-5 1633 ND 1ng/L0.544.5
Perfluorotetradecanoic acid (PFTeDA)376-06-7 1633 ND 1ng/L0.240.91
Perfluorotridecanoic acid (PFTrDA)72629-94-8 1633 ND 1ng/L0.180.91
Perfluoroundecanoic acid (PFUnA)2058-94-8 1633 ND 1ng/L0.230.91
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 10 of 29
Page 15 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
MW-7
YJ16031-003
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
AcceptanceRun 1
Surrogate Q % Recovery Limits
13C2-4:2FTS 83 20-150
13C2-6:2FTS 81 20-150
13C2-8:2FTS 54 20-150
13C2-PFDoA 45 20-150
13C2-PFTeDA 37 20-150
13C3-HFPO-DA 83 20-150
13C3-PFBS 77 20-150
13C3-PFHxS 78 20-150
13C4-PFBA 83 20-150
13C4-PFHpA 82 20-150
13C5-PFHxA 77 20-150
13C5-PFPeA 82 20-150
13C6-PFDA 59 20-150
13C7-PFUnA 54 20-150
13C8-PFOA 81 20-150
13C8-PFOS 59 20-150
13C8-PFOSA 68 20-150
13C9-PFNA 68 20-150
D3-NMeFOSA 43 20-150
D3-NMeFOSAA 58 20-150
D5-NEtFOSA 33 20-150
D5-NEtFOSAA 51 20-150
D7-NMeFOSE 23 20-150
D9-NEtFOSE N 10 20-150
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 11 of 29
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PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
LEACHATE
YJ16031-004
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1633 1633 1 12/21/2023 1823 ALM 12/01/2023 1728 91287
AnalyticalCAS
Parameter Number Method Result Q LOQ Units Run DL
11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3...)763051-92-9 1633 ND 1ng/L4.521
9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid (9Cl-PF3ONS)756426-58-1 1633 ND 1ng/L3.421
4,8-Dioxa-3H-perfluorononanoic acid (ADONA)919005-14-4 1633 ND 1ng/L3.421
1H,1H,2H,2H-Perfluorodecane sulfonic acid (8:2FTS)39108-34-4 1633 11 J 1ng/L3.121
1H,1H,2H,2H-Perfluorohexane sulfonic acid (4:2FTS)757124-72-4 1633 ND 1ng/L2.021
1H,1H,2H,2H-Perfluorooctane sulfonic acid (6:2FTS)27619-97-2 1633 47 1ng/L1026
2H,2H,3H,3H-Perfluorooctanoic acid (5:3FTCA)914637-49-3 1633 1000 1ng/L22130
Hexafluoropropylene oxide dimer acid (HFPO-DA)13252-13-6 1633 ND 1ng/L5.121
N-ethyl perfluorooctanesulfonamide (NEtFOSA)4151-50-2 1633 ND 1ng/L0.665.1
N-ethyl perfluorooctanesulfonamidoacetic acid (NEtFOSAA)2991-50-6 1633 45 1ng/L1.55.1
N-ethyl perfluorooctanesulfonamidoethanol (NEtFOSE)1691-99-2 1633 ND 1ng/L3.151
N-methyl perfluorooctanesulfonamide (NMeFOSA)31506-32-8 1633 ND 1ng/L1.15.1
N-methyl perfluorooctanesulfonamidoacetic acid (NMeFOSAA)2355-31-9 1633 18 1ng/L1.55.1
N-methyl perfluorooctanesulfonamidoethanol (NMeFOSE)24448-09-7 1633 ND 1ng/L3.251
Nonafluoro-3,6-dioxaheptanoic acid (NFDHA)151772-58-6 1633 ND 1ng/L3.010
Perfluoro(2-ethoxyethane)sulfonic acid (PFEESA)113507-82-7 1633 ND 1ng/L1.910
Perfluoro-3-methoxypropanoic acid (PFMPA)377-73-1 1633 1.3 J 1ng/L0.9510
Perfluoro-4-methoxybutanoic acid (PFMBA)863090-89-5 1633 ND 1ng/L2.010
Perfluorobutanesulfonic acid (PFBS)375-73-5 1633 36 1ng/L0.485.1
Perfluorobutanoic acid (PFBA)375-22-4 1633 230 1ng/L2.621
Perfluorodecanesulfonic acid (PFDS)335-77-3 1633 ND 1ng/L0.855.1
Perfluorodecanoic acid (PFDA)335-76-2 1633 3.7 J 1ng/L0.705.1
Perfluorododecanesulfonic acid (PFDoS)79780-39-5 1633 ND 1ng/L0.795.1
Perfluorododecanoic acid (PFDoA)307-55-1 1633 ND 1ng/L0.555.1
Perfluoroheptanesulfonic acid (PFHpS)375-92-8 1633 ND 1ng/L0.985.1
Perfluoroheptanoic acid (PFHpA)375-85-9 1633 130 1ng/L1.15.1
3-Perfluoroheptyl propanoic acid (7:3FTCA)812-70-4 1633 50 J 1ng/L21130
Perfluorohexanesulfonic acid (PFHxS)355-46-4 1633 120 1ng/L0.955.1
Perfluorohexanoic acid (PFHxA)307-24-4 1633 660 1ng/L0.735.1
Perfluorononanesulfonic acid (PFNS)68259-12-1 1633 ND 1ng/L0.755.1
Perfluorononanoic acid (PFNA)375-95-1 1633 8.0 1ng/L0.535.1
Perfluorooctanesulfonamide (PFOSA)754-91-6 1633 ND 1ng/L1.05.1
Perfluorooctanesulfonic acid (PFOS)1763-23-1 1633 17 1ng/L1.35.1
Perfluorooctanoic acid (PFOA)335-67-1 1633 230 1ng/L1.15.1
Perfluoropentanesulfonic acid (PFPeS)2706-91-4 1633 4.9 J 1ng/L1.35.1
Perfluoropentanoic acid (PFPeA)2706-90-3 1633 200 1ng/L0.9510
3-Perfluoropropyl propanoic acid (3:3FTCA)356-02-5 1633 60 1ng/L3.126
Perfluorotetradecanoic acid (PFTeDA)376-06-7 1633 ND 1ng/L1.45.1
Perfluorotridecanoic acid (PFTrDA)72629-94-8 1633 ND 1ng/L1.05.1
Perfluoroundecanoic acid (PFUnA)2058-94-8 1633 ND 1ng/L1.35.1
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 12 of 29
Page 17 of 34
PFAS by LC/MS/MS
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Pace Analytical Services, Inc.
LEACHATE
YJ16031-004
10/09/2023
10/14/2023
Aqueous
Project Name: Cherokee Lined PFAS
Project Number: 92692753
AcceptanceRun 1
Surrogate Q % Recovery Limits
13C2-4:2FTS 116 20-150
13C2-6:2FTS 116 20-150
13C2-8:2FTS 59 20-150
13C2-PFDoA 53 20-150
13C2-PFTeDA 58 20-150
13C3-HFPO-DA 82 20-150
13C3-PFBS 84 20-150
13C3-PFHxS 82 20-150
13C4-PFBA 83 20-150
13C4-PFHpA 81 20-150
13C5-PFHxA 83 20-150
13C5-PFPeA 84 20-150
13C6-PFDA 76 20-150
13C7-PFUnA 59 20-150
13C8-PFOA 82 20-150
13C8-PFOS 79 20-150
13C8-PFOSA 59 20-150
13C9-PFNA 79 20-150
D3-NMeFOSA 40 20-150
D3-NMeFOSAA 53 20-150
D5-NEtFOSA 36 20-150
D5-NEtFOSAA 48 20-150
D7-NMeFOSE 48 20-150
D9-NEtFOSE 45 20-150
J = Estimated result < LOQ and > DL_
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the DL N = Recovery is out of criteria
H = Out of holding time
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
DL = Detection Limit
W = Reported on wet weight basis
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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Page 18 of 34
QC Summary
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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PFAS by LC/MS/MS - MB
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-001
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Parameter Result Q LOQ DL Units Analysis DateDil
11Cl-PF3OUdS ND 11/07/2023 14434.0 0.87 ng/L1
9Cl-PF3ONS ND 11/07/2023 14434.0 0.67 ng/L1
ADONA ND 11/07/2023 14434.0 0.66 ng/L1
8:2FTS ND 11/07/2023 14434.0 0.61 ng/L1
4:2FTS ND 11/07/2023 14434.0 0.40 ng/L1
6:2FTS ND 11/07/2023 14435.0 2.0 ng/L1
5:3FTCA ND 11/07/2023 1443254.3 ng/L1
HFPO-DA ND 11/07/2023 14434.0 0.99 ng/L1
NEtFOSA ND 11/07/2023 14431.0 0.13 ng/L1
NEtFOSAA ND 11/07/2023 14431.0 0.29 ng/L1
NEtFOSE ND 11/07/2023 1443100.61 ng/L1
NMeFOSA ND 11/07/2023 14431.0 0.22 ng/L1
NMeFOSAA ND 11/07/2023 14431.0 0.29 ng/L1
NMeFOSE ND 11/07/2023 1443100.63 ng/L1
NFDHA ND 11/07/2023 14432.0 0.58 ng/L1
2-ethoxyethane)sulfonic acid (PFEESA ND 11/07/2023 14432.0 0.36 ng/L1
PFMPA ND 11/07/2023 14432.0 0.18 ng/L1
PFMBA ND 11/07/2023 14432.0 0.39 ng/L1
PFBS ND 11/07/2023 14431.0 0.094 ng/L1
PFBA ND 11/07/2023 14434.0 0.51 ng/L1
PFDS ND 11/07/2023 14431.0 0.16 ng/L1
PFDA ND 11/07/2023 14431.0 0.14 ng/L1
PFDoS ND 11/07/2023 14431.0 0.15 ng/L1
PFDoA ND 11/07/2023 14431.0 0.11 ng/L1
PFHpS ND 11/07/2023 14431.0 0.19 ng/L1
PFHpA ND 11/07/2023 14431.0 0.21 ng/L1
7:3FTCA ND 11/07/2023 1443254.2 ng/L1
PFHxS ND 11/07/2023 14431.0 0.18 ng/L1
PFHxA ND 11/07/2023 14431.0 0.14 ng/L1
PFNS ND 11/07/2023 14431.0 0.15 ng/L1
PFNA ND 11/07/2023 14431.0 0.10 ng/L1
PFOSA ND 11/07/2023 14431.0 0.20 ng/L1
PFOS ND 11/07/2023 14431.0 0.25 ng/L1
PFOA ND 11/07/2023 14431.0 0.21 ng/L1
PFPeS ND 11/07/2023 14431.0 0.26 ng/L1
PFPeA ND 11/07/2023 14432.0 0.18 ng/L1
3:3FTCA ND 11/07/2023 14435.0 0.60 ng/L1
PFTeDA ND 11/07/2023 14431.0 0.27 ng/L1
PFTrDA ND 11/07/2023 14431.0 0.19 ng/L1
PFUnA ND 11/07/2023 14431.0 0.25 ng/L1
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 86 20-150
13C2-6:2FTS 80 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 15 of 29
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PFAS by LC/MS/MS - MB
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-001
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 74 20-150
13C2-PFDoA 86 20-150
13C2-PFTeDA 87 20-150
13C3-HFPO-DA 94 20-150
13C3-PFBS 86 20-150
13C3-PFHxS 83 20-150
13C4-PFBA 89 20-150
13C4-PFHpA 94 20-150
13C5-PFHxA 89 20-150
13C5-PFPeA 90 20-150
13C6-PFDA 87 20-150
13C7-PFUnA 88 20-150
13C8-PFOA 93 20-150
13C8-PFOS 91 20-150
13C8-PFOSA 86 20-150
13C9-PFNA 89 20-150
D3-NMeFOSA 59 20-150
D3-NMeFOSAA 94 20-150
D5-NEtFOSA 60 20-150
D5-NEtFOSAA 84 20-150
D7-NMeFOSE 79 20-150
D9-NEtFOSE 77 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 16 of 29
Page 21 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-002
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
%Rec
LimitDil(ng/L)(ng/L)
11Cl-PF3OUdS 8.3 11/07/2023 14521107.6 40-1501
9Cl-PF3ONS 7.6 11/07/2023 14521027.5 40-1501
ADONA 8.5 11/07/2023 14521137.6 40-1501
8:2FTS 8.6 11/07/2023 14521127.7 40-1501
4:2FTS 8.2 11/07/2023 14521097.5 40-1501
6:2FTS 6.6 11/07/2023 1452877.6 40-1501
5:3FTCA 54 11/07/2023 14521085040-1501
HFPO-DA 8.5 11/07/2023 14521068.0 40-1501
NEtFOSA 2.1 11/07/2023 14521062.0 40-1501
NEtFOSAA 2.2 11/07/2023 14521102.0 40-1501
NEtFOSE 21 11/07/2023 14521072040-1501
NMeFOSA 2.1 11/07/2023 14521062.0 40-1501
NMeFOSAA 2.1 11/07/2023 14521062.0 40-1501
NMeFOSE 21 11/07/2023 14521062040-1501
NFDHA 5.0 11/07/2023 14521254.0 40-1501
2-ethoxyethane)sulfonic acid (PFEESA 3.8 11/07/2023 14521053.6 40-1501
PFMPA 4.5 11/07/2023 14521124.0 40-1501
PFMBA 4.1 11/07/2023 14521024.0 40-1501
PFBS 1.8 11/07/2023 1452991.8 40-1501
PFBA 7.5 11/07/2023 1452948.0 40-1501
PFDS 1.8 11/07/2023 1452951.9 40-1501
PFDA 1.9 11/07/2023 1452962.0 40-1501
PFDoS 1.9 11/07/2023 1452961.9 40-1501
PFDoA 2.2 11/07/2023 14521102.0 40-1501
PFHpS 1.9 11/07/2023 1452981.9 40-1501
PFHpA 1.9 11/07/2023 1452952.0 40-1501
7:3FTCA 48 11/07/2023 1452965040-1501
PFHxS 2.1 11/07/2023 14521181.8 40-1501
PFHxA 2.1 11/07/2023 14521052.0 40-1501
PFNS 1.9 11/07/2023 14521001.9 40-1501
PFNA 2.0 11/07/2023 1452982.0 40-1501
PFOSA 2.0 11/07/2023 1452992.0 40-1501
PFOS 2.0 11/07/2023 14521061.9 40-1501
PFOA 2.1 11/07/2023 14521072.0 40-1501
PFPeS 1.9 11/07/2023 14521001.9 40-1501
PFPeA 3.8 11/07/2023 1452954.0 40-1501
3:3FTCA 12 11/07/2023 14521181040-1501
PFTeDA 2.1 11/07/2023 14521042.0 40-1501
PFTrDA 2.0 11/07/2023 14521012.0 40-1501
PFUnA 2.2 11/07/2023 14521082.0 40-1501
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 83 20-150
13C2-6:2FTS 91 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 17 of 29
Page 22 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-002
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 75 20-150
13C2-PFDoA 87 20-150
13C2-PFTeDA 86 20-150
13C3-HFPO-DA 81 20-150
13C3-PFBS 86 20-150
13C3-PFHxS 82 20-150
13C4-PFBA 84 20-150
13C4-PFHpA 82 20-150
13C5-PFHxA 77 20-150
13C5-PFPeA 81 20-150
13C6-PFDA 89 20-150
13C7-PFUnA 88 20-150
13C8-PFOA 96 20-150
13C8-PFOS 80 20-150
13C8-PFOSA 77 20-150
13C9-PFNA 94 20-150
D3-NMeFOSA 42 20-150
D3-NMeFOSAA 85 20-150
D5-NEtFOSA 40 20-150
D5-NEtFOSAA 82 20-150
D7-NMeFOSE 68 20-150
D9-NEtFOSE 64 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 18 of 29
Page 23 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-102
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
%Rec
LimitDil(ng/L)(ng/L)
11Cl-PF3OUdS 89 11/07/2023 1501999140-1501
9Cl-PF3ONS 83 11/07/2023 1501929040-1501
ADONA 85 11/07/2023 1501949140-1501
8:2FTS 86 11/07/2023 1501949240-1501
4:2FTS 88 11/07/2023 1501989040-1501
6:2FTS 95 11/07/2023 15011049140-1501
5:3FTCA 560 11/07/2023 15019360040-1501
HFPO-DA 85 11/07/2023 1501889640-1501
NEtFOSA 24 11/07/2023 15011022440-1501
NEtFOSAA 25 11/07/2023 15011042440-1501
NEtFOSE 240 11/07/2023 150110024040-1501
NMeFOSA 24 11/07/2023 1501992440-1501
NMeFOSAA 22 11/07/2023 1501922440-1501
NMeFOSE 240 11/07/2023 15019824040-1501
NFDHA 49 11/07/2023 15011014840-1501
2-ethoxyethane)sulfonic acid (PFEESA 42 11/07/2023 1501984340-1501
PFMPA 53 11/07/2023 15011104840-1501
PFMBA 48 11/07/2023 15011004840-1501
PFBS 21 11/07/2023 1501972140-1501
PFBA 85 11/07/2023 1501889640-1501
PFDS 20 11/07/2023 1501862340-1501
PFDA 24 11/07/2023 15011002440-1501
PFDoS 21 11/07/2023 1501892340-1501
PFDoA 25 11/07/2023 15011052440-1501
PFHpS 21 11/07/2023 1501912340-1501
PFHpA 23 11/07/2023 1501972440-1501
7:3FTCA 540 11/07/2023 15018960040-1501
PFHxS 20 11/07/2023 1501932240-1501
PFHxA 22 11/07/2023 1501932440-1501
PFNS 21 11/07/2023 1501922340-1501
PFNA 23 11/07/2023 1501962440-1501
PFOSA 23 11/07/2023 1501972440-1501
PFOS 20 11/07/2023 1501912240-1501
PFOA 23 11/07/2023 1501972440-1501
PFPeS 20 11/07/2023 1501862340-1501
PFPeA 46 11/07/2023 1501964840-1501
3:3FTCA 130 11/07/2023 150110712040-1501
PFTeDA 24 11/07/2023 1501992440-1501
PFTrDA 23 11/07/2023 1501962440-1501
PFUnA 25 11/07/2023 15011042440-1501
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 92 20-150
13C2-6:2FTS 89 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 19 of 29
Page 24 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ89295-102
89295 1633
11/06/2023 1514Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 92 20-150
13C2-PFDoA 91 20-150
13C2-PFTeDA 92 20-150
13C3-HFPO-DA 94 20-150
13C3-PFBS 92 20-150
13C3-PFHxS 94 20-150
13C4-PFBA 90 20-150
13C4-PFHpA 92 20-150
13C5-PFHxA 91 20-150
13C5-PFPeA 89 20-150
13C6-PFDA 89 20-150
13C7-PFUnA 91 20-150
13C8-PFOA 96 20-150
13C8-PFOS 93 20-150
13C8-PFOSA 85 20-150
13C9-PFNA 86 20-150
D3-NMeFOSA 55 20-150
D3-NMeFOSAA 95 20-150
D5-NEtFOSA 51 20-150
D5-NEtFOSAA 92 20-150
D7-NMeFOSE 78 20-150
D9-NEtFOSE 75 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 20 of 29
Page 25 of 34
PFAS by LC/MS/MS - MB
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-001
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Parameter Result Q LOQ DL Units Analysis DateDil
11Cl-PF3OUdS ND 12/21/2023 1756204.4 ng/L1
9Cl-PF3ONS ND 12/21/2023 1756203.3 ng/L1
ADONA ND 12/21/2023 1756203.3 ng/L1
8:2FTS ND 12/21/2023 1756203.0 ng/L1
4:2FTS ND 12/21/2023 1756202.0 ng/L1
6:2FTS ND 12/21/2023 17562510ng/L1
5:3FTCA ND 12/21/2023 175613021ng/L1
HFPO-DA ND 12/21/2023 1756205.0 ng/L1
NEtFOSA ND 12/21/2023 17565.0 0.64 ng/L1
NEtFOSAA ND 12/21/2023 17565.0 1.5 ng/L1
NEtFOSE ND 12/21/2023 1756503.1 ng/L1
NMeFOSA ND 12/21/2023 17565.0 1.1 ng/L1
NMeFOSAA ND 12/21/2023 17565.0 1.5 ng/L1
NMeFOSE ND 12/21/2023 1756503.2 ng/L1
NFDHA ND 12/21/2023 1756102.9 ng/L1
2-ethoxyethane)sulfonic acid (PFEESA ND 12/21/2023 1756101.8 ng/L1
PFMPA ND 12/21/2023 1756100.92 ng/L1
PFMBA ND 12/21/2023 1756101.9 ng/L1
PFBS ND 12/21/2023 17565.0 0.47 ng/L1
PFBA ND 12/21/2023 1756202.6 ng/L1
PFDS ND 12/21/2023 17565.0 0.82 ng/L1
PFDA ND 12/21/2023 17565.0 0.68 ng/L1
PFDoS ND 12/21/2023 17565.0 0.77 ng/L1
PFDoA ND 12/21/2023 17565.0 0.53 ng/L1
PFHpS ND 12/21/2023 17565.0 0.95 ng/L1
PFHpA ND 12/21/2023 17565.0 1.1 ng/L1
7:3FTCA ND 12/21/2023 175613021ng/L1
PFHxS ND 12/21/2023 17565.0 0.92 ng/L1
PFHxA ND 12/21/2023 17565.0 0.71 ng/L1
PFNS ND 12/21/2023 17565.0 0.73 ng/L1
PFNA ND 12/21/2023 17565.0 0.52 ng/L1
PFOSA ND 12/21/2023 17565.0 0.99 ng/L1
PFOS ND 12/21/2023 17565.0 1.2 ng/L1
PFOA ND 12/21/2023 17565.0 1.0 ng/L1
PFPeS ND 12/21/2023 17565.0 1.3 ng/L1
PFPeA ND 12/21/2023 1756100.92 ng/L1
3:3FTCA ND 12/21/2023 1756253.0 ng/L1
PFTeDA ND 12/21/2023 17565.0 1.3 ng/L1
PFTrDA ND 12/21/2023 17565.0 0.97 ng/L1
PFUnA ND 12/21/2023 17565.0 1.2 ng/L1
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 84 20-150
13C2-6:2FTS 77 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 21 of 29
Page 26 of 34
PFAS by LC/MS/MS - MB
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-001
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 74 20-150
13C2-PFDoA 65 20-150
13C2-PFTeDA 65 20-150
13C3-HFPO-DA 83 20-150
13C3-PFBS 82 20-150
13C3-PFHxS 78 20-150
13C4-PFBA 82 20-150
13C4-PFHpA 88 20-150
13C5-PFHxA 80 20-150
13C5-PFPeA 83 20-150
13C6-PFDA 73 20-150
13C7-PFUnA 73 20-150
13C8-PFOA 79 20-150
13C8-PFOS 76 20-150
13C8-PFOSA 71 20-150
13C9-PFNA 82 20-150
D3-NMeFOSA 50 20-150
D3-NMeFOSAA 75 20-150
D5-NEtFOSA 53 20-150
D5-NEtFOSAA 72 20-150
D7-NMeFOSE 67 20-150
D9-NEtFOSE 66 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 22 of 29
Page 27 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-002
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
%Rec
LimitDil(ng/L)(ng/L)
11Cl-PF3OUdS 30 12/21/2023 18051003040-1501
9Cl-PF3ONS 32 12/21/2023 18051093040-1501
ADONA 36 12/21/2023 18051193040-1501
8:2FTS 37 12/21/2023 18051203140-1501
4:2FTS 33 12/21/2023 18051113040-1501
6:2FTS 33 12/21/2023 18051083040-1501
5:3FTCA 200 12/21/2023 18059920040-1501
HFPO-DA 33 12/21/2023 18051043240-1501
NEtFOSA 8.5 12/21/2023 18051068.0 40-1501
NEtFOSAA 8.3 12/21/2023 18051038.0 40-1501
NEtFOSE 85 12/21/2023 18051068040-1501
NMeFOSA 7.5 12/21/2023 1805948.0 40-1501
NMeFOSAA 8.6 12/21/2023 18051078.0 40-1501
NMeFOSE 86 12/21/2023 18051088040-1501
NFDHA 15 12/21/2023 1805941640-1501
2-ethoxyethane)sulfonic acid (PFEESA 15 12/21/2023 18051021440-1501
PFMPA 16 12/21/2023 1805971640-1501
PFMBA 16 12/21/2023 18051001640-1501
PFBS 7.4 12/21/2023 18051057.1 40-1501
PFBA 35 12/21/2023 18051083240-1501
PFDS 7.7 12/21/2023 18051007.7 40-1501
PFDA 11 12/21/2023 18051378.0 40-1501
PFDoS 7.0 12/21/2023 1805907.8 40-1501
PFDoA 9.1 12/21/2023 18051148.0 40-1501
PFHpS 8.6 12/21/2023 18051137.6 40-1501
PFHpA 8.6 12/21/2023 18051088.0 40-1501
7:3FTCA 200 12/21/2023 180510120040-1501
PFHxS 7.4 12/21/2023 18051017.3 40-1501
PFHxA 8.0 12/21/2023 18051008.0 40-1501
PFNS 8.5 12/21/2023 18051107.7 40-1501
PFNA 8.7 12/21/2023 18051098.0 40-1501
PFOSA 8.4 12/21/2023 18051058.0 40-1501
PFOS 6.7 12/21/2023 1805907.4 40-1501
PFOA 7.5 12/21/2023 1805938.0 40-1501
PFPeS 7.6 12/21/2023 18051017.5 40-1501
PFPeA 17 12/21/2023 18051041640-1501
3:3FTCA 38 12/21/2023 1805964040-1501
PFTeDA 9.0 12/21/2023 18051138.0 40-1501
PFTrDA 8.0 12/21/2023 18051008.0 40-1501
PFUnA 8.5 12/21/2023 18051078.0 40-1501
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 74 20-150
13C2-6:2FTS 71 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 23 of 29
Page 28 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-002
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 66 20-150
13C2-PFDoA 67 20-150
13C2-PFTeDA 58 20-150
13C3-HFPO-DA 81 20-150
13C3-PFBS 74 20-150
13C3-PFHxS 74 20-150
13C4-PFBA 78 20-150
13C4-PFHpA 82 20-150
13C5-PFHxA 82 20-150
13C5-PFPeA 84 20-150
13C6-PFDA 70 20-150
13C7-PFUnA 68 20-150
13C8-PFOA 73 20-150
13C8-PFOS 77 20-150
13C8-PFOSA 73 20-150
13C9-PFNA 75 20-150
D3-NMeFOSA 54 20-150
D3-NMeFOSAA 79 20-150
D5-NEtFOSA 57 20-150
D5-NEtFOSAA 74 20-150
D7-NMeFOSE 68 20-150
D9-NEtFOSE 66 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

Page 24 of 29
Page 29 of 34
PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-102
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
%Rec
LimitDil(ng/L)(ng/L)
11Cl-PF3OUdS 360 12/21/2023 181410036040-1501
9Cl-PF3ONS 400 12/21/2023 181411036040-1501
ADONA 430 12/21/2023 181411736040-1501
8:2FTS 430 12/21/2023 181411637040-1501
4:2FTS 420 12/21/2023 181411836040-1501
6:2FTS 440 12/21/2023 181412136040-1501
5:3FTCA 2400 12/21/2023 1814100240040-1501
HFPO-DA 420 12/21/2023 181410938040-1501
NEtFOSA 110 12/21/2023 18141129640-1501
NEtFOSAA 100 12/21/2023 18141079640-1501
NEtFOSE 1100 12/21/2023 181411596040-1501
NMeFOSA 110 12/21/2023 18141139640-1501
NMeFOSAA 100 12/21/2023 18141089640-1501
NMeFOSE 1100 12/21/2023 181411796040-1501
NFDHA 210 12/21/2023 181411119040-1501
2-ethoxyethane)sulfonic acid (PFEESA 190 12/21/2023 181410917040-1501
PFMPA 220 12/21/2023 181411419040-1501
PFMBA 210 12/21/2023 181411119040-1501
PFBS 90 12/21/2023 18141068540-1501
PFBA 440 12/21/2023 181411538040-1501
PFDS 100 12/21/2023 18141089340-1501
PFDA 110 12/21/2023 18141199640-1501
PFDoS 85 12/21/2023 1814929340-1501
PFDoA 120 12/21/2023 18141229640-1501
PFHpS 100 12/21/2023 18141149140-1501
PFHpA 110 12/21/2023 18141159640-1501
7:3FTCA 2200 12/21/2023 181491240040-1501
PFHxS 100 12/21/2023 18141198840-1501
PFHxA 110 12/21/2023 18141159640-1501
PFNS 110 12/21/2023 18141169240-1501
PFNA 110 12/21/2023 18141149640-1501
PFOSA 110 12/21/2023 18141169640-1501
PFOS 99 12/21/2023 18141118940-1501
PFOA 110 12/21/2023 18141129640-1501
PFPeS 120 12/21/2023 18141309040-1501
PFPeA 220 12/21/2023 181411519040-1501
3:3FTCA 480 12/21/2023 18149948040-1501
PFTeDA 120 12/21/2023 18141209640-1501
PFTrDA 99 12/21/2023 18141039640-1501
PFUnA 110 12/21/2023 18141149640-1501
Surrogate Q % Rec
Acceptance
Limit
13C2-4:2FTS 82 20-150
13C2-6:2FTS 79 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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PFAS by LC/MS/MS - LCS
Batch:Prep Method:
Prep Date:
Sample ID:YQ91287-102
91287 1633
12/01/2023 1728Analytical Method:1633
Matrix:Aqueous
Surrogate Q % Rec
Acceptance
Limit
13C2-8:2FTS 70 20-150
13C2-PFDoA 67 20-150
13C2-PFTeDA 55 20-150
13C3-HFPO-DA 82 20-150
13C3-PFBS 83 20-150
13C3-PFHxS 78 20-150
13C4-PFBA 81 20-150
13C4-PFHpA 79 20-150
13C5-PFHxA 82 20-150
13C5-PFPeA 80 20-150
13C6-PFDA 73 20-150
13C7-PFUnA 71 20-150
13C8-PFOA 76 20-150
13C8-PFOS 79 20-150
13C8-PFOSA 73 20-150
13C9-PFNA 83 20-150
D3-NMeFOSA 56 20-150
D3-NMeFOSAA 76 20-150
D5-NEtFOSA 57 20-150
D5-NEtFOSAA 73 20-150
D7-NMeFOSE 69 20-150
D9-NEtFOSE 69 20-150
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
LOQ = Limit of Quantitation ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria
_DL = Detection Limit
* = RSD is out of criteria
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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Chain of Custody
and
Miscellaneous Documents
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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PACE ANALYTICAL SERVICES, LLC

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)

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