1809_DukeMarshall FGD LF GWMR_Q3_2023_FID_20240107

DUKE
�, ENERGY-
January 7, 2024
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. Highway 70
Swannanoa, NC 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semiannual Water Quality Monitoring Report — September 2023
Flue Gas Desulfurization Landfill
Permit No.: 1809-INDUS-2006
Marshall Steam Station
Terrell, North Carolina 28682
Dear Ms. Moutos:
525 N. Tryon St.
Charlotte NC, 28202
Duke Energy is providing the result of the semiannual water quality monitoring for the Duke Energy
Carolinas, Marshall Steam Station, Flue Gas Desulfurization (FGD) Landfill, located near Terrell,
North Carolina.
On September 11, 2023, leachate and groundwater samples were collected in accordance with the
facility's Water Quality Monitoring Plan (WQMP) approved July 24, 2019, and the updated parameter
and constituent list, approved March 20, 2023. Field sampling forms, chain of custody (COC) forms,
and laboratory reports are included in Appendix A and B.
The leachate sampling field and analytical results are presented in Table 5. Leachate analytical
results are not compared to groundwater or surface water quality standards and are provided for
informational purposes only.
A summary of the groundwater sampling field and analytical results are presented in Table 6. The
analytical results for the constituents are compared to the groundwater standards found in Title 15A
NCAC 02L .0202 (21- Standards). Results with values that are equal to or greater than the 2L
Standards are indicated on Table 6 by bold font. A summary of the analytical results that are equal
to or greater than the 2L Standards and a preliminary analysis of the cause and significance of such
occurrences are presented in Table 7.
Leachate, groundwater, and surface water locations at the Marshall FGD Landfill are sampled
semiannually during March and September. The next water quality monitoring event is planned for
March 2024 with a report of monitoring results to follow.
If you need additional information regarding this submittal do not hesitate to email or call me at
Ashley. Healy(a)duke-energy.com or [phone].
www.duke-energy.com Page 1 of 2

Respectfully,
Ashley Healy, P.G.
Environmental Services
Attachments: INDUS-1809 Marshall FGD LF GW Monitoring Report September 2023_01-07-2024 w
cvr Itr
cc (via e-mail): Claire Osborn, NCDEQ
Elizabeth Werner, NCDEQ
Sherri Stanley, NCDEQ
Ed Mussler, NCDEQ
Dan Zakary, Duke Energy
Scott La Sala, Duke Energy
Tyler Hardin, Duke Energy
Thomas Colton, SynTerra
www.duke-energy.com Page 2 of 2

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Duke Energy Carolinas, LLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Thomas Colton
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 8320 East NC-150
Marshall Steam Station Terrell, North Carolina 28682 �1809 .0500 September 11. 2023
Flue Gas Desulfurization Residue
Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Assessment Monitoring
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
❑ Corrective Action
Notification attached?
❑
)( No. No groundwater or surface water standards were exceeded.
Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Kathy Webb Program Manager [phone]
Facility Representative Name (Print) Title (Area Code) Telephone Number
KIA, 1/5/2024
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009)
Affix NC Licensed/ Professional Geologist Seal
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
FLUE GAS DESULFURIZATION RESIDUE LANDFILL
PERMIT NO. 1809-INDUS
TITLE: SEMIANNUAL WATER QUALITY MONITORING REPORT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: �, Date
1/5/2024
� I
Approved by: C� Date: 1/5/2024
Project Manager: G. Thomas Colton, PE
Licensed Geologist Seal:
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
SEPTEMBER 2023 SAMPLING EVENT
FLUE GAS DESULFURIZATION RESIDUE LANDFILL
PERMIT NO. 1809-INDUS)
CATAWBA COUNTY
MARSHALL STEAM STATION
8320 NC HIGHWAY 150E
TERRELL, NORTH CAROLINA
JANUARY 2024
PREPARED FOR
r� DUKE
ENERGY,:
CAROLINAS
DUKE ENERGY CAROLINAS, LLC
Kathy Webb, L.G. #1328 Kevin ei ly
Senior Peer Reviewer Projec Scien st
Thomas Colton, P.E.#056667
Project Manager

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0 INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1 Site and Landfill Information......................................................................................1-1
1.2 Hydrogeologic Setting................................................................................................1-1
1.3 Landfill Semiannual Monitoring Program...................................................................1-2
2.0 METHODS.................................................................................................................. 2-1
2.1 Sampling and Analysis Methods.................................................................................2-1
2.2 Regulatory Criteria.....................................................................................................2-1
2.3 Statement of Work.....................................................................................................2-1
3.0 RESULTS.....................................................................................................................3-1
3.1 Site Groundwater Flow...............................................................................................3-1
3.2 Analytical Results.......................................................................................................3-1
3.3 Quality Assurance/Quality Control.............................................................................3-2
4.0 REFERENCES...............................................................................................................4-1
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
Figure 3 Water -level Map — Surficial Flow Zone — September 2023
LIST OF TABLES
Table 1 Well Construction Summary
Table 2 Monitoring Parameters
Table 3 Monitoring Location Summary
Table 4 Groundwater Seepage Velocities
Table 5 Leachate Results and Analytical Detections
Table 6 Groundwater Field Results and Analytical Detections
Table 7 Field and Analytical Results that Greater Than or Equal to Groundwater Quality
Standards
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
Appendix C Time Versus Constituent Concentrations Plots
January 2024 Page i
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
LIST OF ACRONYMS
02B
Title 15A NCAC, Subchapter 02B .0200, Surface Water and Wetland
Standards
02L
Title 15A NCAC, Subchapter 02L .0202(g), Groundwater Quality Standards
Duke Energy
Duke Energy Carolinas, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
FGD
Flue Gas Desulfurization
Landfill
Dry Ash Landfill
Marshall
Marshall Steam Station
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
Piedmont
Piedmont physiographic province
PTO
permit to operate
Site
Marshall Steam Station
SWS
Solid Waste Section
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
January 2024 Page H
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
This semiannual report pertains to the Duke Energy Carolinas, LLC (Duke Energy) Marshall
Steam Station (Marshall or Site) Flue Gas Desulfurization (FGD) Residue Landfill (Landfill) and
documents the results of the September 2023 FGD Landfill groundwater, surface water, and
leachate monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates Marshall Steam Station, located at 8320 NC Highway 150E in
Terrell, Catawba County, North Carolina (Figure 1).
The North Carolina Department of Environmental Quality (NCDEQ) Division of Waste
Management (DWM) issued a permit to operate (PTO) the FGD Residue Landfill (Landfill; No.
1809 - INDUS) on November 21, 2006. Closure activities began in July 2018 and were completed
in March 2019; the Closure Permit was issued on June 30, 2020. The Landfill encompasses an
18-acre landfill footprint. The FGD Residue Landfill is constructed with a leachate collection and
removal system and an engineered liner system to prevent effects on groundwater.
1.2 Hydrogeologic Setting
The Landfill site is located within the Piedmont physiographic province (Piedmont). Piedmont
bedrock primarily consists of igneous and metamorphic bedrock. The fractured bedrock is
overlain by a mantle of unconsolidated material known as regolith. The regolith includes, where
present, the soil zone, a zone of weathered, decomposed bedrock known as saprolite, and
alluvium. Saprolite, the product of chemical and mechanical weathering of the underlying
bedrock, is typically composed of clay and coarser granular material up to boulder size and may
reflect the texture of the rock from which it was formed. The weathering product of granitic
rocks may be quartz -rich and sandy -textured, whereas rocks poor in quartz and rich in feldspar
and other soluble minerals form a more clayey saprolite.
Groundwater at the Site typically occurs in three interconnected flow zones. The shallowest
groundwater flow zone — the surficial flow zone — occurs in the residual soil and/or the upper
section of saprolite. Beneath the surficial flow zone, the transition zone flow zone occurs in the
lower portions of the saprolite and partially weathered bedrock and is the most permeable part
of the Site hydrogeologic system. Bedrock underlies the transition zone and comprises the least
permeable flow zone of the Site hydrogeologic system, where groundwater flow occurs
predominantly along fractures, joints, and faults. Groundwater is usually first encountered in
the surficial flow zone.
Groundwater flows to the south and emerges in a discharge zone. The water flows from the
discharge zone to an unnamed tributary that ultimately flows to Lake Norman. The surface
water classification of Lake Norman is WS-IV.
January 2024 Page 1-1
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
1.3 Landfill Semiannual Monitoring Program
The initial Water Quality Monitoring Plan (WQMP) (Altamont, 2006) has been revised over time
to incorporate changes. The March 2023 sampling event and this Semiannual Water Quality
Monitoring Report comply with WQMP, Revision 2 (Wood, 2019) submitted to the DWM on
July 24, 2019. The Landfill semiannual monitoring program, described in detail in the WQMP,
consists of nine groundwater monitoring locations, one surface water monitoring location, and
one leachate monitoring location (Table 3 and Figure 2). A summary of monitoring well
construction information is presented in Table 1, and analytical parameter coverage for the
Landfill semiannual water quality monitoring program is summarized in Table 2.
January 2024 Page 1-2
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Duke Energy Groundwater Science Group personnel (Duke Energy North Carolina Field
Certification #5193) performed groundwater sampling on September 11, 2023, in accordance
with the North Carolina Solid Waste Management Guidelines. Copies of the field sampling
forms are included in Appendix A. Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248) analyzed the samples for reported parameters and constituents.
The laboratory report and chain -of -custody forms are included in Appendix B.
Duke Energy developed a list of parameters and constituents using guidance from the NCDEQ
DWM, Solid Waste Section (SWS). The samples were analyzed using the updated parameter and
constituent list, approved by NCDEQ on March 20, 2023. The monitoring parameters, along
with the U.S. Environmental Protection Agency (USEPA) Solid Waste (SW)-846 analytical
methods, Title 15A, North Carolina Administrative Code (NCAC), Subchapter 02L .0202(g)
Groundwater Quality Standards (02L), and Title 1SA, NCAC, Subchapter 02B .0200, Surface
Water and Wetland Standards (0213) are presented in Table 2.
2.2 Regulatory Criteria
Semiannual monitoring analytical results were compared to the following regulatory criteria:
Grnundwater
• 02L standard
Surface water
• 02B standard
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Collected groundwater, surface water, and leachate samples on September 11, 2023.
• Reviewed the laboratory analytical results pertaining to the parameters listed in Table 2.
• Compared groundwater analytical results to the 02L standard and historical
concentration ranges.
• Developed generalized groundwater surface contour maps using groundwater elevation
data. Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Converted the laboratory -provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of the EDDs to
the NCDEQ DWM with this report.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
January 2024 Page 2-1
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
3.1 Site Groundwater Flow
Groundwater flow in the aquifer beneath the Landfill footprint generally flows to the east and
southeast beneath the landfill, toward the Ash Basin and Lake Norman.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the Landfill are shown on Figure 3 for the shallow flow zone. Those contours were
developed by calculating groundwater elevations in each monitoring well using the depth -to -
water measurements taken during the September 2023 monitoring event. Depth -to -water
measurements and calculated groundwater elevations are presented in Table 1. Calculated
groundwater flow velocities are presented in Table 4. Calculated groundwater elevations based
on depth -to -water measurements gauged during the September 2023 water -level sweep
indicate groundwater at the Landfill generally flows to the east-southeast, consistent with
historical Site observations.
3.2 Analytical Results
Analytical results and reference comparisons discussed below are summarized in Table 5
through Table 8. Sample locations are depicted on Figure 2.
Leachate
A leachate sample was collected from C-1 on the east side of the Landfill. Analytical results are
presented in Table S. Leachate analytical results are not compared to groundwater (02L) or
surface water (02B) quality standards and are provided for informational purposes only.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 6. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than 02L standards are noted in
Table 6 in bold font. The laboratory analytical reports are included in Appendix B. A summary
of the downgradient groundwater field and analytical results that are equal to or greater than
applicable comparison criteria is presented in Table 7. Constituent concentrations greater than
their applicable comparative criteria are within the historical range. The concentrations and
historical range are demonstrated in Appendix C.
Surface Water
The sample location, SW-1, is shown on Figure 2. Surface water was not sampled during the
reporting period because SW-1 was dry. Analytical results for the surface water sample, when
available, are compared with applicable 02B Class C and WS-IV surface water standards.
January 2024 Page 3-1
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
3.3 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of a field blank to evaluate if contamination was imparted to the samples by the
sample container, preservative, or other exogenous sources. A field duplicate sample was also
collected to estimate sampling and laboratory precision.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are in the lab report in Appendix B. Additional QA/QC data, laboratory
analyses, and chain -of -custody forms are included in Appendix B.
January 2024 Page 3-2
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
LIKIM."".4401"I
Altamont. (Rev 0, 2006). Water Quality Monitoring Plan, Marshall Flue Gas Desulfurization
Residue Landfill, November 2006.
Wood. (Rev 2, 2019). Water Quality Monitoring Plan, Marshall Flue Gas Desulfurization Residue
Landfill, July 2019.
January 2024 Page 4-1
Project: 00.0083.61

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
FIGURES
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Science & Engineering Consultants

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NOTES:
1. FGD - FLUE GAS DESULFURIZATION
2. ALL BOUNDARIES ARE APPROXIMATE.
3. AERIAL IMAGERY IN THE AREA OF INTEREST IS A COMBINATION OF DUKE ENERGY
PROPELLER PHOTOGRAPHY COLLECTED ON MARCH 31, 2023 AND SEPTEMBER 11, 2023.
BACKGROUND AERIAL IMAGERY PROVIDED BY ESRI, COLLECTED ON MARCH 20, 2022.
FIGURE 1
DUKE
ENERGY®
CATAWBA
COUNTY
WINSTON-SAIEM
SITE LOCATION MAP
SEPTEMBER 2023 SAMPLING EVENT
FGD RESIDUE LANDFILL
CAROLINAS
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE
CHARLOTTE
MARSHALL STEAM STATION
TERRELL, NORTH CAROLINA
DRAWN BV_ T KING DATE 05/15/2019
REVISED 8Y L FORE
O'RMAN DATE12/26/2023
CRECEDBYK LDATE: 12/26/2023
1,000 0 1,002,000
synTerra
DATE: 12/26/2023
PROJECT MANAGER: T. COLTON
GRAPHIC SCALE (IN FEET)
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LEGEND
GROUNDWATER MONITORING WELL
■
SURFACE WATER SAMPLE LOCATION
A
LEACHATE SAMPLE LOCATION
— - —
LANDFILL REVIEW BOUNDARY
LANDFILL LIMIT OF WASTE
LANDFILL COMPLIANCE BOUNDARY
ASH BASIN WASTE BOUNDARY
— - DUKE ENERGY CAROLINAS PROPERTY LINE
)o STREAM (MCKIM & CREED 2016)
f
WETLAND (MCKIM & CREED 2016)
MS-14
'•3.
^I.
.'1
NOTES:
`
1. FGD - FLUE GAS DESULFURIZATION.
A
2. THE STREAMS AND WETLANDS JURISDICTIONAL DETERMINATION WAS APPROVED
BY THE US ARMY CORPS OF ENGINEERS ON OCTOBER 25, 2017 (SAW-2015-01412).
WETLANDS AND STREAMS BOUNDARIES WERE OBTAINED FROM AMEC FOSTER
WHEELER ENVIRONMENTALAND INFRASTRUCTURE, INC. NATURAL RESOURCES
TECHNICAL REPORT (NRTR) DATED JUNE 2015.
3. SAMPLE LOCATIONS WERE DERIVED FROM VARIOUS SOURCES AND ARE A MIX OF
SURVEYED AND APPROXIMATE LOCATIONS. THFRFFORF SAMPI F I OCATIONS ARF TO RF
4DUKE
ENERGY®
CAROLINAS
DEEMED APPROXIMATE.
4. ALL BOUNDARIES ARE APPROXIMATE
5. AERIAL IMAGERY ISACOMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON MARCH 31, 2023 AND AERIAL IMAGERY PROVIDED BY ESRI, COLLECTED ON
�:-
MARCH 20, 2022.
6. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
,.�'•,-^ �.-S
COORDINATE SYSTEM RIPS 3200 (NAD83).
GRAPHIC SCALE
FIGURE 2
160 0 160 320
SAMPLE LOCATION MAP
(IN FELT)
SEPTEMBER 2023 SAMPLING EVENT
DRAWN BY: T. KING DATE: 02/03/2021
FGD RESIDUE LANDFILL
REVISED FOREMAN DATE 12/26/2023
SEMIANNUAL WATER QUALITY MONITORING REPORT
CHECKED BY: K. O'REILLY DATE: 12/26/2023
CHECKED BY.
APPROVED BYTCOLTON DATE12/2612023
MARSHALL STEAM STATION
PROJECT MANAGER ICOLTON
TERRELL, NORTH CAROLINA
www.s nterracor .com
P:\DARCGIS PROPROJECTS\DUKE ENERGY\MARSHALL\2023\SEMIANNUAL
WATEROUALITYM ONITORI N GREPORT\SEMAN NUAL WATEROUALITYMON ITOR I HG REPORT APRX

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LEGEND
GROUNDWATER MONITORING WELL
GROUNDWATER FLOW DIRECTION
INFERRED GROUNDWATER CONTOUR (NAVD88)
R
S ` _ A LEACHATE SAMPLE LOCATION
LANDFILL LIMIT OF WASTE
■ }, y I ' MS-15
I811.22 — - — LANDFILL REVIEW BOUNDARY
LANDFILL COMPLIANCE BOUNDARY
o � MS-11 �'►
z' 1 824.32 ASH BASIN WASTE BOUNDARY
.•,�- . . — - DUKE ENERGY CAROLINAS PROPERTY LINE
STREAM (MCKIM & CREED 2016)
WETLAND (MCKIM & CREED 2016)
TOPOGRAPHIC CONTOUR (10' INTERVAL)
07 63 NOTES:
.1. WATER LEVELS GAUGED SEPTEMBER 11, 2023.
�. `T.: ' 2. FGD - FLUE GAS DESULFURIZATION.
0 «. 3. THE STREAMS AND WETLANDS JURISDICTIONAL DETERMINATION WAS APPROVED
'"` • BY THE US ARMY CORPS OF ENGINEERS ON OCTOBER 25, 2017 (SAW-2015-01412).
MS-13 WETLANDS AND STREAMS BOUNDARIES WERE OBTAINED FROM AMEC FOSTER
HOLDING 810.69 WHEELER ENVIRONMENTALAND INFRASTRUCTURE, INC. NATURAL RESOURCES
BASIN TECHNICAL REPORT (NRTR) DATED JUNE 2015.
w -
_ n '' 4. SAMPLE LOCATIONS WERE DERIVED FROM VARIOUS SOURCES ANDAREAMIX OF
SURVEYED AND APPROXIMATE LOCATIONS. THEREFORE, SAMPLE LOCATIONS ARE TO BE
DEEMED APPROXIMATE.
♦ L 812.10
5. ALL BOUNDARIES ARE APPROXIMATE.
A T •+Y 1 6. AERIAL IMAGERY IS ACOMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON MARCH 31, 2023 AND AERIAL IMAGERY PROVIDED BY ESRI, COLLECTED ON
MARCH 20, 2022.
• 7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
- _ - COORDINATE SYSTEM RIPS 3200 (NAD83).
' GRAPHIC SCALE FIGURE 3
>so o is0 320
h° ENERGY WATER LEVEL MAP - SURFICIAL FLOW ZONE
CAROLINAS (IN FEET) SEPTEMBER 2023 SAMPLING EVENT
DRAWN BYTKING DATE02/03/2021 FGD RESIDUE LANDFILL
FIEVI5EDBY L FOREMAN DATE 12/26/2023 SEMIANNUAL WATER QUALITY MONITORING REPORT
�' - Q i • - - �� CHECKED BY: K. O'REILLY DATE_ 12/26/2023
860 APPROVED BY T COLTON DATE 12/26/2023 MARSHALL STEAM STATION
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Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
TABLES
L7
synTerra
Science & Engineering Consultants

TABLE 1
WELL CONSTRUCTION SUMMARY
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Well ID
Date
Installed
Flow
Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(Ft, BTOQ
Screened
Interval
(Ft, BGS)
Measuring
Point TOC
(Ft, NAVD 88)
Ground
Surface
(Ft, NAVD 88)
Groundwater
Elevation
(Ft, NAVD 88)
Depth to
Water
(Ft, BTOC)
MS-8*
9/12/2006
Shallow
PVC
2
35.6064200
-80.9782600
48.0
38 - 48
872.34
869.35
826.03
46.31
MS-9
1/16/2003
Shallow
PVC
2
35.6061300
-80.9776900
50.0
40 - 50
868.04
865.36
824.79
43.25
MS-10
7/8/2003
Shallow
PVC
2
35.6051100
-80.9795500
20.0
44 - 54
851.29
848.29
832.09
19.20
MS-11
7/9/2003
Shallow
PVC
2
35.6031100
-80.9797000
39.0
29 - 39
859.78
856.87
824.32
35.46
MS-12
2/11/2003
Shallow
PVC
2
35.6010500
-80.9778900
27.0
17 - 27
835.66
832.70
812.1
23.56
MS-13
12/17/2002
Shallow
PVC
2
35.6016100
-80.9765100
38.0
28 - 38
841.90
839.19
810.69
31.21
MS-14
1/7/2003
Shallow
PVC
2
35.6022900
-80.9744300
41.0
31- 41
844.07
841.27
807.63
36.44
MS-15
12/3/2002
Shallow
PVC
2
35.6035300
-80.9749200
53.6
43.6 - 53.6
854.28
851.86
811.22
43.06
MS-16
9/11/2006
Shallow
PVC
2
35.6054800
-80.9766600
34.0
24 - 34
836.98
834.25
810.18
26.80
Notes:
* - Indicates background groundwater monitoring well.
Groundwater elevations are based on data collected in September 11, 2023.
BGS - Below ground surface
BTOC - Below top of casing
Ft - Feet
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988
PVC - Polyvinylchloride
TOC - Top of casing
Revised by: TAW Checked by: CSM
Page 1 of 1

TABLE 2
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2023 SAMPLING EVENT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Constituent
Units
Analytical Methods
15A NCAC 02L
Standards for
Groundwater
15A NCAC 02B
Standards, ISTV, and
USEPA Criteria for
Surface Water
In Situ Parameters
Field pH
S.U.
Multi -Parameter Water Quality Meter
6.5-8.5
6.0-9.0
Field Specific Conductance
[10/cm
Multi -Parameter Water Quality Meter
NE
NE
Field Temperature
degrees Celsius
Multi -Parameter Water Quality Meter
NE
<_ 32
Field Dissolved Oxygen
mg/L
Multi -Parameter Water Quality Meter
NE
>_ 4
Field Oxidation Reduction Potential
mV
Multi -Parameter Water Quality Meter
NE
NE
Field Turbidity
NTU
Turbidimeter
NE
Streams <_ 50
Water Level
feet
Water Level Meter
NE
NE
Laboratory Analyses
Antimony
µg/L
EPA 200.8 / SW 6020E
1
5,300#
Arsenic
µg/L
EPA 200.8 / SW 6020B
10
10
Barium
µg/L
EPA 200.7 / SW 6010D
700
1,000
Beryllium
µg/L
EPA 200.8 / SW 6020B
4
NE
Beryllium (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
65^
Boron
µg/L
EPA 200.7 / SW 6010D
700
34,000#
Cadmium
µg/L
EPA 200.8 / SW 6020E
2
NE
Cadmium (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
0.75^'t
Calcium
mg/L
EPA 200.7 / SW 6010D
NE
NE
Chloride
mg/L
EPA 300.0 / EPA 9056A
250
230
Chromium
µg/L
EPA 200.8 / SW 6020E
10
NE
Chromium (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
NE
Cobalt
µg/L
EPA 200.8 / SW 6020E
1
3
Copper
µg/L
EPA 200.8 / SW 6020B
1,000
1,300*
Copper (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
3.6"'t
Fluoride
mg/L
EPA 300.0 / EPA 9056A
2
1.8
Iron
µg/L
EPA 200.7 / SW 6010D
300
1,000*
Lead
µg/L
EPA 200.8 / SW 6020B
15
NE
Lead (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
14A't
Lithium
µg/L
EPA 200.7 / SW 6010D
NE
NE
Magnesium
mg/L
EPA 200.7 / SW 6010D
NE
NE
Manganese
µg/L
EPA 200.7 / SW 6010D
50
50*
Mercury
µg/L
EPA 245.1 / SW 7470A
1
0.012
Molybdenum
µg/L
EPA 200.8 / SW 6020B
NE
160#
Nickel
µg/L
EPA 200.8 / SW 6020E
100
25
Nickel (dissolved)
µg/L
EPA 200.8 / SW 6020B
NE
145^'t
Nitrate
mg/L
EPA 300.0 / EPA 9056A
10
10
Selenium
µg/L
EPA 200.8 / SW 6020B
20
170*
Selenium (dissolved)
µg/L
EPA 200.8 / SW 6020E
NE
3.1&
Silver
µg/L
EPA 200.8 or SW 6020A
20
NE
Silver (dissolved)
µg/L
EPA 200.8 or SW 6020A
NE
0.30A't
Sulfate
mg/L
EPA 300.0 / EPA 9056A
250
250
Thallium
µg/L
EPA 200.8 / SW 6020E
2
2$
Total Dissolved Solids
mg/L
SM 2540C / EPA 160.1 / ASTM D5907
500
NE
Total Hardness
mg/L
Calculation (2.497 (calcium) + 4.118 (magnesium))
NE
100
Vanadium
µg/L
EPA 200.8 / SW 6020B
7
NE
Zinc
µg/L
EPA 200.7 / SW 6010D
1,000
7,400*
Zinc (dissolved)
µg/L
EPA 200.7 / SW 6010D
NE
36.2"
Prepared by: GTC Checked by: DAA TWL
Notes:
Constituents analyzed in the WQMP were approved by NCDEQ on March 20, 2023.
15A NCAC 02L Standards for Groundwater - North Carolina Class GA Standards found in 15A NCAC 02L .0202 Groundwater Quality Standards (effective April 1, 2022).
15A NCAC 02B Standards for Surface Water - 15A NCAC 02B Standards for Class WS-IV surface waters. North Carolina surface water and wetland standards (effective September 1, 2022).
ISTV for Surface Water - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria for Surface Water - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
Dissolved constituents are applicable to surface water analytical parameters only.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or
Fish Consumption value.
"- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not
automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening
purposes only.
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
&- Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
EPA - Environmental Protection Agency
µg/L - micrograms per liter
µfa/cm - micro -ohms per centimeter
mg/L - milligrams per liter
mV - millivolts
NCDEQ- North Carolina Department of Environmental Quality
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
SW - Solid Waste
Page 1 of 1

TABLE 3
MONITORING LOCATION SUMMARY
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Media
Monitoring Location ID
Comments
MS-8 is located upgradient of the
landfill and serves as a background
MS-8
water quality monitoring well. See
Table 1 Well Construction Summary
for background monitoring well
construction information.
Groundwater
MS-9
MS-10
MS-11
See Table 1 Well Construction
Summary for monitoring well
MS-12
MS-13
construction information.
MS-14
MS-15
MS-16
Surface water monitoring locations in
Surface Water
SW-1
tributary south of the landfill (sampled
if flow is present during semi-annual
monitoring).
Leachate sample, representing
Leachate
C-1 Leachate
leachate from the entire landfill,
collected from sampling point in
collection system east of the landfill.
Prepared by: GTC Checked by: DAA
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Shallow and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Effective
Velocity
Well ID
Elevation
Elevation
(ft/day)1
(ft)
(ft)
PorosityZ
2
(ft/day)
(ft, NAVD 88)
(ft, NAVD 88)
MS-10 to MS-14
832.09
807.63
0.71
24.46
559
0.2765
0.111
MS-11 to MS-13
824.32
810.69
0.71
13.63
333
0.2765
0.104
Prepared by: TAW Checked by: CSM
Notes:
- Values used are a calculated mean of hydraulic conductivities in MS-8, MS-9, MS-10, MS-11, MS-12 (OW-3), and MS-13(MS-6).
Z - Values used are a calculated mean of effective porosities in MS-8, MS-9, MS-10, MS-11, MS-12 (OW-3), and MS-13(MS-6) taken from the Hydrogeologic Study for the Proposed FGD Scrubber
Landfill, August 2003.
Groundwater elevations are based on water level data collected on September 11, 2023.
Hydraulic gradients and groundwater velocities are approximate.
ft - feet
ft/day - feet per day
NAVD 88 - North American Vertical Datum 1988
Page 1 of 1

TABLE 5
LEACHATE RESULTS AND ANALYTICAL DETECTIONS
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
C-1 Leachate
pH
320
S.U.
4.7
Temperature
325
Deg C
18
Specific Conductance
323
µmhos/cm
4015
Dissolved Oxygen
-
mg/L
7.64
Oxidation Reduction Potential
336
mV
386
Eh
-
mV
591.0
Turbidity
330
NTUs
15.4
-
Antimony
13
µg/L
< 1
0.104
Arsenic
14
µg/L
1.94
0.111
Barium
15
µg/L
22
2
Beryllium
23
µg/L
3.63
2
Boron
428
µg/L
57600
5
Cadmium
34
µg/L
0.246 J
0.032
Calcium
375
mg/L
547
0.012
Chloride
301
mg/L
370
0.0154
Chromium
51
µg/L
< 1
0.185
Cobalt
53
µg/L
42.7
0.077
Copper
54
µg/L
2.50
1
Fluoride
312
mg/L
1.2 J
0.0479
Iron
340
µg/L
164000
4
Lead
131
µg/L
0.126J
0.037
Lithium
-
µg/L
2010
2
Magnesium
376
mg/L
227
0.008
Manganese
342
µg/L
5650
1
Mercury
132
µg/L
< 0.05
0.01
Molybdenum
397
µg/L
634
1
Nickel
152
µg/L
108
1
Nitrate (as N)
303
mg-N/L
2.0
0.002
Selenium
183
µg/L
46.1
0.193
Silver
184
µg/L
< 1
0.035
Sulfate
315
mg/L
2800
0.0428
Thallium
194
µg/L
0.098 J
0.041
Total Dissolved Solids
311
mg/L
4900
25
Vanadium
209
µg/L
< 1
0.114
Zinc
213
µg/L
264
4
Notes:
A blank cell means there is no relevant information.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 11/15/2023.
Samples collected by Duke personnel on September 11, 2023.
<- Concentration not detected at or above the adjusted reporting limit.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Deg C - degrees Celsius
1 - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - miligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - Millivolts
NTUs - nephelometric turbidity units
S.U. - Standard Units
SWS ID - Solid Waste Section Identification Number
U - Analyte was analyzed for, but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
Prepared by: CSM Checked by: TAW
Page 1 of 1

TABLE 6
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Parameter
SWS ID
Units
Monitoring Wells
15A NCAC 02L
Standard
MS-08
MS-09
MS-10
MS-11
MS-12
MS-13
MS-14
MS-15
MS-16
pH
320
S.U.
5.6
6.5
5.1
5.3
4.9
5.0
5.9
6.1
6.0
6.5-8.5
Temperature
325
Deg C
19
19
17
18
15
17
16
19
18
NE
Specific Conductance
323
µmhos/cm
41
98
31
51
22
59
65
324
75
NE
Dissolved Oxygen
-
mg/L
7.10
8.71
6.85
6.09
7.23
4.83
7.00
9.30
7.42
NE
Oxidation Reduction Potential
336
mV
393
316
402
358
490
460
416
362
381
NE
Eh
-
mV
598.0
521.0
607.0
563.0
695.0
665.0
621.0
567.0
586.0
NE
Turbidity
330
NTUs
1.9
1.2
3.60
2.20
9.10
3.6
3.2
5.9
4.0
NE
Antimony
13
µg/L
< 1
0.265 J
< 1
< 1
< 1
< 1
< 1
0.153 J
< 1
1
Arsenic
14
µg/L
<1
<1
0.151J
<1
<1
<1
0.184J
0.115J
0.208J
10
Barium
15
µg/L
39
51
103
79
77
118
55
361
96
700
Beryllium
23
µg/L
<1
<1
<1
<1
<1
0.43J
<1
<1
<1
4
Boron
428
µg/L
< 50
< 50
< 50
< 50
< 50
< 50
< 50
< 50
< 50
700
Cadmium
34
µg/L
<1
<1
<1
<1
<1
<1
<1
0.049J
<1
2
Calcium
375
mg/L
4.08
16.2
0.210
2.36
0.178
6.38
5.49
32.8
8.29
NE
Chloride
301
mg/L
1.2
1.5
1.10
3.90
2.70
3.3
0.96
81
1.7
250
Chromium
51
µg/L
3.84
1.60
1.30
2.59
0.518 J
< 1
0.213 J
19.5
4.22
10
Cobalt
53
µg/L
< 1
< 1
0.804 J
0.138 J
1.12
< 1
< 1
0.106 J
0.394 J
1
Copper
54
µg/L
< 1
< 1
< 1
< 1
< 1
< 1
< 1
< 1
1.94
1,000
Fluoride
312
mg/L
0.12
< 0.1
< 0.1
< 0.1
< 0.1
< 0.1
0.08 J
< 0.2
0.21
2
Iron
340
µg/L
72
23 J
1110
193 J
197
20 J
14 J
547
1530
300
Lead
131
µg/L
< 1
< 1
0.611 J
0.07 J
0.261 J
0.059 J
< 1
0.235 J
0.584 J
15
Lithium
-
µg/L
< 5
<5
<5
<5
<5
<5
<5
2 J
<5
NE
Magnesium
376
mg/L
1.80
1.39
0.505
1.260
0.539
1.47
1.16
15.7
3.90
NE
Manganese
342
µg/L
11
3 J
36
13
18
15
< 5
6
27
50
Mercury
132
µg/L
< 0.05
< 0.05
< 0.05
< 0.05
0.01 J
0.02 J
< 0.05
0.01 J
< 0.05
1
Molybdenum
397
µg/L
< 1
0.181 J
0.336 J
< 1
< 1
< 1
< 1
< 1
0.306 J
NE
Nickel
152
µg/L
0.555 J
< 1
1.2
1.2
0.298 J
0.268 J
< 1
24.7
2.01
100
Nitrate (as N)
303
mg-N/L
0.16
0.11
0.22
0.02 J
0.04 J
0.85
0.01 J
2.1
0.61
10
Selenium
183
µg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
20
Silver
184
µg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
20
Sulfate
315
mg/L
0.18
0.65
0.09 J
0.25
0.14
0.12
0.09 J
0.67
0.39
250
Thallium
194
µg/L
<1
<1
<1
<1
0.042J
<1
<1
<1
<1
2
Total Dissolved Solids
311
mg/L
54.0
86.0
< 25
35.00
< 25
45.0
67.0
299
82.0
500
Vanadium
209
µg/L
4.00
2.47
2.62
0.294 J
0.433 J
0.421 J
2.27
2.89
6.31
7
Zinc
213
µg/L
1 <5
1 <5
7
4 J
4 J
<5
<5
4.1
6
1,000
Notes:
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 11/15/2023.
Samples collected by Duke personnel on September 11, 2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards (last amended on April 1, 2022)
A blank cell means there is no relevant information.
<- Concentration not detected at or above the adjusted reporting limit.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Deg C - degrees Celsius
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - miligrams per liter
mg-N/L - milligrams Nitrogen per liter
mV - Millivolts
NCAC - North Carolina Administrative Code
NE - Not Established
NTU - nephelometric turbidity units
S.U. - Standard Units
SWS ID - Solid Waste Section Identification Number
U - Analyte was analyzed for, but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
Prepared by: TAW Checked by: CSM
Page 1 of 1

TABLE 7
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
FGD RESIDUE LANDFILL (No. 1809-INDUS)
SEMIANNUAL WATER QUALITY MONITORING REPORT
MARSHALL STEAM STATION
DUKE ENERGY CAROLINAS, LLC, TERRELL, NC
Parameter
Sample ID
September
2023
Concentration
Units
15A NCAC 02L
Standard
Historical
Concentration
Range
Significance
pH
MS-8
5.6
S.U.
6.5 - 8.5
4.9 - 6.92
pH is consistent with the range of historical readings at MS-8
MS-10
5.1
3.6 - 5.89
pH is consistent with the range of historical readings at MS-10
MS-11
5.3
4.3 - 5.8
pH is consistent with the range of historical readings at MS-11
MS-12
4.9
4.4 - 5.34
pH is consistent with the range of historical readings at MS-12
MS-13
5.0
4.2 - 5.5
pH is consistent with the range of historical readings at MS-13
MS-14
5.9
5.49 - 6.2
pH is consistent with the range of historical readings at MS-14
MS-15
6.1
5.66 - 9.8
pH is consistent with the range of historical readings at MS-15
MS-16
6
5.2 - 6.43
pH is consistent with the range of historical readings at MS-16
Chromium
MS-15
19.5
µg/L
10
11.5 - 29.7
Chromium is consistent with the range of historical concentrations at MS-15
Cobalt
MS-12
1.12
µg/L
1
0.752 J - 1.6 J
Cobalt is consistent with the range of historical concentrations at MS-12
Iron
MS-10
1110
ug/L
300
28 - 2353
Iron is consistent with the range of historical concentrations at MS-10
MS-15
547
11.5 - 1894
Iron is consistent with the range of historical concentrations at MS-15
MS-16
1530
29.5 - 57572
Iron is consistent with the range of historical concentrations at MS-16
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 11/15/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
Historical ranges are based on data from the monitoring events that occurred between September 2006 and September 2022.
µg/L - micrograms per liter
S.U. -Standard Units
Prepared by: TAW Checked by: CSM
Page 1 of 1

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
L7
synTerra
Science & Engineering Consultants

❑CAMA ❑CCR ❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB SPECIAL STUDYto KE
FIELD SAMPLING LOG ENE
Site: MSS
Well/SW ID: G1 _ Lec-c6a-E'- Date: 9-27-z3
El GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: C157-
COMPANY: DUKE ENERGY
❑ OTHER:
WEATHER:
❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW AIR TEMP: 'F
FIELD METER TYPE/ SERIAL #: 15'tq lG
TURBIDI METER TYPE/ SERIAL #:_ 337M
START PURGE TIME: Ot q Z SAMPLE COLLECTION TIME: 0950
PUMP/TUBING INTAKE DEPTH: _ (ft) DEPTH TO WATER: "' N• S (ft) MOLT FACTOR *: 0.163 ['(radiusll2)2 3:14'7.48J
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: A SU (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
a
a
°
1� QCrP
❑ Tubin /Pump Inspected I 00 I (see) I (Sec) I Low Flow Sampling Stabilization Criteria
❑Good (Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event • PH f 0.1 standard unit
• Speck Conductance t 5% in NS/cm
Additional Notes: • DO f 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(mL /min)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mV)
W
(NTU)
(x.x)
O$t{N
Z50
01LS
1`6
7.75
qe) et
K6 2
372
(I.L
0646
2S0
0.50
I
7.61-/
Not 5
°!-61
3s
t5:Y
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[:] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?Q YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR J�' e 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH lne Minor Strong
ADDITIONAL NOTES: APPEARANCE F�ar Cloudy Turbid Red/Iron Film on Surface Sheen Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F-]CAMA F-]CCRF-]Landfill [:]NPDES ❑ DGW❑ASW F-]LRB ❑ SPECIAL STUDY,
Site:
Well/SW ID:
tDUKE
E1 ERGG
Date:
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mUmin)
(gallons OR mL)
VC)
(mg/L)
I
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
W
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA [—]CCR❑Landfill F]NPDES ❑ DGWFIASW [—]LRB ❑ SPECIAL STUDY.
FIELD SAMPLING LOG
Site: M5 Well/SW ID: M S-12�
P DUKE
ENERGY
Date: 7- 2 7- Z 3
GROUNDWATER SAMPLESURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: (7 Z—
COMPANY: a DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN []SNOW AIR TEMP: `F
FIELD METER TYPE/ SERIAL #: gS[48L
TURBIDIMETER TYPE/ SERIAL #: 331'q
START PURGE TIME: Of? KU SAMPLE COLLECTION TIME: 0450
PUMP/TUBING INTAKE DEPTH: yn (ft) DEPTH TO WATER: K(s•NS (ft) MULT FACTOR *: 0.163 ['(radius/12)2'3.147.48]
WELL DIAMETER: 7.0 (in) HEIGHT OF WC: 5.13 (ft) WELL VOLUME: 0, Se( (gal)
WELL DEPTH: 51. 5 8 (ft) TOTAL VOLUME PURGED: 6.13 Z (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
❑ Tubin /Pump Inspected I (ase) I (sec) (sec) I Low Flow Sampling Stabilization Criteria
OGood Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
Additional Notes: Specific Conductance t 5% in VS/cm PdDOe Turbidity less than 10 NTUs saturation
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
oggt,l
d7.2S
Itio
0.50
la
g_Z5
Ct 3
S.6 2-
397
2- 3
Ok47
`17.15
lZC
132
to
`f t
5159
3113
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 0 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES 0 NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR & e 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH 6-ne Minor Strong
ADDITIONAL NOTES: APPEARANCE ee> r Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
6,,I,c 1 (4&441 Version 1.2 Revised 09/29/2022 HPB

F-]CAMA F-]CCRF-]Landfiill F-]NPDES ❑ DGW[—]ASW 7LRB SPECIAL STUDY
Site:
Well/SW ID:
Date:
.&, DUKE
'*' ENERGI
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mL/min)
(gallons OR mL)
VC)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

OCAMA F—]CCR❑Landfill [:]NPDES DGW[—] ASWF—]LRB ❑ SPECIAL STUDY.
Site: NtS5
FIELD SAMPLING LOG
Well/SW ID: /14S-9
•t, DUKE
ENERGY
Date: q-Z-?-Z 3
GROUNDWATER SAMPLE SURFACE WATER SAMPLE 1:1LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: C WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAINSNOW AIRTEMP: "F
COMPANY: 0 DUKE ENERGY FIELD METER TYPE/ SERIAL #: °!�
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 37Z"C
START PURGE TIME: (UU't- SAMPLE COLLECTION TIME: fol± 1020
SO.Sv (ft) K3.117 (ft) MULT FACTOR" 0.163 ['(radius/12)2 3.14'7.48]
PUMP/TUBING INTAKE DEPTH: DEPTH TO WATER:
WELL DIAMETER: ?.v (in) HEIGHT OF WC: (ft) WELL VOLUME: 1. s6 (gal)
WELL DEPTH: 53 •J (ft) TOTAL VOLUME PURGED: 0, SO (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
'
a
o
❑ Tubin m /Pup Inspected I (") I (Sec) I (sec)
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned [—]Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Gnteria
• pH
• Specmc Conductance
• DO
• Turbidity
t 0.1 standard unit
f 5% in pS/cm
t 0.2 mg1L or 10% saturation
less than 10 NTUs
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(IC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
1004
fl(3.71
(00
to
o
&SS
/v(
4./
3Ti
('25
ruu�
y,cv
/uo
ZU
11
8•51
qT
3 M
z o
IOro
gq.oq
too
61,30
( q
8-66
17
b•'(8
37-
10(3
'( .04
luu
o.'{6
( I
r*7v
`J
6•Sl
370
r-v
101(e
4q,01
IUU
s.Sv
11
S.71
$
6•57-
16
I.2
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES D NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES PNO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR Oe 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH to a Minor Strong
ADDITIONAL NOTES: APPEARANCE bar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
version 1.z Revised oslzalzulz Arts

DCAMA F�CCR❑Landfill F—]NPDES ❑ DGW❑ASW F—]LRB ❑ SPECIAL STUDY
Site: Well/SW ID:
DUKE
ENERGY
Date:
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA❑CCR❑Landfill ❑NPDES❑DGW❑ASW❑LRB�SPECIAL STUDY FG/�
FIELD SAMPLING LOG � DUKE
ENERGY
Site: MSS
Well/SW ID: MS -co
Date: y-Z?-L3
❑GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: r, -22—
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑RAIN ❑SNOW AIR TEMP: "F
FIELD METER TYPE/ SERIAL #: 951r166
TURBIDIMETER TYPE/ SERIAL #: 33-41
START PURGE TIME: 0111 SAMPLE COLLECTION TIME: Og3S
PUMP/TUBING INTAKE DEPTH: Z0. SK (ft) DEPTH TO WATER: 7-0-&0 Ift) MULT FACTOR ": 0.163 ['(radius/12)2 3.14'7.48]
WELL DIAMETER: ZO (in) HEIGHT OF WC: 3, 3K (ft) WELL VOLUME: 0_SK (gal)
WELL DEPTH: Z3. 34 (ft) TOTAL VOLUME PURGED: a6U (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
Tubing/Pump Inspected cPsi) (sec) (sec)
OGood LTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH
• Specific Conductance
• DO
• Turbidity
t 0.1 standard unit
t 5% in NS/cm
f 0.2 mgrL or 10% saturation
less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
( FT)
(x.xx)
(mL/min )
(x)
(gallons OR mL )
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
W
(Sul
(x.xx)
(mv)
W
(NTU)
(x.x)
On
Z0.36
("ID
0.15
1R•77
3'1
y-15
`13
Ifs
C"M
Zo•5v
0.36
17
6-411
30
5.oz,
100
S.(
01116
70•S0
p.NS
17
6.g2
Zq
5,041
3-1'y
3.Z
Uh31
ZV40
1 110
0.60
17
-g
31
505
yvt
3.6
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES Q NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? QYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ -YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR &a 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH V;e Minor Strong
ADDITIONAL NOTES: APPEARANCE r Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA [—ICCR Landfill FNPDES ❑ DGW❑ASW 1-7LRB SPECIAL STUDY
Site:
Well/SW ID:
Date:
•%� DUKE
`r ENERGY
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
W
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCRdandfill ❑NPDES ❑ DGW❑ASW nLRB ❑ SPECIAL STUDY,
DUKE
ENERGY
Site:Nw,44a Well/SW ID: 1VI5 -1( Date: q 07 Z3
ROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: U
COMPANY: gDUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑ PARTLY CLOUDY I `� OVERCAST []RAIN FISNOW AIR TEMP: (D 3 °F
FIELD METER TYPE/ SERIAL#: % 93
TURBIDIMETER TYPE/ SERIAL #: 33aa-
START PURGE TIME: 3 2SAMPLE COLLECTION TIME: O
PUMPITUBING INTAKE DEPTH: 3�f•50 (ft) DEPTH TO WATER: .3 5 79 (ft) MULT FACTOR': 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: 2.oO (in) HEIGHT OF WC: 5.Ry (ft) WELL VOLUME: a G 7 (gal)
WELL DEPTH: q(. 7.2- (ft) TOTAL VOLUME PURGED: 0.76 (9a1)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
e
/0 F
5 °
�ubin /Pump Inspected I (Ps) I o-C) I (sec) I Low Flow Sampling Stabilization Criteria
Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event - PH t 0.1 standard unit
Additional Notes: ��L, • Speck Conductance t 5% in pS/cm
Y F V _ Z(�ZJ�-I Z7—� d7tF�(� • DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(mUnnin)
(x)
(gallons OR mL)
(x.xx)
CC)
(x)
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Nd
5.15
120
0.Y
. 3
S5
5,3X
3VI
70
01
•15
/ a
0. 0
l
&4
S, (p
yf
_f
OS
5
/Zo
0/
S
, / �{
50
9 9
3515
120
+
6.09
. A
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES O 0
IS A TURBIDITY METER DUPLICATE REQUIRED? []YES v NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR o H2S
ODOR STRENGTH ems/ - Minor
ADDITIONAL NOTES: APPEARANCE I f cloudy
O
'E
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? S ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ YES 210
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRYE PAD
GOOD
'AAD
NONE
GOOD
,BAD
NONE
GOOD
B D
NONE
GOOD
BAD
NONE
GOOD
/BAD
NONE
VA
7
Version 1.2 Revised 09/29/2022 HPB

F-]CAMA F—]CCRF-]LandfiII F—]NPDES ❑ DGWFIASW F—]LRB ❑ SPECIAL STUDY
Site:
Well/SW ID: Date:
i
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

F]CAMA F-]CCR gLandfill F-]NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
fin FIELD SAMPLING LOG DUKE
ENERG'
Site: Well/SW ID: S — Z Date: q 3
ROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE [:]WLO DWELL DEVELOPMENT
FIELD STAFF: 7 K
COMPANY: DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLY CLOUDY E� OVERCAST ❑RAIN nSNOW AIRTEMP:10-5 'F
FIELD METER TYPE/ SERIAL #: R771n 3
TURBIDIMETER TYPE/ SERIAL #: 39 22,
START PURGE TIME: l0 2 ( SAMPLE COLLECTION TIME: 60
2 U
PUMP/TUBING INTAKE DEPTH: 4+ So (ft) DEPTH TO WATER: 3 �I S (ft) MULT FACTOR *• 0.163 [•(radius/12)2'3.14'7.48]
WELL DIAMETER: 7 ::)&2 (in) HEIGHT OF WC: 7 (ft) WELL VOLUME: / / (a (gal)
WELL DEPTH: 3% © % (ft) TOTAL VOLUME PURGED: ,?• 7Zi (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
f
SAMPLING METHOD:
P MP SETTING:
R
ubin /Pump Inspected
(psi)
(sec)
(se-)
Low Flow Sampling Stabilization
Criteria
Iv, — u I uu"19 Eau Urump baa Ucnanged/Gleaned UCorrect Next Event
Additional Notes:
pH
Specific Conductance
DO
Turbidity
t 0.1 standard unit
f 5% In pS/cm
t 0.2 mg/L or 10% saturation
less than 1 n NTIIc
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
/a S.
�Sd
�
6
(FT)
(x.xx)
a Z
�Z
Y-62
Y-6Z
(mL/min)
W
.900
o
mod
0
06
(gallons OR mL)
(x.xx)
0.70
>0
d
.
c>2, SO
a
CC)
W
5
I's —.7,23
/S
(mg/L)
(x.xx
7 2 y
7.
- , 3
(pS/cm )
(x)
I
�.
1=2119-
ao2
(su)
(x.xx)
yd
9s
7t��/
8
�f
(mv)
(x)
F7
_34
9
90
(NTU)
(x.x)
z
3 2./
.Xy
�0� 5
0 r
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE
CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES Y
PO
IS A TURBIDITY METER DUPLICATE REQUIRED?
MYESYNO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
None H2S
ODOR STRENGTH
None Minor
ADDITIONAL NOTES: APPEARANCE
Clear Cloudy
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? E'']YYES [I NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?�(ES NO
O DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid Red/Iron Film nn Sivraca Shaun ra.,.,..
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
-BD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Floc
Version 1.2 Revised 09/29/2022 HPB

[-]CAMA F-]CCR❑Landfill F-]NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
Site: Well/SW ID: Date:
TIME
WATER
LEVEL
(FT)
(x.xx)
FLOW
RATE
(mL/min)
W
VOLUME
REMOVED
(gallons OR mL)
(x.xx)
TEMPERATURE
VC)
(x)
DO
(mg/L)
(x.xx)
SPECIFIC
CONDUCTANCE
(NS/cm)
(x)
p H
(su)
(x.xx)
ORP
(mv)
(x)
TURBIDITY
(NTU)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

FICAMA RCCR Landfill ONPDES ❑ DGWRASW ❑LRB a SPECIAL STUDY.
FIELD SAMPLING LOG [DUKE
ENERG
Site: Ma4d Well/SW ID: MS-(3 Date: I/Z71Z3
-11—
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE WLO WELL DEVELOPMENT
FIELD STAFF: S WEATHER: QSUNNY El PARTLY CLOUDY [OVERCAST n RAIN SNOW AIR TEMP: (12 'F
COMPANY: 7DUKE ENERGY FIELD METER TYPE/ SERIAL #: z
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3 a%
START PURGE TIME: 0 FSo SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: 39 00(ft) DEPTH TO WATER: _ 3(.55 (ft) MULT FACTOR *• 0.163 [*(radius/12)2*3.14'9.48j
WELL DIAMETER: 2. 06 (in) HEIGHT OF WC: 9 7 (ft) WELL VOLUME: I. l# Z (gal)
WELL DEPTH: y 52- (ft) TOTAL VOLUME PURGED: 0,5D (gal)
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
J ubin /Pump Inspected L
Good [Tubing Bad Pump Bad
Additional Notes:
Bladder ) Peristaltic I 12 Volt Grundfos Other ( )
2o`�os°
(psi) tse°t o. Low Flow Sampling Stabilization Criteria
Changed/Cleaned nCorrect Next Event pH t 0.1 standard unit
• Specific Conductance t 5% In pS/cm
DO t 0.2 mg1L or 10% saturation
• Turbidity less than in KIT] Ic
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
SS
48`S
l
BRCS
(FT)
x
(x.xx)
�'0
31-
3r. Jv
C. �0
(mL/min)
(x)
ZL
2
IZO
(gallons OR nnL)
(x.xx)
p 6
0,56
G.
G•
(°C)
(x)
/
I
(mg/L)
(x.xx)
f z
y 3
(NS/cm )
(x)
q
5a
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
5
8
5.63
�
S, oZ
Gr0
3, U
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE
CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑ YES
-]YES
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?
❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?
15%? Q YES NO DUPLICATE 1
CE" ES ❑ NO
FINAL SAMPLE OBSERVATIONS:
(NTU) DUPLICATE 2
(NTU)
DETECTED ODOR
Non 1-12S
Petroleum Earthy Musty Undetermined
ODOR STRENGTH
Minor
Strong
ADDITIONAL NOTES: APPEARANCE
Cie Cloudy
Turbid Red/Iron Film on Surface Sheen
Fines Floc
WELL TAG
GOOD BAD NONE
LOCK I DUST CAP CONCRETE PAD
GOOD BAD I NONE GOOD BAD NONE I GOOD I BAD NONE
Version 1.2 Revised 09/29/2022 HPB

[-]CAMA [-]CCR❑Landfill [-�NPDES a DGW❑ASW [:]LRB[—] SPECIAL STUDY_
cite•
Well/SW ID:
Date:
�0
FLOW
RATE
(mUmin)
(x)
VOLUME
REMOVED
(gallons OR ML)
(x.xx)
TEMPERATURE
VC)
(x)
DO
(mg/L)
(x.xx)
SPECIFIC
CONDUCTANCE
(Ns/cm)
(x)
P H
(su)
(x.xx)
ORP
(mv)
(x)
TURBIDITY
(NTU)
(x.x)
TIME
WATER
LEVEL
(FT)
(x.xx)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR41Landfill ❑NPDES ❑ DGW❑ASW F—]LRB ❑SPECIAL STUDY
FIELD SAMPLING LOG 1P DUKE
ENERG)
Site: MoW Well/SW ID:s ' Date: Z7 L3
F12GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: X WEATHER: [-]SUNNY PARTLY CLOUDY ❑ OVERCAST ❑RAIN IS OW AIR TEMP: -F
COMPANY: DUKE ENERGY FIELD METER TYPE/ SERIAL #: F/<:i
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 332.2
START PURGE TIME: 11 SAMPLE COLLECTION TIME: MS
PUMPITUBING INTAKE DEPTH: I-S % (ft) DEPTH TO WATER: G-VP (ft) MULT FACTOR': 0.163 [•(radius/12)2*3.14.7.48]
WELL DIAMETER: 2 ' O (in) HEIGHT OF WC: %- So2 (ft) WELL VOLUME:
WELL DEPTH: LI ff• 3 $ (ft) TOTAL VOLUME PURGED: O' XS (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
/0 R
D
(ubin /Pump Inspected (psi)(see) *-)
Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH
• Specific Conductance
• DO
• Turbidity
f 0.1standard unit
t 5% in NSlcm
t 0.2 mg/L or 10% saturation
less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
1
37t.2
(e6
d-
0
7/1
5.8-1
VW,
7 a
l
ff 3 7
0
37l2
37--u-
7 (l
Q
(�
106
d. SS
, 7
7.r
x o 3
CAS
&S
S'g-
5 Fs
W6
W7
_3
-9. k
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES f O
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ENO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR H2S
ODOR STRENGTH Minor
ADDITIONAL NOTES: APPEARANCE ear Cloudy
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? � ES [I NO
� ❑
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES NO
O DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
50 NCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
AD
NONE
GOOD
BAD
NONE
G D
I BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F-�CAMA F-]CCR[-]Landfill F-]NPDES ❑ DGW❑ASW FILRB ❑ SPECIAL STUDY,
Site:
Well/SW ID:
Date:
•
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mL/min)
(gallons OR mL)
(°C)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB 0 SPECIAL STUDY F6-6
FIELD SAMPLING LOG ot DUKE
ENE )
Site: M55
Well/SW ID: MS-/5 Date:
❑GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: (')'L
COMPANY: Q DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAINSNOW AIR TEMP: "F
FIELD METER TYPE/ SERIAL #: R 158t,
TURBIDIMETER TYPE/ SERIAL M 3321
START PURGE TIME: 1100 SAMPLE COLLECTION TIME: 117,0
PUMP/TUBING INTAKE DEPTH: 60.58 (ft) DEPTH TO WATER: K3.31-- (ft) MULT FACTOR *• 0.163 [*(radius/12)2*3.14`7;48]
WELL DIAMETER: 7.(2 (in) HEIGHT OF WC: I`1.74 (ft) WELL VOLUME: 3. 2 Z (gal)
WELL DEPTH: 6 3.O S (ft) TOTAL VOLUME PURGED: I Lt) (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
i
PUMP SETTING:
P
R
°
Tubing/Pump /Pump Inspected (psi) (see) (see)
QGood [Tubing Bad [:]]Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
• pH
• Specific Conductance
• DO
• Turbidity
t 0.1 standard unit
± 5% In NS/cm
t 0.2 mg/L or 10% saturation
less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR ml-)
(x.xx)
CC)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x )
Ito4
(i3.so
7C7
010
21
9,60
33-7
6.&T
3SS
ZZ.'7
ltcn
d4.D6
Tw
0.Ko
7.45
g.s$
1 3zt(
6.12
360
tr.S
I'w
KN,I0
Zua
0.60
l q
q•2g
3L6
6_v9
2
12.2
it(3
4L1.10
arn,
0A0
l
9.3u
320
6.06
3 Sq
ff•G
11(6
HN•lU
ZOO
1(w
19
9.3(
3Z3
b•US
4-2
11(�
WN tv
I-'W
Iq
v
6.06
3G2
S.Ct
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? E]YES El
IS A TURBIDITY METER DUPLICATE REQUIRED? DYES R NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? Fj YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR pe 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH 1 one Minor Strong
ADDITIONAL NOTES: APPEARANCE Car Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
f
Version 1.2 Revised 09/29/2022 HPB

F—]CAMA F—]CCR❑Landfill F—]NPDES ❑ DGW❑ASW [—]LRB ❑ SPECIAL STUDY
Site-
Well/SW ID:
Date:
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(uS/Cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA [--]CCR ❑Landfill ONPDES DGW[:]ASW [--]LRB 0 SPECIAL STUDY FGD
FIELD SAMPLING LOG
ENERGY
Site: 11455 Well/SW ID: M s -1! Date: 7-2-?'Z3
El GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE WLO WELL DEVELOPMENT
FIELD STAFF: C)" WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN SNOW AIRTEMP: °F
COMPANY: F/ DUKE ENERGY FIELD METER TYPE/ SERIAL #: `�StQijC
❑ OTHER: TURBIDIMETER TYPE//SERIAL #: 33 of
START PURGE TIME: IOZB SAMPLE COLLECTION TIME: /UKS
PUMPITUBING INTAKE DEPTH: 3q.11 (ft) DEPTH TO WATER: 2'7�3 (ft) MULT FACTOR *• 0.163 [*(radius/12)2*3.14.7.48]
WELL DIAMETER: 2 (in) HEIGHT OF WC: _ 16. Z
WELL DEPTH: 17.Ki 1 (ft) WELL VOLUME: 1,67 (gal)
(ft) TOTAL VOLUME PURGED: 0. (fS (gal)
TYPE OF PUMP: Bladder Peristaltic 12 Volt Grundfos Other
PURGE METHOD:
SAMPLING METHOD: i
PUMP SETTING: R °
0 Tubin /Pump Inspected 1.(PSI) (sec) (see) Low Flow Sampling Stabilization Criteria
©Good []Tubing Bad Pump Bad Changed/Cleaned Correct Next Event pH f 0.1'standard unit
Additional Notes: Speck Conductance t 5% In pS/cm
• DO :k 0.2 mg/L or 10% saturation
• Turbidity ram..., 6— ,
TIME
I43t
WATER
LEVEL
(FT)
(x.xx)
Z�SI
FLOW
RATE
(mL/min)
(x)
$O
VOLUME
REMOVED
(gallons OR mL)
(x.xx)
b.tv
TEMPERATURE
(°C)
W
DO
(mg/L)
(x.xx)
SPECIFIC
CONDUCTANCE
(x)
7°I
77
-76
77
75
BACK OF THIS SHEET
pH
ORP
TURBIDITY
(x.xx)
(x)
(NTU)
(x.x)
6.3Z
353
tq
t�K
27.8u
fst7
0.20
S-AR 01
C'
36�
is-v
Iv;�
27:q;
Bo
iso
7.5b
i,.at
37 L
b 2
foHO
Z7.gS
6.35
l$
7 Sl
5:917
377
N.2,
(°`13
27.65
So
7.K
S.aS
3fit
lio
PLEASE REFER
TO THE
IF THE
CHART ABOVE
IS Fill I
IJ KtutvtLUPMENT NEEDED (>10 NTUS)? U YES 0 NO.
IS A TURBIDITY METER DUPLICATE REQUIRED? YES 0 NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES NC
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR lJ" 1-12S
ODOR STRENGTH Minor
ADDITIONAL NOTES: APPEARANCE ZZ Cloudy
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?.E] YES Q NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum
Strong
Turbid
Earthy
Red/Iron
Musty Undetermined
Film on Surface Sheen Fine Floc
UST CAP
CONCRETE PAD
BAD
NONE
GOOD
BAD
NONE
version 1.2 Kevised 09/29/2022 HPB

OCAMA F�CCR❑Landfill 0NPDES ❑ DGW❑ASW DLRB ❑ SPECIAL STUDY
j.� DUKE
ENERGY
Site:
Well/SW ID: Date:
FLOW VOLUME SPECIFIC H ORP TURBIDITY
TEMPERATURE DO CONDUCTANCE P
RATE REMOVED
mL/min) VC) (mglL) (NS/cm) (su) (mv) (NTU)
( (gallons OR mL)
(x) (x.xx) (x) (x.xx) (x) (x.xx) (x) (x.x)
TIME
WATER
LEVEL
(FT)
(x.xx)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCRjLandfill ❑NPDES ❑ DGW ASW LRB SPECIAL STUDY
Site: &5
—0
❑GROUNDWATER SAMPLE
FIELD STAFF: IK5
COMPANY: DUKE ENERGY
❑ OTHER:
Well/SW ID: , 5 ) I
WEATHER:
DUKE � ENERGY
Date: Z Z3
WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
❑SUNNY ❑PARTLY CLOUDY ❑i OVERCAST ❑RAIN ❑SNOW AIR TEMP: 67 3 *F
FIELD METER TYPE/ SERIAL M 771913
TURBIDIMETER TYPE/ SERIAL #: 332 1
START PURGE TIME: SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR*: 0.163 ['(radius/12)2"3.14'7.48]
WELL DIAMETER: (in) HEIGHT OF WC: — (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
❑ Tubin /Pump Inspected (P52
❑Good [Tubing Bad ❑Pump Bad ❑
Additional Notes:
Bladder I Peristaltic 12 Volt
(sec) I (sec)
hanged/Cleaned ❑Correct Next Event
Grundfos I Other( )
Low Flow Sampling Stabilization Criteria
pH * 0.1 standard unit
Specific Conductance t 5% in yS/cm
DO t 0.2 mg/L or 10% saturation
Turbidlty lwcs than 1n nlTI lc
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
pH ORP TURBIDITY
CONDUCTANCE
(FT)
x
(x.xx)
(mLlmin)
(x)
(gallons OR mL)
(x.xx)
(C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
a�
PLEASE REFER
TO THE
BACK OF THIS SHEET
IF THE
CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ N
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S
ODOR STRENGTH None Minor
ADDITIONAL NOTES: APPEARANCE Clear Cloudv
O
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [:]YES ❑ NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE?❑ YES Q"NO
DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
Petroleum Earthy Musty Undetermined
Strong
Turbid
G
PROT7BADNONE
LOCK
DUST CAP
TGOODBAD
NONE
GOOD
GOOD
BAD
NONE
GOOD
BAD
NONE
Karl/iron Gil..,.,., o.o.,..,. FLOC
Sheen Fines
CONCRETE PAD
GOOD BAD NONE
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA F�CCR❑Landfill ONPDES ❑ DGW❑ASW ❑LRB 0 SPECIAL STUDY
Site: Well/SW ID: Date:
FLOW
RATE
(mUmin)
(x)
VOLUME
REMOVED
(gallons OR mL)
(x.xx)
TEMPERATURE
(°C)
(x)
DO
(mg/L)
(x.xx)
SPECIFIC
CONDUCTANCE
(uS/cm)
(x)
p H
(su)
(x.xx)
ORP
(mv)
(x)
TURBIDITY
(NTU)
(x.x)
TIME
WATER
LEVEL
(FT)
(x.xx)
Version 1.2 Revised 09/29/2022 HPB

[:JCAMA F-]CCR Landfill [—]NPDES ❑ DGW[--]ASW ❑LRB ❑ SPECIAL STUDY
DAILY CALIBRATION LOCH
Site: 'MGrrS�u�i� Date:
om
WEATHER: ❑SUNNY ❑PARTLY CLOUDY E4VERCAST FIELD PERSONNEL: SS
❑ RAIN ❑SNOW TEMPERATURE (APPROX):
INSITU SERIAL #: Y7793 °F
2100Q SERIAL #: 3i2_
Revised 12/18/2018 KKH

CAMA CCR E/ Landfill ONPDES ❑ DGW❑ ASW ❑ LRB ❑ SPECIAL STUDY DU VE
ENERGY-.
DAILY CALIBRATION LOG Site: Date: q/Z7/1 Field Personnel: �5ffS
Barometric
pressure
(mmHg)
Chart DO
(mg/L)
Meter
Reading
(mg/L)
%Saturation
(%Sat).
Within ± 0.5?
Dissolved Oxygen
Time:
-7,'
`3
Temperature
oC
( )
7q&,0
�q�r .y7
q'RO
$.q0
g.q2-
/ 00 33
Y N
a N
j -,y
Calibration Check as Live
Iq.72-
Reading
Post Calibration-Zt�
Date: q 7 Z3 r�d •S(a -71t4-5 l 7,20 /J0,KS ay N
Time:
TurbiditV
Time:
Post Calibration -
Date: yZ3
Time:
Acceptance
Meter Reading
Within ±
Standard (NTU)
Range (NTU)
(NTU)
5%?
160
16-/" F-7
/ '7 -7
Y N
D
IN
Daily Turbidity Meter BLANK DI Water (NTU) Less than 0.10 NTU?
Date: Q Z7 2 3 N
Time: 7- 33
Revised 12/18/2018 KKH

F_]CAMA F_]CCRF,�LandfiII NPDES ❑ DGWF_]ASW ❑LRB a SPECIAL STUDY F >
DAILY CALIBRATION LOG
Site: MSS Date: q-"Z7-23
c�DUKE
ENERGY
FIELD PERSONNEL:_(�SZ
WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑ OVERCAST ❑ RAIN []SNOW TEMPERATURE (APPROX): -
INSITU SERIAL#: 951R$b F
2100Q SERIAL #: 331,9
H
Buffer
Chart
Meter
Time:y *6 ou
Lot Number
Expiration
Temperature
pH
Reading
Within #
(°C)
(Su)
(su)
0.1 su?
7.00 su
7 v 156
06-30-24
I& 6 1
7.007-
70-2-
CY N
10.01 su
223616
1b -30 -Z7
1S.70
10106
lo. OS
N
4.01 su
2.1KZZO
06-3o-211
ig.56
Kw
yvv
N
Check of 7.00 su as Live Reading
21$156
06-30-14
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Time: ogo
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Reading (Ns)
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Standard Value: 72o [is
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Post Calibration- Date: Time:
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Revised 12/18/2018 KKH

F]CAMA F-]CCRgLandfill F-�NPDES DGW❑ASW ❑LRB SPECIAL STUDY FG'b
r DUKE
ENERGY.
Site: - /11S5 Date: 9-2-2-Z3 Field Personnel: Cs-L
Dissolved Oxygen
Temperature
Barometric
Pressure
Chart DO
Meter_
Reading
% Saturation
Within t 0.5?
Time:
('C)
(mmHg)
(mg/L)
(m9/L)
°Sat )
(1°
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Calibration Check as Live
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Date: °I 2?-2
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Turbidity
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Range (NTU)
,
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Post Calibration -
Date: 9-2-7 -Z3
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Time: 13 S
Daily Turbidity Meter BLANK
DI Water (NTU)
Less than 0.10 NTU?
Date: 'l -7-i-z3
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Time: °st S
Revised 12/18/2018 KKH

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
L7
synTerra
Science & Engineering Consultants

Analytical Data Review Checklist - Aqueous
Facility/Site
"aram Station
State
NC
Location/Sample IDs
Cl-LEACHATE, MS-8, MS-9, MS-10, MS-11, MS-12, MS-13, MS-14, MS 15, MS-16
Duke Central Lab
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date ❑ Groundwater
J23090511 9/27/2023 9/27/2023 10/13/2023 ❑ Surface Water
❑v Other
References: National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
Sample Receipt and Chain of Custody
®®
❑v ❑ I� 1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
❑v
[Il
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
(]
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
0
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑
❑�
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
O
❑
❑
5) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑
❑�
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑�
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
(]
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and/or Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
(]
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
(]
7f) Hexavalent Chromium: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
I]
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
❑
0
❑
9) Method Blank- Were any parameters detected in the method blank(s)?
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
10a) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
❑v
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
11 a) Was the original sample spiked a project sample? If so, then:
❑
❑�
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
7❑e!Assurance/Quality
❑v ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
❑ ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
❑ 0 ❑ 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
❑e ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
❑v ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Mia Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑
❑v ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier/ provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
Lab Qualifiers:
J-Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
7
U-Analyte was analyzed for, but not detected above the MDL.
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than lox the blank concentration.
• The RPD between MS-11 and the field duplicate is greater than 35%for Iron (0.193/0.314 mg/L).
• Chloride (0.03 mg/L), Nitrate (0.05 mg/L), Nitrate as N (0.01 mg-N/L), Boron (0.018 mg/L), and Iron (0.005 mg/L) were detected in the Equipment Blank; Nitrate, Nitrate as N, Boron, and Iron
were also detected in the samples at concentrations less than lox the blank concentrations.
• Nitrate (0.04 mg/L), Nitrate as N (0.01 mg-N/L), and Boron (0.012 mg/L) were detected in the Field Blank; Nitrate, Nitrate as N, and Boron were also detected in the samples at concentrations
less than lox the blank concentrations.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 10/17/2023
Technical Lead GTC 1/2/2024

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J23090511
Project Name: MARSHALL - GW FGD LANDFILL
Task Code: LF
Customer Name(s): Ashley Healy, Bryan Moeller, Josh Stowe,Dee Obrien
Customer Address: Marshall Steam Station
8320 NC Hwy 150 East
Mail Code: Marshall Steam Station
Terrell, NC 28682
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Date:
(Signature)
eg Kendall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
10/13/2023
Page 1 of 28
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Page 2 of 28
Sample Description
2023024019
MARSHALL
27-Sep-23
9:50 AM
Connor Zahora
MSS—MS-8
2023024020
MARSHALL
27-Sep-23
10:20 AM
Connor Zahora
MSS—MS-9
2023024021
MARSHALL
27-Sep-23
9:35 AM
Connor Zahora
MSS_MS-10
2023024022
MARSHALL
27-Sep-23
9:50 AM
Ethan Smith
MSS_MS-11
2023024023
MARSHALL
27-Sep-23
11:00 AM
Ethan Smith
MSS_MS-12
2023024024
MARSHALL
27-Sep-23
9:05 AM
Ethan Smith
MSS_MS-13
2023024025
MARSHALL
27-Sep-23
11:45 AM
Ethan Smith
MSS_MS-14
2023024026
MARSHALL
27-Sep-23
11:20 AM
Connor Zahora
MSS_MS-15
2023024027
MARSHALL
27-Sep-23
10:45 AM
Connor Zahora
MSS_MS-16
2023024029
MARSHALL
27-Sep-23
8:50 AM
Connor Zahora
MSS_Cl-LEACHATE
2023024030
MARSHALL
27-Sep-23
Ethan Smith
MSS_FD-20230927-1
2023024031
MARSHALL
27-Sep-23
8:15 AM
Connor Zahora
MSS_EB-20230927-0815
2023024032
MARSHALL
27-Sep-23
8:30 AM
Connor Zahora
MSS_FB-20230927-0830
13 Total Samples

Page 3 of 28
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
W Job Summary Report
0 Sample Identification
❑� Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑� Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑d Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/13/2023

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-8
Collection Date: 09/27/2023 09:50 AM Loc code: MSS-MS-8
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 1.2 mg/L
Fluoride 0.12 mg/L
Nitrate 0.72 mg/L
Nitrate as N 0.16 mg-N/L
Sulfate 0.18 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.039
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
4.08
mg/L
Iron (Fe)
0.072
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.80
mg/L
Manganese (Mn)
0.001 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
3.84
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.555 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
4.00
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 54.0 mg/L
Sample #: 2023024019
Matrix: GW RCRA
Page 4 of 28
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 16:16
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 16:16
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 16:16
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 16:16
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 16:16
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:33
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:10
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:10
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:10
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:10
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:10
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:10
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:10
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:10
CELL106
1
0.104
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.111
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.249
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.032
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.185
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.077
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.787
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.037
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.18
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.256
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.193
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.035
1
SW 6020E
09/29/2023 19:44
MHALL3
1
0.041
1
SW 6020B
09/29/2023 19:44
MHALL3
1
0.114
1
SW 6020E
09/29/2023 19:44
MHALL3
25
25
1
SM2540C
09/29/2023 09:00
HHOOGKA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-9
Collection Date: 09/27/2023 10:20 AM Loc code: MSS-MS-9
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 1.5 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.50 mg/L
Nitrate as N 0.11 mg-N/L
Sulfate 0.65 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.051
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
16.2
mg/L
Iron (Fe)
0.023
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.39
mg/L
Manganese (Mn)
0.003 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.265 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.60
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.181 J
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
2.47
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 86.0 mg/L
Sample #: 2023024020
Matrix: GW RCRA
Page 5 of 28
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 17:16
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 17:16
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 17:16
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 17:16
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 17:16
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:36
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:15
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:15
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:15
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:15
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:15
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:15
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:15
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:15
CELL106
1
0.104
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.111
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.249
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.032
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.185
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.077
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.787
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.037
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.18
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.256
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.193
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.035
1
SW 6020E
09/29/2023 19:53
MHALL3
1
0.041
1
SW 6020B
09/29/2023 19:53
MHALL3
1
0.114
1
SW 6020E
09/29/2023 19:53
MHALL3
25
25
1
SM2540C
09/29/2023 09:01
HHOOGKA

Certificate of Laboratory Analysis Page 6 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-10 Sample #: 2023024021
Collection Date: 09/27/2023 09:35 AM Loc code: MSS MS-10 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 1.1 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.95 mg/L
Nitrate as N 0.22 mg-N/L
Sulfate 0.09 J mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.103
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.210
mg/L
Iron (Fe)
1.11
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.505
mg/L
Manganese (Mn)
0.036
mg/L
Zinc (Zn)
0.007
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.151 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.30
ug/L
Cobalt (Co)
0.804 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.611 J
ug/L
Molybdenum (Mo)
0.336 J
ug/L
Nickel (Ni)
1.22
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
2.62
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 25 U mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 17:35
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 17:35
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 17:35
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 17:35
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 17:35
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:39
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:19
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:19
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:19
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:19
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:19
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:19
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:19
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:19
CELL106
1
0.104
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.111
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.249
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.032
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.185
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.077
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.787
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.037
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.18
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.256
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.193
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.035
1
SW 6020E
09/29/2023 20:03
MHALL3
1
0.041
1
SW 6020B
09/29/2023 20:03
MHALL3
1
0.114
1
SW 6020E
09/29/2023 20:03
MHALL3
25
25
1
SM2540C
09/29/2023 09:01
HHOOGKA

Certificate of Laboratory Analysis Page 7 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-11 Sample #: 2023024022
Collection Date: 09/27/2023 09:50 AM Loc code: MSS-MS-1 1 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 3.9 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.09 J mg/L
Nitrate as N 0.02 J mg-N/L
Sulfate 0.25 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.079
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
2.36
mg/L
Iron (Fe)
0.193
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.26
mg/L
Manganese (Mn)
0.013
mg/L
Zinc (Zn)
0.004 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
2.59
ug/L
Cobalt (Co)
0.138 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.07 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
1.16
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
0.294 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 35.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 17:55
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 17:55
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 17:55
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 17:55
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 17:55
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:41
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:32
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:32
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:32
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:32
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:32
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:32
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:32
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:32
CELL106
1
0.104
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.111
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.249
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.032
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.185
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.077
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.787
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.037
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.18
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.256
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.193
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.035
1
SW 6020E
09/29/2023 20:40
MHALL3
1
0.041
1
SW 6020B
09/29/2023 20:40
MHALL3
1
0.114
1
SW 6020E
09/29/2023 20:40
MHALL3
25
25
1
SM2540C
09/29/2023 09:01
HHOOGKA

Certificate of Laboratory Analysis Page 8 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-12 Sample #: 2023024023
Collection Date: 09/27/2023 11:00 AM Loc code: MSS MS-12 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride
2.7
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
0.19
mg/L
Nitrate as N
0.04
mg-N/L
Sulfate
0.14
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.077
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
0.178
mg/L
Iron (Fe)
0.197
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.539
mg/L
Manganese (Mn)
0.018
mg/L
Zinc (Zn)
0.004 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.518 J
ug/L
Cobalt (Co)
1.12
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.261 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.298 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.042 J
ug/L
Vanadium (V)
0.433 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 25 U mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 18:15
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 18:15
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 18:15
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 18:15
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 18:15
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:44
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:37
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:37
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:37
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:37
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:37
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:37
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:37
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:37
CELL106
1
0.104
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.111
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.249
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.032
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.185
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.077
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.787
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.037
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.18
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.256
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.193
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.035
1
SW 6020E
09/29/2023 20:50
MHALL3
1
0.041
1
SW 6020B
09/29/2023 20:50
MHALL3
1
0.114
1
SW 6020E
09/29/2023 20:50
MHALL3
25
25
1
SM2540C
09/29/2023 09:01
HHOOGKA

Certificate of Laboratory Analysis Page 9 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-13 Sample #: 2023024024
Collection Date: 09/27/2023 09:05 AM Loc code: MSS MS-13 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride
3.3
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
3.8
mg/L
Nitrate as N
0.85
mg-N/L
Sulfate
0.12
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg)
0.02 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.118
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
6.38
mg/L
Iron (Fe)
0.020
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.47
mg/L
Manganese (Mn)
0.015
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.43 J
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.059 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.268 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
0.421 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 45.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 18:34
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 18:34
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 18:34
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 18:34
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 18:34
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:47
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:42
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:42
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:42
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:42
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:42
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:42
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:42
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:42
CELL106
1
0.104
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.111
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.249
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.032
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.185
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.077
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.787
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.037
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.18
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.256
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.193
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.035
1
SW 6020E
09/29/2023 20:59
MHALL3
1
0.041
1
SW 6020B
09/29/2023 20:59
MHALL3
1
0.114
1
SW 6020E
09/29/2023 20:59
MHALL3
25
25
1
SM2540C
09/29/2023 09:02
HHOOGKA

Certificate of Laboratory Analysis Page 10 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-14 Sample #: 2023024025
Collection Date: 09/27/2023 11:45 AM Loc code: MSS MS-14 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 0.96 mg/L
Fluoride 0.08 J mg/L
Nitrate 0.04 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.09 J mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.055
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
5.49
mg/L
Iron (Fe)
0.014
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.16
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.184 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.213 J
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
2.27
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 67.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 18:54
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 18:54
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 18:54
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 18:54
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 18:54
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 11:56
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:47
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:47
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:47
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:47
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:47
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:47
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:47
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:47
CELL106
1
0.104
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.111
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.249
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.032
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.185
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.077
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.787
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.037
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.18
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.256
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.193
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.035
1
SW 6020E
09/29/2023 21:08
MHALL3
1
0.041
1
SW 6020B
09/29/2023 21:08
MHALL3
1
0.114
1
SW 6020E
09/29/2023 21:08
MHALL3
25
25
1
SM2540C
09/29/2023 09:02
HHOOGKA

Certificate of Laboratory Analysis Page 11 of28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-15 Sample #: 2023024026
Collection Date: 09/27/2023 11:20 AM Loc code: MSS MS-15 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride
81
mg/L
Fluoride
0.0479 U
mg/L
Nitrate
9.4
mg/L
Nitrate as N
2.1
mg-N/L
Sulfate
0.67
mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg)
0.01 J
ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.361
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
32.8
mg/L
Iron (Fe)
0.547
mg/L
Lithium (Li)
0.002 J
mg/L
Magnesium (Mg)
15.7
mg/L
Manganese (Mn)
0.006
mg/L
Zinc (Zn)
0.004 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.153 J
ug/L
Arsenic (As)
0.115 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.049 J
ug/L
Chromium (Cr)
19.5
ug/L
Cobalt (Co)
0.106 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.235 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
24.7
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
2.89
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 299 mg/L
Method Analysis Date/Time Analyst
2
0.0154
20
EPA 9056A
09/27/2023 23:07
EBATIAN
0.2
0.0479
2
EPA 9056A
09/27/2023 23:07
EBATIAN
0.2
0.0209
2
EPA 9056A
09/27/2023 23:07
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 23:07
EBATIAN
0.2
0.0428
2
EPA 9056A
09/27/2023 23:07
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 12:05
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:51
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:51
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:51
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:51
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:51
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:51
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:51
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:51
CELL106
1
0.104
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.111
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.249
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.032
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.185
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.077
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.787
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.037
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.18
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.256
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.193
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.035
1
SW 6020E
09/29/2023 21:18
MHALL3
1
0.041
1
SW 6020B
09/29/2023 21:18
MHALL3
1
0.114
1
SW 6020E
09/29/2023 21:18
MHALL3
25
25
1
SM2540C
09/29/2023 09:02
HHOOGKA

Certificate of Laboratory Analysis Page 12 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS MS-16 Sample #: 2023024027
Collection Date: 09/27/2023 10:45 AM Loc code: MSS MS-16 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 1.7 mg/L
Fluoride 0.21 mg/L
Nitrate 2.7 mg/L
Nitrate as N 0.61 mg-N/L
Sulfate 0.39 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.096
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
8.29
mg/L
Iron (Fe)
1.53
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
3.90
mg/L
Manganese (Mn)
0.027
mg/L
Zinc (Zn)
0.006
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.208 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
4.22
ug/L
Cobalt (Co)
0.394 J
ug/L
Copper (Cu)
1.94
ug/L
Lead (Pb)
0.584 J
ug/L
Molybdenum (Mo)
0.306 J
ug/L
Nickel (Ni)
2.01
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
6.31
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 82.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 19:33
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 19:33
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 19:33
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 19:33
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 19:33
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 12:07
SNEGLIA
0.005
0.002
1
SW 601OD
09/29/2023 19:56
CELL106
0.05
0.005
1
SW 601OD
09/29/2023 19:56
CELL106
0.05
0.012
1
SW 601OD
09/29/2023 19:56
CELL106
0.01
0.004
1
SW 601OD
09/29/2023 19:56
CELL106
0.005
0.002
1
SW 601OD
09/29/2023 19:56
CELL106
0.02
0.008
1
SW 601OD
09/29/2023 19:56
CELL106
0.005
0.001
1
SW 601OD
09/29/2023 19:56
CELL106
0.005
0.004
1
SW 601OD
09/29/2023 19:56
CELL106
1
0.104
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.111
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.249
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.032
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.185
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.077
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.787
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.037
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.18
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.256
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.193
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.035
1
SW 6020E
09/29/2023 21:27
MHALL3
1
0.041
1
SW 6020B
09/29/2023 21:27
MHALL3
1
0.114
1
SW 6020E
09/29/2023 21:27
MHALL3
25
25
1
SM2540C
09/29/2023 09:02
HHOOGKA

Certificate of Laboratory Analysis Page 13 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS
Cl-LEACHATE
Sample #:
2023024029
Collection Date: 09/27/2023 08:50 AM
Loc code: MSS C1-LEACHATE
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23090400
Chloride
370
mg/L
5
0.0154
50
EPA 9056A
09/27/2023 22:48
EBATIAN
Fluoride
1.2 J
mg/L
5
0.0479
50
EPA 9056A
09/27/2023 22:48
EBATIAN
Nitrate
8.9
mg/L
5
0.0209
50
EPA 9056A
09/27/2023 22:48
EBATIAN
Nitrate as N
2.0
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2023 22:48
EBATIAN
Sulfate
2800
mg/L
50
0.0428
500
EPA 9056A
09/27/2023 22:48
EBATIAN
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23100007
Zinc (Zn)
0.263
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.022
mg/L
0.005
0.002
Boron (B)
57.6
mg/L
0.5
0.005
Calcium (Ca)
547
mg/L
0.5
0.012
Iron (Fe)
164
mg/L
0.1
0.004
Lithium (Li)
2.01
mg/L
0.005
0.002
Magnesium (Mg)
227
mg/L
0.2
0.008
Manganese (Mn)
5.65
mg/L
0.005
0.001
Zinc (Zn)
0.264
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS
(DISSOLVED) - Q23100013
Beryllium (Be)
2.51
ug/L
1
0.249
Cadmium (Cd)
0.274 J
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Copper (Cu)
5.57
ug/L
1
0.787
Lead (Pb)
0.131 J
ug/L
1
0.037
Nickel (Ni)
112
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
1
EPA 7470A
09/29/2023 12:10
SNEGLIA
1
SW 601 OD
10/03/2023 18:07
CELL106
1
SW 601 OD
09/29/2023 20:01
CELL106
10
SW 601 OD
09/29/2023 20:01
CELL106
10
SW 601 OD
09/29/2023 20:01
CELL106
10
SW 601 OD
09/29/2023 20:01
CELL106
1
SW 601 OD
09/29/2023 20:01
CELL106
10
SW 601 OD
09/29/2023 20:01
CELL106
1
SW 601 OD
09/29/2023 20:01
CELL106
1
SW 601 OD
09/29/2023 20:01
CELL106
1
SW 6020B
10/03/2023 18:55
MHALL3
1
SW 6020B
10/03/2023 18:55
MHALL3
1
SW 6020E
10/03/2023 18:55
MHALL3
1
SW 6020B
10/03/2023 18:55
MHALL3
1
SW 6020E
10/03/2023 18:55
MHALL3
1
SW 6020B
10/03/2023 18:55
MHALL3
1
SW 6020B
10/03/2023 18:55
MHALL3

Certificate of Laboratory Analysis Page 14 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS C1-LEACHATE
Sample #:
2023024029
Collection Date:
09/27/2023 08:50 AM
Loc code: MSS C1-LEACHATE
Matrix:
GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23090413
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
09/29/2023 21:36
MHALL3
Arsenic (As)
1.94
ug/L
1
0.111
1
SW 6020B
09/29/2023 21:36
MHALL3
Beryllium (Be)
3.63
ug/L
1
0.249
1
SW 6020E
09/29/2023 21:36
MHALL3
Cadmium (Cd)
0.246 J
ug/L
1
0.032
1
SW 6020B
09/29/2023 21:36
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
09/29/2023 21:36
MHALL3
Cobalt (Co)
42.7
ug/L
1
0.077
1
SW 6020E
09/29/2023 21:36
MHALL3
Copper (Cu)
2.50
ug/L
1
0.787
1
SW 6020B
09/29/2023 21:36
MHALL3
Lead (Pb)
0.126 J
ug/L
1
0.037
1
SW 6020E
09/29/2023 21:36
MHALL3
Molybdenum (Mo)
634
ug/L
100
0.18
100
SW 6020B
09/29/2023 21:36
MHALL3
Nickel (Ni)
108
ug/L
1
0.256
1
SW 6020E
09/29/2023 21:36
MHALL3
Selenium (Se)
46.1
ug/L
1
0.193
1
SW 6020B
09/29/2023 21:36
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020E
09/29/2023 21:36
MHALL3
Thallium (TI)
0.098 J
ug/L
1
0.041
1
SW 6020B
09/29/2023 21:36
MHALL3
Vanadium (V)
0.114 U
ug/L
1
0.114
1
SW 6020E
09/29/2023 21:36
MHALL3
TOTAL DISSOLVED SOLIDS - Q23090428
TDS
4900
mg/L
100
25
1
SM2540C
09/29/2023 09:02
HHOOGKA

Site: MSS FD-20230927-1
Collection Date: 09/27/2023
Certificate of Laboratory Analysis Page 15 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Sample #: 2023024030
Loc code: MSS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 3.4 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.08 J mg/L
Nitrate as N 0.02 J mg-N/L
Sulfate 0.23 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.079
mg/L
Boron (B)
0.027 J
mg/L
Calcium (Ca)
2.48
mg/L
Iron (Fe)
0.314
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.29
mg/L
Manganese (Mn)
0.016
mg/L
Zinc (Zn)
0.004 J
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
2.85
ug/L
Cobalt (Co)
0.221 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.087 J
ug/L
Molybdenum (Mo)
0.371 J
ug/L
Nickel (Ni)
1.23
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
0.268 J
ug/L
TOTAL DISSOLVED SOLIDS -
023090428
TDS 35.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/28/2023 12:14
Ebatian
0.1
0.0479
1
EPA 9056A
09/28/2023 12:14
Ebatian
0.1
0.0209
1
EPA 9056A
09/28/2023 12:14
Ebatian
0.023
0.002
1
EPA 9056A
09/28/2023 12:14
Ebatian
0.1
0.0428
1
EPA 9056A
09/28/2023 12:14
Ebatian
0.05
0.01
1
EPA 7470A
09/29/2023 12:13
SNEGLIA
0.005
0.002
1
SW 601 OD
09/29/2023 20:06
CELL106
0.05
0.005
1
SW 601 OD
09/29/2023 20:06
CELL106
0.05
0.012
1
SW 601 OD
09/29/2023 20:06
CELL106
0.01
0.004
1
SW 601 OD
09/29/2023 20:06
CELL106
0.005
0.002
1
SW 601 OD
09/29/2023 20:06
CELL106
0.02
0.008
1
SW 601 OD
09/29/2023 20:06
CELL106
0.005
0.001
1
SW 601 OD
09/29/2023 20:06
CELL106
0.005
0.004
1
SW 601 OD
09/29/2023 20:06
CELL106
1
0.104
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.111
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.249
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.032
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.185
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.077
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.787
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.037
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.18
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.256
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.193
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.035
1
SW 6020E
09/29/2023 21:46
MHALL3
1
0.041
1
SW 6020B
09/29/2023 21:46
MHALL3
1
0.114
1
SW 6020E
09/29/2023 21:46
MHALL3
25
25
1
SM2540C
09/29/2023 09:03
HHOOGKA

Certificate of Laboratory Analysis Page 16 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS EB-20230927-0815 Sample #: 2023024031
Collection Date: 09/27/2023 08:15 AM Loc code: MSS EB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 0.03 J mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.05 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.018 J
mg/L
Calcium (Ca)
0.012 U
mg/L
Iron (Fe)
0.005 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 21:50
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 21:50
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 21:50
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 21:50
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 21:50
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 12:16
SNEGLIA
0.005
0.002
1
SW 601 OD
09/29/2023 20:11
CELL106
0.05
0.005
1
SW 601 OD
09/29/2023 20:11
CELL106
0.05
0.012
1
SW 601 OD
09/29/2023 20:11
CELL106
0.01
0.004
1
SW 601 OD
09/29/2023 20:11
CELL106
0.005
0.002
1
SW 601 OD
09/29/2023 20:11
CELL106
0.02
0.008
1
SW 601 OD
09/29/2023 20:11
CELL106
0.005
0.001
1
SW 601 OD
09/29/2023 20:11
CELL106
0.005
0.004
1
SW 601 OD
09/29/2023 20:11
CELL106
1
0.104
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.111
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.249
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.032
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.185
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.077
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.787
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.037
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.18
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.256
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.193
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.035
1
SW 6020E
09/29/2023 21:55
MHALL3
1
0.041
1
SW 6020B
09/29/2023 21:55
MHALL3
1
0.114
1
SW 6020E
09/29/2023 21:55
MHALL3

Certificate of Laboratory Analysis Page 17 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Site: MSS FB-20230927-0830 Sample #: 2023024032
Collection Date: 09/27/2023 08:30 AM Loc code: MSS QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23090400
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.04 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q23090422
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23090409
Barium (Ba)
0.002 U
mg/L
Boron (B)
0.012 J
mg/L
Calcium (Ca)
0.012 U
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.008 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS -
Q23090413
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI)
0.041 U
ug/L
Vanadium (V)
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/27/2023 22:09
EBATIAN
0.1
0.0479
1
EPA 9056A
09/27/2023 22:09
EBATIAN
0.1
0.0209
1
EPA 9056A
09/27/2023 22:09
EBATIAN
0.023
0.002
1
EPA 9056A
09/27/2023 22:09
EBATIAN
0.1
0.0428
1
EPA 9056A
09/27/2023 22:09
EBATIAN
0.05
0.01
1
EPA 7470A
09/29/2023 12:19
SNEGLIA
0.005
0.002
1
SW 601 OD
09/29/2023 20:16
CELL106
0.05
0.005
1
SW 601 OD
09/29/2023 20:16
CELL106
0.05
0.012
1
SW 601 OD
09/29/2023 20:16
CELL106
0.01
0.004
1
SW 601 OD
09/29/2023 20:16
CELL106
0.005
0.002
1
SW 601 OD
09/29/2023 20:16
CELL106
0.02
0.008
1
SW 601 OD
09/29/2023 20:16
CELL106
0.005
0.001
1
SW 601 OD
09/29/2023 20:16
CELL106
0.005
0.004
1
SW 601 OD
09/29/2023 20:16
CELL106
1
0.104
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.111
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.249
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.032
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.185
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.077
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.787
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.037
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.18
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.256
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.193
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.035
1
SW 6020E
09/29/2023 22:05
MHALL3
1
0.041
1
SW 6020B
09/29/2023 22:05
MHALL3
1
0.114
1
SW 6020E
09/29/2023 22:05
MHALL3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 18 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090400 Dionex INORGANIC IONS BY IC
Blank # 1
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.002
0.002
mg/L
1
0.0428
0.1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
4.98
4.98
mg/L
1
0.0154
5
99.6
80
120
Fluoride
5.14
5.14
mg/L
1
0.0479
5
103
80
120
Nitrate
5.01
5.01
mg/L
1
0.0209
5
100
80
120
Sulfate
5
5
mg/L
1
0.0428
5
99.9
80
120
Parent Sample:
J23080627 -- 2023021556
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
1.97
19.7
mg/L
10
0.0154
5
100
80
120
Fluoride
Not Tested
mg/L
1
0.0479
5
80
120
Nitrate
6.84
6.84
mg/L
1
0.0209
5
102
80
120
Sulfate
5.17
51.6
mg/L
10
0.0428
5
91
80
120
Parent Sample:
J23080627 -- 2023021556
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Chloride
1.95
19.5
mg/L
10
0.0154
5
96.8
80
120
3.45
Fluoride
Not Tested
mg/L
1
0.0479
5
80
120
Nitrate
6.72
6.72
mg/L
1
0.0209
5
100
80
120
2.37
Sulfate
5.15
51.5
mg/L
10
0.0428
5
87.4
80
120
4.04
Parent Sample:
J23090511
-- 2023024019
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Chloride
6.32
6.32
mg/L
1
0.0154
5
101
80
120
Fluoride
5.37
5.37
mg/L
1
0.0479
5
105
80
120
Nitrate
5.81
5.81
mg/L
1
0.0209
5
102
80
120
Sulfate
5.27
5.27
mg/L
1
0.0428
5
102
80
120
Parent Sample:
J23090511
-- 2023024019
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Chloride
6.22
6.22
mg/L
1
0.0154
5
99.5
80
120
1.89
Fluoride
5.3
5.3
mg/L
1
0.0479
5
104
80
120
1.36
Nitrate
5.71
5.71
mg/L
1
0.0209
5
99.7
80
120
2.1
Sulfate
5.18
5.18
mg/L
1
0.0428
5
100
80
120
1.71
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 19 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090422 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.004
0.004
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.003
0.003
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.006
0.006
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.002
0.002
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
1.99
1.99
ug/L
1
0.01
2
99.6 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.98
1.98
ug/L
1
0.01
2
99
85 115
MS # 1
Parent Sample:
J23090047 -- 2023021929
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL UCL
Qualifier
Mercury (Hg)
1.16
1.16
ug/L
1
0.01
1
111
75 125
MSD # 1
Parent Sample:
J23090047 -- 2023021929
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.14
1.14
ug/L
1
0.01
1
109
75 125 1.55
MS # 2
Parent Sample:
J23090473 -- 2023023821
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.994
0.994
ug/L
1
0.01
1
99.3
75 125
MSD # 2
Parent Sample:
J23090473 -- 2023023821
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.98
0.98
ug/L
1
0.01
1
97.9
75 125 1.42
MS # 3
Parent Sample:
J23090496 -- 2023023951
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.1
1.1
ug/L
1
0.01
1
109
75 125

Certificate of Laboratory Analysis Page 20 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090422 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3
Parent Sample:
J23090496
-- 2023023951
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
1.09
1.09
ug/L
1
0.01
1
107
75
125 1.11
MS # 4
Parent Sample:
J23090511
-- 2023024025
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
103
75
125
MSD # 4
Parent Sample:
J23090511
-- 2023024025
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
103
75
125 0.0969

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23100007 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Page 21 of 28
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
-0.000345
-0.000345
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.08
5.08
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J23090047 -- 2023021948
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.05
5.05
mg/L
1
0.004
5
101
70
130
MSD # 1
Parent Sample:
J23090047 -- 2023021948
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.04
5.04
mg/L
1
0.004
5
101
70
130 0.297
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090409 ICP_TRM TOTAL RECOVERABLE METALS BY iCP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.0012
-0.0012
mg/L
1
0.002
0.005
< MDL
Boron (B)
-0.000589
-0.000589
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00558
0.00558
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.000933
0.000933
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.00124
-0.00124
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.0012
0.0012
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000029
-0.000029
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000047
-0.000047
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 22 of 28
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.99
4.99
mg/L
1
0.002
5
99.7
80
120
Boron (B)
4.86
4.86
mg/L
1
0.005
5
97.3
80
120
Calcium (Ca)
5.06
5.06
mg/L
1
0.012
5
101
80
120
Iron (Fe)
5
5
mg/L
1
0.004
5
100
80
120
Lithium (Li)
4.83
4.83
mg/L
1
0.002
5
96.6
80
120
Magnesium (Mg)
4.96
4.96
mg/L
1
0.008
5
99.1
80
120
Manganese (Mn)
5.02
5.02
mg/L
1
0.001
5
100
80
120
Zinc (Zn)
5
5
mg/L
1
0.004
5
100
80
120
MS # 1
Parent Sample:
J23090047
-- 2023021929
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Barium (Ba)
5.19
5.19
mg/L
1
0.002
5
103
75
125
Boron (B)
5.04
5.04
mg/L
1
0.005
5
101
75
125
Calcium (Ca)
15
15
mg/L
1
0.012
5
102
75
125
Iron (Fe)
5.27
5.27
mg/L
1
0.004
5
103
75
125
Lithium (Li)
5
5
mg/L
1
0.002
5
99.8
75
125
Magnesium (Mg)
9.75
9.75
mg/L
1
0.008
5
98.4
75
125
Manganese (Mn)
5.17
5.17
mg/L
1
0.001
5
103
75
125
Zinc (Zn)
5.11
5.11
mg/L
1
0.004
5
102
75
125
MSD # 1
Parent Sample:
J23090047
-- 2023021929
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.2
5.2
mg/L
1
0.002
5
103
75
125
0.212
Boron (B)
5.01
5.01
mg/L
1
0.005
5
100
75
125
0.597
Calcium (Ca)
15.1
15.1
mg/L
1
0.012
5
103
75
125
0.419
Iron (Fe)
5.27
5.27
mg/L
1
0.004
5
103
75
125
0.0948
Lithium (Li)
4.99
4.99
mg/L
1
0.002
5
99.6
75
125
0.18
Magnesium (Mg)
9.77
9.77
mg/L
1
0.008
5
98.9
75
125
0.225
Manganese (Mn)
5.19
5.19
mg/L
1
0.001
5
104
75
125
0.328
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 23 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090409 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23090047 -- 2023021929
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.12 5.12 mg/L 1 0.004 5 102 75 125 0.117

Certificate of Laboratory Analysis Page 24 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23100013 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
0.002
0.002
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.003
0.003
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.001
-0.001
ug/L
1
0.185
1
< MDL
Copper (Cu)
0.016
0.016
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.009
0.009
ug/L
1
0.037
1
< MDL
Nickel (Ni)
0.009
0.009
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.003
0.003
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Beryllium (Be)
50.3
50.3
ug/L
1
0.249
50
101
80
120
Cadmium (Cd)
50.2
50.2
ug/L
1
0.032
50
100
80
120
Chromium (Cr)
51.3
51.3
ug/L
1
0.185
50
103
80
120
Copper(Cu)
51.9
51.9
ug/L
1
0.787
50
104
80
120
Lead (Pb)
50.7
50.7
ug/L
1
0.037
50
101
80
120
Nickel (Ni)
50.8
50.8
ug/L
1
0.256
50
102
80
120
Silver (Ag)
50.9
50.9
ug/L
1
0.035
50
102
80
120
Parent Sample:
J23090511
-- 2023024029
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Beryllium (Be)
47.6
47.6
ug/L
1
0.249
50
90.2
75
125
Cadmium (Cd)
48.3
48.3
ug/L
1
0.032
50
96
75
125
Chromium (Cr)
48
48
ug/L
1
0.185
50
95.8
75
125
Copper (Cu)
56.2
56.2
ug/L
1
0.787
50
101
75
125
Lead (Pb)
50.9
50.9
ug/L
1
0.037
50
101
75
125
Nickel (Ni)
165
165
ug/L
1
0.256
50
107
75
125
Silver (Ag)
48.7
48.7
ug/L
1
0.035
50
97.5
75
125
Parent Sample:
J23090511
-- 2023024029
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
RPD
Beryllium (Be)
46.1
46.1
ug/L
1
0.249
50
87.2
75
125
3.44
Cadmium (Cd)
48.9
48.9
ug/L
1
0.032
50
97.2
75
125
1.2
Chromium (Cr)
48.3
48.3
ug/L
1
0.185
50
96.5
75
125
0.757
Copper (Cu)
56.5
56.5
ug/L
1
0.787
50
102
75
125
0.703
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
103
75
125
1.08
Nickel (Ni)
166
166
ug/L
1
0.256
50
108
75
125
1.35
Silver (Ag)
49.2
49.2
ug/L
1
0.035
50
98.5
75
125
1.01
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090413 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.024
-0.024
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.005
0.005
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.015
0.015
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.118
-0.118
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.001
-0.001
ug/L
1
0.077
1
< MDL
Copper (Cu)
-0.033
-0.033
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.001
-0.001
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.009
0.009
ug/L
1
0.18
1
< MDL
Nickel (Ni)
-0.019
-0.019
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.063
-0.063
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.009
0.009
ug/L
1
0.035
1
< MDL
Thallium (TI)
-0.006
-0.006
ug/L
1
0.041
1
< MDL
Vanadium (V)
-0.017
-0.017
ug/L
1
0.114
1
< MDL
LCS # 1
Page 25 of 28
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recover v
LCL
UCL
Antimony (Sb)
49.5
49.5
ug/L
1
0.104
50
99.1
80
120
Arsenic (As)
49.7
49.7
ug/L
1
0.111
50
99.4
80
120
Beryllium (Be)
51.9
51.9
ug/L
1
0.249
50
104
80
120
Cadmium (Cd)
49.5
49.5
ug/L
1
0.032
50
99.1
80
120
Chromium (Cr)
48.9
48.9
ug/L
1
0.185
50
97.8
80
120
Cobalt (Co)
48.7
48.7
ug/L
1
0.077
50
97.3
80
120
Copper (Cu)
48.7
48.7
ug/L
1
0.787
50
97.4
80
120
Lead (Pb)
49.1
49.1
ug/L
1
0.037
50
98.2
80
120
Molybdenum (Mo)
49.5
49.5
ug/L
1
0.18
50
99
80
120
Nickel (Ni)
49
49
ug/L
1
0.256
50
97.9
80
120
Selenium (Se)
47.9
47.9
ug/L
1
0.193
50
95.8
80
120
Silver (Ag)
50.2
50.2
ug/L
1
0.035
50
100
80
120
Thallium (TI)
48.9
48.9
ug/L
1
0.041
50
97.8
80
120
Vanadium (V)
49.3
49.3
ug/L
1
0.114
50
98.6
80
120
MS # 1
Parent Sample:
J23090047
-- 2023021934
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.8
48.8
ug/L
1
0.104
50
97.5
75
125
Arsenic (As)
47.6
47.6
ug/L
1
0.111
50
95
75
125
Beryllium (Be)
52.1
52.1
ug/L
1
0.249
50
104
75
125
Cadmium (Cd)
49.1
49.1
ug/L
1
0.032
50
98.2
75
125
Chromium (Cr)
49.5
49.5
ug/L
1
0.185
50
97.6
75
125
Cobalt (Co)
47.7
47.7
ug/L
1
0.077
50
94.1
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090413 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Copper (Cu)
48.5
48.5
ug/L
1
0.787
Lead (Pb)
48.3
48.3
ug/L
1
0.037
Molybdenum (Mo)
49.3
49.3
ug/L
1
0.18
Nickel (Ni)
48.6
48.6
ug/L
1
0.256
Selenium (Se)
46.3
46.3
ug/L
1
0.193
Silver (Ag)
49.9
49.9
ug/L
1
0.035
Thallium (TI)
47.6
47.6
ug/L
1
0.041
Vanadium (V)
49.7
49.7
ug/L
1
0.114
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Antimony (Sb)
49.2
49.2
ug/L
1
0.104
Arsenic (As)
48.1
48.1
ug/L
1
0.111
Beryllium (Be)
54.3
54.3
ug/L
1
0.249
Cadmium (Cd)
49.7
49.7
ug/L
1
0.032
Chromium (Cr)
50.6
50.6
ug/L
1
0.185
Cobalt (Co)
48.3
48.3
ug/L
1
0.077
Copper (Cu)
49.1
49.1
ug/L
1
0.787
Lead (Pb)
49
49
ug/L
1
0.037
Molybdenum (Mo)
49.9
49.9
ug/L
1
0.18
Nickel (Ni)
48.8
48.8
ug/L
1
0.256
Selenium (Se)
47.4
47.4
ug/L
1
0.193
Silver (Ag)
50.2
50.2
ug/L
1
0.035
Thallium (TI)
48.2
48.2
ug/L
1
0.041
Vanadium (V)
50.4
50.4
ug/L
1
0.114
Parent Sample:
J23090047 -- 2023021934
Spike
% Recovery
LCL
UCL
50
95.3
75
125
50
96.3
75
125
50
97.2
75
125
50
95.4
75
125
50
92.7
75
125
50
98.5
75
125
50
95.1
75
125
50
98.4
75
125
Parent Sample:
J23090047
-- 2023021934
Spike
% Recovery
LCL
UCL
RPD
50
98.2
75
125
0.74
50
96
75
125
1.04
50
109
75
125
4.25
50
99.3
75
125
1.14
50
99.8
75
125
2.24
50
95.3
75
125
1.23
50
96.5
75
125
1.31
50
97.7
75
125
1.41
50
98.4
75
125
1.21
50
95.7
75
125
0.293
50
94.7
75
125
2.17
50
99.2
75
125
0.686
50
96.4
75
125
1.33
50
99.8
75
125
1.43
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 27 of 28
This report shall not be reproduced, except in full.
Order # J23090511
Level II QC Summary
Q23090428 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 0
Parameter Measured Final
TDS -0.1
Duplicate # 1
Parameter Measured Final
TDS 56
Duplicate # 2
Parameter Measured Final
TDS 530
LCS # 1
LCS # 2
Parameter Measured Final
TDS 485
Parameter Measured Final
TDS 485
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23090511
-- 2023024019
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
3.64
Parent Sample:
J23090517 -- 2023024071
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
0.377
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
97
90
110
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
97
90
110

Page 28 of 28
CHAIN OF CUSTODY RECORD AND ANALYSIS RFOtIFST FORM
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Project Name MARSHALL FGD LANDFILL P^°"`"°: iV°nd°r -S( Drinking Water_ UST_
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Project•. AMS000640 Activity ID: Facility iMMSS
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Container Volume (mL)
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SAMPLE ID i
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Dab Time Primed Name Si nature
(Metals Prep - TRM) ICP -
SW6010D: Be, B, Ca, Fe,
Li, Mg, Mn, Zn (8)1 Hg
EPA 7470A I INS -
SW60208: Sb, As, Ba,
Cd, Cy Co, Cu, Pb, Mo,
Ni, Se, AgTl, V (l4)Pb,
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Comments
Regulatory Agency: NCDENR/DWM - SW Section - NCDEQ EDD Required I Permit #18-09 EQUIS EDD REQUIRED
Use indicated or comparable methods. Note: Hardness by Calculation (Ca + Mg ICP_TRM) added to SW-1
e`
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V
'Other
•Add. Cost Will Apply

Semiannual Water Quality Monitoring Report — September 2023 Sampling Event
Marshall Steam Station — FGD Residue Landfill (Permit No. 1809-INDUS)
Terrell, North Carolina
APPENDIX C
TIME VERSUS CONSTITUENT CONCENTRATIONS PLOTS
L7
synTerra
Science & Engineering Consultants

MS-8
MS-10
10
10
9
9
8
8
D
6
D 6
-0
c
5
-0 5
c
4
S 4
Q'
3
a 3
2
2
1
1
0
0
0 0
0 0 0 0 0
0
0
0 0 0 0 0 0
0 0 0
0 0 0 0 0 0 0 0
N N
N N N N N
N
N
N N N N N N
N N N
N N N N N N N N
O O
V OD
O O O O O
co NO N N W
O
A
O
O
V
O O O O O O
O O 0
W co O N W
O_ O O
A (Ji O
O O O O O O O O
N N N N
V Do O O N W A
Date
Date
MS-11
MS-12
10
10
9
9
8
8
D
6
6-
-2
-o
c
5
-0 5
c
4
4
2
Q'
3
=
3
2
2
1
1
0
0
0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0
0 o
O
o O o 0 0 0
0 0 0
0 0 0 0 0 0 0 0
N N N N
O O O O
N N N N N N N N N N N N
O O O O O O O O O O O Cl
N N
O O
71
N
OO
N N N N
OO O O O
N
ON N
N N N Cl ClN
N ON ClO
O O O
OD O O
N NNN
N W A cy, O) V 00 (D O
W
O
VOD
OO
CD O — W
_
A U. 0)
jNV
V OD (D O WN?
Date
Date
LEGEND
Notes:
S.U.— Standard units
15A NCAC 02L PH STANDARD
(6.5-8.5)
DUKE
DRAWN BY: D. AVARD
DATE: 06/06/2022
APPENDIX C
� Deteat tect
ENERGY
REVISED BY: K. O'REILLY
DATE: 12/04/2023
TIME VERSUS PH CONCENTRATIONS
GAROLI�:
CHECKED BY: T. COLTON
DATE: 12/04/2023
FGD LANDFILL
APPROVED BY: T. COLTON
DATE: 12/04/2023
SEMIANNUAL WATER QUALITY
410
PROJECT MANAGER: T. COLTON
MONITORING REPORT
1 MARSHALL STEAM STATION
www.synterracorp.com
WnTerm
TERRELL, NORTH CAROLINA

MS-13
MS-14
10
10
9
9
8
8
N
7
7
6
6
5
5
ca
ca
4
4
2
CL
3
2
CL
3
2
2
1
1
0
0
0
0
0 0
0 0 0
0
0 0 0 0 0
0
0 0
0
0
0
0 0 0 0 0 0
0 0 0
0 0 0 0 0 0 0 0
N
N
N N
N N N
N
N fJ N N N
O O
N
O
N N
O O
N
O
N
O
N
N N N N N N
N N N
N N N N N N N N
OD
(OO O
N W
A
Cn O V co CD
O
j N
W
?
O
OV
co O O_ O O O
OOD w O — N W
O_
A M O
V co CD O j N W A
Date
Date
MS-15
MS-16
10
10
9
N A
—
8
8
7
N
7
6
6-
5-
4
4
CL
3
CL
3
2
1
1
0
0
0
0
0 0
0 0 0
0
0 0 0 0 0
0
0 0
0
0
0
0 0 0 0 0 0
0 0 0
0 0 0 0 0 0 0 0
NO
NO
N
N
N N ON ON ON ON
ON ON ON
N O
ON ON ON ON ON ON Cl
OOO
V
OD
w O
O
W
O
A
Cf 0) --4 co w
O
O
O O
jN
O
W
O
?
V
OD w O — N W
A N D)
V coOD w O j N W ?
Date
Date
LEGEND
Notes:
s.U.— standard Units
15A NCAC 02L PH STANDARD
(6.5-8.5)
DUKE
DRAWN BY: D. AVARD
DATE: 06/06/2022
APPENDIX C
Detedt tect
ENERGY
REVISED BY: K. Y
DATE: 12/04/2023
TIME VERSUS PH CONCENTRATIONS
CAROLIN.•
COLTON
CHECKED BY: T. COLTON
DATE: 12/04/2023
FGD LANDFILL
APPROVED BY: T. COLTON
DATE: 12/04/2023
SEMIANNUAL WATER QUALITY
41P
PROJECT MANAGER: T. COLTON
MONITORING REPORT
MARSHALL STEAM STATION
www.synterracorp.com
synTerra
TERRELL, NORTH CAROLINA

MS-1 5
35
J 28
0)
=.
0
cu 21
aD
U
0
U
� 14
0
U 7
Q
o
1
Q
1
o
1
0
1
0
1
0
0
0
1
0 0 0
1 1 1
0 0 0
1 1 1
0 0
0
1
0
1
N3
N
N
N
IV
N
N
N
N IV N
N IV IV
N N
N
N
0
0
0
0
0
0
0
0
0 0 0
0 0 0
0 0
0
0
CD
a
CD
s
s
1
1 1 1
1
s N
N N
N
IV
4
00
(D
a
N
W
-0:1
01 d) -I
OO (D Q
N
W
-1�:.
Date
LEGEND
Notes: 15A NCAC 02L CHROMIUM STANDARD
DUKE
DRAWN BY: D. AVARD
DATE: 06/06/2022
APPENDIX C
Non -detect
Detect
µg/L— micrograms per liter
(10 µg/L)
441)
r
ENERGY
REVISED BY: K. O'REILLY
DATE: 12/04/2023
TIME VERSUS CHROMIUM CONCENTRATIONS
CHECKED BY: T. COLTON
DATE: 12/04/2023
FGD LANDFILL
APPROVED BY: T. COLTON
DATE: 12/04/2023
SEMIANNUAL WATER QUALITY
,trip
PROJECT MANAGER: T. COLTON
MONITORING REPORT
MARSHALL STEAM STATION
www.synterracorp.com
synTerm
TERRELL, NORTH CAROLINA

MS-1 2
10
8
J
o
�
Cu
U
0
U
4
Cu
0
V
r
V
0
0
0
0 0
0
0
0
N
1
N
1
N
N N
N
N
R]
0
O
0
0 C)Q
C)
�
�
Q
—4
oo
(o
0 1
N
w
4i..
Date
LEGEND
Notes:
15A NCAC 02L COBALT STANDARD
DUKE r�
DRAWN BY: D. AVARD
DATE: 06/06/2022
APPENDIX C
Non -detect
Detect
µg/L— micrograms per liter
(1 µg/L)
NERVr Y
ENERGY
REVISED BY: K. O'REILLY
DATE: 12/04/2023
TIME VERSUS COBALT CONCENTRATIONS
CHECKED BY: T. COLTON
DATE: 12/04/2023
FGD LANDFILL
APPROVED BY: T. COLTON
DATE: 12/04/2023
SEMIANNUAL WATER QUALITY
,trip
PROJECT MANAGER: T. COLTON
MONITORING REPORT
MARSHALL STEAM STATION
www.synterracorp.com
synTerm
TERRELL, NORTH CAROLINA

MS-1 5
2000
1600
J
0 1200
Cu
aD
U
0 800
U
0
L
H 11
V
o
0
0
0
0
0
0
0
0 0 0
0 0 0
0 0
0
0
N
N
N
N
N
N
N
N
N N N
N N N
N N
N
N
0
a
0
0
0
0
0
0
0 0 0
0 0 0
0 0
0
0
0
0
0
�
�
�
�
�
1 1 1
1 � N
N N
N
N
4
Od
(D
O
N
W
Gil ai —1
07 (D O
N
W
4i..
Date
LEGEND
Notes: 15A NCAC 02L IRON STANDARD
— micrograms liter (300
DUKE
DRAWN BY: D. AVARD
DATE: 06/06/2022
APPENDIX C
Non -detect
� Detect
µg/Lper µg/L)
r
tENERGY
REVISED BY: K. O'REILLY
DATE: 12/04/2023
TIME VERSUS IRON CONCENTRATIONS
NERVY
CHECKED BY: T. COLTON
DATE: 12/04/2023
FGD LANDFILL
APPROVED BY: T. COLTON
DATE: 12/04/2023
SEMIANNUAL WATER QUALITY
,trip
PROJECT MANAGER: T. COLTON
MONITORING REPORT
MARSHALL STEAM STATION
www.synterracorp.com
synTerm
TERRELL, NORTH CAROLINA