WS-3985_13353_CA_MRP_20231009

CES Group Engineers, LLP
IMPROVING. PROTECTING. RESTORING.

CHARLOTTE, NC
3525 Whitehall Park Drive, Suite 150
Charlotte, NC 28273

COLUMBIA, SC
1411 Gervais Street, Suite 140
Columbia, SC 29201

www.ces-group.net

October 9, 2023

Scott Ryals, PE
Environmental Engineer
North Carolina Department of Environmental Quality
DWM UST Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

RE: Groundwater Monitoring Report
Bullins Grocery
Incident No.: 13353
UST ID No.: WS-3985
Facility ID No.: N/A
1107 N Main Street
Walnut Cove, Stokes County, North Carolina 27052

Dear Mr. Ryals:

CES Group Engineers, LLP (CES), while under contract with the North Carolina Department of
Environmental Quality (NCDEQ), Contract No.: N042023, executed on February 24, 2023, is
submitting this Groundwater Monitoring Report to you electronically via email. The performed
work was authorized by NCDEQ Task Authorization (TA) #01, approved on April 21, 2023. Should
you have any questions regarding this submittal, please do not hesitate to contact me at (704)
325-5408.

Regards,

Greg Hans, PMP
Environmental Division Manager

Enclosures: Groundwater Monitoring Report

CES Project No. 8076.0123E 1
October 9, 2023

Groundwater Monitoring Report

Bullins Grocery
1107 N Main Street
Walnut Cove, Stokes County, North Carolina 27052
NCDEQ Incident No.: 13353
UST ID No.: WS-3985
Facility ID No.: N/A

October 9, 2023

Prepared for:

Mr. Scott Ryals
NCDEQ DWM UST Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Prepared by:

CES Group Engineers, LLP
3525 Whitehall Park Drive, Suite 150
Charlotte, North Carolina 28273
CES Project No. 8076.0123E 2
October 9, 2023

TABLE OF CONTENTS
Page

1.0 SITE INFORMATION ................................................................................................. 5
1.1 Site Identification............................................................................................. 5
1.2 Contact Information ......................................................................................... 5
1.3 Release Information ........................................................................................ 5
1.4 Certification ..................................................................................................... 6
2.0 EXECUTIVE SUMMARY ............................................................................................ 7
3.0 SCOPE OF SERVICES ............................................................................................ 10
4.0 SITE HISTORY AND CHARACTERIZATION ........................................................... 11
4.1 Responsible Party Information ...................................................................... 12
4.2 UST Information ............................................................................................ 12
4.3 AST Information ............................................................................................ 13
4.4 Release Description ...................................................................................... 13
4.5 Site Characteristics ....................................................................................... 13
4.6 Affected Property Owners and Occupants .................................................... 13
4.7 Receptor Information .................................................................................... 14
4.8 Remedial Plan Implementation ..................................................................... 15
4.9 Remediation Progress .................................................................................. 15
5.0 CURRENT SITE ASSESSMENT INFORMATION .................................................... 16
5.1 Water Level and Free Product Thickness Measurements ............................. 16
5.2 Groundwater Monitoring and Sampling Event ............................................... 16
5.3 Surface Water Monitoring Event ................................................................... 16
5.4 Soil Monitoring Event .................................................................................... 16
5.5 Summary of Soil, Groundwater, and Free Product Assessment Information . 17
5.6 Site Geology and Hydrogeology .................................................................... 18
5.7 Evaluation of Soil, Groundwater, and Free Product Thickness Information ... 19
6.0 FREE PRODUCT REMOVAL ................................................................................... 20
6.1 Free Product Current and Historical Status ................................................... 20
6.2 Free Product Effluent Discharge and/or Recovery ........................................ 20
6.3 Free Product Recovery Methods ................................................................... 20
6.4 Free Product Conclusion and Recommendations ......................................... 20
7.0 SOIL REMEDIATION ............................................................................................... 21
7.1 Soil Remediation Activities ............................................................................ 21
7.2 Chronology of Soil Remediation Activities (Corrective Action Plan) ............... 21
7.3 Cost of Soil Remediation Activities ................................................................ 21
8.0 GROUNDWATER REMEDIATION ........................................................................... 22
8.1 Groundwater Remediation Activities ............................................................. 22
8.2 Chronology of Groundwater Remediation Activities (Corrective Action Plan) 22
8.3 Costs of Groundwater Remediation Activities ............................................... 22
CES Project No. 8076.0123E 3
October 9, 2023

9.0 CONCLUSIONS AND RECOMMENDATIONS ......................................................... 23
9.1 Conclusions .................................................................................................. 23
9.2 Recommendations ........................................................................................ 23
10.0 REFRENCES ........................................................................................................... 24

CES Project No. 8076.0123E 4
October 9, 2023

FIGURES
FIGURE 1 SITE LOCATION MAP
FIGURE 2 SITE MAP
FIGURE 3 SOIL CONCENTRATION AND ESTIMATED EXTENT OF
CONTAMINATION MAP
FIGURE 4 GROUNDWATER CONCENTRATION AND ELEVATION AND
ESTIMATED EXTENT OF CONTAMINATION MAP
FIGURE 5 POTENTIAL RECEPTOR AND LAND USE MAP
FIGURE 6 PROPOSED MONITORING WELL LOCATION MAP
TABLES
TABLE B-1 SITE HISTORY – UST/AST SYSTEM AND OTHER RELEASE
INFORMATION
TABLE B-2 SITE HISTORY – UST/AST OWNER/OPERATOR AND OTHER
RESPONSIBLE PARTY INFORMATION
TABLE B-3 SUMMARY OF SOIL ANALYTICAL RESULTS
TABLE B-4 GROUNDWATER ANALYTICAL RESULTS
TABLE B-5 PUBLIC AND PRIVATE WATER SUPPLY WELL AND OTHER
RECEPTOR INFORMATION
TABLE B-6 CONTIGUOUS PROPERTY OWNERS/OCCUPANTS
TABLE B-7 GROUNDWATER MONITORING WELL CONSTRUCTION
INFORMATION
TABLE B-9 CURRENT GROUNDWATER ELEVATIONS
APPENDICES
APPENDIX A SITE PHOTOGRAPHS
APPENDIX B MONITORING FIELD DATA SHEETS, SAMPLING PROTOCOLS, JOB
HAZARD ANALYSIS, AND HEALTH & SAFETY PLAN
APPENDIX C SOIL AND GROUNDWATER LABORATORY REPORTS AND CHAIN-OF-
CUSTODY RECORDS
APPENDIX D SOIL BORING LOGS, MONITORING WELL CONSTRUCTION FORM,
AND NCDEQ AND NCDOT WELL PERMITS
CES Project No. 8076.0123E 5
October 9, 2023

1.0 SITE INFORMATION
1.1 Site Identification
Date of Report: October 9, 2023 Site Risk/Ranking: Low
Facility I.D.:N/A UST Incident Number (if known):
WS-3985 /
13353
Site Name: Bullins Grocery
Street Address:1107 N Main Street
City/Town:Walnut Cove Zip Code: 27052 County: Stokes
Description of Geographical Data Point (e.g., MW):MW-1
Location Method (GPS, topographical map, online map, other):GIS Address Matching
Latitude (decimal
degrees):36.31306 Longitude (decimal
degrees): -80.13904
1.2 Contact Information
UST/AST Owner:
Dennis Bullins – Bullins Grocery
(Deceased) Email: N/A
Address: N/A Tel: N/A
UST/AST Operator:
Dennis Bullins – Bullins Grocery
(Deceased) Email: N/A
Address: N/A Tel: N/A
Property Owner:
Ghamdan Salim (Green Group
Properties, LLC) Email: [e-mail]
Address:
100 E Murphy Street, Madison,
NC 27025 Tel: [phone]
Property Occupant: Vacant Email: N/A
Address:
1107 N Main Street, Walnut Cove,
NC 27052 Tel: N/A
Consultant/Contractor: CES Group Engineers, LLP. Email: [e-mail]
Address:
3525 Whitehall Park Drive,
Ste150, Charlotte, NC 28273 Tel: [phone]
Analytical Laboratory: Waypoint Analytical State Certification No: 402
Address:
449 Springbrook Road, Charlotte,
NC 28217 Tel: [phone]
Drilling Contractor: Carolina Soil Investigations Email: [e-mail]
Address: 132 Gurney Road, Olin, NC 28660 Tel: [phone]
1.3 Release Information
Date Discovered: 6/17/1992 (According to NCDEQ UST Incident Maps)
Estimated Quantity of Release: Unknown
Cause of Release: Unknown
Source of Release (e.g.,
Dispenser/Piping/UST):USTs/Dispenser/Piping
Sizes and Contents of Tanks or Other
Containment from
which the Release Occurred: 
Two 500-gal diesel USTs
One 1,000-gal gasoline UST
One 3,000-gal gasoline UST

CES Project No. 8076.0123E 6
October 9, 2023

1.4 Certification
I, Charles D. Heleine, a North Carolina Licensed Professional Engineer employed by CES,
do certify that the information contained in this report is accurate, to the best of my
knowledge.

E-Signature 10/09/2023

Charles D. Heleine, NC PE No. 27196

CES Group Engineers, LLP (CES) is licensed to practice engineering in North Carolina.
The firm license number is F-1240.

CES Project No. 8076.0123E 7
October 9, 2023

2.0 EXECUTIVE SUMMARY

This Groundwater Monitoring Report summarizes petroleum hydrocarbon impacts in soil and
groundwater from an apparent release of petroleum hydrocarbon-related constituents from retail
petroleum underground storage tank (UST or tank) systems, located at Bullins Grocery, 1107 N
Main Street, Walnut Cove, Stokes County, North Carolina (hereafter identified as the site, subject
site, subject property, or property). The site location, including topographic features, is depicted
on Figure 1. CES Group Engineers, LLP (CES) has been authorized to perform soil and
groundwater sampling activities by the North Carolina Department of Environmental Quality
(NCDEQ), represented by Scott Ryals, PE, Environmental Engineer.

Based on the reported evidence of contamination during a Phase I Limited Site Assessment (LSA)
performed in April, 2023 from soil and groundwater (GCL benzene and 1,2-Dibromethane
exceedances) samples collected from MW-1, located around the former USTs, the dispenser
island, and product piping on the southern portion of the property, three additional soil
borings/groundwater monitoring wells (MW-2, MW-3, and MW-4) were installed on September
14, 2023, under the direction of CES. The three soil borings/groundwater monitoring wells were
installed on the southern perimeter of the property, outside the presumed location of the former
USTs, the dispenser island, product piping, and existing USTs to facilitate the collection of soil
and groundwater samples for laboratory analysis to further assess the site.

During the installation of groundwater monitoring wells MW-2, MW-3, and MW-4 on September
14, 2023, soil samples were collected based on visual, olfactory observations, field screening the
encountered soils with a MiniRAE 2000 Photoionization Detector (PID), and the estimated depth
of groundwater encountered in the field during soil boring/groundwater monitoring well installation.
One soil sample from each soil boring/groundwater monitoring well location was collected above
the depth to groundwater where PID screening was highest, placed in laboratory provided vials
and glassware, stored on ice, and hand delivered under chain-of-custody (COC) procedures on
September 14, 2023 to Waypoint Analytical (Waypoint) of Charlotte, North Carolina (NC
Certification No. 402) for laboratory analysis of volatile organic compounds (VOCs) by 8260 plus
MTBE/IPE, semi-volatile organic compounds (SVOCs) by 8270 BNA, metals Pb and Cr, and VPH
and EPH by Massachusetts Department of Environmental Protection (MADEP) methodologies.

Soil laboratory analytical results from MW-2, MW-3, and MW-4 reported the following petroleum
hydrocarbon-related constituent concentrations above the Soil-to-Water Maximum Soil
Contaminant Concentration (MSCC):

MW-2 and MW-3: chromium.

MW-4: chromium, benzene, n-butylbenzene, sec-butylbenzene, ethylbenzene,
isopropylbenzene, 4-isopropyl toluene, naphthalene, n-propylbenzene,
toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, o-xylene, m,p-
xylene, total xylene, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8
aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

Soil laboratory analytical results from MW-4 reported the following petroleum hydrocarbon-related
constituent concentrations above Residential Soil Cleanups Levels:

MW-4: chromium, naphthalene, and 1,2,4-trimethylbenzene.

CES Project No. 8076.0123E 8
October 9, 2023

Soil laboratory analytical results from MW-2, MW-3, and MW-4 reported the following petroleum
hydrocarbon-related constituent concentrations above Industrial/Commercial MSCC:

MW-2, MW-3, and MW-4: chromium.

All other concentrations of petroleum hydrocarbon-related constituents in soil were reported below
the Soil-to-Water MSCC, Residential Soil Cleanup Levels and Industrial/Commercial MSCC from
MW-2, MW-3, and MW-4.

On September 14, 2023, depth to groundwater (DTW) measurements were recorded from MW-
2, MW-3, and MW-4 using a water level meter capable of detecting light non-aqueous phase liquid
(LNAPL or Free Product) to an accuracy of 0.01 feet. Free product was not detected in any of the
three groundwater monitoring wells. DTW measurements ranged between 22.81-feet below
grade in MW-2 to 26.80-feet below grade in MW-3. Groundwater samples were then collected
from each groundwater monitoring well, placed on ice, and hand delivered under COC procedures
to Waypoint on September 14, 2023, for analysis of VOCs by 6200B plus Oxygenates, VOCs by
504.1 (EDB), Bases/Neutrals and Acids by 625 BNA plus TICs, Metals Pb and Cr, and VPH and
EPH by MADEP methodologies.

Groundwater laboratory analytical results from MW-2, MW-3, and MW4 reported the following
petroleum hydrocarbon-related constituent concentrations above the 2L Standards:

MW-2: chromium, lead, benzene, methyl tert-butyl ether, naphthalene, n-
propylbenzene, tert-butyl alcohol, 1,2,4-trimethylbenzene, o-xylene, m,p-
xylene, total xylene, 1-methylnaphthalene, 1,2-dibromoethane, C5-C8
aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

MW-3: chromium, lead, benzene, di-isopropyl ether, 1,2-dichloroethane,
ethylbenzene, isopropyl benzene, 2-hexanone, methyl ethyl ketone, methyl
tert-butyl ether, naphthalene, n-propylbenzene, 4-methyl 2-pentanone, tert-
butyl alcohol, tert-amyl alcohol, toluene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, o-xylene, m,p-xylene, total xylene, 1-
methylnaphthalene, 2-methylnaphthalene, 1,2-dibromoethane, C5-C8
aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

MW-4: chromium, lead, benzene, di-isopropyl ether, 1,2-dichloroethane, 1,2-
dichloropropane, ethylbenzene, isopropyl benzene, 2-hexanone, methyl
ethyl ketone, methyl tert-butyl ether, naphthalene, n-propylbenzene, 4-
methyl 2-pentanone, tert-butyl alcohol, tert-amyl alcohol, toluene, 1,2,4-
trimethylbenzene, 1,3,5-trimethylbenzene, o-xylene, m,p-xylene, total
xylene, 1-methylnaphthalene, 2-methylnaphthalene, 1,2-dibromoethane,
C5-C8 aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

Groundwater laboratory analytical results from MW-2, MW-3, and MW-4 reported the following
petroleum hydrocarbon-related constituent concentrations above the GCL Standard:

MW-3: benzene and 1,2-dibromoethane.

MW-4: benzene, 1,2-dichloroethane and 1,2-dibromoethane.

CES Project No. 8076.0123E 9
October 9, 2023

All other concentrations of petroleum hydrocarbon-related constituent concentrations were
reported below the 2L and GCL from MW-2, MW-3, and MW-4.

Based upon soil and groundwater samples collected from MW-2, MW-3, and MW-4 on September
14, 2023, reporting petroleum hydrocarbon-related constituent concentrations above applicable
soil and groundwater standards, including groundwater concentrations of benzene, 1,2-
dichloroethane and 1,2-dibromoethane reported above the GCL Standard, it is the opinion of CES
that two additional monitoring wells would be required on the property located across N Main
Street to the east, identified as a Hardee’s Restaurant, to evaluate the extent of the GCL
contaminant plume to the east.

CES Project No. 8076.0123E 10
October 9, 2023

3.0 SCOPE OF SERVICES

The scope of services for this report were authorized by NCDEQ Task Authorization (TA) #02,
approved on April 21, 2023, under CES Contract Number N042023, dated February 24, 2023. In
accordance with the approved TA, the scope of services included the following:

 Install three soil borings/groundwater monitoring wells at the 1107 N Main Street property
(Bullins Grocery) to an approximate depth of 30-feet below grade, with the three soil
borings/groundwater monitoring wells located on the southern portion of the property,
outside the area of the former USTs, the dispenser island, product piping, and existing
USTs.

 Monitor and collect soil samples from the three soil borings/groundwater monitoring wells
for laboratory analysis of VOCs by 8260 plus MTBE/IPE, SVOCs by 8270 BNA, metals Pb
and Cr, and VPH and EPH by MADEP methodologies.

 Monitor and collect groundwater samples from the three soil borings/groundwater
monitoring wells for laboratory analysis by VOCs by 6200B plus Oxygenates, VOCs by
504.1 (EDB), Bases/Neutrals and Acids by 625 BNA plus TICs, Metals Pb and Cr, and
VPH and EPH by MADEP methodologies.

 Prepare and submit one groundwater monitoring report summarizing the field and
laboratory analytical findings.
CES Project No. 8076.0123E 11
October 9, 2023

4.0 SITE HISTORY AND CHARACTERIZATION

The subject site is located at 1107 N Main Street, where the soil and groundwater monitoring and
sampling event was performed on September 14, 2023, and consists of one parcel, identified as
Stokes County Parcel Identification Number (PIN) 6963-44-4932. Figures 1 and 2 depict a Site
Location Map and Site Plan, respectively. The site is in a mixed-use area of Walnut Cove, Stokes
County, North Carolina, with N Main Street to the east and a restaurant (Hardee’s) located across
the roadway, a single-family residence to the north, the intersection of N Main Street and NC
Highway 89E to the south, and NC Highway 89E to the west, with a gasoline service station
(Speedway) located across the roadway, and is generally situated in an area of commercial,
residential, agricultural, and institutional uses. The subject property is currently unoccupied and
vacant, with one structure in disrepair and asphalt-paved areas located on the southern portion
of the site, and with the remainder of the property predominantly covered by vegetative
overgrowth and wooded areas. This soil boring/groundwater monitoring well installation (i.e., MW-
2, MW-3, and MW-4) and soil and groundwater sampling event was performed on the southern
perimeter of the property, outside the presumed location of the former USTs, the dispenser island,
product piping, and existing USTs. Site photographs are included in Appendix A.

In June of 1992, a total of four underground storage tanks (USTs) were removed from the site by
a local backhoe operator, while under the direction of the property and business owner at that
time, Mr. Dennis Bullins. Upon removal of the USTs, a total of eight soil samples were collected
from beneath the four removed USTs by a representative of Walnut Cove Fuel Supply, Inc. Based
on elevated petroleum hydrocarbons, reported as total petroleum hydrocarbons (TPH), from
underneath the gasoline USTs, approximately 100 cubic yards of potentially contaminated soils
were excavated and removed from the area of the former gasoline USTs. Since concentrations
of TPH were not detected from beneath the diesel USTs, no over-excavation of potentially
contaminated soils occurred from the area of the former diesel USTs. Based on the reported
concentration levels of TPH from the area of the former gasoline USTs, NCDEQ subsequently
issued Incident Number 13353 for the apparent release condition to Mr. Bullins in June, 1992.

After receiving a request from NCDEQ to conduct additional soil sampling around the former
USTs and product piping in March of 1995, Law Engineering and Environmental Services (LAW)
of Greensboro, North Carolina installed a total of five soil borings at the site in June, 1995, which
reported elevated concentrations of TPH from soil samples collected from underneath the product
piping (sample BH-1: 4,800 mg/kg) and from the former diesel UST area (sample BH-2: 1,800
mg/kg). During the removal of the four USTs and soil boring investigation, groundwater was not
encountered at the maximum exploration depth of 15 feet below grade. Based on the previously
completed soil remediation activities conducted around the former gasoline USTs (June, 1992)
and reported TPH concentration levels from BH-1 and BH-2 (June, 1995), additional assessment
activities were recommended around the former diesel USTs and product piping by LAW.

Since the completion of the soil boring investigation in June, 1995, CES performed a Phase I LSA
in March, 2023, and subsequent field monitoring and sampling activities on September 14, 2023,
as detailed herein, to further assess the subject site soil and groundwater impacts.

CES Project No. 8076.0123E 12
October 9, 2023

4.1 Responsible Party Information
UST Owner/Operator: Dennis Bullins – Bullins Grocery (Deceased)
Address: N/A
Phone: N/A

Other Person(s) Associated
With USTs: (Site accepted into State-Lead Cleanup Program)
Address: N/A
Phone: N/A

Current Property Owner: Ghamden Salim (Green Group Properties, LLC)
Address: 100 Murphy Street, Madison, North Carolina 27025
Phone: [phone]

On January 12, 2023, the site was accepted into the NCDEQ State-Lead Cleanup Program to
conduct further investigative measures relative to Incident Number 13353.

Additional responsible party information is provided in Table B-1 and Table B-2, and above in
Section 1.2.
4.2 UST Information
A general summary of the UST system is presented below, with further information included in
Tables B-1 and B-2:

UST ID No Current/Last
Contents
Capacity
(gallons)
Date
Installed *
Date
Removed
Discovery
of Release
1 Diesel 500 Unknown 6/11/1992

Yes

2 Diesel 500 Unknown 6/11/1992

Yes

3 Gasoline 1,000 Unknown 6/11/1992

Yes

4 Gasoline 3,000 Unknown 6/11/1992

Yes

5 Gasoline 4,000 7/10/1992 N/A
(Existing UST)

No

6 Gasoline 8,000 7/10/1992 N/A
(Existing UST)

No

* No UST information was available from the NCDEQ UST Database.

CES Project No. 8076.0123E 13
October 9, 2023

4.3 AST Information
Not applicable. No ASTs or other above ground vessels or substantial petroleum storage
containers are known to exist at the site.
4.4 Release Description
As reported in the UST Closure Report, dated October 26, 1996, prepared by LAW, during the
removal of two diesel USTs and two gasoline USTs in June 1992, and during subsequent soil
boring investigations conducted in June 1995, a release of petroleum related constituents to the
subsurface from the historical operation of the UST system(s) was discovered, with NCDEQ
subsequently issuing Incident Number 13353 for the apparent release condition. The UST
Closure Report, prepared by LAW and dated October 26, 1995.
4.5 Site Characteristics
The subject property is zoned Neighborhood Business (NB-2) in the Town of Walnut Cove, and
includes one parcel, with Stokes County PIN 6963-44-4932, occupying an area of approximately
1.36-acres. According to Stokes County GIS, Land Use of the subject property has been identified
as Commercial. The adjoining property to the north of the site is a single-family residence. The
adjoining property to the west of the site is NC Highway 89E with a gasoline service station
(Speedway) located across the roadway. The adjoining property to the south of the site is the
intersection of N Main Street and NC Highway 89E. The adjoining property to the east of the site
is N Main Street, with a restaurant (Hardee’s) located across the roadway.

The subject property is currently unoccupied and vacant, and previously operated as a gasoline
service station and grocery store, identified as Bullins Grocery, which occupied an approximately
1,428-square foot building constructed in the year 1926, with remodeling completed in the year
1966, and is located on the southern portion of the site, near the intersection of N Main Street and
NC Highway 89E.

The subject site is situated at the intersection of N Main Street, a 2-lane, asphalt surfaced, rural
section roadway, and NC Highway 89E, a 2 to 3-lane, asphalt surfaced, rural section roadway.
The subject site is served by commercial utilities, including electrical power, telephone, and
natural gas services. Public water distribution and sanitary sewer services provided by the Town
of Walnut Cove serve the site.
4.6 Affected Property Owners and Occupants
The subject site where the contamination was initially discovered in June 1992, with residual
contamination remaining in-situ as evident by groundwater analytical results reported from MW-
1 during the January 31, 2023 Phase I LSA and from MW-2, MW-3, and MW-4 during the most
recent field monitoring and sampling event on September 14, 2023, has been found to be
generally located throughout the entirety of the southern portion of the property, including outside
the location of the former USTs, the dispenser island, product piping, and existing USTs. The 2L
and GCL groundwater contaminate plume is presumed to extend east-southeasterly beyond MW-
2 and MW-3, and west-southwesterly beyond MW-4 for an unknown extent and beyond the
subject property. Based on petroleum hydrocarbon-related constituent concentrations reported
above applicable groundwater standards (2L and GCL), nearby and surrounding property owners
and occupants may be impacted by the apparent release from Incident Number 13353.

CES Project No. 8076.0123E 14
October 9, 2023

Table B-6 summarizes property owners and occupants.

4.7 Receptor Information
Water Supply Wells:

As part of this LSA, a water supply well survey was conducted by interviewing the owner of the
subject property, conducting a windshield survey, and sending out Request for Water Supply Well
Information forms to property owners located within a 1,500-feet radius of the subject property.
According to information obtained from the subject property owner, nearby and surrounding
property owners, a review of NCDEQ SWAPInfo 2.0 and historical documents, and the Town of
Walnut Cove and Stokes County, at least three water supply wells are known to exist within a
1,500-feet radius of the site.

On March 1, 2023, CES sent out Request for Water Supply Well Information forms to 121
properties within a 1,500-feet radius of the subject property. A total of 15 Water Supply Well
Information forms were returned to CES, or information was otherwise communicated to CES,
which did not report the presence of water supply wells within a 1,500-feet radius of the site,
except for one water supply well that services the residential structure at 5128 NC Highway 89 E,
which is situated approximately 1,300-feet to the west-southwest of the roadway (NC Highway 89
E) and approximately 1,350-feet from the site. Additionally, water supply wells located at 202
Millbrook Drive (irrigation/swimming pool only) and 427 West Wellington Lane (inactive) were
previously identified during a historical review of available online documents associated with
NCDEQ Incidents located in the general area of the site. The properties at 202 Millbrook Drive
and 427 West Wellington Lane are located approximately 575-feet and 1,490-feet to the northwest
of the site, respectively.

Table B-5 summarizes public and private water supply well information.

Public Water Supplies:

According to the NC SWAPInfo 2.0 Map and NC One Map - Public Water Supply Water
Resources Map, no public water supply wells are known to exist within a 1,500-feet radius of the
subject property. A total of seven groundwater wells, identified as the Town of Walnut Cove Wells
#1 through #7, were reported in Walnut Cove and supply the municipal water distribution system.
The closest of these groundwater wells, Well #4-Club Street, is located approximately 2,450 feet
to the southeast of the site.

Municipal water distribution systems provided by the Town of Walnut are available to serve the
subject property and surrounding properties.

Surface Water:

According to the NC One Map – Surface Water Classifications Map, the nearest surface water
body, Mills Creek, is located approximately 4,390 feet to the west of the site. Additionally, two
surface water retention ponds, associated with the Food Lion Grocery Store and agricultural land,
are located approximately 615-feet and 1,875-feet to the east of the site, respectively.

According to the NC One Map – Surface Water Intakes Map, no surface water intakes are located
within a 1,500-feet radius of the subject site.
CES Project No. 8076.0123E 15
October 9, 2023

Wellhead Protection Areas:

According to the NC SWAP website, no wellhead protection areas are in Stokes County.

Deep Aquifers in the Coastal Plain Physiographic Region:

Not applicable to the subject site as the site lies within the Piedmont Physiographic Region.

Subsurface Structures:

Underground utilities have been identified at and adjacent to the subject site, and the potential
exists for soil and groundwater contamination to be in contact with these underground utilities.
Groundwater has historically been measured at approximately 26-feet below ground surface at
the site. Because the underground utilities are expected to be at a shallower depth than 26-feet,
the utility lines would not be considered receptors or conduits for ground water contaminant
migration. No subsurface structures have been identified at the site.

Figure 5 depicts a 1,500-feet Potential Receptor Map.
4.8 Remedial Plan Implementation
To date, it is the understanding of CES that a remedial plan has not been submitted and/or
implemented for the subject site.
4.9 Remediation Progress
Not applicable.

CES Project No. 8076.0123E 16
October 9, 2023

5.0 CURRENT SITE ASSESSMENT INFORMATION

Prior to the commencement of the subject field monitoring and sampling event, CES prepared
and reviewed a site-specific Job Hazards Analysis (JHA) and Emergency Management and
Health & Safety Plan (HASP), acknowledging that potential hazards exist onsite, and were
properly recognized and evaluated by onsite personnel. A copy of the site-specific JHA and HASP
are included in Appendix B.
5.1 Water Level and Free Product Thickness Measurements
During this field monitoring and sampling event, depth to groundwater measurements were
collected from MW-2, MW-3, and MW-4 on September 14, 2023.

Depth to groundwater was measured and recorded utilizing a water level meter capable of
detecting LNAPL or free product to an accuracy of 0.01 feet.

Free product was not detected in any onsite groundwater monitoring wells.

After measuring depth to groundwater at each groundwater monitoring well, the water level meter
was decontaminated by using a soapy water mixture (alconox and water).

DTW ranged between 22.81-feet below top of casing (TOC) in MW-2 to 26.80-feet below TOC in
MW-3, on September 14, 2023. Based on visual observations at the site and surrounding area,
groundwater flow direction is anticipated to flow in an easterly direction. A summary of depth to
groundwater measurements are included in Table B-9 and in Appendix B, respectively.
5.2 Groundwater Monitoring and Sampling Event
After collecting depth to groundwater measurements, and after calculating the volume of water to
be removed from the above referenced groundwater monitoring wells, a dedicated 1.5-inch
disposable bailer was used to develop each well utilizing surging methods, and then
approximately three to five well volumes were purged from each groundwater monitoring well on
September 14, 2023, utilizing dedicated disposable bailers for each well. Groundwater samples
were then collected from each groundwater monitoring well on September 14, 2023, placed on
ice, and hand delivered under COC procedures to Waypoint on September 14, 2023, for analysis
of VOCs by 6200B plus Oxygenates, VOCs by 504.1 (EDB), Bases/Neutrals and Acids by 625
BNA plus TICs, Metals Pb and Cr, and VPH and EPH by MADEP methodologies. A summary of
groundwater analytical results are included on Table B-4. Groundwater laboratory analytical
reports are included as Appendix C.
5.3 Surface Water Monitoring Event
Not applicable. No surface water monitoring events were conducted during this field monitoring
and sampling event.
5.4 Soil Monitoring Event
On September 14, 2023, three permanent groundwater monitoring wells (MW-2, MW-3, MW-4)
were installed at the 1107 N Main Street property, on the southern perimeter of the property,
outside the presumed location of the former USTs, the dispenser island, product piping, and
existing USTs, with soil samples collected for laboratory analysis from all three locations.
CES Project No. 8076.0123E 17
October 9, 2023

During the installation of MW-2, MW-3, and MW-4 on September 14, 2023, soil samples were
collected above the water table, as observed during field drilling operations, at a depth of
approximately 14 to 16-feet below grade (MW-2), 4 to 6-feet below grade (MW-3), and 14 to 16-
feet below grade (MW-4) and placed in laboratory provided vials and glassware, stored on ice,
and hand delivered under COC procedures on September 14, 2023 to Waypoint for laboratory
analysis of VOCs by 8260 plus MTBE/IPE, SVOCs by 8270 BNA, metals Pb and Cr, and VPH
and EPH by MADEP methodologies. A summary of soil analytical results are included on Table
B-3. Soil laboratory analytical reports are included as Appendix C.

Groundwater monitoring well construction information for MW-2, MW-3, and MW-4 are included
on Table B-7. Field notes, classifying encountered soils during the installation of MW-2, MW-3,
and MW-4, and prepared by a CES Geologist, are included in Appendix D. Well construction
records, provided by the driller, Carolina Soil Investigations, Inc, and groundwater monitoring well
construction permits for 1107 N Main Street, Permit Number WM0401479, issued by the NCDEQ
Division of Water Resources, and Permit Number E092-085-23-00439, issued by North Carolina
Department of Transportation are included in Appendix D.
5.5 Summary of Soil, Groundwater, and Free Product Assessment Information
Soil laboratory analytical results from MW-2, MW-3, and MW-4 reported the following petroleum
hydrocarbon-related constituent concentrations above the Soil-to-Water MSCC:

MW-2 and MW-3: chromium.

MW-4: chromium, benzene, n-butylbenzene, sec-butylbenzene, ethylbenzene,
isopropylbenzene, 4-isopropyl toluene, naphthalene, n-propylbenzene,
toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, o-xylene, m,p-
xylene, total xylene, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8
aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

Soil laboratory analytical results from MW-4 reported the following petroleum hydrocarbon-related
constituent concentrations above Residential Soil Cleanups Levels:

MW-4: chromium, naphthalene, and 1,2,4-trimethylbenzene.

Soil laboratory analytical results from MW-2, MW-3, and MW-4 reported the following petroleum
hydrocarbon-related constituent concentrations above Industrial/Commercial MSCC:

MW-2, MW-3, and MW-4: chromium.

All other concentrations of petroleum hydrocarbon-related constituents in soil were reported below
the Soil-to-Water MSCC, Residential Soil Cleanup Levels and Industrial/Commercial MSCC from
MW-2, MW-3, and MW-4.

Groundwater laboratory analytical results from MW-2, MW-3, and MW4 reported the following
petroleum hydrocarbon-related constituent concentrations above the 2L Standards:

MW-2: chromium, lead, benzene, methyl tert-butyl ether, naphthalene, n-
propylbenzene, tert-butyl alcohol, 1,2,4-trimethylbenzene, o-xylene, m,p-
xylene, total xylene, 1-methylnaphthalene, 1,2-dibromoethane, C5-C8
CES Project No. 8076.0123E 18
October 9, 2023

aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

MW-3: chromium, lead, benzene, di-isopropyl ether, 1,2-dichloroethane,
ethylbenzene, isopropyl benzene, 2-hexanone, methyl ethyl ketone, methyl
tert-butyl ether, naphthalene, n-propylbenzene, 4-methyl 2-pentanone, tert-
butyl alcohol, tert-amyl alcohol, toluene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, o-xylene, m,p-xylene, total xylene, 1-
methylnaphthalene, 2-methylnaphthalene, 1,2-dibromoethane, C5-C8
aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

MW-4: chromium, lead, benzene, di-isopropyl ether, 1,2-dichloroethane, 1,2-
dichloropropane, ethylbenzene, isopropyl benzene, 2-hexanone, methyl
ethyl ketone, methyl tert-butyl ether, naphthalene, n-propylbenzene, 4-
methyl 2-pentanone, tert-butyl alcohol, tert-amyl alcohol, toluene, 1,2,4-
trimethylbenzene, 1,3,5-trimethylbenzene, o-xylene, m,p-xylene, total
xylene, 1-methylnaphthalene, 2-methylnaphthalene, 1,2-dibromoethane,
C5-C8 aliphatic, C9-C12 aliphatic, and C9-C10 aromatics.

Groundwater laboratory analytical results from MW-2, MW-3, and MW-4 reported the following
petroleum hydrocarbon-related constituent concentrations above the GCL Standard:

MW-3: benzene and 1,2-dibromoethane.

MW-4: benzene, 1,2-dichloroethane and 1,2-dibromoethane.

All other concentrations of petroleum hydrocarbon-related constituent concentrations were
reported below the 2L and GCL from MW-2, MW-3, and MW-4.

Figure 2 depicts the locations of MW-2, MW-3, and MW-4. The soil concentration and estimated
extent of contamination plan is included as Figure 3. The groundwater concentration and
elevation and estimated extent of contamination plan is included as Figure 4. A summary of soil
and groundwater analytical results are included on Tables B-3 and B-4, respectfully. Soil and
groundwater laboratory analytical reports are included as Appendix C.
5.6 Site Geology and Hydrogeology
According to the Geological Map of North Carolina (1985), the subject site is located within the
Piedmont Physiographic Province, is underlain by sedimentary rocks of the Triassic Basins Belt,
Belt, and is within a stoneville formation. A description of the underlaying Rock Unit TRds is
conglomerate, sandstone, and mudstone, lenticular and laterally-gradational.

According to the US Department of Agriculture, Natural Resources Conservation Service, Web
Soil Survey, soils at the subject property consist of Clover-Land complex (CrB), which generally
have a 2 to 10 percent slope, and are classified as well drained fine sandy loam (0 to 6-inches),
sandy clay loam (6 to 9-inches), clay (9 to 33-inches), sandy clay loam (33 to 40-inches) and
sandy clay loam (40 to 80-inches). Parent materials were classified as Residuum weathered from
mudstone and/or shale and siltstone and/or sandstone. Encountered soils from groundwater
monitoring well MW-2, MW-3, and MW-4 were generally classified as dark brown clay.

According to a review of applicable USGS topographic mapping for the subject property and
onsite observations, it has been determined that natural surface drainage in the vicinity of the
CES Project No. 8076.0123E 19
October 9, 2023

subject site is generally in an east-southeasterly direction. While not always the case,
groundwater flow direction typically follows the direction of surface water flow, and is, therefore,
anticipated to flow east-southeasterly. Man-made improvements may alter natural local drainage
patterns to some degree.

The data obtained and reported herein is representative of conditions only at the referenced
boring and monitoring well location and is not necessarily indicative of conditions elsewhere on
the subject property.
5.7 Evaluation of Soil, Groundwater, and Free Product Thickness Information
Based upon petroleum hydrocarbon-related constituent concentrations reported in soil and
groundwater above applicable state standards, the primary source of contamination is believed
to emanant from the location of the former USTs, the dispenser island, product piping, and existing
USTs, and in an easterly direction towards N Main Street and west-southwesterly direction
towards NC Highway 89 E.

Free product was not detected in any of the onsite groundwater monitoring wells during the field
monitoring and sampling event.

The data obtained and reported herein is representative of conditions only at the referenced
groundwater monitoring well locations and is not necessarily indicative of conditions elsewhere
on the subject site.

CES Project No. 8076.0123E 20
October 9, 2023

6.0 FREE PRODUCT REMOVAL

6.1 Free Product Current and Historical Status
Not applicable. Free product has not been detected from onsite groundwater monitoring wells.
6.2 Free Product Effluent Discharge and/or Recovery
Not applicable. Free product has not been detected from onsite groundwater monitoring wells.
6.3 Free Product Recovery Methods
Not applicable. Free product has not been detected from onsite groundwater monitoring wells.
6.4 Free Product Conclusion and Recommendations
Not applicable. Free product has not been detected from onsite groundwater monitoring wells.

CES Project No. 8076.0123E 21
October 9, 2023

7.0 SOIL REMEDIATION

7.1 Soil Remediation Activities
Not applicable. Soil remediation activities were not performed during this field monitoring and
sampling event.
7.2 Chronology of Soil Remediation Activities (Corrective Action Plan)
Not applicable. Soil remediation activities were not performed during this field monitoring and
sampling event.
7.3 Cost of Soil Remediation Activities
Not applicable. Soil remediation activities were not performed during this field monitoring and
sampling event.

CES Project No. 8076.0123E 22
October 9, 2023

8.0 GROUNDWATER REMEDIATION

8.1 Groundwater Remediation Activities
Not applicable. Groundwater remediation activities were not performed during the field monitoring
and sampling event.
8.2 Chronology of Groundwater Remediation Activities (Corrective Action Plan)
Not applicable. Groundwater remediation activities were not performed during the field monitoring
and sampling event.
8.3 Costs of Groundwater Remediation Activities
Not applicable. Groundwater remediation activities were not performed during the field monitoring
and sampling event.

CES Project No. 8076.0123E 23
October 9, 2023

9.0 CONCLUSIONS AND RECOMMENDATIONS
9.1 Conclusions
The findings of the September 14, 2023, soil and groundwater monitoring and sampling event are
as follows:

 Three groundwater monitoring wells (MW-2, MW-3, and MW-4) were installed to an
approximate depth of 30-feet below grade.

 Soil samples were collected during the installation of MW-2, MW-3, MW-4 and analyzed
for VOCs by 8260 plus MTBE/IPE, SVOCs by 8270 BNA, metals Pb and Cr, and VPH and
EPH by MADEP methodologies.

 Three groundwater monitoring wells (MW-2, MW-3, and MW-4) were monitored and
sampled for VOCs by 6200B plus Oxygenates, VOCs by 504.1 (EDB), Bases/Neutrals
and Acids by 625 BNA plus TICs, Metals Pb and Cr, and VPH and EPH by MADEP
methodologies.

 LNAPL or free product was not detected in MW-2, MW-3, and MW-4.

 DTW measurements ranged between 22.81 feet below TOC in MW-2 to 26.80-feet below
TOC in MW-3.

 Apparent groundwater flow is generally in an easterly direction.

 Petroleum hydrocarbon-related constituent concentrations in soil were reported above the
Soil-to-Water MSCC in MW-2, MW-3, and MW-3, above Residential Soil Cleanup Levels
in MW-4, and above Industrial/Commercial MSCC in MW-2, MW-3, and MW-4.

 Petroleum hydrocarbon-related constituent concentrations in groundwater were reported
above the 2L in MW-2, MW-3, and MW-4, and above the GCL Standard in MW-3 and MW-
4.
9.2 Recommendations
Based upon groundwater concentration levels reported above the GCL Standard from
groundwater monitoring wells MW-3, and MW-4 during the field monitoring and sampling event,
it is the opinion of CES that two additional monitoring wells would be required on the property
located across N Main Street to the east, identified as a Hardee’s Restaurant, to evaluate the
extent of the GCL contaminant plume to the east.

Figure 6 depicts the location of the proposed monitoring wells on the Hardee’s Restaurant
property to the east of the site.

CES Project No. 8076.0123E 24
October 9, 2023

10.0 REFRENCES

CES Group Engineers, LLP of Charlotte, North Carolina. Phase I Limited Site Assessment, dated
April 5, 2023.

Law Engineering and Environmental Services of Greensboro, North Carolina. Report of
Underground Storage Tanks Closure dated October 26, 1995.

FIGURES

^_
Site Location
Figure 1Topographic Site Location MapBullins Grocery1107 N Main StreetWalnut Cove, Stokes County, North CarolinaDrawn on: 2/24/2023
Drawn by: Amy Schmidt

3525 Whitehall Park DriveSuite 150Charlotte, North Carolina 28273T: 704-489-1500www.ces-group.net³
0 2,000 4,000 6,000 8,0001,000
FEET
REFERENCE:USGS The National Map: National Boundaries Dataset, 3DEP Elevation Program, Geographic Names Information System,National Hydrography Dataset, National Land Cover Database, National Structures Dataset, and National TransportationDataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.Department of State Humanitarian Information Unit; and NOAA National Centers for Environmental Information, U.S.Coastal Relief Model. Data refreshed June, 2022.
CES Project No. 8076.0123
Reviewed by: Greg Hans
DRAWN BY: BN
CHECKED BY: GH
PROJECT NUMBER:
8076.0123E
DRAWING TITLE:
SHEET NUMBER:
SEAL:PROJECT DESCRIPTION:Site PlanCES GROUP ENGINEERS, LLP
NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net
DATE: 03/27/2023
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RSite Location
Figure 5Potential Receptor and Land Use MapBullins Grocery1107 N Main StreetWalnut Cove, Stokes County, North CarolinaCES Project No. 8076.0123
Drawn on: 3/22/2023
Drawn by: Amy Schmidt

3525 Whitehall Park DriveSuite 150Charlotte, North Carolina 28273T: 704-489-1500www.ces-group.net³
0 300 600 900 1,200150
FEET
Legend
^_Site Location
1,500' Radius
Parcels
!(Water Supply Wells - None Present
!(Water Supply Wells - Active
!(Water Supply Wells - Active (Irrigation/Swimming Use Only)
!(Water Supply Wells - Inactive
REFERENCE:NC OneMap aerial orthoimagery dated 2022. Parcel data and street dataobtained from NC OneMap and Guilford County
Reviewed by: Greg Hans

TABLES

Table B-1: Site History – UST/AST System and Other Release Information
Revision Date: 02/24/2023 Incident Number and Name: 13353; Bullins Grocery UST ID#: WS-3985
Unknown Unknown 7/10/1992
Existing (Out
of Service)No5 Gasoline Gasoline 4,000 Unknown
5.3' x 18' Unknown Unknown
Permanent
Closure /
Removed
(6/1992)
Yes / Release
discovered
6/1992
4 Gasoline Unknown 3,000 Unknown
5.3' x 12' Unknown Unknown
Permanent
Closure /
Removed
(6/1992)
Yes / Release
discovered
6/1992
3 Gasoline Unknown 1,000 Unknown
4' x 6' Unknown Unknown
Permanent
Closure /
Removed
(6/1992)
Yes / Release
discovered
6/1992
2 Diesel Unknown 500 Unknown
Unknown Unknown 7/10/1992
Existing (Out
of Service)No6 Gasoline Gasoline 8,000 Unknown
UST ID
Number
Diesel 500 Unknown 4' x 6'1 Unknown
Tank Dimensions
(diameter x
length)
Construction
Details
Capacity (in
gallons)
Previous
Contents
Current/Last
Contents
Yes / Release
discovered
6/1992
Description of
Associated
Piping and
Pumps
Was release
associated with
the UST
System?
Status of USTDate Tank
Installed
Unknown Unknown
Permanent
Closure /
Removed
(6/1992)
Page 1 of 2
Table B-1: Site History – UST/AST System and Other Release Information
Revision Date: 02/24/2023 Incident Number and Name: 13353; Bullins Grocery UST ID#: WS-3985
Incident
Number
Material
Released Date of Release
13353 Petroleum 6/17/1992
*Information retrieved from Report of Underground Storage Tank Closure, Law Engineering and Environmental Services, dated October 26, 1995
AST ID
Number
Current/Last
Contents *
Previous
Contents *
Capacity (in
gallons)
Construction
Details **Tank Dimensions Status of AST
***
Description of Release
Soil contamination reported during the removal of USTs in June 1992
Description of
Associated
Piping and
Pumps
Was release
associated with
the AST
System?
Date Tank
Installed
Page 2 of 2
Table B-2: Site History - UST/AST Owner/Operator and
Other Responsible Party Information
Revision Date: 02/24/2023 Incident Number and Name: 13353; Bullins Grocery
UST ID#: WS-3985
2
3
4
5
6
State Zip
N/A N/A
State Zip
N/A N/A
State Zip
Street Address
N/A
City Telephone Number
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
Dennis Bullins - Bullins Grocery (Deceased)Tanks 1 - 4 (Unknown through 6/10/1992) Tanks
5 - 6 (7/10/1992 through Unknown)
N/A N/A
Incident
Number 13353
Name of Other Responsible Party Dates of Release(s)
(mm/dd/yy to mm/dd/yy)
Street Address
City Telephone Number
City Telephone Number
N/A N/A
N/A
Street Address
Dennis Bullins - Bullins Grocery (Deceased)
Tanks 1 - 4 (Unknown through 6/10/1992) Tanks
5 - 6 (7/10/1992 through Unknown)
UST ID
Number
1
Facility ID Number
Name of Owner Dates of Operation
(mm/dd/yy to mm/dd/yy)
N/A
Page 1 of 1
Table B-3: Summary of Soil Analytical ResultsRevision Date: 09/29/2023 Incident No's. 13353; Bullins Grocery UST ID#: WS-3985
6010D 6010D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8270E 8270E 8270E
MADEP-EPH MADEP-EPH MADEP-EPH MADEP-VPH MADEP-VPH MADEP-VPH
Sample ID Date Collected (m/dd/yy)
Source Area (eg. Tank Grave)
Sample Depth(Feet BGS)
PID (ppmv)
MW-2 9/14/23
Around the general location of the form USTs, the dispenser island, and product piping
15 225 30.8 17.1 BDL BDL BDL BDL 0.001 J BDL BDL 0.003 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
MW-3 9/14/23
Around the general location of the form USTs, the dispenser island, and product piping
5 1,369 32.4 19.7 BDL BDL BDL BDL 0.002 J BDL BDL 0.002 J 0.011 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 17.4 J BDL BDL BDL BDL
MW-4 9/14/23
Around the general
location of the form
USTs, the dispenser
island, and product
piping
15 3,208 28.8 51.1 2.7 6.04 3.03 51.2 11.1 7.69 2.18 BDL 22.0 27.1 0.523 J 87.1 186 55.4 89.1 212 301 2.83 6.29 9.69 325 BDL 123 589 685 421
3.8 270 0.0072 2.4 2.2 8 N/A 1.3 0.12 0.023 0.2 1.4 0.9 5.4 6.6 6.6 6 6 6 0.054 1.5 0.2 540 N/A N/A 68 540 31
1.32 400 12 782 1,560 60.3 N/A 1,560 1,560 93.8 5.5 1,560 3,120 1,250 156 156 3,120 3,120 3,120 22.8 62.5 5.5 1,560 31,200 N/A 625 1,500 469
6.54 400 59.4 11,600 23,300 297 N/A 23,300 23,300 1,400 27 23,300 46,700 18,600 2,330 2,330 46,700 46,700 46,700 112 934 27 23,300 467,000 N/A 9,340 40,000 12,264
Feet BGS = feet below ground surface
mg/kg =milligrams per kilogram
ppmv: parts per million per volume as detected by MiniRAE2000 photoionization detector (PID)BDL = Below Laboratory Detection Limit
N/A = Not applicable
Highlighted Yellow / Bold = Values exceeding the Soil-to-Water Soil StandardHighlighted Green / Bold = Values exceeding the Residential Soil Cleanup Standard
Highlighted Red / Bold = Values exceeding Soil-to-Water, Residential and Industrial/Commercial Standards
Concentrations compared to Table - 1, Rev 10/5/2021, Site Checks, Tank Closure, and Initial Response and Abatement (same as current version of Table 1 - Assessment and Corrective Action for UST Releases)C19-C36 Aliphatic4-Isopropyl tolueneStyreneNaphthaleneXylenes (Total)1-Methylnaphthalene2-Methylnaphthalenem,p-Xyleneo-XyleneMethylene ChlorideSoil-to-Water Maximum Contaminant Concentration (mg/kg)
Residential Soil Cleanup Levels (mg/kg)BenzeneIndustrial/Commercial MSCC (mg/kg)n-HexaneChromiumLead C9-C10 AromaticsAnalytical Method (e.g., VOCs by 8260D) 
Contaminant of Concern (mg/kg) C5-C8 Aliphaticn-Butylbenzenesec-ButylbenzeneEthylbenzeneIsopropylbenzeneNaphthalenen-PropylbenzeneC9-C18 AliphaticC11-C22 AromaticC9-C12 AliphaticToluene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene
Table B-4: Summary of Groundwater Analytical ResultsRevision Date: 09/29/2023 Incident Number and Name: Incident No. 13353; Bullins Grocery UST ID#: WS-3985
6010D 6010D 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 625.1 625.1 625.1 625.1 625.1 625.1 625.1 504.1
MADEP EPH MADEP EPH MADEP VPH MADEP VPH MADEP VPH
Sample ID Date Collected (m/dd/yy)
Incident Phase
MW-1 3/16/2023 LSA 12 9 BDL 12,100 18.7 13.70 975 158 8.69 3,480 130 5.72 123 315 71.9 404 385 81.6 56.8 J BDL 481 E 36,500 2,230 698 20,400 BDL BDL BDL 26.6 55.8 272 BDL 305 759 701 83,600 43,700 5,100
MW-2 9/14/2023 GWR 31 19 BDL 11 10.2 7.00 0.851 BDL BDL 393 50.2 3.14 BDL BDL 140 167 86.8 4.36 41.8 7.68 J 0.669 J 72.2 863 98.4 2,850 BDL BDL 39.3 9.55 19.5 76.6 BDL 0.173 BDL 614 740 6,020 1,740
MW-3 9/14/2023 GWR 93 65 892 10,900 BDL BDL 1,080 229 BDL 3,010 85.9 BDL 882 771 304 736 235 452 925 3,320 BDL 41,000 2,040 508 17,900 38 BDL BDL 18.6 37.9 170 1.03 J 108 41.5 J 545 80,500 39,700 5,450
MW-4 9/14/2023 GWR 29 28 1,720 17,900 20.4 J 25.9 J 6,970 2,150 60.8 1,730 89 BDL 372 1,820 354 838 200 223 648 J 12,800 BDL 22,900 1,670 461 9,560 BDL 138 BDL 48.6 72.9 171 BDL 462 59.4 J 871 68,200 10,800 3,490
10 15 6,000 1 70 70 70 0.4 0.6 600 70 25 40 400 20 6 70 100 10 40 128 600 400 400 500 30,000 700 6,000 1 30 6 200 0.02 700 N/A 400 700 200
10,000 15,000 6,000,000 5,000 5,900 8800 70,000 400 600 80,000 30,500 11,700 40,000 4,000,000 20,000 6,000 26,100 100,000 10,000 40,000 128,000 260,000 28,500 24,100 50,000 1,700,000 700,000 N/A 1,000 12,000 6,000 550 50 N/A N/A N/A N/A N/A
µg/l = Micrograms per Liter
GCL = Gross Contamination LevelBDL = Below Laboratory Detection Limit
N/A = Not Applicable
J = Detected but below the Reporting Limit; therefore, result is an estimated concentrationConcentrations in BOLD and Highlighted Yellow reported above 2L Standards (March 16 & September 14, 2023)
Concentrations in BOLD and Highlighted Red reported above GCL Standards (March 16 & September 14, 2023)
Constituents not listed above were reported as BDLsLaboratory analysis performed by Waypoint Analytical, Inc of Charlotte, NC (NC Certification No. 402)tert-Amy Methyl Ether (TAME)2L Standard (ug/L) (Effective 4/1/2022)
GCL (ug/L) (Table 2 - Revised
10/8/2020)Di-Isopropyl Ether (DIPE)EthylbenzeneBenzene1,2-Dichloroethane1,2-DichloropropaneMethyl Ethyl Ketone (MEK)2-Hexanone4-Methyl 2-PentanoneChromiumLeadtert-Amyl Alcohol (TAA)AcetoneC9-C10 AromaticC5-C8 AliphaticC9-C12 AliphaticAnalytical Method (e.g., VOCs by EPA 6200B) 
Contaminant of Concern (mg/kg) n-ButylbenzeneXylene (Total)Isopropyl benzene4-Isoproply tolueneMethyl tert-butyl ether (MTBE)1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneNaphthalenen-Propyl benzenetert-Butyl Alcohol (TBA)sec-Butyl benzeneToluene2-MethylnaphthaleneNaphthaleneC11-C22 AromaticC9-C18 Aliphatic1,2-Dibromoethane1-MethylnaphthaleneDiethyl phthalateBenzoic AcidPhenanthreneBenzyl Alcohol
Table B-5: Public and Private Water Supply Well and Other Receptor Information
Revision Date: 09/29/2023 Incident Number and Name: No. 13353; Bullins Grocery UST ID#: WS-3985
Water Supply Well and Other Receptor Information
1 WSW Joel Brown Both 336-745-7406
5128 NC Highway
89 E, Walnut Cove,
NC 27052
Serves
Residential
Structure
36.31155 -
80.14336 A / P ~ 1,350 feet Up
2* WSW Dawn Frye Both N/A
202 Millbrook
Drive, Walnut
Cove, NC 27052
Irrigation &
Swimming Pool
36.31430 -
80.14024 A / NP ~ 575 feet Up
3* WSW James Branch, Sr. Both N/A
427 West
Wellington Lane,
Walnut Cove, NC
27053
Previously
Served
Residential
Structure
36.31459
-80.14385 IA / P ~1,490 feet Up
Additional Information for Water Supply Wells (and Other Receptors, if applicable)
Well # / ID
(same as
above)
Public Water:
Connected /
Available / Not
Available
Well Currently Used
for:
Active /
Inactive /
Abandoned
Construction
Method and
Well Type
Total Depth (ft
BGS)
Screened
Interval (x to y
ft BGS)
ft BGS = Feet below ground surface
* Information retrieved from ATC Group Services, LLC of North Carolina, Limited Site Assessment Report, dated December 20, 2019
Distance from
Source (ft)
Street Address for
Receptor
* Ex: WSW = Water Supply Well, SWB = Surface Water Body, Resvr = Reservoir, PWS = Public Water Supply, PW = Public Well, SW = Supply Well, WPA = Wellhead Protection Areas, RA = Recharge Areas (for
deep aquifers), Sub = Subsurface Structures, Con = Conduits, Other:
** The location and/or latitude/longitude (IN DECIMAL DEGREES) must be sufficiently accurate and precise to allow easy location of wells (or recovery if buried/paved/covered-over, lost, or otherwise damaged) and
for the location / replication of sampling points for any other receptor. Coordinates are estimated based on physical location of onsite structure(s)
*** Status: A = Active or IA = Inactive *and* Use: P = Potable or NP = Non-Potable Use. (Describe further in Additional Information for Water Supply Wells table below.)
Up or
Downgradient
(if known)
Well # Contact Name
Source
Status & Use
***
Type *Owner/User/
Both Contact Phone #
Receptor
Description
and Location
Details **
Latitude/
Longitude **
(decimal degrees)
Private / Public / Semi-Public Casing Depth (ft BGS)
No other receptors are known to exist within close proximity to the site.
Page 1 of 1
Table B-6: Contiguous Property Owners/Occupant
Revision Date: 03/17/2023 Incident No: 13353; Name: Bullins Grocery UST ID#: WS-3985
Tax Parcel
Number / Map
ID
Owner / Occupant
Name
Address
(Physical)
Address
(Mailing)
6963-44-4932
(subject property)
Green Group Properties,
LLC
1107 N Main Street, Walnut Cove,
NC 27052
2041 Pembroke Forest Drive, Winston-
Salem, NC 27106
6963-45-4187
(adjoining property
to the north)
W.C. Jr & Louise Nelson 5109 NC 89 Highway E, Walnut
Cove, NC 27052
5109 NC 89 Highway E, Walnut Cove,
NC 27052
6963-44-1745
(property across
NC 89 Highway E
to the west)
Susan Mann 5142 NC 89 Highway E, Walnut
Cove, NC 27052
2403 Reynolds Road, Winston Salem,
NC 27104
6963-44-5760
(property across N
Main Street to the
east)
Walnut Property, LLC 1070 N Main Street, Walnut Cove,
NC 27052
6700 Tower Circle, Suite 1000,
Franklin, TN 37067
Table B-7: Monitoring and Remediation Well Construction Information
Revision Date: 9/27/2023 Incident Number and Name: 13353; Bullins Grocery UST ID#: WS-3985
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Diameter
(in.)
Well
Casing
Depth
(ft. bgs)
Screened
Interval
(x to y ft. bgs)
Depth of
Well
(ft. bgs)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing (ft.)
Free
Product
Thickness*
* (ft.)
Initial
Groundwater
Elevation* (ft.)
Latitude/
Longitude
(decimal
degrees)***
MW-2 9/14/2023 9/14/2023 2 15 15 to 30 30 N/A 22.81 0.0 22.81 36.312833
-80.139133
MW-3 9/14/2023 9/14/2023 2 15 15 to 30 30 N/A 26.80 0.0 26.80
36.312833
-80.139133
MW-4 9/14/2023 9/14/2023 2 15 15 to 30 30 N/A 24.68 0.0 24.68
36.312833
-80.139133
bgs = below ground surface
ft. = feet
in. = inch
N/A = not applicable
* Reference Point for Elevation Measurements (Mean Sea Level)
** If free product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581]
*** The location must be sufficiently accurate and precise to allow easy recovery of lost or damaged wells.
Page 1 of 1
Table B-9: Groundwater Elevations and Free Product Thickness
Revision Date: 09/27/2023 Incident No. 13353; Incident Name: Bullins Grocery UST ID#: WS-3985
Well ID #Top of Casing
Elevation (MSL)
Screened Interval
(top of screen to
bottom of screen, ft.
bgs)
Date Depth to Water*
Uncorrected (ft. bgs)
Free Product
Thickness (ft.)
Depth to Water*
Corrected
for Free Product
Thickness (ft. bgs)
Groundwater Surface
Elevation (MSL)
MW-2 N/A 15 to 30 9/14/2023 22.81 0.0 N/A N/A
MW-3 N/A 15 to 30 9/14/2023 26.80 0.0 N/A N/A
MW-4 N/A 15 to 30 9/14/2023 24.68 0.0 N/A N/A
bgs = below ground surface
ft. = feet
MSL = mean sea level
N/A = not applicable
APPENDIX A
SITE PHOTOGRAPHS

View of driller and Geoprobe rig drilling monitoring well MW-2

View of drillers and Geoprobe rig drilling monitoring well MW-3

View of drillers and Geoprobe rig drilling monitoring well MW-4

View of monitoring well MW-2

View of monitoring well MW-3

View of monitoring well MW-4
APPENDIX B
MONITORING FIELD DATA SHEETS,
SAMPLING PROTOCOLS, JOB HAZARD
ANALYSIS, AND HEALTH & SAFETY
PLAN
Appendix C: Groundwater Monitoring Field Data
Completion Date: 9/29/2023 Incident Number and Name: 13353; Bullins Grocery UST ID No. WS-3985
Well ID
Sampling
Date
(m/dd/yy)
Well
Casing
Diameter
(in.)
Screened
Interval (x to y
ft. BGS)
Depth of
Well (ft. BGS)
Top of
Casing
Elevation
* (ft.)
Depth to
Water from
Top of
Casing (ft.)
Free Product
Thickness (ft.)
Groundwater
Elevation* (ft.)
Sample
Analysis
Number of
Sample
Containers
Proposed
Purged
Volume
(gal)
Actual
Purged
Volume
(gal)
Purge Comments MNA Parameters
MW-2 9/14/2023 2 15 to 30 30 N/A 22.81 ND N/A
6200B +
Oxygenates,
504.1 (EDB),
625 BNA +
TICs, VPH,
EPH, and
Metals (Pb
and Cr)
15 4-gal 4-gal
Purged appr. 4-gallons prior to
sampling. Bailer on bottom.
Purged bailings observed to be
clear to murky brown. Odor
present, no sheen present on
bailings.
Not Collected
MW-3 9/14/2023 2 15 to 30 30 N/A 26.80 ND N/A
6200B +
Oxygenates,
504.1 (EDB),
625 BNA +
TICs, VPH,
EPH, and
Metals (Pb
and Cr)
15 2-gal 2-gal
Purged appr. 2-gallons prior to
sampling. Bailer on bottom.
Purged bailings observed to be
clear to murky brown. Odor
present, no sheen present on
bailings.
Not Collected
MS-4 9/14/2023 2 15 to 30 30 N/A 24.68 ND N/A
6200B +
Oxygenates,
504.1 (EDB),
625 BNA +
TICs, VPH,
EPH, and
Metals (Pb
and Cr)
15 3-gal 3-gal
Purged appr. 3-gallons prior to
sampling. Bailer on bottom.
Purged bailings observed to be
clear to murky brown. Odor
present, no sheen present on
bailings.
Not Collected
Bullins Grocery, NCDEQ Incident No.: 13353, UST ID No.: WS-3985
*: Top-of-Casing elevations not obtained under current task order / work order
1

ENVIRONMENTAL MANAGEMENT AND HEALTH AND SAFETY
PLAN

NCDEQ Project WS-3985_13353
Bullins Grocery
1107 N Main Street
Walnut Cove, Stokes County, NC

CES PROJECT NUMBER: 8076.0123E

Prepared by:

CES GROUP ENGINEERS, LLP
3525 Whitehall Park Drive, Suite 150
Charlotte, NC 28273

February 3, 2023

i

TABLE OF CONTENTS

Page
1.0 INTRODUCTION 1
1.1 PURPOSE/OBJECTIVE 2
1.2 RESPONSIBILITIES FOR HEALTH AND SAFETY 3
1.3 SUBCONTRACTOR’S RESPONSIBILITY 3

2.0 ASSIGNMENT OF RESPONSIBILITY 4
2.1 SITE SAFETY OFFICER 4
2.2 PROJECT MANAGER(S) 5

3.0 BACKGROUND AND HAZARD EVALUATION 7
3.1 PROJECT DESCRIPTION 7
3.2 HAZARD EVALUATION 7
3.3 SAFETY DATA SHEETS (SDS) 8

4.0 AIR MONITORING 9
4.1 MONITORING EQUIPMENT 9
4.2 TYPES AND FREQUENCY OF MONITORING 10
4.2.1 Breathing Zone Monitoring 10
4.2.2 Explosive Gas Source Monitoring 10
4.2.3 Work Area Monitoring 10
4.2.4 Dust Monitoring 10
4.3 ACTION LEVELS 11

5.0 PERSONAL PROTECTIVE EQUIPMENT AND PROCEDURES 11
5.1 RESPIRATORY PROTECTION 11
5.2 PROTECTIVE CLOTHING 12
5.3 LEVELS OF PROTECTION 13
5.3.1 Modified Level D 13
5.3.2 Level D Protection 13
5.3.3 Level C Protection 14
5.3.4 Level B Protection 14

6.0 SITE CONTROL 15
6.1 REGULATED AREAS 15
6.2 ACCESS/SITE SECURITY 16
6.3 POSTING/BARRICADES 16

ii

Page
7.0 POLICIES 16
7.1 GENERAL WORK PRACTICES 16
7.2 HEAVY EQUIPMENT OPERATION 17
7.3 SANITATION 19

8.0 DECONTAMINATION 19
8.1 PERSONAL DECONTAMINATION 20
8.2 EQUIPMENT DECONTAMINATION 21

9.0 TRAINING 22
9.1 BASIC TRAINING 22
9.2 SITE-SPECIFIC TRAINING 22

10.0 HEALTH MONITORING 23
10.1 PHYSICAL EXAMINATION 23
10.2 HEAT STRESS 23
10.3 COLD STRESS 24
10.4 SELF MONITORING 26

11.0 SITE STANDARD OPERATING PROCEDURES 26
11.1 WORK PRACTICES 26
11.2 COMMUNICATION PROCEDURES 27

12.0 EMERGENCY PROCEDURES 28
12.1 GENERAL 28
12.2 RESPONSIBILITIES 29
12.3 EMERGENCY CONTACT LIST 30
12.4 PERSONNEL INJURY IN THE EXCLUSION ZONE 32
12.5 PERSONNEL INJURY IN THE SUPPORT ZONE 32
12.6 FIRE OR EXPLOSION 32
12.7 PERSONAL PROTECTIVE EQUIPMENT FAILURE 32
12.8 POLLUTANT DISCHARGES/SPILLS 32

APPENDIX A Safety Data Sheet (Benzene - Volatile Organic Compounds)

APPENDIX B Emergency Phone Numbers / Contact List

APPENDIX C Route to Hospital

1

ENVIRONMENTAL MANAGEMENT AND HEALTH AND SAFETY PLAN (EMP)

NCDEQ Project WS-3985_13353
Bullins Grocery
1107 N Main Street
Walnut Cove, Stokes County, NC

1.0 INTRODUCTION

This Environmental Management and Health and Safety Plan (EMP), additionally referred to
as the ‘plan”, has been developed for CES Group Engineers, LLP (CES), for application to
work completed at NCDEQ WS-3985_13353, Bullins Grocery, 1107 N Main Street, Walnut
Cove, Stokes County, North Carolina, under CES Project Number: 8076.0123E. For the
purpose of this plan, the term “project” references “NCDEQ WS-3985_13353”. Additionally,
this plan should also be utilized for any work completed at surrounding properties where
contamination, or additional assessment activities, may be located. For the purpose of this
plan, the term “subsurface investigation” will include, but is not limited to, geophysical
investigations, drilling soil borings with conversion to temporary or permanent monitoring
wells, excavation and removal of encountered underground storage tanks (USTs), and
contaminated soils / groundwater, and additional assessment and remediation activities,
which may include hand-augering of soil borings, installation of monitoring wells and/or
remedial recovery wells, groundwater monitoring and sampling, and injections, and the
abandonment of monitoring wells. The term “subsurface investigation” may also be referred
to as “excavation” in this plan. The plan addresses health and safety procedures and
information relevant to environmental services being provided by CES personnel, and/or
subcontracted personnel. The health and safety portion of the plan provides procedures to
minimize: (1) the potential for accidents from physical hazards, and (2) the potential for
exposure to chemical contaminants during activities which disturb the subsurface materials
in the event that contamination of soil or groundwater by special wastes is encountered. The
Project Manager, assisted by the assigned Site Safety officer, will ensure that all on-site
subcontractor personnel, and site visitors, comply with the specified health and safety
requirements. At least one copy of this EMP will be maintained at the local office of CES, as
well as one copy will be maintained onsite by CES, and/or subcontracted personnel.

2

As part of CES’ safety program, a site-specific Job Hazard Analysis (JHA) form will be used,
in conjunction with this plan, which will also include the name, address, and telephone
number of the nearest hospital in relation to the project address where work is being
completed. CES personnel have been instructed to utilize 911 as the first call should an
accident, or issue, be apparent that warrants an immediate emergency response action. This
plan is intended for general use during subsurface investigation activities completed by CES
personnel, or CES subconsultants/subcontractors, and as a general reference for workers to
review and understand the potential environmental and health and safety conditions that may
be present under normal subsurface investigation conditions. Additionally, this plan should
also be utilized for any work completed at surrounding properties where subsurface
investigation activities are, or may be required.

Prior to initiating subsurface investigation activities, as those referenced above, CES
personnel (Project Manager(s), Site Safety Officer, and/or Field Crews) will complete Job
Hazard Analysis (JHA) and selected CES safety forms which detail job specifics, including
the sequence of basic job steps, potential incidents or hazards, and recommended
procedures to eliminate potential incidents or hazards.

1.1 PURPOSE / OBJECTIVE
The protection of workers and environmental safety and health are major concerns during
this project and cannot be understated. The objective of the EMP is to document procedures
and precautions to be implemented during any geophysical investigations and installation of
soil borings with conversion to permanent monitoring wells, and site assessments, including
soil and groundwater monitoring and/or remediation activities, in order to provide for and
promote safe working conditions at the site during field activities, specifically at locations
where contamination of soil and groundwater has been documented and/or is expected to be
encountered. The safety organization and procedures have been established based on a
previous analysis of potential hazards at the site. Personal protection measures have been
selected in response to these potential hazards.

This EMP and HASP has also been developed based upon review of the requirements
described in the U.S. Environmental Protection Agency (USEPA) Standard Operating Safety
Guide and the U.S. Department of Labor OSHA standards 29 CFR Part 1910. Reasonable
precautions will be taken by the contractor’s representative and its subcontractors to provide
for and promote the safety and health of workers and the general public. Subcontractors will

3

be given copies and will be required to follow this EMP.

1.2 RESPONSIBILITIES FOR HEALTH AND SAFETY
All site activities which have the potential to expose personnel to site contamination or a
related injury are subject to this EMP. Personnel will be responsible for adherence to the
safety procedures during the performance of the work. In no case may work be performed
in a manner that conflicts with the intent of, or the inherent safety and environmental cautions
expressed in, these procedures. Following due warning(s), personnel who violate safety
procedures will be dismissed from the site, and may be terminated. In the event that
contamination is encountered during regular construction operations, personnel will be
exclusively employed in the affected area of the project site, who have been properly trained
in health and safety regulations associated with handling hazardous materials or special
wastes as specified in the training section (Section 9.0) of this EMP.

The requirements provided herein may be modified as the work progresses to accommodate
changing conditions, but a reduction or increase in the health and safety requirements will
not be made without prior approval by the assigned Site Safety Officer (SSO). The prevention
of adverse health effects and injuries to site workers is totally dependent on the contribution
of all project participants. Open communication among workers, supervisors, and
management concerning safety at the site is an essential element of this EMP.

1.3 SUBCONTRACTOR’S RESPONSIBILITY
The Subcontractor is solely responsible for the health, safety, and protection of their own on-
site personnel during the performance of the survey services work scope. The Subcontractor
will perform the work specified in the contract documents in accordance with the HEALTH
AND SAFETY REQUIREMENTS specified herein, and federal, OSHA, state, and local health
and safety regulations. It will be the responsibility of the Subcontractor to be familiar with the
required health and safety regulations in the performance of this work. The Subcontractor
will designate a Site Safety officer to implement and monitor activities related to this EMP.

Should any unforeseen or site-specific safety-related factor, hazard, or condition become
evident during the performance of the work, the Subcontractor will take immediate and
prudent action to establish and maintain safe working conditions and to safeguard site
personnel, the public, and the environment.

4

2.0 ASSIGNMENT OF RESPONSIBILITY
All site activities which have the potential to expose CES personnel to site contamination or
related injury are subject to this EMP. As previously discussed, all site personnel are
responsible for adherence to the safety procedures during performance of the work. Specific
oversight responsibilities are assigned to various personnel as discussed in the paragraphs
to follow.

2.1 SITE SAFETY OFFICER
The SSO will be assigned to monitor the daily activities to assure that all health and safety
procedures/policies are being followed by CES personnel. This includes communicating the
specific requirements to all personnel, including subcontractors, implementing the EMP,
conducting site inspections to monitor compliance with EMP as required, providing or
coordinating training as required, coordinating the medical monitoring program, coordinating
respirator fit tests as required, coordinating the acquisition, calibration and maintenance of
air monitoring equipment, respirators and other safety equipment, directing on-site health and
safety activities, and reporting safety related incidents or accidents to the Project Manager.

The SSO for CES is: Greg Hans, PMP
CES Group Engineers, LLP
3525 Whitehall Park Drive, Suite 150
Charlotte, NC 28273
704.325.5408 (direct)
617.828.9948 (mobile)

It should be noted that the SSO may and will delegate responsibilities to a representative of
CES, subconsultants and/or subcontractors working at the Site and offsite properties for any
and all tasks associated with additional subsurface investigation activities.

2.2 PROJECT MANAGER(S)
The project manager is ultimately responsible for ensuring that all project participants abide
by the requirements set forth in this plan. Any and all changes in the scope of health and
safety requirements or site characterization will be communicated from the Project Manager
and/or Environmental Scientist/Engineer to the SSO.

5

Environmental Project Manager: Greg Hans, PMP
CES Group Engineers, LLP
3525 Whitehall Park Drive, Suite 150
Charlotte, NC 28273
704.325.5408 (direct)
617.828.9948 (mobile)

Environmental Engineer: Chuck Heleine, PE
CES Group Engineers, LLP
3525 Whitehall Park Drive, Suite 150
Charlotte, NC 28273
704.308.7916 (mobile)

3.0 BACKGROUND AND HAZARD EVALUATION

3.1 PROJECT DESCRIPTION
This project involves monitoring of potentially contaminated groundwater with petroleum
related constituents, and may also include geophysical investigations or utility clearance, and
the installation of soil borings with conversion to permanent monitoring wells via mechanical
drilling techniques, and potential future assessment, monitoring and remediation of soil and
groundwater contaminants potentially encountered by said or existing borings. Future
activities at the site may include, but are not limited to excavation and removal of encountered
underground storage tanks (USTs), and contaminated soils / groundwater, and additional
assessment and remediation activities, which may include hand-augering of soil borings,
installation of permanent monitoring wells and/or remedial recovery wells, groundwater
monitoring, and injections, and abandonment of monitoring wells. During the completion of
the aforementioned activities, heavy equipment and machinery, such as drilling rigs,
excavators, back-hoes, dump trucks, etc may be utilized and present onsite.

3.2 HAZARD EVALUATION
Constant attention will be given to physical hazards encountered during work day activities,
particularly those activities associated near heavy equipment such as drilling, subsurface
excavations, and/or earthmoving equipment. An evaluation of the potential hazards
associated with site activities has been completed by reviewing the general construction

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scope of work for each of the projects, to be performed by others. The following potential
exposure pathways have been identified:

· Dermal contact, inhalation and ingestion of contaminated soils and
groundwater
· Inhalation and ingestion of contaminated vapors and particles
· Ingestion of waste solids (accidental/poor hygiene)
· Dermal contact with waste solids

Given that subsurface investigation activities may occur in close proximity to ongoing or future
construction (ie, excavations) related activities that may disturb surficial and subsurface soils,
pipes, etc and the physical properties of the contaminants that may be present at these
locations, there is a potential respiratory hazard from contaminants such as petroleum related
compounds, and therefore a contact hazard from petroleum related compounds. A
respiratory hazard from dust and contaminated dust particles may also exist during nearby
drilling, excavation and removal activities.

It is recognized that site hazard evaluation is a dynamic and on-going process that changes
on a daily basis during progression of the work. However, significant deviation from the
prescribed site characterization will necessitate re-evaluation and possible EMP revision.
Communication from the SSO will initiate the re-evaluation process by the Project Manager.

3.3 SAFETY DATA SHEETS (SDS)
Consistent with 29 CFS 1910.1200, (Hazard Communication Standard) applicable Safety
Data Sheets (or equivalent) will be kept on-site, in each vehicle, and with the Project
Manager. All subcontractors must ensure that their employees are informed of their rights
and responsibilities under the OSHA Hazard Communication Standard. Subcontractors will
provide SDS sheets for items which they bring on the site, as applicable. Due to the presence
of petroleum related constituents, a SDS for Benzene (prepared by Marathon Petroleum
Company, dated 5/14/2015), as VOC concentrations may be encountered onsite, has been
included as Appendix A. It should be noted that the attached SDS is representative of
potential chemicals and materials that may be encountered in the field during subsurface
investigation activities. Should these, or any other chemicals or hazardous materials, actually
be encountered by CES employees while in the field, the hazards and exposures of these
chemicals or hazardous materials will be re-evaluated.

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4.0 AIR MONITORING
The purpose of air monitoring during subsurface investigation activities is to identify and
quantify airborne contaminants to determine the level of protection needed. Should air
monitoring for airborne contaminants be necessary, air monitoring with direct reading
instruments will be conducted during all intrusive activities. Four categories of air monitoring
will be conducted as follows:
· Breathing Zone Monitoring
· Explosive Gas Source Monitoring
· Work Area Monitoring
· Dust Monitoring

Equipment to be used in conducting air monitoring activities, along with a description of the
type and frequency of monitoring and associated action levels are discussed in the
paragraphs to follow. It should be noted that the contractors working in active construction
zones, including but not limited to excavations, trenches, bore holes, etc should be
responsible for proper air monitoring of these areas. However, should CES feel the need to
perform additional air monitoring, the following procedures (as outlined in sections 4.0
through 6.0, and to an extent, sections 7.0 through 11.0) may be implemented.

4.1 MONITORING EQUIPMENT
If CES employees are working in, or near, active construction zones where the potential
exists for chemical hazards and exposures to be present, the breathing zones will be
monitored using a MiniRAE portable VOC monitor. These instruments use a photoionization
detector that is designed to measure trace quantities of VOCs with a parts-per-million (ppm)
sensitivity range. It does not detect methane. The survey instrument will be calibrated using
an appropriate standard according to manufacturer’s instructions. The VOC monitor will be
calibrated prior to each use if the instrument is used infrequently, or daily when in constant
use.

If the MiniRAE portable VOC monitor detects elevated levels of VOC concentrations (> 50
ppmv), in ambient air at the site, a Gastech 02 /explosion/H2S meter will be used to measure
oxygen concentrations, explosion potential, and hydrogen sulfide (H2S) concentration. The
instrument will be calibrated with methane and H2S according to the manufacturer’s
instructions.

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Air monitoring equipment will be certified intrinsically safe and operated by personnel trained
in the use of the specific equipment provided.

4.2 TYPES AND FREQUENCY OF MONITORING
4.2.1 Breathing Zone Monitoring
The breathing zone of a representative employee suspected of greatest exposure for each
job category engaged in work with potentially hazardous substances will be monitored as
follows:

· For excavation operations, monitor the breathing zone of the
equipment operator and laborers with an OVM when the waste
material is initially exposed. The results of the monitoring, the
employee’s name, and the work activity will be recorded in the
daily log

4.2.2 Explosive Gas Source Monitoring
During all operations identified as having a fire/explosion hazard, a combustible gas meter
set to measure the lower explosive level (LEL) will be used to continuously monitor the top of
the trench or excavation.

4.2.3 Work Area Monitoring
Each work area associated with hazardous waste spills and/or contamination will be
monitored at least one time each day with an OVM to determine the concentration of
contaminants being released into the general area.

4.2.4 Dust Monitoring
Chemical exposure via inhalation will be mitigated through the evaluation of wind velocity,
and common sense. Personal protective equipment will be utilized as necessary (based on
specific action levels) to prevent chemical exposure in excess of the exposure limits.

When possible, personnel should be situated upwind of work activity when working at the
site. Excavated areas should be allowed to vent for one to two minutes prior to investigative
activities to allow any vapors, dusts, or gases to dissipate. Liquids and solids should never
be smelled to confirm the presence or absence of chemicals.

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The SSO or CES representative will screen the site for dusty conditions to prevent inhalation
of chemicals in particulate form (e.g. residue on soil grains). If dusty conditions are observed,
all workers will wear appropriate respiratory protection designed for dusts. Extremely dusty
conditions may require dust suppression via water mist or spray prior to returning to work.

4.3 ACTION LEVELS
The action levels as prescribed by the National Institute for Occupational Safety and Health
(NIOSH) will be used to initiate protective actions including, but not limited to, use of personal
protective devices, shut down of specific work activities, and site evacuation. A current
volume of the NIOSH Pocket Guide (electronic version) to Chemical hazards will, or may be
utilized as an on-site referenced by the SSO.

5.0 PERSONAL PROTECTIVE EQUIPMENT AND PROCEDURES

5.1 RESPIRATORY PROTECTION
During excavation or construction activities in an area where special wastes are expected or
have been encountered, the use of respiratory protection equipment may be required.
Respiratory protection is of primary importance as inhalation is one of the major routes of
exposure to chemical toxicants. Respiratory protective devices include air purifying
respirators, air-line respirators, and self-contained breathing apparatus.

The following respiratory protection practices will be observed by all workers at the Site when
conditions warrant respiratory protection:

· The respiratory protection utilized on-site will be in accordance
with OSHA, 29 CFR 1910.134

· Only properly cleaned, maintained, NIOSH/MSHA-approved,
respirators will be used on-site (if required)

· Selection of respirators, as well as any decisions regarding
upgrading or downgrading of respiratory protection, will be
made by the SSO

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· Air-purifying cartridges will be replaced on a regular basis (at
least once per day) as determined by the SSO

· No employee will be assigned to tasks requiring the use of
respirators if, based upon the most recent examination, a
physician determines that the employee will be unable to
function normally wearing a respirator or that the safety or
health of the employee or other employees will be
compromised by use of a respirator

· Persons required to wear full-face respirators must not have
beards or moustaches that interfere with proper respirator seal.
All personnel wearing full-face respirators or personnel working
in the exclusion zone will be required to be clean-shaven prior
to each day’s shift. This will be strictly enforced by the SSO

· All personnel required to use APRs must be properly fit tested
prior to engaging in field activities in accordance with OSHA
standards (29 CFR 1910.1025)

5.2 PROTECTIVE CLOTHING
To protect workers against dermal contact with contaminants, the following apparel must be
worn during site-specific work activities depending on the level of protection specified for
those activities (Section 5.3 of this EMP):

· Disposable Tyvek coveralls
· PVC-coated or equivalent coveralls for splash protection
· Nitrile gloves or equivalent
· Inner gloves - latex or vinyl
· Outer disposable boots
· Hard hat
· Chemical-resistant boots (Neoprene, PVC, or equivalent)
· Hearing protection (as applicable)
· Steel-toed safety shoes

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· Goggles or safety glasses will be worn at all times in the work area
· Sleeves taped to gloves and cuffs taped to boots
· Face shield attachments for use with hard hats
· Disposable, chemical-resistant outer boots

Upgrading or downgrading selected protective equipment will be the decision of the SSO
based on assessment of exposure potential during specific tasks.

5.3 LEVELS OF PROTECTION
The levels of protection to be utilized at the site, and the activities to which they apply, are
described in the following paragraphs. The SSO will select the appropriate level of PPE
based on air monitoring results.

5.3.1 Modified Level D
This is the minimum level of protective clothing to be worn at the site during subsurface
investigation activities. All workers, supervisors, and visitors will be required to don the
following clothing prior to entering the project site. Based on the anticipated activities to be
performed at the site, it is anticipated that Modified Level D will provide adequate protection
coverage.

· Work clothes
· Hard hat
· Safety shoes
· Visibility vest
· Work gloves (only as necessary)

5.3.2 Level D Protection
Level D protection includes chemical resistant gloves and will be used for site work whenever
contact with contaminated equipment or materials is possible. The following clothing will be
required for Level D:

· Disposable, chemical-resistant outer boots
· Coveralls (work uniform)
· Hard hat
· Eye protection (safety glasses, goggles, or face-shield)*
· Safety shoes
· Nitrile gloves*

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* Optional, as determined by SSO

Dust masks shall be used to reduce employee exposure to fugitive dust, an optional Level D
device. The absence of dusty conditions at the site will be justification for the SSO to permit
personnel to remove their masks.

5.3.3 Level C Protection
Level C will be used for site work when the inhalation and dermal contact hazard is elevated.
When conditions for Level C protection are appropriate, the following equipment will be
required:
· Tyvek coveralls/chemical-resistant protective coverall
· Gloves (inner latex gloves and outer nitrile gloves)
· Hard hat
· Safety shoes
· Full-face or half-face air purifying respirator with organic vapor
cartridge (or other proper type cartridge for the intended use,
as determined by the SSO)
· Chemical-resistant outer boots
· Tape gloves and boots to coveralls to prevent leakage
· Hearing protection (as determined by SSO)

5.3.4 Level B Protection
Level B will be used for site work when inhalation and dermal contact hazard are elevated to
the point that a positive pressure, supplied air source is needed.

· Saranex coveralls/chemical-resistant clothing
· Gloves (inner latex gloves and outer nitrile gloves)
· Hard hat
· Self-contained breathing apparatus (SCBA), or Supplied Air-
Line Respirator (SAR)
· Chemical-resistant safety boots
· Gloves and boots taped to prevent leakage

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6.0 SITE CONTROL

The purpose of site control is to minimize potential contamination of workers and to protect
the surrounding area from hazards found at the site. If the project site is not secured by
fencing or other suitable site control means and is not routinely patrolled by police or other
independent security personnel; certain procedures must be followed to ensure suitable site
control and limitation of access so that those persons who may be unaware of site conditions
are not exposed to hazards.

All excavations left open and unattended by site personnel will be appropriately barricaded
and visibly posted with “No Trespassing” or other appropriate signage. All heavy machinery
and equipment shall be locked or chained each evening upon completion of daily activities.
All potentially contaminated media, such as soil, will be covered with plastic prior to leaving
the site.

6.1 REGULATED AREAS
As appropriate to the task conducted, the site vicinity will be divided into three zones to allow
control of worker exposures. These zones are described as follows:

· Exclusion Zone. This zone includes the actual area of
contamination and localized work area where specific
investigative and/or construction equipment is operating. This
zone has the highest inhalation exposure potential, and/or
presents a high probability of skin contact with cutaneous
percutaneous - affecting chemicals. New exclusion zones
may exist during certain site-specific activities. This will be
defined by the SSO and access by individuals not necessary
to operation will be limited. (Level D is minimum).

· Contamination Reduction Zone. This zone includes the areas
immediately surrounding the Exclusion Zone. All personnel
and equipment leaving the Exclusion Zone shall be
decontaminated in this zone.

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Support Zone. This zone covers all areas outside of the
Contamination Reduction Zone. Administrative activities are
conducted in the Support zone, as well as equipment supply
and first aid supply. It is essential that contamination be kept
out of this zone.

6.2 ACCESS/SITE SECURITY
Access to contaminated work areas (Exclusion and Contamination Reduction Zones) will be
regulated and limited to authorized persons. Such persons include the Contractor’s
employees, designated equipment operators, and designated union representatives, as
applicable. The SSO will enforce access limitations during work hours.

6.3 POSTING/BARRICADES
Warning signs will be posted and hung, as applicable, in readily visible locations in or near
contaminated work areas. Barricades or barricade tape will be utilized to prevent access to
various work areas as indicated above.

7.0 POLICIES

7.1 GENERAL WORK PRACTICES
General work practices to be employed on-site are as follows:

· At least one copy of this EMP will be available at the work site

· No food or beverages will be present or consumed in the
exclusion or contamination reduction zones. No tobacco
products will be present or used, and cosmetics will not be
applied in the exclusion or contamination reduction zones

· No matches or lighters are permitted in the exclusion or
contamination reduction zones

· During operations within an area of contamination, all
employees will be required to wash their hands and face before
eating, drinking, smoking, or applying cosmetics

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· Field personnel must observe each other for signs of exposure.
Indications of adverse effects include, but are not limited to, the
following:
- Changes in complexion and skin
discoloration
- Changes in coordination
- Changes in demeanor
- Excessive salivation and
pupillary response
- Changes in speech pattern

Field personnel will be cautioned to inform the SSO of non-
visible effects of exposure such as the following:

- Headaches
- Dizziness
- Nausea
- Blurred vision
- Cramps
- Irritation of eyes, skin, or respiratory tract
·
7.2 HEAVY EQUIPMENT OPERATION
Extra attention should be paid to the following information regarding work around heavy
equipment (cranes, excavators, front end/backhoe loaders, drilling rigs, etc.).

· Use common sense

· Follow OSHA requirements found in 29 CFR 1910 and 29 CFR
1926

· Wear hard hats, hearing protection, and safety glasses at all
times (when not prohibited by the use of air purifying
respirators). Wear other protective gear as specified in the
Health and Safety Plan

16

· A closed cab or cage will be required for equipment used at the
site

· Pay attention at all times

· Maintain visual contact at all times

· Establish hand signal communication when verbal
communication is difficult. Select one person per work group
to be the one to give hand signals to equipment operators

· Be aware of footing at all times

· Be sure that all heavy equipment has a backup alarm

· Be sure that only qualified people operate heavy equipment

· Use chains, hoists, straps, and other equipment to safely move
heavy materials

· Use proper personal lifting techniques. (Use your legs, not your
back)

· Never walk directly in back of, or to the side of, heavy
equipment without the operator’s knowledge

· Never use a piece of equipment unless you are familiar with its
operation. This applies to heavy as well as light equipment (for
example, chain saws)

· Make sure all precautions have been taken before moving pipe
sections and other materials to be utilized during this project as
they are extremely heavy. Let the equipment, not your body,
do the moving

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· Be sure that no underground or overhead power lines, sewer
lines, gas lines, or telephone lines will present a hazard in the
work area

7.3 SANITATION
Onsite sanitation facilities (e.g., wash stations, etc.) may be provided for use by field
personnel assigned to the work if work activities involve the direct handling of contaminated
soils and groundwater.

8.0 DECONTAMINATION

The process of removing or neutralizing contaminants that have accumulated on personnel
and equipment is critical to personnel protection. Decontamination protects workers from
hazardous substances that may contaminate and eventually permeate the protective
clothing, respiratory equipment, tools, vehicles, and other equipment used on site.
Decontamination protects site personnel in the following ways: minimizing the transfer of
harmful materials into clean areas; preventing the mixing of incompatible chemicals; and
protecting the community by preventing uncontrolled transportation of contaminants from the
site.

General – Each time an employee enters the Contamination Reduction Zone from the
Exclusion Zone, he/she just make a thorough self-examination. Equipment must be removed
without exposure to the wearer. Hands and face must be scrubbed before eating or use of
tobacco or cosmetic products to avoid accidental ingestion of wastes. Footwear must be
changed prior to leaving the Contamination Reduction Zone to avoid “tracking” of
contaminants outside the area.

Clothing – The Contractor will provide all required protective clothing. Protective clothes will
be left in the change facility. No clothing (including boots) is to be worn or carried away from
the site. Soiled clothing is to be disposed of as appropriate.

Respirators – All required respirators will be provided and maintained by the Contractor and
will be cleaned daily. Cleaning and maintenance will be performed in accordance with the
appropriate OSHA standard (29 CFR 1910.134).

18

Packaging of Waste Items – All disposable clothing and other contaminated material will be
placed in containers for storage on-site. Personnel will make a conscious effort to minimize
the volume of contaminated materials. Legible and understandable precautionary labels will
be affixed prominently to containers of contaminated scrap, waste, debris, and clothing.
Containers will be disposed with other solids in an EPA-approved manner.

8.1 PERSONAL DECONTAMINATION
Minimum measures to be undertaken for decontamination are outlined below. These
measures are to be followed, as applicable, unless the SSO specifies that a higher level of
decontamination is warranted, and accordingly, sets forth upgraded decontamination
procedures.
MINIMUM MEASURES FOR DECONTAMINATION
STATION PROCEDURES
1. Equipment Drop 1. Deposit equipment used on site (tools, sampling
devices and containers, monitoring instruments, radios,
clipboards, etc.) on plastic drop cloths or in different
containers with plastic liners. During hot weather
operations, a cool down station may be set up within this
area.
2. Outer Garment, Boots and
Gloves Wash and Rinse
2. Scrub outer boots, outer gloves and fully encapsulating
suit with decon solution or detergent and water. Rinse off
using copious amounts of water.
3. Outer Boot and Glove
Removal
3. Remove outer boots and gloves. Deposit in container
with plastic liner.
4. Tank Change 4. If worker leaves Exclusion Zone to change air tanks,
this is the last step in the decontamination procedure.
Worker’s air tank is exchanged, new outer gloves and boot
covers donned, joints taped, and worker returns to duty.
5. Boot, Gloves and Outer
Garment Removal
5. Boots, fully-encapsulated suit, inner gloves removed
and deposited in separate containers lined with plastic.
6. SCBA Removal 6. SCBA backpack and facepiece is removed (avoid
touching face with fingers). SCBA deposited on plastic
sheets.
7. Field Wash 7. Hands and face are thoroughly washed. Shower as
soon as possible.

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EQUIPMENT NEEDED TO PERFORM MINIMUM DECONTAMINATION MEASURES

STATION EQUIPMENT
1 A. Various Size Containers
B. Plastic Liners
C. Plastic Drop Cloths
2 A. Container (20-30 Gallons)
B. Decon. Solution or Detergent Water
C. Rinse Water
D. 2-3 Long-Handled, Soft Bristled Scrub
Brushes
3 A. Container (20-30 Gallons)
B. Plastic Liners
C. Bench or Stools
4 A. Air Tanks or Masks and Cartridges,
depending Upon Level.
B. Tape
C. Boot Covers
D. Gloves
5 A. Containers (20-30 Gallons)
B. Plastic Liners
C. Bench or Stools
6 A. Plastic Sheets
B. Basin or Bucket
C. Soap and Towels
D. Bench or Stools

8.2 EQUIPMENT DECONTAMINATION
Any items taken into the Exclusion Zone will be assumed to be contaminated. In general,
vehicles, equipment, and materials brought into the Exclusion Zone will remain in the
Exclusion Zone until no longer necessary to the project.

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All contaminated vehicles and equipment will be decontaminated before they are taken off-
site. The Contractor will provide and maintain the following facilities for equipment
decontamination:
- equipment decontamination pad
- contaminated water collection system
- high-pressure water or steam cleaners
- trisodium phosphate detergent
- wire brushes and scrapers

9.0 TRAINING
9.1 BASIC TRAINING
All employees who will perform work at the site must have completed environmental and
safety training as approved and/or provided by CES, the Owner, the Contractor, or if required,
by 3rd party General Contractor.

9.2 SITE-SPECIFIC TRAINING
Employees assigned to the site may, as needed, be given site-specific training and field
experience to include the following topics:
- Acute and chronic effects of the toxic chemicals found at the site
- Routes of potential exposure and field activities which could result in such
exposure
- Need for personal protection, types of protection, fit effectiveness and
limitations
- Medical surveillance program
- Work zones established at the site
- Prohibited activities in the Exclusion and Contamination Reduction Zones
- Engineering controls and safe work practices associated with each
employee’s work assignment, including dust control measures
- Personal and equipment decontamination procedures
- Emergency response procedures
- Basic operational safety, emphasizing hazards expected on-site
- Drum handling procedures
- Spill control
- Sampling procedures
- Site communication procedures

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-
10.0 HEALTH MONITORING

10.1 PHYSICAL EXAMINATION
The Contractor may require all of its field workers to pass a pre-employment medical
examination prior to working at the site. The examination shall include a complete medical
and occupational history, and an evaluation from the attending physician as to whether the
employee is qualified to work in areas where exposure to chemicals or physical stress is
possible, and is physically able to use protective equipment, including respirators.

10.2 HEAT STRESS
Subsurface investigation tasks, assignments, projects etc will, or may be conducted during
all four season, winter, spring, summer and fall. Accordingly, warm temperatures during
these time periods may put extra physical stress on the body. Long periods of exposure to
heat may cause illness, particularly if the employee is not accustomed to working in hot areas.
Also, heat builds up inside protective clothing, so there is a risk of heat stress even if outside
temperatures are moderate.

The signs, symptoms and treatment of heat stress are outlined below. All individuals
participating in work in the Exclusion Zone and Contamination Reduction Zones should be
monitored regularly for heat stress symptoms.

Heat Cramps

Symptoms: painful muscle spasms

Cause: profuse sweating and drinking large amounts of water

Treatment: provide liquids with electrolytes (sodium, potassium) like diluted
Gatorade

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Heat Exhaustion

Symptoms: weakness, fatigue, dizziness; pale, cool, moist skin; heavy sweating;
Headache; nausea; and fainting

Cause: reduced blood volume resulting from dehydration from profuse
sweating and insufficient replacement of water and salts

Treatment: If worker is conscious, rest in cool place; replace water and electrolytes
lost in sweat; if unconscious, get medical help immediately. DO NOT
give liquids if person is unconscious
Heat Stroke

Symptoms: very dry, hot skin with red mottled or bluish appearance; confusion;
Convulsions; unconsciousness; rapidly rising temperature

Cause: body becomes overheated because the worker does not sweat.
Can be fatal.

Treatment: call for medical help immediately; move person to cool place;
remove PPE; use wet towels or water and fan to cool while waiting
for help.

10.4 COLD STRESS
Subsurface investigation tasks, assignments, projects etc will, or may be conducted during
all four season, winter, spring, summer and fall. Accordingly, cold temperatures during these
time periods may put extra physical stress on the body. Long periods of exposure to cold
may cause illness, particularly if the employee is not accustomed to working in cold areas.
Cold stress occurs by driving down the body’s skin temperature and eventually the body
temperature (core temperature).

The signs, symptoms and treatment of cold stress are outlined below. All individuals
participating in work in the Exclusion Zone and Contamination Reduction Zones should be
monitored regularly for cold stress symptoms.

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Hypothermia:

Symptoms: shivering, reduced circulation, slow/weak pulse, slowed breathing, lack
of coordination, irritability, confusion, sleepy behavior
Cause: body heat is lost faster than it can be replaced and normal body
temperature drops below 95 degrees F

Treatment: move person to warm and dry area, remove wet clothes and replace
with dry clothes, layer with blankets, give warm sweetened liquids, if
unconscious, get medical help immediately. DO NOT give liquids if
person is unconscious

Frostbite

Symptoms: reddened skin, with development of gray/white patches, numbness,
firm or hard parts affected, blisters
Cause: freezing of skin and underlying tissues typically affecting extremities,
particularly the feet and hands

Treatment: move person to warm and dry area, remove wet clothes and replace
with dry clothes, layer with blankets, give warm sweetened liquids, if
unconscious, get medical help immediately. DO NOT give liquids if
person is unconscious. DO NOT rub affected area, DO NOT break
blisters, DO NOT try to directly warm the frostbite areas without
medical attention

Trench Foot

Symptoms: redness of skin, swelling, numbness, blisters

Cause: prolonged exposure to wet and cold temperatures, constantly wet and
cold feet, wet and cold feet lose heat 25x faster than dry feet

Treatment: call for medical help immediately; remove the shoes, boots, wet
socks, dry the feet

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10.5 SELF MONITORING
While at the site, CES employees and sub-contractors will be required to monitor their own
health and that of their co-workers. Visual observations include:

- behavioral changes
- change in appetite
- coordination losses
- gum and lip discoloration
- increased salivation
- pupil dilation
- sensation losses
- skin rashes
- slurred speech

Any abnormalities or changes are to be reported to the physician and investigated
immediately. Such aspects could be symptoms of toxic exposure and must not be allowed to
persist without medical attention. In addition, all accidents and injuries, no matter how small,
are to be reported to the SSO and investigated.

11.0 SITE STANDARD OPERATING PROCEDURES

11.1 WORK PRACTICES
The need to exercise caution in the performance of specific work tasks is made more acute
due to weather conditions, restricted mobility, and reduced peripheral vision caused by the
protective gear itself, the need to maintain the integrity of the protective gear, and the
increased difficulty in communicating caused by respirators. Work at the site will be
conducted according to established procedures and guidelines for the safety and health of
all involved. Among the most important of these principles for working at the site are:

- In any unknown situation, always assume the worst conditions and plan
accordingly

- Establish and maintain communication

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- Minimize contact with excavated or contaminated materials. Plan work
work areas, decontamination areas, and procedures to accomplish this.
Do not place equipment on drums or on the ground. Do not sit or stand
on drums or other materials

- Employ disposable items when possible to minimize risks during
decontamination and possible cross-contamination during
sampling/handling.
This will require a common-sense approach to potential risks and costs

- Smoking, eating, or drinking after entering the work zone and before
decontamination will not be allowed. Oral ingestion of contaminants from
your hands are a likely means of introduction of the toxic substances into the
body

- Avoid heat and other work stresses relating to wearing the protective gear.
Work breaks and proper tracking are planned to prevent stress-related
accidents or fatigue

- Maintain monitoring systems. Conditions can change quickly if sub-surface
areas of contamination are penetrated

- Be observant of not only your own immediate surroundings but also that of
others. It is a team effort to notice and warn of impending dangerous
situations. Extra precautions are necessary when working near heavy
equipment while utilizing personal protective gear, as vision, hearing, and
communication may be restricted by the protective gear

- Be aware that chemical contaminants may aggravate or worsen symptoms
of other illnesses or intoxication. Avoid use of alcohol and working when ill

11.2 COMMUNICATION PROCEDURES
Personnel in the Exclusion Zone shall remain within sight of other project personnel, and
should work in conjunction with another individual. Since it is not anticipated that the project
area will encompass a large area at any given time, radio communication will not be required.

26

The following standard hand signals will be used in the event that communication is required
amongst workers in and/or between the Exclusion Zone and Contamination Reduction Zone.

Hand gripping throat Out of air, cannot breathe

Grip partner’s wrist, or both Leave area immediately
Hands around partner’s waist

Rotating hands above the head Need assistance

Right hand thumb up OK, I’m all right, I understand

Right hand thumb down No, negative

12.0 EMERGENCY PROCEDURES

12.1 GENERAL
A comprehensive emergency response plan has been developed to handle all on-site
emergencies. A list of site conditions which might require implementation of the plan includes
but is not limited to:

- Fire or explosion on-site
- Serious employee injury
- Accumulation of combustible gases or vapors at concentrations greater than
background
- Oxygen concentration below 19.5%
- Unsafe working conditions, such as inclement weather or hazardous material
releases
- Major release of toxic materials for which appropriate PPE is not being worn
by workers

27

12.2 RESPONSIBILITIES
The emergency coordinator is the SSO (Greg Hans) or assigned CES representative working
onsite; the alternate or back-up is the Environmental Engineer (Chuck Heleine). The
emergency coordinator is responsible for:

- Assessing the situation and determining whether an emergency exists which
requires activating the plan
- Directing all efforts in the area, including evacuating personnel and minimizing
property loss
- Ensuring that outside emergency services such as fire departments, police,
ambulance, and hospitals are notified when necessary
- Directing the shut-down of site operations when necessary
- Notifying regulatory agencies as necessary

28

12.3 EMERGENCY CONTACT LIST

Emergency Contact Phone Number
Environmental PM: Greg Hans, PMP 617.828.9948 (M)
CES Group Engineers, LLP 704.325.5408 (D)

Other SSO (if assigned by
by Env PM) Carolina Soil Investigations (Drillers) 704.539.5279
(assigned CSI field crew chief)

Back-up PM Chuck Heleine 704.308.7916 (M)
CES Group Engineers, LLP

Police: North Carolina Highway Patrol 911
Stokes County Sheriff 336.593.8787

Hospital: Novant Health Forsyth Medical Center 336.718.5000
3333 Silas Creek Parkway
Winston-Salem, NC 27103

Fire: Walnut Cove Volunteer Fire Department 336.591.4477

Doctor: Novant Health Forsyth Medical Center 336.718.5000

Ambulance 911

NCDENR (Winston-Salem Region) 336.776.9800

Directions to the nearest hospital: Novant Health Forsyth Medical Center, 3333 Silas
Creek Parkway, Winston-Salem, NC 27103

Refer to Appendix C.

29

12.4 PERSONNEL INJURY IN THE EXCLUSION ZONE
When there is an injury in the Exclusion Zone, a continuous horn blast will be sounded as an
emergency signal (as applicable). Upon the sounding of the emergency signal, all site
personnel shall assemble in the personnel decontamination area. Rescue personnel will
enter the Exclusion Zone (if required) to remove the injured person. The SSO, or CES
representative, will evaluate the nature of the injury and call for an ambulance (if needed),
and the affected person will be decontaminated to the extent possible prior to movement to
the Support Zone. The appropriate first aid will be administered. No persons shall re-enter
the Exclusion Zone until the cause of the injury or symptom is determined.

12.5 PERSONAL INJURY IN THE SUPPORT ZONE
Upon notification of an injury in the Support Zone, the SSO, or CES representative, will
assess the nature of the injury. If the injury or absence of the injured person does not affect
the performance of site personnel, operations may continue while appropriate first aid and
follow-up is initiated. If the injury increases the risk to others, the designated emergency
signal (continuous horn blast) shall be sounded, and all site personnel shall move to the
decontamination line for further instructions. Activities on-site will stop until the added risk is
removed or minimized.

12.6 FIRE OR EXPLOSION
Upon notification of a fire or explosion on-site, a continuous horn blast will be sounded, and
all site personnel will assemble at the decontamination area. The fire department must be
alerted and all personnel moved as soon as possible to a safe distance.

12.7 PERSONAL PROTECTIVE EQUIPMENT FAILURE
If any site worker experiences a failure or alteration of protective equipment which may alter
the protection factor, that person and his/her work partner must immediately leave the
Exclusion Zone. Re-entry shall not be permitted until the equipment has been appropriately
repaired or replaced.

12.8 POLLUTANT DISCHARGES/SPILLS
In the event of an unauthorized discharge of pollutants or contaminants into the soil, sewers, or
ambient air, the person first finding such an incident should immediately notify the Project
Manager and/or the SSO. The Project Manager and/or SSO will immediately notify Greg Hans
or Chuck Heleine and the Local Fire / Emergency Management agency (Forsyth County
Emergency Management at 336.703.2750).
APPENDIX A
SAFETY DATA SHEETS
(BENZENE)

SAFETY DATA SHEET
SDS ID NO.:0156MAR019
Revision Date 05/14/2015
1. IDENTIFICATION
Product Name:Marathon Petroleum Benzene
Synonym:Benzene; Cyclohexatriene
Product Code:0156MAR019
Chemical Family:Petroleum Hydrocarbon
Recommended Use:Solvent. Chemical intermediate.
Restrictions on Use:All others.
SDS information:1-419-421-3070
Emergency Telephone:[phone]
2. HAZARD IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Germ cell mutagenicity Category 1B
Carcinogenicity Category 1A
Specific target organ toxicity (repeated exposure)Category 1
Aspiration toxicity Category 1
Acute aquatic toxicity Category 2
Hazards Not Otherwise Classified (HNOC)
Static accumulating flammable liquid
Label elements
EMERGENCY OVERVIEW
Manufacturer, Importer, or Responsible Party Name and Address:
MARATHON PETROLEUM COMPANY LP
539 South Main Street
Findlay, OH 45840
Flammable liquids Category 2
Danger
HIGHLY FLAMMABLE LIQUID AND VAPOR
May accumulate electrostatic charge and ignite or explode
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 1 of 10
May be fatal if swallowed and enters airways
Causes skin irritation
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools.
Take precautionary measures against static discharge
Do not breathe dust/fume/gas/mist/vapors/spray
Do not eat, drink or smoke when using this product
Wash hands and any possibly exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid release to the environment
Precautionary Statements - Response
IF exposed or concerned: Get medical attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation occurs: Get medical attention
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use water spray, fog or regular foam for extinction
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container at an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS
Benzene is a six carbon aromatic petroleum hydrocarbon.
Composition Information:
Name CAS Number % Concentration
Benzene 71-43-2 99-100
All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
Causes serious eye irritation
May cause genetic defects
May cause cancer
Causes damage to organs (blood, blood-forming organs, immune system) through prolonged or repeated exposure
Toxic to aquatic life
Appearance Clear Liquid Physical State Liquid Odor Sweet , Distinct
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 2 of 10
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
4. FIRST AID MEASURES
First Aid Measures
General Advice:In case of accident or if you feel unwell, seek medical advice immediately (show directions
for use or safety data sheet if possible).
Inhalation:Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult,
ensure airway is clear, give oxygen and continue to monitor. If heart has stopped,
immediately begin cardiopulmonary resuscitation (CPR). Keep affected person warm and at
rest. GET IMMEDIATE MEDICAL ATTENTION.
Skin Contact:Immediately wash exposed skin with plenty of soap and water while removing contaminated
clothing and shoes. May be absorbed through the skin in harmful amounts. Get medical
attention if irritation persists.
Place contaminated clothing in closed container until cleaned or discarded. If clothing is to
be laundered, inform the person performing the operation of contaminant's hazardous
properties. Destroy contaminated, non-chemical resistant footwear.
Eye Contact:Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be
held away from the eyeball to ensure thorough rinsing. Gently remove contacts while
flushing. Get medical attention if irritation persists.
Ingestion:Do not induce vomiting because of danger of aspirating liquid into lungs, causing serious
damage and chemical pneumonitis. If spontaneous vomiting occurs, keep head below hips,
or if patient is lying down, turn body and head to side to prevent aspiration and monitor for
breathing difficulty. Never give anything by mouth to an unconscious person. Keep affected
person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.
Most important signs and symptoms, both short-term and delayed with overexposure
Adverse Effects:Overexposure to vapors may cause eye, skin and respiratory irritation. Headache,
drowsiness, dizziness, loss of coordination, disorientation and fatigue. Prolonged and
repeated contact may cause defatting and drying of the skin and may lead to irritation
and/or dermatitis. Prolonged or repeated exposure may cause adverse effects on blood,
blood-forming organs, and immune system.
Indication of any immediate medical attention and special treatment needed
Notes To Physician:INHALATION: This material (or a component) sensitizes the myocardium to the effects of
sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate
cardiac arrhythmias in individuals exposed to this material. Administration of
sympathomimetic drugs should be avoided.
INGESTION: This material represents a significant aspiration and chemical pneumonitis
hazard. Induction of emesis is not recommended.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam (AFFF/ATC) or water spray can be used. For
large fires, water spray, fog or foam (AFFF/ATC) can be used. Firefighting should be attempted only by those who are adequately
trained and equipped with proper protective equipment.
Unsuitable extinguishing media
Do not use straight water streams to avoid spreading fire.
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 3 of 10
Specific hazards arising from the chemical
This product has been determined to be a highly flammable liquid per the OSHA Hazard Communication Standard and should be
handled accordingly. Vapors may travel along the ground or be moved by ventilation and ignited by many sources such as pilot
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
lights, sparks, electric motors, static discharge, or other ignition sources at locations distant from material handling. Flashback can
occur along vapor trail. For additional fire related information, see NFPA 30 or the Emergency Response Guidebook 130.
Hazardous combustion products
Smoke, carbon monoxide, and other products of incomplete combustion.
Explosion data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.
Special protective equipment and precautions for firefighters
Firefighters should wear full protective clothing and positive-pressure self-contained breathing apparatus (SCBA) with a full
face-piece, as appropriate. Avoid using straight water streams. Water may be ineffective in extinguishing low flash point fires, but
can be used to cool exposed surfaces. Avoid excessive water spray application. Water spray and foam (AFFF/ATC) must be
applied carefully to avoid frothing and from as far a distance as possible. Keep run-off water out of sewers and water sources.
Additional firefighting tactics
FIRES INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or
monitor nozzles. Cool containers with flooding quantities of water until well after the fire is out. Do not direct water at source of leak
or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of
tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles: if this is
impossible, withdraw from area and let fire burn.
EVACUATION: Consider initial downwind evacuation for at least 1000 feet. If tank, rail car or tank truck is involved in a fire,
ISOLATE for 5280 feet (1 mile) in all directions; also, consider initial evacuation of 5280 feet (1 mile) in all directions.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all
ignition sources.
Protective equipment:Use personal protection measures as recommended in Section 8.
Emergency procedures:Advise authorities and National Response Center (800-424-8802) if the product has
entered a water course or sewer. Notify local health and pollution control agencies, if
appropriate.
Environmental precautions:Avoid release to the environment. Avoid subsoil penetration.
Methods and materials for
containment:
Contain liquid with sand or soil.
Methods and materials for cleaning
up:
Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual
liquids. Recover and return free product to proper containers. When recovering free liquids
ensure all equipment is grounded and bonded. Use only non-sparking tools.
7. HANDLING AND STORAGE
Safe Handling Precautions:NEVER SIPHON THIS PRODUCT BY MOUTH. Static accumulating flammable liquid. Use
appropriate grounding and bonding practices. Bonding and grounding may be insufficient to
eliminate the hazard from static electricity. Do not expose to heat, open flames, strong
oxidizers or other sources of ignition. Use only non-sparking tools. Do not cut, drill, grind or
weld on empty containers since explosive residues may remain. Avoid contact with skin,
eyes and clothing. Avoid breathing vapors or mists. Use only with adequate ventilation.
Use personal protection measures as recommended in Section 8. Exercise good personal
hygiene including removal of soiled clothing and prompt washing with soap and water.
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements.
NFPA Health 2 Flammability 3 Instability 0 Special Hazard -
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 4 of 10
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
Hydrocarbons are basically non-conductors of electricity and can become electrostatically
charged during mixing, filtering, pumping at high flow rates or loading and transfer
operations. If this charge reaches a sufficiently high level, sparks can form that may ignite
the vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists
from process equipment operating under elevated temperature and pressure, or sudden
ingress of air into vacuum equipment may result in ignition of vapors or mists without the
presence of obvious ignition sources. Nozzle spouts must be kept in contact with the
containers or tank during the entire filling operation.
Storage Conditions:Store in properly closed containers that are appropriately labeled and in a cool,
well-ventilated area.
Incompatible Materials Strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Name ACGIH TLV OSHA PELS:OSHA - Vacated PELs NIOSH IDLH
Benzene
71-43-2
0.5 ppm TWA
2.5 ppm STEL
Skin - potential significant
contribution to overallexposure by the cutaneous
route
TWA: 10 ppm (applies to
industry segments exempt
from the benzene
standard)TWA: 1 ppm
STEL: 5 ppm
(see 29 CFR 1910.1028)
25 ppm Ceiling
1 ppm TWA
5 ppm STEL
500 ppm
Notes:The manufacturer has voluntarily elected to provide exposure limits contained in OSHA's
1989 air contaminants standard in its SDSs, even though certain of those exposure limits
were vacated in 1992.
Engineering measures:Local or general exhaust required in an enclosed area or when there is inadequate
ventilation. Use mechanical ventilation equipment that is explosion-proof.
Personal protective equipment
Eye protection:Use goggles or face-shield if the potential for splashing exists.
Skin and body protection:For non-exposure jobs or where exposure is expected to be less than 15 minutes, neoprene
gloves can be used to prevent skin contact. For all exposure jobs expected to be greater
than 15 minutes, Viton® gloves should be used to prevent skin contact. Glove suitability is
based on workplace conditions and usage. Contact the glove manufacturer for specific
advice on glove selection and breakthrough times. Depending upon the conditions of use
and specific work situations, additional protective equipment and/or clothing may be
required to control exposures.
Respiratory protection:Approved organic vapor chemical cartridge or supplied air respirators should be worn for
exposures to any components exceeding the established exposure limits. Observe
respirator assigned protection factors (APFs) criteria cited in federal OSHA 29 CFR
1910.134. Self-contained breathing apparatus should be used for fire fighting.
Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance Clear Liquid
Color Colorless
Odor Sweet , Distinct
Odor Threshold 12 ppmv
Property Values (Method)
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 5 of 10
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
Melting Point / Freezing Point 5.5 °C / 42 °F
Initial Boiling Point / Boiling Range 80 °C / 176 °F
Flash Point -11 °C / 12 °F
Evaporation Rate 5.1 (Butyl acetate = 1)
Flammability (solid, gas)Not applicable.
Flammability Limit in Air (%):
Upper Flammability Limit:7.1
Lower Flammability Limit:1.4
Explosion limits:No data available.
Vapor Pressure 3.21 psia @ 100°F
Vapor Density 2.7 (Air = 1)
Specific Gravity / Relative Density 0.883
Water Solubility No data available.
Solubility in other solvents No data available.
Partition Coefficient No data available.
Decomposition temperature No data available.
pH:Not applicable.
Autoignition Temperature 562 °C / 1044 °F
Kinematic Viscosity 0.593 cSt @ 100°F
Dynamic Viscosity No data available.
Explosive Properties No data available.
VOC Content (%)No data available.
Density No data available.
Bulk Density Not applicable.
10. STABILITY AND REACTIVITY
Chemical stability The material is stable at 70°F (21°C ), 760 mmHg pressure.
Possibility of hazardous reactions None under normal processing.
Hazardous polymerization Will not occur.
Conditions to avoid Sources of heat or ignition.
Incompatible Materials Strong oxidizing agents.
Hazardous decomposition products None known under normal conditions of use.
11. TOXICOLOGICAL INFORMATION
Potential short-term adverse effects from overexposures
Inhalation Overexposure may cause respiratory tract irritation and central nervous system
depression. Breathing high concentrations of this material, for example, in a confined space
or by intentional abuse, can cause irregular heartbeats which can cause death.
Eye contact Irritating to eyes.
Skin contact Irritating to skin. May be absorbed through the skin in harmful amounts. Effects may
become more serious with repeated or prolonged contact.
Ingestion May be fatal if swallowed or vomited and enters airways. May cause irritation of the mouth,
throat and gastrointestinal tract. May cause central nervous system depression or effects.
Acute toxicological data
Name Oral LD50 Dermal LD50 Inhalation LC50
Benzene > 2000 mg/kg (Rat)> 5000 mg/kg (Rabbit)> 20 mg/l (Rat) 4 h
Reactivity The product is non-reactive under normal conditions.
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 6 of 10
_____________________________________________________________________________________________
0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
71-43-2
Delayed and immediate effects as well as chronic effects from short and long-term exposure
BENZENE: Studies of workers exposed to benzene show clear evidence that overexposure
can cause cancer and other diseases of the blood forming organs including Acute
Myelogenous Leukemia (AML), and Aplastic Anemia (AA), an often fatal disease. Some
studies suggest overexposure to benzene may also be associated with Myelodysplastic
Syndrome (MDS). Findings from a case control study of workers exposed to benzene was
reported during the 2009 Benzene Symposium in Munich included an increase in Acute
Myeloid Leukemias and Non-Hodgkins Lymphoid Neoplasms (NHLN) of the subtype
follicular lymphoma (FL) in some occupational categories. Some studies of workers
exposed to benzene have shown an association with increased rates of chromosome
aberrations in circulating lymphocytes. One study of women workers exposed to benzene
suggested a weak association with irregular menstruation. However, other studies of
workers exposed to benzene have not demonstrated clear evidence of an effect on fertility
or reproductive outcome in humans. Benzene can cross the placenta and affect the
developing fetus. Cases of AA have been reported in the offspring of persons severely
overexposed to benzene. Studies in laboratory animals indicate that prolonged, repeated
exposure to high levels of benzene vapor can cause bone marrow suppression and cancer
in multiple organ systems. Studies in laboratory animals show evidence of adverse effects
on male reproductive organs following high levels of exposure but no significant effects on
reproduction have been observed. Embryotoxicity has been reported in studies of
laboratory animals but effects were limited to reduced fetal weight and minor skeletal
variations. Benzene has been classified as a proven human carcinogen by OSHA and a
Group 1 (Carcinogenic to Humans) material by IARC. The current proposed IARC
classification for benzene is summarized as follows: Sufficient evidence for Acute Myeloid
Leukemia; limited evidence for Acute Lymphatic Leukemia, Chronic Lymphatic Leukemia,
Non-Hodgkin Lymphoma, and Multiple Myeloma.
Adverse effects related to the physical, chemical and toxicological characteristics
Signs and Symptoms Overexposure to vapors may cause eye, skin and respiratory irritation. Inhalation of high
vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea
and vomiting Repeated or prolonged skin contact may cause drying, reddening, itching and
cracking.
Sensitization Not expected to be a skin or respiratory sensitizer.
Mutagenic effects May cause genetic defects.
Carcinogenicity Cancer designations are listed in the table below
Name ACGIH
(Class)
IARC
(Class)
NTP OSHA
Benzene
71-43-2
Confirmed human
carcinogen (A1)
Carcinogenic to humans (1)Known to be human
carcinogen
Known carcinogen
Reproductive toxicity None known.
Specific Target Organ Toxicity
(STOT) - single exposure
Not classified.
Specific Target Organ Toxicity
(STOT) - repeated exposure
Blood. Blood-forming organs. Immune system.
Aspiration hazard May be fatal if swallowed or vomited and enters airways.
12. ECOLOGICAL INFORMATION
Ecotoxicity This product should be considered toxic to aquatic organisms.
Name Algae/aquatic plants Fish Toxicity to Crustacea
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 7 of 10
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
Microorganisms
Benzene
71-43-2
72-hr EC50 = 29 mg/l
Algae
96-hr LC50 = 5.3 mg/l
Rainbow trout
(flow-through)
-48-hr EC50 = 8.76-15.6 mg/l
Daphnia magna (Static)
Persistence and degradability Readily biodegradable in the environment.
Bioaccumulation Not expected to bioaccumulate in aquatic organisms.
Mobility in soil May partition into air, soil and water.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Description of Waste Residues
This material may be a flammable liquid waste.
Safe Handling of Wastes
Handle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required. Use
appropriate grounding and bonding practices. Use only non-sparking tools. Do not expose to heat, open flames, strong oxidizers or
other sources of ignition. No smoking.
Disposal of Wastes / Methods of Disposal
The user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordance
with federal, state and local regulations.
Methods of Contaminated Packaging DisposalEmpty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on empty
containers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (49 CFR 172.101):
UN Proper Shipping Name:Benzene
UN/Identification No:UN 1114
Class:3
Packing Group:II
TDG (Canada):
UN Proper Shipping Name:Benzene
UN/Identification No:UN 1114
Transport Hazard Class(es):3
Packing Group:II
15. REGULATORY INFORMATION
US Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b):This product and/or its components are listed on the TSCA
Chemical Inventory.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302:This product does not contain any component(s) included on EPA's Extremely Hazardous
Substance (EHS) List.
Name CERCLA/SARA - Section 302 Extremely Hazardous
Substances and TPQs
Benzene NA
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 8 of 10
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0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
SARA Section 304:This product may contain component(s) identified either as an EHS or a CERCLA
Hazardous substance which in case of a spill or release may be subject to SARA reporting
requirements:
Name Hazardous Substances RQs
Benzene 10
SARA Section 311/312:The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA Section 313:This product may contain component(s), which if in exceedance of the de minimus
threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic
Release Reporting (Form R).
Name CERCLA/SARA 313 Emission reporting:
Benzene 0.1 % de minimis concentration
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Benzene
Louisiana Right-To-Know:Not Listed
California Proposition 65:Carcinogen, initial date 2/27/87
Developmental toxicity, initial date 12/26/97
Male reproductive toxicity, initial date 12/26/97
New Jersey Right-To-Know:SN 0197
Pennsylvania Right-To-Know:Environmental hazard; Special hazardous substance
Massachusetts Right-To Know:Carcinogen; Extraordinarily hazardous
Florida Substance List:Not Listed
Rhode Island Right-To-Know:Toxic (skin); Flammable (skin); Carcinogen (skin)
Michigan Critical Materials Register List:100 lb Annual usage threshold
Massachusetts Extraordinarily Hazardous Substances:Carcinogen; Extraordinarily hazardous
California - Regulated Carcinogens:Not Listed
Pennsylvania RTK - Special Hazardous
Substances:
Present
New Jersey - Special Hazardous Substances:Carcinogen; Flammable - third degree; Mutagen
New Jersey - Environmental Hazardous
Substances List:
SN 0197 TPQ: 500 lb
Illinois - Toxic Air Contaminants:Present
New York - Reporting of Releases Part 597 -
List of Hazardous Substances:
10 lb RQ (air); 1 lb RQ (land/water)
Canada DSL/NDSL Inventory:This product and/or its components are listed either on the Domestic Substances List (DSL)
or are exempt.
Canadian Regulatory Information:This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the SDS contains all of the information required by those
regulations.
Name Canada - WHMIS: Classifications of
Substances:
Canada - WHMIS: Ingredient
Disclosure:
Benzene B2,D2A,D2B 0.1%
Note:Not applicable.
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 9 of 10
16. OTHER INFORMATION
_____________________________________________________________________________________________
0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015
Prepared By Toxicology and Product Safety
Revision Notes
Revision Date 05/14/2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information is intended as guidance for safe handling, use, processing, storage,
transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 10 of 10
APPENDIX B
EMERGENCY PHONE NUMBERS

Emergency Contact Phone Number
Environmental PM: Greg Hans, PMP 617.828.9948 (M)
CES Group Engineers, LLP 704.325.5408 (D)

Other SSO (if assigned by
by Env PM) Carolina Soil Investigations (Drillers) 704.539.5279
(assigned CSI field crew chief)

Back-up PM Chuck Heleine 704.308.7916 (M)
CES Group Engineers, LLP

Police: North Carolina Highway Patrol 911
Stokes County Sheriff 336.593.8787

Hospital: Novant Health Forsyth Medical Center 336.718.5000
3333 Silas Creek Parkway
Winston-Salem, NC 27103

Fire: Walnut Cove Volunteer Fire Department 336.591.4477

Doctor: Novant Health Forsyth Medical Center 336.718.5000

Ambulance 911

NCDENR (Winston-Salem Region) 336.776.9800

Directions to the nearest hospital: Novant Health Forsyth Medical Center, 3333 Silas
Creek Parkway, Winston-Salem, NC 27103

Refer to Appendix C.

APPENDIX C
ROUTE TO HOSPITAL

Starting at approximate address of 1107 N Main Street, Walnut Cove, NC 27052

End at Novant Health Forsyth Medical Center, 3333 Silas Creek Parkway, Winston-Salem,
NC 27103

Site/Location Contract Number N040722
Customer NCDEQ STF (Scott Ryals)Prepared By Greg Hans
Competent Person Greg Hans Date Prepared 1/24/2023
Phone Number 617-828-9948 PPE Level Level D
Step
Step
Step
Step
Step
Closest Hospital/ER Novant Health Forsyth Medical Center
Hospital Address 3333 Silas Creek Parkway, Winston-Salem, NC CALL 911 Hospital Phone #[phone] FOR
Local Police Number 336-593-8787 (Stokes County Sherriff)EMERGENCY
Greg Hans 1/24/2023
Signature Date Printed Name
3525 Whitehall Park Drive, Suite 150, Charlotte, NC 28273
Follow Driving and Parking Steps each
mobilization. Maintain safe distance from drilling
equipment while in progress. Discuss SOW with
drillers. Keep close eye on where drillers stand,
and do not venture into areas of drilling w/o
discussing with drillers first
Sequence of Basic Job Steps Potential Incidents or Hazards
Recommended Procedures to Eliminate
Potential Hazards/Incidents
5 Collecting Soil and GW Samples Exposure to Contaminants
Wear proper PPE (change gloves to avoid cross
contamination). Monitor ambient air for petroleum
vapors. Discuss planned soil and GW collection
procedures with drillers prior to starting
2 Parking Vehicular accidents / damage to vehicles
Park in areas off of roadway, at least 10 feet, use
orange cones and flashers to identify parked
location. Discuss parking areas with current site
owners/managers, and confirm with
subconsultants
3 Site Recon / Surveys Slips, Trips, Falls / Vehicles
Wear proper PPE (including visibility vest),
maintain safe distance from travel lanes at all
times, do not turn back to oncoming traffic. Avoid
crossing busy streets/intersections. Check surface
areas prior to accessing for S, T, F hazards
Job Hazard Analysis & Health/Safety Issues
Sequence of Basic Job Steps Potential Incidents or Hazards
Recommended Procedures to Eliminate
Potential Hazards/Incidents
Driving / Site Access Vehicular accidents / traffic violations /
accidents with large equipment
Practice defensive driving techniques, use turn
signals, stay in lanes, obey speed limits / while
onsite, pay close attention to large pieces of
equipment in facility and make eye contact with
operators before proceeding / always have strobe
light flashers on
1
Bullins Grocery (1107 N Main
Street, Walnut Cove, NC)
Sequence of Basic Job Steps Potential Incidents or Hazards
Recommended Procedures to Eliminate
Potential Hazards/Incidents
Sequence of Basic Job Steps Potential Incidents or Hazards
Recommended Procedures to Eliminate
Potential Hazards/Incidents
Sequence of Basic Job Steps Potential Incidents or Hazards
Recommended Procedures to Eliminate
Potential Hazards/Incidents
4 Drilling Contact with Heavy Equipment
APPENDIX C
SOIL AND GROUNDWATER WELL
LABORATORY REPORTS AND CHAIN-
OF-CUSTODY RECORDS

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

9/27/2023
CES Group Greg Hans
3525 Whitehall Park Dr. Suite 150 Charlotte, NC, 28273
Ref: Analytical Testing
Lab Report Number: 23-258-0006 Client Project Description: Bullins Grocery
Dear Greg Hans:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 9/15/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 113
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/23-258-0006
Page 2 of 113
Report Number:
Sample Summary Table
Client Project Description:
23-258-0006
Bullins Grocery
Lab No Client Sample ID Matrix Date Collected Date Received
09/14/2023 09:45Solids 95231 MW-2 09/15/2023 16:20
09/14/2023 10:30Solids 95232 MW-3 09/15/2023 16:20
09/14/2023 11:30Solids 95233 MW-4 09/15/2023 16:20
09/14/2023 11:55Aqueous 95234 MW-2 09/15/2023 16:20
09/14/2023 12:55Aqueous 95235 MW-3 09/15/2023 16:20
09/14/2023 13:00Aqueous 95236 MW-4 09/15/2023 16:20
Page 3 of 113
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-258-0006
Report Limit
Project:Bullins Grocery
V 95231MW-2
30.8 09/19/2023 15:176010DChromiummg/Kg - dry 1.09
17.1 09/19/2023 15:176010DLeadmg/Kg - dry 0.507
J0.001 09/15/2023 14:408260Dn-Hexane mg/Kg - dry 0.0008
J0.003 09/15/2023 14:408260DMethylene Chloride mg/Kg - dry 0.001
22.1 09/18/2023 16:10SW-DRYWT Moisture %
V 95232MW-3
32.4 09/18/2023 23:276010DChromiummg/Kg - dry 0.217
19.7 09/18/2023 23:276010DLeadmg/Kg - dry 0.100
J0.002 09/15/2023 15:088260Dn-Hexane mg/Kg - dry 0.0008
J0.002 09/15/2023 15:088260DMethylene Chloride mg/Kg - dry 0.001
J0.011 09/15/2023 15:088260DNaphthalenemg/Kg - dry 0.001
J17.4 09/20/2023 00:22MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 15.6
21.7 09/18/2023 16:10SW-DRYWT Moisture %
V 95233MW-4
28.8 09/19/2023 15:226010DChromiummg/Kg - dry 1.06
51.1 09/19/2023 15:226010DLeadmg/Kg - dry 0.493
2.72 09/15/2023 16:028260DBenzenemg/Kg - dry 0.181
6.04 09/15/2023 16:028260Dn-Butylbenzene mg/Kg - dry 0.153
3.03 09/15/2023 16:028260Dsec-Butyl benzene mg/Kg - dry 0.174
51.2 09/15/2023 16:028260DEthylbenzenemg/Kg - dry 0.181
11.1 09/15/2023 16:028260Dn-Hexane mg/Kg - dry 0.205
7.69 09/15/2023 16:028260DIsopropylbenzenemg/Kg - dry 0.143
2.18 09/15/2023 16:028260D4-Isopropyl toluene mg/Kg - dry 0.405
22.0 09/15/2023 16:028260DNaphthalenemg/Kg - dry 0.309
27.1 09/15/2023 16:028260Dn-Propylbenzene mg/Kg - dry 0.168
J0.523 09/15/2023 16:028260DStyrenemg/Kg - dry 0.443
87.1 09/15/2023 16:028260DToluenemg/Kg - dry 0.205
186 09/15/2023 16:298260D1,2,4-Trimethylbenzene mg/Kg - dry 1.54
55.4 09/15/2023 16:028260D1,3,5-Trimethylbenzene mg/Kg - dry 0.168
89.1 09/15/2023 16:028260Do-Xylene mg/Kg - dry 0.156
212 09/15/2023 16:028260Dm,p-Xylene mg/Kg - dry 0.393
301 09/15/2023 16:028260DXylene (Total)mg/Kg - dry 0.156
2.83 09/20/2023 18:148270E1-Methylnaphthalene mg/Kg - dry 0.132
6.29 09/20/2023 18:148270E2-Methylnaphthalene mg/Kg - dry 0.124
9.69 09/21/2023 12:468270ENaphthalenemg/Kg - dry 0.359
325 09/20/2023 00:58MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 11.5
Page 4 of 113
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-258-0006
Report Limit
Project:Bullins Grocery
V 95233MW-4
123 09/20/2023 00:58MADEP-EPH Aromatic C11-C22 mg/Kg - dry 17.9
589 09/15/2023 16:07MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 7.59
685 09/15/2023 16:07MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 28.5
421 09/15/2023 16:07MADEP-VPH Aromatic C9-C10 mg/Kg - dry 3.90
19.9 09/18/2023 16:10SW-DRYWT Moisture %
V 95234MW-2
0.031 09/20/2023 15:326010DChromiummg/L 0.002
0.019 09/19/2023 20:456010DLeadmg/L 0.002
11.0 09/21/2023 15:586200BBenzeneµg/L 0.180
10.2 09/21/2023 15:586200Bn-Butylbenzene µg/L 0.180
7.00 09/21/2023 15:586200Bsec-Butyl benzene µg/L 0.200
0.851 09/21/2023 15:586200BDi-Isopropyl Ether (DIPE)µg/L 0.500
393 09/22/2023 19:146200BEthylbenzeneµg/L 1.70
50.2 09/21/2023 15:586200BIsopropylbenzeneµg/L 0.180
3.14 09/21/2023 15:586200B4-Isopropyl toluene µg/L 0.089
140 09/22/2023 19:146200BMethyl tert-butyl ether (MTBE)µg/L 1.40
4.36 09/21/2023 15:586200B4-Methyl-2-Pentanone µg/L 0.078
167 09/22/2023 19:146200BNaphthaleneµg/L 4.70
86.8 09/21/2023 15:586200Bn-Propylbenzene µg/L 0.190
41.8 09/21/2023 15:586200Btert-Butyl Alcohol (TBA)µg/L 1.60
J7.68 09/21/2023 15:586200Btert-Amyl Alcohol (TAA)µg/L 1.90
J0.669 09/21/2023 15:586200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
72.2 09/21/2023 15:586200BTolueneµg/L 0.220
863 09/22/2023 19:146200B1,2,4-Trimethylbenzene µg/L 1.90
98.4 09/21/2023 15:586200B1,3,5-Trimethylbenzene µg/L 0.180
866 09/22/2023 19:146200Bo-Xylene µg/L 2.10
1980 09/25/2023 22:426200Bm,p-Xylene µg/L 42.0
2850 09/22/2023 19:146200BXylene (Total)µg/L 2.10
39.3 09/18/2023 21:09625.1 Diethyl phthalate µg/L 0.745
9.55 09/18/2023 21:09625.1 1-Methylnaphthalene µg/L 1.14
19.5 09/18/2023 21:09625.1 2-Methylnaphthalene µg/L 0.666
76.7 09/18/2023 21:09625.1 Naphthalene µg/L 0.728
0.173 09/21/2023 14:51EPA-504.1 1,2-Dibromoethane µg/L 0.00347
614 09/19/2023 20:08MADEP-EPH Aromatic C11-C22 µg/L 61.2
740 09/15/2023 20:03MADEP-VPH Aliphatic C5-C8 µg/L 115
6020 09/15/2023 20:03MADEP-VPH Aliphatic C9-C12 µg/L 258
Page 5 of 113
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-258-0006
Report Limit
Project:Bullins Grocery
V 95234MW-2
1740 09/15/2023 20:03MADEP-VPH Aromatic C9-C10 µg/L 40.2
V 95235MW-3
0.093 09/20/2023 15:366010DChromiummg/L 0.002
0.065 09/19/2023 20:496010DLeadmg/L 0.002
J89209/21/2023 21:206200BAcetoneµg/L 180
10900 09/22/2023 21:506200BBenzeneµg/L 180
1080 09/21/2023 21:206200BDi-Isopropyl Ether (DIPE)µg/L 50.0
229 09/21/2023 21:206200B1,2-Dichloroethane µg/L 15.0
3010 09/21/2023 21:206200BEthylbenzeneµg/L 17.0
882 09/21/2023 21:206200B2-Hexanone µg/L 38.0
85.9 09/21/2023 21:206200BIsopropylbenzeneµg/L 18.0
771 09/21/2023 21:206200BMethyl Ethyl Ketone (MEK)µg/L 71.0
304 09/21/2023 21:206200BMethyl tert-butyl ether (MTBE)µg/L 14.0
452 09/21/2023 21:206200B4-Methyl-2-Pentanone µg/L 7.80
736 09/21/2023 21:206200BNaphthaleneµg/L 47.0
235 09/21/2023 21:206200Bn-Propylbenzene µg/L 19.0
J92509/21/2023 21:206200Btert-Butyl Alcohol (TBA)µg/L 160
3320 09/21/2023 21:206200Btert-Amyl Alcohol (TAA)µg/L 190
41000 09/22/2023 21:506200BTolueneµg/L 220
2040 09/21/2023 21:206200B1,2,4-Trimethylbenzene µg/L 19.0
508 09/21/2023 21:206200B1,3,5-Trimethylbenzene µg/L 18.0
5740 09/21/2023 21:206200Bo-Xylene µg/L 21.0
12200 09/21/2023 21:206200Bm,p-Xylene µg/L 42.0
17900 09/21/2023 21:206200BXylene (Total)µg/L 21.0
38.2 09/18/2023 21:32625.1 Benzoic Acid µg/L 1.10
18.6 09/18/2023 21:32625.1 1-Methylnaphthalene µg/L 1.14
37.9 09/18/2023 21:32625.1 2-Methylnaphthalene µg/L 0.666
170 09/18/2023 21:32625.1 Naphthalene µg/L 0.728
J1.03 09/18/2023 21:32625.1 Phenanthrene µg/L 0.428
108 09/21/2023 15:49EPA-504.1 1,2-Dibromoethane µg/L 0.685
J41.5 09/19/2023 20:44MADEP-EPH Aliphatic C9-C18 µg/L 28.2
545 09/19/2023 20:44MADEP-EPH Aromatic C11-C22 µg/L 61.2
80500 09/15/2023 21:37MADEP-VPH Aliphatic C5-C8 µg/L 1150
39700 09/15/2023 21:37MADEP-VPH Aliphatic C9-C12 µg/L 2580
5450 09/15/2023 21:37MADEP-VPH Aromatic C9-C10 µg/L 402
Page 6 of 113
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-258-0006
Report Limit
Project:Bullins Grocery
V 95236MW-4
0.029 09/20/2023 15:416010DChromiummg/L 0.002
0.028 09/19/2023 20:536010DLeadmg/L 0.002
1720 09/21/2023 21:456200BAcetoneµg/L 180
17900 09/22/2023 22:166200BBenzeneµg/L 180
J20.4 09/21/2023 21:456200Bn-Butylbenzene µg/L 18.0
J25.9 09/21/2023 21:456200Bsec-Butyl benzene µg/L 20.0
6970 09/21/2023 21:456200BDi-Isopropyl Ether (DIPE)µg/L 50.0
2150 09/21/2023 21:456200B1,2-Dichloroethane µg/L 15.0
60.8 09/21/2023 21:456200B1,2-Dichloropropane µg/L 19.0
1730 09/21/2023 21:456200BEthylbenzeneµg/L 17.0
372 09/21/2023 21:456200B2-Hexanone µg/L 38.0
89.0 09/21/2023 21:456200BIsopropylbenzeneµg/L 18.0
1820 09/21/2023 21:456200BMethyl Ethyl Ketone (MEK)µg/L 71.0
354 09/21/2023 21:456200BMethyl tert-butyl ether (MTBE)µg/L 14.0
223 09/21/2023 21:456200B4-Methyl-2-Pentanone µg/L 7.80
838 09/21/2023 21:456200BNaphthaleneµg/L 47.0
200 09/21/2023 21:456200Bn-Propylbenzene µg/L 19.0
J64809/21/2023 21:456200Btert-Butyl Alcohol (TBA)µg/L 160
12800 09/22/2023 22:166200Btert-Amyl Alcohol (TAA)µg/L 1900
22900 09/22/2023 22:166200BTolueneµg/L 220
1670 09/21/2023 21:456200B1,2,4-Trimethylbenzene µg/L 19.0
461 09/21/2023 21:456200B1,3,5-Trimethylbenzene µg/L 18.0
2850 09/21/2023 21:456200Bo-Xylene µg/L 21.0
6710 09/21/2023 21:456200Bm,p-Xylene µg/L 42.0
9560 09/21/2023 21:456200BXylene (Total)µg/L 21.0
138 09/18/2023 21:55625.1 Benzyl alcohol µg/L 0.684
48.6 09/18/2023 21:55625.1 1-Methylnaphthalene µg/L 1.14
72.9 09/18/2023 21:55625.1 2-Methylnaphthalene µg/L 0.666
171 09/18/2023 21:55625.1 Naphthalene µg/L 0.728
462 09/21/2023 16:09EPA-504.1 1,2-Dibromoethane µg/L 1.73
J59.4 09/19/2023 21:20MADEP-EPH Aliphatic C9-C18 µg/L 28.2
871 09/19/2023 21:20MADEP-EPH Aromatic C11-C22 µg/L 61.2
68200 09/15/2023 20:50MADEP-VPH Aliphatic C5-C8 µg/L 1150
10800 09/15/2023 20:27MADEP-VPH Aliphatic C9-C12 µg/L 258
3490 09/15/2023 20:27MADEP-VPH Aromatic C9-C10 µg/L 40.2
Page 7 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
22.1 %Moisture 1 09/18/23 16:10 SW-DRYWTCNC
30.8 mg/Kg - dry 1.09 3.21Chromium 5 09/19/23 15:17 6010DJKC
17.1 mg/Kg - dry 0.507 1.93Lead 5 09/19/23 15:17 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 8 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.003 mg/Kg - dry 0.003 0.025Acetone 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.025Acrolein 1 09/15/23 14:40 V37960TBL
<0.0010 mg/Kg - dry 0.0010 0.025Acrylonitrile 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Benzene 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Bromobenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromochloromethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 09/15/23 14:40 V37960TBL
<0.002 mg/Kg - dry 0.002 0.012
Bromomethane 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006tert-Butyl benzene 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 09/15/23 14:40 V37960TBL
<0.002 mg/Kg - dry 0.002 0.006Carbon Tetrachloride 1 09/15/23 14:40 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.006Chlorobenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Chloroethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.012Chloromethane 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0062-Chlorotoluene 1 09/15/23 14:40 V37960TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 09/15/23 14:40 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.006Di-Isopropyl Ether (DIPE)1 09/15/23 14:40 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 9 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0006 mg/Kg - dry 0.0006 0.0121,2-Dibromo-3-Chloropropane 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,2-Dibromoethane 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 09/15/23 14:40 V37960TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 09/15/23 14:40 V37960TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,4-Dichlorobenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Dichlorodifluoromethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 09/15/23 14:40 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,1-Dichloroethene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006cis-1,2-Dichloroethene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2-Dichloropropane 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 09/15/23 14:40 V37960TBL
<0.0010 mg/Kg - dry 0.0010 0.006
1,1-Dichloropropene 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,3-Dichloropropene 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Ethylbenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.064Ethyl Tertiary Butyl Ether (ETBE)1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Hexachlorobutadiene 1 09/15/23 14:40 V37960TBL
0.001 J mg/Kg - dry 0.0008 0.012n-Hexane 1 09/15/23 14:40 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0008 mg/Kg - dry 0.0008 0.0252-Hexanone 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.025Methyl Ethyl Ketone (MEK)1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 09/15/23 14:40 V37960TBL
<0.019 mg/Kg - dry 0.019 0.0254-Methyl-2-Pentanone 1 09/15/23 14:40 V37960TBL
0.003 J mg/Kg - dry 0.001 0.012Methylene Chloride 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Naphthalene 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 09/15/23 14:40 V37960TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Toluene 1 09/15/23 14:40 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0121,2,3-Trichlorobenzene 1 09/15/23 14:40 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.012
1,2,4-Trichlorobenzene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 09/15/23 14:40 V37960TBL
<0.002 mg/Kg - dry 0.002 0.012Trichlorofluoromethane 1 09/15/23 14:40 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 09/15/23 14:40 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0007 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Acetate 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Chloride 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006o-Xylene 1 09/15/23 14:40 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012m,p-Xylene 1 09/15/23 14:40 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Xylene (Total)1 09/15/23 14:40 V37960
Surrogate: 4-Bromofluorobenzene 99.1 Limits: 70-130%09/15/23 14:401 TBL V37960
Surrogate: Dibromofluoromethane 104 Limits: 84-123%09/15/23 14:401 TBL V37960
Surrogate: Toluene-d8 93.5 Limits: 76-129%09/15/23 14:401 TBL V37960
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.148 mg/Kg - dry 0.148 0.847Acenaphthene 1 09/20/23 17:51 V38117AMP
<0.134 mg/Kg - dry 0.134 0.847Acenaphthylene 1 09/20/23 17:51 V38117AMP
<0.195 mg/Kg - dry 0.195 0.847Aniline 1 09/20/23 17:51 V38117AMP
<0.183 mg/Kg - dry 0.183 0.847Anthracene 1 09/20/23 17:51 V38117AMP
<0.178 mg/Kg - dry 0.178 0.847Benzo(a)anthracene 1 09/20/23 17:51 V38117AMP
<0.188 mg/Kg - dry 0.188 0.847
Benzo(a)pyrene 1 09/20/23 17:51 V38117AMP
<0.187 mg/Kg - dry 0.187 0.847Benzo(b)fluoranthene 1 09/20/23 17:51 V38117AMP
<0.174 mg/Kg - dry 0.174 0.847Benzo(g,h,i)perylene 1 09/20/23 17:51 V38117AMP
<0.175 mg/Kg - dry 0.175 0.847Benzo(k)fluoranthene 1 09/20/23 17:51 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.744 mg/Kg - dry 0.744 2.57Benzoic Acid 1 09/20/23 17:51 V38117AMP
<0.134 mg/Kg - dry 0.134 0.847Benzyl alcohol 1 09/20/23 17:51 V38117AMP
<0.151 mg/Kg - dry 0.151 0.847Bis(2-Chloroethoxy)methane 1 09/20/23 17:51 V38117AMP
<0.137 mg/Kg - dry 0.137 0.847Bis(2-Chloroethyl)ether 1 09/20/23 17:51 V38117AMP
<0.174 mg/Kg - dry 0.174 0.423Bis(2-Chloroisopropyl)ether 1 09/20/23 17:51 V38117AMP
<0.154 mg/Kg - dry 0.154 0.847Bis(2-ethylhexyl)phthalate 1 09/20/23 17:51 V38117AMP
<0.139 mg/Kg - dry 0.139 0.8474-Bromophenyl phenyl ether 1 09/20/23 17:51 V38117AMP
<0.145 mg/Kg - dry 0.145 0.423Butyl benzyl phthalate 1 09/20/23 17:51 V38117AMP
<0.118 mg/Kg - dry 0.118 0.847
4-Chloro-3-methylphenol 1 09/20/23 17:51 V38117AMP
<0.143 mg/Kg - dry 0.143 0.4234-Chloroaniline 1 09/20/23 17:51 V38117AMP
<0.148 mg/Kg - dry 0.148 0.8472-Chloronaphthalene 1 09/20/23 17:51 V38117AMP
<0.126 mg/Kg - dry 0.126 0.8472-Chlorophenol 1 09/20/23 17:51 V38117AMP
<0.161 mg/Kg - dry 0.161 1.284-Chlorophenyl phenyl ether 1 09/20/23 17:51 V38117AMP
<0.182 mg/Kg - dry 0.182 0.847Chrysene 1 09/20/23 17:51 V38117AMP
<0.295 mg/Kg - dry 0.295 0.847Dibenz(a,h)anthracene 1 09/20/23 17:51 V38117AMP
<0.152 mg/Kg - dry 0.152 0.847
Dibenzofuran 1 09/20/23 17:51 V38117AMP
<0.121 mg/Kg - dry 0.121 0.8471,2-Dichlorobenzene 1 09/20/23 17:51 V38117AMP
<0.124 mg/Kg - dry 0.124 0.8471,3-Dichlorobenzene 1 09/20/23 17:51 V38117AMP
<0.125 mg/Kg - dry 0.125 0.4231,4-Dichlorobenzene 1 09/20/23 17:51 V38117AMP
<0.188 mg/Kg - dry 0.188 0.8473,3'-Dichlorobenzidine 1 09/20/23 17:51 V38117AMP
<0.122 mg/Kg - dry 0.122 0.8472,4-Dichlorophenol 1 09/20/23 17:51 V38117AMP
<0.231 mg/Kg - dry 0.231 0.847Diethyl phthalate 1 09/20/23 17:51 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.223 mg/Kg - dry 0.223 0.847Dimethyl phthalate 1 09/20/23 17:51 V38117AMP
<0.138 mg/Kg - dry 0.138 0.4232,4-Dimethylphenol 1 09/20/23 17:51 V38117AMP
<0.137 mg/Kg - dry 0.137 0.847Di-n-butyl phthalate 1 09/20/23 17:51 V38117AMP
<0.308 mg/Kg - dry 0.308 1.934,6-Dinitro-2-methylphenol 1 09/20/23 17:51 V38117AMP
<0.667 mg/Kg - dry 0.667 1.932,4-Dinitrophenol 1 09/20/23 17:51 V38117AMP
<0.124 mg/Kg - dry 0.124 0.8472,4-Dinitrotoluene 1 09/20/23 17:51 V38117AMP
<0.138 mg/Kg - dry 0.138 0.8472,6-Dinitrotoluene 1 09/20/23 17:51 V38117AMP
<0.183 mg/Kg - dry 0.183 0.423Di-n-Octyl Phthalate 1 09/20/23 17:51 V38117AMP
<0.157 mg/Kg - dry 0.157 0.847
Fluoranthene 1 09/20/23 17:51 V38117AMP
<0.164 mg/Kg - dry 0.164 0.847Fluorene 1 09/20/23 17:51 V38117AMP
<0.136 mg/Kg - dry 0.136 0.847Hexachlorobenzene 1 09/20/23 17:51 V38117AMP
<0.125 mg/Kg - dry 0.125 0.847Hexachlorobutadiene 1 09/20/23 17:51 V38117AMP
<0.201 mg/Kg - dry 0.201 0.847Hexachlorocyclopentadiene 1 09/20/23 17:51 V38117AMP
<0.101 mg/Kg - dry 0.101 0.847Hexachloroethane 1 09/20/23 17:51 V38117AMP
<0.229 mg/Kg - dry 0.229 0.847Indeno(1,2,3-cd)pyrene 1 09/20/23 17:51 V38117AMP
<0.245 mg/Kg - dry 0.245 0.847
Isophorone 1 09/20/23 17:51 V38117AMP
<0.136 mg/Kg - dry 0.136 0.8471-Methylnaphthalene 1 09/20/23 17:51 V38117AMP
<0.128 mg/Kg - dry 0.128 0.8472-Methylnaphthalene 1 09/20/23 17:51 V38117AMP
<0.124 mg/Kg - dry 0.124 0.8472-Methylphenol 1 09/20/23 17:51 V38117AMP
<0.108 mg/Kg - dry 0.108 0.8473&4 Methylphenol 1 09/20/23 17:51 V38117AMP
<0.184 mg/Kg - dry 0.184 0.847Naphthalene 1 09/20/23 17:51 V38117AMP
<0.124 mg/Kg - dry 0.124 0.8472-Nitroaniline 1 09/20/23 17:51 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.154 mg/Kg - dry 0.154 0.8473-Nitroaniline 1 09/20/23 17:51 V38117AMP
<0.119 mg/Kg - dry 0.119 0.4234-Nitroaniline 1 09/20/23 17:51 V38117AMP
<0.148 mg/Kg - dry 0.148 0.423Nitrobenzene 1 09/20/23 17:51 V38117AMP
<0.113 mg/Kg - dry 0.113 0.8472-Nitrophenol 1 09/20/23 17:51 V38117AMP
<0.150 mg/Kg - dry 0.150 0.8474-Nitrophenol 1 09/20/23 17:51 V38117AMP
<0.337 mg/Kg - dry 0.337 0.847N-Nitrosodimethylamine 1 09/20/23 17:51 V38117AMP
<0.232 mg/Kg - dry 0.232 0.847N-Nitrosodiphenylamine 1 09/20/23 17:51 V38117AMP
<0.151 mg/Kg - dry 0.151 0.847N-Nitroso-di-n-propylamine 1 09/20/23 17:51 V38117AMP
<0.445 mg/Kg - dry 0.445 1.28
Pentachlorophenol 1 09/20/23 17:51 V38117AMP
<0.267 mg/Kg - dry 0.267 0.847Phenanthrene 1 09/20/23 17:51 V38117AMP
<0.143 mg/Kg - dry 0.143 0.847Phenol 1 09/20/23 17:51 V38117AMP
<0.172 mg/Kg - dry 0.172 0.847Pyrene 1 09/20/23 17:51 V38117AMP
<0.101 mg/Kg - dry 0.101 0.423Pyridine 1 09/20/23 17:51 V38117AMP
<0.137 mg/Kg - dry 0.137 0.8471,2,4-Trichlorobenzene 1 09/20/23 17:51 V38117AMP
<0.123 mg/Kg - dry 0.123 0.8472,4,5-Trichlorophenol 1 09/20/23 17:51 V38117AMP
<0.124 mg/Kg - dry 0.124 0.847
2,4,6-Trichlorophenol 1 09/20/23 17:51 V38117AMP
8270ESurrogate: Phenol-d5 66.1 Limits: 34-121%09/20/23 17:511 AMP
Surrogate: 2-Fluorobiphenyl 80.7 Limits: 44-115%09/20/23 17:511 AMP V38117
Surrogate: 2-Fluorophenol 67.6 Limits: 35-115%09/20/23 17:511 AMP V38117
Surrogate: Nitrobenzene-d5 77.1 Limits: 37-122%09/20/23 17:511 AMP V38117
Surrogate: 4-Terphenyl-d14 91.0 Limits: 54-127%09/20/23 17:511 AMP V38117
Surrogate: 2,4,6-Tribromophenol 81.7 Limits: 39-132%09/20/23 17:511 AMP V38117
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95231 Matrix:
9/14/2023 9:45
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V37937 09/18/23 10:40
<11.8 mg/Kg - dry 11.8 64.2Aliphatic C9-C18 1 09/19/23 23:46 V38061AMP
<15.7 mg/Kg - dry 15.7 64.2Aliphatic C19-C36 1 09/19/23 23:46 V38061AMP
<18.2 mg/Kg - dry 18.2 64.2Aromatic C11-C22 1 09/19/23 23:46 V38061AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 80.5 Limits: 40-140%09/19/23 23:461 AMP
MADEP-EPHSurrogate: Chlorooctadecane 73.9 Limits: 40-140%09/19/23 23:461 AMP
MADEP-EPHSurrogate: OTP Surrogate 78.1 Limits: 40-140%09/19/23 23:461 AMP
Surrogate: 2-Fluorobiphenyl 87.3 Limits: 40-140%09/19/23 23:461 AMP V38061
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37913 09/15/23 08:00
<1.57 mg/Kg - dry 1.57 10.3
Aliphatic C5-C8 100 09/15/23 14:57 V37914TBL
<5.85 mg/Kg - dry 5.85 10.3Aliphatic C9-C12 100 09/15/23 14:57 V37914TBL
<0.801 mg/Kg - dry 0.801 10.3Aromatic C9-C10 100 09/15/23 14:57 V37914TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)97.2 Limits: 70-130%09/15/23 14:57100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)94.4 Limits: 70-130%09/15/23 14:57100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
21.7 %Moisture 1 09/18/23 16:10 SW-DRYWTCNC
32.4 mg/Kg - dry 0.217 0.638Chromium 1 09/18/23 23:27 6010DJKC
19.7 mg/Kg - dry 0.100 0.383Lead 1 09/18/23 23:27 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.003 mg/Kg - dry 0.003 0.025Acetone 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.025Acrolein 1 09/15/23 15:08 V37960TBL
<0.0010 mg/Kg - dry 0.0010 0.025Acrylonitrile 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Benzene 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Bromobenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromochloromethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 09/15/23 15:08 V37960TBL
<0.002 mg/Kg - dry 0.002 0.012
Bromomethane 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006tert-Butyl benzene 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 09/15/23 15:08 V37960TBL
<0.002 mg/Kg - dry 0.002 0.006Carbon Tetrachloride 1 09/15/23 15:08 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.006Chlorobenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Chloroethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.012Chloromethane 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0062-Chlorotoluene 1 09/15/23 15:08 V37960TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 09/15/23 15:08 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.006Di-Isopropyl Ether (DIPE)1 09/15/23 15:08 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0006 mg/Kg - dry 0.0006 0.0121,2-Dibromo-3-Chloropropane 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,2-Dibromoethane 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 09/15/23 15:08 V37960TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 09/15/23 15:08 V37960TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,4-Dichlorobenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Dichlorodifluoromethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 09/15/23 15:08 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,1-Dichloroethene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006cis-1,2-Dichloroethene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2-Dichloropropane 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 09/15/23 15:08 V37960TBL
<0.0010 mg/Kg - dry 0.0010 0.006
1,1-Dichloropropene 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,3-Dichloropropene 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006Ethylbenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.063Ethyl Tertiary Butyl Ether (ETBE)1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012Hexachlorobutadiene 1 09/15/23 15:08 V37960TBL
0.002 J mg/Kg - dry 0.0008 0.012n-Hexane 1 09/15/23 15:08 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0008 mg/Kg - dry 0.0008 0.0252-Hexanone 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.025Methyl Ethyl Ketone (MEK)1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 09/15/23 15:08 V37960TBL
<0.019 mg/Kg - dry 0.019 0.0254-Methyl-2-Pentanone 1 09/15/23 15:08 V37960TBL
0.002 J mg/Kg - dry 0.001 0.012Methylene Chloride 1 09/15/23 15:08 V37960TBL
0.011 J mg/Kg - dry 0.001 0.012Naphthalene 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 09/15/23 15:08 V37960TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.006Toluene 1 09/15/23 15:08 V37960TBL
<0.0007 mg/Kg - dry 0.0007 0.0121,2,3-Trichlorobenzene 1 09/15/23 15:08 V37960TBL
<0.0008 mg/Kg - dry 0.0008 0.012
1,2,4-Trichlorobenzene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 09/15/23 15:08 V37960TBL
<0.002 mg/Kg - dry 0.002 0.012Trichlorofluoromethane 1 09/15/23 15:08 V37960TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 09/15/23 15:08 V37960TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37959 09/15/23 08:00
<0.0007 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Acetate 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Chloride 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006o-Xylene 1 09/15/23 15:08 V37960TBL
<0.001 mg/Kg - dry 0.001 0.012m,p-Xylene 1 09/15/23 15:08 V37960TBL
<0.0006 mg/Kg - dry 0.0006 0.006Xylene (Total)1 09/15/23 15:08 V37960
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%09/15/23 15:081 TBL V37960
Surrogate: Dibromofluoromethane 105 Limits: 84-123%09/15/23 15:081 TBL V37960
Surrogate: Toluene-d8 94.1 Limits: 76-129%09/15/23 15:081 TBL V37960
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.592 mg/Kg - dry 0.592 3.37Acenaphthene 4 09/20/23 22:28 V38117AMP
<0.536 mg/Kg - dry 0.536 3.37Acenaphthylene 4 09/20/23 22:28 V38117AMP
<0.776 mg/Kg - dry 0.776 3.37Aniline 4 09/20/23 22:28 V38117AMP
<0.730 mg/Kg - dry 0.730 3.37Anthracene 4 09/20/23 22:28 V38117AMP
<0.710 mg/Kg - dry 0.710 3.37Benzo(a)anthracene 4 09/20/23 22:28 V38117AMP
<0.750 mg/Kg - dry 0.750 3.37
Benzo(a)pyrene 4 09/20/23 22:28 V38117AMP
<0.745 mg/Kg - dry 0.745 3.37Benzo(b)fluoranthene 4 09/20/23 22:28 V38117AMP
<0.694 mg/Kg - dry 0.694 3.37Benzo(g,h,i)perylene 4 09/20/23 22:28 V38117AMP
<0.699 mg/Kg - dry 0.699 3.37Benzo(k)fluoranthene 4 09/20/23 22:28 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<2.96 mg/Kg - dry 2.96 10.2Benzoic Acid 4 09/20/23 22:28 V38117AMP
<0.536 mg/Kg - dry 0.536 3.37Benzyl alcohol 4 09/20/23 22:28 V38117AMP
<0.602 mg/Kg - dry 0.602 3.37Bis(2-Chloroethoxy)methane 4 09/20/23 22:28 V38117AMP
<0.546 mg/Kg - dry 0.546 3.37Bis(2-Chloroethyl)ether 4 09/20/23 22:28 V38117AMP
<0.694 mg/Kg - dry 0.694 1.69Bis(2-Chloroisopropyl)ether 4 09/20/23 22:28 V38117AMP
<0.613 mg/Kg - dry 0.613 3.37Bis(2-ethylhexyl)phthalate 4 09/20/23 22:28 V38117AMP
<0.556 mg/Kg - dry 0.556 3.374-Bromophenyl phenyl ether 4 09/20/23 22:28 V38117AMP
<0.577 mg/Kg - dry 0.577 1.69Butyl benzyl phthalate 4 09/20/23 22:28 V38117AMP
<0.472 mg/Kg - dry 0.472 3.37
4-Chloro-3-methylphenol 4 09/20/23 22:28 V38117AMP
<0.572 mg/Kg - dry 0.572 1.694-Chloroaniline 4 09/20/23 22:28 V38117AMP
<0.592 mg/Kg - dry 0.592 3.372-Chloronaphthalene 4 09/20/23 22:28 V38117AMP
<0.501 mg/Kg - dry 0.501 3.372-Chlorophenol 4 09/20/23 22:28 V38117AMP
<0.643 mg/Kg - dry 0.643 5.114-Chlorophenyl phenyl ether 4 09/20/23 22:28 V38117AMP
<0.725 mg/Kg - dry 0.725 3.37Chrysene 4 09/20/23 22:28 V38117AMP
<1.17 mg/Kg - dry 1.17 3.37Dibenz(a,h)anthracene 4 09/20/23 22:28 V38117AMP
<0.607 mg/Kg - dry 0.607 3.37
Dibenzofuran 4 09/20/23 22:28 V38117AMP
<0.482 mg/Kg - dry 0.482 3.371,2-Dichlorobenzene 4 09/20/23 22:28 V38117AMP
<0.496 mg/Kg - dry 0.496 3.371,3-Dichlorobenzene 4 09/20/23 22:28 V38117AMP
<0.498 mg/Kg - dry 0.498 1.691,4-Dichlorobenzene 4 09/20/23 22:28 V38117AMP
<0.750 mg/Kg - dry 0.750 3.373,3'-Dichlorobenzidine 4 09/20/23 22:28 V38117AMP
<0.489 mg/Kg - dry 0.489 3.372,4-Dichlorophenol 4 09/20/23 22:28 V38117AMP
<0.919 mg/Kg - dry 0.919 3.37Diethyl phthalate 4 09/20/23 22:28 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.888 mg/Kg - dry 0.888 3.37Dimethyl phthalate 4 09/20/23 22:28 V38117AMP
<0.551 mg/Kg - dry 0.551 1.692,4-Dimethylphenol 4 09/20/23 22:28 V38117AMP
<0.546 mg/Kg - dry 0.546 3.37Di-n-butyl phthalate 4 09/20/23 22:28 V38117AMP
<1.23 mg/Kg - dry 1.23 7.664,6-Dinitro-2-methylphenol 4 09/20/23 22:28 V38117AMP
<2.66 mg/Kg - dry 2.66 7.662,4-Dinitrophenol 4 09/20/23 22:28 V38117AMP
<0.492 mg/Kg - dry 0.492 3.372,4-Dinitrotoluene 4 09/20/23 22:28 V38117AMP
<0.551 mg/Kg - dry 0.551 3.372,6-Dinitrotoluene 4 09/20/23 22:28 V38117AMP
<0.730 mg/Kg - dry 0.730 1.69Di-n-Octyl Phthalate 4 09/20/23 22:28 V38117AMP
<0.628 mg/Kg - dry 0.628 3.37
Fluoranthene 4 09/20/23 22:28 V38117AMP
<0.653 mg/Kg - dry 0.653 3.37Fluorene 4 09/20/23 22:28 V38117AMP
<0.541 mg/Kg - dry 0.541 3.37Hexachlorobenzene 4 09/20/23 22:28 V38117AMP
<0.498 mg/Kg - dry 0.498 3.37Hexachlorobutadiene 4 09/20/23 22:28 V38117AMP
<0.802 mg/Kg - dry 0.802 3.37Hexachlorocyclopentadiene 4 09/20/23 22:28 V38117AMP
<0.404 mg/Kg - dry 0.404 3.37Hexachloroethane 4 09/20/23 22:28 V38117AMP
<0.914 mg/Kg - dry 0.914 3.37Indeno(1,2,3-cd)pyrene 4 09/20/23 22:28 V38117AMP
<0.975 mg/Kg - dry 0.975 3.37
Isophorone 4 09/20/23 22:28 V38117AMP
<0.541 mg/Kg - dry 0.541 3.371-Methylnaphthalene 4 09/20/23 22:28 V38117AMP
<0.510 mg/Kg - dry 0.510 3.372-Methylnaphthalene 4 09/20/23 22:28 V38117AMP
<0.495 mg/Kg - dry 0.495 3.372-Methylphenol 4 09/20/23 22:28 V38117AMP
<0.434 mg/Kg - dry 0.434 3.373&4 Methylphenol 4 09/20/23 22:28 V38117AMP
<0.735 mg/Kg - dry 0.735 3.37Naphthalene 4 09/20/23 22:28 V38117AMP
<0.494 mg/Kg - dry 0.494 3.372-Nitroaniline 4 09/20/23 22:28 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.613 mg/Kg - dry 0.613 3.373-Nitroaniline 4 09/20/23 22:28 V38117AMP
<0.476 mg/Kg - dry 0.476 1.694-Nitroaniline 4 09/20/23 22:28 V38117AMP
<0.592 mg/Kg - dry 0.592 1.69Nitrobenzene 4 09/20/23 22:28 V38117AMP
<0.453 mg/Kg - dry 0.453 3.372-Nitrophenol 4 09/20/23 22:28 V38117AMP
<0.597 mg/Kg - dry 0.597 3.374-Nitrophenol 4 09/20/23 22:28 V38117AMP
<1.34 mg/Kg - dry 1.34 3.37N-Nitrosodimethylamine 4 09/20/23 22:28 V38117AMP
<0.924 mg/Kg - dry 0.924 3.37N-Nitrosodiphenylamine 4 09/20/23 22:28 V38117AMP
<0.602 mg/Kg - dry 0.602 3.37N-Nitroso-di-n-propylamine 4 09/20/23 22:28 V38117AMP
<1.78 mg/Kg - dry 1.78 5.11
Pentachlorophenol 4 09/20/23 22:28 V38117AMP
<1.06 mg/Kg - dry 1.06 3.37Phenanthrene 4 09/20/23 22:28 V38117AMP
<0.572 mg/Kg - dry 0.572 3.37Phenol 4 09/20/23 22:28 V38117AMP
<0.684 mg/Kg - dry 0.684 3.37Pyrene 4 09/20/23 22:28 V38117AMP
<0.404 mg/Kg - dry 0.404 1.69Pyridine 4 09/20/23 22:28 V38117AMP
<0.546 mg/Kg - dry 0.546 3.371,2,4-Trichlorobenzene 4 09/20/23 22:28 V38117AMP
<0.491 mg/Kg - dry 0.491 3.372,4,5-Trichlorophenol 4 09/20/23 22:28 V38117AMP
<0.492 mg/Kg - dry 0.492 3.37
2,4,6-Trichlorophenol 4 09/20/23 22:28 V38117AMP
8270ESurrogate: Phenol-d5 70.6 Limits: 34-121%09/20/23 22:284 AMP
Surrogate: 2-Fluorobiphenyl 85.6 Limits: 44-115%09/20/23 22:284 AMP V38117
Surrogate: 2-Fluorophenol 71.2 Limits: 35-115%09/20/23 22:284 AMP V38117
Surrogate: Nitrobenzene-d5 77.8 Limits: 37-122%09/20/23 22:284 AMP V38117
Surrogate: 4-Terphenyl-d14 91.6 Limits: 54-127%09/20/23 22:284 AMP V38117
Surrogate: 2,4,6-Tribromophenol 82.3 Limits: 39-132%09/20/23 22:284 AMP V38117
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95232 Matrix:
9/14/2023 10:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V37937 09/18/23 10:40
<11.7 mg/Kg - dry 11.7 63.7Aliphatic C9-C18 1 09/20/23 00:22 V38061AMP
17.4 J mg/Kg - dry 15.6 63.7Aliphatic C19-C36 1 09/20/23 00:22 V38061AMP
<18.1 mg/Kg - dry 18.1 63.7Aromatic C11-C22 1 09/20/23 00:22 V38061AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 82.5 Limits: 40-140%09/20/23 00:221 AMP
MADEP-EPHSurrogate: Chlorooctadecane 67.4 Limits: 40-140%09/20/23 00:221 AMP
MADEP-EPHSurrogate: OTP Surrogate 76.7 Limits: 40-140%09/20/23 00:221 AMP
Surrogate: 2-Fluorobiphenyl 84.2 Limits: 40-140%09/20/23 00:221 AMP V38061
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37913 09/15/23 08:00
<1.56 mg/Kg - dry 1.56 10.2
Aliphatic C5-C8 100 09/15/23 15:20 V37914TBL
<5.82 mg/Kg - dry 5.82 10.2Aliphatic C9-C12 100 09/15/23 15:20 V37914TBL
<0.796 mg/Kg - dry 0.796 10.2Aromatic C9-C10 100 09/15/23 15:20 V37914TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)107 Limits: 70-130%09/15/23 15:20100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)102 Limits: 70-130%09/15/23 15:20100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
19.9 %Moisture 1 09/18/23 16:10 SW-DRYWTCNC
28.8 mg/Kg - dry 1.06 3.12Chromium 5 09/19/23 15:22 6010DJKC
51.1 mg/Kg - dry 0.493 1.87Lead 5 09/19/23 15:22 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37992 09/15/23 08:00
<0.749 mg/Kg - dry 0.749 6.24Acetone 500 09/15/23 16:02 V37993TBL
<0.378 mg/Kg - dry 0.378 6.24Acrolein 500 09/15/23 16:02 V37993TBL
<0.234 mg/Kg - dry 0.234 6.24Acrylonitrile 500 09/15/23 16:02 V37993TBL
2.72 mg/Kg - dry 0.181 1.56Benzene 500 09/15/23 16:02 V37993TBL
<0.156 mg/Kg - dry 0.156 1.56Bromobenzene 500 09/15/23 16:02 V37993TBL
<0.249 mg/Kg - dry 0.249 1.56Bromochloromethane 500 09/15/23 16:02 V37993TBL
<0.372 mg/Kg - dry 0.372 1.56Bromodichloromethane 500 09/15/23 16:02 V37993TBL
<0.315 mg/Kg - dry 0.315 1.56Bromoform 500 09/15/23 16:02 V37993TBL
<0.568 mg/Kg - dry 0.568 3.12
Bromomethane 500 09/15/23 16:02 V37993TBL
6.04 mg/Kg - dry 0.153 1.56n-Butylbenzene 500 09/15/23 16:02 V37993TBL
3.03 mg/Kg - dry 0.174 1.56sec-Butyl benzene 500 09/15/23 16:02 V37993TBL
<0.156 mg/Kg - dry 0.156 1.56tert-Butyl benzene 500 09/15/23 16:02 V37993TBL
<0.199 mg/Kg - dry 0.199 1.56Carbon Disulfide 500 09/15/23 16:02 V37993TBL
<0.493 mg/Kg - dry 0.493 1.56Carbon Tetrachloride 500 09/15/23 16:02 V37993TBL
<0.209 mg/Kg - dry 0.209 1.56Chlorobenzene 500 09/15/23 16:02 V37993TBL
<0.278 mg/Kg - dry 0.278 1.56
Chlorodibromomethane 500 09/15/23 16:02 V37993TBL
<0.278 mg/Kg - dry 0.278 3.12Chloroethane 500 09/15/23 16:02 V37993TBL
<0.328 mg/Kg - dry 0.328 1.56Chloroform 500 09/15/23 16:02 V37993TBL
<0.197 mg/Kg - dry 0.197 3.12Chloromethane 500 09/15/23 16:02 V37993TBL
<0.159 mg/Kg - dry 0.159 1.562-Chlorotoluene 500 09/15/23 16:02 V37993TBL
<0.121 mg/Kg - dry 0.121 1.564-Chlorotoluene 500 09/15/23 16:02 V37993TBL
<0.228 mg/Kg - dry 0.228 1.56Di-Isopropyl Ether (DIPE)500 09/15/23 16:02 V37993TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37992 09/15/23 08:00
<0.137 mg/Kg - dry 0.137 3.121,2-Dibromo-3-Chloropropane 500 09/15/23 16:02 V37993TBL
<0.184 mg/Kg - dry 0.184 1.561,2-Dibromoethane 500 09/15/23 16:02 V37993TBL
<0.309 mg/Kg - dry 0.309 1.56Dibromomethane 500 09/15/23 16:02 V37993TBL
<0.096 mg/Kg - dry 0.096 1.561,2-Dichlorobenzene 500 09/15/23 16:02 V37993TBL
<0.118 mg/Kg - dry 0.118 1.561,3-Dichlorobenzene 500 09/15/23 16:02 V37993TBL
<0.187 mg/Kg - dry 0.187 1.561,4-Dichlorobenzene 500 09/15/23 16:02 V37993TBL
<0.411 mg/Kg - dry 0.411 3.12Dichlorodifluoromethane 500 09/15/23 16:02 V37993TBL
<0.255 mg/Kg - dry 0.255 1.561,1-Dichloroethane 500 09/15/23 16:02 V37993TBL
<0.430 mg/Kg - dry 0.430 1.56
1,2-Dichloroethane 500 09/15/23 16:02 V37993TBL
<0.228 mg/Kg - dry 0.228 1.561,1-Dichloroethene 500 09/15/23 16:02 V37993TBL
<0.247 mg/Kg - dry 0.247 1.56cis-1,2-Dichloroethene 500 09/15/23 16:02 V37993TBL
<0.328 mg/Kg - dry 0.328 1.56trans-1,2-Dichloroethene 500 09/15/23 16:02 V37993TBL
<0.137 mg/Kg - dry 0.137 1.561,2-Dichloropropane 500 09/15/23 16:02 V37993TBL
<0.172 mg/Kg - dry 0.172 1.561,3-Dichloropropane 500 09/15/23 16:02 V37993TBL
<0.397 mg/Kg - dry 0.397 1.562,2-Dichloropropane 500 09/15/23 16:02 V37993TBL
<0.237 mg/Kg - dry 0.237 1.56
1,1-Dichloropropene 500 09/15/23 16:02 V37993TBL
<0.168 mg/Kg - dry 0.168 1.56cis-1,3-Dichloropropene 500 09/15/23 16:02 V37993TBL
<0.249 mg/Kg - dry 0.249 1.56trans-1,3-Dichloropropene 500 09/15/23 16:02 V37993TBL
51.2 mg/Kg - dry 0.181 1.56Ethylbenzene 500 09/15/23 16:02 V37993TBL
<0.259 mg/Kg - dry 0.259 31.2Ethyl Tertiary Butyl Ether (ETBE)500 09/15/23 16:02 V37993TBL
<0.247 mg/Kg - dry 0.247 3.12Hexachlorobutadiene 500 09/15/23 16:02 V37993TBL
11.1 mg/Kg - dry 0.205 3.12n-Hexane 500 09/15/23 16:02 V37993TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37992 09/15/23 08:00
<0.193 mg/Kg - dry 0.193 6.242-Hexanone 500 09/15/23 16:02 V37993TBL
7.69 mg/Kg - dry 0.143 1.56Isopropylbenzene 500 09/15/23 16:02 V37993TBL
2.18 mg/Kg - dry 0.405 1.564-Isopropyl toluene 500 09/15/23 16:02 V37993TBL
<0.203 mg/Kg - dry 0.203 6.24Methyl Ethyl Ketone (MEK)500 09/15/23 16:02 V37993TBL
<0.193 mg/Kg - dry 0.193 1.56Methyl tert-butyl ether (MTBE)500 09/15/23 16:02 V37993TBL
<4.68 mg/Kg - dry 4.68 6.244-Methyl-2-Pentanone 500 09/15/23 16:02 V37993TBL
<0.459 mg/Kg - dry 0.459 1.56Methylene Chloride 500 09/15/23 16:02 V37993TBL
22.0 mg/Kg - dry 0.309 3.12Naphthalene 500 09/15/23 16:02 V37993TBL
27.1 mg/Kg - dry 0.168 1.56
n-Propylbenzene 500 09/15/23 16:02 V37993TBL
0.523 J mg/Kg - dry 0.443 1.56Styrene 500 09/15/23 16:02 V37993TBL
<0.328 mg/Kg - dry 0.328 1.561,1,1,2-Tetrachloroethane 500 09/15/23 16:02 V37993TBL
<0.099 mg/Kg - dry 0.099 1.561,1,2,2-Tetrachloroethane 500 09/15/23 16:02 V37993TBL
<0.280 mg/Kg - dry 0.280 1.56Tetrachloroethene 500 09/15/23 16:02 V37993TBL
87.1 mg/Kg - dry 0.205 1.56Toluene 500 09/15/23 16:02 V37993TBL
<0.168 mg/Kg - dry 0.168 3.121,2,3-Trichlorobenzene 500 09/15/23 16:02 V37993TBL
<0.199 mg/Kg - dry 0.199 3.12
1,2,4-Trichlorobenzene 500 09/15/23 16:02 V37993TBL
<0.449 mg/Kg - dry 0.449 1.561,1,1-Trichloroethane 500 09/15/23 16:02 V37993TBL
<0.147 mg/Kg - dry 0.147 1.561,1,2-Trichloroethane 500 09/15/23 16:02 V37993TBL
<0.287 mg/Kg - dry 0.287 1.56Trichloroethene 500 09/15/23 16:02 V37993TBL
<0.652 mg/Kg - dry 0.652 3.12Trichlorofluoromethane 500 09/15/23 16:02 V37993TBL
<0.224 mg/Kg - dry 0.224 1.561,2,3-Trichloropropane 500 09/15/23 16:02 V37993TBL
186 mg/Kg - dry 1.54 15.61,2,4-Trimethylbenzene 5000 09/15/23 16:29 V37993TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V37992 09/15/23 08:00
55.4 mg/Kg - dry 0.168 1.561,3,5-Trimethylbenzene 500 09/15/23 16:02 V37993TBL
<0.143 mg/Kg - dry 0.143 3.12Vinyl Acetate 500 09/15/23 16:02 V37993TBL
<0.149 mg/Kg - dry 0.149 3.12Vinyl Chloride 500 09/15/23 16:02 V37993TBL
89.1 mg/Kg - dry 0.156 1.56o-Xylene 500 09/15/23 16:02 V37993TBL
212 mg/Kg - dry 0.393 3.12m,p-Xylene 500 09/15/23 16:02 V37993TBL
301 mg/Kg - dry 0.156 1.56Xylene (Total)500 09/15/23 16:02 V37993
Surrogate: 4-Bromofluorobenzene 99.1 Limits: 70-130%09/15/23 16:02500 TBL V37993
Surrogate: Dibromofluoromethane 101 Limits: 70-130%09/15/23 16:02500 TBL V37993
Surrogate: Toluene-d8 94.0 Limits: 76-129%09/15/23 16:02500 TBL V37993
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%09/15/23 16:295000 TBL V37993
Surrogate: Dibromofluoromethane 101 Limits: 70-130%09/15/23 16:295000 TBL V37993
Surrogate: Toluene-d8 93.2 Limits: 76-129%09/15/23 16:295000 TBL V37993
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.144 mg/Kg - dry 0.144 0.825Acenaphthene 1 09/20/23 18:14 V38117AMP
<0.131 mg/Kg - dry 0.131 0.825Acenaphthylene 1 09/20/23 18:14 V38117AMP
<0.189 mg/Kg - dry 0.189 0.825Aniline 1 09/20/23 18:14 V38117AMP
<0.178 mg/Kg - dry 0.178 0.825Anthracene 1 09/20/23 18:14 V38117AMP
<0.173 mg/Kg - dry 0.173 0.825Benzo(a)anthracene 1 09/20/23 18:14 V38117AMP
<0.183 mg/Kg - dry 0.183 0.825Benzo(a)pyrene 1 09/20/23 18:14 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.182 mg/Kg - dry 0.182 0.825Benzo(b)fluoranthene 1 09/20/23 18:14 V38117AMP
<0.169 mg/Kg - dry 0.169 0.825Benzo(g,h,i)perylene 1 09/20/23 18:14 V38117AMP
<0.171 mg/Kg - dry 0.171 0.825Benzo(k)fluoranthene 1 09/20/23 18:14 V38117AMP
<0.724 mg/Kg - dry 0.724 2.50Benzoic Acid 1 09/20/23 18:14 V38117AMP
<0.131 mg/Kg - dry 0.131 0.825Benzyl alcohol 1 09/20/23 18:14 V38117AMP
<0.147 mg/Kg - dry 0.147 0.825Bis(2-Chloroethoxy)methane 1 09/20/23 18:14 V38117AMP
<0.133 mg/Kg - dry 0.133 0.825Bis(2-Chloroethyl)ether 1 09/20/23 18:14 V38117AMP
<0.169 mg/Kg - dry 0.169 0.411Bis(2-Chloroisopropyl)ether 1 09/20/23 18:14 V38117AMP
<0.149 mg/Kg - dry 0.149 0.825
Bis(2-ethylhexyl)phthalate 1 09/20/23 18:14 V38117AMP
<0.136 mg/Kg - dry 0.136 0.8254-Bromophenyl phenyl ether 1 09/20/23 18:14 V38117AMP
<0.141 mg/Kg - dry 0.141 0.411Butyl benzyl phthalate 1 09/20/23 18:14 V38117AMP
<0.115 mg/Kg - dry 0.115 0.8254-Chloro-3-methylphenol 1 09/20/23 18:14 V38117AMP
<0.139 mg/Kg - dry 0.139 0.4114-Chloroaniline 1 09/20/23 18:14 V38117AMP
<0.144 mg/Kg - dry 0.144 0.8252-Chloronaphthalene 1 09/20/23 18:14 V38117AMP
<0.122 mg/Kg - dry 0.122 0.8252-Chlorophenol 1 09/20/23 18:14 V38117AMP
<0.157 mg/Kg - dry 0.157 1.25
4-Chlorophenyl phenyl ether 1 09/20/23 18:14 V38117AMP
<0.177 mg/Kg - dry 0.177 0.825Chrysene 1 09/20/23 18:14 V38117AMP
<0.287 mg/Kg - dry 0.287 0.825Dibenz(a,h)anthracene 1 09/20/23 18:14 V38117AMP
<0.148 mg/Kg - dry 0.148 0.825Dibenzofuran 1 09/20/23 18:14 V38117AMP
<0.117 mg/Kg - dry 0.117 0.8251,2-Dichlorobenzene 1 09/20/23 18:14 V38117AMP
<0.121 mg/Kg - dry 0.121 0.8251,3-Dichlorobenzene 1 09/20/23 18:14 V38117AMP
<0.121 mg/Kg - dry 0.121 0.4111,4-Dichlorobenzene 1 09/20/23 18:14 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.183 mg/Kg - dry 0.183 0.8253,3'-Dichlorobenzidine 1 09/20/23 18:14 V38117AMP
<0.119 mg/Kg - dry 0.119 0.8252,4-Dichlorophenol 1 09/20/23 18:14 V38117AMP
<0.224 mg/Kg - dry 0.224 0.825Diethyl phthalate 1 09/20/23 18:14 V38117AMP
<0.217 mg/Kg - dry 0.217 0.825Dimethyl phthalate 1 09/20/23 18:14 V38117AMP
<0.134 mg/Kg - dry 0.134 0.4112,4-Dimethylphenol 1 09/20/23 18:14 V38117AMP
<0.133 mg/Kg - dry 0.133 0.825Di-n-butyl phthalate 1 09/20/23 18:14 V38117AMP
<0.299 mg/Kg - dry 0.299 1.874,6-Dinitro-2-methylphenol 1 09/20/23 18:14 V38117AMP
<0.649 mg/Kg - dry 0.649 1.872,4-Dinitrophenol 1 09/20/23 18:14 V38117AMP
<0.120 mg/Kg - dry 0.120 0.825
2,4-Dinitrotoluene 1 09/20/23 18:14 V38117AMP
<0.134 mg/Kg - dry 0.134 0.8252,6-Dinitrotoluene 1 09/20/23 18:14 V38117AMP
<0.178 mg/Kg - dry 0.178 0.411Di-n-Octyl Phthalate 1 09/20/23 18:14 V38117AMP
<0.153 mg/Kg - dry 0.153 0.825Fluoranthene 1 09/20/23 18:14 V38117AMP
<0.159 mg/Kg - dry 0.159 0.825Fluorene 1 09/20/23 18:14 V38117AMP
<0.132 mg/Kg - dry 0.132 0.825Hexachlorobenzene 1 09/20/23 18:14 V38117AMP
<0.121 mg/Kg - dry 0.121 0.825Hexachlorobutadiene 1 09/20/23 18:14 V38117AMP
<0.196 mg/Kg - dry 0.196 0.825
Hexachlorocyclopentadiene 1 09/20/23 18:14 V38117AMP
<0.099 mg/Kg - dry 0.099 0.825Hexachloroethane 1 09/20/23 18:14 V38117AMP
<0.223 mg/Kg - dry 0.223 0.825Indeno(1,2,3-cd)pyrene 1 09/20/23 18:14 V38117AMP
<0.238 mg/Kg - dry 0.238 0.825Isophorone 1 09/20/23 18:14 V38117AMP
2.83 mg/Kg - dry 0.132 0.8251-Methylnaphthalene 1 09/20/23 18:14 V38117AMP
6.29 mg/Kg - dry 0.124 0.8252-Methylnaphthalene 1 09/20/23 18:14 V38117AMP
<0.121 mg/Kg - dry 0.121 0.8252-Methylphenol 1 09/20/23 18:14 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.106 mg/Kg - dry 0.106 0.8253&4 Methylphenol 1 09/20/23 18:14 V38117AMP
9.69 mg/Kg - dry 0.359 1.65Naphthalene 2 09/21/23 12:46 V38117AMP
<0.120 mg/Kg - dry 0.120 0.8252-Nitroaniline 1 09/20/23 18:14 V38117AMP
<0.149 mg/Kg - dry 0.149 0.8253-Nitroaniline 1 09/20/23 18:14 V38117AMP
<0.116 mg/Kg - dry 0.116 0.4114-Nitroaniline 1 09/20/23 18:14 V38117AMP
<0.144 mg/Kg - dry 0.144 0.411Nitrobenzene 1 09/20/23 18:14 V38117AMP
<0.110 mg/Kg - dry 0.110 0.8252-Nitrophenol 1 09/20/23 18:14 V38117AMP
<0.146 mg/Kg - dry 0.146 0.8254-Nitrophenol 1 09/20/23 18:14 V38117AMP
<0.328 mg/Kg - dry 0.328 0.825
N-Nitrosodimethylamine 1 09/20/23 18:14 V38117AMP
<0.225 mg/Kg - dry 0.225 0.825N-Nitrosodiphenylamine 1 09/20/23 18:14 V38117AMP
<0.147 mg/Kg - dry 0.147 0.825N-Nitroso-di-n-propylamine 1 09/20/23 18:14 V38117AMP
<0.433 mg/Kg - dry 0.433 1.25Pentachlorophenol 1 09/20/23 18:14 V38117AMP
<0.259 mg/Kg - dry 0.259 0.825Phenanthrene 1 09/20/23 18:14 V38117AMP
<0.139 mg/Kg - dry 0.139 0.825Phenol 1 09/20/23 18:14 V38117AMP
<0.167 mg/Kg - dry 0.167 0.825Pyrene 1 09/20/23 18:14 V38117AMP
<0.098 mg/Kg - dry 0.098 0.411
Pyridine 1 09/20/23 18:14 V38117AMP
<0.133 mg/Kg - dry 0.133 0.8251,2,4-Trichlorobenzene 1 09/20/23 18:14 V38117AMP
<0.120 mg/Kg - dry 0.120 0.8252,4,5-Trichlorophenol 1 09/20/23 18:14 V38117AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 33 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V38087 09/20/23 11:30
<0.120 mg/Kg - dry 0.120 0.8252,4,6-Trichlorophenol 1 09/20/23 18:14 V38117AMP
8270ESurrogate: Phenol-d5 68.0 Limits: 34-121%09/20/23 18:141 AMP
Surrogate: 2-Fluorobiphenyl 92.2 Limits: 44-115%09/20/23 18:141 AMP V38117
Surrogate: 2-Fluorophenol 72.5 Limits: 35-115%09/20/23 18:141 AMP V38117
Surrogate: Nitrobenzene-d5 88.0 Limits: 37-122%09/20/23 18:141 AMP V38117
Surrogate: 4-Terphenyl-d14 92.8 Limits: 54-127%09/20/23 18:141 AMP V38117
Surrogate: 2,4,6-Tribromophenol 95.5 Limits: 39-132%09/20/23 18:141 AMP V38117
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 34 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95233 Matrix:
9/14/2023 11:30
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V37937 09/18/23 10:40
325 mg/Kg - dry 11.5 62.7Aliphatic C9-C18 1 09/20/23 00:58 V38061AMP
<15.2 mg/Kg - dry 15.2 62.7Aliphatic C19-C36 1 09/20/23 00:58 V38061AMP
123 mg/Kg - dry 17.9 62.7Aromatic C11-C22 1 09/20/23 00:58 V38061AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 96.3 Limits: 40-140%09/20/23 00:581 AMP
MADEP-EPHSurrogate: Chlorooctadecane 65.8 Limits: 40-140%09/20/23 00:581 AMP
MADEP-EPHSurrogate: OTP Surrogate 90.8 Limits: 40-140%09/20/23 00:581 AMP
Surrogate: 2-Fluorobiphenyl 99.5 Limits: 40-140%09/20/23 00:581 AMP V38061
MADEP-EPHSurrogate: 2-Bromonaphthalene 72.9 Limits: 40-140%09/20/23 11:162 AMP
MADEP-EPHSurrogate: Chlorooctadecane 61.3 Limits: 40-140%09/20/23 11:162 AMP
MADEP-EPHSurrogate: OTP Surrogate 70.2 Limits: 40-140%09/20/23 11:162 AMP
Surrogate: 2-Fluorobiphenyl 75.4 Limits: 40-140%09/20/23 11:162 AMP V38061
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37913 09/15/23 08:00
589 mg/Kg - dry 7.59 49.9
Aliphatic C5-C8 500 09/15/23 16:07 V37914TBL
685 mg/Kg - dry 28.5 49.9Aliphatic C9-C12 500 09/15/23 16:07 V37914TBL
421 mg/Kg - dry 3.90 49.9Aromatic C9-C10 500 09/15/23 16:07 V37914TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)98.1 Limits: 70-130%09/15/23 16:07500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)103 Limits: 70-130%09/15/23 16:07500 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 35 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 09/21/23 15:58 6200BMSA
0.031 mg/L 0.002 0.005Chromium 1 09/20/23 15:32 6010DJKC
0.019 mg/L 0.002 0.006Lead 1 09/19/23 20:45 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 36 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
V38366 09/25/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/21/23 15:58 V38230MSA
11.0 µg/L 0.180 0.500Benzene 1 09/21/23 15:58 V38230MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/21/23 15:58 V38230MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/21/23 15:58 V38230MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/21/23 15:58 V38230MSA
<1.50 µg/L 1.50 5.00Bromoform 1 09/21/23 15:58 V38230MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 09/21/23 15:58 V38230MSA
10.2 µg/L 0.180 0.500n-Butylbenzene 1 09/21/23 15:58 V38230MSA
7.00 µg/L 0.200 0.500
sec-Butyl benzene 1 09/21/23 15:58 V38230MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/21/23 15:58 V38230MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/21/23 15:58 V38230MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/21/23 15:58 V38230MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/21/23 15:58 V38230MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 09/21/23 15:58 V38230MSA
<0.220 µg/L 0.220 0.500Chloroform 1 09/21/23 15:58 V38230MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 09/21/23 15:58 V38230MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/21/23 15:58 V38230MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/21/23 15:58 V38230MSA
0.851 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/21/23 15:58 V38230MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/21/23 15:58 V38230MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/21/23 15:58 V38230MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/21/23 15:58 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 37 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
V38366 09/25/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/21/23 15:58 V38230MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/21/23 15:58 V38230MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/21/23 15:58 V38230MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/21/23 15:58 V38230MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/21/23 15:58 V38230MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/21/23 15:58 V38230MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/21/23 15:58 V38230MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/21/23 15:58 V38230MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 09/21/23 15:58 V38230MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/21/23 15:58 V38230MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/21/23 15:58 V38230MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/21/23 15:58 V38230MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/21/23 15:58 V38230MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/21/23 15:58 V38230MSA
<42.0 µg/L 42.0 200Ethanol 1 09/21/23 15:58 V38230MSA
393 µg/L 1.70 5.00
Ethylbenzene 10 09/22/23 19:14 V38305MSA
<0.059 µg/L 0.059 10.0Ethyl Tertiary Butyl Ether (ETBE)1 09/21/23 15:58 V38230MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/21/23 15:58 V38230MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 09/21/23 15:58 V38230MSA
50.2 µg/L 0.180 0.500Isopropylbenzene 1 09/21/23 15:58 V38230MSA
3.14 µg/L 0.089 0.5004-Isopropyl toluene 1 09/21/23 15:58 V38230MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/21/23 15:58 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 38 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
V38366 09/25/23 09:00
140 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 09/22/23 19:14 V38305MSA
4.36 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/21/23 15:58 V38230MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/21/23 15:58 V38230MSA
167 µg/L 4.70 10.0Naphthalene 10 09/22/23 19:14 V38305MSA
86.8 µg/L 0.190 0.500n-Propylbenzene 1 09/21/23 15:58 V38230MSA
<0.220 µg/L 0.220 0.500Styrene 1 09/21/23 15:58 V38230MSA
41.8 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 09/21/23 15:58 V38230MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 09/21/23 15:58 V38230MSA
7.68 J
µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 09/21/23 15:58 V38230MSA
0.669 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 09/21/23 15:58 V38230MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/21/23 15:58 V38230MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/21/23 15:58 V38230MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/21/23 15:58 V38230MSA
72.2 µg/L 0.220 0.500Toluene 1 09/21/23 15:58 V38230MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/21/23 15:58 V38230MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 09/21/23 15:58 V38230MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/21/23 15:58 V38230MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/21/23 15:58 V38230MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/21/23 15:58 V38230MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/21/23 15:58 V38230MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/21/23 15:58 V38230MSA
863 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 09/22/23 19:14 V38305MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 39 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
V38366 09/25/23 09:00
98.4 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/21/23 15:58 V38230MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/21/23 15:58 V38230MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/21/23 15:58 V38230MSA
866 µg/L 2.10 5.00o-Xylene 10 09/22/23 19:14 V38305MSA
1980 µg/L 42.0 100m,p-Xylene 100 09/25/23 22:42 V38367MSA
2850 µg/L 2.10 5.00Xylene (Total)10 09/22/23 19:14 V38367
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%09/21/23 15:581 MSA V38230
Surrogate: Dibromofluoromethane 100 Limits: 70-130%09/21/23 15:581 MSA V38230
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%09/21/23 15:581 MSA V38230
Surrogate: Toluene-d8 98.0 Limits: 70-130%09/21/23 15:581 MSA V38230
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%09/22/23 19:1410 MSA V38305
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%09/22/23 19:1410 MSA V38305
Surrogate: 1,2-Dichloroethane - d4 95.8 Limits: 70-130%09/22/23 19:1410 MSA V38305
Surrogate: Toluene-d8 98.4 Limits: 70-130%09/22/23 19:1410 MSA V38305
Surrogate: 4-Bromofluorobenzene 94.6 Limits: 70-130%09/25/23 22:42100 MSA V38367
Surrogate: Dibromofluoromethane 103 Limits: 70-130%09/25/23 22:42100 MSA V38367
Surrogate: 1,2-Dichloroethane - d4 106 Limits: 70-130%09/25/23 22:42100 V38367
Surrogate: Toluene-d8 97.2 Limits: 70-130%09/25/23 22:42100 MSA V38367
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 40 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/18/23 21:09 V37986AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/18/23 21:09 V37986AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/18/23 21:09 V37986AMP
<1.32 µg/L 1.32 10.0Benzidine 1 09/18/23 21:09 V37986AMP
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/18/23 21:09 V37986AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/18/23 21:09 V37986AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/18/23 21:09 V37986AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/18/23 21:09 V37986AMP
<1.99 µg/L 1.99 5.00
Benzo(k)fluoranthene 1 09/18/23 21:09 V37986AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/18/23 21:09 V37986AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/18/23 21:09 V37986AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/18/23 21:09 V37986AMP
<1.04 µg/L 1.04 5.00Bis(2-Chloroethyl)ether 1 09/18/23 21:09 V37986AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/18/23 21:09 V37986AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/18/23 21:09 V37986AMP
<1.11 µg/L 1.11 5.00
4-Bromophenyl phenyl ether 1 09/18/23 21:09 V37986AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/18/23 21:09 V37986AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/18/23 21:09 V37986AMP
<7.38 M µg/L 7.38 20.02-Chloronaphthalene 1 09/18/23 21:09 V37986AMP
<0.938 µg/L 0.938 10.02-Chlorophenol 1 09/18/23 21:09 V37986AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/18/23 21:09 V37986AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/18/23 21:09 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 41 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/18/23 21:09 V37986AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/18/23 21:09 V37986AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/18/23 21:09 V37986AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/18/23 21:09 V37986AMP
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/18/23 21:09 V37986AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/18/23 21:09 V37986AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/18/23 21:09 V37986AMP
39.3 µg/L 0.745 5.00Diethyl phthalate 1 09/18/23 21:09 V37986AMP
<0.939 µg/L 0.939 5.00
Dimethyl phthalate 1 09/18/23 21:09 V37986AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/18/23 21:09 V37986AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/18/23 21:09 V37986AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/18/23 21:09 V37986AMP
<1.92 µg/L 1.92 10.02,4-Dinitrophenol 1 09/18/23 21:09 V37986AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/18/23 21:09 V37986AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/18/23 21:09 V37986AMP
<1.65 µg/L 1.65 5.00
Di-n-Octyl Phthalate 1 09/18/23 21:09 V37986AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/18/23 21:09 V37986AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/18/23 21:09 V37986AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/18/23 21:09 V37986AMP
<2.73 µg/L 2.73 5.00Hexachlorobutadiene 1 09/18/23 21:09 V37986AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/18/23 21:09 V37986AMP
<1.76 M µg/L 1.76 5.00Hexachloroethane 1 09/18/23 21:09 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 42 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/18/23 21:09 V37986AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/18/23 21:09 V37986AMP
9.55 µg/L 1.14 2.001-Methylnaphthalene 1 09/18/23 21:09 V37986AMP
19.5 µg/L 0.666 2.002-Methylnaphthalene 1 09/18/23 21:09 V37986AMP
76.7 µg/L 0.728 2.00Naphthalene 1 09/18/23 21:09 V37986AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/18/23 21:09 V37986AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/18/23 21:09 V37986AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/18/23 21:09 V37986AMP
<1.10 µg/L 1.10 5.00
N-Nitrosodiphenylamine 1 09/18/23 21:09 V37986AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/18/23 21:09 V37986AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/18/23 21:09 V37986AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/18/23 21:09 V37986AMP
<0.651 µg/L 0.651 5.00Phenol 1 09/18/23 21:09 V37986AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/18/23 21:09 V37986AMP
<2.21 M µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/18/23 21:09 V37986AMP
<1.32 µg/L 1.32 5.00
2,4,6-Trichlorophenol 1 09/18/23 21:09 V37986AMP
625.1Surrogate: Phenol-d5 22.8 Limits: 10-63%09/18/23 21:091 AMP
Surrogate: 2-Fluorobiphenyl 65.2 Limits: 49-118%09/18/23 21:091 AMP V37986
Surrogate: 2-Fluorophenol 33.9 Limits: 22-84%09/18/23 21:091 AMP V37986
Surrogate: Nitrobenzene-d5 61.4 Limits: 43-123%09/18/23 21:091 AMP V37986
Surrogate: 4-Terphenyl-d14 82.6 Limits: 49-151%09/18/23 21:091 AMP V37986
Surrogate: 2,4,6-Tribromophenol 72.7 Limits: 31-144%09/18/23 21:091 AMP V37986
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 43 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V38133 09/21/23 12:31
0.173 µg/L 0.00347 0.02101,2-Dibromoethane 1 09/21/23 14:51 V38177TJW
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 44 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-2
95234 Matrix:
9/14/2023 11:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V38005 09/19/23 10:16
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 09/19/23 20:08 V38062AMP
<124 µg/L 124 500Aliphatic C19-C36 1 09/19/23 20:08 V38062AMP
614 µg/L 61.2 250Aromatic C11-C22 1 09/19/23 20:08 V38062AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 91.0 Limits: 40-140%09/19/23 20:081 AMP
MADEP-EPHSurrogate: Chlorooctadecane 64.6 Limits: 40-140%09/19/23 20:081 AMP
MADEP-EPHSurrogate: OTP Surrogate 71.3 Limits: 40-140%09/19/23 20:081 AMP
Surrogate: 2-Fluorobiphenyl 82.8 Limits: 40-140%09/19/23 20:081 AMP V38062
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37915 09/15/23 08:00
740 µg/L 115 500
Aliphatic C5-C8 10 09/15/23 20:03 V37916TBL
6020 µg/L 258 500Aliphatic C9-C12 10 09/15/23 20:03 V37916TBL
1740 µg/L 40.2 500Aromatic C9-C10 10 09/15/23 20:03 V37916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)90.6 Limits: 70-130%09/15/23 20:0310 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)86.7 Limits: 70-130%09/15/23 20:0310 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 45 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100 10003,3-Dimethyl-1-butanol 100 09/21/23 21:20 6200BMSA
0.093 mg/L 0.002 0.005Chromium 1 09/20/23 15:36 6010DJKC
0.065 mg/L 0.002 0.006Lead 1 09/19/23 20:49 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 46 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
892 J µg/L 180 1000Acetone 100 09/21/23 21:20 V38230MSA
10900 µg/L 180 500Benzene 1000 09/22/23 21:50 V38305MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 09/21/23 21:20 V38230MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 09/21/23 21:20 V38230MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 09/21/23 21:20 V38230MSA
<150 µg/L 150 500Bromoform 100 09/21/23 21:20 V38230MSA
<28.0 µg/L 28.0 100Bromomethane 100 09/21/23 21:20 V38230MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 09/21/23 21:20 V38230MSA
<20.0 µg/L 20.0 50.0
sec-Butyl benzene 100 09/21/23 21:20 V38230MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 09/21/23 21:20 V38230MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 09/21/23 21:20 V38230MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 09/21/23 21:20 V38230MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 09/21/23 21:20 V38230MSA
<43.0 µg/L 43.0 100Chloroethane 100 09/21/23 21:20 V38230MSA
<22.0 µg/L 22.0 50.0Chloroform 100 09/21/23 21:20 V38230MSA
<22.0 µg/L 22.0 50.0
Chloromethane 100 09/21/23 21:20 V38230MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 09/21/23 21:20 V38230MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 09/21/23 21:20 V38230MSA
1080 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 09/21/23 21:20 V38230MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 09/21/23 21:20 V38230MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 09/21/23 21:20 V38230MSA
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 09/21/23 21:20 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 47 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 09/21/23 21:20 V38230MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 09/21/23 21:20 V38230MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 09/21/23 21:20 V38230MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 09/21/23 21:20 V38230MSA
229 µg/L 15.0 50.01,2-Dichloroethane 100 09/21/23 21:20 V38230MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 09/21/23 21:20 V38230MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 09/21/23 21:20 V38230MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 09/21/23 21:20 V38230MSA
<19.0 µg/L 19.0 50.0
1,2-Dichloropropane 100 09/21/23 21:20 V38230MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 09/21/23 21:20 V38230MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 09/21/23 21:20 V38230MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 09/21/23 21:20 V38230MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 09/21/23 21:20 V38230MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 09/21/23 21:20 V38230MSA
<4200 µg/L 4200 20000Ethanol 100 09/21/23 21:20 V38230MSA
3010 µg/L 17.0 50.0
Ethylbenzene 100 09/21/23 21:20 V38230MSA
<5.90 µg/L 5.90 1000Ethyl Tertiary Butyl Ether (ETBE)100 09/21/23 21:20 V38230MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 09/21/23 21:20 V38230MSA
882 µg/L 38.0 1002-Hexanone 100 09/21/23 21:20 V38230MSA
85.9 µg/L 18.0 50.0Isopropylbenzene 100 09/21/23 21:20 V38230MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 09/21/23 21:20 V38230MSA
771 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 09/21/23 21:20 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 48 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
304 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 09/21/23 21:20 V38230MSA
452 µg/L 7.80 1004-Methyl-2-Pentanone 100 09/21/23 21:20 V38230MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 09/21/23 21:20 V38230MSA
736 µg/L 47.0 100Naphthalene 100 09/21/23 21:20 V38230MSA
235 µg/L 19.0 50.0n-Propylbenzene 100 09/21/23 21:20 V38230MSA
<22.0 µg/L 22.0 50.0Styrene 100 09/21/23 21:20 V38230MSA
925 J µg/L 160 1000tert-Butyl Alcohol (TBA)100 09/21/23 21:20 V38230MSA
<35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 09/21/23 21:20 V38230MSA
3320 µg/L 190 1000
tert-Amyl Alcohol (TAA)100 09/21/23 21:20 V38230MSA
<28.0 µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 09/21/23 21:20 V38230MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 09/21/23 21:20 V38230MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 09/21/23 21:20 V38230MSA
<22.0 µg/L 22.0 50.0Tetrachloroethene 100 09/21/23 21:20 V38230MSA
41000 µg/L 220 500Toluene 1000 09/22/23 21:50 V38305MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 09/21/23 21:20 V38230MSA
<31.0 µg/L 31.0 50.0
1,2,4-Trichlorobenzene 100 09/21/23 21:20 V38230MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 09/21/23 21:20 V38230MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 09/21/23 21:20 V38230MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 09/21/23 21:20 V38230MSA
<18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 09/21/23 21:20 V38230MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 09/21/23 21:20 V38230MSA
2040 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 09/21/23 21:20 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 49 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
508 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 09/21/23 21:20 V38230MSA
<100 µg/L 100 500Vinyl Acetate 100 09/21/23 21:20 V38230MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 09/21/23 21:20 V38230MSA
5740 µg/L 21.0 50.0o-Xylene 100 09/21/23 21:20 V38230MSA
12200 µg/L 42.0 100m,p-Xylene 100 09/21/23 21:20 V38230MSA
17900 µg/L 21.0 50.0Xylene (Total)100 09/21/23 21:20 V38230
Surrogate: 4-Bromofluorobenzene 99.2 Limits: 70-130%09/21/23 21:20100 MSA V38230
Surrogate: Dibromofluoromethane 102 Limits: 70-130%09/21/23 21:20100 MSA V38230
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%09/21/23 21:20100 MSA V38230
Surrogate: Toluene-d8 102 Limits: 70-130%09/21/23 21:20100 MSA V38230
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%09/22/23 21:501000 MSA V38305
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%09/22/23 21:501000 MSA V38305
Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 70-130%09/22/23 21:501000 MSA V38305
Surrogate: Toluene-d8 100 Limits: 70-130%09/22/23 21:501000 MSA V38305
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/18/23 21:32 V37986AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/18/23 21:32 V37986AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/18/23 21:32 V37986AMP
<1.32 µg/L 1.32 10.0Benzidine 1 09/18/23 21:32 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 50 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/18/23 21:32 V37986AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/18/23 21:32 V37986AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/18/23 21:32 V37986AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/18/23 21:32 V37986AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/18/23 21:32 V37986AMP
38.2 µg/L 1.10 10.0Benzoic Acid 1 09/18/23 21:32 V37986AMP
<0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/18/23 21:32 V37986AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/18/23 21:32 V37986AMP
<1.04 µg/L 1.04 5.00
Bis(2-Chloroethyl)ether 1 09/18/23 21:32 V37986AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/18/23 21:32 V37986AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/18/23 21:32 V37986AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/18/23 21:32 V37986AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/18/23 21:32 V37986AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/18/23 21:32 V37986AMP
<7.38 M µg/L 7.38 20.02-Chloronaphthalene 1 09/18/23 21:32 V37986AMP
<0.938 µg/L 0.938 10.0
2-Chlorophenol 1 09/18/23 21:32 V37986AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/18/23 21:32 V37986AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/18/23 21:32 V37986AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/18/23 21:32 V37986AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/18/23 21:32 V37986AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/18/23 21:32 V37986AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/18/23 21:32 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 51 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/18/23 21:32 V37986AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/18/23 21:32 V37986AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/18/23 21:32 V37986AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/18/23 21:32 V37986AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/18/23 21:32 V37986AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/18/23 21:32 V37986AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/18/23 21:32 V37986AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/18/23 21:32 V37986AMP
<1.92 µg/L 1.92 10.0
2,4-Dinitrophenol 1 09/18/23 21:32 V37986AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/18/23 21:32 V37986AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/18/23 21:32 V37986AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/18/23 21:32 V37986AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/18/23 21:32 V37986AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/18/23 21:32 V37986AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/18/23 21:32 V37986AMP
<2.73 µg/L 2.73 5.00
Hexachlorobutadiene 1 09/18/23 21:32 V37986AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/18/23 21:32 V37986AMP
<1.76 M µg/L 1.76 5.00Hexachloroethane 1 09/18/23 21:32 V37986AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/18/23 21:32 V37986AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/18/23 21:32 V37986AMP
18.6 µg/L 1.14 2.001-Methylnaphthalene 1 09/18/23 21:32 V37986AMP
37.9 µg/L 0.666 2.002-Methylnaphthalene 1 09/18/23 21:32 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 52 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
170 µg/L 0.728 2.00Naphthalene 1 09/18/23 21:32 V37986AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/18/23 21:32 V37986AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/18/23 21:32 V37986AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/18/23 21:32 V37986AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/18/23 21:32 V37986AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/18/23 21:32 V37986AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/18/23 21:32 V37986AMP
1.03 J µg/L 0.428 2.00Phenanthrene 1 09/18/23 21:32 V37986AMP
<0.651 µg/L 0.651 5.00
Phenol 1 09/18/23 21:32 V37986AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/18/23 21:32 V37986AMP
<2.21 M µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/18/23 21:32 V37986AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/18/23 21:32 V37986AMP
625.1Surrogate: Phenol-d5 27.2 Limits: 10-63%09/18/23 21:321 AMP
Surrogate: 2-Fluorobiphenyl 67.0 Limits: 49-118%09/18/23 21:321 AMP V37986
Surrogate: 2-Fluorophenol 26.3 Limits: 22-84%09/18/23 21:321 AMP V37986
Surrogate: Nitrobenzene-d5 63.6 Limits: 43-123%09/18/23 21:321 AMP V37986
Surrogate: 4-Terphenyl-d14 83.8 Limits: 49-151%09/18/23 21:321 AMP V37986
Surrogate: 2,4,6-Tribromophenol 76.6 Limits: 31-144%09/18/23 21:321 AMP V37986
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 53 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V38133 09/21/23 12:31
108 µg/L 0.685 4.151,2-Dibromoethane 200 09/21/23 15:49 V38177TJW
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 54 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-3
95235 Matrix:
9/14/2023 12:55
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V38005 09/19/23 10:16
41.5 J µg/L 28.2 350Aliphatic C9-C18 1 09/19/23 20:44 V38062AMP
<124 µg/L 124 500Aliphatic C19-C36 1 09/19/23 20:44 V38062AMP
545 µg/L 61.2 250Aromatic C11-C22 1 09/19/23 20:44 V38062AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 92.5 Limits: 40-140%09/19/23 20:441 AMP
MADEP-EPHSurrogate: Chlorooctadecane 67.1 Limits: 40-140%09/19/23 20:441 AMP
MADEP-EPHSurrogate: OTP Surrogate 72.5 Limits: 40-140%09/19/23 20:441 AMP
Surrogate: 2-Fluorobiphenyl 90.3 Limits: 40-140%09/19/23 20:441 AMP V38062
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37915 09/15/23 08:00
80500 µg/L 1150 5000
Aliphatic C5-C8 100 09/15/23 21:37 V37916TBL
39700 µg/L 2580 5000Aliphatic C9-C12 100 09/15/23 21:37 V37916TBL
5450 µg/L 402 5000Aromatic C9-C10 100 09/15/23 21:37 V37916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.4 Limits: 70-130%09/15/23 21:37100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)87.1 Limits: 70-130%09/15/23 21:37100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 55 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100 10003,3-Dimethyl-1-butanol 100 09/21/23 21:45 6200BMSA
0.029 mg/L 0.002 0.005Chromium 1 09/20/23 15:41 6010DJKC
0.028 mg/L 0.002 0.006Lead 1 09/19/23 20:53 6010DJKC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 56 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
1720 µg/L 180 1000Acetone 100 09/21/23 21:45 V38230MSA
17900 µg/L 180 500Benzene 1000 09/22/23 22:16 V38305MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 09/21/23 21:45 V38230MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 09/21/23 21:45 V38230MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 09/21/23 21:45 V38230MSA
<150 µg/L 150 500Bromoform 100 09/21/23 21:45 V38230MSA
<28.0 µg/L 28.0 100Bromomethane 100 09/21/23 21:45 V38230MSA
20.4 J µg/L 18.0 50.0n-Butylbenzene 100 09/21/23 21:45 V38230MSA
25.9 J
µg/L 20.0 50.0
sec-Butyl benzene 100 09/21/23 21:45 V38230MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 09/21/23 21:45 V38230MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 09/21/23 21:45 V38230MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 09/21/23 21:45 V38230MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 09/21/23 21:45 V38230MSA
<43.0 µg/L 43.0 100Chloroethane 100 09/21/23 21:45 V38230MSA
<22.0 µg/L 22.0 50.0Chloroform 100 09/21/23 21:45 V38230MSA
<22.0 µg/L 22.0 50.0
Chloromethane 100 09/21/23 21:45 V38230MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 09/21/23 21:45 V38230MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 09/21/23 21:45 V38230MSA
6970 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 09/21/23 21:45 V38230MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 09/21/23 21:45 V38230MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 09/21/23 21:45 V38230MSA
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 09/21/23 21:45 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 57 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 09/21/23 21:45 V38230MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 09/21/23 21:45 V38230MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 09/21/23 21:45 V38230MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 09/21/23 21:45 V38230MSA
2150 µg/L 15.0 50.01,2-Dichloroethane 100 09/21/23 21:45 V38230MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 09/21/23 21:45 V38230MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 09/21/23 21:45 V38230MSA
<18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 09/21/23 21:45 V38230MSA
60.8 µg/L 19.0 50.0
1,2-Dichloropropane 100 09/21/23 21:45 V38230MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 09/21/23 21:45 V38230MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 09/21/23 21:45 V38230MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 09/21/23 21:45 V38230MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 09/21/23 21:45 V38230MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 09/21/23 21:45 V38230MSA
<4200 µg/L 4200 20000Ethanol 100 09/21/23 21:45 V38230MSA
1730 µg/L 17.0 50.0
Ethylbenzene 100 09/21/23 21:45 V38230MSA
<5.90 µg/L 5.90 1000Ethyl Tertiary Butyl Ether (ETBE)100 09/21/23 21:45 V38230MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 09/21/23 21:45 V38230MSA
372 µg/L 38.0 1002-Hexanone 100 09/21/23 21:45 V38230MSA
89.0 µg/L 18.0 50.0Isopropylbenzene 100 09/21/23 21:45 V38230MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 09/21/23 21:45 V38230MSA
1820 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 09/21/23 21:45 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 58 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
354 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 09/21/23 21:45 V38230MSA
223 µg/L 7.80 1004-Methyl-2-Pentanone 100 09/21/23 21:45 V38230MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 09/21/23 21:45 V38230MSA
838 µg/L 47.0 100Naphthalene 100 09/21/23 21:45 V38230MSA
200 µg/L 19.0 50.0n-Propylbenzene 100 09/21/23 21:45 V38230MSA
<22.0 µg/L 22.0 50.0Styrene 100 09/21/23 21:45 V38230MSA
648 J µg/L 160 1000tert-Butyl Alcohol (TBA)100 09/21/23 21:45 V38230MSA
<35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 09/21/23 21:45 V38230MSA
12800 µg/L 1900 10000
tert-Amyl Alcohol (TAA)1000 09/22/23 22:16 V38305MSA
<28.0 µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 09/21/23 21:45 V38230MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 09/21/23 21:45 V38230MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 09/21/23 21:45 V38230MSA
<22.0 µg/L 22.0 50.0Tetrachloroethene 100 09/21/23 21:45 V38230MSA
22900 µg/L 220 500Toluene 1000 09/22/23 22:16 V38305MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 09/21/23 21:45 V38230MSA
<31.0 µg/L 31.0 50.0
1,2,4-Trichlorobenzene 100 09/21/23 21:45 V38230MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 09/21/23 21:45 V38230MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 09/21/23 21:45 V38230MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 09/21/23 21:45 V38230MSA
<18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 09/21/23 21:45 V38230MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 09/21/23 21:45 V38230MSA
1670 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 09/21/23 21:45 V38230MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 59 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V38229 09/21/23 14:00 V38304 09/22/23 09:00
461 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 09/21/23 21:45 V38230MSA
<100 µg/L 100 500Vinyl Acetate 100 09/21/23 21:45 V38230MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 09/21/23 21:45 V38230MSA
2850 µg/L 21.0 50.0o-Xylene 100 09/21/23 21:45 V38230MSA
6710 µg/L 42.0 100m,p-Xylene 100 09/21/23 21:45 V38230MSA
9560 µg/L 21.0 50.0Xylene (Total)100 09/21/23 21:45 V38230
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%09/21/23 21:45100 MSA V38230
Surrogate: Dibromofluoromethane 102 Limits: 70-130%09/21/23 21:45100 MSA V38230
Surrogate: 1,2-Dichloroethane - d4 104 Limits: 70-130%09/21/23 21:45100 MSA V38230
Surrogate: Toluene-d8 102 Limits: 70-130%09/21/23 21:45100 MSA V38230
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%09/22/23 22:161000 MSA V38305
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%09/22/23 22:161000 MSA V38305
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%09/22/23 22:161000 MSA V38305
Surrogate: Toluene-d8 99.8 Limits: 70-130%09/22/23 22:161000 MSA V38305
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.302 µg/L 0.302 2.00Acenaphthene 1 09/18/23 21:55 V37986AMP
<0.297 µg/L 0.297 2.00Acenaphthylene 1 09/18/23 21:55 V37986AMP
<0.836 µg/L 0.836 2.00Anthracene 1 09/18/23 21:55 V37986AMP
<1.32 µg/L 1.32 10.0Benzidine 1 09/18/23 21:55 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 60 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/18/23 21:55 V37986AMP
<1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/18/23 21:55 V37986AMP
<2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/18/23 21:55 V37986AMP
<1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/18/23 21:55 V37986AMP
<1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/18/23 21:55 V37986AMP
<1.10 µg/L 1.10 10.0Benzoic Acid 1 09/18/23 21:55 V37986AMP
138 µg/L 0.684 5.00Benzyl alcohol 1 09/18/23 21:55 V37986AMP
<0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/18/23 21:55 V37986AMP
<1.04 µg/L 1.04 5.00
Bis(2-Chloroethyl)ether 1 09/18/23 21:55 V37986AMP
<1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/18/23 21:55 V37986AMP
<3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/18/23 21:55 V37986AMP
<1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/18/23 21:55 V37986AMP
<1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/18/23 21:55 V37986AMP
<1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/18/23 21:55 V37986AMP
<7.38 M µg/L 7.38 20.02-Chloronaphthalene 1 09/18/23 21:55 V37986AMP
<0.938 µg/L 0.938 10.0
2-Chlorophenol 1 09/18/23 21:55 V37986AMP
<1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/18/23 21:55 V37986AMP
<0.405 µg/L 0.405 2.00Chrysene 1 09/18/23 21:55 V37986AMP
<0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/18/23 21:55 V37986AMP
<0.856 µg/L 0.856 5.00Dibenzofuran 1 09/18/23 21:55 V37986AMP
<2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/18/23 21:55 V37986AMP
<2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/18/23 21:55 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 61 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
<2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/18/23 21:55 V37986AMP
<1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/18/23 21:55 V37986AMP
<1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/18/23 21:55 V37986AMP
<0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/18/23 21:55 V37986AMP
<0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/18/23 21:55 V37986AMP
<1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/18/23 21:55 V37986AMP
<2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/18/23 21:55 V37986AMP
<2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/18/23 21:55 V37986AMP
<1.92 µg/L 1.92 10.0
2,4-Dinitrophenol 1 09/18/23 21:55 V37986AMP
<1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/18/23 21:55 V37986AMP
<0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/18/23 21:55 V37986AMP
<1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/18/23 21:55 V37986AMP
<0.250 µg/L 0.250 2.00Fluoranthene 1 09/18/23 21:55 V37986AMP
<0.807 µg/L 0.807 2.00Fluorene 1 09/18/23 21:55 V37986AMP
<0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/18/23 21:55 V37986AMP
<2.73 µg/L 2.73 5.00
Hexachlorobutadiene 1 09/18/23 21:55 V37986AMP
<2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/18/23 21:55 V37986AMP
<1.76 M µg/L 1.76 5.00Hexachloroethane 1 09/18/23 21:55 V37986AMP
<0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/18/23 21:55 V37986AMP
<0.444 µg/L 0.444 5.00Isophorone 1 09/18/23 21:55 V37986AMP
48.6 µg/L 1.14 2.001-Methylnaphthalene 1 09/18/23 21:55 V37986AMP
72.9 µg/L 0.666 2.002-Methylnaphthalene 1 09/18/23 21:55 V37986AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 62 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V37964 09/18/23 10:59
171 µg/L 0.728 2.00Naphthalene 1 09/18/23 21:55 V37986AMP
<0.905 µg/L 0.905 5.00Nitrobenzene 1 09/18/23 21:55 V37986AMP
<0.493 µg/L 0.493 5.002-Nitrophenol 1 09/18/23 21:55 V37986AMP
<1.23 µg/L 1.23 10.04-Nitrophenol 1 09/18/23 21:55 V37986AMP
<1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/18/23 21:55 V37986AMP
<0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/18/23 21:55 V37986AMP
<1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/18/23 21:55 V37986AMP
<0.428 µg/L 0.428 2.00Phenanthrene 1 09/18/23 21:55 V37986AMP
<0.651 µg/L 0.651 5.00
Phenol 1 09/18/23 21:55 V37986AMP
<0.434 µg/L 0.434 2.00Pyrene 1 09/18/23 21:55 V37986AMP
<2.21 M µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/18/23 21:55 V37986AMP
<1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/18/23 21:55 V37986AMP
625.1Surrogate: Phenol-d5 31.0 Limits: 10-63%09/18/23 21:551 AMP
Surrogate: 2-Fluorobiphenyl 60.0 Limits: 49-118%09/18/23 21:551 AMP V37986
Surrogate: 2-Fluorophenol 34.1 Limits: 22-84%09/18/23 21:551 AMP V37986
Surrogate: Nitrobenzene-d5 70.4 Limits: 43-123%09/18/23 21:551 AMP V37986
Surrogate: 4-Terphenyl-d14 76.0 Limits: 49-151%09/18/23 21:551 AMP V37986
Surrogate: 2,4,6-Tribromophenol 69.0 Limits: 31-144%09/18/23 21:551 AMP V37986
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 63 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V38133 09/21/23 12:31
462 µg/L 1.73 10.51,2-Dibromoethane 500 09/21/23 16:09 V38177TJW
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 64 of 113
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28273
23-258-0006
00012
CES Group
3525 Whitehall Park Dr. Suite 150
Greg Hans
Charlotte
Received : 09/15/2023
Bullins Grocery
Report Date : 09/27/2023
Sample ID :
Lab No :
Sampled:MW-4
95236 Matrix:
9/14/2023 13:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V38005 09/19/23 10:16
59.4 J µg/L 28.2 350Aliphatic C9-C18 1 09/19/23 21:20 V38062AMP
<124 µg/L 124 500Aliphatic C19-C36 1 09/19/23 21:20 V38062AMP
871 µg/L 61.2 250Aromatic C11-C22 1 09/19/23 21:20 V38062AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 89.5 Limits: 40-140%09/19/23 21:201 AMP
MADEP-EPHSurrogate: Chlorooctadecane 57.4 Limits: 40-140%09/19/23 21:201 AMP
MADEP-EPHSurrogate: OTP Surrogate 65.4 Limits: 40-140%09/19/23 21:201 AMP
Surrogate: 2-Fluorobiphenyl 86.5 Limits: 40-140%09/19/23 21:201 AMP V38062
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V37915 09/15/23 08:00
68200 µg/L 1150 5000
Aliphatic C5-C8 100 09/15/23 20:50 V37916TBL
10800 µg/L 258 500Aliphatic C9-C12 10 09/15/23 20:27 V37916TBL
3490 µg/L 40.2 500Aromatic C9-C10 10 09/15/23 20:27 V37916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)86.7 Limits: 70-130%09/15/23 20:2710 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.5 Limits: 70-130%09/15/23 20:2710 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)85.0 Limits: 70-130%09/15/23 20:50100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)99.5 Limits: 70-130%09/15/23 20:50100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 65 of 113
Sample ID Report Lab NoLRB-V37964 23-258-0006 LRB
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
Hexadecanoic acid 14730 ug/L 1 625 9/18/2023 18:08 APANN V37986
Sample ID Report Lab No
MW-2 23-258-0006 95234
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
Ethylbenzene 210130 ug/L
1 625 9/18/2023 21:09 APANN V37986
Benzene, dimethyl-382780 ug/L
1 625 9/18/2023 21:09 APANN V37986
Benzene, propyl-47430 ug/L 1 625 9/18/2023 21:09 APANN V37986
Benzene, 1-ethyl-3-methyl-192870 ug/L 1 625 9/18/2023 21:09 APANN V37986
Benzene, 1-ethyl-2-methyl-86800 ug/L 1 625 9/18/2023 21:09 APANN V37986
Benzene, trimethyl-335600 ug/L 1 625 9/18/2023 21:09 APANN V37986
Indane 61380 ug/L
1 625 9/18/2023 21:09 APANN V37986
Benzene, iodo-dimethyl-99370 ug/L
1 625 9/18/2023 21:09 APANN V37986
Trimethyliodobenzene 51490 ug/L 1 625 9/18/2023 21:09 APANN V37986
Dimethylbenzyl chloride 48890 ug/L 1 625 9/18/2023 21:09 APANN V37986
Sample ID Report Lab No
MW-3 23-258-0006 95235
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
Benzene 188440 ug/L 1 625 9/18/2023 21:32 APANN V37986
Pentanone 195930 ug/L 1 625 9/18/2023 21:32 APANN V37986
Pentanol, methyl-253540 ug/L 1 625 9/18/2023 21:32 APANN V37986
Toluene 531690 ug/L
1 625 9/18/2023 21:32 APANN V37986
Ethylbenzene 264230 ug/L
1 625 9/18/2023 21:32 APANN V37986
Benzene, dimethyl-352440 ug/L 1 625 9/18/2023 21:32 APANN V37986
Benzene, trimethyl-254360 ug/L 1 625 9/18/2023 21:32 APANN V37986
Sample ID Report Lab No
MW-4 23-258-0006 95236
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
Toluene 533570 ug/L 1 625 9/18/2023 21:55 APANN V37986
Cyclopentanol, methyl-495720 ug/L 1 625 9/18/2023 21:55 APANN V37986
Page 66 of 113
Benzene, dimethyl-378770 ug/L
1 625 9/18/2023 21:55 APANN V37986
p-Xylene 303810 ug/L
1 625 9/18/2023 21:55 APANN V37986
Page 67 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Metals Analysis
6010D
V38011QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3050B
QC Prep:V37921
Associated Lab Samples: 95231, 95232, 95233
LRB-V37921 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/18/23 21:420.5000.170<0.170mg/KgChromium
09/18/23 21:420.3000.079<0.079mg/KgLead
LCS-V37921Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11457.150.0mg/KgChromium 80-120
1165.785.00mg/KgLead 80-120
V 95188-MS-V37921 V 95188-MSD-V37921Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
54.1 94.054.550.049.57.47mg/KgChromium 94.0 75-125 0.7 20
10.8 87.011.25.004.956.50mg/KgLead 94.0 75-125 3.6 20
V 95188-PDS-V37921Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
09/18/23 22:04101130mg/KgChromium
09/18/23 22:0410316.2mg/KgLead
Page 1 of 44Date:09/27/2023 07:51 AM
Page 68 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Metals Analysis
6010D
V38070,V38126QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V37999
Associated Lab Samples: 95234, 95235, 95236
LRB-V37999 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/19/23 18:460.0050.002<0.002mg/LChromium
09/19/23 18:460.0060.002<0.002mg/LLead
LCS-V37999Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1101.101.00mg/LChromium 80-120
1030.1030.100mg/LLead 80-120
V 94940-MS-V37999 V 94940-MSD-V37999Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.08 1081.071.001.000.003mg/LChromium 107 75-125 0.9 20.0
0.105 1020.1020.1000.1000.003mg/LLead 99.0 75-125 2.8 20.0
V 94940-PDS-V37999Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
09/20/23 14:481082.70mg/LChromium
09/19/23 18:591000.250mg/LLead
Page 2 of 44Date:09/27/2023 07:51 AM
Page 69 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
Associated Lab Samples: 95234, 95235, 95236
LRB-V38229 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/21/23 13:5410.01.80<1.80µg/LAcetone
09/21/23 13:540.5000.180<0.180µg/LBenzene
09/21/23 13:540.5000.210<0.210µg/LBromobenzene
09/21/23 13:541.000.420<0.420µg/LBromochloromethane
09/21/23 13:540.5000.160<0.160µg/LBromodichloromethane
09/21/23 13:545.001.50<1.50µg/LBromoform
09/21/23 13:541.000.280<0.280µg/LBromomethane
09/21/23 13:540.5000.180<0.180µg/Ln-Butylbenzene
09/21/23 13:540.5000.200<0.200µg/Lsec-Butyl benzene
09/21/23 13:542.000.920<0.920µg/Ltert-Butyl benzene
09/21/23 13:540.5000.180<0.180µg/LCarbon Tetrachloride
09/21/23 13:540.5000.190<0.190µg/LChlorobenzene
09/21/23 13:540.5000.190<0.190µg/LChlorodibromomethane
09/21/23 13:541.000.430<0.430µg/LChloroethane
09/21/23 13:540.5000.220<0.220µg/LChloroform
09/21/23 13:540.5000.220<0.220µg/LChloromethane
09/21/23 13:540.5000.200<0.200µg/L2-Chlorotoluene
09/21/23 13:540.5000.200<0.200µg/L4-Chlorotoluene
09/21/23 13:540.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/21/23 13:542.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/21/23 13:540.5000.230<0.230µg/LDibromomethane
09/21/23 13:540.5000.220<0.220µg/L1,2-Dichlorobenzene
09/21/23 13:540.5000.190<0.190µg/L1,3-Dichlorobenzene
09/21/23 13:540.5000.210<0.210µg/L1,4-Dichlorobenzene
09/21/23 13:545.001.20<1.20µg/LDichlorodifluoromethane
09/21/23 13:540.5000.240<0.240µg/L1,1-Dichloroethane
09/21/23 13:540.5000.150<0.150µg/L1,2-Dichloroethane
Page 3 of 44Date:09/27/2023 07:51 AM
Page 70 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
Associated Lab Samples: 95234, 95235, 95236
LRB-V38229 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/21/23 13:540.5000.150<0.150µg/L1,1-Dichloroethene
09/21/23 13:540.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/21/23 13:540.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/21/23 13:540.5000.190<0.190µg/L1,2-Dichloropropane
09/21/23 13:540.5000.130<0.130µg/L1,3-Dichloropropane
09/21/23 13:542.000.210<0.210µg/L2,2-Dichloropropane
09/21/23 13:540.5000.200<0.200µg/L1,1-Dichloropropene
09/21/23 13:540.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/21/23 13:540.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/21/23 13:5420042.0<42.0µg/LEthanol
09/21/23 13:540.5000.170<0.170µg/LEthylbenzene
09/21/23 13:5410.00.059<0.059µg/LEthyl Tertiary Butyl Ether (ETBE)
09/21/23 13:543.000.350<0.350µg/LHexachlorobutadiene
09/21/23 13:541.000.380<0.380µg/L2-Hexanone
09/21/23 13:540.5000.180<0.180µg/LIsopropylbenzene
09/21/23 13:540.5000.089<0.089µg/L4-Isopropyl toluene
09/21/23 13:545.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/21/23 13:541.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/21/23 13:541.000.078<0.078µg/L4-Methyl-2-Pentanone
09/21/23 13:542.000.330<0.330µg/LMethylene Chloride
09/21/23 13:541.000.470<0.470µg/LNaphthalene
09/21/23 13:540.5000.190<0.190µg/Ln-Propylbenzene
09/21/23 13:540.5000.220<0.220µg/LStyrene
09/21/23 13:5410.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
09/21/23 13:5410.00.350<0.350µg/Ltert-Butyl formate (TBF)
09/21/23 13:5410.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
09/21/23 13:5410.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 4 of 44Date:09/27/2023 07:51 AM
Page 71 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
Associated Lab Samples: 95234, 95235, 95236
LRB-V38229 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/21/23 13:540.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/21/23 13:540.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/21/23 13:540.5000.220<0.220µg/LTetrachloroethene
09/21/23 13:540.5000.220<0.220µg/LToluene
09/21/23 13:540.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/21/23 13:540.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/21/23 13:540.5000.160<0.160µg/L1,1,1-Trichloroethane
09/21/23 13:540.5000.096<0.096µg/L1,1,2-Trichloroethane
09/21/23 13:540.5000.180<0.180µg/LTrichloroethene
09/21/23 13:540.5000.180<0.180µg/LTrichlorofluoromethane
09/21/23 13:540.5000.270<0.270µg/L1,2,3-Trichloropropane
09/21/23 13:540.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/21/23 13:540.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/21/23 13:545.001.00<1.00µg/LVinyl Acetate
09/21/23 13:540.5000.170<0.170µg/LVinyl Chloride
09/21/23 13:540.5000.210<0.210µg/Lo-Xylene
09/21/23 13:541.000.420<0.420µg/Lm,p-Xylene
09/21/23 13:5410.01.00<1.00µg/L3,3-Dimethyl-1-butanol
09/21/23 13:544-Bromofluorobenzene (S)98.8 70-130
09/21/23 13:54Dibromofluoromethane (S)101 70-130
09/21/23 13:541,2-Dichloroethane - d4 (S)98.0 70-130
09/21/23 13:54Toluene-d8 (S)103 70-130
Page 5 of 44Date:09/27/2023 07:51 AM
Page 72 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
LCS-V38229 LCSD-V38229Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
46.9 11712650.440.0µg/LAcetone 40-160 7.1 20.0
21.2 10610520.920.0µg/LBenzene 70-130 1.4 20.0
22.3 11211122.220.0µg/LBromobenzene 70-130 0.4 20.0
21.3 10710521.020.0µg/LBromochloromethane 70-130 1.4 20.0
20.8 10410721.320.0µg/LBromodichloromethane 70-130 2.3 20.0
22.1 11111422.820.0µg/LBromoform 70-130 3.1 20.0
19.9 99.510320.520.0µg/LBromomethane 60-140 2.9 20.0
23.3 11711523.020.0µg/Ln-Butylbenzene 70-130 1.2 20.0
21.7 10910721.320.0µg/Lsec-Butyl benzene 70-130 1.8 20.0
21.2 10610621.220.0µg/Ltert-Butyl benzene 70-130 0.0 20.0
19.7 98.511322.620.0µg/LCarbon Tetrachloride 70-130 13.7 20.0
21.8 10910821.620.0µg/LChlorobenzene 70-130 0.9 20.0
22.8 11411623.120.0µg/LChlorodibromomethane 70-130 1.3 20.0
16.5 82.596.019.220.0µg/LChloroethane 60-140 15.1 20.0
20.3 10210420.820.0µg/LChloroform 70-130 2.4 20.0
18.0 90.099.019.820.0µg/LChloromethane 60-140 9.5 20.0
21.0 10510420.820.0µg/L2-Chlorotoluene 70-130 0.9 20.0
21.5 10810821.620.0µg/L4-Chlorotoluene 70-130 0.4 20.0
21.1 10610320.620.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.3 20.0
24.3 12211923.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.0 20.0
22.4 11210921.720.0µg/LDibromomethane 70-130 3.1 20.0
22.5 11311422.820.0µg/L1,2-Dichlorobenzene 70-130 1.3 20.0
22.1 11111122.120.0µg/L1,3-Dichlorobenzene 70-130 0.0 20.0
21.7 10910921.820.0µg/L1,4-Dichlorobenzene 70-130 0.4 20.0
19.6 98.010521.020.0µg/LDichlorodifluoromethane 60-140 6.8 20.0
21.0 10510721.320.0µg/L1,1-Dichloroethane 70-130 1.4 20.0
Page 6 of 44Date:09/27/2023 07:51 AM
Page 73 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
LCS-V38229 LCSD-V38229Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.7 10410120.220.0µg/L1,2-Dichloroethane 70-130 2.4 20.0
20.3 10210721.320.0µg/L1,1-Dichloroethene 70-130 4.8 20.0
20.8 10410420.820.0µg/Lcis-1,2-Dichloroethene 70-130 0.0 20.0
21.3 10710520.920.0µg/Ltrans-1,2-Dichloroethene 70-130 1.8 20.0
22.1 11110821.520.0µg/L1,2-Dichloropropane 70-130 2.7 20.0
23.1 11611222.320.0µg/L1,3-Dichloropropane 70-130 3.5 20.0
21.7 10911723.320.0µg/L2,2-Dichloropropane 70-130 7.1 20.0
22.7 11411623.120.0µg/L1,1-Dichloropropene 70-130 1.7 20.0
22.6 11310921.820.0µg/Lcis-1,3-Dichloropropene 70-130 3.6 20.0
22.6 11311522.920.0µg/Ltrans-1,3-Dichloropropene 70-130 1.3 20.0
407 81.497.2486500µg/LEthanol 60-140 17.6 20.0
21.4 10710420.820.0µg/LEthylbenzene 70-130 2.8 20.0
44.8 11211345.140.0µg/LEthyl Tertiary Butyl Ether (ETBE)70-130 0.6 20.0
22.8 11411322.620.0µg/LHexachlorobutadiene 70-130 0.8 20.0
24.9 12513526.920.0µg/L2-Hexanone 60-140 7.7 20.0
22.3 11211222.320.0µg/LIsopropylbenzene 70-130 0.0 20.0
22.4 11211322.520.0µg/L4-Isopropyl toluene 70-130 0.4 20.0
22.1 11111523.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 3.9 20.0
21.7 10911222.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.7 20.0
23.6 11811422.820.0µg/L4-Methyl-2-Pentanone 60-140 3.4 20.0
18.5 92.592.518.520.0µg/LMethylene Chloride 70-130 0.0 20.0
26.3 132*12925.820.0µg/LNaphthalene 70-130 1.9 20.0
21.9 11010921.720.0µg/Ln-Propylbenzene 70-130 0.9 20.0
21.9 11011021.920.0µg/LStyrene 70-130 0.0 20.0
42.5 10611244.740.0µg/Ltert-Butyl Alcohol (TBA)40-140 5.0 20.0
46.4 11611445.440.0µg/Ltert-Butyl formate (TBF)40-140 2.1 20.0
Page 7 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 74 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38230QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38229
LCS-V38229 LCSD-V38229Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.6 10886.517.320.0µg/Ltert-Amyl Alcohol (TAA)40-140 22.1*20.0
44.5 11111044.140.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.9 20.0
22.6 11311122.120.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.2 20.0
24.5 12311723.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 5.0 20.0
21.9 11011222.420.0µg/LTetrachloroethene 70-130 2.2 20.0
20.8 10410621.120.0µg/LToluene 70-130 1.4 20.0
31.2 156*161*32.120.0µg/L1,2,3-Trichlorobenzene 70-130 2.8 20.0
27.6 138*140*27.920.0µg/L1,2,4-Trichlorobenzene 70-130 1.0 20.0
20.7 10410320.620.0µg/L1,1,1-Trichloroethane 70-130 0.4 20.0
22.2 11111322.520.0µg/L1,1,2-Trichloroethane 70-130 1.3 20.0
20.1 10110220.320.0µg/LTrichloroethene 70-130 0.9 20.0
20.3 10210921.720.0µg/LTrichlorofluoromethane 60-140 6.6 20.0
21.8 10911122.120.0µg/L1,2,3-Trichloropropane 70-130 1.3 20.0
22.3 11211021.920.0µg/L1,2,4-Trimethylbenzene 70-130 1.8 20.0
21.8 10911022.020.0µg/L1,3,5-Trimethylbenzene 70-130 0.9 20.0
27.9 14013126.120.0µg/LVinyl Acetate 60-140 6.6 20.0
19.8 99.010621.220.0µg/LVinyl Chloride 60-140 6.8 20.0
21.3 10710621.220.0µg/Lo-Xylene 70-130 0.4 20.0
45.6 11411144.540.0µg/Lm,p-Xylene 70-130 2.4 20.0
22.2 11111422.820.0µg/L3,3-Dimethyl-1-butanol 70-130 2.6 20.0
97.896.64-Bromofluorobenzene (S)70-130
101101Dibromofluoromethane (S)70-130
1021051,2-Dichloroethane - d4 (S)70-130
104103Toluene-d8 (S)70-130
Page 8 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 75 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38305QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38304
Associated Lab Samples: 95234, 95235, 95236
LRB-V38304 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/22/23 16:130.5000.180<0.180µg/LBenzene
09/22/23 16:130.5000.170<0.170µg/LEthylbenzene
09/22/23 16:131.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/22/23 16:131.000.470<0.470µg/LNaphthalene
09/22/23 16:1310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
09/22/23 16:130.5000.220<0.220µg/LToluene
09/22/23 16:130.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/22/23 16:130.5000.210<0.210µg/Lo-Xylene
09/22/23 16:134-Bromofluorobenzene (S)103 70-130
09/22/23 16:13Dibromofluoromethane (S)97.8 70-130
09/22/23 16:131,2-Dichloroethane - d4 (S)97.0 70-130
09/22/23 16:13Toluene-d8 (S)98.0 70-130
LCS-V38304 LCSD-V38304Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10099.519.920.0µg/LBenzene 70-130 0.5 20.0
19.4 97.097.519.520.0µg/LEthylbenzene 70-130 0.5 20.0
21.1 10610420.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.4 20.0
19.6 98.010420.720.0µg/LNaphthalene 70-130 5.4 20.0
20.1 10111422.820.0µg/Ltert-Amyl Alcohol (TAA)40-140 12.5 20.0
19.5 97.597.019.420.0µg/LToluene 70-130 0.5 20.0
20.8 10410520.920.0µg/L1,2,4-Trimethylbenzene 70-130 0.4 20.0
20.1 10110120.220.0µg/Lo-Xylene 70-130 0.4 20.0
1011004-Bromofluorobenzene (S)70-130
97.896.0Dibromofluoromethane (S)70-130
Page 9 of 44Date:09/27/2023 07:51 AM
Page 76 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38305QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38304
LCS-V38304 LCSD-V38304Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
98.098.21,2-Dichloroethane - d4 (S)70-130
99.099.6Toluene-d8 (S)70-130
Page 10 of 44Date:09/27/2023 07:51 AM
Page 77 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V38367QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V38366
Associated Lab Samples: 95234
LRB-V38366 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/25/23 14:541.000.420<0.420µg/Lm,p-Xylene
09/25/23 14:544-Bromofluorobenzene (S)94.2 70-130
09/25/23 14:54Dibromofluoromethane (S)98.0 70-130
09/25/23 14:541,2-Dichloroethane - d4 (S)105 70-130
09/25/23 14:54Toluene-d8 (S)99.4 70-130
LCS-V38366 LCSD-V38366Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.3 10810943.640.0µg/Lm,p-Xylene 70-130 0.6 20.0
91.891.64-Bromofluorobenzene (S)70-130
10199.8Dibromofluoromethane (S)70-130
1141141,2-Dichloroethane - d4 (S)70-130
98.496.4Toluene-d8 (S)70-130
Page 11 of 44Date:09/27/2023 07:51 AM
Page 78 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
Associated Lab Samples: 95234, 95235, 95236
LRB-V37964 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/18/23 18:082.000.302<0.302µg/LAcenaphthene
09/18/23 18:082.000.297<0.297µg/LAcenaphthylene
09/18/23 18:082.000.836<0.836µg/LAnthracene
09/18/23 18:0810.01.32<1.32µg/LBenzidine
09/18/23 18:082.000.637<0.637µg/LBenzo(a)anthracene
09/18/23 18:082.001.02<1.02µg/LBenzo(a)pyrene
09/18/23 18:085.002.49<2.49µg/LBenzo(b)fluoranthene
09/18/23 18:085.001.01<1.01µg/LBenzo(g,h,i)perylene
09/18/23 18:085.001.99<1.99µg/LBenzo(k)fluoranthene
09/18/23 18:0810.01.10<1.10µg/LBenzoic Acid
09/18/23 18:085.000.684<0.684µg/LBenzyl alcohol
09/18/23 18:085.000.468<0.468µg/LBis(2-Chloroethoxy)methane
09/18/23 18:085.001.04<1.04µg/LBis(2-Chloroethyl)ether
09/18/23 18:085.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
09/18/23 18:0810.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
09/18/23 18:085.001.11<1.11µg/L4-Bromophenyl phenyl ether
09/18/23 18:085.001.83<1.83µg/LButyl benzyl phthalate
09/18/23 18:085.001.18<1.18µg/L4-Chloro-3-methylphenol
09/18/23 18:0820.07.38<7.38µg/L2-Chloronaphthalene
09/18/23 18:0810.00.938<0.938µg/L2-Chlorophenol
09/18/23 18:085.001.71<1.71µg/L4-Chlorophenyl phenyl ether
09/18/23 18:082.000.405<0.405µg/LChrysene
09/18/23 18:082.000.434<0.434µg/LDibenz(a,h)anthracene
09/18/23 18:085.000.856<0.856µg/LDibenzofuran
09/18/23 18:085.002.00<2.00µg/L1,2-Dichlorobenzene
09/18/23 18:085.002.00<2.00µg/L1,3-Dichlorobenzene
09/18/23 18:085.002.05<2.05µg/L1,4-Dichlorobenzene
Page 12 of 44Date:09/27/2023 07:51 AM
Page 79 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
Associated Lab Samples: 95234, 95235, 95236
LRB-V37964 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/18/23 18:085.001.89<1.89µg/L3,3'-Dichlorobenzidine
09/18/23 18:0810.01.46<1.46µg/L2,4-Dichlorophenol
09/18/23 18:085.000.745<0.745µg/LDiethyl phthalate
09/18/23 18:085.000.939<0.939µg/LDimethyl phthalate
09/18/23 18:0820.01.57<1.57µg/L2,4-Dimethylphenol
09/18/23 18:085.002.06<2.06µg/LDi-n-butyl phthalate
09/18/23 18:0810.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
09/18/23 18:0810.01.92<1.92µg/L2,4-Dinitrophenol
09/18/23 18:085.001.11<1.11µg/L2,4-Dinitrotoluene
09/18/23 18:085.000.809<0.809µg/L2,6-Dinitrotoluene
09/18/23 18:085.001.65<1.65µg/LDi-n-Octyl Phthalate
09/18/23 18:082.000.250<0.250µg/LFluoranthene
09/18/23 18:082.000.807<0.807µg/LFluorene
09/18/23 18:085.000.979<0.979µg/LHexachlorobenzene
09/18/23 18:085.002.73<2.73µg/LHexachlorobutadiene
09/18/23 18:085.002.05<2.05µg/LHexachlorocyclopentadiene
09/18/23 18:085.001.76<1.76µg/LHexachloroethane
09/18/23 18:082.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
09/18/23 18:085.000.444<0.444µg/LIsophorone
09/18/23 18:082.001.14<1.14µg/L1-Methylnaphthalene
09/18/23 18:082.000.666<0.666µg/L2-Methylnaphthalene
09/18/23 18:082.000.728<0.728µg/LNaphthalene
09/18/23 18:085.000.905<0.905µg/LNitrobenzene
09/18/23 18:085.000.493<0.493µg/L2-Nitrophenol
09/18/23 18:0810.01.23<1.23µg/L4-Nitrophenol
09/18/23 18:085.001.10<1.10µg/LN-Nitrosodiphenylamine
09/18/23 18:085.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 13 of 44Date:09/27/2023 07:51 AM
Page 80 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
Associated Lab Samples: 95234, 95235, 95236
LRB-V37964 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/18/23 18:085.001.43<1.43µg/LPentachlorophenol
09/18/23 18:082.000.428<0.428µg/LPhenanthrene
09/18/23 18:085.000.651<0.651µg/LPhenol
09/18/23 18:082.000.434<0.434µg/LPyrene
09/18/23 18:085.002.21<2.21µg/L1,2,4-Trichlorobenzene
09/18/23 18:085.001.32<1.32µg/L2,4,6-Trichlorophenol
09/18/23 18:082-Fluorobiphenyl (S)75.8 49-118
09/18/23 18:082-Fluorophenol (S)38.0 22-84
09/18/23 18:08Nitrobenzene-d5 (S)70.6 43-123
09/18/23 18:084-Terphenyl-d14 (S)91.6 49-151
09/18/23 18:082,4,6-Tribromophenol (S)78.5 31-144
09/18/23 18:08Phenol-d5 (S)24.3 10-63
LCS-V37964 LCSD-V37964Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
29.7 59.461.630.850.0µg/LAcenaphthene 47-145 3.6 20.0
29.8 59.661.630.850.0µg/LAcenaphthylene 33-145 3.3 20.0
36.5 73.074.837.450.0µg/LAnthracene 27-133 2.4 20.0
25.1 50.230.215.150.0µg/LBenzidine 15-150 49.7*20.0
35.7 71.471.835.950.0µg/LBenzo(a)anthracene 33-143 0.5 20.0
36.1 72.272.436.250.0µg/LBenzo(a)pyrene 17-163 0.2 20.0
34.3 68.669.234.650.0µg/LBenzo(b)fluoranthene 24-159 0.8 20.0
31.8 63.663.631.850.0µg/LBenzo(g,h,i)perylene 10-219 0.0 20.0
33.8 67.667.033.550.0µg/LBenzo(k)fluoranthene 11-162 0.8 20.0
17.2 34.434.017.050.0µg/LBenzoic Acid 10-125 1.1 20.0
Page 14 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 81 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
LCS-V37964 LCSD-V37964Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
27.4 54.855.027.550.0µg/LBenzyl alcohol 16-107 0.3 20.0
29.1 58.259.429.750.0µg/LBis(2-Chloroethoxy)methane 33-184 2.0 20.0
25.0 50.052.626.350.0µg/LBis(2-Chloroethyl)ether 12-158 5.0 20.0
26.3 52.655.027.550.0µg/LBis(2-Chloroisopropyl)ether 36-166 4.4 20.0
37.2 74.476.038.050.0µg/LBis(2-ethylhexyl)phthalate 10-158 2.1 20.0
34.6 69.271.235.650.0µg/L4-Bromophenyl phenyl ether 53-127 2.8 20.0
36.7 73.474.037.050.0µg/LButyl benzyl phthalate 10-152 0.8 20.0
29.7 59.459.829.950.0µg/L4-Chloro-3-methylphenol 22-147 0.6 20.0
28.3 56.6*59.2*29.650.0µg/L2-Chloronaphthalene 60-118 4.4 20.0
27.2 54.456.828.450.0µg/L2-Chlorophenol 23-134 4.3 20.0
32.8 65.667.433.750.0µg/L4-Chlorophenyl phenyl ether 25-158 2.7 20.0
35.6 71.272.236.150.0µg/LChrysene 17-168 1.3 20.0
22.0 44.043.621.850.0µg/LDibenz(a,h)anthracene 10-227 0.9 20.0
30.5 61.063.031.550.0µg/LDibenzofuran 39-114 3.2 20.0
20.4 40.843.021.550.0µg/L1,2-Dichlorobenzene 32-129 5.2 20.0
19.7 39.441.220.650.0µg/L1,3-Dichlorobenzene 20-124 4.4 20.0
19.3 38.641.820.950.0µg/L1,4-Dichlorobenzene 20-124 7.9 20.0
35.5 71.071.835.950.0µg/L3,3'-Dichlorobenzidine 10-262 1.1 20.0
29.4 58.860.230.150.0µg/L2,4-Dichlorophenol 39-135 2.3 20.0
35.6 71.271.835.950.0µg/LDiethyl phthalate 10-114 0.8 20.0
35.4 70.871.035.550.0µg/LDimethyl phthalate 10-112 0.2 20.0
39.4 78.878.839.450.0µg/L2,4-Dimethylphenol 32-119 0.0 20.0
38.3 76.679.839.950.0µg/LDi-n-butyl phthalate 10-118 4.0 20.0
35.7 71.471.235.650.0µg/L4,6-Dinitro-2-methylphenol 10-181 0.2 20.0
34.4 68.861.430.750.0µg/L2,4-Dinitrophenol 10-191 11.3 20.0
35.5 71.071.635.850.0µg/L2,4-Dinitrotoluene 39-139 0.8 20.0
Page 15 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 82 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
LCS-V37964 LCSD-V37964Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
34.2 68.468.834.450.0µg/L2,6-Dinitrotoluene 50-158 0.5 20.0
35.5 71.070.035.050.0µg/LDi-n-Octyl Phthalate 10-146 1.4 20.0
33.2 66.468.434.250.0µg/LFluoranthene 26-137 2.9 20.0
32.4 64.865.632.850.0µg/LFluorene 59-121 1.2 20.0
35.5 71.075.437.750.0µg/LHexachlorobenzene 10-152 6.0 20.0
20.8 41.643.821.950.0µg/LHexachlorobutadiene 24-116 5.1 20.0
21.0 42.041.820.950.0µg/LHexachlorocyclopentadiene 32-117 0.4 20.0
18.5 37.0*40.220.150.0µg/LHexachloroethane 40-113 8.2 20.0
31.5 63.064.032.050.0µg/LIndeno(1,2,3-cd)pyrene 10-171 1.5 20.0
27.5 55.054.427.250.0µg/LIsophorone 21-196 1.0 20.0
23.3 46.647.623.850.0µg/L1-Methylnaphthalene 40-135 2.1 20.0
22.5 45.047.223.650.0µg/L2-Methylnaphthalene 18-121 4.7 20.0
22.5 45.047.223.650.0µg/LNaphthalene 21-133 4.7 20.0
24.5 49.050.425.250.0µg/LNitrobenzene 35-180 2.8 20.0
26.9 53.854.227.150.0µg/L2-Nitrophenol 29-182 0.7 20.0
18.0 36.035.417.750.0µg/L4-Nitrophenol 10-132 1.6 20.0
42.1 84.286.443.250.0µg/LN-Nitrosodiphenylamine 69-152 2.5 20.0
28.3 56.658.429.250.0µg/LN-Nitroso-di-n-propylamine 10-230 3.1 20.0
45.9 91.891.245.650.0µg/LPentachlorophenol 14-176 0.6 20.0
35.1 70.272.836.450.0µg/LPhenanthrene 54-120 3.6 20.0
13.7 27.428.014.050.0µg/LPhenol 10-112 2.1 20.0
36.6 73.273.036.550.0µg/LPyrene 52-115 0.2 20.0
20.8 41.6*43.6*21.850.0µg/L1,2,4-Trichlorobenzene 44-142 4.6 20.0
35.2 70.470.635.350.0µg/L2,4,6-Trichlorophenol 37-144 0.2 20.0
66.869.42-Fluorobiphenyl (S)49-118
32.634.12-Fluorophenol (S)22-84
Page 16 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 83 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V37986QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V37964
LCS-V37964 LCSD-V37964Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
53.656.6Nitrobenzene-d5 (S)43-123
79.280.04-Terphenyl-d14 (S)49-151
71.873.02,4,6-Tribromophenol (S)31-144
22.122.8Phenol-d5 (S)10-63
Page 17 of 44Date:09/27/2023 07:51 AM
Page 84 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
Associated Lab Samples: 95231, 95232
LRB-V37959 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0200.002<0.002mg/KgAcetone
09/15/23 14:130.0200.001<0.001mg/KgAcrolein
09/15/23 14:130.0200.0008<0.0008mg/KgAcrylonitrile
09/15/23 14:130.0050.0006<0.0006mg/KgBenzene
09/15/23 14:130.0050.0005<0.0005mg/KgBromobenzene
09/15/23 14:130.0050.0008<0.0008mg/KgBromochloromethane
09/15/23 14:130.0050.001<0.001mg/KgBromodichloromethane
09/15/23 14:130.0050.001<0.001mg/KgBromoform
09/15/23 14:130.0100.001<0.001mg/KgBromomethane
09/15/23 14:130.0050.0005<0.0005mg/Kgn-Butylbenzene
09/15/23 14:130.0050.0006<0.0006mg/Kgsec-Butyl benzene
09/15/23 14:130.0050.0005<0.0005mg/Kgtert-Butyl benzene
09/15/23 14:130.0050.0006<0.0006mg/KgCarbon Disulfide
09/15/23 14:130.0050.001<0.001mg/KgCarbon Tetrachloride
09/15/23 14:130.0050.0007<0.0007mg/KgChlorobenzene
09/15/23 14:130.0050.0009<0.0009mg/KgChlorodibromomethane
09/15/23 14:130.0100.0009<0.0009mg/KgChloroethane
09/15/23 14:130.0050.001<0.001mg/KgChloroform
09/15/23 14:130.0100.0006<0.0006mg/KgChloromethane
09/15/23 14:130.0050.0005<0.0005mg/Kg2-Chlorotoluene
09/15/23 14:130.0050.0004<0.0004mg/Kg4-Chlorotoluene
09/15/23 14:130.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
09/15/23 14:130.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
09/15/23 14:130.0050.0006<0.0006mg/Kg1,2-Dibromoethane
09/15/23 14:130.0050.0006<0.0006mg/KgDibromomethane
09/15/23 14:130.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
09/15/23 14:130.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 18 of 44Date:09/27/2023 07:51 AM
Page 85 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
Associated Lab Samples: 95231, 95232
LRB-V37959 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
09/15/23 14:130.0100.001<0.001mg/KgDichlorodifluoromethane
09/15/23 14:130.0050.0008<0.0008mg/Kg1,1-Dichloroethane
09/15/23 14:130.0050.001<0.001mg/Kg1,2-Dichloroethane
09/15/23 14:130.0050.0007<0.0007mg/Kg1,1-Dichloroethene
09/15/23 14:130.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
09/15/23 14:130.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
09/15/23 14:130.0050.0004<0.0004mg/Kg1,2-Dichloropropane
09/15/23 14:130.0050.0006<0.0006mg/Kg1,3-Dichloropropane
09/15/23 14:130.0050.001<0.001mg/Kg2,2-Dichloropropane
09/15/23 14:130.0050.0008<0.0008mg/Kg1,1-Dichloropropene
09/15/23 14:130.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
09/15/23 14:130.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
09/15/23 14:130.0050.0006<0.0006mg/KgEthylbenzene
09/15/23 14:130.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
09/15/23 14:130.0100.0008<0.0008mg/KgHexachlorobutadiene
09/15/23 14:130.0100.0007<0.0007mg/Kgn-Hexane
09/15/23 14:130.0200.0006<0.0006mg/Kg2-Hexanone
09/15/23 14:130.0050.0005<0.0005mg/KgIsopropylbenzene
09/15/23 14:130.0050.001<0.001mg/Kg4-Isopropyl toluene
09/15/23 14:130.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
09/15/23 14:130.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
09/15/23 14:130.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
09/15/23 14:130.0100.001<0.001mg/KgMethylene Chloride
09/15/23 14:130.0100.0010<0.0010mg/KgNaphthalene
09/15/23 14:130.0050.0005<0.0005mg/Kgn-Propylbenzene
09/15/23 14:130.0050.001<0.001mg/KgStyrene
Page 19 of 44Date:09/27/2023 07:51 AM
Page 86 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
Associated Lab Samples: 95231, 95232
LRB-V37959 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
09/15/23 14:130.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
09/15/23 14:130.0050.0009<0.0009mg/KgTetrachloroethene
09/15/23 14:130.0050.0007<0.0007mg/KgToluene
09/15/23 14:130.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
09/15/23 14:130.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
09/15/23 14:130.0050.001<0.001mg/Kg1,1,1-Trichloroethane
09/15/23 14:130.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
09/15/23 14:130.0050.0009<0.0009mg/KgTrichloroethene
09/15/23 14:130.0100.002<0.002mg/KgTrichlorofluoromethane
09/15/23 14:130.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
09/15/23 14:130.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
09/15/23 14:130.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
09/15/23 14:130.0100.0005<0.0005mg/KgVinyl Acetate
09/15/23 14:130.0100.0005<0.0005mg/KgVinyl Chloride
09/15/23 14:130.0050.0005<0.0005mg/Kgo-Xylene
09/15/23 14:130.0100.001<0.001mg/Kgm,p-Xylene
09/15/23 14:134-Bromofluorobenzene (S)99.8 70-130
09/15/23 14:13Dibromofluoromethane (S)100 84-123
09/15/23 14:13Toluene-d8 (S)94.2 76-129
LCS-V37959 LCSD-V37959Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.102 10295.00.0950.100mg/KgAcetone 29-198 7.1 20
0.110 1101060.1060.100mg/KgAcrolein 70-130 3.7 20
Page 20 of 44Date:09/27/2023 07:51 AM
Page 87 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
LCS-V37959 LCSD-V37959Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.115 1151060.1060.100mg/KgAcrylonitrile 65-134 8.1 20
0.045 90.494.80.0470.050mg/KgBenzene 74-127 4.7 20
0.042 85.887.60.0430.050mg/KgBromobenzene 73-125 2.0 20
0.053 1061080.0540.050mg/KgBromochloromethane 72-134 1.6 20
0.048 96.096.80.0480.050mg/KgBromodichloromethane 75-122 0.8 20
0.057 1151100.0550.050mg/KgBromoform 66-135 4.2 20
0.044 88.890.60.0450.050mg/KgBromomethane 20-180 2.0 20
0.042 84.691.60.0450.050mg/Kgn-Butylbenzene 65-135 7.9 20
0.042 84.290.00.0450.050mg/Kgsec-Butyl benzene 66-131 6.6 20
0.042 85.290.40.0450.050mg/Kgtert-Butyl benzene 67-132 5.9 20
0.039 79.686.40.0430.050mg/KgCarbon Disulfide 61-129 8.1 20
0.045 91.699.00.0490.050mg/KgCarbon Tetrachloride 64-143 7.7 20
0.046 92.495.60.0470.050mg/KgChlorobenzene 74-118 3.4 20
0.050 10199.60.0490.050mg/KgChlorodibromomethane 73-122 1.3 20
0.040 80.888.60.0440.050mg/KgChloroethane 33-149 9.2 20
0.045 91.294.60.0470.050mg/KgChloroform 73-127 3.6 20
0.040 81.880.00.0400.050mg/KgChloromethane 45-143 2.2 20
0.042 84.688.60.0440.050mg/Kg2-Chlorotoluene 67-124 4.6 20
0.042 84.688.60.0440.050mg/Kg4-Chlorotoluene 71-126 4.6 20
0.041 83.084.20.0420.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.4 20
0.058 1161090.0540.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 6.3 20
0.052 1051040.0510.050mg/Kg1,2-Dibromoethane 70-132 1.3 20
0.051 1021020.0500.050mg/KgDibromomethane 74-133 0.5 20
0.048 96.695.60.0470.050mg/Kg1,2-Dichlorobenzene 72-123 1.0 20
0.045 90.895.80.0470.050mg/Kg1,3-Dichlorobenzene 71-120 5.3 20
0.045 90.692.00.0460.050mg/Kg1,4-Dichlorobenzene 71-123 1.5 20
Page 21 of 44Date:09/27/2023 07:51 AM
Page 88 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
LCS-V37959 LCSD-V37959Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.046 92.095.20.0470.050mg/KgDichlorodifluoromethane 26-146 3.4 20
0.043 86.890.80.0450.050mg/Kg1,1-Dichloroethane 74-127 4.5 20
0.045 91.091.40.0450.050mg/Kg1,2-Dichloroethane 68-128 0.4 20
0.039 78.685.20.0420.050mg/Kg1,1-Dichloroethene 67-149 8.0 20
0.044 88.292.80.0460.050mg/Kgcis-1,2-Dichloroethene 76-134 5.0 20
0.041 83.689.80.0440.050mg/Kgtrans-1,2-Dichloroethene 73-132 7.1 20
0.045 90.293.60.0460.050mg/Kg1,2-Dichloropropane 73-130 3.6 20
0.048 96.296.60.0480.050mg/Kg1,3-Dichloropropane 75-124 0.4 20
0.042 85.692.40.0460.050mg/Kg2,2-Dichloropropane 50-142 7.6 20
0.043 86.094.00.0470.050mg/Kg1,1-Dichloropropene 71-130 8.8 20
0.050 1011020.0510.050mg/Kgcis-1,3-Dichloropropene 71-125 1.3 20
0.053 1081060.0530.050mg/Kgtrans-1,3-Dichloropropene 68-123 1.1 20
0.043 86.090.40.0450.050mg/KgEthylbenzene 74-128 4.9 20
0.091 91.992.20.0920.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.3 20
0.047 94.099.20.0490.050mg/KgHexachlorobutadiene 64-125 5.3 20
0.046 93.01010.0500.050mg/Kgn-Hexane 70-130 8.6 20
0.046 93.487.80.0430.050mg/Kg2-Hexanone 61-157 6.1 20
0.042 84.289.00.0440.050mg/KgIsopropylbenzene 68-126 5.5 20
0.043 86.892.20.0460.050mg/Kg4-Isopropyl toluene 68-129 6.0 20
0.050 10088.60.0440.050mg/KgMethyl Ethyl Ketone (MEK)63-149 12.4 20
0.050 10098.40.0490.050mg/KgMethyl tert-butyl ether (MTBE)70-130 1.6 20
0.050 1011000.0500.050mg/Kg4-Methyl-2-Pentanone 57-162 0.1 20
0.040 80.883.40.0410.050mg/KgMethylene Chloride 74-129 3.1 20
0.055 1121070.0530.050mg/KgNaphthalene 57-157 4.3 20
0.041 82.487.60.0430.050mg/Kgn-Propylbenzene 67-130 6.1 20
0.048 97.41000.0500.050mg/KgStyrene 77-121 2.8 20
Page 22 of 44Date:09/27/2023 07:51 AM
Page 89 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37960QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37959
LCS-V37959 LCSD-V37959Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.048 97.698.80.0490.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 1.2 20
0.049 99.093.80.0460.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 5.3 20
0.046 93.81010.0500.050mg/KgTetrachloroethene 68-130 7.5 20
0.045 91.697.20.0480.050mg/KgToluene 71-129 5.9 20
0.051 1041030.0510.050mg/Kg1,2,3-Trichlorobenzene 68-130 1.1 20
0.051 1041040.0510.050mg/Kg1,2,4-Trichlorobenzene 66-125 0.0 20
0.044 88.294.80.0470.050mg/Kg1,1,1-Trichloroethane 67-131 7.2 20
0.049 98.497.40.0480.050mg/Kg1,1,2-Trichloroethane 70-133 1.0 20
0.046 92.699.20.0490.050mg/KgTrichloroethene 75-133 6.8 20
0.037 74.080.60.0400.050mg/KgTrichlorofluoromethane 44-146 8.5 20
0.052 1051020.0510.050mg/Kg1,2,3-Trichloropropane 60-137 2.8 20
0.043 87.491.80.0450.050mg/Kg1,2,4-Trimethylbenzene 69-129 4.9 20
0.043 86.090.20.0450.050mg/Kg1,3,5-Trimethylbenzene 69-128 4.7 20
0.062 1251170.0580.050mg/KgVinyl Acetate 60-140 6.6 20
0.042 85.684.60.0420.050mg/KgVinyl Chloride 48-147 1.1 20
0.045 90.694.20.0470.050mg/Kgo-Xylene 74-126 3.8 20
0.088 88.693.30.0930.100mg/Kgm,p-Xylene 75-124 5.1 20
10098.44-Bromofluorobenzene (S)70-130
101101Dibromofluoromethane (S)84-123
94.694.2Toluene-d8 (S)76-129
Page 23 of 44Date:09/27/2023 07:51 AM
Page 90 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
Associated Lab Samples: 95233
LRB-V37992 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0200.002<0.002mg/KgAcetone
09/15/23 14:130.0200.001<0.001mg/KgAcrolein
09/15/23 14:130.0200.0008<0.0008mg/KgAcrylonitrile
09/15/23 14:130.0050.0006<0.0006mg/KgBenzene
09/15/23 14:130.0050.0005<0.0005mg/KgBromobenzene
09/15/23 14:130.0050.0008<0.0008mg/KgBromochloromethane
09/15/23 14:130.0050.001<0.001mg/KgBromodichloromethane
09/15/23 14:130.0050.001<0.001mg/KgBromoform
09/15/23 14:130.0100.001<0.001mg/KgBromomethane
09/15/23 14:130.0050.0005<0.0005mg/Kgn-Butylbenzene
09/15/23 14:130.0050.0006<0.0006mg/Kgsec-Butyl benzene
09/15/23 14:130.0050.0005<0.0005mg/Kgtert-Butyl benzene
09/15/23 14:130.0050.0006<0.0006mg/KgCarbon Disulfide
09/15/23 14:130.0050.001<0.001mg/KgCarbon Tetrachloride
09/15/23 14:130.0050.0007<0.0007mg/KgChlorobenzene
09/15/23 14:130.0050.0009<0.0009mg/KgChlorodibromomethane
09/15/23 14:130.0100.0009<0.0009mg/KgChloroethane
09/15/23 14:130.0050.001<0.001mg/KgChloroform
09/15/23 14:130.0100.0006<0.0006mg/KgChloromethane
09/15/23 14:130.0050.0005<0.0005mg/Kg2-Chlorotoluene
09/15/23 14:130.0050.0004<0.0004mg/Kg4-Chlorotoluene
09/15/23 14:130.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
09/15/23 14:130.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
09/15/23 14:130.0050.0006<0.0006mg/Kg1,2-Dibromoethane
09/15/23 14:130.0050.0010<0.0010mg/KgDibromomethane
09/15/23 14:130.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
09/15/23 14:130.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 24 of 44Date:09/27/2023 07:51 AM
Page 91 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
Associated Lab Samples: 95233
LRB-V37992 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
09/15/23 14:130.0100.001<0.001mg/KgDichlorodifluoromethane
09/15/23 14:130.0050.0008<0.0008mg/Kg1,1-Dichloroethane
09/15/23 14:130.0050.001<0.001mg/Kg1,2-Dichloroethane
09/15/23 14:130.0050.0007<0.0007mg/Kg1,1-Dichloroethene
09/15/23 14:130.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
09/15/23 14:130.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
09/15/23 14:130.0050.0004<0.0004mg/Kg1,2-Dichloropropane
09/15/23 14:130.0050.0006<0.0006mg/Kg1,3-Dichloropropane
09/15/23 14:130.0050.001<0.001mg/Kg2,2-Dichloropropane
09/15/23 14:130.0050.0008<0.0008mg/Kg1,1-Dichloropropene
09/15/23 14:130.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
09/15/23 14:130.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
09/15/23 14:130.0050.0006<0.0006mg/KgEthylbenzene
09/15/23 14:130.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
09/15/23 14:130.0100.0008<0.0008mg/KgHexachlorobutadiene
09/15/23 14:130.0100.0007<0.0007mg/Kgn-Hexane
09/15/23 14:130.0200.0006<0.0006mg/Kg2-Hexanone
09/15/23 14:130.0050.0005<0.0005mg/KgIsopropylbenzene
09/15/23 14:130.0050.001<0.001mg/Kg4-Isopropyl toluene
09/15/23 14:130.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
09/15/23 14:130.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
09/15/23 14:130.0050.001<0.001mg/KgMethylene Chloride
09/15/23 14:130.0100.0010<0.0010mg/KgNaphthalene
09/15/23 14:130.0050.0005<0.0005mg/Kgn-Propylbenzene
09/15/23 14:130.0050.001<0.001mg/KgStyrene
09/15/23 14:130.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
Page 25 of 44Date:09/27/2023 07:51 AM
Page 92 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
Associated Lab Samples: 95233
LRB-V37992 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:130.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
09/15/23 14:130.0050.0009<0.0009mg/KgTetrachloroethene
09/15/23 14:130.0050.0007<0.0007mg/KgToluene
09/15/23 14:130.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
09/15/23 14:130.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
09/15/23 14:130.0050.001<0.001mg/Kg1,1,1-Trichloroethane
09/15/23 14:130.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
09/15/23 14:130.0050.0009<0.0009mg/KgTrichloroethene
09/15/23 14:130.0100.002<0.002mg/KgTrichlorofluoromethane
09/15/23 14:130.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
09/15/23 14:130.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
09/15/23 14:130.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
09/15/23 14:130.0100.0005<0.0005mg/KgVinyl Acetate
09/15/23 14:130.0100.0005<0.0005mg/KgVinyl Chloride
09/15/23 14:130.0050.0005<0.0005mg/Kgo-Xylene
09/15/23 14:130.0100.001<0.001mg/Kgm,p-Xylene
09/15/23 14:134-Bromofluorobenzene (S)99.8 70-130
09/15/23 14:13Dibromofluoromethane (S)100 70-130
09/15/23 14:13Toluene-d8 (S)94.2 76-129
LCS-V37992 LCSD-V37992Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.102 10295.00.0950.100mg/KgAcetone 29-198 7.1 20
0.110 1101060.1060.100mg/KgAcrolein 70-130 3.7 20
0.115 1151060.1060.100mg/KgAcrylonitrile 65-134 8.1 20
Page 26 of 44Date:09/27/2023 07:51 AM
Page 93 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
LCS-V37992 LCSD-V37992Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.045 90.494.80.0470.050mg/KgBenzene 74-127 4.7 20
0.042 85.887.60.0430.050mg/KgBromobenzene 73-125 2.0 20
0.053 1061080.0540.050mg/KgBromochloromethane 72-134 1.6 20
0.048 96.096.80.0480.050mg/KgBromodichloromethane 75-122 0.8 20
0.057 1151100.0550.050mg/KgBromoform 66-135 4.2 20
0.044 88.890.60.0450.050mg/KgBromomethane 20-180 2.0 20
0.042 84.691.60.0450.050mg/Kgn-Butylbenzene 65-135 7.9 20
0.042 84.290.00.0450.050mg/Kgsec-Butyl benzene 66-131 6.6 20
0.042 85.290.40.0450.050mg/Kgtert-Butyl benzene 67-132 5.9 20
0.039 79.686.40.0430.050mg/KgCarbon Disulfide 61-129 8.1 20
0.045 91.699.00.0490.050mg/KgCarbon Tetrachloride 64-143 7.7 20
0.046 92.495.60.0470.050mg/KgChlorobenzene 74-118 3.4 20
0.050 10199.60.0490.050mg/KgChlorodibromomethane 73-122 1.3 20
0.040 80.888.60.0440.050mg/KgChloroethane 33-149 9.2 20
0.045 91.294.60.0470.050mg/KgChloroform 73-127 3.6 20
0.040 81.880.00.0400.050mg/KgChloromethane 45-143 2.2 20
0.042 84.688.60.0440.050mg/Kg2-Chlorotoluene 67-124 4.6 20
0.042 84.688.60.0440.050mg/Kg4-Chlorotoluene 71-126 4.6 20
0.041 83.084.20.0420.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.4 20
0.058 1161090.0540.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 6.3 20
0.052 1051040.0510.050mg/Kg1,2-Dibromoethane 70-132 1.3 20
0.051 1021020.0500.050mg/KgDibromomethane 74-133 0.5 20
0.048 96.695.60.0470.050mg/Kg1,2-Dichlorobenzene 72-123 1.0 20
0.045 90.895.80.0470.050mg/Kg1,3-Dichlorobenzene 71-120 5.3 20
0.045 90.692.00.0460.050mg/Kg1,4-Dichlorobenzene 71-123 1.5 20
0.046 92.095.20.0470.050mg/KgDichlorodifluoromethane 26-146 3.4 20
Page 27 of 44Date:09/27/2023 07:51 AM
Page 94 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
LCS-V37992 LCSD-V37992Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.043 86.890.80.0450.050mg/Kg1,1-Dichloroethane 74-127 4.5 20
0.045 91.091.40.0450.050mg/Kg1,2-Dichloroethane 68-128 0.4 20
0.039 78.685.20.0420.050mg/Kg1,1-Dichloroethene 67-149 8.0 20
0.044 88.292.80.0460.050mg/Kgcis-1,2-Dichloroethene 76-134 5.0 20
0.041 83.689.80.0440.050mg/Kgtrans-1,2-Dichloroethene 73-132 7.1 20
0.045 90.293.60.0460.050mg/Kg1,2-Dichloropropane 73-130 3.6 20
0.048 96.296.60.0480.050mg/Kg1,3-Dichloropropane 75-124 0.4 20
0.042 85.692.40.0460.050mg/Kg2,2-Dichloropropane 50-142 7.6 20
0.043 86.094.00.0470.050mg/Kg1,1-Dichloropropene 71-130 8.8 20
0.050 1011020.0510.050mg/Kgcis-1,3-Dichloropropene 71-125 1.3 20
0.053 1081060.0530.050mg/Kgtrans-1,3-Dichloropropene 68-123 1.1 20
0.043 86.090.40.0450.050mg/KgEthylbenzene 74-128 4.9 20
0.091 91.992.20.0920.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.3 20
0.047 94.099.20.0490.050mg/KgHexachlorobutadiene 64-125 5.3 20
0.046 93.01010.0500.050mg/Kgn-Hexane 70-130 8.6 20
0.046 93.487.80.0430.050mg/Kg2-Hexanone 61-157 6.1 20
0.042 84.289.00.0440.050mg/KgIsopropylbenzene 68-126 5.5 20
0.043 86.892.20.0460.050mg/Kg4-Isopropyl toluene 68-129 6.0 20
0.050 10088.60.0440.050mg/KgMethyl Ethyl Ketone (MEK)63-149 12.4 20
0.050 10098.40.0490.050mg/KgMethyl tert-butyl ether (MTBE)70-130 1.6 20
0.040 80.883.40.0410.050mg/KgMethylene Chloride 74-129 3.1 20
0.055 1121070.0530.050mg/KgNaphthalene 57-157 4.3 20
0.041 82.487.60.0430.050mg/Kgn-Propylbenzene 67-130 6.1 20
0.048 97.41000.0500.050mg/KgStyrene 77-121 2.8 20
0.048 97.698.80.0490.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 1.2 20
0.049 99.093.80.0460.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 5.3 20
Page 28 of 44Date:09/27/2023 07:51 AM
Page 95 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V37993QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V37992
LCS-V37992 LCSD-V37992Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.046 93.81010.0500.050mg/KgTetrachloroethene 68-130 7.5 20
0.045 91.697.20.0480.050mg/KgToluene 71-129 5.9 20
0.051 1041030.0510.050mg/Kg1,2,3-Trichlorobenzene 68-130 1.1 20
0.051 1041040.0510.050mg/Kg1,2,4-Trichlorobenzene 66-125 0.0 20
0.044 88.294.80.0470.050mg/Kg1,1,1-Trichloroethane 67-131 7.2 20
0.049 98.497.40.0480.050mg/Kg1,1,2-Trichloroethane 70-133 1.0 20
0.046 92.699.20.0490.050mg/KgTrichloroethene 75-133 6.8 20
0.037 74.080.60.0400.050mg/KgTrichlorofluoromethane 44-146 8.5 20
0.052 1051020.0510.050mg/Kg1,2,3-Trichloropropane 60-137 2.8 20
0.043 87.491.80.0450.050mg/Kg1,2,4-Trimethylbenzene 69-129 4.9 20
0.043 86.090.20.0450.050mg/Kg1,3,5-Trimethylbenzene 69-128 4.7 20
0.062 1251170.0580.050mg/KgVinyl Acetate 60-140 6.6 20
0.042 85.684.60.0420.050mg/KgVinyl Chloride 48-147 1.1 20
0.045 90.694.20.0470.050mg/Kgo-Xylene 74-126 3.8 20
0.088 88.693.30.0930.100mg/Kgm,p-Xylene 75-124 5.1 20
10098.44-Bromofluorobenzene (S)70-130
101101Dibromofluoromethane (S)70-130
94.694.2Toluene-d8 (S)76-129
Page 29 of 44Date:09/27/2023 07:51 AM
Page 96 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
Associated Lab Samples: 95231, 95232, 95233
LRB-V38087 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/20/23 16:190.6600.116<0.116mg/KgAcenaphthene
09/20/23 16:190.6600.105<0.105mg/KgAcenaphthylene
09/20/23 16:190.6600.152<0.152mg/KgAniline
09/20/23 16:190.6600.143<0.143mg/KgAnthracene
09/20/23 16:190.6600.139<0.139mg/KgBenzo(a)anthracene
09/20/23 16:190.6600.147<0.147mg/KgBenzo(a)pyrene
09/20/23 16:190.6600.146<0.146mg/KgBenzo(b)fluoranthene
09/20/23 16:190.6600.136<0.136mg/KgBenzo(g,h,i)perylene
09/20/23 16:190.6600.137<0.137mg/KgBenzo(k)fluoranthene
09/20/23 16:192.000.580<0.580mg/KgBenzoic Acid
09/20/23 16:190.6600.105<0.105mg/KgBenzyl alcohol
09/20/23 16:190.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
09/20/23 16:190.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
09/20/23 16:190.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
09/20/23 16:190.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
09/20/23 16:190.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
09/20/23 16:190.3300.113<0.113mg/KgButyl benzyl phthalate
09/20/23 16:190.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
09/20/23 16:190.3300.112<0.112mg/Kg4-Chloroaniline
09/20/23 16:190.6600.116<0.116mg/Kg2-Chloronaphthalene
09/20/23 16:190.6600.098<0.098mg/Kg2-Chlorophenol
09/20/23 16:191.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
09/20/23 16:190.6600.142<0.142mg/KgChrysene
09/20/23 16:190.6600.230<0.230mg/KgDibenz(a,h)anthracene
09/20/23 16:190.6600.119<0.119mg/KgDibenzofuran
09/20/23 16:190.6600.094<0.094mg/Kg1,2-Dichlorobenzene
09/20/23 16:190.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 30 of 44Date:09/27/2023 07:51 AM
Page 97 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
Associated Lab Samples: 95231, 95232, 95233
LRB-V38087 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/20/23 16:190.3300.097<0.097mg/Kg1,4-Dichlorobenzene
09/20/23 16:190.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
09/20/23 16:190.6600.095<0.095mg/Kg2,4-Dichlorophenol
09/20/23 16:190.6600.180<0.180mg/KgDiethyl phthalate
09/20/23 16:190.6600.174<0.174mg/KgDimethyl phthalate
09/20/23 16:190.3300.108<0.108mg/Kg2,4-Dimethylphenol
09/20/23 16:190.6600.107<0.107mg/KgDi-n-butyl phthalate
09/20/23 16:191.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
09/20/23 16:191.500.520<0.520mg/Kg2,4-Dinitrophenol
09/20/23 16:190.6600.096<0.096mg/Kg2,4-Dinitrotoluene
09/20/23 16:190.6600.108<0.108mg/Kg2,6-Dinitrotoluene
09/20/23 16:190.3300.143<0.143mg/KgDi-n-Octyl Phthalate
09/20/23 16:190.6600.123<0.123mg/KgFluoranthene
09/20/23 16:190.6600.128<0.128mg/KgFluorene
09/20/23 16:190.6600.106<0.106mg/KgHexachlorobenzene
09/20/23 16:190.6600.097<0.097mg/KgHexachlorobutadiene
09/20/23 16:190.6600.157<0.157mg/KgHexachlorocyclopentadiene
09/20/23 16:190.6600.079<0.079mg/KgHexachloroethane
09/20/23 16:190.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
09/20/23 16:190.6600.191<0.191mg/KgIsophorone
09/20/23 16:190.6600.106<0.106mg/Kg1-Methylnaphthalene
09/20/23 16:190.6600.100<0.100mg/Kg2-Methylnaphthalene
09/20/23 16:190.6600.097<0.097mg/Kg2-Methylphenol
09/20/23 16:190.6600.084<0.084mg/Kg3&4 Methylphenol
09/20/23 16:190.6600.144<0.144mg/KgNaphthalene
09/20/23 16:190.6600.096<0.096mg/Kg2-Nitroaniline
09/20/23 16:190.6600.120<0.120mg/Kg3-Nitroaniline
Page 31 of 44Date:09/27/2023 07:51 AM
Page 98 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
Associated Lab Samples: 95231, 95232, 95233
LRB-V38087 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/20/23 16:190.3300.093<0.093mg/Kg4-Nitroaniline
09/20/23 16:190.3300.116<0.116mg/KgNitrobenzene
09/20/23 16:190.6600.088<0.088mg/Kg2-Nitrophenol
09/20/23 16:190.6600.117<0.117mg/Kg4-Nitrophenol
09/20/23 16:190.6600.263<0.263mg/KgN-Nitrosodimethylamine
09/20/23 16:190.6600.181<0.181mg/KgN-Nitrosodiphenylamine
09/20/23 16:190.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
09/20/23 16:191.000.347<0.347mg/KgPentachlorophenol
09/20/23 16:190.6600.208<0.208mg/KgPhenanthrene
09/20/23 16:190.6600.112<0.112mg/KgPhenol
09/20/23 16:190.6600.134<0.134mg/KgPyrene
09/20/23 16:190.3300.079<0.079mg/KgPyridine
09/20/23 16:190.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
09/20/23 16:190.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
09/20/23 16:190.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
09/20/23 16:192-Fluorobiphenyl (S)82.6 44-115
09/20/23 16:192-Fluorophenol (S)70.2 35-115
09/20/23 16:19Nitrobenzene-d5 (S)80.2 37-122
09/20/23 16:194-Terphenyl-d14 (S)94.6 54-127
09/20/23 16:192,4,6-Tribromophenol (S)74.7 39-132
09/20/23 16:19Phenol-d5 (S)69.0 34-121
LCS-V38087Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
80.81.351.67mg/KgAcenaphthene 40-123
82.61.381.67mg/KgAcenaphthylene 32-132
Page 32 of 44Date:09/27/2023 07:51 AM
Page 99 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
LCS-V38087Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
220*3.681.67mg/KgAniline 12-197
95.21.591.67mg/KgAnthracene 47-123
88.01.471.67mg/KgBenzo(a)anthracene 49-126
1001.671.67mg/KgBenzo(a)pyrene 45-129
91.01.521.67mg/KgBenzo(b)fluoranthene 45-132
91.61.531.67mg/KgBenzo(g,h,i)perylene 43-134
91.01.521.67mg/KgBenzo(k)fluoranthene 47-132
0.0*<0.5801.67mg/KgBenzoic Acid 10-83
74.81.251.67mg/KgBenzyl alcohol 29-122
85.01.421.67mg/KgBis(2-Chloroethoxy)methane 36-121
68.81.151.67mg/KgBis(2-Chloroethyl)ether 31-120
77.81.301.67mg/KgBis(2-Chloroisopropyl)ether 33-131
97.01.621.67mg/KgBis(2-ethylhexyl)phthalate 51-133
89.21.491.67mg/Kg4-Bromophenyl phenyl ether 46-124
95.21.591.67mg/KgButyl benzyl phthalate 48-132
85.61.431.67mg/Kg4-Chloro-3-methylphenol 45-122
1011.681.67mg/Kg4-Chloroaniline 17-106
79.01.321.67mg/Kg2-Chloronaphthalene 41-114
74.81.251.67mg/Kg2-Chlorophenol 34-121
85.61.431.67mg/Kg4-Chlorophenyl phenyl ether 45-121
83.81.401.67mg/KgChrysene 50-124
63.41.061.67mg/KgDibenz(a,h)anthracene 45-134
80.21.341.67mg/KgDibenzofuran 44-120
67.01.121.67mg/Kg1,2-Dichlorobenzene 33-117
65.21.091.67mg/Kg1,3-Dichlorobenzene 30-115
65.21.091.67mg/Kg1,4-Dichlorobenzene 31-115
68.21.141.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 33 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 100 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
LCS-V38087Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
83.81.401.67mg/Kg2,4-Dichlorophenol 40-122
89.21.491.67mg/KgDiethyl phthalate 50-124
88.61.481.67mg/KgDimethyl phthalate 48-124
1111.861.67mg/Kg2,4-Dimethylphenol 30-127
98.81.651.67mg/KgDi-n-butyl phthalate 51-128
71.21.191.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
41.60.6961.67mg/Kg2,4-Dinitrophenol 27-129
89.81.501.67mg/Kg2,4-Dinitrotoluene 48-126
88.61.481.67mg/Kg2,6-Dinitrotoluene 46-124
98.21.641.67mg/KgDi-n-Octyl Phthalate 45-140
86.21.441.67mg/KgFluoranthene 50-127
85.01.421.67mg/KgFluorene 43-125
88.61.481.67mg/KgHexachlorobenzene 45-122
79.01.321.67mg/KgHexachlorobutadiene 32-123
71.81.201.67mg/KgHexachlorocyclopentadiene 32-117
65.21.091.67mg/KgHexachloroethane 28-117
93.41.561.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
76.61.281.67mg/KgIsophorone 30-122
76.61.281.67mg/Kg1-Methylnaphthalene 40-119
77.21.291.67mg/Kg2-Methylnaphthalene 38-122
74.21.241.67mg/Kg2-Methylphenol 32-122
70.01.171.67mg/Kg3&4 Methylphenol 34-119
75.41.261.67mg/KgNaphthalene 35-123
84.41.411.67mg/Kg2-Nitroaniline 44-127
84.41.411.67mg/Kg3-Nitroaniline 33-119
90.41.511.67mg/Kg4-Nitroaniline 63-147
75.41.261.67mg/KgNitrobenzene 34-122
Page 34 of 44Date:09/27/2023 07:51 AM
Page 101 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
LCS-V38087Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
79.01.321.67mg/Kg2-Nitrophenol 36-123
88.61.481.67mg/Kg4-Nitrophenol 30-132
62.21.041.67mg/KgN-Nitrosodimethylamine 10-146
1101.841.67mg/KgN-Nitrosodiphenylamine 38-127
73.61.231.67mg/KgN-Nitroso-di-n-propylamine 36-120
92.21.541.67mg/KgPentachlorophenol 25-133
89.21.491.67mg/KgPhenanthrene 50-121
69.41.161.67mg/KgPhenol 34-121
85.61.431.67mg/KgPyrene 47-127
51.10.8551.67mg/KgPyridine 10-80
74.21.241.67mg/Kg1,2,4-Trichlorobenzene 34-118
84.41.411.67mg/Kg2,4,5-Trichlorophenol 41-124
83.81.401.67mg/Kg2,4,6-Trichlorophenol 39-126
81.42-Fluorobiphenyl (S)44-115
67.22-Fluorophenol (S)35-115
79.0Nitrobenzene-d5 (S)37-122
88.64-Terphenyl-d14 (S)54-127
81.02,4,6-Tribromophenol (S)39-132
64.2Phenol-d5 (S)34-121
V 95489-MS-V38087 V 95489-MSD-V38087Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.17 70.01.161.671.67<0.116mg/KgAcenaphthene 69.4 40-123 0.8 20
1.19 71.21.181.671.67<0.105mg/KgAcenaphthylene 70.6 32-132 0.8 20
2.83 1692.791.671.67<0.152mg/KgAniline 167 12-197 1.4 20
Page 35 of 44Date:09/27/2023 07:51 AM
Page 102 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
V 95489-MS-V38087 V 95489-MSD-V38087Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.30 77.81.301.671.67<0.143mg/KgAnthracene 77.8 47-123 0.0 20
1.30 77.81.251.671.67<0.139mg/KgBenzo(a)anthracene 74.8 49-126 3.9 20
1.32 79.01.261.671.67<0.147mg/KgBenzo(a)pyrene 75.4 45-129 4.6 20
1.23 73.61.231.671.67<0.146mg/KgBenzo(b)fluoranthene 73.6 45-132 0.0 20
1.15 68.80.9031.671.67<0.136mg/KgBenzo(g,h,i)perylene 54.0 43-134 24.0*20
1.14 68.21.061.671.67<0.137mg/KgBenzo(k)fluoranthene 63.4 47-132 7.2 20
0.615 36.8<0.5801.671.67<0.580mg/KgBenzoic Acid 0.0*10-83 5.8 20
1.21 72.41.251.671.67<0.105mg/KgBenzyl alcohol 74.8 29-122 3.2 20
1.23 73.61.211.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 72.4 36-121 1.6 20
1.01 60.41.031.671.67<0.107mg/KgBis(2-Chloroethyl)ether 61.6 31-120 1.9 20
1.17 70.01.191.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 71.2 33-131 1.6 20
1.36 81.41.281.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 76.6 51-133 6.0 20
1.32 79.01.311.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 78.4 46-124 0.7 20
1.31 78.41.231.671.67<0.113mg/KgButyl benzyl phthalate 73.6 48-132 6.2 20
1.25 74.81.231.671.67<0.092mg/Kg4-Chloro-3-methylphenol 73.6 45-122 1.6 20
1.32 79.01.341.671.67<0.112mg/Kg4-Chloroaniline 80.2 17-106 1.5 20
1.17 70.01.171.671.67<0.116mg/Kg2-Chloronaphthalene 70.0 41-114 0.0 20
1.12 67.01.131.671.67<0.098mg/Kg2-Chlorophenol 67.6 34-121 0.8 20
1.22 73.01.241.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 74.2 45-121 1.6 20
1.20 71.81.121.671.67<0.142mg/KgChrysene 67.0 50-124 6.8 20
0.858 51.30.7551.671.67<0.230mg/KgDibenz(a,h)anthracene 45.2 45-134 12.7 20
1.17 70.01.161.671.67<0.119mg/KgDibenzofuran 69.4 44-120 0.8 20
0.998 59.71.031.671.67<0.094mg/Kg1,2-Dichlorobenzene 61.6 33-117 3.1 20
0.957 57.30.9881.671.67<0.097mg/Kg1,3-Dichlorobenzene 59.1 30-115 3.1 20
0.980 58.60.9841.671.67<0.097mg/Kg1,4-Dichlorobenzene 58.9 31-115 0.4 20
0.734 43.90.7551.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 45.2 22-121 2.8 20
Page 36 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 103 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
V 95489-MS-V38087 V 95489-MSD-V38087Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.29 77.21.281.671.67<0.095mg/Kg2,4-Dichlorophenol 76.6 40-122 0.7 20
1.23 73.61.211.671.67<0.180mg/KgDiethyl phthalate 72.4 50-124 1.6 20
1.21 72.41.221.671.67<0.174mg/KgDimethyl phthalate 73.0 48-124 0.8 30
1.72 1031.731.671.67<0.108mg/Kg2,4-Dimethylphenol 104 30-127 0.5 20
1.38 82.61.391.671.67<0.107mg/KgDi-n-butyl phthalate 83.2 51-128 0.7 20
1.00 59.80.8401.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 50.2 29-132 17.3 20
1.04 62.20.7701.671.67<0.520mg/Kg2,4-Dinitrophenol 46.1 27-129 29.8*20
1.28 76.61.311.671.67<0.096mg/Kg2,4-Dinitrotoluene 78.4 48-126 2.3 20
1.30 77.81.331.671.67<0.108mg/Kg2,6-Dinitrotoluene 79.6 46-124 2.2 20
1.27 76.01.241.671.67<0.143mg/KgDi-n-Octyl Phthalate 74.2 45-140 2.3 20
1.22 73.01.201.671.67<0.123mg/KgFluoranthene 71.8 50-127 1.6 20
1.21 72.41.201.671.67<0.128mg/KgFluorene 71.8 43-125 0.8 20
1.28 76.61.251.671.67<0.106mg/KgHexachlorobenzene 74.8 45-122 2.3 20
1.19 71.21.231.671.67<0.097mg/KgHexachlorobutadiene 73.6 32-123 3.3 20
0.716 42.80.3301.671.67<0.157mg/KgHexachlorocyclopentadiene 19.7*32-117 73.8*20
0.941 56.30.9451.671.67<0.079mg/KgHexachloroethane 56.5 28-117 0.4 20
1.20 71.81.001.671.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 59.8 45-133 18.1 20
1.10 65.81.101.671.67<0.191mg/KgIsophorone 65.8 30-122 0.0 20
1.13 67.61.151.671.67<0.106mg/Kg1-Methylnaphthalene 68.8 40-119 1.7 20
1.15 68.81.171.671.67<0.100mg/Kg2-Methylnaphthalene 70.0 38-122 1.7 20
1.11 66.41.111.671.67<0.097mg/Kg2-Methylphenol 66.4 32-122 0.0 20
1.02 61.01.051.671.67<0.084mg/Kg3&4 Methylphenol 62.8 34-119 2.8 20
1.16 69.41.141.671.67<0.144mg/KgNaphthalene 68.2 35-123 1.7 20
1.18 70.61.251.671.67<0.096mg/Kg2-Nitroaniline 74.8 44-127 5.7 20
1.18 70.61.251.671.67<0.120mg/Kg3-Nitroaniline 74.8 33-119 5.7 20
1.17 70.01.141.671.67<0.093mg/Kg4-Nitroaniline 68.2 63-147 2.5 20
Page 37 of 44* QC Fail Date:09/27/2023 07:51 AM
Page 104 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V38117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V38087
V 95489-MS-V38087 V 95489-MSD-V38087Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.12 67.01.121.671.67<0.116mg/KgNitrobenzene 67.0 34-122 0.0 20
1.23 73.61.231.671.67<0.088mg/Kg2-Nitrophenol 73.6 32-123 0.0 20
1.36 81.41.331.671.67<0.117mg/Kg4-Nitrophenol 79.6 30-132 2.2 20
0.885 52.90.8851.671.67<0.263mg/KgN-Nitrosodimethylamine 52.9 10-146 0.0 30
1.55 92.81.541.671.67<0.181mg/KgN-Nitrosodiphenylamine 92.2 38-127 0.6 20
1.06 63.41.091.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 65.2 36-120 2.7 20
1.62 97.01.561.671.67<0.347mg/KgPentachlorophenol 93.4 25-133 3.7 20
1.24 74.21.221.671.67<0.208mg/KgPhenanthrene 73.0 50-121 1.6 20
1.03 61.61.041.671.67<0.112mg/KgPhenol 62.2 34-121 0.9 20
1.22 73.01.151.671.67<0.134mg/KgPyrene 68.8 47-127 5.9 20
0.741 44.30.7661.671.67<0.079mg/KgPyridine 45.8 10-80 3.3 20
1.12 67.01.131.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 67.6 34-118 0.8 20
1.28 76.61.241.671.67<0.096mg/Kg2,4,5-Trichlorophenol 74.2 41-124 3.1 20
1.25 74.81.241.671.67<0.096mg/Kg2,4,6-Trichlorophenol 74.2 39-126 0.8 20
74.82-Fluorobiphenyl (S)74.8 44-115
64.82-Fluorophenol (S)65.1 35-115
74.2Nitrobenzene-d5 (S)73.0 37-122
78.44-Terphenyl-d14 (S)74.2 54-127
75.32,4,6-Tribromophenol (S)73.8 39-132
60.6Phenol-d5 (S)61.5 34-121
Page 38 of 44Date:09/27/2023 07:51 AM
Page 105 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V38177QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V38133
Associated Lab Samples: 95234, 95235, 95236
LRB-V38133 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/21/23 12:530.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V38133 LCSD-V38133Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.297 1191070.2670.250µg/L1,2-Dibromoethane 70-130 10.6 20.0
V 95234-DUP-V38133Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 09/21/23 14:1217.80.2070.173µg/L1,2-Dibromoethane
V 95198-MS-V38133Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.307 1180.261< 0.00345µg/L1,2-Dibromoethane 70-130
Page 39 of 44Date:09/27/2023 07:51 AM
Page 106 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V38061QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V37937
Associated Lab Samples: 95231, 95232, 95233
LRB-V37937 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/19/23 21:5650.09.20<9.20mg/KgAliphatic C9-C18
09/19/23 21:5650.012.2<12.2mg/KgAliphatic C19-C36
09/19/23 21:5650.014.2<14.2mg/KgAromatic C11-C22
09/19/23 21:562-Fluorobiphenyl (S)79.7 40-140
09/19/23 21:562-Bromonaphthalene (S)72.5 40-140
09/19/23 21:56Chlorooctadecane (S)67.5 40-140
09/19/23 21:56OTP Surrogate (S)68.0 40-140
LCS-V37937 LCSD-V37937Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
42.5 70.873.143.960.0mg/KgAliphatic C9-C18 40-140 3.2 50
77.5 96.895.276.280.0mg/KgAliphatic C19-C36 40-140 1.6 50
162 95.298.8168170mg/KgAromatic C11-C22 40-140 3.6 50
84.590.52-Fluorobiphenyl (S)40-140
80.589.22-Bromonaphthalene (S)40-140
73.371.1Chlorooctadecane (S)40-140
77.783.8OTP Surrogate (S)40-140
Page 40 of 44Date:09/27/2023 07:51 AM
Page 107 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V38062QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V38005
Associated Lab Samples: 95234, 95235, 95236
LRB-V38005 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/19/23 15:1735028.2<28.2µg/LAliphatic C9-C18
09/19/23 15:17500124<124µg/LAliphatic C19-C36
09/19/23 15:1725061.2<61.2µg/LAromatic C11-C22
09/19/23 15:172-Fluorobiphenyl (S)70.0 40-140
09/19/23 15:172-Bromonaphthalene (S)73.0 40-140
09/19/23 15:17Chlorooctadecane (S)58.7 40-140
09/19/23 15:17OTP Surrogate (S)61.5 40-140
LCS-V38005 LCSD-V38005Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
354 59.060.5363600µg/LAliphatic C9-C18 40-140 2.5 50.0
687 85.891.7734800µg/LAliphatic C19-C36 40-140 6.6 50.0
1430 84.188.815101700µg/LAromatic C11-C22 40-140 5.4 50.0
76.578.52-Fluorobiphenyl (S)40-140
73.275.52-Bromonaphthalene (S)40-140
66.569.2Chlorooctadecane (S)40-140
69.371.8OTP Surrogate (S)40-140
Page 41 of 44Date:09/27/2023 07:51 AM
Page 108 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V37914QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V37913
Associated Lab Samples: 95231, 95232, 95233
LRB-V37913 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 14:338.001.22<1.22mg/KgAliphatic C5-C8
09/15/23 14:338.004.56<4.56mg/KgAliphatic C9-C12
09/15/23 14:338.000.624<0.624mg/KgAromatic C9-C10
09/15/23 14:332,5-Dibromotoluene (FID) (S)90.4 70-130
09/15/23 14:332,5-Dibromotoluene (PID) (S)79.4 70-130
LCS-V37913 LCSD-V37913Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
28.7 89.687.828.132.0mg/KgAliphatic C5-C8 70-130 2.1 50
35.7 11211035.132.0mg/KgAliphatic C9-C12 70-130 1.6 50
10.9 10210311.010.7mg/KgAromatic C9-C10 70-130 0.9 50
97.196.22,5-Dibromotoluene (FID) (S)70-130
85.585.22,5-Dibromotoluene (PID) (S)70-130
Page 42 of 44Date:09/27/2023 07:51 AM
Page 109 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V37916QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V37915
Associated Lab Samples: 95234, 95235, 95236
LRB-V37915 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/15/23 19:1650.011.5<11.5µg/LAliphatic C5-C8
09/15/23 19:1650.025.8<25.8µg/LAliphatic C9-C12
09/15/23 19:1650.04.02<4.02µg/LAromatic C9-C10
09/15/23 19:162,5-Dibromotoluene (FID) (S)88.4 70-130
09/15/23 19:162,5-Dibromotoluene (PID) (S)85.4 70-130
LCS-V37915 LCSD-V37915Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
258 86.086.3259300µg/LAliphatic C5-C8 70-130 0.3 50.0
335 112110330300µg/LAliphatic C9-C12 70-130 1.5 50.0
104 104104104100µg/LAromatic C9-C10 70-130 0.0 50.0
93.887.02,5-Dibromotoluene (FID) (S)70-130
89.577.52,5-Dibromotoluene (PID) (S)70-130
Page 43 of 44Date:09/27/2023 07:51 AM
Page 110 of 113
Quality Control Data
23-258-0006Report No:
Project Description:
Client ID:CES Group
Bullins Grocery
Dry Weight Determination
SW-DRYWT
V37972QC Analytical Batch:
Analysis Method:
Analysis Description:
V 95071-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 09/18/23 16:100.270.970.7%Moisture
V 95305-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 09/18/23 16:106.37.938.45%Moisture
Page 44 of 44Date:09/27/2023 07:51 AM
Page 111 of 113
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-258-0006
CES Group
00012
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 4.2C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:09/15/2023 09:49:44
Special precautions or instructions included?
Comments:
Page 112 of 113
Page 113 of 113
APPENDIX D
SOIL BORING LOG , MONITORING WELL
CONSTRUCTION FORMS AND WELL
PERMITS
CES Project No.: 8076.0123E Boring Number: MW-2 Page: 1 of 1
Site Name: Bullins Grocery Boring Location:

Located east of the former USTs location

Address: 1107 North Main Street,
Walnut Cove, NC 27052
Date: September 14, 2023 Sample Number Lab Sample Sample Recovery (5 Foot Intervals) Depth (feet)

Detailed Soil and Rock Description

PID (PPMV)

Remarks / Notes

0__

5__

(0-5'): Lite brown clay 32.5 No Staining
Odor Present

100%

10__
(5-10’): Dark brown clay 120 No Staining
Odor Present
100%

MW-2 *

15__
(10-15’): Dark brown clay (moist) 225 No Staining
Odor Present 100%

100%
20__(15-20’): Dark brown clay (wet) 96.3 No Staining
No Odor

100%
25__(20-25’): Dark brown clay (wet) 87.7 No Staining
No Odor

100%
30__(25-30’): Dark brown clay (wet) 38.4 No Staining
No Odor
__
* Soil sample collected for laboratory analysis
Note: Stratification lines are approximate; in-situ transition between soil types may be gradual.
Ground Water Data:
Drilling Information:
Drilling Co.: Carolina Soil Investigations, LLC
Water Indication (during boring): N/A Engineer/Geologist: Greg Hans, PMP
Ground Water Depth (after boring): 22.81’ Drilling Method: Geoprobe Augering via Trac Mounted 6712DT
Drill Rig
PID Reading (instrument units): PPMV Sampling Method: 5-foot samples from auger flights
Borehole Depth: 30’
Abandonment: N/A
CES Group Engineers, LLP

3525 Whitehall Park Drive, Suite 150,
Charlotte, NC 28273

CES Project No.: 8076.0123E Boring Number: MW-3 Page: 1 of 1
Site Name: Bullins Grocery Boring Location:

Located southeast of the former USTs
location

Address: 1107 North Main Street,
Walnut Cove, NC 27052
Date: September 14, 2023 Sample Number Lab Sample Sample Recovery (5 Foot Intervals) Depth (feet)

Detailed Soil and Rock Description

PID (PPMV)

Remarks / Notes

0__
*

5__

(0-5'): Lite brown clay 1,369 No Staining
Odor Present

100%

10__
(5-10’): Dark brown clay 1,224 No Staining
Odor Present
100%

MW-3

15__
(10-15’): Dark brown clay 825 No Staining
Odor Present 100%

100%
20__(15-20’): Dark brown clay (moist) 565 No Staining
Odor Present

100%
25__(20-25’): Dark brown clay (moist to wet) 216 No Staining
Odor Present

100%
30__(25-30’): Dark brown clay (wet) 266 No Staining
Odor Present
__
* Soil sample collected for laboratory analysis
Note: Stratification lines are approximate; in-situ transition between soil types may be gradual.
Ground Water Data:
Drilling Information:
Drilling Co.: Carolina Soil Investigations, LLC
Water Indication (during boring): N/A Engineer/Geologist: Greg Hans, PMP
Ground Water Depth (after boring): 26.80’ Drilling Method: Geoprobe Augering via Trac Mounted 6712DT
Drill Rig
PID Reading (instrument units): PPMV Sampling Method: 5-foot samples from auger flights
Borehole Depth: 30’
Abandonment: N/A
CES Group Engineers, LLP

3525 Whitehall Park Drive, Suite 150,
Charlotte, NC 28273

CES Project No.: 8076.0123E Boring Number: MW-4 Page: 1 of 1
Site Name: Bullins Grocery Boring Location:

Located southwest of the former USTs
location

Address: 1107 North Main Street,
Walnut Cove, NC 27052
Date: September 14, 2023 Sample Number Lab Sample Sample Recovery (5 Foot Intervals) Depth (feet)

Detailed Soil and Rock Description

PID (PPMV)

Remarks / Notes

0__

5__

(0-5'): Lite brown clay 32.5 No Staining
Odor Present

100%

10__
(5-10’): Dark brown clay 120 No Staining
Odor Present
100%

MW-4 *

15__
(10-15’): Dark brown clay (moist) 225 No Staining
Odor Present 100%

100%
20__(15-20’): Dark brown clay (moist to wet) 96.3 No Staining
Odor Present

100%
25__(20-25’): Dark brown clay (wet) 87.7 No Staining
Odor Present

100%
30__(25-30’): Dark brown clay (wet) 38.4 No Staining
Odor Present
__
* Soil sample collected for laboratory analysis
Note: Stratification lines are approximate; in-situ transition between soil types may be gradual.
Ground Water Data:
Drilling Information:
Drilling Co.: Carolina Soil Investigations, LLC
Water Indication (during boring): N/A Engineer/Geologist: Greg Hans, PMP
Ground Water Depth (after boring): 24.68’ Drilling Method: Geoprobe Augering via Trac Mounted 6712DT
Drill Rig
PID Reading (instrument units): PPMV Sampling Method: 5-foot samples from auger flights
Borehole Depth: 30’
Abandonment: N/A
CES Group Engineers, LLP

3525 Whitehall Park Drive, Suite 150,
Charlotte, NC 28273

North Carolina Department of Environmental Quality | Division of Water Resources
Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Winston-Salem, North Carolina 27105
336.776.9800

September 6, 2023

Scott Ryals
NCDEQ DWM
1646 Mail Service Center
Raleigh, NC 27699

SUBJECT: MONITORING WELL CONSTRUCTION
PERMIT NO. WM0401479
COUNTY: Stokes
FILE NAME: Bullins Grocery

Dear Mr. Ryals:

In accordance with your application received on September 1, 2023, we are forwarding herewith:

1. Monitoring Well Construction Permit No. WM0401479 for the construction of three (3)
monitoring wells at 1107 N Main Stret, Walnut Cove, NC in Stokes County.

Henceforth, correspondence and data relating to this well shall be designated as specified in the
subject heading above. This Permit will be effective from the date of issuance and shall be subject
to the conditions and limitations as specified therein. If you have any questions regarding this
permit, please contact me or Shuying Wang at [phone].

Sincerely,

Lon T. Snider
Regional Supervisor
Water Quality Regional Operations Section
Division of Water Resources, NCDEQ – WSRO

cc: Greg Hans - CES Group Engineers, LLP (Electronic Copy)
Ghamdan Salim (Electronic Copy)
WSRO E-files

North Carolina Department of Environmental Quality | Division of Water Resources
Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Winston-Salem, North Carolina 27105
336.776.9800

NORTH CAROLINA
DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES – WATER QUALITY REGIONAL OPERATIONS
SECTION

PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL

In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and
other applicable Laws, Rules and Regulations.

PERMISSION IS HEREBY GRANTED TO

NCDEQ DWM UST Section State-Lead Program

FOR THE CONSTRUCTION OF A MONITOR WELL SYSTEM consisting of three (3)
monitoring wells owned by NCDEQ DWM UST Section State-Lead Program. The wells will be
located at 1107 N Main Stret in Walnut Cove, North Carolina, in Stokes County. This Permit is
issued in accordance with the application received on September 1, 2023 in conformity with
specifications and supporting data, all of which are filed with the Department of Environmental
Quality and are considered integral parts of this Permit.

This Permit is for well construction only and does not waive any provision or requirement of any
other applicable law or regulation. Construction of any well under this Permit shall be in strict
compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC
02C .0100), and other State and Local Laws and regulations pertaining to well construction.

If any requirements or limitations specified in this Permit are unacceptable, you have a right to an
adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request
must be in the form of a written petition conforming to Chapter 150B of the North Carolina General
Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh,
North Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding.

This Permit will be effective for one year from the date of its issuance and shall be subject to other
specified conditions, limitations, or exceptions as follows:

1. Issuance of this Permit does not obligate reimbursement from State trust funds, if these
wells are being installed as part of an investigation for contamination from an underground
storage tank or dry cleaner incident.
2. Issuance of this Permit does not supersede any other agreement, permit, or requirement
issued by another agency.
3. The well(s) shall be located and constructed as shown on the attachments submitted as part
of the Permit application.
4. Each well shall have a Well Contractor Identification Plate in accordance with 15A NCAC
02C .0108(o).

North Carolina Department of Environmental Quality | Division of Water Resources
Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Winston-Salem, North Carolina 27105
336.776.9800

5. Well construction records (GW-1) for each well shall be submitted to the Division of Water
Resources’ Information Processing Unit within 30 days of the well completion.
6. When the well is discontinued or abandoned, it shall be abandoned in accordance with 15A
NCAC 02C .0113 and a well abandonment record (GW-30) shall be submitted to the
Division of Water Resources’ Information Processing Unit within 30 days of the well
abandonment.
7. The County Health Department may require a county monitoring well construction permit.
Please contact the health department for their requirements.

Permit issued on 6th day of September 2023

FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

_______________________________________________
Lon T. Snider, Regional Supervisor
Water Quality Regional Operations Section
Division of Water Resources, NCDEQ - WSRO

By Authority of the Environmental Management Commission

Permit No. # WM0401479

STATE OF NORTH CAROLINA
DEPARTMENT OF TRANSPORTATION
ROY COOPER J. ERIC BOYETTE
GOVERNOR SECRETARY

Mailing Address:
NC DEPARTMENT OF TRANSPORTATION
DIVISION NINE / DISTRICT TWO
SILAS CREEK PARKWAY
WINSTON-SALEM, NC 27127
Telephone: [phone]
Fax: [phone]
Customer Service: 1-877-368-4968

Website: ncdot.gov
Location:
375 SILAS CREEK PARKWAY
WINSTON-SALEM, NC 27127

August 30, 2023

Stokes County: NC 89 and US 311

Subject: Right of Way Encroachment Contract – R/W 16.1A – Job Number – E092-085-23-
00439 – Installation of Monitoring Wells

Mr. Matt Sumner, Project Manager
CES Group Engineers, LLP
3525 Whitehall Park Drive, Ste 150
Charlotte, North Carolina 28273

Dear Mr. Sumner:

Attached, for your file, is a copy of the above referenced Right of Way Encroachment Contract,
properly executed. This contract covers the following:

Installation of 3 monitoring wells along NC 89 and US 311 – N Main Street, as shown on the
attached plans.
APPROVED SUBJECT TO: Attached Special Provisions
ENVIRONMENTAL ISSUES AGREEMENT
The encroaching party shall comply with all applicable state and federal environmental regulations,
and shall obtain all necessary state, federal and local environmental permits, including but not
limited to, those related to sediment control, stormwater, wetlands, streams, endangered species,
and historical sites.

Sincerely,

Scott A. Jones, P.E.
DISTRICT ENGINEER

SAJ/REO
cc: Andrew Bennett, P.E. • Stokes County Maintenance Engineer

SPECIAL PROVISIONS – Page 1
R/W 16.1A – CES Group Engineers
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1. Approval may be rescinded upon failure to follow any of the provisions in this permit and
may be considered a violation of the encroachment agreement.

2. The Encroaching party or their contractor shall provide the following notices prior to
construction activity within the NCDOT Right of Way:
a. Three (3) business days advance phone call at telephone [phone] to the
Stokes County Maintenance Engineer.
Failure to provide these notifications prior to beginning construction is subject to the
Division Engineer’s discretion to cease construction activity for this encroachment. NCDOT
reserves the right to cease any construction or maintenance work associated with this
installation by the encroaching party until the construction or maintenance meets the
satisfaction of the Division Engineer or their representative.

3. Prior to beginning work, it is the requirement of the Encroaching Party to contact the
appropriate Utility Companies involved and make arrangements to adjust or relocate any
utilities that conflict with the proposed work.

4. It shall be the responsibility of the encroaching party to determine the location of utilities
within the encroachment area. NCGS § 87-115 through § 87-130 of the Underground Utility
Safety and Damage Prevention Act requires underground utilities to be located by calling
811 prior to construction. The encroaching party shall be responsible for notifying other
utility owners and providing protection and safeguards to prevent damage or interruption to
existing facilities and maintain access to them.

5. The encroaching party shall notify the appropriate municipal office prior to beginning any
work within the municipality’s limits of jurisdiction.

6. This approval and associated plans and supporting documents shall not be interpreted to
allow any design change or change in the intent of the design by the Owner, Design
Engineer, or any of their representatives. Any revisions or changes to these approved plans
or intent for construction must be obtained in writing from the Division Engineer’s office or
their representative prior to construction or during construction, if an issue arises during
construction to warrant changes.

7. NCDOT does not guarantee the right of way on this road, nor will it be responsible for any
claim for damages brought about by any property owner by reason of this installation. It is
the responsibility of the encroaching party to verify the right of way.

8. Encroaching party shall be responsible for obtaining all necessary permanent and/or
temporary construction, drainage, utility and/or sight distance easements.

9. All Right of Way and easements necessary for construction and maintenance shall be
dedicated to NCDOT with proof of dedication furnished to the District Engineer prior to
beginning work.

10. Traffic control shall be coordinated with the Stokes County Maintenance Office at telephone
[phone], prior to construction.

11. WORK ZONE TRAFFIC CONTROL QUALIFICATIONS AND TRAINING PROGRAM

All personnel performing any activity inside the highway right of way are required to be
familiar with the NCDOT Maintenance / Utility Traffic Control Guidelines (MUTCG). No
SPECIAL PROVISIONS – Page 2
R/W 16.1A – CES Group Engineers
E092-085-23-00439
specific training course or test is required for qualification in the Maintenance /Utility
Traffic Control Guidelines (MUTCG).

All flagging, spotting, or operating Automated Flagger Assist Devices (AFAD) inside the
highway right of way requires qualified and trained Work Zone Flaggers. Training for this
certification is provided by NCDOT approved training resources and by private entities that
have been pre-approved to train themselves.

All personnel involved with the installation of Work Zone Traffic Control devices inside the
highway right of way are required to be qualified and trained Work Zone Installers. Training
for this certification is provided by NCDOT approved training resources and by private
entities that have been pre-approved to train themselves.

All personnel in charge of overseeing work zone Temporary Traffic Control operations and
installations inside the highway right of way are required to be qualified and trained Work
Zone Supervisors. Training for this certification is provided by NCDOT approved training
resources and by private entities that have been pre-approved to train themselves.

For questions and/or additional information regarding this training program please refer to
https://connect.ncdot.gov/projects/WZTC/Pages/Training.aspx or call the NCDOT Work
Zone Traffic Control Section [phone].

12. The party of the second part shall employ traffic control measures that are in accordance
with the prevailing federal, state, local, and NCDOT policies, standards, and procedures.
These policies, standards, and procedures include, but are not limited to the following:
a. Manual on Uniform Traffic Control Devices (MUTCD) – North Carolina has
adopted the MUTCD to provide basic principles and guidelines for traffic control
device design, application, installation, and maintenance. North Carolina uses the
MUTCD as a minimum requirement where higher supplemental standards specific to
North Carolina are not established. Use fundamental principles and best practices of
MUTCD (Part 6, Temporary Traffic Control).
b. NCDOT Maintenance / Utility Traffic Control Guidelines – This document enhances
the fundamental principles and best practices established in MUTCD Part 6,
Temporary Traffic Control, incorporating NCDOT-specific standards and details.
It also covers important safety knowledge for a wide range of work zone job
responsibilities.

13. If the Traffic Control Supervisor determines that portable concrete barrier (PCB) is required
to shield a hazard within the clear zone, then PCB shall be designed and sealed by a licensed
North Carolina Professional Engineer. PCB plans and design calculations shall be submitted
to the District Engineer for review and approval prior to installation.

14. Ingress and egress shall be maintained to all businesses and dwellings affected by the project.
Special attention shall be paid to police, EMS and fire stations, fire hydrants, secondary
schools, and hospitals.

15. Traffic shall be maintained at all times. All lanes of traffic are to be open during the hours of
7:00 A.M. to 9:00 A.M. and from 4:00 P.M. to 6:00 P.M. Monday through Friday, during
any time of inclement weather, or as directed by the County Maintenance Engineer. Any
violation of these hours will result in ceasing any further construction by the Encroaching
Party or their contractor.

SPECIAL PROVISIONS – Page 3
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16. Nighttime and weekend operations will NOT be allowed unless written approval is received
from the District Engineer. If nighttime or weekend work is allowed or required, all signs
must be retro-reflective, and a work zone lighting plan must be submitted for approval prior
to construction.

17. Two-way traffic shall be maintained at all times unless designated by the County
Maintenance Engineer. Traffic shall not be rerouted or detoured without the prior written
approval from the County Maintenance Engineer. No utility work will be allowed on state
holidays from 7:00 PM the night before through 9:00 AM the day prior to, following or
during local events without prior approval from the County Maintenance Engineer. If the
construction is within 1000 feet of a school location or on a designated bus route, the
construction shall be coordinated with the school start and end times to avoid traffic delays.

18. Work requiring lane or shoulder closures shall not be performed on both sides of the road
simultaneously within the same area.

19. Any work requiring equipment or personnel within 5 feet of the edge of any travel lane of an
undivided facility and within 10 feet of the edge of any travel lane of a divided facility shall
require a lane closure with appropriate tapers per current NCDOT Roadway Standard
Drawings or MANUAL ON UNIFORM TRAFFIC CONTROL DEVICES.

20. At the discretion of the District Engineer, a traffic control plan shall be developed and
submitted under the seal and signature of a Licensed North Carolina Professional Engineer
prior to construction. The plan shall be specific to the site and adequately detailed. Issues
such as the close proximity to intersections shall be addressed.

21. Any pavement markings that are damaged or obliterated shall be restored by the encroaching
party at no expense to NCDOT.

22. Sidewalk closures shall be installed as necessary. Pedestrian traffic shall be detoured around
these closures and shall be signed appropriately and in accordance with The American with
Disabilities Act Accessibility Guidelines. The encroaching party must adhere to the
guidelines for accommodating pedestrians in encroachment work zones as described in the
NCDOT Pedestrian Work Zone Accommodations Training found at
https://www.youtube.com/watch?v=AOuYa5IW3dg&feature=youtu.be

23. The encroaching party shall comply with all applicable Federal, State and local
environmental regulations and shall obtain all necessary Federal, State and local
environmental permits, including but not limited to, those related to sediment control,
stormwater, wetland, streams, endangered species and historical sites. Additional information
can be obtained by contacting the NCDOT Roadside Environmental Engineer regarding the
North Carolina Natural Heritage Program or the United States Fish and Wildlife Services.
Contact the Division Roadside Environmental Engineer’s Office at 336-896-2380.

24. All erosion control devices and measures shall be constructed, installed, maintained, and
removed by the Encroacher in accordance with all applicable Federal, State, and Local laws,
regulations, ordinances, and policies. Permanent vegetation shall be established on all
disturbed areas in accordance with the recommendations of the Division Roadside
Environmental Engineer. All areas disturbed (shoulders, ditches, removed accesses, etc.)
shall be graded and seeded in accordance with the latest NCDOT Standards Specifications
for Roads and Structures and within 15 calendar days with an approved NCDOT seed
mixture (all lawn type areas shall be maintained and reseeded as such). Seeding rates per
acre shall be applied according to the Division Roadside Environmental Engineer. Any plant
SPECIAL PROVISIONS – Page 4
R/W 16.1A – CES Group Engineers
E092-085-23-00439
or vegetation in the NCDOT planted sites that is destroyed or damaged as a result of this
encroachment shall be replaced with plants of like kind or similar shape.

25. The contractor shall not begin the construction until after the traffic control and erosion
control devices have been installed to the satisfaction of the County Maintenance Engineer
or their agent.

26. An executed copy of the encroachment agreement, provisions and approved plans shall be
present at the construction site at all times. If safety or traffic conditions warrant such an
action, NCDOT reserves the right to further limit, restrict or suspend operations within the
right of way.

27. The Encroaching Party and/or their Contractor shall comply with all OSHA requirements. If
OSHA visits the work area associated with this encroachment, the District Office shall be
notified by the encroaching party immediately if any violations are cited.

28. All disturbed areas are to be fully restored to current NCDOT minimum roadway standards
or as directed by the Division Engineer or their representative. Disturbed areas within
NCDOT Right-of-Way include, but not limited to, any excavation areas, pavement removal,
drainage or other features.

29. The encroaching party shall notify the County Maintenance Engineer or their representative
immediately in the event any drainage structure is blocked, disturbed or damaged. All
drainage structures disturbed, damaged or blocked shall be restored to its original condition
as directed by the Division Engineer or their representative.

30. Unless specified otherwise, during non-working hours, equipment shall be located away from
the job site or parked as close to the right of way line as possible and be properly barricaded
in order not to have any equipment obstruction within the Clear Recovery Area. Also, during
non-working hours, no parking or material storage shall be allowed along the shoulders of
any state-maintained roadway.

31. Right of Way monuments disturbed during construction shall be referenced by a registered
Land Surveyor and reset after construction.

32. All Traffic signs moved during construction shall be reinstalled as soon as possible to the
satisfaction of the Division Traffic Engineer or their representative.

33. All driveways disturbed during construction shall be returned to a state comparable with the
condition of the driveways prior to construction.

34. If the approved method of construction is unsuccessful and other means are required, prior
approval must be obtained through the District Engineer before construction may continue.

35. All traffic control, asphalt mixes, structures, construction, workmanship and construction
methods, and materials shall be in compliance with the most-recent versions of the following
resources: ASTM Standards, Manual on Uniform Traffic Control Devices, NCDOT Utilities
Accommodations Manual, NCDOT Standard Specifications for Roads and Structures,
NCDOT Roadway Standard Drawings, NCDOT Asphalt Quality Management System
manual, and the approved plans.

36. Excavation material shall not be placed on pavement.

SPECIAL PROVISIONS – Page 5
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37. It is the responsibility of the encroaching party or their contractor to prevent any mud/dirt
from tracking onto the roadway. Any dirt which may collect on the roadway pavement from
equipment and/or truck traffic on site shall be immediately removed to avoid any unsafe
traffic conditions.

38. Any pavement damaged because of settlement of the pavement or damaged by equipment
used to perform encroachment work, shall be re-surfaced to the satisfaction of the District
Engineer. This may include the removal of pavement and a 50’ mechanical overlay. All
pavement work and pavement markings (temporary and final) are the responsibility of the
Encroaching Party.

39. The Encroaching party shall notify the District Engineer’s office within 2 business days after
construction is complete. The County Maintenance Engineer may perform a construction
inspection. Any deficiencies may be noted and reported to the encroaching party to make
immediate repairs or resolve any issues to restore the right-of-way to a similar condition
prior to construction, including pavement, signage, traffic signals, pavement markings,
drainage, structures/pipes, or other highway design features.

40. If the actual construction differs from the approved plans associated with this encroachment,
a copy of “as-built” plans shall be submitted to the District Engineer’s office in a PDF format
and in a current ESRI GIS format within 4 weeks of construction.

FORM R/W 16.1A (Revised February 2021)
STATE OF NORTH CAROLINA
ROUTE PROJECT COUNTY OF
DEPARTMENT OF TRANSPORTATION
-AND-
RIGHT OF WAY ENCROACHMENT AGREEMENT
FOR NON-UTILITY ENCROACHMENTS ON
PRIMARY AND SECONDARY HIGHWAYS
THIS AGREEMENT, made and entered into this the day of , 20 , by and between the Department
of Transportation, party of the first part; and
party of the second part,
W I T N E S S E T H
THAT WHEREAS, the party of the second part desires to encroach on the right of way of the public road designated as
Route(s) , located
with the construction and/or erection of:
WHEREAS, it is to the material advantage of the party of the second part to effect this encroachment, and the
party of the first part in the exercise of authority conferred upon it by statute, is willing to permit the encroachment
within the limits of the right of way as indicated, subject to the conditions of this agreement;
NOW, THEREFORE, IT IS AGREED that the party of the first part hereby grants to the party of the second
part the right and privilege to make this encroachment as shown on attached plan sheet(s), specifications and
special provisions which are made a part hereof upon the following conditions, to wit:
That the said party of the second part binds and obligates himself to install and maintain the encroaching facility in such safe
and proper condition that it will not interfere with or endanger travel upon said highway, nor obstruct nor interfere with the proper
maintenance thereof, to reimburse the party of the first part for the cost incurred for any repairs or maintenance to its roadways
and structures necessary due to the installation and existence of the facilities of the party of the second part, and if at any time the
party of the first part shall require the removal of or changes in the location of the said facilities, that the said party of the second
part binds himself, his successors and assigns, to promptly remove or alter the said facilities, in order to conform to the said
requirement, without any cost to the party of the first part.
That the party of the second part agrees to provide during construction and any subsequent maintenance proper signs, signal
lights, flagmen and other warning devices for the protection of traffic in conformance with the latest Manual on Uniform Traffic
Control Devices for Streets and Highways and Amendments or Supplements thereto. Information as to the above rules and
regulations may be obtained from the Division Engineer of the party of the first part.
That the party of the second part hereby agrees to indemnify and save harmless the party of the first part from all damages
and claims for damage that may arise by reason of the installation and maintenance of this encroachment.
It is clearly understood by the party of the second part that the party of the first part will assume no responsibility for any
damage that may be caused to such facilities, within the highway rights of way limits, in carrying out its construction and
maintenance operations.
That the party of the second part agrees to restore all areas disturbed during installation and maintenance to the satisfaction of
the Division Engineer of the party of the first part. The party of the second part agrees to exercise every reasonable precaution
during construction and maintenance to prevent eroding of soil; silting or pollution of rivers, streams, lakes, reservoirs, other water
impoundments, ground surfaces or other property; or pollution of the air. There shall be compliance with applicable rules and
regulations of the North Carolina Division of Environmental Management, North Carolina Sedimentation Control Commission, and
with ordinances and regulations of various counties, municipalities and other official agencies relating to pollution prevention and
control. When any installation or maintenance operation disturbs the ground surface and existing ground cover, the party of the
second part agrees to remove and replace the sod or otherwise reestablish the grass cover to meet the satisfaction of the Division
Engineer of the party of the first part.
That the party of the second part agrees to assume the actual cost of any inspection of the work considered to be necessary
by the Division Engineer of the party of the first part.
That the party of the second part agrees to have available at the encroaching site, at all times during construction, a copy of
this agreement showing evidence of approval by the party of the first part. The party of the first part reserves the right to stop all
work unless evidence of approval can be shown.
Provided the work contained in this agreement is being performed on a completed highway open to traffic; the party of the
second part agrees to give written notice to the Division Engineer of the party of the first part when all work contained herein has
been completed. Unless specifically requested by the party of the first part, written notice of completion of work on highway
projects under construction will not be required.
That in the case of noncompliance with the terms of this agreement by the party of the second part, the party of the first part
reserves the right to stop all work until the facility has been brought into compliance or removed from the right of way at no cost to
the party of the first part.
That it is agreed by both parties that this agreement shall become void if actual construction of the work contemplated herein
is not begun within one (1) year from the date of authorization by the party of the first part unless written waiver is secured by the
party of the second part from the party of the first part.
NC HWY 89 E and US HWY 311 Bullins Grocery Stokes
CES Group Engineers, LLP
3525 Whitehall Park Drive, Ste 150
7 August 23
CES Group Engineers, LLP
NC HWY 89 E and US HWY 311/N Main Street (the intersection)at 1107 N Main Street, Walnut Cove, Stokes County, North
Carolina 27052.
three monitoring wells outside the property line and in the NCDOT ROW on the shoulder of N
Main Street and on the shoulder of NC HWY 89 E (see figure with proposed monitoring wells).
Charlotte, NC 28273
R/W (161A) : Party of the Second Part certifies that this agreement is true and accurate copy of the form
R/W (161A) incorporating all revisions to date.
IN WITNESS WHEREOF, each of the parties to this agreement has caused the same to be executed the day and
year first above written.
DEPARTMENT OF TRANSPORTATION
BY:
DIVISION ENGINEER
ATTEST OR WITNESS:
Second Party
INSTRUCTIONS
When the applicant is a corporation or a municipality, this agreement must have the corporate seal and
be attested by the corporation secretary or by the empowered city official, unless a waiver of corporate
seal and attestation by the secretary or by the empowered City official is on file in the Raleigh office of the
State Utilities Manager. In the space provided in this agreement for execution, the name of the
corporation or municipality shall be typed above the name, and title of all persons signing the agreement
should be typed directly below their signature.
When the applicant is not a corporation, then his signature must be witnessed by one person. The
address should be included in this agreement and the names of all persons signing the agreement
should be typed directly below their signature.
This agreement must be accompanied, in the form of an attachment, by plans or drawings showing the
following applicable information:
1.All roadways and ramps.
2.Right of way lines and where applicable, the control of access lines.
3.Location of the proposed encroachment.
4.Length and type of encroachment.
5.Location by highway survey station number. If station number cannot be obtained, location
should be shown by distance from some identifiable point, such as a bridge, road,
intersection, etc. (To assist in preparation of the encroachment plan, the Department’s
roadway plans may be seen at the various Highway Division Offices, or at the Raleigh
office.)
6.Drainage structures or bridges if affected by encroachment.
7.Typical section indicating the pavement design and width, and the slopes, widths and
details for either a curb and gutter or a shoulder and ditch section, whichever is applicable.
8.Horizontal alignment indicating general curve data, where applicable.
9.Vertical alignment indicated by percent grade, P.I. station and vertical curve length, where
applicable.
10.Amount of material to be removed and/or placed on NCDOT right of way, if applicable.
11.Cross-sections of all grading operations, indicating slope ratio and reference by station
where applicable.
12.All pertinent drainage structures proposed. Include all hydraulic data, pipe sizes, structure
details and other related information.
13.Erosion and sediment control.
14.Any special provisions or specifications as to the performance of the work or the method of
construction that may be required by the Department must be shown on a separate sheet
attached to encroachment agreement provided that such information cannot be shown on
plans or drawings.
15.The Department’s Division Engineer should be given notice by the applicant prior to actual
starting of installation included in this agreement.
16.Method of handling traffic during construction where applicable.
17.Scale of plans, north arrow, etc.
Matt Sumner
Environmental Scientist/Project Manager
CES Group Engineers, LLP
8-8-2023
DISTRICT ENGINEER
DRAWN BY: BN
CHECKED BY: GH
PROJECT NUMBER:
8076.0123E
DRAWING TITLE:
SHEET NUMBER:
SEAL:
PROJECT DESCRIPTION:Proposed Monitoring Well LocationsCES GROUP ENGINEERS, LLP
NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net
DATE: 04/04/2023
SCALE : 1" = 20'
WELL CONSTRUCTION RECORD (GW-1)

4. Date Well(s) Completed: Well ID#
5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient)
N W
6.Is(are) the well(s): Permanent or Temporary
7. Is this a repair to an existing well: Yes or No
If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8.For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wellsdrilled:
9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Static water level below top of casing: (ft.) If water level is above casing, use “+”
11. Borehole diameter: (in.)
12.Well construction method: (i.e. auger, rotary, cable, direct push, etc.)
22.Certification:
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Site diagram or additional well details: You may use the back of this page to provide additional well site details or wellconstruction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well construction to the following:
Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following:
Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed.
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018
Print Form
For Internal Use Only:
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
NC Well Contractor Certification Number
Carolina Soil Investigations, LLC
Company Name
2.Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3.Well Use (check well use):
14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
Water Supply Well:
Municipal/Public
Residential Water Supply (single)
Residential Water Supply (shared)
Wells > 100,000 GPD
Agricultural
Geothermal (Heating/Cooling Supply)
Industrial/Commercial Irrigation
17. SCREENFROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUTFROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
Non-Water Supply Well:
Monitoring Recovery
ft. ft.
ft. ft.
Injection Well: Aquifer Recharge Groundwater Remediation
Aquifer Storage and Recovery Salinity Barrier
Aquifer Test Stormwater Drainage
Experimental Technology Subsidence Control
Geothermal (Closed Loop) Tracer
Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks)
ft. ft.
19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS
1.Well Contractor Information:
___________________________________________________________
Well Contractor Name