Loading...
HomeMy WebLinkAboutWS-3254_9547_CA_RPTS_20220729ANNUAL MONITORING REPORT Jerry’s Place (Incident # 9547) 983 US Highway 21 State Road, Surry County, North Carolina July 29, 2022 Terracon Project No. 75207118 Prepared for: North Carolina Department of Environmental Quality Division of Waste Management Raleigh, North Carolina Prepared by: Terracon Consultants, Inc. Greensboro, North Carolina Terracon Consultants, Inc. 7327-G West Friendly Avenue Greensboro, NC 27410 P 336-854-8135 F 336-365-7020 terracon.com July 29, 2022 Mr. Herbert Berger, P.G. North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Email: Herbert.Berger@ncdenr.gov Re: Annual Monitoring Report Jerry’s Place 983 US Highway 21 State Road, Surry County, North Carolina UST Incident Number: 9547 Terracon Project No. 75207118 Dear Mr. Berger: Terracon Consultants, Inc. (Terracon) is pleased to submit this Annual Monitoring Report for the above referenced property. This report has been prepared in general accordance with North Carolina Department of Environmental Quality (NCDEQ), UST Section Corrective Action Guidelines, dated January 19, 2021 and Task Authorization No. TA-02, approved on May 24, 2022. If you have any questions regarding this report or the assessment activities, please contact us at 336-854-8135. Sincerely, Terracon Consultants, Inc. Laura R. Elliott, P.G. M. Neal McElveen, P.E. Senior Geologist Principal/Senior Consultant F. Chris Driscoll, P.G. Project Geologist Enclosures Table of Contents A. SITE INFORMATION .............................................................................................................. 1 B. EXECUTIVE SUMMARY ........................................................................................................ 2 C. SITE HISTORY AND CHARACTERIZATION ........................................................................ 2 C.1 Site Setting ........................................................................................................................ 3 C.2 Release Summary ............................................................................................................. 3 C.3 Previous Investigations ................................................................................................... 3 C.4 Water Supply Wells .......................................................................................................... 4 C.5 Surface Water .................................................................................................................... 4 D. ASSESSMENT INFORMATION ............................................................................................. 4 D.1 Site Geology and Hydrology ........................................................................................... 4 D.2 Sampling Activities ........................................................................................................... 6 D.3 LNAPL Evaluation ............................................................................................................. 6 D.4 Groundwater Sampling Activities ................................................................................... 6 D.5 Analytical Results ............................................................................................................. 6 E. AQUIFER TESTING ................................................................................................................ 7 F. GROUNDWATER MODELING ............................................................................................... 8 E. CONCLUSIONS AND RECOMMENDATIONS .................................................................... 11 F. REFERENCES ...................................................................................................................... 12 EXHIBITS Exhibit 1: Topographic Map Exhibit 2: Site Diagram Exhibit 3: Water Supply Well Location Map Exhibit 4: Groundwater Elevation Contour Map (June 2022) Exhibit 5: Groundwater Sample Analytical Results (June 2022) Exhibit 6: Mann Kendall Analysis – RW-1 (BTEX) Exhibit 7: Mann Kendall Analysis – RW-1 (Selected Constituents) Exhibit 8: Mann Kendall Analysis – MW-2 (BTEX) Exhibit 9: Mann Kendall Analysis – RW-2 (Selected Constituents) Table of Contents (Continued) TABLES Table 1: Water Supply Well Information Table 2: Monitoring Well Construction Details and Groundwater Elevation Data Table 3: Summary of Groundwater Analytical Results Table 4: Summary of Historical Groundwater Analytical Results APPENDICES Appendix A: Field Notes Appendix B: Laboratory Analytical Results and Chain of Custody Form Appendix C: AQTESOLV Results Appendix D: RBCA Toolkit Model Results Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 1 ANNUAL MONITORING REPORT A. SITE INFORMATION Date of Report: July 29, 2022 NCDEQ Incident No: 9547 UST #: WS-3254 Site Name: Jerry’s Place Site Location: 983 US Highway 21 State Road, Surry County, North Carolina Latitude: N: 36°18’52” Longitude: W: 80°51’38” UST Owner/Operator: Jerry’s Place Current Property Owner: Matthew Kennedy and Michael Maher 983 US Highway 21 State Road, Surry County, North Carolina Consultant: Terracon Consultants, Inc. (Contact: Laura Elliott) 7327-G West Friendly Avenue Greensboro, North Carolina 27410 (336) 854-8135 Laboratory: Pace National Center for Testing and Innovation (NCDEQ No. 375) 12065 Lebanon Road Mt. Juliet, Tennessee 01028 (800) 767-5859 Release Information: Release Date: 1992 Estimated Quantity: Unknown Cause of Release: Underground Storage Tank (UST) System, Former USTs: four 4,000-gallon gasoline USTs Currently Active Tanks: None Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 2 I, Laura R. Elliott, P.G., a Licensed Geologist for Terracon Consultants, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. Laura R. Elliott, P.G. NC License No. 2271 Terracon Consultants, Inc. is licensed to practice geology and engineering in North Carolina. The certification numbers of the corporation are C-367 and F-0869, respectively. B. EXECUTIVE SUMMARY Jerry’s Place, the subject property located at 983 US Highway 21, is situated on a 1.58-acre parcel (Surry County Parcel No. 495301186476) in State Road, North Carolina. The facility reportedly operated four 4,000-gallon gasoline underground storage tanks (USTs) which were removed from the site in 1992. At the direction of the NCDEQ, Terracon mobilized to the site on June 10, 2022, to conduct slug testing on three monitoring wells in order to model groundwater influence from the site. Terracon remobilized to the site on June 16, 2022, to collect groundwater samples from eight monitoring wells (MW-2/RW-2, MW-3/RW-3, MW-4/RW-4, MW-5, RW-5, MW-6, MW-7, and MW-8) for analysis by EPA Method 6200. Based on information obtained during the completion of these assessment activities, Terracon provides the following findings and conclusions:  Several petroleum constituents were detected at concentrations exceeding the 2L Standards but below the GCLs in groundwater samples from wells MW-2/RW-2 and MW-3/RW-3.  Multiple petroleum constituents were also detected in groundwater samples from wells MW-2/RW-2, MW-3/RW-3, and RW-5 at concentrations exceeding the laboratory detection limits but below the 2L Standards.  No target compounds were detected above laboratory detection limits in samples collected from monitoring wells MW-4/RW-4, RW-5, MW-6, MW-7, or MW-8.  Measurable thicknesses of LNAPL were not observed in the monitoring wells gauged.  Groundwater flow was estimated, based on groundwater elevation data, to be toward the northeast, east, and southeast.  The biodegradation model appears to simulate contaminant transport and degradation between RW-5 and MW-5 accurately, with the exception of the model Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 3 underpredicting the concentrations of contaminants ethylbenzene and 1,2,4- trimethylbenzene.  Based on the biodegradation model, it does not appear likely that on-site contaminant concentrations will impact water supply well WSW-5 or WSW-6, or other supply wells in the future. Based on the data presented in this Annual Monitoring Report, Terracon recommends the following activities be completed at the site:  Based on the results of the biodegradation model, the incident may be closed with a Notice of Residual Petroleum (NORP) and a groundwater use restriction. C. SITE HISTORY AND CHARACTERIZATION This Monitoring Report was prepared in response to a request by Mr. Herbert Berger, P.G., Incident Manager with the NCDEQ Division of Waste Management, Trust Fund Branch. The report was prepared in general accordance with 15A NCAC 2L .0115 regulations and the NCDEQ UST Section Corrective Action Guidelines dated January 19, 2021, under the supervision of Ms. Laura Elliott, a North Carolina licensed geologist (North Carolina License No. 2271). The purpose of this Monitoring Report is to present the current status of the groundwater quality at the Jerry’s Place site located at 983 US Highway 21 in State Road, Surry County, North Carolina (Exhibit 1). Terracon completed this report to summarize the findings of groundwater sampling activities performed on June 10 and June 16, 2022, and to model the likelihood of petroleum- impacted groundwater onsite reaching any nearby water supply wells, based on hydraulic conductivities collected in the field during this TA. C.1 Site Setting Jerry’s Place, the subject property located at 983 US Highway 21, is situated on a 1.58-acre parcel (Surry County Parcel No. 495301186476) in State Road, North Carolina (Exhibit 1). The facility reportedly operated four 4,000-gallon gasoline USTs which were removed from the site in 1992. The site is currently occupied by commercial businesses (Exhibit 2). C.2 Release Summary According to prior reports, four 4,000-gallon gasoline USTs were removed from the site in 1992. During closure activities, LNAPL was observed flowing into a test pit that was excavated to a depth of approximately 19 feet below ground surface (bgs). Approximately 1,029 tons of petroleum contaminated soil was subsequently excavated during the UST closure activities. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 4 C.3 Previous Investigations According to information included in the incident folder, four 4,000-gallon gasoline USTs were removed from the site in 1992. Eight monitoring wells (MW-1 through MW-8) and two recovery wells (RW-5 and RW-6) were installed between 1993 and 1994. On-site monitoring wells were sampled in 1993, 2009, 2010, 2011, 2014, 2015, 2018, and 2019. The contaminant concentrations appear to have been decreasing since 1993. A previous consultant conducted a free product/vapor recovery event on July 29, 1996. A mobile multiphase extraction (MMPE) event was later conducted in 2001. According to a Groundwater Monitoring Report completed by a previous consultant and dated January 7, 2020, methyl tert-butyl ether (MTBE) has been detected in the on-site water supply well (WSW-5) since 2009 at a concentration below its 2L Standard. C.4 Water Supply Wells According to a Groundwater Monitoring Report prepared by Engineering Consulting Services (ECS) and dated September 16, 2014, sixteen water supply wells were identified within 1,000 feet of the site. A copy of the ECS water supply well location map is presented as Exhibit 3, and Table 1 presents information on the water supply wells located within approximately 500 feet of the site. Water supply well WSW-5 is located on the site, approximately 90 feet southwest and cross- gradient from the source area. Groundwater samples from well WSW-5 have not contained detected concentrations of petroleum constituents since 2018. Well WSW-6 is located approximately 350 feet north and upgradient of the source area of the release and has not contained detected concentrations of petroleum constituents since at least 2009. Wells WSW-3 and WSW-4 are located approximately 550 to 600 feet southwest and cross-gradient relative to the source area of the release. The wells previously contained detected concentrations of petroleum products including MTBE; however, petroleum constituents have not been detected in groundwater samples from the wells since at least 2009. Municipal water is not available to the site and surrounding properties. C.5 Surface Water Based on review of the USGS Topographic Map, the closest body of water is intermittent Camp Creek (Grass Creek, Stream Index 12-62-14, in the Yadkin Pee-Dee River Basin) located approximately 225 feet east of the site. Surface water intakes are not known to be located within 1,500 feet of the source area of the release. Nearby surface water bodies are shown on Exhibit 1. D. ASSESSMENT INFORMATION D.1 Site Geology and Hydrology The following resources were reviewed to evaluate site-specific geological and hydrogeological characteristics. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 5 Elkin N Quadrangle, North Carolina, USGS 7.5-minute series topographic map, dated 2000 (Exhibit 1). Geologic Map of North Carolina, dated 1985. Soil Survey of Surry County, North Carolina, US Department of Agriculture, Natural Resources Conservation Service, Web Soil Survey via the Internet, http://websoilsurvey.nrcs.usda.gov/app/. The site is located within the Alligator Back Formation of the Blue Ridge Belt in the Piedmont Physiographic Province. The Piedmont Physiographic Province generally consists of low to medium elevation, rounded hills and long rolling northeast to southwest trending ridges with incised creeks and river channels. Rocks in the site vicinity consist of mica schist and phyllite. In-place chemical and physical weathering of parent rocks typically forms residual soils in the Piedmont region. Weathering is facilitated by the presence of fractures, joints, and less resistant minerals in the rock. In areas not altered by erosion, alluvial deposition or the activities of man, the typical residual soil profile consists of clay-rich unconsolidated materials at the surface, transitioning to sandy silts and silty sands at depth. Typically, the boundary between soil and bedrock is not sharply defined. This transitional zone is termed “partially weathered rock”. Information obtained from the Surry County Soil Survey depicts soils on the site as Fairview sandy clay loam (FeC2). The FeC2 is found on 8 to 15 percent slopes and consists of sandy clay loams that originated from weathered schists and other micaceous metamorphic rock. In the Piedmont, groundwater generally occurs in pore spaces within soils and in the structural features present in the underlying rock (i.e. joints, fractures, and faults). Recharge to the water table is primarily by precipitation infiltrating the surficial soils and percolating downward under the influence of gravity to the water table. Typically, the water table is not a level surface, but a subdued reflection of the land surface. The depth to the water table is not consistent and is dependent upon several factors that include the amount of rainfall, permeability of the soil, the extent of fracturing in the underlying rock and the influences of groundwater pumping. Groundwater typically flows in directions sub-parallel to the ground surface and under the influence of gravity to discharge points such as surface water features and the toes of slopes or natural springs. Fluctuations in the depth of the water table can be expected depending on variations in precipitation, surface water run-off and other factors not evident at the time of our subsurface exploration. Normally, the highest levels of the water table occur in late winter and spring and the lowest levels occur in the late summer and fall. Based on groundwater elevation measurements taken in June 2022, groundwater is estimated to flow radially from the site toward the northeast, east, and southeast on site. D.2 Sampling Activities Terracon mobilized to the site on June 10, 2022 to conduct slug testing for hydraulic conductivity on three site monitoring wells. Terracon remobilized to the site on June 16, 2022 to collect groundwater Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 6 samples from the site monitoring wells (MW-2/RW-2, MW-3/RW-3, MW-4/RW-4, MW-5, RW-5, MW- 6, MW-7, and MW-8). The approximate locations of the wells are depicted on Exhibit 2 and copies of Terracon’s field notes are included in Appendix A. D.3 LNAPL Evaluation Measurable thicknesses of LNAPL were not encountered in the monitoring wells during this assessment. D.4 Groundwater Sampling Activities Prior to sample collection, Terracon gauged the groundwater elevations in the monitoring wells using a decontaminated electronic water level meter. The approximate locations of the wells are shown on Exhibit 2 and monitoring well construction details and groundwater elevation measurements are provided in Table 2. Groundwater flow was estimated, based on groundwater elevation data, to be directed radially from the site to the northeast, east, and southeast. Groundwater elevations and groundwater elevation contours are depicted on Exhibit 4. The monitoring wells were purged with a submersible pump using low flow sampling techniques (i.e., <200 milliliters per minute) prior to sampling. The following parameters were periodically measured during purging: pH, temperature, oxidation reduction potential (ORP), dissolved oxygen (DO), and conductivity. Purging was considered complete once the field parameters stabilized. Monitoring wells MW-7 and MW-8 did not have adequate volume present to purge the wells; samples were collected with new, disposable bailers without purging or collecting parameter readings. The groundwater samples were then collected into laboratory-supplied glassware, labeled and stored in an ice-packed cooler. The samples, along with chain-of-custody documentation, were delivered to Pace National in Mt. Juliet, Tennessee under a standard turnaround time for analysis of volatile organic compounds (VOCs) by EPA Method 6200B including xylenes, MTBE, EDB, and di- isopropyl ether (IPE). Copies of field notes including groundwater parameters are provided in Appendix B. D.5 Analytical Results Based on the laboratory analytical report, several petroleum constituents were identified at concentrations exceeding the established 2L Standards in groundwater samples collected from monitoring wells MW-2/RW-2 and MW-3/RW-3 during this sampling event.  Benzene [234 µg/L], naphthalene [184 µg/L], n-propylbenzene [144 µg/L], 1,2,4- trimethylbenzene [650 µg/L], and total xylenes [752 µg/L] were detected in the groundwater sample from monitoring well MW-2/RW-2 at concentrations exceeding the 2L Standards but below the GCLs. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 7  Benzene [14.8 µg/L], naphthalene [179 µg/L], n-propylbenzene [157 µg/L], and 1,2,4-trimethylbenzene [384 µg/L] were detected in the groundwater sample from monitoring well MW-3/RW-3 at concentrations exceeding the 2L Standards but below the GCLs.  Multiple petroleum constituents were also detected in groundwater samples from wells MW-2/RW-2, MW-3/RW-3, and MW-5 at concentrations exceeding the laboratory detection limits but below the 2L Standards.  No petroleum constituents were detected above laboratory detection limits in groundwater samples collected from monitoring wells MW-4/RW-4, RW-5, MW-6, MW-7, or MW-8. Summaries of the groundwater analytical results are included on Table 2 and Exhibit 5. The historical groundwater analytical results summaries are in Table 4. A copy of the laboratory analytical report is provided in Appendix B. E. AQUIFER TESTING To evaluate aquifer properties (i.e., aquifer permeability and the potential suitability of contaminant migration), slug tests were conducted on June 10, 2022 at three on-site monitoring well locations (MW-2/RW-2, MW-3/RW-3, and RW-5) by introducing a solid slug of known volume into each well and measuring the resulting change in head following the introduction (i.e., “slug-in”). A Solinst Levelogger pressure transducer was used to monitor the change in head within the wells. The tests continued until water levels recovered to at least 95 percent of the initial static level within a reasonable time period. After the water level had returned to the approximate static level, the slug was removed and the resulting change in head was also monitored (i.e. “slug-out” test). Hydraulic conductivity was then estimated from slug test results using AQTESOLV Pro software. Terracon’s field notes are provided in Appendix A. Aquifer slug test summary reports and AQTESOLV data reports are provided in Appendix C. Time versus water displacement data collected from slug-in (falling head) and slug-out (rising head) tests conducted at monitoring wells MW-2/RW-2, MW-3/RW-3, and RW-5 were analyzed using the Bower and Rice (1976) Slug Test Solution for unconfined aquifers. The falling and rising head slug tests yielded the following hydraulic conductivities (K): Slug Test K (feet/minute) MW-2/RW-2 (slug-in) 7.21 x 10-4 MW-2/RW-2 (slug-out) 6.57 x 10-4 MW-3/RW-3 (slug-in) 7.55 x 10-4 MW-3/RW-3 (slug-out) 5.99 x 10-4 RW-5 (slug-in) 3.30 x 10-4 RW-5 (slug-out) 4.73 x 10-4 Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 8 These K values correspond to a range of 173.4 feet per year (ft/yr) to 396.8 ft/yr with an average of 309.6 ft/yr. This range of hydraulic conductivity values falls within the conductive published range for silts in Domenico and Schwartz, 1990. Previous borings drilled on the property indicated the lithology was dominantly composed of clayey silt to silt, which is often seen in the Piedmont of North Carolina. Given the agreement seen in fate and transport results with real world concentration data using the average calculated hydraulic conductivity (see below), the calculated hydraulic conductivities appear representative of on-site subsurface conditions. F. GROUNDWATER MODELING Terracon conducted a fate and transport evaluation of petroleum constituents detected in the on- site monitoring wells to determine the potential for the constituents to migrate toward nearby water supply wells WSW-5 and WSW-6, which are located approximately 90 feet south and 350 feet north from the source area, respectively. Terracon utilized available site-specific data (contaminant concentrations, hydraulic gradient, and hydraulic conductivity) to simulate natural attenuation and transport of the contaminant plume. The model simulations to evaluate solute transport was completed using the RBCA Tool Kit for Chemical Releases® Version 2.6. Two different models were utilized: 1) a model simulating biodegradation through the use of 1st order decay constants for contaminants of concern (i.e. decay half-lives); and 2) a dispersion only model. Because the contaminant concentrations at the site in the source area at RW-5 have generally been stable or exhibit no trend since 1993 (as demonstrated by Mann-Kendall statistical analysis; see Exhibits 6 and 9), Terracon believes the model that simulates biodegradation is more representative of the actual physical processes occurring at the site. The site-specific parameters used for the models and a discussion of the results are presented below. Site Specific Model Inputs (RBCA Tool Kit) Terracon utilized site-specific hydraulic conductivity data from the slug testing performed by Terracon in June 2022 to simulate natural attenuation and transport of the contaminant plume. The model simulations to evaluate solute transport were completed using the RBCA Toolkit. The average hydraulic conductivity was estimated at 309.6 ft/yr for the site. The average hydraulic gradient, 0.0363 ft/ft, was estimated for the site based on the historic groundwater elevations of MW-2/RW-2 and MW-5 (average from ten previous sampling events). Using an estimated porosity of 0.38, the seepage velocity used by the model was calculated as approximately 23 ft per yr. Site specific data for soil bulk density, the partition coefficient, and fraction organic carbon were not available, so the default values were used in the model simulation. The depth to water in the source area is approximately 20 feet bls and sampler refusal (noted as 50 blows over any six-inch increment) was noted in previous borings at approximately 30 feet bls (indicative of partially weather rock). The elevation difference between the site (1,285 ft) and Camp Creek (1,255 ft) to the east is approximately 30 ft. Based on the above, the plume thickness at the Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 9 source area was estimated to be approximately 20 feet by assuming that the aquifer extends an additional 10 feet below the creek elevation (from 30 to 40 feet bls, consistent with the creek elevation) prior to the occurrence of bedrock. Based on Mann-Kendall statistical analysis (see Exhibits 6 through 9), contaminant concentrations at the source area are either decreasing or exhibit no trend. As such, a model simulating biodegradation for contaminants of concern appears appropriate. Initial Model Calibration (Modeling Transport from RW-5 to MW-5) Prior to evaluating transport from the source area to WSW-5 and WSW-6, Terracon utilized site- specific concentration data from RW-5 and MW-5 to calibrate the desired model inputs and evaluate how well the biodegradation model can reproduce real world data. Concentrations of benzene, toluene, ethylbenzene, total xylenes, isopropylbenzene, MTBE, naphthalene, and 1,2,4- trimethylbenzene detected within RW-5 during the October 2009 sampling event were used as beginning concentrations. Contaminant concentrations at MW-5, located approximately 215 feet directly down-gradient from RW-5, were calculated using the model. MW-5 Concentrations: Fate and Transport Model Results vs. June 2022 MW-5 Analytical Data Constituent RBCA-Calculated Concentrations (MW-5) June 2022 (MW-5) Benzene 8.8 <1 Toluene 1.5 x 10-10 <1 Ethylbenzene 0.1 1.26 Xylenes (Total) 2.1 <2 Isopropylbenzene 6.6 x 10-57 <1 MTBE 0.28 <1 Naphthalene 6.4 x 10-7 <5 1,2,4- Trimethylbenzene 6.1 x 10-14 1.89 *Concentrations are given in μg/L Based on the initial calibration, the model calculated concentrations benzene at a marginally greater concentration than those present at the site and concentrations of ethylbenzene and 1,2,4- trimethylbenzene at lower concentrations than those present at the site. As such, it appears that a 1st order decay model for these specific contaminants may not accurately calculate contaminant degradation apparent at the site. Therefore, the output of these constituents in the biodegradation model should be compared relative to the initial calibration when evaluating the risk to WSW-5 and WSW-6, located approximately 90 and 350 feet from the source area, respectively. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 10 Fate and Transport Model Concentrations of ethylbenzene, total xylenes, isopropylbenzene, naphthalene, and 1,2,4- trimethylbenzene identified within RW-5 during the June 2022 sampling event were used as the contaminant concentrations in the source area to populate the biodegradation model. Contaminants benzene, toluene, and MTBE were not included as contaminants of concern in the model as concentrations during the June 2022 sampling event were below the MDLs. The data and inputs used for the model are described above and are also indicated on the input screen included in Appendix C. Fate and Transport Model Results (Source Area to WSW-5) Biodegradation Model Results The biodegradation model for WSW-5 indicates that the steady-state concentrations of the selected constituents calculated to exist at the point of exposure (POE; i.e. receptor WSW-5) range from 3.7 μg/L (total xylenes) to 3.1 x 10-36 μg/L (isopropylbenzene). The calculated total hazard index (1.5x 10-3) for the point of exposure is lower than NCDEQ’s acceptable risk tolerance of 1. Carcinogenic constituents were less than the MDLs in the source area and therefore the total pathway carcinogenic risk was not calculated. As the plume appears to be either stable or shrinking, the biodegradation model calculates the following concentrations to exist at the point of exposure after 20 years: Calculated Concentrations at WSW-5 Constituent Calculated Concentrations After 20 Years Steady State Concentrations Calculated Years to Reach Steady State Conditions Ethylbenzene 0.46 0.46 10 Xylenes (Total) 3.7 3.7 10 Isopropylbenzene 3.1 x 10-36 3.1 x 10-36 4 Naphthalene 7.7 x 10-4 7.7 x 10-4 14 1,2,4- Trimethylbenzene 3.0 x 10-8 3.0 x 10-8 5 *Concentrations are given in μg/L The biodegradation model for WSW-6 indicates that the steady-state concentrations of the selected constituents calculated to exist at the point of exposure (POE; i.e. receptor WSW-6) range from 2.3 x 10-3 μg/L (total xylenes) to 1.4 x 10-74 μg/L (isopropylbenzene). The calculated total hazard index (7.8 x 10-7) for the point of exposure is lower than NCDEQ’s acceptable risk tolerance of 1. Carcinogenic constituents were less than the MDLs in the source area and therefore the total pathway carcinogenic risk was not calculated. As the plume appears to be either stable or shrinking, the biodegradation model calculates the Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 11 following concentrations to exist at the point of exposure after 20 years: Calculated Concentrations at WSW-6 Constituent Calculated Concentrations After 20 Years Steady State Concentrations Calculated Years to Reach Steady State Conditions Ethylbenzene 6.9 x 10-5 6.9 x 10-5 15 Xylenes (Total) 2.3 x 10-3 2.3 x 10-3 15 Isopropylbenzene 1.4 x 10-74 1.4 x 10-74 7 Naphthalene 6.5 x 10-11 7.0 x 10-11 25 1,2,4- Trimethylbenzene 3.9 x 10-20 3.9 x 10-20 8 *Concentrations are given in μg/L Fate and Transport Model Summary Summaries of the model results are provided in Appendix D. Contaminants of concern appear to be either stable or decreasing and did not exhibit GCL exceedances during this sampling event. Based on the biodegradation model, which appears to simulate contaminant transport and degradation between RW-5 and MW-5 accurately, it does not appear likely that the on-site contaminant concentrations will impact water supply wells WSW-2 or WSW-3 at levels exceeding the 2L Standards in the future. Further, it can be extrapolated that any other water supply wells located further from the source area are at even lower risk of future impact. The potential risk to Camp Creek (the only other receptor located within 300 feet and down-gradient of the site) is similarly low as it is located further from the source area than WSW-5 and the calculated concentrations of pollutants listed under the NCAC 2B Standards fall significantly under the limits. As such, the incident may be closed with a Notice of Residual Petroleum (NORP) and a deed restriction for groundwater. G. CONCLUSIONS AND RECOMMENDATIONS Based on information obtained during the completion of these assessment activities, Terracon provides the following findings and conclusions:  Several petroleum constituents were detected at concentrations exceeding the 2L Standards but below the GCLs in groundwater samples from wells MW-2/RW-2 and MW-3/RW-3.  Multiple petroleum constituents were also detected in groundwater samples from wells MW-2/RW-2, MW-3/RW-3, and RW-5 at concentrations exceeding the laboratory detection limits but below the 2L Standards.  No target compounds were detected above laboratory detection limits in samples collected from monitoring wells MW-4/RW-4, RW-5, MW-6, MW-7, or MW-8. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 12  Measurable thicknesses of LNAPL were not observed in the monitoring wells gauged.  Groundwater flow was estimated, based on groundwater elevation data, to be toward the northeast, east, and southeast.  The biodegradation model appears to simulate contaminant transport and degradation between RW-5 and MW-5 accurately, with the exception of the model underpredicting the concentrations of contaminants ethylbenzene and 1,2,4- trimethylbenzene.  Based on the biodegradation model, it does not appear likely that on-site contaminant concentrations will impact water supply well WSW-5 or WSW-6, or other supply wells in the future. Based on the data presented in this Annual Monitoring Report, Terracon recommends the following activities be completed at the site:  Based on the results of the biodegradation model, the incident may be closed with a Notice of Residual Petroleum (NORP) and a groundwater use restriction. Annual Monitoring Report Jerry’s Place - Incident No. 9547 ■ State Road, NC July 29, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable 13 H. REFERENCES The following sources were utilized in developing this report: ECS, Ltd., 2020. Groundwater Monitoring Report, ECS, dated January 7, 2020. ECS, Ltd., 2015. Groundwater Monitoring Report, ECS, dated October 14, 2015. ECS, Ltd., 2014. Groundwater Monitoring Report, ECS, dated September 16, 2014. S&ME, Inc., 2011. Water Supply Well Sampling Report, S&ME, Inc., dated June 13, 2011. Terraine, Inc., 2005. Groundwater Monitoring Report, Terraine, Inc., dated November 28, 2005. Aggressive Fluid/Vapor Recovery Evaluation, November 22, 1996. Bain, Palmer & Associates, Inc., 1993. Site Assessment Jerry’s Convenience Store, Bain, Palmer & Associates, Inc., dated June 30, 1993. EXHIBITS TOPOGRAPHIC MAP Jerry’s Place (Incident No. 9547) 983 US Highway 21 State Road, Surry County, NC TOPOGRAPHIC MAP IMAGE COURTESY OF THE U.S. GEOLOGICAL SURVEY QUADRANGLES INCLUDE: THURMOND, NC (1/1/1971) and ELKIN NORTH, NC (1/1/2000). 7327 W Friendly Ave Ste G Greensboro, NC 27410-6253 75207118 Project Manager: Drawn by: Checked by: Approved by: FCD MNM MNM 1”=2,000’ July 2022 Project No. Scale: File Name: Date: 1 LE Exhibit APPROXIMATE SITE BOUNDARY Jerrys Place @A @A @A @A @A @A @A@A ED "ÑÎ "ÑÎ Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 0 30 60Feet Legend "ÑÎ Former Monitoring Well ED Water Supply Well @A Monitoring Well Site Boundary Parcel Boundary File Path: Date: Project No. Scale: LRE JWR MNM MNM 2 PM: Drawn By: Checked By: Approved By:7327-G West Friendly Avenue Greensboro, NC 27410 Phone: (336) 854-28135 Fax: (336) 365-7020 75207118 EXHIBITNO.SITE DIAGRAM July 2022 Jerry's Place (Incident No. 9547)983 US Highway 21State Road, Surry County, NC WSW-5 MW-7 MW-3/RW-3(PAVED OVER)RW-6 RW-5 U.S . H IGHWAY 21 MW-2/RW-2 MW-6 MW-1(DESTROYED) MW-8 MW-4/RW-4 MW-5 1 inch = 60 ft. WATER SUPPLY WELL LOCATION MAP Jerry’s Place (Incident No. 9547)983 US Highway 21State Road, Surry County, NC MIM MNM MNM Scale: 3 ExhibitProject Manager: Drawn by: Checked by: Approved by: Project No. File Name: Date: LRE Site boundary 7327-G West Friendly Avenue Greensboro, NC 75207118 Jerry’s Place July 2022 1” = 500’ Water Supply Well Source: Groundwater Monitoring Report, ECS, 2014 @A @A @A @A @A @A @A@A ED "ÑÎ "ÑÎ Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 0 30 60Feet Legend "ÑÎ Former Monitoring Well ED Water Supply Well @A Monitoring Well Groundwater Elevation Contour Groundwater Flow Direction Site Boundary Parcel Boundary File Path: Date: Project No. Scale: LRE JWR MNM MNM 4 PM: Drawn By: Checked By: Approved By:7327-G West Friendly Avenue Greensboro, NC 27410 Phone: (336) 854-28135 Fax: (336) 365-7020 75207118 EXHIBITNO.GROUNDWATER CONTOUR MAP (JUNE 2022) July 2022 Jerry's Place (Incident No. 9547)983 US Highway 21State Road, Surry County, NC WSW-5 MW-7 MW-3/RW-3 NM(PAVED OVER)RW-6 RW-5 U.S . H IGHWAY 21 MW-2/RW-2 MW-6 MW-1(DESTROYED) MW-8 MW-4/RW-4 MW-5 1 inch = 60 ft. (82.25)(79.64) (75.50) (75.10) (74.01)(72.80) (79.28) (77.95) 74.00 76.0075.00 73.00 78.0077.0079.00 80.00 81.00 82.00 @A @A @A @A @A @A @A@A ED "ÑÎ "ÑÎ Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 0 30 60Feet Legend "ÑÎ Former Monitoring Well ED Water Supply Well @A Monitoring Well Site Boundary Parcel Boundary File Path: Date: Project No. Scale: LRE JWR MNM MNM 5 PM: Drawn By: Checked By: Approved By:7327-G West Friendly Avenue Greensboro, NC 27410 Phone: (336) 854-28135 Fax: (336) 365-7020 75207118 EXHIBITNO.GROUNDWATER ANALYTICAL RESULTS MAP (JUNE 2022) July 2022 Jerry's Place (Incident No. 9547)983 US Highway 21State Road, Surry County, NC WSW-5Not Sampled MW-7 MW-3/RW-3 (PAVED OVER)RW-6 RW-5 U.S . H IGHWAY 21 MW-2/RW-2 MW-6 MW-1(DESTROYED) MW-8 MW-4/RW-4 MW-5 1 inch = 60 ft. MW-2VOCs by 6200Benzene = 234 µg/LEthylbenzene = 379 µg/LIsopropylbenzene = 49.8 µg/LNaphthalene = 184 µg/Ln-Propylbenzene = 144 µg/LToluene = 42.7 µg/L1,2,4-Trimethylbenzene = 650 µg/L1,3,5-Trimethylbenzene = 295 µg/LXylenes (Total) = 752 µg/L MW-3/RW-3VOCs by 6200Benzene = 14.8 µg/Ln-Butylbenzene = 13.4 µg/Lsec-Butylbenzene = 15.9 µg/LEthylbenzene = 86.4 µg/LIsopropylbenzene = 59.1 µg/LNaphthalene = 179 µg/Ln-Propylbenzene = 157 µg/L1,2,4-Trimethylbenzene = 384 µg/L1,3,5-Trimethylbenzene = 130 µg/LXylenes (Total) = 143.5 µg/L RW-5VOCs by 6200All Analytes Below Detection Limits MW-4/RW-4VOCs by 6200All Analytes Below Detection Limits MW-5VOCs by 6200Ethylbenzene = 1.26 µg/LIsopropylbenzene = 1.27 µg/Ln-Propylbenzene = 3.03 µg/L1,2,4-Trimethylbenzene = 1.89 µg/L MW-7VOCs by 6200All Analytes Below Detection Limits MW-8VOCs by 6200All Analytes Below Detection Limits MW-6VOCs by 6200All Analytes Below Detection Limits Evaluation Date:Job ID: Facility Name:Constituent: Conducted By:Concentration Units:ug/L Sampling Point ID:Benzene Toluene Ethylbenzene Total Xylenes Sampling Sampling Event Date 1 7-Oct-09 300 580 1100 3300 2 22-Apr-10 470 330 550 950 3 13-Sep-11 110 300 12000 2700 4 27-Jun-14 0.5 477 468 1290 5 29-Apr-21 0.5 0.5 42 108.2 6 16-Jun-22 0.5 0.5 0.5 1 7 8 9 10 11 12 13 14 15 16 17 18 19 20Coefficient of Variation:1.34 0.85 2.01 0.97 Mann-Kendall Statistic (S):-10 -10 -11 -11 Confidence Factor:95.2%95.2%97.2%97.2% Concentration Trend:Decreasing Decreasing Decreasing Decreasing Notes: 1.At least four independent sampling events per well are required for calculating the trend.Methodology is valid for 4 to 40 samples. 2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; ≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable. 3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water , 41(3):355-367, 2003. DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. RW-5 (BTEX) CONCENTRATION (ug/L) GSI Environmental Inc., www.gsi-net.com GSI MANN-KENDALL TOOLKIT for Constituent Trend Analysis 12-Jul-22 75207118 Jerry's Place RW-5 (BTEX) C Driscoll 0.1 1 10 100 1000 10000 100000 10/06 07/09 04/12 12/14 09/17 06/20 03/23Concentration (ug/L)Sampling Date Benzene Toluene Ethylbenzene Total Xylenes Exhibit 6:Mann Kendall Analysis – RW-1 (BTEX) Evaluation Date:Job ID: Facility Name:Constituent: Conducted By:Concentration Units:ug/L Sampling Point ID:Isopropylbenzene MTBE Naphthalene 1,2,4 Trimethylbenzene Sampling Sampling Event Date 1 7-Oct-09 85 34 560 1100 2 22-Apr-10 51 68 150 280 3 13-Sep-11 83 15 380 1100 4 27-Jun-14 35.5 0.5 238 794 5 29-Apr-21 13.3 0.5 58.5 131 6 16-Jun-22 0.5 0.5 0.5 0.5 7 8 9 10 11 12 13 14 15 16 17 18 19 20Coefficient of Variation:0.78 1.37 0.91 0.87 Mann-Kendall Statistic (S):-13 -10 -11 -10 Confidence Factor:99.2%95.2%97.2%95.2% Concentration Trend:Decreasing Decreasing Decreasing Decreasing Notes: 1.At least four independent sampling events per well are required for calculating the trend.Methodology is valid for 4 to 40 samples. 2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; ≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable. 3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. RW-5 (SELECTED CONSTITUENTS) CONCENTRATION (ug/L) GSI Environmental Inc., www.gsi-net.com GSI MANN-KENDALL TOOLKIT for Constituent Trend Analysis 6-Jun-22 75159687B JH Foster RW-5 (Selected constituents) C Driscoll 0.1 1 10 100 1000 10000 10/06 07/09 04/12 12/14 09/17 06/20 03/23Concentration (ug/L)Sampling Date Isopropylbenzene MTBE Naphthalene 1,2,4 Trimethylbenzene Exhibit 7: Mann Kendall Analysis – RW-1 (Selected Constituents) Evaluation Date:Job ID: Facility Name:Constituent: Conducted By:Concentration Units:ug/L Sampling Point ID:Benzene Toluene Ethylbenzene Total Xylenes Sampling Sampling Event Date 1 23-May-93 14000 54000 2000 17000 2 7-Oct-09 2400 800 960 1230 3 22-Apr-10 1700 1400 1200 3800 4 13-Sep-11 2300 4000 1300 5500 5 27-Jun-14 1830 6390 1530 7320 6 22-Sep-15 1410 1120 1270 4750 7 20-Feb-18 1300 150 750 1200 8 12-Dec-19 583 1040 1230 4650 9 29-Apr-21 510 455 590 1716 10 16-Jun-22 234 42.7 379 752 11 12 13 14 15 16 17 18 19 20Coefficient of Variation:1.55 2.40 0.42 1.00 Mann-Kendall Statistic (S):-41 -25 -23 -19 Confidence Factor:>99.9%98.6%97.7%94.6% Concentration Trend:Decreasing Decreasing Decreasing Prob. Decreasing Notes: 1.At least four independent sampling events per well are required for calculating the trend.Methodology is valid for 4 to 40 samples. 2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; ≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable. 3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. MW-2 (BTEX) CONCENTRATION (ug/L) GSI Environmental Inc., www.gsi-net.com GSI MANN-KENDALL TOOLKIT for Constituent Trend Analysis 12-Jul-22 75207118 Jerry's Place MW-2 (BTEX) C Driscoll 1 10 100 1000 10000 100000 01/00 09/13 05/27 01/41 10/54 06/68 02/82 10/95 07/09 03/23 11/36Concentration (ug/L)Sampling Date Benzene Toluene Ethylbenzene Total Xylenes Exhibit 8: Mann Kendall Analysis – MW-2 (BTEX) Evaluation Date:Job ID: Facility Name:Constituent: Conducted By:Concentration Units:ug/L Sampling Point ID:Isopropylbenzene MTBE Naphthalene 1,2,4 Trimethylbenzene Sampling Sampling Event Date 1 23-May-93 25000 2 7-Oct-09 95 380 590 350 3 22-Apr-10 100 260 600 1300 4 13-Sep-11 91 220 560 1500 5 27-Jun-14 80 0.5 761 2300 6 22-Sep-15 100 74 403 2010 7 20-Feb-18 110 51 230 590 8 12-Dec-19 76 0.5 504 1530 9 29-Apr-21 47.3 2.09 194 639 10 16-Jun-22 49.8 0.5 184 650 11 12 13 14 15 16 17 18 19 20Coefficient of Variation:0.27 3.03 0.46 0.57 Mann-Kendall Statistic (S):-15 -34 -24 2 Confidence Factor:92.5%100.0%99.4%54.0% Concentration Trend:Prob. Decreasing Decreasing Decreasing No Trend Notes: 1.At least four independent sampling events per well are required for calculating the trend.Methodology is valid for 4 to 40 samples. 2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; ≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable. 3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. MW-2 (SELECTED CONSTITUENTS) CONCENTRATION (ug/L) GSI Environmental Inc., www.gsi-net.com GSI MANN-KENDALL TOOLKIT for Constituent Trend Analysis 6-Jun-22 75159687B JH Foster MW-2 (Selected constituents) C Driscoll 0.1 1 10 100 1000 10000 100000 01/00 09/13 05/27 01/41 10/54 06/68 02/82 10/95 07/09 03/23 11/36Concentration (ug/L)Sampling Date Isopropylbenzene MTBE Naphthalene 1,2,4 Trimethylbenzene Exhibit 9: Mann Kendall Analysis – RW-2 (Selected Constituents) TABLES TABLE 1 Water Supply Well Information Jerry’s Place State Road, Surry County, North Carolina Terracon Project No. 75207118 NCDEQ Incident No. 9547 May 17, 2021 Note: Table generated from Groundwater Monitoring Report, ECS, dated September 16, 2014 TABLE 2Monitoring Well Construction Details and Groundwater Elevation DataJerry's PlaceState Road, Surry County, North CarolinaTerracon Project No. 75207118NCDEQ Incident No. 9547Well IDScreened Interval (ft. TOC)Total Well Depth (ft. BTOC)Top of Casing ElevationDate Water Level MeasuredDepth to Water (ft. BTOC)Groundwater ElevationCommentsMW-2/RW-2 12-32 30 101.45 6/16/2022 19.20 82.25 4-inch diameter Type II well MW-3/RW-3 10-30 30 97.99 6/16/2022 18.35 79.64 4-inch diameter Type II well MW-4/RW-4 2-12 30 95.94 6/16/2022 20.44 75.50 4-inch diameter Type II well MW-5 15-25 15 80.57 6/16/2022 5.47 75.10 2-inch diameter Type II well; Stick-up completionRW-5 Unknown 27 97.99 6/16/2022 20.04 77.95 4-inch diameter Type II well MW-6 15-25 25 99.63 6/16/2022 20.35 79.28 2-inch diameter Type II well MW-7 15-25 25 97.20 6/16/2022 24.40 72.80 2-inch diameter Type II well MW-8 15-25 25 98.51 6/16/2022 24.50 74.01 2-inch diameter Type II well Notes:ft = feet TOC = Top of CasingbTOC = below TOC TABLE 3Summary of Groundwater Analytical Results983 US Highway 21State Road, Surry County, North CarolinaNCDEQ Incident No. 9547Terracon Project No. 75207118Monitoring WellI.D. Date Collected 4/29/2021510<20.0 <20.04.21 590 47.3 10.6 2.09 194 97.8 23.3 455 639 206 17166/16/2022234<20.0 <20.0 <20.0379 49.8<200 <20.0184 144<20.042.7 650 295 7524/29/2021<10.012.6 12.2<10.099.4 59.4<10.0 <10.0207 130<10.0 <10.0478 134 2336/16/202214.8 13.4 15.9<10.086.4 59.1<100 <10.0179 157<10.0 <10.0384 130 143.54/29/2021<1.0 <1.0 <1.0 <1.0 <1.01.41<10.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.06/16/2022<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <2.004/29/2021<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.06/16/2022<1.00 <1.00 <1.00 <1.001.26 1.27<1.00 <1.00 <5.003.03<1.00 <1.001.89<1.00 <2.004/29/2021<5.0 <5.0 <5.0 <5.042 13.30<50.0 <5.058.5 21.30<5.0 <5.0131 17.4 108.26/16/2022<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <2.00MW-6 6/16/2022<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <2.00MW-7 6/16/2022<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <2.00MW-8 6/16/2022<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <2.00WSW-5 4/29/2021<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0FB-1 4/29/2021<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <10.0 <1.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.01 70 70 70 600 70 100 20 6 70 70 600 400 400 5005000 6900 8500 70000 84500 25000 100000 20000 6000 30000 70000 260000 28500 25000 85500Notes:All measurements in micrograms per liter (μ/L)Bold indicated detection above Laboratory Reported Detection Limit NE = Not Established indicates concentrations exceeding 2LJ = Detected below laboratory reporting limit indicates concentrations exceeding GCLNR = Not ReportedGroundwater standards pursuant to NCDEQ, UST Section [Guidelines for Assessment and Corrective Action]FB= Field Blank dated January 19, 2021Analytical MethodContaminant of Concern →Di-isopropyl etherEthylbenzeneIsopropylbenzeneN-ButylbenzeneSec-ButylbenzeneBenzeneVOCs by Method 6200B1,2,4-TrimethylbenzeneTolueneStyrenen-PropylbenzeneXylenes (Total)1,3,5-TrimethylbenzeneGross Contamination Levels for Groundwater (GCL)NaphthaleneNorth Carolina Groundwater Quality Standards (2L Standards)4-Methyl-2-PentanoneMethyl Tert-Butyl etherRW-5MW-5MW-4/RW-4MW-3/RW-3MW-2/RW-21 of 1 APPENDIX A FIELD NOTES NCDEQ 2020-2023-Jerrys Place ■ Incident # 9547 State Road, NC Date Pictures Taken: June 16, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable Photo 1 Overview of site, facing WNW. Photo 2 Monitoring well MW-5 stick up well in background. Storm drain access in foreground. Photo 3 Monitoring well MW-5 stick up well. Photo 4 Monitoring well MW-4/RW-4. Photo 5 Monitoring well MW-3/RW-3. Photo 6 Monitoring well MW-2/RW-2. NCDEQ 2020-2023-Jerrys Place ■ Incident # 9547 State Road, NC Date Pictures Taken: June 16, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable Photo 7 Monitoring well MW-6. Photo 8 Recovery well RW-5. Photo 9 Monitoring well MW-8. Photo 10 Monitoring well MW-7. Photo 11 View from site toward cemetery to the east. Photo 12 View from site toward cemetery to the east. NCDEQ 2020-2023-Jerrys Place ■ Incident # 9547 State Road, NC Date Pictures Taken: June 16, 2022 ■ Terracon Project No. 75207118 Responsive ■ Resourceful ■ Reliable Photo 13 View from site toward the north. Photo 14 View from site toward the south. Photo 15 View from site toward the west. APPENDIX B LABORATORY ANALYTICAL RESULTS AND CHAIN-OF-CUSTODY FORMS ANALYTICAL REPORT June 27, 2022 Terracon - Greensboro, NC Sample Delivery Group:L1506699 Samples Received:06/17/2022 Project Number:75207118 Description:Jerry's Place Report To:Laura Elliott 7327-G, West Friendly Ave Greensboro, NC 27410 Entire Report Reviewed By: June 27, 2022 [Preliminary Report] Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 1 of 27 June 28, 2022 Heather J Wagner Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 1 of 27 TABLE OF CONTENTS Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-2 L1506699-01 5 MW-3 L1506699-02 7 MW-4 L1506699-03 9 MW-5 L1506699-04 11 RW-5 L1506699-05 13 MW-6 L1506699-06 15 MW-7 L1506699-07 17 MW-8 L1506699-08 19 Qc: Quality Control Summary 21 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 21 Gl: Glossary of Terms 25 Al: Accreditations & Locations 26 Sc: Sample Chain of Custody 27 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 2 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 2 of 27 SAMPLE SUMMARY Collected by Collected date/time Received date/time MW-2 L1506699-01 GW Dylan Edwards 06/16/22 14:20 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 20 06/27/22 00:15 06/27/22 00:15 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3 L1506699-02 GW Dylan Edwards 06/16/22 13:35 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 10 06/27/22 00:37 06/27/22 00:37 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1506699-03 GW Dylan Edwards 06/16/22 12:10 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 20:33 06/26/22 20:33 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-5 L1506699-04 GW Dylan Edwards 06/16/22 10:50 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 20:55 06/26/22 20:55 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time RW-5 L1506699-05 GW Dylan Edwards 06/16/22 12:45 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 21:18 06/26/22 21:18 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-6 L1506699-06 GW Dylan Edwards 06/16/22 09:10 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 21:40 06/26/22 21:40 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-7 L1506699-07 GW Dylan Edwards 06/16/22 10:00 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 22:02 06/26/22 22:02 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-8 L1506699-08 GW Dylan Edwards 06/16/22 09:45 06/17/22 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1885693 1 06/26/22 22:24 06/26/22 22:24 JHH Mt. Juliet, TN 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 3 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 3 of 27 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. [Preliminary Report] Heather J Wagner Project Manager 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 4 of 27 Heather J Wagner Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 4 of 27 SAMPLE RESULTS - 01 L1506699 MW-2 Collected date/time: 06/16/22 14:20 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 1000 20 06/27/2022 00:15 WG1885693 Acrolein ND 1000 20 06/27/2022 00:15 WG1885693 Acrylonitrile ND 200 20 06/27/2022 00:15 WG1885693 Benzene 234 20.0 20 06/27/2022 00:15 WG1885693 Bromobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 Bromodichloromethane ND 20.0 20 06/27/2022 00:15 WG1885693 Bromoform ND 20.0 20 06/27/2022 00:15 WG1885693 Bromomethane ND 100 20 06/27/2022 00:15 WG1885693 n-Butylbenzene ND 20.0 20 06/27/2022 00:15 WG1885693 sec-Butylbenzene ND 20.0 20 06/27/2022 00:15 WG1885693 tert-Butylbenzene ND 20.0 20 06/27/2022 00:15 WG1885693 Carbon tetrachloride ND 20.0 20 06/27/2022 00:15 WG1885693 Chlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 Chlorodibromomethane ND 20.0 20 06/27/2022 00:15 WG1885693 Chloroethane ND 100 20 06/27/2022 00:15 WG1885693 Chloroform ND 100 20 06/27/2022 00:15 WG1885693 Chloromethane ND 50.0 20 06/27/2022 00:15 WG1885693 2-Chlorotoluene ND 20.0 20 06/27/2022 00:15 WG1885693 4-Chlorotoluene ND 20.0 20 06/27/2022 00:15 WG1885693 1,2-Dibromo-3-Chloropropane ND 100 20 06/27/2022 00:15 WG1885693 1,2-Dibromoethane ND 20.0 20 06/27/2022 00:15 WG1885693 Dibromomethane ND 20.0 20 06/27/2022 00:15 WG1885693 1,2-Dichlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 1,3-Dichlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 1,4-Dichlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 Dichlorodifluoromethane ND 100 20 06/27/2022 00:15 WG1885693 1,1-Dichloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 1,2-Dichloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 1,1-Dichloroethene ND 20.0 20 06/27/2022 00:15 WG1885693 cis-1,2-Dichloroethene ND 20.0 20 06/27/2022 00:15 WG1885693 trans-1,2-Dichloroethene ND 20.0 20 06/27/2022 00:15 WG1885693 1,2-Dichloropropane ND 20.0 20 06/27/2022 00:15 WG1885693 1,1-Dichloropropene ND 20.0 20 06/27/2022 00:15 WG1885693 1,3-Dichloropropane ND 20.0 20 06/27/2022 00:15 WG1885693 2,2-Dichloropropane ND 20.0 20 06/27/2022 00:15 WG1885693 Di-isopropyl ether ND 20.0 20 06/27/2022 00:15 WG1885693 Ethylbenzene 379 20.0 20 06/27/2022 00:15 WG1885693 Hexachloro-1,3-butadiene ND 20.0 20 06/27/2022 00:15 WG1885693 Isopropylbenzene 49.8 20.0 20 06/27/2022 00:15 WG1885693 p-Isopropyltoluene ND 20.0 20 06/27/2022 00:15 WG1885693 2-Butanone (MEK)ND 200 20 06/27/2022 00:15 WG1885693 Methylene Chloride ND J4 100 20 06/27/2022 00:15 WG1885693 4-Methyl-2-pentanone (MIBK)ND 200 20 06/27/2022 00:15 WG1885693 Methyl tert-butyl ether ND 20.0 20 06/27/2022 00:15 WG1885693 Naphthalene 184 100 20 06/27/2022 00:15 WG1885693 n-Propylbenzene 144 20.0 20 06/27/2022 00:15 WG1885693 Styrene ND 20.0 20 06/27/2022 00:15 WG1885693 1,1,1,2-Tetrachloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 1,1,2,2-Tetrachloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 Tetrachloroethene ND 20.0 20 06/27/2022 00:15 WG1885693 Toluene 42.7 20.0 20 06/27/2022 00:15 WG1885693 1,2,3-Trichlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 1,2,4-Trichlorobenzene ND 20.0 20 06/27/2022 00:15 WG1885693 1,1,1-Trichloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 1,1,2-Trichloroethane ND 20.0 20 06/27/2022 00:15 WG1885693 Trichloroethene ND 20.0 20 06/27/2022 00:15 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 5 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 5 of 27 SAMPLE RESULTS - 01 L1506699 MW-2 Collected date/time: 06/16/22 14:20 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 100 20 06/27/2022 00:15 WG1885693 1,2,3-Trichloropropane ND 50.0 20 06/27/2022 00:15 WG1885693 1,2,4-Trimethylbenzene 650 20.0 20 06/27/2022 00:15 WG1885693 1,3,5-Trimethylbenzene 295 20.0 20 06/27/2022 00:15 WG1885693 Vinyl chloride ND 20.0 20 06/27/2022 00:15 WG1885693 o-Xylene 281 20.0 20 06/27/2022 00:15 WG1885693 m&p-Xylenes 471 40.0 20 06/27/2022 00:15 WG1885693 (S) Toluene-d8 99.7 80.0-120 06/27/2022 00:15 WG1885693 (S) 4-Bromofluorobenzene 99.8 77.0-126 06/27/2022 00:15 WG1885693 (S) 1,2-Dichloroethane-d4 104 70.0-130 06/27/2022 00:15 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 6 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 6 of 27 SAMPLE RESULTS - 02 L1506699 MW-3 Collected date/time: 06/16/22 13:35 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 500 10 06/27/2022 00:37 WG1885693 Acrolein ND 500 10 06/27/2022 00:37 WG1885693 Acrylonitrile ND 100 10 06/27/2022 00:37 WG1885693 Benzene 14.8 10.0 10 06/27/2022 00:37 WG1885693 Bromobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 Bromodichloromethane ND 10.0 10 06/27/2022 00:37 WG1885693 Bromoform ND 10.0 10 06/27/2022 00:37 WG1885693 Bromomethane ND 50.0 10 06/27/2022 00:37 WG1885693 n-Butylbenzene 13.4 10.0 10 06/27/2022 00:37 WG1885693 sec-Butylbenzene 15.9 10.0 10 06/27/2022 00:37 WG1885693 tert-Butylbenzene ND 10.0 10 06/27/2022 00:37 WG1885693 Carbon tetrachloride ND 10.0 10 06/27/2022 00:37 WG1885693 Chlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 Chlorodibromomethane ND 10.0 10 06/27/2022 00:37 WG1885693 Chloroethane ND 50.0 10 06/27/2022 00:37 WG1885693 Chloroform ND 50.0 10 06/27/2022 00:37 WG1885693 Chloromethane ND 25.0 10 06/27/2022 00:37 WG1885693 2-Chlorotoluene ND 10.0 10 06/27/2022 00:37 WG1885693 4-Chlorotoluene ND 10.0 10 06/27/2022 00:37 WG1885693 1,2-Dibromo-3-Chloropropane ND 50.0 10 06/27/2022 00:37 WG1885693 1,2-Dibromoethane ND 10.0 10 06/27/2022 00:37 WG1885693 Dibromomethane ND 10.0 10 06/27/2022 00:37 WG1885693 1,2-Dichlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 1,3-Dichlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 1,4-Dichlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 Dichlorodifluoromethane ND 50.0 10 06/27/2022 00:37 WG1885693 1,1-Dichloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 1,2-Dichloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 1,1-Dichloroethene ND 10.0 10 06/27/2022 00:37 WG1885693 cis-1,2-Dichloroethene ND 10.0 10 06/27/2022 00:37 WG1885693 trans-1,2-Dichloroethene ND 10.0 10 06/27/2022 00:37 WG1885693 1,2-Dichloropropane ND 10.0 10 06/27/2022 00:37 WG1885693 1,1-Dichloropropene ND 10.0 10 06/27/2022 00:37 WG1885693 1,3-Dichloropropane ND 10.0 10 06/27/2022 00:37 WG1885693 2,2-Dichloropropane ND 10.0 10 06/27/2022 00:37 WG1885693 Di-isopropyl ether ND 10.0 10 06/27/2022 00:37 WG1885693 Ethylbenzene 86.4 10.0 10 06/27/2022 00:37 WG1885693 Hexachloro-1,3-butadiene ND 10.0 10 06/27/2022 00:37 WG1885693 Isopropylbenzene 59.1 10.0 10 06/27/2022 00:37 WG1885693 p-Isopropyltoluene ND 10.0 10 06/27/2022 00:37 WG1885693 2-Butanone (MEK)ND 100 10 06/27/2022 00:37 WG1885693 Methylene Chloride ND J4 50.0 10 06/27/2022 00:37 WG1885693 4-Methyl-2-pentanone (MIBK)ND 100 10 06/27/2022 00:37 WG1885693 Methyl tert-butyl ether ND 10.0 10 06/27/2022 00:37 WG1885693 Naphthalene 179 50.0 10 06/27/2022 00:37 WG1885693 n-Propylbenzene 157 10.0 10 06/27/2022 00:37 WG1885693 Styrene ND 10.0 10 06/27/2022 00:37 WG1885693 1,1,1,2-Tetrachloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 1,1,2,2-Tetrachloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 Tetrachloroethene ND 10.0 10 06/27/2022 00:37 WG1885693 Toluene ND 10.0 10 06/27/2022 00:37 WG1885693 1,2,3-Trichlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 1,2,4-Trichlorobenzene ND 10.0 10 06/27/2022 00:37 WG1885693 1,1,1-Trichloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 1,1,2-Trichloroethane ND 10.0 10 06/27/2022 00:37 WG1885693 Trichloroethene ND 10.0 10 06/27/2022 00:37 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 7 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 7 of 27 SAMPLE RESULTS - 02 L1506699 MW-3 Collected date/time: 06/16/22 13:35 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 50.0 10 06/27/2022 00:37 WG1885693 1,2,3-Trichloropropane ND 25.0 10 06/27/2022 00:37 WG1885693 1,2,4-Trimethylbenzene 384 10.0 10 06/27/2022 00:37 WG1885693 1,3,5-Trimethylbenzene 130 10.0 10 06/27/2022 00:37 WG1885693 Vinyl chloride ND 10.0 10 06/27/2022 00:37 WG1885693 o-Xylene 51.0 10.0 10 06/27/2022 00:37 WG1885693 m&p-Xylenes 92.5 20.0 10 06/27/2022 00:37 WG1885693 (S) Toluene-d8 99.8 80.0-120 06/27/2022 00:37 WG1885693 (S) 4-Bromofluorobenzene 99.6 77.0-126 06/27/2022 00:37 WG1885693 (S) 1,2-Dichloroethane-d4 105 70.0-130 06/27/2022 00:37 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 8 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 8 of 27 SAMPLE RESULTS - 03 L1506699 MW-4 Collected date/time: 06/16/22 12:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 20:33 WG1885693 Acrolein ND 50.0 1 06/26/2022 20:33 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 20:33 WG1885693 Benzene ND 1.00 1 06/26/2022 20:33 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 20:33 WG1885693 Bromoform ND 1.00 1 06/26/2022 20:33 WG1885693 Bromomethane ND 5.00 1 06/26/2022 20:33 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 20:33 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 20:33 WG1885693 Chloroethane ND 5.00 1 06/26/2022 20:33 WG1885693 Chloroform ND 5.00 1 06/26/2022 20:33 WG1885693 Chloromethane ND 2.50 1 06/26/2022 20:33 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 20:33 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 20:33 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 20:33 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 20:33 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 20:33 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 20:33 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 20:33 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 20:33 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 20:33 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 20:33 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 20:33 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 20:33 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 20:33 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 20:33 WG1885693 Ethylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 20:33 WG1885693 Isopropylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 20:33 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 20:33 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 20:33 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 20:33 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 20:33 WG1885693 Naphthalene ND 5.00 1 06/26/2022 20:33 WG1885693 n-Propylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Styrene ND 1.00 1 06/26/2022 20:33 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 20:33 WG1885693 Toluene ND 1.00 1 06/26/2022 20:33 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 20:33 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 20:33 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 20:33 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 9 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 9 of 27 SAMPLE RESULTS - 03 L1506699 MW-4 Collected date/time: 06/16/22 12:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 20:33 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 20:33 WG1885693 1,2,4-Trimethylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 20:33 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 20:33 WG1885693 o-Xylene ND 1.00 1 06/26/2022 20:33 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 20:33 WG1885693 (S) Toluene-d8 100 80.0-120 06/26/2022 20:33 WG1885693 (S) 4-Bromofluorobenzene 95.3 77.0-126 06/26/2022 20:33 WG1885693 (S) 1,2-Dichloroethane-d4 105 70.0-130 06/26/2022 20:33 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 10 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 10 of 27 SAMPLE RESULTS - 04 L1506699 MW-5 Collected date/time: 06/16/22 10:50 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 20:55 WG1885693 Acrolein ND 50.0 1 06/26/2022 20:55 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 20:55 WG1885693 Benzene ND 1.00 1 06/26/2022 20:55 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 20:55 WG1885693 Bromoform ND 1.00 1 06/26/2022 20:55 WG1885693 Bromomethane ND 5.00 1 06/26/2022 20:55 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 20:55 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 20:55 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 20:55 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 20:55 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 20:55 WG1885693 Chloroethane ND 5.00 1 06/26/2022 20:55 WG1885693 Chloroform ND 5.00 1 06/26/2022 20:55 WG1885693 Chloromethane ND 2.50 1 06/26/2022 20:55 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 20:55 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 20:55 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 20:55 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 20:55 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 20:55 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 20:55 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 20:55 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 20:55 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 20:55 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 20:55 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 20:55 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 20:55 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 20:55 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 20:55 WG1885693 Ethylbenzene 1.26 1.00 1 06/26/2022 20:55 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 20:55 WG1885693 Isopropylbenzene 1.27 1.00 1 06/26/2022 20:55 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 20:55 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 20:55 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 20:55 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 20:55 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 20:55 WG1885693 Naphthalene ND 5.00 1 06/26/2022 20:55 WG1885693 n-Propylbenzene 3.03 1.00 1 06/26/2022 20:55 WG1885693 Styrene ND 1.00 1 06/26/2022 20:55 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 20:55 WG1885693 Toluene ND 1.00 1 06/26/2022 20:55 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 20:55 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 20:55 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 20:55 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 11 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 11 of 27 SAMPLE RESULTS - 04 L1506699 MW-5 Collected date/time: 06/16/22 10:50 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 20:55 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 20:55 WG1885693 1,2,4-Trimethylbenzene 1.89 1.00 1 06/26/2022 20:55 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 20:55 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 20:55 WG1885693 o-Xylene ND 1.00 1 06/26/2022 20:55 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 20:55 WG1885693 (S) Toluene-d8 101 80.0-120 06/26/2022 20:55 WG1885693 (S) 4-Bromofluorobenzene 99.3 77.0-126 06/26/2022 20:55 WG1885693 (S) 1,2-Dichloroethane-d4 109 70.0-130 06/26/2022 20:55 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 12 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 12 of 27 SAMPLE RESULTS - 05 L1506699 RW-5 Collected date/time: 06/16/22 12:45 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 21:18 WG1885693 Acrolein ND 50.0 1 06/26/2022 21:18 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 21:18 WG1885693 Benzene ND 1.00 1 06/26/2022 21:18 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 21:18 WG1885693 Bromoform ND 1.00 1 06/26/2022 21:18 WG1885693 Bromomethane ND 5.00 1 06/26/2022 21:18 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 21:18 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 21:18 WG1885693 Chloroethane ND 5.00 1 06/26/2022 21:18 WG1885693 Chloroform ND 5.00 1 06/26/2022 21:18 WG1885693 Chloromethane ND 2.50 1 06/26/2022 21:18 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 21:18 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 21:18 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 21:18 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 21:18 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 21:18 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 21:18 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 21:18 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 21:18 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 21:18 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 21:18 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 21:18 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 21:18 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 21:18 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 21:18 WG1885693 Ethylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 21:18 WG1885693 Isopropylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 21:18 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 21:18 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 21:18 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 21:18 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 21:18 WG1885693 Naphthalene ND 5.00 1 06/26/2022 21:18 WG1885693 n-Propylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Styrene ND 1.00 1 06/26/2022 21:18 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 21:18 WG1885693 Toluene ND 1.00 1 06/26/2022 21:18 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 21:18 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 21:18 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 21:18 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 13 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 13 of 27 SAMPLE RESULTS - 05 L1506699 RW-5 Collected date/time: 06/16/22 12:45 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 21:18 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 21:18 WG1885693 1,2,4-Trimethylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 21:18 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 21:18 WG1885693 o-Xylene ND 1.00 1 06/26/2022 21:18 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 21:18 WG1885693 (S) Toluene-d8 102 80.0-120 06/26/2022 21:18 WG1885693 (S) 4-Bromofluorobenzene 97.9 77.0-126 06/26/2022 21:18 WG1885693 (S) 1,2-Dichloroethane-d4 105 70.0-130 06/26/2022 21:18 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 14 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 14 of 27 SAMPLE RESULTS - 06 L1506699 MW-6 Collected date/time: 06/16/22 09:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 21:40 WG1885693 Acrolein ND 50.0 1 06/26/2022 21:40 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 21:40 WG1885693 Benzene ND 1.00 1 06/26/2022 21:40 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 21:40 WG1885693 Bromoform ND 1.00 1 06/26/2022 21:40 WG1885693 Bromomethane ND 5.00 1 06/26/2022 21:40 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 21:40 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 21:40 WG1885693 Chloroethane ND 5.00 1 06/26/2022 21:40 WG1885693 Chloroform ND 5.00 1 06/26/2022 21:40 WG1885693 Chloromethane ND 2.50 1 06/26/2022 21:40 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 21:40 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 21:40 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 21:40 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 21:40 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 21:40 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 21:40 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 21:40 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 21:40 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 21:40 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 21:40 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 21:40 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 21:40 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 21:40 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 21:40 WG1885693 Ethylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 21:40 WG1885693 Isopropylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 21:40 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 21:40 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 21:40 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 21:40 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 21:40 WG1885693 Naphthalene ND 5.00 1 06/26/2022 21:40 WG1885693 n-Propylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Styrene ND 1.00 1 06/26/2022 21:40 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 21:40 WG1885693 Toluene ND 1.00 1 06/26/2022 21:40 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 21:40 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 21:40 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 21:40 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 15 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 15 of 27 SAMPLE RESULTS - 06 L1506699 MW-6 Collected date/time: 06/16/22 09:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 21:40 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 21:40 WG1885693 1,2,4-Trimethylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 21:40 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 21:40 WG1885693 o-Xylene ND 1.00 1 06/26/2022 21:40 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 21:40 WG1885693 (S) Toluene-d8 102 80.0-120 06/26/2022 21:40 WG1885693 (S) 4-Bromofluorobenzene 96.8 77.0-126 06/26/2022 21:40 WG1885693 (S) 1,2-Dichloroethane-d4 111 70.0-130 06/26/2022 21:40 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 16 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 16 of 27 SAMPLE RESULTS - 07 L1506699 MW-7 Collected date/time: 06/16/22 10:00 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 22:02 WG1885693 Acrolein ND 50.0 1 06/26/2022 22:02 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 22:02 WG1885693 Benzene ND 1.00 1 06/26/2022 22:02 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 22:02 WG1885693 Bromoform ND 1.00 1 06/26/2022 22:02 WG1885693 Bromomethane ND 5.00 1 06/26/2022 22:02 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 22:02 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 22:02 WG1885693 Chloroethane ND 5.00 1 06/26/2022 22:02 WG1885693 Chloroform ND 5.00 1 06/26/2022 22:02 WG1885693 Chloromethane ND 2.50 1 06/26/2022 22:02 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 22:02 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 22:02 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 22:02 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 22:02 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 22:02 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 22:02 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 22:02 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 22:02 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 22:02 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 22:02 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 22:02 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 22:02 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 22:02 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 22:02 WG1885693 Ethylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 22:02 WG1885693 Isopropylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 22:02 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 22:02 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 22:02 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 22:02 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 22:02 WG1885693 Naphthalene ND 5.00 1 06/26/2022 22:02 WG1885693 n-Propylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Styrene ND 1.00 1 06/26/2022 22:02 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 22:02 WG1885693 Toluene ND 1.00 1 06/26/2022 22:02 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 22:02 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 22:02 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 22:02 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 17 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 17 of 27 SAMPLE RESULTS - 07 L1506699 MW-7 Collected date/time: 06/16/22 10:00 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 22:02 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 22:02 WG1885693 1,2,4-Trimethylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 22:02 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 22:02 WG1885693 o-Xylene ND 1.00 1 06/26/2022 22:02 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 22:02 WG1885693 (S) Toluene-d8 104 80.0-120 06/26/2022 22:02 WG1885693 (S) 4-Bromofluorobenzene 99.6 77.0-126 06/26/2022 22:02 WG1885693 (S) 1,2-Dichloroethane-d4 108 70.0-130 06/26/2022 22:02 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 18 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 18 of 27 SAMPLE RESULTS - 08 L1506699 MW-8 Collected date/time: 06/16/22 09:45 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Acetone ND 50.0 1 06/26/2022 22:24 WG1885693 Acrolein ND 50.0 1 06/26/2022 22:24 WG1885693 Acrylonitrile ND 10.0 1 06/26/2022 22:24 WG1885693 Benzene ND 1.00 1 06/26/2022 22:24 WG1885693 Bromobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Bromodichloromethane ND 1.00 1 06/26/2022 22:24 WG1885693 Bromoform ND 1.00 1 06/26/2022 22:24 WG1885693 Bromomethane ND 5.00 1 06/26/2022 22:24 WG1885693 n-Butylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 sec-Butylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 tert-Butylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Carbon tetrachloride ND 1.00 1 06/26/2022 22:24 WG1885693 Chlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Chlorodibromomethane ND 1.00 1 06/26/2022 22:24 WG1885693 Chloroethane ND 5.00 1 06/26/2022 22:24 WG1885693 Chloroform ND 5.00 1 06/26/2022 22:24 WG1885693 Chloromethane ND 2.50 1 06/26/2022 22:24 WG1885693 2-Chlorotoluene ND 1.00 1 06/26/2022 22:24 WG1885693 4-Chlorotoluene ND 1.00 1 06/26/2022 22:24 WG1885693 1,2-Dibromo-3-Chloropropane ND 5.00 1 06/26/2022 22:24 WG1885693 1,2-Dibromoethane ND 1.00 1 06/26/2022 22:24 WG1885693 Dibromomethane ND 1.00 1 06/26/2022 22:24 WG1885693 1,2-Dichlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 1,3-Dichlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 1,4-Dichlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Dichlorodifluoromethane ND 5.00 1 06/26/2022 22:24 WG1885693 1,1-Dichloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 1,2-Dichloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 1,1-Dichloroethene ND 1.00 1 06/26/2022 22:24 WG1885693 cis-1,2-Dichloroethene ND 1.00 1 06/26/2022 22:24 WG1885693 trans-1,2-Dichloroethene ND 1.00 1 06/26/2022 22:24 WG1885693 1,2-Dichloropropane ND 1.00 1 06/26/2022 22:24 WG1885693 1,1-Dichloropropene ND 1.00 1 06/26/2022 22:24 WG1885693 1,3-Dichloropropane ND 1.00 1 06/26/2022 22:24 WG1885693 2,2-Dichloropropane ND 1.00 1 06/26/2022 22:24 WG1885693 Di-isopropyl ether ND 1.00 1 06/26/2022 22:24 WG1885693 Ethylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Hexachloro-1,3-butadiene ND 1.00 1 06/26/2022 22:24 WG1885693 Isopropylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 p-Isopropyltoluene ND 1.00 1 06/26/2022 22:24 WG1885693 2-Butanone (MEK)ND 10.0 1 06/26/2022 22:24 WG1885693 Methylene Chloride ND J4 5.00 1 06/26/2022 22:24 WG1885693 4-Methyl-2-pentanone (MIBK)ND 10.0 1 06/26/2022 22:24 WG1885693 Methyl tert-butyl ether ND 1.00 1 06/26/2022 22:24 WG1885693 Naphthalene ND 5.00 1 06/26/2022 22:24 WG1885693 n-Propylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Styrene ND 1.00 1 06/26/2022 22:24 WG1885693 1,1,1,2-Tetrachloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 1,1,2,2-Tetrachloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 Tetrachloroethene ND 1.00 1 06/26/2022 22:24 WG1885693 Toluene ND 1.00 1 06/26/2022 22:24 WG1885693 1,2,3-Trichlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 1,2,4-Trichlorobenzene ND 1.00 1 06/26/2022 22:24 WG1885693 1,1,1-Trichloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 1,1,2-Trichloroethane ND 1.00 1 06/26/2022 22:24 WG1885693 Trichloroethene ND 1.00 1 06/26/2022 22:24 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 19 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 19 of 27 SAMPLE RESULTS - 08 L1506699 MW-8 Collected date/time: 06/16/22 09:45 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/l ug/l date / time Trichlorofluoromethane ND 5.00 1 06/26/2022 22:24 WG1885693 1,2,3-Trichloropropane ND 2.50 1 06/26/2022 22:24 WG1885693 1,2,4-Trimethylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 1,3,5-Trimethylbenzene ND 1.00 1 06/26/2022 22:24 WG1885693 Vinyl chloride ND 1.00 1 06/26/2022 22:24 WG1885693 o-Xylene ND 1.00 1 06/26/2022 22:24 WG1885693 m&p-Xylenes ND 2.00 1 06/26/2022 22:24 WG1885693 (S) Toluene-d8 102 80.0-120 06/26/2022 22:24 WG1885693 (S) 4-Bromofluorobenzene 97.1 77.0-126 06/26/2022 22:24 WG1885693 (S) 1,2-Dichloroethane-d4 108 70.0-130 06/26/2022 22:24 WG1885693 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 20 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 20 of 27 QUALITY CONTROL SUMMARYWG1885693 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1506699-01,02,03,04,05,06,07,08 Method Blank (MB) (MB) R3807990-4 06/26/22 16:53 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l Acetone U 11.3 50.0 Acrolein U 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene U 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 sec-Butylbenzene U 0.125 1.00 tert-Butylbenzene U 0.127 1.00 Carbon tetrachloride U 0.128 1.00 Chlorobenzene U 0.116 1.00 Chlorodibromomethane U 0.140 1.00 Chloroethane U 0.192 5.00 Chloroform U 0.111 5.00 Chloromethane U 0.960 2.50 2-Chlorotoluene U 0.106 1.00 4-Chlorotoluene U 0.114 1.00 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1,2-Dibromoethane U 0.126 1.00 Dibromomethane U 0.122 1.00 1,2-Dichlorobenzene U 0.107 1.00 1,3-Dichlorobenzene U 0.110 1.00 1,4-Dichlorobenzene U 0.120 1.00 Dichlorodifluoromethane U 0.374 5.00 1,1-Dichloroethane U 0.100 1.00 1,2-Dichloroethane U 0.0819 1.00 1,1-Dichloroethene U 0.188 1.00 cis-1,2-Dichloroethene U 0.126 1.00 trans-1,2-Dichloroethene U 0.149 1.00 1,2-Dichloropropane U 0.149 1.00 1,1-Dichloropropene U 0.142 1.00 1,3-Dichloropropane U 0.110 1.00 2,2-Dichloropropane U 0.161 1.00 Di-isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 21 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 21 of 27 QUALITY CONTROL SUMMARYWG1885693 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1506699-01,02,03,04,05,06,07,08 Method Blank (MB) (MB) R3807990-4 06/26/22 16:53 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l 2-Butanone (MEK)U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK)U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethylbenzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 o-Xylene U 0.174 1.00 m&p-Xylenes U 0.430 2.00 (S) Toluene-d8 99.2 80.0-120 (S) 4-Bromofluorobenzene 99.7 77.0-126 (S) 1,2-Dichloroethane-d4 109 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3807990-1 06/26/22 15:03 • (LCSD) R3807990-2 06/26/22 15:25 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Acetone 25.0 28.9 30.0 116 120 19.0-160 3.74 27 Acrolein 25.0 23.8 26.4 95.2 106 10.0-160 10.4 26 Acrylonitrile 25.0 24.4 29.1 97.6 116 55.0-149 17.6 20 Benzene 5.00 5.58 5.82 112 116 70.0-123 4.21 20 Bromobenzene 5.00 4.91 5.20 98.2 104 73.0-121 5.74 20 Bromodichloromethane 5.00 5.18 5.47 104 109 75.0-120 5.45 20 Bromoform 5.00 3.88 4.29 77.6 85.8 68.0-132 10.0 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 22 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 22 of 27 QUALITY CONTROL SUMMARYWG1885693 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1506699-01,02,03,04,05,06,07,08 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3807990-1 06/26/22 15:03 • (LCSD) R3807990-2 06/26/22 15:25 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Bromomethane 5.00 4.51 4.18 90.2 83.6 10.0-160 7.59 25 n-Butylbenzene 5.00 5.39 5.52 108 110 73.0-125 2.38 20 sec-Butylbenzene 5.00 5.57 5.82 111 116 75.0-125 4.39 20 tert-Butylbenzene 5.00 5.34 5.47 107 109 76.0-124 2.41 20 Carbon tetrachloride 5.00 5.41 5.48 108 110 68.0-126 1.29 20 Chlorobenzene 5.00 4.97 5.35 99.4 107 80.0-121 7.36 20 Chlorodibromomethane 5.00 4.36 4.51 87.2 90.2 77.0-125 3.38 20 Chloroethane 5.00 5.54 5.77 111 115 47.0-150 4.07 20 Chloroform 5.00 5.47 5.90 109 118 73.0-120 7.56 20 Chloromethane 5.00 3.65 3.61 73.0 72.2 41.0-142 1.10 20 2-Chlorotoluene 5.00 5.39 5.67 108 113 76.0-123 5.06 20 4-Chlorotoluene 5.00 4.99 5.11 99.8 102 75.0-122 2.38 20 1,2-Dibromo-3-Chloropropane 5.00 3.57 4.15 71.4 83.0 58.0-134 15.0 20 1,2-Dibromoethane 5.00 4.69 4.95 93.8 99.0 80.0-122 5.39 20 Dibromomethane 5.00 5.45 5.51 109 110 80.0-120 1.09 20 1,2-Dichlorobenzene 5.00 4.82 5.08 96.4 102 79.0-121 5.25 20 1,3-Dichlorobenzene 5.00 4.94 5.05 98.8 101 79.0-120 2.20 20 1,4-Dichlorobenzene 5.00 4.85 5.34 97.0 107 79.0-120 9.62 20 Dichlorodifluoromethane 5.00 4.83 4.75 96.6 95.0 51.0-149 1.67 20 1,1-Dichloroethane 5.00 5.52 5.71 110 114 70.0-126 3.38 20 1,2-Dichloroethane 5.00 5.46 5.71 109 114 70.0-128 4.48 20 1,1-Dichloroethene 5.00 5.46 5.46 109 109 71.0-124 0.000 20 cis-1,2-Dichloroethene 5.00 5.75 5.81 115 116 73.0-120 1.04 20 trans-1,2-Dichloroethene 5.00 5.51 5.56 110 111 73.0-120 0.903 20 1,2-Dichloropropane 5.00 5.69 5.89 114 118 77.0-125 3.45 20 1,1-Dichloropropene 5.00 5.73 5.86 115 117 74.0-126 2.24 20 1,3-Dichloropropane 5.00 4.83 5.17 96.6 103 80.0-120 6.80 20 2,2-Dichloropropane 5.00 5.56 5.60 111 112 58.0-130 0.717 20 Di-isopropyl ether 5.00 5.41 5.64 108 113 58.0-138 4.16 20 Ethylbenzene 5.00 5.35 5.32 107 106 79.0-123 0.562 20 Hexachloro-1,3-butadiene 5.00 5.42 5.32 108 106 54.0-138 1.86 20 Isopropylbenzene 5.00 5.41 5.60 108 112 76.0-127 3.45 20 p-Isopropyltoluene 5.00 5.31 5.53 106 111 76.0-125 4.06 20 2-Butanone (MEK)25.0 25.1 27.8 100 111 44.0-160 10.2 20 Methylene Chloride 5.00 5.62 6.04 112 121 67.0-120 J4 7.20 20 4-Methyl-2-pentanone (MIBK)25.0 25.1 27.5 100 110 68.0-142 9.13 20 Methyl tert-butyl ether 5.00 5.08 5.50 102 110 68.0-125 7.94 20 Naphthalene 5.00 4.15 4.52 83.0 90.4 54.0-135 8.54 20 n-Propylbenzene 5.00 5.57 5.65 111 113 77.0-124 1.43 20 Styrene 5.00 4.69 4.78 93.8 95.6 73.0-130 1.90 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 23 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 23 of 27 QUALITY CONTROL SUMMARYWG1885693 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1506699-01,02,03,04,05,06,07,08 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3807990-1 06/26/22 15:03 • (LCSD) R3807990-2 06/26/22 15:25 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% 1,1,1,2-Tetrachloroethane 5.00 4.80 4.87 96.0 97.4 75.0-125 1.45 20 1,1,2,2-Tetrachloroethane 5.00 5.02 5.37 100 107 65.0-130 6.74 20 Tetrachloroethene 5.00 5.35 5.54 107 111 72.0-132 3.49 20 Toluene 5.00 5.04 5.30 101 106 79.0-120 5.03 20 1,2,3-Trichlorobenzene 5.00 4.68 5.02 93.6 100 50.0-138 7.01 20 1,2,4-Trichlorobenzene 5.00 4.58 4.89 91.6 97.8 57.0-137 6.55 20 1,1,1-Trichloroethane 5.00 5.69 5.71 114 114 73.0-124 0.351 20 1,1,2-Trichloroethane 5.00 4.76 5.07 95.2 101 80.0-120 6.31 20 Trichloroethene 5.00 5.41 5.69 108 114 78.0-124 5.05 20 Trichlorofluoromethane 5.00 6.02 5.94 120 119 59.0-147 1.34 20 1,2,3-Trichloropropane 5.00 5.00 5.27 100 105 73.0-130 5.26 20 1,2,4-Trimethylbenzene 5.00 5.11 5.22 102 104 76.0-121 2.13 20 1,3,5-Trimethylbenzene 5.00 5.33 5.48 107 110 76.0-122 2.78 20 Vinyl chloride 5.00 5.32 5.29 106 106 67.0-131 0.566 20 o-Xylene 5.00 4.86 5.30 97.2 106 80.0-122 8.66 20 m&p-Xylenes 10.0 10.2 11.0 102 110 80.0-122 7.55 20 (S) Toluene-d8 98.5 99.5 80.0-120 (S) 4-Bromofluorobenzene 99.1 98.5 77.0-126 (S) 1,2-Dichloroethane-d4 106 107 70.0-130 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 24 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 24 of 27 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). RDL Reported Detection Limit. Rec.Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. (S) Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Dilution If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Limits These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Qualifier This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. Result The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry)Confidence level of 2 sigma. Case Narrative (Cn) A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control Summary (Qc) This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. Sample Chain of Custody (Sc) This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. Sample Results (Sr) This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J4 The associated batch QC was outside the established quality control range for accuracy. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 25 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 25 of 27 Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey–NELAP TN002 California 2932 New Mexico ¹TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina ¹DW21704 Georgia NELAP North Carolina ³41 Georgia ¹923 North Dakota R-140 Idaho TN00003 Ohio–VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LAO00356 Kentucky ¹ ⁶KY90010 South Carolina 84004002 Kentucky ²16 South Dakota n/a Louisiana AI30792 Tennessee ¹ ⁴2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas ⁵LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2LA A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2LA – ISO 17025 ⁵1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA–Crypto TN00003 ACCREDITATIONS & LOCATIONS ¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/27/22 17:04 26 of 27 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: Terracon - Greensboro, NC 75207118 L1506699 06/28/22 12:28 26 of 27 APPENDIX C AQTESOLV RESULTS AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\MW2 Slug In.aqt Date: 07/18/22 Time: 10:00:15 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 20.9 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:MW2 Slug In X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.0637 ft Static Water Column Height: 10.9 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 10.9 ft Total Well Penetration Depth: 10.9 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 62 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 160.0.0637 780.0.0001 180.0.0141 800.-0.001 200.0.0092 820.-0.0009 220.0.009 840.-0.0024 240.0.0026 860.-0.0005 260.0.0038 880.-0.0026 280.0.0033 900.-0.0013 300.0.0014 920.-0.0012 320.0.0029 940.-0.0014 340.0.0026 960.-0.0023 360.0.0026 980.-0.0012 380.0.003 1000.-0.0018 400.0.0019 1020.-0.0011 420.-0.0001 1040.-0.0015 440.0.0019 1060.-0.0019 07/18/22 1 10:00:15 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 460.0.0019 1080.-0.007 480.0.0018 1100.-0.0008 500.-0.0011 1120.-0.0019 520.0.0009 1140.-0.0025 540.-0.0008 1160.-0.0024 560.0.0005 1180.-0.0009 580.-0.0001 1200.-0.0007 600.0.0008 1220.-0.0024 620.-0.0009 1240.-0.0025 640.0.0002 1260.-0.0023 660.0.0007 1280.-0.0048 680.-0.0003 1300.-0.0017 700.-0.0003 1320.-0.0037 720.-0.0005 1340.-0.0031 740.-0.0012 1360.-0.005 760.-0.0005 1380.-0.0024 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.841 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0007211 ft/min y0 0.00845 ft K = 0.0003663 cm/sec T = K*b = 0.01507 ft²/min (0.2334 sq. cm/sec) 07/18/22 2 10:00:15 0. 400. 800. 1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set: \...\MW2 Slug In.aqt Date: 07/18/22 Time: 09:59:58 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Well: MW-3 Test Date: 3/7/22 AQUIFER DATA Saturated Thickness: 20.9 ft Anisotropy Ratio (Kz/Kr): 1. WELL DATA (MW2 Slug In) Initial Displacement: 0.0637 ft Static Water Column Height: 10.9 ft Total Well Penetration Depth: 10.9 ft Screen Length: 10.9 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Gravel Pack Porosity: 0. SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0007211 ft/min y0 = 0.00845 ft AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\MW2 Slug Out.aqt Date: 07/18/22 Time: 10:01:14 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 20.9 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:MW2 Slug Out X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.1211 ft Static Water Column Height: 10.9 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 10.9 ft Total Well Penetration Depth: 10.9 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 60 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 20.0.0016 620.0.0088 40.0.1211 640.0.0076 60.0.0297 660.0.0098 80.0.0166 680.0.0082 100.0.0101 700.0.0067 120.0.0083 720.0.0097 140.0.0074 740.0.0081 160.0.0065 760.0.0091 180.0.0074 780.0.0095 200.0.0068 800.0.0105 220.0.0075 820.0.0098 240.0.0076 840.0.0114 260.0.006 860.0.0095 280.0.0063 880.0.0092 300.0.0052 900.0.0111 07/18/22 1 10:01:14 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 320.0.0078 920.0.0095 340.0.0052 940.0.0106 360.0.0044 960.0.0102 380.0.0059 980.0.011 400.0.0052 1000.0.0107 420.0.0057 1020.0.0114 440.0.0054 1040.0.0122 460.0.0057 1060.0.0123 480.0.0062 1080.0.0118 500.0.0068 1100.0.0102 520.0.007 1120.0.0121 540.0.0064 1140.0.0129 560.0.0057 1160.0.0095 580.0.008 1180.0.0118 600.0.0065 1200.0.0116 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.841 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0006576 ft/min y0 0.01339 ft K = 0.0003341 cm/sec T = K*b = 0.01374 ft²/min (0.2128 sq. cm/sec) 07/18/22 2 10:01:14 0.400.800.1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set:\...\MW2 Slug Out.aqt Date:07/18/22 Time:10:00:51 PROJECT INFORMATION Company:Terracon Client:NCDEQ Project:75159687B Location:Mocksville, NC Test Well:MW-3 Test Date:3/7/22 AQUIFER DATA Saturated Thickness:20.9 ft Anisotropy Ratio (Kz/Kr):1. WELL DATA (MW2 Slug Out) Initial Displacement:0.1211 ft Static Water Column Height:10.9 ft Total Well Penetration Depth:10.9 ft Screen Length:10.9 ft Casing Radius:0.166 ft Well Radius:0.166 ft Gravel Pack Porosity:0. SOLUTION Aquifer Model:Unconfined Solution Method:Bouwer-Rice K =0.0006576 ft/min y0 =0.01339 ft AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\MW3 Slug In.aqt Date: 07/18/22 Time: 10:01:51 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 21.76 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:MW3 Slug In X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.1491 ft Static Water Column Height: 11.76 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 11.76 ft Total Well Penetration Depth: 11.76 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 60 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 20.0.1491 620.0.0033 40.0.1296 640.0.004 60.0.1123 660.0.0024 80.0.1009 680.0.0013 100.0.0886 700.0.0021 120.0.0786 720.0.0003 140.0.0723 740.0.0022 160.0.063 760.0. 180.0.0565 780.0.0025 200.0.0502 800.0.0007 220.0.0444 820.0.0011 240.0.0424 840.0.0041 260.0.0388 860.0.0031 280.0.0348 880.0.0049 300.0.03 900.0.0006 07/18/22 1 10:01:51 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 320.0.0292 920.0.0043 340.0.025 940.0.0032 360.0.0239 960.0.0026 380.0.0221 980.0.0016 400.0.0178 1000.0.0029 420.0.0165 1020.0.0024 440.0.0133 1040.0.0048 460.0.0121 1060.0.0044 480.0.0122 1080.0.0039 500.0.0091 1100.0.0017 520.0.0085 1120.0.0032 540.0.0078 1140.0.0041 560.0.0073 1160.0.0036 580.0.0067 1180.0.0054 600.0.0049 1200.0.0047 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.905 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0007551 ft/min y0 0.03522 ft K = 0.0003836 cm/sec T = K*b = 0.01643 ft²/min (0.2544 sq. cm/sec) 07/18/22 2 10:01:51 0.400.800.1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set:\...\MW3 Slug In.aqt Date:07/18/22 Time:10:01:37 PROJECT INFORMATION Company:Terracon Client:NCDEQ Project:75159687B Location:Mocksville, NC Test Well:MW-3 Test Date:3/7/22 AQUIFER DATA Saturated Thickness:21.76 ft Anisotropy Ratio (Kz/Kr):1. WELL DATA (MW3 Slug In) Initial Displacement:0.1491 ft Static Water Column Height:11.76 ft Total Well Penetration Depth:11.76 ft Screen Length:11.76 ft Casing Radius:0.166 ft Well Radius:0.166 ft Gravel Pack Porosity:0. SOLUTION Aquifer Model:Unconfined Solution Method:Bouwer-Rice K =0.0007551 ft/min y0 =0.03522 ft AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\MW3 Slug Out.aqt Date: 07/18/22 Time: 10:02:27 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 21.76 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:MW3 Slug In X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.1728 ft Static Water Column Height: 11.76 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 11.76 ft Total Well Penetration Depth: 11.76 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 60 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 20.0.1728 620.0.0162 40.0.0861 640.0.0181 60.0.0738 660.0.015 80.0.0677 680.0.0133 100.0.0597 700.0.0124 120.0.0604 720.0.012 140.0.0581 740.0.0131 160.0.0587 760.0.012 180.0.0563 780.0.0117 200.0.0541 800.0.0133 220.0.0522 820.0.014 240.0.0483 840.0.0117 260.0.0441 860.0.0129 280.0.0424 880.0.011 300.0.0411 900.0.0107 07/18/22 1 10:02:27 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 320.0.0381 920.0.0116 340.0.0334 940.0.0118 360.0.0339 960.0.0108 380.0.031 980.0.0094 400.0.031 1000.0.0113 420.0.0279 1020.0.0115 440.0.0266 1040.0.0101 460.0.0257 1060.0.0095 480.0.0228 1080.0.0085 500.0.0233 1100.0.0094 520.0.0206 1120.0.0075 540.0.0198 1140.0.0101 560.0.0185 1160.0.0101 580.0.0183 1180.0.0106 600.0.0157 1200.0.0113 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.905 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0005998 ft/min y0 0.09702 ft K = 0.0003047 cm/sec T = K*b = 0.01305 ft²/min (0.2021 sq. cm/sec) 07/18/22 2 10:02:27 0.400.800.1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set:\...\MW3 Slug Out.aqt Date:07/18/22 Time:10:02:13 PROJECT INFORMATION Company:Terracon Client:NCDEQ Project:75159687B Location:Mocksville, NC Test Well:MW-3 Test Date:3/7/22 AQUIFER DATA Saturated Thickness:21.76 ft Anisotropy Ratio (Kz/Kr):1. WELL DATA (MW3 Slug In) Initial Displacement:0.1728 ft Static Water Column Height:11.76 ft Total Well Penetration Depth:11.76 ft Screen Length:11.76 ft Casing Radius:0.166 ft Well Radius:0.166 ft Gravel Pack Porosity:0. SOLUTION Aquifer Model:Unconfined Solution Method:Bouwer-Rice K =0.0005998 ft/min y0 =0.09702 ft AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\RW5 Slug In.aqt Date: 07/18/22 Time: 10:03:00 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 19.94 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:RW5 Slug In X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.1132 ft Static Water Column Height: 6.94 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 6.94 ft Total Well Penetration Depth: 6.94 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 61 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 20.0.1132 640.0.0718 40.0.1032 660.0.0707 60.0.1012 680.0.0697 80.0.0987 700.0.0684 100.0.0964 720.0.0696 120.0.0931 740.0.0678 140.0.0917 760.0.0679 160.0.0918 780.0.0697 180.0.0899 800.0.0679 200.0.0884 820.0.0667 220.0.0904 840.0.0671 240.0.0888 860.0.0669 260.0.0875 880.0.0687 280.0.086 900.0.0686 300.0.0846 920.0.0657 07/18/22 1 10:03:00 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 320.0.085 940.0.0685 340.0.084 960.0.0676 360.0.082 980.0.0692 380.0.0835 1000.0.0703 400.0.0844 1020.0.0701 420.0.0835 1040.0.0675 440.0.0834 1060.0.0678 460.0.0825 1080.0.0667 480.0.0798 1100.0.0664 500.0.0788 1120.0.0667 520.0.0787 1140.0.0654 540.0.0754 1160.0.0644 560.0.0772 1180.0.0637 580.0.0752 1200.0.0633 600.0.0738 1220.0.0623 620.0.0748 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.441 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0003304 ft/min y0 0.1083 ft K = 0.0001679 cm/sec T = K*b = 0.006588 ft²/min (0.102 sq. cm/sec) AUTOMATIC ESTIMATION RESULTS Estimated Parameters Parameter Estimate Std. Error Approx. C.I.t-Ratio K 0.00012 5.03E-6 +/- 1.007E-5 23.85 ft/min y0 0.09873 0.001062 +/- 0.002124 93.ft C.I. is approximate 95% confidence interval for parameter t-ratio = estimate/std. error No estimation window K = 6.094E-5 cm/sec T = K*b = 0.002392 ft²/min (0.03704 sq. cm/sec) Parameter Correlations K y0 07/18/22 2 10:03:00 AQTESOLV for Windows K 1.00 0.83 y0 0.83 1.00 Residual Statistics for weighted residuals Sum of Squares.. 0.0007705 ft2 Variance.......... 1.306E-5 ft2 Std. Deviation .... 0.003614 ft Mean ............. 2.571E-5 ft No. of Residuals . 61 No. of Estimates.. 2 07/18/22 3 10:03:00 0.400.800.1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set:\...\RW5 Slug In.aqt Date:07/18/22 Time:10:02:44 PROJECT INFORMATION Company:Terracon Client:NCDEQ Project:75159687B Location:Mocksville, NC Test Well:MW-3 Test Date:3/7/22 AQUIFER DATA Saturated Thickness:19.94 ft Anisotropy Ratio (Kz/Kr):1. WELL DATA (RW5 Slug In) Initial Displacement:0.1132 ft Static Water Column Height:6.94 ft Total Well Penetration Depth:6.94 ft Screen Length:6.94 ft Casing Radius:0.166 ft Well Radius:0.166 ft Gravel Pack Porosity:0. SOLUTION Aquifer Model:Unconfined Solution Method:Bouwer-Rice K =0.0003304 ft/min y0 =0.1083 ft AQTESOLV for Windows Data Set: \\P75WFS01\Data\Projects\2020\75207118\Working Files\Diagrams-Drawings-Figures\Model\AQTESOLV\RW5 Slug Out.aqt Date: 07/18/22 Time: 10:03:37 PROJECT INFORMATION Company: Terracon Client: NCDEQ Project: 75159687B Location: Mocksville, NC Test Date: 3/7/22 Test Well: MW-3 AQUIFER DATA Saturated Thickness: 19.94 ft Anisotropy Ratio (Kz/Kr): 1. SLUG TEST WELL DATA Test Well:RW5 Slug Out X Location: 0. ft Y Location: 0. ft Initial Displacement: 0.1232 ft Static Water Column Height: 6.94 ft Casing Radius: 0.166 ft Well Radius: 0.166 ft Well Skin Radius: 0.166 ft Screen Length: 6.94 ft Total Well Penetration Depth: 6.94 ft Corrected Casing Radius (Bouwer-Rice Method): 0.166 ft Gravel Pack Porosity: 0. No. of Observations: 63 Observation Data Time (sec)Displacement (ft)Time (sec)Displacement (ft) 20.0.1232 660.0.0636 40.0.0992 680.0.062 60.0.0948 700.0.0614 80.0.0928 720.0.0628 100.0.0894 740.0.0622 120.0.0903 760.0.061 140.0.0915 780.0.0606 160.0.09 800.0.0595 180.0.0884 820.0.06 200.0.0886 840.0.0582 220.0.0873 860.0.0566 240.0.0855 880.0.0576 260.0.083 900.0.0549 280.0.0829 920.0.0537 300.0.0822 940.0.0531 07/18/22 1 10:03:37 AQTESOLV for Windows Time (sec)Displacement (ft)Time (sec)Displacement (ft) 320.0.0821 960.0.0531 340.0.0804 980.0.0526 360.0.0798 1000.0.0519 380.0.0782 1020.0.0519 400.0.0759 1040.0.0492 420.0.074 1060.0.0498 440.0.0759 1080.0.0495 460.0.0774 1100.0.049 480.0.0756 1120.0.0473 500.0.0728 1140.0.0485 520.0.0735 1160.0.0466 540.0.0726 1180.0.0465 560.0.0705 1200.0.0451 580.0.0708 1220.0.0448 600.0.0686 1240.0.0443 620.0.0647 1260.0.0441 640.0.0667 SOLUTION Slug Test Aquifer Model: Unconfined Solution Method: Bouwer-Rice ln(Re/rw): 2.441 VISUAL ESTIMATION RESULTS Estimated Parameters Parameter Estimate K 0.0004734 ft/min y0 0.1068 ft K = 0.0002405 cm/sec T = K*b = 0.00944 ft²/min (0.1462 sq. cm/sec) AUTOMATIC ESTIMATION RESULTS Estimated Parameters Parameter Estimate Std. Error Approx. C.I.t-Ratio K 0.0001974 5.117E-6 +/- 1.023E-5 38.57 ft/min y0 0.102 0.001035 +/- 0.00207 98.53 ft C.I. is approximate 95% confidence interval for parameter t-ratio = estimate/std. error No estimation window K = 0.0001003 cm/sec T = K*b = 0.003935 ft²/min (0.06094 sq. cm/sec) Parameter Correlations 07/18/22 2 10:03:37 AQTESOLV for Windows K y0 K 1.00 0.81 y0 0.81 1.00 Residual Statistics for weighted residuals Sum of Squares.. 0.0006671 ft2 Variance.......... 1.094E-5 ft2 Std. Deviation .... 0.003307 ft Mean ............. 1.271E-5 ft No. of Residuals . 63 No. of Estimates.. 2 07/18/22 3 10:03:37 0.400.800.1.2E+3 1.6E+3 2.0E+3 0.001 0.01 0.1 1. Time (sec)Normalized Head (ft/ft)WELL TEST ANALYSIS Data Set:\...\RW5 Slug Out.aqt Date:07/18/22 Time:10:03:20 PROJECT INFORMATION Company:Terracon Client:NCDEQ Project:75159687B Location:Mocksville, NC Test Well:MW-3 Test Date:3/7/22 AQUIFER DATA Saturated Thickness:19.94 ft Anisotropy Ratio (Kz/Kr):1. WELL DATA (RW5 Slug Out) Initial Displacement:0.1232 ft Static Water Column Height:6.94 ft Total Well Penetration Depth:6.94 ft Screen Length:6.94 ft Casing Radius:0.166 ft Well Radius:0.166 ft Gravel Pack Porosity:0. SOLUTION Aquifer Model:Unconfined Solution Method:Bouwer-Rice K =0.0004734 ft/min y0 =0.1068 ft APPENDIX D RBCA TOOLKIT MODEL RESULTS RBCA Tool Kit for Chemical Releases, Version 2.6 ##4. RBCA Evaluation Process 1. Project Information Site Name: Location: Completed By: Date:11-Jul-22 Job ID:75207118 2. Which Type of RBCA Analysis? ##### ##### ##### 3. Calculation Options ### ### Individual Constituent Risk Goals Only Individual and Cumulative Risk Goals 5. Commands and Options Apply Source Depletion Algorithm Time to Future Exposure 0 (yr) C. Driscoll Surry County, NC Jerrys Place Baseline Risks (Forward mode) RBCA Cleanup Levels (Backward mode) Main Screen Affects which input data are required Prepare Input Data Review Output Data Complete? ( = yes, = no) Site-Specific Target Levels Risk-Based Screening Levels Tier Tier 2/3 RBCA Tool Kit for Chemical Releases© 2011 GSI Environmental Inc.Version 2.6 User Chemical Database ? Print Sheet New Site QuitHelp Sav e Data ? Set Units Print Load Data... Exposure Pathways Air ParametersAir Parameters GW Parameters Soil ParametersSoil Parameters Transport Models Constituents of Concern (COCs) Exposure Flowchart COC Chem. Parameters Input Data Summary User-Spec. COC Data... Transient Domenico Analysis... Baseline Risks... Cleanup Levels... RBCA Tool Kit for Chemical Releases, Version 2.6 #Site Name: Jerrys Place Location: Surry County, NC 1. Groundwater Exposure Compl. By: C. Driscoll Groundwater Ingestion/Job ID: 75207118 Date: 11-Jul-22 Surface Water Impact 3. Air Exposure Receptor: to Outdoor Air Inhalation On-site Off-site1 Off-site2 Receptor: Distance:0 215 215 (ft)On-site Off-site1 Off-site2 Source Media:Distance:0 0 0 (ft) Affected Groundwater Source Media:Construction worker Affected Soils Leaching to Groundwater Affected Soils--Volatilization to Ambient Outdoor Air Option:Affected Groundwater--Volatilization to Ambient Outdoor Air Apply MCL value as ingestion RBEL (backward mode only)Affected Surface Soils--Particulates to Ambient Outdoor Air GW Discharge to Surface Water Exposure Volatilization to Indoor Air Inhalation Swimming Receptor: Fish Consumption On-site Off-site1 Off-site2 Specified Water Quality Criteria Source Media:Distance:0 0 0 (ft) Affected Soils--Volatilization to Enclosed Space Affected Soils Leaching to GW--Volatilization to Enclosed Space 2. Surface Soil Exposure Affected Groundwater--Volatilization to Enclosed SpaceSource Media: Receptor: Direct Ingestion 4. Commands and Options On-site Dermal Contact Construction Worker Inhalation (vol+part) Option: Vegetable Ingestion Apply UK (CLEA) SGV as soil concentration limit Combined Exposure Volatilization and Particulates Exposure Pathway Identification Main Print Sheet Help ? ? ? Exposure Flowchart Set Units ? Veg OptionsVeg Options Bldg OptionsBldg Options Exposure Factors & Target Risks Enter CriteriaEnter Criteria RBCA Tool Kit for Chemical Releases, Version 2.6 Site Name: Jerrys Place Job ID: 75207118 Commands and Options Location: Surry County, NC Date: 11-Jul-22 Compl. By: C. Driscoll Selected COCs Representative COC Concentration Groundwater Source Zone Soil Source Zone Mole Fraction o n in Source n o Material (mg/L)note (mg/kg)note (-) Benzene 3.0E-1 Concentrations of RW-5 on Toluene 5.8E-1 10/7/2009 sampling event Ethyl benzene 1.1E+0 Xylenes (mixed isomers)3.3E+0 Cumene 8.5E-2 Methyl t-Butyl ether (MTBE)3.4E-2 Naphthalene 5.6E-1 Trimethylbenzene, 1,2,4-1.1E+0 Apply Raoul t's Source Media Constituents of Concern (COCs) COC Sort List: Top Bottom MoveUAdd/Ins Delete MoveD Main Screen Print Help ? ?? View Chemical Parameters Enter Site DataEnter Site Data Enter Site DataEnter Site Data RBCA Tool Kit for Chemical Releases, Version 2.6 ##Site Name: Jerrys Place Job ID: 75207118 Location: Surry County, NC Date: 11-Jul-22 1. Vertical Transport, Surface Soil Column Compl. By: C. Driscoll Outdoor Air Volatilization Factors 3. Groundwater Dilution Attenuation Factor Surface soil volatilization model only Combination surface soil/Johnson & Ettinger models Thickness of surface soil zone 3.28 (ft)Calculate DAF using Domenico Model User-specified VF from other model Domenico equation with dispersion only (no biodegradation) Indoor Air Volatilization Factors Domenico equation first-order decay Johnson & Ettinger model for soil and groundwater volatilization Modified Domenico equation using Johnson & Ettinger for soil, Mass Flux model for groundwater electron acceptor superposition User-specified VF from other model Biodegradation Capacity NC (mg/L) Soil-to-Groundwater Leaching Factor — or — ASTM Model User-Specified DAF Values Apply Soil Attenuation Model (SAM)DAF values from other model or site data Allow first-order biodecay User-specified LF from other model 4. Chemical Decay and Source Depletion Modeling Options Disable Mass Balance Limit Apply Dual Equilibrium Desorption Model 2. Lateral Air Dispersion Factor 5. Commands and Options 3-D Gaussian dispersion model Off-site 1 Off-site 2 User-Specified ADF 1.00E+0 1.00E+0 (-) Transport Modeling Options C Enter VF ValuesEnter VF Values Print SheetMain Screen Help ? ? ASTM ModelASTM Model ? Enter Source MassEnter Source Mass Enter Decay RatesEnter Decay Rates Enter DAF ValuesEnter DAF Values Enter Site DataEnter Site Data Enter Decay Rates Enter Decay RatesEnter Decay Rates Enter LF ValuesEnter LF Values Enter VF ValuesEnter VF Values ? ? ? ? C RBCA Tool Kit for Chemical Releases, Version 2.6 Site Name: Jerrys Place Job ID: 75207118 Commands and Options Location: Surry County, NC Date: 11-Jul-22 Compl. By: C. Driscoll Saturated Zone Unsaturated Zone First-Order Decay First-Order Decay Constituent Half-Life Coefficient Half-Life Coefficient (day)(1/day)(day)(1/day) Benzene 7.2E+2 9.6E-4 7.2E+2 9.6E-4 Toluene 2.8E+1 2.5E-2 2.8E+1 2.5E-2 Ethyl benzene 2.3E+2 3.0E-3 2.3E+2 3.0E-3 Xylenes (mixed isomers)3.6E+2 1.9E-3 3.6E+2 1.9E-3 Cumene 1.6E+1 4.3E-2 1.6E+1 4.3E-2 Methyl t-Butyl ether (MTBE)3.6E+2 1.9E-3 1.8E+2 3.9E-3 Naphthalene 2.6E+2 2.7E-3 2.6E+2 2.7E-3 Trimethylbenzene, 1,2,4-5.6E+1 1.2E-2 5.6E+1 1.2E-2 Constituent Decay Rates Return Print Sheet HelpPaste Default Values RBCA Tool Kit for Chemical Releases, Version 2.6 #Site Name: Jerrys Place Job ID: 75207118 Location: Surry County, NC Date: 11-Jul-22 1. Water-Bearing Unit Compl. By: C. Driscoll Hydrogeology 3. Groundwater Dispersion Groundwater Darcy velocity 1.1E+1 (ft/yr)Model:GW Ingestion Groundwater seepage velocity 3.0E+1 (ft/yr)Off-site 1 Off-site 2 Off-site 1 Off-site 2 or Distance to GW receptors 215 215 0 0 (ft) Hydraulic conductivity 3.1E+2 (ft/yr) Hydraulic gradient 0.0363 (-)Longitudinal dispersivity 21.5 21.5 0 0 (ft) Effective porosity 0.38 (-)Transverse dispersivity 7.095 7.095 0 0 (ft) Sorption Vertical dispersivity 1.075 1.075 0 0 (ft) Fraction organic carbon--saturated zone 0.001 (-) 4. Groundwater Discharge to Surface Water Groundwater pH 6.46 (-) 2. Groundwater Source Zone Off-site 2 Groundwater plume width at source 100 (ft)Distance to GW/SW disharge point NA (ft) Plume (mixing zone) thickness at source 20 (ft) Plume width at GW/SW discharge (ft) Saturated thickness 20 (ft)Plume thickness at GW/SW discharge (ft) Length of source zone 147.637795 (ft) Surface water flowrate at GW/SW discharge (ft^3/yr) 5. Commands and Options GW to Indoor Air Site-Specific Groundwater Parameters or or ? ? ? Main Screen Use/Set Default Values Set Units Print Sheet Help ? RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 1 of 8 Constiuent:Benzene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###8.8E-3 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####8.9E-3 NA POE Concentration Limit (mg/L)4.5E-2 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 9.0E-9 6.1E-5 9.0E-4 2.8E-3 5.0E-3 6.6E-3 7.7E-3 8.3E-3 8.6E-3 8.8E-3 Off-site1 NA Off-site2 (215 ft)0.0E+0 9.0E-9 6.1E-5 9.0E-4 2.8E-3 5.0E-3 6.6E-3 7.7E-3 8.3E-3 8.6E-3 8.8E-3 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 2 of 8 Constiuent:Toluene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###1.5E-13 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####1.5E-13 NA POE Concentration Limit (mg/L)1.3E+0 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 5.0E-15 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 Off-site1 NA Off-site2 (215 ft)0.0E+0 5.0E-15 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 1.5E-13 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 3 of 8 Constiuent:Ethyl benzene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###1.0E-4 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####1.0E-4 NA POE Concentration Limit (mg/L)1.6E+0 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 2.2E-12 5.0E-7 1.5E-5 5.1E-5 8.1E-5 9.5E-5 1.0E-4 1.0E-4 1.0E-4 1.0E-4 Off-site1 NA Off-site2 (215 ft)0.0E+0 2.2E-12 5.0E-7 1.5E-5 5.1E-5 8.1E-5 9.5E-5 1.0E-4 1.0E-4 1.0E-4 1.0E-4 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 4 of 8 Constiuent:Xylenes (mixed isomers) Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###2.1E-3 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####2.2E-3 NA POE Concentration Limit (mg/L)3.1E+0 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 1.1E-12 1.2E-6 7.9E-5 4.6E-4 1.0E-3 1.5E-3 1.9E-3 2.0E-3 2.1E-3 2.1E-3 Off-site1 NA Off-site2 (215 ft)0.0E+0 1.1E-12 1.2E-6 7.9E-5 4.6E-4 1.0E-3 1.5E-3 1.9E-3 2.0E-3 2.1E-3 2.1E-3 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 5 of 8 Constiuent:Cumene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###6.6E-60 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####6.6E-60 NA POE Concentration Limit (mg/L)1.6E+0 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 0.0E+0 3.2E-69 6.6E-61 6.5E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 Off-site1 NA Off-site2 (215 ft)0.0E+0 0.0E+0 3.2E-69 6.6E-61 6.5E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 6.6E-60 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 6 of 8 Constiuent:Methyl t-Butyl ether (MTBE) Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###2.8E-4 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####2.8E-4 NA POE Concentration Limit (mg/L)1.6E-1 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 1.9E-8 1.7E-5 1.1E-4 2.0E-4 2.5E-4 2.7E-4 2.8E-4 2.8E-4 2.8E-4 2.8E-4 Off-site1 NA Off-site2 (215 ft)0.0E+0 1.9E-8 1.7E-5 1.1E-4 2.0E-4 2.5E-4 2.7E-4 2.8E-4 2.8E-4 2.8E-4 2.8E-4 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 7 of 8 Constiuent:Naphthalene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###6.4E-10 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####9.5E-10 NA POE Concentration Limit (mg/L)3.1E-1 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 0.0E+0 1.1E-25 3.8E-18 1.4E-14 1.2E-12 1.8E-11 9.1E-11 2.5E-10 4.5E-10 6.4E-10 Off-site1 NA Off-site2 (215 ft)0.0E+0 0.0E+0 1.1E-25 3.8E-18 1.4E-14 1.2E-12 1.8E-11 9.1E-11 2.5E-10 4.5E-10 6.4E-10 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 8 of 8 Constiuent:Trimethylbenzene, 1,2,4- Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)13.0 #DIV/0!##Off-site1 Off-site2 (for given time)#DIV/0!##Residential None Distance (ft)0 5 10 15 20 25 30 35 40 45 50 ###215 NA t = 13.0 yr #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!###6.1E-17 NA Steady-state #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####6.1E-17 NA POE Concentration Limit (mg/L)7.8E-1 NA t = 13.0 yr Concentration vs. Time Distance (ft)215 #DIV/0! (for given distance from source)0 0 #DIV/0! Time (yr)0 1.3 2.6 3.9 5.2 6.5 7.8 9.1 10.4 11.7 13 13 Time to Reach x = 215 ft #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!#####Conc. Limit (yr) Off-site1 (215 ft)0.0E+0 0.0E+0 8.9E-21 1.0E-17 5.0E-17 6.0E-17 6.1E-17 6.1E-17 6.1E-17 6.1E-17 6.1E-17 Off-site1 NA Off-site2 (215 ft)0.0E+0 0.0E+0 8.9E-21 1.0E-17 5.0E-17 6.0E-17 6.1E-17 6.1E-17 6.1E-17 6.1E-17 6.1E-17 Off-site2 NA x = 215 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-23.0E-24.0E-2 5.0E-2 6.0E-27.0E-28.0E-2 9.0E-2 1.0E-1 0 5 10 15 20 25 30 35 40 45 50Conc. (mg/L)Distance Steady-state t = 13.0 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-3 1.0E-2 1.5E-2 2.0E-2 2.5E-2 3.0E-2 0 2 4 6 8 10 12Conc. (mg/L)Time (yr) x = 215 ft Off-site1 (215 ft) Off-site2 (215 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.6 #Site Name: Jerrys Place Location: Surry County, NC 1. Groundwater Exposure Compl. By: C. Driscoll Groundwater Ingestion/Job ID: 75207118 Date: 11-Jul-22 Surface Water Impact 3. Air Exposure Receptor: to Outdoor Air Inhalation On-site Off-site1 Off-site2 Receptor: Distance:0 90 350 (ft)On-site Off-site1 Off-site2 Source Media:Distance:0 0 0 (ft) Affected Groundwater Source Media:Construction worker Affected Soils Leaching to Groundwater Affected Soils--Volatilization to Ambient Outdoor Air Option:Affected Groundwater--Volatilization to Ambient Outdoor Air Apply MCL value as ingestion RBEL (backward mode only)Affected Surface Soils--Particulates to Ambient Outdoor Air GW Discharge to Surface Water Exposure Volatilization to Indoor Air Inhalation Swimming Receptor: Fish Consumption On-site Off-site1 Off-site2 Specified Water Quality Criteria Source Media:Distance:0 0 0 (ft) Affected Soils--Volatilization to Enclosed Space Affected Soils Leaching to GW--Volatilization to Enclosed Space 2. Surface Soil Exposure Affected Groundwater--Volatilization to Enclosed Space Source Media: Receptor: Direct Ingestion 4. Commands and Options On-site Dermal Contact Construction Worker Inhalation (vol+part) Option: Vegetable Ingestion Apply UK (CLEA) SGV as soil concentration limit Combined Exposure Volatilization and Particulates Exposure Pathway Identification Main Print Sheet Help ? ? ? Exposure Flowchart Set Units ? Veg OptionsVeg Options Bldg OptionsBldg Options Exposure Factors & Target Risks Enter CriteriaEnter Criteria RBCA Tool Kit for Chemical Releases, Version 2.51 Site Name: Jerrys Place Job ID: 75207118 Commands and Options Location: Surry County, NC Date: 11-Jul-22 Compl. By: C. Driscoll Selected COCs Representative COC Concentration Groundwater Source Zone Soil Source Zone Mole Fraction o n in Source n o Material (mg/L)note (mg/kg)note (-) Benzene 0.0E+0 Concentrations of RW-5 on Toluene 0.0E+0 4/29/2021 sampling event Ethyl benzene 4.2E-2 Xylenes (mixed isomers)1.1E-1 Cumene 1.3E-2 Methyl t-Butyl ether (MTBE)0.0E+0 Naphthalene 5.9E-2 Trimethylbenzene, 1,2,4-1.3E-1 Apply Raoul t's Source Media Constituents of Concern (COCs) COC Sort List: Top Bottom MoveUAdd/Ins Delete MoveD Main Screen Print Help ? ?? View Chemical Parameters Enter Site DataEnter Site Data Enter Site DataEnter Site Data RBCA Tool Kit for Chemical Releases, Version 2.6 ##Site Name: Jerrys Place Job ID: 75207118 Location: Surry County, NC Date: 11-Jul-22 1. Vertical Transport, Surface Soil Column Compl. By: C. Driscoll Outdoor Air Volatilization Factors 3. Groundwater Dilution Attenuation Factor Surface soil volatilization model only Combination surface soil/Johnson & Ettinger models Thickness of surface soil zone 3.28 (ft)Calculate DAF using Domenico Model User-specified VF from other model Domenico equation with dispersion only (no biodegradation) Indoor Air Volatilization Factors Domenico equation first-order decay Johnson & Ettinger model for soil and groundwater volatilization Modified Domenico equation using Johnson & Ettinger for soil, Mass Flux model for groundwater electron acceptor superposition User-specified VF from other model Biodegradation Capacity NC (mg/L) Soil-to-Groundwater Leaching Factor — or — ASTM Model User-Specified DAF Values Apply Soil Attenuation Model (SAM)DAF values from other model or site data Allow first-order biodecay User-specified LF from other model 4. Chemical Decay and Source Depletion Modeling Options Disable Mass Balance Limit Apply Dual Equilibrium Desorption Model 2. Lateral Air Dispersion Factor 5. Commands and Options 3-D Gaussian dispersion model Off-site 1 Off-site 2 User-Specified ADF 1.00E+0 1.00E+0 (-) Transport Modeling Options C Enter VF ValuesEnter VF Values Print SheetMain Screen Help ? ? ASTM ModelASTM Model ? Enter Source MassEnter Source Mass Enter Decay RatesEnter Decay Rates Enter DAF ValuesEnter DAF Values Enter Site DataEnter Site Data Enter Decay Rates Enter Decay RatesEnter Decay Rates Enter LF ValuesEnter LF Values Enter VF ValuesEnter VF Values ? ? ? ? C RBCA Tool Kit for Chemical Releases, Version 2.6 #Site Name: Jerrys Place Job ID: 75207118 Location: Surry County, NC Date: 11-Jul-22 1. Water-Bearing Unit Compl. By: C. Driscoll Hydrogeology 3. Groundwater Dispersion Groundwater Darcy velocity 1.1E+1 (ft/yr)Model:GW Ingestion Groundwater seepage velocity 3.0E+1 (ft/yr)Off-site 1 Off-site 2 Off-site 1 Off-site 2 or Distance to GW receptors 90 350 0 0 (ft) Hydraulic conductivity 3.1E+2 (ft/yr) Hydraulic gradient 0.0363 (-)Longitudinal dispersivity 9 35 0 0 (ft) Effective porosity 0.38 (-)Transverse dispersivity 2.97 11.55 0 0 (ft) Sorption Vertical dispersivity 0.45 1.75 0 0 (ft) Fraction organic carbon--saturated zone 0.001 (-) 4. Groundwater Discharge to Surface Water Groundwater pH 6.46 (-) 2. Groundwater Source Zone Off-site 2 Groundwater plume width at source 100 (ft)Distance to GW/SW disharge point NA (ft) Plume (mixing zone) thickness at source 20 (ft) Plume width at GW/SW discharge (ft) Saturated thickness 20 (ft)Plume thickness at GW/SW discharge (ft) Length of source zone 147.637795 (ft) Surface water flowrate at GW/SW discharge (ft^3/yr) 5. Commands and Options GW to Indoor Air Site-Specific Groundwater Parameters or or ? ? ? Main Screen Use/Set Default Values Set Units Print Sheet Help ? RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 3 of 8 Constiuent:Ethyl benzene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)20.0 FALSE 0 Off-site1 Off-site2 (for given time)0.01 ##Residential Residential Distance (ft)0 35 70 105 140 175 210 245 280 315 350 ###90 350 t = 20 yr 4.2E-2 5.2E-3 1.1E-3 2.4E-4 6.0E-5 1.6E-5 4.6E-6 1.5E-6 5.0E-7 1.8E-7 6.9E-8 ###4.6E-4 6.9E-8 Steady-state 4.2E-2 5.2E-3 1.1E-3 2.4E-4 6.0E-5 1.6E-5 4.6E-6 1.5E-6 5.0E-7 1.8E-7 6.9E-8 #####4.6E-4 6.9E-8 POE Concentration Limit (mg/L)1.6E+0 1.6E+0 t = 20 yr Concentration vs. Time Distance (ft)350 0.0001 (for given distance from source)0 0 5.0E-4 Time (yr)0 2 4 6 8 10 12 14 16 18 20 20 Time to Reach x = 350 ft 0.0E+0 3.7E-15 9.7E-10 2.1E-8 5.1E-8 6.5E-8 6.8E-8 6.8E-8 6.9E-8 6.9E-8 6.9E-8 #####Conc. Limit (yr) Off-site1 (90 ft)0.0E+0 4.2E-5 3.6E-4 4.5E-4 4.5E-4 4.6E-4 4.6E-4 4.6E-4 4.6E-4 4.6E-4 4.6E-4 Off-site1 NA Off-site2 (350 ft)0.0E+0 3.7E-15 9.7E-10 2.1E-8 5.1E-8 6.5E-8 6.8E-8 6.8E-8 6.9E-8 6.9E-8 6.9E-8 Off-site2 NA x = 350 ftConc.(mg/L)Conc.(mg/L)0.0E+0 5.0E-3 1.0E-21.5E-22.0E-2 2.5E-2 3.0E-23.5E-24.0E-2 4.5E-2 5.0E-2 0 50 100 150 200 250 300 350Conc. (mg/L)Distance Steady-state t = 20 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 1.0E-4 2.0E-4 3.0E-4 4.0E-4 5.0E-4 0 2 4 6 8 10 12 14 16 18 20Conc. (mg/L)Time (yr) x = 350 ft Off-site1 (90 ft) Off-site2 (350 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 4 of 8 Constiuent:Xylenes (mixed isomers) Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)20.0 FALSE 0 Off-site1 Off-site2 (for given time)0.1 ##Residential Residential Distance (ft)0 35 70 105 140 175 210 245 280 315 350 ###90 350 t = 20 yr 1.1E-1 2.4E-2 7.1E-3 2.2E-3 7.0E-4 2.3E-4 8.1E-5 3.1E-5 1.2E-5 5.2E-6 2.3E-6 ###3.7E-3 2.3E-6 Steady-state 1.1E-1 2.4E-2 7.1E-3 2.2E-3 7.0E-4 2.3E-4 8.1E-5 3.1E-5 1.2E-5 5.2E-6 2.3E-6 #####3.7E-3 2.3E-6 POE Concentration Limit (mg/L)3.1E+0 3.1E+0 t = 20 yr Concentration vs. Time Distance (ft)350 0.001 (for given distance from source)0 0 4.0E-3 Time (yr)0 2 4 6 8 10 12 14 16 18 20 20 Time to Reach x = 350 ft 0.0E+0 1.8E-15 3.1E-9 1.8E-7 8.6E-7 1.6E-6 2.0E-6 2.2E-6 2.3E-6 2.3E-6 2.3E-6 #####Conc. Limit (yr) Off-site1 (90 ft)0.0E+0 1.1E-4 2.1E-3 3.3E-3 3.6E-3 3.7E-3 3.7E-3 3.7E-3 3.7E-3 3.7E-3 3.7E-3 Off-site1 NA Off-site2 (350 ft)0.0E+0 1.8E-15 3.1E-9 1.8E-7 8.6E-7 1.6E-6 2.0E-6 2.2E-6 2.3E-6 2.3E-6 2.3E-6 Off-site2 NA x = 350 ftConc.(mg/L)Conc.(mg/L)0.0E+0 2.0E-2 4.0E-26.0E-28.0E-2 1.0E-1 1.2E-11.4E-11.6E-1 1.8E-1 2.0E-1 0 50 100 150 200 250 300 350Conc. (mg/L)Distance Steady-state t = 20 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-4 1.0E-3 1.5E-3 2.0E-3 2.5E-3 3.0E-3 3.5E-3 4.0E-3 0 2 4 6 8 10 12 14 16 18 20Conc. (mg/L)Time (yr) x = 350 ft Off-site1 (90 ft) Off-site2 (350 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 5 of 8 Constiuent:Cumene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)20.0 FALSE 0 Off-site1 Off-site2 (for given time)0.01 ##Residential Residential Distance (ft)0 35 70 105 140 175 210 245 280 315 350 ###90 350 t = 20 yr 1.3E-2 1.1E-24 1.2E-34 2.3E-42 6.3E-49 9.8E-55 5.4E-60 7.8E-65 2.4E-69 1.4E-73 1.4E-77 ###3.1E-39 1.4E-77 Steady-state 1.3E-2 1.1E-24 1.2E-34 2.3E-42 6.3E-49 9.8E-55 5.4E-60 7.8E-65 2.4E-69 1.4E-73 1.4E-77 #####3.1E-39 1.4E-77 POE Concentration Limit (mg/L)1.6E+0 1.6E+0 t = 20 yr Concentration vs. Time Distance (ft)350 1E-39 (for given distance from source)0 0 4.0E-39 Time (yr)0 2 4 6 8 10 12 14 16 18 20 20 Time to Reach x = 350 ft 0.0E+0 0.0E+0 8.8E-83 1.2E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 #####Conc. Limit (yr) Off-site1 (90 ft)0.0E+0 1.8E-42 3.1E-39 3.1E-39 3.1E-39 3.1E-39 3.1E-39 3.1E-39 3.1E-39 3.1E-39 3.1E-39 Off-site1 NA Off-site2 (350 ft)0.0E+0 0.0E+0 8.8E-83 1.2E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 1.4E-77 Off-site2 NA x = 350 ftConc.(mg/L)Conc.(mg/L)0.0E+0 2.0E-3 4.0E-36.0E-38.0E-3 1.0E-2 1.2E-21.4E-21.6E-2 1.8E-2 2.0E-2 0 50 100 150 200 250 300 350Conc. (mg/L)Distance Steady-state t = 20 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-40 1.0E-39 1.5E-39 2.0E-39 2.5E-39 3.0E-39 3.5E-39 4.0E-39 0 2 4 6 8 10 12 14 16 18 20Conc. (mg/L)Time (yr) x = 350 ft Off-site1 (90 ft) Off-site2 (350 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 7 of 8 Constiuent:Naphthalene Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)20.0 FALSE 0 Off-site1 Off-site2 (for given time)0.01 ##Residential Residential Distance (ft)0 35 70 105 140 175 210 245 280 315 350 ###90 350 t = 20 yr 5.9E-2 1.7E-4 4.5E-6 2.2E-7 1.5E-8 1.3E-9 1.3E-10 1.7E-11 2.4E-12 3.8E-13 6.5E-14 ###7.7E-7 6.5E-14 Steady-state 5.9E-2 1.7E-4 4.5E-6 2.2E-7 1.5E-8 1.3E-9 1.4E-10 1.7E-11 2.4E-12 3.9E-13 7.0E-14 #####7.7E-7 7.0E-14 POE Concentration Limit (mg/L)3.1E-1 3.1E-1 t = 20 yr Concentration vs. Time Distance (ft)350 1E-07 (for given distance from source)0 0 8.0E-7 Time (yr)0 2 4 6 8 10 12 14 16 18 20 20 Time to Reach x = 350 ft 0.0E+0 0.0E+0 4.6E-29 2.8E-21 9.4E-18 6.4E-16 6.3E-15 2.2E-14 4.2E-14 5.7E-14 6.5E-14 #####Conc. Limit (yr) Off-site1 (90 ft)0.0E+0 5.1E-15 4.2E-9 1.5E-7 4.7E-7 6.8E-7 7.5E-7 7.7E-7 7.7E-7 7.7E-7 7.7E-7 Off-site1 NA Off-site2 (350 ft)0.0E+0 0.0E+0 4.6E-29 2.8E-21 9.4E-18 6.4E-16 6.3E-15 2.2E-14 4.2E-14 5.7E-14 6.5E-14 Off-site2 NA x = 350 ftConc.(mg/L)Conc.(mg/L)0.0E+0 1.0E-2 2.0E-2 3.0E-2 4.0E-2 5.0E-2 6.0E-2 0 50 100 150 200 250 300 350Conc. (mg/L)Distance Steady-state t = 20 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 1.0E-7 2.0E-7 3.0E-7 4.0E-7 5.0E-7 6.0E-7 7.0E-7 8.0E-7 0 2 4 6 8 10 12 14 16 18 20Conc. (mg/L)Time (yr) x = 350 ft Off-site1 (90 ft) Off-site2 (350 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT TIER 2 TRANSIENT DOMENICO ANALYSIS Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 8 of 8 Constiuent:Trimethylbenzene, 1,2,4- Source Medium:Affected Groundwater Biodegredation:1st Order Concentration vs. Distance from Source Time (yr)20.0 FALSE 0 Off-site1 Off-site2 (for given time)0.1 ##Residential Residential Distance (ft)0 35 70 105 140 175 210 245 280 315 350 ###90 350 t = 20 yr 1.3E-1 5.5E-7 6.9E-10 3.4E-12 3.3E-14 5.3E-16 1.2E-17 3.7E-19 1.5E-20 7.0E-22 3.9E-23 ###3.0E-11 3.9E-23 Steady-state 1.3E-1 5.5E-7 6.9E-10 3.4E-12 3.3E-14 5.3E-16 1.2E-17 3.7E-19 1.5E-20 7.0E-22 3.9E-23 #####3.0E-11 3.9E-23 POE Concentration Limit (mg/L)7.8E-1 7.8E-1 t = 20 yr Concentration vs. Time Distance (ft)350 1E-11 (for given distance from source)0 0 3.0E-11 Time (yr)0 2 4 6 8 10 12 14 16 18 20 20 Time to Reach x = 350 ft 0.0E+0 1.1E-38 1.3E-25 2.4E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 #####Conc. Limit (yr) Off-site1 (90 ft)0.0E+0 7.7E-13 2.8E-11 3.0E-11 3.0E-11 3.0E-11 3.0E-11 3.0E-11 3.0E-11 3.0E-11 3.0E-11 Off-site1 NA Off-site2 (350 ft)0.0E+0 1.1E-38 1.3E-25 2.4E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 3.9E-23 Off-site2 NA x = 350 ftConc.(mg/L)Conc.(mg/L)0.0E+0 2.0E-2 4.0E-26.0E-28.0E-2 1.0E-1 1.2E-11.4E-11.6E-1 1.8E-1 2.0E-1 0 50 100 150 200 250 300 350Conc. (mg/L)Distance Steady-state t = 20 yr Off-site1 Conc.Limit Off-site2 Conc.Limit 0.0E+0 5.0E-12 1.0E-11 1.5E-11 2.0E-11 2.5E-11 3.0E-11 0 2 4 6 8 10 12 14 16 18 20Conc. (mg/L)Time (yr) x = 350 ft Off-site1 (90 ft) Off-site2 (350 ft) Off-site1 Conc.Limit Off-site2 Conc.Limit RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 1 OF 7 TIER 2 EXPOSURE CONCENTRATION AND INTAKE CALCULATION GROUNDWATER EXPOSURE PATHWAYS o (Checked if Pathway is Complete) SOILS : LEACHING TO GROUNDWATER INGESTION 1) Source Medium 2) NAF Value (L/kg)3) Exposure Medium Receptor Groundwater: POE Conc. (mg/L) (1)/(2) Soil Conc. On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern (mg/kg)None Residential Residential None Residential Residential Benzene Toluene Ethyl benzene Xylenes (mixed isomers) Cumene Methyl t-Butyl ether (MTBE) Naphthalene Trimethylbenzene, 1,2,4- * = Chemical with user-specified data NOTE: NAF = Natural attenuation factor POE = Point of exposure Site Name: Jerrys Place Date Completed: 11-Jul-22 Site Location: Surry County, NC Job ID: 75207118 Completed By: C. Driscoll RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 2 OF 7 TIER 2 EXPOSURE CONCENTRATION AND INTAKE CALCULATION GROUNDWATER EXPOSURE PATHWAYS SOILS : LEACHING TO GROUNDWATER INGESTION (cont'd)4) Exposure Multiplier 5) Average Daily Intake Rate (IRxEFxED)/(BWxAT) (L/kg-day)(mg/kg/day) (3) x (4) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern None Residential Residential None Residential Residential Benzene Toluene Ethyl benzene Xylenes (mixed isomers) Cumene Methyl t-Butyl ether (MTBE) Naphthalene Trimethylbenzene, 1,2,4- * = Chemical with user-specified data NOTE: AT = Averaging time (days)ED = Exposure duration (yr)IR = Ingestion rate (mg/day) BW = Body weight (kg)EF = Exposure frequency (days/yr) Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 3 OF 7 TIER 2 EXPOSURE CONCENTRATION AND INTAKE CALCULATION GROUNDWATER EXPOSURE PATHWAYS n (Checked if Pathway is Complete) GROUNDWATER: INGESTION 1) Source Medium 2) NAF Value (unitless)3) Exposure Medium Receptor Groundwater: POE Conc. (mg/L) (1)/(2) Groundwater On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern Conc. (mg/L)None Residential Residential None Residential Residential Benzene 0.0E+0 3.6E+0 2.7E+2 0.0E+0 0.0E+0 Toluene 0.0E+0 2.0E+7 6.5E+16 0.0E+0 0.0E+0 Ethyl benzene 4.2E-2 9.2E+1 6.1E+5 4.6E-4 6.9E-8 Xylenes (mixed isomers)1.1E-1 3.0E+1 4.7E+4 3.7E-3 2.3E-6 Cumene 1.3E-2 4.4E+36 9.2E+74 3.1E-39 1.4E-77 Methyl t-Butyl ether (MTBE)0.0E+0 7.2E+0 1.6E+3 0.0E+0 0.0E+0 Naphthalene 5.9E-2 7.6E+4 8.4E+11 7.7E-7 7.0E-14 Trimethylbenzene, 1,2,4-1.3E-1 4.4E+9 3.3E+21 3.0E-11 3.9E-23 NOTE: NAF = Natural attenuation factor POE = Point of exposure Site Name: Jerrys Place Date Completed: 11-Jul-22 Site Location: Surry County, NC Job ID: 75207118 Completed By: C. Driscoll RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 4 OF 7 TIER 2 EXPOSURE CONCENTRATION AND INTAKE CALCULATION GROUNDWATER EXPOSURE PATHWAYS GROUNDWATER INGESTION (cont'd) 4) Exposure Multiplier 5) Average Daily Intake Rate (IRxEFxED)/(BWxAT) (L/kg/day)(mg/kg/day) (3) x (4) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern None Residential Residential None Residential Residential Benzene 1.5E-2 1.5E-2 0.0E+0 0.0E+0 Toluene 6.4E-2 6.4E-2 0.0E+0 0.0E+0 Ethyl benzene 6.4E-2 6.4E-2 2.9E-5 4.4E-9 Xylenes (mixed isomers)6.4E-2 6.4E-2 2.3E-4 1.5E-7 Cumene 6.4E-2 6.4E-2 2.0E-40 9.2E-79 Methyl t-Butyl ether (MTBE)1.5E-2 1.5E-2 0.0E+0 0.0E+0 Naphthalene 6.4E-2 6.4E-2 4.9E-8 4.5E-15 Trimethylbenzene, 1,2,4-6.4E-2 6.4E-2 1.9E-12 2.5E-24 * = Chemical with user-specified data NOTE: AT = Averaging time (days)ED = Exposure duration (yr)IR = Ingestion rate (mg/day) BW = Body weight (kg)EF = Exposure frequency (days/yr) Site Name: Jerrys Place Completed By: C. Driscoll Job ID: 75207118 Site Location: Surry County, NC Date Completed: 11-Jul-22 RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 5 OF 7 TIER 2 EXPOSURE CONCENTRATION AND INTAKE CALCULATION GROUNDWATER EXPOSURE PATHWAYS MAXIMUM PATHWAY INTAKE (mg/kg/day) (Maximum intake of active pathways soil leaching & groundwater routes.) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern None Residential Residential Benzene Toluene Ethyl benzene 2.9E-5 4.4E-9 Xylenes (mixed isomers)2.3E-4 1.5E-7 Cumene 2.0E-40 9.2E-79 Methyl t-Butyl ether (MTBE) Naphthalene 4.9E-8 4.5E-15 Trimethylbenzene, 1,2,4-1.9E-12 2.5E-24 * = Chemical with user-specified data Site Name: Jerrys Place Date Completed: 11-Jul-22 Site Location: Surry County, NC Job ID: 75207118 Completed By: C. Driscoll RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 6 OF 7 TIER 2 PATHWAY RISK CALCULATION GROUNDWATER EXPOSURE PATHWAYS n (Checked if Pathway is Complete) CARCINOGENIC RISK (1) Is (2) Maximum Carcinogenic (3) Oral (4) Individual COC Carcinogenic Intake Rate (mg/kg/day)Slope Factor Risk (2) x (3) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) (mg/kg-day)^-1 On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern None Residential Residential None Residential Residential Benzene TRUE 1.5E-2 Toluene FALSE - Ethyl benzene FALSE - Xylenes (mixed isomers)FALSE - Cumene FALSE - Methyl t-Butyl ether (MTBE)TRUE 1.8E-3 Naphthalene FALSE - Trimethylbenzene, 1,2,4-FALSE - Total Pathway Carcinogenic Risk = Site Name: Jerrys Place Date Completed: 11-Jul-22 Site Location: Surry County, NC Job ID: 75207118 Completed By: C. Driscoll RBCA Tool Kit for Chemical Releases, Version 2.51 RBCA SITE ASSESSMENT 7 OF 7 TIER 2 PATHWAY RISK CALCULATION GROUNDWATER EXPOSURE PATHWAYS n (Checked if Pathway is Complete) TOXIC EFFECTS (5) Maximum Toxicant (6) Oral (7) Individual COC Intake Rate (mg/kg/day)Reference Hazard Quotient (5) / (6) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Dose (mg/kg/day) On-site (0 ft) Off-site 1 (90 ft) Off-site 2 (350 ft) Constituents of Concern None Residential Residential None Residential Residential Benzene 0.0E+0 0.0E+0 4.0E-3 0.0E+0 0.0E+0 Toluene 8.0E-2 Ethyl benzene 2.9E-5 4.4E-9 1.0E-1 2.9E-4 4.4E-8 Xylenes (mixed isomers)2.3E-4 1.5E-7 2.0E-1 1.2E-3 7.4E-7 Cumene 2.0E-40 9.2E-79 1.0E-1 2.0E-39 9.2E-78 Methyl t-Butyl ether (MTBE)0.0E+0 0.0E+0 1.0E-2 0.0E+0 0.0E+0 Naphthalene 4.9E-8 4.5E-15 2.0E-2 2.5E-6 2.2E-13 Trimethylbenzene, 1,2,4-1.9E-12 2.5E-24 5.0E-2 3.8E-11 5.0E-23 Total Pathway Hazard Index =1.5E-3 7.8E-7 Site Name: Jerrys Place Date Completed: 11-Jul-22 Site Location: Surry County, NC Job ID: 75207118 Completed By: C. Driscoll