RA-6716_33873_CA_LSA_20210920

LIMITED SITE ASSESSMENT REPORT

Cheek Road Grocery 5801 Cheek Road Durham, Durham County, North Carolina NCDEQ Incident No. 33873 Risk Classification: High
September 20, 2021 Prepared For:

Mr. Mark Petermann NCDEQ, DWM, UST Section 1646 Mail Service Center
Raleigh, NC 27699-1646 CATLIN Project No. 221007
Prepared By:
220 Old Dairy Road Wilmington, North Carolina 28405 [phone]
Corporate Geology License No. C-118 Corporate Licensure No. For Engineering Services C-0585

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021
TABLE OF CONTENTS PAGE
1.0 SITE INFORMATION 1
2.0 EXECUTIVE SUMMARY 2
3.0 SCOPE OF SERVICES 3
4.0 SITE HISTORY AND CHARACTERIZATION 3
4.1 UST/AST OWNER AND OPERATOR INFORMATION 3 4.2 UST INFORMATION 3 4.3 CONTAMINANT SOURCE INVENTORY 4 4.4 SITE CHARACTERISTICS 4 4.5 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 4
5.0 RISK CHARACTERIZATION 4
6.0 RECEPTOR INFORMATION 7
6.1 WATER SUPPLY WELLS 7 6.2 PUBLIC WATER SUPPLIES 7 6.3 SURFACE WATER 8
6.4 WELLHEAD PROTECTION AREAS 8 6.5 DEEP AQUIFERS IN THE COASTAL PLAIN PHYSIOGRAPHIC REGION 8 6.6 SUBSURFACE STRUCTURES 8
7.0 LAND USE 8
7.1 PROPERTY OWNERS AND OCCUPANTS 8 7.2 SENSITIVE LAND USE FEATURES 8
8.0 SITE GEOLOGY AND HYDROGEOLOGY 9
8.1 SOIL AND BEDROCK 9 8.2 HYDROGEOLOGY 9
9.0 PHASE I INVESTIGATION 9
9.1 MONITORING WELL INSTALLATION 9 9.2 SOIL SAMPLING DATA 10 9.3 SUMMARY OF SOIL INFORMATION 10 9.4 GROUNDWATER GAUGING DATA 11 9.5 GROUNDWATER SAMPLING DATA 11 9.6 SUMMARY OF GROUNDWATER INFORMATION 11
10.0 CONCLUSIONS AND RECOMMENDATIONS 12
11.0 LIMITATIONS 13
12.0 REFERENCES 13

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021
TABLES
TABLE 1 SITE HISTORY – UST/AST SYSTEM AND OTHER RELEASE INFORMATION
TABLE 2 PUBLIC AND PRIVATE WATER SUPPLY WELL AND OTHER RECEPTOR INFORMATION
TABLE 3 CONTIGUOUS PROPERTY OWNERS/OCCUPANTS
TABLE 4 SENSITIVE LAND USE FEATURES
TABLE 5 WELL CONSTRUCTION AND WATER LEVEL GAUGING DATA – AUGUST 20, 2021
TABLE 6 FIELD SCREENING DATA – AUGUST 11, 2021
TABLE 7 SUMMARY OF SOIL LABORATORY RESULTS – EPA METHOD 8260D AND MADEP VPH
TABLE 8 SUMMARY OF GROUNDWATER LABORATORY RESULTS – SM 6200B, MADEP VPH, AND EPA METHOD 6020B
FIGURES FIGURE 1 SITE VICINITY MAP
FIGURE 2 POTENTIAL RECEPTOR MAP
FIGURE 3 SITE MAP
FIGURE 4 ZONING MAP
FIGURE 5 SUMMARIZED ANALYTICAL RESULTS – AUGUST 20, 2021
APPENDICES APPENDIX A HISTORICAL DATA
APPENDIX B SITE PHOTOGRAPHS
APPENDIX C FIELD DATA SHEETS, HEALTH AND SAFETY PLAN, AND JOB HAZARD ANALYSIS
APPENDIX D WELL LOG, MONITORING WELL CONSTRUCTION RECORD, AND TRANSMITTAL LETTER
APPENDIX E LABORATORY ANALYTICAL REPORTS AND CHAIN OF CUSTODY DOCUMENTS
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 1 September 2021
1.0 SITE INFORMATION Date: 09/17/21
UST Number: RA-6716 Incident Number: 33873 Site Risk/Priority Rank High
Site Name: Cheek Road Grocery
Site Location: 5801 Cheek Road
Nearest City/Town: Durham County: Durham
UST Owner: Jerry Hinesley
Address: 4802 Rogers Road, Durham NC 27704 Phone: [phone]
UST Operator: Jerry Hinesley Address: 4802 Rogers Road, Durham NC 27704 Phone: [phone]
Property Owner: Larry L. Ricks
Address: 4802 Rogers Road, Durham NC 27704 Phone: [phone]
Property Occupant: Pizza Mia Heritage Grill
Address: 5801 Cheek Road, Durham NC 27704 Phone: [phone]
Consultant/Contractor: CATLIN Engineers and Scientists
Address: 220 Old Dairy Road, Wilmington, North Carolina 28405 Phone: [phone]
Consultant/Contractor License No.: C - 0585
Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703
Address: 39 Spruce St., East Longmeadow, MA 01028 Phone: [phone]
Release Information
Date Discovered: 06/27/07 Longitude (decimal degrees): -78.773363° Latitude (decimal degrees): 36.029161° Estimated Quantity of Release: Unknown Cause of Release: Unknown
Source of Release: UST system

Sizes and contents of UST system(s) from which the release occurred:
Tank #1 – 8,000-gal gasoline Tank #2 – 4,000-gal gasoline Tank #3 – 1,000-gal gasoline Tank #4 – 550-gal kerosene Tank #5 – 1,000-gal gasoline
I, Sean J. O’Neil a Licensed Engineer for CATLIN Engineers and Scientists, do certify that the information contained in this report is correct and Accurate to the best of my knowledge.
CATLIN Engineers and Scientists is licensed to practice geology and engineering in North Carolina. The Corporate Engineering License Number C-0585.

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 2 September 2021
2.0 EXECUTIVE SUMMARY The Cheek Road Grocery site is located at 5801 Cheek Road, Durham, North
Carolina. Light non-aqueous phase liquid (LNAPL aka free product) was discovered beneath three dispensers during an underground storage tank (UST) inspection on June 27, 2007. In February 2010 five USTs were removed from the site and soil samples taken from the excavation confirmed the presence of total petroleum hydrocarbons (TPH). The site is currently operating as a restaurant, Pizza Mia
Heritage Grill.
The purpose of this report is to document the Limited Site Assessment (LSA) activities for the site. On August 11, 2021, CATLIN Engineers and Scientists (CATLIN) personnel advanced a boring for construction of a Type II monitoring well
(MW-01). During boring advancement, one soil sample [MW-01 (5.0-7.0)] was
collected for laboratory analysis. The soil sample was analyzed per U.S. Environmental Protection Agency (EPA) Method 8260D, EPA Method 8270E, and Massachusetts Department of Environmental Protection (MADEP) volatile petroleum hydrocarbons (VPH) and extractable petroleum hydrocarbons (EPH). Sample
results revealed several analytes above their lowest corresponding maximum soil
contaminant concentrations (MSCC) including benzene, 1-methylnaphthalene, C5-C8 aliphatics, and C9-C22 aromatics. CATLIN conducted a field receptor survey on August 12, 2021. The receptor survey
identified 18 potable water supply wells, within 1,000 feet of the subject site. Four
surface water bodies, all ponds, are located between 500 and 1,500 feet of the subject site. No sensitive land features were identified within a 1,500-foot radius. Municipal water is not available within 1,500 feet of the site.
On August 20, 2021, CATLIN mobilized to the site to collect a groundwater sample from monitoring well MW-01. The groundwater sample was submitted for volatile organic compound (VOC) analysis via Standard Method (SM) 6200B, MADEP-VPH and EPH, and for lead per EPA Method 6020B. Analytical results revealed lead and 1,2-dichloroethane above regulatory limits as defined in Title 15A of the North
Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards (2L GWQS). No targeted analytes were detected above the gross contaminant levels (GCL). Based on the results of the LSA field activities, CATLIN recommends installing
additional monitoring wells to the north and south of the former UST. In addition, during the next sampling event, attempts should be made to sample water supply wells WSW-1, WSW-2 and WSW-18.

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 3 September 2021
3.0 SCOPE OF SERVICES

The scope of services for this LSA were performed in general accordance with CATLIN proposal number 221007.P, dated June 25, 2021. Services were authorized by NCDEQ’s Task Authorization (TA) #01, dated June 25, 2021, and Contract Number N122019D.
The approved scope of services for this Task Authorization included:
• Prepare a site specific Health and Safety Plan (HASP);
• Install one monitoring well (MW-01);
• Collect one soil sample from the monitoring well boring;
• Collect a groundwater sample from MW-01;
• Analyze three groundwater samples (MW-01, a trip blank, and a field blank)
per SM 6200B (EDB, MTBE & IPE), Total Lead, 625 (Plus BNA & TICs), MADEP VPH, and MADEP EPH;
• Analyze one soil sample per 8260, 8270, MADEP VPH, and MADEP EPH;
• Conduct a receptor survey;
• Prepare and submit an LSA report summarizing the findings.
These services were provided as proposed. 4.0 SITE HISTORY AND CHARACTERIZATION The Cheek Road Grocery site is located at 5801 Cheek Road, Durham, North
Carolina (Figures 1, 2 and 3). Summarized available historical sampling and
gauging data are provided in Appendix A and site photographs are presented in Appendix B.
4.1 UST/AST OWNER AND OPERATOR INFORMATION

Five USTs and one above ground storage tank (AST) historically operated at the site. The tanks were reportedly owned by Jerry Hinesley and operated at Cheek Road Grocery prior to their removal in 2010 (HN, 2010). Due to Mr. Hinesley’s financial situation, the site was accepted into the North Carolina
UST Section Trust Fund Branch State Lead Program.
UST owner and operator information are provided on Table 1. 4.2 UST INFORMATION

Based on information provided in the 20 Day Report, one 8,000-gallon, one 4,000-gallon, and two 1,000-gallon gasoline USTs, one 550-gallon kerosene USTs, and one 1,000-gallon kerosene AST were removed between February 23 and 24, 2010. These tanks were owned and operated from April 21, 1978
to February 23, 2010 (HN, 2010).
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 4 September 2021
Available UST information is presented on Table 1 and the approximate former UST locations are illustrated on Figure 3.
4.3 CONTAMINANT SOURCE INVENTORY A petroleum release was discovered on June 27, 2007, during a UST inspection. LNAPL was observed under three of the dispensers, and a soil
sample confirmed TPH contamination (UST-61, 2007).
4.4 SITE CHARACTERISTICS The site is currently owned by Larry L. Ricks and operates as a restaurant,
Pizza Mia Heritage Grill. The site consists of the store building, sheds to the
east and west of the restaurant building, a residence further to the north of the property, and an asphalt paved parking lot. Site photographs are provided in Appendix B.
4.5 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES Following the discovery of the release in 2007 a Notice of Violation (NOV) was sent to Jerry Hinesley requiring a site check to be conducted. On July
13, 2010 a 20-Day Report was submitted by Henry Nemargut Engineering
Services documenting the removal of five USTs, one AST and the excavation of 240 tons of impacted soil on February 23 and 24, 2010 by Zebra Environmental & Industrial Services, Inc.
A Notice of Regulatory Requirement (NORR) dated February 25, 2019 required an LSA be conducted at the site; however, due to Mr. Honesley’s financial hardships, the LSA was not conducted (Powers, 2020). 5.0 RISK CHARACTERIZATION
LIMITED SITE ASSESSMENT RISK CLASSIFICATION AND LAND USE FORM Part I – Groundwater/Surface Water/Vapor Impacts High Risk
1. Has the release contaminated any water supply well including any well used
for non-drinking purposes? NO There has been no documentation of water supply well sampling at this site.
2. Is a water supply well used for drinking water located within 1,000 feet of the
source area of the release? YES
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 5 September 2021
3. Is a water supply well not used for drinking water (e.g., irrigation, washing
cars, industrial cooling water, filling swimming pools) located within 250 feet
of the source area of the release? NO
4. Does groundwater within 500 feet of the source area of the release have the
potential for future use (there is no other source of water supply other than
the groundwater)? YES
5. Do vapors from the release pose a threat of explosion because of
accumulation of the vapors in a confined space or pose any other serious
threat to public health, public safety or the environment? NO
If yes, describe. Not applicable

6. Are there any other factors that would cause the release to pose an imminent
danger to public health, public safety, or the environment? NO
If yes, describe. Not applicable Intermediate Risk
1. Is a surface water body located within 500 feet of the source area of the
release? NO
Describe. There are several farm ponds located between the 500 feet and 1,000 feet from the subject site.
If YES, does the maximum groundwater contaminant concentration exceed
the surface water quality standards and criteria found in 15A NCAC 2B .0200
by a factor of 10? Not applicable NO 2. Is the source area of the release located within an approved or planned
wellhead protection area as defined in 42 USC 300h-7(e)? NO
If yes, describe. 3. Is the release located in the Coastal Plain physiographic region as
designated on a map entitled “Geology of North Carolina” published by the
Department in 1985? NO
If YES, is the source area of the release located in an area in which there
is recharge to an unconfined or semi-confined deeper aquifer that is being
used or may be used as a source of drinking water? NO
If yes, describe. Not applicable

4. Do the levels of groundwater contamination for any contaminant exceed the
gross contamination levels (See Table 2) established by the Department? NO
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 6 September 2021
Part II - Land Use Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the
release. 1. Does the property contain one or more primary or secondary residences
(permanent or temporary)? YES
Describe. There is a building located on the northern portion of the property
that could be used as a residence.
2. Does the property contain a school, daycare center, hospital, playground,
park, recreation area, church, nursing home, or other place of public
assembly? YES
Describe. There is a restaurant on-site where people can gather.
3. Does the property contain a commercial (e.g., retail, warehouse,
office/business space, etc.) or industrial (e.g., manufacturing, utilities,
industrial research and development, chemical/petroleum bulk storage, etc.)
enterprise, an inactive commercial or industrial enterprise, or is the land
undeveloped? YES
Describe. The site is currently a restaurant and retail store.
4. Do children visit the property? YES
Explain. It is a store; therefore, children are likely to visit.

Is access to the property reliably restricted consistent with its use (e.g., by
fences, security personnel or both)? NO
Explain. The property is a store and open to the public.

5. Do pavement, buildings, or other structures cap the contaminated soil? YES
Describe. There is an asphalt pavement parking lot above the former USTs.
If yes, what mechanisms are in place or can be put into place to ensure that
the contaminated soil will remain capped in the foreseeable future? Maintaining the asphalt pavement will ensure this.
6. What is the zoning status of the property?
Based on Durham County GIS viewer, the zoning for the subject site is Residential Rural. 7. Is the use of the property likely to change in the next 20 years? YES
Explain. There are no plans for the property to change; however, there is a
chance that the property use changes in the next 20 years.
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 7 September 2021
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the
release (excludes property containing source area of the release):

1. What is the distance from the source area of the release to the nearest
primary or secondary residence (permanent or temporary)? Approximately 160 feet to the east northeast is a residence building.
2. What is the distance from the source area of the release to the nearest
school, daycare center, hospital, playground, park, recreation area, church,
nursing home or other place of public assembly? Plainview Baptist Church is approximately 3,100 feet to the southwest
3. What is the zoning status of properties in the surrounding area?
Surrounding properties are zoned as Rural Residential. See Figure 4 for zoning status within 1,500 feet. 4. Briefly characterize the use and activities of the land in the surrounding area.
The surrounding area is mainly used as low density rural residential land.
See Table 3 for contiguous property land use information and Table 4 for sensitive land use features within 1,500 feet. 6.0 RECEPTOR INFORMATION

On August 12, 2021, CATLIN personnel conducted a receptor survey within 1,500 feet of the site. Potential receptors located within 1,500 feet of the subject site are illustrated on Figure 2 and pertinent receptor information is described below and presented on Table 2.
6.1 WATER SUPPLY WELLS During the receptor survey, CATLIN identified a total of 28 potable water supply wells within 1,500 feet of the subject site. Of the 28 wells, 18 are
within 1,000 feet of the subject site. No non-potable wells were observed within 1,500 feet of the site. 6.2 PUBLIC WATER SUPPLIES

Based on utility data obtained from the City of Durham, municipal water or sewer is not available to properties within 1,500 feet of the site. No public water supply wells were identified within 1,500 feet of the site. The nearest municipal water connection point is approximately 1.65 miles west of the site.
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 8 September 2021
6.3 SURFACE WATER Four ponds were identified within 1,500 feet of the subject site. Their
locations are noted on Figure 2 and details are available on Table 2. 6.4 WELLHEAD PROTECTION AREAS On September 8, 2021, CATLIN accessed the NCDEQ Division of Water
Resources (DWR), Public Water Supply Well (PWS) Section web page and
verified that there are no known wellhead protection areas within 1,500 feet of the site. 6.5 DEEP AQUIFERS IN THE COASTAL PLAIN PHYSIOGRAPHIC REGION

It is unknown if the source area is potentially located in an area in which there is recharge to an unconfined or semi-confined deeper aquifer. The 2020 Visual Hydrogeologic Framework (VHF) – North Carolina Hydrogeological Database could not identify boreholes within the vicinity of
the subject site. The three closest boreholes could not be used to create an
estimate of the hydrogeology.
6.6 SUBSURFACE STRUCTURES
No known subsurface utilities are known to exist at the site currently.
7.0 LAND USE

7.1 PROPERTY OWNERS AND OCCUPANTS
The site is owned by Larry L. Ricks and operates as the Pizza Mia Heritage Grill . The eastern adjacent property is owned by Brenda Gregory, the northern adjacent property by Larry and Deborah Jones, and the western adjacent by Randolph Clements. The property across Cheek Road is owned
by Frank and Shirley Clemmensen. Contiguous property owner/occupant information is provided in Table 3 and property locations are shown on Figure 4.
7.2 SENSITIVE LAND USE FEATURES No sensitive land use features were identified within 1,500 feet of the site.

Land use features, zoning information, street addresses, and distance from the source area are detailed in Table 4. Continuous property owners/occupants and zoning information are shown on Figure 4.

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 9 September 2021
8.0 SITE GEOLOGY AND HYDROGEOLOGY
8.1 SOIL AND BEDROCK
As defined in the Geologic Map of North Carolina, published by the North Carolina Department of Natural Resources and Community Development (1985), the site lies within the Piedmont physiographic province. The site is underlain by the Durham-Sandford Triassic Basin, which consists of a
collection of sedimentary rocks including conglomerate, fanglomerate,
sandstone, and mudstone. Based on the well log for MW-01 the site is immediately underlain by three feet of well graded clayey sand. Between 3.5 and and 8.5 feet below land
surface (BLS) a micaceous sand clay was encountered. Below 8.5 feet BLS
a layer of micaceous silty sand was observed until the boring was terminated at 22 feet BLS. 8.2 HYDROGEOLOGY

Groundwater -- Based on the 2020 VHF Database, the three closest boreholes to the site could not be used to develop an approximate cross section of the aquifers below the subject site.
Surface Water – Four ponds were identified within 1,500 feet of the subject
site, but none were within the 500-foot radius. 9.0 PHASE I INVESTIGATION
Field activities included installing one monitoring well (MW-01), collecting one soil sample and obtaining one groundwater sample (from MW-01). Prior to completing any field activities, a site-specific HASP was prepared. Daily safety briefings detailing hazards identified in the task specific job hazard analysis (JHA) forms were conducted prior to initiating field work. The site-specific HASP and JHA forms are
included in Appendix C. 9.1 MONITORING WELL INSTALLATION On August 11, 2021, a boring was advanced to 22 feet BLS for monitoring
well construction by a North Carolina Certified Well Contractor, utilizing hollow stem augers and a Central Mine Equipment Model 45B drill rig mounted on a tracked carrier. Cuttings generated during drilling activities were spread on-site.
The monitoring well (MW-01) was constructed of new, threaded PVC casing and screen. No glues or cements were used in joining PVC components. New nitrile gloves were worn while handling all well materials. The monitoring
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 10 September 2021
well was constructed with a pointed PVC sediment trap, 10 feet of 2-inch diameter, 0.010-inch slotted PVC well screen and approximately ten feet of 2-inch diameter solid PVC riser to the surface. The annular space was filled
with coarse sand pack to approximately one-half foot above the well screen and bentonite chips to within one-half foot of the ground surface. The bentonite chips were poured from the surface while simultaneously pouring water to facilitate hydration. The well was finished with a concrete pad and flush-mount steel wellhead and locking well cap. After installation, the
monitoring well was developed by over-pumping.
Monitoring well construction information is summarized on Table 5 and a site map with monitoring well location is illustrated on Figure 3. Site photographs are presented in Appendix B. A copy of the well log and Well Construction
Record are provided in Appendix D.
9.2 SOIL SAMPLING DATA On August 11, 2021, during monitoring well (MW-01) installation, soils were
classified according to the Unified Soil Classification System (USCS). Split
spoon samples were collected from the surface level and at five foot intervals, in general accordance with NCDEQ guidelines and EPA Region 4 operating procedures. Soil samples were field screened using a photoionization detector (PID). The PID concentrations are presented on
Table 6.
After field screening, the soil sample was placed in appropriate glassware, labeled, and placed on ice in an insulated cooler. The Soil sample was submitted to Con-Test Analytical Laboratory (Certification NC 652 and NC-
DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol for analysis. 9.3 SUMMARY OF SOIL INFORMATION

The soil sample collected from the MW-01 boring [MW-01 (5.0-7.0) was analyzed per EPA Method 8260D, EPA Method 8270E, MADEP VPH, and EPH. Across all laboratory analyses, benzene (estimated value), 1-methylnaphthalene (estimated value), C5-C8 aliphatics, and C9-C22 aromatics were detected above their Soil-to-Groundwater (STGW) MSCCs.
No compounds were detected above Residential or Industrial/Commercial MSCCs. Soil laboratory analytical results are summarized on Table 7 and illustrated on Figure 5. A copy of the complete laboratory report and COC
documentation are in Appendix E.
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 11 September 2021
9.4 GROUNDWATER GAUGING DATA On August 20, 2021, depth to water was measured using an electronic
probe. Gauging data were recorded on an electronic groundwater sampling form using a tablet device. Gauging procedures were performed in general accordance with NCDEQ and EPA Region 4 guidelines. Depth to water in MW-01 was 8.61 feet below top of casing. Gauging results
are detailed on Table 5.
9.5 GROUNDWATER SAMPLING DATA Following gauging, monitoring well MW-01 was sampled in general
accordance with NCDEQ guidelines and EPA Region 4 operating
procedures. Prior to obtaining a representative groundwater sample, the monitoring well was purged by removing a minimum of three well volumes using a new, disposable bailer. Groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua TROLL 600
Multiparameter Sonde (Aqua TROLL). Conductivity, pH, oxidation reduction
potential (ORP), dissolved oxygen, and temperature measurements were recorded utilizing the VuSitu mobile application (version 1.17.12). The Aqua TROLL was decontaminated with an isopropyl alcohol and water solution and rinsed with distilled water after use at the monitoring well. Groundwater
parameter data were transferred from the VuSitu mobile application to the
electronic groundwater sampling form. A Copy of the monitoring well sampling form is available in Appendix C. A field blank was collected by pouring water from a new, sealed gallon of
distilled water directly into laboratory-provided, pre-preserved glassware. The glassware was labeled and placed on ice in an insulated cooler. A laboratory provided trip blank was maintained in the cooler for the duration of the sampling event.
After the well was purged a minimum of three well volumes a groundwater sample was collected from the well from a disposable bailer and poured directly into appropriate laboratory provided glassware, labeled, and placed on ice in an insulated cooler. The groundwater sample and a laboratory provided trip blank were submitted to Con-Test Analytical Laboratory, under
proper chain of custody COC protocol. 9.6 SUMMARY OF GROUNDWATER INFORMATION One groundwater sample (MW-01), one field blank, and one laboratory
provided trip blank were submitted for analyses detailed below.
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 12 September 2021
Monitoring Well The groundwater sample collected from monitoring well MW-01 was
analyzed per SM 6200B, MADEP VPH and EPH, EPA Method 625, and EPA Method 6020. Both lead and 1,2-dichloroethane were detected above the 2L GWQS. Both concentrations were below GCLs. Results are summarized on Table 8.
Trip Blank and Field Blank
A laboratory provided trip blank and field blank were submitted for analysis per SM 6200B. The only detection in the trip blank sample was an estimated concentration of toluene. The field blank contained estimated detections of
acetone and toluene. Acetone is occasionally found as a laboratory artifact,
and the toluene levels were similarly low levels in all three analyzed samples. 10.0 CONCLUSIONS AND RECOMMENDATIONS

Conclusions
Findings from LSA activities (risk characterization, receptor survey execution, monitoring well installation, and soil and groundwater sample procurement and analysis) are summarized below:

• The on-site USTs were removed in 2010 and the site is currently occupied by a restaurant and grocery store.
• No sensitive land use features were observed within a 1,500-foot radius from
the source area.
• The site is located within the Piedmont physiographic province and it is unknown if it is potentially located in a recharge area to an unconfined or
semi-confined deeper aquifer.
• 18 active potable water supply wells were identified within 1,000 feet of the site. No active non-potable water supply wells were identified within 1,500 feet from the site.
• Four ponds were located between 500 and 1,000 feet from the site. No other surface water features were identified.
• Four targeted analytes were detected in the soil sample collected from 5 to 7
feet BLS [MW-01 (5.0-7.0)] above their respective STW MSCCs including
benzene (estimated), 1-methylnaphthalene (estimated), C5-C8 aliphatics, and C9-C22 Aromatics. No analytes were detected above their residential MSCCs
• 1,2-dichloroethane and lead were detected above their respective 2L GWQS
in the sample collected from MW-01.
• No constituents were reported above their respective GCL in the groundwater samples collected from monitoring well MW-01

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 13 September 2021
Recommendations Based on the results of the LSA field activities, CATLIN recommends installing
additional monitoring wells to the north and south of the former UST. In addition, during the next sampling event, attempts should be made to sample water supply wells WSW-1, WSW-2 and WSW-18. 11.0 LIMITATIONS

The soil and groundwater samples analyzed as part of this investigation only provide isolated data points and may not represent conditions at every location in the project area. Analyses and conclusions of this report, being based on interpolation of data points at the project area, may not be completely representative of all site
conditions. Conclusions and recommendations of this investigation and report are
based on the best available data in an effort to comply with current regulatory requirements. 12.0 REFERENCES

Henry Nemargut Engineering Services, 20 Day Report¸July 13, 2010.
Henry Nemargut Engineering Services, UST-61: 24-Hour Release and UST Leak
Reporting Form, July 27, 2007.
NCDEQ, Division of Water Resources, 2020 Visual Hydrogeologic Framework,
North Carolina Hydrogeological Database, ncwater.org/?page=350,
accessed April 6, 2021.
NCDEQ, Division of Waste Management, Document Management System (Laserfiche), Miscellaneous (documents associated with Incident No. 18221), accessed November 2020-April 2021.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Sampling, UST Section, North Carolina Department of Environment and Natural Resources, December 1, 2013.
NCDEQ, UST Section, North Carolina Department of Environment Quality, Division
of Waste Management, Guidelines for Site Checks, Tank Closure, and Initial
Response and Abatement for Petroleum and Hazardous Substance UST
Releases, Petroleum Non-UST Releases, January 19, 2021.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, UST Section Assessment Guidelines,
Petroleum and Hazardous Substance UST Releases, Petroleum Non-UST
Releases, January 19, 2021.
NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 14 September 2021
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, UST Section Corrective Action Guidelines,
Petroleum and Hazardous Substance UST Releases, Petroleum Non-UST
Releases, January 19, 2021.
Powers, Mark, Recommendation for State Lead, November 2, 2020.
Rhodes, Thomas S., and Conrad, Stephen G., 1985, Geologic Map of North Carolina: Department of Natural Resources and Community Development, Division of Land Resources, and the NC Geological Survey, compiled by
Brown, Philip M., et al, and Parker, John M. III, and in association with the
State Geologic Map Advisory Committee, scale 1:500,000.
City of Durham, Durham Maps, https://durhamnc.gov/1455/Interactive-Maps, accessed September 8, 2021.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and
Ecosystem Support Division, Athens Georgia, Guidance – Design and
Installation of Monitoring Wells, Striggow, B., US. EPA Report No. SESGUID-101-R0, Effective Date February 18, 2008.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field
Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S.
EPA Report No. SESDPROC-206-R3, Effective Date December 18, 2015.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure –
Groundwater Level and Well Depth Measurement, Striggow, B., U.S. EPA
Report No. SESDPROC-105-R3, Effective Date November 3, 2016.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure –
Groundwater Sampling, Striggow, B., U.S. EPA Report No. SESDPROC-301-R4, Effective Date April 26, 2017.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – In Situ
Water Quality Monitoring, Chief, Field Services Branch, U.S. EPA Report No. SESDPROC-111-R4, Effective Date March 14, 2018.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Laboratory Services
and Applied Science Division, Athens Georgia, Operating Procedure Potable
Water Supply Sampling, Chief, Applied Science Branch, U.S. EPA Report No. ASBPROC-305-R4, Effective Date June 11, 2019.

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

TABLES
Page 1 of 1
TABLE 1
SITE HISTORY - UST/AST AND OTHER RELEASE INFORMATION
Incident Name and No.: Cheek Road Grocery - 33873
UST ID
Number
Name of
Owner/
Operator
Dates of
Ownership
Dates of
Operation
Last
Contents
Previous
Contents
Capacity
(gal)
Construction
Details
Tank
Dimensions
(inches)
Installation
Date
(mm/dd/yy)
Date
Removed
(mm/dd/yy)
1*04/21/78-
02/23/10
04/21/78-
02/23/10 Gasoline Gasoline 8,000 Steel 254 x 96 04/21/78 02/23/10
2*04/21/78-
02/23/10
04/21/78-
02/23/10 Gasoline Gasoline 4,000 Steel 288 x 64 04/21/78 02/23/10
3 04/23/71-
02/23/10
04/23/71-
02/23/10 Gasoline Gasoline 1,000 Steel 148 x 46 04/23/71 02/23/10
4*Unknown-
02/23-10
Unknown-
02/23-10 Kerosene Unknown 550 Steel 76 x 46 Unknown 02/23/10
5 Unknown-
02/24/10
Unknown-
02/24/10 Gasoline Unknown 1,000 Steel 145 x 46 Unknown 02/24/10
AST ID
Number
Name of
Owner/
Operator
Dates of
Ownership
Dates of
Operation
Last
Contents
Previous
Contents
Capacity
(gal)
Construction
Details
Tank
Dimensions
(inches)
Installation
Date
(mm/dd/yy)
Date
Removed
(mm/dd/yy)
1 Hinsley, Jerry Unknown-
02/23/10
Unknown-
02/23/10 Kerosene Unknown 1,000 Steel Unknown Unknown 02/23/10
Incident
Number
Material
Released
Date
Release
Discovered
(mm/dd/yy)
33873 Gasoline 06/27/07
Information obtained from HN (2010)
* = Tank system was associated with the release.
Description of the Release
Free product discovered on soils beneath gasoline dispensers at the site during UST inspection on June 27,
2007. TPH confirmed in soil samples taken during tank closure activities on February 23-24, 2010.
Hinesley,
Jerry
NCDEQ; 33873_Cheek Road Grocery; T1_Site History
CATLIN Project No. 221007
CATLIN Engineers and Scientists
Septmeber 2021
Page 1 of 3
TABLE 2
Incident Name and No.: Cheek Road Grocery - 33873
Well ID Property Address Durham County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
WSW-1 5801 Cheek Rd 0862-02-79-
0811 Ricks, Larry L 4802 Rogers Rd,
Durham, NC 27704
Active
Potable 130 / NE
WSW-2 5731 Cheek Rd 0862-02-69-
8766 Clements, Randolph K 5604 Cheek Rd,
Durham, NC 27704
Active
Potable 70 / SW
WSW-3 5721 Cheek Rd 0862-02-69-
8766 Clements, Randolph K 5604 Cheek Rd,
Durham, NC 27704
Active
Potable 180 / E
WSW-4 5613 Cheek Rd 0862-02-69-
2459
Thompson, Bobby;
Thompson, Gloria M
133 Jane Ct, Eden ,
NC 27288
Active
Potable 660 / W
WSW-5 3420 Paulwood Ct 0863-60-20-
6149 Hawkins, Evelyn T Same Active
Potable 750 / NW
WSW-6 3420 Paulwood Ct 0863-60-20-
6149 Hawkins, Evelyn T Same Active
Potable 750 / NW Per surveyor,well looks to be an old
hand-dug well
WSW-7 3424 Paulwood Ct 0863-60-00-
5614 Crabtree, Russell G Sr.Same Active
Potable 1,000 / NW
WSW-8 3423 Paulwood Ct 0862-02-69-
0749
Konrad, Steven; Konrad,
Jackie M Same Active
Potable 950 / W
WSW-9 3419 Paulwood Ct 0862-69-17-
4678 Knight, Patricia J Same Active
Potable 850 / W
WSW-10 5607 Cheek Rd 0862-02-69-
1503
Penell, Nathaniel D;
Pennell, Whitney Black Same Active
Potable 810 / W
WSW-11 5501 Cheek Rd 0862-02-59-
5890 Hudson, Patricia P Same Active
Potable 1,280 / W
WSW-12 5520 Cheek Rd 0862-02-59-
7299 Carter, Hope B Same Active
Potable 1,200 / W
WSW-13 5604 Cheek Rd 0862-02-58-
9545
Clements, Randolph K;
Clements, Diane S Same Active
Potable 1,195 / SW
PUBLIC AND PRIVATE WATER SUPPLY WELLS
NCDEQ; 33873_Cheek Road Grocery; T2_WSW Info
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 2 of 3
Incident Name and No.: Cheek Road Grocery - 33873
Well ID Property Address Durham County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
PUBLIC AND PRIVATE WATER SUPPLY WELLS
WSW-14 5610 Cheek Rd 0862-02-69-
2147
Moore, Ronnie R; Moore,
Melanie M
PO Box 21291,
Durham, NC 27703
Active
Potable 800 / SW
WSW-15 5706 Cheek Rd 0862-02-68-
6295
Riggs-Debalsi, Jera;
Debalsi, Karen L Same Active
Potable 1,050 / S
WSW-16 5704 Cheek Rd 0862-02-69-
5251
Parton, David J; Parton,
Jennifer L Same Active
Potable 550 / SW
WSW-17 5712 Cheek Rd 0862-02-69-
7223
Riggs, George K; Riggs,
Ruth F Same Active
Potable 420 / SW
WSW-18 5714 Cheek Rd 0862-02-79-
2014
Clemmensen, Frank G;
Clemmensen, Shirley J Same Active
Potable 460 / S
Per resident, 5804 Cheek Rd
(abandoned) is also connected to
well
WSW-19 5820 Cheek Rd 0862-02-79-
7612
Rogers, Jerry W;
Rogers, Donna H Same Active
Potable 880 / E
WSW-20 6003 Cheek Rd 0863-04-80-
3344
Wilson, Michael; Keith,
Tammy
5925 Cheek Rd,
Durham, NC 27704
Active
Potable 1,485 / NE
WSW-21 5925 Cheek Rd 0863-04-70-
8468
Keith, Thomas E; Keith,
Tammy M W Same Active
Potable 1,200 / NE
WSW-22 5919 Cheek Rd 0863-04-80-
0282
Wilson, Michael E;
Wilson, Leonard T;
Keith, Tammy M W
5925 Cheek Rd,
Durham, NC 27704
Active
Potable 1,290 / NE
WSW-23 5917 Cheek Rd 0863-04-70-
9190
Pittman, Timothy B;
Pittman, Heather R Same Active
Potable 1,160 / NE
WSW-24 5913 Cheek Rd 0863-04-70-
8098 Boney, John S Same Active
Potable 1,050 / E Residents drink bottled water
WSW-25 5909 Cheek Rd 0863-70-80-
3186
Rogers, Jerry W; Rogers
Donna H
5820 Cheek Rd,
Durham, NC 27704
Active
Potable 950 / E
WSW-26 5901 Cheek Rd 0863-04-70-
3545
Bordeaux, Billie R;
Bordeaux, Franklin D Same Active
Potable 630 / E
NCDEQ; 33873_Cheek Road Grocery; T2_WSW Info
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 3 of 3
Incident Name and No.: Cheek Road Grocery - 33873
Well ID Property Address Durham County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
PUBLIC AND PRIVATE WATER SUPPLY WELLS
WSW-27 5821 Cheek Rd 0862-02-79-
4818
Pope, Michael S; Pope,
Lisa D Same Active
Potable 530 / E
WSW-28 5813 Cheek Rd 0862-79-29-
0084 Gregory, Brenda N Same Active
Potable 350 / E
Receptor
ID Location Contact
Distance/
Direction from
Source Area (ft.)
Pond 1 5702 Cheek Rd Jera Gooch 955 / SW
Pond 2 5901 Cheek Rd Billie and Franklin
Bordeaux 745 / NE
Pond 3 5721 Cheek Rd Randolph Clements 730 / NW
Pond 4 5501 Cheek Rd Patricia Hudson 1,390 / WNW
Property data was obtained from the Durham County GIS data viewer, accessed August 30, 2021
Information obtained from a receptor survey conducted on August 12, 2021.
Pond created by damming an intermittent stream
Pond created by damming an intermittent stream
Pond created by damming an intermittent stream
Pond created by damming an intermittent stream
Description
NCDEQ; 33873_Cheek Road Grocery; T2_WSW Info
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 3
Incident Name and No.: Cheek Road Grocery - 33873
Map
ID #
Duhram County
PIN Number Property Address Occupant Owner Owner's Mailing Address
Site 0862-02-79-0811 5801 Cheek Road Unknown Residents Ricks, Larry L.4801 Rogers Road, Durham, NC
27704
1 0862-79-29-0084 5813 Cheek Road Gregory, Brenda N.Gregory, Brenda N.5813 Cheek Road, Durham, NC
27704
2 0862-02-79-2014 5714 Cheek Road Clemmensen, Frank G.;
Clemmensen, Shirley J.
Clemmensen, Frank G.;
Clemmensen, Shirley J.
5714 Cheek Road, Durham, NC
27704
3 0862-02-69-8766 5713 Cheek Road Unknown Residents Clements, Randolph K.5604 Cheek Road, Durham, NC
27704
4 0863-04-61-4571 3306 Creech Road Unknown Residents Jones, Larry W.; Jones,
Deborah H.
1012 Homer Street, Durham, NC
27707
Property data was obtained from the Durham County Maps GIS data viewer, accessed on August 30, 2021
CONTIGUOUS PROPERTY OWNERS/OCCUPANTS
NCDEQ; 33873_Cheek Road Grocery; T3_Contiguous Prop
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 4
Incident Name and No.: Cheek Road Grocery - 33873
Map ID
#
Date
Determined
(mm/dd/yy)
Name Land Use
Feature Zoning District Location
(Street Address)
Approximate
Distance / Direction
from Site
(feet)
Information obtained from the Durham County Maps GIS data viewer, accessed on August 30, 2021
SENSITIVE LAND USE FEATURES
No sensitive land use features within 1,500 feet.
NCDEQ; 33873_Cheek Road Grocery; T4_Land Use
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 5
Incident Name and No.: Cheek Road Grocery - 33873
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well
Diameter
(inches)
Well
Casing
Depth
(ft. BLS)*
Screened
Interval
(x to y ft.
BLS)
Bottom
of Well
(ft. BLS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free-Phase
Product
Thickness**
(ft.)
Ground
Water
Elevation
(ft.)
Comments
MW-01 08/11/21 08/20/21 2.0 10.0 10.0-20.0 20.0 NM 8.61 NMT NM Ɨ
Ɨ = Depth to water is above the screened interval
NMT = No Measureable Thickness
ft. BLS = Feet below land surface
NM = Not Measured
WELL CONSTRUCTION AND WATER LEVEL GAUGING DATA - AUGUST 20, 2021
NCDEQ; 33873_Cheek Road Grocery; T5_Well Con & Gauging
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 6
Incident Name and No.: Cheek Road Grocery - 33873
Boring ID Depth
(ft. BLS)
Date
Sampled
Time
Sampled
Concentration
(ppm)Comments
0.5-2.0 08/11/21 NA 6.6 Dry
4.0-6.0 08/11/21 NA 41.6 Dry
8.0-12.0 08/11/21 NA 1.7 Dry
14.0-16.0 08/11/21 NA 1.3 Wet
ft. BLS = feet Below Land Surface
ppm = parts per million
NA = Not Available (time not noted)
MW-01
FIELD SCREENING DATA - AUGUST 11, 2021
NCDEQ; 33873_Cheek Road Grocery; T6_Field Screening
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 7
Incident Name and No.: Cheek Road Grocery - 33873
Date
Collected
08/11/21 0.049 J 0.59 0.079 0.40 0.094 0.048 J 0.56 J 0.40 0.024 J 2.6 0.84 0.72 BMDL 0.13 J 0.33 0.11 J BMDL 140 188 BMDL 190
Sample depth (feet below land surface) is indicated in parantheses in the sample ID.
All results in milligrams per kilogram (mg/kg).
Bold results indicate concentrations above the lowest MSCC.
EPA = Environmental Protection Agency
MADEP = Massachusetts Department of Environmental Protection
EPH = Extractable Petroleum Hydrocarbon
VPH = Volatile Petroleum Hydrocarbon
MSCC = Maximum Soil Contaminant Concentration
# = Health based level> 100%
BMDL = Below Method Detection Limit
STGW = Soil-To-Groundwater
J = Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag).C5-C8 AliphaticsC9-C18 AliphaticsVaries
Varies
Varies1,2,4-TrimethylbenzeneTotal Xylenes1-Methylnaphthalene540
1,560
23,300
6.6
156
2,330
31
469
7,000
68
625
9,340
Combined MADEP EPH/VPH Fractions
C9-C22 Aromatics6
3,120
46,700 NaphthaleneAll other EPA Method 8270E AnalytesVaries
Varies
Varies
EPA Method 8270E
All other EPA Method 8260D AnalytesEPA Method 8260D
C19-C36 Aliphatics#
31,200
467,000
0.054
22.8
112
1.5
62.5
934
0.2
5.5
27
SUMMARY OF SOIL LABORATORY RESULTS - EPA METHOD 8260D, EPA METHOD 8270E, AND COMBINED MADEP EPH/VPH FRACTIONS
0.12
1,560
23,300
0.2
5.5
27
1.4
1,560
23,300
Method
Sample
ID
Contaminant of
Concern
MW-01
(5.0-7.0)Ethylbenzene6.6
156
2,330Benzene n-Butylbenzene2-Methylnaphthalenesec-Butylbenzene 1,3,5-TrimethylbenzeneIsopropylbenzene (Cumene)2.4
782
11,600
2.2
1,560
23,300
8
60.3
297
1.3
1,560
23,300
STGW MSCC
Residential MSCC
Industrial/Commercial MSCC
0.0072
12
59.4 p-Isopropyltoluene (p-Cymene)5.4
1,250
18,600Naphthalene n-PropylbenzeneToluene NCDEQ; 33873_Cheek Road Grocery; T7_Soil Results
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021
Page 1 of 1
TABLE 8
Incident Name and No.: Cheek Road Grocery - 33873
EPA
6020B
EPA
625
Date
Collected
08/20/21 5.2 J 0.68 1.2 0.30 J 0.41 J 0.17 J 0.24 J BMDL <100 <100 <100 <100 27 BMDL
08/20/21 6.2 J <0.13 <0.32 <0.15 <0.17 0.13 J <0.10 BMDL NA NA NA NA NA BMDL
08/20/21 <2.4 <0.13 <0.32 <0.15 <0.17 0.19 J <0.10 BMDL NA NA NA NA NA BMDL
All results in micrograms per liter (µg/L).
SM = Standard Method
EPA = Environmental Protection Agency
MADEP = Massachusetts Department of Environmental Protection
EPH = Extractable Petroleum Hydrocarbon
VPH = Volatile Petroleum Hydrocarbon
BMDL = Below Method Detection Limit
Bold results indicate concentrations above 2L GWQS.
GCL = Gross Contaminant Level
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
< = Less than method detection limit
J = Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag).
NE = Not Established
NA = Not Analyzed
Varies
VariesAll EPA 625 AnalytesSUMMARY OF GROUNDWATER LABORATORY RESULTS - SM 6200B, MADEP EPH/VPH, EPA METHOD 6020B AND 625
Method
Benzene Combined MADEP EPH/VPH
Fractions
LeadContaminant of
Concern
Toluene SM 6200B
260,000
600
70,000
70
20,000
20
Well/
Sample
ID
NE
200
Trip Blank
GCL (µg/L)
2L GWQS (µg/L)
Field Blank
6,000,000
6,000
5,000
1
Varies
Varies
28,500
400
15,000
15
MW-01 1,2-Dichloroethane Diisopropyl Ether (DIPE)Methyl tert-Butyl Ether (MTBE)Acetone 0.4
400 C5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AromaticsC19-C36 Aliphatics1,2,4-TrimethylbenzeneAll Other SM 6200B AnalytesNE
400
NE
700
NE
10,000
NCDEQ; 33873_Cheek Road Grocery; T8_GW Results
CATLIN Project No. 221007
CATLIN Engineers and Scientists
September 2021

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

FIGURES
SITE LOCATION
CHEEK RDREDWOOD RDCopyright:© 2013 National Geographic Society, i-cubed
FIGUREPROJECTTITLE
1CHEEK ROAD GROCERY5801 CHEEK RDDURHAM, NC SITE VICINITY MAP
2,000 0 2,000 4,0001,000
Feet
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007SEPT 2021 AS SHOWN KMU/SJO
³
!(P
!(P
!(P
!(P !(P
!(P
!(P!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P !(P
!(P
!(P
!(P !(P !(P
!(P !(P
!(P !(P
!(P
!(P
!(P
SITE LOCATIONCHEEK RD
1 ,0 0 0 F EET RADIUS
250FE E T RADIU
S
WSW-21
WSW-20
WSW-22WSW-23WSW-24
WSW-19
WSW-25WSW-26
WSW-27WSW-28
WSW-18WSW-17
WSW-16
WSW-4
WSW-3
WSW-6
WSW-5WSW-7
WSW-8
WSW-9
WSW-10
WSW-14
WSW-11
WSW-12
WSW-13
WSW-1
WSW-15
WSW-2
POND 1
POND 2
POND 4 POND 3
Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS,USDA, USGS, AeroGRID, IGN, and the GIS User Community
FIGUREPROJECTTITLE
2CHEEK ROAD GROCERY5801 CHEEK RDDURHAM, NC POTENTIAL RECEPTOR MAP
500 0 500 1,000250
Feet
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007SEPT 2021 AS SHOWN KMU/SJO
PotableWater Supply Well!(P
LEGEND
³
NOTE: Well locations were obtained from a field survey conducted on 08/12/21 and are approximate.
!(P
!(P
!>C H E E K R DT2T1T5T3T4
AST
WSW-1
WSW-2
MW-01
FORMER DISPENSERS
Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS,USDA, USGS, AeroGRID, IGN, and the GIS User Community
FIGUREPROJECTTITLE
3CHEEK ROAD GROCERY5801 CHEEK RDDURHAM, NC SITE MAP
40 0 40 8020
Feet
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007SEPT 2021 AS SHOWN KMU/SJO
Parcel Boundary
Potable
Water Supply Well!(P
NOTES: 1. Tank locations were obtained from previous reports prepared by other consultants and are approximate.2. Well locations were obtained from a field survey conducted on 08/12/21 and are approximate.
Approximate Location ofFormer UST/AST System
LEGEND
³
Monitoring Well(Type II)!>
Unknown Lines
Electric Lines
CHEEK RD
1 ,5 0 0 F E ET RADIUS
(3)
(2)
(1)
(4)
Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS,USDA, USGS, AeroGRID, IGN, and the GIS User Community
FIGUREPROJECTTITLE
4CHEEK ROAD GROCERY5801 CHEEK RDDURHAM, NC ZONING MAP
500 0 500 1,000250
Feet
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007SEPT 2021 AS SHOWN KMU/SJO
LEGEND
Residential Rural (RD)
NOTES:1. Zoning information were obtained from Open Data City and County of Durham and are approximate.2. Numbers correspond to contiguous property owners/occupants. Refer to Table 3.
³
Parcel Boundary
!(P
!(P
!>
C H E E K R D
WSW-1
WSW-2
MW-01
Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS,USDA, USGS, AeroGRID, IGN, and the GIS User Community
FIGUREPROJECTTITLE
5CHEEK ROAD GROCERY5801 CHEEK RDDURHAM, NC
SUMMARIZED ANALYTICAL RESULTS –AUGUST 11 & 20, 2021
40 0 40 8020
Feet
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007SEPT 2021 AS SHOWN KMU/SJO
Parcel Boundary
PotableWater Supply Well!(P
NOTES: 1. Tank locations were obtained from previous reports prepared by other consultants and are approximate.2. Well locations were obtained from a field survey conducted on 08/12/21 and are approximate.
Approximate Location ofFormer UST/AST System
LEGEND
³
Sampled Monitoring Well (Type II)!>
Incident Name and No.: Cheek Road Grocery - 33873MADEP EPH/VPH EPA 6020B EPA 625
DateCollected
08/20/21 1.2 B2L B2L 27 BMDL
All results in micrograms per liter (µg/L).B2L = Below 2L GWQSBold results indicate concentrations above 2L GWQS.BMDL = Below Method Detection Limits2L GWQS = NCAC T15A:02L Groundwater Quality StandardsRefer to Table 8 for additional notes
Method
SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS - Various Methods
All MADEP EPH/VPH FractionsLeadAll EPA 625 AnalytesGCL (µg/L)2L GWQS (µg/L) 0.4400 VariesVaries VariesVaries 15,00015 VariesVaries
Well/SampleIDMW-01
SM 6200B
Contaminant of Concern
1,2-Dichloroethane All Other SM 6200B AnalytesIncident Name and No.: Cheek Road Grocery - 33873
DateCollected
08/11/21 0.049 J BMSCC 0.13 J BMSCC 140 190 BMSCC
Sample depth (feet below land surface) is indicated in parantheses in the sample ID.Bold results indicate concentrations above the lowest MSCC.I/C = Industrial/Commercial All results in milligrams per kilogram (mg/kg).BMSCC = below lowest MSCC llimit See Table 7 for all other notes
Combined MADEP EPH/VPH Fractions
Benzene All other EPA Method 8260D AnalytesSampleIDMW-01(5.0-7.0)
Method EPA Method 8260D
SUMMARY OF SOIL LABORATORY RESULTS - Various Methods
Contaminant of Concern
686259,340
314697,000
VariesVariesVaries
VariesVariesVaries
0.05422.8112
VariesVariesVaries C9-C22 AromaticsAll other MADEP EPH/VPH FractionsSTGW MSCC Residential MSCC I/C MSCC
0.00721259.4 1-MethylnaphthaleneAll other EPA Method 8270E AnalytesC5-C8 AliphaticsEPA Method 8270E

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDICES

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDIX A HISTORICAL DATA
APPENDIX A HISTORICAL DATA (HN; 2010)
NCDEQ; 33873_Cheek Road Grocery; AppA CATLIN Project No. 221007 CATLIN Engineers and Scientists September 2021

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDIX B SITE PHOTOGRAPHS
APPENDIX B SITE PHOTOGRAPHS – AUGUST 12, 2021
NCDEQ; 33873_Cheek Road Grocery; AppB CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

Cheek Road Grocery
MW-01
Facing North
Cheek Road Grocery
MW-01

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDIX C
JOB HAZARD ANALYSIS, FIELD DATA SHEETS, AND
HEALTH AND SAFETY PLAN
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Drill Rig N/A
tools and materials N/A
Drill Rig 85 dBA
Drill Rig N/A
Exposure Potential
Likely
Likely
Likely
Start Stop
7:00 7:15
7:15 14:00
Date and Time:
8/11/2021 @ 7:15
8/11/2021 @ 7:15
8/11/2021 @ 7:15
Cold Weather Operations Unlikely
Heat (ambient)Likely
Slips/Trips/Falls Likely
NAPHTHALENE ppm
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
* Gas and/or Diesel
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
Potential Chemicals Concentration
BENZENE ppm
ETHYL BENZENE ppm
Chemical Hazards
Sunny and very hot
Site-Specific Job Hazard Analysis
Location Where Task/Operation Performed
Cheek Road Grocery (Durham)
Task/Operation
Well Installation
Employee Certifying this JHA
Print Name: Benjamin J. Ashba, P.G.Signature:
Operational Phase
Drilling
Date(s) this JHA
Conducted:
August 11
Weather:
PERSONNEL ONSITE
Name and Company (Print)Signature
Tommy Chalmers/CATLIN
Olivia Daynes/CATLIN Olivia Daynes
On-site safey meeting conducted. Topics included: staying hydrated, wearing safety vest when working near the
road, making sure no jewelry is worn near the drill rig, being mindful of the rig when it is in operation, listening to
the driller, lifting with legs when lifting heavy objects, making sure to wear hardhat, safety glasses and hearing protection when the drill rig is running, being careful of your footing and mindful of traffic on the roadway.
Installation of proposed well MW-01 to a depth of 20 feet BLS.
Equipment Used:PPE D/Water Level Indicator/Sampling Supplies/Generator/Pressure Washer/50' of Tubing
Drill Rig Operations Likely
Heavy Lifting/ Moving Likely
Noise Likely
Name of Biological Hazard Source
Start:End:
DAILY TASK
Edward Swain/CATLIN
surroundings
Biological Hazards
Rolling or Pinching Objects Likely
Van Mileage:
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac)surroundings
Insect bites and stings
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Exposure Potential
Likely
Likely
Unlikely
Start Stop
8:15 9:30
9:30 9:45
9:45 12:30
12:30 13:00
13:00 14:00
Date and Time:
8/11/21 @ 9:30
NAPHTHALENE ppm
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
* Gas and/or Diesel
Travel back to Carter's Grocery site.
Likely
Slips/Trips/Falls Likely
surroundings
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
Potential Chemicals Concentration
BENZENE ppm
ETHYL BENZENE ppm
Chemical Hazards
Sunny 90s
Site-Specific Job Hazard Analysis
Location Where Task/Operation Performed
Durham, NC
Task/Operation
Receptor Survey
Employee Certifying this JHA
Print Name: Sean O'Neil, P.E. Signature:
Operational Phase
Monitoring
Date(s) this JHA
Conducted:
8/12/21
PERSONNEL ONSITE
Name and Company (Print) Signature
Nathaniel Newman / CATLIN
Attempted to sample MW-1 but well was found to be completely dry.
Start: End:
DAILY TASK
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac) surroundings
Equipment Used: PPE D/Water Level Indicator/Sampling Supplies/Aqua Troll 600/Bailers
Van #39 Mileage:
Weather:
MOB and Travel to site
On site safety meeting. Watch for snakes. Wear safety vest when near the road and watch for dogs during
receptor survey. Watch for cars when near and crossing road. Drink plenty of water.
Receptor survey conducted within 1,500 feet.
Biological Hazards
Name of Biological Hazard Source
Insect bites and stings
Cold Weather Operations Unlikely
Heat (ambient)
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Exposure Potential
Likely
Unlikely
Unlikely
Start Stop
8:30 9:05
9:45 10:00
10:00 10:45
Date and Time:
8/11/21 @ 9:30
NAPHTHALENE ppm
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
* Gas and/or Diesel
Likely
Slips/Trips/Falls Likely
surroundings
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
Potential Chemicals Concentration
BENZENE ppm
ETHYL BENZENE ppm
Chemical Hazards
Sunny 90s
Site-Specific Job Hazard Analysis
Location Where Task/Operation Performed
Durham, NC
Task/Operation
Gauge and Sample Well
Employee Certifying this JHA
Print Name: Sean O'Neil, P.E. Signature:
Operational Phase
Monitoring
Date(s) this JHA
Conducted:
8/20/21
PERSONNEL ONSITE
Name and Company (Print) Signature
Nathaniel Newman / CATLIN
Start: End:
DAILY TASK
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac) surroundings
Equipment Used: PPE D/Water Level Indicator/Sampling Supplies/Aqua Troll 600/Bailers
Van #39 Mileage:
Weather:
MOB and Travel to site.
On site safety meeting. Watch for insects and spiders. Wear safety vest when in the parking lot. Set out cone in
parking lot while sampling. Watch for cars when near theroad. Drink plenty of water.
Sampled MW-01.
Biological Hazards
Name of Biological Hazard Source
Insect bites and stings
Cold Weather Operations Unlikely
Heat (ambient)
CATLIN PROJECT: SAMPLED BY:
CATLIN PROJECT # : DATE SAMPLED:
CLIENT'S NAME:
MW-1 11.39
8.61 1.859
NMT 5.577
20 9.294
2
Method:Bailer Purge Start Time:9:57
Required Bails for 3 Well Volumes:24 Purge Stop Time:10:09
Required Bails for 5 Well Volumes:39 Was Well Purged Dry?No
Number of Bails Removed:24 Sample Time:10:09
Groundwater Removed (gal):5.8
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
9:57 6.33 425.15 0.05 8.12 25.16
9:58 6.54 366.72 27.24 6.65 25.34
9:59 6.22 -39.23 424.93 5.63 25.48
10:00 6.28 -72.61 451.66 5.75 25.23
10:01 6.30 -102.29 481.83 5.64 24.94
10:02 6.35 -131.10 530.39 5.48 24.58
10:03 6.45 -162.86 572.54 5.21 24.28
10:04 6.47 -166.24 575.73 5.15 24.20
10:05 6.47 -161.21 576.91 5.12 24.17
10:06 6.47 -162.38 577.39 5.13 24.16
10:07 6.47 -164.50 577.76 5.10 24.16
10:08 6.48 -165.91 578.55 5.09 24.19
10:09 6.84 -6.08 231.30 5.07 24.30
Laboratory: Con-Test Analysis:
Well Data
Well ID
Depth to Product (ft below TOC)
Total Well Depth (ft)
Purging Information Information
Volume of Groundwater in Well
Well Diameter (inches)
GROUNDWATER SAMPLING FORM
Water Column (ft below TOC)
One Well Volume (gal)
Three Well Volumes (gal)
Five Well Volumes (gal)
6200B
Laboratory Analysis Information
Geochemical Parameters
Depth to Water (ft below TOC)
Mild turbidity. Light gray to
brown/red
Aqua Troll 600
Turbidity and Additional
Sampling Notes
NC-DEQ
Monitoring Well Information
Nate Newman
8/20/2021
Cheek Rd. Grocery
221007
HEALTH AND SAFETY PLAN
PROJECT NAME: CHEEK ROAD GROCERY
INCIDENT #: 33873
UST #: RA-6716
5801 CHEEK RD DURHAM, NC
CATLIN PROJECT NUMBER: 221007
PREPARED FOR: NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
PREPARED BY:
CATLIN ENGINEERS AND SCIENTISTS P.O. BOX 10279
WILMINGTON, NC 28404-0279
[phone]
PROJECT NAME and No.:
CLIENT NAME:
PROJECT ADDRESS:
SOIL:
GROUNDWATER:
FREE-PHASE PRODUCT:
PROJECT WORK
SCOPE:
NOTE: ATTACH SITE MAP(S), HOSPITAL ROUTE MAP(S) WITH WRITTEN DIRECTIONS, AND
MATERIAL SAFETY DATA SHEETS (MSDS) FOR EVERY CONTAMINANT LISTED ABOVE.
(Access information,
pass/badges required, etc.)
None
Groundwater Sampling
Confirm access agreement/right to enter before Site Recon. If not
on file, must receive Verbal approval. If no approval, CAN NOT
PROCEED OR BILL TRAVEL TIME.
ADDITIONAL
INFORMATION:
(Describe free-phase product
contamination.)
(List all field activities to be
completed.)
Ben Ashba - [phone]
Sean O'Neil - [phone]
PROJECT MANAGER
NAME and NUMBER:
CONTAMINATION INFORMATION
FIELD ACTIVITIES
EMERGENCY CONTACT
(NAME and NUMBER):
Ben Ashba - [phone]
Sean O'Neil - [phone]
Shane Chasteen - [phone]
HEALTH AND SAFETY PLAN
SITE SPECIFIC INFORMATION
Petroleum - Gasoline and/or Diesel and/or Kerosene
Petroleum - Gasoline and/or Diesel and/or Kerosene
(Describe soil contamination
and list potential
contaminants.)
(Describe groundwater
contamination and list
potential contaminants.)
SITE CONTACT (NAME
and NUMBER):
Ben Ashba - [phone]
Sean O'Neil - [phone]
Cheek Road Grocery - CATLIN Project No. 221007
North Carolina Department of Environmental Quality
5801 Cheek Rd., Durham, NC
NCDEQ SLP; SiteSpecificHASPinfo.xls
CATLIN Project No. 221007
CATLIN Engineers and Scientists
CHAPTER 1 ORGANIZATIONAL STRUCTURE
CHAPTER 2 JOB HAZARD ANALYSIS
CHAPTER 3 SITE CONTROL
CHAPTER 4 TRAINING PROGRAM
CHAPTER 5 MEDICAL SURVEILLANCE REQUIREMENTS
CHAPTER 6 PERSONAL PROTECTIVE EQUIPMENT
CHAPTER 7 EXPOSURE MONITORING
CHAPTER 8 THERMAL STRESS
CHAPTER 9 SPILL CONTAINMENT PROGRAM
CHAPTER 10 DECONTAMINATION PROGRAM
CHAPTER 11 EMERGENCY RESPONSE/CONTINGENCY PLAN
CHAPTER 12 STANDARD OPERATING PROCEDURES
CHAPTER 13 CONFINED SPACES PROGRAM
CHAPTER 14 HOTWORK
CHAPTER 15 HAZARDOUS ENERGY CONTROL PROGRAM (LOTO)
TABLE OF CONTENTS
Date of Program:Site Name:Cheek Road Grocery
1.0 ORGANIZATIONAL STRUCTURE
(in compliance with 29 CFR 1910.120(b)(2))
1.1 Roles and Responsibilities
This chapter of the Health and Safety Plan describes lines of authority, responsibility, and communication as they
pertain to health and safety functions at this site. The purpose of this chapter is to identify the personnel who impact
the development and implementation of the site health and safety plan and to describe their roles and
responsibilities. This chapter also identifies other contractors and subcontractors involved in work operations and
establishes the lines of communication among them for safety and health matters.
* the general supervisor who has the responsibility and authority to direct all field activities under CATLIN's contract.
* the lines of authority, responsibility, and communication for safety and health functions
The organizational structure of this site’s safety and health program is consistent with OSHA requirements in 29
CFR 1910.120(b)(2) and provides the following site-specific information:
* other personnel needed for hazardous waste operations and emergency response and their general functions
and responsibilities
* the site safety and health officer who has the responsibility and authority to develop and implement this HASP
and verify compliance
This section is reviewed and updated as necessary to reflect the current organizational structure at this site.
All personnel and visitors on this site must comply with the requirements of this HASP. All persons must speak and
understand English as part of compliance with this HASP. Failure to comply with this HASP may result in disciplinary
action as determined by the Owner. The specific responsibilities and authority of management, safety and health, and
other personnel on this site are detailed in the following paragraphs. A site organizational chart illustrating the
hierarchy of personnel and lines of communication within this company and with additional contractors on site is found
in Figure 1-1. Let it be known that one individual can perform multiply roles, if deemed necessary.
The Project Manager (PM) for this site is Benjamin Ashba. The PM has responsibility and authority to direct all work
operations. The PM coordinates safety and health functions with the Site Safety and Health Officer (SSHO), has the
authority to oversee and monitor the performance of the SSHO, and bears ultimate responsibility for the proper
implementation of this HASP. The specific duties of the PM are:
Preparing and coordinating the site work plan; providing site supervisor(s) with work assignments and overseeing their
performance; coordinating safety and health efforts with the SSHO; ensuring effective emergency response through
coordination with the Emergency Response Coordinator (ERC); serving as primary site liaison with public agencies and
officials and site contractors.
The qualified alternate Project Manager (PM) for this site is Sean O'Neil.
Project Manager (PM)
The Site Safety and Health Officer (SSHO) for this site is TBD. The SSHO has full responsibility and authority to develop
and implement this HASP and to verify compliance. The SSHO reports to the Project Manager. The SSHO is on site or
readily accessible to the site during all work operations and has the authority to halt site work if unsafe conditions are
detected. The specific responsibilities of the SSHO are:
Managing the safety and health functions on this site; serving as the site’s point of contact for safety and health matters;
ensuring site monitoring, worker training, and effective selection and use of PPE; assessing site conditions for unsafe acts
and conditions and providing corrective action; assisting the preparation and review of this HASP; maintaining effective
safety and health records as described in this HASP; coordinating with the Emergency Response Coordinator (ERC), Site
Supervisor(s), and others as necessary for safety and health efforts.
Site Safety and Health Officer (SSHO)
1 - 1 of 4 Date of Program:Site Name:Cheek Road Grocery
1.2 Identification of Other Site Contractors
Safety and health lines of communication with these contractors are illustrated in Figure 1-1.
The other contractors and subcontractors on this site who could be affected by the tasks and operations associated with
this workplan and HASP are listed in Table 1-2 below.
Company Function
Table 1-2 Other Site Contractors and Subcontractors
TBD
The Emergency Response Coordinator (ERC) for this site is TBD. The ERC is responsible for assessing site conditions
and directing and controlling emergency response activities in accordance with the Site Emergency Response Plan. The
ERC reports to the Project Manager (PM). The ERC will ensure the evacuation, emergency transport, and treatment of
site personnel and will notify the appropriate emergency response units and management staff in accordance with the
emergency response plan of this HASP. Specific duties of the ERC include:
Developing and reviewing the emergency response plan; conducting emergency response rehearsals; ensuring effective
emergency response to and evacuation of the site; coordinating emergency response functions with the Site Safety and
Health Officer (SSHO), and integrating site emergency response plans with the disaster, fire, and/or emergency response
plans of local, state, and federal organizations and agencies.
Emergency Response Coordinator (ERC)
The Site Supervisor for this site is TBD. The Site Supervisor is responsible for field operations and reports to the Project
Manager (PM). The Site Supervisor ensures the implementation of the HASP requirements and procedures in the field.
The specific responsibilities of the Site Supervisor are:
Executing the work plan and schedule as detailed by the PM; coordination with the Site Safety and Health Officer (SSHO)
on safety and health; ensuring site work compliance with the requirements of this HASP.
Site Supervisor
Site workers are responsible for complying with this HASP, using the proper PPE, reporting unsafe acts and conditions,
and following the work and safety and health instructions of the Project Manager (PM), Site Safety and Health Officer
(SSHO), and Site Supervisor.
Site Workers
1 - 2 of 4 Date of Program:Site Name:Cheek Road Grocery
1.3 Other local/State/Federal Agency Representatives and Their Roles Responsibilities
1 - 3 of 4 Date of Program:Site Name:Cheek Road Grocery
Figure 1-1 Organizational Chart
Insert the site organizational chart here, showing S&H lines of authority and communication among site contractors.
1 - 4 of 4 Date of Program:Site Name:Cheek Road Grocery
CONTRACT MANAGER
Benjamin J. Ashba, PG
CONTRACT QUALITY ASSURANCE
Michael E. Mason, PEACCOUNTING AND COST CONTROL SUPPORT
ENGINEERING TEAM
Michael E. Mason, PE
Jason R. Catlin, PE
Nicole L. Hall, PE
Joshua Norris, PE
Ben D. Lackey, PE
M. Robin Austin, PE, LEED AP
Cindy Liu, PhD, PE
Fowler Del Porto, PE, LEED AP
Matthew Aupperle, EI
FIELD SUPPORT TEAM
William Miller, CWC
Tommy Chalmers, CWC
Corey Futral, CWC
Stuart Bowman, CWC
Jordan Edmondson
Patrick McCain
Eddie Swain
Larry Wessell
Robert Baldwin, PG
Trevor Mizelle
Nate Newman
AutoCAD / GIS
Jeffery A. Roney
Buster Whitfield
Adrienne Willis
Karly Ulfsax
Brandon Hinkle
AutoCAD / GIS
Jeffery A. Roney
Buster Whitfield
Adrienne Willis
Karly Ulfsax
Brandon Hinkle
ASSESSMENT TEAM
Steve Hudson, PG, CWC
Lee Stone, PG
Corey Futral, CWC
Lindsay Pugh, PG
Kyle Swain
Stacey Martin
Jeffery Wilson
Abby Wesley
Sandy Miller
GEOTECHNICAL LABORATORYMichael D. MasonOlivia Daynes
GEOTECHNICAL LABORATORYMichael D. MasonOlivia Daynes
PROJECT MANAGERS
Sean J. O’Neil, PE
Shane Chasteen, PG
William J. Walsh, PE
2.0 JOB HAZARD ANALYSIS
(in compliance with 29 CFR 1910.120(b)(4)(ii)(A),and 1910.120(i))
This chapter of the HASP describes the safety and health hazards associated with site work and the control measures
selected to protect workers. The purpose of a job hazard analysis (JHA) is to identify and quantify the health and safety
hazards associated with each site task and operation, and to evaluate the risks to workers. Using this information,
appropriate control methods are selected to eliminate the identified risks if possible, or to effectively control them. The
control methods are documented in each task-specific JHA. The information contained in this chapter is essential to
effective preparation of all other chapters of the HASP. This section of the HASP includes:
2.1 Site History
The following text describes the site and its conditions as they relate to the need to perform hazardous substance clean-
up operations.
* a site description
* job hazard analysis
* hazardous substance information
* employee notification of hazards
2.2 Job Hazard Analysis
Health hazard information for all chemical substance identified in site JHAs appears in hazard data sheets attached to this
chapter.
The person responsible for ongoing job hazard analysis at this site is Ben Ashba or Sean O'Neil.
IB Property Holdings, LLc is the landowner if a property formerly operated as Cheek Road Grocery, located at 5801
Cheek Road in Durham, NC. The site formerly contained (1) 8,000 gallon gasoline, (1) 4,000 gallon gasoline & (1) 1,000
gasoline USTs which were registered with the NCDENR. It also contained (1) 1,000 gallon gasoline and (1) 550 gallon
kerosene USTs not registered and a, 1,000 gallon kerosene AST. A release from the USTs was discovered in 2007. All
tanks were removed from the site in 2010.
The sources used to provide the above description include:
Benjamin Ashba modifies site-specific JHAs and the accompanying data sheets when:
* the scope of work is changed by adding, eliminating, or modifying tasks
* new methods of performing site tasks are selected
* observation of the performance of site tasks results in a revised characterization of the hazards
* new chemical, biological, or physical hazards are identified
* exposure data indicate changes in the concentration and/or likelihood of exposure
* new/different control measures are selected
Each site-specific JHA appears on a separate copy of Table 2-2. Each JHA lists a task or operation required during site
clean-up and the location(s) where that task or operation is performed. A single JHA may be used for a task/operation
performed in multiple locations if the hazards, potential exposures, and controls are the same in each location.
Each JHA lists the chemical hazards associated with that task and their known or anticipated airborne concentrations
during performance of the task. Each JHA also identifies anticipated physical and biological hazards and potential
exposure levels or the likelihood of exposure. The final section of each JHA lists the control measures implemented to
protect employees from exposure to the identified hazards. The information provided here is designed to satisfy the job
hazard analysis requirements of 1910.120(b)(4)(ii)(A) and the workplace hazard assessment requirements of 1910.132(d).
When JHAs are modified, related provisions in other chapters of this HASP are modified as needed.
Monitoring Report
2 - 1 of 17 Date of Program:Site Name:Cheek Road Grocery
Table 2-2: Site-Specific Job Hazard Analysis
Operational Phase Task/Operation Location Where Task/Operation Performed
Monitoring Gauge and Sample Wells Subject Site
Date(s) this JHA Conducted Employee Certifying this JHA
TBD
Print Name Signature
Phase No
Exposure LimitChemical Name Source Concentration
Chemical Hazards
Groundwater ppm 0.5 ppm TLV-TWA ACGIHBENZENE
Groundwater ppm 100 ppm TLV-TWA ACGIHETHYL BENZENE
Groundwater ppm 20 ppm TLV-TWA ACGIHTOLUENE
Groundwater ppm 100 ppm TLV-TWA ACGIHXYLENE, ALL ISOMERS
Groundwater ppm 50 ppm TLV-TWA ACGIHMETHYL TERT-BUTYL ETHER
Groundwater ppm 10 ppm TLV-TWA ACGIHNAPHTHALENE
1,1,1,2-TETRACHLORO-2,2-
DIFLUOROETHANE
* Chemicals added by user
Exposure Level/
Potential
Name of Physical Hazard Exposure LimitSource
Physical Hazards
N/AatmosphereLikelyCold Weather Operations
N/AatmosphereLikelyHeat (ambient)
N/AsurroundingsLikelySlips/Trips/Falls
Source Exposure PotentialName of Biological Hazard
Biological Hazards
surroundings LikelyInsect bites and stings
surroundings LikelySnakes
surroundings LikelyPoison Plants (Ivy, Oak, and/or
Sumac)
surroundings LikelyLyme Disease - Ticks
2 - 2 of 17 Date of Program:Site Name:Cheek Road Grocery
Control Measures Used
Engineering Controls: See SOPs in Chapter 12
Work Practices: See SOPs in Chapter 12
Level of PPE: D Respirator Cartridge/Canister: Not Applicable
Service Life: Not Applicable
PPE Upgrade: No
PPE Downgrade: No
2 - 3 of 17 Date of Program:Site Name:Cheek Road Grocery
2.3 Employee Notification of Hazards and Overall Site Information Program
The information in the JHAs and the attached data sheets is made available to all employees who could be affected by it
prior to the time they begin their work activities. Modifications to JHAs and the accompanying data sheets are
communicated during routine briefings.
Consistent with paragraph (i) of HAZWOPER, we also inform other contractors and subcontractors about the nature and
level of hazardous substances at this site, and the likely degree of exposure to workers who participate in site operations.
For purposes of this HASP and all future project sites, Benzene and Lead constituents will be included, at a minimum, as
potential health risks.
The person responsible for providing site information, this HASP, and any modifications to the HASP to other contractors
and subcontractors working on this site is: TBD
2.4 Container Labeling
Labels and other forms of warning shall be in accordance with 29 CFR 1910.1200(f) and its subsections.
2 - 4 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: 1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE
CAS #: 76-11-9 Formula: CCl3CClF2UN No: NA
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
197ºF
105ºF
203.8
Physical Description: Colorless solid with a slight, ether-like odor. [Note: A liquid above 105ºF.]
40 mmHg
NA
NA
NA
NA
EXPOSURE GUIDELINES
500
OSHA NIOSH ACGIH Related Information
4170
NA
NA
NA
NA
Notes: NA
4170
NA
NA
NA
NA
Notes: NA
100
834
NA
NA
NA
NA
Notes: NA
IDLH ppm: 2000 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: NA
Carcinogen Classifications: NA
IDLH Notes: NA
HEALTH INFORMATION
Symptoms: central nervous system depression; pulmonary edema; eye, skin irritation; drowsiness; dyspnea
Health Effects: irritation-eyes, skin---mild; narcosis
Target Organ: eyes, skin, respiratory system, central nervous system
EMERGENCY RESPONSE INFORMATION
First Aid: Eyes: Irrigate immediately; Skins: Soap wash prompt; Inhalation: Respiratory support; Ingestion: Medical attention
immediately
Reactivity: Chemically-active metals such as potassium, beryllium, powdered aluminum, zinc, calcium, magnesium & sodium
acids
Nonfire Spill Response: NA
Fire Response: NA
Synonyms: 2,2-Difluoro-1,1,1,2-tetrachloroethane; Freon ® 112a; Halocarbon 112a; Refrigerant 112a
1.65
NA
NA
NA
NA
NA
Skin Notation:
500REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 5 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: BENZENE
CAS #: 71-43-2 Formula: C6H6UN No: 1114
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
176ºF
42ºF
78.1
Physical Description: Colorless to light-yellow liquid with an aromatic odor. [Note: A solid below 42ºF.]
75 mmHg
3
2
0
NA
EXPOSURE GUIDELINES
1
OSHA NIOSH ACGIH Related Information
3
5
15
NA
NA
Notes: SEE 29 CFR
1910.1028, FOR
INDUSTRIES EXEMPT
FROM THIS STANDARD
THE PELs ARE LOCATED
IN 29 CFR 1910.1000 TABLE
Z-2 (8-HR TWA=10 ppm,
C=25ppm, PEAK=50ppm
FOR A 10 MINUTE
INTERVAL DURING AN 8-
0.32
1
3.2
NA
NA
Notes: CARCINOGEN (Ca)
0.5
1.6
2.5
8
NA
NA
Notes: BEI,SKIN
IDLH ppm: 500 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: 50 ppm/150
ppm/1000 ppm
Carcinogen Classifications:
IARC-1, NIOSH-Ca, NTP-K,
OSHA-Ca, TLV-A1, EPA-K
IDLH Notes: Ca
HEALTH INFORMATION
Symptoms: eye, nose, respiratory system irritation; giddiness; headaches; nausea; staggered gait; fatigue; anorexia; lassitude;
dermatitis; bone marrow depression; [carcinogenic]
Health Effects: suspect leukemogen; cumulative bone marrow damage; TDlo (oral, human) 130 mg/mg
Target Organ: eyes, skin, respiratory system, blood, central nervous system, bone marrow
EMERGENCY RESPONSE INFORMATION
First Aid: EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or
medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after
flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected
skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with
soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation)
develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared
to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the
Synonyms: Benzol, Phenyl hydride
0.88
12ºF
1.2%
7.8%
9.24 eV
NA
Skin Notation:
0.1REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 6 of 17 Date of Program:Site Name:Cheek Road Grocery
mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever
possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or
equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high
risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious
and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control
center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by
mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT
INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. OTHER: Since this chemical is a known or
suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential
recommendation for medical monitoring. Recommendations from the physician will depend upon the specific compound, its
chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)
Reactivity: CHEMICAL PROFILE: Allyl chloride or other alkyl halides will react vigorously with benzene or toluene, even at
minus 70C. in the presence of ethyl aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported
(NFPA 491M 1991). Benzene ignites in contact with the powdered chromic anhydride (Mellor 11:235 1946-47).
(REACTIVITY, 1999)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to
knock-down vapors. ( AAR, 1999)
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of
water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as
possible. Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)
2 - 7 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: ETHYL BENZENE
CAS #: 100-41-4 Formula: C8H10UN No: 1175
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
277ºF
-139ºF
106.2
Physical Description: Colorless liquid with an aromatic odor.
7 mmHg
3
2
0
NA
EXPOSURE GUIDELINES
100
OSHA NIOSH ACGIH Related Information
435
NA
NA
NA
NA
Notes: NA
435
125
545
NA
NA
Notes: NA
100
434
125
543
NA
NA
Notes: BEI
IDLH ppm: 800 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: NA
Carcinogen Classifications:
IARC-2B, TLV-A3, EPA-D
IDLH Notes: 10% of LEL
HEALTH INFORMATION
Symptoms: eye, mucous membrane irritation; headaches; dermatitis; narcosis; coma
Health Effects: irritation-eye, nose, throat, skin---moderate; narcosis
Target Organ: eyes, skin, respiratory system, central nervous system
EMERGENCY RESPONSE INFORMATION
First Aid: EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or
medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after
flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected
skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with
soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to
transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep
breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest)
develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers
entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not
Synonyms: Ethylbenzol, Phenylethane
0.87
55ºF
0.8%
6.7%
8.76 eV
NA
Skin Notation:
100REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 8 of 17 Date of Program:Site Name:Cheek Road Grocery
available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT
INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and
IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a
physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and
lay the victim on his/her side with the Headache lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY
transport the victim to a hospital. (NTP, 1992)
Reactivity: STABILITY: This chemical is stable under normal laboratory conditions. Solutions of this chemical should be
stable for 24 hours under normal lab conditions.REACTIVITY: This compound can react vigorously with strong oxidizing
materials. (NTP, 1992)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to
knock-down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow
using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial
sorbents. Apply "universal" gelling agent to immobilize spill. Apply approriate foam to diminish vapor and fire hazard. Water
spill: Use natural barriers or oil spill control booms to limit spill travel. Use surface active agent (e.g. detergent, soaps,
alcohols), if approved by epa. Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms. If
dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount. Remove trapped
material with suction hoses. Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. (
AAR, 1999)
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of
water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as
possible. Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)
2 - 9 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: METHYL TERT-BUTYL ETHER
CAS #: 1634-04-4 Formula: C5H12OUN No: 2398
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
55.2
NA
88.17
Physical Description:
NA
NA
NA
NA
NA
EXPOSURE GUIDELINES
NA
OSHA NIOSH ACGIH Related Information
NA
NA
NA
NA
NA
Notes: NA
NA
NA
NA
NA
NA
Notes: NA
50
180
NA
NA
NA
NA
Notes: NA
IDLH ppm: NA IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: NA
Carcinogen Classifications:
IARC-3, TLV-A3
IDLH Notes: NA
HEALTH INFORMATION
Symptoms: NA
Health Effects: NA
Target Organ: NA
EMERGENCY RESPONSE INFORMATION
First Aid: INHALATION: Move victim to fresh air; call emergency medical care. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. EYES OR SKIN: Flush with running water for at least 15 minutes; hold eyelids open if
necessary. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body
temperature. INGESTION: If victim is unconscious or having convulsions, do nothing except keep victim warm. (USCG, 1999)
Reactivity: CHEMICAL PROFILE: Oxidizes readily in air to form unstable peroxides that may explode spontaneously
(Bretherick 1979. p.151-154, 164). A mixture of liquid air and diethyl ether exploded spontaneously (MCA Case History 616.
1960). (REACTIVITY, 1999)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors. ( AAR, 1999)
Synonyms: NA
NA
NA
NA
NA
NA
NA
Skin Notation:
NAREL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 10 of 17 Date of Program:Site Name:Cheek Road Grocery
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of
water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as
possible. Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)
2 - 11 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: NAPHTHALENE
CAS #: 91-20-3 Formula: C10H8UN No: 1334
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
424ºF
165 to 176ºF
128.2
Physical Description: Colorless to brown solid with an odor of mothballs. [Note: Shipped as a molten solid.]
0.08 mmHg
2
2
0
NA
EXPOSURE GUIDELINES
10
OSHA NIOSH ACGIH Related Information
50
NA
NA
NA
NA
Notes: NA
50
15
75
NA
NA
Notes: NA
10
52
15
79
NA
NA
Notes: SKIN
IDLH ppm: 250 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: NA
Carcinogen Classifications:
TLV-A4, EPA-CBD, NTP-R
IDLH Notes: NA
HEALTH INFORMATION
Symptoms: eye irritation; headaches; confusion, excitement, malaise; nausea, vomiting, abdominal pain; bladder irritation;
profuse sweating; jaundice; hematuria, hemoglobinuria, renal shutdown; dermatitis
Health Effects: irritation-eye, nose, throat, skin---marked; ocular damage/anemia/central nervous system damage
Target Organ: eyes, skin, blood, liver, kidneys, central nervous system
EMERGENCY RESPONSE INFORMATION
First Aid: EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or
medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after
flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected
skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with
soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation)
develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared
to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the
Synonyms: Naphthalin, Tar camphor, White tar
1.15
174ºF
0.9%
5.9%
8.12 eV
NA
Skin Notation:
10REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 12 of 17 Date of Program:Site Name:Cheek Road Grocery
mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever
possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or
equal to that advised under Protective Clothing. INGESTION: If the victim is conscious and not convulsing, give 1 or 2 glasses
of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Generally, the induction of
vomiting is NOT recommended outside of a physician's care due to the risk of aspirating the chemical into the victim's lungs.
However, if the victim is conscious and not convulsing and if medical help is not readily available, consider the risk of inducing
vomiting because of the high toxicity of the chemical ingested. Ipecac syrup or salt water may be used in such an emergency.
IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth,
ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body. DO NOT
INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Reactivity: CHEMICAL PROFILE: Naphthalene, camphor, glycerol, or turpentine will react violently with chromic anhydride
(Haz. Chem. Data 1967. p 68). (REACTIVITY, 1999)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid
material. Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water. Water spill: Use natural deep
water pockets, excavated lagoons, or sand bag barriers to trap material at bottom. If dissolved, in region of 10 ppm or greater
concentration, apply activated carbon at ten times the spilled amount. Remove trapped material with suction hoses. Use
mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Cool all affected
containers with flooding quantities of water. Apply water from as far a distance as possible. Solid streams of water may be
ineffective. Use "alcohol" foam, dry chemical or carbon dioxide. ( AAR, 1999)
2 - 13 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: TOLUENE
CAS #: 108-88-3 Formula: C7H8UN No: 1294
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
232ºF
-139ºF
92.1
Physical Description: Colorless liquid with a sweet, pungent, benzene-like odor.
21 mmHg
3
2
0
NA
EXPOSURE GUIDELINES
200
OSHA NIOSH ACGIH Related Information
NA
NA
300
NA
NA
Notes: PEAK = 500 ppm FOR
A 10 MINUTE INTERVAL
DURING AN 8-HOUR SHIFT
375
150
560
NA
NA
Notes: NA
20
75
NA
NA
NA
NA
Notes: NA
IDLH ppm: 500 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: 50 ppm/300
ppm/1000 ppm
Carcinogen Classifications:
IARC-3, TLV-A4, EPA-NL
IDLH Notes: NA
HEALTH INFORMATION
Symptoms: fatigue, weakness; confusion, euphoria, dizziness; headaches; dilated pupils, lacrimation; nervousness; muscle
fatigue; insomnia; paresthesia; dermatitis
Health Effects: irritation-eye, nose, throat, skin---moderate; narcosis;
Target Organ: eyes, skin, respiratory system, central nervous system, liver, kidneys
EMERGENCY RESPONSE INFORMATION
First Aid: EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or
medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after
flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected
skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with
soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to
transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep
breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest)
develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers
Synonyms: Methyl benzene, Methyl benzol, Phenyl methane, Toluol
0.87
40ºF
1.1%
7.1%
8.82 eV
NA
Skin Notation:
100REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 14 of 17 Date of Program:Site Name:Cheek Road Grocery
entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not
available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT
INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and
IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a
physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and
lay the victim on his/her side with the Headache lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY
transport the victim to a hospital. (NTP, 1992)
Reactivity: CHEMICAL PROFILE: Allyl chloride or other alkyl halides will react vigorously with benzene or toluene, even at
minus 70 C in the presence of ethyl aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported
(NFPA 491M 1991). (REACTIVITY, 1999)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to
knock-down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow
using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial
sorbents. Apply "universal" gelling agent to immobilize spill. Apply approriate foam to diminish vapor and fire hazard. Water
spill: Use natural barriers or oil spill control booms to limit spill travel. Use surface active agent (e.g. detergent, soaps,
alcohols), if approved by epa. Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms. If
dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount. Remove trapped
material with suction hoses. Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. (
AAR, 1999)
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of
water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as
possible. Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)
2 - 15 of 17 Date of Program:Site Name:Cheek Road Grocery
Chemical Name: XYLENE, ALL ISOMERS
CAS #: 1330-20-7 Formula: C8H10UN No: 1307
CHEMICAL IDENTIFICATION
PHYSICAL PROPERTIES
281ºF
-12/-54/55ºF
106.2
Physical Description: Colorless liquid with an aromatic odor. [Note: A solid below 56ºF.]
9 mmHg
3
2
0
NA
EXPOSURE GUIDELINES
100
OSHA NIOSH ACGIH Related Information
435
NA
NA
NA
NA
Notes: NA
435
150
655
NA
NA
Notes: NA
100
434
150
651
NA
NA
Notes: BEI
IDLH ppm: 900 IDLH mg/m3: NA
AIHA Emergency Response
Planning Guidelines
(ERPGs)EPRG-1/EPRG-
2/EPRG-3: NA
Carcinogen Classifications:
IARC-3, TLV-A4, EPA-D; I
IDLH Notes: NA
HEALTH INFORMATION
Symptoms: irritation eyes, skin, nose, throat; dizziness, excitement, drowsiness, incoordination, staggering gait; corneal
vacuolization; anorexia, nausea, vomiting, abdominal pain; dermatitis
Health Effects: irritation-eye, nose, throat, skin---moderate; narcosis;
Target Organ: eyes, skin, respiratory system, central nervous system, gastrointestinal tract, blood, liver, kidneys
EMERGENCY RESPONSE INFORMATION
First Aid: EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline
solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or
medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after
flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected
skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with
soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to
transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep
breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest)
develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers
Synonyms: 1,2(3 or 4)-Dimethylbenzene, ortho(meta or para)-Xylene, o(m or p)-Xylol
0.86-0.88
81-90ºF
0.9-1.1%
6.7-7.0%
8.44-8.56 eV
NA
Skin Notation:
100REL-TWA ppm:
REL-TWA mg/m3:
REL-STEL ppm:
REL-STEL mg/m3:
REL-C ppm:
REL-C mg/m3:
PEL-TWA ppm:
PEL-TWA mg/m3:
PEL-STEL ppm:
PEL-STEL mg/m3:
PEL-C ppm:
PEL-C mg/m3:
TLV-TWA ppm:
TLV-TWA mg/m3:
TLV-STEL ppm:
TLV-STEL mg/m3:
TLV-C ppm:
TLV-C mg/m3:
BP:
MLT:
Fl.P:
Sp. Gr.:
MW:
VP:
VD:
IP:
LEL:
UEL:
NFPA Fire Rating:
NFPA Health Rating:
NFPA Reactivity Rating:
NFPA Sp. Inst.:
2 - 16 of 17 Date of Program:Site Name:Cheek Road Grocery
entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not
available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT
INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and
IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a
physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and
lay the victim on his/her side with the Headache lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY
transport the victim to a hospital. (NTP, 1992)
Reactivity: CHEMICAL PROFILE: Xylene reacts with sulfuric acid, nitric acid, and strong oxidants liberating heat. (Handling
Chemicals Safely 1980. p. 962). (REACTIVITY, 1999)
Nonfire Spill Response: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and
sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to
knock-down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow
using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial
sorbents. Apply "universal" gelling agent to immobilize spill. Apply approriate foam to diminish vapor and fire hazard. Water
spill: Use natural barriers or oil spill control booms to limit spill travel. Use surface active agent (e.g. detergent, soaps,
alcohols), if approved by epa. Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms. If
dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount. Remove trapped
material with suction hoses. Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. (
AAR, 1999)
Fire Response: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of
water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as
possible. Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)
2 - 17 of 17 Date of Program:Site Name:Cheek Road Grocery
3.0 SITE CONTROL
(in compliance with 29 CFR 1910.120(b)(4)(ii)(F) and 29 CFR 1910.120(d))
* a site map, indicating site perimeter and work zones
* site access procedures
* site security
TBD is responsible for evaluating site conditions and for verifying that the site control program functions effectively. The site control
program is updated regularly to reflect current site conditions, work operations, and procedures.
Access to this site is restricted to reduce the potential for exposure to its safety and health hazards. During hours of
site operation, site entry and exit is authorized only at the point(s) identified in Figure 3-1. Entry and exit at these
points is controlled by the following: Property Owner. When the site is not operating, access to the site is controlled
by the following: Property Owner.
This site control program is designed to reduce the spread of hazardous substances from contaminated areas to clean
areas, to identify and isolate contaminated areas of the site, to facilitate emergency evacuation and medical care, to prevent
unauthorized entry to the site, and to deter vandalism and theft. If a site is determined to be non-hazardous, based on level
and type of contaminants, then the PM will establish appropriate site control measures.
* site work zones including standard operating procedures
* both internal (on-site) and external communications
* use of the buddy system
3.1 Site Map
3. 2 Site Access
3.3 Site Security
A map of this site, showing site boundaries, designated work zones, and points of entry and exit is provided in Figure 3-1, at the
end of this chapter. Please note that this information will likely be added by the SSHO during the initial site visit and prior to start of
any work.
3.4 Site Work Zones (To be established by PM prior to start of any work)
Security at this site is maintained during both working hours and non-working hours to prevent unauthorized entry; removal of
contaminated material from the exclusion zone; exposure of unauthorized, unprotected people to site hazards; and increased
hazards due to vandalism and theft.
The site control program includes the elements specified in 29 CFR 1910.120(d) and provides the following site-specific
information:
Visitors to the site register with TBD, and are escorted at all times. Visitors are expected to comply with the
requirements of this HASP. Visitors who want to enter contaminated areas of the site must provide documentation
that they have the required training and medical evaluation and must receive a site-specific briefing about protecting
themselves from site hazards, recognizing site zones demarcations, and following emergency evacuation
procedures. PPE for visitors is provided by Not Applicable.
Security During Working Hours
Not Applicable is responsible for establishing and maintaining site security during working hours. This site takes the following
measures for security during working hours:
Security During Non-working Hours
Not Applicable is responsible for establishing and maintaining site security during non-working hours. The following measures
have been taken for security during non-working hours:
The site is monitored for changing conditions that may warrant adjustment of zone boundaries. Zone boundaries are adjusted as
necessary to protect personnel and clean areas. Whenever boundaries are adjusted, zone markings are also changed and
workers are immediately notified of the change.
This site is divided into three (3) major zones, described below and shown in Figure 3-1. Please note that dividing the site into three
zones may not be necessary pending level and type of contaminants. These zones are
Zone boundaries are clearly marked at all times and the flow of personnel among the zones is controlled.
characterized by presence or absence of biological and chemical hazards and the activities performed within them.
This is a private residence and no security measures are enforced. 1.
This is a private residence and they prevent unauthorized entry on their property. 2.
A local police department is used for site surveillance. 1.
Operations are outdoors and no entry into the residence is required. 2.
3 - 1 of 6 Date of Program : Site Name :Cheek Road Grocery
The following criteria were considered in establishing the site work zones:
Personnel in the Exclusion Zone will adhere to the following SOPs:
Personnel and equipment will enter and exit the Exclusion Zone from the designated access points in the Contamination Reduction
Zone (CRZ), shown in Figure 3-1.
Exclusion Zone
The Exclusion Zone is the area where hazardous substance is known or suspected to be present and pose the
greatest potential for exposure. Remediation operations (site clean-up) are performed in the Exclusion Zone. At this
site, the Exclusion Zone boundaries are marked with the following: CATLIN personnel determines boundaries when
on-site.
The CRZ is located between the Exclusion Zone and the Support Zone (clean zone). Its primary purpose is for
decontamination of workers and equipment. The CRZ also serves as a buffer between the Exclusion Zone and
Support Zone, to limit the potential for contamination to spread to the Support Zone and outlying areas. At this site,
the CRZ boundaries are marked with CATLIN personnel determines boundaries when on-site..
Contamination Reduction Zone (CRZ)
Exclusion Zone (ExZ) SOPs
Based on monitoring results, the CRZ boundaries may be adjusted to ensure that the Support Zone remains uncontaminated.
Required clean-up activities. 1.
Sampling results for air and surface contaminants. 2.
Air dispersion calculations. 3.
Potential for fire. 4.
Physical, chemical, toxicological, and other characteristics of substances present. 5.
Physical and topographical features of the site. 6.
Weather conditions, particularly the direction of prevailing winds relative to the locations of the support zone and
other uncontaminated areas onsite.
7.
Potential for explosion and flying debris. 8.
Check in and out of this zone at the designated access point(s). 1.
Use the buddy system at all times. 2.
Wear the PPE required for this zone (see PPE section of this HASP). 3.
Perform air monitoring as required for this zone (see Exposure Monitoring section of this HASP). 4.
No smoking, eating, or drinking. 5.
No matches, lighters, or open flame. 6.
Monitor self and buddy for signs of heat or cold stress or chemical overexposure. 7.
Alert supervisor to signs of changing or unanticipated hazards. 8.
No horseplay. 9.
Monitor self and buddy for PPE rips, tears, and/or damage. 10.
Use monitoring equipment and tools that are safe for the working environment. 11.
Use ground-fault circuit interrupters (GFCIs) when necessary to prevent electric shock. 12.
Use three-wire grounded extension cords for portable electric tools and appliances. 13.
Keep loose-fitting clothing or loose long hair away from moving machinery. 14.
Use signaling to direct heavy equipment operating in tight quarters. 15.
No refueling engines while equipment is running. 16.
No ignition sources within 50 feet of refueling areas. 17.
Lower all blades and buckets to the ground and set parking brakes before shutting off vehicles. 18.
Never exceed the rated load capacity of a vehicle. 19.
3 - 2 of 6 Date of Program : Site Name :Cheek Road Grocery
Workers and equipment exit the Exclusion Zone through the designated access point(s) into the CRZ. Workers and equipment are
then decontaminated in the CRZ, according to the procedures specified in the Decontamination section of this HASP. Workers and
equipment then exit the CRZ into the Support Zone through the designated access points, shown in Figure 3-1.
Within the Support Zone, personnel will adhere to the following SOPs:
3.5 Buddy System
While working in the Exclusion Zone, site workers use the buddy system. The buddy system means that personnel work in pairs
and stay in close visual contact to be able to observe one another and summon rapid assistance in case of an emergency. The
responsibilities of workers using the buddy system include:
If necessary, emergency decontamination procedures are implemented. Emergency decontamination procedures are described in
the site's emergency response program.
Personnel in the CRZ will adhere to the following SOPs:
The Support Zone is the clean area of the site, beyond the outer boundary of the CRZ. There should be no contamination in this
zone. Administrative, clerical, and other support functions are based in the Support Zone.
Support Zone
The Support Zone is shown in Figure 3-1 and its boundaries are marked by CATLIN personnel determines boundaries when on-
site..
3.6 Site Communications
The following communication equipment is used to support on-site communications:
Telephones at this site are located in the following areas:
Contamination Reduction Zone (CRZ) SOPs
Support Zone (SZ) SOPs
Based on monitoring results, the CRZ boundaries may be adjusted to ensure that the Support Zone remains uncontaminated.
Air and surface monitoring are conducted in the Support Zone as needed to ensure that it remains uncontaminated. If
contamination is detected, zone boundaries are adjusted until corrective action is taken and monitoring results indicate that this
zone is again uncontaminated.
* remaining in close visual contact with partner,
* providing partner with assistance as needed or requested,
* observing partner for signs of heat stress or other difficulties,
* periodically checking the integrity of partner's PPE, and
* notifying the site manager or other site personnel if emergency assistance is needed.
Check in and out of this zone at the designated access point(s). 1.
Wear the PPE required for this zone (see PPE section of this HASP). 2.
Perform air and surface sampling as required for this zone (see Exposure Monitoring section of this HASP). 3.
Use monitoring equipment and tools that are safe for the working environment. 4.
No smoking, eating, or drinking. 5.
No matches, lighters, or open flame. 6.
Monitor self and buddy for signs of heat or cold stress or chemical overexposure. 7.
Alert supervisor to signs of changing or unanticipated hazards. 8.
No horseplay. 9.
Monitor self and buddy for PPE rips, tears, and/or damage. 10.
Check in and out of this zone at the designated site access point(s). 1.
Alert supervisor to signs of changing or unanticipated hazards. 2.
No horseplay. 3.
Perform air and surface sampling as required for this zone (see Exposure Monitoring section of this HASP). 4.
3 - 3 of 6 Date of Program : Site Name :Cheek Road Grocery
In addition, site personnel are trained to recognize and use hand signals when visual contact is possible but noise or PPE inhibit
voice communication. These hand signals are listed below in Table 3-6
Signal Meaning
Telephones at this site are located in the following areas:
A current list of emergency contact numbers is posted in the following locations:
Table 3-6 Site Communication - Hand Signals
Each person is equipped with a cell phone
Site Field Book
Clutching throat Out of air/cannot breathe
Thumbs down No
Thumbs up OK/understood
Both arms waving upright above head Need assistance/send support
Stand with hands on waist or grab partner's wrist Exit immediately
3 - 4 of 6 Date of Program : Site Name :Cheek Road Grocery
3.7 Emergency Medical Assistance (To be filled in by PM prior to start of any work)
The nearest emergency medical assistance selected to support this site is:
Organization:
Contact:
Address/Location:
Telephone:
Duke University Hospital
On-site Staff
2301 Erwin Rd, Durham, NC 27710
9196848111
A map to this facility is located in the Emergency Response chapter of this HASP, Figure 11-3b.
3 - 5 of 6 Date of Program : Site Name :Cheek Road Grocery
Figure 3-1 Map of Site Boundaries, Work Zones, and Entry/Exit Points
Insert site map with zone boundaries and access points here.
3 - 6 of 6 Date of Program : Site Name :Cheek Road Grocery
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FIGUREPROJECTTITLE
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INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY33873221007JULY 2021 AS SHOWN KMU/SJO
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Approximate Location ofFormer UST/AST System
LEGEND
4.0 TRAINING PROGRAM
(in compliance with 29 CFR 1910.120(e))
4.1a Training Elements to be Covered for Site Workers:
* training for site workers
* site briefings for visitors and workers
* initial HAZWOPER training (40 or 24 hr)
* supervised field experience
* management and supervisor training
* qualification of trainers
* training certification
* emergency response training ##
* refresher training
* equivalent training
* training records
Other training received by workers that is in addition to required training elements described above is detailed below in
the following table (Table 4-1a):
Table 4-1a Other Training for Site Workers
The site training program is designed to ensure that workers receive the training they need to work safely on this site.
Site safety and health training requirements are based on the job hazard assessments contained in Chapter 2 of this
HASP and relevant OSHA requirements. At this site, CATLIN Project Manager oversees the implementation of this
training program and is responsible for ensuring that employees are adequately and currently trained for all tasks they are
asked to perform. Employees who have not been trained to a level required by their job function and responsibility are not
permitted to participate in or supervise field activities.
A site-specific briefing is provided to all site visitors who enter this site beyond the site entry point.
4.2 Initial Training
For visitors, the site-specific briefing provides information about site hazards, the site lay-out including work zones and
places of refuge, the emergency alarm system and emergency evacuation procedures, and other pertinent safety and
health requirements as appropriate.
This training program is consistent with the requirements of 29 CFR 1910.120(e) and addresses the following site-specific
information:
## Emergency response training is addressed in HASP Chapter 11, Emergency Response Plan.
- names of personnel and alternates responsible for site safety and health
- safety, health and other hazards present on the site
- use of PPE
- work practices by which the employee can minimize risks from hazards
- safe use of engineering controls and equipment on the site
- medical surveillance requirements detailed in Chapter 5 of this HASP
- decontamination procedures detailed in Chapter 10 of this HASP
- the emergency response plan detailed in Chapter 11 of this HASP
- confined space entry procedures detailed in Chapter 13 of this HASP
- the spill containment program detailed in Chapter 9 of this HASP
- the site control plan detailed in Chapter 3 of this HASP
4.1b Site-Specific Briefings for Visitors
Site personnel review this HASP and are provided a site-specific briefing prior to the commencement of work to ensure that
employees are familiar with this HASP and the information and requirements it contains. Additional briefings are provided as
necessary to notify employees of any changes to this HASP as a result of information gathered during ongoing site
characterization and analysis. Conditions for which we schedule additional briefings include, but are not limited to: changes in
site conditions, changes in the work schedule/plan, newly discovered hazards, and incidents occurring during site work.
4.1c HASP Information and Site-Specific Briefings for Workers
Heat and cold stress prevention
Working safely around heavy equipment
Hearing conservation, in accordance with 29 CFR 1910.95
Basic First Aid and CPR
4 - 1 of 2 Date of Program:Site Name:Cheek Road Grocery
Personnel at this site must successfully complete 40-hour initial HAZWOPER training consistent with the requirements of 29
CFR 1910.120(e)(3)(i) in order to work in contaminated areas. In addition, such personnel provide documentation of having
received 3 days of supervised field experience applicable to this site, or receive three days of supervised field experience at this
site.
Training received by managers and supervisors is summarized below in the following table (Table 4-3):
Only instructors qualified in accordance with 29 CFR 1910.120(e)(5) are used to train workers for this site. Qualified
instructors have either completed a training program for teaching the subjects they are expected to teach or have the
academic credentials and instructional experience necessary for teaching the subjects.
Initial training requirements are based on a worker’s potential for exposure and compliance with the requirements of 29
CFR 1910.120(e)(3).
This site does not accept prior academic training or job site experience in lieu of HAZWOPER initial training for workers
and supervisors.
4.3 Management and Supervisor Training
On-site managers and supervisors who are directly responsible for or who supervise workers engaged in hazardous
waste operations receive, in addition to the appropriate level of worker HAZWOPER training described above, 8
additional hours of specialized supervisory training, in compliance with 29 CFR 1910.120(e)(4).
Table 4-3 Training for Managers and Supervisors
4.4 Qualification of Trainers
Employees and supervisors that receive and complete the necessary training and field experience are certified when
they complete the necessary training. A written certificate is given to each person so certified. Any person who has not
been so certified or who does not meet the requirements of equivalent training is prohibited from engaging in hazardous
waste operations on this site.
4.5 Training Certification
Emergency response training is addressed in Chapter 11 of this HASP, Emergency Response Plan.
4.6 Emergency Response
All workers on this site including managers and supervisors receive annual HAZWOPER refresher training consistent
with the requirements of 29 CFR 1910.120(e)(8). The following table (Table 4-7) details refresher training topics:
4.7 Refresher Training
Table 4-7 Refresher Training Topics
4.8 Equivalent Training
4.9 Training Records
This site maintains written certification of the successful completion of applicable training requirements for each worker.
Training records are maintained up-to-date and are retained onsite at the following location: CATLIN Wilmington Office.
Written certificates have been given to each person so certified. Additionally, an employee sign off sheet indicating that
each worker has received a copy of this HASP and understands its contents is stored at the same location.
Personal protective equipment program
Management of the site work zones
Employer’s safety and health program
Review of PPE including levels of protection
Review of safety procedures
Review of policy changes
Review of emergency response procedures
Review of physical hazards
Review of chemical hazards
4 - 2 of 2 Date of Program:Site Name:Cheek Road Grocery
Medical Surveillance RequirementsLocationPeriodic ExamTask/OperationBaseline Exam
5.0 MEDICAL SURVEILLANCE
(in compliance with 29 CFR 1910.120(f) and other substance-specific medical surveillance requirements found in
29 CFR 1910.1001-1052)
5.1 Site Medical Surveillance Program
Medical surveillance requirements are based on a worker’s potential for exposure as determined by the site characterization and
job hazard analysis documented in Chapter 2 of this HASP and on compliance with the requirements of 29 CFR 1910.120(f)(2).
The medical surveillance program is consistent with 29 CFR 1910.120(f) and addresses the following information:
* provisions of the site medical surveillance program
* communication between the site, physicians, and workers
* medical recordkeeping procedures
The medical surveillance section of the Health and Safety Plan describes how worker health status is monitored at this site.
Medical surveillance is used when there is the potential for worker exposure to hazardous substance at levels above OSHA
permissible exposure limits or other published limits. The purpose of a medical surveillance program is to medically monitor
worker health to ensure that personnel are not adversely affected by site hazards. The provisions for medical surveillance at
this site are based on the site characterization and job hazard analysis found in Chapter 2 of this HASP and are consistent
with OSHA requirements in 29 CFR 1910.120(f) and the following substance-specific requirements: BENZENE (1910.1028,
1926.1128).
3. Medical examination for personnel within the medical surveillance program were determined by the site's attending
physician and include the following:
5.2 Communication Between the Site, Physicians, and Workers
The medical facility providing medical monitoring and overexposure examinations required by personnel at this site is:
The licensed attending physician for this site is:
CATLIN has provided information about site hazards and potential exposure levels, work activities, and PPE
requirements, and other information as required by OSHA in 29 CFR 1910.120(f)(6) to the above-mentioned facility and
physician. CATLIN will also make this information available to site personnel and/or their personal physicians.
A physician’s written opinion of the results of these examinations is required for each worker and a copy is maintained at
CATLIN's Corporate Office. The contents of the written opinion is limited to:
* a statement of the worker’s health status in relation to his or her job duties and a description of any detected medical
condition that could put the worker at increased risk.
* notation of any recommended limitations in work activity or PPE use.
* confirmation that the physician has informed the employee of the examination results and any further examination or
treatment required.
Name:
Location:
Phone:
Name:
Phone:
The person with responsibility for ensuring this program is implemented and maintained is Mike D. Mason.
Operational Phase
Medac Coporate Health
4402 Shipyard Blv. Wilmington, NC
9104527000
Dan Shapiro, PA-C
9104527000
Table 5-1a Types of Workers Included in the Medical Surveillance Program
Termination Exam
Table 5-1b Medical Surviellance for Site Workers
Monitoring Gauge and Sample
Wells
Subject Site
Survey Receptor Survey within 1,500
feet of the site
5 - 1 of 2 Date of Program:Site Name:Cheek Road Grocery
5.3 Medical Recordkeeping Procedures
(in compliance with 29 CFR 1910.120(f)(8) and 1910.1020)
The following items are maintained in worker medical records:
5.4 Program Review
* review of accident and injury records and medical records to determine whether the causes of accidents and illness
are promptly investigated and whether corrective measures are taken wherever possible,
* evaluation of the appropriateness of required medical tests on the basis of site exposures, and
* review of emergency treatment procedures and emergency contacts list to ensure they are site-specific, effective,
and current.
Corporate medical recordkeeping procedures are consistent with the requirements of 29 CFR 1910.1020 and
are described in the company’s overall safety and health program. A copy of that program is available at
CATLIN Corporate Office.
Every year, the medical program is reviewed to ensure its effectiveness. Dan Shapiro, PA-C is responsible for this
review. At a minimum, this review consists of:
Records required under this medical surveillance program, consistent with 1910.120(f)(8), are kept accurate
and updated and are available on site at Admin Office.
Respirator fit test and selection
Physician's medical opinion of fitness for duty (pre-placement, periodic, termination)
Physician's medical opinion of fitness for respirator protection (pre-placement, periodicc)
Exposure monitoring results
5 - 2 of 2 Date of Program:Site Name:Cheek Road Grocery
6.0 PERSONAL PROTECTIVE EQUIPMENT
(in compliance with 29 CFR 1910.120(b)(4)(ii)(C) and 29 CFR 1910.120(g))
This chapter of the HASP describes how personal protective equipment (PPE) is used to protect against employee
exposures to hazardous substances and hazardous conditions on this site. Exposure hazards from the decontamination
process are also considered. The following topics are addressed in this chapter:
6.1 PPE Selection Criteria
Site safety and health hazards are eliminated or reduced to the greatest extent possible through engineering controls and
work practices. Where hazards are still present, a combination of engineering controls, work practices, and PPE are used
to protect employees.
* PPE selection criteria
* Site-specific PPE ensembles
* Criteria for PPE upgrades and downgrades
* Procedures for determining work duration
The person with the overall responsibility for the PPE program is CATLIN Project Manager.
An initial level of PPE is assigned to each task to provide an adequate barrier to exposure hazards. Initial PPE ensembles
are selected based on the anticipated route(s) of entry of the hazardous substances on site and their concentration.
Ensemble materials are selected using permeation data supplied by individual manufacturers. Materials providing the
greatest duration of protection have been chosen. Tear and seam strength of the PPE are also considered to ensure
ensemble durability while work is performed. When necessary, multiple layers of protection are used to accommodate
the range of hazards that may be encountered. Where possible, employees are provided with a range of component sizes
to ensure properly fitted PPE.
* Training in use of PPE
* Respiratory protection
* Hearing conservation
* PPE maintenance & storage
* Evaluation of this program
The following criteria are used in selecting PPE levels at this site.
Use of Level D Protection
Employees use Level D protection during tasks that have the following characteristics:
* The atmosphere contains no known or suspected hazardous substances at concentrations that meet or exceed the published
exposure limit.
* Contact with hazardous levels of any chemicals through splashes, immersion, or by other means will not occur.
* There is no potential for unexpected inhalation or contact with hazardous levels of any chemical.
6 - 1 of 5 Date of Program:Site Name:Cheek Road Grocery
6.2 Use of PPE
Site-specific PPE ensembles and materials are identified below in Table 6-2a. These ensembles are consistent with
Appendix B of 29 CFR 1910.120. PPE is used in accordance with manufacturers’ recommendations.
6 - 2 of 5 Date of Program:Site Name:Cheek Road Grocery
Coveralls/Standard Work Clothes
Company Supplied No
Company Supplied No
Level D
Boots/shoes, chemical-resistant steel toe and
shank
Escape Mask: N/A
Table 6-2a Site-Specific PPE Ensembles
Equipment Model Material Employee
Purchased
Safety glasses Company Supplied Plastic No
Hard hat Company Supplied Plastic No
Gloves Company Supplied Leather and other No
6 - 3 of 5 Date of Program:Site Name:Cheek Road Grocery
Criteria for PPE Upgrades and Downgrades
Task-specific criteria for PPE upgrades and downgrades are used at this site. If the need for a PPE upgrade or
downgrade is anticipated for a task or operation, the action level(s) and/or conditions that result in a PPE upgrade or
downgrade are described on the Job Hazard Analysis form (JHA) in Chapter 2 of this HASP. Since PPE is primarily used
as a barrier to hazardous substance exposure, airborne concentrations are monitored routinely, in accordance with
Chapter 7, Exposure Monitoring.
TBD has the authority to upgrade or downgrade PPE in a timely manner to respond to changing site conditions and to protect
employee health and safety. Routine evaluation of the effectiveness of the PPE program is conducted as identified in Section
6.7 below.
Procedures for Determining Work Duration
SSHO identifies task-specific work duration based on the following:
Employees are informed about task-specific work duration by the SSHO, during pre-entry briefing for each task
Work duration is consistent with the requirements outlined in Chapter 8, Thermal Stress and the respiratory protection capacity
for the assigned PPE. Work duration is continuously re-evaluated in response to changes in working conditions.
6.3 Training
Employees receive general training regarding proper selection, use and inspection of PPE during initial HAZWOPER training (or
equivalent) and subsequent refresher training. Site-specific PPE requirements, including task-specific PPE, ensemble
components, cartridge/canister service times, and inspection and maintenance procedures are communicated as identified in
Chapter 4, Training.
6.4 Respiratory Protection
The type of respiratory protection used on site are identified in Table 6-2a. Respiratory protection is selected, fitted, used,
stored and maintained in accordance with CATLIN's Respiratory Protection Program. A copy of the Respiratory Protection
Program is included in Section 12. The written Respiratory Protection Program is consistent with the other requirements of this
HASP.
6.5 Hearing Conservation
Employees must use hearing protection when noise exposures equal or exceed an 8-hour time-weighted average sound level of
85 dBA. Where noise exposure meets or exceeds this level, noise is listed as a physical hazard in the JHA for the
tasks/operation, and hearing protection is included as one of the control measures (PPE). Employees required to use hearing
protection participate in a Hearing Conservation Program. A copy of CATLIN's Hearing Protection Program is included in
Section 12.Currently, no site tasks have noise exposure that equals or exceeds the 85 dBA limit.
6.6 PPE Maintenance Storage
In order to ensure that PPE continues to provide the anticipated protection, this site uses specific procedures for PPE
inspection, cleaning, maintenance, and storage. Adherence to these procedures is tracked with written inspection records.
6.7 Evaluation of PPE Program
Evaluation of the effectiveness of site PPE selections occurs throughout site activities in response to employee exposure
monitoring results and employee feedback. Surface samples are collected from the inside surfaces of used PPE to ensure that
the equipment provides an adequate barrier throughout the work shift. Surface monitoring procedures are described in Chapter
7 of this HASP, Exposure Monitoring.
Mike D. Mason is responsible for modifying initially selected PPE. Affected employees are immediately informed about these
modifications and are provided with additional training if necessary. The JHAs in Chapter 2 of the HASP are also updated as
needed to reflect current information about job hazards and selected controls.
* Physiological requirements of the task
* PPE level for the task
* Ambient temperature and humidity
* Respiratory protection capacity (air supply or cartridge change requirements)
* Chemical protective clothing capacity (permeation rate of on-site materials)
* Acclimatization of the work force
6 - 4 of 5 Date of Program:Site Name:Cheek Road Grocery
6 - 5 of 5 Date of Program:Site Name:Cheek Road Grocery
7.0 EXPOSURE MONITORING
(in compliance with 29 CFR 1910.120(b)(4)(ii)(E) and 29 CFR 1910.120(h))
This chapter of the HASP describes how employee exposures to hazardous substances are monitored. This chapter
provides site-specific information about:
7.1 Air Monitoring
Employee exposures to airborne hazardous substances are fully characterized throughout site operations to ensure that
exposure controls are effectively chosen and modified as needed on a timely basis. The approach to air monitoring is
consistent with OSHA requirements in HAZWOPER and includes:
* air monitoring procedures,
* surface sampling procedures,
* equipment calibration and maintenance, and
* the handling and management of monitoring data.
SSHO is responsible for implementing site exposure monitoring procedures.
* initial monitoring prior to the beginning of site activities to identify conditions that may cause death or serious harm and
to permit preliminary selection of site controls,
-commencement of work on another portion of the site,
The following personnel are qualified to use the air monitoring instruments at this site and to interpret monitoring
results:
The following personnel are qualified to conduct surface sampling at this site and to interpret surface sampling results:
Sean O'Neil
Ben Ashba
Bill Miller
Bill Walsh
Robert Baldwin
Corey Futral
Jason Catlin
Stacey Martin
* personal monitoring after site activities begin so that employee exposures are quantified and fully characterized, and
* periodic monitoring throughout site operations when conditions and employee exposures may change rapidly. This can
include, but is not limited to, the following situations
-exposure to or handling of contaminants/hazards not previously identified,
-commencement of a new task/operation,
-change in environmental conditions, and
-commencement of task/operation that is likely to increase airborne concentrations of hazardous substances.
Monitoring Instrument
Ben Ashba
Bill Miller
Bill Walsh
Corey Futral
Jason Catlin
Robert Baldwin
Sean O'Neil
Stacey Martin
7 - 1 of 3 Date of Program:Site Name:Cheek Road Grocery
7.2 Surface Sampling
Air monitoring is conducted using direct-reading instruments and by collecting and analyzing personal samples. Consistent with
HAZWOPER, personal air samples are collected in the breathing zones of employees expected to have the highest exposure
during the task or operation being evaluated. If exposures for these employees exceed the exposure limits, additional samples
are collected in the breathing zones of all employees likely to have similar exposures. Full-shift and short-term samples are
collected, providing quantitative results that can be compared to OSHA Permissible Exposure Limits and other published
exposure limits. In addition, the results of lab-analyzed samples are correlated with direct-reading monitoring results to ensure
that direct-reading results are interpreted correctly.
If an employees exposure to Benzene or Lead exceed Permissible Exposure LImits established by OSHA, then the employee(s)
shall be notified in writing within 15 working days of receipt of air monitoring results. The employer shall provide air monitoring,
engineering controls, etc. in accordance with 29 CFR 1910.1025 for Lead and 29 CFR 1910.1028 for Benzene if the potential
exposure exists.
Surface sampling is used as needed in contaminated areas to evaluate potential employee exposures. Surface sampling is
used in the CRZ and SZ to evaluate the effectiveness of decontamination methods and exposure controls, including hygiene
practices, and to ensure that zone boundaries accurately reflect the presence or absence of contamination. Surface sample
locations, methods, and permissible contamination limits are listed in Table 7-2.
Table 7-1, Task-Specific Air Monitoring Procedures, summarizes the air monitoring procedures for this site based on tasks and
operations conducted here. This table includes action levels and required actions we have established based on the direct-
reading instruments we use and the contaminants we measure.
This site contains contaminants addressed in one or more of OSHA's substance-specific standards, specifically
BENZENE. Site monitoring procedures comply with OSHA's substance-specific requirements as well as those of
HAZWOPER.
Table 7-1: Task-Specific Air Monitoring Procedures
7.3 Equipment Calibration and Maintenance
Surface concentrations in excess of the established limits may result in adjustments of PPE, decontamination procedures, site
zone boundaries, and other exposure controls. Mike D. Mason is responsible for evaluating surface sampling results and
determining corrective actions if sample results indicate contaminant levels in excess of permissible surface concentration.
Table 7-2 Surface Monitoring Procedures
Table 7-3 Equipment Calibration Maintenance
7.4 Handling and Maintenance of Monitoring Data
Procedures for collecting, handling, and shipping laboratory samples are included Chapter 12, Standard Operating Practices
and in the sampling methods identified in Table 7-1. Documentation procedures for analytical results and direct-reading
monitoring data are also addressed in Chapter 12. Samples are shipped to and analyzed by the laboratory selected by the PM.
Laboratory Name: Con-Test Analytical Laboratory
Addresses: 6104 Westgate Road, Suite 129
Raleigh NC, 27617
Telephone: [phone]
All analytes
Analyte(s)
7 - 2 of 3 Date of Program:Site Name:Cheek Road Grocery
Laboratory results are available within 10 days of sample collection. Employees may review general air and surface monitoring
results and may obtain copies of their personal monitoring results. Results from lab-analyzed samples are stored on site in/at:
Cooler. Direct-reading monitoring results are documented and stored in/at: Field Book.
Employees who participated in an air monitoring event receive written notification of their respective personal exposures within
1 working days of receipt of results. Mike D. Mason is responsible for providing employees with copies of their exposure
monitoring results and helping them understand the information.
7.5 Noise Monitoring
Currently, no site tasks have noise exposure that equals or exceeds the 85 dBA limit so noise monitoring is not conducted.
Laboratory Contact: Adam Phillips
7 - 3 of 3 Date of Program:Site Name:Cheek Road Grocery
8.0 THERMAL STRESS PREVENTION PROGRAM
(in compliance with 29 CFR 1910.120(h))
8.1 Implementation Criteria
This section of the HASP describes how the site-specific environmental conditions (temperature, humidity, air movement), work
loads, and PPE may expose workers to hazards resulting in illness or injury related to heat or cold stress. This Thermal Stress
Prevention Program outlines exposure controls designed to protect workers working in hot or cold environments. The elements
of this program are outlined in this section and include the following:
* Implementation criteria
* Prevention strategies
* Medical management
* Employee training
SSHO is responsible for implementing this program.
The Thermal Stress Prevention Program is implemented when the work area temperature rises above 95 oF WBGT or falls
below 35 oF Wind Chill Adjusted.
Throughout each work shift, air temperatures in the work area are measured, the adjusted temperature is calculated, and
the values are recorded Cell Phones.
8.2 Prevention Strategies
Heat Stress
· defining and adjusting worker work/rest intervals
· monitoring for signs of heat stress
· providing shaded rest areas protected from radiant heat
· using a liquid replacement program
· providing cooling garments or other PPE
Work practices and exposure controls are used to reduce the risk of elevating a worker’s core body temperature.
These work practices and exposure controls include the following:
Work Area Temperature Range PPE Level
Worker Work/Rest Intervals
Table 8-2hb: Heat Stress Work/Rest Schedules
Work/rest intervals are based on PPE, work loads, environmental conditions (temperature, humidity, air movement),
and monitoring results. Work/rest intervals are determined by All Site Workers. Work/rest intervals are adjusted
throughout the work shift as needed and communicated to each worker at the conclusion of an applicable rest period,
prior to reentry into the work zone. Guidelines for work/rest schedules for this site are provided in Table 8-2hb.
Work Period (minutes)Rest Period (minutes)
>95 Level D 30 minutes 5 minutes
Monitoring
We also use physiological monitoring to alert workers and their supervisors to potential heat stress illness.
Physiological monitoring is conducted by the employees themselves. The schedule and approach to physiological
monitoring at this site is described in Table 8-2hc.
Workers monitor each other’s actions, speech, and appearance for signs and symptoms of heat-related illnesses
including heat exhaustion and heat stroke. Physical signs and symptoms of heat exhaustion include headache,
nausea, vertigo, weakness, thirst, and giddiness. Heat exhaustion may progress to heat stroke if a worker is unable
to cool and re-hydrate their body. The primary signs and symptoms of heat stroke are confusion; irrational behavior;
loss of consciousness; convulsions; a lack of sweating (usually); hot, dry skin; and an abnormally high body
temperature. Workers should be aware of the key differences between the signs and symptoms of heat stroke and
those of heat exhaustion, such as the lack of sweating, the color of the skin (red), and the rise in body temperature.
Heat stroke is a medical emergency that requires immediate medical attention.
Physical signs and symptoms of heat stress are discussed with workers Daily and reviewed as necessary.
8 - 1 of 4 Date of Program:Site Name:Cheek Road Grocery
Type of monitoring Monitoring Location
Table 8-2hc Heat Stress Physiological Monitoring Procedures
Monitoring Frequency Action Level Required Action
Heart rate (pulse)on-site when needed
Visual on-site Before and after each
work period
Rest Areas
Rest areas that are shaded and protected from radiant heat are located:
company vehicles
Rest areas are equipped with cool (50?- 60?F) liquids.
Work Area Temperature Range Work Period Between Drinks
Liquid Replacement Program
Table 8-2hd Heat Stress Liquid Replacement Regimen
Minimum Quantity (Ounces)Liquid Type
Since dehydration is a primary cause of heat illness, workers on this site follow a regimen for liquid consumption
detailed in Table 8-2hd.
>95 30 minutes 1 cup (8 oz.)Water
>95 30 minutes 1 cup (8 oz.)Sports drink
Work Area Temperature Range Task/Location
Use of Cooling Garments:
Table 8-2hf: Use of Cooling Garments
PPE Level Cooling Garment Used
Cooling garments are provided for workers to reduce the risk of heat related illnesses and injuries. Workers don the
appropriate cooling garment based on the guidelines provided in Table 8-2hf.
>95 Receptor Survey -- within
1,500 feet of the site
Level D Air circulation
>95 Gauge and Sample Wells --
Subject Site
Level D Air circulation
Cold Stress
· defining and adjusting worker work/rest intervals
· monitoring for physiological signs of cold stress
· providing warm, sheltered rest areas
· providing warm liquids
· providing and requiring the use of warm garment or other PPE
Work practices and exposure controls are used to reduce the risk of lowering a worker’s core body temperature.
These work practices and exposure controls include the following:
Worker Work/Rest Intervals
Work/rest intervals are based on PPE, work load, environmental conditions, and monitoring results.
Work/rest intervals are determined by All Site Workers and communicated to workers. Work/rest
intervals are adjusted throughout the work shift as needed and communicated to each worker at the
conclusion of an applicable rest period, prior to reentry into the work zone. Guidelines for work/rest
schedules for this site are provided in Table 8-2ca. Resting workers are sheltered in a warm
enclosure.
8 - 2 of 4 Date of Program:Site Name:Cheek Road Grocery
8.3 Medical Management
If a worker exhibits signs or symptoms of heat exhaustion or heat stroke, we use the following procedures:
* site person in shade
* cool wrap on head
* get liquids in person
* get person ice
* contact 911 if needed
The physician's written opinion specifically addresses fitness for duty for under heat stress conditions. This evaluation is
described in Chapter 5, Medical Surveillance.
8.4 Training
Work Area Temperature Range PPE Level
Table 8-2ca: Cold Stress Work/Rest Schedules
Work Period (minutes)Rest Period (minutes)
<35 Level D 30 minutes 5 minutes
Monitoring
Workers monitor each other’s actions, speech, and appearance for signs and symptoms of cold-
related injury including hypothermia and frostbite. The first symptoms of hypothermia are
uncontrollable shivering and the sensation of cold. Cool skin, muscle rigidity, low blood pressure,
slowed or irregular pulse and apparent exhaustion and fatigue after rest manifest as hypothermia
progresses and the core body temperature falls. Frostbite can occur without hypothermia when
extremities do not receive sufficient heat from central body stores. Frostbite occurs when the fluids
around the tissue cells freeze and usually affects the extremities, nose, and cheeks. Damage from
frostbite can result in tissue death.
Physical signs and symptoms of hypothermia and frost bite are discussed with workers Daily and
reviewed as necessary.
Warm Shelters
Warm, non-caffeinated liquids are provided in each rest area.
Worker rest areas are warm and isolated from environmental conditions. These rest areas are located at vehicles.
Work Area Temperature Range Work Period Between Drinks
Liquid Replacement Program:
Table 8-2cb Cold Stress Liquid Replacement Regimen
Minimum Quantity (Ounces)Liquid Type
Dehydration through perspiration is a concern in cold weather. Workers on this site follow the liquid
replacement regimen in Table 8-2cb.
<35 30 minutes 1 cup (8 oz.)Water
Work Area Temperature Range Task/Location
Use of Cold Temperature Clothing:
Table 8-2cc Use of Cold Temperature Clothing
PPE Level Cold Temperature Clothin
Workers don layered thermal protective clothing based on the guidelines provided in Table 8-2cc.
<35 Receptor Survey -- within
1,500 feet of the site
Level D Insulated clothing
<35 Gauge and Sample Wells --
Subject Site
Level D Insulated clothing
Physical signs and symptoms of heat stress are discussed with workers <35 and reviewed as
necessary.
8 - 3 of 4 Date of Program:Site Name:Cheek Road Grocery
Workers receive general training regarding thermal stress-related injuries and illnesses during initial HAZWOPER training and
subsequent refresher training. The site-specific program and procedures are described in Chapter 4, Training.
8 - 4 of 4 Date of Program:Site Name:Cheek Road Grocery
9.0 SPILL CONTAINMENT PROGRAM
(in compliance with 29 CFR 1910.120(b)(4)(ii)(J) and (j)(1)(viii))
This chapter of the Health and Safety Plan describes the potential for hazardous substance spills at this site and
procedures for controlling and containing such spills. The purpose of this chapter of the Plan is to ensure that spill
containment planning is conducted and appropriate control measures are established.
The spill containment program is consistent with OSHA requirements in 29 CFR 1910.120(b)(4)(ii)(J) and (j)(1)(viii) and
addresses the following site-specific information:
* potential hazardous substance spills and available controls
* initial notification and response
* spill evaluation and response
* post-spill evaluation
9.1 Potential Spills and Available Controls
Table 9-1 below lists the location and type of potential hazardous substance spills at this site. This table also describes the
activities or situations in which an accidental spill could occur and the type of release--either an incidental or an emergency
release -- likely to result.
Wherever spills, leaks, or ruptures can occur, this site keeps suitable quantities of proper absorbent and US Department of
Transportation-specified salvage drums/containers. Their location is noted in Table 9-1. In addition, all areas subject to
potential spills are diked or a means to adequately dike these areas in the event of a spill is available so that the entire
volume of the hazardous substance being spilled can be contained and isolated. The type and location of spill
containment equipment is also listed in Table 9-1.
Table 9-1 Potential Spills and Controls
9.2 Initial Spill Notification and Response
9.3 Spill Evaluation and Response
Any worker who discovers a hazardous substance spill will immediately notify (name/title). The worker will, to his/her best ability,
report the hazardous substance involved, the location of the spill, the estimated quantity of material spilled, the direction/flow of
the spill material, related fire/explosion incidents, and any associated injuries. The site Emergency Response Plan, found in
Chapter 11 of this HASP, will immediately be implemented if an emergency release has occurred.
(Name/title) is responsible for evaluating spills and determining the appropriate response. When this evaluation is being made,
the spill area will be isolated and demarcated to the extent possible.
Table 9-3 Off-site Notification Requirements
Location
Spill Volume/
Conditions Required Notification
The procedures of the Emergency Response Chapter of this HASP are implemented when the spill is determined to
require emergency precautions and action. If necessary to protect nearby community members, notification of the
appropriate authorities is made. Table 9-3 below lists the spill conditions that trigger notification of Federal, state, and
local agencies.
When an incidental release occurs, cleanup personnel receive instructions in a pre-cleanup meeting as to spill conditions,
PPE, response activities, decontamination, and waste handling. The following are general measures that response/
cleanup personnel take when responding to a spill:
Hazardous Substance
* To minimize the potential for a hazardous spill, hazardous substance and contaminated soils, control/absorbent
media, drums and containers, and other contaminated materials are properly stored and labeled.
9 - 1 of 2 Date of Program:Site Name:Cheek Road Grocery
9.4 Post-Spill Evaluation
A written spill response report is prepared at the conclusion of clean-up operations. The report includes, at a minimum,
the following information:
* date of spill incident
* cause of incident
* spill response actions
* any outside agencies involved, including their incident reports
* lessons learned or suggested improvements
The spill area is inspected to ensure the area has been satisfactorily cleaned. The use of soil, water, and air sampling is
utilized in this determination as necessary. The root cause of the spill is examined and corrective steps taken to ensure
the engineering and control measures in place have performed as required. If alternative precautions or measures are
needed, they are made available and implemented.
All durable equipment placed into use during cleanup activities is decontaminated as specified in the Decontamination
chapter of this HASP for future utilization. All spill response equipment and supplies are replenished as required.
* When a spill occurs, only those persons involved in overseeing or performing spill containment operations will be
allowed within the designated hazard areas. If necessary, the area will be roped, ribboned or otherwise blocked off.
Unauthorized personnel are kept clear of the spill area.
* Appropriate PPE, as specified during the pre-cleanup meeting, is donned before entering the spill area.
* Appropriate spill control measures are specified in the pre-cleanup meeting and applied during spill response.
* Whenever possible without endangerment of personnel, the spill is stopped at the source or as close to the source
as possible.
* Ignition points are removed if fire or explosion hazards exist.
* Surrounding reactive materials are removed.
* Drains or drainage in the spill area will be blocked or surrounded by berms to exclude the spilled waste and any
materials applied to it.
* Provisions are made to contain and recover a neutralizing solution, if used.
* Small spills or leaks from a drum, tank, or pipe will require evacuation of at least __ feet in all directions to allow
cleanup and to prevent employee exposure. For small spills, sorbent materials such as sand, sawdust, or
commercial sorbents (see Table 9-1 above for site-specific sorbent media) are placed directly on the waste to
prevent further spreading and aid in recovery.
* If any spill is large and/or continuing, an initial isolation area of at least __ feet in all directions is used. Large spills
are diked at the leading edge of the spill. Berms of earthen or sorbent material are constructed downstream of the
leading edge of the spill to contain it. Where feasible, pumps are utilized to transfer the liquid to appropriate
containers.
* Spill area is sprayed with appropriate foam where the possibility of volatile emissions exist.
* If the spill results in the formation of a toxic vapor cloud, from vaporization, or reaction with surrounding materials
or by the outbreak of fire, further evacuation may be required.
* To dispose of spill waste, all contaminated sorbents, liquid waste, or earthen material will be cleaned up and
placed in small quantities (__ pounds) in approved drums for proper storage or disposal as hazardous waste.
9 - 2 of 2 Date of Program:Site Name:Cheek Road Grocery
10.0 DECONTAMINATION
(in compliance with 29 CFR 1910.120(b)(4)(ii)(G) and 1910.120(k))
* the location and type of site decontamination facilities
* general and specific decontamination procedures for personnel and PPE
* general and specific decontamination procedures for equipment
On-site field personnel oversees implementation of site decontamination procedures and is responsible for ensuring their
effectiveness.
Based on the nature of the hazards and duration of work, showers and change rooms are not necessary and are not provided for
workers.
The decontamination section of the Health and Safety Plan describes how personnel and equipment are decontaminated when
they leave the Exclusion Zone. This section also describes how residual waste from decontamination processes is disposed.
The site decontamination procedures are designed to achieve an orderly, controlled removal or neutralization of contaminants
that may accumulate on personnel or equipment. These procedures minimize worker contact with contaminants and protect
against the transfer of contaminants to clean areas of the site and off-site. They also extend the useful life of PPE by reducing
the amount of time that contaminants contact and can permeate PPE surfaces. The decontamination procedures described
below are designed to meet the requirements of 1910.120(k) and include site-specific information about:
* disposal of residual waste from decontamination
* monitoring the effectiveness of decontamination procedures
* decontamination equipment and solvents
10.1 Site Decontamination Facilities
10.2 Decontamination Procedures for Personnel and PPE
Decontamination procedures on this site are designed for the level of PPE used. Site-specific procedures for personnel and PPE
decontamination minimize the potential for hazardous skin or inhalation exposure and to avoid cross-contamination and
chemical incompatibilities.
Decontamination on this site is conducted in the contamination reduction zone (CRZ). The CRZ acts as a buffer between the hot-
zone and the support zone. The location and design of decontamination stations minimize the spread of contamination beyond
these stations. Separate facilities are used for personnel and for equipment. The location of these facilities is marked on Figure
3-1.
The following are general decontamination procedures established and implemented at this site. More specific procedures for
personnel and PPE decontamination are provided in Table 10-2.
Emergency decontamination procedures are detailed in the Emergency Response section of this HASP.
Decontamination is required for all workers exiting a contaminated area. Personnel may re-enter the Support Zone
only after undergoing the decontamination procedures described below in the next section.
1.
Protective clothing is decontaminated, cleaned, laundered, maintained and/or replaced as needed to ensure its
effectiveness.
2.
PPE used at this site that requires maintenance or parts replacement is decontaminated prior to repairs or service. 3.
PPE used at this site is decontaminated or prepared for disposal on the premises. Personnel who handle
contaminated equipment have been trained in the proper means to do so to avoid hazardous exposure.
4.
This site uses an off-site laundry for decontamination of PPE. The site has informed that facility of the hazards
associated with contaminated PPE from this site.
5.
The site requires and trains workers that if their permeable clothing is splashed or becomes wetted with a
hazardous substance, they will immediately exit the work zone, perform applicable decontamination procedures,
shower, and change into uncontaminated clothing.
6.
Procedures for disposal of decontamination waste meet applicable local, State, and Federal regulations. 7.
10 - 1 of 3 Date of Program:Site Name:Cheek Road Grocery
Tables 10-2a and -2b lists site-specific procedures for personnel decontamination and handling of personnel decontamination
waste.
Table 10-2a Level D Storage & Cleaning Procedures
Stored in vehicles prior to use
10.3 Decontamination Procedures for Equipment
All tools, equipment, and machinery from the Exclusion Zone or CRZ are decontaminated in the CRZ prior to removal to the
Support Zone. Equipment decontamination procedures are designed to minimize the potential for hazardous skin or inhalation
exposure and to avoid cross-contamination and chemical incompatibilities.
Level D Storage Procedures:
Throw away nitrile gloves, store safety glasses, saftey vests and hard hats in vehicle
Level D Cleaning Procedures:
Other Level D Special Handling Requirements:
General Equipment Decontamination Procedures:
Tables 10-3a and -3b lists site-specific procedures for equipment decontamination and handling of equipment decontamination
wastes.
Type of Equipment Decontamination Solution Decontamination Procedure
The following are general equipment decontamination procedures established and implemented at this site. More specific
procedures for equipment decontamination are provided in Table 10-3a and 10-3b.
Table 10-3b Waste Handling for Equipment Decontamination
Table 10-3a Equipment Decontamination Procedures
Decontamination is required for all equipment exiting a contaminated area. Equipment may re-enter the Support
Zone only after undergoing the equipment decontamination procedures described in the table below (Table 10-3, Site-
specific Equipment Decontamination Procedures).
1.
Vehicles that travel regularly between the contaminated and clean areas of the site are carefully decontaminated each
time they exit the Exclusion Zone and the effectiveness of that decontamination is monitored to reduce the likelihood
that contamination will be spread to other parts of the site.
2.
Particular attention is given to decontaminating tires, scoops, and other parts of heavy equipment that are directly
exposed to contaminants and contaminated soil.
3.
Sampling equipment Tap water
Soap
Water or liquid rinse using pressurized or gravity flow
Water or liquid rinse using pressurized or gravity flow
Waste Streams/Products for Equipment Disposal Procedures for Waste Stream/Product
Table 10-2b Waste Handling for Personnel Decontamination
disposable bailers throw away
nitrile gloves throw away
water level indicater decon on-site near well
Waste Streams/Products
for Equipment
Disposal Procedures for
Waste Stream/Product
water spread on-site
10 - 2 of 3 Date of Program:Site Name:Cheek Road Grocery
10.4 Monitoring the Effectiveness of Decontamination Procedures
Visual examination and sampling are used to evaluated the effectiveness of decontamination procedures, in compliance with 29
CFR 1910.120(k)(2)(iv). Visual examination is used to ensure that procedures are implemented as described and that they
appear to control the spread of contaminants under changing site conditions. Visual examination is also used to inspect for signs
of residual contamination or for contaminant permeation of PPE.
Sampling, both air sampling and surface sampling, are used to verify the effectiveness of decontamination. Air samples are
taken in the clean zone to ensure that airborne contaminants have not spread to clean areas of the site. Surface samples are
taken from the inside surfaces of PPE, from decontaminated heavy equipment, and from surfaces within clean areas of the site to
ensure that site decontamination and control procedures are performing as anticipated. The type and frequency of air and
surface sampling used to ensure the effectiveness of decontamination procedures are detailed in the Exposure Monitoring section
of this HASP.
Personnel who work in contaminated areas of the site, either the Contamination Reduction Zone (CRZ) or the Exclusion Zone,
are trained in the principles and practices of decontamination described in this section of the HASP and in related SOPs. If site
procedures are changed as a results of inspection and monitoring, all affected employees are notified of these changes.
Results of the inspections of decontamination procedures and documentation of any action taken to correct deficiencies are
recorded and stored at Field Book .
10 - 3 of 3 Date of Program:Site Name:Cheek Road Grocery
11.0 EMERGENCY RESPONSE PLAN
(in compliance with 29 CFR 1910.120(l) and 1910.120(b)(4)(ii)(H)
This is the site-specific emergency response plan. This chapter of the Health and Safety Plan describes potential
emergencies at this site, procedures for responding to those emergencies, roles and responsibilities during emergency
response, and training that workers must receive in order to follow emergency procedures. This plan also describes the
provisions this site has made to coordinate its emergency response planning with other contractors on site and with off-site
emergency response organizations.
11.1 Pre-emergency Planning
This site has been evaluated for potential emergency occurrences, based on site hazards, the tasks within the work plan, the
site topography, and prevailing weather conditions. The results of that evaluation are shown in Table 11-1 below.
This emergency response plan is consistent with the requirements of 29 CFR 1910.120(l) and provides the following site-
specific information:
* pre-emergency planning
* personnel roles, lines of authority, and communication
* emergency recognition and prevention
* safe distances and places of refuge
* site security and control
* evacuation routes and procedures
* decontamination procedures
* emergency medical treatment and first aid
* emergency alerting and response procedures
* critique of response and follow-up
* PPE and emergency equipment
Table 11-1 Potential Site Emergencies
Type of Emergency Source of Emergency Location of Source
11.2 On-Site Emergency Response Equipment
Emergency procedures may require specialized equipment to facilitate worker rescue, contamination control and reduction,
or post-emergency clean-up. Emergency response equipment stocked on this site is listed in Table 11-2. The equipment
inventory and storage locations are based on the potential emergencies described in Table 11-1. This equipment inventory is
designed to meet on-site emergency response needs and any specialized equipment needs that off-site responders might
require because of the hazards at this site but not ordinarily stocked.
Any additional PPE required and stocked for emergency response is also listed in Table 11-2 below. During an emergency,
the Emergency Response Coordinator is responsible for specifying the level of PPE required for emergency response. At a
minimum, personal protective equipment used by emergency responders will comply with Chapter 6, Personal Protective
Equipment, of this HASP.
During the development of this emergency response plan, local, state, and federal agency disaster, fire, and emergency
response organizations were consulted to ensure that this plan is compatible and integrated with the plans of those
organizations. Documentation of the dates of these consultations and the names of individuals contacted is kept at Field
Book.
Emergency response equipment is inspected at regular intervals and maintained in good working order. The equipment
inventory is replenished as necessary to maintain response capabilities.
Collision (person/equipment or
equipment/equipment)
Operator error Vehicles
Lightning Weather outside
High winds - microbursts Weather outside
Hurricane Weather outside
Heat stress/worker collapses employee outside
11 - 1 of 8 Date of Program:Site Name:Cheek Road Grocery
Table 11-2 Emergency Equipment and Emergency PPE
Emergency Equipment Specific Type Location StoredQuantity Stocked
Emergency PPE Specific Type Location StoredQuantity Stocked
Decontamination solution unknown one each vehicle
First aid kit unknown one each vehicle
Fire extinguisher unknown one each vehicle
Water unknown varies each vehicle
Gloves nitrile at least one box each vehicle
Eye protection unknown varies each vehicle
11 - 2 of 8 Date of Program:Site Name:Cheek Road Grocery
11.3 Emergency Planning Maps
11.4 Roles and Responsibilities for On-Site and Off-Site Personnel
TBD is responsible for implementing the emergency response plan and coordinates emergency response activities on this
site. He/she provides specific direction for emergency action based upon information available regarding the incident and
response capabilities and initiates emergency procedures, including protection of the public and notification of appropriate
authorities.
In the event of an emergency, site personnel are evacuated and do not participate in emergency response activities. As a
result, this emergency response plan is designed to comply with 29 CFR 1910.38. The on-site personnel and their alternates
responsible for coordinating site evacuation efforts are listed in Table 11-4. The emergency response coordinator or one of
his/her alternates is on site whenever work operations are underway.
The site relies upon the off-site emergency response organizations listed in the Emergency Contact Information, Table 11-4,
to respond to site emergencies. These organizations have been provided a copy of the site HASP, have been thoroughly
briefed on site operations, hazards, and potential emergencies; have participated in a site walk-through if necessary; and are
appropriately trained, staffed, and equipped to provide emergency response to this site. These organizations are contacted
at least semi-annually or when changes in operations or hazards occur on site to verify the accuracy of phone numbers and
contact names and to ensure that current points of contact are aware of site operations and hazards.
If evacuation notice is given, site workers leave the worksite with their respective buddies, if possible, by way of the
nearest exit. Emergency decontamination procedures detailed in Chapter 10 of this HASP are followed to the extent
practical without compromising the safety and health of site personnel.
Appropriate primary and alternate evacuation routes and assembly areas have been identified and are shown on the
Emergency Response Map Fig 3-1. The routes and assembly area will be determined by conditions at the time of the
evacuation based on wind direction, the location of the hazard source, and other factors as determined by rehearsals
and inputs from emergency response organizations.
11.5 Emergency Alerting and Evacuation
Wind direction indicators are located so that workers can determine a safe up wind or cross wind evacuation route and
assembly area if not informed by the emergency response coordinator at the time the evacuation alarm sounds.
Contractors and subcontractors on this site have coordinated their emergency response plans to ensure that these
plans are compatible and that source(s) of potential emergencies are recognized, alarm systems are clearly
understood, and evacuation routes are accessible to all personnel relying upon them.
11.6 Emergency Response
The Emergency Response Team Leader, after investigating the incident and reviewing relevant information, determines the level of
response required for containment, rescue, medical care and clean-up. The emergency response team is mobilized to the incident
site and supplied with sufficient members, PPE, and emergency equipment.
When the Team Leader determines that on-site emergency response is inadequate for the emergency or that outside assistance is
needed or otherwise required, the applicable off-site organization shown in Table 11-4 is contacted. The Emergency Response
Personnel exiting the site gather at a designated assembly point. To determine that everyone has successfully exited
the site, personnel will be accounted for at the assembly site. If any worker cannot be accounted for, notification is
given to TBD so that appropriate action can be initiated.
Figure 3-1 provides a map of the site with key on-site emergency planning information clearly marked. Emergency evacuation
route(s), places of refuge, assembly point(s), and the locations of key site emergency equipment are identified on this map, if
applicable. Site zone boundaries are shown to alert responders to known areas of contamination, if known. Figure 3-1is posted at
site entry points and at locations throughout the work site.
Figure 11-3b indicates the route to the nearest emergency medical assistance. Figure 11-3b is posted at the following
locations:
Field Book
Upon discovering an emergency situation, personnel notify TBD, who will evaluate available information and initiate
response. Site workers are alerted to emergencies through the use of an employee alarm system. The employee
alarm systems at this site are listed in Table 11-5.
Type of Alarm Location How Alarm is Used
Table 11-5 Employee Alarm Systems
CATLIN Employee on-site verbal
This alarm system meets the requirements of 29 CFR 1910.165 and is tested (frequency) under normal site operating
conditions to ensure that it is in good working order and can effectively alert all persons on-site. A log of alarm tests is
kept by TBD.
11 - 3 of 8 Date of Program:Site Name:Cheek Road Grocery
This site has At least once workers with current first aid certification assigned to provide first aid during each shift. Because of this
practice, the site has an exposure control plan in accordance with OSHA's bloodborne pathogens standard, 1910.1030 (c)(1)(i).
The site also offers Hepatitis B vaccinations to workers who are assigned to provide first aid. A record of those vaccinations or the
employee's declination of the vaccination is kept in her/his medical records file.
Team Leader provides relevant information to the responding organizations, including hazards associated with the emergency
incident, potential containment problems, and missing site personnel.
11.7 Emergency Medical Treatment and First Aid
Personnel who require medical care and/or who are transferred to a medical facility are accompanied by MSDSs and other
applicable hazard data to apprise caregivers of the chemicals and hazards to which the victim has been potentially exposed. The
emergency medical care facility for this site is Duke University Hospital. The route to the facility is shown in Figure 11-3b.
11.8 Emergency Response Critique and Plan Updates
This emergency response plan is evaluated periodically throughout site operations and updated for accuracy. Changes made to
emergency response procedures as the result of rehearsals or actual response incidents are recorded in this Plan. Site workers
receive notification and training on changes to the Plan by Weekly field crew meetings weekly.
11.9 Emergency Response Training
All persons who enter this worksite, including visitors, receive a site-specific briefing about anticipated emergency situations
and the emergency procedures.
This site relies on off-site organizations for emergency response (see Table 11-4), the training of personnel in those off-site
organizations has been evaluated and is deemed adequate for response to this site.
Site personnel are trained to evacuate in a safe and orderly manner in accordance with 29 CFR 1910.38. Workers do not
participate in emergency response rehearsals at this site.
After every emergency incident or evacuation of this site, Mike D. Mason or Project Manager will evaluate the quality and safety of
response activities. Any deficiencies in response actions will be included in a specific follow-up plan and corrected.
11 - 4 of 8 Date of Program:Site Name:Cheek Road Grocery
11 - 5 of 8 Date of Program:Site Name:Cheek Road Grocery
Table 11-4 Emergency Contact Information
SITE PERSONNEL
OUTSIDE ASSISTANCE
Title Contact Telephone
Agency Contact TelephoneAddress/Location
Project Manager (PM)Sean O'Neil 9195394403
Site Safety and Health Officer (SSHO)TBD 9104525861
Emergency Response Coordinator (ERC)TBD 9104525861
Site Supervisor TBD 9104525861
Emergency Response Coordinator 1st Alternate 9104525861
Emergency Response Coordinator 2nd Alternate 9104525861
Subcontractor:TBD
Ambulance/EMS 911
Police 911
Fire 911
National Reponse Center 800-424-8802
State Police 911
Local Emergency Response
Agency
911
Emergency Medical
Assistance
On-site Staff 2301 Erwin Rd, Durham, NC 27710 9196848111
Poison Control Center
Secondary Medical Facility
Poison Control Center (your state
agency #)
State Authority
Center for Disease Control
Chemtrec 800-424-9300
The list of telephone numbers below are the emergency contact numbers for this site. These emergency numbers are
verified to be accurate, working numbers. Site personnel are trained and rehearsed in site-specific emergency calling
procedures. A copy of this contact information is posted at the following locations:
Site Field Book
11 - 6 of 8 Date of Program:Site Name:Cheek Road Grocery
Figure 11-3a Emergency Planning Map
Insert emergency planning map here.
11 - 7 of 8 Date of Program:Site Name:Cheek Road Grocery
Insert map of driving route to Emergency Medical Assistance.
Figure 11-3b Driving Route to Emergency Medical Assistance
11 - 8 of 8 Date of Program:Site Name:Cheek Road Grocery
5/3/2021 5801 Cheek Rd, Durham, NC 27704 to 2301 Erwin Road, Durham, NC - Google Maps
https://www.google.com/maps/dir/5801+Cheek+Rd,+Durham,+NC+27704/2301+Erwin+Road,+Durham,+NC/@36.0184679,-78.8906551,13z/am=t/dat…1/2
Map data ©2021 1 mi
Durham, NC 27704
5801 Cheek Rd
1.Head south toward Cheek Rd
2.Turn right onto Cheek Rd
Continue on Carpenter Rd to E Club Blvd
3.Turn right onto Carpenter Rd
4.Turn left onto Ferrell Rd
Take I-85 S to your destination in Durham
5.Continue onto E Club Blvd
6.Turn left to merge onto I-85 S
5 s (89 ft)
4 min (2.6 mi)
3 min (1.8 mi)
1.1 mi
0.7 mi
11 min (7.1 mi)
0.4 mi
5.1 mi
Drive 11.6 miles, 21 min5801 Cheek Rd, Durham, NC 27704 to 2301 Erwin
Road, Durham, NC
5/3/2021 5801 Cheek Rd, Durham, NC 27704 to 2301 Erwin Road, Durham, NC - Google Maps
https://www.google.com/maps/dir/5801+Cheek+Rd,+Durham,+NC+27704/2301+Erwin+Road,+Durham,+NC/@36.0184679,-78.8906551,13z/am=t/dat…2/2
These directions are for planning purposes only.
You may nd that construction projects, trac,
weather, or other events may cause conditions to
differ from the map results, and you should plan
your route accordingly. You must obey all signs or
notices regarding your route.
Durham, NC 27705
7.Use the right 2 lanes to take exit 174B for
Hillandale Rd
8.Use the left 2 lanes to turn left onto Hillandale Rd
9.Continue straight onto Fulton St
10.Continue straight
Destination will be on the right
2301 Erwin Rd
0.2 mi
1.1 mi
0.4 mi
1 min (344 ft)
12.0 Standard Operating Procedures (SOPs)
(in compliance with 29 CFR 1910.120(b)(1)(ii))
Work at this site will be conducted in accordance with the following SOPs, which have been attached for reference.
Sun Exposure 1.
Fire Safety 2.
Snakes, Insects and Plants 3.
Well Gauging 4.
Hand Tools 5.
Well Sampling 6.
Hearing Conservation Program 7.
12 - 1 of 1 Date of Program:Site Name:Cheek Road Grocery

Sun Exposure SOP
Information for both on and off the job.
1. By far, the most common cause of skin cancer is overexposure to the sun.
Ninety percent of all skin cancers occur on parts of the body that usually are not
covered by clothing. 2. People who sunburn easily and have fair skin with red or blond hair are most prone to develop skin cancer. The amount of time spent in the sun also affects a person’s risk of skin cancer.
3. To reduce the risk of skin cancer:
a. Cover up with a wide-brimmed hat and a bandanna for your neck. Wear long-sleeved shirts and pants that the sun cannot penetrate. b. Use sunscreens to help prevent skin cancer as well as premature aging of your skin.
Use a Sun Protective Factor (SPF) rating of 15 or higher. Women may receive
added protection by using tinted opaque cosmetic foundation along with a sunscreen. Apply sunscreen at least an hour before going into the sun and again after swimming or perspiring a lot. Do not use indoor sunlamps, tanning parlors, or tanning pills.
c. You can still get burned on a cloudy day. Try to stay out of the direct sun at
midday, because sunrays are the strongest between 10 a.m. and 3 p.m. Beware of high altitudes – where there is less atmosphere to filter out the ultraviolet rays. Skiers should remember that snow reflects the sun’s rays, too. 4. Know your skin. Whatever your skin type, do a monthly self-examination of
your skin to note any moles, blemishes or birthmarks. Check them once a month
and if you notice any changes in size, shape or color, or if a sore does not heal, see your physician without delay.
SAFE OPERATING PROCEDURES
Fire Safety/Fire Extinguisher
Buildings
1. All employees should know escape routes and locations of fire exits.
2. All fire exits must be unobstructed, unlocked and marked.
3. Fire/smoke alarms should be tested and fire drills conducted regularly.
4. All employees should know the location of and selected employees know how
to use fire extinguishers. Employee training of fire extinguisher use is required
prior to use.
5. Facilities should be periodically inspected to ensure fire extinguishers are
charged and to identify and eliminate fire hazards. Fire extinguisher locations
should be properly marked.
6. Wiring and/or extension cords used for office machines or other appliances
should be checked periodically. Job Sites
1. When refueling vehicles, turn off engines. No smoking or open flames are
permitted in the area.
2. Use extra caution when working with flammable materials on job site. Refer to
MSDS.
3. Use only approved marked safety containers for storing and transporting
flammable materials.
4. After refueling portable tools/equipment with gasoline engines, move at least
25 feet from refueling site to start engine.
5. Operator should know the location of and how to use the fire extinguishers.
Fire extinguishers should be inspected monthly to ensure that they are charged.
6. Allow space for fuel expansion in fuel tanks and containers.

SAFE OPERATING PROCEDURES
Poisonous Snakes, Insects and Plants SOP
Like most accidents and injuries, prevention is important in controlling hazards from
poisonous snakes, insects and plants. Therefore, each employee should review the work
activities planned to determine what exposures might exist. Efforts should then be made
to minimize situations, which might result in a snakebite, insect sting or exposure to
poisonous plants. Employees should also avoid wearing bright clothes, perfumes, after-
shaves, etc., to help minimize attraction of snakes or insects. Snakes 1. Employees should wear work boots, long pants and long sleeved shirts when going into hazardous areas. 2. Employees should make as much noise as possible when approaching a
possible snake area to give the snake time to leave.
3. Employees should be equipped with a bush axe for clearing underbrush and for protection. 4. Employees should avoid reaching or stepping into hidden areas whenever possible.
5. If a snakebite should occur, the employee should:
a) Remain as calm as possible. b) Move away from the snake. c) Apply a constricting bandage (not tourniquet) between the wound and heart. A finger should be able to pass under it. Apply ice to bite area, if available.
d) Allow a fellow worker to transport him/her to closest medical facility.
e) If possible, kill the snake and carry to medical facility for identification. 6. Under no circumstances should incisions and suction be used to treat a snakebite unless: a) The victim is over 1.5 hours from medical assistance, and
b) The person administering first aid has received advanced training in medical
assistance such as First Responder, EMT, etc. Insect Stings Employees should: 1. Wear appropriate clothing. 2. Avoid areas where insects might be whenever possible. 3. Schedule work in infested areas during the cool months.
4. Avoid high smelling after-shaves, colognes, etc., that may attract insects. 5. Use an insect repellent. 6. If a sting does occur, any stinger should be removed with a knife blade or fingernail. The area should then be treated with Hydrocortisone.

Ticks
Ticks are especially important to pay attention to because of the possibility of Rocky
Mountain Spotted Fever of Lyme Disease.
To minimize exposure, employees should follow these guidelines:
1. Wear appropriate clothing when working in wooded area. 2. Check yourself at least twice a day, paying particular attention to the hair, neck, and groin area. 3. Use a Tick Repellent.
4. Notify your supervisor if a tick is found and request that the date and condition
(i.e. attached? crawling?) be noted for future reference. (If possible retain engorged ticks and place in a container for identification of the tick type by a CATLIN preferred provider.) 5. Call your CATLIN preferred provider if fever, chills, headaches or muscle
aches develop within 3-10 days after exposure. In some cases, a rash may
develop on the wrists and ankles 1-3 days after the fever begins.

Poisonous Plants
CATLIN employees have exposure to at least three types of poisonous plants: poison oak,
poison ivy and poison sumac. Reactions range from mild (very little or none) to severe
(rash and blisters). Employees who have no reaction may not have become sensitized, but
once they are, future exposures can result in an allergic reaction. To avoid problems with poisonous plants, employees should:
1. Avoid working in severely infested areas if at all possible. (Learn what the plants look like.) 2. Wear long sleeve shirts, long pants, and work gloves. If you are performing clearing activities with either hand (e.g. bush axes, machetes, etc.) or powered tools use eye goggles/Safety glasses to prevent poisonous plants from entering
your eyes. 3. Use silicone protective or other barrier creams where available. 4. Make sure that any clothes or shoes that may have been exposed receive thorough washing. Leftover oils on anything could cause a reaction even days
later.
5. If a severe reaction develops, contact your CATLIN preferred provider for possible treatments. 6. Avoid rubbing your eyes if you have been in contact with poisonous plants.

SOP - WELL GAUGING 1 of 6 Revised February 2009
CATLIN STANDARD OPERATING PROCEDURES
WELL GAUGING
1. PURPOSE AND SCOPE:

This document outlines CATLIN’s Standard Operating Procedure for determining depth to groundwater and measurement to product (if present) in a monitoring well. The document details gauging with an electronic water level indicator (probe) as well as using a metal engineering tape with free-phase product and water finding paste.
Please note that free-phase product is considered by CATLIN to be synonymous with Light Non-Aqueous Phase Liquids as it relates to this document. Based on previously determined top-of-casing elevations, these measurements may ultimately be used to calculate hydraulic gradients, determine direction of
groundwater flow at the site, and estimate free-phase product thickness (if present) in the subsurface. The calculations for these determinations are not included in this Scope. Be sure to obtain the most recent field data forms and well information for the
subject site. Please keep in mind that well information can be obtained from gINT.
2. EQUIPMENT LIST:
Safety/Personal Protective Equipment (PPE) Items
___ Appropriate personal protective equipment (PPE) gloves ___ First aid kit ___ Traffic cones ___ Appropriate PPE for contaminants of concern Measurement Items
___ Site map ___ Replacement lock and cap (be sure to bill to client)
___ Field Book (Daily Sheets and Water Elevation Sheets)
___ #2 Pencil or pen for record keeping ___ Hammer ___ Wrenches
___ Socket set up to 15/16” (9/16” and 15/16” typical)
___ Screwdriver
___ Something to remove water from well shield (i.e. turkey baster, jar, bottle, boat pump, sponge) ___ Appropriate keys for job site ___ Bolt cutters (just in case)
___ Saw (mark with a notch in high spot on TOC if none)
___ Sharpie (permanent marker) ___ Water and product paste ___ Measuring tape or electronic level indicator ___ T-handle wrench
___ Extra battery for electronic probes

SOP - WELL GAUGING 2 of 6 Revised February 2009

Decontamination ___ Paper towels ___ Trash bags ___ Spray bottle with phosphate-free detergent/water ___ Distilled water and spray bottle with distilled water
___ Spray bottle with diluted alcohol; pesticide-grade isopropyl alcohol (isopropanol, 2-
propanol) mixed with 1:10 alcohol and distilled water
3. GENERAL INFORMATION: The following information is critical and pertinent to either of the gauging procedures described in Section 4 and should be reviewed prior to leaving the office.

a. NO MATH SHOULD BE PERFORMED IN THE FIELD PRIOR TO
RECORDING DATA. This essentially means that you should not “calculate” measurements in your head. Record each measurement directly onto the
CATLIN “Groundwater Elevations” field form (attached). Calculations for
depth to water and product thickness will be completed after recording all
data. b. Use the appropriate PPE and clothing (rain gear) suitable for site conditions (check with project manager!). c. If historical data is available, review carefully so that you can gauge
historically “clean” wells first and historically “dirty”, recovery, or free product
wells last. d. If practical, open all wells prior to gauging in order to ensure that the groundwater equilibrates. e. Final measurements (for groundwater contouring) will be taken in monitoring
well no sooner than 24 hours after completion of well development activities.
f. For preparation of groundwater elevation maps and hydraulic gradient calculations, all monitoring wells will be measured on the same day. g. Make sure that the probe or metal tape is of sufficient length to reach the water table at your site. Some of our tapes are only 25 feet in length, which is
not long enough to determine depth to water at some of our sites. h. For wells with shallow surficial water tables, you may be able to look into the well and see the surface of the water. This allows for ease in measurement, especially when using the metal tape method as you are able to observe the probe/tape entering the groundwater.

SOP - WELL GAUGING 3 of 6 Revised February 2009
4. GAUGING PROCEDURES:
CATLIN typically uses one of two procedures for determination of depth to water: (1) the electronic water level indicator (or oil/water interface probe), and (2) the metal engineers tape with water and product finding paste. Whichever procedure you use, be consistent. The two procedures do not necessarily result in the same
measurement, so do not use both procedures for different wells gauged at the
same site on the same day! The following information details some characteristics of each method:
• The water level probe may not be used when free-product is present due to potential damage to equipment and inaccurate reading.
• The water level indicator is generally faster, but less accurate and precise.
• The water level indicator helps to minimize the risk of “missing” the top of
the water surface the first attempt.
• The metal engineers tape is more dependable, accurate, precise, and allows for determination of depth to product by using product-finding
paste.
• Never use a “plumb-bob” or weight at the end of a probe or tape. This can cause water displacement and give an inaccurate measurement.
The following sub-sections summarize the procedures for each method for
determining the depth to water.
Method 1 – Electronic Level Probe
1. Starting with the cleanest well, remove protective cover from each wellhead.
2. Unlock and remove the expandable locking well cap. 3. Allow each well at least a few minutes to equilibrate prior to taking the measurement. 4. Properly decontaminate the probe tip prior to use (Refer to Section 5). Do
not use alcohol of any kind on the probe tip. Use distilled water or wipe outside of probe tip with alcohol on paper towel. 5. Turn on the water level probe. Test to make sure the battery is good and the instrument is working properly. Take extra battery. Be sure to attach grounding cable for interface probe before taking measurements.
6. Starting with the cleanest well, slowly lower the probe into the well until the
audible sound indicator emits a beep or buzz. Interface probe will emit one signal for product and another for water. Verify with the equipment manual. You may need to work the tape up and down to get the exact point at which the probe intersects the water or free-phase product.
7. Record the Well ID on the Groundwater Elevations field form (attached).
8. Record the point where the probe tape intersects the well top-of-casing under
“Tape Held On (B)” on the Groundwater Elevations field form. IF there is no
product present, this measurement is also equal to “Depth to Groundwater
(E).” This measurement should be to the nearest 0.01 foot.
9. If depth of well is needed, use a tape. Extend the tape to the bottom of the
well, and record the well “total depth” on your daily field log. 10. Withdraw the probe or tape and decontaminate in accordance with Section 5. 11. Replace and lock the expandable cap, and secure the well shield.
SOP - WELL GAUGING 4 of 6 Revised February 2009

Method 2 – Metal Engineers Tape (For wells with or without product)
(Refer to Figure 1) 1. Starting with the cleanest well, remove protective cover from each wellhead. This may be a bolt of various sizes or a specialty bolt for flush mount wells.
Aboveground well shields will have a hinged cover with one of our standard
locks. 2. Unlock and remove the expandable locking well cap. 3. Allow each well a few minutes to equilibrate prior to taking the measurement. 4. Properly decontaminate the tape prior to use (Refer to Section 5).
5. Some tapes may be dedicated for free product use. Do not use one of these
tapes in a “clean” well or well without product. 6. Start with the cleanest well. 7. Smear a thin coating of water finding paste lengthwise along one half of the tape, from the end of the tape to a point between the 1.0 and 2.0-foot mark.
Be careful not to completely obscure the numbers.
8. Smear a thin coating of product finding paste lengthwise along the other half of the tape. Extend this line above the end of the water finding paste. Be careful not to completely obscure the numbers. The length of the product paste smear may vary to several feet depending on the product thickness in
the well.
9. Record the Well ID on the Groundwater Elevations field form. 10. Slowly lower the tape into the well until the tape intersects the water/product surface (s). Advance the tape to the nearest 0.5 or 1.0 foot interval. 11. Record the point where the tape intersects the well top-of-casing under “Tape
Held On (B)” on the Groundwater Elevations field form. This measurement should be to the nearest 0.01 foot. 12. Slowly withdraw the tape from the well. 13. If product is present, record the measurement at which the product paste
changes color under “Product Cut (C)” on the field form. Record “NMT” if no
product present. 14. Record the measurement at which the water finding paste changes color
under “Groundwater Cut (D).” 15. Figure 1 illustrates a typical measurement from a well with product present. 16. If information needed, extend the tape to the bottom of the well and record the
“total depth” on your daily field log. Decon per number 12. 17. Properly decontaminate the tape prior to gauging the next well in accordance with Section 5. 18. Replace and lock the expandable cap and secure the well shield.

SOP - WELL GAUGING 5 of 6 Revised February 2009

SOP - WELL GAUGING 6 of 6 Revised February 2009
5. DECONTAMINATION PROCEDURES:
The measuring device will be decontaminated between wells in the following manner:
• Spray the tape/probe with the alcohol, water or detergent/water mixture first.
• Rinse with distilled water.
• Wipe with paper towel.
• Repeat as necessary.
• Waste paper towels and PPE shall be properly disposed of (on-site if possible).
• Site-specific decontamination procedures may supersede standard operating
procedures. 6. RECORDING / DEMOBILIZATION:
• Record start and stop times for gauging activities on Daily Activities Sheet.
• For preparation of groundwater elevation maps, calculate a complete set of water elevations from the same day as shown on the attached Groundwater Elevations
field form.
• Restock all used materials.
SOP - WELL SAMPLING (Standard) Page 1 of 4 Revised February 2009
CATLIN STANDARD OPERATING PROCEDURES WELL SAMPLING (STANDARD) 1. PURPOSE AND SCOPE:
This document outlines CATLIN’s Standard Operating Procedure for obtaining a
groundwater sample from a monitoring well using standard procedures (non-low flow procedures). Be sure to obtain the most recent field data forms and well information for the
subject site. Please keep in mind that well information can be obtained from gINT. Regulatory Considerations:
• Be sure to understand the regulatory authority that is responsible for oversight of
this project. The PM will provided details on the impacts that the Regulatory
Authority may have on the sampling.
• Keep in mind sampling for each regulatory authority is generally the same with the main difference being associated with QA/QC samples and appropriate test
methods. 2. EQUIPMENT LIST: Safety/Personal Protective Equipment (PPE) Items
___ Appropriate personal protective equipment (PPE) gloves ___ First aid kit ___ Traffic cones ___ Appropriate PPE for contaminants of concern
Sampling Items
___ Replacement lock and cap (be sure to bill to client) ___ Hammer ___ Wrenches
___ Socket set up to 15/16”
___ Screwdriver ___ Something to remove water from well shield (i.e. turkey baster, jar, bottle, boat pump, sponge) ___ Appropriate Keys (at least 0536 and 3247 for NC projects and dolphin locks for GA
projects)
___ Bolt Cutters (just in case) ___ Saw (mark with a notch in high spot on TOC if none) ___ Sharpie (permanent marker) ___ Water and product paste
___ Measuring tape or electronic water level indicator
___ T-handle wrench ___ String
SOP - WELL SAMPLING (Standard) Page 2 of 4 Revised February 2009
___ Bailers or pump and tubing ___ Weighted fishing lure – Treble Hook (no lead) ___ 5-gallon bucket
___ 55-gallon drum (if required) ___ Knife ___ Ice ___ Cooler ___ Glassware
___ labels
___ baggie/ziploc ___ duct tape if shipping ___ custody seal ___ watch
___ calculator
___ Applicable field parameter equipment. Be sure to calibrate equipment prior to use and document on appropriate CATLIN Calibration Logs. ___ Plastic for around well and under equipment.
Decontamination
___ Paper towels ___ Trash bags ___ Spray bottle with phosphate-free detergent/water. ___ Distilled water and spray bottle with distilled water
___ Spray bottle with diluted alcohol; pesticide-grade isopropyl alcohol (isopropanol, 2-
propanol) mixed with 1:10 alcohol and distilled water Paper Work Items ___ Field book (daily activities sheet with water elevations sheet, maps, sampling
worksheet, COC) ___ Appropriate figures/maps (i.e. plume map and others) ___ #2 pencil/pens ___ Shipping paper work (FedEx, UPS, DHL) ___ Historical data (if applicable)
3. PROCEDURES: BEFORE LEAVING THE OFFICE:
• Gather equipment – use the checklist above.
• Meet with PM on paperwork needed and how it should be completed.
• Determine laboratory QA/QC samples needed.
• Call site to notify that you’re coming, if necessary.
• Verify proper equipment for developing wells - check for pump size and depth of
wells. Check with PM for applicable method for developing wells.
• Check glassware against bottle order against for what you are sampling.
• Be sure to sign out equipment and vehicle.

SOP - WELL SAMPLING (Standard) Page 3 of 4 Revised February 2009
AT SITE:
• Get ice before sampling.
• Check in at site with appropriate personnel, if necessary.
• If you are familiar with the site, gauge and sample clean wells first then
contaminated wells.
• Fill out labels as much as possible and glassware.
• Place plastic around well – approximately 4’ x 4’ area.
• Gauge wells according to CATLIN Well Gauging SOP.
• Fill out well sampling worksheet and determine volume to remove or number of bails prior to sampling.
• Purging is conducted with pumps or bailers.
• Purge three volumes or until dry. If well is purged dry, allow water to recharge and collect sample.
• Dispose of purge water appropriately (check with PM).
• If using a bailer, be sure not to let the string hit the ground.
• Sample with bailer or pump.
• Lower bailers slowly into water column.
• The order of sample container filling should proceed from most volatile to least
volatile compounds.
• Collect samples required with zero headspace for volatile organic analysis (VOA) vials to obtain minimum headspace for others.
• If filling glassware containing a preservative, don’t overfill the sample jar.
• Immediately place samples on sufficient ice in a cooler to maintain less than 4°C until it arrives at the laboratory.
• Collect appropriate number of QA/QC samples.
• Complete labeling of the sample jars.
• Fill out chain of custody (COC) COMPLETELY and accurately and neatly. If not sure of any information on the form, be sure to verify with PM.
• Clean site and handle investigative derived waste appropriately.
• Replace locking well cap, lock and secure well head.
• Deliver samples to laboratory within appropriate hold times on sufficient ice. Request applicable Electronic Data Deliverable (EDD) format on COC if necessary. Also put appropriate quote number on the COC.
• When returning to the office, return equipment to proper place and be sure to fill
out equipment log for billing purposes.
• Fill out mileage log properly.
• Make sure to have debriefing with PM after returning to the office. This can be
accomplished via telephone.
4. DECONTAMINATION PROCEDURES: The sampling equipment is to be decontaminated between wells in the following
manner:

• Spray the reusable items with the alcohol, water or detergent/water mixture first.
• Rinse with distilled water.
SOP - WELL SAMPLING (Standard) Page 4 of 4 Revised February 2009
• Repeat as necessary.
• Waste paper towels, PPE and non-reusable items shall be properly disposed of
(on-site if possible).
• Site-specific decontamination procedures may supersede standard operating procedures.
5. REPORT:
• Record required information on the CATLIN Sample Record Form, laboratory
Chain-of-Custody and labels, and all other forms requested by the PM.
• Put copy of Chain of Custody in field book.
13.0 PERMIT-REQUIRED CONFINED SPACES
(in compliance with 29 CFR 1910.120(b)(4)(ii)(I) and 1910.146)
This permit-required confined space program (permit space program) includes the elements specified in 29 CFR 1910.146
and provides the following site-specific information:
* identification and evaluation of permit spaces
* measures to prevent unauthorized entry
* entry permit system
The person with overall responsibility for the permit space program is Project Manager. The permit space program is
modified to reflect changing site conditions or work operations. This program is reviewed if any of the following conditions
occur:
This site has been carefully evaluated by Project Manager on 11/11/2020 and there are no confined spaces on this site.
This section of the Health and Safety Plan represents the site-specific written confined space entry program. The purpose
of this section of the Health and Safety Plan is to identify all permit-required confined spaces (permit spaces) on site and
to describe the procedures that have been developed and implemented to ensure worker safety and health in permit-
required confined spaces. In compliance with the requirements of 29 CFR 1910.120(b)(4)(ii)(I), this section of the HASP
is included even when no permit-required confined spaces are present on site in order to indicate that a site-specific
evaluation for permit spaces has been made.
* entry equipment and personal protective equipment
* permit spaces training
* rescue and emergency procedures
* employee participation
* entry procedures
* occurrence of unauthorized entry of a permit space
* discovery of a permit space hazard not covered by the permit
* detection of a condition prohibited by the permit
* occurrence of a injury or near-miss during entry
* employee complaints of permit space program ineffectiveness
* change in the use or configuration of a confined space
Additionally, an annual review of all entries performed during the previous 12 month period is conducted. If no entries
were made into a permit space, then no annual review is performed.
13.1 Identification and Evaluation of Permit Spaces
13 - 1 of 1 Date of Program:Site Name:Cheek Road Grocery
14.0 HOT WORK
(in compliance with 29 CFR 1910.252(a))
An evaluation concluded that no welding or cutting would occur on this site. For that reason, no hot work program is
implemented for this site.
14 - 1 of 2 Date of Program:Site Name:Cheek Road Grocery
14 - 2 of 2 Date of Program:Site Name:Cheek Road Grocery
15.0 Energy Control or Lockout/Tagout Program
(in compliance with 29 CFR 1910.147)
This section of the Health and Safety Plan represents the site-specific hazardous energy control program. The purpose of this
section of the Health and Safety Plan is to identify all machine and equipment repair and maintenance activities that require
LOTO procedures under 1910.147.
This site was carefully evaluated by Project Manager on 11/11/2020 and it was determined that LOTO procedures are not
necessary for any machines or equipment to protect site employees from hazardous energy. This section of the HASP is
included even when the employer is not covered by 1910.147 in order to indicate that a site-specific evaluation for the control of
hazardous energy has been made.
[NOTE: The employer may want to indicate the specific reason they are not covered by the LOTO standard, especially in cases
where repair and maintenance of machines or equipment on the site is necessary. If an employer is exempt because of normal
production operations (1910.147(a)(2)(ii)), hot tap operations (1910.147(a)(2)(iii)(B)), or other reasons, he/she should note the
reason for the LOTO exemption.]
15 - 1 of 1 Date of Program:Site Name:Cheek Road Grocery

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDIX D

WELL LOG, MONITORING WELL CONSTRUCTION RECORD,
AND TRANSMITTAL LETTER
Re:NC Well Construction Record
Cheek Road Grocery5801 CHEEK ROAD
Durham, North Carolina 27704CATLIN Project No.: 221007
August 31, 2021
To Whom It May Concern:
CATLIN Engineers and Scientists (CATLIN) recently constructed one (1) monitoring well at the above
referenced site. Attached to this letter are completed North Carolina Well Construction Record with
associated Attachment(s) for the above referenced site located at 5801 Cheek Road in Durham, North
Carolina.
If you have any questions or require any additional information, please feel free to contact us at (910)
452-5861.
Sincerely,
Sean O'Neil, P.E.
Project Manager
Enclosures: Well Log and Well Construction Record
North Carolina Department of Environmental Quality
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
1044 Washington Street
Raleigh, NC 27605
[phone]
www.CatlinUSA.com
D.T. CHALMERS, JR.
08/11/21
HSA
4146A
DRY
MW-01
Bent. Pellets8.5
1
1
0
10 20 PVC
2
Sch. 40
Surface Pour
0 Sch. 40 PVC10
Portland Cement
N/A
8.5 22
ORANGE
1
X
8/31/2021
8.25
Surface Pour
CATLIN Engineers and Scientists
X
20
X
2 Slot .010
5801 CHEEK ROAD, DURHAM, NC 27704
TO DIAMETER THICKNESS MATERIAL
FROM17. SCREEN DIAMETER SLOT SIZE MATERIALTHICKNESS
FROM TO MATERIAL
ft.ft.
ft.
ft.
FROM TO
18. GROUT
MATERIAL
19. SAND/GRAVEL PACK (if applicable)
1. Well Contractor Information:
This form can be used for single or multiple wells
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural
Non-Water Supply Well:
Monitoring
Geothermal (Heating/Cooling Supply)
Industrial/Commercial
Irrigation
15. INNER CASING OR TUBING (geothermal closed-loop)
Municipal/Public
Residential Water Supply (single)
ft.
ft.ft.
ft.ft.
ft.
ft.ft.
ft.
TO
EMPLACEMENT METHOD & AMOUNT
in.
in.
in.
EMPLACEMENT METHOD
Recovery
Injection Well:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of
this record has been provided to the well owner.
If this is a repair, fill out known well construction information and explain the nature ofthe repair under #21 remarks section or on the back of this form.
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
13a. Yield (gpm)
FOR WATER SUPPLY WELLS ONLY:
Method of test:
Amount:
For Internal Use ONLY:
14. WATER ZONES
FROM TO DESCRIPTION
FROM TO
24c. For Water Sypply & Injection Wells:Also submit one copy of this form within 30 days of completion of wellconstruction to the county health department of the county where constructed.
DIAMETER THICKNESS
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
21. REMARKS
20. DRILLING LOG (attach additional sheets if necessary)
5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees:
Signature of Certified Well Contractor Date
24a. For All Wells: Submit this form within 30 days of completion of wellconstruction to the following:
SUBMITTAL INSTRUCTIONS
Division of Water Resources, Information Processing Unit,1617 Mail Service Center, Raleigh, NC 27699-1617
Division of Water Resources, Underground Injection Control Program,1636 Mail Service Center, Raleigh, NC 27699-1636
16. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
North Carolina Department of Environment and Natural Resources - Division of Water Resources
24b. For Injection Wells ONLY: In addition to sending the form to theaddress in 24a above, also submit a copy of this form within 30 days ofcompletion of well construction to the following:
WELL CONSTRUCTION RECORD
23. Site diagram or additional well details:
Aquifer Recharge Groundwater Remediation
Stormwater Drainage
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling Return)
Salinity Barrier
Subsidence Control
Tracer
Other (explain under #21 Remarks)
4. Date Well(s) Completed:
5a. Well Location:
Well ID#:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
(if well field, one lat/long is sufficient)
N
6. Is (are) the well(s):
Yes
TemporaryPermanent or
or No7. Is this a repair to an existing well:
8. Number of wells constructed:
For multiple injection or non-water supply wells ONLY with the same construction, youcan submit one form.
9. Total well depth below land surface:
For multiple wells list all depths in different (example- 3@200' and 2@100')
W
(ft.)10. Static water level below top of casing:
If water level is above casing, use "+"
11. Borehole diameter:
MATERIAL
FROM
Residential Water Supply (shared)
Adapted from Form GW-1
ft.
f#.2 Medium Sand Torpedo Sand
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.
ft.
(ft.)
(in.)
ft.
ft.ft.
ft.
ft.
ft.in.
in.
ft.
ft.
ft.ft.
ft.
ft.
13b. Disinfection type:
22. Certification:
Revised 2-22-2016
ft.
SEE
ATTAC
H
E
D
Cheek Road GroceryLarry L Ricks
ft.
36.029161 -78.773363
22.0
0.8
5.0
10.0
15.0
20.0
NM
6
30
44
32
4
2
5
6
8
4
4
27
25
28
4
2
13
14
17
20.0
10.0
20.0
0.0
1.0
8.5
22.02" Sch. 40 PVC2" Slot .010Sch. 40 PVCD
D
D
D
W
0.50.8
3.5
8.5
0.50.8
3.5
8.5
22.0
MW-01
(5-7')
ASPHALT
(GW) - ABC STONE
(SC) - Tan, well graded SAND w/Clay. HCO
(CL) - Lt. gray, Micaceous CLAY w/little sand. Faint
HCO
(SM) - Red grading to brown, Micaceous Silty SAND
BORING TERMINATED AT DEPTH 22.0 ft in Silty
micaseous SAND/SAPPROLITE
MW-01
(5-7')
6.6
41.6
1.7
1.3
DRILL MACHINE:CME 45B TRACK METHOD:HSA
COUNTY:ORANGE
T.O.C. ELEV.:
TOTAL DEPTH:
WELL DEPTH:
NC
SHEET
DRY
N/A
DEPTH
LOCATION:DURHAM
1
22.0
20.0
0 HOUR DTW:
24 HOUR DTW:END DATE:8/11/21
OF1
BORING LOCATION:W. of Former UST BASIN (T5)
BLOW COUNT
0.5ft
START DATE:8/11/21
0.5ft
WELL ID:
STATE:
MW-01NORTHING:
LOGGED BY:
DRILLER:
CREW:
0.5ft0.5ft
EASTING:
PROJECT NO.:221007
SYSTEM:NCSP NAD 83 (USft)
CHEEK ROAD GROCERYPROJECT:O. DAYNES
D.T. CHALMERS, JR.
E. SWAIN
CATLIN BORING LOG 221007_NCDEQ SLP CHEEK ROAD GROCERY.GPJ CATLIN.GDT 8/31/21Portland Cement Bentonite Pellets #2 Medium Sand
0.0
WELL LOG
WELL
DETAIL
SOIL AND ROCK
DESCRIPTIONLAB.DEPTH
MOIS
0.0 LAND SURFACE
LOG
OVA
(ppm)
221007
30727057 31348406
NM

NCDEQ; 33873_Cheek Road Grocery CATLIN Engineers and Scientists
CATLIN Project No. 221007 September 2021

APPENDIX E

LABORATORY ANALYTICAL REPORTS AND
CHAIN OF CUSTODY DOCUMENTS

39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
August 24, 2021
Ben Ashba
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
Project Location: 5301 Check Road, Durham, NC
Client Job Number:
Project Number: 221007
Laboratory Work Order Number: 21H0743
Enclosed are results of analyses for samples received by the laboratory on August 13, 2021. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kaitlyn A. Feliciano
Project Manager
Page 1 of 43
Table of Contents
Table of Contents
Sample Summary 3
Hits Only Report 4
Case Narrative 5
Sample Results 9
21H0743-01 9
Sample Preparation Information 16
QC Data 17
Volatile Organic Compounds by GC/MS 17
B288355 17
Semivolatile Organic Compounds by GC/MS 22
B288487 22
Petroleum Hydrocarbons Analyses - EPH 27
B288346 27
Petroleum Hydrocarbons Analyses - VPH 29
B288458 29
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) 31
B288395 31
Flag/Qualifier Summary 32
Certifications 33
Chain of Custody/Sample Receipt 40
Page 2 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
8/24/2021
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
ATTN: Ben Ashba
221007
21H0743
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
5301 Check Road, Durham, NC
210817-3
MW01 (5.0-7.0)21H0743-01 Soil MADEP EPH rev 2.1
MADEP-VPH-Feb
2018 Rev 2.1
SM 2540G
SW-846 8260D
SW-846 8270E
[TOC_1]Sample Summary[TOC]
Page 3 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
[TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
21H0743-01MW01 (5.0-7.0)
DL
1,2,4-Trimethylbenzene 2.6 0.066 mg/Kg dry SW-846 8260D0.0066
1,3,5-Trimethylbenzene 0.84 0.066 mg/Kg dry SW-846 8260D0.0066
Benzene 0.049 0.066 mg/Kg dry SW-846 8260DJ0.0085
Ethylbenzene 0.40 0.066 mg/Kg dry SW-846 8260D0.0059
Isopropylbenzene (Cumene)0.094 0.066 mg/Kg dry SW-846 8260D0.0066
m+p Xylene 0.45 0.13 mg/Kg dry SW-846 8260D0.012
Naphthalene 0.56 0.13 mg/Kg dry SW-846 8260D0.0098
n-Butylbenzene 0.59 0.066 mg/Kg dry SW-846 8260D0.0092
n-Propylbenzene 0.40 0.066 mg/Kg dry SW-846 8260D0.0052
o-Xylene 0.27 0.066 mg/Kg dry SW-846 8260D0.0059
p-Isopropyltoluene (p-Cymene)0.048 0.066 mg/Kg dry SW-846 8260DJ0.0059
sec-Butylbenzene 0.079 0.066 mg/Kg dry SW-846 8260D0.0066
Toluene 0.024 0.066 mg/Kg dry SW-846 8260DJ0.0072
1-Methylnaphthalene 0.13 0.22 mg/Kg dry SW-846 8270EJ0.061
2-Methylnaphthalene 0.33 0.22 mg/Kg dry SW-846 8270E0.070
Naphthalene 0.11 0.22 mg/Kg dry SW-846 8270EJ0.060
C9-C18 Aliphatics 18 13 mg/Kg dry MADEP EPH rev 2.113
C5-C8 Aliphatics 140 52 mg/Kg dry MADEP-VPH-Feb 2018 Rev 2.113
C9-C10 Aromatics 190 52 mg/Kg dry MADEP-VPH-Feb 2018 Rev 2.17.3
C9-C12 Aliphatics 170 52 mg/Kg dry MADEP-VPH-Feb 2018 Rev 2.110
% Solids 77.3 % Wt SM 2540G
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 4 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA VPH, only hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
Page 5 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
MADEP-VPH-Feb 2018 Rev 2.1
Qualifications:
Soil/methanol ratio does not meet method specifications. Excess amount of soil. Sample was completely covered with methanol, but with
less than the method-specified amount.
Analyte & Samples(s) Qualified:
O-01
21H0743-01[MW01 (5.0-7.0)]
Surrogate recovery outside of control limits due to suspected sample matrix interference. Chromatogram(s) is attached.
Analyte & Samples(s) Qualified:
S-15
2,5-Dibromotoluene (FID)
21H0743-01[MW01 (5.0-7.0)]
2,5-Dibromotoluene (PID)
21H0743-01[MW01 (5.0-7.0)]
Closing CCV surrogate has high recovery. This is due to sample matrix. Samples were reanlayzed with repeated results.
Analyte & Samples(s) Qualified:
Z-01
2,5-Dibromotoluene (FID)
S062547-CCV2
2,5-Dibromotoluene (PID)
S062547-CCV2
SW-846 8260D
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not
affected since all results are "not detected" for associated samples in this batch and bias is on the high side.
Analyte & Samples(s) Qualified:
L-02
Bromomethane
B288355-BS1, B288355-BSD1
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
Chloromethane
21H0743-01[MW01 (5.0-7.0)], B288355-BLK1, B288355-BS1, B288355-BSD1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
Chloromethane
21H0743-01[MW01 (5.0-7.0)], B288355-BLK1, B288355-BS1, B288355-BSD1, S062494-CCV1
Dichlorodifluoromethane (Freon 12)
21H0743-01[MW01 (5.0-7.0)], B288355-BLK1, B288355-BS1, B288355-BSD1, S062494-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Bromochloromethane
B288355-BS1, B288355-BSD1, S062494-CCV1
Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is
estimated.
Analyte & Samples(s) Qualified:
V-34
Bromomethane
21H0743-01[MW01 (5.0-7.0)], B288355-BLK1, B288355-BS1, B288355-BSD1, S062494-CCV1
Chloromethane
21H0743-01[MW01 (5.0-7.0)], B288355-BLK1, B288355-BS1, B288355-BSD1, S062494-CCV1
SW-846 8270E
Page 6 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Qualifications:
Initial calibration did not meet method specifications. Compound was calibrated using a response factor where %RSD is outside of method
specified criteria. Reported result is estimated.
Analyte & Samples(s) Qualified:
V-04
Benzidine
21H0743-01[MW01 (5.0-7.0)], B288487-BLK1, B288487-BS1, B288487-BSD1, S062529-CCV1, S062545-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound.
Analyte & Samples(s) Qualified:
V-06
2,4-Dinitrophenol
S062545-CCV1
4,6-Dinitro-2-methylphenol
S062545-CCV1
Benzidine
S062545-CCV1
Benzoic Acid
S062545-CCV1
Bis(2-chloroisopropyl)ether
S062545-CCV1
N-Nitrosodimethylamine
S062545-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
2,4-Dinitrophenol
21H0743-01[MW01 (5.0-7.0)]
4,6-Dinitro-2-methylphenol
21H0743-01[MW01 (5.0-7.0)]
Benzidine
21H0743-01[MW01 (5.0-7.0)]
Benzoic Acid
21H0743-01[MW01 (5.0-7.0)]
Bis(2-chloroisopropyl)ether
21H0743-01[MW01 (5.0-7.0)]
N-Nitrosodimethylamine
21H0743-01[MW01 (5.0-7.0)]
Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is
estimated.
Analyte & Samples(s) Qualified:
V-34
4-Chloroaniline
21H0743-01[MW01 (5.0-7.0)], B288487-BLK1, B288487-BS1, B288487-BSD1, S062529-CCV1, S062545-CCV1
Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is
estimated.
Analyte & Samples(s) Qualified:
V-35
Benzidine
21H0743-01[MW01 (5.0-7.0)], S062545-CCV1
Page 7 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
MADEP-VPH-Feb 2018 Rev 2.1
No significant modifications were made to the method. All VPH samples were received preserved properly in methanol with a soil/methanol ratio of 1:1 +/- 25% completely
covered by methanol in the proper containers specified on the chain-of-custody form unless specified in this narrative.
Analytical column used for VPH analysis is Restek, Rtx-502.2, 105meter, 0.53mmID, 3um df. Trap used for VPH analysis is Carbopack B/CarboSieveS-III.
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Tod E. Kopyscinski
Laboratory Director
Page 8 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
[TOC_2]21H0743-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 3.3 8/17/21 14:52 LBDmg/Kg dry0.15 8/17/21SW-846 8260D1Acetone
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.045 8/17/21SW-846 8260D1Acrylonitrile
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D1tert-Amyl Methyl Ether (TAME)
0.049 0.066 8/17/21 14:52 LBDmg/Kg dry0.0085 8/17/21SW-846 8260D1JBenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0085 8/17/21SW-846 8260D1Bromobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.024 8/17/21SW-846 8260D1Bromochloromethane
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0092 8/17/21SW-846 8260D1Bromodichloromethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.019 8/17/21SW-846 8260D1Bromoform
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.070 8/17/21SW-846 8260D1V-34Bromomethane
ND 1.3 8/17/21 14:52 LBDmg/Kg dry0.12 8/17/21SW-846 8260D12-Butanone (MEK)
ND 1.3 8/17/21 14:52 LBDmg/Kg dry0.35 8/17/21SW-846 8260D1tert-Butyl Alcohol (TBA)
0.59 0.066 8/17/21 14:52 LBDmg/Kg dry0.0092 8/17/21SW-846 8260D1n-Butylbenzene
0.079 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D1sec-Butylbenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D1tert-Butylbenzene
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0072 8/17/21SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.10 8/17/21SW-846 8260D1Carbon Disulfide
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.011 8/17/21SW-846 8260D1Carbon Tetrachloride
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0052 8/17/21SW-846 8260D1Chlorobenzene
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.010 8/17/21SW-846 8260D1Chlorodibromomethane
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.024 8/17/21SW-846 8260D1Chloroethane
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D1Chloroform
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.025 8/17/21SW-846 8260D1V-05, L-04, V-34Chloromethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D12-Chlorotoluene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D14-Chlorotoluene
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.047 8/17/21SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D11,2-Dibromoethane (EDB)
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.019 8/17/21SW-846 8260D1Dibromomethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D11,2-Dichlorobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D11,3-Dichlorobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0072 8/17/21SW-846 8260D11,4-Dichlorobenzene
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.12 8/17/21SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.013 8/17/21SW-846 8260D1V-05Dichlorodifluoromethane (Freon 12)
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.010 8/17/21SW-846 8260D11,1-Dichloroethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.021 8/17/21SW-846 8260D11,2-Dichloroethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.010 8/17/21SW-846 8260D11,1-Dichloroethylene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D1cis-1,2-Dichloroethylene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.011 8/17/21SW-846 8260D1trans-1,2-Dichloroethylene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D11,2-Dichloropropane
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0079 8/17/21SW-846 8260D11,3-Dichloropropane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.020 8/17/21SW-846 8260D12,2-Dichloropropane
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.017 8/17/21SW-846 8260D11,1-Dichloropropene
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0079 8/17/21SW-846 8260D1cis-1,3-Dichloropropene
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D1trans-1,3-Dichloropropene
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.014 8/17/21SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 9 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D1Diisopropyl Ether (DIPE)
ND 3.3 8/17/21 14:52 LBDmg/Kg dry1.4 8/17/21SW-846 8260D11,4-Dioxane
0.40 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D1Ethylbenzene
ND 0.039 8/17/21 14:52 LBDmg/Kg dry0.027 8/17/21SW-846 8260D1Hexachlorobutadiene
ND 0.66 8/17/21 14:52 LBDmg/Kg dry0.091 8/17/21SW-846 8260D12-Hexanone (MBK)
0.094 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D1Isopropylbenzene (Cumene)
0.048 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D1Jp-Isopropyltoluene (p-Cymene)
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.011 8/17/21SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.020 8/17/21SW-846 8260D1Methylene Chloride
ND 0.66 8/17/21 14:52 LBDmg/Kg dry0.11 8/17/21SW-846 8260D14-Methyl-2-pentanone (MIBK)
0.56 0.13 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D1Naphthalene
0.40 0.066 8/17/21 14:52 LBDmg/Kg dry0.0052 8/17/21SW-846 8260D1n-Propylbenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0052 8/17/21SW-846 8260D1Styrene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0092 8/17/21SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.033 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D11,1,2,2-Tetrachloroethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.013 8/17/21SW-846 8260D1Tetrachloroethylene
ND 0.66 8/17/21 14:52 LBDmg/Kg dry0.038 8/17/21SW-846 8260D1Tetrahydrofuran
0.024 0.066 8/17/21 14:52 LBDmg/Kg dry0.0072 8/17/21SW-846 8260D1JToluene
ND 0.33 8/17/21 14:52 LBDmg/Kg dry0.0092 8/17/21SW-846 8260D11,2,3-Trichlorobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.010 8/17/21SW-846 8260D11,2,4-Trichlorobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D11,3,5-Trichlorobenzene
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.011 8/17/21SW-846 8260D11,1,1-Trichloroethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.0098 8/17/21SW-846 8260D11,1,2-Trichloroethane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D1Trichloroethylene
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.020 8/17/21SW-846 8260D11,2,3-Trichloropropane
ND 0.066 8/17/21 14:52 LBDmg/Kg dry0.016 8/17/21SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
2.6 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D11,2,4-Trimethylbenzene
0.84 0.066 8/17/21 14:52 LBDmg/Kg dry0.0066 8/17/21SW-846 8260D11,3,5-Trimethylbenzene
ND 0.13 8/17/21 14:52 LBDmg/Kg dry0.013 8/17/21SW-846 8260D1Vinyl Chloride
0.45 0.13 8/17/21 14:52 LBDmg/Kg dry0.012 8/17/21SW-846 8260D1m+p Xylene
0.27 0.066 8/17/21 14:52 LBDmg/Kg dry0.0059 8/17/21SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 75.0 8/17/21 14:5270-130
Toluene-d8 94.9 8/17/21 14:5270-130
4-Bromofluorobenzene 101 8/17/21 14:5270-130
Page 10 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Semivolatile Organic Compounds by GC/MS
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.069 8/18/21SW-846 8270E1Acenaphthene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.067 8/18/21SW-846 8270E1Acenaphthylene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.060 8/18/21SW-846 8270E1Acetophenone
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.092 8/18/21SW-846 8270E1Aniline
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.072 8/18/21SW-846 8270E1Anthracene
ND 0.85 8/19/21 13:55 IMRmg/Kg dry0.20 8/18/21SW-846 8270E1V-04, V-20, V-35Benzidine
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.061 8/18/21SW-846 8270E1Benzo(a)anthracene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.067 8/18/21SW-846 8270E1Benzo(a)pyrene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.066 8/18/21SW-846 8270E1Benzo(b)fluoranthene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.092 8/18/21SW-846 8270E1Benzo(g,h,i)perylene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.060 8/18/21SW-846 8270E1Benzo(k)fluoranthene
ND 1.3 8/19/21 13:55 IMRmg/Kg dry0.52 8/18/21SW-846 8270E1V-20Benzoic Acid
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.057 8/18/21SW-846 8270E1Bis(2-chloroethoxy)methane
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.060 8/18/21SW-846 8270E1Bis(2-chloroethyl)ether
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.10 8/18/21SW-846 8270E1V-20Bis(2-chloroisopropyl)ether
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.074 8/18/21SW-846 8270E1Bis(2-Ethylhexyl)phthalate
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.056 8/18/21SW-846 8270E14-Bromophenylphenylether
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.070 8/18/21SW-846 8270E1Butylbenzylphthalate
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.072 8/18/21SW-846 8270E1Carbazole
ND 0.85 8/19/21 13:55 IMRmg/Kg dry0.058 8/18/21SW-846 8270E1V-344-Chloroaniline
ND 0.85 8/19/21 13:55 IMRmg/Kg dry0.073 8/18/21SW-846 8270E14-Chloro-3-methylphenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.051 8/18/21SW-846 8270E12-Chloronaphthalene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.061 8/18/21SW-846 8270E12-Chlorophenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.063 8/18/21SW-846 8270E14-Chlorophenylphenylether
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.064 8/18/21SW-846 8270E1Chrysene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.089 8/18/21SW-846 8270E1Dibenz(a,h)anthracene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.065 8/18/21SW-846 8270E1Dibenzofuran
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.062 8/18/21SW-846 8270E1Di-n-butylphthalate
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.050 8/18/21SW-846 8270E11,2-Dichlorobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.048 8/18/21SW-846 8270E11,3-Dichlorobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.046 8/18/21SW-846 8270E11,4-Dichlorobenzene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.064 8/18/21SW-846 8270E13,3-Dichlorobenzidine
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.065 8/18/21SW-846 8270E12,4-Dichlorophenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.067 8/18/21SW-846 8270E1Diethylphthalate
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.12 8/18/21SW-846 8270E12,4-Dimethylphenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.064 8/18/21SW-846 8270E1Dimethylphthalate
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.30 8/18/21SW-846 8270E1V-204,6-Dinitro-2-methylphenol
ND 0.85 8/19/21 13:55 IMRmg/Kg dry0.38 8/18/21SW-846 8270E1V-202,4-Dinitrophenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.086 8/18/21SW-846 8270E12,4-Dinitrotoluene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.073 8/18/21SW-846 8270E12,6-Dinitrotoluene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.16 8/18/21SW-846 8270E1Di-n-octylphthalate
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.063 8/18/21SW-846 8270E11,2-Diphenylhydrazine/Azobenzene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.070 8/18/21SW-846 8270E1Fluoranthene
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.074 8/18/21SW-846 8270E1Fluorene
Page 11 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Semivolatile Organic Compounds by GC/MS
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.060 8/18/21SW-846 8270E1Hexachlorobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.056 8/18/21SW-846 8270E1Hexachlorobutadiene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.18 8/18/21SW-846 8270E1Hexachlorocyclopentadiene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.052 8/18/21SW-846 8270E1Hexachloroethane
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.10 8/18/21SW-846 8270E1Indeno(1,2,3-cd)pyrene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.073 8/18/21SW-846 8270E1Isophorone
0.13 0.22 8/19/21 13:55 IMRmg/Kg dry0.061 8/18/21SW-846 8270E1J1-Methylnaphthalene
0.33 0.22 8/19/21 13:55 IMRmg/Kg dry0.070 8/18/21SW-846 8270E12-Methylnaphthalene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.081 8/18/21SW-846 8270E12-Methylphenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.071 8/18/21SW-846 8270E13/4-Methylphenol
0.11 0.22 8/19/21 13:55 IMRmg/Kg dry0.060 8/18/21SW-846 8270E1JNaphthalene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.094 8/18/21SW-846 8270E12-Nitroaniline
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.075 8/18/21SW-846 8270E13-Nitroaniline
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.094 8/18/21SW-846 8270E14-Nitroaniline
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.064 8/18/21SW-846 8270E1Nitrobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.069 8/18/21SW-846 8270E12-Nitrophenol
ND 0.85 8/19/21 13:55 IMRmg/Kg dry0.18 8/18/21SW-846 8270E14-Nitrophenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.066 8/18/21SW-846 8270E1V-20N-Nitrosodimethylamine
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.066 8/18/21SW-846 8270E1N-Nitrosodiphenylamine/Diphenylamine
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.061 8/18/21SW-846 8270E1N-Nitrosodi-n-propylamine
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.074 8/18/21SW-846 8270E1Pentachloronitrobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.19 8/18/21SW-846 8270E1Pentachlorophenol
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.069 8/18/21SW-846 8270E1Phenanthrene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.063 8/18/21SW-846 8270E1Phenol
ND 0.22 8/19/21 13:55 IMRmg/Kg dry0.070 8/18/21SW-846 8270E1Pyrene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.045 8/18/21SW-846 8270E1Pyridine
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.057 8/18/21SW-846 8270E11,2,4,5-Tetrachlorobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.055 8/18/21SW-846 8270E11,2,4-Trichlorobenzene
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.068 8/18/21SW-846 8270E12,4,5-Trichlorophenol
ND 0.44 8/19/21 13:55 IMRmg/Kg dry0.068 8/18/21SW-846 8270E12,4,6-Trichlorophenol
Surrogates % Recovery Recovery Limits Flag/Qual
2-Fluorophenol 58.8 8/19/21 13:5530-130
Phenol-d6 78.3 8/19/21 13:5530-130
Nitrobenzene-d5 66.9 8/19/21 13:5530-130
2-Fluorobiphenyl 68.4 8/19/21 13:5530-130
2,4,6-Tribromophenol 70.9 8/19/21 13:5530-130
p-Terphenyl-d14 83.8 8/19/21 13:5530-130
Page 12 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - EPH
18 13 8/20/21 13:39 AYHmg/Kg dry 8/17/21MADEP EPH rev 2.11C9-C18 Aliphatics
ND 13 8/20/21 13:39 AYHmg/Kg dry 8/17/21MADEP EPH rev 2.11C19-C36 Aliphatics
ND 13 8/20/21 13:39 AYHmg/Kg dry 8/17/21MADEP EPH rev 2.11Unadjusted C11-C22 Aromatics
ND 13 8/20/21 13:39 AYHmg/Kg dry 8/17/21MADEP EPH rev 2.11C11-C22 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
Chlorooctadecane (COD)63.1 8/20/21 13:3940-140
o-Terphenyl (OTP)80.8 8/20/21 13:3940-140
2-Bromonaphthalene 130 8/20/21 13:3940-140
2-Fluorobiphenyl 130 8/20/21 13:3940-140
Page 13 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Sample Flags: O-01
Soil/Methanol Preservation Ratio: 1.29
Petroleum Hydrocarbons Analyses - VPH
140 52 8/18/21 22:10 KMBmg/Kg dry 8/18/21MADEP-VPH-Feb 2018
Rev 2.1
4C5-C8 Aliphatics
170 52 8/18/21 22:10 KMBmg/Kg dry 8/18/21MADEP-VPH-Feb 2018
Rev 2.1
4C9-C12 Aliphatics
190 52 8/18/21 22:10 KMBmg/Kg dry 8/18/21MADEP-VPH-Feb 2018
Rev 2.1
4C9-C10 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
2,5-Dibromotoluene (FID)153 8/18/21 22:10*S-1570-130
2,5-Dibromotoluene (PID)149 8/18/21 22:10*S-1570-130
Page 14 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/13/2021
Work Order: 21H0743Sample Description:Project Location: 5301 Check Road, Durham, NC
Sample ID: 21H0743-01
Field Sample #: MW01 (5.0-7.0)
Sample Matrix: Soil
Sampled: 8/11/2021 10:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
77.3 8/18/21 16:57 CV% Wt 8/17/21SM 2540G1% Solids
Page 15 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 3546-MADEP EPH rev 2.1
Lab Number [Field ID]Batch DateInitial [g]Final [mL]
B288346 08/17/2120.0 2.0021H0743-01 [MW01 (5.0-7.0)]
Prep Method: MA VPH-MADEP-VPH-Feb 2018 Rev 2.1
Lab Number [Field ID]Batch DateInitial [g]Final [mL]
B288458 08/18/216.45 6.4621H0743-01 [MW01 (5.0-7.0)]
Prep Method: % Solids-SM 2540G
Lab Number [Field ID]Batch Date
B288395 08/17/2121H0743-01 [MW01 (5.0-7.0)]
Prep Method: SW-846 5035-SW-846 8260D
Lab Number [Field ID]Batch
Sample
Amount(g)
Methanol
Volume(mL)
Methanol
Aliquot(mL)
Final
Volume(mL)Date
21H0743-01 [MW01 (5.0-7.0)]B288355 6.36 6.44 1 50 08/17/21
Prep Method: SW-846 3546-SW-846 8270E
Lab Number [Field ID]Batch DateInitial [g]Final [mL]
B288487 08/18/2130.0 1.0021H0743-01 [MW01 (5.0-7.0)]
[TOC_1]Sample Preparation Information[TOC]
Page 16 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B288355 - SW-846 5035
[TOC_3]B288355[TOC]
Blank (B288355-BLK1) Prepared & Analyzed: 08/17/21
Acetone mg/Kg wet2.5ND
Acrylonitrile mg/Kg wet0.25ND
tert-Amyl Methyl Ether (TAME)mg/Kg wet0.025ND
Benzene mg/Kg wet0.050ND
Bromobenzene mg/Kg wet0.050ND
Bromochloromethane mg/Kg wet0.050ND
Bromodichloromethane mg/Kg wet0.025ND
Bromoform mg/Kg wet0.050ND
Bromomethane mg/Kg wet0.10 V-34ND
2-Butanone (MEK)mg/Kg wet1.0ND
tert-Butyl Alcohol (TBA)mg/Kg wet1.0ND
n-Butylbenzene mg/Kg wet0.050ND
sec-Butylbenzene mg/Kg wet0.050ND
tert-Butylbenzene mg/Kg wet0.050ND
tert-Butyl Ethyl Ether (TBEE)mg/Kg wet0.025ND
Carbon Disulfide mg/Kg wet0.25ND
Carbon Tetrachloride mg/Kg wet0.050ND
Chlorobenzene mg/Kg wet0.050ND
Chlorodibromomethane mg/Kg wet0.025ND
Chloroethane mg/Kg wet0.10ND
Chloroform mg/Kg wet0.10ND
Chloromethane mg/Kg wet0.10 L-04, V-05, V-34ND
2-Chlorotoluene mg/Kg wet0.050ND
4-Chlorotoluene mg/Kg wet0.050ND
1,2-Dibromo-3-chloropropane (DBCP)mg/Kg wet0.25ND
1,2-Dibromoethane (EDB)mg/Kg wet0.025ND
Dibromomethane mg/Kg wet0.050ND
1,2-Dichlorobenzene mg/Kg wet0.050ND
1,3-Dichlorobenzene mg/Kg wet0.050ND
1,4-Dichlorobenzene mg/Kg wet0.050ND
trans-1,4-Dichloro-2-butene mg/Kg wet0.10ND
Dichlorodifluoromethane (Freon 12)mg/Kg wet0.10 V-05ND
1,1-Dichloroethane mg/Kg wet0.050ND
1,2-Dichloroethane mg/Kg wet0.050ND
1,1-Dichloroethylene mg/Kg wet0.050ND
cis-1,2-Dichloroethylene mg/Kg wet0.050ND
trans-1,2-Dichloroethylene mg/Kg wet0.050ND
1,2-Dichloropropane mg/Kg wet0.050ND
1,3-Dichloropropane mg/Kg wet0.025ND
2,2-Dichloropropane mg/Kg wet0.050ND
1,1-Dichloropropene mg/Kg wet0.10ND
cis-1,3-Dichloropropene mg/Kg wet0.025ND
trans-1,3-Dichloropropene mg/Kg wet0.025ND
Diethyl Ether mg/Kg wet0.10ND
Diisopropyl Ether (DIPE)mg/Kg wet0.025ND
1,4-Dioxane mg/Kg wet2.5ND
Ethylbenzene mg/Kg wet0.050ND
Hexachlorobutadiene mg/Kg wet0.030ND
2-Hexanone (MBK)mg/Kg wet0.50ND
Isopropylbenzene (Cumene)mg/Kg wet0.050ND
p-Isopropyltoluene (p-Cymene)mg/Kg wet0.050ND
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.050ND
[TOC_1]QC Data[TOC]
Page 17 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288355 - SW-846 5035
Blank (B288355-BLK1) Prepared & Analyzed: 08/17/21
Methylene Chloride mg/Kg wet0.25ND
4-Methyl-2-pentanone (MIBK)mg/Kg wet0.50ND
Naphthalene mg/Kg wet0.10ND
n-Propylbenzene mg/Kg wet0.050ND
Styrene mg/Kg wet0.050ND
1,1,1,2-Tetrachloroethane mg/Kg wet0.050ND
1,1,2,2-Tetrachloroethane mg/Kg wet0.025ND
Tetrachloroethylene mg/Kg wet0.050ND
Tetrahydrofuran mg/Kg wet0.50ND
Toluene mg/Kg wet0.050ND
1,2,3-Trichlorobenzene mg/Kg wet0.25ND
1,2,4-Trichlorobenzene mg/Kg wet0.050ND
1,3,5-Trichlorobenzene mg/Kg wet0.050ND
1,1,1-Trichloroethane mg/Kg wet0.050ND
1,1,2-Trichloroethane mg/Kg wet0.050ND
Trichloroethylene mg/Kg wet0.050ND
Trichlorofluoromethane (Freon 11)mg/Kg wet0.10ND
1,2,3-Trichloropropane mg/Kg wet0.10ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
mg/Kg wet0.050ND
1,2,4-Trimethylbenzene mg/Kg wet0.050ND
1,3,5-Trimethylbenzene mg/Kg wet0.050ND
Vinyl Chloride mg/Kg wet0.10ND
m+p Xylene mg/Kg wet0.10ND
o-Xylene mg/Kg wet0.050ND
mg/Kg wet 0.0250 70-130Surrogate: 1,2-Dichloroethane-d4 76.20.0191
mg/Kg wet 0.0250 70-130Surrogate: Toluene-d8 92.70.0232
mg/Kg wet 0.0250 70-130Surrogate: 4-Bromofluorobenzene 98.80.0247
LCS (B288355-BS1) Prepared & Analyzed: 08/17/21
Acetone mg/Kg wet0.057 0.113 70-16093.10.105
Acrylonitrile mg/Kg wet0.0057 0.0113 70-1301140.0130
tert-Amyl Methyl Ether (TAME)mg/Kg wet0.00057 0.0113 70-1301000.0114
Benzene mg/Kg wet0.0011 0.0113 70-1301070.0121
Bromobenzene mg/Kg wet0.0011 0.0113 70-1301070.0122
Bromochloromethane mg/Kg wet0.0011 0.0113 V-2070-1301280.0145
Bromodichloromethane mg/Kg wet0.00057 0.0113 70-1301080.0122
Bromoform mg/Kg wet0.0011 0.0113 70-1301170.0132
Bromomethane mg/Kg wet0.0023 0.0113 L-02, V-3440-130133*0.0151
2-Butanone (MEK)mg/Kg wet0.023 0.113 70-1601000.114
tert-Butyl Alcohol (TBA)mg/Kg wet0.023 0.113 40-13096.40.109
n-Butylbenzene mg/Kg wet0.0011 0.0113 70-13088.50.0100
sec-Butylbenzene mg/Kg wet0.0011 0.0113 70-13089.90.0102
tert-Butylbenzene mg/Kg wet0.0011 0.0113 70-16095.40.0108
tert-Butyl Ethyl Ether (TBEE)mg/Kg wet0.00057 0.0113 70-1301020.0116
Carbon Disulfide mg/Kg wet0.0057 0.113 70-1301010.115
Carbon Tetrachloride mg/Kg wet0.0011 0.0113 70-1301030.0117
Chlorobenzene mg/Kg wet0.0011 0.0113 70-1301130.0129
Chlorodibromomethane mg/Kg wet0.00057 0.0113 70-1301120.0127
Chloroethane mg/Kg wet0.0023 0.0113 70-13098.70.0112
Chloroform mg/Kg wet0.0023 0.0113 70-1301020.0116
Chloromethane mg/Kg wet0.0023 0.0113 V-05, L-04, V-3470-13040.9 *0.00464
2-Chlorotoluene mg/Kg wet0.0011 0.0113 70-1301050.0119
Page 18 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288355 - SW-846 5035
LCS (B288355-BS1) Prepared & Analyzed: 08/17/21
4-Chlorotoluene mg/Kg wet0.0011 0.0113 70-1301060.0120
1,2-Dibromo-3-chloropropane (DBCP)mg/Kg wet0.0057 0.0113 70-13087.10.00987
1,2-Dibromoethane (EDB)mg/Kg wet0.00057 0.0113 70-1301200.0135
Dibromomethane mg/Kg wet0.0011 0.0113 70-1301130.0128
1,2-Dichlorobenzene mg/Kg wet0.0011 0.0113 70-13099.80.0113
1,3-Dichlorobenzene mg/Kg wet0.0011 0.0113 70-1301000.0114
1,4-Dichlorobenzene mg/Kg wet0.0011 0.0113 70-13098.90.0112
trans-1,4-Dichloro-2-butene mg/Kg wet0.0023 0.0113 70-1301150.0130
Dichlorodifluoromethane (Freon 12)mg/Kg wet0.0023 0.0113 V-0540-16088.30.0100
1,1-Dichloroethane mg/Kg wet0.0011 0.0113 70-1301060.0121
1,2-Dichloroethane mg/Kg wet0.0011 0.0113 70-1301040.0118
1,1-Dichloroethylene mg/Kg wet0.0011 0.0113 70-1301010.0115
cis-1,2-Dichloroethylene mg/Kg wet0.0011 0.0113 70-1301080.0122
trans-1,2-Dichloroethylene mg/Kg wet0.0011 0.0113 70-1301120.0126
1,2-Dichloropropane mg/Kg wet0.0011 0.0113 70-1301160.0132
1,3-Dichloropropane mg/Kg wet0.00057 0.0113 70-1301130.0128
2,2-Dichloropropane mg/Kg wet0.0011 0.0113 70-1301010.0114
1,1-Dichloropropene mg/Kg wet0.0023 0.0113 70-1301060.0120
cis-1,3-Dichloropropene mg/Kg wet0.00057 0.0113 70-1301120.0127
trans-1,3-Dichloropropene mg/Kg wet0.00057 0.0113 70-1301080.0122
Diethyl Ether mg/Kg wet0.0023 0.0113 70-13099.00.0112
Diisopropyl Ether (DIPE)mg/Kg wet0.00057 0.0113 70-1301060.0120
1,4-Dioxane mg/Kg wet0.057 0.113 40-1601070.121
Ethylbenzene mg/Kg wet0.0011 0.0113 70-1301080.0122
Hexachlorobutadiene mg/Kg wet0.00068 0.0113 70-1601000.0114
2-Hexanone (MBK)mg/Kg wet0.011 0.113 70-1601000.114
Isopropylbenzene (Cumene)mg/Kg wet0.0011 0.0113 70-1301090.0123
p-Isopropyltoluene (p-Cymene)mg/Kg wet0.0011 0.0113 70-13096.70.0110
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.0011 0.0113 70-1301010.0114
Methylene Chloride mg/Kg wet0.0057 0.0113 40-1601030.0116
4-Methyl-2-pentanone (MIBK)mg/Kg wet0.011 0.113 70-1601070.121
Naphthalene mg/Kg wet0.0023 0.0113 40-13083.80.00950
n-Propylbenzene mg/Kg wet0.0011 0.0113 70-1301040.0118
Styrene mg/Kg wet0.0011 0.0113 70-1301130.0129
1,1,1,2-Tetrachloroethane mg/Kg wet0.0011 0.0113 70-1301220.0138
1,1,2,2-Tetrachloroethane mg/Kg wet0.00057 0.0113 70-1301120.0126
Tetrachloroethylene mg/Kg wet0.0011 0.0113 70-1301300.0147
Tetrahydrofuran mg/Kg wet0.011 0.0113 70-1301020.0115
Toluene mg/Kg wet0.0011 0.0113 70-1301130.0129
1,2,3-Trichlorobenzene mg/Kg wet0.0057 0.0113 70-13092.30.0105
1,2,4-Trichlorobenzene mg/Kg wet0.0011 0.0113 70-13098.70.0112
1,3,5-Trichlorobenzene mg/Kg wet0.0011 0.0113 70-1301020.0115
1,1,1-Trichloroethane mg/Kg wet0.0011 0.0113 70-1301020.0116
1,1,2-Trichloroethane mg/Kg wet0.0011 0.0113 70-1301160.0131
Trichloroethylene mg/Kg wet0.0011 0.0113 70-1301160.0131
Trichlorofluoromethane (Freon 11)mg/Kg wet0.0023 0.0113 70-13093.30.0106
1,2,3-Trichloropropane mg/Kg wet0.0023 0.0113 70-1301230.0140
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
mg/Kg wet0.0011 0.0113 70-1301060.0120
1,2,4-Trimethylbenzene mg/Kg wet0.0011 0.0113 70-13094.90.0108
1,3,5-Trimethylbenzene mg/Kg wet0.0011 0.0113 70-1301090.0124
Vinyl Chloride mg/Kg wet0.0023 0.0113 40-13099.80.0113
Page 19 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288355 - SW-846 5035
LCS (B288355-BS1) Prepared & Analyzed: 08/17/21
m+p Xylene mg/Kg wet0.0023 0.0227 70-1301110.0252
o-Xylene mg/Kg wet0.0011 0.0113 70-1301070.0121
mg/Kg wet 0.0283 70-130Surrogate: 1,2-Dichloroethane-d4 75.00.0212
mg/Kg wet 0.0283 70-130Surrogate: Toluene-d8 95.00.0269
mg/Kg wet 0.0283 70-130Surrogate: 4-Bromofluorobenzene 99.90.0283
LCS Dup (B288355-BSD1) Prepared & Analyzed: 08/17/21
Acetone mg/Kg wet0.057 0.113 2570-16094.6 1.660.107
Acrylonitrile mg/Kg wet0.0057 0.0113 2570-130115 0.5240.0130
tert-Amyl Methyl Ether (TAME)mg/Kg wet0.00057 0.0113 2570-13099.7 0.6000.0113
Benzene mg/Kg wet0.0011 0.0113 2570-130107 0.2810.0121
Bromobenzene mg/Kg wet0.0011 0.0113 2570-130103 3.800.0117
Bromochloromethane mg/Kg wet0.0011 0.0113 25 V-2070-130127 0.8620.0144
Bromodichloromethane mg/Kg wet0.00057 0.0113 2570-130105 2.540.0119
Bromoform mg/Kg wet0.0011 0.0113 2570-130114 2.260.0129
Bromomethane mg/Kg wet0.0023 0.0113 25 L-02, V-3440-130136 1.71*0.0154
2-Butanone (MEK)mg/Kg wet0.023 0.113 2570-160100 0.1500.113
tert-Butyl Alcohol (TBA)mg/Kg wet0.023 0.113 2540-13097.5 1.130.111
n-Butylbenzene mg/Kg wet0.0011 0.0113 2570-13087.4 1.250.00991
sec-Butylbenzene mg/Kg wet0.0011 0.0113 2570-13090.0 0.1110.0102
tert-Butylbenzene mg/Kg wet0.0011 0.0113 2570-16094.2 1.270.0107
tert-Butyl Ethyl Ether (TBEE)mg/Kg wet0.00057 0.0113 2570-130106 3.930.0120
Carbon Disulfide mg/Kg wet0.0057 0.113 2570-130100 1.030.113
Carbon Tetrachloride mg/Kg wet0.0011 0.0113 2570-130101 1.670.0115
Chlorobenzene mg/Kg wet0.0011 0.0113 2570-130112 1.690.0126
Chlorodibromomethane mg/Kg wet0.00057 0.0113 2570-130111 0.5380.0126
Chloroethane mg/Kg wet0.0023 0.0113 2570-13095.3 3.510.0108
Chloroform mg/Kg wet0.0023 0.0113 2570-130102 0.09770.0116
Chloromethane mg/Kg wet0.0023 0.0113 25 V-34, L-04, V-0570-13040.8 0.245*0.00462
2-Chlorotoluene mg/Kg wet0.0011 0.0113 2570-130106 0.6640.0120
4-Chlorotoluene mg/Kg wet0.0011 0.0113 2570-130105 1.420.0119
1,2-Dibromo-3-chloropropane (DBCP)mg/Kg wet0.0057 0.0113 2570-13085.5 1.850.00969
1,2-Dibromoethane (EDB)mg/Kg wet0.00057 0.0113 2570-130117 2.110.0133
Dibromomethane mg/Kg wet0.0011 0.0113 2570-130115 1.580.0130
1,2-Dichlorobenzene mg/Kg wet0.0011 0.0113 2570-13098.2 1.620.0111
1,3-Dichlorobenzene mg/Kg wet0.0011 0.0113 2570-130100 0.1990.0114
1,4-Dichlorobenzene mg/Kg wet0.0011 0.0113 2570-13098.6 0.3040.0112
trans-1,4-Dichloro-2-butene mg/Kg wet0.0023 0.0113 2570-130114 0.5240.0129
Dichlorodifluoromethane (Freon 12)mg/Kg wet0.0023 0.0113 25 V-0540-16085.4 3.340.00968
1,1-Dichloroethane mg/Kg wet0.0011 0.0113 2570-130107 0.09380.0121
1,2-Dichloroethane mg/Kg wet0.0011 0.0113 2570-130104 0.09600.0118
1,1-Dichloroethylene mg/Kg wet0.0011 0.0113 2570-13098.4 2.810.0112
cis-1,2-Dichloroethylene mg/Kg wet0.0011 0.0113 2570-130106 1.500.0120
trans-1,2-Dichloroethylene mg/Kg wet0.0011 0.0113 2570-130112 0.6260.0127
1,2-Dichloropropane mg/Kg wet0.0011 0.0113 2570-130117 0.6850.0133
1,3-Dichloropropane mg/Kg wet0.00057 0.0113 2570-130113 0.5310.0128
2,2-Dichloropropane mg/Kg wet0.0011 0.0113 2570-13095.8 5.090.0109
1,1-Dichloropropene mg/Kg wet0.0023 0.0113 2570-130105 0.7610.0119
cis-1,3-Dichloropropene mg/Kg wet0.00057 0.0113 2570-130113 1.070.0128
trans-1,3-Dichloropropene mg/Kg wet0.00057 0.0113 2570-130106 1.400.0121
Diethyl Ether mg/Kg wet0.0023 0.0113 2570-130104 5.020.0118
Diisopropyl Ether (DIPE)mg/Kg wet0.00057 0.0113 2570-130104 1.900.0118
Page 20 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288355 - SW-846 5035
LCS Dup (B288355-BSD1) Prepared & Analyzed: 08/17/21
1,4-Dioxane mg/Kg wet0.057 0.113 5040-160112 5.200.127
Ethylbenzene mg/Kg wet0.0011 0.0113 2570-130108 0.09250.0123
Hexachlorobutadiene mg/Kg wet0.00068 0.0113 2570-16097.0 3.250.0110
2-Hexanone (MBK)mg/Kg wet0.011 0.113 2570-160101 0.2290.114
Isopropylbenzene (Cumene)mg/Kg wet0.0011 0.0113 2570-130106 2.320.0121
p-Isopropyltoluene (p-Cymene)mg/Kg wet0.0011 0.0113 2570-13095.0 1.770.0108
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.0011 0.0113 2570-130102 1.480.0116
Methylene Chloride mg/Kg wet0.0057 0.0113 2540-160102 0.3900.0116
4-Methyl-2-pentanone (MIBK)mg/Kg wet0.011 0.113 2570-160105 1.190.119
Naphthalene mg/Kg wet0.0023 0.0113 2540-13084.4 0.7130.00957
n-Propylbenzene mg/Kg wet0.0011 0.0113 2570-130104 0.8660.0117
Styrene mg/Kg wet0.0011 0.0113 2570-130113 0.5310.0128
1,1,1,2-Tetrachloroethane mg/Kg wet0.0011 0.0113 2570-130120 2.150.0135
1,1,2,2-Tetrachloroethane mg/Kg wet0.00057 0.0113 2570-130109 2.080.0124
Tetrachloroethylene mg/Kg wet0.0011 0.0113 2570-130125 3.610.0142
Tetrahydrofuran mg/Kg wet0.011 0.0113 2570-130101 1.090.0114
Toluene mg/Kg wet0.0011 0.0113 2570-130112 1.060.0127
1,2,3-Trichlorobenzene mg/Kg wet0.0057 0.0113 2570-13092.2 0.1080.0104
1,2,4-Trichlorobenzene mg/Kg wet0.0011 0.0113 2570-130102 2.990.0115
1,3,5-Trichlorobenzene mg/Kg wet0.0011 0.0113 2570-130103 1.270.0117
1,1,1-Trichloroethane mg/Kg wet0.0011 0.0113 2570-13098.0 4.200.0111
1,1,2-Trichloroethane mg/Kg wet0.0011 0.0113 2570-130118 1.720.0133
Trichloroethylene mg/Kg wet0.0011 0.0113 2570-130116 0.1730.0131
Trichlorofluoromethane (Freon 11)mg/Kg wet0.0023 0.0113 2570-13093.9 0.6410.0106
1,2,3-Trichloropropane mg/Kg wet0.0023 0.0113 2570-130116 6.190.0131
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
mg/Kg wet0.0011 0.0113 2570-130103 2.880.0116
1,2,4-Trimethylbenzene mg/Kg wet0.0011 0.0113 2570-13094.3 0.6340.0107
1,3,5-Trimethylbenzene mg/Kg wet0.0011 0.0113 2570-130108 1.470.0122
Vinyl Chloride mg/Kg wet0.0023 0.0113 2540-13096.5 3.360.0109
m+p Xylene mg/Kg wet0.0023 0.0227 2570-130110 0.9950.0249
o-Xylene mg/Kg wet0.0011 0.0113 2570-130106 1.040.0120
mg/Kg wet 0.0283 70-130Surrogate: 1,2-Dichloroethane-d4 77.80.0220
mg/Kg wet 0.0283 70-130Surrogate: Toluene-d8 94.60.0268
mg/Kg wet 0.0283 70-130Surrogate: 4-Bromofluorobenzene 99.00.0281
Page 21 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Semivolatile Organic Compounds by GC/MS[TOC]
Batch B288487 - SW-846 3546
[TOC_3]B288487[TOC]
Blank (B288487-BLK1) Prepared: 08/18/21 Analyzed: 08/19/21
Acenaphthene mg/Kg wet0.17ND
Acenaphthylene mg/Kg wet0.17ND
Acetophenone mg/Kg wet0.34ND
Aniline mg/Kg wet0.34ND
Anthracene mg/Kg wet0.17ND
Benzidine mg/Kg wet0.66 V-04ND
Benzo(a)anthracene mg/Kg wet0.17ND
Benzo(a)pyrene mg/Kg wet0.17ND
Benzo(b)fluoranthene mg/Kg wet0.17ND
Benzo(g,h,i)perylene mg/Kg wet0.17ND
Benzo(k)fluoranthene mg/Kg wet0.17ND
Benzoic Acid mg/Kg wet1.0ND
Bis(2-chloroethoxy)methane mg/Kg wet0.34ND
Bis(2-chloroethyl)ether mg/Kg wet0.34ND
Bis(2-chloroisopropyl)ether mg/Kg wet0.34ND
Bis(2-Ethylhexyl)phthalate mg/Kg wet0.34ND
4-Bromophenylphenylether mg/Kg wet0.34ND
Butylbenzylphthalate mg/Kg wet0.34ND
Carbazole mg/Kg wet0.17ND
4-Chloroaniline mg/Kg wet0.66 V-34ND
4-Chloro-3-methylphenol mg/Kg wet0.66ND
2-Chloronaphthalene mg/Kg wet0.34ND
2-Chlorophenol mg/Kg wet0.34ND
4-Chlorophenylphenylether mg/Kg wet0.34ND
Chrysene mg/Kg wet0.17ND
Dibenz(a,h)anthracene mg/Kg wet0.17ND
Dibenzofuran mg/Kg wet0.34ND
Di-n-butylphthalate mg/Kg wet0.34ND
1,2-Dichlorobenzene mg/Kg wet0.34ND
1,3-Dichlorobenzene mg/Kg wet0.34ND
1,4-Dichlorobenzene mg/Kg wet0.34ND
3,3-Dichlorobenzidine mg/Kg wet0.17ND
2,4-Dichlorophenol mg/Kg wet0.34ND
Diethylphthalate mg/Kg wet0.34ND
2,4-Dimethylphenol mg/Kg wet0.34ND
Dimethylphthalate mg/Kg wet0.34ND
4,6-Dinitro-2-methylphenol mg/Kg wet0.34ND
2,4-Dinitrophenol mg/Kg wet0.66ND
2,4-Dinitrotoluene mg/Kg wet0.34ND
2,6-Dinitrotoluene mg/Kg wet0.34ND
Di-n-octylphthalate mg/Kg wet0.34ND
1,2-Diphenylhydrazine/Azobenzene mg/Kg wet0.34ND
Fluoranthene mg/Kg wet0.17ND
Fluorene mg/Kg wet0.17ND
Hexachlorobenzene mg/Kg wet0.34ND
Hexachlorobutadiene mg/Kg wet0.34ND
Hexachlorocyclopentadiene mg/Kg wet0.34ND
Hexachloroethane mg/Kg wet0.34ND
Indeno(1,2,3-cd)pyrene mg/Kg wet0.17ND
Isophorone mg/Kg wet0.34ND
1-Methylnaphthalene mg/Kg wet0.17ND
2-Methylnaphthalene mg/Kg wet0.17ND
Page 22 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288487 - SW-846 3546
Blank (B288487-BLK1) Prepared: 08/18/21 Analyzed: 08/19/21
2-Methylphenol mg/Kg wet0.34ND
3/4-Methylphenol mg/Kg wet0.34ND
Naphthalene mg/Kg wet0.17ND
2-Nitroaniline mg/Kg wet0.34ND
3-Nitroaniline mg/Kg wet0.34ND
4-Nitroaniline mg/Kg wet0.34ND
Nitrobenzene mg/Kg wet0.34ND
2-Nitrophenol mg/Kg wet0.34ND
4-Nitrophenol mg/Kg wet0.66ND
N-Nitrosodimethylamine mg/Kg wet0.34ND
N-Nitrosodiphenylamine/Diphenylamine mg/Kg wet0.34ND
N-Nitrosodi-n-propylamine mg/Kg wet0.34ND
Pentachloronitrobenzene mg/Kg wet0.34ND
Pentachlorophenol mg/Kg wet0.34ND
Phenanthrene mg/Kg wet0.17ND
Phenol mg/Kg wet0.34ND
Pyrene mg/Kg wet0.17ND
Pyridine mg/Kg wet0.34ND
1,2,4,5-Tetrachlorobenzene mg/Kg wet0.34ND
1,2,4-Trichlorobenzene mg/Kg wet0.34ND
2,4,5-Trichlorophenol mg/Kg wet0.34ND
2,4,6-Trichlorophenol mg/Kg wet0.34ND
mg/Kg wet 6.67 30-130Surrogate: 2-Fluorophenol 74.24.95
mg/Kg wet 6.67 30-130Surrogate: Phenol-d6 79.35.28
mg/Kg wet 3.33 30-130Surrogate: Nitrobenzene-d5 75.92.53
mg/Kg wet 3.33 30-130Surrogate: 2-Fluorobiphenyl 74.02.47
mg/Kg wet 6.67 30-130Surrogate: 2,4,6-Tribromophenol 71.84.79
mg/Kg wet 3.33 30-130Surrogate: p-Terphenyl-d14 83.32.78
LCS (B288487-BS1) Prepared: 08/18/21 Analyzed: 08/19/21
Acenaphthene mg/Kg wet0.17 1.67 40-14080.91.35
Acenaphthylene mg/Kg wet0.17 1.67 40-14082.61.38
Acetophenone mg/Kg wet0.34 1.67 40-14083.31.39
Aniline mg/Kg wet0.34 1.67 10-14067.51.13
Anthracene mg/Kg wet0.17 1.67 40-14084.61.41
Benzidine mg/Kg wet0.66 1.67 V-0440-1401141.89
Benzo(a)anthracene mg/Kg wet0.17 1.67 40-14080.71.34
Benzo(a)pyrene mg/Kg wet0.17 1.67 40-14091.41.52
Benzo(b)fluoranthene mg/Kg wet0.17 1.67 40-14084.11.40
Benzo(g,h,i)perylene mg/Kg wet0.17 1.67 40-14088.61.48
Benzo(k)fluoranthene mg/Kg wet0.17 1.67 40-14084.51.41
Benzoic Acid mg/Kg wet1.0 1.67 J30-13040.80.681
Bis(2-chloroethoxy)methane mg/Kg wet0.34 1.67 40-14080.31.34
Bis(2-chloroethyl)ether mg/Kg wet0.34 1.67 40-14082.61.38
Bis(2-chloroisopropyl)ether mg/Kg wet0.34 1.67 40-14096.31.60
Bis(2-Ethylhexyl)phthalate mg/Kg wet0.34 1.67 40-14081.01.35
4-Bromophenylphenylether mg/Kg wet0.34 1.67 40-14074.61.24
Butylbenzylphthalate mg/Kg wet0.34 1.67 40-14080.11.34
Carbazole mg/Kg wet0.17 1.67 40-14085.91.43
4-Chloroaniline mg/Kg wet0.66 1.67 V-3410-14060.21.00
4-Chloro-3-methylphenol mg/Kg wet0.66 1.67 30-13088.91.48
2-Chloronaphthalene mg/Kg wet0.34 1.67 40-14076.61.28
Page 23 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288487 - SW-846 3546
LCS (B288487-BS1) Prepared: 08/18/21 Analyzed: 08/19/21
2-Chlorophenol mg/Kg wet0.34 1.67 30-13077.51.29
4-Chlorophenylphenylether mg/Kg wet0.34 1.67 40-14081.91.37
Chrysene mg/Kg wet0.17 1.67 40-14080.61.34
Dibenz(a,h)anthracene mg/Kg wet0.17 1.67 40-14092.61.54
Dibenzofuran mg/Kg wet0.34 1.67 40-14086.81.45
Di-n-butylphthalate mg/Kg wet0.34 1.67 40-14078.61.31
1,2-Dichlorobenzene mg/Kg wet0.34 1.67 40-14071.81.20
1,3-Dichlorobenzene mg/Kg wet0.34 1.67 40-14068.61.14
1,4-Dichlorobenzene mg/Kg wet0.34 1.67 40-14069.21.15
3,3-Dichlorobenzidine mg/Kg wet0.17 1.67 20-14071.01.18
2,4-Dichlorophenol mg/Kg wet0.34 1.67 30-13080.71.35
Diethylphthalate mg/Kg wet0.34 1.67 40-14086.41.44
2,4-Dimethylphenol mg/Kg wet0.34 1.67 30-13082.41.37
Dimethylphthalate mg/Kg wet0.34 1.67 40-14083.41.39
4,6-Dinitro-2-methylphenol mg/Kg wet0.34 1.67 30-13072.01.20
2,4-Dinitrophenol mg/Kg wet0.66 1.67 30-13063.61.06
2,4-Dinitrotoluene mg/Kg wet0.34 1.67 40-14093.61.56
2,6-Dinitrotoluene mg/Kg wet0.34 1.67 40-14093.11.55
Di-n-octylphthalate mg/Kg wet0.34 1.67 40-14081.31.36
1,2-Diphenylhydrazine/Azobenzene mg/Kg wet0.34 1.67 40-14083.01.38
Fluoranthene mg/Kg wet0.17 1.67 40-14086.31.44
Fluorene mg/Kg wet0.17 1.67 40-14088.01.47
Hexachlorobenzene mg/Kg wet0.34 1.67 40-14079.11.32
Hexachlorobutadiene mg/Kg wet0.34 1.67 40-14070.11.17
Hexachlorocyclopentadiene mg/Kg wet0.34 1.67 40-14068.11.14
Hexachloroethane mg/Kg wet0.34 1.67 40-14071.61.19
Indeno(1,2,3-cd)pyrene mg/Kg wet0.17 1.67 40-14097.21.62
Isophorone mg/Kg wet0.34 1.67 40-14083.51.39
1-Methylnaphthalene mg/Kg wet0.17 1.67 40-14073.21.22
2-Methylnaphthalene mg/Kg wet0.17 1.67 40-14087.01.45
2-Methylphenol mg/Kg wet0.34 1.67 30-13088.91.48
3/4-Methylphenol mg/Kg wet0.34 1.67 30-13094.41.57
Naphthalene mg/Kg wet0.17 1.67 40-14076.71.28
2-Nitroaniline mg/Kg wet0.34 1.67 40-1401181.97
3-Nitroaniline mg/Kg wet0.34 1.67 30-14082.41.37
4-Nitroaniline mg/Kg wet0.34 1.67 40-1401011.68
Nitrobenzene mg/Kg wet0.34 1.67 40-14079.61.33
2-Nitrophenol mg/Kg wet0.34 1.67 30-13078.11.30
4-Nitrophenol mg/Kg wet0.66 1.67 30-1301001.67
N-Nitrosodimethylamine mg/Kg wet0.34 1.67 40-14081.61.36
N-Nitrosodiphenylamine/Diphenylamine mg/Kg wet0.34 1.67 40-14083.81.40
N-Nitrosodi-n-propylamine mg/Kg wet0.34 1.67 40-14089.41.49
Pentachloronitrobenzene mg/Kg wet0.34 1.67 40-14083.81.40
Pentachlorophenol mg/Kg wet0.34 1.67 30-13075.21.25
Phenanthrene mg/Kg wet0.17 1.67 40-14083.01.38
Phenol mg/Kg wet0.34 1.67 30-13084.41.41
Pyrene mg/Kg wet0.17 1.67 40-14083.01.38
Pyridine mg/Kg wet0.34 1.67 30-14042.20.703
1,2,4,5-Tetrachlorobenzene mg/Kg wet0.34 1.67 40-14071.11.19
1,2,4-Trichlorobenzene mg/Kg wet0.34 1.67 40-14070.21.17
2,4,5-Trichlorophenol mg/Kg wet0.34 1.67 30-13085.81.43
2,4,6-Trichlorophenol mg/Kg wet0.34 1.67 30-13082.21.37
Page 24 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288487 - SW-846 3546
LCS (B288487-BS1) Prepared: 08/18/21 Analyzed: 08/19/21
mg/Kg wet 6.67 30-130Surrogate: 2-Fluorophenol 86.45.76
mg/Kg wet 6.67 30-130Surrogate: Phenol-d6 93.66.24
mg/Kg wet 3.33 30-130Surrogate: Nitrobenzene-d5 85.12.84
mg/Kg wet 3.33 30-130Surrogate: 2-Fluorobiphenyl 80.02.67
mg/Kg wet 6.67 30-130Surrogate: 2,4,6-Tribromophenol 97.46.50
mg/Kg wet 3.33 30-130Surrogate: p-Terphenyl-d14 84.42.81
LCS Dup (B288487-BSD1) Prepared: 08/18/21 Analyzed: 08/19/21
Acenaphthene mg/Kg wet0.17 1.67 3040-14081.1 0.1981.35
Acenaphthylene mg/Kg wet0.17 1.67 3040-14081.9 0.8761.36
Acetophenone mg/Kg wet0.34 1.67 3040-14081.6 2.091.36
Aniline mg/Kg wet0.34 1.67 5010-14078.5 15.01.31
Anthracene mg/Kg wet0.17 1.67 3040-14084.7 0.09451.41
Benzidine mg/Kg wet0.66 1.67 30 V-0440-140123 8.262.06
Benzo(a)anthracene mg/Kg wet0.17 1.67 3040-14081.3 0.7901.36
Benzo(a)pyrene mg/Kg wet0.17 1.67 3040-14091.8 0.4801.53
Benzo(b)fluoranthene mg/Kg wet0.17 1.67 3040-14086.6 2.981.44
Benzo(g,h,i)perylene mg/Kg wet0.17 1.67 3040-14089.1 0.5631.49
Benzo(k)fluoranthene mg/Kg wet0.17 1.67 3040-14086.7 2.591.44
Benzoic Acid mg/Kg wet1.0 1.67 50 J30-13040.3 1.230.672
Bis(2-chloroethoxy)methane mg/Kg wet0.34 1.67 3040-14081.0 0.9671.35
Bis(2-chloroethyl)ether mg/Kg wet0.34 1.67 3040-14080.9 2.181.35
Bis(2-chloroisopropyl)ether mg/Kg wet0.34 1.67 3040-14095.5 0.8551.59
Bis(2-Ethylhexyl)phthalate mg/Kg wet0.34 1.67 3040-14094.2 15.11.57
4-Bromophenylphenylether mg/Kg wet0.34 1.67 3040-14078.9 5.551.31
Butylbenzylphthalate mg/Kg wet0.34 1.67 3040-14089.7 11.31.50
Carbazole mg/Kg wet0.17 1.67 3040-14085.9 0.06981.43
4-Chloroaniline mg/Kg wet0.66 1.67 30 V-3410-14054.9 9.170.915
4-Chloro-3-methylphenol mg/Kg wet0.66 1.67 3030-13085.4 4.061.42
2-Chloronaphthalene mg/Kg wet0.34 1.67 3040-14077.0 0.5731.28
2-Chlorophenol mg/Kg wet0.34 1.67 3030-13076.9 0.8551.28
4-Chlorophenylphenylether mg/Kg wet0.34 1.67 3040-14084.8 3.481.41
Chrysene mg/Kg wet0.17 1.67 3040-14081.0 0.4701.35
Dibenz(a,h)anthracene mg/Kg wet0.17 1.67 3040-14094.0 1.441.57
Dibenzofuran mg/Kg wet0.34 1.67 3040-14085.3 1.791.42
Di-n-butylphthalate mg/Kg wet0.34 1.67 3040-14085.6 8.531.43
1,2-Dichlorobenzene mg/Kg wet0.34 1.67 3040-14071.4 0.5871.19
1,3-Dichlorobenzene mg/Kg wet0.34 1.67 3040-14068.1 0.7601.14
1,4-Dichlorobenzene mg/Kg wet0.34 1.67 3040-14068.8 0.5801.15
3,3-Dichlorobenzidine mg/Kg wet0.17 1.67 5020-14071.0 0.001.18
2,4-Dichlorophenol mg/Kg wet0.34 1.67 3030-13078.7 2.531.31
Diethylphthalate mg/Kg wet0.34 1.67 3040-14085.7 0.8831.43
2,4-Dimethylphenol mg/Kg wet0.34 1.67 3030-13079.1 4.161.32
Dimethylphthalate mg/Kg wet0.34 1.67 3040-14084.4 1.241.41
4,6-Dinitro-2-methylphenol mg/Kg wet0.34 1.67 3030-13072.3 0.3601.20
2,4-Dinitrophenol mg/Kg wet0.66 1.67 3030-13060.3 5.331.00
2,4-Dinitrotoluene mg/Kg wet0.34 1.67 3040-14091.4 2.381.52
2,6-Dinitrotoluene mg/Kg wet0.34 1.67 3040-14091.6 1.621.53
Di-n-octylphthalate mg/Kg wet0.34 1.67 3040-14098.8 19.41.65
1,2-Diphenylhydrazine/Azobenzene mg/Kg wet0.34 1.67 3040-14088.4 6.261.47
Fluoranthene mg/Kg wet0.17 1.67 3040-14085.3 1.141.42
Fluorene mg/Kg wet0.17 1.67 3040-14087.6 0.3871.46
Page 25 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288487 - SW-846 3546
LCS Dup (B288487-BSD1) Prepared: 08/18/21 Analyzed: 08/19/21
Hexachlorobenzene mg/Kg wet0.34 1.67 3040-14082.2 3.791.37
Hexachlorobutadiene mg/Kg wet0.34 1.67 3040-14071.9 2.511.20
Hexachlorocyclopentadiene mg/Kg wet0.34 1.67 3040-14076.1 11.01.27
Hexachloroethane mg/Kg wet0.34 1.67 3040-14072.5 1.251.21
Indeno(1,2,3-cd)pyrene mg/Kg wet0.17 1.67 3040-14099.7 2.521.66
Isophorone mg/Kg wet0.34 1.67 3040-14082.7 0.9141.38
1-Methylnaphthalene mg/Kg wet0.17 1.67 3040-14071.4 2.431.19
2-Methylnaphthalene mg/Kg wet0.17 1.67 3040-14088.2 1.371.47
2-Methylphenol mg/Kg wet0.34 1.67 3030-13085.2 4.251.42
3/4-Methylphenol mg/Kg wet0.34 1.67 3030-13089.2 5.641.49
Naphthalene mg/Kg wet0.17 1.67 3040-14075.1 2.111.25
2-Nitroaniline mg/Kg wet0.34 1.67 3040-140116 1.851.93
3-Nitroaniline mg/Kg wet0.34 1.67 3030-14079.8 3.161.33
4-Nitroaniline mg/Kg wet0.34 1.67 3040-14093.9 7.331.56
Nitrobenzene mg/Kg wet0.34 1.67 3040-14075.9 4.681.27
2-Nitrophenol mg/Kg wet0.34 1.67 3030-13076.2 2.461.27
4-Nitrophenol mg/Kg wet0.66 1.67 5030-13087.6 13.51.46
N-Nitrosodimethylamine mg/Kg wet0.34 1.67 3040-14076.6 6.221.28
N-Nitrosodiphenylamine/Diphenylamine mg/Kg wet0.34 1.67 3040-14087.1 3.841.45
N-Nitrosodi-n-propylamine mg/Kg wet0.34 1.67 3040-14087.7 1.991.46
Pentachloronitrobenzene mg/Kg wet0.34 1.67 3040-14087.4 4.211.46
Pentachlorophenol mg/Kg wet0.34 1.67 3030-13077.0 2.291.28
Phenanthrene mg/Kg wet0.17 1.67 3040-14084.0 1.201.40
Phenol mg/Kg wet0.34 1.67 3030-13081.5 3.541.36
Pyrene mg/Kg wet0.17 1.67 3040-14086.4 3.991.44
Pyridine mg/Kg wet0.34 1.67 3030-14040.1 4.910.669
1,2,4,5-Tetrachlorobenzene mg/Kg wet0.34 1.67 3040-14074.7 4.881.24
1,2,4-Trichlorobenzene mg/Kg wet0.34 1.67 3040-14072.0 2.481.20
2,4,5-Trichlorophenol mg/Kg wet0.34 1.67 3030-13088.1 2.641.47
2,4,6-Trichlorophenol mg/Kg wet0.34 1.67 3030-13081.6 0.7081.36
mg/Kg wet 6.67 30-130Surrogate: 2-Fluorophenol 83.75.58
mg/Kg wet 6.67 30-130Surrogate: Phenol-d6 88.85.92
mg/Kg wet 3.33 30-130Surrogate: Nitrobenzene-d5 82.92.76
mg/Kg wet 3.33 30-130Surrogate: 2-Fluorobiphenyl 84.82.83
mg/Kg wet 6.67 30-130Surrogate: 2,4,6-Tribromophenol 99.06.60
mg/Kg wet 3.33 30-130Surrogate: p-Terphenyl-d14 92.03.07
Page 26 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - EPH[TOC]
Batch B288346 - SW-846 3546
[TOC_3]B288346[TOC]
Blank (B288346-BLK1) Prepared: 08/17/21 Analyzed: 08/20/21
C9-C18 Aliphatics mg/Kg wet10ND
C19-C36 Aliphatics mg/Kg wet10ND
Unadjusted C11-C22 Aromatics mg/Kg wet10ND
C11-C22 Aromatics mg/Kg wet10ND
Acenaphthene mg/Kg wet0.10ND
Acenaphthylene mg/Kg wet0.10ND
Anthracene mg/Kg wet0.10ND
Benzo(a)anthracene mg/Kg wet0.10ND
Benzo(a)pyrene mg/Kg wet0.10ND
Benzo(b)fluoranthene mg/Kg wet0.10ND
Benzo(g,h,i)perylene mg/Kg wet0.10ND
Benzo(k)fluoranthene mg/Kg wet0.10ND
Chrysene mg/Kg wet0.10ND
Dibenz(a,h)anthracene mg/Kg wet0.10ND
Fluoranthene mg/Kg wet0.10ND
Fluorene mg/Kg wet0.10ND
Indeno(1,2,3-cd)pyrene mg/Kg wet0.10ND
2-Methylnaphthalene mg/Kg wet0.10ND
Naphthalene mg/Kg wet0.10ND
Phenanthrene mg/Kg wet0.10ND
Pyrene mg/Kg wet0.10ND
Naphthalene-aliphatic fraction mg/Kg wet0.10ND
2-Methylnaphthalene-aliphatic fraction mg/Kg wet0.10ND
mg/Kg wet 5.00 40-140Surrogate: Chlorooctadecane (COD)68.03.40
mg/Kg wet 5.00 40-140Surrogate: o-Terphenyl (OTP)90.94.54
mg/Kg wet 5.00 40-140Surrogate: 2-Bromonaphthalene 1095.44
mg/Kg wet 5.00 40-140Surrogate: 2-Fluorobiphenyl 1105.52
LCS (B288346-BS1) Prepared: 08/17/21 Analyzed: 08/20/21
C9-C18 Aliphatics mg/Kg wet10 30.0 40-14077.523.3
C19-C36 Aliphatics mg/Kg wet10 40.0 40-14079.831.9
Unadjusted C11-C22 Aromatics mg/Kg wet10 85.0 40-14081.769.4
Acenaphthene mg/Kg wet0.10 5.00 40-14067.53.38
Acenaphthylene mg/Kg wet0.10 5.00 40-14063.23.16
Anthracene mg/Kg wet0.10 5.00 40-14073.23.66
Benzo(a)anthracene mg/Kg wet0.10 5.00 40-14089.64.48
Benzo(a)pyrene mg/Kg wet0.10 5.00 40-14087.44.37
Benzo(b)fluoranthene mg/Kg wet0.10 5.00 40-14084.44.22
Benzo(g,h,i)perylene mg/Kg wet0.10 5.00 40-14082.04.10
Benzo(k)fluoranthene mg/Kg wet0.10 5.00 40-14081.94.09
Chrysene mg/Kg wet0.10 5.00 40-14084.64.23
Dibenz(a,h)anthracene mg/Kg wet0.10 5.00 40-14087.94.40
Fluoranthene mg/Kg wet0.10 5.00 40-14078.53.93
Fluorene mg/Kg wet0.10 5.00 40-14068.73.44
Indeno(1,2,3-cd)pyrene mg/Kg wet0.10 5.00 40-14081.54.08
2-Methylnaphthalene mg/Kg wet0.10 5.00 40-14061.33.06
Naphthalene mg/Kg wet0.10 5.00 40-14056.82.84
Phenanthrene mg/Kg wet0.10 5.00 40-14075.53.78
Pyrene mg/Kg wet0.10 5.00 40-14081.14.05
Naphthalene-aliphatic fraction mg/Kg wet0.10 5.00 0-5ND
2-Methylnaphthalene-aliphatic fraction mg/Kg wet0.10 5.00 0-5ND
mg/Kg wet 5.00 40-140Surrogate: Chlorooctadecane (COD)72.23.61
Page 27 of 43
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
Batch B288346 - SW-846 3546
LCS (B288346-BS1) Prepared: 08/17/21 Analyzed: 08/20/21
mg/Kg wet 5.00 40-140Surrogate: o-Terphenyl (OTP)78.33.92
mg/Kg wet 5.00 40-140Surrogate: 2-Bromonaphthalene 93.64.68
mg/Kg wet 5.00 40-140Surrogate: 2-Fluorobiphenyl 95.24.76
LCS Dup (B288346-BSD1) Prepared: 08/17/21 Analyzed: 08/20/21
C9-C18 Aliphatics mg/Kg wet10 30.0 2540-14080.9 4.2724.3
C19-C36 Aliphatics mg/Kg wet10 40.0 2540-14084.3 5.4333.7
Unadjusted C11-C22 Aromatics mg/Kg wet10 85.0 2540-14082.8 1.3670.4
Acenaphthene mg/Kg wet0.10 5.00 2540-14064.5 4.543.23
Acenaphthylene mg/Kg wet0.10 5.00 2540-14060.8 3.883.04
Anthracene mg/Kg wet0.10 5.00 2540-14073.2 0.03013.66
Benzo(a)anthracene mg/Kg wet0.10 5.00 2540-14090.7 1.244.54
Benzo(a)pyrene mg/Kg wet0.10 5.00 2540-14088.6 1.314.43
Benzo(b)fluoranthene mg/Kg wet0.10 5.00 2540-14085.3 1.114.27
Benzo(g,h,i)perylene mg/Kg wet0.10 5.00 2540-14081.9 0.1444.10
Benzo(k)fluoranthene mg/Kg wet0.10 5.00 2540-14083.2 1.544.16
Chrysene mg/Kg wet0.10 5.00 2540-14086.0 1.654.30
Dibenz(a,h)anthracene mg/Kg wet0.10 5.00 2540-14088.5 0.6084.42
Fluoranthene mg/Kg wet0.10 5.00 2540-14079.3 0.9583.96
Fluorene mg/Kg wet0.10 5.00 2540-14066.5 3.273.32
Indeno(1,2,3-cd)pyrene mg/Kg wet0.10 5.00 2540-14081.8 0.2924.09
2-Methylnaphthalene mg/Kg wet0.10 5.00 2540-14058.6 4.522.93
Naphthalene mg/Kg wet0.10 5.00 2540-14054.2 4.672.71
Phenanthrene mg/Kg wet0.10 5.00 2540-14075.1 0.5203.76
Pyrene mg/Kg wet0.10 5.00 2540-14081.9 1.024.09
Naphthalene-aliphatic fraction mg/Kg wet0.10 5.00 0-5ND
2-Methylnaphthalene-aliphatic fraction mg/Kg wet0.10 5.00 0-5ND
mg/Kg wet 5.00 40-140Surrogate: Chlorooctadecane (COD)74.33.71
mg/Kg wet 5.00 40-140Surrogate: o-Terphenyl (OTP)76.43.82
mg/Kg wet 5.00 40-140Surrogate: 2-Bromonaphthalene 96.44.82
mg/Kg wet 5.00 40-140Surrogate: 2-Fluorobiphenyl 97.64.88
Page 28 of 43
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - VPH[TOC]
Batch B288458 - MA VPH
[TOC_3]B288458[TOC]
Blank (B288458-BLK1) Prepared & Analyzed: 08/18/21
C5-C8 Aliphatics mg/Kg wet10ND
C9-C12 Aliphatics mg/Kg wet10ND
C9-C10 Aromatics mg/Kg wet10ND
Benzene mg/Kg wet0.050ND
Butylcyclohexane mg/Kg wet0.050ND
Decane mg/Kg wet0.050ND
Ethylbenzene mg/Kg wet0.050ND
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.050ND
2-Methylpentane mg/Kg wet0.050ND
Naphthalene mg/Kg wet0.50ND
Nonane mg/Kg wet0.050ND
Pentane mg/Kg wet0.050ND
Toluene mg/Kg wet0.050ND
1,2,4-Trimethylbenzene mg/Kg wet0.050ND
2,2,4-Trimethylpentane mg/Kg wet0.050ND
m+p Xylene mg/Kg wet0.10ND
o-Xylene mg/Kg wet0.050ND
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10742.7
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)10943.7
LCS (B288458-BS1) Prepared & Analyzed: 08/18/21
C9-C10 Aromatics mg/Kg wet0.20 70-1300.0573
Benzene mg/Kg wet0.0010 0.0500 70-13088.40.0442
Butylcyclohexane mg/Kg wet0.0010 0.0500 70-1301210.0607
Decane mg/Kg wet0.0010 0.0500 70-13089.40.0447
Ethylbenzene mg/Kg wet0.0010 0.0500 70-13088.10.0440
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.0010 0.0500 70-13080.00.0400
2-Methylpentane mg/Kg wet0.0010 0.0500 70-13087.60.0438
Naphthalene mg/Kg wet0.010 0.0500 70-13098.30.0491
Nonane mg/Kg wet0.0010 0.0500 30-1301210.0606
Pentane mg/Kg wet0.0010 0.0500 70-13089.90.0450
Toluene mg/Kg wet0.0010 0.0500 70-13087.40.0437
1,2,4-Trimethylbenzene mg/Kg wet0.0010 0.0500 70-13083.80.0419
2,2,4-Trimethylpentane mg/Kg wet0.0010 0.0500 70-13084.90.0425
m+p Xylene mg/Kg wet0.0020 0.100 70-13087.80.0878
o-Xylene mg/Kg wet0.0010 0.0500 70-13089.60.0448
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10642.5
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)11445.5
LCS Dup (B288458-BSD1) Prepared & Analyzed: 08/18/21
C9-C10 Aromatics mg/Kg wet0.20 2570-130 7.010.0614
Benzene mg/Kg wet0.0010 0.0500 2570-13097.9 10.20.0489
Butylcyclohexane mg/Kg wet0.0010 0.0500 2570-130121 0.5220.0604
Decane mg/Kg wet0.0010 0.0500 2570-13089.0 0.4460.0445
Ethylbenzene mg/Kg wet0.0010 0.0500 2570-13097.1 9.730.0485
Methyl tert-Butyl Ether (MTBE)mg/Kg wet0.0010 0.0500 2570-13085.5 6.630.0427
2-Methylpentane mg/Kg wet0.0010 0.0500 2570-13083.9 4.330.0420
Naphthalene mg/Kg wet0.010 0.0500 2570-130108 9.150.0538
Nonane mg/Kg wet0.0010 0.0500 2530-130121 0.5170.0603
Pentane mg/Kg wet0.0010 0.0500 2570-13079.3 12.50.0397
Toluene mg/Kg wet0.0010 0.0500 2570-13097.6 11.00.0488
1,2,4-Trimethylbenzene mg/Kg wet0.0010 0.0500 2570-13092.8 10.30.0464
Page 29 of 43
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
Batch B288458 - MA VPH
LCS Dup (B288458-BSD1) Prepared & Analyzed: 08/18/21
2,2,4-Trimethylpentane mg/Kg wet0.0010 0.0500 2570-13085.6 0.8070.0428
m+p Xylene mg/Kg wet0.0020 0.100 2570-13097.0 9.950.0970
o-Xylene mg/Kg wet0.0010 0.0500 2570-13099.2 10.20.0496
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)11646.3
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)12550.1
Page 30 of 43
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) - Quality Control
QUALITY CONTROL
[TOC_2]Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)[TOC]
Batch B288395 - % Solids
[TOC_3]B288395[TOC]
Duplicate (B288395-DUP4) Prepared: 08/17/21 Analyzed: 08/18/21 Source: 21H0743-01
% Solids % Wt 50.50577.7 77.3
Page 31 of 43
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*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
FLAG/QUALIFIER SUMMARY
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits.
Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is
on the high side.
L-02
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Soil/methanol ratio does not meet method specifications. Excess amount of soil. Sample was completely covered
with methanol, but with less than the method-specified amount.
O-01
Surrogate recovery outside of control limits due to suspected sample matrix interference. Chromatogram(s) is
attached.
S-15
Initial calibration did not meet method specifications. Compound was calibrated using a response factor where
%RSD is outside of method specified criteria. Reported result is estimated.
V-04
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for
this compound.
V-06
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this
compound. Reported result is estimated.
V-34
Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this
compound. Reported result is estimated.
V-35
Closing CCV surrogate has high recovery. This is due to sample matrix. Samples were reanlayzed with repeated
results.
Z-01
[TOC_1]Flag/Qualifier Summary[TOC]
Page 32 of 43
Table of Contents
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP EPH rev 2.1 in Soil
CT,NC,ME,NH-PC9-C18 Aliphatics
CT,NC,ME,NH-PC19-C36 Aliphatics
CT,NC,ME,NH-PUnadjusted C11-C22 Aromatics
CT,NC,ME,NH-PC11-C22 Aromatics
CT,NC,ME,NH-PAcenaphthene
CT,NC,ME,NH-PAcenaphthylene
CT,NC,ME,NH-PAnthracene
CT,NC,ME,NH-PBenzo(a)anthracene
CT,NC,ME,NH-PBenzo(a)pyrene
CT,NC,ME,NH-PBenzo(b)fluoranthene
CT,NC,ME,NH-PBenzo(g,h,i)perylene
CT,NC,ME,NH-PBenzo(k)fluoranthene
CT,NC,ME,NH-PChrysene
CT,NC,ME,NH-PDibenz(a,h)anthracene
CT,NC,ME,NH-PFluoranthene
CT,NC,MEFluorene
CT,NC,ME,NH-PIndeno(1,2,3-cd)pyrene
CT,NC,ME2-Methylnaphthalene
CT,NC,ME,NH-PNaphthalene
CT,NC,ME,NH-PPhenanthrene
CT,NC,ME,NH-PPyrene
MADEP-VPH-Feb 2018 Rev 2.1 in Soil
CT,NC,ME,NH-PC5-C8 Aliphatics
CT,NC,ME,NH-PC9-C12 Aliphatics
CT,NC,ME,NH-PC9-C10 Aromatics
CT,NC,ME,NH-PBenzene
CT,NC,ME,NH-PEthylbenzene
CT,NC,ME,NH-PMethyl tert-Butyl Ether (MTBE)
CT,NC,ME,NH-PNaphthalene
CT,NC,ME,NH-PToluene
CT,NC,ME,NH-Pm+p Xylene
CT,NC,ME,NH-Po-Xylene
SW-846 8260D in Soil
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
[TOC_1]Certifications[TOC]
Page 33 of 43
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Soil
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
Page 34 of 43
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Soil
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
SW-846 8270E in Soil
CT,NY,NH,ME,NC,VAAcenaphthene
CT,NY,NH,ME,NC,VAAcenaphthylene
NY,NH,ME,NC,VAAcetophenone
NY,NH,ME,NC,VAAniline
CT,NY,NH,ME,NC,VAAnthracene
CT,NY,NH,ME,NC,VABenzidine
CT,NY,NH,ME,NC,VABenzo(a)anthracene
CT,NY,NH,ME,NC,VABenzo(a)pyrene
CT,NY,NH,ME,NC,VABenzo(b)fluoranthene
CT,NY,NH,ME,NC,VABenzo(g,h,i)perylene
CT,NY,NH,ME,NC,VABenzo(k)fluoranthene
NY,NH,ME,NC,VABenzoic Acid
CT,NY,NH,ME,NC,VABis(2-chloroethoxy)methane
CT,NY,NH,ME,NC,VABis(2-chloroethyl)ether
CT,NY,NH,ME,NC,VABis(2-chloroisopropyl)ether
CT,NY,NH,ME,NC,VABis(2-Ethylhexyl)phthalate
CT,NY,NH,ME,NC,VA4-Bromophenylphenylether
CT,NY,NH,ME,NC,VAButylbenzylphthalate
NCCarbazole
CT,NY,NH,ME,NC,VA4-Chloroaniline
CT,NY,NH,ME,NC,VA4-Chloro-3-methylphenol
CT,NY,NH,NC,VA2-Chloronaphthalene
CT,NY,NH,ME,NC,VA2-Chlorophenol
CT,NY,NH,ME,NC,VA4-Chlorophenylphenylether
CT,NY,NH,ME,NC,VAChrysene
CT,NY,NH,ME,NC,VADibenz(a,h)anthracene
CT,NY,NH,ME,NC,VADibenzofuran
CT,NY,NH,ME,NC,VADi-n-butylphthalate
NY,NH,ME,NC,VA1,2-Dichlorobenzene
Page 35 of 43
Table of Contents
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8270E in Soil
NY,NH,ME,NC,VA1,3-Dichlorobenzene
NY,NH,ME,NC,VA1,4-Dichlorobenzene
CT,NY,NH,ME,NC,VA3,3-Dichlorobenzidine
CT,NY,NH,ME,NC,VA2,4-Dichlorophenol
CT,NY,NH,ME,NC,VADiethylphthalate
CT,NY,NH,ME,NC,VA2,4-Dimethylphenol
CT,NY,NH,ME,NC,VADimethylphthalate
CT,NY,NH,ME,NC,VA4,6-Dinitro-2-methylphenol
CT,NY,NH,ME,NC,VA2,4-Dinitrophenol
CT,NY,NH,ME,NC,VA2,4-Dinitrotoluene
CT,NY,NH,ME,NC,VA2,6-Dinitrotoluene
CT,NY,NH,ME,NC,VADi-n-octylphthalate
NY,NH,ME,NC,VA1,2-Diphenylhydrazine/Azobenzene
CT,NY,NH,ME,NC,VAFluoranthene
NY,NH,ME,NC,VAFluorene
CT,NY,NH,ME,NC,VAHexachlorobenzene
CT,NY,NH,ME,NC,VAHexachlorobutadiene
CT,NY,NH,ME,NC,VAHexachlorocyclopentadiene
CT,NY,NH,ME,NC,VAHexachloroethane
CT,NY,NH,ME,NC,VAIndeno(1,2,3-cd)pyrene
CT,NY,NH,ME,NC,VAIsophorone
NC1-Methylnaphthalene
CT,NY,NH,ME,NC,VA2-Methylnaphthalene
CT,NY,NH,ME,NC,VA2-Methylphenol
CT,NY,NH,ME,NC,VA3/4-Methylphenol
CT,NY,NH,ME,NC,VANaphthalene
CT,NY,NH,ME,NC,VA2-Nitroaniline
CT,NY,NH,ME,NC,VA3-Nitroaniline
CT,NY,NH,ME,NC,VA4-Nitroaniline
CT,NY,NH,ME,NC,VANitrobenzene
CT,NY,NH,ME,NC,VA2-Nitrophenol
CT,NY,NH,ME,NC,VA4-Nitrophenol
CT,NY,NH,ME,NC,VAN-Nitrosodimethylamine
CT,NY,NH,ME,NC,VAN-Nitrosodi-n-propylamine
NY,NCPentachloronitrobenzene
CT,NY,NH,ME,NC,VAPentachlorophenol
CT,NY,NH,ME,NC,VAPhenanthrene
CT,NY,NH,ME,NC,VAPhenol
CT,NY,NH,ME,NC,VAPyrene
CT,NY,NH,ME,NC,VAPyridine
NY,NC1,2,4,5-Tetrachlorobenzene
CT,NY,NH,ME,NC,VA1,2,4-Trichlorobenzene
CT,NY,NH,ME,NC,VA2,4,5-Trichlorophenol
CT,NY,NH,ME,NC,VA2,4,6-Trichlorophenol
NC2-Fluorophenol
SW-846 8270E in Water
Page 36 of 43
Table of Contents
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8270E in Water
CT,NY,NC,ME,NH,VAAcenaphthene
CT,NY,NC,ME,NH,VAAcenaphthylene
NY,NCAcetophenone
CT,NY,NC,ME,VAAniline
CT,NY,NC,ME,NH,VAAnthracene
CT,NY,NC,ME,NH,VABenzidine
CT,NY,NC,ME,NH,VABenzo(a)anthracene
CT,NY,NC,ME,NH,VABenzo(a)pyrene
CT,NY,NC,ME,NH,VABenzo(b)fluoranthene
CT,NY,NC,ME,NH,VABenzo(g,h,i)perylene
CT,NY,NC,ME,NH,VABenzo(k)fluoranthene
NY,NC,ME,NH,VABenzoic Acid
CT,NY,NC,ME,NH,VABis(2-chloroethoxy)methane
CT,NY,NC,ME,NH,VABis(2-chloroethyl)ether
CT,NY,NC,ME,NH,VABis(2-chloroisopropyl)ether
CT,NY,NC,ME,NH,VABis(2-Ethylhexyl)phthalate
CT,NY,NC,ME,NH,VA4-Bromophenylphenylether
CT,NY,NC,ME,NH,VAButylbenzylphthalate
NCCarbazole
CT,NY,NC,ME,NH,VA4-Chloroaniline
CT,NY,NC,ME,NH,VA4-Chloro-3-methylphenol
CT,NY,NC,ME,NH,VA2-Chloronaphthalene
CT,NY,NC,ME,NH,VA2-Chlorophenol
CT,NY,NC,ME,NH,VA4-Chlorophenylphenylether
CT,NY,NC,ME,NH,VAChrysene
CT,NY,NC,ME,NH,VADibenz(a,h)anthracene
CT,NY,NC,ME,NH,VADibenzofuran
CT,NY,NC,ME,NH,VADi-n-butylphthalate
CT,NY,NC,ME,NH,VA1,2-Dichlorobenzene
CT,NY,NC,ME,NH,VA1,3-Dichlorobenzene
CT,NY,NC,ME,NH,VA1,4-Dichlorobenzene
CT,NY,NC,ME,NH,VA3,3-Dichlorobenzidine
CT,NY,NC,ME,NH,VA2,4-Dichlorophenol
CT,NY,NC,ME,NH,VADiethylphthalate
CT,NY,NC,ME,NH,VA2,4-Dimethylphenol
CT,NY,NC,ME,NH,VADimethylphthalate
CT,NY,NC,ME,NH,VA4,6-Dinitro-2-methylphenol
CT,NY,NC,ME,NH,VA2,4-Dinitrophenol
CT,NY,NC,ME,NH,VA2,4-Dinitrotoluene
CT,NY,NC,ME,NH,VA2,6-Dinitrotoluene
CT,NY,NC,ME,NH,VADi-n-octylphthalate
NY,NC1,2-Diphenylhydrazine/Azobenzene
CT,NY,NC,ME,NH,VAFluoranthene
NY,NC,ME,NH,VAFluorene
CT,NY,NC,ME,NH,VAHexachlorobenzene
CT,NY,NC,ME,NH,VAHexachlorobutadiene
CT,NY,NC,ME,NH,VAHexachlorocyclopentadiene
Page 37 of 43
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8270E in Water
CT,NY,NC,ME,NH,VAHexachloroethane
CT,NY,NC,ME,NH,VAIndeno(1,2,3-cd)pyrene
CT,NY,NC,ME,NH,VAIsophorone
NC1-Methylnaphthalene
CT,NY,NC,ME,NH,VA2-Methylnaphthalene
CT,NY,NC,NH,VA2-Methylphenol
CT,NY,NC,NH,VA3/4-Methylphenol
CT,NY,NC,ME,NH,VANaphthalene
CT,NY,NC,ME,NH,VA2-Nitroaniline
CT,NY,NC,ME,NH,VA3-Nitroaniline
CT,NY,NC,ME,NH,VA4-Nitroaniline
CT,NY,NC,ME,NH,VANitrobenzene
CT,NY,NC,ME,NH,VA2-Nitrophenol
CT,NY,NC,ME,NH,VA4-Nitrophenol
CT,NY,NC,ME,NH,VAN-Nitrosodimethylamine
CT,NY,NC,ME,NH,VAN-Nitrosodi-n-propylamine
NCPentachloronitrobenzene
CT,NY,NC,ME,NH,VAPentachlorophenol
CT,NY,NC,ME,NH,VAPhenanthrene
CT,NY,NC,ME,NH,VAPhenol
CT,NY,NC,ME,NH,VAPyrene
CT,NY,NC,ME,NH,VAPyridine
NY,NC1,2,4,5-Tetrachlorobenzene
CT,NY,NC,ME,NH,VA1,2,4-Trichlorobenzene
CT,NY,NC,ME,NH,VA2,4,5-Trichlorophenol
CT,NY,NC,ME,NH,VA2,4,6-Trichlorophenol
NC2-Fluorophenol
Page 38 of 43
Table of Contents
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The CON-TEST Environmental Laboratory operates under the following certifications and accreditations:
Code Description Number Expires
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10899 NELAPNew York State Department of HealthNY 04/1/2022
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2022
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LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2022
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2021
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2021
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2022
25703North Carolina Department of HealthNC-DW 07/31/2022
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2022
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2021
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
August 30, 2021
Ben Ashba
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
Project Location: Durham, NC
Client Job Number:
Project Number: 221007
Laboratory Work Order Number: 21H1156
Enclosed are results of analyses for samples received by the laboratory on August 23, 2021. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kaitlyn A. Feliciano
Project Manager
Page 1 of 39
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Table of Contents
Sample Summary 3
Hits Only Report 4
Case Narrative 5
Sample Results 7
21H1156-01 7
21H1156-02 9
21H1156-03 11
Sample Preparation Information 18
QC Data 19
Volatile Organic Compounds by GC/MS 19
B288897 19
Semivolatile Organic Compounds by - GC/MS 23
B288889 23
Petroleum Hydrocarbons Analyses - EPH 27
B288844 27
Petroleum Hydrocarbons Analyses - VPH 29
B288805 29
Metals Analyses (Total) 31
B288997 31
Flag/Qualifier Summary 32
Certifications 33
Chain of Custody/Sample Receipt 37
Page 2 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
8/30/2021
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
ATTN: Ben Ashba
221007
21H1156
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Durham, NC
210820-5
Field Blank 21H1156-01 Ground Water SM21-23 6200B
Trip Blank 21H1156-02 Ground Water SM21-23 6200B
MW-01 21H1156-03 Ground Water 625.1
MADEP EPH rev 2.1
MADEP-VPH-Feb
2018 Rev 2.1
SM21-23 6200B
SW-846 6020B
[TOC_1]Sample Summary[TOC]
Page 3 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
[TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
21H1156-01Field Blank
DL
Acetone 6.2 50 g/L SM21-23 6200BJ2.4
Toluene 0.13 0.50 g/L SM21-23 6200BJ0.11
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
21H1156-02Trip Blank
DL
Toluene 0.19 0.50 g/L SM21-23 6200BJ0.11
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
21H1156-03MW-01
DL
1,2,4-Trimethylbenzene 0.24 0.50 g/L SM21-23 6200BJ0.10
1,2-Dichloroethane 1.2 0.50 g/L SM21-23 6200B0.32
Acetone 5.2 50 g/L SM21-23 6200BJ2.4
Benzene 0.68 0.50 g/L SM21-23 6200B0.13
Diisopropyl Ether (DIPE)0.30 0.50 g/L SM21-23 6200BJ0.15
Methyl tert-Butyl Ether (MTBE)0.41 0.50 g/L SM21-23 6200BJ0.17
Toluene 0.17 0.50 g/L SM21-23 6200BJ0.11
Lead 27 0.50 g/L SW-846 6020B0.14
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 4 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA VPH, only hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
625.1
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
1,2,4-Trichlorobenzene
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1
2-Chloronaphthalene
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1
Hexachloroethane
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1
N-Nitrosodimethylamine
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1
Initial calibration did not meet method specifications. Compound was calibrated using a response factor where %RSD is outside of method
specified criteria. Reported result is estimated.
Analyte & Samples(s) Qualified:
V-04
Benzidine
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1, S062731-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
Benzidine
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1, S062731-CCV1
Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is
estimated.
Analyte & Samples(s) Qualified:
V-35
Benzidine
21H1156-03[MW-01], B288889-BLK1, B288889-BS1, B288889-BSD1, S062731-CCV1
SM21-23 6200B
Qualifications:
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.Analyte & Samples(s) Qualified:
L-07
Ethanol
B288897-BSD1
Page 5 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
MADEP-VPH-Feb 2018 Rev 2.1
No significant modifications were made to the method. All VPH samples were received preserved properly at pH <2 in the proper containers as specified on the chain-of-custody
form unless specified in this narrative.
Analytical column used for VPH analysis is Restek, Rtx-502.2, 105meter, 0.53mmID, 3um df. Trap used for VPH analysis is Carbopack B/CarboSieveS-III.
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 6 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-01
Field Sample #: Field Blank
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
[TOC_2]21H1156-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
6.2 50 8/26/21 0:40 EEHg/L2.4 8/25/21SM21-23 6200B1JAcetone
ND 0.50 8/26/21 0:40 EEHg/L0.13 8/25/21SM21-23 6200B1Benzene
ND 0.50 8/26/21 0:40 EEHg/L0.13 8/25/21SM21-23 6200B1Bromobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.36 8/25/21SM21-23 6200B1Bromochloromethane
ND 0.50 8/26/21 0:40 EEHg/L0.14 8/25/21SM21-23 6200B1Bromodichloromethane
ND 0.50 8/26/21 0:40 EEHg/L0.29 8/25/21SM21-23 6200B1Bromoform
ND 2.0 8/26/21 0:40 EEHg/L1.1 8/25/21SM21-23 6200B1Bromomethane
ND 5.0 8/26/21 0:40 EEHg/L1.9 8/25/21SM21-23 6200B12-Butanone (MEK)
ND 0.50 8/26/21 0:40 EEHg/L0.14 8/25/21SM21-23 6200B1n-Butylbenzene
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B1sec-Butylbenzene
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B1tert-Butylbenzene
ND 0.50 8/26/21 0:40 EEHg/L0.17 8/25/21SM21-23 6200B1Carbon Tetrachloride
ND 0.50 8/26/21 0:40 EEHg/L0.080 8/25/21SM21-23 6200B1Chlorobenzene
ND 50 8/26/21 0:40 EEHg/L34 8/25/21SM21-23 6200B1Ethanol
ND 0.50 8/26/21 0:40 EEHg/L0.16 8/25/21SM21-23 6200B1Chlorodibromomethane
ND 0.50 8/26/21 0:40 EEHg/L0.37 8/25/21SM21-23 6200B1Chloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.19 8/25/21SM21-23 6200B1Chloroform
ND 2.0 8/26/21 0:40 EEHg/L0.38 8/25/21SM21-23 6200B1Chloromethane
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B12-Chlorotoluene
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B14-Chlorotoluene
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.11 8/25/21SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.20 8/25/21SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 8/26/21 0:40 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.32 8/25/21SM21-23 6200B11,2-Dichloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethylene
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 8/26/21 0:40 EEHg/L0.17 8/25/21SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 8/26/21 0:40 EEHg/L0.18 8/25/21SM21-23 6200B11,2-Dichloropropane
ND 0.50 8/26/21 0:40 EEHg/L0.12 8/25/21SM21-23 6200B11,3-Dichloropropane
ND 0.50 8/26/21 0:40 EEHg/L0.31 8/25/21SM21-23 6200B12,2-Dichloropropane
ND 0.50 8/26/21 0:40 EEHg/L0.26 8/25/21SM21-23 6200B11,1-Dichloropropene
ND 0.50 8/26/21 0:40 EEHg/L0.12 8/25/21SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B1Ethylbenzene
ND 5.0 8/26/21 0:40 EEHg/L1.4 8/25/21SM21-23 6200B12-Hexanone (MBK)
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 8/26/21 0:40 EEHg/L0.17 8/25/21SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/26/21 0:40 EEHg/L0.30 8/25/21SM21-23 6200B1Methylene Chloride
ND 5.0 8/26/21 0:40 EEHg/L1.6 8/25/21SM21-23 6200B14-Methyl-2-pentanone (MIBK)
[TOC_1]Sample Results[TOC]
Page 7 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-01
Field Sample #: Field Blank
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B1Naphthalene
ND 0.50 8/26/21 0:40 EEHg/L0.080 8/25/21SM21-23 6200B1n-Propylbenzene
ND 0.50 8/26/21 0:40 EEHg/L0.080 8/25/21SM21-23 6200B1Styrene
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.20 8/25/21SM21-23 6200B1Tetrachloroethylene
0.13 0.50 8/26/21 0:40 EEHg/L0.11 8/25/21SM21-23 6200B1JToluene
ND 1.0 8/26/21 0:40 EEHg/L0.14 8/25/21SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.16 8/25/21SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 8/26/21 0:40 EEHg/L0.17 8/25/21SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.15 8/25/21SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 8/26/21 0:40 EEHg/L0.18 8/25/21SM21-23 6200B1Trichloroethylene
ND 0.50 8/26/21 0:40 EEHg/L0.19 8/25/21SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 8/26/21 0:40 EEHg/L0.31 8/25/21SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 8/26/21 0:40 EEHg/L0.10 8/25/21SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 8/26/21 0:40 EEHg/L5.5 8/25/21SM21-23 6200B1Vinyl Acetate
ND 0.50 8/26/21 0:40 EEHg/L0.20 8/25/21SM21-23 6200B1Vinyl Chloride
ND 1.0 8/26/21 0:40 EEHg/L0.18 8/25/21SM21-23 6200B1m+p Xylene
ND 0.50 8/26/21 0:40 EEHg/L0.090 8/25/21SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 95.8 8/26/21 0:4070-130
Toluene-d8 96.1 8/26/21 0:4070-130
4-Bromofluorobenzene 94.8 8/26/21 0:4070-130
Page 8 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-02
Field Sample #: Trip Blank
Sample Matrix: Ground Water
Sampled: 8/20/2021 00:00
[TOC_2]21H1156-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/26/21 1:07 EEHg/L2.4 8/25/21SM21-23 6200B1Acetone
ND 0.50 8/26/21 1:07 EEHg/L0.13 8/25/21SM21-23 6200B1Benzene
ND 0.50 8/26/21 1:07 EEHg/L0.13 8/25/21SM21-23 6200B1Bromobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.36 8/25/21SM21-23 6200B1Bromochloromethane
ND 0.50 8/26/21 1:07 EEHg/L0.14 8/25/21SM21-23 6200B1Bromodichloromethane
ND 0.50 8/26/21 1:07 EEHg/L0.29 8/25/21SM21-23 6200B1Bromoform
ND 2.0 8/26/21 1:07 EEHg/L1.1 8/25/21SM21-23 6200B1Bromomethane
ND 5.0 8/26/21 1:07 EEHg/L1.9 8/25/21SM21-23 6200B12-Butanone (MEK)
ND 0.50 8/26/21 1:07 EEHg/L0.14 8/25/21SM21-23 6200B1n-Butylbenzene
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B1sec-Butylbenzene
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B1tert-Butylbenzene
ND 0.50 8/26/21 1:07 EEHg/L0.17 8/25/21SM21-23 6200B1Carbon Tetrachloride
ND 0.50 8/26/21 1:07 EEHg/L0.080 8/25/21SM21-23 6200B1Chlorobenzene
ND 50 8/26/21 1:07 EEHg/L34 8/25/21SM21-23 6200B1Ethanol
ND 0.50 8/26/21 1:07 EEHg/L0.16 8/25/21SM21-23 6200B1Chlorodibromomethane
ND 0.50 8/26/21 1:07 EEHg/L0.37 8/25/21SM21-23 6200B1Chloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.19 8/25/21SM21-23 6200B1Chloroform
ND 2.0 8/26/21 1:07 EEHg/L0.38 8/25/21SM21-23 6200B1Chloromethane
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B12-Chlorotoluene
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B14-Chlorotoluene
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.11 8/25/21SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.20 8/25/21SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 8/26/21 1:07 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.32 8/25/21SM21-23 6200B11,2-Dichloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethylene
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 8/26/21 1:07 EEHg/L0.17 8/25/21SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 8/26/21 1:07 EEHg/L0.18 8/25/21SM21-23 6200B11,2-Dichloropropane
ND 0.50 8/26/21 1:07 EEHg/L0.12 8/25/21SM21-23 6200B11,3-Dichloropropane
ND 0.50 8/26/21 1:07 EEHg/L0.31 8/25/21SM21-23 6200B12,2-Dichloropropane
ND 0.50 8/26/21 1:07 EEHg/L0.26 8/25/21SM21-23 6200B11,1-Dichloropropene
ND 0.50 8/26/21 1:07 EEHg/L0.12 8/25/21SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B1Ethylbenzene
ND 5.0 8/26/21 1:07 EEHg/L1.4 8/25/21SM21-23 6200B12-Hexanone (MBK)
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 8/26/21 1:07 EEHg/L0.17 8/25/21SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/26/21 1:07 EEHg/L0.30 8/25/21SM21-23 6200B1Methylene Chloride
ND 5.0 8/26/21 1:07 EEHg/L1.6 8/25/21SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 9 of 39
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-02
Field Sample #: Trip Blank
Sample Matrix: Ground Water
Sampled: 8/20/2021 00:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B1Naphthalene
ND 0.50 8/26/21 1:07 EEHg/L0.080 8/25/21SM21-23 6200B1n-Propylbenzene
ND 0.50 8/26/21 1:07 EEHg/L0.080 8/25/21SM21-23 6200B1Styrene
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.20 8/25/21SM21-23 6200B1Tetrachloroethylene
0.19 0.50 8/26/21 1:07 EEHg/L0.11 8/25/21SM21-23 6200B1JToluene
ND 1.0 8/26/21 1:07 EEHg/L0.14 8/25/21SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.16 8/25/21SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 8/26/21 1:07 EEHg/L0.17 8/25/21SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.15 8/25/21SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 8/26/21 1:07 EEHg/L0.18 8/25/21SM21-23 6200B1Trichloroethylene
ND 0.50 8/26/21 1:07 EEHg/L0.19 8/25/21SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 8/26/21 1:07 EEHg/L0.31 8/25/21SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 8/26/21 1:07 EEHg/L0.10 8/25/21SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 8/26/21 1:07 EEHg/L5.5 8/25/21SM21-23 6200B1Vinyl Acetate
ND 0.50 8/26/21 1:07 EEHg/L0.20 8/25/21SM21-23 6200B1Vinyl Chloride
ND 1.0 8/26/21 1:07 EEHg/L0.18 8/25/21SM21-23 6200B1m+p Xylene
ND 0.50 8/26/21 1:07 EEHg/L0.090 8/25/21SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.0 8/26/21 1:0770-130
Toluene-d8 96.5 8/26/21 1:0770-130
4-Bromofluorobenzene 93.5 8/26/21 1:0770-130
Page 10 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
[TOC_2]21H1156-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
5.2 50 8/26/21 1:34 EEHg/L2.4 8/25/21SM21-23 6200B1JAcetone
0.68 0.50 8/26/21 1:34 EEHg/L0.13 8/25/21SM21-23 6200B1Benzene
ND 0.50 8/26/21 1:34 EEHg/L0.13 8/25/21SM21-23 6200B1Bromobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.36 8/25/21SM21-23 6200B1Bromochloromethane
ND 0.50 8/26/21 1:34 EEHg/L0.14 8/25/21SM21-23 6200B1Bromodichloromethane
ND 0.50 8/26/21 1:34 EEHg/L0.29 8/25/21SM21-23 6200B1Bromoform
ND 2.0 8/26/21 1:34 EEHg/L1.1 8/25/21SM21-23 6200B1Bromomethane
ND 5.0 8/26/21 1:34 EEHg/L1.9 8/25/21SM21-23 6200B12-Butanone (MEK)
ND 0.50 8/26/21 1:34 EEHg/L0.14 8/25/21SM21-23 6200B1n-Butylbenzene
ND 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B1sec-Butylbenzene
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B1tert-Butylbenzene
ND 0.50 8/26/21 1:34 EEHg/L0.17 8/25/21SM21-23 6200B1Carbon Tetrachloride
ND 0.50 8/26/21 1:34 EEHg/L0.080 8/25/21SM21-23 6200B1Chlorobenzene
ND 50 8/26/21 1:34 EEHg/L34 8/25/21SM21-23 6200B1Ethanol
ND 0.50 8/26/21 1:34 EEHg/L0.16 8/25/21SM21-23 6200B1Chlorodibromomethane
ND 0.50 8/26/21 1:34 EEHg/L0.37 8/25/21SM21-23 6200B1Chloroethane
ND 0.50 8/26/21 1:34 EEHg/L0.19 8/25/21SM21-23 6200B1Chloroform
ND 2.0 8/26/21 1:34 EEHg/L0.38 8/25/21SM21-23 6200B1Chloromethane
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B12-Chlorotoluene
ND 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B14-Chlorotoluene
ND 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.11 8/25/21SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.20 8/25/21SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 8/26/21 1:34 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethane
1.2 0.50 8/26/21 1:34 EEHg/L0.32 8/25/21SM21-23 6200B11,2-Dichloroethane
ND 0.50 8/26/21 1:34 EEHg/L0.16 8/25/21SM21-23 6200B11,1-Dichloroethylene
ND 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 8/26/21 1:34 EEHg/L0.17 8/25/21SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 8/26/21 1:34 EEHg/L0.18 8/25/21SM21-23 6200B11,2-Dichloropropane
ND 0.50 8/26/21 1:34 EEHg/L0.12 8/25/21SM21-23 6200B11,3-Dichloropropane
ND 0.50 8/26/21 1:34 EEHg/L0.31 8/25/21SM21-23 6200B12,2-Dichloropropane
ND 0.50 8/26/21 1:34 EEHg/L0.26 8/25/21SM21-23 6200B11,1-Dichloropropene
ND 0.50 8/26/21 1:34 EEHg/L0.12 8/25/21SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B1trans-1,3-Dichloropropene
0.30 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B1JDiisopropyl Ether (DIPE)
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B1Ethylbenzene
ND 5.0 8/26/21 1:34 EEHg/L1.4 8/25/21SM21-23 6200B12-Hexanone (MBK)
ND 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
0.41 0.50 8/26/21 1:34 EEHg/L0.17 8/25/21SM21-23 6200B1JMethyl tert-Butyl Ether (MTBE)
ND 5.0 8/26/21 1:34 EEHg/L0.30 8/25/21SM21-23 6200B1Methylene Chloride
ND 5.0 8/26/21 1:34 EEHg/L1.6 8/25/21SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 11 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B1Naphthalene
ND 0.50 8/26/21 1:34 EEHg/L0.080 8/25/21SM21-23 6200B1n-Propylbenzene
ND 0.50 8/26/21 1:34 EEHg/L0.080 8/25/21SM21-23 6200B1Styrene
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 8/26/21 1:34 EEHg/L0.20 8/25/21SM21-23 6200B1Tetrachloroethylene
0.17 0.50 8/26/21 1:34 EEHg/L0.11 8/25/21SM21-23 6200B1JToluene
ND 1.0 8/26/21 1:34 EEHg/L0.14 8/25/21SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.16 8/25/21SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 8/26/21 1:34 EEHg/L0.17 8/25/21SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 8/26/21 1:34 EEHg/L0.15 8/25/21SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 8/26/21 1:34 EEHg/L0.18 8/25/21SM21-23 6200B1Trichloroethylene
ND 0.50 8/26/21 1:34 EEHg/L0.19 8/25/21SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 8/26/21 1:34 EEHg/L0.31 8/25/21SM21-23 6200B11,2,3-Trichloropropane
0.24 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B1J1,2,4-Trimethylbenzene
ND 0.50 8/26/21 1:34 EEHg/L0.10 8/25/21SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 8/26/21 1:34 EEHg/L5.5 8/25/21SM21-23 6200B1Vinyl Acetate
ND 0.50 8/26/21 1:34 EEHg/L0.20 8/25/21SM21-23 6200B1Vinyl Chloride
ND 1.0 8/26/21 1:34 EEHg/L0.18 8/25/21SM21-23 6200B1m+p Xylene
ND 0.50 8/26/21 1:34 EEHg/L0.090 8/25/21SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 97.9 8/26/21 1:3470-130
Toluene-d8 97.0 8/26/21 1:3470-130
4-Bromofluorobenzene 94.0 8/26/21 1:3470-130
Page 12 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Semivolatile Organic Compounds by - GC/MS
<0.319 4.76 8/27/21 13:05 BGLg/L0.319 8/25/21625.11Acenaphthene
<0.306 4.76 8/27/21 13:05 BGLg/L0.306 8/25/21625.11Acenaphthylene
<0.377 4.76 8/27/21 13:05 BGLg/L0.377 8/25/21625.11Anthracene
<9.47 19.0 8/27/21 13:05 BGLg/L9.47 8/25/21625.11V-04, V-05, V-35Benzidine
<0.361 4.76 8/27/21 13:05 BGLg/L0.361 8/25/21625.11Benzo(a)anthracene
<0.456 4.76 8/27/21 13:05 BGLg/L0.456 8/25/21625.11Benzo(a)pyrene
<0.397 4.76 8/27/21 13:05 BGLg/L0.397 8/25/21625.11Benzo(b)fluoranthene
<0.610 4.76 8/27/21 13:05 BGLg/L0.610 8/25/21625.11Benzo(g,h,i)perylene
<0.351 4.76 8/27/21 13:05 BGLg/L0.351 8/25/21625.11Benzo(k)fluoranthene
<0.365 9.52 8/27/21 13:05 BGLg/L0.365 8/25/21625.114-Bromophenylphenylether
<0.663 9.52 8/27/21 13:05 BGLg/L0.663 8/25/21625.11Butylbenzylphthalate
<0.515 9.52 8/27/21 13:05 BGLg/L0.515 8/25/21625.114-Chloro-3-methylphenol
<0.411 9.52 8/27/21 13:05 BGLg/L0.411 8/25/21625.11Bis(2-chloroethoxy)methane
<0.494 9.52 8/27/21 13:05 BGLg/L0.494 8/25/21625.11Bis(2-chloroethyl)ether
<0.569 9.52 8/27/21 13:05 BGLg/L0.569 8/25/21625.11Bis(2-chloroisopropyl)ether
<0.252 9.52 8/27/21 13:05 BGLg/L0.252 8/25/21625.11L-042-Chloronaphthalene
<0.356 9.52 8/27/21 13:05 BGLg/L0.356 8/25/21625.112-Chlorophenol
<0.316 9.52 8/27/21 13:05 BGLg/L0.316 8/25/21625.114-Chlorophenylphenylether
<0.357 4.76 8/27/21 13:05 BGLg/L0.357 8/25/21625.11Chrysene
<0.676 4.76 8/27/21 13:05 BGLg/L0.676 8/25/21625.11Dibenz(a,h)anthracene
<0.473 9.52 8/27/21 13:05 BGLg/L0.473 8/25/21625.11Di-n-butylphthalate
<0.229 4.76 8/27/21 13:05 BGLg/L0.229 8/25/21625.111,3-Dichlorobenzene
<0.252 4.76 8/27/21 13:05 BGLg/L0.252 8/25/21625.111,4-Dichlorobenzene
<0.223 4.76 8/27/21 13:05 BGLg/L0.223 8/25/21625.111,2-Dichlorobenzene
<0.595 9.52 8/27/21 13:05 BGLg/L0.595 8/25/21625.113,3-Dichlorobenzidine
<0.348 9.52 8/27/21 13:05 BGLg/L0.348 8/25/21625.112,4-Dichlorophenol
<0.458 9.52 8/27/21 13:05 BGLg/L0.458 8/25/21625.11Diethylphthalate
<0.920 9.52 8/27/21 13:05 BGLg/L0.920 8/25/21625.112,4-Dimethylphenol
<0.383 9.52 8/27/21 13:05 BGLg/L0.383 8/25/21625.11Dimethylphthalate
<6.26 9.52 8/27/21 13:05 BGLg/L6.26 8/25/21625.114,6-Dinitro-2-methylphenol
<7.64 9.52 8/27/21 13:05 BGLg/L7.64 8/25/21625.112,4-Dinitrophenol
<0.580 9.52 8/27/21 13:05 BGLg/L0.580 8/25/21625.112,4-Dinitrotoluene
<0.476 9.52 8/27/21 13:05 BGLg/L0.476 8/25/21625.112,6-Dinitrotoluene
<5.33 9.52 8/27/21 13:05 BGLg/L5.33 8/25/21625.11Di-n-octylphthalate
<0.501 9.52 8/27/21 13:05 BGLg/L0.501 8/25/21625.111,2-Diphenylhydrazine/Azobenzene
<0.880 9.52 8/27/21 13:05 BGLg/L0.880 8/25/21625.11Bis(2-Ethylhexyl)phthalate
<0.352 4.76 8/27/21 13:05 BGLg/L0.352 8/25/21625.11Fluoranthene
<0.397 4.76 8/27/21 13:05 BGLg/L0.397 8/25/21625.11Fluorene
<0.347 9.52 8/27/21 13:05 BGLg/L0.347 8/25/21625.11Hexachlorobenzene
<0.258 9.52 8/27/21 13:05 BGLg/L0.258 8/25/21625.11Hexachlorobutadiene
<4.02 9.52 8/27/21 13:05 BGLg/L4.02 8/25/21625.11Hexachlorocyclopentadiene
<0.294 9.52 8/27/21 13:05 BGLg/L0.294 8/25/21625.11L-04Hexachloroethane
<0.751 4.76 8/27/21 13:05 BGLg/L0.751 8/25/21625.11Indeno(1,2,3-cd)pyrene
<0.464 9.52 8/27/21 13:05 BGLg/L0.464 8/25/21625.11Isophorone
Page 13 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Semivolatile Organic Compounds by - GC/MS
<0.282 4.76 8/27/21 13:05 BGLg/L0.282 8/25/21625.11Naphthalene
<0.505 9.52 8/27/21 13:05 BGLg/L0.505 8/25/21625.11Nitrobenzene
<0.450 9.52 8/27/21 13:05 BGLg/L0.450 8/25/21625.112-Nitrophenol
<1.96 9.52 8/27/21 13:05 BGLg/L1.96 8/25/21625.114-Nitrophenol
<0.781 9.52 8/27/21 13:05 BGLg/L0.781 8/25/21625.11L-04N-Nitrosodimethylamine
<0.379 9.52 8/27/21 13:05 BGLg/L0.379 8/25/21625.11N-Nitrosodiphenylamine/Diphenylamine
<0.504 9.52 8/27/21 13:05 BGLg/L0.504 8/25/21625.11N-Nitrosodi-n-propylamine
<3.56 9.52 8/27/21 13:05 BGLg/L3.56 8/25/21625.11Pentachlorophenol
<0.316 4.76 8/27/21 13:05 BGLg/L0.316 8/25/21625.112-Methylnaphthalene
<0.378 4.76 8/27/21 13:05 BGLg/L0.378 8/25/21625.11Phenanthrene
<0.348 9.52 8/27/21 13:05 BGLg/L0.348 8/25/21625.112-Methylphenol
<0.235 9.52 8/27/21 13:05 BGLg/L0.235 8/25/21625.11Phenol
<0.363 19.0 8/27/21 13:05 BGLg/L0.363 8/25/21625.113/4-Methylphenol
<0.450 4.76 8/27/21 13:05 BGLg/L0.450 8/25/21625.11Pyrene
<0.233 4.76 8/27/21 13:05 BGLg/L0.233 8/25/21625.11L-041,2,4-Trichlorobenzene
<0.389 9.52 8/27/21 13:05 BGLg/L0.389 8/25/21625.112,4,6-Trichlorophenol
Surrogates % Recovery Recovery Limits Flag/Qual
2-Fluorophenol 27.9 8/27/21 13:0515-110
Phenol-d6 26.7 8/27/21 13:0515-110
Nitrobenzene-d5 51.2 8/27/21 13:0530-130
2-Fluorobiphenyl 56.2 8/27/21 13:0530-130
2,4,6-Tribromophenol 66.7 8/27/21 13:0515-110
p-Terphenyl-d14 79.6 8/27/21 13:0530-130
Page 14 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - EPH
ND 95 8/27/21 0:04 RDDg/L 8/24/21MADEP EPH rev 2.11C9-C18 Aliphatics
ND 95 8/27/21 0:04 RDDg/L 8/24/21MADEP EPH rev 2.11C19-C36 Aliphatics
ND 95 8/27/21 0:04 RDDg/L 8/24/21MADEP EPH rev 2.11C11-C22 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
Chlorooctadecane (COD)61.4 8/27/21 0:0440-140
o-Terphenyl (OTP)72.3 8/27/21 0:0440-140
2-Bromonaphthalene 91.1 8/27/21 0:0440-140
2-Fluorobiphenyl 91.2 8/27/21 0:0440-140
Page 15 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - VPH
ND 100 8/24/21 22:14 KMBg/L 8/24/21MADEP-VPH-Feb 2018
Rev 2.1
1Unadjusted C5-C8 Aliphatics
ND 100 8/24/21 22:14 KMBg/L 8/24/21MADEP-VPH-Feb 2018
Rev 2.1
1C5-C8 Aliphatics
ND 100 8/24/21 22:14 KMBg/L 8/24/21MADEP-VPH-Feb 2018
Rev 2.1
1Unadjusted C9-C12 Aliphatics
ND 100 8/24/21 22:14 KMBg/L 8/24/21MADEP-VPH-Feb 2018
Rev 2.1
1C9-C12 Aliphatics
ND 100 8/24/21 22:14 KMBg/L 8/24/21MADEP-VPH-Feb 2018
Rev 2.1
1C9-C10 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
2,5-Dibromotoluene (FID)83.0 8/24/21 22:1470-130
2,5-Dibromotoluene (PID)88.1 8/24/21 22:1470-130
Page 16 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/23/2021
Work Order: 21H1156Sample Description:Project Location: Durham, NC
Sample ID: 21H1156-03
Field Sample #: MW-01
Sample Matrix: Ground Water
Sampled: 8/20/2021 10:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Metals Analyses (Total)
27 0.50 8/26/21 16:41 MJHg/L0.14 8/26/21SW-846 6020B1Lead
Page 17 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 3510C-625.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B288889 08/25/211050 1.0021H1156-03 [MW-01]
Prep Method: SW-846 3510C-MADEP EPH rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B288844 08/24/211060 2.0021H1156-03 [MW-01]
Prep Method: MA VPH-MADEP-VPH-Feb 2018 Rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B288805 08/24/215 5.0021H1156-03 [MW-01]
Prep Method: SW-846 5030B-SM21-23 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B288897 08/25/215 5.0021H1156-01 [Field Blank]
B288897 08/25/215 5.0021H1156-02 [Trip Blank]
B288897 08/25/215 5.0021H1156-03 [MW-01]
Prep Method: SW-846 3005A-SW-846 6020B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B288997 08/26/2150.0 50.021H1156-03 [MW-01]
[TOC_1]Sample Preparation Information[TOC]
Page 18 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B288897 - SW-846 5030B
[TOC_3]B288897[TOC]
Blank (B288897-BLK1) Prepared & Analyzed: 08/25/21
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
[TOC_1]QC Data[TOC]
Page 19 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288897 - SW-846 5030B
Blank (B288897-BLK1) Prepared & Analyzed: 08/25/21
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.324.1
g/L 25.0 70-130Surrogate: Toluene-d8 96.624.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 94.723.7
LCS (B288897-BS1) Prepared & Analyzed: 08/25/21
Acetone g/L50 100 70-13093.893.8
Benzene g/L0.50 10.0 70-13093.19.31
Bromobenzene g/L0.50 10.0 70-13010310.3
Bromochloromethane g/L0.50 10.0 70-13010910.9
Bromodichloromethane g/L0.50 10.0 70-13010410.4
Bromoform g/L0.50 10.0 70-13011911.9
Bromomethane g/L2.0 10.0 60-14074.97.49
2-Butanone (MEK)g/L5.0 100 70-13099.299.2
n-Butylbenzene g/L0.50 10.0 70-13087.08.70
sec-Butylbenzene g/L0.50 10.0 70-13092.19.21
tert-Butylbenzene g/L0.50 10.0 70-13093.69.36
Carbon Tetrachloride g/L0.50 10.0 70-13010210.2
Chlorobenzene g/L0.50 10.0 70-13010310.3
Ethanol g/L50 100 70-13070.970.9
Chlorodibromomethane g/L0.50 10.0 70-13011011.0
Chloroethane g/L0.50 10.0 60-14012712.7
Chloroform g/L0.50 10.0 70-13097.89.78
Chloromethane g/L0.60 10.0 60-14086.58.65
2-Chlorotoluene g/L0.50 10.0 70-13093.79.37
4-Chlorotoluene g/L0.50 10.0 70-13096.89.68
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010710.7
1,2-Dichlorobenzene g/L0.50 10.0 70-13010210.2
1,3-Dichlorobenzene g/L0.50 10.0 70-13010110.1
1,4-Dichlorobenzene g/L0.50 10.0 70-13098.39.83
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14010110.1
1,1-Dichloroethane g/L0.50 10.0 70-13099.09.90
1,2-Dichloroethane g/L0.50 10.0 70-13010210.2
1,1-Dichloroethylene g/L0.50 10.0 70-13097.19.71
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13097.99.79
trans-1,2-Dichloroethylene g/L0.50 10.0 70-13090.59.05
1,2-Dichloropropane g/L0.50 10.0 70-13010510.5
1,3-Dichloropropane g/L0.50 10.0 70-13010710.7
2,2-Dichloropropane g/L0.50 10.0 70-13090.29.02
1,1-Dichloropropene g/L0.50 10.0 70-13094.19.41
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010310.3
trans-1,3-Dichloropropene g/L0.50 10.0 70-13010610.6
Page 20 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288897 - SW-846 5030B
LCS (B288897-BS1) Prepared & Analyzed: 08/25/21
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13010010.0
Ethylbenzene g/L0.50 10.0 70-13010110.1
2-Hexanone (MBK)g/L5.0 100 70-130106106
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13097.89.78
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13091.39.13
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13099.99.99
Methylene Chloride g/L5.0 10.0 70-13010710.7
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-130105105
Naphthalene g/L0.50 10.0 70-13080.28.02
n-Propylbenzene g/L0.50 10.0 70-13095.39.53
Styrene g/L0.50 10.0 70-13010110.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13011211.2
Tetrachloroethylene g/L0.50 10.0 70-13010210.2
Toluene g/L0.50 10.0 70-13099.39.93
1,2,3-Trichlorobenzene g/L1.0 10.0 70-13085.58.55
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13086.58.65
1,1,1-Trichloroethane g/L0.50 10.0 70-13099.29.92
1,1,2-Trichloroethane g/L0.50 10.0 70-13010710.7
Trichloroethylene g/L0.50 10.0 70-13010310.3
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13010410.4
1,2,3-Trichloropropane g/L0.50 10.0 70-13011411.4
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13092.99.29
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13094.59.45
Vinyl Acetate g/L20 100 70-130110110
Vinyl Chloride g/L0.50 10.0 60-14077.77.77
m+p Xylene g/L1.0 20.0 70-13010020.0
o-Xylene g/L0.50 10.0 70-13010210.2
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.224.1
g/L 25.0 70-130Surrogate: Toluene-d8 95.723.9
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.024.5
LCS Dup (B288897-BSD1) Prepared & Analyzed: 08/25/21
Acetone g/L50 100 2570-13089.3 4.8789.3
Benzene g/L0.50 10.0 2570-13090.5 2.839.05
Bromobenzene g/L0.50 10.0 2570-13099.0 3.779.90
Bromochloromethane g/L0.50 10.0 2570-130103 5.0010.3
Bromodichloromethane g/L0.50 10.0 2570-130100 3.7210.0
Bromoform g/L0.50 10.0 2570-130114 4.3011.4
Bromomethane g/L2.0 10.0 2560-14085.5 13.28.55
2-Butanone (MEK)g/L5.0 100 2570-13094.1 5.3094.1
n-Butylbenzene g/L0.50 10.0 2570-13088.2 1.378.82
sec-Butylbenzene g/L0.50 10.0 2570-13090.9 1.319.09
tert-Butylbenzene g/L0.50 10.0 2570-13092.8 0.8589.28
Carbon Tetrachloride g/L0.50 10.0 2570-13098.3 3.409.83
Chlorobenzene g/L0.50 10.0 2570-130100 2.8510.0
Ethanol g/L50 100 25 L-0770-13066.5 6.39*66.5
Chlorodibromomethane g/L0.50 10.0 2570-130104 5.5310.4
Chloroethane g/L0.50 10.0 2560-140124 2.5512.4
Chloroform g/L0.50 10.0 2570-13094.1 3.869.41
Chloromethane g/L0.60 10.0 2560-14083.5 3.538.35
2-Chlorotoluene g/L0.50 10.0 2570-13092.9 0.8579.29
4-Chlorotoluene g/L0.50 10.0 2570-13095.8 1.049.58
Page 21 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B288897 - SW-846 5030B
LCS Dup (B288897-BSD1) Prepared & Analyzed: 08/25/21
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130104 2.8410.4
1,2-Dichlorobenzene g/L0.50 10.0 2570-13099.2 2.499.92
1,3-Dichlorobenzene g/L0.50 10.0 2570-13098.5 2.319.85
1,4-Dichlorobenzene g/L0.50 10.0 2570-13098.1 0.2049.81
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14096.0 4.889.60
1,1-Dichloroethane g/L0.50 10.0 2570-13097.4 1.639.74
1,2-Dichloroethane g/L0.50 10.0 2570-13095.5 6.199.55
1,1-Dichloroethylene g/L0.50 10.0 2570-13092.3 5.079.23
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13096.7 1.239.67
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13087.0 3.948.70
1,2-Dichloropropane g/L0.50 10.0 2570-130101 3.6910.1
1,3-Dichloropropane g/L0.50 10.0 2570-130102 4.4010.2
2,2-Dichloropropane g/L0.50 10.0 2570-13091.8 1.769.18
1,1-Dichloropropene g/L0.50 10.0 2570-13092.6 1.619.26
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13099.9 3.359.99
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13099.4 6.719.94
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13096.5 3.569.65
Ethylbenzene g/L0.50 10.0 2570-13098.4 2.419.84
2-Hexanone (MBK)g/L5.0 100 2570-130101 4.58101
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13096.4 1.449.64
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13091.3 0.009.13
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13094.7 5.349.47
Methylene Chloride g/L5.0 10.0 2570-130100 6.1710.0
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-130100 4.17100
Naphthalene g/L0.50 10.0 2570-13077.4 3.557.74
n-Propylbenzene g/L0.50 10.0 2570-13094.1 1.279.41
Styrene g/L0.50 10.0 2570-13097.9 2.729.79
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130105 5.9910.5
Tetrachloroethylene g/L0.50 10.0 2570-13099.3 2.299.93
Toluene g/L0.50 10.0 2570-13097.0 2.349.70
1,2,3-Trichlorobenzene g/L1.0 10.0 2570-13083.0 2.978.30
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-13085.5 1.168.55
1,1,1-Trichloroethane g/L0.50 10.0 2570-13095.5 3.809.55
1,1,2-Trichloroethane g/L0.50 10.0 2570-130101 5.4710.1
Trichloroethylene g/L0.50 10.0 2570-130102 0.97910.2
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-130103 0.97010.3
1,2,3-Trichloropropane g/L0.50 10.0 2570-130107 6.4410.7
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13092.5 0.4319.25
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13092.6 2.039.26
Vinyl Acetate g/L20 100 2570-13097.8 11.597.8
Vinyl Chloride g/L0.50 10.0 2560-14074.5 4.207.45
m+p Xylene g/L1.0 20.0 2570-13097.8 2.1219.6
o-Xylene g/L0.50 10.0 2570-13099.2 3.179.92
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.423.8
g/L 25.0 70-130Surrogate: Toluene-d8 95.423.9
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 97.524.4
Page 22 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by - GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Semivolatile Organic Compounds by - GC/MS[TOC]
Batch B288889 - SW-846 3510C
[TOC_3]B288889[TOC]
Blank (B288889-BLK1) Prepared: 08/25/21 Analyzed: 08/27/21
Acenaphthene g/L5.00ND
Acenaphthylene g/L5.00ND
Anthracene g/L5.00ND
Benzidine g/L20.0 V-04, V-05, V-35ND
Benzo(a)anthracene g/L5.00ND
Benzo(a)pyrene g/L5.00ND
Benzo(b)fluoranthene g/L5.00ND
Benzo(g,h,i)perylene g/L5.00ND
Benzo(k)fluoranthene g/L5.00ND
4-Bromophenylphenylether g/L10.0ND
Butylbenzylphthalate g/L10.0ND
4-Chloro-3-methylphenol g/L10.0ND
Bis(2-chloroethoxy)methane g/L10.0ND
Bis(2-chloroethyl)ether g/L10.0ND
Bis(2-chloroisopropyl)ether g/L10.0ND
2-Chloronaphthalene g/L10.0 L-04ND
2-Chlorophenol g/L10.0ND
4-Chlorophenylphenylether g/L10.0ND
Chrysene g/L5.00ND
Dibenz(a,h)anthracene g/L5.00ND
Di-n-butylphthalate g/L10.0ND
1,3-Dichlorobenzene g/L5.00ND
1,4-Dichlorobenzene g/L5.00ND
1,2-Dichlorobenzene g/L5.00ND
3,3-Dichlorobenzidine g/L10.0ND
2,4-Dichlorophenol g/L10.0ND
Diethylphthalate g/L10.0ND
2,4-Dimethylphenol g/L10.0ND
Dimethylphthalate g/L10.0ND
4,6-Dinitro-2-methylphenol g/L10.0ND
2,4-Dinitrophenol g/L10.0ND
2,4-Dinitrotoluene g/L10.0ND
2,6-Dinitrotoluene g/L10.0ND
Di-n-octylphthalate g/L10.0ND
1,2-Diphenylhydrazine/Azobenzene g/L10.0ND
Bis(2-Ethylhexyl)phthalate g/L10.0ND
Fluoranthene g/L5.00ND
Fluorene g/L5.00ND
Hexachlorobenzene g/L10.0ND
Hexachlorobutadiene g/L10.0ND
Hexachlorocyclopentadiene g/L10.0ND
Hexachloroethane g/L10.0 L-04ND
Indeno(1,2,3-cd)pyrene g/L5.00ND
Isophorone g/L10.0ND
Naphthalene g/L5.00ND
Nitrobenzene g/L10.0ND
2-Nitrophenol g/L10.0ND
4-Nitrophenol g/L10.0ND
N-Nitrosodimethylamine g/L10.0 L-04ND
N-Nitrosodiphenylamine/Diphenylamine g/L10.0ND
N-Nitrosodi-n-propylamine g/L10.0ND
Pentachlorophenol g/L10.0ND
Page 23 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by - GC/MS - Quality Control
QUALITY CONTROL
Batch B288889 - SW-846 3510C
Blank (B288889-BLK1) Prepared: 08/25/21 Analyzed: 08/27/21
2-Methylnaphthalene g/L5.00ND
Phenanthrene g/L5.00ND
2-Methylphenol g/L10.0ND
Phenol g/L10.0ND
3/4-Methylphenol g/L20.0ND
Pyrene g/L5.00ND
1,2,4-Trichlorobenzene g/L5.00 L-04ND
2,4,6-Trichlorophenol g/L10.0ND
g/L 200 15-110Surrogate: 2-Fluorophenol 23.947.8
g/L 200 15-110Surrogate: Phenol-d6 22.144.2
g/L 100 30-130Surrogate: Nitrobenzene-d5 44.044.0
g/L 100 30-130Surrogate: 2-Fluorobiphenyl 45.545.5
g/L 200 15-110Surrogate: 2,4,6-Tribromophenol 60.5121
g/L 100 30-130Surrogate: p-Terphenyl-d14 76.276.2
LCS (B288889-BS1) Prepared: 08/25/21 Analyzed: 08/27/21
Acenaphthene g/L5.00 50.0 47-14564.432.2
Acenaphthylene g/L5.00 50.0 33-14561.130.5
Anthracene g/L5.00 50.0 27-13371.035.5
Benzidine g/L20.0 50.0 V-04, V-05, V-3540-14068.734.4
Benzo(a)anthracene g/L5.00 50.0 33-14365.332.7
Benzo(a)pyrene g/L5.00 50.0 17-16370.735.4
Benzo(b)fluoranthene g/L5.00 50.0 24-15966.233.1
Benzo(g,h,i)perylene g/L5.00 50.0 10-21972.036.0
Benzo(k)fluoranthene g/L5.00 50.0 11-16267.333.6
4-Bromophenylphenylether g/L10.0 50.0 53-12767.133.6
Butylbenzylphthalate g/L10.0 50.0 10-15271.335.6
4-Chloro-3-methylphenol g/L10.0 50.0 22-14762.731.3
Bis(2-chloroethoxy)methane g/L10.0 50.0 33-18457.128.6
Bis(2-chloroethyl)ether g/L10.0 50.0 12-15841.020.5
Bis(2-chloroisopropyl)ether g/L10.0 50.0 36-16666.733.3
2-Chloronaphthalene g/L10.0 50.0 L-0460-12055.8 *27.9
2-Chlorophenol g/L10.0 50.0 23-13443.621.8
4-Chlorophenylphenylether g/L10.0 50.0 25-15863.431.7
Chrysene g/L5.00 50.0 17-16867.333.6
Dibenz(a,h)anthracene g/L5.00 50.0 10-22769.334.6
Di-n-butylphthalate g/L10.0 50.0 10-12071.435.7
1,3-Dichlorobenzene g/L5.00 50.0 10-17239.419.7
1,4-Dichlorobenzene g/L5.00 50.0 20-12440.020.0
1,2-Dichlorobenzene g/L5.00 50.0 32-12941.020.5
3,3-Dichlorobenzidine g/L10.0 50.0 10-26273.336.6
2,4-Dichlorophenol g/L10.0 50.0 39-13560.530.3
Diethylphthalate g/L10.0 50.0 10-12065.032.5
2,4-Dimethylphenol g/L10.0 50.0 32-12055.327.6
Dimethylphthalate g/L10.0 50.0 10-12064.232.1
4,6-Dinitro-2-methylphenol g/L10.0 50.0 10-18185.842.9
2,4-Dinitrophenol g/L10.0 50.0 10-19182.141.1
2,4-Dinitrotoluene g/L10.0 50.0 39-13970.035.0
2,6-Dinitrotoluene g/L10.0 50.0 50-15870.635.3
Di-n-octylphthalate g/L10.0 50.0 4-14674.937.4
1,2-Diphenylhydrazine/Azobenzene g/L10.0 50.0 40-14072.836.4
Bis(2-Ethylhexyl)phthalate g/L10.0 50.0 8-15876.838.4
Page 24 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by - GC/MS - Quality Control
QUALITY CONTROL
Batch B288889 - SW-846 3510C
LCS (B288889-BS1) Prepared: 08/25/21 Analyzed: 08/27/21
Fluoranthene g/L5.00 50.0 26-13767.833.9
Fluorene g/L5.00 50.0 59-12167.333.6
Hexachlorobenzene g/L10.0 50.0 10-15268.934.5
Hexachlorobutadiene g/L10.0 50.0 24-12037.218.6
Hexachlorocyclopentadiene g/L10.0 50.0 40-14047.123.5
Hexachloroethane g/L10.0 50.0 L-0440-12037.8 *18.9
Indeno(1,2,3-cd)pyrene g/L5.00 50.0 10-17172.036.0
Isophorone g/L10.0 50.0 21-19661.931.0
Naphthalene g/L5.00 50.0 21-13347.623.8
Nitrobenzene g/L10.0 50.0 35-18048.224.1
2-Nitrophenol g/L10.0 50.0 29-18256.628.3
4-Nitrophenol g/L10.0 50.0 10-13234.717.3
N-Nitrosodimethylamine g/L10.0 50.0 L-0440-14039.0 *19.5
N-Nitrosodiphenylamine/Diphenylamine g/L10.0 50.0 40-14079.639.8
N-Nitrosodi-n-propylamine g/L10.0 50.0 10-23054.927.4
Pentachlorophenol g/L10.0 50.0 14-17668.434.2
2-Methylnaphthalene g/L5.00 50.0 40-14061.030.5
Phenanthrene g/L5.00 50.0 54-12068.434.2
2-Methylphenol g/L10.0 50.0 40-14045.622.8
Phenol g/L10.0 50.0 5-12024.212.1
3/4-Methylphenol g/L20.0 50.0 40-14050.325.2
Pyrene g/L5.00 50.0 52-12067.333.7
1,2,4-Trichlorobenzene g/L5.00 50.0 L-0444-14243.1 *21.5
2,4,6-Trichlorophenol g/L10.0 50.0 37-14466.533.2
g/L 200 15-110Surrogate: 2-Fluorophenol 26.552.9
g/L 200 15-110Surrogate: Phenol-d6 29.759.4
g/L 100 30-130Surrogate: Nitrobenzene-d5 51.351.3
g/L 100 30-130Surrogate: 2-Fluorobiphenyl 67.867.8
g/L 200 15-110Surrogate: 2,4,6-Tribromophenol 74.2148
g/L 100 30-130Surrogate: p-Terphenyl-d14 86.486.4
LCS Dup (B288889-BSD1) Prepared: 08/25/21 Analyzed: 08/27/21
Acenaphthene g/L5.00 50.0 4847-14557.4 11.428.7
Acenaphthylene g/L5.00 50.0 7433-14553.9 12.427.0
Anthracene g/L5.00 50.0 6627-13361.9 13.731.0
Benzidine g/L20.0 50.0 30 V-04, V-05, V-3540-14062.9 8.8131.4
Benzo(a)anthracene g/L5.00 50.0 5333-14357.5 12.828.7
Benzo(a)pyrene g/L5.00 50.0 7217-16362.6 12.131.3
Benzo(b)fluoranthene g/L5.00 50.0 7124-15958.9 11.629.5
Benzo(g,h,i)perylene g/L5.00 50.0 9710-21963.3 12.931.6
Benzo(k)fluoranthene g/L5.00 50.0 6311-16259.4 12.429.7
4-Bromophenylphenylether g/L10.0 50.0 4353-12759.2 12.629.6
Butylbenzylphthalate g/L10.0 50.0 6010-15262.3 13.531.2
4-Chloro-3-methylphenol g/L10.0 50.0 7322-14756.8 9.8428.4
Bis(2-chloroethoxy)methane g/L10.0 50.0 5433-18451.9 9.6125.9
Bis(2-chloroethyl)ether g/L10.0 50.0 10812-15838.1 7.2819.0
Bis(2-chloroisopropyl)ether g/L10.0 50.0 7636-16661.4 8.2130.7
2-Chloronaphthalene g/L10.0 50.0 24 L-0460-12048.8 13.3*24.4
2-Chlorophenol g/L10.0 50.0 6123-13441.0 6.1520.5
4-Chlorophenylphenylether g/L10.0 50.0 6125-15855.8 12.627.9
Chrysene g/L5.00 50.0 8717-16858.7 13.729.3
Dibenz(a,h)anthracene g/L5.00 50.0 12610-22759.7 14.929.8
Page 25 of 39
Table of Contents
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Semivolatile Organic Compounds by - GC/MS - Quality Control
QUALITY CONTROL
Batch B288889 - SW-846 3510C
LCS Dup (B288889-BSD1) Prepared: 08/25/21 Analyzed: 08/27/21
Di-n-butylphthalate g/L10.0 50.0 4710-12063.0 12.531.5
1,3-Dichlorobenzene g/L5.00 50.0 3010-17237.0 6.4918.5
1,4-Dichlorobenzene g/L5.00 50.0 3020-12437.9 5.3419.0
1,2-Dichlorobenzene g/L5.00 50.0 3032-12938.4 6.4019.2
3,3-Dichlorobenzidine g/L10.0 50.0 10810-26265.6 11.132.8
2,4-Dichlorophenol g/L10.0 50.0 5039-13555.3 8.9427.7
Diethylphthalate g/L10.0 50.0 10010-12056.9 13.328.4
2,4-Dimethylphenol g/L10.0 50.0 5832-12049.6 10.824.8
Dimethylphthalate g/L10.0 50.0 18310-12056.8 12.228.4
4,6-Dinitro-2-methylphenol g/L10.0 50.0 20310-18175.8 12.337.9
2,4-Dinitrophenol g/L10.0 50.0 13210-19175.9 7.8538.0
2,4-Dinitrotoluene g/L10.0 50.0 4239-13963.1 10.331.6
2,6-Dinitrotoluene g/L10.0 50.0 4850-15863.0 11.331.5
Di-n-octylphthalate g/L10.0 50.0 694-14665.5 13.532.7
1,2-Diphenylhydrazine/Azobenzene g/L10.0 50.0 3040-14062.9 14.631.4
Bis(2-Ethylhexyl)phthalate g/L10.0 50.0 828-15867.3 13.333.6
Fluoranthene g/L5.00 50.0 6626-13760.2 11.930.1
Fluorene g/L5.00 50.0 3859-12159.7 11.929.8
Hexachlorobenzene g/L10.0 50.0 5510-15261.1 12.030.6
Hexachlorobutadiene g/L10.0 50.0 6224-12037.0 0.59318.5
Hexachlorocyclopentadiene g/L10.0 50.0 3040-14043.7 7.5421.8
Hexachloroethane g/L10.0 50.0 52 L-0440-12036.1 4.38*18.1
Indeno(1,2,3-cd)pyrene g/L5.00 50.0 9910-17162.6 14.031.3
Isophorone g/L10.0 50.0 9321-19655.1 11.627.6
Naphthalene g/L5.00 50.0 6521-13345.4 4.6922.7
Nitrobenzene g/L10.0 50.0 6235-18045.4 5.9022.7
2-Nitrophenol g/L10.0 50.0 5529-18253.7 5.1926.8
4-Nitrophenol g/L10.0 50.0 13110-13231.1 11.015.5
N-Nitrosodimethylamine g/L10.0 50.0 30 L-0440-14034.8 11.3*17.4
N-Nitrosodiphenylamine/Diphenylamine g/L10.0 50.0 3040-14070.0 12.835.0
N-Nitrosodi-n-propylamine g/L10.0 50.0 8710-23049.2 11.024.6
Pentachlorophenol g/L10.0 50.0 8614-17657.9 16.628.9
2-Methylnaphthalene g/L5.00 50.0 3040-14056.8 7.1328.4
Phenanthrene g/L5.00 50.0 3954-12060.3 12.730.1
2-Methylphenol g/L10.0 50.0 3040-14041.8 8.5120.9
Phenol g/L10.0 50.0 645-12022.5 7.4511.2
3/4-Methylphenol g/L20.0 50.0 3040-14045.0 11.222.5
Pyrene g/L5.00 50.0 4952-12059.3 12.729.6
1,2,4-Trichlorobenzene g/L5.00 50.0 50 L-0444-14241.5 3.69*20.8
2,4,6-Trichlorophenol g/L10.0 50.0 5837-14459.8 10.629.9
g/L 200 15-110Surrogate: 2-Fluorophenol 25.250.3
g/L 200 15-110Surrogate: Phenol-d6 27.454.8
g/L 100 30-130Surrogate: Nitrobenzene-d5 47.447.4
g/L 100 30-130Surrogate: 2-Fluorobiphenyl 59.759.7
g/L 200 15-110Surrogate: 2,4,6-Tribromophenol 65.7131
g/L 100 30-130Surrogate: p-Terphenyl-d14 74.774.7
Page 26 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - EPH[TOC]
Batch B288844 - SW-846 3510C
[TOC_3]B288844[TOC]
Blank (B288844-BLK1) Prepared: 08/24/21 Analyzed: 08/26/21
C9-C18 Aliphatics g/L100ND
C19-C36 Aliphatics g/L100ND
C11-C22 Aromatics g/L100ND
Acenaphthene g/L2.0ND
Acenaphthylene g/L2.0ND
Anthracene g/L2.0ND
Benzo(a)anthracene g/L2.0ND
Benzo(a)pyrene g/L2.0ND
Benzo(b)fluoranthene g/L2.0ND
Benzo(g,h,i)perylene g/L2.0ND
Benzo(k)fluoranthene g/L2.0ND
Chrysene g/L2.0ND
Dibenz(a,h)anthracene g/L2.0ND
Fluoranthene g/L2.0ND
Fluorene g/L2.0ND
Indeno(1,2,3-cd)pyrene g/L2.0ND
2-Methylnaphthalene g/L2.0ND
Naphthalene g/L2.0ND
Phenanthrene g/L2.0ND
Pyrene g/L2.0ND
Naphthalene-aliphatic fraction g/L2.0ND
2-Methylnaphthalene-aliphatic fraction g/L2.0ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)85.585.5
g/L 100 40-140Surrogate: o-Terphenyl (OTP)76.376.3
g/L 100 40-140Surrogate: 2-Bromonaphthalene 77.477.4
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 75.075.0
LCS (B288844-BS1) Prepared: 08/24/21 Analyzed: 08/26/21
C9-C18 Aliphatics g/L100 600 40-14074.9450
C19-C36 Aliphatics g/L100 800 40-14089.8718
Acenaphthene g/L2.0 100 40-14064.164.1
Acenaphthylene g/L2.0 100 40-14060.060.0
Anthracene g/L2.0 100 40-14074.574.5
Benzo(a)anthracene g/L2.0 100 40-14089.089.0
Benzo(a)pyrene g/L2.0 100 40-14085.085.0
Benzo(b)fluoranthene g/L2.0 100 40-14082.682.6
Benzo(g,h,i)perylene g/L2.0 100 40-14077.177.1
Benzo(k)fluoranthene g/L2.0 100 40-14079.579.5
Chrysene g/L2.0 100 40-14084.084.0
Dibenz(a,h)anthracene g/L2.0 100 40-14081.981.9
Fluoranthene g/L2.0 100 40-14079.079.0
Fluorene g/L2.0 100 40-14065.865.8
Indeno(1,2,3-cd)pyrene g/L2.0 100 40-14076.876.8
2-Methylnaphthalene g/L2.0 100 40-14056.156.1
Naphthalene g/L2.0 100 40-14051.151.1
Phenanthrene g/L2.0 100 40-14075.775.7
Pyrene g/L2.0 100 40-14080.980.9
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)82.482.4
g/L 100 40-140Surrogate: o-Terphenyl (OTP)74.074.0
g/L 100 40-140Surrogate: 2-Bromonaphthalene 83.683.6
Page 27 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
Batch B288844 - SW-846 3510C
LCS (B288844-BS1) Prepared: 08/24/21 Analyzed: 08/26/21
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 84.284.2
LCS Dup (B288844-BSD1) Prepared: 08/24/21 Analyzed: 08/26/21
C9-C18 Aliphatics g/L100 600 2540-14064.7 14.7388
C19-C36 Aliphatics g/L100 800 2540-14079.5 12.2636
Acenaphthene g/L2.0 100 2540-14059.2 8.0359.2
Acenaphthylene g/L2.0 100 2540-14055.8 7.1555.8
Anthracene g/L2.0 100 2540-14064.7 14.064.7
Benzo(a)anthracene g/L2.0 100 2540-14077.2 14.277.2
Benzo(a)pyrene g/L2.0 100 2540-14073.5 14.673.5
Benzo(b)fluoranthene g/L2.0 100 2540-14071.3 14.671.3
Benzo(g,h,i)perylene g/L2.0 100 2540-14066.7 14.466.7
Benzo(k)fluoranthene g/L2.0 100 2540-14068.9 14.368.9
Chrysene g/L2.0 100 2540-14072.9 14.272.9
Dibenz(a,h)anthracene g/L2.0 100 2540-14070.7 14.770.7
Fluoranthene g/L2.0 100 2540-14067.7 15.467.7
Fluorene g/L2.0 100 2540-14059.2 10.659.2
Indeno(1,2,3-cd)pyrene g/L2.0 100 2540-14066.2 14.866.2
2-Methylnaphthalene g/L2.0 100 2540-14053.4 5.0453.4
Naphthalene g/L2.0 100 2540-14049.7 2.8349.7
Phenanthrene g/L2.0 100 2540-14066.0 13.866.0
Pyrene g/L2.0 100 2540-14069.6 15.169.6
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)70.270.2
g/L 100 40-140Surrogate: o-Terphenyl (OTP)64.164.1
g/L 100 40-140Surrogate: 2-Bromonaphthalene 83.783.7
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 84.984.9
Page 28 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - VPH[TOC]
Batch B288805 - MA VPH
[TOC_3]B288805[TOC]
Blank (B288805-BLK1) Prepared & Analyzed: 08/24/21
Unadjusted C5-C8 Aliphatics g/L100ND
C5-C8 Aliphatics g/L100ND
Unadjusted C9-C12 Aliphatics g/L100ND
C9-C12 Aliphatics g/L100ND
C9-C10 Aromatics g/L100ND
Benzene g/L1.0ND
Butylcyclohexane g/L1.0ND
Decane g/L1.0ND
Ethylbenzene g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
2-Methylpentane g/L1.0ND
Naphthalene g/L5.0ND
Nonane g/L1.0ND
Pentane g/L1.0ND
Toluene g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
2,2,4-Trimethylpentane g/L1.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10240.8
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)88.835.5
LCS (B288805-BS1) Prepared & Analyzed: 08/24/21
Benzene g/L1.0 50.0 70-13089.244.6
Butylcyclohexane g/L1.0 50.0 70-13012462.1
Decane g/L1.0 50.0 70-13095.047.5
Ethylbenzene g/L1.0 50.0 70-13090.145.1
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 70-13089.344.6
2-Methylpentane g/L1.0 50.0 70-13091.745.9
Naphthalene g/L5.0 50.0 70-13010954.4
Nonane g/L1.0 50.0 70-13012461.8
Pentane g/L1.0 50.0 70-13094.047.0
Toluene g/L1.0 50.0 70-13088.444.2
1,2,4-Trimethylbenzene g/L1.0 50.0 70-13085.242.6
2,2,4-Trimethylpentane g/L1.0 50.0 70-13087.543.8
m+p Xylene g/L2.0 100 70-13089.589.5
o-Xylene g/L1.0 50.0 70-13090.245.1
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10240.8
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)98.539.4
LCS Dup (B288805-BSD1) Prepared & Analyzed: 08/24/21
Benzene g/L1.0 50.0 2570-13086.1 3.5143.0
Butylcyclohexane g/L1.0 50.0 2570-130120 3.1160.2
Decane g/L1.0 50.0 2570-13089.8 5.6544.9
Ethylbenzene g/L1.0 50.0 2570-13087.3 3.1943.7
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 2570-13090.8 1.6845.4
2-Methylpentane g/L1.0 50.0 2570-13085.4 7.0842.7
Naphthalene g/L5.0 50.0 2570-130111 1.8955.4
Nonane g/L1.0 50.0 2570-130120 2.6260.2
Pentane g/L1.0 50.0 2570-13086.5 8.3843.2
Toluene g/L1.0 50.0 2570-13085.9 2.8542.9
1,2,4-Trimethylbenzene g/L1.0 50.0 2570-13083.2 2.3241.6
Page 29 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
Batch B288805 - MA VPH
LCS Dup (B288805-BSD1) Prepared & Analyzed: 08/24/21
2,2,4-Trimethylpentane g/L1.0 50.0 2570-13082.0 6.5741.0
m+p Xylene g/L2.0 100 2570-13086.8 3.0386.8
o-Xylene g/L1.0 50.0 2570-13088.2 2.2644.1
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10642.5
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)10642.5
Page 30 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Metals Analyses (Total) - Quality Control
QUALITY CONTROL
[TOC_2]Metals Analyses (Total)[TOC]
Batch B288997 - SW-846 3005A
[TOC_3]B288997[TOC]
Blank (B288997-BLK1) Prepared & Analyzed: 08/26/21
Lead g/L0.50ND
LCS (B288997-BS1) Prepared & Analyzed: 08/26/21
Lead g/L5.0 500 80-120102511
LCS Dup (B288997-BSD1) Prepared & Analyzed: 08/26/21
Lead g/L5.0 500 2080-120104 2.11522
Page 31 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
FLAG/QUALIFIER SUMMARY
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Initial calibration did not meet method specifications. Compound was calibrated using a response factor where
%RSD is outside of method specified criteria. Reported result is estimated.
V-04
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this
compound. Reported result is estimated.
V-35
[TOC_1]Flag/Qualifier Summary[TOC]
Page 32 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
625.1 in Water
CT,MA,NH,NY,NC,RI,ME,VAAcenaphthene
CT,MA,NH,NY,NC,RI,ME,VAAcenaphthylene
CT,MA,NH,NY,NC,RI,ME,VAAnthracene
CT,MA,NH,NY,NC,RI,ME,VABenzidine
CT,MA,NH,NY,NC,RI,ME,VABenzo(a)anthracene
CT,MA,NH,NY,NC,RI,ME,VABenzo(a)pyrene
CT,MA,NH,NY,NC,RI,ME,VABenzo(b)fluoranthene
CT,MA,NH,NY,NC,RI,ME,VABenzo(g,h,i)perylene
CT,MA,NH,NY,NC,RI,ME,VABenzo(k)fluoranthene
CT,MA,NH,NY,NC,RI,ME,VA4-Bromophenylphenylether
CT,MA,NH,NY,NC,RI,ME,VAButylbenzylphthalate
CT,MA,NH,NY,NC,RI,VA4-Chloro-3-methylphenol
CT,MA,NH,NY,NC,RI,ME,VABis(2-chloroethoxy)methane
CT,MA,NH,NY,NC,RI,ME,VABis(2-chloroethyl)ether
CT,MA,NH,NY,NC,RI,ME,VABis(2-chloroisopropyl)ether
CT,MA,NH,NY,NC,RI,ME,VA2-Chloronaphthalene
CT,MA,NH,NY,NC,RI,ME,VA2-Chlorophenol
CT,MA,NH,NY,NC,RI,ME,VA4-Chlorophenylphenylether
CT,MA,NH,NY,NC,RI,ME,VAChrysene
CT,MA,NH,NY,NC,RI,ME,VADibenz(a,h)anthracene
CT,MA,NH,NY,NC,RI,ME,VADi-n-butylphthalate
MA,NC1,3-Dichlorobenzene
MA,NC1,4-Dichlorobenzene
MA,NC1,2-Dichlorobenzene
CT,MA,NH,NY,NC,RI,ME,VA3,3-Dichlorobenzidine
CT,MA,NH,NY,NC,RI,ME,VA2,4-Dichlorophenol
CT,MA,NH,NY,NC,RI,ME,VADiethylphthalate
CT,MA,NH,NY,NC,RI,ME,VA2,4-Dimethylphenol
CT,MA,NH,NY,NC,RI,ME,VADimethylphthalate
CT,MA,NH,NY,NC,RI,ME,VA4,6-Dinitro-2-methylphenol
CT,MA,NH,NY,NC,RI,ME,VA2,4-Dinitrophenol
CT,MA,NH,NY,NC,RI,ME,VA2,4-Dinitrotoluene
CT,MA,NH,NY,NC,RI,ME,VA2,6-Dinitrotoluene
CT,MA,NH,NY,NC,RI,ME,VADi-n-octylphthalate
NC1,2-Diphenylhydrazine/Azobenzene
CT,MA,NH,NY,NC,RI,ME,VABis(2-Ethylhexyl)phthalate
CT,MA,NH,NY,NC,RI,ME,VAFluoranthene
CT,MA,NH,NY,NC,RI,ME,VAFluorene
CT,MA,NH,NY,NC,RI,ME,VAHexachlorobenzene
CT,MA,NH,NY,NC,RI,ME,VAHexachlorobutadiene
CT,MA,NH,NY,NC,RI,ME,VAHexachlorocyclopentadiene
CT,MA,NH,NY,NC,RI,ME,VAHexachloroethane
CT,MA,NH,NY,NC,RI,ME,VAIndeno(1,2,3-cd)pyrene
CT,MA,NH,NY,NC,RI,ME,VAIsophorone
CT,MA,NH,NY,NC,RI,ME,VANaphthalene
CT,MA,NH,NY,NC,RI,ME,VANitrobenzene
CT,MA,NH,NY,NC,RI,ME,VA2-Nitrophenol
[TOC_1]Certifications[TOC]
Page 33 of 39
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
625.1 in Water
CT,MA,NH,NY,NC,RI,ME,VA4-Nitrophenol
CT,MA,NH,NY,NC,RI,ME,VAN-Nitrosodimethylamine
CT,MA,NH,NY,NC,RI,ME,VAN-Nitrosodi-n-propylamine
CT,MA,NH,NY,NC,RI,ME,VAPentachlorophenol
NC2-Methylnaphthalene
CT,MA,NH,NY,NC,RI,ME,VAPhenanthrene
NY,NC2-Methylphenol
CT,MA,NH,NY,NC,RI,ME,VAPhenol
NY,NC3/4-Methylphenol
CT,MA,NH,NY,NC,RI,ME,VAPyrene
CT,MA,NH,NY,NC,RI,ME,VA1,2,4-Trichlorobenzene
CT,MA,NH,NY,NC,RI,ME,VA2,4,6-Trichlorophenol
NC2-Fluorophenol
MADEP EPH rev 2.1 in Water
CT,NC,ME,NH-PC9-C18 Aliphatics
CT,NC,ME,NH-PC19-C36 Aliphatics
CT,NC,ME,NH-PC11-C22 Aromatics
CT,NC,ME,NH-PAcenaphthene
CT,NC,ME,NH-PAcenaphthylene
CT,NC,ME,NH-PAnthracene
CT,NC,ME,NH-PBenzo(a)anthracene
CT,NC,ME,NH-PBenzo(a)pyrene
CT,NC,ME,NH-PBenzo(b)fluoranthene
CT,NC,ME,NH-PBenzo(g,h,i)perylene
CT,NC,ME,NH-PBenzo(k)fluoranthene
CT,NC,ME,NH-PChrysene
CT,NC,ME,NH-PDibenz(a,h)anthracene
CT,NC,ME,NH-PFluoranthene
CT,NC,MEFluorene
CT,NC,ME,NH-PIndeno(1,2,3-cd)pyrene
CT,NC,ME2-Methylnaphthalene
CT,NC,ME,NH-PNaphthalene
CT,NC,ME,NH-PPhenanthrene
CT,NC,ME,NH-PPyrene
MADEP-VPH-Feb 2018 Rev 2.1 in Water
CT,NC,ME,NH-PUnadjusted C5-C8 Aliphatics
CT,NC,ME,NH-PC5-C8 Aliphatics
CT,NC,ME,NH-PUnadjusted C9-C12 Aliphatics
CT,NC,ME,NH-PC9-C12 Aliphatics
CT,NC,ME,NH-PC9-C10 Aromatics
CT,NC,ME,NH-PBenzene
CT,NC,ME,NH-PEthylbenzene
CT,NC,ME,NH-PMethyl tert-Butyl Ether (MTBE)
CT,NC,ME,NH-PNaphthalene
CT,NC,ME,NH-PToluene
CT,NC,ME,NH-Pm+p Xylene
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP-VPH-Feb 2018 Rev 2.1 in Water
CT,NC,ME,NH-Po-Xylene
SM21-23 6200B in Water
NCAcetone
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCCarbon Tetrachloride
NCChlorobenzene
NCEthanol
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromoethane (EDB)
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiisopropyl Ether (DIPE)
NCEthylbenzene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-23 6200B in Water
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Acetate
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
SW-846 6020B in Water
CT,NH,NY,ME,VA,NCLead
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Code Description Number Expires
100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022
M-MA100Massachusetts DEPMA 06/30/2022
PH-0165Connecticut Department of Publilc HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2022
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2022
LAO00112Rhode Island Department of HealthRI 12/30/2021
652North Carolina Div. of Water QualityNC 12/31/2021
MA007 NELAPNew Jersey DEPNJ 06/30/2022
E871027 NELAPFlorida Department of HealthFL 06/30/2022
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2022
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2021
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2021
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2022
25703North Carolina Department of HealthNC-DW 07/31/2022
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2022
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2021
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