RA-1601_10221_CA_LAB_20231122_Waypoint Lab Rpt 23-320-0013PDFreport

 
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

11/22/2023
North Carolina Dept of Environmental Quality Linda Blalock
1646 Mail Service Center Raleigh, NC, 27699
Ref: Analytical Testing
Lab Report Number: 23-320-0013 Client Project Description: 6166 Highway 96N
TF#10221
Dear Linda Blalock:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/16/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 21
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202437735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202499012State ProgramSouth Carolina
12/31/202399012State ProgramSouth Carolina
Page 1 of 1 00016/23-320-0013
Page 2 of 21
Report Number:
Sample Summary Table
Client Project Description:
23-320-0013
6166 Highway 96N
TF#10221
Lab No Client Sample ID Matrix Date Collected Date Received
11/09/2023 15:31Aqueous 89370 D1 11/16/2023 10:00
11/09/2023 15:34Aqueous 89371 D3 11/16/2023 10:00
Page 3 of 21
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-320-0013
Report Limit
Project:6166 Highway 96N
V 89370D1
0.778 11/16/2023 23:336200Bsec-Butyl benzene µg/L 0.500
0.608 11/16/2023 23:336200B1,2-Dichloroethane µg/L 0.500
Page 4 of 21

Client: North Carolina Dept of Environmental Quality CASE NARRATIVE
Project: 6166 Highway 96N Lab Report Number: 23-320-0013
Date: 11/20/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V40342/V40340
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 2-Butanone QC Batch No: V40342/V40340
LCS fails high. All other QC associated with this batch passes including the LCSD. Data not affected. No further action taken.

Page 5 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D1
89370 Matrix:
11/9/2023 15:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<10.0 µg/L 10.0Acetone 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Benzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Bromobenzene 1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.00Bromochloromethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Bromodichloromethane 1 11/16/23 23:33 V40342MSA
<5.00 µg/L 5.00Bromoform 1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.00Bromomethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500n-Butylbenzene 1 11/16/23 23:33 V40342MSA
0.778 µg/L 0.500sec-Butyl benzene 1 11/16/23 23:33 V40342MSA
<2.00 µg/L 2.00tert-Butyl benzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Chlorobenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Chlorodibromomethane 1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.00Chloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Chloroform 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Chloromethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5002-Chlorotoluene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5004-Chlorotoluene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 11/16/23 23:33 V40342MSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Dibromomethane 1 11/16/23 23:33 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D1
89370 Matrix:
11/9/2023 15:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 11/16/23 23:33 V40342MSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 11/16/23 23:33 V40342MSA
0.608 µg/L 0.5001,2-Dichloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 11/16/23 23:33 V40342MSA
<2.00 µg/L 2.002,2-Dichloropropane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 11/16/23 23:33 V40342MSA
<200 µg/L 200Ethanol 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Ethylbenzene 1 11/16/23 23:33 V40342MSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.002-Hexanone 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Isopropylbenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 11/16/23 23:33 V40342MSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 11/16/23 23:33 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D1
89370 Matrix:
11/9/2023 15:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 11/16/23 23:33 V40342MSA
<2.00 µg/L 2.00Methylene Chloride 1 11/16/23 23:33 V40342MSA
<1.00 µg/L 1.00Naphthalene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500n-Propylbenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Styrene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Tetrachloroethene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Toluene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Trichloroethene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 11/16/23 23:33 V40342MSA
<5.00 µg/L 5.00Vinyl Acetate 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Vinyl Chloride 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500o-Xylene 1 11/16/23 23:33 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D1
89370 Matrix:
11/9/2023 15:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<1.00 µg/L 1.00m,p-Xylene 1 11/16/23 23:33 V40342MSA
<0.500 µg/L 0.500Xylene (Total)1 11/16/23 23:33 V40342
Surrogate: 4-Bromofluorobenzene 98.8 Limits: 70-130%11/16/23 23:331 MSA V40342
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%11/16/23 23:331 MSA V40342
Surrogate: 1,2-Dichloroethane - d4 104 Limits: 70-130%11/16/23 23:331 MSA V40342
Surrogate: Toluene-d8 97.0 Limits: 70-130%11/16/23 23:331 MSA V40342
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 9 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D3
89371 Matrix:
11/9/2023 15:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<10.0 µg/L 10.0Acetone 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Benzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Bromobenzene 1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.00Bromochloromethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Bromodichloromethane 1 11/16/23 23:57 V40342MSA
<5.00 µg/L 5.00Bromoform 1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.00Bromomethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500n-Butylbenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500sec-Butyl benzene 1 11/16/23 23:57 V40342MSA
<2.00 µg/L 2.00tert-Butyl benzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Chlorobenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Chlorodibromomethane 1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.00Chloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Chloroform 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Chloromethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5002-Chlorotoluene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5004-Chlorotoluene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 11/16/23 23:57 V40342MSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Dibromomethane 1 11/16/23 23:57 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 10 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D3
89371 Matrix:
11/9/2023 15:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 11/16/23 23:57 V40342MSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 11/16/23 23:57 V40342MSA
<2.00 µg/L 2.002,2-Dichloropropane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 11/16/23 23:57 V40342MSA
<200 µg/L 200Ethanol 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Ethylbenzene 1 11/16/23 23:57 V40342MSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.002-Hexanone 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Isopropylbenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 11/16/23 23:57 V40342MSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 11/16/23 23:57 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 11 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D3
89371 Matrix:
11/9/2023 15:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 11/16/23 23:57 V40342MSA
<2.00 µg/L 2.00Methylene Chloride 1 11/16/23 23:57 V40342MSA
<1.00 µg/L 1.00Naphthalene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500n-Propylbenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Styrene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Tetrachloroethene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Toluene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Trichloroethene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 11/16/23 23:57 V40342MSA
<5.00 µg/L 5.00Vinyl Acetate 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Vinyl Chloride 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500o-Xylene 1 11/16/23 23:57 V40342MSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 12 of 21
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27699
23-320-0013
00439
North Carolina Dept of Environmental Quality
1646 Mail Service Center
Linda Blalock
Raleigh
Danyale Love
Project Manager
TF#10221 Received : 11/16/2023
6166 Highway 96N
Report Date : 11/22/2023
Sample ID :
Lab No :
Sampled:D3
89371 Matrix:
11/9/2023 15:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V40340 11/16/23 09:00
<1.00 µg/L 1.00m,p-Xylene 1 11/16/23 23:57 V40342MSA
<0.500 µg/L 0.500Xylene (Total)1 11/16/23 23:57 V40342
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%11/16/23 23:571 MSA V40342
Surrogate: Dibromofluoromethane 97.6 Limits: 70-130%11/16/23 23:571 MSA V40342
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%11/16/23 23:571 MSA V40342
Surrogate: Toluene-d8 99.8 Limits: 70-130%11/16/23 23:571 MSA V40342
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 13 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
Associated Lab Samples: 89370, 89371
LRB-V40340 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/16/23 19:2610.0< 10.0µg/LAcetone
11/16/23 19:260.500< 0.500µg/LBenzene
11/16/23 19:260.500< 0.500µg/LBromobenzene
11/16/23 19:261.00< 1.00µg/LBromochloromethane
11/16/23 19:260.500< 0.500µg/LBromodichloromethane
11/16/23 19:265.00< 5.00µg/LBromoform
11/16/23 19:261.00< 1.00µg/LBromomethane
11/16/23 19:260.500< 0.500µg/Ln-Butylbenzene
11/16/23 19:260.500< 0.500µg/Lsec-Butyl benzene
11/16/23 19:262.00< 2.00µg/Ltert-Butyl benzene
11/16/23 19:260.500< 0.500µg/LCarbon Tetrachloride
11/16/23 19:260.500< 0.500µg/LChlorobenzene
11/16/23 19:260.500< 0.500µg/LChlorodibromomethane
11/16/23 19:261.00< 1.00µg/LChloroethane
11/16/23 19:260.500< 0.500µg/LChloroform
11/16/23 19:260.500< 0.500µg/LChloromethane
11/16/23 19:260.500< 0.500µg/L2-Chlorotoluene
11/16/23 19:260.500< 0.500µg/L4-Chlorotoluene
11/16/23 19:260.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
11/16/23 19:262.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
11/16/23 19:260.500< 0.500µg/L1,2-Dibromoethane
11/16/23 19:260.500< 0.500µg/LDibromomethane
11/16/23 19:260.500< 0.500µg/L1,2-Dichlorobenzene
11/16/23 19:260.500< 0.500µg/L1,3-Dichlorobenzene
11/16/23 19:260.500< 0.500µg/L1,4-Dichlorobenzene
11/16/23 19:265.00< 5.00µg/LDichlorodifluoromethane
11/16/23 19:260.500< 0.500µg/L1,1-Dichloroethane
Page 1 of 6Date:11/22/2023 05:28 PM
Page 14 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
Associated Lab Samples: 89370, 89371
LRB-V40340 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/16/23 19:260.500< 0.500µg/L1,2-Dichloroethane
11/16/23 19:260.500< 0.500µg/L1,1-Dichloroethene
11/16/23 19:260.500< 0.500µg/Lcis-1,2-Dichloroethene
11/16/23 19:260.500< 0.500µg/Ltrans-1,2-Dichloroethene
11/16/23 19:260.500< 0.500µg/L1,2-Dichloropropane
11/16/23 19:260.500< 0.500µg/L1,3-Dichloropropane
11/16/23 19:262.00< 2.00µg/L2,2-Dichloropropane
11/16/23 19:260.500< 0.500µg/L1,1-Dichloropropene
11/16/23 19:260.500< 0.500µg/Lcis-1,3-Dichloropropene
11/16/23 19:260.500< 0.500µg/Ltrans-1,3-Dichloropropene
11/16/23 19:26200< 200µg/LEthanol
11/16/23 19:260.500< 0.500µg/LEthylbenzene
11/16/23 19:263.00< 3.00µg/LHexachlorobutadiene
11/16/23 19:261.00< 1.00µg/L2-Hexanone
11/16/23 19:260.500< 0.500µg/LIsopropylbenzene
11/16/23 19:260.500< 0.500µg/L4-Isopropyl toluene
11/16/23 19:265.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
11/16/23 19:261.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
11/16/23 19:261.00< 1.00µg/L4-Methyl-2-Pentanone
11/16/23 19:262.00< 2.00µg/LMethylene Chloride
11/16/23 19:261.00< 1.00µg/LNaphthalene
11/16/23 19:260.500< 0.500µg/Ln-Propylbenzene
11/16/23 19:260.500< 0.500µg/LStyrene
11/16/23 19:260.500< 0.500µg/L1,1,1,2-Tetrachloroethane
11/16/23 19:260.500< 0.500µg/L1,1,2,2-Tetrachloroethane
11/16/23 19:260.500< 0.500µg/LTetrachloroethene
11/16/23 19:260.500< 0.500µg/LToluene
Page 2 of 6Date:11/22/2023 05:28 PM
Page 15 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
Associated Lab Samples: 89370, 89371
LRB-V40340 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/16/23 19:260.500< 0.500µg/L1,2,3-Trichlorobenzene
11/16/23 19:260.500< 0.500µg/L1,2,4-Trichlorobenzene
11/16/23 19:260.500< 0.500µg/L1,1,1-Trichloroethane
11/16/23 19:260.500< 0.500µg/L1,1,2-Trichloroethane
11/16/23 19:260.500< 0.500µg/LTrichloroethene
11/16/23 19:260.500< 0.500µg/LTrichlorofluoromethane
11/16/23 19:260.500< 0.500µg/L1,2,3-Trichloropropane
11/16/23 19:260.500< 0.500µg/L1,2,4-Trimethylbenzene
11/16/23 19:260.500< 0.500µg/L1,3,5-Trimethylbenzene
11/16/23 19:265.00< 5.00µg/LVinyl Acetate
11/16/23 19:260.500< 0.500µg/LVinyl Chloride
11/16/23 19:260.500< 0.500µg/Lo-Xylene
11/16/23 19:261.00< 1.00µg/Lm,p-Xylene
11/16/23 19:264-Bromofluorobenzene (S)98.8 70-130
11/16/23 19:26Dibromofluoromethane (S)96.4 70-130
11/16/23 19:261,2-Dichloroethane - d4 (S)95.0 70-130
11/16/23 19:26Toluene-d8 (S)95.2 70-130
LCS-V40340 LCSD-V40340Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
61.7 15416063.840.0µg/LAcetone 40-160 3.3 20.0
21.9 11011623.120.0µg/LBenzene 70-130 5.3 20.0
19.3 96.510420.720.0µg/LBromobenzene 70-130 7.0 20.0
21.4 10711122.220.0µg/LBromochloromethane 70-130 3.6 20.0
20.7 10411021.920.0µg/LBromodichloromethane 70-130 5.6 20.0
Page 3 of 6Date:11/22/2023 05:28 PM
Page 16 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
LCS-V40340 LCSD-V40340Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.0 95.097.019.420.0µg/LBromoform 70-130 2.0 20.0
21.2 10610320.520.0µg/LBromomethane 60-140 3.3 20.0
19.3 96.510420.720.0µg/Ln-Butylbenzene 70-130 7.0 20.0
19.1 95.510220.320.0µg/Lsec-Butyl benzene 70-130 6.0 20.0
19.1 95.510220.320.0µg/Ltert-Butyl benzene 70-130 6.0 20.0
21.8 10911523.020.0µg/LCarbon Tetrachloride 70-130 5.3 20.0
20.3 10210621.220.0µg/LChlorobenzene 70-130 4.3 20.0
19.5 97.510220.420.0µg/LChlorodibromomethane 70-130 4.5 20.0
20.3 10210320.620.0µg/LChloroethane 60-140 1.4 20.0
21.3 10711021.920.0µg/LChloroform 70-130 2.7 20.0
21.1 10610521.020.0µg/LChloromethane 60-140 0.4 20.0
18.8 94.099.519.920.0µg/L2-Chlorotoluene 70-130 5.6 20.0
19.3 96.510320.520.0µg/L4-Chlorotoluene 70-130 6.0 20.0
22.0 11011723.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 5.7 20.0
18.5 92.510520.920.0µg/L1,2-Dibromo-3-Chloropropane 70-130 12.1 20.0
19.5 97.510020.020.0µg/L1,2-Dibromoethane 70-130 2.5 20.0
21.5 10811422.720.0µg/LDibromomethane 70-130 5.4 20.0
18.9 94.510320.520.0µg/L1,2-Dichlorobenzene 70-130 8.1 20.0
19.2 96.010320.620.0µg/L1,3-Dichlorobenzene 70-130 7.0 20.0
18.9 94.510220.320.0µg/L1,4-Dichlorobenzene 70-130 7.1 20.0
12.0 60.061.012.220.0µg/LDichlorodifluoromethane 60-140 1.6 20.0
22.8 11411823.620.0µg/L1,1-Dichloroethane 70-130 3.4 20.0
20.7 10410821.620.0µg/L1,2-Dichloroethane 70-130 4.2 20.0
22.7 11412124.220.0µg/L1,1-Dichloroethene 70-130 6.3 20.0
21.4 10711322.520.0µg/Lcis-1,2-Dichloroethene 70-130 5.0 20.0
21.8 10911422.820.0µg/Ltrans-1,2-Dichloroethene 70-130 4.4 20.0
Page 4 of 6Date:11/22/2023 05:28 PM
Page 17 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
LCS-V40340 LCSD-V40340Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.4 10711222.420.0µg/L1,2-Dichloropropane 70-130 4.5 20.0
19.5 97.510020.020.0µg/L1,3-Dichloropropane 70-130 2.5 20.0
21.9 11011522.920.0µg/L2,2-Dichloropropane 70-130 4.4 20.0
22.7 11412124.120.0µg/L1,1-Dichloropropene 70-130 5.9 20.0
20.7 10410921.820.0µg/Lcis-1,3-Dichloropropene 70-130 5.1 20.0
20.3 10210721.320.0µg/Ltrans-1,3-Dichloropropene 70-130 4.8 20.0
559 112123617500µg/LEthanol 60-140 9.8 20.0
20.2 10110520.920.0µg/LEthylbenzene 70-130 3.4 20.0
17.1 85.591.018.220.0µg/LHexachlorobutadiene 70-130 6.2 20.0
24.8 12412524.920.0µg/L2-Hexanone 60-140 0.4 20.0
20.2 10110521.020.0µg/LIsopropylbenzene 70-130 3.8 20.0
19.9 99.510521.020.0µg/L4-Isopropyl toluene 70-130 5.3 20.0
25.7 129141*28.220.0µg/LMethyl Ethyl Ketone (MEK)60-140 9.2 20.0
20.6 10311021.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.1 20.0
22.5 11312024.020.0µg/L4-Methyl-2-Pentanone 60-140 6.4 20.0
22.0 11011623.120.0µg/LMethylene Chloride 70-130 4.8 20.0
18.2 91.011122.120.0µg/LNaphthalene 70-130 19.3 20.0
19.7 98.510520.920.0µg/Ln-Propylbenzene 70-130 5.9 20.0
20.8 10410621.120.0µg/LStyrene 70-130 1.4 20.0
20.2 10110320.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.9 20.0
19.5 97.510621.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 7.8 20.0
20.3 10210420.720.0µg/LTetrachloroethene 70-130 1.9 20.0
21.9 11011623.120.0µg/LToluene 70-130 5.3 20.0
19.0 95.012224.420.0µg/L1,2,3-Trichlorobenzene 70-130 24.8*20.0
18.8 94.010520.920.0µg/L1,2,4-Trichlorobenzene 70-130 10.5 20.0
21.7 10911222.420.0µg/L1,1,1-Trichloroethane 70-130 3.1 20.0
Page 5 of 6* QC Fail Date:11/22/2023 05:28 PM
Page 18 of 21
Quality Control Data
23-320-0013Report No:
Project Description:
Client ID:North Carolina Dept of Environmental Quality
6166 Highway 96N
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V40342QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V40340
LCS-V40340 LCSD-V40340Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.8 10911522.920.0µg/L1,1,2-Trichloroethane 70-130 4.9 20.0
21.2 10611122.220.0µg/LTrichloroethene 70-130 4.6 20.0
21.4 10711022.020.0µg/LTrichlorofluoromethane 60-140 2.7 20.0
18.6 93.010420.820.0µg/L1,2,3-Trichloropropane 70-130 11.1 20.0
19.7 98.510621.220.0µg/L1,2,4-Trimethylbenzene 70-130 7.3 20.0
19.7 98.510521.020.0µg/L1,3,5-Trimethylbenzene 70-130 6.3 20.0
22.7 11412124.220.0µg/LVinyl Acetate 60-140 6.3 20.0
21.0 10510821.520.0µg/LVinyl Chloride 60-140 2.3 20.0
20.4 10210420.720.0µg/Lo-Xylene 70-130 1.4 20.0
42.8 10711043.840.0µg/Lm,p-Xylene 70-130 2.3 20.0
97.099.04-Bromofluorobenzene (S)70-130
95.294.4Dibromofluoromethane (S)70-130
93.093.01,2-Dichloroethane - d4 (S)70-130
94.093.0Toluene-d8 (S)70-130
Page 6 of 6Date:11/22/2023 05:28 PM
Page 19 of 21
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-320-0013
North Carolina Dept of Environmental Quality
00439
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.0C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:11/16/2023 11:49:26
Special precautions or instructions included?
Comments:
Page 20 of 21
Page 21 of 21