RA-613_3831_CA_LAB_20220529_Eurofins Lab Report WSW e Christie Williams

ANALYTICAL REPORT
Eurofins Pensacola
3355 McLemore Drive
Pensacola, FL 32514
Tel: [phone]
Laboratory Job ID: 400-220165-1
Laboratory Sample Delivery Group: NC0259 TF#3831
Client Project/Site: Christie Williams
For:
North Carolina Dept of Env Quality
NCDEQ-DWM-UST SECTION
1646 Mail Service Center
Raleigh, North Carolina 27699
Attn: Linda Blalock
Authorized for release by:
5/31/2022 7:57:32 AM
Isabel Enfinger, Project Manager I
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI
requirements for accredited parameters, exceptions are noted in this report. This
report may not be reproduced except in full, and with written approval from the
laboratory. For questions please contact the Project Manager at the e-mail address or
telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic
signature is intended to be the legally binding equivalent of a traditionally handwritten
signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Table of Contents
Client: North Carolina Dept of Env Quality
Project/Site: Christie Williams
Laboratory Job ID: 400-220165-1
SDG: NC0259 TF#3831
Page 2 of 20 Eurofins Pensacola5/31/2022
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Case Narrative
Client: North Carolina Dept of Env Quality Job ID: 400-220165-1
Project/Site: Christie Williams SDG: NC0259 TF#3831
Job ID: 400-220165-1
Laboratory: Eurofins Pensacola
Narrative
Job Narrative
400-220165-1
Comments
No additional comments.
Receipt
The samples were received on 5/19/2022 8:59 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 0.0º C.
GC/MS VOA
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins PensacolaPage 3 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Detection Summary
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Client Sample ID: D1 Lab Sample ID: 400-220165-1
Methyl tert-butyl ether
RL
1.0 ug/L
MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type
Total/NA139SM6200-B
Client Sample ID: D3 Lab Sample ID: 400-220165-2
No Detections.
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
Page 4 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Method Summary
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Method Method Description LaboratoryProtocol
SMSM6200-B Volatile Organic Compounds TAL PEN
SW8465030BPurge and Trap TAL PEN
Protocol References:
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
Page 5 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Sample Summary
Client: North Carolina Dept of Env Quality Job ID: 400-220165-1
SDG: NC0259 TF#3831Project/Site: Christie Williams
Lab Sample ID Client Sample ID Matrix Collected Received
400-220165-1 D1 Water 05/17/22 16:30 05/19/22 08:59
400-220165-2 D3 Water 05/17/22 16:35 05/19/22 08:59
Eurofins PensacolaPage 6 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Client Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Lab Sample ID: 400-220165-1Client Sample ID: D1
Matrix: WaterDate Collected: 05/17/22 16:30
Date Received: 05/19/22 08:59
Method: SM6200-B - Volatile Organic Compounds
RL MDL
1,1,1-Trichloroethane <1.0 1.0 ug/L 05/29/22 16:47 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1.0 ug/L 05/29/22 16:47 11,1,2,2-Tetrachloroethane <1.0
1.0 ug/L 05/29/22 16:47 11,1,2-Trichloro-1,2,2-trifluoroethane <1.0
5.0 ug/L 05/29/22 16:47 11,1,2-Trichloroethane <5.0
1.0 ug/L 05/29/22 16:47 11,1-Dichloroethane <1.0
1.0 ug/L 05/29/22 16:47 11,1-Dichloroethene <1.0
1.0 ug/L 05/29/22 16:47 11,2,3-Trichlorobenzene <1.0
1.0 ug/L 05/29/22 16:47 11,2,4-Trichlorobenzene <1.0
1.0 ug/L 05/29/22 16:47 11,2,4-Trimethylbenzene <1.0
5.0 ug/L 05/29/22 16:47 11,2-Dibromo-3-Chloropropane <5.0
1.0 ug/L 05/29/22 16:47 11,2-Dichlorobenzene <1.0
1.0 ug/L 05/29/22 16:47 11,2-Dichloroethane <1.0
1.0 ug/L 05/29/22 16:47 11,2-Dichloropropane <1.0
1.0 ug/L 05/29/22 16:47 11,3,5-Trimethylbenzene <1.0
1.0 ug/L 05/29/22 16:47 11,3-Dichlorobenzene <1.0
1.0 ug/L 05/29/22 16:47 11,4-Dichlorobenzene <1.0
25 ug/L 05/29/22 16:47 12-Butanone (MEK)<25
25 ug/L 05/29/22 16:47 12-Hexanone <25
25 ug/L 05/29/22 16:47 14-Methyl-2-pentanone (MIBK)<25
25 ug/L 05/29/22 16:47 1Acetone<25
1.0 ug/L 05/29/22 16:47 1Benzene<1.0
5.0 ug/L 05/29/22 16:47 1Bromoform<5.0
1.0 ug/L 05/29/22 16:47 1Bromomethane<1.0
1.0 ug/L 05/29/22 16:47 1Carbon disulfide <1.0
1.0 ug/L 05/29/22 16:47 1Carbon tetrachloride <1.0
1.0 ug/L 05/29/22 16:47 1Chlorobenzene<1.0
1.0 ug/L 05/29/22 16:47 1Chlorobromomethane<1.0
1.0 ug/L 05/29/22 16:47 1Chlorodibromomethane<1.0
1.0 ug/L 05/29/22 16:47 1Chloroethane<1.0
1.0 ug/L 05/29/22 16:47 1Chloroform<1.0
1.0 ug/L 05/29/22 16:47 1Chloromethane<1.0
1.0 ug/L 05/29/22 16:47 1cis-1,2-Dichloroethene <1.0
5.0 ug/L 05/29/22 16:47 1cis-1,3-Dichloropropene <5.0
5.0 ug/L 05/29/22 16:47 1Dibromomethane<5.0
1.0 ug/L 05/29/22 16:47 1Dichlorobromomethane<1.0
1.0 ug/L 05/29/22 16:47 1Dichlorodifluoromethane<1.0
1.0 ug/L 05/29/22 16:47 1Ethylbenzene<1.0
1.0 ug/L 05/29/22 16:47 1Ethylene Dibromide <1.0
1.0 ug/L 05/29/22 16:47 1Methyl tert-butyl ether 39
5.0 ug/L 05/29/22 16:47 1Methylene Chloride <5.0
5.0 ug/L 05/29/22 16:47 1m-Xylene & p-Xylene <5.0
5.0 ug/L 05/29/22 16:47 1Naphthalene<5.0
5.0 ug/L 05/29/22 16:47 1o-Xylene <5.0
1.0 ug/L 05/29/22 16:47 1Styrene<1.0
1.0 ug/L 05/29/22 16:47 1Tetrachloroethene<1.0
1.0 ug/L 05/29/22 16:47 1Toluene<1.0
1.0 ug/L 05/29/22 16:47 1Trichloroethene<1.0
1.0 ug/L 05/29/22 16:47 1Trichlorofluoromethane<1.0
1.0 ug/L 05/29/22 16:47 1Vinyl chloride <1.0
Eurofins Pensacola
Page 7 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Client Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Lab Sample ID: 400-220165-1Client Sample ID: D1
Matrix: WaterDate Collected: 05/17/22 16:30
Date Received: 05/19/22 08:59
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
Xylenes, Total <10 10 ug/L 05/29/22 16:47 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1.0 ug/L 05/29/22 16:47 1Isopropyl ether <1.0
4-Bromofluorobenzene 112 72-119 05/29/22 16:47 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 98 05/29/22 16:47 175-126
Toluene-d8 (Surr)103 05/29/22 16:47 164-132
Eurofins Pensacola
Page 8 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Client Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Lab Sample ID: 400-220165-2Client Sample ID: D3
Matrix: WaterDate Collected: 05/17/22 16:35
Date Received: 05/19/22 08:59
Method: SM6200-B - Volatile Organic Compounds
RL MDL
1,1,1-Trichloroethane <1.0 1.0 ug/L 05/29/22 17:12 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1.0 ug/L 05/29/22 17:12 11,1,2,2-Tetrachloroethane <1.0
1.0 ug/L 05/29/22 17:12 11,1,2-Trichloro-1,2,2-trifluoroethane <1.0
5.0 ug/L 05/29/22 17:12 11,1,2-Trichloroethane <5.0
1.0 ug/L 05/29/22 17:12 11,1-Dichloroethane <1.0
1.0 ug/L 05/29/22 17:12 11,1-Dichloroethene <1.0
1.0 ug/L 05/29/22 17:12 11,2,3-Trichlorobenzene <1.0
1.0 ug/L 05/29/22 17:12 11,2,4-Trichlorobenzene <1.0
1.0 ug/L 05/29/22 17:12 11,2,4-Trimethylbenzene <1.0
5.0 ug/L 05/29/22 17:12 11,2-Dibromo-3-Chloropropane <5.0
1.0 ug/L 05/29/22 17:12 11,2-Dichlorobenzene <1.0
1.0 ug/L 05/29/22 17:12 11,2-Dichloroethane <1.0
1.0 ug/L 05/29/22 17:12 11,2-Dichloropropane <1.0
1.0 ug/L 05/29/22 17:12 11,3,5-Trimethylbenzene <1.0
1.0 ug/L 05/29/22 17:12 11,3-Dichlorobenzene <1.0
1.0 ug/L 05/29/22 17:12 11,4-Dichlorobenzene <1.0
25 ug/L 05/29/22 17:12 12-Butanone (MEK)<25
25 ug/L 05/29/22 17:12 12-Hexanone <25
25 ug/L 05/29/22 17:12 14-Methyl-2-pentanone (MIBK)<25
25 ug/L 05/29/22 17:12 1Acetone<25
1.0 ug/L 05/29/22 17:12 1Benzene<1.0
5.0 ug/L 05/29/22 17:12 1Bromoform<5.0
1.0 ug/L 05/29/22 17:12 1Bromomethane<1.0
1.0 ug/L 05/29/22 17:12 1Carbon disulfide <1.0
1.0 ug/L 05/29/22 17:12 1Carbon tetrachloride <1.0
1.0 ug/L 05/29/22 17:12 1Chlorobenzene<1.0
1.0 ug/L 05/29/22 17:12 1Chlorobromomethane<1.0
1.0 ug/L 05/29/22 17:12 1Chlorodibromomethane<1.0
1.0 ug/L 05/29/22 17:12 1Chloroethane<1.0
1.0 ug/L 05/29/22 17:12 1Chloroform<1.0
1.0 ug/L 05/29/22 17:12 1Chloromethane<1.0
1.0 ug/L 05/29/22 17:12 1cis-1,2-Dichloroethene <1.0
5.0 ug/L 05/29/22 17:12 1cis-1,3-Dichloropropene <5.0
5.0 ug/L 05/29/22 17:12 1Dibromomethane<5.0
1.0 ug/L 05/29/22 17:12 1Dichlorobromomethane<1.0
1.0 ug/L 05/29/22 17:12 1Dichlorodifluoromethane<1.0
1.0 ug/L 05/29/22 17:12 1Ethylbenzene<1.0
1.0 ug/L 05/29/22 17:12 1Ethylene Dibromide <1.0
1.0 ug/L 05/29/22 17:12 1Methyl tert-butyl ether <1.0
5.0 ug/L 05/29/22 17:12 1Methylene Chloride <5.0
5.0 ug/L 05/29/22 17:12 1m-Xylene & p-Xylene <5.0
5.0 ug/L 05/29/22 17:12 1Naphthalene<5.0
5.0 ug/L 05/29/22 17:12 1o-Xylene <5.0
1.0 ug/L 05/29/22 17:12 1Styrene<1.0
1.0 ug/L 05/29/22 17:12 1Tetrachloroethene<1.0
1.0 ug/L 05/29/22 17:12 1Toluene<1.0
1.0 ug/L 05/29/22 17:12 1Trichloroethene<1.0
1.0 ug/L 05/29/22 17:12 1Trichlorofluoromethane<1.0
1.0 ug/L 05/29/22 17:12 1Vinyl chloride <1.0
Eurofins Pensacola
Page 9 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Client Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Lab Sample ID: 400-220165-2Client Sample ID: D3
Matrix: WaterDate Collected: 05/17/22 16:35
Date Received: 05/19/22 08:59
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
Xylenes, Total <10 10 ug/L 05/29/22 17:12 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1.0 ug/L 05/29/22 17:12 1Isopropyl ether <1.0
4-Bromofluorobenzene 111 72-119 05/29/22 17:12 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 102 05/29/22 17:12 175-126
Toluene-d8 (Surr)102 05/29/22 17:12 164-132
Eurofins Pensacola
Page 10 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Surrogate Summary
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (72-119)(75-126)(64-132)
BFB DBFM TOL
112 98 103400-220165-1
Percent Surrogate Recovery (Acceptance Limits)
D1
111 102 102400-220165-2 D3
101 96 100400-220273-A-7 MS Matrix Spike
106 97 101400-220273-A-7 MSD Matrix Spike Duplicate
102 97 101LCS 400-579356/1002 Lab Control Sample
113 101 103MB 400-579356/4 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Eurofins Pensacola
Page 11 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Definitions/Glossary
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Pensacola
Page 12 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
QC Association Summary
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
GC/MS VOA
Analysis Batch: 579356
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-220165-1 D1 Total/NA
Water SM6200-B400-220165-2 D3 Total/NA
Water SM6200-BMB 400-579356/4 Method Blank Total/NA
Water SM6200-BLCS 400-579356/1002 Lab Control Sample Total/NA
Eurofins Pensacola
Page 13 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
QC Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 400-579356/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 579356
RL MDL
1,1,1-Trichloroethane <1.0 1.0 ug/L 05/29/22 13:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<1.0 1.0 ug/L 05/29/22 13:51 11,1,2,2-Tetrachloroethane
<1.0 1.0 ug/L 05/29/22 13:51 11,1,2-Trichloro-1,2,2-trifluoroethane
<5.0 5.0 ug/L 05/29/22 13:51 11,1,2-Trichloroethane
<1.0 1.0 ug/L 05/29/22 13:51 11,1-Dichloroethane
<1.0 1.0 ug/L 05/29/22 13:51 11,1-Dichloroethene
<1.0 1.0 ug/L 05/29/22 13:51 11,2,3-Trichlorobenzene
<1.0 1.0 ug/L 05/29/22 13:51 11,2,4-Trichlorobenzene
<1.0 1.0 ug/L 05/29/22 13:51 11,2,4-Trimethylbenzene
<5.0 5.0 ug/L 05/29/22 13:51 11,2-Dibromo-3-Chloropropane
<1.0 1.0 ug/L 05/29/22 13:51 11,2-Dichlorobenzene
<1.0 1.0 ug/L 05/29/22 13:51 11,2-Dichloroethane
<1.0 1.0 ug/L 05/29/22 13:51 11,2-Dichloropropane
<1.0 1.0 ug/L 05/29/22 13:51 11,3,5-Trimethylbenzene
<1.0 1.0 ug/L 05/29/22 13:51 11,3-Dichlorobenzene
<1.0 1.0 ug/L 05/29/22 13:51 11,4-Dichlorobenzene
<25 25 ug/L 05/29/22 13:51 12-Butanone (MEK)
<25 25 ug/L 05/29/22 13:51 12-Hexanone
<25 25 ug/L 05/29/22 13:51 14-Methyl-2-pentanone (MIBK)
<25 25 ug/L 05/29/22 13:51 1Acetone
<1.0 1.0 ug/L 05/29/22 13:51 1Benzene
<5.0 5.0 ug/L 05/29/22 13:51 1Bromoform
<1.0 1.0 ug/L 05/29/22 13:51 1Bromomethane
<1.0 1.0 ug/L 05/29/22 13:51 1Carbon disulfide
<1.0 1.0 ug/L 05/29/22 13:51 1Carbon tetrachloride
<1.0 1.0 ug/L 05/29/22 13:51 1Chlorobenzene
<1.0 1.0 ug/L 05/29/22 13:51 1Chlorobromomethane
<1.0 1.0 ug/L 05/29/22 13:51 1Chlorodibromomethane
<1.0 1.0 ug/L 05/29/22 13:51 1Chloroethane
<1.0 1.0 ug/L 05/29/22 13:51 1Chloroform
<1.0 1.0 ug/L 05/29/22 13:51 1Chloromethane
<1.0 1.0 ug/L 05/29/22 13:51 1cis-1,2-Dichloroethene
<5.0 5.0 ug/L 05/29/22 13:51 1cis-1,3-Dichloropropene
<5.0 5.0 ug/L 05/29/22 13:51 1Dibromomethane
<1.0 1.0 ug/L 05/29/22 13:51 1Dichlorobromomethane
<1.0 1.0 ug/L 05/29/22 13:51 1Dichlorodifluoromethane
<1.0 1.0 ug/L 05/29/22 13:51 1Ethylbenzene
<1.0 1.0 ug/L 05/29/22 13:51 1Ethylene Dibromide
<1.0 1.0 ug/L 05/29/22 13:51 1Methyl tert-butyl ether
<5.0 5.0 ug/L 05/29/22 13:51 1Methylene Chloride
<5.0 5.0 ug/L 05/29/22 13:51 1m-Xylene & p-Xylene
<5.0 5.0 ug/L 05/29/22 13:51 1Naphthalene
<5.0 5.0 ug/L 05/29/22 13:51 1o-Xylene
<1.0 1.0 ug/L 05/29/22 13:51 1Styrene
<1.0 1.0 ug/L 05/29/22 13:51 1Tetrachloroethene
<1.0 1.0 ug/L 05/29/22 13:51 1Toluene
<1.0 1.0 ug/L 05/29/22 13:51 1Trichloroethene
<1.0 1.0 ug/L 05/29/22 13:51 1Trichlorofluoromethane
Eurofins Pensacola
Page 14 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
QC Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-579356/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 579356
RL MDL
Vinyl chloride <1.0 1.0 ug/L 05/29/22 13:51 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<10 10 ug/L 05/29/22 13:51 1Xylenes, Total
<1.0 1.0 ug/L 05/29/22 13:51 1Isopropyl ether
4-Bromofluorobenzene 113 72-119 05/29/22 13:51 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
101 05/29/22 13:51 1Dibromofluoromethane75-126
103 05/29/22 13:51 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-579356/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 579356
1,1,1-Trichloroethane 50.0 50.0 ug/L 100 68-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 50.0 48.1 ug/L 96 70-131
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 47.6 ug/L 95 60-139
1,1,2-Trichloroethane 50.0 47.7 ug/L 95 70-130
1,1-Dichloroethane 50.0 48.3 ug/L 97 70-130
1,1-Dichloroethene 50.0 49.3 ug/L 99 63-134
1,2,3-Trichlorobenzene 50.0 57.7 ug/L 115 60-138
1,2,4-Trichlorobenzene 50.0 55.6 ug/L 111 60-140
1,2,4-Trimethylbenzene 50.0 62.0 ug/L 124 70-130
1,2-Dibromo-3-Chloropropane 50.0 50.3 ug/L 101 54-135
1,2-Dichlorobenzene 50.0 52.8 ug/L 106 67-130
1,2-Dichloroethane 50.0 46.6 ug/L 93 69-130
1,2-Dichloropropane 50.0 48.7 ug/L 97 70-130
1,3,5-Trimethylbenzene 50.0 61.3 ug/L 123 69-130
1,3-Dichlorobenzene 50.0 53.9 ug/L 108 70-130
1,4-Dichlorobenzene 50.0 53.8 ug/L 108 70-130
2-Butanone (MEK)200 200 ug/L 100 61-145
2-Hexanone 200 206 ug/L 103 65-137
4-Methyl-2-pentanone (MIBK)200 203 ug/L 101 69-138
Acetone 200 204 ug/L 102 43-160
Benzene 50.0 49.5 ug/L 99 70-130
Bromoform 50.0 42.7 ug/L 85 57-140
Bromomethane 50.0 42.9 ug/L 86 10-160
Carbon disulfide 50.0 47.9 ug/L 96 61-137
Carbon tetrachloride 50.0 48.8 ug/L 98 61-137
Chlorobenzene 50.0 51.3 ug/L 103 70-130
Chlorobromomethane 50.0 45.1 ug/L 90 70-130
Chlorodibromomethane 50.0 43.8 ug/L 88 67-135
Chloroethane 50.0 46.1 ug/L 92 55-141
Chloroform 50.0 48.7 ug/L 97 69-130
Chloromethane 50.0 46.2 ug/L 92 58-137
cis-1,2-Dichloroethene 50.0 48.2 ug/L 96 68-130
cis-1,3-Dichloropropene 50.0 47.7 ug/L 95 69-132
Dibromomethane 50.0 46.7 ug/L 93 70-130
Eurofins Pensacola
Page 15 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
QC Sample Results
Job ID: 400-220165-1Client: North Carolina Dept of Env Quality
SDG: NC0259 TF#3831Project/Site: Christie Williams
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-579356/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 579356
Dichlorobromomethane 50.0 45.5 ug/L 91 67-133
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Dichlorodifluoromethane 50.0 45.5 ug/L 91 41-146
Ethylbenzene 50.0 55.9 ug/L 112 70-130
Ethylene Dibromide 50.0 47.4 ug/L 95 70-130
Methyl tert-butyl ether 50.0 46.6 ug/L 93 66-130
Methylene Chloride 50.0 46.3 ug/L 93 66-135
m-Xylene & p-Xylene 50.0 56.8 ug/L 114 70-130
Naphthalene 50.0 54.8 ug/L 110 47-149
o-Xylene 50.0 55.0 ug/L 110 70-130
Styrene 50.0 54.4 ug/L 109 70-130
Tetrachloroethene 50.0 49.5 ug/L 99 65-130
Toluene 50.0 52.3 ug/L 105 70-130
Trichloroethene 50.0 49.0 ug/L 98 70-130
Trichlorofluoromethane 50.0 47.8 ug/L 96 65-138
Vinyl chloride 50.0 47.0 ug/L 94 59-136
Xylenes, Total 100 112 ug/L 112 70-130
Isopropyl ether 50.0 48.0 ug/L 96 64-132
4-Bromofluorobenzene 72 -119
Surrogate
102
LCS LCS
Qualifier Limits%Recovery
97Dibromofluoromethane 75 -126
101Toluene-d8 (Surr)64 -132
Eurofins Pensacola
Page 16 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Lab Chronicle
Client: North Carolina Dept of Env Quality Job ID: 400-220165-1
Project/Site: Christie Williams SDG: NC0259 TF#3831
Client Sample ID: D1 Lab Sample ID: 400-220165-1
Matrix: WaterDate Collected: 05/17/22 16:30
Date Received: 05/19/22 08:59
Analysis SM6200-B BEP05/29/22 16:471 TAL PEN579356
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: D3 Lab Sample ID: 400-220165-2
Matrix: WaterDate Collected: 05/17/22 16:35
Date Received: 05/19/22 08:59
Analysis SM6200-B BEP05/29/22 17:121 TAL PEN579356
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-579356/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B BEP05/29/22 13:511 TAL PEN579356
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-579356/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B BEP05/29/22 12:531 TAL PEN579356
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
TAL PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
Page 17 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Accreditation/Certification Summary
Client: North Carolina Dept of Env Quality Job ID: 400-220165-1
Project/Site: Christie Williams SDG: NC0259 TF#3831
Laboratory: Eurofins Pensacola
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 314 12-31-22
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
SM6200-B Water 1,1,2-Trichloro-1,2,2-trifluoroethane
SM6200-B Water 2-Butanone (MEK)
SM6200-B Water 2-Hexanone
SM6200-B Water 4-Methyl-2-pentanone (MIBK)
SM6200-B Water Acetone
SM6200-B Water Carbon disulfide
Eurofins Pensacola
Page 18 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Page 19 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Login Sample Receipt Checklist
Client: North Carolina Dept of Env Quality Job Number: 400-220165-1
SDG Number: NC0259 TF#3831
Login Number: 220165
Question Answer Comment
Creator: Whitley, Adrian
List Source: Eurofins Pensacola
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
N/AThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.0.0°C IR9
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Pensacola
Page 20 of 20 5/31/2022
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15