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HomeMy WebLinkAboutRA-517_3274_CA_MRP_20191021-compressed October 21, 2019 Mr. Mark Petermann NCDEQ, Division of Waste Management, UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Reference: Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C Dear Mr. Petermann: As authorized by your acceptance of ECS Southeast, LLP (ECS) Task Authorization Request #4 dated June 19, 2019; ECS has completed the Environmental Services Report for the above- referenced site. Included in this report is a description of the field activities, the results obtained, and our conclusions and recommendations. ECS appreciates the opportunity to provide our environmental consulting services to you on this project. If you have any questions concerning this report or this project, please contact us. Sincerely, ECS SOUTHEAST, LLP Samantha M. Szakasits, G.I.T. Matthew Gillis Assistant Staff Project Manager Senior Environmental Project Manager sszakasits@ecslimited.com mgillis@ecslimited.com (919) 861-9832 (919) 861-9845 Roger A. Smith, P.G. Principal Geologist NC License No. 1724 rsmith3@ecslimited.com (704) 525-5152 Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 1 SITE INFORMATION Facility I.D.: #0-224946 UST Incident No.: TF-3274 Site Rank: H210A Land Use Category: Commercial Site Name and Location: Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina Parcel Identification Number: 9776-23-9124 Latitude and Longitude: 35.846815 North, -79.091187 West Contacts Property Owner: Jean Williams PO Box 429 Carrboro, North Carolina 27510 (919) 929-2645 Property Owner Legal Representative: Benjamin D. Overby 522 South Lexington Ave. Burlington, NC 27216-2958 (336) 227-8851 Consultant: ECS Southeast, LLP 9001 Glenwood Avenue Raleigh, North Carolina 27617 (919) 861-9910 Attn: Matthew Gillis Laboratory: Con-Test Analytical Laboratory 39 Spruce Street East Longmeadow, MA 01028 (413) 525-2332 NC Certification No. 652 Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 3 EXECUTIVE SUMMARY The subject site is known as the Petro Mart #4 site and is located at 11455 NC Highway 15/501 North in Chapel Hill, Chatham County, North Carolina (Figure 1 and Figure 2). The subject site is further identified by Chatham County Geographic Information Systems (GIS) Parcel Identification Number (PIN) 9776-23-9124. INCIDENT RISK EVALUATION SUMMARY SOURCE INFORMATION Source, Date, and Nature of Release 1 x 2,000-gallon UST (kerosene), 1 x 3,000-gallon UST (diesel), 1 x 6,000-gallon (gasoline), and 2 x 8,000-gallon USTs (gasoline) – removed March 7, 2001 Each Known Source Removed? Yes – 5 USTs removed in March 7, 2001 Additional Sources Likely Present? Yes – current USTs – 1 x 12,000-gallon UST (gasoline), 1 x 8,000-gallon UST (gasoline), and 1 x 6,000-gallon UST (diesel) Known Sources Assessed (USTs, Piping, Dispensers)? Yes FREE PRODUCT Free Product Present? Currently, no. Historically, yes in MW-3 SITE SOIL CONDITIONS TPH Soil Data Available? Maximum concentration at site Unknown Risk-Based Soil Data Available? Yes Maximum Soil Contaminant Concentrations Aliphatics (C9-C12) at 3,080 mg/kg from SS-5B (2018) Current Extent of Soil Impact Delineated? Yes SITE GROUNDWATER CONDITIONS Average Depth to Groundwater? Approx. 30 feet below top of casing (btoc) Contaminants Present Above NC2L? Yes (Monitoring wells MW-1 through MW-4 and MW-12) Contaminants Present Above GCLs? Yes (Monitoring well MW-3) Groundwater Plume Delineated? Yes Groundwater Plume Migrated Off-Site? No Contaminant Level Trend Stable / Decreasing RECEPTOR INFORMATION Date of Most Current Receptor Survey August 10, 2015 Potable Water-Supply Wells within 1,000’? Yes – see section on water supply well information Water Available to Properties within 1,000’? Yes Non-Potable Wells within 250’? No Site within Wellhead Protection Area? No Surface Water Bodies within 500’? No REMEDIAL ACTIVITIES Remedial activities conducted? O-Sox Remedial Device Deployment and AFVR’s VAPOR INTRUSION Dissolved Contaminants exceeding Groundwater Screening Levels for Vapors present within 5’ of Ground Surface? No Occupied Structures on the Site? Yes, Active Gas Station Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 4 On September 24 and 25, 2019, Quantex, on behalf of ECS, installed four Type II groundwater monitoring wells: MW-9 through MW-12. Monitoring wells MW-9 and MW-10 were installed at 5186 Manns Chapel Road south of the subject site and monitor wells MW-11 and MW-12 were installed as deeper wells that are screened 10 to 15 feet deeper than adjacent wells. On October 1, 2019, ECS collected a field blank and groundwater samples from monitoring wells MW-1 through MW-12. ECS additionally contracted with KCI to professionally survey and tie in the four (4) newly installed monitoring wells to the existing monitoring wells. Laboratory analysis reported benzene at a concentration above its Gross Contamination Level (GCL) in monitoring well MW-3. Laboratory analysis reported several additional targeted analytes at concentrations above their respective North Carolina 2L Groundwater Quality Standard (NC2LGWQS) but below their respective GCL in the groundwater sample collected from monitoring well MW-3. Laboratory analysis reported several targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCL in the groundwater samples collected from monitoring wells MW-1, MW-2, MW-4, and MW-12. Laboratory analysis reported several targeted analytes at concentrations above the laboratory reporting limits but below their respective NC2LGWQS in the groundwater samples collected from monitoring wells MW-1, MW- 2, MW-3, MW-4, MW-7, MW-8, MW-9, MW-10, MW-11, and MW-12. Based on the results of this Environmental Services Report, ECS concludes the following:  Based on the survey data, the groundwater flow direction is generally to the east below the site.  Laboratory analysis detected benzene at a concentration above its GCL in the groundwater sample collected from monitoring well MW-3. Since conducting the February 2019 AFVR event, free product has not been observed in the monitoring well since the past three sampling events and the concentration of benzene has decreased significantly.  Laboratory analysis detected several targeted analytes above their respective NC2LGWQS, but did not exceed their respective GCL in monitoring wells MW-1, MW-2, MW-3, MW-4, and MW-12.  Groundwater flow direction is generally to the east and water supply well WSW-1 is located approximately 380 feet west of the site; therefore, ECS considers WSW-1 unlikely to be impacted by the onsite petroleum-related contamination. Based on the conclusions of this Environmental Services Report, ECS recommends the following:  Conducting an AFVR event on monitoring well MW-3 and MW-12 in an effort to reduce petroleum-related compounds detected above their respective GCLs and conduct a groundwater sampling event approximately three to five weeks after the AFVR event to assess its efficiency.  Contacting AQUA and inform them, ECS is contracted by the NCDEQ to perform Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 5 environmental site assessments at the Petro Mart site and would like to request laboratory analytical data for water supply well WSW-1 as well as any additional information regarding the well such as the total well depth, screen interval, gallons per minute output, and usage.  Conduct a Fate and Transport Modeling event to determine if the dissolved contaminant plume could impact the nearest water supply well (WSW-1). Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 6 TABLE OF CONTENTS 1.0 SITE HISTORY ......................................................................................................... 7 2.0 SITE GEOLOGY AND HYDROGEOLOGY............................................................. 10 3.0 RECEPTOR INFORMATION .................................................................................. 10 4.0 FILE REVIEW .......................................................................................................... 11 5.0 FIELD ACTIVITIES ................................................................................................. 11 6.0 RESULTS ............................................................................................................... 13 7.0 CONCLUSIONS ...................................................................................................... 14 8.0 RECOMMENDATIONS ........................................................................................... 15 FIGURES Figure 1 Site Location Map Figure 2 Aerial Site Map Figure 3 2018 Soil Sample Location Map Figure 4 Water Supply Well Location Map Figure 5 Monitoring Well Location Map Figure 6 Groundwater Elevation Map Figure 7 Pantry #294 Site Map Figure 8 Groundwater Concentration Map Figure 9 MTBE Isoconcentration Map TABLES Table 1 UST Information Table 2 Summary of Historical Soil Sample Analytical Results Table 3 Water Supply Well Survey Table 4 Geochemical Measurements Table 5 Monitoring Well Construction and Groundwater Elevation Details Table 6 Summary of Current Groundwater Analytical Results Table 7 Summary of Historical Groundwater Analytical Results APPENDICIES Appendix A Access Agreement Appendix B ECS Personnel Field Notes and Sampling Data Sheets Appendix C Monitoring Well Construction Records Appendix D Site Photographs Appendix E Laboratory Analytical Data Sheets and Chain of Custody (COC) Record Appendix F Surveying Data Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 7 1.0 SITE HISTORY The Petro Mart #4 site is located at 11455 NC Highway 15/501 North in Chapel Hill, Chatham County, North Carolina (Figures 1 and 2). According to information provided to ECS by the North Carolina Department of Environmental Quality (NCDEQ), the site is an active gasoline station that formerly contained one 2,000-gallon kerosene UST, one 2,000-gallon diesel UST, one 6,000- gallon gasoline UST, and two 8,000-gallon gasoline USTs. The site currently contains one 12,000- gallon gasoline UST, one 8,000-gallon gasoline UST, and one 6,000-gallon diesel UST (Table 1). In August 1986, a release of approximately 25-gallons of gasoline was reported on the site. In October 1986, two monitoring wells (MW-1 and MW-2) were installed at the site to depths of 20 and 30 feet below ground surface (ft. bgs.). Laboratory analysis of soil samples collected from the monitoring well borings did not report petroleum-related contamination. The monitoring wells were determined to be dry and were not sampled. In 1987, laboratory analysis of soil samples collected by the NCDEQ reported benzene at 8.6 milligrams per kilogram (mg/kg) and methyl-ethyl ketone (MEK) at 120 mg/kg; however, the location of these soil borings is not known. In September 1994, groundwater samples were collected from five off-site water supply wells. Laboratory analysis of the groundwater samples reported methyl tert-butyl ether (MTBE) at 72 parts per billion (ppb) in the water supply well at the Park & Stay mobile home park (WSW-2) located approximately 800 feet south of the subject site. Water-supply well WSW-2 has subsequently been abandoned and the Cole Park Plaza Shopping Center has been constructed at that location. In February 1995, two monitoring wells were installed at the site. Monitoring well MW-1 was installed adjacent to the current tank basin and monitoring well MW-2 was installed on the southeast corner of the subject site. Laboratory analysis reported several targeted analytes at concentrations above their respective North Carolina 2L Groundwater Quality Standards (NC2LGWQS) in the groundwater samples collected from monitoring wells MW-1 and MW-2. In March 2001, five USTs were removed from the site. A total of eight soil samples were collected during closure activities. Laboratory analysis of seven of the eight soil samples reported total petroleum hydrocarbons (TPH) above the NCDEQ UST Sections Action Levels of 10 milligrams per kilogram (mg/kg). Monitoring wells MW-1 and MW-2 were abandoned. In December 2008, a receptor survey was conducted for the site. At that time, the site consisted of an active gasoline station (Petro Mart) and one 20,000-gallon compartmentalized UST containing regular and premium gasoline and diesel. ECS could not determine the current status of this UST. The receptor survey did not identify monitoring wells or water supply wells on the subject site. The site was determined to utilize water obtained from water supply well WSW-1 located on an off-site property approximately 350 feet west and upgradient of the site. Water supply well WSW-1 is owned by Aqua who indicated that water supply well WSW-1 is sampled regularly for VOCs. Water supply well WSW-1 is approximately 410 feet deep, has a capacity of 60 gallons per minute (gpm), and has been in service since the late 1970s. Five additional water supply wells (WSW-2, WSW-3, and WSW-5 through WSW-7) were identified within 1,000 feet of the site. It was reported that these wells are inactive or have been abandoned. Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 8 In April 2010, a review of the active UST system compliance records for the site was conducted. According to a February 2009 compliance inspection, three new USTs were installed on the site in May 2001 consisting of one 12,000-gallon gasoline, one 8,000-gallon gasoline, and one 6,000- gallon diesel UST. The inspection identified five violations consisting of the following: 1) Failure to provide secondary containment on UST systems installed or replaced after May 1, 2000 near wells and surface waters (the UST system is located within 500 feet of a public water supply well); 2) No leak detection for tanks; 3) Failure to conduct leak detection properly; 4) Failure to report a suspected release (weeps were reportedly observed beneath three of the four dispensing pumps); and, 5) Failure to investigate a suspected release. In the compliance record file, there was a response letter from the property owner (K&M Services, Inc.) regarding to the compliance report. Included in the letter were line and ELD test results, tank tightness testing results, copies of invoices for a continuous statistical leak detection system installed in the existing tank monitoring device, an invoice for seven sensors installed in sump pumps, and dispenser pans, and tank monitoring tapes. In addition, the letter indicates that all weeps beneath the dispensers had been repaired and that old filters had been removed from the containment sump. The 2010 compliance review report concluded that the UST system is in compliance and that residual soil and groundwater contamination may be present in the areas of the former UST pit and dispensing pumps. The report indicates that groundwater contamination beneath the site may be originating from an adjoining leaking UST site (Pantry #294). On April 15 and 16, 2015, ECS installed monitoring wells (MW-1 and MW-2) to depths of 55 and 54 ft. bgs, respectively. Monitoring wells MW-1 and MW-2 are located near the current UST basin. ECS collected two soil samples from each monitoring well boring at depths of 3 to 5 ft bgs (SS-1A and SS-2A) and 8 to 10 ft bgs (SS-1B and SS-2B). Soil samples SS-1A and SS-1B were collected from the boring for monitoring well MW-1 and soil samples SS-2A and SS-2B were collected from the boring for monitoring well MW-2. ECS also collected groundwater samples from monitoring wells MW-1 and MW-2. Laboratory analysis reported methylene chloride at a concentration above its Soil-to-Groundwater Maximum Soil Contamination Concentration (MSCC) in the soil sample collected from SS-2A, as shown on Table 2. Laboratory analysis reported MTBE and lead at concentrations above their respective NC2LGWQS but below their respective Gross Contamination Levels (GCLs) in the groundwater sample collected from monitoring well MW-1. Laboratory analysis reported benzene and MTBE at concentrations above their respective NC2LGWQS but below their respective GCLs in the groundwater sample collected from monitoring well MW-2. On August 10-12, 2015, ECS installed four monitoring wells (MW-3 through MW-6) to depths ranging from 46 to 52 ft. bgs. ECS collected groundwater samples from monitoring wells MW-1 and MW-2 and the four newly installed monitoring wells. On August 24, 2015, Bateman Civil Survey surveyed the site monitoring wells. Laboratory analysis reported benzene and MTBE at concentrations above their respective GCLs in the groundwater sample collected from monitoring well MW-3, which is located adjacent to the former UST basin. Laboratory analysis reported Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 9 several additional targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCLs in the groundwater samples collected from monitoring wells MW-1 through MW-6. ECS conducted a receptor survey update for the subject site. ECS observed two water supply well houses (WSW-1 and WSW-6) within 500 feet of the subject site and two water supply wells (WSW-5 and WSW-7) within 1,000 feet of the subject site. ECS spoke with Ms. Shonda, a representative of Aqua who confirmed that the subject site utilizes municipal water obtained from the community water supply well (WSW-1) located approximately 350 feet west and topographically upgradient of the site. Aqua also confirmed that the community water supply well WSW-1 supplies water to the residences within Cedar Terrace. Water supply well WSW-1 is maintained by Aqua who indicated that WSW-1 is sampled regularly for VOCs. ECS spoke with Ms. Jean Williams, the owner of the properties associated with water supply wells WSW-5 through WSW-7, who confirmed that the water supply wells are active and are sampled regularly by an unknown agent. ECS was not provided with laboratory reports from this testing. On March 7, 2018, ECS collected groundwater samples from monitoring wells MW-1, MW-2, MW-4, MW-5, and MW-6. Prior to sampling, ECS gauged each monitoring well for the presence of free product. Free product was detected in monitoring well MW-3, and was therefore not sampled. The samples collected were shipped to Con-Test Analytical Laboratory for analyses for volatile organic compounds (VOCs) by SM 6200B. ECS subsequently deployed an O-Sox remedial device in monitoring well MW-4. Laboratory analysis of the groundwater samples collected from monitoring wells MW-1, MW-2, and MW-4 detected petroleum-related hydrocarbons at concentrations that exceeded their respective NC2LGWQS, but did not exceed their respective GCLs. The groundwater results show similar concentrations as previous samplings events. In November 2018, ECS contracted with Quantex to advance eight soil borings to collect 24 total soil samples at depths ranging from 12 to 20 ft. bgs for risk-based analysis along the sidewalls of the investigate soil quality in the vicinity of the former UST basin (Table 2 and Figure 3). ECS also installed two Type II groundwater monitoring wells: MW-7 and MW-8, conducted a groundwater monitoring event, and deployed O-Sox remedial device in monitoring well MW-4. Laboratory analysis detected benzene in monitoring well MW-3 at a concentration above its respective GCL and other petroleum-related compounds were detected in monitoring wells MW-1, MW-2, and MW-4, at concentrations exceeding their respective NC2LGWQS. Laboratory analysis reported several targeted analytes at concentrations above their respective Soil-to-Water MSCCs in several soil samples collected at the site. On February 20, 2019, ECS contracted with Zebra Environmental & Industrial Services (Zebra) to conduct an Aggressive Fluid and Vapor Recovery (AFVR) event at the site using monitoring well MW-3 as an extraction point. On March 6, 2019, ECS collected a field blank and groundwater samples from monitoring wells MW-1 through MW-8. ECS deployed an O-Sox remedial device in monitoring well MW-3. Laboratory analysis reported benzene at a concentration above its GCL in monitoring well MW-3. Laboratory analysis reported several additional targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCL in the groundwater sample collected from monitoring well MW-3. Laboratory analysis reported several targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCL in the groundwater sample collected from monitoring well MW-4. Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 10 2.0 SITE GEOLOGY AND HYDROGEOLOGY As determined from the USGS Topographic Map, Farrington, North Carolina Quadrangle dated 1993 (Figure 1), the site is at an approximate elevation of 550 feet above mean sea level. The subject site is situated in the Piedmont Physiographic Province. The soils encountered in this area are the residual product of in-place chemical weathering of rock presently underlying the site and/or historic depositional events. In general, shallow unconfined groundwater movement within the overlying soils is controlled largely by topographic gradients. However, as the groundwater percolates downward, it becomes controlled by the subsurface geologic conditions. Thus, the direction of groundwater movement in the deeper aquifers may not be consistent with the reflecting topography. In general, shallow unconfined groundwater movement within the overlying soils is controlled largely by topographic gradients. Recharge occurs primarily by infiltration along higher elevations and typically discharges into streams or other surface water bodies. The elevation of the shallow water table is transient and can vary with seasonal fluctuations in precipitation. Movement of shallow groundwater is generally from higher to lower elevations. 3.0 RECEPTOR INFORMATION 3.1 Water Supply Wells On August 10, 2015, ECS conducted a receptor survey update for the subject site. ECS observed two water supply well houses (WSW-1 and WSW-6) within 500 feet of the subject site and two water supply wells (WSW-5 and WSW-7) within 1,000 feet of the subject site (Figure 4). ECS spoke with Ms. Shonda, a representative of Aqua who confirmed that the subject site utilizes municipal water obtained from the community water supply well (WSW-1) located approximately 350 feet west and topographically upgradient of the site. Aqua also confirmed that the community water supply well WSW-1 supplies water to the residences within Cedar Terrace. Water supply well WSW-1 is maintained by Aqua who indicated that WSW-1 is sampled regularly for VOCs. ECS spoke with Ms. Jean Williams, the owner of the properties associated with water supply wells WSW-5 through WSW-7, who confirmed that the water supply wells are active and are sampled regularly by an unknown company. ECS was not provided with laboratory reports from this testing. During the March 2019 and October 2019 sampling event, it appeared several residences west of the subject site appeared to be vacant and/or abandoned. These vacant and/or abandoned residences were associated with water supply wells WSW-5, WSW-6, and WSW-7; therefore, ECS assumes these water supply wells are inactive. 3.2 Public Water Supplies ECS contacted Chatham County Public Works Utilities and Water Division to inquire if municipal water is available for the subject site and surrounding area. According to Chatham County personnel and the Chatham County GIS website, municipal water supply lines are located on Manns Chapel Road and NC Highway 15/501 which can supply municipal water to the subject site and surrounding area. The commercial properties located east of the subject Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 11 site and some residences south and west of the subject site are currently connected to the municipal water supply. 3.3 Surface Water As determined from the USGS Topographic Map, Farrington, North Carolina Quadrangle dated 1993 (Figure 1), the site is at an approximate elevation of 550 feet above mean sea level. Surface runoff on the site is generally to the southeast. 3.4 Subsurface Structures ECS did not identify subsurface structures associated with the subject site other than underground utilities such as municipal water/sewer and fiber optic lines. 3.5 Land Use The subject site is developed with a commercial property and currently operates as a convenience store and gasoline station. The surrounding area is a mixture of residential and commercial properties. 3.6 Property Owners and Occupants The Chatham County GIS website was utilized to identify the adjacent property owners. The names and addresses of the owners of adjacent properties and properties located within 500 feet of the site are shown on Table 3. 4.0 FILE REVIEW A separate leaking gasoline UST site, identified as “the Pantry #294” (Incident #22718) (Facility ID #0-021416) is located across Manns Chapel Road, approximately 270 feet south from the subject site. ECS obtained and reviewed the Withers and Ravenel (WR) May 2013 Groundwater Monitoring Report and found that WR concluded that several VOCs were identified above their respective NC2LGWQS. WR reported, “The most concentrated contaminant area appears to be around MW-3. MW-3 and deep well MW-4 were the only wells with contaminants exceeding 15A NCAC 2L groundwater standards.” Additionally, no analyzed VOCs were detected above their respective GCL. As shown in Figure 7, off-site monitoring wells MW-3 and deep well MW-4 associated with the Pantry #294 site are located near the eastern portion of the adjacent site. ECS determined that it is unlikely that the current and former USTs located at the Pantry #294 have impacted the subject site based on the eastern plume delineation. 5.0 FIELD ACTIVITIES 5.1 Pre-assessment Activities Prior to the drilling activities, ECS mailed an access agreement to Mr. Leon Chaplin Jr.’s requesting permission to installed two monitoring wells on his property south of the subject site Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 12 at 5186 Manns Chapel Road. ECS additionally made several attempts to contact Mr. Chaplin. ECS obtained an access agreement to install two monitoring wells on Mr. Chaplin’s property after speaking with him on the phone and explaining our proposed scope of work. The signed access agreement in included in Appendix A. ECS also attempted to call Mr. Benjamin Overby, the property owner’s legal representative of the subject site, three times and left a message informing him of our scope of work and schedule; however, ECS did not receive a return phone call. 5.2 Public and Private Utility Clearance Prior to commencing with field activities, ECS contacted 811 to locate/mark public utilities at the site. ECS additionally contracted with KCI to locate/mark private underground utilities at the site. Required separation distances between subsurface activities and marked utilities (typically 30-inches) were maintained during the field activities. Required separation distances between subsurface activities and marked utilities (typically 30-inches) were maintained during the field activities. 5.3 Monitoring Well Installation On September 24 and 25, 2019, Quantex, on behalf of ECS, installed four Type II groundwater monitoring wells: MW-9 through MW-12. Monitoring wells MW-9 and MW-10 were installed at 5186 Manns Chapel Road south of the subject site. Monitoring wells MW-11 and MW-12 were installed near of monitoring wells MW-4 and MW-7, respectively and were installed and screened deeper. Monitoring well construction details and groundwater level data is summarized in Table 5 and the locations of site monitoring wells are shown on Figure 5. The four monitoring wells were installed using solid stem augers. Drilling with solid stem augers involves rotating a continuous stem of augers into the ground to a depth of 50 and 70 feet, respectively. As drilling advances, the soil cuttings are removed by the rotating auger. Prior to advancing the boring, the down hole equipment and drill rig were decontaminated using high pressure steam cleaner and municipal water. The four Type II monitoring wells were constructed with 2-inch schedule 40 PVC flush threaded screen and casing. The PVC screen and casing was lowered into the open borehole of monitoring wells MW-9 and MW-10 to a depth of 50 ft. bgs. A 20-foot length of 0.01-inch slotted well screen with a threaded bottom plug was installed to a depth such that the screened interval intersected the estimated groundwater surface, as encountered during drilling activities for monitoring wells MW-9 and MW-10. Whereas for monitoring wells MW-11 and MW-12, the PVC screen and casing was lowered into the open boreholes to a depth of 69 and 66 ft. bgs., respectively, instead of the drilled depth of 70 ft. bgs due to the borehole sidewalls collapsing. A 10-foot length of 0.01-inch slotted well screen with a threaded bottom plug was installed to a depth such that the screened interval was submerged to an intermediate depth as previously discussed and instructed by NCDEQ. The solid section of PVC casing was placed above the screened interval and extended to a point just below the ground surface. The annular space around the well screens was filled with washed and graded medium sand to approximately 2- feet above the top of the well screen. A minimum two-foot thick seal of bentonite pellets was paced above the sand pack and allowed to hydrate before backfilling the remaining borehole Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 13 annulus with a bentonite/neat cement mixture. The top of the well casings were equipped with a lockable, water tight well plug and a flush mounted protective steel cover. ECS personnel field notes and boring logs are included in Appendix B. Monitoring well construction diagram and NCDEQ Well Construction Records are included in Appendix C. Following installation completion, monitoring wells MW-9 through MW-12 were developed on September 25, 2019. The wells were developed to remove the sand, silt, and other fine sediments that may have entered the wells during construction. 5.4 Groundwater Sampling On October 1, 2019, ECS collected a field blank and groundwater samples from monitoring wells MW-1 through MW-12 (Figure 5). Purging and sampling of monitoring wells were accomplished using a disposable bailer. ECS collected geochemical measurements at each well for each well volume purged using a YSI-556 multi-parameter meter. Geochemical measurements are shown in Table 4. Groundwater Monitoring Well Sampling Data sheets and personnel field notes are provided in Appendix B. Site Photographs are included in Appendix D. After purging the well, the groundwater samples were transferred into sample containers provided by the laboratory. The sample containers were labeled with ECS project number, sample identification, sample date and time, and requested analytical analysis. The containers were placed into protective packaging material and placed into a cooler with ice to maintain the samples at approximately 4 Celsius (C). The samples were submitted to Con-test Analytical Laboratory located in East Longmeadow, MA for chemical analysis for VOCs using Standard Method 6200B. ECS maintained proper COC procedures throughout the sample collection and transportation process. Copies of the COC are included in Appendix E. 6.0 RESULTS 6.1 Groundwater Flow Direction On October 1, 2019, ECS contracted with KCI to conduct a professional survey of the top of casing measurements for the four (4) newly installed monitoring wells (MW-9 through MW-12) and tie in with the top of casing elevation data for the eight (8) previously existing monitoring wells (MW-1 through MW-8). The surveying data collected provided by KCI is included in Appendix F. ECS measured the depth to groundwater in each of the wells (Table 5) and used this data to calculate groundwater flow direction. The calculated groundwater flow direction is generally to the east below the site as determined by the site monitoring wells. A potentiometric flow map for the subject site is depicted as Figure 6. A 2013 potentiometric flow map for the adjacent Pantry #294 site (Figure 7) depicts groundwater flow northeast. 6.2 Groundwater Sampling Results Laboratory analysis reported benzene at a concentration above its GCL in monitoring well MW-3. Laboratory analysis reported several additional targeted analytes at concentrations above their Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 14 respective NC2LGWQS but below their respective GCL in the groundwater sample collected from monitoring well MW-3. Laboratory analysis reported several targeted analytes at concentrations above their respective NC2LGWQS but below their respective GCL in the groundwater samples collected from monitoring wells MW-1, MW-2, MW-4, and MW-12. Laboratory analysis reported several targeted analytes at concentrations above the laboratory reporting limits but below their respective NC2LGWQS in the groundwater samples collected from monitoring wells MW-1, MW-2, MW-3, MW-4, MW-7, MW-8, MW-9, MW-10, MW-11, and MW- 12. Laboratory analysis reported acetone and ethanol at a concentrations above the laboratory reporting limits but below their respective NC2LGWQS in the field blank. The concentrations were denoted with a J-Flag, which is an estimated concentration; therefore, ECS considers these detections to be laboratory contaminants and not representative of the current site groundwater conditions. Laboratory analysis did not report targeted analytes above the laboratory reporting limits in the groundwater samples collected from monitoring wells MW-5 and MW-6. A summary of the current groundwater laboratory analytical results is included in Table 6 and depicted on Figure 8. Historical analytical data from groundwater assessment is included in Table 7. The laboratory data sheets and COC are included in Appendix E. Using the laboratory analytical results of the groundwater samples collected from the monitoring wells, an isoconcentration map showing the horizontal extent for MTBE is included as Figure 9. 7.0 CONCLUSIONS Based on the results of this Environmental Services Report, ECS concludes the following:  Based on the survey data, the groundwater flow direction is generally to the east below the site.  Laboratory analysis detected benzene at a concentration above its GCL in the groundwater sample collected from monitoring well MW-3. Since conducting the previous AFVR event, free product has been has not been observed in the monitoring well since the past three sampling events and the concentration of benzene has decreased significantly.  Laboratory analysis detected several targeted analytes above their respective NC2LGWQS, but did not exceed their respective GCL in monitoring wells MW-1, MW-2, MW-3, MW-4, and MW-12.  Groundwater flow direction is generally to the east and water supply well WSW-1 is located approximately 380 feet west of the site; therefore, ECS considers WSW-1 unlikely to be impacted by the onsite petroleum-related contamination. Environmental Services Report – Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 NCDEQ Contract: N17006 ECS Project: 49:6230-C 15 8.0 RECOMMENDATIONS Based on the findings of this Environmental Services Report, ECS recommends the following:  Conducting an AFVR event on monitoring well MW-3 and MW-12 in an effort to reduce petroleum-related compounds detected above their respective GCLs and conduct a groundwater sampling event approximately three weeks after the AFVR event to assess its efficiency.  Contacting AQUA and inform them, ECS is contracted by the NCDEQ to perform environmental site assessments at the Petro Mart site and would like to request laboratory analytical data for water supply well WSW-1 as well as any additional information regarding the well such as the total well depth, screen interval, gallons per minute output, and usage.  Conduct a Fate and Transport Modeling event to determine if the dissolved contaminant plume could impact the nearest water supply well (WSW-1). FIGURES SOURCE: USGS TOPOGRAPHIC MAP FARRINGTON NC QUADRANGLE DATED 1993 SCALE: 1 : 24,000 FIGURE 1 SITE LOCATION MAP PETRO MART #4 11455 NC HWY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C SITE FIGURE 2 AERIAL SITE MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C SOURCE: CHATHAM COUNTY GIS DATED 2013 SCALE AS SHOWN Scale: 1 inch = 170 feet SITE COMMERCIAL SINGLE-FAMILY RESIDENCES SINGLE-FAMILY RESIDENCES THE PANTRY #294 LEGEND Approximate Location of Monitoring Well Approximate Location of Soil Sample Boring Approximate Location of Former USTs Approximate Location of Current USTs SOURCE: CHATHAM COUNTY GIS DATED 2017 SCALE AS SHOWN FIGURE 3 2018 SOIL SAMPLE LOCATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C Scale: 1 inch = 60 feet MW-1 MW-2 MW-5MW-6 MW-3 MW-4 MW-7 MW-8 MW-1 SS-1 MW-6 MW-5 MW-8 MW-7 MW-4 MW-1 MW-2 MW-3 SS-1SS-2 SS-11SS-10 SS-8SS-9 SS-3SS-4SS-5 SS-7 SS-6 SS-12 SOURCE: CHATHAM COUNTY GIS DATED 2017 SCALE AS SHOWN FIGURE 4 WATER SUPPLY WELL LOCATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C Scale: 1 inch = 400 feet LEGEND Approximate Location of Active Water Supply Well Approximate Location of Inactive Water Supply Well Approximate Location of Fire Hydrant WSW-1 500 ft. Radius 1,000 ft. Radius SITE WSW-1 WSW-6 WSW-7 WSW-5 WSW-5 SOURCE: CHATHAM COUNTY GIS DATED 2013 SCALE AS SHOWN FIGURE 5 MONITORING WELL LOCATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C Scale: 1 inch = 80 feet MW-1 MW-2 LEGEND Approximate Location of Monitoring Well Approximate Location of Former USTs Approximate Location of Current USTs MW-1 MW-5MW-6 MW-3 MW-4 MW-7 MW-8 MW-11 MW-12 MW-9 MW-10 SOURCE: CHATHAM COUNTY GIS DATED 2013 SCALE AS SHOWN FIGURE 6 GROUNDWATER ELEVATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C Scale: 1 inch = 80 feet LEGEND Approximate Location of Monitoring Well Groundwater Elevation Groundwater Contour Line Estimated Direction of Groundwater Flow MW-1 521.99 MW-4 522.86 Approximate Location of Current USTs MW-6 522.31 MW-1 521.99 Approximate Location of Former USTs MW-11 522.61 MW-12 522.79 MW-10 524.54 MW-7 522.96 MW-8 523.17 MW-5 521.97 MW-9 522.61 MW-3 523.08 523 522524 MW-2 522.54 FIGURE 7 PANTRY #294 SITE MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C SOURCE: Withers and Ravenel (WR) May 2013 Groundwater Monitoring Report SCALE AS SHOWN SITE COMMERCIAL SINGLE-FAMILY RESIDENCES THE PANTRY 294 MW-3 MW-4 SOURCE: CHATHAM COUNTY GIS DATED 2013 SCALE AS SHOWN FIGURE 8 GROUNDWATER CONCENTRATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C Scale: 1 inch = 80 feet MW-5 BRL MW-6 BRL MW-1 Diisopropyl Ether 0.45 J Methyl tert-Butyl Ether 28 LEGEND Approximate Location of Monitoring Well 6.7 Concentrations Above Laboratory Reporting Limits (µg/L) 400 Bold Concentrations Above NC2LGWQS (µg/L) 24,000 Bold Underlined Concentrations Above GCL (µg/L) BRL Below Reporting Limit J Estimated Concentration MW-1 MW-2 Diisopropyl Ether 7.0 Methyl tert-Butyl Ether 68 MW-10 Chloroform 11 MW-9 Diisopropyl Ether 0.21 J Methyl tert-Butyl Ether 11 MW-11 Toluene 0.18 J Methyl tert-Butyl Ether 2.2 MW-7 Methyl tert-Butyl Ether 2.8 MW-8 Methyl tert-Butyl Ether 2.7 MW-3 Benzene 24,000 Toluene 48,000 Ethylbenzene 4,200 Total Xylenes 20,600 2-Butanone 2,400 J Diisopropyl Ether 280 2-Hexanone 810 J Isopropylbenzene 140 J Methyl tert-Butyl Ether 3,600 Naphthalene 2,300 J n-Propylbenzene 440 1,2,4-Trimethylbenzene 2,400 1,3,5-Trimethylbenzene 780 MW-4 Benzene 410 Toluene 6.7 Ethylbenzene 81 Total Xylenes 206 Diisopropyl Ether 68 Isopropylbenzene 3.8 J Methyl tert-Butyl Ether 400 n-Propylbenzene 6.8 1,2,4-Trimethylbenzene 27 1,3,5-Trimethylbenzene 26 MW-12 Benzene 2,300 Toluene 4,600 Ethylbenzene 540 Total Xylenes 1,119 Diisopropyl Ether 180 2-Hexanone 460 J Isopropylbenzene 19 J Methyl tert-Butyl Ether 1,300 4-Methyl-2-pentanone 190 J Naphthalene 450 J n-Propylbenzene 39 J 1,2,4-Trimethylbenzene 520 1,3,5-Trimethylbenzene 190 SOURCE: CHATHAM COUNTY GIS DATED 2013 SCALE AS SHOWN FIGURE 9 MTBE ISOCONCENTRATION MAP PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY, NORTH CAROLINA NCDEQ INCIDENT: TF-3274 ECS PROJECT: 49:6230-C MW-3 Scale: 1 inch = 80 feet LEGEND Approximate Location of Monitoring Well MTBE Isoconcentration Contour (µg/L) 400 Bold Concentration Above NC2LGWQS BRL Below Reporting Limit MW-1 MW-5 BRL MW-6 BRL Approximate Location of Former USTs Approximate Location of Current USTs MW-2 68 20MW-1 28 MW-8 2.7 MW-7 2.8 MW-3 3,600 MW-4 400 200 2,000 MW-11* 2.2 MW-12* 1,300 MW-9 11 MW-10 BRL TABLES UST ID Number Last Contents Previous Contents Capacity (in Gallons) Construction Details Tank Dimensions Installation Date Removal Date Status 1 Kerosene Kerosene 2,000 Unknown 12.0' x 5.33'11/10/1986 3/7/2001 Removed 2 Diesel Diesel 3,000 Unknown 12.0' x 5.33'11/10/1986 3/7/2001 Removed 3 Gasoline Gasoline 6,000 Unknown 16.16' x 8.0'11/10/1986 3/7/2001 Removed 4 Gasoline Gasoline 8,000 Unknown 20.66' x 8'11/10/1986 3/7/2001 Removed 5 Gasoline Gasoline 8,000 Unknown 20.66' x 8'11/10/1986 3/7/2001 Removed 6 Gasoline Gasoline 12,000 Unknown Unknown May 2001 Current Current 7 Gasoline Gasoline 8,000 Unknown Unknown May 2001 Current Current 8 Diesel Diesel 6,000 Unknown Unknown May 2001 Current Current Chapel Hill, Chatham County, North Carolina ECS Project: 49:6230-C Table 1 UST Information Petro Mart #4 11455 NC Highway 15/501 North NCDEQ Incident: 3274 PARAMETER Sample ID SS-1A SS-1B SS-2A SS-2B SS-1A SS-1B SS-2A SS-2B SS-3A SS-3B SS-4A SS-4B SS-5A SS-5B SS-6A SS-6B SS-7A SS-7B SS-8A SS-8B SS-9A SS-9B SS-10A SS-10B SS-11A SS-11B SS-12A SS-12B Collection Date Sample Depth (ft bgs)3-5 8-10 3-5 8-10 11.5-13.5 18.5-19.5 14.0-15.0 18.5-19.5 14.0-15.0 18.5-19.5 14.0-15.0 18.5-19.5 13.0-14.0 18.5-19.5 8.5-9.5 18.5-19.5 8.5-9.5 18.5-19.5 8.5-9.5 18.5-19.5 14.5-15.5 18.5-19.5 9.0-13.0 18.5-19.5 4.0-14.0 18.5-19.5 9.0-10.0 18.5-19.5 PID Reading (ppm)NA NA NA NA 3.2 7.2 8.4 5.7 38.0 40.8 33.7 24.5 21.7 22.1 20.0 18.4 0.4 5.1 2.2 68.0 9.5 62.7 25.2 41.1 33.3 31.3 6.6 33.8 Benzene BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1.8 BRL 3.1 BRL 0.0064 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.0056 18 164 n-Butylbenzene BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.30 8.5 20.8 17.2 40.7 BRL 0.13 BRL BRL BRL BRL BRL BRL BRL 0.50 2.3 18.2 BRL BRL 4.3 626 16,350 Methylene chloride BRL BRL 0.032 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.02 85 763 Methyl-tert-butyl ether BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 0.010 BRL 0.011 0.0058 0.020 BRL 0.032 BRL BRL BRL BRL BRL BRL 0.091 350 3,100 sec-Butylbenzene BRL BRL BRL BRL BRL BRL BRL BRL 0.99 BRL 2.0 4.4 3.5 8.3 BRL 0.023 BRL BRL BRL BRL BRL BRL BRL BRL 0.55 4.7 BRL BRL 3.3 626 16,350 Isopropylbenzene BRL BRL BRL BRL BRL BRL BRL BRL 1.7 BRL 2.8 10.6 4.8 19.8 BRL 0.024 BRL BRL BRL BRL BRL BRL BRL BRL 0.71 8.9 BRL BRL 1.7 1,564 40,880 Ethylbenzene BRL BRL BRL BRL BRL BRL BRL BRL 10.8 0.32 11.0 101 27.4 176 BRL 0.12 BRL BRL BRL BRL 0.0062 BRL BRL BRL 2.7 42.7 BRL BRL 4.9 1,560 40,000 p-Isopropyltoluene BRL BRL BRL BRL BRL BRL BRL 1.6 3.6 0.18 5.3 BRL 9.0 20.8 BRL 0.066 BRL BRL BRL BRL BRL BRL 0.012 BRL 1.5 11.7 BRL BRL 0.12 100 4,000 Naphthalene BRL BRL BRL BRL BRL BRL BRL 10.7 14.1 1.2 30.0 121 48.6 149 BRL BRL BRL BRL BRL 0.024 0.038 0.081 0.56 3.3 8.6 45.3 BRL 0.059 0.16 313 8,176 Acetone BRL BRL BRL BRL BRL BRL BRL 31.0 11.8 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 24 14,000 360,000 n-Propylbenzene BRL BRL BRL BRL BRL BRL BRL 2.3 7.3 0.34 11.6 44.7 25.4 90.3 BRL 0.12 BRL BRL BRL BRL BRL BRL 0.0098 BRL 3.2 BRL BRL BRL 1.7 626 16,350 Toluene BRL BRL BRL BRL BRL BRL BRL BRL 6.9 0.20 3.0 170 16.6 245 BRL 0.11 BRL BRL BRL 0.0096 BRL 0.012 BRL BRL 0.60 22.6 BRL BRL 4.3 1,200 32,000 1,2,3-Trichloropropane BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 3.7 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL NS NS NS 1,2,4-Trimethylbenzene BRL BRL BRL BRL BRL BRL BRL 21.2 59.1 3.3 100 272 182 592 BRL 0.23 BRL BRL BRL 0.0064 0.039 0.022 0.15 3.0 24.3 190 0.0073 0.0062 8.5 782 20,440 1,3,5-Trimethylbenzene BRL BRL BRL BRL BRL BRL BRL 6.2 18.3 0.96 29.9 81.8 51.7 177 BRL BRL BRL BRL BRL BRL 0.010 BRL 0.036 0.80 7.4 57.7 BRL BRL 8.5 782 20,440 Total Xylenes BRL BRL BRL BRL BRL BRL BRL 7.0 61.4 2.4 66.3 506 128 943 BRL BRL BRL BRL BRL BRL 0.017 0.022 0.023 0.32 15.5 234 BRL BRL 4.6 3,129 81,760 All Other VOCs BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 1-Methylnaphthalene NS NS NS NS BRL BRL BRL 7.1 6.0 BRL 7.8 23.5 21.5 25.2 BRL 0.51 BRL BRL BRL BRL BRL BRL BRL 1.3 1.8 11.5 BRL BRL 0.004 20 100 2-Methylnaphthalene NS NS NS NS BRL BRL BRL 13.8 12.0 0.63 15.5 64.5 45.0 54.9 BRL 0.96 BRL BRL BRL BRL BRL BRL 0.73 2.6 3.8 24.6 BRL BRL 3.6 63 1,635 Naphthalene NS NS NS NS BRL BRL BRL 12.2 10.3 0.63 14.3 62.7 34.4 59.6 BRL 0.44 BRL BRL BRL BRL BRL BRL BRL 1.6 3.3 24.7 BRL BRL 0.16 313 8,176 Phrenanthene NS NS NS NS BRL BRL BRL 0.65 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 56 469 12,264 All other SVOCs NS NS NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL Aliphatics (C5-C8)NS NS NS NS BRL BRL BRL 10.3 31.9 BRL 166 736 113 573 BRL BRL BRL BRL BRL BRL BRL BRL BRL 7.6 70.7 118 BRL BRL 68 939 24,528 Aliphatics (C9-C18)NS NS NS NS BRL BRL 2.8 422.1 287 6.8 576 1,353 868 1,900 BRL 5.7 BRL BRL BRL BRL BRL BRL 3.2 15.3 337 898 BRL BRL 540 1,500 40,000 Aliphatics (C19-C36)NS NS NS NS BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL Immobile 31,000 810,000 Aromatics (C9-C22)NS NS NS NS BRL BRL 5.2 220.7 272 4.8 539 1,154 896 1,993 BRL BRL BRL BRL BRL BRL BRL BRL 3.4 9.8 318.2 509 BRL BRL 31 469 12,264 Notes: Results presented in milligrams per kilogram (mg/kg), analogous to parts per million (ppm) mg/kg = Milligrams per Kilogram Underlined = Detected above the Soil-to-Water Maximum Contaminant Concentration and Residential Soil Cleanup Level Bold = Detected above the Action Level or Soil-to-Water Maximum Contaminant Concentration BRL = Below Laboratory Reporting Limit NS = Not Standard NA = Not Applicable 4/15/2015 NCDEQ = North Carolina Department of Environmental Quality 11/5/2018 Volitile Petroluem Hydrocarbons (VPH) and Extractable Petroleum Hydrocarbons (EPH) by MADEP ECS Project: 49:6230-C Volatile Organic Compounds (VOCs) by EPA Method 8260 -- Semi-Volatile Organic Compounds (SVOCs) by EPA Method 8270 -- Soil-to-Water Maximum Contaminant Concentration Residential Soil Cleanup Level Industrial/ Commercial Soil Cleanup Level Table 2 Summary of Historical Soil Analytical Results Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: 3274 ANALYTICAL RESULTS Water Supply Well ID Well Owner / Address**Well Address Well Use Well Depth (ft bgs)Type of Well Approximate Distance from Source Area of Release (ft) WSW-1 Jean Williams (AQUA) PO Box 429 Carrboro, NC 27510 Cedar Terrace Chapel Hill, NC 27514 Potable Unknown Drilled Approximately 380 ft west WSW-5 Jean Williams PO Box 429 Carrboro, NC 27510 29 Cedar Lake Road Chapel Hill, NC 27514 Inactive Unknown Drilled Approximately 680 ft west WSW-6 Cheryl Curl Atwater and Toni Buck Curl 709 Reserve Estates Drive Wake Forest, NC 27586 Cedar Village Road Chapel Hill, NC 27514 Inactive Unknown Drilled Approximately 280 ft southwest WSW-7 Cheryl Curl Atwater and Toni Buck Curl 709 Reserve Estates Drive Wake Forest, NC 27587 103 Cedar Village Road Chapel Hill, NC 27514 Inactive Unknown Drilled Approximately 930 ft southwest ** ECS confirmed ownership details via Chatham County GIS on October 10, 2019. ECS Project: 49:6230-C Table 3 Water Supply Well Survey Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: TF-3274 SAMPLE ID MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 MW-12 Date Sampled pH 7.22 6.21 6.23 6.21 7.89 5.15 6.43 7.08 6.29 7.11 6.49 7.22 Temperature (oC)18.73 19.21 20.02 19.74 17.00 17.11 21.54 20.59 19.90 19.61 20.02 18.73 Conductivity (mS/cm)0.161 0.115 0.270 0.395 0.184 0.181 0.168 0.101 0.263 0.143 0.260 0.161 Dissolved O2 (mg/L)3.63 8.27 5.72 9.34 4.00 5.81 3.90 1.47 5.20 3.91 6.34 3.63 Turbidity (Observed)NT ST NT NT ST ST T ST T ST NT ST Notes: mS/cm = milliseimens per centimeter mV = millivolts °C = degress Celsius NT= Not Turbid ST= Slightly Turbid T= Turbid mg/L= milligrams per Liter Measured using YSI model 560 Meter ECS Project: 49:6230-C 10/1/2019 Table 4 Geochemical Measurements Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: 3274 Monitoring Well ID Date Measured Depth to Groundwater (ft. btoc) Date Installed Total Well Depth (ft. btoc) Screen Interval (ft. btoc) TOC Elevation* Groundwater Elevation (ft) MW-1 10/1/2019 31.44 4/15/2015 55 40-55 553.43 521.99 MW-2 10/1/2019 29.90 4/15/2015 54 39-54 552.44 522.54 MW-3 10/1/2019 29.95 8/10/2015 49 29-49 553.03 523.08 MW-4 10/1/2019 28.90 8/10/2015 46 26-46 551.76 522.86 MW-5 10/1/2019 31.43 8/10/2015 52 32-52 553.40 521.97 MW-6 10/1/2019 29.63 8/10/2015 52 32-52 551.94 522.31 MW-7 10/1/2019 31.22 11/6/2018 45 30-45 554.18 522.96 MW-8 10/1/2019 28.77 11/6/2018 45 30-45 551.94 523.17 MW-9 10/1/2019 30.91 9/24/2019 50 30-50 553.57 522.66 MW-10 10/1/2019 33.48 9/24/2019 50 30-50 558.02 524.54 MW-11 10/1/2019 31.25 9/25/2019 69 59-69 553.86 522.61 MW-12 10/1/2019 28.97 9/25/2019 66 56-66 551.76 522.79 Notes: ft. btoc = Feet Below Top of Casing TOC = Top of Casing* = Survey performed by Bateman Civil Survey and KCI on March 6, 2019 and October 1, 2019, respectively. The site vertical datum is based on NAV88 and the horizontal datum is based on NAD83. Table 5 Monitoring Well Construction and Groundwater Elevation Details Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina ECS Project: 49:6230-C NCDEQ Incident: 3274 Sample ID Sample Date BenzeneTolueneEthylbenzeneTotal XylenesAcetone2-ButanoneChloroformDiisopropyl etherEthanol 2-HexanoneIsopropylbenzeneMethyl tert-Butyl Ether 4-Methyl-2-pentanoneNaphthalenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneMW-1 10/1/2019 BRL BRL BRL BRL BRL BRL BRL 0.45 J BRL BRL BRL 28 BRL BRL BRL BRL BRL MW-2 10/1/2019 BRL BRL BRL BRL BRL BRL BRL 7.0 BRL BRL BRL 68 BRL BRL BRL BRL BRL MW-3 10/1/2019 24,000 48,000 4,200 20,600 BRL 2,400 J BRL 280 BRL 810 J 140 J 3,600 BRL 2,300 J 440 2,400 780 MW-4 10/1/2019 410 6.7 81 206 BRL BRL BRL 68 BRL BRL 3.8 J 400 BRL BRL 6.8 27 26 MW-5 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL MW-6 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL MW-7 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.8 BRL BRL BRL BRL BRL MW-8 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.7 BRL BRL BRL BRL BRL MW-9 10/1/2019 BRL BRL BRL BRL BRL BRL BRL 0.21 J BRL BRL BRL 11 BRL BRL BRL BRL BRL MW-10 10/1/2019 BRL BRL BRL BRL BRL BRL 11 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL MW-11 10/1/2019 BRL 0.18 J BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.2 BRL BRL BRL BRL BRL MW-12 10/1/2019 2,300 4,600 540 1,119 BRL BRL BRL 180 BRL 460 J 19 J 1,300 190 J 450 J 39 J 520 190 Field Blank 10/1/2019 BRL BRL BRL BRL 11 J BRL BRL BRL 23 J BRL BRL BRL BRL BRL BRL BRL BRL 1 600 600 500 6,000 4,000 70 70 4,000 40 70 20 100 6 70 400 400 5,000 260,000 84,500 85,500 6,000,000 4,000,000 70,000 70,000 4,000,000 40,000 25,000 20,000 100,000 6,000 30,000 28,500 25,000 Notes: NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012 (µg/L) = Micrograms per Liter Bold = Reported above the NC2LGWQS Underline = Reported above the NC2LGWQS and GCL BRL = Below Laboratory Reporting Limit J = Estimated Concentration NC2LGWQS (µg/L) GCL (µg/L) Table 6 Summary of Current Groundwater Analytical Results Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina NCDEQ Incident: 3274 ECS Project: 49:6230-C Contaminant of Concern (µg/L)Analytical Method Standard Method 6200B Sample ID Date Collected BenzeneTolueneEthylbenzeneTotal XylenesAcetone2-ButanoneChloroform1,4-DichlorobenzeneDiisopropyl etherEthanol2-HexanoneIsopropylbenzeneMethyl tert-butyl ether4-Methyl-2-pentanoneNaphthalenen-PropylbenzeneStyrene1,2,4- Trimethylbenzene1,3,5-Trimethylbenzene*MW-1 2/8/1995 1,800 3,400 300 760 BRL BRL BRL BRL BRL BRL BRL BRL 1,200 BRL BRL BRL BRL BRL BRL *MW-2 2/8/1995 1.0 1.6 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 4/16/2015 BRL BRL BRL BRL BRL BRL BRL BRL 0.90 BRL 12,830 BRL 53.5 BRL BRL BRL BRL BRL BRL 8/12/2015 BRL BRL BRL BRL BRL BRL BRL BRL 1.2 BRL BRL BRL 76.5 BRL BRL BRL BRL BRL BRL 3/7/2018 BRL BRL BRL BRL BRL BRL BRL BRL 0.64 BRL BRL BRL 53 BRL BRL BRL BRL BRL BRL 11/5/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 37.2 BRL BRL BRL BRL BRL BRL 3/6/2019 BRL BRL BRL BRL BRL BRL BRL BRL 0.43 J BRL BRL BRL 41 BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL 0.45 J BRL BRL BRL 28 BRL BRL BRL BRL BRL BRL 4/16/2015 73.3 0.64 2.7 83.8 BRL BRL BRL BRL 17.3 BRL BRL 1.7 296 BRL BRL 1.4 BRL 6.2 BRL 8/12/2015 BRL BRL BRL BRL BRL BRL BRL BRL 13.5 BRL BRL BRL 250 BRL BRL BRL BRL BRL BRL 3/7/2018 BRL BRL BRL BRL BRL BRL BRL BRL 9.9 BRL BRL BRL 130 BRL BRL BRL BRL BRL BRL 11/5/2018 BRL BRL BRL BRL BRL BRL BRL BRL 6.9 BRL BRL BRL 84.4 BRL BRL BRL BRL BRL BRL 3/6/2019 BRL BRL BRL BRL BRL BRL BRL BRL 7.3 BRL BRL BRL 100 BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL 7.0 BRL BRL BRL 68 BRL BRL BRL BRL BRL BRL 8/12/2015 29,900 32,800 1,860 9,140 BRL BRL BRL BRL 229 BRL BRL 50.3 22,700 BRL 733 188 34.4 1,350 340 3/7/2018 11/5/2018 31,900 38,700 2,880 13,830 BRL BRL BRL BRL 130 BRL BRL BRL 7,760 BRL 758 BRL BRL 2,150 BRL 3/6/2019 28,000 43,000 3,300 16,600 10,000 J 2,700 BRL BRL 290 BRL BRL 100 J 7,200 BRL 1,900 290 BRL 2,400 560 10/1/2019 24,000 48,000 4,200 20,600 BRL 2,400 J BRL BRL 280 BRL 810 J 140 J 3,600 BRL 2,300 J 440 BRL 2,400 780 8/12/2015 1,410 1,680 98.9 2,497 BRL BRL BRL BRL 296 BRL BRL BRL 4,950 BRL 26.2 7.5 BRL 306 124 3/7/2018 1,200 620 74 1,730 BRL BRL BRL BRL 160 BRL 320 3.6 J 2,100 47 J BRL 11 BRL 200 74 11/5/2018 309 24.3 37 311 BRL BRL BRL BRL 76.4 BRL BRL BRL 834 BRL 10.1 BRL BRL 47.9 BRL 3/6/2019 420 4.5 J 28 271 BRL BRL BRL BRL 77 BRL BRL 1.3 J 830 BRL 36 2.0 J BRL 48 20 10/1/2019 410 6.7 81 206 BRL BRL BRL BRL 68 BRL BRL 3.8 J 400 BRL BRL 6.8 BRL 27 26 8/12/2015 1.3 2.8 0.53 2.55 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 3/7/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 11/5/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 3/6/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 8/12/2015 2.4 5.2 0.76 3.7 BRL BRL BRL BRL BRL BRL BRL BRL 0.76 BRL BRL BRL BRL BRL BRL 3/7/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 11/5/2018 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 3/6/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 11/8/2018 BRL BRL BRL BRL BRL BRL BRL 0.9 BRL BRL BRL BRL 5.1 BRL BRL BRL BRL BRL BRL 3/6/2019 0.17 J 0.65 BRL 0.31 J BRL BRL BRL 0.50 BRL BRL BRL BRL 3.9 BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.8 BRL BRL BRL BRL BRL BRL 11/8/2018 BRL BRL BRL BRL BRL BRL BRL 0.57 BRL BRL BRL BRL 4.8 BRL BRL BRL BRL BRL BRL 3/6/2019 BRL 0.43 J BRL BRL BRL BRL BRL 0.23 J BRL BRL BRL BRL 3.6 BRL BRL BRL BRL BRL BRL 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.7 BRL BRL BRL BRL BRL BRL MW-9 10/1/2019 BRL BRL BRL BRL BRL BRL BRL BRL 0.21 J BRL BRL BRL 11 BRL BRL BRL BRL BRL BRL MW-10 10/1/2019 BRL BRL BRL BRL BRL BRL 11 BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL MW-11^10/1/2019 BRL 0.18 J BRL BRL BRL BRL BRL BRL BRL BRL BRL BRL 2.2 BRL BRL BRL BRL BRL BRL MW-12^10/1/2019 2,300 4,600 540 1,119 BRL BRL BRL BRL 180 BRL 460 J 19 J 1,300 190 J 450 J 39 J BRL 520 190 1 600 600 500 6,000 4,000 70 6 70 4,000 40 70 20 100 6 70 70 400 400 5,000 260,000 84,500 85,500 6,000,000 4,000,000 70,000 6,000 70,000 4,000,000 40,000 25,000 20,000 100,000 6,000 30,000 70,000 28,500 25,000 Notes: NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012 (µg/L) = Micrograms per Liter Bold = Reported above the NC2LGWQS or NCDEQ Final and Interim GWQS Underline = Reported above the NC2LGWQS and GCL BRL = Below Laboratory Reporting Limit J = Estimated Concentration * = Monitoring wells were abandoned in March 2001 ^ = Deep, Type II monitoring wells MW-4 Table 7 Summary of Historical Groundwater Analytical Results Petro Mart #4 11455 NC Highway 15/501 North Chapel Hill, Chatham County, North Carolina Standard Method 6200B (or equivalent) NCDEQ Incident: 3274 ECS Project: 49:6230-C Contaminant of Concern (µg/L)Analytical Method Free Product ≈ 0.36'' MW-1 MW-2 MW-3 NC2LGWQS (µg/L) Gross Contamination Level (µg/L) MW-5 MW-6 MW-7 MW-8 APPENDIX A APPENDIX B APPENDIX C  :(//&216758&7,215(&25' 7KLVIRUPFDQEHXVHGIRUVLQJOHRUPXOWLSOHZHOOV )RUP*:1RUWK&DUROLQD'HSDUWPHQWRI(QYLURQPHQWDQG1DWXUDO5HVRXUFHV±'LYLVLRQRI:DWHU4XDOLW\5HYLVHG-DQ :HOO&RQWUDFWRU,QIRUPDWLRQ  :HOO&RQWUDFWRU1DPH  1&:HOO&RQWUDFWRU&HUWLILFDWLRQ1XPEHU  &RPSDQ\1DPH  :HOO&RQVWUXFWLRQ3HUPLW List all applicable well construction 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LIDSSOLFDEOH  )520720$7(5,$/(03/$&(0(170(7+2' IWIW IWIW '5,//,1*/2* DWWDFKDGGLWLRQDOVKHHWVLIQHFHVVDU\  )52072'(6&5,37,21 FRORUKDUGQHVVVRLOURFNW\SHJUDLQVL]HHWF  IWIW IWIW IWIW IWIW IWIW IWIW IWIW 5(0$5.6   &HUWLILFDWLRQ  6LJQDWXUHRI&HUWLILHG:HOO&RQWUDFWRU'DWHBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner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o. 3274 ECS PROJECT NO. 49:6230-C Photograph 1: View of the underground utility markings near monitoring well MW-12. Photograph 2: View of the underground utility markings near monitoring well MW-11 SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 3: View of the drilling activities conducted on monitoring well MW-9. Photograph 4: View of monitoring well MW-9 construction details. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 5: View of the drilling activities conducted on monitoring well MW-10. Photograph 6: View of monitoring well MW-10 construction details. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 7: View of the drilling activities conducted on monitoring well MW-11. Photograph 8: View of monitoring well MW-11 construction details. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 9: View of the drilling activities conducted on monitoring well MW-12. Photograph 10: View of monitoring well MW-12 construction details. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 11: View of monitoring well MW-1. View is to the south. Photograph 12: View of monitoring well MW-2. View is to the south. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 13: View of monitoring well MW-3. View is to the south. Photograph 14: View of monitoring wells MW-4 and MW-12. View is to the south. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 15: View of monitoring well MW-5. View is to the north. Photograph 16: View of monitoring well MW-6. View is to the west. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 17: View of monitoring wells MW-7 and MW-11. View is to the south. Photograph 18: View of monitoring well MW-8. View is to the north. SITE PHOTOGRAPHS PETRO MART #4 11455 NC HIGHWAY 15/501 NORTH CHAPEL HILL, CHATHAM COUNTY NORTH CAROLINA NCDEQ INCIDENT No. 3274 ECS PROJECT NO. 49:6230-C Photograph 19: View of monitoring well MW-9. View is to the north. Photograph 20: View of monitoring well MW-10. View is to the north. APPENDIX E 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 October 9, 2019 Matt Gillis ECS Southeast - Raleigh, NC 9001 Glenwood Avenue Raleigh, NC 27617 Project Location: Chapel Hill, NC Client Job Number: Project Number: 49:6230-C Laboratory Work Order Number: 19J0185 Enclosed are results of analyses for samples received by the laboratory on October 2, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager Page 1 of 49 Table of Contents Table of Contents Sample Summary 3 Hits Only Report 4 Case Narrative 7 Sample Results 8 19J0185-01 8 19J0185-02 10 19J0185-03 12 19J0185-04 14 19J0185-05 16 19J0185-06 18 19J0185-07 20 19J0185-08 22 19J0185-09 24 19J0185-10 26 19J0185-11 28 19J0185-12 30 19J0185-13 32 Sample Preparation Information 34 QC Data 35 Volatile Organic Compounds by GC/MS 35 B242256 35 B242263 39 Flag/Qualifier Summary 43 Certifications 44 Chain of Custody/Sample Receipt 46 Page 2 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 10/9/2019 ECS Southeast - Raleigh, NC 9001 Glenwood Avenue Raleigh, NC 27617 ATTN: Matt Gillis 49:6230-C 19J0185 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Chapel Hill, NC Field Blank 19J0185-01 Field Blank SM21-22 6200B MW-1 19J0185-02 Ground Water SM21-22 6200B MW-2 19J0185-03 Ground Water SM21-22 6200B MW-3 19J0185-04 Ground Water SM21-22 6200B MW-4 19J0185-05 Ground Water SM21-22 6200B MW-5 19J0185-06 Ground Water SM21-22 6200B MW-6 19J0185-07 Ground Water SM21-22 6200B MW-7 19J0185-08 Ground Water SM21-22 6200B MW-8 19J0185-09 Ground Water SM21-22 6200B MW-9 19J0185-10 Ground Water SM21-22 6200B MW-10 19J0185-11 Ground Water SM21-22 6200B MW-11 19J0185-12 Ground Water SM21-22 6200B MW-12 19J0185-13 Ground Water SM21-22 6200B [TOC_1]Sample Summary[TOC] Page 3 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 [TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY Client ID:Lab ID:19J0185-06MW-5 No Results Detected Client ID:Lab ID:19J0185-07MW-6 No Results Detected Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary section of this report. Users must review this report in its entirety to determine data usability and assessment. Page 4 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 EXECUTIVE SUMMARY Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-01Field Blank DL Acetone 11 50 g/L SM21-22 6200BJ3.8 Ethanol 23 50 g/L SM21-22 6200BJ11 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-02MW-1 DL Diisopropyl Ether (DIPE)0.45 0.50 g/L SM21-22 6200BJ0.17 Methyl tert-Butyl Ether (MTBE)28 0.50 g/L SM21-22 6200B0.25 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-03MW-2 DL Diisopropyl Ether (DIPE)7.0 0.50 g/L SM21-22 6200B0.17 Methyl tert-Butyl Ether (MTBE)68 0.50 g/L SM21-22 6200B0.25 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-04MW-3 DL 1,2,4-Trimethylbenzene 2400 250 g/L SM21-22 6200B90 1,3,5-Trimethylbenzene 780 250 g/L SM21-22 6200B70 2-Butanone (MEK)2400 2500 g/L SM21-22 6200BJ970 2-Hexanone (MBK)810 2500 g/L SM21-22 6200BJ760 Benzene 24000 250 g/L SM21-22 6200B90 Diisopropyl Ether (DIPE)280 250 g/L SM21-22 6200B85 Ethylbenzene 4200 250 g/L SM21-22 6200B65 Isopropylbenzene (Cumene)140 250 g/L SM21-22 6200BJ85 m+p Xylene 14000 500 g/L SM21-22 6200B150 Methyl tert-Butyl Ether (MTBE)3600 250 g/L SM21-22 6200B120 Naphthalene 2300 2500 g/L SM21-22 6200BJ160 n-Propylbenzene 440 250 g/L SM21-22 6200B65 o-Xylene 6600 250 g/L SM21-22 6200B85 Toluene 48000 250 g/L SM21-22 6200B70 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-05MW-4 DL 1,2,4-Trimethylbenzene 27 5.0 g/L SM21-22 6200B1.8 1,3,5-Trimethylbenzene 26 5.0 g/L SM21-22 6200B1.4 Benzene 410 5.0 g/L SM21-22 6200B1.8 Diisopropyl Ether (DIPE)68 5.0 g/L SM21-22 6200B1.7 Ethylbenzene 81 5.0 g/L SM21-22 6200B1.3 Isopropylbenzene (Cumene)3.8 5.0 g/L SM21-22 6200BJ1.7 m+p Xylene 160 10 g/L SM21-22 6200B3.0 Methyl tert-Butyl Ether (MTBE)400 5.0 g/L SM21-22 6200B2.5 n-Propylbenzene 6.8 5.0 g/L SM21-22 6200B1.3 o-Xylene 46 5.0 g/L SM21-22 6200B1.7 Toluene 6.7 5.0 g/L SM21-22 6200B1.4 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-08MW-7 DL Methyl tert-Butyl Ether (MTBE)2.8 0.50 g/L SM21-22 6200B0.25 Page 5 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-09MW-8 DL Methyl tert-Butyl Ether (MTBE)2.7 0.50 g/L SM21-22 6200B0.25 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-10MW-9 DL Diisopropyl Ether (DIPE)0.21 0.50 g/L SM21-22 6200BJ0.17 Methyl tert-Butyl Ether (MTBE)11 0.50 g/L SM21-22 6200B0.25 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-11MW-10 DL Chloroform 11 0.50 g/L SM21-22 6200B0.17 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-12MW-11 DL Methyl tert-Butyl Ether (MTBE)2.2 0.50 g/L SM21-22 6200B0.25 Toluene 0.18 0.50 g/L SM21-22 6200BJ0.14 Client ID:Lab ID: Analyte Results/Qual RL Units Method 19J0185-13MW-12 DL 1,2,4-Trimethylbenzene 520 50 g/L SM21-22 6200B18 1,3,5-Trimethylbenzene 190 50 g/L SM21-22 6200B14 2-Hexanone (MBK)460 500 g/L SM21-22 6200BJ150 4-Methyl-2-pentanone (MIBK)190 500 g/L SM21-22 6200BJ170 Benzene 2300 50 g/L SM21-22 6200B18 Diisopropyl Ether (DIPE)180 50 g/L SM21-22 6200B17 Ethylbenzene 540 50 g/L SM21-22 6200B13 Isopropylbenzene (Cumene)19 50 g/L SM21-22 6200BJ17 m+p Xylene 2500 100 g/L SM21-22 6200B30 Methyl tert-Butyl Ether (MTBE)1300 50 g/L SM21-22 6200B25 Naphthalene 450 500 g/L SM21-22 6200BJ31 n-Propylbenzene 39 50 g/L SM21-22 6200BJ13 o-Xylene 1100 50 g/L SM21-22 6200B17 Toluene 4600 50 g/L SM21-22 6200B14 Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary section of this report. Users must review this report in its entirety to determine data usability and assessment. Page 6 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. For method 6200B elevated reporting limits for samples 19J0185-04+05 due to high concentrations of target compounds. [TOC_1]Case Narrative[TOC] SM21-22 6200B Qualifications: Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is on the high side. Analyte & Samples(s) Qualified: L-02 Vinyl Chloride B242256-BS1, B242256-BSD1 Elevated reporting limit due to high concentration of target compounds. Analyte & Samples(s) Qualified: RL-11 19J0185-04[MW-3], 19J0185-05[MW-4], 19J0185-13[MW-12] The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 7 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-01 Field Sample #: Field Blank Sample Matrix: Field Blank Sampled: 10/1/2019 09:46 [TOC_2]19J0185-01[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 11 50 10/5/19 2:15 EEHg/L3.8 10/4/19SM21-22 6200B1JAcetone ND 0.50 10/5/19 2:15 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 2:15 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 2:15 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 2:15 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 2:15 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 2:15 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 2:15 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 2:15 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 2:15 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 2:15 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene 23 50 10/5/19 2:15 EEHg/L11 10/4/19SM21-22 6200B1JEthanol ND 0.50 10/5/19 2:15 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 2:15 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 2:15 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 0.60 10/5/19 2:15 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 2:15 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 2:15 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 2:15 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 2:15 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 2:15 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 2:15 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 0.50 10/5/19 2:15 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 2:15 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 2:15 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 2:15 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 2:15 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 2:15 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 2:15 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 2:15 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 2:15 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 2:15 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 2:15 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 2:15 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 2:15 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 2:15 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 10/5/19 2:15 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 2:15 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 2:15 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) [TOC_1]Sample Results[TOC] Page 8 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-01 Field Sample #: Field Blank Sample Matrix: Field Blank Sampled: 10/1/2019 09:46 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 10/5/19 2:15 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 2:15 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 2:15 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 2:15 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 2:15 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 2:15 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 1.0 10/5/19 2:15 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 2:15 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 2:15 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 2:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 2:15 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 2:15 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 2:15 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 2:15 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 2:15 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 2:15 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 2:15 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 2:15 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 2:15 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 101 10/5/19 2:1570-130 Toluene-d8 99.8 10/5/19 2:1570-130 4-Bromofluorobenzene 90.3 10/5/19 2:1570-130 Page 9 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-02 Field Sample #: MW-1 Sample Matrix: Ground Water Sampled: 10/1/2019 10:43 [TOC_2]19J0185-02[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 8:36 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 8:36 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 8:36 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 8:36 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 8:36 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 8:36 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 8:36 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 8:36 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 8:36 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 8:36 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 8:36 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 8:36 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 8:36 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 8:36 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 8:36 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 8:36 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 8:36 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 8:36 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 8:36 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 8:36 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 8:36 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 8:36 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 8:36 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 8:36 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 8:36 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 8:36 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 8:36 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 8:36 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 8:36 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 8:36 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 8:36 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene 0.45 0.50 10/5/19 8:36 EEHg/L0.17 10/4/19SM21-22 6200B1JDiisopropyl Ether (DIPE) ND 0.50 10/5/19 8:36 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 8:36 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 8:36 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 8:36 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 28 0.50 10/5/19 8:36 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 8:36 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 8:36 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 10 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-02 Field Sample #: MW-1 Sample Matrix: Ground Water Sampled: 10/1/2019 10:43 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 8:36 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 8:36 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 8:36 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 8:36 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 8:36 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 8:36 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 8:36 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 8:36 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 8:36 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 8:36 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 8:36 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 8:36 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 8:36 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 8:36 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 8:36 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 8:36 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 8:36 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 8:36 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 8:36 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 95.0 10/5/19 8:3670-130 Toluene-d8 97.5 10/5/19 8:3670-130 4-Bromofluorobenzene 96.4 10/5/19 8:3670-130 Page 11 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-03 Field Sample #: MW-2 Sample Matrix: Ground Water Sampled: 10/1/2019 11:16 [TOC_2]19J0185-03[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 9:05 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 9:05 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 9:05 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 9:05 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 9:05 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 9:05 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 9:05 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 9:05 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 9:05 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 9:05 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 9:05 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 9:05 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 9:05 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 9:05 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 9:05 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 9:05 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 9:05 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 9:05 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 9:05 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 9:05 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 9:05 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 9:05 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 9:05 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 9:05 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 9:05 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 9:05 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 9:05 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 9:05 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 9:05 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 9:05 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 9:05 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene 7.0 0.50 10/5/19 9:05 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 9:05 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 9:05 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 9:05 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 9:05 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 68 0.50 10/5/19 9:05 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 9:05 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 9:05 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 12 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-03 Field Sample #: MW-2 Sample Matrix: Ground Water Sampled: 10/1/2019 11:16 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 9:05 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 9:05 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 9:05 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 9:05 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 9:05 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 9:05 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 9:05 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 9:05 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 9:05 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 9:05 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 9:05 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 9:05 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 9:05 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 9:05 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 9:05 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 9:05 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 9:05 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 9:05 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 9:05 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 95.4 10/5/19 9:0570-130 Toluene-d8 96.2 10/5/19 9:0570-130 4-Bromofluorobenzene 94.4 10/5/19 9:0570-130 Page 13 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-04 Field Sample #: MW-3 Sample Matrix: Ground Water Sampled: 10/1/2019 12:30 [TOC_2]19J0185-04[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 25000 10/5/19 10:02 EEHg/L1900 10/4/19SM21-22 6200B500Acetone 24000 250 10/5/19 10:02 EEHg/L90 10/4/19SM21-22 6200B500Benzene ND 250 10/5/19 10:02 EEHg/L75 10/4/19SM21-22 6200B500Bromobenzene ND 250 10/5/19 10:02 EEHg/L160 10/4/19SM21-22 6200B500Bromochloromethane ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B500Bromodichloromethane ND 250 10/5/19 10:02 EEHg/L230 10/4/19SM21-22 6200B500Bromoform ND 500 10/5/19 10:02 EEHg/L390 10/4/19SM21-22 6200B500Bromomethane 2400 2500 10/5/19 10:02 EEHg/L970 10/4/19SM21-22 6200B500J2-Butanone (MEK) ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B500n-Butylbenzene ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B500sec-Butylbenzene ND 250 10/5/19 10:02 EEHg/L85 10/4/19SM21-22 6200B500tert-Butylbenzene ND 250 10/5/19 10:02 EEHg/L55 10/4/19SM21-22 6200B500Carbon Tetrachloride ND 250 10/5/19 10:02 EEHg/L75 10/4/19SM21-22 6200B500Chlorobenzene ND 25000 10/5/19 10:02 EEHg/L5300 10/4/19SM21-22 6200B500Ethanol ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B500Chlorodibromomethane ND 250 10/5/19 10:02 EEHg/L180 10/4/19SM21-22 6200B500Chloroethane ND 250 10/5/19 10:02 EEHg/L85 10/4/19SM21-22 6200B500Chloroform ND 500 10/5/19 10:02 EEHg/L220 10/4/19SM21-22 6200B500Chloromethane ND 250 10/5/19 10:02 EEHg/L60 10/4/19SM21-22 6200B5002-Chlorotoluene ND 250 10/5/19 10:02 EEHg/L70 10/4/19SM21-22 6200B5004-Chlorotoluene ND 250 10/5/19 10:02 EEHg/L95 10/4/19SM21-22 6200B5001,2-Dibromoethane (EDB) ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B5001,2-Dichlorobenzene ND 250 10/5/19 10:02 EEHg/L60 10/4/19SM21-22 6200B5001,3-Dichlorobenzene ND 250 10/5/19 10:02 EEHg/L65 10/4/19SM21-22 6200B5001,4-Dichlorobenzene ND 250 10/5/19 10:02 EEHg/L130 10/4/19SM21-22 6200B500Dichlorodifluoromethane (Freon 12) ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B5001,1-Dichloroethane ND 500 10/5/19 10:02 EEHg/L200 10/4/19SM21-22 6200B5001,2-Dichloroethane ND 250 10/5/19 10:02 EEHg/L160 10/4/19SM21-22 6200B5001,1-Dichloroethylene ND 250 10/5/19 10:02 EEHg/L65 10/4/19SM21-22 6200B500cis-1,2-Dichloroethylene ND 250 10/5/19 10:02 EEHg/L160 10/4/19SM21-22 6200B500trans-1,2-Dichloroethylene ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B5001,2-Dichloropropane ND 250 10/5/19 10:02 EEHg/L55 10/4/19SM21-22 6200B5001,3-Dichloropropane ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B5002,2-Dichloropropane ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B5001,1-Dichloropropene ND 250 10/5/19 10:02 EEHg/L65 10/4/19SM21-22 6200B500cis-1,3-Dichloropropene ND 250 10/5/19 10:02 EEHg/L120 10/4/19SM21-22 6200B500trans-1,3-Dichloropropene 280 250 10/5/19 10:02 EEHg/L85 10/4/19SM21-22 6200B500Diisopropyl Ether (DIPE) 4200 250 10/5/19 10:02 EEHg/L65 10/4/19SM21-22 6200B500Ethylbenzene 810 2500 10/5/19 10:02 EEHg/L760 10/4/19SM21-22 6200B500J2-Hexanone (MBK) 140 250 10/5/19 10:02 EEHg/L85 10/4/19SM21-22 6200B500JIsopropylbenzene (Cumene) ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B500p-Isopropyltoluene (p-Cymene) 3600 250 10/5/19 10:02 EEHg/L120 10/4/19SM21-22 6200B500Methyl tert-Butyl Ether (MTBE) ND 2500 10/5/19 10:02 EEHg/L170 10/4/19SM21-22 6200B500Methylene Chloride ND 2500 10/5/19 10:02 EEHg/L840 10/4/19SM21-22 6200B5004-Methyl-2-pentanone (MIBK) Page 14 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-04 Field Sample #: MW-3 Sample Matrix: Ground Water Sampled: 10/1/2019 12:30 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS 2300 2500 10/5/19 10:02 EEHg/L160 10/4/19SM21-22 6200B500JNaphthalene 440 250 10/5/19 10:02 EEHg/L65 10/4/19SM21-22 6200B500n-Propylbenzene ND 250 10/5/19 10:02 EEHg/L55 10/4/19SM21-22 6200B500Styrene ND 250 10/5/19 10:02 EEHg/L110 10/4/19SM21-22 6200B5001,1,2,2-Tetrachloroethane ND 250 10/5/19 10:02 EEHg/L90 10/4/19SM21-22 6200B500Tetrachloroethylene 48000 250 10/5/19 10:02 EEHg/L70 10/4/19SM21-22 6200B500Toluene ND 1000 10/5/19 10:02 EEHg/L280 10/4/19SM21-22 6200B5001,2,3-Trichlorobenzene ND 250 10/5/19 10:02 EEHg/L200 10/4/19SM21-22 6200B5001,2,4-Trichlorobenzene ND 250 10/5/19 10:02 EEHg/L100 10/4/19SM21-22 6200B5001,1,1-Trichloroethane ND 250 10/5/19 10:02 EEHg/L80 10/4/19SM21-22 6200B5001,1,2-Trichloroethane ND 250 10/5/19 10:02 EEHg/L120 10/4/19SM21-22 6200B500Trichloroethylene ND 250 10/5/19 10:02 EEHg/L160 10/4/19SM21-22 6200B500Trichlorofluoromethane (Freon 11) ND 250 10/5/19 10:02 EEHg/L120 10/4/19SM21-22 6200B5001,2,3-Trichloropropane 2400 250 10/5/19 10:02 EEHg/L90 10/4/19SM21-22 6200B5001,2,4-Trimethylbenzene 780 250 10/5/19 10:02 EEHg/L70 10/4/19SM21-22 6200B5001,3,5-Trimethylbenzene ND 10000 10/5/19 10:02 EEHg/L5100 10/4/19SM21-22 6200B500Vinyl Acetate ND 250 10/5/19 10:02 EEHg/L220 10/4/19SM21-22 6200B500Vinyl Chloride 14000 500 10/5/19 10:02 EEHg/L150 10/4/19SM21-22 6200B500m+p Xylene 6600 250 10/5/19 10:02 EEHg/L85 10/4/19SM21-22 6200B500o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 93.7 10/5/19 10:0270-130 Toluene-d8 95.7 10/5/19 10:0270-130 4-Bromofluorobenzene 97.6 10/5/19 10:0270-130 Page 15 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-05 Field Sample #: MW-4 Sample Matrix: Ground Water Sampled: 10/1/2019 12:14 [TOC_2]19J0185-05[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 500 10/5/19 9:33 EEHg/L38 10/4/19SM21-22 6200B10Acetone 410 5.0 10/5/19 9:33 EEHg/L1.8 10/4/19SM21-22 6200B10Benzene ND 5.0 10/5/19 9:33 EEHg/L1.5 10/4/19SM21-22 6200B10Bromobenzene ND 5.0 10/5/19 9:33 EEHg/L3.2 10/4/19SM21-22 6200B10Bromochloromethane ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B10Bromodichloromethane ND 5.0 10/5/19 9:33 EEHg/L4.6 10/4/19SM21-22 6200B10Bromoform ND 10 10/5/19 9:33 EEHg/L7.8 10/4/19SM21-22 6200B10Bromomethane ND 50 10/5/19 9:33 EEHg/L19 10/4/19SM21-22 6200B102-Butanone (MEK) ND 5.0 10/5/19 9:33 EEHg/L2.1 10/4/19SM21-22 6200B10n-Butylbenzene ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B10sec-Butylbenzene ND 5.0 10/5/19 9:33 EEHg/L1.7 10/4/19SM21-22 6200B10tert-Butylbenzene ND 5.0 10/5/19 9:33 EEHg/L1.1 10/4/19SM21-22 6200B10Carbon Tetrachloride ND 5.0 10/5/19 9:33 EEHg/L1.5 10/4/19SM21-22 6200B10Chlorobenzene ND 500 10/5/19 9:33 EEHg/L110 10/4/19SM21-22 6200B10Ethanol ND 5.0 10/5/19 9:33 EEHg/L2.1 10/4/19SM21-22 6200B10Chlorodibromomethane ND 5.0 10/5/19 9:33 EEHg/L3.5 10/4/19SM21-22 6200B10Chloroethane ND 5.0 10/5/19 9:33 EEHg/L1.7 10/4/19SM21-22 6200B10Chloroform ND 10 10/5/19 9:33 EEHg/L4.5 10/4/19SM21-22 6200B10Chloromethane ND 5.0 10/5/19 9:33 EEHg/L1.2 10/4/19SM21-22 6200B102-Chlorotoluene ND 5.0 10/5/19 9:33 EEHg/L1.4 10/4/19SM21-22 6200B104-Chlorotoluene ND 5.0 10/5/19 9:33 EEHg/L1.9 10/4/19SM21-22 6200B101,2-Dibromoethane (EDB) ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B101,2-Dichlorobenzene ND 5.0 10/5/19 9:33 EEHg/L1.2 10/4/19SM21-22 6200B101,3-Dichlorobenzene ND 5.0 10/5/19 9:33 EEHg/L1.3 10/4/19SM21-22 6200B101,4-Dichlorobenzene ND 5.0 10/5/19 9:33 EEHg/L2.6 10/4/19SM21-22 6200B10Dichlorodifluoromethane (Freon 12) ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B101,1-Dichloroethane ND 10 10/5/19 9:33 EEHg/L4.1 10/4/19SM21-22 6200B101,2-Dichloroethane ND 5.0 10/5/19 9:33 EEHg/L3.2 10/4/19SM21-22 6200B101,1-Dichloroethylene ND 5.0 10/5/19 9:33 EEHg/L1.3 10/4/19SM21-22 6200B10cis-1,2-Dichloroethylene ND 5.0 10/5/19 9:33 EEHg/L3.1 10/4/19SM21-22 6200B10trans-1,2-Dichloroethylene ND 5.0 10/5/19 9:33 EEHg/L2.0 10/4/19SM21-22 6200B101,2-Dichloropropane ND 5.0 10/5/19 9:33 EEHg/L1.1 10/4/19SM21-22 6200B101,3-Dichloropropane ND 5.0 10/5/19 9:33 EEHg/L2.0 10/4/19SM21-22 6200B102,2-Dichloropropane ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B101,1-Dichloropropene ND 5.0 10/5/19 9:33 EEHg/L1.3 10/4/19SM21-22 6200B10cis-1,3-Dichloropropene ND 5.0 10/5/19 9:33 EEHg/L2.3 10/4/19SM21-22 6200B10trans-1,3-Dichloropropene 68 5.0 10/5/19 9:33 EEHg/L1.7 10/4/19SM21-22 6200B10Diisopropyl Ether (DIPE) 81 5.0 10/5/19 9:33 EEHg/L1.3 10/4/19SM21-22 6200B10Ethylbenzene ND 50 10/5/19 9:33 EEHg/L15 10/4/19SM21-22 6200B102-Hexanone (MBK) 3.8 5.0 10/5/19 9:33 EEHg/L1.7 10/4/19SM21-22 6200B10JIsopropylbenzene (Cumene) ND 5.0 10/5/19 9:33 EEHg/L2.0 10/4/19SM21-22 6200B10p-Isopropyltoluene (p-Cymene) 400 5.0 10/5/19 9:33 EEHg/L2.5 10/4/19SM21-22 6200B10Methyl tert-Butyl Ether (MTBE) ND 50 10/5/19 9:33 EEHg/L3.4 10/4/19SM21-22 6200B10Methylene Chloride ND 50 10/5/19 9:33 EEHg/L17 10/4/19SM21-22 6200B104-Methyl-2-pentanone (MIBK) Page 16 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-05 Field Sample #: MW-4 Sample Matrix: Ground Water Sampled: 10/1/2019 12:14 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 50 10/5/19 9:33 EEHg/L3.1 10/4/19SM21-22 6200B10Naphthalene 6.8 5.0 10/5/19 9:33 EEHg/L1.3 10/4/19SM21-22 6200B10n-Propylbenzene ND 5.0 10/5/19 9:33 EEHg/L1.1 10/4/19SM21-22 6200B10Styrene ND 5.0 10/5/19 9:33 EEHg/L2.2 10/4/19SM21-22 6200B101,1,2,2-Tetrachloroethane ND 5.0 10/5/19 9:33 EEHg/L1.8 10/4/19SM21-22 6200B10Tetrachloroethylene 6.7 5.0 10/5/19 9:33 EEHg/L1.4 10/4/19SM21-22 6200B10Toluene ND 20 10/5/19 9:33 EEHg/L5.7 10/4/19SM21-22 6200B101,2,3-Trichlorobenzene ND 5.0 10/5/19 9:33 EEHg/L4.0 10/4/19SM21-22 6200B101,2,4-Trichlorobenzene ND 5.0 10/5/19 9:33 EEHg/L2.0 10/4/19SM21-22 6200B101,1,1-Trichloroethane ND 5.0 10/5/19 9:33 EEHg/L1.6 10/4/19SM21-22 6200B101,1,2-Trichloroethane ND 5.0 10/5/19 9:33 EEHg/L2.4 10/4/19SM21-22 6200B10Trichloroethylene ND 5.0 10/5/19 9:33 EEHg/L3.3 10/4/19SM21-22 6200B10Trichlorofluoromethane (Freon 11) ND 5.0 10/5/19 9:33 EEHg/L2.5 10/4/19SM21-22 6200B101,2,3-Trichloropropane 27 5.0 10/5/19 9:33 EEHg/L1.8 10/4/19SM21-22 6200B101,2,4-Trimethylbenzene 26 5.0 10/5/19 9:33 EEHg/L1.4 10/4/19SM21-22 6200B101,3,5-Trimethylbenzene ND 200 10/5/19 9:33 EEHg/L100 10/4/19SM21-22 6200B10Vinyl Acetate ND 5.0 10/5/19 9:33 EEHg/L4.5 10/4/19SM21-22 6200B10Vinyl Chloride 160 10 10/5/19 9:33 EEHg/L3.0 10/4/19SM21-22 6200B10m+p Xylene 46 5.0 10/5/19 9:33 EEHg/L1.7 10/4/19SM21-22 6200B10o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 95.2 10/5/19 9:3370-130 Toluene-d8 97.2 10/5/19 9:3370-130 4-Bromofluorobenzene 96.3 10/5/19 9:3370-130 Page 17 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-06 Field Sample #: MW-5 Sample Matrix: Ground Water Sampled: 10/1/2019 10:31 [TOC_2]19J0185-06[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 3:49 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 3:49 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 3:49 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 3:49 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 3:49 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 3:49 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 3:49 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 3:49 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 3:49 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 3:49 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 3:49 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 3:49 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 3:49 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 3:49 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 3:49 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 3:49 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 3:49 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 3:49 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 3:49 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 3:49 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 3:49 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 3:49 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 3:49 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 3:49 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 3:49 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 3:49 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 3:49 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 3:49 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 3:49 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 3:49 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 3:49 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 3:49 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 3:49 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 3:49 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 3:49 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 3:49 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 10/5/19 3:49 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 3:49 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 3:49 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 18 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-06 Field Sample #: MW-5 Sample Matrix: Ground Water Sampled: 10/1/2019 10:31 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 3:49 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 3:49 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 3:49 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 3:49 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 3:49 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 3:49 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 3:49 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 3:49 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 3:49 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 3:49 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 3:49 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 3:49 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 3:49 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 3:49 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 3:49 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 3:49 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 3:49 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 3:49 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 3:49 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 94.1 10/5/19 3:4970-130 Toluene-d8 97.2 10/5/19 3:4970-130 4-Bromofluorobenzene 83.9 10/5/19 3:4970-130 Page 19 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-07 Field Sample #: MW-6 Sample Matrix: Ground Water Sampled: 10/1/2019 10:15 [TOC_2]19J0185-07[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 4:17 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 4:17 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 4:17 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 4:17 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 4:17 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 4:17 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 4:17 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 4:17 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 4:17 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 4:17 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 4:17 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 4:17 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 4:17 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 4:17 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 4:17 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 4:17 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 4:17 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 4:17 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 4:17 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 4:17 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 4:17 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 4:17 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 4:17 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 4:17 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 4:17 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 4:17 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 4:17 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 4:17 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 4:17 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 4:17 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 4:17 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 4:17 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 4:17 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 4:17 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 4:17 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 4:17 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 10/5/19 4:17 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 4:17 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 4:17 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 20 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-07 Field Sample #: MW-6 Sample Matrix: Ground Water Sampled: 10/1/2019 10:15 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 4:17 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 4:17 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 4:17 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 4:17 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 4:17 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 4:17 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 4:17 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 4:17 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 4:17 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 4:17 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 4:17 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 4:17 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 4:17 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 4:17 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 4:17 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 4:17 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 4:17 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 4:17 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 4:17 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 96.4 10/5/19 4:1770-130 Toluene-d8 98.4 10/5/19 4:1770-130 4-Bromofluorobenzene 94.1 10/5/19 4:1770-130 Page 21 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-08 Field Sample #: MW-7 Sample Matrix: Ground Water Sampled: 10/1/2019 15:00 [TOC_2]19J0185-08[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 4:46 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 4:46 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 4:46 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 4:46 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 4:46 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 4:46 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 4:46 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 4:46 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 4:46 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 4:46 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 4:46 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 4:46 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 4:46 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 4:46 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 4:46 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 4:46 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 4:46 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 4:46 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 4:46 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 4:46 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 4:46 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 4:46 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 4:46 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 4:46 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 4:46 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 4:46 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 4:46 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 4:46 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 4:46 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 4:46 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 4:46 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 4:46 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 4:46 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 4:46 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 4:46 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 4:46 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 2.8 0.50 10/5/19 4:46 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 4:46 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 4:46 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 22 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-08 Field Sample #: MW-7 Sample Matrix: Ground Water Sampled: 10/1/2019 15:00 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 4:46 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 4:46 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 4:46 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 4:46 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 4:46 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 4:46 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 4:46 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 4:46 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 4:46 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 4:46 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 4:46 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 4:46 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 4:46 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 4:46 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 4:46 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 4:46 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 4:46 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 4:46 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 4:46 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 92.5 10/5/19 4:4670-130 Toluene-d8 101 10/5/19 4:4670-130 4-Bromofluorobenzene 93.5 10/5/19 4:4670-130 Page 23 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-09 Field Sample #: MW-8 Sample Matrix: Ground Water Sampled: 10/1/2019 14:43 [TOC_2]19J0185-09[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 5:15 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 5:15 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 5:15 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 5:15 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 5:15 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 5:15 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 5:15 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 5:15 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 5:15 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 5:15 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 5:15 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 5:15 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 5:15 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 5:15 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 5:15 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 5:15 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 5:15 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 5:15 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 5:15 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 5:15 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 5:15 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 5:15 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 5:15 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 5:15 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 5:15 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 5:15 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 5:15 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 5:15 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 5:15 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 5:15 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 5:15 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 5:15 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 5:15 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 5:15 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 5:15 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 5:15 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 2.7 0.50 10/5/19 5:15 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 5:15 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 5:15 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 24 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-09 Field Sample #: MW-8 Sample Matrix: Ground Water Sampled: 10/1/2019 14:43 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 5:15 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 5:15 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 5:15 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 5:15 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 5:15 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 5:15 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 5:15 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 5:15 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 5:15 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 5:15 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 5:15 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 5:15 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 5:15 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 5:15 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 5:15 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 5:15 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 5:15 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 5:15 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 5:15 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 99.3 10/5/19 5:1570-130 Toluene-d8 104 10/5/19 5:1570-130 4-Bromofluorobenzene 92.0 10/5/19 5:1570-130 Page 25 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-10 Field Sample #: MW-9 Sample Matrix: Ground Water Sampled: 10/1/2019 17:04 [TOC_2]19J0185-10[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 5:43 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 5:43 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 5:43 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 5:43 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 5:43 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 5:43 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 5:43 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 5:43 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 5:43 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 5:43 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 5:43 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 5:43 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 5:43 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 5:43 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 5:43 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 5:43 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 5:43 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 5:43 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 5:43 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 5:43 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 5:43 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 5:43 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 5:43 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 5:43 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 5:43 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 5:43 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 5:43 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 5:43 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 5:43 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 5:43 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 5:43 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene 0.21 0.50 10/5/19 5:43 EEHg/L0.17 10/4/19SM21-22 6200B1JDiisopropyl Ether (DIPE) ND 0.50 10/5/19 5:43 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 5:43 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 5:43 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 5:43 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 11 0.50 10/5/19 5:43 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 5:43 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 5:43 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 26 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-10 Field Sample #: MW-9 Sample Matrix: Ground Water Sampled: 10/1/2019 17:04 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 5:43 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 5:43 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 5:43 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 5:43 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 5:43 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 5:43 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 5:43 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 5:43 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 5:43 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 5:43 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 5:43 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 5:43 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 5:43 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 5:43 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 5:43 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 5:43 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 5:43 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 5:43 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 5:43 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 96.0 10/5/19 5:4370-130 Toluene-d8 106 10/5/19 5:4370-130 4-Bromofluorobenzene 96.8 10/5/19 5:4370-130 Page 27 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-11 Field Sample #: MW-10 Sample Matrix: Ground Water Sampled: 10/1/2019 00:00 [TOC_2]19J0185-11[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 6:12 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 6:12 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 6:12 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 6:12 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 6:12 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 6:12 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 6:12 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 6:12 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 6:12 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 6:12 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 6:12 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 6:12 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 6:12 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 6:12 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane 11 0.50 10/5/19 6:12 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 6:12 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 6:12 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 6:12 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 6:12 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 6:12 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 6:12 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 6:12 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 6:12 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 6:12 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 6:12 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 6:12 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 6:12 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 6:12 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 6:12 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 6:12 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 6:12 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 6:12 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 6:12 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 6:12 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 6:12 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 6:12 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 10/5/19 6:12 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 6:12 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 6:12 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 28 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-11 Field Sample #: MW-10 Sample Matrix: Ground Water Sampled: 10/1/2019 00:00 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 6:12 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 6:12 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 6:12 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 6:12 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 6:12 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene ND 0.50 10/5/19 6:12 EEHg/L0.14 10/4/19SM21-22 6200B1Toluene ND 2.0 10/5/19 6:12 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 6:12 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 6:12 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 6:12 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 6:12 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 6:12 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 6:12 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 6:12 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 6:12 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 6:12 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 6:12 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 6:12 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 6:12 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 95.8 10/5/19 6:1270-130 Toluene-d8 97.2 10/5/19 6:1270-130 4-Bromofluorobenzene 106 10/5/19 6:1270-130 Page 29 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-12 Field Sample #: MW-11 Sample Matrix: Ground Water Sampled: 10/1/2019 15:20 [TOC_2]19J0185-12[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 10/5/19 6:41 EEHg/L3.8 10/4/19SM21-22 6200B1Acetone ND 0.50 10/5/19 6:41 EEHg/L0.18 10/4/19SM21-22 6200B1Benzene ND 0.50 10/5/19 6:41 EEHg/L0.15 10/4/19SM21-22 6200B1Bromobenzene ND 0.50 10/5/19 6:41 EEHg/L0.32 10/4/19SM21-22 6200B1Bromochloromethane ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B1Bromodichloromethane ND 0.50 10/5/19 6:41 EEHg/L0.46 10/4/19SM21-22 6200B1Bromoform ND 1.0 10/5/19 6:41 EEHg/L0.78 10/4/19SM21-22 6200B1Bromomethane ND 5.0 10/5/19 6:41 EEHg/L1.9 10/4/19SM21-22 6200B12-Butanone (MEK) ND 0.50 10/5/19 6:41 EEHg/L0.21 10/4/19SM21-22 6200B1n-Butylbenzene ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B1sec-Butylbenzene ND 0.50 10/5/19 6:41 EEHg/L0.17 10/4/19SM21-22 6200B1tert-Butylbenzene ND 0.50 10/5/19 6:41 EEHg/L0.11 10/4/19SM21-22 6200B1Carbon Tetrachloride ND 0.50 10/5/19 6:41 EEHg/L0.15 10/4/19SM21-22 6200B1Chlorobenzene ND 50 10/5/19 6:41 EEHg/L11 10/4/19SM21-22 6200B1Ethanol ND 0.50 10/5/19 6:41 EEHg/L0.21 10/4/19SM21-22 6200B1Chlorodibromomethane ND 0.50 10/5/19 6:41 EEHg/L0.35 10/4/19SM21-22 6200B1Chloroethane ND 0.50 10/5/19 6:41 EEHg/L0.17 10/4/19SM21-22 6200B1Chloroform ND 1.0 10/5/19 6:41 EEHg/L0.45 10/4/19SM21-22 6200B1Chloromethane ND 0.50 10/5/19 6:41 EEHg/L0.12 10/4/19SM21-22 6200B12-Chlorotoluene ND 0.50 10/5/19 6:41 EEHg/L0.14 10/4/19SM21-22 6200B14-Chlorotoluene ND 0.50 10/5/19 6:41 EEHg/L0.19 10/4/19SM21-22 6200B11,2-Dibromoethane (EDB) ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B11,2-Dichlorobenzene ND 0.50 10/5/19 6:41 EEHg/L0.12 10/4/19SM21-22 6200B11,3-Dichlorobenzene ND 0.50 10/5/19 6:41 EEHg/L0.13 10/4/19SM21-22 6200B11,4-Dichlorobenzene ND 0.50 10/5/19 6:41 EEHg/L0.26 10/4/19SM21-22 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloroethane ND 1.0 10/5/19 6:41 EEHg/L0.41 10/4/19SM21-22 6200B11,2-Dichloroethane ND 0.50 10/5/19 6:41 EEHg/L0.32 10/4/19SM21-22 6200B11,1-Dichloroethylene ND 0.50 10/5/19 6:41 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,2-Dichloroethylene ND 0.50 10/5/19 6:41 EEHg/L0.31 10/4/19SM21-22 6200B1trans-1,2-Dichloroethylene ND 0.50 10/5/19 6:41 EEHg/L0.20 10/4/19SM21-22 6200B11,2-Dichloropropane ND 0.50 10/5/19 6:41 EEHg/L0.11 10/4/19SM21-22 6200B11,3-Dichloropropane ND 0.50 10/5/19 6:41 EEHg/L0.20 10/4/19SM21-22 6200B12,2-Dichloropropane ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B11,1-Dichloropropene ND 0.50 10/5/19 6:41 EEHg/L0.13 10/4/19SM21-22 6200B1cis-1,3-Dichloropropene ND 0.50 10/5/19 6:41 EEHg/L0.23 10/4/19SM21-22 6200B1trans-1,3-Dichloropropene ND 0.50 10/5/19 6:41 EEHg/L0.17 10/4/19SM21-22 6200B1Diisopropyl Ether (DIPE) ND 0.50 10/5/19 6:41 EEHg/L0.13 10/4/19SM21-22 6200B1Ethylbenzene ND 5.0 10/5/19 6:41 EEHg/L1.5 10/4/19SM21-22 6200B12-Hexanone (MBK) ND 0.50 10/5/19 6:41 EEHg/L0.17 10/4/19SM21-22 6200B1Isopropylbenzene (Cumene) ND 0.50 10/5/19 6:41 EEHg/L0.20 10/4/19SM21-22 6200B1p-Isopropyltoluene (p-Cymene) 2.2 0.50 10/5/19 6:41 EEHg/L0.25 10/4/19SM21-22 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 10/5/19 6:41 EEHg/L0.34 10/4/19SM21-22 6200B1Methylene Chloride ND 5.0 10/5/19 6:41 EEHg/L1.7 10/4/19SM21-22 6200B14-Methyl-2-pentanone (MIBK) Page 30 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-12 Field Sample #: MW-11 Sample Matrix: Ground Water Sampled: 10/1/2019 15:20 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 5.0 10/5/19 6:41 EEHg/L0.31 10/4/19SM21-22 6200B1Naphthalene ND 0.50 10/5/19 6:41 EEHg/L0.13 10/4/19SM21-22 6200B1n-Propylbenzene ND 0.50 10/5/19 6:41 EEHg/L0.11 10/4/19SM21-22 6200B1Styrene ND 0.50 10/5/19 6:41 EEHg/L0.22 10/4/19SM21-22 6200B11,1,2,2-Tetrachloroethane ND 0.50 10/5/19 6:41 EEHg/L0.18 10/4/19SM21-22 6200B1Tetrachloroethylene 0.18 0.50 10/5/19 6:41 EEHg/L0.14 10/4/19SM21-22 6200B1JToluene ND 2.0 10/5/19 6:41 EEHg/L0.57 10/4/19SM21-22 6200B11,2,3-Trichlorobenzene ND 0.50 10/5/19 6:41 EEHg/L0.40 10/4/19SM21-22 6200B11,2,4-Trichlorobenzene ND 0.50 10/5/19 6:41 EEHg/L0.20 10/4/19SM21-22 6200B11,1,1-Trichloroethane ND 0.50 10/5/19 6:41 EEHg/L0.16 10/4/19SM21-22 6200B11,1,2-Trichloroethane ND 0.50 10/5/19 6:41 EEHg/L0.24 10/4/19SM21-22 6200B1Trichloroethylene ND 0.50 10/5/19 6:41 EEHg/L0.33 10/4/19SM21-22 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 10/5/19 6:41 EEHg/L0.25 10/4/19SM21-22 6200B11,2,3-Trichloropropane ND 0.50 10/5/19 6:41 EEHg/L0.18 10/4/19SM21-22 6200B11,2,4-Trimethylbenzene ND 0.50 10/5/19 6:41 EEHg/L0.14 10/4/19SM21-22 6200B11,3,5-Trimethylbenzene ND 20 10/5/19 6:41 EEHg/L10 10/4/19SM21-22 6200B1Vinyl Acetate ND 0.50 10/5/19 6:41 EEHg/L0.45 10/4/19SM21-22 6200B1Vinyl Chloride ND 1.0 10/5/19 6:41 EEHg/L0.30 10/4/19SM21-22 6200B1m+p Xylene ND 0.50 10/5/19 6:41 EEHg/L0.17 10/4/19SM21-22 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 96.8 10/5/19 6:4170-130 Toluene-d8 97.5 10/5/19 6:4170-130 4-Bromofluorobenzene 93.1 10/5/19 6:4170-130 Page 31 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-13 Field Sample #: MW-12 Sample Matrix: Ground Water Sampled: 10/1/2019 13:00 [TOC_2]19J0185-13[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS ND 5000 10/5/19 10:31 EEHg/L380 10/4/19SM21-22 6200B100Acetone 2300 50 10/5/19 10:31 EEHg/L18 10/4/19SM21-22 6200B100Benzene ND 50 10/5/19 10:31 EEHg/L15 10/4/19SM21-22 6200B100Bromobenzene ND 50 10/5/19 10:31 EEHg/L32 10/4/19SM21-22 6200B100Bromochloromethane ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B100Bromodichloromethane ND 50 10/5/19 10:31 EEHg/L46 10/4/19SM21-22 6200B100Bromoform ND 100 10/5/19 10:31 EEHg/L78 10/4/19SM21-22 6200B100Bromomethane ND 500 10/5/19 10:31 EEHg/L190 10/4/19SM21-22 6200B1002-Butanone (MEK) ND 50 10/5/19 10:31 EEHg/L21 10/4/19SM21-22 6200B100n-Butylbenzene ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B100sec-Butylbenzene ND 50 10/5/19 10:31 EEHg/L17 10/4/19SM21-22 6200B100tert-Butylbenzene ND 50 10/5/19 10:31 EEHg/L11 10/4/19SM21-22 6200B100Carbon Tetrachloride ND 50 10/5/19 10:31 EEHg/L15 10/4/19SM21-22 6200B100Chlorobenzene ND 5000 10/5/19 10:31 EEHg/L1100 10/4/19SM21-22 6200B100Ethanol ND 50 10/5/19 10:31 EEHg/L21 10/4/19SM21-22 6200B100Chlorodibromomethane ND 50 10/5/19 10:31 EEHg/L35 10/4/19SM21-22 6200B100Chloroethane ND 50 10/5/19 10:31 EEHg/L17 10/4/19SM21-22 6200B100Chloroform ND 100 10/5/19 10:31 EEHg/L45 10/4/19SM21-22 6200B100Chloromethane ND 50 10/5/19 10:31 EEHg/L12 10/4/19SM21-22 6200B1002-Chlorotoluene ND 50 10/5/19 10:31 EEHg/L14 10/4/19SM21-22 6200B1004-Chlorotoluene ND 50 10/5/19 10:31 EEHg/L19 10/4/19SM21-22 6200B1001,2-Dibromoethane (EDB) ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B1001,2-Dichlorobenzene ND 50 10/5/19 10:31 EEHg/L12 10/4/19SM21-22 6200B1001,3-Dichlorobenzene ND 50 10/5/19 10:31 EEHg/L13 10/4/19SM21-22 6200B1001,4-Dichlorobenzene ND 50 10/5/19 10:31 EEHg/L26 10/4/19SM21-22 6200B100Dichlorodifluoromethane (Freon 12) ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B1001,1-Dichloroethane ND 100 10/5/19 10:31 EEHg/L41 10/4/19SM21-22 6200B1001,2-Dichloroethane ND 50 10/5/19 10:31 EEHg/L32 10/4/19SM21-22 6200B1001,1-Dichloroethylene ND 50 10/5/19 10:31 EEHg/L13 10/4/19SM21-22 6200B100cis-1,2-Dichloroethylene ND 50 10/5/19 10:31 EEHg/L31 10/4/19SM21-22 6200B100trans-1,2-Dichloroethylene ND 50 10/5/19 10:31 EEHg/L20 10/4/19SM21-22 6200B1001,2-Dichloropropane ND 50 10/5/19 10:31 EEHg/L11 10/4/19SM21-22 6200B1001,3-Dichloropropane ND 50 10/5/19 10:31 EEHg/L20 10/4/19SM21-22 6200B1002,2-Dichloropropane ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B1001,1-Dichloropropene ND 50 10/5/19 10:31 EEHg/L13 10/4/19SM21-22 6200B100cis-1,3-Dichloropropene ND 50 10/5/19 10:31 EEHg/L23 10/4/19SM21-22 6200B100trans-1,3-Dichloropropene 180 50 10/5/19 10:31 EEHg/L17 10/4/19SM21-22 6200B100Diisopropyl Ether (DIPE) 540 50 10/5/19 10:31 EEHg/L13 10/4/19SM21-22 6200B100Ethylbenzene 460 500 10/5/19 10:31 EEHg/L150 10/4/19SM21-22 6200B100J2-Hexanone (MBK) 19 50 10/5/19 10:31 EEHg/L17 10/4/19SM21-22 6200B100JIsopropylbenzene (Cumene) ND 50 10/5/19 10:31 EEHg/L20 10/4/19SM21-22 6200B100p-Isopropyltoluene (p-Cymene) 1300 50 10/5/19 10:31 EEHg/L25 10/4/19SM21-22 6200B100Methyl tert-Butyl Ether (MTBE) ND 500 10/5/19 10:31 EEHg/L34 10/4/19SM21-22 6200B100Methylene Chloride 190 500 10/5/19 10:31 EEHg/L170 10/4/19SM21-22 6200B100J4-Methyl-2-pentanone (MIBK) Page 32 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 10/2/2019 Work Order: 19J0185Sample Description:Project Location: Chapel Hill, NC Sample ID: 19J0185-13 Field Sample #: MW-12 Sample Matrix: Ground Water Sampled: 10/1/2019 13:00 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Sample Flags: RL-11 Volatile Organic Compounds by GC/MS 450 500 10/5/19 10:31 EEHg/L31 10/4/19SM21-22 6200B100JNaphthalene 39 50 10/5/19 10:31 EEHg/L13 10/4/19SM21-22 6200B100Jn-Propylbenzene ND 50 10/5/19 10:31 EEHg/L11 10/4/19SM21-22 6200B100Styrene ND 50 10/5/19 10:31 EEHg/L22 10/4/19SM21-22 6200B1001,1,2,2-Tetrachloroethane ND 50 10/5/19 10:31 EEHg/L18 10/4/19SM21-22 6200B100Tetrachloroethylene 4600 50 10/5/19 10:31 EEHg/L14 10/4/19SM21-22 6200B100Toluene ND 200 10/5/19 10:31 EEHg/L57 10/4/19SM21-22 6200B1001,2,3-Trichlorobenzene ND 50 10/5/19 10:31 EEHg/L40 10/4/19SM21-22 6200B1001,2,4-Trichlorobenzene ND 50 10/5/19 10:31 EEHg/L20 10/4/19SM21-22 6200B1001,1,1-Trichloroethane ND 50 10/5/19 10:31 EEHg/L16 10/4/19SM21-22 6200B1001,1,2-Trichloroethane ND 50 10/5/19 10:31 EEHg/L24 10/4/19SM21-22 6200B100Trichloroethylene ND 50 10/5/19 10:31 EEHg/L33 10/4/19SM21-22 6200B100Trichlorofluoromethane (Freon 11) ND 50 10/5/19 10:31 EEHg/L25 10/4/19SM21-22 6200B1001,2,3-Trichloropropane 520 50 10/5/19 10:31 EEHg/L18 10/4/19SM21-22 6200B1001,2,4-Trimethylbenzene 190 50 10/5/19 10:31 EEHg/L14 10/4/19SM21-22 6200B1001,3,5-Trimethylbenzene ND 2000 10/5/19 10:31 EEHg/L1000 10/4/19SM21-22 6200B100Vinyl Acetate ND 50 10/5/19 10:31 EEHg/L45 10/4/19SM21-22 6200B100Vinyl Chloride 2500 100 10/5/19 10:31 EEHg/L30 10/4/19SM21-22 6200B100m+p Xylene 1100 50 10/5/19 10:31 EEHg/L17 10/4/19SM21-22 6200B100o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 92.6 10/5/19 10:3170-130 Toluene-d8 96.2 10/5/19 10:3170-130 4-Bromofluorobenzene 96.6 10/5/19 10:3170-130 Page 33 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: SW-846 5030B-SM21-22 6200B Lab Number [Field ID]Batch DateInitial [mL]Final [mL] B242256 10/04/195 5.0019J0185-02 [MW-1] B242256 10/04/195 5.0019J0185-03 [MW-2] B242256 10/04/190.01 5.0019J0185-04 [MW-3] B242256 10/04/190.5 5.0019J0185-05 [MW-4] B242256 10/04/195 5.0019J0185-06 [MW-5] B242256 10/04/195 5.0019J0185-07 [MW-6] B242256 10/04/195 5.0019J0185-08 [MW-7] B242256 10/04/195 5.0019J0185-09 [MW-8] B242256 10/04/195 5.0019J0185-10 [MW-9] B242256 10/04/195 5.0019J0185-11 [MW-10] B242256 10/04/195 5.0019J0185-12 [MW-11] B242256 10/04/190.05 5.0019J0185-13 [MW-12] Prep Method: SW-846 5030B-SM21-22 6200B Lab Number [Field ID]Batch DateInitial [mL]Final [mL] B242263 10/04/195 5.0019J0185-01 [Field Blank] [TOC_1]Sample Preparation Information[TOC] Page 34 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL [TOC_2]Volatile Organic Compounds by GC/MS[TOC] Batch B242256 - SW-846 5030B [TOC_3]B242256[TOC] Blank (B242256-BLK1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50ND Benzene g/L0.50ND Bromobenzene g/L0.50ND Bromochloromethane g/L0.50ND Bromodichloromethane g/L0.50ND Bromoform g/L0.50ND Bromomethane g/L1.0ND 2-Butanone (MEK)g/L5.0ND n-Butylbenzene g/L0.50ND sec-Butylbenzene g/L0.50ND tert-Butylbenzene g/L0.50ND Carbon Tetrachloride g/L0.50ND Chlorobenzene g/L0.50ND Ethanol g/L50ND Chlorodibromomethane g/L0.50ND Chloroethane g/L0.50ND Chloroform g/L0.50ND Chloromethane g/L0.60ND 2-Chlorotoluene g/L0.50ND 4-Chlorotoluene g/L0.50ND 1,2-Dibromoethane (EDB)g/L0.50ND 1,2-Dichlorobenzene g/L0.50ND 1,3-Dichlorobenzene g/L0.50ND 1,4-Dichlorobenzene g/L0.50ND Dichlorodifluoromethane (Freon 12)g/L0.50ND 1,1-Dichloroethane g/L0.50ND 1,2-Dichloroethane g/L0.50ND 1,1-Dichloroethylene g/L0.50ND cis-1,2-Dichloroethylene g/L0.50ND trans-1,2-Dichloroethylene g/L0.50ND 1,2-Dichloropropane g/L0.50ND 1,3-Dichloropropane g/L0.50ND 2,2-Dichloropropane g/L0.50ND 1,1-Dichloropropene g/L0.50ND cis-1,3-Dichloropropene g/L0.50ND trans-1,3-Dichloropropene g/L0.50ND Diisopropyl Ether (DIPE)g/L0.50ND Ethylbenzene g/L0.50ND 2-Hexanone (MBK)g/L5.0ND Isopropylbenzene (Cumene)g/L0.50ND p-Isopropyltoluene (p-Cymene)g/L0.50ND Methyl tert-Butyl Ether (MTBE)g/L0.50ND Methylene Chloride g/L5.0ND 4-Methyl-2-pentanone (MIBK)g/L5.0ND Naphthalene g/L0.50ND n-Propylbenzene g/L0.50ND Styrene g/L0.50ND 1,1,2,2-Tetrachloroethane g/L0.50ND Tetrachloroethylene g/L0.50ND Toluene g/L0.50ND 1,2,3-Trichlorobenzene g/L1.0ND 1,2,4-Trichlorobenzene g/L0.50ND [TOC_1]QC Data[TOC] Page 35 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242256 - SW-846 5030B Blank (B242256-BLK1) Prepared: 10/04/19 Analyzed: 10/05/19 1,1,1-Trichloroethane g/L0.50ND 1,1,2-Trichloroethane g/L0.50ND Trichloroethylene g/L0.50ND Trichlorofluoromethane (Freon 11)g/L0.50ND 1,2,3-Trichloropropane g/L0.50ND 1,2,4-Trimethylbenzene g/L0.50ND 1,3,5-Trimethylbenzene g/L0.50ND Vinyl Acetate g/L20ND Vinyl Chloride g/L0.50ND m+p Xylene g/L1.0ND o-Xylene g/L0.50ND g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.224.1 g/L 25.0 70-130Surrogate: Toluene-d8 97.624.4 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 85.121.3 LCS (B242256-BS1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50 100 70-13084.084.0 Benzene g/L0.50 10.0 70-13081.28.12 Bromobenzene g/L0.50 10.0 70-13010710.7 Bromochloromethane g/L0.50 10.0 70-13094.89.48 Bromodichloromethane g/L0.50 10.0 70-13010410.4 Bromoform g/L0.50 10.0 70-13011611.6 Bromomethane g/L1.0 10.0 60-14060.36.03 2-Butanone (MEK)g/L5.0 100 70-13081.381.3 n-Butylbenzene g/L0.50 10.0 70-13010810.8 sec-Butylbenzene g/L0.50 10.0 70-13011111.1 tert-Butylbenzene g/L0.50 10.0 70-13010610.6 Carbon Tetrachloride g/L0.50 10.0 70-13096.09.60 Chlorobenzene g/L0.50 10.0 70-13010710.7 Ethanol g/L50 100 70-130130130 Chlorodibromomethane g/L0.50 10.0 70-13099.59.95 Chloroethane g/L0.50 10.0 60-14078.57.85 Chloroform g/L0.50 10.0 70-13085.28.52 Chloromethane g/L0.60 10.0 60-14072.47.24 2-Chlorotoluene g/L0.50 10.0 70-13010110.1 4-Chlorotoluene g/L0.50 10.0 70-13011311.3 1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13097.99.79 1,2-Dichlorobenzene g/L0.50 10.0 70-13010710.7 1,3-Dichlorobenzene g/L0.50 10.0 70-13011011.0 1,4-Dichlorobenzene g/L0.50 10.0 70-13010710.7 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14074.47.44 1,1-Dichloroethane g/L0.50 10.0 70-13089.98.99 1,2-Dichloroethane g/L0.50 10.0 70-13010110.1 1,1-Dichloroethylene g/L0.50 10.0 70-13083.38.33 cis-1,2-Dichloroethylene g/L0.50 10.0 70-13089.58.95 trans-1,2-Dichloroethylene g/L0.50 10.0 70-13091.89.18 1,2-Dichloropropane g/L0.50 10.0 70-13095.49.54 1,3-Dichloropropane g/L0.50 10.0 70-13091.89.18 2,2-Dichloropropane g/L0.50 10.0 70-13074.97.49 1,1-Dichloropropene g/L0.50 10.0 70-13084.58.45 cis-1,3-Dichloropropene g/L0.50 10.0 70-13094.69.46 trans-1,3-Dichloropropene g/L0.50 10.0 70-13090.19.01 Page 36 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242256 - SW-846 5030B LCS (B242256-BS1) Prepared: 10/04/19 Analyzed: 10/05/19 Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13098.89.88 Ethylbenzene g/L0.50 10.0 70-13011011.0 2-Hexanone (MBK)g/L5.0 100 70-130103103 Isopropylbenzene (Cumene)g/L0.50 10.0 70-13011111.1 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13010310.3 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13071.87.18 Methylene Chloride g/L5.0 10.0 70-13089.68.96 4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-130109109 Naphthalene g/L0.50 10.0 70-13010310.3 n-Propylbenzene g/L0.50 10.0 70-13011111.1 Styrene g/L0.50 10.0 70-13095.89.58 1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13011411.4 Tetrachloroethylene g/L0.50 10.0 70-13010510.5 Toluene g/L0.50 10.0 70-13096.99.69 1,2,3-Trichlorobenzene g/L1.0 10.0 70-13012112.1 1,2,4-Trichlorobenzene g/L0.50 10.0 70-13011711.7 1,1,1-Trichloroethane g/L0.50 10.0 70-13094.09.40 1,1,2-Trichloroethane g/L0.50 10.0 70-13093.99.39 Trichloroethylene g/L0.50 10.0 70-13097.39.73 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13076.27.62 1,2,3-Trichloropropane g/L0.50 10.0 70-13010410.4 1,2,4-Trimethylbenzene g/L0.50 10.0 70-13092.39.23 1,3,5-Trimethylbenzene g/L0.50 10.0 70-13011011.0 Vinyl Acetate g/L20 100 70-13086.286.2 Vinyl Chloride g/L0.50 10.0 L-0260-140286*28.6 m+p Xylene g/L1.0 20.0 70-13010921.8 o-Xylene g/L0.50 10.0 70-13011411.4 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.423.8 g/L 25.0 70-130Surrogate: Toluene-d8 97.424.4 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10125.2 LCS Dup (B242256-BSD1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50 100 2570-13085.8 2.0785.8 Benzene g/L0.50 10.0 2570-13081.7 0.6148.17 Bromobenzene g/L0.50 10.0 2570-130105 1.9710.5 Bromochloromethane g/L0.50 10.0 2570-13095.5 0.7369.55 Bromodichloromethane g/L0.50 10.0 2570-130103 0.29010.3 Bromoform g/L0.50 10.0 2570-130116 0.0011.6 Bromomethane g/L1.0 10.0 2560-14063.0 4.386.30 2-Butanone (MEK)g/L5.0 100 2570-13083.1 2.1883.1 n-Butylbenzene g/L0.50 10.0 2570-130108 0.0010.8 sec-Butylbenzene g/L0.50 10.0 2570-130112 0.62911.2 tert-Butylbenzene g/L0.50 10.0 2570-130106 0.47210.6 Carbon Tetrachloride g/L0.50 10.0 2570-13093.9 2.219.39 Chlorobenzene g/L0.50 10.0 2570-130106 1.1210.6 Ethanol g/L50 100 2570-130127 1.78127 Chlorodibromomethane g/L0.50 10.0 2570-13092.8 6.979.28 Chloroethane g/L0.50 10.0 2560-14087.3 10.68.73 Chloroform g/L0.50 10.0 2570-13084.1 1.308.41 Chloromethane g/L0.60 10.0 2560-14075.2 3.797.52 2-Chlorotoluene g/L0.50 10.0 2570-13099.6 1.109.96 4-Chlorotoluene g/L0.50 10.0 2570-130110 2.2511.0 Page 37 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242256 - SW-846 5030B LCS Dup (B242256-BSD1) Prepared: 10/04/19 Analyzed: 10/05/19 1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13089.3 9.198.93 1,2-Dichlorobenzene g/L0.50 10.0 2570-130105 1.9810.5 1,3-Dichlorobenzene g/L0.50 10.0 2570-130111 1.3611.1 1,4-Dichlorobenzene g/L0.50 10.0 2570-130105 1.6910.5 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14073.2 1.637.32 1,1-Dichloroethane g/L0.50 10.0 2570-13088.3 1.808.83 1,2-Dichloroethane g/L0.50 10.0 2570-13098.6 2.409.86 1,1-Dichloroethylene g/L0.50 10.0 2570-13087.6 5.038.76 cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13091.1 1.779.11 trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13090.0 1.989.00 1,2-Dichloropropane g/L0.50 10.0 2570-13094.9 0.5259.49 1,3-Dichloropropane g/L0.50 10.0 2570-13083.2 9.838.32 2,2-Dichloropropane g/L0.50 10.0 2570-13073.2 2.307.32 1,1-Dichloropropene g/L0.50 10.0 2570-13088.1 4.178.81 cis-1,3-Dichloropropene g/L0.50 10.0 2570-13092.5 2.249.25 trans-1,3-Dichloropropene g/L0.50 10.0 2570-13083.0 8.208.30 Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13098.4 0.4069.84 Ethylbenzene g/L0.50 10.0 2570-130109 0.82310.9 2-Hexanone (MBK)g/L5.0 100 2570-13092.4 10.892.4 Isopropylbenzene (Cumene)g/L0.50 10.0 2570-130112 0.44811.2 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-130105 1.5410.5 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13073.0 1.667.30 Methylene Chloride g/L5.0 10.0 2570-13092.8 3.519.28 4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-130110 0.947110 Naphthalene g/L0.50 10.0 2570-13097.2 5.899.72 n-Propylbenzene g/L0.50 10.0 2570-130109 2.1810.9 Styrene g/L0.50 10.0 2570-13093.6 2.329.36 1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130109 4.3010.9 Tetrachloroethylene g/L0.50 10.0 2570-13099.2 5.879.92 Toluene g/L0.50 10.0 2570-13087.3 10.48.73 1,2,3-Trichlorobenzene g/L1.0 10.0 2570-130108 11.110.8 1,2,4-Trichlorobenzene g/L0.50 10.0 2570-130117 0.42811.7 1,1,1-Trichloroethane g/L0.50 10.0 2570-13094.2 0.2139.42 1,1,2-Trichloroethane g/L0.50 10.0 2570-13088.9 5.478.89 Trichloroethylene g/L0.50 10.0 2570-13099.3 2.039.93 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13077.2 1.307.72 1,2,3-Trichloropropane g/L0.50 10.0 2570-130105 0.95710.5 1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13094.0 1.839.40 1,3,5-Trimethylbenzene g/L0.50 10.0 2570-130108 1.3810.8 Vinyl Acetate g/L20 100 2570-13087.9 2.0187.9 Vinyl Chloride g/L0.50 10.0 25 L-0260-140306 6.70*30.6 m+p Xylene g/L1.0 20.0 2570-130108 1.1121.6 o-Xylene g/L0.50 10.0 2570-130110 3.8411.0 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.024.0 g/L 25.0 70-130Surrogate: Toluene-d8 88.722.2 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.824.7 Page 38 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242263 - SW-846 5030B [TOC_3]B242263[TOC] Blank (B242263-BLK1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50ND Benzene g/L0.50ND Bromobenzene g/L0.50ND Bromochloromethane g/L0.50ND Bromodichloromethane g/L0.50ND Bromoform g/L0.50ND Bromomethane g/L1.0ND 2-Butanone (MEK)g/L5.0ND n-Butylbenzene g/L0.50ND sec-Butylbenzene g/L0.50ND tert-Butylbenzene g/L0.50ND Carbon Tetrachloride g/L0.50ND Chlorobenzene g/L0.50ND Ethanol g/L50ND Chlorodibromomethane g/L0.50ND Chloroethane g/L0.50ND Chloroform g/L0.50ND Chloromethane g/L0.60ND 2-Chlorotoluene g/L0.50ND 4-Chlorotoluene g/L0.50ND 1,2-Dibromoethane (EDB)g/L0.50ND 1,2-Dichlorobenzene g/L0.50ND 1,3-Dichlorobenzene g/L0.50ND 1,4-Dichlorobenzene g/L0.50ND Dichlorodifluoromethane (Freon 12)g/L0.50ND 1,1-Dichloroethane g/L0.50ND 1,2-Dichloroethane g/L0.50ND 1,1-Dichloroethylene g/L0.50ND cis-1,2-Dichloroethylene g/L0.50ND trans-1,2-Dichloroethylene g/L0.50ND 1,2-Dichloropropane g/L0.50ND 1,3-Dichloropropane g/L0.50ND 2,2-Dichloropropane g/L0.50ND 1,1-Dichloropropene g/L0.50ND cis-1,3-Dichloropropene g/L0.50ND trans-1,3-Dichloropropene g/L0.50ND Diisopropyl Ether (DIPE)g/L0.50ND Ethylbenzene g/L0.50ND 2-Hexanone (MBK)g/L5.0ND Isopropylbenzene (Cumene)g/L0.50ND p-Isopropyltoluene (p-Cymene)g/L0.50ND Methyl tert-Butyl Ether (MTBE)g/L0.50ND Methylene Chloride g/L5.0ND 4-Methyl-2-pentanone (MIBK)g/L5.0ND Naphthalene g/L0.50ND n-Propylbenzene g/L0.50ND Styrene g/L0.50ND 1,1,2,2-Tetrachloroethane g/L0.50ND Tetrachloroethylene g/L0.50ND Toluene g/L0.50ND 1,2,3-Trichlorobenzene g/L1.0ND 1,2,4-Trichlorobenzene g/L0.50ND Page 39 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242263 - SW-846 5030B Blank (B242263-BLK1) Prepared: 10/04/19 Analyzed: 10/05/19 1,1,1-Trichloroethane g/L0.50ND 1,1,2-Trichloroethane g/L0.50ND Trichloroethylene g/L0.50ND Trichlorofluoromethane (Freon 11)g/L0.50ND 1,2,3-Trichloropropane g/L0.50ND 1,2,4-Trimethylbenzene g/L0.50ND 1,3,5-Trimethylbenzene g/L0.50ND Vinyl Acetate g/L20ND Vinyl Chloride g/L0.50ND m+p Xylene g/L1.0ND o-Xylene g/L0.50ND g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10325.8 g/L 25.0 70-130Surrogate: Toluene-d8 98.924.7 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.324.1 LCS (B242263-BS1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50 200 70-13096.8194 Benzene g/L0.50 20.0 70-13010821.6 Bromobenzene g/L0.50 20.0 70-13010420.9 Bromochloromethane g/L0.50 20.0 70-13011122.3 Bromodichloromethane g/L0.50 20.0 70-13010721.4 Bromoform g/L0.50 20.0 70-13010120.1 Bromomethane g/L1.0 20.0 60-14082.916.6 2-Butanone (MEK)g/L5.0 200 70-13095.6191 n-Butylbenzene g/L0.50 20.0 70-13010320.7 sec-Butylbenzene g/L0.50 20.0 70-13011222.4 tert-Butylbenzene g/L0.50 20.0 70-13011022.0 Carbon Tetrachloride g/L0.50 20.0 70-13010420.7 Chlorobenzene g/L0.50 20.0 70-13011222.4 Ethanol g/L50 200 70-130110220 Chlorodibromomethane g/L0.50 20.0 70-13010120.2 Chloroethane g/L0.50 20.0 60-14010921.8 Chloroform g/L0.50 20.0 70-13010821.6 Chloromethane g/L0.60 20.0 60-14092.318.5 2-Chlorotoluene g/L0.50 20.0 70-13010821.6 4-Chlorotoluene g/L0.50 20.0 70-13010721.3 1,2-Dibromoethane (EDB)g/L0.50 20.0 70-13010921.8 1,2-Dichlorobenzene g/L0.50 20.0 70-13011222.4 1,3-Dichlorobenzene g/L0.50 20.0 70-13011723.3 1,4-Dichlorobenzene g/L0.50 20.0 70-13011122.2 Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 60-14078.715.7 1,1-Dichloroethane g/L0.50 20.0 70-13010921.8 1,2-Dichloroethane g/L0.50 20.0 70-13010420.8 1,1-Dichloroethylene g/L0.50 20.0 70-13011122.3 cis-1,2-Dichloroethylene g/L0.50 20.0 70-13010621.3 trans-1,2-Dichloroethylene g/L0.50 20.0 70-13010621.3 1,2-Dichloropropane g/L0.50 20.0 70-13010921.8 1,3-Dichloropropane g/L0.50 20.0 70-13010521.0 2,2-Dichloropropane g/L0.50 20.0 70-13082.816.6 1,1-Dichloropropene g/L0.50 20.0 70-13010821.7 cis-1,3-Dichloropropene g/L0.50 20.0 70-13010120.3 trans-1,3-Dichloropropene g/L0.50 20.0 70-13097.419.5 Page 40 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242263 - SW-846 5030B LCS (B242263-BS1) Prepared: 10/04/19 Analyzed: 10/05/19 Diisopropyl Ether (DIPE)g/L0.50 20.0 70-13010420.8 Ethylbenzene g/L0.50 20.0 70-13010821.7 2-Hexanone (MBK)g/L5.0 200 70-13091.2182 Isopropylbenzene (Cumene)g/L0.50 20.0 70-13010921.9 p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 70-13010621.1 Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 70-13010420.8 Methylene Chloride g/L5.0 20.0 70-13011122.2 4-Methyl-2-pentanone (MIBK)g/L5.0 200 70-13092.4185 Naphthalene g/L0.50 20.0 70-13082.416.5 n-Propylbenzene g/L0.50 20.0 70-13010621.3 Styrene g/L0.50 20.0 70-13010721.3 1,1,2,2-Tetrachloroethane g/L0.50 20.0 70-13011623.2 Tetrachloroethylene g/L0.50 20.0 70-13010821.5 Toluene g/L0.50 20.0 70-13010721.4 1,2,3-Trichlorobenzene g/L1.0 20.0 70-13081.416.3 1,2,4-Trichlorobenzene g/L0.50 20.0 70-13088.417.7 1,1,1-Trichloroethane g/L0.50 20.0 70-13010621.2 1,1,2-Trichloroethane g/L0.50 20.0 70-13011122.2 Trichloroethylene g/L0.50 20.0 70-13011222.3 Trichlorofluoromethane (Freon 11)g/L0.50 20.0 70-13096.519.3 1,2,3-Trichloropropane g/L0.50 20.0 70-13011122.2 1,2,4-Trimethylbenzene g/L0.50 20.0 70-13010821.6 1,3,5-Trimethylbenzene g/L0.50 20.0 70-13010220.3 Vinyl Acetate g/L20 200 70-13081.0162 Vinyl Chloride g/L0.50 20.0 60-14098.919.8 m+p Xylene g/L1.0 40.0 70-13010843.2 o-Xylene g/L0.50 20.0 70-13011122.1 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.324.8 g/L 25.0 70-130Surrogate: Toluene-d8 99.224.8 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.824.7 LCS Dup (B242263-BSD1) Prepared: 10/04/19 Analyzed: 10/05/19 Acetone g/L50 200 2570-130102 5.21204 Benzene g/L0.50 20.0 2570-130106 1.7321.2 Bromobenzene g/L0.50 20.0 2570-130104 0.57720.8 Bromochloromethane g/L0.50 20.0 2570-130111 0.27022.2 Bromodichloromethane g/L0.50 20.0 2570-130104 2.4620.9 Bromoform g/L0.50 20.0 2570-13099.8 0.84820.0 Bromomethane g/L1.0 20.0 2560-14090.4 8.6618.1 2-Butanone (MEK)g/L5.0 200 2570-130100 4.47200 n-Butylbenzene g/L0.50 20.0 2570-130103 0.048320.7 sec-Butylbenzene g/L0.50 20.0 2570-130110 1.8522.0 tert-Butylbenzene g/L0.50 20.0 2570-130106 3.6121.2 Carbon Tetrachloride g/L0.50 20.0 2570-13098.0 5.6519.6 Chlorobenzene g/L0.50 20.0 2570-130110 2.2121.9 Ethanol g/L50 200 2570-130120 8.99241 Chlorodibromomethane g/L0.50 20.0 2570-130101 0.44520.3 Chloroethane g/L0.50 20.0 2560-140108 0.78421.6 Chloroform g/L0.50 20.0 2570-130104 3.5320.9 Chloromethane g/L0.60 20.0 2560-14090.8 1.6418.2 2-Chlorotoluene g/L0.50 20.0 2570-130104 3.5320.9 4-Chlorotoluene g/L0.50 20.0 2570-130102 4.2620.4 Page 41 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B242263 - SW-846 5030B LCS Dup (B242263-BSD1) Prepared: 10/04/19 Analyzed: 10/05/19 1,2-Dibromoethane (EDB)g/L0.50 20.0 2570-130108 0.87721.6 1,2-Dichlorobenzene g/L0.50 20.0 2570-130109 2.9421.8 1,3-Dichlorobenzene g/L0.50 20.0 2570-130114 2.3922.8 1,4-Dichlorobenzene g/L0.50 20.0 2570-130105 5.2821.0 Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 2560-14073.9 6.2914.8 1,1-Dichloroethane g/L0.50 20.0 2570-130106 3.1221.1 1,2-Dichloroethane g/L0.50 20.0 2570-130104 0.38620.7 1,1-Dichloroethylene g/L0.50 20.0 2570-130107 3.9421.4 cis-1,2-Dichloroethylene g/L0.50 20.0 2570-130103 3.1520.6 trans-1,2-Dichloroethylene g/L0.50 20.0 2570-130103 3.4920.5 1,2-Dichloropropane g/L0.50 20.0 2570-130104 4.2220.9 1,3-Dichloropropane g/L0.50 20.0 2570-130105 0.14221.1 2,2-Dichloropropane g/L0.50 20.0 2570-13077.4 6.8015.5 1,1-Dichloropropene g/L0.50 20.0 2570-130104 4.2920.8 cis-1,3-Dichloropropene g/L0.50 20.0 2570-13099.3 1.9919.9 trans-1,3-Dichloropropene g/L0.50 20.0 2570-13096.0 1.4019.2 Diisopropyl Ether (DIPE)g/L0.50 20.0 2570-130102 2.2820.4 Ethylbenzene g/L0.50 20.0 2570-130107 1.3921.4 2-Hexanone (MBK)g/L5.0 200 2570-13099.3 8.52199 Isopropylbenzene (Cumene)g/L0.50 20.0 2570-130105 4.0121.0 p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 2570-130104 2.0120.7 Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 2570-130105 0.86420.9 Methylene Chloride g/L5.0 20.0 2570-130110 1.2721.9 4-Methyl-2-pentanone (MIBK)g/L5.0 200 2570-13098.2 6.07196 Naphthalene g/L0.50 20.0 2570-13087.2 5.7217.4 n-Propylbenzene g/L0.50 20.0 2570-130103 3.0120.6 Styrene g/L0.50 20.0 2570-130105 1.3721.0 1,1,2,2-Tetrachloroethane g/L0.50 20.0 2570-130118 1.7123.6 Tetrachloroethylene g/L0.50 20.0 2570-130107 0.69921.4 Toluene g/L0.50 20.0 2570-130105 2.0721.0 1,2,3-Trichlorobenzene g/L1.0 20.0 2570-13080.5 1.1116.1 1,2,4-Trichlorobenzene g/L0.50 20.0 2570-13088.6 0.28217.7 1,1,1-Trichloroethane g/L0.50 20.0 2570-130102 4.1820.4 1,1,2-Trichloroethane g/L0.50 20.0 2570-130110 1.4021.9 Trichloroethylene g/L0.50 20.0 2570-130108 2.8221.7 Trichlorofluoromethane (Freon 11)g/L0.50 20.0 2570-13089.4 7.6917.9 1,2,3-Trichloropropane g/L0.50 20.0 2570-130107 3.6321.4 1,2,4-Trimethylbenzene g/L0.50 20.0 2570-130105 2.5421.0 1,3,5-Trimethylbenzene g/L0.50 20.0 2570-130101 1.0920.1 Vinyl Acetate g/L20 200 2570-13080.5 0.601161 Vinyl Chloride g/L0.50 20.0 2560-14093.4 5.7718.7 m+p Xylene g/L1.0 40.0 2570-130103 4.2841.4 o-Xylene g/L0.50 20.0 2570-130109 1.5521.8 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10025.0 g/L 25.0 70-130Surrogate: Toluene-d8 10125.2 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 97.724.4 Page 42 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. No results have been blank subtracted unless specified in the case narrative section. FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is on the high side. L-02 Elevated reporting limit due to high concentration of target compounds.RL-11 [TOC_1]Flag/Qualifier Summary[TOC] Page 43 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-22 6200B in Water NCAcetone NCBenzene NCBromobenzene NCBromochloromethane NCBromodichloromethane NCBromoform NCBromomethane NC2-Butanone (MEK) NCn-Butylbenzene NCsec-Butylbenzene NCtert-Butylbenzene NCCarbon Tetrachloride NCChlorobenzene NCEthanol NCChlorodibromomethane NCChloroethane NCChloroform NCChloromethane NC2-Chlorotoluene NC4-Chlorotoluene NC1,2-Dibromoethane (EDB) NC1,2-Dichlorobenzene NC1,3-Dichlorobenzene NC1,4-Dichlorobenzene NCDichlorodifluoromethane (Freon 12) NC1,1-Dichloroethane NC1,2-Dichloroethane NC1,1-Dichloroethylene NCcis-1,2-Dichloroethylene NCtrans-1,2-Dichloroethylene NC1,2-Dichloropropane NC1,3-Dichloropropane NC2,2-Dichloropropane NC1,1-Dichloropropene NCcis-1,3-Dichloropropene NCtrans-1,3-Dichloropropene NCDiisopropyl Ether (DIPE) NCEthylbenzene NC2-Hexanone (MBK) NCIsopropylbenzene (Cumene) NCp-Isopropyltoluene (p-Cymene) NCMethyl tert-Butyl Ether (MTBE) NCMethylene Chloride NC4-Methyl-2-pentanone (MIBK) NCNaphthalene NCn-Propylbenzene NCStyrene [TOC_1]Certifications[TOC] Page 44 of 49 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-22 6200B in Water NC1,1,2,2-Tetrachloroethane NCTetrachloroethylene NCToluene NC1,2,3-Trichlorobenzene NC1,2,4-Trichlorobenzene NC1,1,1-Trichloroethane NC1,1,2-Trichloroethane NCTrichloroethylene NCTrichlorofluoromethane (Freon 11) NC1,2,3-Trichloropropane NC1,2,4-Trimethylbenzene NC1,3,5-Trimethylbenzene NCVinyl Acetate NCVinyl Chloride NCm+p Xylene NCo-Xylene The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2020 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2019 652North Carolina Div. of Water QualityNC 12/31/2019 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2019 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 45 of 49 Table of Contents Page 46 of 49 Table of Contents Page 47 of 49 Table of Contents Page 48 of 49 Table of Contents Page 49 of 49 Table of Contents APPENDIX F 4505 Falls of Neuse Rd Page: 1 Suite 400 Raleigh, NC 27609 Project: Date: 10-03-19 (919) 783-9214 (919) 783-9266 Fax Project No.: Crew:MK MW NAME Northing Easting Top PVC Elev MW-3 763045.905 1972875.066 X MW-4 763043.818 1972945.439 X MW-8 763183.987 1972768.57 X MW-9 762927.657 1972914.256 553.57 MW-10 762927.791 1972796.236 558.02 MW-11 763074.066 1972782.322 553.86 MW-12 763044.858 1972953.359 551.76 Monitoring Well Sheet Petro Mart #4 HORIZONTAL AND VERTICAL CONTROL BASED ON KCI GPS 11455 NC Highway 15/501 North, Chapel Hill, NC Top Lid Ground Elev X 554.18 552.04 552.18 554.18 551.98 554.11 558.78 553.12 551.96 X X 554.09 558.63