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HomeMy WebLinkAboutMO-28622_47861_CA_MRP_20231004_LSA CES Group Engineers, LLP IMPROVING. PROTECTING. RESTORING. CHARLOTTE, NC 3525 Whitehall Park Drive, Suite 150 Charlotte, NC 28273 COLUMBIA, SC 1411 Gervais Street, Suite 140 Columbia, SC 29201 www.ces-group.net October 4, 2023 Scott Ryals, PE Environmental Engineer North Carolina Department of Environmental Quality DWM UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 RE: Phase I Limited Site Assessment Mountain Village Pantry Incident No.: 47861 UST ID No.: MO-28622 Facility ID No.: 00-0-0000015758 2302 Dallas Cherryville Highway Dallas, Gaston County, North Carolina 28034 Dear Mr. Ryals: CES Group Engineers, LLP (CES), while under contract with the North Carolina Department of Environmental Quality (NCDEQ), Contract No.: N042023, executed on February 24, 2023, is submitting this Phase I Limited Site Assessment to you for the above referenced property, via email transmission. The performed work was authorized by NCDEQ Task Authorization (TA) #01, approved on June 16, 2023. Should you have any questions in regards to this submittal, please do not hesitate to contact me at (704) 325-5408. Regards, Greg Hans, PMP Environmental Division Manager Enclosures: Phase I Limited Site Assessment CES Project No. 8173.0623E 1 October 4, 2023 PHASE I LIMITED SITE ASSESSMENT REPORT Mountain Village Pantry 2302 Dallas Cherryville Highway Dallas, Gaston County, North Carolina 28034 NCDEQ Incident No.: 47861 UST ID No.: MO-28622 Facility ID No.: 00-0-0000015758 October 4, 2023 Prepared for: Mr. Scott Ryals NCDEQ DWM UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Prepared by: CES Group Engineers, LLP 3525 Whitehall Park Drive, Suite 150 Charlotte, North Carolina 28273 CES Project No. 8173.0623E 2 October 4, 2023 TABLE OF CONTENTS Page 1.0 SITE INFORMATION ................................................................................................. 4 1.1 Site Identification............................................................................................. 4 1.2 Contact Information ......................................................................................... 4 1.3 Release Information ........................................................................................ 4 1.4 Certification ..................................................................................................... 5 2.0 EXECUTIVE SUMMARY ............................................................................................ 6 3.0 SITE HISTORY AND CHARACTERIZATION ............................................................. 9 3.1 Responsible Party Information ........................................................................ 9 3.2 UST Information ............................................................................................ 10 3.3 AST Information ............................................................................................ 10 3.4 Release Description ...................................................................................... 10 3.5 Site Characteristics ....................................................................................... 10 3.6 Prior Actions ................................................................................................. 11 4.0 RISK CHARACTERIZATION .................................................................................... 12 4.1 Part I – Groundwater/Surface Water/Vapor Impacts ..................................... 12 4.2 Part II – Land Use ......................................................................................... 13 5.0 RECEPTOR INFORMATION .................................................................................... 16 5.1 Water Supply Wells ....................................................................................... 16 5.2 Public Water Supplies ................................................................................... 16 5.3 Surface Water ............................................................................................... 16 5.4 Wellhead Protection Areas ............................................................................ 17 5.5 Deep Aquifers in the Coastal Plain Physiographic Region ............................ 17 5.6 Subsurface Structures .................................................................................. 17 6.0 LAND USE ............................................................................................................... 18 6.1 Property Owners and Occupants .................................................................. 18 7.0 SITE GEOLOGY AND HYDROGEOLOGY ............................................................... 19 8.0 SAMPLING RESULTS ............................................................................................. 20 8.1 Phase I Investigation ..................................................................................... 20 9.0 CONCLUSIONS AND RECOMMENDATIONS ......................................................... 23 9.1 Conclusions and Recommendations ............................................................. 23 10.0 REFERENCES ......................................................................................................... 24 CES Project No. 8173.0623E 3 October 4, 2023 FIGURES FIGURE 1 SITE LOCATION MAP FIGURE 2 SITE MAP FIGURE 3 ESTIMATED EXTENT OF SOIL CONTAMINATION MAP FIGURE 4 GROUNDWATER ELEVATION AND ESTIMATED EXTENT OF CONTAMINATION MAP FIGURE 5 POTENTIAL RECEPTOR AND LAND USE MAP FIGURE 6 PROPOSED MONITORING WELL LOCATION MAP TABLES TABLE B-1 SITE HISTORY – UST/AST SYSTEM AND OTHER RELEASE INFORMATION TABLE B-2 SITE HISTORY – UST/AST OWNER/OPERATOR AND OTHER RESPONSIBLE PARTY INFORMATION TABLE B-3 SUMMARY OF SOIL ANALYTICAL RESULTS TABLE B-4 GROUNDWATER ANALYTICAL RESULTS TABLE B-5 PUBLIC AND PRIVATE WATER SUPPLY WELL AND OTHER RECEPTOR INFORMATION TABLE B-6 CONTIGUOUS PROPERTY OWNERS/OCCUPANTS TABLE B-7 MONITORING WELL CONSTRUCTION INFORMATION TABLE B-9 CURRENT GROUNDWATER ELEVATIONS APPENDICES APPENDIX A HISTORICAL DATA APPENDIX B SITE PHOTOGRAPHS APPENDIX C MONITORING FIELD DATA SHEETS, SAMPLING PROTOCOLS, JOB HAZARD ANALYSIS, AND HEALTH & SAFETY PLAN APPENDIX D SOIL AND GROUNDWATER LABORATORY REPORTS AND CHAIN-OF- CUSTODY RECORDS APPENDIX E SOIL BORING LOG, MONITORING WELL CONSTRUCTION FORM AND NCDEQ WELL PERMIT CES Project No. 8173.0623E 4 October 4, 2023 1.0 SITE INFORMATION 1.1 Site Identification Date of Report: October 4, 2023 Site Risk/Ranking: Low Facility I.D.:00-0-0000015758 UST Incident Number (if known): MO-28622 / 47861 Site Name: Mountain Village Pantry Street Address:2302 Dallas Cherryville Highway City/Town:Dallas Zip Code: 28034 County: Gaston Description of Geographical Data Point (e.g., MW):MW-1 Location Method (GPS, topographical map, online map, other):GIS Address Matching Latitude (decimal degrees):35.31986 Longitude (decimal degrees): -81.21742 1.2 Contact Information UST/AST Owner: Dustin Smithers Email: sitesolutions4800@gmail.com Address: 2302 Dallas Cherryville Highway, Dallas, NC 28034 Tel: 704-400-2800 UST/AST Operator: Dustin Smithers Email: sitesolutions4800@gmail.com Address: 2302 Dallas Cherryville Highway, Dallas, NC 28034 Tel: 704-400-2800 Property Owner: Dustin Smithers Email: sitesolutions4800@gmail.com Address: 2302 Dallas Cherryville Highway, Dallas, NC 28034 Tel: 704-400-2800 Property Occupant: Unnamed Landscape / Grading Business Email: sitesolutions4800@gmail.com Address: 2302 Dallas Cherryville Highway, Dallas, NC 28034 Tel: 704-400-2800 Consultant/Contractor: CES Group Engineers, LLP. Email: ghans@ces-group.net Address: 3525 Whitehall Park Drive, Ste150, Charlotte, NC 28273 Tel: 704-325-5408 Analytical Laboratory: Waypoint Analytical State Certification No: 402 Address: 449 Springbrook Road, Charlotte, NC 28217 Tel: 704-529-6364 Drilling Contractor: Carolina Soil Investigations Email: keith@csieco.com Address: 132 Gurney Road, Olin, NC 28660 Tel: 704-539-5279 1.3 Release Information Date Discovered: 6/11/2021 (According to available historical site records) Estimated Quantity of Release: Unknown Cause of Release: Unknown Source of Release (e.g., Dispenser/Piping/UST):USTs/Dispenser/Piping Sizes and Contents of Tanks or Other Containment from which the Release Occurred:  Two 6,000-gal gasoline USTs; One 4,000-gal diesel UST CES Project No. 8173.0623E 5 October 4, 2023 1.4 Certification I, Charles D. Heleine, a North Carolina Licensed Professional Engineer employed by CES, do certify that the information contained in this report is accurate, to the best of my knowledge. E-Signature 10/03/2023 Charles D. Heleine, NC PE No. 27196 CES Group Engineers, LLP (CES) is licensed to practice engineering in North Carolina. The firm license number is F-1240. CES Project No. 8173.0623E 6 October 4, 2023 2.0 EXECUTIVE SUMMARY The purpose of this Phase I Limited Site Assessment (LSA) is to provide the information necessary for the North Carolina Department of Environmental Quality (NCDEQ) to evaluate the level of risk to human health and the environment resulting from the apparent release of petroleum-related constituents from the historical operation of an underground storage tank (UST or tank) system (removed in June, 2021), located at Mountain Village Pantry, 2302 Dallas Cherryville Highway, Gaston County, North Carolina (hereafter identified as the site, subject site, subject property or property). The site location, including topographic features, is depicted on Figure 1. CES Group Engineers, LLP (CES) has been authorized to perform this LSA by NCDEQ, represented by Scott Ryals, PE, Environmental Engineer. A Phase I LSA of the subject property was completed by CES to evaluate if soil and groundwater has been impacted at the site by the apparent release condition, and if the potential exists for nearby water supply wells and/or other receptors to be impacted. As reported in an UST Closure Report, dated September 7, 2021, prepared by Paragon Environmental Consultants, Inc (Paragon), of Thomasville, North Carolina, during the removal of two 6,000-gallon gasoline USTs and one 4,000-gallon diesel UST from the site in June, 2021, a total of twelve soil samples collected from underneath the former dispenser island, product piping and USTs reported total petroleum hydrocarbons (TPH) diesel range organics (DRO) and/or gasoline range organics (GRO) above NCDEQ Initial Action Levels for Contamination. During the removal of the three USTs in June, 2021, it was reported that no over-excavation of contaminated soils occurred, and soils excavated to safely remove the UST system were returned to the open excavated area without the completion of any additional backfilling to fill the open excavated hole to grade. Based on the reported concentration levels of TPH from the area of the former dispenser island, product piping and USTS, NCDEQ subsequently issued Incident Number 47861 for the apparent release condition to Dustin Smithers in June, 2021. Since the completion of the UST system removal in June, 2021, no further assessment, monitoring and/or remediation activities are known to have taken place at the site. On August 31, 2023, under the direction of CES, one (1) soil boring was installed near the former dispenser island and subsequently converted to a 2-inch diameter permanent groundwater monitoring well (MW-1) to facilitate the collection of groundwater samples for laboratory analysis. It should be noted that an open hole (ie, an area not backfilled) remains at the site from the excavation and removal of the USTs in June, 2021. Therefore, for safety considerations, MW-1 was installed approximately 15-feet from the edge of the open excavated area, in the area of the former dispenser island. During the installation of groundwater monitoring well MW-1 on August 31, 2023, one unsaturated soil sample was collected from the groundwater interface, at a depth of approximately 40-feet below grade, placed in laboratory provided vials and glassware, stored on ice, and hand delivered under chain-of-custody (COC) procedures on August 31, 2023 to Waypoint Analytical (Waypoint) of Charlotte, North Carolina (NC Certification No. 402) for laboratory analysis of VOCs by 8260, sVOCs by 8270, Metals (Pb & Cr) and VPH and EPH by MassDEP methodologies. Soil laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the Soil to Water Maximum Soil Contaminant Concentration (MSCC): CES Project No. 8173.0623E 7 October 4, 2023  MW-1: chromium, benzene, n-butylbenzene, sec-butylbenzene, ethylbenzene, isopropylbenzene, 4-isopropyl toluene, methyl ethyl ketone (MEK), naphthalene, n-propylbenzene, styrene, toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, total xylenes, 1- methylnaphthalene, 2-methylnaphthalene, C11-C22 aromatics, C5- C8 aliphatic, C9-C12 aliphatic and C9-C10 aromatics. Additionally, concentrations of 1,2,4-trimethylnaphthalene, C5-C8 aliphatic and C9-C10 aromatics were reported above Residential Cleanup Levels, and concentrations of chromium and naphthalene were reported above the Industrial/Commercial MSCC. All other concentrations of petroleum-related constituents in soil were reported below Soil to Water MSCC, Residential Soil Cleanup Levels, and Industrial/Commercial MSCC from MW-1. Upon completion of the soil boring to a depth of approximately 45-feet below grade after refusal was encountered, after depth to groundwater (DTW) was estimated between 40 and 45-feet below grade, and subsequent conversion to a 2-inch diameter permanent monitoring well, DTW measurements were recorded using a water level meter capable of detecting light non-aqueous phase liquid (LNAPL or Free Product) to an accuracy of 0.01 feet. Free product was not detected in MW-1. A DTW measurement from MW-1 was recorded at a depth of 38.39-feet below grade. Groundwater samples were then collected from MW-1, placed on ice, and delivered under COC procedures to Waypoint on August 31, 2023, for analysis of VOCs by 6200B and 504.1, Base/Neutrals and Acids by 625, Metals (Pb & Cr) and VPH and EPH by MassDEP methodologies. Groundwater laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the 2L Standards:  MW-1: benzene (GCL), di-isopropylether (DIPE), ethylbenzene, 2- hexanone, isopropylbenzene, MTBE, 4-methyl-2-pentanone, naphthalene, n-propylbenzene, styrene, tert-butyl alcohol (TBA), tert-Amyl Alcohol (TAA), tert-amyl methyl ether (TAME), toluene, 1,2,4-trimethylbenzene, total xylenes, 1-methylnaphthalene, 2- methylnaphthalene, C5-C8 aliphatic, C9-C12 aliphatic and C9-C10 aromatic. Groundwater laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the Gross Contaminant Level (GCL):  MW-1: benzene. All other concentrations of petroleum-related constituents in groundwater were reported below 2L Standards and the GCL from MW-1. Municipal water distribution systems provided by the City of Dallas are available to serve the subject property and surrounding properties. Per conversations with Bill Trudnak, City of Dallas Public Works Director, five properties within 500-feet of the site are not connected to the municipal water system. Based on this information, it is presumed that at least five water supply wells exist within 500-feet of the site. CES Project No. 8173.0623E 8 October 4, 2023 Based upon soil and groundwater samples collected from MW-1 on August 31, 2023, reporting petroleum-related constituents above applicable soil and groundwater standards, including groundwater concentrations of benzene and naphthalene reported above the GCL Standard, it is the opinion of CES that additional groundwater monitoring wells would be required to determine the extent of subsurface soil and groundwater impacts, and if the groundwater GCL plume has potentially migrated offsite. CES Project No. 8173.0623E 9 October 4, 2023 3.0 SITE HISTORY AND CHARACTERIZATION The subject site where this LSA was performed, where an apparent release of petroleum-related constituent occurred, consists of one parcel, identified as Gaston County Parcel Identification Number (PIN) 3537885891, and is situated along the northern line of Dallas Cherryville Highway, as shown on Figure 1. The site is in a mixed-use area of Dallas, Gaston County, North Carolina, with Dallas Cherryville Highway to the south, with a manufacturing facility located across the roadway, Venice Drive to the east with a residential structure further to the northeast, varying pieces of large equipment and machines with a residential dwelling to the north, and a residential dwelling to the west, and is generally situated in an area of residential, commercial, manufacturing, and institutional uses. The subject site contains one main structure located on the central portion of the site, an approximate 5,216-square foot building currently operating as a storage facility for landscaping and grading equipment. The main structure previously operated as a convenience store, and was reportedly constructed in the year 1978. The remainder of the subject site contains hard-packed gravel surfacing material, asphalt-paved entranceways and parking areas, and landscaped areas, with the former UST excavation area currently secured by chain-link fencing and concrete barriers. This LSA (i.e., the installation of monitoring well MW-1) was performed on the eastern portion of the site, in the area of the former UST system. Figure 2 depicts pertinent site features, including the property’s boundary lines in relation to MW-1, and the former gasoline and diesel USTs, which were removed in June of 2021. 3.1 Responsible Party Information UST Owner/Operator: Dustin Smithers Address: 2304 Dallas Cherryville Highway, Dallas, NC 28034 Phone: 704-400-2800 Other Person(s) Associated With USTs: (Site accepted into State-Lead Cleanup Program) Address: N/A Phone: N/A Current Property Owner: Dustin Smithers Address: 2304 Dallas Cherryville Highway, Dallas, NC 28034 Phone: 704-400-2800 On May 31, 2023, the site was accepted into the NCDEQ State-Lead Cleanup Program to conduct further investigative measures relative to Incident Number 47861. Additional responsible party information is provided in Table B-1 and Table B-2, and above in Section 1.2. CES Project No. 8173.0623E 10 October 4, 2023 3.2 UST Information A general summary of the UST system is presented below, with further information included in Tables B-1 and B-2: UST ID No Current/Last Contents Capacity (gallons) Date Installed * Date Removed * Discovery of Release 1 Gasoline 6,000 1/17/1980 6/11/2021 Yes 2 Gasoline 6,000 1/17/1980 6/11/2021 Yes 3 Diesel 4,000 1/17/1980 6/11/2021 Yes * According to UST information retrieved from the NCDEQ UST Database and the UST Closure Report, dated September 7, 2021, and prepared by Paragon. UST information, as retrieved from the NCDEQ UST Database is included in Appendix A. 3.3 AST Information Not Applicable. No ASTs or other above ground vessels or substantial petroleum storage containers are known to exist at the site, except for a presumed UST resting at grade level near the area of the former excavation area and the observed presence of AST(s) located behind the existing onsite building. 3.4 Release Description As reported in an UST Closure Report, dated September 7, 2021, prepared by Paragon, during the removal of two 6,000-gallon gasoline USTs and one 4,000-gallon diesel UST from the site in June, 2021, a total of twelve soil samples collected from underneath the former dispenser island, product piping and USTs reported TPH-DRO and/or GRO above NCDEQ Initial Action Levels for Contamination. Based on the reported concentration levels of TPH from the area of the former dispenser island, product piping and USTS, NCDEQ subsequently issued Incident Number 47861 for the apparent release condition to Dustin Smithers in June, 2021. 3.5 Site Characteristics The subject property is zoned General Industrial (I-2) in Gaston County, and includes one parcel, with Gaston County Parcel Identification Number 3537885891, occupying an area of approximately 1-acre. According to Gaston County GIS, Land Use of the subject property has been identified as Commercial. The adjoining property to the south of the site is Dallas Cherryville Highway with a manufacturing facility (Sherrill Contract Manufacturing) located across the roadway. The adjoining property to the west of the site is a residential dwelling. The adjoining property to the north of the site is a laydown area storing varying pieces of landscape and grading equipment, supplies and materials, with a residential dwelling further to the north. The adjoining property to the east of the site is Venice Drive, with a residential dwelling to the northeast. CES Project No. 8173.0623E 11 October 4, 2023 The subject site contains one main structure located on the central portion of the site, an approximate 5,216-square foot building currently operating as a storage facility for landscaping and grading equipment. The main structure previously operated as a convenience store, and was reportedly constructed in the year 1978. The remainder of the subject site contains hard-packed gravel surfacing material, asphalt-paved entranceways and parking areas, and landscaped areas, with the former UST excavation area currently secured by chain-link fencing and concrete barriers. The subject site is situated along Dallas Cherryville Highway, a 2 to 3-lane, asphalt surfaced, rural section roadway. The subject site is served by commercial utilities, including electrical power, telephone, and natural gas services. Public water distribution and sanitary sewer services provided by the City of Dallas are available to serve the site. 3.6 Prior Actions According to a review of available documents, prior actions at the site included the removal of two 6,000-gallon gasoline USTs and one 4,000-gallon diesel UST in June, 2021, without any reported excavation, removal, and disposal of contaminated soils being completed during the UST system removal. Since the documented removal of the UST system in June, 2021, no further assessment, monitoring and/or remediation activities are known to have taken place at this site. CES Project No. 8173.0623E 12 October 4, 2023 4.0 RISK CHARACTERIZATION 4.1 Part I – Groundwater/Surface Water/Vapor Impacts High Risk 1. Has the release contaminated any water supply well including any well used for non- drinking purposes? NO Not to our knowledge. 2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the release? YES According to conversations with Bill Trudnak, City of Dallas Public Works Director, properties within 500-feet of the site are not connected to the municipal water system, and therefore are presumed to have water supply wells used for drinking water purposes. However, the municipal water distribution system running along Dallas Cherryville Highway is available to serve the subject property and surrounding properties. 3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling water, filling swimming pools) located within 250 feet of the source area of the release? NO Not to our knowledge. 4. Does groundwater within 500 feet of the source area of the release have the potential for use (there is no other source of water supply other than the groundwater)? NO Not to our knowledge. Municipal water distribution systems are available to serve the subject property and surrounding properties. 5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a confined space or pose any other serious threat to public health, public safety, or the environment? NO To date, and to CES’ knowledge, no known incidents of explosion threats have been reported. CES Project No. 8173.0623E 13 October 4, 2023 Intermediate Risk 6. Are there any other factors that would cause the release to pose an imminent danger to public health, public safety, or the environment? NO 7. Is a surface water body located within 500 feet of the source area of the release? NO 8. Is the source area of the release located within an approved or planned wellhead protection area as defined in 42 USC 300h-7(e)? NO 9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled “Geology of North Carolina” published by the Department in 1985? NO 10. Do the levels of groundwater contamination for any contaminant exceed the gross contamination levels (See Table 2.) established by the Department? YES A concentration of benzene (8,230 ug/l) was reported from MW-1 above the GCL. 4.2 Part II – Land Use Property Containing Source Area of Release 1. Does the property contain one or more primary or secondary residences (permanent or temporary)? NO 2. Does the property contain a school, daycare center, hospital, playground, park, recreation area, church, nursing home, or other place of public assembly? NO 3. Does the property contain a commercial (e.g., retail, warehouse, office/business space etc.) or industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial enterprise, or is the land undeveloped? YES Currently, the property is a storage and laydown yard for a landscaping and grading business, and previously operated as a gasoline service station and convenience store. 4. Do children visit the property? YES Children have the ability to visit the property. Is access to the property reliably restricted consistent with its use (e.g., by fences, security CES Project No. 8173.0623E 14 October 4, 2023 personnel or both)? YES The former UST area, including the areas of the former dispensers, product piping and USTs, is currently secured by chain-link fencing and concrete barriers restricting access to the open excavated area. 5. Do pavement, buildings, or other structures cap the contaminated soil? NO Currently, the area of the former UST system, including the areas of the former dispensers, product piping and USTs is not paved, nor do any structures cap the contaminated soils. The excavated area of the former USTs was not backfilled to grade upon removal in June, 2021, with an open area to an approximate depth of 10-feet below grade. If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil will remain capped in the foreseeable future? Not Applicable. However, per conversations with the current property owner, Dustin Smithers, plans for the site include backfilling the open excavated hole to grade, re- grading the area of the former USTs, and restoring with an asphalt-paved surface. 6. What is the zoning status of the property? General Industrial (I-2) 7. Is the use of the property likely to change in the next 20 years? NO According to conversations with the current property owner, Dustin Smithers, the property will continue to be utilized for storage and operation of equipment for landscaping and grading purposes. Property Surrounding Source Area of Release 1. What is the distance from the source area of the release to the nearest primary or secondary residence (permanent or temporary)? Approximately 235-feet to the west 2. What is the distance from the source area of the release to the nearest school, daycare center, hospital, playground, park, recreation area, church, nursing home or other place of public assembly? Approximately 440-feet to the east Independent Baptist Tabernacle and Community Christian Academy is located approximately 440-feet to the east. 3. What is the zoning status of properties in the surrounding area? General Industrial (I-2) Light Commercial (C-1) Single-Family Limited Residential (R-1) CES Project No. 8173.0623E 15 October 4, 2023 4. Briefly characterize the use and activities of the land in the surrounding area. The site is generally located in a rural area of Dallas, with predominantly residential, commercial, manufacturing, and institutional uses. The site is bordered to the north by a laydown yard for landscaping and grading equipment, on the west by a residential dwelling, on the south by Dallas Cherryville Highway, and on the east by Venice Drive and a residential dwelling. CES Project No. 8173.0623E 16 October 4, 2023 5.0 RECEPTOR INFORMATION 5.1 Water Supply Wells As part of this LSA, a water supply well survey was conducted by interviewing the owner of the subject property, conducting a windshield survey, and sending out Request for Water Supply Well Information forms to property owners located within a 500-feet radius of the subject property. According to information obtained from the subject property owner, nearby and surrounding property owners, a review of NCDEQ SWAPInfo 2.0 and the City of Dallas and Gaston County GIS systems, water supply wells are known to exist within a 500-feet radius. However, the municipal water distribution system running along Dallas Cherryville Highway is available to serve the subject property and surrounding properties. On September 1, 2023, CES sent out Request for Water Supply Well Information forms to nine properties within a 500-feet radius of the subject property. A total of four Water Supply Well Information forms were returned to CES, or information was otherwise communicated to CES, which did not report the presence of water supply wells within a 500-feet radius of the site. Additionally, according to Samantha Dye, Gaston County Environmental Health Administrator, no water supply well records exist in their files for the nine properties located within 500-feet of the site. However, Ms. Dye indicated that the Gaston County water supply well permit program started in 1989 and therefore, water supply wells installed prior to 1989 would be undocumented. Furthermore, CES contacted Bill Trudnak, City of Dallas Public Works Director, who confirmed that municipal water is available to properties along Dallas Cherryville Highway. Mr. Trudnak also confirmed that properties located at 114, 124 and 134 Venice Drive and 2125, 2133, 2310, 2312 and 2314 Dallas Cherryville Highway are not connected to the municipal water distribution system, and therefore, are presumed to utilize water supply wells as their source of potable water. Figure 5 depicts the presumed location of water supply wells in relation to the subject site. Table B-5 summarizes public and private water supply well information. 5.2 Public Water Supplies According to the NC SWAPInfo 2.0 Map and NC One Map - Public Water Supply Well Resources Map, one public water supply well, associated with the Christian Fellowship Assembly, and located approximately 1,325-feet to the west-northwest is located within a 1,500-feet radius of the subject property. Municipal water distribution systems provided by the City of Dallas are available to serve the subject property and surrounding properties. 5.3 Surface Water According to the NC One Map – Surface Water Classifications Map, the nearest surface water body is Little Long Creek, located approximately 1,625-feet to the north of the site. According to the NC One Map – Surface Water Intakes Map, no surface water intakes are located within a 1,500-foot radius of the subject site. CES Project No. 8173.0623E 17 October 4, 2023 5.4 Wellhead Protection Areas According to the NC SWAP website and database of approved North Carolina Wellhead Protection Areas, no wellhead protection areas and/or approved wellhead protection plans are known to exist within a 1,500-foot radius of the subject site. One wellhead protection area and/or approved wellhead protection plan is known to exist in Gaston County, associated with Belmont Abbey College, and located approximately 10-miles to the east-southeast of the site. 5.5 Deep Aquifers in the Coastal Plain Physiographic Region Not applicable to the subject site, as the site lies within the Piedmont Physiographic Region. 5.6 Subsurface Structures Underground utilities have been identified at and adjacent to the subject site, and the potential exists for soil and groundwater contamination to be in contact with these underground utilities. Groundwater has historically been measured at approximately 38-feet below ground surface at the site. Because the underground utilities are expected to be at a shallower depth than 38-feet, the utility lines would not be considered receptors or conduits for ground water contaminant migration. No subsurface structures have been identified at the site. Figure 5 depicts a 1,500-feet Potential Receptor Map. CES Project No. 8173.0623E 18 October 4, 2023 6.0 LAND USE 6.1 Property Owners and Occupants Land use in the vicinity of the subject property can be characterized as commercial, residential, and institutional uses. Based on petroleum-related constituents reported above applicable groundwater standards (2L and GCL Standard), nearby and surrounding property owners and occupants may be impacted by the apparent release from Incident Number 47861, should the contaminant plume happen to extend beyond the subject property. Table B-6 summarizes contiguous property owners and occupants. No sensitive land use features, such as schools, daycare centers, nursing homes, hospitals, playgrounds, churches, camps, or other places of assembly, have been identified within 1,500- feet of the source of the release, with the exception of Independent Baptist Tabernacle and Community Christian Academy located approximately 440-feet to the east, Fellowship Church located approximately 1,155-feet to the northwest, and Applewood Veterinary Hospital located approximately 1,325-feet to the west. Aerial imagery depicting land use in the general vicinity of the site is included on Figure 5. CES Project No. 8173.0623E 19 October 4, 2023 7.0 SITE GEOLOGY AND HYDROGEOLOGY According to the Geological Map of North Carolina (1985), the subject site is located within the Piedmont Physiographic Province, is underlain by intrusive rocks of the Kings Mountain Belt and is within a foliated to massive granitic rock formation. A description of the underlaying Rock Unit PPmg is megacrystic to equigranular and high shoals granite. According to the US Department of Agriculture, Natural Resources Conservation Service, Web Soil Survey, soils at the subject property consist of Cecil sandy clay loam (CeB2), which generally have a 2 to 8 percent slope, are moderately eroded and are classified as well drained sandy clay loam (0 to 6-inches), clay (6 to 40-inches), clay loam (40 to 48-inches), and sandy loam (48 to 80- inches). Parent materials were classified as Saprolite derived from granite and gneiss, and/or schist. Encountered soils from monitoring well MW-1 were generally classified as a brownish red sandy silt (0 to 15-feet), a reddish tan silty sand with some clay (15 to 40-feet), and reddish tan silty clay with some sand (40 to 45-feet). According to a review of applicable USGS topographic mapping for the subject property and onsite observations, it has been determined that natural surface drainage in the vicinity of the subject site is generally in a north-northwesterly direction. While not always the case, groundwater flow direction typically follows the direction of surface water flow, and is, therefore, anticipated to flow north-northwesterly. Man-made improvements may alter natural local drainage patterns to some degree. The data obtained and reported herein is representative of conditions only at the referenced boring and monitoring well location, and is not necessarily indicative of conditions elsewhere on the subject property. CES Project No. 8173.0623E 20 October 4, 2023 8.0 SAMPLING RESULTS 8.1 Phase I Investigation On August 31, 2023, under the direction of a CES environmental scientist, one soil boring was installed on the eastern portion of the site, in the area of the former dispenser island, to a depth of approximately 45-feet below grade after refusal was encountered, after depth to groundwater was estimated at between 35 to 40-feet below grade, to facilitate the completion of one 2-inch diameter permanent groundwater well (MW-1) for groundwater collection purposes. Soil boring/monitoring well MW-1 was installed by a sub-contracted driller, Carolina Soil Investigations, LLC of Olin, North Carolina, via augering techniques, utilizing a track-mounted geoprobe rig, Model 6712DT. Prior to the completion of MW-1, Monitoring Well Construction Permit Number WM0301285 and Environmental Health Permit Number 20995 were obtained from the Water Quality Regional Operations Section of the NCDEQ Division of Water Resources and the Gaston County Environmental Health Department, respectively. During the advancement of the soil boring, subsurface soils were primarily classified as a brownish red sandy silt (0 to 15-feet), a reddish tan silty sand with some clay (15 to 40-feet), and reddish tan silty clay with some sand (40 to 45-feet), with moist samples observed at a depth of approximately 40 to 45-feet below grade. The Site Plan, as shown on Figure 2, depicts the location of monitoring well MW-1. A monitoring well construction log and drilling form for the soil boring/monitoring well are included as Table B- 7 and Appendix E, respectively. The Monitoring Well Construction Permits are included in Appendix E. During the advancement of the soil boring, the CES Environmental Scientist field screened encountered soils with a MiniRAE 2000 Photoionization Detector (PID) for the presence of volatile organic compounds (VOCs), reported in parts per million per volume (ppmv), to facilitate the selection of one soil sample for subsequent laboratory analysis. PID measurements ranged from 77 ppmv, collected from an unsaturated soil sample between grade and 5-feet below grade, to 3,819 ppmv, collected from an unsaturated soil sample at approximately 40-feet below grade. Based on PID measurements and the approximate depth of encountered groundwater (between 35 to 40-feet below grade), the soil sample at a depth of approximately 40-feet below grade was collected in laboratory provided vials and glassware, stored on ice, and hand delivered under COC procedures on September 1, 2023, to Waypoint for laboratory analysis of the following:  VOCs by 8260 + MTBE/IPE  sVOCS by 8270 BNA  MassDEP VPH  MassDEP EPH  Metals: Pb + Cr Soil laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the Soil to Water Maximum Soil Contaminant Concentration (MSCC):  MW-1: chromium, benzene, n-butylbenzene, sec-butylbenzene, ethylbenzene, isopropylbenzene, 4-isopropyl toluene, methyl ethyl ketone (MEK), naphthalene, n-propylbenzene, styrene, toluene, CES Project No. 8173.0623E 21 October 4, 2023 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, total xylenes, 1- methylnaphthalene, 2-methylnaphthalene, C11-C22 aromatics, C5- C8 aliphatic, C9-C12 aliphatic and C9-C10 aromatics. Additionally, concentrations of 1,2,4-trimethylnaphthalene, C5-C8 aliphatic and C9-C10 aromatics were reported above Residential Cleanup Levels, and concentrations of chromium and naphthalene were reported above the Industrial/Commercial MSCC. All other concentrations of petroleum-related constituents in soil were reported below Soil to Water MSCC, Residential Soil Cleanup Levels, and Industrial/Commercial MSCC from MW-1. A photographic log depicting the site and soil boring location is included in Appendix B. Figure 2 depicts the location of soil boring/monitoring well MW-1. Figure 3 depicts an Estimated Extent of Soil Contamination Map. Table B-3 summarizes soil laboratory analytical results. Soil laboratory analytical reports are included in Appendix D. Upon completion of the soil boring to a depth of approximately 45-feet below grade, and subsequent conversion to a 2-inch diameter monitoring well, DTW measurements were recorded using a water level meter capable of detecting LNAPL to an accuracy of 0.01 feet. LNAPL was not detected in groundwater monitoring well MW-1. DTW measurement from MW-1 was recorded at a depth of approximately 38.39-feet below grade. After collecting depth to groundwater measurements, and after calculating the volume of water to be removed from MW-1, a dedicated 1.5-inch disposable bailer was used to develop the well by surging methods, and then approximately three to five well volumes were purged from the monitoring well. Groundwater samples were then collected in laboratory provided vials and glassware via the dedicated 1.5-inch disposable bailer, stored on ice, and hand delivered under COC procedures on September 1, 2023, to Waypoint for laboratory analysis of the following:  VOCs by SM 6200B ext + 5 oxy  VOCs by 504.1 (EDB)  Base/Neutrals and Acids by 625 BNA  MassDEP VPH  MassDEP EPH  Metals: PB + Cr Groundwater laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the 2L Standards:  MW-1: benzene (GCL), di-isopropylether (DIPE), ethylbenzene, 2- hexanone, isopropylbenzene, MTBE, 4-methyl-2-pentanone, naphthalene, n-propylbenzene, styrene, tert-butyl alcohol (TBA), tert-Amyl Alcohol (TAA), tert-amyl methyl ether (TAME), toluene, 1,2,4-trimethylbenzene, total xylenes, 1-methylnaphthalene, 2- methylnaphthalene, C5-C8 aliphatic, C9-C12 aliphatic and C9-C10 aromatic. Groundwater laboratory analytical results from MW-1 reported the following petroleum-related constituent concentrations above the Gross Contaminant Level (GCL): CES Project No. 8173.0623E 22 October 4, 2023  MW-1: benzene. All other concentrations of petroleum-related constituents in groundwater were reported below 2L Standards and the GCL from MW-1. Figure 4 depicts a Groundwater Elevation and Estimated Extent of Contamination Map. Tables B-4 and B-9 summarize groundwater analytical results and depth to groundwater measurements, respectively. Field data sheets for groundwater sampling, along with CES’ standard operating procedures for soil and groundwater investigations, and the prepared and reviewed Job Hazard Analysis (JHA) and Emergency Management and Health & Safety Plan (HASP) are included in Appendix C. Groundwater analytical reports are included in Appendix D. CES Project No. 8173.0623E 23 October 4, 2023 9.0 CONCLUSIONS AND RECOMMENDATIONS 9.1 Conclusions and Recommendations Conclusions: A Phase I LSA of the subject property was completed by CES to evaluate if soil and groundwater has been impacted at the site by the apparent release condition from the historical operation of the UST system (removed in June, 2021), and if the potential exists for nearby water supply wells and/or other receptors to be impacted. Subsequent findings indicated that a soil sample collected from a soil boring/monitoring well (MW- 1) installed on the eastern portion of the site, in the area of the former dispenser island, reported concentrations of petroleum-related constituents above NCDEQ Soil Standards, and subsequent groundwater samples collected from MW-1 reported concentrations of petroleum-related constituents above 2L Standards, with a concentration of benzene reported above the GCL. The findings of the receptor survey indicated that water supply wells have been identified within 500-feet of the site. Recommendations: Based upon soil and groundwater samples collected from MW-1 on August 31, 2023, reporting petroleum-related constituents above applicable soil and groundwater standards, including groundwater concentrations of benzene and naphthalene reported above the GCL Standard, it is the opinion of CES that additional groundwater monitoring wells, as depicted on Figure 6, would be required to determine the extent of subsurface soil and groundwater impacts, and if the groundwater GCL plume has potentially migrated offsite. CES Project No. 8173.0623E 24 October 4, 2023 10.0 REFERENCES Paragon Environmental Consultants, Inc of Thomasville, North Carolina. UST Closure Report, dated September 7, 2021. FIGURES ^_ SITE LOCATION Drawn on: 7/17/2023 Drawn by: Amy Schmidt Reviewed by: Greg Hans 3525 Whitehall Park DriveSuite 150Charlotte, North Carolina 28273T: 704-489-1500www.ces-group.net³ 0 2,000 4,000 6,000 8,0001,000 FEET REFERENCE:USGS The National Map: National Boundaries Dataset, 3DEP Elevation Program, Geographic Names Information System,National Hydrography Dataset, National Land Cover Database, National Structures Dataset, and National TransportationDataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.Department of State Humanitarian Information Unit; and NOAA National Centers for Environmental Information, U.S.Coastal Relief Model. Data refreshed April, 2023.Figure 1Site Location MapMountain Village Grocery2302 Dallas Cherryville HighwayDallas, Gaston County, North CarolinaCES Project No. 8172.0623E DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8173.0623E DRAWING TITLE: SHEET NUMBER: SEAL:PROJECT DESCRIPTION:Site PlanCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 09/22/2023 SCALE : 1" = 20' DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8173.0623E DRAWING TITLE: SHEET NUMBER: SEAL:PROJECT DESCRIPTION:Estimated Extent of Soil Contamination MapCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 09/22/2023 SCALE : 1" = 20' DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8173.0623E DRAWING TITLE: SHEET NUMBER: SEAL:Groundwater Elevation andEstimated Extent of Contamination MapCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 09/22/2023 SCALE : 1" = 20' ^_ !( !(!( !( !( ! !( !( !( !( SITE LOCATION Drawn on: 10/2/2023 Drawn by: Amy Schmidt Reviewed by: Greg Hans 3525 Whitehall Park Drive Suite 150 Charlotte, North Carolina 28273T: 704-489-1500 www.ces-group.net 0 300 600 900 1,200150 FEET Legend ^_Site Location 500' Radius 1,000' Radius 1,500' Radius Parcels !(Water Supply Wells - None Present !(Water Supply Wells - None Present (Capped Years Ago) !(Water Supply Wells - Presumed (No Municipal Water Account) REFERENCE:NC OneMap aerial orthoimagery dated 2022. Parcel data and street dataobtained from NC OneMap and Gaston County Figure 51,500-FT Radius MapMountain Village Grocery2302 Dallas Cherryville HighwayDallas, Gaston County, North CarolinaCES Project No. 8172.0623E ! DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8173.0623E DRAWING TITLE: SHEET NUMBER: SEAL:Proposed Monitoring Well Location MapCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 09/26/2023 SCALE : 1" = 20' TABLES Table B-1: Site History – UST/AST System and Other Release Information Revision Date: 09/17/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 64" x 24'Single-Wall Steel 1/17/1980 Permanently Closed (Removed 6/11/2021) Yes3 Diesel Unknown 4,000 Steel 8' x 16'1"Single-Wall Steel 1/17/1980 Permanently Closed (Removed 6/11/2021) Yes2 Gasoline Unknown 6,000 Steel UST ID Number Gasoline 6,000 Steel 8' x 16'1"1 Unknown Tank Dimensions (diameter x length) Construction Details Capacity (in gallons) Previous Contents Current/Last Contents Yes Description of Associated Piping and Pumps Was release associated with the UST System? Status of USTDate Tank Installed Single-Wall Steel 1/17/1980 Permanently Closed (Removed 6/11/2021) Page 1 of 2 Table B-1: Site History – UST/AST System and Other Release Information Revision Date: 09/17/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 Incident Number Material Released Date of Release 47861 Petroleum 6/11/2021 *It should be noted that ASTs were observed onsite, located behind the building (locked gate) AST ID Number * Current/Last Contents Previous Contents Capacity (in gallons) Construction Details Tank Dimensions Status of AST Description of Release Soil contamination encountered during removal of UST system in June, 2021 Description of Associated Piping and Pumps Was release associated with the AST System? Date Tank Installed Page 2 of 2 Table B-2: Site History - UST/AST Owner/Operator and Other Responsible Party Information Revision Date: 09/17/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 2 3 State Zip NC 28034 State Zip NC 28034 State Zip Street Address Dustin Smithers Tanks 1,2 and 3 (1/17/1980 to 3/1/2008) UST ID Number 1 Facility ID Number Name of Owner Dates of Operation (mm/dd/yy to mm/dd/yy) 00-0-0000015758 City Telephone Number Dallas 704-400-2800 2304 Dallas Cherryville Highway Name of Other Responsible Party Dates of Release(s) (mm/dd/yy to mm/dd/yy) Street Address City Telephone Number Dallas 704-400-2800 Incident Number 47861 Street Address 2304 Dallas Cherryville Highway City Telephone Number Name of Operator Dates of Operation (mm/dd/yy to mm/dd/yy) Dustin Smithers Tanks 1,2 and 3 (1/17/1980 to 3/1/2008) Page 1 of 1 Table B-3: Summary of Soil Analytical Results Revision Date: 09/15/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 6010D 6010D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8260D 8270E 8270E 8270E MADEP-EPH MADEP- EPH MADEP- VPH MADEP- VPH MADEP- VPH Sample ID Date Collected (m/dd/yy) Source Area (eg. Tank Grave) Sample Depth (feet BGS) PID (ppmv) MW-1 8/31/23 Former Dispensers / Tank Grave 35' 3819.0 27.9 17.7 11 4.83 9.35 2.74 50 19.4 5.15 1.51 J 63.1 39.1 23.5 1.42 J 107 166 48.8 274 7.07 16.7 18.1 169 207 885 1200 696 3.8 270 24 0.0072 2.4 2.2 8 N/A 1.3 0.12 16 0.2 1.4 0.9 5.4 6.6 6.6 6 0.054 1.5 0.2 540 31 68 540 31 1.32 400 14000 12 782 1560 60.3 N/A 1560 1560 9380 5.5 1560 3120 1250 156 156 3120 22.8 62.5 5.5 1560 469 625 1560 469 6.54 400 210000 59.4 11600 23300 297 N/A 23300 23300 140000 27 23300 46700 18600 2330 2330 46700 112 934 27 23300 7000 9340 23300 7000 Feet BGS = feet below ground surface mg/kg =milligrams per kilogram ppmv: parts per million per volume as detected by MiniRAE2000 photoionization detector (PID) BDL = Below Laboratory Detection Limit NA = Not applicable J = Detected but below the Reporting Limit; therefore, result is an estimated concentration Highlighted Yellow / Bold = Values exceeding the Soil-to-Water Soil Standard Highlighted Green / Bold = Values exceeding the Residential Soil Cleanup Standard Highlighted Red / Bold = Values exceeding Soil-to-Water, Residential and Industrial/Commercial Standards Concentrations compared to Table - 1, Rev 10/5/2021, Comprehensive Tables for Corrective Action Guidelines (September 7, 2022 Version, Change 5)C9-C10 AromaticAnalytical Method (e.g., VOCs by 8260D)  Contaminant of Concern (mg/kg) C5-C8 Aliphaticn-Butylbenzenesec-ButylbenzeneEthylbenzeneIsopropylbenzeneNaphthalenen-PropylbenzeneC9-C12 Aliphatic1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene4-Isopropyl tolueneXylenes1-MethylnaphthaleneResidential Soil Cleanup Levels (mg/kg) Industrial/Commercial MSCC (mg/kg)n-HexaneChromiumLeadAcetoneBenzeneNaphthaleneC9-C18 AliphaticC11-C22 Aromatic2-MethylnaphthaleneSoil-to-Water Maximum Contaminant Concentration (mg/kg)Methyl Ether Ketone (MEK)TolueneStyrene Table B-4: Summary of Groundwater Analytical Results Revision Date: 09/15/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 6010D 6010D 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 625.1 625.1 625.1 MADEP EPH MADEP EPH MADEP VPH MADEP VPH MADEP VPH Sample ID Date Collected (m/dd/yy) Incident Phase MW-1 8/31/23 LSA 8 BDL 8230 27.4 J 873 3030 290 101 2470 120 816 320 134 418 J 4230 276 J 29900 2670 666 15300 62.3 135 486 130 1270 70000 40000 6860 10 15 1 70 70 600 40 70 20 100 6 70 70 10 40 128 600 400 400 500 1 30 6 700 NA 400 700 200 10000 15000 5000 5900 70000 80000 40000 30500 20000 100000 6000 26100 70000 10000 40000 128000 260000 28500 24100 50000 1000 12000 6000 NA NA NA NA NA µg/l = Micrograms per Liter GCL = Gross Contamination Level BDL = Below Laboratory Detection Limit NA = Not Applicable J = Detected but below the Reporting Limit; therefore, result is an estimated concentration Concentrations in BOLD and Highlighted Yellow reported above 2L Standards (August 31, 2023) Concentrations in BOLD and Highlighted Red reported above GCL Standards (August 31, 2023) Constituents not listed above were reported as BDLs Laboratory analysis performed by Waypoint Analytical, Inc of Charlotte, NC (NC Certification No. 402)NaphthaleneC11-C22 AromaticC9-C18 Aliphatic1-MethylnaphthaleneC9-C10 AromaticC5-C8 AliphaticC9-C12 Aliphatic2-MethylnaphthaleneAnalytical Method (e.g., VOCs by EPA 6200B)  Contaminant of Concern (mg/kg) n-ButylbenzeneXylene (Total)Isopropyl benzene4-Methyl-2-Pentanone (MIBK)1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneNaphthalenen-Propyl benzeneStyrene2-HexanoneMTBEtert-Butyl Alcohol (TBA)tert-Amyl Alcohol (TAA)tert-Amyl Methyl Ether (TAME)Toluene2L Standard (ug/L) (Effective 4/1/2022) GCL (ug/L) (Table 2 - Revised 10/8/2020)Di-Isopropyl Ether (DIPE)EthylbenzeneBenzeneChromiumLead Table B-5: Public and Private Water Supply Well and Other Receptor Information Revision Date: 10/01/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 Water Supply Well and Other Receptor Information **** 1 WSW Timothy Smithers Both N/A 114 Venice Drive, Dallas, NC 28034 Residential 35.32047 -81.21665 A / P ~315-Feet Unknown 2 WSW Pamela Smithers Carter Both N/A 124 Venice Drive, Dallas, NC 28034 Residential 35.32108 -81.21655 A / P ~495-Feet Unknown 3 WSW Pamela Smithers Carter Both N/A 134 Venice Drive, Dallas, NC 28034 Residential 35.32184 -81.21701 A / P ~725-Feet Unknown 4 WSW MALM Holdings, LLC Owner N/A 2125 Dallas Cherryville Highway, Dallas, NC 28034 Business 35.31840 -81.21606 A / P ~670-Feet Unknown 5 WSW MALM Holdings, LLC Owner N/A 2133 Dallas Cherryville Highway, Dallas, NC 28034 Residential 35.31812 -81.21685 A / P ~645-Feet Unknown 6 WSW Pamela Smithers Carter Both N/A 2310 - 2312 Dallas Cherryville Highway, Dallas, NC 28034 Residential 35.32029 -81.21799 A / P ~225-Feet Unknown 7 WSW RKC Dallas, LLC Owner N/A 2314 Dallas Cherryville Highway, Dallas, NC 28034 Residential 35.32054 -81.21830 A / P ~350-Feet Unknown Additional Information for Water Supply Wells (and Other Receptors, if applicable) Well # / ID (same as above) Public Water: Connected / Available / Not Available Well Currently Used for: Active / Inactive / Abandoned Construction Method and Well Type Total Depth (ft BGS) Screened Interval (x to y ft BGS) ft BGS = Feet below ground surface Up or Downgradie nt (if known) Street Address for Receptor Receptor Description and Location Details ** Latitude/ Longitude ** (decimal degrees) Source Status & Use *** Distance from Source (ft) Well # Type * Contact Name Owner/User/Both Contact Phone # * Ex: WSW = Water Supply Well, SWB = Surface Water Body, Resvr = Reservoir, PWS = Public Water Supply, PW = Public Well, SW = Supply Well, WPA = Wellhead Protection Areas, RA = Recharge Areas (for deep aquifers), Sub = Subsurface Structures, Con = Conduits, Other: ** The location and/or latitude/longitude (IN DECIMAL DEGREES) must be sufficiently accurate and precise to allow easy location of wells (or recovery if buried/paved/covered-over, lost, or otherwise damaged) and for the location / replication of sampling points for any other receptor. Coordinates of Well # 3-11 are estimated based on physical location of onsite structure *** Status: A = Active or IA = Inactive *and* Use: P = Potable or NP = Non-Potable Use. (Describe further in Additional Information for Water Supply Wells table below.) Private / Public / Semi-Public Casing Depth (ft BGS) **** Water Supply Well Survey Forms not returned by property owner for Well # 1 through 6. Presumed WSW servicing onsite residence with owner and user information presumed as well. Information obtained from the City of Dallas DPW indicated no municipal water account is currently on file. Page 1 of 1 Table B-6: Contiguous Property Owners/Occupants Revision Date: 09/18/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 Tax Parcel Number / Map ID Owner / Occupant Name Address (Physical) Address (Mailing) 3537885891 (subject property) Dustin Smithers / Landscaping 2302 Dallas Cherryville Highway, Dallas, NC 28034 2304 Dallas Cherryville Highway, Dallas, NC 28034 3537887887 (adjoining property to the east) Timothy Smithers / Residential 114 Venice Drive, Dallas, NC 28034 921 Forestbrook Drive, Gastonia, NC 28056 3537896141 (adjoining property to the north) Dustin Smithers / Residential 2308 Dallas Cherryville Highway, Dallas, NC 28034 134 Venice Drive, Dallas, NC 28034 3537884941 (adjoining property to the west) Pamela Smithers / Residential 2312 Dallas Cherryville Highway, Dallas, NC 28034 124 Venice Drive, Dallas, NC 28034 Table B-7: Monitoring and Remediation Well Construction Information Revision Date: 09/01/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 Well ID Date Installed (m/dd/yy) Date Water Level Measured (m/dd/yy) Well Casing Diameter (in.) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Depth of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness ** (ft.) Initial Groundwater Elevation* (ft.) Latitude/ Longitude (decimal degrees)*** MW-1 8/31/2023 8/31/2023 2" 25' 25 to 45' 45' N/A 38.39 0.0 N/A 35.31986 -81.21742 ft BGS = feet below ground * Reference Point for Elevation Measurements Sea Level ** If free product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581] *** The location must be sufficiently accurate and precise to allow easy recovery of lost or damaged wells. Page 1 of 1 Table B-9: Groundwater Elevations and Free Product Thickness Revision Date: 09/01/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID#: MO-28622 Well ID #Top of Casing Elevation (MSL) Screened Interval (top of screen, bottom of screen) Date Depth to Water* Uncorrected (feet) Free Product Thickness (feet) Depth to Water* Corrected for Free Product Thickness(feet) Groundwater Surface Elevation (MSL) MW-1 NA 25 - 45' 8/31/2023 38.39 0 38.39 NA APPENDIX A HISTORICAL DATA RUST: mountain village pantry Incident Number 47861 UST Number MO-28622 Incident Name mountain village pantry Facility ID 00-0-0000015758 Address 2302 dallas-cherryville highway City/Town dallas County GASTO Zip Code 28034 Incident Manager's Initials BCN Regional Office Code MOR Date Incident Occurred 6/17/2021, 8:00 PM Date Incident Reported 6/23/2021, 8:00 PM date Incident Closed Commercial, Non-Commercial, or Both C Regulated, Non-Regulated, or Both R Confirmed Risk U Risk Rank 0 Risk Abatement Code Risk Assessment Date Land Use Notice of Residual Petroleum (NRP) Filed Media Restricted Per NRP Date NRP Rescinded Link To Documents More info Latitude 35.320071 Longitude -81.217628 "00-0-0000015758","MOUNTAIN VILLAGE PANTRY","2302 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034","DUSTIN VENICE. SMITHERS","2304 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034-7709","1","0","0","0","0",,"1980/01/17 00:00:00","2021/06/11 00:00:00","6000","1","1",,,,,,"Gasoline, Gas Mix",,"Gaston","35.31978"," -81.21734",,,,,,,,,,4/20/2017 15:04:50,"200745141R","European SucƟon","Single Wall Steel",,"200745141R", "00-0-0000015758","MOUNTAIN VILLAGE PANTRY","2302 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034","DUSTIN VENICE. SMITHERS","2304 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034-7709","2","0","0","0","0",,"1980/01/17 00:00:00","2021/06/11 00:00:00","6000","1","1",,,,,,"Gasoline, Gas Mix",,"Gaston","35.31978"," -81.21734",,,,,,,,,,4/20/2017 15:04:50,"200745141R","European SucƟon","Single Wall Steel",,"200745141R", "00-0-0000015758","MOUNTAIN VILLAGE PANTRY","2302 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034","DUSTIN VENICE. SMITHERS","2304 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034-7709","3","0","0","0","0",,"1980/01/17 00:00:00","2021/06/11 00:00:00","4000","1","1",,,,,,"Diesel",,"Gaston","35.31978"," -81.21734",,,,,,,,,,4/20/2017 15:04:50,"200745141R","European SucƟon","Single Wall Steel",,"200745141R", "00-0-0000015758","DUSTIN VENICE. SMITHERS","2304 DALLAS CHERRYVILLE HWY",,"DALLAS","NC","28034-7709",227182.00,"96908","Gaston","(704) 922- 3506","Owner",,"35.31978"," -81.21734" APPENDIX B SITE PHOTOGRAPHS View of signage at 2302 Dallas Cherryville Highway, Dallas, NC View of former UST area, excavated and removed in June, 2021 and currently secured with chain-link fencing Current view of open, excavated area (former USTs) with no backfilling acƟviƟes occurring during UST removals in June, 2021 AddiƟonal of open, excavated area (former USTs) with no backfilling acƟviƟes occurring during UST removals in June, 2021 LocaƟon of MW-1 (located near former dispenser island, and approximately 15-feet from open, excavated former UST area) AddiƟonal view of MW-1 (located near former dispenser island, and approximately 15-feet from open, excavated former UST area) APPENDIX C MONITORING FIELD DATA SHEETS, SAMPLING PROTOCOLS, JOB HAZARD ANALYSIS, AND HEALTH & SAFETY PLAN Appendix C: Groundwater Monitoring Field Data Completion Date: 09/11/2023 Incident Number and Name: 47861; Mountain Village Pantry UST ID No. MO-28622 Well ID Sampling Date (m/dd/yy) Well Casing Diameter (in.) Screened Interval (x to y ft. BGS) Depth of Well (ft. BGS) Top of Casing Elevation * (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness (ft.) Groundwater Elevation* (ft.) Sample Analysis Number of Sample Containers Proposed Purged Volume (gal) Actual Purged Volume (gal) Purge Comments MNA Parameters MW-1 8/31/2023 2" 25 - 45' 45' N/A 38.39 ND N/A 6200B + 5 oxy, 504.1, 625 BNA + TICs, VPH, EPH, PB + Cr 15 6.25-gal 2.5-gal Developed, and purged 2.5-gallons prior to sampling after bailer on bottom. Purged bailings observed to be a murky brown. Petroleum odor present, no sheens present on bailings Not Collected Mountain Village Pantry, NCDEQ Incident No.: 47861, UST ID No.: MO-28622 *: Top-of-Casing elevations not obtained under current task order / work order Site/Location Contract Number N042023 Customer NCDEQ STF (Scott Ryals)Prepared By Greg Hans Competent Person Greg Hans Date Prepared 6/19/2023 Phone Number 617-828-9948 PPE Level Level D Step Step Step Step Step Closest Hospital/ER CaroMount Regional Medical Center Hospital Address 2525 Court Drive, Gastonia, NC 28054 CALL 911 Hospital Phone #704-834-2000 FOR Local Police Number 704-922-3131 (Dallas PD)EMERGENCY Greg Hans 6/19/2023 Signature Date Printed Name 3525 Whitehall Park Drive, Suite 150, Charlotte, NC 28273 Follow Driving and Parking Steps each mobilization. Maintain safe distance from drilling equipment while in progress. Discuss SOW with drillers. Keep close eye on where drillers stand, and do not venture into areas of drilling w/o discussing with drillers first Sequence of Basic Job Steps Potential Incidents or Hazards Recommended Procedures to Eliminate Potential Hazards/Incidents 5 Collecting Soil and GW Samples Exposure to Contaminants Wear proper PPE (change gloves to avoid cross contamination). Monitor ambient air for petroleum vapors. Discuss planned soil and GW collection procedures with drillers prior to starting 2 Parking Vehicular accidents / damage to vehicles Park in areas off of roadway, at least 10 feet, use orange cones and flashers to identify parked location. Discuss parking areas with current site owners/managers, and confirm with subconsultants 3 Site Recon / Surveys Slips, Trips, Falls / Vehicles Wear proper PPE (including visibility vest), maintain safe distance from travel lanes at all times, do not turn back to oncoming traffic. Avoid crossing busy streets/intersections. Check surface areas prior to accessing for S, T, F hazards Job Hazard Analysis & Health/Safety Issues Sequence of Basic Job Steps Potential Incidents or Hazards Recommended Procedures to Eliminate Potential Hazards/Incidents Driving / Site Access Vehicular accidents / traffic violations / accidents with large equipment Practice defensive driving techniques, use turn signals, stay in lanes, obey speed limits / while onsite, pay close attention to large pieces of equipment in facility and make eye contact with operators before proceeding / always have strobe light flashers on 1 Mountain Village Grocery (2302 Dallas Cherryville Hwy, NC) Sequence of Basic Job Steps Potential Incidents or Hazards Recommended Procedures to Eliminate Potential Hazards/Incidents Sequence of Basic Job Steps Potential Incidents or Hazards Sequence of Basic Job Steps Potential Incidents or Hazards Recommended Procedures to Eliminate Potential Hazards/Incidents 4 Drilling Contact with Heavy Equipment APPENDIX D SOIL AND GROUNDWATER LABORATORY REPORTS AND CHAIN- OF-CUSTODY RECORDS   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   9/14/2023 CES Group Greg Hans 3525 Whitehall Park Dr. Suite 150 Charlotte, NC, 28273 Ref: Analytical Testing Lab Report Number: 23-244-0009 Client Project Description: Mountain Village Park Dear Greg Hans: Waypoint Analytical, LLC (Charlotte) received sample(s) on 9/1/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 64 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202437735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202499012State ProgramSouth Carolina 12/31/202399012State ProgramSouth Carolina Page 1 of 1 00016/23-244-0009 Page 2 of 64 Report Number: Sample Summary Table Client Project Description: 23-244-0009 Mountain Village Park Lab No Client Sample ID Matrix Date Collected Date Received 08/31/2023 10:45Solids 93944 MW-1 09/01/2023 10:06 08/31/2023 11:00Aqueous 93945 MW-1 09/01/2023 10:06 Page 3 of 64 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-244-0009 Report Limit Project:Mountain Village Park V 93944MW-1 27.9 09/06/2023 13:156010DChromiummg/Kg - dry 0.979 17.7 09/06/2023 13:156010DLeadmg/Kg - dry 0.455 11.0 09/05/2023 17:438260DAcetonemg/Kg - dry 0.761 4.83 09/05/2023 17:438260DBenzenemg/Kg - dry 0.184 9.35 09/05/2023 17:438260Dn-Butylbenzene mg/Kg - dry 0.155 2.74 09/05/2023 17:438260Dsec-Butyl benzene mg/Kg - dry 0.178 50.0 09/05/2023 17:438260DEthylbenzenemg/Kg - dry 0.184 19.4 09/05/2023 17:438260Dn-Hexane mg/Kg - dry 0.209 5.15 09/05/2023 17:438260DIsopropylbenzenemg/Kg - dry 0.146 J1.51 09/05/2023 17:438260D4-Isopropyl toluene mg/Kg - dry 0.413 63.1 09/05/2023 17:438260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.206 39.1 09/05/2023 17:438260DNaphthalenemg/Kg - dry 0.313 23.5 09/05/2023 17:438260Dn-Propylbenzene mg/Kg - dry 0.171 J1.42 09/05/2023 17:438260DStyrenemg/Kg - dry 0.451 107 09/05/2023 17:438260DToluenemg/Kg - dry 0.209 166 09/06/2023 19:388260D1,2,4-Trimethylbenzene mg/Kg - dry 1.56 48.8 09/05/2023 17:438260D1,3,5-Trimethylbenzene mg/Kg - dry 0.171 84.0 09/05/2023 17:438260Do-Xylene mg/Kg - dry 0.158 190 09/05/2023 17:438260Dm,p-Xylene mg/Kg - dry 0.399 274 09/05/2023 17:438260DXylene (Total)mg/Kg - dry 0.158 7.07 09/08/2023 19:058270E1-Methylnaphthalene mg/Kg - dry 0.488 16.7 09/08/2023 19:058270E2-Methylnaphthalene mg/Kg - dry 0.460 18.1 09/08/2023 19:058270ENaphthalenemg/Kg - dry 0.663 169 09/13/2023 10:46MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 10.6 207 09/13/2023 10:46MADEP-EPH Aromatic C11-C22 mg/Kg - dry 16.2 885 09/02/2023 05:23MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 7.00 1200 09/02/2023 05:23MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 26.3 696 09/02/2023 05:23MADEP-VPH Aromatic C9-C10 mg/Kg - dry 3.59 13.2 09/05/2023 11:43SW-DRYWT Moisture % V 93945MW-1 0.008 09/06/2023 19:246010DChromiummg/L 0.002 8230 09/07/2023 08:576200BBenzeneµg/L 18.0 J27.4 09/07/2023 08:576200Bn-Butylbenzene µg/L 18.0 873 09/07/2023 08:576200BDi-Isopropyl Ether (DIPE)µg/L 50.0 3030 09/07/2023 08:576200BEthylbenzeneµg/L 17.0 290 09/07/2023 08:576200B2-Hexanone µg/L 38.0 Page 4 of 64 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-244-0009 Report Limit Project:Mountain Village Park V 93945MW-1 101 09/07/2023 08:576200BIsopropylbenzeneµg/L 18.0 2470 09/07/2023 08:576200BMethyl tert-butyl ether (MTBE)µg/L 14.0 120 09/07/2023 08:576200B4-Methyl-2-Pentanone µg/L 7.80 816 09/07/2023 08:576200BNaphthaleneµg/L 47.0 320 09/07/2023 08:576200Bn-Propylbenzene µg/L 19.0 134 09/07/2023 08:576200BStyreneµg/L 22.0 J41809/07/2023 08:576200Btert-Butyl Alcohol (TBA)µg/L 160 4230 09/07/2023 08:576200Btert-Amyl Alcohol (TAA)µg/L 190 J27609/07/2023 08:576200Btert-Amyl Methyl Ether (TAME)µg/L 28.0 29900 09/07/2023 19:246200BTolueneµg/L 220 2670 09/07/2023 08:576200B1,2,4-Trimethylbenzene µg/L 19.0 666 09/07/2023 08:576200B1,3,5-Trimethylbenzene µg/L 18.0 4850 09/07/2023 08:576200Bo-Xylene µg/L 21.0 10400 09/07/2023 08:576200Bm,p-Xylene µg/L 42.0 15300 09/07/2023 08:576200BXylene (Total)µg/L 21.0 62.3 09/07/2023 14:14625.1 1-Methylnaphthalene µg/L 1.14 135 09/07/2023 14:14625.1 2-Methylnaphthalene µg/L 0.666 486 09/07/2023 15:00625.1 Naphthalene µg/L 2.91 J13009/12/2023 13:38MADEP-EPH Aliphatic C9-C18 µg/L 28.2 1270 09/12/2023 13:38MADEP-EPH Aromatic C11-C22 µg/L 61.2 70000 09/01/2023 19:34MADEP-VPH Aliphatic C5-C8 µg/L 1150 40000 09/01/2023 19:34MADEP-VPH Aliphatic C9-C12 µg/L 2580 6860 09/01/2023 19:34MADEP-VPH Aromatic C9-C10 µg/L 402 Page 5 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 13.2 %Moisture 1 09/05/23 11:43 SW-DRYWTCNC 27.9 mg/Kg - dry 0.979 2.88Chromium 5 09/06/23 13:15 6010DJKC 17.7 mg/Kg - dry 0.455 1.73Lead 5 09/06/23 13:15 6010DJKC Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 6 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5035 8260D Prep Batch(es):V37514 09/05/23 08:00 11.0 mg/Kg - dry 0.761 6.35Acetone 500 09/05/23 17:43 V37515TBL <0.383 mg/Kg - dry 0.383 6.35Acrolein 500 09/05/23 17:43 V37515TBL <0.238 mg/Kg - dry 0.238 6.35Acrylonitrile 500 09/05/23 17:43 V37515TBL 4.83 mg/Kg - dry 0.184 1.59Benzene 500 09/05/23 17:43 V37515TBL <0.158 mg/Kg - dry 0.158 1.59Bromobenzene 500 09/05/23 17:43 V37515TBL <0.254 mg/Kg - dry 0.254 1.59Bromochloromethane 500 09/05/23 17:43 V37515TBL <0.377 mg/Kg - dry 0.377 1.59Bromodichloromethane 500 09/05/23 17:43 V37515TBL <0.321 mg/Kg - dry 0.321 1.59Bromoform 500 09/05/23 17:43 V37515TBL <0.577 mg/Kg - dry 0.577 3.17 Bromomethane 500 09/05/23 17:43 V37515TBL 9.35 mg/Kg - dry 0.155 1.59n-Butylbenzene 500 09/05/23 17:43 V37515TBL 2.74 mg/Kg - dry 0.178 1.59sec-Butyl benzene 500 09/05/23 17:43 V37515TBL <0.158 mg/Kg - dry 0.158 1.59tert-Butyl benzene 500 09/05/23 17:43 V37515TBL <0.203 mg/Kg - dry 0.203 1.59Carbon Disulfide 500 09/05/23 17:43 V37515TBL <0.502 mg/Kg - dry 0.502 1.59Carbon Tetrachloride 500 09/05/23 17:43 V37515TBL <0.213 mg/Kg - dry 0.213 1.59Chlorobenzene 500 09/05/23 17:43 V37515TBL <0.283 mg/Kg - dry 0.283 1.59 Chlorodibromomethane 500 09/05/23 17:43 V37515TBL <0.282 mg/Kg - dry 0.282 3.17Chloroethane 500 09/05/23 17:43 V37515TBL <0.334 mg/Kg - dry 0.334 1.59Chloroform 500 09/05/23 17:43 V37515TBL <0.199 mg/Kg - dry 0.199 3.17Chloromethane 500 09/05/23 17:43 V37515TBL <0.162 mg/Kg - dry 0.162 1.592-Chlorotoluene 500 09/05/23 17:43 V37515TBL <0.124 mg/Kg - dry 0.124 1.594-Chlorotoluene 500 09/05/23 17:43 V37515TBL <0.231 mg/Kg - dry 0.231 1.59Di-Isopropyl Ether (DIPE)500 09/05/23 17:43 V37515TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 7 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5035 8260D Prep Batch(es):V37514 09/05/23 08:00 <0.139 mg/Kg - dry 0.139 3.171,2-Dibromo-3-Chloropropane 500 09/05/23 17:43 V37515TBL <0.187 mg/Kg - dry 0.187 1.591,2-Dibromoethane 500 09/05/23 17:43 V37515TBL <0.314 mg/Kg - dry 0.314 1.59Dibromomethane 500 09/05/23 17:43 V37515TBL <0.098 mg/Kg - dry 0.098 1.591,2-Dichlorobenzene 500 09/05/23 17:43 V37515TBL <0.120 mg/Kg - dry 0.120 1.591,3-Dichlorobenzene 500 09/05/23 17:43 V37515TBL <0.191 mg/Kg - dry 0.191 1.591,4-Dichlorobenzene 500 09/05/23 17:43 V37515TBL <0.418 mg/Kg - dry 0.418 3.17Dichlorodifluoromethane 500 09/05/23 17:43 V37515TBL <0.260 mg/Kg - dry 0.260 1.591,1-Dichloroethane 500 09/05/23 17:43 V37515TBL <0.438 mg/Kg - dry 0.438 1.59 1,2-Dichloroethane 500 09/05/23 17:43 V37515TBL <0.231 mg/Kg - dry 0.231 1.591,1-Dichloroethene 500 09/05/23 17:43 V37515TBL <0.251 mg/Kg - dry 0.251 1.59cis-1,2-Dichloroethene 500 09/05/23 17:43 V37515TBL <0.334 mg/Kg - dry 0.334 1.59trans-1,2-Dichloroethene 500 09/05/23 17:43 V37515TBL <0.139 mg/Kg - dry 0.139 1.591,2-Dichloropropane 500 09/05/23 17:43 V37515TBL <0.175 mg/Kg - dry 0.175 1.591,3-Dichloropropane 500 09/05/23 17:43 V37515TBL <0.404 mg/Kg - dry 0.404 1.592,2-Dichloropropane 500 09/05/23 17:43 V37515TBL <0.241 mg/Kg - dry 0.241 1.59 1,1-Dichloropropene 500 09/05/23 17:43 V37515TBL <0.171 mg/Kg - dry 0.171 1.59cis-1,3-Dichloropropene 500 09/05/23 17:43 V37515TBL <0.254 mg/Kg - dry 0.254 1.59trans-1,3-Dichloropropene 500 09/05/23 17:43 V37515TBL 50.0 mg/Kg - dry 0.184 1.59Ethylbenzene 500 09/05/23 17:43 V37515TBL <0.262 mg/Kg - dry 0.262 31.7Ethyl Tertiary Butyl Ether (ETBE)500 09/05/23 17:43 V37515TBL <0.250 mg/Kg - dry 0.250 3.17Hexachlorobutadiene 500 09/05/23 17:43 V37515TBL 19.4 mg/Kg - dry 0.209 3.17n-Hexane 500 09/05/23 17:43 V37515TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 8 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5035 8260D Prep Batch(es):V37514 09/05/23 08:00 <0.197 mg/Kg - dry 0.197 6.352-Hexanone 500 09/05/23 17:43 V37515TBL 5.15 mg/Kg - dry 0.146 1.59Isopropylbenzene 500 09/05/23 17:43 V37515TBL 1.51 J mg/Kg - dry 0.413 1.594-Isopropyl toluene 500 09/05/23 17:43 V37515TBL 63.1 mg/Kg - dry 0.206 6.35Methyl Ethyl Ketone (MEK)500 09/05/23 17:43 V37515TBL <0.197 mg/Kg - dry 0.197 1.59Methyl tert-butyl ether (MTBE)500 09/05/23 17:43 V37515TBL <4.76 mg/Kg - dry 4.76 6.354-Methyl-2-Pentanone 500 09/05/23 17:43 V37515TBL <0.467 mg/Kg - dry 0.467 1.59Methylene Chloride 500 09/05/23 17:43 V37515TBL 39.1 mg/Kg - dry 0.313 3.17Naphthalene 500 09/05/23 17:43 V37515TBL 23.5 mg/Kg - dry 0.171 1.59 n-Propylbenzene 500 09/05/23 17:43 V37515TBL 1.42 J mg/Kg - dry 0.451 1.59Styrene 500 09/05/23 17:43 V37515TBL <0.334 mg/Kg - dry 0.334 1.591,1,1,2-Tetrachloroethane 500 09/05/23 17:43 V37515TBL <0.101 mg/Kg - dry 0.101 1.591,1,2,2-Tetrachloroethane 500 09/05/23 17:43 V37515TBL <0.285 mg/Kg - dry 0.285 1.59Tetrachloroethene 500 09/05/23 17:43 V37515TBL 107 mg/Kg - dry 0.209 1.59Toluene 500 09/05/23 17:43 V37515TBL <0.171 mg/Kg - dry 0.171 3.171,2,3-Trichlorobenzene 500 09/05/23 17:43 V37515TBL <0.202 mg/Kg - dry 0.202 3.17 1,2,4-Trichlorobenzene 500 09/05/23 17:43 V37515TBL <0.457 mg/Kg - dry 0.457 1.591,1,1-Trichloroethane 500 09/05/23 17:43 V37515TBL <0.149 mg/Kg - dry 0.149 1.591,1,2-Trichloroethane 500 09/05/23 17:43 V37515TBL <0.292 mg/Kg - dry 0.292 1.59Trichloroethene 500 09/05/23 17:43 V37515TBL <0.662 mg/Kg - dry 0.662 3.17Trichlorofluoromethane 500 09/05/23 17:43 V37515TBL <0.229 mg/Kg - dry 0.229 1.591,2,3-Trichloropropane 500 09/05/23 17:43 V37515TBL 166 mg/Kg - dry 1.56 15.91,2,4-Trimethylbenzene 5000 09/06/23 19:38 V37515TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 9 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5035 8260D Prep Batch(es):V37514 09/05/23 08:00 48.8 mg/Kg - dry 0.171 1.591,3,5-Trimethylbenzene 500 09/05/23 17:43 V37515TBL <0.146 mg/Kg - dry 0.146 3.17Vinyl Acetate 500 09/05/23 17:43 V37515TBL <0.152 mg/Kg - dry 0.152 3.17Vinyl Chloride 500 09/05/23 17:43 V37515TBL 84.0 mg/Kg - dry 0.158 1.59o-Xylene 500 09/05/23 17:43 V37515TBL 190 mg/Kg - dry 0.399 3.17m,p-Xylene 500 09/05/23 17:43 V37515TBL 274 mg/Kg - dry 0.158 1.59Xylene (Total)500 09/05/23 17:43 V37515 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%09/05/23 17:43500 TBL V37515 Surrogate: Dibromofluoromethane 99.1 Limits: 70-130%09/05/23 17:43500 TBL V37515 Surrogate: Toluene-d8 98.5 Limits: 76-129%09/05/23 17:43500 TBL V37515 Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%09/06/23 19:385000 TBL V37515 Surrogate: Dibromofluoromethane 101 Limits: 70-130%09/06/23 19:385000 TBL V37515 Surrogate: Toluene-d8 98.9 Limits: 76-129%09/06/23 19:385000 TBL V37515 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V37540 09/07/23 10:00 <0.534 mg/Kg - dry 0.534 3.04Acenaphthene 4 09/08/23 19:05 V37578AMP <0.483 mg/Kg - dry 0.483 3.04Acenaphthylene 4 09/08/23 19:05 V37578AMP <0.700 mg/Kg - dry 0.700 3.04Aniline 4 09/08/23 19:05 V37578AMP <0.658 mg/Kg - dry 0.658 3.04Anthracene 4 09/08/23 19:05 V37578AMP <0.640 mg/Kg - dry 0.640 3.04Benzo(a)anthracene 4 09/08/23 19:05 V37578AMP <0.677 mg/Kg - dry 0.677 3.04Benzo(a)pyrene 4 09/08/23 19:05 V37578AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 10 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V37540 09/07/23 10:00 <0.672 mg/Kg - dry 0.672 3.04Benzo(b)fluoranthene 4 09/08/23 19:05 V37578AMP <0.626 mg/Kg - dry 0.626 3.04Benzo(g,h,i)perylene 4 09/08/23 19:05 V37578AMP <0.631 mg/Kg - dry 0.631 3.04Benzo(k)fluoranthene 4 09/08/23 19:05 V37578AMP <2.67 mg/Kg - dry 2.67 9.23Benzoic Acid 4 09/08/23 19:05 V37578AMP <0.483 mg/Kg - dry 0.483 3.04Benzyl alcohol 4 09/08/23 19:05 V37578AMP <0.543 mg/Kg - dry 0.543 3.04Bis(2-Chloroethoxy)methane 4 09/08/23 19:05 V37578AMP <0.493 mg/Kg - dry 0.493 3.04Bis(2-Chloroethyl)ether 4 09/08/23 19:05 V37578AMP <0.626 mg/Kg - dry 0.626 1.52Bis(2-Chloroisopropyl)ether 4 09/08/23 19:05 V37578AMP <0.552 mg/Kg - dry 0.552 3.04 Bis(2-ethylhexyl)phthalate 4 09/08/23 19:05 V37578AMP <0.502 mg/Kg - dry 0.502 3.044-Bromophenyl phenyl ether 4 09/08/23 19:05 V37578AMP <0.520 mg/Kg - dry 0.520 1.52Butyl benzyl phthalate 4 09/08/23 19:05 V37578AMP <0.426 mg/Kg - dry 0.426 3.044-Chloro-3-methylphenol 4 09/08/23 19:05 V37578AMP <0.516 mg/Kg - dry 0.516 1.524-Chloroaniline 4 09/08/23 19:05 V37578AMP <0.534 mg/Kg - dry 0.534 3.042-Chloronaphthalene 4 09/08/23 19:05 V37578AMP <0.452 mg/Kg - dry 0.452 3.042-Chlorophenol 4 09/08/23 19:05 V37578AMP <0.581 mg/Kg - dry 0.581 4.62 4-Chlorophenyl phenyl ether 4 09/08/23 19:05 V37578AMP <0.654 mg/Kg - dry 0.654 3.04Chrysene 4 09/08/23 19:05 V37578AMP <1.06 mg/Kg - dry 1.06 3.04Dibenz(a,h)anthracene 4 09/08/23 19:05 V37578AMP <0.548 mg/Kg - dry 0.548 3.04Dibenzofuran 4 09/08/23 19:05 V37578AMP <0.435 mg/Kg - dry 0.435 3.041,2-Dichlorobenzene 4 09/08/23 19:05 V37578AMP <0.448 mg/Kg - dry 0.448 3.041,3-Dichlorobenzene 4 09/08/23 19:05 V37578AMP <0.449 mg/Kg - dry 0.449 1.521,4-Dichlorobenzene 4 09/08/23 19:05 V37578AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 11 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V37540 09/07/23 10:00 <0.677 mg/Kg - dry 0.677 3.043,3'-Dichlorobenzidine 4 09/08/23 19:05 V37578AMP <0.441 mg/Kg - dry 0.441 3.042,4-Dichlorophenol 4 09/08/23 19:05 V37578AMP <0.829 mg/Kg - dry 0.829 3.04Diethyl phthalate 4 09/08/23 19:05 V37578AMP <0.801 mg/Kg - dry 0.801 3.04Dimethyl phthalate 4 09/08/23 19:05 V37578AMP <0.497 mg/Kg - dry 0.497 1.522,4-Dimethylphenol 4 09/08/23 19:05 V37578AMP <0.493 mg/Kg - dry 0.493 3.04Di-n-butyl phthalate 4 09/08/23 19:05 V37578AMP <1.11 mg/Kg - dry 1.11 6.924,6-Dinitro-2-methylphenol 4 09/08/23 19:05 V37578AMP <2.40 mg/Kg - dry 2.40 6.922,4-Dinitrophenol 4 09/08/23 19:05 V37578AMP <0.444 mg/Kg - dry 0.444 3.04 2,4-Dinitrotoluene 4 09/08/23 19:05 V37578AMP <0.497 mg/Kg - dry 0.497 3.042,6-Dinitrotoluene 4 09/08/23 19:05 V37578AMP <0.658 mg/Kg - dry 0.658 1.52Di-n-Octyl Phthalate 4 09/08/23 19:05 V37578AMP <0.566 mg/Kg - dry 0.566 3.04Fluoranthene 4 09/08/23 19:05 V37578AMP <0.589 mg/Kg - dry 0.589 3.04Fluorene 4 09/08/23 19:05 V37578AMP <0.488 mg/Kg - dry 0.488 3.04Hexachlorobenzene 4 09/08/23 19:05 V37578AMP <0.449 mg/Kg - dry 0.449 3.04Hexachlorobutadiene 4 09/08/23 19:05 V37578AMP <0.723 mg/Kg - dry 0.723 3.04 Hexachlorocyclopentadiene 4 09/08/23 19:05 V37578AMP <0.365 mg/Kg - dry 0.365 3.04Hexachloroethane 4 09/08/23 19:05 V37578AMP <0.824 mg/Kg - dry 0.824 3.04Indeno(1,2,3-cd)pyrene 4 09/08/23 19:05 V37578AMP <0.880 mg/Kg - dry 0.880 3.04Isophorone 4 09/08/23 19:05 V37578AMP 7.07 mg/Kg - dry 0.488 3.041-Methylnaphthalene 4 09/08/23 19:05 V37578AMP 16.7 mg/Kg - dry 0.460 3.042-Methylnaphthalene 4 09/08/23 19:05 V37578AMP <0.447 mg/Kg - dry 0.447 3.042-Methylphenol 4 09/08/23 19:05 V37578AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 12 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V37540 09/07/23 10:00 <0.391 mg/Kg - dry 0.391 3.043&4 Methylphenol 4 09/08/23 19:05 V37578AMP 18.1 mg/Kg - dry 0.663 3.04Naphthalene 4 09/08/23 19:05 V37578AMP <0.445 mg/Kg - dry 0.445 3.042-Nitroaniline 4 09/08/23 19:05 V37578AMP <0.552 mg/Kg - dry 0.552 3.043-Nitroaniline 4 09/08/23 19:05 V37578AMP <0.429 mg/Kg - dry 0.429 1.524-Nitroaniline 4 09/08/23 19:05 V37578AMP <0.534 mg/Kg - dry 0.534 1.52Nitrobenzene 4 09/08/23 19:05 V37578AMP <0.408 mg/Kg - dry 0.408 3.042-Nitrophenol 4 09/08/23 19:05 V37578AMP <0.539 mg/Kg - dry 0.539 3.044-Nitrophenol 4 09/08/23 19:05 V37578AMP <1.21 mg/Kg - dry 1.21 3.04 N-Nitrosodimethylamine 4 09/08/23 19:05 V37578AMP <0.834 mg/Kg - dry 0.834 3.04N-Nitrosodiphenylamine 4 09/08/23 19:05 V37578AMP <0.543 mg/Kg - dry 0.543 3.04N-Nitroso-di-n-propylamine 4 09/08/23 19:05 V37578AMP <1.60 mg/Kg - dry 1.60 4.62Pentachlorophenol 4 09/08/23 19:05 V37578AMP <0.958 mg/Kg - dry 0.958 3.04Phenanthrene 4 09/08/23 19:05 V37578AMP <0.516 mg/Kg - dry 0.516 3.04Phenol 4 09/08/23 19:05 V37578AMP <0.617 mg/Kg - dry 0.617 3.04Pyrene 4 09/08/23 19:05 V37578AMP <0.365 mg/Kg - dry 0.365 1.52 Pyridine 4 09/08/23 19:05 V37578AMP <0.493 mg/Kg - dry 0.493 3.041,2,4-Trichlorobenzene 4 09/08/23 19:05 V37578AMP <0.443 mg/Kg - dry 0.443 3.042,4,5-Trichlorophenol 4 09/08/23 19:05 V37578AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 13 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V37540 09/07/23 10:00 <0.444 mg/Kg - dry 0.444 3.042,4,6-Trichlorophenol 4 09/08/23 19:05 V37578AMP 8270ESurrogate: Phenol-d5 76.3 Limits: 34-121%09/08/23 19:054 AMP Surrogate: 2-Fluorobiphenyl 89.8 Limits: 44-115%09/08/23 19:054 AMP V37578 Surrogate: 2-Fluorophenol 85.6 Limits: 35-115%09/08/23 19:054 AMP V37578 Surrogate: Nitrobenzene-d5 87.4 Limits: 37-122%09/08/23 19:054 AMP V37578 Surrogate: 4-Terphenyl-d14 102 Limits: 54-127%09/08/23 19:054 AMP V37578 Surrogate: 2,4,6-Tribromophenol 99.4 Limits: 39-132%09/08/23 19:054 AMP V37578 Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 14 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93944 Matrix: 8/31/2023 10:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V37493 09/06/23 11:50 169 mg/Kg - dry 10.6 57.4Aliphatic C9-C18 1 09/13/23 10:46 V37620NDL <14.1 mg/Kg - dry 14.1 57.4Aliphatic C19-C36 1 09/13/23 10:46 V37620NDL 207 mg/Kg - dry 16.2 57.4Aromatic C11-C22 1 09/13/23 10:46 V37620NDL MADEP-EPHSurrogate: 2-Bromonaphthalene 88.7 Limits: 40-140%09/13/23 10:461 NDL MADEP-EPHSurrogate: Chlorooctadecane 65.6 Limits: 40-140%09/13/23 10:461 NDL MADEP-EPHSurrogate: OTP Surrogate 81.4 Limits: 40-140%09/13/23 10:461 NDL Surrogate: 2-Fluorobiphenyl 92.2 Limits: 40-140%09/13/23 10:461 NDL V37620 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAVPH (Prep) MADEP-VPH Prep Batch(es):V37396 09/01/23 08:00 885 mg/Kg - dry 7.00 46.1 Aliphatic C5-C8 500 09/02/23 05:23 V37397TBL 1200 mg/Kg - dry 26.3 46.1Aliphatic C9-C12 500 09/02/23 05:23 V37397TBL 696 mg/Kg - dry 3.59 46.1Aromatic C9-C10 500 09/02/23 05:23 V37397TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)86.0 Limits: 70-130%09/02/23 05:23500 TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)97.2 Limits: 70-130%09/02/23 05:23500 TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 15 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 100 10003,3-Dimethyl-1-butanol 100 09/07/23 08:57 6200BMSA 0.008 mg/L 0.002 0.005Chromium 1 09/06/23 19:24 6010DJKC <0.002 mg/L 0.002 0.006Lead 1 09/06/23 19:24 6010DJKC Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 16 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V37563 09/06/23 14:00 V37631 09/07/23 09:00 <180 µg/L 180 1000Acetone 100 09/07/23 08:57 V37564MSA 8230 µg/L 18.0 50.0Benzene 100 09/07/23 08:57 V37564MSA <21.0 µg/L 21.0 50.0Bromobenzene 100 09/07/23 08:57 V37564MSA <42.0 µg/L 42.0 100Bromochloromethane 100 09/07/23 08:57 V37564MSA <16.0 µg/L 16.0 50.0Bromodichloromethane 100 09/07/23 08:57 V37564MSA <150 µg/L 150 500Bromoform 100 09/07/23 08:57 V37564MSA <28.0 µg/L 28.0 100Bromomethane 100 09/07/23 08:57 V37564MSA 27.4 J µg/L 18.0 50.0n-Butylbenzene 100 09/07/23 08:57 V37564MSA <20.0 µg/L 20.0 50.0 sec-Butyl benzene 100 09/07/23 08:57 V37564MSA <92.0 µg/L 92.0 200tert-Butyl benzene 100 09/07/23 08:57 V37564MSA <18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 09/07/23 08:57 V37564MSA <19.0 µg/L 19.0 50.0Chlorobenzene 100 09/07/23 08:57 V37564MSA <19.0 µg/L 19.0 50.0Chlorodibromomethane 100 09/07/23 08:57 V37564MSA <43.0 µg/L 43.0 100Chloroethane 100 09/07/23 08:57 V37564MSA <22.0 µg/L 22.0 50.0Chloroform 100 09/07/23 08:57 V37564MSA <22.0 µg/L 22.0 50.0 Chloromethane 100 09/07/23 08:57 V37564MSA <20.0 µg/L 20.0 50.02-Chlorotoluene 100 09/07/23 08:57 V37564MSA <20.0 µg/L 20.0 50.04-Chlorotoluene 100 09/07/23 08:57 V37564MSA 873 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 09/07/23 08:57 V37564MSA <110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 09/07/23 08:57 V37564MSA <23.0 µg/L 23.0 50.0Dibromomethane 100 09/07/23 08:57 V37564MSA <22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 09/07/23 08:57 V37564MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 17 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V37563 09/06/23 14:00 V37631 09/07/23 09:00 <19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 09/07/23 08:57 V37564MSA <21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 09/07/23 08:57 V37564MSA <120 µg/L 120 500Dichlorodifluoromethane 100 09/07/23 08:57 V37564MSA <24.0 µg/L 24.0 50.01,1-Dichloroethane 100 09/07/23 08:57 V37564MSA <15.0 µg/L 15.0 50.01,2-Dichloroethane 100 09/07/23 08:57 V37564MSA <15.0 µg/L 15.0 50.01,1-Dichloroethene 100 09/07/23 08:57 V37564MSA <20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 09/07/23 08:57 V37564MSA <18.0 µg/L 18.0 50.0trans-1,2-Dichloroethene 100 09/07/23 08:57 V37564MSA <19.0 µg/L 19.0 50.0 1,2-Dichloropropane 100 09/07/23 08:57 V37564MSA <13.0 µg/L 13.0 50.01,3-Dichloropropane 100 09/07/23 08:57 V37564MSA <21.0 µg/L 21.0 2002,2-Dichloropropane 100 09/07/23 08:57 V37564MSA <20.0 µg/L 20.0 50.01,1-Dichloropropene 100 09/07/23 08:57 V37564MSA <21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 09/07/23 08:57 V37564MSA <15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 09/07/23 08:57 V37564MSA <4200 µg/L 4200 20000Ethanol 100 09/07/23 08:57 V37564MSA 3030 µg/L 17.0 50.0 Ethylbenzene 100 09/07/23 08:57 V37564MSA <5.90 µg/L 5.90 1000Ethyl Tertiary Butyl Ether (ETBE)100 09/07/23 08:57 V37564MSA <35.0 µg/L 35.0 300Hexachlorobutadiene 100 09/07/23 08:57 V37564MSA 290 µg/L 38.0 1002-Hexanone 100 09/07/23 08:57 V37564MSA 101 µg/L 18.0 50.0Isopropylbenzene 100 09/07/23 08:57 V37564MSA <8.90 µg/L 8.90 50.04-Isopropyl toluene 100 09/07/23 08:57 V37564MSA <71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 09/07/23 08:57 V37564MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 18 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V37563 09/06/23 14:00 V37631 09/07/23 09:00 2470 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 09/07/23 08:57 V37564MSA 120 µg/L 7.80 1004-Methyl-2-Pentanone 100 09/07/23 08:57 V37564MSA <33.0 µg/L 33.0 200Methylene Chloride 100 09/07/23 08:57 V37564MSA 816 µg/L 47.0 100Naphthalene 100 09/07/23 08:57 V37564MSA 320 µg/L 19.0 50.0n-Propylbenzene 100 09/07/23 08:57 V37564MSA 134 µg/L 22.0 50.0Styrene 100 09/07/23 08:57 V37564MSA 418 J µg/L 160 1000tert-Butyl Alcohol (TBA)100 09/07/23 08:57 V37564MSA <35.0 µg/L 35.0 1000tert-Butyl formate (TBF)100 09/07/23 08:57 V37564MSA 4230 µg/L 190 1000 tert-Amyl Alcohol (TAA)100 09/07/23 08:57 V37564MSA 276 J µg/L 28.0 1000tert-Amyl Methyl Ether (TAME)100 09/07/23 08:57 V37564MSA <16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 09/07/23 08:57 V37564MSA <16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 09/07/23 08:57 V37564MSA <22.0 µg/L 22.0 50.0Tetrachloroethene 100 09/07/23 08:57 V37564MSA 29900 µg/L 220 500Toluene 1000 09/07/23 19:24 V37632MSA <38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 09/07/23 08:57 V37564MSA <31.0 µg/L 31.0 50.0 1,2,4-Trichlorobenzene 100 09/07/23 08:57 V37564MSA <16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 09/07/23 08:57 V37564MSA <9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 09/07/23 08:57 V37564MSA <18.0 µg/L 18.0 50.0Trichloroethene 100 09/07/23 08:57 V37564MSA <18.0 µg/L 18.0 50.0Trichlorofluoromethane 100 09/07/23 08:57 V37564MSA <27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 09/07/23 08:57 V37564MSA 2670 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 09/07/23 08:57 V37564MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 19 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V37563 09/06/23 14:00 V37631 09/07/23 09:00 666 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 09/07/23 08:57 V37564MSA <100 µg/L 100 500Vinyl Acetate 100 09/07/23 08:57 V37564MSA <17.0 µg/L 17.0 50.0Vinyl Chloride 100 09/07/23 08:57 V37564MSA 4850 µg/L 21.0 50.0o-Xylene 100 09/07/23 08:57 V37564MSA 10400 µg/L 42.0 100m,p-Xylene 100 09/07/23 08:57 V37564MSA 15300 µg/L 21.0 50.0Xylene (Total)100 09/07/23 08:57 V37564 Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%09/07/23 08:57100 MSA V37564 Surrogate: Dibromofluoromethane 97.0 Limits: 70-130%09/07/23 08:57100 MSA V37564 Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%09/07/23 08:57100 MSA V37564 Surrogate: Toluene-d8 98.2 Limits: 70-130%09/07/23 08:57100 MSA V37564 Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%09/07/23 19:241000 MSA V37632 Surrogate: Dibromofluoromethane 98.4 Limits: 70-130%09/07/23 19:241000 MSA V37632 Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%09/07/23 19:241000 MSA V37632 Surrogate: Toluene-d8 97.4 Limits: 70-130%09/07/23 19:241000 MSA V37632 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V37482 09/06/23 10:05 <0.302 µg/L 0.302 2.00Acenaphthene 1 09/07/23 14:14 V37519AMP <0.297 µg/L 0.297 2.00Acenaphthylene 1 09/07/23 14:14 V37519AMP <0.836 µg/L 0.836 2.00Anthracene 1 09/07/23 14:14 V37519AMP <1.32 µg/L 1.32 10.0Benzidine 1 09/07/23 14:14 V37519AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 20 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V37482 09/06/23 10:05 <0.637 µg/L 0.637 2.00Benzo(a)anthracene 1 09/07/23 14:14 V37519AMP <1.02 µg/L 1.02 2.00Benzo(a)pyrene 1 09/07/23 14:14 V37519AMP <2.49 µg/L 2.49 5.00Benzo(b)fluoranthene 1 09/07/23 14:14 V37519AMP <1.01 µg/L 1.01 5.00Benzo(g,h,i)perylene 1 09/07/23 14:14 V37519AMP <1.99 µg/L 1.99 5.00Benzo(k)fluoranthene 1 09/07/23 14:14 V37519AMP <1.10 µg/L 1.10 10.0Benzoic Acid 1 09/07/23 14:14 V37519AMP <0.684 µg/L 0.684 5.00Benzyl alcohol 1 09/07/23 14:14 V37519AMP <0.468 µg/L 0.468 5.00Bis(2-Chloroethoxy)methane 1 09/07/23 14:14 V37519AMP <1.04 µg/L 1.04 5.00 Bis(2-Chloroethyl)ether 1 09/07/23 14:14 V37519AMP <1.08 µg/L 1.08 5.00Bis(2-Chloroisopropyl)ether 1 09/07/23 14:14 V37519AMP <3.46 µg/L 3.46 10.0Bis(2-ethylhexyl)phthalate 1 09/07/23 14:14 V37519AMP <1.11 µg/L 1.11 5.004-Bromophenyl phenyl ether 1 09/07/23 14:14 V37519AMP <1.83 µg/L 1.83 5.00Butyl benzyl phthalate 1 09/07/23 14:14 V37519AMP <1.18 µg/L 1.18 5.004-Chloro-3-methylphenol 1 09/07/23 14:14 V37519AMP <7.38 µg/L 7.38 20.02-Chloronaphthalene 1 09/07/23 14:14 V37519AMP <0.938 µg/L 0.938 10.0 2-Chlorophenol 1 09/07/23 14:14 V37519AMP <1.71 µg/L 1.71 5.004-Chlorophenyl phenyl ether 1 09/07/23 14:14 V37519AMP <0.405 µg/L 0.405 2.00Chrysene 1 09/07/23 14:14 V37519AMP <0.434 µg/L 0.434 2.00Dibenz(a,h)anthracene 1 09/07/23 14:14 V37519AMP <0.856 µg/L 0.856 5.00Dibenzofuran 1 09/07/23 14:14 V37519AMP <2.00 µg/L 2.00 5.001,2-Dichlorobenzene 1 09/07/23 14:14 V37519AMP <2.00 µg/L 2.00 5.001,3-Dichlorobenzene 1 09/07/23 14:14 V37519AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 21 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V37482 09/06/23 10:05 <2.05 µg/L 2.05 5.001,4-Dichlorobenzene 1 09/07/23 14:14 V37519AMP <1.89 µg/L 1.89 5.003,3'-Dichlorobenzidine 1 09/07/23 14:14 V37519AMP <1.46 µg/L 1.46 10.02,4-Dichlorophenol 1 09/07/23 14:14 V37519AMP <0.745 µg/L 0.745 5.00Diethyl phthalate 1 09/07/23 14:14 V37519AMP <0.939 µg/L 0.939 5.00Dimethyl phthalate 1 09/07/23 14:14 V37519AMP <1.57 µg/L 1.57 20.02,4-Dimethylphenol 1 09/07/23 14:14 V37519AMP <2.06 µg/L 2.06 5.00Di-n-butyl phthalate 1 09/07/23 14:14 V37519AMP <2.07 µg/L 2.07 10.04,6-Dinitro-2-methylphenol 1 09/07/23 14:14 V37519AMP <1.92 µg/L 1.92 10.0 2,4-Dinitrophenol 1 09/07/23 14:14 V37519AMP <1.11 µg/L 1.11 5.002,4-Dinitrotoluene 1 09/07/23 14:14 V37519AMP <0.809 µg/L 0.809 5.002,6-Dinitrotoluene 1 09/07/23 14:14 V37519AMP <1.65 µg/L 1.65 5.00Di-n-Octyl Phthalate 1 09/07/23 14:14 V37519AMP <0.250 µg/L 0.250 2.00Fluoranthene 1 09/07/23 14:14 V37519AMP <0.807 µg/L 0.807 2.00Fluorene 1 09/07/23 14:14 V37519AMP <0.979 µg/L 0.979 5.00Hexachlorobenzene 1 09/07/23 14:14 V37519AMP <2.73 µg/L 2.73 5.00 Hexachlorobutadiene 1 09/07/23 14:14 V37519AMP <2.05 µg/L 2.05 5.00Hexachlorocyclopentadiene 1 09/07/23 14:14 V37519AMP <1.76 µg/L 1.76 5.00Hexachloroethane 1 09/07/23 14:14 V37519AMP <0.477 µg/L 0.477 2.00Indeno(1,2,3-cd)pyrene 1 09/07/23 14:14 V37519AMP <0.444 µg/L 0.444 5.00Isophorone 1 09/07/23 14:14 V37519AMP 62.3 µg/L 1.14 2.001-Methylnaphthalene 1 09/07/23 14:14 V37519AMP 135 µg/L 0.666 2.002-Methylnaphthalene 1 09/07/23 14:14 V37519AMP Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 22 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V37482 09/06/23 10:05 486 µg/L 2.91 8.00Naphthalene 4 09/07/23 15:00 V37519AMP <0.905 µg/L 0.905 5.00Nitrobenzene 1 09/07/23 14:14 V37519AMP <0.493 µg/L 0.493 5.002-Nitrophenol 1 09/07/23 14:14 V37519AMP <1.23 µg/L 1.23 10.04-Nitrophenol 1 09/07/23 14:14 V37519AMP <1.10 µg/L 1.10 5.00N-Nitrosodiphenylamine 1 09/07/23 14:14 V37519AMP <0.641 µg/L 0.641 5.00N-Nitroso-di-n-propylamine 1 09/07/23 14:14 V37519AMP <1.43 µg/L 1.43 5.00Pentachlorophenol 1 09/07/23 14:14 V37519AMP <0.428 µg/L 0.428 2.00Phenanthrene 1 09/07/23 14:14 V37519AMP <0.651 µg/L 0.651 5.00 Phenol 1 09/07/23 14:14 V37519AMP <0.434 µg/L 0.434 2.00Pyrene 1 09/07/23 14:14 V37519AMP <2.21 µg/L 2.21 5.001,2,4-Trichlorobenzene 1 09/07/23 14:14 V37519AMP <1.32 µg/L 1.32 5.002,4,6-Trichlorophenol 1 09/07/23 14:14 V37519AMP Surrogate: 2-Fluorobiphenyl 63.2 Limits: 49-118%09/07/23 14:141 AMP V37519 Surrogate: Nitrobenzene-d5 76.8 Limits: 43-123%09/07/23 14:141 AMP V37519 Surrogate: 4-Terphenyl-d14 71.2 Limits: 49-151%09/07/23 14:141 AMP V37519 Surrogate: 2,4,6-Tribromophenol 60.3 Limits: 31-144%09/07/23 14:141 AMP V37519 625.1Surrogate: Phenol-d5 29.9 Limits: 10-63%09/07/23 15:004 AMP Surrogate: 2-Fluorobiphenyl 58.8 Limits: 49-118%09/07/23 15:004 AMP V37519 Surrogate: 2-Fluorophenol 48.5 Limits: 22-84%09/07/23 15:004 AMP V37519 Surrogate: Nitrobenzene-d5 74.6 Limits: 43-123%09/07/23 15:004 AMP V37519 Surrogate: 4-Terphenyl-d14 66.2 Limits: 49-151%09/07/23 15:004 AMP V37519 Surrogate: 2,4,6-Tribromophenol 50.4 Limits: 31-144%09/07/23 15:004 AMP V37519 Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 23 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF EPA-504.1(PREP) EPA-504.1 Prep Batch(es):V37608 09/08/23 12:55 <0.00343 µg/L 0.00343 0.02081,2-Dibromoethane 1 09/08/23 17:48 V37661TJW Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 24 of 64 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-244-0009 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 09/01/2023 Mountain Village Park Report Date : 09/14/2023 Sample ID : Lab No : Sampled:MW-1 93945 Matrix: 8/31/2023 11:00 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V37556 09/07/23 15:11 130 J µg/L 28.2 350Aliphatic C9-C18 1 09/12/23 13:38 V37698NDL <124 µg/L 124 500Aliphatic C19-C36 1 09/12/23 13:38 V37698NDL 1270 µg/L 61.2 250Aromatic C11-C22 1 09/12/23 13:38 V37698NDL MADEP-EPHSurrogate: 2-Bromonaphthalene 97.0 Limits: 40-140%09/12/23 13:381 NDL MADEP-EPHSurrogate: Chlorooctadecane 45.5 Limits: 40-140%09/12/23 13:381 NDL MADEP-EPHSurrogate: OTP Surrogate 59.3 Limits: 40-140%09/12/23 13:381 NDL Surrogate: 2-Fluorobiphenyl 99.5 Limits: 40-140%09/12/23 13:381 NDL V37698 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAVPH (Prep) MADEP-VPH Prep Batch(es):V37398 09/01/23 08:00 70000 µg/L 1150 5000 Aliphatic C5-C8 100 09/01/23 19:34 V37399TBL 40000 µg/L 2580 5000Aliphatic C9-C12 100 09/01/23 19:34 V37399TBL 6860 µg/L 402 5000Aromatic C9-C10 100 09/01/23 19:34 V37399TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)79.4 Limits: 70-130%09/01/23 19:34100 TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)87.5 Limits: 70-130%09/01/23 19:34100 TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 25 of 64 Sample ID Report Lab NoLRB-V37482 23-244-0009 LRB Paramater Result Units Dilution Factor Method Analysis Date/Time Analyst Batch ID Triphenylphosphine oxide 17630 ug/L 1 625 9/7/2023 12:21 APANN V37519 Sample ID Report Lab NoMW-1 23-244-0009 93945 Paramater Result Units Dilution Factor Method Analysis Date/Time Analyst Batch ID Amylene Hydrate 200540 ug/L 1 625 9/7/2023 14:14 APANN V37519 Benzene 192230 ug/L 1 625 9/7/2023 14:14 APANN V37519 2-Pentanol, 2-methyl-285230 ug/L 1 625 9/7/2023 14:14 APANN V37519 3-Pentanol, 3-methyl-231440 ug/L 1 625 9/7/2023 14:14 APANN V37519 Toluene 1550940 ug/L 1 625 9/7/2023 14:14 APANN V37519 Cyclopentanol, methyl-258870 ug/L 1 625 9/7/2023 14:14 APANN V37519 p-Xylene 700480 ug/L 1 625 9/7/2023 14:14 APANN V37519 Benzene, trimethyl-577260 ug/L 1 625 9/7/2023 14:14 APANN V37519 Indane 359320 ug/L 1 625 9/7/2023 14:14 APANN V37519 Page 26 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Metals Analysis 6010D V37476QC Analytical Batch(es): Analysis Method: Analysis Description: 3050B QC Prep:V37405 Associated Lab Samples: 93944 LRB-V37405 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits 09/05/23 19:260.5000.170<0.170mg/KgChromium 09/05/23 19:260.3000.079<0.079mg/KgLead LCS-V37405Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10552.550.0mg/KgChromium 80-120 1045.215.00mg/KgLead 80-120 V 93941-MS-V37405 V 93941-MSD-V37405Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 47.6 90.049.849.549.53.10mg/KgChromium 94.0 75-125 4.5 20 38.0 166*36.74.954.9529.8mg/KgLead 139*75-125 3.4 20 V 93941-PDS-V37405Post Digestion Spike Parameter Analyzed% Recovery PDS ResultUnits 09/05/23 19:56101128mg/KgChromium 09/05/23 19:5610127.6mg/KgLead Page 1 of 36* QC Fail Date:09/14/2023 08:12 AM Page 27 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Metals Analysis 6010D V37523QC Analytical Batch(es): Analysis Method: Analysis Description: 3005A QC Prep:V37471 Associated Lab Samples: 93945 LRB-V37471 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits 09/06/23 18:080.0050.002<0.002mg/LChromium 09/06/23 18:080.0060.002<0.002mg/LLead LCS-V37471Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1071.071.00mg/LChromium 80-120 1060.1060.100mg/LLead 80-120 V 94259-MS-V37471 V 94259-MSD-V37471Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.07 1071.071.001.000.002mg/LChromium 107 75-125 0.0 20.0 0.105 1050.1050.1000.100< 0.002mg/LLead 105 75-125 0.0 20.0 V 94259-PDS-V37471Post Digestion Spike Parameter Analyzed% Recovery PDS ResultUnits 09/06/23 18:391122.81mg/LChromium 09/06/23 18:391110.276mg/LLead Page 2 of 36Date:09/14/2023 08:12 AM Page 28 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 Associated Lab Samples: 93945 LRB-V37563 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 01:3010.01.80<1.80µg/LAcetone 09/07/23 01:300.5000.180<0.180µg/LBenzene 09/07/23 01:300.5000.210<0.210µg/LBromobenzene 09/07/23 01:301.000.420<0.420µg/LBromochloromethane 09/07/23 01:300.5000.160<0.160µg/LBromodichloromethane 09/07/23 01:305.001.50<1.50µg/LBromoform 09/07/23 01:301.000.280<0.280µg/LBromomethane 09/07/23 01:300.5000.180<0.180µg/Ln-Butylbenzene 09/07/23 01:300.5000.200<0.200µg/Lsec-Butyl benzene 09/07/23 01:302.000.920<0.920µg/Ltert-Butyl benzene 09/07/23 01:300.5000.180<0.180µg/LCarbon Tetrachloride 09/07/23 01:300.5000.190<0.190µg/LChlorobenzene 09/07/23 01:300.5000.190<0.190µg/LChlorodibromomethane 09/07/23 01:301.000.430<0.430µg/LChloroethane 09/07/23 01:300.5000.220<0.220µg/LChloroform 09/07/23 01:300.5000.220<0.220µg/LChloromethane 09/07/23 01:300.5000.200<0.200µg/L2-Chlorotoluene 09/07/23 01:300.5000.200<0.200µg/L4-Chlorotoluene 09/07/23 01:300.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE) 09/07/23 01:302.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane 09/07/23 01:300.5000.230<0.230µg/LDibromomethane 09/07/23 01:300.5000.220<0.220µg/L1,2-Dichlorobenzene 09/07/23 01:300.5000.190<0.190µg/L1,3-Dichlorobenzene 09/07/23 01:300.5000.210<0.210µg/L1,4-Dichlorobenzene 09/07/23 01:305.001.20<1.20µg/LDichlorodifluoromethane 09/07/23 01:300.5000.240<0.240µg/L1,1-Dichloroethane 09/07/23 01:300.5000.150<0.150µg/L1,2-Dichloroethane Page 3 of 36Date:09/14/2023 08:12 AM Page 29 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 Associated Lab Samples: 93945 LRB-V37563 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 01:300.5000.150<0.150µg/L1,1-Dichloroethene 09/07/23 01:300.5000.200<0.200µg/Lcis-1,2-Dichloroethene 09/07/23 01:300.5000.180<0.180µg/Ltrans-1,2-Dichloroethene 09/07/23 01:300.5000.190<0.190µg/L1,2-Dichloropropane 09/07/23 01:300.5000.130<0.130µg/L1,3-Dichloropropane 09/07/23 01:302.000.210<0.210µg/L2,2-Dichloropropane 09/07/23 01:300.5000.200<0.200µg/L1,1-Dichloropropene 09/07/23 01:300.5000.210<0.210µg/Lcis-1,3-Dichloropropene 09/07/23 01:300.5000.150<0.150µg/Ltrans-1,3-Dichloropropene 09/07/23 01:3020042.0<42.0µg/LEthanol 09/07/23 01:300.5000.170<0.170µg/LEthylbenzene 09/07/23 01:3010.00.059<0.059µg/LEthyl Tertiary Butyl Ether (ETBE) 09/07/23 01:303.000.350<0.350µg/LHexachlorobutadiene 09/07/23 01:301.000.380<0.380µg/L2-Hexanone 09/07/23 01:300.5000.180<0.180µg/LIsopropylbenzene 09/07/23 01:300.5000.089<0.089µg/L4-Isopropyl toluene 09/07/23 01:305.000.710<0.710µg/LMethyl Ethyl Ketone (MEK) 09/07/23 01:301.000.140<0.140µg/LMethyl tert-butyl ether (MTBE) 09/07/23 01:301.000.078<0.078µg/L4-Methyl-2-Pentanone 09/07/23 01:302.000.330<0.330µg/LMethylene Chloride 09/07/23 01:301.000.470<0.470µg/LNaphthalene 09/07/23 01:300.5000.190<0.190µg/Ln-Propylbenzene 09/07/23 01:300.5000.220<0.220µg/LStyrene 09/07/23 01:3010.01.60<1.60µg/Ltert-Butyl Alcohol (TBA) 09/07/23 01:3010.00.350<0.350µg/Ltert-Butyl formate (TBF) 09/07/23 01:3010.01.90<1.90µg/Ltert-Amyl Alcohol (TAA) 09/07/23 01:3010.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME) Page 4 of 36Date:09/14/2023 08:12 AM Page 30 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 Associated Lab Samples: 93945 LRB-V37563 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 01:300.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane 09/07/23 01:300.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane 09/07/23 01:300.5000.220<0.220µg/LTetrachloroethene 09/07/23 01:300.5000.380<0.380µg/L1,2,3-Trichlorobenzene 09/07/23 01:300.5000.310<0.310µg/L1,2,4-Trichlorobenzene 09/07/23 01:300.5000.160<0.160µg/L1,1,1-Trichloroethane 09/07/23 01:300.5000.096<0.096µg/L1,1,2-Trichloroethane 09/07/23 01:300.5000.180<0.180µg/LTrichloroethene 09/07/23 01:300.5000.180<0.180µg/LTrichlorofluoromethane 09/07/23 01:300.5000.270<0.270µg/L1,2,3-Trichloropropane 09/07/23 01:300.5000.190<0.190µg/L1,2,4-Trimethylbenzene 09/07/23 01:300.5000.180<0.180µg/L1,3,5-Trimethylbenzene 09/07/23 01:305.001.00<1.00µg/LVinyl Acetate 09/07/23 01:300.5000.170<0.170µg/LVinyl Chloride 09/07/23 01:300.5000.210<0.210µg/Lo-Xylene 09/07/23 01:301.000.420<0.420µg/Lm,p-Xylene 09/07/23 01:3010.01.00<1.00µg/L3,3-Dimethyl-1-butanol 09/07/23 01:304-Bromofluorobenzene (S)102 70-130 09/07/23 01:30Dibromofluoromethane (S)99.0 70-130 09/07/23 01:301,2-Dichloroethane - d4 (S)96.6 70-130 09/07/23 01:30Toluene-d8 (S)100 70-130 LCS-V37563 LCSD-V37563Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 28.9 72.267.527.040.0µg/LAcetone 40-160 6.7 20.0 Page 5 of 36Date:09/14/2023 08:12 AM Page 31 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 LCS-V37563 LCSD-V37563Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 22.1 11111122.220.0µg/LBenzene 70-130 0.4 20.0 21.7 10910821.520.0µg/LBromobenzene 70-130 0.9 20.0 21.4 10710520.920.0µg/LBromochloromethane 70-130 2.3 20.0 21.1 10610420.820.0µg/LBromodichloromethane 70-130 1.4 20.0 19.7 98.598.019.620.0µg/LBromoform 70-130 0.5 20.0 22.3 11211021.920.0µg/LBromomethane 60-140 1.8 20.0 21.7 10910821.620.0µg/Ln-Butylbenzene 70-130 0.4 20.0 21.1 10610721.320.0µg/Lsec-Butyl benzene 70-130 0.9 20.0 21.2 10610621.120.0µg/Ltert-Butyl benzene 70-130 0.4 20.0 22.0 11011022.020.0µg/LCarbon Tetrachloride 70-130 0.0 20.0 21.4 10710821.620.0µg/LChlorobenzene 70-130 0.9 20.0 21.1 10610320.620.0µg/LChlorodibromomethane 70-130 2.3 20.0 22.2 11111322.520.0µg/LChloroethane 60-140 1.3 20.0 21.3 10710621.120.0µg/LChloroform 70-130 0.9 20.0 19.5 97.510120.120.0µg/LChloromethane 60-140 3.0 20.0 21.5 10810721.320.0µg/L2-Chlorotoluene 70-130 0.9 20.0 21.6 10810921.820.0µg/L4-Chlorotoluene 70-130 0.9 20.0 21.3 10710621.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.4 20.0 23.1 11610721.320.0µg/L1,2-Dibromo-3-Chloropropane 70-130 8.1 20.0 21.8 10910320.620.0µg/LDibromomethane 70-130 5.6 20.0 22.1 11110921.720.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0 21.4 10710621.220.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0 21.3 10710621.120.0µg/L1,4-Dichlorobenzene 70-130 0.9 20.0 21.2 10610821.620.0µg/LDichlorodifluoromethane 60-140 1.8 20.0 21.9 11011022.020.0µg/L1,1-Dichloroethane 70-130 0.4 20.0 20.7 10410320.520.0µg/L1,2-Dichloroethane 70-130 0.9 20.0 Page 6 of 36Date:09/14/2023 08:12 AM Page 32 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 LCS-V37563 LCSD-V37563Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 23.2 11611523.020.0µg/L1,1-Dichloroethene 70-130 0.8 20.0 22.0 11011022.020.0µg/Lcis-1,2-Dichloroethene 70-130 0.0 20.0 22.4 11211122.120.0µg/Ltrans-1,2-Dichloroethene 70-130 1.3 20.0 21.7 10910821.520.0µg/L1,2-Dichloropropane 70-130 0.9 20.0 21.3 10710521.020.0µg/L1,3-Dichloropropane 70-130 1.4 20.0 19.6 98.098.519.720.0µg/L2,2-Dichloropropane 70-130 0.5 20.0 23.4 11711723.320.0µg/L1,1-Dichloropropene 70-130 0.4 20.0 21.3 10710621.120.0µg/Lcis-1,3-Dichloropropene 70-130 0.9 20.0 21.6 10810621.120.0µg/Ltrans-1,3-Dichloropropene 70-130 2.3 20.0 491 98.298.6493500µg/LEthanol 60-140 0.4 20.0 21.5 10810721.420.0µg/LEthylbenzene 70-130 0.4 20.0 46.0 11511445.440.0µg/LEthyl Tertiary Butyl Ether (ETBE)70-130 1.3 20.0 21.1 10610420.820.0µg/LHexachlorobutadiene 70-130 1.4 20.0 19.8 99.092.518.520.0µg/L2-Hexanone 60-140 6.7 20.0 22.2 11111021.920.0µg/LIsopropylbenzene 70-130 1.3 20.0 21.7 10910921.720.0µg/L4-Isopropyl toluene 70-130 0.0 20.0 19.4 97.089.517.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 8.0 20.0 21.9 11010721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.3 20.0 21.7 10910120.120.0µg/L4-Methyl-2-Pentanone 60-140 7.6 20.0 21.8 10911022.020.0µg/LMethylene Chloride 70-130 0.9 20.0 24.6 12311823.520.0µg/LNaphthalene 70-130 4.5 20.0 22.0 11011021.920.0µg/Ln-Propylbenzene 70-130 0.4 20.0 21.6 10810821.520.0µg/LStyrene 70-130 0.4 20.0 42.8 10710542.040.0µg/Ltert-Butyl Alcohol (TBA)40-140 1.8 20.0 37.1 92.710240.740.0µg/Ltert-Butyl formate (TBF)40-140 9.2 20.0 17.5 87.588.517.720.0µg/Ltert-Amyl Alcohol (TAA)40-140 1.1 20.0 Page 7 of 36Date:09/14/2023 08:12 AM Page 33 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37564QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37563 LCS-V37563 LCSD-V37563Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 44.8 11211043.940.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 2.0 20.0 21.7 10911021.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0 20.9 10510120.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.4 20.0 21.6 10810821.520.0µg/LTetrachloroethene 70-130 0.4 20.0 27.4 137*12825.520.0µg/L1,2,3-Trichlorobenzene 70-130 7.1 20.0 23.6 11811522.920.0µg/L1,2,4-Trichlorobenzene 70-130 3.0 20.0 21.8 10910921.820.0µg/L1,1,1-Trichloroethane 70-130 0.0 20.0 21.5 10810521.020.0µg/L1,1,2-Trichloroethane 70-130 2.3 20.0 22.8 11411222.420.0µg/LTrichloroethene 70-130 1.7 20.0 22.2 11111222.320.0µg/LTrichlorofluoromethane 60-140 0.4 20.0 22.1 11110220.420.0µg/L1,2,3-Trichloropropane 70-130 8.0 20.0 21.8 10910821.620.0µg/L1,2,4-Trimethylbenzene 70-130 0.9 20.0 21.7 10910921.720.0µg/L1,3,5-Trimethylbenzene 70-130 0.0 20.0 17.0 85.098.519.720.0µg/LVinyl Acetate 60-140 14.7 20.0 23.2 11611823.520.0µg/LVinyl Chloride 60-140 1.2 20.0 21.3 10710721.320.0µg/Lo-Xylene 70-130 0.0 20.0 45.9 11511546.140.0µg/Lm,p-Xylene 70-130 0.4 20.0 17.8 89.082.516.520.0µg/L3,3-Dimethyl-1-butanol 70-130 7.5 20.0 10099.04-Bromofluorobenzene (S)70-130 98.697.6Dibromofluoromethane (S)70-130 99.899.41,2-Dichloroethane - d4 (S)70-130 99.4101Toluene-d8 (S)70-130 Page 8 of 36* QC Fail Date:09/14/2023 08:12 AM Page 34 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V37632QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V37631 Associated Lab Samples: 93945 LRB-V37631 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 13:370.5000.220<0.220µg/LToluene 09/07/23 13:374-Bromofluorobenzene (S)99.2 70-130 09/07/23 13:37Dibromofluoromethane (S)98.6 70-130 09/07/23 13:371,2-Dichloroethane - d4 (S)96.0 70-130 09/07/23 13:37Toluene-d8 (S)97.2 70-130 LCS-V37631 LCSD-V37631Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 22.3 11211422.820.0µg/LToluene 70-130 2.2 20.0 99.299.84-Bromofluorobenzene (S)70-130 97.297.4Dibromofluoromethane (S)70-130 97.697.21,2-Dichloroethane - d4 (S)70-130 99.499.4Toluene-d8 (S)70-130 Page 9 of 36Date:09/14/2023 08:12 AM Page 35 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 Associated Lab Samples: 93945 LRB-V37482 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 12:212.000.302<0.302µg/LAcenaphthene 09/07/23 12:212.000.297<0.297µg/LAcenaphthylene 09/07/23 12:212.000.836<0.836µg/LAnthracene 09/07/23 12:2110.01.32<1.32µg/LBenzidine 09/07/23 12:212.000.637<0.637µg/LBenzo(a)anthracene 09/07/23 12:212.001.02<1.02µg/LBenzo(a)pyrene 09/07/23 12:215.002.49<2.49µg/LBenzo(b)fluoranthene 09/07/23 12:215.001.01<1.01µg/LBenzo(g,h,i)perylene 09/07/23 12:215.001.99<1.99µg/LBenzo(k)fluoranthene 09/07/23 12:2110.01.10<1.10µg/LBenzoic Acid 09/07/23 12:215.000.684<0.684µg/LBenzyl alcohol 09/07/23 12:215.000.468<0.468µg/LBis(2-Chloroethoxy)methane 09/07/23 12:215.001.04<1.04µg/LBis(2-Chloroethyl)ether 09/07/23 12:215.001.08<1.08µg/LBis(2-Chloroisopropyl)ether 09/07/23 12:2110.03.46<3.46µg/LBis(2-ethylhexyl)phthalate 09/07/23 12:215.001.11<1.11µg/L4-Bromophenyl phenyl ether 09/07/23 12:215.001.83<1.83µg/LButyl benzyl phthalate 09/07/23 12:215.001.18<1.18µg/L4-Chloro-3-methylphenol 09/07/23 12:2120.07.38<7.38µg/L2-Chloronaphthalene 09/07/23 12:2110.00.938<0.938µg/L2-Chlorophenol 09/07/23 12:215.001.71<1.71µg/L4-Chlorophenyl phenyl ether 09/07/23 12:212.000.405<0.405µg/LChrysene 09/07/23 12:212.000.434<0.434µg/LDibenz(a,h)anthracene 09/07/23 12:215.000.856<0.856µg/LDibenzofuran 09/07/23 12:215.002.00<2.00µg/L1,2-Dichlorobenzene 09/07/23 12:215.002.00<2.00µg/L1,3-Dichlorobenzene 09/07/23 12:215.002.05<2.05µg/L1,4-Dichlorobenzene Page 10 of 36Date:09/14/2023 08:12 AM Page 36 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 Associated Lab Samples: 93945 LRB-V37482 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 12:215.001.89<1.89µg/L3,3'-Dichlorobenzidine 09/07/23 12:2110.01.46<1.46µg/L2,4-Dichlorophenol 09/07/23 12:215.000.745<0.745µg/LDiethyl phthalate 09/07/23 12:215.000.939<0.939µg/LDimethyl phthalate 09/07/23 12:2120.01.57<1.57µg/L2,4-Dimethylphenol 09/07/23 12:215.002.06<2.06µg/LDi-n-butyl phthalate 09/07/23 12:2110.02.07<2.07µg/L4,6-Dinitro-2-methylphenol 09/07/23 12:2110.01.92<1.92µg/L2,4-Dinitrophenol 09/07/23 12:215.001.11<1.11µg/L2,4-Dinitrotoluene 09/07/23 12:215.000.809<0.809µg/L2,6-Dinitrotoluene 09/07/23 12:215.001.65<1.65µg/LDi-n-Octyl Phthalate 09/07/23 12:212.000.250<0.250µg/LFluoranthene 09/07/23 12:212.000.807<0.807µg/LFluorene 09/07/23 12:215.000.979<0.979µg/LHexachlorobenzene 09/07/23 12:215.002.73<2.73µg/LHexachlorobutadiene 09/07/23 12:215.002.05<2.05µg/LHexachlorocyclopentadiene 09/07/23 12:215.001.76<1.76µg/LHexachloroethane 09/07/23 12:212.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene 09/07/23 12:215.000.444<0.444µg/LIsophorone 09/07/23 12:212.001.14<1.14µg/L1-Methylnaphthalene 09/07/23 12:212.000.666<0.666µg/L2-Methylnaphthalene 09/07/23 12:212.000.728<0.728µg/LNaphthalene 09/07/23 12:215.000.905<0.905µg/LNitrobenzene 09/07/23 12:215.000.493<0.493µg/L2-Nitrophenol 09/07/23 12:2110.01.23<1.23µg/L4-Nitrophenol 09/07/23 12:215.001.10<1.10µg/LN-Nitrosodiphenylamine 09/07/23 12:215.000.641<0.641µg/LN-Nitroso-di-n-propylamine Page 11 of 36Date:09/14/2023 08:12 AM Page 37 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 Associated Lab Samples: 93945 LRB-V37482 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/07/23 12:215.001.43<1.43µg/LPentachlorophenol 09/07/23 12:212.000.428<0.428µg/LPhenanthrene 09/07/23 12:215.000.651<0.651µg/LPhenol 09/07/23 12:212.000.434<0.434µg/LPyrene 09/07/23 12:215.002.21<2.21µg/L1,2,4-Trichlorobenzene 09/07/23 12:215.001.32<1.32µg/L2,4,6-Trichlorophenol 09/07/23 12:212-Fluorobiphenyl (S)85.0 49-118 09/07/23 12:212-Fluorophenol (S)46.5 22-84 09/07/23 12:21Nitrobenzene-d5 (S)85.6 43-123 09/07/23 12:214-Terphenyl-d14 (S)96.8 49-151 09/07/23 12:212,4,6-Tribromophenol (S)80.4 31-144 09/07/23 12:21Phenol-d5 (S)30.4 10-63 LCS-V37482 LCSD-V37482Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 41.6 83.285.842.950.0µg/LAcenaphthene 47-145 3.0 20.0 40.4 80.883.041.550.0µg/LAcenaphthylene 33-145 2.6 20.0 45.2 90.493.046.550.0µg/LAnthracene 27-133 2.8 20.0 27.7 55.411456.950.0µg/LBenzidine 15-150 69.0*20.0 44.6 89.291.845.950.0µg/LBenzo(a)anthracene 33-143 2.8 20.0 50.1 10010351.550.0µg/LBenzo(a)pyrene 17-163 2.7 20.0 46.1 92.294.047.050.0µg/LBenzo(b)fluoranthene 24-159 1.9 20.0 43.7 87.491.445.750.0µg/LBenzo(g,h,i)perylene 10-219 4.4 20.0 45.9 91.894.047.050.0µg/LBenzo(k)fluoranthene 11-162 2.3 20.0 19.6 39.237.218.650.0µg/LBenzoic Acid 10-125 5.2 20.0 Page 12 of 36* QC Fail Date:09/14/2023 08:12 AM Page 38 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 LCS-V37482 LCSD-V37482Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 37.3 74.682.441.250.0µg/LBenzyl alcohol 16-107 9.9 20.0 37.3 74.677.838.950.0µg/LBis(2-Chloroethoxy)methane 33-184 4.1 20.0 34.6 69.275.037.550.0µg/LBis(2-Chloroethyl)ether 12-158 8.0 20.0 37.9 75.883.241.650.0µg/LBis(2-Chloroisopropyl)ether 36-166 9.3 20.0 47.3 94.698.249.150.0µg/LBis(2-ethylhexyl)phthalate 10-158 3.7 20.0 43.8 87.693.046.550.0µg/L4-Bromophenyl phenyl ether 53-127 5.9 20.0 50.7 10110452.150.0µg/LButyl benzyl phthalate 10-152 2.7 20.0 39.9 79.882.241.150.0µg/L4-Chloro-3-methylphenol 22-147 2.9 20.0 39.4 78.882.441.250.0µg/L2-Chloronaphthalene 60-118 4.4 20.0 35.3 70.675.237.650.0µg/L2-Chlorophenol 23-134 6.3 20.0 43.9 87.891.845.950.0µg/L4-Chlorophenyl phenyl ether 25-158 4.4 20.0 44.1 88.292.246.150.0µg/LChrysene 17-168 4.4 20.0 36.2 72.473.836.950.0µg/LDibenz(a,h)anthracene 10-227 1.9 20.0 40.5 81.085.042.550.0µg/LDibenzofuran 39-114 4.8 20.0 31.6 63.266.033.050.0µg/L1,2-Dichlorobenzene 32-129 4.3 20.0 30.1 60.264.232.150.0µg/L1,3-Dichlorobenzene 20-124 6.4 20.0 30.0 60.063.031.550.0µg/L1,4-Dichlorobenzene 20-124 4.8 20.0 48.3 96.697.848.950.0µg/L3,3'-Dichlorobenzidine 10-262 1.2 20.0 39.0 78.080.640.350.0µg/L2,4-Dichlorophenol 39-135 3.2 20.0 45.9 91.895.047.550.0µg/LDiethyl phthalate 10-114 3.4 20.0 46.6 93.291.845.950.0µg/LDimethyl phthalate 10-112 1.5 20.0 51.5 10310351.750.0µg/L2,4-Dimethylphenol 32-119 0.3 20.0 49.3 98.610050.150.0µg/LDi-n-butyl phthalate 10-118 1.6 20.0 46.0 92.098.049.050.0µg/L4,6-Dinitro-2-methylphenol 10-181 6.3 20.0 53.3 10711055.050.0µg/L2,4-Dinitrophenol 10-191 3.1 20.0 45.9 91.892.446.250.0µg/L2,4-Dinitrotoluene 39-139 0.6 20.0 Page 13 of 36Date:09/14/2023 08:12 AM Page 39 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 LCS-V37482 LCSD-V37482Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 45.4 90.893.446.750.0µg/L2,6-Dinitrotoluene 50-158 2.8 20.0 50.7 10110452.250.0µg/LDi-n-Octyl Phthalate 10-146 2.9 20.0 41.4 82.885.442.750.0µg/LFluoranthene 26-137 3.0 20.0 43.0 86.088.444.250.0µg/LFluorene 59-121 2.7 20.0 43.2 86.490.445.250.0µg/LHexachlorobenzene 10-152 4.5 20.0 29.9 59.863.231.650.0µg/LHexachlorobutadiene 24-116 5.5 20.0 36.3 72.675.437.750.0µg/LHexachlorocyclopentadiene 32-117 3.7 20.0 29.2 58.463.431.750.0µg/LHexachloroethane 40-113 8.2 20.0 46.0 92.092.846.450.0µg/LIndeno(1,2,3-cd)pyrene 10-171 0.8 20.0 36.1 72.273.436.750.0µg/LIsophorone 21-196 1.6 20.0 33.0 66.067.633.850.0µg/L1-Methylnaphthalene 40-135 2.3 20.0 32.5 65.066.433.250.0µg/L2-Methylnaphthalene 18-121 2.1 20.0 30.4 60.864.232.150.0µg/LNaphthalene 21-133 5.4 20.0 32.5 65.068.034.050.0µg/LNitrobenzene 35-180 4.5 20.0 35.0 70.073.836.950.0µg/L2-Nitrophenol 29-182 5.2 20.0 17.7 35.436.818.450.0µg/L4-Nitrophenol 10-132 3.8 20.0 52.9 10611255.850.0µg/LN-Nitrosodiphenylamine 69-152 5.3 20.0 42.3 84.686.443.250.0µg/LN-Nitroso-di-n-propylamine 10-230 2.1 20.0 57.2 11411658.150.0µg/LPentachlorophenol 14-176 1.5 20.0 43.1 86.290.245.150.0µg/LPhenanthrene 54-120 4.5 20.0 17.2 34.439.219.650.0µg/LPhenol 10-112 13.0 20.0 46.0 92.094.647.350.0µg/LPyrene 52-115 2.7 20.0 29.4 58.862.031.050.0µg/L1,2,4-Trichlorobenzene 44-142 5.2 20.0 43.7 87.487.843.950.0µg/L2,4,6-Trichlorophenol 37-144 0.4 20.0 80.482.02-Fluorobiphenyl (S)49-118 41.744.62-Fluorophenol (S)22-84 Page 14 of 36Date:09/14/2023 08:12 AM Page 40 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V37519QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V37482 LCS-V37482 LCSD-V37482Laboratory Control Sample & LCSD LCSD ResultParameter LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 68.671.8Nitrobenzene-d5 (S)43-123 90.695.04-Terphenyl-d14 (S)49-151 75.880.92,4,6-Tribromophenol (S)31-144 27.229.9Phenol-d5 (S)10-63 Page 15 of 36Date:09/14/2023 08:12 AM Page 41 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 Associated Lab Samples: 93944 LRB-V37514 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/05/23 11:480.0200.002<0.002mg/KgAcetone 09/05/23 11:480.0200.001<0.001mg/KgAcrolein 09/05/23 11:480.0200.0008<0.0008mg/KgAcrylonitrile 09/05/23 11:480.0050.0006<0.0006mg/KgBenzene 09/05/23 11:480.0050.0005<0.0005mg/KgBromobenzene 09/05/23 11:480.0050.0008<0.0008mg/KgBromochloromethane 09/05/23 11:480.0050.001<0.001mg/KgBromodichloromethane 09/05/23 11:480.0050.001<0.001mg/KgBromoform 09/05/23 11:480.0100.001<0.001mg/KgBromomethane 09/05/23 11:480.0050.0005<0.0005mg/Kgn-Butylbenzene 09/05/23 11:480.0050.0006<0.0006mg/Kgsec-Butyl benzene 09/05/23 11:480.0050.0005<0.0005mg/Kgtert-Butyl benzene 09/05/23 11:480.0050.0006<0.0006mg/KgCarbon Disulfide 09/05/23 11:480.0050.001<0.001mg/KgCarbon Tetrachloride 09/05/23 11:480.0050.0007<0.0007mg/KgChlorobenzene 09/05/23 11:480.0050.0009<0.0009mg/KgChlorodibromomethane 09/05/23 11:480.0100.0009<0.0009mg/KgChloroethane 09/05/23 11:480.0050.001<0.001mg/KgChloroform 09/05/23 11:480.0100.0006<0.0006mg/KgChloromethane 09/05/23 11:480.0050.0005<0.0005mg/Kg2-Chlorotoluene 09/05/23 11:480.0050.0004<0.0004mg/Kg4-Chlorotoluene 09/05/23 11:480.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE) 09/05/23 11:480.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane 09/05/23 11:480.0050.0006<0.0006mg/Kg1,2-Dibromoethane 09/05/23 11:480.0050.0010<0.0010mg/KgDibromomethane 09/05/23 11:480.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene 09/05/23 11:480.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene Page 16 of 36Date:09/14/2023 08:12 AM Page 42 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 Associated Lab Samples: 93944 LRB-V37514 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/05/23 11:480.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene 09/05/23 11:480.0100.001<0.001mg/KgDichlorodifluoromethane 09/05/23 11:480.0050.0008<0.0008mg/Kg1,1-Dichloroethane 09/05/23 11:480.0050.001<0.001mg/Kg1,2-Dichloroethane 09/05/23 11:480.0050.0007<0.0007mg/Kg1,1-Dichloroethene 09/05/23 11:480.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene 09/05/23 11:480.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene 09/05/23 11:480.0050.0004<0.0004mg/Kg1,2-Dichloropropane 09/05/23 11:480.0050.0006<0.0006mg/Kg1,3-Dichloropropane 09/05/23 11:480.0050.001<0.001mg/Kg2,2-Dichloropropane 09/05/23 11:480.0050.0008<0.0008mg/Kg1,1-Dichloropropene 09/05/23 11:480.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene 09/05/23 11:480.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene 09/05/23 11:480.0050.0006<0.0006mg/KgEthylbenzene 09/05/23 11:480.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE) 09/05/23 11:480.0100.0008<0.0008mg/KgHexachlorobutadiene 09/05/23 11:480.0100.0007<0.0007mg/Kgn-Hexane 09/05/23 11:480.0200.0006<0.0006mg/Kg2-Hexanone 09/05/23 11:480.0050.0005<0.0005mg/KgIsopropylbenzene 09/05/23 11:480.0050.001<0.001mg/Kg4-Isopropyl toluene 09/05/23 11:480.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK) 09/05/23 11:480.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE) 09/05/23 11:480.0050.001<0.001mg/KgMethylene Chloride 09/05/23 11:480.0100.0010<0.0010mg/KgNaphthalene 09/05/23 11:480.0050.0005<0.0005mg/Kgn-Propylbenzene 09/05/23 11:480.0050.001<0.001mg/KgStyrene 09/05/23 11:480.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane Page 17 of 36Date:09/14/2023 08:12 AM Page 43 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 Associated Lab Samples: 93944 LRB-V37514 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/05/23 11:480.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane 09/05/23 11:480.0050.0009<0.0009mg/KgTetrachloroethene 09/05/23 11:480.0050.0007<0.0007mg/KgToluene 09/05/23 11:480.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene 09/05/23 11:480.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene 09/05/23 11:480.0050.001<0.001mg/Kg1,1,1-Trichloroethane 09/05/23 11:480.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane 09/05/23 11:480.0050.0009<0.0009mg/KgTrichloroethene 09/05/23 11:480.0100.002<0.002mg/KgTrichlorofluoromethane 09/05/23 11:480.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane 09/05/23 11:480.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene 09/05/23 11:480.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene 09/05/23 11:480.0100.0005<0.0005mg/KgVinyl Acetate 09/05/23 11:480.0100.0005<0.0005mg/KgVinyl Chloride 09/05/23 11:480.0050.0005<0.0005mg/Kgo-Xylene 09/05/23 11:480.0100.001<0.001mg/Kgm,p-Xylene 09/05/23 11:484-Bromofluorobenzene (S)102 70-130 09/05/23 11:48Dibromofluoromethane (S)105 70-130 09/05/23 11:48Toluene-d8 (S)99.8 76-129 LCS-V37514 LCSD-V37514Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.083 83.992.50.0920.100mg/KgAcetone 29-198 9.7 20 0.104 1041060.1060.100mg/KgAcrolein 70-130 1.9 20 0.104 1041060.1060.100mg/KgAcrylonitrile 65-134 1.9 20 Page 18 of 36Date:09/14/2023 08:12 AM Page 44 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 LCS-V37514 LCSD-V37514Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.045 90.893.60.0460.050mg/KgBenzene 74-127 3.0 20 0.047 95.098.20.0490.050mg/KgBromobenzene 73-125 3.3 20 0.050 1021060.0520.050mg/KgBromochloromethane 72-134 3.8 20 0.047 95.895.80.0470.050mg/KgBromodichloromethane 75-122 0.0 20 0.055 1121110.0550.050mg/KgBromoform 66-135 0.5 20 0.046 92.098.20.0490.050mg/KgBromomethane 20-180 6.5 20 0.048 96.01000.0500.050mg/Kgn-Butylbenzene 65-135 4.2 20 0.046 93.497.60.0480.050mg/Kgsec-Butyl benzene 66-131 4.3 20 0.046 93.698.80.0490.050mg/Kgtert-Butyl benzene 67-132 5.4 20 0.040 80.486.00.0430.050mg/KgCarbon Disulfide 61-129 6.7 20 0.040 80.297.80.0480.050mg/KgCarbon Tetrachloride 64-143 19.7 20 0.048 97.099.00.0490.050mg/KgChlorobenzene 74-118 2.0 20 0.051 1021030.0510.050mg/KgChlorodibromomethane 73-122 0.9 20 0.045 91.496.60.0480.050mg/KgChloroethane 33-149 5.5 20 0.045 91.094.00.0470.050mg/KgChloroform 73-127 3.2 20 0.037 75.280.00.0400.050mg/KgChloromethane 45-143 6.1 20 0.046 93.897.60.0480.050mg/Kg2-Chlorotoluene 67-124 3.9 20 0.046 93.897.40.0480.050mg/Kg4-Chlorotoluene 71-126 3.7 20 0.043 86.089.00.0440.050mg/KgDi-Isopropyl Ether (DIPE)59-159 3.4 20 0.055 1111150.0570.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 4.2 20 0.053 1071060.0520.050mg/Kg1,2-Dibromoethane 70-132 1.5 20 0.048 96.898.00.0490.050mg/KgDibromomethane 74-133 1.2 20 0.051 1021050.0520.050mg/Kg1,2-Dichlorobenzene 72-123 2.5 20 0.050 1001020.0510.050mg/Kg1,3-Dichlorobenzene 71-120 1.9 20 0.048 97.499.20.0490.050mg/Kg1,4-Dichlorobenzene 71-123 1.8 20 0.042 85.490.60.0450.050mg/KgDichlorodifluoromethane 26-146 5.9 20 Page 19 of 36Date:09/14/2023 08:12 AM Page 45 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 LCS-V37514 LCSD-V37514Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.044 89.892.00.0460.050mg/Kg1,1-Dichloroethane 74-127 2.4 20 0.044 89.489.40.0440.050mg/Kg1,2-Dichloroethane 68-128 0.0 20 0.040 81.088.60.0440.050mg/Kg1,1-Dichloroethene 67-149 8.9 20 0.044 89.892.00.0460.050mg/Kgcis-1,2-Dichloroethene 76-134 2.4 20 0.042 85.291.60.0450.050mg/Kgtrans-1,2-Dichloroethene 73-132 7.2 20 0.046 92.694.40.0470.050mg/Kg1,2-Dichloropropane 73-130 1.9 20 0.049 99.299.40.0490.050mg/Kg1,3-Dichloropropane 75-124 0.2 20 0.043 87.892.40.0460.050mg/Kg2,2-Dichloropropane 50-142 5.1 20 0.043 87.694.20.0470.050mg/Kg1,1-Dichloropropene 71-130 7.2 20 0.049 99.01010.0500.050mg/Kgcis-1,3-Dichloropropene 71-125 2.1 20 0.051 1031050.0520.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.4 20 0.045 91.695.20.0470.050mg/KgEthylbenzene 74-128 3.8 20 0.092 92.494.20.0940.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.9 20 0.050 1021040.0520.050mg/KgHexachlorobutadiene 64-125 2.7 20 0.046 92.01010.0500.050mg/Kgn-Hexane 70-130 9.5 20 0.043 87.691.20.0450.050mg/Kg2-Hexanone 61-157 4.0 20 0.047 94.098.00.0490.050mg/KgIsopropylbenzene 68-126 4.1 20 0.047 95.21000.0500.050mg/Kg4-Isopropyl toluene 68-129 5.3 20 0.041 83.480.40.0400.050mg/KgMethyl Ethyl Ketone (MEK)63-149 3.6 20 0.049 98.097.40.0480.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.6 20 0.040 80.685.20.0420.050mg/KgMethylene Chloride 74-129 5.5 20 0.057 1141110.0550.050mg/KgNaphthalene 57-157 2.6 20 0.046 92.697.00.0480.050mg/Kgn-Propylbenzene 67-130 4.6 20 0.051 1031040.0510.050mg/KgStyrene 77-121 0.9 20 0.050 1011010.0500.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.1 20 0.050 1021030.0510.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.1 20 Page 20 of 36Date:09/14/2023 08:12 AM Page 46 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Volatile Organic Compounds - GC/MS 8260D V37515QC Analytical Batch(es): Analysis Method: Analysis Description: 5035 QC Prep:V37514 LCS-V37514 LCSD-V37514Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.045 91.497.00.0480.050mg/KgTetrachloroethene 68-130 5.9 20 0.045 90.894.20.0470.050mg/KgToluene 71-129 3.6 20 0.056 1121080.0530.050mg/Kg1,2,3-Trichlorobenzene 68-130 4.0 20 0.055 1111100.0550.050mg/Kg1,2,4-Trichlorobenzene 66-125 0.7 20 0.042 85.892.40.0460.050mg/Kg1,1,1-Trichloroethane 67-131 7.4 20 0.050 1001010.0500.050mg/Kg1,1,2-Trichloroethane 70-133 0.1 20 0.046 92.896.20.0480.050mg/KgTrichloroethene 75-133 3.5 20 0.038 77.882.80.0410.050mg/KgTrichlorofluoromethane 44-146 6.2 20 0.052 1061050.0520.050mg/Kg1,2,3-Trichloropropane 60-137 0.1 20 0.048 97.41000.0500.050mg/Kg1,2,4-Trimethylbenzene 69-129 2.8 20 0.047 95.81000.0500.050mg/Kg1,3,5-Trimethylbenzene 69-128 4.2 20 0.057 1161080.0540.050mg/KgVinyl Acetate 60-140 6.4 20 0.033 67.683.20.0410.050mg/KgVinyl Chloride 48-147 20.6*20 0.047 95.898.80.0490.050mg/Kgo-Xylene 74-126 3.0 20 0.094 94.097.30.0970.100mg/Kgm,p-Xylene 75-124 3.4 20 1021024-Bromofluorobenzene (S)70-130 102103Dibromofluoromethane (S)70-130 102102Toluene-d8 (S)76-129 Page 21 of 36* QC Fail Date:09/14/2023 08:12 AM Page 47 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 Associated Lab Samples: 93944 LRB-V37540 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/08/23 15:130.6600.116<0.116mg/KgAcenaphthene 09/08/23 15:130.6600.105<0.105mg/KgAcenaphthylene 09/08/23 15:130.6600.152<0.152mg/KgAniline 09/08/23 15:130.6600.143<0.143mg/KgAnthracene 09/08/23 15:130.6600.139<0.139mg/KgBenzo(a)anthracene 09/08/23 15:130.6600.147<0.147mg/KgBenzo(a)pyrene 09/08/23 15:130.6600.146<0.146mg/KgBenzo(b)fluoranthene 09/08/23 15:130.6600.136<0.136mg/KgBenzo(g,h,i)perylene 09/08/23 15:130.6600.137<0.137mg/KgBenzo(k)fluoranthene 09/08/23 15:132.000.580<0.580mg/KgBenzoic Acid 09/08/23 15:130.6600.105<0.105mg/KgBenzyl alcohol 09/08/23 15:130.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane 09/08/23 15:130.6600.107<0.107mg/KgBis(2-Chloroethyl)ether 09/08/23 15:130.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether 09/08/23 15:130.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate 09/08/23 15:130.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether 09/08/23 15:130.3300.113<0.113mg/KgButyl benzyl phthalate 09/08/23 15:130.6600.092<0.092mg/Kg4-Chloro-3-methylphenol 09/08/23 15:130.3300.112<0.112mg/Kg4-Chloroaniline 09/08/23 15:130.6600.116<0.116mg/Kg2-Chloronaphthalene 09/08/23 15:130.6600.098<0.098mg/Kg2-Chlorophenol 09/08/23 15:131.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether 09/08/23 15:130.6600.142<0.142mg/KgChrysene 09/08/23 15:130.6600.230<0.230mg/KgDibenz(a,h)anthracene 09/08/23 15:130.6600.119<0.119mg/KgDibenzofuran 09/08/23 15:130.6600.094<0.094mg/Kg1,2-Dichlorobenzene 09/08/23 15:130.6600.097<0.097mg/Kg1,3-Dichlorobenzene Page 22 of 36Date:09/14/2023 08:12 AM Page 48 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 Associated Lab Samples: 93944 LRB-V37540 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/08/23 15:130.3300.097<0.097mg/Kg1,4-Dichlorobenzene 09/08/23 15:130.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine 09/08/23 15:130.6600.095<0.095mg/Kg2,4-Dichlorophenol 09/08/23 15:130.6600.180<0.180mg/KgDiethyl phthalate 09/08/23 15:130.6600.174<0.174mg/KgDimethyl phthalate 09/08/23 15:130.3300.108<0.108mg/Kg2,4-Dimethylphenol 09/08/23 15:130.6600.107<0.107mg/KgDi-n-butyl phthalate 09/08/23 15:131.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol 09/08/23 15:131.500.520<0.520mg/Kg2,4-Dinitrophenol 09/08/23 15:130.6600.096<0.096mg/Kg2,4-Dinitrotoluene 09/08/23 15:130.6600.108<0.108mg/Kg2,6-Dinitrotoluene 09/08/23 15:130.3300.143<0.143mg/KgDi-n-Octyl Phthalate 09/08/23 15:130.6600.123<0.123mg/KgFluoranthene 09/08/23 15:130.6600.128<0.128mg/KgFluorene 09/08/23 15:130.6600.106<0.106mg/KgHexachlorobenzene 09/08/23 15:130.6600.097<0.097mg/KgHexachlorobutadiene 09/08/23 15:130.6600.157<0.157mg/KgHexachlorocyclopentadiene 09/08/23 15:130.6600.079<0.079mg/KgHexachloroethane 09/08/23 15:130.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene 09/08/23 15:130.6600.191<0.191mg/KgIsophorone 09/08/23 15:130.6600.106<0.106mg/Kg1-Methylnaphthalene 09/08/23 15:130.6600.100<0.100mg/Kg2-Methylnaphthalene 09/08/23 15:130.6600.097<0.097mg/Kg2-Methylphenol 09/08/23 15:130.6600.084<0.084mg/Kg3&4 Methylphenol 09/08/23 15:130.6600.144<0.144mg/KgNaphthalene 09/08/23 15:130.6600.096<0.096mg/Kg2-Nitroaniline 09/08/23 15:130.6600.120<0.120mg/Kg3-Nitroaniline Page 23 of 36Date:09/14/2023 08:12 AM Page 49 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 Associated Lab Samples: 93944 LRB-V37540 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/08/23 15:130.3300.093<0.093mg/Kg4-Nitroaniline 09/08/23 15:130.3300.116<0.116mg/KgNitrobenzene 09/08/23 15:130.6600.088<0.088mg/Kg2-Nitrophenol 09/08/23 15:130.6600.117<0.117mg/Kg4-Nitrophenol 09/08/23 15:130.6600.263<0.263mg/KgN-Nitrosodimethylamine 09/08/23 15:130.6600.181<0.181mg/KgN-Nitrosodiphenylamine 09/08/23 15:130.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine 09/08/23 15:131.000.347<0.347mg/KgPentachlorophenol 09/08/23 15:130.6600.208<0.208mg/KgPhenanthrene 09/08/23 15:130.6600.112<0.112mg/KgPhenol 09/08/23 15:130.6600.134<0.134mg/KgPyrene 09/08/23 15:130.3300.079<0.079mg/KgPyridine 09/08/23 15:130.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene 09/08/23 15:130.6600.096<0.096mg/Kg2,4,5-Trichlorophenol 09/08/23 15:130.6600.096<0.096mg/Kg2,4,6-Trichlorophenol 09/08/23 15:132-Fluorobiphenyl (S)92.8 44-115 09/08/23 15:132-Fluorophenol (S)84.6 35-115 09/08/23 15:13Nitrobenzene-d5 (S)101 37-122 09/08/23 15:134-Terphenyl-d14 (S)105 54-127 09/08/23 15:132,4,6-Tribromophenol (S)90.0 39-132 09/08/23 15:13Phenol-d5 (S)80.4 34-121 LCS-V37540Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 95.21.591.67mg/KgAcenaphthene 40-123 98.21.641.67mg/KgAcenaphthylene 32-132 Page 24 of 36Date:09/14/2023 08:12 AM Page 50 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 LCS-V37540Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 230*3.841.67mg/KgAniline 12-197 1081.811.67mg/KgAnthracene 47-123 1041.741.67mg/KgBenzo(a)anthracene 49-126 1141.911.67mg/KgBenzo(a)pyrene 45-129 1071.781.67mg/KgBenzo(b)fluoranthene 45-132 1001.671.67mg/KgBenzo(g,h,i)perylene 43-134 1101.831.67mg/KgBenzo(k)fluoranthene 47-132 62.81.051.67mg/KgBenzoic Acid 10-83 94.61.581.67mg/KgBenzyl alcohol 29-122 92.81.551.67mg/KgBis(2-Chloroethoxy)methane 36-121 80.81.351.67mg/KgBis(2-Chloroethyl)ether 31-120 89.21.491.67mg/KgBis(2-Chloroisopropyl)ether 33-131 1141.911.67mg/KgBis(2-ethylhexyl)phthalate 51-133 1051.751.67mg/Kg4-Bromophenyl phenyl ether 46-124 1131.891.67mg/KgButyl benzyl phthalate 48-132 1041.731.67mg/Kg4-Chloro-3-methylphenol 45-122 116*1.941.67mg/Kg4-Chloroaniline 17-106 94.01.571.67mg/Kg2-Chloronaphthalene 41-114 89.21.491.67mg/Kg2-Chlorophenol 34-121 1011.691.67mg/Kg4-Chlorophenyl phenyl ether 45-121 1041.731.67mg/KgChrysene 50-124 82.61.381.67mg/KgDibenz(a,h)anthracene 45-134 97.61.631.67mg/KgDibenzofuran 44-120 83.21.391.67mg/Kg1,2-Dichlorobenzene 33-117 78.41.311.67mg/Kg1,3-Dichlorobenzene 30-115 79.01.321.67mg/Kg1,4-Dichlorobenzene 31-115 98.81.651.67mg/Kg3,3'-Dichlorobenzidine 22-121 Page 25 of 36* QC Fail Date:09/14/2023 08:12 AM Page 51 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 LCS-V37540Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1021.701.67mg/Kg2,4-Dichlorophenol 40-122 1041.741.67mg/KgDiethyl phthalate 50-124 1051.761.67mg/KgDimethyl phthalate 48-124 1171.951.67mg/Kg2,4-Dimethylphenol 30-127 1171.951.67mg/KgDi-n-butyl phthalate 51-128 1041.731.67mg/Kg4,6-Dinitro-2-methylphenol 29-132 79.61.331.67mg/Kg2,4-Dinitrophenol 27-129 1111.851.67mg/Kg2,4-Dinitrotoluene 48-126 1161.941.67mg/Kg2,6-Dinitrotoluene 46-124 1171.961.67mg/KgDi-n-Octyl Phthalate 45-140 98.21.641.67mg/KgFluoranthene 50-127 98.81.651.67mg/KgFluorene 43-125 1031.721.67mg/KgHexachlorobenzene 45-122 89.21.491.67mg/KgHexachlorobutadiene 32-123 74.81.251.67mg/KgHexachlorocyclopentadiene 32-117 80.21.341.67mg/KgHexachloroethane 28-117 1001.671.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 82.61.381.67mg/KgIsophorone 30-122 86.81.451.67mg/Kg1-Methylnaphthalene 40-119 89.21.491.67mg/Kg2-Methylnaphthalene 38-122 89.21.491.67mg/Kg2-Methylphenol 32-122 87.41.461.67mg/Kg3&4 Methylphenol 34-119 86.21.441.67mg/KgNaphthalene 35-123 1222.041.67mg/Kg2-Nitroaniline 44-127 122*2.041.67mg/Kg3-Nitroaniline 33-119 1202.001.67mg/Kg4-Nitroaniline 63-147 94.61.581.67mg/KgNitrobenzene 34-122 Page 26 of 36* QC Fail Date:09/14/2023 08:12 AM Page 52 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 LCS-V37540Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1101.831.67mg/Kg2-Nitrophenol 36-123 98.81.651.67mg/Kg4-Nitrophenol 30-132 74.21.241.67mg/KgN-Nitrosodimethylamine 10-146 1272.121.67mg/KgN-Nitrosodiphenylamine 38-127 87.41.461.67mg/KgN-Nitroso-di-n-propylamine 36-120 1282.141.67mg/KgPentachlorophenol 25-133 1021.701.67mg/KgPhenanthrene 50-121 83.81.401.67mg/KgPhenol 34-121 1021.711.67mg/KgPyrene 47-127 61.61.031.67mg/KgPyridine 10-80 83.81.401.67mg/Kg1,2,4-Trichlorobenzene 34-118 1061.771.67mg/Kg2,4,5-Trichlorophenol 41-124 1021.711.67mg/Kg2,4,6-Trichlorophenol 39-126 93.42-Fluorobiphenyl (S)44-115 79.22-Fluorophenol (S)35-115 94.0Nitrobenzene-d5 (S)37-122 1054-Terphenyl-d14 (S)54-127 1032,4,6-Tribromophenol (S)39-132 73.5Phenol-d5 (S)34-121 V 93889-MS-V37540 V 93889-MSD-V37540Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.62 97.01.611.671.67<0.116mg/KgAcenaphthene 96.4 40-123 0.6 20 1.65 98.81.651.671.67<0.105mg/KgAcenaphthylene 98.8 32-132 0.0 20 3.81 228*3.941.671.67<0.152mg/KgAniline 236*12-197 3.3 20 Page 27 of 36* QC Fail Date:09/14/2023 08:12 AM Page 53 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 V 93889-MS-V37540 V 93889-MSD-V37540Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.83 1101.811.671.67<0.143mg/KgAnthracene 108 47-123 1.0 20 1.81 1081.811.671.67<0.139mg/KgBenzo(a)anthracene 108 49-126 0.0 20 1.99 1192.011.671.67<0.147mg/KgBenzo(a)pyrene 120 45-129 1.0 20 1.89 1131.881.671.67<0.146mg/KgBenzo(b)fluoranthene 113 45-132 0.5 20 1.76 1051.761.671.67<0.136mg/KgBenzo(g,h,i)perylene 105 43-134 0.0 20 1.73 1041.721.671.67<0.137mg/KgBenzo(k)fluoranthene 103 47-132 0.5 20 1.85 111*1.891.671.67<0.580mg/KgBenzoic Acid 113*10-83 2.1 20 1.65 98.81.731.671.67<0.105mg/KgBenzyl alcohol 104 29-122 4.7 20 1.60 95.81.641.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 98.2 36-121 2.4 20 1.37 82.01.431.671.67<0.107mg/KgBis(2-Chloroethyl)ether 85.6 31-120 4.2 20 1.52 91.01.591.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 95.2 33-131 4.5 20 1.95 1171.941.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 116 51-133 0.5 20 1.81 1081.801.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 108 46-124 0.5 20 1.93 1161.901.671.67<0.113mg/KgButyl benzyl phthalate 114 48-132 1.5 20 1.75 1051.761.671.67<0.092mg/Kg4-Chloro-3-methylphenol 105 45-122 0.5 20 1.91 114*1.911.671.67<0.112mg/Kg4-Chloroaniline 114*17-106 0.0 20 1.60 95.81.631.671.67<0.116mg/Kg2-Chloronaphthalene 97.6 41-114 1.8 20 1.54 92.21.601.671.67<0.098mg/Kg2-Chlorophenol 95.8 34-121 3.8 20 1.75 1051.741.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 104 45-121 0.5 20 1.74 1041.721.671.67<0.142mg/KgChrysene 103 50-124 1.1 20 1.59 95.21.551.671.67<0.230mg/KgDibenz(a,h)anthracene 92.8 45-134 2.5 20 1.64 98.21.661.671.67<0.119mg/KgDibenzofuran 99.4 44-120 1.2 20 1.39 83.21.441.671.67<0.094mg/Kg1,2-Dichlorobenzene 86.2 33-117 3.5 20 1.31 78.41.401.671.67<0.097mg/Kg1,3-Dichlorobenzene 83.8 30-115 6.6 20 1.34 80.21.411.671.67<0.097mg/Kg1,4-Dichlorobenzene 84.4 31-115 5.0 20 1.67 1001.711.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 102 22-121 2.3 20 Page 28 of 36* QC Fail Date:09/14/2023 08:12 AM Page 54 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 V 93889-MS-V37540 V 93889-MSD-V37540Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.69 1011.711.671.67<0.095mg/Kg2,4-Dichlorophenol 102 40-122 1.1 20 1.77 1061.781.671.67<0.180mg/KgDiethyl phthalate 107 50-124 0.5 20 1.76 1051.761.671.67<0.174mg/KgDimethyl phthalate 105 48-124 0.0 30 2.23 134*2.251.671.67<0.108mg/Kg2,4-Dimethylphenol 135*30-127 0.8 20 1.97 1181.941.671.67<0.107mg/KgDi-n-butyl phthalate 116 51-128 1.5 20 1.75 1051.741.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 104 29-132 0.5 20 1.83 1101.861.671.67<0.520mg/Kg2,4-Dinitrophenol 111 27-129 1.6 20 1.84 1101.931.671.67<0.096mg/Kg2,4-Dinitrotoluene 116 48-126 4.7 20 1.94 1161.981.671.67<0.108mg/Kg2,6-Dinitrotoluene 119 46-124 2.0 20 2.02 1212.031.671.67<0.143mg/KgDi-n-Octyl Phthalate 122 45-140 0.4 20 1.65 98.81.611.671.67<0.123mg/KgFluoranthene 96.4 50-127 2.4 20 1.69 1011.721.671.67<0.128mg/KgFluorene 103 43-125 1.7 20 1.85 1111.811.671.67<0.106mg/KgHexachlorobenzene 108 45-122 2.1 20 1.58 94.61.591.671.67<0.097mg/KgHexachlorobutadiene 95.2 32-123 0.6 20 1.04 62.21.001.671.67<0.157mg/KgHexachlorocyclopentadiene 59.8 32-117 3.9 20 1.32 79.01.411.671.67<0.079mg/KgHexachloroethane 84.4 28-117 6.5 20 1.79 1071.831.671.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 110 45-133 2.2 20 1.41 84.41.421.671.67<0.191mg/KgIsophorone 85.0 30-122 0.7 20 1.47 88.01.491.671.67<0.106mg/Kg1-Methylnaphthalene 89.2 40-119 1.3 20 1.49 89.21.561.671.67<0.100mg/Kg2-Methylnaphthalene 93.4 38-122 4.5 20 1.50 89.81.531.671.67<0.097mg/Kg2-Methylphenol 91.6 32-122 1.9 20 1.46 87.41.441.671.67<0.085mg/Kg3&4 Methylphenol 86.2 34-119 1.3 20 1.47 88.01.501.671.67<0.144mg/KgNaphthalene 89.8 35-123 2.0 20 2.14 128*2.171.671.67<0.096mg/Kg2-Nitroaniline 130*44-127 1.3 20 2.14 128*2.171.671.67<0.120mg/Kg3-Nitroaniline 130*33-119 1.3 20 1.93 1161.951.671.67<0.093mg/Kg4-Nitroaniline 117 63-147 1.0 20 Page 29 of 36* QC Fail Date:09/14/2023 08:12 AM Page 55 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V37578QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V37540 V 93889-MS-V37540 V 93889-MSD-V37540Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.59 95.21.661.671.67<0.116mg/KgNitrobenzene 99.4 34-122 4.3 20 1.85 1111.911.671.67<0.088mg/Kg2-Nitrophenol 114 32-123 3.1 20 1.81 1081.811.671.67<0.117mg/Kg4-Nitrophenol 108 30-132 0.0 20 1.20 71.81.281.671.67<0.263mg/KgN-Nitrosodimethylamine 76.6 10-146 6.4 30 2.15 129*2.141.671.67<0.181mg/KgN-Nitrosodiphenylamine 128*38-127 0.4 20 1.47 88.01.541.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 92.2 36-120 4.6 20 2.66 159*2.571.671.67<0.347mg/KgPentachlorophenol 154*25-133 3.4 20 1.72 1031.681.671.67<0.208mg/KgPhenanthrene 101 50-121 2.3 20 1.41 84.41.421.671.67<0.112mg/KgPhenol 85.0 34-121 0.7 20 1.73 1041.761.671.67<0.134mg/KgPyrene 105 47-127 1.7 20 1.02 61.01.111.671.67<0.079mg/KgPyridine 66.4 10-80 8.4 20 1.47 88.01.541.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 92.2 34-118 4.6 20 1.84 1101.881.671.67<0.096mg/Kg2,4,5-Trichlorophenol 113 41-124 2.1 20 1.81 1081.831.671.67<0.096mg/Kg2,4,6-Trichlorophenol 110 39-126 1.0 20 92.82-Fluorobiphenyl (S)94.0 44-115 81.42-Fluorophenol (S)83.4 35-115 97.6Nitrobenzene-d5 (S)101 37-122 1084-Terphenyl-d14 (S)107 54-127 1112,4,6-Tribromophenol (S)109 39-132 75.7Phenol-d5 (S)75.0 34-121 Page 30 of 36* QC Fail Date:09/14/2023 08:12 AM Page 56 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: EDB and DBCP by Microextraction GC/ECD EPA-504.1 V37661QC Analytical Batch(es): Analysis Method: Analysis Description: EPA-504.1(PREP) QC Prep:V37608 Associated Lab Samples: 93945 LRB-V37608 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits 09/08/23 13:360.02000.00330<0.00330µg/L1,2-Dibromoethane LCS-V37608 LCSD-V37608Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.313 1251280.3190.250µg/L1,2-Dibromoethane 70-130 1.8 20.0 V 93893-DUP-V37608Duplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 09/08/23 15:040.4<0.0209< 0.0209µg/L1,2-Dibromoethane V 93892-MS-V37608Matrix Spike MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits 0.495 1280.2610.161µg/L1,2-Dibromoethane 70-130 Page 31 of 36Date:09/14/2023 08:12 AM Page 57 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Massachusetts EPH MADEP-EPH V37620QC Analytical Batch(es): Analysis Method: Analysis Description: MAEPH (Prep) QC Prep:V37493 Associated Lab Samples: 93944 LRB-V37493 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/13/23 10:4650.09.20<9.20mg/KgAliphatic C9-C18 09/13/23 10:4650.012.2<12.2mg/KgAliphatic C19-C36 09/13/23 10:4650.014.2<14.2mg/KgAromatic C11-C22 09/13/23 10:462-Fluorobiphenyl (S)67.7 40-140 09/13/23 10:462-Bromonaphthalene (S)62.0 40-140 09/13/23 10:46Chlorooctadecane (S)66.6 40-140 09/13/23 10:46OTP Surrogate (S)64.2 40-140 LCS-V37493 LCSD-V37493Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 42.5 70.854.332.660.0mg/KgAliphatic C9-C18 40-140 26.3 50 75.6 94.583.366.780.0mg/KgAliphatic C19-C36 40-140 12.5 50 147 86.468.8117170mg/KgAromatic C11-C22 40-140 22.7 50 76.071.22-Fluorobiphenyl (S)40-140 71.766.52-Bromonaphthalene (S)40-140 66.663.2Chlorooctadecane (S)40-140 69.362.5OTP Surrogate (S)40-140 Page 32 of 36Date:09/14/2023 08:12 AM Page 58 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Massachusetts EPH MADEP-EPH V37698QC Analytical Batch(es): Analysis Method: Analysis Description: MAEPH (Prep) QC Prep:V37556 Associated Lab Samples: 93945 LRB-V37556 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/13/23 10:4835028.2<28.2µg/LAliphatic C9-C18 09/13/23 10:48500124<124µg/LAliphatic C19-C36 09/13/23 10:4825061.2<61.2µg/LAromatic C11-C22 09/13/23 10:482-Fluorobiphenyl (S)73.0 40-140 09/13/23 10:482-Bromonaphthalene (S)67.2 40-140 09/13/23 10:48Chlorooctadecane (S)65.2 40-140 09/13/23 10:48OTP Surrogate (S)65.0 40-140 LCS-V37556 LCSD-V37556Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 416 69.382.8497600µg/LAliphatic C9-C18 40-140 17.7 50.0 822 103115918800µg/LAliphatic C19-C36 40-140 11.0 50.0 1630 95.810718201700µg/LAromatic C11-C22 40-140 11.0 50.0 80.780.02-Fluorobiphenyl (S)40-140 76.575.22-Bromonaphthalene (S)40-140 60.371.7Chlorooctadecane (S)40-140 69.074.5OTP Surrogate (S)40-140 Page 33 of 36Date:09/14/2023 08:12 AM Page 59 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Massachusetts VPH MADEP-VPH V37397QC Analytical Batch(es): Analysis Method: Analysis Description: MAVPH (Prep) QC Prep:V37396 Associated Lab Samples: 93944 LRB-V37396 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/01/23 23:068.001.22<1.22mg/KgAliphatic C5-C8 09/01/23 23:068.004.56<4.56mg/KgAliphatic C9-C12 09/01/23 23:068.000.624<0.624mg/KgAromatic C9-C10 09/01/23 23:062,5-Dibromotoluene (FID) (S)84.9 70-130 09/01/23 23:062,5-Dibromotoluene (PID) (S)83.7 70-130 LCS-V37396 LCSD-V37396Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 34.7 10810834.632.0mg/KgAliphatic C5-C8 70-130 0.2 50 36.8 11511336.332.0mg/KgAliphatic C9-C12 70-130 1.3 50 12.9 12111912.710.7mg/KgAromatic C9-C10 70-130 1.5 50 74.878.52,5-Dibromotoluene (FID) (S)70-130 77.691.42,5-Dibromotoluene (PID) (S)70-130 Page 34 of 36Date:09/14/2023 08:12 AM Page 60 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park QC Prep Batch Method: Massachusetts VPH MADEP-VPH V37399QC Analytical Batch(es): Analysis Method: Analysis Description: MAVPH (Prep) QC Prep:V37398 Associated Lab Samples: 93945 LRB-V37398 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 09/01/23 14:5150.011.5<11.5µg/LAliphatic C5-C8 09/01/23 14:5150.025.8<25.8µg/LAliphatic C9-C12 09/01/23 14:5150.04.02<4.02µg/LAromatic C9-C10 09/01/23 14:512,5-Dibromotoluene (FID) (S)105 70-130 09/01/23 14:512,5-Dibromotoluene (PID) (S)103 70-130 LCS-V37398 LCSD-V37398Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 317 106103310300µg/LAliphatic C5-C8 70-130 2.2 50.0 347 116113339300µg/LAliphatic C9-C12 70-130 2.3 50.0 110 110111111100µg/LAromatic C9-C10 70-130 0.9 50.0 80.585.52,5-Dibromotoluene (FID) (S)70-130 92.988.22,5-Dibromotoluene (PID) (S)70-130 Page 35 of 36Date:09/14/2023 08:12 AM Page 61 of 64 Quality Control Data 23-244-0009Report No: Project Description: Client ID:CES Group Mountain Village Park Dry Weight Determination SW-DRYWT V37425QC Analytical Batch: Analysis Method: Analysis Description: V 93890-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 09/05/23 11:433.030.029.1%Moisture V 94062-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 09/05/23 11:430.025.725.7%Moisture Page 36 of 36Date:09/14/2023 08:12 AM Page 62 of 64 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-244-0009 CES Group 00012 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 4.4C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs ü Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:09/01/2023 11:42:26 Special precautions or instructions included? Comments: Page 63 of 64 Page 64 of 64 APPENDIX E SOIL BORING LOG, WELL PERMIT AND WELL CONSTRUCTION RECORD CES Project No.: 8173.0623E Boring Number: MW-1 Page: 1 of 1 Site Name: Mountain Village Pantry Boring Location: Near Former Dispenser Island and USTs Address: 2302 Dallas Cherryville Highway, Dallas, NC Date: August 31, 2023 Sample Number Lab Sample Sample Recovery (5 Foot Intervals) Depth (feet) Detailed Soil and Rock Description PID (PPMV) Remarks / Notes 0__ 5__ (0-5'): Brownish-red clay 77 Petroleum Odor/No Staining 100% 10__ (5-10’): Brownish-red sandy silt 406 Petroleum Odor/No Staining 100% 15__ (10-15’): Brownish-red sandy silt 684 Petroleum Odor/No Staining 100% 100% 100% 20__(15-20’): Reddish-tan silty sand with some clay 1,702 Petroleum Odor/No Staining 100% 25__(20-25’): Reddish-tan silty sand with some clay 1,695 Petroleum Odor/No Staining 100% 30__(25-30’): Reddish-tan sandy silt with some clay 1,690 Petroleum Odor/No Staining 100% 35__(30-35’): Reddish-tan sandy silt with some clay 621 Petroleum Odor/No Staining 40__(35-40’): Reddish-tan sandy silt with some clay 2,703 Petroleum Odor/No Staining 100% MW-1 * 100% 45__ (40-45’): Reddish-tan silty clay with some sand 3,819 Petroleum Odor/No Staining Note: Stratification lines are approximate; in-situ transition between soil types may be gradual. Ground Water Data: Drilling Information: Drilling Co.: Carolina Soil Investigations, LLC Water Indication (during boring): 35 – 40 ’ Engineer/Geologist: Matthew Sumner Ground Water Depth (after boring): 38.39’ Drilling Method: Geoprobe Augering via Trac Mounted 6712DT Drill Rig PID Reading (instrument units): PPMV Sampling Method: 5-foot samples from auger flights Borehole Depth: 45’ Abandonment: N/A CES Group Engineers, LLP 3525 Whitehall Park Drive, Suite 150, Charlotte, NC 28273 WELL CONSTRUCTION RECORD (GW-1) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6.Is(are) the well(s): Permanent or Temporary 7. Is this a repair to an existing well: Yes or No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8.For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wellsdrilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10.Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12.Well construction method: (i.e. auger, rotary, cable, direct push, etc.) 22.Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23.Site diagram or additional well details: You may use the back of this page to provide additional well site details or wellconstruction details. You may also attach additional pages if necessary. SUBMITTAL INSTRUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Injection Wells: In addition to sending the form to the address in 24a above, also submit one copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636 24c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well construction to the county health department of the county where constructed. Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 Print Form For Internal Use Only: FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: NC Well Contractor Certification Number Carolina Soil Investigations, LLC Company Name 2.Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3.Well Use (check well use): 14. WATER ZONES FROM TO DESCRIPTION ft. ft. ft. ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. ft. ft. in. Water Supply Well: Municipal/Public Residential Water Supply (single) Residential Water Supply (shared) Wells > 100,000 GPD Agricultural Geothermal (Heating/Cooling Supply) Industrial/Commercial Irrigation 17. SCREENFROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft. ft. in. ft. ft. in. 18. GROUTFROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT Non-Water Supply Well: Monitoring Recovery ft. ft. ft. ft. Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks) ft. ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft. ft. ft. ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. 21. REMARKS 1.Well Contractor Information: ___________________________________________________________ Well Contractor Name 991 West Hudson Boulevard  Gastonia, North Carolina 28052 704-853-5000  www.gastonhhs.org GASTON COUNTY DEPARTMENT OF HEALTH & HUMAN SERVICES July 21, 2023 Monitoring Well Permit 20995 Greg Hans – CES Engineers, LLP - Applicant 3525 Whitehall Park Suite 150 Charlotte, NC 28273 Mountain Village Grocery Dustin Smithers 2304 Dallas Cherryville Hwy. Dallas, NC 28034 This is to serve as the Gaston County Environmental Health monitoring well construction permit for 2304 Dallas Cherryville Hwy., Dallas, NC 28034. This permit allows the applicant to install as many monitoring wells as necessary on this parcel. Well construction logs must be submitted to Gaston County Environmental Health within 30 days from the time of construction. When the well is abandoned a well abandonment log must be submitted to Gaston County Environmental Health within 30 days of abandonment. Applicant must abide by all Rules and Regulations of the State of North Carolina Well Construction Rules and Gaston County Well Ordinance. Issued by: Samantha Dye Samantha Dye, MSEH, REHS Environmental Health Administrator Gaston County Department of Health & Human Services Samantha.dye@gastongov.com 704-853-5230