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HomeMy WebLinkAboutFA-3910_29832_CA_MRP_20230817SUBSEQUENT MONITORING REPORT CLARK BROTHERS (INCIDENT NO. 29832) CORNER OF GREEN STREET AND COLLEGE STREET CLARKTON, BLADEN COUNTY, NORTH CAROLINA ESP Project No. 23-00200-020 Prepared For: North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Prepared By: ESP Associates, Inc. P. O. Box 7030 Charlotte, North Carolina 28241 August 17, 2023 ESP Associates, Inc. P.O. Box 7030 • Charlotte, NC 28241 1.800.960.7317 • NC: 704.583.4949, fax 704.583.4950 • SC: 803.802.2440, fax 803.802.2515 www.espassociates.com August 17, 2023 Ms. Hassan Osman North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Email: Hassan.Osman@deq.nc.gov Reference: SUBSEQUENT MONITORING REPORT Clark Brothers Corner of Green Street and College Street Clarkton, Bladen County, North Carolina NCDEQ Incident No: 29832 ESP Project No. 23-00200-020 Dear Mr. Osman ESP Associates, Inc. (ESP) is pleased to present this Subsequent Monitoring Report documenting activities performed at the subject site, Clark Brothers, in accordance with North Carolina Department of Environmental Quality (NCDEQ), Task Authorization No. 1, approved on May 22, 2023. The subject site is located at the corner of North College Street and West Green Street in Clarkton, North Carolina. We appreciate the opportunity to provide environmental services on this project. If you should have any questions, please do not hesitate to contact us at (704) 506-7618. Sincerely, ESP Associates, Inc. Matthew R. Craig Christopher J. Ward, PG, RSM Project Manager Senior Geologist Attachment – Subsequent Monitoring Report TABLE OF CONTENTS Section Page SITE INFORMATION ..................................................................................................................... i EXECUTIVE SUMMARY ............................................................................................................. iii 1.0 INTRODUCTION ............................................................................................................... 1 1.1 SITE SETTING ........................................................................................................... 1 1.2 SITE GEOLOGY AND HYDROGEOLOGY ................................................................. 1 1.3 SURFACE WATER ..................................................................................................... 2 1.4 WATER SUPPLY WELLS ........................................................................................... 2 2.0 SITE HISTORY .................................................................................................................. 3 3.0 FIELD ACTIVITIES ........................................................................................................... 5 3.1 FREE PRODUCT EVALUATION ................................................................................ 5 3.2 WATER LEVEL GAUGING ........................................................................................ 5 3.3 GROUNDWATER SAMPLING ................................................................................... 6 3.4 FIELD QUALITY CONTROL SAMPLING AND ANALYSIS ....................................... 6 4.0 ANALYTICAL RESULTS .................................................................................................. 7 5.0 CONCLUSIONS AND RECOMMENDATIONS ................................................................. 8 6.0 REFERENCES ................................................................................................................... 9 FIGURES Figure 1 USGS Topographic Site Location Map Figure 2 Site Map Figure 3 Groundwater Elevation Map Figure 4 Groundwater Results Map Figure 5 Benzene Isoconcentration Map Figure 6 Water Supply Well Radius Map TABLES Table 1 Water Supply Well Information Table 2 Monitoring Well Construction and Groundwater Elevation Data Table 3 Summary of Groundwater Analytical Results APPENDICES Appendix A Tables of Previous Groundwater Elevations and Analytical Results Appendix B Field Documentation and Photographs Appendix C Laboratory Data Reports Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 i SITE INFORMATION Date of Report: August 17, 2023 NCDEQ Incident No: 29832 NCDEQ UST No.: FA-3910 Site Name: Clark Brothers Site Location: Corner of Green Street and College Street Clarkton, Bladen County, North Carolina 28433 Latitude: N 34.487809 Longitude: W 78.656136 UST Owner/ Operator: Brisson Oil Company (Dissolved) Current Property Owner: Gary Michael Melvin P.O. Box 814 Clarkton, North Carolina 28433 Current Property Occupant: N/A- property is not currently occupied. Currently used for parking for adjacent business. Consultant: ESP Associates, Inc. P.O. Box 7030 Charlotte, North Carolina 28241 (704) 583-4949 Laboratory: Pace Analytical Services, LLC NCDEQ No. 5342 9800 Kincey Avenue Huntersville, North Carolina 28028 (704) 875-9092 Release Information: Release Discovery Date: unknown, discovered in 2003 Estimate Quantity: Unknown Cause of Release: Leaking UST system Source of Release: Possibly two 6,000-gallon USTs and an additional two to four USTs of unknown size Active Tanks: None Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 ii I, Christopher J. Ward, a Professional Geologist for ESP Associates, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. ESP Associates, Inc. is licensed to practice both geology and engineering in North Carolina. ESP Associates, Inc.’ certification numbers are: Geology: C-556 / Engineering: F-1407 Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 iii EXECUTIVE SUMMARY This executive summary section provides an abbreviated reporting of our Site observations and findings. Refer to the main text and appendices for a complete reporting of our observations and findings. ESP Associates, Inc. (ESP) has completed a Subsequent Monitoring Report documenting assessment activity performed at the Clark Brothers site (Incident No. 29832). The site is an approximately 0.21-acre developed site (Tax Parcel No. 0007734) located at the corner of North College Street and West Green Street in Clarkton, Bladen County, North Carolina. This report was completed to summarize the findings of assessment activities performed on June 14, 2023, in accordance with North Carolina Department of Environmental Quality (NCDEQ), Task Authorization No. 1, approved on May 22, 2023. The work was performed as part of the State Lead Contract #N70522-D between NCDEQ and ESP. This report was prepared in general accordance with the 15A NCAC 2L .0115 regulations and the NCDEQ Underground Storage Tank (UST) Section Guidelines for Assessment and Corrective Action for UST Releases, January 2021, under the supervision of Christopher J. Ward, North Carolina registered professional geologist (North Carolina License No. 1600). Field activities performed by ESP on June 14, 2023, included: • Gauging static water levels in monitoring wells MW-18, MW-19, MW-20, and MW-21; • Gauging the level of free product in MW-21; and • Collecting groundwater samples from MW-18, MW-19, and MW-20, along with a field duplicate. Although planned, ESP was unable to obtain a groundwater sample from MW- 21 as free product was present. Collected water samples were analyzed for volatile organic compounds (VOCs) for comparison to both North Carolina Groundwater Quality Standards 15A NCAC 2L .0202 (2L Standards) and Gross Contaminant Levels (GCLs). Based on results of the above field activities and previous reporting, ESP concludes the following: • Static water level depths beneath the site ranged from 11.10 ft to 12.60 ft bTOC; • The general direction of shallow groundwater flow beneath the site is toward the south- southwest; • The site and surrounding areas are connected to municipal water which obtains its water from a water supply well (TOC WSW-1) located approximately 1,000 feet northwest of the site. No other water supply wells have been identified within 1,000 feet of the site; • Free product was measured at a thickness of 0.05 ft in MW-21 and thus a groundwater sample was not collected for laboratory analysis; Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 iv • The AFVR event conducted on June 29, 2022, appears to have reduced the thickness of free product in MW-21 but did not eliminate its presence; • No VOCs were detected above their GCLs in any of the sampled monitoring wells; • Several VOCs were detected above their respective 2L standards in MW-18, MW-19, and MW-20; • A comparison of groundwater analytical results from the June 14, 2023, sampling event to sampling events conducted since April 2019, reveals that constituent concentrations in MW-18 have generally remained relatively stable; while concentrations in MW-19 and MW-20 have generally decreased.; and • The June 29, 2022, AFVR event using MW-21 appears to have reduced free product thickness in MW-21 while dissolved concentrations in site monitoring wells decreased. Based on the above results, ESP offers the following recommendations: • Continue to sample site monitoring wells on a semi-annual basis to further understand concentration trends and plume stability; • Continue to gauge free product thickness in MW-21. Purge and obtain groundwater sample if no product is present; • Consider an additional AFVR event on MW-21 to extract free product and reduce dissolved contaminant concentrations; and • Consider installing ORC sleeves in MW-18, MW-20, and MW-21 to further aid in contaminant degradation and plume stability. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 1 1.0 INTRODUCTION 1.1 Site Setting The Clark Brothers site is an approximate 0.21-acre site (Tax Parcel No. 0007734) located at the northwest corner of the intersection of North College Street and West Green Street in Clarkton, Bladen County, North Carolina (see Figures 1 and 2). The site was originally the location of Clark Brothers convenience store. No physical structures are presently on the site which currently serves as a paved parking lot for the adjacent Melvin Automotive and includes various parked automobiles in disrepair. The site is bounded to the north by a garage for Melvin Automotive; to the west by an undeveloped lot; to the south by West Green Street and beyond by a Family Dollar; and to the east by North College Street and beyond by a vacant bank. 1.2 Site Geology and Hydrogeology Consideration of surface and subsurface drainage and geology are of interest since they provide an indication of the direction that contamination, if present on-site or off-site, could be transported. The site is in the Coastal Plain Region, or Inner Coastal Plains. This region is a higher, denser area of sandy soil. The Coastal Plain Region was developed on loose, unconsolidated, and flat layers of sediment, caused by sea level changes and erosion of the mountains. Most parts of the Coastal Plain Region consist of well to moderately well-drained loamy soils. The site is underlain by a sequence of marine sediments of the Cretaceous age known as the Black Creek Formation (Kb). The Black Creek Formation consists of thin beds of fine grained, micaceous sand and thick beds of coarse sand with fossiliferous clay in the upper layers. The soil on the site was found to consist of Dragston fine sandy loan, 0 to 2 percent slopes (Da). Da soil types are found in the uplands. They are developed from beds of sand that grade into and are interbedded with light sandy clays. Da soil types are somewhat poorly drained, with slow runoff, and depth to the water table is at or near the surface in lower areas. Groundwater at the site is supplied by the Black Creek Aquifer. The aquifer’s characteristics are lagoonal to marine consisting of thinly laminated clay interlayered with sand. Sediments in the subsurface are highly organic and are from the Black Creek and Middendorf Formations. On average, the Black Creek Aquifer consists of “nearly 60 percent sand”, and the hydraulic conductivity ranges from 15 to 50 feet/day, averaging 28 feet/day. Recharge of the groundwater is the result of downward percolation from the overlying aquifers. Discharge is typically into streams where there are channels cut into it or its overlying confining unit. The depth to the water table is not consistent and is dependent upon several factors that include the amount of rainfall, permeability of the soil, and the influences of groundwater pumping. Based Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 2 on depth-to-water level measurements, the general groundwater flow direction beneath the site is estimated to be toward the south and southwest. 1.3 Surface Water An unnamed intermittent stream is located approximately 890 feet north-northeast of the source area (see Figure 1). The stream does not serve as a runoff or tributary to a larger body of water. There are no other notable surface water features within 1,000 feet of the site. 1.4 Water Supply Wells Based on previous receptor surveys conducted by others, a water supply well (TOC WSW-1) was identified on an upgradient property located at 81 Elm Street approximately 1,000 feet northwest of the site (see Figure 6). This water supply well reportedly serves as the municipal water supply for the city of Clarkton. No other water supply wells have been identified within 1,000 feet of the site. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 3 2.0 SITE HISTORY The following description of historical site activities was obtained from a report titled “Subsequent Monitoring Report, Clark Brothers (Incident #29832)” dated November 2, 2021, by Terracon Consultants Inc. (Terracon) and a report titled “Aggressive Fluid Vapor Recovery Event Letter Report, Clark Brothers” dated August 4, 2022, by Terracon. • The site and surrounding areas are connected to municipal water which obtains its water from a water supply well (TOC WSW-1) located approximately 1,000 feet northwest of the site. • The site’s former UST system comprised of two 6,000-gallon gasoline USTs and an additional two to four USTs of unknown capacity. The entire UST network was removed in 1998. • Monitoring wells MW-18, MW-19, MW-10, and MW-21 were installed in association with the groundwater assessment for the Butler’s BP (Incident #21816), which is directly adjacent to the Clark Brothers site. • A release was identified when free product was observed in MW-20 and MW-21 during a 2003 sampling event for the Butler’s BP site. Free product has been consistently observed in MW-21 since 2012. • There were also several adjacent and off-site petroleum release incidents and/or former gasoline stations that may have contributed to the contamination in the on-site and off- site monitoring wells. These incidents/properties included Butler’s BP (Incident #21816) at 10519 South College Street, a former gasoline station at 7 East Green Street, and the former Green Residence (Incident #29902) at 10528 South College Street. • In 2016, S&ME performed a site reconnaissance and receptor survey on the site. They confirmed the presence of the town’s municipal water supply well within 1,000 feet of the site and confirmed the presence of free product in MW-21. It was also confirmed that the site is situated within a Well Head Protection Area. • In 2016, NCDEQ closed out the Butler’s BP incident and transferred ownership of MW- 18 through MW-21 to the State-Lead Program to continue monitoring and remedial efforts on the Clark Brothers site. • In 2019, S&ME mobilized to conduct a groundwater sampling event, and to gauge the free product present in MW-21. S&ME measured 0.88 feet of free product present in MW-21. Several constituents were present above their 2L standards in MW-18 through MW-20, but none exceeded their GCL. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 4 • In 2019 and 2020, S&ME would re-mobilize each year to continue to monitor development of the plume and gauge for free product. Both sampling events yielded the same results, with free product present in MW-21 and several constituents above 2L standard but below GCL in MW-18 through MW-20. • On September 16, 2021, Terracon mobilized to conduct a sampling event for monitoring wells MW-18 through MW-20. MW-21 was to be hand bailed of free product and sorbent socks were to be installed to reduce free product in the well. Approximately 7 gallons of free product were removed from MW-21 and disposed of offsite. After sampling, an Oxygen Release Compound (ORC) sock was installed in MW-20 to reduce the concentration of petroleum constituents. • On June 29, 2022, Terracon, along with subcontractor Hazmat Emergency Response and Remediation (HERR), mobilized to perform an Aggressive Fluid Vapor Recovery event (AFVR). HERR proceeded to perform the recovery for 8 hours, extracting the vapors via MW-21. Approximately 0.02 gallons of gasoline were recovered from MW-21, with a total liquid recovery volume of 1,375 gallons of fluid. Historical groundwater elevations and analytical results are provided in Appendix A. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 5 3.0 FIELD ACTIVITIES Field activities performed by ESP on June 14, 2023, included: • Gauging static water levels in monitoring wells MW-18, MW-19, MW-20, and MW-21; • Gauging the level of free product in MW-21; and • Collecting groundwater samples from MW-18, MW-19, and MW-20, along with a field duplicate. Although planned, ESP was unable to obtain a groundwater sample from MW- 21 as free product was present. Sample locations are depicted on Figure 2. Field logbook entries along with water level survey, groundwater sampling, and field instrument calibration forms were completed in the field to document site activities (see Appendix B). Photographs are also provided in Appendix B. Details of field activities are provided below. 3.1 Free Product Evaluation On June 14, 2023, free product was measured using an oil/water interface probe in monitoring well MW-21 at a thickness of 0.05 feet. Free product has been observed in MW-21 consistently since 2012 and was previously reported at a thickness of 1.04 feet on September 21, 2021. The AFVR event conducted on June 29, 2022, appears to have reduced the thickness of free product in MW- 21 but did not eliminate its presence. 3.2 Water Level Gauging On June 14, 2023, prior to purging or collecting groundwater samples, depth to groundwater from the top of casing (TOC) within each monitoring well was measured and recorded using a decontaminated electronic water level meter. The water level measurements were collected by first removing covers and plunger caps from all site monitoring wells and allowing water within the wells to stabilize. The electronic water level meter probe was then lowered into the well and the depth to water measured relative to the well’s TOC. As noted on Table 1, static water level depths ranged from 11.10 ft to 12.60 ft below top of casing (ft bTOC). Figure 3 depicts the groundwater elevations based off a benchmark of 100.00 ft given to an arbitrary point on site as noted in previous reporting. As depicted in Figure 3, shallow groundwater flow beneath the site is toward the south and southwest. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 6 3.3 Groundwater Sampling On June 14, 2023, groundwater samples were collected from monitoring wells MW-18, MW-19, and MW-20. Due to the presence of free product in MW-21, a groundwater sample was not collected for analysis from this monitoring well. Groundwater samples were collected using dedicated and disposable polyvinyl chloride (PVC) bailers (1.5” x 3’) attached to braided nylon rope. Prior to groundwater sample collection, each well was purged using the bailer. During purging, water quality parameters including pH, conductivity, temperature, and turbidity were measured using calibrated field water quality instruments. Readings were taken at the start of purging and periodically until a minimum of three well volumes were removed from the well and water quality parameters stabilized. Following purging, a groundwater sample for laboratory analysis was collected from the well using the bailer. The water quality parameters were recorded on groundwater sampling forms along with time, water level depth, and cumulative volume of water purged (see groundwater sampling forms in Appendix B). Groundwater samples were collected following Guidelines for Sampling by the Underground Storage Tank Section, Division of Waste Management, North Carolina Department of Environmental Quality (NCDEQ, 2022). Groundwater samples were placed in laboratory- prepared vials preserved with hydrochloric acid (HCl), labeled, and stored on ice in a cooler for subsequent delivery under standard chain-of-custody (COC) procedures to Pace Analytical (Pace), a North Carolina-certified laboratory, located in Huntersville, North Carolina, for analysis. The groundwater samples were analyzed for VOCs by EPA Method 6200B including MTBE, ethylene dibromide (EDB), and isopropyl ether (IPE). 3.4 Field Quality Control Sampling and Analysis A field duplicate groundwater sample, designated Field Duplicate, was collected on June 14, 2023, from MW-19 and analyzed for VOCs by EPA Method 6200B including MTBE, EDB, and IPE to assess variance between collected samples. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 7 4.0 ANALYTICAL RESULTS Results of the laboratory analysis of groundwater samples MW-18, MW-19, and MW-20 are tabulated in Table 3. As noted in Table 3, the analytical results are compared to both 2L standards and GCLs. The Pace laboratory analytical report is provided in Appendix C. No analytes were detected at concentrations exceeding their respective GCLs; however, various analytes were detected at concentrations greater than their respective 2L standards in each of the three sampled monitoring wells (see Table 3). A summary of the analytical results is as follows: • In MW-18, benzene (21.6 µg/L), cumene (83.3 µg/L), naphthalene (45.0 µg/L), n- propylbenzene (176 µg/L), and total xylenes (574 µg/L) were all detected above their respective 2L standards; • In MW-19, naphthalene (44.9 µg/L) was detected above its 2L standard; and • In MW-20, benzene (726 µg/L), naphthalene (277 µg/L), and total xylenes (1,471 µg/L) were all detected above their respective 2L standards. Groundwater sampling results relative to each well location depicting VOCs exceeding their 2L standard or GCL are provided on Figure 4 while Figure 5 depicts the approximate lateral extent of the dissolved benzene groundwater plume. A comparison of groundwater laboratory analytical results from the June 14, 2023, sampling event to sampling events conducted since April 2019, reveals the following: • In MW-18, constituent concentrations have generally remained relatively stable; • In MW-19, constituent concentrations have generally decreased somewhat; and • In MW-20, constituent concentrations have decreased. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 8 5.0 CONCLUSIONS AND RECOMMENDATIONS Based on results of the above field activities and previous reporting, ESP concludes the following: • Static water level depths beneath the site ranged from 11.10 ft to 12.60 ft bTOC; • The general direction of shallow groundwater flow beneath the site is toward the south- southwest; • The site and surrounding areas are connected to municipal water which obtains its water from a water supply well (TOC WSW-1) located approximately 1,000 feet northwest of the site. No other water supply wells have been identified within 1,000 feet of the site; • Free product was measured at a thickness of 0.05 ft in MW-21 and thus a groundwater sample was not collected for laboratory analysis; • The AFVR event conducted on June 29, 2022, appears to have reduced the thickness of free product in MW-21 but did not eliminate its presence; • No VOCs were detected above their GCLs in any of the sampled monitoring wells; • Several VOCs were detected above their respective 2L standards in MW-18, MW-19, and MW-20; • A comparison of groundwater analytical results from the June 14, 2023, sampling event to sampling events conducted since April 2019, reveals that constituent concentrations in MW-18 have generally remained relatively stable; while concentrations in MW-19 and MW-20 have generally decreased.; and • The June 29, 2022, AFVR event using MW-21 appears to have reduced free product thickness in MW-21 while dissolved concentrations in site monitoring wells decreased. Based on the above results, ESP offers the following recommendations: • Continue to sample site monitoring wells on a semi-annual basis to further understand concentration trends and plume stability; • Continue to gauge free product thickness in MW-21. Purge and obtain groundwater sample if no product is present; • Consider an additional AFVR event on MW-21 to extract free product and reduce dissolved contaminant concentrations; and • Consider installing ORC sleeves in MW-18, MW-20, and MW-21 to further aid in contaminant degradation and plume stability. Subsequent Monitoring Report ESP Project No. 23-00200-020 Clark Brothers (Incident #29832) August 17, 2023 9 6.0 REFERENCES Bladen County, North Carolina GIS website, https://gis.bladenco.org/. 1985 Geologic Map of North Carolina, The North Carolina Geological Survey, Phillip M. Brown, 1985. Guideline for Sampling Underground Storage Tank Section, Division of Waste Management, North Carolina Division of Environmental Quality, March 7, 2022, Change 4. Terracon, November 2, 2021, Subsequent Monitoring Report: Clark Brothers, Clarkton, Bladen County, North Carolina. Terracon, August 4, 2022, Letter Report: Aggressive Fluid Vapor Recovery Event Letter Report, Clark Brothers, Clarkton, Bladen County, North Carolina. FIGURES 0 350 700Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-020 ET CWDATE08/01/2023 FIGURE 1USGS TOPOGRAPHIC SITE LOCATION MAPµAs Shown CHARLOTTE, NORTH CAROLINA SITE BOUNDARY All locations are approximate. CLARK BROTHERS SITE LEGEND: < < < < MW-21 MW-20 MW-19 MW-18 MELVIN AUTOMOTIVE NORTH COLLEGE STREETCOX STREETWEST GREEN STREET 0 20 40Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-020 ET CWDATE08/01/2023 FIGURE 2SITE MAPµAs Shown CHARLOTTE, NORTH CAROLINA SITE BOUNDARY MONITORING WELL All locations are approximate. CLARK BROTHERS SITE LEGEND: < < < < < MW-21 MW-20 MW-19 MW-18NORTH COLLEGE STREETCOX STREETWEST GREEN STREET 0 10 20Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-020 ET CWDATE08/01/2023 FIGURE 3GROUNDWATER ELEVATION MAPJUNE 14, 2023µAs Shown CLARKTON, NORTH CAROLINA SITE BOUNDARYMONITORING WELLESTIMATED GROUNDWATER ELEVATION CONTOURESTIMATED GROUNDWATER FLOW DIRECTION All locations are approximate. CLARK BROTHERS SITE LEGEND: < < < < < MW-21 MW-20 MW-19 MW-18NORTH COLLEGE STREETCOX STREETWEST GREEN STREET 0 10 20Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-020 ET CWDATE08/01/2023 FIGURE 4GROUNDWATER RESULTS MAPJUNE 14, 2023µAs Shown CLARKTON, NORTH CAROLINA SITE BOUNDARY MONITORING WELL All locations are approximate. CLARK BROTHERS SITE LEGEND: < < < < < MW-21 MW-20 MW-19 MW-18NORTH COLLEGE STREETCOX STREETWEST GREEN STREET 0 10 20Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-00200-020 ET CWDATE08/01/2023 FIGURE 5BENZENE ISOCONCENTRATION MAPJUNE 14, 2023µAs Shown CLARKTON, NORTH CAROLINA SITE BOUNDARY MONITORING WELL ISOCONCENTRATION CONTOUR All locations are approximate. CLARK BROTHERS SITE LEGEND: < PLANK ROAD GADDY'S FERRY ROADED WSW-6 WSW-3 ED WSW-8 ED WSW-9 ED ED WSW-2 WSW-11 WSW-5 ED ED WSW-4 WSW-1A&B ED ED WSW-12 WSW-14 ED ED 500-ft 1,000-ft 0 110 220Feet ESP Associates, Inc. P.O. Box 7030Charlotte, NC 28241 Phone 704.583.4949 www.espassociates.com SHEET TITLE PROJECT PROJECT NO. SCALE DRAWN BY CHECKED BY 23-0200-020 ET CWDATE08/07/2023 FIGURE 6WATER SUPPLY WELL RADIUS MAPµAs Shown CLARKTON, NORTH CAROLINA SITE BOUNDARYWATER SUPPLY WELLWATER SUPPLY WELL (ABANDONED)RIVERINE WETLANDFRESHWATER POND All locations are approximate. CLARK BROTHERS SITE LEGEND: ED ED TABLES Table 1 Water Supply Well Information Clark Brothers Clarkton, North Carolina NCDEQ Incident No. 29832 Well No.Property Owner Mailing Address Property Address Distance from Source Area (feet) Hydraulic Relationship to Source Area Well Status/Use Municpal Water Parcel ID No. TOC WSW-1 Town of Clarkton P.O. Box 307 Clarkton, NC 28433 81 Elm Street Clarkton, NC 28433 ~1,000 feet northwest Upgradient Active - Potable Yes (Municipal Well) 120606299472 Notes: Information obtained from previous monitoring report. Table 2 Monitoring Well Construction and Groundwater Elevation Data Clark Brothers Clarkton, North Carolina NCDEQ Incident No. 29832 Well ID Date Intalled Screened Interval (ft BGS) a Bottom of Well (ft BGS) a Top of Casing Elevation (ft) a,b Date Water Level Measured Depth to Water from Top of Casing (ft bTOC) Groundwater Elevation (ft) Free Product Thickness (ft) 4/17/19 8.90 88.69 .--- 8/11/20 10.20 87.39 .--- 2/8/21 8.87 88.72 .--- 9/16/21 11.78 85.81 .--- 6/14/23 12.60 84.99 .--- 4/17/19 9.09 88.57 .--- 8/11/20 10.09 87.57 .--- 2/8/21 8.00 89.66 .--- 9/15/21 10.67 86.99 .--- 6/29/22 12.67 84.99 .--- 6/14/23 12.46 85.20 .--- 4/17/19 8.78 88.16 .--- 8/11/20 10.28 86.66 .--- 2/8/21 8.43 88.51 .--- 9/15/21 10.07 86.87 .--- 6/29/22 12.65 84.29 .--- 6/14/23 11.97 84.97 .--- 4/17/19 8.93 88.35 0.88 8/11/20 9.93 87.20 0.67 2/8/21 8.36 88.72 0.60 9/15/21 11.27 86.13 1.04 6/29/22 11.86 84.98 0.27 6/14/23 11.10 85.58 0.05 Notes: a Top of casing elevations, screened intervals, and bottom of well measurements are from previous consultants' monitoring reports. b Top of casing elevations are based off of an assumed benchmark elevation obtained from a prior report prepared by Terracon. -- - no measureable free product BGS - below ground surface ft - feet ft bTOC - feet below TOC FP - free product TOC - top of casing 17.0 17.0 MW-21 10/17/2003 2.0-17.0 96.6417.0 c Groundwater elevation adjusted for measurable free product by using the following calculation: (TOC Elevation - Depth to water) + (FP thickness * 0.729), where 0.729 is the specific gravity for automotive gasoline. MW-18 MW-19 MW-20 10/17/2003 10/17/2003 10/17/2003 2.0-17.0 2.0-17.0 2.0-17.0 96.94 97.66 17.0 97.59 Table 3 Summary of Groundwater Analytical Results Clark Brothers Clarkton, North Carolina NCDEQ Incident No. 29832 (Page 1 of 1) 1 70 70 70 70 0.02 70 600 70 20 6 70 70 600 400 400 500 500 500 5,000 5,900 8,800 14,750 70,000 50 70,000 80,000 30,500 20,000 6,000 26,100 70,000 260,000 28,500 24,100 50,000 50,000 50,000 4/17/19 17.0 33.0 29.0 3.6 <1.7 <1.9 <1.7 420 18.0 <2.5 180 270 <1.1 44.0 200 130 254 210 44.0 8/11/20 28.0 44.0 27.0 3.5 <0.85 <0.95 <0.85 400 79.0 <1.2 41.0 200 <0.55 23.0 200 110 472 430 42.0 9/16/21 66.0 <8.0 13.0 <8.0 <8.0 <8.0 <8.0 760 68.0 <8.0 33.0 150 <8.0 87.0 220 130 1,740 1,500 240 6/14/23 21.6 <1.2 <1.0 <0.81 <1.1 <0.68 <0.77 397 83.3 <1.1 45.0 176 <0.73 17.4 228 126 574 498 75.9 4/17/19 8.7 4.3 3.9 <1.7 <1.7 <1.9 <1.7 360 27.0 <2.5 100 53.0 1.7 340 200 35.0 1,100 680 330 8/11/20 8.5 11.0 4.6 <1.7 <1.7 <1.9 <1.7 650 50.0 <2.5 96.0 80.0 <1.1 270 430 100 1,900 1,600 300 9/16/21 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 970 64.0 <20.0 110 130 <20.0 620 480 160 3,410 2,700 710 6/14/23 0.61 <0.49 <0.40 <0.32 <0.43 <0.27 <0.31 57.5 22.5 <0.42 44.9 39.6 <0.29 1.5 36.8 3.8 45.5 43.0 2.5 4/17/19 3,100 16.0 <6.4 <6.8 <6.8 12.0 <6.8 1,700 100 <10.0 530 130 27.0 450 1,100 380 4,900 3,900 1,000 8/11/20 1,900 29.0 9.2 <3.4 <3.4 6.8 <3.4 1,500 33.0 <5.0 410 110 <2.2 200 970 300 3,570 3,200 370 9/16/21 2,800 <20.0 <20.0 <20.0 <20.0 <20.0 <20.0 1,100 48.0 <20.0 260 67.0 <20.0 98.0 570 250 2,150 1,900 250 6/14/23 726 <2.4 <2.0 <1.6 <2.2 <1.4 <1.5 475 28.4 <2.1 277 29.0 10.1 598 278 92.2 1,471 1,110 361 4/17/19 8/11/20 9/16/21 6/14/23 Notes: Bold values indicate constituent concentrations were greater than the 2L Standard. Yellow highlighted values indicate constituent concentrations were greater than the GCL. Samples presented prior to the June 14, 2023 event were obtained from previous consultants reports. <## - less than the Method Detection Limit (MDL) µg/L - micrograms per liter 2L Standard - North Carolina 02L standard for groundwater GCL - Gross Contaminant Level J - Estimated concentration above the method detection limit and below the reporting limit. NR - not reported 1.5 <0.49 <0.40 <0.32 56.7Field Duplicate (MW-19) GCL (µg/L) Sample ID Collection Date MW-18 MW-19 6/14/23 2L Standard (µg/L)n-PropylbenzeneBenzenen-Butylbenzenesec-Butylbenzenetert-Butylbenzene1,2-Dibromethane (EDB)Diisopropyl ether (IPE)ChloroformEthylbenzeneIsopropylbenzene (cumene)Methyl Tert-Butyl Ethyl (MTBE)Naphthalene<0.42<0.43 <0.27 <0.31 43.321.0 36.8 2.1 36.9 4.0 49.5 46.8 2.7Styrene<0.29 o-XyleneToluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylene (Total)m&p-XyleneMW-20 Not Sampled - Free Product Detected Not Sampled - Free Product Detected Not Sampled - Free Product Detected Not Sampled - Free Product Detected MW-21 APPENDICES APPENDIX A APPENDIX B APPENDIX C ESP Corporate Office 3475 Lakemont Boulevard Fort Mill, SC 29708 803.802.2440 Mailing Address: P.O. Box 7030 Charlotte, NC 28241 800.960.7317 | www.espassociates.com Concord 7144 Weddington Rd. NW Suite 110 Concord, NC 28027 704.793.9855 Cornelius 20484 Chartwell Center Dr. Suite D Cornelius, NC 28031 704.649.2863 Raleigh 2200 Gateway Centre Blvd. Suite 216 Morrisville, NC 27560 919.678.1070 Greensboro 7011 Albert Pick Rd Suite E Greensboro, NC 27409 336.334.7724 Wilmington 211 Racine Drive Suite 101 Wilmington, NC 28403 910.313.6648 Charleston 2154 North Center Street Suite E-503 North Charleston, SC 29406 843.714.2040 Nashville 500 Wilson Pike Circle Suite 310 Brentwood, TN 37027 615.760.8300 Pittsburgh One Williamsburg Place Suite G-5, Box 13 Warrendale, PA 15086 724.462.6606 Bradenton 518 13th Street West Bradenton, FL 34205 941.345.5451 Indianapolis 8673 Bash Street Indianapolis, IN 46256 317.537.6979 Albuquerque 1203 West Ella Drive Corrales, NM 87048 505.314.1322 Birmingham 291 Cahaba Valley Parkway North Suite A Pelham, AL 35124 205.664.8498 Vickrey & Associates, LLC - An ESP Company San Antonio 12970 Country Parkway San Antonio TX 78216 210.349.3271 Austin 3600 West Parmer Lane Suite 175 Austin, TX 78727 512.494.8014 McAllen 1216 East Jasmine Avenue Suite C McAllen, TX 78501 956.340.0045