WS-6603_19720_CA_GWRP_20120208

ACTIVE REMEDIATION MONITORING REPORT

FORMER PURGASON’S GROCERY
4956 HIGHWAY 54
GRAHAM, ALAMANCE COUNTY, NORTH CAROLINA
INCIDENT NO. 19720

Prepared For:

North Carolina Department of Environment and Natural Resources
UST Section
1637 Mail Service Center
Raleigh, North Carolina 27699-1637

Prepared By:

Progress Environmental, Inc.
P.O. Box 5884
Winston-Salem, North Carolina 27113

Progress Project 151183.004

February 8, 2013

February 8,2013
Ms. Linda Blalock
North Carolina Department of Environment and Natural Resources
Division of Waste Management, UST Section
163l Mail Service Center
Raleigh, North Carolina 27 699-1631
Subject:Active Remediation Monitoring Report
Former Purgason's Grocely
4956 Highway 54
Graham, Alamance County, North Carolina
Incident No. 19720
Progress Project No. 151183.004
Dear Ms. Blalock:
On behalf of the North Carolina Department of Environment and Natural Resources, Progress
Environmental, Inc. (Progress) is submitting this Active Remediation Monitoring Report for the
above-referenced site. Included in this report is a description of the field activities, the results
obtained, and the conclusions and recommendations.
This Active Remediation Monitoring Report has been prepared in general accordance with the
Underground Storage Tank Section guidelines presented in the NCDENR Guidelines for Assessment
and Corcective Actionfor UST Releases dated December l, 2008.
We appreciate your consideration and cooperation in the submission of this report. If you have any
questions concerning this report please feel free to contact us at [phone].
Sincerely,
PROGRESS EIIVIRONMENTAL, INC.
6" i. Ricks
Seni or Environmental Scientist
PO Box 5BB4 . Winston-Solem, NC 2Zl l3-5884
336-722-?999 Office . 336-722-9998 Fax
www. progresse nviro n mento l.com
s.oro$4'
ttl:o-itus

TABLE OF CONTENTS

1. BACKGROUND INFORMATION ........................................................................................1
2. FIELD ACTIVITIES................................................................................................................5
3. LABORATORY RESULTS.....................................................................................................5
4. CONCLUSIONS.......................................................................................................................5
5. RECOMMENDATIONS..........................................................................................................6
6. QUALIFICATIONS OF REPORT.........................................................................................6

FIGURES
Figure 1 -- Topographic Site Map
Figure 2 -- Site Location Map
Figure 3 -- Site Map
Figure 4 -- Summary of Detected Analytical Results Map

TABLE
Table 1 -- Summary of Groundwater Analytical Results

APPENDIX
Monitoring Well Sampling Data Sheets
Laboratory Data Sheets and Chain-of-Custody Records

Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

1
1. BACKGROUND INFORMATION

The site is the former Purgason’s Grocery located at 4956 Highway 54 in Graham, Alamance County,
North Carolina. The site is located in a rural area, sparsely developed with residential properties along
NC Highway 54. There is an active automobile repair facility occupying a portion of the on-site building
(Figures 1 and 2).

Four underground storage tanks (USTs): two 8,000-gallon gasoline, one 2,000-gallon diesel fuel, and one
500-gallon kerosene were registered to Janice Purgason who was listed as the tank owner. According to
the UST database records, these USTs were installed in 1972. In 1993, the site was inspected for UST
compliance and was found to be out of compliance since the USTs had been in temporary closure for
more than 12 months. Mrs. Purgason informed the inspector that she did not have the financial funds to
pay for the removal of the USTs.

In January and July 1999, Geophex conducted two soil sampling events at the site to determine if a
release had occurred from the UST systems. The soil samples confirmed a release from the diesel fuel
UST and the site was officially accepted into the Federal Trust Fund Program. Geophex also conducted
a water-supply well survey of the site area. Several water-supply wells were identified within 1,000 feet
of the source area.

On March 24 and 25, 2000, Geophex was contracted to supervise the removal of four USTs from the
Purgason’s Grocery site. One 2,000-gallon diesel fuel UST, one 500-gallon kerosene UST, and two
8,000-gallon gasoline USTs were removed. One soil sample was collected from the diesel UST pit, one
soil sample was collected from the kerosene UST pit, and two soil samples were collected from beneath
each of the gasoline USTs. Soil contamination was confirmed beneath both the diesel fuel and kerosene
USTs.

On May 11, 2000, three bedrock groundwater monitoring wells were installed at the site. The monitoring
wells were also sampled on May 11, 2000 for volatile organic compounds using EPA Methods 601 and
602. Detectable concentrations of petroleum compounds were not identified in the groundwater samples.
Please note, due to the nature of the releases at the site it would have been prudent to analyze the
groundwater samples for both volatile and semi-volatile organic compounds analyses.

Pyramid Environmental & Engineering, P.C. completed a Soil and Groundwater Assessment Report,
dated February 7, 2005. Their report concluded the following:

• Fifteen water-supply wells were identified within a 1,000-foot radius of the source area. Five water-
supply wells are located within 500 feet of the site.

• Analytical results of the soil samples collected from eleven soil borings indicated concentrations of
petroleum compounds exceeding their respective Soil-to-Groundwater Maximum Soil Contaminant
Concentrations (MSCCs) in samples collected within the former diesel UST pit, the diesel pump island,
and the former kerosene UST pit. Trace concentrations of petroleum compounds were also detected in
the soil samples collected along the gasoline product line. None of the detected concentrations exceeded
their respective Residential MSCCs.

• Analytical results from the groundwater samples collected from temporary monitoring wells indicated
concentrations of petroleum-related compounds exceeding their respective North Carolina 2L
Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

2
Groundwater Quality Standards (NC2LGWQS) in the area of the former diesel and kerosene USTs.
Please note, groundwater samples were not collected in the area of the former gasoline USTs or the pump
islands.

• None of the compounds detected in the groundwater samples were detected at concentrations above the
applicable Gross Contamination Levels (GCLs).

• The most recent groundwater samples collected from the nearby water-supply wells did not contain
detectable concentrations of targeted compounds.

On May 9 and 10, 2011 Progress and Stewart’s Grading and Hauling (Stewart’s) were on-site to excavate
the accessible impacted soil located in the vicinity of the former UST system. Based on previously
collected soil data and persisting elevated concentrations of petroleum-related compounds in the
groundwater, Progress supervised the excavation of approximately 387.70 tons of contaminated soil in
the vicinity of the former UST system. Soil excavation activities were conducted utilizing a track
mounted excavator. Note that soil excavation activities were limited by the presence of the on-site
building to the east and underground utilities from the building to the former pump island.

Two excavation areas were completed at the site. Progress collected soil samples along the sidewalls of
the southern excavation (N-1, E-1, W-1, and S-1) and disposal soil sample (Disposal-1) from the
excavated soil for confirmation/disposal purposes. Soil samples (N-2, E-2, S-2, and W-2) and disposal
soil sample (Disposal-2) were collected from the northern excavation. Upon completion of the southern
soil excavation activities, the over-excavation area had a width of approximately 26 feet, an approximate
length of 30 feet, and a depth ranging from 10 to 13 feet below land surface (bls). The northern
excavation (which had a triangular shape) had a width of approximately 15 feet, a length of
approximately 18 feet and a depth of approximately ten feet bls. Former dispenser islands and concrete
material from the previous excavations were encountered in the northern excavation. Soil samples were
not collected from the base of the excavations due to the historical static groundwater levels ranging from
approximately six to eight feet bls. The soil samples were collected using the bucket of the trackhoe and
transported to Pace Analytical Services (Pace) under chain-of-custody via their courier for analysis. The
sidewall soil samples were analyzed for volatile organic compounds using EPA Method 8260/5035,
semi-volatile organic compounds using EPA Method 8270, and volatile and extractable petroleum
hydrocarbons (VPH & EPH) using the Massachusetts Department of Environmental Protection
(MADEP) Method. The disposal soil samples were analyzed by Pace for gasoline and diesel range total
petroleum hydrocarbons (TPH) using EPA Methods 8015/5035 and 3550, respectively. In addition,
approximately 150 pounds of PermeOx Plus® was placed and mixed into the base of the southern
excavation and 50 pounds into the northern excavation prior to backfilling. The excavation was
backfilled with clean fill material and the ground surface covered with stone.

The results of the laboratory testing indicated the following:

• Laboratory analysis of disposal soil samples Disposal-1 and Disposal-2 detected total petroleum
hydrocarbons (TPH) as gasoline and as diesel above the NC Action Levels of 10 mg/Kg.

• Laboratory analysis of soil sample N-1 detected targeted compounds above their respective Soil-
to-Groundwater Maximum Soil Contaminant Concentrations (MSCCs) and benzo(a)pyrene
above its Residential MSCC.

Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

3
• Laboratory analysis of soil samples E-2 and N-2 detected targeted compounds above their
respective Soil-to-Groundwater MSCCs. Please note, further lateral excavation on these
sidewalls was not feasible without electrical service disruption and building shoring activities.

• Laboratory analysis of soil samples E-1, S-1, W-1, S-2, and W-2 detected targeted compounds at
concentrations below their respective Soil-to-Groundwater MSCCs.

Based on the results of the assessment, Progress concluded the following:

• Approximately 387.70 tons of petroleum impacted soil was excavated from two separate
excavations at the site. Following the soil excavation and prior to backfilling the excavation with
imported material, Progress implemented in-situ chemical remediation by placing approximately
150 pounds of PermeOx Plus® in the base of the southern excavation and 50 pounds in the
northern excavation.

• Laboratory analysis of soil sample N-1 detected targeted compounds above their respective Soil-
to-Groundwater MSCCs and benzo(a)pyrene above its Residential MSCC. Benzo(a)pyrene is a
polycyclic aromatic hydrocarbon that could be related to the burning of organic material or coal.

• Laboratory analysis of soil samples E-2 and N-2 detected targeted compounds above their
respective Soil-to-Groundwater MSCCs. Note that additional excavation along these sidewalls
was not feasible.

• Laboratory analysis of soil samples E-1, S-1, W-1, S-2, and W-2 detected targeted compounds at
concentrations below their respective Soil-to-Groundwater MSCCs.

Fifteen water-supply wells were previously identified by others within 1,000 feet of the site and five
water-supply wells were identified within 500 feet of the site.

Based on the removal of the accessible impacted soil within the source area and the concentrations of
petroleum-related compounds in the groundwater prior to the excavation of the contaminated soil,
Progress recommended the following:

• Install one monitoring well in the vicinity of each of the two excavation areas.

• Conduct a groundwater sampling event following the installation of site monitoring wells and
again in approximately three months to verify the effectiveness of the remedial efforts.

• Survey the top of casing of each monitoring well relative to a benchmark to determine the
groundwater flow direction beneath the site. Based on the groundwater flow direction and the
laboratory test results it may be necessary to install and sample additional monitoring wells to
adequately define the horizontal extent of groundwater contamination.

Because Progress had utilized the chemical in-situ remediation product PermeOx Plus®, Progress
recommended monitoring the groundwater quarterly to document the long-term effect of the remedial
activities on the petroleum-related compounds previously detected in the groundwater.

Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

4
On July 8, 2011 Progress supervised and documented the installation of two permanent two-inch
monitoring wells (MW-4 and MW-5) in the area of the southern excavation and the northern tank pit,
respectively, using the hollow stem auger drilling method. Progress sampled monitoring wells MW-1
through MW-5 on July 26, 2011 (Progress Project 151183.002, Source Investigation Report, dated
August 23, 2011). Laboratory analysis of the groundwater sample collected from monitoring well MW-4
detected 1,2-dichloroethane, di-isopropyl ether (IPE), and methyl-tert-butyl ether (MTBE) above their
respective NC2LGWQS. Laboratory analysis of the groundwater samples collected from monitoring
wells MW-1, MW-2, MW-3, and MW-5 did not detect targeted compounds above their respective
NC2LGWQS. Progress recommended completing additional groundwater monitoring (quarterly) to
document the effect of the remedial activities on the petroleum-related compounds in the groundwater for
at least one year.

Progress sampled monitoring wells MW-1 through MW-5 on June 1, 2012 (Progress Project 151183.003,
Active Remediation Monitoring Report, dated June 19, 2012). Laboratory analysis of the groundwater
sample collected from monitoring well MW-4 detected 1,2-dichloroethane and MTBE above their
respective NC2LGWQS; however, the concentrations detected during the June 2012 sampling event
demonstrate substantial decreases as compared to the results of the July 2011 sampling event.
Laboratory analysis of the groundwater samples collected from monitoring wells MW-1, MW-2, MW-3,
and MW-5 did not detect targeted compounds above their respective NC2LGWQS.

Progress recommended completing additional groundwater monitoring (quarterly) to document the effect
of the remedial activities on the petroleum-related compounds in the groundwater for at least one year.

Site Geology and Hydrogeology

According to the Geologic Map of North Carolina, the subject site is located in the Carolina Slate Belt of
the Piedmont Physiographic Province of North Carolina. The site is located in an area underlain by rocks
composed of metavolcanic rocks. In the Piedmont Physiographic Province, groundwater generally
occurs under water-table conditions and is stored in the pore space between individual grains of residual
soil and in the fractures within the underlying parent rock. Due to the intense shearing associated with
the thrust faulting in the area, it can be expected that the fractures play a major role in the flow of
groundwater in the subsurface.

Recharge to the water table is primarily by precipitation infiltrating the upper soils and percolating
downward, under the influence of gravity, to the groundwater table. Typically, the water table is not a
level surface, but a subdued reflection of the land surface. However, the depth to the water table is not
constant, and depends on many factors, which include the amount of rainfall, the permeability of the soil,
and the amount of groundwater being pumped in the area.

Based on our review of the topographic map and on-site observation, the site is located along the western
edge of a north south trending ridge. Groundwater generally flows in directions sub-parallel to the
ground surface slopes and under the influence of gravity toward points of discharge such as creeks,
swamps, drainage swales, or pumped groundwater wells. Based on topographic inference, groundwater
beneath the site most likely flows to the south-southeast towards an unnamed intermittent stream (Figure
1).

Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

5
2. FIELD ACTIVITIES

Progress collected groundwater samples from the existing on-site monitoring wells (MW-1 through MW-
5, Figure 3) on January 24, 2013. Prior to sampling, a static water level measurement was collected from
each of the on-site monitoring well to determine the existing well volumes and to determine the
groundwater flow direction beneath the site. The water meter was decontaminated prior to use and in-
between wells by washing in a solution of Alconox detergent and deionized water followed by a rinse
with deionized water. The monitoring wells were then purged by evacuating at least three well volumes
using a new disposable bailer dedicated to the well. To further demonstrate that the wells were
sufficiently purged, Progress continued to purge the wells until the following geochemical field
measurements had stabilized; temperature, and pH. Progress utilized an Oakton ph/CON 10 Series for
pH and conductivity calibrated using the manufacturers’ recommendations. Copies of the monitoring
well sampling sheets used during the field activities to document well volumes, geochemical testing and
other pertinent information are included in the Appendix.
Following purging, a groundwater sample was collected from the monitoring wells using disposable
bailers. Care was taken to minimize volatilization of the samples during the sampling process.
Immediately after collection, the groundwater samples were decanted into sample containers provided by
the laboratory. The groundwater samples collected from monitoring wells MW-1 through MW-5 were
analyzed for VOCs by Standard Method 6200B, for SVOCs using USEPA Method 625BNA plus ten
tentatively identified compounds (TICs), for ethylene dibromide (EDB) using EPA Method 504.1, and
for VPH and EPH using the MADEP Methods. The sample containers were labeled with the project
name, sample location, and the date and time the sample was collected. The samples were placed in a
cooler containing ice to maintain the samples at four degrees Celsius and were picked up via courier and
delivered to the Pace Analytical Services, Inc. (Pace) facility located in Huntersville, North Carolina for
chemical analysis. Proper chain-of-custody (COC) procedures were maintained throughout the sample
collection and transportation process. A copy of the COC is included in the Appendix.

3. LABORATORY RESULTS

• Laboratory analysis of the groundwater samples collected from monitoring wells MW-1, MW-2,
MW-3, and MW-5 did not detect targeted compounds above their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-4 detected
MTBE (153 µg/L) at a concentration which exceeds its NC2LGWQS.

A summary of the laboratory results for the groundwater samples is included in Table 1 and Figure 4.

4. CONCLUSIONS

Based on the results of the assessment, Progress concludes the following:

• Progress purged and sampled monitoring wells MW-1 through MW-5.

• Laboratory analysis of the groundwater samples collected from monitoring wells MW-1, MW-2,
MW-3, and MW-5 did not detect targeted compounds above their respective NC2LGWQS.

Former Purgason’s Grocery
Graham, Alamance County, North Carolina
Progress Project No. 151183.004
February 8, 2013

6
• Laboratory analysis of the groundwater sample collected from monitoring well MW-4 detected
MTBE above its NC2LGWQS; however, the concentrations detected during the January 2013
sampling event demonstrate substantial decreases as compared to the results of the July 2011
sampling event. Specifically, the concentration of MTBE detected in the groundwater sample
collected from monitoring well MW-4 during the most recent sampling event (153 µg/L) as
compared to the concentration detected in the groundwater sample collected from monitoring
well MW-4 in July 2011 (2,290 µg/L) represents an approximately 93% decrease. It is the
opinion of Progress that excavation of residual soil contamination within the source area and the
addition of PermeOx Plus® during over-excavation activities completed in 2011 has accelerated
the remediation of the groundwater beneath the site.

• Fifteen water-supply wells were previously identified by others within 1,000 feet of the site and
five water-supply wells were identified within 500 feet of the site.

5. RECOMMENDATIONS

Based on the use of the PermeOx Plus® during over-excavation activities and the remaining
concentrations of MTBE detected in the groundwater sample collected from monitoring well MW-4,
Progress recommends the following:

• Conduct an additional quarterly groundwater monitoring events to document the effectiveness of
the remedial activities on the petroleum-related compounds in the groundwater.

6. QUALIFICATIONS OF REPORT

The activities and evaluative approaches used in this assessment are consistent with those normally
employed in hydrogeologic projects of this type. Our evaluation of site conditions has been based on our
understanding of the site project information and the data obtained during our field activities.

FIGURES

Figure 1
Topographic Site Map

Former Purgason’s Grocery
4956 Highway 54
Graham, North Carolina

Project: Fmr. Purgason’s Groc.
Client: NCDENR
Progress Job #: 151183.004
P.O. Box 5884
Winston-Salem, NC 27113
Telephone: [phone]
Fax: [phone]
www.progressenvironmental.com

United States Department of the Interior
United States Geological Survey
7.5 Minute Series Topographic Map
Contour Interval: 10 feet
Scale: 1”=2000’
Saxapahaw, N.C.
Date: 1977
Date: February 2013

Site
0'100'GRAPHIC SCALE100'200'1" = 100'ProgressENVIRONMENTAL, INC.JTB151183.004JAN 2013JTRSHOWNJAN 2013Figure 2.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 2SITE LOCATION MAPFORMER PURGASON'S GROCERY4956 NC HIGHWAY 54GRAHAM, NORTH CAROLINA%db("MAG-DATE")PROJECTSITE
REV
0
DRAWING TITLE
DRAWING NUMBER
BY DATEREV
DR.: JTR JAN 2013
CK.:
APP'D.:
SCALE: 1" = 15'
PROGRESS NO.: 151183.004
www.progressenvironmental.com %db("MAG-DATE")MW-3
MW-2
MW-1
Highway 54Fmr. 8,000-gal
Gasoline USTs
Fmr. 500-gal
Kerosene UST
& Dispenser
Fmr. 2,000-gal
Diesel UST
0'15'
GRAPHIC SCALE
15' 30'
1" = 15'
MW-5
MW-4
Figure 3
P.O. Box 5884
Winston-Salem, North Carolina 27113
[phone]
Progress
Environmental, Inc.
Site Map
Former Purgason's Grocery
4956 Highway 54
Graham, North Carolina
Fmr. Purgason's Grocery
Active Automotive Repair
FORMER DISPENSERS
*NOTE: Information obtained from Pyramid Environmental &
Engineering Report and Progress Field Notes
MONITORING WELL LOCATION
REV
0
DRAWING TITLE
DRAWING NUMBER
BY DATEREV
DR.: JTR FEB 13
CK.:
APP'D.:
SCALE: 1" = 15'
PROGRESS NO.: 151183.004
www.progressenvironmental.com %db("MAG-DATE")MW-3
MW-2
MW-1
Highway 54Fmr. 8,000-gal
Gasoline USTs
Fmr. 500-gal
Kerosene UST
& Dispenser
Fmr. 2,000-gal
Diesel UST
0'15'
GRAPHIC SCALE
15' 30'
1" = 15'
MW-5
MW-4
Figure 4
P.O. Box 5884
Winston-Salem, North Carolina 27113
[phone]
Progress
Environmental, Inc.
Summary of Detected Analytical Results Map
Former Purgason's Grocery
4956 Highway 54
Graham, North Carolina
Fmr. Purgason's Grocery
Active Automotive Repair
FORMER DISPENSERS
*NOTE: Information obtained from Pyramid Environmental &
Engineering Report and Progress Field Notes
MONITORING WELL LOCATION
MW-4 1/24/13
C5-C8 Aliphatics 89.7 ug/L
Lead 5.1 ug/L
sec-Butylbenzene 0.46J ug/L
Diisopropyl ether 9.5 ug/L
MTBE 153 ug/L
MW-5 1/24/13
Lead 5.2 ug/L
Diethylphthalate 1.0J ug/L
sec-Butylbenzene 0.29J ug/L
MW-1 1/24/13
ND
MW-2 1/24/13
Lead 13.4 ug/L
MW-3 1/24/13
ND

TABLE
3030CWell IDDate Collected (mm/dd/yy)Depth to Water (Ft. Below TOC)07/26/11 11.27 ND ND ND ND ND ND ND NA NA NA NA NA06/01/12 8.05 ND ND ND ND ND ND1.1JNA ND ND ND ND01/24/13 8.61 ND ND ND ND ND ND ND ND ND ND ND ND07/26/11 10.81 ND ND ND ND ND ND ND NA NA NA NA NA06/01/12 7.80 ND ND ND ND ND ND ND NA ND ND ND ND01/24/13 7.90 ND ND ND ND ND ND ND13.4ND ND ND ND07/26/11 8.55 ND ND ND ND ND ND ND NA NA NA NA NA06/01/12 6.38 ND ND ND ND ND ND ND NA ND ND ND ND01/24/13 6.31 ND ND ND ND ND ND ND ND ND ND ND ND07/26/11 9.3124.4 118 2,270ND ND ND ND NA NA NA NA NA06/01/12 6.271.6 20.2 272ND ND ND ND NA234ND ND ND01/24/13 7.30 ND9.5 153ND0.46JND ND5.1 89.7ND ND ND07/26/11 9.24 ND ND1.1 2.6 0.62ND ND NA NA NA NA NA06/01/12 6.79 ND ND ND ND0.95ND ND NA ND ND ND ND01/24/13 7.07 ND ND ND ND0.29J 1.0JND5.2ND ND ND ND0.4 70 20 6 70 6,000 3 15 400 700 200 10,000400 70,000 20,000 15,500 8,500 NS 170 15,000 NS NS NS NS = Values are those that exceed the North Carolina 2L Groundwater Quality Standard = Values are those that exceed the Gross Contamination LevelsND = not detected above laboratory detection standardResults are reported in µg/lµg/L = micrograms per literGCL = gross contamination levelTOC = top of casingNS = No StandardNA = Not AnalyzedAnalytical Method6200BTable 1Summary of Groundwater Analytical Results Active Remediation Monitoring ReportFormer Purgason's GroceryNCDENR Incident No. 19720GCL (µg/l)Contaminant of ConcernDiisopropyl ether (IPE)2L Standard (µg/l)MW-1MW-2MW-3MW-4MW-5sec-Butylbenzene1,2-DichloroethaneEPH & VPHC5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AromaticsC19-C36 AromaticsMethyl-tert-butyl ether (MTBE)NaphthaleneLead625BNA+10Diethylphthalatebis(2-ethylhexyl)phthalate

APPENDIX
:. :
. 1 . .'
':!1,. . .. r:.. .: ', -l,t
GROUNDWATER MONITORING WELL SAMPLING DATA
Total Depth: L|0
t ,(-3 Gals.
YES_ NO X lf YES, Amount
Good Locked?Bolted? Y
Project Name:Purqason's Site
Field Personnel:7tL l7L Weather:c,l^fuur^1
IWell lD: MW- t Well Diameter= 2" SWL from TOC:x .61
Calculations: (1" well = 0.O421gal/ft.) (2" well = .1632 gaUft)(4"well =.6328 gaUft)
Gals.Actual Volume Purged:f.
^t
Dare: (121 .zots
Volume of Water in Well:
Free Product:
Well Condition:
Geochemical Measu rements
Measurement
After Amount
Purqed
pH (s.u.)Temp (C")Conductivity(pmhos/cm)
DO
(ms/L)
Turbidity
Observation*
lnitial 7,7(/'l , I .Lf 7 T
7 a., n-/a.7 7Y4 {
i{G,1t 16.2//f
NT = Not Turbid (clear) ST = Slightly Turbid T = Turbid VT = Very Turbid
zc 5
GROUNDWATER MONITORING WELL SAMPLING DATA
Project Name:Purqason's Site Date:| [t'{2013
Fiefd Personnet: I t I I ft Weather:c- l/ fu,^^.7
Well lD: MW- L Wef l Diam eter: 2" SWL from TOC: 7 .1 0 tohl Depth:3 z. "//
Calcufations: (1" well = 0.O421gallft.)(2" wefl = .1632 gal/ft)(4"well =.6328 gal/ft)
LJVolume of Water in Well: / Gals.Actual Volume Purged:tL Gals.
Free Product:
Well Condition:
YES_ NO
Good
X lf YES, Amount
Locked?Bolted? Y
Geochemical Measurements
Measurement
After Amount
Purqed
pH (S.U.)Temp (G")Gonductivity
$mhos/cm)
DO
(mg/L)
Turbidity
Observation"
lnitial 1-( L t8 l 2f7 7=,f
3 (r.?/t(. 1 276 T
6 aco (7t ;-9VqLf?[7, I aqv ---
l1-b,1 t (? 7 7Fq 1,
* NT = Not Turbid (clear) ST = Slightly Turbid T = Turbid W = Very Turbid
Project Name: Purqason's Site
Fietd Personnet: 1 L I JfL Weather:
nWefl lD: MW- J Well Diameter: 2" SWL from TOC:
Cafculations: (1" well = 0.O421gallft.) (2" well = .1632 gal/ft)
DATA
Date:l/ztl 2013
L" lr( n 9'-u,
Lrotat Depth:3'7. /0
(4"well=.6328 gal/ft)
/{Gals.Volume of Water in Well:Gals.Actual Volume Purged:
Free Product:
Well Gondition:
YES_ NO X lf YES, Amount
Good Locked?Bolted?Y
Geochemical Measurements
Measurement
After Amount
Purqed
pH (S.U.)Temp (C")Conductivity
(pmhos/cm)
DO(ms/L)Turbidity
Observation"
lnitial 7,o7 /(,1 L6Z T
7 (o,T?l-/" L 7.5 1----
,'T(5 119 17/731 l -e/t{
* NT = Not Turbid (clear) ST = Slightly Turbid T = Turbid W = Very Turbid
GROUNDWATER MONITORING WELL SAMPLING DATA
Project Name:Purqason's Site Date: I 1z't .2013
Field Personnel: JL ltw Weather:Co[ol fu^n'
Well lD: Mw- '-l Well Diam eter: 2" SWL from TOC: 1 .?0 total Depth:
Calcufations: (1" well = 0.04219a1/ft.) (2" well = .1632 gal/ft)(4"well= .6328 gal/ft)
Volume of Water in Well:t.?Gals.Actual Volume Purged:
Free Product YES_ NO X lf YES, Amount_
Well Condition: Good Locked?_ Y _Bolted?_ Y
(
,//1t, 5a wQlerl/-tGeochem ical Measurements Qi*d l-.r1
(8
5 ,Z Gals.
1116-yr6lrn6-7^5lsr6
1B:ml!a
1r1 a a4
Measurement
After Amount
Puroed
pH (S.U.)Temp (C")Conductivity
(pmhos/cm)
DO(ms/L)Turbidity
Observation*
Initial hqb nL bat 7-
I 6q f t1 "E 61]T
1 b,1,(.'( , 0 7o1 T
" NT = Not Turbid (clear) ST = Slightly Turbid T = Turbid W = Very Turbid
GROU N DWATER MONITORING
Project Name: Purqason's Site
WELL SAMPLING DATA
Date: t/tLl .2013
Field Personnel:1L l IlL ,t r'
Weather: (,,lc! 'u^*
zo
YES_ NO X lf YES, Amount
Y
-/'
Well fD: MW- -{ Well Diameter: 2" SWLfrom TOC: 1,0- { totat Depth:
Calculations: (1" well = O.O421gal/ft.) (2" well = .1632 gal/ft) (4"well = .6328 gal/ft)
Volume of Water in Well:z. (l Gals.Actual Volume Purged:
Free Product:
Well Gondition:Good Locked? Y Bolted?
(. ?)Gals.
Geochemical Measurements
Measurement
After Amount
Purqed
pH (s.u.)Temp (C')Gonductivity
(pmhos/cm)
DO(ms/L)Turbidity
Observation*
lnitial ?"11 f,,/7rl /7
7'tnl a7t t-r
{7.1-)K,i 1(L f,
* NT = Not Turbid (clear) ST = Slightly Turbid T = Turbid W = Very Turbid
#=CL#
February 05, 2013
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92146051
92146051
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR - UST Section
1637 Mail Service Center
Raleigh, NC 276991637
Purgason's #19720
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on January 25, 2013.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92146051
Purgason's #19720
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92146051
Purgason's #19720
Lab ID Sample ID Matrix Date Collected Date Received
92146051001 MW-1 Water 01/24/13 14:00 01/25/13 15:55
92146051002 MW-2 Water 01/24/13 14:10 01/25/13 15:55
92146051003 MW-3 Water 01/24/13 14:30 01/25/13 15:55
92146051004 MW-4 Water 01/24/13 14:40 01/25/13 15:55
92146051005 MW-5 Water 01/24/13 14:55 01/25/13 15:55
92146051006 TRIP BLANK Water 01/24/13 00:00 01/25/13 15:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92146051
Purgason's #19720
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92146051001 MW-1 EPA 504.1 2 PASI-CRES
MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-ASH1
EPA 625 59 PASI-CBPJ
SM 6200B 67 PASI-CMCK
92146051002 MW-2 EPA 504.1 2 PASI-CRES
MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-ASH1
EPA 625 59 PASI-CBPJ
SM 6200B 67 PASI-CMCK
92146051003 MW-3 EPA 504.1 2 PASI-CRES
MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-ASH1
EPA 625 59 PASI-CBPJ
SM 6200B 67 PASI-CMCK
92146051004 MW-4 EPA 504.1 2 PASI-CRES
MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-ASH1
EPA 625 59 PASI-CBPJ
SM 6200B 67 PASI-CMCK
92146051005 MW-5 EPA 504.1 2 PASI-CRES
MADEP EPH 7 PASI-CMEJ
MADEP VPH 5 PASI-CRGF
EPA 200.7 1 PASI-ASH1
EPA 625 59 PASI-CBPJ
SM 6200B 67 PASI-CMCK
92146051006 TRIP BLANK SM 6200B 67 PASI-CMCK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=HO#
HITS ONLY
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92146051002 MW-2
Lead 13.4 ug/L 01/29/13 23:105.0EPA 200.7
92146051004 MW-4
Aliphatic (C05-C08)89.7 ug/L 02/01/13 03:06 N250.0MADEP VPH
Lead 5.1 ug/L 01/29/13 23:205.0EPA 200.7
sec-Butylbenzene 0.46J ug/L 02/03/13 17:020.50SM 6200B
Diisopropyl ether 9.5 ug/L 02/03/13 17:020.50SM 6200B
Methyl-tert-butyl ether 153 ug/L 02/03/13 17:020.50SM 6200B
92146051005 MW-5
Lead 5.2 ug/L 01/29/13 23:385.0EPA 200.7
Diethylphthalate 1.0J ug/L 01/31/13 10:305.0EPA 625
sec-Butylbenzene 0.29J ug/L 02/01/13 06:250.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-1 Lab ID:92146051001 Collected:01/24/13 14:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 01/30/13 23:26 106-93-401/30/13 17:210.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)107 %1 01/30/13 23:26 301-79-5601/30/13 17:2170-130
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 02/03/13 13:42 N201/30/13 14:00111111
Aliphatic (C19-C36)ND ug/L 1 02/03/13 13:42 N201/30/13 14:00111111
Aromatic (C11-C22)ND ug/L 1 02/03/13 13:42 N201/30/13 14:00111111
Surrogates
Nonatriacontane (S)77 %1 02/03/13 13:42 7194-86-701/30/13 14:0040-140
o-Terphenyl (S)61 %1 02/03/13 13:42 84-15-101/30/13 14:0040-140
2-Fluorobiphenyl (S)88 %1 02/03/13 13:42 321-60-801/30/13 14:0040-140
2-Bromonaphthalene (S)95 %1 02/03/13 13:42 580-13-201/30/13 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 02/01/13 01:57 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 02/01/13 01:57 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 02/01/13 01:57 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)108 %1 02/01/13 01:57 460-00-470-130
4-Bromofluorobenzene (PID) (S)74 %1 02/01/13 01:57 460-00-470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 01/29/13 23:07 7439-92-101/26/13 10:155.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/30/13 08:23 83-32-901/28/13 15:005.0 0.25
Acenaphthylene ND ug/L 1 01/30/13 08:23 208-96-801/28/13 15:005.0 0.21
Anthracene ND ug/L 1 01/30/13 08:23 120-12-701/28/13 15:005.0 0.14
Benzo(a)anthracene ND ug/L 1 01/30/13 08:23 56-55-301/28/13 15:005.0 0.33
Benzo(a)pyrene ND ug/L 1 01/30/13 08:23 50-32-801/28/13 15:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 01/30/13 08:23 205-99-201/28/13 15:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 01/30/13 08:23 191-24-201/28/13 15:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 01/30/13 08:23 207-08-901/28/13 15:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 01/30/13 08:23 101-55-301/28/13 15:005.0 0.82
Butylbenzylphthalate ND ug/L 1 01/30/13 08:23 85-68-701/28/13 15:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 01/30/13 08:23 59-50-701/28/13 15:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 01/30/13 08:23 111-91-101/28/13 15:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 01/30/13 08:23 111-44-401/28/13 15:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/30/13 08:23 108-60-101/28/13 15:005.0 0.95
2-Chloronaphthalene ND ug/L 1 01/30/13 08:23 91-58-701/28/13 15:005.0 0.98
2-Chlorophenol ND ug/L 1 01/30/13 08:23 95-57-801/28/13 15:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 01/30/13 08:23 7005-72-301/28/13 15:005.0 0.87
Chrysene ND ug/L 1 01/30/13 08:23 218-01-901/28/13 15:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 01/30/13 08:23 53-70-301/28/13 15:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 01/30/13 08:23 91-94-101/28/13 15:0025.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 6 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-1 Lab ID:92146051001 Collected:01/24/13 14:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol ND ug/L 1 01/30/13 08:23 120-83-201/28/13 15:005.0 1.7
Diethylphthalate ND ug/L 1 01/30/13 08:23 84-66-201/28/13 15:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 01/30/13 08:23 105-67-901/28/13 15:0010.0 1.2
Dimethylphthalate ND ug/L 1 01/30/13 08:23 131-11-301/28/13 15:005.0 0.76
Di-n-butylphthalate ND ug/L 1 01/30/13 08:23 84-74-201/28/13 15:005.0 0.75
4,6-Dinitro-2-methylphenol ND ug/L 1 01/30/13 08:23 534-52-101/28/13 15:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 01/30/13 08:23 51-28-501/28/13 15:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 01/30/13 08:23 121-14-201/28/13 15:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 01/30/13 08:23 606-20-201/28/13 15:005.0 0.98
Di-n-octylphthalate ND ug/L 1 01/30/13 08:23 117-84-001/28/13 15:005.0 0.66
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/30/13 08:23 117-81-701/28/13 15:005.0 0.79
Fluoranthene ND ug/L 1 01/30/13 08:23 206-44-001/28/13 15:005.0 0.21
Fluorene ND ug/L 1 01/30/13 08:23 86-73-701/28/13 15:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 01/30/13 08:23 87-68-301/28/13 15:005.0 0.94
Hexachlorobenzene ND ug/L 1 01/30/13 08:23 118-74-101/28/13 15:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 01/30/13 08:23 77-47-401/28/13 15:0010.0 0.88
Hexachloroethane ND ug/L 1 01/30/13 08:23 67-72-101/28/13 15:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/30/13 08:23 193-39-501/28/13 15:005.0 0.29
Isophorone ND ug/L 1 01/30/13 08:23 78-59-101/28/13 15:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 01/30/13 08:23 91-57-601/28/13 15:005.0 0.28
Naphthalene ND ug/L 1 01/30/13 08:23 91-20-301/28/13 15:005.0 0.34
Nitrobenzene ND ug/L 1 01/30/13 08:23 98-95-301/28/13 15:005.0 1.1
2-Nitrophenol ND ug/L 1 01/30/13 08:23 88-75-501/28/13 15:005.0 0.91
4-Nitrophenol ND ug/L 1 01/30/13 08:23 100-02-701/28/13 15:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 01/30/13 08:23 62-75-901/28/13 15:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 01/30/13 08:23 621-64-701/28/13 15:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 01/30/13 08:23 86-30-601/28/13 15:0010.0 1.0
Pentachlorophenol ND ug/L 1 01/30/13 08:23 87-86-501/28/13 15:0025.0 4.6
Phenanthrene ND ug/L 1 01/30/13 08:23 85-01-801/28/13 15:005.0 0.22
Phenol ND ug/L 1 01/30/13 08:23 108-95-201/28/13 15:005.0 1.9
Pyrene ND ug/L 1 01/30/13 08:23 129-00-001/28/13 15:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 01/30/13 08:23 120-82-101/28/13 15:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 01/30/13 08:23 88-06-201/28/13 15:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)24 %1 01/30/13 08:23 4165-60-001/28/13 15:0010-120
2-Fluorobiphenyl (S)24 %1 01/30/13 08:23 321-60-801/28/13 15:0015-120
Terphenyl-d14 (S)36 %1 01/30/13 08:23 1718-51-001/28/13 15:0011-131
Phenol-d6 (S)7 %1 01/30/13 08:23 13127-88-3 S001/28/13 15:0010-120
2-Fluorophenol (S)13 %1 01/30/13 08:23 367-12-401/28/13 15:0010-120
2,4,6-Tribromophenol (S)28 %1 01/30/13 08:23 118-79-601/28/13 15:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/01/13 02:38 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/01/13 02:38 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/01/13 02:38 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/01/13 02:38 75-27-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 7 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-1 Lab ID:92146051001 Collected:01/24/13 14:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Bromoform ND ug/L 1 02/01/13 02:38 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/01/13 02:38 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/01/13 02:38 104-51-80.50 0.25
sec-Butylbenzene ND ug/L 1 02/01/13 02:38 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/01/13 02:38 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/01/13 02:38 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/01/13 02:38 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/01/13 02:38 75-00-31.0 0.50
Chloroform ND ug/L 1 02/01/13 02:38 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/01/13 02:38 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/01/13 02:38 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/01/13 02:38 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/01/13 02:38 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/01/13 02:38 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/01/13 02:38 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/01/13 02:38 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/01/13 02:38 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/01/13 02:38 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/01/13 02:38 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/01/13 02:38 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/01/13 02:38 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/01/13 02:38 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/01/13 02:38 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/01/13 02:38 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/01/13 02:38 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/01/13 02:38 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/01/13 02:38 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/01/13 02:38 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/01/13 02:38 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/01/13 02:38 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/01/13 02:38 10061-02-60.50 0.25
Diisopropyl ether ND ug/L 1 02/01/13 02:38 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/01/13 02:38 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/01/13 02:38 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/01/13 02:38 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/01/13 02:38 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/01/13 02:38 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/01/13 02:38 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/01/13 02:38 108-10-15.0 5.0
Methyl-tert-butyl ether ND ug/L 1 02/01/13 02:38 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/01/13 02:38 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/01/13 02:38 103-65-10.50 0.25
Styrene ND ug/L 1 02/01/13 02:38 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/01/13 02:38 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/01/13 02:38 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/01/13 02:38 127-18-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 8 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-1 Lab ID:92146051001 Collected:01/24/13 14:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 1 02/01/13 02:38 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/01/13 02:38 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/01/13 02:38 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/01/13 02:38 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/01/13 02:38 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/01/13 02:38 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/01/13 02:38 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/01/13 02:38 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/01/13 02:38 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/01/13 02:38 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/01/13 02:38 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/01/13 02:38 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/01/13 02:38 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)124 %1 02/01/13 02:38 17060-07-070-130
Dibromofluoromethane (S)106 %1 02/01/13 02:38 1868-53-770-130
4-Bromofluorobenzene (S)92 %1 02/01/13 02:38 460-00-470-130
Toluene-d8 (S)101 %1 02/01/13 02:38 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 9 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-2 Lab ID:92146051002 Collected:01/24/13 14:10 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 01/30/13 23:46 106-93-401/30/13 17:210.021 0.021
Surrogates
1-Chloro-2-bromopropane (S)107 %1 01/30/13 23:46 301-79-5601/30/13 17:2170-130
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 02/03/13 14:15 N201/30/13 14:00110110
Aliphatic (C19-C36)ND ug/L 1 02/03/13 14:15 N201/30/13 14:00110110
Aromatic (C11-C22)ND ug/L 1 02/03/13 14:15 N201/30/13 14:00110110
Surrogates
Nonatriacontane (S)69 %1 02/03/13 14:15 7194-86-701/30/13 14:0040-140
o-Terphenyl (S)67 %1 02/03/13 14:15 84-15-101/30/13 14:0040-140
2-Fluorobiphenyl (S)92 %1 02/03/13 14:15 321-60-801/30/13 14:0040-140
2-Bromonaphthalene (S)101 %1 02/03/13 14:15 580-13-201/30/13 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 02/01/13 02:20 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 02/01/13 02:20 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 02/01/13 02:20 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)111 %1 02/01/13 02:20 460-00-470-130
4-Bromofluorobenzene (PID) (S)76 %1 02/01/13 02:20 460-00-470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 13.4 ug/L 1 01/29/13 23:10 7439-92-101/26/13 10:155.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/30/13 08:50 83-32-901/28/13 15:005.0 0.25
Acenaphthylene ND ug/L 1 01/30/13 08:50 208-96-801/28/13 15:005.0 0.21
Anthracene ND ug/L 1 01/30/13 08:50 120-12-701/28/13 15:005.0 0.14
Benzo(a)anthracene ND ug/L 1 01/30/13 08:50 56-55-301/28/13 15:005.0 0.33
Benzo(a)pyrene ND ug/L 1 01/30/13 08:50 50-32-801/28/13 15:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 01/30/13 08:50 205-99-201/28/13 15:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 01/30/13 08:50 191-24-201/28/13 15:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 01/30/13 08:50 207-08-901/28/13 15:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 01/30/13 08:50 101-55-301/28/13 15:005.0 0.82
Butylbenzylphthalate ND ug/L 1 01/30/13 08:50 85-68-701/28/13 15:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 01/30/13 08:50 59-50-701/28/13 15:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 01/30/13 08:50 111-91-101/28/13 15:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 01/30/13 08:50 111-44-401/28/13 15:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/30/13 08:50 108-60-101/28/13 15:005.0 0.95
2-Chloronaphthalene ND ug/L 1 01/30/13 08:50 91-58-701/28/13 15:005.0 0.98
2-Chlorophenol ND ug/L 1 01/30/13 08:50 95-57-801/28/13 15:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 01/30/13 08:50 7005-72-301/28/13 15:005.0 0.87
Chrysene ND ug/L 1 01/30/13 08:50 218-01-901/28/13 15:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 01/30/13 08:50 53-70-301/28/13 15:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 01/30/13 08:50 91-94-101/28/13 15:0025.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 10 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-2 Lab ID:92146051002 Collected:01/24/13 14:10 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol ND ug/L 1 01/30/13 08:50 120-83-201/28/13 15:005.0 1.7
Diethylphthalate ND ug/L 1 01/30/13 08:50 84-66-201/28/13 15:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 01/30/13 08:50 105-67-901/28/13 15:0010.0 1.2
Dimethylphthalate ND ug/L 1 01/30/13 08:50 131-11-301/28/13 15:005.0 0.76
Di-n-butylphthalate ND ug/L 1 01/30/13 08:50 84-74-201/28/13 15:005.0 0.75
4,6-Dinitro-2-methylphenol ND ug/L 1 01/30/13 08:50 534-52-101/28/13 15:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 01/30/13 08:50 51-28-501/28/13 15:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 01/30/13 08:50 121-14-201/28/13 15:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 01/30/13 08:50 606-20-201/28/13 15:005.0 0.98
Di-n-octylphthalate ND ug/L 1 01/30/13 08:50 117-84-001/28/13 15:005.0 0.66
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/30/13 08:50 117-81-701/28/13 15:005.0 0.79
Fluoranthene ND ug/L 1 01/30/13 08:50 206-44-001/28/13 15:005.0 0.21
Fluorene ND ug/L 1 01/30/13 08:50 86-73-701/28/13 15:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 01/30/13 08:50 87-68-301/28/13 15:005.0 0.94
Hexachlorobenzene ND ug/L 1 01/30/13 08:50 118-74-101/28/13 15:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 01/30/13 08:50 77-47-401/28/13 15:0010.0 0.88
Hexachloroethane ND ug/L 1 01/30/13 08:50 67-72-101/28/13 15:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/30/13 08:50 193-39-501/28/13 15:005.0 0.29
Isophorone ND ug/L 1 01/30/13 08:50 78-59-101/28/13 15:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 01/30/13 08:50 91-57-601/28/13 15:005.0 0.28
Naphthalene ND ug/L 1 01/30/13 08:50 91-20-301/28/13 15:005.0 0.34
Nitrobenzene ND ug/L 1 01/30/13 08:50 98-95-301/28/13 15:005.0 1.1
2-Nitrophenol ND ug/L 1 01/30/13 08:50 88-75-501/28/13 15:005.0 0.91
4-Nitrophenol ND ug/L 1 01/30/13 08:50 100-02-701/28/13 15:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 01/30/13 08:50 62-75-901/28/13 15:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 01/30/13 08:50 621-64-701/28/13 15:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 01/30/13 08:50 86-30-601/28/13 15:0010.0 1.0
Pentachlorophenol ND ug/L 1 01/30/13 08:50 87-86-501/28/13 15:0025.0 4.6
Phenanthrene ND ug/L 1 01/30/13 08:50 85-01-801/28/13 15:005.0 0.22
Phenol ND ug/L 1 01/30/13 08:50 108-95-201/28/13 15:005.0 1.9
Pyrene ND ug/L 1 01/30/13 08:50 129-00-001/28/13 15:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 01/30/13 08:50 120-82-101/28/13 15:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 01/30/13 08:50 88-06-201/28/13 15:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)32 %1 01/30/13 08:50 4165-60-001/28/13 15:0010-120
2-Fluorobiphenyl (S)33 %1 01/30/13 08:50 321-60-801/28/13 15:0015-120
Terphenyl-d14 (S)36 %1 01/30/13 08:50 1718-51-001/28/13 15:0011-131
Phenol-d6 (S)10 %1 01/30/13 08:50 13127-88-301/28/13 15:0010-120
2-Fluorophenol (S)17 %1 01/30/13 08:50 367-12-401/28/13 15:0010-120
2,4,6-Tribromophenol (S)34 %1 01/30/13 08:50 118-79-601/28/13 15:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/01/13 02:54 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/01/13 02:54 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/01/13 02:54 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/01/13 02:54 75-27-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 11 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-2 Lab ID:92146051002 Collected:01/24/13 14:10 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Bromoform ND ug/L 1 02/01/13 02:54 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/01/13 02:54 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/01/13 02:54 104-51-80.50 0.25
sec-Butylbenzene ND ug/L 1 02/01/13 02:54 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/01/13 02:54 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/01/13 02:54 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/01/13 02:54 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/01/13 02:54 75-00-31.0 0.50
Chloroform ND ug/L 1 02/01/13 02:54 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/01/13 02:54 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/01/13 02:54 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/01/13 02:54 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/01/13 02:54 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/01/13 02:54 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/01/13 02:54 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/01/13 02:54 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/01/13 02:54 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/01/13 02:54 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/01/13 02:54 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/01/13 02:54 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/01/13 02:54 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/01/13 02:54 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/01/13 02:54 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/01/13 02:54 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/01/13 02:54 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/01/13 02:54 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/01/13 02:54 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/01/13 02:54 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/01/13 02:54 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/01/13 02:54 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/01/13 02:54 10061-02-60.50 0.25
Diisopropyl ether ND ug/L 1 02/01/13 02:54 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/01/13 02:54 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/01/13 02:54 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/01/13 02:54 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/01/13 02:54 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/01/13 02:54 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/01/13 02:54 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/01/13 02:54 108-10-15.0 5.0
Methyl-tert-butyl ether ND ug/L 1 02/01/13 02:54 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/01/13 02:54 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/01/13 02:54 103-65-10.50 0.25
Styrene ND ug/L 1 02/01/13 02:54 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/01/13 02:54 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/01/13 02:54 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/01/13 02:54 127-18-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 12 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-2 Lab ID:92146051002 Collected:01/24/13 14:10 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 1 02/01/13 02:54 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/01/13 02:54 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/01/13 02:54 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/01/13 02:54 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/01/13 02:54 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/01/13 02:54 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/01/13 02:54 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/01/13 02:54 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/01/13 02:54 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/01/13 02:54 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/01/13 02:54 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/01/13 02:54 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/01/13 02:54 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)124 %1 02/01/13 02:54 17060-07-070-130
Dibromofluoromethane (S)103 %1 02/01/13 02:54 1868-53-770-130
4-Bromofluorobenzene (S)92 %1 02/01/13 02:54 460-00-470-130
Toluene-d8 (S)101 %1 02/01/13 02:54 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 13 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-3 Lab ID:92146051003 Collected:01/24/13 14:30 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 01/31/13 00:07 106-93-401/30/13 17:210.021 0.021
Surrogates
1-Chloro-2-bromopropane (S)109 %1 01/31/13 00:07 301-79-5601/30/13 17:2170-130
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 02/03/13 14:47 N201/30/13 14:00111111
Aliphatic (C19-C36)ND ug/L 1 02/03/13 14:47 N201/30/13 14:00111111
Aromatic (C11-C22)ND ug/L 1 02/03/13 14:47 N201/30/13 14:00111111
Surrogates
Nonatriacontane (S)84 %1 02/03/13 14:47 7194-86-701/30/13 14:0040-140
o-Terphenyl (S)77 %1 02/03/13 14:47 84-15-101/30/13 14:0040-140
2-Fluorobiphenyl (S)107 %1 02/03/13 14:47 321-60-801/30/13 14:0040-140
2-Bromonaphthalene (S)112 %1 02/03/13 14:47 580-13-201/30/13 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 02/01/13 02:43 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 02/01/13 02:43 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 02/01/13 02:43 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)106 %1 02/01/13 02:43 460-00-470-130
4-Bromofluorobenzene (PID) (S)71 %1 02/01/13 02:43 460-00-470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 01/29/13 23:13 7439-92-101/26/13 10:155.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/31/13 09:36 83-32-901/28/13 15:005.0 0.25
Acenaphthylene ND ug/L 1 01/31/13 09:36 208-96-801/28/13 15:005.0 0.21
Anthracene ND ug/L 1 01/31/13 09:36 120-12-701/28/13 15:005.0 0.14
Benzo(a)anthracene ND ug/L 1 01/31/13 09:36 56-55-301/28/13 15:005.0 0.33
Benzo(a)pyrene ND ug/L 1 01/31/13 09:36 50-32-801/28/13 15:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 01/31/13 09:36 205-99-201/28/13 15:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 01/31/13 09:36 191-24-201/28/13 15:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 01/31/13 09:36 207-08-901/28/13 15:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 01/31/13 09:36 101-55-301/28/13 15:005.0 0.82
Butylbenzylphthalate ND ug/L 1 01/31/13 09:36 85-68-701/28/13 15:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 01/31/13 09:36 59-50-701/28/13 15:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 01/31/13 09:36 111-91-101/28/13 15:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 01/31/13 09:36 111-44-401/28/13 15:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/31/13 09:36 108-60-101/28/13 15:005.0 0.95
2-Chloronaphthalene ND ug/L 1 01/31/13 09:36 91-58-701/28/13 15:005.0 0.98
2-Chlorophenol ND ug/L 1 01/31/13 09:36 95-57-801/28/13 15:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 01/31/13 09:36 7005-72-301/28/13 15:005.0 0.87
Chrysene ND ug/L 1 01/31/13 09:36 218-01-901/28/13 15:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 01/31/13 09:36 53-70-301/28/13 15:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 01/31/13 09:36 91-94-101/28/13 15:0025.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 14 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-3 Lab ID:92146051003 Collected:01/24/13 14:30 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol ND ug/L 1 01/31/13 09:36 120-83-201/28/13 15:005.0 1.7
Diethylphthalate ND ug/L 1 01/31/13 09:36 84-66-201/28/13 15:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 01/31/13 09:36 105-67-901/28/13 15:0010.0 1.2
Dimethylphthalate ND ug/L 1 01/31/13 09:36 131-11-301/28/13 15:005.0 0.76
Di-n-butylphthalate ND ug/L 1 01/31/13 09:36 84-74-201/28/13 15:005.0 0.75
4,6-Dinitro-2-methylphenol ND ug/L 1 01/31/13 09:36 534-52-101/28/13 15:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 01/31/13 09:36 51-28-501/28/13 15:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 01/31/13 09:36 121-14-201/28/13 15:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 01/31/13 09:36 606-20-201/28/13 15:005.0 0.98
Di-n-octylphthalate ND ug/L 1 01/31/13 09:36 117-84-001/28/13 15:005.0 0.66
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/31/13 09:36 117-81-701/28/13 15:005.0 0.79
Fluoranthene ND ug/L 1 01/31/13 09:36 206-44-001/28/13 15:005.0 0.21
Fluorene ND ug/L 1 01/31/13 09:36 86-73-701/28/13 15:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 01/31/13 09:36 87-68-301/28/13 15:005.0 0.94
Hexachlorobenzene ND ug/L 1 01/31/13 09:36 118-74-101/28/13 15:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 01/31/13 09:36 77-47-401/28/13 15:0010.0 0.88
Hexachloroethane ND ug/L 1 01/31/13 09:36 67-72-101/28/13 15:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/31/13 09:36 193-39-501/28/13 15:005.0 0.29
Isophorone ND ug/L 1 01/31/13 09:36 78-59-101/28/13 15:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 01/31/13 09:36 91-57-601/28/13 15:005.0 0.28
Naphthalene ND ug/L 1 01/31/13 09:36 91-20-301/28/13 15:005.0 0.34
Nitrobenzene ND ug/L 1 01/31/13 09:36 98-95-301/28/13 15:005.0 1.1
2-Nitrophenol ND ug/L 1 01/31/13 09:36 88-75-501/28/13 15:005.0 0.91
4-Nitrophenol ND ug/L 1 01/31/13 09:36 100-02-701/28/13 15:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 01/31/13 09:36 62-75-901/28/13 15:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 01/31/13 09:36 621-64-701/28/13 15:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 01/31/13 09:36 86-30-601/28/13 15:0010.0 1.0
Pentachlorophenol ND ug/L 1 01/31/13 09:36 87-86-501/28/13 15:0025.0 4.6
Phenanthrene ND ug/L 1 01/31/13 09:36 85-01-801/28/13 15:005.0 0.22
Phenol ND ug/L 1 01/31/13 09:36 108-95-201/28/13 15:005.0 1.9
Pyrene ND ug/L 1 01/31/13 09:36 129-00-001/28/13 15:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 01/31/13 09:36 120-82-101/28/13 15:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 01/31/13 09:36 88-06-201/28/13 15:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)30 %1 01/31/13 09:36 4165-60-001/28/13 15:0010-120
2-Fluorobiphenyl (S)31 %1 01/31/13 09:36 321-60-801/28/13 15:0015-120
Terphenyl-d14 (S)37 %1 01/31/13 09:36 1718-51-001/28/13 15:0011-131
Phenol-d6 (S)9 %1 01/31/13 09:36 13127-88-3 S001/28/13 15:0010-120
2-Fluorophenol (S)17 %1 01/31/13 09:36 367-12-401/28/13 15:0010-120
2,4,6-Tribromophenol (S)31 %1 01/31/13 09:36 118-79-601/28/13 15:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/03/13 16:46 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/03/13 16:46 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/03/13 16:46 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/03/13 16:46 75-27-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 15 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-3 Lab ID:92146051003 Collected:01/24/13 14:30 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Bromoform ND ug/L 1 02/03/13 16:46 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/03/13 16:46 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/03/13 16:46 104-51-80.50 0.25
sec-Butylbenzene ND ug/L 1 02/03/13 16:46 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/03/13 16:46 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/03/13 16:46 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/03/13 16:46 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/03/13 16:46 75-00-31.0 0.50
Chloroform ND ug/L 1 02/03/13 16:46 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/03/13 16:46 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/03/13 16:46 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/03/13 16:46 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/03/13 16:46 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/03/13 16:46 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/03/13 16:46 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/03/13 16:46 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/03/13 16:46 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/03/13 16:46 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/03/13 16:46 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/03/13 16:46 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/03/13 16:46 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/03/13 16:46 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/03/13 16:46 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/03/13 16:46 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/03/13 16:46 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/03/13 16:46 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/03/13 16:46 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/03/13 16:46 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/03/13 16:46 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/03/13 16:46 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/03/13 16:46 10061-02-60.50 0.25
Diisopropyl ether ND ug/L 1 02/03/13 16:46 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/03/13 16:46 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/03/13 16:46 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/03/13 16:46 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/03/13 16:46 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/03/13 16:46 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/03/13 16:46 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/03/13 16:46 108-10-15.0 5.0
Methyl-tert-butyl ether ND ug/L 1 02/03/13 16:46 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/03/13 16:46 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/03/13 16:46 103-65-10.50 0.25
Styrene ND ug/L 1 02/03/13 16:46 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/03/13 16:46 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/03/13 16:46 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/03/13 16:46 127-18-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 16 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-3 Lab ID:92146051003 Collected:01/24/13 14:30 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 1 02/03/13 16:46 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/03/13 16:46 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/03/13 16:46 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/03/13 16:46 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/03/13 16:46 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/03/13 16:46 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/03/13 16:46 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/03/13 16:46 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/03/13 16:46 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/03/13 16:46 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/03/13 16:46 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/03/13 16:46 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/03/13 16:46 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)108 %1 02/03/13 16:46 17060-07-070-130
Dibromofluoromethane (S)108 %1 02/03/13 16:46 1868-53-770-130
4-Bromofluorobenzene (S)99 %1 02/03/13 16:46 460-00-470-130
Toluene-d8 (S)100 %1 02/03/13 16:46 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 17 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-4 Lab ID:92146051004 Collected:01/24/13 14:40 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 01/31/13 00:27 106-93-401/30/13 17:210.021 0.021
Surrogates
1-Chloro-2-bromopropane (S)107 %1 01/31/13 00:27 301-79-5601/30/13 17:2170-130
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 02/03/13 15:20 N201/30/13 14:00112112
Aliphatic (C19-C36)ND ug/L 1 02/03/13 15:20 N201/30/13 14:00112112
Aromatic (C11-C22)ND ug/L 1 02/03/13 15:20 N201/30/13 14:00112112
Surrogates
Nonatriacontane (S)63 %1 02/03/13 15:20 7194-86-701/30/13 14:0040-140
o-Terphenyl (S)66 %1 02/03/13 15:20 84-15-101/30/13 14:0040-140
2-Fluorobiphenyl (S)91 %1 02/03/13 15:20 321-60-801/30/13 14:0040-140
2-Bromonaphthalene (S)102 %1 02/03/13 15:20 580-13-201/30/13 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)89.7 ug/L 1 02/01/13 03:06 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 02/01/13 03:06 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 02/01/13 03:06 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)94 %1 02/01/13 03:06 460-00-470-130
4-Bromofluorobenzene (PID) (S)66 %1 02/01/13 03:06 460-00-4 S070-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 5.1 ug/L 1 01/29/13 23:20 7439-92-101/26/13 10:155.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/31/13 10:03 83-32-901/28/13 15:005.0 0.25
Acenaphthylene ND ug/L 1 01/31/13 10:03 208-96-801/28/13 15:005.0 0.21
Anthracene ND ug/L 1 01/31/13 10:03 120-12-701/28/13 15:005.0 0.14
Benzo(a)anthracene ND ug/L 1 01/31/13 10:03 56-55-301/28/13 15:005.0 0.33
Benzo(a)pyrene ND ug/L 1 01/31/13 10:03 50-32-801/28/13 15:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 01/31/13 10:03 205-99-201/28/13 15:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 01/31/13 10:03 191-24-201/28/13 15:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 01/31/13 10:03 207-08-901/28/13 15:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 01/31/13 10:03 101-55-301/28/13 15:005.0 0.82
Butylbenzylphthalate ND ug/L 1 01/31/13 10:03 85-68-701/28/13 15:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 01/31/13 10:03 59-50-701/28/13 15:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 01/31/13 10:03 111-91-101/28/13 15:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 01/31/13 10:03 111-44-401/28/13 15:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/31/13 10:03 108-60-101/28/13 15:005.0 0.95
2-Chloronaphthalene ND ug/L 1 01/31/13 10:03 91-58-701/28/13 15:005.0 0.98
2-Chlorophenol ND ug/L 1 01/31/13 10:03 95-57-801/28/13 15:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 01/31/13 10:03 7005-72-301/28/13 15:005.0 0.87
Chrysene ND ug/L 1 01/31/13 10:03 218-01-901/28/13 15:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 01/31/13 10:03 53-70-301/28/13 15:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 01/31/13 10:03 91-94-101/28/13 15:0025.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 18 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-4 Lab ID:92146051004 Collected:01/24/13 14:40 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol ND ug/L 1 01/31/13 10:03 120-83-201/28/13 15:005.0 1.7
Diethylphthalate ND ug/L 1 01/31/13 10:03 84-66-201/28/13 15:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 01/31/13 10:03 105-67-901/28/13 15:0010.0 1.2
Dimethylphthalate ND ug/L 1 01/31/13 10:03 131-11-301/28/13 15:005.0 0.76
Di-n-butylphthalate ND ug/L 1 01/31/13 10:03 84-74-201/28/13 15:005.0 0.75
4,6-Dinitro-2-methylphenol ND ug/L 1 01/31/13 10:03 534-52-101/28/13 15:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 01/31/13 10:03 51-28-501/28/13 15:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 01/31/13 10:03 121-14-201/28/13 15:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 01/31/13 10:03 606-20-201/28/13 15:005.0 0.98
Di-n-octylphthalate ND ug/L 1 01/31/13 10:03 117-84-001/28/13 15:005.0 0.66
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/31/13 10:03 117-81-701/28/13 15:005.0 0.79
Fluoranthene ND ug/L 1 01/31/13 10:03 206-44-001/28/13 15:005.0 0.21
Fluorene ND ug/L 1 01/31/13 10:03 86-73-701/28/13 15:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 01/31/13 10:03 87-68-301/28/13 15:005.0 0.94
Hexachlorobenzene ND ug/L 1 01/31/13 10:03 118-74-101/28/13 15:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 01/31/13 10:03 77-47-401/28/13 15:0010.0 0.88
Hexachloroethane ND ug/L 1 01/31/13 10:03 67-72-101/28/13 15:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/31/13 10:03 193-39-501/28/13 15:005.0 0.29
Isophorone ND ug/L 1 01/31/13 10:03 78-59-101/28/13 15:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 01/31/13 10:03 91-57-601/28/13 15:005.0 0.28
Naphthalene ND ug/L 1 01/31/13 10:03 91-20-301/28/13 15:005.0 0.34
Nitrobenzene ND ug/L 1 01/31/13 10:03 98-95-301/28/13 15:005.0 1.1
2-Nitrophenol ND ug/L 1 01/31/13 10:03 88-75-501/28/13 15:005.0 0.91
4-Nitrophenol ND ug/L 1 01/31/13 10:03 100-02-701/28/13 15:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 01/31/13 10:03 62-75-901/28/13 15:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 01/31/13 10:03 621-64-701/28/13 15:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 01/31/13 10:03 86-30-601/28/13 15:0010.0 1.0
Pentachlorophenol ND ug/L 1 01/31/13 10:03 87-86-501/28/13 15:0025.0 4.6
Phenanthrene ND ug/L 1 01/31/13 10:03 85-01-801/28/13 15:005.0 0.22
Phenol ND ug/L 1 01/31/13 10:03 108-95-201/28/13 15:005.0 1.9
Pyrene ND ug/L 1 01/31/13 10:03 129-00-001/28/13 15:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 01/31/13 10:03 120-82-101/28/13 15:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 01/31/13 10:03 88-06-201/28/13 15:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)37 %1 01/31/13 10:03 4165-60-001/28/13 15:0010-120
2-Fluorobiphenyl (S)37 %1 01/31/13 10:03 321-60-801/28/13 15:0015-120
Terphenyl-d14 (S)36 %1 01/31/13 10:03 1718-51-001/28/13 15:0011-131
Phenol-d6 (S)10 %1 01/31/13 10:03 13127-88-301/28/13 15:0010-120
2-Fluorophenol (S)19 %1 01/31/13 10:03 367-12-401/28/13 15:0010-120
2,4,6-Tribromophenol (S)39 %1 01/31/13 10:03 118-79-601/28/13 15:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/03/13 17:02 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/03/13 17:02 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/03/13 17:02 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/03/13 17:02 75-27-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 19 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-4 Lab ID:92146051004 Collected:01/24/13 14:40 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Bromoform ND ug/L 1 02/03/13 17:02 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/03/13 17:02 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/03/13 17:02 104-51-80.50 0.25
sec-Butylbenzene 0.46J ug/L 1 02/03/13 17:02 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/03/13 17:02 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/03/13 17:02 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/03/13 17:02 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/03/13 17:02 75-00-31.0 0.50
Chloroform ND ug/L 1 02/03/13 17:02 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/03/13 17:02 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/03/13 17:02 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/03/13 17:02 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/03/13 17:02 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/03/13 17:02 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/03/13 17:02 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/03/13 17:02 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/03/13 17:02 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/03/13 17:02 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/03/13 17:02 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/03/13 17:02 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/03/13 17:02 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/03/13 17:02 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/03/13 17:02 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/03/13 17:02 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/03/13 17:02 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/03/13 17:02 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/03/13 17:02 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/03/13 17:02 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/03/13 17:02 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/03/13 17:02 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/03/13 17:02 10061-02-60.50 0.25
Diisopropyl ether 9.5 ug/L 1 02/03/13 17:02 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/03/13 17:02 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/03/13 17:02 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/03/13 17:02 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/03/13 17:02 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/03/13 17:02 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/03/13 17:02 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/03/13 17:02 108-10-15.0 5.0
Methyl-tert-butyl ether 153 ug/L 1 02/03/13 17:02 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/03/13 17:02 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/03/13 17:02 103-65-10.50 0.25
Styrene ND ug/L 1 02/03/13 17:02 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/03/13 17:02 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/03/13 17:02 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/03/13 17:02 127-18-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 20 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-4 Lab ID:92146051004 Collected:01/24/13 14:40 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 1 02/03/13 17:02 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/03/13 17:02 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/03/13 17:02 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/03/13 17:02 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/03/13 17:02 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/03/13 17:02 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/03/13 17:02 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/03/13 17:02 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/03/13 17:02 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/03/13 17:02 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/03/13 17:02 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/03/13 17:02 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/03/13 17:02 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)101 %1 02/03/13 17:02 17060-07-070-130
Dibromofluoromethane (S)105 %1 02/03/13 17:02 1868-53-770-130
4-Bromofluorobenzene (S)96 %1 02/03/13 17:02 460-00-470-130
Toluene-d8 (S)102 %1 02/03/13 17:02 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 21 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-5 Lab ID:92146051005 Collected:01/24/13 14:55 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 01/31/13 00:47 106-93-401/30/13 17:210.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)108 %1 01/31/13 00:47 301-79-5601/30/13 17:2170-130
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 02/03/13 15:52 N201/30/13 14:00115115
Aliphatic (C19-C36)ND ug/L 1 02/03/13 15:52 N201/30/13 14:00115115
Aromatic (C11-C22)ND ug/L 1 02/03/13 15:52 N201/30/13 14:00115115
Surrogates
Nonatriacontane (S)80 %1 02/03/13 15:52 7194-86-701/30/13 14:0040-140
o-Terphenyl (S)58 %1 02/03/13 15:52 84-15-101/30/13 14:0040-140
2-Fluorobiphenyl (S)80 %1 02/03/13 15:52 321-60-801/30/13 14:0040-140
2-Bromonaphthalene (S)86 %1 02/03/13 15:52 580-13-201/30/13 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 02/01/13 03:29 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 02/01/13 03:29 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 02/01/13 03:29 N250.0 50.0
Surrogates
4-Bromofluorobenzene (FID) (S)107 %1 02/01/13 03:29 460-00-470-130
4-Bromofluorobenzene (PID) (S)72 %1 02/01/13 03:29 460-00-470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 5.2 ug/L 1 01/29/13 23:38 7439-92-101/26/13 10:155.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/31/13 10:30 83-32-901/28/13 15:005.0 0.25
Acenaphthylene ND ug/L 1 01/31/13 10:30 208-96-801/28/13 15:005.0 0.21
Anthracene ND ug/L 1 01/31/13 10:30 120-12-701/28/13 15:005.0 0.14
Benzo(a)anthracene ND ug/L 1 01/31/13 10:30 56-55-301/28/13 15:005.0 0.33
Benzo(a)pyrene ND ug/L 1 01/31/13 10:30 50-32-801/28/13 15:005.0 0.30
Benzo(b)fluoranthene ND ug/L 1 01/31/13 10:30 205-99-201/28/13 15:005.0 0.28
Benzo(g,h,i)perylene ND ug/L 1 01/31/13 10:30 191-24-201/28/13 15:005.0 0.38
Benzo(k)fluoranthene ND ug/L 1 01/31/13 10:30 207-08-901/28/13 15:005.0 0.43
4-Bromophenylphenyl ether ND ug/L 1 01/31/13 10:30 101-55-301/28/13 15:005.0 0.82
Butylbenzylphthalate ND ug/L 1 01/31/13 10:30 85-68-701/28/13 15:005.0 0.79
4-Chloro-3-methylphenol ND ug/L 1 01/31/13 10:30 59-50-701/28/13 15:005.0 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 01/31/13 10:30 111-91-101/28/13 15:0010.0 0.92
bis(2-Chloroethyl) ether ND ug/L 1 01/31/13 10:30 111-44-401/28/13 15:005.0 1.0
bis(2-Chloroisopropyl) ether ND ug/L 1 01/31/13 10:30 108-60-101/28/13 15:005.0 0.95
2-Chloronaphthalene ND ug/L 1 01/31/13 10:30 91-58-701/28/13 15:005.0 0.98
2-Chlorophenol ND ug/L 1 01/31/13 10:30 95-57-801/28/13 15:005.0 1.3
4-Chlorophenylphenyl ether ND ug/L 1 01/31/13 10:30 7005-72-301/28/13 15:005.0 0.87
Chrysene ND ug/L 1 01/31/13 10:30 218-01-901/28/13 15:005.0 0.21
Dibenz(a,h)anthracene ND ug/L 1 01/31/13 10:30 53-70-301/28/13 15:005.0 0.55
3,3'-Dichlorobenzidine ND ug/L 1 01/31/13 10:30 91-94-101/28/13 15:0025.0 2.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 22 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-5 Lab ID:92146051005 Collected:01/24/13 14:55 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol ND ug/L 1 01/31/13 10:30 120-83-201/28/13 15:005.0 1.7
Diethylphthalate 1.0J ug/L 1 01/31/13 10:30 84-66-201/28/13 15:005.0 0.58
2,4-Dimethylphenol ND ug/L 1 01/31/13 10:30 105-67-901/28/13 15:0010.0 1.2
Dimethylphthalate ND ug/L 1 01/31/13 10:30 131-11-301/28/13 15:005.0 0.76
Di-n-butylphthalate ND ug/L 1 01/31/13 10:30 84-74-201/28/13 15:005.0 0.75
4,6-Dinitro-2-methylphenol ND ug/L 1 01/31/13 10:30 534-52-101/28/13 15:0020.0 2.6
2,4-Dinitrophenol ND ug/L 1 01/31/13 10:30 51-28-501/28/13 15:0050.0 9.0
2,4-Dinitrotoluene ND ug/L 1 01/31/13 10:30 121-14-201/28/13 15:005.0 0.90
2,6-Dinitrotoluene ND ug/L 1 01/31/13 10:30 606-20-201/28/13 15:005.0 0.98
Di-n-octylphthalate ND ug/L 1 01/31/13 10:30 117-84-001/28/13 15:005.0 0.66
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/31/13 10:30 117-81-701/28/13 15:005.0 0.79
Fluoranthene ND ug/L 1 01/31/13 10:30 206-44-001/28/13 15:005.0 0.21
Fluorene ND ug/L 1 01/31/13 10:30 86-73-701/28/13 15:005.0 0.21
Hexachloro-1,3-butadiene ND ug/L 1 01/31/13 10:30 87-68-301/28/13 15:005.0 0.94
Hexachlorobenzene ND ug/L 1 01/31/13 10:30 118-74-101/28/13 15:005.0 0.72
Hexachlorocyclopentadiene ND ug/L 1 01/31/13 10:30 77-47-401/28/13 15:0010.0 0.88
Hexachloroethane ND ug/L 1 01/31/13 10:30 67-72-101/28/13 15:005.0 1.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/31/13 10:30 193-39-501/28/13 15:005.0 0.29
Isophorone ND ug/L 1 01/31/13 10:30 78-59-101/28/13 15:0010.0 0.89
2-Methylnaphthalene ND ug/L 1 01/31/13 10:30 91-57-601/28/13 15:005.0 0.28
Naphthalene ND ug/L 1 01/31/13 10:30 91-20-301/28/13 15:005.0 0.34
Nitrobenzene ND ug/L 1 01/31/13 10:30 98-95-301/28/13 15:005.0 1.1
2-Nitrophenol ND ug/L 1 01/31/13 10:30 88-75-501/28/13 15:005.0 0.91
4-Nitrophenol ND ug/L 1 01/31/13 10:30 100-02-701/28/13 15:0050.0 4.1
N-Nitrosodimethylamine ND ug/L 1 01/31/13 10:30 62-75-901/28/13 15:005.0 0.91
N-Nitroso-di-n-propylamine ND ug/L 1 01/31/13 10:30 621-64-701/28/13 15:005.0 0.99
N-Nitrosodiphenylamine ND ug/L 1 01/31/13 10:30 86-30-601/28/13 15:0010.0 1.0
Pentachlorophenol ND ug/L 1 01/31/13 10:30 87-86-501/28/13 15:0025.0 4.6
Phenanthrene ND ug/L 1 01/31/13 10:30 85-01-801/28/13 15:005.0 0.22
Phenol ND ug/L 1 01/31/13 10:30 108-95-201/28/13 15:005.0 1.9
Pyrene ND ug/L 1 01/31/13 10:30 129-00-001/28/13 15:005.0 0.19
1,2,4-Trichlorobenzene ND ug/L 1 01/31/13 10:30 120-82-101/28/13 15:005.0 0.98
2,4,6-Trichlorophenol ND ug/L 1 01/31/13 10:30 88-06-201/28/13 15:0010.0 1.3
Surrogates
Nitrobenzene-d5 (S)30 %1 01/31/13 10:30 4165-60-001/28/13 15:0010-120
2-Fluorobiphenyl (S)30 %1 01/31/13 10:30 321-60-801/28/13 15:0015-120
Terphenyl-d14 (S)32 %1 01/31/13 10:30 1718-51-001/28/13 15:0011-131
Phenol-d6 (S)9 %1 01/31/13 10:30 13127-88-3 S001/28/13 15:0010-120
2-Fluorophenol (S)17 %1 01/31/13 10:30 367-12-401/28/13 15:0010-120
2,4,6-Tribromophenol (S)32 %1 01/31/13 10:30 118-79-601/28/13 15:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/01/13 06:25 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/01/13 06:25 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/01/13 06:25 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/01/13 06:25 75-27-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 23 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-5 Lab ID:92146051005 Collected:01/24/13 14:55 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Bromoform ND ug/L 1 02/01/13 06:25 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/01/13 06:25 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/01/13 06:25 104-51-80.50 0.25
sec-Butylbenzene 0.29J ug/L 1 02/01/13 06:25 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/01/13 06:25 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/01/13 06:25 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/01/13 06:25 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/01/13 06:25 75-00-31.0 0.50
Chloroform ND ug/L 1 02/01/13 06:25 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/01/13 06:25 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/01/13 06:25 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/01/13 06:25 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/01/13 06:25 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/01/13 06:25 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/01/13 06:25 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/01/13 06:25 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/01/13 06:25 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/01/13 06:25 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/01/13 06:25 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/01/13 06:25 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/01/13 06:25 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/01/13 06:25 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/01/13 06:25 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/01/13 06:25 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/01/13 06:25 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/01/13 06:25 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/01/13 06:25 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/01/13 06:25 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/01/13 06:25 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/01/13 06:25 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/01/13 06:25 10061-02-60.50 0.25
Diisopropyl ether ND ug/L 1 02/01/13 06:25 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/01/13 06:25 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/01/13 06:25 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/01/13 06:25 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/01/13 06:25 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/01/13 06:25 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/01/13 06:25 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/01/13 06:25 108-10-15.0 5.0
Methyl-tert-butyl ether ND ug/L 1 02/01/13 06:25 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/01/13 06:25 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/01/13 06:25 103-65-10.50 0.25
Styrene ND ug/L 1 02/01/13 06:25 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/01/13 06:25 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/01/13 06:25 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/01/13 06:25 127-18-40.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 24 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:MW-5 Lab ID:92146051005 Collected:01/24/13 14:55 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 1 02/01/13 06:25 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/01/13 06:25 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/01/13 06:25 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/01/13 06:25 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/01/13 06:25 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/01/13 06:25 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/01/13 06:25 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/01/13 06:25 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/01/13 06:25 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/01/13 06:25 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/01/13 06:25 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/01/13 06:25 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/01/13 06:25 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)123 %1 02/01/13 06:25 17060-07-070-130
Dibromofluoromethane (S)105 %1 02/01/13 06:25 1868-53-770-130
4-Bromofluorobenzene (S)93 %1 02/01/13 06:25 460-00-470-130
Toluene-d8 (S)100 %1 02/01/13 06:25 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 25 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:TRIP BLANK Lab ID:92146051006 Collected:01/24/13 00:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 02/01/13 06:41 71-43-20.50 0.25
Bromobenzene ND ug/L 1 02/01/13 06:41 108-86-10.50 0.25
Bromochloromethane ND ug/L 1 02/01/13 06:41 74-97-50.50 0.25
Bromodichloromethane ND ug/L 1 02/01/13 06:41 75-27-40.50 0.25
Bromoform ND ug/L 1 02/01/13 06:41 75-25-20.50 0.25
Bromomethane ND ug/L 1 02/01/13 06:41 74-83-95.0 0.50
n-Butylbenzene ND ug/L 1 02/01/13 06:41 104-51-80.50 0.25
sec-Butylbenzene ND ug/L 1 02/01/13 06:41 135-98-80.50 0.25
tert-Butylbenzene ND ug/L 1 02/01/13 06:41 98-06-60.50 0.25
Carbon tetrachloride ND ug/L 1 02/01/13 06:41 56-23-50.50 0.25
Chlorobenzene ND ug/L 1 02/01/13 06:41 108-90-70.50 0.25
Chloroethane ND ug/L 1 02/01/13 06:41 75-00-31.0 0.50
Chloroform ND ug/L 1 02/01/13 06:41 67-66-30.50 0.25
Chloromethane ND ug/L 1 02/01/13 06:41 74-87-31.0 0.50
2-Chlorotoluene ND ug/L 1 02/01/13 06:41 95-49-80.50 0.25
4-Chlorotoluene ND ug/L 1 02/01/13 06:41 106-43-40.50 0.25
1,2-Dibromo-3-chloropropane ND ug/L 1 02/01/13 06:41 96-12-81.0 0.50
Dibromochloromethane ND ug/L 1 02/01/13 06:41 124-48-10.50 0.25
1,2-Dibromoethane (EDB)ND ug/L 1 02/01/13 06:41 106-93-40.50 0.25
Dibromomethane ND ug/L 1 02/01/13 06:41 74-95-30.50 0.25
1,2-Dichlorobenzene ND ug/L 1 02/01/13 06:41 95-50-10.50 0.25
1,3-Dichlorobenzene ND ug/L 1 02/01/13 06:41 541-73-10.50 0.25
1,4-Dichlorobenzene ND ug/L 1 02/01/13 06:41 106-46-70.50 0.25
Dichlorodifluoromethane ND ug/L 1 02/01/13 06:41 75-71-80.50 0.25
1,1-Dichloroethane ND ug/L 1 02/01/13 06:41 75-34-30.50 0.25
1,2-Dichloroethane ND ug/L 1 02/01/13 06:41 107-06-20.50 0.25
1,1-Dichloroethene ND ug/L 1 02/01/13 06:41 75-35-40.50 0.25
cis-1,2-Dichloroethene ND ug/L 1 02/01/13 06:41 156-59-20.50 0.25
trans-1,2-Dichloroethene ND ug/L 1 02/01/13 06:41 156-60-50.50 0.25
1,2-Dichloropropane ND ug/L 1 02/01/13 06:41 78-87-50.50 0.25
1,3-Dichloropropane ND ug/L 1 02/01/13 06:41 142-28-90.50 0.25
2,2-Dichloropropane ND ug/L 1 02/01/13 06:41 594-20-70.50 0.25
1,1-Dichloropropene ND ug/L 1 02/01/13 06:41 563-58-60.50 0.25
cis-1,3-Dichloropropene ND ug/L 1 02/01/13 06:41 10061-01-50.50 0.25
trans-1,3-Dichloropropene ND ug/L 1 02/01/13 06:41 10061-02-60.50 0.25
Diisopropyl ether ND ug/L 1 02/01/13 06:41 108-20-30.50 0.25
Ethylbenzene ND ug/L 1 02/01/13 06:41 100-41-40.50 0.25
Hexachloro-1,3-butadiene ND ug/L 1 02/01/13 06:41 87-68-32.0 1.0
2-Hexanone ND ug/L 1 02/01/13 06:41 591-78-65.0 5.0
Isopropylbenzene (Cumene)ND ug/L 1 02/01/13 06:41 98-82-80.50 0.25
p-Isopropyltoluene ND ug/L 1 02/01/13 06:41 99-87-60.50 0.25
Methylene Chloride ND ug/L 1 02/01/13 06:41 75-09-22.0 1.0
4-Methyl-2-pentanone (MIBK)ND ug/L 1 02/01/13 06:41 108-10-15.0 5.0
Methyl-tert-butyl ether ND ug/L 1 02/01/13 06:41 1634-04-40.50 0.25
Naphthalene ND ug/L 1 02/01/13 06:41 91-20-32.0 1.0
n-Propylbenzene ND ug/L 1 02/01/13 06:41 103-65-10.50 0.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 26 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92146051
Purgason's #19720
Sample:TRIP BLANK Lab ID:92146051006 Collected:01/24/13 00:00 Received:01/25/13 15:55 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Styrene ND ug/L 1 02/01/13 06:41 100-42-50.50 0.25
1,1,1,2-Tetrachloroethane ND ug/L 1 02/01/13 06:41 630-20-60.50 0.25
1,1,2,2-Tetrachloroethane ND ug/L 1 02/01/13 06:41 79-34-50.50 0.25
Tetrachloroethene ND ug/L 1 02/01/13 06:41 127-18-40.50 0.25
Toluene ND ug/L 1 02/01/13 06:41 108-88-30.50 0.25
1,2,3-Trichlorobenzene ND ug/L 1 02/01/13 06:41 87-61-62.0 1.0
1,2,4-Trichlorobenzene ND ug/L 1 02/01/13 06:41 120-82-12.0 1.0
1,1,1-Trichloroethane ND ug/L 1 02/01/13 06:41 71-55-60.50 0.25
1,1,2-Trichloroethane ND ug/L 1 02/01/13 06:41 79-00-50.50 0.25
Trichloroethene ND ug/L 1 02/01/13 06:41 79-01-60.50 0.25
Trichlorofluoromethane ND ug/L 1 02/01/13 06:41 75-69-41.0 0.50
1,2,3-Trichloropropane ND ug/L 1 02/01/13 06:41 96-18-40.50 0.25
1,2,4-Trimethylbenzene ND ug/L 1 02/01/13 06:41 95-63-60.50 0.25
1,3,5-Trimethylbenzene ND ug/L 1 02/01/13 06:41 108-67-80.50 0.25
Vinyl chloride ND ug/L 1 02/01/13 06:41 75-01-41.0 0.25
m&p-Xylene ND ug/L 1 02/01/13 06:41 179601-23-11.0 0.50
o-Xylene ND ug/L 1 02/01/13 06:41 95-47-60.50 0.25
Surrogates
1,2-Dichloroethane-d4 (S)124 %1 02/01/13 06:41 17060-07-070-130
Dibromofluoromethane (S)105 %1 02/01/13 06:41 1868-53-770-130
4-Bromofluorobenzene (S)92 %1 02/01/13 06:41 460-00-470-130
Toluene-d8 (S)101 %1 02/01/13 06:41 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 27 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/6594
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:914288
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N202/01/13 00:25
Aliphatic (C09-C12)ug/L ND 50.0 N202/01/13 00:25
Aromatic (C09-C10)ug/L ND 50.0 N202/01/13 00:25
4-Bromofluorobenzene (FID) (S)%103 70-130 02/01/13 00:25
4-Bromofluorobenzene (PID) (S)%71 70-130 02/01/13 00:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
914289LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
914290
Aliphatic (C05-C08)ug/L 236 N23007970-13083250 6 25
Aliphatic (C09-C12)ug/L 252 N23008430-13090269 6 25
Aromatic (C09-C10)ug/L 80.2 N21008070-1308483.8 4 25
4-Bromofluorobenzene (FID) (S)%95 70-13098
4-Bromofluorobenzene (PID) (S)%82 70-13086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 28 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/12461
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:911569
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
Lead ug/L ND 5.0 01/29/13 22:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
911570LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 483500 97 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
911571MATRIX SPIKE SAMPLE:
MSSpike
Result
92146011001
Lead ug/L 475500 88 70-13033.2
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
911573MATRIX SPIKE SAMPLE:
MSSpike
Result
92146051003
Lead ug/L 452500 90 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92146011002
911572SAMPLE DUPLICATE:
Lead ug/L 9.7 2 209.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92146051004
911574SAMPLE DUPLICATE:
Lead ug/L 5.2 3 205.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 29 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21855
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92146051001, 92146051002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913981
Associated Lab Samples:92146051001, 92146051002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/31/13 21:30
1,1,1-Trichloroethane ug/L ND 0.50 01/31/13 21:30
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/31/13 21:30
1,1,2-Trichloroethane ug/L ND 0.50 01/31/13 21:30
1,1-Dichloroethane ug/L ND 0.50 01/31/13 21:30
1,1-Dichloroethene ug/L ND 0.50 01/31/13 21:30
1,1-Dichloropropene ug/L ND 0.50 01/31/13 21:30
1,2,3-Trichlorobenzene ug/L ND 2.0 01/31/13 21:30
1,2,3-Trichloropropane ug/L ND 0.50 01/31/13 21:30
1,2,4-Trichlorobenzene ug/L ND 2.0 01/31/13 21:30
1,2,4-Trimethylbenzene ug/L ND 0.50 01/31/13 21:30
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/31/13 21:30
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/31/13 21:30
1,2-Dichlorobenzene ug/L ND 0.50 01/31/13 21:30
1,2-Dichloroethane ug/L ND 0.50 01/31/13 21:30
1,2-Dichloropropane ug/L ND 0.50 01/31/13 21:30
1,3,5-Trimethylbenzene ug/L ND 0.50 01/31/13 21:30
1,3-Dichlorobenzene ug/L ND 0.50 01/31/13 21:30
1,3-Dichloropropane ug/L ND 0.50 01/31/13 21:30
1,4-Dichlorobenzene ug/L ND 0.50 01/31/13 21:30
2,2-Dichloropropane ug/L ND 0.50 01/31/13 21:30
2-Chlorotoluene ug/L ND 0.50 01/31/13 21:30
2-Hexanone ug/L ND 5.0 01/31/13 21:30
4-Chlorotoluene ug/L ND 0.50 01/31/13 21:30
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 01/31/13 21:30
Benzene ug/L ND 0.50 01/31/13 21:30
Bromobenzene ug/L ND 0.50 01/31/13 21:30
Bromochloromethane ug/L ND 0.50 01/31/13 21:30
Bromodichloromethane ug/L ND 0.50 01/31/13 21:30
Bromoform ug/L ND 0.50 01/31/13 21:30
Bromomethane ug/L ND 5.0 01/31/13 21:30
Carbon tetrachloride ug/L ND 0.50 01/31/13 21:30
Chlorobenzene ug/L ND 0.50 01/31/13 21:30
Chloroethane ug/L ND 1.0 01/31/13 21:30
Chloroform ug/L ND 0.50 01/31/13 21:30
Chloromethane ug/L ND 1.0 01/31/13 21:30
cis-1,2-Dichloroethene ug/L ND 0.50 01/31/13 21:30
cis-1,3-Dichloropropene ug/L ND 0.50 01/31/13 21:30
Dibromochloromethane ug/L ND 0.50 01/31/13 21:30
Dibromomethane ug/L ND 0.50 01/31/13 21:30
Dichlorodifluoromethane ug/L ND 0.50 01/31/13 21:30
Diisopropyl ether ug/L ND 0.50 01/31/13 21:30
Ethylbenzene ug/L ND 0.50 01/31/13 21:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 30 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913981
Associated Lab Samples:92146051001, 92146051002
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 01/31/13 21:30
Isopropylbenzene (Cumene)ug/L ND 0.50 01/31/13 21:30
m&p-Xylene ug/L ND 1.0 01/31/13 21:30
Methyl-tert-butyl ether ug/L ND 0.50 01/31/13 21:30
Methylene Chloride ug/L ND 2.0 01/31/13 21:30
n-Butylbenzene ug/L ND 0.50 01/31/13 21:30
n-Propylbenzene ug/L ND 0.50 01/31/13 21:30
Naphthalene ug/L ND 2.0 01/31/13 21:30
o-Xylene ug/L ND 0.50 01/31/13 21:30
p-Isopropyltoluene ug/L ND 0.50 01/31/13 21:30
sec-Butylbenzene ug/L ND 0.50 01/31/13 21:30
Styrene ug/L ND 0.50 01/31/13 21:30
tert-Butylbenzene ug/L ND 0.50 01/31/13 21:30
Tetrachloroethene ug/L ND 0.50 01/31/13 21:30
Toluene ug/L ND 0.50 01/31/13 21:30
trans-1,2-Dichloroethene ug/L ND 0.50 01/31/13 21:30
trans-1,3-Dichloropropene ug/L ND 0.50 01/31/13 21:30
Trichloroethene ug/L ND 0.50 01/31/13 21:30
Trichlorofluoromethane ug/L ND 1.0 01/31/13 21:30
Vinyl chloride ug/L ND 1.0 01/31/13 21:30
1,2-Dichloroethane-d4 (S)%120 70-130 01/31/13 21:30
4-Bromofluorobenzene (S)%93 70-130 01/31/13 21:30
Dibromofluoromethane (S)%100 70-130 01/31/13 21:30
Toluene-d8 (S)%102 70-130 01/31/13 21:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913982LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.750 97 60-140
1,1,1-Trichloroethane ug/L 50.050 100 60-140
1,1,2,2-Tetrachloroethane ug/L 51.850 104 60-140
1,1,2-Trichloroethane ug/L 56.750 113 60-140
1,1-Dichloroethane ug/L 49.650 99 60-140
1,1-Dichloroethene ug/L 46.650 93 60-140
1,1-Dichloropropene ug/L 50.250 100 60-140
1,2,3-Trichlorobenzene ug/L 58.450 117 60-140
1,2,3-Trichloropropane ug/L 52.250 104 60-140
1,2,4-Trichlorobenzene ug/L 57.350 115 60-140
1,2,4-Trimethylbenzene ug/L 55.250 110 60-140
1,2-Dibromo-3-chloropropane ug/L 69.350 139 60-140
1,2-Dibromoethane (EDB)ug/L 51.350 103 60-140
1,2-Dichlorobenzene ug/L 53.650 107 60-140
1,2-Dichloroethane ug/L 51.750 103 60-140
1,2-Dichloropropane ug/L 52.550 105 60-140
1,3,5-Trimethylbenzene ug/L 55.350 111 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 31 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913982LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 50.850 102 60-140
1,3-Dichloropropane ug/L 52.650 105 60-140
1,4-Dichlorobenzene ug/L 52.050 104 60-140
2,2-Dichloropropane ug/L 46.950 94 60-140
2-Chlorotoluene ug/L 54.850 110 60-140
2-Hexanone ug/L 142 L010014260-140
4-Chlorotoluene ug/L 55.450 111 60-140
4-Methyl-2-pentanone (MIBK)ug/L 148 CU,L010014860-140
Benzene ug/L 50.150 100 60-140
Bromobenzene ug/L 54.450 109 60-140
Bromochloromethane ug/L 48.850 98 60-140
Bromodichloromethane ug/L 53.950 108 60-140
Bromoform ug/L 54.850 110 60-140
Bromomethane ug/L 42.250 84 60-140
Carbon tetrachloride ug/L 50.050 100 60-140
Chlorobenzene ug/L 48.250 96 60-140
Chloroethane ug/L 52.150 104 60-140
Chloroform ug/L 50.350 101 60-140
Chloromethane ug/L 42.750 85 60-140
cis-1,2-Dichloroethene ug/L 49.750 99 60-140
cis-1,3-Dichloropropene ug/L 56.850 114 60-140
Dibromochloromethane ug/L 51.750 103 60-140
Dibromomethane ug/L 51.950 104 60-140
Dichlorodifluoromethane ug/L 41.2 CU,F3508260-140
Diisopropyl ether ug/L 54.850 110 60-140
Ethylbenzene ug/L 49.650 99 60-140
Hexachloro-1,3-butadiene ug/L 53.550 107 60-140
Isopropylbenzene (Cumene)ug/L 48.050 96 60-140
m&p-Xylene ug/L 102100 102 60-140
Methyl-tert-butyl ether ug/L 48.050 96 60-140
Methylene Chloride ug/L 50.850 102 60-140
n-Butylbenzene ug/L 57.150 114 60-140
n-Propylbenzene ug/L 53.950 108 60-140
Naphthalene ug/L 60.550 121 60-140
o-Xylene ug/L 49.050 98 60-140
p-Isopropyltoluene ug/L 57.550 115 60-140
sec-Butylbenzene ug/L 55.250 110 60-140
Styrene ug/L 52.650 105 60-140
tert-Butylbenzene ug/L 53.750 107 60-140
Tetrachloroethene ug/L 43.450 87 60-140
Toluene ug/L 49.750 99 60-140
trans-1,2-Dichloroethene ug/L 47.050 94 60-140
trans-1,3-Dichloropropene ug/L 60.250 120 60-140
Trichloroethene ug/L 46.850 94 60-140
Trichlorofluoromethane ug/L 46.450 93 60-140
Vinyl chloride ug/L 43.850 88 60-140
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%93 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 32 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913982LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromofluoromethane (S)%102 70-130
Toluene-d8 (S)%104 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
913983MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146056002
913984
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 124 60-140107 15 3020ND24.9 21.3
1,1,1-Trichloroethane ug/L 20 133 60-140113 16 3020ND26.6 22.7
1,1,2,2-Tetrachloroethane ug/L 20 126 60-140111 13 3020ND25.3 22.3
1,1,2-Trichloroethane ug/L 20 135 60-140115 16 3020ND27.1 23.1
1,1-Dichloroethane ug/L 20 130 60-140111 16 3020ND26.0 22.2
1,1-Dichloroethene ug/L 20 121 60-140108 12 3020ND24.2 21.5
1,1-Dichloropropene ug/L 20 129 60-140111 15 3020ND25.9 22.2
1,2,3-Trichlorobenzene ug/L 20 115 60-140105 9 3020ND22.9 21.0
1,2,3-Trichloropropane ug/L 20 127 60-140113 12 3020ND25.3 22.5
1,2,4-Trichlorobenzene ug/L 20 117 60-140105 11 3020ND23.4 21.0
1,2,4-Trimethylbenzene ug/L 20 133 60-140115 14 30200.53 27.1 23.6
1,2-Dibromo-3-chloropropane ug/L M12014960-140137 9 3020ND29.8 27.3
1,2-Dibromoethane (EDB)ug/L 20 125 60-140108 15 3020ND25.1 21.6
1,2-Dichlorobenzene ug/L 20 129 60-140112 14 3020ND25.8 22.4
1,2-Dichloroethane ug/L 20 132 60-140117 12 3020ND26.3 23.3
1,2-Dichloropropane ug/L 20 127 60-140112 13 3020ND25.4 22.4
1,3,5-Trimethylbenzene ug/L 20 133 60-140115 14 3020ND26.6 23.0
1,3-Dichlorobenzene ug/L 20 126 60-140110 13 3020ND25.1 22.0
1,3-Dichloropropane ug/L 20 129 60-140111 15 3020ND25.8 22.3
1,4-Dichlorobenzene ug/L 20 126 60-140110 14 3020ND25.2 22.0
2,2-Dichloropropane ug/L 20 117 60-14097 18 3020ND23.4 19.5
2-Chlorotoluene ug/L 20 134 60-140117 13 3020ND26.7 23.4
2-Hexanone ug/L M04015960-140139 13 3040ND63.5 55.6
4-Chlorotoluene ug/L 20 137 60-140120 13 3020ND27.3 23.9
4-Methyl-2-pentanone (MIBK)ug/L M04015960-140137 15 3040ND63.5 54.8
Benzene ug/L 20 127 60-140109 15 3020ND25.5 21.8
Bromobenzene ug/L 20 135 60-140118 13 3020ND27.0 23.6
Bromochloromethane ug/L 20 119 60-140104 13 3020ND23.8 20.9
Bromodichloromethane ug/L 20 134 60-140116 14 3020ND26.7 23.2
Bromoform ug/L 20 134 60-140114 16 3020ND26.9 22.8
Bromomethane ug/L M12015160-140139 9 3020ND30.3 27.7
Carbon tetrachloride ug/L 20 135 60-140114 16 3020ND26.9 22.8
Chlorobenzene ug/L 20 124 60-140109 13 3020ND24.9 21.8
Chloroethane ug/L 20 138 60-140122 12 3020ND27.7 24.4
Chloroform ug/L 20 128 60-140108 17 3020ND25.6 21.6
Chloromethane ug/L 20 106 60-14095 11 3020ND21.3 19.0
cis-1,2-Dichloroethene ug/L 20 124 60-140112 11 3020ND24.8 22.3
cis-1,3-Dichloropropene ug/L 20 124 60-140108 14 3020ND24.8 21.6
Dibromochloromethane ug/L 20 127 60-140112 12 3020ND25.4 22.5
Dibromomethane ug/L 20 124 60-140109 13 3020ND24.7 21.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 33 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
913983MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146056002
913984
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Dichlorodifluoromethane ug/L 20 116 60-140100 15 3020ND23.2 20.0
Diisopropyl ether ug/L 20 137 60-140116 17 3020ND27.4 23.2
Ethylbenzene ug/L 20 127 60-140109 15 3020ND25.8 22.2
Hexachloro-1,3-butadiene ug/L 20 115 60-140100 14 3020ND22.9 20.0
Isopropylbenzene (Cumene)ug/L 20 121 60-140103 16 3020ND24.1 20.6
m&p-Xylene ug/L 40 131 60-140112 15 3040ND52.3 45.0
Methyl-tert-butyl ether ug/L 20 110 60-14094 14 30201.3 23.2 20.1
Methylene Chloride ug/L 20 120 60-140103 15 3020ND24.0 20.6
n-Butylbenzene ug/L 20 127 60-140111 14 3020ND25.4 22.1
n-Propylbenzene ug/L 20 132 60-140117 12 3020ND26.6 23.6
Naphthalene ug/L 20 115 60-140106 8 3020ND22.9 21.1
o-Xylene ug/L 20 122 60-140105 15 3020ND24.7 21.2
p-Isopropyltoluene ug/L 20 133 60-140116 14 3020ND26.6 23.1
sec-Butylbenzene ug/L 20 133 60-140114 15 3020ND26.5 22.8
Styrene ug/L 20 116 60-140100 15 3020ND23.2 20.1
tert-Butylbenzene ug/L 20 131 60-140114 14 3020ND26.3 22.9
Tetrachloroethene ug/L 20 114 60-14099 13 3020ND22.7 19.9
Toluene ug/L 20 125 60-140108 15 3020ND25.0 21.6
trans-1,2-Dichloroethene ug/L 20 119 60-140105 12 3020ND23.8 21.1
trans-1,3-Dichloropropene ug/L 20 134 60-140115 15 3020ND26.8 23.1
Trichloroethene ug/L 20 123 60-140104 16 3020ND24.5 20.8
Trichlorofluoromethane ug/L 20 129 60-140110 16 3020ND25.8 22.1
Vinyl chloride ug/L 20 112 60-14099 12 3020ND22.5 19.9
1,2-Dichloroethane-d4 (S)%112 70-130113
4-Bromofluorobenzene (S)%95 70-13095
Dibromofluoromethane (S)%101 70-130102
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 34 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21856
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92146051003, 92146051004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913988
Associated Lab Samples:92146051003, 92146051004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/03/13 14:38
1,1,1-Trichloroethane ug/L ND 0.50 02/03/13 14:38
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/03/13 14:38
1,1,2-Trichloroethane ug/L ND 0.50 02/03/13 14:38
1,1-Dichloroethane ug/L ND 0.50 02/03/13 14:38
1,1-Dichloroethene ug/L ND 0.50 02/03/13 14:38
1,1-Dichloropropene ug/L ND 0.50 02/03/13 14:38
1,2,3-Trichlorobenzene ug/L ND 2.0 02/03/13 14:38
1,2,3-Trichloropropane ug/L ND 0.50 02/03/13 14:38
1,2,4-Trichlorobenzene ug/L ND 2.0 02/03/13 14:38
1,2,4-Trimethylbenzene ug/L ND 0.50 02/03/13 14:38
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/03/13 14:38
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/03/13 14:38
1,2-Dichlorobenzene ug/L ND 0.50 02/03/13 14:38
1,2-Dichloroethane ug/L ND 0.50 02/03/13 14:38
1,2-Dichloropropane ug/L ND 0.50 02/03/13 14:38
1,3,5-Trimethylbenzene ug/L ND 0.50 02/03/13 14:38
1,3-Dichlorobenzene ug/L ND 0.50 02/03/13 14:38
1,3-Dichloropropane ug/L ND 0.50 02/03/13 14:38
1,4-Dichlorobenzene ug/L ND 0.50 02/03/13 14:38
2,2-Dichloropropane ug/L ND 0.50 02/03/13 14:38
2-Chlorotoluene ug/L ND 0.50 02/03/13 14:38
2-Hexanone ug/L ND 5.0 02/03/13 14:38
4-Chlorotoluene ug/L ND 0.50 02/03/13 14:38
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/03/13 14:38
Benzene ug/L ND 0.50 02/03/13 14:38
Bromobenzene ug/L ND 0.50 02/03/13 14:38
Bromochloromethane ug/L ND 0.50 02/03/13 14:38
Bromodichloromethane ug/L ND 0.50 02/03/13 14:38
Bromoform ug/L ND 0.50 02/03/13 14:38
Bromomethane ug/L ND 5.0 02/03/13 14:38
Carbon tetrachloride ug/L ND 0.50 02/03/13 14:38
Chlorobenzene ug/L ND 0.50 02/03/13 14:38
Chloroethane ug/L ND 1.0 02/03/13 14:38
Chloroform ug/L ND 0.50 02/03/13 14:38
Chloromethane ug/L ND 1.0 02/03/13 14:38
cis-1,2-Dichloroethene ug/L ND 0.50 02/03/13 14:38
cis-1,3-Dichloropropene ug/L ND 0.50 02/03/13 14:38
Dibromochloromethane ug/L ND 0.50 02/03/13 14:38
Dibromomethane ug/L ND 0.50 02/03/13 14:38
Dichlorodifluoromethane ug/L ND 0.50 02/03/13 14:38
Diisopropyl ether ug/L ND 0.50 02/03/13 14:38
Ethylbenzene ug/L ND 0.50 02/03/13 14:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 35 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913988
Associated Lab Samples:92146051003, 92146051004
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L 2.3 2.0 02/03/13 14:38
Isopropylbenzene (Cumene)ug/L ND 0.50 02/03/13 14:38
m&p-Xylene ug/L ND 1.0 02/03/13 14:38
Methyl-tert-butyl ether ug/L ND 0.50 02/03/13 14:38
Methylene Chloride ug/L ND 2.0 02/03/13 14:38
n-Butylbenzene ug/L 0.36J 0.50 02/03/13 14:38
n-Propylbenzene ug/L ND 0.50 02/03/13 14:38
Naphthalene ug/L ND 2.0 02/03/13 14:38
o-Xylene ug/L ND 0.50 02/03/13 14:38
p-Isopropyltoluene ug/L ND 0.50 02/03/13 14:38
sec-Butylbenzene ug/L ND 0.50 02/03/13 14:38
Styrene ug/L ND 0.50 02/03/13 14:38
tert-Butylbenzene ug/L ND 0.50 02/03/13 14:38
Tetrachloroethene ug/L ND 0.50 02/03/13 14:38
Toluene ug/L ND 0.50 02/03/13 14:38
trans-1,2-Dichloroethene ug/L ND 0.50 02/03/13 14:38
trans-1,3-Dichloropropene ug/L ND 0.50 02/03/13 14:38
Trichloroethene ug/L ND 0.50 02/03/13 14:38
Trichlorofluoromethane ug/L ND 1.0 02/03/13 14:38
Vinyl chloride ug/L ND 1.0 02/03/13 14:38
1,2-Dichloroethane-d4 (S)%106 70-130 02/03/13 14:38
4-Bromofluorobenzene (S)%99 70-130 02/03/13 14:38
Dibromofluoromethane (S)%103 70-130 02/03/13 14:38
Toluene-d8 (S)%101 70-130 02/03/13 14:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913989LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.050 106 60-140
1,1,1-Trichloroethane ug/L 49.650 99 60-140
1,1,2,2-Tetrachloroethane ug/L 51.550 103 60-140
1,1,2-Trichloroethane ug/L 51.050 102 60-140
1,1-Dichloroethane ug/L 48.450 97 60-140
1,1-Dichloroethene ug/L 47.750 95 60-140
1,1-Dichloropropene ug/L 52.250 104 60-140
1,2,3-Trichlorobenzene ug/L 56.050 112 60-140
1,2,3-Trichloropropane ug/L 50.650 101 60-140
1,2,4-Trichlorobenzene ug/L 56.350 113 60-140
1,2,4-Trimethylbenzene ug/L 60.450 121 60-140
1,2-Dibromo-3-chloropropane ug/L 54.550 109 60-140
1,2-Dibromoethane (EDB)ug/L 52.050 104 60-140
1,2-Dichlorobenzene ug/L 51.150 102 60-140
1,2-Dichloroethane ug/L 49.650 99 60-140
1,2-Dichloropropane ug/L 50.450 101 60-140
1,3,5-Trimethylbenzene ug/L 51.150 102 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 36 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913989LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 50.950 102 60-140
1,3-Dichloropropane ug/L 51.250 102 60-140
1,4-Dichlorobenzene ug/L 50.750 101 60-140
2,2-Dichloropropane ug/L 49.250 98 60-140
2-Chlorotoluene ug/L 51.250 102 60-140
2-Hexanone ug/L 104100 104 60-140
4-Chlorotoluene ug/L 51.150 102 60-140
4-Methyl-2-pentanone (MIBK)ug/L 98.5100 98 60-140
Benzene ug/L 52.050 104 60-140
Bromobenzene ug/L 52.750 105 60-140
Bromochloromethane ug/L 49.350 99 60-140
Bromodichloromethane ug/L 51.850 104 60-140
Bromoform ug/L 55.550 111 60-140
Bromomethane ug/L 54.350 109 60-140
Carbon tetrachloride ug/L 52.850 106 60-140
Chlorobenzene ug/L 52.250 104 60-140
Chloroethane ug/L 55.250 110 60-140
Chloroform ug/L 45.850 92 60-140
Chloromethane ug/L 50.550 101 60-140
cis-1,2-Dichloroethene ug/L 49.050 98 60-140
cis-1,3-Dichloropropene ug/L 52.150 104 60-140
Dibromochloromethane ug/L 53.450 107 60-140
Dibromomethane ug/L 51.250 102 60-140
Dichlorodifluoromethane ug/L 49.750 99 60-140
Diisopropyl ether ug/L 48.350 97 60-140
Ethylbenzene ug/L 52.450 105 60-140
Hexachloro-1,3-butadiene ug/L 62.450 125 60-140
Isopropylbenzene (Cumene)ug/L 51.950 104 60-140
m&p-Xylene ug/L 107100 107 60-140
Methyl-tert-butyl ether ug/L 47.350 95 60-140
Methylene Chloride ug/L 53.850 108 60-140
n-Butylbenzene ug/L 54.150 108 60-140
n-Propylbenzene ug/L 52.550 105 60-140
Naphthalene ug/L 52.950 106 60-140
o-Xylene ug/L 50.250 100 60-140
p-Isopropyltoluene ug/L 54.750 109 60-140
sec-Butylbenzene ug/L 55.350 111 60-140
Styrene ug/L 53.750 107 60-140
tert-Butylbenzene ug/L 52.250 104 60-140
Tetrachloroethene ug/L 52.650 105 60-140
Toluene ug/L 48.450 97 60-140
trans-1,2-Dichloroethene ug/L 47.450 95 60-140
trans-1,3-Dichloropropene ug/L 51.750 103 60-140
Trichloroethene ug/L 52.050 104 60-140
Trichlorofluoromethane ug/L 48.850 98 60-140
Vinyl chloride ug/L 50.350 101 60-140
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 37 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913989LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromofluoromethane (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
913990MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146051003
913991
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 117 60-140121 3 3020ND23.5 24.3
1,1,1-Trichloroethane ug/L 20 107 60-140116 8 3020ND21.4 23.1
1,1,2,2-Tetrachloroethane ug/L 20 112 60-140113 1 3020ND22.4 22.7
1,1,2-Trichloroethane ug/L 20 121 60-140114 7 3020ND24.3 22.7
1,1-Dichloroethane ug/L 20 107 60-140109 2 3020ND21.5 21.9
1,1-Dichloroethene ug/L 20 103 60-140109 5 3020ND20.6 21.7
1,1-Dichloropropene ug/L 20 112 60-140112 0 3020ND22.3 22.4
1,2,3-Trichlorobenzene ug/L 20 110 60-140114 3 3020ND22.1 22.7
1,2,3-Trichloropropane ug/L 20 111 60-140117 6 3020ND22.1 23.5
1,2,4-Trichlorobenzene ug/L 20 111 60-140116 4 3020ND22.2 23.1
1,2,4-Trimethylbenzene ug/L 20 111 60-140107 4 3020ND22.3 21.4
1,2-Dibromo-3-chloropropane ug/L 20 123 60-140125 1 3020ND24.7 25.0
1,2-Dibromoethane (EDB)ug/L 20 114 60-140115 1 3020ND22.7 23.0
1,2-Dichlorobenzene ug/L 20 112 60-140115 2 3020ND22.4 22.9
1,2-Dichloroethane ug/L 20 107 60-140111 3 3020ND21.5 22.2
1,2-Dichloropropane ug/L 20 108 60-140106 2 3020ND21.7 21.2
1,3,5-Trimethylbenzene ug/L 20 110 60-140112 2 3020ND22.1 22.4
1,3-Dichlorobenzene ug/L 20 110 60-140111 1 3020ND22.0 22.1
1,3-Dichloropropane ug/L 20 115 60-140115 1 3020ND22.9 23.1
1,4-Dichlorobenzene ug/L 20 110 60-140107 3 3020ND22.0 21.5
2,2-Dichloropropane ug/L M0203760-14037 0 3020ND7.3 7.4
2-Chlorotoluene ug/L 20 112 60-140124 10 3020ND22.5 24.9
2-Hexanone ug/L 40 115 60-140122 6 3040ND46.0 48.7
4-Chlorotoluene ug/L 20 115 60-140116 1 3020ND23.0 23.2
4-Methyl-2-pentanone (MIBK)ug/L 40 115 60-140113 2 3040ND46.1 45.2
Benzene ug/L 20 112 60-140111 1 3020ND22.5 22.3
Bromobenzene ug/L 20 114 60-140116 2 3020ND22.9 23.3
Bromochloromethane ug/L 20 107 60-140107 1 3020ND21.4 21.5
Bromodichloromethane ug/L 20 117 60-140115 1 3020ND23.4 23.1
Bromoform ug/L 20 123 60-140123 0 3020ND24.5 24.5
Bromomethane ug/L M0205960-14071 18 3020ND11.8 14.1
Carbon tetrachloride ug/L 20 118 60-140120 2 3020ND23.6 24.0
Chlorobenzene ug/L 20 116 60-140117 1 3020ND23.1 23.3
Chloroethane ug/L 20 91 60-140102 12 3020ND18.1 20.4
Chloroform ug/L 20 106 60-140103 3 3020ND21.1 20.6
Chloromethane ug/L R1206560-14093 36 3020ND13.0 18.7
cis-1,2-Dichloroethene ug/L 20 105 60-140108 2 3020ND21.1 21.6
cis-1,3-Dichloropropene ug/L 20 91 60-14093 2 3020ND18.2 18.6
Dibromochloromethane ug/L 20 122 60-140121 1 3020ND24.3 24.2
Dibromomethane ug/L 20 112 60-140111 1 3020ND22.4 22.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 38 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
913990MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146051003
913991
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Dichlorodifluoromethane ug/L 20 81 60-14085 5 3020ND16.2 17.1
Diisopropyl ether ug/L 20 101 60-140106 5 3020ND20.1 21.2
Ethylbenzene ug/L 20 120 60-140116 4 3020ND24.1 23.1
Hexachloro-1,3-butadiene ug/L 20 102 60-140103 0 3020ND20.5 20.5
Isopropylbenzene (Cumene)ug/L 20 109 60-140112 2 3020ND21.8 22.4
m&p-Xylene ug/L 40 112 60-140110 2 3040ND44.9 44.1
Methyl-tert-butyl ether ug/L 20 100 60-140105 5 3020ND20.0 20.9
Methylene Chloride ug/L 20 113 60-140122 7 3020ND22.6 24.3
n-Butylbenzene ug/L 20 103 60-140104 1 3020ND20.7 20.9
n-Propylbenzene ug/L 20 117 60-140117 0 3020ND23.5 23.5
Naphthalene ug/L 20 126 60-140116 8 3020ND25.6 23.6
o-Xylene ug/L 20 108 60-140110 2 3020ND21.5 22.0
p-Isopropyltoluene ug/L 20 111 60-140112 0 3020ND22.3 22.4
sec-Butylbenzene ug/L 20 117 60-140120 2 3020ND23.5 23.9
Styrene ug/L 20 96 60-14099 3 3020ND19.3 19.8
tert-Butylbenzene ug/L 20 116 60-140120 4 3020ND23.1 24.1
Tetrachloroethene ug/L 20 114 60-140113 2 3020ND22.9 22.5
Toluene ug/L 20 106 60-140107 1 3020ND21.2 21.4
trans-1,2-Dichloroethene ug/L 20 98 60-140106 8 3020ND19.6 21.2
trans-1,3-Dichloropropene ug/L 20 98 60-14094 4 3020ND19.6 18.8
Trichloroethene ug/L 20 109 60-140107 1 3020ND21.7 21.5
Trichlorofluoromethane ug/L 20 99 60-140105 6 3020ND19.8 20.9
Vinyl chloride ug/L 20 86 60-14093 9 3020ND17.1 18.6
1,2-Dichloroethane-d4 (S)%93 70-13097
4-Bromofluorobenzene (S)%98 70-13099
Dibromofluoromethane (S)%99 70-13098
Toluene-d8 (S)%100 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 39 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/21867
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92146051005, 92146051006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:915047
Associated Lab Samples:92146051005, 92146051006
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/01/13 04:31
1,1,1-Trichloroethane ug/L ND 0.50 02/01/13 04:31
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/01/13 04:31
1,1,2-Trichloroethane ug/L ND 0.50 02/01/13 04:31
1,1-Dichloroethane ug/L ND 0.50 02/01/13 04:31
1,1-Dichloroethene ug/L ND 0.50 02/01/13 04:31
1,1-Dichloropropene ug/L ND 0.50 02/01/13 04:31
1,2,3-Trichlorobenzene ug/L ND 2.0 02/01/13 04:31
1,2,3-Trichloropropane ug/L ND 0.50 02/01/13 04:31
1,2,4-Trichlorobenzene ug/L ND 2.0 02/01/13 04:31
1,2,4-Trimethylbenzene ug/L ND 0.50 02/01/13 04:31
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/01/13 04:31
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/01/13 04:31
1,2-Dichlorobenzene ug/L ND 0.50 02/01/13 04:31
1,2-Dichloroethane ug/L ND 0.50 02/01/13 04:31
1,2-Dichloropropane ug/L ND 0.50 02/01/13 04:31
1,3,5-Trimethylbenzene ug/L ND 0.50 02/01/13 04:31
1,3-Dichlorobenzene ug/L ND 0.50 02/01/13 04:31
1,3-Dichloropropane ug/L ND 0.50 02/01/13 04:31
1,4-Dichlorobenzene ug/L ND 0.50 02/01/13 04:31
2,2-Dichloropropane ug/L ND 0.50 02/01/13 04:31
2-Chlorotoluene ug/L ND 0.50 02/01/13 04:31
2-Hexanone ug/L ND 5.0 02/01/13 04:31
4-Chlorotoluene ug/L ND 0.50 02/01/13 04:31
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/01/13 04:31
Benzene ug/L ND 0.50 02/01/13 04:31
Bromobenzene ug/L ND 0.50 02/01/13 04:31
Bromochloromethane ug/L ND 0.50 02/01/13 04:31
Bromodichloromethane ug/L ND 0.50 02/01/13 04:31
Bromoform ug/L ND 0.50 02/01/13 04:31
Bromomethane ug/L ND 5.0 02/01/13 04:31
Carbon tetrachloride ug/L ND 0.50 02/01/13 04:31
Chlorobenzene ug/L ND 0.50 02/01/13 04:31
Chloroethane ug/L ND 1.0 02/01/13 04:31
Chloroform ug/L ND 0.50 02/01/13 04:31
Chloromethane ug/L ND 1.0 02/01/13 04:31
cis-1,2-Dichloroethene ug/L ND 0.50 02/01/13 04:31
cis-1,3-Dichloropropene ug/L ND 0.50 02/01/13 04:31
Dibromochloromethane ug/L ND 0.50 02/01/13 04:31
Dibromomethane ug/L ND 0.50 02/01/13 04:31
Dichlorodifluoromethane ug/L ND 0.50 02/01/13 04:31
Diisopropyl ether ug/L ND 0.50 02/01/13 04:31
Ethylbenzene ug/L ND 0.50 02/01/13 04:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 40 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:915047
Associated Lab Samples:92146051005, 92146051006
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 02/01/13 04:31
Isopropylbenzene (Cumene)ug/L ND 0.50 02/01/13 04:31
m&p-Xylene ug/L ND 1.0 02/01/13 04:31
Methyl-tert-butyl ether ug/L ND 0.50 02/01/13 04:31
Methylene Chloride ug/L ND 2.0 02/01/13 04:31
n-Butylbenzene ug/L ND 0.50 02/01/13 04:31
n-Propylbenzene ug/L ND 0.50 02/01/13 04:31
Naphthalene ug/L ND 2.0 02/01/13 04:31
o-Xylene ug/L ND 0.50 02/01/13 04:31
p-Isopropyltoluene ug/L ND 0.50 02/01/13 04:31
sec-Butylbenzene ug/L ND 0.50 02/01/13 04:31
Styrene ug/L ND 0.50 02/01/13 04:31
tert-Butylbenzene ug/L ND 0.50 02/01/13 04:31
Tetrachloroethene ug/L ND 0.50 02/01/13 04:31
Toluene ug/L ND 0.50 02/01/13 04:31
trans-1,2-Dichloroethene ug/L ND 0.50 02/01/13 04:31
trans-1,3-Dichloropropene ug/L ND 0.50 02/01/13 04:31
Trichloroethene ug/L ND 0.50 02/01/13 04:31
Trichlorofluoromethane ug/L ND 1.0 02/01/13 04:31
Vinyl chloride ug/L ND 1.0 02/01/13 04:31
1,2-Dichloroethane-d4 (S)%124 70-130 02/01/13 04:31
4-Bromofluorobenzene (S)%93 70-130 02/01/13 04:31
Dibromofluoromethane (S)%103 70-130 02/01/13 04:31
Toluene-d8 (S)%101 70-130 02/01/13 04:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
915048LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.550 101 60-140
1,1,1-Trichloroethane ug/L 50.050 100 60-140
1,1,2,2-Tetrachloroethane ug/L 53.550 107 60-140
1,1,2-Trichloroethane ug/L 55.650 111 60-140
1,1-Dichloroethane ug/L 51.650 103 60-140
1,1-Dichloroethene ug/L 47.250 94 60-140
1,1-Dichloropropene ug/L 50.050 100 60-140
1,2,3-Trichlorobenzene ug/L 56.9 1g5011460-140
1,2,3-Trichloropropane ug/L 54.850 110 60-140
1,2,4-Trichlorobenzene ug/L 55.750 111 60-140
1,2,4-Trimethylbenzene ug/L 55.450 111 60-140
1,2-Dibromo-3-chloropropane ug/L 67.550 135 60-140
1,2-Dibromoethane (EDB)ug/L 53.250 106 60-140
1,2-Dichlorobenzene ug/L 53.550 107 60-140
1,2-Dichloroethane ug/L 53.250 106 60-140
1,2-Dichloropropane ug/L 51.350 103 60-140
1,3,5-Trimethylbenzene ug/L 55.550 111 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 41 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
915048LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 52.250 104 60-140
1,3-Dichloropropane ug/L 54.350 109 60-140
1,4-Dichlorobenzene ug/L 52.050 104 60-140
2,2-Dichloropropane ug/L 44.150 88 60-140
2-Chlorotoluene ug/L 55.250 110 60-140
2-Hexanone ug/L 144 L310014460-140
4-Chlorotoluene ug/L 56.050 112 60-140
4-Methyl-2-pentanone (MIBK)ug/L 140 CU10014060-140
Benzene ug/L 49.650 99 60-140
Bromobenzene ug/L 54.950 110 60-140
Bromochloromethane ug/L 49.650 99 60-140
Bromodichloromethane ug/L 54.750 109 60-140
Bromoform ug/L 56.550 113 60-140
Bromomethane ug/L 42.450 85 60-140
Carbon tetrachloride ug/L 50.150 100 60-140
Chlorobenzene ug/L 49.950 100 60-140
Chloroethane ug/L 53.950 108 60-140
Chloroform ug/L 51.050 102 60-140
Chloromethane ug/L 43.450 87 60-140
cis-1,2-Dichloroethene ug/L 51.050 102 60-140
cis-1,3-Dichloropropene ug/L 55.050 110 60-140
Dibromochloromethane ug/L 53.650 107 60-140
Dibromomethane ug/L 51.350 103 60-140
Dichlorodifluoromethane ug/L 41.9 CU,F3508460-140
Diisopropyl ether ug/L 57.550 115 60-140
Ethylbenzene ug/L 51.050 102 60-140
Hexachloro-1,3-butadiene ug/L 52.150 104 60-140
Isopropylbenzene (Cumene)ug/L 49.450 99 60-140
m&p-Xylene ug/L 105100 105 60-140
Methyl-tert-butyl ether ug/L 48.150 96 60-140
Methylene Chloride ug/L 51.950 104 60-140
n-Butylbenzene ug/L 55.950 112 60-140
n-Propylbenzene ug/L 54.150 108 60-140
Naphthalene ug/L 58.4 1g5011760-140
o-Xylene ug/L 51.150 102 60-140
p-Isopropyltoluene ug/L 56.750 113 60-140
sec-Butylbenzene ug/L 55.050 110 60-140
Styrene ug/L 54.750 109 60-140
tert-Butylbenzene ug/L 53.650 107 60-140
Tetrachloroethene ug/L 44.750 89 60-140
Toluene ug/L 49.050 98 60-140
trans-1,2-Dichloroethene ug/L 47.550 95 60-140
trans-1,3-Dichloropropene ug/L 57.950 116 60-140
Trichloroethene ug/L 47.150 94 60-140
Trichlorofluoromethane ug/L 47.750 95 60-140
Vinyl chloride ug/L 44.650 89 60-140
1,2-Dichloroethane-d4 (S)%112 70-130
4-Bromofluorobenzene (S)%94 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 42 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
915048LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromofluoromethane (S)%102 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 43 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/20581
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913383
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
1,2-Dibromoethane (EDB)ug/L ND 0.021 01/30/13 18:59
1-Chloro-2-bromopropane (S)%110 70-130 01/30/13 18:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913384LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
913385
1,2-Dibromoethane (EDB)ug/L 0.29.29 100 70-1301060.31 6 20
1-Chloro-2-bromopropane (S)%111 70-130110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
913386MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146052003
913387
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dibromoethane (EDB)ug/L .3 106 65-135106 0 20.3ND 0.32 0.32
1-Chloro-2-bromopropane (S)%108 70-130108
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92146052004
913388SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 20ND
1-Chloro-2-bromopropane (S)%105 0107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 44 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/20538
EPA 625
EPA 625
625 MSS
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:912007
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 01/30/13 01:10
2,4,6-Trichlorophenol ug/L ND 10.0 01/30/13 01:10
2,4-Dichlorophenol ug/L ND 5.0 01/30/13 01:10
2,4-Dimethylphenol ug/L ND 10.0 01/30/13 01:10
2,4-Dinitrophenol ug/L ND 50.0 01/30/13 01:10
2,4-Dinitrotoluene ug/L ND 5.0 01/30/13 01:10
2,6-Dinitrotoluene ug/L ND 5.0 01/30/13 01:10
2-Chloronaphthalene ug/L ND 5.0 01/30/13 01:10
2-Chlorophenol ug/L ND 5.0 01/30/13 01:10
2-Methylnaphthalene ug/L ND 5.0 01/30/13 01:10
2-Nitrophenol ug/L ND 5.0 01/30/13 01:10
3,3'-Dichlorobenzidine ug/L ND 25.0 01/30/13 01:10
4,6-Dinitro-2-methylphenol ug/L ND 20.0 01/30/13 01:10
4-Bromophenylphenyl ether ug/L ND 5.0 01/30/13 01:10
4-Chloro-3-methylphenol ug/L ND 5.0 01/30/13 01:10
4-Chlorophenylphenyl ether ug/L ND 5.0 01/30/13 01:10
4-Nitrophenol ug/L ND 50.0 01/30/13 01:10
Acenaphthene ug/L ND 5.0 01/30/13 01:10
Acenaphthylene ug/L ND 5.0 01/30/13 01:10
Anthracene ug/L ND 5.0 01/30/13 01:10
Benzo(a)anthracene ug/L ND 5.0 01/30/13 01:10
Benzo(a)pyrene ug/L ND 5.0 01/30/13 01:10
Benzo(b)fluoranthene ug/L ND 5.0 01/30/13 01:10
Benzo(g,h,i)perylene ug/L ND 5.0 01/30/13 01:10
Benzo(k)fluoranthene ug/L ND 5.0 01/30/13 01:10
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/30/13 01:10
bis(2-Chloroethyl) ether ug/L ND 5.0 01/30/13 01:10
bis(2-Chloroisopropyl) ether ug/L ND 5.0 01/30/13 01:10
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 01/30/13 01:10
Butylbenzylphthalate ug/L ND 5.0 01/30/13 01:10
Chrysene ug/L ND 5.0 01/30/13 01:10
Di-n-butylphthalate ug/L ND 5.0 01/30/13 01:10
Di-n-octylphthalate ug/L ND 5.0 01/30/13 01:10
Dibenz(a,h)anthracene ug/L ND 5.0 01/30/13 01:10
Diethylphthalate ug/L ND 5.0 01/30/13 01:10
Dimethylphthalate ug/L ND 5.0 01/30/13 01:10
Fluoranthene ug/L ND 5.0 01/30/13 01:10
Fluorene ug/L ND 5.0 01/30/13 01:10
Hexachloro-1,3-butadiene ug/L ND 5.0 01/30/13 01:10
Hexachlorobenzene ug/L ND 5.0 01/30/13 01:10
Hexachlorocyclopentadiene ug/L ND 10.0 01/30/13 01:10
Hexachloroethane ug/L ND 5.0 01/30/13 01:10
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 01/30/13 01:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 45 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:912007
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
Isophorone ug/L ND 10.0 01/30/13 01:10
N-Nitroso-di-n-propylamine ug/L ND 5.0 01/30/13 01:10
N-Nitrosodimethylamine ug/L ND 5.0 01/30/13 01:10
N-Nitrosodiphenylamine ug/L ND 10.0 01/30/13 01:10
Naphthalene ug/L ND 5.0 01/30/13 01:10
Nitrobenzene ug/L ND 5.0 01/30/13 01:10
Pentachlorophenol ug/L ND 25.0 01/30/13 01:10
Phenanthrene ug/L ND 5.0 01/30/13 01:10
Phenol ug/L ND 5.0 01/30/13 01:10
Pyrene ug/L ND 5.0 01/30/13 01:10
2,4,6-Tribromophenol (S)%27 10-137 01/30/13 01:10
2-Fluorobiphenyl (S)%21 15-120 01/30/13 01:10
2-Fluorophenol (S)%14 10-120 01/30/13 01:10
Nitrobenzene-d5 (S)%27 10-120 01/30/13 01:10
Phenol-d6 (S)%8 10-120 S001/30/13 01:10
Terphenyl-d14 (S)%33 11-131 01/30/13 01:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
912008LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 21.7 L2504344-142
2,4,6-Trichlorophenol ug/L 38.450 77 37-144
2,4-Dichlorophenol ug/L 36.150 72 1-191
2,4-Dimethylphenol ug/L 35.150 70 32-119
2,4-Dinitrophenol ug/L 178250 71 1-181
2,4-Dinitrotoluene ug/L 34.250 68 39-139
2,6-Dinitrotoluene ug/L 34.850 70 50-158
2-Chloronaphthalene ug/L 28.7 L2505760-118
2-Chlorophenol ug/L 34.850 70 23-134
2-Methylnaphthalene ug/L 27.150 54 25-150
2-Nitrophenol ug/L 39.550 79 29-182
3,3'-Dichlorobenzidine ug/L 87.1100 87 1-262
4,6-Dinitro-2-methylphenol ug/L 81.8100 82 1-181
4-Bromophenylphenyl ether ug/L 39.750 79 53-127
4-Chloro-3-methylphenol ug/L 78.1100 78 22-147
4-Chlorophenylphenyl ether ug/L 38.050 76 25-158
4-Nitrophenol ug/L 83.3250 33 1-132
Acenaphthene ug/L 35.150 70 47-145
Acenaphthylene ug/L 34.550 69 33-145
Anthracene ug/L 38.250 76 1-166
Benzo(a)anthracene ug/L 41.150 82 33-143
Benzo(a)pyrene ug/L 40.350 81 17-163
Benzo(b)fluoranthene ug/L 37.750 75 24-159
Benzo(g,h,i)perylene ug/L 40.850 82 1-219
Benzo(k)fluoranthene ug/L 35.350 71 11-162
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 46 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
912008LABORATORY CONTROL SAMPLE:
LCSSpike
bis(2-Chloroethoxy)methane ug/L 39.750 79 33-184
bis(2-Chloroethyl) ether ug/L 44.050 88 12-158
bis(2-Chloroisopropyl) ether ug/L 40.050 80 36-166
bis(2-Ethylhexyl)phthalate ug/L 39.450 79 8-158
Butylbenzylphthalate ug/L 38.750 77 1-152
Chrysene ug/L 37.850 76 17-168
Di-n-butylphthalate ug/L 35.350 71 1-118
Di-n-octylphthalate ug/L 45.950 92 4-146
Dibenz(a,h)anthracene ug/L 41.950 84 1-227
Diethylphthalate ug/L 34.350 69 1-114
Dimethylphthalate ug/L 34.350 69 1-112
Fluoranthene ug/L 42.050 84 26-137
Fluorene ug/L 37.550 75 59-121
Hexachloro-1,3-butadiene ug/L 18.950 38 24-116
Hexachlorobenzene ug/L 38.050 76 1-152
Hexachlorocyclopentadiene ug/L 20.650 41 25-150
Hexachloroethane ug/L 20.050 40 40-113
Indeno(1,2,3-cd)pyrene ug/L 41.950 84 1-171
Isophorone ug/L 34.150 68 21-196
N-Nitroso-di-n-propylamine ug/L 44.850 90 1-230
N-Nitrosodimethylamine ug/L 28.050 56 25-150
N-Nitrosodiphenylamine ug/L 36.750 73 25-150
Naphthalene ug/L 27.250 54 21-133
Nitrobenzene ug/L 32.050 64 35-180
Pentachlorophenol ug/L 79.0100 79 14-176
Phenanthrene ug/L 36.550 73 54-120
Phenol ug/L 17.950 36 5-112
Pyrene ug/L 39.050 78 52-115
2,4,6-Tribromophenol (S)%39 10-137
2-Fluorobiphenyl (S)%29 15-120
2-Fluorophenol (S)%20 10-120
Nitrobenzene-d5 (S)%34 10-120
Phenol-d6 (S)%13 10-120
Terphenyl-d14 (S)%34 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
912009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146011001
912010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 100 55 44-14266 17 30100ND55.4 66.0
2,4,6-Trichlorophenol ug/L 100 69 37-14489 25 30100ND69.2 88.6
2,4-Dichlorophenol ug/L 100 63 1-19178 20 30100ND63.5 77.7
2,4-Dimethylphenol ug/L 100 64 32-11979 21 30100ND63.9 78.5
2,4-Dinitrophenol ug/L R1500611-18193 42 30500ND303464
2,4-Dinitrotoluene ug/L R11006339-13986 31 30100ND62.8 85.9
2,6-Dinitrotoluene ug/L 100 63 50-15884 29 30100ND62.7 84.2
2-Chloronaphthalene ug/L 100 63 60-11878 21 30100ND63.1 78.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 47 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
912009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146011001
912010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorophenol ug/L 100 63 23-13477 20 30100ND62.7 76.8
2-Methylnaphthalene ug/L 100 63 25-15078 21 30100ND62.6 77.5
2-Nitrophenol ug/L 100 69 29-18281 16 30100ND69.3 81.2
3,3'-Dichlorobenzidine ug/L 200 66 1-26268 3 30200ND133136
4,6-Dinitro-2-methylphenol ug/L 200 72 1-18191 24 30200ND144183
4-Bromophenylphenyl ether ug/L 100 69 53-12788 24 30100ND69.0 88.2
4-Chloro-3-methylphenol ug/L R12007022-14795 31 30200ND140191
4-Chlorophenylphenyl ether ug/L 100 69 25-15890 26 30100ND69.0 90.0
4-Nitrophenol ug/L R1500421-13273 55 30500ND209366
Acenaphthene ug/L 100 69 47-14585 21 30100ND68.8 84.9
Acenaphthylene ug/L 100 68 33-14585 22 30100ND68.2 84.9
Anthracene ug/L 100 66 1-16686 27 30100ND66.1 86.4
Benzo(a)anthracene ug/L 100 71 33-14391 25 30100ND70.9 91.0
Benzo(a)pyrene ug/L 100 70 17-16391 26 30100ND70.2 91.2
Benzo(b)fluoranthene ug/L R11006424-15987 31 30100ND63.9 87.0
Benzo(g,h,i)perylene ug/L 100 74 1-21996 25 30100ND74.2 95.8
Benzo(k)fluoranthene ug/L 100 60 11-16281 30 30100ND60.1 80.9
bis(2-Chloroethoxy)methane ug/L 100 69 33-18483 18 30100ND68.8 82.7
bis(2-Chloroethyl) ether ug/L 100 77 12-15891 16 30100ND77.4 90.8
bis(2-Chloroisopropyl) ether ug/L 100 73 36-16686 17 30100ND72.6 85.9
bis(2-Ethylhexyl)phthalate ug/L 100 68 8-15890 28 30100ND68.2 90.2
Butylbenzylphthalate ug/L 100 67 1-15285 24 30100ND66.7 85.1
Chrysene ug/L 100 67 17-16887 26 30100ND66.8 86.9
Di-n-butylphthalate ug/L 100 63 1-11884 28 30100ND63.0 83.8
Di-n-octylphthalate ug/L 100 79 4-146106 28 30100ND79.4 106
Dibenz(a,h)anthracene ug/L 100 76 1-22797 25 30100ND75.6 97.3
Diethylphthalate ug/L 100 61 1-11483 30 30100ND61.4 83.1
Dimethylphthalate ug/L 100 61 1-11282 29 30100ND61.3 81.8
Fluoranthene ug/L 100 75 26-137100 29 30100ND74.7 99.8
Fluorene ug/L 100 69 59-12188 25 30100ND68.5 87.7
Hexachloro-1,3-butadiene ug/L 100 51 24-11662 19 30100ND51.3 62.0
Hexachlorobenzene ug/L 100 65 1-15284 26 30100ND64.7 83.7
Hexachlorocyclopentadiene ug/L 100 60 25-15073 18 30100ND60.4 72.6
Hexachloroethane ug/L 100 51 40-11357 11 30100ND51.1 57.1
Indeno(1,2,3-cd)pyrene ug/L 100 76 1-17198 26 30100ND76.1 98.4
Isophorone ug/L 100 60 21-19673 20 30100ND59.8 72.8
N-Nitroso-di-n-propylamine ug/L 100 78 1-23097 21 30100ND78.2 96.6
N-Nitrosodimethylamine ug/L 100 60 25-15073 19 30100ND60.2 72.7
N-Nitrosodiphenylamine ug/L 100 65 25-15079 19 30100ND65.1 78.6
Naphthalene ug/L 100 61 21-13372 17 30100ND61.0 72.1
Nitrobenzene ug/L 100 56 35-18066 17 30100ND56.0 66.5
Pentachlorophenol ug/L 200 72 14-17694 27 30200ND144189
Phenanthrene ug/L 100 64 54-12083 26 30100ND63.6 83.0
Phenol ug/L R1100395-11256 35 30100ND39.1 56.0
Pyrene ug/L 100 69 52-11588 25 30100ND68.5 87.8
2,4,6-Tribromophenol (S)%33 10-13746
2-Fluorobiphenyl (S)%26 15-12034
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 48 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
912009MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92146011001
912010
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Fluorophenol (S)%19 10-12026
Nitrobenzene-d5 (S)%28 10-12036
Phenol-d6 (S)%14 10-12023
Terphenyl-d14 (S)%23 11-13126
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 49 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92146051
Purgason's #19720
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/20569
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:913088
Associated Lab Samples:92146051001, 92146051002, 92146051003, 92146051004, 92146051005
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N202/03/13 12:05
Aliphatic (C19-C36)ug/L ND 100 N202/03/13 12:05
Aromatic (C11-C22)ug/L ND 100 N202/03/13 12:05
2-Bromonaphthalene (S)%93 40-140 02/03/13 12:05
2-Fluorobiphenyl (S)%86 40-140 02/03/13 12:05
Nonatriacontane (S)%93 40-140 02/03/13 12:05
o-Terphenyl (S)%75 40-140 02/03/13 12:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
913089LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
913090
Aliphatic (C09-C18)ug/L 167 N23005640-14064191 13 50
Aliphatic (C19-C36)ug/L 278 N24006940-14081325 16 50
Aromatic (C11-C22)ug/L 645 N28507640-14080681 5 50
2-Bromonaphthalene (S)%95 40-14093
2-Fluorobiphenyl (S)%94 40-14093
Nonatriacontane (S)%74 40-14086
o-Terphenyl (S)%72 40-14074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 50 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92146051
Purgason's #19720
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The end continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.1g
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.CU
The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.F3
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 51 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92146051
Purgason's #19720
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92146051001 OEXT/20581 GCSV/13841MW-1 EPA 504.1 EPA 504.1
92146051002 OEXT/20581 GCSV/13841MW-2 EPA 504.1 EPA 504.1
92146051003 OEXT/20581 GCSV/13841MW-3 EPA 504.1 EPA 504.1
92146051004 OEXT/20581 GCSV/13841MW-4 EPA 504.1 EPA 504.1
92146051005 OEXT/20581 GCSV/13841MW-5 EPA 504.1 EPA 504.1
92146051001 OEXT/20569 GCSV/13865MW-1 MADEP EPH MADEP EPH
92146051002 OEXT/20569 GCSV/13865MW-2 MADEP EPH MADEP EPH
92146051003 OEXT/20569 GCSV/13865MW-3 MADEP EPH MADEP EPH
92146051004 OEXT/20569 GCSV/13865MW-4 MADEP EPH MADEP EPH
92146051005 OEXT/20569 GCSV/13865MW-5 MADEP EPH MADEP EPH
92146051001 GCV/6594MW-1 MADEP VPH
92146051002 GCV/6594MW-2 MADEP VPH
92146051003 GCV/6594MW-3 MADEP VPH
92146051004 GCV/6594MW-4 MADEP VPH
92146051005 GCV/6594MW-5 MADEP VPH
92146051001 MPRP/12461 ICP/11378MW-1 SM 3030C EPA 200.7
92146051002 MPRP/12461 ICP/11378MW-2 SM 3030C EPA 200.7
92146051003 MPRP/12461 ICP/11378MW-3 SM 3030C EPA 200.7
92146051004 MPRP/12461 ICP/11378MW-4 SM 3030C EPA 200.7
92146051005 MPRP/12461 ICP/11378MW-5 SM 3030C EPA 200.7
92146051001 OEXT/20538 MSSV/7276MW-1 EPA 625 EPA 625
92146051002 OEXT/20538 MSSV/7276MW-2 EPA 625 EPA 625
92146051003 OEXT/20538 MSSV/7276MW-3 EPA 625 EPA 625
92146051004 OEXT/20538 MSSV/7276MW-4 EPA 625 EPA 625
92146051005 OEXT/20538 MSSV/7276MW-5 EPA 625 EPA 625
92146051001 MSV/21855MW-1 SM 6200B
92146051002 MSV/21855MW-2 SM 6200B
92146051003 MSV/21856MW-3 SM 6200B
92146051004 MSV/21856MW-4 SM 6200B
92146051005 MSV/21867MW-5 SM 6200B
92146051006 MSV/21867TRIP BLANK SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 02/05/2013 04:21 PM Page 52 of 52
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]