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HomeMy WebLinkAboutWS-6334_23926_CA_MRP_20230815 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 Telephone 919-871-0999 www.atcgroupservices.com August 15, 2023 Mr. Hassan Osman North Carolina Department of Environmental Quality Division of Waste Management – Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699 Subject: Free Product Recovery and Groundwater Monitoring Report Auddies #3 6071 Old NC Highway 49 Asheboro, Randolph County, North Carolina NCDEQ Incident No. 23926 ATC Project No.: SLC2392603 Dear Mr. Osman: ATC Associates of North Carolina, P.C. (ATC) is submitting the enclosed Free Product Recovery and Groundwater Monitoring Report for the Auddies #3 site. The report presents investigative procedures, field activities, and laboratory analytical results for a groundwater sampling event conducted in June and July 2023. If you have any questions or require additional information, please contact our office at (919) 871-0999. Sincerely, ATC Associates of North Carolina, P.C. Laura I. de Sousa Gabriel Araos, P.E. Staff Scientist Branch Manager Direct Line: (919) 948-3554 Direct Line: (919) 573-1205 Email: laura.deSousa@oneatlas.com Email: gabe.araos@oneatlas.com Attachments: 1. Groundwater Monitoring Report Prepared for: North Carolina Department of Environmental Quality Division of Waste Management – Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699 FREE PRODUCT RECOVERY AND GROUNDWATER MONITORING REPORT AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA ATC Project No. STL2392601 Prepared by: ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, North Carolina 27604 Telephone 919-871-0999 Laura I. de Sousa Staff Scientist Direct Line: (919) 948-3554 Email: laura.deSousa@oneatlas.com Gabriel Araos, P.E. Senior Project Manager Direct Line: 919-573-1205 Email: gabe.araos@oneatlas.com August 15, 2023 Auddies #3 August 15, 2023 Page 1 of 7 Table of Contents 1.0 SITE IDENTIFICATION .......................................................................................................................... 2 2.0 EXECUTIVE SUMMARY ........................................................................................................................ 3 3.0 SITE DESCRIPTION .............................................................................................................................. 3 3.1 SITE CHARACTERIZATION .................................................................................................................................... 3 3.2 SITE BACKGROUND ............................................................................................................................................ 4 4.1 MMPE EVENT ................................................................................................................................................. 6 5.0 GROUNDWATER ASSESSMENT ACTIVITIES .................................................................................. 6 5.1 GROUNDWATER LEVELS...................................................................................................................................... 6 5.2 GROUNDWATER QUALITY ................................................................................................................................... 6 6.0 CONCLUSIONS AND RECOMMENDATIONS .................................................................................... 7 TABLES: Table 1 – Water Supply Well Information Table 2 – Monitoring Well Construction and Groundwater Elevation Data Table 3 – Field Parameters Table 4 – Groundwater Analytical Results Table 5 – Historical Groundwater Analytical Results Table 6 – Water Supply Well Analytical Results FIGURES: Figure 1 – Topographic Map Figure 2 – Site Map Figure 3 – Water Supply Well Location Map Figure 4 – Groundwater Elevation Contour Map Figure 5 – Dissolved Benzene Isoconcentration Map Figure 6 – Additional Contaminants of Concern in Groundwater Map APPENDICES: Appendix A – Field Notes Appendix B – MMPE Report and Waste Disposal Manifests Appendix C – Laboratory Analytical Results Appendix D – Site Photographs Auddies #3 August 15, 2023 Page 3 of 7 ATC Project No. STL2392601 NCDEQ State Lead Program 2.0 EXECUTIVE SUMMARY ATC Associates of North Carolina, P.C. (ATC) has completed a mobile multi-phase extraction (MMPE) event and a groundwater monitoring event for the Auddies #3. This report documents activities conducted at the site in June and July 2023. The activities were performed based on a April 24, 2023 Task Authorization (TA-03) by the Trust Fund Branch of the Underground Storage Tank (UST) Section, Division of Waste Management, North Carolina Department of Environmental Quality (NCDEQ). The work is being performed as part of State Lead Contract #N70522-B between NCDEQ and ATC. The former Auddies #3 site is located at 6071 Old NC Highway 49, Asheboro, Randolph County, North Carolina. The Auddies #3 building, which is a former petroleum retail facility, is currently used by the Farmer Civitan Club for meetings and to store fund raising items. A residential structure, which is also occupied by the Farmer Civitan Club, adjoins the Auddies #3 building to the northeast. The former UST system consisted of one 4,000-gallon gasoline UST (T1), two 2,000-gallon gasoline USTs (T2 and T3), one 1,000-gallon diesel UST (T4), one 1,000-gallon kerosene UST (T5), one 1,050-gallon UST of unknown use (T6), and one 400-gallon unknown use UST (T7), which were closed either by removal or in place at the site. Five monitoring wells (MW-1A, MW-2, MW-3, MW-4, and MW-5) are associated with the site. One active water supply well (WSW-1) is also located on the property. Previous assessment activities at the site have identified fourteen active potable water supply wells located within 1,000 feet of the site. Municipal water is not available to the area. From June 5 to June 9, 2023, Eastern Environmental Management, LLC (Eastern) performed an MMPE event on wells MW-2, MW-4, and MW-5 and generated approximately 9,951 gallons of impacted groundwater and recovered 94.85 gallons of petroleum vapor. On July 7, 2023, ATC returned to the site to collected groundwater samples from MW-2, MW-4, and MW-5. The July 2023 sampling event indicated the local groundwater flows predominately in the northeasterly direction. The previous assessment conducted in April 2022 at the site indicated the local groundwater flows to the northeast. Light non-aqueous phase liquid (LNAPL) was not detected. Monitoring wells MW-2, MW-4, and MW-5 contained compounds exceeding the Title 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards). Additionally, MW-2 and MW-5 contained compounds that exceeded the Gross Contaminant Levels (GCLs). Based on the GCL exceedances in MW-2 and MW-5 and the presence of potable water supply wells within 1,000 feet of the site, ATC recommends reviewing alternative remedial technologies to reduce the GCLs in MW-2 and MW-5. If funding allows, ATC recommends the installation of additional monitoring wells to delineate the horizontal and vertical extent of the groundwater plume. 3.0 SITE DESCRIPTION 3.1 SITE CHARACTERIZATION The former Auddies #3 site is located at 6071 Old NC Highway 49, Asheboro, Randolph County, North Carolina. The Auddies #3 building, which is a former country store that previously sold gasoline, diesel fuel and kerosene, is currently used by the Farmer Civitan Club for meetings and to store fund raising items. A residential structure, which is also occupied by the Farmer Civitan Club, adjoins the Auddies #3 building to the northeast. The former UST system consisted of one 4,000-gallon gasoline UST (T1), two 2,000-gallon gasoline USTs (T2 and T3), one 1,000-gallon diesel UST (T4), one 1,000-gallon kerosene UST (T5), one 1,050-gallon UST of unknown use (T6), and one 400-gallon unknown use UST (T7), which were closed either by removal or in place at the site. Six Type II monitoring wells (WR-1, MW-1A, and MW-2 through MW-5) are located at the site. One additional monitoring well, WR-2, was previously installed at the site; however, WR-2 was abandoned at a depth of approximately 9 feet below ground surface (bgs). One active water supply well (WSW-1) is also located on the property. Auddies #3 August 15, 2023 Page 4 of 7 ATC Project No. STL2392601 NCDEQ State Lead Program The property is located in a rural residential and agricultural area of Randolph County. Adjacent properties to the east and west of the site are used for residential purposes. The north adjoining property is undeveloped. Two properties located to the south and across Dunbar Bridge Road from the site are occupied by Farmers United Methodist Church and C&M Ministries, Inc. A site topographic map is included as Figure 1. Previous assessment activities at the site have identified fourteen active potable water supply wells located within 1,000 feet of the site. Municipal water is not available to the area. Water supply well ownership information is included in Table 1 and a site map depicting monitoring well locations and other pertinent site features is included as Figure 2. A potential receptor map is included as Figure 3. 3.2 SITE BACKGROUND On December 22, 2001 Paragon Environmental Consultants, Inc. submitted a UST Closure Report documenting the closure by removal of five USTs (one 4,000-gallon gasoline UST [T1], two 2,000-gallon gasoline USTs [T2 and T3], one 1,000-gallon diesel UST [T4] and one 1,000-gallon kerosene UST [T5]). Total Petroleum Hydrocarbons (TPH) Gasoline Range Organics (GRO) were detected in soil samples collected during the removal of the tanks, which exceeded the North Carolina Action Level of 10 milligrams per kilograms (mg/kg). Soil samples collected beneath the product lines and dispenser were below the laboratory method detection limits. Approximately 222 tons of petroleum impacted soil was excavated during the removal of the tanks and disposed of offsite. Several target constituents were detected in soil samples collected after the removal of petroleum impacted soil at concentrations exceeding the Soil-to- Groundwater Maximum Soil Contaminant Concentrations (MSCCs). In December 2008, Withers & Ravenel completed a Phase I Limited Site Assessment (LSA) report for the site. Two monitoring wells (WR-1 and WR-2) were installed in the former UST basin (source) but both were reported as dry wells following installation. Soil samples collected during the installation of the monitoring wells identified several target constituents at concentrations exceeding the Soil-to-Groundwater MSCCs. Municipal water was not available to the area. Twenty-two water supply wells were identified within 1,500 feet of the site. The site was supplied with water from a water supply well (WSW-1) located in the crawl space of the attached residential structure. No surface water bodies were reported to be within 500 feet of the site. In February 2010, S&ME, Inc. (S&ME) conducted a groundwater monitoring event, which included the installation and sampling of monitoring well MW-1A and the sampling of the onsite water supply well (WSW- 1). The results of the monitoring event were summarized in a Well Installation and Monitoring Report dated March 15, 2010. Monitoring well MW-1A was installed within the former UST basin. Existing monitoring wells WR-1 and WR-2 were dry. WR-2 appeared to have been abandoned to a depth of 9.5 feet bgs. Two existing USTs (T6 and T7) were observed on the site by S&ME personnel. Tank T6 was observed near the southwest corner of the building adjacent to a concrete sidewalk. Tank 7, which appeared to be a heating oil tank, was observed at the northeast corner of the building. Several target constituents were detected in groundwater samples collected from MW-1A at concentrations exceeding the 2L Standards. Two target constituents (benzene and 1,2-dibromomethane) were detected at concentrations exceeding the GCLs. No target constituents were detected in the sample collected from WSW-1 at concentrations exceeding the laboratory method detection limits. In August 2010, S&ME sampled MW-1A and three water supply wells (WSW-6, WSW-7, and WSW-18). Benzene was detected in MW-1A at concentrations exceeding the GCL. No target constituents were detected in the samples collected from the sampled water supply wells. In December 2011, S&ME sampled MW-1A and three water supply wells (WSW-1, WSW-7, and WSW-18). S&ME personnel were informed that the properties located at 4722 Dunbar Bridge Road (WSW-3) and 4716 Dunbar Bridge Road (WSW-4) share a well. No target constituents were detected in the samples collected from the sampled water supply wells. Several target constituents were detected in MW-1A at concentrations exceeding the 2L Standards but below the GCLs. Auddies #3 August 15, 2023 Page 5 of 7 ATC Project No. STL2392601 NCDEQ State Lead Program In June and July 2012, S&ME conducted a groundwater monitoring event, which included the installation of monitoring wells MW-2, MW-3 and MW-4. Monitoring wells MW-2 and MW-3 were installed downgradient of the former UST basin. Monitoring well MW-4 was installed next to existing tank T6 located near the southwest corner of the building. Soil boring B-1 was advanced next to Tank T6 during the installation of monitoring well MW-4. TPH-GRO was detected in the soil sample collected from B-1 at a depth of approximately 18 feet bgs at a concentration of 12 mg/kg. Groundwater samples were not collected from MW-4. Three target constituents (1,2-dibromoethane, benzene and total chromium) were detected at concentrations exceeding the Soil-to-Groundwater MSCCs at B-1. Benzene and 1,2-dibromoethane were detected in MW-2 at concentrations exceeding the GCLs. Groundwater was reported to flow to the northwest. In July 2015, S&ME conducted a monitoring event at the site. Groundwater samples were collected from monitoring wells MW-1A through MW-4, as well as water supply wells WSW-1, WSW-6, WSW-7, and WSW-18. WR-1 and WR-2 were each dry during the sampling event. Several petroleum constituents were identified in MW-1A through MW-4. Benzene concentrations in MW-1A, MW-2, and MW-4 exceeded the GCLs. 1,2-Dibromoethane concentrations in MW-2 also exceeded the GCL. No constituents were detected in the water supply well samples. In July 2018, S&ME conducted a monitoring event at the site. Groundwater samples were collected from monitoring wells MW-2, MW-3, and MW-4, as well as water supply wells WSW-1, WSW-6, WSW-7, and WSW-18. Benzene concentrations in MW-2 and MW-4 exceeded the GCL. No constituents, with the exception of chloroform, were detected in the water supply well samples. In August 2018, S&ME performed a limited geophysical survey at the site to mark the locations of tank T-6 and the suspected second UST (T-7). An Initial Abatement Action report, dated June 10, 2019, documented the closure by removal of T-6 in April 2019. During the excavation activities, T-7 was found to have been previously closed-in-place, and was not removed. Approximately 101 tons of petroleum impacted soils were excavated and transported offsite for disposal. Four soil samples were collected from the sidewalls of the excavated area following the abatement activities. Petroleum constituents were detected in all four samples exceeding the Residential MSCCs. Additionally, concentrations exceeded the Industrial/Commercial MSCCs in the sample collected adjacent to T-7. On January 10, 2020, S&ME submitted a Corrective Action Performance/Monitoring Report documenting the installation of monitoring well MW-5 and subsequent sampling event. Two soil samples were collected during the installation of MW-5 (MW-5 - 7.5 and MW-5 - 20). Petroleum constituent concentrations in both samples exceeded the Soil-to-Groundwater MSCCs, while concentrations in MW-5 – 7.5 also exceeded Residential MSCCs. Groundwater samples were collected from monitoring MW-2, MW-4, and MW-5, as well as water supply wells WSW-1, WSW-5, WSW-6, and WSW-7. Constituent concentrations were detected in monitoring wells MW-2 and MW-5 exceeding the GCLs. No constituents, with the exception of chloroform, were detected in the water supply well samples exceeding the method detection limits. On March 2, 2021, ATC submitted a Groundwater Monitoring Report documenting a sampling event, which occurred in February 2021. Groundwater samples were collected from monitoring MW-1A, MW-4, and MW- 5, as well as water supply wells WSW-1. Constituent concentrations were detected in monitoring well MW- 5 exceeding the GCLs. No constituents were detected in WSW-1 exceeding the method detection limits. On November 9, 2021, ATC submitted a Groundwater Monitoring Report documenting a sampling event, which occurred in September 2021. Groundwater samples were collected from monitoring MW-1A, MW-2, MW-3, MW-4, and MW-5. Constituent concentrations were detected in monitoring wells MW-2 and MW-5 exceeding the GCLs. On May 16, 2022, ATC submitted a Groundwater Monitoring Report documenting a sampling event, which occurred in March 2022. Groundwater samples were collected from monitoring MW-2, MW-4, and MW-5. Constituent concentrations were detected in monitoring wells MW-2 and MW-5 exceeding the GCLs. . Auddies #3 August 15, 2023 Page 6 of 7 ATC Project No. STL2392601 NCDEQ State Lead Program 4.0 MMPE ACTIVITIES 4.1 MMPE EVENT Eastern was subcontracted to perform a MMPE event from June 5 to June 9, 2023. Monitoring wells MW- 2, MW-4, and MW-5 were used as the extraction points for the event. The event was conducted to reduce groundwater contaminant concentrations. Prior to the event, wells MW-2, MW-4, and MW-5 were gauged to record the groundwater elevation. Light non-aqueous phase liquid (LNAPL) was not detected in any of the monitoring wells. Monitoring well construction details and groundwater elevation data are included as Table 2. Prior to the start of the event, the intake for the vacuum piping was set approximately 2 feet below the top of the water column in the extraction wells and was adjusted throughout the event to maximize volume recovery. The MMPE event was initiated at 10:00 a.m. on June 5, 2023. The event was concluded at 10:00 a.m. on June 9, 2023. A tanker change out was required on June 7, 2023. During that time, groundwater samples were collected from monitoring wells MW-2, MW-4, and MW- 5. Samples were collected in laboratory-approved containers, packed in ice and delivered under chain of custody protocol to Pace Analytical in Mount Juliet, Tennessee for analyses. Groundwater samples were analyzed for VOCs by Environmental Protection Agency (EPA) Method 602. Approximately 9,951 gallons of impacted groundwater and 94.85 gallons of petroleum vapor were recovered during the event. Field notes are included as Appendix A. During the event, vacuum at the recovery pump stabilized at approximately 25.0 inches of mercury. Airflow rates ranged from 289 to 411 feet per minute. System temperature ranged from 67 to 114 degrees Fahrenheit and humidity maintained 100 percent. Field gauged VOCs decreased from 6,040 parts per million (ppm) to 1,171 ppm throughout the event. The MMPE report and waste disposal manifests are included as Appendix B. The laboratory analytical report and chain-of- custody forms are included in Appendix C. 5.0 GROUNDWATER ASSESSMENT ACTIVITIES 5.1 GROUNDWATER LEVELS On July 7, 2023, groundwater level measurements and samples were collected from monitoring wells MW- 2, MW-4, and MW-5. LNAPL was not observed in the monitoring wells. Depth to groundwater measurements ranged from 41.48 feet bgs in MW-2 to 42.68 feet bgs in MW-4. Monitoring well construction details and groundwater elevation data are summarized in Table 2. Field parameter data including temperature, dissolved oxygen, conductivity, pH, and oxygen reduction potential were recorded during the sampling event and are included in Table 3. Field notes from the sampling event are included in Appendix A. Photographs of the monitoring well locations are included in Appendix D. A Groundwater Elevation Contour Map is included as Table 4. 5.2 GROUNDWATER QUALITY On July 7, 2023, groundwater samples were collected from monitoring wells MW-2, MW-4, and MW-5. Samples were collected in laboratory-approved containers, packed in ice and delivered under chain of custody protocol to to Pace Analytical in Mount Juliet, Tennessee for analyses. Groundwater samples were analyzed for VOCs by Environmental Protection Agency (EPA) Method 602. Analytical results indicated toluene (1,800 µg/L), ethylbenzene (1,320 µg/L), total xylenes (4,540 µg/L), MTBE (3,230 µg/L), diisopropyl ether (262 µg/L), isopropylbenzene (74.2 J µg/L), n-propylbenzene (162 µg/L), 1,2,4-trimethylbenzene (1,120 µg/L), and naphthalene (425 µg/L) were detected above the 2L Auddies #3 August 15, 2023 Page 7 of 7 ATC Project No. STL2392601 NCDEQ State Lead Program Standard in MW-2. Benzene (921 µg/L), MTBE (4,280 µg/L), diisopropyl ether (730 µg/L), naphthalene (50.5 µg/L), and 1,2- dichloroethane (187 µg/L) were detected above the 2L Standard in MW-4. Toluene (1,850 µg/L), ethylbenzene (1,300 µg/L), total xylenes (3,680 µg/L), MTBE (15,000 µg/L), diisopropyl ether (991 µg/L), p-isopropyltoluene (37.6 J µg/L), naphthalene (405 µg/L), n-propylbenzene (133 µg/L), 1,2,4- trimethylbenzene (841 µg/L), and 4-methyl-2-petanone (233 µg/L) were detected above the 2L Standard in MW-5. Benzene (12,100 µg/L) and 1,2-dichloroethane (439 µg/L) exceeded the GCLs in MW-2. Benzene (20,600 µg/L) and 1,2-dichloroethane (667 µg/L) exceeded the GCLs in MW-5. Current monitoring well groundwater analytical data is summarized in Table 4. Historical monitoring well groundwater analytical data is summarized in Table 5. Historical water supply well analytical data is summarized in Table 6. A Dissolved Benzene Isoconcentration Map is included as Figure 5, and Additional Conaminants of Concern in Groundwater are shown on Figure 6. A comparison of the analytical results from the current sampling event (July 2023) to the previous sampling event (April 2022) for each well indicated an increase in petroleum constituent concentrations in MW-2 and MW-5. There is a decrease in petroleum constituent concentrations in MW-4. The laboratory analytical report and chain-of-custody forms are included in Appendix C. As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the laboratory report was conducted. During the review, it was concluded that samples were received by the laboratory in acceptable condition and properly preserved. Samples were analyzed within the correct holding times, and the chain of custody was properly completed by all parties. The laboratory QC report shows an internal blank was analyzed for each method that was used for the original samples. The laboratory fortified blank (LFB) and laboratory control sample (LCS) data results were also provided for each analytical method. Refer to the laboratory report in Appendix C for details regarding QA results for the laboratory samples and any noted exceptions. Overall, ATC concludes that the laboratory results are usable and any exceptions do not significantly impact the conclusions presented in this report. 6.0 CONCLUSIONS AND RECOMMENDATIONS On behalf of the Trust Fund Branch of the UST Section, ATC completed a MMPE and groundwater monitoring event for the Auddies #3 site located at 6071 Old NC Highway 49, Asheboro, Randolph County, North Carolina. Groundwater samples were collected from monitoring wells MW-2, MW-4, and MW-5. An MMPE event performed from June 5 to June 9, 2023, generated approximately 9,951 gallons of impacted groundwater and recovered 94.85 gallons of petroleum vapor. Monitoring wells MW-2, MW-4, and MW-5 were used as the extraction points for the event. The July 2023 sampling event indicated the local groundwater flows predominately in the southeasterly direction. LNAPL was not detected in the gauged monitoring wells. Monitoring wells MW-2, MW4, and MW- 5 contained compounds exceeding the 2L Standards. Additionally, MW-2 and MW-5 contained compounds exceeded the GCLs. A comparison of the analytical results from the current sampling event (July 2023) to the previous sampling event (April 2022) for each well indicated an increase in petroleum constituent concentrations in MW-2 and MW-5. There is a decrease in petroleum constituent concentrations in MW-4. It doesn’t appear that the MMPE events have been effective in the GCL reduction at the site. Based on the GCL exceedances in MW-2 and MW-5 and the presence of potable water supply wells within 1,000 feet of the site, ATC recommends reviewing alternative remedial technologies to reduce the GCLs in MW-2 and MW-5. If funding allows, ATC recommends the installation of additional monitoring wells to delineate the horizontal and vertical extent of the groundwater plume. Auddies #3 TABLES TABLE 1 WATER SUPPLY WELL INFORMATION AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 Well ID Property Owner Well Address Property Owner's Address PIN ID#Well Use Distance from Source Area (ft.) Comments WSW-1 (Site) Farmer Civitan Club, Inc. (336-465-1470) 6071 Old NC Highway 49 Asheboro, NC 27205 4297 Harris Family Lane Asheboro, NC 27205 7609949108 Active-Potable 50 SE Well is located in crawl space of onsite adjoining residential structure. WSW-2 Candace Wells Hammond William Heafner (336-629-2600) Triad Rental Properties (336-626-7235) 4730 Dunbar Bridge Rd Asheboro, NC 27205 6056 Old Highway 49 Asheboro, NC 27205 7619040038 Active-Potable 210 SE Nearest residential property to the east. Owner is out of the country, contact William Heafner for access. 113 Worth St, Asheboro, NC 27203 WSW-3 Leann L. Smith (336-241-5251) 4722 Dunbar Bridge Rd Asheboro, NC 27205 4220 River Bluff Drive Denton, NC 27239 7619042105 Inactive 300 SE Property at WSW-3 is connected to WSW-4 WSW-4 Lawson Dempsey Lowe (336-857-2872) 4716 Dunbar Bridge Rd Asheboro, NC 27205 4638 Dunbar Bridge Rd Asheboro, NC 27205 7619042087 Active-Potable 380 SE Property at WSW-3 is connected to WSW-4 WSW-5 Farmer United Methodist Church 6127 Old NC Hwy 49 Denton, NC 27239 2473 Falling Oak Rd Asheboro, NC 27205 7609934882 Active-Potable 450 SW Property located southwest of the site. WSW-6 Mary K. Walker 4637 Farmer Denton Rd Denton, NC 27239 4740 Old Winston Rd Kernersville, NC 27284 7609941110 Active-Potable 460 W Property is adjacent to site to the west WSW-7 Wilford Hammond 4612 Farmer Denton Rd Denton, NC 27239 4612 Farmer Denton Rd Denton, NC 27239 7609946692 Active-Potable 330 NW Property is adjacent to site to the northwest WSW-8 Candace Hammond William Heafner (336-629-2600) 6054 Old Highway 49 Asheboro, NC 27205 6056 Old Highway 49 Asheboro, NC 27205 7619057861 Active-Potable 220 N Property is adjacent to site to the north-northwest. Owner is out of the country, contact William Heafner for access. 113 Worth St, Asheboro, NC 27203 WSW-9 Lawson Dempsey Lowe 4626 Dunbar Bridge Rd Asheboro, NC 27205 4638 Dunbar Bridge Rd Asheboro, NC 27205 7619034977 Active-Potable 550 SE WSW-10 Amy Nelson Owens 4582 Dunbar Bridge Rd Asheboro, NC 27205 4598 Dunbar Bridge Rd Asheboro, NC 27205 7619039913 Active-Potable 860 SE WSW-14 Rodney C Hall 3129 Grange Hall Rd Asheboro, NC 27205 3129 Grange Hall Rd Asheboro, NC 27205 7619033661 Active-Potable 610 SE WSW-15 Carolyn Wilson 3137 Grange Hall Rd Asheboro, NC 27205 3137 Grange Hall Rd Asheboro, NC 27205 7619033318 Active-Potable 880 SE WSW-18 Love of God Baptist Church (336-475-1031) 4751 Dunbar Bridge Rd Asheboro, NC 27205 5606 S. NC Highway 109 Thomasville, NC 27205 7609936350 Active-Potable 440 S Property is adjacent to site to the south. WSW-21 Michael Blackwelder 5976 Old NC Highway 49 Asheboro, NC 27205 5976 Old NC Highway 49 Asheboro, NC 27205 7619044882 Active-Potable 920 NE WSW-22 Ritchie & Kimberly Hogan 5961 Old Highway 49 Asheboro, NC 27205 5961 Old Highway 49 Asheboro, NC 27205 7619141569 Active-Potable 760 NE Notes: 1. Only water supply wells located within 1,000 feet of the site are included. 2. The owner of WSW-2 and WSW-8 (Candace Hammond) is out of the country. Contact William Heafner for access. 3. Residence at WSW-2 is a rental property. Contact Triad Rental Properties at least 24 hrs prior to WSW sampling. TABLE 2 MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 Well ID Date Installed Date Water Level Measured Well Casing Diameter (inches) Well Casing Depth (ft bgs) Screen Interval (ft bgs) Total Depth (ft bgs) Top of Casing Elevation (feet) Depth to Water from Top of Casing (ft bgs) Groundwater Elevation (feet) Comments 9/10/2008 Dry NS 9/22/2008 Dry NS 10/3/2008 Dry NS 2/8/2010 Dry NS 8/26/2010 Dry NS 12/19/2011 Dry NS 7/5/2012 Dry NS 7/22/2015 Dry NS 2/2/2021 NM NS Could not locate 9/24/2021 37.76 NS 10/3/2008 Dry NS 2/8/2010 Dry NS 8/26/2010 Dry NS 12/19/2011 Dry NS 7/5/2012 Dry NS 7/22/2015 Dry NS 2/2/2021 NM NS Could not locate 9/24/2021 Dry NS Obstruction at 9 ft bgs. 2/8/2010 49.91 48.46 8/26/2010 49.03 49.34 12/19/2011 56.65 41.72 7/5/2012 54.25 44.12 7/22/2015 48.41 49.96 2/2/2021 NM NM Could not locate 9/24/2021 39.02 59.35 7/5/2012 58.80 40.00 7/22/2015 48.87 49.93 7/2/2018 46.79 52.01 12/4/2019 44.75 54.05 2/2/2021 35.71 63.09 9/24/2021 39.42 59.38 3/14/2022 40.04 58.76 3/18/2022 (Post-MMPE)42.16 56.64 4/18/2022 38.44 60.36 6/5/2023 40.50 58.30 6/9/2023 (Post-MMPE)43.32 55.48 7/7/2023 41.48 57.32 7/5/2012 53.60 43.71 7/22/2015 47.68 49.63 7/2/2018 45.59 51.72 12/4/2019 43.61 53.70 2/2/2021 NM NM Could not locate 9/24/2021 38.16 59.15 7/5/2012 55.85 44.15 7/22/2015 50.60 49.40 7/2/2018 47.99 52.01 12/4/2019 45.99 54.01 2/2/2021 37.31 62.69 9/24/2021 40.63 59.37 3/14/2022 41.24 58.76 3/18/2022 (Post-MMPE)42.31 57.69 4/18/2022 39.54 60.46 6/5/2023 41.68 58.32 6/9/2023 (Post-MMPE)44.10 55.90 7/7/2023 42.68 57.32 12/4/2019 45.28 54.26 2/2/2021 36.77 62.77 9/24/2021 40.05 59.49 3/14/2022 40.68 58.86 3/18/2022 (Post-MMPE)36.52 63.02 4/18/2022 39.07 60.47 6/5/2023 41.14 58.40 6/9/2023 (Post-MMPE)45.81 53.73 7/7/2023 42.13 57.41 Notes: 5. NS = Not Surveyed. 6. MMPE = Mobile Multi-Phase Extraction. 35.30 - 55.30 55.5 99.54 MW-4 6/25/2012 2 Unknown Unknown 60 6/25/2012 2 44 44 - 59 100.00 MW-2 6/25/2012 2 47 47 - 62 WR-2 appears to be abandoned to a depth of approximately 9 ft bgs. 98.37 59 97.31 Unknown Unknown 51.5 62 Unknown 43 WR-2 1. TOC = Top of casing. 2/3/2010 2 42 42 - 62 62 MW-3 NS NS MW-1A 10/3/2008 2 98.8 WR-1 9/10/2008 2 Unknown MW-5 11/13/2019 2 4. NM = Not Measured. 2. Monitoring well MW-4 is the site benchmark at 100.00 feet. 3. ft bgs = Feet below ground level. 35.30 TABLE 3 FIELD PARAMETERS AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 MW-1A 9/24/2021 21.9 1.23 213.8 5.81 113.5 2/2/2021 9/24/2021 4/18/2022 7/7/2023 MW-3 9/24/2021 21.5 1.61 229.6 6.19 80.4 2/2/2021 16.9 0.85 657 6.50 -30.9 9/24/2021 19.8 2.21 594 6.50 -30.5 4/18/2022 17.7 1.29 605 6.31 27.6 7/7/2023 23.4 2.60 610 8.12 -93.0 2/2/2021 9/24/2021 21.5 1.98 661 6.57 -24.2 4/18/2022 7/7/2023 Notes: 1. oC = Degrees Celsius. 2. mg/L = milligrams per liter. 3. µs/cm = micro Siemens per centimeter. 4. SU = Standard Units. 5. ORP = Oxidation Reduction Potential. 6. mV = Millivolts. Stong Odor, No Field Readings Sheen, Stong Odor, No Field Readings Sheen, Stong Odor, No Field Readings Stong Odor, No Field Readings Stong Odor, No Field ReadingsMW-2 MW-4 MW-5 Sheen, Stong Odor, No Field Readings Sheen, Stong Odor, No Field ReadingsTemperature (oC)Dissolved Oxygen (mg/L)Conductivity (us/cm)pH (SU)ORP (mV)WELL ID Date Collected TABLE 4 GROUNDWATER ANALYTICAL RESULTS AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 WELL ID Date Collected BenzeneTolueneEthylbenzeneXylenes (total)Methyl Tert-Butyl EtherNaphthalenen-Butylbenzenesec-Butylbenzene1,2-DichloroethaneDi-isopropyl etherIsopropylbenzenep-Isopropyltoluene2-Butanone (MEK)4-Methyl-2-Pentanone (MIBK)n-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneMW-2 07/07/23 12,100 1,800 1,320 4,540 3,230 425 24.0 J 10.1 J 439 262 74.2 9.93 J <500 <500 162 21.5 J 1,120 357 MW-4 07/07/23 921 176 92.5 129.7 J 4,280 50.5 J <50.0 <50.0 187 730 54.8 17.9 J <500 69.6 J 9.24 J <50.0 36.7 J 24.7 J MW-5 07/07/23 20,600 1,850 1,300 3,680 15,000 405 21.4 J 9.44 J 667 991 62.1 37.6 J 760 233 J 133 <50.0 841 302 1 600 600 500 20 6 70 70 0.4 70 70 25 4,000 100 70 70 400 400 5,000 260,000 80,000 50,000 20,000 6,000 5,900 8,800 400 70,000 30,500 11,700 4,000,000 100,000 26,100 70,000 28,500 24,100 Notes: 1. "<" or ND = Not detected at or above the laboratory reporting limit or method detection limit. 2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb). 3. Concentrations in BOLD equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard). 4. GCL = Gross Contamination Level. 5. Concentrations in ITALICS equal or exceed the corresponding GCL. 6. J = Indicates constituent was detected above laboratory detection limit but below laboratory reporting limit. 2L Standard GCL ANALYTICAL METHOD Volitile Organic Compounds by EPA Method 6200B TABLE 5 HISTORICAL GROUNDWATER ANALYTICAL RESULTS AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 WELL ID Date Collected BenzeneTolueneEthylbenzeneXylenes (total)Acetone2-Butanone (MEK)2-Hexanone (MBK)ChloroformMethyl Tert Butyl Ethern-Butylbenzenesec-ButylbenzeneMethylene chlorideDiisopropyl etherIsopropylbenzeneStyreneNaphthalenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenep-Isopropyltoluene1,2-Dichloropropane1,2-Dichloroethane1,2-Dibromoethane (Ethylene Dibromide)C5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics02/08/10 5,400 370 560 4,000 ND ND ND ND 940 17 11 NA 41 70 ND 340 130 1,100 430 17 ND 130 57 21,000 5,400 4,900 08/26/10 10,000 700 970 5,800 68 ND ND ND 1,500 ND ND NA 82 ND 68 270 130 890 290 ND ND 280 <50 NA NA NA 12/19/11 3,200 140 370 2,700 380 J ND ND ND 1,300 140 75 ND 62 140 ND 420 270 2,100 860 83 NA 130 <20 NA NA NA 07/05/12 1,800 150 240 3,200 ND ND ND ND 160 110 27 NA 11 91 12 270 200 1,500 610 34 NA 16.0 <0.5 NA NA NA 07/22/15 5,210 441 557 3,065 NA ND ND ND 741 <25 <25 108 234 61.7 <25 230 116 921 338 NA <25 193 33.8 NA NA NA 2/2/2021*1,430 205 153 694 <200 <500 <20 <10 546 <10 <10 <10 120 21.1 <10 78.3 26.4 210 68.3 <10 <6.0 47.6 <10 NA NA NA 09/24/21 647 22.7 24.3 157 21.6 J <250 <10 <5.0 65.1 10.3 <5.0 2.0 J 5.5 16.2 1.7 J 92.2 19.3 142 60.7 4.9 J <3.0 6.5 <5.0 NA NA NA 07/05/12 10,000 490 470 2,500 100 ND ND ND 24 ND ND NA 110 ND 12 ND ND 320 110 ND NA 370 130 NA NA NA 07/22/15 7,750 727 776 3,950 NA ND ND ND 1,640 <5 <5 21.1 73.3 37 10.3 259 70.8 686 238 NA <5 260 76.6 NA NA NA 07/02/18 8,100 6,700 2,500 12,400 <5,000 450 J ND 22 J 660 67 33 J <500 63 160 31 J 820 350 2,900 850 26 J <50 <100 41 J NA NA NA 12/04/19 8,600 5,200 1,800 8,900 <5,000 <500 <500 <50 4,600 34 J 20 J <500 220 120 33 J 720 260 1,700 680 <50 <50 600 170 1 NA NA NA 2/2/2021* 09/24/21 9,680 2,710 1,570 7,070 <2,000 <5,000 <200 <100 4,770 40.4 J <100 <100 165 92.3 J <100 812 238 2,110 622 <100 <60 449 <100 NA NA NA 04/18/22 9,330 2,260 1,050 5,800 <2,000 <5,000 <200 <100 3,780 <100 <100 101 194 70.1 J <100 458 158 1,300 413 <100 <60 374 122 NA NA NA 07/07/23 12,100 1,800 1,320 4,540 <2,500 <500 NA <250 3,230 24.0 J 10.1 J <250 262 74.2 21.5 J 425 162 1,120 357 9.93 J <50.0 439 <50.0 NA NA NA 07/05/12 0.56 ND ND 0.70 J ND ND ND ND 3.5 ND ND NA ND ND ND ND ND ND ND ND NA 3.2 <0.5 NA NA NA 07/22/15 4.6 <0.5 <0.5 <1.5 NA ND ND ND 4.5 <0.5 <0.5 <2 0.66 <0.5 <0.5 <2 <0.5 <0.5 <0.5 NA <0.5 0.7 <0.5 NA NA NA 07/02/18 7.4 <0.50 <0.50 0.23 J <50 <5.0 ND <0.50 31 <0.50 <0.50 <5.0 6.1 0.20 J <0.50 <0.50 <0.50 0.19 J <0.50 <0.50 <0.50 3.6 <0.50 NA NA NA 02/02/21 09/24/21 211 5.6 18.4 10.6 6.8 J <130 <5.0 <2.5 384 <2.5 <2.5 1.1 J 54.5 3.1 <2.5 16.7 3.5 5.2 3.4 <2.5 <1.5 29.9 <2.5 NA NA NA 07/22/15 6,670 90.3 111 725 NA ND ND ND 1,550 <10 <10 46.8 1,060 20 <10 291 18.4 228 102 NA 10.9 326 <10 NA NA NA 07/02/18 7,600 51 220 380 <5,000 <500 ND <50 4,800 <50 <50 <500 1,100 38 J <50 640 28 J 260 110 <50 <50 300 <50 NA NA NA 12/04/19 950 12 39 31 J <1,200 <120 <120 12 2,000 <12 <12 <120 410 16 <12 120 J 6.5 J 7.2 J 11 J 9.5 J <12 120 0.042 NA NA NA 02/02/21 821 <25 75.2 61.7 <500 <1,300 <50 <25 4,400 <25 <25 <25 573 49.6 <25 55.9 <25 36.4 <25 <25 <15 137 <25 NA NA NA 09/24/21 1,290 120 137 121 67.6 J <500 138 <10 5,800 E <10 <10 15.2 758 47.6 <10 117 14.9 80.3 47.3 25.1 5.8 J 198 <10 NA NA NA 04/18/22 1,290 149 132 147 <1,000 <2,500 <100 <50 6,520 <50 <50 55.6 809 95.2 <50 113 <50 81.0 45.1 J 27.5 J <30 303 <50 NA NA NA 07/07/23 921 176 92.5 129.7 J <2,500 <500 NA <250 4,280 <50.0 <50.0 <250 730 54.8 <50.0 50.5 J 9.24 J 36.7 J 24.7 J 17.9 J <50.0 187 <50.0 NA NA NA 12/04/19 9,800 4,000 990 6,500 19,000 4,500 860 J <120 2,200 <120 <120 <1200 910 90 J <120 <1,200 180 1,200 500 <120 <120 550 18 45,000 <4,000 6,900 02/02/21 23,600 23,900 1,720 9,620 <2,000 <5,000 <200 <100 17,200 <100 <100 <100 1,360 <100 <100 582 146 1,280 345 <100 <60 609 236 NA NA NA 09/24/21 16,700 11,900 1,200 5,830 <2,000 <5,000 <200 <100 14,900 <100 <100 55.1 J 755 41.4 J <100 490 102 940 239 <100 <60 522 179 NA NA NA 04/18/22 16,700 16,400 1,240 6,710 <2,000 <5,000 270 <100 11,800 <100 <100 103 1,210 49.4 J <100 390 106 907 269 34.4 J <60 550 185 NA NA NA 07/07/23 20,600 1,850 1,300 3,680 <2,500 760 NA <250 15,000 21.4 J 9.44 J <250 991 62.1 <50.0 405 133 841 302 37.6 J <50.0 667 <50.0 NA NA NA 1 600 600 500 6,000 4,000 40 70 20 70 70 400 70 70 70 6 70 400 400 25 0.6 0.4 0.02 400 700 200 5,000 260,000 80,000 50,000 6,000,000 4,000,000 40,000 70,000 20,000 5,900 8,800 400,000 70,000 30,500 70,000 6,000 26,100 28,500 24,100 11,700 600 400 50 NE NE NE Notes: 1. "<" or ND = Not detected at or above the laboratory reporting limit or method detection limit. 2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb). 3. Concentrations in BOLD equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard). 4. GCL = Gross Contamination Level. 5. Concentrations in ITALICS equal or exceed the corresponding GCL. 6. NE = Not established. 7. J = Indicates constituent was detected above laboratory detection limit but below laboratory reporting limit. 8. NA = Not Analyzed or original lab report not provided. 9. E = Value exceeds calibration range. 10. 1 = Analyzed by Method 504.1. 11. * = Sample labels were switched during sampling event. Therefore, labels do not match actual sample location. 2L Standard GCL ANALYTICAL METHOD MW-4 MW-5 MADEP-VPHVolitile Organic Compounds by EPA Method 6200B MW-1A MW-3 Not Sampled, Could Not Locate Not Sampled, Could Not Locate MW-2 TABLE 6 WATER SUPPLY WELL ANALYTICAL RESULTS AUDDIES #3 6071 OLD NC HIGHWAY 49 ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA NCDEQ INCIDENT #23926 WELL ID Date Collected BenzeneTolueneEthylbenzeneXylenes (total)Chloroform02/08/10 ND ND ND ND ND 12/19/11 ND ND ND ND ND 07/22/15 <0.5 <0.5 <0.5 <1.5 ND 07/02/18 <0.50 <0.50 <0.50 <1.50 0.34 J 02/02/21 <0.50 <0.50 <0.50 <0.50 <0.50 09/24/21 WSW-5 (6127 Old NC Hwy 49)12/04/19 <0.50 <0.50 <0.50 <1.50 0.37 J 08/26/10 ND ND ND ND ND 07/22/15 <0.5 <0.5 <0.5 <1.5 ND 07/02/18 <0.50 <0.50 <0.50 <1.50 0.53 12/04/19 <0.50 <0.50 <0.50 <1.50 0.27 J 08/26/10 ND ND ND ND ND 12/19/11 ND ND ND ND ND 07/22/15 <0.5 <0.5 <0.5 <1.5 ND 07/02/18 <0.50 <0.50 <0.50 <1.50 0.35 J 12/04/19 <0.50 <0.50 <0.50 <1.50 <0.50 08/26/10 ND ND ND ND ND 12/19/11 ND ND ND ND ND 07/22/15 <0.5 <0.5 <0.5 <1.5 ND 07/02/18 <0.50 <0.50 <0.50 <1.50 0.87 1 600 600 500 70 5,000 260,000 80,000 50,000 70,000 Notes: 1. "<" or ND = Not detected at or above the laboratory reporting limit or method detection limit. 2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb). 3. Concentrations in BOLD equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard). 4. GCL = Gross Contamination Level. 5. Concentrations in ITALICS equal or exceed the corresponding GCL. 6. NE = Not established. 7. J = Indicates constituent was detected above laboratory detection limit but below laboratory reporting limit. 8. NA = Not Analyzed or original lab report not provided. Volitile Organic Compounds by EPA Method 6200BANALYTICAL METHOD GCL WSW-6 (4637 Farmer Denton Road) WSW-7 (4612 Farmer Denton Road) WSW-18 (4751 Dunbar Bridge Road) 2L Standard WSW-1 (6071 Old NC Hwy 49) Unable to Sample. Auddies #3 FIGURES OLD NORTH CAROLINA HIGHWAY 49DUNBAR BRIDGE ROADMW-3WR-2MW-1AWR-1MW-2MW-5MW-4WSW-1TANK 5TANK 4TANK 3TANK 2TANK 1FORMERDISPENSERISLANDFORMERDIESEL/KEROSENEDISPENSERSTANK 7TANK 6SITELEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-1MONITORING WELLWell IdentificationWSW-1WATER SUPPLY WELLWell Identification10SCALE: 1" = 30'02030NFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\AUDDIE'S 3\STL2392601-SITE.DWG, FIG2 SITE MAP08/04/2023SEE LOWER LEFTAUDDIES #3 6071 OLD NORTH CAROLINA HIGHWAY 49 ASHEBORO, NORTH CAROLINA NCDEQ INCIDENT #23926 STL2392601AS SHOWNDH BB2NOTES: 1.Features shown are not an authoritative location, nor are they presented to a stated accuracy. COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET SITE 1,500' RADIUS1,000' RADIUS500' RADIUS OLD NORTH CAROLINA HIGHWAY 49DUNBAR BRIDGE ROADMW-3WR-2MW-1AWR-1MW-2MW-5MW-4WSW-1TANK 5TANK 4TANK 3TANK 2TANK 1FORMERDIESEL/KEROSENEDISPENSERSTANK 7TANK 6SITELEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEWSW-1WATER SUPPLY WELLWell Identification57.4GROUNDWATER ELEVATION CONTOUR(DASHED WHERE INFERRED) (ft)GROUNDWATER FLOW DIRECTIONMW-457.32MONITORING WELLWell IdentificationRelative Groundwater Elevation (ft)NMNM57.3257.41NM57.32NMFORMERDISPENSERISLAND10SCALE: 1" = 30'02030NFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\AUDDIE'S 3\STL2392601-POT.DWG, FIG4 GROUNDWATER ELEVATION CONTOUR MAP08/04/2023SEE LOWER LEFTAUDDIES #3 6071 OLD NORTH CAROLINA HIGHWAY 49 ASHEBORO, NORTH CAROLINA NCDEQ INCIDENT #23926 STL2392601AS SHOWNDH BB4NOTES: 1.Features shown are not an authoritative location, nor are they presented to a stated accuracy. 2.Groundwater measured July 7, 2023. 3.NM = not measured COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET OLD NOR TH CARO L INA H IGHWAY 49DUNBAR BRIDGE ROADMW-3WR-2MW-1AWR-1MW-2MW-5MW-4WSW-1TANK 5TANK 4TANK 3TANK 2TANK 1FORMERDISPENSERISLANDFORMERDIESEL/KEROSENEDISPENSERSTANK 7TANK 6SITELEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEWSW-1WATER SUPPLY WELLWell Identification100BENZENE ISOCONCENTRATION CONTOUR(DASHED WHERE INFERRED) (µg/L)MW-4921MONITORING WELLWell IdentificationBenzene Concentration (µg/L)NSNS92120,600NS12,100NS10,0001,000100101 10SCALE: 1" = 30'02030NFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\AUDDIE'S 3\STL2392601-BENZ.DWG, FIG5 DISSOLVED BENZENE ISOCONCENTRATION MAP08/04/2023SEE LOWER LEFTAUDDIES #3 6071 OLD NORTH CAROLINA HIGHWAY 49 ASHEBORO, NORTH CAROLINA NCDEQ INCIDENT #23926 STL2392601AS SHOWNDH BB5NOTES: 1.Features shown are not an authoritative location, nor are they presented to a stated accuracy. 2.Groundwater sampled July 7, 2023. 3.NS = Not Sampled 4.µg/L = micrograms per liter COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET OLD NORTH CAROLINA HIGHWAY 49DUNBAR BRIDGE ROADMW-3WR-2MW-1AWR-1MW-2MW-5MW-4WSW-1TANK 5TANK 4TANK 3TANK 2TANK 1FORMERDISPENSERISLANDFORMERDIESEL/KEROSENEDISPENSERSTANK 7TANK 6SITELEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-1MONITORING WELLWell IdentificationWSW-1WATER SUPPLY WELLWell Identification10SCALE: 1" = 30'02030NNSNSNSNSFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\AUDDIE'S 3\STL2392601-GW.DWG, FIG6 ADDITIONAL CONTAMINANTS OF CONCERN IN GROUNDWATER08/04/2023SEE LOWER LEFTAUDDIES #3 6071 OLD NORTH CAROLINA HIGHWAY 49 ASHEBORO, NORTH CAROLINA NCDEQ INCIDENT #23926 STL2392601AS SHOWNDH BB6NOTES: 1.Features shown are not an authoritative location, nor are they presented to a stated accuracy. 2.NS = Not Sampled 3.Concentrations are reported in micrograms per liter (µg/L) = parts per billion (ppb) 4.J = Indicates constituent was detected above laboratory detection limit but below laboratory reporting limit. 5.Concentrations in BOLD equal or exceed the corresponding NCDEQ Groundwater Quality 2L Standard (2L Standard). 6.Concentrations in ITALICS equal or exceed the corresponding GCL. COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET Auddies #3 ATC Project No. STL2392601 NCDEQ State Lead Program APPENDIX A FIELD NOTES Auddies #3 ATC Project No. STL2392601 NCDEQ State Lead Program APPENDIX B MMPE REPORT AND WASTE DISPOSAL MANIFESTS Auddies #3 ATC Project No. STL2392601 NCDEQ State Lead Program APPENDIX C LABORATORY ANALYTICAL RESULTS ANALYTICAL REPORT June 21, 2023 ATC Group Services LLC Sample Delivery Group:L1625468 Samples Received:06/13/2023 Project Number:STL2392601 Description:Auddies #3 Report To:Brian Buchanan 2725 E. Millbrook Road, Ste 121 Raleigh, NC 27604 Entire Report Reviewed By: June 21, 2023 [Preliminary Report] Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 1 of 12 June 21, 2023 Heather J Wagner Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 1 of 12 TABLE OF CONTENTS Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-2 L1625468-01 5 MW-4 L1625468-02 6 MW-5 L1625468-03 7 Qc: Quality Control Summary 8 Volatile Organic Compounds (GC/MS) by Method 602MS 8 Gl: Glossary of Terms 10 Al: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 2 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 2 of 12 SAMPLE SUMMARY Collected by Collected date/time Received date/time MW-2 L1625468-01 GW Justin Jones 06/07/23 11:00 06/13/23 09:15 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 602MS WG2079421 50 06/17/23 03:46 06/17/23 03:46 DYW Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1625468-02 GW Justin Jones 06/07/23 11:05 06/13/23 09:15 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 602MS WG2081339 100 06/21/23 01:50 06/21/23 01:50 BAM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-5 L1625468-03 GW Justin Jones 06/07/23 11:10 06/13/23 09:15 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 602MS WG2081339 100 06/21/23 02:10 06/21/23 02:10 BAM Mt. Juliet, TN 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 3 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 3 of 12 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. [Preliminary Report] Heather J Wagner Project Manager 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 4 of 12 Heather J Wagner Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 4 of 12 SAMPLE RESULTS - 01 L1625468 MW-2 Collected date/time: 06/07/23 11:00 Volatile Organic Compounds (GC/MS) by Method 602MS Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Benzene 4430 4.71 50.0 50 06/17/2023 03:46 WG2079421 Toluene 841 13.9 50.0 50 06/17/2023 03:46 WG2079421 Ethylbenzene 866 6.85 50.0 50 06/17/2023 03:46 WG2079421 Total Xylenes 3030 8.70 150 50 06/17/2023 03:46 WG2079421 Methyl tert-butyl ether 1520 5.05 50.0 50 06/17/2023 03:46 WG2079421 Di-isopropyl ether 199 5.25 50.0 50 06/17/2023 03:46 WG2079421 (S) Toluene-d8 98.8 80.0-120 06/17/2023 03:46 WG2079421 (S) 4-Bromofluorobenzene 101 77.0-126 06/17/2023 03:46 WG2079421 (S) 1,2-Dichloroethane-d4 107 70.0-130 06/17/2023 03:46 WG2079421 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 5 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 5 of 12 SAMPLE RESULTS - 02 L1625468 MW-4 Collected date/time: 06/07/23 11:05 Volatile Organic Compounds (GC/MS) by Method 602MS Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Benzene 571 9.41 100 100 06/21/2023 01:50 WG2081339 Toluene 103 27.8 100 100 06/21/2023 01:50 WG2081339 Ethylbenzene U 13.7 100 100 06/21/2023 01:50 WG2081339 Total Xylenes 69.3 J 17.4 300 100 06/21/2023 01:50 WG2081339 Methyl tert-butyl ether 1410 10.1 100 100 06/21/2023 01:50 WG2081339 Di-isopropyl ether 274 10.5 100 100 06/21/2023 01:50 WG2081339 (S) Toluene-d8 116 80.0-120 06/21/2023 01:50 WG2081339 (S) 4-Bromofluorobenzene 88.4 77.0-126 06/21/2023 01:50 WG2081339 (S) 1,2-Dichloroethane-d4 126 70.0-130 06/21/2023 01:50 WG2081339 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 6 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 6 of 12 SAMPLE RESULTS - 03 L1625468 MW-5 Collected date/time: 06/07/23 11:10 Volatile Organic Compounds (GC/MS) by Method 602MS Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Benzene 5470 9.41 100 100 06/21/2023 02:10 WG2081339 Toluene 2390 27.8 100 100 06/21/2023 02:10 WG2081339 Ethylbenzene 290 13.7 100 100 06/21/2023 02:10 WG2081339 Total Xylenes 1730 17.4 300 100 06/21/2023 02:10 WG2081339 Methyl tert-butyl ether 4600 10.1 100 100 06/21/2023 02:10 WG2081339 Di-isopropyl ether 509 10.5 100 100 06/21/2023 02:10 WG2081339 (S) Toluene-d8 115 80.0-120 06/21/2023 02:10 WG2081339 (S) 4-Bromofluorobenzene 89.9 77.0-126 06/21/2023 02:10 WG2081339 (S) 1,2-Dichloroethane-d4 126 70.0-130 06/21/2023 02:10 WG2081339 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 7 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 7 of 12 QUALITY CONTROL SUMMARYWG2079421 Volatile Organic Compounds (GC/MS) by Method 602MS L1625468-01 Method Blank (MB) (MB) R3939017-3 06/16/23 18:07 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l Benzene U 0.0941 1.00 Toluene U 0.278 1.00 Ethylbenzene U 0.137 1.00 Total Xylenes U 0.174 3.00 Methyl tert-butyl ether U 0.101 1.00 Di-isopropyl ether U 0.105 1.00 (S) Toluene-d8 92.3 80.0-120 (S) 4-Bromofluorobenzene 98.6 77.0-126 (S) 1,2-Dichloroethane-d4 125 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3939017-1 06/16/23 17:02 • (LCSD) R3939017-2 06/16/23 17:24 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Benzene 5.00 5.12 5.17 102 103 70.0-123 0.972 20 Toluene 5.00 4.83 4.69 96.6 93.8 79.0-120 2.94 20 Ethylbenzene 5.00 5.08 4.93 102 98.6 79.0-123 3.00 20 Total Xylenes 15.0 15.1 14.6 101 97.3 79.0-123 3.37 20 Methyl tert-butyl ether 5.00 5.55 5.66 111 113 68.0-125 1.96 20 Di-isopropyl ether 5.00 5.09 5.24 102 105 58.0-138 2.90 20 (S) Toluene-d8 93.5 96.3 80.0-120 (S) 4-Bromofluorobenzene 102 101 77.0-126 (S) 1,2-Dichloroethane-d4 123 122 70.0-130 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 8 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 8 of 12 QUALITY CONTROL SUMMARYWG2081339 Volatile Organic Compounds (GC/MS) by Method 602MS L1625468-02,03 Method Blank (MB) (MB) R3939418-3 06/20/23 19:39 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l Benzene U 0.0941 1.00 Toluene U 0.278 1.00 Ethylbenzene U 0.137 1.00 Total Xylenes U 0.174 3.00 Methyl tert-butyl ether U 0.101 1.00 Di-isopropyl ether U 0.105 1.00 (S) Toluene-d8 120 80.0-120 (S) 4-Bromofluorobenzene 91.6 77.0-126 (S) 1,2-Dichloroethane-d4 124 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3939418-1 06/20/23 17:56 • (LCSD) R3939418-2 06/20/23 19:19 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Benzene 5.00 5.18 5.06 104 101 70.0-123 2.34 20 Toluene 5.00 5.32 5.19 106 104 79.0-120 2.47 20 Ethylbenzene 5.00 4.99 4.77 99.8 95.4 79.0-123 4.51 20 Total Xylenes 15.0 14.5 13.6 96.7 90.7 79.0-123 6.41 20 Methyl tert-butyl ether 5.00 5.53 4.97 111 99.4 68.0-125 10.7 20 Di-isopropyl ether 5.00 6.67 6.69 133 134 58.0-138 0.299 20 (S) Toluene-d8 117 114 80.0-120 (S) 4-Bromofluorobenzene 93.5 92.3 77.0-126 (S) 1,2-Dichloroethane-d4 125 123 70.0-130 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 9 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 9 of 12 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. RDL Reported Detection Limit. Rec.Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. (S) Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Dilution If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Limits These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Qualifier This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. Result The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry)Confidence level of 2 sigma. Case Narrative (Cn) A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control Summary (Qc) This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. Sample Chain of Custody (Sc) This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. Sample Results (Sr) This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable; the reported value is an estimate. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 10 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 10 of 12 Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey–NELAP TN002 California 2932 New Mexico ¹TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina ¹DW21704 Georgia NELAP North Carolina ³41 Georgia ¹923 North Dakota R-140 Idaho TN00003 Ohio–VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LAO00356 Kentucky ¹ ⁶KY90010 South Carolina 84004002 Kentucky ²16 South Dakota n/a Louisiana AI30792 Tennessee ¹ ⁴2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas ⁵LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2LA A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2LA – ISO 17025 ⁵1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA–Crypto TN00003 ACCREDITATIONS & LOCATIONS ¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 14:26 11 of 12 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1625468 06/21/23 15:26 11 of 12 ANALYTICAL REPORT July 19, 2023 ATC Group Services LLC Sample Delivery Group:L1634590 Samples Received:07/12/2023 Project Number:STL2392601 Description:Auddies #3 Report To:Brian Buchanan 2725 E. Millbrook Road, Ste 121 Raleigh, NC 27604 Entire Report Reviewed By: July 19, 2023 [Preliminary Report] Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 1 of 20 July 19, 2023 Jason Romer Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 1 of 20 TABLE OF CONTENTS Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-2 L1634590-01 5 MW-4 L1634590-02 7 MW-5 L1634590-03 9 FB-1 (FIELD BLANK) L1634590-04 11 Qc: Quality Control Summary 13 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 13 Gl: Glossary of Terms 18 Al: Accreditations & Locations 19 Sc: Sample Chain of Custody 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 2 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 2 of 20 SAMPLE SUMMARY Collected by Collected date/time Received date/time MW-2 L1634590-01 GW Garrett Lewis 07/07/23 12:10 07/12/23 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2094839 50 07/14/23 16:21 07/14/23 16:21 JHH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2096255 500 07/19/23 04:24 07/19/23 04:24 DYW Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1634590-02 GW Garrett Lewis 07/07/23 13:30 07/12/23 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2094839 50 07/14/23 16:41 07/14/23 16:41 JHH Mt. Juliet, TN Collected by Collected date/time Received date/time MW-5 L1634590-03 GW Garrett Lewis 07/07/23 13:00 07/12/23 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2094839 50 07/14/23 17:00 07/14/23 17:00 JHH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2096255 500 07/19/23 04:44 07/19/23 04:44 DYW Mt. Juliet, TN Collected by Collected date/time Received date/time FB-1 (FIELD BLANK) L1634590-04 GW Garrett Lewis 07/07/23 13:40 07/12/23 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2094839 1 07/14/23 12:13 07/14/23 12:13 ACG Mt. Juliet, TN 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 3 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 3 of 20 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. [Preliminary Report] Heather J Wagner Project Manager 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 4 of 20 Jason Romer Project Manager ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 4 of 20 SAMPLE RESULTS - 01 L1634590 MW-2 Collected date/time: 07/07/23 12:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Acetone U 565 2500 50 07/14/2023 16:21 WG2094839 Acrolein U 127 2500 50 07/14/2023 16:21 WG2094839 Acrylonitrile U 33.6 500 50 07/14/2023 16:21 WG2094839 Benzene 12100 47.1 500 500 07/19/2023 04:24 WG2096255 Bromobenzene U 5.90 50.0 50 07/14/2023 16:21 WG2094839 Bromodichloromethane U 6.80 50.0 50 07/14/2023 16:21 WG2094839 Bromoform U 6.45 50.0 50 07/14/2023 16:21 WG2094839 Bromomethane U 30.3 250 50 07/14/2023 16:21 WG2094839 n-Butylbenzene 24.0 J 7.85 50.0 50 07/14/2023 16:21 WG2094839 sec-Butylbenzene 10.1 J 6.25 50.0 50 07/14/2023 16:21 WG2094839 tert-Butylbenzene U 6.35 50.0 50 07/14/2023 16:21 WG2094839 Carbon tetrachloride U 6.40 50.0 50 07/14/2023 16:21 WG2094839 Chlorobenzene U 5.80 50.0 50 07/14/2023 16:21 WG2094839 Chlorodibromomethane U 7.00 50.0 50 07/14/2023 16:21 WG2094839 Chloroethane U 9.60 250 50 07/14/2023 16:21 WG2094839 Chloroform U 5.55 250 50 07/14/2023 16:21 WG2094839 Chloromethane U 48.0 125 50 07/14/2023 16:21 WG2094839 2-Chlorotoluene U 5.30 50.0 50 07/14/2023 16:21 WG2094839 4-Chlorotoluene U 5.70 50.0 50 07/14/2023 16:21 WG2094839 1,2-Dibromo-3-Chloropropane U 13.8 250 50 07/14/2023 16:21 WG2094839 1,2-Dibromoethane U 6.30 50.0 50 07/14/2023 16:21 WG2094839 Dibromomethane U 6.10 50.0 50 07/14/2023 16:21 WG2094839 1,2-Dichlorobenzene U 5.35 50.0 50 07/14/2023 16:21 WG2094839 1,3-Dichlorobenzene U 5.50 50.0 50 07/14/2023 16:21 WG2094839 1,4-Dichlorobenzene U 6.00 50.0 50 07/14/2023 16:21 WG2094839 Dichlorodifluoromethane U 18.7 250 50 07/14/2023 16:21 WG2094839 1,1-Dichloroethane U 5.00 50.0 50 07/14/2023 16:21 WG2094839 1,2-Dichloroethane 439 4.09 50.0 50 07/14/2023 16:21 WG2094839 1,1-Dichloroethene U 9.40 50.0 50 07/14/2023 16:21 WG2094839 cis-1,2-Dichloroethene U 6.30 50.0 50 07/14/2023 16:21 WG2094839 trans-1,2-Dichloroethene U 7.45 50.0 50 07/14/2023 16:21 WG2094839 1,2-Dichloropropane U 7.45 50.0 50 07/14/2023 16:21 WG2094839 1,1-Dichloropropene U 7.10 50.0 50 07/14/2023 16:21 WG2094839 1,3-Dichloropropane U 5.50 50.0 50 07/14/2023 16:21 WG2094839 2,2-Dichloropropane U 8.05 50.0 50 07/14/2023 16:21 WG2094839 Di-isopropyl ether 262 5.25 50.0 50 07/14/2023 16:21 WG2094839 Ethylbenzene 1320 6.85 50.0 50 07/14/2023 16:21 WG2094839 Hexachloro-1,3-butadiene U 16.9 50.0 50 07/14/2023 16:21 WG2094839 Isopropylbenzene 74.2 5.25 50.0 50 07/14/2023 16:21 WG2094839 p-Isopropyltoluene 9.93 J 6.00 50.0 50 07/14/2023 16:21 WG2094839 2-Butanone (MEK)U 59.5 500 50 07/14/2023 16:21 WG2094839 Methylene Chloride U 21.5 250 50 07/14/2023 16:21 WG2094839 4-Methyl-2-pentanone (MIBK)U 23.9 500 50 07/14/2023 16:21 WG2094839 Methyl tert-butyl ether 3230 5.05 50.0 50 07/14/2023 16:21 WG2094839 Naphthalene 425 50.0 250 50 07/14/2023 16:21 WG2094839 n-Propylbenzene 162 4.97 50.0 50 07/14/2023 16:21 WG2094839 Styrene 21.5 J 5.90 50.0 50 07/14/2023 16:21 WG2094839 1,1,1,2-Tetrachloroethane U 7.35 50.0 50 07/14/2023 16:21 WG2094839 1,1,2,2-Tetrachloroethane U 6.65 50.0 50 07/14/2023 16:21 WG2094839 Tetrachloroethene U 15.0 50.0 50 07/14/2023 16:21 WG2094839 Toluene 1800 13.9 50.0 50 07/14/2023 16:21 WG2094839 1,2,3-Trichlorobenzene U 11.5 50.0 50 07/14/2023 16:21 WG2094839 1,2,4-Trichlorobenzene U 24.1 50.0 50 07/14/2023 16:21 WG2094839 1,1,1-Trichloroethane U 7.45 50.0 50 07/14/2023 16:21 WG2094839 1,1,2-Trichloroethane U 7.90 50.0 50 07/14/2023 16:21 WG2094839 Trichloroethene U 9.50 50.0 50 07/14/2023 16:21 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 5 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 5 of 20 SAMPLE RESULTS - 01 L1634590 MW-2 Collected date/time: 07/07/23 12:10 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Trichlorofluoromethane U 8.00 250 50 07/14/2023 16:21 WG2094839 1,2,3-Trichloropropane U 11.9 125 50 07/14/2023 16:21 WG2094839 1,2,4-Trimethylbenzene 1120 16.1 50.0 50 07/14/2023 16:21 WG2094839 1,3,5-Trimethylbenzene 357 5.20 50.0 50 07/14/2023 16:21 WG2094839 Vinyl chloride U 11.7 50.0 50 07/14/2023 16:21 WG2094839 o-Xylene 1160 8.70 50.0 50 07/14/2023 16:21 WG2094839 m&p-Xylenes 3380 21.5 100 50 07/14/2023 16:21 WG2094839 (S) Toluene-d8 106 80.0-120 07/14/2023 16:21 WG2094839 (S) Toluene-d8 102 80.0-120 07/19/2023 04:24 WG2096255 (S) 4-Bromofluorobenzene 96.3 77.0-126 07/14/2023 16:21 WG2094839 (S) 4-Bromofluorobenzene 103 77.0-126 07/19/2023 04:24 WG2096255 (S) 1,2-Dichloroethane-d4 109 70.0-130 07/14/2023 16:21 WG2094839 (S) 1,2-Dichloroethane-d4 111 70.0-130 07/19/2023 04:24 WG2096255 Sample Narrative: L1634590-01 WG2094839: Target compounds too high to run at a lower dilution. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 6 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 6 of 20 SAMPLE RESULTS - 02 L1634590 MW-4 Collected date/time: 07/07/23 13:30 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Acetone U 565 2500 50 07/14/2023 16:41 WG2094839 Acrolein U 127 2500 50 07/14/2023 16:41 WG2094839 Acrylonitrile U 33.6 500 50 07/14/2023 16:41 WG2094839 Benzene 921 4.71 50.0 50 07/14/2023 16:41 WG2094839 Bromobenzene U 5.90 50.0 50 07/14/2023 16:41 WG2094839 Bromodichloromethane U 6.80 50.0 50 07/14/2023 16:41 WG2094839 Bromoform U 6.45 50.0 50 07/14/2023 16:41 WG2094839 Bromomethane U 30.3 250 50 07/14/2023 16:41 WG2094839 n-Butylbenzene U 7.85 50.0 50 07/14/2023 16:41 WG2094839 sec-Butylbenzene U 6.25 50.0 50 07/14/2023 16:41 WG2094839 tert-Butylbenzene U 6.35 50.0 50 07/14/2023 16:41 WG2094839 Carbon tetrachloride U 6.40 50.0 50 07/14/2023 16:41 WG2094839 Chlorobenzene U 5.80 50.0 50 07/14/2023 16:41 WG2094839 Chlorodibromomethane U 7.00 50.0 50 07/14/2023 16:41 WG2094839 Chloroethane U 9.60 250 50 07/14/2023 16:41 WG2094839 Chloroform U 5.55 250 50 07/14/2023 16:41 WG2094839 Chloromethane U 48.0 125 50 07/14/2023 16:41 WG2094839 2-Chlorotoluene U 5.30 50.0 50 07/14/2023 16:41 WG2094839 4-Chlorotoluene U 5.70 50.0 50 07/14/2023 16:41 WG2094839 1,2-Dibromo-3-Chloropropane U 13.8 250 50 07/14/2023 16:41 WG2094839 1,2-Dibromoethane U 6.30 50.0 50 07/14/2023 16:41 WG2094839 Dibromomethane U 6.10 50.0 50 07/14/2023 16:41 WG2094839 1,2-Dichlorobenzene U 5.35 50.0 50 07/14/2023 16:41 WG2094839 1,3-Dichlorobenzene U 5.50 50.0 50 07/14/2023 16:41 WG2094839 1,4-Dichlorobenzene U 6.00 50.0 50 07/14/2023 16:41 WG2094839 Dichlorodifluoromethane U 18.7 250 50 07/14/2023 16:41 WG2094839 1,1-Dichloroethane U 5.00 50.0 50 07/14/2023 16:41 WG2094839 1,2-Dichloroethane 187 4.09 50.0 50 07/14/2023 16:41 WG2094839 1,1-Dichloroethene U 9.40 50.0 50 07/14/2023 16:41 WG2094839 cis-1,2-Dichloroethene U 6.30 50.0 50 07/14/2023 16:41 WG2094839 trans-1,2-Dichloroethene U 7.45 50.0 50 07/14/2023 16:41 WG2094839 1,2-Dichloropropane U 7.45 50.0 50 07/14/2023 16:41 WG2094839 1,1-Dichloropropene U 7.10 50.0 50 07/14/2023 16:41 WG2094839 1,3-Dichloropropane U 5.50 50.0 50 07/14/2023 16:41 WG2094839 2,2-Dichloropropane U 8.05 50.0 50 07/14/2023 16:41 WG2094839 Di-isopropyl ether 730 5.25 50.0 50 07/14/2023 16:41 WG2094839 Ethylbenzene 92.5 6.85 50.0 50 07/14/2023 16:41 WG2094839 Hexachloro-1,3-butadiene U 16.9 50.0 50 07/14/2023 16:41 WG2094839 Isopropylbenzene 54.8 5.25 50.0 50 07/14/2023 16:41 WG2094839 p-Isopropyltoluene 17.9 J 6.00 50.0 50 07/14/2023 16:41 WG2094839 2-Butanone (MEK)U 59.5 500 50 07/14/2023 16:41 WG2094839 Methylene Chloride U 21.5 250 50 07/14/2023 16:41 WG2094839 4-Methyl-2-pentanone (MIBK)69.6 J 23.9 500 50 07/14/2023 16:41 WG2094839 Methyl tert-butyl ether 4280 5.05 50.0 50 07/14/2023 16:41 WG2094839 Naphthalene 50.5 J 50.0 250 50 07/14/2023 16:41 WG2094839 n-Propylbenzene 9.24 J 4.97 50.0 50 07/14/2023 16:41 WG2094839 Styrene U 5.90 50.0 50 07/14/2023 16:41 WG2094839 1,1,1,2-Tetrachloroethane U 7.35 50.0 50 07/14/2023 16:41 WG2094839 1,1,2,2-Tetrachloroethane U 6.65 50.0 50 07/14/2023 16:41 WG2094839 Tetrachloroethene U 15.0 50.0 50 07/14/2023 16:41 WG2094839 Toluene 176 13.9 50.0 50 07/14/2023 16:41 WG2094839 1,2,3-Trichlorobenzene U 11.5 50.0 50 07/14/2023 16:41 WG2094839 1,2,4-Trichlorobenzene U 24.1 50.0 50 07/14/2023 16:41 WG2094839 1,1,1-Trichloroethane U 7.45 50.0 50 07/14/2023 16:41 WG2094839 1,1,2-Trichloroethane U 7.90 50.0 50 07/14/2023 16:41 WG2094839 Trichloroethene U 9.50 50.0 50 07/14/2023 16:41 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 7 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 7 of 20 SAMPLE RESULTS - 02 L1634590 MW-4 Collected date/time: 07/07/23 13:30 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Trichlorofluoromethane U 8.00 250 50 07/14/2023 16:41 WG2094839 1,2,3-Trichloropropane U 11.9 125 50 07/14/2023 16:41 WG2094839 1,2,4-Trimethylbenzene 36.7 J 16.1 50.0 50 07/14/2023 16:41 WG2094839 1,3,5-Trimethylbenzene 24.7 J 5.20 50.0 50 07/14/2023 16:41 WG2094839 Vinyl chloride U 11.7 50.0 50 07/14/2023 16:41 WG2094839 o-Xylene 36.0 J 8.70 50.0 50 07/14/2023 16:41 WG2094839 m&p-Xylenes 93.7 J 21.5 100 50 07/14/2023 16:41 WG2094839 (S) Toluene-d8 105 80.0-120 07/14/2023 16:41 WG2094839 (S) 4-Bromofluorobenzene 101 77.0-126 07/14/2023 16:41 WG2094839 (S) 1,2-Dichloroethane-d4 110 70.0-130 07/14/2023 16:41 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 8 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 8 of 20 SAMPLE RESULTS - 03 L1634590 MW-5 Collected date/time: 07/07/23 13:00 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Acetone U 565 2500 50 07/14/2023 17:00 WG2094839 Acrolein U 127 2500 50 07/14/2023 17:00 WG2094839 Acrylonitrile U 33.6 500 50 07/14/2023 17:00 WG2094839 Benzene 20600 47.1 500 500 07/19/2023 04:44 WG2096255 Bromobenzene U 5.90 50.0 50 07/14/2023 17:00 WG2094839 Bromodichloromethane U 6.80 50.0 50 07/14/2023 17:00 WG2094839 Bromoform U 6.45 50.0 50 07/14/2023 17:00 WG2094839 Bromomethane U 30.3 250 50 07/14/2023 17:00 WG2094839 n-Butylbenzene 21.4 J 7.85 50.0 50 07/14/2023 17:00 WG2094839 sec-Butylbenzene 9.44 J 6.25 50.0 50 07/14/2023 17:00 WG2094839 tert-Butylbenzene U 6.35 50.0 50 07/14/2023 17:00 WG2094839 Carbon tetrachloride U 6.40 50.0 50 07/14/2023 17:00 WG2094839 Chlorobenzene U 5.80 50.0 50 07/14/2023 17:00 WG2094839 Chlorodibromomethane U 7.00 50.0 50 07/14/2023 17:00 WG2094839 Chloroethane U 9.60 250 50 07/14/2023 17:00 WG2094839 Chloroform U 5.55 250 50 07/14/2023 17:00 WG2094839 Chloromethane U 48.0 125 50 07/14/2023 17:00 WG2094839 2-Chlorotoluene U 5.30 50.0 50 07/14/2023 17:00 WG2094839 4-Chlorotoluene U 5.70 50.0 50 07/14/2023 17:00 WG2094839 1,2-Dibromo-3-Chloropropane U 13.8 250 50 07/14/2023 17:00 WG2094839 1,2-Dibromoethane U 6.30 50.0 50 07/14/2023 17:00 WG2094839 Dibromomethane U 6.10 50.0 50 07/14/2023 17:00 WG2094839 1,2-Dichlorobenzene U 5.35 50.0 50 07/14/2023 17:00 WG2094839 1,3-Dichlorobenzene U 5.50 50.0 50 07/14/2023 17:00 WG2094839 1,4-Dichlorobenzene U 6.00 50.0 50 07/14/2023 17:00 WG2094839 Dichlorodifluoromethane U 18.7 250 50 07/14/2023 17:00 WG2094839 1,1-Dichloroethane U 5.00 50.0 50 07/14/2023 17:00 WG2094839 1,2-Dichloroethane 667 4.09 50.0 50 07/14/2023 17:00 WG2094839 1,1-Dichloroethene U 9.40 50.0 50 07/14/2023 17:00 WG2094839 cis-1,2-Dichloroethene U 6.30 50.0 50 07/14/2023 17:00 WG2094839 trans-1,2-Dichloroethene U 7.45 50.0 50 07/14/2023 17:00 WG2094839 1,2-Dichloropropane U 7.45 50.0 50 07/14/2023 17:00 WG2094839 1,1-Dichloropropene U 7.10 50.0 50 07/14/2023 17:00 WG2094839 1,3-Dichloropropane U 5.50 50.0 50 07/14/2023 17:00 WG2094839 2,2-Dichloropropane U 8.05 50.0 50 07/14/2023 17:00 WG2094839 Di-isopropyl ether 991 5.25 50.0 50 07/14/2023 17:00 WG2094839 Ethylbenzene 1300 6.85 50.0 50 07/14/2023 17:00 WG2094839 Hexachloro-1,3-butadiene U 16.9 50.0 50 07/14/2023 17:00 WG2094839 Isopropylbenzene 62.1 5.25 50.0 50 07/14/2023 17:00 WG2094839 p-Isopropyltoluene 37.6 J 6.00 50.0 50 07/14/2023 17:00 WG2094839 2-Butanone (MEK)760 59.5 500 50 07/14/2023 17:00 WG2094839 Methylene Chloride U 21.5 250 50 07/14/2023 17:00 WG2094839 4-Methyl-2-pentanone (MIBK)233 J 23.9 500 50 07/14/2023 17:00 WG2094839 Methyl tert-butyl ether 15000 50.5 500 500 07/19/2023 04:44 WG2096255 Naphthalene 405 50.0 250 50 07/14/2023 17:00 WG2094839 n-Propylbenzene 133 4.97 50.0 50 07/14/2023 17:00 WG2094839 Styrene U 5.90 50.0 50 07/14/2023 17:00 WG2094839 1,1,1,2-Tetrachloroethane U 7.35 50.0 50 07/14/2023 17:00 WG2094839 1,1,2,2-Tetrachloroethane U 6.65 50.0 50 07/14/2023 17:00 WG2094839 Tetrachloroethene U 15.0 50.0 50 07/14/2023 17:00 WG2094839 Toluene 1850 13.9 50.0 50 07/14/2023 17:00 WG2094839 1,2,3-Trichlorobenzene U 11.5 50.0 50 07/14/2023 17:00 WG2094839 1,2,4-Trichlorobenzene U 24.1 50.0 50 07/14/2023 17:00 WG2094839 1,1,1-Trichloroethane U 7.45 50.0 50 07/14/2023 17:00 WG2094839 1,1,2-Trichloroethane U 7.90 50.0 50 07/14/2023 17:00 WG2094839 Trichloroethene U 9.50 50.0 50 07/14/2023 17:00 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 9 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 9 of 20 SAMPLE RESULTS - 03 L1634590 MW-5 Collected date/time: 07/07/23 13:00 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Trichlorofluoromethane U 8.00 250 50 07/14/2023 17:00 WG2094839 1,2,3-Trichloropropane U 11.9 125 50 07/14/2023 17:00 WG2094839 1,2,4-Trimethylbenzene 841 16.1 50.0 50 07/14/2023 17:00 WG2094839 1,3,5-Trimethylbenzene 302 5.20 50.0 50 07/14/2023 17:00 WG2094839 Vinyl chloride U 11.7 50.0 50 07/14/2023 17:00 WG2094839 o-Xylene 1060 8.70 50.0 50 07/14/2023 17:00 WG2094839 m&p-Xylenes 2620 21.5 100 50 07/14/2023 17:00 WG2094839 (S) Toluene-d8 103 80.0-120 07/14/2023 17:00 WG2094839 (S) Toluene-d8 99.9 80.0-120 07/19/2023 04:44 WG2096255 (S) 4-Bromofluorobenzene 96.6 77.0-126 07/14/2023 17:00 WG2094839 (S) 4-Bromofluorobenzene 101 77.0-126 07/19/2023 04:44 WG2096255 (S) 1,2-Dichloroethane-d4 109 70.0-130 07/14/2023 17:00 WG2094839 (S) 1,2-Dichloroethane-d4 114 70.0-130 07/19/2023 04:44 WG2096255 Sample Narrative: L1634590-03 WG2094839: Target compounds too high to run at a lower dilution. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 10 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 10 of 20 SAMPLE RESULTS - 04 L1634590 FB-1 (FIELD BLANK) Collected date/time: 07/07/23 13:40 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Acetone 12.3 J 11.3 50.0 1 07/14/2023 12:13 WG2094839 Acrolein U 2.54 50.0 1 07/14/2023 12:13 WG2094839 Acrylonitrile U 0.671 10.0 1 07/14/2023 12:13 WG2094839 Benzene U 0.0941 1.00 1 07/14/2023 12:13 WG2094839 Bromobenzene U 0.118 1.00 1 07/14/2023 12:13 WG2094839 Bromodichloromethane U 0.136 1.00 1 07/14/2023 12:13 WG2094839 Bromoform U 0.129 1.00 1 07/14/2023 12:13 WG2094839 Bromomethane U 0.605 5.00 1 07/14/2023 12:13 WG2094839 n-Butylbenzene U 0.157 1.00 1 07/14/2023 12:13 WG2094839 sec-Butylbenzene U 0.125 1.00 1 07/14/2023 12:13 WG2094839 tert-Butylbenzene U 0.127 1.00 1 07/14/2023 12:13 WG2094839 Carbon tetrachloride U 0.128 1.00 1 07/14/2023 12:13 WG2094839 Chlorobenzene U 0.116 1.00 1 07/14/2023 12:13 WG2094839 Chlorodibromomethane U 0.140 1.00 1 07/14/2023 12:13 WG2094839 Chloroethane U 0.192 5.00 1 07/14/2023 12:13 WG2094839 Chloroform U 0.111 5.00 1 07/14/2023 12:13 WG2094839 Chloromethane U 0.960 2.50 1 07/14/2023 12:13 WG2094839 2-Chlorotoluene U 0.106 1.00 1 07/14/2023 12:13 WG2094839 4-Chlorotoluene U 0.114 1.00 1 07/14/2023 12:13 WG2094839 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/14/2023 12:13 WG2094839 1,2-Dibromoethane U 0.126 1.00 1 07/14/2023 12:13 WG2094839 Dibromomethane U 0.122 1.00 1 07/14/2023 12:13 WG2094839 1,2-Dichlorobenzene U 0.107 1.00 1 07/14/2023 12:13 WG2094839 1,3-Dichlorobenzene U 0.110 1.00 1 07/14/2023 12:13 WG2094839 1,4-Dichlorobenzene U 0.120 1.00 1 07/14/2023 12:13 WG2094839 Dichlorodifluoromethane U 0.374 5.00 1 07/14/2023 12:13 WG2094839 1,1-Dichloroethane U 0.100 1.00 1 07/14/2023 12:13 WG2094839 1,2-Dichloroethane U 0.0819 1.00 1 07/14/2023 12:13 WG2094839 1,1-Dichloroethene U 0.188 1.00 1 07/14/2023 12:13 WG2094839 cis-1,2-Dichloroethene U 0.126 1.00 1 07/14/2023 12:13 WG2094839 trans-1,2-Dichloroethene U 0.149 1.00 1 07/14/2023 12:13 WG2094839 1,2-Dichloropropane U 0.149 1.00 1 07/14/2023 12:13 WG2094839 1,1-Dichloropropene U 0.142 1.00 1 07/14/2023 12:13 WG2094839 1,3-Dichloropropane U 0.110 1.00 1 07/14/2023 12:13 WG2094839 2,2-Dichloropropane U 0.161 1.00 1 07/14/2023 12:13 WG2094839 Di-isopropyl ether U 0.105 1.00 1 07/14/2023 12:13 WG2094839 Ethylbenzene U 0.137 1.00 1 07/14/2023 12:13 WG2094839 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/14/2023 12:13 WG2094839 Isopropylbenzene U 0.105 1.00 1 07/14/2023 12:13 WG2094839 p-Isopropyltoluene U 0.120 1.00 1 07/14/2023 12:13 WG2094839 2-Butanone (MEK)2.91 J 1.19 10.0 1 07/14/2023 12:13 WG2094839 Methylene Chloride U 0.430 5.00 1 07/14/2023 12:13 WG2094839 4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 07/14/2023 12:13 WG2094839 Methyl tert-butyl ether U 0.101 1.00 1 07/14/2023 12:13 WG2094839 Naphthalene U 1.00 5.00 1 07/14/2023 12:13 WG2094839 n-Propylbenzene U 0.0993 1.00 1 07/14/2023 12:13 WG2094839 Styrene U 0.118 1.00 1 07/14/2023 12:13 WG2094839 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/14/2023 12:13 WG2094839 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/14/2023 12:13 WG2094839 Tetrachloroethene U 0.300 1.00 1 07/14/2023 12:13 WG2094839 Toluene U 0.278 1.00 1 07/14/2023 12:13 WG2094839 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/14/2023 12:13 WG2094839 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/14/2023 12:13 WG2094839 1,1,1-Trichloroethane U 0.149 1.00 1 07/14/2023 12:13 WG2094839 1,1,2-Trichloroethane U 0.158 1.00 1 07/14/2023 12:13 WG2094839 Trichloroethene U 0.190 1.00 1 07/14/2023 12:13 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 11 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 11 of 20 SAMPLE RESULTS - 04 L1634590 FB-1 (FIELD BLANK) Collected date/time: 07/07/23 13:40 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/l ug/l ug/l date / time Trichlorofluoromethane U 0.160 5.00 1 07/14/2023 12:13 WG2094839 1,2,3-Trichloropropane U 0.237 2.50 1 07/14/2023 12:13 WG2094839 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/14/2023 12:13 WG2094839 1,3,5-Trimethylbenzene U 0.104 1.00 1 07/14/2023 12:13 WG2094839 Vinyl chloride U 0.234 1.00 1 07/14/2023 12:13 WG2094839 o-Xylene U 0.174 1.00 1 07/14/2023 12:13 WG2094839 m&p-Xylenes U 0.430 2.00 1 07/14/2023 12:13 WG2094839 (S) Toluene-d8 104 80.0-120 07/14/2023 12:13 WG2094839 (S) 4-Bromofluorobenzene 95.7 77.0-126 07/14/2023 12:13 WG2094839 (S) 1,2-Dichloroethane-d4 109 70.0-130 07/14/2023 12:13 WG2094839 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 12 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 12 of 20 QUALITY CONTROL SUMMARYWG2094839 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1634590-01,02,03,04 Method Blank (MB) (MB) R3948701-3 07/14/23 10:25 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l Acetone U 11.3 50.0 Acrolein U 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene U 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 sec-Butylbenzene U 0.125 1.00 tert-Butylbenzene U 0.127 1.00 Carbon tetrachloride U 0.128 1.00 Chlorobenzene U 0.116 1.00 Chlorodibromomethane U 0.140 1.00 Chloroethane U 0.192 5.00 Chloroform U 0.111 5.00 Chloromethane U 0.960 2.50 2-Chlorotoluene U 0.106 1.00 4-Chlorotoluene U 0.114 1.00 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1,2-Dibromoethane U 0.126 1.00 Dibromomethane U 0.122 1.00 1,2-Dichlorobenzene U 0.107 1.00 1,3-Dichlorobenzene U 0.110 1.00 1,4-Dichlorobenzene U 0.120 1.00 Dichlorodifluoromethane U 0.374 5.00 1,1-Dichloroethane U 0.100 1.00 1,2-Dichloroethane U 0.0819 1.00 1,1-Dichloroethene U 0.188 1.00 cis-1,2-Dichloroethene U 0.126 1.00 trans-1,2-Dichloroethene U 0.149 1.00 1,2-Dichloropropane U 0.149 1.00 1,1-Dichloropropene U 0.142 1.00 1,3-Dichloropropane U 0.110 1.00 2,2-Dichloropropane U 0.161 1.00 Di-isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 13 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 13 of 20 QUALITY CONTROL SUMMARYWG2094839 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1634590-01,02,03,04 Method Blank (MB) (MB) R3948701-3 07/14/23 10:25 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l 2-Butanone (MEK)U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK)U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethylbenzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 o-Xylene U 0.174 1.00 m&p-Xylenes U 0.430 2.00 (S) Toluene-d8 107 80.0-120 (S) 4-Bromofluorobenzene 97.3 77.0-126 (S) 1,2-Dichloroethane-d4 106 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3948701-1 07/14/23 09:28 • (LCSD) R3948701-2 07/14/23 09:47 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Acetone 25.0 21.8 22.6 87.2 90.4 19.0-160 3.60 27 Acrolein 25.0 37.2 39.2 149 157 10.0-160 5.24 26 Acrylonitrile 25.0 26.6 25.7 106 103 55.0-149 3.44 20 Benzene 5.00 5.00 5.22 100 104 70.0-123 4.31 20 Bromobenzene 5.00 4.82 4.95 96.4 99.0 73.0-121 2.66 20 Bromodichloromethane 5.00 5.04 5.26 101 105 75.0-120 4.27 20 Bromoform 5.00 4.57 4.62 91.4 92.4 68.0-132 1.09 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 14 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 14 of 20 QUALITY CONTROL SUMMARYWG2094839 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1634590-01,02,03,04 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3948701-1 07/14/23 09:28 • (LCSD) R3948701-2 07/14/23 09:47 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Bromomethane 5.00 4.99 5.13 99.8 103 10.0-160 2.77 25 n-Butylbenzene 5.00 4.45 4.94 89.0 98.8 73.0-125 10.4 20 sec-Butylbenzene 5.00 4.63 5.03 92.6 101 75.0-125 8.28 20 tert-Butylbenzene 5.00 4.63 5.03 92.6 101 76.0-124 8.28 20 Carbon tetrachloride 5.00 5.14 5.11 103 102 68.0-126 0.585 20 Chlorobenzene 5.00 4.94 5.01 98.8 100 80.0-121 1.41 20 Chlorodibromomethane 5.00 4.78 4.92 95.6 98.4 77.0-125 2.89 20 Chloroethane 5.00 4.82 4.66 96.4 93.2 47.0-150 3.38 20 Chloroform 5.00 5.04 5.31 101 106 73.0-120 5.22 20 Chloromethane 5.00 5.31 5.06 106 101 41.0-142 4.82 20 2-Chlorotoluene 5.00 4.84 5.04 96.8 101 76.0-123 4.05 20 4-Chlorotoluene 5.00 4.80 5.00 96.0 100 75.0-122 4.08 20 1,2-Dibromo-3-Chloropropane 5.00 4.28 4.29 85.6 85.8 58.0-134 0.233 20 1,2-Dibromoethane 5.00 4.87 5.09 97.4 102 80.0-122 4.42 20 Dibromomethane 5.00 5.05 5.17 101 103 80.0-120 2.35 20 1,2-Dichlorobenzene 5.00 4.68 4.89 93.6 97.8 79.0-121 4.39 20 1,3-Dichlorobenzene 5.00 4.74 5.04 94.8 101 79.0-120 6.13 20 1,4-Dichlorobenzene 5.00 4.69 4.84 93.8 96.8 79.0-120 3.15 20 Dichlorodifluoromethane 5.00 5.10 4.57 102 91.4 51.0-149 11.0 20 1,1-Dichloroethane 5.00 5.21 5.22 104 104 70.0-126 0.192 20 1,2-Dichloroethane 5.00 5.43 5.78 109 116 70.0-128 6.24 20 1,1-Dichloroethene 5.00 4.60 4.61 92.0 92.2 71.0-124 0.217 20 cis-1,2-Dichloroethene 5.00 4.95 4.86 99.0 97.2 73.0-120 1.83 20 trans-1,2-Dichloroethene 5.00 4.91 5.11 98.2 102 73.0-120 3.99 20 1,2-Dichloropropane 5.00 5.28 5.35 106 107 77.0-125 1.32 20 1,1-Dichloropropene 5.00 5.10 5.35 102 107 74.0-126 4.78 20 1,3-Dichloropropane 5.00 4.97 5.14 99.4 103 80.0-120 3.36 20 2,2-Dichloropropane 5.00 5.03 4.92 101 98.4 58.0-130 2.21 20 Di-isopropyl ether 5.00 5.42 5.48 108 110 58.0-138 1.10 20 Ethylbenzene 5.00 4.87 4.86 97.4 97.2 79.0-123 0.206 20 Hexachloro-1,3-butadiene 5.00 4.46 4.98 89.2 99.6 54.0-138 11.0 20 Isopropylbenzene 5.00 4.71 4.79 94.2 95.8 76.0-127 1.68 20 p-Isopropyltoluene 5.00 4.68 5.02 93.6 100 76.0-125 7.01 20 2-Butanone (MEK)25.0 25.9 26.9 104 108 44.0-160 3.79 20 Methylene Chloride 5.00 4.86 4.89 97.2 97.8 67.0-120 0.615 20 4-Methyl-2-pentanone (MIBK)25.0 27.9 27.9 112 112 68.0-142 0.000 20 Methyl tert-butyl ether 5.00 4.62 4.76 92.4 95.2 68.0-125 2.99 20 Naphthalene 5.00 4.08 4.55 81.6 91.0 54.0-135 10.9 20 n-Propylbenzene 5.00 4.77 5.01 95.4 100 77.0-124 4.91 20 Styrene 5.00 4.39 4.67 87.8 93.4 73.0-130 6.18 20 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 15 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 15 of 20 QUALITY CONTROL SUMMARYWG2094839 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1634590-01,02,03,04 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3948701-1 07/14/23 09:28 • (LCSD) R3948701-2 07/14/23 09:47 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% 1,1,1,2-Tetrachloroethane 5.00 4.76 4.90 95.2 98.0 75.0-125 2.90 20 1,1,2,2-Tetrachloroethane 5.00 4.61 4.64 92.2 92.8 65.0-130 0.649 20 Tetrachloroethene 5.00 5.07 5.00 101 100 72.0-132 1.39 20 Toluene 5.00 4.82 4.91 96.4 98.2 79.0-120 1.85 20 1,2,3-Trichlorobenzene 5.00 4.32 4.81 86.4 96.2 50.0-138 10.7 20 1,2,4-Trichlorobenzene 5.00 4.34 4.66 86.8 93.2 57.0-137 7.11 20 1,1,1-Trichloroethane 5.00 5.09 5.13 102 103 73.0-124 0.783 20 1,1,2-Trichloroethane 5.00 4.84 4.97 96.8 99.4 80.0-120 2.65 20 Trichloroethene 5.00 5.17 5.45 103 109 78.0-124 5.27 20 Trichlorofluoromethane 5.00 4.98 5.02 99.6 100 59.0-147 0.800 20 1,2,3-Trichloropropane 5.00 4.84 5.07 96.8 101 73.0-130 4.64 20 1,2,4-Trimethylbenzene 5.00 4.63 4.84 92.6 96.8 76.0-121 4.44 20 1,3,5-Trimethylbenzene 5.00 4.72 4.99 94.4 99.8 76.0-122 5.56 20 Vinyl chloride 5.00 4.70 4.43 94.0 88.6 67.0-131 5.91 20 o-Xylene 5.00 4.65 4.67 93.0 93.4 80.0-122 0.429 20 m&p-Xylenes 10.0 9.81 9.68 98.1 96.8 80.0-122 1.33 20 (S) Toluene-d8 100 102 80.0-120 (S) 4-Bromofluorobenzene 96.7 95.9 77.0-126 (S) 1,2-Dichloroethane-d4 109 109 70.0-130 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 16 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 16 of 20 QUALITY CONTROL SUMMARYWG2096255 Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1634590-01,03 Method Blank (MB) (MB) R3950237-4 07/18/23 20:09 MB Result MB Qualifier MB MDL MB RDL Analyte ug/l ug/l ug/l Benzene U 0.0941 1.00 Methyl tert-butyl ether U 0.101 1.00 (S) Toluene-d8 103 80.0-120 (S) 4-Bromofluorobenzene 102 77.0-126 (S) 1,2-Dichloroethane-d4 113 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3950237-1 07/18/23 18:46 • (LCSD) R3950237-2 07/18/23 19:07 Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/l ug/l ug/l %%%%% Benzene 5.00 5.49 5.05 110 101 70.0-123 8.35 20 Methyl tert-butyl ether 5.00 5.65 5.48 113 110 68.0-125 3.05 20 (S) Toluene-d8 99.1 98.4 80.0-120 (S) 4-Bromofluorobenzene 102 102 77.0-126 (S) 1,2-Dichloroethane-d4 112 114 70.0-130 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 17 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 17 of 20 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. RDL Reported Detection Limit. Rec.Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. (S) Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Dilution If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Limits These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Qualifier This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. Result The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry)Confidence level of 2 sigma. Case Narrative (Cn) A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control Summary (Qc) This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. Sample Chain of Custody (Sc) This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. Sample Results (Sr) This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable; the reported value is an estimate. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 18 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 18 of 20 Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey–NELAP TN002 California 2932 New Mexico ¹TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina ¹DW21704 Georgia NELAP North Carolina ³41 Georgia ¹923 North Dakota R-140 Idaho TN00003 Ohio–VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LAO00356 Kentucky ¹ ⁶KY90010 South Carolina 84004002 Kentucky ²16 South Dakota n/a Louisiana AI30792 Tennessee ¹ ⁴2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas ⁵LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2LA A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2LA – ISO 17025 ⁵1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA–Crypto TN00003 ACCREDITATIONS & LOCATIONS ¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. 1 Cp 2Tc 3Ss 4Cn 5Sr 6Qc 7Gl 8Al 9Sc ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 17:23 19 of 20 ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE: ATC Group Services LLC STL2392601 L1634590 07/19/23 18:26 19 of 20 Auddies #3 ATC Project No. STL2392601 NCDEQ State Lead Program APPENDIX D SITE PHOTOGRAPHS Photo 1: Front of Site – Facing East. Photo 2: MMPE Setup – Facing north. Site Photographs Auddies #3 6071 Old NC Highway 49 Asheboro, Randolph County, North Carolina 2725 E. Millbrook Road, Suite 121 Raleigh, North Carolina (919) 871-0999 FAX (737) 207-8261 Photograph Taken By: Justin Jones NCDEQ Incident #23926 ATC Project No.: STL2392601 Photo 3: MMPE Setup – MW-2, facing south. Photo 4: MMPE Setup – MW-4, facing east. Site Photographs Auddies #3 6071 Old NC Highway 49 Asheboro, Randolph County, North Carolina 2725 E. Millbrook Road, Suite 121 Raleigh, North Carolina (919) 871-0999 FAX (737) 207-8261 Photograph Taken By: Justin Jones NCDEQ Incident #23926 ATC Project No.: STL2392601 Photo 3: MMPE Setup – MW-5, facing east. Photo 4: MMPE Setup – Site, facing east. Site Photographs Auddies #3 6071 Old NC Highway 49 Asheboro, Randolph County, North Carolina 2725 E. Millbrook Road, Suite 121 Raleigh, North Carolina (919) 871-0999 FAX (737) 207-8261 Photograph Taken By: Justin Jones NCDEQ Incident #23926 ATC Project No.: STL2392601