RA-1717_10538_CA_MRP_20230825

ENVIRONMENTAL | CIVIL | GEOTECHNICAL

MONITORING REPORT WILLIAM WATTS STORE 2100 AUBURN ROAD RALEIGH, WAKE COUNTY, NC NCDEQ INCIDENT NO. 10538 RISK CLASSIFICATION: H0350D

AUGUST 25, 2023 NCDEQ CONTRACT NO. N70522-A TASK AUTHORIZATION NO. 01 CATLIN PROJECT NO. 221081 PREPARED FOR: MR. MARK PETERMANN NCDEQ, DWM, UST SECTION 1646 MAIL SERVICE CENTER RALEIGH, NC 27699-1646 PREPARED BY: CATLIN ENGINEERS AND SCIENTISTS 220 OLD DAIRY ROAD WILMINGTON, NC 28405 [phone]
CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585
CORPORATE LICENSURE NO. FOR GEOLOGY SERVICES C-118

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023
TABLE OF CONTENTS
PAGE
1.0 SITE INFORMATION 1
2.0 EXECUTIVE SUMMARY 2
3.0 SCOPE OF SERVICES 3
4.0 SITE HISTORY AND CHARACTERIZATION 3
4.1 UST OWNER AND OPERATOR INFORMATION 3 4.2 UST INFORMATION 3 4.3 CONTAMINANT SOURCE INVENTORY 4 4.4 SITE CHARACTERISTICS 4 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE 4 4.6 RECEPTOR INFORMATION 4 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 5
5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 7
5.1 SOIL AND BEDROCK 7
5.2 HYDROGEOLOGY 7
6.0 SITE ASSESSMENT INFORMATION 7
6.1 GAUGING DATA 8 6.2 SAMPLING DATA 8 6.3 SUMMARY OF GROUNDWATER INFORMATION 9 6.4 EVALUATION OF ASSESSMENT INFORMATION 10
7.0 CONCLUSIONS AND RECOMMENDATIONS 11
8.0 LIMITATIONS 11
9.0 STATEMENTS AND CERTIFICATION 12
10.0 REFERENCES 12

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023
TABLES
TABLE 1 SITE HISTORY – UST AND OTHER RELEASE INFORMATION
TABLE 2 PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA
TABLE 4 SUMMARY OF GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B
TABLE 5 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B
FIGURES FIGURE 1 SITE VICINITY MAP
FIGURE 2 POTENTIAL RECEPTOR MAP
FIGURE 3 SITE MAP
FIGURE 4 GROUNDWATER ELEVATION – JULY 13, 2023
FIGURE 5 MONITORING WELL GROUNDWATER SAMPLE ANALYTICAL RESULTS –
JULY 13, 2023
FIGURE 6 WATER SUPPLY WELL GROUNDWATER SAMPLE ANALYTICAL RESULTS – JULY 13, 2023
APPENDICES
APPENDIX A HISTORICAL DATA
APPENDIX B SITE PHOTOGRAPHS
APPENDIX C DAILY ACTIVITIES LOG AND FIELD DATA SHEETS
APPENDIX D LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 1 August 2023
1.0 SITE INFORMATION
Site Identification
Date: 08/25/2023 Site Risk/Priority Rank: H0350D
UST Number: RA-1717 Incident Number: 10538
Site Name: William Watts Store Facility ID: Unknown
Site Location: 2100 Auburn Road
Nearest City/Town: Raleigh County: Wake
Description of Geographical Data Point: Former Dispenser Island
Location Method: Google Earth
Latitude (decimal degrees): 35.693002° Longitude (decimal degrees): -78.555279°
Contacts Information
Former UST Owner: Mr. William Watts
Address: 3923 St. James Church Rd., Raleigh, NC 27604 Phone: Not Applicable
Former UST Operator: Mr. William Watts
Address: 3923 St. James Church Rd., Raleigh, NC 27604 Phone: Not Applicable
Property Owner: Auburn Road, LLC
Address: 200 US Highway 70E, Garner, NC 27529 Phone: Unknown
Property Occupant: Light of Life Ministries
Address: 2100 Auburn Road, Raleigh, NC 27610 Phone: [phone]
Consultant: CATLIN Engineers and Scientists
Address: 220 Old Dairy Rd., Wilmington, NC 28405 Phone: [phone]
Corporate Licensure No. For Engineering Services: C-0585
Corporate Geology License No.: C-118
Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703
Address: 39 Spruce St., E. Longmeadow, MA 01028 Phone: [phone]
Release Information
Date Discovered: 06/19/1992
Estimated Quantity of Release: Unknown
Cause of Release: Leak in the UST system
Source of Release: UST system or associated fitting(s)
Sizes and contents of UST system(s) from which the release occurred:
• One 1,000-gallon gasoline UST
• One 550-gallon kerosene UST

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 2 August 2023
2.0 EXECUTIVE SUMMARY
The William Watts Store site is located at 2100 Auburn Road, Raleigh, Wake
County, North Carolina. Two underground storage tanks (USTs) were previously
operated at the site. One 1,000-gallon gasoline UST and one 550-gallon kerosene UST were removed from the site in 1993. A petroleum release was discovered when residents noticed gasoline in their potable water supply wells. Petroleum-impacted soils were identified during UST closures.

The purpose of this report is to document the latest groundwater sampling event. On July 13, 2023, CATLIN Engineers and Scientists (CATLIN) personnel measured groundwater at approximately 11.7 feet below the top of casing (BTOC) across the site. Groundwater samples from five monitoring wells and three water supply wells
(WSWs) were collected. One WSW (WSW-9) had a point of entry (POE) treatment
system, and a sample was collected both pre- and post-treatment (influent and effluent). The samples were submitted for laboratory analysis of volatile organic compounds (VOCs) per Standard Method (SM) 6200B plus ethylene dibromide (EDB), methyl tert-butyl ether (MTBE), and diisopropyl ether (DIPE).

Laboratory results did not indicate any dissolved petroleum constituents above their respective Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards (2L GWQS) in the samples collected from monitoring wells MW-1, MW-3R, MW-7, or MW-9. Naphthalene was detected in
the sample from MW-4 at a concentration above its 2L GWQS. Light non-aqueous
phase liquid (LNAPL aka free-phase product) has not been detected at this site. Groundwater flow direction is towards the northwest. Analytical results from the samples from water supply well WSW-9 E (Effluent),
WSW-12, and WSW-24 did not indicate any dissolved petroleum constituents above laboratory reporting limits. The influent sample from water supply well WSW-9 (WSW-9 I) revealed benzene and naphthalene at concentrations which exceeded their 2L GWQS as well as multiple estimated (“J”-value) and low concentrations of additional constituents.
Contaminant concentrations appear to have decreased in the sample from monitoring well MW-4 since the March 2022 sampling event. CATLIN recommends to:
• Continue to pursue the relocation of WSW-9. On March 18, 2022, Mr. Mark Petermann (NCDEQ) emailed the owner of WSW-9 to see if he was willing to relocate the water supply well on-site. If agreed upon, CATLIN recommends
installing a new water supply well on the parcel, abandon WSW-9 and
installing an additional water supply well on the adjacent property (currently utilizing WSW-9).
• Install a Provectus®-ORS (ORS Sleeve) into monitoring well MW-4 to reduce dissolved contamination.
• Conduct a sampling event approximately 6-months after deployment of the ORS Sleeves.
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 3 August 2023
3.0 SCOPE OF SERVICES The scope of services for this report was performed in general accordance with
CATLIN proposal number 221081.01P, dated July 6, 2023. Services were
authorized by the North Carolina Department of Environmental Quality’s (NCDEQ’s) Task Authorization (TA) #01, accepted on July 7, 2023, and Contract Number N70522-A.
The approved scope of services for this Task Authorization included to:
• Collect monitoring well samples from five monitoring wells (MW-1, MW-3R, MW-4, MW-7, and MW-9);
• Collect water supply well samples from four wells [WSW-2 (if access granted), WSW-9 (influent and effluent), WSW-12, and WSW-24];
• Analyze 12 samples (five monitoring wells, five water supply well samples, one trip blank, and one field blank) per SM 6200B (including EDB, MTBE,
and DIPE);
• Prepare an Annual Monitoring Report documenting the findings. CATLIN personnel were unable to gain access to WSW-2; therefore, this well was
not sampled. The remaining scope of services was conducted in general
accordance with the approved TA. 4.0 SITE HISTORY AND CHARACTERIZATION
The William Watts Store site is located at 2100 Auburn Road, Raleigh, Wake
County, North Carolina (Figures 1 and 2). Summarized available historical sampling and gauging data done by other consultants are provided in Appendix A and site photographs are presented in Appendix B.
4.1 UST OWNER AND OPERATOR INFORMATION
Mr. William Watts owned the two USTs historically operated on-site. The tanks were operated by Watts Store for petroleum retail sales. Upon his passing, ownership was transferred to Mr. Samuel Watts, his son, who did
not participate in the store operation. Mr. William Watts is deceased, and the
site was accepted into the North Carolina UST Section Trust Fund Branch State Lead Program (ATEC, 1994). Available information regarding UST owners/operators is presented on
Table 1.
4.2 UST INFORMATION Reportedly, one 1,000-gallon gasoline and one 550-gallon kerosene UST
were previously operated on-site. The installation dates for the tanks are
unknown and they operated until July 1993 when they were removed from the site (OHM, 1993).
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 4 August 2023
Available UST system information is presented in Table 1 and the approximate former UST basin locations are illustrated on Figure 3.
4.3 CONTAMINANT SOURCE INVENTORY
An on-site release was discovered in June 1992 when residents noticed gasoline in their potable water supply wells. During the tank closure activities in July 1993, approximately 9.91 tons of contaminated soils were excavated
and removed from the site and soil samples were collected. The analytical
results revealed total petroleum hydrocarbons (TPH) above State Action Levels (W&R, 2008; S&ME, 2017). 4.4 SITE CHARACTERISTICS

The property is currently owned by Auburn Road, LLC and it is occupied by Light of Life Ministries church and several residential homes. The parcel is comprised of the church building, several residential homes and structures, trees, grassy areas, and gravel/dirt driveways. Site photographs are
presented in Appendix B.
4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE
Properties in the site vicinity are residential. The site is bounded by Auburn
Road to the north and east with a train track and residences beyond, Gin Street to the west with residences beyond, and residences to the south. 4.6 RECEPTOR INFORMATION
CATLIN performed a receptor survey in September 2021. CATLIN personnel walked a 500-foot radius from the site and performed a windshield survey of all properties within the remaining 1,500 feet from the site. Additionally, Request for Water Supply Well Information Survey letters were sent to all
property owners within 1,000 feet of the site. Information obtained from the field survey and letter responses were compiled with water supply well information provided by S&ME on September 15, 2014 and is summarized below.
Based on utility data and GIS information obtained from correspondence with the City of Raleigh Public Utilities department, municipal water is available to many properties within 1,500 feet of the site. The properties where public water is not currently available, water lines could be extended in those areas to provide connections (CATLIN, 2021).
A total of 24 water supply wells were identified within 1,500 feet. Within 1,000 feet of the site, 17 potable wells are located. Most wells identified during the survey were either confirmed to be potable wells or assumed to be potable
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 5 August 2023
based on municipal water information (CATLIN, 2021). The use of several wells was undetermined and are included as “unknown” on Table 2.
Three surface water bodies were identified within 1,500 feet of the site.
According to CATLIN personnel observations during the receptor survey, three unnamed/unclassified small creeks were identified within 1,500 feet of the site (CATLIN, 2021).
Potential receptors are illustrated on Figure 2 and receptor information is
shown on Table 2. 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES
As discussed above, the on-site release was discovered in June 1992 when
residents noticed gasoline in their potable water supply wells. During the tank closure activities in July 1993, soil samples were collected, and the analytical results revealed TPH above State Action Levels. Additionally, a groundwater sample from the on-site potable well was collected and sampled. The
laboratory analytical results indicated that 1,2-dichloroethane was present at
a concentration which exceeded the 2L GWQS (ATEC, 1994; W&R, 2008). Annual water supply well sampling was conducted at the subject site and surrounding wells until February 24, 2000, when the on-site residences were
connected to public water and the on-site water supply well (WSW-1) was
abandoned in August 2000 (MM&A, 2001). Between September 2005 and August 2014, nine monitoring wells were installed and sampled by various consultants. The laboratory analytical
results of samples from monitoring wells MW-3 and MW-4 have historically
detected multiple petroleum constituents at concentrations which exceeded their 2L GWQS. In October 2010, S&ME advanced seven soil borings on the property to varying depths, with soil samples collected at selected intervals. The laboratory analytical results of the soil samples indicated that several
VOCs, carbon fractions, and/or other petroleum constituents were detected in
soil boring SB-1 (to the west of the UST basin) at a depth of five feet below land surface (BLS) at concentrations exceeding their respective Maximum Soil Contaminant Concentrations (MSCCs) or State Action Levels. Monitoring wells MW-3 and MW-6D were abandoned in June 2016 in preparation for the
removal of impacted soil in their vicinity. A total of 128.34 tons of additional
petroleum-impacted soil was removed at this time. Six confirmatory soil samples were collected from the sidewalls of the excavation for laboratory analysis. No target constituents were reported in these samples at concentrations exceeding their respective Soil to Groundwater MSCCs.
Samples were not collected from the base of the excavation due to excessive
moisture. Well MW-3R was later installed as a replacement. Laboratory analytical results from MW-3R have not detected petroleum constituents above 2L GWQS. The surrounding water supply wells have also continued to be sampled and monitored (S&ME, 2010; S&ME, 2016; S&ME, 2017).
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 6 August 2023
Since the release was discovered in June 1992, different water supply wells have been sampled at various times by various consultants (the wells include WSW-1 through WSW-9, WSW-11, WSW-12, WSW-13 through WSW-16,
WSW-18, and WSW-24). Water supply well WSW-9 currently has a POE
treatment system and both influent and effluent samples are collected. Multiple VOCs (including benzene, 1,2-dichloroethane, and naphthalene) have been detected in samples from wells WSW-1 (until it was abandoned) and the influent sample from WSW-9.

CATLIN conducted the most recent monitoring event in September 2021. Monitoring wells MW-1 through MW-5 and MW-7 through MW-9 were sampled as well as three nearby water supply wells (WSW-9 [influent and effluent], WSW-12, and WSW-24). Water supply well WSW-2 was not
sampled due to lack of access. Groundwater laboratory analysis revealed
naphthalene above its 2L GWQS in the MW-4 sample. Multiple petroleum constituents were detected in the WSW-9 influent sample. However, all contaminants were below their corresponding Gross Contaminant Levels (GCLs). No analytes were detected in the WSW-9 (effluent), WSW-12, or
WSW-24 samples (CATLIN, 2021).
CATLIN also performed a receptor survey in September 2021. A total of 24 water supply wells were identified within 1,500 feet of the site. Seventeen active potable wells were identified between 250 and 1,000 feet from the site
and three surface water bodies (small, unnamed creeks) were identified
within 1,500 feet. Public water surface was noted to be available to some, but not all, properties in the site vicinity. Water lines were present along East Garner Road and a water line crosses over to Auburn Road in the vicinity of Antelope Lane and continues to the southeast along Auburn Road (CATLIN
2021).
On March 10, 2022, CATLIN personnel collected groundwater samples from five monitoring wells and three WSWs. Laboratory results from the samples from supply wells WSW-9E (effluent), WSW-12, and WSW-24 did not
indicate any dissolved petroleum constituents above laboratory reporting
limits. The influent sample from water supply well WSW-9 revealed benzene and naphthalene at concentrations which exceeded their 2L GWQS as well as multiple estimated (“J”-value) and low concentrations of additional constituents (CATLIN, 2022).
Summarized available historical monitoring well sampling and gauging data conducted by other consultants are provided in Appendix A.
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 7 August 2023
5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 5.1 SOIL AND BEDROCK

As defined in the Geologic Map of North Carolina, published by the North Carolina Department of Natural Resources and Community Development (1985), the site lies within the Piedmont physiographic province.
The site is underlain by the foliated to massive intrusive granitic rocks of the
Rolesville Suite within the Raleigh Belt. These are megacrystic to equigranular rocks, and the Wise and Lemon Springs intrusives are exposed in the site area.
Boring logs provided in S&ME October 2010 and S&ME September 2014
reports indicate that tan-orange-yellow silty sands and sandy silty clays are present to approximately 45 feet BLS (S&ME, 2010; S&ME, 2014). 5.2 HYDROGEOLOGY

Groundwater - The 2020 Visual Hydrogeologic Framework (VHF) – North Carolina Hydrogeological Database did not identify sufficient boreholes near the site to draw a cross-section.
Surface Water – Three surface water bodies were identified within 1,500 feet
of the site. According to CATLIN personnel observations during the receptor survey, three unnamed/unclassified small creeks were identified within 1,500 feet of the site (CATLIN, 2021).
6.0 SITE ASSESSMENT INFORMATION
CATLIN personnel followed the previously prepared Health and Safety Plan (HASP) when conducting the site visit. CATLIN conducted field activities on July 13, 2023 in general accordance with the approved TA. Upon arrival at the site, potential hazards
were evaluated before beginning field work and are documented on a Daily
Activities Log. The Daily Activities Log is included in Appendix C. Photographs from the site visit are included in Appendix B. CATLIN personnel gauged and collected groundwater samples for laboratory
analysis of VOCs per SM 6200B from five monitoring wells (MW-1, MW-3R, MW-4,
MW-7, and MW-9) and three water supply wells (WSW-9, WSW-12, and WSW-24). Water supply well WSW-9 has a POE treatment system and samples were collected at the influent and effluent locations. CATLIN was unable to gain access to sample water supply well WSW-2, so this well was not sampled. Water supply well locations
are illustrated on Figure 2 and well information is provided in Table 2. Monitoring well locations and site features are shown on Figure 3 and monitoring well construction details are presented in Table 3.
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 8 August 2023
6.1 GAUGING DATA Historically, depth to water has ranged from 7.57 feet BTOC (MW-8, 2016) to
16.68 feet BTOC (MW-5, 2017). The groundwater flow direction has been
towards the northwest (S&ME, 2018). During July 2023 event, CATLIN personnel measured depth to water in five monitoring wells using an electronic water interface probe. To prevent cross
contamination, the probe and cabling were decontaminated according to
manufacturer’s recommendations between use in each well. Gauging data were recorded on an electronic groundwater sampling form using a tablet device. Gauging procedures were performed in general accordance with North Carolina Department of Environmental and Natural Resources
(NCDENR) and NCDEQ Guidelines, and Environmental Protection Agency
(EPA) Region 4 Operating Procedures. Depth to water ranged from 8.83 feet BTOC (MW-9) to 13.38 feet BTOC (MW-4). The depths to water measured in all the gauged wells were within
their respective screened intervals. Based on groundwater elevations calculated for this monitoring period, groundwater flow direction is towards the northwest, which is consistent with the historical groundwater flow direction.
Monitoring well gauging results are presented in Table 3. Groundwater elevations are illustrated on Figure 4 and field data sheets are provided in Appendix C. 6.2 SAMPLING DATA
Following gauging, the monitoring wells and water supply wells were sampled in general accordance with NCDENR and NCDEQ Guidelines, and EPA Region 4 Operating Procedures. Prior to obtaining representative groundwater samples, each monitoring well was purged by removing a
minimum of three well volumes (or bailing the well dry) using a new, disposable bailer. The water supply wells were purged by allowing the spigot to run for approximately 15 minutes. Monitoring well groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua TROLL 600 Multiparameter Sonde (Aqua TROLL). Conductivity, pH,
oxidation reduction potential (ORP), dissolved oxygen, and temperature measurements were recorded utilizing the VuSitu mobile application (version 1.17.12). Groundwater parameter data were transferred from the VuSitu mobile application to the electronic field data sheets. Copies of the field data sheets are available in Appendix C.

After purging activities, a groundwater sample was collected from each well and poured from the bailer directly into appropriate laboratory-provided, pre-preserved glassware, labeled, and placed on ice in an insulated cooler. The water supply well samples were collected directly from either a spigot located
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 9 August 2023
on the well or potentially on the residential structure. These samples were directly into appropriate laboratory-provided, pre-preserved glassware, labeled, and placed on ice in an insulated cooler.

A field blank was collected by pouring water from a new, sealed gallon of distilled water directly into laboratory-provided glassware. The glassware was labeled and placed on ice in an insulated cooler. A laboratory-provided trip blank was maintained in the cooler for the duration of the sampling event.

The groundwater samples, the field blank, and the trip blank were submitted to Con-Test Analytical Laboratory (Certification NC 652 and NC-DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol for analyses described in Section 3.0 Scope of Services. The COC
is included with the analytical report provided Appendix D.
6.3 SUMMARY OF GROUNDWATER INFORMATION Historically, samples from monitoring well MW-3 have revealed the highest
concentrations of petroleum constituents. However, since additional soil
excavation was conducted in 2016 near former MW-3, MW-4 has exhibited the highest petroleum constituent concentrations. During the previous sampling event conducted by CATLIN in March 2022, the sample from MW-4 contained VOCs at concentrations above the 2L GWQS. Summarized
available historical gauging and sampling data from other consultants are
provided in Appendix A. The latest groundwater sampling laboratory results for SM 6200B analysis are summarized in Table 4 and historical results are in Table 5. Monitoring
well sample analytical results are illustrated on Figure 5 and water supply well results are summarized on Figure 6. A copy of the complete laboratory report and COC documentation are in Appendix D. Monitoring Wells
During the July 2023 monitoring event, five monitoring well groundwater samples (MW-1, MW-3R, MW-4, MW-7, and MW-9) were collected and submitted for analysis via SM 6200B (including EDB, MTBE, and DIPE). Laboratory results did not indicate any dissolved petroleum constituents
above their respective laboratory reporting limits in the samples from monitoring wells MW-1, MW-3R, MW-7, or MW-9. Multiple VOCs were detected in the sample from MW-4 at concentrations greater than their respective laboratory reporting limits, including naphthalene at a concentration above its 2L GWQS.

Water Supply Wells
Laboratory analytical results per SM 6200B (including EDB, MTBE, and DIPE) did not indicate any dissolved petroleum constituents above their
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 10 August 2023
respective laboratory reporting limits in the samples from water supply wells WSW-9 (Effluent), WSW-12, and WSW-24. The influent sample from water supply well WSW-9 (WSW-9 I) contained several contaminant concentrations
above the laboratory method detection limits, including benzene and
naphthalene at concentrations which exceeded their 2L GWQS.
Field Blank and Trip Blank
One field blank sample and one laboratory-provided trip blank sample were
submitted for analysis per SM 6200B (including EDB, MTBE, and DIPE). Laboratory analysis of the field blank sample detected an estimated (“J”-value) concentration of acetone. No additional targeted analytes were detected in the field blank sample. No targeted analytes were detected in the
trip blank sample.
6.4 EVALUATION OF ASSESSMENT INFORMATION Extent of Contamination

Naphthalene was detected above its 2L GWQS in the MW-4 sample. A summary of monitoring well groundwater sample analytical results is illustrated on Figure 5. The highest contaminant concentrations have historically been reported in samples from MW-4. The concentrations in the
sample from MW-4 collected during this monitoring event revealed
concentrations lower than those reported during the previous event in March 2022 (CATLIN, 2022). Additionally, laboratory analytical results of the pre-treatment water supply
well sample WSW-9 I revealed benzene and naphthalene concentrations
which exceeded their respective 2L GWQS. Cleanup Levels Achieved
Soil – To date, 138.25 tons of impacted soil have been removed from the site. Laboratory analysis via EPA Method 8260B and Massachusetts Department of Environmental Protection (MADEP) volatile petroleum hydrocarbon (VPH) methods of the soil samples obtained from the post-excavation activities in 2016 indicated that petroleum constituent
concentrations did not exceed the MSCCs (S&ME, 2016).
Groundwater – Groundwater contaminant concentrations are above 2L GWQS at the site, both in a monitoring well (MW-4) and a water supply well (WSW-9).

LNAPL – LNAPL has not been detected at this site.
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 11 August 2023
7.0 CONCLUSIONS AND RECOMMENDATIONS

Conclusions

Groundwater monitoring findings for this period are summarized below:
• Five monitoring wells (MW-1, MW-3R, MW-4, MW-7, and MW-9) were
sampled.
• Three water supply wells (WSW-9, WSW-12, and WSW-24) were sampled.
• Water supply well WSW-2 was not sampled due to lack of access.
• Naphthalene was revealed as above its 2L GWQS in MW-4.
• Contaminant concentrations in MW-4 have decreased since the March 2022
sampling event.
• Petroleum constituents which exceeded their 2L GWQS were detected in the
pre-treatment WSW-9 I sample.
• No petroleum constituents were detected in the WSW-9 Effluent, WSW-12,
or WSW-24 samples.
• Groundwater flow was found to be in the northwest direction.

Beginning in the summer of 2023, discussions between Wake County, the Town of
Garner, and the NCDEQ State Lead Program have been on-going concerning
connecting the area in the vicinity of the subject site to municipal water. A public
meeting is scheduled for September 12, 2023 to gage interest.

Recommendations

CATLIN recommends to:
• Pending the outcome of the September 12th public meeting, connect nearby
parcels to municipal water if it becomes available.
• Install an ORS Sleeve into monitoring well MW-4 to reduce dissolved
contamination.
• Conduct a sampling event approximately 6-months after deployment of the
ORS Sleeves.

8.0 LIMITATIONS

The groundwater samples analyzed as part of this investigation only provide isolated
data points and may not represent conditions at every location in the project area.
Analyses and conclusions of this report, being based on interpolation between data
points at the project area, may not be completely representative of all site
conditions. Conclusions and recommendations of this investigation and report are
based on the best available data in an effort to comply with current regulatory
requirements.

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 12 August 2023
9.0 STATEMENTS AND CERTIFICATION

1 Enter the date the monitoring report was due. August 25, 2023
Will this report be submitted after the established due date?
NO
2 Was any required information from the above template missing from this report?

YES
No cross sections are provided. Adequate subsurface information is not available.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved in the Corrective Action Plan not be met?

NA
No CAP has been submitted for this site.
4 Does any known or suspected source zone soil contamination or free product remain outside of the assessed area that could be inhibiting natural attenuation?
NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a potential new release from a separate onsite or offsite source? NO
6 Certification:
I, Sean J. O’Neil, a Licensed Engineer for CATLIN Engineers and Scientists, do certify that the
information contained in this report is correct and accurate to the best of my knowledge.

CATLIN Engineers and Scientists is licensed to practice engineering in North Carolina. The
certification number of the company or corporation is C-0585.

10.0 REFERENCES

ATEC Associates, Inc., Initial Investigation, William Watts Store, 2100 Auburn Road,
Auburn, NC (Wake County), DEM Task Number 10538-2, September 23,
1994.
CATLIN Engineers and Scientists, Monitoring Report, William Watts Store, 2100
Auburn Road, Raleigh, Wake County, North Carolina, NCDEQ Incident No.
10538, Risk Classification: H0350D, October 7, 2021.
CATLIN Engineers and Scientists, Monitoring Report, William Watts Store, 2100
Auburn Road, Raleigh, Wake County, North Carolina, NCDEQ Incident No.
10538, Risk Classification: H0350D, April 7, 2022.
Horton, J. Wright, Jr. and Victor A. Zullo, An Introduction to the Geology of the
Carolinas: The Geology of the Carolinas, pp 1-11.

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 13 August 2023
Marshall Miller & Associates, Water Supply Well Annual Monitoring Report, Watts
Store, 2100 Auburn Road, Garner, Wake County, NC, Incident No. 10538, November 27, 2001.
Narkunas, J., Groundwater Evaluation in the Central Coastal Plain of North
Carolina, North Carolina Department of Natural Resources and Community
Development, 1980, pp 119.
NCDEQ, Division of Water Resources, 2020 Visual Hydrogeologic Framework, North Carolina Hydrogeological Database, ncwater.org/?page=350.
NCDEQ, UST Section, North Carolina Department of Environmental Quality,
Division of Waste Management, Corrective Action Guidelines, January 19, 2021.
NCDENR, UST Section, North Carolina Department of Environment and Natural Resources, Division of Waste Management, Guidelines for Sampling,
December 1, 2013.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Site Checks, Tank Closure,
and Initial Response and Abatement, January 19, 2021.
North Carolina Department of Natural Resources and Community Development,
Geological Map of North Carolina, 1985.
OHM Corporation, UST Closure and Site Sensitivity Evaluation Report, August 31, 1993.
S&ME, Inc., Groundwater Monitoring Report, Former William Watts Store, 2100 Auburn Road, Raleigh, Wake County, NC, 27610, NCDENR Incident No.
10538, October 15, 2010.
S&ME, Inc., Groundwater Monitoring Report, Former William Watts Store, # 10538,
2100 Auburn Road, Raleigh, Wake County, NC, 27610, September 15, 2014.
S&ME, Inc., Soil Removal Report, William Watts Store, Incident # 10538, 2100 Auburn Road, Raleigh, Wake County, NC, 27610, September 19, 2016.
S&ME, Inc., Groundwater Monitoring Report, Former William Watts Store, # 10538,
2100 Auburn Road, Raleigh, Wake County, NC, 27610, January 18, 2017.
S&ME, Inc., Groundwater Monitoring Report, Former William Watts Store, # 10538,
2100 Auburn Road, Raleigh, Wake County, NC, 27610, February 16, 2018.
U.S. Department of Agriculture, Natural Resources Conservation Service, Web Soil
Survey, https://websoilsurvey.sc.egov.usda.gov/App/WebSoilSurvey.aspx.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field
Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S. EPA Report No. SESDPROC-206-R3, Effective Date December 18, 2015.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Laboratory Services and Applied Science Division, Athens Georgia, Operating Procedure Potable
Water Supply Sampling, Chief, Applied Science Branch, U.S. EPA Report No. ASBPROC-305-R4, Effective Date June 11, 2019.
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 14 August 2023
U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Level and Well Depth Measurement, Striggow, B., U.S. EPA Report No. SESDPROC-105-R3,
Effective Date November 3, 2016.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure –
Groundwater Sampling, Striggow, B., U.S. EPA Report No. SESDPROC-301-R4, Effective Date April 26, 2017.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and
Ecosystem Support Division, Athens Georgia, Operating Procedure – In Situ
Water Quality Monitoring, Chief, Field Services Branch, U.S. EPA Report No. SESDPROC-111-R4, Effective Date March 14, 2018.
Winner, M.D, Jr., and Coble, R.W., Hydrogeologic Framework of the North Carolina
Coastal Plain Aquifer System: U.S. Geological Survey Open File Report 87-
690, 1989, pp 155.
Withers & Ravenel, Phase I Limited Site Assessment, Watts Store, 2100 Auburn
Road, Garner, Wake County, NC, Incident No. 10538, November 11, 2005.
Withers & Ravenel, Additional Site Assessment Report, Watts Store, 2100 Auburn
Road, Garner, Wake County, NC, Incident No. 10538, March 3, 2006.
Withers & Ravenel, Monitoring Report, Watts’ Store, 2100 Auburn Road, Garner,
Wake County, North Carolina, Incident # 10538, W&R Project No. 97505.0, December 30, 2008.

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

TABLES
Page 1 of 1
TABLE 1
SITE HISTORY — UST AND OTHER RELEASE INFORMATION
Incident Name and No.: William Watts Store - 10538
UST ID
Number
Name of
Owner/
Operator
Last
Contents
Previous
Contents
Capacity
(gal)
Construction
Details
Tank
Dimensions
(inches)
Installation
Date
(mm/dd/yy)
Date
Removed
(mm/dd/yy)
1 Gasoline Gasoline 1,000 Unknown Unknown Unknown 07/30/93
2 Kerosene Kerosene 550 Unknown Unknown Unknown 07/30/93
Incident
Number
Material
Released
Date of
Release
(mm/dd/yy)
10538 Kerosene
Gasoline 06/19/92
Information obtained from S&ME (2018).
gal = gallons
Dates of
Ownership/Operation
(mm/dd/yy)
Mr. William
Watts
Description of the Release
Residents began to notice gasoline in their potable water supply well in June of 1992. TPH later discovered in soils
during UST excavation on July 30, 1993.
Unknown - 07/30/93
Unknown - 07/30/93
NCDEQ; 10538_William Watts Store; T1_Site History
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 1 of 4
TABLE 2
Incident Name and No.: William Watts Store - 10538
Well ID Property
Address
Wake County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
WSW-2
2112 Auburn
Road, Raleigh,
NC
1730262960 Wright, Carolyn
C
4736 Gin Street,
Raleigh, NC Potable 430 / SE
Per municipality,no water connection.
Assumed potable.Owner did not answer
door.
WSW-3 4721 Gin Street,
Raleigh, NC 1730260962 Hinton, Ewarja
and Johgre
2700 Adcox Place,
Raleigh, NC Potable 535 / S
Per municipality,no water connection.
Assumed potable.Owner did not answer
door.
WSW-4
2025 Auburn
Road, Raleigh,
NC
1730176649
Mazza, Anthony;
Helguera-
Jimenez, Maria
2025 Auburn Road,
Raleigh, NC Potable 429 / WNW
Per municipality,no water connection.
Assumed potable.Owner did not answer
door.
WSW-5
2036 E. Garner
Road, Raleigh,
NC
1730277241 Watts, Laura;
Gaul, Barbara
132 S, Hiddenbrooke
Drive, Advance, NC Potable 461 / E Per municipality,no water connection.Well
located but no answer. Assumed potable.
WSW-6
2017 E. Garner
Road, Raleigh,
NC
1730270794 JPWR Properties
LLC
2304 Smith Drive,
Clayton, NC Unknown 322 / N
Per municipality,no water connection.
Property appeared vacant and could not
confirm location of well.
WSW-7
2021 E. Garner
Road, Raleigh,
NC
1730271676 JPWR Properties
LLC
2304 Smith Drive,
Clayton, NC Unknown 253 / NNE
Per municipality,no water connection.
Property appeared vacant and could not
confirm location of well.
WSW-8
2021 Auburn
Road, Raleigh,
NC
1730175657 Colley, Kay;
Hinton, Bobbie
3616 Open Sight Ct,
Raleigh, NC Potable 498 / WNW Per municipality,no water connection.Well
located on property. Assumed potable.
WSW-9 4710 Gin Street,
Raleigh, NC 1730177184 Woods, John and
Larry
4710 Gin Street,
Raleigh, NC Potable 370 / SW Influent and Effluent samples were taken
from POE sample.
PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
NCDEQ; 10538_William Watts Store; T2_Receptor Info
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 2 of 4
TABLE 2
Incident Name and No.: William Watts Store - 10538
PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
Well ID Property
Address
Wake County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
WSW-11 4724 Gin Street,
Raleigh, NC 1730168787 Jupiter
Investments LLC
3038 Medlin Drive,
Raleigh, NC Potable 624 / SSW Per municipality,no water connection.Well
located on property. Assumed potable.
WSW-12
2020 Auburn
Road, Raleigh,
NC
1730177385 Newkirk,
Charlene
2020 Auburn Road,
Raleigh, NC Potable 292 / SW Well located on property.Per owner,this
well also serves 4700 Gin Street.
WSW-13
2005 Auburn
Road, Raleigh,
NC
1730174746 Curtis, Foston
and Ethel
2005 Auburn Road,
Raleigh, NC Potable 626 / WNW Per municipality,no water connection.Well
located on property. Assumed potable.
WSW-14
2101 E. Garner
Road, Raleigh,
NC
1730289409 Auburn Estates
MHP LLC
PO Box 1440,
Clayton, NC Unknown 760 / E
Well located on front property and all plots
have a water meter after.Potentially a
community well for the trailerpark.
WSW-15 4737 Gin Street,
Raleigh, NC 1730260529 Pair, Ella 4737 Gin Street,
Raleigh, NC Potable 820 / S Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-16 4741 Gin Street,
Raleigh, NC 1730260499 Williams, Joel 1306 Walnut Street,
Cary, NC Potable 919 / S Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-17
3109 Antelope
Lane, Raleigh,
NC
1730285069 Bannister, David PO Box 324, Garner,
NC Potable 817 / NE Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-18
2208 Auburn
Road, Raleigh,
NC
1730264949 Howell, Mindy PO Box 1657, New
Port, NC Potable 560 / ESE Per municipality,no water connection.Well
noticed on property. Assumed potable.
NCDEQ; 10538_William Watts Store; T2_Receptor Info
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 3 of 4
TABLE 2
Incident Name and No.: William Watts Store - 10538
PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
Well ID Property
Address
Wake County
PIN Number
Owner Name
(Last, First MI)
Owner Mailing
Address Well Use
Distance/
Direction
from
Source Area
(ft.)
Comment
WSW-19
3112 Antelope
Lane, Raleigh,
NC
1730283057 Maldonado, Rene 3112 Antelope Lane,
Raleigh, NC Potable 736 / NNE Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-20
3108 Antelope
Lane, Raleigh,
NC
1730283235 Spinks, Patricia 3108 Antelope Lane,
Raleigh, NC Potable 902 / NNE Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-21
2104 E. Garner
Road, Raleigh,
NC
1730370123 Watts, Laura;
Gaul, Barbara
132 Hiddenbrooke
Drive, Advance, NC Potable 987 / E Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-22
3100 Antelope
Lane, Raleigh,
NC
1730283666 Bently, Allen and
Dixie
1901 Strikland Lane,
Clayton, NC Potable 1,135 / NNE Per municipality,no water connection.Well
noticed on property. Assumed potable.
WSW-23
1837 E. Garner
Road, Raleigh,
NC
1730184702
Broken Wing
Fellowship
Original Freewill
Baptist Church
1009 Bent Oak
Court, Raleigh, NC Unknown 1,320 / NW
Well noticed on property.Fire hydrant
nearby so possible that public water is
available.
WSW-24
2029 Auburn
Road, Raleigh,
NC
1730177672 Taylor, Thornton
and Nancy
2029 Auburn Road,
Raleigh, NC Potable 352 / NW Well was sampled.
WSW-25
1829 E. Garner
Road, Raleigh,
NC
1730181773 McLawhorn,
Benny
1829 E. Garner
Road, Raleigh, NC Unknown 1,496 / NW
Well noticed on property.Fire hydrant
nearby so possible that public water is
available.
WSW-26
3101 Antelope
Lane, Raleigh,
NC
1730285543 Bannister, David
W.
P.O. Box 324,
Garner, NC Potable 1,480 / NW Per municipality,no water connection.Well
noticed on property. Assumed potable.
NCDEQ; 10538_William Watts Store; T2_Receptor Info
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 4 of 4
TABLE 2
Incident Name and No.: William Watts Store - 10538
PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION
Receptor
ID
Distance/
Direction from
Source Area
(ft.)
CREEK 1 410 / N
CREEK 2 555 / SE
CREEK 3 583 / E
Information obtained from field survey conducted on September 10, 2021 and Wake County GIS Viewer (iMaps).
ft. = feet
Description
Runoff / small creek that runs away from the site.
Runoff / small creek that runs away from the site.
Runoff / small creek that runs away from the site.
Location
NW to NE of site
Southeast of site
East of site
NCDEQ; 10538_William Watts Store; T2_Receptor Info
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 1 of 1
TABLE 3
WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA
Incident Name and No.: William Watts Store - 10538
Well ID
Date
Installed
(mm/dd/yy)*
Date Water
Level
Measured
(mm/dd/yy)
Well
Diameter
(inches)
Well
Casing
Depth
(ft. BLS)*
Screened
Interval
(x to y ft.
BLS)*
Bottom
of Well
(ft. BLS)*
Top of
Casing
Elevation*
(ft.)
Free-Phase
Product
Thickness**
Depth to
Groundwater
from Top of
Casing (ft.)
Groundwater
Elevation (ft.)
09/08/21 NMT 12.84 83.56
03/10/22 NMT 13.24 83.16
07/13/23 NMT 12.72 83.68
MW-2 01/23/06 09/08/21 2.0 5.0 5.0-20.0 20.0 97.18 NMT 13.57 83.61
09/08/21 NMT 12.94 83.58
03/10/22 NMT 13.35 83.17
07/13/23 NMT 12.83 83.69
09/08/21 NMT 13.67 83.24
03/10/22 NMT 13.82 83.09
07/13/23 NMT 13.38 83.53
MW-5 09/08/10 09/08/21 2.0 10.0 10.0-20.0 20.0 97.90 NMT 13.97 83.93
09/08/21 NMT 10.65 83.42
03/10/22 NMT 11.04 83.03
07/13/23 NMT 10.62 83.45
MW-8 08/07/14 09/08/21 2.0 5.0 5.0-20.0 20.0 91.31 NMT 8.50 82.81
09/08/21 NMT 8.90 83.28
03/10/22 NMT 9.16 83.02
07/13/23 NMT 8.83 83.35
NMT = No Measurable Thickness
* = Data obtained from S&ME (2018).
20.0 96.40
5.0 5.0-20.0 20.0 96.52
** = if free-phase product is present in a well, ground water elevation should be calculated by : [top of casing elevation - depth to water]+ [free product thickness x specific gravity
of the fuel type]
ft. BLS = feet Below Land Surface
MW-7 08/07/14
MW-9 08/07/14 2.0
5.0 5.0-20.0 20.0
5.0 5.0-20.0 20.0 92.18
2.0
2.0
2.0
2.0
94.07
MW-1 09/28/05
MW-3R 10/01/16
MW-4 09/08/10 10.0 10.0-20.0 20.0 96.91
7.0 7.0-20.0
NCDEQ; 10538_William Watts Store; T3_Well Construction & Gauging
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 1 of 1
TABLE 4
SUMMARY OF GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B
Incident Name and No.: William Watt's Store - 10538
Well
Type
Well/
Sample ID
Date
Collected
MW-1 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 0.23 J <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
MW-3R 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
MW-4 07/13/23 <2.0 <0.18 5.9 5.0 1.5 <0.14 34 14 11 <0.17 21 15 <0.17 160 7.2 5.78 J BMDL
MW-7 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
MW-9 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
WSW-9 I 07/13/23 <2.0 48 0.33 J 0.38 J 0.31 J <0.14 <0.22 4.0 <0.13 0.19 J 30 <0.12 0.29 J 0.84 <0.15 <0.73 BMDL
WSW-9 E 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
WSW-12 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
WSW-24 07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
07/13/23 3.0 J <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
07/13/23 <2.0 <0.18 <0.15 <0.13 <0.14 <0.14 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.20 <0.15 <0.73 BMDL
All results in micrograms per liter (µg/L).
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
I / E = Influent / Effluent
GCL = Gross Contaminant Level
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
Bold results indicate concentrations above 2L GWQS.
< = Less than Method Detection Limit
J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag).
GCL (µg/L)
2L GWQS (µg/L)
6,000,000
6,000
5,000
1 tert-Butylbenzene 5,900
70
8,800
70
14,750
70MonitoringWater SupplyField Blank / FB
Contaminant of
Concern
Acetone Benzene sec-Butylbenzene n-ButylbenzeneEthylbenzenep-Isopropyltoluene(p-Cymene)Chloroform Trip Blank / TB
28,500
400
700
0.7
20,000
20 Naphthalene Isopropylbenzene (Cumene)All Other SM 6200B AnalytesTetrachloroethylene70,000
70 1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneTotal XylenesMethyl tert-Butyl Ether (MTBE)Varies
Varies
80,000
600
30,500
70
11,700
25
6,000
6
26,100
70
50,000
500
24,100
400
NCDEQ; 10538_William Watts Store; T4_GW Results
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023
Page 1 of 1
TABLE 5
SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B
Incident Name and No.: William Watt's Store - 10538
Well
Type
Well/
Sample ID
Date
Collected
(mm/dd/yy)
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 0.23 J <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
MW-2 09/08/21 <2.4 <0.13 <1.9 <0.14 0.13 J <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 0.12 J <0.10 <0.27 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
09/08/21 <9.4 <0.52 <7.5 11 4.4 1.5 J BMDL <1.30 ƚ 110 20 13 BMDL 46 17 BMDL 0.60 J 280 69 80.90 BMDL
03/10/22 11 J <0.80 36 18 8.1 2.7 BMDL <1.2 ƚ 160 30 25 <0.69 67 31 <0.75 ƚ <0.90 480 78 59.3 BMDL
07/13/23 <2.0 <0.18 <1.7 5.9 5.0 1.5 <0.14 <0.30 34 14 11 <0.17 21 15 <0.17 <0.22 160 7.2 5.78 J BMDL
MW-5 09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
MW-8 09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL 0.12 J <0.10 <0.10 <0.27 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL 0.11 J <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
09/08/21 <2.4 32 <1.9 0.22 J 0.32 J 0.33 J BMDL 1.6 <0.090 4.0 <0.090 BMDL 29 <0.080 BMDL 0.12 J 0.85 <0.10 0.29 J BMDL
03/10/22 <2.0 61 <1.6 0.46 J 0.60 0.52 BMDL <0.31 <0.21 6.1 0.48 J 0.29 J 43 <0.086 0.38 J <0.22 1.6 <0.11 <0.69 BMDL
07/13/23 <2.0 48 <1.7 0.33 J 0.38 J 0.31 J <0.14 <0.30 <0.22 4.0 <0.13 0.19 J 30 <0.12 0.29 J <0.22 0.84 <0.15 <0.73 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
09/08/21 <2.4 <0.13 <1.9 <0.14 <0.10 <0.090 BMDL <0.32 <0.090 <0.10 <0.090 BMDL <0.15 <0.080 BMDL <0.11 <0.10 <0.10 <0.27 BMDL
03/10/22 <2.0 <0.20 <1.6 <0.15 <0.11 <0.13 BMDL <0.31 <0.21 <0.11 <0.097 <0.17 <0.24 <0.086 <0.19 <0.22 <0.20 <0.11 <0.69 BMDL
07/13/23 <2.0 <0.18 <1.7 <0.15 <0.13 <0.14 <0.14 <0.30 <0.22 <0.15 <0.13 <0.17 <0.38 <0.12 <0.17 <0.22 <0.20 <0.15 <0.73 BMDL
All results in micrograms per liter (µg/L).
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
GCL = Gross Contaminant Level
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
Bold results indicate concentrations above 2L GWQS.< = Less than Method Detection Limit
ƚ = The Method Detection Limit is above the 2L GWQS.
J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag).
400
0.4
GCL (µg/L)
2L GWQS (µg/L)
6,000,000
6,000
5,000
1
4,000,000
4,000
5,900
70
8,800
70
14,750
70
70,000
70
28,500
400
24,100
400
50,000
500
Varies
Varies
80,000
600
30,500
70
11,700
25
6,000
6
26,100
70
260,000
600
20,000
20
700
0.7 All Other SM 6200B Analytestert-Butylbenzene 1,2-Dichloroethane EthylbenzeneIsopropylbenzene (Cumene)p-Isopropyltoluene(p-Cymene)Naphthalene n-PropylbenzeneToluene 1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesMethyl tert-Butyl Ether (MTBE)TetrachloroethyleneChloroform sec-Butylbenzene Contaminant of
Concern
Acetone Benzene 2-Butanone (MEK)n-ButylbenzeneMonitoringWSW-9
Influent
WSW-9
Effluent
WSW-12Water SupplyWSW-24
MW-1
MW-3R
MW-4
MW-7
MW-9
NCDEQ; 10538_William Watts Store; T5_Historical GW Results
CATLIN Project No. 221081
CATLIN Engineers and Scientists
August 2023

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

FIGURES
FIGUREPROJECTTITLE
1WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC SITE VICINITY MAP
SITE LOCATION
INTERSTATE 40
AUBURN RD
Copyright:© 2013 National Geographic Society, i-cubed
2,000 0 2,000 4,0001,000
Feet
³
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
FIGUREPROJECTTITLE
2WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC POTENTIAL RECEPTOR MAP
!(P
!(P
!(P !(P
!(P
!(P
!(P
!(P
!(P!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P!(P
!(P
!(P
!(P
!(P
!(P
SITE LOCATION
1 ,5 0 0 F EET RADIUS
INTERSTATE 40
AUBURN RD
WSW-6
WSW-7WSW-24
WSW-12
WSW-9
WSW-3
WSW-2WSW-18
WSW-22
WSW-20
WSW-17
WSW-19
WSW-25
WSW-24
WSW-14
WSW-21
WSW-5
WSW-11
WSW-15
WSW-16
WSW-13
WSW-8WSW-4
WSW-26
500F E E T RADIUS
CREEK 2
CREEK 3
CREEK 1
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
500 0 500 1,000250
Feet
³
NOTE: Well locations were obtained from a field survey conducted on September 10, 2021 and are approximate.
LEGEND
!(P Active Potable
Water Supply Well
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
FIGUREPROJECTTITLE
3WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC SITE MAP
!>
!>
!>
!>!>!>!>
!>!>
!>
AUBURN RD
MW-8
MW-7
MW-9
MW-4
MW-1
MW-3 MW-6DMW-3R
MW-2
MW-5
FORMERDISPENSER ISLAND
FORMER 550-GAL.KEROSENE UST
FORMER 1,000-GAL.GASOLINE UST
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
30 0 30 6015
Feet
³
NOTE: Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
Parcel Boundary
LEGEND
Monitoring Well
(Type II)!>
Approximate Location
of Former UST System
Abandoned Monitoring Well (Type II)!>
FIGUREPROJECTTITLE
4WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC
GROUNDWATER ELEVATION –JULY 13, 2023
!>
!>
!>
!>
!>
!>!>
!><AUBURN RD
MW-8
MW-7(83.45)
MW-9(83.35)
MW-4(83.53)
MW-1(83.68)
MW-3R(83.69)
MW-2
MW-583.5083.6083.40Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
30 0 30 6015
Feet
³
NOTES: 1. Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.2. The groundwater elevation contour interval is 0.10 feet.
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
Parcel Boundary
LEGEND
Monitoring Well(Type II)!>
Approximate Location of Former UST System
Gauged Monitoring Well (Type II)!>
Groundwater FlowDirection
Groundwater Contour<Groundwater Elevation (Feet)(##)
FIGUREPROJECTTITLE
5WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC
MONITORING WELLGROUNDWATER SAMPLEANALYTICAL RESULTS –JULY 13, 2023
!>
!>
!>
!>
!>
!>!>
!>
AUBURN RD
MW-8
MW-7
MW-9
MW-4
MW-1
MW-3R
MW-2
MW-5
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
30 0 30 6015
Feet
³
NOTE: Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
Parcel Boundary
LEGEND
Monitoring Well(Type II)!>
Approximate Location of Former UST System
Sampled Monitoring Well (Type II)!>
DateCollected
07/13/23 <0.3807/13/23 <0.3807/13/23 2107/13/23 <0.3807/13/23 <0.38
All results in micrograms per liter (µg/L).Bold results are above 2L GWQS. Refer to Table 4 for all results and notes.
SUMMARY OF GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
6,0006Naphthalene Incident Name and No.: William Watts Store - 10538
GCL (µg/L)2L GWQS (µg/L)
Contaminant of Concern
MW-4
Well/ SampleIDMW-1MW-3R
MW-7MW-9
FIGUREPROJECTTITLE
6WILLIAM WATTS STORE2100 AUBURN ROADRALEIGH, NC
WATER SUPPLY WELLGROUNDWATER SAMPLEANALYTICAL RESULTS –JULY 13, 2023
!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P
!(P!(P
!(P
!(P
!(P
!(P
!(P
AUBURN RD
WSW-8WSW-4
WSW-5
WSW-9
WSW-3
WSW-2
WSW-7
WSW-6
WSW-26
WSW-16
WSW-15
WSW-11
WSW-13
WSW-14
WSW-21
WSW-23
WSW-25
WSW-22
WSW-20
WSW-19 WSW-17
WSW-24
WSW-12
WSW-18
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
300 0 300 600150
Feet
³
NOTE: Well locations were obtained from a field survey conducted on September 10, 2021 and are approximate.
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10538221081AUG 2023 AS SHOWN KMC/SJO
LEGEND
!(P Active PotableWater Supply Well
!(P Sampled PotableWater Supply Well
Parcel Boundary
DateCollected
07/13/23 48 0.33 J 0.38 J 0.31 J 4.0 0.19 J 30 0.29 J 0.8407/13/23 <0.18 <0.15 <0.13 <0.14 <0.15 <0.17 <0.38 <0.17 <0.2007/13/23 <0.18 <0.15 <0.13 <0.14 <0.15 <0.17 <0.38 <0.17 <0.2007/13/23 <0.18 <0.15 <0.13 <0.14 <0.15 <0.17 <0.38 <0.17 <0.20
All results in micrograms per liter (µg/L).Bold results are above 2L GWQS. Refer to Table 4 for all results and notes.
28,500400
WSW-12WSW-9 EWSW-9 I
5,0001
WSW-24 GCL (µg/L)2L GWQS (µg/L) 6,00065,90070 8,80070 14,75070 30,50070 20,00020 7000.7
SUMMARY OF GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
Contaminant of Concern
1,2,4-TrimethylbenzeneWell/ SampleID Benzene Incident Name and No.: William Watts Store - 10538
Naphthalene n-Butylbenzenesec-Butylbenzene tert-Butylbenzene Isopropylbenzene (Cumene)Methyl tert-Butyl Ether (MTBE)Tetrachloroethylene

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

APPENDICES

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

APPENDIX A HISTORICAL DATA
TABLE 1UST OWNER/OPERATOR INFORMATIONUST Incident Name (Incident No. 10538, UST #: RA-1717)2100 Auburn Road, Raleigh, Wake County, North CarolinaS&ME Project # 4305-17-132AUST Facility ID # RA-171712Notes:Information collected from Wake County GIS and The NCDEQ Regional Underground Storage Tank Database updated March 3, 2017Unknown3923 St. James Church Rd., Raleigh, NC 27604AddressIncidentNumberTelephone NumberOwner or Operator?UST/AST IDNumber(s)Name of Owner or OperatorDates of Ownership / OperationSamuel Watts Unknown to 7/30/1993 10538 BothAPPENDIX A HISTORICAL DATA (S&ME, 2017)NCDEQ; 10538_William Watts Store CATLIN Project No. 221081CATLIN Engineers and Scientists August 2023
TABLE 2UST INFORMATIONUST Incident Name (Incident No. 10538, UST #: RA-1717)2100 Auburn Road, Raleigh, Wake County, North CarolinaS&ME Project # 4305-17-132AUST Facility ID # RA-1717USTID NumberCurrent/LastContents *PreviousContents *Capacity(gallons)Construction Details **Tank DimensionsD/L (ft)Description of Associated Piping and PumpsDate USTInstalled Status of UST ***Was ReleaseAssociated WithUST System?(Yes/No)1 Gasoline Gasoline 1,000 Unknown Unknown Unknown Unknown Permanently closed by removal (7/30/93) Yes2 Kerosene Kerosene 500 Unknown Unknown Unknown Unknown Permanently closed by removal (7/30/93) YesAPPENDIX A HISTORICAL DATA (S&ME, 2017)NCDEQ; 10538_William Watts Store CATLIN Project No. 221081CATLIN Engineers and Scientists August 2023
TABLE 3
MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER ELEVATIONS
UST Facility ID # RA-1717
Well
ID
Date
Installed
Date
Water Level
Measured
Well
Casing
Depth
(ft BGS)
Well
Casing
Diameter
(in)
Depth
of Well
(ft-BGS)
Top of
Casing
Elevation*
(ft)
Depth to
Water
from Top
of Casing
(ft)
Free
Product
Thickness
(ft)
Groundwater
Elevation
(ft)
Latitude
(decimal)
Longitude
(decimal)
11/11/08 15.20 0.00 81.20
09/08/10 13.16 0.00 83.24
08/07/14 11.94 0.00 84.46
10/13/16 12.04 0.00 84.36
12/21/17 15.13 0.00 81.27
11/11/08 15.98 0.00 81.20
09/08/10 13.89 0.00 83.29
08/07/14 12.57 0.00 84.61
10/13/16 12.80 0.00 84.38
12/21/17 15.92 0.00 81.26
11/11/08 15.36 0.00 81.51
09/08/10 13.60 0.00 83.27
08/07/14 12.44 0.00 84.43
Well Abandoned
10/13/16 12.15 0.00 84.37
12/21/17 15.22 0.00 81.30
09/09/10 13.70 0.00 83.21
08/07/14 12.62 0.00 84.29
10/13/16 12.64 0.00 84.27
12/21/17 15.60 0.00 81.31
09/09/10 14.57 0.00 83.33
08/07/14 13.16 0.00 84.74
10/13/16 13.34 0.00 84.56
12/21/17 16.68 0.00 81.22
09/09/10 13.96 0.00 83.23
08/08/14 12.88 0.00 84.31
Well Abandoned
08/08/14 9.85 0.00 84.22
10/14/16 9.79 0.00 84.28
12/21/17 12.79 0.00 81.28
08/08/14 7.83 0.00 83.48
10/13/16 7.57 0.00 83.74
12/21/17 10.21 0.00 81.10
08/08/14 8.05 0.00 84.13
10/13/16 8.02 0.00 84.16
12/21/17 10.93 0.00 81.25
ft = feet
in = inches
ft-BGS = feet below ground surface
-78.553000
-78.555275
35.692991
35.693041
-78.555291
-78.555367
35.692935
35.693001
30.0 94.07
-78.555492
35.692922 -78.555129
35.692998 -78.555264
-78.555254
35.693312 -78.555532
35.693151
35.693082
Well Abandoned
Well Abandoned
5-20
10-20
97.19
96.52
96.8720.05-20
97.1820.05-20
9/8/2010
2.0
97.9020.0
20.0
20.0
96.912.0
2.01/23/2006
2.010/1/2016
9/8/2010
UST Incident Name (Incident No. 10538, UST #: RA-1717)
Screen
Interval
(ft-BGS)
MW-1 9/28/2005 2.0 20.0 96.400-7 7-20 -78.555412
2100 Auburn Road, Raleigh, Wake County, North Carolina
S&ME Project # 4305-17-132A
1/23/2006
35.692927
MW-2
MW-3R
MW-9
MW-5
44.0
10-20
39-44
5-20
MW-6D 9/9/2010 2.0
MW-7 8/7/2014 2.0
2.00-10
0-39
0-5
MW-4
0-5
0-5
0-5
0-10
MW-3
2.0
92.1820.0
MW-8 8/7/2014
2.08/7/2014 0-5
0-5 5-20
5-20
20.0 91.31
APPENDIX A
HISTORICAL DATA (S&ME, 2017)
NCDEQ; 10538_William Watts Store CATLIN Project No. 221081 CATLIN Engineers and Scientists August 2023
UST Facility ID # RA-1717Well IDAddressOwnerApproximate Distance and Direction from SiteWell In UseWSW-24736 Gin Street Carolyn Christmas and James Ralph Wright462 feet southwestYesWSW-34721 Gin Street Ewarja Dasberey and Johgre J. L. Hinton505 feet south, southwestYesWSW-6 2017 E. Garner RoadJPWR Properties LLC313 feet northYesWSW-7 2021 E. Garner RoadJPWR Properties LLC240 feet northeastYesWSW-94710 Gin StreetJohn Henry Jr. and Larry Carlton Woods 300 feet south, southwest YesWSW-12 2020 Auburn Road Charlene B. Newkirk 240 feet southwest YesWSW-18 2208 Auburn Road Mindy Anne Howell 565 feet southeast YesWSW-24 2029 Auburn Road Hazel McClamb 272 feet northwest YesNotes:Information collected from Wake County GIS Parcel Data, dated September 2017WATER SUPPLY WELL INFORMATIONTABLE 4S&ME Project # 4305-17-132A2100 Auburn Road, Raleigh, Wake County, North CarolinaUST Incident Name (Incident No. 10538, UST #: RA-1717)APPENDIX A HISTORICAL DATA (S&ME, 2017)NCDEQ; 10538_William Watts Store CATLIN Project No. 221081CATLIN Engineers and Scientists August 2023
TABLE 5SUMMARY OF HISTORICAL AND CURRENT GROUNDWATER ANALYTICAL RESULTSUST Incident Name (Incident No. 10538, UST #: RA-1717)2100 Auburn Road, Raleigh, Wake County, North CarolinaS&ME Project # 4305-17-132AUST Facility ID # RA-1717Standard Method 6200B or equivalentWellIDDateCollected11/11/2008 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA9/8/2010 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA8/7/2014 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA10/13/2016 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.75 J11/11/2008 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA9/8/2010 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA8/7/2014 NA --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA10/13/2016 14 J --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---11/11/2008 --1.5 40 140 800--- ---6.5 2 200 33---21 430 150---1.5NA9/8/2010 ---1.7 39 273 1,451--- --- --- ---324 58.8---55.6 788 235--- --- NA8/7/2014 NA ---44.6 219 1,095--- --- --- ---249 35.4---36.3 533 188--- --- NA10/14/2016 26 J ---0.49 0.7 5--- 0.27 J --- --- 0.83 ---0.17 J0.27 J4.4 1.8--- --- NA12/21/2017 --- --- --- ---1.3--- --- --- --- 1.8 0.200.17---3.0 0.14--- --- ---9/9/2010 --- ---5.8 69.5 256--- --- --- ---98.5 26.3---22.6490189--- --- NA8/7/2014 NA ---3.8 15.8 86.1--- --- --- ---20.6 10.8---5.7 2.9 55--- --- NA10/13/2016 --- 0.3810 38 160 3.2 J 20 5.9 1.7 26 15 18 11.0 150 79--- --- NA12/21/2017 -- ---6.6 43 118 20 15 3.6 1.3 37 11 15 9.0 200 60--- --- ---9/9/2010 -- -- -- -- --- --- --- --- --- --- --- --- --- --- --- --- --- NA8/7/2014 -- -- -- -- --- --- --- --- --- --- --- --- --- --- --- --- --- NA10/13/2016 11 J -- -- -- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 11 J --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.23 J9/10/2010 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA8/8/2014 NA --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA8/8/2014 NA --- ---2--- --- --- --- --- --- --- --- --- --- --- --- --- NA10/14/2016 7.9 J --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---8/8/2014 NA --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA10/14/2016 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---8/8/2014 NA --- --- ---20--- --- --- --- --- --- --- --- --- --- --- --- NA10/13/2016 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- NA12/21/2017 --- --- 0.31 J --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---WSW-9 12/21/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---WSW-9 Effluent 12/27/2017 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---WSW-9 Influent 12/27/2017 ---58--- --- 0.65 J --- 0.47 J 0.41 J 0.37 J42 3.5--- --- --- ---2.2--- ---6,000 1 600 600 500 4,000 70 70 70 6 70 25 70 400 400 70 70 706,000,000 5,000 260,000 84,500 85,500 4,000,000 6,900 8,500 15,000 6,000 25,000 11,700 30,000 28,500 25,000 70,000 70,000 70,000Notes:Analytes that are not shown for the method were not detected.Concentrations are reported in micrograms per liter (μg/L).2L Standard: North Carolina Groundwater Quality Standards: 15A NCAC 2L.0202Concentrations exceeding the 2L Standards are shown in Shaded and BOLD fields.Concentrations exceeding the laboratory's reporting limits are shown in BOLD fields.NA: Analysis for sample not requested.GCL - Gross Contamination Level--- : Not detected above laboratory reporting limits.ChloroformTotal Xylenes1,2,4-Trimethylbenzenen-Propylbenzene1,3,5-TrimethylbenzeneStyrene1,2-DichloroethaneAnalytical Method ĺContaminant of Concern ĺp-Isopropyltoluenesec-butylbenzeneNaphthalenetert-butylbenzene2-ButanoneIsopropylbenzenen-butylbenzeneEthylbenzeneTolueneAcetoneBenzene2L Standard (μg/L) GCL (μg/L) MW-5MW-3RMW-1MW-2MW-4MW-3MW-9MW-6DMW-7MW-8APPENDIX A HISTORICAL DATA (S&ME, 2017)NCDEQ; 10538_William Watts Store CATLIN Project No. 221081CATLIN Engineers and Scientists August 2023

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

APPENDIX B SITE PHOTOGRAPHS
APPENDIX B SITE PHOTOGRAPHS – JULY 13, 2023
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists CATLIN Project No. 221081 August 2023

View of site, facing south-southwest.

View of MW-1, facing south-southwest.
APPENDIX B SITE PHOTOGRAPHS – JULY 13, 2023
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists CATLIN Project No. 221081 August 2023

View of MW-3R, facing south-southwest.

View of MW-4, facing east.
APPENDIX B SITE PHOTOGRAPHS – JULY 13, 2023
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists CATLIN Project No. 221081 August 2023

View of MW-7, facing west-northwest.

View of MW-9, facing north.
APPENDIX B SITE PHOTOGRAPHS – JULY 13, 2023
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists CATLIN Project No. 221081 August 2023

View of system for WSW-9.

Closer view of sampling points labelled.
APPENDIX B SITE PHOTOGRAPHS – JULY 13, 2023
NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists CATLIN Project No. 221081 August 2023

View of sampling point for WSW-12.

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

APPENDIX C
DAILY ACTIVITIES LOG
AND FIELD DATA SHEETS

CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
MW-1 7.28
12.72 1.188
NMT 3.564
20 5.940
2
Method:Bailer Purge Start Time:11:28
Required Bails for 3 Well Volumes:15 Purge Stop Time:11:44
Required Bails for 5 Well Volumes:25 Was Well Purged Dry?Yes
Number of Bails Removed:12.5 Sample Time:11:48
Groundwater Removed (gal):3.0
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
11:29 191.76 6.79 6.74 174.81 19.87
11:30 210.40 6.08 6.28 197.46 18.42
11:31 211.78 6.15 6.22 204.12 18.25
11:32 212.13 6.19 6.18 207.70 18.20
11:33 212.82 6.20 6.15 210.58 18.18
11:34 213.00 6.20 6.13 213.08 18.20
11:35 213.21 6.21 6.11 214.85 18.21
11:36 213.18 6.22 6.09 216.48 18.23
11:37 213.15 6.22 6.08 217.59 18.24
11:38 213.15 6.22 6.07 218.55 18.24
11:39 213.06 6.22 6.06 219.18 18.25
11:40 213.06 6.22 6.05 219.82 18.27
11:41 213.91 6.28 6.02 221.98 18.42
11:42 212.27 6.34 6.04 222.09 18.29
11:43 212.53 6.40 6.04 222.45 18.26
Laboratory: Con-Test Analysis:
Well Data
Well ID
Depth to Product (ft below TOC)
Total Well Depth (ft)
Purging Information Information
Volume of Groundwater in Well
Well Diameter (inches)
GROUNDWATER SAMPLING FORM
Water Column (ft below TOC)
One Well Volume (gal)
Three Well Volumes (gal)
Five Well Volumes (gal)
6200B
Laboratory Analysis Information
Geochemical Parameters
Depth to Water (ft below TOC)
Mild turbidity; light tan. dry
at 12.5 bails
Aqua TROLL 600
Turbidity and Additional
Sampling Notes
NCDEQ-SPL; Petermann
Monitoring Well Information
Nate Newman
7/13/2023
William Watts Store
221081.01
CATLIN PROJECT: SAMPLED BY:
CATLIN PROJECT # : DATE SAMPLED:
CLIENT'S NAME:
MW-3R 7.17
12.83 1.170
NMT 3.510
20 5.851
2
Method:Bailer Purge Start Time:11:03
Required Bails for 3 Well Volumes:15 Purge Stop Time:11:18
Required Bails for 5 Well Volumes:25 Was Well Purged Dry?No
Number of Bails Removed:15 Sample Time:11:18
Groundwater Removed (gal):3.6
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
11:04 506.66 3.71 6.42 201.76 19.72
11:05 340.84 3.87 6.44 200.80 19.39
11:06 945.26 4.08 6.46 200.64 19.21
11:07 651.34 4.26 6.46 201.35 19.13
11:08 1127.02 4.40 6.46 201.88 19.12
11:09 1127.79 4.53 6.45 202.79 19.09
11:10 1130.42 4.59 6.44 203.69 19.13
11:11 1130.38 4.59 6.43 204.48 19.23
11:12 1129.10 4.59 6.43 205.09 19.23
11:13 1125.94 4.54 6.43 205.69 19.44
11:14 1130.02 4.47 6.42 206.41 19.47
11:15 1129.91 4.52 6.42 206.73 19.48
11:16 1130.56 4.57 6.42 207.05 19.56
Laboratory: Con-Test Analysis:
Depth to Water (ft below TOC) One Well Volume (gal)
GROUNDWATER SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SPL; Petermann
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
6200B
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft) Five Well Volumes (gal)
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua TROLL 600
Turbidity and Additional
Sampling Notes
Moderate turbidity; light tan
Laboratory Analysis Information
CATLIN PROJECT: SAMPLED BY:
CATLIN PROJECT # : DATE SAMPLED:
CLIENT'S NAME:
MW-4 6.62
13.38 1.080
NMT 3.241
20 5.402
2
Method:Bailer Purge Start Time:10:47
Required Bails for 3 Well Volumes:14 Purge Stop Time:10:55
Required Bails for 5 Well Volumes:23 Was Well Purged Dry?No
Number of Bails Removed:14 Sample Time:10:55
Groundwater Removed (gal):3.4
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
10:48 117.04 3.89 5.05 258.79 19.69
10:49 140.57 3.87 5.27 250.80 19.30
10:50 165.55 4.01 5.48 241.04 19.15
10:51 164.93 4.06 5.47 240.84 19.15
10:52 167.77 4.08 5.47 240.58 19.21
10:53 168.84 4.10 5.45 242.40 19.24
Laboratory: Con-Test Analysis:
Depth to Water (ft below TOC) One Well Volume (gal)
GROUNDWATER SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SPL; Petermann
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
6200B
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft) Five Well Volumes (gal)
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua TROLL 600
Turbidity and Additional
Sampling Notes
Moderate turbidity; light
brown
Laboratory Analysis Information
CATLIN PROJECT: SAMPLED BY:
CATLIN PROJECT # : DATE SAMPLED:
CLIENT'S NAME:
MW-7 9.38
10.62 1.531
NMT 4.592
20 7.654
2
Method:Bailer Purge Start Time:10:08
Required Bails for 3 Well Volumes:20 Purge Stop Time:10:18
Required Bails for 5 Well Volumes:32 Was Well Purged Dry?No
Number of Bails Removed:20 Sample Time:10:18
Groundwater Removed (gal):4.8
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
10:09 129.86 3.89 4.41 278.67 20.70
10:10 137.34 4.05 4.37 283.40 20.17
10:11 140.81 4.15 4.29 289.71 20.07
10:12 144.83 4.32 4.22 294.62 19.94
10:13 146.88 4.38 4.17 297.85 19.83
10:14 147.05 4.39 4.12 299.66 19.86
10:15 149.67 4.39 4.08 303.40 19.84
10:16 149.78 4.46 4.07 302.55 19.99
Laboratory: Con-Test Analysis:
Depth to Water (ft below TOC) One Well Volume (gal)
GROUNDWATER SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SPL; Petermann
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
6200B
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft) Five Well Volumes (gal)
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua TROLL 600
Turbidity and Additional
Sampling Notes
Light turbidity; light tan
Laboratory Analysis Information
CATLIN PROJECT: SAMPLED BY:
CATLIN PROJECT # : DATE SAMPLED:
CLIENT'S NAME:
MW-9 11.17
8.83 1.823
NMT 5.469
20 9.115
2
Method:Bailer Purge Start Time:10:29
Required Bails for 3 Well Volumes:23 Purge Stop Time:10:37
Required Bails for 5 Well Volumes:38 Was Well Purged Dry?No
Number of Bails Removed:23 Sample Time:10:37
Groundwater Removed (gal):5.5
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
10:30 261.30 4.55 5.51 232.44 20.48
10:31 253.74 4.62 5.50 233.31 20.12
10:32 248.38 4.69 5.47 235.65 19.91
10:33 247.11 4.71 5.45 237.77 19.81
10:34 246.81 4.74 5.44 239.02 19.69
10:35 246.95 4.80 5.43 240.22 19.66
10:36 247.06 4.86 5.43 239.88 19.70
Laboratory: Con-Test Analysis:
Depth to Water (ft below TOC) One Well Volume (gal)
GROUNDWATER SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SPL; Petermann
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
6200B
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft) Five Well Volumes (gal)
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua TROLL 600
Turbidity and Additional
Sampling Notes
Moderate turbidity; light
brown
Laboratory Analysis Information
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
WSW-2
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
Laboratory: Con-Test Analysis:
Purge Stop Time Screen Interval
WATER SUPPLY WELL SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SLP; Petermann
Water Supply Well Purging Information
Water Supply Well ID Well Depth
Purge Start Time Well Diamater
6200B
Was Well Purged Dry? Date Installled
Sample Time Well Material
Comments
Knocked on door and did not get an answer. Do not have an access agreement.
Geochemical Parameters
Turbidity and Additional
Sampling Notes
Laboratory Analysis Information
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
WSW-9 Influent
13:38
13:53
No
13:53
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
Laboratory: Con-Test Analysis:6200B
Laboratory Analysis Information
William Watts Store
221081.01
NCDEQ-SLP; Petermann
Nate Newman
7/13/2023
Comments
No VuSitu Data.
Geochemical Parameters
Turbidity and Additional
Sampling Notes
Purge Stop Time Screen Interval
Was Well Purged Dry? Date Installled
Sample Time Well Material
WATER SUPPLY WELL SAMPLING FORM
Water Supply Well Purging Information
Water Supply Well ID Well Depth
Purge Start Time Well Diamater
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
WSW-9 Effluent
13:54
14:09
No
14:09
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
Laboratory: Con-Test Analysis:6200B
Was Well Purged Dry? Date Installled
Sample Time Well Material
Comments
No VuSitu data.
Geochemical Parameters
Turbidity and Additional
Sampling Notes
Laboratory Analysis Information
Purge Stop Time Screen Interval
WATER SUPPLY WELL SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SLP; Petermann
Water Supply Well Purging Information
Water Supply Well ID Well Depth
Purge Start Time Well Diamater
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
WSW-12
13:16
13:31
No
13:31
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
Laboratory: Con-Test Analysis:
Purge Stop Time Screen Interval
WATER SUPPLY WELL SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SLP; Petermann
Water Supply Well Purging Information
Water Supply Well ID Well Depth
Purge Start Time Well Diamater
6200B
Was Well Purged Dry? Date Installled
Sample Time Well Material
Comments
Sample taken from spigot on house. No VuSitu data.
Geochemical Parameters
Turbidity and Additional
Sampling Notes
Laboratory Analysis Information
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
WSW-24
12:50
13:05
No
13:05
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
Laboratory: Con-Test Analysis:
Purge Stop Time Screen Interval
WATER SUPPLY WELL SAMPLING FORM
William Watts Store Nate Newman
221081.01 7/13/2023
NCDEQ-SLP; Petermann
Water Supply Well Purging Information
Water Supply Well ID Well Depth
Purge Start Time Well Diamater
6200B
Was Well Purged Dry? Date Installled
Sample Time Well Material
Comments
Sample taken from spigot on well house. No VuSitu data.
Geochemical Parameters
Turbidity and Additional
Sampling Notes
Laboratory Analysis Information

NCDEQ; 10538_William Watts Store CATLIN Engineers and Scientists
CATLIN Project No. 221081 August 2023

APPENDIX D

LABORATORY ANALYTICAL REPORT AND
CHAIN OF CUSTODY DOCUMENT

39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
July 26, 2023
Sean O’Neil
CATLIN Engineers & Scientists
1044 Washington Street
Raleigh, NC 27605
Project Location: Raleigh NC
Client Job Number:
Project Number: 221081.01
Laboratory Work Order Number: 23G1784
Enclosed are results of analyses for samples as received by the laboratory on July 14, 2023. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kaitlyn A. Feliciano
Project Manager
Page 1 of 46
Table of Contents
Table of Contents
Sample Summary 3
Hits Only Report 4
Case Narrative 6
Sample Results 8
23G1784-01 8
23G1784-02 10
23G1784-03 12
23G1784-04 14
23G1784-05 16
23G1784-06 18
23G1784-07 20
23G1784-08 22
23G1784-09 24
23G1784-10 26
23G1784-11 28
Sample Preparation Information 30
QC Data 31
Volatile Organic Compounds by GC/MS 31
B346265 31
B346361 35
Flag/Qualifier Summary 39
Certifications 40
Chain of Custody/Sample Receipt 42
Page 2 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
7/26/2023
CATLIN Engineers & Scientists
1044 Washington Street
Raleigh, NC 27605
ATTN: Sean O’Neil
221081.01
23G1784
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Raleigh NC
230713-3
MW-1 23G1784-01 Ground Water SM21-23 6200B
MW-3R 23G1784-02 Ground Water SM21-23 6200B
MW-4 23G1784-03 Ground Water SM21-23 6200B
MW-7 23G1784-04 Ground Water SM21-23 6200B
MW-9 23G1784-05 Ground Water SM21-23 6200B
WSW-9 I 23G1784-06 Ground Water SM21-23 6200B
WSW-9 E 23G1784-07 Ground Water SM21-23 6200B
WSW-12 23G1784-08 Ground Water SM21-23 6200B
WSW-24 23G1784-09 Ground Water SM21-23 6200B
FB 23G1784-10 Field Blank SM21-23 6200B
TB 23G1784-11 Trip Blank Water SM21-23 6200B
[TOC_1]Sample Summary[TOC]
Page 3 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
[TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY
Client ID:Lab ID:23G1784-02MW-3R
No Results Detected
Client ID:Lab ID:23G1784-04MW-7
No Results Detected
Client ID:Lab ID:23G1784-05MW-9
No Results Detected
Client ID:Lab ID:23G1784-07WSW-9 E
No Results Detected
Client ID:Lab ID:23G1784-08WSW-12
No Results Detected
Client ID:Lab ID:23G1784-09WSW-24
No Results Detected
Client ID:Lab ID:23G1784-11TB
No Results Detected
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 4 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
EXECUTIVE SUMMARY
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23G1784-01MW-1
DL
Chloroform 0.23 0.50 g/L SM21-23 6200BJ0.14
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23G1784-03MW-4
DL
1,2,4-Trimethylbenzene 160 10 g/L SM21-23 6200B4.0
1,3,5-Trimethylbenzene 7.2 0.50 g/L SM21-23 6200B0.15
Ethylbenzene 34 0.50 g/L SM21-23 6200B0.22
Isopropylbenzene (Cumene)14 0.50 g/L SM21-23 6200B0.15
m+p Xylene 5.3 1.0 g/L SM21-23 6200B0.49
Naphthalene 21 0.50 g/L SM21-23 6200B0.38
n-Butylbenzene 5.9 0.50 g/L SM21-23 6200B0.15
n-Propylbenzene 15 0.50 g/L SM21-23 6200B0.12
o-Xylene 0.48 0.50 g/L SM21-23 6200BJ0.24
p-Isopropyltoluene (p-Cymene)11 0.50 g/L SM21-23 6200B0.13
sec-Butylbenzene 5.0 0.50 g/L SM21-23 6200B0.13
tert-Butylbenzene 1.5 0.50 g/L SM21-23 6200B0.14
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23G1784-06WSW-9 I
DL
1,2,4-Trimethylbenzene 0.84 0.50 g/L SM21-23 6200B0.20
Benzene 48 0.50 g/L SM21-23 6200B0.18
Isopropylbenzene (Cumene)4.0 0.50 g/L SM21-23 6200B0.15
Methyl tert-Butyl Ether (MTBE)0.19 0.50 g/L SM21-23 6200BJ0.17
Naphthalene 30 0.50 g/L SM21-23 6200B0.38
n-Butylbenzene 0.33 0.50 g/L SM21-23 6200BJ0.15
sec-Butylbenzene 0.38 0.50 g/L SM21-23 6200BJ0.13
tert-Butylbenzene 0.31 0.50 g/L SM21-23 6200BJ0.14
Tetrachloroethylene 0.29 0.50 g/L SM21-23 6200BJ0.17
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23G1784-10FB
DL
Acetone 3.0 50 g/L SM21-23 6200BJ2.0
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 5 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SM21-23 6200B
Qualifications:
Reported result is estimated. Value reported over verified calibration range.
Analyte & Samples(s) Qualified:
E
1,2,4-Trimethylbenzene
23G1784-03[MW-4]
Reported results are estimated. Analysis performed on a previously used vial.
Analyte & Samples(s) Qualified:
H-08
23G1784-03RE1[MW-4], 23G1784-04[MW-7], 23G1784-07[WSW-9 E]
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
Bromomethane
23G1784-01[MW-1], 23G1784-02[MW-3R], 23G1784-03[MW-4], 23G1784-05[MW-9], 23G1784-06[WSW-9 I], 23G1784-08[WSW-12], 23G1784-09[WSW-24],
23G1784-10[FB], 23G1784-11[TB], B346265-BLK1, B346265-BS1, B346265-BSD1, S090669-CCV1
Chloromethane
23G1784-01[MW-1], 23G1784-02[MW-3R], 23G1784-03[MW-4], 23G1784-05[MW-9], 23G1784-06[WSW-9 I], 23G1784-08[WSW-12], 23G1784-09[WSW-24],
23G1784-10[FB], 23G1784-11[TB], B346265-BLK1, B346265-BS1, B346265-BSD1, S090669-CCV1
Dichlorodifluoromethane (Freon 12)
23G1784-01[MW-1], 23G1784-02[MW-3R], 23G1784-03[MW-4], 23G1784-05[MW-9], 23G1784-06[WSW-9 I], 23G1784-08[WSW-12], 23G1784-09[WSW-24],
23G1784-10[FB], 23G1784-11[TB], B346265-BLK1, B346265-BS1, B346265-BSD1, S090669-CCV1
Naphthalene
23G1784-04[MW-7], 23G1784-07[WSW-9 E], B346361-BLK1, B346361-BS1, B346361-BSD1, S090781-CCV1
Trichlorofluoromethane (Freon 11)
23G1784-01[MW-1], 23G1784-02[MW-3R], 23G1784-03[MW-4], 23G1784-05[MW-9], 23G1784-06[WSW-9 I], 23G1784-08[WSW-12], 23G1784-09[WSW-24],
23G1784-10[FB], 23G1784-11[TB], B346265-BLK1, B346265-BS1, B346265-BSD1, S090669-CCV1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
2-Butanone (MEK)
B346265-BS1
Vinyl Chloride
B346265-BSD1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
outside of control limits. Reduced precision anticipated for any reported result for this compound.
Analyte & Samples(s) Qualified:
L-07A
Ethanol
B346265-BSD1
Page 6 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Reporting Specialist
Page 7 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 7/13/2023 11:48
[TOC_2]23G1784-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 19:21 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 19:21 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 19:21 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 19:21 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 19:21 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 19:21 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 19:21 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 19:21 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 19:21 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 19:21 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 19:21 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 19:21 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
0.23 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B1JChloroform
ND 0.60 7/18/23 19:21 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 19:21 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 19:21 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 19:21 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 19:21 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 19:21 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 19:21 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 19:21 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 19:21 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 19:21 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 19:21 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 19:21 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 19:21 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 19:21 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 19:21 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 19:21 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
[TOC_1]Sample Results[TOC]
Page 8 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 7/13/2023 11:48
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 19:21 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 19:21 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 19:21 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 19:21 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 19:21 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 19:21 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 19:21 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 19:21 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 19:21 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 19:21 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 19:21 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 19:21 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 19:21 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 19:21 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 19:21 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 99.0 7/18/23 19:2170-130
Toluene-d8 101 7/18/23 19:2170-130
4-Bromofluorobenzene 95.6 7/18/23 19:2170-130
Page 9 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-02
Field Sample #: MW-3R
Sample Matrix: Ground Water
Sampled: 7/13/2023 11:18
[TOC_2]23G1784-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 19:48 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 19:48 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 19:48 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 19:48 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 19:48 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 19:48 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 19:48 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 19:48 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 19:48 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 19:48 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 19:48 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 19:48 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 19:48 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 19:48 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 19:48 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 19:48 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 19:48 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 19:48 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 19:48 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 19:48 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 19:48 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 19:48 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 19:48 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 19:48 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 19:48 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 19:48 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 19:48 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 19:48 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 10 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-02
Field Sample #: MW-3R
Sample Matrix: Ground Water
Sampled: 7/13/2023 11:18
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 19:48 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 19:48 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 19:48 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 19:48 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 19:48 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 19:48 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 19:48 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 19:48 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 19:48 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 19:48 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 19:48 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 19:48 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 19:48 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 19:48 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 19:48 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 97.2 7/18/23 19:4870-130
Toluene-d8 99.6 7/18/23 19:4870-130
4-Bromofluorobenzene 93.2 7/18/23 19:4870-130
Page 11 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-03
Field Sample #: MW-4
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:55
[TOC_2]23G1784-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 20:16 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 20:16 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 20:16 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 20:16 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 20:16 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 20:16 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
5.9 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
5.0 0.50 7/18/23 20:16 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
1.5 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 20:16 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 20:16 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 20:16 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 20:16 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 20:16 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 20:16 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 20:16 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 20:16 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 20:16 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 20:16 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 20:16 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 20:16 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 20:16 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 20:16 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 20:16 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
34 0.50 7/18/23 20:16 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 20:16 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
14 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
11 0.50 7/18/23 20:16 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 20:16 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 20:16 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 20:16 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 12 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-03
Field Sample #: MW-4
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:55
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
21 0.50 7/18/23 20:16 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
15 0.50 7/18/23 20:16 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 20:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 20:16 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 20:16 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 20:16 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 20:16 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 20:16 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 20:16 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
270 0.50 7/18/23 20:16 MFFg/L0.20 7/18/23SM21-23 6200B1E1,2,4-Trimethylbenzene
160 10 7/20/23 19:56 MFFg/L4.0 7/18/23SM21-23 6200B201,2,4-Trimethylbenzene
7.2 0.50 7/18/23 20:16 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 20:16 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 20:16 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
5.3 1.0 7/18/23 20:16 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
0.48 0.50 7/18/23 20:16 MFFg/L0.24 7/18/23SM21-23 6200B1Jo-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 101 7/20/23 19:5670-130
1,2-Dichloroethane-d4 96.6 7/18/23 20:1670-130
Toluene-d8 96.9 7/18/23 20:1670-130
Toluene-d8 97.0 7/20/23 19:5670-130
4-Bromofluorobenzene 99.0 7/18/23 20:1670-130
4-Bromofluorobenzene 88.3 7/20/23 19:5670-130
Page 13 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-04
Field Sample #: MW-7
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:18
[TOC_2]23G1784-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: H-08 Volatile Organic Compounds by GC/MS
ND 50 7/20/23 16:49 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/20/23 16:49 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/20/23 16:49 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/20/23 16:49 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/20/23 16:49 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/20/23 16:49 MFFg/L1.3 7/18/23SM21-23 6200B1Bromomethane
ND 5.0 7/20/23 16:49 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/20/23 16:49 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/20/23 16:49 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/20/23 16:49 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/20/23 16:49 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/20/23 16:49 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/20/23 16:49 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/20/23 16:49 MFFg/L0.50 7/18/23SM21-23 6200B1Chloromethane
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/20/23 16:49 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/20/23 16:49 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/20/23 16:49 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/20/23 16:49 MFFg/L0.16 7/18/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/20/23 16:49 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/20/23 16:49 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/20/23 16:49 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/20/23 16:49 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/20/23 16:49 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/20/23 16:49 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/20/23 16:49 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/20/23 16:49 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/20/23 16:49 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/20/23 16:49 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/20/23 16:49 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/20/23 16:49 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 14 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-04
Field Sample #: MW-7
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:18
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: H-08 Volatile Organic Compounds by GC/MS
ND 2.0 7/20/23 16:49 MFFg/L0.38 7/18/23SM21-23 6200B1L-04Naphthalene
ND 0.50 7/20/23 16:49 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/20/23 16:49 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/20/23 16:49 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/20/23 16:49 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 1.0 7/20/23 16:49 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/20/23 16:49 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 7/20/23 16:49 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/20/23 16:49 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/20/23 16:49 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/20/23 16:49 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/20/23 16:49 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/20/23 16:49 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/20/23 16:49 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 96.5 7/20/23 16:4970-130
Toluene-d8 102 7/20/23 16:4970-130
4-Bromofluorobenzene 81.0 7/20/23 16:4970-130
Page 15 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-05
Field Sample #: MW-9
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:37
[TOC_2]23G1784-05[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 21:11 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 21:11 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 21:11 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 21:11 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 21:11 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 21:11 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 21:11 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 21:11 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 21:11 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 21:11 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 21:11 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 21:11 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 21:11 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 21:11 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 21:11 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 21:11 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 21:11 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 21:11 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 21:11 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 21:11 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 21:11 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 21:11 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 21:11 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 21:11 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 21:11 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 21:11 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 21:11 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 21:11 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 16 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-05
Field Sample #: MW-9
Sample Matrix: Ground Water
Sampled: 7/13/2023 10:37
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 21:11 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 21:11 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 21:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 21:11 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 21:11 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 21:11 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 21:11 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 21:11 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 21:11 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 21:11 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 21:11 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 21:11 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 21:11 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 21:11 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 21:11 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 96.6 7/18/23 21:1170-130
Toluene-d8 99.8 7/18/23 21:1170-130
4-Bromofluorobenzene 95.7 7/18/23 21:1170-130
Page 17 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-06
Field Sample #: WSW-9 I
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:53
[TOC_2]23G1784-06[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 21:39 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
48 0.50 7/18/23 21:39 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 21:39 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 21:39 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 21:39 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 21:39 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
0.33 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B1Jn-Butylbenzene
0.38 0.50 7/18/23 21:39 MFFg/L0.13 7/18/23SM21-23 6200B1Jsec-Butylbenzene
0.31 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B1Jtert-Butylbenzene
ND 0.50 7/18/23 21:39 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 21:39 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 21:39 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 21:39 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 21:39 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 21:39 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 21:39 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 21:39 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 21:39 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 21:39 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 21:39 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 21:39 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 21:39 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 21:39 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 21:39 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 21:39 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 21:39 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
4.0 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 21:39 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
0.19 0.50 7/18/23 21:39 MFFg/L0.17 7/18/23SM21-23 6200B1JMethyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 21:39 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 21:39 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 18 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-06
Field Sample #: WSW-9 I
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:53
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
30 0.50 7/18/23 21:39 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 21:39 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 21:39 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
0.29 0.50 7/18/23 21:39 MFFg/L0.17 7/18/23SM21-23 6200B1JTetrachloroethylene
ND 0.50 7/18/23 21:39 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 21:39 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 21:39 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 21:39 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 21:39 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
0.84 0.50 7/18/23 21:39 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 21:39 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 21:39 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 21:39 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 21:39 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 21:39 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 96.3 7/18/23 21:3970-130
Toluene-d8 98.1 7/18/23 21:3970-130
4-Bromofluorobenzene 96.2 7/18/23 21:3970-130
Page 19 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-07
Field Sample #: WSW-9 E
Sample Matrix: Ground Water
Sampled: 7/13/2023 14:09
[TOC_2]23G1784-07[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: H-08 Volatile Organic Compounds by GC/MS
ND 50 7/20/23 17:16 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/20/23 17:16 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/20/23 17:16 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/20/23 17:16 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/20/23 17:16 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/20/23 17:16 MFFg/L1.3 7/18/23SM21-23 6200B1Bromomethane
ND 5.0 7/20/23 17:16 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/20/23 17:16 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/20/23 17:16 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/20/23 17:16 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/20/23 17:16 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/20/23 17:16 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/20/23 17:16 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/20/23 17:16 MFFg/L0.50 7/18/23SM21-23 6200B1Chloromethane
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/20/23 17:16 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/20/23 17:16 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/20/23 17:16 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/20/23 17:16 MFFg/L0.16 7/18/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/20/23 17:16 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/20/23 17:16 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/20/23 17:16 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/20/23 17:16 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/20/23 17:16 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/20/23 17:16 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/20/23 17:16 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/20/23 17:16 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/20/23 17:16 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/20/23 17:16 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/20/23 17:16 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/20/23 17:16 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 20 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-07
Field Sample #: WSW-9 E
Sample Matrix: Ground Water
Sampled: 7/13/2023 14:09
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: H-08 Volatile Organic Compounds by GC/MS
ND 2.0 7/20/23 17:16 MFFg/L0.38 7/18/23SM21-23 6200B1L-04Naphthalene
ND 0.50 7/20/23 17:16 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/20/23 17:16 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/20/23 17:16 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/20/23 17:16 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 1.0 7/20/23 17:16 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/20/23 17:16 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 7/20/23 17:16 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/20/23 17:16 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/20/23 17:16 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/20/23 17:16 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/20/23 17:16 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/20/23 17:16 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/20/23 17:16 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 99.1 7/20/23 17:1670-130
Toluene-d8 95.3 7/20/23 17:1670-130
4-Bromofluorobenzene 83.9 7/20/23 17:1670-130
Page 21 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-08
Field Sample #: WSW-12
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:31
[TOC_2]23G1784-08[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 22:35 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 22:35 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 22:35 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 22:35 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 22:35 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 22:35 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 22:35 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 22:35 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 22:35 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 22:35 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 22:35 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 22:35 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 22:35 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 22:35 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 22:35 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 22:35 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 22:35 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 22:35 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 22:35 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 22:35 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 22:35 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 22:35 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 22:35 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 22:35 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 22:35 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 22:35 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 22:35 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 22:35 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 22 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-08
Field Sample #: WSW-12
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:31
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 22:35 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 22:35 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 22:35 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 22:35 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 22:35 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 22:35 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 22:35 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 22:35 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 22:35 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 22:35 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 22:35 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 22:35 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 22:35 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 22:35 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 22:35 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 94.4 7/18/23 22:3570-130
Toluene-d8 98.6 7/18/23 22:3570-130
4-Bromofluorobenzene 93.6 7/18/23 22:3570-130
Page 23 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-09
Field Sample #: WSW-24
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:05
[TOC_2]23G1784-09[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 23:02 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 23:02 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 23:02 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 23:02 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 23:02 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 23:02 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 23:02 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 23:02 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 23:02 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 23:02 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 23:02 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 23:02 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 23:02 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 23:02 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 23:02 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 23:02 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 23:02 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 23:02 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 23:02 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 23:02 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 23:02 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 23:02 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 23:02 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 23:02 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 23:02 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 23:02 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 23:02 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 23:02 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 24 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-09
Field Sample #: WSW-24
Sample Matrix: Ground Water
Sampled: 7/13/2023 13:05
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 23:02 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 23:02 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 23:02 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 23:02 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 23:02 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 23:02 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 23:02 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 23:02 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 23:02 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 23:02 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 23:02 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 23:02 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 23:02 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 23:02 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 23:02 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 93.7 7/18/23 23:0270-130
Toluene-d8 99.4 7/18/23 23:0270-130
4-Bromofluorobenzene 93.2 7/18/23 23:0270-130
Page 25 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-10
Field Sample #: FB
Sample Matrix: Field Blank
Sampled: 7/13/2023 12:00
[TOC_2]23G1784-10[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
3.0 50 7/18/23 23:30 MFFg/L2.0 7/18/23SM21-23 6200B1JAcetone
ND 0.50 7/18/23 23:30 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 23:30 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 23:30 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 23:30 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 23:30 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 23:30 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 23:30 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 23:30 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 23:30 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 23:30 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 23:30 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 23:30 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 23:30 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 23:30 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 23:30 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 23:30 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 23:30 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 23:30 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 23:30 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 23:30 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 23:30 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 23:30 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 23:30 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 23:30 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 23:30 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 23:30 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 23:30 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 26 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-10
Field Sample #: FB
Sample Matrix: Field Blank
Sampled: 7/13/2023 12:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 23:30 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 23:30 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 23:30 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 23:30 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 23:30 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 23:30 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 23:30 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 23:30 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 23:30 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 23:30 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 23:30 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 23:30 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 23:30 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 23:30 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 23:30 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 94.8 7/18/23 23:3070-130
Toluene-d8 99.6 7/18/23 23:3070-130
4-Bromofluorobenzene 94.4 7/18/23 23:3070-130
Page 27 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-11
Field Sample #: TB
Sample Matrix: Trip Blank Water
Sampled: 7/13/2023 00:00
[TOC_2]23G1784-11[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/18/23 15:11 MFFg/L2.0 7/18/23SM21-23 6200B1Acetone
ND 0.50 7/18/23 15:11 MFFg/L0.18 7/18/23SM21-23 6200B1Benzene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B1Bromobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.28 7/18/23SM21-23 6200B1Bromochloromethane
ND 0.50 7/18/23 15:11 MFFg/L0.16 7/18/23SM21-23 6200B1Bromodichloromethane
ND 0.50 7/18/23 15:11 MFFg/L0.41 7/18/23SM21-23 6200B1Bromoform
ND 2.0 7/18/23 15:11 MFFg/L1.3 7/18/23SM21-23 6200B1L-04Bromomethane
ND 5.0 7/18/23 15:11 MFFg/L1.7 7/18/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B1n-Butylbenzene
ND 0.50 7/18/23 15:11 MFFg/L0.13 7/18/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 7/18/23 15:11 MFFg/L0.16 7/18/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 7/18/23 15:11 MFFg/L0.12 7/18/23SM21-23 6200B1Chlorobenzene
ND 50 7/18/23 15:11 MFFg/L20 7/18/23SM21-23 6200B1Ethanol
ND 0.50 7/18/23 15:11 MFFg/L0.20 7/18/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 7/18/23 15:11 MFFg/L0.34 7/18/23SM21-23 6200B1Chloroethane
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B1Chloroform
ND 0.60 7/18/23 15:11 MFFg/L0.50 7/18/23SM21-23 6200B1L-04Chloromethane
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B12-Chlorotoluene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B14-Chlorotoluene
ND 0.50 7/18/23 15:11 MFFg/L0.16 7/18/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 7/18/23 15:11 MFFg/L0.13 7/18/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.13 7/18/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.16 7/18/23SM21-23 6200B1L-04Dichlorodifluoromethane (Freon 12)
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethane
ND 1.0 7/18/23 15:11 MFFg/L0.30 7/18/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 7/18/23 15:11 MFFg/L0.17 7/18/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 7/18/23 15:11 MFFg/L0.19 7/18/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 7/18/23 15:11 MFFg/L0.12 7/18/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 7/18/23 15:11 MFFg/L0.35 7/18/23SM21-23 6200B12,2-Dichloropropane
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 7/18/23 15:11 MFFg/L0.16 7/18/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 7/18/23 15:11 MFFg/L0.20 7/18/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 7/18/23 15:11 MFFg/L0.22 7/18/23SM21-23 6200B1Ethylbenzene
ND 5.0 7/18/23 15:11 MFFg/L1.2 7/18/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 7/18/23 15:11 MFFg/L0.13 7/18/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 7/18/23 15:11 MFFg/L0.17 7/18/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/18/23 15:11 MFFg/L0.18 7/18/23SM21-23 6200B1Methylene Chloride
ND 5.0 7/18/23 15:11 MFFg/L1.3 7/18/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 28 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/14/2023
Work Order: 23G1784Sample Description:Project Location: Raleigh NC
Sample ID: 23G1784-11
Field Sample #: TB
Sample Matrix: Trip Blank Water
Sampled: 7/13/2023 00:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/18/23 15:11 MFFg/L0.38 7/18/23SM21-23 6200B1Naphthalene
ND 0.50 7/18/23 15:11 MFFg/L0.12 7/18/23SM21-23 6200B1n-Propylbenzene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B1Styrene
ND 0.50 7/18/23 15:11 MFFg/L0.14 7/18/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 7/18/23 15:11 MFFg/L0.17 7/18/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 7/18/23 15:11 MFFg/L0.22 7/18/23SM21-23 6200B1Toluene
ND 1.0 7/18/23 15:11 MFFg/L0.34 7/18/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.30 7/18/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 7/18/23 15:11 MFFg/L0.19 7/18/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 7/18/23 15:11 MFFg/L0.17 7/18/23SM21-23 6200B1Trichloroethylene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B1L-04Trichlorofluoromethane (Freon 11)
ND 0.50 7/18/23 15:11 MFFg/L0.28 7/18/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 7/18/23 15:11 MFFg/L0.20 7/18/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 7/18/23 15:11 MFFg/L0.15 7/18/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 7/18/23 15:11 MFFg/L1.7 7/18/23SM21-23 6200B1Vinyl Acetate
ND 0.50 7/18/23 15:11 MFFg/L0.24 7/18/23SM21-23 6200B1Vinyl Chloride
ND 1.0 7/18/23 15:11 MFFg/L0.49 7/18/23SM21-23 6200B1m+p Xylene
ND 0.50 7/18/23 15:11 MFFg/L0.24 7/18/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 99.1 7/18/23 15:1170-130
Toluene-d8 99.6 7/18/23 15:1170-130
4-Bromofluorobenzene 94.9 7/18/23 15:1170-130
Page 29 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B-SM21-23 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B346265 07/18/235 5.0023G1784-01 [MW-1]
B346265 07/18/235 5.0023G1784-02 [MW-3R]
B346265 07/18/235 5.0023G1784-03 [MW-4]
B346265 07/18/235 5.0023G1784-05 [MW-9]
B346265 07/18/235 5.0023G1784-06 [WSW-9 I]
B346265 07/18/235 5.0023G1784-08 [WSW-12]
B346265 07/18/235 5.0023G1784-09 [WSW-24]
B346265 07/18/235 5.0023G1784-10 [FB]
B346265 07/18/235 5.0023G1784-11 [TB]
Prep Method: SW-846 5030B-SM21-23 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B346361 07/18/230.25 5.0023G1784-03RE1 [MW-4]
B346361 07/18/235 5.0023G1784-04 [MW-7]
B346361 07/18/235 5.0023G1784-07 [WSW-9 E]
[TOC_1]Sample Preparation Information[TOC]
Page 30 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B346265 - SW-846 5030B
[TOC_3]B346265[TOC]
Blank (B346265-BLK1) Prepared & Analyzed: 07/18/23
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L2.0 L-04ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60 L-04ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50 L-04ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
[TOC_1]QC Data[TOC]
Page 31 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346265 - SW-846 5030B
Blank (B346265-BLK1) Prepared & Analyzed: 07/18/23
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50 L-04ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 97.824.4
g/L 25.0 70-130Surrogate: Toluene-d8 99.024.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 94.023.5
LCS (B346265-BS1) Prepared & Analyzed: 07/18/23
Acetone g/L50 200 70-13071.0142
Benzene g/L0.50 20.0 70-13011222.3
Bromobenzene g/L0.50 20.0 70-13011222.4
Bromochloromethane g/L0.50 20.0 70-13011723.4
Bromodichloromethane g/L0.50 20.0 70-13010320.6
Bromoform g/L0.50 20.0 70-13010921.9
Bromomethane g/L2.0 20.0 L-0460-14044.3 *8.86
2-Butanone (MEK)g/L5.0 200 L-0770-130142*283
n-Butylbenzene g/L0.50 20.0 70-13011322.7
sec-Butylbenzene g/L0.50 20.0 70-13012023.9
tert-Butylbenzene g/L0.50 20.0 70-13011022.0
Carbon Tetrachloride g/L0.50 20.0 70-13010520.9
Chlorobenzene g/L0.50 20.0 70-13010621.2
Ethanol g/L50 200 70-13073.2146
Chlorodibromomethane g/L0.50 20.0 70-13010621.2
Chloroethane g/L0.50 20.0 60-14070.914.2
Chloroform g/L0.50 20.0 70-13011022.0
Chloromethane g/L0.60 20.0 L-0460-14039.3 *7.86
2-Chlorotoluene g/L0.50 20.0 70-13097.719.5
4-Chlorotoluene g/L0.50 20.0 70-13011021.9
1,2-Dibromoethane (EDB)g/L0.50 20.0 70-13010921.9
1,2-Dichlorobenzene g/L0.50 20.0 70-13011222.3
1,3-Dichlorobenzene g/L0.50 20.0 70-13011222.4
1,4-Dichlorobenzene g/L0.50 20.0 70-13010520.9
Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 L-0460-14051.2 *10.2
1,1-Dichloroethane g/L0.50 20.0 70-13012324.6
1,2-Dichloroethane g/L1.0 20.0 70-13091.218.2
1,1-Dichloroethylene g/L0.50 20.0 70-13071.214.2
cis-1,2-Dichloroethylene g/L0.50 20.0 70-13011923.9
trans-1,2-Dichloroethylene g/L0.50 20.0 70-13011322.7
1,2-Dichloropropane g/L0.50 20.0 70-13011122.2
1,3-Dichloropropane g/L0.50 20.0 70-13011022.0
2,2-Dichloropropane g/L0.50 20.0 70-13010921.8
1,1-Dichloropropene g/L0.50 20.0 70-13010921.8
cis-1,3-Dichloropropene g/L0.50 20.0 70-13011122.3
trans-1,3-Dichloropropene g/L0.50 20.0 70-13011923.8
Page 32 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346265 - SW-846 5030B
LCS (B346265-BS1) Prepared & Analyzed: 07/18/23
Diisopropyl Ether (DIPE)g/L0.50 20.0 70-13012024.0
Ethylbenzene g/L0.50 20.0 70-13011021.9
2-Hexanone (MBK)g/L5.0 200 70-130112223
Isopropylbenzene (Cumene)g/L0.50 20.0 70-13010621.2
p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 70-13011723.3
Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 70-13010020.0
Methylene Chloride g/L5.0 20.0 70-13083.816.8
4-Methyl-2-pentanone (MIBK)g/L5.0 200 70-130109219
Naphthalene g/L0.50 20.0 70-13097.419.5
n-Propylbenzene g/L0.50 20.0 70-13011222.3
Styrene g/L0.50 20.0 70-13011222.4
1,1,2,2-Tetrachloroethane g/L0.50 20.0 70-13012324.5
Tetrachloroethylene g/L0.50 20.0 70-13010921.7
Toluene g/L0.50 20.0 70-13010921.7
1,2,3-Trichlorobenzene g/L1.0 20.0 70-13010320.6
1,2,4-Trichlorobenzene g/L0.50 20.0 70-13010821.5
1,1,1-Trichloroethane g/L0.50 20.0 70-13010921.8
1,1,2-Trichloroethane g/L0.50 20.0 70-13011522.9
Trichloroethylene g/L0.50 20.0 70-13010621.2
Trichlorofluoromethane (Freon 11)g/L0.50 20.0 L-0470-13064.8 *13.0
1,2,3-Trichloropropane g/L0.50 20.0 70-13011723.4
1,2,4-Trimethylbenzene g/L0.50 20.0 70-13011022.1
1,3,5-Trimethylbenzene g/L0.50 20.0 70-13010721.5
Vinyl Acetate g/L20 200 70-130118237
Vinyl Chloride g/L0.50 20.0 60-14065.013.0
m+p Xylene g/L1.0 40.0 70-13010742.9
o-Xylene g/L0.50 20.0 70-13011122.2
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 97.224.3
g/L 25.0 70-130Surrogate: Toluene-d8 97.224.3
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10025.0
LCS Dup (B346265-BSD1) Prepared & Analyzed: 07/18/23
Acetone g/L50 200 2570-13073.6 3.59147
Benzene g/L0.50 20.0 2570-130113 1.5122.6
Bromobenzene g/L0.50 20.0 2570-130113 0.80222.5
Bromochloromethane g/L0.50 20.0 2570-130122 4.0724.3
Bromodichloromethane g/L0.50 20.0 2570-130103 0.097120.6
Bromoform g/L0.50 20.0 2570-130112 2.8022.5
Bromomethane g/L2.0 20.0 25 L-0460-14054.0 19.7*10.8
2-Butanone (MEK)g/L5.0 200 2570-130118 17.9237
n-Butylbenzene g/L0.50 20.0 2570-130115 1.1823.0
sec-Butylbenzene g/L0.50 20.0 2570-130120 0.75024.1
tert-Butylbenzene g/L0.50 20.0 2570-130110 0.22722.0
Carbon Tetrachloride g/L0.50 20.0 2570-130103 1.8820.5
Chlorobenzene g/L0.50 20.0 2570-130106 0.42421.2
Ethanol g/L50 200 25 L-07A70-13041.5 55.3**83.0
Chlorodibromomethane g/L0.50 20.0 2570-130111 4.7922.2
Chloroethane g/L0.50 20.0 2560-14070.5 0.56614.1
Chloroform g/L0.50 20.0 2570-130111 1.1322.3
Chloromethane g/L0.60 20.0 25 L-0460-14044.0 11.3*8.80
2-Chlorotoluene g/L0.50 20.0 2570-130102 4.5020.4
4-Chlorotoluene g/L0.50 20.0 2570-130110 0.77222.1
Page 33 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346265 - SW-846 5030B
LCS Dup (B346265-BSD1) Prepared & Analyzed: 07/18/23
1,2-Dibromoethane (EDB)g/L0.50 20.0 2570-130117 6.2823.3
1,2-Dichlorobenzene g/L0.50 20.0 2570-130115 2.7022.9
1,3-Dichlorobenzene g/L0.50 20.0 2570-130113 1.0722.6
1,4-Dichlorobenzene g/L0.50 20.0 2570-130107 1.9421.3
Dichlorodifluoromethane (Freon 12)g/L0.50 20.0 25 L-0460-14050.4 1.57*10.1
1,1-Dichloroethane g/L0.50 20.0 2570-130123 0.20324.6
1,2-Dichloroethane g/L1.0 20.0 2570-13094.4 3.3918.9
1,1-Dichloroethylene g/L0.50 20.0 2570-13071.7 0.63014.3
cis-1,2-Dichloroethylene g/L0.50 20.0 2570-130121 1.7024.3
trans-1,2-Dichloroethylene g/L0.50 20.0 2570-130115 1.0122.9
1,2-Dichloropropane g/L0.50 20.0 2570-130113 1.4322.5
1,3-Dichloropropane g/L0.50 20.0 2570-130111 1.1722.3
2,2-Dichloropropane g/L0.50 20.0 2570-130108 1.2921.5
1,1-Dichloropropene g/L0.50 20.0 2570-130111 1.2722.1
cis-1,3-Dichloropropene g/L0.50 20.0 2570-130112 0.44822.4
trans-1,3-Dichloropropene g/L0.50 20.0 2570-130122 2.7824.5
Diisopropyl Ether (DIPE)g/L0.50 20.0 2570-130124 3.2024.8
Ethylbenzene g/L0.50 20.0 2570-130108 1.3321.6
2-Hexanone (MBK)g/L5.0 200 2570-130115 2.86230
Isopropylbenzene (Cumene)g/L0.50 20.0 2570-130106 0.094321.2
p-Isopropyltoluene (p-Cymene)g/L0.50 20.0 2570-130115 1.2123.0
Methyl tert-Butyl Ether (MTBE)g/L0.50 20.0 2570-130105 4.9221.0
Methylene Chloride g/L5.0 20.0 2570-13076.0 9.7615.2
4-Methyl-2-pentanone (MIBK)g/L5.0 200 2570-130113 3.66227
Naphthalene g/L0.50 20.0 2570-130106 8.4621.2
n-Propylbenzene g/L0.50 20.0 2570-130112 0.13422.3
Styrene g/L0.50 20.0 2570-130111 1.2622.1
1,1,2,2-Tetrachloroethane g/L0.50 20.0 2570-130126 2.8925.2
Tetrachloroethylene g/L0.50 20.0 2570-130108 0.55421.6
Toluene g/L0.50 20.0 2570-130107 1.1621.5
1,2,3-Trichlorobenzene g/L1.0 20.0 2570-130110 6.3621.9
1,2,4-Trichlorobenzene g/L0.50 20.0 2570-130108 0.83321.7
1,1,1-Trichloroethane g/L0.50 20.0 2570-130108 0.96821.6
1,1,2-Trichloroethane g/L0.50 20.0 2570-130119 4.0223.9
Trichloroethylene g/L0.50 20.0 2570-130108 1.5921.6
Trichlorofluoromethane (Freon 11)g/L0.50 20.0 25 L-0470-13064.0 1.24*12.8
1,2,3-Trichloropropane g/L0.50 20.0 2570-130120 2.5324.0
1,2,4-Trimethylbenzene g/L0.50 20.0 2570-130110 0.13622.1
1,3,5-Trimethylbenzene g/L0.50 20.0 2570-130108 0.27921.5
Vinyl Acetate g/L20 200 2570-130122 3.10244
Vinyl Chloride g/L0.50 20.0 25 L-0760-14058.9 9.85*11.8
m+p Xylene g/L1.0 40.0 2570-130107 0.49042.7
o-Xylene g/L0.50 20.0 2570-130110 0.40722.1
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 93.023.2
g/L 25.0 70-130Surrogate: Toluene-d8 97.524.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.524.6
Page 34 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346361 - SW-846 5030B
[TOC_3]B346361[TOC]
Blank (B346361-BLK1) Prepared: 07/19/23 Analyzed: 07/20/23
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50 L-04ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
Page 35 of 46
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346361 - SW-846 5030B
Blank (B346361-BLK1) Prepared: 07/19/23 Analyzed: 07/20/23
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.424.1
g/L 25.0 70-130Surrogate: Toluene-d8 10025.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 82.120.5
LCS (B346361-BS1) Prepared: 07/19/23 Analyzed: 07/20/23
Acetone g/L50 100 70-13088.088.0
Benzene g/L0.50 10.0 70-13010310.3
Bromobenzene g/L0.50 10.0 70-13099.49.94
Bromochloromethane g/L0.50 10.0 70-13011111.1
Bromodichloromethane g/L0.50 10.0 70-13010410.4
Bromoform g/L0.50 10.0 70-13083.78.37
Bromomethane g/L2.0 10.0 60-14011211.2
2-Butanone (MEK)g/L5.0 100 70-13096.996.9
n-Butylbenzene g/L0.50 10.0 70-13095.19.51
sec-Butylbenzene g/L0.50 10.0 70-13090.29.02
tert-Butylbenzene g/L0.50 10.0 70-13084.18.41
Carbon Tetrachloride g/L0.50 10.0 70-13079.17.91
Chlorobenzene g/L0.50 10.0 70-13010310.3
Ethanol g/L50 100 70-13072.072.0
Chlorodibromomethane g/L0.50 10.0 70-13095.99.59
Chloroethane g/L0.50 10.0 60-14086.98.69
Chloroform g/L0.50 10.0 70-13099.39.93
Chloromethane g/L0.60 10.0 60-14096.29.62
2-Chlorotoluene g/L0.50 10.0 70-13099.69.96
4-Chlorotoluene g/L0.50 10.0 70-13094.79.47
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010310.3
1,2-Dichlorobenzene g/L0.50 10.0 70-13097.79.77
1,3-Dichlorobenzene g/L0.50 10.0 70-13010010.0
1,4-Dichlorobenzene g/L0.50 10.0 70-13010210.2
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14090.19.01
1,1-Dichloroethane g/L0.50 10.0 70-13097.29.72
1,2-Dichloroethane g/L0.50 10.0 70-13098.19.81
1,1-Dichloroethylene g/L0.50 10.0 70-13090.69.06
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13094.99.49
trans-1,2-Dichloroethylene g/L0.50 10.0 70-13090.49.04
1,2-Dichloropropane g/L0.50 10.0 70-13010710.7
1,3-Dichloropropane g/L0.50 10.0 70-13010210.2
2,2-Dichloropropane g/L0.50 10.0 70-13095.09.50
1,1-Dichloropropene g/L0.50 10.0 70-13010110.1
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010110.1
trans-1,3-Dichloropropene g/L0.50 10.0 70-13010110.1
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346361 - SW-846 5030B
LCS (B346361-BS1) Prepared: 07/19/23 Analyzed: 07/20/23
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13097.69.76
Ethylbenzene g/L0.50 10.0 70-13099.49.94
2-Hexanone (MBK)g/L5.0 100 70-13091.291.2
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13090.99.09
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13092.49.24
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13088.28.82
Methylene Chloride g/L5.0 10.0 70-13091.79.17
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-13090.390.3
Naphthalene g/L0.50 10.0 L-0470-13064.6 *6.46
n-Propylbenzene g/L0.50 10.0 70-13094.49.44
Styrene g/L0.50 10.0 70-13091.29.12
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13098.99.89
Tetrachloroethylene g/L0.50 10.0 70-13011011.0
Toluene g/L0.50 10.0 70-13010310.3
1,2,3-Trichlorobenzene g/L1.0 10.0 70-13080.18.01
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13076.07.60
1,1,1-Trichloroethane g/L0.50 10.0 70-13097.19.71
1,1,2-Trichloroethane g/L0.50 10.0 70-13010410.4
Trichloroethylene g/L0.50 10.0 70-13010310.3
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13092.69.26
1,2,3-Trichloropropane g/L0.50 10.0 70-13012112.1
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13088.58.85
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13096.49.64
Vinyl Acetate g/L20 100 70-13094.094.0
Vinyl Chloride g/L0.50 10.0 60-14099.29.92
m+p Xylene g/L1.0 20.0 70-13096.719.3
o-Xylene g/L0.50 10.0 70-13090.89.08
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.924.0
g/L 25.0 70-130Surrogate: Toluene-d8 10125.3
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 93.823.4
LCS Dup (B346361-BSD1) Prepared: 07/19/23 Analyzed: 07/20/23
Acetone g/L50 100 2570-13085.1 3.3685.1
Benzene g/L0.50 10.0 2570-13099.7 3.649.97
Bromobenzene g/L0.50 10.0 2570-130100 0.70210.0
Bromochloromethane g/L0.50 10.0 2570-130109 1.1810.9
Bromodichloromethane g/L0.50 10.0 2570-13099.5 4.429.95
Bromoform g/L0.50 10.0 2570-13082.7 1.208.27
Bromomethane g/L2.0 10.0 2560-140110 1.8911.0
2-Butanone (MEK)g/L5.0 100 2570-13094.2 2.8494.2
n-Butylbenzene g/L0.50 10.0 2570-13093.7 1.489.37
sec-Butylbenzene g/L0.50 10.0 2570-13089.7 0.5568.97
tert-Butylbenzene g/L0.50 10.0 2570-13084.4 0.3568.44
Carbon Tetrachloride g/L0.50 10.0 2570-13073.6 7.207.36
Chlorobenzene g/L0.50 10.0 2570-130102 0.87710.2
Ethanol g/L50 100 2570-13075.8 5.1775.8
Chlorodibromomethane g/L0.50 10.0 2570-13095.0 0.9439.50
Chloroethane g/L0.50 10.0 2560-14087.4 0.5748.74
Chloroform g/L0.50 10.0 2570-13096.5 2.869.65
Chloromethane g/L0.60 10.0 2560-14091.4 5.129.14
2-Chlorotoluene g/L0.50 10.0 2570-13095.9 3.799.59
4-Chlorotoluene g/L0.50 10.0 2570-13095.6 0.9469.56
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B346361 - SW-846 5030B
LCS Dup (B346361-BSD1) Prepared: 07/19/23 Analyzed: 07/20/23
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130100 3.1410.0
1,2-Dichlorobenzene g/L0.50 10.0 2570-130101 3.5210.1
1,3-Dichlorobenzene g/L0.50 10.0 2570-130100 0.0010.0
1,4-Dichlorobenzene g/L0.50 10.0 2570-13099.3 3.079.93
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14082.0 9.418.20
1,1-Dichloroethane g/L0.50 10.0 2570-13095.3 1.979.53
1,2-Dichloroethane g/L0.50 10.0 2570-13096.1 2.069.61
1,1-Dichloroethylene g/L0.50 10.0 2570-13089.0 1.788.90
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13093.8 1.179.38
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13089.3 1.228.93
1,2-Dichloropropane g/L0.50 10.0 2570-130106 1.0410.6
1,3-Dichloropropane g/L0.50 10.0 2570-130101 1.2810.1
2,2-Dichloropropane g/L0.50 10.0 2570-13089.7 5.748.97
1,1-Dichloropropene g/L0.50 10.0 2570-13094.2 6.679.42
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13097.7 3.129.77
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13097.6 3.329.76
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13096.6 1.039.66
Ethylbenzene g/L0.50 10.0 2570-13095.2 4.329.52
2-Hexanone (MBK)g/L5.0 100 2570-13087.2 4.5787.2
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13089.1 2.008.91
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13089.8 2.858.98
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13086.7 1.728.67
Methylene Chloride g/L5.0 10.0 2570-13091.2 0.5479.12
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13085.1 5.9285.1
Naphthalene g/L0.50 10.0 25 L-0470-13063.3 2.03*6.33
n-Propylbenzene g/L0.50 10.0 2570-13091.3 3.349.13
Styrene g/L0.50 10.0 2570-13090.8 0.4409.08
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130100 1.1110.0
Tetrachloroethylene g/L0.50 10.0 2570-130100 9.4010.0
Toluene g/L0.50 10.0 2570-13098.5 4.859.85
1,2,3-Trichlorobenzene g/L1.0 10.0 2570-13082.9 3.448.29
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-13077.0 1.317.70
1,1,1-Trichloroethane g/L0.50 10.0 2570-13094.9 2.299.49
1,1,2-Trichloroethane g/L0.50 10.0 2570-130105 1.4310.5
Trichloroethylene g/L0.50 10.0 2570-130101 1.8610.1
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13089.4 3.528.94
1,2,3-Trichloropropane g/L0.50 10.0 2570-130120 1.5812.0
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13088.9 0.4518.89
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13094.5 1.999.45
Vinyl Acetate g/L20 100 2570-13091.4 2.8391.4
Vinyl Chloride g/L0.50 10.0 2560-14094.7 4.649.47
m+p Xylene g/L1.0 20.0 2570-13094.0 2.7818.8
o-Xylene g/L0.50 10.0 2570-13089.9 0.9968.99
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 93.223.3
g/L 25.0 70-130Surrogate: Toluene-d8 99.124.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 93.023.2
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*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
FLAG/QUALIFIER SUMMARY
Reported result is estimated. Value reported over verified calibration range.E
Reported results are estimated. Analysis performed on a previously used vial.H-08
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD outside of control limits. Reduced precision anticipated for any reported result for
this compound.
L-07A
[TOC_1]Flag/Qualifier Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-23 6200B in Water
NCAcetone
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCCarbon Tetrachloride
NCChlorobenzene
NCEthanol
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromoethane (EDB)
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiisopropyl Ether (DIPE)
NCEthylbenzene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
[TOC_1]Certifications[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-23 6200B in Water
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Acetate
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
The CON-TEST Environmental Laboratory operates under the following certifications and accreditations:
Code Description Number Expires
652North Carolina Div. of Water QualityNC 12/31/2023
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