MO_8934_40437_CA_MRP_20230808

7606 Whitehall Executive Center Drive,
Suite 800
Charlotte, NC 28273
Telephone [phone]
Fax [phone]
www.atcgroupservices.com

August 8, 2023
Mr. Dan Bowser
NCDEQ / DMW / UST Section
610 East Center Avenue, Suite 300
Mooresville, North Carolina 28105

RE: Monitoring Report
Circle K No. 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
NCDEQ UST Facility No. 0-035583
NCDEQ Incident No. 40437
ATC Project No. PAN394018
Dear Mr. Bowser:

ATC Associates of North Carolina, P.C. (ATC), on behalf of Circle K Stores Inc. (Circle K) is
pleased to submit the following Monitoring Report for the above-referenced site for your review
and approval. This report summarizes site assessment activities conducted by ATC in June 19
to June 23, 2023 and July 20, 2023 as authorized by. Pre-Approval Task Authorization (PATA)
number 36286-18, approved on May 22, 2023

If you have any questions or comments pertaining to this project please feel free to contact me at
[phone] or by email at [e-mail]

Sincerely,
ATC ASSOCIATES OF NORTH CAROLINA, P.C.

Noelle France, P.G.
Senior Project Manager
cc: Mr. Alan Cubberley - Circle K Stores Inc., Raleigh, NC (via Titan)

MONITORING REPORT

CIRCLE K NO. 2723940

10409 Mallard Creek Road
Charlotte, North Carolina

NCDEQ UST Facility No. 0-035583
NCDEQ Incident No. 40437
ATC Project No. CIRK394017

Prepared for:

Mr. Alan Cubberley
Environmental Director

Circle K Stores Inc.
1100 Situs Court
Suite 100
Raleigh, North Carolina 27606

Prepared by:

ATC Associates of North Carolina, P.C.

7606 Whitehall Executive Center Drive
Charlotte, North Carolina 28273
tel [phone]
fax [phone]
www.atcassociates.com

August 8, 2023
Monitoring Report Circle K 2723940
Incident No. 40437 Page iii

SITE INFORMATION
SITE IDENTIFICATION
Date of Report August 8, 2023
UST Facility ID No: 0-035583
UST Incident No: 40437
Site Risk & Rank: High – 130D
Agency Contact: Dan Bowser, NCDEQ, MRO, UST Section
Site Name: Circle K No. 2723940
Site Street Address: 10409 Mallard Creek Road
Charlotte, Mecklenburg County, NC
Latitude / Longitude: N 35° 20’ 29.8” W 80° 46’ 6.5” (Topographic Map)
Geographical Data Point: Center of Site
SITE CONTACT INFORMATION
UST Owner/Operator & Occupant: Circle K Stores Inc.
Address: 1100 Situs Ct, Ste 100, Raleigh, NC 27606
Telephone: [phone]
Contact: Alan Cubberly, Environmental Director
Property Owner: National Retail Properties, LP
450 South Orange Avenue, Orlando, Florida 32801
Consultant: ATC Associates of North Carolina, P.C.
Address: 7606 Whitehall Executive Center Drive, Suite 800,
Charlotte, NC 28273
Telephone: [phone]
NC License No: C-415 & C-3018
Analytical Laboratory: Pace Analytical Services, LLC
Address: 9800 Kincey Ave, Ste 100, Huntersville, NC 28078
Telephone: [phone]
Certification No: 12
INFORMATION ABOUT RELEASE
Date Discovered: March 2, 2007 and December 24, 2014
Estimated Quantity of Release: Unknown
Cause of Release: UST System
Source of Release: UST / Piping
Active UST(s) Size & Contents: (1) 20,000-gallon Gasoline, (1) 8,000-gallon Gasoline
(1) 3,000-gallon Gasoline, and (1) 3,000-gallon Diesel

Monitoring Report Circle K 2723940
Incident No. 40437 Page iv

CERTIFICATION
I, Michael D. Shaw , a Professional Geologist employed by ATC Associates of North Carolina,
P.C., do certify that the information contained in this report is correct and accurate to the best of
my knowledge.

ATC Associates of North Carolina, P.C. is licensed to practice geology and engineering in North
Carolina. The certification number of the company or corporation to practice geology is C-1598.

Michael D. Shaw, P.G.
Licensed Geologist
North Carolina Seal No. 1338

Monitoring Report Circle K 2723940
Incident No. 40437 Page v

TABLE OF CONTENTS
SITE INFORMATION ................................................................................................................. III
1.0 EXECUTIVE SUMMARY ..................................................................................................... 1
2.0 SITE CHARACTERIZATION AND HISTORY ...................................................................... 2
2.1 Area of Investigation 2
2.2 Receptor Survey 2
2.3 Site History 2
3.0 GEOLOGIC FRAMEWORK ................................................................................................. 6
4.0 MOBILE MULTI-PHASE EXTRACTION EVENT ................................................................. 6
5.0 SITE ASSESSMENT ACTIVITIES ....................................................................................... 7
5.1 Groundwater Sampling Activities 7
5.2 Groundwater Analytical Results 7
6.0 CONCLUSIONS AND RECOMMENDATIONS .................................................................... 8
7.0 LIMITATIONS ...................................................................................................................... 9
TABLES
Table 1: Site History - UST System and Other Release Information
Table 2: Site History – UST Owner/Operator Information
Table 3: Adjoining Property Information
Table 4: Water Supply Well & Receptor Data
Table 5: Well Construction and Groundwater Elevation Data
Table 6: Current Groundwater Analytical Data
Table 7: Historical Groundwater Analytical Data
FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Potential Receptors Map
Figure 4: Groundwater Elevation Contour Map
Figure 5: Contaminants of Concern Map

APPENDICES
Appendix A: MMPE Report
Appendix B: Laboratory Analytical Report

Monitoring Report Circle K 2723940
Incident No. 40437 Page 1

1.0 EXECUTIVE SUMMARY
The Circle K Store No. 2723940 facility is located at 10409 Mallard Creek Road in Charlotte,
Mecklenburg County, North Carolina (site or subject facility). The facility is operated by Circle K
Stores Inc., as a convenience store, gas station, and car wash. The current UST system consists
of one 20,000-gallon gasoline UST, one 8,000-gallon gasoline UST, one 3,000-gallon gasoline
UST, and one 3,000-gallon diesel UST.

On July 17, 2023, ATC conducted a groundwater monitoring event at the Circle K Store No.
2723940, which included gauging the site wells and collecting groundwater samples for laboratory
analysis. These activities were conducted in accordance with the Pre-Approval Task Authorization
(PATA) number 36286-19, approved on May 22, 2023

Based on the field activities and laboratory analysis discussed herein, ATC offers the following
findings:
 An estimated 123.68 pounds (22.95 equivalent gallons) of petroleum hydrocarbons were
recovered as vapor during the MMPE event. The MMPE event generated approximately
5,456 gallons of petroleum impacted groundwater.
 ATC gauged and sampled monitoring wells MW-1A, MW-3, MW-4, MW-6, MW-10, MW-
11, MW-12, MW-13, MW-14, MW-15, MW-16, DW-1, DW-2, DW-3.
 LNAPL was not detected during the July 2023 sampling event.
 Methyl-Tert-Butyl-Ether (MTBE and Tert-butyl Alcohol (TBA) were detected above the
North Carolina Gross Contamination Levels for Groundwater Levels (GCLs) in the
samples collected from monitoring well MW-11.
 Monitoring wells MW-1A, MW-4, MW-10, MW-11, MW-12, MW-14, MW-15, MW-16, and
DW-1 also contained two or more petroleum constituents at concentrations above 2L
Standards.
 Monitoring wells MW-3, MW-6, MW-13, DW-2 and DW-3 did not contain detectable
concentrations of VOCs.
 Groundwater flows to the northwest and to the southeast from a high centered at MW-1A.
 The concentration of MTBE in DW-1 indicates that the vertical extent of the contaminant
plume has not been defined at depth in that area.

Subsequent to the MMPE event groundwater analytical results indicate that the contaminant
plume is generally stable, and LNAPL was not detected in MW-16. The constituent
concentrations reported in MW-16 were reduced compared to the June 2022 sampling event.

ATC recommends an additional groundwater monitoring event to monitor the stability of the
constituent concentrations and determine if the presence of residual LNAPL has been addressed.

Monitoring Report Circle K 2723940
Incident No. 40437 Page 2

2.0 SITE CHARACTERIZATION AND HISTORY

2.1 Area of Investigation
The site is located at 10409 Mallard Creek Road in Charlotte, Mecklenburg County, North
Carolina, and is currently an active convenience store and gas station. The site is developed with
one single-story building, an automatic car wash, four active underground storage tanks (USTs),
and one fuel canopy with five dispenser islands. The UST system consists of one 20,000-gallon
gasoline UST, one 8,000-gallon gasoline UST, one 3,000-gallon gasoline UST, and one 3,000-
gallon diesel UST. According to information obtained from the NCDEQ UST Registry Database,
the existing USTs were installed in August 1997. Summaries of UST system and owner/operator
information is included in Table 1 and Table 2. A site vicinity map with topographic features is
included as Figure 1. Site features are illustrated on Figure 2.

Immediately surrounding properties are developed for commercial use. Prosperity Church Road
adjoins and provides site access to the north, Mallard Creek Road adjoins and provides site
access to the south, and the two roads intersect to the east. Table 3 summarizes adjoining
property owners/occupants.

2.2 Receptor Survey
A receptor survey was conducted by a previous consultant to identify water supply wells, surface
water bodies, and other potential receptors within 1,500-feet of the source area. During the
receptor survey, one active water supply well (WSW-1) was identified approximately 915-feet
northwest of the source area and was reportedly utilized for potable drinking water. A second
water supply well was identified over 1,000 feet away, but the well status was unknown. Table 4
summarizes water supply well and potential receptor information. Locations of potential receptors
are illustrated on Figure 3.

The site is not located in a wellhead protection area or within the Coastal Plain Physiographic
province. Underground utilities are present on site, however they do not intersect the water table.

2.3 Site History
Incident # 36286

As part of a preliminary Phase II ESA conducted prior to a property transaction, SEI Environmental
(SEI) collected groundwater samples from observation wells installed in the UST pit. The
groundwater samples contained petroleum constituents at concentrations in excess of 2L
Standards, and a release was reported to the UST Section on April 2, 2007.

SEI conducted Site Check and Site Check Addendum investigations in June and August 2007.
Soil samples collected from soil borings advanced around the perimeter of the four UST systems,
the sumps of each UST, and the product lines and dispensers revealed gasoline range - total
petroleum hydrocarbons (TPH-GRO) in two of the soil samples advanced around the perimeter
of the UST systems. Groundwater samples collected from the UST pit observation wells indicated
concentrations of petroleum constituents exceeding the 2L Standards but below the Gross
Monitoring Report Circle K 2723940
Incident No. 40437 Page 3

Contamination Levels (GCLs). UST, line, and leak detector integrity testing was completed on
March 31, 2007, and all components passed their respective testing method requirements. SEI
concluded in their August 30, 2007, report that the source of the release was likely associated
with the condition of entry boots for the regular gasoline UST sump and the premium gasoline
UST sump.

In January 2008, Withers Ravenel (WR) completed Phase I and Phase II LSAs. One active water
supply well was identified within 1,000 feet of the site. Monitoring well MW-1, installed during a
previous phase of investigation, was determined to be improperly constructed, and was replaced
by WR. Monitoring wells MW-1A, MW-2, MW-3, and MW-4, were installed and sampled.
Laboratory analysis indicated monitoring well MW-1A and MW-4 contained concentrations of
petroleum constituents exceeding the 2L Standards but below GCLs.

In August 2009, WR sampled the four monitoring wells. The laboratory analytical results detected
concentrations of MTBE exceeding 2L Standards in monitoring wells MW-1A and MW-4. Di-
isopropyl ether was detected above 2L Standards in monitoring well MW-1A. All concentrations
were below their respective GCLs.

Comprehensive Site Assessment (CSA) activities were conducted in late 2009. Soil samples
were collected from three sides of the UST pit. One soil sample, installed in the general
area of SB-9 advanced by SEI during the Site Checks, contained MTBE above the soil-
to-groundwater MSCC. Five additional Type II monitoring wells (MW-5 through MW-9) and
one Type III monitoring well (DW-1) were installed and sampled in addition to the existing
monitoring wells. The laboratory analytical results detected concentrations of MTBE (MW-
1A, MW-3, MW-4, and DW-1), C5-C8 Aliphatics (MW-1A and DW-1), benzene (MW-1A), and
di-isopropyl ether (MW-1A and DW-1) exceeding their established 2L Standards in the
monitoring wells; however, all concentrations were below their respective GCLs.

Groundwater monitoring events were conducted by WR in October 2010, April 2011, and
September 2011. Groundwater samples were collected from each of the ten onsite
monitoring wells for analysis by EPA Methods 6200B, 625, and MADEP VPH/EPH. For all
three monitoring events, laboratory analytical results detected concentrations of MTBE above
2L Standards in MW-1A, MW-3, MW-4, and DW-1; C5-C8 aliphatics detected above 2L
Standards in MW-1A and DW-1; and DW-1 had 2L exceedances of di-isopropyl ether and
bis(2-ethyhexyl)phthalate. Monitoring well MW-1A had 2L exceedances of C9-C22 aromatics
and benzene in October 2011, and benzene in April 2011. Detected petroleum constituents
were below applicable GCLs for all sampling events.

In February 2012, groundwater samples were collected from each of the ten onsite wells
for analysis by EPA Methods 6200B and MADEP VPH/EPH. Laboratory analyses
indicated concentrations of MTBE equal to the GCL in monitoring well DW-1, and above
2L Standards in monitoring wells MW-1A and MW-4. Concentrations of C5-C8 aliphatics
were also above the 2L Standard in MW-1A and DW-1, and DW-1 also contained di-
isopropyl ether over the 2L Standard.

Monitoring Report Circle K 2723940
Incident No. 40437 Page 4

In November 2012, WR installed monitoring wells MW-10, MW-11, and DW-2 through
DW-4, and conducted a comprehensive groundwater sampling event. Concentrations of
C5-C8 aliphatics were detected above 2L Standards in monitoring wells MW-1A, MW-10,
and DW-1. MTBE exceedances were detected in MW-1, MW-1A, MW-3, MW-4, MW-10,
MW-11, DW-1, and DW-2.

In September 2013, WR conducted a comprehensive groundwater sampling event.
MTBE exceeded the GCL of 20,000 µg/L in wells DW-1 and MW-1A. Multiple monitoring
wells also contained one or more of the following contaminants at concentrations above
their respective 2L Standards: C5-C8 aliphatics, benzene, IPE, MTBE, and naphthalene.

WR and Advanced Environmental Services completed a 96-hour MMPE event from
August 26 – 30, 2013, on monitoring wells MW-1A, MW-10, and DW-1. A total of 1,604-
gallons of impacted groundwater and 15.87-gallons of VOC’s as vapor were removed
during the event.

A Corrective Action Plan, prepared by WR, proposed the installation of two shallow and two deep
screened ISOC Oxygen Diffusion wells in the area of MW-10 and DW-1 to address the MTBE
plume. The CAP was approved by NCDEQ in a NORR letter dated June 20, 2014, but was put
on hold following a new release discovered in December 2014.

Incident # 40437

In December 2014, gasoline product was observed discharging from the secondary
containment piping in the STP sump associated with the 20,000-gallon gasoline UST.
Line tightness testing revealed a leak in the flex connector. LNAPL assessment and
groundwater sampling activities were conducted in January 2015. MTBE exceeded the
GCL in well MW-10, and the 2L Standard in wells MW-3, MW-4, MW-11, DW-1, and DW-
2. Monitoring well MW-10 also contained Di-Isopropyl Ether, Toluene, and Total Xylenes
above 2L Standards.

Initial Abatement Actions completed in early 2015 involved soil sampling during the
installation of five Type II monitoring wells (MW-12 through MW-16), and four AFVR events.
Shallow soil samples contained benzene above the MSCC in three of the sampled locations.
Monitoring wells MW-12, MW-13, and MW-16 contained measurable LNAPL. MTBE
exceeded the GCL in well MW-14, which was attributed to the previous release, as MTBE
had reportedly been phased out several years prior. Four AFVR events completed in
January and February 2015 removed a combined total of 237.27 pounds (38.45
equivalent gallons) of gasoline as vapor, 7,970 gallons of impacted groundwater, and 9
gallons of free phase product.

A 96-hour MMPE event conducted in February 2016, removed 108.59 pounds (17.65
gallons) of VOCs as vapor, and 2,735 gallons of impacted groundwater. The subsequent
groundwater monitoring event detected concentrations of MTBE exceeding the GCL in
Monitoring Report Circle K 2723940
Incident No. 40437 Page 5

monitoring wells DW-1, MW-10, and MW-14. Multiple monitoring wells contained VOCs
exceeding 2L Standards.

Additional groundwater monitoring events were conducted in November 2016, April
2017, November 2017, April 2018, October 2018, May 2019, December 2019, and June
2020. Monitoring well MW-10 consistently contained MTBE above the GCL. Multiple
other wells contained additional VOCs exceeding 2L Standards. In June 2020, WR also
placed Provectus Oxygen Releasing Socks (ORS) in monitoring wells MW-10 and MW-
14. WR recommended semi-annual sampling of select monitoring wells until GCL
exceedances are reduced by biodegradation.

In January 2021, ATC conducted a limited groundwater monitoring event at the Circle K Store
No. 2723940, gauged the specified site wells and collected groundwater samples for laboratory
analysis. LNAPL was not measured or observed in the gauged and sampled monitoring wells.
Volatile organic compounds (VOCs) were not detected above Gross Contamination Levels
(GCLs) in the sampled monitoring wells. Methyl-tert-butyl-ether (MTBE) was detected above
North Carolina Groundwater Quality Standards according to 15A NCAC 2L .0202 Standards (2L
Standards) in the samples collected from monitoring wells MW-1A, MW-10, MW-14, MW-16, DW-
1, and DW-2. Monitoring wells MW-1A, MW-10, MW-16, DW-1, and DW-2 also contained two or
more petroleum constituents at concentrations above 2L Standards. Oxygenate tert-butyl alcohol
(TBA) was detected above 2L Standards in monitoring wells MW-10, MW-16, DW-1, and DW-2.
Monitoring well DW-3 did not contain detectable concentrations of VOCs. Petroleum constituents
were not detected in the water sample collected from water supply well WSW-1.

In June 2022, ATC conducted a groundwater monitoring event at the Circle K Store No. 2723940.
LNAPL was not measured or observed in the gauged and sampled monitoring wells. MTBE was
detected above 2L Standards in the samples collected from monitoring wells MW-4, MW-10, MW-
11, MW-12, MW-14, MW-15, MW-16, and DW-1.Oxygenate tert-butyl alcohol (TBA) was detected
above the North Carolina Gross Contamination Levels for Groundwater (GCL) in MW-10. TBA
was also detected above the above the North Carolina Groundwater Quality Standards according
to 15A NCAC 2L .0202 Standards (2L Standards) in the samples collected from monitoring wells
MW-4, MW-11, MW-12, MW-14, and DW-1.Monitoring wells MW-1A, MW-4, MW-10, MW-11,
MW-12, MW-14, MW-15, MW-16, and DW-1 also contained two or more petroleum constituents
at concentrations above 2L Standards. Based on the findings of this report, it appears that
constituents are generally decreasing in monitoring wells MW-1A, MW-3, MW-13, MW-4 and MW-
15. Constituent concentrations are generally stable in monitoring wells MW-4, MW-11, and MW-
12.

On December 8, 2022, ATC conducted a groundwater sampling event. Monitoring wells MW-1A,
MW-3, MW-4, MW-6, MW-10, MW-11, MW-12, MW-13, MW-14, MW-15, and DW-1 through DW-
3 were gauged for depth to water and total well depth, with an electronic water level indicator.
On December 8, 2022, ATC gauged and sampled monitoring wells MW-1A, MW-3, MW-4, MW-
6, MW-10, MW-11, MW-12, MW-13, MW-14, MW-15, DW-1, DW-2, DW-3. ATC sampled
monitoring wells MW-1A, MW-3, MW-4, MW-6, MW-10, MW-11, MW-12, MW-13, MW-14, MW-
Monitoring Report Circle K 2723940
Incident No. 40437 Page 6

15, DW-1, DW-2, DW-3. LNAPL was measured at a thickness of 0.08 feet in MW-16 therefore it
was not sampled. Methyl-Tert-Butyl-Ether (MTBE and Tert-butyl Alcohol (TBA) were detected
above the North Carolina Gross Contamination Levels for Groundwater Levels (GCLs) in the
samples collected from monitoring wells MW-11 and DW-1. Monitoring wells MW-1A, MW-4, MW-
10, MW-11, MW-12, MW-14, MW-15, MW-16, and DW-1 also contained two or more petroleum
constituents at concentrations above 2L Standards. Monitoring wells MW-3, MW-6, MW-13, and
DW-3 did not contain detectable concentrations of VOCs.

3.0 GEOLOGIC FRAMEWORK

According to the 1985 “Geologic Map of North Carolina”, the site is located in the Charlotte Belt
of the Piedmont Physiographic Province. Subsurface lithology in the region consists of
metamorphosed, inter-bedded tuffs and flow rock of felsic to mafic composition. Granitic
intrusions are also common in the area.

The soils are typically saprolitic and are formed by in-place weathering of bedrock and the
subsequent breakdown of associated minerals. Surficial soils reported by previous consultants
during drilling activities consisted of red silt clay to approximately 15-feet Below Ground Surface
(BGS) and partially weathered rock (PWR) from 15-feet BGS to at least 20-feet BGS.

4.0 MOBILE MULTI-PHASE EXTRACTION EVENT
From June 19 to June 23, 2023, Zava Industrial, Inc. (Zava) performed 96-hour MMPE event.
ATC personnel provided onsite supervision for event set-up and break-down. Monitoring wells
MW-11, MW-12 and MW-16 were utilized as target extraction wells for the 96-hour MMPE event.
Prior to starting and upon completion of the MMPE event, extraction wells were gauged for liquid
levels. LNAPL was not detected in the wells during pre- or post-MMPE well gauging.

During MMPE activities, a liquid ring vacuum pump unit is plumbed to the designated extraction
point, and a drop pipe is extended into the well through an airtight seal at the top of the well casing
and into the water column. Throughout the MMPE process, a cone of depression forms around
the designated recovery point by drawing down the groundwater surface levels, thus causing
impacted water surrounding the recovery point to be extracted. Petroleum-impacted soil vapor
within the cone of depression and the overlying vadose zone is removed as part of the MMPE
extraction process.

The 96-hour AS/MMPE event began on June 19, 2023, and ended on June 23, 2023. The effluent
air stream was monitored for temperature, velocity, relative humidity, and organic vapor
concentrations on a daily basis. Calculated effluent airflow rates and the vapor concentration
readings from the vacuum truck indicated that an estimated 123.68 pounds (22.95 equivalent
gallons) of petroleum hydrocarbons were recovered as vapor during the MMPE event. The MMPE
event generated approximately 5,456 gallons of petroleum impacted groundwater.

Monitoring Report Circle K 2723940
Incident No. 40437 Page 7

A report provided by Zava, which includes monitoring data, emissions and recovery calculations,
and waste disposal manifests is included in Appendix A.

5.0 SITE ASSESSMENT ACTIVITIES

5.1 Groundwater Sampling Activities
On July 17, 2023, ATC conducted a groundwater sampling event. monitoring wells MW-1A, MW-
3, MW-4, MW-6, MW-10, MW-11, MW-12, MW-13, MW-14, MW-15, MW-16 and DW-1 through
DW-3 were gauged for depth to water and total well depth with an electronic water level indicator.

Depths to groundwater in the shallow monitoring wells ranged from 7.64-feet below top of casing
(ft-BTOC) in MW-4, to 12.25 ft-BTOC in MW-11. Shallow groundwater flow was interpreted to
trend generally to the northeast as shown on Figure 4. The screened intervals for deep monitoring
wells DW-1 through DW-3 do not intersect the water table, thus these wells were not utilized in
the determination of shallow groundwater flow. Groundwater generally flows to the northwest.

Type III monitoring wells DW-1 and DW-3 are both installed to 50-feet BGS and screened from
45 to 50-feet BGS and monitoring well DW-2 is installed to 80-feet BGS and screened from 70 to
80-feet BGS. Due to the difference in constructions, it is not possible to interpret potential
groundwater movement deeper in the aquifer. A summary of current and historical liquid level
data is included as Table 5.

Groundwater samples were collected from monitoring wells MW-1A, MW-3, MW-4, MW-6, MW-
10, MW-11, MW-12, MW-13, MW-14, MW-15, MW-16, and DW-1 through DW-3. The wells were
purged prior to sample collection using new, disposable polyvinyl chloride bailers or a submersible
pump and clean tubing, while wearing new, disposable nitrile gloves. Purging was accomplished
by removing a minimum of three well volumes or until the well was bailed dry and allowed to
recharge. Field parameters were measured at the time of sampling and recorded in field books.
Field notes are included as Appendix A.

Groundwater samples were placed into laboratory provided sample containers, sealed and
labeled, and placed into an ice-filled cooler for preservation. Following completion of sampling
activities, samples were submitted under chain-of-custody protocol to Pace Analytical Services,
LLC (Pace), a North Carolina certified laboratory, located in Huntersville, North Carolina. The
groundwater samples were analyzed for select volatile organic compounds (VOCs) and
oxygenates by Standard Method 6200B.

5.2 Groundwater Analytical Results
Groundwater analytical results from samples collected are summarized as follows:
 ATC sampled monitoring wells MW-1A, MW-3, MW-4, MW-6, MW-10, MW-11, MW-12,
MW-13, MW-14, MW-15, MW-16 and DW-1, DW-2, DW-3.
Monitoring Report Circle K 2723940
Incident No. 40437 Page 8

 Methyl-Tert-Butyl-Ether (MTBE and Tert-butyl Alcohol (TBA) were detected above the
North Carolina Gross Contamination Levels for Groundwater Levels (GCLs) in the
samples collected from monitoring well MW-11.
 Monitoring wells MW-1A, MW-4, MW-10, MW-11, MW-12, MW-14, MW-15, MW-16, and
DW-1 also contained two or more petroleum constituents at concentrations above 2L
Standards.
 Monitoring wells MW-3, MW-6, MW-13, DW-2 and DW-3 did not contain detectable
concentrations of VOCs.

Summaries of the current and historical groundwater analytical data are provided in Table 6 and
Table 7 Contaminants detected above 2L Standards are identified and summarized on Figure 5.
The laboratory analytical report and chain-of-custody documentation is included as Appendix B.

6.0 CONCLUSIONS AND RECOMMENDATIONS

From June 19 to June 23, 2023, Zava Industrial, Inc. (Zava) performed 96-hour MMPE event. On
July 17, 2023, ATC conducted a groundwater monitoring event at the Circle K Store No. 2723940,
which included gauging the site wells and collecting groundwater samples for laboratory analysis.
These activities were conducted in accordance with the Pre-Approval Task Authorization (PATA)
number 36286-19, approved on May 22, 2023 based on the field activities and laboratory analysis
discussed herein, ATC offers the following findings:

 An estimated 123.68 pounds (22.95 equivalent gallons) of petroleum hydrocarbons were
recovered as vapor during the MMPE event. The MMPE event generated approximately
5,456 gallons of petroleum impacted groundwater.
 ATC gauged and sampled monitoring wells MW-1A, MW-3, MW-4, MW-6, MW-10, MW-
11, MW-12, MW-13, MW-14, MW-15, MW-16, DW-1, DW-2, DW-3.
 LNAPL was not detected during the July 2023 sampling event.
 Methyl-Tert-Butyl-Ether (MTBE and Tert-butyl Alcohol (TBA) were detected above the
North Carolina Gross Contamination Levels for Groundwater Levels (GCLs) in the
samples collected from monitoring well MW-11.
 Monitoring wells MW-1A, MW-4, MW-10, MW-11, MW-12, MW-14, MW-15, MW-16, and
DW-1 also contained two or more petroleum constituents at concentrations above 2L
Standards.
 Monitoring wells MW-3, MW-6, MW-13, DW-2 and DW-3 did not contain detectable
concentrations of VOCs.
 Groundwater flows to the northwest and to the southeast from a high centered at MW-1A.
 The concentration of MTBE in DW-1 indicates that the vertical extent of the contaminant
plume has not been defined at depth in that area.

Subsequent to the MMPE event groundwater analytical results indicate that the contaminant
plume is generally stable, and LNAPL was not detected in MW-16. The constituent
concentrations reported in MW-16 were reduced compared to the June 2022 sampling event.
Monitoring Report Circle K 2723940
Incident No. 40437 Page 9

ATC recommends an additional groundwater monitoring event to monitor the stability of the
constituent concentrations and determine if the presence of residual LNAPL has been
addressed.
7.0 LIMITATIONS
This report has been prepared for the exclusive use of Circle K Stores Inc. for specific application
to the referenced site in Charlotte, North Carolina. The assessment was conducted based on the
scope-of-work and level of effort requested by the NCDEQ and with resources adequate only for
that scope-of-work. Our findings have been developed in accordance with generally accepted
standards of geology and hydrogeology practices in the State of North Carolina, available
information, and our professional judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise
locations sampled and at the time the samples were collected. Additionally, the data obtained
from samples would be interpreted as being meaningful with respect to parameters indicated in
the laboratory report. No additional information can be logically be inferred from these data.
Conclusions and recommendations set forth herein are applicable only to the facts and conditions
described at the time of this report.

TABLES
UST ID
Number
Current / Last
Contents*
Previous
Contents*
Capacity
(gal)
Construction
Details**
Tank
Dimensions
Description
of Associated
Piping &
Pumps
Date Tank
Installed
Status of
UST System***
Was Release
Associated with
the UST
System?
1A Unleaded N/A 20,000 Fiberglass Unknown Fiberglass 8/15/1997 Active Yes
1B Premium N/A 8,000 Fiberglass Unknown Fiberglass 8/15/1997 Active Yes
2A Diesel N/A 3,000 Fiberglass Unknown Fiberglass 8/15/1997 Active Yes
2B Boat Fuel Race Fuel 3,000 Fiberglass Unknown Fiberglass 8/15/1997 Active Yes
AST ID Number Current / Last
Contents*
Previous
Contents*
Capacity
(gal)
Construction
Details**
Tank
Dimensions
Description
of Associated
Piping &
Pumps
Date Tank
Installed
Status of
AST System***
Was Release
Associated with
the AST
System?
Incident
Number
Material
Released Date of Release
36286 Gasoline/Diesel 3/2/2007
40437 Gasoline 12/23/2014
Table 1: Site History - UST System and Other Release Information
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Pressure loss from the 20,000-gallon gasoline UST distribution piping to the dispesner identified as 9/10 was observed on
December 23, 2014. Subsequent investigation revealed free phase product within the STP sump associated with the 20,000-
gallon gasoilne UST and in the tank field observation wells
Incident Number: 36286 & 40437
Not Applicable
Description of Release
UST assessment activities took place on March 1, 2007. Confirmation of a release was detected on March 2, 2007 and
provided to NCDENR on April 2, 2007.
Page 1 of 1
UST ID Number 0-035583
State Zip
NC 27606
Incident Number
State Zip
NC 27511
State Zip
----
State Zip
----
1 through 4 Facility ID Number
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
City Telephone Number
Raleigh [phone]
36286 & 40437
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
The Pantry April 2007 - March 2015
Unknown Unknown
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
Circle K Stores, Inc.March 2015 - Present
Petro Properties, LLC April 1999 - April 2007
Street Address
Street Address
Unknown
City Telephone Number
Street Address
1100 Situs Court, Suite 100
305 Gregson Drive
City Telephone Number
Cary [phone]
Table 2: Site History - UST Owner/Operator Information
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
H&H Properties, LLC December 1997 - April 1999
Street Address
Unknown
City Telephone Number
Unknown Unknown
Page 1 of 2
UST ID Number 0-0355831 through 4 Facility ID Number
Table 2: Site History - UST Owner/Operator Information
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
State Zip
----
Name of Operator Dates of Operation
(mm/dd/yy to mm/dd/yy)
DHS Associates August - December 1997
Street Address
Unknown
City Telephone Number
Unknown Unknown
Page 2 of 2
Parcel
Number Property Street Address Property Owner Owner's Mailing Address Occupant/Use
(Site)
2936206
National Retail Properties,
LP Site
2936109 #123 WEC 99J-51 LLC
(CVS Pharmacy)CVS Pharmacy EastP.O. Box 4900 Scottsdale,
AZ 85261
10515 Mallard Creek Road
Charlotte, NC
450 S. Orange Avenue,
Suite 900 Orlando, FL
32801
South Central Oil Co. Inc.
(Mallard Crossing Shopping
Center)
2121 West Main Street
Albemarle, NC 28001
H&L Zoukis, LLC 4492 Edsall Avenue
Woodbridge, VA 22192
Ralph and Shirley Moncy 59 Tarheel Road Maggie
Valley, NC 28751
2936207 Bellsouth
Telecommunications, Inc.Utilities East1155 N.E. Peachtree Street
Atlanta, GA 30309
10415 Mallard Creek Road
Charlotte, NC
4716819 Cogdell Investors and the
Cogdell Group, Inc.Commercial South
4716820 Private Investor XV, LLC Commercial Southeast2423 Highway 17 South N.
Myrtle Beach, SC 29502
10400 Mallard Creek Road
Charlotte, NC
10310 Mallard Creek Road
Charlotte, NC
4401 Barclay Downs Drive,
#300 Charlotte, NC 28209
10409 Mallard Creek Road
Charlotte, NC
10329 Mallard Creek Road
Charlotte, NC
3021 Properity Church Road
Charlotte, NC
3116 Prosperity Church Road
Charlotte, NC2936105 Commercial North
2936203 Bank of America West
2936205 Bojangles West
Location in Relation to Site
Source
Circle K 2723940
Table 3: Adjoining Property Information
Cirlce K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
Page 1 of 1
10124 Pinewood Drive
Charlotte, NC 28269
10115 Pinewood Lane
Charlotte, NC 28269
Other Potential Receptors
Distance
From
Source Area
(feet)
Unknown
Current
Status
Year
Installed Well Use Well
Construction
Up or
Down
Gradient
Up
Well No.Parcel
Number Property Owner Well and Owner Mailing
Address
Not Applicable
Receptor ID Parcel
Number Property Owner Owner's Mailing Address Location
WSW-1 2726145 Roy Martin Kinnamon Unknown Active
Owner's
Phone Number
Usage
Distance
from Source
Area (feet)
~900
Up or down gradient
Sole
Source Unknown
Table 4: Water Supply Well & Receptor Data
WSW-2 2727187 Eugene & Brenda Brand Unkown Unlown Unknown Unkown Unknown Up ~1400
Incident Number: 36286 & 40437
Charlotte, Mecklenburg County, North Carolina
10409 Mallard Creek Road
Circle K 2723940
Page 1 of 1
Well ID Date Measured
Screen
Interval
(ft)
Well
Depth
(ft BGS)
Top of
Casing
Elevation
(ft)
Depth to
LNAPL (ft
BTOC)
Depth to
Water (ft
BTOC)
LNAPL
Thickness
(ft)
Groundwater
Elevation (ft)
1/21/2008 -6.51 -91.98
8/13/2009 -9.34 -89.15
12/21/2009 -8.94 -89.55
10/19/2010 -11.31 -87.18
4/11/2011 -10.36 -88.13
9/13/2011 -10.61 -87.88
2/2/2012 -9.43 -89.06
11/9/2012 -10.77 -87.72
9/19/2013 -9.44 -89.05
1/6/2015 9.18 14.18 5.00 84.31
3/22/2016 -7.89 -90.60
11/15/2016 -9.86 -88.63
4/27/2017 -9.76 -88.73
4/17/2018 -9.89 -88.60
10/31/2018 -8.85 -89.64
5/3/2019 -4.97 -93.52
12/4/2019 -8.39 -90.10
6/2/2020 -7.15 -91.34
1/7/2021 -8.89 -89.60
6/30/2022 -10.21 -88.28
12/8/2022 -9.85 -88.64
7/17/2023 -9.29 -89.20
1/21/2008 -16.00 -84.00
8/13/2009 -13.01 -86.99
12/21/2009 -12.70 -87.30
10/19/2010 -13.77 -86.23
4/11/2011 -12.97 -87.03
9/13/2011 -15.50 -84.50
2/2/2012 -13.97 -86.03
11/9/2012 -16.13 -83.87
9/19/2013 -13.99 -86.01
1/6/2015 -14.40 -85.60
3/22/2016 -NM --
11/15/2016 -NM --
6/30/2022 -14.88 -85.12
1/21/2008 -17.02 -79.18
8/13/2009 -8.19 -88.01
12/21/2009 -9.22 -86.98
10/19/2010 -10.80 -85.40
4/11/2011 -9.41 -86.79
9/13/2011 -11.86 -84.34
2/2/2012 -8.65 -87.55
11/9/2012 -13.82 -82.38
9/19/2013 -10.38 -85.82
1/6/2015 -9.65 -86.55
3/22/2016 -8.41 -87.79
11/15/2016 -11.74 -84.46
4/27/2017 -4.47 -91.73
6/30/2022 -12.29 -83.91
12/8/2022 -11.01 -85.19
7/17/2023 -9.02 -87.18
MW-3 3.5 - 18.5 19 96.2
MW-2 4 - 19 19 100
MW-1A 4 - 19 19 98.49
Table 5: Well Construction and Groundwater Elevation Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1/21/2008 -8.48 -85.97
8/13/2009 -9.15 -85.30
12/21/2009 -7.10 -87.35
10/19/2010 -8.91 -85.54
4/11/2011 -8.51 -85.94
9/13/2011 -10.10 -84.35
2/2/2012 -8.14 -86.31
11/9/2012 -10.79 -83.66
9/19/2013 -8.45 -86.00
1/6/2015 -8.50 -85.95
3/22/2016 -7.30 -87.15
11/15/2016 -9.82 -84.63
4/27/2017 -7.00 -87.45
6/30/2022 -9.28 -85.17
12/8/2022 -10.05 -84.40
7/17/2023 -7.64 -86.81
12/21/2009 -11.07 -89.13
10/19/2010 -12.58 -87.62
4/11/2011 -11.78 -88.42
9/13/2011 -13.61 -86.59
2/2/2012 -11.15 -89.05
11/9/2012 -14.41 -85.79
9/19/2013 -11.47 -88.73
1/6/2015 -NM --
3/22/2016 -NM --
11/15/2016 -NM --
6/30/2022 -12.61 -87.59
12/21/2009 -10.27 -88.66
10/19/2010 -12.11 -86.82
4/11/2011 -11.38 -87.55
9/13/2011 -13.02 -85.91
2/2/2012 -10.70 -88.23
11/9/2012 -14.98 -83.95
9/19/2013 -10.55 -88.38
1/6/2015 -NM --
3/22/2016 -NM --
11/15/2016 -NM --
4/27/2017 -5.36 -93.57
6/30/2022 -11.90 -87.03
12/8/2022 -13.57 -85.36
7/17/2023 -7.82 -91.11
12/21/2009 -19.13 -80.38
10/19/2010 -20.44 -79.07
4/11/2011 -20.13 -79.38
9/13/2011 -21.96 -77.55
2/2/2012 -19.98 -79.53
11/9/2012 -22.53 -76.98
9/19/2013 -19.53 -79.98
1/6/2015 -20.94 -78.57
3/22/2016 -17.65 -81.86
11/15/2016 -21.36 -78.15
4/27/2017 -19.99 -79.52
6/30/2022 -21.13 -78.38
12/21/2009 -5.15 -89.49
10/19/2010 -5.83 -88.81
4/11/2011 -7.12 -87.52
9/13/2011 -12.61 -82.03
2/2/2012 -7.25 -87.39
11/9/2012 -13.42 -81.22
9/19/2013 -9.58 -85.06
1/6/2015 -10.26 -84.38
3/22/2016 -NM --
11/15/2016 -NM --
6/30/2022
MW-7 7 - 37 37 99.51
Not Located
MW-8 5 - 20 20 94.64
MW-5 5 - 20 20 100.2
MW-6 2.5 - 17.5 17.5 98.93
MW-4 4 - 29 29 94.45
12/21/2009 -5.91 -88.02
10/19/2010 -6.58 -87.35
4/11/2011 -7.57 -86.36
9/13/2011 -16.07 -77.86
2/2/2012 -5.68 -88.25
11/9/2012 -16.43 -77.50
9/19/2013 -7.93 -86.00
1/6/2015 -7.20 -86.73
3/22/2016 -5.67 -88.26
11/15/2016 -15.03 -78.90
4/27/2017 -3.82 -90.11
6/30/2022 -13.73 -80.20
11/9/2012 -14.91 -83.70
9/19/2013 -11.88 -86.73
1/6/2015 -13.58 -85.03
3/22/2016 -11.47 -87.14
11/15/2016 -14.03 -84.58
4/27/2017 -12.08 -86.53
4/17/2018 -12.58 -86.03
10/31/2018 -11.75 -86.86
5/3/2019 -9.79 -88.82
12/4/2019 -12.94 -85.67
6/2/2020 -10.03 -88.58
1/7/2021 -11.81 -86.80
6/30/2022 -13.61 -85.00
12/8/2022 -14.70 -83.91
7/17/2023 -12.11 -86.50
11/9/2012 -15.28 -83.83
9/19/2013 -12.93 -86.18
1/6/2015 -14.59 -84.52
3/22/2016 -NM --
11/15/2016 -14.54 -84.57
6/30/2022 -13.86 -85.25
12/8/2022 -15.90 -83.21
7/17/2023 -12.25 -86.86
3/22/2016 -8.95 -89.00
11/15/2016 -13.55 -84.40
4/27/2017 -12.69 -85.26
6/30/2022 -13.58 -84.37
12/8/2022 -12.05 -85.90
7/17/2023 -11.25 -86.70
3/22/2016 -5.96 -92.92
11/15/2016 -9.93 -88.95
4/27/2017 -9.67 -89.21
6/30/2022 -11.19 -87.69
12/8/2022 -11.65 -87.23
7/17/2023 -9.21 -89.67
3/22/2016 -9.68 -88.53
11/15/2016 -11.70 -86.51
4/27/2017 -9.64 -88.57
4/17/2018 -10.79 -87.42
10/31/2018 -9.75 -88.46
5/3/2019 -8.92 -89.29
12/4/2019 -10.23 -87.98
6/2/2020 -9.19 -89.02
1/7/2021 -10.10 -88.11
6/30/2022 -12.05 -86.16
12/8/2022 -12.75 -85.46
7/17/2023 -10.17 -88.04
3/22/2016 -9.49 -89.24
11/15/2016 -11.25 -87.48
4/27/2017 -9.28 -89.45
6/30/2022 -12.11 -86.62
12/8/2022 -12.60 -86.13
7/17/2023 -10.17 -88.56
MW-12 3 - 18 18 97.95
MW-13 5 - 20 20 98.88
MW-15 5 - 20 20 98.73
MW-9 5 - 20 20 93.93
MW-14 5 - 20 20 98.21
MW-10 5 - 20 25 98.61
MW-11 5 - 20 25 99.11
3/22/2016 -9.70 -87.55
11/15/2016 -12.69 -84.56
4/27/2017 -11.74 -85.51
4/17/2018 -12.03 -85.22
10/31/2018 -11.42 -85.83
5/3/2019 -7.69 -89.56
12/4/2019 -11.84 -85.41
6/2/2020 -6.73 -90.52
1/7/2021 -10.56 -86.69
6/30/2022 -13.24 -84.01
12/8/2022 14.33 14.41 0.08 82.90
7/17/2023 -10.96 -86.29
12/21/2009 -14.89 -83.45
10/19/2010 -14.30 -84.04
4/11/2011 -14.47 -83.87
9/13/2011 -14.71 -83.63
2/2/2012 -13.64 -84.70
11/9/2012 -16.42 -81.92
9/19/2013 -12.53 -85.81
1/6/2015 -12.58 -85.76
3/22/2016 -12.40 -85.94
11/15/2016 -13.26 -85.08
4/27/2017 -11.83 -86.51
4/17/2018 -13.23 -85.11
10/31/2018 -13.80 -84.54
5/3/2019 -10.31 -88.03
12/4/2019 -9.72 -88.62
6/2/2020 -9.94 -88.40
1/7/2021 -9.77 -88.57
6/30/2022 -13.01 -85.33
12/8/2022 -14.70 -83.64
7/17/2023 -12.67 -85.67
11/9/2012 -31.14 -66.13
9/19/2013 -17.79 -79.48
1/6/2015 -18.10 -79.17
3/22/2016 -14.77 -82.50
11/15/2016 -18.52 -78.75
4/27/2017 -17.77 -79.50
4/17/2018 -18.10 -79.17
10/31/2018 -17.72 -79.55
5/3/2019 -12.96 -84.31
12/4/2019 -18.18 -79.09
6/2/2020 -13.66 83.61
1/7/2021 -15.94 -81.33
6/30/2022 -18.68 -78.59
12/8/2022 -20.15 -77.12
7/17/2023 -16.30 -80.97
11/9/2012 -15.24 -83.85
9/19/2013 -11.64 -87.45
1/6/2015 -14.46 -84.63
3/22/2016 -NM --
11/15/2016 -NM --
4/17/2018 -11.53 -87.56
10/31/2018 -11.94 -87.15
5/3/2019 -12.27 -86.82
12/4/2019 -9.69 -89.40
1/7/2021 -10.48 -88.61
1/7/2021 -10.82 -88.27
6/30/2022 -13.73 -85.36
12/8/2022 -15.13 -83.96
7/17/2023 -11.51 -87.58
DW-3 45 - 50 50 99.09
DW-1 45 - 50 50 98.34
DW-2 70 - 80 80 97.27
MW-16 5 - 20 20 97.25
11/9/2012 -NM --
9/19/2013 -13.02 -87.12
1/6/2015 -16.15 -83.99
3/22/2016 -NM --
11/15/2016 -NM --
6/30/2022 -21.98 -78.16
Notes:
ft = feet
ft-bgs = feet below ground surface
ft-toc = feet below top of casing
LNAPL = Light Non-Aqueous Phase Liquid
- = LNAPL Not Measured
DW-4 38 - 43 43 100.14
1 600 600 500 20 6 70 70 70 400 400 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 70,000 26,100 26,100 28,500 24,100 12,800 10,000 8,500 N/A 70,000
MW-1A 07/17/2023 86.8 21.3 755 2,700 66.4 435 3.3J 109 371 3,330 882 <3.1 309J <2.1 <4.3 <1.7
MW-3 07/17/2023 <0.079 <0.090 <0.081 <234 0.47J <0.10 <0.072 <0.11 <0.10 <0.031 <0.071 <0.12 <4.1 <0.085 <0.17 <0.069
MW-4 07/17/2023 <0.39 <0.45 <0.41 <1.19 850 <0.50 12.2 <0.53 <0.52 2.5 <0.36 <0.62 294 <0.43 <0.86 <0.35
MW-6 07/17/2023 <0.079 0.33J <0.081 <234 <0.053 0.11J <0.072 <0.11 <0.10 <0.031 <0.071 <0.12 <4.1 <0.085 <0.17 <0.069
MW-10 07/17/2023 <7.9 67.3 47.9J 208.4 9,480 <10.1 92.9 <10.6 <10.5 52.7 <7.1 176J 8,210 <8.5 <17.3 <6.9
MW-11 07/17/2023 <9.8 <11.2 <10.2 <47.1 22,800 <12.6 405 <13.2 <13.1 40.3J 12.5J 464J 14,000 <10.6 <21.6 <8.6
MW-12 07/17/2023 1,490 799 2,210 9,420 2,840 733 70.5 136 414 3,520 761 47.3J 3,810 18.2J 21.3 <2.8
MW-13 07/17/2023 0.15J 0.32J 0.10J <0.56J 0.39J 0.34J <0.072 <0.11 <0.10 0.64 0.092J <0.12 5.0J 0.65 <0.17 4.6
MW-14 07/17/2023 <1.6 <1.8 <1.6 <4.8 2,710 7.6J 39.2 <2.1 <2.1 11.4 <1.4 52.7J 1,720 <1.7 <3.5 <1.4
MW-15 07/17/2023 <0.16 <0.18 0.60J 2.5 227 0.84J 4.5 <0.21 <0.21 3.3 <0.14 4.0J 91.7J <0.17 <0.35 <0.14
MW-16 07/17/2023 55.0 83.7 1,260 6,820 3,250 915 51.6 115 335 3,530 701 50.8J 3,140 <2.1 16.7 4.3J
DW-1 07/17/2023 <9.8 <11.2 <10.2 <29.7 13,900 <12.6 181 <13.2 <13.1 64.8 <8.9 280J 7,460 <10.6 <21.6 949
DW-2 07/17/2023 <0.079 <0.090 <0.081 <234 4.4 <0.10 13.0 <0.11 <0.10 <0.031 <0.071 <0.12 <4.1 <0.085 <0.17 <0.069
DW-3 07/17/2023 <0.079 <0.090 <0.081 <234 0.087J <0.10 <0.072 <0.11 <0.10 <0.031 <0.071 <0.12 <4.1 <0.085 <0.17 <0.069
Results in BOLD exceed 2L Standards
Results in BOLD ITALICS exceed GCL
Table 6: Current Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroformDiisopropyl etherIsopropylbenzene n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2L Standards
GCL Standards tert-Amylmethyl ethertert-Butyl Alcoholsec-ButylbenzeneWell IDConstituent of ConcernBenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalenePage 1 of 1
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
MW-1 7/20/2009 1,480 515.0 134 548 10,500 BDL BDL BDL BDL BDL BDL BDL BDL ------
1/18/08 BDL BDL BDL BDL 43,000 BDL BDL BDL BDL BDL BDL BDL BDL ------
8/13/09 BDL BDL BDL BDL 19,900 BDL BDL 165 BDL BDL BDL BDL BDL ------
12/15/09 14 BDL BDL BDL 21,000 BDL BDL 140 BDL BDL BDL BDL BDL ------
10/19/10 2 BDL BDL BDL 2,600 BDL BDL 31 BDL BDL BDL BDL BDL ------
4/12/11 5 BDL BDL BDL 5,000 BDL BDL 48 BDL BDL BDL BDL BDL ------
9/13/11 4 BDL BDL BDL 8,800 BDL BDL 64 BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL 5,000 BDL BDL BDL BDL BDL BDL BDL BDL ------
11/6/12 BDL BDL BDL BDL 1,600 BDL BDL 24 BDL BDL BDL BDL BDL ------
9/19/13 72 BDL 73 114 3,200 19 4 29 BDL 4.0 6.4 70 5.4 ------
3/22/16 3,300 12,700 2,080 16,750 1,340 BDL BDL BDL BDL BDL 405 4,380 999 ------
11/15/16 3,030 7,970 1,970 15,540 519 <1000 <200 <200 <200 <200 339 3,960 927 ------
4/27/17 1,180 3,950 1,400 11,280 BDL 522 BDL BDL BDL 98 270 3,460 858 ------
4/17/18 464 719 1,210 8,030 BDL BDL BDL BDL BDL BDL 244 2,780 712 ------
10/31/18 260 270 530 3,090 55 220 BDL 8 BDL BDL 100 1,300 420 ------
5/3/19 10 6 1,100 1,810 BDL 530 BDL BDL 10 48 190 2,100 370 ------
12/4/19 1,300 80 1,500 7,000 440 600 BDL 63 70 130 410 4,300 1,100 ------
6/2/20 1,340 72.4 J 1,250 4,549 208 392 J BDL 22.3 J 52.3 J 79.1 J 227 2,890 565 ------
1/7/21 865 35.9 2,060 6,770 289 911 <13.2 <16.7 <17.6 226 776 7,410 1,650 <2020 <148 <880 ---
6/30/2022 7.1 6.6 437 11.7 <1.1 367 <0.80 <0.77 <1.2 56.1 179 6.1 2.3 <91.0 <23.1 <67.0 13.6 --
12/8/2022 18.9 5.3 400 8.9 <1.1 274 <0.80 <0.77 <1.2 59.5 167 2.0 <0.83 <91.0 <23.1 <67.0 12.8 --
07/17/2023 86.8 21.3 755 2,700 66.4 435 <2.6 3.3J <1.7 109 371 3,330 882 <186 <3.1 309J <2.1 <4.3 <1.7
1/18/08 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
8/13/09 BDL BDL BDL BDL 58 BDL BDL BDL BDL BDL BDL BDL BDL ------
12/17/09 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
4/12/11 BDL 10.0 2 12 BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL 1 BDL BDL BDL BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
11/6/12 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
3/22/16 -------------------
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
MW-2 1,2,3-TrichloropropaneChloroformMW-1A
Page 1 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform1/18/08 BDL BDL BDL BDL 50 BDL -5 ---BDL -------
8/13/09 BDL BDL BDL BDL 109 NT -BDL ---BDL -------
12/16/09 BDL BDL BDL BDL 100 BDL -3 ---BDL -------
10/19/10 BDL BDL BDL BDL 92 BDL -3 ---BDL -------
4/12/11 BDL BDL BDL BDL 34 BDL -1 ---BDL -------
9/13/11 BDL BDL BDL BDL 70 BDL -2 ---BDL -------
2/2/12 BDL BDL BDL BDL 19 NT -BDL ---BDL -------
11/6/12 BDL BDL BDL BDL 37 BDL -BDL ---BDL -------
9/19/13 BDL BDL BDL BDL 69 BDL -BDL ---BDL -------
1/6/15 BDL BDL BDL BDL 21 --BDL ---BDL -------
3/22/16 BDL BDL BDL BDL 28.5 --BDL ---BDL -------
11/15/16 BDL BDL BDL BDL 16.6 --BDL ---BDL -------
4/27/17 BDL BDL BDL BDL BDL --BDL ---BDL -------
06/30/2022 <0.34 <0.48 <0.30 <0.34 4.0 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
12/08/2022 <0.34 <0.24 <0.30 <1.05 1.2 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
07/17/2023 <0.079 <0.090 <0.081 <234 0.47J <0.10 <0.11 <0.072 <0.066 <0.11 <0.10 <0.031 <0.071 <7.4 <0.12 <4.1 <0.085 <0.17 <0.069
1/18/08 BDL BDL BDL BDL 1,100 BDL -36 ---BDL -------
8/13/09 BDL BDL BDL BDL 496 NT -36 ---BDL -------
12/15/09 BDL BDL BDL BDL 430 BDL -7 ---BDL -------
10/19/10 BDL BDL BDL BDL 140 BDL -2 ---BDL -------
4/12/11 BDL BDL BDL BDL 500 BDL -BDL ---BDL -------
9/13/11 BDL BDL BDL BDL 250 BDL -3 ---BDL -------
2/2/12 BDL BDL BDL BDL 260 NT -BDL ---BDL -------
11/6/12 BDL BDL BDL BDL 230 BDL -2 ---BDL -------
9/19/13 BDL BDL BDL BDL 91 BDL -1 ---BDL -------
1/6/15 BDL BDL BDL BDL 260 --5 ---BDL -------
3/22/16 BDL BDL BDL BDL 433 --6 ---BDL -------
11/15/16 BDL BDL BDL BDL 244 --2.96 ---BDL -------
4/27/17 BDL BDL BDL BDL 230 --2.74 --BDL -------
06/30/2022 <4.3 <6.1 <3.8 <4.2 1440 <8.1 <4.0 19.7 <6.1 <4.2 <4.2 <6.2 <4.2 <455 <116 427J <5.0 --
12/08/2022 <0.86 <0.60 <0.76 <2.64 402 <1.6 <0.80 4.9 <1.2 <0.83 <0.85 <1.2 <0.83 <91.0 <23.1 185 <1.0 --
07/17/2023 <0.39 <0.45 <0.41 <1.19 850 <0.50 <0.53 12.2 <0.33 <0.53 <0.52 2.5 <0.36 <37.2 <0.62 294 <0.43 <0.86 <0.35
MW-3
MW-4
Page 2 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform12/16/09 BDL BDL BDL BDL BDL BDL -BDL ---BDL -----
10/19/10 BDL BDL BDL BDL BDL BDL -BDL ---BDL -------
4/12/11 BDL BDL BDL 6.0 BDL BDL -BDL ---BDL -------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL ---BDL -------
2/2/12 BDL BDL BDL BDL BDL NT -BDL ---BDL -------
11/7/12 BDL BDL BDL BDL BDL BDL -BDL ---BDL -------
9/19/13 BDL BDL BDL BDL BDL BDL -BDL ---BDL -------
1/13/15 BDL BDL BDL BDL BDL BDL -BDL --BDL -------
12/17/09 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
4/12/11 BDL 16 6.3 39 BDL BDL -BDL BDL BDL BDL 2.4 BDL ------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
11/7/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL 5.4 BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
1/13/15 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
4/27/17 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL -----
06/30/2022 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
12/08/2022 <0.34 <0.24 <0.30 <1.05 <0.42 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
07/17/2023 <0.079 0.33J <0.081 <234 <0.053 0.11J <0.11 <0.072 <0.066 <0.11 <0.10 <0.031 <0.071 <7.4 <0.12 <4.1 <0.085 <0.17 <0.069
12/21/09 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
4/12/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
11/6/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 26.3 BDL -2.6 BDL BDL BDL BDL BDL ------
11/15/16 BDL BDL BDL BDL 7.88 BDL -1.01 BDL BDL BDL BDL BDL ------
4/27/17 BDL BDL BDL BDL 32.2 BDL -3.28 BDL BDL BDL BDL BDL ------
MW-5
MW-7
MW-6
Page 3 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform12/16/09 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
4/12/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
11/8/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
12/17/09 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
4/12/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
11/8/12 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 6.07 BDL -BDL BDL BDL BDL BDL BDL ------
11/15/16 <1 <5 <1 <2 <1 <5 -<1 <5 <5 <5 <1 <5 ------
4/27/17 BDL BDL BDL BDL BDL BDL -BDL BDL BDL BDL BDL BDL ------
11/7/12 BDL BDL BDL BDL 29,000 BDL -360 BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL 43,000 BDL -560 BDL BDL BDL BDL BDL ------
1/6/15 BDL 1000 BDL 1100 29,000 BDL -330 BDL BDL BDL 320 BDL ------
3/22/16 BDL BDL BDL BDL 34,600 BDL -303 BDL BDL BDL BDL BDL ------
11/15/16 <20 <100 <20 <40 33,700 <100 -242 <100 <100 <100 <20 <100 ------
4/27/17 BDL BDL BDL BDL 19,800 BDL -207 BDL BDL BDL BDL BDL ------
4/17/18 BDL BDL BDL BDL 23,500 BDL -240 BDL BDL BDL BDL BDL ------
10/31/18 BDL BDL BDL BDL 23,000 BDL -250 BDL BDL BDL BDL BDL ------
5/3/19 BDL BDL BDL BDL 52,000 BDL -380 BDL BDL BDL BDL BDL ------
12/4/19 BDL BDL BDL BDL 32,000 BDL -270 BDL BDL BDL BDL BDL ------
6/2/20 BDL BDL BDL BDL 27,300 BDL -220 J BDL BDL BDL BDL BDL ------
1/7/21 <24.0 <22.8 <24.0 86.5 J 9,630 286 <26.3 105 <35.3 <23.8 <24.1 198 <22.7 <4050 <296 1,780 J ---
06/30/2022 <34.5 <48.5 <30.4 <33.8 15,300 <64.5 <32.2 132 <49.0 <33.3 <34.0 <49.5 <33.2 <3640 <925 11,000 <40.0 --
12/08/2022 <17.2 20.0J <15.2 <52.3 7,830 <32.2 <16.1 83.6 <24.5 <16.6 <17.0 <24.8 <16.6 <1820 <462 5,970 <20.0 --
07/17/2023 <7.9 67.3 47.9J 208.4 9,480 <10.1 <10.6 92.9 <6.6 <10.6 <10.5 52.7 <7.1 <744 176J 8,210 <8.5 <17.3 <6.9
MW-10
MW-8
MW-9
Page 4 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform11/8/12 3 BDL BDL BDL 400 BDL -16 BDL BDL BDL BDL BDL ------
9/19/13 1 BDL BDL BDL 200 BDL -7 BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL 940 BDL 1,200 BDL -47 BDL BDL BDL BDL BDL ------
3/22/16 -------------------
11/15/16 2.04 <5 <1 <2 2,050 <5 -66.3 <5 <5 <5 <1 <5 ------
06/30/2022 <34.5 <48.5 <30.4 <33.8 12,000 <64.5 <32.2 257 <49.0 <33.3 <34.0 <49.5 <33.2 <3640 <925 6,740 <40.0 --
12/08/2022 <43.1 <29.9 <38.0 <130.8 20,100 <80.6 <40.2 316 <61.2 <41.6 <42.5 <61.9 <41.5 <4550 <1160 15,900 <50.0 --
07/17/2023 <9.8 <11.2 <10.2 <47.1 22,800 <12.6 <13.2 405 <8.3 <13.2 <13.1 40.3J 12.5J 4290J 464J 14,000 <10.6 <21.6 <8.6
3/22/16 2,940 8,800 1,260 10,600 2,330 BDL -BDL BDL BDL BDL 3,430 BDL ------
11/15/16 1,620 8,820 1,860 12,520 2,400 <1250 -<250 <1250 <1250 <1250 3,540 <1250 ------
4/27/17 520 2,850 1,300 8,840 248 BDL -9.64 BDL BDL BDL 2,900 BDL ------
06/30/2022 1,810 92.5 2,370 4,500 2,640 688 <6.4 83.1 <9.8 118 313 3,050 494 4,140 <185 5,510 <8.0 --
07/17/2023 1,490 799 2,210 9,420 2,840 733 <4.2 70.5 <2.7 136 414 3,520 761 3240J 47.3J 3,810 18.2J 21.3 <2.8
3/22/16 1,210 18,500 2,380 15,170 <100 BDL -26 BDL BDL BDL 2,290 BDL ------
11/15/16 201 141 423 873 <25 <125 -<25 <125 <125 <125 598 <125 ------
4/27/17 119 1.05 145 28 49 BDL -9.64 BDL BDL BDL 107 BDL ------
06/30/2022 0.37J <0.48 <0.30 <0.34 0.58 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 2.3 --
12/08/2022 <0.34 <0.24 <0.30 <1.05 1.0 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 0.95 --
07/17/2023 0.15J 0.32J 0.10J <0.56J 0.39J 0.34J <0.11 <0.072 <0.066 <0.11 <0.10 0.64 0.092J <7.4 <0.12 5.0J 0.65 <0.17 4.6
1/19/15 BDL BDL BDL BDL 46,000 BDL -940 BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 22,400 BDL -312 BDL BDL BDL BDL BDL ------
11/15/2016 <20 <100 <20 <40 33,800 <100 -374 <100 <100 <100 <20 <100 ------
4/27/2017 BDL BDL BDL BDL 17,100 BDL -291 BDL BDL BDL 0.428 BDL ------
4/17/2018 BDL BDL BDL BDL 17,000 BDL -243 BDL BDL BDL BDL BDL ------
10/31/2018 BDL BDL BDL BDL 16,000 BDL -240 BDL BDL BDL BDL BDL ------
5/3/2019 BDL BDL BDL BDL 18,000 BDL -240 BDL BDL BDL BDL BDL ------
12/4/2019 BDL BDL BDL BDL 8,600 BDL -130 BDL BDL BDL BDL BDL ------
6/2/2020 4.92 J BDL BDL BDL 3,980 BDL -66 BDL BDL BDL BDL BDL ------
1/7/21 <6.0 <5.7 <6.0 <12.5 4,620 <16.5 <6.6 69.2 <8.8 <6.0 <6.0 <4.8 <5.7 <1010 89.1 J <440 ---
06/30/2022 <8.6 <12.1 <7.6 <8.4 2,310 <16.1 <8.0 36.1 <12.2 <8.3 <8.5 <12.4 <8.3 <910 <231 1,360 <10.0 --
12/08/2022 <1.7 <1.2 <1.5 <5.2 909 <3.2 <1.6 13.2 <2.4 <1.7 <1.7 <2.5 <1.7 <182 <46.2 640 <2.0 --
07/17/2023 <1.6 <1.8 <1.6 <4.8 2,710 7.6J <2.1 39.2 <1.3 <2.1 <2.1 11.4 <1.4 <149 52.7J 1720 <1.7 <3.5 <1.4
MW-11
MW-12
MW-13
MW-14
Page 5 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform1/20/15 70 17 BDL 23 12,000 BDL -BDL BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 1,960 BDL -65 BDL BDL BDL BDL BDL ------
11/15/16 <10 <50 <10 <20 11,000 <50 -155 <50 <50 <50 <10 <50 ------
4/27/17 BDL BDL BDL BDL 1,420 BDL -44.2 BDL BDL BDL BDL BDL ------
06/30/2022 <3.4 <4.8 <3.0 <3.4 1,090 <6.4 <3.2 28.6 <4.9 <3.3 <3.4 <5.0 <3.3 <364 <92.5 407J <4.0 --
12/08/2022 <6.9 <4.8 <6.1 <21 2,390 <12.9 <6.4 33.7 <9.8 <6.7 <6.8 10.9 <6.6 <728 <185 1,390 <8.0 --
07/17/2023 <0.16 <0.18 0.60J 2.5 227 0.84J <0.21 4.5 <0.13 <0.21 <0.21 3.3 <0.14 <14.9 4.0J 91.7J <0.17 <0.35 <0.14
3/22/16 2,330 6,450 BDL 7,430 2,020 BDL -BDL BDL BDL BDL 2720 BDL ------
11/15/16 1,800 8,350 2,410 15,890 3,210 <1000 -<200 <1000 <1000 <1000 4,540 <1000 ------
4/27/17 1,840 6,530 2,990 19,210 4,630 BDL -147 BDL BDL BDL 5,140 BDL ------
4/17/18 1,440 5,700 3,360 21,090 -BDL -BDL BDL BDL BDL 5410 BDL ------
10/31/18 1,400 4,400 3,400 21,100 6,700 BDL -190 BDL BDL BDL 7,000 BDL ------
5/3/19 1,500 1,200 2,700 16,900 2,100 1600 -130 75 160 560 6500 1300 ------
12/4/19 1,500 910 3,000 14,000 2,600 890 -120 58 170 520 4700 1000 ------
6/2/20 966 1,330 3,080 17,950 2,370 1,180 -101 J 182 J 218 788 7070 1300 ------
1/7/21 794 640 2,910 13,900 3,040 870 <13.2 112 <17.6 166 <12.0 4,800 <11.4 <2020 <148 3,170 ---
06/30/2022 510 437 2,710 15,200 4,180 894 <16.1 105 <24.5 165 478 4,580 997 <1820 <462 <1340 <20.0 --
12/8/2022
07/17/2023 55.0 83.7 1,260 6,820 3,250 915 <2.6 51.6 <1.7 115 335 3,530 701 <186 50.8J 3,140 <2.1 16.7 4.3J
MW-15
MW-16
LNAPL present
Page 6 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform12/21/09 BDL BDL BDL BDL 5,200 BDL BDL 200 BDL BDL BDL BDL BDL ------
10/19/10 BDL BDL BDL BDL 4,800 BDL BDL 190 BDL BDL BDL BDL BDL ------
4/12/11 BDL BDL BDL BDL 7,900 BDL BDL 210 BDL BDL BDL BDL BDL ------
9/13/11 BDL BDL BDL BDL 13,000 BDL BDL 350 BDL BDL BDL BDL BDL ------
2/2/12 BDL BDL BDL BDL 20,000 BDL BDL 430 BDL BDL BDL BDL BDL ------
11/7/12 BDL BDL BDL BDL 25,000 BDL BDL 850 BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL 31,000 BDL BDL 550 BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL 820 BDL BDL 19 BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 24,700 BDL BDL 357 BDL BDL BDL BDL BDL ------
11/15/16 <20 <100 <20 <40 39,500 <100 <20 420 <20 <20 <20 <20 <20 ------
4/27/17 BDL BDL BDL BDL 7.22 BDL BDL BDL BDL BDL BDL BDL BDL ------
4/17/18 BDL BDL BDL BDL 364 BDL BDL 7.49 BDL BDL BDL BDL BDL ------
10/31/18 BDL BDL BDL BDL 1,400 BDL BDL 29.0 BDL BDL BDL BDL BDL ------
5/3/19 BDL BDL BDL BDL 7,500 14 BDL 120.0 BDL BDL BDL 6 BDL ------
12/4/19 BDL BDL BDL BDL 8,600 BDL BDL 73.0 BDL BDL BDL BDL BDL ------
6/2/20 BDL BDL BDL 4.78 J BDL BDL BDL BDL BDL BDL BDL 3.52 J BDL ------
1/7/21 <3.0 <2.8 <3.0 <6.2 1,680 8.5 J <3.3 27.2 <4.4 <3.0 <3.0 <2.4 <2.8 <506 <37.0 835 ---
06/30/2022 <43.1 <60.6 <38.0 <42.2 17,400 <80.6 <40.2 241 <61.2 <41.6 <42.5 <61.9 <41.5 <4550 <1160 9,390 <50.0 --
12/08/2022 <43.1 34.0J <38.0 <130.8 21,200 <80.6 <40.2 285 <61.2 <41.6 <42.5 <61.9 <41.5 <4550 <1160 12,300 <50.0 --
07/17/2023 <9.8 <11.2 <10.2 <29.7 13,900 <12.6 <13.2 181 <8.3 <13.2 <13.1 64.8 <8.9 <930 280J 7,460 <10.6 <21.6 949
11/8/12 BDL BDL BDL BDL 37 BDL BDL 1.2 BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL 28 BDL BDL BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL 74 BDL BDL 2.5 BDL BDL BDL BDL BDL ------
3/22/16 BDL BDL BDL BDL 188 BDL BDL 1.56 BDL BDL BDL BDL BDL ------
11/15/16 <2 <10 <2 <4 169 <10 <2 6.15 BDL <2 <2 <2 <2 ------
4/27/17 BDL BDL BDL BDL BDL BDL BDL 1.47 BDL BDL BDL BDL BDL ------
4/17/18 BDL BDL BDL BDL 27.1 BDL BDL 10.2 BDL BDL BDL BDL BDL ------
10/31/18 BDL BDL BDL BDL 8.4 BDL BDL 5.9 BDL BDL BDL BDL BDL ------
5/3/19 BDL BDL BDL BDL 100 BDL BDL 9 BDL BDL BDL BDL BDL ------
12/4/19 BDL BDL BDL BDL BDL BDL BDL 1.6 BDL BDL BDL BDL BDL ------
6/2/20 BDL BDL BDL BDL 0.104 J BDL BDL 2.55 BDL BDL BDL BDL BDL ------
1/7/21 <0.96 <0.91 <0.96 <2.0 362 12.7 <1.1 12.4 <1.4 <0.95 <0.96 <0.77 <0.91 <162 <11.8 219 ---
06/30/2022 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.32 2.2 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
12/08/2022 <0.34 <0.24 <0.30 <1.05 35.6 <0.64 <0.32 9.7 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
07/17/2023 <0.079 <0.090 <0.081 <234 4.4 <0.10 <0.11 13.0 <0.066 <0.11 <0.10 <0.031 <0.071 <7.4 <0.12 <4.1 <0.085 <0.17 <0.069
DW-1
DW-2
Page 7 of 8
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalene1,2-DichloroethaneDiisopropyl ethern-ButylbenzeneIsopropylbenzene (Cumene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl Alcoholsec-butylbenzene1 600 600 500 20 6 0.4 70 70 70 70 400 400 40 128 10 70 0.005 70
5,000 260,000 80,000 50,000 20,000 6,000 400 70,000 6,900 26,100 26,100 28,500 24,100 40,000 128,000 10,000 8,500 N/A 70,000
NCAC 2L
GCLs
Table 7: Historical Groundwater Analytical Data
Circle K 2723940
10409 Mallard Creek Road
Charlotte, Mecklenburg County, North Carolina
Incident Number: 36286 & 40437
1,2,3-TrichloropropaneChloroform11/8/12 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
3/22/16 -------------------
4/17/18 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
10/31/18 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
5/3/19 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
12/4/19 BDL BDL BDL BDL BDL 1.8 BDL 1.6 BDL BDL BDL BDL BDL ------
6/2/20 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
1/7/21 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 <0.26 <0.33 <0.35 <0.24 <0.24 <0.19 <0.23 <40.5 <3.0 <17.6 ---
6/30/2022 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
12/08/2022 <0.34 <0.24 <0.30 <1.05 <0.42 <0.64 <0.32 <0.31 <0.49 <0.33 <0.34 <0.50 <0.33 <36.4 <9.2 <26.8 <0.40 --
07/17/2023 <0.079 <0.090 <0.081 <234 0.087J <0.10 <0.11 <0.072 <0.066 <0.11 <0.10 <0.031 <0.071 <7.4 <0.12 <4.1 <0.085 <0.17 <0.069
11/8/12 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
9/19/13 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
1/6/15 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL ------
6/2/20 <0.0941 <0.044 <0.137 <0.430 <0.101 <1.00 -<0.105 <0.157 <0.105 <0.0993 <0.322 <0.104 ------
1/7/21 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 <0.26 <0.33 <0.35 <0.24 <0.24 <0.19 <0.23 <40.5 <3.0 <17.6 ---
All results reported in micrograms per liter (ug/L)
- = Result not reported duing previous assessment. Likely not detected.
BDL = Below detection levels
Results in BOLD exceed 2L Standards
Results in BOLD and higlighted exceed GCL
LNAPL - Light Non-aqueous Phase Liquid
WSW-1
DW-4
DW-3
Page 8 of 8

FIGURES
[phone]
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILE LEGEND
MW-9MW-8MW-7MW-5MW-3MW-4MW-6MW-2MW-11MW-13MW-14MW-15MW-16MW-1AMW-12MW-10DW-4DW-3DW-1DW-2PROSPERITY CHURCH ROADMALLARD CREEK
ROADCVSPHARMACYFOOD LIONSHOPPING CENTERBANK OFAMERICABOJANGLES(704) 529-3200
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILE LEGENDType II Monitoring Well LocationProperty LineType III Monitoring Well Location
1,500' RADIUS1,000' RADIUS500' RADIUSSITEWSW-1WSW-2(704) 529-3200
PROJECT NO.
Charlotte, North Carolina 28273
NOTES:
DATE
TITLE
SCALEREV. BYPREP. BYCAD FILE LEGEND
PROSPERITY CHURCH ROADMALLARD CREEK
ROADSITEBUILDINGCARWASHUSTAREABANK OFAMERICABOJANGLESFOOD LIONSHOPPINGCENTERCVSPHARMARCYMW-7MW-3MW-16MW-12MW-1AMW-14MW-15MW-4MW-10MW-13MW-11MW-2MW-6MW-5DW-2DW-1DW-3DW-4MW-8MW-9SCALE: 1" = 50'01030204050NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEDW-1TYPE III MONITORING WELLWell Identification91.0GROUNDWATER ELEVATION CONTOUR(DASHED WHERE INFERRED) (ft)MW-189.20TYPE II MONITORING WELLWell IdentificationRelative Groundwater Elevation (ft)NM*87.5891.1186.50*85.6786.8186.2986.70*80.9789.2089.6786.8687.1888.56NMNMNMNMNM88.049
1
.
0
89
.
0
87
.089
.0
0
87
.
0
0
87.
0GROUNDWATER FLOW DIRECTIONFigure:Drawing File:
Project Number:
Ckd. By:
Drn. By:
App'd By:
Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\PANTRY 3940\PAN3940018-POT.DWG, FIG4
GROUNDWATER ELEVATION CONTOUR MAP08/02/2023SEE LOWER LEFTCIRCLE K #3940
10409 MALLARD CREEK ROAD
CHARLOTTE, NORTH CAROLINA
PAN3940018AS SHOWNDH
NF4NOTES:
1.Features shown are not an authoritative location, nor are they presented
to a stated accuracy.
2.NM = not measured.
3.* = groundwater elevations not used to evaluate groundwater flow.
COORDINATE SYSTEM:
NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET
PROSPERITY CHURCH ROADMALLARD CREEK
ROADSITEBUILDINGCARWASHUSTAREABANK OFAMERICABOJANGLESFOOD LIONSHOPPINGCENTERCVSPHARMARCYMW-7MW-3MW-16MW-12MW-1AMW-14MW-15MW-4MW-10MW-13MW-11MW-2MW-6MW-5DW-2DW-1DW-3DW-4MW-8MW-9SCALE: 1" = 50'01030204050NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-1TYPE II MONITORING WELLWell IdentificationDW-1TYPE III MONITORING WELLWell IdentificationNSNSNSNSNSNSFigure:Drawing File:
Project Number:
Ckd. By:
Drn. By:
App'd By:
Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\PANTRY 3940\PAN3940018-GW.DWG, FIG5
CONTAMINANTS OF CONCERN MAP08/01/2023SEE LOWER LEFTCIRCLE K #3940
10409 MALLARD CREEK ROAD
CHARLOTTE, NORTH CAROLINA
PAN3940018AS SHOWNDH
NF5NOTES:
1.Features shown are not an authoritative location, nor are they presented
to a stated accuracy.
2.NS = not sampled.
COORDINATE SYSTEM:
NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET

APPENDIX A
MMPE REPORT

APPENDIX B
LABORATORY ANALYTICAL REPORT
#=CL#
July 25, 2023
LIMS USE: FR - NOELLE FRANCE
LIMS OBJECT ID: 92677890
92677890
Project:
Pace Project No.:
RE:
Noelle France
ATC Group Services LLC- South Charlotte
7606 Whitehall Exe Center Dr
Suite 800
Charlotte, NC 28273
CK 3940
Dear Noelle France:
Enclosed are the analytical results for sample(s) received by the laboratory on July 18, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92677890
CK 3940
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 49
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92677890
CK 3940
Lab ID Sample ID Matrix Date Collected Date Received
92677890001 MW-1A Water 07/17/23 13:40 07/18/23 07:15
92677890002 MW-3 Water 07/17/23 11:30 07/18/23 07:15
92677890003 MW-4 Water 07/17/23 11:50 07/18/23 07:15
92677890004 MW-6 Water 07/17/23 15:10 07/18/23 07:15
92677890005 MW-10 Water 07/17/23 12:55 07/18/23 07:15
92677890006 MW-11 Water 07/17/23 14:35 07/18/23 07:15
92677890007 MW-12 Water 07/17/23 13:10 07/18/23 07:15
92677890008 MW-13 Water 07/17/23 14:05 07/18/23 07:15
92677890009 MW-14 Water 07/17/23 13:45 07/18/23 07:15
92677890010 MW-15 Water 07/17/23 12:45 07/18/23 07:15
92677890011 MW-16 Water 07/17/23 12:25 07/18/23 07:15
92677890012 DW-1 Water 07/17/23 13:10 07/18/23 07:15
92677890013 DW-2 Water 07/17/23 11:25 07/18/23 07:15
92677890014 DW-3 Water 07/17/23 14:00 07/18/23 07:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92677890
CK 3940
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92677890001 MW-1A SM 6200B 69 PASI-CTMH
92677890002 MW-3 SM 6200B 69 PASI-CJJK
92677890003 MW-4 SM 6200B 69 PASI-CTMH
92677890004 MW-6 SM 6200B 69 PASI-CJJK
92677890005 MW-10 SM 6200B 69 PASI-CTMH
92677890006 MW-11 SM 6200B 69 PASI-CJJK
92677890007 MW-12 SM 6200B 69 PASI-CJJK
92677890008 MW-13 SM 6200B 69 PASI-CJJK
92677890009 MW-14 SM 6200B 69 PASI-CTMH
92677890010 MW-15 SM 6200B 69 PASI-CTMH
92677890011 MW-16 SM 6200B 69 PASI-CTMH
92677890012 DW-1 SM 6200B 69 PASI-CTMH
92677890013 DW-2 SM 6200B 69 PASI-CJJK
92677890014 DW-3 SM 6200B 69 PASI-CJJK
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-1A Lab ID:92677890001 Collected:07/17/23 13:40 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <186 ug/L 07/20/23 17:06 75-85-4250018625
tert-Amylmethyl ether <3.1 ug/L 07/20/23 17:06 994-05-82503.1 25
Benzene 86.8 ug/L 07/20/23 17:06 71-43-212.5 2.0 25
Bromobenzene <3.4 ug/L 07/20/23 17:06 108-86-112.5 3.4 25
Bromochloromethane <2.4 ug/L 07/20/23 17:06 74-97-512.5 2.4 25
Bromodichloromethane <4.2 ug/L 07/20/23 17:06 75-27-412.5 4.2 25
Bromoform <4.9 ug/L 07/20/23 17:06 75-25-212.5 4.9 25
Bromomethane <5.6 ug/L 07/20/23 17:06 74-83-91255.6 25
tert-Butyl Alcohol 309J ug/L 07/20/23 17:06 75-65-0125010225
n-Butylbenzene <1.7 ug/L 07/20/23 17:06 104-51-812.5 1.7 25
sec-Butylbenzene <2.1 ug/L 07/20/23 17:06 135-98-812.5 2.1 25
tert-Butylbenzene <2.1 ug/L 07/20/23 17:06 98-06-612.5 2.1 25
tert-Butyl Formate <7.5 ug/L 07/20/23 17:06 762-75-412507.5 25
Carbon tetrachloride <4.2 ug/L 07/20/23 17:06 56-23-512.5 4.2 25
Chlorobenzene <2.1 ug/L 07/20/23 17:06 108-90-712.5 2.1 25
Chloroethane <4.3 ug/L 07/20/23 17:06 75-00-325.0 4.3 25
Chloroform <1.7 ug/L 07/20/23 17:06 67-66-312.5 1.7 25
Chloromethane <4.4 ug/L 07/20/23 17:06 74-87-325.0 4.4 25
2-Chlorotoluene <3.2 ug/L 07/20/23 17:06 95-49-812.5 3.2 25
4-Chlorotoluene <2.4 ug/L 07/20/23 17:06 106-43-412.5 2.4 25
1,2-Dibromo-3-chloropropane <4.5 ug/L 07/20/23 17:06 96-12-825.0 4.5 25
Dibromochloromethane <3.7 ug/L 07/20/23 17:06 124-48-112.5 3.7 25
1,2-Dibromoethane (EDB)<3.7 ug/L 07/20/23 17:06 106-93-412.5 3.7 25
Dibromomethane <4.7 ug/L 07/20/23 17:06 74-95-312.5 4.7 25
1,2-Dichlorobenzene <2.4 ug/L 07/20/23 17:06 95-50-112.5 2.4 25
1,3-Dichlorobenzene <2.4 ug/L 07/20/23 17:06 541-73-112.5 2.4 25
1,4-Dichlorobenzene <2.2 ug/L 07/20/23 17:06 106-46-712.5 2.2 25
Dichlorodifluoromethane <3.1 ug/L 07/20/23 17:06 75-71-812.5 3.1 25
1,1-Dichloroethane <1.4 ug/L 07/20/23 17:06 75-34-312.5 1.4 25
1,2-Dichloroethane <2.6 ug/L 07/20/23 17:06 107-06-212.5 2.6 25
1,1-Dichloroethene <2.0 ug/L 07/20/23 17:06 75-35-412.5 2.0 25
cis-1,2-Dichloroethene <2.8 ug/L 07/20/23 17:06 156-59-212.5 2.8 25
trans-1,2-Dichloroethene <2.5 ug/L 07/20/23 17:06 156-60-512.5 2.5 25
1,2-Dichloropropane <3.4 ug/L 07/20/23 17:06 78-87-512.5 3.4 25
1,3-Dichloropropane <2.1 ug/L 07/20/23 17:06 142-28-912.5 2.1 25
2,2-Dichloropropane <3.0 ug/L 07/20/23 17:06 594-20-712.5 3.0 25
1,1-Dichloropropene <1.6 ug/L 07/20/23 17:06 563-58-612.5 1.6 25
cis-1,3-Dichloropropene <2.2 ug/L 07/20/23 17:06 10061-01-512.5 2.2 25
trans-1,3-Dichloropropene <3.3 ug/L 07/20/23 17:06 10061-02-612.5 3.3 25
Diisopropyl ether 3.3J ug/L 07/20/23 17:06 108-20-312.5 1.8 25
Ethanol <126 ug/L 07/20/23 17:06 64-17-5500012625
Ethylbenzene 755 ug/L 07/20/23 17:06 100-41-412.5 2.0 25
Ethyl-tert-butyl ether <2.8 ug/L 07/20/23 17:06 637-92-32502.8 25
Hexachloro-1,3-butadiene <8.8 ug/L 07/20/23 17:06 87-68-350.0 8.8 25
Isopropylbenzene (Cumene)109 ug/L 07/20/23 17:06 98-82-812.5 2.6 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-1A Lab ID:92677890001 Collected:07/17/23 13:40 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <47.2 ug/L 07/20/23 17:06 75-09-250.0 47.2 25
Methyl-tert-butyl ether 66.4 ug/L 07/20/23 17:06 1634-04-412.5 1.3 25
Naphthalene 435 ug/L 07/20/23 17:06 91-20-350.0 2.5 25
n-Propylbenzene 371 ug/L 07/20/23 17:06 103-65-112.5 2.6 25
Styrene <3.4 ug/L 07/20/23 17:06 100-42-512.5 3.4 25
1,1,1,2-Tetrachloroethane <2.3 ug/L 07/20/23 17:06 630-20-612.5 2.3 25
1,1,2,2-Tetrachloroethane <1.8 ug/L 07/20/23 17:06 79-34-512.5 1.8 25
Tetrachloroethene <2.1 ug/L 07/20/23 17:06 127-18-412.5 2.1 25
Toluene 21.3 ug/L 07/20/23 17:06 108-88-312.5 2.2 25
1,2,3-Trichlorobenzene <3.0 ug/L 07/20/23 17:06 87-61-650.0 3.0 25
1,2,4-Trichlorobenzene <3.9 ug/L 07/20/23 17:06 120-82-150.0 3.9 25
1,1,1-Trichloroethane <2.7 ug/L 07/20/23 17:06 71-55-612.5 2.7 25
1,1,2-Trichloroethane <2.4 ug/L 07/20/23 17:06 79-00-512.5 2.4 25
Trichloroethene <4.3 ug/L 07/20/23 17:06 79-01-612.5 4.3 25
Trichlorofluoromethane <3.6 ug/L 07/20/23 17:06 75-69-425.0 3.6 25
1,2,3-Trichloropropane <4.3 ug/L 07/20/23 17:06 96-18-412.5 4.3 25
1,2,4-Trimethylbenzene 3330 ug/L 07/20/23 17:06 95-63-612.5 0.77 25
1,3,5-Trimethylbenzene 882 ug/L 07/20/23 17:06 108-67-812.5 1.8 25
Vinyl chloride <3.7 ug/L 07/20/23 17:06 75-01-425.0 3.7 25
m&p-Xylene 2700 ug/L 07/20/23 17:06 179601-23-125.0 2.3 25
o-Xylene 10.9J ug/L 07/20/23 17:06 95-47-612.5 3.6 25
Surrogates
1,2-Dichloroethane-d4 (S)103 %07/20/23 17:06 17060-07-070-130 25
4-Bromofluorobenzene (S)95 %07/20/23 17:06 460-00-470-130 25
Toluene-d8 (S)104 %07/20/23 17:06 2037-26-570-130 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-3 Lab ID:92677890002 Collected:07/17/23 11:30 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 07/19/23 15:17 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 07/19/23 15:17 994-05-810.0 0.12 1
Benzene <0.079 ug/L 07/19/23 15:17 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 07/19/23 15:17 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 07/19/23 15:17 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 07/19/23 15:17 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 07/19/23 15:17 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 07/19/23 15:17 74-83-95.0 0.22 1
tert-Butyl Alcohol <4.1 ug/L 07/19/23 15:17 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 07/19/23 15:17 104-51-80.50 0.066 1
sec-Butylbenzene <0.085 ug/L 07/19/23 15:17 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 07/19/23 15:17 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 07/19/23 15:17 762-75-4 M150.0 0.30 1
Carbon tetrachloride <0.17 ug/L 07/19/23 15:17 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 07/19/23 15:17 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 07/19/23 15:17 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 07/19/23 15:17 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 07/19/23 15:17 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 07/19/23 15:17 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 07/19/23 15:17 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 07/19/23 15:17 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 07/19/23 15:17 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 07/19/23 15:17 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 07/19/23 15:17 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 07/19/23 15:17 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 07/19/23 15:17 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 07/19/23 15:17 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 07/19/23 15:17 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 07/19/23 15:17 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 07/19/23 15:17 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 07/19/23 15:17 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 07/19/23 15:17 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 07/19/23 15:17 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 07/19/23 15:17 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 07/19/23 15:17 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 07/19/23 15:17 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 07/19/23 15:17 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 07/19/23 15:17 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 07/19/23 15:17 10061-02-60.50 0.13 1
Diisopropyl ether <0.072 ug/L 07/19/23 15:17 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 07/19/23 15:17 64-17-52005.0 1
Ethylbenzene <0.081 ug/L 07/19/23 15:17 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 07/19/23 15:17 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 07/19/23 15:17 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 07/19/23 15:17 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-3 Lab ID:92677890002 Collected:07/17/23 11:30 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 07/19/23 15:17 75-09-22.0 1.9 1
Methyl-tert-butyl ether 0.47J ug/L 07/19/23 15:17 1634-04-40.50 0.053 1
Naphthalene <0.10 ug/L 07/19/23 15:17 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 07/19/23 15:17 103-65-10.50 0.10 1
Styrene <0.14 ug/L 07/19/23 15:17 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 07/19/23 15:17 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 07/19/23 15:17 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 07/19/23 15:17 127-18-40.50 0.086 1
Toluene <0.090 ug/L 07/19/23 15:17 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 07/19/23 15:17 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 07/19/23 15:17 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 07/19/23 15:17 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 07/19/23 15:17 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 07/19/23 15:17 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 07/19/23 15:17 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 07/19/23 15:17 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene <0.031 ug/L 07/19/23 15:17 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 07/19/23 15:17 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 07/19/23 15:17 75-01-41.0 0.15 1
m&p-Xylene <0.094 ug/L 07/19/23 15:17 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 07/19/23 15:17 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %07/19/23 15:17 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %07/19/23 15:17 460-00-470-130 1
Toluene-d8 (S)99 %07/19/23 15:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-4 Lab ID:92677890003 Collected:07/17/23 11:50 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <37.2 ug/L 07/20/23 17:42 75-85-450037.2 5
tert-Amylmethyl ether <0.62 ug/L 07/20/23 17:42 994-05-850.0 0.62 5
Benzene <0.39 ug/L 07/20/23 17:42 71-43-22.5 0.39 5
Bromobenzene <0.68 ug/L 07/20/23 17:42 108-86-12.5 0.68 5
Bromochloromethane <0.47 ug/L 07/20/23 17:42 74-97-52.5 0.47 5
Bromodichloromethane <0.85 ug/L 07/20/23 17:42 75-27-42.5 0.85 5
Bromoform <0.98 ug/L 07/20/23 17:42 75-25-22.5 0.98 5
Bromomethane <1.1 ug/L 07/20/23 17:42 74-83-925.0 1.1 5
tert-Butyl Alcohol 294 ug/L 07/20/23 17:42 75-65-025020.4 5
n-Butylbenzene <0.33 ug/L 07/20/23 17:42 104-51-82.5 0.33 5
sec-Butylbenzene <0.43 ug/L 07/20/23 17:42 135-98-82.5 0.43 5
tert-Butylbenzene <0.43 ug/L 07/20/23 17:42 98-06-62.5 0.43 5
tert-Butyl Formate <1.5 ug/L 07/20/23 17:42 762-75-42501.5 5
Carbon tetrachloride <0.84 ug/L 07/20/23 17:42 56-23-52.5 0.84 5
Chlorobenzene <0.42 ug/L 07/20/23 17:42 108-90-72.5 0.42 5
Chloroethane <0.86 ug/L 07/20/23 17:42 75-00-35.0 0.86 5
Chloroform <0.35 ug/L 07/20/23 17:42 67-66-32.5 0.35 5
Chloromethane <0.88 ug/L 07/20/23 17:42 74-87-35.0 0.88 5
2-Chlorotoluene <0.64 ug/L 07/20/23 17:42 95-49-82.5 0.64 5
4-Chlorotoluene <0.48 ug/L 07/20/23 17:42 106-43-42.5 0.48 5
1,2-Dibromo-3-chloropropane <0.90 ug/L 07/20/23 17:42 96-12-85.0 0.90 5
Dibromochloromethane <0.74 ug/L 07/20/23 17:42 124-48-12.5 0.74 5
1,2-Dibromoethane (EDB)<0.74 ug/L 07/20/23 17:42 106-93-42.5 0.74 5
Dibromomethane <0.94 ug/L 07/20/23 17:42 74-95-32.5 0.94 5
1,2-Dichlorobenzene <0.47 ug/L 07/20/23 17:42 95-50-12.5 0.47 5
1,3-Dichlorobenzene <0.49 ug/L 07/20/23 17:42 541-73-12.5 0.49 5
1,4-Dichlorobenzene <0.45 ug/L 07/20/23 17:42 106-46-72.5 0.45 5
Dichlorodifluoromethane <0.62 ug/L 07/20/23 17:42 75-71-82.5 0.62 5
1,1-Dichloroethane <0.28 ug/L 07/20/23 17:42 75-34-32.5 0.28 5
1,2-Dichloroethane <0.53 ug/L 07/20/23 17:42 107-06-22.5 0.53 5
1,1-Dichloroethene <0.39 ug/L 07/20/23 17:42 75-35-42.5 0.39 5
cis-1,2-Dichloroethene <0.56 ug/L 07/20/23 17:42 156-59-22.5 0.56 5
trans-1,2-Dichloroethene <0.50 ug/L 07/20/23 17:42 156-60-52.5 0.50 5
1,2-Dichloropropane <0.68 ug/L 07/20/23 17:42 78-87-52.5 0.68 5
1,3-Dichloropropane <0.43 ug/L 07/20/23 17:42 142-28-92.5 0.43 5
2,2-Dichloropropane <0.61 ug/L 07/20/23 17:42 594-20-72.5 0.61 5
1,1-Dichloropropene <0.33 ug/L 07/20/23 17:42 563-58-62.5 0.33 5
cis-1,3-Dichloropropene <0.45 ug/L 07/20/23 17:42 10061-01-52.5 0.45 5
trans-1,3-Dichloropropene <0.66 ug/L 07/20/23 17:42 10061-02-62.5 0.66 5
Diisopropyl ether 12.2 ug/L 07/20/23 17:42 108-20-32.5 0.36 5
Ethanol <25.2 ug/L 07/20/23 17:42 64-17-5100025.2 5
Ethylbenzene <0.41 ug/L 07/20/23 17:42 100-41-42.5 0.41 5
Ethyl-tert-butyl ether <0.56 ug/L 07/20/23 17:42 637-92-350.0 0.56 5
Hexachloro-1,3-butadiene <1.8 ug/L 07/20/23 17:42 87-68-310.0 1.8 5
Isopropylbenzene (Cumene)<0.53 ug/L 07/20/23 17:42 98-82-82.5 0.53 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-4 Lab ID:92677890003 Collected:07/17/23 11:50 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <9.4 ug/L 07/20/23 17:42 75-09-210.0 9.4 5
Methyl-tert-butyl ether 850 ug/L 07/20/23 17:42 1634-04-42.5 0.27 5
Naphthalene <0.50 ug/L 07/20/23 17:42 91-20-310.0 0.50 5
n-Propylbenzene <0.52 ug/L 07/20/23 17:42 103-65-12.5 0.52 5
Styrene <0.68 ug/L 07/20/23 17:42 100-42-52.5 0.68 5
1,1,1,2-Tetrachloroethane <0.46 ug/L 07/20/23 17:42 630-20-62.5 0.46 5
1,1,2,2-Tetrachloroethane <0.37 ug/L 07/20/23 17:42 79-34-52.5 0.37 5
Tetrachloroethene <0.43 ug/L 07/20/23 17:42 127-18-42.5 0.43 5
Toluene <0.45 ug/L 07/20/23 17:42 108-88-32.5 0.45 5
1,2,3-Trichlorobenzene <0.60 ug/L 07/20/23 17:42 87-61-610.0 0.60 5
1,2,4-Trichlorobenzene <0.78 ug/L 07/20/23 17:42 120-82-110.0 0.78 5
1,1,1-Trichloroethane <0.54 ug/L 07/20/23 17:42 71-55-62.5 0.54 5
1,1,2-Trichloroethane <0.48 ug/L 07/20/23 17:42 79-00-52.5 0.48 5
Trichloroethene <0.86 ug/L 07/20/23 17:42 79-01-62.5 0.86 5
Trichlorofluoromethane <0.72 ug/L 07/20/23 17:42 75-69-45.0 0.72 5
1,2,3-Trichloropropane <0.86 ug/L 07/20/23 17:42 96-18-42.5 0.86 5
1,2,4-Trimethylbenzene 2.5 ug/L 07/20/23 17:42 95-63-62.5 0.15 5
1,3,5-Trimethylbenzene <0.36 ug/L 07/20/23 17:42 108-67-82.5 0.36 5
Vinyl chloride <0.74 ug/L 07/20/23 17:42 75-01-45.0 0.74 5
m&p-Xylene <0.47 ug/L 07/20/23 17:42 179601-23-15.0 0.47 5
o-Xylene <0.72 ug/L 07/20/23 17:42 95-47-62.5 0.72 5
Surrogates
1,2-Dichloroethane-d4 (S)104 %07/20/23 17:42 17060-07-070-130 5
4-Bromofluorobenzene (S)101 %07/20/23 17:42 460-00-470-130 5
Toluene-d8 (S)100 %07/20/23 17:42 2037-26-570-130 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-6 Lab ID:92677890004 Collected:07/17/23 15:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 07/19/23 16:30 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 07/19/23 16:30 994-05-810.0 0.12 1
Benzene <0.079 ug/L 07/19/23 16:30 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 07/19/23 16:30 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 07/19/23 16:30 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 07/19/23 16:30 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 07/19/23 16:30 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 07/19/23 16:30 74-83-95.0 0.22 1
tert-Butyl Alcohol <4.1 ug/L 07/19/23 16:30 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 07/19/23 16:30 104-51-80.50 0.066 1
sec-Butylbenzene <0.085 ug/L 07/19/23 16:30 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 07/19/23 16:30 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 07/19/23 16:30 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 07/19/23 16:30 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 07/19/23 16:30 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 07/19/23 16:30 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 07/19/23 16:30 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 07/19/23 16:30 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 07/19/23 16:30 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 07/19/23 16:30 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 07/19/23 16:30 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 07/19/23 16:30 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 07/19/23 16:30 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 07/19/23 16:30 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 07/19/23 16:30 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 07/19/23 16:30 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 07/19/23 16:30 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 07/19/23 16:30 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 07/19/23 16:30 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 07/19/23 16:30 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 07/19/23 16:30 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 07/19/23 16:30 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 07/19/23 16:30 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 07/19/23 16:30 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 07/19/23 16:30 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 07/19/23 16:30 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 07/19/23 16:30 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 07/19/23 16:30 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 07/19/23 16:30 10061-02-60.50 0.13 1
Diisopropyl ether <0.072 ug/L 07/19/23 16:30 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 07/19/23 16:30 64-17-52005.0 1
Ethylbenzene <0.081 ug/L 07/19/23 16:30 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 07/19/23 16:30 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 07/19/23 16:30 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 07/19/23 16:30 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-6 Lab ID:92677890004 Collected:07/17/23 15:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 07/19/23 16:30 75-09-22.0 1.9 1
Methyl-tert-butyl ether <0.053 ug/L 07/19/23 16:30 1634-04-40.50 0.053 1
Naphthalene 0.11J ug/L 07/19/23 16:30 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 07/19/23 16:30 103-65-10.50 0.10 1
Styrene <0.14 ug/L 07/19/23 16:30 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 07/19/23 16:30 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 07/19/23 16:30 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 07/19/23 16:30 127-18-40.50 0.086 1
Toluene 0.33J ug/L 07/19/23 16:30 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 07/19/23 16:30 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 07/19/23 16:30 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 07/19/23 16:30 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 07/19/23 16:30 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 07/19/23 16:30 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 07/19/23 16:30 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 07/19/23 16:30 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene <0.031 ug/L 07/19/23 16:30 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 07/19/23 16:30 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 07/19/23 16:30 75-01-41.0 0.15 1
m&p-Xylene <0.094 ug/L 07/19/23 16:30 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 07/19/23 16:30 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %07/19/23 16:30 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %07/19/23 16:30 460-00-470-130 1
Toluene-d8 (S)99 %07/19/23 16:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-10 Lab ID:92677890005 Collected:07/17/23 12:55 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <744 ug/L 07/20/23 18:18 75-85-410000744100
tert-Amylmethyl ether 176J ug/L 07/20/23 18:18 994-05-8100012.4 100
Benzene <7.9 ug/L 07/20/23 18:18 71-43-250.0 7.9 100
Bromobenzene <13.5 ug/L 07/20/23 18:18 108-86-150.0 13.5 100
Bromochloromethane <9.4 ug/L 07/20/23 18:18 74-97-550.0 9.4 100
Bromodichloromethane <17.0 ug/L 07/20/23 18:18 75-27-450.0 17.0 100
Bromoform <19.7 ug/L 07/20/23 18:18 75-25-250.0 19.7 100
Bromomethane <22.2 ug/L 07/20/23 18:18 74-83-950022.2 100
tert-Butyl Alcohol 8210 ug/L 07/20/23 18:18 75-65-05000409100
n-Butylbenzene <6.6 ug/L 07/20/23 18:18 104-51-850.0 6.6 100
sec-Butylbenzene <8.5 ug/L 07/20/23 18:18 135-98-850.0 8.5 100
tert-Butylbenzene <8.6 ug/L 07/20/23 18:18 98-06-650.0 8.6 100
tert-Butyl Formate <30.0 ug/L 07/20/23 18:18 762-75-4500030.0 100
Carbon tetrachloride <16.9 ug/L 07/20/23 18:18 56-23-550.0 16.9 100
Chlorobenzene <8.5 ug/L 07/20/23 18:18 108-90-750.0 8.5 100
Chloroethane <17.3 ug/L 07/20/23 18:18 75-00-310017.3 100
Chloroform <6.9 ug/L 07/20/23 18:18 67-66-350.0 6.9 100
Chloromethane <17.5 ug/L 07/20/23 18:18 74-87-310017.5 100
2-Chlorotoluene <12.9 ug/L 07/20/23 18:18 95-49-850.0 12.9 100
4-Chlorotoluene <9.6 ug/L 07/20/23 18:18 106-43-450.0 9.6 100
1,2-Dibromo-3-chloropropane <17.9 ug/L 07/20/23 18:18 96-12-810017.9 100
Dibromochloromethane <14.8 ug/L 07/20/23 18:18 124-48-150.0 14.8 100
1,2-Dibromoethane (EDB)<14.7 ug/L 07/20/23 18:18 106-93-450.0 14.7 100
Dibromomethane <18.7 ug/L 07/20/23 18:18 74-95-350.0 18.7 100
1,2-Dichlorobenzene <9.4 ug/L 07/20/23 18:18 95-50-150.0 9.4 100
1,3-Dichlorobenzene <9.8 ug/L 07/20/23 18:18 541-73-150.0 9.8 100
1,4-Dichlorobenzene <9.0 ug/L 07/20/23 18:18 106-46-750.0 9.0 100
Dichlorodifluoromethane <12.3 ug/L 07/20/23 18:18 75-71-850.0 12.3 100
1,1-Dichloroethane <5.6 ug/L 07/20/23 18:18 75-34-350.0 5.6 100
1,2-Dichloroethane <10.6 ug/L 07/20/23 18:18 107-06-250.0 10.6 100
1,1-Dichloroethene <7.9 ug/L 07/20/23 18:18 75-35-450.0 7.9 100
cis-1,2-Dichloroethene <11.1 ug/L 07/20/23 18:18 156-59-250.0 11.1 100
trans-1,2-Dichloroethene <10.1 ug/L 07/20/23 18:18 156-60-550.0 10.1 100
1,2-Dichloropropane <13.6 ug/L 07/20/23 18:18 78-87-550.0 13.6 100
1,3-Dichloropropane <8.5 ug/L 07/20/23 18:18 142-28-950.0 8.5 100
2,2-Dichloropropane <12.2 ug/L 07/20/23 18:18 594-20-750.0 12.2 100
1,1-Dichloropropene <6.6 ug/L 07/20/23 18:18 563-58-650.0 6.6 100
cis-1,3-Dichloropropene <9.0 ug/L 07/20/23 18:18 10061-01-550.0 9.0 100
trans-1,3-Dichloropropene <13.2 ug/L 07/20/23 18:18 10061-02-650.0 13.2 100
Diisopropyl ether 92.9 ug/L 07/20/23 18:18 108-20-350.0 7.2 100
Ethanol <505 ug/L 07/20/23 18:18 64-17-520000505100
Ethylbenzene 47.9J ug/L 07/20/23 18:18 100-41-450.0 8.1 100
Ethyl-tert-butyl ether <11.2 ug/L 07/20/23 18:18 637-92-3100011.2 100
Hexachloro-1,3-butadiene <35.1 ug/L 07/20/23 18:18 87-68-320035.1 100
Isopropylbenzene (Cumene)<10.6 ug/L 07/20/23 18:18 98-82-850.0 10.6 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-10 Lab ID:92677890005 Collected:07/17/23 12:55 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <189 ug/L 07/20/23 18:18 75-09-2200189100
Methyl-tert-butyl ether 9480 ug/L 07/20/23 18:18 1634-04-450.0 5.3 100
Naphthalene <10.1 ug/L 07/20/23 18:18 91-20-320010.1 100
n-Propylbenzene <10.5 ug/L 07/20/23 18:18 103-65-150.0 10.5 100
Styrene <13.7 ug/L 07/20/23 18:18 100-42-550.0 13.7 100
1,1,1,2-Tetrachloroethane <9.1 ug/L 07/20/23 18:18 630-20-650.0 9.1 100
1,1,2,2-Tetrachloroethane <7.4 ug/L 07/20/23 18:18 79-34-550.0 7.4 100
Tetrachloroethene <8.6 ug/L 07/20/23 18:18 127-18-450.0 8.6 100
Toluene 67.3 ug/L 07/20/23 18:18 108-88-350.0 9.0 100
1,2,3-Trichlorobenzene <12.1 ug/L 07/20/23 18:18 87-61-620012.1 100
1,2,4-Trichlorobenzene <15.6 ug/L 07/20/23 18:18 120-82-120015.6 100
1,1,1-Trichloroethane <10.7 ug/L 07/20/23 18:18 71-55-650.0 10.7 100
1,1,2-Trichloroethane <9.6 ug/L 07/20/23 18:18 79-00-550.0 9.6 100
Trichloroethene <17.1 ug/L 07/20/23 18:18 79-01-650.0 17.1 100
Trichlorofluoromethane <14.4 ug/L 07/20/23 18:18 75-69-410014.4 100
1,2,3-Trichloropropane <17.3 ug/L 07/20/23 18:18 96-18-450.0 17.3 100
1,2,4-Trimethylbenzene 52.7 ug/L 07/20/23 18:18 95-63-650.0 3.1 100
1,3,5-Trimethylbenzene <7.1 ug/L 07/20/23 18:18 108-67-850.0 7.1 100
Vinyl chloride <14.9 ug/L 07/20/23 18:18 75-01-410014.9 100
m&p-Xylene 155 ug/L 07/20/23 18:18 179601-23-11009.4 100
o-Xylene 53.4 ug/L 07/20/23 18:18 95-47-650.0 14.4 100
Surrogates
1,2-Dichloroethane-d4 (S)104 %07/20/23 18:18 17060-07-070-130 100
4-Bromofluorobenzene (S)95 %07/20/23 18:18 460-00-470-130 100
Toluene-d8 (S)104 %07/20/23 18:18 2037-26-570-130 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-11 Lab ID:92677890006 Collected:07/17/23 14:35 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 4290J ug/L 07/19/23 21:02 75-85-412500930125
tert-Amylmethyl ether 464J ug/L 07/19/23 21:02 994-05-8125015.5 125
Benzene <9.8 ug/L 07/19/23 21:02 71-43-262.5 9.8 125
Bromobenzene <16.9 ug/L 07/19/23 21:02 108-86-162.5 16.9 125
Bromochloromethane <11.8 ug/L 07/19/23 21:02 74-97-562.5 11.8 125
Bromodichloromethane <21.2 ug/L 07/19/23 21:02 75-27-462.5 21.2 125
Bromoform <24.6 ug/L 07/19/23 21:02 75-25-262.5 24.6 125
Bromomethane <27.8 ug/L 07/19/23 21:02 74-83-962527.8 125
tert-Butyl Alcohol 14000 ug/L 07/19/23 21:02 75-65-06250511125
n-Butylbenzene <8.3 ug/L 07/19/23 21:02 104-51-862.5 8.3 125
sec-Butylbenzene <10.6 ug/L 07/19/23 21:02 135-98-862.5 10.6 125
tert-Butylbenzene <10.7 ug/L 07/19/23 21:02 98-06-662.5 10.7 125
tert-Butyl Formate <37.5 ug/L 07/19/23 21:02 762-75-4625037.5 125
Carbon tetrachloride <21.1 ug/L 07/19/23 21:02 56-23-562.5 21.1 125
Chlorobenzene <10.6 ug/L 07/19/23 21:02 108-90-762.5 10.6 125
Chloroethane <21.6 ug/L 07/19/23 21:02 75-00-312521.6 125
Chloroform <8.6 ug/L 07/19/23 21:02 67-66-362.5 8.6 125
Chloromethane <21.9 ug/L 07/19/23 21:02 74-87-312521.9 125
2-Chlorotoluene <16.1 ug/L 07/19/23 21:02 95-49-862.5 16.1 125
4-Chlorotoluene <12.0 ug/L 07/19/23 21:02 106-43-462.5 12.0 125
1,2-Dibromo-3-chloropropane <22.4 ug/L 07/19/23 21:02 96-12-812522.4 125
Dibromochloromethane <18.5 ug/L 07/19/23 21:02 124-48-162.5 18.5 125
1,2-Dibromoethane (EDB)<18.4 ug/L 07/19/23 21:02 106-93-462.5 18.4 125
Dibromomethane <23.4 ug/L 07/19/23 21:02 74-95-362.5 23.4 125
1,2-Dichlorobenzene <11.8 ug/L 07/19/23 21:02 95-50-162.5 11.8 125
1,3-Dichlorobenzene <12.2 ug/L 07/19/23 21:02 541-73-162.5 12.2 125
1,4-Dichlorobenzene <11.2 ug/L 07/19/23 21:02 106-46-762.5 11.2 125
Dichlorodifluoromethane <15.4 ug/L 07/19/23 21:02 75-71-862.5 15.4 125
1,1-Dichloroethane <7.0 ug/L 07/19/23 21:02 75-34-362.5 7.0 125
1,2-Dichloroethane <13.2 ug/L 07/19/23 21:02 107-06-262.5 13.2 125
1,1-Dichloroethene <9.8 ug/L 07/19/23 21:02 75-35-462.5 9.8 125
cis-1,2-Dichloroethene <13.9 ug/L 07/19/23 21:02 156-59-262.5 13.9 125
trans-1,2-Dichloroethene <12.6 ug/L 07/19/23 21:02 156-60-562.5 12.6 125
1,2-Dichloropropane <17.0 ug/L 07/19/23 21:02 78-87-562.5 17.0 125
1,3-Dichloropropane <10.7 ug/L 07/19/23 21:02 142-28-962.5 10.7 125
2,2-Dichloropropane <15.2 ug/L 07/19/23 21:02 594-20-762.5 15.2 125
1,1-Dichloropropene <8.2 ug/L 07/19/23 21:02 563-58-662.5 8.2 125
cis-1,3-Dichloropropene <11.2 ug/L 07/19/23 21:02 10061-01-562.5 11.2 125
trans-1,3-Dichloropropene <16.5 ug/L 07/19/23 21:02 10061-02-662.5 16.5 125
Diisopropyl ether 405 ug/L 07/19/23 21:02 108-20-362.5 9.1 125
Ethanol <631 ug/L 07/19/23 21:02 64-17-525000631125
Ethylbenzene <10.2 ug/L 07/19/23 21:02 100-41-462.5 10.2 125
Ethyl-tert-butyl ether <14.0 ug/L 07/19/23 21:02 637-92-3125014.0 125
Hexachloro-1,3-butadiene <43.9 ug/L 07/19/23 21:02 87-68-325043.9 125
Isopropylbenzene (Cumene)<13.2 ug/L 07/19/23 21:02 98-82-862.5 13.2 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-11 Lab ID:92677890006 Collected:07/17/23 14:35 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <236 ug/L 07/19/23 21:02 75-09-2250236125
Methyl-tert-butyl ether 22800 ug/L 07/19/23 21:02 1634-04-462.5 6.7 125
Naphthalene <12.6 ug/L 07/19/23 21:02 91-20-325012.6 125
n-Propylbenzene <13.1 ug/L 07/19/23 21:02 103-65-162.5 13.1 125
Styrene <17.1 ug/L 07/19/23 21:02 100-42-562.5 17.1 125
1,1,1,2-Tetrachloroethane <11.4 ug/L 07/19/23 21:02 630-20-662.5 11.4 125
1,1,2,2-Tetrachloroethane <9.2 ug/L 07/19/23 21:02 79-34-562.5 9.2 125
Tetrachloroethene <10.7 ug/L 07/19/23 21:02 127-18-462.5 10.7 125
Toluene <11.2 ug/L 07/19/23 21:02 108-88-362.5 11.2 125
1,2,3-Trichlorobenzene <15.1 ug/L 07/19/23 21:02 87-61-625015.1 125
1,2,4-Trichlorobenzene <19.5 ug/L 07/19/23 21:02 120-82-125019.5 125
1,1,1-Trichloroethane <13.4 ug/L 07/19/23 21:02 71-55-662.5 13.4 125
1,1,2-Trichloroethane <12.0 ug/L 07/19/23 21:02 79-00-562.5 12.0 125
Trichloroethene <21.4 ug/L 07/19/23 21:02 79-01-662.5 21.4 125
Trichlorofluoromethane <18.0 ug/L 07/19/23 21:02 75-69-412518.0 125
1,2,3-Trichloropropane <21.6 ug/L 07/19/23 21:02 96-18-462.5 21.6 125
1,2,4-Trimethylbenzene 40.3J ug/L 07/19/23 21:02 95-63-6 C862.5 3.8 125
1,3,5-Trimethylbenzene 12.5J ug/L 07/19/23 21:02 108-67-862.5 8.9 125
Vinyl chloride <18.6 ug/L 07/19/23 21:02 75-01-412518.6 125
m&p-Xylene 29.1J ug/L 07/19/23 21:02 179601-23-112511.7 125
o-Xylene <18.0 ug/L 07/19/23 21:02 95-47-662.5 18.0 125
Surrogates
1,2-Dichloroethane-d4 (S)96 %07/19/23 21:02 17060-07-070-130 125
4-Bromofluorobenzene (S)99 %07/19/23 21:02 460-00-470-130 125
Toluene-d8 (S)100 %07/19/23 21:02 2037-26-570-130 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-12 Lab ID:92677890007 Collected:07/17/23 13:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 3240J ug/L 07/19/23 20:25 75-85-4400029840
tert-Amylmethyl ether 47.3J ug/L 07/19/23 20:25 994-05-84005.0 40
Benzene 1490 ug/L 07/19/23 20:25 71-43-220.0 3.1 40
Bromobenzene <5.4 ug/L 07/19/23 20:25 108-86-120.0 5.4 40
Bromochloromethane <3.8 ug/L 07/19/23 20:25 74-97-520.0 3.8 40
Bromodichloromethane <6.8 ug/L 07/19/23 20:25 75-27-420.0 6.8 40
Bromoform <7.9 ug/L 07/19/23 20:25 75-25-220.0 7.9 40
Bromomethane <8.9 ug/L 07/19/23 20:25 74-83-92008.9 40
tert-Butyl Alcohol 3810 ug/L 07/19/23 20:25 75-65-0200016440
n-Butylbenzene <2.7 ug/L 07/19/23 20:25 104-51-820.0 2.7 40
sec-Butylbenzene 18.2J ug/L 07/19/23 20:25 135-98-820.0 3.4 40
tert-Butylbenzene <3.4 ug/L 07/19/23 20:25 98-06-620.0 3.4 40
tert-Butyl Formate <12.0 ug/L 07/19/23 20:25 762-75-4200012.0 40
Carbon tetrachloride <6.8 ug/L 07/19/23 20:25 56-23-520.0 6.8 40
Chlorobenzene <3.4 ug/L 07/19/23 20:25 108-90-720.0 3.4 40
Chloroethane <6.9 ug/L 07/19/23 20:25 75-00-340.0 6.9 40
Chloroform <2.8 ug/L 07/19/23 20:25 67-66-320.0 2.8 40
Chloromethane <7.0 ug/L 07/19/23 20:25 74-87-340.0 7.0 40
2-Chlorotoluene <5.2 ug/L 07/19/23 20:25 95-49-820.0 5.2 40
4-Chlorotoluene <3.8 ug/L 07/19/23 20:25 106-43-420.0 3.8 40
1,2-Dibromo-3-chloropropane <7.2 ug/L 07/19/23 20:25 96-12-840.0 7.2 40
Dibromochloromethane <5.9 ug/L 07/19/23 20:25 124-48-120.0 5.9 40
1,2-Dibromoethane (EDB)<5.9 ug/L 07/19/23 20:25 106-93-420.0 5.9 40
Dibromomethane <7.5 ug/L 07/19/23 20:25 74-95-320.0 7.5 40
1,2-Dichlorobenzene <3.8 ug/L 07/19/23 20:25 95-50-120.0 3.8 40
1,3-Dichlorobenzene <3.9 ug/L 07/19/23 20:25 541-73-120.0 3.9 40
1,4-Dichlorobenzene <3.6 ug/L 07/19/23 20:25 106-46-720.0 3.6 40
Dichlorodifluoromethane <4.9 ug/L 07/19/23 20:25 75-71-820.0 4.9 40
1,1-Dichloroethane <2.2 ug/L 07/19/23 20:25 75-34-320.0 2.2 40
1,2-Dichloroethane <4.2 ug/L 07/19/23 20:25 107-06-220.0 4.2 40
1,1-Dichloroethene <3.1 ug/L 07/19/23 20:25 75-35-420.0 3.1 40
cis-1,2-Dichloroethene <4.4 ug/L 07/19/23 20:25 156-59-220.0 4.4 40
trans-1,2-Dichloroethene <4.0 ug/L 07/19/23 20:25 156-60-520.0 4.0 40
1,2-Dichloropropane <5.4 ug/L 07/19/23 20:25 78-87-520.0 5.4 40
1,3-Dichloropropane <3.4 ug/L 07/19/23 20:25 142-28-920.0 3.4 40
2,2-Dichloropropane <4.9 ug/L 07/19/23 20:25 594-20-720.0 4.9 40
1,1-Dichloropropene <2.6 ug/L 07/19/23 20:25 563-58-620.0 2.6 40
cis-1,3-Dichloropropene <3.6 ug/L 07/19/23 20:25 10061-01-520.0 3.6 40
trans-1,3-Dichloropropene <5.3 ug/L 07/19/23 20:25 10061-02-620.0 5.3 40
Diisopropyl ether 70.5 ug/L 07/19/23 20:25 108-20-320.0 2.9 40
Ethanol <202 ug/L 07/19/23 20:25 64-17-5800020240
Ethylbenzene 2210 ug/L 07/19/23 20:25 100-41-420.0 3.2 40
Ethyl-tert-butyl ether <4.5 ug/L 07/19/23 20:25 637-92-34004.5 40
Hexachloro-1,3-butadiene <14.0 ug/L 07/19/23 20:25 87-68-380.0 14.0 40
Isopropylbenzene (Cumene)136 ug/L 07/19/23 20:25 98-82-820.0 4.2 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-12 Lab ID:92677890007 Collected:07/17/23 13:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <75.6 ug/L 07/19/23 20:25 75-09-280.0 75.6 40
Methyl-tert-butyl ether 2840 ug/L 07/19/23 20:25 1634-04-420.0 2.1 40
Naphthalene 733 ug/L 07/19/23 20:25 91-20-380.0 4.0 40
n-Propylbenzene 414 ug/L 07/19/23 20:25 103-65-120.0 4.2 40
Styrene <5.5 ug/L 07/19/23 20:25 100-42-520.0 5.5 40
1,1,1,2-Tetrachloroethane <3.6 ug/L 07/19/23 20:25 630-20-620.0 3.6 40
1,1,2,2-Tetrachloroethane <3.0 ug/L 07/19/23 20:25 79-34-520.0 3.0 40
Tetrachloroethene <3.4 ug/L 07/19/23 20:25 127-18-420.0 3.4 40
Toluene 799 ug/L 07/19/23 20:25 108-88-320.0 3.6 40
1,2,3-Trichlorobenzene <4.8 ug/L 07/19/23 20:25 87-61-680.0 4.8 40
1,2,4-Trichlorobenzene <6.2 ug/L 07/19/23 20:25 120-82-180.0 6.2 40
1,1,1-Trichloroethane <4.3 ug/L 07/19/23 20:25 71-55-620.0 4.3 40
1,1,2-Trichloroethane <3.8 ug/L 07/19/23 20:25 79-00-520.0 3.8 40
Trichloroethene <6.8 ug/L 07/19/23 20:25 79-01-620.0 6.8 40
Trichlorofluoromethane <5.8 ug/L 07/19/23 20:25 75-69-440.0 5.8 40
1,2,3-Trichloropropane 21.3 ug/L 07/19/23 20:25 96-18-420.0 6.9 40
1,2,4-Trimethylbenzene 3520 ug/L 07/19/23 20:25 95-63-620.0 1.2 40
1,3,5-Trimethylbenzene 761 ug/L 07/19/23 20:25 108-67-820.0 2.9 40
Vinyl chloride <6.0 ug/L 07/19/23 20:25 75-01-440.0 6.0 40
m&p-Xylene 7750 ug/L 07/19/23 20:25 179601-23-140.0 3.7 40
o-Xylene 1670 ug/L 07/19/23 20:25 95-47-620.0 5.8 40
Surrogates
1,2-Dichloroethane-d4 (S)97 %07/19/23 20:25 17060-07-070-130 40
4-Bromofluorobenzene (S)100 %07/19/23 20:25 460-00-470-130 40
Toluene-d8 (S)100 %07/19/23 20:25 2037-26-570-130 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-13 Lab ID:92677890008 Collected:07/17/23 14:05 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 07/19/23 16:48 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 07/19/23 16:48 994-05-810.0 0.12 1
Benzene 0.15J ug/L 07/19/23 16:48 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 07/19/23 16:48 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 07/19/23 16:48 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 07/19/23 16:48 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 07/19/23 16:48 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 07/19/23 16:48 74-83-95.0 0.22 1
tert-Butyl Alcohol 5.0J ug/L 07/19/23 16:48 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 07/19/23 16:48 104-51-80.50 0.066 1
sec-Butylbenzene 0.65 ug/L 07/19/23 16:48 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 07/19/23 16:48 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 07/19/23 16:48 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 07/19/23 16:48 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 07/19/23 16:48 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 07/19/23 16:48 75-00-31.0 0.17 1
Chloroform 4.6 ug/L 07/19/23 16:48 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 07/19/23 16:48 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 07/19/23 16:48 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 07/19/23 16:48 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 07/19/23 16:48 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 07/19/23 16:48 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 07/19/23 16:48 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 07/19/23 16:48 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 07/19/23 16:48 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 07/19/23 16:48 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 07/19/23 16:48 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 07/19/23 16:48 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 07/19/23 16:48 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 07/19/23 16:48 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 07/19/23 16:48 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 07/19/23 16:48 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 07/19/23 16:48 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 07/19/23 16:48 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 07/19/23 16:48 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 07/19/23 16:48 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 07/19/23 16:48 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 07/19/23 16:48 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 07/19/23 16:48 10061-02-60.50 0.13 1
Diisopropyl ether <0.072 ug/L 07/19/23 16:48 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 07/19/23 16:48 64-17-52005.0 1
Ethylbenzene 0.10J ug/L 07/19/23 16:48 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 07/19/23 16:48 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 07/19/23 16:48 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 07/19/23 16:48 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-13 Lab ID:92677890008 Collected:07/17/23 14:05 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 07/19/23 16:48 75-09-22.0 1.9 1
Methyl-tert-butyl ether 0.39J ug/L 07/19/23 16:48 1634-04-40.50 0.053 1
Naphthalene 0.34J ug/L 07/19/23 16:48 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 07/19/23 16:48 103-65-10.50 0.10 1
Styrene <0.14 ug/L 07/19/23 16:48 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 07/19/23 16:48 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 07/19/23 16:48 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 07/19/23 16:48 127-18-40.50 0.086 1
Toluene 0.32J ug/L 07/19/23 16:48 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 07/19/23 16:48 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 07/19/23 16:48 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 07/19/23 16:48 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 07/19/23 16:48 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 07/19/23 16:48 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 07/19/23 16:48 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 07/19/23 16:48 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene 0.64 ug/L 07/19/23 16:48 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene 0.092J ug/L 07/19/23 16:48 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 07/19/23 16:48 75-01-41.0 0.15 1
m&p-Xylene 0.42J ug/L 07/19/23 16:48 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 07/19/23 16:48 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %07/19/23 16:48 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %07/19/23 16:48 460-00-470-130 1
Toluene-d8 (S)99 %07/19/23 16:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-14 Lab ID:92677890009 Collected:07/17/23 13:45 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <149 ug/L 07/20/23 18:55 75-85-4200014920
tert-Amylmethyl ether 52.7J ug/L 07/20/23 18:55 994-05-82002.5 20
Benzene <1.6 ug/L 07/20/23 18:55 71-43-210.0 1.6 20
Bromobenzene <2.7 ug/L 07/20/23 18:55 108-86-110.0 2.7 20
Bromochloromethane <1.9 ug/L 07/20/23 18:55 74-97-510.0 1.9 20
Bromodichloromethane <3.4 ug/L 07/20/23 18:55 75-27-410.0 3.4 20
Bromoform <3.9 ug/L 07/20/23 18:55 75-25-210.0 3.9 20
Bromomethane <4.4 ug/L 07/20/23 18:55 74-83-91004.4 20
tert-Butyl Alcohol 1720 ug/L 07/20/23 18:55 75-65-0100081.8 20
n-Butylbenzene <1.3 ug/L 07/20/23 18:55 104-51-810.0 1.3 20
sec-Butylbenzene <1.7 ug/L 07/20/23 18:55 135-98-810.0 1.7 20
tert-Butylbenzene <1.7 ug/L 07/20/23 18:55 98-06-610.0 1.7 20
tert-Butyl Formate <6.0 ug/L 07/20/23 18:55 762-75-410006.0 20
Carbon tetrachloride <3.4 ug/L 07/20/23 18:55 56-23-510.0 3.4 20
Chlorobenzene <1.7 ug/L 07/20/23 18:55 108-90-710.0 1.7 20
Chloroethane <3.5 ug/L 07/20/23 18:55 75-00-320.0 3.5 20
Chloroform <1.4 ug/L 07/20/23 18:55 67-66-310.0 1.4 20
Chloromethane <3.5 ug/L 07/20/23 18:55 74-87-320.0 3.5 20
2-Chlorotoluene <2.6 ug/L 07/20/23 18:55 95-49-810.0 2.6 20
4-Chlorotoluene <1.9 ug/L 07/20/23 18:55 106-43-410.0 1.9 20
1,2-Dibromo-3-chloropropane <3.6 ug/L 07/20/23 18:55 96-12-820.0 3.6 20
Dibromochloromethane <3.0 ug/L 07/20/23 18:55 124-48-110.0 3.0 20
1,2-Dibromoethane (EDB)<2.9 ug/L 07/20/23 18:55 106-93-410.0 2.9 20
Dibromomethane <3.7 ug/L 07/20/23 18:55 74-95-310.0 3.7 20
1,2-Dichlorobenzene <1.9 ug/L 07/20/23 18:55 95-50-110.0 1.9 20
1,3-Dichlorobenzene <2.0 ug/L 07/20/23 18:55 541-73-110.0 2.0 20
1,4-Dichlorobenzene <1.8 ug/L 07/20/23 18:55 106-46-710.0 1.8 20
Dichlorodifluoromethane <2.5 ug/L 07/20/23 18:55 75-71-810.0 2.5 20
1,1-Dichloroethane <1.1 ug/L 07/20/23 18:55 75-34-310.0 1.1 20
1,2-Dichloroethane <2.1 ug/L 07/20/23 18:55 107-06-210.0 2.1 20
1,1-Dichloroethene <1.6 ug/L 07/20/23 18:55 75-35-410.0 1.6 20
cis-1,2-Dichloroethene <2.2 ug/L 07/20/23 18:55 156-59-210.0 2.2 20
trans-1,2-Dichloroethene <2.0 ug/L 07/20/23 18:55 156-60-510.0 2.0 20
1,2-Dichloropropane <2.7 ug/L 07/20/23 18:55 78-87-510.0 2.7 20
1,3-Dichloropropane <1.7 ug/L 07/20/23 18:55 142-28-910.0 1.7 20
2,2-Dichloropropane <2.4 ug/L 07/20/23 18:55 594-20-710.0 2.4 20
1,1-Dichloropropene <1.3 ug/L 07/20/23 18:55 563-58-610.0 1.3 20
cis-1,3-Dichloropropene <1.8 ug/L 07/20/23 18:55 10061-01-510.0 1.8 20
trans-1,3-Dichloropropene <2.6 ug/L 07/20/23 18:55 10061-02-610.0 2.6 20
Diisopropyl ether 39.2 ug/L 07/20/23 18:55 108-20-310.0 1.4 20
Ethanol <101 ug/L 07/20/23 18:55 64-17-5400010120
Ethylbenzene <1.6 ug/L 07/20/23 18:55 100-41-410.0 1.6 20
Ethyl-tert-butyl ether <2.2 ug/L 07/20/23 18:55 637-92-32002.2 20
Hexachloro-1,3-butadiene <7.0 ug/L 07/20/23 18:55 87-68-340.0 7.0 20
Isopropylbenzene (Cumene)<2.1 ug/L 07/20/23 18:55 98-82-810.0 2.1 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-14 Lab ID:92677890009 Collected:07/17/23 13:45 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <37.8 ug/L 07/20/23 18:55 75-09-240.0 37.8 20
Methyl-tert-butyl ether 2710 ug/L 07/20/23 18:55 1634-04-410.0 1.1 20
Naphthalene 7.6J ug/L 07/20/23 18:55 91-20-340.0 2.0 20
n-Propylbenzene <2.1 ug/L 07/20/23 18:55 103-65-110.0 2.1 20
Styrene <2.7 ug/L 07/20/23 18:55 100-42-510.0 2.7 20
1,1,1,2-Tetrachloroethane <1.8 ug/L 07/20/23 18:55 630-20-610.0 1.8 20
1,1,2,2-Tetrachloroethane <1.5 ug/L 07/20/23 18:55 79-34-510.0 1.5 20
Tetrachloroethene <1.7 ug/L 07/20/23 18:55 127-18-410.0 1.7 20
Toluene <1.8 ug/L 07/20/23 18:55 108-88-310.0 1.8 20
1,2,3-Trichlorobenzene <2.4 ug/L 07/20/23 18:55 87-61-640.0 2.4 20
1,2,4-Trichlorobenzene <3.1 ug/L 07/20/23 18:55 120-82-140.0 3.1 20
1,1,1-Trichloroethane <2.1 ug/L 07/20/23 18:55 71-55-610.0 2.1 20
1,1,2-Trichloroethane <1.9 ug/L 07/20/23 18:55 79-00-510.0 1.9 20
Trichloroethene <3.4 ug/L 07/20/23 18:55 79-01-610.0 3.4 20
Trichlorofluoromethane <2.9 ug/L 07/20/23 18:55 75-69-420.0 2.9 20
1,2,3-Trichloropropane <3.5 ug/L 07/20/23 18:55 96-18-410.0 3.5 20
1,2,4-Trimethylbenzene 11.4 ug/L 07/20/23 18:55 95-63-610.0 0.61 20
1,3,5-Trimethylbenzene <1.4 ug/L 07/20/23 18:55 108-67-810.0 1.4 20
Vinyl chloride <3.0 ug/L 07/20/23 18:55 75-01-420.0 3.0 20
m&p-Xylene <1.9 ug/L 07/20/23 18:55 179601-23-120.0 1.9 20
o-Xylene <2.9 ug/L 07/20/23 18:55 95-47-610.0 2.9 20
Surrogates
1,2-Dichloroethane-d4 (S)104 %07/20/23 18:55 17060-07-070-130 20
4-Bromofluorobenzene (S)95 %07/20/23 18:55 460-00-470-130 20
Toluene-d8 (S)105 %07/20/23 18:55 2037-26-570-130 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-15 Lab ID:92677890010 Collected:07/17/23 12:45 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <14.9 ug/L 07/20/23 19:31 75-85-420014.9 2
tert-Amylmethyl ether 4.0J ug/L 07/20/23 19:31 994-05-820.0 0.25 2
Benzene <0.16 ug/L 07/20/23 19:31 71-43-21.0 0.16 2
Bromobenzene <0.27 ug/L 07/20/23 19:31 108-86-11.0 0.27 2
Bromochloromethane <0.19 ug/L 07/20/23 19:31 74-97-51.0 0.19 2
Bromodichloromethane <0.34 ug/L 07/20/23 19:31 75-27-41.0 0.34 2
Bromoform <0.39 ug/L 07/20/23 19:31 75-25-21.0 0.39 2
Bromomethane <0.44 ug/L 07/20/23 19:31 74-83-910.0 0.44 2
tert-Butyl Alcohol 91.7J ug/L 07/20/23 19:31 75-65-01008.2 2
n-Butylbenzene <0.13 ug/L 07/20/23 19:31 104-51-81.0 0.13 2
sec-Butylbenzene <0.17 ug/L 07/20/23 19:31 135-98-81.0 0.17 2
tert-Butylbenzene <0.17 ug/L 07/20/23 19:31 98-06-61.0 0.17 2
tert-Butyl Formate <0.60 ug/L 07/20/23 19:31 762-75-41000.60 2
Carbon tetrachloride <0.34 ug/L 07/20/23 19:31 56-23-51.0 0.34 2
Chlorobenzene <0.17 ug/L 07/20/23 19:31 108-90-71.0 0.17 2
Chloroethane <0.35 ug/L 07/20/23 19:31 75-00-32.0 0.35 2
Chloroform <0.14 ug/L 07/20/23 19:31 67-66-31.0 0.14 2
Chloromethane <0.35 ug/L 07/20/23 19:31 74-87-32.0 0.35 2
2-Chlorotoluene <0.26 ug/L 07/20/23 19:31 95-49-81.0 0.26 2
4-Chlorotoluene <0.19 ug/L 07/20/23 19:31 106-43-41.0 0.19 2
1,2-Dibromo-3-chloropropane <0.36 ug/L 07/20/23 19:31 96-12-82.0 0.36 2
Dibromochloromethane <0.30 ug/L 07/20/23 19:31 124-48-11.0 0.30 2
1,2-Dibromoethane (EDB)<0.29 ug/L 07/20/23 19:31 106-93-41.0 0.29 2
Dibromomethane <0.37 ug/L 07/20/23 19:31 74-95-31.0 0.37 2
1,2-Dichlorobenzene <0.19 ug/L 07/20/23 19:31 95-50-11.0 0.19 2
1,3-Dichlorobenzene <0.20 ug/L 07/20/23 19:31 541-73-11.0 0.20 2
1,4-Dichlorobenzene <0.18 ug/L 07/20/23 19:31 106-46-71.0 0.18 2
Dichlorodifluoromethane <0.25 ug/L 07/20/23 19:31 75-71-81.0 0.25 2
1,1-Dichloroethane <0.11 ug/L 07/20/23 19:31 75-34-31.0 0.11 2
1,2-Dichloroethane <0.21 ug/L 07/20/23 19:31 107-06-21.0 0.21 2
1,1-Dichloroethene <0.16 ug/L 07/20/23 19:31 75-35-41.0 0.16 2
cis-1,2-Dichloroethene <0.22 ug/L 07/20/23 19:31 156-59-21.0 0.22 2
trans-1,2-Dichloroethene <0.20 ug/L 07/20/23 19:31 156-60-51.0 0.20 2
1,2-Dichloropropane <0.27 ug/L 07/20/23 19:31 78-87-51.0 0.27 2
1,3-Dichloropropane <0.17 ug/L 07/20/23 19:31 142-28-91.0 0.17 2
2,2-Dichloropropane <0.24 ug/L 07/20/23 19:31 594-20-71.0 0.24 2
1,1-Dichloropropene <0.13 ug/L 07/20/23 19:31 563-58-61.0 0.13 2
cis-1,3-Dichloropropene <0.18 ug/L 07/20/23 19:31 10061-01-51.0 0.18 2
trans-1,3-Dichloropropene <0.26 ug/L 07/20/23 19:31 10061-02-61.0 0.26 2
Diisopropyl ether 4.5 ug/L 07/20/23 19:31 108-20-31.0 0.14 2
Ethanol <10.1 ug/L 07/20/23 19:31 64-17-540010.1 2
Ethylbenzene 0.60J ug/L 07/20/23 19:31 100-41-41.0 0.16 2
Ethyl-tert-butyl ether <0.22 ug/L 07/20/23 19:31 637-92-320.0 0.22 2
Hexachloro-1,3-butadiene <0.70 ug/L 07/20/23 19:31 87-68-34.0 0.70 2
Isopropylbenzene (Cumene)<0.21 ug/L 07/20/23 19:31 98-82-81.0 0.21 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-15 Lab ID:92677890010 Collected:07/17/23 12:45 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <3.8 ug/L 07/20/23 19:31 75-09-24.0 3.8 2
Methyl-tert-butyl ether 227 ug/L 07/20/23 19:31 1634-04-41.0 0.11 2
Naphthalene 0.84J ug/L 07/20/23 19:31 91-20-34.0 0.20 2
n-Propylbenzene <0.21 ug/L 07/20/23 19:31 103-65-11.0 0.21 2
Styrene <0.27 ug/L 07/20/23 19:31 100-42-51.0 0.27 2
1,1,1,2-Tetrachloroethane <0.18 ug/L 07/20/23 19:31 630-20-61.0 0.18 2
1,1,2,2-Tetrachloroethane <0.15 ug/L 07/20/23 19:31 79-34-51.0 0.15 2
Tetrachloroethene <0.17 ug/L 07/20/23 19:31 127-18-41.0 0.17 2
Toluene <0.18 ug/L 07/20/23 19:31 108-88-31.0 0.18 2
1,2,3-Trichlorobenzene <0.24 ug/L 07/20/23 19:31 87-61-64.0 0.24 2
1,2,4-Trichlorobenzene <0.31 ug/L 07/20/23 19:31 120-82-14.0 0.31 2
1,1,1-Trichloroethane <0.21 ug/L 07/20/23 19:31 71-55-61.0 0.21 2
1,1,2-Trichloroethane <0.19 ug/L 07/20/23 19:31 79-00-51.0 0.19 2
Trichloroethene <0.34 ug/L 07/20/23 19:31 79-01-61.0 0.34 2
Trichlorofluoromethane <0.29 ug/L 07/20/23 19:31 75-69-42.0 0.29 2
1,2,3-Trichloropropane <0.35 ug/L 07/20/23 19:31 96-18-41.0 0.35 2
1,2,4-Trimethylbenzene 3.3 ug/L 07/20/23 19:31 95-63-61.0 0.061 2
1,3,5-Trimethylbenzene <0.14 ug/L 07/20/23 19:31 108-67-81.0 0.14 2
Vinyl chloride <0.30 ug/L 07/20/23 19:31 75-01-42.0 0.30 2
m&p-Xylene 2.5 ug/L 07/20/23 19:31 179601-23-12.0 0.19 2
o-Xylene 0.52J ug/L 07/20/23 19:31 95-47-61.0 0.29 2
Surrogates
1,2-Dichloroethane-d4 (S)104 %07/20/23 19:31 17060-07-070-130 2
4-Bromofluorobenzene (S)95 %07/20/23 19:31 460-00-470-130 2
Toluene-d8 (S)107 %07/20/23 19:31 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-16 Lab ID:92677890011 Collected:07/17/23 12:25 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <186 ug/L 07/20/23 20:07 75-85-4250018625
tert-Amylmethyl ether 50.8J ug/L 07/20/23 20:07 994-05-82503.1 25
Benzene 55.0 ug/L 07/20/23 20:07 71-43-212.5 2.0 25
Bromobenzene <3.4 ug/L 07/20/23 20:07 108-86-112.5 3.4 25
Bromochloromethane <2.4 ug/L 07/20/23 20:07 74-97-512.5 2.4 25
Bromodichloromethane <4.2 ug/L 07/20/23 20:07 75-27-412.5 4.2 25
Bromoform <4.9 ug/L 07/20/23 20:07 75-25-212.5 4.9 25
Bromomethane <5.6 ug/L 07/20/23 20:07 74-83-91255.6 25
tert-Butyl Alcohol 3140 ug/L 07/20/23 20:07 75-65-0125010225
n-Butylbenzene <1.7 ug/L 07/20/23 20:07 104-51-812.5 1.7 25
sec-Butylbenzene <2.1 ug/L 07/20/23 20:07 135-98-812.5 2.1 25
tert-Butylbenzene <2.1 ug/L 07/20/23 20:07 98-06-612.5 2.1 25
tert-Butyl Formate <7.5 ug/L 07/20/23 20:07 762-75-412507.5 25
Carbon tetrachloride <4.2 ug/L 07/20/23 20:07 56-23-512.5 4.2 25
Chlorobenzene <2.1 ug/L 07/20/23 20:07 108-90-712.5 2.1 25
Chloroethane <4.3 ug/L 07/20/23 20:07 75-00-325.0 4.3 25
Chloroform 4.3J ug/L 07/20/23 20:07 67-66-312.5 1.7 25
Chloromethane <4.4 ug/L 07/20/23 20:07 74-87-325.0 4.4 25
2-Chlorotoluene <3.2 ug/L 07/20/23 20:07 95-49-812.5 3.2 25
4-Chlorotoluene <2.4 ug/L 07/20/23 20:07 106-43-412.5 2.4 25
1,2-Dibromo-3-chloropropane <4.5 ug/L 07/20/23 20:07 96-12-825.0 4.5 25
Dibromochloromethane <3.7 ug/L 07/20/23 20:07 124-48-112.5 3.7 25
1,2-Dibromoethane (EDB)<3.7 ug/L 07/20/23 20:07 106-93-412.5 3.7 25
Dibromomethane <4.7 ug/L 07/20/23 20:07 74-95-312.5 4.7 25
1,2-Dichlorobenzene <2.4 ug/L 07/20/23 20:07 95-50-112.5 2.4 25
1,3-Dichlorobenzene <2.4 ug/L 07/20/23 20:07 541-73-112.5 2.4 25
1,4-Dichlorobenzene <2.2 ug/L 07/20/23 20:07 106-46-712.5 2.2 25
Dichlorodifluoromethane <3.1 ug/L 07/20/23 20:07 75-71-812.5 3.1 25
1,1-Dichloroethane <1.4 ug/L 07/20/23 20:07 75-34-312.5 1.4 25
1,2-Dichloroethane <2.6 ug/L 07/20/23 20:07 107-06-212.5 2.6 25
1,1-Dichloroethene <2.0 ug/L 07/20/23 20:07 75-35-412.5 2.0 25
cis-1,2-Dichloroethene <2.8 ug/L 07/20/23 20:07 156-59-212.5 2.8 25
trans-1,2-Dichloroethene <2.5 ug/L 07/20/23 20:07 156-60-512.5 2.5 25
1,2-Dichloropropane <3.4 ug/L 07/20/23 20:07 78-87-512.5 3.4 25
1,3-Dichloropropane <2.1 ug/L 07/20/23 20:07 142-28-912.5 2.1 25
2,2-Dichloropropane <3.0 ug/L 07/20/23 20:07 594-20-712.5 3.0 25
1,1-Dichloropropene <1.6 ug/L 07/20/23 20:07 563-58-612.5 1.6 25
cis-1,3-Dichloropropene <2.2 ug/L 07/20/23 20:07 10061-01-512.5 2.2 25
trans-1,3-Dichloropropene <3.3 ug/L 07/20/23 20:07 10061-02-612.5 3.3 25
Diisopropyl ether 51.6 ug/L 07/20/23 20:07 108-20-312.5 1.8 25
Ethanol <126 ug/L 07/20/23 20:07 64-17-5500012625
Ethylbenzene 1260 ug/L 07/20/23 20:07 100-41-412.5 2.0 25
Ethyl-tert-butyl ether <2.8 ug/L 07/20/23 20:07 637-92-32502.8 25
Hexachloro-1,3-butadiene <8.8 ug/L 07/20/23 20:07 87-68-350.0 8.8 25
Isopropylbenzene (Cumene)115 ug/L 07/20/23 20:07 98-82-812.5 2.6 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:MW-16 Lab ID:92677890011 Collected:07/17/23 12:25 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <47.2 ug/L 07/20/23 20:07 75-09-250.0 47.2 25
Methyl-tert-butyl ether 3250 ug/L 07/20/23 20:07 1634-04-412.5 1.3 25
Naphthalene 915 ug/L 07/20/23 20:07 91-20-350.0 2.5 25
n-Propylbenzene 335 ug/L 07/20/23 20:07 103-65-112.5 2.6 25
Styrene <3.4 ug/L 07/20/23 20:07 100-42-512.5 3.4 25
1,1,1,2-Tetrachloroethane <2.3 ug/L 07/20/23 20:07 630-20-612.5 2.3 25
1,1,2,2-Tetrachloroethane <1.8 ug/L 07/20/23 20:07 79-34-512.5 1.8 25
Tetrachloroethene <2.1 ug/L 07/20/23 20:07 127-18-412.5 2.1 25
Toluene 83.7 ug/L 07/20/23 20:07 108-88-312.5 2.2 25
1,2,3-Trichlorobenzene <3.0 ug/L 07/20/23 20:07 87-61-650.0 3.0 25
1,2,4-Trichlorobenzene <3.9 ug/L 07/20/23 20:07 120-82-150.0 3.9 25
1,1,1-Trichloroethane <2.7 ug/L 07/20/23 20:07 71-55-612.5 2.7 25
1,1,2-Trichloroethane <2.4 ug/L 07/20/23 20:07 79-00-512.5 2.4 25
Trichloroethene <4.3 ug/L 07/20/23 20:07 79-01-612.5 4.3 25
Trichlorofluoromethane <3.6 ug/L 07/20/23 20:07 75-69-425.0 3.6 25
1,2,3-Trichloropropane 16.7 ug/L 07/20/23 20:07 96-18-412.5 4.3 25
1,2,4-Trimethylbenzene 3530 ug/L 07/20/23 20:07 95-63-612.5 0.77 25
1,3,5-Trimethylbenzene 701 ug/L 07/20/23 20:07 108-67-812.5 1.8 25
Vinyl chloride <3.7 ug/L 07/20/23 20:07 75-01-425.0 3.7 25
m&p-Xylene 5420 ug/L 07/20/23 20:07 179601-23-125.0 2.3 25
o-Xylene 1400 ug/L 07/20/23 20:07 95-47-612.5 3.6 25
Surrogates
1,2-Dichloroethane-d4 (S)101 %07/20/23 20:07 17060-07-070-130 25
4-Bromofluorobenzene (S)94 %07/20/23 20:07 460-00-470-130 25
Toluene-d8 (S)107 %07/20/23 20:07 2037-26-570-130 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-1 Lab ID:92677890012 Collected:07/17/23 13:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <930 ug/L 07/20/23 20:43 75-85-412500930125
tert-Amylmethyl ether 280J ug/L 07/20/23 20:43 994-05-8125015.5 125
Benzene <9.8 ug/L 07/20/23 20:43 71-43-262.5 9.8 125
Bromobenzene <16.9 ug/L 07/20/23 20:43 108-86-162.5 16.9 125
Bromochloromethane <11.8 ug/L 07/20/23 20:43 74-97-562.5 11.8 125
Bromodichloromethane <21.2 ug/L 07/20/23 20:43 75-27-462.5 21.2 125
Bromoform <24.6 ug/L 07/20/23 20:43 75-25-262.5 24.6 125
Bromomethane <27.8 ug/L 07/20/23 20:43 74-83-962527.8 125
tert-Butyl Alcohol 7460 ug/L 07/20/23 20:43 75-65-06250511125
n-Butylbenzene <8.3 ug/L 07/20/23 20:43 104-51-862.5 8.3 125
sec-Butylbenzene <10.6 ug/L 07/20/23 20:43 135-98-862.5 10.6 125
tert-Butylbenzene <10.7 ug/L 07/20/23 20:43 98-06-662.5 10.7 125
tert-Butyl Formate <37.5 ug/L 07/20/23 20:43 762-75-4625037.5 125
Carbon tetrachloride <21.1 ug/L 07/20/23 20:43 56-23-562.5 21.1 125
Chlorobenzene <10.6 ug/L 07/20/23 20:43 108-90-762.5 10.6 125
Chloroethane <21.6 ug/L 07/20/23 20:43 75-00-312521.6 125
Chloroform 949 ug/L 07/20/23 20:43 67-66-362.5 8.6 125
Chloromethane <21.9 ug/L 07/20/23 20:43 74-87-312521.9 125
2-Chlorotoluene <16.1 ug/L 07/20/23 20:43 95-49-862.5 16.1 125
4-Chlorotoluene <12.0 ug/L 07/20/23 20:43 106-43-462.5 12.0 125
1,2-Dibromo-3-chloropropane <22.4 ug/L 07/20/23 20:43 96-12-812522.4 125
Dibromochloromethane <18.5 ug/L 07/20/23 20:43 124-48-162.5 18.5 125
1,2-Dibromoethane (EDB)<18.4 ug/L 07/20/23 20:43 106-93-462.5 18.4 125
Dibromomethane <23.4 ug/L 07/20/23 20:43 74-95-362.5 23.4 125
1,2-Dichlorobenzene <11.8 ug/L 07/20/23 20:43 95-50-162.5 11.8 125
1,3-Dichlorobenzene <12.2 ug/L 07/20/23 20:43 541-73-162.5 12.2 125
1,4-Dichlorobenzene <11.2 ug/L 07/20/23 20:43 106-46-762.5 11.2 125
Dichlorodifluoromethane <15.4 ug/L 07/20/23 20:43 75-71-862.5 15.4 125
1,1-Dichloroethane <7.0 ug/L 07/20/23 20:43 75-34-362.5 7.0 125
1,2-Dichloroethane <13.2 ug/L 07/20/23 20:43 107-06-262.5 13.2 125
1,1-Dichloroethene <9.8 ug/L 07/20/23 20:43 75-35-462.5 9.8 125
cis-1,2-Dichloroethene <13.9 ug/L 07/20/23 20:43 156-59-262.5 13.9 125
trans-1,2-Dichloroethene <12.6 ug/L 07/20/23 20:43 156-60-562.5 12.6 125
1,2-Dichloropropane <17.0 ug/L 07/20/23 20:43 78-87-562.5 17.0 125
1,3-Dichloropropane <10.7 ug/L 07/20/23 20:43 142-28-962.5 10.7 125
2,2-Dichloropropane <15.2 ug/L 07/20/23 20:43 594-20-762.5 15.2 125
1,1-Dichloropropene <8.2 ug/L 07/20/23 20:43 563-58-662.5 8.2 125
cis-1,3-Dichloropropene <11.2 ug/L 07/20/23 20:43 10061-01-562.5 11.2 125
trans-1,3-Dichloropropene <16.5 ug/L 07/20/23 20:43 10061-02-662.5 16.5 125
Diisopropyl ether 181 ug/L 07/20/23 20:43 108-20-362.5 9.1 125
Ethanol <631 ug/L 07/20/23 20:43 64-17-525000631125
Ethylbenzene <10.2 ug/L 07/20/23 20:43 100-41-462.5 10.2 125
Ethyl-tert-butyl ether <14.0 ug/L 07/20/23 20:43 637-92-3125014.0 125
Hexachloro-1,3-butadiene <43.9 ug/L 07/20/23 20:43 87-68-325043.9 125
Isopropylbenzene (Cumene)<13.2 ug/L 07/20/23 20:43 98-82-862.5 13.2 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-1 Lab ID:92677890012 Collected:07/17/23 13:10 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <236 ug/L 07/20/23 20:43 75-09-2250236125
Methyl-tert-butyl ether 13900 ug/L 07/20/23 20:43 1634-04-462.5 6.7 125
Naphthalene <12.6 ug/L 07/20/23 20:43 91-20-325012.6 125
n-Propylbenzene <13.1 ug/L 07/20/23 20:43 103-65-162.5 13.1 125
Styrene <17.1 ug/L 07/20/23 20:43 100-42-562.5 17.1 125
1,1,1,2-Tetrachloroethane <11.4 ug/L 07/20/23 20:43 630-20-662.5 11.4 125
1,1,2,2-Tetrachloroethane <9.2 ug/L 07/20/23 20:43 79-34-562.5 9.2 125
Tetrachloroethene <10.7 ug/L 07/20/23 20:43 127-18-462.5 10.7 125
Toluene <11.2 ug/L 07/20/23 20:43 108-88-362.5 11.2 125
1,2,3-Trichlorobenzene <15.1 ug/L 07/20/23 20:43 87-61-625015.1 125
1,2,4-Trichlorobenzene <19.5 ug/L 07/20/23 20:43 120-82-125019.5 125
1,1,1-Trichloroethane <13.4 ug/L 07/20/23 20:43 71-55-662.5 13.4 125
1,1,2-Trichloroethane <12.0 ug/L 07/20/23 20:43 79-00-562.5 12.0 125
Trichloroethene <21.4 ug/L 07/20/23 20:43 79-01-662.5 21.4 125
Trichlorofluoromethane <18.0 ug/L 07/20/23 20:43 75-69-412518.0 125
1,2,3-Trichloropropane <21.6 ug/L 07/20/23 20:43 96-18-462.5 21.6 125
1,2,4-Trimethylbenzene 64.8 ug/L 07/20/23 20:43 95-63-662.5 3.8 125
1,3,5-Trimethylbenzene <8.9 ug/L 07/20/23 20:43 108-67-862.5 8.9 125
Vinyl chloride <18.6 ug/L 07/20/23 20:43 75-01-412518.6 125
m&p-Xylene <11.7 ug/L 07/20/23 20:43 179601-23-112511.7 125
o-Xylene <18.0 ug/L 07/20/23 20:43 95-47-662.5 18.0 125
Surrogates
1,2-Dichloroethane-d4 (S)103 %07/20/23 20:43 17060-07-070-130 125
4-Bromofluorobenzene (S)95 %07/20/23 20:43 460-00-470-130 125
Toluene-d8 (S)105 %07/20/23 20:43 2037-26-570-130 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-2 Lab ID:92677890013 Collected:07/17/23 11:25 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 07/19/23 17:42 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 07/19/23 17:42 994-05-810.0 0.12 1
Benzene <0.079 ug/L 07/19/23 17:42 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 07/19/23 17:42 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 07/19/23 17:42 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 07/19/23 17:42 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 07/19/23 17:42 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 07/19/23 17:42 74-83-95.0 0.22 1
tert-Butyl Alcohol <4.1 ug/L 07/19/23 17:42 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 07/19/23 17:42 104-51-80.50 0.066 1
sec-Butylbenzene <0.085 ug/L 07/19/23 17:42 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 07/19/23 17:42 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 07/19/23 17:42 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 07/19/23 17:42 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 07/19/23 17:42 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 07/19/23 17:42 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 07/19/23 17:42 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 07/19/23 17:42 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 07/19/23 17:42 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 07/19/23 17:42 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 07/19/23 17:42 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 07/19/23 17:42 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 07/19/23 17:42 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 07/19/23 17:42 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 07/19/23 17:42 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 07/19/23 17:42 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 07/19/23 17:42 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 07/19/23 17:42 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 07/19/23 17:42 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 07/19/23 17:42 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 07/19/23 17:42 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 07/19/23 17:42 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 07/19/23 17:42 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 07/19/23 17:42 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 07/19/23 17:42 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 07/19/23 17:42 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 07/19/23 17:42 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 07/19/23 17:42 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 07/19/23 17:42 10061-02-60.50 0.13 1
Diisopropyl ether 13.0 ug/L 07/19/23 17:42 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 07/19/23 17:42 64-17-52005.0 1
Ethylbenzene <0.081 ug/L 07/19/23 17:42 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 07/19/23 17:42 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 07/19/23 17:42 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 07/19/23 17:42 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-2 Lab ID:92677890013 Collected:07/17/23 11:25 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 07/19/23 17:42 75-09-22.0 1.9 1
Methyl-tert-butyl ether 4.4 ug/L 07/19/23 17:42 1634-04-40.50 0.053 1
Naphthalene <0.10 ug/L 07/19/23 17:42 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 07/19/23 17:42 103-65-10.50 0.10 1
Styrene <0.14 ug/L 07/19/23 17:42 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 07/19/23 17:42 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 07/19/23 17:42 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 07/19/23 17:42 127-18-40.50 0.086 1
Toluene <0.090 ug/L 07/19/23 17:42 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 07/19/23 17:42 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 07/19/23 17:42 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 07/19/23 17:42 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 07/19/23 17:42 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 07/19/23 17:42 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 07/19/23 17:42 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 07/19/23 17:42 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene <0.031 ug/L 07/19/23 17:42 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 07/19/23 17:42 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 07/19/23 17:42 75-01-41.0 0.15 1
m&p-Xylene <0.094 ug/L 07/19/23 17:42 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 07/19/23 17:42 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %07/19/23 17:42 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %07/19/23 17:42 460-00-470-130 1
Toluene-d8 (S)100 %07/19/23 17:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-3 Lab ID:92677890014 Collected:07/17/23 14:00 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7.4 ug/L 07/19/23 17:06 75-85-41007.4 1
tert-Amylmethyl ether <0.12 ug/L 07/19/23 17:06 994-05-810.0 0.12 1
Benzene <0.079 ug/L 07/19/23 17:06 71-43-20.50 0.079 1
Bromobenzene <0.14 ug/L 07/19/23 17:06 108-86-10.50 0.14 1
Bromochloromethane <0.094 ug/L 07/19/23 17:06 74-97-50.50 0.094 1
Bromodichloromethane <0.17 ug/L 07/19/23 17:06 75-27-40.50 0.17 1
Bromoform <0.20 ug/L 07/19/23 17:06 75-25-20.50 0.20 1
Bromomethane <0.22 ug/L 07/19/23 17:06 74-83-95.0 0.22 1
tert-Butyl Alcohol <4.1 ug/L 07/19/23 17:06 75-65-050.0 4.1 1
n-Butylbenzene <0.066 ug/L 07/19/23 17:06 104-51-80.50 0.066 1
sec-Butylbenzene <0.085 ug/L 07/19/23 17:06 135-98-80.50 0.085 1
tert-Butylbenzene <0.086 ug/L 07/19/23 17:06 98-06-60.50 0.086 1
tert-Butyl Formate <0.30 ug/L 07/19/23 17:06 762-75-450.0 0.30 1
Carbon tetrachloride <0.17 ug/L 07/19/23 17:06 56-23-50.50 0.17 1
Chlorobenzene <0.085 ug/L 07/19/23 17:06 108-90-70.50 0.085 1
Chloroethane <0.17 ug/L 07/19/23 17:06 75-00-31.0 0.17 1
Chloroform <0.069 ug/L 07/19/23 17:06 67-66-30.50 0.069 1
Chloromethane <0.18 ug/L 07/19/23 17:06 74-87-31.0 0.18 1
2-Chlorotoluene <0.13 ug/L 07/19/23 17:06 95-49-80.50 0.13 1
4-Chlorotoluene <0.096 ug/L 07/19/23 17:06 106-43-40.50 0.096 1
1,2-Dibromo-3-chloropropane <0.18 ug/L 07/19/23 17:06 96-12-81.0 0.18 1
Dibromochloromethane <0.15 ug/L 07/19/23 17:06 124-48-10.50 0.15 1
1,2-Dibromoethane (EDB)<0.15 ug/L 07/19/23 17:06 106-93-40.50 0.15 1
Dibromomethane <0.19 ug/L 07/19/23 17:06 74-95-30.50 0.19 1
1,2-Dichlorobenzene <0.094 ug/L 07/19/23 17:06 95-50-10.50 0.094 1
1,3-Dichlorobenzene <0.098 ug/L 07/19/23 17:06 541-73-10.50 0.098 1
1,4-Dichlorobenzene <0.090 ug/L 07/19/23 17:06 106-46-70.50 0.090 1
Dichlorodifluoromethane <0.12 ug/L 07/19/23 17:06 75-71-80.50 0.12 1
1,1-Dichloroethane <0.056 ug/L 07/19/23 17:06 75-34-30.50 0.056 1
1,2-Dichloroethane <0.11 ug/L 07/19/23 17:06 107-06-20.50 0.11 1
1,1-Dichloroethene <0.079 ug/L 07/19/23 17:06 75-35-40.50 0.079 1
cis-1,2-Dichloroethene <0.11 ug/L 07/19/23 17:06 156-59-20.50 0.11 1
trans-1,2-Dichloroethene <0.10 ug/L 07/19/23 17:06 156-60-50.50 0.10 1
1,2-Dichloropropane <0.14 ug/L 07/19/23 17:06 78-87-50.50 0.14 1
1,3-Dichloropropane <0.085 ug/L 07/19/23 17:06 142-28-90.50 0.085 1
2,2-Dichloropropane <0.12 ug/L 07/19/23 17:06 594-20-70.50 0.12 1
1,1-Dichloropropene <0.066 ug/L 07/19/23 17:06 563-58-60.50 0.066 1
cis-1,3-Dichloropropene <0.090 ug/L 07/19/23 17:06 10061-01-50.50 0.090 1
trans-1,3-Dichloropropene <0.13 ug/L 07/19/23 17:06 10061-02-60.50 0.13 1
Diisopropyl ether <0.072 ug/L 07/19/23 17:06 108-20-30.50 0.072 1
Ethanol <5.0 ug/L 07/19/23 17:06 64-17-52005.0 1
Ethylbenzene <0.081 ug/L 07/19/23 17:06 100-41-40.50 0.081 1
Ethyl-tert-butyl ether <0.11 ug/L 07/19/23 17:06 637-92-310.0 0.11 1
Hexachloro-1,3-butadiene <0.35 ug/L 07/19/23 17:06 87-68-32.0 0.35 1
Isopropylbenzene (Cumene)<0.11 ug/L 07/19/23 17:06 98-82-80.50 0.11 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677890
CK 3940
Sample:DW-3 Lab ID:92677890014 Collected:07/17/23 14:00 Received:07/18/23 07:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <1.9 ug/L 07/19/23 17:06 75-09-22.0 1.9 1
Methyl-tert-butyl ether 0.087J ug/L 07/19/23 17:06 1634-04-40.50 0.053 1
Naphthalene <0.10 ug/L 07/19/23 17:06 91-20-32.0 0.10 1
n-Propylbenzene <0.10 ug/L 07/19/23 17:06 103-65-10.50 0.10 1
Styrene <0.14 ug/L 07/19/23 17:06 100-42-50.50 0.14 1
1,1,1,2-Tetrachloroethane <0.091 ug/L 07/19/23 17:06 630-20-60.50 0.091 1
1,1,2,2-Tetrachloroethane <0.074 ug/L 07/19/23 17:06 79-34-50.50 0.074 1
Tetrachloroethene <0.086 ug/L 07/19/23 17:06 127-18-40.50 0.086 1
Toluene <0.090 ug/L 07/19/23 17:06 108-88-30.50 0.090 1
1,2,3-Trichlorobenzene <0.12 ug/L 07/19/23 17:06 87-61-62.0 0.12 1
1,2,4-Trichlorobenzene <0.16 ug/L 07/19/23 17:06 120-82-12.0 0.16 1
1,1,1-Trichloroethane <0.11 ug/L 07/19/23 17:06 71-55-60.50 0.11 1
1,1,2-Trichloroethane <0.096 ug/L 07/19/23 17:06 79-00-50.50 0.096 1
Trichloroethene <0.17 ug/L 07/19/23 17:06 79-01-60.50 0.17 1
Trichlorofluoromethane <0.14 ug/L 07/19/23 17:06 75-69-41.0 0.14 1
1,2,3-Trichloropropane <0.17 ug/L 07/19/23 17:06 96-18-40.50 0.17 1
1,2,4-Trimethylbenzene <0.031 ug/L 07/19/23 17:06 95-63-60.50 0.031 1
1,3,5-Trimethylbenzene <0.071 ug/L 07/19/23 17:06 108-67-80.50 0.071 1
Vinyl chloride <0.15 ug/L 07/19/23 17:06 75-01-41.0 0.15 1
m&p-Xylene <0.094 ug/L 07/19/23 17:06 179601-23-11.0 0.094 1
o-Xylene <0.14 ug/L 07/19/23 17:06 95-47-60.50 0.14 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %07/19/23 17:06 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %07/19/23 17:06 460-00-470-130 1
Toluene-d8 (S)100 %07/19/23 17:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
787755
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92677890002, 92677890004, 92677890006, 92677890007, 92677890008, 92677890013, 92677890014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4083697
Associated Lab Samples:92677890002, 92677890004, 92677890006, 92677890007, 92677890008, 92677890013, 92677890014
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.091 0.50 07/19/23 14:410.091
1,1,1-Trichloroethane ug/L <0.11 0.50 07/19/23 14:410.11
1,1,2,2-Tetrachloroethane ug/L <0.074 0.50 07/19/23 14:410.074
1,1,2-Trichloroethane ug/L <0.096 0.50 07/19/23 14:410.096
1,1-Dichloroethane ug/L <0.056 0.50 07/19/23 14:410.056
1,1-Dichloroethene ug/L <0.079 0.50 07/19/23 14:410.079
1,1-Dichloropropene ug/L <0.066 0.50 07/19/23 14:410.066
1,2,3-Trichlorobenzene ug/L <0.12 2.0 07/19/23 14:410.12
1,2,3-Trichloropropane ug/L <0.17 0.50 07/19/23 14:410.17
1,2,4-Trichlorobenzene ug/L <0.16 2.0 07/19/23 14:410.16
1,2,4-Trimethylbenzene ug/L <0.031 0.50 07/19/23 14:410.031
1,2-Dibromo-3-chloropropane ug/L <0.18 1.0 07/19/23 14:410.18
1,2-Dibromoethane (EDB)ug/L <0.15 0.50 07/19/23 14:410.15
1,2-Dichlorobenzene ug/L <0.094 0.50 07/19/23 14:410.094
1,2-Dichloroethane ug/L <0.11 0.50 07/19/23 14:410.11
1,2-Dichloropropane ug/L <0.14 0.50 07/19/23 14:410.14
1,3,5-Trimethylbenzene ug/L <0.071 0.50 07/19/23 14:410.071
1,3-Dichlorobenzene ug/L <0.098 0.50 07/19/23 14:410.098
1,3-Dichloropropane ug/L <0.085 0.50 07/19/23 14:410.085
1,4-Dichlorobenzene ug/L <0.090 0.50 07/19/23 14:410.090
2,2-Dichloropropane ug/L <0.12 0.50 07/19/23 14:410.12
2-Chlorotoluene ug/L <0.13 0.50 07/19/23 14:410.13
4-Chlorotoluene ug/L <0.096 0.50 07/19/23 14:410.096
Benzene ug/L <0.079 0.50 07/19/23 14:410.079
Bromobenzene ug/L <0.14 0.50 07/19/23 14:410.14
Bromochloromethane ug/L <0.094 0.50 07/19/23 14:410.094
Bromodichloromethane ug/L <0.17 0.50 07/19/23 14:410.17
Bromoform ug/L <0.20 0.50 07/19/23 14:410.20
Bromomethane ug/L <0.22 5.0 07/19/23 14:410.22
Carbon tetrachloride ug/L <0.17 0.50 07/19/23 14:410.17
Chlorobenzene ug/L <0.085 0.50 07/19/23 14:410.085
Chloroethane ug/L <0.17 1.0 07/19/23 14:410.17
Chloroform ug/L <0.069 0.50 07/19/23 14:410.069
Chloromethane ug/L <0.18 1.0 07/19/23 14:410.18
cis-1,2-Dichloroethene ug/L <0.11 0.50 07/19/23 14:410.11
cis-1,3-Dichloropropene ug/L <0.090 0.50 07/19/23 14:410.090
Dibromochloromethane ug/L <0.15 0.50 07/19/23 14:410.15
Dibromomethane ug/L <0.19 0.50 07/19/23 14:410.19
Dichlorodifluoromethane ug/L <0.12 0.50 07/19/23 14:410.12
Diisopropyl ether ug/L <0.072 0.50 07/19/23 14:410.072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4083697
Associated Lab Samples:92677890002, 92677890004, 92677890006, 92677890007, 92677890008, 92677890013, 92677890014
Matrix:Water
AnalyzedMDL
Ethanol ug/L <5.0 200 07/19/23 14:415.0
Ethyl-tert-butyl ether ug/L <0.11 10.0 07/19/23 14:410.11
Ethylbenzene ug/L <0.081 0.50 07/19/23 14:410.081
Hexachloro-1,3-butadiene ug/L <0.35 2.0 07/19/23 14:410.35
Isopropylbenzene (Cumene)ug/L <0.11 0.50 07/19/23 14:410.11
m&p-Xylene ug/L <0.094 1.0 07/19/23 14:410.094
Methyl-tert-butyl ether ug/L <0.053 0.50 07/19/23 14:410.053
Methylene Chloride ug/L <1.9 2.0 07/19/23 14:411.9
n-Butylbenzene ug/L <0.066 0.50 07/19/23 14:410.066
n-Propylbenzene ug/L <0.10 0.50 07/19/23 14:410.10
Naphthalene ug/L <0.10 2.0 07/19/23 14:410.10
o-Xylene ug/L <0.14 0.50 07/19/23 14:410.14
sec-Butylbenzene ug/L <0.085 0.50 07/19/23 14:410.085
Styrene ug/L <0.14 0.50 07/19/23 14:410.14
tert-Amyl Alcohol ug/L <7.4 100 07/19/23 14:417.4
tert-Amylmethyl ether ug/L <0.12 10.0 07/19/23 14:410.12
tert-Butyl Alcohol ug/L <4.1 50.0 07/19/23 14:414.1
tert-Butyl Formate ug/L <0.30 50.0 07/19/23 14:410.30
tert-Butylbenzene ug/L <0.086 0.50 07/19/23 14:410.086
Tetrachloroethene ug/L <0.086 0.50 07/19/23 14:410.086
Toluene ug/L <0.090 0.50 07/19/23 14:410.090
trans-1,2-Dichloroethene ug/L <0.10 0.50 07/19/23 14:410.10
trans-1,3-Dichloropropene ug/L <0.13 0.50 07/19/23 14:410.13
Trichloroethene ug/L <0.17 0.50 07/19/23 14:410.17
Trichlorofluoromethane ug/L <0.14 1.0 07/19/23 14:410.14
Vinyl chloride ug/L <0.15 1.0 07/19/23 14:410.15
1,2-Dichloroethane-d4 (S)%96 70-130 07/19/23 14:41
4-Bromofluorobenzene (S)%99 70-130 07/19/23 14:41
Toluene-d8 (S)%99 70-130 07/19/23 14:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4083698LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.920 109 60-140
1,1,1-Trichloroethane ug/L 20.620 103 60-140
1,1,2,2-Tetrachloroethane ug/L 23.420 117 60-140
1,1,2-Trichloroethane ug/L 21.820 109 60-140
1,1-Dichloroethane ug/L 21.220 106 60-140
1,1-Dichloroethene ug/L 22.420 112 60-140
1,1-Dichloropropene ug/L 22.120 111 60-140
1,2,3-Trichlorobenzene ug/L 21.120 105 60-140
1,2,3-Trichloropropane ug/L 21.820 109 60-140
1,2,4-Trichlorobenzene ug/L 20.720 103 60-140
1,2,4-Trimethylbenzene ug/L 21.720 108 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4083698LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 20.420 102 60-140
1,2-Dibromoethane (EDB)ug/L 22.620 113 60-140
1,2-Dichlorobenzene ug/L 21.420 107 60-140
1,2-Dichloroethane ug/L 21.620 108 60-140
1,2-Dichloropropane ug/L 22.020 110 60-140
1,3,5-Trimethylbenzene ug/L 21.320 106 60-140
1,3-Dichlorobenzene ug/L 21.920 109 60-140
1,3-Dichloropropane ug/L 22.020 110 60-140
1,4-Dichlorobenzene ug/L 20.720 103 60-140
2,2-Dichloropropane ug/L 19.620 98 60-140
2-Chlorotoluene ug/L 20.920 105 60-140
4-Chlorotoluene ug/L 21.720 108 60-140
Benzene ug/L 21.720 109 60-140
Bromobenzene ug/L 21.120 105 60-140
Bromochloromethane ug/L 20.020 100 60-140
Bromodichloromethane ug/L 21.220 106 60-140
Bromoform ug/L 17.620 88 60-140
Bromomethane ug/L 14.720 73 60-140
Carbon tetrachloride ug/L 21.820 109 60-140
Chlorobenzene ug/L 21.720 108 60-140
Chloroethane ug/L 21.020 105 60-140
Chloroform ug/L 20.620 103 60-140
Chloromethane ug/L 19.420 97 60-140
cis-1,2-Dichloroethene ug/L 21.020 105 60-140
cis-1,3-Dichloropropene ug/L 21.220 106 60-140
Dibromochloromethane ug/L 21.620 108 60-140
Dibromomethane ug/L 22.120 111 60-140
Dichlorodifluoromethane ug/L 23.220 116 60-140
Diisopropyl ether ug/L 19.920 99 60-140
Ethanol ug/L 765800 96 60-140
Ethyl-tert-butyl ether ug/L 38.940 97 60-140
Ethylbenzene ug/L 21.320 107 60-140
Hexachloro-1,3-butadiene ug/L 20.420 102 60-140
Isopropylbenzene (Cumene)ug/L 22.120 111 60-140
m&p-Xylene ug/L 42.740 107 60-140
Methyl-tert-butyl ether ug/L 19.720 99 60-140
Methylene Chloride ug/L 19.420 97 60-140
n-Butylbenzene ug/L 21.920 109 60-140
n-Propylbenzene ug/L 21.220 106 60-140
Naphthalene ug/L 22.320 111 60-140
o-Xylene ug/L 21.520 108 60-140
sec-Butylbenzene ug/L 20.920 105 60-140
Styrene ug/L 22.020 110 60-140
tert-Amyl Alcohol ug/L 417400 104 60-140
tert-Amylmethyl ether ug/L 42.740 107 60-140
tert-Butyl Alcohol ug/L 194200 97 60-140
tert-Butyl Formate ug/L 150160 94 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4083698LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 17.620 88 60-140
Tetrachloroethene ug/L 21.520 107 60-140
Toluene ug/L 21.020 105 60-140
trans-1,2-Dichloroethene ug/L 21.820 109 60-140
trans-1,3-Dichloropropene ug/L 20.920 105 60-140
Trichloroethene ug/L 22.120 111 60-140
Trichlorofluoromethane ug/L 21.020 105 60-140
Vinyl chloride ug/L 17.720 88 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4083699MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677890002
4083700
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 125 60-140127 2 3020<0.091 25.0 25.4
1,1,1-Trichloroethane ug/L 20 126 60-140127 1 3020<0.11 25.2 25.5
1,1,2,2-Tetrachloroethane ug/L 20 121 60-140128 5 3020<0.074 24.3 25.5
1,1,2-Trichloroethane ug/L 20 122 60-140126 3 3020<0.096 24.3 25.2
1,1-Dichloroethane ug/L 20 126 60-140125 1 3020<0.056 25.2 25.0
1,1-Dichloroethene ug/L 20 137 60-140134 2 3020<0.079 27.5 26.9
1,1-Dichloropropene ug/L 20 136 60-140135 0 3020<0.066 27.1 27.0
1,2,3-Trichlorobenzene ug/L 20 117 60-140120 3 3020<0.12 23.4 24.0
1,2,3-Trichloropropane ug/L 20 114 60-140121 6 3020<0.17 22.9 24.2
1,2,4-Trichlorobenzene ug/L 20 117 60-140119 2 3020<0.16 23.3 23.9
1,2,4-Trimethylbenzene ug/L 20 123 60-140124 0 3020<0.031 24.7 24.7
1,2-Dibromo-3-
chloropropane ug/L 20 102 60-140114 12 3020<0.18 20.4 22.9
1,2-Dibromoethane (EDB)ug/L 20 121 60-140129 6 3020<0.15 24.3 25.9
1,2-Dichlorobenzene ug/L 20 126 60-140124 1 3020<0.094 25.1 24.8
1,2-Dichloroethane ug/L 20 123 60-140124 1 3020<0.11 24.6 24.9
1,2-Dichloropropane ug/L 20 127 60-140129 1 3020<0.14 25.4 25.7
1,3,5-Trimethylbenzene ug/L 20 124 60-140125 1 3020<0.071 24.8 25.0
1,3-Dichlorobenzene ug/L 20 124 60-140125 1 3020<0.098 24.7 24.9
1,3-Dichloropropane ug/L 20 121 60-140124 2 3020<0.085 24.2 24.8
1,4-Dichlorobenzene ug/L 20 119 60-140120 1 3020<0.090 23.8 24.0
2,2-Dichloropropane ug/L 20 125 60-140125 0 3020<0.12 24.9 24.9
2-Chlorotoluene ug/L 20 120 60-140121 1 3020<0.13 23.9 24.1
4-Chlorotoluene ug/L 20 123 60-140121 1 3020<0.096 24.7 24.3
Benzene ug/L 20 128 60-140126 1 3020<0.079 25.6 25.2
Bromobenzene ug/L 20 122 60-140122 0 3020<0.14 24.4 24.5
Bromochloromethane ug/L 20 115 60-140116 1 3020<0.094 22.9 23.3
Bromodichloromethane ug/L 20 121 60-140123 1 3020<0.17 24.2 24.5
Bromoform ug/L 20 96 60-140103 7 3020<0.20 19.2 20.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4083699MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677890002
4083700
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L 20 112 60-140116 3 3020<0.22 22.4 23.1
Carbon tetrachloride ug/L 20 132 60-140135 2 3020<0.17 26.4 27.0
Chlorobenzene ug/L 20 129 60-140126 3 3020<0.085 25.8 25.1
Chloroethane ug/L 20 125 60-140125 0 3020<0.17 25.0 25.1
Chloroform ug/L 20 124 60-140125 0 3020<0.069 24.9 24.9
Chloromethane ug/L 20 117 60-140117 0 3020<0.18 23.4 23.4
cis-1,2-Dichloroethene ug/L 20 125 60-140124 0 3020<0.11 25.0 24.9
cis-1,3-Dichloropropene ug/L 20 123 60-140123 0 3020<0.090 24.5 24.6
Dibromochloromethane ug/L 20 122 60-140126 3 3020<0.15 24.4 25.2
Dibromomethane ug/L 20 122 60-140130 6 3020<0.19 24.5 25.9
Dichlorodifluoromethane ug/L 20 139 60-140139 0 3020<0.12 27.9 27.7
Diisopropyl ether ug/L 20 117 60-140117 1 3020<0.072 23.5 23.3
Ethanol ug/L 800 97 60-140104 7 30800<5.0 776 833
Ethyl-tert-butyl ether ug/L 40 111 60-140113 2 3040<0.11 44.3 45.3
Ethylbenzene ug/L 20 127 60-140124 2 3020<0.081 25.4 24.8
Hexachloro-1,3-butadiene ug/L 20 120 60-140123 2 3020<0.35 24.1 24.5
Isopropylbenzene
(Cumene)ug/L 20 130 60-140130 0 3020<0.11 26.0 26.0
m&p-Xylene ug/L 40 125 60-140123 1 3040<0.094 50.0 49.3
Methyl-tert-butyl ether ug/L 20 110 60-140114 3 30200.47J 22.5 23.3
Methylene Chloride ug/L 20 110 60-140111 0 3020<1.9 22.2 22.3
n-Butylbenzene ug/L 20 127 60-140128 1 3020<0.066 25.4 25.5
n-Propylbenzene ug/L 20 124 60-140123 1 3020<0.10 24.8 24.6
Naphthalene ug/L 20 114 60-140121 6 3020<0.10 22.8 24.2
o-Xylene ug/L 20 126 60-140122 3 3020<0.14 25.1 24.4
sec-Butylbenzene ug/L 20 124 60-140125 1 3020<0.085 24.7 24.9
Styrene ug/L 20 125 60-140126 1 3020<0.14 25.0 25.2
tert-Amyl Alcohol ug/L 400 103 60-140111 7 30400<7.4 414 445
tert-Amylmethyl ether ug/L 40 118 60-140122 3 3040<0.12 47.3 48.8
tert-Butyl Alcohol ug/L 200 129 60-140138 7 30200<4.1 257 276
tert-Butyl Formate ug/L M11603060-14028 30160<0.30 47.7J 44.2J
tert-Butylbenzene ug/L 20 102 60-140103 1 3020<0.086 20.5 20.7
Tetrachloroethene ug/L 20 130 60-140125 4 3020<0.086 26.0 25.0
Toluene ug/L 20 123 60-140123 0 3020<0.090 24.5 24.7
trans-1,2-Dichloroethene ug/L 20 130 60-140131 1 3020<0.10 25.9 26.2
trans-1,3-Dichloropropene ug/L 20 120 60-140122 1 3020<0.13 24.1 24.4
Trichloroethene ug/L 20 129 60-140131 1 3020<0.17 25.9 26.2
Trichlorofluoromethane ug/L 20 127 60-140127 0 3020<0.14 25.4 25.4
Vinyl chloride ug/L 20 106 60-140109 2 3020<0.15 21.2 21.7
1,2-Dichloroethane-d4 (S)%93 70-13093
4-Bromofluorobenzene (S)%101 70-130101
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
788034
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92677890001, 92677890003, 92677890005, 92677890009, 92677890010, 92677890011, 92677890012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4085225
Associated Lab Samples:92677890001, 92677890003, 92677890005, 92677890009, 92677890010, 92677890011, 92677890012
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.091 0.50 07/20/23 11:590.091
1,1,1-Trichloroethane ug/L <0.11 0.50 07/20/23 11:590.11
1,1,2,2-Tetrachloroethane ug/L <0.074 0.50 07/20/23 11:590.074
1,1,2-Trichloroethane ug/L <0.096 0.50 07/20/23 11:590.096
1,1-Dichloroethane ug/L <0.056 0.50 07/20/23 11:590.056
1,1-Dichloroethene ug/L <0.079 0.50 07/20/23 11:590.079
1,1-Dichloropropene ug/L <0.066 0.50 07/20/23 11:590.066
1,2,3-Trichlorobenzene ug/L <0.12 2.0 07/20/23 11:590.12
1,2,3-Trichloropropane ug/L <0.17 0.50 07/20/23 11:590.17
1,2,4-Trichlorobenzene ug/L <0.16 2.0 07/20/23 11:590.16
1,2,4-Trimethylbenzene ug/L <0.031 0.50 07/20/23 11:590.031
1,2-Dibromo-3-chloropropane ug/L <0.18 1.0 07/20/23 11:590.18
1,2-Dibromoethane (EDB)ug/L <0.15 0.50 07/20/23 11:590.15
1,2-Dichlorobenzene ug/L <0.094 0.50 07/20/23 11:590.094
1,2-Dichloroethane ug/L <0.11 0.50 07/20/23 11:590.11
1,2-Dichloropropane ug/L <0.14 0.50 07/20/23 11:590.14
1,3,5-Trimethylbenzene ug/L <0.071 0.50 07/20/23 11:590.071
1,3-Dichlorobenzene ug/L <0.098 0.50 07/20/23 11:590.098
1,3-Dichloropropane ug/L <0.085 0.50 07/20/23 11:590.085
1,4-Dichlorobenzene ug/L <0.090 0.50 07/20/23 11:590.090
2,2-Dichloropropane ug/L <0.12 0.50 07/20/23 11:590.12
2-Chlorotoluene ug/L <0.13 0.50 07/20/23 11:590.13
4-Chlorotoluene ug/L <0.096 0.50 07/20/23 11:590.096
Benzene ug/L <0.079 0.50 07/20/23 11:590.079
Bromobenzene ug/L <0.14 0.50 07/20/23 11:590.14
Bromochloromethane ug/L <0.094 0.50 07/20/23 11:590.094
Bromodichloromethane ug/L <0.17 0.50 07/20/23 11:590.17
Bromoform ug/L <0.20 0.50 07/20/23 11:590.20
Bromomethane ug/L <0.22 5.0 07/20/23 11:590.22
Carbon tetrachloride ug/L <0.17 0.50 07/20/23 11:590.17
Chlorobenzene ug/L <0.085 0.50 07/20/23 11:590.085
Chloroethane ug/L <0.17 1.0 07/20/23 11:590.17
Chloroform ug/L <0.069 0.50 07/20/23 11:590.069
Chloromethane ug/L <0.18 1.0 07/20/23 11:590.18
cis-1,2-Dichloroethene ug/L <0.11 0.50 07/20/23 11:590.11
cis-1,3-Dichloropropene ug/L <0.090 0.50 07/20/23 11:590.090
Dibromochloromethane ug/L <0.15 0.50 07/20/23 11:590.15
Dibromomethane ug/L <0.19 0.50 07/20/23 11:590.19
Dichlorodifluoromethane ug/L <0.12 0.50 07/20/23 11:590.12
Diisopropyl ether ug/L <0.072 0.50 07/20/23 11:590.072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4085225
Associated Lab Samples:92677890001, 92677890003, 92677890005, 92677890009, 92677890010, 92677890011, 92677890012
Matrix:Water
AnalyzedMDL
Ethanol ug/L <5.0 200 07/20/23 11:595.0
Ethyl-tert-butyl ether ug/L <0.11 10.0 07/20/23 11:590.11
Ethylbenzene ug/L <0.081 0.50 07/20/23 11:590.081
Hexachloro-1,3-butadiene ug/L <0.35 2.0 07/20/23 11:590.35
Isopropylbenzene (Cumene)ug/L <0.11 0.50 07/20/23 11:590.11
m&p-Xylene ug/L <0.094 1.0 07/20/23 11:590.094
Methyl-tert-butyl ether ug/L <0.053 0.50 07/20/23 11:590.053
Methylene Chloride ug/L <1.9 2.0 07/20/23 11:591.9
n-Butylbenzene ug/L <0.066 0.50 07/20/23 11:590.066
n-Propylbenzene ug/L <0.10 0.50 07/20/23 11:590.10
Naphthalene ug/L <0.10 2.0 07/20/23 11:590.10
o-Xylene ug/L <0.14 0.50 07/20/23 11:590.14
sec-Butylbenzene ug/L <0.085 0.50 07/20/23 11:590.085
Styrene ug/L <0.14 0.50 07/20/23 11:590.14
tert-Amyl Alcohol ug/L <7.4 100 07/20/23 11:597.4
tert-Amylmethyl ether ug/L <0.12 10.0 07/20/23 11:590.12
tert-Butyl Alcohol ug/L <4.1 50.0 07/20/23 11:594.1
tert-Butyl Formate ug/L <0.30 50.0 07/20/23 11:590.30
tert-Butylbenzene ug/L <0.086 0.50 07/20/23 11:590.086
Tetrachloroethene ug/L <0.086 0.50 07/20/23 11:590.086
Toluene ug/L <0.090 0.50 07/20/23 11:590.090
trans-1,2-Dichloroethene ug/L <0.10 0.50 07/20/23 11:590.10
trans-1,3-Dichloropropene ug/L <0.13 0.50 07/20/23 11:590.13
Trichloroethene ug/L <0.17 0.50 07/20/23 11:590.17
Trichlorofluoromethane ug/L <0.14 1.0 07/20/23 11:590.14
Vinyl chloride ug/L <0.15 1.0 07/20/23 11:590.15
1,2-Dichloroethane-d4 (S)%92 70-130 07/20/23 11:59
4-Bromofluorobenzene (S)%97 70-130 07/20/23 11:59
Toluene-d8 (S)%107 70-130 07/20/23 11:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4085226LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.520 103 60-140
1,1,1-Trichloroethane ug/L 18.020 90 60-140
1,1,2,2-Tetrachloroethane ug/L 20.120 101 60-140
1,1,2-Trichloroethane ug/L 19.120 96 60-140
1,1-Dichloroethane ug/L 19.520 97 60-140
1,1-Dichloroethene ug/L 21.020 105 60-140
1,1-Dichloropropene ug/L 18.920 94 60-140
1,2,3-Trichlorobenzene ug/L 20.520 103 60-140
1,2,3-Trichloropropane ug/L 21.320 106 60-140
1,2,4-Trichlorobenzene ug/L 19.920 100 60-140
1,2,4-Trimethylbenzene ug/L 18.920 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4085226LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 18.020 90 60-140
1,2-Dibromoethane (EDB)ug/L 20.920 105 60-140
1,2-Dichlorobenzene ug/L 20.620 103 60-140
1,2-Dichloroethane ug/L 20.220 101 60-140
1,2-Dichloropropane ug/L 21.420 107 60-140
1,3,5-Trimethylbenzene ug/L 19.120 95 60-140
1,3-Dichlorobenzene ug/L 20.820 104 60-140
1,3-Dichloropropane ug/L 21.220 106 60-140
1,4-Dichlorobenzene ug/L 20.820 104 60-140
2,2-Dichloropropane ug/L 19.320 97 60-140
2-Chlorotoluene ug/L 19.120 96 60-140
4-Chlorotoluene ug/L 19.620 98 60-140
Benzene ug/L 21.020 105 60-140
Bromobenzene ug/L 19.920 100 60-140
Bromochloromethane ug/L 20.320 102 60-140
Bromodichloromethane ug/L 20.420 102 60-140
Bromoform ug/L 17.120 85 60-140
Bromomethane ug/L 16.420 82 60-140
Carbon tetrachloride ug/L 21.320 106 60-140
Chlorobenzene ug/L 20.920 105 60-140
Chloroethane ug/L 21.320 106 60-140
Chloroform ug/L 16.220 81 60-140
Chloromethane ug/L 20.920 104 60-140
cis-1,2-Dichloroethene ug/L 19.120 96 60-140
cis-1,3-Dichloropropene ug/L 19.820 99 60-140
Dibromochloromethane ug/L 19.120 96 60-140
Dibromomethane ug/L 20.620 103 60-140
Dichlorodifluoromethane ug/L 26.420 132 60-140
Diisopropyl ether ug/L 18.520 93 60-140
Ethanol ug/L 766800 96 60-140
Ethyl-tert-butyl ether ug/L 36.740 92 60-140
Ethylbenzene ug/L 20.220 101 60-140
Hexachloro-1,3-butadiene ug/L 19.620 98 60-140
Isopropylbenzene (Cumene)ug/L 20.220 101 60-140
m&p-Xylene ug/L 39.740 99 60-140
Methyl-tert-butyl ether ug/L 17.920 89 60-140
Methylene Chloride ug/L 21.320 106 60-140
n-Butylbenzene ug/L 19.320 97 60-140
n-Propylbenzene ug/L 19.120 96 60-140
Naphthalene ug/L 20.020 100 60-140
o-Xylene ug/L 19.720 99 60-140
sec-Butylbenzene ug/L 18.620 93 60-140
Styrene ug/L 19.920 99 60-140
tert-Amyl Alcohol ug/L 389400 97 60-140
tert-Amylmethyl ether ug/L 40.840 102 60-140
tert-Butyl Alcohol ug/L 166200 83 60-140
tert-Butyl Formate ug/L 144160 90 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4085226LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 15.420 77 60-140
Tetrachloroethene ug/L 21.520 108 60-140
Toluene ug/L 20.120 100 60-140
trans-1,2-Dichloroethene ug/L 20.420 102 60-140
trans-1,3-Dichloropropene ug/L 19.620 98 60-140
Trichloroethene ug/L 21.620 108 60-140
Trichlorofluoromethane ug/L 20.320 102 60-140
Vinyl chloride ug/L 17.320 86 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4085227MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677657002
4085228
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M120060-1400 3020ND<22.8 <22.8
1,1,1-Trichloroethane ug/L M120060-1400 3020ND<26.8 <26.8
1,1,2,2-Tetrachloroethane ug/L M120060-140125 3020ND<18.4 25.0J
1,1,2-Trichloroethane ug/L M120060-1400 3020ND<23.9 <23.9
1,1-Dichloroethane ug/L M1203360-14029 3020ND<14.0 <14.0
1,1-Dichloroethene ug/L M1204160-1400 3020ND<19.7 <19.7
1,1-Dichloropropene ug/L M120060-1400 3020ND<16.5 <16.5
1,2,3-Trichlorobenzene ug/L M12013360-1400 3020ND<30.2 <30.2
1,2,3-Trichloropropane ug/L M12017360-140165 3020ND<43.2 <43.2
1,2,4-Trichlorobenzene ug/L M1206160-1400 3020ND<39.0 <39.0
1,2,4-Trimethylbenzene ug/L M120478060-1404500 1 3020282037803720
1,2-Dibromo-3-
chloropropane ug/L M120060-1400 3020ND<44.8 <44.8
1,2-Dibromoethane (EDB)ug/L M120060-1400 3020ND<36.8 <36.8
1,2-Dichlorobenzene ug/L 20 112 60-14096 3020ND<23.5 <23.5
1,2-Dichloroethane ug/L M120060-1400 3020ND<26.5 <26.5
1,2-Dichloropropane ug/L M120060-1400 3020ND<34.0 <34.0
1,3,5-Trimethylbenzene ug/L M120102060-1401220 5 3020631836875
1,3-Dichlorobenzene ug/L M1208560-14037 3020ND<24.5 <24.5
1,3-Dichloropropane ug/L M120060-1400 3020ND<21.4 <21.4
1,4-Dichlorobenzene ug/L 20 100 60-14086 3020ND<22.4 <22.4
2,2-Dichloropropane ug/L M120060-1400 3020ND<30.5 <30.5
2-Chlorotoluene ug/L M120060-1400 3020ND<32.2 <32.2
4-Chlorotoluene ug/L 20 104 60-140107 3020ND<23.9 <23.9
Benzene ug/L M120215060-1401190 5 3020380042304040
Bromobenzene ug/L M120060-1400 3020ND<33.8 <33.8
Bromochloromethane ug/L M120060-1400 3020ND<23.6 <23.6
Bromodichloromethane ug/L M120060-1400 3020ND<42.5 <42.5
Bromoform ug/L M120060-1400 3020ND<49.2 <49.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677890
CK 3940
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4085227MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677657002
4085228
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L M120060-140138 3020ND<55.5 <55.5
Carbon tetrachloride ug/L M120060-1400 3020ND<42.2 <42.2
Chlorobenzene ug/L 20 75 60-14068 3020ND<21.2 <21.2
Chloroethane ug/L M120060-1400 3020ND<43.2 <43.2
Chloroform ug/L 20 112 60-140103 3020ND22.4J 20.7J
Chloromethane ug/L M120060-14090 3020ND<43.8 <43.8
cis-1,2-Dichloroethene ug/L M120060-1400 3020ND<27.8 <27.8
cis-1,3-Dichloropropene ug/L M120060-1400 3020ND<22.4 <22.4
Dibromochloromethane ug/L M120060-1400 3020ND<37.0 <37.0
Dibromomethane ug/L M120060-1400 3020ND<46.8 <46.8
Dichlorodifluoromethane ug/L M120060-1400 3020ND<30.8 <30.8
Diisopropyl ether ug/L M120-2 60-14010 1 3020221220222
Ethanol ug/L M1800060-1400 30800ND<1260 <1260
Ethyl-tert-butyl ether ug/L 40 65 60-14083 3040ND<28.0 33.3J
Ethylbenzene ug/L M120233060-1402700 2 3020377042404310
Hexachloro-1,3-butadiene ug/L M120060-140208 3020ND<87.8 <87.8
Isopropylbenzene
(Cumene)ug/L M12031360-140306 1 3020126188187
m&p-Xylene ug/L M140442060-1404490 0 3040154001720017200
Methyl-tert-butyl ether ug/L M1202760-14033 302079.9J 85.2J 86.5J
Methylene Chloride ug/L M120060-1400 3020ND<472 <472
n-Butylbenzene ug/L M12051560-140536 3020ND103J107J
n-Propylbenzene ug/L M12082660-140790 1 3020342508500
Naphthalene ug/L M12084360-140739 2 3020684852832
o-Xylene ug/L M120354060-1403010 1 3020764083508240
sec-Butylbenzene ug/L M12029960-140330 3020ND59.7J 66.0J
Styrene ug/L M120060-1400 3020ND<34.2 <34.2
tert-Amyl Alcohol ug/L M140028760-140271 30400ND<1860 <1860
tert-Amylmethyl ether ug/L M14030260-140304 3040ND121J122J
tert-Butyl Alcohol ug/L M12006660-14042 30200ND<1020 <1020
tert-Butyl Formate ug/L M11605860-14048 30160ND93.1J 77.1J
tert-Butylbenzene ug/L 20 95 60-140112 3020ND<21.4 22.4J
Tetrachloroethene ug/L M120060-1400 3020ND<21.4 <21.4
Toluene ug/L M120-4900 60-1405410 5 3020393003840040400
trans-1,2-Dichloroethene ug/L M120060-1400 3020ND<25.2 <25.2
trans-1,3-Dichloropropene ug/L M120060-1400 3020ND<33.0 <33.0
Trichloroethene ug/L M120060-1400 3020ND<42.8 <42.8
Trichlorofluoromethane ug/L M120060-1400 3020ND<36.0 <36.0
Vinyl chloride ug/L M120060-14081 3020ND<37.2 <37.2
1,2-Dichloroethane-d4 (S)%96 70-130100
4-Bromofluorobenzene (S)%93 70-13096
Toluene-d8 (S)%98 70-130105
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92677890
CK 3940
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Result may be biased high due to carryover from previously analyzed sample.C8
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92677890
CK 3940
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92677890001 788034MW-1A SM 6200B
92677890002 787755MW-3 SM 6200B
92677890003 788034MW-4 SM 6200B
92677890004 787755MW-6 SM 6200B
92677890005 788034MW-10 SM 6200B
92677890006 787755MW-11 SM 6200B
92677890007 787755MW-12 SM 6200B
92677890008 787755MW-13 SM 6200B
92677890009 788034MW-14 SM 6200B
92677890010 788034MW-15 SM 6200B
92677890011 788034MW-16 SM 6200B
92677890012 788034DW-1 SM 6200B
92677890013 787755DW-2 SM 6200B
92677890014 787755DW-3 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/25/2023 09:39 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 49
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