MO-29324_48487_CA_LSA_20230412

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
February 21, 2023

Mr. Jerren Rogers
NCDEQ-UST Section
Raleigh Regional Office
1628 Mail Service Center
Raleigh, NC 27699-1628

Re: Limited Site Assessment Report
Silver Express
5115 North Tryon Street
Charlotte, Mecklenburg County
North Carolina
Facility ID Number: 0-030632
Incident Number: 48487
GRI Project Number: 5413

Dear Mr. Rogers,

Please find enclosed the referenced report for the above referenced site.
If you have any questions, please contact Eric Eubanks at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Christopher Whittaker; Nisbet Oil Company, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Limited Site Assessment Report
Silver Express
5115 North Tryon Street
Charlotte, Mecklenburg County
North Carolina
Facility ID Number: 0-030632
Incident Number: 48487
GRI Project Number: 5413

Prepared for:

Christopher Whittaker
Nisbet Oil Company
1818 Baxter Street
Charlotte, North Carolina 28204

February 20, 2023

Joanna Alley, P.E.
Project Manager
Eric M. Eubanks, P.G.
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
i
EXECUTIVE SUMMARY
The Silver Express site is located at 5115 North Tryon Street in Charlotte, Mecklenburg County, North
Carolina. The property operates as a strip mall and includes a petroleum retail facility and convenience
store. The site is covered by concrete, asphalt, and grass. There are two 8,200-gallon and one 10,000-
gallon gasoline USTs currently in use at the site with three associated dispenser islands. The surrounding
properties are commercial and residential.

During annual compliance testing activities on May 25, 2021, a non-passing spill bucket was reported for
one of the 8,200-gallon gasoline UST. On April 7, 2022, GRI conducted a site check in the area of the non-
passing spill bucket for the 8,200-gallon gasoline UST and installed one Type II monitoring well.
Contaminant concentrations reported in the ground water sample collected from monitoring well MW-1
were above the MACs and/or GCLs. No free product was observed at the site. Based on this information,
an LSA was required.

A receptor survey was conducted on October 4, 2022. Four water supply wells were identified within a
1,000-foot radius of the site. Of those four water supplies, one potable water supply well (WSW-4) was
identified. No water supply wells were identified within a 250-foot radius of the site. Public water is
available to the subject site and to all surrounding properties. No surface water bodies were identified
within a 500-foot radius of the site.

On October 4, 2022, a ground water sample was collected from MW-1 as part of LSA activities. The
concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, TAME, n-butylbenzene,
sec-butylbenzene, isopropylbenzene, IPE, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, C5-C8 aliphatics, C9-C12 aliphatics and C9-C10 aromatics reported in the ground water
sample collected from monitoring well MW-1 were above the MACs. None of the reported contaminant
concentrations exceeded the GCLs. No free product was observed at the site. Based on the reported
ground water contaminant concentrations and the presence of a potable water supply well within a 1,000-
foot radius of the site, a Phase II Limited Site Assessment was required to be completed at the site.

On January 30, 2023, GRI returned to the site to install three additional monitoring wells to determine the
ground water flow direction. A ground water sample was collected from each well following installation.
The concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, TAA, TAME, TBA, n-
butylbenzene, 2-hexanone, isopropylbenzene, IPE, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, C5-C8 aromatics, C9-C12 aliphatics and/or C9-C10 aromatics reported in the ground
water samples collected from MW-2, MW-3 and MW-4 exceeded the MACs. The concentration of TBA
reported in the ground water sample collected from MW-3 exceeded the GCLs. Although the reported
concentration of 2-hexanone exceeded the MAC, this compound is not considered to be a petroleum
constituent. No free product was observed at the site.

Based on the presence of a potable water supply well within 1,000 feet of the site and contaminant

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
ii
concentrations exceeding the MACs, the site risk classification should be “High”, and a CSA should be
conducted at the site. Prior to conducting the CSA, an attempt to contact the owner of WSW-4 should be
considered to determine whether they would be willing to connect to municipal water.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1. RISK CHARACTERIZATION .....................................................................................................1
2. RECEPTOR INFORMATION .....................................................................................................4
3. SITE GEOLOGY AND HYDROGEOLOGY ...................................................................................5
4. SITE INVESTIGATION .............................................................................................................5
5. CONCLUSIONS AND RECOMMENDATIONS ............................................................................7
6. LIMITATIONS ........................................................................................................................8

FIGURES
Figure 1: Site Location Map
Figure 2A: Site Vicinity Map
Figure 2B: Zoning Map
Figure 3: Site Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Land Use Information
Table 4: Receptor Information
Table 5: Adjacent Property Owner Information
Table 6: Well Construction and Gauging Information
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: Returned Water Use Questionnaires
Appendix B: Mecklenburg County Property Cards
Appendix C: Well Permits, Well Construction Records and Subsurface Logs
Appendix D: State Correspondence
Appendix E: Historical Soil Quality Data
Appendix F: Laboratory Analytical Reports

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
1
1. RISK CHARACTERIZATION
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? NO

2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? YES

One potable water supply well (WSW-4) is located approximately 655 feet to the northwest of the
source area.

3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release?
NO

4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? NO

Public water is available to the site and surrounding properties.

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety, or the
environment?
NO

6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? NO
If YES, explain:

Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? N/A

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? NO

9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? NO

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Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
2
10. If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? N/A
If YES, describe.
11. Do the levels of ground water contamination for any contaminant exceed the gross contamination
levels established by the Department? YES

The concentration of TBA reported in the ground water sample collected from MW-3 exceeded
the GCL.

Part II – Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? NO
Explain:

The subject property is an active convenience store and petroleum retail facility.

2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? NO
Explain:

The subject property is an active convenience store and petroleum retail facility.

3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES
Explain:

The subject property is an active convenience store and petroleum retail facility.

4. Do children visit the property? YES
Explain:

The site is currently a convenience store and children would likely visit the property.

5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel or both)? NO
Explain:
The property is easily accessible to pedestrian and vehicular traffic.

6. Do pavement, buildings, or other structures cap the contaminated soil? YES

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
3
Explain:

The site is currently covered with concrete and asphalt.

If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site is expected to remain in operation as an active convenience store and petroleum retail
facility for the foreseeable future.
7. What is the zoning status of the property?
According to the City of Charlotte Official Zoning Map, the site is zoned B-2 (General Business).

8. Is the use of the property likely to change in the next 20 years? NO
Explain:

The subject property is currently an active convenience store and petroleum retail facility and
likely remain a convenience store for the foreseeable future.
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):

9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?

The closest primary residence is 4947 Fitzgerald Avenue, located approximately 560 feet
northwest of the UST basin.

10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?

Fresenius Kidney Care North Charlotte is located at 5220 North Tryon St, approximately 610 feet
east-southeast of the source area at the site.

11. What is the zoning status of properties in the surrounding area?

According to the City of Charlotte Official Zoning Map, the surrounding areas are zoned Business
(B-2 and B-2(CD)), Industrial (I-2), Institutional (INST(CD)), Residential (R-4, R-5, R-5(CD), R-12MF,
R-17MF, R-22MF and UR-2(CD)) and Transit-Oriented Development (TOD-R(CD), TOD-M(O) and
TOD-TR).

12. Briefly characterize the use and activities of the land in the surrounding area.

The area surrounding the site is a mixture of commercial and residential properties. Land use

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
4
information is included as Table 3. A zoning map is included as Figure 2B.

2. RECEPTOR INFORMATION
1. Water Supply Wells:
A receptor survey was conducted on October 4, 2022. Four water supply wells were identified
within a 1,000-foot radius of the site. Of those four water supply wells, one potable water supply
well (WSW-4) was identified. None of the water supply wells are located within a 250-foot radius
of the site. A Site Location Map is provided as Figure 1 and a Site Vicinity Map showing property
boundaries for the site and surrounding properties is included as Figure 2A. Water supply well
information is provided in Table 4. Returned water use questionnaires are included as Appendix
A.

2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply. Explain:
Municipal water is available to the site and the surrounding properties. Water lines run along the
public streets in the area. Public water is supplied by the City of Charlotte.

3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
A dry stream bed was identified approximately 750 feet north of the source area.

4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas in the vicinity of the source area. This
information must be shown on the USGS topographic map. Wellhead protection areas are defined
in 42 USC 300h-7(e).
On November 2, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify
wellhead protection areas in the vicinity of the subject site. The site is not located within a
wellhead protection area.

5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is not located in the Coastal Plain Physiographic Region.

6. Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. The water main
and other underground utilities run along North Tryon Street and Lambeth Drive, and several
underground utility lines were observed on the property.

7. Property Owners and Occupants:
The names and addresses of the owners of properties adjacent to the site are presented in Table

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
5
5. Property boundaries are shown on Figure 2A. Property cards for the adjacent property owners
are attached as Appendix B.
3. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is in the Charlotte Belt. The bedrock is
generally described as metagabbro, metadiorite and mafic plutonic-volcanic complexes. The soil samples
collected during well installation activities were generally described as brown, tan and red clayey silts to
sandy silts. The depths to ground water during the January 2023 gauging event ranged from 23.13 to 26.23
feet below TOC. Copies of the well permits, well construction records and subsurface logs have been
included as Appendix C. A Site Map is included as Figure 3. Well construction and gauging information is
presented in Table 6. Photographs of the newly installed monitoring wells are shown below:

4. SITE INVESTIGATION
On May 25, 2021, a non-passing spill bucket was reported for one of the 8,200-gallon gasoline USTs, and
on April 7, 2022, GRI conducted a site check at the subject site. Due to the presence of pea gravel, one
monitoring well was installed adjacent to the spill bucket to a depth of approximately 30 feet BGS. Three
soil samples (MW-1-5’, MW-1 (10’) and MW-1 (15’)) were collected at 5-foot intervals during the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
6
installation of monitoring well MW-1. The MTBE concentration reported in soil sample MW-1-15’
exceeded the MCC. A ground water sample was also collected from MW-1. The concentrations of
benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, n-butylbenzene, sec-butylbenzene,
isopropylbenzene, n-propylbenzene, TAA, TAME, TBA, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene,
C5-C8 aliphatics, C9-C12 aliphatics and C9-C10 aromatics reported in the ground water sample collected
from monitoring well MW-1 exceeded the MACs. The concentrations of benzene and TBA reported in the
ground water sample collected from MW-1 also exceeded the GCLs. Based on these results, a LSA was
recommended in the Site Check.

In accordance with the NORR dated June 8, 2022, LSA activities were conducted at the site on October 4,
2022 and monitoring well MW-1 was gauged, purged and sampled. A copy of the NORR is included as
Appendix D.

Based on the presence of a potable water supply well within 1,000 feet of the source area and analytical
results of MW-1, three additional monitoring well were required to be installed at the site in order to
determine the ground water flow direction. Monitoring wells MW-2 through MW-4 were installed at the
site on January 30, 2023, each to a total depth of 30 feet BGS with a screened interval of 15 feet. The
depth to ground water in the wells ranged from 23.13 to 26.23 feet below TOC. Ground water flow was
to the northwest with a horizontal gradient of approximately 0.09 feet per foot between monitoring wells
MW-2 and MW-1. A Water Table Surface Map is included as Figure 4. Gauging data from the January
2023 gauging event is included in Table 6. A summary of the current gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Groundwater
Elevation
(ft.)
MW-1 10 - 30 30 100.00 25.33 74.67
MW-2 15 - 30 30 99.83 23.13 76.70
MW-3 15 - 30 30 100.06 26.23 73.83
MW-4 15 - 30 30 99.95 25.95 74.00

1. Soil Sampling
On April 7, 2022, three soil samples (MW-1 (5’), MW-1 (10’) and MW-1 (15’)) were collected at 5-foot
intervals during the installation of monitoring well MW-1. The soil samples were submitted for
analysis of VOCs by EPA Method 8260D and/or VPH by the MADEP method. The soil-to-water MCC
was below the concentration of benzene reported in soil sample MW-1 (15’). Historical soil quality
data has been included as Appendix E.

2. Ground Water Sampling:
On January 30, 2023, all four Type II monitoring wells at the site (MW-1 through MW-4) were gauged,
purged and/or sampled in accordance with NCDEQ guidelines. The ground water samples collected
from MW-2, MW-3, and MW-4 were submitted for analyses of VOCs, lead and MADEP VPH. The

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
7
concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, TAA, TAME, TBA, n-
butylbenzene, 2-hexanone, isopropylbenzene, IPE, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, C5-C8 aromatics, C9-C12 aliphatics, and/or C9-C10 aromatics reported in the
ground water samples collected from MW-2, MW-3, and MW-4 exceeded the MACs. The
concentration of TBA reported in the ground water sample collected from MW-3 exceeded the GCLs.
Although the reported concentration of 2-hexanone exceeded the MAC, this compound is not
considered to be a petroleum constituent. No free product was observed at the site. A Ground Water
Quality Map is included as Figure 5. A summary of the ground water analytical data is included in
Table 7. A copy of the laboratory analytical report is included in Appendix F. A summary of the most
recent ground water sampling data is shown below:

Contaminant of
Concern
 Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene TBA Well
ID
MAC (µg/l) 1 600 600 500 20 6 10
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000 10,000
MW-1 3,880 45,000 4,810 24,780 5,960 1,230 <200
MW-2 122 3,690 1,300 10,600 168 312 1,390
MW-3 3,240 26,400 2,990 17,100 18,000 346 27,700
MW-4 4.55 J 42.2 11.9 58.1 2,150 10.8 1,030

2. Quality Control:
The ground water samples were immediately placed in laboratory-supplied containers after
collection, which were then placed in iced coolers. New disposable bailers were used to sample the
monitoring wells and new nitrile gloves were worn during ground water sampling. Samples were
logged using proper chain-of-custody procedures. The samples were transported to a North Carolina
certified laboratory for analysis.

5. CONCLUSIONS AND RECOMMENDATIONS
 The site is a strip mall that contains an active convenience store and petroleum retail facility. Land
use in the area consists of commercial and residential properties.
 A receptor survey was conducted on October 4, 2022. Four water supply wells were identified
within a 1,000-foot radius of the site. Of the four water supply wells, one potable well (WSW-4)
was identified. No water supply wells were identified within a 250-foot radius of the site. Public
water is available to the subject site and to all surrounding properties.
 No surface water bodies were identified within a 500-foot radius of the site.
 On January 30, 2023, three Type II monitoring wells (MW-2 through MW-4) were installed at the
site, each to a total depth of 30 feet BGS with a screened interval of 15 feet.
 Ground water flow was to the northwest with a horizontal gradient of approximately 0.09 feet
per foot between monitoring wells MW-2 and MW-1.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: February 20, 2023 Silver Express
Project Manager: Joanna Alley, P.E. GRI Project No. 5413
8
 On January 30, 2023 all four monitoring wells at the site (MW-1 through MW-4) were gauged,
purged and/or sampled. The concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE,
naphthalene, TAA, TAME, TBA, n-butylbenzene, 2-hexanone, isopropylbenzene, IPE, n-
propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, C5-C8 aromatics, C9-C12
aliphatics, and/or C9-C10 aromatics reported in the ground water samples collected from MW-2,
MW-3, and MW-4 exceeded the MACs. The concentration of TBA reported in the ground water
sample collected from MW-3 exceeded the GCLs. Although the reported concentration of 2-
hexanone exceeded the MAC, this compound is not considered to be a petroleum constituent. No
free product was observed at the site.
 Based on the presence of a potable water supply well within 1,000 feet of the site and
contaminant concentrations exceeding the MACs, the site risk classification should be “High”, and
a CSA should be conducted at the site. Prior to conducting the CSA, an attempt to contact the
owner of WSW-4 should be considered to determine whether they would be willing to connect
to municipal water.

6. LIMITATIONS
This report has been prepared for the exclusive use of Nisbet Oil Company for specific application to the
referenced site in Mecklenburg County, North Carolina. The assessment was conducted based on the
scope of work and level of effort specified by NCDEQ and with resources adequate only for that scope of
work. Our findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATION500 M2000 FTDate: 06/20/2020Location: 35.258973° N -80.780409° W Dad Figure 1 Site Location Map Silver Express5115 North Tryon Street Charlotte, Mecklenburg County, NC Incident No. 48487 GRI Project No. 5413
"J "J "J "J
SITE
08902405
089024040890240608902403WSW-4WSW-3WSW-2WSW-1
09101131
08911104
08911115
09101124 08
9
111
13
091011350891110308911114
091
011290891110208911101 N Tryon StEastway DrLambeth DrBennett StCurtiswood Dr Bi
ngham DrBurroughs StGal ax D r Northpark Mall DrHillsboro Av Or chi d Brid g e Rd
Fitzgerald Av W Eas
t
wa
y Dr
Edward St
Northchase Dr
Spri n gview Rd Masor LnPri
nc
e Charl
es StKentbrook DrOld Concord Rd
Pumpernickel Rd
J H Wheeler St
St Anne PlHi
gh
la
k
e Dr
M errick StHolloway St
FIGURE 2A: SITE VICINITY MAPSILVER EXPRESS5115 NORTH TRYON STREETCHARLOTTE, MECKLENBURG COUNTYNORTH CAROLINAINCIDENT NO. 48487GRI NO. 5413
PREPARED BY:GEOLOGICALRESOURCES, INC.SEPTEMBER 30, 2022
³
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
500-FOOT RADIUS
250-FOOT RADIUS
1
2
5
3
4
LEGEND
Dry Stream Bed
"J Water Supply Well
Streets
Railroads
Creeks_Streams
Lakes_Ponds
Adjacent Properties
Mecklenburg County Parcels
Land Use Code1
6
7
"J "J "J "J
SITE
WSW-4WSW-3WSW-2WSW-1 N Tryon StEastway DrLambeth DrBennett StCurtiswood Dr Bi
ngham DrBurroughs StGal ax D r Northpark Mall DrHillsboro Av Or chi d Brid g e Rd
Fitzgerald Av W Eas
t
wa
y Dr
Edward St
Northchase Dr
Spri n gview Rd Masor LnPri
nc
e Charl
es StKentbrook DrOld Concord Rd
Pumpernickel Rd
J H Wheeler St
St Anne PlHi
gh
la
k
e Dr
M errick StHolloway St

SEPTEMBER 30, 2022
³
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
500-FOOT RADIUS
250-FOOT RADIUS
1
2
5
3
4
LEGEND
"J Water Supply Well
Streets
Railroads
Creeks_Streams
Lakes_Ponds
ZONING -R-5
ZONING - R-4
ZONING - R-5(CD)
ZONING - INST(CD)
ZONING - TOD- R(CD)
ZONING - TOD-M(O)
ZONING - R-12MF
ZONING - R-22MF
ZONING - TOD-TR
ZONING - R-17MF
ZONING - UR-2(CD)
ZONING - B-2
ZONING - B-2(CD)
ZONING - I-2
Mecklenburg County Parcels
Land Use Code1
6
7
FIGURE 2B: ZONING MAPSILVER EXPRESS5115 NORTH TRYON STREETCHARLOTTE, MECKLENBURG COUNTYNORTH CAROLINAINCIDENT NO. 48487GRI NO. 5413
PREPARED BY:GEOLOGICAL RESOURCES, INC.

TABLES
Date: 04/28/22 Facility ID#: 0-030632
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner
1818 Baxter Street, Charlotte, NC 28204 704-458-8271
0-030632
Name of Owner or Operator Dates of Ownership / Operation
NISBET Oil Company 4/1/1989 to present
TABLE 1
UST OWNER/OPERATOR INFORMATION
SILVER EXPRESS (INCIDENT NO. 48487)
Address Telephone Number
Address Telephone Number
Unknown Unknown
0-030632
Name of Owner or Operator Dates of Ownership / Operation
Unknown 09/21/1988 to 4/1/1989
Page 1 of 1
Date: 04/28/22
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 10,000 09/21/1988 Single Wall Steel Unknown Single Wall FRP Current No
2 Gasoline NA 8,200 09/21/1988 Single Wall Steel Unknown Single Wall FRP Current Yes
3 Gasoline NA 8,200 09/21/1988 Single Wall Steel Unknown Single Wall FRP Current No
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
SILVER EXPRESS (INCIDENT NO. 48487)
Facility ID #: 0-030632
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Date: 10/06/2022 Facility ID # : 00-0-0000030632
Map ID No. Land Use Feature Zoning Description Address
Distance from
Source Area
(feet)
1 Kiddie Farms Child
Development Center B-2 Daycare
131 Bennett St.,
Charlotte, NC 28213 ~1,280
2 Iglesia de Dios Sinai Charlotte
NC I-2 Church
4901 C, N Tryon St.,
Charlotte, NC 28213 ~920
3 Aunt Alice Day Care Center Daycare
224 Bennett St.,
Charlotte, NC 28213 ~1,080
4 Smart Kids Lambeth Daycare
225 Lambeth Dr.,
Charlotte, NC 28213 ~545
5 Iglesia Universal TOD-TR Church
5000 N Tryon St.,
Charlotte, NC 28213 ~775
6 Linda's Daycare R-5 Daycare 311 Prince Charles St.,
Charlotte, NC 28213 ~1,455
7 Fresenius Kidney Care North
Charlotte I-2 Medical Facility
5220 N Tryon Street A,
Charlotte, NC 28213 ~610
n/a B-2 General Business n/a n/a
n/a B-2/(CD)
Neighborhood Buisness
(Conditional Zoning)n/a n/a
n/a UR-2/(CD)
Urban Residential
(Conditional Zoning)n/a n/a
n/a I-2 Industrial (General District) n/a n/a
n/a INST(CD) Institutional (Conditional Zoning) n/a n/a
n/a R-4 Single Family 4.0 Units Per Acre n/a n/a
n/a R-5 Single Family 5.0 Units Per Acre n/a n/a
n/a R-5(CD) Single Family (Conditional Zoning) n/a n/a
n/a R-12MF
Residential Multi-Family (Conditonal
Zoning) 12.0 units per acre n/a n/a
n/a R-17MF
Residential Multi-Family (Conditional
Zoning) 17.0 Units per acre n/a n/a
n/a R-22MF
Residential Multi-Family (Conditional
Zoning) 22.0 Units per acre n/a n/a
n/a TOD-R(CD)
Transit Oriented Development -
Residentially Oriented n/a n/a
n/a TOD-M(O)
Transit Oriented Development - Mixed-
Use Oriented n/a n/a
n/a TOD-TR
Transit Oriented Development - Transit
Transition n/a n/a
Note:
• Properties are keyed to Figure 2B.
TABLE 3
SILVER EXPRESS (INCIDENT NO. 48487)
LAND USE INFORMATION
R-12MF
Page 1 of 1
Facility ID # : 0-030632
Well ID. Parcel ID No. Well Owner Mailing Address Well Address
Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
1 8902402 Gloria Christine Washington
4920 Hillsboro Avenue
Charlotte, NC 28213
4909 Fitzgerald Avenue
Charlotte, NC 28213 Unknown Non-potable Yes Yes ~1,030 NW
2 8902403 Gloria Christine Washington
4920 Hillsboro Avenue
Charlotte, NC 28213
4915 Fitzgerald Avenue
Charlotte, NC 28213 Unknown Non-potable Yes *Vacant Lot ~985 NW
3 8902404 Jerry and Donna Ross
307 Riverside Drive
Mount Holly, NC 28120
4929 Fitzgerald Avenue
Charlotte, NC 28213 Unknown Non-potable Yes Yes ~895 NW
4 8902406 BDF1 Homes 2 LLC
3495 Piedmont Road NE, Bldg 11
Suite 300, Atlanta, GA 30305
4947 Fitzgerald Avenue
Charlotte, NC 28213 Active Potable Yes No ~655' NW
Notes:
• Receptors are shown on Figure 2A.
• n/a: not applicable.
TABLE 4
RECEPTOR INFORMATION
SILVER EXPRESS (INCIDENT NO. 48487)
Date: 10/07/2022
Page 1 of 1
Date: 10/06/2022 Facility ID #: 0-030632
Parcel ID Parcel Address Property Owner Name Mailing Address
08911104 5115 N Tryon St.
Charlotte, NC 28213 Margaret Ann Wallace 5115 N Tryon St., Suite C
Charlotte, NC 28213
08911113 5135 N Tryon St.
Charlotte, NC 28213
Ruth G. Dellinger and
Chesley Y. Dellinger, Jr.
6221 Woodbridge Rd.
Charlotte, NC 28227
08911115 220 Lambeth Dr.
Charlotte, NC 28213 Kennedy Properties, LLC P.O. Box 33324
Charlotte, NC 28233
08911114 210 Lambeth Dr.
Charlotte, NC 28213 Day Care Properties, LLC 1014 Maxwell Mill Rd.
Fort Mill, SC 29708
08911101 130 Lambeth Dr.
Charlotte, NC 28213
Estelle W. Fuller and
Arnold R. Fuller Sr.
4830 Carnbrook Pl.
Charlotte, NC 28212
08911102 122 Lambeth Dr.
Charlotte, NC 28213 Zeeshawn, Inc.1203 E. Sugar Creek Rd.
Charlotte, NC 28205
08911103 5101 N Tryon St.
Charlotte, NC 28213 Margaret Ann Wallace 5115 N Tryon St., Suite C
Charlotte, NC 28213
09101124 5038 and 5100 N Tryon St.
Charlotte, NC 28213 Sary Enterprises, LLC 1516 Glenn Valley Dr.
Matthews, NC 28105
09101129 5108 N Tryon St.
Charlotte, NC 28213
09101131 5130 N Tryon St.
Charlotte, NC 28213
09101135 5136 N Tryon St.
Charlotte, NC 28213
Corporate Property Associates &
Auto Zone, Inc.
P.O. Box 2198
Memphis, TN 38101
Note:
• Properties are keyed to Figure 2A.
TABLE 5
SILVER EXPRESS (INCIDENT NO. 48487)
ADJACENT PROPERTY INFORMATION
32 West 21st St.
Huntington Station, NY 11746La Placita
Page 1 of 1
Date: 02/01/23
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
04/09/22 24.05 ---75.95
10/04/22 26.48 ---73.52
01/30/23 25.33 ---74.67
MW-2 01/30/23 01/30/23 15 15 - 30 30 99.83 23.13 ---76.70
MW-3 01/30/23 01/30/23 15 15 - 30 30 100.06 26.23 ---73.83
MW-4 01/30/23 01/30/23 15 15 - 30 30 99.95 25.95 ---74.00
Notes:
• Elevation relative to mean sea level.
• ft BGS : feet below ground surface.
• NM : Not measured.
TABLE 6
WELL CONSTRUCTION AND GAUGING INFORMATION
SILVER EXPRESS (INCIDENT NO. 48487)
Facility ID # : 0-030632
3010 - 301004/07/22MW-1 100.00
Page 1 of 1
Date: 02/15/23
EPA 504.1 SW846
6010D
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 70 70 40 70 70 70 400 400 0.02 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 128,000 10,000 5,900 8,800 40,000 30,500 70,000 26,100 28,500 24,100 50 15,000 NE NE NE
10/04/22 3,880 45,000 4,810 24,780 5,960 1,230 <200 1,070 <200 354 218 NA 582 81.8 2,200 4,820 3,240 NR NR 75,000 63,700 25,300
MW-2 01/30/23 122 3,690 1,300 10,600 168 312 1,330 7.96 J 1,390 97.4 51.2 <3.80 115 <5.00 375 2,610 778 NR <10.0 2,500 11,700 6,930
MW-3 01/30/23 3,240 26,400 2,990 17,100 18,000 346 13,700 1,920 27,700 16.6 9.28 128 89.6 121 216 2,210 467 NR <10.0 14,000 11,400 5,370
MW-4 01/30/23 4.55 J 42.2 11.9 58.1 2,150 10.8 150 128 1,030 <1.80 <2.00 <3.80 <1.80 21.5 2.59 J 14.2 9.19 NR <10.0 878 J <51.6 165
10/04/22 <0.13 <0.13 <0.13 NA <0.13 <0.13 NR NR NR <0.13 <0.13 NA <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR
01/30/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NR NR <0.180 <0.200 <0.380 <0.180 <0.500 <0.190 <0.190 <0.180 NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the reported concentrations were above the MAC.
• J: Estimated value.
• E: indicated value exceeds calibration range
• NE: Not established.
• NA: Not Analyzed.
• NR: Not requested.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
EPA 6200B
Trip Blank
TABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
SILVER EXPRESS (INCIDENT NO. 48487)Facility ID # : 0-030632
MADEP VPH
C5-C8 Aliphatics1,2-Dibromoethane(EDB)LeadC9-C10 Aromatics1,2,4-Trimethylbenzene2-Hexanonen-PropylbenzeneDi-isopropyl etherIsopropylbenzeneAnalytical Method
→BenzeneTolueneEthylbenzeneTotal Xylenestert-Butyl alcohol(TBA)tert-Amyl methyl ether (TAME)Methyl-tert-butyl ether(MTBE)NaphthaleneMW-1
Contaminant of Concern
→sec-Butylbenzenen-Butylbenzenetert-Amyl alcohol(TAA)MAC (μg/l)
GCL (μg/l)C9-C12 Aliphatics1,3,5-TrimethylbenzenePage 1 of 1

APPENDICES

APPENDIX A
Returned Water Use Questionnaires
5413 Received OCT 19 2022

APPENDIX B
Mecklenburg County Property Cards
MECKLENBURG COUNTY, North Carolina
POLARIS 3G PARCEL OWNERSHIP AND GIS SUMMARY
Date Printed: 11/01/2022
Identity
Parcel ID GIS ID
09101135 09101135
Ownership
Owner Name Mailing Address
ATTN: DEPT 8088 PO BOX 2198
MEMPHIS TN 38101
CORPORATE PROPERTY
ASSOCIATES % AUTO ZONE
INC
PO BOX 2198
MEMPHIS TN 38101
Property Characteristics
Legal desc NA
Land Area 0.57 AC
Fire District CITY OF CHARLOTTE
Special District
Account Type NON-NC CORP
Municipality CHARLOTTE
Property Use COMMERCIAL
Deed Reference(s) and Sale Price
Deed Sale Date Sale Price
11000-793 12/30/1999 $0.00
Site Location
ETJ Area Charlotte
Charlotte Historic District No
Charlotte 6/30/2011 Annexation Area No
Census Tract #53.06
Zoning
Contact appropriate Planning Department or see Map.
Water Quality Buffer
Parcel Inside Water Quality Buffer No
Post Construction District
Jurisdiction Charlotte
District Central Catawba
FEMA and Community Floodplain
FEMA Panel#3710456500K
FEMA Panel Date 02/19/2014
FEMA Flood Zone OUT:VIEW FEMA FLOODPLAIN TO
VERIFY
Community Flood
Zone
OUT:VIEW COMMUNITY FLOODPLAIN
TO VERIFY
Stream Watershed Districts
Stream Watershed Name UPPER LITTLE SUGAR
Situs Addresses Tied to Parcel
5136 N TRYON ST CHARLOTTE
04/09/2014 from Mecklenburg County
This map or report is prepared for the inventory of real property within Mecklenburg County and is compiled from recorded deeds, plats, tax maps,
surveys, planimetric maps, and other public records and data. Users of this map or report are hereby notified that the aforementioned public primary
information sources should be consulted for verification. Mecklenburg County and its mapping contractors assume no legal responsibility for the
information contained herein.
Page 1/1

APPENDIX C
Well Permits, Well Construction Records and Subsurface Logs
SIPForm–revised2/15/11

MecklenburgCountyHealthDepartmentGroundwater&WastewaterServices
700N.TryonSt.,Suite211Charlotte,NC28202Phone:[phone]
Fax:[phone]http://groundwater.charmeck.org
PermitIssuanceDate:_______________
PermitNumber:____________________

SUBSURFACE INVESTIGATION PERMIT
I. Well Owner Information

Name:___________________________________
Attn:_____________________________________
Phone#:_____________________
Address1:________________________________
Address2:________________________________
City:__________________________State:_______Zip:_____________
II.Agent Information(if applicable)

Name:___________________________________
Attn:_____________________________________
Phone#:_____________________
Address1:________________________________
Address2:________________________________
City:__________________________State:_______Zip:_____________

III. Site Information

SiteName;________________________________
ParcelIDNumber:_____________________
Address:________________________________
City:__________________________State:_______Zip:_____________

General Conditions of This Permit:
•ThispermitshallbeVALIDforaperiodnottoexceedtwelve(12)monthsfromthedateofissuance.
•ThispermitisVALIDforthesitespecifiedabove and mustbeon-siteduringthecourseoftheinvestigationandmadeavailabletoaDepartmentrepresentativeuponrequest.
•ANorthCarolinaCertifiedWellContratormustperformanywellcontractoractivitiesassociatedwiththispermit.
•AllwellsshallbeconstructedandabandonedtothestandardsofChapterVI,SectionVandSectionVIoftheMecklenburgCountyGroundwaterWellRegulations.
•Alltemporarywells,includingthoseinstalledusingDirectPushTechnology,mustbeabandoned
tothestandardsofChapterVI,SectionVIoftheMecklenburgCountyGroundwaterWellRegulations.
•RegistrationinformationforallwellsmustbesubmittedtotheDepartmentwithinthirty(30)daysofwellcompletion.Ifwatersamplesarecollected,itisrecommendedthatthewellNOTberegistereduntilthe
analyticalresultsarereceived.
28208
3205 Freedom Dr.
[phone]

North Carolina Department of Environmental Quality | Division of Water Resources
Mooresville Regional Office | 601 East Center Avenue, Suite 301 | Mooresville, NC 28115
704.663.1699
December 29, 2022

Mr. Christopher Whittaker (via email)
Nisbet Oil Company
1818 Baxter Street
Charlotte, NC 28235

RE: Monitoring Well Construction Permit
Silver Express
Permit # WM0301254
5115 N. Tryon Street, Charlotte
Mecklenburg County

Dear Mr. Whittaker,

In accordance with your completed application received on December 28, 2022, we are forwarding herewith
Monitoring Well Construction Permit Numbered WM0301254 and issued for the construction of four (4)
monitoring wells located near the subject site in Charlotte, Mecklenburg County.

This Permit will be effective for one year from the date of issuance and shall be subject to the conditions and
limitations as specified therein.

Should you have any questions, please contact Edward Watson at [phone], or by email at
[e-mail].

Sincerely,

Andrew H. Pitner, P.G. Assistant Regional Supervisor
Mooresville Regional Office
Water Quality Regional Operations Section
Division of Water Resources

CC: WQROS, Central Office (via Laserfiche)
Joanna Alley, Geological Resources, Inc. (via email)

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES
PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL
In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other applicable Laws,
Rules and Regulations.
PERMISSION IS HEREBY GRANTED TO
Nisbet Oil Company (Geological Resources, Inc. as Agent)

FOR THE CONSTRUCTION OF A MONITOR WELL SYSTEM consisting of four (4) monitoring wells owned by Nisbet Oil
Company at the subject site located along North Tryon Street., Charlotte, Mecklenburg County. This Permit is issued in
accordance with the application received on December 28, 2022, in conformity with specifications and supporting data, all
of which are filed with the Department of Environmental Quality and are considered integral parts of this Permit.
This Permit is for well construction only and does not waive any provision or requirement of any other applicable law or
regulation. Construction of any well under this Permit shall be in strict compliance with the North Carolina Well Construction
Regulations and Standards (15A NCAC 02C .0100), and other State and Local Laws and regulations pertaining to well
construction.

If any requirements or limitations specified in this Permit are unacceptable, you have a right to an adjudicatory hearing upon
written request within 30 days of receipt of this Permit. The request must be in the form of a written petition conforming to
Chapter 150B of the North Carolina General Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service
Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding.
This Permit will be effective for one year from the date of its issuance and shall be subject to other specified conditions,
limitations, or exceptions as follows:

1. Issuance of this Permit does not obligate reimbursement from State trust funds, if these wells are being installed as
part of an investigation for contamination from an underground storage tank or dry cleaner incident.
2. Issuance of this Permit does not supersede any other agreement, permit, or requirement issued by another agency.
3. The well(s) shall be located and constructed as shown on the attachments submitted as part of the Permit application.
4. Each well shall have a Well Contractor Identification Plate in accordance with 15A NCAC 02C .0108(o).
5. Well construction records (GW-1) for each well shall be submitted to the Division of Water Resources’ Information
Processing Unit within 30 days of the well completion.
6. When the well is discontinued or abandoned, it shall be abandoned in accordance with 15A NCAC 02C .0113 and a
well abandonment record (GW-30) shall be submitted to the Division of Water Resources’ Information Processing
Unit within 30 days of the well abandonment.
7. If the well penetrates any water-bearing zone that contains contaminated waters, the upper three feet of the well
shall be grouted within one day after the casing is set or the well abandoned.
8. Temporary wells must be permanently abandoned or converted to a permanent well within seven days (168 hours)
of completion of drilling the borehole.
9. Adequate permits shall be obtained from Mecklenburg County Groundwater and Wastewater Services.

Permit issued the 29th day of December 2022

FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

_______________________________________________
Andrew H. Pitner, P.G., Assistant Regional Supervisor
Division of Water Resources
By Authority of the Environmental Management Commission
Permit No. # WM0301254
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Photo 1: Preclearing Photo 2: Completion
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-2
6"
30'
Well installed at completion
0.0 0.5 asphalt
0.5 6.0 sandy SILT tan/red Dry None
6.0 19.0 clayey SILT red Dry None
19.0 24.0 sandy SILT tan/red Moist Present
24.0 30.0 sandy SILT red/brown Wet Present

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM -MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-2
6"23.13
14 30
12 14
0 12
0 0 0
0 15 2
15 30 2
12
14
30
15
30
WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3.WellUse(checkwelluse):WaterSupplyWell:□Agricultural□Municipal/Public□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)□Irrigation
Non-WaterSupplyWell:□Monitoring□Recovery
InjectionWell:□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)
4.DateWell(s)Completed:____________WellID#______________________5a.WellLocation:
Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip
CountyParcelIdentificationNo.(PIN)5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:(ifwellfield,onelat/longissufficient)N W
6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”
11.Boreholediameter:(in.)12.Wellconstructionmethod: (i.e.auger,rotary,cable,directpush,etc.)FORWATERSUPPLYWELLSONLY:13a.Yield(gpm) Methodoftest:13b.Disinfectiontype:Amount:

14.WATERZONESFROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREENFROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:
SignatureofCertifiedWellContractorDate
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwellconstructiondetails.Youmayalsoattachadditionalpagesifnecessary.SUBMITTALINSTUCTIONS24a.ForAllWells:Submitthis formwithin30daysofcompletionofwellconstructiontothefollowing:DivisionofWaterResources,InformationProcessingUnit,1617MailServiceCenter,Raleigh,NC27699-161724b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30daysofcompletion ofwellconstructiontothefollowing:DivisionofWaterResources,UndergroundInjectionControlProgram,1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submit one copyof this form within30days ofcompletionofwellconstructiontothecountyhealthdepartmentofthecountywhereconstructed.
ForInternalUseONLY:
_______________
Matt Steele
4548A
Geological Resources, Inc.
WM0301254
01/30/2023 MW-2
Silver Express 00-0-0000030632
5115 North Tryon Street, Charlotte 28213
Mecklenburg 08911104
35.25855115 80.78046020
1
30
23.13
6"
Solid Stem Auger
23.13 30 sandy SILT
0 0 0
0 15 2 Sch 40 PVC
15 30 2 0.010 Sch 40 PVC
0 12 grout pour
12 14 bentonite pour
14 30 #2 Sand Pour
0.0 0.5 asphalt
0.5 6.0 sandy SILT
6.0 19.0 clayey SILT
19.0 24.0 sandy SILT
24.0 30.0 sandy SILT
01/30/2023
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Photo 1: Preclearing Photo 2: Completion
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-3
6"
30'
Well installed at completion
0.0 0.5 asphalt
0.5 7.0 clayey SILT red Dry None
7.0 18.0 silty CLAY red/brown Dry None
18.0 25.0 silty CLAY red Moist Present
25.0 30.0 silty CLAY brown/red Wet Present

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM -MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-3
6"26.23
14 30
12 14
0 12
0 15 2
15 30 2
12
14
30
15
30
WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3.WellUse(checkwelluse):WaterSupplyWell:□Agricultural□Municipal/Public□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)□Irrigation
Non-WaterSupplyWell:□Monitoring□Recovery
InjectionWell:□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)
4.DateWell(s)Completed:____________WellID#______________________5a.WellLocation:
Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip
CountyParcelIdentificationNo.(PIN)5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:(ifwellfield,onelat/longissufficient)N W
6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”
11.Boreholediameter:(in.)12.Wellconstructionmethod: (i.e.auger,rotary,cable,directpush,etc.)FORWATERSUPPLYWELLSONLY:13a.Yield(gpm) Methodoftest:13b.Disinfectiontype:Amount:

14.WATERZONESFROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREENFROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:
SignatureofCertifiedWellContractorDate
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwellconstructiondetails.Youmayalsoattachadditionalpagesifnecessary.SUBMITTALINSTUCTIONS24a.ForAllWells:Submitthis formwithin30daysofcompletionofwellconstructiontothefollowing:DivisionofWaterResources,InformationProcessingUnit,1617MailServiceCenter,Raleigh,NC27699-161724b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30daysofcompletion ofwellconstructiontothefollowing:DivisionofWaterResources,UndergroundInjectionControlProgram,1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submit one copyof this form within30days ofcompletionofwellconstructiontothecountyhealthdepartmentofthecountywhereconstructed.
ForInternalUseONLY:
_______________
Matt Steele
4548A
Geological Resources, Inc.
WM0301254
01/30/2023 MW-3
Silver Express 00-0-0000030632
5115 North Tryon Street, Charlotte 28213
Mecklenburg 08911104
35.25854594 80.78058897
1
30
26.23
6"
Solid Stem Auger
26.23 30 silty CLAY
0 15 2 Sch 40 PVC
15 30 2 0.010 Sch 40 PVC
0 12 grout pour
12 14 bentonite pour
14 30 #2 Sand Pour
0.0 0.5 asphalt
0.5 7.0 clayey SILT
7.0 18.0 silty CLAY
18.0 25.0 silty CLAY
25.0 30.0 silty CLAY
01/30/2023
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Photo 1: Preclearing Photo 2: Completion
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-4
6"
30'
Well installed at completion
0.0 0.5 asphalt
0.5 9.0 clayey SILT tan/red Dry None
9.0 20.0 clayey SILT red Dry None
20.0 26.0 clayey SILT red Moist Present
26.0 30.0 sandy SILT tan/red Wet Present

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM -MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Silver Express
5413
01/30/2023
Kyle Perry
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548A
MW-4
6"25.95
14 30
12 14
0 12
0 0 0
0 15 2
15 30 2
12
14
30
15
30
WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3.WellUse(checkwelluse):WaterSupplyWell:□Agricultural□Municipal/Public□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)□Irrigation
Non-WaterSupplyWell:□Monitoring□Recovery
InjectionWell:□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)
4.DateWell(s)Completed:____________WellID#______________________5a.WellLocation:
Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip
CountyParcelIdentificationNo.(PIN)5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:(ifwellfield,onelat/longissufficient)N W
6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”
11.Boreholediameter:(in.)12.Wellconstructionmethod: (i.e.auger,rotary,cable,directpush,etc.)FORWATERSUPPLYWELLSONLY:13a.Yield(gpm) Methodoftest:13b.Disinfectiontype:Amount:

14.WATERZONESFROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREENFROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:
SignatureofCertifiedWellContractorDate
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwellconstructiondetails.Youmayalsoattachadditionalpagesifnecessary.SUBMITTALINSTUCTIONS24a.ForAllWells:Submitthis formwithin30daysofcompletionofwellconstructiontothefollowing:DivisionofWaterResources,InformationProcessingUnit,1617MailServiceCenter,Raleigh,NC27699-161724b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30daysofcompletion ofwellconstructiontothefollowing:DivisionofWaterResources,UndergroundInjectionControlProgram,1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submit one copyof this form within30days ofcompletionofwellconstructiontothecountyhealthdepartmentofthecountywhereconstructed.
ForInternalUseONLY:
_______________
Matt Steele
4548A
Geological Resources, Inc.
WM0301254
01/30/2023 MW-4
Silver Express 00-0-0000030632
5115 North Tryon Street, Charlotte 28213
Mecklenburg 08911104
35.25865205 80.78049331
1
30
25.95
6"
Solid Stem Auger
0 0 0
0 15 2 Sch 40 PVC
15 30 2 0.010 Sch 40 PVC
0 12 grout pour
12 14 bentonite pour
14 30 #2 Sand Pour
0.0 0.5 asphalt
0.5 9.0 clayey SILT
9.0 20.0 clayey SILT
20.0 26.0 clayey SILT
26.0 30.0 sandy SILT
01/30/2023

APPENDIX D
State Correspondence

June 8, 2022

Nisbet Oil Company
1818 Baxter Street
Charlotte, North Carolina 28204
Attention: Christopher Whitaker

Re: Notice of Regulatory Requirements
15A NCAC 2L .0405
Risk-based Assessment and Corrective
Action for Petroleum Underground Storage
Tanks

Silver Express
5115 N Tryon St
Charlotte, NC
Incident Number: 48487

Mr. Whitaker:

The Site Check Report received by the UST Section, Division of Waste Management, Mooresville Regional Office
on May 16, 2022, confirms a release or discharge from a petroleum underground storage tank (UST) system at the
above-referenced location. The report indicates that soil contamination exceeds or equals the 10 mg/kg total petroleum
hydrocarbons (TPH) screening limit (or exceeds the lower of the residential or soil-to-groundwater maximum soil
contaminant `concentrations (MSCCs) established in Title 15A NCAC 2L .0411) and/or that groundwater
contamination exceeds the standards or interim standards established in Title 15A NCAC 2L.0202.

Therefore, the responsible party must comply with the assessment and reporting requirements of Title 15A NCAC 2L
.0405, which includes the preparation and submittal of a Limited Site Assessment (LSA) Report, in accordance with
the rule and the most recent version of the Guidelines for Assessment and Corrective Action for UST Releases, within
120 days of discovery of the release. The Limited Site Assessment (LSA) report outline and requirements can be
found online at: http://portal.ncdenr.org/web/wm/ust/guidance; the LSA investigation and report must follow these
specifications.

Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer, certified by the
State of North Carolina, is required to prepare and certify all reports submitted to the Department in accordance with
Title 15A NCAC 2L .0103(e), and 2L .0111(b).

Please note that before you sell, transfer, or request a “No Further Action” determination for a property that has not
been remediated to below “unrestricted use” standards, you must file a Notice of Residual Petroleum ("Notice") with
the Register of Deeds in the county where the property is located (NCGS 143B-279.9 and 143B-279.11).
5413 Received JUN 08 2022

Failure to comply with the State's rules in the manner and time specified may result in the assessment of civil penalties
and/or the use of other enforcement mechanisms.

If you have any questions regarding trust fund eligibility or reimbursement from the Commercial or Noncommercial
Leaking Petroleum Underground Storage Tank Cleanup Funds, please contact the UST Section Trust Fund Branch at
[phone]. If you have any questions regarding the actions that must be taken or the rules mentioned in this
letter, please contact me at the address or telephone number listed below.

Sincerely,

Daniel Bowser, PG
Hydrogeologist
UST Section, Division of Waste Management, NCDEQ
Mooresville Regional Office
[phone]

cc via email: Samuel McKay, PG, GRI
Shawna Caldwell, LUESA- Mecklenburg County Health Department

APPENDIX E
Historical Soil Quality Data
Sample ID Date Collected
(mm/dd/yy)
50 100
SB-1B (3') 06/17/2020 <0.7 0.6
RAL (mg/kg)
Contaminant of Concern Æ
TPH-GROTPH-DRO
Date: 06/23/20
5030/
8015D
3550/
8015C
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHDiesel-Range TPHBenzeneTolueneEthylbenzeneTotal Xylenes50 100 NE NE NE NE
NE NE 0.0056 4.3 4.9 4.6
NE NE 18 1,200 1,560 3,129
SB-1B 06/17/20 3 <0.7 0.6 NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the soil-to-water MCCs were below the reported concentrations.
• Concentrations in italic type indicate the residential SCLs were below the reported concentrations.
• NE: Not Established
• NR: Not Requested.
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
Analytical Method EPA Method 8260B
Facility ID #: 0-030632
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
SILVER EXPRESS (INCIDENT NO. N/A)
Page 1 of 1

APPENDIX F
Laboratory Analytical Reports
10/24/22
Technical Report for
GRI (Geological Resources Inc.)
Silver Express; 5115A N Tryon St, Charlotte, NC
5413
SGS Job Number: FA99528
Sampling Date: 10/04/22
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: Sam McKay
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 10/24/22
e-Hardcopy 2.0
Automated Report
32
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 32
FA99528
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA99528-1: MW-1 ........................................................................................................6
3.2: FA99528-2: TRIP BLANK ...........................................................................................10
Section 4: Misc. Forms ............................................................................................................12
4.1: Chain of Custody ...........................................................................................................13
Section 5: MS Volatiles - QC Data Summaries .....................................................................16
5.1: Method Blank Summary ................................................................................................17
5.2: Blank Spike Summary ...................................................................................................21
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................25
Section 6: GC Volatiles - QC Data (SGS Scott, LA) .............................................................29
6.1: Method Blank Summary ................................................................................................30
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................31
6.3: Duplicate Summary .......................................................................................................32 1234562 of 32
FA99528
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA99528
Silver Express; 5115A N Tryon St, Charlotte, NC
Project No: 5413
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA99528-1 10/04/22 14:22 JA 10/06/22 AQ Ground Water MW-1
FA99528-2 10/04/22 00:00 JA 10/06/22 AQ Trip Blank Water TRIP BLANK
3 of 32
FA995281
Summary of Hits Page 1 of 1
Job Number:FA99528
Account:GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Collected:10/04/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA99528-1 MW-1
Benzene 3980 50 13 ug/l SM 6200B
n-Butylbenzene 354 50 13 ug/l SM 6200B
sec-Butylbenzene 218 50 13 ug/l SM 6200B
Di-Isopropyl Ether 81.8 50 13 ug/l SM 6200B
Ethylbenzene a 4810 500 130 ug/l SM 6200B
Isopropylbenzene 582 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether a 5960 500 130 ug/l SM 6200B
Naphthalene 1670 50 13 ug/l SM 6200B
n-Propylbenzene 2200 50 13 ug/l SM 6200B
Tert-Amyl Methyl Ether 1070 100 20 ug/l SM 6200B
Toluene 40900 E 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene a 4820 500 130 ug/l SM 6200B
1,3,5-Trimethylbenzene 3240 50 13 ug/l SM 6200B
m,p-Xylene a 16100 1000 130 ug/l SM 6200B
o-Xylene a 8680 500 130 ug/l SM 6200B
Benzene b 3880 1000 28 ug/l MADEP VPH REV 2.1
Ethylbenzene b 6500 1000 35 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether b 8850 1000 27 ug/l MADEP VPH REV 2.1
Naphthalene b 1230 1000 82 ug/l MADEP VPH REV 2.1
Toluene b 45000 1000 30 ug/l MADEP VPH REV 2.1
m,p-Xylene b 21700 2000 80 ug/l MADEP VPH REV 2.1
o-Xylene b 10600 1000 37 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.) b 133000 20000 10000 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics (Unadj.) b 128000 20000 10000 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.) b 25300 20000 4000 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics b 75000 20000 10000 ug/l MADEP VPH REV 2.1
C9- C12 Aliphatics b 63700 20000 10000 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics b 25300 20000 4000 ug/l MADEP VPH REV 2.1
FA99528-2 TRIP BLANK
Methyl Chloride c 0.66 B 0.50 0.20 ug/l SM 6200B
(a) Sample re-analyzed beyond hold time.
(b) Analysis performed at SGS Scott, LA.
(c) Suspected instrument contaminant.
4 of 32
FA995282
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
5 of 32
FA995283
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-1
Lab Sample ID:FA99528-1 Date Sampled:10/04/22
Matrix:AQ - Ground Water Date Received:10/06/22
Method:SM 6200B Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234867.D 100 10/11/22 20:14 SS n/a n/a VA3255
Run #2 a A0235001.D 1000 10/19/22 21:43 SS n/a n/a VA3261
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3980 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene 354 50 13 ug/l
135-98-8 sec-Butylbenzene 218 50 13 ug/l
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9952833.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-1
Lab Sample ID:FA99528-1 Date Sampled:10/04/22
Matrix:AQ - Ground Water Date Received:10/06/22
Method:SM 6200B Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 81.8 50 13 ug/l
64-17-5 Ethyl Alcohol b ND 10000 6500 ug/l
100-41-4 Ethylbenzene 4810 c 500 130 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 582 50 13 ug/l
99-87-6 p-Isopropyltoluene ND 50 13 ug/l
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride 0.00 50 20 ug/l B
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride d ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 5960 c 500 130 ug/l
91-20-3 Naphthalene 1670 50 13 ug/l
103-65-1 n-Propylbenzene 2200 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
75-85-4 Tert-Amyl Alcohol e ND 1000 200 ug/l
994-05-8 Tert-Amyl Methyl Ether 1070 100 20 ug/l
75-65-0 Tert-Butyl Alcohol ND 1000 200 ug/l
762-75-4 Tert-Butyl Formate ND 1000 200 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 40900 50 13 ug/l E
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 4820 c 500 130 ug/l
108-67-8 1,3,5-Trimethylbenzene 3240 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 16100 c 1000 130 ug/l
95-47-6 o-Xylene 8680 c 500 130 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 92%95%70-130%
17060-07-0 1,2-Dichloroethane-D4 95%96%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 32
FA9952833.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-1
Lab Sample ID:FA99528-1 Date Sampled:10/04/22
Matrix:AQ - Ground Water Date Received:10/06/22
Method:SM 6200B Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 96%102%70-130%
460-00-4 4-Bromofluorobenzene 107%106%70-130%
(a) Sample re-analyzed beyond hold time.
(b) Associated CCV and ECC outside control limits.
(c) Result is from Run# 2
(d) Associated BS recovery outside control limits low.
(e) Associated CCV outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 32
FA9952833.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA99528-1 Date Sampled:10/04/22
Matrix:AQ - Ground Water Date Received:10/06/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a LE038674.D 200 10/13/22 18:38 ALA n/a n/a L:GLE2292
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3880 1000 28 ug/l
100-41-4 Ethylbenzene 6500 1000 35 ug/l
1634-04-4 Methyl Tert Butyl Ether 8850 1000 27 ug/l
91-20-3 Naphthalene 1230 1000 82 ug/l
108-88-3 Toluene 45000 1000 30 ug/l
m,p-Xylene 21700 2000 80 ug/l
95-47-6 o-Xylene 10600 1000 37 ug/l
C5- C8 Aliphatics (Unadj.)133000 20000 10000 ug/l
C9- C12 Aliphatics (Unadj.)128000 20000 10000 ug/l
C9- C10 Aromatics (Unadj.)25300 20000 4000 ug/l
C5- C8 Aliphatics 75000 20000 10000 ug/l
C9- C12 Aliphatics 63700 20000 10000 ug/l
C9- C10 Aromatics 25300 20000 4000 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
615-59-8 2,5-Dibromotoluene 101%70-130%
615-59-8 2,5-Dibromotoluene 90%70-130%
(a) Analysis performed at SGS Scott, LA.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 32
FA9952833.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA99528-2 Date Sampled:10/04/22
Matrix:AQ - Trip Blank Water Date Received:10/06/22
Method:SM 6200B Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0234847.D 1 10/11/22 12:37 SS n/a n/a VA3255
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 32
FA9952833.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA99528-2 Date Sampled:10/04/22
Matrix:AQ - Trip Blank Water Date Received:10/06/22
Method:SM 6200B Percent Solids:n/a
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride a 0.66 0.50 0.20 ug/l B
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride b ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 105%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
(a) Suspected instrument contaminant.
(b) Associated BS recovery outside control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 32
FA9952833.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
12 of 32
FA995284
FA99528: Chain of Custody
Page 1 of 3
13 of 32
FA9952844.1
SGS Sample Receipt Summary
Job Number:FA99528 Client:GRI
Date / Time Received:10/6/2022 10:00:00 AM Delivery Method:FX
Project:SILVER EXPRESS
Airbill #'s:199063798629
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments ONE REQUESTED ANALYSIS IS "VPH", BUT VIALS RECEIVED LABLED FOR "8011" FOR SAMPLE -1.
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.0);
Cooler 1: (3.6);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:; IR 1; Therm CF:0; 0.6; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SAMUELM Date:Date: 10/6/2022 10:00:00 A
SM001Rev. Date 05/24/17
FA99528: Chain of Custody
Page 2 of 3
14 of 32
FA9952844.1
Per client COC is correct. Analyze sample MW-1 for 6200 and VPH.Response:
Response Date:10/10/22CSR:Muna Mohammed
SM001Rev. Date 05/24/17
FA99528: Chain of Custody
Page 3 of 3
15 of 32
FA9952844.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
16 of 32
FA995285
Method Blank Summary Page 1 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-MB A0234844.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
17 of 32
FA9952855.1.1
Method Blank Summary Page 2 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-MB A0234844.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.63 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol 27.1 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%70-130%
18 of 32
FA9952855.1.1
Method Blank Summary Page 3 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-MB A0234844.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 105%70-130%
460-00-4 4-Bromofluorobenzene 107%70-130%
19 of 32
FA9952855.1.1
Method Blank Summary Page 1 of 1
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3261-MB A0234979.D 1 10/19/22 SS n/a n/a VA3261
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1
CAS No.Compound Result RL MDL Units Q
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 104%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
20 of 32
FA9952855.1.2
Blank Spike Summary Page 1 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-BS A0234842.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 8.6 86 70-130
108-86-1 Bromobenzene 10 8.4 84 70-130
74-97-5 Bromochloromethane 10 8.5 85 70-130
75-27-4 Bromodichloromethane 10 8.3 83 70-130
75-25-2 Bromoform 10 7.5 75 70-130
104-51-8 n-Butylbenzene 10 8.1 81 70-130
135-98-8 sec-Butylbenzene 10 9.0 90 70-130
98-06-6 tert-Butylbenzene 10 8.5 85 70-130
56-23-5 Carbon Tetrachloride 10 8.8 88 70-130
108-90-7 Chlorobenzene 10 8.7 87 70-130
75-00-3 Chloroethane 10 7.3 73 60-140
67-66-3 Chloroform 10 8.5 85 70-130
95-49-8 o-Chlorotoluene 10 8.4 84 70-130
106-43-4 p-Chlorotoluene 10 8.2 82 70-130
124-48-1 Dibromochloromethane 10 7.6 76 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 7.8 78 70-130
106-93-4 1,2-Dibromoethane 10 8.8 88 70-130
75-71-8 Dichlorodifluoromethane 10 6.3 63 60-140
95-50-1 1,2-Dichlorobenzene 10 8.8 88 70-130
541-73-1 1,3-Dichlorobenzene 10 9.0 90 70-130
106-46-7 1,4-Dichlorobenzene 10 8.5 85 70-130
75-34-3 1,1-Dichloroethane 10 8.9 89 70-130
107-06-2 1,2-Dichloroethane 10 8.2 82 70-130
75-35-4 1,1-Dichloroethylene 10 9.3 93 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.0 90 70-130
156-60-5 trans-1,2-Dichloroethylene 10 8.8 88 70-130
78-87-5 1,2-Dichloropropane 10 8.1 81 70-130
142-28-9 1,3-Dichloropropane 10 8.2 82 70-130
594-20-7 2,2-Dichloropropane 10 9.1 91 70-130
563-58-6 1,1-Dichloropropene 10 8.9 89 70-130
10061-01-5 cis-1,3-Dichloropropene 10 7.7 77 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.1 81 70-130
108-20-3 Di-Isopropyl Ether 10 8.1 81 70-130
64-17-5 Ethyl Alcohol 500 345 69*70-130
100-41-4 Ethylbenzene 10 8.7 87 70-130
637-92-3 Ethyl Tert Butyl Ether 10 6.8 68*70-130
* = Outside of Control Limits.
21 of 32
FA9952855.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-BS A0234842.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 9.1 91 70-130
98-82-8 Isopropylbenzene 10 8.8 88 70-130
99-87-6 p-Isopropyltoluene 10 8.6 86 70-130
74-83-9 Methyl Bromide 10 7.4 74 60-140
74-87-3 Methyl Chloride 10 10.9 109 60-140
74-95-3 Methylene Bromide 10 8.3 83 70-130
75-09-2 Methylene Chloride 10 6.2 62*70-130
1634-04-4 Methyl Tert Butyl Ether 10 7.0 70 70-130
91-20-3 Naphthalene 10 9.6 96 70-130
103-65-1 n-Propylbenzene 10 8.5 85 70-130
100-42-5 Styrene 10 8.8 88 70-130
75-85-4 Tert-Amyl Alcohol 100 96.2 96 70-130
994-05-8 Tert-Amyl Methyl Ether 10 7.3 73 70-130
75-65-0 Tert-Butyl Alcohol 100 101 101 70-130
762-75-4 Tert-Butyl Formate 100 90.9 91 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 8.6 86 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 8.6 86 70-130
127-18-4 Tetrachloroethylene 10 9.1 91 70-130
108-88-3 Toluene 10 8.5 85 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.6 96 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.3 93 70-130
71-55-6 1,1,1-Trichloroethane 10 9.0 90 70-130
79-00-5 1,1,2-Trichloroethane 10 8.8 88 70-130
79-01-6 Trichloroethylene 10 8.7 87 70-130
75-69-4 Trichlorofluoromethane 10 8.2 82 60-140
96-18-4 1,2,3-Trichloropropane 10 7.8 78 70-130
95-63-6 1,2,4-Trimethylbenzene 10 8.4 84 70-130
108-67-8 1,3,5-Trimethylbenzene 10 8.2 82 70-130
75-01-4 Vinyl Chloride 10 7.8 78 60-140
m,p-Xylene 20 15.8 79 70-130
95-47-6 o-Xylene 10 8.3 83 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 98%70-130%
* = Outside of Control Limits.
22 of 32
FA9952855.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3255-BS A0234842.D 1 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
23 of 32
FA9952855.2.1
Blank Spike Summary Page 1 of 1
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3261-BS A0234977.D 1 10/19/22 SS n/a n/a VA3261
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
100-41-4 Ethylbenzene 10 9.8 98 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.0 80 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.0 90 70-130
m,p-Xylene 20 17.6 88 70-130
95-47-6 o-Xylene 10 9.1 91 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
24 of 32
FA9952855.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA99528-1MS A0234853.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1MSD A0234854.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1 A0234867.D 100 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
FA99528-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 3980 1000 5200 122 1000 4820 84 8 70-130/20
108-86-1 Bromobenzene ND 1000 894 89 1000 873 87 2 70-130/20
74-97-5 Bromochloromethane ND 1000 854 85 1000 853 85 0 70-130/20
75-27-4 Bromodichloromethane ND 1000 996 100 1000 942 94 6 70-130/20
75-25-2 Bromoform ND 1000 727 73 1000 736 74 1 70-130/20
104-51-8 n-Butylbenzene 354 1000 1080 73 1000 1030 68*5 70-130/20
135-98-8 sec-Butylbenzene 218 1000 1050 83 1000 1000 78 5 70-130/20
98-06-6 tert-Butylbenzene ND 1000 928 93 1000 877 88 6 70-130/20
56-23-5 Carbon Tetrachloride ND 1000 900 90 1000 897 90 0 70-130/20
108-90-7 Chlorobenzene ND 1000 1010 101 1000 982 98 3 70-130/20
75-00-3 Chloroethane ND 1000 961 96 1000 748 75 25*60-140/20
67-66-3 Chloroform ND 1000 943 94 1000 893 89 5 70-130/20
95-49-8 o-Chlorotoluene ND 1000 1230 123 1000 1150 115 7 70-130/20
106-43-4 p-Chlorotoluene ND 1000 847 85 1000 831 83 2 70-130/20
124-48-1 Dibromochloromethane ND 1000 795 80 1000 795 80 0 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 912 91 1000 898 90 2 70-130/20
106-93-4 1,2-Dibromoethane ND 1000 828 83 1000 857 86 3 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 733 73 1000 642 64 13 60-140/20
95-50-1 1,2-Dichlorobenzene ND 1000 975 98 1000 958 96 2 70-130/20
541-73-1 1,3-Dichlorobenzene ND 1000 970 97 1000 962 96 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 1000 928 93 1000 909 91 2 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 956 96 1000 910 91 5 70-130/20
107-06-2 1,2-Dichloroethane ND 1000 864 86 1000 830 83 4 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 921 92 1000 914 91 1 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 877 88 1000 902 90 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 900 90 1000 878 88 2 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 923 92 1000 871 87 6 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 785 79 1000 797 80 2 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 864 86 1000 843 84 2 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 926 93 1000 910 91 2 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 836 84 1000 830 83 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 814 81 1000 830 83 2 70-130/20
108-20-3 Di-Isopropyl Ether 81.8 1000 945 86 1000 919 84 3 70-130/20
64-17-5 Ethyl Alcohol ND 50000 24400 49*50000 33200 66*31*70-130/20
100-41-4 Ethylbenzene 8830 E 1000 9540 71 1000 8730 -10* a 9 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 1000 665 67*1000 722 72 8 70-130/20
* = Outside of Control Limits.
25 of 32
FA9952855.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA99528-1MS A0234853.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1MSD A0234854.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1 A0234867.D 100 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
FA99528-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 1000 1070 107 1000 970 97 10 70-130/20
98-82-8 Isopropylbenzene 582 1000 1350 77 1000 1320 74 2 70-130/20
99-87-6 p-Isopropyltoluene ND 1000 963 96 1000 931 93 3 70-130/20
74-83-9 Methyl Bromide ND 1000 944 94 1000 711 71 28*60-140/20
74-87-3 Methyl Chloride 0.00 B 1000 1260 105 1000 862 66 38*60-140/20
74-95-3 Methylene Bromide ND 1000 854 85 1000 833 83 2 70-130/20
75-09-2 Methylene Chloride ND 1000 671 67*1000 640 64*5 70-130/20
1634-04-4 Methyl Tert Butyl Ether 6800 E 1000 8100 130 1000 8250 145* a 2 70-130/20
91-20-3 Naphthalene 1670 1000 2280 61*1000 2250 58*1 70-130/20
103-65-1 n-Propylbenzene 2200 1000 2640 44* a 1000 2480 28* a 6 70-130/20
100-42-5 Styrene ND 1000 900 90 1000 890 89 1 70-130/20
75-85-4 Tert-Amyl Alcohol ND 10000 10300 103 10000 14400 144*33*70-130/20
994-05-8 Tert-Amyl Methyl Ether 1070 1000 1910 84 1000 2100 103 9 70-130/20
75-65-0 Tert-Butyl Alcohol ND 10000 14100 141*10000 19700 197*33*70-130/20
762-75-4 Tert-Butyl Formate ND 10000 9060 91 10000 14900 149*49*70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 844 84 1000 815 82 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 975 98 1000 938 94 4 70-130/20
127-18-4 Tetrachloroethylene ND 1000 888 89 1000 887 89 0 70-130/20
108-88-3 Toluene 40900 E 1000 43200 230* a 1000 40300 -60* a 7 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 1030 103 1000 987 99 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 1100 110 1000 1030 103 7 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 902 90 1000 906 91 0 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 916 92 1000 908 91 1 70-130/20
79-01-6 Trichloroethylene ND 1000 1000 100 1000 925 93 8 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 1010 101 1000 814 81 21*60-140/20
96-18-4 1,2,3-Trichloropropane ND 1000 750 75 1000 723 72 4 70-130/20
95-63-6 1,2,4-Trimethylbenzene 12900 E 1000 11400 -150* a 1000 10600 -230* a 7 70-130/20
108-67-8 1,3,5-Trimethylbenzene 3240 1000 3370 13* a 1000 3190 -5* a 5 70-130/20
75-01-4 Vinyl Chloride ND 1000 925 93 1000 786 79 16 60-140/20
m,p-Xylene 25700 E 2000 26600 45* a 2000 24400 -65* a 9 70-130/20
95-47-6 o-Xylene 13500 E 1000 13900 40* a 1000 12800 -70* a 8 70-130/20
CAS No.Surrogate Recoveries MS MSD FA99528-1 Limits
1868-53-7 Dibromofluoromethane 95%95%92%70-130%
* = Outside of Control Limits.
26 of 32
FA9952855.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA99528-1MS A0234853.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1MSD A0234854.D 100 10/11/22 SS n/a n/a VA3255
FA99528-1 A0234867.D 100 10/11/22 SS n/a n/a VA3255
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1, FA99528-2
CAS No.Surrogate Recoveries MS MSD FA99528-1 Limits
17060-07-0 1,2-Dichloroethane-D4 100%100%95%70-130%
2037-26-5 Toluene-D8 95%96%96%70-130%
460-00-4 4-Bromofluorobenzene 101%103%107%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
27 of 32
FA9952855.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA99528
Account:GRINCC GRI (Geological Resources Inc.)
Project:Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA99528-1MS A0234990.D 1000 10/19/22 SS n/a n/a VA3261
FA99528-1MSD A0234991.D 1000 10/19/22 SS n/a n/a VA3261
FA99528-1 a A0235001.D 1000 10/19/22 SS n/a n/a VA3261
The QC reported here applies to the following samples:Method: SM 6200B
FA99528-1
FA99528-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
100-41-4 Ethylbenzene 4810 10000 15100 103 10000 15600 108 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 5960 10000 15200 92 10000 15900 99 5 70-130/20
95-63-6 1,2,4-Trimethylbenzene 4820 10000 14400 96 10000 15300 105 6 70-130/20
m,p-Xylene 16100 20000 34500 92 20000 35300 96 2 70-130/20
95-47-6 o-Xylene 8680 10000 18100 94 10000 19000 103 5 70-130/20
CAS No.Surrogate Recoveries MS MSD FA99528-1 Limits
1868-53-7 Dibromofluoromethane 97%98%95%70-130%
17060-07-0 1,2-Dichloroethane-D4 97%97%96%70-130%
2037-26-5 Toluene-D8 98%100%102%70-130%
460-00-4 4-Bromofluorobenzene 102%104%106%70-130%
(a) Sample re-analyzed beyond hold time.
* = Outside of Control Limits.
28 of 32
FA9952855.3.2
SGS North America Inc.
GC Volatiles
QC Data Summaries
(SGS Scott, LA)
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
29 of 32
FA995286
Method Blank Summary Page 1 of 1
Job Number:FA99528
Account:ALSE SGS Orlando, FL
Project:GRINCC: Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLE2292-MB1 LE038665.D 1 10/13/22 NN n/a n/a GLE2292
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA99528-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 5.0 0.14 ug/l
100-41-4 Ethylbenzene 0.28 5.0 0.17 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 5.0 0.14 ug/l
91-20-3 Naphthalene 2.0 5.0 0.41 ug/l J
108-88-3 Toluene 0.20 5.0 0.15 ug/l J
m,p-Xylene 1.2 10 0.40 ug/l J
95-47-6 o-Xylene 0.56 5.0 0.18 ug/l J
C5- C8 Aliphatics (Unadj.)ND 100 50 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 50 ug/l
C9- C10 Aromatics (Unadj.)ND 100 20 ug/l
C5- C8 Aliphatics ND 100 50 ug/l
C9- C12 Aliphatics ND 100 50 ug/l
C9- C10 Aromatics ND 100 20 ug/l
CAS No.Surrogate Recoveries Limits
615-59-8 2,5-Dibromotoluene 91%70-130%
615-59-8 2,5-Dibromotoluene 79%70-130%
30 of 32
FA9952866.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA99528
Account:ALSE SGS Orlando, FL
Project:GRINCC: Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLE2292-BS1 LE038663.D 1 10/13/22 NN n/a n/a GLE2292
GLE2292-BSD1 LE038664.D 1 10/13/22 NN n/a n/a GLE2292
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA99528-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 40 35.1 88 34.7 87 1 70-130/25
100-41-4 Ethylbenzene 40 35.8 90 35.7 89 0 70-130/25
1634-04-4 Methyl Tert Butyl Ether 40 33.0 83 34.6 87 5 70-130/25
91-20-3 Naphthalene 40 35.5 89 35.7 89 1 70-130/25
108-88-3 Toluene 40 35.0 88 35.2 88 1 70-130/25
m,p-Xylene 80 72.0 90 71.3 89 1 70-130/25
95-47-6 o-Xylene 40 34.9 87 35.0 88 0 70-130/25
C5- C8 Aliphatics (Unadj.)120 125 105 125 104 0 70-130/25
C9- C12 Aliphatics (Unadj.)120 115 96 111 93 3 70-130/25
C9- C10 Aromatics (Unadj.)40 34.9 87 35.3 88 1 70-130/25
C5- C8 Aliphatics 240 238 1 70-130/25
C9- C12 Aliphatics 293 292 0 70-130/25
C9- C10 Aromatics 40 34.9 87 35.3 88 1 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
615-59-8 2,5-Dibromotoluene 94%96%70-130%
615-59-8 2,5-Dibromotoluene 83%86%70-130%
* = Outside of Control Limits.
31 of 32
FA9952866.2.1
Duplicate Summary Page 1 of 1
Job Number:FA99528
Account:ALSE SGS Orlando, FL
Project:GRINCC: Silver Express; 5115A N Tryon St, Charlotte, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA99528-1DUP LE038675.D 200 10/13/22 NN n/a n/a GLE2292
FA99528-1 LE038674.D 200 10/13/22 NN n/a n/a GLE2292
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA99528-1
FA99528-1 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene 3880 3940 2 50
100-41-4 Ethylbenzene 6500 6500 0 50
1634-04-4 Methyl Tert Butyl Ether 8850 8800 1 50
91-20-3 Naphthalene 1230 1230 0 50
108-88-3 Toluene 45000 45000 0 50
m,p-Xylene 21700 21600 0 50
95-47-6 o-Xylene 10600 10500 1 50
C5- C8 Aliphatics (Unadj.)133000 135000 1 50
C9- C12 Aliphatics (Unadj.)128000 129000 1 50
C9- C10 Aromatics (Unadj.)25300 26200 3 50
C5- C8 Aliphatics 75000 77100 3 50
C9- C12 Aliphatics 63700 63900 0 50
C9- C10 Aromatics 25300 26200 3 50
CAS No.Surrogate Recoveries DUP FA99528-1 Limits
615-59-8 2,5-Dibromotoluene 99%101%70-130%
615-59-8 2,5-Dibromotoluene 89%90%70-130%
* = Outside of Control Limits.
32 of 32
FA9952866.3.1

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

2/7/2023
Geological Resources, Inc. Joanna Alley
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 23-030-0031 Client Project Description: Silver Express
GRI #5413
Dear Joanna Alley:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 1/30/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 61
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-030-0031
Page 2 of 61
Report Number:
Sample Summary Table
Client Project Description:
23-030-0031
Silver Express
GRI #5413
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
01/30/2023 14:15Aqueous 98716 MW-2 01/30/2023 15:59
01/30/2023 14:15Aqueous 98716 MW-2 01/30/2023 15:59 6010D Eurofins -
01/30/2023 14:45Aqueous 98717 MW-3 01/30/2023 15:59
01/30/2023 14:45Aqueous 98717 MW-3 01/30/2023 15:59 6010D Eurofins -
01/30/2023 14:30Aqueous 98718 MW-4 01/30/2023 15:59
01/30/2023 14:30Aqueous 98718 MW-4 01/30/2023 15:59 6010D Eurofins -
01/30/2023 14:00Aqueous 98719 Trip Blanks 01/30/2023 15:59
Eurofins - Savannah: Eurofins Environmental Testing Southeast, Savannah, Savannah, GA
Page 3 of 61
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0031
Report Limit
Project:Silver Express
V 98716MW-2
122 02/03/2023 07:146200BBenzeneµg/L 1.80
97.4 02/03/2023 07:146200Bn-Butylbenzene µg/L 1.80
51.2 02/03/2023 07:146200Bsec-Butyl benzene µg/L 2.00
1300 02/03/2023 19:246200BEthylbenzeneµg/L 17.0
115 02/03/2023 07:146200BIsopropylbenzeneµg/L 1.80
22.4 02/03/2023 07:146200B4-Isopropyl toluene µg/L 0.890
168 02/03/2023 07:146200BMethyl tert-butyl ether (MTBE)µg/L 1.40
312 02/03/2023 07:146200BNaphthaleneµg/L 4.70
375 02/03/2023 07:146200Bn-Propylbenzene µg/L 1.90
1390 02/03/2023 07:146200Btert-Butyl Alcohol (TBA)µg/L 16.0
1330 02/03/2023 19:246200Btert-Amyl Alcohol (TAA)µg/L 190
J7.96 02/03/2023 07:146200Btert-Amyl Methyl Ether (TAME)µg/L 2.80
3690 02/03/2023 19:246200BTolueneµg/L 22.0
2610 02/03/2023 19:246200B1,2,4-Trimethylbenzene µg/L 19.0
778 02/03/2023 07:146200B1,3,5-Trimethylbenzene µg/L 1.80
3460 02/03/2023 19:246200Bo-Xylene µg/L 21.0
7130 02/03/2023 19:246200Bm,p-Xylene µg/L 42.0
10600 02/03/2023 19:246200BXylene (Total)µg/L 21.0
2500 02/01/2023 09:18CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
11700 02/01/2023 09:18CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 2580
6930 02/01/2023 09:18CALCULATIONAromatic C9-C10 (Adjusted)µg/L 402
6310 02/01/2023 09:18MADEP-VPH Aliphatic C5-C8 µg/L 1150
30500 02/01/2023 09:18MADEP-VPH Aliphatic C9-C12 µg/L 2580
6930 02/01/2023 09:18MADEP-VPH Aromatic C9-C10 µg/L 402
V 98717MW-3
673 02/03/2023 07:396200BAcetoneµg/L 18.0
3240 02/03/2023 21:146200BBenzeneµg/L 180
16.6 02/03/2023 07:396200Bn-Butylbenzene µg/L 1.80
9.28 02/03/2023 07:396200Bsec-Butyl benzene µg/L 2.00
121 02/03/2023 07:396200BDi-Isopropyl Ether (DIPE)µg/L 5.00
2990 02/03/2023 21:146200BEthylbenzeneµg/L 170
128 02/03/2023 07:396200B2-Hexanone µg/L 3.80
89.6 02/03/2023 07:396200BIsopropylbenzeneµg/L 1.80
J3.46 02/03/2023 07:396200B4-Isopropyl toluene µg/L 0.890
491 02/03/2023 07:396200BMethyl Ethyl Ketone (MEK)µg/L 7.10
18000 02/03/2023 21:146200BMethyl tert-butyl ether (MTBE)µg/L 140
Page 4 of 61
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0031
Report Limit
Project:Silver Express
V 98717MW-3
64.6 02/03/2023 07:396200B4-Methyl-2-Pentanone µg/L 0.780
346 02/03/2023 07:396200BNaphthaleneµg/L 4.70
216 02/03/2023 07:396200Bn-Propylbenzene µg/L 1.90
27700 02/03/2023 21:146200Btert-Butyl Alcohol (TBA)µg/L 1600
13700 02/03/2023 21:146200Btert-Amyl Alcohol (TAA)µg/L 1900
1920 02/03/2023 07:396200Btert-Amyl Methyl Ether (TAME)µg/L 2.80
26400 02/03/2023 21:146200BTolueneµg/L 220
2210 02/03/2023 21:146200B1,2,4-Trimethylbenzene µg/L 190
467 02/03/2023 07:396200B1,3,5-Trimethylbenzene µg/L 1.80
6150 02/03/2023 21:146200Bo-Xylene µg/L 210
10900 02/03/2023 21:146200Bm,p-Xylene µg/L 420
17100 02/03/2023 21:146200BXylene (Total)µg/L 210
14000 01/31/2023 16:34CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
11400 01/31/2023 16:34CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 2580
5370 01/31/2023 16:34CALCULATIONAromatic C9-C10 (Adjusted)µg/L 402
43600 01/31/2023 16:34MADEP-VPH Aliphatic C5-C8 µg/L 1150
36800 01/31/2023 16:34MADEP-VPH Aliphatic C9-C12 µg/L 2580
5370 01/31/2023 16:34MADEP-VPH Aromatic C9-C10 µg/L 402
V 98718MW-4
J4.55 02/03/2023 08:036200BBenzeneµg/L 1.80
21.5 02/03/2023 08:036200BDi-Isopropyl Ether (DIPE)µg/L 5.00
11.9 02/03/2023 08:036200BEthylbenzeneµg/L 1.70
2150 02/03/2023 19:526200BMethyl tert-butyl ether (MTBE)µg/L 14.0
10.8 02/03/2023 08:036200BNaphthaleneµg/L 4.70
J2.59 02/03/2023 08:036200Bn-Propylbenzene µg/L 1.90
1030 02/03/2023 08:036200Btert-Butyl Alcohol (TBA)µg/L 16.0
150 02/03/2023 08:036200Btert-Amyl Alcohol (TAA)µg/L 19.0
128 02/03/2023 08:036200Btert-Amyl Methyl Ether (TAME)µg/L 2.80
42.2 02/03/2023 08:036200BTolueneµg/L 2.20
14.2 02/03/2023 08:036200B1,2,4-Trimethylbenzene µg/L 1.90
9.19 02/03/2023 08:036200B1,3,5-Trimethylbenzene µg/L 1.80
24.2 02/03/2023 08:036200Bo-Xylene µg/L 2.10
33.9 02/03/2023 08:036200Bm,p-Xylene µg/L 4.20
58.1 02/03/2023 08:036200BXylene (Total)µg/L 2.10
J87802/01/2023 10:30CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 23.0
165 02/01/2023 10:30CALCULATIONAromatic C9-C10 (Adjusted)µg/L 8.04
Page 5 of 61
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0031
Report Limit
Project:Silver Express
V 98718MW-4
925 02/01/2023 10:30MADEP-VPH Aliphatic C5-C8 µg/L 23.0
241 02/01/2023 10:30MADEP-VPH Aliphatic C9-C12 µg/L 51.6
165 02/01/2023 10:30MADEP-VPH Aromatic C9-C10 µg/L 8.04
Page 6 of 61

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Silver Express Lab Report Number: 23-030-0031
Date: 2/7/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: Carbon Tetrachloride QC Batch No: V29449/V29448
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Carbon Tetrachloride QC Batch No: V29449/V29448
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Carbon Tetrachloride QC Batch No: V29529/V29448
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Ethanol QC Batch No: V29531/V29448
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 7 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 02/03/23 07:14 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 90.8 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: Toluene-d8 99.6 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 99.4 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 19:24100 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
<18.0 µg/L 18.0 100Acetone 10 02/03/23 07:14 V29449MSA
122 µg/L 1.80 5.00Benzene 10 02/03/23 07:14 V29449MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 02/03/23 07:14 V29449MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 02/03/23 07:14 V29449MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 02/03/23 07:14 V29449MSA
<15.0 µg/L 15.0 50.0Bromoform 10 02/03/23 07:14 V29449MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 02/03/23 07:14 V29449MSA
97.4 µg/L 1.80 5.00n-Butylbenzene 10 02/03/23 07:14 V29449MSA
51.2 µg/L 2.00 5.00sec-Butyl benzene 10 02/03/23 07:14 V29449MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 02/03/23 07:14 V29449MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 02/03/23 07:14 V29449MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 02/03/23 07:14 V29449MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 02/03/23 07:14 V29449MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 02/03/23 07:14 V29449MSA
<2.20 µg/L 2.20 5.00Chloroform 10 02/03/23 07:14 V29449MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 02/03/23 07:14 V29449MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 02/03/23 07:14 V29449MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 02/03/23 07:14 V29449MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 02/03/23 07:14 V29449MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 02/03/23 07:14 V29449MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 02/03/23 07:14 V29449MSA
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 02/03/23 07:14 V29449MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 02/03/23 07:14 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 02/03/23 07:14 V29449MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 02/03/23 07:14 V29449MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 02/03/23 07:14 V29449MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 02/03/23 07:14 V29449MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 02/03/23 07:14 V29449MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 02/03/23 07:14 V29449MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 02/03/23 07:14 V29449MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 02/03/23 07:14 V29449MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 02/03/23 07:14 V29449MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 02/03/23 07:14 V29449MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 02/03/23 07:14 V29449MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 02/03/23 07:14 V29449MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 02/03/23 07:14 V29449MSA
<420 µg/L 420 2000Ethanol 10 02/03/23 07:14 V29449MSA
1300 µg/L 17.0 50.0Ethylbenzene 100 02/03/23 19:24 V29529MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 02/03/23 07:14 V29449MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 02/03/23 07:14 V29449MSA
115 µg/L 1.80 5.00Isopropylbenzene 10 02/03/23 07:14 V29449MSA
22.4 µg/L 0.890 5.004-Isopropyl toluene 10 02/03/23 07:14 V29449MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 02/03/23 07:14 V29449MSA
168 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 02/03/23 07:14 V29449MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 02/03/23 07:14 V29449MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 02/03/23 07:14 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
312 µg/L 4.70 10.0Naphthalene 10 02/03/23 07:14 V29449MSA
375 µg/L 1.90 5.00n-Propylbenzene 10 02/03/23 07:14 V29449MSA
<2.20 µg/L 2.20 5.00Styrene 10 02/03/23 07:14 V29449MSA
1390 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 02/03/23 07:14 V29449MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 02/03/23 07:14 V29449MSA
1330 µg/L 190 1000tert-Amyl Alcohol (TAA)100 02/03/23 19:24 V29529MSA
7.96 J µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 02/03/23 07:14 V29449MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 02/03/23 07:14 V29449MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 02/03/23 07:14 V29449MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 02/03/23 07:14 V29449MSA
3690 µg/L 22.0 50.0Toluene 100 02/03/23 19:24 V29529MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 02/03/23 07:14 V29449MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 02/03/23 07:14 V29449MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 02/03/23 07:14 V29449MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 02/03/23 07:14 V29449MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 02/03/23 07:14 V29449MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 02/03/23 07:14 V29449MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 02/03/23 07:14 V29449MSA
2610 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 02/03/23 19:24 V29529MSA
778 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 02/03/23 07:14 V29449MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 02/03/23 07:14 V29449MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 02/03/23 07:14 V29449MSA
3460 µg/L 21.0 50.0o-Xylene 100 02/03/23 19:24 V29529MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
7130 µg/L 42.0 100m,p-Xylene 100 02/03/23 19:24 V29529MSA
10600 µg/L 21.0 50.0Xylene (Total)100 02/03/23 19:24 V29529
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 90.8 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: Toluene-d8 99.6 Limits: 70-130%02/03/23 07:1410 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 99.4 Limits: 70-130%02/03/23 19:24100 MSA V29529
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 19:24100 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-2
98716 Matrix:
1/30/2023 14:15
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
2500 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)10 02/01/23 09:18
11700 µg/L 2580 5000Aliphatics C9-C12 (Adjusted)100 02/01/23 09:18
6930 µg/L 402 5000Aromatic C9-C10 (Adjusted)100 02/01/23 09:18
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
6310 µg/L 1150 5000Aliphatic C5-C8 100 02/01/23 09:18 V29322TBL
30500 µg/L 2580 5000Aliphatic C9-C12 100 02/01/23 09:18 V29322TBL
6930 µg/L 402 5000Aromatic C9-C10 100 02/01/23 09:18 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)91.6 Limits: 70-130%02/01/23 09:18100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)86.4 Limits: 70-130%02/01/23 09:18100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 02/03/23 07:39 6200BMSA
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: Toluene-d8 99.0 Limits: 70-130%02/03/23 21:141000 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
673 µg/L 18.0 100Acetone 10 02/03/23 07:39 V29449MSA
3240 µg/L 180 500Benzene 1000 02/03/23 21:14 V29529MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 02/03/23 07:39 V29449MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 02/03/23 07:39 V29449MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 02/03/23 07:39 V29449MSA
<15.0 µg/L 15.0 50.0Bromoform 10 02/03/23 07:39 V29449MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 02/03/23 07:39 V29449MSA
16.6 µg/L 1.80 5.00n-Butylbenzene 10 02/03/23 07:39 V29449MSA
9.28 µg/L 2.00 5.00sec-Butyl benzene 10 02/03/23 07:39 V29449MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 02/03/23 07:39 V29449MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 02/03/23 07:39 V29449MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 02/03/23 07:39 V29449MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 02/03/23 07:39 V29449MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 02/03/23 07:39 V29449MSA
<2.20 µg/L 2.20 5.00Chloroform 10 02/03/23 07:39 V29449MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 02/03/23 07:39 V29449MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 02/03/23 07:39 V29449MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 02/03/23 07:39 V29449MSA
121 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 02/03/23 07:39 V29449MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 02/03/23 07:39 V29449MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 02/03/23 07:39 V29449MSA
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 02/03/23 07:39 V29449MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 02/03/23 07:39 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 02/03/23 07:39 V29449MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 02/03/23 07:39 V29449MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 02/03/23 07:39 V29449MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 02/03/23 07:39 V29449MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 02/03/23 07:39 V29449MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 02/03/23 07:39 V29449MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 02/03/23 07:39 V29449MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 02/03/23 07:39 V29449MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 02/03/23 07:39 V29449MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 02/03/23 07:39 V29449MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 02/03/23 07:39 V29449MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 02/03/23 07:39 V29449MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 02/03/23 07:39 V29449MSA
<420 µg/L 420 2000Ethanol 10 02/03/23 07:39 V29449MSA
2990 µg/L 170 500Ethylbenzene 1000 02/03/23 21:14 V29529MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 02/03/23 07:39 V29449MSA
128 µg/L 3.80 10.02-Hexanone 10 02/03/23 07:39 V29449MSA
89.6 µg/L 1.80 5.00Isopropylbenzene 10 02/03/23 07:39 V29449MSA
3.46 J µg/L 0.890 5.004-Isopropyl toluene 10 02/03/23 07:39 V29449MSA
491 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 02/03/23 07:39 V29449MSA
18000 µg/L 140 1000Methyl tert-butyl ether (MTBE)1000 02/03/23 21:14 V29529MSA
64.6 µg/L 0.780 10.04-Methyl-2-Pentanone 10 02/03/23 07:39 V29449MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 02/03/23 07:39 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
346 µg/L 4.70 10.0Naphthalene 10 02/03/23 07:39 V29449MSA
216 µg/L 1.90 5.00n-Propylbenzene 10 02/03/23 07:39 V29449MSA
<2.20 µg/L 2.20 5.00Styrene 10 02/03/23 07:39 V29449MSA
27700 µg/L 1600 10000tert-Butyl Alcohol (TBA)1000 02/03/23 21:14 V29529MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 02/03/23 07:39 V29449MSA
13700 µg/L 1900 10000tert-Amyl Alcohol (TAA)1000 02/03/23 21:14 V29529MSA
1920 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 02/03/23 07:39 V29449MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 02/03/23 07:39 V29449MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 02/03/23 07:39 V29449MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 02/03/23 07:39 V29449MSA
26400 µg/L 220 500Toluene 1000 02/03/23 21:14 V29529MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 02/03/23 07:39 V29449MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 02/03/23 07:39 V29449MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 02/03/23 07:39 V29449MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 02/03/23 07:39 V29449MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 02/03/23 07:39 V29449MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 02/03/23 07:39 V29449MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 02/03/23 07:39 V29449MSA
2210 µg/L 190 5001,2,4-Trimethylbenzene 1000 02/03/23 21:14 V29529MSA
467 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 02/03/23 07:39 V29449MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 02/03/23 07:39 V29449MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 02/03/23 07:39 V29449MSA
6150 µg/L 210 500o-Xylene 1000 02/03/23 21:14 V29529MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
10900 µg/L 420 1000m,p-Xylene 1000 02/03/23 21:14 V29529MSA
17100 µg/L 210 500Xylene (Total)1000 02/03/23 21:14 V29529
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 07:3910 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 70-130%02/03/23 21:141000 MSA V29529
Surrogate: Toluene-d8 99.0 Limits: 70-130%02/03/23 21:141000 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-3
98717 Matrix:
1/30/2023 14:45
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
14000 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)100 01/31/23 16:34
11400 µg/L 2580 5000Aliphatics C9-C12 (Adjusted)100 01/31/23 16:34
5370 µg/L 402 5000Aromatic C9-C10 (Adjusted)100 01/31/23 16:34
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
43600 µg/L 1150 5000Aliphatic C5-C8 100 01/31/23 16:34 V29322TBL
36800 µg/L 2580 5000Aliphatic C9-C12 100 01/31/23 16:34 V29322TBL
5370 µg/L 402 5000Aromatic C9-C10 100 01/31/23 16:34 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)90.0 Limits: 70-130%01/31/23 16:34100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)82.1 Limits: 70-130%01/31/23 16:34100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 02/03/23 08:03 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 91.6 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 100 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: Toluene-d8 99.4 Limits: 70-130%02/03/23 19:52100 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
<18.0 µg/L 18.0 100Acetone 10 02/03/23 08:03 V29449MSA
4.55 J µg/L 1.80 5.00Benzene 10 02/03/23 08:03 V29449MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 02/03/23 08:03 V29449MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 02/03/23 08:03 V29449MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 02/03/23 08:03 V29449MSA
<15.0 µg/L 15.0 50.0Bromoform 10 02/03/23 08:03 V29449MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00n-Butylbenzene 10 02/03/23 08:03 V29449MSA
<2.00 µg/L 2.00 5.00sec-Butyl benzene 10 02/03/23 08:03 V29449MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 02/03/23 08:03 V29449MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 02/03/23 08:03 V29449MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 02/03/23 08:03 V29449MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 02/03/23 08:03 V29449MSA
<2.20 µg/L 2.20 5.00Chloroform 10 02/03/23 08:03 V29449MSA
<2.20 µg/L 2.20 5.00Chloromethane 10 02/03/23 08:03 V29449MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 02/03/23 08:03 V29449MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 02/03/23 08:03 V29449MSA
21.5 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 02/03/23 08:03 V29449MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 02/03/23 08:03 V29449MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 02/03/23 08:03 V29449MSA
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 02/03/23 08:03 V29449MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 02/03/23 08:03 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 02/03/23 08:03 V29449MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 02/03/23 08:03 V29449MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 02/03/23 08:03 V29449MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 02/03/23 08:03 V29449MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 02/03/23 08:03 V29449MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 02/03/23 08:03 V29449MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 02/03/23 08:03 V29449MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 02/03/23 08:03 V29449MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 02/03/23 08:03 V29449MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 02/03/23 08:03 V29449MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 02/03/23 08:03 V29449MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 02/03/23 08:03 V29449MSA
<420 µg/L 420 2000Ethanol 10 02/03/23 08:03 V29449MSA
11.9 µg/L 1.70 5.00Ethylbenzene 10 02/03/23 08:03 V29449MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 02/03/23 08:03 V29449MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00Isopropylbenzene 10 02/03/23 08:03 V29449MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 02/03/23 08:03 V29449MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 02/03/23 08:03 V29449MSA
2150 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 02/03/23 19:52 V29529MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 02/03/23 08:03 V29449MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 02/03/23 08:03 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
10.8 µg/L 4.70 10.0Naphthalene 10 02/03/23 08:03 V29449MSA
2.59 J µg/L 1.90 5.00n-Propylbenzene 10 02/03/23 08:03 V29449MSA
<2.20 µg/L 2.20 5.00Styrene 10 02/03/23 08:03 V29449MSA
1030 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 02/03/23 08:03 V29449MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 02/03/23 08:03 V29449MSA
150 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 02/03/23 08:03 V29449MSA
128 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 02/03/23 08:03 V29449MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 02/03/23 08:03 V29449MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 02/03/23 08:03 V29449MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 02/03/23 08:03 V29449MSA
42.2 µg/L 2.20 5.00Toluene 10 02/03/23 08:03 V29449MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 02/03/23 08:03 V29449MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 02/03/23 08:03 V29449MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 02/03/23 08:03 V29449MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 02/03/23 08:03 V29449MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 02/03/23 08:03 V29449MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 02/03/23 08:03 V29449MSA
14.2 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 02/03/23 08:03 V29449MSA
9.19 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 02/03/23 08:03 V29449MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 02/03/23 08:03 V29449MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 02/03/23 08:03 V29449MSA
24.2 µg/L 2.10 5.00o-Xylene 10 02/03/23 08:03 V29449MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29448 02/02/23 14:00 V29528 02/03/23 09:00
33.9 µg/L 4.20 10.0m,p-Xylene 10 02/03/23 08:03 V29449MSA
58.1 µg/L 2.10 5.00Xylene (Total)10 02/03/23 08:03 V29449
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: 1,2-Dichloroethane - d4 91.6 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: Toluene-d8 100 Limits: 70-130%02/03/23 08:0310 MSA V29449
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 100 Limits: 70-130%02/03/23 19:52100 MSA V29529
Surrogate: Toluene-d8 99.4 Limits: 70-130%02/03/23 19:52100 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:MW-4
98718 Matrix:
1/30/2023 14:30
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
878 J µg/L 23.0 100Aliphatic C5-C8 (Adjusted)10 02/01/23 10:30
<51.6 µg/L 51.6 100Aliphatics C9-C12 (Adjusted)10 02/01/23 10:30
165 µg/L 8.04 100Aromatic C9-C10 (Adjusted)2 02/01/23 10:30
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
925 µg/L 23.0 100Aliphatic C5-C8 2 02/01/23 10:30 V29322TBL
241 µg/L 51.6 100Aliphatic C9-C12 2 02/01/23 10:30 V29322TBL
165 µg/L 8.04 100Aromatic C9-C10 2 02/01/23 10:30 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)101 Limits: 70-130%02/01/23 10:302 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)95.0 Limits: 70-130%02/01/23 10:302 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:Trip Blanks
98719 Matrix:
1/30/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29530 02/03/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500Benzene 1 02/03/23 14:50 V29531MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/03/23 14:50 V29531MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/03/23 14:50 V29531MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/03/23 14:50 V29531MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/03/23 14:50 V29531MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 02/03/23 14:50 V29531MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/03/23 14:50 V29531MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/03/23 14:50 V29531MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/03/23 14:50 V29531MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.500Chloroform 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/03/23 14:50 V29531MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/03/23 14:50 V29531MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 02/03/23 14:50 V29531MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/03/23 14:50 V29531MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:Trip Blanks
98719 Matrix:
1/30/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29530 02/03/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/03/23 14:50 V29531MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/03/23 14:50 V29531MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/03/23 14:50 V29531MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/03/23 14:50 V29531MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/03/23 14:50 V29531MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 02/03/23 14:50 V29531MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 02/03/23 14:50 V29531MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/03/23 14:50 V29531MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/03/23 14:50 V29531MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/03/23 14:50 V29531MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/03/23 14:50 V29531MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/03/23 14:50 V29531MSA
<42.0 µg/L 42.0 200Ethanol 1 02/03/23 14:50 V29531MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 02/03/23 14:50 V29531MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/03/23 14:50 V29531MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 02/03/23 14:50 V29531MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/03/23 14:50 V29531MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/03/23 14:50 V29531MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/03/23 14:50 V29531MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/03/23 14:50 V29531MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:Trip Blanks
98719 Matrix:
1/30/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29530 02/03/23 09:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/03/23 14:50 V29531MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 02/03/23 14:50 V29531MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.500Styrene 1 02/03/23 14:50 V29531MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/03/23 14:50 V29531MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 02/03/23 14:50 V29531MSA
<0.220 µg/L 0.220 0.500Toluene 1 02/03/23 14:50 V29531MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/03/23 14:50 V29531MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/03/23 14:50 V29531MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/03/23 14:50 V29531MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 02/03/23 14:50 V29531MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/03/23 14:50 V29531MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/03/23 14:50 V29531MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/03/23 14:50 V29531MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/03/23 14:50 V29531MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/03/23 14:50 V29531MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 02/03/23 14:50 V29531MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 02/03/23 14:50 V29531MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 61
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-030-0031
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #5413 Received : 01/30/2023
Silver Express
Report Date : 02/07/2023
Sample ID :
Lab No :
Sampled:Trip Blanks
98719 Matrix:
1/30/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29530 02/03/23 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 02/03/23 14:50 V29531
Surrogate: 4-Bromofluorobenzene 96.0 Limits: 70-130%02/03/23 14:501 MSA V29531
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%02/03/23 14:501 MSA V29531
Surrogate: 1,2-Dichloroethane - d4 89.0 Limits: 70-130%02/03/23 14:501 MSA V29531
Surrogate: Toluene-d8 99.2 Limits: 70-130%02/03/23 14:501 MSA V29531
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 61
ANALYTICAL REPORT
PREPARED FOR
Attn: PM Group NC
Waypoint Analytical, Inc.
449 Springbrook Road
Charlotte, North Carolina 28217
Generated 2/7/2023 6:07:55 PM
JOB DESCRIPTION
23-030-0031
JOB NUMBER
680-229975-1
See page two for job notes and contact information.
Savannah GA 31404
5102 LaRoche Avenue
Eurofins Savannah
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Eurofins Savannah
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report may not be
reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the person who
signed this report.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
2/7/2023 6:07:55 PM
Authorized for release by
John Andros, Project Manager I
[e-mail]
[phone]
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Definitions/Glossary
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Savannah
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Sample Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229975-1
Project/Site: 23-030-0031
Lab Sample ID Client Sample ID Matrix Collected Received
680-229975-1 MW-2 / 98716 Water 01/30/23 14:15 02/03/23 13:30
680-229975-2 MW-3 / 98717 Water 01/30/23 14:45 02/03/23 13:30
680-229975-3 MW-4 / 98718 Water 01/30/23 14:30 02/03/23 13:30
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Case Narrative
Client: Waypoint Analytical, Inc.Job ID: 680-229975-1
Project/Site: 23-030-0031
Job ID: 680-229975-1
Laboratory: Eurofins Savannah
Narrative
Job Narrative
680-229975-1
Receipt
The samples were received on 2/3/2023 1:30 PM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 5.4°C
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Client Sample Results
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Lab Sample ID: 680-229975-1Client Sample ID: MW-2 / 98716
Matrix: WaterDate Collected: 01/30/23 14:15
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 6.60 ug/L 02/06/23 06:43 02/06/23 19:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Lab Sample ID: 680-229975-2Client Sample ID: MW-3 / 98717
Matrix: WaterDate Collected: 01/30/23 14:45
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 6.60 ug/L 02/06/23 06:43 02/06/23 19:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Lab Sample ID: 680-229975-3Client Sample ID: MW-4 / 98718
Matrix: WaterDate Collected: 01/30/23 14:30
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 6.60 ug/L 02/06/23 06:43 02/06/23 19:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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QC Sample Results
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-762014/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762327 Prep Batch: 762014
RL MDL
Lead ND 10.0 6.60 ug/L 02/06/23 06:43 02/06/23 18:47 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-762014/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762327 Prep Batch: 762014
Lead 505 478.7 ug/L 95 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 680-229955-A-3-B MS
Matrix: Water Prep Type: Dissolved
Analysis Batch: 762327 Prep Batch: 762014
Lead ND 505 489.3 ug/L 97 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 680-229955-A-3-C MSD
Matrix: Water Prep Type: Dissolved
Analysis Batch: 762327 Prep Batch: 762014
Lead ND 505 488.8 ug/L 97 75-125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Eurofins Savannah
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QC Association Summary
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Metals
Prep Batch: 762014
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A680-229975-1 MW-2 / 98716 Total Recoverable
Water 3005A680-229975-2 MW-3 / 98717 Total Recoverable
Water 3005A680-229975-3 MW-4 / 98718 Total Recoverable
Water 3005AMB 680-762014/1-A Method Blank Total Recoverable
Water 3005ALCS 680-762014/2-A Lab Control Sample Total Recoverable
Water 3005A680-229955-A-3-B MS Matrix Spike Dissolved
Water 3005A680-229955-A-3-C MSD Matrix Spike Duplicate Dissolved
Analysis Batch: 762327
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 762014680-229975-1 MW-2 / 98716 Total Recoverable
Water 6010D 762014680-229975-2 MW-3 / 98717 Total Recoverable
Water 6010D 762014680-229975-3 MW-4 / 98718 Total Recoverable
Water 6010D 762014MB 680-762014/1-A Method Blank Total Recoverable
Water 6010D 762014LCS 680-762014/2-A Lab Control Sample Total Recoverable
Water 6010D 762014680-229955-A-3-B MS Matrix Spike Dissolved
Water 6010D 762014680-229955-A-3-C MSD Matrix Spike Duplicate Dissolved
Eurofins Savannah
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Lab Chronicle
Client: Waypoint Analytical, Inc.Job ID: 680-229975-1
Project/Site: 23-030-0031
Client Sample ID: MW-2 / 98716 Lab Sample ID: 680-229975-1
Matrix: WaterDate Collected: 01/30/23 14:15
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 06:43 EET SAV762014
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762327 02/06/23 19:11 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-3 / 98717 Lab Sample ID: 680-229975-2
Matrix: WaterDate Collected: 01/30/23 14:45
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 06:43 EET SAV762014
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762327 02/06/23 19:20 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-4 / 98718 Lab Sample ID: 680-229975-3
Matrix: WaterDate Collected: 01/30/23 14:30
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 06:43 EET SAV762014
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762327 02/06/23 19:23 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Accreditation/Certification Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229975-1
Project/Site: 23-030-0031
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW) State 269 12-31-23
South Carolina State 98001 06-30-23
Eurofins Savannah
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Method Summary
Job ID: 680-229975-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0031
Method Method Description LaboratoryProtocol
SW8466010D Metals (ICP)EET SAV
SW8463005A Preparation, Total Recoverable or Dissolved Metals EET SAV
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Login Sample Receipt Checklist
Client: Waypoint Analytical, Inc.Job Number: 680-229975-1
Login Number: 229975
Question Answer Comment
Creator: Sims, Robert D
List Source: Eurofins Savannah
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Savannah
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Page 44 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
Associated Lab Samples: 98716, 98717, 98718
LRB-V29448 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 01:5610.01.80<1.80µg/LAcetone
02/03/23 01:560.5000.180<0.180µg/LBenzene
02/03/23 01:560.5000.210<0.210µg/LBromobenzene
02/03/23 01:561.000.420<0.420µg/LBromochloromethane
02/03/23 01:560.5000.160<0.160µg/LBromodichloromethane
02/03/23 01:565.001.50<1.50µg/LBromoform
02/03/23 01:561.000.280<0.280µg/LBromomethane
02/03/23 01:560.5000.180<0.180µg/Ln-Butylbenzene
02/03/23 01:560.5000.200<0.200µg/Lsec-Butyl benzene
02/03/23 01:562.000.920<0.920µg/Ltert-Butyl benzene
02/03/23 01:560.5000.180<0.180µg/LCarbon Tetrachloride
02/03/23 01:560.5000.190<0.190µg/LChlorobenzene
02/03/23 01:560.5000.190<0.190µg/LChlorodibromomethane
02/03/23 01:561.000.430<0.430µg/LChloroethane
02/03/23 01:560.5000.220<0.220µg/LChloroform
02/03/23 01:560.5000.220<0.220µg/LChloromethane
02/03/23 01:560.5000.200<0.200µg/L2-Chlorotoluene
02/03/23 01:560.5000.200<0.200µg/L4-Chlorotoluene
02/03/23 01:560.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
02/03/23 01:562.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
02/03/23 01:560.5000.230<0.230µg/LDibromomethane
02/03/23 01:560.5000.220<0.220µg/L1,2-Dichlorobenzene
02/03/23 01:560.5000.190<0.190µg/L1,3-Dichlorobenzene
02/03/23 01:560.5000.210<0.210µg/L1,4-Dichlorobenzene
02/03/23 01:565.001.20<1.20µg/LDichlorodifluoromethane
02/03/23 01:560.5000.240<0.240µg/L1,1-Dichloroethane
02/03/23 01:560.5000.150<0.150µg/L1,2-Dichloroethane
Page 1 of 15Date:02/07/2023 06:41 PM
Page 45 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
Associated Lab Samples: 98716, 98717, 98718
LRB-V29448 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 01:560.5000.150<0.150µg/L1,1-Dichloroethene
02/03/23 01:560.5000.200<0.200µg/Lcis-1,2-Dichloroethene
02/03/23 01:560.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
02/03/23 01:560.5000.190<0.190µg/L1,2-Dichloropropane
02/03/23 01:560.5000.130<0.130µg/L1,3-Dichloropropane
02/03/23 01:562.000.210<0.210µg/L2,2-Dichloropropane
02/03/23 01:560.5000.200<0.200µg/L1,1-Dichloropropene
02/03/23 01:560.5000.210<0.210µg/Lcis-1,3-Dichloropropene
02/03/23 01:560.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
02/03/23 01:5620042.0<42.0µg/LEthanol
02/03/23 01:560.5000.170<0.170µg/LEthylbenzene
02/03/23 01:563.000.350<0.350µg/LHexachlorobutadiene
02/03/23 01:561.000.380<0.380µg/L2-Hexanone
02/03/23 01:560.5000.180<0.180µg/LIsopropylbenzene
02/03/23 01:560.5000.089<0.089µg/L4-Isopropyl toluene
02/03/23 01:565.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
02/03/23 01:561.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/03/23 01:561.000.078<0.078µg/L4-Methyl-2-Pentanone
02/03/23 01:562.000.330<0.330µg/LMethylene Chloride
02/03/23 01:561.000.470<0.470µg/LNaphthalene
02/03/23 01:560.5000.190<0.190µg/Ln-Propylbenzene
02/03/23 01:560.5000.220<0.220µg/LStyrene
02/03/23 01:5610.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
02/03/23 01:5610.00.350<0.350µg/Ltert-Butyl formate (TBF)
02/03/23 01:5610.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
02/03/23 01:5610.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
02/03/23 01:560.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 2 of 15Date:02/07/2023 06:41 PM
Page 46 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
Associated Lab Samples: 98716, 98717, 98718
LRB-V29448 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 01:560.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
02/03/23 01:560.5000.220<0.220µg/LTetrachloroethene
02/03/23 01:560.5000.220<0.220µg/LToluene
02/03/23 01:560.5000.380<0.380µg/L1,2,3-Trichlorobenzene
02/03/23 01:560.5000.310<0.310µg/L1,2,4-Trichlorobenzene
02/03/23 01:560.5000.160<0.160µg/L1,1,1-Trichloroethane
02/03/23 01:560.5000.096<0.096µg/L1,1,2-Trichloroethane
02/03/23 01:560.5000.180<0.180µg/LTrichloroethene
02/03/23 01:560.5000.180<0.180µg/LTrichlorofluoromethane
02/03/23 01:560.5000.270<0.270µg/L1,2,3-Trichloropropane
02/03/23 01:560.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/03/23 01:560.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/03/23 01:565.001.00<1.00µg/LVinyl Acetate
02/03/23 01:560.5000.170<0.170µg/LVinyl Chloride
02/03/23 01:560.5000.210<0.210µg/Lo-Xylene
02/03/23 01:561.000.420<0.420µg/Lm,p-Xylene
02/03/23 01:5610.01.00<1.00µg/L3,3-Dimethyl-1-butanol
02/03/23 01:564-Bromofluorobenzene (S)99.2 70-130
02/03/23 01:56Dibromofluoromethane (S)99.0 70-130
02/03/23 01:561,2-Dichloroethane - d4 (S)90.2 70-130
02/03/23 01:56Toluene-d8 (S)99.8 70-130
LCS-V29448 LCSD-V29448Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.0 10811646.340.0µg/LAcetone 40-160 7.3 20.0
Page 3 of 15Date:02/07/2023 06:41 PM
Page 47 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
LCS-V29448 LCSD-V29448Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.3 96.598.519.720.0µg/LBenzene 70-130 2.0 20.0
17.9 89.590.018.020.0µg/LBromobenzene 70-130 0.5 20.0
20.6 10310721.320.0µg/LBromochloromethane 70-130 3.3 20.0
19.8 99.099.019.820.0µg/LBromodichloromethane 70-130 0.0 20.0
22.1 11111422.720.0µg/LBromoform 70-130 2.6 20.0
15.0 75.074.014.820.0µg/LBromomethane 60-140 1.3 20.0
18.7 93.596.519.320.0µg/Ln-Butylbenzene 70-130 3.1 20.0
18.9 94.596.019.220.0µg/Lsec-Butyl benzene 70-130 1.5 20.0
19.0 95.095.019.020.0µg/Ltert-Butyl benzene 70-130 0.0 20.0
21.8 109134*26.720.0µg/LCarbon Tetrachloride 70-130 20.2*20.0
19.3 96.598.519.720.0µg/LChlorobenzene 70-130 2.0 20.0
20.6 10310621.120.0µg/LChlorodibromomethane 70-130 2.3 20.0
19.7 98.510320.520.0µg/LChloroethane 60-140 3.9 20.0
20.2 10110320.620.0µg/LChloroform 70-130 1.9 20.0
17.9 89.595.519.120.0µg/LChloromethane 60-140 6.4 20.0
18.3 91.595.519.120.0µg/L2-Chlorotoluene 70-130 4.2 20.0
19.0 95.096.519.320.0µg/L4-Chlorotoluene 70-130 1.5 20.0
20.3 10210521.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.3 20.0
20.9 10511021.920.0µg/L1,2-Dibromo-3-Chloropropane 70-130 4.6 20.0
18.3 91.592.018.420.0µg/LDibromomethane 70-130 0.5 20.0
19.9 99.599.519.920.0µg/L1,2-Dichlorobenzene 70-130 0.0 20.0
19.7 98.510120.220.0µg/L1,3-Dichlorobenzene 70-130 2.5 20.0
19.9 99.510420.720.0µg/L1,4-Dichlorobenzene 70-130 3.9 20.0
20.6 10311322.620.0µg/LDichlorodifluoromethane 60-140 9.2 20.0
19.7 98.510521.020.0µg/L1,1-Dichloroethane 70-130 6.3 20.0
18.5 92.598.019.620.0µg/L1,2-Dichloroethane 70-130 5.7 20.0
Page 4 of 15* QC Fail Date:02/07/2023 06:41 PM
Page 48 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
LCS-V29448 LCSD-V29448Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.6 98.010320.620.0µg/L1,1-Dichloroethene 70-130 4.9 20.0
18.9 94.510020.020.0µg/Lcis-1,2-Dichloroethene 70-130 5.6 20.0
17.6 88.095.519.120.0µg/Ltrans-1,2-Dichloroethene 70-130 8.1 20.0
19.4 97.095.519.120.0µg/L1,2-Dichloropropane 70-130 1.5 20.0
18.6 93.095.019.020.0µg/L1,3-Dichloropropane 70-130 2.1 20.0
18.6 93.097.019.420.0µg/L2,2-Dichloropropane 70-130 4.2 20.0
21.4 10711022.020.0µg/L1,1-Dichloropropene 70-130 2.7 20.0
20.0 10010220.420.0µg/Lcis-1,3-Dichloropropene 70-130 1.9 20.0
19.0 95.099.019.820.0µg/Ltrans-1,3-Dichloropropene 70-130 4.1 20.0
576 115120599500µg/LEthanol 60-140 3.9 20.0
19.0 95.096.519.320.0µg/LEthylbenzene 70-130 1.5 20.0
22.2 11111222.420.0µg/LHexachlorobutadiene 70-130 0.8 20.0
17.3 86.587.017.420.0µg/L2-Hexanone 60-140 0.5 20.0
19.0 95.010120.220.0µg/LIsopropylbenzene 70-130 6.1 20.0
19.7 98.510020.020.0µg/L4-Isopropyl toluene 70-130 1.5 20.0
17.4 87.094.518.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 8.2 20.0
18.7 93.597.019.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.6 20.0
16.6 83.086.517.320.0µg/L4-Methyl-2-Pentanone 60-140 4.1 20.0
17.9 89.594.018.820.0µg/LMethylene Chloride 70-130 4.9 20.0
18.2 91.093.518.720.0µg/LNaphthalene 70-130 2.7 20.0
18.4 92.095.519.120.0µg/Ln-Propylbenzene 70-130 3.7 20.0
20.5 10310120.120.0µg/LStyrene 70-130 1.9 20.0
31.5 78.790.536.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 13.8 20.0
35.1 87.786.534.640.0µg/Ltert-Butyl formate (TBF)40-140 1.4 20.0
16.7 83.594.518.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 12.3 20.0
39.4 98.599.539.840.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.0 20.0
Page 5 of 15Date:02/07/2023 06:41 PM
Page 49 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29449QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29448
LCS-V29448 LCSD-V29448Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.9 10510320.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0
18.8 94.093.518.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.5 20.0
19.8 99.010320.520.0µg/LTetrachloroethene 70-130 3.4 20.0
18.9 94.598.519.720.0µg/LToluene 70-130 4.1 20.0
19.6 98.099.019.820.0µg/L1,2,3-Trichlorobenzene 70-130 1.0 20.0
19.9 99.510220.420.0µg/L1,2,4-Trichlorobenzene 70-130 2.4 20.0
20.3 10210320.520.0µg/L1,1,1-Trichloroethane 70-130 0.9 20.0
18.3 91.598.019.620.0µg/L1,1,2-Trichloroethane 70-130 6.8 20.0
19.9 99.510220.320.0µg/LTrichloroethene 70-130 1.9 20.0
19.4 97.010220.320.0µg/LTrichlorofluoromethane 60-140 4.5 20.0
17.4 87.083.516.720.0µg/L1,2,3-Trichloropropane 70-130 4.1 20.0
18.5 92.596.519.320.0µg/L1,2,4-Trimethylbenzene 70-130 4.2 20.0
19.2 96.097.019.420.0µg/L1,3,5-Trimethylbenzene 70-130 1.0 20.0
18.2 91.083.516.720.0µg/LVinyl Acetate 60-140 8.5 20.0
19.7 98.598.019.620.0µg/LVinyl Chloride 60-140 0.5 20.0
18.8 94.096.019.220.0µg/Lo-Xylene 70-130 2.1 20.0
38.6 96.597.739.140.0µg/Lm,p-Xylene 70-130 1.2 20.0
17.4 87.085.017.020.0µg/L3,3-Dimethyl-1-butanol 70-130 2.3 20.0
95.697.44-Bromofluorobenzene (S)70-130
104104Dibromofluoromethane (S)70-130
93.296.81,2-Dichloroethane - d4 (S)70-130
99.2101Toluene-d8 (S)70-130
Page 6 of 15Date:02/07/2023 06:41 PM
Page 50 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29529QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29528
Associated Lab Samples: 98716, 98717, 98718
LRB-V29528 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 13:580.5000.180<0.180µg/LBenzene
02/03/23 13:580.5000.170<0.170µg/LEthylbenzene
02/03/23 13:581.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/03/23 13:5810.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
02/03/23 13:5810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
02/03/23 13:580.5000.220<0.220µg/LToluene
02/03/23 13:580.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/03/23 13:580.5000.210<0.210µg/Lo-Xylene
02/03/23 13:581.000.420<0.420µg/Lm,p-Xylene
02/03/23 13:584-Bromofluorobenzene (S)100 70-130
02/03/23 13:58Dibromofluoromethane (S)97.6 70-130
02/03/23 13:581,2-Dichloroethane - d4 (S)98.2 70-130
02/03/23 13:58Toluene-d8 (S)100 70-130
LCS-V29528 LCSD-V29528Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.510120.220.0µg/LBenzene 70-130 1.4 20.0
19.8 99.010320.620.0µg/LEthylbenzene 70-130 3.9 20.0
21.3 10710721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.4 20.0
38.6 96.590.736.340.0µg/Ltert-Butyl Alcohol (TBA)40-140 6.1 20.0
21.1 10612524.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 16.5 20.0
20.2 10110120.120.0µg/LToluene 70-130 0.4 20.0
21.3 10710921.720.0µg/L1,2,4-Trimethylbenzene 70-130 1.8 20.0
21.1 10610721.320.0µg/Lo-Xylene 70-130 0.9 20.0
42.3 10611043.840.0µg/Lm,p-Xylene 70-130 3.4 20.0
Page 7 of 15Date:02/07/2023 06:41 PM
Page 51 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29529QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29528
LCS-V29528 LCSD-V29528Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
10098.64-Bromofluorobenzene (S)70-130
98.696.8Dibromofluoromethane (S)70-130
99.099.01,2-Dichloroethane - d4 (S)70-130
100101Toluene-d8 (S)70-130
Page 8 of 15Date:02/07/2023 06:41 PM
Page 52 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
Associated Lab Samples: 98719
LRB-V29530 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 14:2610.01.80<1.80µg/LAcetone
02/03/23 14:260.5000.180<0.180µg/LBenzene
02/03/23 14:260.5000.210<0.210µg/LBromobenzene
02/03/23 14:261.000.420<0.420µg/LBromochloromethane
02/03/23 14:260.5000.160<0.160µg/LBromodichloromethane
02/03/23 14:265.001.50<1.50µg/LBromoform
02/03/23 14:261.000.280<0.280µg/LBromomethane
02/03/23 14:260.5000.180<0.180µg/Ln-Butylbenzene
02/03/23 14:260.5000.200<0.200µg/Lsec-Butyl benzene
02/03/23 14:262.000.920<0.920µg/Ltert-Butyl benzene
02/03/23 14:260.5000.180<0.180µg/LCarbon Tetrachloride
02/03/23 14:260.5000.190<0.190µg/LChlorobenzene
02/03/23 14:260.5000.190<0.190µg/LChlorodibromomethane
02/03/23 14:261.000.430<0.430µg/LChloroethane
02/03/23 14:260.5000.220<0.220µg/LChloroform
02/03/23 14:260.5000.220<0.220µg/LChloromethane
02/03/23 14:260.5000.200<0.200µg/L2-Chlorotoluene
02/03/23 14:260.5000.200<0.200µg/L4-Chlorotoluene
02/03/23 14:260.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
02/03/23 14:262.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
02/03/23 14:260.5000.200<0.200µg/L1,2-Dibromoethane
02/03/23 14:260.5000.230<0.230µg/LDibromomethane
02/03/23 14:260.5000.220<0.220µg/L1,2-Dichlorobenzene
02/03/23 14:260.5000.190<0.190µg/L1,3-Dichlorobenzene
02/03/23 14:260.5000.210<0.210µg/L1,4-Dichlorobenzene
02/03/23 14:265.001.20<1.20µg/LDichlorodifluoromethane
02/03/23 14:260.5000.240<0.240µg/L1,1-Dichloroethane
Page 9 of 15Date:02/07/2023 06:41 PM
Page 53 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
Associated Lab Samples: 98719
LRB-V29530 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 14:260.5000.150<0.150µg/L1,2-Dichloroethane
02/03/23 14:260.5000.150<0.150µg/L1,1-Dichloroethene
02/03/23 14:260.5000.200<0.200µg/Lcis-1,2-Dichloroethene
02/03/23 14:260.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
02/03/23 14:260.5000.190<0.190µg/L1,2-Dichloropropane
02/03/23 14:260.5000.130<0.130µg/L1,3-Dichloropropane
02/03/23 14:262.000.210<0.210µg/L2,2-Dichloropropane
02/03/23 14:260.5000.200<0.200µg/L1,1-Dichloropropene
02/03/23 14:260.5000.210<0.210µg/Lcis-1,3-Dichloropropene
02/03/23 14:260.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
02/03/23 14:2620042.0<42.0µg/LEthanol
02/03/23 14:260.5000.170<0.170µg/LEthylbenzene
02/03/23 14:263.000.350<0.350µg/LHexachlorobutadiene
02/03/23 14:261.000.380<0.380µg/L2-Hexanone
02/03/23 14:260.5000.180<0.180µg/LIsopropylbenzene
02/03/23 14:260.5000.089<0.089µg/L4-Isopropyl toluene
02/03/23 14:265.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
02/03/23 14:261.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/03/23 14:261.000.078<0.078µg/L4-Methyl-2-Pentanone
02/03/23 14:262.000.330<0.330µg/LMethylene Chloride
02/03/23 14:261.000.470<0.470µg/LNaphthalene
02/03/23 14:260.5000.190<0.190µg/Ln-Propylbenzene
02/03/23 14:260.5000.220<0.220µg/LStyrene
02/03/23 14:260.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
02/03/23 14:260.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
02/03/23 14:260.5000.220<0.220µg/LTetrachloroethene
02/03/23 14:260.5000.220<0.220µg/LToluene
Page 10 of 15Date:02/07/2023 06:41 PM
Page 54 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
Associated Lab Samples: 98719
LRB-V29530 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 14:260.5000.380<0.380µg/L1,2,3-Trichlorobenzene
02/03/23 14:260.5000.310<0.310µg/L1,2,4-Trichlorobenzene
02/03/23 14:260.5000.160<0.160µg/L1,1,1-Trichloroethane
02/03/23 14:260.5000.096<0.096µg/L1,1,2-Trichloroethane
02/03/23 14:260.5000.180<0.180µg/LTrichloroethene
02/03/23 14:260.5000.180<0.180µg/LTrichlorofluoromethane
02/03/23 14:260.5000.270<0.270µg/L1,2,3-Trichloropropane
02/03/23 14:260.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/03/23 14:260.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/03/23 14:265.001.00<1.00µg/LVinyl Acetate
02/03/23 14:260.5000.170<0.170µg/LVinyl Chloride
02/03/23 14:260.5000.210<0.210µg/Lo-Xylene
02/03/23 14:261.000.420<0.420µg/Lm,p-Xylene
02/03/23 14:264-Bromofluorobenzene (S)99.2 70-130
02/03/23 14:26Dibromofluoromethane (S)100 70-130
02/03/23 14:261,2-Dichloroethane - d4 (S)91.8 70-130
02/03/23 14:26Toluene-d8 (S)98.6 70-130
LCS-V29530 LCSD-V29530Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.6 10210843.340.0µg/LAcetone 40-160 6.4 20.0
19.0 95.096.519.320.0µg/LBenzene 70-130 1.5 20.0
18.2 91.092.018.420.0µg/LBromobenzene 70-130 1.0 20.0
19.5 97.510521.020.0µg/LBromochloromethane 70-130 7.4 20.0
19.9 99.510120.120.0µg/LBromodichloromethane 70-130 1.0 20.0
Page 11 of 15Date:02/07/2023 06:41 PM
Page 55 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
LCS-V29530 LCSD-V29530Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.6 10811022.020.0µg/LBromoform 70-130 1.8 20.0
17.1 85.587.517.520.0µg/LBromomethane 60-140 2.3 20.0
19.1 95.596.019.220.0µg/Ln-Butylbenzene 70-130 0.5 20.0
19.3 96.596.519.320.0µg/Lsec-Butyl benzene 70-130 0.0 20.0
19.2 96.097.519.520.0µg/Ltert-Butyl benzene 70-130 1.5 20.0
20.7 10410020.020.0µg/LCarbon Tetrachloride 70-130 3.4 20.0
20.0 10098.519.720.0µg/LChlorobenzene 70-130 1.5 20.0
21.5 10810320.620.0µg/LChlorodibromomethane 70-130 4.2 20.0
19.8 99.010220.420.0µg/LChloroethane 60-140 2.9 20.0
19.2 96.099.519.920.0µg/LChloroform 70-130 3.5 20.0
18.4 92.095.519.120.0µg/LChloromethane 60-140 3.7 20.0
19.5 97.596.019.220.0µg/L2-Chlorotoluene 70-130 1.5 20.0
19.3 96.594.518.920.0µg/L4-Chlorotoluene 70-130 2.0 20.0
19.4 97.099.519.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.5 20.0
20.6 10399.519.920.0µg/L1,2-Dibromo-3-Chloropropane 70-130 3.4 20.0
20.3 10298.519.720.0µg/L1,2-Dibromoethane 70-130 3.0 20.0
17.5 87.590.518.120.0µg/LDibromomethane 70-130 3.3 20.0
20.1 10110120.120.0µg/L1,2-Dichlorobenzene 70-130 0.0 20.0
19.8 99.099.519.920.0µg/L1,3-Dichlorobenzene 70-130 0.5 20.0
20.3 10210020.020.0µg/L1,4-Dichlorobenzene 70-130 1.4 20.0
21.8 10911322.520.0µg/LDichlorodifluoromethane 60-140 3.1 20.0
19.6 98.010120.220.0µg/L1,1-Dichloroethane 70-130 3.0 20.0
18.0 90.094.518.920.0µg/L1,2-Dichloroethane 70-130 4.8 20.0
19.2 96.095.019.020.0µg/L1,1-Dichloroethene 70-130 1.0 20.0
19.0 95.098.019.620.0µg/Lcis-1,2-Dichloroethene 70-130 3.1 20.0
17.3 86.588.517.720.0µg/Ltrans-1,2-Dichloroethene 70-130 2.2 20.0
Page 12 of 15Date:02/07/2023 06:41 PM
Page 56 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
LCS-V29530 LCSD-V29530Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.8 94.096.519.320.0µg/L1,2-Dichloropropane 70-130 2.6 20.0
18.4 92.090.518.120.0µg/L1,3-Dichloropropane 70-130 1.6 20.0
18.4 92.098.519.720.0µg/L2,2-Dichloropropane 70-130 6.8 20.0
21.3 10710220.320.0µg/L1,1-Dichloropropene 70-130 4.8 20.0
19.2 96.098.519.720.0µg/Lcis-1,3-Dichloropropene 70-130 2.5 20.0
19.5 97.594.518.920.0µg/Ltrans-1,3-Dichloropropene 70-130 3.1 20.0
400 80.0113564500µg/LEthanol 60-140 34.0*20.0
19.0 95.092.518.520.0µg/LEthylbenzene 70-130 2.6 20.0
22.1 11111222.420.0µg/LHexachlorobutadiene 70-130 1.3 20.0
16.5 82.583.016.620.0µg/L2-Hexanone 60-140 0.6 20.0
19.6 98.098.519.720.0µg/LIsopropylbenzene 70-130 0.5 20.0
19.4 97.099.019.820.0µg/L4-Isopropyl toluene 70-130 2.0 20.0
15.9 79.589.017.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 11.2 20.0
17.9 89.591.018.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.6 20.0
15.6 78.082.016.420.0µg/L4-Methyl-2-Pentanone 60-140 5.0 20.0
17.3 86.588.017.620.0µg/LMethylene Chloride 70-130 1.7 20.0
17.6 88.092.518.520.0µg/LNaphthalene 70-130 4.9 20.0
19.1 95.595.519.120.0µg/Ln-Propylbenzene 70-130 0.0 20.0
20.1 10110320.620.0µg/LStyrene 70-130 2.4 20.0
20.8 10499.019.820.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.9 20.0
17.9 89.595.019.020.0µg/L1,1,2,2-Tetrachloroethane 70-130 5.9 20.0
21.6 10810621.220.0µg/LTetrachloroethene 70-130 1.8 20.0
18.7 93.595.019.020.0µg/LToluene 70-130 1.5 20.0
19.9 99.510721.420.0µg/L1,2,3-Trichlorobenzene 70-130 7.2 20.0
20.0 10010020.020.0µg/L1,2,4-Trichlorobenzene 70-130 0.0 20.0
19.6 98.098.519.720.0µg/L1,1,1-Trichloroethane 70-130 0.5 20.0
Page 13 of 15* QC Fail Date:02/07/2023 06:41 PM
Page 57 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29531QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29530
LCS-V29530 LCSD-V29530Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.4 92.092.518.520.0µg/L1,1,2-Trichloroethane 70-130 0.5 20.0
19.5 97.596.019.220.0µg/LTrichloroethene 70-130 1.5 20.0
20.4 10210420.820.0µg/LTrichlorofluoromethane 60-140 1.9 20.0
17.2 86.087.017.420.0µg/L1,2,3-Trichloropropane 70-130 1.1 20.0
19.5 97.596.019.220.0µg/L1,2,4-Trimethylbenzene 70-130 1.5 20.0
19.5 97.597.519.520.0µg/L1,3,5-Trimethylbenzene 70-130 0.0 20.0
19.6 98.011522.920.0µg/LVinyl Acetate 60-140 15.5 20.0
19.5 97.510220.420.0µg/LVinyl Chloride 60-140 4.5 20.0
19.3 96.595.519.120.0µg/Lo-Xylene 70-130 1.0 20.0
39.6 99.097.038.840.0µg/Lm,p-Xylene 70-130 2.0 20.0
97.299.84-Bromofluorobenzene (S)70-130
100101Dibromofluoromethane (S)70-130
93.895.21,2-Dichloroethane - d4 (S)70-130
10297.8Toluene-d8 (S)70-130
Page 14 of 15Date:02/07/2023 06:41 PM
Page 58 of 61
Quality Control Data
23-030-0031Report No:
Project Description:
Client ID:Geological Resources, Inc.
Silver Express
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V29322QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V29321
Associated Lab Samples: 98716, 98717, 98718
LRB-V29321 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/31/23 12:5950.011.5<11.5µg/LAliphatic C5-C8
01/31/23 12:5950.025.8<25.8µg/LAliphatic C9-C12
01/31/23 12:5950.04.02<4.02µg/LAromatic C9-C10
01/31/23 12:592,5-Dibromotoluene (FID) (S)97.3 70-130
01/31/23 12:592,5-Dibromotoluene (PID) (S)91.9 70-130
LCS-V29321 LCSD-V29321Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
324 108103309300µg/LAliphatic C5-C8 70-130 4.7 50.0
363 121123369300µg/LAliphatic C9-C12 70-130 1.6 50.0
108 108106106100µg/LAromatic C9-C10 70-130 1.8 50.0
87.278.92,5-Dibromotoluene (FID) (S)70-130
78.077.32,5-Dibromotoluene (PID) (S)70-130
Page 15 of 15Date:02/07/2023 06:41 PM
Page 59 of 61
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-030-0031
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:01/30/2023 18:49:47
Special precautions or instructions included?
Comments:
Page 60 of 61
Page 61 of 61