MO-9494_47003_CA_LTRRPT_20231109

100 East Ruffin Street, Mebane, North Carolina 27302
Telephone [phone] ·Facsimile [phone]
www.terraquestpc.com
November 9, 2023

Brad C. Newton, P.G. VIA EMAIL
NCDWM-UST Mooresville Regional Office
610 East Center Avenue, Suite 301, Mooresville, NC 28115

Re: Letter Report (PAF-016 PW sampling)
Little Market Basket #1, 3541 Taylorsville Hwy., Statesville, Iredell County, NC
NCDWM-UST Incident No. 47003 // Terraquest Project No. 09419

Dear Mr. Newton,

On behalf of Bumgarner Oil Company, Inc., Terraquest Environmental Consultants, P.C. is providing
the results of potable well sampling associated with the release incident at Little Market Basket #1 in
Statesville, NC. The sampling was requested by the NCDWM-UST in a August 14, 2023
correespondence. Costs for the work were pre-approved on ePATA 47003-016. The site’s location,
vicinity, and layout are shown on the attached Figures 1, 2, and 3.

Terraquest personnel wearing new disposable nitrile gloves, collected a groundwater sample from
the potable well at the Mitchell residence (PW1 (MITCHELL)) on October 25, 2023. The spigot was
first allowed to flow for sufficient time to purge plumbing and allow for the collection of a sample
representative of the aquifer. The sample was collected directly into the laboratory-provided
containers. The containers were labeled, packed on ice, and shipped to an NC-certified laboratory
for analysis per 6200B.

As shown on the attached Table 1 and analytical report, the results did not have any petroleum-type
compounds reported at concentrations in excess of the lab’s reporting limit.

If you have any questions regarding this report, please contact us at [phone].

Sincerely,

TERRAQUEST ENVIRONMENTAL CONSULTANTS, P.C.

Ryan D. Kerins
Project Manager

Attachments
cc: Bumgarner Oil Company, Inc. – Zach Bumgarner
NVIRONMENTAL ONSULTANTS, P.C.E C
Table 1
Date: 11/9/23
6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200BWell ID
Date
Collected
PW1 10/25/23 < 0.500 < 0.900 < 0.500 < 1.60 < 0.220 < 0.200 < 24.0 < 0.530 < 3.00 < 0.760 < 0.690 < 0.710 < 0.700
1 600 600 500 20 70 4,000 70 6 70 70 25 70
5,000 260,000 84,500 85,500 20,000 70,000 4,000,000 25,000 6,000 6,900 30,000 11,700 8,500
Notes:
1. All results in µg/L.
2. Bold denotes a compound detection
3. Shading denotes a 2L Standard violation
4. Italics denotes a GCL violation.
5. < - denotes less than sample detection limit p-Isopropyltoluenesec-Butylbenzene2L StandardGCL Diisopropyl etherEthanolIsopropylbenzeneNaphthalenen-ButylbenzeneN-PropylbenzeneSUMMARY OF GROUNDWATER SAMPLING RESULTS
Incident Name: Little Market Basket #1 Incident No. 47003 Facility ID No.: 00-0-0000021441
Analytical Method
Contaminant of Concern
BenzeneTolueneEthylbenzeneXylenes, TotalMethyl tert-butyl ether
ANALYTICAL REPORT
PREPARED FOR
Attn: Ryan Kerins
Terraquest Environmental Consultants, PC
100 E. Ruffin Street
Mebane, North Carolina 27302
Generated 11/8/2023 5:55:20 PM
JOB DESCRIPTION
Little Market Basket
JOB NUMBER
400-245655-1
See page two for job notes and contact information.
Pensacola FL 32514
3355 McLemore Drive
Eurofins Pensacola
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Eurofins Pensacola
Eurofins Pensacola is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
11/8/2023 5:55:20 PM
Authorized for release by
Chad Bechtold, Project Manager
[e-mail]
[phone]
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Table of Contents
Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Laboratory Job ID: 400-245655-1
Page 3 of 20 Eurofins Pensacola11/8/2023
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
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Case Narrative
Client: Terraquest Environmental Consultants, PC Job ID: 400-245655-1
Project/Site: Little Market Basket
Job ID: 400-245655-1
Laboratory: Eurofins Pensacola
Narrative
Job Narrative
400-245655-1
Receipt
The sample was received on 10/26/2023 8:49 AM. Unless otherwise noted below, the sample arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 1.0°C
GC/MS VOA
Method SM6200_B: The following analyte recovered outside control limits for the Laboratory Control Sample (LCS) associated with
analytical batch 400-648802: Dichlorodifluoromethane. This is not indicative of a systematic control problem because this was a random
marginal exceedance. Qualified results have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Detection Summary
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Client Sample ID: PW1 Lab Sample ID: 400-245655-1
No Detections.
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
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Sample Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-245655-1
Project/Site: Little Market Basket
Lab Sample ID Client Sample ID Matrix Collected Received
400-245655-1 PW1 Water 10/25/23 14:40 10/26/23 08:49
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Client Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Lab Sample ID: 400-245655-1Client Sample ID: PW1
Matrix: WaterDate Collected: 10/25/23 14:40
Date Received: 10/26/23 08:49
Method: SM6200-B - Volatile Organic Compounds
RL MDL
0.160 U 1.00 0.160 ug/L 11/06/23 16:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.180 ug/L 11/06/23 16:25 10.180 U1,1,1-Trichloroethane
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,1,2,2-Tetrachloroethane
5.00 0.210 ug/L 11/06/23 16:25 10.210 U1,1,2-Trichloroethane
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,1-Dichloroethane
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,1-Dichloroethene
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,1-Dichloropropene
1.00 0.900 ug/L 11/06/23 16:25 10.900 U1,2,3-Trichlorobenzene
5.00 0.840 ug/L 11/06/23 16:25 10.840 U1,2,3-Trichloropropane
1.00 0.820 ug/L 11/06/23 16:25 10.820 U1,2,4-Trichlorobenzene
1.00 0.820 ug/L 11/06/23 16:25 10.820 U1,2,4-Trimethylbenzene
1.00 0.230 ug/L 11/06/23 16:25 10.230 U1,2-Dibromoethane (EDB)
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,2-Dichlorobenzene
1.00 0.190 ug/L 11/06/23 16:25 10.190 U1,2-Dichloroethane
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,2-Dichloropropane
1.00 0.560 ug/L 11/06/23 16:25 10.560 U1,3,5-Trimethylbenzene
1.00 0.540 ug/L 11/06/23 16:25 10.540 U1,3-Dichlorobenzene
1.00 0.500 ug/L 11/06/23 16:25 10.500 U1,3-Dichloropropane
1.00 0.640 ug/L 11/06/23 16:25 10.640 U1,4-Dichlorobenzene
1.00 0.500 ug/L 11/06/23 16:25 10.500 U2,2-Dichloropropane
25.0 2.60 ug/L 11/06/23 16:25 12.60 U2-Butanone (MEK)
1.00 0.570 ug/L 11/06/23 16:25 10.570 U2-Chlorotoluene
25.0 1.40 ug/L 11/06/23 16:25 11.40 U2-Hexanone
1.00 0.560 ug/L 11/06/23 16:25 10.560 U4-Chlorotoluene
25.0 1.80 ug/L 11/06/23 16:25 11.80 U4-Methyl-2-pentanone (MIBK)
25.0 10.0 ug/L 11/06/23 16:25 110.0 UAcetone
1.00 0.500 ug/L 11/06/23 16:25 10.500 UBenzene
1.00 0.540 ug/L 11/06/23 16:25 10.540 UBromobenzene
1.00 0.210 ug/L 11/06/23 16:25 10.210 UBromochloromethane
1.00 0.500 ug/L 11/06/23 16:25 10.500 UBromodichloromethane
5.00 0.250 ug/L 11/06/23 16:25 10.250 UBromoform
1.00 0.980 ug/L 11/06/23 16:25 10.980 UBromomethane
1.00 0.190 ug/L 11/06/23 16:25 10.190 UCarbon tetrachloride
1.00 0.900 ug/L 11/06/23 16:25 10.900 UChlorobenzene
1.00 0.760 ug/L 11/06/23 16:25 10.760 UChloroethane
1.00 0.900 ug/L 11/06/23 16:25 10.900 UChloroform
1.00 0.900 ug/L 11/06/23 16:25 10.900 UChloromethane
1.00 0.200 ug/L 11/06/23 16:25 10.200 Ucis-1,2-Dichloroethene
5.00 0.500 ug/L 11/06/23 16:25 10.500 Ucis-1,3-Dichloropropene
1.00 0.240 ug/L 11/06/23 16:25 10.240 UDibromochloromethane
1.00 0.850 ug/L 11/06/23 16:25 10.850 U *-Dichlorodifluoromethane
1.00 0.200 ug/L 11/06/23 16:25 10.200 UDiisopropyl ether
100 24.0 ug/L 11/06/23 16:25 124.0 UEthanol
1.00 0.500 ug/L 11/06/23 16:25 10.500 UEthylbenzene
1.00 0.530 ug/L 11/06/23 16:25 10.530 UIsopropylbenzene
1.00 0.220 ug/L 11/06/23 16:25 10.220 UMethyl tert-butyl ether
5.00 3.00 ug/L 11/06/23 16:25 13.00 UMethylene Chloride
5.00 0.630 ug/L 11/06/23 16:25 10.630 Um-Xylene & p-Xylene
5.00 3.00 ug/L 11/06/23 16:25 13.00 UNaphthalene
Eurofins Pensacola
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Client Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Lab Sample ID: 400-245655-1Client Sample ID: PW1
Matrix: WaterDate Collected: 10/25/23 14:40
Date Received: 10/26/23 08:49
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
0.760 U 1.00 0.760 ug/L 11/06/23 16:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Butylbenzene
1.00 0.690 ug/L 11/06/23 16:25 10.690 UN-Propylbenzene
5.00 0.600 ug/L 11/06/23 16:25 10.600 Uo-Xylene
1.00 0.710 ug/L 11/06/23 16:25 10.710 Up-Cymene (p-Isopropyltoluene)
1.00 0.700 ug/L 11/06/23 16:25 10.700 Usec-Butylbenzene
1.00 1.00 ug/L 11/06/23 16:25 11.00 UStyrene
1.00 0.630 ug/L 11/06/23 16:25 10.630 Utert-Butylbenzene
1.00 0.900 ug/L 11/06/23 16:25 10.900 UTetrachloroethene
1.00 0.900 ug/L 11/06/23 16:25 10.900 UToluene
1.00 0.500 ug/L 11/06/23 16:25 10.500 Utrans-1,2-Dichloroethene
5.00 0.200 ug/L 11/06/23 16:25 10.200 Utrans-1,3-Dichloropropene
1.00 0.150 ug/L 11/06/23 16:25 10.150 UTrichloroethene
1.00 0.520 ug/L 11/06/23 16:25 10.520 UTrichlorofluoromethane
25.0 0.930 ug/L 11/06/23 16:25 10.930 UVinyl acetate
1.00 0.500 ug/L 11/06/23 16:25 10.500 UVinyl chloride
10.0 1.60 ug/L 11/06/23 16:25 11.60 UXylenes, Total
4-Bromofluorobenzene 112 72-130 11/06/23 16:25 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 93 11/06/23 16:25 175-126
Toluene-d8 (Surr)109 11/06/23 16:25 164-132
Eurofins Pensacola
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Definitions/Glossary
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Qualifiers
GC/MS VOA
Qualifier Description
*-LCS and/or LCSD is outside acceptance limits, low biased.
Qualifier
U Indicates the analyte was analyzed for but not detected.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Pensacola
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Surrogate Summary
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (72-130)(75-126)(64-132)
BFB DBFM TOL
112 93 109400-245655-1
Percent Surrogate Recovery (Acceptance Limits)
PW1
105 94 103LCS 400-648802/1002 Lab Control Sample
104 92 104MB 400-648802/5 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Eurofins Pensacola
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QC Association Summary
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
GC/MS VOA
Analysis Batch: 648802
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-245655-1 PW1 Total/NA
Water SM6200-BMB 400-648802/5 Method Blank Total/NA
Water SM6200-BLCS 400-648802/1002 Lab Control Sample Total/NA
Eurofins Pensacola
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QC Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 400-648802/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 648802
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 11/06/23 08:37 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 11/06/23 08:37 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 11/06/23 08:37 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 11/06/23 08:37 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 11/06/23 08:37 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 11/06/23 08:37 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 11/06/23 08:37 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 11/06/23 08:37 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 11/06/23 08:37 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,2-Dichloropropane
0.560 U 0.5601.00 ug/L 11/06/23 08:37 11,3,5-Trimethylbenzene
0.540 U 0.5401.00 ug/L 11/06/23 08:37 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 11/06/23 08:37 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 11/06/23 08:37 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 11/06/23 08:37 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 11/06/23 08:37 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 11/06/23 08:37 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 11/06/23 08:37 12-Hexanone
0.560 U 0.5601.00 ug/L 11/06/23 08:37 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 11/06/23 08:37 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 11/06/23 08:37 1Acetone
0.500 U 0.5001.00 ug/L 11/06/23 08:37 1Benzene
0.540 U 0.5401.00 ug/L 11/06/23 08:37 1Bromobenzene
0.210 U 0.2101.00 ug/L 11/06/23 08:37 1Bromochloromethane
0.500 U 0.5001.00 ug/L 11/06/23 08:37 1Bromodichloromethane
0.250 U 0.2505.00 ug/L 11/06/23 08:37 1Bromoform
0.980 U 0.9801.00 ug/L 11/06/23 08:37 1Bromomethane
0.190 U 0.1901.00 ug/L 11/06/23 08:37 1Carbon tetrachloride
0.900 U 0.9001.00 ug/L 11/06/23 08:37 1Chlorobenzene
0.760 U 0.7601.00 ug/L 11/06/23 08:37 1Chloroethane
0.900 U 0.9001.00 ug/L 11/06/23 08:37 1Chloroform
0.900 U 0.9001.00 ug/L 11/06/23 08:37 1Chloromethane
0.200 U 0.2001.00 ug/L 11/06/23 08:37 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 11/06/23 08:37 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 11/06/23 08:37 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 11/06/23 08:37 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 11/06/23 08:37 1Diisopropyl ether
24.0 U 24.0100 ug/L 11/06/23 08:37 1Ethanol
0.500 U 0.5001.00 ug/L 11/06/23 08:37 1Ethylbenzene
0.530 U 0.5301.00 ug/L 11/06/23 08:37 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 11/06/23 08:37 1Methyl tert-butyl ether
3.00 U 3.005.00 ug/L 11/06/23 08:37 1Methylene Chloride
0.630 U 0.6305.00 ug/L 11/06/23 08:37 1m-Xylene & p-Xylene
Eurofins Pensacola
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QC Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-648802/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 648802
RL MDL
Naphthalene 3.00 U 5.00 3.00 ug/L 11/06/23 08:37 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.760 U 0.7601.00 ug/L 11/06/23 08:37 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 11/06/23 08:37 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 11/06/23 08:37 1o-Xylene
0.710 U 0.7101.00 ug/L 11/06/23 08:37 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 11/06/23 08:37 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 11/06/23 08:37 1Styrene
0.630 U 0.6301.00 ug/L 11/06/23 08:37 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 11/06/23 08:37 1Tetrachloroethene
0.900 U 0.9001.00 ug/L 11/06/23 08:37 1Toluene
0.500 U 0.5001.00 ug/L 11/06/23 08:37 1trans-1,2-Dichloroethene
0.200 U 0.2005.00 ug/L 11/06/23 08:37 1trans-1,3-Dichloropropene
0.150 U 0.1501.00 ug/L 11/06/23 08:37 1Trichloroethene
0.520 U 0.5201.00 ug/L 11/06/23 08:37 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 11/06/23 08:37 1Vinyl acetate
0.500 U 0.5001.00 ug/L 11/06/23 08:37 1Vinyl chloride
1.60 U 1.6010.0 ug/L 11/06/23 08:37 1Xylenes, Total
4-Bromofluorobenzene 104 72-130 11/06/23 08:37 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
92 11/06/23 08:37 1Dibromofluoromethane75-126
104 11/06/23 08:37 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-648802/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 648802
1,1,1,2-Tetrachloroethane 50.0 49.52 ug/L 99 67-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 42.66 ug/L 85 68-130
1,1,2,2-Tetrachloroethane 50.0 50.37 ug/L 101 70-131
1,1,2-Trichloroethane 50.0 51.55 ug/L 103 70-130
1,1-Dichloroethane 50.0 48.22 ug/L 96 70-130
1,1-Dichloroethene 50.0 40.29 ug/L 81 63-134
1,1-Dichloropropene 50.0 46.58 ug/L 93 70-130
1,2,3-Trichlorobenzene 50.0 59.92 ug/L 120 60-138
1,2,3-Trichloropropane 50.0 48.77 ug/L 98 70-130
1,2,4-Trichlorobenzene 50.0 59.55 ug/L 119 60-140
1,2,4-Trimethylbenzene 50.0 49.13 ug/L 98 70-130
1,2-Dibromoethane (EDB)50.0 49.57 ug/L 99 70-130
1,2-Dichlorobenzene 50.0 48.92 ug/L 98 67-130
1,2-Dichloroethane 50.0 42.21 ug/L 84 69-130
1,2-Dichloropropane 50.0 52.50 ug/L 105 70-130
1,3,5-Trimethylbenzene 50.0 49.50 ug/L 99 69-130
1,3-Dichlorobenzene 50.0 50.45 ug/L 101 70-130
1,3-Dichloropropane 50.0 52.17 ug/L 104 70-130
1,4-Dichlorobenzene 50.0 49.92 ug/L 100 70-130
2,2-Dichloropropane 50.0 43.73 ug/L 87 52-135
Eurofins Pensacola
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QC Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-648802/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 648802
2-Butanone (MEK)200 256.4 ug/L 128 61-145
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
2-Chlorotoluene 50.0 49.82 ug/L 100 70-130
2-Hexanone 200 248.5 ug/L 124 65-137
4-Chlorotoluene 50.0 48.26 ug/L 97 70-130
4-Methyl-2-pentanone (MIBK)200 209.0 ug/L 104 69-138
Acetone 200 232.0 ug/L 116 43-160
Benzene 50.0 47.48 ug/L 95 70-130
Bromobenzene 50.0 52.21 ug/L 104 70-132
Bromochloromethane 50.0 45.34 ug/L 91 70-130
Bromodichloromethane 50.0 48.22 ug/L 96 67-133
Bromoform 50.0 58.90 ug/L 118 57-140
Bromomethane 25.0 18.86 ug/L 75 10-160
Carbon tetrachloride 50.0 43.41 ug/L 87 61-137
Chlorobenzene 50.0 50.22 ug/L 100 70-130
Chloroethane 25.0 16.32 ug/L 65 55-141
Chloroform 50.0 44.35 ug/L 89 69-130
Chloromethane 25.0 17.03 ug/L 68 58-137
cis-1,2-Dichloroethene 50.0 49.08 ug/L 98 68-130
cis-1,3-Dichloropropene 50.0 50.63 ug/L 101 69-132
Dibromochloromethane 50.0 50.90 ug/L 102 67-135
Dichlorodifluoromethane 25.0 9.164 *-ug/L 37 41-146
Diisopropyl ether 50.0 53.70 ug/L 107 64-132
Ethanol 2000 1675 ug/L 84 20-160
Ethylbenzene 50.0 51.52 ug/L 103 70-130
Isopropylbenzene 50.0 48.73 ug/L 97 70-130
Methyl tert-butyl ether 50.0 47.99 ug/L 96 66-130
Methylene Chloride 50.0 43.95 ug/L 88 66-135
m-Xylene & p-Xylene 50.0 50.81 ug/L 102 70-130
Naphthalene 50.0 54.78 ug/L 110 47-149
n-Butylbenzene 50.0 51.27 ug/L 103 67-130
N-Propylbenzene 50.0 49.14 ug/L 98 70-130
o-Xylene 50.0 48.77 ug/L 98 70-130
p-Cymene (p-Isopropyltoluene)50.0 49.91 ug/L 100 65-130
sec-Butylbenzene 50.0 49.21 ug/L 98 66-130
Styrene 50.0 47.22 ug/L 94 70-130
tert-Butylbenzene 50.0 53.55 ug/L 107 64-139
Tetrachloroethene 50.0 48.95 ug/L 98 65-130
Toluene 50.0 52.42 ug/L 105 70-130
trans-1,2-Dichloroethene 50.0 45.57 ug/L 91 70-130
trans-1,3-Dichloropropene 50.0 51.42 ug/L 103 63-130
Trichloroethene 50.0 46.45 ug/L 93 70-130
Trichlorofluoromethane 25.0 16.62 ug/L 66 65-138
Vinyl acetate 50.0 45.56 ug/L 91 26-160
Vinyl chloride 25.0 18.27 ug/L 73 59-136
Xylenes, Total 100 99.58 ug/L 100 70-130
4-Bromofluorobenzene 72 -130
Surrogate
105
LCS LCS
Qualifier Limits%Recovery
Eurofins Pensacola
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QC Sample Results
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-648802/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 648802
Dibromofluoromethane 75 -126
Surrogate
94
LCS LCS
Qualifier Limits%Recovery
103Toluene-d8 (Surr)64 -132
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-245655-1
Project/Site: Little Market Basket
Client Sample ID: PW1 Lab Sample ID: 400-245655-1
Matrix: WaterDate Collected: 10/25/23 14:40
Date Received: 10/26/23 08:49
Analysis SM6200-B WPD11/06/23 16:251 EET PEN648802
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-648802/5
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B WPD11/06/23 08:371 EET PEN648802
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-648802/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B WPD11/06/23 07:301 EET PEN648802
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Method Summary
Job ID: 400-245655-1Client: Terraquest Environmental Consultants, PC
Project/Site: Little Market Basket
Method Method Description LaboratoryProtocol
SMSM6200-B Volatile Organic Compounds EET PEN
SW8465030BPurge and Trap EET PEN
Protocol References:
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Accreditation/Certification Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-245655-1
Project/Site: Little Market Basket
Laboratory: Eurofins Pensacola
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 314 12-31-23
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
SM6200-B Water 2-Butanone (MEK)
SM6200-B Water 2-Hexanone
SM6200-B Water 4-Methyl-2-pentanone (MIBK)
SM6200-B Water Acetone
SM6200-B Water Vinyl acetate
Eurofins Pensacola
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Login Sample Receipt Checklist
Client: Terraquest Environmental Consultants, PC Job Number: 400-245655-1
Login Number: 245655
Question Answer Comment
Creator: Roberts, Alexis J
List Source: Eurofins Pensacola
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
N/AThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.1.0°C IR8
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Pensacola
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