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HomeMy WebLinkAbout23061_Caraustar Mill Building Assessment Report_2021122001675-001/00351942-1 Brownfields Indoor Air and Sub- Slab Soil Gas Testing Report Caraustar and Savona Mills South Turner Avenue and Chamberlain Avenue Charlotte, Mecklenburg County, North Carolina NCBP #23061-19-060 December 20, 2021 Terracon Project No. 71167021 Prepared for: Savona II, LLC Charlotte, North Carolina Prepared by: Terracon Consultants, Inc. Charlotte, North Carolina ii TABLE OF CONTENTS 1.0 PROJECT BACKGROUND ............................................................................................ 1 1.1 Site Description .................................................................................................... 1 1.2 Site History .......................................................................................................... 1 1.3 Prior Investigations .............................................................................................. 2 1.4 Purpose of Soil Vapor Evaluation ......................................................................... 3 2.0 SCOPE OF SERVICES ................................................................................................... 3 2.1 Standard of Care.................................................................................................. 4 2.2 Additional Scope Limitations ................................................................................ 4 2.3 Reliance ............................................................................................................... 4 3.0 FIELD INVESTIGATION METHODS ............................................................................... 4 3.1 Indoor Air Sampling ............................................................................................. 5 3.2 Soil Vapor Sampling ............................................................................................ 6 4.0 ANALYTICAL RESULTS ................................................................................................ 7 4.1 Indoor Air Sample Results ................................................................................... 7 4.2 Soil Vapor Sample Results .................................................................................. 8 4.3 NCDEQ Risk Calculator ....................................................................................... 8 5.0 CONCLUSIONS .............................................................................................................. 9 Table Table 1 – Soil Vapor/Indoor Air Analytical Results-Savona Mill Building (2020 and 2021) Exhibits Exhibit 1 – Topographic Map Exhibit 2 – Site Diagram Exhibit 3 – Soil Vapor and Indoor Air Sample Location Map – Savona Mill Building Appendices APPENDIX A – FIELD NOTES/DOCUMENTATION APPENDIX B – LABORATORY ANALYTICAL REPORT APPENDIX C – NCDEQ RISK CALCULATOR SUMMARY Responsive ■ Resourceful ■ Reliable 1 BROWNFIELDS INDOOR AIR AND SUB-SLAB SOIL GAS TESTING REPORT CARAUSTAR AND SAVONA MILLS SOUTH TURNER AVENUE AND CHAMBERLAIN AVENUE CHARLOTTE, NORTH CAROLINA NCBP #23061-19-060 Terracon Project No. 71167021 December 20, 2021 1.0 PROJECT BACKGROUND 1.1 Site Description The proposed Brownfields site consists of nine contiguous tax parcels totaling approximately 31.3 acres located along both sides of South Turner Avenue and Chamberlain Avenue in Charlotte, North Carolina (Figure 1). The current site layout is depicted in Figure 2. The site is bound to the south and southwest by Stewart Creek and wooded land and to the south by State Street, residences and an automotive mechanics shop. Currently, adjoining properties to the north and east consist predominantly of residences; however, the former Flint Ink facility was previously located on an adjacent property to the east/northeast of the site. 1.2 Site History Available historical information indicates Savona Manufacturing Company constructed a one- story weave mill building on the southern portion of the site in 1915/1916. A three-story spinning mill building was constructed as a building addition along the northern side of the weave mill in 1921. Several residential structures were located to the north of the mill building from at least the 1920s to the 1980s. Residences were also depicted in the southeastern portion of the site. A railroad spur also extended onto the site to the northeast from a nearby rail line located to the southwest along the western side of the mill buildings. Ancillary structures were built to the west, between the mill building and Stewart Creek. Primary operations at the mill included spinning, weaving, dyeing, bleaching and finishing of cotton fabrics. Other operations included petroleum storage, wastewater treatment with clarifiers and an aeration basin, a boiler room, oil house, AST area, rotary dryer area, engine house, maintenance shop, and various storage warehouses. Savona Manufacturing Company ceased textile operations at the site in 1931 but leased the property to Alfred Cotton Mills for a couple of years. Textile production operations at the site ceased by 1934. In 1935, Old Dominion Box Company (ODBC) began manufacturing boxes and paperboard products on the site. Operations were expanded in the mid-1950s, with ODBC constructing a three-story paper warehouse at the northern end of the Savona Mill building and adding several buildings to the north near the intersection of Chamberlain Avenue and Gardner Avenue. Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 2 According to historical information, ODBC continued operations until the late-1980s or mid-1990s. In the 1940s, Carolina Paperboard Corporation (CPC) constructed a paperboard manufacturing facility to the northwest of the ODBC operation. The CPC facility included a pulp mill, offices, finishing room, machine shop, settling basin, and other ancillary structures. The former on-site CPC reportedly operated one 3,000-gallon underground gasoline storage tank (UST), one 2,000-gallon diesel UST, one 4,000-gallon diesel UST, one 10,000-gallon diesel UST, and six 30,000-gallon fuel oil USTs which were installed between 1968 and 1982. The tanks were reportedly removed from the ground in 1993. A UST closure report available from the NCDEQ documented the removal of the six 30,000-gallon USTs and two associated fuel oil ASTs in February 1993. The February 1993 closure report indicates minor petroleum contamination was identified in soils during removal activities. A subsequent initial abatement report including delineation of soil impacts using soil borings identified residual soil impacts limited to the area of the USTs. A groundwater monitoring well installed at that time was not impacted by petroleum constituents above laboratory detection limits; however, the release incident remains open. In 1980, CPC merged into Caraustar Industries, Inc. (Caraustar) and Atlantic Coast Carton Company. The new entity continued paper manufacturing operations on the property until approximately 2010. Limited recycling and storage operations continued until 2016. Caraustar demolished most of the structures on the site to the west of the Savona Mill building between 2000 and 2010. An auxiliary metal building was constructed along the south side of the Savona mill building in 1996. The building has been occupied by Blue Blaze Brewing since 2016. 1.3 Prior Investigations Terracon completed sampling events at the site in 2016, 2018, 2020 and early 2021, which included the collection of soil, groundwater and soil vapor samples. Since the purpose of this report is to document the results of recent indoor air testing within the Savona Mill building (which is planned for non-residential use; see Section 1.4 below), the summary below is limited to prior sub-slab sampling activities completed within the Savona Mill building. A summary of soil and groundwater sampling as well as shallow exterior and sub-slab soil vapor sampling completed elsewhere on the site is available in Terracon’s Brownfields Data Gap Assessment Report, dated June 8, 2021. Sample locations are shown on Figure 3. Analytical data is summarized in Table 1. In August 2020, Terracon collected four sub-slab samples (2020-SV-01 through 2020-SV-04) from within the Savona Mill building. Numerous volatile organic compounds (VOCs) were identified within sub-slab soil vapor. Benzene, 1,3-butadiene, carbon tetrachloride, chloroform, isopropanol, 1,2,4-trimethylbenzene and 1,3,5-trimethylbenzene were identified above their Residential Soil Gas Screening Levels (SGSLs) but below their Non-Residential SGSLs. Naphthalene concentrations were detected in several samples above its Residential SGSL, and naphthalene concentrations detected in samples 2020-SV-03 and 2020-SV-04 exceeded its Non- Residential SGSL. At the request of the NCBP, in January 2021 Terracon collected additional Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 3 sub-slab soil vapor samples (2021-SV-11 and 2021-SV-12) in the northern end of the Savona Mill building to further evaluate the analytical results from sample points 2020-SV-03 and 2020-SV- 04. Numerous VOCs were identified in both samples. Naphthalene exceeded its Residential SGSL in 2021-SV-11. No other VOC concentrations exceeded Residential SGSLs, and no VOC concentrations were identified above their Non-Residential SGSLs. Risk to future non-residential building occupants associated with the soil vapor to indoor air exposure pathway was evaluated using the North Carolina Department of Environmental Quality (NCDEQ) Risk Calculator. The maximum concentration of each compound detected within the above-referenced samples was entered into the calculator to provide a conservative evaluation. The calculator indicated the total carcinogenic risk to future non-residential building occupants was 4.7x10-6 with an associated hazard index of 0.38, which do not exceed the thresholds for unacceptable risk of 1x10-4 and 1, respectively. 1.4 Purpose of Soil Vapor Evaluation Based on review of the historical assessment data, the NCBP requested the collection of two indoor air samples from the northern end of the Savona Mill building near the prior locations of soil vapor samples 2020-SV-03, 2020-SV-04 and 2021-SV-11 and 2021-SV-12. Additionally, the NCBP requested the collection of one sub-slab sample at one of these locations to assist in evaluation of the indoor air results. The purpose of the sampling is to confirm that neither vapor mitigation nor post-construction pre-occupancy testing/on-going monitoring is necessary for the proposed redevelopment. The Savona Mill building is proposed for future non-residential use, and thus the relevant screening levels for this building (and the other existing buildings on the site) are non-residential screening levels. Since Prospective Developer understands that multi-family residential use will be authorized for the site, this report also includes references to residential screening levels. Given the planned non-residential use of the existing buildings at the site, Prospective Developer proposes that the Brownfields agreement include a land use restriction requiring additional vapor intrusion evaluation should Prospective Developer propose to convert any existing building (including the Savona Mill building) to multi-family residential use. 2.0 SCOPE OF SERVICES The scope of services was conducted using the protocols outlined in the approved Brownfields Work Plan, dated March 19, 2020 (revised July 29, 2020 and approved August 5, 2020) and in accordance with the additional procedures included in email correspondence between Terracon and the NCBP. These latter procedures were approved by the NCBP via email on October 21, 2021. Technical approaches and methods utilized during the soil vapor investigation were in accordance with the Interstate Technical and Regulatory Council’s Vapor Intrusion: A Practical Guideline (2007) and Vapor Intrusion Pathway: Investigative Approaches for Typical Scenarios Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 4 (2007), as well as the North Carolina Division of Waste Management (DWM) Vapor Intrusion Guidance (2018). 2.1 Standard of Care Terracon’s services were performed in a manner consistent with generally accepted practices of the profession undertaken in similar studies in the same geographical area during the same time. Terracon makes no warranties, either expressed or implied, regarding the findings, conclusions, or recommendations. Please note that Terracon does not warrant the work of laboratories, regulatory agencies, or other third parties supplying information used in the preparation of the report. The services were performed in accordance with the scope of work authorized by our client, as reflected in our proposal and were not conducted in accordance with ASTM E1903-11. 2.2 Additional Scope Limitations Findings, conclusions, and recommendations resulting from these services are based upon information derived from the on-site activities and other services performed under this scope of work; such information is subject to change over time. Certain indicators of the presence of hazardous substances, petroleum products, or other constituents may have been latent, inaccessible, unobservable, non-detectable, or not present during these services. We cannot represent the site as being free of hazardous substances, toxic materials, petroleum products, or other latent conditions beyond those identified during this investigation. Subsurface conditions may vary from those encountered at specific borings or wells or during other surveys, tests, assessments, investigations, or exploratory services. The data, interpretations, findings, and our recommendations are based solely upon data obtained at the time and within the scope of these services. 2.3 Reliance This report has been prepared for the exclusive use of Savona II, LLC, its affiliates, and their lenders providing financing for the site. Any authorization for use or reliance by another party (except a governmental entity) is prohibited without the expressed written authorization of Savona II, LLC and Terracon. Any unauthorized distribution or reuse is at the sole risk of Savona II, LLC. Reliance by authorized parties, except governmental agencies, will be subject to the terms, conditions, and limitations stated in the Agreement for Services between Savona II, LLC and Terracon. 3.0 FIELD INVESTIGATION METHODS Terracon conducted the field work under a health and safety plan developed for this project. Work was performed using United States Environmental Protection Agency (USEPA) Level D work attire consisting of a hard hat, safety glasses, safety vest, protective gloves and protective boots. Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 5 Field notes, photographs, the indoor air building survey, and soil vapor purge/sampling logs are provided in Appendix A. 3.1 Indoor Air Sampling Due to on-going interior renovation work within the Savona Mill building, the building is not currently enclosed. Per the approved scope of work, prior to conducting the indoor air sampling, polyethylene barriers were erected to enclose the proposed sampling areas. In addition, a core hole observed within the concrete floor surface, approximately 40 feet from the northernmost proposed indoor air sample, but outside the enclosed area, was also sealed using polyethylene sheeting. The core hole apparently had been created during a previous evaluation to determine the slab thickness and had not been patched/resurfaced. The polyethylene barriers remained in place for a minimum of 72 hours prior to collection of the indoor air samples. Multiple 5-gallon buckets of lead paint abatement lockdown sealant located within the enclosed area surrounding the 2021-IA-01 sample location were removed approximately 72 hours in advance of the indoor air sampling. In addition, the abatement contractor was instructed to cease its removal of elevator equipment from the northern end of the Savona Mill building via use of a propane-fired torch leading up to the sampling event. Indoor Air Survey On November 11, 2021, after the beginning of the indoor air testing, Terracon completed a building survey form for building spaces where samples would be collected (see Appendix A). While completing the survey, Terracon noted one empty aerosol can of “low-VOC” super-spray glue within the enclosed space near the 2021-IA-02 testing location. The can was immediately removed from the area. A parts-per-billion (ppb) capable photo-ionization detector (PID) was used to collect field screening values of indoor air within the two enclosed sample spaces. Concentrations of VOCs were measured via PID up to 140 ppb within the testing areas. During the indoor air survey, Terracon observed through the open freight elevator doorway an apparent open room located beneath the enclosed space where sample 2021-IA-01 was to be collected. Terracon entered the basement of the mill building but could not identify a doorway or access to the space. Upon further exploration, it was determined that an exterior doorway located along the western side of the mill building could be used to enter the space. This doorway had previously been obscured by debris. The space is tall enough for a person to stand without crouching. Since a building slab is not present and the floor consists of exposed soil, the room is considered a crawl space. Given the presence of the crawl space, samples 2020-SV-03 and 2021-SV-12, which were previously thought to represent sub-slab soil vapor samples, are in fact representative of air within the crawl space collected over 10-minute periods of time. Presently, the PD has not made a decision regarding redevelopment or re-use of the crawl space. A building slab would be poured if re-use is proposed in the future. As such, the sample results from 2021- SV-03 and 2021-SV-12 are not representative of future occupied exposure conditions within the Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 6 space. The indoor air concentrations identified within sample 2021-IA-01 should be used to evaluate risk to building occupants on the first floor of the mill building near this location, regardless of the future use/non-use of the underlying crawl space. Indoor Air Sample Collection On November 11, 2021, Terracon collected two indoor air samples (2021-IA-01 and 2021-IA-02) from the northern end of the Savona Mill building. The samples were collected in laboratory supplied, individually-certified 6-liter Summa® canisters attached to a flow controller set for approximately 8 hours. Following completion of the field activities, the Summa® canisters, along with chain-of-custody documentation, were shipped to Con-test Analytical Laboratory in East Longmeadow, Massachusetts for analysis of VOCs by modified EPA Method TO-15 Low Level. Terracon recorded the remaining vacuum pressure inside each of the Summa® canisters at regular intervals throughout the sampling period. Field sample collection records for indoor and outdoor air are provided in Appendix A. 3.2 Soil Vapor Sampling Soil Vapor Point Installation After completion of the indoor air sampling activities on November 11, 2021, one sub-slab soil vapor sampling point (2021-SV-11B) was installed in the northern end of the Savona Mill building at the location of 2021-IA-02. The sub-slab sample point was installed using a hammer drill to penetrate the slab. The point was constructed using a Vapor Pin™ installed within the 5/8-inch diameter hole. A pre-cut silicone sleeve around the Vapor Pin™ was hammered into the hole to create a competent seal with the concrete floor slab. The Vapor Pin™ was capped and the soil gas point was allowed to equilibrate overnight before sampling. Shut-In and Helium Tracer Testing On November 12, 2021 and prior to sample collection, Terracon conducted a shut-in (deadhead) test of the laboratory-provided sampling equipment and a helium tracer test to verify the integrity of the vapor point seal. The shut-in test was conducted by attaching the laboratory-supplied Summa® canister and flow controller manifold at each point to Teflon® lined tubing and a syringe. The syringe was used to induce a vacuum within the flow controller manifold, at which point, the manifold’s shut-off valve was closed. The stationary Summa® canister and manifold were sealed from the atmosphere for approximately 10 minutes and the pressures within the manifold at the beginning and the end of the shut-in period were recorded and compared. When no loss of pressure was observed during the shut-in test period, the Summa® canister and manifold were deemed suitable for sample collection. During the helium tracer test, the sample point and sampling train was enclosed within a shroud. The shroud atmosphere was enriched to a helium concentration of approximately 15 percent. At least three volumes of the vapor point annulus and attached Teflon® lined tubing and sample train was purged and directed into a Tedlar bag using a syringe. After each purge volume was Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 7 collected, the concentration of helium within the Tedlar bag was measured using an MGD-2002 helium detector. The sample seal was considered sufficiently sealed if the helium concentration within the Tedlar bag was less than 10% of the concentration of helium within the shroud. Concentrations of helium above the MGD-2002’s detection limit (25 parts per million) were not identified during the helium tracer test; thus, sample point 2021-SV-011B was considered sufficiently sealed. Sample Collection After completion of the shut-in and helium tracer test, the soil vapor sample was collected within a batch-certified 1.0-liter Summa® canister equipped with a flow controller restricting the air flow rate to less than approximately 200 mL/min. The vacuum pressure of the canister was monitored and recorded at regular intervals throughout the sampling period. The sample period was terminated prior to the vacuum pressure within each Summa® canister reaching 0 mmHg. After completion of soil vapor sampling activities, the sample point was abandoned by removal of the tubing and Vapor Pin™ and patching the borehole with a ready-mix concrete material. Following completion of the field activities, the Summa® canisters, along with chain-of-custody documentation, were shipped to Con-Test Analytical Laboratories in East Longmeadow, Massachusetts for laboratory analysis of VOCs by EPA Method TO-15. Con-Test was instructed to record the pressure within the Summa® canisters upon receipt. 4.0 ANALYTICAL RESULTS The laboratory analytical reports and chain-of-custody records are provided in Appendix B and are summarized on Table 1. The following sections describe the sample results. 4.1 Indoor Air Sample Results Sample results for the two indoor air samples collected at the site were compared to the NCDEQ Division of Waste Management (DWM) Indoor Air and Crawlspace Screening Concentrations (IASLs) for residential and non-residential exposure scenarios, updated June 2021 (see Section 1.4, above, regarding applicable screening levels and exposure scenarios). The IASLs are based on a target carcinogenic risk of 1.0E-6 and a target hazard quotient of 0.2. ▪ Benzene was detected in each indoor air sample at concentrations (1.8 and 1.9 µg/m3) slightly exceeding its Non-Residential IASL of 1.6 µg/m3. ▪ Naphthalene was detected within each indoor air sample at concentrations (0.61 and 0.55 µg/m3) slightly above its Non-Residential IASL of 0.36 µg/m3. ▪ Chloroform was detected within each indoor air sample at concentrations (0.25 and 0.32 µg/m3) slightly above its Residential IASL of 0.12 µg/m3 but below its Non-Residential IASL. Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 8 ▪ 1,4-Dichlorobenzene was detected within each indoor air sample at concentrations (0.32 and 0.57 µg/m3) slightly above its Residential IASL of 0.26 µg/m3 but below its Non- Residential IASL. ▪ Ethylbenzene was detected within each indoor air sample at concentrations (1.5 and 1.3 µg/m3) slightly above its Residential IASL of 1.1 µg/m3 but below its Non- Residential IASL. ▪ Numerous other VOCs were detected within the indoor air samples (including trichloroethylene [TCE] at an estimated concentration of 0.079 J µg/m3 in sample 2021- IA-02); however, the detected concentrations do not exceed their Residential IASLs. 4.2 Soil Vapor Sample Results The laboratory analytical results for the soil vapor sample were compared to the NCDEQ Residential and Non-Residential Soil Gas Screening Levels (SGSLs), dated June 2021 (see Section 1.4, above, regarding applicable screening levels and exposure scenarios). ▪ Naphthalene was detected in sample 2021-SV-11B at a concentration (6.7 µg/m3) above its Residential SGSL of 2.8 µg/m3 but below its Non-Residential SGSL. ▪ 1,2,4-Trimethylbenzene was detected in sample 2021-SV-11B at a concentration (2,800 µg/m3) above its Residential SGSL of 420 µg/m3 but below its Non-Residential SGSL. ▪ 1,3,5-Trimethylbenzene was detected in sample 2021-SV-11B at a concentration (2,000 µg/m3) above its Residential SGSL of 420 µg/m3 but below its Non-Residential SGSL. ▪ Numerous other VOCs were detected within sample 2021-SV-11B; however, the detected concentrations do not exceed their Residential IASLs. TCE was not detected within the sub-slab soil vapor sample. 4.3 NCDEQ Risk Calculator Terracon evaluated the cumulative carcinogenic risk and the non-carcinogenic hazard index for future non-residential occupants of the Savona Mill building by entering the concentrations for each compound detected within the indoor air and soil vapor samples at each location using the most recent version (June 2021) of the NCDEQ Brownfields Risk Calculator. The calculated risks are summarized in the table below: Brownfields Indoor Air and Sub-Slab Soil Gas Testing Report Caraustar and Savona Mills (NCBP# 23061-19-060) ■ Charlotte, North Carolina December 20, 2021 ■ Terracon Project No. 71167021 Responsive ■ Resourceful ■ Reliable 9 Non-Residential Sample ID Carcinogenic Hazard Index 2021-SV-11B 2.7 x 10-7 0.2 2021-IA-01 4.1 x 10-6 0.12 2021-IA-02 4.4 x 10-6 0.16 Unacceptable risks to future non-residential site occupants associated with the indoor air and sub- slab soil vapor concentrations detected during the November 2021 sampling event were not identified at the site. A copy of the NCDEQ Risk Calculator summary sheets is included in Appendix C. 5.0 CONCLUSIONS Based on the scope of services described in this report and subject to the limitations described herein, Terracon provides the following conclusions. ▪ During the indoor air survey, it was determined that a previously unknown crawl space is located beneath the location of prior sub-slab soil vapor samples 2020-SV-03 and 2021- SV-12. Given the presence of the crawl space, samples 2020-SV-03 and 2021-SV-12, which were previously thought to represent sub-slab soil vapor samples, are in fact representative of air within the crawl space collected over 10-minute periods of time. ▪ Numerous VOCs were detected within the indoor air and sub-slab soil vapor samples at the northern end of the Savona mill building. ▪ Evaluation using the NCDEQ Risk Calculator indicates that there is not unacceptable risk to future non-residential building occupants associated with the identified indoor air concentrations. Cumulative carcinogenic risks at either sample location are two orders of magnitude lower than the unacceptable risk threshold of 1x10-4 and the associated hazard indices are greater than 6 times lower than the unacceptable risk threshold of 1. Based on the detected indoor air and sub-slab soil vapor concentrations, the NCDEQ SGSLs and IASLs, the NCDEQ Risk Calculator results, and the planned non-residential use of the Savona Mill building, further sampling, vapor mitigation, and post-construction testing/monitoring are not necessary within the Savona Mill building for future non-residential use. TABLE Table 1 Soil Vapor/Indoor Air Analytical Results - Savona Mill Building (2020 and 2021) Caraustar and Savona Mills Brownfields Site No. 23061-19-060 Charlotte, Mecklenburg County, North Carolina Terracon Project No. 71167021 Sample ID:2020-SV-01 2020-SV-02 2020-SV-03 DUP-01 (SV-03)2021-SV-12 2021-IA-01 2020-SV-04 UnAdj.2020-SV-04 Adj.2021-SV-11 2021-SV-11B 2021-IA-02 Sample Date:August 19, 2020 August 19, 2020 August 19, 2020 August 19, 2020 January 11, 2021 November 11, 2021 August 20, 2020 August 19, 2020 January 11, 2021 November 12, 2021 November 11, 2021 Sample Depth:Sub-Slab Sub-Slab Indoor Air*Indoor Air*Indoor Air*Indoor Air Sub-Slab Sub-Slab Sub-Slab Sub-Slab Indoor Air EPA Method TO-15 Acetone 55 20 240 210 25 98 8,700 11,869 130 280 190 220,000 2,700,000 6,500 27,000 Benzene 16 3.6 22 15 2.6 1.8 <0.19 <0.19 1.4 <0.77 1.9 12 160 0.36 1.6 1,3-Butadiene <0.32 <0.32 12 8.1 <0.32 <0.054 <0.32 <0.32 <0.32 <1.5 <0.054 3.1 41 0.094 0.41 2-Butanone (MEK)8.8 J <2.0 77 56 3.5 J 2.9 J 42 57 6.2 J 28 J 4.3 35,000 440,000 1,000 4,400 Carbon Disulfide <1.6 <1.6 <1.6 <1.6 <1.6 <0.28 <1.6 <1.6 4.8 J <7.9 <0.28 4,900 61,000 150 610 Carbon Tetrachloride 75 1.3 <0.33 <0.33 0.45 J 0.43 <0.33 <0.33 <0.33 <1.9 0.44 16 200 0.47 2 Chloroform 4.7 <0.24 <0.24 <0.24 0.35 J 0.25 <0.24 <0.24 <0.24 2.3 J 0.32 4.1 53 0.12 0.53 Chloromethane <0.32 <0.32 <0.32 <0.32 0.63 J 0.97 <0.32 <0.32 1.0 <0.85 1 630 7,900 19 79 Cyclohexane <0.34 <0.34 <0.34 <0.34 1.3 1 <0.34 <0.34 2.5 <2.3 1 42,000 530,000 1,300 5,300 1,4-Dichlorobenzene <0.27 <0.27 <0.27 <0.27 <0.27 0.32 <0.27 <0.27 <0.27 <2.4 0.57 8.5 110 0.26 1.1 Dichlorodifluoromethane (Freon 12)<0.31 <0.31 <0.31 <0.31 2.3 2.4 <0.31 <0.31 2.7 2.8 J 2.4 700 8,800 21 88 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)<0.79 <0.79 <0.79 <0.79 <0.79 0.13 J <0.79 <0.79 <0.79 <2.4 0.13 J NE NE NE NE Ethanol 150 59 120 91 54 20 650 887 190 270 25 NE NE NE NE Ethyl Acetate <4.3 <4.3 <4.3 <4.3 <4.3 1.3 <4.3 <4.3 <4.3 <21 2.1 490 6,100 15 61 Ethylbenzene 3.2 1.6 4.8 3.7 3.7 1.5 <0.18 <0.18 6.6 2 J 1.3 37 490 1.1 4.9 4-Ethyltoluene <0.30 <0.30 3.9 2.8 3.1 0.4 180 246 4.5 160 0.57 NE NE NE NE Heptane 2.7 <0.35 5.0 4.3 2.6 3.5 5.0 6.8 5.2 1.7 J 36 2,800 35,000 83 350 Hexane 2.9 J <1.3 <1.3 33 3.4 J 12 53 72 3.8 J <12 11 4,900 61,000 150 610 2-Hexanone (Methyl butyl ketone)<0.46 <0.46 41 <0.46 <0.46 <0.072 <0.46 <0.46 <0.46 <2.1 <0.072 210 2,600 6.3 26 Isopropanol 72 25 86 59 13 J 2.5 J 12,000 16,371 120 150 5.9 1,400 18,000 42 180 Methylene Chloride <1.6 <1.6 <1.6 19 17 1.5 32 44 26 <8.0 0.71 J 3,400 53,000 100 530 Naphthalene 12 6.8 42 33 <0.59 0.61 99 135 29 6.7 0.55 2.8 36 0.083 0.36 Propene <1.2 <1.2 <1.2 <1.2 6.2 J <0.20 <1.2 <1.2 2.2 J <5.8 <0.20 21,000 260,000 630 2,600 Styrene 2.0 0.9 5.4 3.6 <0.24 0.54 <0.24 <0.24 0.26 J <1.3 0.77 7,000 88,000 210 880 Tetrachloroethylene 15 8.4 1.1 J <0.44 0.62 1.2 69 94 25 160 1.6 280 3,500 8.3 35 Tetrahydrofuran <1.5 <1.5 <1.5 <1.5 <1.5 0.52 J <1.5 <1.5 <1.5 <7.3 <0.25 14,000 180,000 420 1,800 Toluene 17 5.4 22 16 18 7.9 55 75 13 5.8 7 35,000 440,000 1,000 4,400 1,1,1-Trichloroethane <0.36 <0.36 <0.36 <0.36 <0.36 0.18 J <0.36 <0.36 1.3 <2.5 <0.088 35,000 440,000 1,000 4,400 Trichloroethylene <0.40 <0.40 <0.40 <0.40 0.84 J <0.069 <0.40 <0.40 <0.40 <2.0 0.079 J 14 180 0.42 1.8 Trichlorofluoromethane (Freon 11)1.6 J 1.9 J <0.85 1.6 J 1.3 J 1.3 <0.85 <0.85 1.1 J <2.2 1.3 NE NE NE NE 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)<1.2 <1.2 <1.2 <1.2 <1.2 0.61 J <1.2 <1.2 <1.2 <2.7 0.49 J 35,000 440,000 1,000 4,400 1,2,4-Trimethylbenzene <0.22 3.3 34 26 3.1 1.9 590 805 6.0 2,800 2.5 420 5,300 13 53 1,3,5-Trimethylbenzene 1.0 0.87 J 8.8 6.6 0.81 J 0.46 690 941 1.8 2,000 0.77 420 5,300 13 53 m&p-xylene 13 6.4 11 9.5 12 3.5 <0.30 <0.30 13 11 4.1 700 8,800 21 88 o-Xylene 4.3 2.3 5.1 4.5 4.7 2 <0.23 <0.23 4.8 <1.2 1.8 700 8,800 21 88 Notes: Concentrations are reported in micrograms per cubic meter (μg/m3) unless otherwise noted. Only compounds detected in one or more sub-slab soil vapor samples are shown. Detected concentrations are in bold font. 2020-SV-04 did not pass the helium tracer test. During sampling, the helium concentration within the shroud was maintained at approximately 15% helium. 2020-SV-04 was analyzed for helium via EPA Method 3C and determined to have a concentration of 4% helium, indicating breakthrough of approximately 26.7%. VOC concentrations have been adjusted upward to account for introduction of ambient air into the sample, conservatively assuming that VOC compounds were not present within ambient air and therefore assuming that the introduced air acted solely to dilute the detected concentrations within the sub-slab. For more information regarding the adjustment method, see Section 5.3 of the report. Unadjusted concentrations are shown in the left column and adjusted concentrations in the right column. Thick vertical borders separate sets of samples that come from the same area (e.g. 2020-SV-04, 2021-SV-11, 2021-SV-11B, and 2021-IA-02 were all collected from the central portion of the northernmost room of the Savona Mill building). The red border groups paired (adjcent) sub-slab and indoor air samples that were collected at the same time (one day apart). NE - Standard Not Established DWM - North Carolina Department of Environmental Quality, Division of Waste Management SGSL - DWM Sub-slab and Exterior Soil Gas Screening Level, updated June 2021. Highlighted concentrations exceed their respective Residential SGSL. J - Estimated concentration between the laboratory method detection and reporting limits. *During the November 11, 2021 sampling activities, it was discovered that a previously unknown (to Terracon) crawl-space type room is present beneath the 2020-SV-03/2021-SV-11 sample location. Since these samples were previously thought to be representative of sub-slab samples, they are in fact indoor air samples from this "crawl space" collected over approximate 10-minute periods. Sample 2021-IA-01 is an indoor air sample collected from the first floor of the mill building (above the "crawl space") over an 8-hour period. Residential SGSL Non-Residential SGSL Residential IASL Non-Residential IASL FIGURES Brownfields Indoor Air and Sub-Slab Soil Gas TestingCaraustar and Savona Mills Brownfields Site No. 23061-19-060 Charlotte, Mecklenburg County, North Carolina Copyright:© 2013 National Geographic Society, i-cubed USGS TOPOGRAPHIC MAPCHARLOTTE EAST, NORTH CAROLINA QUADRANGLE (1988) 0 2,000 4,000 6,000 8,000 10,0001,000 Feet CONTOUR INTERVAL: 10FT FIGURENO. Filename: Date: PM: Drawn By: Checked By: Approved By: Project No. Scale: 1 2701 Westport Road Charlotte, North Carolina 28208 Phone: (704) 509-1777 Fax: (704) 509-1888 1:24,000 Dec. 2021 Topographic Map Site 1 inch = 2,000 feet ³ WOF 71167021 WOF CLC CLC 71167021.topo Site Diagram FIGNUOR.E NC Center for Geographic Information & Analysis Legend Site BoundaryTax Parcels Brownfields Indoor Air and Sub-Slab Soil Gas Testing Caraustar and Savona MillsBrownfields Site No. 23061-19-060 Charlotte, Mecklenburg County, North Carolina2701 Westport Road Charlotte, North Carolina 28208Phone: (704) 509-1777 Fax: (704) 509-1888 ³ 0 400 800200Feet PM: Drawn By: Checked By: Approved By: WOF WOF CLC CLC Project No: Scale: Filename: Date:Dec 2021 71167021_IA_2 1 inch = 400 feet 71167021 2South Turner AvenueChamberlain Avenue S t a t e S t r e e t Former CaraustarWarehouse Savona MillsBuilding Former WikoffColor Building Blue BlazeBrewing Rozzelles Ferry Road C o x e A v e n u e Soil Vapor and Indoor Air Sample Location Map - Savona Mill Building FIGNUOR.E NC Center for Geographic Information & Analysis Legend Indoor Air Samples Soil Vapor Samples Site BoundaryTax Parcels Brownfields Indoor Air TestingCaraustar and Savona MillsBrownfields Site No. 23061-19-0602701 Westport Road Charlotte, North Carolina 28208 Charlotte, Mecklenburg County, North CarolinaPhone: (704) 509-1777 Fax: (704) 509-1888 0 170 34085Feet PM: Drawn By: Checked By: Approved By: WOF WOF MNM MNM Project No: Scale: Filename: Date:December 2021 1 inch = 170 feet 71167021 3South Turner Avenue2020-SV-04 2020-SV-03 2020-SV-02 2020-SV-01 S t a t e S t r e e t C o x e A v e n u e 2021-SV-11 and 2021-SV-11B 2021-SV-12 2021-IA-01 2021-IA-02 APPENDIX A FIELD NOTES/DOCUMENTATION Brownfields Indoor Air Testing Report Caraustar and Savona Mills (NCBP #23061-19-060) ■ Charlotte, NC Photos Taken: Nov. 8, 11, and 12, 2021 ■ Terracon Project No. 71167021 Photo #1 View of enclosed area in which 2021-IA-01 was collected. Photo #2 View of enclosed area in which 2021-IA-01 was collected. Photo #3 View of lead abatement sealants removed from site prior to sampling. Photo #4 View of lead abatement sealants removed from site prior to sampling. Photo #5 View of 2021-IA-01. Photo #6 View of sealed corehole within concrete outside the 2021-IA-02 sample enclosure area. Brownfields Indoor Air Testing Report Caraustar and Savona Mills (NCBP #23061-19-060) ■ Charlotte, NC Photos Taken: Nov. 8, 11, and 12, 2021 ■ Terracon Project No. 71167021 Photo #7 View of low-VOC spray glue removed from 2021-IA-02 sample enclosure area at outset of sampling. Photo #8 View of 2021-IA-02. Photo #9 View of 2021-IA-02. Photo #10 View of 2021-SV-11B location adjacent to 2021-IA-02. Photo #11 View of 2021-SV-11B vapor pin. Photo #12 View of soil vapor sampling set up at 2021-SV-11B. Brownfields Indoor Air Testing Report Caraustar and Savona Mills (NCBP #23061-19-060) ■ Charlotte, NC Photos Taken: Nov. 8, 11, and 12, 2021 ■ Terracon Project No. 71167021 Photo #13 View of entrance to crawl space beneath 2021-IA-01 area. Photo #14 View of crawl space beneath 2021-IA-01 area. Photo #15 View of crawl space beneath 2021-IA-01 area. Photo #16 View of crawl space beneath 2021-IA-01 area. APPENDIX B LABORATORY ANALYTICAL REPORTS 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 November 19, 2021 Will Frazier Terracon - Charlotte, NC 2701 Westport Road Charlotte, NC 28208 Project Location: Charlotte, NC Client Job Number: Project Number: 71167021 Laboratory Work Order Number: 21K1098 Enclosed are results of analyses for samples as received by the laboratory on November 15, 2021. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 11/19/2021Terracon - Charlotte, NC 2701 Westport Road Charlotte, NC 28208 ATTN: Will Frazier 71167021 21K1098 The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Charlotte, NC 2021-IA-01 21K1098-01 Indoor air EPA TO-15 2021-IA-02 21K1098-02 Indoor air EPA TO-15 2021-SV-11B 21K1098-03 Sub Slab EPA TO-15 Page 2 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. Page 3 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 EPA TO-15 Qualifications: Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: Vinyl Acetate B295058-BS1, B295141-BS1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: Ethyl Acetate 21K1098-01[2021-IA-01], 21K1098-02[2021-IA-02], 21K1098-03[2021-SV-11B], B295058-BLK1, B295058-BS1, B295141-BLK1, B295141-BS1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the high side. Analyte & Samples(s) Qualified: Ethanol 21K1098-01[2021-IA-01], 21K1098-02[2021-IA-02], B295058-BS1 Elevated reporting limit due to high concentration of target compounds. Analyte & Samples(s) Qualified: 21K1098-03[2021-SV-11B] Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: Ethyl Acetate 21K1098-01[2021-IA-01], 21K1098-02[2021-IA-02], B295058-BLK1, B295058-BS1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: Ethanol 21K1098-01[2021-IA-01], 21K1098-02[2021-IA-02], 21K1098-03[2021-SV-11B], B295058-BS1, B295141-BS1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: Vinyl Acetate B295058-BS1, B295141-BS1 Page 4 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 5 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-IA-01 Sample ID: 21K1098-01 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -9 Receipt Vacuum(in Hg): -8.8 Sampled: 11/11/2021 15:57 Canister ID: 1016 Flow Controller ID: 3571 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 41 4.0 11/18/21 6:51 BRF98 29.52.4 5.7 Benzene 0.56 0.035 11/17/21 18:32 BRF1.8 0.6980.110.0084 0.027 Benzyl chloride ND 0.035 11/17/21 18:32 BRFND0.6980.180.016 0.081 Bromodichloromethane ND 0.035 11/17/21 18:32 BRFND0.6980.230.013 0.085 Bromoform ND 0.035 11/17/21 18:32 BRFND0.6980.360.013 0.13 Bromomethane ND 0.035 11/17/21 18:32 BRFND0.6980.140.028 0.11 1,3-Butadiene ND 0.035 11/17/21 18:32 BRFND0.6980.0770.024 0.054 2-Butanone (MEK)0.98 1.4 11/17/21 18:32 BRFJ2.9 0.6984.10.12 0.34 Carbon Disulfide ND 0.35 11/17/21 18:32 BRFND0.6981.10.089 0.28 Carbon Tetrachloride 0.069 0.035 11/17/21 18:32 BRF0.43 0.6980.220.011 0.066 Chlorobenzene ND 0.035 11/17/21 18:32 BRFND0.6980.160.010 0.048 Chloroethane ND 0.035 11/17/21 18:32 BRFND0.6980.0920.025 0.067 Chloroform 0.052 0.035 11/17/21 18:32 BRF0.25 0.6980.170.0084 0.041 Chloromethane 0.47 0.070 11/17/21 18:32 BRF0.97 0.6980.140.014 0.030 Cyclohexane 0.30 0.035 11/17/21 18:32 BRF1.0 0.6980.120.023 0.079 Dibromochloromethane ND 0.035 11/17/21 18:32 BRFND0.6980.300.012 0.100 1,2-Dibromoethane (EDB)ND 0.035 11/17/21 18:32 BRFND0.6980.270.0098 0.075 1,2-Dichlorobenzene ND 0.035 11/17/21 18:32 BRFND0.6980.210.013 0.078 1,3-Dichlorobenzene ND 0.035 11/17/21 18:32 BRFND0.6980.210.0084 0.051 1,4-Dichlorobenzene 0.054 0.035 11/17/21 18:32 BRF0.32 0.6980.210.014 0.085 Dichlorodifluoromethane (Freon 12)0.48 0.035 11/17/21 18:32 BRF2.4 0.6980.170.011 0.053 1,1-Dichloroethane ND 0.035 11/17/21 18:32 BRFND0.6980.140.012 0.047 1,2-Dichloroethane ND 0.035 11/17/21 18:32 BRFND0.6980.140.013 0.052 1,1-Dichloroethylene ND 0.035 11/17/21 18:32 BRFND0.6980.140.014 0.054 cis-1,2-Dichloroethylene ND 0.035 11/17/21 18:32 BRFND0.6980.140.012 0.047 trans-1,2-Dichloroethylene ND 0.035 11/17/21 18:32 BRFND0.6980.140.012 0.048 1,2-Dichloropropane ND 0.035 11/17/21 18:32 BRFND0.6980.160.013 0.058 cis-1,3-Dichloropropene ND 0.035 11/17/21 18:32 BRFND0.6980.160.016 0.073 trans-1,3-Dichloropropene ND 0.035 11/17/21 18:32 BRFND0.6980.160.011 0.049 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)0.018 0.035 11/17/21 18:32 BRFJ0.13 0.6980.240.012 0.084 1,4-Dioxane ND 0.35 11/17/21 18:32 BRFND0.6981.30.024 0.085 Ethanol 10 1.4 11/17/21 18:32 BRFL-05, V-35 20 0.6982.60.42 0.80 Ethyl Acetate 0.37 0.35 11/17/21 18:32 BRFL-03, V-34 1.3 0.6981.30.21 0.75 Ethylbenzene 0.34 0.035 11/17/21 18:32 BRF1.5 0.6980.150.0090 0.039 4-Ethyltoluene 0.082 0.035 11/17/21 18:32 BRF0.40 0.6980.170.011 0.053 Heptane 0.84 0.035 11/17/21 18:32 BRF3.5 0.6980.140.014 0.059 Hexachlorobutadiene ND 0.035 11/17/21 18:32 BRFND0.6980.370.019 0.21 Hexane 3.4 1.4 11/17/21 18:32 BRF12 0.6984.90.11 0.40 2-Hexanone (MBK)ND 0.035 11/17/21 18:32 BRFND0.6980.140.018 0.072 Isopropanol 1.0 1.4 11/17/21 18:32 BRFJ2.5 0.6983.40.32 0.79 Methyl tert-Butyl Ether (MTBE)ND 0.035 11/17/21 18:32 BRFND0.6980.130.014 0.050 Methylene Chloride 0.43 0.35 11/17/21 18:32 BRF1.5 0.6981.20.080 0.28 4-Methyl-2-pentanone (MIBK)ND 0.035 11/17/21 18:32 BRFND0.6980.140.018 0.073 Naphthalene 0.12 0.035 11/17/21 18:32 BRF0.61 0.6980.180.022 0.12 Propene ND 1.4 11/17/21 18:32 BRFND0.6982.40.12 0.20 Styrene 0.13 0.035 11/17/21 18:32 BRF0.54 0.6980.150.011 0.047 1,1,2,2-Tetrachloroethane ND 0.035 11/17/21 18:32 BRFND0.6980.240.011 0.073 Page 6 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-IA-01 Sample ID: 21K1098-01 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -9 Receipt Vacuum(in Hg): -8.8 Sampled: 11/11/2021 15:57 Canister ID: 1016 Flow Controller ID: 3571 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.18 0.035 11/17/21 18:32 BRF1.2 0.6980.240.010 0.070 Tetrahydrofuran 0.18 0.35 11/17/21 18:32 BRFJ0.52 0.6981.00.086 0.25 Toluene 2.1 0.035 11/17/21 18:32 BRF7.9 0.6980.130.015 0.055 1,2,4-Trichlorobenzene ND 0.035 11/17/21 18:32 BRFND0.6980.260.024 0.18 1,1,1-Trichloroethane 0.032 0.035 11/17/21 18:32 BRFJ0.18 0.6980.190.016 0.088 1,1,2-Trichloroethane ND 0.035 11/17/21 18:32 BRFND0.6980.190.014 0.076 Trichloroethylene ND 0.035 11/17/21 18:32 BRFND0.6980.190.013 0.069 Trichlorofluoromethane (Freon 11)0.23 0.14 11/17/21 18:32 BRF1.3 0.6980.780.014 0.078 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.080 0.14 11/17/21 18:32 BRFJ0.61 0.6981.10.012 0.095 1,2,4-Trimethylbenzene 0.38 0.035 11/17/21 18:32 BRF1.9 0.6980.170.010 0.051 1,3,5-Trimethylbenzene 0.093 0.035 11/17/21 18:32 BRF0.46 0.6980.170.0096 0.047 Vinyl Acetate ND 0.70 11/17/21 18:32 BRFND0.6982.50.065 0.23 Vinyl Chloride ND 0.035 11/17/21 18:32 BRFND0.6980.0890.014 0.035 m&p-Xylene 0.80 0.070 11/17/21 18:32 BRF3.5 0.6980.300.019 0.084 o-Xylene 0.46 0.035 11/17/21 18:32 BRF2.0 0.6980.150.0093 0.041 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)101 11/17/21 18:3270-130 4-Bromofluorobenzene (1)103 11/18/21 6:5170-130 Page 7 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-IA-02 Sample ID: 21K1098-02 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -8.5 Receipt Vacuum(in Hg): -8.9 Sampled: 11/11/2021 15:58 Canister ID: 1989 Flow Controller ID: 3553 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 79 8.0 11/18/21 7:21 BRF190 4194.8 11 Benzene 0.58 0.035 11/17/21 19:09 BRF1.9 0.6980.110.0084 0.027 Benzyl chloride ND 0.035 11/17/21 19:09 BRFND0.6980.180.016 0.081 Bromodichloromethane ND 0.035 11/17/21 19:09 BRFND0.6980.230.013 0.085 Bromoform ND 0.035 11/17/21 19:09 BRFND0.6980.360.013 0.13 Bromomethane ND 0.035 11/17/21 19:09 BRFND0.6980.140.028 0.11 1,3-Butadiene ND 0.035 11/17/21 19:09 BRFND0.6980.0770.024 0.054 2-Butanone (MEK)1.5 1.4 11/17/21 19:09 BRF4.3 0.6984.10.12 0.34 Carbon Disulfide ND 0.35 11/17/21 19:09 BRFND0.6981.10.089 0.28 Carbon Tetrachloride 0.070 0.035 11/17/21 19:09 BRF0.44 0.6980.220.011 0.066 Chlorobenzene ND 0.035 11/17/21 19:09 BRFND0.6980.160.010 0.048 Chloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.0920.025 0.067 Chloroform 0.065 0.035 11/17/21 19:09 BRF0.32 0.6980.170.0084 0.041 Chloromethane 0.50 0.070 11/17/21 19:09 BRF1.0 0.6980.140.014 0.030 Cyclohexane 0.30 0.035 11/17/21 19:09 BRF1.0 0.6980.120.023 0.079 Dibromochloromethane ND 0.035 11/17/21 19:09 BRFND0.6980.300.012 0.100 1,2-Dibromoethane (EDB)ND 0.035 11/17/21 19:09 BRFND0.6980.270.0098 0.075 1,2-Dichlorobenzene ND 0.035 11/17/21 19:09 BRFND0.6980.210.013 0.078 1,3-Dichlorobenzene ND 0.035 11/17/21 19:09 BRFND0.6980.210.0084 0.051 1,4-Dichlorobenzene 0.094 0.035 11/17/21 19:09 BRF0.57 0.6980.210.014 0.085 Dichlorodifluoromethane (Freon 12)0.48 0.035 11/17/21 19:09 BRF2.4 0.6980.170.011 0.053 1,1-Dichloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.140.012 0.047 1,2-Dichloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.140.013 0.052 1,1-Dichloroethylene ND 0.035 11/17/21 19:09 BRFND0.6980.140.014 0.054 cis-1,2-Dichloroethylene ND 0.035 11/17/21 19:09 BRFND0.6980.140.012 0.047 trans-1,2-Dichloroethylene ND 0.035 11/17/21 19:09 BRFND0.6980.140.012 0.048 1,2-Dichloropropane ND 0.035 11/17/21 19:09 BRFND0.6980.160.013 0.058 cis-1,3-Dichloropropene ND 0.035 11/17/21 19:09 BRFND0.6980.160.016 0.073 trans-1,3-Dichloropropene ND 0.035 11/17/21 19:09 BRFND0.6980.160.011 0.049 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)0.018 0.035 11/17/21 19:09 BRFJ0.13 0.6980.240.012 0.084 1,4-Dioxane ND 0.35 11/17/21 19:09 BRFND0.6981.30.024 0.085 Ethanol 13 1.4 11/17/21 19:09 BRFL-05, V-35 25 0.6982.60.42 0.80 Ethyl Acetate 0.58 0.35 11/17/21 19:09 BRFL-03, V-34 2.1 0.6981.30.21 0.75 Ethylbenzene 0.30 0.035 11/17/21 19:09 BRF1.3 0.6980.150.0090 0.039 4-Ethyltoluene 0.12 0.035 11/17/21 19:09 BRF0.57 0.6980.170.011 0.053 Heptane 8.8 0.035 11/17/21 19:09 BRF36 0.6980.140.014 0.059 Hexachlorobutadiene ND 0.035 11/17/21 19:09 BRFND0.6980.370.019 0.21 Hexane 3.2 1.4 11/17/21 19:09 BRF11 0.6984.90.11 0.40 2-Hexanone (MBK)ND 0.035 11/17/21 19:09 BRFND0.6980.140.018 0.072 Isopropanol 2.4 1.4 11/17/21 19:09 BRF5.9 0.6983.40.32 0.79 Methyl tert-Butyl Ether (MTBE)ND 0.035 11/17/21 19:09 BRFND0.6980.130.014 0.050 Methylene Chloride 0.20 0.35 11/17/21 19:09 BRFJ0.71 0.6981.20.080 0.28 4-Methyl-2-pentanone (MIBK)ND 0.035 11/17/21 19:09 BRFND0.6980.140.018 0.073 Naphthalene 0.10 0.035 11/17/21 19:09 BRF0.55 0.6980.180.022 0.12 Propene ND 1.4 11/17/21 19:09 BRFND0.6982.40.12 0.20 Styrene 0.18 0.035 11/17/21 19:09 BRF0.77 0.6980.150.011 0.047 1,1,2,2-Tetrachloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.240.011 0.073 Page 8 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-IA-02 Sample ID: 21K1098-02 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -8.5 Receipt Vacuum(in Hg): -8.9 Sampled: 11/11/2021 15:58 Canister ID: 1989 Flow Controller ID: 3553 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.23 0.035 11/17/21 19:09 BRF1.6 0.6980.240.010 0.070 Tetrahydrofuran ND 0.35 11/17/21 19:09 BRFND0.6981.00.086 0.25 Toluene 1.9 0.035 11/17/21 19:09 BRF7.0 0.6980.130.015 0.055 1,2,4-Trichlorobenzene ND 0.035 11/17/21 19:09 BRFND0.6980.260.024 0.18 1,1,1-Trichloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.190.016 0.088 1,1,2-Trichloroethane ND 0.035 11/17/21 19:09 BRFND0.6980.190.014 0.076 Trichloroethylene 0.015 0.035 11/17/21 19:09 BRFJ0.079 0.6980.190.013 0.069 Trichlorofluoromethane (Freon 11)0.23 0.14 11/17/21 19:09 BRF1.3 0.6980.780.014 0.078 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.064 0.14 11/17/21 19:09 BRFJ0.49 0.6981.10.012 0.095 1,2,4-Trimethylbenzene 0.51 0.035 11/17/21 19:09 BRF2.5 0.6980.170.010 0.051 1,3,5-Trimethylbenzene 0.16 0.035 11/17/21 19:09 BRF0.77 0.6980.170.0096 0.047 Vinyl Acetate ND 0.70 11/17/21 19:09 BRFND0.6982.50.065 0.23 Vinyl Chloride ND 0.035 11/17/21 19:09 BRFND0.6980.0890.014 0.035 m&p-Xylene 0.94 0.070 11/17/21 19:09 BRF4.1 0.6980.300.019 0.084 o-Xylene 0.41 0.035 11/17/21 19:09 BRF1.8 0.6980.150.0093 0.041 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)101 11/18/21 7:2170-130 4-Bromofluorobenzene (1)101 11/17/21 19:0970-130 Page 9 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-SV-11B Sample ID: 21K1098-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -26 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.1 Sampled: 11/12/2021 08:49 Canister ID: 2540 Flow Controller ID: 4153 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 Sample Flags: RL-11 MDL MDL Acetone 120 40 11/18/21 5:45 BRF280 20952457 Benzene ND 1.0 11/18/21 5:45 BRFND203.20.24 0.77 Benzyl chloride ND 1.0 11/18/21 5:45 BRFND205.20.45 2.3 Bromodichloromethane ND 1.0 11/18/21 5:45 BRFND206.70.36 2.4 Bromoform ND 1.0 11/18/21 5:45 BRFND20100.36 3.7 Bromomethane ND 1.0 11/18/21 5:45 BRFND203.90.82 3.2 1,3-Butadiene ND 1.0 11/18/21 5:45 BRFND202.20.70 1.5 2-Butanone (MEK)9.5 40 11/18/21 5:45 BRFJ28 201203.3 9.8 Carbon Disulfide ND 10 11/18/21 5:45 BRFND20312.5 7.9 Carbon Tetrachloride ND 1.0 11/18/21 5:45 BRFND206.30.30 1.9 Chlorobenzene ND 1.0 11/18/21 5:45 BRFND204.60.30 1.4 Chloroethane ND 1.0 11/18/21 5:45 BRFND202.60.73 1.9 Chloroform 0.48 1.0 11/18/21 5:45 BRFJ2.3 204.90.24 1.2 Chloromethane ND 2.0 11/18/21 5:45 BRFND204.10.41 0.85 Cyclohexane ND 1.0 11/18/21 5:45 BRFND203.40.66 2.3 Dibromochloromethane ND 1.0 11/18/21 5:45 BRFND208.50.34 2.9 1,2-Dibromoethane (EDB)ND 1.0 11/18/21 5:45 BRFND207.70.28 2.2 1,2-Dichlorobenzene ND 1.0 11/18/21 5:45 BRFND206.00.37 2.2 1,3-Dichlorobenzene ND 1.0 11/18/21 5:45 BRFND206.00.24 1.5 1,4-Dichlorobenzene ND 1.0 11/18/21 5:45 BRFND206.00.41 2.4 Dichlorodifluoromethane (Freon 12)0.56 1.0 11/18/21 5:45 BRFJ2.8 204.90.31 1.5 1,1-Dichloroethane ND 1.0 11/18/21 5:45 BRFND204.00.34 1.4 1,2-Dichloroethane ND 1.0 11/18/21 5:45 BRFND204.00.37 1.5 1,1-Dichloroethylene ND 1.0 11/18/21 5:45 BRFND204.00.39 1.6 cis-1,2-Dichloroethylene ND 1.0 11/18/21 5:45 BRFND204.00.34 1.3 trans-1,2-Dichloroethylene ND 1.0 11/18/21 5:45 BRFND204.00.35 1.4 1,2-Dichloropropane ND 1.0 11/18/21 5:45 BRFND204.60.36 1.7 cis-1,3-Dichloropropene ND 1.0 11/18/21 5:45 BRFND204.50.46 2.1 trans-1,3-Dichloropropene ND 1.0 11/18/21 5:45 BRFND204.50.31 1.4 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 1.0 11/18/21 5:45 BRFND207.00.35 2.4 1,4-Dioxane ND 10 11/18/21 5:45 BRFND20360.68 2.4 Ethanol 140 40 11/18/21 5:45 BRFV-35 270 20751223 Ethyl Acetate ND 10 11/18/21 5:45 BRFL-03 ND 20365.9 21 Ethylbenzene 0.46 1.0 11/18/21 5:45 BRFJ2.0 204.30.26 1.1 4-Ethyltoluene 32 1.0 11/18/21 5:45 BRF160 204.90.31 1.5 Heptane 0.42 1.0 11/18/21 5:45 BRFJ1.7 204.10.41 1.7 Hexachlorobutadiene ND 1.0 11/18/21 5:45 BRFND20110.56 5.9 Hexane ND 40 11/18/21 5:45 BRFND201403.3 12 2-Hexanone (MBK)ND 1.0 11/18/21 5:45 BRFND204.10.50 2.1 Isopropanol 59 40 11/18/21 5:45 BRF150 20989.2 23 Methyl tert-Butyl Ether (MTBE)ND 1.0 11/18/21 5:45 BRFND203.60.40 1.4 Methylene Chloride ND 10 11/18/21 5:45 BRFND20352.3 8.0 4-Methyl-2-pentanone (MIBK)ND 1.0 11/18/21 5:45 BRFND204.10.51 2.1 Naphthalene 1.3 1.0 11/18/21 5:45 BRF6.7 205.20.63 3.3 Propene ND 40 11/18/21 5:45 BRFND20693.3 5.8 Styrene ND 1.0 11/18/21 5:45 BRFND204.30.32 1.3 1,1,2,2-Tetrachloroethane ND 1.0 11/18/21 5:45 BRFND206.90.31 2.1 Page 10 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 11/15/2021 Work Order: 21K1098Sample Description/Location: Field Sample #: 2021-SV-11B Sample ID: 21K1098-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -26 Final Vacuum(in Hg): -3 Receipt Vacuum(in Hg): -5.1 Sampled: 11/12/2021 08:49 Canister ID: 2540 Flow Controller ID: 4153 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 Sample Flags: RL-11 MDL MDL Tetrachloroethylene 24 1.0 11/18/21 5:45 BRF160 206.80.30 2.0 Tetrahydrofuran ND 10 11/18/21 5:45 BRFND20292.5 7.3 Toluene 1.5 1.0 11/18/21 5:45 BRF5.8 203.80.42 1.6 1,2,4-Trichlorobenzene ND 1.0 11/18/21 5:45 BRFND207.40.70 5.2 1,1,1-Trichloroethane ND 1.0 11/18/21 5:45 BRFND205.50.46 2.5 1,1,2-Trichloroethane ND 1.0 11/18/21 5:45 BRFND205.50.40 2.2 Trichloroethylene ND 1.0 11/18/21 5:45 BRFND205.40.37 2.0 Trichlorofluoromethane (Freon 11)ND 4.0 11/18/21 5:45 BRFND20220.40 2.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 4.0 11/18/21 5:45 BRFND20310.35 2.7 1,2,4-Trimethylbenzene 570 1.0 11/18/21 5:45 BRF2800 204.90.30 1.5 1,3,5-Trimethylbenzene 400 1.0 11/18/21 5:45 BRF2000 204.90.27 1.3 Vinyl Acetate ND 20 11/18/21 5:45 BRFND20701.9 6.6 Vinyl Chloride ND 1.0 11/18/21 5:45 BRFND202.60.40 1.0 m&p-Xylene 2.5 2.0 11/18/21 5:45 BRF11 208.70.55 2.4 o-Xylene ND 1.0 11/18/21 5:45 BRFND204.30.27 1.2 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)95.7 11/18/21 5:4570-130 Page 11 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 21K1098-01 [2021-IA-01]B295058 1.5 1 N/A 1000 200 430 11/17/21 21K1098-01RE1 [2021-IA-01]B295058 1.5 1 N/A 1000 200 150 11/17/21 21K1098-02 [2021-IA-02]B295058 1.5 1 N/A 1000 200 430 11/17/21 21K1098-02RE1 [2021-IA-02]B295058 1.5 1 N/A 1000 200 75 11/17/21 Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 21K1098-03 [2021-SV-11B]B295141 1.5 1 N/A 1000 400 30 11/17/21 Page 12 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295058 - TO-15 Prep Blank (B295058-BLK1)Prepared & Analyzed: 11/17/21 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.35 L-03, V-34NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 13 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295058 - TO-15 Prep Blank (B295058-BLK1)Prepared & Analyzed: 11/17/21 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.35NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.08 LCS (B295058-BS1)Prepared & Analyzed: 11/17/21 5.00 70-13082.34.12Acetone 5.00 70-13091.94.59Benzene 5.00 70-13079.23.96Benzyl chloride 5.00 70-13092.94.65Bromodichloromethane 5.00 70-13090.84.54Bromoform 5.00 70-13093.04.65Bromomethane 5.00 70-13088.64.431,3-Butadiene 5.00 70-13084.64.232-Butanone (MEK) 5.00 70-13088.34.41Carbon Disulfide 5.00 70-13095.04.75Carbon Tetrachloride 5.00 70-13090.74.54Chlorobenzene 5.00 70-13092.54.62Chloroethane 5.00 70-13089.14.46Chloroform 5.00 70-13086.44.32Chloromethane 5.00 70-13095.34.77Cyclohexane 5.00 70-13088.74.44Dibromochloromethane 5.00 70-13090.74.541,2-Dibromoethane (EDB) 5.00 70-13092.04.601,2-Dichlorobenzene 5.00 70-13091.04.551,3-Dichlorobenzene 5.00 70-13075.13.761,4-Dichlorobenzene 5.00 70-13097.64.88Dichlorodifluoromethane (Freon 12) 5.00 70-13089.94.501,1-Dichloroethane 5.00 70-13091.94.601,2-Dichloroethane 5.00 70-13094.04.701,1-Dichloroethylene 5.00 70-13092.14.60cis-1,2-Dichloroethylene 5.00 70-13092.34.62trans-1,2-Dichloroethylene 5.00 70-13089.34.461,2-Dichloropropane Page 14 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295058 - TO-15 Prep LCS (B295058-BS1)Prepared & Analyzed: 11/17/21 5.00 70-13095.74.79cis-1,3-Dichloropropene 5.00 70-13098.34.91trans-1,3-Dichloropropene 5.00 70-13090.34.511,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-13093.54.681,4-Dioxane 5.00 L-05, V-3570-1301396.95Ethanol * 5.00 L-03, V-3470-13060.23.01Ethyl Acetate * 5.00 70-13093.24.66Ethylbenzene 5.00 70-13097.84.894-Ethyltoluene 5.00 70-13092.24.61Heptane 5.00 70-13082.84.14Hexachlorobutadiene 5.00 70-13095.34.76Hexane 5.00 70-13094.84.742-Hexanone (MBK) 5.00 70-13078.13.90Isopropanol 5.00 70-13088.94.45Methyl tert-Butyl Ether (MTBE) 5.00 70-13088.14.40Methylene Chloride 5.00 70-13098.54.924-Methyl-2-pentanone (MIBK) 5.00 70-13077.23.86Naphthalene 5.00 70-1301085.38Propene 5.00 70-13098.04.90Styrene 5.00 70-13093.24.661,1,2,2-Tetrachloroethane 5.00 70-13090.04.50Tetrachloroethylene 5.00 70-13092.24.61Tetrahydrofuran 5.00 70-13092.44.62Toluene 5.00 70-13071.83.591,2,4-Trichlorobenzene 5.00 70-1301015.071,1,1-Trichloroethane 5.00 70-13095.44.771,1,2-Trichloroethane 5.00 70-13098.74.94Trichloroethylene 5.00 70-13097.14.86Trichlorofluoromethane (Freon 11) 5.00 70-13099.74.981,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13091.64.581,2,4-Trimethylbenzene 5.00 70-13092.94.641,3,5-Trimethylbenzene 5.00 L-01, V-3670-1301447.22Vinyl Acetate * 5.00 70-13085.44.27Vinyl Chloride 10.0 70-13094.69.46m&p-Xylene 5.00 70-13096.04.80o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1038.21 Page 15 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295141 - TO-15 Prep Blank (B295141-BLK1)Prepared & Analyzed: 11/17/21 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.35 L-03NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene Page 16 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295141 - TO-15 Prep Blank (B295141-BLK1)Prepared & Analyzed: 11/17/21 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.35NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)95.57.64 LCS (B295141-BS1)Prepared & Analyzed: 11/17/21 5.00 70-13075.63.78Acetone 5.00 70-13085.34.26Benzene 5.00 70-13099.84.99Benzyl chloride 5.00 70-13084.34.21Bromodichloromethane 5.00 70-13089.54.48Bromoform 5.00 70-13074.13.71Bromomethane 5.00 70-13071.83.591,3-Butadiene 5.00 70-13092.14.612-Butanone (MEK) 5.00 70-13083.04.15Carbon Disulfide 5.00 70-13089.34.46Carbon Tetrachloride 5.00 70-13083.74.18Chlorobenzene 5.00 70-13073.73.68Chloroethane 5.00 70-13088.44.42Chloroform 5.00 70-13072.93.64Chloromethane 5.00 70-13080.14.00Cyclohexane 5.00 70-13087.14.35Dibromochloromethane 5.00 70-13086.84.341,2-Dibromoethane (EDB) 5.00 70-13086.34.311,2-Dichlorobenzene 5.00 70-13087.44.371,3-Dichlorobenzene 5.00 70-13086.04.301,4-Dichlorobenzene 5.00 70-13090.74.53Dichlorodifluoromethane (Freon 12) 5.00 70-13086.34.321,1-Dichloroethane 5.00 70-13090.54.521,2-Dichloroethane 5.00 70-13088.54.431,1-Dichloroethylene 5.00 70-13088.14.41cis-1,2-Dichloroethylene 5.00 70-13087.14.36trans-1,2-Dichloroethylene 5.00 70-13082.24.111,2-Dichloropropane Page 17 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B295141 - TO-15 Prep LCS (B295141-BS1)Prepared & Analyzed: 11/17/21 5.00 70-13089.54.47cis-1,3-Dichloropropene 5.00 70-13095.24.76trans-1,3-Dichloropropene 5.00 70-13073.43.671,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-13091.34.561,4-Dioxane 5.00 V-3570-1301025.08Ethanol 5.00 L-0370-13064.43.22Ethyl Acetate * 5.00 70-13092.14.61Ethylbenzene 5.00 70-13097.14.854-Ethyltoluene 5.00 70-13081.44.07Heptane 5.00 70-13086.64.33Hexachlorobutadiene 5.00 70-13096.64.83Hexane 5.00 70-13089.84.492-Hexanone (MBK) 5.00 70-13070.73.53Isopropanol 5.00 70-13093.74.68Methyl tert-Butyl Ether (MTBE) 5.00 70-13082.34.12Methylene Chloride 5.00 70-13087.94.404-Methyl-2-pentanone (MIBK) 5.00 70-1301045.18Naphthalene 5.00 70-13081.54.08Propene 5.00 70-13095.94.79Styrene 5.00 70-13080.74.041,1,2,2-Tetrachloroethane 5.00 70-13087.44.37Tetrachloroethylene 5.00 70-13090.54.52Tetrahydrofuran 5.00 70-13090.84.54Toluene 5.00 70-13095.04.751,2,4-Trichlorobenzene 5.00 70-13085.14.251,1,1-Trichloroethane 5.00 70-13085.64.281,1,2-Trichloroethane 5.00 70-13080.14.00Trichloroethylene 5.00 70-13073.43.67Trichlorofluoromethane (Freon 11) 5.00 70-13088.84.441,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13094.14.711,2,4-Trimethylbenzene 5.00 70-13095.94.801,3,5-Trimethylbenzene 5.00 L-01, V-3670-1301407.00Vinyl Acetate * 5.00 70-13072.03.60Vinyl Chloride 10.0 70-13094.79.47m&p-Xylene 5.00 70-13094.04.70o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)97.97.83 Page 18 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the high side. L-05 Elevated reporting limit due to high concentration of target compounds.RL-11 Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. V-34 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side for this compound. Reported result is estimated. V-35 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Page 19 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Rebecca FaustRLF Kerry K. McGeeKKM Brittany R. FiskBRF Page 20 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q 2021-IA-01 (21K1098-01 )Lab File ID: K21A321014.D Analyzed: 11/17/21 18:32 Bromochloromethane (1)57078 2.969 60 - 140 2.9690 +/-0.50 1,4-Difluorobenzene (1)177807 3.566 60 - 140 3.5660 +/-0.50 Chlorobenzene-d5 (1)171610 5.156 60 - 140 5.1560 +/-0.50 2021-IA-02 (21K1098-02 )Lab File ID: K21A321015.D Analyzed: 11/17/21 19:09 Bromochloromethane (1)58975 2.97 60 - 140 2.9700 +/-0.50 1,4-Difluorobenzene (1)182307 3.571 60 - 140 3.5710 +/-0.50 Chlorobenzene-d5 (1)176888 5.156 60 - 140 5.1560 +/-0.50 2021-IA-01 (21K1098-01RE1 )Lab File ID: K21A321029.D Analyzed: 11/18/21 06:51 Bromochloromethane (1)50291 2.969 60 - 140 2.9690 +/-0.50 1,4-Difluorobenzene (1)170467 3.571 60 - 140 3.5710 +/-0.50 Chlorobenzene-d5 (1)162318 5.156 60 - 140 5.1560 +/-0.50 2021-IA-02 (21K1098-02RE1 )Lab File ID: K21A321030.D Analyzed: 11/18/21 07:21 Bromochloromethane (1)47395 2.965 60 - 140 2.9650 +/-0.50 1,4-Difluorobenzene (1)158396 3.571 60 - 140 3.5710 +/-0.50 Chlorobenzene-d5 (1)149649 5.156 60 - 140 5.1560 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q 2021-SV-11B (21K1098-03 )Lab File ID: G21A321032.D Analyzed: 11/18/21 05:45 Bromochloromethane (1)1795426 8.503 60 - 140 8.5030 +/-0.50 1,4-Difluorobenzene (1)4732170 10.277 60 - 140 10.2770 +/-0.50 Chlorobenzene-d5 (1)4443046 14.642 60 - 140 14.6420 +/-0.50 Page 21 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL % DIFF / DRIFTRESPONSE FACTOR STD * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 22 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 23 of 27 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2022 PH-0165Connecticut Department of Publilc HealthCT 12/31/2022 10899 NELAPNew York State Department of HealthNY 04/1/2022 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2022 LAO00112Rhode Island Department of HealthRI 12/30/2021 652North Carolina Div. of Water QualityNC 12/31/2021 MA007 NELAPNew Jersey DEPNJ 06/30/2022 E871027 NELAPFlorida Department of HealthFL 06/30/2022 LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2022 MA00100State of MaineME 06/9/2023 460217Commonwealth of VirginiaVA 12/14/2021 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2022 25703North Carolina Department of HealthNC-DW 07/31/2022 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2022 9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022 Page 24 of 27 Page 25 of 27 Page 26 of 27 Page 27 of 27 APPENDIX C NCDEQ RISK CALCULATOR SUMMARY Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Terracon Consultants, Inc 2021-IA-02 North Carolina Department of Environmental Quality Risk Calculator Caraustar and Savona Mill Brownfields 23061-19-060 June 2021 May 2021 EPA RSL Table North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-IA-02 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 190 67-64-1 Acetone ug/m3 1.9 71-43-2 Benzene ug/m3 0.44 56-23-5 Carbon Tetrachloride ug/m3 0.32 67-66-3 Chloroform ug/m3 1 74-87-3 Chloromethane ug/m3 1 110-82-7 Cyclohexane ug/m3 0.57 106-46-7 Dichlorobenzene, 1,4-ug/m3 2.4 75-71-8 Dichlorodifluoromethane ug/m3 2.1 141-78-6 Ethyl Acetate ug/m3 1.3 100-41-4 Ethylbenzene ug/m3 36 142-82-5 Heptane, N-ug/m3 11 110-54-3 Hexane, N-ug/m3 5.9 67-63-0 Isopropanol ug/m3 4.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.71 75-09-2 Methylene Chloride ug/m3 0.55 91-20-3 ~Naphthalene ug/m3 0.77 100-42-5 Styrene ug/m3 1.6 127-18-4 Tetrachloroethylene ug/m3 7 108-88-3 Toluene ug/m3 0.49 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.079 79-01-6 Trichloroethylene ug/m3 1.3 75-69-4 Trichlorofluoromethane ug/m3 2.5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.77 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 4.1 106-42-3 Xylene, P-ug/m3 4.4 108-38-3 Xylene, m-ug/m3 1.8 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-IA-02 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 4.4E-06 1.6E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Terracon Consultants, Inc 2021-SV-11B North Carolina Department of Environmental Quality Risk Calculator Caraustar and Savona Mill Brownfields 23061-19-060 June 2021 May 2021 EPA RSL Table North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-SV-11B Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 280 67-64-1 Acetone ug/m3 2.3 67-66-3 Chloroform ug/m3 2.8 75-71-8 Dichlorodifluoromethane ug/m3 2 100-41-4 Ethylbenzene ug/m3 1.7 142-82-5 Heptane, N-ug/m3 150 67-63-0 Isopropanol ug/m3 28 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 6.7 91-20-3 ~Naphthalene ug/m3 160 127-18-4 Tetrachloroethylene ug/m3 5.8 108-88-3 Toluene ug/m3 2800 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2000 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 11 106-42-3 Xylene, P-ug/m3 11 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-SV-11B Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.7E-07 2.0E-01 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2021-IA-01 North Carolina Department of Environmental Quality Risk Calculator Caraustar and Savona Mill Brownfields 23061-19-060 June 2021 May 2021 EPA RSL Table Prepared By:Terracon Consultants, Inc North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-IA-01 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 98 67-64-1 Acetone ug/m3 1.8 71-43-2 Benzene ug/m3 0.43 56-23-5 Carbon Tetrachloride ug/m3 0.25 67-66-3 Chloroform ug/m3 0.97 74-87-3 Chloromethane ug/m3 1 110-82-7 Cyclohexane ug/m3 0.32 106-46-7 Dichlorobenzene, 1,4-ug/m3 2.4 75-71-8 Dichlorodifluoromethane ug/m3 1.3 141-78-6 Ethyl Acetate ug/m3 1.5 100-41-4 Ethylbenzene ug/m3 0.52 109-99-9 ~Tetrahydrofuran ug/m3 3.5 142-82-5 Heptane, N-ug/m3 12 110-54-3 Hexane, N-ug/m3 2.5 67-63-0 Isopropanol ug/m3 2.9 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.5 75-09-2 Methylene Chloride ug/m3 0.61 91-20-3 ~Naphthalene ug/m3 0.54 100-42-5 Styrene ug/m3 1.2 127-18-4 Tetrachloroethylene ug/m3 7.9 108-88-3 Toluene ug/m3 0.61 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.18 71-55-6 Trichloroethane, 1,1,1-ug/m3 1.3 75-69-4 Trichlorofluoromethane ug/m3 1.9 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.46 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 3.5 106-42-3 Xylene, P-ug/m3 3.5 108-38-3 Xylene, m-ug/m3 2 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: June 2021 Basis: May 2021 EPA RSL Table Site ID: 23061-19-060 Exposure Unit ID: 2021-IA-01 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 4.1E-06 1.2E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator