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HomeMy WebLinkAboutMO-6015_23108_G_WSW_20230705_PAYNEHRE July 5, 2023 Janice Payne P.O. Box 417 Alexis, North Carolina 28006 Re: Health Risk Evaluation of Water Supply Tracking ID: Inc. No. 23108 Dear Ms. Payne: Please find attached the Sample Analytical Results for the water samples collected from your well, identified as WS-6 (Before) and WS-6 (after), located at 120 Alexis-Lucia Road, Alexis, Gaston County, on May 5, 2023. The samples were collected and analyzed as part of the investigation of a petroleum release in the vicinity. The water samples were analyzed for specific target analytes (contaminants), which are listed on the attached Sample Analytical Results. Contaminants were detected in the water samples, as shown on the attached Sample Analytical Results. Because contaminants were detected in the water sample, a Health Risk Evaluation of each water supply sample was performed by an environmental toxicologist in the Division of Waste Management. The Health Risk Evaluation, which is attached also, compares the detected concentration of contaminants to acceptable concentrations and provides a recommendation for safe use of the water. If you have any questions, please contact David Lilley at (919) 707-8200, or contact me at (704) 663-1699. Sincerely, Brad C. Newton, P.G. Hydrogeologist Mooresville Regional Office UST Section, Division of Waste Management, NCDEQ Attachments: Payne Sample Analytical Results Health Risk Evaluation cc: Gaston County Health Department Gaston County Manager July 5, 2023 TO: Brad Newton Mooresville Regional Office NC UST Section RE: Health Risk Evaluation Incident # 23108 Payne Well Sampling Results (before) 120 Alexis-Lucia Road Alexis, NC During this sampling event, two contaminants were detected in the well water. The standards used to determine if the water is suitable for drinking and cooking are the United States Environmental Protection Agency’s Maximum Contaminant Levels (MCLs) or, if no MCLs exist, North Carolina Groundwater Standards (2L). If any contaminant concentrations exceed applicable standards for using the water for drinking and cooking, those contaminant concentrations are further analyzed to determine if the water is suitable for other household uses, such as showering, bathing, washing dishes, flushing toilets, and hand washing. The chart below compares the detected contaminant concentrations with the applicable standards: Sample ID Contaminant Concentration (µg/L) MCL (µg/L) 2L (µg/L) YE08015-003 Methyl tertiary butyl ether 2.0 20 Methylene chloride 0.50 5 µg/L – Stands for micrograms of contaminant per liter of water and is roughly equivalent to parts per billion. RECOMMENDATION: None of the contaminants detected exceeded the applicable water standards. Therefore, no restrictions on the use of this water are recommended at this time. David Lilley, Environmental Toxicologist Division of Waste Management, NCDEQ July 5, 2023 TO: Brad Newton Mooresville Regional Office NC UST Section RE: Health Risk Evaluation Incident # 23108 Payne Well Sampling Results (after) 120 Alexis-Lucia Road Alexis, NC During this sampling event, one contaminant was detected in the well water. The standards used to determine if the water is suitable for drinking and cooking are the United States Environmental Protection Agency’s Maximum Contaminant Levels (MCLs) or, if no MCLs exist, North Carolina Groundwater Standards (2L). If the contaminant concentration exceeds the applicable standard for using the water for drinking and cooking, the contaminant concentration is further analyzed to determine if the water is suitable for other household uses, such as showering, bathing, washing dishes, flushing toilets, and hand washing. The chart below compares the detected contaminant concentration with the applicable standard: Sample ID Contaminant Concentration (µg/L) MCL (µg/L) 2L (µg/L) YE08015-004 Methyl tertiary butyl ether 2.1 20 µg/L – Stands for micrograms of contaminant per liter of water and is roughly equivalent to parts per billion. RECOMMENDATION: The detected contaminant did not exceed the applicable water standard. Therefore, no restrictions on the use of this water are recommended at this time. David Lilley, Environmental Toxicologist Division of Waste Management, NCDEQ Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (Before) YE08015-003 05/05/2023 1158 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 05/18/2023 0244 CDA 75593 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 SM 6200B-2011 ND 1ug/L10 Benzene 71-43-2 SM 6200B-2011 ND 1ug/L0.50 Bromobenzene 108-86-1 SM 6200B-2011 ND 1ug/L0.50 Bromochloromethane 74-97-5 SM 6200B-2011 ND 1ug/L0.50 Bromodichloromethane 75-27-4 SM 6200B-2011 ND 1ug/L0.50 Bromoform 75-25-2 SM 6200B-2011 ND 1ug/L0.50 Bromomethane (Methyl bromide)74-83-9 SM 6200B-2011 ND 1ug/L0.50 2-Butanone (MEK)78-93-3 SM 6200B-2011 ND 1ug/L10 n-Butylbenzene 104-51-8 SM 6200B-2011 ND 1ug/L0.50 sec-Butylbenzene 135-98-8 SM 6200B-2011 ND 1ug/L0.50 tert-Butylbenzene 98-06-6 SM 6200B-2011 ND 1ug/L0.50 Carbon tetrachloride 56-23-5 SM 6200B-2011 ND 1ug/L0.50 Chlorobenzene 108-90-7 SM 6200B-2011 ND 1ug/L0.50 Chloroethane 75-00-3 SM 6200B-2011 ND 1ug/L0.50 Chloroform 67-66-3 SM 6200B-2011 ND 1ug/L0.50 Chloromethane (Methyl chloride)74-87-3 SM 6200B-2011 ND 1ug/L0.50 2-Chlorotoluene 95-49-8 SM 6200B-2011 ND 1ug/L0.50 4-Chlorotoluene 106-43-4 SM 6200B-2011 ND 1ug/L0.50 Dibromochloromethane 124-48-1 SM 6200B-2011 ND 1ug/L0.50 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-2011 ND 1ug/L0.50 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichlorobenzene 95-50-1 SM 6200B-2011 ND 1ug/L0.50 1,3-Dichlorobenzene 541-73-1 SM 6200B-2011 ND 1ug/L0.50 1,4-Dichlorobenzene 106-46-7 SM 6200B-2011 ND 1ug/L0.50 Dichlorodifluoromethane 75-71-8 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloroethane 75-34-3 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichloroethane 107-06-2 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloroethene 75-35-4 SM 6200B-2011 ND 1ug/L0.50 cis-1,2-Dichloroethene 156-59-2 SM 6200B-2011 ND 1ug/L0.50 trans-1,2-Dichloroethene 156-60-5 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichloropropane 78-87-5 SM 6200B-2011 ND 1ug/L0.50 1,3-Dichloropropane 142-28-9 SM 6200B-2011 ND 1ug/L0.50 2,2-Dichloropropane 594-20-7 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloropropene 563-58-6 SM 6200B-2011 ND 1ug/L0.50 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-2011 ND 1ug/L0.50 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-2011 ND 1ug/L0.50 Diisopropyl ether (IPE)108-20-3 SM 6200B-2011 ND 1ug/L0.50 Ethylbenzene 100-41-4 SM 6200B-2011 ND 1ug/L0.50 Hexachlorobutadiene 87-68-3 SM 6200B-2011 ND 1ug/L0.50 2-Hexanone 591-78-6 SM 6200B-2011 ND 1ug/L10 Isopropylbenzene (Cumene)98-82-8 SM 6200B-2011 ND 1ug/L0.50 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-2011 ND 1ug/L0.50 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-2011 2.0 1ug/L0.50 4-Methyl-2-pentanone 108-10-1 SM 6200B-2011 ND 1ug/L10 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 11 of 28 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (Before) YE08015-003 05/05/2023 1158 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 05/18/2023 0244 CDA 75593 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Methylene chloride 75-09-2 SM 6200B-2011 0.50 1ug/L0.50 Naphthalene 91-20-3 SM 6200B-2011 ND 1ug/L0.50 n-Propylbenzene 103-65-1 SM 6200B-2011 ND 1ug/L0.50 Styrene 100-42-5 SM 6200B-2011 ND 1ug/L0.50 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-2011 ND 1ug/L0.50 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-2011 ND 1ug/L0.50 Tetrachloroethene 127-18-4 SM 6200B-2011 ND 1ug/L0.50 Toluene 108-88-3 SM 6200B-2011 ND 1ug/L0.50 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-2011 ND 1ug/L0.50 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-2011 ND 1ug/L0.50 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-2011 ND 1ug/L0.50 1,1,1-Trichloroethane 71-55-6 SM 6200B-2011 ND 1ug/L0.50 1,1,2-Trichloroethane 79-00-5 SM 6200B-2011 ND 1ug/L0.50 Trichloroethene 79-01-6 SM 6200B-2011 ND 1ug/L0.50 Trichlorofluoromethane 75-69-4 SM 6200B-2011 ND 1ug/L0.50 1,2,3-Trichloropropane 96-18-4 SM 6200B-2011 ND 1ug/L0.50 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-2011 ND 1ug/L0.50 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-2011 ND 1ug/L0.50 Vinyl chloride 75-01-4 SM 6200B-2011 ND 1ug/L0.50 m+p - Xylenes 179601-23-1 SM 6200B-2011 ND 1ug/L0.50 o - Xylenes 95-47-6 SM 6200B-2011 ND 1ug/L0.50 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 110 70-130 Bromofluorobenzene 86 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 12 of 28 EDB & DBCP by Microextraction Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (Before) YE08015-003 05/05/2023 1158 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 05/12/2023 1543 MEZ 05/12/2023 1038 75138 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.0097 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 84 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 13 of 28 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (After) YE08015-004 05/05/2023 1211 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 05/18/2023 0307 CDA 75593 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Acetone 67-64-1 SM 6200B-2011 ND 1ug/L10 Benzene 71-43-2 SM 6200B-2011 ND 1ug/L0.50 Bromobenzene 108-86-1 SM 6200B-2011 ND 1ug/L0.50 Bromochloromethane 74-97-5 SM 6200B-2011 ND 1ug/L0.50 Bromodichloromethane 75-27-4 SM 6200B-2011 ND 1ug/L0.50 Bromoform 75-25-2 SM 6200B-2011 ND 1ug/L0.50 Bromomethane (Methyl bromide)74-83-9 SM 6200B-2011 ND 1ug/L0.50 2-Butanone (MEK)78-93-3 SM 6200B-2011 ND 1ug/L10 n-Butylbenzene 104-51-8 SM 6200B-2011 ND 1ug/L0.50 sec-Butylbenzene 135-98-8 SM 6200B-2011 ND 1ug/L0.50 tert-Butylbenzene 98-06-6 SM 6200B-2011 ND 1ug/L0.50 Carbon tetrachloride 56-23-5 SM 6200B-2011 ND 1ug/L0.50 Chlorobenzene 108-90-7 SM 6200B-2011 ND 1ug/L0.50 Chloroethane 75-00-3 SM 6200B-2011 ND 1ug/L0.50 Chloroform 67-66-3 SM 6200B-2011 ND 1ug/L0.50 Chloromethane (Methyl chloride)74-87-3 SM 6200B-2011 ND 1ug/L0.50 2-Chlorotoluene 95-49-8 SM 6200B-2011 ND 1ug/L0.50 4-Chlorotoluene 106-43-4 SM 6200B-2011 ND 1ug/L0.50 Dibromochloromethane 124-48-1 SM 6200B-2011 ND 1ug/L0.50 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-2011 ND 1ug/L0.50 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichlorobenzene 95-50-1 SM 6200B-2011 ND 1ug/L0.50 1,3-Dichlorobenzene 541-73-1 SM 6200B-2011 ND 1ug/L0.50 1,4-Dichlorobenzene 106-46-7 SM 6200B-2011 ND 1ug/L0.50 Dichlorodifluoromethane 75-71-8 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloroethane 75-34-3 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichloroethane 107-06-2 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloroethene 75-35-4 SM 6200B-2011 ND 1ug/L0.50 cis-1,2-Dichloroethene 156-59-2 SM 6200B-2011 ND 1ug/L0.50 trans-1,2-Dichloroethene 156-60-5 SM 6200B-2011 ND 1ug/L0.50 1,2-Dichloropropane 78-87-5 SM 6200B-2011 ND 1ug/L0.50 1,3-Dichloropropane 142-28-9 SM 6200B-2011 ND 1ug/L0.50 2,2-Dichloropropane 594-20-7 SM 6200B-2011 ND 1ug/L0.50 1,1-Dichloropropene 563-58-6 SM 6200B-2011 ND 1ug/L0.50 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-2011 ND 1ug/L0.50 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-2011 ND 1ug/L0.50 Diisopropyl ether (IPE)108-20-3 SM 6200B-2011 ND 1ug/L0.50 Ethylbenzene 100-41-4 SM 6200B-2011 ND 1ug/L0.50 Hexachlorobutadiene 87-68-3 SM 6200B-2011 ND 1ug/L0.50 2-Hexanone 591-78-6 SM 6200B-2011 ND 1ug/L10 Isopropylbenzene (Cumene)98-82-8 SM 6200B-2011 ND 1ug/L0.50 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-2011 ND 1ug/L0.50 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-2011 2.1 1ug/L0.50 4-Methyl-2-pentanone 108-10-1 SM 6200B-2011 ND 1ug/L10 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 14 of 28 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (After) YE08015-004 05/05/2023 1211 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 05/18/2023 0307 CDA 75593 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Methylene chloride 75-09-2 SM 6200B-2011 ND 1ug/L0.50 Naphthalene 91-20-3 SM 6200B-2011 ND 1ug/L0.50 n-Propylbenzene 103-65-1 SM 6200B-2011 ND 1ug/L0.50 Styrene 100-42-5 SM 6200B-2011 ND 1ug/L0.50 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-2011 ND 1ug/L0.50 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-2011 ND 1ug/L0.50 Tetrachloroethene 127-18-4 SM 6200B-2011 ND 1ug/L0.50 Toluene 108-88-3 SM 6200B-2011 ND 1ug/L0.50 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-2011 ND 1ug/L0.50 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-2011 ND 1ug/L0.50 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-2011 ND 1ug/L0.50 1,1,1-Trichloroethane 71-55-6 SM 6200B-2011 ND 1ug/L0.50 1,1,2-Trichloroethane 79-00-5 SM 6200B-2011 ND 1ug/L0.50 Trichloroethene 79-01-6 SM 6200B-2011 ND 1ug/L0.50 Trichlorofluoromethane 75-69-4 SM 6200B-2011 ND 1ug/L0.50 1,2,3-Trichloropropane 96-18-4 SM 6200B-2011 ND 1ug/L0.50 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-2011 ND 1ug/L0.50 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-2011 ND 1ug/L0.50 Vinyl chloride 75-01-4 SM 6200B-2011 ND 1ug/L0.50 m+p - Xylenes 179601-23-1 SM 6200B-2011 ND 1ug/L0.50 o - Xylenes 95-47-6 SM 6200B-2011 ND 1ug/L0.50 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 111 70-130 Bromofluorobenzene 86 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 15 of 28 EDB & DBCP by Microextraction Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. WS-6 (After) YE08015-004 05/05/2023 1211 05/08/2023 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 05/12/2023 1555 MEZ 05/12/2023 1038 75138 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.0099 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 78 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failureW = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) Page 16 of 28