MO-5710_20107_CA_MRP_20230724

June 14, 2023
Groundwater Sampling and Analyses Event
Gold Mine 66
5949 Sherrills Ford Road
Catawba, North Carolina
Incident No.: 20107
Facility ID No.: 0-007037
Risk Classification: High
Land Use: Industrial/Commercial
Lat: 35° 39' 03" North
Long: 8JD03' 13" West
Release Discovery Date: March 11, 1999
Estimated Quantity: Unknown
Commercial USTs: 2,000-Gallon Gasoline
6,000-Gallon Gasoline
550-Gallon Kerosene
Prepared for (Owner):
Ms. Cyndi Miller
Drum's Self Service, Inc.
5949 Sherrills Ford Road
Catawba, North Carolina 28609
[phone]
Prepared by (Consultant):
Harmon Environmental, PA
Ric/tar L. Harmon, P.G. 615 Bruce Thomas Road
Monroe, North Carolina 28112
704-292-4527
www.harmonenvironmental.com
President/Principal Hydrogeologist
July 12, 2023
June 14, 2023 Groundwater Sampling and Analyses Event
Gold Mine 66
5949 Sherrills Ford Road
Catawba, North Carolina
Table of Contents
Section Page
1. 0 Discussion of Sampling Methods and Results ..................................................................... 1
2. 0 Conclusions and Recommendations .................................................................................... 2
Figure 1
Figure 2
Figure 3
Figure 4
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Table 8
Table 9
Table 10
Table 11
Site Location Map
Site Layout Map
List of Figures
Shallow Groundwater Potentiometric Map
June 14, 2023 Groundwater Analytical Results
List of Tables
Groundwater Levels and Well Construction Details (B-7 Format)
Summary of Historic Groundwater Elevation Measurements
Summary of June 14, 2023 Groundwater Samples Analytical Results
Summary of Historic Groundwater Analytical Data MW-1
Summary of Historic Groundwater Analytical Data MW-2
Summary of Historic Groundwater Analytical Data MW-3
Summary of Historic Groundwater Analytical Data MW-4
Summary of Historic Groundwater Analytical Data MW-5
Summary of Historic Groundwater Analytical Data MW-6D
Summary of Historic Groundwater Analytical Data MW-7
Summary of Historic Groundwater Analytical Data MW-8
List of Appendices
Appendix A Analytical Report and Chain-ofCustody Record, June 14, 2023 Groundwater
Sampling Event
June 14, 2023 Groundwater Sampling and Analyses Event
Gold Mine 66
5949 Sherrills Ford Road
Catawba, North Carolina
1.0 Discussion ofSampling Methods and Results
On June 1, 2023, Harmon Environmental, P A was retained by Gold Mine 66 to address the
requirements of the May 16, 2022 letter from the North Carolina Department of Environmental
Quality (NCDEQ) requesting a groundwater sampling event be conducted at the facility.
On June 1, 2023, Harmon Environmental, P A on behalf of Gold Mine 66 submitted a letter to the
NCDEQ requesting an extension to the 2023 sampling event. On June 5, 2023, Mr. Brad Newton,
P.G. of the NCDEQ granted an extension to July 15, 2023. To comply with the May 16,2022
letter, prior to initiating these activities, on June 2, 2023, Harmon Environmental, PA requested
trust fund pre-approval to complete the requested task. On June 7, 2023, Harmon Environmental,
PA received pre-approval under Task Authorization 27 for conducting these services.
Figure 1 presents the location ofthe Gold Mine 66 site on an excerpt from a United States Geologic
Survey (USGS), 7.5-minute topographic series map of the region.
On June 14,2023, Harmon Environmental, PA personnel collected groundwater samples from the
five monitor wells (MW-1, MW-2, MW-3, MW-6D and MW-7) and the water supply well located
at 5936 Sherrills Ford Road. These groundwater samples were collected in general accordance
with NCDEQ accepted sampling protocols. As collected, each ofthe groundwater samples were
placed in a cooler on ice pending delivery to Waypoint Analytical, LLC for analyses. Chain-of-
Custody protocol was maintained throughout the sample shipping process. Upon receipt,
Waypoint analyzed the samples for volatile organic compounds by EPA Standard Method 6200B
extended to include methyl tert butyl ether, isopropyl ether, and ethylene dibromide.
Prior to collecting the groundwater samples, the water level was measured relative to the top of
the well casing using an electronic water level indicator. The water levels and calculated
groundwater elevations, based on an arbitrary on-site datum, are presented in Table 1. Figure 3
presents a water table potentiometric map generated based on the calculated groundwater
elevations associated with the June 14, 2023 groundwater measurements. As indicated by this
map, the horizontal component of shallow groundwater flow in the vicinity of the former
underground storage tanks is generally toward the northeast-northeast with a calculated horizontal
gradient of approximately 0.01 feet per foot (ft/ft).
Laboratory equipment failure caused holding time issues with some of the samples. On July 5,
2023 , Harmon Environmental, PA contacted Mr. Brad Newton, P.G. of the NCDEQ via telephone
and left a voice mail message explaining the issue. Harmon Environmental, P A offered to
resample should the NCDEQ desire. On July 5, 2023, Mr. Newton advised Harmon
Environmental, P A via email to proceed with the report preparation and submission without
resampling.
June 14. 202 3 Groundwa!er Sampling Even!
Goldmine 66
5949 Sherrills Ford Rd., Calmvba, North Carolina
July 12, 2023
Harmon Environmental, PA
615 Bruce Thomas Road
Monroe, North Carolina
www. harmonenvironmental. com
The analytical results associated with the June 14, 2023 sampling event are summarized on Table
3 and Figure 4. These results are also presented with the historical data associated with
groundwater samples collected from the monitor well network on Tables 4 through 11 .
2. 0 Conclusions and Recommendations
The analytical results associated with the June 14, 2023 groundwater sampling event indicated
benzene, 1,1 ,2-trichloroethane, 1 ,2-trichloroethene, naphthalene and me thy 1 tert butyl ether were
present in concentrations exceeding the North Carolina Groundwater Quality Standard as
established in North Carolina Administrative Code, Title 15A, Subchapter 2L (15A NCAC 2L).
Benzene was detected in the sample collected from monitor well MW -2 at a concentration of 6.67
micrograms per liter (f!g/L). The Groundwater Quality Standard for benzene established in North
Carolina Administrative Code, Title 15A, Subchapter 2L is 1 f!g/L. 1,1 ,2-trichloroethane was
detected in the sample collected from monitor well MW-2 at a concentration of 1.93 f!g/L. The
Groundwater Quality Standard for 1,1 ,2-trichlroethane is 0.6 f!g/L. 1 ,2-dichloroethane was
detected at concentrations of 1.19 f!g/L, 79.6 f!g/L and 3.41 f!g/L in the samples collected from
monitor wells MW-1 , MW-2 and MW-6D, respectively. The Groundwater Quality Standard for
1 ,2-dichloroethane is 0.4 f!g/L. Naphthalene was detected in the June 14, 2023 sample from
monitor well MW-2 at a concentration of 95.4 f!g/L. The Groundwater Quality Standard for
naphthalene is 6 f!g/L. Methyl tert butyl ether was detected in the samples collected from monitor
wells MW-1, MW-2 and MW-6D at concentrations of 60.7 f!g/L, 96.7 f!g/L and 56.5 f!g/L,
respectively. The Groundwater Quality Standard for Methyl tert butyl ether is 20 f!g/L.
The analytical results associated with the April 26, 2022 sample collected from an outside faucet
at 5936 Sherrills Ford Road indicated the presence of chloroform at 3.59 f!g/L. The Groundwater
Quality Standard for chloroform is 70 f!g/L. It should be noted that the 5936 Sherrills Ford sample
exceeded the hold time due to laboratory equipment failure.
Based on a review of the recent data and historical analytical data associated with the site, Harmon
Environmental, P A recommends the DENR consider continuing the annually routine monitoring
at this site. Based on the historic analytical data and the well construction information, Harmon
Environmental, P A recommends the mmual groundwater sampling event be limited to monitor
wells MW-1, MW-2, MW-6D and MW-7 and the water supply well at 5936 Sherrills Ford Road.
June 14. 2023 Groundwater Sampling Event
Goldmine 66
5949 Sherrills Ford Rd., Catawba, North Carolina
July 12, 2023
2 Harmon Environmental, PA
615 Bruce Thomas Road
Monroe, North Carolina
1Vlvw.harmonenvironmental.com
Figures
SOURCE: MAPTECH.COM
HARMON ENVIRONMENTAL, PA
615 BRUCE THOMAS ROAD
MONROE, NORTH CAROLINA 28112
704-292-4527
harmonenvironmental.com
APPROXIMATE SCALE IN FEET
0 2000
FIGURE 1
SITE LOCATION MAP
GOLD MINE 66
5949 SHERRILLS FORD ROAD
CATAWBA, NORTH CAROLINA
4000
MW-8 • I
4 MW-7
I
I
I
I
I
~-I
I
ASPHALT
~--PLANTER
MW-6D.
4 MW-1
I
I
BUILDING
MW-5
---------~ MW-2 c _ PLANTER ~
EAST BANDY'S ROAD
REFERENCE: FIGURE 1, COMPREHENSIVE SITE ASSESSMENT ADDENDUM, TRIGON ENGINEERING CONSULTANTS, INC., JULY 22,2002 AND CATAWBA COUNTY GIS.
'
4 MW-4 ' '
GRAVEL PARKING AREA
GRASS
LEGEND
APPROXIMATE LOCATION OF MONITOR WELLS
APPROXIMATE LOCATION OF PROPERTY BOUNDARIES
APPROXIMATE LOCATION OF STRUCTURES
I
_ __/
APPROXIMATE SCALE IN FEET
0 30 60
• ...J
~ z w ~ z
~ -> z w
z
0 ~
0::: <( :c
316-25FIG2.DWG
~-I
I
I
MW-B-t
I
I
I
I
I
I
_.t,_MW-7
'!"" 59.13 -59-25-
59.50---
.........
-
I
........
' ..._5
I
MW-3 ""'-.........
60.0B '!"" ......... ......... ' I ~~
GRAVEL
DRIVEWAY
/
ASPHALT
I
I
,....
_,---IPLANTER
I
CANOPY X
I r----~
I
BUILDING I
I
I
I /
/
/
' -...;GRASS '-
60.:Js
MW-6D.
.MW-1
60.43
CANOPY
c_ PLANTER Mw-!t"\
----60.5_4 _ _j......t..._
EAST BANDY'S ROAD
'
LEGEND
APPROXIMATE LOCATION OF MONITOR WELLS
APPROXIMATE LOCATION OF PROPERlY BOUNDARIES
APPROXIMATE LOCATION OF STRUCTURES
- -60 - -SHALLOW POTENTIOMETRIC CONTOUR INTERVAL BASED
ON THE JUNE 14. 2023 WATER LEVEL MEASUREMENTS
' '
CALCULATED GROUNDWATER ELEVATION IN MONITOR WELL
60.0B AS MEASURED ON JUNE 14. 2023 BASED ON ARBITRARY
ON-SITE DATUM
SHALLOW HORIZONTAL GROUNDWATER FLOW DIRECTION
NOTES:
THE POTENTIOMETRIC CONTOURS PRESENTED IN THIS
DRAWING ARE BASED ON INTERPOLATION BETWEEN THE
GROUNDWATER ELEVATIONS MEASURED IN EACH
OF THE MONITOR WELLS ON JUNE 14. 2023.
GRAVEL PARKING AREA
GRASS
I
___/
APPROXIMATE SCALE IN FEET
REFERENCE: FIGURE 1. COMPREHENSIVE SITE ASSESSMENT ADDENDUM. TRIGON ENGINEERING CONSULTANTS. INC.. JULY 22.2002 AND CATAWBA COUNlY GIS. 0 30 60
J ~ z w
~ z ~ -> z w
z
0 ~
<( :r:
0
I
~-!
I
I
I
MW-8 •
I
I
I
I
I
GRAVEL
DRIVEWAY
BUILDING
PLANTER
EAST BANDY'S ROAD
APPROXIMATE SCALE IN FEET
30 60
ASPHALT
MW-7
METHOD 6200B
NO TARGETED COMPOUNDS DETECTED ABOVE
THE ANALYTICAL METHOD REPORTING LIMIT (H).
MW-3
METHOD 6200B
ACETONE 2.54 ug/L
MW-6D
METHOD 6200B
'I' 1,2-DICHLOROETHANE
BENZENE '
~ METHYL TERT BUTYL ETHER
XYLENES (TOTAL)
ISOPROPYL ETHER
' VINYL CHLORIDE GRASS '
-t .... '
~ .r.y<"~ ' ;e.«,.
MW-4 •
ug/L
3.41 ug/L
0.546 ug/L
56.5 ug/L
1.46(J) ug/L
4.57 ug/L
0.203()) ug/L
GRASS I
__/
REFERENCE: FIGURE 1, COMPREHENSIVE SITE ASSESSMENT ADDENDUM, TRIGON ENGINEERING CONSULTANTS, INC., JULY 22, 2002 AND CATAWBA COUNTY GIS.
LEGEND
APPROXIMATE LOCATION OF MONITOR WELLS
APPROXIMATE LOCATION OF PROPERTY BOUNDARY
APPROXIMATE LOCATION OF STRUCTURES
MICROGRAMS PER LITER
NOTES:
THE GROUNDWATER ANALYTICAL RESULTS PRESENTED
ON THIS MAP ARE BASED ON SAMPLES COLLECTED ON
JUNE 14,2023 BY HARMON ENVIRONMENT A L, PA
PERSONNEL AND ANALYZED BY WAYPOINT
ANALYTICAL SERVICES, LLC OF CHARLOTTE, N ORTH
CAROLINA.
H = ANALYTE CONCENTRATIONS EXCEEDED
CALIBRATION. DUE TO EQUIPMENT FAILURE AT THE
ANALYZING LABORATORY
J =ESTIMATED CONCENTRATION BELOWTH E
ANALYTICAL METOHD DETECTION LIMIT
MW-1
METHOD 6200B
ACETONE 2.06 (J) ug/L
1,2-DICHLOROETHANE 1.19 ug/L
METHYL TERT BUTYL ETHER 60.7 ug/L
ISOPROPYL ETHER 1.71 ug/L
MW-2
METHOD 6200B
ACETONE 7.63 (J) ug/L
BROMOMETHANE 0.52 (J) ug/L
ISOPROPYL ETHER 10.4 ug/L
1,2-DIBROMOETHANE 18.0 ug/L
1,1-DICHLOROPROPANE 0.305 (J) ug/L
2-HEXANONE 3.36 ug/L
4-ISOPROPYL TOLUENE 2.41 ug/L
4-METHYL-2-PENTANONE 5.25 ug/L
1,1,2-TRICHLOROETHANE 1.92 ug/L
1,2,4-TRIMETHYLBENZENE 138 (H) ug/L
1,3,5-TRIMETHYLBENZENE 98.3 (H) ug/L
1,2-DICHLOROETHANE 79.6 ug/L
ISOPROPYLBENZENE 7.31 ug/L
TOLUENE 12.3 ug/L
NAPHTHALENE 95.4 ug/L
N-BUTYLBENZENE 1.46 ug/L
N-PROPYLBENZENE 7.54 ug/L
SEC-BUTYLBENZENE 1.38 ug/L
ETHYLBENZENE 24.6 ug/L
BENZENE 6.67 ug/L
METHYL TERT BUTYL ETHER 96.7 ug/L
XYLENES (TOTAL) 702 (H) ug/L
<(
Q..
• ....J
<(
1-z w
~ z
0 ~ -> z w
z
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Tables
Table 1
Groundwater Levels and Well Construction Details
Well Construction Information
Appendix B
Reporting Tables
(Table B-7 format)
D J l 11 2023 I . d N b d N 201 07 G ld M. 66 ate: uv net ent urn er an arne: ' 0 me act 1ty I -7 37 F ·1· D# 0 00 0
Date Water Well Free-
Date Level Casing Bottom of Depth to Water Product
Installed Measured Depth Screened Interval Well Top of Casing from Top of Thickness Groundwater
Well ID (m/dd/yy) (m/dd/yy) (ft. BGS) (!. to y ft. BGS) (ft. BGS) Elevation* (ft.) Casing (ft.) ** (ft.) Elevation (ft.)
MW-l 01 /11/00 6/14/23 42 42 to 52 52 97.43 37.00 None 60.43
MW-2 0 l/1l/OO 6/14/23 40 40 to 50 50 100.01 39.47 None 60.54
MW-3 12/01 6/14/23 43 43 to 48 48 95.08 35.00 None 60.08
MW-4 12/0l Not Measured 45 45 to 50 50 98.84 Not Measured None Not Measured
MW-5 12/0l Not Measured 55 55 to 60 60 101.29 Not Measured None Not Measured
MW-6D 12/01 6/14/23 45 45 to 55 55 97.30 36.60 None 60.70
MW-7 6/02 6/14/23 43 43 to 53 53 91.93 32.80 None 59.13
MW-8 10/31/02 Not Measured 45 45 to 60 60 Not Surveyed Not Measured None Not Measured
* Reference Pomt for Elevation Measurements Assumed ElevatiOn: 100.00 ft.
** If free product is present in a well, groundwater elevation should be calculated by [Top of Casing Elevation -Depth to Water] + [free product thickness x 0.8581]
Monitor wells MW-1 and MW-2 were installed under the oversight of Spatco Engineering and Geological Services, P.C.
Monitor wells MW-3, MW-4, MW-5, MW-6D and MW-7 were installed under the oversight of Trigon Engineering Consultants, Inc.
Monitor well MW -8 was installed under the oversight of Harmon Environmental, P A
B-71
Comments
April2001
I Well No. I
Top of Casing
Elevation
Table 2
Summary of Historic Groundwater Elevation Measurements
Goldmine 66, 5949 Sherrills Ford Road, Catawba. North Carolina
Incident No. 20107, Project No. 316-25
MW-1 MW-2 MW-3 MW-4 MW-5 MW-6D
97.43 100.01 95.08 98.84 101.29 97.30
MW-7 MW-8
91.93 Not Surveyed
I Measurement Date I
9/11/1999 55.27 60.43 ------------------
1/11 /2000 56.40 56.33 ------------------
12/27/2001 52.22 52.31 51.93 52.27 53.02 49.63 ------
6/19/2002 50.88 51.22 50.57 51.38 51.59 Not Measured ------
11/1/2002 Dry 50.40 49.85 50.52 50.86 50.29 49.58 Not Surveyed
2/4/2003 Dry 50.62 50.17 50.71 50.93 50.38 44.78 Not Surveyed
4/28/2003 52.04 52.46 52.12 52.58 52.85 52.22 49.09 Not Surveyed
8/14/2003 57.18 57.58 48.05 57.89 68.24 57.28 50.98 Not Surveyed
1/20/2004 60.02 60.33 59.56 60.65 60.89 60.20 55 .93 Not Surveyed
7/29/2004 60.13 60.41 59.68 Not Measured Not Measured 60.25 58.68 Not Surveyed
2/14/2007 57.43 57.69 57.26 58.08 58.30 57.56 56.18 Not Surveyed
10/29/2007 56.25 55.81 55.12 Not Measured Not Measured 55.66 54.02 Not Surveyed
4/15/2008 53.11 53.41 52.94 53.74 53.90 53.20 51 .81 Not Surveyed
10/22/2008 51.86 52.2 51.83 52.43 52.68 51.98 50.74 Not Surveyed
5/26/2009 52.21 52.49 52.29 52.79 53.06 52.36 51.08 Not Surveyed
4/12/2010 56.98 57.36 56.80 57.62 57.93 57.4 55.67 Not Surveyed
4/19/2011 57.64 58.31 57.59 55.99 60.69 58.34 56.36 Not Surveyed
4/20/2012 54.78 54.29 54.63 55.34 55.55 54.81 53.58 Not Surveyed
4/26/2013 52.27 53.92 52.24 50.5 3 54.19 53.33 51.08 Not Surveyed
5/8/2014 54.24 54.06 54.19 54.79 55.00 54.17 53.10 Not Surveyed
4/13/2015 53.15 53.49 53.76 54.49 54.50 53.38 52.29 Not Surveyed
4/14/2016 54.01 54.32 54.10 54.62 54.89 54.12 52.84 Not Surveyed
4/12/2017 53.15 53.42 53.34 Not Measured Not Measured 53.25 51.98 Not Surveyed
4/10/2018 51.89 52.12 59.76 Not Measured Not Measured 54.95 50.79 Not Measured
4/30/2019 58.94 59.23 58.73 Not Measured Not Measured 59.06 57.57 Not Measured
4/28/2020 61.22 61.47 60.93 Not Measured Not Measured 61.33 79.92 Not Measured
4/23/2021 66.43 65.51 65.95 Not Measured Not Measured 66.6 65.18 Not Measured
4/26/2022 59.09 61.25 61.03 Not Measured Not Measured 61.37 59.88 Not Measured
5/14/2023 60.43 60.54 60.08 Not Measured Not Measured 60.70 59.13 Not Measured
Notes: Groundwater elevation measurements collected on 9/11/99, 1/11/00. 12/27/01 and 6/9/02 based on Trigon
Engineering Consultants. Inc. Comprehensive Site Assessment Addendum Report dated July 19. 2002. Subsequent
groundwater elevations measurements collected by Harmon Environmental. PA personnel.
---= Groundwater measuring event predates the well installation date.
Dry = Monitor well was dry during the measuring event
I Constituent (1-Jg/L)
acetone
bromomethane
di-isopropyl ether
1.2-dibromoethane
1,2-dich loropropane
2-hexanone
4-isopropyl toluene
4-methyl-2-pentanone
1, 1.2-trichloroethane
1.2,4-trimethylbenzene
1,3.5-trimethylbenzene
1.2-dichloroethane
isopropylbenzene
toluene
naphthalene
n-butylbenzene
n-propylbenzene
sec-butyl benzene
ethylbenzene
benzene
methyl tert butyl ether
vinyl chloride
xylenes (total)
Table 3
Summary of June 14, 2023
Groundwater Analytical Results
Goldmine 66
5949 Sherrels Ford Road, Catawba, North Carolina
Incident No. 20107
Project No. 316-25
I NCAC 2L I
Standard . MW-1 I MW-2 I MW-3 I
6,000 2.06(J) 7.63(J) 2.54(J)
10 <0.280 0.521 (J) <0.280
NS 1.71 10.4 <0.500
NS <0.200 18.0 <0.200
0.6 <0.200 0.305(J) <0.200
NS <0.380 3.36 <0.380
25 <0.089 2.41 <0.089
NS <0.078 5.25 <0.078
0.6 <0.096 1.92 <0.096
400 <0.190 138(H) <0.190
400 <0.180 98.3(H) <0.180
0.4 1.19 79.6 <0.150
70 <0.180 7.31 <0.180
600 <0.220 12.3 <0.220
6 <0.470 95.4 <0.470
70 <0.180 1.46 <0.180
70 <0.190 7.54 <0.190
70 <0.200 1.38 <0.200
600 <0.170 24.6 <0.170
1 <0.180 6.67 <0.180
20 60.7 96.7 <0.140
0.03 <0.170 <0.170 <0.170
500 <0.21 702(H) <0.21
MW-6D I MW-7 I
<1.80 <1.80(H)
<0.280 <0.280(H)
4.57 <0.500(H)
<0.200 <0.200(H)
<0.200 <0.200(H)
<0.380 <0.380(H)
<0.089 <0.089(H)
<0.078 <0.078(H)
<0.096 <0.096(H)
<0.190 <0.190(H)
<0.180 <0.180(H)
3.41 <0.150(H)
<0.180 <0.180(H)
<0.220 <0.220(H)
<0.470 <0.470(H)
<0.180 <0.180(H)
<0.190 <0.190(H)
<0.200 <0.200(H)
<0.170 <0.170(H)
0.546 <0.180(H)
56.5 <0.140(H)
0.203(J) <0.170(H)
1.46(J) <0.21(H)
Notes: Samples collected by Harmon Environmental, PA personnel on June 14, 2023 and analyzed
by Waypoint Analytical of Charlotte, North Carolina.
Only the constituents detected in the groundwater samples are presented herein. For complete
analytical reports. please refer to Appendix C.
J..l/L = micrograms per liter
NCAC 2L Stand. = North Carolina Administrative Code, Title 15 A, Subchapter 2L, Groundwater
Quality Standards (Effective April 1, 2022)
NS = No Standard
J = Estimated concentration below the analytical method reporting limit
H = Analyte concentration exceeded calibration. Due to equipment failure,
dilution conducted after hold time exceeded.
NCAC 2LStandardbenzene 1 82 brl 25.5 --- brl 1.4 11 7.5 1.5 brl 4.8 25 24 13 brl 1.9 brl brl brl brl brl 3.730.0 7.63.0 brl brlacetone 6,000 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl --- --- --- --- --- 2.06(J)ethyl benzene 600 12.3 brl brl --- brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl 1.3brl brlbrl brl brlmethyl tert butyl ether 20 --- brl brl --- brl brl brl brl 10 24 18 35 24 45 80 110 240 210 300 310 360 210370 190190 19.9 60.7toluene 600 4.9 brl brl --- brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl 2.8brl brlbrl brl brlxylenes (total) 500 387.2 brl 23.6 --- brl 7.6 17 8.1 2.37(J) 1.3 13.9 40 5.4 19.3 brl 4.4 brl brl brl brl brl 9.146.2 11.56.0 brl brldi-isopropyl ether70 --- brl --- --- brl 2.5 brl 2.7(J) 8.3 15 12 15 15 19 15 24 47 23 41 25 33 16.133.8 12.112.0 0.50 1.71lead 15 --- brl 42 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ ------ brl brl1,1,1-trichloroethane 200 brl 7 3.2 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl brlbrl brlbrl brl brl1,1-dichloroethene 7 brl 4.4 2.5 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl brlbrl brlbrl brl brl1,1-dichloroethane 6 brl brl 20.3 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl 6.6brl brlbrl brl brl1,2-dichloroethane 0.4 brl 18.8 12.7 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 7.3 6.5 7.0 brl31.0 12.28.9 0.94 1.19chloroform 70 brl 3.1 5.6 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.67 brl 0.60 brlbrl brlbrl brl brl2-methyl-3-pentanolNo Standard23 120 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl ------ ------ --- brl1-ethyl-4-methylbenzeneNo Standard31 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ ------ --- brl1,3,5-trimethylbenzene 400 10 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl brlbrl brlbrl brl brl1,2,4-trimethylbenzene 400 25 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl 3.88.4 2.11.2 brl brlnaphthalene 6 brl --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl brl brlbrl brl5.1 brl brlC5-C12 aliphatics 400 590 440 212 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ ------ --- brlC9-C12 aliphatics 700 590 brl brl --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ ------ --- brlC9-C10 aromatics 200 270 brl brl --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ ------ --- brlNotes: The analytical data associated with the Auguat 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018 through April 26, 2022 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Hunterville, North Carolina. The June 15, 2023 samples were collected byHarmon Environmental, PA personnel and analyzed by Waypoint Analytical of Charlotte, North Carolina.Monitor well MW-1 was dry at the time of the November 1, 2002 and February 4, 2003 sampling events.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.4/20/20124/23/20214/28/20204/12/2017dry dry11/1/2002 2/4/20035/26/20094/28/2003 8/14/20034/12/20104/30/20194/15/20084/13/2015 4/14/201610/22/2008 4/19/2011Constituent (μg/L) 8/11/1999 1/11/2001 5/14/2001 12/21/20014/26/2022 6/14/2023Table 4Summary of Historic Groundwater Analytical DataMonitor Well MW-1Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-254/10/20184/26/2013 5/8/20141/20/2004 7/29/2004 2/14/2007 10/29/2007
NCAC 2LStandardbenzene 1 6.9 brl 33.2 2.6 1.9 5.0 69 36 21 39 46 34 47 41 67 48 17 11 8.6 6.4 7.1 3.5 4.9 8.8 2.8 3.2 2.7 6.67acetone 6,000------ --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 7.63(J)bromomethane 10------ ------ ------ --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl 0.521(J)di-isopropyl etherNS------ ------ ------ --- --- --- --- --- --- --- --- brl 1.2(J) --- --- --- --- --- --- --- --- --- --- 5.9 10.41,2-dibromoethaneNS------ ------ ------ --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl 18.01,2-dichloropropane0.06------ ------ ------ --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl 0.305(J)ethyl dibromide 0.02 brl brl brlbrl brl brl brl brl brl brl brl brl brl brl brl0.52(J)brl brlbrl brl brl brl brl brl brl --- brl---ethyl benzene 600 brl brl brlbrl brl brl brl brl brl brl0.95(J)brl1.4brl brl brl brl0.59 brl brl brl brl 0.73 brl 11.1 2.3 3.0 24.6ethylene dibromide 0.02------ ---brl brl brl brl brl --- ---brl0.85(J)brlbrl 1.2 0.52(J) brlbrl brl brl brl brl brl brl brl brl brl brl2-hexanone NS------ ------ --- --- --- --- --- --------------- --- --- ------ --- brl brl brl --- --- --- --- --- 3.36methyl tert butyl ether20 brl brl brlbrl brl brl brl brl3.7(J)brl brl brl brl brl brl brl brl brlbrl brl brl brl brl 11.7 5.4 22.8 43.5 96.74-methyl-2-pentanoneNS------ ------ --- --------- --- --- --- --- --- --- --- ------ --- --- --- --- --- --- --- --- 5.25toluene 600 brl brl brlbrl brl brl brl brl brl brl2.7 0.73(J) 1.3brl1.2brl brl brlbrl brl brl brl brl brl brl 1.8 3.7 12.31,1,2-trichloroethane0.06------ ------ --- --- --- --- --- ------ --- ------------ --- ------ brl brl brl brl brl brl brl brl 1.921,2,4-trimthylbenzene400--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---63 150(A) brl 152 48.3 29.8 31.2 48.0 138(H)1,2-dichloroethane0.4--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---9.6 5.3 5.7 4.0 59.7 31.6 54.8 69.6 79.61,3,5-trimethylbenzene400--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---17 35 8.1 27.3 5.4 6.1 22.7 36.7 98.3(H)4-isopropyltoluene NS--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---0.73 1.8 0.59 7.5 2.3 2.1 brl brl 2.41isopropylbenzene 70--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---5.4 9.3 2.7 9.9 1.1 1.2 brl 1.9 7.31naphthalene NS--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---6.1 10 4.1 12.0 25.0 13.2 28.7 39.6 95.4n-butylbenzene6--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---2.2 6.9 1.6 5.2 brl 1.0 brl brl 1.46n-propylbenzene70--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---brl 1.1 brl brl brl brl brl brl 7.54sec-butylbenzene 70--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---1.4 2.9 0.52 brl brl brl brl brl 1.38xylenes (total) 500 10.6 brl 55.66.1 5.3100 130 64 100 185 193 174 254 218 263 162 86 98 54 58 86 37 126 240 126 250.2 324.8 702(H)lead 15 33 --- ------ --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ --- --- --- --- --- ------Notes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020, April 23, 2021 and April 26, 2022 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina.The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.(A) = Dilution performed outside of hold time. Origin al run performed within hold time.(H) = Analyte concentration exceeded calibration. Due to equipment failure, dilution conducted after holding time exceeded.Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-255/14/20016/14/2023Not Sampled2/14/20075/8/20145/26/2009 4/12/2010 4/19/2011 4/20/201210/22/200810/29/20078/14/2003 4/15/20082/4/2003 1/20/2004 7/29/20044/28/200312/21/2001Table 5Summary of Historic Groundwater Analytical DataMonitor Well MW-24/26/2013 4/12/20174/14/2016 4/26/20224/23/20214/30/20194/13/2015 4/28/20204/20/201811/1/2002Consituent (μg/L) 8/11/1999 1/11/2001
NCAC 2LStandardbenzene 1 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlacetone 6 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- <10 6.0(J) 13 --- --- --- brl brl 2.54(J)ethyl benzene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlmethyl tert butyl ether 20 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brltoluene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl 0.75 brl 1.2 5.6 8.5 34.7 brlxylenes (total) 500 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl 4.1 brl brl brl brl brlisopropyl ether 70 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlethylene dibromide 0.02 --- brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl ---methyl isobutyl ketone NS --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl 3.7 --- --- --- --- --- ---lead 15 9.8--- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ------ --- --- --- --- --- --- ---Notes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020, April 21, 2021 and April 26, 2022 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina. The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.Consituent (μg/L) 12/21/2001 11/1/2002 2/4/200310/22/20087/29/2004 4/15/20081/20/20044/23/20214/28/20204/30/20194/12/20174/19/2011 4/20/2012 4/14/20164/13/20154/26/2013 5/8/20146/14/2023Table 6Summary of Historic Groundwater Analytical DataMonitor Well MW-3Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-255/26/20094/26/20222/14/2007 4/12/20104/10/20184/28/2003 8/14/2003 10/29/2007
NCAC 2LStandardbenzene 1 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlethyl benzene 600 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlmethyl tert butyl ether 20 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brltoluene 600 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlxylenes (total) 500 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlisopropyl ether 70 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlethylene dibromide 0.02 --- brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brllead 15 3.1--- --- --- --- --- --- --- --- --- --- --- --- --- --- ------Notes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020, April 23, 3021 and April 26, 2022 samples were collected by Harmon Environmental, PA personnel and analyzed byPace Analytical Services, LLC of Huntersville, North Carolina. The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.4/23/2021Not SampledNot Sampled4/28/2020Not Sampled4/26/2013 4/30/20195/8/2014Not SampledNot Sampled4/19/2011 4/10/2018Not SampledNot Sampled10/29/20074/14/20162/4/20034/12/2010 4/13/20157/29/20048/14/2003 1/20/2004 2/14/20074/20/201210/22/2008 5/26/20094/15/20085/14/2023Not SampledTable 7Summary of Historic Groundwater Analytical DataMonitor Well MW-4Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-254/26/2022Not Sampled4/28/20034/12/2017Consituent (μg/L) 12/21/2001 11/1/2002
NCAC 2LStandardbenzene 1 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlethyl benzene 600 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlmethyl tert butyl ether 20 1.4 brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brltoluene 600 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlxylenes (total) 500 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlisopropyl ether 70 brl brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brlethylene dibromide 0.02 --- brl brl brl brl brl --- brl brl brl brl brl brl brl brl brl brllead 15 3.1--- --- --- --- --- --- --- --- --- --- --- --- --- --- ------Notes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020 and April 23, 2021 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina. The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.Not Sampled4/28/2003 8/14/2003 1/20/20044/12/2010 4/14/2016Not SampledNot Sampled10/22/2008 5/26/200910/29/2007 4/15/2008 4/19/2011 5/8/2014 4/23/2021Not Sampled4/28/2020Not Sampled4/30/2019Not Sampled4/10/20187/29/2004Consituent (μg/L) 12/21/2001 11/1/2002 2/4/2003 2/14/20075/14/2023Not SampledTable 8Summary of Historic Groundwater Analytical DataMonitor Well MW-5Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-254/26/2022Not SampledNot Sampled4/12/20174/13/20154/20/2012 4/26/2013
NCAC 2LStandardbenzene 1 4.6 3.5 6.2 6.9 7.0 4.1 5.6 6.69.3 1214 11 19 16 4.4 10 9.3 5.4 46 22 31.4 18.3 5.3 1.8 0.5461,1-dichloroethane 6 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.64 2.2 1.7 1.0 brl brl brl 3.411,2,4-trimethylbenzene 400 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.89 3.8 3.9 5.1 3.6 1.5 0.90 brl(H)1,2-dichloroethane 0.4 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 3.9 24 19 20.9 21.8 13.7 7.0 brl(H)methyl isobutyl ketone NS --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 0.82(J) brl brl --- --- --- --- ---ethyl benzene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)methyl tert butyl ether 20 3.4 brl brl brl brl brl brl brl 3.4(J) 8.1 7.3 8.4 13 35 13 23 25 18 100(A) 130 196 227 191 79.1 56.5toluene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlxylenes (total) 500 8.7 5.3 7.7 8.7 7.6 5.5 7.7 10.2 13.7 17.9 19.2 16.1 27 20.4 7.6 11 8.2 5.2 40 33 38.1 27.4 10.6 5.9 1.46(J)isopropyl ether 70 brl brl brl brl brl brl brl brl brl brl 3.7(J) 4.5(J) 5.2 9.6 3.5(J) 6.1 5.9 4.2(J) 21 22 26.2 25.7 19.8 9.0 4.57ethylene dibromide 0.02 --- brl brl brl brl brl brl brlbrl brlbrl brl brl brl brl brl brl brl brl brl brl brl brl brl brlNotes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020 and April 23, 2021 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina. The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.(A) = Dilutions performed outside hold time. Original run performed within hold time.(H) = Analyte concentration exceeded calibration. Due to equipment failure, dilution conducted after holding time exceeded.10/22/20084/14/2016 4/23/20214/28/2020Consituent (μg/L) 12/27/2001 11/1/2002 2/4/2003 4/28/20034/20/20128/14/20034/13/20154/26/20131/20/2004 7/29/2004 2/14/2007 5/26/20095/14/2023Table 9Summary of Historic Groundwater Analytical DataMonitor Well MW-6DGoldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-254/26/20224/12/2010 4/19/201110/29/2007 4/15/20084/30/20194/12/20175/8/2014
NCAC 2LStandardbenzene 1 brl brl brl brl brl brl brlbrl brlbrl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)ethyl benzene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)methyl tert butyl ether 20 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)toluene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)xylenes (total) 500 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)isopropyl ether 70 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)ethylene dibromide 0.02 brl brl brl brl brl brl brlbrl brlbrl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl(H)Notes: The analytical data associated with the August 11, 1999, January 11, 2001, May 14, 2001 and December 21, 2001 sampling events based on data presented in the Trigon Engineering Consultant Comprehensive Site Assessment Addendum dated June 19, 2002. Subsequent analytical data until 2017 represent samples collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The April 10, 2018, April 30, 2019, April 28, 2020 and April 23, 2021 samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina. The June 14, 2023 samples were collected by Harmon Environmental, PA personnel and analyzed by Waypoint Analytical LLC of Charlotte, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.(H) = Analyte concentration exceeded calibration. Due to equipment failure, dilution conducted after holding time exceeded.5/24/2023Table 10Summary of Historic Groundwater Analytical DataMonitor Well MW-7Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-254/23/20214/28/20204/30/20194/13/20151/20/2004 7/29/2004 2/14/2007 4/15/2008 4/20/2012 5/8/201410/22/2008Consituent (μg/L) 11/1/2002 2/4/2003 4/28/2003 8/14/20034/26/20224/10/20185/26/20094/12/201710/29/20074/14/20164/12/2010 4/19/2011 4/26/2013
NCAC 2LStandardbenzene 1 brl brl brl brl brl brl brlbrl brlbrl brl brl brl brl brl brl brl brlbrlchloroform 70 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- brl brl1.6ethyl benzene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlbrlmethyl tert butyl ether 20 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlbrltoluene 600 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlbrlxylenes (total) 500 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlbrlisopropyl ether 70 brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brl brlbrlethylene dibromide 0.02 brl brl brl brl brl brl brlbrl brlbrl brl brl brl brl brl brl brl brlbrlNotes: Groundwater samples from 2002 through 2017 were collected by Harmon Environmental, PA personnel and analyzed by Prism Laboratories, Inc. of Charlotte, North Carolina. The 2018, 2019, 2020, 2021 and 2022 groundwater samples were collected by Harmon Environmental, PA personnel and analyzed by Pace Analytical Services, LLC of Huntersville, North Carolina.brl = below analytical method reporting limitμg/L = micrograms per liter--- = Sample not analyzed for targeted constituent(J) = estimated concentration below the analytical method reporting limit.5/14/2023Not SampledTable 11Summary of Historic Groundwater Analytical DataMonitor Well MW-8Goldmine 665949 Sherrills Ford Road, Catwaba, North CarolinaIncident No. 20107Project No. 316-258/14/20034/19/2011 4/20/2012 4/13/20157/29/2004 2/14/2007 10/29/20074/10/20184/12/2010 4/14/2016 4/23/2021Not SampledNot SampledNot Sampled4/30/2019 4/28/2020Not Sampled4/12/20174/15/2008 10/22/2008 4/26/2013 5/8/20145/26/2009Consituent (μg/L) 11/1/2002 2/4/20034/26/2022Not Sampled4/28/2003 1/20/2004
Appendix A
Analytical Report and Chain-of-Custody Record
June 14, 2023 Groundwater Sampling Event

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

6/30/2023
Harmon Environmental, PA Rick Harmon
615 Bruce Thomas Rd. Monroe, NC, 28112
Ref: Analytical Testing
Lab Report Number: 23-166-0032 Client Project Description: Goldmime 66
Dear Rick Harmon:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 6/15/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 44
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-166-0032
Page 2 of 44
Report Number:
Sample Summary Table
Client Project Description:
23-166-0032
Goldmine 66
Lab No Client Sample ID Matrix Date Collected Date Received
06/14/2023 10:15Aqueous 98489 MW-2 06/15/2023 15:36
06/14/2023 10:52Aqueous 98490 MW-1 06/15/2023 15:36
06/14/2023 11:05Aqueous 98491 MW-6D 06/15/2023 15:36
06/14/2023 11:15Aqueous 98492 MW-3 06/15/2023 15:36
06/14/2023 11:35Aqueous 98493 MW-7 06/15/2023 15:36
06/14/2023 11:50Aqueous 98494 5936 06/15/2023 15:36
Page 3 of 44
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-166-0032
Report Limit
Project:Goldmime 66
V 98489MW-2
J7.63 06/24/2023 09:336200BAcetoneµg/L 1.80
6.67 06/24/2023 09:336200BBenzeneµg/L 0.180
J0.521 06/24/2023 09:336200BBromomethaneµg/L 0.280
1.46 06/24/2023 09:336200Bn-Butylbenzene µg/L 0.180
1.38 06/24/2023 09:336200Bsec-Butyl benzene µg/L 0.200
10.4 06/24/2023 09:336200BDi-Isopropyl Ether (DIPE)µg/L 0.500
18.0 06/24/2023 09:336200B1,2-Dibromoethane µg/L 0.200
79.6 06/24/2023 09:336200B1,2-Dichloroethane µg/L 0.150
J0.305 06/24/2023 09:336200B1,2-Dichloropropane µg/L 0.190
24.6 06/24/2023 09:336200BEthylbenzeneµg/L 0.170
3.36 06/24/2023 09:336200B2-Hexanone µg/L 0.380
7.31 06/24/2023 09:336200BIsopropylbenzeneµg/L 0.180
2.41 06/24/2023 09:336200B4-Isopropyl toluene µg/L 0.089
96.7 06/24/2023 09:336200BMethyl tert-butyl ether (MTBE)µg/L 0.140
5.25 06/24/2023 09:336200B4-Methyl-2-Pentanone µg/L 0.078
95.4 06/24/2023 09:336200BNaphthaleneµg/L 0.470
7.54 06/24/2023 09:336200Bn-Propylbenzene µg/L 0.190
12.3 06/24/2023 09:336200BTolueneµg/L 0.220
1.92 06/24/2023 09:336200B1,1,2-Trichloroethane µg/L 0.096
H13806/29/2023 20:206200B1,2,4-Trimethylbenzene µg/L 1.90
H98.3 06/29/2023 20:206200B1,3,5-Trimethylbenzene µg/L 1.80
H46906/29/2023 20:206200Bo-Xylene µg/L 2.10
H23306/29/2023 20:206200Bm,p-Xylene µg/L 4.20
H70206/29/2023 20:206200BXylene (Total)µg/L 2.10
V 98490MW-1
J2.06 06/24/2023 08:106200BAcetoneµg/L 1.80
1.71 06/24/2023 08:106200BDi-Isopropyl Ether (DIPE)µg/L 0.500
1.19 06/24/2023 08:106200B1,2-Dichloroethane µg/L 0.150
60.7 06/24/2023 08:106200BMethyl tert-butyl ether (MTBE)µg/L 0.140
V 98491MW-6D
0.546 06/24/2023 08:386200BBenzeneµg/L 0.180
4.57 06/24/2023 08:386200BDi-Isopropyl Ether (DIPE)µg/L 0.500
3.41 06/24/2023 08:386200B1,2-Dichloroethane µg/L 0.150
56.5 06/24/2023 08:386200BMethyl tert-butyl ether (MTBE)µg/L 0.140
J0.203 06/24/2023 08:386200BVinyl Chloride µg/L 0.170
0.533 06/24/2023 08:386200Bo-Xylene µg/L 0.210
Page 4 of 44
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-166-0032
Report Limit
Project:Goldmime 66
V 98491MW-6D
J0.928 06/24/2023 08:386200Bm,p-Xylene µg/L 0.420
J1.46 06/24/2023 08:386200BXylene (Total)µg/L 0.210
V 98492MW-3
J2.54 06/24/2023 09:056200BAcetoneµg/L 1.80
V 984945936
H3.59 06/29/2023 17:356200BChloroformµg/L 0.220
Page 5 of 44

Client: Harmon Environmental, PA CASE NARRATIVE
Project: Goldmine 66 Lab Report Number: 23-166-0032
Date: 7/5/2023
Report Comments Revised Report: Revision 1 The case narrative has been updated.
Volatile Organic Compounds - GC/MS Method 6200B
Sample 98489 (MW-2) QC Batch No: V34841/V34684
The analysis for this sample was performed outside the EPA required holding time. 1x sample run was performed within holding. Dilution was analyzed outside of holding time.
Analyte: 2-Butanone
QC Batch No: V34685/V34684 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Sample 98493 (MW-7)
QC Batch No: V34841/V34839 The analysis for this sample was performed outside the EPA required holding time.
Sample 98494 (5936)
QC Batch No: V34841/V34839 The analysis for this sample was performed outside the EPA required holding time.
Page 6 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-2
98489 Matrix:
6/14/2023 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00 V34839 06/29/23 09:00
7.63 J µg/L 1.80 10.0Acetone 1 06/24/23 09:33 V34685MSA
6.67 µg/L 0.180 0.500Benzene 1 06/24/23 09:33 V34685MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 06/24/23 09:33 V34685MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 06/24/23 09:33 V34685MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 06/24/23 09:33 V34685MSA
<1.50 µg/L 1.50 5.00Bromoform 1 06/24/23 09:33 V34685MSA
0.521 J µg/L 0.280 1.00Bromomethane 1 06/24/23 09:33 V34685MSA
1.46 µg/L 0.180 0.500n-Butylbenzene 1 06/24/23 09:33 V34685MSA
1.38 µg/L 0.200 0.500
sec-Butyl benzene 1 06/24/23 09:33 V34685MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 06/24/23 09:33 V34685MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 06/24/23 09:33 V34685MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 06/24/23 09:33 V34685MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 06/24/23 09:33 V34685MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 06/24/23 09:33 V34685MSA
<0.220 µg/L 0.220 0.500Chloroform 1 06/24/23 09:33 V34685MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 06/24/23 09:33 V34685MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 06/24/23 09:33 V34685MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 06/24/23 09:33 V34685MSA
10.4 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/24/23 09:33 V34685MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/24/23 09:33 V34685MSA
18.0 µg/L 0.200 0.5001,2-Dibromoethane 1 06/24/23 09:33 V34685MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 06/24/23 09:33 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 7 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-2
98489 Matrix:
6/14/2023 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00 V34839 06/29/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/24/23 09:33 V34685MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/24/23 09:33 V34685MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/24/23 09:33 V34685MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 06/24/23 09:33 V34685MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 06/24/23 09:33 V34685MSA
79.6 µg/L 0.150 0.5001,2-Dichloroethane 1 06/24/23 09:33 V34685MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 06/24/23 09:33 V34685MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/24/23 09:33 V34685MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/24/23 09:33 V34685MSA
0.305 J µg/L 0.190 0.5001,2-Dichloropropane 1 06/24/23 09:33 V34685MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 06/24/23 09:33 V34685MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 06/24/23 09:33 V34685MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 06/24/23 09:33 V34685MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/24/23 09:33 V34685MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/24/23 09:33 V34685MSA
<42.0 µg/L 42.0 200
Ethanol 1 06/24/23 09:33 V34685MSA
24.6 µg/L 0.170 0.500Ethylbenzene 1 06/24/23 09:33 V34685MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 06/24/23 09:33 V34685MSA
3.36 µg/L 0.380 1.002-Hexanone 1 06/24/23 09:33 V34685MSA
7.31 µg/L 0.180 0.500Isopropylbenzene 1 06/24/23 09:33 V34685MSA
2.41 µg/L 0.089 0.5004-Isopropyl toluene 1 06/24/23 09:33 V34685MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/24/23 09:33 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-2
98489 Matrix:
6/14/2023 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00 V34839 06/29/23 09:00
96.7 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/24/23 09:33 V34685MSA
5.25 µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/24/23 09:33 V34685MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 06/24/23 09:33 V34685MSA
95.4 µg/L 0.470 1.00Naphthalene 1 06/24/23 09:33 V34685MSA
7.54 µg/L 0.190 0.500n-Propylbenzene 1 06/24/23 09:33 V34685MSA
<0.220 µg/L 0.220 0.500Styrene 1 06/24/23 09:33 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/24/23 09:33 V34685MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/24/23 09:33 V34685MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 06/24/23 09:33 V34685MSA
12.3 µg/L 0.220 0.500Toluene 1 06/24/23 09:33 V34685MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/24/23 09:33 V34685MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/24/23 09:33 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/24/23 09:33 V34685MSA
1.92 µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/24/23 09:33 V34685MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 06/24/23 09:33 V34685MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 06/24/23 09:33 V34685MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/24/23 09:33 V34685MSA
138 H µg/L 1.90 5.001,2,4-Trimethylbenzene 10 06/29/23 20:20 V34841MSA
98.3 H µg/L 1.80 5.001,3,5-Trimethylbenzene 10 06/29/23 20:20 V34841MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 06/24/23 09:33 V34685MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 06/24/23 09:33 V34685MSA
469 H µg/L 2.10 5.00o-Xylene 10 06/29/23 20:20 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-2
98489 Matrix:
6/14/2023 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00 V34839 06/29/23 09:00
233 H µg/L 4.20 10.0m,p-Xylene 10 06/29/23 20:20 V34841MSA
702 H µg/L 2.10 5.00Xylene (Total)10 06/29/23 20:20 V34841
Surrogate: 4-Bromofluorobenzene 94.2 Limits: 70-130%06/24/23 09:331 MSA V34685
Surrogate: Dibromofluoromethane 103 Limits: 70-130%06/24/23 09:331 MSA V34685
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%06/24/23 09:331 MSA V34685
Surrogate: Toluene-d8 97.4 Limits: 70-130%06/24/23 09:331 MSA V34685
Surrogate: 4-Bromofluorobenzene 93.4 Limits: 70-130%06/29/23 20:2010 MSA V34841
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%06/29/23 20:2010 MSA V34841
Surrogate: 1,2-Dichloroethane - d4 94.4 Limits: 70-130%06/29/23 20:2010 MSA V34841
Surrogate: Toluene-d8 95.4 Limits: 70-130%06/29/23 20:2010 MSA V34841
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-1
98490 Matrix:
6/14/2023 10:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
2.06 J µg/L 1.80 10.0Acetone 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500Benzene 1 06/24/23 08:10 V34685MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 06/24/23 08:10 V34685MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 06/24/23 08:10 V34685MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 06/24/23 08:10 V34685MSA
<1.50 µg/L 1.50 5.00Bromoform 1 06/24/23 08:10 V34685MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 06/24/23 08:10 V34685MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 06/24/23 08:10 V34685MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 06/24/23 08:10 V34685MSA
<0.220 µg/L 0.220 0.500Chloroform 1 06/24/23 08:10 V34685MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 06/24/23 08:10 V34685MSA
1.71 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/24/23 08:10 V34685MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 06/24/23 08:10 V34685MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 06/24/23 08:10 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-1
98490 Matrix:
6/14/2023 10:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/24/23 08:10 V34685MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/24/23 08:10 V34685MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 06/24/23 08:10 V34685MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 06/24/23 08:10 V34685MSA
1.19 µg/L 0.150 0.5001,2-Dichloroethane 1 06/24/23 08:10 V34685MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 06/24/23 08:10 V34685MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 06/24/23 08:10 V34685MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 06/24/23 08:10 V34685MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 06/24/23 08:10 V34685MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/24/23 08:10 V34685MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/24/23 08:10 V34685MSA
<42.0 µg/L 42.0 200
Ethanol 1 06/24/23 08:10 V34685MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 06/24/23 08:10 V34685MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 06/24/23 08:10 V34685MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 06/24/23 08:10 V34685MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 06/24/23 08:10 V34685MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/24/23 08:10 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-1
98490 Matrix:
6/14/2023 10:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
60.7 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/24/23 08:10 V34685MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/24/23 08:10 V34685MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 06/24/23 08:10 V34685MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 06/24/23 08:10 V34685MSA
<0.220 µg/L 0.220 0.500Styrene 1 06/24/23 08:10 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/24/23 08:10 V34685MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/24/23 08:10 V34685MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 06/24/23 08:10 V34685MSA
<0.220 µg/L 0.220 0.500Toluene 1 06/24/23 08:10 V34685MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/24/23 08:10 V34685MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/24/23 08:10 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/24/23 08:10 V34685MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 06/24/23 08:10 V34685MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/24/23 08:10 V34685MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 06/24/23 08:10 V34685MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 06/24/23 08:10 V34685MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 06/24/23 08:10 V34685MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 06/24/23 08:10 V34685MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 06/24/23 08:10 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-1
98490 Matrix:
6/14/2023 10:52
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 06/24/23 08:10 V34685MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 06/24/23 08:10 V34685
Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%06/24/23 08:101 MSA V34685
Surrogate: Dibromofluoromethane 104 Limits: 70-130%06/24/23 08:101 MSA V34685
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%06/24/23 08:101 MSA V34685
Surrogate: Toluene-d8 95.8 Limits: 70-130%06/24/23 08:101 MSA V34685
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-6D
98491 Matrix:
6/14/2023 11:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 06/24/23 08:38 V34685MSA
0.546 µg/L 0.180 0.500Benzene 1 06/24/23 08:38 V34685MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 06/24/23 08:38 V34685MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 06/24/23 08:38 V34685MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 06/24/23 08:38 V34685MSA
<1.50 µg/L 1.50 5.00Bromoform 1 06/24/23 08:38 V34685MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 06/24/23 08:38 V34685MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 06/24/23 08:38 V34685MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 06/24/23 08:38 V34685MSA
<0.220 µg/L 0.220 0.500Chloroform 1 06/24/23 08:38 V34685MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 06/24/23 08:38 V34685MSA
4.57 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/24/23 08:38 V34685MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 06/24/23 08:38 V34685MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 06/24/23 08:38 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-6D
98491 Matrix:
6/14/2023 11:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/24/23 08:38 V34685MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/24/23 08:38 V34685MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 06/24/23 08:38 V34685MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 06/24/23 08:38 V34685MSA
3.41 µg/L 0.150 0.5001,2-Dichloroethane 1 06/24/23 08:38 V34685MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 06/24/23 08:38 V34685MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 06/24/23 08:38 V34685MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 06/24/23 08:38 V34685MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 06/24/23 08:38 V34685MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/24/23 08:38 V34685MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/24/23 08:38 V34685MSA
<42.0 µg/L 42.0 200
Ethanol 1 06/24/23 08:38 V34685MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 06/24/23 08:38 V34685MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 06/24/23 08:38 V34685MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 06/24/23 08:38 V34685MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 06/24/23 08:38 V34685MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/24/23 08:38 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-6D
98491 Matrix:
6/14/2023 11:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
56.5 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/24/23 08:38 V34685MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/24/23 08:38 V34685MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 06/24/23 08:38 V34685MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 06/24/23 08:38 V34685MSA
<0.220 µg/L 0.220 0.500Styrene 1 06/24/23 08:38 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/24/23 08:38 V34685MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/24/23 08:38 V34685MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 06/24/23 08:38 V34685MSA
<0.220 µg/L 0.220 0.500Toluene 1 06/24/23 08:38 V34685MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/24/23 08:38 V34685MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/24/23 08:38 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/24/23 08:38 V34685MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 06/24/23 08:38 V34685MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/24/23 08:38 V34685MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 06/24/23 08:38 V34685MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 06/24/23 08:38 V34685MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 06/24/23 08:38 V34685MSA
0.203 J µg/L 0.170 0.500Vinyl Chloride 1 06/24/23 08:38 V34685MSA
0.533 µg/L 0.210 0.500o-Xylene 1 06/24/23 08:38 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-6D
98491 Matrix:
6/14/2023 11:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
0.928 J µg/L 0.420 1.00m,p-Xylene 1 06/24/23 08:38 V34685MSA
1.46 J µg/L 0.210 0.500Xylene (Total)1 06/24/23 08:38 V34685
Surrogate: 4-Bromofluorobenzene 93.6 Limits: 70-130%06/24/23 08:381 MSA V34685
Surrogate: Dibromofluoromethane 104 Limits: 70-130%06/24/23 08:381 MSA V34685
Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%06/24/23 08:381 MSA V34685
Surrogate: Toluene-d8 96.4 Limits: 70-130%06/24/23 08:381 MSA V34685
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 18 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-3
98492 Matrix:
6/14/2023 11:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
2.54 J µg/L 1.80 10.0Acetone 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500Benzene 1 06/24/23 09:05 V34685MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 06/24/23 09:05 V34685MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 06/24/23 09:05 V34685MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 06/24/23 09:05 V34685MSA
<1.50 µg/L 1.50 5.00Bromoform 1 06/24/23 09:05 V34685MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 06/24/23 09:05 V34685MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 06/24/23 09:05 V34685MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 06/24/23 09:05 V34685MSA
<0.220 µg/L 0.220 0.500Chloroform 1 06/24/23 09:05 V34685MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 06/24/23 09:05 V34685MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/24/23 09:05 V34685MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 06/24/23 09:05 V34685MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 06/24/23 09:05 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 19 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-3
98492 Matrix:
6/14/2023 11:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/24/23 09:05 V34685MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/24/23 09:05 V34685MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 06/24/23 09:05 V34685MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 06/24/23 09:05 V34685MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 06/24/23 09:05 V34685MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 06/24/23 09:05 V34685MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 06/24/23 09:05 V34685MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 06/24/23 09:05 V34685MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 06/24/23 09:05 V34685MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/24/23 09:05 V34685MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/24/23 09:05 V34685MSA
<42.0 µg/L 42.0 200
Ethanol 1 06/24/23 09:05 V34685MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 06/24/23 09:05 V34685MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 06/24/23 09:05 V34685MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 06/24/23 09:05 V34685MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 06/24/23 09:05 V34685MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/24/23 09:05 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 20 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-3
98492 Matrix:
6/14/2023 11:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/24/23 09:05 V34685MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/24/23 09:05 V34685MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 06/24/23 09:05 V34685MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 06/24/23 09:05 V34685MSA
<0.220 µg/L 0.220 0.500Styrene 1 06/24/23 09:05 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/24/23 09:05 V34685MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/24/23 09:05 V34685MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 06/24/23 09:05 V34685MSA
<0.220 µg/L 0.220 0.500Toluene 1 06/24/23 09:05 V34685MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/24/23 09:05 V34685MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/24/23 09:05 V34685MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/24/23 09:05 V34685MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 06/24/23 09:05 V34685MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/24/23 09:05 V34685MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 06/24/23 09:05 V34685MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 06/24/23 09:05 V34685MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 06/24/23 09:05 V34685MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 06/24/23 09:05 V34685MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 06/24/23 09:05 V34685MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 21 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-3
98492 Matrix:
6/14/2023 11:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34684 06/23/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 06/24/23 09:05 V34685MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 06/24/23 09:05 V34685
Surrogate: 4-Bromofluorobenzene 94.8 Limits: 70-130%06/24/23 09:051 MSA V34685
Surrogate: Dibromofluoromethane 104 Limits: 70-130%06/24/23 09:051 MSA V34685
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%06/24/23 09:051 MSA V34685
Surrogate: Toluene-d8 96.6 Limits: 70-130%06/24/23 09:051 MSA V34685
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 22 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-7
98493 Matrix:
6/14/2023 11:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<1.80 H µg/L 1.80 10.0Acetone 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.500Benzene 1 06/29/23 17:08 V34841MSA
<0.210 H µg/L 0.210 0.500Bromobenzene 1 06/29/23 17:08 V34841MSA
<0.420 H µg/L 0.420 1.00Bromochloromethane 1 06/29/23 17:08 V34841MSA
<0.160 H µg/L 0.160 0.500Bromodichloromethane 1 06/29/23 17:08 V34841MSA
<1.50 H µg/L 1.50 5.00Bromoform 1 06/29/23 17:08 V34841MSA
<0.280 H µg/L 0.280 1.00Bromomethane 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.500n-Butylbenzene 1 06/29/23 17:08 V34841MSA
<0.200 H
µg/L 0.200 0.500
sec-Butyl benzene 1 06/29/23 17:08 V34841MSA
<0.920 H µg/L 0.920 2.00tert-Butyl benzene 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.500Carbon Tetrachloride 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.500Chlorobenzene 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.500Chlorodibromomethane 1 06/29/23 17:08 V34841MSA
<0.430 H µg/L 0.430 1.00Chloroethane 1 06/29/23 17:08 V34841MSA
<0.220 H µg/L 0.220 0.500Chloroform 1 06/29/23 17:08 V34841MSA
<0.220 H
µg/L 0.220 0.500
Chloromethane 1 06/29/23 17:08 V34841MSA
<0.200 H µg/L 0.200 0.5002-Chlorotoluene 1 06/29/23 17:08 V34841MSA
<0.200 H µg/L 0.200 0.5004-Chlorotoluene 1 06/29/23 17:08 V34841MSA
<0.500 H µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/29/23 17:08 V34841MSA
<1.10 H µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/29/23 17:08 V34841MSA
<0.200 H µg/L 0.200 0.5001,2-Dibromoethane 1 06/29/23 17:08 V34841MSA
<0.230 H µg/L 0.230 0.500Dibromomethane 1 06/29/23 17:08 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 23 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-7
98493 Matrix:
6/14/2023 11:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.220 H µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/29/23 17:08 V34841MSA
<0.210 H µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/29/23 17:08 V34841MSA
<1.20 H µg/L 1.20 5.00Dichlorodifluoromethane 1 06/29/23 17:08 V34841MSA
<0.240 H µg/L 0.240 0.5001,1-Dichloroethane 1 06/29/23 17:08 V34841MSA
<0.150 H µg/L 0.150 0.5001,2-Dichloroethane 1 06/29/23 17:08 V34841MSA
<0.150 H µg/L 0.150 0.5001,1-Dichloroethene 1 06/29/23 17:08 V34841MSA
<0.200 H µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/29/23 17:08 V34841MSA
<0.180 H
µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.5001,2-Dichloropropane 1 06/29/23 17:08 V34841MSA
<0.130 H µg/L 0.130 0.5001,3-Dichloropropane 1 06/29/23 17:08 V34841MSA
<0.210 H µg/L 0.210 2.002,2-Dichloropropane 1 06/29/23 17:08 V34841MSA
<0.200 H µg/L 0.200 0.5001,1-Dichloropropene 1 06/29/23 17:08 V34841MSA
<0.210 H µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/29/23 17:08 V34841MSA
<0.150 H µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/29/23 17:08 V34841MSA
<42.0 H
µg/L 42.0 200
Ethanol 1 06/29/23 17:08 V34841MSA
<0.170 H µg/L 0.170 0.500Ethylbenzene 1 06/29/23 17:08 V34841MSA
<0.350 H µg/L 0.350 3.00Hexachlorobutadiene 1 06/29/23 17:08 V34841MSA
<0.380 H µg/L 0.380 1.002-Hexanone 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.500Isopropylbenzene 1 06/29/23 17:08 V34841MSA
<0.089 H µg/L 0.089 0.5004-Isopropyl toluene 1 06/29/23 17:08 V34841MSA
<0.710 H µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/29/23 17:08 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 24 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-7
98493 Matrix:
6/14/2023 11:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.140 H µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/29/23 17:08 V34841MSA
<0.078 H µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/29/23 17:08 V34841MSA
<0.330 H µg/L 0.330 2.00Methylene Chloride 1 06/29/23 17:08 V34841MSA
<0.470 H µg/L 0.470 1.00Naphthalene 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.500n-Propylbenzene 1 06/29/23 17:08 V34841MSA
<0.220 H µg/L 0.220 0.500Styrene 1 06/29/23 17:08 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/29/23 17:08 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/29/23 17:08 V34841MSA
<0.220 H
µg/L 0.220 0.500
Tetrachloroethene 1 06/29/23 17:08 V34841MSA
<0.220 H µg/L 0.220 0.500Toluene 1 06/29/23 17:08 V34841MSA
<0.380 H µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/29/23 17:08 V34841MSA
<0.310 H µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/29/23 17:08 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/29/23 17:08 V34841MSA
<0.096 H µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.500Trichloroethene 1 06/29/23 17:08 V34841MSA
<0.180 H
µg/L 0.180 0.500
Trichlorofluoromethane 1 06/29/23 17:08 V34841MSA
<0.270 H µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/29/23 17:08 V34841MSA
<0.190 H µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 06/29/23 17:08 V34841MSA
<0.180 H µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 06/29/23 17:08 V34841MSA
<1.00 H µg/L 1.00 5.00Vinyl Acetate 1 06/29/23 17:08 V34841MSA
<0.170 H µg/L 0.170 0.500Vinyl Chloride 1 06/29/23 17:08 V34841MSA
<0.210 H µg/L 0.210 0.500o-Xylene 1 06/29/23 17:08 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 25 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:MW-7
98493 Matrix:
6/14/2023 11:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.420 H µg/L 0.420 1.00m,p-Xylene 1 06/29/23 17:08 V34841MSA
<0.21 H µg/L 0.210 0.500Xylene (Total)1 06/29/23 17:08 V34841
Surrogate: 4-Bromofluorobenzene 94.8 Limits: 70-130%06/29/23 17:081 MSA V34841
Surrogate: Dibromofluoromethane 96.0 Limits: 70-130%06/29/23 17:081 MSA V34841
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%06/29/23 17:081 MSA V34841
Surrogate: Toluene-d8 96.2 Limits: 70-130%06/29/23 17:081 MSA V34841
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 26 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:5936
98494 Matrix:
6/14/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<1.80 H µg/L 1.80 10.0Acetone 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.500Benzene 1 06/29/23 17:35 V34841MSA
<0.210 H µg/L 0.210 0.500Bromobenzene 1 06/29/23 17:35 V34841MSA
<0.420 H µg/L 0.420 1.00Bromochloromethane 1 06/29/23 17:35 V34841MSA
<0.160 H µg/L 0.160 0.500Bromodichloromethane 1 06/29/23 17:35 V34841MSA
<1.50 H µg/L 1.50 5.00Bromoform 1 06/29/23 17:35 V34841MSA
<0.280 H µg/L 0.280 1.00Bromomethane 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.500n-Butylbenzene 1 06/29/23 17:35 V34841MSA
<0.200 H
µg/L 0.200 0.500
sec-Butyl benzene 1 06/29/23 17:35 V34841MSA
<0.920 H µg/L 0.920 2.00tert-Butyl benzene 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.500Carbon Tetrachloride 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.500Chlorobenzene 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.500Chlorodibromomethane 1 06/29/23 17:35 V34841MSA
<0.430 H µg/L 0.430 1.00Chloroethane 1 06/29/23 17:35 V34841MSA
3.59 H µg/L 0.220 0.500Chloroform 1 06/29/23 17:35 V34841MSA
<0.220 H
µg/L 0.220 0.500
Chloromethane 1 06/29/23 17:35 V34841MSA
<0.200 H µg/L 0.200 0.5002-Chlorotoluene 1 06/29/23 17:35 V34841MSA
<0.200 H µg/L 0.200 0.5004-Chlorotoluene 1 06/29/23 17:35 V34841MSA
<0.500 H µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 06/29/23 17:35 V34841MSA
<1.10 H µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 06/29/23 17:35 V34841MSA
<0.200 H µg/L 0.200 0.5001,2-Dibromoethane 1 06/29/23 17:35 V34841MSA
<0.230 H µg/L 0.230 0.500Dibromomethane 1 06/29/23 17:35 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 27 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:5936
98494 Matrix:
6/14/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.220 H µg/L 0.220 0.5001,2-Dichlorobenzene 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.5001,3-Dichlorobenzene 1 06/29/23 17:35 V34841MSA
<0.210 H µg/L 0.210 0.5001,4-Dichlorobenzene 1 06/29/23 17:35 V34841MSA
<1.20 H µg/L 1.20 5.00Dichlorodifluoromethane 1 06/29/23 17:35 V34841MSA
<0.240 H µg/L 0.240 0.5001,1-Dichloroethane 1 06/29/23 17:35 V34841MSA
<0.150 H µg/L 0.150 0.5001,2-Dichloroethane 1 06/29/23 17:35 V34841MSA
<0.150 H µg/L 0.150 0.5001,1-Dichloroethene 1 06/29/23 17:35 V34841MSA
<0.200 H µg/L 0.200 0.500cis-1,2-Dichloroethene 1 06/29/23 17:35 V34841MSA
<0.180 H
µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.5001,2-Dichloropropane 1 06/29/23 17:35 V34841MSA
<0.130 H µg/L 0.130 0.5001,3-Dichloropropane 1 06/29/23 17:35 V34841MSA
<0.210 H µg/L 0.210 2.002,2-Dichloropropane 1 06/29/23 17:35 V34841MSA
<0.200 H µg/L 0.200 0.5001,1-Dichloropropene 1 06/29/23 17:35 V34841MSA
<0.210 H µg/L 0.210 0.500cis-1,3-Dichloropropene 1 06/29/23 17:35 V34841MSA
<0.150 H µg/L 0.150 0.500trans-1,3-Dichloropropene 1 06/29/23 17:35 V34841MSA
<42.0 H
µg/L 42.0 200
Ethanol 1 06/29/23 17:35 V34841MSA
<0.170 H µg/L 0.170 0.500Ethylbenzene 1 06/29/23 17:35 V34841MSA
<0.350 H µg/L 0.350 3.00Hexachlorobutadiene 1 06/29/23 17:35 V34841MSA
<0.380 H µg/L 0.380 1.002-Hexanone 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.500Isopropylbenzene 1 06/29/23 17:35 V34841MSA
<0.089 H µg/L 0.089 0.5004-Isopropyl toluene 1 06/29/23 17:35 V34841MSA
<0.710 H µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 06/29/23 17:35 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 28 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:5936
98494 Matrix:
6/14/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.140 H µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 06/29/23 17:35 V34841MSA
<0.078 H µg/L 0.078 1.004-Methyl-2-Pentanone 1 06/29/23 17:35 V34841MSA
<0.330 H µg/L 0.330 2.00Methylene Chloride 1 06/29/23 17:35 V34841MSA
<0.470 H µg/L 0.470 1.00Naphthalene 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.500n-Propylbenzene 1 06/29/23 17:35 V34841MSA
<0.220 H µg/L 0.220 0.500Styrene 1 06/29/23 17:35 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 06/29/23 17:35 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 06/29/23 17:35 V34841MSA
<0.220 H
µg/L 0.220 0.500
Tetrachloroethene 1 06/29/23 17:35 V34841MSA
<0.220 H µg/L 0.220 0.500Toluene 1 06/29/23 17:35 V34841MSA
<0.380 H µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 06/29/23 17:35 V34841MSA
<0.310 H µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 06/29/23 17:35 V34841MSA
<0.160 H µg/L 0.160 0.5001,1,1-Trichloroethane 1 06/29/23 17:35 V34841MSA
<0.096 H µg/L 0.096 0.5001,1,2-Trichloroethane 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.500Trichloroethene 1 06/29/23 17:35 V34841MSA
<0.180 H
µg/L 0.180 0.500
Trichlorofluoromethane 1 06/29/23 17:35 V34841MSA
<0.270 H µg/L 0.270 0.5001,2,3-Trichloropropane 1 06/29/23 17:35 V34841MSA
<0.190 H µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 06/29/23 17:35 V34841MSA
<0.180 H µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 06/29/23 17:35 V34841MSA
<1.00 H µg/L 1.00 5.00Vinyl Acetate 1 06/29/23 17:35 V34841MSA
<0.170 H µg/L 0.170 0.500Vinyl Chloride 1 06/29/23 17:35 V34841MSA
<0.210 H µg/L 0.210 0.500o-Xylene 1 06/29/23 17:35 V34841MSA
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 29 of 44
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28112
23-166-0032
00358
Harmon Environmental, PA
615 Bruce Thomas Rd.
Rick Harmon
Monroe
Received : 06/15/2023
Goldmine 66
Revised Report Date: 07/05/2023
Original Report Date : 06/30/2023
Sample ID :
Lab No :
Sampled:5936
98494 Matrix:
6/14/2023 11:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V34839 06/29/23 09:00
<0.420 H µg/L 0.420 1.00m,p-Xylene 1 06/29/23 17:35 V34841MSA
<0.21 H µg/L 0.210 0.500Xylene (Total)1 06/29/23 17:35 V34841
Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%06/29/23 17:351 MSA V34841
Surrogate: Dibromofluoromethane 96.0 Limits: 70-130%06/29/23 17:351 MSA V34841
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%06/29/23 17:351 MSA V34841
Surrogate: Toluene-d8 96.4 Limits: 70-130%06/29/23 17:351 MSA V34841
Qualifiers/
Definitions
Beyond holding timeHDilution FactorDF
Method Quantitation LimitMQLEstimated valueJ
Page 30 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
Associated Lab Samples: 98489, 98490, 98491, 98492
LRB-V34684 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/24/23 04:0210.01.80<1.80µg/LAcetone
06/24/23 04:020.5000.180<0.180µg/LBenzene
06/24/23 04:020.5000.210<0.210µg/LBromobenzene
06/24/23 04:021.000.420<0.420µg/LBromochloromethane
06/24/23 04:020.5000.160<0.160µg/LBromodichloromethane
06/24/23 04:025.001.50<1.50µg/LBromoform
06/24/23 04:021.000.280<0.280µg/LBromomethane
06/24/23 04:020.5000.180<0.180µg/Ln-Butylbenzene
06/24/23 04:020.5000.200<0.200µg/Lsec-Butyl benzene
06/24/23 04:022.000.920<0.920µg/Ltert-Butyl benzene
06/24/23 04:020.5000.180<0.180µg/LCarbon Tetrachloride
06/24/23 04:020.5000.190<0.190µg/LChlorobenzene
06/24/23 04:020.5000.190<0.190µg/LChlorodibromomethane
06/24/23 04:021.000.430<0.430µg/LChloroethane
06/24/23 04:020.5000.220<0.220µg/LChloroform
06/24/23 04:020.5000.220<0.220µg/LChloromethane
06/24/23 04:020.5000.200<0.200µg/L2-Chlorotoluene
06/24/23 04:020.5000.200<0.200µg/L4-Chlorotoluene
06/24/23 04:020.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
06/24/23 04:022.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
06/24/23 04:020.5000.200<0.200µg/L1,2-Dibromoethane
06/24/23 04:020.5000.230<0.230µg/LDibromomethane
06/24/23 04:020.5000.220<0.220µg/L1,2-Dichlorobenzene
06/24/23 04:020.5000.190<0.190µg/L1,3-Dichlorobenzene
06/24/23 04:020.5000.210<0.210µg/L1,4-Dichlorobenzene
06/24/23 04:025.001.20<1.20µg/LDichlorodifluoromethane
06/24/23 04:020.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 12Date:06/30/2023 03:00 PM
Page 31 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
Associated Lab Samples: 98489, 98490, 98491, 98492
LRB-V34684 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/24/23 04:020.5000.150<0.150µg/L1,2-Dichloroethane
06/24/23 04:020.5000.150<0.150µg/L1,1-Dichloroethene
06/24/23 04:020.5000.200<0.200µg/Lcis-1,2-Dichloroethene
06/24/23 04:020.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
06/24/23 04:020.5000.190<0.190µg/L1,2-Dichloropropane
06/24/23 04:020.5000.130<0.130µg/L1,3-Dichloropropane
06/24/23 04:022.000.210<0.210µg/L2,2-Dichloropropane
06/24/23 04:020.5000.200<0.200µg/L1,1-Dichloropropene
06/24/23 04:020.5000.210<0.210µg/Lcis-1,3-Dichloropropene
06/24/23 04:020.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
06/24/23 04:0220042.0<42.0µg/LEthanol
06/24/23 04:020.5000.170<0.170µg/LEthylbenzene
06/24/23 04:023.000.350<0.350µg/LHexachlorobutadiene
06/24/23 04:021.000.380<0.380µg/L2-Hexanone
06/24/23 04:020.5000.180<0.180µg/LIsopropylbenzene
06/24/23 04:020.5000.089<0.089µg/L4-Isopropyl toluene
06/24/23 04:025.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
06/24/23 04:021.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
06/24/23 04:021.000.078<0.078µg/L4-Methyl-2-Pentanone
06/24/23 04:022.000.330<0.330µg/LMethylene Chloride
06/24/23 04:021.000.470<0.470µg/LNaphthalene
06/24/23 04:020.5000.190<0.190µg/Ln-Propylbenzene
06/24/23 04:020.5000.220<0.220µg/LStyrene
06/24/23 04:020.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
06/24/23 04:020.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
06/24/23 04:020.5000.220<0.220µg/LTetrachloroethene
06/24/23 04:020.5000.220<0.220µg/LToluene
Page 2 of 12Date:06/30/2023 03:00 PM
Page 32 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
Associated Lab Samples: 98489, 98490, 98491, 98492
LRB-V34684 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/24/23 04:020.5000.380<0.380µg/L1,2,3-Trichlorobenzene
06/24/23 04:020.5000.310<0.310µg/L1,2,4-Trichlorobenzene
06/24/23 04:020.5000.160<0.160µg/L1,1,1-Trichloroethane
06/24/23 04:020.5000.096<0.096µg/L1,1,2-Trichloroethane
06/24/23 04:020.5000.180<0.180µg/LTrichloroethene
06/24/23 04:020.5000.180<0.180µg/LTrichlorofluoromethane
06/24/23 04:020.5000.270<0.270µg/L1,2,3-Trichloropropane
06/24/23 04:020.5000.190<0.190µg/L1,2,4-Trimethylbenzene
06/24/23 04:020.5000.180<0.180µg/L1,3,5-Trimethylbenzene
06/24/23 04:025.001.00<1.00µg/LVinyl Acetate
06/24/23 04:020.5000.170<0.170µg/LVinyl Chloride
06/24/23 04:020.5000.210<0.210µg/Lo-Xylene
06/24/23 04:021.000.420<0.420µg/Lm,p-Xylene
06/24/23 04:024-Bromofluorobenzene (S)95.8 70-130
06/24/23 04:02Dibromofluoromethane (S)104 70-130
06/24/23 04:021,2-Dichloroethane - d4 (S)102 70-130
06/24/23 04:02Toluene-d8 (S)97.4 70-130
LCS-V34684 LCSD-V34684Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
35.6 89.095.038.040.0µg/LAcetone 40-160 6.5 20.0
19.1 95.510120.120.0µg/LBenzene 70-130 5.1 20.0
17.6 88.089.517.920.0µg/LBromobenzene 70-130 1.6 20.0
19.7 98.510120.120.0µg/LBromochloromethane 70-130 2.0 20.0
17.5 87.589.017.820.0µg/LBromodichloromethane 70-130 1.6 20.0
Page 3 of 12Date:06/30/2023 03:00 PM
Page 33 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
LCS-V34684 LCSD-V34684Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.3 91.594.018.820.0µg/LBromoform 70-130 2.6 20.0
21.2 10610621.220.0µg/LBromomethane 60-140 0.0 20.0
17.7 88.591.518.320.0µg/Ln-Butylbenzene 70-130 3.3 20.0
17.1 85.588.517.720.0µg/Lsec-Butyl benzene 70-130 3.4 20.0
17.0 85.089.017.820.0µg/Ltert-Butyl benzene 70-130 4.5 20.0
17.8 89.096.519.320.0µg/LCarbon Tetrachloride 70-130 8.0 20.0
18.7 93.596.019.220.0µg/LChlorobenzene 70-130 2.6 20.0
18.0 90.091.018.220.0µg/LChlorodibromomethane 70-130 1.1 20.0
19.2 96.010120.120.0µg/LChloroethane 60-140 4.5 20.0
18.7 93.597.519.520.0µg/LChloroform 70-130 4.1 20.0
17.7 88.592.018.420.0µg/LChloromethane 60-140 3.8 20.0
16.9 84.587.517.520.0µg/L2-Chlorotoluene 70-130 3.4 20.0
16.7 83.585.517.120.0µg/L4-Chlorotoluene 70-130 2.3 20.0
17.9 89.594.518.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 5.4 20.0
18.6 93.097.519.520.0µg/L1,2-Dibromo-3-Chloropropane 70-130 4.7 20.0
19.0 95.092.518.520.0µg/L1,2-Dibromoethane 70-130 2.6 20.0
18.2 91.094.518.920.0µg/LDibromomethane 70-130 3.7 20.0
18.5 92.595.019.020.0µg/L1,2-Dichlorobenzene 70-130 2.6 20.0
18.3 91.592.018.420.0µg/L1,3-Dichlorobenzene 70-130 0.5 20.0
18.0 90.091.518.320.0µg/L1,4-Dichlorobenzene 70-130 1.6 20.0
18.7 93.510320.620.0µg/LDichlorodifluoromethane 60-140 9.6 20.0
18.4 92.095.519.120.0µg/L1,1-Dichloroethane 70-130 3.7 20.0
18.1 90.589.517.920.0µg/L1,2-Dichloroethane 70-130 1.1 20.0
18.2 91.010020.020.0µg/L1,1-Dichloroethene 70-130 9.4 20.0
18.3 91.594.018.820.0µg/Lcis-1,2-Dichloroethene 70-130 2.6 20.0
18.3 91.596.519.320.0µg/Ltrans-1,2-Dichloroethene 70-130 5.3 20.0
Page 4 of 12Date:06/30/2023 03:00 PM
Page 34 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
LCS-V34684 LCSD-V34684Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.4 87.091.018.220.0µg/L1,2-Dichloropropane 70-130 4.4 20.0
17.9 89.589.517.920.0µg/L1,3-Dichloropropane 70-130 0.0 20.0
16.2 81.089.517.920.0µg/L2,2-Dichloropropane 70-130 9.9 20.0
19.9 99.510521.020.0µg/L1,1-Dichloropropene 70-130 5.3 20.0
17.3 86.590.018.020.0µg/Lcis-1,3-Dichloropropene 70-130 3.9 20.0
17.0 85.085.517.120.0µg/Ltrans-1,3-Dichloropropene 70-130 0.5 20.0
579 116117583500µg/LEthanol 60-140 0.6 20.0
16.9 84.589.017.820.0µg/LEthylbenzene 70-130 5.1 20.0
17.7 88.592.018.420.0µg/LHexachlorobutadiene 70-130 3.8 20.0
15.8 79.079.015.820.0µg/L2-Hexanone 60-140 0.0 20.0
17.2 86.089.517.920.0µg/LIsopropylbenzene 70-130 3.9 20.0
18.1 90.593.018.620.0µg/L4-Isopropyl toluene 70-130 2.7 20.0
15.6 78.062.012.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 22.8*20.0
19.4 97.010020.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.0 20.0
16.1 80.582.516.520.0µg/L4-Methyl-2-Pentanone 60-140 2.4 20.0
18.8 94.097.019.420.0µg/LMethylene Chloride 70-130 3.1 20.0
16.5 82.586.517.320.0µg/LNaphthalene 70-130 4.7 20.0
16.9 84.588.017.620.0µg/Ln-Propylbenzene 70-130 4.0 20.0
18.1 90.593.018.620.0µg/LStyrene 70-130 2.7 20.0
18.5 92.593.518.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.0 20.0
17.9 89.589.517.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.0 20.0
17.3 86.592.518.520.0µg/LTetrachloroethene 70-130 6.7 20.0
17.5 87.593.518.720.0µg/LToluene 70-130 6.6 20.0
19.5 97.510621.120.0µg/L1,2,3-Trichlorobenzene 70-130 7.8 20.0
19.8 99.010320.620.0µg/L1,2,4-Trichlorobenzene 70-130 3.9 20.0
18.5 92.510020.020.0µg/L1,1,1-Trichloroethane 70-130 7.7 20.0
Page 5 of 12* QC Fail Date:06/30/2023 03:00 PM
Page 35 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34685QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34684
LCS-V34684 LCSD-V34684Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.4 92.091.518.320.0µg/L1,1,2-Trichloroethane 70-130 0.5 20.0
18.1 90.598.019.620.0µg/LTrichloroethene 70-130 7.9 20.0
19.2 96.010420.720.0µg/LTrichlorofluoromethane 60-140 7.5 20.0
18.0 90.087.517.520.0µg/L1,2,3-Trichloropropane 70-130 2.8 20.0
17.2 86.089.017.820.0µg/L1,2,4-Trimethylbenzene 70-130 3.4 20.0
17.5 87.589.517.920.0µg/L1,3,5-Trimethylbenzene 70-130 2.2 20.0
21.0 10588.517.720.0µg/LVinyl Acetate 60-140 17.0 20.0
20.0 10010621.120.0µg/LVinyl Chloride 60-140 5.3 20.0
17.3 86.590.018.020.0µg/Lo-Xylene 70-130 3.9 20.0
36.9 92.296.238.540.0µg/Lm,p-Xylene 70-130 4.2 20.0
93.893.64-Bromofluorobenzene (S)70-130
104103Dibromofluoromethane (S)70-130
1041041,2-Dichloroethane - d4 (S)70-130
98.298.6Toluene-d8 (S)70-130
Page 6 of 12Date:06/30/2023 03:00 PM
Page 36 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
Associated Lab Samples: 98489, 98493, 98494
LRB-V34839 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/29/23 14:5110.01.80<1.80µg/LAcetone
06/29/23 14:510.5000.180<0.180µg/LBenzene
06/29/23 14:510.5000.210<0.210µg/LBromobenzene
06/29/23 14:511.000.420<0.420µg/LBromochloromethane
06/29/23 14:510.5000.160<0.160µg/LBromodichloromethane
06/29/23 14:515.001.50<1.50µg/LBromoform
06/29/23 14:511.000.280<0.280µg/LBromomethane
06/29/23 14:510.5000.180<0.180µg/Ln-Butylbenzene
06/29/23 14:510.5000.200<0.200µg/Lsec-Butyl benzene
06/29/23 14:512.000.920<0.920µg/Ltert-Butyl benzene
06/29/23 14:510.5000.180<0.180µg/LCarbon Tetrachloride
06/29/23 14:510.5000.190<0.190µg/LChlorobenzene
06/29/23 14:510.5000.190<0.190µg/LChlorodibromomethane
06/29/23 14:511.000.430<0.430µg/LChloroethane
06/29/23 14:510.5000.220<0.220µg/LChloroform
06/29/23 14:510.5000.220<0.220µg/LChloromethane
06/29/23 14:510.5000.200<0.200µg/L2-Chlorotoluene
06/29/23 14:510.5000.200<0.200µg/L4-Chlorotoluene
06/29/23 14:510.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
06/29/23 14:512.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
06/29/23 14:510.5000.200<0.200µg/L1,2-Dibromoethane
06/29/23 14:510.5000.230<0.230µg/LDibromomethane
06/29/23 14:510.5000.220<0.220µg/L1,2-Dichlorobenzene
06/29/23 14:510.5000.190<0.190µg/L1,3-Dichlorobenzene
06/29/23 14:510.5000.210<0.210µg/L1,4-Dichlorobenzene
06/29/23 14:515.001.20<1.20µg/LDichlorodifluoromethane
06/29/23 14:510.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 12Date:06/30/2023 03:00 PM
Page 37 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
Associated Lab Samples: 98489, 98493, 98494
LRB-V34839 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/29/23 14:510.5000.150<0.150µg/L1,2-Dichloroethane
06/29/23 14:510.5000.150<0.150µg/L1,1-Dichloroethene
06/29/23 14:510.5000.200<0.200µg/Lcis-1,2-Dichloroethene
06/29/23 14:510.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
06/29/23 14:510.5000.190<0.190µg/L1,2-Dichloropropane
06/29/23 14:510.5000.130<0.130µg/L1,3-Dichloropropane
06/29/23 14:512.000.210<0.210µg/L2,2-Dichloropropane
06/29/23 14:510.5000.200<0.200µg/L1,1-Dichloropropene
06/29/23 14:510.5000.210<0.210µg/Lcis-1,3-Dichloropropene
06/29/23 14:510.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
06/29/23 14:5120042.0<42.0µg/LEthanol
06/29/23 14:510.5000.170<0.170µg/LEthylbenzene
06/29/23 14:513.000.350<0.350µg/LHexachlorobutadiene
06/29/23 14:511.000.380<0.380µg/L2-Hexanone
06/29/23 14:510.5000.180<0.180µg/LIsopropylbenzene
06/29/23 14:510.5000.089<0.089µg/L4-Isopropyl toluene
06/29/23 14:515.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
06/29/23 14:511.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
06/29/23 14:511.000.078<0.078µg/L4-Methyl-2-Pentanone
06/29/23 14:512.000.330<0.330µg/LMethylene Chloride
06/29/23 14:511.000.470<0.470µg/LNaphthalene
06/29/23 14:510.5000.190<0.190µg/Ln-Propylbenzene
06/29/23 14:510.5000.220<0.220µg/LStyrene
06/29/23 14:510.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
06/29/23 14:510.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
06/29/23 14:510.5000.220<0.220µg/LTetrachloroethene
06/29/23 14:510.5000.220<0.220µg/LToluene
Page 8 of 12Date:06/30/2023 03:00 PM
Page 38 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
Associated Lab Samples: 98489, 98493, 98494
LRB-V34839 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
06/29/23 14:510.5000.380<0.380µg/L1,2,3-Trichlorobenzene
06/29/23 14:510.5000.310<0.310µg/L1,2,4-Trichlorobenzene
06/29/23 14:510.5000.160<0.160µg/L1,1,1-Trichloroethane
06/29/23 14:510.5000.096<0.096µg/L1,1,2-Trichloroethane
06/29/23 14:510.5000.180<0.180µg/LTrichloroethene
06/29/23 14:510.5000.180<0.180µg/LTrichlorofluoromethane
06/29/23 14:510.5000.270<0.270µg/L1,2,3-Trichloropropane
06/29/23 14:510.5000.190<0.190µg/L1,2,4-Trimethylbenzene
06/29/23 14:510.5000.180<0.180µg/L1,3,5-Trimethylbenzene
06/29/23 14:515.001.00<1.00µg/LVinyl Acetate
06/29/23 14:510.5000.170<0.170µg/LVinyl Chloride
06/29/23 14:510.5000.210<0.210µg/Lo-Xylene
06/29/23 14:511.000.420<0.420µg/Lm,p-Xylene
06/29/23 14:514-Bromofluorobenzene (S)95.2 70-130
06/29/23 14:51Dibromofluoromethane (S)95.0 70-130
06/29/23 14:511,2-Dichloroethane - d4 (S)94.4 70-130
06/29/23 14:51Toluene-d8 (S)95.0 70-130
LCS-V34839 LCSD-V34839Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
46.9 11711746.840.0µg/LAcetone 40-160 0.2 20.0
19.1 95.597.519.520.0µg/LBenzene 70-130 2.0 20.0
17.8 89.092.518.520.0µg/LBromobenzene 70-130 3.8 20.0
20.2 10110120.220.0µg/LBromochloromethane 70-130 0.0 20.0
18.6 93.094.518.920.0µg/LBromodichloromethane 70-130 1.6 20.0
Page 9 of 12Date:06/30/2023 03:00 PM
Page 39 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
LCS-V34839 LCSD-V34839Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.4 92.094.018.820.0µg/LBromoform 70-130 2.1 20.0
18.8 94.095.019.020.0µg/LBromomethane 60-140 1.0 20.0
18.7 93.596.019.220.0µg/Ln-Butylbenzene 70-130 2.6 20.0
18.8 94.096.019.220.0µg/Lsec-Butyl benzene 70-130 2.1 20.0
18.8 94.097.519.520.0µg/Ltert-Butyl benzene 70-130 3.6 20.0
18.2 91.095.019.020.0µg/LCarbon Tetrachloride 70-130 4.3 20.0
19.7 98.598.019.620.0µg/LChlorobenzene 70-130 0.5 20.0
18.3 91.592.518.520.0µg/LChlorodibromomethane 70-130 1.0 20.0
18.3 91.595.019.020.0µg/LChloroethane 60-140 3.7 20.0
18.5 92.594.518.920.0µg/LChloroform 70-130 2.1 20.0
16.2 81.089.517.920.0µg/LChloromethane 60-140 9.9 20.0
18.2 91.091.518.320.0µg/L2-Chlorotoluene 70-130 0.5 20.0
17.7 88.591.018.220.0µg/L4-Chlorotoluene 70-130 2.7 20.0
18.0 90.090.518.120.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.5 20.0
18.0 90.090.518.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 0.5 20.0
19.2 96.098.019.620.0µg/L1,2-Dibromoethane 70-130 2.0 20.0
18.6 93.097.019.420.0µg/LDibromomethane 70-130 4.2 20.0
19.1 95.597.519.520.0µg/L1,2-Dichlorobenzene 70-130 2.0 20.0
19.1 95.597.519.520.0µg/L1,3-Dichlorobenzene 70-130 2.0 20.0
18.8 94.095.019.020.0µg/L1,4-Dichlorobenzene 70-130 1.0 20.0
20.6 10310821.620.0µg/LDichlorodifluoromethane 60-140 4.7 20.0
18.5 92.594.518.920.0µg/L1,1-Dichloroethane 70-130 2.1 20.0
18.1 90.592.018.420.0µg/L1,2-Dichloroethane 70-130 1.6 20.0
19.0 95.094.018.820.0µg/L1,1-Dichloroethene 70-130 1.0 20.0
18.2 91.090.018.020.0µg/Lcis-1,2-Dichloroethene 70-130 1.1 20.0
18.4 92.095.019.020.0µg/Ltrans-1,2-Dichloroethene 70-130 3.2 20.0
Page 10 of 12Date:06/30/2023 03:00 PM
Page 40 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
LCS-V34839 LCSD-V34839Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.5 92.591.518.320.0µg/L1,2-Dichloropropane 70-130 1.0 20.0
18.6 93.095.019.020.0µg/L1,3-Dichloropropane 70-130 2.1 20.0
18.7 93.598.019.620.0µg/L2,2-Dichloropropane 70-130 4.6 20.0
19.3 96.598.019.620.0µg/L1,1-Dichloropropene 70-130 1.5 20.0
19.0 95.095.519.120.0µg/Lcis-1,3-Dichloropropene 70-130 0.5 20.0
18.1 90.592.518.520.0µg/Ltrans-1,3-Dichloropropene 70-130 2.1 20.0
546 109111553500µg/LEthanol 60-140 1.2 20.0
18.1 90.593.018.620.0µg/LEthylbenzene 70-130 2.7 20.0
20.1 10198.519.720.0µg/LHexachlorobutadiene 70-130 2.0 20.0
18.0 90.090.518.120.0µg/L2-Hexanone 60-140 0.5 20.0
18.4 92.094.518.920.0µg/LIsopropylbenzene 70-130 2.6 20.0
19.1 95.598.019.620.0µg/L4-Isopropyl toluene 70-130 2.5 20.0
16.8 84.086.517.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 2.9 20.0
19.1 95.597.019.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.5 20.0
17.2 86.085.517.120.0µg/L4-Methyl-2-Pentanone 60-140 0.5 20.0
18.3 91.595.019.020.0µg/LMethylene Chloride 70-130 3.7 20.0
16.0 80.079.015.820.0µg/LNaphthalene 70-130 1.2 20.0
18.5 92.594.518.920.0µg/Ln-Propylbenzene 70-130 2.1 20.0
19.0 95.097.519.520.0µg/LStyrene 70-130 2.5 20.0
19.1 95.597.019.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.5 20.0
18.4 92.090.518.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.6 20.0
19.9 99.510220.420.0µg/LTetrachloroethene 70-130 2.4 20.0
18.9 94.597.019.420.0µg/LToluene 70-130 2.6 20.0
18.2 91.098.019.620.0µg/L1,2,3-Trichlorobenzene 70-130 7.4 20.0
19.1 95.598.519.720.0µg/L1,2,4-Trichlorobenzene 70-130 3.0 20.0
19.1 95.598.019.620.0µg/L1,1,1-Trichloroethane 70-130 2.5 20.0
Page 11 of 12Date:06/30/2023 03:00 PM
Page 41 of 44
Quality Control Data
23-166-0032Report No:
Project Description:
Client ID:Harmon Environmental, PA
Goldmime 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V34841QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V34839
LCS-V34839 LCSD-V34839Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.9 94.598.019.620.0µg/L1,1,2-Trichloroethane 70-130 3.6 20.0
20.0 10010120.120.0µg/LTrichloroethene 70-130 0.4 20.0
19.6 98.010520.920.0µg/LTrichlorofluoromethane 60-140 6.4 20.0
18.5 92.592.518.520.0µg/L1,2,3-Trichloropropane 70-130 0.0 20.0
18.6 93.094.518.920.0µg/L1,2,4-Trimethylbenzene 70-130 1.6 20.0
18.6 93.094.518.920.0µg/L1,3,5-Trimethylbenzene 70-130 1.6 20.0
19.2 96.010420.820.0µg/LVinyl Acetate 60-140 8.0 20.0
18.9 94.599.519.920.0µg/LVinyl Chloride 60-140 5.1 20.0
19.1 95.596.519.320.0µg/Lo-Xylene 70-130 1.0 20.0
39.9 99.710140.340.0µg/Lm,p-Xylene 70-130 0.9 20.0
94.694.84-Bromofluorobenzene (S)70-130
95.494.2Dibromofluoromethane (S)70-130
96.296.41,2-Dichloroethane - d4 (S)70-130
96.296.2Toluene-d8 (S)70-130
Page 12 of 12Date:06/30/2023 03:00 PM
Page 42 of 44
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-166-0032
Harmon Environmental, PA
00358
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:06/15/2023 17:26:08
Special precautions or instructions included?
Comments:
Page 43 of 44
Page 44 of 44. • CHAIN OF CUSTODY RECORD Waypoint PAGE • OF_ QUOTE.TOENSUREPROPERBIU.ING: ______ _ ANALYTICAL Project Name: -lo.(}A--"C\..=O"-'V..=-='....._=<?-:.....=(,o...C,~-------::::----44ih~~~~~~~36l: ~~~~~'s~~J:~7 Short Hold Analysis (Yes) (No) UST Project: ff8S) (No) \.-\~~~~ ~,.,., tO,h •Please ATTACH any project specific reporting (QC LEVEL'r1fiiiiV) Client Company Name: 'Vl~1(j1J J14Ln provisions a.rl{:l/or QC Requirements ReportTo/ContactName: ___ ~~--lnvolceTo: \-\f\.a...,...o--J ~yl.t.N""~~'-1 (J'A Reporti~Address: ~ LJ4t.uy,;:(]"llccV">-~ Address:Gz (S f>Lvvk T~~~ g.o ' ~ aJrt.11~ ~( '2.-~JIZ... tJ\ovQm:s IVC t:iti'Z. Phone: 1d 1..<\ t u S:,)-Fax (Yes)(No): -Purchase Order No./BIIIing Reference _ _,3'-'t'-'c.=-~....::t,:..._~.:.__ ____ _ Email Address: h"'~f"W fl v p. '1 c l--ee: <.<·"" Requested Due Date 0 1 Day o 2 Days U 3 Days 0 4 Days CJ 5 Days EDD Type: PDF .:::t__ Excei __ Other "Wortdng Days" ...JS-9 Days \1 Standard 10 days :::1 Rush Work Must Be Pre Approved Site Location Name: y c ,.I') ,VI.fy IS. fc(, Samp4es received after 15:00 will be processed next business day Site Physical Address: SCJ 'I 'i' S~-tE:Ut c..v;; Turnaround bme IS based on business days. excluding weekends and holidays. -v (SEE REVERSE FOR TERMS & CONDmoNS REGARDING SERVICES 0 RENDERED BY WAYPOINT ANALYTICAL, U.C TO CLIENT) CUE NT SAMPLE DESCRIPTION DATE COLLECTED MATRIX (SOIL, WATER, OR SLUDGE) SAMPLE CONTAINER "TYPE SEE BELOW NO. SIZE PRESERVA· TIVES LAB USE ONLY YES NO N/A Samples INTACT upon arnval? ReceiVed IN ICE? PROPER PRESERVATIVES IndiCated? ReceiVed WITHIN HOLDING TIMES? ~ ~ ~ -'<..-CUSTODY SEALS INTACT? X:: VOLATILES rec'd W/OUT HEADSPACE? .::::z!E __ __ L PROPER CONTAINERS used? X __ __ TEMP: Therm 1~{ Observed t.::f.::c/Corr~·c TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: Nc_:!___ SC __ Other __ N/A Water Chlorinated: YES_ No_!_ Samples Iced Upon Collection: YES~NO __ REMARKS IDNO. 111111111111111111111111111111111111~1111111111111111111 ::-oo32 Harmon EnVIronmental PA 06-15-2023 Goldmtme66 172312 .J NC .J sc I :J NC 0 sc I (J NC 0 sc :J o o o __ _ A= Amber C = Clear G= Glass P = Plastic; TL "'Teflon-Lined Cap VOA "' Volatile Organics Analysis (Zero Head Space) LAB USE ONLY stt. Arrival nme: Site Departure nme: I Field Tech Fee: Mileage: SEE REVERSE FOR TERMS & CONDITIONS ORIGINAL