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HomeMy WebLinkAbout5002_JacksonCounty_MSWLF_CDLF_March23GW_FID1818165_20230926DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event#: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reoortina Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QEA of North Carolina, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Chuck Pippin Phone: 828-281-3350 E-mail: cpippin@anchorgea.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Jackson County Municipal Solid US Highway 441 50-02 .1600 March 22 to 28, 2023 Waste Landfill Dillsboro, North Carolina 28725 Environmental Status: (Check all that apply) Initial/Background Monitoring 0 Detection Monitoring Assessment Monitoring Corrective Action T e of data submitted: (Check all that apply) X Groundwater monitoring data from monitoring wells Methane gas monitoring data X Groundwater monitoring data from private water supply wells Corrective action data (specify) X Leachate monitoring data ❑ X Surface water monitoring data Other(specify) No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Chuck Pippin, P.G. Project Manager 828-281-3350 Facility Represent itle (Area Code) Telephone Number 9/26/2023 Affix NC Licensed/ Professional Geologist Seal Signature j // / { / Date 231 Haywood Street Asheville, North Carolina 28801 Facility Representative Address P-1649 NC PE Firm License Number (if applicable effective May 1, 2009) I. \A C A R o •.,,, GEN 1587 2? ��ykcFOLOG�S�`Q� . S G. ­00 Revised 6/2009 F r l l i September 2023 ANCHOR Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 INZ Q E A `'`'" Spring 2023 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department September 2023 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Spring 2023 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department 401 Grindstaff Cove Road Sylva, North Carolina 28779 Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 J ssica Ma rs SVff Scientist Project Number: C01480-01.02 \\WCL-FS1\Asheville\Projects\Jackson County\02_Reports - Groundwater\2023\01_Spring\Deliverables\a_Draft SubmittalWackson County -Semiannual Water Quality Report_Spring_2023.docx Table of Contents Table of Contents Abbreviations 1 Introduction 1 2 Semiannual Monitoring...........................................................................................................3 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling..........................................3 2.1.1 Monitoring Well Purging and Sampling Methods.................................................................3 2.1.2 Surface Water Sampling Methods................................................................................................4 2.1.3 Leachate Sampling Methods..........................................................................................................5 2.1.4 Domestic Well Sampling Methods...............................................................................................5 2.2 Sample Handling, Documentation, and Analysis....................................................................................5 2.2.1 Sampling Schedule.............................................................................................................................5 2.2.2 Spring 2023 Sampling.......................................................................................................................6 3 Findings........................................................................................................................................8 3.1 Groundwater.........................................................................................................................................................8 3.1.1 Field Parameters..................................................................................................................................9 3.1.2 Appendix I Metals (Total).................................................................................................................9 3.1.3 Appendix I Metals (Dissolved)..................................................................................................... 10 3.1.4 Appendix I VOCs and 1,4-Dioxane............................................................................................ 10 3.1.5 Natural Attenuation Parameters................................................................................................. 11 3.1.6 Surface Water..................................................................................................................................... 11 3.1.7 Field Parameters............................................................................................................................... 11 3.1.8 Appendix I Metals............................................................................................................................ 12 3.1.9 Appendix I VOCs and 1,4-Dioxane............................................................................................ 12 3.2 Leachate...............................................................................................................................................................12 3.3 Domestic Well.................................................................................................................................................... 13 3.3.1 Field Parameters............................................................................................................................... 13 3.3.2 VOCs...................................................................................................................................................... 13 3.4 Groundwater Flow Directions...................................................................................................................... 13 4 Summary....................................................................................................................................14 4.1 Groundwater Quality...................................................................................................................................... 14 4.1.1 Appendix I Metals............................................................................................................................ 14 Spring 2023 Semiannual Water Quality Monitoring Report i September 2023 4.1.2 Appendix I Volatile Organic Compounds and 1,4-Dioxane............................................. 14 4.1.3 Field Parameters and Other Constituents............................................................................... 14 4.2 Surface Water Quality..................................................................................................................................... 14 4.3 Leachate Quality............................................................................................................................................... 15 4.4 Domestic Well Water Quality...................................................................................................................... 15 5 Future Activities 16 6 References.................................................................................................................................17 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Well Construction Details and Corresponding Elevations Table 3 Analytical Summary Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) FIGURES Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Generalized Groundwater Flow Direction Figure 4 Hydrograph and Constituents of Concern Versus Time — MW-01 Figure 5 Hydrograph and Constituents of Concern Versus Time — MW-02 Figure 6 Hydrograph and Constituents of Concern Versus Time — MW-03 Figure 7 Hydrograph and Constituents of Concern Versus Time — MW-04 Figure 8 Hydrograph and Constituents of Concern Versus Time — MW-05R Figure 9 Hydrograph and Constituents of Concern Versus Time — MW-06 Figure 10 Hydrograph and Constituents of Concern Versus Time — MW-07 APPENDICES Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Spring 2023 Semiannual Water Quality Monitoring Report ii September 2023 Abbreviations pg/L micrograms per liter pmhos/cm micromhos per centimeter 2L standard 15A NCAC 2L.0202 Groundwater Standard CAER Five -Year Corrective Action Evaluation Report CAP Corrective Action Plan DEQ North Carolina Department of Environmental Quality DO dissolved oxygen EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration J estimated concentration that is greater than the analytical laboratory's method detection limit and less than the practical quantitation limit MDL method detection limit mg/L milligrams per liter MNA monitored natural attenuation mV millivolts NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation reduction potential PWR partially weathered rock SC specific conductivity Site closed Municipal Solid Waste Landfill SM Standard Method SU standard unit SWS Solid Waste Section TWSA Tuckasegee Water & Sewer Authority VOC volatile organic compound Spring 2023 Semiannual Water Quality Monitoring Report iii September 2023 1 Introduction The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (Site) approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management, Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County. The landfill permit requires semiannual monitoring of groundwater and surface water quality. Since October 2007, when Anchor QEA of North Carolina, PLLC, began performing water quality monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level concentrations of constituents that exceeded groundwater quality standards. In response to the continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was submitted to the North Carolina Department of Environment and Natural Resources (now DEQ) on September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was implemented upon approval by the North Carolina Department of Environmental and Natural Resources, as recorded in the September 1, 2011, letter regarding "Approval of the County's Corrective Action Plan" (DENR 2011). The implemented remedy includes the extraction of leachate through dedicated submersible pumps installed within landfill gas extraction wells and disposal of the leachate into the Tuckasegee Water & Sewer Authority (TWSA) collection system. In addition to the leachate extraction, groundwater natural attenuation parameters are monitored, and natural attenuation processes are evaluated. As discussed in the CAP, a corrective action evaluation report is prepared every 5 years. The evaluation report analyzes the progress of the approved corrective action remedy based on semiannual water quality monitoring data. The remedy was implemented in a phased approach, with full implementation occurring on September 6, 2013. The first Five -Year Corrective Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016 (Altamont 2016), concluded that the current conditions of the monitored natural attenuation (MNA) parameters and Site geochemical parameters allow for the slow degradation of the select contaminants identified in the CAER. The second CAER was submitted by Anchor QEA on January 13, 2022, and concluded that the leachate extraction system has improved but still does not align with the anticipated performance as modeled in the CAP. This report serves as the first semiannual water quality monitoring report for 2023. The report provides an evaluation of groundwater and surface water quality. The water quality monitoring network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water monitoring, this report includes analysis of the extracted leachate and two domestic water wells. The water samples collected from selected monitoring points during the spring sampling event were analyzed for a range of parameters, as presented in Section 2.2 and Table 1. The spring 2023 Spring 2023 Semiannual Water Quality Monitoring Report 1 September 2023 sampling event was performed on March 22, 23, 27, and 28, 2023 and is being reported in accordance with requirements stipulated in the DEQ Solid Waste Management Rules codified under Title 15A, Subchapter 13B of the North Carolina Administrative Code (NCAC). Spring 2023 Semiannual Water Quality Monitoring Report 2 September 2023 2 Semiannual Monitoring 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface water sample locations (SW-01, SW-02, and SW-03), leachate sample location (LT-01), and domestic wells (DW-01 and DW-02) were sampled between March 22 and 28, 2023, by Anchor QEA. Surface water sample location, SW-03, was added during the spring 2022 sampling event following a request by DEQ to include one additional new surface water sampling location between SW-01 and SW-02 to further monitor 1,4-dioxane. The request was included in the letter to Jackson County from DEQ regarding review and approval of the Five -Year CAER, dated February 3, 2022. Static groundwater level measurements and field parameter data are included on the sampling logs presented in Appendix A. Field equipment calibration logs for the YSI Professional Plus Multiparameter Water Quality Meter and the Hach 2100Q Turbidimeter are also provided in Appendix A. The full suite of groundwater and surface water laboratory analytical results is presented in the laboratory analysis reports in Appendix B. Monitoring wells MW-01 and MW-06 are considered to be the Site's upgradient monitoring wells; MW-03 and MW-05R are located in the mid -gradient portion of the Site; and MW-02, MW-04, and MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the monitoring wells range from 43 to 110.5 feet below ground surface. The geology of the screened intervals of the monitoring wells is as follows: • Saprolite': MW-04 and MW-05R • Partially weathered rock (PWR)2: MW-03 • Bedrock3: MW-01, MW-02, MW-06, and MW-07 The locations of the monitoring wells, surface water samples, leachate, and domestic well sample locations are shown in Figure 2. 2.1. 7 Monitoring Well Purging and Sampling Methods Before the monitoring wells were sampled, the static water level was gauged in each well, and an initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]). Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock. z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite. 3 Bedrock is solid competent rock that underlies Saprolite and partially weathered rock. Spring 2023 Semiannual Water Quality Monitoring Report 3 September 2023 Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the monitoring wells and collect groundwater samples. The total depth, condition of the casing, and groundwater recharge rate determined the purging and sample collection method employed at each monitoring well. Four of the monitoring wells (MW-03, MW-04, MW-064, and MW-07) were purged using low -flow techniques in accordance with the procedures described by the U.S. Environmental Protection Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996). During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had generally stabilized for three consecutive readings. The required stabilization criteria are determined by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater Sampling (EPA 2017) and are summarized as follows: • pH values within ±0.1 standard unit (SU) • SC values within ±5% • Temperature, DO, and turbidity values within ±10% • ORP values within ±10 millivolts (mV) Once the parameters had stabilized, a groundwater sample was collected by field personnel wearing a new pair of nitrile gloves, using laboratory -supplied sample containers. Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged and sampled using disposable bailers. The three wells were purged dry on March 21 and sampled on March 23, 2023, after they had sufficient time to recharge. A round of field parameters was measured and recorded at the start of purging and after each consecutive well volume had been purged. Field parameter data are shown in the well sampling logs included in Appendix A. 2.1.2 Surface Water Sampling Methods Surface water samples SW-01, SW-02, and SW-03 were collected on March 23, 2023, at designated locations from the Tuckasegee River, which is adjacent to and southwest of the landfill (Figure 2). Sampling location SW-01 is assumed to represent surface water quality upstream of the landfill, and sampling location SW-02 is assumed to represent surface water quality downstream of the landfill. SW-03 is assumed to represent surface water quality adjacent to the landfill. One round of field parameters was measured and recorded at each surface water sampling location immediately prior ° MW-06 was also sampled using a bailer on March 28, 2023, to collect a sample for nitrate analysis. The original nitrate analysis was not analyzed within hold time by the analytical laboratory. Spring 2023 Semiannual Water Quality Monitoring Report 4 September 2023 to collecting the sample (Appendix A). The surface water samples were collected in laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves. 2. 7.3 Leachate Sampling Methods Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells EW-1 R, EW-2R, EW-31R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization tank, which is connected to the TWSA wastewater collection system. The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab sample of leachate (LT-01) was acquired on March 28, 2023, by collecting a sample as the leachate entered the flow equalization tank. One round of field parameters was measured and recorded after the sample was collected (Appendix A). 2.1.4 Domestic Well Sampling Methods The domestic well water samples (DW-01 and DW-02) were collected on March 28, 2023, from an outside spigot at the residence located at 318 Joe Wilkey Road (DW-01) and 138 Joe Wilkey Road (DW-02), bordering the northern boundary of the landfill (Figure 2). Each well was purged of 30 gallons prior to sample collection. One round of field parameters was measured and recorded after the 30 gallons had been purged. The domestic well water samples were collected in laboratory -provided sample containers by field personnel wearing new nitrile gloves. 2.2 Sample Handling, Documentation, and Analysis 2.2. 7 Sampling Schedule The sampling schedule for semiannual sampling events at the Jackson County Landfill is as follows: Spring 2023 Semiannual Water Quality Monitoring Report 5 September 2023 Parameter Groundwater Surface Water Leachate Domestic Well Groundwater Appendix I VOCs Annual Spring Annual Spring Annual Spring Not Applicable Appendix I Metals Annual Spring Annual Spring Annual Spring Not Applicable Appendix II VOC Annual Fall Annual Fall Annual Fall Not Applicable Appendix 11 SVOC Annual Fall Annual Fall Annual Fall Not Applicable Appendix II Metals Annual Fall Annual Fall Annual Fall Not Applicable Mercury Annual Fall Annual Fall Annual Fall Not Applicable 1,4-Dioxane Semiannual Semiannual Semiannual Not Applicable Herbicides and Pesticides Biennial — Fall Even Years Biennial — Fall Even Years Not Applicable Not Applicable MNA Parameters Biennial Spring and Fall Odd Years Not Applicable Not Applicable Not Applicable Hardness Not Applicable Semiannual Not Applicable Not Applicable VOC by 524.2 Not Applicable Not Applicable Not Applicable Semiannual 2.2.2 Spring 2023 Sampling Field parameters and additional observations pertaining to the Site sampling locations are provided in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water, leachate, and domestic well water sample was immediately placed on ice in a sample cooler for transport to Waypoint Analytical Laboratories, a North Carolina -certified laboratory in Charlotte, North Carolina. The groundwater samples collected from the monitoring wells were analyzed for the following parameters (Table 1): • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I volatile organic compounds (VOCs) using EPA Method 8260D • 1,4-dioxane using EPA Method 8260DSIM • MNA parameters: — Alkalinity, using Standard Method (SM) 2320B — Biochemical oxygen demand (BOD; 5-day), using SM 5210B — Volatile fatty acids, carbon dioxide, ethane, ethene, and methane, using Analytical Method (AM) 20GAX — Hydrogen (only in MW-03, MW-04, MW-06, and MW-07), using AM20GAX — Chemical oxygen demand (COD), using SM 5220D — Chloride, nitrate, and sulfate, using EPA Method 9056A — Ferrous iron, using SM 3500-Fe D — Sulfide, using SM 4500-S F Spring 2023 Semiannual Water Quality Monitoring Report 6 September 2023 — Total organic carbon (TOC), using SM 9060A — Nitrate as N, chloride, and sulfate, using EPA Methods 9056A The surface water samples were analyzed for the following parameters: • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I VOCs using EPA Method 8260D • 1,4-dioxane using EPA Method 8260DSIM • Hardness using SM2340C The leachate sample was analyzed for the following parameters: • Appendix I VOCs, using EPA Method 8260D • 1,4-dioxane, using EPA Method 8260DSIM • Appendix I metals using EPA Method 6020B The domestic well samples were analyzed for the following parameters: • VOCs using EPA Method 524.2 Proper chain -of -custody documentation procedures were followed during collection and transportation of each sample (Appendix B). Two trip blank samples for quality control/quality assurance purposes were included in the sample coolers and analyzed for Appendix I VOCs when applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses performed on the samples are summarized in Table 1. Spring 2023 Semiannual Water Quality Monitoring Report 7 September 2023 3 Findings The field parameter data and laboratory analytical results for the groundwater samples (from monitoring wells MW-01 through MW-07), surface water samples (SW-01, SW-02, and SW-03), leachate sample (LT-01), and domestic well samples (DW-01 and DW-02) collected at the landfill are included in Appendices A and B. The results are also submitted separately to the DEQ Division of Waste Management SWS in the Electronic Data Deliverable format (DEQ 2020). The laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections are values reported by the laboratory as less than the method detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit. The method reporting limit is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Groundwater Quality Standard: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is defined in the 15A NCAC 2L.0202 Groundwater Standard 15A NCAC 2L.0202 (2L standard). Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L.0202 [c]). For the purposes of this report, groundwater standards were taken from the October 15, 2018, list published by the North Carolina SWS (DEQ 2018). • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards defined in 15A NCAC 2B (213 standards). Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 3 summarizes detected concentrations of analytes that exceeded their respective 2L standard, IMAC, or 2B standard. 3.1 Groundwater Measured field parameters and analytical results for groundwater samples collected from the monitoring wells during the spring 2023 sampling event are discussed in the following sections and summarized in Table 3. Spring 2023 Semiannual Water Quality Monitoring Report 8 September 2023 3.1.7 Field Parameters Field parameter measurements were obtained from all Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07). Field parameters are presented in Table 3 and summarized below: • pH: The pH readings ranged from 5.6 SU in MW-06 to 6.7 SU in MW-05R. Of these monitoring wells, the pH values for MW-01, MW-02, MW-04, MW-06, and MW-07 were less than the 2L standard pH range of 6.5 to 8.5 SU. The pH values for MW-03 (6.6 SU) and MW-05R (6.7 SU) were within the 2L standard pH range. • Turbidity: Turbidity ranged from 0.46 nephelometric turbidity units (NTUs) in MW-04 to 197 NTU in MW-05R. Generally, the higher values were measured at the monitoring wells (MW-02 and MW-05R) that were purged and sampled using the bailer method (Section 2.1.1). The bailers were lowered gently to minimize water column disturbance when the samples were collected. • Dissolved Oxygen (DO): DO concentrations at the Site ranged from 2.08 milligram per liter (mg/L) in monitoring well MW-01 to 26.74 mg/L in monitoring well MW-04. • SC: SC concentrations at the Site ranged from 68.7 micromhos per centimeter (pmhos/cm) in monitoring well MW-06 to 819 pmhos/cm in monitoring well MW-07. • Oxidation/Reduction Potential: ORP concentrations at the Site ranged from -95.7 mV in monitoring well MW-05R to 539.1 mV in monitoring well MW-04. 3.1.2 Appendix 1 Metals (Total) Thirteen metals were detected in one or more of the monitoring well samples. Three of these metals (chromium, cobalt, and vanadium) were detected at concentrations above their respective 2L water quality standards in one or more of the groundwater samples. A summary of the detections that exceed the 2L standards is provided below. • Chromium (21L standard of 10 pg/L): Chromium was detected in MW-02 at a concentration of 41.7 pg/L. • Cobalt (21L standard of 1 pg/L): Cobalt was detected in MW-01, MW-02, MW-03, MW-05R, MW-06, and MW-07. Cobalt concentrations in these samples ranged from 2.7 pg/L (MW-07) to 115 pg/L (MW-01). As noted in Section 2.1, monitoring well MW-01 is considered to represent upgradient conditions. The second upgradient well (MW-06) also showed an exceedance of cobalt (13.8 pg/L). Historically, cobalt has been present at concentrations that exceeded its applicable water quality standard in groundwater samples from each of the seven monitoring wells. • Vanadium (21L standard of 7 pg/L): Vanadium was detected in MW-02 at a concentration of 52.5 pg/L. Spring 2023 Semiannual Water Quality Monitoring Report 9 September 2023 These metals have historically been present at concentrations exceeding their water quality standard in samples collected from multiple groundwater monitoring wells at the Site. 3.7.3 Appendix 1 Metals (Dissolved) Laboratory -filtered analysis of Appendix I metals was performed for monitoring well samples MW-02 and MW-05R because of their elevated turbidity readings (111 and 197 NTU, respectively) during sample collection. The reported concentrations for the dissolved metals were consistently lower than the total unfiltered metals analytical results for each monitoring well. Dissolved concentrations for chromium, cobalt, and vanadium were generally lower in concentration but still exceeded the 2L standards (Table 3). 3.7.4 Appendix 1 VOCs and 7,4-Dioxane Eleven VOCs were detected in one or more of the monitoring wells (Table 3). Four of these VOCs (1,4-dioxane; benzene; vinyl chloride, and 1,4-dichlorbenzene) were detected at concentrations that exceeded their respective 2L standards in the groundwater samples collected from one or more monitoring wells. Concentration -versus -time graphs (trend plots) were created for the monitoring wells that have historically exhibited the following VOC concentrations that exceeded the associated 2L standards (Figures 4 through 10): • 1-4-dichlorobenzene (2L standard of 6 pg/L): The detected concentration of 1,4-dichlorobenzene exceeded its 2L standard in monitoring wells MW-05R (8.57 pg/L) and MW-07 (6.20 pg/L). Historical 1,4-dichlorobenzene concentrations in MW-05R have consistently fluctuated (Figure 8). The historical 1,4-dichlorobenzene concentrations in MW-07 remain relatively stable (Figure 10). • 1,4-dioxane (2L standard of 3 pg/L): The detected concentrations of 1,4-dioxane exceeded its 2L standard in MW-04 (5.04 pg/L), MW-05R (6.18 pg/L), and MW-07 (15.8 pg/L). 1,4-dioxane was not detected in monitoring wells MW-01, MW-02, MW-03, or MW-06. In general, the trend plot for 1,4-dioxane concentrations in MW-07 shows declining concentrations since sampling for this compound began in October 2018 with the exception of a peak of 20.2 pg/L in the fall of 2021. • Benzene (2L standard of 1 pg/L): Benzene was detected at concentrations that exceeded its 2L standard in MW-05R (1.58 pg/L) and MW-07 (1.59 pg/L). Benzene has historically been reported with exceedances in MW-01, MW-05R, and MW-07. Overall, benzene concentrations in monitoring well MW-01 have shown a generalized downward trend since April 2007 (Figure 4), and for this sampling event it was not detected. Benzene concentrations at MW- 05R have fluctuated since 2012 (Figure 8). Benzene concentrations at MW-07 have been relatively stable since 2011 (Figure 10). • Vinyl chloride (2L standard of 0.03 pg/L): The concentrations of vinyl chloride in the samples collected from MW-04 (0.210 pg/L) and MW-05R (0.684 pg/L) exceeded the compound's Spring 2023 Semiannual Water Quality Monitoring Report 10 September 2023 2L standard. Trend plots for vinyl chloride in MW-04 and MW-05R show fluctuating concentrations (Figures 7 and 8). A review of historical groundwater data indicates the VOCs (1,4-dichlorobenzene; 1,4-dioxane; benzene; and vinyl chloride) exhibiting concentrations that exceeded the 2L standards during the spring 2023 sampling event have been detected at relatively similar concentrations for the past several years. As described in Section 3.2.3, historical surface water samples from the Tuckasegee River, which may receive discharge from the saprolite groundwater -bearing zone, have consistently shown no detections of these compounds or other VOCs. 3. 7.5 Natural Attenuation Parameters During this sampling event, the groundwater samples were analyzed for MNA parameters as described in Section 2.2 (Table 1). The results of these analyses are summarized in Table 35. These parameters were detected in one or more groundwater samples collected from the monitoring wells. Many of these parameters do not have established groundwater standards. Of the parameters that do have established groundwater standards, only nitrate in MW-04 (25.8 mg/L) exceeded its 2L standard. An in-depth analysis of the MNA parameters that apply to the Site's select contaminants was presented in the first and second Five -Year CAER (Altamont 2016, Anchor QEA, 2022). The CAER concluded that the MNA data provide evidence that reductive degradation and aerobic degradation are occurring in different portions of the Site. The dataset of the MNA parameters collected from spring 2017 to spring 2026 will be used in the third Five -Year CAER (scheduled for fall 2026) to evaluate the degradation processes at the Site. 3.1.6 Surface Water The following sections summarize the measured field parameters and analytical results associated with the two surface water samples collected during the spring 2023 sampling event. 3. 7.7 Field Parameters Field parameters are presented in Table 3 and summarized below: • pH: The pH readings for the upstream (SW-01), and midstream (SW-03), downstream (SW-02) surface water samples collected during the spring 2023 sampling event were 7.1, 7.0, and 6.9 SU, respectively. The pH readings for all three surface water samples were within the 2B standard range of 6.0 to 9.0 SU. 5 The nitrate results for MW-02 and MW-03 and the ferrous iron results for MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07 were analyzed outside of the hold time due to laboratory error. Spring 2023 Semiannual Water Quality Monitoring Report 11 September 2023 • Turbidity: The turbidity values measured in SW-01 (6.04 NTU), SW-03 (5.57 NTU), and SW-02 (12.0 NTU) were less than the 2B standard, which is established at less than or equal to 50 NTU for the receiving water in streams not designated as trout waters. • DO: DO was measured at a concentration of 11.4 mg/L in SW-01, 11.12 mg/L in SW-03, and 11.2 mg/L in SW-02. The 2B standard is established as greater than or equal to 6 mg/L; thus, each sample is within the acceptable DO range. • SC: SC values in surface water samples SW-01, SW-03, and SW-02 were recorded at 27.2, 25.3, 26.4 and pmhos/cm, respectively. These values of SC are consistent with historical data for both surface water samples. • ORP: ORP values for SW-01, SW-03,and SW-02 were 136, 167.6, 156.5 mV, respectively. These observed values are consistent with historical data. 3.1.8 Appendix I Metals Ten metals were detected in the three surface water sampling locations. Of these metals, concentrations of zinc and lead exceeded applicable 213 standards. Zinc was reported at a concentration greater than the 2B standard (14.08 pg/L) in SW-02 (18.5 pg/L). Lead was reported with a concentration greater than NC213 (.15 pg/L) in SW-03 (0.285 J pg/L). Lead has historically been detected above 2B standards at both the upstream and downstream sampling locations. In Spring 2023, lead was a non -detect in surface water samples SW-01 and SW-02. 3. 7.9 Appendix I VOCs and 1,4-Dioxane Acetone was the only VOC detected in the surface water samples and was also detected at a similar concentration in the trip blank sample included with the surface water samples. 3.2 Leachate Eight metals (arsenic [15.4 pg/L], barium [1260 pg/L], chromium [20.3 pg/L], cobalt [9.39 J pg/L], copper [8.50 J pg/L], lead [303 J pg/L], nickel [34.3 pg/L], and vanadium [26.5 J pg/L]) were detected in the leachate sample (LT-01). Four VOCs (1,4-dichlorobenzene [2.34 J pg/L]; 1,4-dioxane [48.7 pg/L]; 1,2-dichloroethene, cis- [2.16 J pg/L]; and tetrahydrofuran [95.7 pg/L]) were detected in the leachate sample (LT-01). On September 1, 2012, leachate extraction was initiated following installation of leachate extraction pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Based on readings taken from the leachate totalizer during the March 2023 monitoring events, approximately 30,804 gallons of leachate were discharged through a permanent connection to the TWSA between October 4, 2022, and March 28, 2023. Spring 2023 Semiannual Water Quality Monitoring Report 12 September 2023 In fall 2013, the active portion of the approved corrective action remedy was initiated. Based on the leachate analytical results for the sample collected on March 28, 2023, Anchor QEA estimates that approximately 0.0382 pounds of VOCs were removed with the extracted leachate between the October 2022 and March 2023 sampling events. Mass removal calculations through March 2023 are included in Table 4. 3.3 Domestic Well The following sections summarize measured field parameters and analytical results associated with the domestic well water samples collected during the spring 2023 sampling event. 3.3.7 Field Parameters The pH readings for the domestic well samples for DW-01 and DW-02 were 6.6 and 6.8 SU, respectively, which are within the 2L standard range of 6.5 to 8.5 SU. Turbidity measured in DW-01 was 32.6 NTU. DO was measured at a concentration of 18.82 mg/L in DW-01. SC and ORP values in DW-01 were recorded at 63.3 pmhos/cm and 223.6 mV, respectively. Turbidity measured in DW-02 was 1.19 NTU. DO was measured at a concentration of 22.69 mg/L in DW-02. SC and ORP values in DW-02 were recorded at 63.3 pmhos/cm and 274 mV, respectively. These parameters do not have established water quality standards. 3.3.2 VOCs No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. 3.4 Groundwater Flow Directions Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three of the bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is located southwest of the landfill (Figure 3). PWR monitoring well MW-03 and saprolite monitoring wells MW-04 and MW-05R (Figure 3) are located in the south-central and southern parts of the landfill, respectively. The spring 2023 water level data collected from the Site wells are presented in Figure 3. These data were used to determine the generalized groundwater flow direction for all aquifer zones, which is to the southwest (Figure 3). Spring 2023 Semiannual Water Quality Monitoring Report 13 September 2023 4 Summary The first semiannual water quality monitoring event of 2023 for the Site was performed between March 23 and 28, 2023. Appendices A and B and Table 3 provide detailed analytical results and field data summarizing the groundwater, surface water, and leachate quality at the landfill. 4.1 Groundwater Quality 4.1. 7 Appendix I Metals Three metals (chromium, cobalt, and vanadium) were detected at concentrations that exceeded their associated groundwater quality standards in one or more of the monitoring wells (Table 3). Chromium concentrations exceeded their 2L standard in MW-02. Cobalt concentrations exceeded their 2L standard in all the collected groundwater samples with the exception of MW-04. Vanadium exceeded its 2L concentration in MW-02. These results are consistent with historical data. 4.1.2 Appendix I Volatile Organic Compounds and 1,4-Dioxane Four VOCs (1,4-dichlorobenzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at concentrations that exceeded their respective 2L standards (Table 3) in one or more monitoring wells. Trend plots for samples from monitoring wells that had VOC concentrations that exceeded their 2L standards (Figures 4 through 10) show relatively stable or declining concentrations with time. 4.1.3 Field Parameters and Other Constituents Five of the seven samples collected from the monitoring wells had pH readings outside of the 2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are characteristic of the natural groundwater quality of the region. Turbidity readings ranged from 0.46 NTU (MW-04) to 197 NTU (MW-05R). 4.2 Surface Water Quality Laboratory estimated concentrations of lead greater than 2B standards were detected in surface water sample SW-03 (midstream) at a concentration of 0.285 J pg/L. Zinc was detected in SW-02 (downstream) at a concentration greater than its 2B standard. Historically, detections of these metals have been observed in the upstream sample location, SW-01, at similar concentrations, suggesting that these metals are naturally occurring. Field parameters measured in all surface water samples, including turbidity and DO, were within the 2B standards established for these parameters. The pH measured at all surface water locations were within the range of 2B standards. Spring 2023 Semiannual Water Quality Monitoring Report 14 September 2023 4.3 Leachate Quality The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for Appendix I VOCs and 1,4-dioxane. Four VOCs were detected in the leachate sample (Table 3). There are no established water quality standards for leachate. 1,4-dioxane was detected at 48.7 fag/L, which is higher than the detected concentrations of the compound in the monitoring well groundwater samples. 4.4 Domestic Well Water Quality No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. Spring 2023 Semiannual Water Quality Monitoring Report 15 September 2023 5 Future Activities Anchor QEA will continue to monitor the water quality on a semiannual basis at the Site. During fall 2023, domestic well owners will be contacted, and groundwater samples will be collected from domestic wells if permitted by the well owner, and if possible, based on well pump operability. Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring wells, surface water monitoring points, and leachate flow equalization tank during fall 2023 and spring 2024. The analytical suites associated with the current and future sampling events are outlined in the 2011 CAP (Altamont 2011), the first CAER (Altamont 2016), and the second CAER (Anchor QEA 2022). The upcoming sampling event parameters are as follows: Sampling Event Analytical Suite Appendix II VOCs (including 1,4-dioxane) Fall 2023 Appendix II Metals (including Mercury) Appendix II semivolatile organic compounds MNA Parameters Appendix I VOCs (including 1,4-dioxane) Appendix I Metals Spring 2024 Pesticides Herbicides Per the March 13, 2023, memorandum from the DEQ, per and polyfluoroalkyl substance (PFAS) will also be analyzed during the fall 2023 and spring 2024 sampling events (DEQ 2023). Spring 2023 Semiannual Water Quality Monitoring Report 16 September 2023 6 References Altamont (Altamont Environmental, Inc.), 2010. Assessment of Corrective Measures. Prepared for North Carolina Department of Environment and Natural Resources. September 7, 2010. Altamont, 2011. Corrective Action Plan. Prepared for North Carolina Department of Environment and Natural Resources. June 30, 2011. Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina Department of Environmental Quality. October 31, 2016. Anchor QEA (Anchor QEA of North Carolina, PLLC), 2020. Spring 2020 Semiannual Water Quality Monitoring Report. Prepared for Jackson County Solid Waste Department. June 2020. Anchor QEA, 2022. Five -Year Corrective Action Evaluation Report. Prepared for North Carolina Department of Environmental Quality. January 13, 2022. DENR (North Carolina Department of Environmental and Natural Resources), 2011. Letter to: Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan. September 1, 2011. DEQ, 2018. "Groundwater Protection Compliance Standards — Constituents List." Last modified October 15, 2018. Available at: https://edocs.deq.nc.gov/WasteManagement/0/edoc/12571811SWS_EnviroMonitoring_Const ituents_List.pdf?searchid=13f8efbl -eel l-485a-b03f-718f2287b271. DEQ, 2020. Memorandum to: Solid Waste Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding: New Electronic Data Deliverable (EDD) Format. July 20, 2020. DEQ, 2022. Letter to Jackson County from DEQ regarding review and approval of the Five -Year Corrective Action Evaluation Report. DEQ, 2023. Memorandum to: Solid Waste Directors and Landfill Owners/Operators. Regarding: PFAS Monitoring Requirements for Solid Waste Sanitary Landfills, March 13, 2023. EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. Office of Land and Emergency Management, EPA/540/5-95/504. EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling. April 26, 2017. Spring 2023 Semiannual Water Quality Monitoring Report 17 September 2023 Tables Figures Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Location ID Date Collected Sample ID Appendix I VOCs 1,4-Dioxane Appendix I Metals Mercury Appendix II SVOCs Appendix II Herbicides Appendix II Pesticides EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A EPA 8270D EPA 8151A EPA 8081 B and 8141 B MW-01 03/23/2023 MW-01-20230323 X X X X X X X MW-02 03/23/2023 MW-02-20210310 X X X X X X X MW-03 03/27/2023 MW-03-20230327 X X X X X X X MW-04 03/28/2023 MW-04-20230328 X X X X X X X MW-05R 03/23/2023 MW-05R-20230323 X X X X X X X MW-06 03/22/2023 MW-06-20230322 X X X X X X X MW-07 03/27/2023 MW-07-20230327 X X X X X X X DUPLICATE 03/27/2023 DUP-20230327 X X X X X X X Surface Water, Leachate, Domestic Well, and Quality Control Samples Location ID Date Collected Sample ID Appendix I VOCs 1,4-Dioxane Appendix I Metals Mercury Appendix II SVOCs Calcium, Magnesium, Hardness VOCs EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A EPA 8270D EPA 200.7 EPA 524.2 DW-01 03/28/2023 DW-01-20230328 X DW-02 03/28/2023 DW-02-20230328 X LT-01 03/28/2023 LT-01-20230328 X X X SW-01 03/23/2023 SW-01-20230323 X X X X X X SW-02 03/23/2023 SW-02-20230323 X X X X X X SW-03 03/23/2023 SW-03-20230323 X X X X X X TB-01 03/23/2023 TB-20230323 X TB-02 03/27/2023 TB-20230327 X TB-03 03/28/2023 TB-20230328 X Groundwater and Surface Water Samples: Monitored Natural Attenuation Parameters Location ID Date Collected Sample ID COD BOD Ferrous Iron Total Alkalinity to pH 4.5 Nitrate as N Chloride Sulfate TOC Sulfide Volatile Fatty Acids Carbon Dioxide Ethane, Ethene, Methane Dissolved Hydrogen SM 5220D SM 5210B SM 3500-Fe D SM 2320B EPA 9056A 531OC-2011 SM4500-S2F AM23G AM20GAX and RSK 175 MW-01 03/23/2023 MW-01-20230323 X X X X X X X X X X X X X MW-02 03/23/2023 MW-02-20230323 X X X X X X X MW-02 03/27/2023 MW-02-20230327 X X X X X X MW-03 03/27/2023 MW-03-20230327 X X X X X X X X X X X X X MW-03 03/28/2023 MW-03-20230328 X X X X MW-04 03/28/2023 MW-04-20230328 X X X X X X X X X X X X X MW-05R 03/23/2023 MW-05R-20230323 X X X X X X X X X X X X X MW-06 03/22/2023 MW-06-20230322 X X X X X X X X X X X X MW-06 03/28/2023 MW-06-20230328 X MW-07 03/27/2023 MW-07-20230327 X X X X X X X MW-07 03/28/2023 MW-07-20230328 X X X X X X DUPLICATE 03/27/2023 DUP-20230327 X X X X X X X X X X X X X Notes: 1: An additional sample was collected for a laboratory -filtered dissolved metals analysis. Appendix II constituents were analyzed per Title 40 Code of Federal Regulations, Part 258. Blank cell: Analysis was not performed on that sample. BOD: biochemical oxygen demand COD: chemical oxygen demand EPA: U.S. Environmental Protection Agency (method) SIM: selective ion monitoring SM: Standard Method SVOC: semivolatile organic compound TB: trip blank TOC: total organic carbon VOC: volatile organic compound Spring 2023 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 2 Well Construction Details and Corresponding Elevations Stick Up Depth to Depth to Elevation of Ground (feet Depth To Approximate Approximate Top of Bottom of Top Elevation Bottom of Surface TOC above Total Well Water Depth to Top of Bedrock Screened Screened of Screened Screened Geology of Source of Well Elevation Elevation ground Depth (feet below Groundwater Bedrock Elevation Interval Interval Interval Interval Screened Construction Facility Permit Well ID Date Drilled (feet) (feet) surface) (feet bgs) TOC) Elevation (feet) (feet bgs) (feet) (feet bgs) (feet bgs) (feet) (feet) Interval Information MW-01 04/23/1992 2,169.40 2,171.42 2.0 110.5 107.58 2,063.84 83.0 2,086.40 95.0 110.0 2,074.40 2,059.40 Bedrock MW-02 04/22/1992 2,013.15 2,015.38 2.3 60.7 43.25 1,972.13 13.0 2,000.15 45.0 60.0 1,968.15 1,953.15 Bedrock Partially S&ME, Inc. MW-03 04/21/1992 2,044.16 2,045.53 1.3 65.5 46.38 1,999.15 57.0 1,987.16 48.5 63.5 1,995.66 1,980.66 Weathered Rock 50-02 MW-04 04/21/1992 1,978.68 1,980.77 2.0 43.0 25.50 1,955.27 NA NA 25.0 40.0 1,953.68 1,938.68 Saprolite MW-05R 01/26/2012 2,027.98 2,030.95 2.8 54.0 49.50 1,981.45 NA NA 44.0 54.0 1,983.98 1,973.98 Saprolite MW-06 03/23/2004 2,136.58 2,139.57 3.0 94.0 86.00 2,053.57 47.6 2,088.98 84.6 94.6 2,051.98 2,041.98 Bedrock Altamont Environmental, Inc. MW-07 07/30/2010 1,978.71 1,981.29 2.6 95.0 31.92 1,949.37 44.0 1,935.00 70.0 95.0 1,908.71 1,883.71 Bedrock Notes: Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc. Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveying, PA. Depth to water was measured on March 9 and 10, 2021. Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., boring logs completed April 21 through 23, 1992. Depth to bedrock and screened interval for MW-06 was taken from an Altamont Environmental, Inc., boring log completed March 23, 2004. Depth to bedrock and screened interval for MW-07 was taken from an Altamont Environmental, Inc., boring log completed July 30, 2010. Depth to bedrock and screened interval for MW-05R was taken from an Altamont Environmental, Inc., boring loq completed January 26, 2012. Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05. Monitorinq well MW-05R was surveyed by Wes Cole Land Surveyinq, PA, on September 28, 2012. bgs: below ground surface NA: not applicable TOC: top of casing Spring 2023 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Location ID Sample ID Sample Date Domestic Well Samples Leachate Sample DW-01 DW-02 LT-01 MW-01 DW-01- 20230328 DW-02- 20230328 LT-01-20230328 MW-01- 20230323 3/28/2023 3/28/2023 3/28/2023 3/23/2023 NC2L Method NC21- IMAC NC213 Conventional Parameters Monitoring Well Samples MW-02 MW-02 MW-03 MW-03 MW-04 MW-05R MW-06 MW-02- MW-02- MW-03- MW-03- MW-04- MW-05R- MW-06- 20230323 20230327 20230327 20230328 20230328 20230323 20230322 3/23/2023 3/27/2023 3/27/2023 3/28/2023 3/28/2023 3/23/2023 3/22/2023 Water Level Depth (ft) Field -- -- -- -- -- -- 107.58 43.25 -- 46.38 -- 25.5 49.5 86 Temperature (°C) Field -- -- -- 15.0 13.6 14.0 15.2 15.0 -- 16.9 -- 14.9 17.0 12.2 pH (SU) Field 6.5-8.5 -- 6.0-9.0 6.6 6.8 7.5 5.8 6.0 -- 6.6 -- 5.8 6.7 5.6 Turbidity (NTU) Field -- -- <50 32.6 1.19 1000 5.02 111 -- 3.86 -- 0.46 197 1.73 Dissolved oxygen (mg/L) Field -- -- <6.0 18.82 22.69 14.33 2.08 6.73 -- 13.67 -- 26.74 5.64 7.29 Specific Conductivity (µmhos/cm) Field -- -- -- 63.3 108.9 4376 187.4 206.7 -- 375.1 -- 527.2 665 68.7 ORP (mV) Field -- -- -- 223.6 274 -190.7 25.5 189.2 -- 163 -- 539.1 -95.7 243.2 Hardness as Ca and Mg (mg/L) EPA 200.7 -- -- -- -- -- -- -- -- -- -- -- -- -- -- Monitored Natural Attenuation Results Alkalinity, Total (µg/L) SM2320B -- -- 20000 -- -- -- 77000 -- 34000 166000 -- 106000 217000 35000 Biochemical oxygen demand (mg/L) SM5210B -- -- -- -- -- -- 2.0 U -- 2.0 U 2.0 U -- 2.0 U 4.0 2.0 U Chemical oxygen demand (mg/L) SM5220C -- -- -- -- -- -- 9.0 J 101 -- 16 J -- 16 J 22 J 9.0 J Chloride (mg/L) SW9056A 250 -- 250 -- -- -- 0.437 J -- 25.5 15.4 -- 54.1 72.0 0.37 U Nitrate as nitrogen (mg/L) SW9056A 10 -- 10 -- -- -- 0.076 U -- 0.624 H 4.93 H -- 25.8 0.076 U -- Sulfate (mg/L) SW9056 250 -- 250 -- -- -- 0.650 U -- 10.8 2.79 -- 94.9 0.65 U 0.65 U Sulfide (mg/L) SM4500S2F -- -- -- -- -- -- 0.830 U 0.830 U -- 0.830 U -- 17.3 0.83 U 0.83 U Total organic carbon (mg/L) SM5310B -- -- -- -- -- -- 0.902 J 1.02 -- 3.13 -- 2.29 3.12 0.684 J Lactic Acid (mg/L) AM23G -- -- -- -- -- -- 0.59 1.2 J -- 0.39 J -- 0.53 U 3.3 J 0.39 J Acetic acid (mg/L) AM23G 5000 -- -- -- -- -- 1.0 2.7 J -- 0.78 -- 2.6 J 2.1 J 2.9 Propionic Acid (mg/L) AM23G -- -- -- -- -- -- 0.18 J 1.2 J -- 0.094 J -- 0.53 J 1.1 J 0.15 J Formic acid (mg/L) AM23G -- -- -- -- -- -- 7.2 67 -- 6.1 -- 54 65 7.1 Butyric Acid (mg/L) AM23G -- -- -- -- -- -- 0.058 U 0.580 U -- 0.061 J -- 0.58 U 0.58 U 0.058 U Pyruvic Acid (mg/L) AM23G -- -- -- -- -- -- 0.060 U 0.60 U -- 0.060 U -- 0.60 U 0.60 U 0.060 U i-Pentanoic Acid (mg/L) AM23G -- -- -- -- -- -- 0.061 U 0.610 U -- 0.061 U -- 0.61 U 0.61 U 0.061 U Pentanoic Acid (mg/L) AM23G -- -- -- -- -- -- 0.056 U 0.560 U -- 0.056 U -- 0.56 U 0.56 U 0.056 U i-Hexanoic Acid (mg/L) AM23G -- -- -- -- -- -- 0.056 U 0.560 U -- 0.056 U -- 0.56 U 0.56 U 0.056 U Hexanoic Acid (mg/L) AM23G -- -- -- -- -- -- 0.059 J 0.58 U -- 0.13 J -- 0.58 U 0.58 U 0.058 U Methane (µg/L) AM20GAX -- -- -- -- 410 2.7 J -- 2.2 J -- 9.3 3600 2.7 J Ethane (µg/L) AM20GAX -- -- -- -- -- -- 0.17 U 0.19 J -- 0.17 U -- 0.29 J 1.3 J 0.17 U Ethene (µg/L) AM20GAX -- -- -- -- -- -- 0.24 U 0.25 J -- 0.24 U -- 0.24 U 1.2 J 0.24 U Carbon dioxide (µg/L) EPA RSK-175 -- -- -- -- -- -- 260000 30100 -- 51400 -- 257000 99200 141000 Ferrous iron (µg/L) SM3500FeB -- -- 1000 -- -- -- 8340 H -- 50.0 U H 50.0 U H -- 50.0 U H 23500 H 50.0 U H Hydrogen (nM) AM20GAX -- -- -- -- -- -- -- -- -- -- 0.49U 10 -- 100 Spring 2023 Semiannual Water Quality Monitoring Report Page 1 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Surface Water Samples QC Samples Location ID MW-06 MW-07 MW-07 SW-01 SW-02 SW-03 Field QC FieldQC FieIdQC FieIdQC MW-06- MW-07- MW-07- SW-01- SW-02- SW-03- SamplelD 20230328 20230327 20230328 20230323 20230323 20230323 DUP-20230327 TB-20230323 TB-20230327 TB-20230328 Sample Date 3/28/2023 3/27/2023 3/28/2023 3/23/2023 3/23/2023 3/23/2023 3/27/2023 3/23/2023 3/27/2023 3/28/2023 NC2L Method NC21- IMAC NC213 Conventional Parameters Water Level Depth (ft) Field -- -- -- - 31.92 31.95 -- -- -- -- -- Temperature (°C) Field -- -- -- -- 16.0 15.4 12.1 11.7 12.0 pH (SU) Field 6.5-8.5 -- 6.0-9.0 -- 6.0 6.1 7.1 6.9 7.0 -- -- Turbidity (NTU) Field -- -- <50 -- 3.64 7.98 6.04 12.0 5.57 -- -- Dissolved oxygen (mg/L) Field -- -- <6.0 -- 5.06 25.77 11.4 11.2 11.12 -- -- -- Specific Conductivity (µmhos/cm) Field -- -- -- -- 817 819 27.2 26.4 25.3 -- -- ORP (mV) Field -- -- -- -- 129.3 176.7 136 156.5 167.6 -- -- Hardness as Ca and Mg (mg/L) EPA 200.7 -- -- -- -- -- -- 8.32 9.00 8.20 -- -- Monitored Natural Attenuation Results Alkalinity, Total (µg/L) SM2320B -- -- 20000 -- -- 308000 -- -- -- 164000 -- Biochemical oxygen demand (mg/L) SM5210B -- -- -- -- -- 2.0 U -- -- -- 2.0 U -- Chemical oxygen demand (mg/L) SM5220C -- -- -- -- 12 J 2.0 U -- -- -- 22 J Chloride (mg/L) SW9056A 250 -- 250 -- -- 92.5 -- -- -- 15.0 -- Nitrate as nitrogen (mg/L) SW9056A 10 -- 10 0.076 U -- 0.076 U -- -- -- 4.87 H -- Sulfate (mg/L) SW9056 250 -- 250 -- -- 21.8 -- -- -- 2.70 -- Sulfide (mg/L) SM4500S2F -- -- -- -- 12.0 J -- -- -- -- 2.80 -- Total organic carbon (mg/L) SM5310B -- -- -- -- 3.29 -- -- -- -- 3.06 -- Lactic Acid (mg/L) AM23G -- -- -- -- 0.053 U -- -- -- -- 0.55 -- Acetic acid (mg/L) AM23G 5000 -- -- -- 0.52 -- -- -- -- 0.73 -- Propionic Acid (mg/L) AM23G -- -- -- -- 0.12 J -- -- -- -- 0.082 J Formic acid (mg/L) AM23G -- -- -- -- 5.3 -- -- -- -- 5.7 -- -- Butyric Acid (mg/L) AM23G -- -- -- -- 0.058 U -- -- -- -- 0.058 U Pyruvic Acid (mg/L) AM23G -- -- -- -- 0.21 J -- -- -- -- 0.060 U i-Pentanoic Acid (mg/L) AM23G -- -- -- -- 0.061 U -- -- -- -- 0.061 U -- -- Pentanoic Acid (mg/L) AM23G -- -- -- -- 0.056 U -- -- -- -- 0.056 U -- -- i-Hexanoic Acid (mg/L) AM23G -- -- -- -- 0.056 U -- -- -- -- 0.056 U -- - -- Hexanoic Acid (mg/L) AM23G -- -- -- -- 0.058 U -- -- -- -- 0.11 J -- -- Methane (µg/L) AM20GAX -- -- -- -- 570 -- -- -- -- 2.7 J -- -- Ethane (µg/L) AM20GAX 0.24 J -- -- -- - 0.17 U -- -- Et ene (µg/L) AM20GAX -- -- -- -- 0.25 J -- -- -- -- 0.24 U -- -- -- Carbon dioxide (µg/L) EPA RSK-175 -- -- -- -- 341000 -- -- -- -- 56300 -- -- -- Ferrous iron (µg/L) SM3500FeB -- -- 1000 -- -- 50.0 U H -- -- -- 50.0 U H -- -- -- Hydrogen (nM) AM20GAX -- -- -- -- 2.6 -- -- -- -- -- -- -- -- Spring 2023 Semiannual Water Quality Monitoring Report Page 2 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Location ID SamplelD Sample Date NC2L Method NC21- IMAC NC213 Domestic Well Samples Leachate Sample Monitoring Well Samples DW-01 DW-02 LT-01 MW-01 MW-02 MW-02 MW-03 MW-03 MW-04 MW-05R MW-06 DW-01- 20230328 DW-02- 20230328 LT-01-20230328 MW-01- 20230323 MW-02- 20230323 MW-02- 20230327 MW-03- 20230327 MW-03- 20230328 MW-04- 20230328 MW-0511- 20230323 MW-06- 20230322 3/28/2023 3/28/2023 3/28/2023 3/23/2023 3/23/2023 3/27/2023 3/27/2023 3/28/2023 3/28/2023 3/23/2023 3/22/2023 Appendix I Metals, Total (Ng/L) Antimony SW6020 1 -- 5.6 -- 6.18 U 0.618 U 0.618 U -- 0.618 U -- 0.618 U 0.618 U 0.618 U Arsenic SW6020 10 -- 10 -- 15.4 0.297 U 2.53 -- 0.453 J -- 0.388 J 6.76 0.297 U Barium SW6020 700 -- 1000 -- -- 1260 104 188 -- 104 -- 42.1 234 53.0 Beryllium SW6020 4 -- 6.5 -- -- 1.02 U 0.102 U 0.887 J -- 0.102 U -- 0.102 U 0.102 U 0.102 U Cadmium SW6020 2 -- *0.07 -- -- 3.50 U 0.810 J 0.350 U -- 0.350 U -- 0.350 U 0.350 U 0.350 U Calcium EPA 200.7 -- -- -- -- -- -- -- -- -- -- -- -- -- Chromium SW6020 10 -- *9.85 -- -- 20.3 0.346 U 41.7 0.968 J -- 0.346 U 4.84 0.346 U Cobalt SW6020 1 -- 1.6 -- -- 9.39 J 115 59.3 -- 3.97 -- 0.526 J 16.3 13.8 Copper SW6020 1000 -- *1.09 -- -- 8.50 J 2.91 34.9 -- 3.33 -- 0.952 J 8.39 1.31 Lead SW6020 15 -- *0.15 -- -- 3.03 J 0.307 J 9.21 -- 0.264 U -- 0.516 J 1.66 0.701 J Magnesium EPA 200.7 -- -- -- -- -- -- -- -- -- -- -- -- -- -- Mercury SW7470 1 -- 0.012 -- -- -- 0.130 U 0.130 U -- 0.130 U -- 0.130 U 0.130 U 0.130 U Nickel SW6020 100 -- *6.47 -- -- 34.3 16.4 31.8 -- 1.09 -- 2.10 5.96 5.32 Selenium SW6020 20 -- 5 -- -- 7.03 U 0.703 U 3.19 -- 0.703 U -- 0.703 U 0.703 U 0.703 U Silver SW6020 20 -- *0.05 -- -- 0.570 U 0.0570 U 0.0570 U -- 0.0570 U -- 0.0570 U 0.0570 U 0.0570 U Thallium SW6020 2 -- 2 -- -- 0.610 U 1.55 0.771 J -- 0.0610 U -- 0.0610 U 0.147 J 0.518 J Vanadium SW6020 7 -- -- -- I -- 1 26.5 J 0.767 U 52.5 -- 0.767 U -- 0.767 U 5.85 0.767 U Zinc SW6020 1000 -- *14.08 -- -- 46.7 U 60.5 160 -- 7.51 J -- 4.67 J 25.7 53.6 B Appendix I Metals, Dissolved (Ng/L) Antimony SW6020 1 -- 5.6 -- -- -- -- 0.618 U -- -- -- -- 0.618 U -- Arsenic SW6020 10 -- 10 -- -- -- -- 0.906 J -- -- -- -- 5.08 -- Barium SW6020 700 -- 1000 -- -- -- -- 160 -- -- -- -- 242 -- Beryllium SW6020 4 -- 6.5 -- -- -- -- 0.344 J -- -- -- -- 0.102 U -- Cadmium SW6020 2 -- *0.07 -- -- -- -- 0.350 U -- -- -- -- 0.350 U -- Chromium SW6020 10 -- *9.85 -- -- -- -- 22.9 -- -- -- -- 0.776 J -- Cobalt SW6020 1 -- 1.6 -- -- -- -- 51.0 -- -- -- -- 16.3 -- Copper SW6020 1000 -- *1.09 -- -- -- -- 19.4 -- -- -- -- 3.20 -- Lead SW6020 15 -- *0.16 -- -- -- -- 5.57 -- -- -- -- 1.22 -- Mercury SW7470 1 -- 0.012 -- -- -- -- 0.130 U -- -- -- -- 0.130 U -- Nickel SW6020 100 -- *6.47 -- -- -- -- 19.9 -- -- -- -- 3.62 -- Selenium SW6020 20 -- 5 -- -- -- -- 2.15 -- -- -- -- 0.703 U -- Silver SW6020 20 -- *0.05 -- -- -- -- 0.0570 U -- -- -- -- 0.0570 U -- Thallium SW6020 2 -- 2 -- -- -- -- 0.573 J -- -- -- -- 0.0638 J -- Vanadium SW6020 7 -- -- -- -- -- -- 29.0 -- -- -- -- 1.13 J -- Zinc SW6020 1000 -- *14.53 -- -- -- -- 173 -- -- -- -- 37.5 -- Spring 2023 Semiannual Water Quality Monitoring Report Page 3 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Location ID Sample ID Sample Date NC2L Method NC21- IMAC NC2B Surface Water Samples QC Samples MW-06 MW-07 MW-07 SW-01 SW-02 SW-03 Field QC FieldQC FieIdQC FieIdQC MW-06- 20230328 MW-07- 20230327 MW-07- 20230328 SW-01- 20230323 SW-02- 20230323 SW-03- 20230323 DUP-20230327 TB-20230323 TB-20230327 TB-20230328 3/28/2023 3/27/2023 3/28/2023 3/23/2023 3/23/2023 3/23/2023 3/27/2023 3/23/2023 3/27/2023 3/28/2023 Appendix I Metals, Total (Ng/L) Antimony SW6020 1 -- 5.6 -- 0.618 U -- 0.618 U 0.618 U 0.618 U 0.618 U -- -- Arsenic SW6020 10 -- 10 -- 3.42 -- 0.297 U 0.297 U 0.297 U 0.519 J -- -- Barium SW6020 700 -- 1000 -- 461 -- 12.4 13.5 13.5 103 -- -- Beryllium SW6020 4 -- 6.5 -- 0.102 U -- 1.00 U 1.00 U 0.102 U 0.102 U -- -- Cadmium SW6020 2 -- *0.07 -- 0.350 U -- 0.350 U 0.350 U 0.350 U 0.350 U -- -- Calcium EPA 200.7 -- -- -- -- -- -- 2110 2300 2060 -- Chromium SW6020 10 -- *9.85 -- 0.346 U -- 0.562 J 0.742 J 0.840 J 1.43 -- -- Cobalt SW6020 1 -- 1.6 2.70 -- 0.133 J 0.217 J 0.235 J 3.83 -- -- Copper SW6020 1000 -- *1.09 -- 0.759 J -- 0.660 J 0.862 J 0.860 J 3.42 -- -- Lead SW6020 15 -- *0.15 -- 0.264 U -- 0.264 U 0.264 U 0.285 J 0.264 U -- -- Magnesium EPA 200.7 -- -- -- -- -- -- 740 792 743 -- Mercury SW7470 1 -- 0.012 -- 0.130 U -- 0.130 U 0.130 U 0.130 U 0.130 U -- -- Nickel SW6020 100 -- *6.47 -- 8.69 -- 0.182 U 0.365 J 0.389 J 1.43 -- -- Selenium SW6020 20 -- 5 -- 0.703 U -- 0.703 U 0.703 U 0.703 U 0.703 U -- -- Silver SW6020 20 -- *0.05 -- 0.0570 U -- 0.0570 U 0.0570 U 0.0570 U 0.0570 U -- -- Thallium SW6020 2 -- 2 -- 0.0610 U -- 0.0610 U 0.0610 U 0.0610 U 0.0610 U -- -- Vanadium SW6020 7 -- -- -- 0.767 U -- 0.767 U 0.767 U 0.767 U 0.767 U -- -- Zinc SW6020 1000 -- *14.08 -- 103 -- 13.9 18.5 9.75 J 16.7 -- -- Appendix I Metals, Dissolved (Ng/L) Antimony SW6020 1 -- 5.6 -- -- -- -- -- -- -- -- -- -- Arsenic SW6020 10 -- 10 -- -- -- -- -- -- -- -- -- Barium SW6020 700 -- 1000 -- -- -- -- -- -- -- -- -- Beryllium SW6020 4 -- 6.5 -- -- -- -- -- -- -- -- -- Cadmium SW6020 2 -- *0.07 -- -- -- -- -- -- -- -- -- Chromium SW6020 10 -- *9.85 -- -- -- -- -- -- -- -- -- Cobalt SW6020 1 -- 1.6 -- -- -- -- -- -- -- -- -- Copper SW6020 1000 -- *1.09 -- -- -- -- -- -- -- -- -- Lead SW6020 15 -- *0.16 -- -- -- -- -- -- -- -- -- Mercury SW7470 1 -- 0.012 -- -- -- -- -- -- -- -- -- Nickel SW6020 100 -- *6.47 -- -- -- -- -- -- -- -- -- Selenium SW6020 20 -- 5 -- -- -- -- -- -- -- -- -- Silver SW6020 20 -- *0.05 -- -- -- -- -- -- -- -- -- Thallium SW6020 2 -- 2 -- -- -- -- -- -- -- -- -- Vanadium SW6020 7 -- -- -- -- -- -- -- -- -- -- -- Zinc SW6020 1000 -- *14.53 -- -- -- -- -- -- -- -- -- Spring 2023 Semiannual Water Quality Monitoring Report Page 4 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Location ID SamplelD Sample Date NC2L Method NC2L IMAC NC213 Domestic Well Samples Leachate Sample Monitoring Well Samples DW-01 DW-02 LT-01 MW-01 MW-02 MW-02 MW-03 MW-03 MW-04 MW-05R MW-06 DW-01- 20230328 DW-02- 20230328 LT-01-20230328 MW-01- 20230323 MW-02- 20230323 MW-02- 20230327 MW-03- 20230327 MW-03- 20230328 MW-04- 20230328 MW-0511- 20230323 MW-06- 20230322 3/28/2023 3/28/2023 3/28/2023 3/23/2023 3/23/2023 3/27/2023 3/27/2023 3/28/2023 3/28/2023 3/23/2023 3/22/2023 Appendix I Volatile Organic Compounds (VOCs) and 1,4-Dioxane (Ng/L) 1,1,1,2-Tetrachloroethane SW8260D 1 -- -- -- -- 0.11 U 1.60 U 0.160 U -- 0.160 U -- 0.160 U 0.160 U 0.160 U 1,1,1-Trichloroethane SW8260D 200 -- -- 0.27 U 0.27 U 0.061 U 1.60 U 0.160 U -- 0.160 U -- 0.160 U 0.160 U 0.160 U 1,1,2,2-Tetrachloroethane SW8260D 0.2 -- 0.17 -- -- 0.036 U 1.60 U 0.160 U -- 0.160 U -- 0.160 U 0.160 U 0.160 U 1,1,2-Trichloroethane SW8260D 0.6 -- 0.55 0.28 U 0.28 U 0.066 U 0.960 U 0.096 U -- 0.096 U -- 0.096 U 0.096 U 0.096 U 1,1-Dichloroethane SW8260D 6 -- 6 0.29 U 0.29 U 0.083 U 2.40 U 0.244 J -- 0.240 U -- 0.240 U 0.240 U 0.801 1,2-Dichloroethene, cis- SW8260D 70 -- 60 0.33 U 0.33 U 2.16 J 2.00 U 0.200 U -- 0.380 J -- 0.471 J 3.94 0.499 J 1,4-Dioxane SW8260DSIM 3 -- 0.35 -- -- 48.7 0.139 U 1.79 J -- 0.139 U -- 5.04 6.18 0.139 U Acetone SW8260D 6000 -- 2000 -- -- 18.0 U 18.0 U 1.80 U -- 2.43 J -- 1.80 U 1.80 U 1.80 U Benzene SW8260D 1 -- 1.19 0.40 U 0.40 U 1.80 U 1.80 U 0.180 U -- 0.180 U -- 0.180 U 1.58 0.180 U Chlorobenzene SW8260D 50 -- 140 0.26 U 0.26 U 1.90 U 1.90 U 0.190 U -- 0.190 U -- 0.190 U 7.57 0.190 U Chloroethane SW8260D 3000 -- -- -- -- 4.30 U 4.30 U 0.430 U -- 0.430 U -- 0.430 U 0.430 U 0.430 U Chloroform SW8260D 70 -- 60 -- -- 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.220 U 0.220 U Chloromethane SW8260D 3 -- 2.6 -- -- 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.220 U 0.220 U Dibromochloromethane SW8260D 0.4 -- 21 -- -- 0.081 U 5.00 U 0.500 U -- 0.500 U -- 0.500 U 0.500 U 0.500 U Dibromomethane SW8260D -- 70 -- -- -- 2.30 U 2.30 U 0.230 U -- 0.230 U -- 0.230 U 0.230 U 0.230 U Dichlorodifluoromethane SW8260D 1000 -- -- -- -- 12.0 U 12.0 U 1.20 U -- 1.20 U -- 1.20 U 1.20 U 1.20 U Dichloromethane (Methylene chloride) SW8260D 5 -- 20 0.44 U 0.44 U 3.30 U 3.30 U 0.330 U -- 0.330 U -- 0.330 U 0.330 U 0.330 U Diisopropylether (Isopropyl Ether) SW8260D 70 -- -- -- -- 9.60 U 9.60 U 0.960 U -- 0.960 U -- 9.60 U 0.960 U 0.960 U Ethylbenzene SW8260D 600 -- 97 0.23 U 0.23 U 1.70 U 1.70 U 0.170 U -- 0.170 U -- 0.170 U 0.170 U 0.170 U Ethylene dibromide (1,2-Dibromoethane) SW8260D 0.02 -- 0.02 -- -- 2.00 U 2.00 U 0.200 U -- 0.200 U -- 0.200 U 0.200 U 0.200 U m,p-Xylene SW8260D 500 -- 420 -- -- 4.20 U 4.20 U 0.420 U -- 0.420 U -- 0.420 U 0.420 U 0.420 U Methyl ethyl ketone (2-Butanone) SW8260D 4000 -- 20000 -- -- 7.10 U 7.10 U 0.710 U -- 0.710 U -- 0.710 U 0.710 U 0.710 U o-Xylene SW8260D 500 -- 600 -- -- 2.10 U 2.10 U 0.210 U -- 0.210 U -- 0.210 U 0.210 U 0.210 U Styrene SW8260D 70 -- -- 0.20 U 0.20 U 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.220 U 0.220 U Tetrachloroethene (PCE) SW8260D 0.7 -- 0.7 0.26 U 0.26 U 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.220 U 0.220 U Tetrahydrofuran SW8260D -- 2000 3100 -- -- 95.7 J 15.0 U 1.50 U -- 1.50 U -- 1.50 U 1.50 U 1.50 U Toluene SW8260D 600 -- 11 0.28 U 0.28 U 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.220 U 0.220 U Total Xylene SW8260D 500 -- 670 0.11 U 0.11 U 2.1 U 2.1 U 0.21 U -- 0.21 U -- 0.21 U 0.21 U 0.21 U Trichloroethene (TCE) SW8260D 3 -- 2.5 0.26 U 0.26 U 1.80 U 1.80 U 0.180 U -- 0.288 J -- 0.180 U 0.180 U 0.180 U Trichlorofluoromethane (Fluorotrichloromeft SW8260D 2000 -- 9100 -- -- 1.80 U 1.80 U 0.180 U -- 0.180 U -- 0.180 U 0.180 U 0.180 U Vinyl acetate SW8260D -- 88 -- -- -- 10.0 U 10.0 U 1.00 U -- 1.00 U -- 1.00 U 1.00 U 1.00 U Vinyl chloride SW8260D 0.03 -- 0.025 0.12 U 0.12 U 1.70 U 1.70 U 0.170 U -- 0.170 U -- 0.210 J 0.684 0.170 U 1,2-Dichlorobenzene SW8260D 20 -- 470 0.26 U 0.26 U 2.20 U 2.20 U 0.220 U -- 0.220 U -- 0.220 U 0.280 J 0.220 U 1,4-Dichlorobenzene SW8260D 6 -- 488 0.30 U 0.30 U 2.34 J 5.79 0.210 U -- 0.210 U -- 1.94 8.57 1.07 �] Spring 2023 Semiannual Water Quality Monitoring Report Page 5 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary Location ID SamplelD Sample Date NC2L Method NC21- IMAC NC213 Surface Water Samples QC Samples MW-06 MW-07 MW-07 SW-01 SW-02 SW-03 Field QC FieldQC FieIdQC FieIdQC MW-06- 20230328 MW-07- 20230327 MW-07- 20230328 SW-01- 20230323 SW-02- 20230323 SW-03- 20230323 DUP-20230327 TB-20230323 TB-20230327 TB-20230328 3/28/2023 3/27/2023 3/28/2023 3/23/2023 3/23/2023 3/23/2023 3/27/2023 3/23/2023 3/27/2023 3/28/2023 Appendix I Volatile Organic Compounds (VOCs) and 1,4-Dioxane (Ng/L) 1,1,1,2-Tetrachloroethane SW8260D 1 -- -- -- 0.160 U -- 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 1,1,1-Trichloroethane SW8260D 200 -- -- -- 0.160 U -- 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 1,1,2,2-Tetrachloroethane SW8260D 0.2 -- 0.17 -- 0.160 U -- 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 0.160 U 1,1,2-Trichloroethane SW8260D 0.6 -- 0.55 -- 0.096 U -- 0.096 U 0.096 U 0.096 U 0.096 U 0.096 U 0.096 U 0.096 U 1,1-Dichloroethane SW8260D 6 -- 6 -- 0.240 U -- 0.240 U 0.240 U 0.240 U 0.240 U 0.240 U 0.240 U 0.240 U 1,2-Dichloroethene, cis- SW8260D 70 -- 60 -- 1.75 -- 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 1,4-Dioxane SW8260DSIM 3 -- 0.35 -- 15.8 -- 0.139 U 0.139 U 0.139 U 0.139 U 0.139 U 0.139 U 0.139 U Acetone SW8260D 6000 -- 2000 -- 7.71 -- 10.2 1.80 U 1.80 U 2.24 J 1.80 U 1.80 U 1.80 U Benzene SW8260D 1 -- 1.19 -- 1.59 -- 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U Chlorobenzene SW8260D 50 -- 140 -- 4.78 -- 0.190 U 0.190 U 0.190 U 0.190 U 0.190 U 0.190 U 0.190 U Chloroethane SW8260D 3000 -- -- -- 0.430 U -- 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U 0.430 U Chloroform SW8260D 70 -- 60 -- 0.220 U -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U Chloromethane SW8260D 3 -- 2.6 -- 0.220 U -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U Dibromochloromethane SW8260D 0.4 -- 21 -- 0.081 U -- 0.081 U 0.081 U 0.081 U 0.081 U 0.081 U 0.081 U 0.081 U Dibromomethane SW8260D -- 70 -- -- 0.230 U -- 0.230 U 0.230 U 0.230 U 0.230 U 0.230 U 0.230 U 0.230 U Dichlorodifluoromethane SW8260D 1000 -- -- -- 1.20 U -- 1.20 U 1.20 U 1.20 U 1.20 U 1.20 U 1.20 U 1.20 U Dichloromethane (Methylene chloride) SW8260D 5 -- 20 -- 0.330 U -- 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U 0.330 U Diisopropylether (Isopropyl Ether) SW8260D 70 -- -- -- 0.960 U -- 0.960 U 0.960 U 0.960 U 0.960 U 0.960 U 0.960 U 0.960 U Ethylbenzene SW8260D 600 -- 97 -- 0.170 U -- 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U Ethylene dibromide (1,2-Dibromoethane) SW8260D 0.02 -- 0.02 -- 0.200 U -- 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U m,p-Xylene SW8260D 500 -- 420 -- 0.420 U -- 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U 0.420 U Methyl ethyl ketone (2-Butanone) SW8260D 4000 -- 20000 -- 0.710 U -- 0.710 U 0.710 U 0.710 U 0.710 U 0.710 U 0.710 U 0.710 U o-Xylene SW8260D 500 -- 600 -- 0.210 U -- 0.210 U 0.210 U 0.210 U 0.210 U 0.210 U 0.210 U 0.210 U Styrene SW8260D 70 -- -- -- 0.220 U -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U Tetrachloroethene (PCE) SW8260D 0.7 -- 0.7 -- 0.220 U -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U Tetrahydrofuran SW8260D -- 2000 3100 -- 2.40 J -- 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U 1.50 U Toluene SW8260D 600 -- 11 -- 0.220 U -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U Total Xylene SW8260D 500 -- 670 -- 0.21 U -- 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Trichloroethene (TCE) SW8260D 3 -- 2.5 -- 0.180 U -- 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U Trichlorofluoromethane (Fluorotrichloromeft SW8260D 2000 -- 9100 -- 0.180 U -- 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U 0.180 U Vinyl acetate SW8260D -- 88 -- -- 1.00 U -- 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U Vinyl chloride SW8260D 0.03 -- 0.025 -- 0.170 U -- 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 0.170 U 1,2-Dichlorobenzene SW8260D 20 -- 470 -- 0.346 J -- 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 0.220 U 1,4-Dichlorobenzene SW8260D 6 -- 488 -- 6.20 -- 0.210 U 0.210 U 0.210 U 0.226 J 0.210 U 0.210 U 0.210 U Spring 2023 Semiannual Water Quality Monitoring Report Page 6 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 3 Analytical Summary N otes: 'Detected concentration is greater than NC2L or NC2L IMAC standard Detected concentration is greater than NC26 standard Bold: Detected result Italicized: Non -detected concentration is above one or more identified NC2L standard *: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, NC213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. All nondetect results are reported at the method detection limit. Appendix I: per 40 Code of Federal Regulations Part 258 Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (US Survey Feet). --: not sampled °C: degrees Celsius N pg/L: micrograms per liter pmhos/cm: micromhos per centimeter ft:feet GW: groundwater IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. J: Estimated value mg/L: milligrams per liter mv: millivolts N: normal environmental sample NTU: nephelometric turbidity unit ORP: oxidation-reduction potential SU: standard unit SW: surface water TB: Trip Blank U: Compound analyzed for, but not detected above minimum detection limit WG: groundwater sample WQ: water quality H: Analyzed out of hold time due to laboratory error Spring 2021 Semiannual Water Quality Monitoring Report Page 7 of 7 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Sample Dates Detected VOCs Concen- tration in LT-01 (mg/L) Cumulative Flow at Gauge (gal) Differential Flow (gal) Mass Removed (lb) Estimated Cumulative Mass Removed (lb) Beginning Ending 9/1/2012 10/25/2012 1,4-dichlorobenzene 0.0034 11,500 J J J J 11,500 0.00033 4-meth I-2- entanone (MIBK) 0.0021 0.00020 Acetone 0.0292 0.00280 Benzene 0.0021 0.00020 Chlorobenzene 0.0029 0.00028 cis- 1,2-dichloroethene 0.00063 0.00006 Dichlorodifluoro-methane 0.00093 0.00009 Eth (benzene 0.0102 0.00098 Naphthalene 0.0069 0.00066 Styrene 0.00033 0.00003 Toluene 10.003 0.00029 Total x lenes 0.0094H 0.00090 Total: 0.00681 0.00681 10/26/2012 4/11/2013 1,4-dichlorobenzene 0.006 65,500 J J J J J 54,000 0.00270 Acetone 0.012 0.00540 Benzene 0.0011 0.00049 Carbon disulfide 0.0067 0.00301 Chlorobenzene 0.0024 0.00108 cis- 1,2-dichloroethene 0.00058 0.00026 Eth (benzene 0.0083 0.00373 Toluene 0.00059 0.00027 Total x lenes 0.0078 0.00351 Total: 0.02045 0.02726 4/12/2013 10/8/2013 1,4-dichlorobenzene 0.0055 114,737 J J 49,237 0.00226 4-meth I-2- entanone (MIBK) 0.0012 0.00049 Benzene 0.0020 0.00082 Chlorobenzene 0.0039 0.00160 cis- 1,2-dichloroethene 0.00080 0.00033 Eth (benzene 0.0151 0.00619 Naphthalene 0.0184 0.00754 Toluene 0.0012 0.00049 Total x lenes 0.0090 0.00369 Total: 0.02341 0.05067 10/9/2013 4/8/2014' 1,4-dichlorobenzene 0.0056 164,437 J J J 49,700 0.00232 Benzene 0.0018 0.00075 Chlorobenzene 0.0051 0.00211 cis- 1,2-dichloroethene 0.00049 0.00020 Eth (benzene 0.0047 0.00195 Toluene 10.00041 0.00017 Total x lenes 0.0021 0.00087 Total: 0.00836 0.05903 4/8/2014 10/23/20141 1,4-dichlorobenzene 0.0053 200,148 J J J 35,710 0.00158 Benzene 0.0014 0.00042 Chlorobenzene 0.003 0.00089 cis- 1,2-dichloroethene 0.00049 0.00015 Eth (benzene 0.0027 0.00080 Toluene 10.00051 0.00015 Total x lenes 10.0014 0.00042 Total: 0.00440 0.06343 10/23/2014 4/21/2015 1,2,3-trimethyl benzene 0.00062 241,700 J J 41,552 0.0002 1,2,4-trimethyl benzene 0.00076 0.00026 2-chlorotoluene 0.00067 0.00023 1,4-dichlorobenzene 0.0059 Acetone 0.00790 Benzene 0.0022 0.00076 Chlorobenzene 0.003 0.00 04 Eth (benzene 0.0056 000794 Isopropyl benzene 0.0013 0.00045 Methy tert-but I -ether 0.0013 0.00045 Na thalene 0.024 n-propylbenzene 0.00088 0.00030 Tetrah drofuran 0.089 .03080 Toluene 0.00054 0.000 9 Vin I chloride 10.00038 Total x lenes 10.0030 0.00 04 Total: 0.05089 0.11432 4/21/2015 10/13/2015 1,4-dichlorobenzene 0.00600 278,420 J J J 36,720 0.00183 2-butanone 0.00960 0.00294 Benzene 0.00210 0.00064 Chlorobenzene 0.0040 0.00122 Eth (benzene 0.00710 0.00217 Naphthalene 0.021 0.00642 Tetrah drofuran 0.062 0.01896 Toluene 0.00058 0.00018 Total x lenes 0.0031 0.00095 Total: 0.03531 0.14963 10/13/2015 4/5/2016 1,4-dichlorobenzene 0.00590 337,398 J 58,978 0.00290 Benzene 0.00170 0.00083 Chlorobenzene 0.0038 0.00187 Eth (benzene 0.00500 0.00246 Toluene 0.00063 0.00031 Total x lenes 10.0025 IJI 0.00123 Total: 0.00959 0.15922 Spring 2023 Semiannual Water Quality Monitoring Report Page 1 of 3 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Sample Dates Detected VOCs Concen- tration in LT-01 (mg/L) Cumulative Flow at Gauge (gal) Differential Flow (gal) Mass Removed (lb) Estimated Cumulative Mass Removed (lb) Beginning Ending 4/5/2016 10/11/2016Z No detected compounds 352,745 15,347 0.00000 Total: 0.00000 0.15922 10/11/2016 3/21/2017 1,4-dichlorobenzene 0.0046 355,947 3,202 0.00012 Acetone 0.0094 J HJ 0.00025 Benzene 0.0015 0.00004 Chlorobenzene 0.0043 0.00011 Eth (benzene 0.0014 0.00004 Tetrah drofuran 10.066 0.00176 Total x lenes 10.0015 0.00004 Total: 0.00237 0.16159 3/21/2017 10/11/2017 1,4-dichlorobenzene 0.0041 386,495 30,548 0.00104 Acetone 0.0067 J J 0.00770 Acetonitrile 0.008 0.00204 Benzene 0.00061 0.00016 Chlorobenzene 0.0012 0.0003 Eth (benzene 10.00087 0.00022 Na hthalene 10.0012 0.0003 Tetrah drofuran 10.12 0.03053 Total: 0.03630 0.19789 10/12/2017 10/18/2018' 1,4-dichlorobenzene 0.0028 398,872 12,377 0.00029 Acetone 0.017 J J 0.00175 Benzene 0.0012 0.00012 Chlorobenzene 0.0024 0.00025 Eth (benzene 0.0018 0.00019 Methylene chloride 10.00034 1 10.00098 1 0.00004 Total x lenes 0.00010 Total: 0.0027 0.20062 10/18/2018 10/22/2019' 1,4-dichlorobenzene 0.0037 407,807 8,936 0.00028 Acetone 0.006 0.00045 Benzene 0.0017 0.00013 Chlorobenzene 0.0038 0.00028 Eth (benzene 0.0016 0.00012 Toluene 10.00039 NJ 0.00003 Total x lenes 0.0017 0.00013 Total: 0.0014 0.20203 10/22/2019 3/18/2020' 1,4-dichlorobenzene 0.0056 539,644 131,836 0.00615 1,4-dioxane 0.06 J J 0.06585 Acetone 0.0064 0.00702 Benzene 0.0013 0.00143 Chlorobenzene 0.0032 0.00351 Eth (benzene 0.0027 0.00296 Methyl isobut I ketone 0.00079 0.00087 Toluene 0.00070 0.00077 Total x lenes 0.00209 0.00229 Total: 0.0886 0.29058 3/18/2020 10/14/2020' 1,2-dichloroethene, cis- 0.00029 J 639,343 99,699 0.00024 1,3-dichlorobenzene 0.00027 J J J J 0.00022 1,4-dichlorobenzene 0.0048 0.00398 1,4-dioxane 0.058 0.04814 Acetone 0.011 0.00913 Acetonitri e (et anenitn e) 0.0047 0.00390 Benzene 0.0024 0.00199 Chlorobenzene 0.0044 0.00365 Chloroethane 0.00047 0.00039 Eth (benzene 0.0018 0.00149 Naphthalene 0.013 0.01079 Tetrah drofuran 0.094 0.07802 Toluene 0.00079 0.00066 Total x lenes 0.0037 0.00307 Vin I chloride 10.00022 0.00018 Total: 0.1659 0.45645 10/14/20204 10/20/2021 1,4-dichlorobenzene 0.00385 701,994 62,651 0.0020 1,4-dioxane 0.0488 0.02546 Acetone 0.008 4 0.00425 Benzene 0.00245 0.00128 Chlorobenzene 0.00428 0.002 Eth (benzene 0.000838 0.00044 Naphthalene 0.0 360.00710 Tetrah drofuran 0.203 5 Total x lenes 0.0028 47 Total: 0.1501 0.60659 10/20/2021 3/7/2022 1,4-dichlorobenzene 0.00168 710,029 8,035 1,4-dioxane 0. 06 Acetone 00064Benzene P0.022155 000 48 Chlorobenzene 0004 8 Tetrah drofuran 0. 68 Total: 0.0585 0.66508 Spring 2023 Semiannual Water Quality Monitoring Report Page 2 of 3 Jackson County Closed Municipal Solid Waste Landfill September 2023 Table 4 Mass Removal Calculations for VOCs Detected in the Leachate Sample (LT-01) Sample Dates Detected VOCs Concen- tration in LT-01 (mg/L) Cumulative Flow at Gauge (gal) Differential Flow (gal) Mass Removed (lb) Estimated Cumulative Mass Removed (Ib) Beginning Ending 3/7/2022 10/4/2022 1,4-dioxane 0.08 734,436 24,407 0.01626 Benzene 0.000568 C oro enzene 0.00 39 -777077- Tetra hyd rofu ra n 0.0678 0.01378 4-Methyl-2-pentanone 0.00112 0.00023 Carbon disulfide 0.000683 0.00014 Ethylbenzene 0.000267 0.00005 Methyl ethyl ketone 0.00236 0.00048 Naphthalene 0.00366 0.00074 o-xylene 0.000465 0.00009 Toluene 0.00024 0.00005 Total xylene 0.000465 0.00009 1,4-dichlorobenzene 0.00182 0.00037 Total: 0.0327 0.69777 10/4/2022 3/28/2023 1,4-dioxane 0.0487 765,240 30,804 0.0 1249 2-Dic oroet ene, cis- 55 Tetra y ro uran 0. 57 0.02455 1,4-dichlorobenzene 0.00 4 0.00060 Total: 0.0382 1 0.73597 Notes: Total xylenes represent the sum of m,p-xylenes and o-xylenes. Only detected VOCs in leachate sample LT-01 are included in the mass removal calculation. Leachate extraction at the landfill was initiated on September 1, 2012. Connection to the TWSA sewer was completed on September 6, 2013. Up until the connection to the TWSA sewer, leachate was pumped into a temporary collection tank and then hauled off site. Extraction volume measurements for leachate hauled off site were recorded and Provided by Jackson County staff. Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next sampling event occurs and that the leachate removal system has a 100% removal and treatment efficiency. Differential flow represents the total flow between the LT-01 sample dates. Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the concentration 1. Totalizer readings were not recorded during the sampling event, and the differential flow was calculated based on an interpolated totalizer reading using monthly readings taken by TWSA for 3 months before and after the sample date. 2. No VOCs were detected in the leachate sample collected during the October 2016 sampling event. 3. In March 2018, the totalizer at the TWSA connection was replaced. During the March 2018 sampling event, Anchor QEA began reading an incorrect totalizer for the volume of extracted the leachate. Differential flow was calculated for the sample dates in the same manner as Note 1. This table has been updated to reflect the updated totalizer readings from previous groundwater monitoring reports. 4. Totalizer buried during March 2021 monitoring event, due to on -Site construction. Therefore a totalizer reading was not obtained. gal: gallon J: indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit lb: pound mg/L: milligrams per liter TWSA: Tuckaseigee Water and Sewer Authority VOC: volatile organic compound Spring 2023 Semiannual Water Quality Monitoring Report Page 3 of 3 Jackson County Closed Municipal Solid Waste Landfill September 2023 Figures r ` i r a 1 lull �.� LEGEND: SOURCES: 1. BasemaU.S. Geological Survey Topographic ® Site Parcel Boundary Maps - Gree ens Creek and Whittier 7.5-minute Quadrangles 0 2. Parcel. Jackson County GIS 0 2,000 Feet Publish Date: 2022/04/22, 3:58 PM I User: kpressleybernal Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2022\Spring WQWQFig01_JacksonCounty_SpringWQ2022_Sitel-ocationMap.nnxcl ANCHOR Figure 1 QEA�`'`� Site Location Map Anchor QEA of North Carolina, PLLC Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill LEGEND: DW-02 Saprolite Monitoring Well ® PWR Monitoring Well ® Bedrock Monitoring Well Domestic Well Sampling Location Leachate Sample Location and Flow Equalization Tank ® Surface Water Sample Location + Leachate/Landfill Gas Extraction Well Compliance Boundary SW-02 F� • • • Edge of Waste a — Stream Q Property Boundary MW-06 — Road ® MW-01 DW 01 — Elevation Contour (20-Foot Interval) woo ` EW-7 ` EW-5 MW-02 1 EW-3111 ® ` EW 1R. v` EW-9�� ••�� EW-2R ••' ` EW-10 ♦� ,` ZQ Rio �pQ� � ZZ MW-03 ; • '• LT-01 NOTES: O • SW-03 ® EW-4 1.Contours, roads, and parcel boundaries are • from Jackson County GIS. /rPc�i •.•• i 2. Monitoring well locations are approximate. 012 ` '•, 3. Basemap provided by Esri. ` 4. PWR: Partially Weathered Rock �6 -A MW-OSR100, , MW-07 (N MW-04 � I Publish Date: 2022/06/01, 2:56 PM I User: kpressleybernal Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2022\Spring WQ\AQ_Fig02_JacksonCounty_SpringWQ2022_SampleLocationMap.mxd kZANCHOR QEA Anchor QEA of North Carolina, PLLC SW-01 L - �pOO y0 APR 0 300 Feet Figure 2 Site Layout Map Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill 2120 CONNOR WILKEY MW-06 DSO,)® MW-01 • 20 (2;063.84) 60. �♦ �,, �.,••�� WILKEY '. ' • 0S ♦ ♦ . : 40� (i11972.13) ♦♦ ♦♦ ♦ �L ♦� ♦ 1q, 07 :• ♦ ` ♦ 20 C9. p ' . •. , as 8 ♦ ♦ C S•01 '. MW-05111/ (1,981.45) M W -07 ,, ♦�020 (1,94\9.37,) SO , ~�9 MW-04_ Publish Date: 2023/07/27, 1:45 PM I User: alesueur Filepath: \\orcas\gis\Jobs\JacksonCounty_NC_1480\Maps\JacksonCoLF_SemiAnnualReports\JacksonCoLF_SemiAnnualReports.aprx 0 N LEGEND: ® Saprolite Monitoring Well PWR Monitoring Well Bedrock Monitoring Well Generalized Groundwater Elevation �y Contour (10-Foot Interval) �F< Leachate Sample Location and Flow Equalization Tank 110 .... Edge of Waste 0 Stream 0 Property Boundary Road WILKEY Elevation Contour (20-Foot Interval) NOTES: 1. Contours, roads, and parcel boundaries are from Jackson County GIS. 2. Monitoring well locations are approximate. 3. Groundwater elevations and flow direction 2220 are updated on a semiannual basis every April and October following the sample collection events. 4. Groundwater flow direction is based on groundwater elevations in feet in monitoring wells MW-01, MW-02, MW-03, MW-04, MW-05R, and MW-06. Direction is calculated based on depth to water measured on March 27 and 28, 2023. 5. Last names of property owners are shown in parcels that border the landfill property. 6. GW: Groundwater 7. PWR: Partially Weathered Rock 0 0 00 0 200 N o Feet kZANCHOR Figure 3 QEA Generalized Groundwater Flow Direction Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill 5 4 �3 c O 1 0 14 12 10 c o g c 6 c 0 U 4 2 0 Tetrachloroethene (PCE) 2079 2077 2075 c 2073 .M > w 2071 2069 -0 O -- - -- - - ------ I 2065 2063 Date 2079 2077 2075 2073 .M > LU 2071 3 2069 -0 D O 2067 0 2065 2063 2��$2�1�2�1T2�1�26\,o �2d"i2)ITTQT� Date Benzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:23 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py ANCHOR QEA 6 5 J 4 >s c O 3 c v U 2 1 0 20.0 17.5 15.0 _� 12.5 10.0 12 rZ 7.5 0 U 5.0 2.5 0.0 Trichloroethene (TCE) 2079 2077 2075 c 2073 M > w 2071 � 3 2069 _0 n O 4111FAM r� I 2065 2063 22S\I) S\IT�1N2�1�01$2QT�2�TT2�T Date 2079 2077 2075 2073 LU 2071 3 2069 -0 Z) O 0111FAM 2065 2063 200 6\1)2�1T2�1�2�1601$2QT�2�TT 2�T� Date 1,4-Dichlorobenzene 102 a 101 c 0 — 12 v 100 c O U 10-1 20. 17. 15. c 12. 0 10. v 0 7. U 5. 2. 0. cis-1,2-Dichloroethene 2Qp$2Q1,) S\'L �1b' "'10 �1�2�T1,1) 2�T� Date Date 1,4-Dioxane 2079 101 2077 2075_ � o J 2073.; � 100 0 w O 2071 �, a � 3 c 0 2069 -0 c O 0 U 2067 0 10-1 2065 2063 )79 )77 )75 )73 m )71 3 )69 -0 O )67 )65 Vinyl Chloride 2079 2077 2075 c 2073 o > 0 w 2071 2069 O NIBITAW 2065 2063 2QP,6 6"" S\l Q)1RT ,\,0 )N-- pai) QTTTpTN Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 4 Hydrograph and Constituents of Concern Versus Time - MW-01 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll Tetrachloroethene (PCE) 5 4 M c 2 c O U 1 0 1990 1988 1986 1984 1982 .g 1980 w 1978 Y 1976 1974 O 1972 1970 1968 1966 $ c O 3 c v o 2 U 1 0 ' 1990 Zu.0 14 ' 1988 17.5 12 1986 1984 15.0 10 1982 .o � 12.5 1980 a r- O 8 I ai o 1978 � 10.0 0 6 'U 1976 o 1 1974 0 7.5 0 U , O U 4 1972 5.0 1970 2 --------------• 1968 2.5 0 1966 0.0 Trichloroethene (TCE) Date 1990 1 1988 1986 1984 v 1982 � .o � 1 Y 1980 w o 1978 Y 12 1976 Y v 1 1974 0 0 O U 1972 1970 1968 1c 1966 1990 1 1988 1986 1984 � J 1982 .o Y 1980 > 1 w o 1978 Y Y 1976 U 1974 0 0 O U 1972 10 1970 1968 1966 S\I- A , 2�1�2�2�2�222�2� 1990 1990 1988 20.0 1988 1986 17.5 1986 1984 v 1984 v 1982 0 � 15.0 1982 .g 1980 > c 12.5 1980 W o ' W 1978 1978 °Y' Y 10.0 a 1976 3 v 1976 1974 0 7.5 1974 O U I O 1972 1972 5.0 1970 1970 1968 2•5 - -� 1968 1966 0.0 1966 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� 1,o2�1$2�2�2�222�2� 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:23 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA i 1990 1988 1986 I 1984 V I I I 1982 � o •Y i 1980 1978 w 1976 1974 0 1972 O 1970 1968 ------------T----------------------- 1966 S122�1�2�1,o -No �2�2Q2Ll- � Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) — Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 5 Hydrograph and Constituents of Concern Versus Time - MW-02 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c 0 M c 2 c 0 v X 14 12 10 c 0 8 M c 0 6 c 0 V 4 2 0 Tetrachloroethene (PCE) 2009 2007 2005 2003 0 2001 > Q) w 1999 iv 1997 1995 0 6 1993 1991 .;. 6 5 J 4 >s c 0 3 c v rZ Vo 2 it Trichloroethene (TCE) 2009 102 2007 2005 2003 0 101 2001 w 0 1999 12 1997 10° 1995 0 1993 1991 10-1 1989 cis-1,2-Dichloroethene 2�1�2�1�2�211) 2�2� 2���2�1�2�122�1�2�1�2�1$2�2�2�222�2� 2��82�1�2�1I- \" � ,'o \,)2�2" o"2 �2� Date Date Date 20.0 2009 2007 17.5 2005 15.0 2003 0 M 12.5 2001 > o 1999 a 10.0 1997 � c c 7.5 1995 0 0 v �9 5.0 1993 1991 2.5 1989 0.0 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� 162�1$2�2�2�222�2� Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:23 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 2009 20 2007 2005 17 2003 0 15 2001 > c 12 w � 1999 10 1997 3: c 0 7 1995 0 U � 5 1993 1991 2 1989 0 2009 101 2007 2005 2003 0 2001 > 10° w 0 1999 iv � 1997 c c 1995 0 v 10-1 1993 1991 1989 2009 2007 2005 2003 0 2001 1999 1997 c 1995 0 1993 1991 1989 Date 1,4-Dioxane Vinyl Chloride 2009 2007 2005 2003 0 2001 w 1999 1997 1995 0 6 1993 1991 .;. 2Q000 16x" o",2�2� Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 6 Hydrograph and Constituents of Concern Versus Time - MW-03 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c O M c 2 c O U 1 4 14 12 10 c O 8 M c 0 6 c O U 4 2 0 Tetrachloroethene (PCE) I I I I I I I I I I I cuu• u• c• 1958 6 5 1956 v O \ J 4 o 1954 3 3: 0 qj � 0 U V o 2 0 U 1952 (D 1 1950 0 Trichloroethene (TCE) 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� 2���2�1�2�122�1�2�1�2�1$2�2�2�222�2� Date Date 1958 20.0 17.5 1956_ 15.0 � o 2 J \ 0) 12.5 0 1954 � 10.0 nz c U 7.5 O 0 U 1952 5.0 2.5 1950 0.0 1958 102 1956 v 101 0 \ 1954 � 12 3 100 C C 0 O 0 1952 V 10-1 1950 cis-1,2-Dichloroethene i 1 1 1 1 1 1 I 2Q0$2S1I2S\I- \A2�162�1�2�2�2�222�2� 1958 101 1956 v � O J \ > 100 1954 0 � C 7 U 0 0 O 1952 0 U 10-1 1950 1958 , 20.0 1956 17.5 1956 1 o 15.0 g 1954 Q c 12.5 a>> w 0 w 1954 fu 10.0 M 3: c v 7.5 o U 1952 0 1952 (� 5.0 1 1 2.5 1 1 1950 0.0 1950 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� 162�1$2�2�2�222�2� 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:24 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA Vinyl Chloride 1958 1956 C 0 1954 C 0 1952 (D I I I I I I ----------- ---------------- 1950 Q�1,3 S\Q- CNN '\102�1O2�2�2�22262I, Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 7 Hydrograph and Constituents of Concern Versus Time - MW-04 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll J a c O c U c O U 5 1989 1987 4wa��� 1985 0 •2 3 1983 w 2 1981 0 l7 1 1979 1977 0 2201'�)162ON"�2Q2LL � 2��$2ON" Date 14 12 10 c O 8 M c 6 c O U 4 2 0 6 1989 1 5 1987 4 i 1985 v 0 .2 1 2 0 if 3 ---------- ------ -- 1983 — � v 1 2 1981 n 0 O 1 1979 1c 1977 0 Date 1989 ZU.0 17.5 1987 15.0 1985 g .2 0) 12.5 0 1983 - � 10.0 � c 1981 c o 7.5 O U 5.0 1979 2.5 1977 0.0 1989 20.0 1987 17.5 1985 0 15.0 iv c 12.5 1983 10.0 3 v 1981 0 7.5 O 5.0 1979 2.5 1977 0.0 1989 1 1987 1985 g � � 1 w O 1983 U � C 1981 � v 0 1c 1979 1977 S\I- A , 2�1�2�2�2�222�2� 1II 200 162�1$2�2�2�222�2� 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:24 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 87 85 c O 83 w 79 i 1989 1987 1985 .2 0 1983 i 1981 O 1979 1977 S\I- \II1,0 NCO, �2Q2l- Q2� Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) — Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 8 Hydrograph and Constituents of Concern Versus Time - MW-05R Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll 5 4 �3 c O M 0 14 12 10 c 0 8 M c 6 c 0 V 4 2 0 Tetrachloroethene (PCE) I I I I I I I I 1 1 I 1 I 1 I - - ------ --------------- I I $ 2�1� 2�122�1 2�1 Date Date Benzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet 2066 WOM 2062 2060 c 0 2058 2056 "' iv 2054 2052 = O 2050 6 2048 2046 Trichloroethene (TCE) 6 I I 5 J 4 >s 1 0 Date 2066 20.0 2064 17.5 2062 15.0 2060 J o 12.5 2058 o 2056 w � 10.0 iv 2054 U 7.5 2052 0 v 2050 �9 5.0 2048 2.5 2046 0.0 Publish Date: 09/11/2023 11:24 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 2Q00231I32;),\1 \R161$�112'31, Q2� Date 1,4-Dichlorobenzene 2066 102 2064 2062 2060 J 101 o 2058 0 °— 2056 LU 2054 100 -6 2052 0 V c 0 2050 2048 10-1 2046 cis-1,2-Dichloroethene ------- i----------- 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 S\I- \A161,)2�2�2�222�2� 2066 , 2064 20.0 2062 17.5 ' 1 2060 15.0 o 2058 a', c 12.5 2056 10.0 2054 3 1 2052 0 0 7.5 2050 5.0 2048 2.5 -- ---- - 2046 0.0 Date 1,4-Dioxane 2066 101 2064 2062 Y 2060 J O 2058 10° °— 2056 "' 2054 2052 0 U C v 2050 10-1 2048 2046 64 62 60 58 56 54 52 O 50 48 46 Vinyl Chloride I i\\/II -------------------- I I I I I 2���2�1�2�122�1�2�162�1�2�2�2�222�2� Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TICE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date 2066 2064 2062 Y 2060 0 2058 Q) 2056 2054 2052 0 2050 2048 2046 Figure 9 Hydrograph and Constituents of Concern Versus Time - MW-06 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll Tetrachloroethene (PCE) 5 4 �3 c O M c 2 c O U 1 19S4 1952 0 w 1950 C O 0 I `CQDPCD ME; " µ 1948 $ Date 14 12 10 c O 8 M c 6 c O U 4 2 0 LD Trichloroethene (TCE) 6 5 J 4 c 0 3 c v o 2 U 1 0 1954 20.0 17.5 15.0 1952 0 .2 0) 12.5 w o � 10.0 1950 u o 7.5 O U 5.0 2.5 1948 0.0 102 1952 0 1 10 2 w 0 0 3 100 1950 � o O U 6 10-1 1948 Date 1954 20.0 17.5 1952 0 15.0 > c 12.5 w .0 10.0 3 v 1950 0 7.5 O U 5.0 2.5 1948 0.0 cis-1,2-Dichloroethene 1954 101 1952 0 > 10° tv w C o 3 U 1950 C u o O U 0 10-1 1948 Date 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� 200 162�1$2�2�2�222�2� 2��$2�1�2�122�1�2�1�2�1�2�2�2�222�2� Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction. 3. Non -detects are plotted as an open symbol at the method detection limit. 4. Data presented are from semiannual sampling events from 2007 to Spring 2023. µg/L: micrograms per liter ft: feet Publish Date: 09/11/2023 11:24 AM I User: SAR-SCOL File Path: \\Wcl-fs1\asheville\Projects\Jackson County\02-Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA w 1950 (" IM 1948 Vinyl Chloride 1954 1952 0 w 1950 C O ----- 1948 �)162Ci1co,�)xl) Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) -- Leachate Extraction Start Date Figure 10 Hydrograph and Constituents of Concern Versus Time - MW-07 Spring 2023 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landifll Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets ANCHOR .�, QEA ` Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log well ID: MW-01 Project Name: Jackson County Landfill Date: • '4t > r � (]�j�23 123 Project Number: C21480-01.01 Weather. g '. ',UA 4, I C la� Project Location: D'lllsborro,, NC Facility ID or Permit 4 (if applicable): S0.02 Sample Collector(s):-Iim 1 C9_ Sample ID (on COC): MW-01-toti3cTS23, Well Diameter. 2 in Sample Time: 10 : 140 0-j fi3 t?,3 j Screen Interval: N/A ft bgs Measuring Point: TOC Well Depth (WD): 110.5 ft TOC Well Type: xStick Up ❑flush Mount o,-+ � 5 Water Level in Feet (WL): TOC Comments: 1 —j _ft 1 Length of Water Column (LWC): 5 . i 1 ft; (WD - WL) wA yr> I One Casing Volume: (� , [ }(p gallons; (LWC x WCV) ®n INA 112i 1 �,S Three Casing Volumes: gallons -torhaVIRA0 Actual Volume Purged: gallons Tagged Bottom: Inobt— ft at (time): w r Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft P7= 0.16 Gal/Ft 3" = 0.37 Gal/Pt 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity report to 0.1 Potential Turbidity Reading Time Purged VQ (mg/L) (pmhos/cm) S.U. (m1) (NTU) Comments 1 i01.% ---- iS Z I. 9 1 i 6.2 2 J" IS j 5 2 2. 1 5 2, v4 3 .3 4 : 25 l -W 2.3 r— 71) 5 % ! I S - 2.2© S- 2... 6 %?>S I 7 IS2 r + S 2-a$ S+O 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: i/ Pad: -�J_ Loclic= Vegetation: Access: _X yt0.a �b'c Ayu C,[- CLCC2,.%j Sample Analysts sample Signature:0. P-4w Analysts mott.. Date: t O�l�-3 L e Name: J� Notes: d 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity,, +/- 0.1 pH unit +/- 70 mV (orORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staffmembers initials and dater t t n (l L4C 3. Samples are analyzed immediately upon collection. J 4. NC Field Laboratory Certificate Number 5445 Abbreviations: l °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units ft: feet in: inches bgs: below ground surface TOC: top of casing _^ 5 Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 0 G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log Well ID: MW-02 Project Name: Jackson County Landfill Date: 0�1/27. 1Z3 Project Number. C21480-01.01 Weather. 60 8 " Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50.02 ILI Sample Collector(s): �1 c Sample ID (on COC): MW-02- 7 p p Well Diameter. 2 in Sample Time: Screen Interval: N/A ft bgs Measuring Point: TOC Well Depth (WD): f0,7 ft TOC Well Type: t6tick U ❑Flush Mount Water Level in Feet p (WILY � ft TOC ��yp Comments: W L 7 �T %X_A bz3 it OLly!30 �.tj • Length of Water Column (LWQ: ft; (WD - WL) bh C;34 Z. i rZA One Casing Volume: gallons; (LWC x WCV) 8au U.ck 2 } c!w Three Casing Volumes: gallons Actual Volume Purged: gallons,� 2 IS Tagged Bottom: �ft at (time): �'� "• '(7 5 Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity report to 0.1 Potential Turbidity Reading Time Purged CQ (mg/L) (pmhos/cm) S.U. (mv) (NTU) Comments .� 2 i I i� . i I clU6 i 3 S 1` yr 5 5�° a • S `.00 t 6 t S• c7 .•} & •-0 6 lYv� FO 7 1 �i 8 0� �L�Ttsu 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Q, + Other Protective Casing: Pad: Lock: Vegetation: Access: Sample Analysts Sample Signature: Analysts Name: ]Q SS I' C'C� Date: 0-b 123 i'Z-j Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,, +/- 3% Conductivity; +/- 0.1 pH unit' +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 �4_A "'` / Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log well ID: MW-03 Project Name: Jackson County Landfill Project Number. C21480-01.01 Project Location: Dillsboro, NC Sample Collector(s):.__�g? 1 t _ Well Diameter. 2 Screen Interval: 48.5-63.5 Well Depth (as constructed):_ 65.5 Depth to Water. L� 1'20 Measuring Point TOC Depth of Pump Intake: 5o _ Pump Used (circle): Peristaltic Bladder Comments: �.l.i'vj f Date: C�b (12-. ITA Weather. '• 3' t 5_V,-V .� c.tU �. r� Facility ID or Permit * (if applicable): SO-02 Sample ID (on COC): MW-03-��- in Arrive at Well: If bgs Start Time: I �� ft bgs Sample Time: ft Leave Well: Well Type: xStick Up oFlush Mount ft Tagged Bottom: ft at (time): Other (describe): Purge Rate: �� 00 L m 'r„ L Total Volume Purged: Pump Speed: ❑ ;,U; re-_ _ Time DTW (feet) Temperature ('Q Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potenrtiial (mV) Turbidity (NTU) �0-4 - V 1 y C 1 1 o L 0 .Q 3C7 . ca H 5 '-15 4 Sample Analyst Signature: Sample Analyst Name: ICE Date: ,.Z-} .Z . Notes.• 9 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity; +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017: 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 S. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: 'C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2016 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOO top of casing Turbidity: SM 2130 B-2011 Ir 1 JOSS' ell( S Sa.v1fPJ 03, Page 1 of 1 ANCHOR Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log iWelf ID: MW-04 Project Name: Jackson County Landfill Project Number. C21480-01.01 Project Location: Millsboro, NC Sample Collector(s): lam Well Diameter: 2 Screen Interval: 25- 40 Well Depth (as constructed): Depth to Water: © Measuring Point:TOC Depth of Pump Intake: 35 Pump Used (circle): Peristaltic Bladder Comments: t, n 1 �l7vL` �� Date: Z3 Weather. J`-,rcGt, Facility ID or Permit # (if applicable): 50-02 Sample ID (on COC): MW-04- in Arrive at Well: ; ft bgs Start Time: ft bgs Sample Time: bJ ft Leave Well: Well Type: )[Stick Up ❑Flush Mount ft Tagged Bottom: - 4q ft at (time): S : 'i Other (describe): Purge Rate: L fMi Total Volume Purged: Pump Speed: Time DTW (feet) Temperature (°C) Dissolved O (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) 15 "7I°r 1 2 2 5, �S .3 ,# S l �5- so 51-2- --B3 r S 25. 55 �-0 2 2r. 5 2,1 a s 9 5 l l Sample Analyst Signature: i Sample Analyst Name: s L Date. - Notes: r 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit; +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017: 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 VS/cm Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1962 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2016 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 A'SC)q" (din Dt Page") of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Well Sampling Log iWell ID: MW-OSR Project Name: Jackson County Landfill Date: O f Z Project Number. C21480-01.01 Weather. Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50.02 Sample Collector(s): �1f �; ��� ram` Sample ID (on COC): _ MW-05R-Lty2.7� 2 Well Diameter. 2 in Sample Time: ' Z L S1 Screen Interval: N/A ft bgs Measuring Point TOC Well Depth (WD): 54 ft TOC Well Type: NStick Up oFlush Mount Water Level in Feet (WL): • 9 ., S ft TOC 0312-1 I2'3 Comments: ��]� y� A1,� ` s�- Length of Water Column (LWC):©I} ft; (WD - WL) t �'Q�. �Q� %2.1 �� One Casing Volume: 9 gallons; (LWC x WCV) i -- i v\. (q&) Three Casing Volumes: gallons i I ° Y� Actual Volume Purged: gallons Tagged Bottom: ft at (time): 1i5 ; Three Casing Volumes: gallons Well Casing Volumes (WCV) V' = 0.04 Gal/Ft 2" = 0.16 GaVFt 3" = 0.37 Gal/Ft 4" = 0.65 GaVFt . 6" = 1.47 GaVFt 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer-Disp. Bailer -Teflon Dedicated Pump Bailer -Teflon . Dedicated Pump Whale Pump Grundfos Whale Pump Grundfos Other. Other. Sample Method: Oxidation Dissolved Specific pH (S.U.) Reduction Gallons Temperature Oxygen Conductivity reportto 0.7 Potential Turbidity Reading Time Purged VQ (mg/L) (pmhos/cm) S.U. (mV) (NTU) Comments Z - 1 - l `t 2 2 i 2r.. .� . 2. �� 3 _9 3 3 4 5 , 5� .`L 4:::d ' 5 a 2 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: Pad: Lock: Vegetation: Access: Sample Analysts Sample Signature: Analysts Name: \ (Q. Date: -2 notes: .7 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% conductivity,- +/- 0.1 pH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: `C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L milligrams per liter in: inches DO: SM 4500 O G-2011 mV: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity. SM 2130 B-2011 Page 1 of 1 ANCHOR usI 1�.�� C�1 vv � ,� i , s�� Anchor QEA of North Carolina, PLLC tsz Q� 231 Haywood Street .� .cam Asheville, North Carolina 28861 Low -Flow Sampling Log well ID: MW-06 Project Name: Jackson County Landfill _ Date: () 6! , j 123 Project Number. C21480-01.01 Weather. 41 e YGL� rC�: Project. Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 ss�� Sample Collector(s): t C Sample ID (on CDC): MW-06- -_Tt Cr� Well Diameter. 2 in Arrive at Well: Screen Interval: 84-94 ft bgs Start Time: p' Well Depth (as constructed): 94 ft bgs 'Sample Time: 1 L Depth to Water. . 00 ft Leave Well: Measuring Point TOC Well Type: 3 Stick Up ❑Flush Mount Depth of Pump Intake: 91 ft Tagged Bottom: 17110ft at (time): 0 Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: (, M ih Comments: +kk Me p.^ Total Volume Purged: IOCA P� 1 Do : t30 �r : 3J1��, S�O�L �s s Pump Speed: ' `25 r- Time DTW (feet) Temperature (*Q Dissolved Oxygen (mg/L) Specific I Conductivity (Nmhos/cm) pH (S-U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Go "I 2 - . . 2,4 2.. - S . 3 t q iZ .-j_ z qq t 6- Z . � `l L � Z3Lf • 1 2.5-+ : I . o a.. S-S? '2WT -A t 1 l "i S • S Sample Analyst Signature: Sample Analyst Name: es i�ca IYt u-��= s Date: OAj 22�" _3 Notes 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,, +/- 3% Conductivity,, +/- 0.7 pH unit,' +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017: - 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 umho/cm = 1 uS/cm Abbreviations: Method Reference: T S 2 -5 °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L; milligrams per liter in: inches DO: SM 4500 O G-2016 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 br^ IrC-rk �t f�"V-\p -\�,A_AA pr Page 1 of 1 ANCHOR Q1:.1"i a..�� c..c-1ci Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log lWell ID: MW-07 Project Name: Jackson County Landfill Date: 031 Project Number. C21480-01.01 Weather. rF i -&"hyyk1 C %: Project Location: Dlllsbof o, NC Facility ID or Permit # (if applicable): 50-02 11 Sample Collector(s):�� Sample ID (on COC): MW-07- Well Diameter. 2 in Arrive at Well: :a-, Screen Interval: 70 - 95 ft bgs Start Time: I ., tit( Well Depth (as constructed): 95 ft bgs Sample Time:: Depth to Water. , q ft Leave Well: Measuring Point: TOC Well Type., xStick Up ❑Flush Mount Depth of Pump Intake: 85 ft Tagged Bottom: ft at (time):;�� Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: L ' Comments: ��yy' L n Total Volume Purged: �►0]rU G 1 { `: +T� _ _ Pump Speed: D 2Z i , Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) � 3 i S 65 1i -5 to '2- 'Z . t .0 IS.q 2 51q •" 1 Z u �S, q S,q •p„ � 1 2(c 2O 2 S 1 s - .. 2 =:10 t b-o 4; r r6i fi q ; -6 `z D . D S 4 0`3 Ci b bil- �. q i'Z Sample Analyst Signature: Sample Analyst Name: 5S1 �� Date: 03 bj 1 Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity,- +/- 0.1 pH uniZ7 +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017: 2. Documentation errors are to be crossed out with a single line. so the original text is still legible, followed by the staff member's initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2016 mV: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 * Cv u, t ek (lam{' SA,,VV Pke-, �-O,( PC -)On e Y, I �,Dql W.2;, 1 a ­ %eb C / c Page 1 of 1 Anchor QEA of North Carolina, PLLC 231 Haywood Street ANCHOR .� QEA Asheville, North Carolina 28801 Well Sampling Log IWO ID: ' 04 Project Name�1 JS 50 V\ Co. j a&y,,A ;" { { Date: 051� of 1Z3 Project Number: Weather. � C, Project Location: Facility ID or Permit # (if applicable): 50--02 Sample Collector(s): r C Sample ID (on COC): y(\�—(�—��2� Well Diameter: Z in Sample Time: Screen Interval: CJ S ft bgs Measuring Point: — �� Well Depth (WD): �' ft TOC Well Type: "Stick Up ❑Flush Mount Water Level in Feet (WL):q ft TOC Comments: f&A in,_ D : 2 Q 'V-7 t 20 Length of Water Column (LWQ: ft; (WD - WL) One Casing Volume: gallons; (LWC x WCV) 4 V Three Casing Volumes: gallons 1' 42 8�r� Actual Volume Purged: gallons v Tagged Bottom: ft at (time): Three Casing Volumes: gallons Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: si l w Oxidation ssolved Specific pH (S.U.) Reduction GatlOms Temperature Oxygen Conductivity reportto 0.7 Potential Turbidity Reading Time P Wd CQ (mg/L) (pmhos/cm) S.U. (mV) (NTU) Comments 1 L4 `2— o p t (o . . 2 2 2 Z. i Q 2' O S c9 20 s �d -4 3 32-2p 15� L5•i I • oq 1r35. Z0 4 I 51 -0S (o-O 1 9-S q� 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: Pad: Lock: Vegetation: Access: Sample Analysts Sample Signature: U A�t Analysts Name: _ Date:C0. Date: 0 3 P7j 123 Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. ,per ;`^^ VA � F° , ` t i , n 4. NC Field Laboratory Certificate Number 5445 �l(,�' �C. it CSL1 ON`^'4 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U: standard units ft: feet in: inches bgs: below ground surface TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 0 G-2011 pH: SM 4500-H` B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR OEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Sampling Log - Grab Location ID: LT-01 Project Name: Jackson County Landfill Date: 2;3 Project Number. C21480-01.01 Weather, o Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): SO-02 Sample Collector(s):� L'� Sample ID (on COC): LT-01 -?vZj o32 Comments: Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other. Dissolved, Specific Oxidation Temperature Oxyg Conductivity pH (S.U.) Reduction Turbidity Time CC) (mg/L (Nmhos/cm) report to 0, f S.U. Potential (m1) (NTU) , 00'(�- Comments -i qC) Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: Sample Analyst Sample Analyst Signature Name: S' Cc` m Date: notes: 1. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 0 G-2011 PH:SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR � QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Sampling Log - Grab Location ID: DW-01 Project Name. Jackson County Landfill Date: Project Number. C21480-01.01 Weather. S r Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): r L Q Sample ID (on COC): DW-01- Comments: Purged 30 gallons prior to sampling. Wilkey residence. Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other. Dissolved Specific Oxidation Temperature Oxygen ` Conductivity pH (S.U.) Reduction Turbidity Time VC) (mg/L) (/pmhos/ccm) reportto 0.1 S.U. Potential (m1) (NTU) Comments i+ Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 3 1 L Glass Other Vegetation: Access: Sample Analyst Sample Analyst Signature: Name: �-e Ssl ��Date: Z 1. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: 'C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Sampling Log - Grab Location ID: DW-02 Project Name: Project Number. Project Location: Sample Collector(s): Comments: Jackson County Landfill Date: 12 C21480-01.01 Weather: Dlllsboro, INC Facility ID or Permit # (if applicable): 50-02 0-92, Sample ID (on COC): DW-02- From spigot on house at Kim's property. Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other. Time Temperature (°C) Dissolved Oxygen . , (mg/L) ,, Specific Conductivity (pmhos/cm) pH (S.U.) reportto 0.7 S.U. Oxidation Reduction Potential (MV) Turbidity (NTU) Comments T 2- I r i 9 Sampling Container Number of Containers Requested Analysis 500 mL Plastic ca \r ( CIS 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Sample Analyst Signature. Sample Analyst Name: Access: Notes: d 1. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Date: cZZ�E�Z Page 1 of 1 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SW-01 Project Name: Jackson County Landfill Project Number: C21480-01.01 Project Location: Dillsboro, NC Sample Collector(s): ji(�{1 j Comments: Upstream of landfill Date: Weather'. Facility ID or Permit # (if applicable): Sample ID (on COC): C6 1 Z ° YIVI 50-02 SW-01- p20323 Sample Method (circle one) Grab Syringe Pump Bailer-Disp. Other: Time Temperature VQ Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.15.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments Sampling Container Number of Containers Requested Analysis 500 mL Plastic C — 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: Sample Analyst Sample Analyst Signature: t Name: Date: 2 Notes: 1. Documentation errors are to be crossed out with a single line, so the orioinal text is still leoible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L milligrams per liter DO: SM 4500 0 G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbidity: SM 2130 B-2011 S.U.: standard units Page 1 of 1 ANCHOR QEAw Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SW-02 Project Name: Jackson County Landfill Date: b3 2Zv .LZ Project Number: C21480-01.01 Weather: 3 w C:IO Project Location: Dillsboro, NC Facility ID or Permit* (if applicable): 50-02 Sample Collector(s):,13Lno c Sample ID (on COC): SW-02- a Comments: Downstream of landfill Sample Method (circle one): Grab Syringe Pump Bailer-Disp. Other: Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VC) Oxygen (mg/L) (Nmhos/cm) report to 0.1 S.U. Potential (mV) (NTU) Comments .en i o-y-, VAW%XA 4::E> Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: `V(f(r1y Access: v Sample Analyst Sample Analyst Signature: Name: SS iI� , Date: ob Z L3 Notes: 1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: 'C: degrees Celsius Temperature: SM 2550 B-2010 Nmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbiditv: SM 2130 B-2011 S.U.: standard units Page 1 of 1 4 ANCHOR QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SW-03 Project Name: Jackson County Landfill Date: ro Project Number: C21480-01.01 Weather:' . D u l Project Location: Dillsboro, NC Facility ID or Permit # (if applicable): 50-02 Sample Collector(s): (� ` C.� Sample ID (on COQ SW-03- 2O7- u-j Comments: Mid -stream of landfill Sample Method (circle one): = Syringe Pump Bailer-Disp. Other: Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VC) Oxygen (mg/L) (pmhos/cm) report to 0.1 S.U. Potential (m1) (NTU) Comments �� y l Z •0 11 C� 2 5 3V62_ .b Jo .5- Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: Sample Analyst Sample Analyst Signature: Name: 7�55� Lg (Y1tAuPX Date: 05123123 Notes: 1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L• milligrams per liter DO: SM 4500 O G-2011 mV: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbiditv: SM 2130 B-2011 S.U.: standard units Page 1 of 1 ANCHOR 4.09.1-9.rr 1,,zQTAd6Po4�v11r ui ment Documentation and Instrument Calibration Data Sheet Project Name: Jackson COun(}' Landfill Analyst Conducting Calibration: • (jr �>lur; t Project Number. C21480-01.01 Date of Calibration:_ _0 4 Project Location: Dillsboro, NC Date of Field Measurements: 17,3 Facility ID or Permit # (if applicable): 50-02 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Com any Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Select Turbidimeter. Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n } Instrument Readings 10 NTU Ift -L.I M O (Hach 20 NTU Ait2,$ 0 A 12 Cal (NTU): ' Qi 21000) 100 NTU 2 i Z 3 Cal (NTU): � (, 800 NTU 1 l0 I Cal (NTU): +QL Cal Std Information Lot #: Expiration Date: 'Pre -Analysis Time:O �`— Result (NT Time: uvzo Time: Time: ci- 2 Calibration Verification: Check (10 NTU): .Post -Analysis Result (NTU): Time: Check (10 NTU): YSI Professional Plus Multiparameter Meter (s/n 10101802) Cal Std Information Instrument Readings Date Lot a Opened Exp. Date Dissolved Oxygen Initial (%): Cal (%): b�/• mmHg: -i+[ —I �Ij Temperature CQ: -- Time: (% saturation) 1 tl- 1 . ..SL DO (Site #2, Initial (%): Cal (%): mmHg: Temperature CC): Time: if a livable)" QC** Check DO Time: Result (%): Time: Result (%): rime: Result (%): PH 7 S.U. report to 0.7 S.U. Initial: �"•O� pHmV: (• '... t Cal (S.U.): . 0 pHmV: "' �' • Time: U G! V S 1) �' +[ 123 pH 4 S.U. Initial: pHmV: Cal (S.U.): r� pHmV: I� i Time: 1 y� A01�2 report to 0.7 S.U. ,IV . (� V 3 tp • U 2 4 01123 pH 10 S.U. report to0.7S.U. Initial: (7ao 1 pHmV: •-?�S. Cal (S.U.): I� .� 1 pHmV: -ws. �� Ti n ems, V-t't {p s►i �i! �`i2 o�IL�J QC** pH 7 S.U. Time: oiy Result (S.U.): y A- Time: Result (S.U.): Time: Result (S.U.):(2� 10 011,24 report to 0.7 S.U. r" • 0- i Spec. Cond. Initial: Cal (Nmhos/cm): 77e: 1,000yimhos/cm �L q 2 1.000 O65q (4S % Recovery= QC** Spec. Cond. Time: Result (Nmhos/cm): Time: Result (Nmhos/cm): Time: Result (Nmhos/cm): &o 1,000 umhos/cm v`-�r - 2-S q J() t I• 08127- C4123 % Recovery= ORP 200 mV Initial: tqq. Cal: tad Temperature CC): l�.3 Time: U+�-'�„ 61 y�o t,l(23 b3t'k3 Analyst Signature: �%r Analyst ';S" CO. m�PXS Date: ��1Z Notes: �J Revision 8, 1/11/2?, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual 2. Speck Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows : Specific Conductivity, pH 7, PH 4, PH 10, DO, ORP, QC checks. 4- *When performing DO analyses at multiple sample sites (i.e. projecVfacility locations), the DO probe must be calibrated at each sample site prior to analysis. 5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. " QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot 4 as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 Pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 •C: degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011 mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Equipment Documentation and Instrument Calibration Data Sheet Project Name: _Jackson County Landfill Analyst Conducting Calibration:�aAA Project Number. C21480-01.01 Date of Calibration: (}� 12.2.1 Z'a y Project Location: Dillsboro, NC Date of Field Measurements: Facility ID or Permit # (if applicable): 50-02 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: EquipmentType Brand Serial Number Date of Use Rental Company Select Turbidimeter.® Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n Instrument Readings (Hach 2100Q) Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU Lot#: f}Z 22. n-J-1 21 3 Fit to Expiration Date: Cal (NTU): �� Cal (NTU.1`0 Cal (NTU): &M Time: Q 0 53 c7 TimeO S S �J Time: Q` �cy Calibration Verification: 'Pre -Analysis Check (10 NTU): Result (NTU): a. D Time: / 1FJ Sri *Post -Analysis Check (10 NTU): Result (NTU): q • ��/ Time: �� �� YSI Professional Plus Multiparameter Meter (s/n 188101802) Instrument Readings Cal Std Information Lot# Date Opened Exp. Date Dissolved Oxygen (% satumdon) Initial (%): q L4, Cal (%): too— mmHg: ', Temperature CC): , 2- Time: 0 q 31 DO (Site #2, if a livable)* Initial (%): Cal (%): mmHg: Temperature CC): Time: QC** Check: DO Time: �( f t Result (%): Time: Result (%): Time: Result (%): PH 7 S.U. report to0.7S.U..� Initial: r�pHmV•:�l1 ''D�1• Cal (S.U.): `I."'�+r01 pHmV•: G7l•Q Time:* �t CJ`OL�GF 7y I0l2L 1 ��Z3 PH 4 S.U. report to 0. 7 S.U. Initial: . O 9 pHml:2 � Cal (S.U.):O� jj�„,�� pHmV: C� 2-. (Q Time: O LLID _ VuLiq tot i..Z 69 (2%J PH 10 S.U. report to0.7S.U. Initial: Q' pHmV: —2D6.(Q Cal �(S.U.): to.,C7 pHmV�:1 e-20a•0 Time�::CC�� / (� Vsr/ � 1 I ea 5((0 Q ( 0Vt21 �p VI`23 QC*. pH 7 S.U. reorttoaiSU.113, Time: Result (S.U.): S Time: Result (S.U.): Time: Result (S.U.):►p ` W(9 10(22 01 4 Spec. Cond. 1,000pmhos/cm Initial: 100 Cal (pm os/cm): L oO 6 Time: 0(O3 11 122 6812,3. % Recovery= QC** Spec. Cond. 1,000 pmhos/cm Time: �` 3g Result (pmhos/cm): ( t ab Time: Result (pmhos/cm): Time: Result (pmhos/cm): 2 CAp U4 68 la 6417,3 % Recovery= ORP 200 mV Initial: ( It[ta .1.4 Cal: g� DIDVt Temper ure CC): Time: 1410 2 01f ZJ OV&.91 Analyst Signature: Analyst Name: esv CA. Date. oz 1 Notes: Revision 6, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, PH 7, PH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. S. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial Qc. 7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number S445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 *C: degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev, 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011 mg/L• milligrams per liter S.U: standard units pH: SM 4500-H* B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1of1 1Z ANCHOR ta.r.K..+sr Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Eciuioment Documentation and Instrument Calibration Data Sheet Project Name: Jackson County Landfill _ Analyst Conducting Calibration: �� Project Number: C21480-01.01 Date of Calibration: 27� f9-'A Project Location: Dillsboro, NC Date of Field Measurements: (+�Z f ] S 123 Facility ID or Permit # (if applicable): 50-02 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: EquipmentType Brand Serial Number Date of Use Rental Company Select Turbidimeter. Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n Instrument Readings (Hach 21000) Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU Lot #-. 'L L L 25 110 Expiration Date: 0 f5 019 113 Cal (NTU): Cal (NTU)- q Cal (NTU): Time: Time: C> )�0 tp>Time: VD Calibration Verification: *Pre -Analysis I Check (10 NTU): Result (NTU): , M Time:!, V � l7 - (fig t A *Post -Analysis Check (10 NTU): Result (NTUyy. O 0.1 . Time: -.o` p V y, 6 p YSI Professional Plus Multiparameter Meter (s/n 186101802) Instrument Readings Cal Std Information Lot # Date Opened Date Dissolved Oxygen (% saturation) Initial (%): �� . 2 Cal (%): ' 0 `f mmHg: >� Temperature CQ: la • Time: a 9 2 DO (Site #2, if a licable)* Initial (%): Cal (%): mmHg: Temperature CQ: Time: QC** Check: DO Time: LO 1-0 903• Result (%): Time: Result (%): Time: Result (%): PH 7 S.U. report to0.1 S.U. Initial: Q - -{ pHmV: _1 Cal (S.L1 fir♦ -0k pHmV: —� Q • Time: r 0 -:Zi to > �E(�� b6 2. PH 4 S.U. reportto 0.1 S.U. Initial: pHmV: Cal (S.U.): 4.00 pHmV: Time:' b^- 7, 1 6%I 0 PH 10 S.U. report to 0.1 S.U. Initial4: ,q pHmV:•7 _ L Cal (S.U.): 1 Q� pHmV: •�' Time: D TT 4 riL1 05ta QC** pH 7 S.U. r •ortto 0.15.U. Time: 1 Li T �� Result (S.U.): 4.0 ID Time: � a5 �I Result S.U.). ,o Time: Result (S.U.): 2Ldt A l'zZ. Qt 12 Spec. Cond. 1,000 pmhos/cm Initial: r, /_ 0 " v (0 Cal (pmhos/cm): 10 00 Time: 6 `•' (0u za S �� % Recovery= QC** Spec. Cond. 1,000 pmhos/cm Time: l� 0 ` Result (pmmhhooss/cm): � t ( Time: c ^� J T Result (pmhos/cm): Ci g 6 Time: Result (pmhos/cm): 2 D Am I q 9 3tu 1 l�i % Recovery= ORP 200 mV Initial: xm.O Cal: ?gyp Temperature ('C): ` Time: O_ 10 Analyst Signature: Analyst Name: 1 CC,_ rS Date: 123 12 Notes: Revision 8, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, PH 7, PH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. S. QC Acceptable Ranges: PH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. - QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm . True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 'C degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 45000 G-2011 mg/L: milligrams per liter S.U.: standard units pH: SM 450o-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1 of 1 1l,zANCHOR c1c A q ..r..+r_0W Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 ui ment Documentation and Instrument Calibration Data Sheet Project Name: S�l[.1�blsrt �n�[ C(y �'I Analyst Conducting Calibration: Project Number: 1�� (� —Qk, Date of Calibration: 0-6 12} ( Z 73 r Project Location: YV I f\it Date of Field Measurements: Facility ID or Permit # (if applicable): 50—OIL tQUII'MINI LIOGUMINTATION Rental sample analvsis eauioment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company Select Turbidimeter. Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n Instrument Readings 10 NTU Wz 0 ig J'J,_JO (Hach 20 NTU Cal (NTU): 0,0 21000) 100 NTU Pak%- O Cal (NTU): 800 NTU 10 l 2 Cal (NTU) Cal Std Information Lot # Expiration Da *Pre -Analysis Time: ram/ ( Result NTU): Time&,, Ti �! Time: Yo Calibration Verification: Check (10 NTU): *Post -Analysis Check (10 NTU): Result NTU): 4 D 3 7� Time: Q -` YSI Professional Plus M rameter Meter (s/n 188101802) Cal Std Information Instrument Readings Date Lot # Onened Exp. Date Dissolved Oxygen Initial (%): o 8 Cal (%): mmHQ: Temperature CQ: Time: (% saturation) DO (Site 92, Initial (% • Cal (%): mmHg: Temperature (°C): Time: I f applicable)* QC** Check: DO Time: Res It %): S• Time: Result (%): Time: Result (%): PH 7 S.U. Initial: —I pHmV: Cal (S.U.): pHmV: Time: � report to0.1S.U. 2 •03 —S%,oZ. 'k t _SS •W ( �l, m� iiOIL2. 12 PH 4 S.U. reporttoO.I S.U. Initial: `q \ •V�"' pHm • r � , c 10 Cal (S.U.): 4-06 pHmV: 1 en. I 7 LC)q0J 40ll'L 0Q13 PH 10 S.U. report to0.1S.U. Initial: pHmV: a Cal (S.U.): -01 pHmVq: rr -- - 4 l0- Time: Z GJ'L enr— S 0812,Z (q1 QC** pH 7 S.U. Time: -5 Result (S.U.): -+ Time: 4 Result S.U.): �' Time: Result (S.U.): 7 i r� '• �Y r re ortto 0.1 S.U. * p 12L ot Spec. Cond. Initial: Cal (pmhos/cm): Time: � 1,000 pmhos/cm L 0 WOO { 0 L (p kil lu % Recovery= QC** Spec. Cond. Timgge::(• Result (pmhos/cm): Time: Re /cm): Time: Result (pmhos/cm): Z�O 1,000 µmhos/cm 1J10 U i (7 L�T—FTR( Q !. 1 J ®({ ,,ap M (ZZ �y 6q 17A % Rewvery= ORP 200 mV Initial: �/) r_ G Cal: 41 (1i� Temperature _(*C): 20. W Time: / •� h lD t75 e a Ito Analyst Name: Date: Notes: 0 a Revision 8, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. 5. Qc Acceptable Ranges: pH +/- o1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. `• QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm - True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 1'. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 •C: degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011 mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H` B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1 of 1 �ZANCHOR E A 4_.C_09_.1" Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Equipment Documentation and Instrument Calibration Data Sheet Project Name: tCiaLS G r l G . 1. lGl�r (( _ Analyst Conducting Calibration: Project Number. r JA 413 Q — V 1. tS ( Date of Calibration: � a,, I ',M / Project Location: ik5106" f V4C Date of Field Measurements: 0_ Facility ID or Permit # (if applicable): 5o —(.>Z EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Select Turbidimeter. Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n Instrument Readings (Hach 2100Q) Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU Lot #: Z 21 L V 10 Expiration Date: C 2 7, Ca( (NTU)W -O Cal (NTU):&A. Ca( (NTU): Time: 0- Time: Z Time: .4,2, Calibration Verification: *Pre -Analysis Check (10 NTU): Result (NTU): 2 Time: �^ *Post -Analysis Check (10 NTU): Result (NTU): Time: YSI Professional Plus Multiparemeter Meter (s/n 188101802) Instrument Readings Cal Std Information Lot# Date O ened Date Dissolved Oxygen (% saturation) Initial (%): Z . Z Cal (%): l 106 /. mmHg: 7 ~fi • 4 . Temperature (°C): e P S „ Z Time: 4 o - { �t DO (Site #2, ifapplicable)* Initial (%): Cal (%): mmHg: Temperature (°C): Time: QC** Check: DO Time: Result (%): Time: Result (%): Time: Result (%): PH 7 S.U. reportto 0.1 S.U. Initi pHmV: Ca( (S.U.): pHmV: % • Time: ( &►- 16 PH 4 S.U. report to 0.1 S. U. Init al: �"E . 1 pHmV: � . Ca( (S.U.): pHmV: - (� Time: rr� l J LGT ttoA q (b tit. i/ PH 10 S.U. report to 0.1 S.U. Initial: pHmV: - 2 0(p •--1-. Cal (S.U.): licl,w pHmV: -10,1-• Time: D b'L , AM 08122 2 QC** pH 7 S.U. re port to 0.1 S.U. Tim ^ fi Result (S.U.): Time: Resulltt .U.): T . Time: Result (S.U.): 2.&tA 22 Ob I&I Spec. Cond. 11000 pmhos/cm Initial: s -Ircli 5 Cal (pmhoss/cm): 16 V0 Time: 0:?rOL Z(jtM biz ZZ 111 % Recovery= QC** Spec. Cond. 1,000 pmhos/cm Time: 1✓� R Resullttj(pmmhos/cm): 4 l� Time: V-` 20 d Resultt((pmhos/cm): l & Time: Result (pmhos/cm): ZGD % Recovery= ORP 200 mV Initial: � L% Cal: �? 6O Temperature Cc): Time: Analyst Signature: Analyst Name:-1,0 W601- Date: a I� ! Notes: Q 0 Revision•8, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. `When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. 5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm - True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 °C: degrees Celsius ORP. oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011 mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1 of 1 Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Waypointo ANALYTICAL 5/4/2023 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville, NC, 28801 Ref: Analytical Testing Lab Report Number: 23-084-0001 Client Project Description: Jackson County Landfill Site: Jackson Project Number: C21480-01.01 Dear Jessica Mayers: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/25/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 84 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2023 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2023 South Carolina State Program 99012 12/31/2022 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00016/23-084-0001 Page 2 of 84 Waypoint. (2) ANALYTICAL Sample Report Number: 23-084-0001 Client Project Description: Jackson County Landfill 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca I som Summary Table Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 AM20GAX Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 RSK-175 Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 AM23G Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 7470A WP MTN 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 6020E WP MTN 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 531OC-2011 WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 RSK-175 Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 AM23G Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 AM20GAX Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 7470A WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 6020E WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 531OC-2011 WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 RSK-175 Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 AM23G Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 AM20GAX Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 7470A WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 6020E WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 531OC-2011 WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 7470A WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 6020E WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 EPA-200.7 WP MTN 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 7470A WP MTN Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 23-084-0001 Client Project Description: Jackson County Landfill Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 6020B WP MTN 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 EPA-200.7 WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 EPA-200.7 WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 7470A WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 6020E WP MTN 92269 TB-23240323 Aqueous 03/23/2023 03/25/2023 10:15 Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 4 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica l.com Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-01-20230323 V 92263 Result Units Report Limit Analyzed 2320B-2011 Alkalinity (as CaCO3) 77000 pg/L 800 03/30/2023 15:20 5220D-2011 COD (Chemical Oxygen Demand) 9000 Ng/L 8000 03/28/2023 10:31 5310C-2011 TOC 902 pg/L 682 04/10/202316:44 6020E Barium 104 Ng/L 0.453 03/31/2023 04:48 6020E Cadmium 0.810 pg/L 0.350 03/31/2023 04:48 6020E Cobalt 115 Ng/L 0.060 03/31/2023 04:48 6020E Copper 2.91 pg/L 0.489 03/31/2023 04:48 6020E Lead 0.307 Ng/L 0.264 03/31/2023 04:48 6020E Nickel 16.4 pg/L 0.182 03/31/2023 04:48 6020E Thallium 1.55 Ng/L 0.0610 03/31/2023 04:48 6020E Zinc 60.5 pg/L 4.67 03/31/2023 04:48 8260D 1,4-Dichlorobenzene 5.79 Ng/L 2.10 04/05/2023 22:20 9056A Chloride 437 pg/L 370 03/25/202310:23 SM-3500-Fe-B Ferrous Iron 8340 Ng/L 1250 03/27/2023 17:15 MW-02-20230323 V 92264 5220D-2011 COD (Chemical Oxygen Demand) 10000 pg/L 8000 03/28/2023 10:31 5310C-2011 TOC 1020 Ng/L 682 04/10/2023 17:22 6020B Arsenic 2.53 pg/L 0.297 03/31/2023 04:51 6020B Dissolved Arsenic 0.906 Ng/L 0.297 03/30/2023 22:17 6020B Barium 188 pg/L 0.453 03/31/2023 04:51 6020B Dissolved Barium 160 Ng/L 0.453 03/30/2023 22:17 6020B Beryllium 0.887 pg/L 0.102 03/31/2023 04:51 6020B Dissolved Beryllium 0.344 Ng/L 0.102 03/30/2023 22:17 6020E Chromium 41.7 pg/L 0.346 03/31/2023 04:51 6020B Dissolved Chromium 22.9 Ng/L 0.346 03/30/2023 22:17 6020B Cobalt 59.3 pg/L 0.060 03/31/2023 04:51 6020E Dissolved Cobalt 51.0 Ng/L 0.060 03/30/2023 22:17 6020E Copper 34.9 pg/L 0.489 03/31/2023 04:51 6020E Dissolved Copper 19.4 Ng/L 0.489 03/30/2023 22:17 6020E Lead 9.21 pg/L 0.264 03/31/2023 04:51 6020E Dissolved Lead 5.57 Ng/L 0.264 03/30/2023 22:17 6020E Dissolved Nickel 19.9 pg/L 0.182 03/30/2023 22:17 6020E Nickel 31.8 Ng/L 0.182 03/31/2023 04:51 6020E Selenium 3.19 pg/L 0.703 03/31/2023 04:51 6020E Dissolved Selenium 2.15 Ng/L 0.703 03/30/2023 22:17 6020B Thallium 0.771 Ng/L 0.0610 03/31/2023 04:51 Qualifiers I 0 0 .1 IJ i I 0 Page 5 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica Isom Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-02-20230323 V 92264 Result Units Report Limit Analyzed Qualifiers 6020B Dissolved Thallium 0.573 pg/L 0.0610 03/30/2023 22:17 6020E Vanadium 52.5 Ng/L 0.767 03/31/2023 04:51 6020E Dissolved Vanadium 29.0 pg/L 0.767 03/30/2023 22:17 6020E Zinc 160 Ng/L 4.67 03/31/2023 04:51 6020B Dissolved Zinc 173 pg/L 4.67 03/30/2023 22:17 8260D 1,1-Dichloroethane 0.244 Ng/L 0.240 04/05/2023 20:16 8260D SIM 1,4-Dioxane 1.79 pg/L 0.139 03/28/2023 12:18 MW-05R-20230323 V 92265 2320B-2011 Alkalinity (as CaCO3) 217000 Ng/L 800 03/31/2023 16:00 5210E-2015 Biochemical Oxygen Demand (5-day) 4000 pg/L 2000 03/25/2023 08:25 5220D-2011 COD (Chemical Oxygen Demand) 22000 Ng/L 8000 03/28/2023 10:31 5310C-2011 TOC 3120 pg/L 682 04/10/202318:00 6020E Arsenic 6.76 Ng/L 0.297 03/31/2023 04:55 6020E Dissolved Arsenic 5.08 pg/L 0.297 03/30/2023 22:21 6020E Barium 234 Ng/L 0.453 03/31/2023 04:55 6020E Dissolved Barium 242 pg/L 0.453 03/30/2023 22:21 6020E Chromium 4.84 Ng/L 0.346 03/31/2023 04:55 6020E Dissolved Chromium 0.776 pg/L 0.346 03/30/2023 22:21 6020E Cobalt 16.3 Ng/L 0.060 03/31/2023 04:55 6020E Dissolved Cobalt 16.3 pg/L 0.060 03/30/2023 22:21 6020E Copper 8.39 Ng/L 0.489 03/31/2023 04:55 6020E Dissolved Copper 3.20 pg/L 0.489 03/30/2023 22:21 6020E Lead 1.66 Ng/L 0.264 03/31/2023 04:55 6020E Dissolved Lead 1.22 pg/L 0.264 03/30/2023 22:21 6020E Dissolved Nickel 3.62 Ng/L 0.182 03/30/2023 22:21 6020E Nickel 5.96 pg/L 0.182 03/31/2023 04:55 6020E Thallium 0.147 Ng/L 0.0610 03/31/2023 04:55 6020E Dissolved Thallium 0.0638 pg/L 0.0610 03/30/2023 22:21 6020E Vanadium 5.85 Ng/L 0.767 03/31/202318:29 6020E Dissolved Vanadium 1.13 pg/L 0.767 03/30/2023 22:21 6020E Zinc 25.7 Ng/L 4.67 03/31/2023 04:55 6020E Dissolved Zinc 37.5 pg/L 4.67 03/30/2023 22:21 8260D Benzene 1.58 Ng/L 0.180 04/05/202319:02 8260D Chlorobenzene 7.57 pg/L 0.190 04/05/202319:02 8260D 1,2-Dichlorobenzene 0.280 Ng/L 0.220 04/05/202319:02 8260D 1,4-Dichlorobenzene 8.57 pg/L 0.210 04/05/202319:02 I I J 0 I I J Page 6 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica Isom Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-05R-20230323 8260D 8260D 8260D SIM 9056A SM-3500-Fe-B SW-01-20230323 6020E 6020E 6020E 6020E 6020E 8260D EPA-200.7 EPA-200.7 EPA-200.7 SW-02-20230323 6020B 6020E 6020E 6020E 6020E 6020E EPA-200.7 EPA-200.7 EPA-200.7 SW-03-20230323 6020B 6020E 6020B 6020E 6020B 6020E 6020B EPA-200.7 EPA-200.7 V 92265 cis- 1,2-Dichloroethene Vinyl Chloride 1,4-Dioxane Chloride Ferrous Iron V 92266 Barium Chromium Cobalt Copper Zinc Acetone Calcium Hardness as CaCO3 Magnesium V 92267 Barium Chromium Cobalt Copper Nickel Zinc Calcium Hardness as CaCO3 Magnesium V 92268 Barium Chromium Cobalt Copper Lead Nickel Zinc Calcium Hardness as CaCO3 Result Units Report Limit Analyzed Qualifiers 3.94 iag/L 0.200 04/05/202319:02 0.684 lag/L 0.170 04/05/202319:02 6.18 iag/L 0.139 03/28/202312:43 72000 lag/L 370 03/25/202310:39 23500 iag/L 620 03/27/202317:15 H 12.4 lag/L 0.453 03/31/2023 04:59 0.562 iag/L 0.346 03/31/2023 04:59 1 0.133 lag/L 0.060 03/31/2023 04:59 1 0.660 iag/L 0.489 03/31/2023 04:59 1 13.9 lag/L 4.67 03/31/2023 04:59 10.2 iag/L 1.80 04/06/2023 04:55 2.11 mg/L 0.100 03/29/2023 21:01 8320 lag/L 100 03/29/2023 21:01 0.740 mg/L 0.100 03/29/2023 21:01 13.5 lag/L 0.453 03/31/2023 05:02 0.742 lag/L 0.346 03/31/2023 05:02 1 0.217 lag/L 0.060 03/31/2023 05:02 1 0.862 lag/L 0.489 03/31/2023 05:02 1 0.365 lag/L 0.182 03/31/2023 05:02 1 18.5 lag/L 4.67 03/31/2023 05:02 2.30 mg/L 0.100 03/29/2023 21:07 9000 lag/L 100 03/29/2023 21:07 0.792 mg/L 0.100 03/29/2023 21:07 13.5 lag/L 0.453 03/31/2023 05:13 0.840 lag/L 0.346 03/31/2023 05:13 1 0.235 lag/L 0.060 03/31/2023 05:13 1 0.860 lag/L 0.489 03/31/2023 05:13 1 0.285 lag/L 0.264 03/31/2023 05:13 1 0.389 lag/L 0.182 03/31/2023 05:13 1 9.75 lag/L 4.67 03/31/2023 05:13 1 2.06 mg/L 0.100 03/29/2023 21:22 8200 lag/L 100 03/29/2023 21:22 Page 7 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers SW-03-20230323 V 92268 EPA-200.7 Magnesium 0.743 mq/L 0.100 03/29/2023 21:22 Page 8 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron 8340 H Ng/L 1250 5000 1 03/27/23 17:15 SLO SM-3500-Fe-B 1,4-Dioxane <0.139 pg/L 0.139 2.00 1 03/28/23 11:53 TBL 8260D SIM Alkalinity (as CaCO3) 77000 Ng/L 800 5000 1 03/30/23 15:20 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 pg/L 2000 2000 1 03/25/23 08:25 SLO 521OB-2015 Chloride 4373 Ng/L 370 1000 1 03/25/23 10:23 CM] 9056A COD (Chemical Oxygen Demand) 90003 pg/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/25/23 10:23 CM] 9056A TOC 9023 pg/L 682 1000 1 04/10/23 16:44 SRJ 531OC-2011 Sulfate <650 Ng/L 650 2000 1 03/25/23 10:23 CM] 9056A Sulfide <830 pg/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:48 CPW 6020B Arsenic <0.297 pg/L 0.297 1.00 1 03/31/23 04:48 CPW 6020B Barium 104 Ng/L 0.453 1.00 1 03/31/23 04:48 CPW 6020B Beryllium <1.00 pg/L 0.102 1.00 1 03/31/23 04:48 CPW 6020B Cadmium 0.8103 Ng/L 0.350 1.00 1 03/31/23 04:48 CPW 6020B Chromium <0.346 pg/L 0.346 1.00 1 03/31/23 04:48 CPW 6020B Cobalt 115 Ng/L 0.060 1.00 1 03/31/23 04:48 CPW 6020B Copper 2.91 pg/L 0.489 1.00 1 03/31/23 04:48 CPW 6020B Lead 0.3073 Ng/L 0.264 1.00 1 03/31/23 04:48 CPW 6020B Mercury (Total) <0.130 pg/L 0.130 0.200 1 03/29/23 11:56 FDS 7470A Nickel 16.4 Ng/L 0.182 1.00 1 03/31/23 04:48 CPW 6020B Selenium <0.703 pg/L 0.703 1.00 1 03/31/23 04:48 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 04:48 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 9 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Sample ID: MW-01-20230323 Matrix: Aqueous Sampled: 3/23/2023 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium 1.55 Ng/L 0.0610 1.00 1 03/31/23 04:48 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 03/31/2318:14 CPW 6020B Zinc 60.5 Ng/L 4.67 10.0 1 03/31/23 04:48 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 10 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <18.0 Ng/L 18.0 50.0 10 04/05/23 22:20 TBL V31670 Acrylonitrile <2.30 ug/L 2.30 50.0 10 04/05/23 22:20 TBL V31670 Benzene <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Bromochloromethane <4.20 ug/L 4.20 10.0 10 04/05/23 22:20 TBL V31670 Bromodichloromethane <1.60 Ng/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 Bromoform <15.0 ug/L 15.0 50.0 10 04/05/23 22:20 TBL V31670 Bromomethane <2.80 Ng/L 2.80 10.0 10 04/05/23 22:20 TBL V31670 Carbon Disulfide <1.50 ug/L 1.50 50.0 10 04/05/23 22:20 TBL V31670 Carbon Tetrachloride <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Chlorobenzene <1.90 ug/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 Chlorodibromomethane <1.90 Ng/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 Chloroethane <4.30 ug/L 4.30 10.0 10 04/05/23 22:20 TBL V31670 Chloroform <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Chloromethane <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Di -Isopropyl Ether (DIPE) <9.60 Ng/L 9.60 50.0 10 04/05/23 22:20 TBL V31670 1,2-Dibromo-3-Chloropropane <11.0 ug/L 11.0 20.0 10 04/05/23 22:20 TBL V31670 1,2-Dibromoethane <2.00 Ng/L 2.00 5.00 10 04/05/23 22:20 TBL V31670 Dibromomethane <2.30 ug/L 2.30 5.00 10 04/05/23 22:20 TBL V31670 trans-1,4-Dichloro-2-butene <13.0 Ng/L 13.0 100 10 04/05/23 22:20 TBL V31670 1,2-Dichlorobenzene <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,4-Dichlorobenzene 5.79 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 Dichlorodifluoromethane <12.0 ug/L 12.0 50.0 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 11 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <2.40 Ng/L 2.40 5.00 10 04/05/23 22:20 TBL V31670 1,2-Dichloroethane <1.50 ug/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 1,1-Dichloroethene <1.50 Ng/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 cis- 1,2-Dich loroethene <2.00 ug/L 2.00 5.00 10 04/05/23 22:20 TBL V31670 trans-1,2-Dichloroethene <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 1,2-Dichloropropane <1.90 ug/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 cis- 1,3-Dich loropropene <2.10 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 trans-1,3-Dichloropropene <1.50 ug/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 Ethylbenzene <1.70 Ng/L 1.70 5.00 10 04/05/23 22:20 TBL V31670 2-Hexanone <3.80 ug/L 3.80 50.0 10 04/05/23 22:20 TBL V31670 Methyl Ethyl Ketone (MEK) <7.10 Ng/L 7.10 50.0 10 04/05/23 22:20 TBL V31670 4-Methyl-2-Pentanone <10.0 ug/L 10.0 50.0 10 04/05/23 22:20 TBL V31670 Methylene Chloride <3.30 Ng/L 3.30 10.0 10 04/05/23 22:20 TBL V31670 Styrene <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,1,1,2-Tetrachloroethane <1.60 Ng/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 1,1,2,2-Tetrachloroethane <1.60 ug/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 Tetrachloroethene <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Tetrahydrofuran <15.0 ug/L 15.0 100 10 04/05/23 22:20 TBL V31670 Toluene <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,1,1-Trichloroethane <1.60 ug/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 1,1,2-Trichloroethane <0.960 Ng/L 0.960 5.00 10 04/05/23 22:20 TBL V31670 Trichloroethene <1.80 ug/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 12 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 Lab No : 92263 Sample ID: MW-01-20230323 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 1,2,3-Trichloropropane <2.70 ug/L 2.70 10.0 10 04/05/23 22:20 TBL V31670 Vinyl Acetate <10.0 Ng/L 10.0 20.0 10 04/05/23 22:20 TBL V31670 Vinyl Chloride <1.70 ug/L 1.70 5.00 10 04/05/23 22:20 TBL V31670 o-Xylene <2.10 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 m,p-Xylene <4.20 ug/L 4.20 10.0 10 04/05/23 22:20 TBL V31670 Xylene (Total) <2.1 Ng/L 2.10 5.00 10 04/05/23 22:20 V31670 Surrogate: 4-Bromofluorobenzene 103 Limits: 80-124% 10 04/05/23 22:20 TBL V31670 Surrogate: Dibromofluoromethane 100 Limits: 75-129% 10 04/05/23 22:20 TBL V31670 Surrogate: 1,2-Dichloroethane - d4 103 Limits: 63-136% 10 04/05/23 22:20 TBL V31670 Surrogate: Toluene-d8 102 Limits: 77-123% 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 13 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 1.793 Ng/L 0.139 2.00 1 03/28/23 12:18 TBL 8260D SIM COD (Chemical Oxygen Demand) 10000 J ug/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 TOC 1020 Ng/L 682 1000 1 04/10/23 17:22 SRJ 531OC-2011 Sulfide <830 ug/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Antimony <0.618 ug/L 0.618 1.00 1 03/30/23 22:17 CPW 6020B Arsenic 2.53 Ng/L 0.297 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Arsenic 0.906 J ug/L 0.297 1.00 1 03/30/23 22:17 CPW 6020B Barium 188 Ng/L 0.453 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Barium 160 ug/L 0.453 1.00 1 03/30/23 22:17 CPW 6020B Beryllium 0.8873 Ng/L 0.102 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Beryllium 0.3443 ug/L 0.102 1.00 1 03/30/23 22:17 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Cadmium <0.350 ug/L 0.350 1.00 1 03/30/23 22:17 CPW 6020B Chromium 41.7 Ng/L 0.346 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Chromium 22.9 ug/L 0.346 1.00 1 03/30/23 22:17 CPW 6020B Cobalt 59.3 Ng/L 0.060 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Cobalt 51.0 ug/L 0.060 1.00 1 03/30/23 22:17 CPW 6020B Copper 34.9 Ng/L 0.489 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Copper 19.4 ug/L 0.489 1.00 1 03/30/23 22:17 CPW 6020B Lead 9.21 Ng/L 0.264 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Lead 5.57 ug/L 0.264 1.00 1 03/30/23 22:17 CPW 6020B Mercury (Total) <0.130 Ng/L 0.130 0.200 1 03/29/23 11:58 FDS 7470A Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 14 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Sample ID: MW-02-20230323 Matrix: Aqueous Sampled: 3/23/2023 15:12 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Dissolved Mercury <0.130 Ng/L 0.130 0.200 1 03/30/23 11:24 FDS 7470A Dissolved Nickel 19.9 ug/L 0.182 1.00 1 03/30/23 22:17 CPW 6020B Nickel 31.8 Ng/L 0.182 1.00 1 03/31/23 04:51 CPW 6020B Selenium 3.19 ug/L 0.703 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Selenium 2.15 Ng/L 0.703 1.00 1 03/30/23 22:17 CPW 6020B Silver <0.0570 ug/L 0.0570 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Silver <0.0570 Ng/L 0.0570 1.00 1 03/30/23 22:17 CPW 6020B Thallium 0.7713 ug/L 0.0610 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Thallium 0.5733 Ng/L 0.0610 1.00 1 03/30/23 22:17 CPW 6020B Vanadium 52.5 ug/L 0.767 5.00 1 03/31/23 04:51 CPW 6020B Dissolved Vanadium 29.0 Ng/L 0.767 5.00 1 03/30/23 22:17 CPW 6020B Zinc 160 ug/L 4.67 10.0 1 03/31/23 04:51 CPW 6020B Dissolved Zinc 173 Ng/L 4.67 10.0 1 03/30/23 22:17 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 15 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 20:16 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 20:16 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 20:16 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 20:16 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 20:16 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 20:16 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 20:16 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 20:16 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 20:16 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 20:16 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 20:16 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 20:16 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 20:16 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 20:16 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 16 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 0.2443 Ng/L 0.240 0.500 1 04/05/23 20:16 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 20:16 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 20:16 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 20:16 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 20:16 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 20:16 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 20:16 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 20:16 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 20:16 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 20:16 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 17 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 105 Limits: 63-136% 103 Limits: 77-123% 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 18 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron 23500 H Ng/L 620 2500 1 03/27/23 17:15 SLO SM-3500-Fe-B 1,4-Dioxane 6.18 ug/L 0.139 2.00 1 03/28/23 12:43 TBL 8260D SIM Alkalinity (as CaCO3) 217000 Ng/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) 4000 ug/L 2000 2000 1 03/25/23 08:25 SLO 521OB-2015 Chloride 72000 Ng/L 370 1000 1 03/25/2310:39 CM] 9056A COD (Chemical Oxygen Demand) 220003 ug/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/25/23 10:39 CM] 9056A TOC 3120 ug/L 682 1000 1 04/10/23 18:00 SRJ 531OC-2011 Sulfate <650 Ng/L 650 2000 1 03/25/2310:39 CM] 9056A Sulfide <830 ug/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Antimony <0.618 ug/L 0.618 1.00 1 03/30/23 22:21 CPW 6020B Arsenic 6.76 Ng/L 0.297 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Arsenic 5.08 ug/L 0.297 1.00 1 03/30/23 22:21 CPW 6020B Barium 234 Ng/L 0.453 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Barium 242 ug/L 0.453 1.00 1 03/30/23 22:21 CPW 6020B Beryllium <0.102 Ng/L 0.102 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Beryllium <0.102 ug/L 0.102 1.00 1 03/30/23 22:21 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Cadmium <0.350 ug/L 0.350 1.00 1 03/30/23 22:21 CPW 6020B Chromium 4.84 Ng/L 0.346 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Chromium 0.7761 ug/L 0.346 1.00 1 03/30/23 22:21 CPW 6020B Cobalt 16.3 Ng/L 0.060 1.00 1 03/31/23 04:55 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 19 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Sample ID: MW-05R-20230323 Matrix: Aqueous Sampled: 3/23/2023 12:52 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Dissolved Cobalt 16.3 Ng/L 0.060 1.00 1 03/30/23 22:21 CPW 6020B Copper 8.39 ug/L 0.489 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Copper 3.20 Ng/L 0.489 1.00 1 03/30/23 22:21 CPW 6020B Lead 1.66 ug/L 0.264 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Lead 1.22 Ng/L 0.264 1.00 1 03/30/23 22:21 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:50 FDS 7470A Dissolved Mercury <0.130 Ng/L 0.130 0.200 1 03/30/23 11:25 FDS 7470A Dissolved Nickel 3.62 ug/L 0.182 1.00 1 03/30/23 22:21 CPW 6020B Nickel 5.96 Ng/L 0.182 1.00 1 03/31/23 04:55 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Selenium <0.703 Ng/L 0.703 1.00 1 03/30/23 22:21 CPW 6020B Silver <0.0570 ug/L 0.0570 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Silver <0.0570 Ng/L 0.0570 1.00 1 03/30/23 22:21 CPW 6020B Thallium 0.147 J ug/L 0.0610 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Thallium 0.0638 J Ng/L 0.0610 1.00 1 03/30/23 22:21 CPW 6020B Vanadium 5.85 ug/L 0.767 5.00 1 03/31/2318:29 CPW 6020B Dissolved Vanadium 1.13 J Ng/L 0.767 5.00 1 03/30/23 22:21 CPW 6020B Zinc 25.7 ug/L 4.67 10.0 1 03/31/23 04:55 CPW 6020B Dissolved Zinc 37.5 Ng/L 4.67 10.0 1 03/30/23 22:21 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 20 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 19:02 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 19:02 TBL V31670 Benzene 1.58 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 19:02 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 19:02 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 19:02 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 19:02 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Chlorobenzene 7.57 ug/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 19:02 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 19:02 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 19:02 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 19:02 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 19:02 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 19:02 TBL V31670 1,2-Dichlorobenzene 0.2801 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,4-Dichlorobenzene 8.57 Ng/L 0.210 0.500 1 04/05/23 19:02 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 19:02 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 21 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 19:02 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 cis- 1,2-Dich loroethene 3.94 ug/L 0.200 0.500 1 04/05/23 19:02 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 19:02 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 19:02 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 19:02 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 19:02 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 19:02 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 19:02 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 19:02 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 19:02 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 22 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride 0.684 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 102 Limits: 75-129% 105 Limits: 63-136% 101 Limits: 77-123% 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 23 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:08 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 04:59 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 04:59 CPW 6020E Barium 12.4 ug/L 0.453 1.00 1 03/31/23 04:59 CPW 6020B Beryllium <1.00 Ng/L 0.102 1.00 1 03/31/23 04:59 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 04:59 CPW 6020B Calcium 2.11 mg/L 0.100 1 03/29/23 21:01 BKN EPA-200.7 Chromium 0.5623 ug/L 0.346 1.00 1 03/31/23 04:59 CPW 6020B Cobalt 0.1333 Ng/L 0.060 1.00 1 03/31/23 04:59 CPW 6020B Copper 0.6603 ug/L 0.489 1.00 1 03/31/23 04:59 CPW 6020B Hardness as CaCO3 8320 Ng/L 100 1 03/29/23 21:01 EPA-200.7 Lead <0.264 ug/L 0.264 1.00 1 03/31/23 04:59 CPW 6020B Magnesium 0.740 mg/L 0.100 1 03/29/23 21:01 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:51 FDS 7470A Nickel <0.182 Ng/L 0.182 1.00 1 03/31/23 04:59 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 04:59 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 04:59 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 04:59 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:36 CPW 6020B Zinc 13.9 ug/L 4.67 10.0 1 03/31/23 04:59 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 24 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 10.2 Ng/L 1.80 5.00 1 04/06/23 04:55 MSA V31704 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/06/23 04:55 MSA V31704 Benzene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/06/23 04:55 MSA V31704 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 Bromoform <1.50 ug/L 1.50 5.00 1 04/06/23 04:55 MSA V31704 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/06/23 04:55 MSA V31704 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/06/23 04:55 MSA V31704 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 Chloroethane <0.430 ug/L 0.430 1.00 1 04/06/23 04:55 MSA V31704 Chloroform <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Chloromethane <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/06/23 04:55 MSA V31704 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/06/23 04:55 MSA V31704 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/06/23 04:55 MSA V31704 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/06/23 04:55 MSA V31704 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/06/23 04:55 MSA V31704 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:55 MSA V31704 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/06/23 04:55 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 25 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/06/23 04:55 MSA V31704 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/06/23 04:55 MSA V31704 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:55 MSA V31704 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/06/23 04:55 MSA V31704 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/06/23 04:55 MSA V31704 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/06/23 04:55 MSA V31704 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/06/23 04:55 MSA V31704 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/06/23 04:55 MSA V31704 Styrene <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/06/23 04:55 MSA V31704 Toluene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/06/23 04:55 MSA V31704 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 26 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31703 04/05/23 14:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 104 Limits: 63-136% 103 Limits: 77-123% 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 H Beyond holding time MQL Method Quantitation Limit Page 27 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:33 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 05:02 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 05:02 CPW 6020E Barium 13.5 ug/L 0.453 1.00 1 03/31/23 05:02 CPW 6020B Beryllium <1.00 Ng/L 0.102 1.00 1 03/31/23 05:02 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 05:02 CPW 6020B Calcium 2.30 mg/L 0.100 1 03/29/23 21:07 BKN EPA-200.7 Chromium 0.7423 ug/L 0.346 1.00 1 03/31/23 05:02 CPW 6020B Cobalt 0.2173 Ng/L 0.060 1.00 1 03/31/23 05:02 CPW 6020B Copper 0.8623 ug/L 0.489 1.00 1 03/31/23 05:02 CPW 6020B Hardness as CaCO3 9000 Ng/L 100 1 03/29/23 21:07 EPA-200.7 Lead <0.264 ug/L 0.264 1.00 1 03/31/23 05:02 CPW 6020B Magnesium 0.792 mg/L 0.100 1 03/29/23 21:07 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:55 FDS 7470A Nickel 0.3653 Ng/L 0.182 1.00 1 03/31/23 05:02 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 05:02 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 05:02 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 05:02 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:41 CPW 6020B Zinc 18.5 ug/L 4.67 10.0 1 03/31/23 05:02 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 28 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 21:06 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 21:06 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 21:06 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 21:06 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 21:06 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 21:06 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 21:06 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 21:06 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 21:06 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 21:06 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 21:06 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 21:06 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 21:06 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 21:06 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 29 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 21:06 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 21:06 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 21:06 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 21:06 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 21:06 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 21:06 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 21:06 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 21:06 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 21:06 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 21:06 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 30 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 100 Limits: 75-129% 99.0 Limits: 63-136% 104 Limits: 77-123% 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 31 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:58 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 05:13 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 05:13 CPW 6020E Barium 13.5 ug/L 0.453 1.00 1 03/31/23 05:13 CPW 6020B Beryllium <0.102 Ng/L 0.102 1.00 1 03/31/23 05:13 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 05:13 CPW 6020B Calcium 2.06 mg/L 0.100 1 03/29/23 21:22 BKN EPA-200.7 Chromium 0.8403 ug/L 0.346 1.00 1 03/31/23 05:13 CPW 6020B Cobalt 0.2353 Ng/L 0.060 1.00 1 03/31/23 05:13 CPW 6020B Copper 0.8603 ug/L 0.489 1.00 1 03/31/23 05:13 CPW 6020B Hardness as CaCO3 8200 Ng/L 100 1 03/29/23 21:22 EPA-200.7 Lead 0.2853 ug/L 0.264 1.00 1 03/31/23 05:13 CPW 6020B Magnesium 0.743 mg/L 0.100 1 03/29/23 21:22 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:57 FDS 7470A Nickel 0.3893 Ng/L 0.182 1.00 1 03/31/23 05:13 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 05:13 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 05:13 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 05:13 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:46 CPW 6020B Zinc 9.75 J ug/L 4.67 10.0 1 03/31/23 05:13 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 32 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/06/23 04:31 MSA V31704 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/06/23 04:31 MSA V31704 Benzene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/06/23 04:31 MSA V31704 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 Bromoform <1.50 ug/L 1.50 5.00 1 04/06/23 04:31 MSA V31704 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/06/23 04:31 MSA V31704 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/06/23 04:31 MSA V31704 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 Chloroethane <0.430 ug/L 0.430 1.00 1 04/06/23 04:31 MSA V31704 Chloroform <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Chloromethane <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/06/23 04:31 MSA V31704 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/06/23 04:31 MSA V31704 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/06/23 04:31 MSA V31704 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/06/23 04:31 MSA V31704 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/06/23 04:31 MSA V31704 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:31 MSA V31704 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/06/23 04:31 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 33 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/06/23 04:31 MSA V31704 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/06/23 04:31 MSA V31704 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:31 MSA V31704 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/06/23 04:31 MSA V31704 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/06/23 04:31 MSA V31704 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/06/23 04:31 MSA V31704 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/06/23 04:31 MSA V31704 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/06/23 04:31 MSA V31704 Styrene <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/06/23 04:31 MSA V31704 Toluene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/06/23 04:31 MSA V31704 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 34 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31703 04/05/23 14:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 101 Limits: 63-136% 106 Limits: 77-123% 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 H Beyond holding time MQL Method Quantitation Limit Page 35 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92269 Matrix: Aqueous Sample ID : TB-23240323 Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 15:44 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 15:44 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 15:44 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 15:44 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 15:44 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 15:44 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 15:44 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 15:44 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 15:44 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 15:44 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 15:44 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 15:44 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 36 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92269 Matrix: Aqueous Sample ID : TB-23240323 Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 15:44 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 15:44 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 1,4-Dioxane <16.0 Ng/L 16.0 150 1 04/05/23 15:44 TBL V31670 Ethylbenzene <0.170 ug/L 0.170 0.500 1 04/05/23 15:44 TBL V31670 2-Hexanone <0.380 Ng/L 0.380 5.00 1 04/05/23 15:44 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 ug/L 0.710 5.00 1 04/05/23 15:44 TBL V31670 4-Methyl-2-Pentanone <1.00 Ng/L 1.00 5.00 1 04/05/23 15:44 TBL V31670 Methylene Chloride <0.330 ug/L 0.330 1.00 1 04/05/23 15:44 TBL V31670 Styrene <0.220 Ng/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 Tetrachloroethene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Tetrahydrofuran <1.50 Ng/L 1.50 10.0 1 04/05/23 15:44 TBL V31670 Toluene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,1,1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 1,1,2-Trichloroethane <0.096 ug/L 0.096 0.500 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 37 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 Lab No : 92269 Sample ID : TB-23240323 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Trichlorofluoromethane <0.180 ug/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 1,2,3-Trichloropropane <0.270 Ng/L 0.270 1.00 1 04/05/23 15:44 TBL V31670 Vinyl Acetate <1.00 ug/L 1.00 2.00 1 04/05/23 15:44 TBL V31670 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 04/05/23 15:44 TBL V31670 o-Xylene <0.210 ug/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 04/05/23 15:44 TBL V31670 Xylene (Total) <0.21 ug/L 0.210 0.500 1 04/05/23 15:44 KCC V31670 Surrogate:4-Bromofluorobenzene 106 Limits:80-124% 1 04/05/23 15:44 TBL V31670 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 04/05/23 15:44 TBL V31670 Surrogate: 1,2-Dichloroethane - d4 107 Limits: 63-136% 1 04/05/23 15:44 TBL V31670 Surrogate: Toluene-d8 103 Limits: 77-123% 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 38 of 84 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Access Analytical 15 Thames Valley Rd Irmo, SC 29063 ATTENTION Ashley Amick PROJECTID 23-084-0001 LABORATORY REPORT NUMBER 223032905 DATE 05/01 /2023 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979 Innovation Park Dr., Baton Rouge, LA 70820. - Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 223032905 05/01/2023 15:03 Page 1 of 16 Page 39 of 84 LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 Analytical ANALYTICAL RESULTS Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 05/01/2023 Report p 223032905 I1II111111IIII Project 23-084-0001 Samples Collected 3/23/23 Deliver To Additional Recipients Ashley Amick Angela Martin, Access Analytical Access Analytical Lab Reports, Access Analytical 15 Thames Valley Rd Irmo, SC 29063 803-781-4243 ACCREDITED] CERT # 6429.01 Lab Report#: 223032905 05/01/2023 15:03 Page 2 of 16 Page 40 of 84 Report#: 223032905 �,ear�ryrocar' Project ID: 23-084-0001 Laboratory Endorsement Report Date: 05/01/2023 Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223032905 Lab Report#: 223032905 05/01/2023 15:03 Page 3 of 16 Page 41 of 84 !"aceA eVica! Report#: 223032905 Project ID: 23-084-0001 Certifications Report Date: 05/01/2023 Certification Certification Number A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Lab Report#: 223032905 05/01/2023 15:03 Page 4 of 16 Page 42 of 84 !"aceA eVica! Report#: 223032905 Project ID: 23-084-0001 Case Narrative Client: Access Analytical Report: 223032905 Report Date: 05/01/2023 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. This report is being revised and reissued to split samples 22303290501 and 22303290505 onto a separate report This report supersedes and replaces any prior reports issued under this workorder VOLATILES GAS CHROMATOGRAPHY In the AM20GAX analysis for analytical batch 762901, Methane was detected at an estimated concentration in the method blank. This is probable laboratory contamination. Lab Report#: 223032905 05/01/2023 15:03 Page 5 of 16 Page 43 of 84 aceA��alyirca! Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303290502 MW-01-20230323 Water 3/23/23 10:40 3/28/23 09:57 22303290503 MW-02-20230323 Water 3/23/23 15:12 3/28/23 09:57 22303290504 MW-05R-20230323 Water 3/23/23 12:52 3/28/23 09:57 Lab Report#: 223032905 05/01/2023 15:03 Page 6 of 16 Page 44 of 84 ceAnalyfrca! Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Lactic Acid mg/L 0.59 1 NA 22303290502 MW-01-20230323 Acetic Acid mg/L 1.0 1 NA 22303290502 MW-01-20230323 Propionic Acid mg/L 0.18J 1 NA 22303290502 MW-01-20230323 Formic Acid mg/L 7.2 1 NA 22303290502 MW-01-20230323 Hexanoic Acid mg/L 0.059J 1 NA 22303290503 MW-02-20230323 Lactic Acid mg/L 1.2,1 10 NA 22303290503 MW-02-20230323 Acetic Acid mg/L 2.7,1 10 NA 22303290503 MW-02-20230323 Propionic Acid mg/L 1.2J 10 NA 22303290503 MW-02-20230323 Formic Acid mg/L 67 10 NA 22303290504 MW-05R-20230323 Lactic Acid mg/L 3.3J 10 NA 22303290504 MW-05R-20230323 Acetic Acid mg/L 2.1 J 10 NA 22303290504 MW-05R-20230323 Propionic Acid mg/L 1.11 10 NA 22303290504 MW-05R-20230323 Formic Acid mg/L 65 10 NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Methane ug/L 410 1 NA 22303290503 MW-02-20230323 Methane ug/L 2.7J 1 NA 22303290503 MW-02-20230323 Ethane ug/L 0.191 1 NA 22303290503 MW-02-20230323 Ethene ug/L 0.25J 1 NA 22303290504 MW-05R-20230323 Methane ug/L 3600 4 NA 22303290504 MW-05R-20230323 Ethane ug/L 1.3J 4 NA 22303290504 MW-05R-20230323 Ethene ug/L 1.2J 4 NA EPA RSK-175 Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Carbon Dioxide ug/L 260000 1 NA 22303290503 MW-02-20230323 Carbon Dioxide ug/L 30100 1 NA 22303290504 MW-05R-20230323 Carbon Dioxide ug/L 99200 1 NA Lab Report#: 223032905 05/01/2023 15:03 Page 7 of 16 Page 45 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-01-20230323 Collect Date 03/23/2023 10:40 Lab ID 22303290502 Receive Date 03/28/2023 09:57 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 22:48 763291 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 260000 585 1200 ug/L AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/01/2315:14 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.59 0.053 0.50 mg/L 64-19-7 Acetic Acid 1.0 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.18J 0.053 0.50 mg/L 64-18-6 Formic Acid 7.2 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 127-17-3 Pyruvic Acid 0.060LI 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.059J 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 07:22 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 410 2.0 5.0 ug/L 74-84-0 Ethane 0.17U 0.17 1.0 ug/L 74-85-1 Ethene 0.24U 0.24 1.0 ug/L MW-02-20230323 Collect Date 03/23/2023 15:12 Lab ID 22303290503 Receive Date 03/28/2023 09:57 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 23:04 763291 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 30100 585 1200 ug/L Lab Report#: 223032905 05/01/2023 15:03 Page 8 of 16 Page 46 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-02-20230323 Collect Date 03/23/2023 15:12 Lab ID 22303290503 Receive Date 03/28/2023 09:57 Matrix Water AM23G *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:20 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 1.2J 0.53 5.0 mg/L 64-19-7 Acetic Acid 2.7J 1.2 5.0 mg/L 79-09-4 Propionic Acid 1.2J 0.53 5.0 mg/L 64-18-6 Formic Acid 67 0.55 5.0 mg/L 107-92-6 Butyric Acid 0.58U 0.58 5.0 mg/L 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.561.1 0.56 5.0 mg/L 142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 07:37 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 2.7J 2.0 5.0 ug/L 74-84-0 Ethane 0.191 0.17 1.0 ug/L 74-85-1 Ethene 0.25J 0.24 1.0 ug/L MW-05R-20230323 Collect Date 03/23/2023 12:52 Lab ID 22303290504 Receive Date 03/28/2023 09:57 Matrix Water RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 23:20 763291 BDP NA Parameter Result DL LOQ I Carbon Dioxide 99200 585 1200 G *Results and limits are adjusted for dilution. Units ug/L Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:52 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 3.3J 0.53 5.0 mg/L 64-19-7 Acetic Acid 2.1J 1.2 5.0 mg/L 79-09-4 Propionic Acid 1.11 0.53 5.0 mg/L 64-18-6 Formic Acid 65 0.55 5.0 mg/L 107-92-6 Butyric Acid 0.581J 0.58 5.0 mg/L Lab Report#: 223032905 05/01/2023 15:03 Page 9 of 16 Page 47 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-05R-20230323 Collect Date 03/23/2023 12:52 Lab ID 22303290504 Receive Date 03/28/2023 09:57 Matrix Water AM23G (Continued) *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:52 762926 LHM NA CAS# Parameter Result DL LOQ Units 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L 142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L AM20GAX *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 4 03/31/23 07:54 762901 LMB NA CAS# Parameter 74-82-8 Methane 74-84-0 Ethane 74-85-1 Ethene Result DL LOCI 3600 7.9 20 1.3J 0.69 4.0 1.2J 0.96 4.0 Units ug/L ug/L ug/L Lab Report#: 223032905 05/01/2023 15:03 Page 10 of 16 Page 48 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 GC Volatiles QC Summary Analytical Batch Client ID MB763291 LCS763291 LCSD763291 763291 Lab ID 2469770 2469771 2469772 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/05/23 22:16 04/05/23 21:44 04/05/23 22:00 Matrix Water Water Water EPA RSK-175 Units ug/L Spike Result %R I Control Spike I Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Carbon Dioxide 124-38-9 585UI 5851 338001 38100 11131 38 - 147 1 338001 37900 112 1 40 Lab Report#: 223032905 05/01/2023 15:03 Page 11 of 16 Page 49 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 General Chemistry QC Summary Analytical Batch Client ID MB762926 LCS762926 LCSD762926 762926 Lab ID 2467944 2467945 2467946 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/01/23 03:39 04/01/23 04:11 04/01/23 04:42 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Lactic Acid 50-21-5 0.053U 0.053 2.0 2.3 115 70 - 130 2.0 2.3 116 1 20 Acetic Acid 64-19-7 0.12U 0.12 2.0 1.9 97 70 - 130 2.0 2.0 98 0 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.0 102 70 - 130 2.0 2.1 103 2 20 Formic Acid 64-18-6 0.055U 0.055 2.0 1.9 97 70 - 130 2.0 1.9 96 1 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.0 102 70 - 130 2.0 2.1 103 1 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 1.9 95 70 - 130 2.0 1.9 95 1 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.1 103 70 - 130 2.0 2.1 107 4 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 106 70 - 130 2.0 2.0 99 7 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.0 102 70 - 130 2.0 2.2 109 7 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 101 70 - 130 2.0 2.0 101 1 20 Lab Report#: 223032905 05/01/2023 15:03 Page 12 of 16 Page 50 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 General Chromatography QC Summary Analytical Batch Client ID MB762901 LCS762901 LCSD762901 762901 Lab ID 2467877 2467878 2467879 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/31/23 05:48 03/31/23 05:16 03/31/23 05:32 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Methane 74-82-8 2.2J 2.0 380 340 90 70-130 380 380 101 11 20 Ethane 74-84-0 0.17U 0.17 97 100 103 70 - 130 97 110 116 12 20 Ethene 74-85-1 0.24U 0.24 120 120 102 70 - 130 120 140 115 12 20 Lab Report#: 223032905 05/01/2023 15:03 Page 13 of 16 Page 51 of 84 rw Ol a2 a.+ � L rl CL M IS CD u u Mti m ru p co m N N Q C C)LLI lid N O N n a x all a x m 'P x G 'y UJ '--N ❑ N N ❑ N y in 7J N FA N W a C G A C �^°� Q o o ua U V -' rp� " U _ 0 v U L7 a n ¢n u C n 'm v w [� u _ 2 � t7 a� ._. 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IN N N N N N [y G7 C d o 4 P Q O d C)ZQL N P y ❑ n' N m m M m M M M l+_'1 Ci N M fY] M Q M M M M 4 4 P 0- O ID d n C d 4 � G g V f- ry N N N N N N N 7 uM 0 C ry C ry d N 0 N 6 N 4 N CDG N N CD N d N d N ;C 0 d V L�rl DZ L:] Lfl Lf] l�A Z-r C ys. p} d 4 Q O d_ C, O b C P P ¢ H r b' b C � p O o O C) Q• u rn O v q C.O 4 a n m r o Z d P P P c d d a o d ,� O o o P 0 4 o tl' � P C P d P C, 4 C,0 P 4 0 G {] rn O co (Yl 03 [n p7 CQ of w v o3 V T O L7 0 0 C7 0 4 4 O C aJ N N N N N � h1 fm4 ry n N N V G n VS cs r a yC a C a c p m 7 � Y C �O U d m Ir Q� �R I N L1 Ct c� o _ N G LO O rn N LM O (Y! N N 0 O Q N 4 (0 J Page 52 of 84 G T 0 Q 0< >Q rnr a o a N a) ay V CL cc V V U v Q IL CL x LL! %-t co N M a, p 71 Q. .. s s ~ iVd y M v 3 p 03 LD N � � O r7 74 x Q LU LLI Cn d O U W a c n w rim v� � LN a Ice 'au ��c � r C �1 � o � x CT] � Y .0 N L G E E- c c M 0 LO M N O N O LO O C, O O N CM O M N N 0 Q Q N(D LL Q J Page 53 of 84 O ❑ ❑ ❑ ❑ ❑ 1 J U W 2 U Z W U W W J � Q k \ ❑ ❑ 2 q � ❑ � � � ❑ � � � 2 � / k § Cl. � \ f § 0 w « k ƒ ■ \ k 0 0 & 2 Page 54 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31424 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/30/23 15:20 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 254000 102 90-110 Duplicate V 92048-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 21000 21000 0.0 20 03/30/23 15:20 Date: 05/04/2023 01:09 PM Page 1 of 28 Page 55 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31484 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92265 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/31/23 16:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 251000 100 90-110 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 217000 204000 6.1 20 03/31/23 16:00 Date: 05/04/2023 01:09 PM Page 2 of 28 Page 56 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31283 Analysis Method: 4500S2F-2011 Analysis Description: Sulfide Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result Sulfide pg/L <830 830 2000 03/27/2313:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Sulfide pg/L 10000 9500 95.0 70-122 Date: 05/04/2023 01:09 PM Page 3 of 28 Page 57 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31376 Analysis Method: 5210B-2015 Analysis Description: Biochemical Oxygen Demand (BOD) Glucose-Glutamic Acid GGA Result Range Analyzed Parameter Units Biochemical Oxygen Demand (5-day) Ng/L 206 167.5-228.E 03/25/23 08:25 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Biochemical Oxygen Demand (5-day) Ng/L 4000 3600 10.5 30 03/25/23 08:25 Date: 05/04/2023 01:09 PM Page 4 of 28 Page 58 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31271 Analysis Method: 5220D-2011 Analysis Description: Chemical Oxygen Demand (COD) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result COD (Chemical Oxygen Demand) pg/L <8000 8000 30000 03/28/23 10:31 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits COD (Chemical Oxygen Demand) pg/L 50000 54000 108 90-110 Matrix Spike & Matrix Spike Duplicate V 92332-MS V 92332-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. COD (Chemical Oxygen Demand) pg/L 17000 50000 50000 59000 57000 84.0 80.0 80-120 3.4 20 Date: 05/04/2023 01:09 PM Page 5 of 28 Page 59 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L675526 QC Analytical Batch(es): L675531 QC Prep Batch Method: 531OC-2011 Analysis Method: 531OC-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-675526 Matrix: AQU Associated Lab Samples: 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result TOC pg/L <682 682 1000 04/10/2312:41 Laboratory Control Sample LCS-1-675526 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC pg/L 5000 4810 96.0 85-115 Duplicate L 89981-DUP-L675526 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC pg/L 4730 4600 2.7 15 04/11/23 00:59 Matrix Spike L 89976-MS-1-675526 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC pg/L 3900 5260 9230 101 85-115 Date: 05/04/2023 01:09 PM Page 6 of 28 Page 60 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-L672669 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed Parameter Units Result Antimony pg/L <0.618 0.618 1.00 03/31/23 03:35 Arsenic pg/L <0.297 0.297 1.00 03/31/23 03:35 Barium pg/L <0.453 0.453 1.00 03/31/23 03:35 Beryllium pg/L <0.102 0.102 1.00 03/31/23 03:35 Cadmium pg/L <0.350 0.350 1.00 03/31/23 03:35 Chromium pg/L <0.346 0.346 1.00 03/31/23 03:35 Cobalt pg/L <0.060 0.060 1.00 03/31/23 03:35 Copper pg/L <0.489 0.489 1.00 03/31/23 03:35 Lead pg/L <0.264 0.264 1.00 03/31/23 03:35 Nickel pg/L <0.182 0.182 1.00 03/31/23 03:35 Selenium pg/L <0.703 0.703 1.00 03/31/23 03:35 Silver pg/L <0.0570 0.0570 1.00 03/31/23 03:35 Thallium pg/L <0.0610 0.0610 1.00 03/31/23 03:35 Vanadium pg/L <0.767 0.767 5.00 03/31/23 16:25 Zinc pg/L <4.67 4.67 10.0 03/31/23 03:35 Laboratory Control Sample LCS-L672669 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 98.2 98.0 80-120 Arsenic pg/L 50.0 46.9 94.0 80-120 Barium pg/L 100 95.3 95.0 80-120 Beryllium pg/L 50.0 52.2 104 80-120 Cadmium pg/L 10.0 9.60 96.0 80-120 Chromium pg/L 100 94.8 95.0 80-120 Cobalt pg/L 100 95.4 95.0 80-120 Copper pg/L 50.0 47.6 95.0 80-120 Date: 05/04/2023 01:09 PM Page 7 of 28 Page 61 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-1-672669 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 50.0 48.0 96.0 80-120 Nickel pg/L 50.0 47.4 95.0 80-120 Selenium pg/L 100 96.0 96.0 80-120 Silver pg/L 10.0 9.64 96.0 80-120 Thallium pg/L 10.0 9.57 96.0 80-120 Vanadium pg/L 500 463 93.0 80-120 Zinc pg/L 500 486 97.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92268-MS-L672669 MS Spike Result Conc. V 92268-MSD-L672669 MSD MS Result MSD Spike Result Conc. MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.618 100 100 96.3 94.7 96.0 95.0 75-125 1.6 20.0 Arsenic pg/L < 0.297 50.0 50.0 50.4 50.0 101 100 75-125 0.7 20.0 Barium pg/L 13.5 100 100 109 107 96.0 94.0 75-125 1.8 20.0 Beryllium pg/L < 0.102 50.0 50.0 47.5 47.5 95.0 95.0 75-125 0.0 20.0 Cadmium pg/L < 0.350 10.0 10.0 9.88 10.1 99.0 101 75-125 2.2 20.0 Chromium pg/L 0.840 100 100 98.5 100 98.0 99.0 75-125 1.5 20.0 Cobalt pg/L 0.235 100 100 99.1 101 99.0 101 75-125 1.8 20.0 Copper pg/L 0.860 50.0 50.0 50.5 51.4 99.0 101 75-125 1.7 20.0 Lead pg/L 0.285 50.0 50.0 49.6 49.4 99.0 98.0 75-125 0.4 20.0 Nickel pg/L 0.389 50.0 50.0 49.8 50.9 99.0 101 75-125 2.1 20.0 Selenium pg/L < 0.703 100 100 107 101 107 101 75-125 5.7 20.0 Silver pg/L < 0.0570 10.0 10.0 10.1 9.91 101 99.0 75-125 1.8 20.0 Thallium pg/L < 0.0610 10.0 10.0 9.83 9.84 98.0 98.0 75-125 0.1 20.0 Vanadium pg/L < 0.767 500 500 523 515 105 103 75-125 1.5 20.0 Zinc pg/L 9.75 500 500 509 509 100 100 75-125 0.0 20.0 Date: 05/04/2023 01:09 PM Page 8 of 28 Page 62 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 92268-PDS-L672669 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 45.5 91.0 03/31/23 05:24 Arsenic pg/L 25.2 101 03/31/23 05:24 Barium pg/L 53.9 95.0 03/31/23 05:24 Beryllium pg/L 24.0 96.0 03/31/2319:01 Cadmium pg/L 5.13 103 03/31/23 05:24 Chromium pg/L 49.8 99.0 03/31/23 05:24 Cobalt pg/L 50.2 100 03/31/23 05:24 Copper pg/L 25.7 101 03/31/23 05:24 Lead pg/L 24.3 97.0 03/31/23 05:24 Nickel pg/L 25.6 101 03/31/23 05:24 Selenium Ng/L 50.0 100 03/31/23 05:24 Silver pg/L 4.98 100 03/31/23 05:24 Thallium pg/L 5.10 102 03/31/23 05:24 Vanadium pg/L 259 104 03/31/23 19:01 Zinc pg/L 262 103 03/31/23 05:24 Date: 05/04/2023 01:09 PM Page 9 of 28 Page 63 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672903 QC Analytical Batch(es): L673329 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-1-672903 Matrix: AQU Associated Lab Samples: 92264, 92265 Parameter Units Blank Result MDL MQL Analyzed Dissolved Antimony pg/L <0.618 0.618 1.00 03/30/23 22:06 Dissolved Arsenic pg/L <0.297 0.297 1.00 03/30/23 22:06 Dissolved Barium pg/L <0.453 0.453 1.00 03/30/23 22:06 Dissolved Beryllium pg/L <0.102 0.102 1.00 03/30/23 22:06 Dissolved Cadmium pg/L <0.350 0.350 1.00 03/30/23 22:06 Dissolved Chromium pg/L <0.346 0.346 1.00 03/30/23 22:06 Dissolved Cobalt pg/L <0.060 0.060 1.00 03/30/23 22:06 Dissolved Copper pg/L <0.489 0.489 1.00 03/30/23 22:06 Dissolved Lead pg/L <0.264 0.264 1.00 03/30/23 22:06 Dissolved Nickel pg/L <0.182 0.182 1.00 03/30/23 22:06 Dissolved Selenium pg/L <0.703 0.703 1.00 03/30/23 22:06 Dissolved Silver pg/L <0.0570 0.0570 1.00 03/30/23 22:06 Dissolved Thallium pg/L <0.0610 0.0610 1.00 03/30/23 22:06 Dissolved Vanadium pg/L <0.767 0.767 5.00 03/30/23 22:06 Dissolved Zinc pg/L <4.67 4.67 10.0 03/30/23 22:06 Laboratory Control Sample & LCSD LCS-L672903 LCSD-L672903 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Dissolved Antimony pg/L 100 93.5 90.7 94.0 91.0 80-120 3.0 20.0 Dissolved Arsenic pg/L 50.0 50.4 48.7 101 97.0 80-120 3.4 20.0 Dissolved Barium pg/L 100 92.5 90.0 93.0 90.0 80-120 2.7 20.0 Dissolved Beryllium pg/L 50.0 50.9 49.1 102 98.0 80-120 3.6 20.0 Dissolved Cadmium pg/L 10.0 9.79 9.38 98.0 94.0 80-120 4.2 20.0 Dissolved Chromium pg/L 100 101 97.2 101 97.0 80-120 3.8 20.0 Dissolved Cobalt pg/L 100 103 97.5 103 98.0 80-120 5.4 20.0 Date: 05/04/2023 01:09 PM Page 10 of 28 Page 64 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672903 QC Analytical Batch(es): L673329 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample & LCSD LCS-1-672903 LCSD-L672903 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dissolved Copper pg/L 50.0 49.8 47.7 100 95.0 80-120 4.3 20.0 Dissolved Lead pg/L 50.0 49.3 47.8 99.0 96.0 80-120 3.0 20.0 Dissolved Nickel pg/L 50.0 50.9 49.0 102 98.0 80-120 3.8 20.0 Dissolved Selenium pg/L 100 104 100 104 100 80-120 3.9 20.0 Dissolved Silver pg/L 10.0 10.1 9.81 101 98.0 80-120 2.9 20.0 Dissolved Thallium pg/L 10.0 9.68 9.55 97.0 96.0 80-120 1.3 20.0 Dissolved Vanadium pg/L 500 490 473 98.0 95.0 80-120 3.5 20.0 Dissolved Zinc pg/L 500 509 489 102 98.0 80-120 4.0 20.0 Date: 05/04/2023 01:09 PM Page 11 of 28 Page 65 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672722 QC Analytical Batch(es): L672893 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-672722 Matrix: AQU Associated Lab Samples: 92263, 92264 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 03/29/23 11:22 Laboratory Control Sample LCS-1-672722 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 4.69 94.0 80-120 Matrix Spike & Matrix Spike Duplicate V 92264-MS-L672722 V 92264-MSD-L672722 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 4.28 3.56 86.0 71.0* 80-120 18.3 20 Post Digestion Spike V 92264-PDS-L672722 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.17 83.0* 03/29/23 12:04 * QC Fail Date: 05/04/2023 01:09 PM Page 12 of 28 Page 66 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672943 QC Analytical Batch(es): L673177 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-672943 Matrix: AQU Associated Lab Samples: 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result Dissolved Mercury pg/L <0.130 0.130 0.200 03/30/23 11:18 Laboratory Control Sample & LCSD LCS-1-672943 LCSD-L672943 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Dissolved Mercury pg/L 5.00 5.41 5.27 108 105 80-120 2.6 20 Date: 05/04/2023 01:09 PM Page 13 of 28 Page 67 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L673565 QC Analytical Batch(es): L673738 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-L673565 Matrix: AQU Associated Lab Samples: 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 04/03/23 12:32 Laboratory Control Sample LCS-1-673565 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 5.22 104 80-120 Matrix Spike & Matrix Spike Duplicate V 92268-MS-L673565 V 92268-MSD-L673565 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 5.08 5.66 102 113 80-120 10.8 20 Post Digestion Spike V 92268-PDS-L673565 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.79 96.0 04/03/23 13:03 Date: 05/04/2023 01:09 PM Page 14 of 28 Page 68 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31322 QC Analytical Batch(es): V31323 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31322 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/28/2311:03 4-Bromofluorobenzene (S) 03/28/23 11:03 103 70-130 Laboratory Control Sample LCS-V31322 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 49.2 98.4 70-130 4-Bromofluorobenzene (S) 128 70-130 Matrix Spike & Matrix Spike Duplicate V 92268-MS-V31322 V 92268-MSD-V31322 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. 1,4-Dioxane pg/L < 0.139 50.0 50.0 46.7 48.4 93.4 96.8 70-130 3.5 20.0 4-Bromofluorobenzene (S) 104 111 70-130 Date: 05/04/2023 01:09 PM Page 15 of 28 Page 69 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31669 Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 QC Analytical Batch(es): V31670 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/05/23 14:55 Acrylonitrile pg/L <0.230 0.230 5.00 04/05/23 14:55 Benzene pg/L <0.180 0.180 0.500 04/05/23 14:55 Bromochloromethane pg/L <0.420 0.420 1.00 04/05/23 14:55 Bromodichloromethane pg/L <0.160 0.160 0.500 04/05/23 14:55 Bromoform pg/L <1.50 1.50 5.00 04/05/23 14:55 Bromomethane pg/L <0.280 0.280 1.00 04/05/23 14:55 Carbon Disulfide pg/L <0.150 0.150 5.00 04/05/23 14:55 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/05/23 14:55 Chlorobenzene pg/L <0.190 0.190 0.500 04/05/23 14:55 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/05/23 14:55 Chloroethane pg/L <0.430 0.430 1.00 04/05/23 14:55 Chloroform pg/L <0.220 0.220 0.500 04/05/23 14:55 Chloromethane pg/L <0.220 0.220 0.500 04/05/23 14:55 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/05/23 14:55 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/05/23 14:55 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/05/23 14:55 Dibromomethane pg/L <0.230 0.230 0.500 04/05/23 14:55 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/05/23 14:55 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/05/23 14:55 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/05/23 14:55 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/05/23 14:55 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/05/23 14:55 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/05/23 14:55 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/05/23 14:55 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/05/23 14:55 Date: 05/04/2023 01:09 PM Page 16 of 28 Page 70 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31669 Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 QC Analytical Batch(es): V31670 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/05/23 14:55 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/05/23 14:55 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/05/23 14:55 1,4-Dioxane pg/L <16.0 16.0 150 04/05/23 14:55 Ethylbenzene pg/L <0.170 0.170 0.500 04/05/23 14:55 2-Hexanone pg/L <0.380 0.380 5.00 04/05/23 14:55 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/05/23 14:55 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/05/23 14:55 Methylene Chloride pg/L <0.330 0.330 1.00 04/05/23 14:55 Styrene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 Tetrachloroethene pg/L <0.220 0.220 0.500 04/05/23 14:55 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/05/23 14:55 Toluene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/05/23 14:55 Trichloroethene pg/L <0.180 0.180 0.500 04/05/23 14:55 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/05/23 14:55 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/05/23 14:55 Vinyl Acetate pg/L <1.00 1.00 2.00 04/05/23 14:55 Vinyl Chloride pg/L <0.170 0.170 0.500 04/05/23 14:55 o-Xylene pg/L <0.210 0.210 0.500 04/05/23 14:55 m,p-Xylene pg/L <0.420 0.420 1.00 04/05/23 14:55 4-Bromofluorobenzene (S) 04/05/23 14:55 105 80-124 Dibromofluoromethane (S) 04/05/23 14:55 98.4 75-129 1,2-Dichloroethane - d4 (S) 04/05/23 14:55 100 63-136 Date: 05/04/2023 01:09 PM Page 17 of 28 Page 71 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31669 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/05/23 14:55 104 77-123 Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 35.9 33.5 89.7 83.7 40-166 6.9 20.0 Acrylonitrile pg/L 40.0 44.7 43.0 112 108 81-127 3.8 20.0 Benzene pg/L 20.0 22.5 22.9 113 115 77-128 1.7 20.0 Bromochloromethane pg/L 20.0 22.3 22.4 112 112 78-135 0.4 20.0 Bromodichloromethane pg/L 20.0 23.5 23.4 118 117 76-138 0.4 20.0 Bromoform pg/L 20.0 22.6 23.3 113 117 71-135 3.0 20.0 Bromomethane pg/L 20.0 18.1 20.0 90.5 100 41-168 9.9 20.0 Carbon Disulfide pg/L 20.0 23.3 24.3 117 122 59-135 4.2 20.0 Carbon Tetrachloride pg/L 20.0 23.7 24.7 119 124 72-142 4.1 20.0 Chlorobenzene pg/L 20.0 22.5 22.5 113 113 78-119 0.0 20.0 Chlorodibromomethane pg/L 20.0 23.8 23.7 119 119 75-134 0.4 20.0 Chloroethane pg/L 20.0 20.1 21.0 101 105 57-142 4.3 20.0 Chloroform pg/L 20.0 22.9 23.5 115 118 77-130 2.5 20.0 Chloromethane pg/L 20.0 19.8 19.3 99.0 96.5 47-145 2.5 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 23.6 23.9 118 120 60-154 1.2 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 25.4 24.3 127 122 63-134 4.4 20.0 1,2-Dibromoethane pg/L 20.0 24.5 24.0 123 120 77-135 2.0 20.0 Dibromomethane pg/L 20.0 22.9 23.1 115 116 76-138 0.8 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 17.2 17.1 86.0 85.5 70-130 0.5 20.0 1,2-Dichlorobenzene pg/L 20.0 23.1 23.8 116 119 78-128 2.9 20.0 1,4-Dichlorobenzene pg/L 20.0 22.1 23.3 111 117 75-126 5.2 20.0 Date: 05/04/2023 01:09 PM Page 18 of 28 Page 72 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 22.9 24.0 115 120 28-163 4.6 20.0 1,1-Dichloroethane pg/L 20.0 23.0 23.7 115 119 70-130 2.9 20.0 1,2-Dichloroethane pg/L 20.0 23.7 23.2 119 116 68-131 2.1 20.0 1,1-Dichloroethene pg/L 20.0 24.0 25.8 120 129 70-154 7.2 20.0 cis-1,2-Dichloroethene pg/L 20.0 23.0 23.5 115 118 76-141 2.1 20.0 trans-1,2-Dichloroethene pg/L 20.0 23.0 23.5 115 118 76-135 2.1 20.0 1,2-Dichloropropane pg/L 20.0 23.5 23.8 118 119 77-130 1.2 20.0 cis-1,3-Dichloropropene pg/L 20.0 24.1 23.5 121 118 65-140 2.5 20.0 trans-1,3-Dichloropropene pg/L 20.0 25.6 24.4 128 122 67-140 4.8 20.0 1,4-Dioxane pg/L 200 266 244 133* 122 70-130 8.6 20.0 Ethylbenzene pg/L 20.0 22.4 22.8 112 114 80-127 1.7 20.0 2-Hexanone pg/L 20.0 25.3 23.3 127 117 64-137 8.2 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.9 19.3 99.5 96.5 71-134 3.0 20.0 4-M ethyl-2-Pentanone pg/L 20.0 25.9 24.5 130 123 69-134 5.5 20.0 Methylene Chloride pg/L 20.0 21.7 21.8 109 109 73-131 0.4 20.0 Styrene pg/L 20.0 22.4 24.0 112 120 78-129 6.8 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 23.2 22.7 116 114 79-134 2.1 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 25.2 25.7 126 129* 62-127 1.9 20.0 Tetrachloroethene pg/L 20.0 22.7 22.5 114 113 80-129 0.8 20.0 Tetrahydrofuran pg/L 20.0 24.3 21.7 122 109 70-130 11.3 20.0 Toluene pg/L 20.0 23.5 23.6 118 118 76-131 0.4 20.0 1,1,1-Trichloroethane pg/L 20.0 23.0 23.8 115 119 75-135 3.4 20.0 1,1,2-Trichloroethane pg/L 20.0 24.4 23.8 122 119 70-140 2.4 20.0 Trichloroethene pg/L 20.0 22.3 22.5 112 113 77-133 0.8 20.0 Trichlorofluoromethane pg/L 20.0 22.5 23.5 113 118 62-148 4.3 20.0 1,2,3-Trichloropropane pg/L 20.0 23.5 24.4 118 122 71-127 3.7 20.0 * QC Fail Date: 05/04/2023 01:09 PM Page 19 of 28 Page 73 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Acetate pg/L 20.0 24.7 23.4 124 117 34-167 5.4 20.0 Vinyl Chloride pg/L 20.0 23.1 23.7 116 119 57-141 2.5 20.0 o-Xylene pg/L 20.0 22.5 23.9 113 120 78-128 6.0 20.0 m,p-Xylene pg/L 40.0 45.8 48.6 115 122 77-133 5.9 20.0 4-Bromofluorobenzene (S) 107 107 80-124 Dibromofluoromethane (S) 104 102 75-129 1,2-Dichloroethane - d4 (S) 109 107 63-136 Toluene-d8(S) 103 103 77-123 Date: 05/04/2023 01:09 PM Page 20 of 28 Page 74 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Prep Batch Method: 5030B QC Analytical Batch(es): V31704 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/06/23 03:17 Acrylonitrile pg/L <0.230 0.230 5.00 04/06/23 03:17 Benzene pg/L <0.180 0.180 0.500 04/06/23 03:17 Bromochloromethane pg/L <0.420 0.420 1.00 04/06/23 03:17 Bromodichloromethane pg/L <0.160 0.160 0.500 04/06/23 03:17 Bromoform pg/L <1.50 1.50 5.00 04/06/23 03:17 Bromomethane pg/L <0.280 0.280 1.00 04/06/23 03:17 Carbon Disulfide pg/L <0.150 0.150 5.00 04/06/23 03:17 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/06/23 03:17 Chlorobenzene pg/L <0.190 0.190 0.500 04/06/23 03:17 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/06/23 03:17 Chloroethane pg/L <0.430 0.430 1.00 04/06/23 03:17 Chloroform pg/L <0.220 0.220 0.500 04/06/23 03:17 Chloromethane pg/L <0.220 0.220 0.500 04/06/23 03:17 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/06/23 03:17 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/06/23 03:17 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/06/23 03:17 Dibromomethane pg/L <0.230 0.230 0.500 04/06/23 03:17 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/06/23 03:17 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/06/23 03:17 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/06/23 03:17 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/06/23 03:17 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/06/23 03:17 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/06/23 03:17 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/06/23 03:17 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/06/23 03:17 Date: 05/04/2023 01:09 PM Page 21 of 28 Page 75 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/06/23 03:17 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/06/23 03:17 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/06/23 03:17 Ethylbenzene pg/L <0.170 0.170 0.500 04/06/23 03:17 2-Hexanone pg/L <0.380 0.380 5.00 04/06/23 03:17 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/06/23 03:17 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/06/23 03:17 Methylene Chloride pg/L <0.330 0.330 1.00 04/06/23 03:17 Styrene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 Tetrachloroethene pg/L <0.220 0.220 0.500 04/06/23 03:17 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/06/23 03:17 Toluene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/06/23 03:17 Trichloroethene pg/L <0.180 0.180 0.500 04/06/23 03:17 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/06/23 03:17 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/06/23 03:17 Vinyl Acetate pg/L <1.00 1.00 2.00 04/06/23 03:17 Vinyl Chloride pg/L <0.170 0.170 0.500 04/06/23 03:17 o-Xylene pg/L <0.210 0.210 0.500 04/06/23 03:17 m,p-Xylene pg/L <0.420 0.420 1.00 04/06/23 03:17 4-Bromofluorobenzene (S) 04/06/23 03:17 104 80-124 Dibromofluoromethane (S) 04/06/23 03:17 99.0 75-129 1,2-Dichloroethane - d4 (S) 04/06/23 03:17 100 63-136 Date: 05/04/2023 01:09 PM Page 22 of 28 Page 76 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8(S) 04/06/23 03:17 103 77-123 Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits Acetone pg/L 40.0 38.6 36.2 96.5 90.5 40-166 Acrylonitrile pg/L 40.0 48.2 46.1 121 115 81-127 Benzene pg/L 20.0 21.6 22.5 108 113 77-128 Bromochloromethane pg/L 20.0 21.7 21.7 109 109 78-135 Bromodichloromethane pg/L 20.0 22.9 22.8 115 114 76-138 Bromoform pg/L 20.0 23.3 22.6 117 113 71-135 Bromomethane pg/L 20.0 18.2 21.1 91.0 106 41-168 Carbon Disulfide pg/L 20.0 21.5 23.0 108 115 59-135 Carbon Tetrachloride pg/L 20.0 21.8 23.4 109 117 72-142 Chlorobenzene pg/L 20.0 21.5 22.5 108 113 78-119 Chlorodibromomethane pg/L 20.0 23.3 23.7 117 119 75-134 Chloroethane pg/L 20.0 19.1 19.8 95.5 99.0 57-142 Chloroform pg/L 20.0 21.9 22.6 110 113 77-130 Chloromethane pg/L 20.0 19.1 20.5 95.5 103 47-145 Di -Isopropyl Ether (DIPE) pg/L 20.0 23.5 23.4 118 117 60-154 1,2-Dibromo-3-Chloropropane pg/L 20.0 25.5 23.7 128 119 63-134 1,2-Dibromoethane pg/L 20.0 24.0 23.3 120 117 77-135 Dibromomethane pg/L 20.0 22.7 21.8 114 109 76-138 trans-1,4-Dichloro-2-butene pg/L 20.0 16.7 15.9 83.5 79.5 70-130 1,2-Dichlorobenzene pg/L 20.0 23.0 22.8 115 114 78-128 1,4-Dichlorobenzene pg/L 20.0 22.5 22.6 113 113 75-126 RPD Max RPD 6.4 20.0 4.4 20.0 4.0 20.0 0.0 20.0 0.4 20.0 3.0 20.0 14.7 20.0 6.7 20.0 7.0 20.0 4.5 20.0 1.7 20.0 3.5 20.0 3.1 20.0 7.0 20.0 0.4 20.0 7.3 20.0 2.9 20.0 4.0 20.0 4.9 20.0 0.8 20.0 0.4 20.0 Date: 05/04/2023 01:09 PM Page 77 of 84 Page 23 of 28 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 21.0 22.1 105 111 28-163 5.1 20.0 1,1-Dichloroethane pg/L 20.0 21.7 22.8 109 114 70-130 4.9 20.0 1,2-Dichloroethane pg/L 20.0 22.6 22.3 113 112 68-131 1.3 20.0 1,1-Dichloroethene pg/L 20.0 22.3 23.8 112 119 70-154 6.5 20.0 cis-1,2-Dichloroethene pg/L 20.0 21.8 22.7 109 114 76-141 4.0 20.0 trans-1,2-Dichloroethene pg/L 20.0 21.2 22.8 106 114 76-135 7.2 20.0 1,2-Dichloropropane pg/L 20.0 22.6 22.9 113 115 77-130 1.3 20.0 cis-1,3-Dichloropropene pg/L 20.0 22.3 22.2 112 111 65-140 0.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 23.8 22.3 119 112 67-140 6.5 20.0 Ethylbenzene pg/L 20.0 20.6 22.2 103 111 80-127 7.4 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 21.2 20.0 106 100 71-134 5.8 20.0 4-Methyl-2-Pentanone pg/L 20.0 28.2 24.2 141* 121 69-134 15.2 20.0 Methylene Chloride pg/L 20.0 20.9 21.4 105 107 73-131 2.3 20.0 Styrene pg/L 20.0 20.9 22.7 105 114 78-129 8.2 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 21.7 23.0 109 115 79-134 5.8 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 24.5 22.4 123 112 62-127 8.9 20.0 Tetrachloroethene pg/L 20.0 21.1 22.9 106 115 80-129 8.1 20.0 Tetrahydrofuran pg/L 20.0 25.6 23.5 128 118 70-130 8.5 20.0 Toluene pg/L 20.0 22.2 22.5 111 113 76-131 1.3 20.0 1,1,1-Trichloroethane pg/L 20.0 21.3 22.8 107 114 75-135 6.8 20.0 1,1,2-Trichloroethane pg/L 20.0 24.9 22.4 125 112 70-140 10.5 20.0 Trichloroethene pg/L 20.0 22.3 23.6 112 118 77-133 5.6 20.0 Trichlorofluoromethane pg/L 20.0 21.2 22.4 106 112 62-148 5.5 20.0 1,2,3-Trichloropropane pg/L 20.0 23.9 21.3 120 107 71-127 11.5 20.0 Vinyl Acetate pg/L 20.0 18.9 15.6 94.5 78.0 34-167 19.1 20.0 Vinyl Chloride pg/L 20.0 21.1 22.3 106 112 57-141 5.5 20.0 * QC Fail Date: 05/04/2023 01:09 PM Page 24 of 28 Page 78 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD o-Xylene pg/L 20.0 21.1 23.2 106 116 78-128 9.4 20.0 m,p-Xylene pg/L 40.0 43.2 46.9 108 117 77-133 8.2 20.0 4-Bromofluorobenzene (S) 105 104 80-124 Dibromofluoromethane (S) 102 101 75-129 1,2-Dichloroethane - d4 (S) 112 107 63-136 Toluene-d8(S) 104 106 77-123 Date: 05/04/2023 01:09 PM Page 25 of 28 Page 79 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31254 QC Analytical Batch(es): V31261 QC Prep Batch Method: SW-9056A (PREP) Analysis Method: 9056A Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V31254 Matrix: AQU Associated Lab Samples: 92263, 92265 Blank MDL MQL Analyzed Parameter Units Result Chloride pg/L <370 370 1000 03/25/23 09:23 Nitrate (NO3-N) pg/L <76.0 76.0 200 03/25/23 09:23 Sulfate pg/L <650 650 2000 03/25/23 09:23 Laboratory Control Sample LCS-V31254 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride pg/L 40000 41300 103 80-120 Nitrate (NO3-N) pg/L 4000 4170 104 80-120 Sulfate pg/L 40000 38700 97.0 80-120 Matrix Spike & Matrix Spike Duplicate V 92265-MS-V31254 V 92265-MSD-V31254 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride pg/L 72000 40000 40000 112000 112000 100 100 80-120 0.0 20 Nitrate (NO3-N) pg/L <79.0 4000 4000 4710 4630 118 116 80-120 1.7 20 Sulfate pg/L <676 40000 40000 38900 39700 97.0 99.0 80-120 2.0 20 Date: 05/04/2023 01:09 PM Page 26 of 28 Page 80 of 84 • Charlotte, NC 28217 Waypoint, 449 Springbrook Rd, Ch Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672614 QC Analytical Batch(es): L673139 QC Prep Batch Method: EPA-200.7 (PREP) Analysis Method: EPA-200.7 Analysis Description: Total Metals Lab Reagent Blank LRB-1-672614 Matrix: AQU Associated Lab Samples: 92266, 92267, 92268 Blank MQL Analyzed Parameter Units Result Calcium pg/L <100 100 03/29/2319:53 Magnesium pg/L <100 100 03/29/2319:53 Laboratory Control Sample LCS-1-672614 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Calcium pg/L 10000 10800 108 85-115 Magnesium pg/L 10000 10200 102 85-115 Matrix Spike & Matrix Spike Duplicate G 60040-MS-1-672614 G 60040-MSD-L672614 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Calcium pg/L 6470 10000 10000 16600 16500 101 100 70-130 0.6 20 Magnesium pg/L 2180 10000 10000 11800 11700 96.0 95.0 70-130 0.8 20 Post Digestion Spike G 60040-PDS-L672614 PDS % Analyzed Parameter Units Result Recovery Calcium pg/L 28400 101 03/29/23 22:10 Magnesium pg/L 25300 97.0 03/29/23 22:10 Date: 05/04/2023 01:09 PM Page 27 of 28 Page 81 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31279 Analysis Method: SM-3500-Fe-13 Analysis Description: Ferrous Iron Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92265 Blank MDL MQL Analyzed Parameter Units Result Ferrous Iron pg/L <50.0 50.0 200 03/27/23 17:15 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ferrous Iron pg/L 2000 1980 99.0 90-110 Matrix Spike & Matrix Spike Duplicate V 92263-MS V 92263-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ferrous Iron pg/L 8340 50000 50000 49000 48600 81.0 81.0 80-120 0.8 20 Date: 05/04/2023 01:09 PM Page 28 of 28 Page 82 of 84 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 23-084-0001 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT15 II AC Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Angelo Norvell Date & Time: 03/25/2023 10:36:27 Page 83 of 84 r- (n Q� 3 3� ji ro a6 w �a m C a� � c O _? m m � n 'm 0 m-M w z 0 a ,a i 'b 11111110 943, %.. .11 '4010 mills IN 011mmmilm 11111311 NEW C N v x p m 0 a v a o > n 3 rot m Z 2► m Z 4 m Q m ,- 0 .CL ,nn� Ram n N � J 3 o n e a c v o a cai a 0 c °c N e� m m jp m toN H' A M. ap T— -- w p N c C D w s❑ D m lam o> CL m y• i n �m y Tdx xW m � imp q v-°-CvQ S W o C a Y Fr{ x❑ + IL w jp m N x y Mr 7 N n m �m m a L 0 m m a r m n o v ❑ N A rI E H�a�as wa ono r`m m 0 m m vC CD m�0�m �Aw n w m I mm 0 o r m a p A OF ens n o o m ra U) o M C vain'zmn N m r! 3 o z C m � O remit I~ u0 N re2��� m o m m IF 3 x T n` ` I I a �F, n I I r n Page 84 of 84 Waypointo ANALYTICAL 4/25/2023 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville, NC, 28801 Ref: Analytical Testing Lab Report Number: 23-089-0004 Client Project Description: Jackson County Landfill Site: Jackson Project Number: C21480-01.01 Dear Jessica Mayers: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/30/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 72 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2023 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2023 South Carolina State Program 99012 12/31/2022 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00016/23-089-0004 Page 2 of 72 Waypoint.(2) ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Sample Summary Table Report Number: 23-089-0004 Client Project Description: Jackson County Landfill Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 AM23G Pace -LA 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 AM20GAX Pace -LA 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 RSK-175 Pace -LA 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 6020B WP MTN 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 7470A WP MTN 92551 MW-04-20230328 Aqueous 03/28/2023 15:50 03/30/2023 10:20 531OC-2011 WP MTN 92552 DW-01-20230328 Aqueous 03/28/2023 12:36 03/30/2023 10:20 524.2 92553 DW-02-20230328 Aqueous 03/28/2023 13:25 03/30/2023 10:20 524.2 92554 LT-01-20240328 Aqueous 03/28/2023 11:27 03/30/2023 10:20 92554 LT-01-20240328 Aqueous 03/28/2023 11:27 03/30/2023 10:20 6020E WP MTN 92555 MW-03-20230328 Aqueous 03/28/2023 19:13 03/30/2023 10:20 AM20GAX Pace -LA 92556 MW-07-20230328 Aqueous 03/28/2023 14:54 03/30/2023 10:20 92557 MW-06-20230328 Aqueous 03/28/2023 11:09 03/30/2023 10:20 92558 TB-20230328 Aqueous 03/28/2023 03/30/2023 10:20 : Pace Analytical - Huntersville, NC, Huntersville, NC Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 72 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 AN LYT I CAL www.waypointanalytica Isom Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-089-0004 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed MW-04-20230328 V 92551 2320B-2011 Alkalinity (as CaCO3) 106000 pg/L 800 03/31/2023 16:00 4500S2F-2011 Sulfide 17300 pg/L 970 03/30/202311:50 5220D-2011 COD (Chemical Oxygen Demand) 16000 pg/L 8000 04/05/2023 10:40 5310C-2011 TOC 2.29 mg/L 0.682 04/08/2023 05:17 6020E Arsenic 0.388 pg/L 0.297 04/04/2023 02:58 6020E Barium 42.1 pg/L 0.453 04/04/2023 02:58 6020E Cobalt 0.526 pg/L 0.060 04/04/2023 02:58 6020E Copper 0.952 pg/L 0.489 04/04/2023 02:58 6020E Lead 0.516 pg/L 0.264 04/04/2023 02:58 6020E Nickel 2.10 pg/L 0.182 04/04/2023 02:58 6020E Zinc 4.67 pg/L 4.67 04/04/2023 02:58 8260D 1,4-Dichlorobenzene 1.94 Ng/L 0.210 04/10/202318:23 8260D cis- 1,2-Dichloroethene 0.471 pg/L 0.200 04/10/202318:23 8260D Vinyl Chloride 0.210 pg/L 0.170 04/10/2023 18:23 8260D SIM 1,4-Dioxane 5.04 pg/L 0.139 03/30/2023 14:15 9056A Chloride 54100 pg/L 370 03/30/202313:41 9056A Nitrate (NO3-N) 2580 pg/L 76.0 03/30/2023 13:41 9056A Sulfate 94900 pg/L 650 03/30/202313:41 LT-01-20240328 V 92554 6020B Arsenic 15.4 pg/L 2.97 04/03/202317:21 6020B Barium 1260 pg/L 4.53 04/03/202317:21 6020B Chromium 20.3 pg/L 3.46 04/03/202317:21 6020B Cobalt 9.39 pg/L 0.600 04/03/202317:21 6020B Copper 8.50 pg/L 4.89 04/03/202317:21 6020B Lead 3.03 pg/L 2.64 04/03/202317:21 6020B Nickel 34.3 pg/L 1.82 04/03/202317:21 6020B Vanadium 26.5 pg/L 7.67 04/03/202317:21 8260D 1,4-Dichlorobenzene 2.34 pg/L 2.10 04/07/2023 21:55 8260D cis- 1,2-Dichloroethene 2.16 pg/L 2.00 04/07/2023 21:55 8260D Tetrahydrofuran 95.7 pg/L 15.0 04/07/2023 21:55 8260D SIM 1,4-Dioxane 48.7 pg/L 0.139 03/30/2023 14:40 MW-07-20230328 V 92556 2320E-2011 Alkalinity (as CaCO3) 308000 pg/L 800 03/31/2023 16:00 9056A Chloride 92500 pg/L 370 03/30/202313:25 9056A Sulfate 21800 pg/L 650 03/30/202313:25 Qualifiers I I Page 4 of 72 Waypointo ANALYTICAL Client: Anchor QEA of North Carolina, PLLC Project: Jackson County Landfill Lab Report Number: 23-089-0004 Date: 4/25/2023 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com CASE NARRATIVE Metals Analyses Method 6020B Sample 92554 (LT-01-20240328) QC Batch No: L673886/L673485 Based on sample screening, a dilution was performed due to high levels of target and/or non -target analytes. Reporting limits have been adjusted accordingly. Sample 92554 (LT-01-20240328) Analyte: Barium QC Batch No: L673886/L673485 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Volatile Organic Compounds - GUMS Method 8260D Sample 92554 (LT-01-20240328) QC Batch No: V31828/V31827 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Analyte: 1,4-Dioxane QC Batch No: V31828/V31827 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichloropropane QC Batch No: V31828/V31886 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 2-Hexanone QC Batch No: V31828/V31886 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 2-Hexanone QC Batch No: V31828/V31886 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: 4-Methyl-2-pentanone QC Batch No: V31828/V31886 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Page 5 of 72 Waypointo ANALYTICAL 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Analyte: Acetone QC Batch No: V31828/V31886 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Acrylonitrile QC Batch No: V31828/V31886 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V31828/V31886 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: trans-1,4-Dichloro-2-butene QC Batch No: V31887/V31886 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Page 6 of 72 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-089-0004 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 04/25/2023 Received : 03/30/2023 Lab No : 92551 Matrix: Aqueous Sample ID: MW-04-20230328 Sampled: 3/28/2023 15:50 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <0.05 H mg/L 0.05 0.20 1 03/30/23 17:00 SLO SM-3500-Fe-B 1,4-Dioxane 5.04 ug/L 0.139 2.00 1 03/30/23 14:15 TBL 8260D SIM Alkalinity (as CaCO3) 106000 Ng/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 ug/L 2000 2000 1 03/30/23 12:40 SLO 521OB-2015 Chloride 54100 Ng/L 370 1000 1 03/30/2313:41 CM] 9056A COD (Chemical Oxygen Demand) 16000 J ug/L 8000 30000 1 04/05/23 10:40 SMW 5220D-2011 Nitrate (NO3-N) 2580 Ng/L 76.0 200 1 03/30/23 13:41 CM] 9056A TOC 2.29 mg/L 0.682 1.00 1 04/08/23 05:17 SRJ 531OC-2011 Sulfate 94900 Ng/L 650 2000 1 03/30/2313:41 CM] 9056A Sulfide 17300 ug/L 970 2350 1 03/30/2311:50 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 04/04/23 02:58 CPW 6020B Arsenic 0.3883 ug/L 0.297 1.00 1 04/04/23 02:58 CPW 6020B Barium 42.1 Ng/L 0.453 1.00 1 04/04/23 02:58 CPW 6020B Beryllium <0.102 ug/L 0.102 1.00 1 04/04/23 22:35 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 04/04/23 02:58 CPW 6020B Chromium <0.346 ug/L 0.346 1.00 1 04/04/23 22:35 CPW 6020B Cobalt 0.526 J Ng/L 0.060 1.00 1 04/04/23 02:58 CPW 6020B Copper 0.9523 ug/L 0.489 1.00 1 04/04/23 02:58 CPW 6020B Lead 0.516 J Ng/L 0.264 1.00 1 04/04/23 02:58 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/04/23 14:10 FDS 7470A Nickel 2.10 Ng/L 0.182 1.00 1 04/04/23 02:58 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 04/04/23 02:58 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 04/04/23 02:58 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 7 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92551 Sample ID: MW-04-20230328 Matrix: Aqueous Sampled: 3/28/2023 15:50 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium <0.0610 Ng/L 0.0610 1.00 1 04/04/23 02:58 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 04/04/23 22:35 CPW 6020B Zinc 4.673 Ng/L 4.67 10.0 1 04/04/23 02:58 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 8 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92551 Matrix: Aqueous Sample ID: MW-04-20230328 Sampled: 3/28/2023 15:50 Analytical Method: 8260D Prep Batch(es): V31886 04/10/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/10/23 18:23 MSA V31887 Acrylonitrile <0.230 pg/L 0.230 5.00 1 04/10/23 18:23 MSA V31887 Benzene <0.180 Ng/L 0.180 0.500 1 04/10/23 18:23 MSA V31887 Bromochloromethane <0.420 pg/L 0.420 1.00 1 04/10/23 18:23 MSA V31887 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/10/23 18:23 MSA V31887 Bromoform <1.50 pg/L 1.50 5.00 1 04/10/23 18:23 MSA V31887 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/10/23 18:23 MSA V31887 Carbon Disulfide <0.150 pg/L 0.150 5.00 1 04/10/23 18:23 MSA V31887 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/10/23 18:23 MSA V31887 Chlorobenzene <0.190 pg/L 0.190 0.500 1 04/10/23 18:23 MSA V31887 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/10/23 18:23 MSA V31887 Chloroethane <0.430 pg/L 0.430 1.00 1 04/10/23 18:23 MSA V31887 Chloroform <0.220 Ng/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 Chloromethane <0.220 pg/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/10/23 18:23 MSA V31887 1,2-Dibromo-3-Chloropropane <1.10 pg/L 1.10 2.00 1 04/10/23 18:23 MSA V31887 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/10/23 18:23 MSA V31887 Dibromomethane <0.230 pg/L 0.230 0.500 1 04/10/23 18:23 MSA V31887 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/10/23 18:23 MSA V31887 1,2-Dichlorobenzene <0.220 pg/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 1,4-Dichlorobenzene 1.94 Ng/L 0.210 0.500 1 04/10/23 18:23 MSA V31887 Dichlorodifluoromethane <1.20 pg/L 1.20 5.00 1 04/10/23 18:23 MSA V31887 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 9 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92551 Matrix: Aqueous Sample ID: MW-04-20230328 Sampled: 3/28/2023 15:50 Analytical Method: 8260D Prep Batch(es): V31886 04/10/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/10/23 18:23 MSA V31887 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/10/23 18:23 MSA V31887 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/10/23 18:23 MSA V31887 cis- 1,2-Dich loroethene 0.471 J ug/L 0.200 0.500 1 04/10/23 18:23 MSA V31887 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/10/23 18:23 MSA V31887 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/10/23 18:23 MSA V31887 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/10/23 18:23 MSA V31887 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/10/23 18:23 MSA V31887 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/10/23 18:23 MSA V31887 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/10/23 18:23 MSA V31887 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/10/23 18:23 MSA V31887 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/10/23 18:23 MSA V31887 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/10/23 18:23 MSA V31887 Styrene <0.220 ug/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/10/23 18:23 MSA V31887 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/10/23 18:23 MSA V31887 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/10/23 18:23 MSA V31887 Toluene <0.220 Ng/L 0.220 0.500 1 04/10/23 18:23 MSA V31887 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/10/23 18:23 MSA V31887 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/10/23 18:23 MSA V31887 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/10/23 18:23 MSA V31887 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 10 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92551 Matrix: Aqueous Sample ID: MW-04-20230328 Sampled: 3/28/2023 15:50 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride 0.2103 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31886 04/10/23 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 104 Limits: 80-124% 98.8 Limits: 75-129% 95.4 Limits: 63-136% 96.6 Limits: 77-123% 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 1 04/10/23 18:23 MSA V31887 H Beyond holding time MQL Method Quantitation Limit Page 11 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92554 Sample ID: LT-01-20240328 Matrix: Aqueous Sampled: 3/28/2023 11:27 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 48.7 Ng/L 0.139 2.00 1 03/30/23 14:40 TBL 8260D SIM Antimony <6.18 ug/L 6.18 10.0 10 04/03/23 17:21 CPW 6020B Arsenic 15.4 Ng/L 2.97 10.0 10 04/03/23 17:21 CPW 6020B Barium 1260 ug/L 4.53 10.0 10 04/03/23 17:21 CPW 6020B Beryllium <1.02 Ng/L 1.02 10.0 10 04/03/23 17:21 CPW 6020B Cadmium <3.50 ug/L 3.50 10.0 10 04/03/23 17:21 CPW 6020B Chromium 20.3 Ng/L 3.46 10.0 10 04/03/23 17:21 CPW 6020E Cobalt 9.393 ug/L 0.600 10.0 10 04/03/23 17:21 CPW 6020B Copper 8.503 Ng/L 4.89 10.0 10 04/03/23 17:21 CPW 6020B Lead 3.033 ug/L 2.64 10.0 10 04/03/23 17:21 CPW 6020B Nickel 34.3 Ng/L 1.82 10.0 10 04/03/23 17:21 CPW 6020B Selenium <7.03 ug/L 7.03 10.0 10 04/03/23 17:21 CPW 6020B Silver <0.570 Ng/L 0.570 10.0 10 04/03/23 17:21 CPW 6020E Thallium <0.610 ug/L 0.610 10.0 10 04/03/23 17:21 CPW 6020B Vanadium 26.53 Ng/L 7.67 50.0 10 04/03/23 17:21 CPW 6020B Zinc <46.7 ug/L 46.7 100 10 04/03/23 17:21 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 12 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92554 Matrix: Aqueous Sample ID: LT-01-20240328 Sampled: 3/28/2023 11:27 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <18.0 Ng/L 18.0 50.0 10 04/07/23 21:55 MSA V31828 Acrylonitrile <2.30 ug/L 2.30 50.0 10 04/07/23 21:55 MSA V31828 Benzene <1.80 Ng/L 1.80 5.00 10 04/07/23 21:55 MSA V31828 Bromochloromethane <4.20 ug/L 4.20 10.0 10 04/07/23 21:55 MSA V31828 Bromodichloromethane <1.60 Ng/L 1.60 5.00 10 04/07/23 21:55 MSA V31828 Bromoform <15.0 ug/L 15.0 50.0 10 04/07/23 21:55 MSA V31828 Bromomethane <2.80 Ng/L 2.80 10.0 10 04/07/23 21:55 MSA V31828 Carbon Disulfide <1.50 ug/L 1.50 50.0 10 04/07/23 21:55 MSA V31828 Carbon Tetrachloride <1.80 Ng/L 1.80 5.00 10 04/07/23 21:55 MSA V31828 Chlorobenzene <1.90 ug/L 1.90 5.00 10 04/07/23 21:55 MSA V31828 Chlorodibromomethane <1.90 Ng/L 1.90 5.00 10 04/07/23 21:55 MSA V31828 Chloroethane <4.30 ug/L 4.30 10.0 10 04/07/23 21:55 MSA V31828 Chloroform <2.20 Ng/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 Chloromethane <2.20 ug/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 Di -Isopropyl Ether (DIPE) <9.60 Ng/L 9.60 50.0 10 04/07/23 21:55 MSA V31828 1,2-Dibromo-3-Chloropropane <11.0 ug/L 11.0 20.0 10 04/07/23 21:55 MSA V31828 1,2-Dibromoethane <2.00 Ng/L 2.00 5.00 10 04/07/23 21:55 MSA V31828 Dibromomethane <2.30 ug/L 2.30 5.00 10 04/07/23 21:55 MSA V31828 trans-1,4-Dichloro-2-butene <13.0 Ng/L 13.0 100 10 04/07/23 21:55 MSA V31828 1,2-Dichlorobenzene <2.20 ug/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 1,4-Dichlorobenzene 2.343 Ng/L 2.10 5.00 10 04/07/23 21:55 MSA V31828 Dichlorodifluoromethane <12.0 ug/L 12.0 50.0 10 04/07/23 21:55 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 13 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92554 Matrix: Aqueous Sample ID: LT-01-20240328 Sampled: 3/28/2023 11:27 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <2.40 Ng/L 2.40 5.00 10 04/07/23 21:55 MSA V31828 1,2-Dichloroethane <1.50 ug/L 1.50 5.00 10 04/07/23 21:55 MSA V31828 1,1-Dichloroethene <1.50 Ng/L 1.50 5.00 10 04/07/23 21:55 MSA V31828 cis- 1,2-Dich loroethene 2.163 ug/L 2.00 5.00 10 04/07/23 21:55 MSA V31828 trans-1,2-Dichloroethene <1.80 Ng/L 1.80 5.00 10 04/07/23 21:55 MSA V31828 1,2-Dichloropropane <1.90 ug/L 1.90 5.00 10 04/07/23 21:55 MSA V31828 cis- 1,3-Dich loropropene <2.10 Ng/L 2.10 5.00 10 04/07/23 21:55 MSA V31828 trans-1,3-Dichloropropene <1.50 ug/L 1.50 5.00 10 04/07/23 21:55 MSA V31828 Ethylbenzene <1.70 Ng/L 1.70 5.00 10 04/07/23 21:55 MSA V31828 2-Hexanone <3.80 ug/L 3.80 50.0 10 04/07/23 21:55 MSA V31828 Methyl Ethyl Ketone (MEK) <7.10 Ng/L 7.10 50.0 10 04/07/23 21:55 MSA V31828 4-Methyl-2-Pentanone <10.0 ug/L 10.0 50.0 10 04/07/23 21:55 MSA V31828 Methylene Chloride <3.30 Ng/L 3.30 10.0 10 04/07/23 21:55 MSA V31828 Styrene <2.20 ug/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 1,1,1,2-Tetrachloroethane <1.60 Ng/L 1.60 5.00 10 04/07/23 21:55 MSA V31828 1,1,2,2-Tetrachloroethane <1.60 ug/L 1.60 5.00 10 04/07/23 21:55 MSA V31828 Tetrachloroethene <2.20 Ng/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 Tetrahydrofuran 95.7 J ug/L 15.0 100 10 04/07/23 21:55 MSA V31828 Toluene <2.20 Ng/L 2.20 5.00 10 04/07/23 21:55 MSA V31828 1,1,1-Trichloroethane <1.60 ug/L 1.60 5.00 10 04/07/23 21:55 MSA V31828 1,1,2-Trichloroethane <0.960 Ng/L 0.960 5.00 10 04/07/23 21:55 MSA V31828 Trichloroethene <1.80 ug/L 1.80 5.00 10 04/07/23 21:55 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 14 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 Lab No : 92554 Sample ID: LT-01-20240328 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 3/28/2023 11:27 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <1.80 Ng/L 1.80 5.00 10 04/07/23 21:55 MSA V31828 1,2,3-Trichloropropane <2.70 ug/L 2.70 10.0 10 04/07/23 21:55 MSA V31828 Vinyl Acetate <10.0 Ng/L 10.0 20.0 10 04/07/23 21:55 MSA V31828 Vinyl Chloride <1.70 ug/L 1.70 5.00 10 04/07/23 21:55 MSA V31828 o-Xylene <2.10 Ng/L 2.10 5.00 10 04/07/23 21:55 MSA V31828 m,p-Xylene <4.20 ug/L 4.20 10.0 10 04/07/23 21:55 MSA V31828 Xylene (Total) <2.1 Ng/L 2.10 5.00 10 04/07/23 21:55 V31828 Surrogate: 4-Bromofluorobenzene 102 Limits: 80-124% 10 04/07/23 21:55 MSA V31828 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 10 04/07/23 21:55 MSA V31828 Surrogate: 1,2-Dichloroethane - d4 109 Limits: 63-136% 10 04/07/23 21:55 MSA V31828 Surrogate: Toluene-d8 98.0 Limits: 77-123% 10 04/07/23 21:55 MSA V31828 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 15 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92556 Sample ID: MW-07-20230328 Matrix: Aqueous Sampled: 3/28/2023 14:54 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <0.05 H mg/L 0.05 0.20 1 03/30/23 17:00 SLO SM-3500-Fe-B Alkalinity (as CaCO3) 308000 pg/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 Ng/L 2000 2000 1 03/30/23 12:40 SLO 521OB-2015 Chloride 92500 ug/L 370 1000 1 03/30/2313:25 CMJ 9056A Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/30/23 13:25 CMJ 9056A Sulfate 21800 ug/L 650 2000 1 03/30/2313:25 CMJ 9056A Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 16 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92557 Matrix: Aqueous Sample ID: MW-06-20230328 Sampled: 3/28/2023 11:09 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Nitrate (NO3-N) <76.0 H Ng/L 76.0 200 1 03/30/23 13:57 CM] 9056A Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 17 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92558 Matrix: Aqueous Sample ID : TB-20230328 Sampled: 3/28/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/07/23 14:59 MSA V31828 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/07/23 14:59 MSA V31828 Benzene <0.180 Ng/L 0.180 0.500 1 04/07/23 14:59 MSA V31828 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/07/23 14:59 MSA V31828 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/07/23 14:59 MSA V31828 Bromoform <1.50 ug/L 1.50 5.00 1 04/07/23 14:59 MSA V31828 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/07/23 14:59 MSA V31828 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/07/23 14:59 MSA V31828 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/07/23 14:59 MSA V31828 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/07/23 14:59 MSA V31828 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/07/23 14:59 MSA V31828 Chloroethane <0.430 ug/L 0.430 1.00 1 04/07/23 14:59 MSA V31828 Chloroform <0.220 Ng/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 Chloromethane <0.220 ug/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/07/23 14:59 MSA V31828 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/07/23 14:59 MSA V31828 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/07/23 14:59 MSA V31828 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/07/23 14:59 MSA V31828 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/07/23 14:59 MSA V31828 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 Dichlorodifluoromethane <1.20 Ng/L 1.20 5.00 1 04/07/23 14:59 MSA V31828 1,1-Dichloroethane <0.240 ug/L 0.240 0.500 1 04/07/23 14:59 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 18 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92558 Matrix: Aqueous Sample ID : TB-20230328 Sampled: 3/28/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dichloroethane <0.150 Ng/L 0.150 0.500 1 04/07/23 14:59 MSA V31828 1,1-Dichloroethene <0.150 ug/L 0.150 0.500 1 04/07/23 14:59 MSA V31828 cis- 1,2-Dich loroethene <0.200 Ng/L 0.200 0.500 1 04/07/23 14:59 MSA V31828 trans- 1.2-Dichloroethene <0.180 ug/L 0.180 0.500 1 04/07/23 14:59 MSA V31828 1,2-Dichloropropene <0.190 Ng/L 0.190 0.500 1 04/07/23 14:59 MSA V31828 cis- 1,3-Dich loropropene <0.210 ug/L 0.210 0.500 1 04/07/23 14:59 MSA V31828 trans-1,3-Dichloropropene <0.150 Ng/L 0.150 0.500 1 04/07/23 14:59 MSA V31828 1,4-Dioxane <16.0 ug/L 16.0 150 1 04/07/23 14:59 MSA V31828 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/07/23 14:59 MSA V31828 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/07/23 14:59 MSA V31828 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/07/23 14:59 MSA V31828 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/07/23 14:59 MSA V31828 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/07/23 14:59 MSA V31828 Styrene <0.220 ug/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 14:59 MSA V31828 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 14:59 MSA V31828 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/07/23 14:59 MSA V31828 Toluene <0.220 Ng/L 0.220 0.500 1 04/07/23 14:59 MSA V31828 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 14:59 MSA V31828 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/07/23 14:59 MSA V31828 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/07/23 14:59 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 19 of 72 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 04/25/2023 231 Haywood Street Information : Received : 03/30/2023 Asheville , NC 28801 Report Number : 23-089-0004 REPOR T OF A NA L YSIS Lab No : 92558 Matrix: Aqueous Sample ID : TB-20230328 Sampled: 3/28/2023 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31827 04/07/23 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 103 Limits: 80-124% 101 Limits: 75-129% 106 Limits: 63-136% 99.6 Limits: 77-123% 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 1 04/07/23 14:59 MSA V31828 H Beyond holding time MQL Method Quantitation Limit Page 20 of 72 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Access Analytical 15 Thames Valley Rd Irmo, SC 29063 ATTENTION Ashley Amick PROJECTID 23-089-0004 LABORATORY REPORT NUMBER 223033139 DATE 04/17/2023 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979 Innovation Park Dr., Baton Rouge, LA 70820. - Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 223033139 04/17/2023 17:14 Page 1 of 14 Page 21 of 72 LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 Analytical ANALYTICAL RESULTS Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 04/17/2023 Report p 223033139 I1II111111III Project 23-089-0004 Samples Collected 3/28/23 Deliver To Additional Recipients Ashley Amick Angela Martin, Access Analytical Access Analytical Lab Reports, Access Analytical 15 Thames Valley Rd Irmo, SC 29063 803-781-4243 ACCREDITED CERT JI 6429,01 Lab Report#: 223033139 04/17/2023 17:14 Page 2 of 14 Page 22 of 72 Report#: 223033139 arraryiecar' Project ID: 23-089-0004 Report Date: 04/17/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223033139 Lab Report#: 223033139 04/17/2023 17:14 Page 3 of 14 Page 23 of 72 !"aceA eVica! Report#: 223033139 Project ID: 23-089-0004 Certifications Report Date: 04/17/2023 Certification Certification Number A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Lab Report#: 223033139 04/17/2023 17:14 Page 4 of 14 Page 24 of 72 Report#: 223033139 ceAnalyfrca! Project ID: 23-089-0004 Report Date: 04/17/2023 Case Narrative Client: Access Analytical Report: 223033139 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. VOLATILES GAS CHROMATOGRAPHY In the AM20GAX analysis for analytical batch 763252„ the LCS and/or LCSD recoveries were outside the control limits, due to sample holding time samples are being reported In the AM20GAX analysis for analytical batch 763252, the LCS/LCSD exhibited RPD failures. Lab Report#: 223033139 04/17/2023 17:14 Page 5 of 14 Page 25 of 72 aceA��alyirca! Report#: 223033139 Project ID: 23-089-0004 Report Date: 04/17/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303313901 MW-04-20230328 Water 3/28/23 15:50 3/31/23 09:38 22303313902 MW-03-20230328 Bubble Strip 3/28/23 19:13 3/31/23 09:38 22303313903 MW-04-20230328 Bubble Strip 3/28/23 15:50 3/31/23 09:38 22303313904 MW-03-20230328 Bubble Strip 3/28/23 19:13 3/31/23 09:38 Lab Report#: 223033139 04/17/2023 17:14 Page 6 of 14 Page 26 of 72 ceAnalyfrca! Report#: Project ID: 223033139 23-089-0004 Report Date: 04/17/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22303313901 22303313901 22303313901 MW-04-20230328 MW-04-20230328 MW-04-20230328 Acetic Acid Propionic Acid Formic Acid mg/L mg/L mg/L 2.6,1 0.53J 54 10 10 10 NA NA NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303313901 22303313901 22303313903 MW-04-20230328 MW-04-20230328 MW-04-20230328 Methane Ethane Hydrogen ug/L ug/L nM 9.3 0.29J 10 1 1 1 NA NA NA EPA RSK-175 Lab ID Client ID Parameter Units Result Dil. %Moist 22303313901 MW-04-20230328 Carbon Dioxide ug/L 257000 1 NA Lab Report#: 223033139 04/17/2023 17:14 Page 7 of 14 Page 27 of 72 Report#: 223033139 Project ID: 23-089-0004 Report Date: 04/17/2023 Sample Results MW-04-20230328 Collect Date 03/28/2023 15:50 Lab ID 22303313901 Receive Date 03/31/2023 09:38 Matrix Water RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/06/2317:55 763353 BDP NA Parameter Result DL LOQ I Carbon Dioxide 257000 585 1200 G *Results and limits are adjusted for dilution. Units ug/L Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/16/2315:44 763404 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.531J 0.53 5.0 mg/L 64-19-7 Acetic Acid 2.6J 1.2 5.0 mg/L 79-09-4 Propionic Acid 0.53J 0.53 5.0 mg/L 64-18-6 Formic Acid 54 0.55 5.0 mg/L 107-92-6 Butyric Acid 0.58U 0.58 5.0 mg/L 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L 142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/10/23 08:41 763252 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 9.3 2.0 5.0 ug/L 74-84-0 Ethane 0.29J 0.17 1.0 ug/L 74-85-1 Ethene 0.24U 0.24 1.0 ug/L MW-03-20230328 Collect Date 03/28/2023 19:13 Lab ID 22303313902 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2312:14 763091 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 0.49U 0.49 1.9 nM Lab Report#: 223033139 04/17/2023 17:14 Page 8 of 14 Page 28 of 72 Report#: 223033139 Project ID: 23-089-0004 Report Date: 04/17/2023 Sample Results MW-04-20230328 Collect Date 03/28/2023 15:50 Lab ID 22303313903 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2312:27 763091 LMB NA CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 10 0.49 1.9 nM MW-03-20230328 Collect Date 03/28/2023 19:13 Lab ID 22303313904 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/07/23 07:20 763397 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 0.49U 0.49 1.9 nM Lab Report#: 223033139 04/17/2023 17:14 Page 9 of 14 Page 29 of 72 2"Arialyirca! Report#: 223033139 Project ID: 23-089-0004 GC Volatiles QC Summary Report Date: 04/17/2023 Analytical Batch Client ID MB763353 LCS763353 LCSD763353 763353 Lab ID 2470074 2470075 2470076 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/06/23 13:09 04/06/23 12:37 04/06/23 12:53 Matrix Water Water Water EPA RSK-175 Units ug/L Spike I Result %R Control Spike Result %R RPD RPD Result DLI Added Limits%R Added Limit Carbon Dioxide 124-38-9 585UJ 5851 33800 1 33300 199 1 38 - 147 338001 40100 119 19 1 40 Lab Report#: 223033139 04/17/2023 17:14 Page 10 of 14 Page 30 of 72 2"Arialyirca! Report#: 223033139 Project ID: 23-089-0004 General Chemistry QC Summary Report Date: 04/17/2023 Analytical Batch Client ID MB763404 LCS763404 LCSD763404 763404 Lab ID 2470289 2470290 2470291 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/15/23 19:05 04/15/23 19:59 04/15/23 20:51 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Lactic Acid 50-21-5 0.053U 0.053 2.0 2.1 104 70 - 130 2.0 2.0 102 2 20 Acetic Acid 64-19-7 0.12U 0.12 2.0 1.9 97 70 - 130 2.0 1.9 97 0 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.0 99 70 - 130 2.0 1.9 97 2 20 Formic Acid 64-18-6 0.055U 0.055 2.0 1.8 90 70 - 130 2.0 1.8 90 0 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 1.9 93 70 - 130 2.0 1.9 97 5 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 1.9 94 70 - 130 2.0 1.9 93 1 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 1.9 93 70 - 130 2.0 1.9 95 2 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.0 98 70 - 130 2.0 1.9 97 1 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 1.9 96 70 - 130 2.0 2.0 98 2 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 1.8 91 70 - 130 2.0 1.9 93 2 20 Lab Report#: 223033139 04/17/2023 17:14 Page 11 of 14 Page 31 of 72 2"Arialyirca! Report#: 223033139 Project ID: 23-089-0004 General Chromatography QC Summary Report Date: 04/17/2023 Analytical Batch Client ID MB763091 LCS763091 LCSD763091 763091 Lab ID 2468699 2468700 2468701 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/03/23 12:02 04/03/23 11:38 04/03/23 11:50 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM I Spike Result %R I Control Spike Result I %R I RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 0.49 12 10 85 70 - 130 12 12199 14 20 Analytical Batch Client ID MB763397 LCS763397 LCSD763397 763397 Lab ID 2470268 2470269 2470270 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/07/23 06:56 04/07/23 06:31 04/07/23 06:43 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R I Control I Spike Result %R RPD RPD I Result DLI Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 1 0.491 121 111 91 1 70-130 1 121 11194 1 4 1 20 Analytical Batch Client ID MB763252 LCS763252 LCSD763252 763252 Lab ID 2469474 2469475 2469476 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/10/23 07:24 04/10/23 06:52 04/10/23 07:08 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Methane 74-82-8 2.OU 2.0 380 280 73 70-130 380 370 98 29* 20 Ethane 74-84-0 0.17U 0.17 97 76 78 70 - 130 97 100 103 28' 20 Ethene 74-85-1 0.24U 0.24 120 96 81 70 - 130 120 130 107 28' 20 Lab Report#: 223033139 04/17/2023 17:14 Page 12 of 14 Page 32 of 72 0 c cn a ni v; U Lit C, lr) L+7 el' Cl) G1 CN N a � Q 0 a a J 2 � N p [C ❑ E fC � ❑ � 4 U � n � o � 0 .Q G vi m 2 V, u d 7 m 7 Q M o Q r.f u] O a ¢ v ap m d _ m ¢ Q N m a M CD 6. u V V •o a_ 4 x W CcY N M M O LO � � M p m m N t t M K a p W LJ C C U ra i h 7) C W Q C77 LL! y ¢ G m EED a U � fll N 41 f6 r W � N 4l 8j y. Q 7 ¢ J � o r. O-75 m -S ❑a d � ,-� N N d) N c Sj v i ¢ ¢ a ❑ ID. a rt fl Z Ln .� O I N N �i [��f L�r7 N k a a CY a < �IN 0 z E � � � co U) o 0 I N N CV MV 67 c 0 O O CD +%A 6 O o fl U z � z m � Ln � Ln Ln CD� Ln pi O N N N 11>1 m ca o [ A o a N N N N Lq p d ry W m m co m c2 VJ o 0 0 00 w N = m N rn r� ry m ry m U N N CD �-I a N n] C ❑ CD O 8 ❑ d" ❑ OO O O O d r m O 6 0 o a o Ln p O m m m m N N N N F E ■ ry� 4 p�j C QV C Q ❑ m m n 1� L� O7 o = � , o o 0 � .v: U v N N 3 N a m C Cru ^ Ln � C� &- O _M (M CM 0 m N N 0 0 Q Q (0 J Page 33 of 72 J U W 2 U Z W U W W J � Q .� k \ ❑ ❑ ❑ ❑ ❑ ❑ ❑ 2 q � ❑ � � � ❑ � � � 2 � / k § Cl. � \ f § w 0 « k ƒ ■ \ k 't § 34 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 April 07, 2023 Danyale Love Waypoint Analytical, LLC 449 Springbrook Rd Charlotte, NC 28217 RE: Project: 3326EXP Pace Project No.: 92659925 Dear Danyale Love: Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Ormond Beach If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Angela Overcash, Waypoint Analytical V AtQ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, B ; without the written consent of Pace Analytical Services, LLC. Page 35 of 72 Page 1 of 13 a� _ ;a'ceAnalyfica( ff www.pacelabs.com I Project: 3326EXP Pace Project No.: 92659925 Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 72 Page 2 of 13 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: 3326EXP Pace Project No.: 92659925 Lab ID Sample ID Matrix Date Collected Date Received 92659925001 92659925002 DW-01-20230328 DW-02-20230328 Water Water 03/28/23 12:36 03/28/23 13:25 03/31/2311:50 03/31/2311:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 Page 37 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: 3326EXP Pace Project No.: 92659925 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659925001 DW-01-20230328 EPA524.2 AS4 24 PASI-O 92659925002 DW-02-20230328 EPA 524.2 AS4 24 PASI-O PASI-O = Pace Analytical Services - Ormond Beach REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 Page 38 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: 3326EXP Pace Project No.: 92659925 Sample: DW-01-20230328 Lab ID: 92659925001 Collected: 03/28/23 12:36 Received: 03/31/23 11:50 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 0.00040 1 04/05/23 15:18 71-43-2 Carbon tetrachloride ND mg/L 0.00050 0.00028 1 04/05/23 15:18 56-23-5 Chlorobenzene ND mg/L 0.00050 0.00026 1 04/05/23 15:18 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 0.00026 1 04/05/23 15:18 95-50-1 1g 1,4-Dichlorobenzene ND mg/L 0.00050 0.00030 1 04/05/23 15:18 106-46-7 1g 1,2-Dichloroethane ND mg/L 0.00050 0.00030 1 04/05/23 15:18 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 0.00029 1 04/05/23 15:18 75-35-4 cis- 1,2-Dichloroethene ND mg/L 0.00050 0.00033 1 04/05/23 15:18 156-59-2 trans- 1 2- Dich loroethene ND mg/L 0.00050 0.00027 1 04/05/23 15:18 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 0.00044 1 04/05/23 15:18 78-87-5 Ethylbenzene ND mg/L 0.00050 0.00023 1 04/05/23 15:18 100-41-4 Methylene Chloride ND mg/L 0.0010 0.00044 1 04/05/23 15:18 75-09-2 Styrene ND mg/L 0.00050 0.00020 1 04/05/23 15:18 100-42-5 1g Tetrachloroethene ND mg/L 0.00050 0.00026 1 04/05/23 15:18 127-18-4 Toluene ND mg/L 0.00050 0.00028 1 04/05/23 15:18 108-88-3 1,2,4-Trichlorobenzene ND mg/L 0.00050 0.00035 1 04/05/23 15:18 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 0.00027 1 04/05/23 15:18 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 0.00028 1 04/05/23 15:18 79-00-5 Trichloroethene ND mg/L 0.00050 0.00026 1 04/05/23 15:18 79-01-6 Vinyl chloride ND mg/L 0.00050 0.00012 1 04/05/23 15:18 75-01-4 L3 Xylene (Total) ND mg/L 0.0010 0.00011 1 04/05/23 15:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 86 % 70-130 1 04/05/23 15:18 460-00-4 Toluene-d8 (S) 97 % 70-130 1 04/05/23 15:18 2037-26-5 1,2-Dichlorobenzene-d4 (S) 101 % 70-130 1 04/05/23 15:18 2199-69-1 Sample: DW-02-20230328 Lab ID: 92659925002 Collected: 03/28/23 13:25 Received: 03/31/23 11:50 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 0.00040 1 04/05/2315:43 71-43-2 Carbon tetrachloride ND mg/L 0.00050 0.00028 1 04/05/23 15:43 56-23-5 Chlorobenzene ND mg/L 0.00050 0.00026 1 04/05/2315:43 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 0.00026 1 04/05/2315:43 95-50-1 1g 1,4-Dichlorobenzene ND mg/L 0.00050 0.00030 1 04/05/2315:43 106-46-7 1g 1,2-Dichloroethane ND mg/L 0.00050 0.00030 1 04/05/2315:43 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 0.00029 1 04/05/2315:43 75-35-4 cis- 1,2-Dichloroethene ND mg/L 0.00050 0.00033 1 04/05/2315:43 156-59-2 trans- 1 2- Dich loroethene ND mg/L 0.00050 0.00027 1 04/05/2315:43 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 0.00044 1 04/05/2315:43 78-87-5 Ethylbenzene ND mg/L 0.00050 0.00023 1 04/05/2315:43 100-41-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/07/2023 07:14 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 13 Page 39 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: 3326EXP Pace Project No.: 92659925 Sample: DW-02-20230328 Parameters Lab ID: 92659925002 Results Units Collected: Report Limit 03/28/23 13:25 MDL DF Received: 03/31/23 11:50 Matrix: Water Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Methylene Chloride ND mg/L 0.0010 0.00044 1 04/05/23 15:43 75-09-2 Styrene ND mg/L 0.00050 0.00020 1 04/05/23 15:43 100-42-5 1g Tetrachloroethene ND mg/L 0.00050 0.00026 1 04/05/23 15:43 127-18-4 Toluene ND mg/L 0.00050 0.00028 1 04/05/23 15:43 108-88-3 1,2,4-Trichlorobenzene ND mg/L 0.00050 0.00035 1 04/05/23 15:43 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 0.00027 1 04/05/23 15:43 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 0.00028 1 04/05/23 15:43 79-00-5 Trichloroethene ND mg/L 0.00050 0.00026 1 04/05/23 15:43 79-01-6 Vinyl chloride ND mg/L 0.00050 0.00012 1 04/05/23 15:43 75-01-4 L3 Xylene (Total) ND mg/L 0.0010 0.00011 1 04/05/23 15:43 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 87 % 70-130 1 04/05/23 15:43 460-00-4 Toluene-d8 (S) 96 % 70-130 1 04/05/23 15:43 2037-26-5 1,2-Dichlorobenzene-d4 (S) 101 % 70-130 1 04/05/23 15:43 2199-69-1 Date: 04/07/2023 07:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 Page 40 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 3326EXP Pace Project No.: 92659925 QC Batch: 906909 Analysis Method: EPA 524.2 QC Batch Method: EPA 524.2 Analysis Description: 524.2 MSV Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92659925001, 92659925002 METHOD BLANK: 4984228 Associated Lab Samples: 92659925001, 92659925002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1-Trichloroethane mg/L ND 0.00050 0.00027 04/05/23 14:53 1,1,2-Trichloroethane mg/L ND 0.00050 0.00028 04/05/23 14:53 1,1-Dichloroethene mg/L ND 0.00050 0.00029 04/05/23 14:53 1,2,4-Trichlorobenzene mg/L ND 0.00050 0.00035 04/05/23 14:53 1,2-Dichlorobenzene mg/L ND 0.00050 0.00026 04/05/23 14:53 1,2-Dichloroethane mg/L ND 0.00050 0.00030 04/05/23 14:53 1,2-Dichloropropane mg/L ND 0.00050 0.00044 04/05/23 14:53 1,4-Dichlorobenzene mg/L ND 0.00050 0.00030 04/05/23 14:53 Benzene mg/L ND 0.00050 0.00040 04/05/23 14:53 Carbon tetrachloride mg/L ND 0.00050 0.00028 04/05/23 14:53 Chlorobenzene mg/L ND 0.00050 0.00026 04/05/23 14:53 cis-1,2-Dichloroethene mg/L ND 0.00050 0.00033 04/05/23 14:53 Ethylbenzene mg/L ND 0.00050 0.00023 04/05/23 14:53 Methylene Chloride mg/L ND 0.0010 0.00044 04/05/23 14:53 Styrene mg/L ND 0.00050 0.00020 04/05/23 14:53 Tetrachloroethene mg/L ND 0.00050 0.00026 04/05/23 14:53 Toluene mg/L ND 0.00050 0.00028 04/05/23 14:53 trans- 1 2- Dich loroethene mg/L ND 0.00050 0.00027 04/05/23 14:53 Trichloroethene mg/L ND 0.00050 0.00026 04/05/23 14:53 Vinyl chloride mg/L ND 0.00050 0.00012 04/05/23 14:53 Xylene (Total) mg/L ND 0.0010 0.00011 04/05/23 14:53 1,2-Dichlorobenzene-d4 (S) % 101 70-130 04/05/23 14:53 4-Bromofluorobenzene (S) % 88 70-130 04/05/23 14:53 Toluene-d8 (S) % 96 70-130 04/05/23 14:53 LABORATORY CONTROL SAMPLE & LCSD: Parameter 4984229 Units Spike Conc. 4984230 LCS LCSD Result Result LCS LCSD % Rec % Rec % Rec Limits RPD Max RPD Qualifiers 1,1,1-Trichloroethane mg/L 0.02 0.018 0.018 88 88 70-130 1 20 1,1,2-Trichloroethane mg/L 0.02 0.018 0.018 92 91 70-130 1 20 1,1-Dichloroethene mg/L 0.02 0.018 0.017 88 86 70-130 1 20 1,2,4-Trichlorobenzene mg/L 0.02 0.017 0.017 87 86 70-130 1 20 1,2-Dichlorobenzene mg/L 0.02 0.020 0.020 100 98 70-130 2 20 1,2-Dichloroethane mg/L 0.02 0.020 0.019 98 97 70-130 1 20 1,2-Dichloropropane mg/L 0.02 0.020 0.019 99 94 70-130 5 20 1,4-Dichlorobenzene mg/L 0.02 0.020 0.019 100 97 70-130 3 20 Benzene mg/L 0.02 0.020 0.020 99 98 70-130 1 20 Carbon tetrachloride mg/L 0.02 0.017 0.017 84 84 70-130 0 20 Chlorobenzene mg/L 0.02 0.020 0.020 99 99 70-130 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/07/2023 07:14 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 13 Page 41 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 3326EXP Pace Project No.: 92659925 LABORATORY CONTROL SAMPLE & LCSD: 4984229 4984230 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers cis-1,2-Dichloroethene mg/L 0.02 0.019 0.019 97 96 70-130 1 20 Ethylbenzene mg/L 0.02 0.020 0.020 100 99 70-130 1 20 Methylene Chloride mg/L 0.02 0.019 0.018 94 91 70-130 3 20 Styrene mg/L 0.02 0.023 0.023 116 115 70-130 1 20 Tetrachloroethene mg/L 0.02 0.017 0.017 84 83 70-130 0 20 Toluene mg/L 0.02 0.020 0.019 98 97 70-130 1 20 trans- 1 2- Dich loroethene mg/L 0.02 0.019 0.018 94 92 70-130 3 20 Trichloroethene mg/L 0.02 0.018 0.018 90 91 70-130 1 20 Vinyl chloride mg/L 0.02 0.027 0.027 134 137 70-130 2 20 L1 Xylene (Total) mg/L 0.06 0.062 0.060 103 101 70-130 2 20 1,2-Dichlorobenzene-d4 (S) % 100 101 70-130 4-Bromofluorobenzene (S) % 93 93 70-130 Toluene-d8 (S) % 98 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/07/2023 07:14 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 13 Page 42 of 72 a� _ ;a'ceAnalyfica( www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: 3326EXP Pace Project No.: 92659925 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS 1 g The recovery of the analyte in the CRDL standard (also known as the reporting limit verification) exceeded the acceptance criteria. Analyte results below the reporting limits are not affected by high bias. Li Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/07/2023 07:14 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13 Page 43 of 72 lacioAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 3326EXP Pace Project No.: 92659925 Lab ID Sample ID QC Batch Method QC Batch 92659925001 DW-01-20230328 EPA 524.2 906909 92659925002 DW-02-20230328 EPA 524.2 906909 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/07/2023 07:14 PM without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 10 of 13 Page 44 of 72 ace DC# Title: ENV-FRM-HUN1-0083 02 Sample Condition Upon Receipt Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden[:] Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample od• Client Name: W�� '• 92659925 t J„ Project 4: Courier: ❑Fed x k OUPS QLAPS Client II I III III �I'I II I I I I �� ❑ Commercial ❑Pace ❑Other: CustodySeal Present? ❑Yes to Seals Intact Packing Material: ❑Bubble Wrap EYBbble Bags ❑Yes 6N ❑None ❑ Other Thermo eter: IR Gun ID: ` /; C Type of Ice: et 11 Correction Factor: Cooler Temp: J Add/Subtract ('C) t-kt Cooler Temp Corrected ,{°/ ` USDA Regulated Soil N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC [check mansl? r—IYP.s FlNn VAMM925 Date/Initials Person Emamining Contents: G Biological Tiss ozen? 1 7 1 []Yes ❑No N/A ❑Btue [].lone Temp should be above freezing to 6°C ❑samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, inchdinaHAwaii and PipartnRirnl7l—IVac F-1t4n Comments/Discrepancy: Chain of Custody Present? Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? es ❑No El N/A 2. Short Hold Time Analysis (02 hr.)? Oyes Na ❑N/A 3. Rush Turn Around Time Requested? ❑Yes V. ❑N/A 4. Sufficient Volume? bGs ❑No []N/A 5. Correct Containers Used? -Pace Containers Used? Ves Yes ❑No ❑No ❑N/A ❑N/A 6. Containers ]ntact? les ❑Nn ❑N/A 7. Dissolved analysis: Sampies Field Filtered? ❑Y ❑No &:�/A 8. Sample Labels Match COC? 1 , -Includes Date/Time/ID/Analysis Matrix: es ❑No ❑N/A 9, Headspace in VOA Vials (?5-6mm)? ❑Yes ❑Na A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes ❑Yes ❑No ❑No Z7N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? [-]Yes ❑No Qualtrax ID: 69614 Page 45 of 72 Pagel 0( 2 Page 11 of 13 race DC##_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt Effective Date; 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and Project rf within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine wo#:92659925 PM: MWB Due Date: 04/10/23 CLIENT: 92—Prism r E z v N c > u a J E a m Z d a v�i Cl c > U a J E N 7 a m Z d 2 ,�i. QI it 7 u a J E a m Z -0 W M M m El m r-r 7 a m N V 2 a ST O _ 4 J N yr M m V S d f,'S O = „ a ..1 N z a co cc Z °b m Itl y a N u a J E i n .f rit 0. m rV n C O z '_' M J E N m a m a L m ID 'o v r c� E �v _ u�. 3 - Z v v Cn N M E Q ..� 7 L7 a N V Q v x E a 2 l7 a ¢ w a ¢ J E 0 7 iM7 a v 0. O r E a ti r�7 a V S Q a S (U Q J Or rV vi C7 a t? C Z -v V = z E a p a v l'1 o ? u O > V = L7 ❑ 4 Z fY1 O V1i N QO > J a ti U Cn 5 Z IDZ a c 0 > J o 7 Q > Z l? m D > E O y ? f9 n ? c _�v 4. ON 111 0.. >c .. Y l_`0 z 7 G r N > % 1 Q V '� a VI J E rN-I a ,� 1 4 Z V a a V} J O N a ^ Q N ry Z u a J EE N a co W N W a> m Q J 0 p N ia7 a ? ,n f0 a u V_t p N LA > Z -C a! Z N m a E QJ OLn V 0 ❑ 1 2 3 4 5 N\:s 7 a 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservatlon adjusted Time preservation adjusted Arnount of Preservative added Lot If .V— VV I --VC; 11EU;tf is d uiauepdncy direcung Nor c.aronna compuance sampces, a copy or tnis Corm win oe sent to the North Carelina DENR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 12 of 13 Page 46 of 72 (D v .n� chi b C Cp CL CL cn� tp' p 1 p 3 v rD W rD ZY o 1 � n C M @ rD � zr rD rt 70 C rDrDW n n rD ro a a n cc o fo LO -I rD N w 0 6 0 CD 41 0 0 N O N W O W IV co N C. IN Ln W Ln p D 10 C N I7d w M 0 co o LD 6 z � Q a w N O n m Ni M p n O N ti N W O Ln W N M13 r^ J M C N S XD 3 C rt x Ln Qr Ln N Z O rn � n 1+ cn S Nj G .. Z X 0 V = kD -0 0 p n r� O N x > ui n a N Z n cu I'D N O V ram3 co rD rD r I^ 3 C O n mmt 3 �+ n 0 Z I N O U) O LO g -0 5. � - � rr n a w O w O N 7 h. V p XXa `fl 'O W A 4 N Qj cu N W : R' -A a N O turf w w N m X T r Q � � a s o E as n o (D 5-@,� a ti rt V V E n Ul -M cli 2 W O ro (} O CD rn p p D rD vLa C d e� CD a, IQ cw � .. \ Io D= w rD Do rt d N n = Coil Q 0 O Q c�J (fn U) 0 C r C rD L9 W �. (D O � � W to V rj cn 0 ti Page 47 of 72 Page 13 of 13 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Analytical Batch: V31484 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92551, 92556 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/31/23 16:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 251000 100 90-110 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 217000 204000 6.1 20 03/31/23 16:00 Date: 04/25/2023 02:09 PM Page 1 of 22 Page 48 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Analytical Batch: V31425 Analysis Method: 4500S2F-2011 Analysis Description: Sulfide Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed Parameter Units Result Sulfide pg/L <830 830 2000 03/30/2311:50 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Sulfide pg/L 10000 9000 90.0 70-122 Date: 04/25/2023 02:09 PM Page 2 of 22 Page 49 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Analytical Batch: V31584 Analysis Method: 521OB-2015 Analysis Description: Biochemical Oxygen Demand (BOD) Glucose-Glutamic Acid GGA Result Range Analyzed Parameter Units Biochemical Oxygen Demand (5-day) Ng/L 178 167.5-228.E 03/30/23 12:40 Duplicate V 92565-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Biochemical Oxygen Demand (5-day) Ng/L 5000 4900 2.0 30 03/30/23 12:40 Date: 04/25/2023 02:09 PM Page 3 of 22 Page 50 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Analytical Batch: V31605 Analysis Method: 5220D-2011 Analysis Description: Chemical Oxygen Demand (COD) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed Parameter Units Result COD (Chemical Oxygen Demand) pg/L <8000 8000 30000 04/05/23 10:40 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits COD (Chemical Oxygen Demand) pg/L 50000 50000 100 90-110 Matrix Spike & Matrix Spike Duplicate V 92587-MS V 92587-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. COD (Chemical Oxygen Demand) pg/L 23000 50000 50000 66000 68000 86.0 90.0 80-120 2.9 20 Date: 04/25/2023 02:09 PM Page 4 of 22 Page 51 of 72 • Charlotte, NC 28217 Waypoint, 449 Springbrook Rd, Ch Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: L675220 QC Analytical Batch(es): L675223 QC Prep Batch Method: 5310C-2011 Analysis Method: 5310C-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-675220 Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed Parameter Units Result TOC mg/L <0.682 0.682 1.00 04/07/23 22:19 Laboratory Control Sample LCS-1-675220 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC mg/L 5.00 4.88 98.0 85-115 Duplicate L 91296-DUP-L675220 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC mg/L 1.43 1.46 2.0 15.0 04/08/23 02:45 Matrix Spike L 91295-MS-1-675220 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC mg/L 1.68 5.26 6.96 100 85-115 Date: 04/25/2023 02:09 PM Page 5 of 22 Page 52 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: L673485 QC Analytical Batch(es): L673886 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-1-673485 Matrix: AQU Associated Lab Samples: 92551, 92554 Parameter Units Blank Result MDL MQL Analyzed Antimony pg/L <0.618 0.618 1.00 04/03/23 16:58 Arsenic pg/L <0.297 0.297 1.00 04/03/23 16:58 Barium pg/L <0.453 0.453 1.00 04/03/23 16:58 Beryllium pg/L <0.102 0.102 1.00 04/03/23 16:58 Cadmium pg/L <0.350 0.350 1.00 04/03/23 16:58 Chromium pg/L <0.346 0.346 1.00 04/03/23 16:58 Cobalt pg/L <0.060 0.060 1.00 04/03/23 16:58 Copper pg/L <0.489 0.489 1.00 04/03/23 16:58 Lead pg/L <0.264 0.264 1.00 04/03/23 16:58 Nickel pg/L <0.182 0.182 1.00 04/03/23 16:58 Selenium pg/L <0.703 0.703 1.00 04/03/23 16:58 Silver pg/L <0.0570 0.0570 1.00 04/03/23 16:58 Thallium pg/L <0.0610 0.0610 1.00 04/03/23 16:58 Vanadium pg/L <0.767 0.767 5.00 04/03/23 16:58 Zinc pg/L <4.67 4.67 10.0 04/03/23 16:58 Laboratory Control Sample LCS-L673485 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 104 104 80-120 Arsenic pg/L 50.0 50.2 100 80-120 Barium pg/L 100 103 103 80-120 Beryllium pg/L 50.0 52.7 105 80-120 Cadmium pg/L 10.0 10.2 102 80-120 Chromium pg/L 100 103 103 80-120 Cobalt pg/L 100 102 102 80-120 Copper pg/L 50.0 52.3 105 80-120 Date: 04/25/2023 02:09 PM Page 6 of 22 Page 53 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: L673485 QC Analytical Batch(es): L673886 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-1-673485 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 50.0 52.0 104 80-120 Nickel pg/L 50.0 53.4 107 80-120 Selenium pg/L 100 104 104 80-120 Silver pg/L 10.0 10.1 101 80-120 Thallium pg/L 10.0 10.5 105 80-120 Vanadium pg/L 500 508 102 80-120 Zinc pg/L 500 509 102 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92554-MS-L673485 MS Spike Result Conc. V 92554-MSD-L673485 MSD MS Result MSD Spike Result Conc. MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 6.18 100 100 95.2 95.6 95.0 96.0 75-125 0.4 20.0 Arsenic pg/L 15.4 50.0 50.0 63.4 63.3 96.0 96.0 75-125 0.1 20.0 Barium pg/L 1260 100 100 1360 1270 100 10.0* 75-125 6.8 20.0 Beryllium pg/L < 1.02 50.0 50.0 51.2 47.9 102 96.0 75-125 6.6 20.0 Cadmium pg/L < 3.50 10.0 10.0 8.97 9.91 90.0 99.0 75-125 9.9 20.0 Chromium pg/L 20.3 100 100 120 115 100 95.0 75-125 4.2 20.0 Cobalt pg/L 9.39 100 100 104 104 95.0 95.0 75-125 0.0 20.0 Copper pg/L 8.50 50.0 50.0 58.5 56.3 100 96.0 75-125 3.8 20.0 Lead pg/L 3.03 50.0 50.0 52.3 51.3 99.0 97.0 75-125 1.9 20.0 Nickel pg/L 34.3 50.0 50.0 83.7 81.7 99.0 95.0 75-125 2.4 20.0 Selenium pg/L < 7.03 100 100 90.8 95.9 91.0 96.0 75-125 5.4 20.0 Silver pg/L < 0.570 10.0 10.0 9.11 9.06 91.0 91.0 75-125 0.5 20.0 Thallium pg/L < 0.610 10.0 10.0 10.2 9.84 102 98.0 75-125 3.5 20.0 Vanadium pg/L 26.5 500 500 503 513 95.0 97.0 75-125 1.9 20.0 Zinc pg/L < 46.7 500 500 523 524 105 105 75-125 0.1 20.0 * QC Fail Date: 04/25/2023 02:09 PM Page 7 of 22 Page 54 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: L673485 QC Analytical Batch(es): L673886 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 92554-PDS-L673485 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 52.2 104 04/03/23 17:33 Arsenic pg/L 26.3 102 04/03/23 17:33 Barium pg/L 115 102 04/03/23 17:33 Beryllium pg/L 24.8 99.0 04/03/23 17:33 Cadmium pg/L 4.90 98.0 04/03/23 17:33 Chromium pg/L 52.3 102 04/03/23 17:33 Cobalt pg/L 51.0 101 04/03/23 17:33 Copper pg/L 26.3 103 04/03/23 17:33 Lead pg/L 25.5 101 04/03/23 17:33 Nickel pg/L 27.8 104 04/03/23 17:33 Selenium pg/L 51.2 102 04/03/23 17:33 Silver pg/L 4.57 91.0 04/03/23 17:33 Thallium pg/L 5.27 105 04/03/23 17:33 Vanadium pg/L 258 103 04/03/23 17:33 Zinc pg/L 263 105 04/03/23 17:33 Date: 04/25/2023 02:09 PM Page 8 of 22 Page 55 of 72 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: L673784 QC Analytical Batch(es): L674000 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-673784 Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 04/04/23 13:34 Laboratory Control Sample LCS-1-673784 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 5.04 101 80-120 Matrix Spike & Matrix Spike Duplicate V 92551-MS-L673784 V 92551-MSD-L673784 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 4.00 4.86 80.0 97.0 80-120 19.4 20 Post Digestion Spike V 92551-PDS-L673784 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.53 91.0 04/04/23 14:16 Date: 04/25/2023 02:09 PM Page 9 of 22 Page 56 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31426 QC Analytical Batch(es): V31427 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31426 Matrix: AQU Associated Lab Samples: 92551, 92554 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/30/23 09:39 4-Bromofluorobenzene (S) 03/30/23 09:39 111 70-130 Laboratory Control Sample LCS-V31426 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 46.8 93.6 70-130 4-Bromofluorobenzene (S) 98.0 70-130 Matrix Spike & Matrix Spike Duplicate V 92499-MS-V31426 V 92499-MSD-V31426 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. 1,4-Dioxane pg/L 13.7 50.0 50.0 58.6 57.5 89.8 87.6 70-130 1.8 20.0 4-Bromofluorobenzene (S) 107 119 70-130 Date: 04/25/2023 02:09 PM Page 10 of 22 Page 57 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31827 QC Prep Batch Method: 5030B QC Analytical Batch(es): V31828 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31827 Matrix: AQU Associated Lab Samples: 92554, 92558 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/07/23 14:10 Acrylonitrile pg/L <0.230 0.230 5.00 04/07/23 14:10 Benzene pg/L <0.180 0.180 0.500 04/07/23 14:10 Bromochloromethane pg/L <0.420 0.420 1.00 04/07/23 14:10 Bromodichloromethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Bromoform pg/L <1.50 1.50 5.00 04/07/23 14:10 Bromomethane pg/L <0.280 0.280 1.00 04/07/23 14:10 Carbon Disulfide pg/L <0.150 0.150 5.00 04/07/23 14:10 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/07/23 14:10 Chlorobenzene pg/L <0.190 0.190 0.500 04/07/23 14:10 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/07/23 14:10 Chloroethane pg/L <0.430 0.430 1.00 04/07/23 14:10 Chloroform pg/L <0.220 0.220 0.500 04/07/23 14:10 Chloromethane pg/L <0.220 0.220 0.500 04/07/23 14:10 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/07/23 14:10 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/07/23 14:10 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/07/23 14:10 Dibromomethane pg/L <0.230 0.230 0.500 04/07/23 14:10 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/07/23 14:10 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/07/23 14:10 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/07/23 14:10 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/07/23 14:10 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/07/23 14:10 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/07/23 14:10 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/07/23 14:10 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Date: 04/25/2023 02:09 PM Page 11 of 22 Page 58 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31827 Matrix: AQU Associated Lab Samples: 92554, 92558 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/07/23 14:10 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/07/23 14:10 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/07/23 14:10 1,4-Dioxane pg/L <16.0 16.0 150 04/07/23 14:10 Ethylbenzene pg/L <0.170 0.170 0.500 04/07/23 14:10 2-Hexanone pg/L <0.380 0.380 5.00 04/07/23 14:10 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/07/23 14:10 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/07/23 14:10 Methylene Chloride pg/L <0.330 0.330 1.00 04/07/23 14:10 Styrene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Tetrachloroethene pg/L <0.220 0.220 0.500 04/07/23 14:10 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/07/23 14:10 Toluene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/07/23 14:10 Trichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/07/23 14:10 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/07/23 14:10 Vinyl Acetate pg/L <1.00 1.00 2.00 04/07/23 14:10 Vinyl Chloride pg/L <0.170 0.170 0.500 04/07/23 14:10 o-Xylene pg/L <0.210 0.210 0.500 04/07/23 14:10 m,p-Xylene pg/L <0.420 0.420 1.00 04/07/23 14:10 4-Bromofluorobenzene (S) 04/07/23 14:10 102 80-124 Dibromofluoromethane (S) 04/07/23 14:10 101 75-129 1,2-Dichloroethane - d4 (S) 04/07/23 14:10 106 63-136 Date: 04/25/2023 02:09 PM Page 12 of 22 Page 59 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31827 Matrix: AQU Associated Lab Samples: 92554, 92558 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/07/23 14:10 97.2 77-123 Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits Acetone pg/L 40.0 62.5 46.6 156 117 40-166 Benzene pg/L 20.0 19.8 19.9 99.0 99.5 77-128 Bromochloromethane pg/L 20.0 21.1 21.2 106 106 78-135 Bromodichloromethane pg/L 20.0 20.3 20.1 102 101 76-138 Bromoform pg/L 20.0 24.8 21.8 124 109 71-135 Bromomethane pg/L 20.0 15.9 18.6 79.5 93.0 41-168 Carbon Disulfide pg/L 20.0 20.0 20.4 100 102 59-135 Carbon Tetrachloride pg/L 20.0 20.1 20.3 101 102 72-142 Chlorobenzene pg/L 20.0 19.3 19.1 96.5 95.5 78-119 Chlorodibromomethane pg/L 20.0 23.1 22.0 116 110 75-134 Chloroethane pg/L 20.0 20.5 21.1 103 106 57-142 Chloroform pg/L 20.0 20.4 20.2 102 101 77-130 Chloromethane pg/L 20.0 19.5 20.7 97.5 104 47-145 Di -Isopropyl Ether (DIPE) pg/L 20.0 19.7 19.4 98.5 97.0 60-154 1,2-Dibromoethane pg/L 20.0 22.4 21.7 112 109 77-135 Dibromomethane pg/L 20.0 21.9 22.4 110 112 76-138 trans-1,4-Dichloro-2-butene pg/L 20.0 21.8 22.0 109 110 70-130 1,2-Dichlorobenzene pg/L 20.0 20.7 20.4 104 102 78-128 1,4-Dichlorobenzene pg/L 20.0 20.0 19.9 100 99.5 75-126 Dichlorodifluoromethane pg/L 20.0 23.2 20.8 116 104 28-163 1,1-Dichloroethane pg/L 20.0 19.8 20.0 99.0 100 70-130 RPD Max RPD 29.1* 20.0 0.5 20.0 0.4 20.0 0.9 20.0 12.8 20.0 15.6 20.0 1.9 20.0 0.9 20.0 1.0 20.0 4.8 20.0 2.8 20.0 0.9 20.0 5.9 20.0 1.5 20.0 3.1 20.0 2.2 20.0 0.9 20.0 1.4 20.0 0.5 20.0 10.9 20.0 1.0 20.0 * QC Fail Date: 04/25/2023 02:09 PM Page 60 of 72 Page 13 of 22 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD 1,2-Dichloroethane pg/L 20.0 21.4 21.3 107 107 68-131 0.4 20.0 1,1-Dichloroethene pg/L 20.0 19.6 20.9 98.0 105 70-154 6.4 20.0 cis-1,2-Dichloroethene pg/L 20.0 19.4 19.5 97.0 97.5 76-141 0.5 20.0 trans-1,2-Dichloroethene pg/L 20.0 19.2 19.2 96.0 96.0 76-135 0.0 20.0 1,2-Dichloropropane pg/L 20.0 18.7 18.9 93.5 94.5 77-130 1.0 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.5 20.8 103 104 65-140 1.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 21.6 21.3 108 107 67-140 1.3 20.0 Ethylbenzene pg/L 20.0 20.0 19.5 100 97.5 80-127 2.5 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 25.8 25.8 129 129 71-134 0.0 20.0 Methylene Chloride pg/L 20.0 18.7 18.7 93.5 93.5 73-131 0.0 20.0 Styrene pg/L 20.0 20.6 19.8 103 99.0 78-129 3.9 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.8 20.8 104 104 79-134 0.0 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 25.2 23.5 126 118 62-127 6.9 20.0 Tetrachloroethene pg/L 20.0 20.6 20.1 103 101 80-129 2.4 20.0 Tetrahydrofuran pg/L 20.0 24.4 23.6 122 118 70-130 3.3 20.0 Toluene pg/L 20.0 20.2 20.1 101 101 76-131 0.4 20.0 1,1,1-Trichloroethane pg/L 20.0 19.7 20.3 98.5 102 75-135 3.0 20.0 1,1,2-Trichloroethane pg/L 20.0 22.5 22.1 113 111 70-140 1.7 20.0 Trichloroethene pg/L 20.0 19.7 19.6 98.5 98.0 77-133 0.5 20.0 Trichlorofluoromethane pg/L 20.0 23.4 22.2 117 111 62-148 5.2 20.0 Vinyl Acetate pg/L 20.0 24.1 21.9 121 110 34-167 9.5 20.0 Vinyl Chloride pg/L 20.0 20.7 21.4 104 107 57-141 3.3 20.0 o-Xylene pg/L 20.0 20.5 19.8 103 99.0 78-128 3.4 20.0 m,p-Xylene pg/L 40.0 41.5 40.9 104 102 77-133 1.4 20.0 4-Bromofluorobenzene (S) 102 101 80-124 Dibromofluoromethane (S) 101 102 75-129 Date: 04/25/2023 02:09 PM Page 14 of 22 Page 61 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD 1,2-Dichloroethane - d4 (S) 109 111 63-136 Toluene-d8 (S) 99.8 99.2 77-123 Date: 04/25/2023 02:09 PM Page 15 of 22 Page 62 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31886 QC Prep Batch Method: 5030B QC Analytical Batch(es): V31887 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31886 Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/10/23 15:41 Acrylonitrile pg/L <0.230 0.230 5.00 04/10/23 15:41 Benzene pg/L <0.180 0.180 0.500 04/10/23 15:41 Bromochloromethane pg/L <0.420 0.420 1.00 04/10/23 15:41 Bromodichloromethane pg/L <0.160 0.160 0.500 04/10/23 15:41 Bromoform pg/L <1.50 1.50 5.00 04/10/23 15:41 Bromomethane pg/L <0.280 0.280 1.00 04/10/23 15:41 Carbon Disulfide pg/L <0.150 0.150 5.00 04/10/23 15:41 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/10/23 15:41 Chlorobenzene pg/L <0.190 0.190 0.500 04/10/23 15:41 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/10/23 15:41 Chloroethane pg/L <0.430 0.430 1.00 04/10/23 15:41 Chloroform pg/L <0.220 0.220 0.500 04/10/23 15:41 Chloromethane pg/L <0.220 0.220 0.500 04/10/23 15:41 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/10/23 15:41 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/10/23 15:41 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/10/23 15:41 Dibromomethane pg/L <0.230 0.230 0.500 04/10/23 15:41 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/10/23 15:41 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/10/23 15:41 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/10/23 15:41 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/10/23 15:41 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/10/23 15:41 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/10/23 15:41 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/10/23 15:41 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/10/23 15:41 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/10/23 15:41 Date: 04/25/2023 02:09 PM Page 16 of 22 Page 63 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31886 QC Analytical Batch(es): V31887 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31886 Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/10/23 15:41 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/10/23 15:41 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/10/23 15:41 Ethylbenzene pg/L <0.170 0.170 0.500 04/10/23 15:41 2-Hexanone pg/L <0.380 0.380 5.00 04/10/23 15:41 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/10/23 15:41 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/10/23 15:41 Methylene Chloride pg/L <0.330 0.330 1.00 04/10/23 15:41 Styrene pg/L <0.220 0.220 0.500 04/10/23 15:41 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/10/23 15:41 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/10/23 15:41 Tetrachloroethene pg/L <0.220 0.220 0.500 04/10/23 15:41 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/10/23 15:41 Toluene pg/L <0.220 0.220 0.500 04/10/23 15:41 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/10/23 15:41 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/10/23 15:41 Trichloroethene pg/L <0.180 0.180 0.500 04/10/23 15:41 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/10/23 15:41 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/10/23 15:41 Vinyl Acetate pg/L <1.00 1.00 2.00 04/10/23 15:41 Vinyl Chloride pg/L <0.170 0.170 0.500 04/10/23 15:41 o-Xylene pg/L <0.210 0.210 0.500 04/10/23 15:41 m,p-Xylene pg/L <0.420 0.420 1.00 04/10/23 15:41 4-Bromofluorobenzene (S) 04/10/23 15:41 106 80-124 Dibromofluoromethane (S) 04/10/23 15:41 96.8 75-129 1,2-Dichloroethane - d4 (S) 04/10/23 15:41 95.0 63-136 Date: 04/25/2023 02:09 PM Page 17 of 22 Page 64 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31886 QC Analytical Batch(es): V31887 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31886 Matrix: AQU Associated Lab Samples: 92551 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/10/23 15:41 97.0 77-123 Laboratory Control Sample & LCSD LCS-V31886 LCSD-V31886 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits Acetone pg/L 40.0 32.9 35.1 82.2 87.7 40-166 Acrylonitrile pg/L 40.0 43.6 43.5 109 109 81-127 Benzene pg/L 20.0 21.4 21.0 107 105 77-128 Bromochloromethane pg/L 20.0 21.7 21.4 109 107 78-135 Bromodichloromethane pg/L 20.0 18.7 19.7 93.5 98.5 76-138 Bromoform pg/L 20.0 19.3 18.8 96.5 94.0 71-135 Bromomethane pg/L 20.0 21.1 19.9 106 99.5 41-168 Carbon Disulfide pg/L 20.0 18.0 17.1 90.0 85.5 59-135 Carbon Tetrachloride pg/L 20.0 19.1 19.0 95.5 95.0 72-142 Chlorobenzene pg/L 20.0 20.2 20.8 101 104 78-119 Chlorodibromomethane pg/L 20.0 18.1 18.5 90.5 92.5 75-134 Chloroethane pg/L 20.0 21.2 21.8 106 109 57-142 Chloroform pg/L 20.0 21.0 21.0 105 105 77-130 Chloromethane pg/L 20.0 19.5 20.8 97.5 104 47-145 Di -Isopropyl Ether (DIPE) pg/L 20.0 21.5 22.0 108 110 60-154 1,2-Dibromo-3-Chloropropane pg/L 20.0 19.6 19.7 98.0 98.5 63-134 1,2-Dibromoethane pg/L 20.0 20.3 20.1 102 101 77-135 Dibromomethane pg/L 20.0 20.4 20.0 102 100 76-138 trans-1,4-Dichloro-2-butene pg/L 20.0 21.4 16.9 107 84.5 70-130 1,2-Dichlorobenzene pg/L 20.0 21.1 21.7 106 109 78-128 1,4-Dichlorobenzene pg/L 20.0 20.9 21.1 105 106 75-126 RPD Max RPD 6.4 20.0 0.2 20.0 1.8 20.0 1.3 20.0 5.2 20.0 2.6 20.0 5.8 20.0 5.1 20.0 0.5 20.0 2.9 20.0 2.1 20.0 2.7 20.0 0.0 20.0 6.4 20.0 2.2 20.0 0.5 20.0 0.9 20.0 1.9 20.0 23.4* 20.0 2.8 20.0 0.9 20.0 * QC Fail Date: 04/25/2023 02:09 PM Page 65 of 72 Page 18 of 22 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31886 QC Analytical Batch(es): V31887 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31886 LCSD-V31886 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 16.6 17.9 83.0 89.5 28-163 7.5 20.0 1,1-Dichloroethane pg/L 20.0 21.0 21.9 105 110 70-130 4.1 20.0 1,2-Dichloroethane pg/L 20.0 19.2 19.6 96.0 98.0 68-131 2.0 20.0 1,1-Dichloroethene pg/L 20.0 19.4 19.8 97.0 99.0 70-154 2.0 20.0 cis-1,2-Dichloroethene pg/L 20.0 21.4 21.5 107 108 76-141 0.4 20.0 trans-1,2-Dichloroethene pg/L 20.0 19.6 19.7 98.0 98.5 76-135 0.5 20.0 1,2-Dichloropropane pg/L 20.0 21.3 21.8 107 109 77-130 2.3 20.0 cis-1,3-Dichloropropene pg/L 20.0 21.5 22.0 108 110 65-140 2.2 20.0 trans-1,3-Dichloropropene pg/L 20.0 21.1 21.5 106 108 67-140 1.8 20.0 Ethylbenzene pg/L 20.0 20.0 20.2 100 101 80-127 0.9 20.0 2-Hexanone pg/L 20.0 20.1 19.1 101 95.5 64-137 5.1 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.5 20.1 97.5 101 71-134 3.0 20.0 4-Methyl-2-Pentanone pg/L 20.0 22.0 21.6 110 108 69-134 1.8 20.0 Methylene Chloride pg/L 20.0 20.6 19.3 103 96.5 73-131 6.5 20.0 Styrene pg/L 20.0 21.7 21.0 109 105 78-129 3.2 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.5 20.1 103 101 79-134 1.9 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 21.5 21.0 108 105 62-127 2.3 20.0 Tetrachloroethene pg/L 20.0 19.9 20.8 99.5 104 80-129 4.4 20.0 Tetrahydrofuran pg/L 20.0 20.4 20.0 102 100 70-130 1.9 20.0 Toluene pg/L 20.0 21.3 22.2 107 111 76-131 4.1 20.0 1,1,1-Trichloroethane pg/L 20.0 19.8 20.7 99.0 104 75-135 4.4 20.0 1,1,2-Trichloroethane pg/L 20.0 21.1 22.7 106 114 70-140 7.3 20.0 Trichloroethene pg/L 20.0 21.3 22.0 107 110 77-133 3.2 20.0 Trichlorofluoromethane pg/L 20.0 18.6 19.9 93.0 99.5 62-148 6.7 20.0 1,2,3-Trichloropropane pg/L 20.0 19.7 19.4 98.5 97.0 71-127 1.5 20.0 Vinyl Acetate pg/L 20.0 23.5 23.9 118 120 34-167 1.6 20.0 Date: 04/25/2023 02:09 PM Page 19 of 22 Page 66 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31886 QC Analytical Batch(es): V31887 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31886 LCSD-V31886 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Chloride pg/L 20.0 19.8 20.8 99.0 104 57-141 4.9 20.0 o-Xylene pg/L 20.0 20.0 20.1 100 101 78-128 0.4 20.0 m,p-Xylene pg/L 40.0 43.2 43.2 108 108 77-133 0.0 20.0 4-Bromofluorobenzene (S) 104 104 80-124 Dibromofluoromethane (S) 97.6 97.8 75-129 1,2-Dichloroethane - d4 (S) 96.0 96.4 63-136 Toluene-d8 (S) 97.8 96.4 77-123 Date: 04/25/2023 02:09 PM Page 20 of 22 Page 67 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Prep: V31479 QC Analytical Batch(es): V31482 QC Prep Batch Method: SW-9056A (PREP) Analysis Method: 9056A Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V31479 Matrix: AQU Associated Lab Samples: 92551, 92556, 92557 Blank MDL MQL Analyzed Parameter Units Result Chloride pg/L <370 370 1000 03/30/23 12:54 Nitrate (NO3-N) pg/L <76.0 76.0 200 03/30/23 12:54 Sulfate pg/L <650 650 2000 03/30/23 12:54 Laboratory Control Sample LCS-V31479 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride pg/L 40000 42000 105 80-120 Nitrate (NO3-N) pg/L 4000 3950 99.0 80-120 Sulfate pg/L 40000 43100 108 80-120 Matrix Spike & Matrix Spike Duplicate V 92557-MS-V31479 V 92557-MSD-V31479 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride pg/L 793 40000 40000 42900 43000 105 106 80-120 0.2 20 Nitrate (NO3-N) pg/L <79.0 4000 4000 3990 3990 100 100 80-120 0.0 20 Sulfate pg/L <676 40000 40000 44200 44300 111 111 80-120 0.2 20 Date: 04/25/2023 02:09 PM Page 21 of 22 Page 68 of 72 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-089-0004 QC Analytical Batch: V31423 Analysis Method: SM-3500-Fe-13 Analysis Description: Ferrous Iron Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92551, 92556 Blank MDL MQL Analyzed Parameter Units Result Ferrous Iron mg/L <0.05 0.05 0.20 03/30/23 17:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ferrous Iron mg/L 2.00 2.04 102 90-110 Matrix Spike & Matrix Spike Duplicate V 92556-MS V 92556-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ferrous Iron mg/L < 0.05 2.00 2.00 2.40 2.40 120 120 80-120 0.0 20.0 Date: 04/25/2023 02:09 PM Page 22 of 22 Page 69 of 72 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 23-089-0004 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT15 4.3C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Angelo Norvell Date & Time: 03/30/2023 10:41:22 Page 70 of 72 C s d 05 n a CL to n 0 3 CP C7 'r, vr- w l i? N a ;r lile N r. MZ i Q � xo0 r, -4 ic coCAmm -' v v m r r = A o a m -0Z-n4° 3 Al 3 y� m � m a a 1° a �- R 6• M m C) CD ( - a o CL 0 a > > � m � a ifl c _;u 3 2C 1> Q —a �p 9 0 6 m m C N a W m 7C cr. 4 m m m Ito a W 0 n a T a V1 oco, � m � L C C] �e A�44 YPN 1 7 � fr �' K C1 � � ;01 m z .. `- H x n p n0 !=21 N O. m 3 3 a H C Q.O m w m °' C N S Y■ v m mm r m �' w nyn a m [' m p ^^ m V 00 0 CG1 7 [ A m m o _W r 5 r C) No m .. m 11 sip O •�, n v 1v�nM T �RF,9 X B q D r' C]Uiyr2m21 �C h�CLm� 3 a 'm va� N2m•mi� 0 a Q 0 M �m 9 ip �y yQn0� w CA � � EA � o m � � a Z Ty ram+ 0 m 1 w 0 N 0 m J11 � o m! ! Page 71 of 72 4.m n r. O 3 00 a =r m r ca (D z @ a f? m �6 fD n 0� O r w V Y ?@ m @ 7 C- CD z;v w m W 6rn p O r C a P j� d, r+ S INA g tj [� Qrn i o ram@ nz z n 0 ra m� n M v y U t-3CM 2 3 O yImm D W w cn m m m ❑ m 0 0 n n a a � = w 'o to H 3 N. 0 _ a N G. 0 CL to m m n m � — ":S a ❑ M n 3 CL o m a : 7 N nr z N A m m 3 o `° a a 6 m m m m e v@ y m R m 0 b ro• m 4 I m y m r�npa� `° W v H a a❑ z o o e y R d o Fn n m2 p m N y m 3 [, ] naro T a z ti3 JD N� x i a s w❑- o i V �1)6- L m i O N N aea q N 0 Y Z N =r jw' tom 3� ''AA n Z A V' ti m a a° zN rn rm—� " o 7 � m a 'm.S o��� y N om ��- o a r+z`{y y rn ; O ym - ' po n prom n H° a� N r m 8� Q yc RL cL m m., m cn r. a _ w Page 72 of'72 Waypointo ANALYTICAL 5/4/2023 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville, NC, 28801 Ref: Analytical Testing Lab Report Number: 23-083-0003 Client Project Description: Jackson County Landfill Site: Jackson Project Number: C21480-01.01 Dear Jessica Mayers: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/24/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 40 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2023 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2023 South Carolina State Program 99012 12/31/2022 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00016/23-083-0003 Page 2 of 40 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 23-083-0003 Client Project Description: Jackson County Landfill Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 AM23G Pace -LA 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 RSK-175 Pace -LA 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 AM20GAX Pace -LA 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 6020B WP MTN 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 7470A WP MTN 92065 MW-06-20230322 Aqueous 03/22/2023 11:21 03/24/2023 10:25 531OC-2011 WP MTN Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 40 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-083-0003 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-06-20230322 V 92065 2320B-2011 Alkalinity (as CaCO3) 5220D-2011 COD (Chemical Oxygen Demand) 5310C-2011 TOC 6020B Barium 6020B Cobalt 6020B Copper 6020B Lead 6020B Nickel 6020B Thallium 6020B Zinc 8260D 1,4-Dichlorobenzene 8260D 1,1-Dichloroethane 8260D cis-1,2-Dichloroethene 35000 9000 684 53.0 13.8 1.31 0.701 5.32 0.518 53.6 1.07 0.801 0.499 pq/L 800 03/30/202315:20 Ng/L 8000 03/28/202310:31 1 uq/L 682 04/10/202316:06 1 Ng/L 0.453 03/30/2023 23:58 uq/L 0.060 03/30/2023 23:58 Ng/L 0.489 03/30/2023 23:58 uq/L 0.264 03/31/2023 22:23 1 pg/L 0.182 03/30/2023 23:58 uq/L 0.0610 03/30/2023 23:58 1 pg/L 4.67 04/03/2023 23:04 B pq/L 0.210 04/05/2023 04:37 Ng/L 0.240 04/05/2023 04:37 pq/L 0.200 04/05/2023 04:37 1 Page 4 of 40 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-083-0003 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/24/2023 Lab No : 92065 Matrix: Aqueous Sample ID: MW-06-20230322 Sampled: 3/22/2023 11:21 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <50.0 H Ng/L 50.0 200 1 03/24/23 14:00 SLO SM-3500-Fe-B 1,4-Dioxane <0.139 ug/L 0.139 2.00 1 03/27/23 12:03 TBL 8260D SIM Alkalinity (as CaCO3) 35000 Ng/L 800 5000 1 03/30/23 15:20 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 ug/L 2000 2000 1 03/24/23 11:18 SLO 521OB-2015 Chloride <370 Ng/L 370 1000 1 03/24/2311:27 CM] 9056A COD (Chemical Oxygen Demand) 90003 ug/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/24/23 11:27 CM] 9056A TOC 6843 ug/L 682 1000 1 04/10/23 16:06 SRJ 531OC-2011 Sulfate <650 Ng/L 650 2000 1 03/24/2311:27 CM] 9056A Sulfide <830 ug/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/30/23 23:58 CPW 6020B Arsenic <0.297 ug/L 0.297 1.00 1 03/30/23 23:58 CPW 6020B Barium 53.0 Ng/L 0.453 1.00 1 03/30/23 23:58 CPW 6020B Beryllium <0.102 ug/L 0.102 1.00 1 03/30/23 23:58 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/30/23 23:58 CPW 6020B Chromium <0.346 ug/L 0.346 1.00 1 03/30/23 23:58 CPW 6020B Cobalt 13.8 Ng/L 0.060 1.00 1 03/30/23 23:58 CPW 6020B Copper 1.31 ug/L 0.489 1.00 1 03/30/23 23:58 CPW 6020B Lead 0.7013 Ng/L 0.264 1.00 1 03/31/23 22:23 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:45 FDS 7470A Nickel 5.32 Ng/L 0.182 1.00 1 03/30/23 23:58 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/30/23 23:58 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/30/23 23:58 CPW 6020B Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions H Beyond holding time J Estimated value MQL Method Quantitation Limit Page 5 of 40 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/24/2023 Asheville , NC 28801 Report Number : 23-083-0003 REPOR T OF A NA L YSIS Lab No : 92065 Sample ID: MW-06-20230322 Matrix: Aqueous Sampled: 3/22/2023 11:21 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium 0.5183 Ng/L 0.0610 1.00 1 03/30/23 23:58 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 03/31/23 22:23 CPW 6020B Zinc 53.6 B Ng/L 4.67 10.0 1 04/03/23 23:04 CPW 6020B Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions H Beyond holding time J Estimated value MQL Method Quantitation Limit Page 6 of 40 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/24/2023 Asheville , NC 28801 Report Number : 23-083-0003 REPORT OF ANAL YSIS Lab No : 92065 Matrix: Aqueous Sample ID: MW-06-20230322 Sampled: 3/22/2023 11:21 Analytical Method: 8260D Prep Batch(es): V31637 04/04/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 04:37 TBL V31638 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 04:37 TBL V31638 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 04:37 TBL V31638 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 04:37 TBL V31638 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 04:37 TBL V31638 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 04:37 TBL V31638 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 04:37 TBL V31638 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 04:37 TBL V31638 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 04:37 TBL V31638 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 04:37 TBL V31638 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 04:37 TBL V31638 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 04:37 TBL V31638 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 04:37 TBL V31638 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 04:37 TBL V31638 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 04:37 TBL V31638 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 04:37 TBL V31638 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 04:37 TBL V31638 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 1,4-Dichlorobenzene 1.07 Ng/L 0.210 0.500 1 04/05/23 04:37 TBL V31638 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 04:37 TBL V31638 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions H Beyond holding time J Estimated value MQL Method Quantitation Limit Page 7 of 40 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/24/2023 Asheville , NC 28801 Report Number : 23-083-0003 REPOR T OF A NA L YSIS Lab No : 92065 Matrix: Aqueous Sample ID: MW-06-20230322 Sampled: 3/22/2023 11:21 Analytical Method: 8260D Prep Batch(es): V31637 04/04/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 0.801 Ng/L 0.240 0.500 1 04/05/23 04:37 TBL V31638 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 04:37 TBL V31638 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 04:37 TBL V31638 cis- 1,2-Dich loroethene 0.4993 ug/L 0.200 0.500 1 04/05/23 04:37 TBL V31638 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 04:37 TBL V31638 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 04:37 TBL V31638 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 04:37 TBL V31638 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 04:37 TBL V31638 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 04:37 TBL V31638 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 04:37 TBL V31638 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 04:37 TBL V31638 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 04:37 TBL V31638 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 04:37 TBL V31638 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 04:37 TBL V31638 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 04:37 TBL V31638 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 04:37 TBL V31638 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 04:37 TBL V31638 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 04:37 TBL V31638 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 04:37 TBL V31638 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 04:37 TBL V31638 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions H Beyond holding time J Estimated value MQL Method Quantitation Limit Page 8 of 40 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/24/2023 Asheville , NC 28801 Report Number : 23-083-0003 REPOR T OF A NA L YSIS Lab No : 92065 Matrix: Aqueous Sample ID: MW-06-20230322 Sampled: 3/22/2023 11:21 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ B Analyte detected in blank Definitions H Beyond holding time MQL Method Quantitation Limit Prep Batch(es): V31637 04/04/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 97.6 Limits: 80-124% 101 Limits: 75-129% 99.8 Limits: 63-136% 109 Limits: 77-123% 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 1 04/05/23 04:37 TBL V31638 DF Dilution Factor J Estimated value Page 9 of 40 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Access Analytical 15 Thames Valley Rd Irmo, SC 29063 ATTENTION Ashley Amick PROJECTID 23-083-0003 LABORATORY REPORT NUMBER 223042861 DATE 05/01 /2023 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979 Innovation Park Dr., Baton Rouge, LA 70820. - Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 223042861 05/01/2023 10:24 Page 1 of 13 Page 10 of 40 LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 Analytical ANALYTICAL RESULTS Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 05/01/2023 Report p 223042661 I1II111111IIII Project 23-083-0003 Samples Collected 3/22/23 Deliver To Additional Recipients Ashley Amick Angela Martin, Access Analytical Access Analytical Lab Reports, Access Analytical 15 Thames Valley Rd Irmo, SC 29063 803-781-4243 ACCREDITED CERT JI 6429,01 Lab Report#: 223042861 05/01/2023 10:24 Page 2 of 13 Page 11 of 40 Report#: 223042861 arraryiecar' Project ID: 23-083-0003 Report Date: 05/01/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223042861 Lab Report#: 223042861 05/01/2023 10:24 Page 3 of 13 Page 12 of 40 !"aceA eVica! Report#: 223042861 Project ID: 23-083-0003 Certifications Report Date: 05/01/2023 Certification Certification Number A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Lab Report#: 223042861 05/01/2023 10:24 Page 4 of 13 Page 13 of 40 ceAnalyfrca! Report#: 223042861 Project ID: 23-083-0003 Report Date: 05/01/2023 Case Narrative Client: Access Analytical Report: 223042861 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Lab Report#: 223042861 05/01/2023 10:24 Page 5 of 13 Page 14 of 40 Report#: 223042861 aceA��alyirca! Project ID: 23-083-0003 Report Date: 05/01/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303290501 MW-06-20230322 22303290505 MW-06-20230322 Water 3/22/23 11:21 3/28/23 09:57 Bubble Strip 3/22/23 11:21 3/28/23 09:57 Lab Report#: 223042861 05/01/2023 10:24 Page 6 of 13 Page 15 of 40 ceAnalyfrca! Report#: Project ID: 223042861 23-083-0003 Report Date: 05/01/2023 Results and Detection Limits are adjusted for dilution and Detect Summary moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22303290501 22303290501 22303290501 22303290501 MW-06-20230322 MW-06-20230322 MW-06-20230322 MW-06-20230322 Lactic Acid Acetic Acid Propionic Acid Formic Acid mg/L mg/L mg/L mg/L 0.39J 2.9 0.15J 7.1 1 1 1 1 NA NA NA NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303290501 22303290505 MW-06-20230322 MW-06-20230322 Methane Hydrogen ug/L nM 2.7J 100 1 5 NA NA EPA RSK-175 Lab ID Client ID Parameter Units Result Dil. %Moist 22303290501 MW-06-20230322 Carbon Dioxide ug/L 141000 1 NA Lab Report#: 223042861 05/01/2023 10:24 Page 7 of 13 Page 16 of 40 Report#: 223042861 Project ID: 23-083-0003 Report Date: 05/01/2023 Sample Results MW-06-20230322 Collect Date 03/22/2023 11:21 Lab ID 22303290501 Receive Date 03/28/2023 09:57 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 22:32 763291 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 141000 585 1200 ug/L AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/01/2314:42 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.39J 0.053 0.50 mg/L 64-19-7 Acetic Acid 2.9 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.151 0.053 0.50 mg/L 64-18-6 Formic Acid 7.1 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.0581.1 0.058 0.50 mg/L 127-17-3 Pyruvic Acid 0.060LI 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 07:06 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 2.7J 2.0 5.0 ug/L 74-84-0 Ethane 0.17U 0.17 1.0 ug/L 74-85-1 Ethene 0.24U 0.24 1.0 ug/L MW-06-20230322 Collect Date 03/22/2023 11:21 Lab ID 22303290505 Receive Date 03/28/2023 09:57 Matrix Bubble Strip AM20GAX *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 5 03/30/2310:39 762809 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 100 2.5 9.5 nM Lab Report#: 223042861 05/01/2023 10:24 Page 8 of 13 Page 17 of 40 2"Arialyirca! Report#: 223042861 Project ID: 23-083-0003 GC Volatiles QC Summary Report Date: 05/01/2023 Analytical Batch Client ID MB763291 LCS763291 LCSD763291 763291 Lab ID 2469770 2469771 2469772 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/05/23 22:16 04/05/23 21:44 04/05/23 22:00 Matrix Water Water Water EPA RSK-175 Units ug/L Spike Result %R I Control Spike I Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Carbon Dioxide 124-38-9 585UI 5851 338001 38100 11131 38 - 147 1 338001 37900 1121 1 40 Lab Report#: 223042861 05/01/2023 10:24 Page 9 of 13 Page 18 of 40 2"Arialyirca! Report#: 223042861 Project ID: 23-083-0003 General Chemistry QC Summary Report Date: 05/01/2023 Analytical Batch Client ID MB762926 LCS762926 LCSD762926 762926 Lab ID 2467944 2467945 2467946 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/01/23 03:39 04/01/23 04:11 04/01/23 04:42 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Lactic Acid 50-21-5 0.053U 0.053 2.0 2.3 115 70 - 130 2.0 2.3 116 1 20 Acetic Acid 64-19-7 0.12U 0.12 2.0 1.9 97 70 - 130 2.0 2.0 98 0 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.0 102 70 - 130 2.0 2.1 103 2 20 Formic Acid 64-18-6 0.055U 0.055 2.0 1.9 97 70 - 130 2.0 1.9 96 1 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.0 102 70 - 130 2.0 2.1 103 1 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 1.9 95 70 - 130 2.0 1.9 95 1 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.1 103 70 - 130 2.0 2.1 107 4 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 106 70 - 130 2.0 2.0 99 7 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.0 102 70 - 130 2.0 2.2 109 7 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 101 70 - 130 2.0 2.0 101 1 20 Lab Report#: 223042861 05/01/2023 10:24 Page 10 of 13 Page 19 of 40 2"Arialyirca! Report#: 223042861 Project ID: 23-083-0003 General Chromatography QC Summary Report Date: 05/01/2023 Analytical Batch Client ID MB762809 LCS762809 LCSD762809 762809 Lab ID 2467477 2467478 2467479 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/30/23 06:30 03/30/23 06:04 03/30/23 06:16 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R I Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 1 0.49U 1 0.49 121 12 11011 70 - 130 121 13 11081 6 1 20 Analytical Batch Client ID MB762901 LCS762901 LCSD762901 762901 Lab ID 2467877 2467878 2467879 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/31/23 05:48 03/31/23 05:16 03/31/23 05:32 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Methane 74-82-8 2.2J 2.0 380 340 90 70-130 380 380 101 11 20 Ethane 74-84-0 0.17U 0.17 97 100 103 70 - 130 97 110 116 12 20 Ethene 74-85-1 0.24U 0.24 120 120 102 70-130 120 140 115 12 20 Lab Report#: 223042861 05/01/2023 10:24 Page 11 of 13 Page 20 of 40 co fu L� f�1 C: O; V7 ur �r G Q_ 1r? 00 Cif CV Liz c7 C! 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Result Limits Alkalinity (as CaCO3) pg/L 250000 254000 102 90-110 Duplicate V 92048-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 21000 21000 0.0 20 03/30/23 15:20 Date: 05/04/2023 08:05 AM Page 1 of 16 Page 23 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Analytical Batch: V31283 Analysis Method: 4500S2F-2011 Analysis Description: Sulfide Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed Parameter Units Result Sulfide pg/L <830 830 2000 03/27/2313:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Sulfide pg/L 10000 9500 95.0 70-122 Date: 05/04/2023 08:05 AM Page 2 of 16 Page 24 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Analytical Batch: V31364 Analysis Method: 521OB-2015 Analysis Description: Biochemical Oxygen Demand (BOD) Glucose-Glutamic Acid GGA Result Range Analyzed Parameter Units Biochemical Oxygen Demand (5-day) Ng/L 219 167.5-228.E 03/24/23 11:18 Duplicate V 92067-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Biochemical Oxygen Demand (5-day) Ng/L 267000 255000 4.5 30 03/24/23 11:18 Date: 05/04/2023 08:05 AM Page 3 of 16 Page 25 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Analytical Batch: V31271 Analysis Method: 5220D-2011 Analysis Description: Chemical Oxygen Demand (COD) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed Parameter Units Result COD (Chemical Oxygen Demand) pg/L <8000 8000 30000 03/28/23 10:31 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits COD (Chemical Oxygen Demand) pg/L 50000 54000 108 90-110 Matrix Spike & Matrix Spike Duplicate V 92332-MS V 92332-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. COD (Chemical Oxygen Demand) pg/L 17000 50000 50000 59000 57000 84.0 80.0 80-120 3.4 20 Date: 05/04/2023 08:05 AM Page 4 of 16 Page 26 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: L672667 QC Analytical Batch(es): L673329,L673574,L673995,L674299 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-1-672667 Matrix: AQU Associated Lab Samples: 92065 Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Blank MDL Units Result pg/L <0.618 0.618 pg/L <0.297 0.297 pg/L <0.453 0.453 pg/L <0.102 0.102 pg/L <0.350 0.350 pg/L <0.346 0.346 pg/L <0.060 0.060 pg/L <0.489 0.489 pg/L <0.264 0.264 pg/L <0.182 0.182 pg/L <0.703 0.703 pg/L <0.0570 0.0570 pg/L <0.0610 0.0610 pg/L <0.767 0.767 pg/L 7.32 4.67 Laboratory Control Sample LCS-L672667 MQL 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 10.0 Analyzed 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/31/23 22:18 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/30/23 23:51 03/31/23 22:18 04/03/23 23:00 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 93.8 94.0 80-120 Arsenic pg/L 50.0 51.1 102 80-120 Barium pg/L 100 95.1 95.0 80-120 Beryllium pg/L 50.0 52.8 106 80-120 Cadmium pg/L 10.0 9.83 98.0 80-120 Chromium pg/L 100 100 100 80-120 Cobalt pg/L 100 102 102 80-120 Copper pg/L 50.0 50.4 101 80-120 Date: 05/04/2023 08:05 AM Page 5 of 16 Page 27 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: L672667 QC Prep Batch Method: 3005A Laboratory Control Sample LCS-1-672667 QC Analytical Batch(es): L673329,L673574,L673995,L674299 Analysis Method: 6020B Analysis Description: Metals Analyses Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 50.0 49.0 98.0 80-120 Nickel pg/L 50.0 50.6 101 80-120 Selenium pg/L 100 104 104 80-120 Silver pg/L 10.0 10.1 101 80-120 Thallium pg/L 10.0 9.84 98.0 80-120 Vanadium pg/L 500 490 98.0 80-120 Zinc pg/L 500 522 104 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92162-MS-L672667 MS Spike Result Conc. V 92162-MSD-L672667 MSD MS Result MSD Spike Result Conc. MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.618 100 100 92.8 92.3 93.0 92.0 75-125 0.5 20.0 Arsenic pg/L < 0.297 50.0 50.0 50.8 52.7 102 105 75-125 3.6 20.0 Barium pg/L 53.4 100 100 144 145 91.0 92.0 75-125 0.6 20.0 Beryllium pg/L < 0.102 50.0 50.0 51.4 50.8 103 102 75-125 1.1 20.0 Cadmium pg/L < 0.350 10.0 10.0 10.1 9.56 101 96.0 75-125 5.4 20.0 Chromium pg/L 0.366 100 100 100 101 100 101 75-125 0.9 20.0 Cobalt pg/L 0.185 100 100 99.4 99.1 99.0 99.0 75-125 0.3 20.0 Copper pg/L 1.68 50.0 50.0 48.5 48.1 94.0 93.0 75-125 0.8 20.0 Lead pg/L < 0.264 50.0 50.0 50.7 51.0 101 102 75-125 0.5 20.0 Nickel pg/L 2.27 50.0 50.0 50.1 51.1 96.0 98.0 75-125 1.9 20.0 Selenium pg/L < 0.703 100 100 101 103 101 103 75-125 1.9 20.0 Silver pg/L < 0.0570 10.0 10.0 9.63 9.68 96.0 97.0 75-125 0.5 20.0 Thallium pg/L < 0.0610 10.0 10.0 10.3 10.4 103 104 75-125 0.9 20.0 Vanadium pg/L 2.08 500 500 421 422 84.0 84.0 75-125 0.2 20.0 Zinc pg/L 10.9 500 500 452 455 88.0 89.0 75-125 0.6 20.0 Date: 05/04/2023 08:05 AM Page 6 of 16 Page 28 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: L672667 QC Analytical Batch(es): L673329,L673574,L673995,L674299 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 92162-PDS-L672667 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 43.6 87.0 03/31/23 01:39 Arsenic pg/L 25.0 100 03/31/23 01:39 Barium pg/L 71.9 94.0 03/31/23 01:39 Beryllium pg/L 24.9 100 03/31/23 01:39 Cadmium pg/L 4.93 99.0 03/31/23 01:39 Chromium Ng/L 50.3 100 03/31/23 01:39 Cobalt pg/L 49.7 99.0 03/31/23 01:39 Copper pg/L 24.7 95.0 03/31/23 01:39 Lead pg/L 24.9 100 03/31/23 01:39 Nickel pg/L 25.1 96.0 03/31/23 01:39 Selenium pg/L 51.1 102 03/31/23 01:39 Silver pg/L 4.79 96.0 03/31/23 01:39 Thallium Ng/L 5.33 107 03/31/23 01:39 Vanadium pg/L 213 85.0 04/04/23 00:43 Zinc pg/L 236 92.0 04/04/23 00:43 Date: 05/04/2023 08:05 AM Page 7 of 16 Page 29 of 40 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: L673565 QC Analytical Batch(es): L673738 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-673565 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 04/03/23 12:32 Laboratory Control Sample LCS-1-673565 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 5.22 104 80-120 Matrix Spike & Matrix Spike Duplicate V 92268-MS-L673565 V 92268-MSD-L673565 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 5.08 5.66 102 113 80-120 10.8 20 Post Digestion Spike V 92268-PDS-L673565 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.79 96.0 04/03/23 13:03 Date: 05/04/2023 08:05 AM Page 8 of 16 Page 30 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31302 QC Analytical Batch(es): V31303 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31302 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/27/2311:38 4-Bromofluorobenzene (S) 03/27/23 11:38 88.6 70-130 Laboratory Control Sample LCS-V31302 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 52.2 104 70-130 4-Bromofluorobenzene (S) 107 70-130 Matrix Spike & Matrix Spike Duplicate V 92065-MS-V31302 V 92065-MSD-V31302 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. 1,4-Dioxane pg/L < 0.139 50.0 50.0 49.1 51.1 98.2 102 70-130 3.9 20.0 4-Bromofluorobenzene (S) 112 123 70-130 Date: 05/04/2023 08:05 AM Page 9 of 16 Page 31 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31637 QC Prep Batch Method: 5030B QC Analytical Batch(es): V31638 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31637 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/05/23 02:59 Acrylonitrile pg/L <0.230 0.230 5.00 04/05/23 02:59 Benzene pg/L <0.180 0.180 0.500 04/05/23 02:59 Bromochloromethane pg/L <0.420 0.420 1.00 04/05/23 02:59 Bromodichloromethane pg/L <0.160 0.160 0.500 04/05/23 02:59 Bromoform pg/L <1.50 1.50 5.00 04/05/23 02:59 Bromomethane pg/L <0.280 0.280 1.00 04/05/23 02:59 Carbon Disulfide pg/L <0.150 0.150 5.00 04/05/23 02:59 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/05/23 02:59 Chlorobenzene pg/L <0.190 0.190 0.500 04/05/23 02:59 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/05/23 02:59 Chloroethane pg/L <0.430 0.430 1.00 04/05/23 02:59 Chloroform pg/L <0.220 0.220 0.500 04/05/23 02:59 Chloromethane pg/L <0.220 0.220 0.500 04/05/23 02:59 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/05/23 02:59 1,2-Dibromo-3-Chloropropane pg/L < 1.10 1.10 2.00 04/05/23 02:59 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/05/23 02:59 Dibromomethane pg/L <0.230 0.230 0.500 04/05/23 02:59 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/05/23 02:59 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/05/23 02:59 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/05/23 02:59 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/05/23 02:59 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/05/23 02:59 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/05/23 02:59 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/05/23 02:59 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/05/23 02:59 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/05/23 02:59 Date: 05/04/2023 08:05 AM Page 10 of 16 Page 32 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31637 QC Analytical Batch(es): V31638 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31637 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/05/23 02:59 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/05/23 02:59 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/05/23 02:59 Ethylbenzene pg/L <0.170 0.170 0.500 04/05/23 02:59 2-Hexanone pg/L <0.380 0.380 5.00 04/05/23 02:59 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/05/23 02:59 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/05/23 02:59 Methylene Chloride pg/L <0.330 0.330 1.00 04/05/23 02:59 Styrene pg/L <0.220 0.220 0.500 04/05/23 02:59 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 02:59 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 02:59 Tetrachloroethene pg/L <0.220 0.220 0.500 04/05/23 02:59 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/05/23 02:59 Toluene pg/L <0.220 0.220 0.500 04/05/23 02:59 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/05/23 02:59 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/05/23 02:59 Trichloroethene pg/L <0.180 0.180 0.500 04/05/23 02:59 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/05/23 02:59 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/05/23 02:59 Vinyl Acetate pg/L <1.00 1.00 2.00 04/05/23 02:59 Vinyl Chloride pg/L <0.170 0.170 0.500 04/05/23 02:59 o-Xylene pg/L <0.210 0.210 0.500 04/05/23 02:59 m,p-Xylene pg/L <0.420 0.420 1.00 04/05/23 02:59 4-Bromofluorobenzene (S) 04/05/23 02:59 98.6 80-124 Dibromofluoromethane (S) 04/05/23 02:59 100 75-129 1,2-Dichloroethane - d4 (S) 04/05/23 02:59 101 63-136 Date: 05/04/2023 08:05 AM Page 11 of 16 Page 33 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31637 QC Analytical Batch(es): V31638 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31637 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8(S) 04/05/23 02:59 110 77-123 Laboratory Control Sample & LCSD LCS-V31637 LCSD-V31637 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 34.8 36.8 87.0 92.0 40-166 5.5 20.0 Acrylonitrile pg/L 40.0 29.9 32.2 74.7* 80.5* 81-127 7.4 20.0 Benzene pg/L 20.0 18.4 18.5 92.0 92.5 77-128 0.5 20.0 Bromochloromethane pg/L 20.0 18.2 18.3 91.0 91.5 78-135 0.5 20.0 Bromodichloromethane pg/L 20.0 17.2 17.2 86.0 86.0 76-138 0.0 20.0 Bromoform pg/L 20.0 18.5 19.1 92.5 95.5 71-135 3.1 20.0 Bromomethane pg/L 20.0 18.6 20.5 93.0 103 41-168 9.7 20.0 Carbon Disulfide pg/L 20.0 17.7 17.5 88.5 87.5 59-135 1.1 20.0 Carbon Tetrachloride pg/L 20.0 19.0 19.0 95.0 95.0 72-142 0.0 20.0 Chlorobenzene pg/L 20.0 20.7 20.4 104 102 78-119 1.4 20.0 Chlorodibromomethane pg/L 20.0 19.5 19.7 97.5 98.5 75-134 1.0 20.0 Chloroethane pg/L 20.0 18.5 19.0 92.5 95.0 57-142 2.6 20.0 Chloroform pg/L 20.0 18.3 18.8 91.5 94.0 77-130 2.6 20.0 Chloromethane pg/L 20.0 15.5 15.5 77.5 77.5 47-145 0.0 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 15.8 16.1 79.0 80.5 60-154 1.8 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 19.5 20.2 97.5 101 63-134 3.5 20.0 1,2-Dibromoethane pg/L 20.0 20.1 20.1 101 101 77-135 0.0 20.0 Dibromomethane pg/L 20.0 17.6 18.1 88.0 90.5 76-138 2.8 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 14.7 14.9 73.5 74.5 70-130 1.3 20.0 1,2-Dichlorobenzene pg/L 20.0 21.7 21.1 109 106 78-128 2.8 20.0 1,4-Dichlorobenzene pg/L 20.0 21.3 20.7 107 104 75-126 2.8 20.0 * QC Fail Date: 05/04/2023 08:05 AM Page 12 of 16 Page 34 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31637 QC Analytical Batch(es): V31638 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31637 LCSD-V31637 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 18.9 21.8 94.5 109 28-163 14.2 20.0 1,1-Dichloroethane pg/L 20.0 18.0 18.2 90.0 91.0 70-130 1.1 20.0 1,2-Dichloroethane pg/L 20.0 17.5 18.1 87.5 90.5 68-131 3.3 20.0 1,1-Dichloroethene pg/L 20.0 19.0 19.3 95.0 96.5 70-154 1.5 20.0 cis-1,2-Dichloroethene pg/L 20.0 17.9 17.9 89.5 89.5 76-141 0.0 20.0 trans-1,2-Dichloroethene pg/L 20.0 18.4 18.5 92.0 92.5 76-135 0.5 20.0 1,2-Dichloropropane pg/L 20.0 17.5 17.7 87.5 88.5 77-130 1.1 20.0 cis-1,3-Dichloropropene pg/L 20.0 17.7 17.5 88.5 87.5 65-140 1.1 20.0 trans-1,3-Dichloropropene pg/L 20.0 17.3 17.7 86.5 88.5 67-140 2.2 20.0 Ethylbenzene pg/L 20.0 20.2 19.8 101 99.0 80-127 2.0 20.0 2-Hexanone pg/L 20.0 15.0 16.6 75.0 83.0 64-137 10.1 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.2 20.8 96.0 104 71-134 8.0 20.0 4-Methyl-2-Pentanone pg/L 20.0 14.5 15.4 72.5 77.0 69-134 6.0 20.0 Methylene Chloride pg/L 20.0 16.8 16.4 84.0 82.0 73-131 2.4 20.0 Styrene pg/L 20.0 20.4 20.0 102 100 78-129 1.9 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.7 20.3 104 102 79-134 1.9 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 19.3 19.5 96.5 97.5 62-127 1.0 20.0 Tetrachloroethene pg/L 20.0 21.7 21.5 109 108 80-129 0.9 20.0 Tetrahydrofuran pg/L 20.0 15.5 16.4 77.5 82.0 70-130 5.6 20.0 Toluene pg/L 20.0 18.2 18.0 91.0 90.0 76-131 1.1 20.0 1,1,1-Trichloroethane pg/L 20.0 18.9 18.6 94.5 93.0 75-135 1.6 20.0 1,1,2-Trichloroethane pg/L 20.0 18.5 18.2 92.5 91.0 70-140 1.6 20.0 Trichloroethene pg/L 20.0 18.8 18.9 94.0 94.5 77-133 0.5 20.0 Trichlorofluoromethane pg/L 20.0 22.1 23.3 111 117 62-148 5.2 20.0 1,2,3-Trichloropropane pg/L 20.0 19.0 19.5 95.0 97.5 71-127 2.5 20.0 Vinyl Acetate pg/L 20.0 17.9 17.9 89.5 89.5 34-167 0.0 20.0 Date: 05/04/2023 08:05 AM Page 13 of 16 Page 35 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31637 QC Analytical Batch(es): V31638 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31637 LCSD-V31637 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Chloride pg/L 20.0 19.0 19.1 95.0 95.5 57-141 0.5 20.0 o-Xylene pg/L 20.0 19.9 19.5 99.5 97.5 78-128 2.0 20.0 m,p-Xylene pg/L 40.0 42.2 41.3 106 103 77-133 2.1 20.0 4-Bromofluorobenzene (S) 97.4 96.0 80-124 Dibromofluoromethane (S) 100 101 75-129 1,2-Dichloroethane - d4 (S) 101 106 63-136 Toluene-d8(S) 109 110 77-123 Date: 05/04/2023 08:05 AM Page 14 of 16 Page 36 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Prep: V31253 QC Analytical Batch(es): V31260,V31422 QC Prep Batch Method: SW-9056A (PREP) Analysis Method: 9056A Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V31253 Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed Parameter Units Result Chloride pg/L <370 370 1000 03/24/23 10:55 Nitrate (NO3-N) pg/L <76.0 76.0 200 03/24/23 10:55 Sulfate pg/L <650 650 2000 03/24/23 10:55 Laboratory Control Sample LCS-V31253 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride pg/L 40000 40500 101 80-120 Nitrate (NO3-N) pg/L 4000 3710 93.0 80-120 Sulfate pg/L 40000 42700 107 80-120 Matrix Spike & Matrix Spike Duplicate V 91889-MS-V31253 V 91889-MSD-V31253 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride pg/L 6800 40000 40000 48100 48100 103 103 80-120 0.0 20 Nitrate (NO3-N) pg/L 379 4000 4000 4290 4290 98.0 98.0 80-120 0.0 20 Sulfate pg/L 7630 40000 40000 51800 51900 110 111 80-120 0.1 20 Date: 05/04/2023 08:05 AM Page 15 of 16 Page 37 of 40 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-083-0003 QC Analytical Batch: V31190 Analysis Method: SM-3500-Fe-13 Analysis Description: Ferrous Iron Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92065 Blank MDL MQL Analyzed Parameter Units Result Ferrous Iron pg/L <50.0 50.0 200 03/24/23 14:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ferrous Iron pg/L 2000 2070 104 90-110 Matrix Spike & Matrix Spike Duplicate V 92065-MS V 92065-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ferrous Iron pg/L <50.0 2000 2000 1960 1930 98.0 97.0 80-120 1.5 20 Date: 05/04/2023 08:05 AM Page 16 of 16 Page 38 of 40 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 23-083-0003 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT15 0.3C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes * No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Angelo Norvell Date & Time: 03/24/2023 11:04:45 Page 39 of 40 0 3 3 cn Wq r m yr mm z n--I v 1 0 z 0 0 ro ra m� nm m O y m pCpa�na m x [n to m m -v m 0 d c o a < _ m' n n b a . m m m d p O 44 Mz��0 m x Q C. W K �A, a m m 0 CD (D n 0 0 o a S a ? 3 •,y � N n-F Z 7 4n a 0. i� - y l� !"* r p� N z n N � v m 7 3 o X1 C Q 7 _ T] 7 m C w 3 ID d N N• W= 2 5m mma� O a� w a 7� o z I� nm 3 c° D° 3 r m a w m L0 7 n 7 0 rrr n M M r. m m p 2 m I Z mo9m FF z d'e nfA c m 9 r 0 E. zo m O fo aQ C V nx y OL w n w- m r A n° x� 3 ❑ m � A 1 m r m h a+ w G ^ mm [ripnm c m 0 m ;L C M v m imp 4ya�xlp Q� Z CL g a� rm p 0 y 3 X v n a m 'All 5 u r m ;u C) cn -0 i ion OR Y a z m N ' rD n �0 Z, � � cy i N=nz�. _ rn A r � �c�mm G r Z CA m � _ D R FL -j ti In m 9 3 Z N '' > •S 0 3 m z N z 0 I o !Illf 0 � rxil r Page 40 of 40 Waypointo ANALYTICAL 5/4/2023 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville, NC, 28801 Ref: Analytical Testing Lab Report Number: 23-084-0001 Client Project Description: Jackson County Landfill Site: Jackson Project Number: C21480-01.01 Dear Jessica Mayers: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/25/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 84 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2023 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2023 South Carolina State Program 99012 12/31/2022 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00016/23-084-0001 Page 2 of 84 Waypoint. (2) ANALYTICAL Sample Report Number: 23-084-0001 Client Project Description: Jackson County Landfill 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca I som Summary Table Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 AM20GAX Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 RSK-175 Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 AM23G Pace -LA 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 7470A WP MTN 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 6020E WP MTN 92263 MW-01-20230323 Aqueous 03/23/2023 10:40 03/25/2023 10:15 531OC-2011 WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 RSK-175 Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 AM23G Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 AM20GAX Pace -LA 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 7470A WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 6020E WP MTN 92264 MW-02-20230323 Aqueous 03/23/2023 15:12 03/25/2023 10:15 531OC-2011 WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 RSK-175 Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 AM23G Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 AM20GAX Pace -LA 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 7470A WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 6020E WP MTN 92265 MW-05R-20230323 Aqueous 03/23/2023 12:52 03/25/2023 10:15 531OC-2011 WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 7470A WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 6020E WP MTN 92266 SW-01-20230323 Aqueous 03/23/2023 18:00 03/25/2023 10:15 EPA-200.7 WP MTN 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 7470A WP MTN Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 23-084-0001 Client Project Description: Jackson County Landfill Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 6020B WP MTN 92267 SW-02-20230323 Aqueous 03/23/2023 16:08 03/25/2023 10:15 EPA-200.7 WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 EPA-200.7 WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 7470A WP MTN 92268 SW-03-20230323 Aqueous 03/23/2023 16:47 03/25/2023 10:15 6020E WP MTN 92269 TB-23240323 Aqueous 03/23/2023 03/25/2023 10:15 Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 4 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica l.com Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-01-20230323 V 92263 Result Units Report Limit Analyzed 2320B-2011 Alkalinity (as CaCO3) 77000 pg/L 800 03/30/2023 15:20 5220D-2011 COD (Chemical Oxygen Demand) 9000 Ng/L 8000 03/28/2023 10:31 5310C-2011 TOC 902 pg/L 682 04/10/202316:44 6020E Barium 104 Ng/L 0.453 03/31/2023 04:48 6020E Cadmium 0.810 pg/L 0.350 03/31/2023 04:48 6020E Cobalt 115 Ng/L 0.060 03/31/2023 04:48 6020E Copper 2.91 pg/L 0.489 03/31/2023 04:48 6020E Lead 0.307 Ng/L 0.264 03/31/2023 04:48 6020E Nickel 16.4 pg/L 0.182 03/31/2023 04:48 6020E Thallium 1.55 Ng/L 0.0610 03/31/2023 04:48 6020E Zinc 60.5 pg/L 4.67 03/31/2023 04:48 8260D 1,4-Dichlorobenzene 5.79 Ng/L 2.10 04/05/2023 22:20 9056A Chloride 437 pg/L 370 03/25/202310:23 SM-3500-Fe-B Ferrous Iron 8340 Ng/L 1250 03/27/2023 17:15 MW-02-20230323 V 92264 5220D-2011 COD (Chemical Oxygen Demand) 10000 pg/L 8000 03/28/2023 10:31 5310C-2011 TOC 1020 Ng/L 682 04/10/2023 17:22 6020B Arsenic 2.53 pg/L 0.297 03/31/2023 04:51 6020B Dissolved Arsenic 0.906 Ng/L 0.297 03/30/2023 22:17 6020B Barium 188 pg/L 0.453 03/31/2023 04:51 6020B Dissolved Barium 160 Ng/L 0.453 03/30/2023 22:17 6020B Beryllium 0.887 pg/L 0.102 03/31/2023 04:51 6020B Dissolved Beryllium 0.344 Ng/L 0.102 03/30/2023 22:17 6020E Chromium 41.7 pg/L 0.346 03/31/2023 04:51 6020B Dissolved Chromium 22.9 Ng/L 0.346 03/30/2023 22:17 6020B Cobalt 59.3 pg/L 0.060 03/31/2023 04:51 6020E Dissolved Cobalt 51.0 Ng/L 0.060 03/30/2023 22:17 6020E Copper 34.9 pg/L 0.489 03/31/2023 04:51 6020E Dissolved Copper 19.4 Ng/L 0.489 03/30/2023 22:17 6020E Lead 9.21 pg/L 0.264 03/31/2023 04:51 6020E Dissolved Lead 5.57 Ng/L 0.264 03/30/2023 22:17 6020E Dissolved Nickel 19.9 pg/L 0.182 03/30/2023 22:17 6020E Nickel 31.8 Ng/L 0.182 03/31/2023 04:51 6020E Selenium 3.19 pg/L 0.703 03/31/2023 04:51 6020E Dissolved Selenium 2.15 Ng/L 0.703 03/30/2023 22:17 6020B Thallium 0.771 Ng/L 0.0610 03/31/2023 04:51 Qualifiers I 0 0 .1 IJ i I 0 Page 5 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica Isom Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-02-20230323 V 92264 Result Units Report Limit Analyzed Qualifiers 6020B Dissolved Thallium 0.573 pg/L 0.0610 03/30/2023 22:17 6020E Vanadium 52.5 Ng/L 0.767 03/31/2023 04:51 6020E Dissolved Vanadium 29.0 pg/L 0.767 03/30/2023 22:17 6020E Zinc 160 Ng/L 4.67 03/31/2023 04:51 6020B Dissolved Zinc 173 pg/L 4.67 03/30/2023 22:17 8260D 1,1-Dichloroethane 0.244 Ng/L 0.240 04/05/2023 20:16 8260D SIM 1,4-Dioxane 1.79 pg/L 0.139 03/28/2023 12:18 MW-05R-20230323 V 92265 2320B-2011 Alkalinity (as CaCO3) 217000 Ng/L 800 03/31/2023 16:00 5210E-2015 Biochemical Oxygen Demand (5-day) 4000 pg/L 2000 03/25/2023 08:25 5220D-2011 COD (Chemical Oxygen Demand) 22000 Ng/L 8000 03/28/2023 10:31 5310C-2011 TOC 3120 pg/L 682 04/10/202318:00 6020E Arsenic 6.76 Ng/L 0.297 03/31/2023 04:55 6020E Dissolved Arsenic 5.08 pg/L 0.297 03/30/2023 22:21 6020E Barium 234 Ng/L 0.453 03/31/2023 04:55 6020E Dissolved Barium 242 pg/L 0.453 03/30/2023 22:21 6020E Chromium 4.84 Ng/L 0.346 03/31/2023 04:55 6020E Dissolved Chromium 0.776 pg/L 0.346 03/30/2023 22:21 6020E Cobalt 16.3 Ng/L 0.060 03/31/2023 04:55 6020E Dissolved Cobalt 16.3 pg/L 0.060 03/30/2023 22:21 6020E Copper 8.39 Ng/L 0.489 03/31/2023 04:55 6020E Dissolved Copper 3.20 pg/L 0.489 03/30/2023 22:21 6020E Lead 1.66 Ng/L 0.264 03/31/2023 04:55 6020E Dissolved Lead 1.22 pg/L 0.264 03/30/2023 22:21 6020E Dissolved Nickel 3.62 Ng/L 0.182 03/30/2023 22:21 6020E Nickel 5.96 pg/L 0.182 03/31/2023 04:55 6020E Thallium 0.147 Ng/L 0.0610 03/31/2023 04:55 6020E Dissolved Thallium 0.0638 pg/L 0.0610 03/30/2023 22:21 6020E Vanadium 5.85 Ng/L 0.767 03/31/202318:29 6020E Dissolved Vanadium 1.13 pg/L 0.767 03/30/2023 22:21 6020E Zinc 25.7 Ng/L 4.67 03/31/2023 04:55 6020E Dissolved Zinc 37.5 pg/L 4.67 03/30/2023 22:21 8260D Benzene 1.58 Ng/L 0.180 04/05/202319:02 8260D Chlorobenzene 7.57 pg/L 0.190 04/05/202319:02 8260D 1,2-Dichlorobenzene 0.280 Ng/L 0.220 04/05/202319:02 8260D 1,4-Dichlorobenzene 8.57 pg/L 0.210 04/05/202319:02 I I J 0 I I J Page 6 of 84 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica Isom Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters MW-05R-20230323 8260D 8260D 8260D SIM 9056A SM-3500-Fe-B SW-01-20230323 6020E 6020E 6020E 6020E 6020E 8260D EPA-200.7 EPA-200.7 EPA-200.7 SW-02-20230323 6020B 6020E 6020E 6020E 6020E 6020E EPA-200.7 EPA-200.7 EPA-200.7 SW-03-20230323 6020B 6020E 6020B 6020E 6020B 6020E 6020B EPA-200.7 EPA-200.7 V 92265 cis- 1,2-Dichloroethene Vinyl Chloride 1,4-Dioxane Chloride Ferrous Iron V 92266 Barium Chromium Cobalt Copper Zinc Acetone Calcium Hardness as CaCO3 Magnesium V 92267 Barium Chromium Cobalt Copper Nickel Zinc Calcium Hardness as CaCO3 Magnesium V 92268 Barium Chromium Cobalt Copper Lead Nickel Zinc Calcium Hardness as CaCO3 Result Units Report Limit Analyzed Qualifiers 3.94 iag/L 0.200 04/05/202319:02 0.684 lag/L 0.170 04/05/202319:02 6.18 iag/L 0.139 03/28/202312:43 72000 lag/L 370 03/25/202310:39 23500 iag/L 620 03/27/202317:15 H 12.4 lag/L 0.453 03/31/2023 04:59 0.562 iag/L 0.346 03/31/2023 04:59 1 0.133 lag/L 0.060 03/31/2023 04:59 1 0.660 iag/L 0.489 03/31/2023 04:59 1 13.9 lag/L 4.67 03/31/2023 04:59 10.2 iag/L 1.80 04/06/2023 04:55 2.11 mg/L 0.100 03/29/2023 21:01 8320 lag/L 100 03/29/2023 21:01 0.740 mg/L 0.100 03/29/2023 21:01 13.5 lag/L 0.453 03/31/2023 05:02 0.742 lag/L 0.346 03/31/2023 05:02 1 0.217 lag/L 0.060 03/31/2023 05:02 1 0.862 lag/L 0.489 03/31/2023 05:02 1 0.365 lag/L 0.182 03/31/2023 05:02 1 18.5 lag/L 4.67 03/31/2023 05:02 2.30 mg/L 0.100 03/29/2023 21:07 9000 lag/L 100 03/29/2023 21:07 0.792 mg/L 0.100 03/29/2023 21:07 13.5 lag/L 0.453 03/31/2023 05:13 0.840 lag/L 0.346 03/31/2023 05:13 1 0.235 lag/L 0.060 03/31/2023 05:13 1 0.860 lag/L 0.489 03/31/2023 05:13 1 0.285 lag/L 0.264 03/31/2023 05:13 1 0.389 lag/L 0.182 03/31/2023 05:13 1 9.75 lag/L 4.67 03/31/2023 05:13 1 2.06 mg/L 0.100 03/29/2023 21:22 8200 lag/L 100 03/29/2023 21:22 Page 7 of 84 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County Landfill Report Number: 23-084-0001 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers SW-03-20230323 V 92268 EPA-200.7 Magnesium 0.743 mq/L 0.100 03/29/2023 21:22 Page 8 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron 8340 H Ng/L 1250 5000 1 03/27/23 17:15 SLO SM-3500-Fe-B 1,4-Dioxane <0.139 pg/L 0.139 2.00 1 03/28/23 11:53 TBL 8260D SIM Alkalinity (as CaCO3) 77000 Ng/L 800 5000 1 03/30/23 15:20 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 pg/L 2000 2000 1 03/25/23 08:25 SLO 521OB-2015 Chloride 4373 Ng/L 370 1000 1 03/25/23 10:23 CM] 9056A COD (Chemical Oxygen Demand) 90003 pg/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/25/23 10:23 CM] 9056A TOC 9023 pg/L 682 1000 1 04/10/23 16:44 SRJ 531OC-2011 Sulfate <650 Ng/L 650 2000 1 03/25/23 10:23 CM] 9056A Sulfide <830 pg/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:48 CPW 6020B Arsenic <0.297 pg/L 0.297 1.00 1 03/31/23 04:48 CPW 6020B Barium 104 Ng/L 0.453 1.00 1 03/31/23 04:48 CPW 6020B Beryllium <1.00 pg/L 0.102 1.00 1 03/31/23 04:48 CPW 6020B Cadmium 0.8103 Ng/L 0.350 1.00 1 03/31/23 04:48 CPW 6020B Chromium <0.346 pg/L 0.346 1.00 1 03/31/23 04:48 CPW 6020B Cobalt 115 Ng/L 0.060 1.00 1 03/31/23 04:48 CPW 6020B Copper 2.91 pg/L 0.489 1.00 1 03/31/23 04:48 CPW 6020B Lead 0.3073 Ng/L 0.264 1.00 1 03/31/23 04:48 CPW 6020B Mercury (Total) <0.130 pg/L 0.130 0.200 1 03/29/23 11:56 FDS 7470A Nickel 16.4 Ng/L 0.182 1.00 1 03/31/23 04:48 CPW 6020B Selenium <0.703 pg/L 0.703 1.00 1 03/31/23 04:48 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 04:48 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 9 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Sample ID: MW-01-20230323 Matrix: Aqueous Sampled: 3/23/2023 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium 1.55 Ng/L 0.0610 1.00 1 03/31/23 04:48 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 03/31/2318:14 CPW 6020B Zinc 60.5 Ng/L 4.67 10.0 1 03/31/23 04:48 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 10 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <18.0 Ng/L 18.0 50.0 10 04/05/23 22:20 TBL V31670 Acrylonitrile <2.30 ug/L 2.30 50.0 10 04/05/23 22:20 TBL V31670 Benzene <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Bromochloromethane <4.20 ug/L 4.20 10.0 10 04/05/23 22:20 TBL V31670 Bromodichloromethane <1.60 Ng/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 Bromoform <15.0 ug/L 15.0 50.0 10 04/05/23 22:20 TBL V31670 Bromomethane <2.80 Ng/L 2.80 10.0 10 04/05/23 22:20 TBL V31670 Carbon Disulfide <1.50 ug/L 1.50 50.0 10 04/05/23 22:20 TBL V31670 Carbon Tetrachloride <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Chlorobenzene <1.90 ug/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 Chlorodibromomethane <1.90 Ng/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 Chloroethane <4.30 ug/L 4.30 10.0 10 04/05/23 22:20 TBL V31670 Chloroform <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Chloromethane <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Di -Isopropyl Ether (DIPE) <9.60 Ng/L 9.60 50.0 10 04/05/23 22:20 TBL V31670 1,2-Dibromo-3-Chloropropane <11.0 ug/L 11.0 20.0 10 04/05/23 22:20 TBL V31670 1,2-Dibromoethane <2.00 Ng/L 2.00 5.00 10 04/05/23 22:20 TBL V31670 Dibromomethane <2.30 ug/L 2.30 5.00 10 04/05/23 22:20 TBL V31670 trans-1,4-Dichloro-2-butene <13.0 Ng/L 13.0 100 10 04/05/23 22:20 TBL V31670 1,2-Dichlorobenzene <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,4-Dichlorobenzene 5.79 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 Dichlorodifluoromethane <12.0 ug/L 12.0 50.0 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 11 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92263 Matrix: Aqueous Sample ID: MW-01-20230323 Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <2.40 Ng/L 2.40 5.00 10 04/05/23 22:20 TBL V31670 1,2-Dichloroethane <1.50 ug/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 1,1-Dichloroethene <1.50 Ng/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 cis- 1,2-Dich loroethene <2.00 ug/L 2.00 5.00 10 04/05/23 22:20 TBL V31670 trans-1,2-Dichloroethene <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 1,2-Dichloropropane <1.90 ug/L 1.90 5.00 10 04/05/23 22:20 TBL V31670 cis- 1,3-Dich loropropene <2.10 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 trans-1,3-Dichloropropene <1.50 ug/L 1.50 5.00 10 04/05/23 22:20 TBL V31670 Ethylbenzene <1.70 Ng/L 1.70 5.00 10 04/05/23 22:20 TBL V31670 2-Hexanone <3.80 ug/L 3.80 50.0 10 04/05/23 22:20 TBL V31670 Methyl Ethyl Ketone (MEK) <7.10 Ng/L 7.10 50.0 10 04/05/23 22:20 TBL V31670 4-Methyl-2-Pentanone <10.0 ug/L 10.0 50.0 10 04/05/23 22:20 TBL V31670 Methylene Chloride <3.30 Ng/L 3.30 10.0 10 04/05/23 22:20 TBL V31670 Styrene <2.20 ug/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,1,1,2-Tetrachloroethane <1.60 Ng/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 1,1,2,2-Tetrachloroethane <1.60 ug/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 Tetrachloroethene <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 Tetrahydrofuran <15.0 ug/L 15.0 100 10 04/05/23 22:20 TBL V31670 Toluene <2.20 Ng/L 2.20 5.00 10 04/05/23 22:20 TBL V31670 1,1,1-Trichloroethane <1.60 ug/L 1.60 5.00 10 04/05/23 22:20 TBL V31670 1,1,2-Trichloroethane <0.960 Ng/L 0.960 5.00 10 04/05/23 22:20 TBL V31670 Trichloroethene <1.80 ug/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 12 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 Lab No : 92263 Sample ID: MW-01-20230323 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 3/23/2023 10:40 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <1.80 Ng/L 1.80 5.00 10 04/05/23 22:20 TBL V31670 1,2,3-Trichloropropane <2.70 ug/L 2.70 10.0 10 04/05/23 22:20 TBL V31670 Vinyl Acetate <10.0 Ng/L 10.0 20.0 10 04/05/23 22:20 TBL V31670 Vinyl Chloride <1.70 ug/L 1.70 5.00 10 04/05/23 22:20 TBL V31670 o-Xylene <2.10 Ng/L 2.10 5.00 10 04/05/23 22:20 TBL V31670 m,p-Xylene <4.20 ug/L 4.20 10.0 10 04/05/23 22:20 TBL V31670 Xylene (Total) <2.1 Ng/L 2.10 5.00 10 04/05/23 22:20 V31670 Surrogate: 4-Bromofluorobenzene 103 Limits: 80-124% 10 04/05/23 22:20 TBL V31670 Surrogate: Dibromofluoromethane 100 Limits: 75-129% 10 04/05/23 22:20 TBL V31670 Surrogate: 1,2-Dichloroethane - d4 103 Limits: 63-136% 10 04/05/23 22:20 TBL V31670 Surrogate: Toluene-d8 102 Limits: 77-123% 10 04/05/23 22:20 TBL V31670 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 13 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 1.793 Ng/L 0.139 2.00 1 03/28/23 12:18 TBL 8260D SIM COD (Chemical Oxygen Demand) 10000 J ug/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 TOC 1020 Ng/L 682 1000 1 04/10/23 17:22 SRJ 531OC-2011 Sulfide <830 ug/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Antimony <0.618 ug/L 0.618 1.00 1 03/30/23 22:17 CPW 6020B Arsenic 2.53 Ng/L 0.297 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Arsenic 0.906 J ug/L 0.297 1.00 1 03/30/23 22:17 CPW 6020B Barium 188 Ng/L 0.453 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Barium 160 ug/L 0.453 1.00 1 03/30/23 22:17 CPW 6020B Beryllium 0.8873 Ng/L 0.102 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Beryllium 0.3443 ug/L 0.102 1.00 1 03/30/23 22:17 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Cadmium <0.350 ug/L 0.350 1.00 1 03/30/23 22:17 CPW 6020B Chromium 41.7 Ng/L 0.346 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Chromium 22.9 ug/L 0.346 1.00 1 03/30/23 22:17 CPW 6020B Cobalt 59.3 Ng/L 0.060 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Cobalt 51.0 ug/L 0.060 1.00 1 03/30/23 22:17 CPW 6020B Copper 34.9 Ng/L 0.489 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Copper 19.4 ug/L 0.489 1.00 1 03/30/23 22:17 CPW 6020B Lead 9.21 Ng/L 0.264 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Lead 5.57 ug/L 0.264 1.00 1 03/30/23 22:17 CPW 6020B Mercury (Total) <0.130 Ng/L 0.130 0.200 1 03/29/23 11:58 FDS 7470A Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 14 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Sample ID: MW-02-20230323 Matrix: Aqueous Sampled: 3/23/2023 15:12 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Dissolved Mercury <0.130 Ng/L 0.130 0.200 1 03/30/23 11:24 FDS 7470A Dissolved Nickel 19.9 ug/L 0.182 1.00 1 03/30/23 22:17 CPW 6020B Nickel 31.8 Ng/L 0.182 1.00 1 03/31/23 04:51 CPW 6020B Selenium 3.19 ug/L 0.703 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Selenium 2.15 Ng/L 0.703 1.00 1 03/30/23 22:17 CPW 6020B Silver <0.0570 ug/L 0.0570 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Silver <0.0570 Ng/L 0.0570 1.00 1 03/30/23 22:17 CPW 6020B Thallium 0.7713 ug/L 0.0610 1.00 1 03/31/23 04:51 CPW 6020B Dissolved Thallium 0.5733 Ng/L 0.0610 1.00 1 03/30/23 22:17 CPW 6020B Vanadium 52.5 ug/L 0.767 5.00 1 03/31/23 04:51 CPW 6020B Dissolved Vanadium 29.0 Ng/L 0.767 5.00 1 03/30/23 22:17 CPW 6020B Zinc 160 ug/L 4.67 10.0 1 03/31/23 04:51 CPW 6020B Dissolved Zinc 173 Ng/L 4.67 10.0 1 03/30/23 22:17 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 15 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 20:16 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 20:16 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 20:16 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 20:16 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 20:16 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 20:16 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 20:16 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 20:16 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 20:16 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 20:16 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 20:16 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 20:16 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 20:16 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 20:16 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 16 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane 0.2443 Ng/L 0.240 0.500 1 04/05/23 20:16 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 20:16 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 20:16 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 20:16 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 20:16 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 20:16 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 20:16 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 20:16 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 20:16 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 20:16 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 20:16 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 20:16 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 20:16 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 20:16 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 20:16 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 17 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92264 Matrix: Aqueous Sample ID: MW-02-20230323 Sampled: 3/23/2023 15:12 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 105 Limits: 63-136% 103 Limits: 77-123% 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 1 04/05/23 20:16 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 18 of 84 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-084-0001 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County Landfill Information : REPORT OF ANAL YSIS Report Date : 05/04/2023 Received : 03/25/2023 Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron 23500 H Ng/L 620 2500 1 03/27/23 17:15 SLO SM-3500-Fe-B 1,4-Dioxane 6.18 ug/L 0.139 2.00 1 03/28/23 12:43 TBL 8260D SIM Alkalinity (as CaCO3) 217000 Ng/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) 4000 ug/L 2000 2000 1 03/25/23 08:25 SLO 521OB-2015 Chloride 72000 Ng/L 370 1000 1 03/25/2310:39 CM] 9056A COD (Chemical Oxygen Demand) 220003 ug/L 8000 30000 1 03/28/23 10:31 SMW 5220D-2011 Nitrate (NO3-N) <76.0 Ng/L 76.0 200 1 03/25/23 10:39 CM] 9056A TOC 3120 ug/L 682 1000 1 04/10/23 18:00 SRJ 531OC-2011 Sulfate <650 Ng/L 650 2000 1 03/25/2310:39 CM] 9056A Sulfide <830 ug/L 830 2000 1 03/27/2313:00 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Antimony <0.618 ug/L 0.618 1.00 1 03/30/23 22:21 CPW 6020B Arsenic 6.76 Ng/L 0.297 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Arsenic 5.08 ug/L 0.297 1.00 1 03/30/23 22:21 CPW 6020B Barium 234 Ng/L 0.453 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Barium 242 ug/L 0.453 1.00 1 03/30/23 22:21 CPW 6020B Beryllium <0.102 Ng/L 0.102 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Beryllium <0.102 ug/L 0.102 1.00 1 03/30/23 22:21 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Cadmium <0.350 ug/L 0.350 1.00 1 03/30/23 22:21 CPW 6020B Chromium 4.84 Ng/L 0.346 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Chromium 0.7761 ug/L 0.346 1.00 1 03/30/23 22:21 CPW 6020B Cobalt 16.3 Ng/L 0.060 1.00 1 03/31/23 04:55 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 19 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Sample ID: MW-05R-20230323 Matrix: Aqueous Sampled: 3/23/2023 12:52 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Dissolved Cobalt 16.3 Ng/L 0.060 1.00 1 03/30/23 22:21 CPW 6020B Copper 8.39 ug/L 0.489 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Copper 3.20 Ng/L 0.489 1.00 1 03/30/23 22:21 CPW 6020B Lead 1.66 ug/L 0.264 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Lead 1.22 Ng/L 0.264 1.00 1 03/30/23 22:21 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:50 FDS 7470A Dissolved Mercury <0.130 Ng/L 0.130 0.200 1 03/30/23 11:25 FDS 7470A Dissolved Nickel 3.62 ug/L 0.182 1.00 1 03/30/23 22:21 CPW 6020B Nickel 5.96 Ng/L 0.182 1.00 1 03/31/23 04:55 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Selenium <0.703 Ng/L 0.703 1.00 1 03/30/23 22:21 CPW 6020B Silver <0.0570 ug/L 0.0570 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Silver <0.0570 Ng/L 0.0570 1.00 1 03/30/23 22:21 CPW 6020B Thallium 0.147 J ug/L 0.0610 1.00 1 03/31/23 04:55 CPW 6020B Dissolved Thallium 0.0638 J Ng/L 0.0610 1.00 1 03/30/23 22:21 CPW 6020B Vanadium 5.85 ug/L 0.767 5.00 1 03/31/2318:29 CPW 6020B Dissolved Vanadium 1.13 J Ng/L 0.767 5.00 1 03/30/23 22:21 CPW 6020B Zinc 25.7 ug/L 4.67 10.0 1 03/31/23 04:55 CPW 6020B Dissolved Zinc 37.5 Ng/L 4.67 10.0 1 03/30/23 22:21 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 20 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 19:02 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 19:02 TBL V31670 Benzene 1.58 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 19:02 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 19:02 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 19:02 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 19:02 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Chlorobenzene 7.57 ug/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 19:02 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 19:02 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 19:02 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 19:02 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 19:02 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 19:02 TBL V31670 1,2-Dichlorobenzene 0.2801 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,4-Dichlorobenzene 8.57 Ng/L 0.210 0.500 1 04/05/23 19:02 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 19:02 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 21 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 19:02 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 cis- 1,2-Dich loroethene 3.94 ug/L 0.200 0.500 1 04/05/23 19:02 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 19:02 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 19:02 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 19:02 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 19:02 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 19:02 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 19:02 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 19:02 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 19:02 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 19:02 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 19:02 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 19:02 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 19:02 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 19:02 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 22 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92265 Matrix: Aqueous Sample ID: MW-05R-20230323 Sampled: 3/23/2023 12:52 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride 0.684 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 102 Limits: 75-129% 105 Limits: 63-136% 101 Limits: 77-123% 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 1 04/05/23 19:02 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 23 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:08 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 04:59 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 04:59 CPW 6020E Barium 12.4 ug/L 0.453 1.00 1 03/31/23 04:59 CPW 6020B Beryllium <1.00 Ng/L 0.102 1.00 1 03/31/23 04:59 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 04:59 CPW 6020B Calcium 2.11 mg/L 0.100 1 03/29/23 21:01 BKN EPA-200.7 Chromium 0.5623 ug/L 0.346 1.00 1 03/31/23 04:59 CPW 6020B Cobalt 0.1333 Ng/L 0.060 1.00 1 03/31/23 04:59 CPW 6020B Copper 0.6603 ug/L 0.489 1.00 1 03/31/23 04:59 CPW 6020B Hardness as CaCO3 8320 Ng/L 100 1 03/29/23 21:01 EPA-200.7 Lead <0.264 ug/L 0.264 1.00 1 03/31/23 04:59 CPW 6020B Magnesium 0.740 mg/L 0.100 1 03/29/23 21:01 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:51 FDS 7470A Nickel <0.182 Ng/L 0.182 1.00 1 03/31/23 04:59 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 04:59 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 04:59 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 04:59 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:36 CPW 6020B Zinc 13.9 ug/L 4.67 10.0 1 03/31/23 04:59 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 24 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 10.2 Ng/L 1.80 5.00 1 04/06/23 04:55 MSA V31704 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/06/23 04:55 MSA V31704 Benzene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/06/23 04:55 MSA V31704 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 Bromoform <1.50 ug/L 1.50 5.00 1 04/06/23 04:55 MSA V31704 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/06/23 04:55 MSA V31704 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/06/23 04:55 MSA V31704 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 Chloroethane <0.430 ug/L 0.430 1.00 1 04/06/23 04:55 MSA V31704 Chloroform <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Chloromethane <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/06/23 04:55 MSA V31704 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/06/23 04:55 MSA V31704 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/06/23 04:55 MSA V31704 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/06/23 04:55 MSA V31704 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/06/23 04:55 MSA V31704 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:55 MSA V31704 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/06/23 04:55 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 25 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/06/23 04:55 MSA V31704 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/06/23 04:55 MSA V31704 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/06/23 04:55 MSA V31704 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:55 MSA V31704 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/06/23 04:55 MSA V31704 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/06/23 04:55 MSA V31704 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/06/23 04:55 MSA V31704 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/06/23 04:55 MSA V31704 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/06/23 04:55 MSA V31704 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/06/23 04:55 MSA V31704 Styrene <0.220 ug/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/06/23 04:55 MSA V31704 Toluene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:55 MSA V31704 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:55 MSA V31704 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/06/23 04:55 MSA V31704 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/06/23 04:55 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 26 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92266 Matrix: Aqueous Sample ID: SW-01-20230323 Sampled: 3/23/2023 18:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31703 04/05/23 14:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 104 Limits: 63-136% 103 Limits: 77-123% 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 1 04/06/23 04:55 MSA V31704 H Beyond holding time MQL Method Quantitation Limit Page 27 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:33 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 05:02 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 05:02 CPW 6020E Barium 13.5 ug/L 0.453 1.00 1 03/31/23 05:02 CPW 6020B Beryllium <1.00 Ng/L 0.102 1.00 1 03/31/23 05:02 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 05:02 CPW 6020B Calcium 2.30 mg/L 0.100 1 03/29/23 21:07 BKN EPA-200.7 Chromium 0.7423 ug/L 0.346 1.00 1 03/31/23 05:02 CPW 6020B Cobalt 0.2173 Ng/L 0.060 1.00 1 03/31/23 05:02 CPW 6020B Copper 0.8623 ug/L 0.489 1.00 1 03/31/23 05:02 CPW 6020B Hardness as CaCO3 9000 Ng/L 100 1 03/29/23 21:07 EPA-200.7 Lead <0.264 ug/L 0.264 1.00 1 03/31/23 05:02 CPW 6020B Magnesium 0.792 mg/L 0.100 1 03/29/23 21:07 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:55 FDS 7470A Nickel 0.3653 Ng/L 0.182 1.00 1 03/31/23 05:02 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 05:02 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 05:02 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 05:02 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:41 CPW 6020B Zinc 18.5 ug/L 4.67 10.0 1 03/31/23 05:02 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 28 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 21:06 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 21:06 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 21:06 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 21:06 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 21:06 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 21:06 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 21:06 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 21:06 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 21:06 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 21:06 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 21:06 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 21:06 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 21:06 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 21:06 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 29 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 21:06 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 21:06 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 21:06 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 21:06 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 21:06 TBL V31670 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/05/23 21:06 TBL V31670 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/05/23 21:06 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/05/23 21:06 TBL V31670 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/05/23 21:06 TBL V31670 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/05/23 21:06 TBL V31670 Styrene <0.220 ug/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/05/23 21:06 TBL V31670 Toluene <0.220 Ng/L 0.220 0.500 1 04/05/23 21:06 TBL V31670 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 21:06 TBL V31670 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/05/23 21:06 TBL V31670 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/05/23 21:06 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 30 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92267 Matrix: Aqueous Sample ID: SW-02-20230323 Sampled: 3/23/2023 16:08 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31669 04/05/23 08:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 100 Limits: 75-129% 99.0 Limits: 63-136% 104 Limits: 77-123% 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 1 04/05/23 21:06 TBL V31670 H Beyond holding time MQL Method Quantitation Limit Page 31 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 03/28/23 13:58 TBL 8260D SIM Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 05:13 CPW 6020B Arsenic <0.297 Ng/L 0.297 1.00 1 03/31/23 05:13 CPW 6020E Barium 13.5 ug/L 0.453 1.00 1 03/31/23 05:13 CPW 6020B Beryllium <0.102 Ng/L 0.102 1.00 1 03/31/23 05:13 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 05:13 CPW 6020B Calcium 2.06 mg/L 0.100 1 03/29/23 21:22 BKN EPA-200.7 Chromium 0.8403 ug/L 0.346 1.00 1 03/31/23 05:13 CPW 6020B Cobalt 0.2353 Ng/L 0.060 1.00 1 03/31/23 05:13 CPW 6020B Copper 0.8603 ug/L 0.489 1.00 1 03/31/23 05:13 CPW 6020B Hardness as CaCO3 8200 Ng/L 100 1 03/29/23 21:22 EPA-200.7 Lead 0.2853 ug/L 0.264 1.00 1 03/31/23 05:13 CPW 6020B Magnesium 0.743 mg/L 0.100 1 03/29/23 21:22 BKN EPA-200.7 Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/03/23 12:57 FDS 7470A Nickel 0.3893 Ng/L 0.182 1.00 1 03/31/23 05:13 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 05:13 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 05:13 CPW 6020B Thallium <0.0610 ug/L 0.0610 1.00 1 03/31/23 05:13 CPW 6020B Vanadium <0.767 Ng/L 0.767 5.00 1 03/31/2318:46 CPW 6020B Zinc 9.75 J ug/L 4.67 10.0 1 03/31/23 05:13 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 32 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/06/23 04:31 MSA V31704 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/06/23 04:31 MSA V31704 Benzene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/06/23 04:31 MSA V31704 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 Bromoform <1.50 ug/L 1.50 5.00 1 04/06/23 04:31 MSA V31704 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/06/23 04:31 MSA V31704 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/06/23 04:31 MSA V31704 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 Chloroethane <0.430 ug/L 0.430 1.00 1 04/06/23 04:31 MSA V31704 Chloroform <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Chloromethane <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/06/23 04:31 MSA V31704 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/06/23 04:31 MSA V31704 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/06/23 04:31 MSA V31704 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/06/23 04:31 MSA V31704 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/06/23 04:31 MSA V31704 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:31 MSA V31704 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/06/23 04:31 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 33 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Batch(es): V31703 04/05/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/06/23 04:31 MSA V31704 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/06/23 04:31 MSA V31704 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/06/23 04:31 MSA V31704 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/06/23 04:31 MSA V31704 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/06/23 04:31 MSA V31704 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/06/23 04:31 MSA V31704 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/06/23 04:31 MSA V31704 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/06/23 04:31 MSA V31704 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/06/23 04:31 MSA V31704 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/06/23 04:31 MSA V31704 Styrene <0.220 ug/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/06/23 04:31 MSA V31704 Toluene <0.220 Ng/L 0.220 0.500 1 04/06/23 04:31 MSA V31704 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/06/23 04:31 MSA V31704 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/06/23 04:31 MSA V31704 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/06/23 04:31 MSA V31704 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 34 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92268 Matrix: Aqueous Sample ID: SW-03-20230323 Sampled: 3/23/2023 16:47 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31703 04/05/23 14:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 101 Limits: 80-124% 101 Limits: 75-129% 101 Limits: 63-136% 106 Limits: 77-123% 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 1 04/06/23 04:31 MSA V31704 H Beyond holding time MQL Method Quantitation Limit Page 35 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92269 Matrix: Aqueous Sample ID : TB-23240323 Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/05/23 15:44 TBL V31670 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/05/23 15:44 TBL V31670 Benzene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/05/23 15:44 TBL V31670 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 Bromoform <1.50 ug/L 1.50 5.00 1 04/05/23 15:44 TBL V31670 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/05/23 15:44 TBL V31670 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/05/23 15:44 TBL V31670 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 Chloroethane <0.430 ug/L 0.430 1.00 1 04/05/23 15:44 TBL V31670 Chloroform <0.220 Ng/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Chloromethane <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/05/23 15:44 TBL V31670 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/05/23 15:44 TBL V31670 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/05/23 15:44 TBL V31670 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/05/23 15:44 TBL V31670 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/05/23 15:44 TBL V31670 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 36 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 REPOR T OF A NA L YSIS Lab No : 92269 Matrix: Aqueous Sample ID : TB-23240323 Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/05/23 15:44 TBL V31670 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/05/23 15:44 TBL V31670 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/05/23 15:44 TBL V31670 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/05/23 15:44 TBL V31670 1,4-Dioxane <16.0 Ng/L 16.0 150 1 04/05/23 15:44 TBL V31670 Ethylbenzene <0.170 ug/L 0.170 0.500 1 04/05/23 15:44 TBL V31670 2-Hexanone <0.380 Ng/L 0.380 5.00 1 04/05/23 15:44 TBL V31670 Methyl Ethyl Ketone (MEK) <0.710 ug/L 0.710 5.00 1 04/05/23 15:44 TBL V31670 4-Methyl-2-Pentanone <1.00 Ng/L 1.00 5.00 1 04/05/23 15:44 TBL V31670 Methylene Chloride <0.330 ug/L 0.330 1.00 1 04/05/23 15:44 TBL V31670 Styrene <0.220 Ng/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,1,1,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 1,1,2,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 Tetrachloroethene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 Tetrahydrofuran <1.50 Ng/L 1.50 10.0 1 04/05/23 15:44 TBL V31670 Toluene <0.220 ug/L 0.220 0.500 1 04/05/23 15:44 TBL V31670 1,1,1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 04/05/23 15:44 TBL V31670 1,1,2-Trichloroethane <0.096 ug/L 0.096 0.500 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 37 of 84 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County Landfill Jessica Mayers Report Date : 05/04/2023 231 Haywood Street Information : Received : 03/25/2023 Asheville , NC 28801 Report Number : 23-084-0001 Lab No : 92269 Sample ID : TB-23240323 REPOR T OF A NA L YSIS Matrix: Aqueous Sampled: 3/23/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31669 04/05/23 08:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichloroethene <0.180 Ng/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 Trichlorofluoromethane <0.180 ug/L 0.180 0.500 1 04/05/23 15:44 TBL V31670 1,2,3-Trichloropropane <0.270 Ng/L 0.270 1.00 1 04/05/23 15:44 TBL V31670 Vinyl Acetate <1.00 ug/L 1.00 2.00 1 04/05/23 15:44 TBL V31670 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 04/05/23 15:44 TBL V31670 o-Xylene <0.210 ug/L 0.210 0.500 1 04/05/23 15:44 TBL V31670 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 04/05/23 15:44 TBL V31670 Xylene (Total) <0.21 ug/L 0.210 0.500 1 04/05/23 15:44 KCC V31670 Surrogate:4-Bromofluorobenzene 106 Limits:80-124% 1 04/05/23 15:44 TBL V31670 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 04/05/23 15:44 TBL V31670 Surrogate: 1,2-Dichloroethane - d4 107 Limits: 63-136% 1 04/05/23 15:44 TBL V31670 Surrogate: Toluene-d8 103 Limits: 77-123% 1 04/05/23 15:44 TBL V31670 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 38 of 84 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Access Analytical 15 Thames Valley Rd Irmo, SC 29063 ATTENTION Ashley Amick PROJECTID 23-084-0001 LABORATORY REPORT NUMBER 223032905 DATE 05/01 /2023 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979 Innovation Park Dr., Baton Rouge, LA 70820. - Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 223032905 05/01/2023 15:03 Page 1 of 16 Page 39 of 84 LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 Analytical ANALYTICAL RESULTS Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 05/01/2023 Report p 223032905 I1II111111IIII Project 23-084-0001 Samples Collected 3/23/23 Deliver To Additional Recipients Ashley Amick Angela Martin, Access Analytical Access Analytical Lab Reports, Access Analytical 15 Thames Valley Rd Irmo, SC 29063 803-781-4243 ACCREDITED] CERT # 6429.01 Lab Report#: 223032905 05/01/2023 15:03 Page 2 of 16 Page 40 of 84 Report#: 223032905 �,ear�ryrocar' Project ID: 23-084-0001 Laboratory Endorsement Report Date: 05/01/2023 Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223032905 Lab Report#: 223032905 05/01/2023 15:03 Page 3 of 16 Page 41 of 84 !"aceA eVica! Report#: 223032905 Project ID: 23-084-0001 Certifications Report Date: 05/01/2023 Certification Certification Number A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Lab Report#: 223032905 05/01/2023 15:03 Page 4 of 16 Page 42 of 84 !"aceA eVica! Report#: 223032905 Project ID: 23-084-0001 Case Narrative Client: Access Analytical Report: 223032905 Report Date: 05/01/2023 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. This report is being revised and reissued to split samples 22303290501 and 22303290505 onto a separate report This report supersedes and replaces any prior reports issued under this workorder VOLATILES GAS CHROMATOGRAPHY In the AM20GAX analysis for analytical batch 762901, Methane was detected at an estimated concentration in the method blank. This is probable laboratory contamination. Lab Report#: 223032905 05/01/2023 15:03 Page 5 of 16 Page 43 of 84 aceA��alyirca! Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303290502 MW-01-20230323 Water 3/23/23 10:40 3/28/23 09:57 22303290503 MW-02-20230323 Water 3/23/23 15:12 3/28/23 09:57 22303290504 MW-05R-20230323 Water 3/23/23 12:52 3/28/23 09:57 Lab Report#: 223032905 05/01/2023 15:03 Page 6 of 16 Page 44 of 84 ceAnalyfrca! Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Lactic Acid mg/L 0.59 1 NA 22303290502 MW-01-20230323 Acetic Acid mg/L 1.0 1 NA 22303290502 MW-01-20230323 Propionic Acid mg/L 0.18J 1 NA 22303290502 MW-01-20230323 Formic Acid mg/L 7.2 1 NA 22303290502 MW-01-20230323 Hexanoic Acid mg/L 0.059J 1 NA 22303290503 MW-02-20230323 Lactic Acid mg/L 1.2,1 10 NA 22303290503 MW-02-20230323 Acetic Acid mg/L 2.7,1 10 NA 22303290503 MW-02-20230323 Propionic Acid mg/L 1.2J 10 NA 22303290503 MW-02-20230323 Formic Acid mg/L 67 10 NA 22303290504 MW-05R-20230323 Lactic Acid mg/L 3.3J 10 NA 22303290504 MW-05R-20230323 Acetic Acid mg/L 2.1 J 10 NA 22303290504 MW-05R-20230323 Propionic Acid mg/L 1.11 10 NA 22303290504 MW-05R-20230323 Formic Acid mg/L 65 10 NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Methane ug/L 410 1 NA 22303290503 MW-02-20230323 Methane ug/L 2.7J 1 NA 22303290503 MW-02-20230323 Ethane ug/L 0.191 1 NA 22303290503 MW-02-20230323 Ethene ug/L 0.25J 1 NA 22303290504 MW-05R-20230323 Methane ug/L 3600 4 NA 22303290504 MW-05R-20230323 Ethane ug/L 1.3J 4 NA 22303290504 MW-05R-20230323 Ethene ug/L 1.2J 4 NA EPA RSK-175 Lab ID Client ID Parameter Units Result Dil. %Moist 22303290502 MW-01-20230323 Carbon Dioxide ug/L 260000 1 NA 22303290503 MW-02-20230323 Carbon Dioxide ug/L 30100 1 NA 22303290504 MW-05R-20230323 Carbon Dioxide ug/L 99200 1 NA Lab Report#: 223032905 05/01/2023 15:03 Page 7 of 16 Page 45 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-01-20230323 Collect Date 03/23/2023 10:40 Lab ID 22303290502 Receive Date 03/28/2023 09:57 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 22:48 763291 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 260000 585 1200 ug/L AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/01/2315:14 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.59 0.053 0.50 mg/L 64-19-7 Acetic Acid 1.0 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.18J 0.053 0.50 mg/L 64-18-6 Formic Acid 7.2 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 127-17-3 Pyruvic Acid 0.060LI 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.059J 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 07:22 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 410 2.0 5.0 ug/L 74-84-0 Ethane 0.17U 0.17 1.0 ug/L 74-85-1 Ethene 0.24U 0.24 1.0 ug/L MW-02-20230323 Collect Date 03/23/2023 15:12 Lab ID 22303290503 Receive Date 03/28/2023 09:57 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 23:04 763291 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 30100 585 1200 ug/L Lab Report#: 223032905 05/01/2023 15:03 Page 8 of 16 Page 46 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-02-20230323 Collect Date 03/23/2023 15:12 Lab ID 22303290503 Receive Date 03/28/2023 09:57 Matrix Water AM23G *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:20 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 1.2J 0.53 5.0 mg/L 64-19-7 Acetic Acid 2.7J 1.2 5.0 mg/L 79-09-4 Propionic Acid 1.2J 0.53 5.0 mg/L 64-18-6 Formic Acid 67 0.55 5.0 mg/L 107-92-6 Butyric Acid 0.58U 0.58 5.0 mg/L 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.561.1 0.56 5.0 mg/L 142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 07:37 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 2.7J 2.0 5.0 ug/L 74-84-0 Ethane 0.191 0.17 1.0 ug/L 74-85-1 Ethene 0.25J 0.24 1.0 ug/L MW-05R-20230323 Collect Date 03/23/2023 12:52 Lab ID 22303290504 Receive Date 03/28/2023 09:57 Matrix Water RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/05/23 23:20 763291 BDP NA Parameter Result DL LOQ I Carbon Dioxide 99200 585 1200 G *Results and limits are adjusted for dilution. Units ug/L Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:52 762926 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 3.3J 0.53 5.0 mg/L 64-19-7 Acetic Acid 2.1J 1.2 5.0 mg/L 79-09-4 Propionic Acid 1.11 0.53 5.0 mg/L 64-18-6 Formic Acid 65 0.55 5.0 mg/L 107-92-6 Butyric Acid 0.581J 0.58 5.0 mg/L Lab Report#: 223032905 05/01/2023 15:03 Page 9 of 16 Page 47 of 84 Report#: 223032905 Project ID: 23-084-0001 Report Date: 05/01/2023 Sample Results MW-05R-20230323 Collect Date 03/23/2023 12:52 Lab ID 22303290504 Receive Date 03/28/2023 09:57 Matrix Water AM23G (Continued) *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 04/01/2317:52 762926 LHM NA CAS# Parameter Result DL LOQ Units 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 109-52-4 Pentanoic Acid 0.56U 0.56 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L 142-62-1 Hexanoic Acid 0.58U 0.58 5.0 mg/L AM20GAX *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 4 03/31/23 07:54 762901 LMB NA CAS# Parameter 74-82-8 Methane 74-84-0 Ethane 74-85-1 Ethene Result DL LOCI 3600 7.9 20 1.3J 0.69 4.0 1.2J 0.96 4.0 Units ug/L ug/L ug/L Lab Report#: 223032905 05/01/2023 15:03 Page 10 of 16 Page 48 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 GC Volatiles QC Summary Analytical Batch Client ID MB763291 LCS763291 LCSD763291 763291 Lab ID 2469770 2469771 2469772 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/05/23 22:16 04/05/23 21:44 04/05/23 22:00 Matrix Water Water Water EPA RSK-175 Units ug/L Spike Result %R I Control Spike I Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Carbon Dioxide 124-38-9 585UI 5851 338001 38100 11131 38 - 147 1 338001 37900 112 1 40 Lab Report#: 223032905 05/01/2023 15:03 Page 11 of 16 Page 49 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 General Chemistry QC Summary Analytical Batch Client ID MB762926 LCS762926 LCSD762926 762926 Lab ID 2467944 2467945 2467946 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/01/23 03:39 04/01/23 04:11 04/01/23 04:42 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Lactic Acid 50-21-5 0.053U 0.053 2.0 2.3 115 70 - 130 2.0 2.3 116 1 20 Acetic Acid 64-19-7 0.12U 0.12 2.0 1.9 97 70 - 130 2.0 2.0 98 0 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.0 102 70 - 130 2.0 2.1 103 2 20 Formic Acid 64-18-6 0.055U 0.055 2.0 1.9 97 70 - 130 2.0 1.9 96 1 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.0 102 70 - 130 2.0 2.1 103 1 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 1.9 95 70 - 130 2.0 1.9 95 1 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.1 103 70 - 130 2.0 2.1 107 4 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 106 70 - 130 2.0 2.0 99 7 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.0 102 70 - 130 2.0 2.2 109 7 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 101 70 - 130 2.0 2.0 101 1 20 Lab Report#: 223032905 05/01/2023 15:03 Page 12 of 16 Page 50 of 84 Report#: 223032905 aceA��alyirca! Project ID: 23-084-0001 Report Date: 05/01/2023 General Chromatography QC Summary Analytical Batch Client ID MB762901 LCS762901 LCSD762901 762901 Lab ID 2467877 2467878 2467879 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/31/23 05:48 03/31/23 05:16 03/31/23 05:32 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Methane 74-82-8 2.2J 2.0 380 340 90 70-130 380 380 101 11 20 Ethane 74-84-0 0.17U 0.17 97 100 103 70 - 130 97 110 116 12 20 Ethene 74-85-1 0.24U 0.24 120 120 102 70 - 130 120 140 115 12 20 Lab Report#: 223032905 05/01/2023 15:03 Page 13 of 16 Page 51 of 84 rw Ol a2 a.+ � L rl CL M IS CD u u Mti m ru p co m N N Q C C)LLI lid N O N n a x all a x m 'P x G 'y UJ '--N ❑ N N ❑ N y in 7J N FA N W a C G A C �^°� Q o o ua U V -' rp� " U _ 0 v U L7 a n ¢n u C n 'm v w [� u _ 2 � t7 a� ._. 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N N 0 O Q N 4 (0 J Page 52 of 84 G T 0 Q 0< >Q rnr a o a N a) ay V CL cc V V U v Q IL CL x LL! %-t co N M a, p 71 Q. .. s s ~ iVd y M v 3 p 03 LD N � � O r7 74 x Q LU LLI Cn d O U W a c n w rim v� � LN a Ice 'au ��c � r C �1 � o � x CT] � Y .0 N L G E E- c c M 0 LO M N O N O LO O C, O O N CM O M N N 0 Q Q N(D LL Q J Page 53 of 84 O ❑ ❑ ❑ ❑ ❑ 1 J U W 2 U Z W U W W J � Q k \ ❑ ❑ 2 q � ❑ � � � ❑ � � � 2 � / k § Cl. � \ f § 0 w « k ƒ ■ \ k 0 0 & 2 Page 54 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31424 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/30/23 15:20 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 254000 102 90-110 Duplicate V 92048-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 21000 21000 0.0 20 03/30/23 15:20 Date: 05/04/2023 01:09 PM Page 1 of 28 Page 55 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31484 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92265 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/31/23 16:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 251000 100 90-110 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 217000 204000 6.1 20 03/31/23 16:00 Date: 05/04/2023 01:09 PM Page 2 of 28 Page 56 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31283 Analysis Method: 4500S2F-2011 Analysis Description: Sulfide Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result Sulfide pg/L <830 830 2000 03/27/2313:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Sulfide pg/L 10000 9500 95.0 70-122 Date: 05/04/2023 01:09 PM Page 3 of 28 Page 57 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31376 Analysis Method: 5210B-2015 Analysis Description: Biochemical Oxygen Demand (BOD) Glucose-Glutamic Acid GGA Result Range Analyzed Parameter Units Biochemical Oxygen Demand (5-day) Ng/L 206 167.5-228.E 03/25/23 08:25 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Biochemical Oxygen Demand (5-day) Ng/L 4000 3600 10.5 30 03/25/23 08:25 Date: 05/04/2023 01:09 PM Page 4 of 28 Page 58 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31271 Analysis Method: 5220D-2011 Analysis Description: Chemical Oxygen Demand (COD) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result COD (Chemical Oxygen Demand) pg/L <8000 8000 30000 03/28/23 10:31 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits COD (Chemical Oxygen Demand) pg/L 50000 54000 108 90-110 Matrix Spike & Matrix Spike Duplicate V 92332-MS V 92332-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. COD (Chemical Oxygen Demand) pg/L 17000 50000 50000 59000 57000 84.0 80.0 80-120 3.4 20 Date: 05/04/2023 01:09 PM Page 5 of 28 Page 59 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L675526 QC Analytical Batch(es): L675531 QC Prep Batch Method: 531OC-2011 Analysis Method: 531OC-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-675526 Matrix: AQU Associated Lab Samples: 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result TOC pg/L <682 682 1000 04/10/2312:41 Laboratory Control Sample LCS-1-675526 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC pg/L 5000 4810 96.0 85-115 Duplicate L 89981-DUP-L675526 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC pg/L 4730 4600 2.7 15 04/11/23 00:59 Matrix Spike L 89976-MS-1-675526 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC pg/L 3900 5260 9230 101 85-115 Date: 05/04/2023 01:09 PM Page 6 of 28 Page 60 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-L672669 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed Parameter Units Result Antimony pg/L <0.618 0.618 1.00 03/31/23 03:35 Arsenic pg/L <0.297 0.297 1.00 03/31/23 03:35 Barium pg/L <0.453 0.453 1.00 03/31/23 03:35 Beryllium pg/L <0.102 0.102 1.00 03/31/23 03:35 Cadmium pg/L <0.350 0.350 1.00 03/31/23 03:35 Chromium pg/L <0.346 0.346 1.00 03/31/23 03:35 Cobalt pg/L <0.060 0.060 1.00 03/31/23 03:35 Copper pg/L <0.489 0.489 1.00 03/31/23 03:35 Lead pg/L <0.264 0.264 1.00 03/31/23 03:35 Nickel pg/L <0.182 0.182 1.00 03/31/23 03:35 Selenium pg/L <0.703 0.703 1.00 03/31/23 03:35 Silver pg/L <0.0570 0.0570 1.00 03/31/23 03:35 Thallium pg/L <0.0610 0.0610 1.00 03/31/23 03:35 Vanadium pg/L <0.767 0.767 5.00 03/31/23 16:25 Zinc pg/L <4.67 4.67 10.0 03/31/23 03:35 Laboratory Control Sample LCS-L672669 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 98.2 98.0 80-120 Arsenic pg/L 50.0 46.9 94.0 80-120 Barium pg/L 100 95.3 95.0 80-120 Beryllium pg/L 50.0 52.2 104 80-120 Cadmium pg/L 10.0 9.60 96.0 80-120 Chromium pg/L 100 94.8 95.0 80-120 Cobalt pg/L 100 95.4 95.0 80-120 Copper pg/L 50.0 47.6 95.0 80-120 Date: 05/04/2023 01:09 PM Page 7 of 28 Page 61 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-1-672669 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 50.0 48.0 96.0 80-120 Nickel pg/L 50.0 47.4 95.0 80-120 Selenium pg/L 100 96.0 96.0 80-120 Silver pg/L 10.0 9.64 96.0 80-120 Thallium pg/L 10.0 9.57 96.0 80-120 Vanadium pg/L 500 463 93.0 80-120 Zinc pg/L 500 486 97.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92268-MS-L672669 MS Spike Result Conc. V 92268-MSD-L672669 MSD MS Result MSD Spike Result Conc. MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.618 100 100 96.3 94.7 96.0 95.0 75-125 1.6 20.0 Arsenic pg/L < 0.297 50.0 50.0 50.4 50.0 101 100 75-125 0.7 20.0 Barium pg/L 13.5 100 100 109 107 96.0 94.0 75-125 1.8 20.0 Beryllium pg/L < 0.102 50.0 50.0 47.5 47.5 95.0 95.0 75-125 0.0 20.0 Cadmium pg/L < 0.350 10.0 10.0 9.88 10.1 99.0 101 75-125 2.2 20.0 Chromium pg/L 0.840 100 100 98.5 100 98.0 99.0 75-125 1.5 20.0 Cobalt pg/L 0.235 100 100 99.1 101 99.0 101 75-125 1.8 20.0 Copper pg/L 0.860 50.0 50.0 50.5 51.4 99.0 101 75-125 1.7 20.0 Lead pg/L 0.285 50.0 50.0 49.6 49.4 99.0 98.0 75-125 0.4 20.0 Nickel pg/L 0.389 50.0 50.0 49.8 50.9 99.0 101 75-125 2.1 20.0 Selenium pg/L < 0.703 100 100 107 101 107 101 75-125 5.7 20.0 Silver pg/L < 0.0570 10.0 10.0 10.1 9.91 101 99.0 75-125 1.8 20.0 Thallium pg/L < 0.0610 10.0 10.0 9.83 9.84 98.0 98.0 75-125 0.1 20.0 Vanadium pg/L < 0.767 500 500 523 515 105 103 75-125 1.5 20.0 Zinc pg/L 9.75 500 500 509 509 100 100 75-125 0.0 20.0 Date: 05/04/2023 01:09 PM Page 8 of 28 Page 62 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672669 QC Analytical Batch(es): L673325,L673578 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 92268-PDS-L672669 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 45.5 91.0 03/31/23 05:24 Arsenic pg/L 25.2 101 03/31/23 05:24 Barium pg/L 53.9 95.0 03/31/23 05:24 Beryllium pg/L 24.0 96.0 03/31/2319:01 Cadmium pg/L 5.13 103 03/31/23 05:24 Chromium pg/L 49.8 99.0 03/31/23 05:24 Cobalt pg/L 50.2 100 03/31/23 05:24 Copper pg/L 25.7 101 03/31/23 05:24 Lead pg/L 24.3 97.0 03/31/23 05:24 Nickel pg/L 25.6 101 03/31/23 05:24 Selenium Ng/L 50.0 100 03/31/23 05:24 Silver pg/L 4.98 100 03/31/23 05:24 Thallium pg/L 5.10 102 03/31/23 05:24 Vanadium pg/L 259 104 03/31/23 19:01 Zinc pg/L 262 103 03/31/23 05:24 Date: 05/04/2023 01:09 PM Page 9 of 28 Page 63 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672903 QC Analytical Batch(es): L673329 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-1-672903 Matrix: AQU Associated Lab Samples: 92264, 92265 Parameter Units Blank Result MDL MQL Analyzed Dissolved Antimony pg/L <0.618 0.618 1.00 03/30/23 22:06 Dissolved Arsenic pg/L <0.297 0.297 1.00 03/30/23 22:06 Dissolved Barium pg/L <0.453 0.453 1.00 03/30/23 22:06 Dissolved Beryllium pg/L <0.102 0.102 1.00 03/30/23 22:06 Dissolved Cadmium pg/L <0.350 0.350 1.00 03/30/23 22:06 Dissolved Chromium pg/L <0.346 0.346 1.00 03/30/23 22:06 Dissolved Cobalt pg/L <0.060 0.060 1.00 03/30/23 22:06 Dissolved Copper pg/L <0.489 0.489 1.00 03/30/23 22:06 Dissolved Lead pg/L <0.264 0.264 1.00 03/30/23 22:06 Dissolved Nickel pg/L <0.182 0.182 1.00 03/30/23 22:06 Dissolved Selenium pg/L <0.703 0.703 1.00 03/30/23 22:06 Dissolved Silver pg/L <0.0570 0.0570 1.00 03/30/23 22:06 Dissolved Thallium pg/L <0.0610 0.0610 1.00 03/30/23 22:06 Dissolved Vanadium pg/L <0.767 0.767 5.00 03/30/23 22:06 Dissolved Zinc pg/L <4.67 4.67 10.0 03/30/23 22:06 Laboratory Control Sample & LCSD LCS-L672903 LCSD-L672903 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Dissolved Antimony pg/L 100 93.5 90.7 94.0 91.0 80-120 3.0 20.0 Dissolved Arsenic pg/L 50.0 50.4 48.7 101 97.0 80-120 3.4 20.0 Dissolved Barium pg/L 100 92.5 90.0 93.0 90.0 80-120 2.7 20.0 Dissolved Beryllium pg/L 50.0 50.9 49.1 102 98.0 80-120 3.6 20.0 Dissolved Cadmium pg/L 10.0 9.79 9.38 98.0 94.0 80-120 4.2 20.0 Dissolved Chromium pg/L 100 101 97.2 101 97.0 80-120 3.8 20.0 Dissolved Cobalt pg/L 100 103 97.5 103 98.0 80-120 5.4 20.0 Date: 05/04/2023 01:09 PM Page 10 of 28 Page 64 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672903 QC Analytical Batch(es): L673329 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample & LCSD LCS-1-672903 LCSD-L672903 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dissolved Copper pg/L 50.0 49.8 47.7 100 95.0 80-120 4.3 20.0 Dissolved Lead pg/L 50.0 49.3 47.8 99.0 96.0 80-120 3.0 20.0 Dissolved Nickel pg/L 50.0 50.9 49.0 102 98.0 80-120 3.8 20.0 Dissolved Selenium pg/L 100 104 100 104 100 80-120 3.9 20.0 Dissolved Silver pg/L 10.0 10.1 9.81 101 98.0 80-120 2.9 20.0 Dissolved Thallium pg/L 10.0 9.68 9.55 97.0 96.0 80-120 1.3 20.0 Dissolved Vanadium pg/L 500 490 473 98.0 95.0 80-120 3.5 20.0 Dissolved Zinc pg/L 500 509 489 102 98.0 80-120 4.0 20.0 Date: 05/04/2023 01:09 PM Page 11 of 28 Page 65 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672722 QC Analytical Batch(es): L672893 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-672722 Matrix: AQU Associated Lab Samples: 92263, 92264 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 03/29/23 11:22 Laboratory Control Sample LCS-1-672722 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 4.69 94.0 80-120 Matrix Spike & Matrix Spike Duplicate V 92264-MS-L672722 V 92264-MSD-L672722 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 4.28 3.56 86.0 71.0* 80-120 18.3 20 Post Digestion Spike V 92264-PDS-L672722 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.17 83.0* 03/29/23 12:04 * QC Fail Date: 05/04/2023 01:09 PM Page 12 of 28 Page 66 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672943 QC Analytical Batch(es): L673177 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-672943 Matrix: AQU Associated Lab Samples: 92264, 92265 Blank MDL MQL Analyzed Parameter Units Result Dissolved Mercury pg/L <0.130 0.130 0.200 03/30/23 11:18 Laboratory Control Sample & LCSD LCS-1-672943 LCSD-L672943 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Dissolved Mercury pg/L 5.00 5.41 5.27 108 105 80-120 2.6 20 Date: 05/04/2023 01:09 PM Page 13 of 28 Page 67 of 84 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L673565 QC Analytical Batch(es): L673738 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-L673565 Matrix: AQU Associated Lab Samples: 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 04/03/23 12:32 Laboratory Control Sample LCS-1-673565 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 5.22 104 80-120 Matrix Spike & Matrix Spike Duplicate V 92268-MS-L673565 V 92268-MSD-L673565 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 5.08 5.66 102 113 80-120 10.8 20 Post Digestion Spike V 92268-PDS-L673565 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.79 96.0 04/03/23 13:03 Date: 05/04/2023 01:09 PM Page 14 of 28 Page 68 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31322 QC Analytical Batch(es): V31323 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31322 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92266, 92267, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/28/2311:03 4-Bromofluorobenzene (S) 03/28/23 11:03 103 70-130 Laboratory Control Sample LCS-V31322 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 49.2 98.4 70-130 4-Bromofluorobenzene (S) 128 70-130 Matrix Spike & Matrix Spike Duplicate V 92268-MS-V31322 V 92268-MSD-V31322 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. 1,4-Dioxane pg/L < 0.139 50.0 50.0 46.7 48.4 93.4 96.8 70-130 3.5 20.0 4-Bromofluorobenzene (S) 104 111 70-130 Date: 05/04/2023 01:09 PM Page 15 of 28 Page 69 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31669 Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 QC Analytical Batch(es): V31670 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/05/23 14:55 Acrylonitrile pg/L <0.230 0.230 5.00 04/05/23 14:55 Benzene pg/L <0.180 0.180 0.500 04/05/23 14:55 Bromochloromethane pg/L <0.420 0.420 1.00 04/05/23 14:55 Bromodichloromethane pg/L <0.160 0.160 0.500 04/05/23 14:55 Bromoform pg/L <1.50 1.50 5.00 04/05/23 14:55 Bromomethane pg/L <0.280 0.280 1.00 04/05/23 14:55 Carbon Disulfide pg/L <0.150 0.150 5.00 04/05/23 14:55 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/05/23 14:55 Chlorobenzene pg/L <0.190 0.190 0.500 04/05/23 14:55 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/05/23 14:55 Chloroethane pg/L <0.430 0.430 1.00 04/05/23 14:55 Chloroform pg/L <0.220 0.220 0.500 04/05/23 14:55 Chloromethane pg/L <0.220 0.220 0.500 04/05/23 14:55 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/05/23 14:55 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/05/23 14:55 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/05/23 14:55 Dibromomethane pg/L <0.230 0.230 0.500 04/05/23 14:55 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/05/23 14:55 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/05/23 14:55 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/05/23 14:55 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/05/23 14:55 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/05/23 14:55 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/05/23 14:55 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/05/23 14:55 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/05/23 14:55 Date: 05/04/2023 01:09 PM Page 16 of 28 Page 70 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31669 Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 QC Analytical Batch(es): V31670 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/05/23 14:55 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/05/23 14:55 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/05/23 14:55 1,4-Dioxane pg/L <16.0 16.0 150 04/05/23 14:55 Ethylbenzene pg/L <0.170 0.170 0.500 04/05/23 14:55 2-Hexanone pg/L <0.380 0.380 5.00 04/05/23 14:55 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/05/23 14:55 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/05/23 14:55 Methylene Chloride pg/L <0.330 0.330 1.00 04/05/23 14:55 Styrene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 Tetrachloroethene pg/L <0.220 0.220 0.500 04/05/23 14:55 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/05/23 14:55 Toluene pg/L <0.220 0.220 0.500 04/05/23 14:55 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/05/23 14:55 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/05/23 14:55 Trichloroethene pg/L <0.180 0.180 0.500 04/05/23 14:55 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/05/23 14:55 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/05/23 14:55 Vinyl Acetate pg/L <1.00 1.00 2.00 04/05/23 14:55 Vinyl Chloride pg/L <0.170 0.170 0.500 04/05/23 14:55 o-Xylene pg/L <0.210 0.210 0.500 04/05/23 14:55 m,p-Xylene pg/L <0.420 0.420 1.00 04/05/23 14:55 4-Bromofluorobenzene (S) 04/05/23 14:55 105 80-124 Dibromofluoromethane (S) 04/05/23 14:55 98.4 75-129 1,2-Dichloroethane - d4 (S) 04/05/23 14:55 100 63-136 Date: 05/04/2023 01:09 PM Page 17 of 28 Page 71 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31669 Matrix: AQU Associated Lab Samples: 92263, 92264, 92265, 92267, 92269 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/05/23 14:55 104 77-123 Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 35.9 33.5 89.7 83.7 40-166 6.9 20.0 Acrylonitrile pg/L 40.0 44.7 43.0 112 108 81-127 3.8 20.0 Benzene pg/L 20.0 22.5 22.9 113 115 77-128 1.7 20.0 Bromochloromethane pg/L 20.0 22.3 22.4 112 112 78-135 0.4 20.0 Bromodichloromethane pg/L 20.0 23.5 23.4 118 117 76-138 0.4 20.0 Bromoform pg/L 20.0 22.6 23.3 113 117 71-135 3.0 20.0 Bromomethane pg/L 20.0 18.1 20.0 90.5 100 41-168 9.9 20.0 Carbon Disulfide pg/L 20.0 23.3 24.3 117 122 59-135 4.2 20.0 Carbon Tetrachloride pg/L 20.0 23.7 24.7 119 124 72-142 4.1 20.0 Chlorobenzene pg/L 20.0 22.5 22.5 113 113 78-119 0.0 20.0 Chlorodibromomethane pg/L 20.0 23.8 23.7 119 119 75-134 0.4 20.0 Chloroethane pg/L 20.0 20.1 21.0 101 105 57-142 4.3 20.0 Chloroform pg/L 20.0 22.9 23.5 115 118 77-130 2.5 20.0 Chloromethane pg/L 20.0 19.8 19.3 99.0 96.5 47-145 2.5 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 23.6 23.9 118 120 60-154 1.2 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 25.4 24.3 127 122 63-134 4.4 20.0 1,2-Dibromoethane pg/L 20.0 24.5 24.0 123 120 77-135 2.0 20.0 Dibromomethane pg/L 20.0 22.9 23.1 115 116 76-138 0.8 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 17.2 17.1 86.0 85.5 70-130 0.5 20.0 1,2-Dichlorobenzene pg/L 20.0 23.1 23.8 116 119 78-128 2.9 20.0 1,4-Dichlorobenzene pg/L 20.0 22.1 23.3 111 117 75-126 5.2 20.0 Date: 05/04/2023 01:09 PM Page 18 of 28 Page 72 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 22.9 24.0 115 120 28-163 4.6 20.0 1,1-Dichloroethane pg/L 20.0 23.0 23.7 115 119 70-130 2.9 20.0 1,2-Dichloroethane pg/L 20.0 23.7 23.2 119 116 68-131 2.1 20.0 1,1-Dichloroethene pg/L 20.0 24.0 25.8 120 129 70-154 7.2 20.0 cis-1,2-Dichloroethene pg/L 20.0 23.0 23.5 115 118 76-141 2.1 20.0 trans-1,2-Dichloroethene pg/L 20.0 23.0 23.5 115 118 76-135 2.1 20.0 1,2-Dichloropropane pg/L 20.0 23.5 23.8 118 119 77-130 1.2 20.0 cis-1,3-Dichloropropene pg/L 20.0 24.1 23.5 121 118 65-140 2.5 20.0 trans-1,3-Dichloropropene pg/L 20.0 25.6 24.4 128 122 67-140 4.8 20.0 1,4-Dioxane pg/L 200 266 244 133* 122 70-130 8.6 20.0 Ethylbenzene pg/L 20.0 22.4 22.8 112 114 80-127 1.7 20.0 2-Hexanone pg/L 20.0 25.3 23.3 127 117 64-137 8.2 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.9 19.3 99.5 96.5 71-134 3.0 20.0 4-M ethyl-2-Pentanone pg/L 20.0 25.9 24.5 130 123 69-134 5.5 20.0 Methylene Chloride pg/L 20.0 21.7 21.8 109 109 73-131 0.4 20.0 Styrene pg/L 20.0 22.4 24.0 112 120 78-129 6.8 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 23.2 22.7 116 114 79-134 2.1 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 25.2 25.7 126 129* 62-127 1.9 20.0 Tetrachloroethene pg/L 20.0 22.7 22.5 114 113 80-129 0.8 20.0 Tetrahydrofuran pg/L 20.0 24.3 21.7 122 109 70-130 11.3 20.0 Toluene pg/L 20.0 23.5 23.6 118 118 76-131 0.4 20.0 1,1,1-Trichloroethane pg/L 20.0 23.0 23.8 115 119 75-135 3.4 20.0 1,1,2-Trichloroethane pg/L 20.0 24.4 23.8 122 119 70-140 2.4 20.0 Trichloroethene pg/L 20.0 22.3 22.5 112 113 77-133 0.8 20.0 Trichlorofluoromethane pg/L 20.0 22.5 23.5 113 118 62-148 4.3 20.0 1,2,3-Trichloropropane pg/L 20.0 23.5 24.4 118 122 71-127 3.7 20.0 * QC Fail Date: 05/04/2023 01:09 PM Page 19 of 28 Page 73 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31669 QC Analytical Batch(es): V31670 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31669 LCSD-V31669 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Acetate pg/L 20.0 24.7 23.4 124 117 34-167 5.4 20.0 Vinyl Chloride pg/L 20.0 23.1 23.7 116 119 57-141 2.5 20.0 o-Xylene pg/L 20.0 22.5 23.9 113 120 78-128 6.0 20.0 m,p-Xylene pg/L 40.0 45.8 48.6 115 122 77-133 5.9 20.0 4-Bromofluorobenzene (S) 107 107 80-124 Dibromofluoromethane (S) 104 102 75-129 1,2-Dichloroethane - d4 (S) 109 107 63-136 Toluene-d8(S) 103 103 77-123 Date: 05/04/2023 01:09 PM Page 20 of 28 Page 74 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Prep Batch Method: 5030B QC Analytical Batch(es): V31704 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/06/23 03:17 Acrylonitrile pg/L <0.230 0.230 5.00 04/06/23 03:17 Benzene pg/L <0.180 0.180 0.500 04/06/23 03:17 Bromochloromethane pg/L <0.420 0.420 1.00 04/06/23 03:17 Bromodichloromethane pg/L <0.160 0.160 0.500 04/06/23 03:17 Bromoform pg/L <1.50 1.50 5.00 04/06/23 03:17 Bromomethane pg/L <0.280 0.280 1.00 04/06/23 03:17 Carbon Disulfide pg/L <0.150 0.150 5.00 04/06/23 03:17 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/06/23 03:17 Chlorobenzene pg/L <0.190 0.190 0.500 04/06/23 03:17 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/06/23 03:17 Chloroethane pg/L <0.430 0.430 1.00 04/06/23 03:17 Chloroform pg/L <0.220 0.220 0.500 04/06/23 03:17 Chloromethane pg/L <0.220 0.220 0.500 04/06/23 03:17 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/06/23 03:17 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/06/23 03:17 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/06/23 03:17 Dibromomethane pg/L <0.230 0.230 0.500 04/06/23 03:17 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/06/23 03:17 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/06/23 03:17 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/06/23 03:17 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/06/23 03:17 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/06/23 03:17 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/06/23 03:17 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/06/23 03:17 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/06/23 03:17 Date: 05/04/2023 01:09 PM Page 21 of 28 Page 75 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/06/23 03:17 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/06/23 03:17 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/06/23 03:17 Ethylbenzene pg/L <0.170 0.170 0.500 04/06/23 03:17 2-Hexanone pg/L <0.380 0.380 5.00 04/06/23 03:17 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/06/23 03:17 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/06/23 03:17 Methylene Chloride pg/L <0.330 0.330 1.00 04/06/23 03:17 Styrene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 Tetrachloroethene pg/L <0.220 0.220 0.500 04/06/23 03:17 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/06/23 03:17 Toluene pg/L <0.220 0.220 0.500 04/06/23 03:17 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/06/23 03:17 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/06/23 03:17 Trichloroethene pg/L <0.180 0.180 0.500 04/06/23 03:17 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/06/23 03:17 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/06/23 03:17 Vinyl Acetate pg/L <1.00 1.00 2.00 04/06/23 03:17 Vinyl Chloride pg/L <0.170 0.170 0.500 04/06/23 03:17 o-Xylene pg/L <0.210 0.210 0.500 04/06/23 03:17 m,p-Xylene pg/L <0.420 0.420 1.00 04/06/23 03:17 4-Bromofluorobenzene (S) 04/06/23 03:17 104 80-124 Dibromofluoromethane (S) 04/06/23 03:17 99.0 75-129 1,2-Dichloroethane - d4 (S) 04/06/23 03:17 100 63-136 Date: 05/04/2023 01:09 PM Page 22 of 28 Page 76 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31703 Matrix: AQU Associated Lab Samples: 92266, 92268 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8(S) 04/06/23 03:17 103 77-123 Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits Acetone pg/L 40.0 38.6 36.2 96.5 90.5 40-166 Acrylonitrile pg/L 40.0 48.2 46.1 121 115 81-127 Benzene pg/L 20.0 21.6 22.5 108 113 77-128 Bromochloromethane pg/L 20.0 21.7 21.7 109 109 78-135 Bromodichloromethane pg/L 20.0 22.9 22.8 115 114 76-138 Bromoform pg/L 20.0 23.3 22.6 117 113 71-135 Bromomethane pg/L 20.0 18.2 21.1 91.0 106 41-168 Carbon Disulfide pg/L 20.0 21.5 23.0 108 115 59-135 Carbon Tetrachloride pg/L 20.0 21.8 23.4 109 117 72-142 Chlorobenzene pg/L 20.0 21.5 22.5 108 113 78-119 Chlorodibromomethane pg/L 20.0 23.3 23.7 117 119 75-134 Chloroethane pg/L 20.0 19.1 19.8 95.5 99.0 57-142 Chloroform pg/L 20.0 21.9 22.6 110 113 77-130 Chloromethane pg/L 20.0 19.1 20.5 95.5 103 47-145 Di -Isopropyl Ether (DIPE) pg/L 20.0 23.5 23.4 118 117 60-154 1,2-Dibromo-3-Chloropropane pg/L 20.0 25.5 23.7 128 119 63-134 1,2-Dibromoethane pg/L 20.0 24.0 23.3 120 117 77-135 Dibromomethane pg/L 20.0 22.7 21.8 114 109 76-138 trans-1,4-Dichloro-2-butene pg/L 20.0 16.7 15.9 83.5 79.5 70-130 1,2-Dichlorobenzene pg/L 20.0 23.0 22.8 115 114 78-128 1,4-Dichlorobenzene pg/L 20.0 22.5 22.6 113 113 75-126 RPD Max RPD 6.4 20.0 4.4 20.0 4.0 20.0 0.0 20.0 0.4 20.0 3.0 20.0 14.7 20.0 6.7 20.0 7.0 20.0 4.5 20.0 1.7 20.0 3.5 20.0 3.1 20.0 7.0 20.0 0.4 20.0 7.3 20.0 2.9 20.0 4.0 20.0 4.9 20.0 0.8 20.0 0.4 20.0 Date: 05/04/2023 01:09 PM Page 77 of 84 Page 23 of 28 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 21.0 22.1 105 111 28-163 5.1 20.0 1,1-Dichloroethane pg/L 20.0 21.7 22.8 109 114 70-130 4.9 20.0 1,2-Dichloroethane pg/L 20.0 22.6 22.3 113 112 68-131 1.3 20.0 1,1-Dichloroethene pg/L 20.0 22.3 23.8 112 119 70-154 6.5 20.0 cis-1,2-Dichloroethene pg/L 20.0 21.8 22.7 109 114 76-141 4.0 20.0 trans-1,2-Dichloroethene pg/L 20.0 21.2 22.8 106 114 76-135 7.2 20.0 1,2-Dichloropropane pg/L 20.0 22.6 22.9 113 115 77-130 1.3 20.0 cis-1,3-Dichloropropene pg/L 20.0 22.3 22.2 112 111 65-140 0.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 23.8 22.3 119 112 67-140 6.5 20.0 Ethylbenzene pg/L 20.0 20.6 22.2 103 111 80-127 7.4 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 21.2 20.0 106 100 71-134 5.8 20.0 4-Methyl-2-Pentanone pg/L 20.0 28.2 24.2 141* 121 69-134 15.2 20.0 Methylene Chloride pg/L 20.0 20.9 21.4 105 107 73-131 2.3 20.0 Styrene pg/L 20.0 20.9 22.7 105 114 78-129 8.2 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 21.7 23.0 109 115 79-134 5.8 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 24.5 22.4 123 112 62-127 8.9 20.0 Tetrachloroethene pg/L 20.0 21.1 22.9 106 115 80-129 8.1 20.0 Tetrahydrofuran pg/L 20.0 25.6 23.5 128 118 70-130 8.5 20.0 Toluene pg/L 20.0 22.2 22.5 111 113 76-131 1.3 20.0 1,1,1-Trichloroethane pg/L 20.0 21.3 22.8 107 114 75-135 6.8 20.0 1,1,2-Trichloroethane pg/L 20.0 24.9 22.4 125 112 70-140 10.5 20.0 Trichloroethene pg/L 20.0 22.3 23.6 112 118 77-133 5.6 20.0 Trichlorofluoromethane pg/L 20.0 21.2 22.4 106 112 62-148 5.5 20.0 1,2,3-Trichloropropane pg/L 20.0 23.9 21.3 120 107 71-127 11.5 20.0 Vinyl Acetate pg/L 20.0 18.9 15.6 94.5 78.0 34-167 19.1 20.0 Vinyl Chloride pg/L 20.0 21.1 22.3 106 112 57-141 5.5 20.0 * QC Fail Date: 05/04/2023 01:09 PM Page 24 of 28 Page 78 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31703 QC Analytical Batch(es): V31704 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31703 LCSD-V31703 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD o-Xylene pg/L 20.0 21.1 23.2 106 116 78-128 9.4 20.0 m,p-Xylene pg/L 40.0 43.2 46.9 108 117 77-133 8.2 20.0 4-Bromofluorobenzene (S) 105 104 80-124 Dibromofluoromethane (S) 102 101 75-129 1,2-Dichloroethane - d4 (S) 112 107 63-136 Toluene-d8(S) 104 106 77-123 Date: 05/04/2023 01:09 PM Page 25 of 28 Page 79 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: V31254 QC Analytical Batch(es): V31261 QC Prep Batch Method: SW-9056A (PREP) Analysis Method: 9056A Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V31254 Matrix: AQU Associated Lab Samples: 92263, 92265 Blank MDL MQL Analyzed Parameter Units Result Chloride pg/L <370 370 1000 03/25/23 09:23 Nitrate (NO3-N) pg/L <76.0 76.0 200 03/25/23 09:23 Sulfate pg/L <650 650 2000 03/25/23 09:23 Laboratory Control Sample LCS-V31254 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride pg/L 40000 41300 103 80-120 Nitrate (NO3-N) pg/L 4000 4170 104 80-120 Sulfate pg/L 40000 38700 97.0 80-120 Matrix Spike & Matrix Spike Duplicate V 92265-MS-V31254 V 92265-MSD-V31254 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride pg/L 72000 40000 40000 112000 112000 100 100 80-120 0.0 20 Nitrate (NO3-N) pg/L <79.0 4000 4000 4710 4630 118 116 80-120 1.7 20 Sulfate pg/L <676 40000 40000 38900 39700 97.0 99.0 80-120 2.0 20 Date: 05/04/2023 01:09 PM Page 26 of 28 Page 80 of 84 • Charlotte, NC 28217 Waypoint, 449 Springbrook Rd, Ch Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Prep: L672614 QC Analytical Batch(es): L673139 QC Prep Batch Method: EPA-200.7 (PREP) Analysis Method: EPA-200.7 Analysis Description: Total Metals Lab Reagent Blank LRB-1-672614 Matrix: AQU Associated Lab Samples: 92266, 92267, 92268 Blank MQL Analyzed Parameter Units Result Calcium pg/L <100 100 03/29/2319:53 Magnesium pg/L <100 100 03/29/2319:53 Laboratory Control Sample LCS-1-672614 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Calcium pg/L 10000 10800 108 85-115 Magnesium pg/L 10000 10200 102 85-115 Matrix Spike & Matrix Spike Duplicate G 60040-MS-1-672614 G 60040-MSD-L672614 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Calcium pg/L 6470 10000 10000 16600 16500 101 100 70-130 0.6 20 Magnesium pg/L 2180 10000 10000 11800 11700 96.0 95.0 70-130 0.8 20 Post Digestion Spike G 60040-PDS-L672614 PDS % Analyzed Parameter Units Result Recovery Calcium pg/L 28400 101 03/29/23 22:10 Magnesium pg/L 25300 97.0 03/29/23 22:10 Date: 05/04/2023 01:09 PM Page 27 of 28 Page 81 of 84 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County Landfill Report No: 23-084-0001 QC Analytical Batch: V31279 Analysis Method: SM-3500-Fe-13 Analysis Description: Ferrous Iron Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92263, 92265 Blank MDL MQL Analyzed Parameter Units Result Ferrous Iron pg/L <50.0 50.0 200 03/27/23 17:15 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ferrous Iron pg/L 2000 1980 99.0 90-110 Matrix Spike & Matrix Spike Duplicate V 92263-MS V 92263-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ferrous Iron pg/L 8340 50000 50000 49000 48600 81.0 81.0 80-120 0.8 20 Date: 05/04/2023 01:09 PM Page 28 of 28 Page 82 of 84 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 23-084-0001 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT15 II AC Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Angelo Norvell Date & Time: 03/25/2023 10:36:27 Page 83 of 84 r- (n Q� 3 3� ji ro a6 w �a m C a� � c O _? m m � n 'm 0 m-M w z 0 a ,a i 'b 11111110 943, %.. .11 '4010 mills IN 011mmmilm 11111311 NEW C N v x p m 0 a v a o > n 3 rot m Z 2► m Z 4 m Q m ,- 0 .CL ,nn� Ram n N � J 3 o n e a c v o a cai a 0 c °c N e� m m jp m toN H' A M. ap T— -- w p N c C D w s❑ D m lam o> CL m y• i n �m y Tdx xW m � imp q v-°-CvQ S W o C a Y Fr{ x❑ + IL w jp m N x y Mr 7 N n m �m m a L 0 m m a r m n o v ❑ N A rI E H�a�as wa ono r`m m 0 m m vC CD m�0�m �Aw n w m I mm 0 o r m a p A OF ens n o o m ra U) o M C vain'zmn N m r! 3 o z C m � O remit I~ u0 N re2��� m o m m IF 3 x T n` ` I I a �F, n I I r n Page 84 of 84 Waypointo ANALYTICAL 4/28/2023 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville, NC, 28801 Ref: Analytical Testing Lab Report Number: 23-088-0002 Client Project Description: Jackson County LF Site: Jackson Project Number: C21480-01.01 Dear Jessica Mayers: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/29/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 66 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2023 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2023 South Carolina State Program 99012 12/31/2022 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00016/23-088-0002 Page 2 of 66 Waypoint. (2) ANALYTICAL Sample Report Number: 23-088-0002 Client Project Description: Jackson County LF 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca I som Summary Table Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 AM23G Pace -LA 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 RSK-175 Pace -LA 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 AM20GAX Pace -LA 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 6020B WP MTN 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 7470A WP MTN 92439 MW-03-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 531OC-2011 WP MTN 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 RSK-175 Pace -LA 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 AM23G Pace -LA 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 AM20GAX Pace -LA 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 7470A WP MTN 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 6020E WP MTN 92440 MW-07-20230327 Aqueous 03/27/2023 11:38 03/29/2023 10:10 531OC-2011 WP MTN 92441 MW-02-20230327 Aqueous 03/27/2023 15:13 03/29/2023 10:10 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 RSK-175 Pace -LA 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 AM23G Pace -LA 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 AM20GAX Pace -LA 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 7470A WP MTN 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 6020E WP MTN 92442 DUP-20230327 Aqueous 03/27/2023 16:45 03/29/2023 10:10 531OC-2011 WP MTN 92443 TB-20230327 Aqueous 03/27/2023 03/29/2023 10:10 Pace -LA: Pace Analytical Services, Inc. - LA, Baton Rouge, LA WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 66 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County LF Report Number: 23-088-0002 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-03-20230327 V 92439 2320B-2011 Alkalinity (as CaCO3) 166000 pq/L 800 03/31/2023 16:00 5220D-2011 COD (Chemical Oxygen Demand) 16000 Ng/L 8000 04/05/2023 10:40 1 5310C-2011 TOC 3.13 mg/L 0.682 04/11/2023 07:19 6020B Arsenic 0.453 Ng/L 0.297 03/31/202318:57 1 6020B Barium 104 uq/L 0.453 03/31/202318:57 6020B Chromium 0.968 Ng/L 0.346 03/31/202318:57 1 6020B Cobalt 3.97 uq/L 0.060 03/31/202318:57 6020B Copper 3.33 pg/L 0.489 03/31/202318:57 6020B Nickel 1.09 uq/L 0.182 04/04/2023 01:19 6020B Zinc 7.51 pg/L 4.67 04/04/2023 01:19 1 8260D Acetone 2.43 pq/L 1.80 04/07/202317:01 1 8260D cis- 1,2-Dichloroethene 0.380 Ng/L 0.200 04/07/202317:01 1 8260D Trichloroethene 0.288 pq/L 0.180 04/07/202317:01 1 9056A Chloride 15400 pg/L 370 03/29/202311:50 9056A Nitrate (NO3-N) 4930 uq/L 76.0 03/29/2023 11:50 H 9056A Sulfate 2790 Ng/L 650 03/29/202311:50 MW-07-20230327 V 92440 4500S2F-2011 Sulfide 1200 pq/L 830 03/30/202311:50 1 5310C-2011 TOC 3.29 mg/L 0.682 04/11/2023 07:57 6020B Arsenic 3.42 pq/L 0.297 03/31/202319:01 6020B Barium 461 Ng/L 0.453 03/31/202319:01 6020B Cobalt 2.70 uq/L 0.060 03/31/202319:01 6020B Copper 0.759 Ng/L 0.489 03/31/202319:01 1 6020B Nickel 8.69 uq/L 0.182 04/04/2023 01:23 6020B Zinc 103 Ng/L 4.67 04/04/2023 01:23 8260D Acetone 7.71 uq/L 1.80 04/07/202317:26 8260D Benzene 1.59 Ng/L 0.180 04/07/202317:26 8260D Chlorobenzene 4.78 uq/L 0.190 04/07/202317:26 8260D 1,2-Dichlorobenzene 0.346 Ng/L 0.220 04/07/202317:26 1 8260D 1,4-Dichlorobenzene 6.20 uq/L 0.210 04/07/202317:26 8260D cis- 1,2-Dichloroethene 1.75 Ng/L 0.200 04/07/202317:26 8260D Tetrahydrofuran 2.40 uq/L 1.50 04/07/202317:26 1 8260D SIM 1,4-Dioxane 15.8 pg/L 0.139 03/30/2023 10:29 MW-02-20230327 V 92441 2320B-2011 Alkalinity (as CaCO3) 34000 pg/L 800 03/31/2023 16:00 9056A Chloride 25500 Ng/L 370 03/29/202311:34 Page 4 of 66 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Jackson County LF Report Number: 23-088-0002 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-02-20230327 V 92441 9056A Nitrate (NO3-N) 624 pq/L 9056A Sulfate 10800 Ng/L DUP-20230327 V 92442 2320B-2011 Alkalinity (as CaCO3) 164000 pq/L 4500S2F-2011 Sulfide 2800 Ng/L 5220D-2011 COD (Chemical Oxygen Demand) 22000 pq/L 5310C-2011 TOC 3.06 mg/L 6020B Arsenic 0.519 pq/L 6020B Barium 103 Ng/L 6020B Chromium 1.43 uq/L 6020B Cobalt 3.83 Ng/L 6020B Copper 3.42 uq/L 6020B Nickel 1.43 Ng/L 6020B Zinc 16.7 uq/L 8260D Acetone 2.24 Ng/L 8260D 1,4-Dichlorobenzene 0.226 uq/L 9056A Chloride 15000 Ng/L 9056A Nitrate (NO3-N) 4870 uq/L 9056A Sulfate 2700 Ng/L 76.0 03/29/202311:34 H 650 03/29/202311:34 800 03/31/202316:00 830 03/30/202311:50 8000 04/05/202310:40 1 0.682 04/11/2023 08:35 0.297 03/31/202319:04 1 0.453 03/31 /2023 19:04 0.346 03/31/202319:04 0.060 03/31 /2023 19:04 0.489 03/31/202319:04 0.182 04/04/2023 01:27 4.67 04/04/2023 01:27 1.80 04/07/202317:50 1 0.210 04/07/202317:50 1 370 03/29/202312:06 76.0 03/29/202312:06 H 650 03/29/202312:06 Page 5 of 66 Waypointo ANALYTICAL Client: Anchor QEA of North Carolina, PLLC Project: Jackson County LF Lab Report Number: 23-088-0002 Date: 4/28/2023 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com CASE NARRATIVE Volatile Organic Compounds - GUMS Method 8260D Analyte: 1,4-Dioxane QC Batch No: V31828/V31827 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichloropropane QC Batch No: V31828/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2,3-Trichloropropane QC Batch No: V32533/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 2-Hexanone QC Batch No: V31828/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 2-Hexanone QC Batch No: V31828/V32532 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: 2-Hexanone QC Batch No: V32533/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 4-Methyl-2-pentanone QC Batch No: V31828/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 4-Methyl-2-pentanone QC Batch No: V32533/V32532 Page 6 of 66 Waypointo ANALYTICAL 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Acetone QC Batch No: V31828/V32532 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Acetone QC Batch No: V32533/V32532 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Acrylonitrile QC Batch No: V31828/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Acrylonitrile QC Batch No: V32533/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Sample 92439 (MW-03-20230327) Analyte: cis-1,2-Dichloroethene QC Batch No: V32533/V32532 Sample ran after a dirty sample which caused potential carryover. Sample was rerun outside of hold and confirmed carryover for this analyte. Original run reported. Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V31828/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V32533/V32532 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Sample 92439 (MW-03-20230327) Analyte: Trichloroethene QC Batch No: V32533/V32532 Sample ran after a dirty sample which caused potential carryover. Sample was rerun outside of hold and confirmed carryover for this analyte. Original run reported. Page 7 of 66 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-088-0002 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County LF Information : REPORT OF ANAL YSIS Report Date : 04/28/2023 Received : 03/29/2023 Lab No : 92439 Matrix: Aqueous Sample ID: MW-03-20230327 Sampled: 3/27/2023 16:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <0.05 H mg/L 0.05 0.20 1 03/29/23 13:30 SLO SM-3500-Fe-B 1,4-Dioxane <0.139 ug/L 0.139 2.00 1 03/30/23 10:04 TBL 8260D SIM Alkalinity (as CaCO3) 166000 Ng/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 ug/L 2000 2000 1 03/29/23 09:52 SLO 521OB-2015 Chloride 15400 Ng/L 370 1000 1 03/29/2311:50 CM] 9056A COD (Chemical Oxygen Demand) 16000 J ug/L 8000 30000 1 04/05/23 10:40 SMW 5220D-2011 Nitrate (NO3-N) 4930 H Ng/L 76.0 200 1 03/29/23 11:50 CM] 9056A TOC 3.13 mg/L 0.682 1.00 1 04/11/23 07:19 SRJ 531OC-2011 Sulfate 2790 Ng/L 650 2000 1 03/29/2311:50 CM] 9056A Sulfide <830 ug/L 830 2000 1 03/30/2311:50 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 18:57 CPW 6020B Arsenic 0.4533 ug/L 0.297 1.00 1 03/31/23 18:57 CPW 6020B Barium 104 Ng/L 0.453 1.00 1 03/31/23 18:57 CPW 6020B Beryllium <0.102 ug/L 0.102 1.00 1 03/31/23 18:57 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 18:57 CPW 6020B Chromium 0.9683 ug/L 0.346 1.00 1 03/31/23 18:57 CPW 6020B Cobalt 3.97 Ng/L 0.060 1.00 1 03/31/23 18:57 CPW 6020B Copper 3.33 ug/L 0.489 1.00 1 03/31/23 18:57 CPW 6020B Lead <0.264 Ng/L 0.264 1.00 1 03/31/23 18:57 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/04/23 14:03 FDS 7470A Nickel 1.09 Ng/L 0.182 1.00 1 04/04/23 01:19 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 18:57 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 18:57 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 8 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92439 Sample ID: MW-03-20230327 Matrix: Aqueous Sampled: 3/27/2023 16:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium <0.0610 Ng/L 0.0610 1.00 1 03/31/2318:57 CPW 6020B Vanadium <0.767 pg/L 0.767 5.00 1 03/31/2318:57 CPW 6020B Zinc 7.513 Ng/L 4.67 10.0 1 04/04/23 01:19 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 9 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92439 Matrix: Aqueous Sample ID: MW-03-20230327 Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Batch(es): V32532 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.433 Ng/L 1.80 5.00 1 04/07/23 17:01 ANG V32533 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/07/23 17:01 ANG V32533 Benzene <0.180 Ng/L 0.180 0.500 1 04/07/23 17:01 ANG V32533 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/07/23 17:01 ANG V32533 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:01 ANG V32533 Bromoform <1.50 ug/L 1.50 5.00 1 04/07/23 17:01 ANG V32533 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/07/23 17:01 ANG V32533 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/07/23 17:01 ANG V32533 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/07/23 17:01 ANG V32533 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/07/23 17:01 ANG V32533 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/07/23 17:01 ANG V32533 Chloroethane <0.430 ug/L 0.430 1.00 1 04/07/23 17:01 ANG V32533 Chloroform <0.220 Ng/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 Chloromethane <0.220 ug/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/07/23 17:01 ANG V32533 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/07/23 17:01 ANG V32533 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/07/23 17:01 ANG V32533 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/07/23 17:01 ANG V32533 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/07/23 17:01 ANG V32533 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/07/23 17:01 ANG V32533 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/07/23 17:01 ANG V32533 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 10 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92439 Matrix: Aqueous Sample ID: MW-03-20230327 Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Batch(es): V32532 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/07/23 17:01 ANG V32533 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/07/23 17:01 ANG V32533 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/07/23 17:01 ANG V32533 cis- 1,2-Dich loroethene 0.3803 ug/L 0.200 0.500 1 04/07/23 17:01 ANG V32533 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/07/23 17:01 ANG V32533 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/07/23 17:01 ANG V32533 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/07/23 17:01 ANG V32533 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/07/23 17:01 ANG V32533 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/07/23 17:01 ANG V32533 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/07/23 17:01 ANG V32533 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/07/23 17:01 ANG V32533 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/07/23 17:01 ANG V32533 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/07/23 17:01 ANG V32533 Styrene <0.220 ug/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:01 ANG V32533 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:01 ANG V32533 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/07/23 17:01 ANG V32533 Toluene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:01 ANG V32533 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:01 ANG V32533 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/07/23 17:01 ANG V32533 Trichloroethene 0.288 J ug/L 0.180 0.500 1 04/07/23 17:01 ANG V32533 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 11 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92439 Sample ID: MW-03-20230327 Matrix: Aqueous Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Batch(es): V32532 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Trichlorofluoromethane <0.180 Ng/L 0.180 0.500 1 04/07/23 17:01 ANG V32533 1,2,3-Trichloropropane <0.270 ug/L 0.270 1.00 1 04/07/23 17:01 ANG V32533 Vinyl Acetate <1.00 Ng/L 1.00 2.00 1 04/07/23 17:01 ANG V32533 Vinyl Chloride <0.170 ug/L 0.170 0.500 1 04/07/23 17:01 ANG V32533 o-Xylene <0.210 Ng/L 0.210 0.500 1 04/07/23 17:01 ANG V32533 m,p-Xylene <0.420 ug/L 0.420 1.00 1 04/07/23 17:01 ANG V32533 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 04/07/23 17:01 V32533 Surrogate:4-Bromofluorobenzene 103 Limits:80-124% 1 04/07/23 17:01 MSA V31828 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 04/07/23 17:01 MSA V31828 Surrogate: 1,2-Dichloroethane - d4 106 Limits: 63-136% 1 04/07/23 17:01 MSA V31828 Surrogate: Toluene-d8 99.8 Limits: 77-123% 1 04/07/23 17:01 MSA V31828 Surrogate:4-Bromofluorobenzene 103 Limits:80-124% 1 04/07/23 17:01 ANG V32533 Surrogate: Dibromofluoromethane 103 Limits: 75-129% 1 04/07/23 17:01 ANG V32533 Surrogate: 1,2-Dichloroethane - d4 106 Limits: 63-136% 1 04/07/23 17:01 ANG V32533 Surrogate: Toluene-d8 99.8 Limits: 77-123% 1 04/07/23 17:01 ANG V32533 Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 12 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92440 Sample ID: MW-07-20230327 Matrix: Aqueous Sampled: 3/27/2023 11:38 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 15.8 Ng/L 0.139 2.00 1 03/30/23 10:29 TBL 8260D SIM TOC 3.29 mg/L 0.682 1.00 1 04/11/23 07:57 SRJ 531OC-2011 Sulfide 12003 Ng/L 830 2000 1 03/30/23 11:50 SLO 4500S2F-2011 Antimony <0.618 ug/L 0.618 1.00 1 03/31/23 19:01 CPW 6020B Arsenic 3.42 Ng/L 0.297 1.00 1 03/31/23 19:01 CPW 6020B Barium 461 ug/L 0.453 1.00 1 03/31/23 19:01 CPW 6020B Beryllium <0.102 Ng/L 0.102 1.00 1 03/31/23 19:01 CPW 6020B Cadmium <0.350 ug/L 0.350 1.00 1 03/31/23 19:01 CPW 6020B Chromium <0.346 Ng/L 0.346 1.00 1 03/31/23 19:01 CPW 6020B Cobalt 2.70 ug/L 0.060 1.00 1 03/31/23 19:01 CPW 6020B Copper 0.7593 Ng/L 0.489 1.00 1 03/31/23 19:01 CPW 6020B Lead <0.264 ug/L 0.264 1.00 1 03/31/23 19:01 CPW 6020B Mercury (Total) <0.130 Ng/L 0.130 0.200 1 04/04/23 14:07 FDS 7470A Nickel 8.69 ug/L 0.182 1.00 1 04/04/23 01:23 CPW 6020B Selenium <0.703 Ng/L 0.703 1.00 1 03/31/23 19:01 CPW 6020B Silver <0.0570 ug/L 0.0570 1.00 1 03/31/23 19:01 CPW 6020B Thallium <0.0610 Ng/L 0.0610 1.00 1 03/31/23 19:01 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 03/31/23 19:01 CPW 6020B Zinc 103 Ng/L 4.67 10.0 1 04/04/23 01:23 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 13 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92440 Matrix: Aqueous Sample ID: MW-07-20230327 Sampled: 3/27/2023 11:38 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 7.71 Ng/L 1.80 5.00 1 04/07/23 17:26 MSA V31828 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/07/23 17:26 MSA V31828 Benzene 1.59 Ng/L 0.180 0.500 1 04/07/23 17:26 MSA V31828 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/07/23 17:26 MSA V31828 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:26 MSA V31828 Bromoform <1.50 ug/L 1.50 5.00 1 04/07/23 17:26 MSA V31828 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/07/23 17:26 MSA V31828 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/07/23 17:26 MSA V31828 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/07/23 17:26 MSA V31828 Chlorobenzene 4.78 ug/L 0.190 0.500 1 04/07/23 17:26 MSA V31828 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/07/23 17:26 MSA V31828 Chloroethane <0.430 ug/L 0.430 1.00 1 04/07/23 17:26 MSA V31828 Chloroform <0.220 Ng/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 Chloromethane <0.220 ug/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/07/23 17:26 MSA V31828 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/07/23 17:26 MSA V31828 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/07/23 17:26 MSA V31828 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/07/23 17:26 MSA V31828 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/07/23 17:26 MSA V31828 1,2-Dichlorobenzene 0.346 J ug/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 1,4-Dichlorobenzene 6.20 Ng/L 0.210 0.500 1 04/07/23 17:26 MSA V31828 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/07/23 17:26 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 14 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92440 Matrix: Aqueous Sample ID: MW-07-20230327 Sampled: 3/27/2023 11:38 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/07/23 17:26 MSA V31828 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/07/23 17:26 MSA V31828 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/07/23 17:26 MSA V31828 cis- 1,2-Dich loroethene 1.75 ug/L 0.200 0.500 1 04/07/23 17:26 MSA V31828 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/07/23 17:26 MSA V31828 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/07/23 17:26 MSA V31828 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/07/23 17:26 MSA V31828 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/07/23 17:26 MSA V31828 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/07/23 17:26 MSA V31828 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/07/23 17:26 MSA V31828 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/07/23 17:26 MSA V31828 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/07/23 17:26 MSA V31828 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/07/23 17:26 MSA V31828 Styrene <0.220 ug/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:26 MSA V31828 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:26 MSA V31828 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 Tetrahydrofuran 2.403 ug/L 1.50 10.0 1 04/07/23 17:26 MSA V31828 Toluene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:26 MSA V31828 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:26 MSA V31828 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/07/23 17:26 MSA V31828 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/07/23 17:26 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 15 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92440 Matrix: Aqueous Sample ID: MW-07-20230327 Sampled: 3/27/2023 11:38 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31827 04/07/23 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 103 Limits: 80-124% 102 Limits: 75-129% 108 Limits: 63-136% 98.2 Limits: 77-123% 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 1 04/07/23 17:26 MSA V31828 H Beyond holding time MQL Method Quantitation Limit Page 16 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92441 Sample ID: MW-02-20230327 Matrix: Aqueous Sampled: 3/27/2023 15:13 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <0.05 H mg/L 0.05 0.20 1 03/29/23 13:30 SLO SM-3500-Fe-B Alkalinity (as CaCO3) 34000 pg/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 Ng/L 2000 2000 1 03/29/23 09:52 SLO 521OB-2015 Chloride 25500 ug/L 370 1000 1 03/29/2311:34 CMJ 9056A Nitrate (NO3-N) 624 H Ng/L 76.0 200 1 03/29/23 11:34 CMJ 9056A Sulfate 10800 ug/L 650 2000 1 03/29/2311:34 CMJ 9056A Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 17 of 66 WavDdibnto ANALYTICAL 01015 Anchor QEA of North Carolina, PLLC Jessica Mayers 231 Haywood Street Asheville , NC 28801 Report Number : 23-088-0002 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project ID : Project Jackson County LF Information : REPORT OF ANAL YSIS Report Date : 04/28/2023 Received : 03/29/2023 Lab No : 92442 Matrix: Aqueous Sample ID: DUP-20230327 Sampled: 3/27/2023 16:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ferrous Iron <0.05 H mg/L 0.05 0.20 1 03/29/23 13:30 SLO SM-3500-Fe-B 1,4-Dioxane <0.139 ug/L 0.139 2.00 1 03/30/23 10:54 TBL 8260D SIM Alkalinity (as CaCO3) 164000 Ng/L 800 5000 1 03/31/23 16:00 SLO 2320B-2011 Biochemical Oxygen Demand (5-day) <2000 ug/L 2000 2000 1 03/29/23 09:52 SLO 521OB-2015 Chloride 15000 Ng/L 370 1000 1 03/29/2312:06 CM] 9056A COD (Chemical Oxygen Demand) 22000 J ug/L 8000 30000 1 04/05/23 10:40 SMW 5220D-2011 Nitrate (NO3-N) 4870 H Ng/L 76.0 200 1 03/29/23 12:06 CM] 9056A TOC 3.06 mg/L 0.682 1.00 1 04/11/23 08:35 SRJ 531OC-2011 Sulfate 2700 Ng/L 650 2000 1 03/29/2312:06 CM] 9056A Sulfide 2800 ug/L 830 2000 1 03/30/2311:50 SLO 4500S2F-2011 Antimony <0.618 Ng/L 0.618 1.00 1 03/31/23 19:04 CPW 6020B Arsenic 0.519 J ug/L 0.297 1.00 1 03/31/23 19:04 CPW 6020B Barium 103 Ng/L 0.453 1.00 1 03/31/23 19:04 CPW 6020B Beryllium <0.102 ug/L 0.102 1.00 1 03/31/23 19:04 CPW 6020B Cadmium <0.350 Ng/L 0.350 1.00 1 03/31/23 19:04 CPW 6020B Chromium 1.43 ug/L 0.346 1.00 1 03/31/23 19:04 CPW 6020B Cobalt 3.83 Ng/L 0.060 1.00 1 03/31/23 19:04 CPW 6020B Copper 3.42 ug/L 0.489 1.00 1 03/31/23 19:04 CPW 6020B Lead <0.264 Ng/L 0.264 1.00 1 03/31/23 19:04 CPW 6020B Mercury (Total) <0.130 ug/L 0.130 0.200 1 04/04/23 14:08 FDS 7470A Nickel 1.43 Ng/L 0.182 1.00 1 04/04/23 01:27 CPW 6020B Selenium <0.703 ug/L 0.703 1.00 1 03/31/23 19:04 CPW 6020B Silver <0.0570 Ng/L 0.0570 1.00 1 03/31/23 19:04 CPW 6020B Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 18 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92442 Sample ID: DUP-20230327 Matrix: Aqueous Sampled: 3/27/2023 16:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Thallium <0.0610 Ng/L 0.0610 1.00 1 03/31/2319:04 CPW 6020B Vanadium <0.767 ug/L 0.767 5.00 1 03/31/2319:04 CPW 6020B Zinc 16.7 Ng/L 4.67 10.0 1 04/04/23 01:27 CPW 6020B Qualifiers/ DF Dilution Factor Definitions J Estimated value H Beyond holding time MQL Method Quantitation Limit Page 19 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92442 Matrix: Aqueous Sample ID: DUP-20230327 Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.243 Ng/L 1.80 5.00 1 04/07/23 17:50 MSA V31828 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/07/23 17:50 MSA V31828 Benzene <0.180 Ng/L 0.180 0.500 1 04/07/23 17:50 MSA V31828 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/07/23 17:50 MSA V31828 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:50 MSA V31828 Bromoform <1.50 ug/L 1.50 5.00 1 04/07/23 17:50 MSA V31828 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/07/23 17:50 MSA V31828 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/07/23 17:50 MSA V31828 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/07/23 17:50 MSA V31828 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/07/23 17:50 MSA V31828 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/07/23 17:50 MSA V31828 Chloroethane <0.430 ug/L 0.430 1.00 1 04/07/23 17:50 MSA V31828 Chloroform <0.220 Ng/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 Chloromethane <0.220 ug/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/07/23 17:50 MSA V31828 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/07/23 17:50 MSA V31828 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/07/23 17:50 MSA V31828 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/07/23 17:50 MSA V31828 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/07/23 17:50 MSA V31828 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 1,4-Dichlorobenzene 0.2263 Ng/L 0.210 0.500 1 04/07/23 17:50 MSA V31828 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/07/23 17:50 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 20 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92442 Matrix: Aqueous Sample ID: DUP-20230327 Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/07/23 17:50 MSA V31828 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/07/23 17:50 MSA V31828 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/07/23 17:50 MSA V31828 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/07/23 17:50 MSA V31828 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/07/23 17:50 MSA V31828 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/07/23 17:50 MSA V31828 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/07/23 17:50 MSA V31828 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/07/23 17:50 MSA V31828 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 04/07/23 17:50 MSA V31828 2-Hexanone <0.380 ug/L 0.380 5.00 1 04/07/23 17:50 MSA V31828 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 04/07/23 17:50 MSA V31828 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 04/07/23 17:50 MSA V31828 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 04/07/23 17:50 MSA V31828 Styrene <0.220 ug/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 17:50 MSA V31828 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:50 MSA V31828 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 04/07/23 17:50 MSA V31828 Toluene <0.220 Ng/L 0.220 0.500 1 04/07/23 17:50 MSA V31828 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 17:50 MSA V31828 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 04/07/23 17:50 MSA V31828 Trichloroethene <0.180 ug/L 0.180 0.500 1 04/07/23 17:50 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 21 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92442 Matrix: Aqueous Sample ID: DUP-20230327 Sampled: 3/27/2023 16:45 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31827 04/07/23 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 100 Limits: 75-129% 104 Limits: 63-136% 99.4 Limits: 77-123% 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 1 04/07/23 17:50 MSA V31828 H Beyond holding time MQL Method Quantitation Limit Page 22 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92443 Matrix: Aqueous Sample ID : TB-20230327 Sampled: 3/27/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 04/07/23 14:35 MSA V31828 Acrylonitrile <0.230 ug/L 0.230 5.00 1 04/07/23 14:35 MSA V31828 Benzene <0.180 Ng/L 0.180 0.500 1 04/07/23 14:35 MSA V31828 Bromochloromethane <0.420 ug/L 0.420 1.00 1 04/07/23 14:35 MSA V31828 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 04/07/23 14:35 MSA V31828 Bromoform <1.50 ug/L 1.50 5.00 1 04/07/23 14:35 MSA V31828 Bromomethane <0.280 Ng/L 0.280 1.00 1 04/07/23 14:35 MSA V31828 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 04/07/23 14:35 MSA V31828 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 04/07/23 14:35 MSA V31828 Chlorobenzene <0.190 ug/L 0.190 0.500 1 04/07/23 14:35 MSA V31828 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 04/07/23 14:35 MSA V31828 Chloroethane <0.430 ug/L 0.430 1.00 1 04/07/23 14:35 MSA V31828 Chloroform <0.220 Ng/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 Chloromethane <0.220 ug/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 04/07/23 14:35 MSA V31828 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 04/07/23 14:35 MSA V31828 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 04/07/23 14:35 MSA V31828 Dibromomethane <0.230 ug/L 0.230 0.500 1 04/07/23 14:35 MSA V31828 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 04/07/23 14:35 MSA V31828 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 04/07/23 14:35 MSA V31828 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 04/07/23 14:35 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 23 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92443 Matrix: Aqueous Sample ID : TB-20230327 Sampled: 3/27/2023 0:00 Analytical Method: 8260D Prep Batch(es): V31827 04/07/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 04/07/23 14:35 MSA V31828 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 04/07/23 14:35 MSA V31828 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 04/07/23 14:35 MSA V31828 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 04/07/23 14:35 MSA V31828 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 04/07/23 14:35 MSA V31828 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 04/07/23 14:35 MSA V31828 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 04/07/23 14:35 MSA V31828 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 04/07/23 14:35 MSA V31828 1,4-Dioxane <16.0 Ng/L 16.0 150 1 04/07/23 14:35 MSA V31828 Ethylbenzene <0.170 ug/L 0.170 0.500 1 04/07/23 14:35 MSA V31828 2-Hexanone <0.380 Ng/L 0.380 5.00 1 04/07/23 14:35 MSA V31828 Methyl Ethyl Ketone (MEK) <0.710 ug/L 0.710 5.00 1 04/07/23 14:35 MSA V31828 4-Methyl-2-Pentanone <1.00 Ng/L 1.00 5.00 1 04/07/23 14:35 MSA V31828 Methylene Chloride <0.330 ug/L 0.330 1.00 1 04/07/23 14:35 MSA V31828 Styrene <0.220 Ng/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 1,1,1,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 04/07/23 14:35 MSA V31828 1,1,2,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 14:35 MSA V31828 Tetrachloroethene <0.220 ug/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 Tetrahydrofuran <1.50 Ng/L 1.50 10.0 1 04/07/23 14:35 MSA V31828 Toluene <0.220 ug/L 0.220 0.500 1 04/07/23 14:35 MSA V31828 1,1,1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 04/07/23 14:35 MSA V31828 1,1,2-Trichloroethane <0.096 ug/L 0.096 0.500 1 04/07/23 14:35 MSA V31828 Qualifiers/ DF Dilution Factor H Beyond holding time Definitions J Estimated value MQL Method Quantitation Limit Page 24 of 66 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01015 Project ID Anchor QEA of North Carolina, PLLC Project Jackson County LF Jessica Mayers Report Date : 04/28/2023 231 Haywood Street Information : Received : 03/29/2023 Asheville , NC 28801 Report Number : 23-088-0002 REPOR T OF A NA L YSIS Lab No : 92443 Matrix: Aqueous Sample ID : TB-20230327 Sampled: 3/27/2023 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichloroethene <0.180 Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Qualifiers/ DF Dilution Factor Definitions J Estimated value Prep Batch(es): V31827 04/07/23 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.180 0.500 Ng/L 0.270 1.00 Pg/L 1.00 2.00 Ng/L 0.170 0.500 Pg/L 0.210 0.500 Ng/L 0.420 1.00 Pg/L 0.210 0.500 103 Limits: 80-124% 100 Limits: 75-129% 106 Limits: 63-136% 98.4 Limits: 77-123% 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 1 04/07/23 14:35 MSA V31828 H Beyond holding time MQL Method Quantitation Limit Page 25 of 66 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Waypoint Analytical 449 Springbrook Rd Charlotte, NC 28217 ATTENTION Angie Overcash PROJECTID 23-088-0002 LABORATORY REPORT NUMBER 223033013 DATE 04/28/2023 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Pace Analytical Gulf Coast, 7979 Innovation Park Dr., Baton Rouge, LA 70820. - Pace Gulf Coast is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of Pace Guld Coast serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 223033013 04/26/2023 11:56 Page 1 of 16 Page 26 of 66 LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 Analytical ANALYTICAL RESULTS •.,N� J Pace Analytical Gulf Coast 7979 innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 04/26/2023 Report N 223033013 I1II �1I 1 1�i 1 1 I��I �1�I I Project 23-088-0002 Samples Collected 3/27/23 ACCREDITED CERT ? 6429.01 Lab Report#: 223033013 04/26/2023 11:56 Page 2 of 16 Page 27 of 66 Report#: 223033013 arraryiecar' Project ID: 23-088-0002 Report Date: 04/26/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223033013 Lab Report#: 223033013 04/26/2023 11:56 Page 3 of 16 Page 28 of 66 !"aceA eVica! Report#: 223033013 Project ID: 23-088-0002 Certifications Report Date: 04/26/2023 Certification Certification Number A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Lab Report#: 223033013 04/26/2023 11:56 Page 4 of 16 Page 29 of 66 ceAnalyfrca! Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Case Narrative Client: Access Analytical Report: 223033013 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. VOLATILES GAS CHROMATOGRAPHY In the AM20GAX analysis for analytical batch 762901, Methane was detected at an estimated concentration in the method blank. This is probable laboratory contamination. Lab Report#: 223033013 04/26/2023 11:56 Page 5 of 16 Page 30 of 66 aceA��alyirca! Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303301301 MW-03-20230327 Water 3/27/23 16:45 3/30/23 09:32 22303301302 MW-07-20230327 Water 3/27/23 11:38 3/30/23 09:32 22303301303 DUP-20230327 Water 3/27/23 16:45 3/30/23 09:32 22303301304 MW-07-20230327 Bubble Strip 3/27/23 11:38 3/30/23 09:32 Lab Report#: 223033013 04/26/2023 11:56 Page 6 of 16 Page 31 of 66 ceAnalyfrca! Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22303301301 MW-03-20230327 Lactic Acid mg/L 0.39J 1 NA 22303301301 MW-03-20230327 Acetic Acid mg/L 0.78 1 NA 22303301301 MW-03-20230327 Propionic Acid mg/L 0.094J 1 NA 22303301301 MW-03-20230327 Formic Acid mg/L 6.1 1 NA 22303301301 MW-03-20230327 Butyric Acid mg/L 0.061J 1 NA 22303301301 MW-03-20230327 Hexanoic Acid mg/L 0.13J 1 NA 22303301302 MW-07-20230327 Acetic Acid mg/L 0.52 1 NA 22303301302 MW-07-20230327 Propionic Acid mg/L 0.12J 1 NA 22303301302 MW-07-20230327 Formic Acid mg/L 5.3 1 NA 22303301302 MW-07-20230327 Pyruvic Acid mg/L 0.21J 1 NA 22303301303 DUP-20230327 Lactic Acid mg/L 0.55 1 NA 22303301303 DUP-20230327 Acetic Acid mg/L 0.73 1 NA 22303301303 DUP-20230327 Propionic Acid mg/L 0.082J 1 NA 22303301303 DUP-20230327 Formic Acid mg/L 5.7 1 NA 22303301303 DUP-20230327 Hexanoic Acid mg/L 0.111 1 NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303301301 MW-03-20230327 Methane ug/L 2.2J 1 NA 22303301302 MW-07-20230327 Methane ug/L 570 1 NA 22303301302 MW-07-20230327 Ethane ug/L 0.24J 1 NA 22303301302 MW-07-20230327 Ethene ug/L 0.25J 1 NA 22303301303 DUP-20230327 Methane ug/L 2.7J 1 NA 22303301304 MW-07-20230327 Hydrogen nM 2.6 1 NA EPA RSK-175 Lab ID Client ID Parameter Units Result Dil. %Moist 22303301301 MW-03-20230327 Carbon Dioxide ug/L 51400 1 NA 22303301302 MW-07-20230327 Carbon Dioxide ug/L 341000 1 NA 22303301303 DUP-20230327 Carbon Dioxide ug/L 56300 1 NA Lab Report#: 223033013 04/26/2023 11:56 Page 7 of 16 Page 32 of 66 Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Sample Results MW-03-20230327 Collect Date 03/27/2023 16:45 Lab ID 22303301301 Receive Date 03/30/2023 09:32 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/06/23 20:35 763357 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 51400 585 1200 ug/L AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/21/23 21:24 764158 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.39J 0.053 0.50 mg/L 64-19-7 Acetic Acid 0.78 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.094J 0.053 0.50 mg/L 64-18-6 Formic Acid 6.1 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.061J 0.058 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.13J 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 06:18 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 2.2,1 2.0 5.0 ug/L 74-84-0 Ethane 0.17U 0.17 1.0 ug/L 74-85-1 Ethene 0.24U 0.24 1.0 ug/L MW-07-20230327 Collect Date 03/27/2023 11:38 Lab ID 22303301302 Receive Date 03/30/2023 09:32 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/06/23 20:19 763357 BDP NA CAS# Parameter 124-38-9 Carbon Dioxide Result DL LOQ 341000 585 1200 Units ug/L Lab Report#: 223033013 04/26/2023 11:56 Page 8 of 16 Page 33 of 66 Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Sample Results MW-07-20230327 Collect Date 03/27/2023 11:38 Lab ID 22303301302 Receive Date 03/30/2023 09:32 Matrix Water AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/21/23 23:59 764158 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.053U 0.053 0.50 mg/L 64-19-7 Acetic Acid 0.52 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.12J 0.053 0.50 mg/L 64-18-6 Formic Acid 5.3 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 127-17-3 Pyruvic Acid 0.21J 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 06:34 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 570 2.0 5.0 ug/L 74-84-0 Ethane 0.24J 0.17 1.0 ug/L 74-85-1 Ethene 0.25J 0.24 1.0 ug/L DUP-20230327 Collect Date 03/27/2023 16:45 Lab ID 22303301303 Receive Date 03/30/2023 09:32 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/06/23 20:51 763357 BDP NA CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 56300 585 1200 ug/L AM23G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/22/23 00:50 764158 LHM NA CAS# Parameter Result DL LOQ Units 50-21-5 Lactic Acid 0.55 0.053 0.50 mg/L 64-19-7 Acetic Acid 0.73 0.12 0.50 mg/L 79-09-4 Propionic Acid 0.082J 0.053 0.50 mg/L 64-18-6 Formic Acid 5.7 0.055 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L Lab Report#: 223033013 04/26/2023 11:56 Page 9 of 16 Page 34 of 66 Report#: 223033013 Project ID: 23-088-0002 Report Date: 04/26/2023 Sample Results DUP-20230327 Collect Date 03/27/2023 16:45 Lab ID 22303301303 Receive Date 03/30/2023 09:32 Matrix Water AM23G (Continued) Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/22/23 00:50 764158 LHM NA CAS# Parameter Result DL LOQ Units 127-17-3 Pyruvic Acid 0.060LI 0.060 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 142-62-1 Hexanoic Acid 0.111 0.058 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 06:50 762901 LMB NA CAS# Parameter Result DL LOQ Units 74-82-8 Methane 2.7,1 2.0 5.0 ug/L 74-84-0 Ethane 0.17U 0.17 1.0 ug/L 74-85-1 Ethene 0.241J 0.24 1.0 ug/L MW-07-20230327 Collect Date 03/27/2023 11:38 Lab ID 22303301304 Receive Date 03/30/2023 09:32 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/31/23 06:46 762899 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 2.6 0.49 1.9 nM Lab Report#: 223033013 04/26/2023 11:56 Page 10 of 16 Page 35 of 66 2"Arialyirca! Report#: 223033013 Project ID: 23-088-0002 GC Volatiles QC Summary Report Date: 04/26/2023 Analytical Batch Client ID MB763357 LCS763357 LCSD763357 763357 Lab ID 2470106 2470107 2470117 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/06/23 20:03 04/06/23 19:31 04/06/23 19:47 Matrix Water Water Water EPA RSK-175 Units ug/L Spike Result %R I Control Spike I Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Carbon Dioxide 124-38-9 585U 1 5851 338001 37900 112 38 - 147 1 338001 38300 1131 1 40 Lab Report#: 223033013 04/26/2023 11:56 Page 11 of 16 Page 36 of 66 2"Analyirca! Report#: 223033013 Project ID: 23-088-0002 General Chemistry QC Summary Report Date: 04/26/2023 Analytical Batch Client ID MB764158 LCS764158 LCSD764158 764158 Lab ID 2474382 2474383 2474384 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/21/23 17:58 04/21/23 18:50 04/21/23 19:41 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Lactic Acid 50-21-5 0.053U 0.053 2.0 2.2 109 70 - 130 2.0 2.2 110 1 20 Acetic Acid 64-19-7 0.12U 0.12 2.0 2.1 106 70 - 130 2.0 2.1 106 0 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.1 104 70 - 130 2.0 2.1 105 1 20 Formic Acid 64-18-6 0.055U 0.055 2.0 1.9 96 70 - 130 2.0 2.0 98 3 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.0 102 70 - 130 2.0 2.1 105 3 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 2.0 99 70 - 130 2.0 2.0 101 2 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.0 99 70 - 130 2.0 2.1 104 5 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.0 102 70 - 130 2.0 2.1 105 2 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 1.6 80 70 - 130 2.0 1.7 86 7 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 98 70 - 130 2.0 2.0 102 5 20 Lab Report#: 223033013 04/26/2023 11:56 Page 12 of 16 Page 37 of 66 2"Arialyirca! Report#: 223033013 Project ID: 23-088-0002 General Chromatography QC Summary Report Date: 04/26/2023 Analytical Batch Client ID MB762899 LCS762899 LCSD762899 762899 Lab ID 2467874 2467875 2467876 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/31/23 06:34 03/31/23 06:06 03/31/23 06:21 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R I RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 1 0.49 121 12 199 1 70 - 130 121 1311101 10 1 20 Analytical Batch Client ID MB762901 LCS762901 LCSD762901 762901 Lab ID 2467877 2467878 2467879 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/31/23 05:48 03/31/23 05:16 03/31/23 05:32 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Methane 74-82-8 2.2J 2.0 380 340 90 70-130 380 380 101 11 20 Ethane 74-84-0 0.17U 0.17 97 100 103 70 - 130 97 110 116 12 20 Ethene 74-85-1 0.24U 0.24 120 120 102 70-130 120 140 115 12 20 Lab Report#: 223033013 04/26/2023 11:56 Page 13 of 16 Page 38 of 66 N � N U r N cl) n 0 � r 0 " CO o O LA M cN V'l ❑ M O tl] it (N CC N c G Q U 0 CL N w a Q n N � c � 3 � 3 O A CLn 0 Q W 3 0. x W O [+7 Pi Ln p �n 0. •• Q � 1�•I o m m t t N a a n W li i rro C Lu - w o rro ruo E w o O C C C 9 1LOco n ro an co 0 Q M O S m O T u U w a v � G1 fo 0,1 Nfu N 0] i9 N W fv t J -D J [4 o u Y CO o a CD �+'7 � N N N N N N OJ Q tj rT Q Q GI Q Q Q Q D o U) Q. 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N its ref - Cy " ty Q v v � O � Q O � C CO 7 u 7 r6 G] u iV r = N /\�j d V' � O O C a- Paa � C L Ln vm ¢ C v N 6 C v U7 Q' G LO m N O N 04 N 7 O CV) O (M CM O m N N 0 O n Q (0 J Page 39 of 66 CO o waypA 03/29/2023 14:23:35 Export Batch Report Export Batch Id : 3313EXP To: pace Analytical Services, Inc. - LA 7979 Innovation Park Drive Baton Rouge, LA 70820 504-469-0333 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.579.6364 www.wayp o i n to n a lyti ca I. co m Page 1 of 1 Created: 3/29/2023 14:23:04 Computer: WPALMS-015 User: Angela D Overcash Project Manager: Angela D Overcash From: Waypoint Analytical, LLC (Charlotte) 449 5pringbrook Road Charlotte, NC 28217 704-529-6364 Report No Sample bate Rush Matrix Lab No Method No Fee Code Description r 23-088-0007 03/2712023 16:45 AQU 92439 RSK-175 {SUB} RSK-175 (Carbon Dioxide SUB) 23-088-0002 03/27/2023 11:38 AQU 92440 RSK-175 {SUB) RSK-175 (Carbon Dioxide SUB) 23-088-0002 03/27/2023 16:45 AQU 92442 RSK-175 (SUB) RSK-175 (Carbon Dioxide SUB) Client ID: 4565 - Access Analytical SDG: 2230331113 PM: RVIIe Sampled By l Method of Shipme Blank / Cooler Temp. 5 5l=3,5' l Remarks -7711 0101 a 160 Relinquished B (sign) Date J Time � � Received By (sign) Date /Time Relinquished By (sign) FcZx Date / Time ReCelved n} Date / Time 3-3o-a3 3 1 CO 0 (M CO 0 M N N 0 C Q J Page 40 of 66 O ❑ ❑ 1 ❑ ❑ 1 J U W 2 U Z W U W W J � Q .� k \ ❑ ❑ 2 q � ❑ ❑ � � ❑ � � � 2 � / k § Cl. � ( \ f § w 0 « k ƒ ■ b / ± 0 0 & 2 \ j \ J Page 41 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Analytical Batch: V31484 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92439, 92441, 92442 Blank MDL MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L <800 800 5000 03/31/23 16:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) pg/L 250000 251000 100 90-110 Duplicate V 92265-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) pg/L 217000 204000 6.1 20 03/31/23 16:00 Date: 04/28/2023 01:31 PM Page 1 of 22 Page 42 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Analytical Batch: V31425 Analysis Method: 4500S2F-2011 Analysis Description: Sulfide Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92439, 92440, 92442 Blank MDL MQL Analyzed Parameter Units Result Sulfide pg/L <830 830 2000 03/30/2311:50 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Sulfide pg/L 10000 9000 90.0 70-122 Date: 04/28/2023 01:31 PM Page 2 of 22 Page 43 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Analytical Batch: V31527 Analysis Method: 5210B-2015 Analysis Description: Biochemical Oxygen Demand (BOD) Glucose-Glutamic Acid GGA Result Range Analyzed Parameter Units Biochemical Oxygen Demand (5-day) Ng/L 202 167.5-228.E 03/29/23 09:52 Duplicate V 92358-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Biochemical Oxygen Demand (5-day) Ng/L 163000 161000 1.2 30 03/29/23 09:52 Date: 04/28/2023 01:31 PM Page 3 of 22 Page 44 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Analytical Batch: V31605 Analysis Method: 5220D-2011 Analysis Description: Chemical Oxygen Demand (COD) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92439, 92442 Blank MDL MQL Analyzed Parameter Units Result COD (Chemical Oxygen Demand) pg/L <8000 8000 30000 04/05/23 10:40 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits COD (Chemical Oxygen Demand) pg/L 50000 50000 100 90-110 Matrix Spike & Matrix Spike Duplicate V 92587-MS V 92587-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. COD (Chemical Oxygen Demand) pg/L 23000 50000 50000 66000 68000 86.0 90.0 80-120 2.9 20 Date: 04/28/2023 01:31 PM Page 4 of 22 Page 45 of 66 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: L675528 QC Analytical Batch(es): L675531 QC Prep Batch Method: 5310C-2011 Analysis Method: 5310C-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-675528 Matrix: AQU Associated Lab Samples: 92439, 92440, 92442 Blank MDL MQL Analyzed Parameter Units Result TOC mg/L <0.682 0.682 1.00 04/10/23 21:11 Laboratory Control Sample LCS-1-675528 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC mg/L 5.00 4.92 98.0 85-115 Duplicate G 60518-DUP-L675528 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC mg/L < 1.00 <1.00 0.0 15.0 04/11/23 04:09 Matrix Spike G 60517-MS-L675528 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC mg/L 0.975 5.26 5.85 111 85-115 Date: 04/28/2023 01:31 PM Page 5 of 22 Page 46 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: L673196 QC Analytical Batch(es): L673616,L673995 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank LRB-1-673196 Matrix: AQU Associated Lab Samples: 92439, 92440, 92442 Parameter Units Blank Result MDL MQL Analyzed Antimony pg/L <0.618 0.618 1.00 03/31/23 17:52 Arsenic pg/L <0.297 0.297 1.00 03/31/23 17:52 Barium pg/L <0.453 0.453 1.00 03/31/23 17:52 Beryllium pg/L <0.102 0.102 1.00 03/31/23 17:52 Cadmium pg/L <0.350 0.350 1.00 03/31/23 17:52 Chromium pg/L <0.346 0.346 1.00 03/31/23 17:52 Cobalt pg/L <0.060 0.060 1.00 03/31/23 17:52 Copper pg/L <0.489 0.489 1.00 03/31/23 17:52 Lead pg/L <0.264 0.264 1.00 03/31/23 17:52 Nickel pg/L <0.182 0.182 1.00 04/04/23 00:51 Selenium pg/L <0.703 0.703 1.00 03/31/23 17:52 Silver pg/L <0.0570 0.0570 1.00 03/31/23 17:52 Thallium pg/L <0.0610 0.0610 1.00 03/31/23 17:52 Vanadium pg/L <0.767 0.767 5.00 03/31/23 17:52 Zinc pg/L <4.67 4.67 10.0 04/04/23 00:51 Laboratory Control Sample LCS-L673196 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 105 105 80-120 Arsenic pg/L 50.0 49.3 99.0 80-120 Barium pg/L 100 99.1 99.0 80-120 Beryllium pg/L 50.0 49.0 98.0 80-120 Cadmium pg/L 10.0 9.99 100 80-120 Chromium pg/L 100 98.6 99.0 80-120 Cobalt pg/L 100 97.7 98.0 80-120 Copper pg/L 50.0 48.5 97.0 80-120 Date: 04/28/2023 01:31 PM Page 6 of 22 Page 47 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: L673196 QC Analytical Batch(es): L673616,L673995 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Laboratory Control Sample LCS-1-673196 Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 50.0 49.6 99.0 80-120 Nickel pg/L 50.0 47.8 96.0 80-120 Selenium pg/L 100 98.0 98.0 80-120 Silver pg/L 10.0 9.75 98.0 80-120 Thallium pg/L 10.0 9.55 96.0 80-120 Vanadium pg/L 500 490 98.0 80-120 Zinc pg/L 500 467 93.0 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 92442-MS-L673196 MS Spike Result Conc. V 92442-MSD-L673196 MSD MS Result MSD Spike Result Conc. MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.618 100 100 108 106 108 106 75-125 1.8 20.0 Arsenic pg/L 0.519 50.0 50.0 50.3 50.2 100 99.0 75-125 0.1 20.0 Barium pg/L 103 100 100 207 204 104 101 75-125 1.4 20.0 Beryllium pg/L < 0.102 50.0 50.0 48.5 49.2 97.0 98.0 75-125 1.4 20.0 Cadmium pg/L < 0.350 10.0 10.0 10.0 9.88 100 99.0 75-125 1.2 20.0 Chromium pg/L 1.43 100 100 101 102 100 101 75-125 0.9 20.0 Cobalt pg/L 3.83 100 100 103 104 99.0 100 75-125 0.9 20.0 Copper pg/L 3.42 50.0 50.0 50.2 51.6 94.0 96.0 75-125 2.7 20.0 Lead pg/L < 0.264 50.0 50.0 50.8 51.2 102 102 75-125 0.7 20.0 Nickel pg/L 1.43 50.0 50.0 49.1 45.9 95.0 89.0 75-125 6.7 20.0 Selenium pg/L < 0.703 100 100 94.5 92.5 95.0 93.0 75-125 2.1 20.0 Silver pg/L < 0.0570 10.0 10.0 9.60 9.88 96.0 99.0 75-125 2.8 20.0 Thallium pg/L < 0.0610 10.0 10.0 9.97 10.1 100 101 75-125 1.2 20.0 Vanadium pg/L < 0.767 500 500 501 501 100 100 75-125 0.0 20.0 Zinc pg/L 16.7 500 500 486 469 94.0 90.0 75-125 3.5 20.0 Date: 04/28/2023 01:31 PM Page 7 of 22 Page 48 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: L673196 QC Analytical Batch(es): L673616,L673995 QC Prep Batch Method: 3005A Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 92442-PDS-L673196 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 49.7 99.0 03/31/23 19:22 Arsenic pg/L 25.9 103 03/31/23 19:22 Barium pg/L 98.8 97.0 03/31/23 19:22 Beryllium pg/L 23.2 93.0 03/31/23 19:22 Cadmium pg/L 5.02 100 03/31/23 19:22 Chromium pg/L 49.6 98.0 03/31/23 19:22 Cobalt Ng/L 50.3 97.0 03/31/23 19:22 Copper pg/L 26.0 97.0 03/31/23 19:22 Lead pg/L 24.9 99.0 03/31/23 19:22 Nickel pg/L 23.8 93.0 04/04/23 01:50 Selenium Ng/L 50.5 101 03/31/23 19:22 Silver pg/L 4.74 95.0 03/31/23 19:22 Thallium pg/L 5.01 100 03/31/23 19:22 Vanadium pg/L 243 97.0 03/31/23 19:22 Zinc pg/L 239 92.0 04/04/23 01:50 Date: 04/28/2023 01:31 PM Page 8 of 22 Page 49 of 66 • Waypoint, 449 Springbrook Rd, Ch Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: L673784 QC Analytical Batch(es): L674000 QC Prep Batch Method: 7470A Analysis Method: 7470A Analysis Description: Total Aqueous Mercury Analysis - CVAA Lab Reagent Blank LRB-1-673784 Matrix: AQU Associated Lab Samples: 92439, 92440, 92442 Blank MDL MQL Analyzed Parameter Units Result Mercury (Total) pg/L <0.130 0.130 0.200 04/04/23 13:34 Laboratory Control Sample LCS-1-673784 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Mercury (Total) pg/L 5.00 5.04 101 80-120 Matrix Spike & Matrix Spike Duplicate V 92551-MS-L673784 V 92551-MSD-L673784 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Mercury (Total) pg/L <0.260 5.00 5.00 4.00 4.86 80.0 97.0 80-120 19.4 20 Post Digestion Spike V 92551-PDS-L673784 PDS % Analyzed Parameter Units Result Recovery Mercury (Total) pg/L 4.53 91.0 04/04/23 14:16 Date: 04/28/2023 01:31 PM Page 9 of 22 Page 50 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31426 QC Analytical Batch(es): V31427 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31426 Matrix: AQU Associated Lab Samples: 92439, 92440, 92442 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 03/30/23 09:39 4-Bromofluorobenzene (S) 03/30/23 09:39 111 70-130 Laboratory Control Sample LCS-V31426 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 46.8 93.6 70-130 4-Bromofluorobenzene (S) 98.0 70-130 Matrix Spike & Matrix Spike Duplicate V 92499-MS-V31426 V 92499-MSD-V31426 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. 1,4-Dioxane pg/L 13.7 50.0 50.0 58.6 57.5 89.8 87.6 70-130 1.8 20.0 4-Bromofluorobenzene (S) 107 119 70-130 Date: 04/28/2023 01:31 PM Page 10 of 22 Page 51 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31827 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31827 Associated Lab Samples: 92440, 92442, 92443 QC Analytical Batch(es): V31828 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/07/23 14:10 Acrylonitrile pg/L <0.230 0.230 5.00 04/07/23 14:10 Benzene pg/L <0.180 0.180 0.500 04/07/23 14:10 Bromochloromethane pg/L <0.420 0.420 1.00 04/07/23 14:10 Bromodichloromethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Bromoform pg/L <1.50 1.50 5.00 04/07/23 14:10 Bromomethane pg/L <0.280 0.280 1.00 04/07/23 14:10 Carbon Disulfide pg/L <0.150 0.150 5.00 04/07/23 14:10 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/07/23 14:10 Chlorobenzene pg/L <0.190 0.190 0.500 04/07/23 14:10 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/07/23 14:10 Chloroethane pg/L <0.430 0.430 1.00 04/07/23 14:10 Chloroform pg/L <0.220 0.220 0.500 04/07/23 14:10 Chloromethane pg/L <0.220 0.220 0.500 04/07/23 14:10 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/07/23 14:10 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/07/23 14:10 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/07/23 14:10 Dibromomethane pg/L <0.230 0.230 0.500 04/07/23 14:10 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/07/23 14:10 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/07/23 14:10 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/07/23 14:10 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/07/23 14:10 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/07/23 14:10 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/07/23 14:10 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/07/23 14:10 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Date: 04/28/2023 01:31 PM Page 11 of 22 Page 52 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31827 QC Prep Batch Method: 5030B Lab Reagent Blank LRB-V31827 Associated Lab Samples: 92440, 92442, 92443 QC Analytical Batch(es): V31828 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Matrix: AQU Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/07/23 14:10 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/07/23 14:10 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/07/23 14:10 1,4-Dioxane pg/L <16.0 16.0 150 04/07/23 14:10 Ethylbenzene pg/L <0.170 0.170 0.500 04/07/23 14:10 2-Hexanone pg/L <0.380 0.380 5.00 04/07/23 14:10 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/07/23 14:10 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/07/23 14:10 Methylene Chloride pg/L <0.330 0.330 1.00 04/07/23 14:10 Styrene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Tetrachloroethene pg/L <0.220 0.220 0.500 04/07/23 14:10 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/07/23 14:10 Toluene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/07/23 14:10 Trichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/07/23 14:10 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/07/23 14:10 Vinyl Acetate pg/L <1.00 1.00 2.00 04/07/23 14:10 Vinyl Chloride pg/L <0.170 0.170 0.500 04/07/23 14:10 o-Xylene pg/L <0.210 0.210 0.500 04/07/23 14:10 m,p-Xylene pg/L <0.420 0.420 1.00 04/07/23 14:10 4-Bromofluorobenzene (S) 04/07/23 14:10 102 80-124 Dibromofluoromethane (S) 04/07/23 14:10 101 75-129 1,2-Dichloroethane - d4 (S) 04/07/23 14:10 106 63-136 Date: 04/28/2023 01:31 PM Page 12 of 22 Page 53 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V31827 Matrix: AQU Associated Lab Samples: 92440, 92442, 92443 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/07/23 14:10 97.2 77-123 Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 62.5 46.6 156 117 40-166 29.1* 20.0 Benzene pg/L 20.0 19.8 19.9 99.0 99.5 77-128 0.5 20.0 Bromochloromethane pg/L 20.0 21.1 21.2 106 106 78-135 0.4 20.0 Bromodichloromethane pg/L 20.0 20.3 20.1 102 101 76-138 0.9 20.0 Bromoform pg/L 20.0 24.8 21.8 124 109 71-135 12.8 20.0 Bromomethane pg/L 20.0 15.9 18.6 79.5 93.0 41-168 15.6 20.0 Carbon Disulfide pg/L 20.0 20.0 20.4 100 102 59-135 1.9 20.0 Carbon Tetrachloride pg/L 20.0 20.1 20.3 101 102 72-142 0.9 20.0 Chlorobenzene pg/L 20.0 19.3 19.1 96.5 95.5 78-119 1.0 20.0 Chlorodibromomethane pg/L 20.0 23.1 22.0 116 110 75-134 4.8 20.0 Chloroethane pg/L 20.0 20.5 21.1 103 106 57-142 2.8 20.0 Chloroform pg/L 20.0 20.4 20.2 102 101 77-130 0.9 20.0 Chloromethane pg/L 20.0 19.5 20.7 97.5 104 47-145 5.9 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 19.7 19.4 98.5 97.0 60-154 1.5 20.0 1,2-Dibromoethane pg/L 20.0 22.4 21.7 112 109 77-135 3.1 20.0 Dibromomethane pg/L 20.0 21.9 22.4 110 112 76-138 2.2 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 21.8 22.0 109 110 70-130 0.9 20.0 1,2-Dichlorobenzene pg/L 20.0 20.7 20.4 104 102 78-128 1.4 20.0 1,4-Dichlorobenzene pg/L 20.0 20.0 19.9 100 99.5 75-126 0.5 20.0 Dichlorodifluoromethane pg/L 20.0 23.2 20.8 116 104 28-163 10.9 20.0 1,1-Dichloroethane pg/L 20.0 19.8 20.0 99.0 100 70-130 1.0 20.0 * QC Fail Date: 04/28/2023 01:31 PM Page 13 of 22 Page 54 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD 1,2-Dichloroethane pg/L 20.0 21.4 21.3 107 107 68-131 0.4 20.0 1,1-Dichloroethene pg/L 20.0 19.6 20.9 98.0 105 70-154 6.4 20.0 cis-1,2-Dichloroethene pg/L 20.0 19.4 19.5 97.0 97.5 76-141 0.5 20.0 trans-1,2-Dichloroethene pg/L 20.0 19.2 19.2 96.0 96.0 76-135 0.0 20.0 1,2-Dichloropropane pg/L 20.0 18.7 18.9 93.5 94.5 77-130 1.0 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.5 20.8 103 104 65-140 1.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 21.6 21.3 108 107 67-140 1.3 20.0 Ethylbenzene pg/L 20.0 20.0 19.5 100 97.5 80-127 2.5 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 25.8 25.8 129 129 71-134 0.0 20.0 Methylene Chloride pg/L 20.0 18.7 18.7 93.5 93.5 73-131 0.0 20.0 Styrene pg/L 20.0 20.6 19.8 103 99.0 78-129 3.9 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.8 20.8 104 104 79-134 0.0 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 25.2 23.5 126 118 62-127 6.9 20.0 Tetrachloroethene pg/L 20.0 20.6 20.1 103 101 80-129 2.4 20.0 Tetrahydrofuran pg/L 20.0 24.4 23.6 122 118 70-130 3.3 20.0 Toluene pg/L 20.0 20.2 20.1 101 101 76-131 0.4 20.0 1,1,1-Trichloroethane pg/L 20.0 19.7 20.3 98.5 102 75-135 3.0 20.0 1,1,2-Trichloroethane pg/L 20.0 22.5 22.1 113 111 70-140 1.7 20.0 Trichloroethene pg/L 20.0 19.7 19.6 98.5 98.0 77-133 0.5 20.0 Trichlorofluoromethane pg/L 20.0 23.4 22.2 117 111 62-148 5.2 20.0 Vinyl Acetate pg/L 20.0 24.1 21.9 121 110 34-167 9.5 20.0 Vinyl Chloride pg/L 20.0 20.7 21.4 104 107 57-141 3.3 20.0 o-Xylene pg/L 20.0 20.5 19.8 103 99.0 78-128 3.4 20.0 m,p-Xylene pg/L 40.0 41.5 40.9 104 102 77-133 1.4 20.0 4-Bromofluorobenzene (S) 102 101 80-124 Dibromofluoromethane (S) 101 102 75-129 Date: 04/28/2023 01:31 PM Page 14 of 22 Page 55 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31827 QC Analytical Batch(es): V31828 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V31827 LCSD-V31827 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD 1,2-Dichloroethane - d4 (S) 109 111 63-136 Toluene-d8 (S) 99.8 99.2 77-123 Date: 04/28/2023 01:31 PM Page 15 of 22 Page 56 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V32532 QC Prep Batch Method: 5030B QC Analytical Batch(es): V32533 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V32532 Matrix: AQU Associated Lab Samples: 92439 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 04/07/23 14:10 Acrylonitrile pg/L <0.230 0.230 5.00 04/07/23 14:10 Benzene pg/L <0.180 0.180 0.500 04/07/23 14:10 Bromochloromethane pg/L <0.420 0.420 1.00 04/07/23 14:10 Bromodichloromethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Bromoform pg/L <1.50 1.50 5.00 04/07/23 14:10 Bromomethane pg/L <0.280 0.280 1.00 04/07/23 14:10 Carbon Disulfide pg/L <0.150 0.150 5.00 04/07/23 14:10 Carbon Tetrachloride pg/L <0.180 0.180 0.500 04/07/23 14:10 Chlorobenzene pg/L <0.190 0.190 0.500 04/07/23 14:10 Chlorodibromomethane pg/L <0.190 0.190 0.500 04/07/23 14:10 Chloroethane pg/L <0.430 0.430 1.00 04/07/23 14:10 Chloroform pg/L <0.220 0.220 0.500 04/07/23 14:10 Chloromethane pg/L <0.220 0.220 0.500 04/07/23 14:10 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 04/07/23 14:10 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 04/07/23 14:10 1,2-Dibromoethane pg/L <0.200 0.200 0.500 04/07/23 14:10 Dibromomethane pg/L <0.230 0.230 0.500 04/07/23 14:10 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 04/07/23 14:10 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 04/07/23 14:10 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 04/07/23 14:10 1,1-Dichloroethane pg/L <0.240 0.240 0.500 04/07/23 14:10 1,2-Dichloroethane pg/L <0.150 0.150 0.500 04/07/23 14:10 1,1-Dichloroethene pg/L <0.150 0.150 0.500 04/07/23 14:10 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 04/07/23 14:10 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Date: 04/28/2023 01:31 PM Page 16 of 22 Page 57 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V32532 QC Analytical Batch(es): V32533 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V32532 Matrix: AQU Associated Lab Samples: 92439 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 04/07/23 14:10 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 04/07/23 14:10 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 04/07/23 14:10 Ethylbenzene pg/L <0.170 0.170 0.500 04/07/23 14:10 2-Hexanone pg/L <0.380 0.380 5.00 04/07/23 14:10 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 04/07/23 14:10 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 04/07/23 14:10 Methylene Chloride pg/L <0.330 0.330 1.00 04/07/23 14:10 Styrene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 Tetrachloroethene pg/L <0.220 0.220 0.500 04/07/23 14:10 Tetrahydrofuran pg/L <1.50 1.50 10.0 04/07/23 14:10 Toluene pg/L <0.220 0.220 0.500 04/07/23 14:10 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 04/07/23 14:10 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 04/07/23 14:10 Trichloroethene pg/L <0.180 0.180 0.500 04/07/23 14:10 Trichlorofluoromethane pg/L <0.180 0.180 0.500 04/07/23 14:10 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 04/07/23 14:10 Vinyl Acetate pg/L <1.00 1.00 2.00 04/07/23 14:10 Vinyl Chloride pg/L <0.170 0.170 0.500 04/07/23 14:10 o-Xylene pg/L <0.210 0.210 0.500 04/07/23 14:10 m,p-Xylene pg/L <0.420 0.420 1.00 04/07/23 14:10 4-Bromofluorobenzene (S) 04/07/23 14:10 102 80-124 Dibromofluoromethane (S) 04/07/23 14:10 101 75-129 1,2-Dichloroethane - d4 (S) 04/07/23 14:10 106 63-136 Date: 04/28/2023 01:31 PM Page 17 of 22 Page 58 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V32532 QC Analytical Batch(es): V32533 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V32532 Matrix: AQU Associated Lab Samples: 92439 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 04/07/23 14:10 97.2 77-123 Laboratory Control Sample & LCSD LCS-V32532 LCSD-V32532 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits Acetone pg/L 40.0 62.5 46.6 156 117 40-166 Acrylonitrile pg/L 40.0 53.8 46.0 135* 115 81-127 Benzene pg/L 20.0 19.8 19.9 99.0 99.5 77-128 Bromochloromethane pg/L 20.0 21.1 21.2 106 106 78-135 Bromodichloromethane pg/L 20.0 20.3 20.1 102 101 76-138 Bromoform pg/L 20.0 24.8 21.8 124 109 71-135 Bromomethane pg/L 20.0 15.9 18.6 79.5 93.0 41-168 Carbon Disulfide pg/L 20.0 20.0 20.4 100 102 59-135 Carbon Tetrachloride pg/L 20.0 20.1 20.3 101 102 72-142 Chlorobenzene pg/L 20.0 19.3 19.1 96.5 95.5 78-119 Chlorodibromomethane pg/L 20.0 23.1 22.0 116 110 75-134 Chloroethane pg/L 20.0 20.5 21.1 103 106 57-142 Chloroform pg/L 20.0 20.4 20.2 102 101 77-130 Chloromethane pg/L 20.0 19.5 20.7 97.5 104 47-145 Di -Isopropyl Ether (DIPE) pg/L 20.0 19.7 19.4 98.5 97.0 60-154 1,2-Dibromo-3-Chloropropane pg/L 20.0 30.1 25.2 151* 126 63-134 1,2-Dibromoethane pg/L 20.0 22.4 21.7 112 109 77-135 Dibromomethane pg/L 20.0 21.9 22.4 110 112 76-138 trans-1,4-Dichloro-2-butene pg/L 20.0 21.8 22.0 109 110 70-130 1,2-Dichlorobenzene pg/L 20.0 20.7 20.4 104 102 78-128 1,4-Dichlorobenzene pg/L 20.0 20.0 19.9 100 99.5 75-126 RPD Max RPD 29.1* 20.0 15.6 20.0 0.5 20.0 0.4 20.0 0.9 20.0 12.8 20.0 15.6 20.0 1.9 20.0 0.9 20.0 1.0 20.0 4.8 20.0 2.8 20.0 0.9 20.0 5.9 20.0 1.5 20.0 17.7 20.0 3.1 20.0 2.2 20.0 0.9 20.0 1.4 20.0 0.5 20.0 * QC Fail Date: 04/28/2023 01:31 PM Page 59 of 66 Page 18 of 22 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V32532 QC Analytical Batch(es): V32533 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V32532 LCSD-V32532 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 23.2 20.8 116 104 28-163 10.9 20.0 1,1-Dichloroethane pg/L 20.0 19.8 20.0 99.0 100 70-130 1.0 20.0 1,2-Dichloroethane pg/L 20.0 21.4 21.3 107 107 68-131 0.4 20.0 1,1-Dichloroethene pg/L 20.0 19.6 20.9 98.0 105 70-154 6.4 20.0 cis-1,2-Dichloroethene pg/L 20.0 19.4 19.5 97.0 97.5 76-141 0.5 20.0 trans-1,2-Dichloroethene pg/L 20.0 19.2 19.2 96.0 96.0 76-135 0.0 20.0 1,2-Dichloropropane pg/L 20.0 18.7 18.9 93.5 94.5 77-130 1.0 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.5 20.8 103 104 65-140 1.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 21.6 21.3 108 107 67-140 1.3 20.0 Ethylbenzene pg/L 20.0 20.0 19.5 100 97.5 80-127 2.5 20.0 2-Hexanone pg/L 20.0 32.2 23.8 161* 119 64-137 30.0* 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 25.8 25.8 129 129 71-134 0.0 20.0 4-Methyl-2-Pentanone pg/L 20.0 27.7 23.3 139* 117 69-134 17.2 20.0 Methylene Chloride pg/L 20.0 18.7 18.7 93.5 93.5 73-131 0.0 20.0 Styrene pg/L 20.0 20.6 19.8 103 99.0 78-129 3.9 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.8 20.8 104 104 79-134 0.0 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 25.2 23.5 126 118 62-127 6.9 20.0 Tetrachloroethene pg/L 20.0 20.6 20.1 103 101 80-129 2.4 20.0 Tetrahydrofuran pg/L 20.0 24.4 23.6 122 118 70-130 3.3 20.0 Toluene pg/L 20.0 20.2 20.1 101 101 76-131 0.4 20.0 1,1,1-Trichloroethane pg/L 20.0 19.7 20.3 98.5 102 75-135 3.0 20.0 1,1,2-Trichloroethane pg/L 20.0 22.5 22.1 113 111 70-140 1.7 20.0 Trichloroethene pg/L 20.0 19.7 19.6 98.5 98.0 77-133 0.5 20.0 Trichlorofluoromethane pg/L 20.0 23.4 22.2 117 111 62-148 5.2 20.0 1,2,3-Trichloropropane pg/L 20.0 26.1 23.1 131* 116 71-127 12.1 20.0 Vinyl Acetate pg/L 20.0 24.1 21.9 121 110 34-167 9.5 20.0 * QC Fail Date: 04/28/2023 01:31 PM Page 19 of 22 Page 60 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V32532 QC Analytical Batch(es): V32533 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V32532 LCSD-V32532 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Chloride pg/L 20.0 20.7 21.4 104 107 57-141 3.3 20.0 o-Xylene pg/L 20.0 20.5 19.8 103 99.0 78-128 3.4 20.0 m,p-Xylene pg/L 40.0 41.5 40.9 104 102 77-133 1.4 20.0 4-Bromofluorobenzene (S) 102 101 80-124 Dibromofluoromethane (S) 101 102 75-129 1,2-Dichloroethane - d4 (S) 109 111 63-136 Toluene-d8 (S) 99.8 99.2 77-123 Date: 04/28/2023 01:31 PM Page 20 of 22 Page 61 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Prep: V31379 QC Analytical Batch(es): V31422 QC Prep Batch Method: SW-9056A (PREP) Analysis Method: 9056A Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V31379 Matrix: AQU Associated Lab Samples: 92439, 92441, 92442 Blank MDL MQL Analyzed Parameter Units Result Chloride pg/L <370 370 1000 03/29/23 10:46 Nitrate (NO3-N) pg/L <76.0 76.0 200 03/29/23 10:46 Sulfate pg/L <650 650 2000 03/29/23 10:46 Laboratory Control Sample LCS-V31379 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride pg/L 40000 41900 105 80-120 Nitrate (NO3-N) pg/L 4000 4020 101 80-120 Sulfate pg/L 40000 43800 110 80-120 Matrix Spike & Matrix Spike Duplicate V 92439-MS-V31379 V 92439-MSD-V31379 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride pg/L 15400 40000 40000 56300 56300 102 102 80-120 0.0 20 Nitrate(NO3-N) pg/L 4930 4000 4000 9030 9040 102 103 80-120 0.1 20 Sulfate pg/L 2790 40000 40000 47400 47400 112 112 80-120 0.0 20 Date: 04/28/2023 01:31 PM Page 21 of 22 Page 62 of 66 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Anchor QEA of North Carolina, PLLC Project Description: Jackson County LF Report No: 23-088-0002 QC Analytical Batch: V31355 Analysis Method: SM-3500-Fe-13 Analysis Description: Ferrous Iron Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 92439, 92441, 92442 Blank MDL MQL Analyzed Parameter Units Result Ferrous Iron mg/L <0.05 0.05 0.20 03/29/23 13:30 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ferrous Iron mg/L 2.00 2.12 106 90-110 Matrix Spike & Matrix Spike Duplicate V 92441-MS V 92441-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ferrous Iron mg/L < 0.05 2.00 2.00 2.18 2.06 109 103 80-120 5.6 20.0 Date: 04/28/2023 01:31 PM Page 22 of 22 Page 63 of 66 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01015 Customer Name: Anchor QEA of North Carolina, PLLC Report Number: 23-088-0002 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IRT15 1.9C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Angelo Norvell Date & Time: 03/29/2023 10:41:50 Page 64 of 66 t'y❑❑❑ z R0C N Z 3 3 3 n� rA m 0 m ° 0 Cn � L L C ' a m y ri1❑ �w m °S aL o ❑❑ k7S �� 7 a n c u C Z aa$n❑ m >o m A 0 m o w e ve °z a= 0 Z a 07 1fL p ° m M G3�@@ 3 °=a p N � 3'�, z ri ❑ � ^al y 7 v m � (!� c7 � T A m y m e s a E F w ;3 ❑Ln� � n Cis ❑' ra S w n n mCD Cim ❑ ❑w m m a x m c w Gr 0 N p � v I n CD yy its❑x ry rD u �10 gam m �a C A ❑ f y CT ° A 0 r a y❑❑o 9 Z = m LIt 1 G 7 7 C) 9 a m = A- n ❑ 3 CD 3 Q z n r y D i P O o r m n or rn nz a x _ d � N a ; NIo 0 mo a m Gn rn m m 'a !p N 0 3 a 0 0 'y °! n a a o T Z TF S 41 n _ a c �1 to }( 9s P ZZ ] m m r lN a7 �77 11 dm 3m Q� nn m w w c n ❑ m a m m y to m z m a y r5O m 1 m ❑ H a � FL W 0 n y ZL G m C r,0 y' L m a n al c a N my �!r w u L �w Q w N W m JA �m m D 3 x � = m m m rn a � m v 3 v co � r � s � f z a a N IZ � a G1 m Im v � m e a r m CD ti '0 A o ❑ a 11 o a o m ❑. 7 - w y Z Vr .n+ N m 3 as sz w Aa>0_ d�n�• 0o r M Y A� � •L V 0 a G C m G m N � :3 n O Z a m Z x� 0 a s m mn c n m o c RL V� 0 Av co F .� jo s r m rN m A O C oNi K H ( O 3 2 2 m r v a M m Q cmn y A z I A m= N m 00, na zm•-j 2 2 C a o y a 0 m j Z N m G7 a 0 0q °1 m kI*xkW C HIIIIln0 Page 65 of 66 Waypointo ANALYTICAL 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529.6364 • Fax: 7041525-0409 Client Company Name: A Report To/Contact Name: i Reporting Address: CHAIN OF CUSTODY RECORD PAGE I OF I QUOTE # TO ENSURE PROPER BILLING: YES NO N/A -; Samples INTACT upon arrival? Project Name: . 4ikidn p. �Ca�iC�rin� _[l� Received IN ICE? Short Hold Analysis (U) (No) UST Project: (Yes) (W&) PROPER PRESERVATIVES indicated? *Please ATTACH any project specific reporting (QC LEVEL 1 H III IV) Received WITHIN HOLDING TIMES? y provisions and/or QC Requirements CUSTODY SEALS INTACT? ' Invoice To: fNV —%%*Y Q_ VOLATILES reed WIOUT HEADSPACE? Address: PROPER CONTAIIjERS used? _ TEMP: Therm ID:,M' 16 Observed °C IC..�'( 1A,Sh.�Vi le -I f4i 7-7t 00 f Phone: - C�jZItS-ba-l3 Fax (Yes)(Wb). Purchase Order NvJBilling Reference TO BE FILLEOIN BY CLIENTISAMPLING PERSONNEL Email Address: �+ iI�A. C(Z 'f Requested Due Date U 1 Day J 2 Days J 3 Days J 4 Days J 5 Days Certification: NC Y-, SC EDD Type: PDF--bL- Excel —other "Working Days" _i 6-8 Days pL$tandard 10 days J Pre AWrrkreMdust Be Site Location Name: a r1 3 Samples received after 15.00 will be processed next business dayp Other N[A Site Location Physical Address: ` Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES, NO bC ISEE REVERSE FOR TERMS S CON DMONS REGARDING SERVICES RENDERED BY WAYPOINT ANALYTICAL, LLC TO CUE"Samples Iced Upon Collection: YES.-,Q�NO CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ,p ANALYSIS REQUESTED L NO. SIZE SAMPLE DESCRIPTION COLLECTED MILITARY WATER, OR TIVES V ��(� t� REMARKS ID NO. HOURS SLUDGE) BELOW If►W-o3-�1.ia37� I'L1 1 �= 4S �SEE I� C? Z.1 Q� . >e- X �4 v S.z W R 02_ 7623 13 L_ {� ��YV12� t6:4s ILO dC aL Dkw -ZO 2A6 o 2-� 00 1 da DC G' ffl s z I I III I I I I II I I I I I II Il I I III 0�29-2023 Anchor QEA of North Carolina. PLLC 1041.00 Jw:ksrrn Sampler's Signature Sampled By (Print Name) , Affiliation F. lkf- ► E7 P Upon relinquishing, thi haln of stody Is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be submitted in writing to the Waypoint Analytical Project Manager. There will be charges for any changes after analyses have been Initialized. Site Arrival Tlme: RadrKzuis d ey (Signature) Received By: (Signature) Date MirraryrHours Additional Comments: Site Departure Time. 4 By: (Signs ) Recerved By: (Signature) Dam Field Tech Fee; tatP-Onquis Relinquished By: (Signature) Received For Waypanl A wal By: yil ^ d Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD 9E TAPED SHUT WITH CUSTODY SEALS FOR TRANSPO N T HE LABORATORY. OC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORA RY ❑ Fed Ex LI UPS J Hand -""red J Waypoint Analyflcai Field Service J Dlher NPDES: UST: GRDUiiEDWATER. DRINKINGWATER: SOLID WASTE: RCRA: BRWNFLD LANDFILL ❑ SC I JSC ❑NC JSC I❑ II I❑ LitZI — L] J J ❑ LJ nC?Ir-;InIAI ID w 0 ko ID a� rn a `CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA - Volatile Organics Analysis (Zero Head Space)