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HomeMy WebLinkAbout4101_Guilford_CityHighPoint_Riverdale_MSWLF_Seaboard_PFASMonitoringWorkPlan_FID1817457_20230912SEABOARD GROUP II AND CITY OF HIGH POINT, NC TO: North Carolina Department of Environmental Quality ATTN: Eric Aufderhaar, Hazardous Waste Section Jackie Drummond, Solid Waste Section FROM: Seaboard Group II and City of High Point SUBJECT: Technical Memorandum No. E-12 — PFAS Monitoring Workplan DATE: September 11, 2023 In response to the NCDEQ's August 10, 2023 request to conduct water quality monitoring for PFAS compounds at the Site, the Seaboard Group II and the City of High Point (Parties) have prepared this Workplan in accordance with the Remedial Action Settlement Agreement (RASA), Exhibit A - Statement of Work, Section B. This Workplan represents Technical Memorandum No. E-12 (TM-12) developed under the amendment provisions of the RASA. The NC Solid Waste Section has issued two Memoranda, dated March 13 and July 17, 2023, regarding selection of sample locations, sample collection and analytical methodology, monitoring frequency, and data reporting. These two documents, in conjunction with the virtual meeting between the Parties and NCDEQ on August 2, 2023, provide the basis for development of this Workplan. The objective of this Workplan is to analyze groundwater and surface water at the former Seaboard Chemical/Riverdale Drive Landfill Site (Site) for the presence of the 40 PFAS compounds identified by EPA Draft Method 1633. The groundwater monitoring wells and surface water sample locations included in this Workplan were selected to determine if PFAS compounds are present in groundwater and/or surface water at the Site. The focus of this Workplan is to analyze groundwater quality at select monitoring locations indicative of Site conditions for the presence of PFAS compounds. The following criteria were used to select the proposed water quality monitoring locations: • An upgradient groundwater monitoring location which has not been impacted by activities at the Site. • Groundwater monitoring locations which are representative of the water quality hydraulically downgradient of the Site. • Monitoring well locations which have shown the presence of Site contaminants during water quality monitoring events conducted over the past 25 years. • Surface water monitoring locations near the downgradient property boundary. Page - 1 of 4 SEABOARD GROUP II AND CITY OF HIGH POINT, NC In line with these selection criteria, the following water quality monitoring locations are proposed for evaluation of PFAS compounds by EPA Draft Method 1633: Upgradient Groundwater Monitoring The existing upgradient groundwater monitoring well MW-1, screened from 47'-57', will provide an upgradient water quality location which has not been affected by activities at the Site. The historical water quality data for this well is provided on Table 1. Northern Intermittent Stream (NIS) Area The NIS area consists of the older portion of the former Landfill and any discharges from the former Burn Pit area. This area of the closed Landfill is currently used for Zones 1 — 11 of the phytoremediation treatment system. One groundwater monitoring well and one surface water location are proposed to analyze for the presence/absence of PFAS compounds: • Monitoring well MW-12A, screened from 5' — 20', is proposed to analyze shallow groundwater immediately downgradient of the closed Landfill area and phytoremediation zones 1- 11. This is the shallow well in a three well nest and has historically shown the highest contaminant concentrations at this location (Table 1). • Surface water monitoring station SW-2 is proposed to analyze overland flow from Phytoremediation Zones 1 - 11 and topographically upgradient properties. Southern Intermittent Stream (SIS) Area The SIS drainage area has been identified as the primary contaminant migration pathway. The presence of the landfill, Soil Residue Mound, and the operational areas of the former Seaboard Chemical facility serve as source areas for the contaminants observed in the SIS drainage valley. Portions of phytoremediation zones 2, 3, 4, 15, and 16 also drain to the SIS valley. The majority of the groundwater extraction activities occur in the SIS drainage valley as noted on Figure 1. Two groundwater monitoring wells and one surface water location are proposed to analyze for the presence/absence of PFAS compounds: • Monitoring well MW-3C (screened from 47' — 57') is proposed to analyze the shallow bedrock zone at the downgradient extent of the SIS drainage valley. The historical contaminant concentrations in MW-3C well pair has decreased over the past five years due to the operation of the extraction system at PW-DR1. • Monitoring well PW-61 (screened from 90' — 100') is proposed to analyze groundwater from the SIS drainage valley. This well represents the approximate eastern extent of the SIS drainage valley contaminant plume. The historical contaminant concentration in this well has remained stable over the past five years. • Surface water monitoring station SW-4 is proposed to analyze the shallow groundwater discharge in the SIS drainage valley which outlets into the SIS Basin. Page - 2 of 4 SEABOARD GROUP II AND CITY OF HIGH POINT, NC Eastern Boundary of Former Landfill Area The eastern extent of the former Landfill adjacent to Interstate 85 is downgradient of Zones 12 — 16 of the phytoremediation treatment system. The monitoring wells on the eastern border of the former Landfill are located along a drainage depression that likely represents a preferential groundwater flow path. To analyze for the presence/absence of PFAS compounds in this area, the sampling of one groundwater monitoring well is proposed: Groundwater Monitoring well MW-10, screened from 8' — 28', will analyze water quality in the shallow groundwater aquifer near the outlet of a wet -weather drainage feature. The contaminant concentrations in this well have been minor in this well over the past five years. Groundwater and Surface Water Collection and The groundwater and surface water evaluation for PFAS compounds will occur as a standalone monitoring event to reduce the potential for cross -contamination during sample collection. The samples will be collected using low -flow techniques to reduce turbidity in the samples. PFAS-specific sample collection precautions will be followed and the sample team will adhere to guidance provided by the Interstate Technology and Regulatory Council (https://pfas-1.itrcweb.org). The following general modifications to the low -flow sampling procedure are planned to limit the potential for cross -contamination during collection of the PFAS samples: • The tubing used for sample collection will consist of silicone tubing for the peristaltic pump head and HDPE for the downhole tubing. New tubing will be used for each sample location. • Powder -free nitrile gloves will be worn by all sampling personnel which will be changed out between each sample location. • The sample collection team will consist of two technicians; one person will operate the pump and tubing while the second person will only handle the sample containers. • No Teflon TM products, insect repellant, or sunscreen will be used by the sample collection team during the monitoring event. A trip blank, two equipment blanks (one following initial sample collection and the second following final sample collection) and one duplicate sample will be collected as part of this effort. The surface water samples for PFAS analysis (SW-2 and SW-4) will be collected as grab samples directly in the laboratory -supplied containers. Sampling personnel will wear new disposable powder -free nitrile gloves for each sample location. All collected samples will be sent to a laboratory accredited to perform draft Method 1633 on aqueous solutions. Page - 3 of 4 SEABOARD GROUP II AND CITY OF HIGH POINT, NC The results of the sampling contained in this Work Plan will be tabulated and provided to NCDEQ as discussed during the August 2, 2023 virtual meeting regarding this effort. Please contact Craig Coslett (610/435-1151, Extension 8001) or Gary Babb (919/605-4719) if there are any questions or comments regarding this Technical Memorandum. Respectfully, Seaboard Group II and City of High Point A Mr. Craig Coslett, Project Coordinator de maximis, inc. 1550 Pond Road, Suite 120 Allentown, PA 18104 ccoslett@demaximis.com Gary D. Babb, P.G. Babb & Associates, P.A. gdbabb@gmail.com Attachments Figure 1— Proposed PFAS Sample Locations Table 1— Historical VOC Analytical Summary 2' SEAL 1' _ 488 Page - 4 of 4 Landfill Property Line N % -1 ad West Lobe Phyto Zones 1 thru 11 SW-6 Located Upstream �At Kivett Dr. Bridge ■NIS Sump MW-12A %' MW-12B MW-1 CPW-14D D SW-DRP2 Soil Residue _ low PW-131 MW-3C ",OW-DR2 LS-1 VIV PW-51D ° •PW-D ORW-SIS8 Mechanical Treatment 1 SIS7 System and LS-2 LCHT5� SW-4 �i P pe L • MW-15A gas S -3 W-4 :. Facility♦ �� ORW IS2 SW-5 • RW-SIS4* •-SIS3 ®r ;k PW-SF10 W-3D PW-41 R-1 ,h PW-16D .. PW-15D :ll . .ItPW-6D PW-61 LCHT2 ■ RW-LFS2 Ah OW-LFS2" 'AG East Lobe Pond 3 Phyto Zones ry� z Former 12 thru 16 kq Site F Seaboard Property Line R N Landfill Property Li :D MW-6 PW-101„rI,MW-10 RW-LFS1 �' PW-101 LCHT1 - Groundwater Monitoring Well Surface Water Monitoring Locatio Leachate Collection Tank/Sump Shallow Groundwater Recovery Well Deep Groundwater Recovery Well Proposed PFAS Sample Location vvell ID Screen Interval I MW-1 47' — 57' MW-12A 5' — 20' MW-3C 47' — 57' PW-61 90' — 100 MW-10 8' — 28' SW-DRP11 Located Downstream At The Confluence O Richland Creek 01 TABLE 1 GROUND WATER ANALYTICAL RESULTS - VOCs and 1,4-Dioxane SEABOARD CHEMICAL/RIVERDALE DRIVE LANDFILL SITE Page I of 3 VOLATILE ORGANIC COMPOUNDS (ug/L) 1 C � y y Sample O n N N 0 p N O M N Sample I.D. b q b F 0 0 b Date 0 0 0 0 c, Q- S 3 S 3 3 M O 3 O S S S S 3 3 O ? O O O O O A y 0 O S 0 O `G fD O O O 7 S O O O O O 0 D W 0 a O O O a n O -4 O O n O N O _O N .. fD .. M W .. O 0 O O n M O 3 O 7 (D O .O. M W 7 3 M .• O M M S : < O x 3 S S 3 =r 3 -a �( .r N N O N 3 �+ O S S N O 3 C S 3 O O O 0) 3 0) 7 N 7 fD 7 0) 7 0) 3 a) 7 O 7 fD 7 M N 7 0) 7 0) 7 fD 7 fD 7 M lD 7 fD 7 N 7 lD 7 CL >v 0 (D fD I M M N M M M M M M M M M M CD M M N M M U) NC 2L Standard NE 200 0.6 6 350 0.4 0.6 3 6000 1 0.3 50 3,000 70 3 70 600 5 0.7 600 100 3 0.03 500 MW-1 1/28/1997 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 3/5/2009 17 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 15.3 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2.1 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 ND 3/31/2010 0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ND ND 11/2/2011 0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <3.0 <5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ND 11/20/2012 54 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 54.4 <5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ND 1/21/2013 ND <2.0 12/9/2013 ND <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <2.0 <5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 ND 12/8/2014 ND <1 <1 <1 <1 <1 <1 <2 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 10/26/2015 ND <1 <1 <1 <1 <1 <1 <2 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 11/14/2016 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 10/11/2017 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 11/1/2018 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 <5 9/10/2019 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 10/13/2020 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 ND 10/26/2021 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 ND 10/12/2022 ND <1 <1 <1 <1 <1 <1 <2 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <0.3 ND MW-3C 8/6/1996 273 11 ND 150 31 5.0 ND ND 6 37 ND ND ND ND 2 J 4J ND ND 14 13 ND ND 1/28/1997 197 6 ND 92 21 3.0 ND ND ND ND 41 14 ND NA ND 1 J ND ND ND 9 10.0 ND ND 9/26/2000 138 <5 <5 41 7.2 <5 <5 <100 NA <5 32 <10 <5 21 <5 <5 <5 37 <5 <5 <10 <10 ND 9/5/2001 178 <5 <5 22.6 <5 <5 <5 117 <10 <5 24.2 <10 <5 14.6 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/18/2002 152 <5 <5 18.4 <5 <5 <5 94.6 <10 <5 27.3 <10 <5 12 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/19/2003 103 <5 <5 <5 <5 <5 <5 90 <10 <5 13.4 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 8/17/2004 132 <5 <5 19.4 <5 <5 <5 71 <10 <5 30.0 <10 <5 12.4 <5 <5 <5 <5 <5 <5 <10 <5 ND 2/27/2009 589 <1.0 <1.0 104 20.3 4.4 <1.0 160 <5.0 3.0 <1.0 151 32.7 <1.0 <1.0 70.1 <1.0 <1.0 1.9 <1.0 <1.0 2.5 39.4 <2.0 ND 3/30/2010 863 <1.0 <1.0 161 32.4 6.31 <1.0 186 <5.0 3.92 <1.0 249 45.7 <1.0 <1.0 108 <1.0 4.87 1.71 <1.0 <1.0 2.71 61 ND ND 11/1/2011 1,861 29.1 <0.5 396 144 14 <0.5 80 <0.5 9.94 <0.5 459 192 <0.5 <0.5 364 <0.5 <0.5 3.09 <0.5 1.15 8.74 157 <0.5 3.26 11 /20/2012 1,798 28.5 <0.5 361 106 <0.5 <0.5 268 <0.5 8.73 <0.5 386 150 <0.5 <0.5 314 <0.5 4.30 3.83 1.26 1.40 8.36 146 0.7 10.31 12/11/2013 2,268 18.6 <5 383 107 15 <5 549 <50 9 <5 559 137 <5 <5 318 <5 <5 <5 <5 <5 <5 173 <5 ND 12/11/2014 2,051 100 <1 290 170 <1 <1 311 <5.0 12 17.0 330 60 <1 <1 620 <1 <1 <1 <1 <1 11 130 <3 ND 10/27/2015 1,262 66 <1 210 100 <1 <1 308 >50 10 <1 350 40 <1 <1 410 <1 <1 <1 <1 <1 9.4 J 67 <30 ND 11/14/2016 872 67 <10 94 56 <10 <10 190 <10 5.4 J 12.0 150 <10 <10 <10 270 <10 <10 <10 <10 <10 6.0 27 <30 ND 10/10/2017 402 15 <1 57 22 1.8 <1 120 <20 2.2 <1 49 6.2 J <1 <1 100 <1 <1 0.81 J <1 0.73 J 2.0 31 <3 1.70 11/2/2018 414 6 <1 54 30 1.9 <1 110 <20 3.2 <1 66 6.3 <1 <1 110 <1 <1 0.62 J <1 0.61 J 2.3 22 <3 2.60 9/11/2019 288 <10 <10 41 17 <10 <10 94 <200 <10 <10 50 <10 <10 <10 72 <10 <10 <10 <10 <10 <10 14 <30 ND 10/13/2020 246 1.7 <1 38 13 1.5 <1 64 <20 1.6 <1 50 5.4 <1 <1 46 <1 <1 <1 0.57 J 0.55 J 1.4 23 <2 ND 10/26/2021 156 <1 <1 37 2 1.4 <1 67 <20 0.93 J <1 36 2.8 <1 <1 9.8 <1 <1 <1 <1 0.53 J <1 21 <2 ND 10/17/2022 173 <1 <1 28 5 1.3 <1 39 <20 0.97 J <1 64 <1 <1 <1 18.0 <1 <1 <1 <1 0.56 J <1 15 <3 1.51 TABLE 1 GROUND WATER ANALYTICAL RESULTS - VOCs and 1,4-Dioxane SEABOARD CHEMICAL/RIVERDALE DRIVE LANDFILL SITE Page 2 of 3 a, 1 0 v; Sample p ^' N v c ^' =? CD ^' Sample I.D. Date �, M b q b a 3 3 n n n E c, m c, a 3 s s s 0 O m ,� O 3 n O 3 S 3 n 3 S_ n 3 3 (DD O ? O O O O O aA y p O 3' p O `G fD O O O 3 3' O O O O O 'a D 07 n a O O O a n O -4 O O n O N CD O O N .. fD .. (D O ,. 0 O _G O n CD O 3 3' fD 3 M .. O .O. O - W 3 3' fD �+ O_ fD a fD - S_ : C 3' 3' 3' 3' 3' 'O x .r N O N =r �+ Ob S 3' N O 3' C S 3' O O O y 0) 3 0) 3 2) 7 CD 3 a) 3 o) 3 a) 3 O 3 fD 7 CL CD 3 a) 3 c) 3 N 3 CD 3 M CD 3 fD 3 N 3 CD 3 Q 2) n fD M fD CD fD fD CD M fD M fD fD fD fD fD fD CD M fD CD fD to NC 2L Standard NE 200 0.6 6 350 0.4 0.6 3 6000 1 0.3 50 3,000 70 3 70 600 5 0.7 600 100 3 0.03 500 MW-10 1/27/1997 126 ND ND 6 ND ND ND 120 ND 2 J ND ND ND ND ND ND ND ND 1 J ND ND ND 7/14/1998 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 9/26/2000 258 <5 <5 7.6 <5 <5 <5 250 NA <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <10 ND 9/6/2001 335 <5 <5 <5 <5 <5 <5 335 <10 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/19/2002 234 <5 <5 <5 <5 <5 <5 234 <10 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/16/2003 221 <5 <5 <5 <5 <5 <5 221 <10 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 8/19/2004 198 <5 <5 <5 <5 <5 <5 198 <10 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 3/6/2009 176 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 162 6.4 1.1 <1.0 4.1 <1.0 <1.0 <1.0 <1.0 <1.0 2.2 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 ND 3/29/2010 184 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 166 10.6 <1.0 <1.0 3.82 1.26 <1.0 <1.0 <1.0 <1.0 2.31 <1.0 <1.0 <1.0 <1.0 <1.0 ND ND 11 /1 /2011 56 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 47 <0.5 <0.5 <0.5 3.99 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 6.45 11/19/2012 148 <5 74 <5 <5 <5 <5 74.4 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ND 12/10/2013 33 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 28.1 <5 <0.5 <0.5 2.27 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <1 2.7 12/10/2014 137 <1 <1 <1 <1 <1 <1 133 <5 <1 <1 2.6 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 1.2 10/26/2015 104 <1 <1 <1 <1 <1 <1 103 <5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 1.1 11/14/2016 130 <1 <1 <1 <1 <1 <1 130 <20 0.78 J <1 2.8 J <1 <1 <1 0.41 J <1 <1 <1 <1 <1 <1 <1 <3 ND 10/10/2017 150 <1 <1 <1 <1 <1 <1 150 <20 <1 <1 <1 1.8 J <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 10/31/2018 160 <1 <1 <1 <1 <1 <1 160 <20 <1 <1 0.93 J 1.1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 9/10/2019 74 <1 <1 <1 <1 <1 <1 72 <20 <1 <1 1.5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND 10/12/2020 14 <1 <1 <1 <1 <1 <1 14 <20 <1 <1 0.46 J <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 ND 10/26/2021 10 <1 <1 <1 <1 <1 <1 10 <20 <1 <1 0.46 J <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 ND 10/14/2022 12 <1 <1 <1 <1 <1 <1 12 <20 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 ND MW-12A 1/23/1997 11 2 J ND ND 3 J ND ND ND ND 2 J ND ND ND ND ND ND 2 J ND 2 J ND ND ND 7/10/1998 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10/30/2000 ND <5 <5 <5 <5 <5 <5 <100 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <10 ND 9/6/2001 12 <5 <5 <5 <5 <5 <5 <10 12.3 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/20/2002 27 <5 <5 <5 <5 <5 <5 11.7 14.9 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/16/2003 28 <5 <5 <5 <5 <5 <5 11.9 15.6 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 8/18/2004 44 <5 <5 <5 <5 <5 <5 <10 43.7 <5 <5 <10 <5 <5 <5 <5 <5 <5 <5 <5 <10 <5 ND 3/6/2009 40 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 38.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1.9 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 ND 4/1/2010 6 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2.50 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 3.09 <1.0 <1.0 <1.0 <1.0 <1.0 ND ND 11 /2/2011 38 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 29.0 <5 <0.5 <0.5 8.04 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.61 11/19/2012 203 <5 <5 <5 <5 <5 <5 203 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ND 12/10/2013 210 <5 <5 <5 <5 <5 <5 210 <50 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <10 ND 12/11/2014 226 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 210 8.3 <1.0 <1.0 5.6 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <3 1.7 10/27/2015 213 <1 <1 <1 <1 <1 <1 200 <5 <1 <1 11 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 2.2 11/14/2016 207 <1 <1 <1 <1 <1 <1 200 19 J <1 <1 5.9 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 1.5 10/10/2017 273 <1 <1 <1 <1 <1 <1 260 <20 <1 <1 11 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 1.7 11/1/2018 93 <1 <1 <1 <1 <1 <1 79 <20 <1 <1 11 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 2.9 9/10/2019 189 <1 <1 <1 <1 <1 <1 180 16 J <1 <1 6.2 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <3 2.9 10/13/2020 34 <1 <1 <1 <1 <1 <1 31 <20 <1 <1 1.0 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 2.0 10/26/2021 188 <1 <1 <1 <1 <1 <1 180 <20 <1 <1 5.8 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <2 1.7 10/17/2022 1 157 <1 I <1 <1 <1 <1 I <1 1 150 1 <20 I <1 <1 6.9 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 I <1 <3 ND TABLE 1 GROUND WATER ANALYTICAL RESULTS - VOCs and 1,4-Dioxane SEABOARD CHEMICAL/RIVERDALE DRIVE LANDFILL SITE Page 3 of 3 Sample I.D. Sample p Date �, a ? O O y 3 O O N .. 3' D) 3 fD ^' M s O O fD .. 3' 01 3 CD b s O O (D 3' N 7 M 1 q s O O 3' CD 3 CD N b 0 O O O ,. 3' a) 3 fD b a 3 O aA 'a 0 O 'O 0) 3 I M _G O X a)O 3 CD D 0 CD .r 3 I M W O 3 N CD 3 M 0 o 3 m ,� y n 3' O CL M n O p rr fD 3 N N 3 fD n 3 O O M .. =r a) 3 I M n 3' O O �+ n E O p S .O. S c) 3 fD v; c, 3 O O O - 3' fD 3 I N m S `< a W 3 N fD 3 M 3 fD n 3' O M fD n 3 O O fD �+ S lD 3 CD -4 O_ C M 3 M a, c, S_ O O fD a 3' N 3 N n 3 O O fD - 3' lD 3 CD 3 n S_ O Q M 3 O N : O 2) O 3' CD C O n to NC 2L Standard NE 200 0.6 6 350 0.4 0.6 3 6000 1 0.3 50 3,000 70 3 70 600 5 0.7 600 100 3 0.03 500 PW-61 1/28/1997 33 ND ND 11 ND 1 J ND ND ND ND 14 4 J ND ND 1 J ND ND ND 2 J ND ND ND 7/14/1998 46 ND ND 10 ND ND ND ND ND ND 14 4 J ND 5 ND ND 5 ND ND 3 J ND ND 5 9/26/2000 29 <5 <5 12 <5 <5 <5 <100 <5 8.4 <10 <5 8.3 <5 <5 <5 <5 <5 <5 <10 <10 ND 9/12/2001 28 <5 <5 10.7 <5 <5 <5 <10 <10 <5 7.2 <10 <5 9.9 <5 <5 <5 <5 <5 <5 <10 <5 ND 9/19/2002 31 <5 <5 12.2 <5 <5 <5 <10 <10 <5 9.0 <10 <5 9.8 <5 <5 <5 <5 <5 <5 <10 <5 ND 10/20/2003 47 <5 <5 12.1 <5 <5 <5 11.6 <10 <5 9.9 <10 <5 13 <5 <5 <5 <5 <5 <5 <10 <5 ND 8/25/2004 42 <5 <5 10.6 <5 <5 <5 11.7 <10 <5 6.2 <10 <5 13.0 <5 <5 <5 <5 <5 <5 <10 <5 ND 3/4/2009 8.2 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <5.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2.0 <1.0 2.4 <1.0 3.8 <1.0 <1.0 <1.0 <2.0 ND 3/31/2010 143.1 <1.0 <1.0 32 1.63 3.47 <1.0 22.5 <5.0 <1.0 <1.0 35.7 10.3 <1.0 <1.0 25.2 <1.0 <1.0 1.56 <1.0 <1.0 2.81 7.88 ND ND 11/3/2011 damaged 11/21/2012 damaged 12/10/2013 damaged new well 12/10/2014 115 0.41 J <1 26 2.2 <1 <1 47.9 <5 <1 <1 2.2 <1 <1 <1 24 <1 1.1 0.7 J 0.7 J <1 1.1 3.3 4.8 1.9 10/27/2015 98 <1 <1 20 1.1 J 3 <1 46.7 <5 <1 <1 7.6 <1 <1 <1 18 <1 <1 0.74 J <1 <1 1.4 <1 <3 1.1 11/17/2016 132 <1 <1 19 1.1 J 11 <1 56 <20 0.47 J <1 21 <1 <1 <1 18 <1 0.53 J 1.0 <1 <1 2.5 3.6 <3 3.89 J 10/10/2017 148 <1 <1 25 0.92 J 3.6 <1 71 <20 0.52 J <1 19 <1 <1 <1 25 <1 <1 0.42 J <1 <1 1.1 3.0 <3 1.4 11/1/2018 128 <1 <1 17 1.1 3.2 0.4 J 60 <20 0.58 J <1 14 <1 <1 <1 24 <1 <1 0.8 J <1 <1 1.7 4.7 <3 1.8 9/12/2019 148 <1 <1 19 1.0 2.9 <1 79 <20 0.74 J <1 13 <1 <1 <1 26 <1 <1 0.42 J <1 <1 <1 5.3 <3 1.8 10/13/2020 137 <1 <1 20 1.4 3.3 <1 63 <20 0.74 J <1 15 <1 <1 <1 26 <1 <1 0.52 J <1 0.43 J 1.6 4.5 <2 1.8 10/28/2021 115 <1 <1 11 0.74 J 2.1 <1 69 <20 0.62 J <1 9.6 <1 <1 <1 18 <1 <1 0.50 J <1 <1 <1 3.2 <2 2.0 10/14/2022 116 <1 <1 8.3 <1 2.0 <1 86 <20 <1 <1 5.2 <1 <1 <1 12 <1 <1 <1 <1 <1 <1 1.6 <3 1.2 ug/1= micrograms per liter J = Estimated Value ND = Not Detected NA - Not Analyzed Bold type indicates value exceeds NC 2L ground water standard