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HomeMy WebLinkAbout23076_RalMGP2II_Odor&AQMngtPlan_20211104RALEIGH MGP II ODOR AND AIR QUALITY MANAGEMENT PLAN 400 S WEST ST AND 561 AND 600 W CABARRUS ST, RALEIGH BROWNFIELDS PROJECT NUMBER: 13022-09-92 (Version 2.0) Prepared for: NC Department of Environmental Quality Division of Waste Management Brownfields Program 217 W Jones St. Raleigh, NC 27699 Prepared by: Aptus Management, PLLC 109 Amber Court Carrboro, NC 27510 NC Firm Engineering License # P-1130 John Gallagher, P.E., RSM �FESS/o,���� SEAL - 024199 N November 4, 2021 CONTENTS 1 INTRODUCTION.....................................................................................................................................1 1.1 Site Location..................................................................................................................................1 1.2 Site History....................................................................................................................................1 1.3 Redevelopment Plan.....................................................................................................................2 1.4 Residual MGP Contamination.......................................................................................................2 1.5 Roles and Responsibilities.............................................................................................................2 2 Real -Time Air Monitoring......................................................................................................................4 2.1 Monitoring Parameters.................................................................................................................4 2.1.1 VOCs......................................................................................................................................4 2.1.2 Particulates...........................................................................................................................4 2.2 Real -Time Action Levels................................................................................................................5 2.2.1 VOCs......................................................................................................................................5 2.2.2 Particulates........................................................................................................................... 6 2.3 Real -Time Monitoring Frequency & Locations............................................................................. 6 3 Time -Integrated Air Quality Monitoring...............................................................................................7 3.1 Pre -Construction Air Quality Monitoring......................................................................................7 3.2 Confirmatory Air Quality Testing..................................................................................................7 3.3 Monitoring Using SUMMA Canister Samples...............................................................................7 3.4 Particle Monitoring.......................................................................................................................8 4 Odor Assessment & Management........................................................................................................9 4.1 Objectives...................................................................................................................................... 9 4.2 Odor Assessment Frequency and Locations.................................................................................9 4.3 Odor Classification........................................................................................................................ 9 5 Odor and Fugitive Emission Controls..................................................................................................10 6 Reporting.............................................................................................................................................11 6.1 Field logs.....................................................................................................................................11 6.2 Real -Time Monitoring Data.........................................................................................................11 6.3 Time -Integrated Sampling Data..................................................................................................11 6.4 Notification and Reporting..........................................................................................................11 FIGURES Figure 1: Site Location Map Figure 2: Existing Conditions C1.00 Plan (Prepared by McAdams) Figure 3: Brownfields Survey Plat Figure 4: Known Residual Contamination Figure 5: Extent of the MGP Cleanup and Areas of Clean Fill Figure 6: Air Monitoring Locations APPENDICES Appendix A — Field Data Forms Appendix B — Monitoring Events/Reports Appendix C — Instrumentation Specification Appendix D — Odor Suppression Foam - Safety Data Sheet 1 INTRODUCTION This Odor and Air Quality Management Plan was prepared as a companion document to the April 8, 2021, Raleigh MGP II site Environmental Management Plan (EMP) prepared by Aptus Management, PLLC (Aptus), which was approved by the NC Department of Environmental Quality (DEQ) on April 9, 2021. The Plan describes the methods, procedures, and response actions for odor and perimeter air quality monitoring during development to control for odors and fugitive emissions in order to minimize impacts to the surrounding community. This Plan includes the following: • Checks conducted at least three time per day to identify detectable and potentially objectionable nuisance odors via olfactory observations and instrument monitoring; • Real-time fence line monitoring conducted at a minimum of eight locations at least three times per day for VOCs and particulates in ambient air; • Verifying real-time monitoring data through collection of confirmatory air quality samples and testing by EPA Method TO-15; • Best management practices (BMPs) for site work to minimize odors and VOCs in ambient air, including limiting open excavation work faces, using clean fill to create a physical barrier, odor suppression, and immediately covering stockpiled waste material prior to offsite disposal; and • Contingency planning and corrective action utilizing physical methods to limit odors and VOC emissions (e.g., suppression foams). 1.1 Site Location The Raleigh MGP II site consists of 5.91 acres of land located on three contiguous lots. A Location Map is attached as Figure 1 and the Existing Conditions C1.00 Plan prepared by McAdams is attached as Figure 2. 1.2 Site History The property was home to various industrial operations dating back to the late 1800s, including, most importantly, a manufactured gas plant (MGP) that operated from 1916 until 1953. The MGP operations caused contamination due to spillage and onsite disposal of tars and other wastes. By 1989, PSNC Energy Company had dismantled all MGP equipment and structures. Starting in 2001 and culminating in 2011, PSNC implemented four large-scale cleanup actions that included removal and offsite disposal of 54,000 tons of contaminated material and using treatment reagents to degrade the remaining pollution. The remediation was overseen by DEQ's Waste Management Division, IHSB, Special Remediation Branch. The past cleanup actions removed much of the contamination caused by the past MGP operations. Remediation was conducted across the former MGP facility footprint, and the cleanup areas were backfilled and covered with clean fill to allow site reuse and redevelopment. Nevertheless, residual contamination remains in some areas below ground in soil and groundwater. Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 2 The site is participating in the NC Brownfields Program. In November 2011, DEQ Brownfields Agreement No. 13022-09-92 was recorded with Wake County that applied to 4.08 acres of the Site where the MGP facility was located. According to DEQ, the original 2011 Brownfields Agreement will be superseded by a new comprehensive agreement for the entire 5.91-acre redevelopment site sometime in 2022. 1.3 Redevelopment Plan The current phase of redevelopment consists of work on the western portion of the site and includes demolition of existing improvements, which have largely been completed, construction of a new stormwater culvert through the site and followed by construction of a mixed -use 436,000- sq-ft building with 443 apartment units. The building will be seven levels in total, one ground level of amenity, commercial and parking areas with six levels of apartments above. The ground level will provide 27,000 square feet of commercial/retail space and 12,250 square feet of lobby space. A 592-space parking structure will be completely wrapped by the commercial and residential portion. The redevelopment will take approximately two years to complete. Ground disturbance where there is the potential for fugitive emissions and odors will occur largely in the first six months of the project, November 2021 through April 2021, including the construction of the new stormwater culvert. Some ground disturbance activities may continue throughout the first year of construction for foundations. Monitoring for VOCs and odors will be conducted whenever there are construction activities where there is the potential to generate fugitive emissions and odors. 1.4 Residual MGP Contamination Gas Plant by-products and wastes are predominantly tars left over when coal was processed to make a burnable gas. Compounds of concern are petroleum -based and include many of the same chemicals as found in asphalt, heating oil and gasoline. Specific pollutants at the Raleigh MGP II site included volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene and xylenes (or BTEX), semi -volatile compounds (naphthalene), and polycyclic aromatic hydrocarbons (or PAHs). The former cleanup areas and the remaining known residual impacts are shown in the attached Brownfields Survey Plat as Figure 3. Known residual contamination in relation to the existing and proposed stormwater culverts and other site features is also shown in Figure 4. The extend of the MGP cleanup and areas of clean fill are shown in Figure 5, which also shows the brownfields site boundaries established by recombination. 1.5 Roles and Responsibilities Provided below is a summary the respective roles and responsibilities associated with the Odor and Air Quality Management Plan. • John Gallagher, PE, will be the principal engineer in overall responsible charge. (Aptus Mgmt) • Robert Hill, PE, will serve as the day-to-day project manager and direct all monitoring and report to Mr. Gallagher. Mr. Hill will supervise monitoring and assist contractors with the Odor and Air Quality Management Plan Raleigh MGP 11 November 4, 2021 Page 3 implementation of preventative and corrective action measures for fugitive emissions and odors. Mr. Hill will participate in real-time monitoring, as outlined below, at least once per week. Either Mr. Hill or Janet Phillips or their designee (an S&ME technician) will conduct TO-15 sampling (REC) • Janet Phillips, Senior Industrial Hygienist, will support the project monitoring and report to Mr. Hill. (S&ME). Suitably trained S&ME technicians will conduct some of the monitoring. • Dennis Strickland is the Clancy & Theys (general contractor) project manager and in overall charge of site construction activities. Mr. Strickland will be responsible for the general contractor's and subcontractors' implementation of preventative and corrective action measures for fugitive emissions and odors. He will work closely with Mr. Hill and Ms. Philips on monitoring and fugitive emission and odor controls. • Monitoring Technicians — we will train two or more technicians to conduct the real-time monitoring under Mr. Hill's direct supervision. They will be Clancy & They project personnel but will report directly to Mr. Hill. (Note: Only Mr. Hill or Ms. Phillips or their designee will conduct time -weighted TO-15 sampling. This will not be done by Clancy & Theys personnel.) Odor and Air Quality Management Plan Raleigh MGP 11 2 REAL-TIME AIR MONITORING November 4, 2021 Page 4 Most of the MGP wastes and impacted materials were removed by PSNC in a series of cleanups that ended in 2011, but residual pockets remain which were infeasible to be removed. During construction, residual MGP waste and impacted materials may be encountered from time to time. Possible sources of fugitive odors and emissions include open ground disturbance work areas, stockpiled impacted material, excavation, foundation spoils and other activities that may encounter residual MGP wastes. Real-time ambient air quality monitoring for particulates and volatile organic compounds (VOCs) will be performed at the site perimeter at eight locations (Figure 6) and within the site at the location of activities (i.e., ground disturbance) which could result in fugitive emissions or odors to help ensure acceptable air quality conditions. Real-time air monitoring will be compared to site - specific action levels to help direct fugitive emission and odor controls. A low -detection photo -ionization ppbRae detector (PID) and an aerosol dust monitor will be used to perform real-time field screening. This real-time data will document measured levels of contaminants and help define when additional vapor, odor and/or dust suppression activities or alteration of work activities are necessary. 2.1 Monitoring Parameters For MGP-impacted material, benzene and naphthalene are key VOCs and benzene is the compound that drives public health concerns due to its prevalence and relative volatility. Moreover, benzene alone has a low exposure limit (EPA IRIS Inhalation Unit Risk 7.8 x 10-6 ug/m3) to be used as a surrogate for the total VOC mixture found in fugitive emissions at MGP sites and naphthalene (which is a sVOC and much less volatile than benzene). Therefore, we propose to focus MGP air quality decisions and action levels on benzene. Benzene is a known human carcinogen (EPA class A) and volatile (vapor pressure 75 mm Hg, 20 °C). This approach — using benzene to set monitoring parameters -- is common and customary for monitoring fugitive emissions at MGP sites (see, for example, Wisconsin DHS: MGP Air Guidance and NY DEC Manufactured Gas Plants Program). 2.1.1 VOCs Real-time monitoring for VOCs will be conducted using a ppbRAE or MiniRAE portable PID with a 10.6ev lamp (or equivalent instrument). The PID will be used to non -selectively monitor VOC concentrations. The PID will have a detection limit of 1 part per billion (ppb). The PID will be used to monitor air quality at along the fence line and within the site at work areas. Instrument readings will be measured over a 1-minute sample interval at each location. Instrument readings will be observed and recorded on data sheets. If/when data is logged by the instrument, the logs will be transferred from the data -logger to electronic files. Documentation of routine, periodic calibration and/or "bump tests" in accordance with the manufacturer's specifications will meet the equipment quality assurance/quality control (QA/QC) for these units. 2.1.2 Particulates Real-time monitoring of fugitive particulates will be conducted during perimeter monitoring and Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 5 within the site at work areas using a TSI Dust Trak II Aerosol Monitor, Thermo DataRAM pDR- Dust Monitor, (or equivalent instrument). The detection limit for these instruments is 0.001 milligrams per cubic meter (mg/m3). Instrument readings will be observed and recorded. If/when data is logged by the instrument, the logs will be transferred to electronic files. Concentrations will be measured for a 1-minute sample interval at each perimeter monitoring location and within the site at work areas and the average measurements will be recorded. The result will be compared to the action level for particulates to assess air quality. Visible emissions of dust leaving the site will be evaluated and addressed regardless of instrument readings. 2.2 Real -Time Action Levels There is no single set of ambient air quality rules or standard that apply to compounds of concern at MGP sites. The ambient air goals and action levels consider a combination of enforceable standards (e.g., National Ambient Air Quality Standards; NC Section .0400 Ambient Air Quality Standards) and non -enforceable guidelines (e.g., risk -based and various adopted state guidelines), which provide concentrations below which unacceptable risk is not expected for the general public. The real-time action levels were set following established methods and are consistent with air quality action levels set for fugitive VOC and particulate emissions at other MGP remediation projects. The most generally accepted protective real-time action level, which has been adopted by a number of states, is 1,000 ppb (1 ppm) for VOCs (Wisconsin DHS: MGP Air Guidance, NY DEC Manufactured Gas Plants Program)and the NAAQS PM10 standard of 150 pg/m3 for particulates. NC's particulate standard is also 150 pg/m3 (15A NCAC 02D .0403). Table 1. Real Time Monitoring Frequency Action Minimum 8 Monitoring Intervention if Action Contaminant Locations Level Reached/ Level Instrument Three Times Exceeded per Day Evaluate and take VOCs 1,000 ppb 24 Observations ppbRAE immediate corrective action per Day to minimize fugitive emissions. TSI Dust Trak II Evaluate and take Particulates 150 tag/m3 24 Observations Aerosol Monitor immediate corrective action per Day to minimize fugitive (or equivalent) emissions. 2.2.1 VOCs For VOCs, including benzene and other contaminants of concern, there are no enforceable standards upon which to establish action levels, so project -specific air quality objectives are set considering MGP waste characteristics, EPA risk -based exposure guidelines and the practical capability of field screening and analytical instruments. Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 6 As outlined as outlined above, the most common accepted protective real-time action level is 1,000 ppb (1 ppm) for fugitive VOCs at MGP cleanup sites and other response actions. Benzene is the most restrictive VOC at MGP sites and is used as the sentinel compound for VOCs. As a check on the protectiveness of the perimeter 1,000 ppb real-time VOC action level, we calculated hypothetical acceptable offsite ambient levels assuming 4 months of exposure occurring 8 hours per day to both benzene and naphthalene. This resulted in hypothetical acceptable ambient levels of 106.5 ppb for benzene and 14.9 and 11.9 ppb for naphthalene (see Table 2 and 3). The real-time action level at the site perimeter of 1,000 ppb total VOCs is expected to be protective and ensure the exposure to the ambient levels presented above would not occur. The rationale for why the perimeter 1,000 ppb action level would be protective is as follows: • Fugitive emissions are expected only intermittently and not expected to result in unacceptable long emission events or elevated ambient contaminant levels lasting more than one hour.. • The real-time action level is for a short, one -minute duration versus longer term exposure which is expected to be at lower concentrations • Only a fraction of the total VOCs will be benzene, the contaminant of most concern, and an even smaller fraction will be naphthalene due to is relatively low vapor pressure • Attenuation will occur between the site perimeter and offsite receptors. 2.2.2 Particulates For particulates emissions, it is common and customary to utilize the NAAQS for total PM10 and that is the action level adopted here. The NAAQS 24-hour average concentration of 150 pg/m3 for PM10 will be used as the project air quality objective for particulates. NC's particulate standard is also 150 pg/m3 (15A NCAC 02D .0403). This particulate action level has been used at a number of MGP cleanup sites, it is both a NC state and federal standard and is the generally -accepted particulate monitoring level used. 2.3 Real -Time Monitoring Frequency & Locations Real-time monitoring will be conducted no less than three times per day when there are construction activities underway with the potential to result in fugitive emissions or odors. Once at the onset of work, mid -day and approximately one hour before completion of work. Real-time monitoring would also be conducted when site conditions change or new activities are started where fugitive emissions may occur. Real-time monitoring would be done in conjunction with nuisance odor assessments. Real-time ambient air quality monitoring for particulates and volatile organic compounds (VOCs) will be performed at the site perimeter at eight locations (Figure 6) and within the site at the location of activities (i.e., ground disturbance) which could result in fugitive emissions or odors to help ensure acceptable air quality conditions.. An Air Monitoring Data Form will be used to record measured concentrations from the dust monitor and photoionization detector (PID) (see attached). Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 7 3 TIME -INTEGRATED AIR QUALITY MONITORING In addition to real-time monitoring, time -integrated air quality monitoring will be conducted to establish baseline air quality conditions for specific contaminants and done at least monthly on a confirmatory basis to help demonstrate ongoing acceptable air quality conditions. 3.1 Pre -Construction Air Quality Monitoring The objective of pre -construction baseline air sampling is to document typical air quality prior to the start of site work that includes ground disturbance. The sampling data will be used to compare air quality data with air quality conditions measured during active construction activities that include ground disturbance and contact with residual MGP-impacted materials. Samples will be collected with SUMMA canasters and analyzed for TO-15 analytes, including for BTEX and naphthalene, chlorinated VOCs (PCE and daughter products), other known VOC site contaminants, and particulate matter. The samples will be collected at the four locations shown on Figure 6 at breathing zone height, for a duration of 8 hours during the day, the length of the typical work shift. Site conditions at the time of sampling will be documented (including photos). 3.2 Confirmatory Air Quality Testing The first sampling event will occur at the start of work that includes ground disturbance for the stormwater culvert construction. Thereafter, monitoring will occur on a monthly basis, at a minimum, with confirmatory air samples for TO-15 analytes, for BTEX and naphthalene, chlorinated VOCs (PCE and daughter products), other known VOC site contaminants, and particulate matter will be collected once site works gets underway. The confirmatory samples will be collected from the downwind location of a suspected emission source or the location that is likely to have the highest concentration of airborne contaminants. The samples will be collected at breathing zone height, for a duration of 8 hours during the day, the length of the typical work shift. Site conditions at the time of sampling will be documented (including photos). We will also conduct a TO-15 sampling during the first odor causing event with concurrent ambient air screening to get an understanding of what compounds are present in the air compared to the real-time screening results. This information may result in the need to revise any approved action levels. Sampling may be conducted elsewhere included offsite to evaluate possible ambient levels of contaminants. Additional sampling would be conducted in close coordination with DEQ. 3.3 Monitoring Using SUMMA Canister Samples Time -weighted ambient air sampling will be conducted for VOCs using EPA Method TO-15 from SUMMA canisters samples (EPA 1999b). Note that naphthalene can be analyzed with the TO-15 method and will be requested. Samples for VOCs will be collected using laboratory certified, 6.0- liter SUMMA canisters and flow controllers. Sampling and laboratory analysis will be completed in accordance with accordance with DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance Document (March 2018).and ITRC guidance documents Per DEQ VI Guidance, Summa canisters that have lost greater than 10% of the initial recorded lab vacuum when received in the field will not be used for sampling. It is assumed that Summa Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 8 canisters are issued with a maximum achievable pressure of 30" Hg. If canisters are received in the field with less than 27" Hg, initial lab pressure measurements will be documented to confirm less than a 10% volume loss or a replacement summa canister obtained. Otherwise, sample results may be rejected. We will indicate a targeted final vacuum reading of at least -5" Hg. Note if the vacuum measurement is less than this, sample acceptance will be in jeopardy and DEQ Brownfields may request a resample. Real-time monitoring and odor assessment will be conducted when time - weighted sampling occurs 3.4 Particle Monitoring Monitoring for particulates will employ a combination of real-time techniques for making action level decisions and time weighted techniques to verify compliance with NAAQS. Monitoring will use Federal Reference Method (FRPS) 1287-065 or equivalent (U.S. EPA 2003c) for PM10 for construction -phase activities with a 1 mg/m3 action level. Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 9 4 ODOR ASSESSMENT & MANAGEMENT 4.1 Objectives Checking for odors and preventing nuisances odors will be a key issue during all work and operations with the potential of handling or disturbing MGP-impacted material. Regular assessment of odors will be conducted, concurrently with the other real-time monitoring for VOCs and particulate. To avoid olfactory fatigue, personnel conducting odor assessments will not work directly in areas where fugitive emissions and odors could be present for at least an hour before conducting the assessment. 4.2 Odor Assessment Frequency and Locations Odor assessment observations will be made at least three times during the workday or more frequently, if needed. The assessor making olfactory (smell) observations at locations will include along the perimeter of the Site at the eight locations shown on Figure 6 and may be expanded elsewhere onsite and offsite (along public right-of-way and roads). Any additional locations surveyed by the team will be noted on the Odor Assessment Form provided in the appendices. 4.3 Odor Classification We will be using a four -level classification of possible odor situations and observations that will be used to trigger odor control response actions: • Level 0 — Nominal odors may be present onsite, but odor is not detectable off -site, or very minimal and very infrequent. • Level 1 — On and off -site odors are present, but the odors are not strong, not steady, and there is minimal potential for impact to the community, or the odors are not noticed by the community. This is an indication that odor control measures at the Site are adequate. • Level 2 - Odors are stronger than a "1" and relatively steady, particularly onsite. The community is not necessarily aware of the odors, but community recognition may occur, and additional odor control measures must be immediately implemented. A follow-up reassessment of possible odors will be conducted after implementation of odor control measures. • Level 3 - Odors are very strong and the community is aware of and reacting to the odors. Odor -generating activities must cease, and full odor control measures implemented. The situation must be re-evaluated prior to re -initiating work activities. Level 3 odors will trigger TO-15 sampling. Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP // Page 10 5 ODOR AND FUGITIVE EMISSION CONTROLS Control of odors and fugitive emissions is a key issue for site work and for all operations that include ground disturbance and possible exposure or handling of MGP-impacted material. All contractors performing excavation and activities that involve ground disturbance will aggressively control odors and fugitive emissions. Best management practices will include: • Stockpiled impacted material will be covered in accordance with EMP. • Odors and fugitive emissions will be controlled by minimizing the excavation areas and open faces • Covering the excavation working faces with clean fill, plastic sheeting and other measures as needed • Applying VOC and odor -control foams/suppression to the exposed excavations if there is the potential for odors or fugitive emissions. The VOC/odor-control foam selected for the project site is a product supplied by ATMOS. Use of the foam, when needed, provides immediate emissions control by stopping VOC volatilization. The foaming materials are safe, non -toxic and has been approved and used for odor control at MGP sites, brownfields sites, landfills and cleanup sites by state environmental agencies and the USEPA. The foam's safety data sheet and certification that the material does not contain PFAS are attached. Inspections of best mgmt practices/controls will be conducted by the environmental professional (Mr. Hill or his designee) weekly during soil disturbance and more often if odors or action levels are reported. Odor and Air Quality Management Plan November 4, 2021 Raleigh MGP 11 Page 11 6 REPORTING 6.1 Field logs Field logs will be maintained throughout the project to accumulate site conditions on a daily basis that have or may have an effect on Site air quality conditions. Information to be recorded in the field logbook will include: • description of site activities; • weather conditions; • general real-time perimeter monitoring observations; • action levels exceedances; and • emission abatement measures implemented in response to action level exceedances. The data recorded in the field logs will be supplemented by data recorded on specific real-time and time -integrated field data sheets. 6.2 Real -Time Monitoring Data The real-time air monitoring data will be recorded on the field data sheets and stored in an electronic database. Field data including measured concentrations recorded during perimeter air monitoring rounds, calibration records, maintenance, sampling irregularities, and repairs will be recorded on data sheets and compiled in the field logbook for the real-time air monitoring. The real-time sampling results will be routinely reported to the site manager to allow prompt evaluation and response to potential emission problems when action levels have been approached or exceeded. 6.3 Time -Integrated Sampling Data Field data, including equipment calibration, sample identification; equipment maintenance, sampling irregularities, and shipments will be recorded on the time -integrated sampling field data sheets and compiled in the spreadsheet where field log data will be summarized. A set of field logbooks will be maintained for the time -integrated sampling network to log daily information of the nature described above, pertinent to documenting the time -integrated sampling program. Preliminary results will be reported to the site manager to assess potential air quality concerns due to site activities. The accumulated time -integrated results, field data, and comparison to the project air quality standards will be presented in the Ambient Air Monitoring Report upon the conclusion of the remediation project. 6.4 Notification and Reporting 48-hour notification (via email) will be provided to DEQ in the event of action level exceedances and odors at level 3. Notification will include copies of field log forms and other pertinent information. Lab data with summary tables will be provided to DEQ if detected ambient air levels exceed residential screening levels within 10 days of receipt of data from the lab Monthly summary reports will be prepared and provided to DEQ. Longer -term reporting will be included with regular EMP updates and reports provided to DEQ. Aptus Management, PLLC Environmental Management Solutions FIGURES Aptus Management, PLLC Aptus Management, PLLC Environmental Management Solutions FIGURE 1 SITE LOCATION MAP Aptus Management, PLLC CEDW Figure 1 Site Location Map 2 KILGOR Ur- WILL1ANSW ,J Oberlin Bus. - �j \ _ t- ^ � i .Whitaker / �5vL ors _ Park /f 01�� - J LT i �CAMER NEST PARK DR �+�- `— { _ �J . W' EACEST, Cameron Park STD (� ED NTON ST 3 Ol t r Q 54 W'M RGAN ST } Bus rTF ✓ BLVD-4-\ 70 \ ! Boylan Heighfu J, , CABA RUS STD TFr,� Cr This report includes information from the following map sheet(s). 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BENCHMARK BY �} \ + MEASURED98 98.42 .50 r VC sy / N /F \ kl,Q�q��1 \ �I JTH HOLDINGS, LLC, ETAL. +� 6��, Leo \ PIN:1703473624 �f O + \ \SS D.B. 13295, PG. 423 o�ti +� - D 9�OTAl B.M. 2016, PG. 800 � \O + 69 �j /Qj CD \ A ,o76 � C �� A, �.' 0� e _o ��l o ^� �cl C s GATE iS N/F 62 SS1 CNTRL � � `S6• \ +\ JTH HOLDINGS, LLC, ETAL. \ ° �- �_ ��59. _DELINEATED 4 PIN:1703472505 r- / F VVETLAf4DS- D.B. 13295, PG. 423 y B.M. 2016, PG. 800 �o�/ �QOi tii ST 700, \ >t ABANDONED RIGHT OF WAY NOTE: EXISTING RIGHT-OF-WAY CLOSED BY QUITCLAIM DEED THAT WAS APPROVED BY THE BOARD OF COMMISSIONERS OF THE CITY OF RALEIGH ON FEBRUARY 17, 1943 AND RECORDED IN DEED BOOK 891, PAGE 372. \INV NAD GRID (NAD83 2011) _ m \ i _ REBARtJ\ \ E \ / SyFo ON LINE /� fINN + N/F y O HW15 �+ BAYSIX PROPERTIES, LLC. ti �� / W / 'CO / \ PIN:1703471498 I / q�C + D.B. 15535, PG. 101 / / / - / / / S B.M. 1920, PG. 40�� ASHALT _ ��s_-_ °1 / -\,�+ V.�HAL x- _x�x - - - - xV -/ _- U 39�; x�x,�x�x_ / \x °� l l �k 300.70 D114two / ASHALT \ O / GAZEBO I �� / + RIG CB1 x \ �\ I / \+yTO TOP=295.94 2 11 �` 15 RCP(S)=293.44 O�o / \ CB2 BAYSIX PROPERTIES, LLC. \ / PARCEL 1 / / / / \+ TOP=295.80 PIN:1703471498 _, a x / 3119 ASSOCIATES, LLC D.B. 15535, PG. 101 h m PIN:1703475257 / / / / 15"RCP(N)=293.10 B.M. 1920, PG. 40 �� a °� +� 18"RCP(SE)=291.91 o \ 516 W. CABARRUS ST. / O " 64 x \� + �� D.B. 16261, PG. 1201 / PARCEL 3 ONE STORY / // i / C83 ° 1� BRICK �oJ \ B.M. 1970, PG. 108 / / 8,947 SQ.FT./ m x ,� 205,793 SQ.FT. SHED 0.21 AC. �, 18" RCP(NW) 287.70 °moo I 4.72 AC. / EIP ON o 18"RCP(S)=287.78 c - h P.O.B. LINE Iml - - PARCEL 3 24" RCP/ ` CB4 I m c` = _ S 87'35'53 E� / �4 1 TOP=288.89 i - _ - 256.22'(TOTAL)-x >K IN X 298 51 / °x -- - - - - - --_ x- 18"RCP(N)=285.48 36.6' - 182.36' = _ _ _- - - � � � / 18"RCP(S)=285.47 \ I \ ONE STORY \ I - TOP /Qg � x � / 24' RCP \ � p,2� � TWO STORY 3•3� � METAL AND i o � � INV�283.39 �, � � TOP=286.58 NT ° 7 - SS9 BRICK L3 BLOCK I 18"RCP N 283.16 THE JOSEPH I LEE REVOCABLE TRUST c i L� O x -= ❑E 319.71 J m ° I 18"RCP(S)=282.48 ' 00 ( ) PIN:1703471260 , _ D.B. 16447, PG. 2091 ,' 1 ' o' a 10 ��� i c / `� � oo N 9 N `t DO 9 CB6 B.M. 1920, PG. 40 / - - \ x 157 RCP Ccg / CLANCY P � COVERED COULD PROPERTIES LLC ✓ m - _ �es I V=284.15 os/ PIN: 1703477144 z LD w o- � °� NOT ACCESS T es� I D120 J 518 W. CABARRUS ST. wIN f u`' o o o a; `' ao ASHALT // / ACCESS / D113 T / W wIATCH / D.B. 8440, PG. 1968 Q (� vi N ° TOP=282.54 w o o Zg5 / ASHALT / �^ - - ) B.M. 1999, PG. 2218 w . / z O ao , F' � o N - o N I / `� 1 o 0 - o ,n 00 18 RCP(N)-279.84 \�__S %-�N(jC� I 1 �7' 18 471, F � W J - I 42(G -� zoQ��N I ° Rlp� P.O.C. NCGS MONUMENT "GIBBONS" PID: EZ6435 V / I-S ix_ Uj Of m ro NAD83(2011) OBSERVED 12 41'08., o I N:738,799.82 V 4j20 �F PUBLLISHED6COMBINED is (GRO N0�19�0 'GRIp� 1 FACTOR:0.99990336 NCGS MONUMENT "PULLEN" PID: EZ6436 NAD83(2011) OBSERVED _j PROPERTY LINE TABLE LINE I BEARING DISTANCE L1 N 04'04'58" W 57.64' L2 N 87'58'45" W 57.03' L3 N 87.50'19" W 15.52' L4 N 02'28'05" E 29.71' 18 / 'o) O\ 1 / i N z a m O W L) �0 18"RCP(E)=279.84 �I i UTILITY STATION AND �/ -I AREA EXCLUDED FROM / `� w Q 9 I o < 0° m Li PIPELINE EASEMENT i `;> / C/ONCRETE °O z O Y rn o' CB8 �7/ 9 BROWNFIELD � � � � i ���t iv D.B. 14367, PG. 1279 / O B.M. 2011, PG. 1133 21 ® I� I I / /� 00 it TWO STORY O °x 0 TOP=282.32 METAL AND V) ° 18"RCP(E)=279.47 o x� _ / i / / I I PARCEL 2 BLOCK 6r�- CO m �I 18"RCP(W)=279.62 GAS FARM / / ON PROP. LINE O ®� I 50,148 SQ.FT. © °CU1 CB9 o � x / / D121 i / 1.15 AC. // z�� 332.57 CB18 I AREA NOT / I i / / 2 -- TOP=281.32 z ACCESSIBLE OF AT / / �� 13 �� °� '1 / / / I I t L2 B16 ° so 24"RCP(E)=275.89 SURVEY i / j � ° 18"RCP(W) 277.68 - - P.0.6. � `� ® / � /' PARCEL 1 C�1 � TOP=281.56 } SS4 'SHUT - - g• N:738,465.17 I - PFF - - p O.B. TWO STORY OVER 5'X5' CON. CULVERT E:2,099,766.01 JB7 335.13' / - = PARCEL 2 BRICK 322.23 INV. CULVERT=268.22 PUBLISHED COMBINED � - -REBAR '4- 24"RCP(W)=275.71 FACTOR:0.99990485 SS2 �c CB8 CB9 CB10 / / N 87'16'53" W _ 296.72 o GENERAL NOTES 1. THIS IS A SURVEY OF AN EXISTING PARCEL(S) OF LAND. THIS IS A ALTA/NSPS LAND TITLE SURVEY. 2. BEARINGS FOR THIS SURVEY ARE BASED ON NC GRID NAD 83. 3. ALL DISTANCES ARE HORIZONTAL GROUND DISTANCES. 4. ZONING: IX-7-UL PER WAKE COUNTY GIS; NO ZONING REPORT PROVIDED 5. AREA BY COORDINATE GEOMETRY. 6. FLOOD NOTE: THIS PROPERTY IS NOT LOCATED IN A SPECIAL FLOOD HAZARD ZONE. IT IS LOCATED IN ZONE "X" AS DEFINED BY F.E.M.A F.I.R.M COMMUNITY PANEL #3720170300J DATED MAY 5, 2006. 7. REFERENCES: AS SHOWN 8. UTILITY STATEMENT THE UNDERGROUND UTILITIES SHOWN HAVE BEEN LOCATED FROM FIELD SURVEY INFORMATION AND EXISTING DRAWINGS. THE SURVEYOR MAKES NO GUARANTEE THAT THE UNDERGROUND UTILITIES SHOWN COMPRISE ALL SUCH UTILITIES IN THE AREA, EITHER IN SERVICE OR ABANDONED. THE SURVEYOR FURTHER DOES NOT WARRANT THAT THE UNDERGROUND UTILITIES SHOWN ARE IN THE EXACT LOCATION INDICATED ALTHOUGH HE DOES CERTIFY THAT THEY ARE LOCATED AS ACCURATELY AS POSSIBLE FROM INFORMATION AVAILABLE. THE SURVEYOR HAS NOT PHYSICALLY LOCATED THE UNDERGROUND UTILITIES. 9. NO GRID MONUMENTS FOUND WITHIN 2000' OF SITE. 10. ELEVATIONS FOR THIS SURVEY ARE BASED ON NAVD 88 11. THE NORTHERN PROPERTY LINE OF PARCEL 11S THE SAME AS THE SOUTHERN RIGHT OF WAY OF THE NORTH CAROLINA RAILROAD COMPANY AS SHOWN ON B.M. 2016, PG, 868-870 OF THE WAKE COUNTY REGISTRY OF DEEDS. 12. FENCE, SHED, AND MATERIAL STORAGE BAYS ENCROACH INTO THE NORTH CAROLINA RAILROAD RIGHT OF WAY AS SHOWN _ 631.85'(TOTAL) _ �� ° _ CB11 ss � SS3 i ' / / , / � � � / TOP=281.31 ss ss ass - sso ° �ss W. CABARR V .7 s, S 5 / / / oZ / / / / / / 0 60' PUBLIC R/W s / -'-c - w , / / i COULD NOT ACCESS �- ou CB11 °`� 12- B.M. 1999, PG. 2218 V �` ° ss -�- \ \ �V _� ss� ss �'��_ ss 3 S6 C - - - c - CB12 \ �� \ ��ss ss' TOP=281.40 �ou �� V A \ V �� A A \ \ ` \ \ \ / \ / S7 OVER 5'X5' CON. CULVERT ss�- INV. CULVERT=268.06 60 R / �� / / / / ou V D113 ° / / / / _ GRATE=282.71 INV�2r��.8�F �� J �� )�/ / I OVER 5'X5' CON. CULVERT 60" CID/ / / / I ° INV. CULVERT=270.51 i /l cNV-11=267.9d' //�// D114 GRATE=286.02 / �/ 20',/ CMP(VERfICAL) / o I 12"DIP(E)=282.62 IN/V 278.77' / I HW15 5'X5' CON. CULVERT INV. CULVERT=281.81 CB16 TOP=305.56 8"TCP(N)=303.61 J 4"TCP(S)=304.46 / � � � PROPERTY LINE / 7TOP=306.51/� / 4"TCP(N)=304.61 FOLLOW CL OF CREED, LINES SHOWN FOR �� �i�//o° / CB18 REFERENCE x TOP=306.79 �4�,7,'�i%� l 18"RCP(SE)=304.04 � � i/ x ��� D119 / W - �/ /�// x / GRATE=309.04 24"RCP(NW)=301.14 ('V� �� / D120 GRATE=290.41 15"RCP(NW)=286.99 Q / P4Q�•- Q<v D121 GRATE=287.25 '//°\ \ COULD NOT ACCESS /3 �� lI 70.04' 1 SS1 s \s \, no f- T S1 kss - ss§ -x I 1 -7 PLAYGROUND 60" RCP INV=264.9 � TO CABARRUS LLC, A NORTH CAROLINA LIMITED LIABILITY COMPANY, FIRST AMERICAN TITLE INSURANCE COMPANY: THIS IS TO CERTIFY THAT THIS MAP OR PLAT AND THE SURVEY ON WHICH IT IS BASED WERE MADE IN ACCORDANCE WITH THE 2016 MINIMUM STANDARD DETAIL REQUIREMENTS FOR ALTA/NSPS LAND TITLE SURVEYS, JOINTLY ESTABLISHED AND ADOPTED BY ALTA AND NSPS, AND INCLUDES ITEMS 1, 2, 3, 4, 5, 6(A)(8), 7(A)(B1)(C), 8, 9, 11, 13, 14, 16, 17, 19, 20 & 21 OF TABLE A THEREOF. THE FIELD WORK WAS COMPLETED ON OCTOBER 17, 2017. DATE OF PLAT OR MAP: NOVEMBER 6, 2017 RONALD T. FREDERICK, P.L.S. L-4720 DATE ���.•`�N CARp*''.,� PRELIMINARY PLAT FN ESSNOT i00 1��, CONVEYOAN ESC ORDATSALOES SEAL c L-4720 ,'0'•, �' ••':� SUR`I�, • �� �•�• .,,��a •r .. LEGEND ass QQ EXISTING IRON PIPE O IRON PIPE SET QS SANITARY SEWER MANHOLE © SANITARY SEWER CLEANOUT WV N WATER VALVE ® WATER METER FIRE HYDRANT QT TELEPHONE MANHOLE LIGHT POLE Wi CURB INLET QD STORM DRAINAGE MANHOLE ❑ YARD INLET D GUY WIRE ❑T TELEPHONE PEDESTAL O BOLLARD GAS TEST STATION © ELECTRICAL TRANSFORMER Ac AIR CONDITIONER HANDICAP SPACE SIGN CO-) POWER POLE 0 ELECTRICAL BOX ® MONITORING WELL SD STORM DRAIN PIPE OU OVERHEAD UTILITY LINES W WATER LINE SS SANITARY SEWER LINE SS1 T TELEPHONE LINE RIM=293.83 8"TCP(S)=285.74 G GAS LINE 8"TCP(NW)=286.16 UE UNDERGROUND ELECTRIC SS2 RIM=283.08 UT UNDERGROUND TELEPHONE 8"TCP(N)=277.27 8"TCP(E)=277.26 -X X- FENCE LINE 4"PVC(S)=278.53 - - RIGHT OF WAY 8"TCP(W)=277.17 SS3 ® PARKING COUNT RIM=282.04 12"TCP(N)=270.35 ® RIP RAP 8"PVC(E)=274.48 12"TCP(S)=270.33 310 OAK 8"TCP(W)=274.40 SS4 P.O.B. POINT OF BEGINNING RIM=281.67 P.O.C. POINT OF COMMENCEMENT 12"TCP(N)=271.06 12"TCP(S)=270.92 GRAPHIC SCALE SS5 0 25 50 100 RIM=289.16 8"TCP(E)=283.80 8"TCP(S)=283.38 1 inch = 50 ft. 8"PVC(W)=283.15 SS6 RIM=310.99 SITE PERMIT REVIEW APPROVAL 8"TCP(W)=305.30 SS7 CITY OF RALEIGH - PLANS AUTHORIZED FOR CONSTRUCTION RIM=312.83 8"TCP(E)=309.86 Plans for the proposed use have been reviewed for general compliance with 8"TCP(S)=310.20 applicable codes. This limited review, and authorization for construction is not to be considered to represent total compliance with all legal requirements for SS8 development and construction. The property owner, design consultants, and RIM=291.46 PUMP STATION contractors are each responsible for compliance with all applicable City, State and Federal laws. This specific authorization below is not a permit, nor shall it be SS9 RIM=292.16 construed to permit any violation of City, State or Federal Law. All Construction GREASE TRAP must be in accordance with all Local, State, and Federal Rules and Regulations. ELECTRONIC APPROVAL: THIS APPROVAL IS BEING ISSUED ELECTRONICALLY. THIS APPROVAL IS VALID ONLY UPON THE SIGNATURE OF A CITY OF RALEIGH REVIEW OFFICER BELOW. THIS CITY WILL RETAIN A COPY OF THE APPROVED PLANS. ANY WORK AUTHORIZED BY THIS APPROVAL MUST PROCEED IN ACCORDANCE WITH THE PLANS KEPT ON FILE WITH THE CITY. THIS ELECTRONIC APPROVAL MAY NOT BE EDITED ONCE ISSUED. ANY MODIFICATIONS TO THIS APPROVAL ONCE ISSUED WILL INVALIDATE THIS APPROVAL. CITY OF RALEIGH DEVELOPMENT APPROVAL ALL CONSTRUCTION SHALL CONFORM WITH THE LATEST VERSION OF THE CITY OF CITY OF RALEIGH REVIEW OFFICER RALEIGH, SPECIFICATIONS AND DETAILS. FINAL DRAWING - NOT RELEASED FOR CONSTRUCTION 'J McADAMS The John R. McAdams Company, Inc. One Glenwood Avenue Suite 201 Raleigh, NC 27603 phone 919. 823. 4300 fax 919. 361. 2269 license number: C-0293, C-187 www.mcadamsco.com CLIENT KANE REALTY CORPORATION 4321 LASSITER AT NORTH HILLS AVE SUITE 250 RALEIGH, NC 27609 REALTY CORPORATION H W W H N LU z I..L.I Q U c � O Q G � z LU(D = a�w V�Q ac W REVISIONS NO. DATE REVISION DESCRIPTION 1 PLAN INFORMATION PROJECT NO FILENAME CHECKED BY DRAWN BY SCALE DATE SHEET KAN-17030 01. 05. 2021 EXISTING CONDITIONS C1600 Aptus Management, PLLC Environmental Management Solutions FIGURE 3 BROWNFIELDS SURVEY PLAT Aptus Management, PLLC �rdd�F r hp,,wcq-qe +Eabm u1�Oya GrsJNb+7Jsrrp £arc rdvxnsrEYq ;OR DATA AY1AYl JROY>0®dTJAlC M, urEAnt�AWCL& wrre£ LPrAaasR+wcn� T1 XESIMTJOFJAOP L 'r� AT j\ / RF W J. MNE5 $0. 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FO`J REGGZTER OF DEEM FDEE uw n e GRAPHIC SCALE trJ WAKE COGxrr sa BY: Rom: .a.+xw ra5G' M TIM 1 13 RECORDED IN BOOK OF MAPS PAGE � �uryrun5unr Fwlwlww�wsfJerol.es-ux Jre Aptus Management, PLLC Environmental Management Solutions FIGURE 4 KNOWN RESIDUAL CONTAMINATION IN RELATION TO THE EXISTING AND PROPOSED STORMWATER CULVERTS AND OTHER SITE FEATURES Aptus Management, PLLC [ Ano fvc-. Y R9CN35Y. \\\ mLVIE ro m wow•Ea S LagTl:n, L9CATIW R IF NCT TH W 'nm[3Fr ALREIE tlR+E--` - � f£i'05f2 1 eE Lax�enm m EE CNOxIb H.W j ` LLC A6 olc, J I � Jtti �•v / '7 4 � 2Samples -NO Hits \\ \\ Existing Storm Drainage Soil Sample Data Summary E o v _ m a = a E MWH-SW-02 3 10 100 97 88 29 36 93 IS 28 5 310 807 MWH-SW-02 3 3 10 6 19 7 5 2 7 6 65 C-SW-14 VC 4 5 4 4 1.4 18 SB-23 3 1 1 2 2 3 C-CULSW-2 VC 10 9.5 3.4 7 3 3 11 ]3 75 C-CULSW-1 VC 2 25 19 22 IS IB 26 4 19 6 31 1117 B-GHSW-9 VC U1 14 18 10 17 17 12 110 .amp a col leered Hbo�e water Table a \ DTW: 7' i j 31 4 6E1 i� RFIgR➢ ? iFr.vasr In 1 it i • ; No Sample Data. But 2 Sam les<20 m I 12/20/19 Geotechnical P pp Report Indicates 17 I Chemical/Petroleum Odors ■ g�}� rom Surface to 22/ bls. \ Ei mi. v<' \ 3�7 P1ucE raEu* E'r' cwa'Ei �1 77 ' f-l� • 111 a1¢ `t.•� ,{,$ � 9¢ m £ Raxrlm 1 �� �3�+aw �911E IIcr % x �'n' !�'. PiY4AM IlE �Il£ 1'3 man cw E�- \ J I 1 FE"CE Ta eE ,d 1K Rauh I o"Ec� wilul I I � na m l 3CAC ESa: - i JI +I iA32 SHEET ram(} I� nh1E3 � � �•�- � ��.�M�Yrr���` n ell $ T a £.7➢ �' = A,.. s• A I I P eeP 95.ppEf [6ninElE To n£ la - cf„]r ,tRwmER u�a.En � SR 1 J i 'rsE`�un m`G °F:w� l n�n•.I x,1T P.wxwc � I i `mT�e � f' 4 E-11C BC]E9 IF HOT 1P. -y Lar tt1 BE RdIXFD 1 I p n[[ wlxwx Fi➢ £ au'rtn+ /; 94£T L600 A F - I alLRS m EE ` I nFMx,E� IEPPCRVH IS- i r � v�•2GGkxhIRT" _ r' ���:� SV FF!<LE DTW: 9' $ o..d ''LL J r�o10Ex 1�{, ��Iio- v I �• =� Ir / n - _ L I' Impacted Soil at Storm Drainages Figure 4 APTUS Management, PLLC Environmental Management Solutions r dGn[ 6FIMN' To �• Proposed Storm Culvert Soil Sample Data Summary E a - - $ z n g f i W-1 VC 2 26 9 4 2.5 4 24 17 8 3 170 MO 200 170 892 C-SW-2 VC 37 43 13 6 5 6 32 3 9 7 30 3 3 120 317 C-SW-4 VC 9 35 17 18 10 11 28 9 IS IB 13 390 720 3100 110 4506 C-SW-5 VC 110 41 9 5 4 5 29 3 22 13 5 220 300 2W 190 1162 Vc 130 91 24 22 12 1111 6 6 15 31 28 14 . 606 VM-SW-02 52 39 31 17 39 110 390 300 978 ] Sample Collected Above Weer Te EL m le rolleaed underwa�rra Hmmr m Basemap Source: McAdams Company Site Permit Review C6.02 West Cabarrus Street Redevelopment Project Raleigh, North Carolina NCBF# 13022-09-92 Aptus Management, PLLC Environmental Management Solutions FIGURE 5 EXTENT OF THE MGP CLEANUP AND AREAS OF CLEAN FILL AND BROWNFIELDS SITE BOUNDARIES ESTABLISHED BY RECOMBINATION Aptus Management, PLLC \ \ \ I I I N/F JTH HOLDINGS LLC \ \ \ MCW HOLDINGS LLC \\ EXISTING JOINT \ I 1 PIN: 1703473624 DRIVEWAY EASEMENT \ I DB. 13295 PG. 0423 \ \ I I 0' PARKING AND BUILDING SETBACK N/F \ I 1 JTH HOLDINGS LLC / \ S55'59'48"E \ I MCW HOLDINGS LLC \ �243.03' \ PIN: 1703472505 EXISTING \ DB. 13295 PG. 0423 PROPERTY LINE S, \ I I \eCP rn \ N/F / 0' PARKING AND INC RAILROAD COMPANY i BUILDING SETBACK PIN: 1703575658 I \ 11 DB. 00021 PG. 0374 I \ I I I I I I i / N/F BAYSIX PROPERTIES LLC / PIN: 1703471498 / DB. 15535 PG. 0101 — 7— EXISTING PROPOSED `�\ \ PROPERTY LINE /----RIGHT OF WAYco ) \ / \ 22 EXISTING M N LOT 1 ' DUPONT CIRCLE Z/M 4.06AC. / (PROPOSED 73' PUBLIC R/W) / PROPOSED PROPERTY LINE ` / N/F PROPOSED NEGATIVE rn BAYSIX PROPERTIES LLC I I EASEMENT TO TIE \`Ln�N PIN: 1703472301 I / I I I BACK TO EXISTING N J DB. 15535 PG. 0106 i PROPERTY LINE LOT 2 w S873. 86' ' "E _ I 73. F I in . 50' PRIVATE STORM IIi 1.64 AC. P — — — — — — — — — 1 DRAINAGE EASEMENT , I N N I N / N/F Z 1 ss2' / JOHNSTON LEE FAMILY i I i —I N87'50'19 / PROPERTIES 5, LLC / I / PIN: 1703471260 DB. 17145 PG. 01425 / _ / i i I �/ INCRAILROAD COMPANY c.) T—T------_I ^�� EX. LOT 3 PIN: 1703570190 / 0 I u n I I I DB. 00038 PG. 0452 Cr l 0.21 AC. � I 000 l z �o olzo EXISTING UTILITY j I z 't / I I Ml"? STATION AND I 104 EXISTING vZi _Z ^� / a I N/F I Zl v PIPELINE EASEMENT S. WEST STREET Q o m IJOHNSTON LEE FAMILY I I PROPERTY I I EXISTING 60 PUBLIC R W apj PROPERTIES 5, LLC PRIVATE STORM � j PROPOSED I I I 9 PIN: 1703472102 S87.16'53' DRAINAGE I I LINE l I ( / ) I DB. 17145 PG. 01425 l 14.76' EASEMENT i I I EX. NEGATIVE SPACE EASEMENT I I D.B. 8481, PG.1412 I 57.03_ I I o f I i I N87'58'45"W Zo / I �I� r----------------- I I Zl� I / 5' UTILITY PLACEMENT VARIABLE WIDTH SIDEWALK i L — — I EASEMENT ACCESS EASEMENT 3 I I EX. RIGHT OF l _ �— _ I I EX. RIGHT OF WAY 64.97' o — — — — _ I WAY 3 �v N87'16'53"W N o — — — = a'. — S87'16'53"E _ — — — — _—I— — I— _ _ _ W. CABARRUSEXISTING � 310.65' --- --- ---1 �— � _� = � ,� �n T——= 256.15' ° 04 EXISTING - (Ex. 60' PUBLIC R/W) — _ _ — — — — _ - - - _ _ — - - - - - - N87' 16'53"W M ' SST CABARRUS—STREET EXISTING I - (�OPOSED 64 PUBLIC R/W) ------ — _ _ WEST IAA I]��R�S7� CA G _ _ _ RESET (EXISTING 60' P BLU IC R7Wj- - - / N/F PRIVATE STORM / // EASEMENT / BOYLAN CONDOMINIUMS / // / DRAINAGE PIN: 1703461995 DB. 11964 PG. 02315 / / / / I / W / / BUFFER; NEUSE RIVER / �/ / / I o / j MEASURED FROM ���' / L HNHARD� TERESA TOP OF BANK / g co Y v7 / // P0Y3463985 IN: 17 B. 1427,0 PG. 01984 I Z O oc / z C o u- _ EXISTING 20' / / \� >/ / I Q �M / m % NITSEWER / / \�`� / EASEMENT / / I N/F I / / I CABARRUS WEST 1 / / I ERTY LLC PIN1703467736P / / I DB. 16659 PG. 0125 I / N/F / N/F I I / GREEN, M H JR HEIRS / CABARRUS WEST I I / PIN:1703465932 / PIN: PROPERTY I I DB. 16659 PG. 0125 I I / I I GRAPHIC SCALE 0 20 40 80 N1 inch = 40 ft. I I FAIRWEATHERNPROPERTIE� LLC PIN: 1703560817 1 1 DB. 09539 PG. 0101 I I I I I I I 1 I I I L I I— — I ALL CONSTRUCTION SHALL CONFORM WITH THE LATEST VERSION OF THE CITY OF RALEIGH, SPECIFICATIONS AND DETAILS. SITE LEGEND PROPERTY LINE RIGHT-OF-WAY LINE LOT LINE EASEMENT LINE PEDESTRIAN ACCESS EASEMENT SITE PERMIT REVIEW APPROVAL CITY OF RALEIGH - PLANS AUTHORIZED FOR CONSTRUCTION Plans for the proposed use have been reviewed for general compliance with applicable codes. This limited review, and authorization for construction is not to be considered to represent total compliance with all legal requirements for development and construction. The property owner, design consultants, and contractors are each responsible for compliance with all applicable City, State and Federal laws. This specific authorization below is not a permit, nor shall it be construed to permit any violation of City, State or Federal Law. All Construction must be in accordance with all Local, State, and Federal Rules and Regulations. ELECTRONIC APPROVAL: THIS APPROVAL IS BEING ISSUED ELECTRONICALLY. THIS APPROVAL IS VALID ONLY UPON THE SIGNATURE OF A CITY OF RALEIGH REVIEW OFFICER BELOW. THIS CITY WILL RETAIN A COPY OF THE APPROVED PLANS. ANY WORK AUTHORIZED BY THIS APPROVAL MUST PROCEED IN ACCORDANCE WITH THE PLANS KEPT ON FILE WITH THE CITY. THIS ELECTRONIC APPROVAL MAY NOT BE EDITED ONCE ISSUED. ANY MODIFICATIONS TO THIS APPROVAL ONCE ISSUED WILL INVALIDATE THIS APPROVAL. CITY OF RALEIGH DEVELOPMENT APPROVAL CITY OF RALEIGH REVIEW OFFICER 'J McADAMS The John R. McAdams Company, Inc. One Glenwood Avenue Suite 201 Raleigh, INC 27603 phone 919. 823. 4300 fax 919. 361. 2269 license number: C-0293, C-187 www.mcadamsco.com CLIENT KANE REALTY CORPORATION 4321 LASSITER AT NORTH HILLS AVE SUITE 250 RALEIGH, INC 27609 REALTY CORPORATION W W LU z i O LLI CC U o � z LLILU 2 LLJ Q v 1 CARD, �.. '.� SSA._ � 0;5-55 REVISIONS NO. DATE REVISION DESCRIPTION 1 PLAN INFORMATION PROJECT NO. KAN-17030 FILENAME KAN17030-S3 CHECKED BY DRAWN BY SCALE 1"=40- DATE 01. 05. 2021 SHEET RECOMBINATION PLAN C so2 FINAL DRAWING - NOT RELEASED FOR CONSTRUCTION Aptus Management, PLLC Environmental Management Solutions FIGURE 6 AIR MONITORING LOCATIONS Aptus Management, PLLC \ X,3� _IN \ (EXISTING DUP NT CIRCLE EX. 4'PUBLIC R W 1 \ \ \\\ � \ 296 5 � EX 15" RCP I EX CB-2 RIM=295.80 I INV=293.10 \ INV=291.91 I IEX 18" RCP FI- I EEC 18" RCP I I� 1 �l EX CB 11 I TO NJBRTED/ 1 EX 18" RCP 1 III u, — EX CB L/_ — — — — CONVERTED �I I TO JB _J� l I I o EXISTING I I DUPONT CIRCLE / I II I (PROPOSED 73' PUBLIC R/W) I� EX 18" RCP 1 p� EX CB TO JB CONVERTED� II N oI ���-- / � e II I CB I oll _ L/ — J =I I 1y1 � k g4 EX 18" RCP I— ? x—x— I EXISTING UTILITY STATION AND I I I/ / PIPELINE EASEMENT I — / I I I " EX JB-2 EXISTING RIM=295.80 — W. CABARRUS ST I INV=293.10 I (EX. 60' PUBLIC R/W) I INV=291.91 —t— SS Ss-4 —1 <, — - SS __> SS — --- -w \ W W W o 2 ou _ 18" RCP Ir PRIVATE STORM DRAINAGE EASEMENT L-7 10'x6' BOX CULVERT r—j WALWS LL W/ (2) WING INV OUT=272.00 EXISTING 20' t� SANITARY SEWER EASEMENT (2) EXISTING 48" DIP STORM PIPES F1 _ J Y M0N11T0tz\1 orli ring, \ \ I 145 LF \ \ OF CLASS \ \ 1 RIPRAP \ \ �o0 12'x5' BOX \ \ \ \ CULVERT HEADWALL \ \ INV IN=282.00' \ \ p Aso TW=292.00 \ \ \ \ BW=282.00\Xy \ TW=292.0� BW=292.00 \\ I _� PERMANENT � JB / \ RETAINING WALL / (DESIGN BY OTHERS) / o 0 CI ITI IDF A GRADING LEGEND 0 FLARED END SECTION ENDWALL SECTION CATCH BASIN DROP INLET ■ STORM SERVICE INLET • STORM SERVICE ROOF —DRAIN O JUNCTION BOX �-► DRAINAGE FLOW ARROW .,� LINE BREAK SYMBOL 250.50 250.00 TOP & BOTTOM CURB ELEVATIONS \TW=223.00 TOP OF WALL ELEVATION BW=213.00 BOTTOM OF WALL ELEVATION (NOTE: BOTTOM OF WALL IS GROUND ELEVATION NOT WALL FOUNDATION) + 250.60 SPOT ELEVATION STORM DRAINAGE STORM SERVICE LINE RD RD RD ROOF DRAIN, 8" ADS NON —PERFORATED TUBING OR EQUAL 1.0% MIN. SLOPE 3' MIN. COVER PVC SCHEDULE 40 IN TRAFFIC AREAS TP TP TP TREE PROTECTION FENCE LD LD LIMITS OF DISTURBANCE WOODED AREA 250 MAJOR CONTOUR 252 MINOR CONTOUR 250 EXISTING MAJOR CONTOUR 252_______ EXISTING MINOR CONTOUR — — — — EASEMENT LINE FUTURE CITY OF RALEIGH BRIDGE PROJECT \ \ ANENT \ \ L TW=310.5 \ \ BW=292.00 \ \ TEMPORARY \ \ \ \ RETAINING WALL \ (DESIGN BY OTHERS) \ 1 TW=310.00 \ BW=310.00 ' \ \ TW=310.00 BW=310.00 TEMPORARY RETAINING WALL (DESIGN BY OTHERS) / EXISTING S. WEST STREET \ (PROPOSED 73' PUBLIC R/W) FUTURE CURB AND \ GUTTER LOCATION \ r \ — — — — — — — — — — — — / — „. — M — —M _ M EXISTING �o�+ll % WEST CABARRUS STREET I y I -- / I I (PROPOSED 64 PUBLIC R/W) I � / I - II I I GRAPHIC SCALE 0 20 40 80 1 inch = 40 ft. PRELIMINARY DRAWING - NOT RELEASED FOR CONSTRUCTION 'J M ADAMs The John R. McAdams Company, Inc. 2905 Meridian Parkway Durham, NC 27713 phone 919. 361. 5000 fax 919. 361. 2269 license number: C-0293 contact: Brian Purdy, RLA Purdy@mcadamsco.com CLIENT KANE REALTY CORPORATION 4321 LASSITER AT NORTH HILLS AVE SUITE 250 RALEIGH, NC 27609 REALTY CORPORATION W u■I z Q N w z V� ~ 0 � Q W U Q Q O Q Ln w vzJ C) LJ Q ��. N CAROB, �.. o Esc/' 0 4 J55 �'•��;� I NEF:•• of 111111" REVISIONS NO. DATE 1 01.02.2020 REVISED PER CITY OF RALEIGH COMMENTS PLAN INFORMATION PROJECT NO. KAN-17030 FILENAME KAN17030-G1 CHECKED BY LJV DRAWN BY JLB SCALE 1"=40' DATE 09. 30. 2019 SHEET GRADING &STORM DRAINAGE PLAN C goo Aptus Management, PLLC Environmental Management Solutions TABLES Aptus Management, PLLC Table 2 Benzene and Naphthalene Inhalation Action Level - Carcinogenic Risk 8-hour Per Day Exposure Raleigh MGP II Site Redevelopment - Raleigh, NC Relevant Equations CA = TRxAT EFxEDxL;R Where: CA is the nir concentration (urg/ui3) TR is the target incremental calker risk (diinensiontess) AT is the averaging time for carcinogenic effects (days) EF is the exposure frequency (days/yr) ED is the exposure duration (yrs) AF is the adjustment factor to address less than 24-liour exposure (tulitless) UR is the inhalation iuiit risk vahie (nig/ni )-1 Source: Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part F, Supplemental Guidance for Inhalation Risk Assessment) Input Parameters Parameter Description Value (Child) Source TR Target Cancer Risk 1.00E-06 USEPA AT Averaging Time 25,550 USEPA EF(') Exposure Frequency 28.9 Site -specific ED Exposure Duration 0.33 Site -specific UR Unit Risk CS(2) See below Action Levels Unit Risk Unit Risk Action Level Action Level Chemical (lag/m3)- 1 (mg/m s) -1 Source (m9/m3) (ppb) (3) benzene 7.80E-06 7.80E-03 USEPA 3.40E-01 106.5 naphthalene 3.40E-05 3.40E-02 USEPA 7.81 E-02 14.9 Notes: (t) Exposure based on child receptor in residential setting, 8-hours per day for 4 months (EF = 28.9 days, ED = 0.33 years). (2) Chemical -specific. (3) Based on molecular weight of benzene = 78.11 g/mol and naphthalene = 128.17 g/mol (e.g., ppm = mg/m3 x 24.45 / MW, where 24.45 is an ideal gas constant based on 25 °C and 1 atmosphere pressure) Odor and Ambient Air Monitoring Plan Raleigh MGP II Site Table 3 Benzene and Naphthalene Inhalation Action Level - Non -Carcinogenic Risk 8-hour Per Day Exposure Raleigh MGP II Site Redevelopment - Raleigh, NC Relevant Equations THQ x At,,, x RfC CA = EFxED Where: THQ is the Target Hazard Quotient AT is the averaging time (days) RfC is the Reference Concentration (mg/m3) EF is the exposure frequency (days/yr) ED is the exposure duration (yrs) Source: Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part F, Supplemental Guidance for Inhalation Risk Assessment) Input Parameters Parameter Description Value (Child) Source THQ Target Hazard Quotient 1.00E+00 USEPA ATn, Averaging Time(i) 122 USEPA EF Exposure Frequency 28.9 Site -specific ED Exposure Duration 0.33 Site -specific RfC Reference Concentration CS(2) See below Action Levels RfC Action Level Action Level Chemical s Source (m9�m) (m9/m3) (ppb)(3) naphthalene 3.00E-03 USEPA 3.80E-02 11.9 Notes: (t) Exposure based on child receptor in residential setting, 8-hours per day for 4 months (EF = 28.9 days, ED = 0.33 years). (2) Chemical -specific. (3) Based on molecular weight of benzene = 78.11 g/mol and naphthalene = 128.17 g/mol (e.g., ppm = mg/m3 x 24.45 / MW, where 24.45 is an ideal gas constant based on 25 °C and 1 atmosphere pressure) Odor and Ambient Air Monitoring Plan Raleigh MGP II Site Aptus Management, PLLC Environmental Management Solutions APPENDICES Aptus Management, PLLC Aptus Management, PLLC Environmental Management Solutions APPENDIX A FIELD DATA FORMS Aptus Management, PLLC Odor Assessment Form Project Name: Page: Project Number: Date: Subject: By: Observer Location Wind Time Rating Odor Description/Comments L a Description of location (Use streets landmarks, addresses, etc.) E OL ° o Z c C -6 O C m o ? oG -0 C aCL a Q 0) C o Description of odors (e.g. strength &persistence), other source(s) of odors, variable weather, etc. N C O ca it d H 0 d LL Additional Notes: Sketch/Map Relevant work activities occurring on -site during odor assessment: Odor Assessment Team Member(s) Daily Air Monitoring Form Project Name: Page: Project Number: Date: Subject: By: Site Activities: of ❑ Excavating / Loading ❑ Decon ❑ Compacting ❑ Backfilling ❑ Installing/pulling slide rail ❑ Rock ❑ Water Treatment ❑ Hauling Clean Fill ❑ No Work O O O M E cn E U) w Q J U H Q a E a a m c m N C d Ln Notes / Comments: Particulates Action Level: >0.200 mg/m3 >0.100 mg/m3 greater than upwind concentration VOCs Action Level: Level One VOC Action Level: >1.0 ppm (>1,000 ppb) Benzene Action Levels: Level Two Action Level: >0.1.ppm (>1,000 ppb) benzene Level Three Action Level: >1.0 ppm (>1,000 ppb) benzene Level Four Action Level: >5.0 ppm (>1,000 ppb) benzene Aptus Management, PLLC Environmental Management Solutions APPENDIX B MONITORING EVENTS/REPORTS Aptus Management, PLLC Aptus Management, PLLC Environmental Management Solutions SITE VISIT OCTOBER 13, 2021 Aptus Management, PLLC Cabarrus Street Area Sampling 516 W. Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 October 25, 2021 Clancy & Theys Construction Company 516 W. Cabarrus Street Raleigh, North Carolina 27603 Attention: Mr. Fleming Herring, P.E. flemingherring@clancytheys.com Reference: Cabarrus Street Air Monitoring Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 Dear Mr. Herring: S&ME, Inc. (S&ME) is pleased to provide this report detailing the area monitoring performed during the revitalization and development of the W. Cabarrus Street Brownfield Site located in Raleigh, North Carolina. The purpose of the assessment was to monitor the site for airborne contamination associated with the pre-existing subsurface contamination including benzene, toluene, ethylbenzene, and xylene (BTEX), volatile organic compounds, and polyaromatic hydrocarbons (PAH) during excavation activities on October 13, 2021. The limited sampling was performed in general accordance with S&ME Proposal No. 215242, dated June 10, 2021. The following report includes the project background, our assessment procedures, our findings, and our conclusions and recommendations. This report is provided for the sole use of Clancy & Theys Construction Company (C&T) as it relates to occupational exposure of BTEX, PAHs and trichloroethylene. Use of this report by any other parties will be at such party's sole risk and S&ME disclaims liability for any such use or reliance by third parties. The information presented are indicative of conditions only during the time of the assessment and of the specific areas referenced. S&ME appreciates this opportunity to provide our services to you. Please call if you have questions concerning this summary. S&ME, Inc. Janet K. Phillips Christopher B. Murray Senior Industrial Hygienist Principal Industrial Hygienist iphillips@smeinc.com cbmurray@smeinc.com cc: Charlie White, Clancy & Theys Construction Company S&ME, Inc. 13201 Spring Forest Road I Raleigh, NC 276161 p 919.872.2660 1 www.smeinc.com Cabarrus Street Air Monitoring Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 E Table of Contents 1.0 Introduction.......................................................................................................................1 ♦ Field Services.....................................................................................................................1 BTEXField Screening..................................................................................................................................................1 ♦ Results.................................................................................................................................2 BTEX, PAHs and TCE Vapor Field Screening Results...........................................................................................2 ♦ Conclusions and Recommendations.............................................................................2 Attachment - Site Figure October 25, 2021 Cabarrus Street Air Monitoring Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 11 E 1.0 Introduction The Cabarrus Street site located at 516 W. Cabarrus Street in Raleigh, North Carolina is currently undergoing select excavation as part of the revitalization and development project. Previous reports by others indicate the 516 W. Cabarrus Street site is a North Carolina Brownfield Site with potential subsurface contamination including benzene, toluene, ethylbenzene, and xylene (BTEX), chlorinated solvents, and polyaromatic hydrocarbons (PAH). As required by the Environmental Management Plan (EMP) prepared by Aptus Management, PLLC, dated April 8, 2021, S&ME prepared and conducted sampling to determine the potential exposure to workers during the initial excavation and trenching activities for the stormwater culvert. S&ME conducted sampling on June 18, 2021, to determine the potential occupational exposure of BTEX, chlorinated solvents and PAHs to workers at levels exceeding the Occupational Safety and Health (OSHA) Permissible Exposure Limits (PELs) and the American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs). C&T and Carolina Civilworks, Incorporated (CCI) simulated conditions that would represent the culvert excavation by preparing an area approximately six feet wide by twelve feet long, to a depth of approximately fifteen feet, in a location where previous groundwater monitoring data indicated the highest concentrations of BTEX, chlorinated solvents and PAHs. During the field screening activities, no elevated levels of BTEX, PAHs nor chlorinated hydrocarbons (TCE) were detected during the excavation utilizing the PID and the Drager CMS Analyzer as reported in the S&ME Report titled Cabarrus Street Exposure Assessment, dated July 6, 2021. C&T requested a follow-up visit October 12, 2021, to conduct additional ambient air monitoring of the Cabarrus Site due to recent air quality concerns and odor complaints from the residential neighbors located across the street from the revitalization site. S&ME conducted additional monitoring of the site on October 13, 2021. Field Services BTEX Field Screening S&ME utilized a MiniRAE 3000 Model PGM-7320 Photo Ionization Detector (PID) with a 10.6 eV lamp to measure the concentrations of volatile organic compounds (VOCs) and PAHs at the breathing zone. The background levels were reported as 0.0 parts per million (ppm). The PID operated continuously during the monitoring and levels were reported as 0.0 ppm along the construction fence surrounding 516 W. Cabarrus Street. Additionally, S&ME visually divided the property into three quadrants and walked each quadrant to measure the ambient air with the PID. These locations included the excavated area of contaminated soil where the concrete slab was uncovered, the pile of asphalt debris, and the pile of concrete debris. The attached drawing depicts the locations of recorded measurements with the understanding the PID ran continuously during the site evaluation. During the site walk at 2 PM in the afternoon of October 13, 2021, the following activities were observed: The excavation of the concrete foundation was underway. October 25, 2021 Cabarrus Street Air Monitoring Cabarrus Street =0 Raleigh, North Carolina S&ME Project No. 215242 11 E ♦ Dump trucks were entering and leaving the site. ♦ Misting during the operation of the concrete crushing equipment. ♦ The temperature was recorded as 87 degrees Fahrenheit with light variable winds at 3 miles per hour and relative humidity of 62 percent. Results BTEX AND PAHs Vapor Field Screening Results During the field screening activities utilizing the PID, levels were reported as 0.0 ppm as representation of BTEX and PAHs during the site walk. These results are consistent with the results recorded during the initial assessment conducted on June 18, 2021. Conclusions and Recommendations Although levels were reported as 0.0 ppm on October 13, 2021, C&T, S&ME and Aptus Management are discussing additional monitoring to ensure levels do not exceed 100 ppm. Based on monitoring results, neighborhood concerns, the North Carolina Department of Environmental Quality, and C&T's commitment to safety and health, S&ME recommends the following: Conduct periodic work area air monitoring and/or personal air monitoring during the installation of the proposed stormwater culvert to evaluate concentrations of BTEX, PAHs, and chlorinated solvents to ensure the workers are not exposed to concentrations above the OSHA PELs and ACGIH TLVs. 2 Be prepared to use engineering controls (e.g., fan), soil encapsulants. 3 Maintain an awareness of possible VOC impacted soil or groundwater. 4 Be prepared to contain and properly dispose of VOC impacted soil and groundwater, if needed. October 25, 2021 ATTACHMENT SITE FIGURE ���atnun— xn LEGEND Readings on 10.13.21 0 All Readings 0.0 Parts Per Million Ni SOURCE: WEST CABARRUS STREET, SITE PERMIT REVIEW, DETAILED GRADING PLAN, Sheet C3.01, PREPARED BY MCADAMS, DATED JANUARY 6, 2021. SCALE: FIGURE NO. NOT TO SCALE DAII_ CABARRUS STREET PLATFORM INDUSTRIAL HYGIENE SERVICES 10/13/2021 1 WEST CABARRUS STREET PRORCT NUMBER RALEIGH, NORTH CAROLINA 215242 Aptus Management, PLLC Environmental Management Solutions EXPOSURE ASSESSMENT REPORT J U LY 6, 2021 Aptus Management, PLLC Cabarrus Street Exposure Assessment 516 W. Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 July 6, 2021 Clancy & Theys Construction Company 516 W. Cabarrus Street Raleigh, North Carolina 27603 Attention: Mr. Fleming Herring, P.E. flemingherring@clancytheys.com Reference: Cabarrus Street Exposure Assessment Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 Dear Mr. Herring: S&ME, Inc. (S&ME) is pleased to provide this report detailing the exposure assessment simulation to evaluate the potential exposures of workers during the revitalization and development of the W. Cabarrus Street Brownfield Site located in Raleigh, North Carolina. The purpose of the assessment was to identify potential exposures to subsurface contamination including benzene, toluene, ethylbenzene, and xylene (BTEX), volatile organic compounds, and polyaromatic hydrocarbons (PAH). The limited assessment was performed in general accordance with S&ME Proposal No. 215242, dated June 10, 2021. The following report includes the project background, our assessment procedures, our findings, and our conclusions and recommendations. This report is provided for the sole use of Clancy & Theys Construction Company (C&T) as it relates to occupational exposure of BTEX, PAHs and trichloroethylene. Use of this report by any other parties will be at such party's sole risk and S&ME disclaims liability for any such use or reliance by third parties. The information presented are indicative of conditions only during the time of the assessment and of the specific areas referenced. S&ME appreciates this opportunity to provide our services to you. Please call if you have questions concerning this summary. S&ME, Inc. Janet K. Phillips Senior Industrial Hygienist jphillips@smeinc.com Tom Raymond, PE Principal Engineer traymond@smeinc.com S&ME, Inc. 13201 Spring Forest Road I Raleigh, NC 27616 1 p 919.872.2660 1 www.smeinc.com Cabarrus Street Exposure Assessment Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 E Table of Contents 1.0 Introduction.......................................................................................................................1 ♦ Field Services.....................................................................................................................1 BTEXField Screening..................................................................................................................................................1 ♦ Results.................................................................................................................................2 BTEX, PAHs and TCE Vapor Field Screening Results...........................................................................................2 ♦ Conclusions and Recommendations.............................................................................2 Appendices Appendix I — Site Plan Appendix II — Photographs July 6, 2021 Cabarrus Street Exposure Assessment Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 11 E 1.0 Introduction The Cabarrus Street site located at 516 W. Cabarrus Street in Raleigh, North Carolina is scheduled to undergo revitalization and development. Previous reports by others indicate the 516 W. Cabarrus Street site is a North Carolina Brownfield Site with potential subsurface contamination including benzene, toluene, ethylbenzene, and xylene (BTEX), chlorinated solvents, and polyaromatic hydrocarbons (PAH). The Environmental Management Plan (EMP) prepared by Aptus Management, PLLC, dated April 8, 2021, required C&T to develop a sampling strategy to determine the potential exposure to workers during the initial excavation and trenching activities for the stormwater culvert. The redevelopment project includes the installation of a culvert with the approximate dimensions of 25 feet wide by approximately 800 to 1,000 linear feet long. The culvert excavations will extend 15 to 20 feet below grade, in 50-foot sections. S&ME developed a sampling strategy to determine the potential occupational exposure of BTEX, chlorinated solvents and PAHs to workers at levels exceeding the Occupational Safety and Health (OSHA) Permissible Exposure Limits (PELs) and the American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs). C&T and Carolina Civilworks, Incorporated (CCI) simulated conditions that would represent the culvert excavation by preparing an area approximately six feet wide by twelve feet long, to a depth of approximately fifteen feet, in a location where previous groundwater monitoring data indicated the highest concentrations of BTEX, chlorinated solvents and PAHs. Hexavalent Chromium was included in the sampling strategy presented in the proposal number 215242 prepared by S&ME, dated June 10, 2021. However, due to the short duration of the excavation, the sampling volume required to properly access the potential exposures to Hexavalent Chromium would be insufficient and potentially invalidate the data. If additional testing is conducted during the excavation of the stormwater culvert, Hexavalent Chromium may be sampled at a later date. Field Services BTEX Field Screening C&T, CCI and S&ME discussed the installation of the culvert associated with the excavation including the following: CCI anticipates the employees will enter the excavation for specific tasks intermittently during an eight - hour shift, totaling a maximum of two hours per day. The area of the simulated excavation was marked with white spray -paint. (Refer to the drawing in Appendix 1) CCI indicated the trench box would be installed once the excavation was complete. The location of the simulation trench was in -filled from previous soil remediation with clean -fill. Temperatures during the simulation exercise would depict similar conditions during the excavation with temperatures ranging between 84 degrees Fahrenheit and 106 degrees Fahrenheit. July 6, 2021 Cabarrus Street Exposure Assessment Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 The excavated soil was scheduled to be removed and stockpiled on black polyethylene sheeting with straw bales serving as a berm around the outer perimeter of the soil pile. S&ME utilized a MiniRAE 3000 Model PGM-7320 Photo Ionization Detector (PID) with a 10.6 eV lamp to measure the concentrations of volatile organic compounds (VOCs) and PAHs at approximately three- to four- foot depth intervals during the excavation. CCI began the excavation on June 18, 2021, utilizing a CAT excavator, Number KTN20031 to perform the excavation. S&ME collected the following readings with the PID (utilizing tubing to reach the lower depths of the trench): Background reading: 0.0 parts per million (ppm) Initial ground break at one foot: 0.0 ppm Approximately four feet at edge of trench: 1.5 ppm Approximate seven -foot depth: 1.3 ppm Approximately nine -foot depth (petroleum odor): 1.1 ppm Approximate fifteen -foot depth (groundwater seepage observed with sheen): 1.6 ppm Ground level adjacent to trench: 1.1 - 1.8 ppm (peak) S&ME utilized a Drager Chip Management System (CMS) Analyzer to screen for the presence of chlorinated solvents - trichloroethylene (TCE) vapors in the base of the trench box on June 24, 2021. The TCE vapors were measured by initially inserting a TCE chip into the analyzer prior to lowering the meter within five to six inches of the trench's bottom. After a result was shown on the analyzer, the PCE chip was then ejected and a TCE chip was then inserted and the steps were repeated to ensure two consecutive readings of 0.0 ppm were recorded. Results BTEX, PAHs and TCE Vapor Field Screening Results During the field screening activities, no elevated levels of BTEX, PAHs nor chlorinated hydrocarbons (TCE) were detected during the excavation utilizing the PID and the Drager CMS Analyzer. Conclusions and Recommendations Based on the limited soil assessment results from the June 18t" and 24t", 2021, sampling events, the following conclusions are presented: S&ME collected eight PID readings for BTEX and PAHs during the excavation of the trench with a maximum depth of approximately fifteen feet. Based on the field screening results, the PID did not alarm and all readings were below 100 ppm. S&ME field screened the base of the trench box for vapor concentrations of TCE using the Drager CMS Analyzer. Based on the field screenings, no detectable concentrations of TCE were measured. July 6, 2021 Cabarrus Street Exposure Assessment Cabarrus Street Raleigh, North Carolina S&ME Project No. 215242 Based upon both sets of data, the reported levels of contaminants of concern did not exceed the OSHA PELs and ACGIH TLVs. Based on the above, S&ME recommends the following: Conduct periodic work area air monitoring and/or personal air monitoring during the installation of the proposed stormwater culvert to evaluate concentrations of BTEX, PAHs, and chlorinated solvents to ensure the workers are not exposed to concentrations above the OSHA PELs and ACGIH TLVs. Be prepared to use engineering controls (e.g. fan) or personal protective equipment to maintain safe levels of worker exposures. Maintain an awareness of possible VOC impacted soil or groundwater. Be prepared to contain and properly dispose of VOC impacted soil and groundwater, if needed. July 6, 2021 Appendices Appendix I - Site Plan I +r Y 'd { Ii lc �d m FE1rH aw■+m1 —- — � •.q I � {YIL 1Afc � I1Q , ..i a.■ � I R6 w w ■IH1 Ir u1FI9d AL ] IYX SILK N IlJ -E- 04F -M! J la' AE [nR.l �x sac ■ I� -9}1I9 ,YR DMJt liT, e' sunDi G me m4.r I eo AI�IF 12X7' 1.}. m cuagrr ■ u..as N FBI eFn � pr. a1.w[ ■ ,� I iFf. M6�{Ip i ]YAN1 I Ni.lb HUURIG k{f 13 ]0 lF 5' ems[ FEE- MiIHQ I 11 II IS• INP • h}1R Ito ii m+I ■f I i mlLl tm it 4 - a.Ea n..i. •11H FFS-MM a' Ix I! 74} {�Ipry ,Y91. oRIaI xm o-• C^° 77 M. 419E Oo-/A VW-dE EEx NFFW tM• 9Uff IAq J - ..r Yar�em DIrnIG YIUT' pr 1fA[ ■ IA �Pf41f CAfdM R[TNI.Y PILL OWN 91' UME-11 / IP P![ ROT G,V11 ' r 1y aRliiww , {LR adc ■ I� YEi 64h ■n i" I eI 41 Ir I;e u &. P.0 (11T } 1= pux aac ■ I!Q aUQF ■ 6Jif �i ■CF lrfw i— 14. 14AT -1E V PVC M "M IF 7+" � _ I ■ 1'ettI t0 lF ii• T ■ N O�iL+6 f 41pi�X Iw 1— aio*T 1 �J I I oo—lY� U41 IF 11 ■ }.� 9Yl ��-X lei SIIw iiL.15 oft •i snsrwce I •1rtgM OFS11I 24.la§w' y iY• • ~'�•^rF—�- : FRL ce rno�s u� '}caT' �. = _ Exisnr#G ; -- __ _._ • ------ WEST CABARRUS STREET {{ ¢ !q _• •e■:w. 1 i--.�:m--,_FMP06EDW PUBUCF11M LEGEND SOURCE: Soil Excavation & Field WEST CABARRUS STREET, SITE PERMIT REVIEW, DETAILED GRADING PLAN, Sheet C3.01, 1 Screening Area PREPARED BY MCADAMS, DATED JANUARY 6, 2021. SCALE: FIGURE NO. FIELD SCREENING AREA NOT TO SCALE i DATE: CABARRUS STREET PLATFORM INDUSTRIAL HYGIENE SERVICES 7/6/2021 1 I I I WEST CABARRUS STREET PROJECT NUMBER RALEIGH, NORTH CAROLINA 215242 Appendix II - Photograph Log N O - N +J Qj d Location / Orientation 516 W. Cabarrus Street, Raleigh, NC 1 Remarks Site location for simulation trench. s •! N �.:. - W t. • -_ -- - • - .. - _ a -do- O 0 O t d Location / Orientation 516 W. Cabarrus Street, Raleigh, NC 3 Remarks Approximate two foot depth N O N 00 N Q a N _ � N O O L a 4 Location / Orientation 516 W. Cabarrus Street, Raleigh, NC Remarks Fifteen -foot trench Location / Orientation 516 W. Cabarrus Street, Raleigh, NC 5 Remarks Soil Pile 00 0 O 0 t d Location / Orientation 516 W. Cabarrus Street, Raleigh, NC 6 Remarks Aptus Management, PLLC Environmental Management Solutions APPENDIX C Aptus Management, PLLC Honeywell THE POWER OF CONNECTED ppbRAE 3000+ Portable Handheld VOC Monitor The compact ppbRAE 3000 + is a comprehensive VOC gas monitor and datalogger for hazardous environments. The ppbRAE 3000 + is one of the most advanced handheld VOC monitors available for parts -per -billion detection. This third -generation patented PID device monitors VOCs using a photoionization detector with a 9.8 eV, 10.6 eV UV -discharge lamp. Workers can easily measure VOCs and wirelessly transmit readings up to 2 miles/3 km away. 1 built-in wireless modem allows real-time data connectivity with the command center located up to two miles/3 km away (with optional RAELink3 portable modem) from the detector. ( ■ V • Accurate VOC measurement in all operating conditions • Easy access to lamp and sensor in seconds without tools • Patented sensor and lamp autocleaning reduces maintenance • Monitors real-time readings and location of people • Low Cost of Ownership: 3-year 10.6 eV lamp Warranty • BLE module and dedicated APP for enhanced datalogging function FEATURES & BENEFITS APPLICATIONS Proven PID Technology 0 Oil & Gas • 3-second response time 0 HazMat • Extended range from 1 ppb to 10,000 ppm with highly acute linearity 0 Industrial Safety • Humidity compensation with integral humidity and temperature sensors 0 Civil Defense • Reflex PID Technology` 0 Environmental & Indoor Air Quality Integrated •';y_T�"+ • Highly connectivity capability through multiple wireless module options ��' 4� �• • Integrated Correction Factors list of 220 compounds —more than any other PID A.r • ••r • Includes flashlight for dark conditions�� f r'•F�' f • Large graphic display presents gas type, ' Correction Factor and concentration ❑� Ih`• • '•+ �k — •{ Durable • Easy access to battery, lamp and sensor in seconds without tools • Rugged housing withstands use in harsh environments • IP-67 waterproof design for easy cleaning and decontamination Size 10"Lx3.0'Wx2.5"H(25.5x7.6x6.4cm) Warranty 3-year warranty for 10.6 eV lamp, 1 year for pump, battery, and instrument Weight 26 oz (738 g) ISM license -free band. IEEE 802,15.4 Wireless Frequency Sub1GHzIEEE Sensors Photoionization sensorwith standard 10.6 eV or optional9.8 eV lamp 802.11 bands b/g 2.4 GHz Battery • Rechargeable, external field -replaceable Lithium -Ion battery pack Wireless Approvals FCC Part 15, CE R&TTE, Others' • Alkaline battery adapter Running time 16 hours of operation (12 hours with alkaline battery) Radio Module Supports Bluetooth or RM900 or BILE Display Graphic 4lines, 28 x43 mm, with LED backlight for enhanced display readability Contact RAE Systems for country -specific wireless approvals and certificates. Keypad 1 operation and 2 programming keys,' flashlight on/off Specifications are subject to change. Instantaneous reading •VOCsasppmbyvolume ormg/m3(3inupper case for cubic) Sensor Specifications Direct Readout •STEL,TWA and PEAK Gas Monitor Range Resolution Response • Battery and shutdown voltage Time T90 • Date, time, temperature 0 to 9999 ppb 1 ppb < 3 s 95 dB (at 12730 cm) buzzerand flashing red LED to indicate exceeded preset limits VOCs 10 to 99 ppm 0.01 ppm < 3 s • High: 3 beeps and flashes persecond 100 to 999 ppm 0.1 ppm < 3 s Alarms • Low: 2 beeps and flashes per second 1000 to 9999 ppm 1 ppm < 3 s • STEL and TWA:1 beep and flash persecond •Alarms latching with manual override orautomatic reset MONITOR ONLY INCLUDES: • Additional alarm for low battery and pump stall Highly resistant to EMI/RFI • ppbRAE 3000 + Monitor EMI/RFI Compliantwith EMC Directive 89/336/EEC • Wireless communication module built in, IPRating •IP-67unit off and without flexible probe as specified •IP-65unit running • Charging/download adapter Datalogging Standard 6 months at one -minute intervals • Organic vapor zeroing kit • Tedlar° bag for calibration Two -point or three-point calibration for zero and span. • Flex -I -Probe'"^ Calibration Reflex PIDTechnologyrM Calibration memoryfor8 calibration gases • External filter •Internal, integrated flow rate at500cc/mn • Rubber boot with straps Sampling Pump .Sample from 100'(30m) horizontally and vertically • Alkaline battery adapter • Lamp -cleaning and tool kit Low Flow Alarm -Auto pump shutoff at low -flow condition • Soft leather case Communication & • Download data and upload instrument set-up from PC through charging cradle or using BILE module and dedicated APP MONITOR WITH ACCESSORIES KIT- Data Download - Wireless data transmission through built-in RIF modem • Hard transport case with pre-cut foam padding Wireless Network Mesh RAE Systems Dedicated Wireless Network • Charging/download cradle • 5 Porous metal filters and O-rings Wireless Range Uptol5ft(5m)forBLE • Gas outlet port adapter and tubing EchoView Host: LOS > 660 ft (200 m) (Typical) ProRAE Guardian & RAEMesh Reader: LOS > 660 ft (200 m) ProRAE Guardian & RAELink3 Mesh: LOS > 330 ft (100 m) OPTIONAL CALIBRATION KIT ADDS: Safety - US and Canada: UL, cUL, Classified as Intrinsically Safe for use in Class 1, Division • 10 ppm isobutylene calibration gas, 34L 1 Groups A, B, C, D • Calibration regulator and flow controller Certifications •Europe:ATEXExll2GExialIC/IIBT4 •IECEx:ExialIC/IIBT4 OPTIONAL GUARANTEED Temperature -4'to113'F(-20°to50°C) COST -OF -OWNERSHIP PROGRAM: • 4-year repair and replacement warranty Humidity 0%to95%relative humidity(non-condensing)• Annual maintenance service Attachments Durable black rubber boot with straps For more information www.honeywellanalytics.com www.raesystems.com Europe, Middle East, Africa Life Safety Distribution GmbH Tel: 00800 333 222 44 (Freephone number) Tel: +4144 943 4380 (Alternative number) Middle East Tel: +9714 450 5800 (Fixed Gas Detection) gasdetection@honeywell.com Americas Honeywell Ana lytics Distribution Inc. Tel: +1 847 955 8200 Toll free: +1 800 538 0363 detectgas@honeywell.com Honeywell RAE Systems Phone: +1408 952 8200 Toll Free: +1 888 723 4800 Datasheet-ppbRAE 3000-+_DS-1018-_EN ©2018 Honeywell International Inc. Asia Pacific Honeywell Analytics Asia Pacific Tel: +82 (0) 2 6909 0300 Ind is Tel: +91 124 4752700 China Tel: +8610 5885 8788-3000 analytics.apChoneywell.com Technical Services EMEA: HAexpertChoneywell.com US: ha.us.serviceChoneywell.com AP: ha.ap.serviceChoneywell.com Technical Note TN-106 Revised 08/2010 Correction Factors, Ionization Energies*, And Calibration Characteristics Correction Factors and Ionization Energies RAE Systems PIDs can be used for the detection of a wide variety of gases that exhibit different responses. In general, any compound with ionization energy (IE) lower than that of the lamp photons can be measured.* The best way to calibrate a PID to different compounds is to use a standard of the gas of interest. However, correction factors have been determined that enable the user to quantify a large number of chemicals using only a single calibration gas, typically isobutylene. In our PIDs, correction factors can be used in one of three ways: 1) Calibrate the monitor with isobutylene in the usual fashion to read in isobutylene equivalents. Manually multiply the reading by the correction factor (CF) to obtain the concentration of the gas being measured. 2) Calibrate the unit with isobutylene in the usual fashion to read in isobutylene equivalents. Call up the correction factor from the instrument memory or download it from a personal computer and then call it up. The monitor will then read directly in units of the gas of interest. 3) Calibrate the unit with isobutylene, but input an equivalent, "corrected" span gas concentration when prompted for this value. The unit will then read directly in units of the gas of interest. * The term "ionization energy" is more scientifically correct and replaces the old term "ionization potential. "High -boiling ("heavy') compounds may not vaporize enough to give a response even when their ionization energies are below the lamp photon energy. Some inorganic compounds like H2O2 and NO2 give weak response even when their ionization energies are well below the lamp photon energy. Example 1: With the unit calibrated to read isobutylene equivalents, the reading is 10 ppm with a 10.6 eV lamp. The gas being measured is butyl acetate, which has a correction factor of 2.6. Multiplying 10 by 2.6 gives an adjusted butyl acetate value of 26 ppm. Similarly, if the gas being measured were trichloroethylene (CF = 0.54), the adjusted value with a 10 ppm reading would be 5.4 ppm. 0-12AM]; 5 Y S i E M 5 Example 2: With the unit calibrated to read isobutylene equivalents, the reading is 100 ppm with a 10.6 eV lamp. The gas measured is m-xylene (CF = 0.43). After downloading this factor, the unit should read about 43 ppm when exposed to the same gas, and thus read directly in m-xylene values. Example 3: The desired gas to measure is ethylene dichloride (EDC). The CF is 0.6 with an 11.7 eV lamp. During calibration with 100 ppm isobutylene, insert 0.6 times 100, or 60 at the prompt for the calibration gas concentration. The unit then reads directly in EDC values. Conversion to mg/m3 To convert from ppm to mg/m3, use the following formula: Cone. (mg/m3) _ [Conc.(ppmv) x mol. wt. (/e moleE molar gas volume (L) For air at 25 °C (77 °F), the molar gas volume is 24.4 L/mole and the formula reduces to: Conc.(mg/m) = Conc.(ppmv) x mol. wt. (g/mole) x 0.041 For example, if the instrument is calibrated with a gas standard in ppmv, such as 100 ppm isobutylene, and the user wants the display to read in mg/m3 of hexane, whose m.w. is 86 and CF is 4.3, the overall correction factor would be 4.3 x 86 x 0.041 equals 15.2. Correction Factors for Mixtures The correction factor for a mixture is calculated from the sum of the mole fractions Xi of each component divided by their respective correction factors CFi: CFmix = 1 / (Xi/CFi + X2/CF2 + X3/CF3 + ... Xi/CFi) Thus, for example, a vapor phase mixture of 5% benzene and 95% n-hexane would have a CFmix of CFmix = 1 / (0.05/0.53 + 0.95/4.3) = 3.2. A reading of 100 would then correspond to 320 ppm of the total mixture, comprised of 16 ppm benzene and 304 ppm hexane. RAE Systems Inc. 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com For a spreadsheet to compute the correction factor and TLV of a mixture see the appendix at the end of the CF table. TLVs and Alarm Limits for Mixtures The correction factor for mixtures can be used to set alarm limits for mixtures. To do this one first needs to calculate the exposure limit for the mixture. The Threshold Limit Value (TLV) often defines exposure limits. The TLV for the mixture is calculated in a manner similar to the CF calculation: TLV mix = 1 / (Xi/TLV1 + X2/TLV2 + X3/TLV3 +... Xl/TLVI) In the above example, the 8-h TLV for benzene is 0.5 ppm and for n-hexane 50 ppm. Therefore the TLV of the mixture is TLVmix = 1 / (0.05/0.5 + 0.95/50) = 8.4 ppm, corresponding to 8.0 ppm hexane and 0.4 ppm benzene. For an instrument calibrated on isobutylene, the reading corrsponding to the TLV is: Alarm Reading = TLVmix / CFmix = 8.4 / 3.2 = 2.6 ppm A common practice is to set the lower alarm limit to half the TLV, and the higher limit to the TLV. Thus, one would set the alarms to 1.3 and 2.6 ppm, respectively. Calibration Characteristics a) Flow Configuration. PID response is essentially independent of gas flow rate as long as it is sufficient to satisfy the pump demand. Four main flow configurations are used for calibrating a PID: 1) Pressurized gas cylinder (Fixed -flow regulator): The flow rate of the regulator should match the flow demand of the instrument pump or be slightly higher. 2) Pressurized gas cylinder (Demand -flow regulator): A demand -flow regulator better matches pump speed differences, but results in a slight vacuum during calibration and thus slightly high readings. 3) Collapsible gas bag: The instrument will draw the calibration gas from the bag at its normal flow rate, as long as the bag valve is large enough. The bag should be filled with enough gas to allow at least one minute of flow (— 0.6 L for a MiniRAE, —0.3 L for MultiRAE). 1-IFNI W 112 IL 1: 5 Y I S i E An 5 Technical Note TN-106 Revised 08/2010 4) T (or open tube) method: The T method uses a T junction with gas flow higher than the pump draw. The gas supply is connected to one end of the T, the instrument inlet is connected to a second end of the T, and excess gas flow escapes through the third, open end of the T. To prevent ambient air mixing, a long tube should be connected to the open end, or a high excess rate should be used. Alternatively, the instrument probe can be inserted into an open tube slightly wider than the probe. Excess gas flows out around the probe. The first two cylinder methods are the most efficient in terms of gas usage, while the bag and T methods give slightly more accurate results because they match the pump flow better. b) Pressure. Pressures deviating from atmospheric pressure affect the readings by altering gas concentration and pump characteristics. It is best to calibrate with the instrument and calibration gas at the same pressure as each other and the sample gas. (Note that the cylinder pressure is not relevant because the regulator reduces the pressure to ambient.) If the instrument is calibrated at atmospheric pressure in one of the flow configurations described above, then 1) pressures slightly above ambient are acceptable but high pressures can damage the pump and 2) samples under vacuum may give low readings if air leaks into the sample train. c) Temperature. Because temperature effects gas density and concentration, the temperature of the calibration gas and instrument should be as close as possible to the ambient temperature where the unit will be used. We recommend that the temperature of the calibration gas be within the instrument's temperature specification (typically 14' to 113' F or -10' to 45' Q. Also, during actual measurements, the instrument should be kept at the same or higher temperature than the sample temperature to avoid condensation in the unit. d) Matrix. The matrix gas of the calibration compound and VOC sample is significant. Some common matrix components, such as methane and water vapor can affect the VOC signal. PIDs are RAE Systems Inc. 2 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com most commonly used for monitoring VOCs in air, in which case the preferred calibration gas matrix is air. For a MiniRAE, methane, methanol, and water vapor reduce the response by about 20% when their concentration is 15,000 ppm and by about 40% at 30,000 ppm. Despite earlier reports of oxygen effects, RAE PID responses with 10.6 eV lamps are independent of oxygen concentration, and calibration gases in a pure nitrogen matrix can be used. H2 and CO2 up to 5 volume % also have no effect. e) Concentration. Although RAE Systems PIDs have electronically linearized output, it is best to calibrate in a concentration range close to the actual measurement range. For example, 100 ppm standard gas for anticipated vapors of 0 to 250 ppm, and 500 ppm standard for expected concentrations of 250 to 1000 ppm. The correction factors in this table were typically measured at 50 to 100 ppm and apply from the ppb range up to about 1000 ppm. Above 1000 ppm the CF may vary and it is best to calibrate with the gas of interest near the concentration of interest. f) Filters. Filters affect flow and pressure conditions and therefore all filters to be used during sampling should also be in place during calibration. Using a water trap (hydrophobic filter) greatly reduces the chances of drawing water aerosols or dirt particles into the instrument. Regular filter replacements are recommended because dirty filters can adsorb VOCs and cause slower response time and shifts in calibration. g) Instrument Design. High -boiling ("heavy") or very reactive compounds can be lost by reaction or adsorption onto materials in the gas sample train, such as filters, pumps and other sensors. Multi -gas meters, including EntryRAE, Mult1RAE and AreaRAE have the pump and other sensors upstream of the PID and are prone to these losses. Compounds possibly affected by such losses are shown in green in the table, and may give slow response, or in extreme cases, no response at all. In many cases the multi -gas meters can still give a rough indication of the relative concentration, without giving an accurate, 12--N W 112 IL 1: 5 Y I S i E An 5 Technical Note TN-106 Revised 08/2010 quantitative reading. The ppbRAE and MiniRAE series instruments have inert sample trains and therefore do not exhibit significant loss; nevertheless, response may be slow for the very heavy compounds and additional sampling time up to a minute or more should be allowed to get a stable reading. Table Abbreviations: CF = Correction Factor (multiply by reading to get corrected value for the compound when calibrated to isobutylene) NR= No Response IE = Ionization Energy (values in parentheses are not well established) C = Confirmed Value indicated by "+" in this column; all others are preliminary or estimated values and are subject to change ne = Not Established ACGIH 8-hr. TWA C## = Ceiling value, given where 8-hr.TWA is not available Disclaimer: Actual readings may vary with age and cleanliness of lamp, relative humidity, and other factors. For accurate work, the instrument should be calibrated regularly under the operating conditions used. The factors in this table were measured in dry air at room temperature, typically at 50-100 ppm. CF values may vary above about 1000 ppm. Updates: The values in this table are subject to change as more or better data become available. Watch for updates of this table on the Internet at http://www.raesystems.com IE data are taken from the CRC Handbook of Chemistry and Physics, 73rd Edition, D.R. Lide (Ed.), CRC Press (1993) and NIST Standard Ref. Database 19A, NIST Positive Ion Energetics, Vers. 2.0, Lias, et.al., U.S. Dept. Commerce (1993). Exposure limits (8-h TWA and Ceiling Values) are from the 2005 ACGIH Guide to Occupational Exposure Values, ACGIH, Cincinnati, OH 2O05. Equations for exposure limits for mixtures of chemicals were taken from the 1997 TLVs and BEIs handbook published by the ACGIH (1997). RAE Systems Inc. 3 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Compound Name Acetaldehyde Acetic acid Acetic anhydride Acetone Acetone cyanohydrin Acetonitrile Acetylene Acrolein Acrylic acid Acrylonitrile Allyl alcohol Allyl chloride Ammonia Amyl acetate Amyl alcohol Aniline Anisole Arsine Benzaldehyde Benzenamine, N-methyl- Benzene Benzonitrile Benzyl alcohol Benzyl chloride Benzyl formate Boron trifluoride Bromine Bromobenzene 2-Bromoethyl methyl ether Bromoform Bromopropane,1- Butadiene Butadiene diepoxide, 1,3- Butanal Butane Butanol, 1- Butanol, t- Butene, 1- Butoxyethanol, 2- Butoxyethanol acetate Butoxyethoxyethanol Butyl acetate, n- Butyl acrylate, n- Synonym/Abbreviation CAS No. 75-07-0 Ethanoic Acid 64-19-7 Ethanoic Acid Anhydride 108-24-7 2-Propanone 67-64-1 2-Hydroxyisobutyronitrile 75-86-5 Methyl cyanide, Cyanomethane 75-05-8 Ethyne 74-86-2 Propenal 107-02-8 Propenoic Acid 79-10-7 Propenenitrile 107-13-1 107-18-6 3-Chloropropene 107-05-1 7664-41-7 mix of n-Pentyl acetate & 628-63-7 2-Methylbutyl acetate 1-Pentanol 75-85-4 Aminobenzene 62-53-3 Methoxybenzene 100-66-3 Arsenic trihydride 7784-42-1 100-52-7 N-Methylphenylamine 100-61-8 71-43-2 Cyanobenzene 100-47-0 a-Hydroxytoluene, 100-51-6 Hydroxymethylbenzene, Benzenemethanol a-Chlorotoluene, Chloromethylbenzene Formic acid benzyl ester 104-57-4 7637-07-2 7726-95-6 108-86-1 6482-24-2 Tribromomethane 75-25-2 n-Propyl bromide 106-94-5 1,3-Butadiene, Vinyl ethylene 106-99-0 1,2,3,4-Diepoxybutane 298-18-0 1-Butanal 123-72-8 106-97-8 Butyl alcohol, n-Butanol 71-36-3 tert-Butanol, t-Butyl alcohol 75-65-0 1-Butylene 106-98-9 Butyl Cellosolve, Ethylene glycol 111-76-2 monobutyl ether Ethanol, 2-(2-butoxyethoxy)-, 124-17-4 acetate 2-(2-Butoxyethoxy)etha nol 112-34-5 123-86-4 Butyl 2-propenoate, 141-32-2 Acrylic acid butyl ester Formula C2H40 C2H402 C4Hs03 C3H60 C4H7NO C2H3N C2H2 C3H40 C3H402 C3H3N C3H60 C3H5C1 H3N C7H1402 C5H120 C7H7N C7H80 AsH3 C7H60 C7H9N C.H_ C7H5N C7H80 100-44-7 C71-17CI Butylamine, n- 109-73-9 Butyl cellosolve see 2-Butoxyethanol 111-76-2 Butyl hydroperoxide, t- Butyl mercaptan 1-Butanethiol Carbon disulfide Carbon tetrachloride Tetrachloromethane Carbonyl sulfide Carbon oxysulfide Cellosolve see 2-Ethoxyethanol CFC-14 see Tetrafluoromethane CFC-113 see 1,1,2-Trichloro-1,2,2-trifluoroethane � RAm F C8H802 BF3 B r2 C6H5Br C3H7OBr CHBr3 C3H7Br C4H6 C4H602 C4H80 C4H10 C4H1oO C4H1oO C4H8 C6H1402 C1oH2o04 C8H 1803 C6H 1202 C7H 1202 C4H11N Technical Note TN-106 Revised 08/2010 9.8 C 10.6 C 11.7 C IE (eV) TWA NR + 6 + 3.3 + 10.23 C25 NR + 22 + 2.6 + 10.66 10 NR + 6.1 + 2.0 + 10.14 5 1.2 + 1.1 + 1.4 + 9.71 500 4 + 11.1 C5 100 12.19 40 2.1 + 11.40 ne 42 + 3.9 + 1.4 + 10.10 0.1 12 + 2.0 + 10.60 2 NR + 1.2 + 10.91 2 4.5 + 2.4 + 1.6 + 9.67 2 4.3 0.7 9.9 1 NR + 9.7 + 5.7 + 10.16 25 11 + 2.3 + 0.95 + <9.9 100 5 1.6 10.00 ne 0.50 + 0.48 + 0.47 + 7.72 2 0.89 + 0.58 + 0.56 + 8.21 ne 1.9 + 9.89 0.05 1 9.49 ne 0.7 7.53 0.55 + 0.53 + 0.6 + 9.25 0.5 1.6 9.62 ne 1.4 + 1.1 + 0.9 + 8.26 ne 0.7 + 0.6 + 0.5 + 9.14 1 0.9 + 0.73 + 0.66 + ne NR NR NR 15.5 C1 NR + 1.30 + 0.74 + 10.51 0.1 0.6 0.5 8.98 ne 0.84 + -10 ne NR + 2.5 + 0.5 + 10.48 0.5 150 + 1.5 + 0.6 + 10.18 ne 0.8 0.85 + 1.1 9.07 2 25 + 3.5 + 1.2 --10 ne 1.8 9.84 67 + 1.2 10.53 800 70 + 4.7 + 1.4 + 9.99 20 6.9 + 2.9 + 9.90 100 0.9 9.58 ne 1.8 + 1.2 + 0.6 + <10 25 5.6 <_10.6 4.6 <_10.6 2.6 + 10 150 1.6 + 0.6 + 10 1.1 + 1.1 + 0.7 + 8.71 C5 75-91-2 C41-11002 2.0 + 1.6 + <10 1 109-79-5 C41-l1oS 0.55 + 0.52 + 9.14 0.5 75-15-0 CS2 4 + 1.2 + 0.44 10.07 10 56-23-5 CCI4 NR + NR + 1.7 + 11.47 5 463-58-1 COS 11.18 RAE Systems Inc. 4 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Technical Note TN-106 Revised 08/2010 Compound Name Synonym/Abbreviation CAS No. Formula 9.8 C 10.6 C 11.7 C IE (eV) TWA Chlorine 7782-50-5 C12 1.0 + 11.48 0.5 Chlorine dioxide 10049-04-4 C1O2 NR + NR + NR + 10.57 0.1 Chlorobenzene Monochlorobenzene 108-90-7 C61-15CI 0.44 + 0.40 + 0.39 + 9.06 10 Chlorobenzotrifluoride, 4- PCBTF, OXSOL 100 98-56-6 C71-14CIF3 0.74 + 0.63 + 0.55 + <9.6 25 p-Chlorobenzotrifluoride Chloro-1,3-butadiene, 2- Chloroprene 126-99-8 C41-15CI 3 10 Chloro-1,1-difluoroethane, 1- HCFC-142B, R-142B 75-68-3 C21-13CIF2 NR NR NR 12.0 ne Chlorodifluoromethane HCFC-22, R-22 75-45-6 CHCIF2 NR NR NR 12.2 1000 Chloroethane Ethyl chloride 75-00-3 C21-15CI NR + NR + 1.1 + 10.97 100 Chloroethanol Ethylene chlrohydrin 107-07-3 C21-15CIO 2.9 10.52 C1 Chloroethyl ether, 2- bis(2-chloroethyl) ether 111-44-4 C41-18Cl2O 8.6 + 3.0 + 5 Chloroethyl methyl ether, 2- Methyl 2-chloroethyl ether 627-42-9 C31-17CIO 3 ne Chloroform Trichloromethane 67-66-3 CHC13 NR + NR + 3.5 + 11.37 10 Chloro-2-methylpropene, 3- Methallyl chloride, Isobutenyl 563-47-3 C41-17CI 1.4 + 1.2 + 0.63 + 9.76 ne chloride Chloropicrin 76-06-2 CC131\1O2 NR + -400 + 7 + ? 0.1 Chlorotoluene, o- o-Chloromethylbenzene 95-49-8 C71-17CI 0.5 0.6 8.83 50 Chlorotoluene, p- p-Chloromethylbenzene 106-43-4 C71-17CI 0.6 8.69 ne Chlorotrifluoroethene CTFE, Chlorotrifluoroethylene 79-38-9 C2CIF3 6.7 + 3.9 + 1.2 + 9.76 5 Genetron 1113 Chlorotrimethylsilane 75-77-4 C31-19CISi NR NR 0.82 + 10.83 ne Cresol, m- m-Hydroxytoluene 108-39-4 C71-18O 0.57 + 0.50 + 0.57 + 8.29 5 Cresol, o- o-Hydroxytoluene 95-48-7 C71-18O 1.0 8.50 Cresol, p- p-Hydroxytoluene 106-44-5 C71-18O 1.4 8.35 Crotonaldehyde trans-2-Butenal 123-73-9 C41-16O 1.5 + 1.1 + 1.0 + 9.73 2 4170-30-3 Cumene Isopropylbenzene 98-82-8 C91-112 0.58 + 0.54 + 0.4 + 8.73 50 Cyanogen bromide 506-68-3 CNBr NR NR NR 11.84 ne Cyanogen chloride 506-77-4 CNCI NR NR NR 12.34 C0.3 Cyclohexane 110-82-7 C61-112 3.3 + 1.4 + 0.64 + 9.86 300 Cyclohexanol Cyclohexyl alcohol 108-93-0 C61-112O 1.5 + 0.9 + 1.1 + 9.75 50 Cyclohexanone 108-94-1 C6H1oO 1.0 + 0.9 + 0.7 + 9.14 25 Cyclohexene 110-83-8 C6H10 0.8 + 8.95 300 Cyclohexylamine 108-91-8 C6H13N 1.2 8.62 10 Cyclopentane 85% 287-92-3 C5H10 NR + 15 + 1.1 10.33 600 2,2-dimethylbutane 15% Cyclopropylamine Aminocyclpropane 765-30-0 C31-17N 1.1 + 0.9 + 0.9 + ne Decamethylcyclopentasiloxane 541-02-6 C10H30O5Si5 0.16 + 0.13 + 0.12 + ne Decamethyltetrasiloxane 141-62-8 C1oH3003Si4 0.17 + 0.13 + 0.12 + <10.2 ne Decane 124-18-5 C1oH22 4.0 + 1.4 + 0.35 + 9.65 ne Diacetone alcohol 4-Methyl-4-hyd roxy-2-penta none 123-42-2 C61-112O2 0.7 50 Dibromochloromethane Chlorodibromomethane 124-48-1 CHBr2Cl NR + 5.3 + 0.7 + 10.59 ne Dibromo-3-chloropropane, 1,2- DBCP 96-12-8 C3H5Br2Cl NR + 1.7 + 0.43 + 0.001 Dibromoethane, 1,2- EDB, Ethylene dibromide, 106-93-4 C2H4Br2 NR + 1.7 + 0.6 + 10.37 ne Ethylene bromide Dichlorobenzene, o- 1,2-Dichlorobenzene 95-50-1 C61-14Cl2 0.54 + 0.47 + 0.38 + 9.08 25 Dichlorodifluoromethane CFC-12 75-71-8 CC12F2 NR + NR + 11.75 1000 Dichlorodimethylsilane 75-78-5 C2H6Cl2Si NR NR 1.1 + >10.7 ne Dichloroethane, 1,2- EDC, 1,2-DCA, Ethylene 107-06-2 C21-14Cl2 NR + 0.6 + 11.04 10 dichloride Dichloroethene, 1,1- 1,1-DCE, Vinylidene chloride 75-35-4 C21-12Cl2 0.82 + 0.8 + 9.79 5 Dichloroethene, c-1,2- c-1,2-DCE, 156-59-2 C21-12Cl2 0.8 9.66 200 cis-Dichloroethylene Dichloroethene, t-1,2- t-1,2-DCE, 156-60-5 C21-12Cl2 0.45 + 0.34 + 9.65 200 trans-Dichloroethylene Dichloro-1-fluoroethane, 1,1- R-141B 1717-00-6 C21-13C12F NR + NR + 2.0 + ne Dichloromethane see Methylene chloride R 5 RAE Systems Inc. 3775 N. First St., San Jose, CA 95134-1708 USA r F M s Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Compound Name Synonym/Abbreviation CAS No. Dichloropentafluoropropane AK-225, mix of -45% 3,3- 442-56-0 dichloro-1,1,1,2,2-pentafluoro- 507-55-1 propane (HCFC-225ca) & -55% 1,3-Dichloro-1,1,2,2,3- pentafluoropropane (HCFC- 225cb) Technical Note TN-106 Revised 08/2010 Formula 9.8 C 10.6 C 11.7 C IE (eV) TWA C3HCl2F5 NR + NR + 25 + ne Dichloropropane, 1,2- 78-87-5 C31-16Cl2 0.7 10.87 75 Dichloro-1-propene, 1,3- 542-75-6 C31-14C12 1.3 + 0.96 + <10 1 Dichloro-1-propene, 2,3- 78-88-6 C31-14Cl2 1.9 + 1.3 + 0.7 + <10 ne Dichloro-1,1,1- R-123 306-83-2 C2HCl2F3 NR + NR + 10.1 + 11.5 ne trifluoroethane, 2,2- Dichloro-2,4,6- DCTFP 1737-93-5 C5Cl2F3N 1.1 + 0.9 + 0.8 + ne trifluoropyridine, 3,5- Dichlorvos Vapona; 0,0-dimethyl 0- 62-73-7 C4H7C12O4P 0.9 + <9.4 0.1 dichlorovinyl phosphate Dicyclopentadiene DCPD, Cyclopentadiene dimer 77-73-6 Ci10H12 0.57 + 0.48 + 0.43 + 8.8 5 Diesel Fuel 68334-30-5 m.w. 226 0.9 + 11 Diesel Fuel #2 (Automotive) 68334-30-5 m.w. 216 1.3 0.7 + 0.4 + 11 Diethylamine 109-89-7 C4H11N 1 + 8.01 5 Diethylaminopropylamine, 3- 104-78-9 C71-1181\12 1.3 ne Diethylbenzene See Dowtherm J Diethylmaleate 141-05-9 C81-112O4 4 ne Diethyl sulfide see Ethyl sulfide Diglyme See Methoxyethyl ether 111-96-6 C61-114O3 Diisobutyl ketone DIBK, 2,2-dimethyl-4-heptanone 108-83-8 C91-118O 0.71 + 0.61 + 0.35 + 9.04 25 Diisopropylamine 108-18-9 C6H15N 0.84 + 0.74 + 0.5 + 7.73 5 Diketene Ketene dimer 674-82-8 C41-14O2 2.6 + 2.0 + 1.4 + 9.6 0.5 Dimethylacetamide, N,N- DMA 127-19-5 C41-191\1O 0.87 + 0.8 + 0.8 + 8.81 10 Dimethylamine 124-40-3 C2H7N 1.5 8.23 5 Dimethyl carbonate Carbonic acid dimethyl ester 616-38-6 C31-16O3 NR + -70 + 1.7 + -10.5 ne Dimethyl disulfide DMDS 624-92-0 C21-16S2 0.2 + 0.20 + 0.21 + 7.4 ne Dimethyl ether see Methyl ether Dimethylethylamine DMEA 598-56-1 C4H11N 1.1 + 1.0 + 0.9 + 7.74 -3 Dimethylformamide, N,N- DMF 68-12-2 C3H7NO 0.7 + 0.7 + 0.8 + 9.13 10 Dimethylhydrazine, 1,1- UDMH 57-14-7 C21-181\12 0.8 + 0.8 + 7.28 0.01 Dimethyl methylphosphonate DMMP, methyl phosphonic acid 756-79-6 C31-19O3P NR + 4.3 + 0.74 + 10.0 ne dimethyl ester Dimethyl sulfate 77-78-1 C21-16O4S -23 -20 + 2.3 + 0.1 Dimethyl sulfide see Methyl sulfide Dimethyl sulfoxide DMSO, Methyl sulfoxide 67-68-5 C21-16OS 1.4 + 9.10 ne Dioxane, 1,4- 123-91-1 C41-18O2 1.3 9.19 25 Dioxolane, 1,3- Ethylene glycol formal 646-06-0 C31-16O2 4.0 + 2.3 + 1.6 + 9.9 20 Dowtherm A see Therminol@ * Dowtherm J (97% Diethylbenzene) 25340-17-4 C1oH14 0.5 DS-108F Wipe Solvent Ethyl lactate/Isopar H/ 97-64-3 m.w. 118 3.3 + 1.6 + 0.7 + ne Propoxypropanol -7:2:1 64742-48-9 1569-01-3 Epichlorohydrin ECH Chloromethyloxirane, 106-89-8 C21-15CIO -200 + 8.5 + 1.4 + 10.2 0.5 1-chloro2,3-epoxypropane Ethane 74-84-0 C21-16 NR + 15 + 11.52 ne Ethanol Ethyl alcohol 64-17-5 C2H6O 10 + 3.1 + 10.47 1000 Ethanolamine MEA, Monoethanolamine 141-43-5 C2H7NO 5.6 + 1.6 + 8.96 3 Ethene Ethylene 74-85-1 C21-14 9 + 4.5 + 10.51 ne Ethoxyethanol, 2- Ethyl cellosolve 110-80-5 C41-110O2 1.3 9.6 5 Ethyl acetate 141-78-6 C41-18O2 4.6 + 3.5 10.01 400 Ethyl acetoacetate 141-97-9 C61-110O3 1.4 + 1.2 + 1.0 + <10 ne Ethyl acrylate 140-88-5 C51-18O2 2.4 + 1.0 + <10.3 5 Ethylamine 75-04-7 C2H7N 0.8 8.86 5 RAE Systems Inc. ■_ R Am F 6 3775 N. First St., San Jose, CA 95134-1708 USA _ _ _ - Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Compound Name Ethylbenzene Ethyl caprylate Ethylenediamine Ethylene glycol * Ethylene glycol, Acrylate Ethylene glycol dimethyl ether Ethylene glycol monobutyl ether acetate Ethylene glycol, monothio Ethylene oxide Ethyl ether Ethyl 3-ethoxypropionate Ethyl formate Ethylhexyl -acrylate, 2- Ethylhexanol Ethyl idenenorbornene Synonym/Abbreviation Ethyl octanoate 1,2-Ethanediamine; 1,2-Diaminoethane 1,2-Ethanediol 2-hydroxyethyl Acrylate 1,2-Dimethoxyethane, Monoglyme 2-Butoxyethyl acetate Technical Note TN-106 Revised 08/2010 CAS No. Formula 9.8 C 10.6 C 11.7 C IE (Ev) TWA 100-41-4 C H i c 0.52 + 0.52 + 0.51 + 8.77 100 106-32-1 C1oH2002 + 0.52 + 0.51 + 107-15-3 C2H8N2 0.9 + 0.8 + 1.0 + 8.6 10 107-21-1 C21-1602 16 + 6 + 10.16 C100 818-61-1 C51-1803 8.2 :510.6 110-71-4 C41-11002 1.1 0.86 0.7 9.2 ne 112-07-2 C81-11603 1.3 :510.6 m e rca pto-2-eth a n o I 6 0-24-2 Oxirane, Epoxyethane 75-21-8 Diethyl ether 60-29-7 E E P 763-69-9 109-94-4 Acrylic acid 2-ethylhexyl ester 103-11-7 2-Ethyl-1-hexanol 104-76-7 5-Ethylidene bicyclo(2,2,1)hept-2-16219-75-3 ene Ethyl (S)-(-)-lactate Ethyl lactate, Ethyl (S)-(-)- 687-47-8 see also DS-108F hydroxypropionate 97-64-3 Ethyl mercaptan Ethanethiol 75-08-1 Ethyl sulfide Diethyl sulfide 352-93-2 Formaldehyde Formalin 50-00-0 Formamide 75-12-7 Formic acid 64-18-6 Furfural 2-Furaldehyde 98-01-1 Furfuryl alcohol 98-00-0 Gasoline #1 8006-61-9 Gasoline #2, 92 octane 8006-61-9 Glutaraldehyde 1,5-Pentanedial, Glutaricdialdehyde 111-30-8 Glycidyl methacrylate 2,3-Epoxypropyl methacrylate 106-91-2 Halothane 2-Bromo-2-chloro-1,1,1- 151-67-7 trifluoroethane HCFC-22 see Chlorodifluoromethane HCFC-123 see 2,2-Dichloro-1,1,1-trifluoroethane HCFC-141B see 1,1-Dichloro-1-fluoroethane HCFC-142B see 1-Chloro-1,1-difluoroethane HCFC-134A see 1,1,1,2-Tetrafluoroethane HCFC-225 see Dichloropentafluoropropane Heptane, n- 142-82-5 Heptanol, 4- Dipropylcarbinol 589-55-9 Hexamethyldisilazane, HMDS 999-97-3 1,1,1,3,3,3- * Hexamethyldisiloxane HMDSx 107-46-0 Hexane, n- 110-54-3 Hexanol, 1- Hexyl alcohol 111-27-3 Hexene, 1- 592-41-6 HFE-7100 see Methyl nonafluorobutyl ether Histoclear (Histo-Clear) Limonene/corn oil reagent Hydrazine * 302-01-2 Hydrazoic acid Hydrogen azide Hydrogen Synthesis gas 1333-74-0 Hydrogen cyanide Hydrocyanic acid 74-90-8 Hydrogen iodide * Hydriodic acid 10034-85-2 Hydrogen peroxide 7722-84-1 Hydrogen sulfide 7783-06-4 Hydroxypropyl methacrylate 27813-02-1 923-26-2 Iodine * 7553-56-2 0,12AM]; $ Y E M S C21-160S 1.5 9.65 C21-140 13 + 3.5 + 10.57 1 C41-11oO 1.1 + 1.7 9.51 400 C71-11403 1.2 + 0.75 + ne C31-1602 1.9 10.61 100 C111-12O02 1.1 + 0.5 + ne C81-1180 1.9 :510.6 C91-112 0.4 + 0.39 + 0.34 + 158.8 ne C51-11003 13 + 3.2 + 1.6 + -10 ne C21-16S 0.60 + 0.56 + 9.29 0.5 C4H1oS 0.5 + 8.43 ne CH2O NR + NR + 1.6 + 10.87 C0.3 CH3NO 6.9 + 4 10.16 10 CH2O2 NR + NR + 9 + 11.33 5 C51-1402 0.92 + 0.8 + 9.21 2 C51-1602 0.80 + <9.5 10 m.w.72 0.9 + 300 m.w.93 1.3 + 1.0 + 0.5 + 300 C51-1802 1.1 + 0.8 + 0.6 + C0.05 C71-11003 2.6 + 1.2 + 0.9 + 0.5 C2HBrCIF3 0.6 11.0 50 C71-116 45 + 2.8 + 0.60 + 9.92 400 C71-1160 1.8 + 1.3 + 0.5 + 9.61 ne C6H19NSi2 0.2 + 0.2 + -8.6 ne C6H18OSi2 0.33 + 0.27 + 0.25 + 9.64 ne C61-114 350 + 4.3 + 0.54 + 10.13 50 C61-1140 9 + 2.5 + 0.55 + 9.89 ne C61-112 0.8 9.44 30 m.w. -136 0.5 + 0.4 + 0.3 + ne H4N2 >8 + 2.6 + 2.1 + 8.1 0.01 HN3 10.7 H2 NR + NR + NR + 15.43 ne HCN NR + NR + NR + 13.6 C4.7 HI -0.6* 10.39 H2O2 NR + NR + NR + 10.54 1 H2S NR + 3.3 + 1.5 + 10.45 10 C71-11203 9.9 + 2.3 + 1.1 + ne 12 0.1 + 0.1 + 0.1 + 9.40 C0.1 RAE Systems Inc. % 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Technical Note TN-106 Revised 08/2010 Compound Name Synonym/Abbreviation CAS No. Formula 9.8 C 10.6 C 11.7 C IE (eV) TWA lodomethane Methyl iodide 74-88-4 CH31 0.21 + 0.22 + 0.26 + 9.54 2 Isoamyl acetate Isopentyl acetate 123-92-2 C71­11402 10.1 2.1 1.0 <10 100 Isobutane 2-Methylpropane 75-28-5 C41­110 100 + 1.2 + 10.57 ne Isobutanol 2-Methyl- 1-propanol 78-83-1 C41­11oO 19 + 3.8 + 1.5 10.02 50 Isobutene Isobutylene, Methyl butene 115-11-7 C41­18 1.00 + 1.00 + 1.00 + 9.24 Ne Isobutyl acrylate Isobutyl 2-propenoate 106-63-8 C71­11202 1.5 + 0.60 + Ne Isoflurane 1-Chloro-2,2,2-trifluoroethyl 26675-46-7 C31­12CIF50 NR + NR + 48 + -11.7 Ne difluoromethyl ether, forane Isooctane 2,2,4-Trimethylpentane 540-84-1 C8H18 1.2 9.86 ne Isopar E Solvent Isoparaffinic hydrocarbons 64741-66-8 m.w. 121 1.7 + 0.8 + Ne Isopar G Solvent Photocopier diluent 64742-48-9 m.w. 148 0.8 + Ne Isopar K Solvent Isoparaffinic hydrocarbons 64742-48-9 m.w. 156 0.9 + 0.5 + 0.27 + Ne Isopar L Solvent Isoparaffinic hydrocarbons 64742-48-9 m.w. 163 0.9 + 0.5 + 0.28 + Ne Isopar M Solvent Isoparaffinic hydrocarbons 64742-47-8 m.w. 191 0.7 + 0.4 + Ne Isopentane 2-Methylbutane 78-78-4 C51­112 8.2 Ne Isophorone 78-59-1 C91­1140 3 9.07 C5 Isoprene 2-Methyl-1,3-butadiene 78-79-5 C51­18 0.69 + 0.63 + 0.60 + 8.85 Ne Isopropanol Isopropyl alcohol, 2-propanol, IPA 67-63-0 C31­180 500 + 6.0 + 2.7 10.12 200 Isopropyl acetate 108-21-4 C51­11002 2.6 9.99 100 Isopropyl ether Diisopropyl ether 108-20-3 C61­1140 0.8 9.20 250 Jet fuel JP-4 Jet B, Turbo B, F-40 8008-20-6 + m.w. 115 1.0 + 0.4 + Ne Wide cut type aviation fuel 64741-42-0 Jet fuel JP-5 Jet 5, F-44, Kerosene type 8008-20-6 + m.w. 167 0.6 + 0.5 + 29 aviation fuel 64747-77-1 Jet fuel JP-8 Jet A-1, F-34, Kerosene type 8008-20-6 + m.w. 165 0.6 + 0.3 + 30 aviation fuel 64741-77-1 Jet fuel A-1 (JP-8) F-34, Kerosene type aviation 8008-20-6 + m.w. 145 0.67 34 fuel 64741-77-1 Jet Fuel TS Thermally Stable Jet Fuel, 8008-20-6 + m.w. 165 0.9 + 0.6 + 0.3 + 30 Hydrotreated kerosene fuel 64742-47-8 Limonene, D- (R)-(+)-Limonene 5989-27-5 C1oH16 0.33 + -8.2 Ne Kerosene C10-C16 petro. d istil late - see Jet Fuels 8008-20-6 MIDI -see 4,4'-Methylenebis(phenylisocyanate) Maleic anhydride 2,5-Furandione Mesitylene 1,3,5-Trimethyl benzene Methallyl chloride - see 3-Chloro-2-methylpropene Methane Natural gas Methanol Methyl alcohol, carbinol Methoxyethanol, 2- Methyl cellosolve, Ethylene glycol monomethyl ether Methoxyethoxyethanol, 2- 2-(2-Methoxyethoxy)ethanol Diethylene glycol monomethyl ether Methoxyethyl ether, 2- bis(2-Methoxyethyl) ether, Diethylene glycol dimethyl ether, Diglyme Methyl acetate Methyl acrylate Methyl 2-propenoate, Acrylic acid methyl ester Methylamine Aminomethane Methyl amyl ketone MAK, 2-Heptanone, Methyl pentyl ketone Methyl bromide Bromomethane Methyl t-butyl ether MTBE, tent -Butyl methyl ether Methyl cellosolve see 2-Methoxyethanol Methyl chloride Chloromethane Methylcyclohexane Methylene bis(phenyl- MIDI, Mondur M isocyanate), 4,4'- OMAF S Y 5 1 E- 5 108-31-6 C41­12O3 108-67-8 C9H12 74-82-8 CH4 67-56-1 CH40 109-86-4 C31­1802 111-77-3 C71­1160 111-96-6 C61­11403 -10.8 0.1 0.36 + 0.35 + 0.3 + 8.41 25 NR + NR + NR + 12.61 Ne NR + NR + 2.5 + 10.85 200 4.8 + 2.4 + 1.4 + 10.1 5 2.3 + 1.2 + 0.9 + <10 Ne 0.64 + 0.54 + 0.44 + <9.8 Ne 79-20-9 C31­1602 NR + 6.6 + 1.4 + 10.27 200 96-33-3 C41­1602 3.7 + 1.2 + (9.9) 2 74-89-5 CH5N 1.2 8.97 5 110-43-0 C71­1140 0.9 + 0.85 + 0.5 + 9.30 50 74-83-9 CH3Br 110 + 1.7 + 1.3 + 10.54 1 1634-04-4 C51­1120 0.9 + 9.24 40 74-87-3 CH3CI NR + NR + 0.74 + 11.22 50 107-87-2 C7H14 1.6 + 0.97 + 0.53 + 9.64 400 C15H1oN202 Very slow ppb level response 0.005 RAE Systems Inc. 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Compound Name Methylene chloride Methyl ether Methyl ethyl ketone Methylhydrazine Methyl isoamyl ketone Methyl isobutyl ketone Methyl isocyanate Methyl isothiocyanate Methyl mercaptan Methyl methacrylate Methyl nonafluorobutyl ether Synonym/Abbreviation Dichloromethane Dimethyl ether MEK, 2-Butanone Monomethylhydrazine, Hydrazomethane MIAK, 5-Methyl-2-hexanone MIBK, 4-Methyl-2-pentanone CH3NCO CH3NCS Methanethiol HFE-710ODL Methyl-1,5-pentanediamine, 2- Dytek-A amine, 2-Methyl (coats lamp) * pentamethylenediamine Methyl propyl ketone MPK, 2-Pentanone Methyl-2-pyrrolidinone, N- NMP, N-Methyl pyrrolidone, 1-Methyl-2-pyrrolidinone, 1-Methyl-2-pyrrolidone Methyl salicylate Methyl 2-hydroxybenzoate Methylstyrene, a- 2-Propenylbenzene Methyl sulfide DMS, Dimethyl sulfide Mineral spirits Stoddard Solvent, Varsol 1, White Spirits Mineral Spirits - Viscor 120B Calibration Fluid, b.p. 156-207°C Monoethanolamine - see Ethanolamine Mustard * HD, Bis(2-chloroethyl) sulfide Naphtha - see VM & P Naptha Naphthalene Mothballs Nickel carbonyl (in CO) Nickel tetracarbonyl Nicotine Nitric oxide Nitrobenzene Nitroethane Nitrogen dioxide Nitrogen trifluoride Nitromethane Nitropropane, 2- Nonane Norpar 12 n-Paraffins, mostly C10-C13 Norpar 13 n-Paraffins, mostly C13-C14 Octamethylcyclotetrasiloxane Octamethyltrisiloxane Octane, n- Octene, 1- Pentane Technical Note TN-106 Revised 08/2010 CAS No. Formula 9.8 C 10.6 C 11.7 C IE (eV) TWA 75-09-2 CH2Cl2 NR + NR + 0.89 + 11.32 25 115-10-6 C21-160 4.8 + 3.1 + 2.5 + 10.03 Ne 78-93-3 C41-180 0.86 + 0.9 + 1.1 + 9.51 200 60-34-4 C21-161\12 1.4 + 1.2 + 1.3 + 7.7 0.01 110-12-3 C71-1140 0.8 + 0.76 + 0.5 + 9.28 50 108-10-1 C61-1120 0.9 + 0.8 + 0.6 + 9.30 50 624-83-9 C21-13NO NR + 4.6 + 1.5 10.67 0.02 551-61-6 C21-13NS 0.5 + 0.45 + 0.4 + 9.25 ne 74-93-1 CH4S 0.65 0.54 0.66 9.44 0.5 80-62-6 C51-1802 2.7 + 1.5 + 1.2 + 9.7 100 163702-08-7, C5H31F90 NR + --35 + ne 163702-07-6 15520-10-2 C6H16N2 -0.6 + <9.0 ne 107-87-9 C51-1120 872-50-4 C51-191\10 119-36-8 C31-1303 98-83-9 C9H10 75-18-3 C21-16S 8020-83-5 m.w.144 8052-41-3 68551-17-7 8052-41-3 m.w.142 505-60-2 C4H8Cl2S 39472-40-7 68157-62-0 91-20-3 13463-39-3 54-11-5 10102-43-9 98-95-3 79-24-3 10102-44-0 7783-54-2 75-52-5 79-46-9 111-84-2 64771-72-8 64771-72-8 556-67-2 107-51-7 111-65-9 111-66-0 109-66-0 Peracetic acid * Peroxyacetic acid, Acetyl 79-21-0 hydroperoxide Peracetic/Acetic acid mix * Peroxyacetic acid, Acetyl 79-21-0 hydroperoxide Perchloroethene PCE, Perch loroethylene, 127-18-4 Tetrachloroethylene PGME Propylene glycol methyl ether, 1- 107-98-2 Methoxy-2-propanol 1� 5 Y 5 i E M 5 CicH_ C4NiO4 C1oH14N2 NO C6H5NO2 C2H5NO2 N 02 NF3 CH3NO2 C3H7NO2 C9H2o m.w. 161 m.w. 189 C8H2404Si4 C8H2402Si3 C8H18 C8H16 C5H12 C2H403 C2H403 C2CI4 C6H1203 0.93 + 0.79 + 9.38 200 1.0 + 0.8 + 0.9 + 9.17 ne 1.3 + 0.9 + 0.9 + -9 ne 0.5 8.18 50 0.49 + 0.44 + 0.46 + 8.69 ne 1.0 0.69 + 0.38 + 100 1.0 + 0.7 + 0.3 + 100 0.6 0.0005 0.45 + 0.42 + 0.40 + 8.13 10 0.18 <8.8 0.001 2.0 <_10.6 -6 5.2 + 2.8 + 9.26 25 2.6 + 1.9 + 1.6 + 9.81 1 3 10.88 100 23 + 16 + 6 + 9.75 3 NR NR NR 13.0 10 4 11.02 20 2.6 10.71 10 1.4 9.72 200 3.2 + 1.1 + 0.28 + ne 2.7 + 1.0 + 0.3 + ne 0.21 + 0.17 + 0.14 + ne 0.23 + 0.18 + 0.17 + <10.0 ne 13 + 1.8 + 9.82 300 0.9 + 0.75 + 0.4 + 9.43 75 80 + 8.4 + 0.7 + 10.35 600 NR + NR + 2.3 + ne 50 + 2.5 + ne 0.69 + 0.57 + 0.31 + 9.32 25 2.4 + 1.5 + 1.1 + 100 RAE Systems Inc. 9 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Technical Note TN-106 Revised 08/2010 Compound Name Synonym/Abbreviation CAS No. Formula 9.8 C 10.6 C 11.7 CIE (eV) TWA PGMEA Propylene glycol methyl ether 108-65-6 C61-11203 1.65 + 1.0 + 0.8 + ne acetate, 1-Methoxy-2- acetoxypropane, 1-Methoxy-2- propanol acetate Phenol Hydroxybenzene 108-95-2 C61-160 1.0 + 1.0 + 0.9 + 8.51 5 Phosgene Dichlorocarbonyl 75-44-5 CC120 NR + NR + 8.5 + 11.2 0.1 Phosgene in Nitrogen Dichlorocarbonyl 75-44-5 CCI20 NR + NR + 6.8 + 11.2 0.1 Phosphine (coats lamp) 7803-51-2 PH3 28 3.9 + 1.1 + 9.87 0.3 Photocopier Toner Isoparaffin mix 0.5 + 0.3 + ne Picoline, 3- 3-Methylpyridine 108-99-6 C6H7N 0.9 9.04 ne Pinene, a- 2437-95-8 C10H16 0.31 + 0.47 8.07 ne Pinene, R- 18172-67-3 C10H16 0.38 + 0.37 + 0.37 + -8 100 Piperylene, isomer mix 1,3-Pentadiene 504-60-9 C51-18 0.76 + 0.69 + 0.64 + 8.6 100 Propane 74-98-6 C31-18 NR + 1.8 + 10.95 2500 Propanol, n- Propyl alcohol 71-23-8 C31-180 5 1.7 10.22 200 Propene Propylene 115-07-1 C31-16 1.5 + 1.4 + 1.6 + 9.73 ne Propionaldehyde Propanal 123-38-6 C31-160 1.9 9.95 ne Propyl acetate, n- 109-60-4 C51-11002 3.5 2.3 10.04 200 Propylamine, n- 1-Propylamine, 107-10-8 C3H9N 1.1 + 1.1 + 0.9 + 8.78 ne 1-Aminopropane Propylene carbonate * 108-32-7 C4H603 62 + 1 + 10.5 ne Propylene glycol 1,2-Propanediol 57-55-6 C31-1802 18 5.5 + 1.6 + <10.2 ne Propylene glycol propyl ether 1-Propoxy-2-propanol 1569-01-3 C61-11402 1.3 + 1.0 + 1.6 + ne Propylene oxide Methyloxirane 75-56-9 C31-160 -240 6.6 + 2.9 + 10.22 20 16088-62-3 15448-47-2 Propyleneimine 2-Methylaziridine 75-55-8 C3H7N 1.5 + 1.3 + 1.0 + 9.0 2 Propyl mercaptan, 2- 2-Propanethiol, Isopropyl 75-33-2 C31-18S 0.64 + 0.66 + 9.15 ne mercaptan Pyridine 110-86-1 C5H5N 0.78 + 0.7 + 0.7 + 9.25 5 Pyrrolidine (coats lamp) Azacyclohexane 123-75-1 C4H9N 2.1 + 1.3 + 1.6 + -8.0 ne RR7300 (PGME/PGMEA) 70:30 PGME:PGMEA (1- 107-98-2 C41-11002 / 1.4 + 1.0 + ne Methoxy-2-propanol: 1 -Methoxy- C61-11203 2-acetoxypropane) Sarin GB, Isopropyl 107-44-8 methylphosphonofluoridate 50642-23-4 Stoddard Solvent - see Mineral Spirits 8020-83-5 Styrene 100-42-5 Sulfur dioxide 7446-09-5 Sulfur hexafluoride 2551-62-4 Sulfuryl fluoride Vikane 2699-79-8 Tabun " Ethyl N N- 77-81-6 Tetrachloroethane, 1,1,1,2- Tetrachloroethane, 1,1,2,2- Tetrachlorosilane Tetraethyl lead Tetraethyl orthosilicate Tetrafluoroethane, 1,1,1,2- Tetrafluoroethene Tetrafluoromethane Tetrahydrofuran Tetramethyl orthosilicate Therminol@ D-12 Therminol@ VP-1 " Toluene �12 A S Y S F E M 5 dimethylphosphoramidocyanidate 630-20-6 79-34-5 10023-04-7 TEL 78-00-2 Ethyl silicate, TEOS 78-10-4 H FC-134A 811-97-2 TFE, Tetrafluoroethylene, 116-14-3 Perfluoroethylene CFC-14, Carbon tetrafluoride 75-73-0 TH F 109-99-9 Methyl silicate, TMOS 681-84-5 Hydrotreated heavy naphtha 64742-48-9 Dowtherm A, 3:1 Diphenyl oxide: 101-84-8 Biphenyl 92-52-4 Methylbenzene 108-88-3 C4H10FO2P -3 C81-18 0.45 + 0.40 + 0.4 + 8.43 20 S02 NR NR + NR + 12.32 2 SF6 NR NR NR 15.3 1000 S02F2 NR NR NR 13.0 5 C5H11N202P 0.8 15ppt C2H2CI4 1.3 -11.1 ne C2H2CI4 NR + NR + 0.60 + -11.1 1 SiCl4 NR NR 15 + 11.79 ne C8H2OPb 0.4 0.3 0.2 --11.1 0.008 C8H2O04Si 0.7 + 0.2 + -9.8 10 C21-12F4 NR NR ne C2F4 -15 10.12 ne CF4 NR + NR + >15.3 ne C41-180 1.9 + 1.7 + 1.0 + 9.41 200 C4H1204Si 10 + 1.9 + -10 1 m.w.160 0.8 + 0.51 + 0.33 + ne C12H1oO 0.4 + 1 C12H10 C71-18 0.54 + 0.50 + 0.51 + 8.82 50 RAE Systems Inc. 10 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Technical Note TN-106 Revised 08/2010 Compound Name Synonym/Abbreviation CAS No. Formula 9.8 C 10.6 C 11.7 C IE (eV) TWA Tolylene-2,4-diisocyanate TDI, 4-Methyl-1,3-phenylene-2,4- 584-84-9 C91­161\1202 1.4 + 1.4 + 2.0 + 0.002 diisocyanate Trichlorobenzene, 1,2,4- 1,2,4-TCB 120-82-1 C6H3CI3 0.7 + 0.46 + 9.04 C5 Trichloroethane, 1,1,1- 1,1,1-TCA, Methyl chloroform 71-55-6 C2H3CI3 NR + 1 + 11 350 Trichloroethane, 1,1,2- 1,1,2-TCA 79-00-5 C2H3CI3 NR + NR + 0.9 + 11.0 10 Trichloroethene TCE, Trichoroethylene 79-01-6 C2HCI3 0.62 + 0.54 + 0.43 + 9.47 50 Trichloromethylsilane Methyltrichlorosilane 75-79-6 CH3CI3Si NR NR 1.8 + 11.36 ne Trichlorotrifluoroethane, 1,1,2- CFC-113 76-13-1 C2CI3F3 NR NR 11.99 1000 Triethylamine TEA 121-44-8 C6H15N 0.95 + 0.9 + 0.65 + 7.3 1 Triethyl borate TEB; Boric acid triethyl ester 150-46-9 C61­11503B 2.2 + 1.1 + -10 ne Triethyl phosphate Ethyl phosphate 78-40-0 C61­11504P -50 + 3.1 + 0.60 + 9.79 ne Trifluoroethane, 1,1,2- 430-66-0 C2H3F3 34 12.9 ne Trimethylamine 75-50-3 C3H9N 0.9 7.82 5 Trimethylbenzene, 1,3,5- - see Mesitylene 108-67-8 25 Trimethyl borate TMB; Boric acid trimethyl ester, 121-43-7 C31­1903B 5.1 + 1.2 + 10.1 ne Boron methoxide Trimethyl phosphate Methyl phosphate 512-56-1 C31­1904P 8.0 + 1.3 + 9.99 ne Trimethyl phosphite Methyl phosphite 121-45-9 C31­19031P 1.1 + + 8.5 2 Turpentine Pinenes (85%) + other 8006-64-2 C10H16 0.37 + 0.30 + 0.29 + -8 20 diisoprenes Undecane 1120-21-4 C111-124 2 9.56 ne Varsol - see Mineral Spirits Vinyl actetate 108-05-4 C41­1602 1.5 + 1.2 + 1.0 + 9.19 10 Vinyl bromide Bromoethylene 593-60-2 C2H3Br 0.4 9.80 5 Vinyl chloride Chloroethylene, VCM 75-01-4 C2H3CI 2.0 + 0.6 + 9.99 5 Vinyl-1-cyclohexene, 4- Butadiene dimer, 100-40-3 C81­112 0.6 + 0.56 + 9.83 0.1 4-Ethenylcyclohexene Vinylidene chloride - see 1,1-Dichloroethene Vinyl-2-pyrrolidinone, 1- NVP, N-vinylpyrrolidone, 1- 88-12-0 C6H9NO 1.0 + 0.8 + 0.9 + ne ethenyl-2-pyrrolidinone Viscor 120B - see Mineral Spirits - Viscor 120B Calibration Fluid V. M. & P. Naphtha Ligroin; Solvent naphtha; Varnish 64742-89-8 m.w. 111 1.7 + 0.97 + 300 maker's & painter's naptha (C8-C9) Xylene, m- 1,3-Dimethylbenzene 108-38-3 C81­11c 0.50 + 0.44 + 0.40 + 8.56 100 Xylene, o- 1,2-Dimethylbenzene 95-47-6 C8H10 0.56 + 0.46 + 0.43 8.56 100 Xylene, p- 1,4-Dimethyl benzene 106-42-3 C8H10 0.48 + 0.39 + 0.38 + 8.44 100 None 1 1 1 Undetectable 1 E+6 1 E+6 1 E+6 Compounds indicated in green can be detected using a MiniRAE 2000 or ppbRAE/+ with slow response, but may be lost by adsorption on a MultiRAE or EntryRAE. Response on multi -gas meters can give an indication of relative concentrations, but may not be quantitative and for some chemicals no response is observed. Therminol® is a registered Trademark of Solutia, Inc. W� R�►� 5 Y F M S RAE Systems Inc. 11 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com Technical Note TN-106 Revised 08/2010 Appendix I: Example of Automatic Calculation of Correction Factors, TLVs and Alarm Limits for Mixtures (Calculations performed using Excel version of this database, available on request) CF CF CF Mol. Compound 9.8 eV 10.6 eV 11.7eV Frac Benzene 0.55 0.53 0.6 0.01 Toluene 0.54 0.5 0.51 0.06 Hexane, n- 300 4.3 0.54 0.06 Heptane, n- 45 2.8 0.6 0.28 Styrene 0.45 0.4 0.42 0.06 Acetone 1.2 1.1 1.4 0.28 Isopropanol 500 6 2.7 0.28 None 1 1 1 0.00 Mixture Value: 2.1 1.5 0.89 1.00 TLV Alarm Setpoint when Calibrated to Isobutylene: 26 37 62 ppm ppm ppm STEL Alarm Setpoint, same Calibration 86 115 193 ppm ppm ppm � R�►� Y F M S Conc TLV STEL ppm ppm Ppm 1 0.5 2.5 10 50 150 10 50 150 50 400 500 10 20 40 50 750 1000 50 400 500 0 1 181 56 172 ppm ppm ppm RAE Systems Inc. 12 3775 N. First St., San Jose, CA 95134-1708 USA Phone:+1.888.723.8823 Email: raesales@raesystems.com Web Site: www.raesystems.com DUSTTRAK T M I I AEROSOL MONITORS MODELS 8530 ' 8530EP AND 8532 DESKTOP OR HANDHELD Features and Benefits All Models + Real-time mass concentration readings and data -logging allow for data analysis during and bfter sampling + Measure aerosol concentrations corresponding to PM1, PM2.5, Respirable, and PM10 size fractions, using a variety of inlet conditioners + Easy -to -use graphical user interface with color touch -screen for effortless operation Handheld Model (8532) + Long life internal pump for continuous sampling + Single -point data collection for walk through surveys + Lightweight design with ergonomic handle for portable applications te@ ' UNDERSTANDING, ACCELERATED Desktop Models (8530 and 8530EP) + Energy -efficient, long lasting external pump for continuous, unattended, 24/7, outdoor monitoring applications (Model 8530EP only) + Long life internal pump for shorter work -shift or IAQ sampling applications (Model 8530) + Gravimetric reference sampling capability for custom reference calibrations + Automatic zeroing (with optional zero module) to minimize the effect of zero drift + STEL alarm setpoint for tracking 15-minute average mass concentrations + Environmental protected and tamper -proof secure (with an optional environmental enclosure) + Inlet sample conditioning (with optional heated inlet sample conditioner) to reduce the effect of humidity on photometric mass measurements (for use with an environmental enclosure) + Cloud Data Management System as hosted by Netronix- Desktop Models: Ideal for Long -Term Surveys and Remote Monitoring Applications The DustTrak 11 is offered as a standard desktop (Model 8530), as well as a desktop with external pump (Model 8530EP.) Both models have manual and programmable data logging functions, making them ideal for unattended applications, The standard desktop model is most suitable for indoor, continuous monitoring, while the desktop with external pump is designed for 24/7 unattended, remote monitoring outdoors. Handheld Models: Perfect for Walk -Through Surveys and Single -Point Data Collection Applications The DustTrak II Handheld Model 8532 is lightweight and portable, It is perfect for industrial hygiene surveys, point source location monitoring, indoor air quality investigations, engineering control evaluations/validation, and for baseline trending and screening, Like the desktop models, it has manual and programmable data logging functions. In addition, the handheld model also has a single -point data logging capability. Single -point data collection is used for walk-through industrial hygiene surveys and indoor The DustTrak II desktop models come with USB (device and host), air quality investigations. Ethernet, and analog and alarm outputs allowing remote access to data. User adjustable alarm setpoints for instantaneous or 15-minute short-term excursion limit (STEL) are also available on desktop models. The alarm output with user -defined setpoint alerts you when upset or changing conditions occur. The DustTrak II desktop monitors have several unique features; + Measure aerosols in high concentrations up to 400 mg/m3. + External pump (Model 8530EP) with low power consumption for continuous, unattended monitoring in remote outdoor locations. + Gravimetric sampling capability using a 37-mm filter cassette which can be inserted in -line with the aerosol stream allowing you to perform an integral gravimetric analysis for custom reference calibrations. + Zeros automatically using the external zeroing module. This optional accessory is used when sampling over extended periods of time. By zeroing the monitor during sampling, the effect of zero drift is minimized. + STEL alarm feature for tracking 15-minute average mass concentrations when alarm setpoint has been reached for applications like monitoring fugitive emissions at hazardous waste sites. + Provide for environmental protection and tamper -proof security using an environmental enclosure, This optional accessory encloses the instrument within a waterproof, lockable, custom -designed case. + Condition the sample air stream before entering the instrument optics using a heated inlet sample conditioner (designed for use with an environmental enclosure.) This optional accessory is used in humid environments. By conditioning the sample, the humidity and water vapor are minimized, reducing elevated measurements. Applications Aerosol research studies Desktop + Handheid + Baseline trending and screening + + Engineering control evaluations + Engineering studies + Epidemiology studies + + Indoor air quality investigations + + Industrial/occupational hygiene surveys + + Point source monitoring + Outdoor environmental monitoring + Process monitoring + + Remote monitoring + Battery Performance Models 8530 and 8530EP (Typical) 6600 mAH Li -Ion Battery Pack P/N 801680 1 Battery 2 Batteries Battery runtime (hours) Up to 6 Up to 12 Charge time* (hours) in DustTrak 4 8 Charge time* (hours) in external battery charger P/N 801685 4 8 Model 8532 (Typical) Battery 9600 mAH Li -Ion Battery Pack P/N 801681 Battery runtime (hours) Up to 6 Charge time* (hours) in DustTrak 4 Charge time* (hours) in external 4 battery charger P/N 801686 * Of a fully depleted battery DustTrak II Aerosol Monitor Features All Models + Li -Ion rechargeable batteries + Internal and external battery charging capabilities + Outlet port for isokinetic sampling applications + User serviceable sheath flow and pump filters + Logged test pause and restart feature + Logged test programming + Color touch screen -either manual mode or program mode + TrakPro- Data Analysis Software via a PC + User adjustable custom calibration settings + Instantaneous alarm settings with visual and audible warnings + Real-time graph display + View statistical information during and after sampling + On -screen instrument status indicators: FLOW, LASER and FILTER + Filter service indicator for user preventative maintenance Desktop Models (8530 and 853OEP) + Long life external pump (853OEP) + Internal pump (8530) + Hot swappable batteries + Gravimetric reference sample capability + STEL alarm setpoint Optional Accessories + Auto zeroing module + Protective environmental enclosure (8535 and 8537) + Heated inlet sample conditioner (for use with an environmental enclosure) + Cloud Data Management System as hosted by Netronix'" Handheld Model (8532) + Long life internal pump + Single -point data collection for walk through surveys Easy to Program and Operate The graphical user interface with color touch -screen puts everything at your fingertips, The easy -to -read display shows real-time mass concentration and graphical data, as well as other statistical information along with instrument pump, laser and flow status, and much more. Perform quick walk-through surveys or program the instrument's advanced logging modes for long-term sampling investigations. Program start times, total sampling times, logging intervals, alarm setpoints and many other parameters. You can even set up the instrument for continuous unattended operation. TrakPro- Software Makes Monitoring Easier than Ever TrakPro" Data Analysis Software allows you to set up and program directly from a PC. It even features the ability for remote programming and data acquisition from your PC via wireless communication options or over an Ethernet network. As always, you can print graphs, raw data tables, and statistical and comprehensive reports for record keeping purposes. Desktop Monitor with External Pump, Model 8530EP SPECIFICATIONS DUSTTRAK 7 II AEROSOL MONITO MOILS 8530, 8530EP AND 8532 Sensor Type Communications 90o light scattering 8530 USB (host and device) and Ethernet. Stored data Particle Size Range accessible using flash 0.1 to 10 pm memory drive 8530EP USB (host and device) Aerosol Concentration Range and Ethernet. Stored data 8530 Desktop 0.001 to 400 mg/m3 accessible using flash 8530EP Desktop with External Pump 0,001 to 400 mg/m3 memory drive plus, cable 8532 Handheld 0.001 to 150 mg/m3 assembly for external pump 8532 USB (Hose and device). Stored Resolution data accessible using flash ±0.1% of reading or 0.001 mg/m3, whichever is greater memory drive Zero Stability Power -AC ±0.002 mg/m3 per 24 hours at 10 sec time constant Switching AC power adapter with universal line cord included, 115-240 VAC Flow Rate 3.0 L/min set at factory,1.40 to 3.0 L/min, user adjustable Analog Out 8530/8530EP User selectable output, Flow Accuracy 0 to 5 V or 4 to 20 mA. ±5% of factory set point, internal flow controlled User selectable scaling range Temperature Coefficient Alarm Out +0.001 mg/m3 per °C B530/8530EP Relay or audible buzzer Relay Operational Temp Non -latching MOSFET switch 32 to 120OF (0 to 50°C) + User selectable set point +-5% deadband Storage Temp + Connector 4-pin, -4 to 140OF (-20 to 60°C) Mini -DIN connectors 8532 Audible buzzer Operational Humidity 0 to 95% RH, non -condensing Screen 6530 5.7 in. VGA color touchscreen Time Constant 8532 3.5 in. VGA color touchscreen User adjustable,1 to 60 seconds Gravimetric Sampling Data Logging 8530/8530EP Removable 37 mm cartridge 5 MB of on -board memory (> 60,000 data points) (user supplied) 45 days at 1 minute logging interval CE Rating Log interval Immunity EN61236-12006 User adjustable,1 second to 1 hour Emissions EN61236-12006 Physical Size (H x W x D) Handheld 4.9 x 4.8 x 12.5 in. (12.5 X 12.1 X 31,6 cm) Desktop 5.3 x 8.5 x 8.8 in. Specifications are subject to change without notice. (13.5 x 21.6 x 22.4 cm) External Pump 4.0 x 7.0 x 3.5 in. TSI and the TS1 logo are registered trademarks, and DustTrak and TrakPro are trademarks (10.0 x 18.0 X 9.0 Cm) of TSI Incorporated. Weight Netronix is a trademark of Netronix, Inc. Handheld 2.9 lb (1.3 kg), 3.3 lb (1.5 kg) with battery Desktop 3.5 lb (1.6 kg), 4.5lb (2.0 k6)-1 battery, 5.5 lb (2.5 kg)-2 batteries External Pump 3.0 lb (1.4 kg) ' UNDERSTANDING, ACCELERATED TSI Incorporated - Visit our website www.tsi.com for more information. USA Tel: +1800 874 2811 India Tel: +9180 67877200 UK Tel: +44149 4 459200 China Tel: +8610 8219 7688 France Tel: +33 4 911187 64 Singapore Tel: +65 6595 6388 Germany Tel: +49 241523030 P/N 6001986 Rev] 02014 TSI Incorporated Printed in U.S.A. Aptus Management, PLLC Environmental Management Solutions APPENDIX D ODOR SUPRESSSION FOAM SAFETY DATA SHEET Aptus Management, PLLC /1 SAFETY DATA SHEET AT M O S LONG DURATION FOAM AC-645 Section 1. Identification GHS product identifier LONG DURATION FOAM AC-645 Chemical name Proprietary Surfactant. Other means of Aqueous anionic surfactant mixture. identification Product type Liquid. Relevant identified uses of the substance or mixture and uses advised against Product use Aqueous Surfactant. Spray application for VOC and Odor control. Area of application Industrial applications. Supplier/Manufacturer CCR Specialty Chemicals (Subs: Rusmar, Inc.) 17 Campus Blvd., Suite 100 Newtown Square, PA 19073 Phone: 1-800-733-3626 or 610-436-4314 E-mail info@atmos-technologies.com Website: www.atmos-technologies.com Emergency telephone number (with hours of CHEMTREC 800 424 9300 operation) Section 2. Hazards identification OSHA/HCS status Classification of the substance or mixture GHS label elements Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Hazards not otherwise classified While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Not classified. No signal word. No known significant effects or critical hazards. Not applicable. Not applicable. Not applicable. Not applicable. None known. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 1/11 United States LONG DURATION FOAM AC-645 Section 3. Composition/information on ingredients Substance/mixture Chemical name Other means of identification CAS number/other identifiers CAS number Product code Substance Proprietary Surfactant. Aqueous anionic surfactant mixture. Not available. Not available. Ingredient name Other names % CAS number Proprietary Surfactant. - 100 - Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Over -exposure signs/symptoms Eye contact No specific data. Inhalation No specific data. Skin contact No specific data. Ingestion No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 2/11 United States LONG DURATION FOAM AC-645 Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Section 5. Fire -fighting measures Extinguishing media Suitable extinguishing Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing None known. media Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Hazardous thermal Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide sulfur oxides Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non -emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non - emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleanina u Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water -insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 3/11 United States LONG DURATION FOAM AC-645 Section 6. Accidental release measures Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handlina Protective measures : Put on appropriate personal protective equipment (see Section 8). Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they controls comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side -shields. Skin protection Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 4/11 United States LONG DURATION FOAM AC-645 Section 8. Exposure controls/personal protection Hand protection Chemical -resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Solubility in water Partition coefficient: n- octanol/water Auto -ignition temperature Decomposition temperature SADT Viscosity Liquid. [Clear viscous liquid.] Translucent. White. Odorless. Not available. Not available. Not available. 99°C (210.2°F) Not applicable. Not available. Not applicable. Not available. 3.3 kPa (25 mm Hg) [room temperature] Not available. 1.01 to 1.06 Easily soluble in the following materials: cold water and hot water. Easily soluble. Not available. Not available. Not available. Not available. Not available. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 5/11 United States LONG DURATION FOAM AC-645 Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions to avoid : Keep away from heat. Incompatible materials : No specific data. Hazardous decomposition Low levels of sulfur oxides on exposure to high temperatures (concentrate). products Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Conclusion/Summary Not expected. Irritation/Corrosion Not available. Sensitization Not available. Mutaaenicit Conclusion/Summary Not available. Carcinogenicity Conclusion/Summary Not available. Reproductive toxicity Conclusion/Summary Not available. Teratogenicity Conclusion/Summary Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely Not available. routes of exposure Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 6/11 United States LONG DURATION FOAM AC-645 Section 11. Toxicological information Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Eye contact No specific data. Inhalation No specific data. Skin contact Ingestion No specific data. No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate Not available. effects Potential delayed effects Not available. Long term exposure Potential immediate Not available. effects Potential delayed effects Not available. Potential chronic health effects Not available. General No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 7/11 United States LONG DURATION FOAM AC-645 Section 12. Ecological information Bioaccumulative potential Not available. Mobility in soil Soil/water partition coefficient (Koc) Other adverse effects Not available. No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT Classification IMDG IATA UN number Not regulated. Not regulated. Not regulated. UN proper shipping name - - - Transport hazard class(es) - - - Packing group - - - Environmental hazards No. No. No. Additional information - - - Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according : Not available. to Annex II of MARPOL 73/78 and the IBC Code Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 8/11 United States LONG DURATION FOAM AC-645 Section 15. Regulatory information U.S. Federal regulations Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) United States inventory (TSCA 8b): Not determined. Not listed Not listed Not listed Not listed Not listed SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ Not applicable. SARA 311 /312 Classification Not applicable. Composition/information on ingredients No products were found. SARA 313 Not applicable. State regulations Massachusetts New York New Jersey Pennsylvania This material is not listed. This material is not listed. This material is not listed. This material is not listed. California Prop. 65 None of the components are listed. Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 9/11 United States LONG DURATION FOAM AC-645 Section 16. Other information Hazardous Material Information System (U.S.A.) 0 Flammability 0 0 Caution: HMISO ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMISO ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMISO ratings are to be used with a fully implemented HMISO program. HMISO is a registered mark of the National Paint & Coatings Association (NPCA). HMISO materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Flammability Health 0 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Not classified. History Date of issue/Date of 05/28/2015 revision Date of previous issue No previous validation Version 1 Prepared by IHS Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods Log Pow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Date of issue/Date of revision : 1112312020 Date of previous issue :No previous validation Version : 1 10/11 United States LONG DURATION FOAM AC-645 Section 16. Other information References HCS (U.S.A.)- Hazard Communication Standard International transport regulations F Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision : 1112312020 Date of previous issue : No previous validation Version : 1 11/11 United States November 3rd, 2021 This letter is to confirm that none of the Rusmar, Inc./CCR products contain, or have ever contained per and polyfluoroalkyl substances (PFAS), or any other toxic substances. Feel free to contact me at any time with any questions. Thank Director Mologies/Rusmar, siness Development - Remediation Atm-- to Inc. 216 Garfield Avenue West Chester, PA 19380 610-436-4314(p) and (610) 436-8436(f) www.rusmarinc.com