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HomeMy WebLinkAbout23057_Charlotte Van&Storage_VIMS Post-Occ Sampling Rpt & Review Letter_20230825August 25, 2023 Sent via Email Patrick Foster Lennar Multifamily Communities, LLC 500 East Morehead Street, Suite 300 Charlotte, North Carolina 28202 patrick.foster@livelmc.com Subject: VIMS Post-Occupancy Sampling Report Review Charlotte Van & Storage Co. Building 1, Clubhouse, & Maintenance Building Charlotte, Mecklenburg County Brownfields Project No. 23057-19-060 Dear Mr. Foster: The North Carolina Department of Environmental Quality’s Brownfields Redevelopment Section (DEQ Brownfields) received the VIMS Post-Occupancy Sampling Report – Building 1, Clubhouse, & Maintenance Building, dated August 8, 2023 (Report) submitted on your behalf by Ms. Haley Martin of Hart & Hickman, PC. DEQ Brownfields has reviewed the Report and evaluated the sub-slab vapor and indoor air data using the DEQ Risk Calculator. As noted in the report, the risk evaluation for sub-slab vapor data indicates that calculated risks are below the DEQ threshold for residential use, but calculated risk for indoor air data exceeds the DEQ non-carcinogenic risk threshold. The primary risk driver is isopropyl alcohol which report suggests may be associated with potential indoor air sources such as cleaning solutions. Attenuation of other volatile organic compounds (VOCs) across the floor slab would tend to support that conclusion. The indoor air and sub-slab vapor data will be re-evaluated following the next semi-annual post-occupancy vapor intrusion sampling event for Building 1. During the next event, please document in the pre-sampling survey any use of materials that may contribute to indoor air concentrations and provide MSDSs as warranted. To the extend practical, low VOC materials should be used on-site to avoid possible indoor air exceedances. Please be advised that this compliance review from DEQ Brownfields does not waive any applicable requirement to obtain necessary permits, licenses or certifications which may be required from other state or local entities. Patrick Foster August 24, 2023 Page 2 If you have questions, please contact me at (984) 275-5391, or by e-mail at peter.doorn@deq.nc.gov. Sincerely, Peter L. Doorn Brownfields Project Manager ec: Patrick Foster, LMC Christie Zawtocki, Hart & Hickman Haley Martin, Hart & Hickman Ralph McGee, Hart & Hickman Tracy Wahl, DEQ Brownfields Kevin Slaughter, DEQ Brownfields Via Email August 8, 2023 NCDEQ – Division of Waste Management Brownfields Redevelopment Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attn: Mr. Pete Doorn Re: VIMS Post-Occupancy Sampling Report Building 1, Clubhouse, & Maintenance Building Charlotte Van and Storage Co. Charlotte, North Carolina Brownfields Project No. 23057-19-060 H&H Project No. LEN-008 Dear Pete: On behalf of Quarterra Multifamily, enclosed please find a copy of the VIMS Post-Occupancy Sampling Report prepared for Building 1, the Clubhouse, and the Maintenance Building recently constructed at the Charlotte Van and Storage Co. Brownfields property located in Charlotte, Mecklenburg County. Should you have questions or need additional information, please do not hesitate to contact us at (704) 586-0007. Sincerely, Hart & Hickman, PC Christie Zawtocki, PE Haley Martin, PG Principal Senior Project Geologist Enclosures cc: Mr. Patrick Foster, Quarterra (Via Email) i S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Post-Occupancy\Bld 1, Clubhouse, Maint\Report\23057 - Charlotte Van & Storage Co - VIMS Post-Occupancy Sampling Report.docx VIMS Post-Occupancy Sampling Report Building 1, Clubhouse, & Maintenance Building Charlotte Van and Storage Co. Charlotte, North Carolina H&H Job No. LEN-008 Table of Contents Section Page No. 1.0 Introduction .............................................................................................................................1  2.0 Vapor Intrusion Mitigation System Installation ..................................................................3  3.0 Post-Occupancy VIMS Effectiveness Sampling ...................................................................4  3.1 Sub-Slab Soil Vapor Sampling ..............................................................................................4  3.1.1 Sub-Slab Soil Vapor Sampling Methodology................................................................ 4  3.1.2 Sub-Slab Soil Vapor Results .......................................................................................... 5  3.1.3 Sub-Slab Soil Vapor Risk Evaluation ............................................................................ 7  3.2 Indoor Air Sampling Activities .............................................................................................8  3.2.1 Building Survey Activities ............................................................................................. 9  3.2.2 Indoor Air Sampling Methodology ................................................................................ 9  3.2.3 Indoor Air Sampling Results ....................................................................................... 10  3.2.4 Indoor Air Risk Evaluation .......................................................................................... 12  4.0 Summary and Conclusions ..................................................................................................14  List of Tables Table 1 Summary of Sub-Slab Soil Vapor Analytical Results Table 2 Summary of Building 1 Indoor Air Analytical Results Table 3 Comparison of Sub-Slab Soil Vapor and Indoor Air Analytical Results List of Figures Figure 1 Site Location Map Figure 2 Site Map ii s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx List of Appendices Appendix A VIMS As-Built Drawings (VM-1, VM-2, VM-3 & VM-5) Appendix B Field Forms Appendix C Laboratory Analytical Report Appendix D DEQ Risk Calculators 1 S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Post-Occupancy\Bld 1, Clubhouse, Maint\Report\23057 - Charlotte Van & Storage Co - VIMS Post-Occupancy Sampling Report.docx VIMS Post-Occupancy Sampling Report Building 1, Clubhouse, & Maintenance Building Charlotte Van and Storage Co. Charlotte, North Carolina H&H Job No. LEN-008 1.0 Introduction On behalf of Quarterra Multifamily (Quarterra), Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation system (VIMS) post-occupancy indoor air and sub- slab sampling activities completed for Building 1, the Clubhouse, and the Maintenance Building associated with the Verbena Street Apartments multi-family development at the Charlotte Van and Storage Co. Brownfields property (Brownfields Project No. 23057-19-060). The Brownfields property is located at the intersection of Verbena Street and Gilead Street in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). The Site consists of one approximately 5.8-acre parcel of land (Parcel Identification No. 14903412) located in a mixed residential, commercial, and industrial use area of lower South End Charlotte. A Site location map is provided as Figure 1, and a Site map is provided as Figure 2. The Site has been redeveloped with two apartment buildings (distinguished as Building 1 and Building 2), a Clubhouse, a Maintenance Building, and associated vehicle access and parking areas. Building 1 is a four-story apartment building with a 31,302 square foot (sq ft) ground floor footprint that includes for-rent residential units, a leasing office, a mail room, and mechanical rooms. Building 2 is a five-story apartment building with a split first level. The Clubhouse is a single-story approximately 3,650-sq ft detached building used as a common space and recreational area for the residential tenants. The Maintenance Building is a single-story approximately 1,145- sq ft structure used as a workspace and equipment/materials storage area for maintenance personnel. No residential use is planned for the Clubhouse or Maintenance Building. This report documents VIMS post-occupancy sampling for Building 1, the Clubhouse, and the Maintenance Building. A separate report will be submitted for Building 2. A Brownfields Agreement was recorded for the Site on September 10, 2021. Results of previous assessment activities indicated that vapor mitigation was warranted for Building 1, Building 2, the 2 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx Clubhouse, and the Maintenance Building. As such, a Vapor Intrusion Mitigation Plan (VIMP) was prepared and submitted to the North Carolina Department of Environmental Quality (DEQ). The VIMP revision dated August 11, 2021, was approved by DEQ in a letter dated August 12, 2021. VIMS installation activities for Building 1, the Clubhouse, and the Maintenance Building are documented in H&H’s VIMS Installation Completion Report dated January 13, 2023 and revised February 3, 2023. A brief summary of the VIMS is provided in Section 2.0, a discussion of post-occupancy sub-slab soil vapor and indoor air sampling activities is provided in Section 3.0, and a summary and conclusions based on the sampling results are provided in Section 4.0. 3 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx 2.0 Vapor Intrusion Mitigation System Installation As detailed in the VIMP, separate VIMSs were installed for Building 1, the Clubhouse, and the Maintenance Building. The VIMSs for Building 1 and the Clubhouse each include a permeable gravel layer, sub-slab vapor collection piping, vapor barrier, riser piping, and passive ventilators. The VIMS for the Maintenance Building includes a permeable gravel layer and vapor barrier. For Building 1 and the Clubhouse, passive sub-slab vapor extraction is achieved through an interconnected system of 3-inch Schedule (SCH) 40 PVC vapor collection/conveyance piping installed in a 4-inch permeable gravel layer beneath the building. The permeable gravel layer (clean #57) was installed beneath the entirety of the buildings to enhance sub-slab vapor transmission and allow for air movement beneath the slabs. In Building 1 and the Clubhouse, the sub-slab vapor collection piping is connected to 3-inch riser piping which extends vertically through the buildings and discharges vapors through exhaust stacks installed above the building roofs. Empire syphon ventilators were installed on the discharge end of the exhaust stacks on the roofs. For each building, a vapor barrier (Vaporblock® Plus™ 20) was installed above the gravel layer and beneath the concrete slab. VIMS as-built drawings are provided in Appendix A. 4 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx 3.0 Post-Occupancy VIMS Effectiveness Sampling The DEQ-approved VIMP states that post-occupancy sampling events will be completed semi- annually to evaluate effectiveness of the VIMS. In compliance with the approved VIMP, the first post-occupancy sampling event was performed approximately six months after the pre-occupancy sampling event and is documented herein. Eight sub-slab soil vapor samples were collected from Building 1, one sub-slab soil vapor sample was collected from the Clubhouse, and one sub-slab soil vapor sample was collected from the Maintenance Building. In addition, three indoor air samples were collected from Building 1 concurrent with the sub-slab soil vapor samples. The sub-slab soil vapor and indoor air assessment activities were conducted in general accordance with the DEQ-approved VIMP and the DEQ Department of Waste Management (DWM) Vapor Intrusion Guidance (Guidance) dated March 2018. Details of the sub-slab soil vapor and indoor air sampling activities and results are provided in the following sections. 3.1 Sub-Slab Soil Vapor Sampling On June 22, 2023, H&H collected sub-slab soil vapor samples from select permanent monitoring points within each building. The sub-slab soil vapor samples were collected from permanent monitoring points MP-1 in the Maintenance Building, MP-2 through MP-9 in Building 1, and MP- 10 in the Clubhouse (see sample locations on VM-3 and VM-5 in Appendix D). For quality assurance/quality control (QA/QC) purposes, one duplicate sub-slab soil vapor sample (SS-MP- DUP) was collected from the MP-2 parent location. The duplicate sample was collected utilizing a laboratory-supplied stainless-steel sampling “T” fitting which allows for the simultaneous collection of two sub-slab soil vapor samples from a single location. The sub-slab soil vapor sampling methodology, results, and risk evaluation are discussed below. 3.1.1 Sub-Slab Soil Vapor Sampling Methodology The sub-slab soil vapor samples were collected from the permanent monitoring points by securing Teflon sample tubing to either the vapor pin or to a 2-inch expandable well cap with a sampling 5 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx port that was secured onto the 2-inch diameter PVC monitoring point. The tubing was connected to a laboratory-supplied airflow regulator and batch-certified 1.4-liter stainless steel Summa canister using a nut and ferrule assembly to create an airtight seal. The airflow regulator was preset by the laboratory to collect a soil vapor sample over a 10-minute period at a flow rate no greater than approximately 140 milliliters per minute. Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a shroud around the monitoring point and sampling train including the Summa canister. The air within the shroud was flooded with helium vapor and concentrations within the shroud were measured with a calibrated helium detector. Helium concentrations within the shroud were maintained between approximately 10% and 15%. A GilAir vacuum pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three volumes (monitoring point and sample train) of soil vapor into a Tedlar® bag at each sampling point. The helium detector was used to measure helium concentrations within the Tedlar bag sample to confirm helium concentrations in the sample train were less than 10% of that measured within the shroud. Results of the helium leak checks indicated that short-circuiting at the monitoring points or within the sampling train was not present. Field forms completed by sampling personnel are included in Appendix B. Following successful leak checks, the airflow regulators were opened to allow collection of the sub-slab soil vapor samples. Vacuum in the Summa canisters was monitored during the sampling event to confirm adequate sample volume was collected at each monitoring point location. Upon completion of sample collection, the airflow regulator was closed to the Summa canister. The canisters were labeled with the sample identification, beginning and ending times, pressure measurements, and the requested analysis. The canisters were then placed in laboratory-supplied shipping containers and delivered to Waypoint Analytical (Waypoint) under standard chain of custody protocols for analysis of volatile organic compounds (VOCs) by EPA Method TO-15. 3.1.2 Sub-Slab Soil Vapor Results The sub-slab soil vapor sample analytical results are summarized in Table 1. The Maintenance Building and Clubhouse results were compared to the DEQ Non-Residential Vapor Intrusion Sub- 6 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx slab and Exterior Soil Gas Screening Levels (SGSLs), and the Building 1 results were compared to the DEQ Residential and Non-Residential Vapor Intrusion SGSLs dated January 2023. Copies of the laboratory analytical report and the chain of custody record are provided in Appendix C. Maintenance Building Laboratory analytical results for the Maintenance Building indicate the presence of several compounds at concentrations above laboratory method detection limits (MDLs) in the sub-slab soil vapor sample. However, no compounds were detected at concentrations above the Non- Residential SGSLs. Tetrachloroethene (PCE) and trichloroethene (TCE) were detected at concentrations of 3.14 micrograms per cubic meter (µg/m3) and 0.999 µg/m3, respectively, which are substantially below the Non-Residential SGSLs of 3,500 µg/m3 and 180 µg/m3, respectively. Building 1 Laboratory analytical results for Building 1 indicate the presence of several compounds at concentrations above laboratory MDLs in the sub-slab soil vapor samples. Only two compounds, chloroform and naphthalene, were detected at concentrations above Residential SGSLs. Chloroform was detected at concentrations above its Residential SGSL of 4.1 µg/m3 in samples SS-MP-3 through SS-MP-9 (ranging from 7.62 µg/m3 to 40.2 µg/m3). Naphthalene was reported in sample SS-MP-6 (4.15 µg/m3) above its Residential SGSL of 2.8 µg/m3. No other compounds were detected at concentrations above DEQ Residential Vapor Intrusion SGSLs, and no compounds were detected above the DEQ Non-Residential Vapor Intrusion SGSLs. PCE was detected in four of the Building 1 sub-slab soil vapor samples (SS-MP-3 through SS- MP-6) at concentrations above the laboratory MDL but below the Residential SGSL of 280 µg/m3, ranging from 1.10 µg/m3 to 40.2 µg/m3. TCE was not detected at concentrations above the laboratory MDL in any of the sub-slab soil vapor samples collected from Building 1. Clubhouse Laboratory analytical results for the Clubhouse indicate the presence of several compounds at concentrations above laboratory MDLs, but below the DEQ Non-Residential Vapor Intrusion SGSLs. PCE and TCE were not detected at concentrations above the laboratory MDL. 7 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx 3.1.3 Sub-Slab Soil Vapor Risk Evaluation The DEQ Vapor Intrusion SGSLs are conservative and based on a Target Carcinogenic Risk (TCR) of 1 x 10-6 and a Target Hazard Quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ and EPA acceptable risk level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1 x 10-4 or less, and the acceptable level for non-carcinogenic risks is a cumulative hazard index (HI) of 1.0 or less. The HI is the sum of hazard quotients (HQs) for each target analyte detected in a sample. To further evaluate sub-slab soil vapor concentrations, H&H utilized the DEQ Risk Calculator (January 2023) to calculate potential vapor intrusion risks for each building. H&H modeled a worst-case scenario for Building 1, the Clubhouse, and the Maintenance Building by using the highest concentrations of any compound detected below the slab of each building. Based on the planned uses of the buildings, H&H calculated risks for the Maintenance Building and Clubhouse assuming a non-residential use scenario, and both residential and non-residential use scenarios for Building 1. The calculated cumulative LICR and HI values are provided in Table 1, and copies of the completed DEQ Risk Calculators are provided in Appendix D. Results of risk calculations for each Site building are discussed below. Maintenance Building As shown in Table 1, the non-residential worst-case risk calculation for the Maintenance Building indicates a calculated cumulative LICR of 1.1 x 10-6 and a HI value of 0.0089. The calculated cumulative LICR and HI values are within the acceptable levels established by the DEQ and EPA. Thus, the sub-slab soil vapor analytical results and risk calculations indicate that the detected sub- slab soil vapor concentrations do not pose potential vapor intrusion risks at unacceptable levels for the Maintenance Building. Building 1 As shown in Table 1, results of the worst-case risk calculations for Building 1 indicate a calculated cumulative LICR of 1.2 x 10-5 and a HI value of 0.36 for a residential use scenario and a cumulative 8 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx LICR of 9.4 x 10-7 and a HI value of 0.028 for a non-residential use scenario. Risk calculator results indicate that under a hypothetical worst-case scenario for both residential and non- residential use for Building 1, the cumulative LICR is less than 1 x 10-4 and the cumulative HI is less than 1.0. Thus, the sub-slab soil vapor analytical results and risk calculations indicate that the VIMS is effectively minimizing the sub-slab accumulation of compounds at concentrations that would pose potential vapor intrusion risks at unacceptable levels for Building 1. Clubhouse As shown in Table 1, results of the non-residential worst-case risk calculation for the Clubhouse indicate a calculated cumulative LICR of 2.8 x 10-8 and a HI value of 0.0015. The calculated non- residential cumulative LICR and HI values are within the DEQ and EPA acceptable levels. Thus, the sub-slab soil vapor analytical results and risk calculations indicate that the VIMS is effectively minimizing the sub-slab accumulation of compounds at concentrations that would pose potential vapor intrusion risks at unacceptable levels for the Clubhouse building. 3.2 Indoor Air Sampling Activities On June 21 and 22, 2023, H&H collected three indoor air samples (IAS-1, IAS-2, and IAS-3) from within Building 1. The indoor air samples were collected prior to collection of sub-slab soil vapor samples to avoid potential cross-contamination associated with temporarily opening and purging the sub-slab monitoring points. The June 2023 indoor air sampling was performed approximately six months after the pre-occupancy sampling event. Note, the pre-occupancy sample location for IAS-3 was in the neighboring unit; however, due to the leasing activities, it was moved to the adjacent residential unit. This location change was discussed with and approved by Mr. Peter Doorn with the DEQ Brownfields Program prior to the sampling event. Each sample was located in a finished residential unit. In addition to the indoor air samples, an exterior background ambient air sample (IAS-BKG) was collected at the time of the indoor air sampling event. The location of the background sample was upwind of Building 1 as determined on the day of the sampling event based on the prevailing wind 9 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx direction. The locations of the indoor air and background air samples are shown on Sheet VM-3 of Appendix A. 3.2.1 Building Survey Activities Prior to collecting indoor air samples, H&H completed a survey within Building 1 to identify potential above-slab sources of VOCs. At the time of sampling, the units were empty and had not been occupied since the completion of the building. H&H observed moderate to heavy vehicular use on Verbena Street and the use of heavy equipment for construction-related purposes on-Site. The heating, ventilation, and air conditioning (HVAC) system for Building 1 was active at the time of indoor air sampling; thus, the samples were representative of normal living conditions. Copies of the indoor air building survey form and the sampling forms completed by H&H sampling personnel during the indoor air sampling event are included in Appendix B. 3.2.2 Indoor Air Sampling Methodology The background and indoor air samples were collected using 6-liter stainless steel Summa sample canisters connected to in-line flow controllers with a vacuum gauge. The indoor air samples were collected using individually-certified Summa canisters, and the outdoor air sample was collected using a batch-certified Summa canister. The flow controllers were set by the laboratory to allow collection of the samples over a 24-hour period. The sample intake point for each canister was positioned approximately 5 ft above grade (typical breathing zone height). One duplicate indoor air sample (IAS-DUP) was collected for quality assurance/quality control (QA/QC) purposes from the IAS-3 parent location during the sampling event. The duplicate sample was collected utilizing a laboratory-supplied stainless-steel sampling “T” fitting which allows for the simultaneous collection of two indoor air samples from a single location. During the sampling activities, indoor/outdoor air pressure differential was measured for the building near the start, middle, and end of the 24-hour sampling period using a manometer sensitive to 0.001 inches of water. In addition, Site-specific weather conditions including exterior wind speed, exterior wind direction, indoor/outdoor temperature, barometric pressure, and 10 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx precipitation were recorded near the start, middle, and end of the sampling period. Indoor air sampling field forms completed by sampling personnel are included in Appendix B. Prior to and after the indoor and background air samples were collected, vacuum in the canisters was measured using a laboratory-supplied vacuum gauge and recorded by sampling personnel. The starting vacuum was within 10% of the vacuum when the Summa canisters left the laboratory. Vacuum within the sample canisters was not allowed to reach 0 inches of mercury; each sample was collected when the canister reached approximately 5 inches of mercury. The starting and ending vacuums in each canister were recorded by sampling personnel on the sample chain of custody. The sample canisters were labeled, packaged in a laboratory provided container, and shipped under standard chain of custody protocols to Waypoint for analysis of a select list of VOCs by TO-15. The target analyte list was determined based on the VOCs detected in the sub-slab soil vapor samples and was approved by Mr. Peter Doorn with the DEQ Brownfields Program in an email dated July 5, 2023. A list of the select VOCs analyzed is included in the laboratory analytical report provided in Appendix C. 3.2.3 Indoor Air Sampling Results The indoor air analytical results are summarized in Table 2 and were compared to the DEQ Residential and Non-Residential Vapor Intrusion Indoor Air Screening Levels (IASLs) dated January 2023. Copies of the laboratory analytical report and chain of custody record are provided in Appendix C. The indoor air sample analytical results indicate that several compounds were detected at concentrations above laboratory MDLs. Three compounds (benzene, chloroform, and isopropyl alcohol) were detected in one or more samples at concentrations above the DEQ Residential Vapor Intrusion IASLs, and one compound (chloroform) was detected in two samples (and the duplicate) at concentrations above the DEQ Non-Residential IASL. A brief discussion of the compounds detected above IASLs is provided below. PCE was detected above the laboratory MDL but below the Residential IASL of 8.3 µg/m3 in one indoor air sample (IAS-3) and the associated duplicate 11 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx sample (IAS-DUP) collected in the east portion of Building (0.922 µg/m3 and 0.732 J µg/m3 respectively). TCE was not detected above the laboratory MDL in any of the indoor air samples. Benzene was detected in each of the indoor air samples at concentrations ranging from 0.559 J µg/m3 to 0.836 J µg/m3. Benzene was also detected in the background, outdoor air sample at a concentration of 0.485 J µg/m3 and was detected in one of the laboratory blank samples at a concentration of 0.571 µg/m3. Table 3 provides a comparison of the sub-slab soil vapor and indoor air sample data. As shown in the table, the detected sub-slab vapor benzene concentrations are lower than the detected indoor air benzene concentrations. Thus, the detected indoor air concentrations of benzene are attributable to outdoor air, laboratory contamination, and/or above- slab sources. Chloroform, was detected in two of the indoor air samples and the associated duplicate sample (IAS-2, IAS-3, and IAS-DUP) at concentrations ranging from 0.786 J µg/m3 to 0.854 J µg/m3, which exceed the DEQ Residential IASL of 0.12 µg/m3and the Non-Residential IASL of 0.53 µg/m3. Each of the detected concentrations of chloroform are J-flag values, indicating that the detected concentrations are above the laboratory MDL, but below the laboratory calibrated reporting limit resulting in laboratory estimated values. Chloroform is found in chlorinated municipal water supplies and is released from water use indoors. As such, chloroform is ubiquitous in indoor air, and the detected indoor air concentrations are not believed to be associated with vapor intrusion. Isopropyl alcohol was detected in two of the indoor air samples and the duplicate sample (56.5 µg/m3 in IAS-1, 134 µg/m3 in IAS-3, and 122 µg/m3 in IAS-DUP) at concentrations above the Residential IASL. The detected indoor air concentrations are higher than the detected sub-slab soil vapor concentrations (Table 3); thus, it appears that the detected concentrations of isopropyl alcohol in the indoor air samples are attributable to an above-slab source. Isopropyl alcohol is commonly found in household cleaning products that would have been used during the finishing activities within the units. 12 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx 3.2.4 Indoor Air Risk Evaluation The DEQ Vapor Intrusion IASLs are conservative and based on a TCR for potential carcinogenic risks of 1 x 10-6 and a THQ of 0.2 for potential non-carcinogenic risks and only apply to indoor air contaminants from structural vapor intrusion. The DEQ and EPA acceptable risk level for potential carcinogenic risks is a cumulative LICR of 1 x 10-4 or less and the acceptable level for non-carcinogenic risks is a HI of 1.0 or less. H&H utilized the DEQ Risk Calculator (January 2023) to evaluate risks associated with the detected indoor air concentrations. Risk calculations were completed for both residential and non- residential use scenarios based on the planned use of Building 1. A conservative, worst-case scenario was evaluated using the highest concentration of any compound detected within any Building 1 indoor air sample. The calculated cumulative LICR and HI values are discussed below and are summarized in Table 2. The calculated risks for a hypothetical worst-case residential scenario for Building 1 indicate the cumulative LICR is 1.2 x 10-5 and the HI is 1.4. The calculated worst-case non-residential risks indicate the cumulative LICR is 2.8 x 10-6 and the cumulative HI is 0.35. The cumulative residential and non-residential LICRs and non-residential HI are within the acceptable risk levels; however, the HI for a residential use scenario exceeds the acceptable risk level of 1.0. Review of the risk calculations indicates that isopropanol (isopropyl alcohol) is the primary driver of the HI exceedance, contributing 0.64 to the total. As mentioned previously, the indoor air concentrations of isopropyl alcohol were higher than the detected sub-slab soil vapor concentrations, and isopropyl alcohol is found in many cleaning products. Thus, the presence of isopropyl alcohol in indoor air is attributable to cleaning materials and is not attributable to environmental impacts identified at the Site. The calculated cumulative LICR and HI values include compounds that are attributable to outdoor, background air sources, laboratory contamination, and/or above-slab sources, as discussed above. 13 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx Thus, the calculated cumulative risks are conservative and are not fully attributable to vapor intrusion. Copies of the completed risk calculators are provided in Appendix D. 14 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx 4.0 Summary and Conclusions H&H completed the first VIMS post-occupancy sampling event for Building 1, the Clubhouse, and the Maintenance Building at the Verbena Apartments, which have been completed at the Charlotte Van & Storage Co. Brownfields property (Brownfields Project No. 23057-19-060). The sub-slab soil vapor and indoor air assessment activities are summarized below. VIMS Effectiveness Testing – Sub-Slab Soil Vapor Sub-slab soil vapor samples were collected from Building 1, the Clubhouse, and the Maintenance Building to evaluate the effectiveness of the VIMS. For Building 1, only two compounds (chloroform and naphthalene) were detected in the sub-slab soil vapor samples at concentrations above the DEQ Residential Vapor Intrusion SGSLs and no compounds were detected at concentrations above the DEQ Non-Residential Vapor Intrusion SGSLs. Risk calculator results indicate that under a hypothetical worst-case scenario for both residential and non-residential use for Building 1, the cumulative LICR is less than 1 x 10-4 and the cumulative HI is less than 1.0. The sub-slab soil vapor laboratory analytical results for the Clubhouse and the Maintenance Building did not identify compounds of concern at concentrations above the DEQ Non-Residential Vapor Intrusion SGSLs. Results of the non-residential use scenario hypothetical worst-case risk calculations completed for each building indicated acceptable risk levels. Based on the sub-slab soil vapor data and the DEQ Risk Calculator results, the detected sub-slab vapor concentrations at the Site do not pose an unacceptable vapor intrusion risk. VIMS Effectiveness Testing – Building 1 Indoor Air In accordance with the DEQ-approved VIMP, post-occupancy indoor air samples were collected from Building 1. The analytical results indicate that several VOCs were detected in the samples at concentrations above laboratory MDLs. Three compounds (benzene, chloroform, and isopropyl alcohol) were detected above DEQ Residential Vapor Intrusion IASLs, and one compound (chloroform) was detected above DEQ Non-Residential Vapor Intrusion IASLs. The compounds detected in indoor air at concentrations above IASLs are attributed to outdoor sources and/or 15 s:\aaa-master projects\lennar (len)\len-008 verbena assemblage\vims post-occupancy\bld 1, clubhouse, maint\report\23057 - charlotte van & storage co - vims post-occupancy sampling report.docx above-slab sources. PCE was detected above the laboratory MDLs in one indoor air sample and the associated duplicate sample at low concentrations an order of magnitude below the DEQ DWM Residential Vapor Intrusion IASL. Results of the hypothetical worst-case risk calculations for Building 1 indicated acceptable risk levels for the cumulative residential LICR, non-residential LICR, and non-residential HI; however, the residential HI exceeded the DEQ and EPA acceptable level of 1.0. The residential HI exceedance was primarily due to the concentration of isopropyl alcohol in sample IAS-3 and is not associated with vapor intrusion. Summary Based on the post-occupancy sub-slab soil vapor and indoor air sampling results, the VIMS is effectively mitigating potential vapor intrusion risks at Building 1, the Clubhouse, and the Maintenance Building. In accordance with the DEQ-approved VIMP, post-occupancy sub-slab soil vapor sampling will continue on a semi-annual basis for future events. For Building 1, indoor air sampling will be completed concurrent with the second post-occupancy sub-slab soil vapor sampling event. If semi-annual sampling results indicate consistent or decreasing concentrations within acceptable risk levels, a request to modify or terminate sampling will be submitted for DEQ approval. After each post-occupancy sampling event, a brief report will be submitted to DEQ to document the sampling activities and results. Table 1 Summary of Sub-Slab Soil Vapor Analytical Results Building 1, Clubhouse, and Maintenance Building Charlotte Van and Storage Co.Charlotte, North CarolinaH&H Project No. LEN-008 Building ID Maintenance Clubhouse Sample ID SS-MP-1 SS-MP-3 SS-MP-4 SS-MP-5 SS-MP-6 SS-MP-7 SS-MP-8 SS-MP-9 SS-MP-10 Sample Date Units VOCs (TO-15) Acetone 46.5 249 252 118 134 763 96.0 5,970 93.1 38.8 76.0 NE NE Benzene 3.56 0.875 J 1.06 J 0.396 J 0.373 J 0.523 J 0.287 J <1.46 <0.146 0.696 J <0.073 12 160 Bromodichloromethane <0.150 <0.299 <0.299 <0.150 <0.150 <0.299 <0.150 <3.00 1.23 J 1.39 J <0.150 2.5 33 Carbon Disulfide 2.54 J 1.49 J 2.50 J 1.60 J 0.971 J 1.25 J 0.965 J 4.61 J 0.741 J 1.26 J 0.759 J 4,900 61,000 Chloroform 51.3 2.97 J 2.97 J 22.1 9.83 22.5 40.2 7.62 J 12.8 26.7 1.43 J 4.1 53 Chloromethane <0.067 2.14 <0.134 0.877 J <0.067 1.65 J <0.067 <1.34 0.631 J <0.067 <0.067 630 7,900 Cyclohexane 3.19 J <0.321 <0.321 <0.161 2.36 J <0.321 <0.161 <3.22 <0.321 1.92 J <0.161 42,000 530,000 1,4-Dichlorobenzene 1.02 J <0.371 <0.371 <0.186 <0.186 <0.371 <0.186 <3.72 <0.371 <0.186 <0.186 8.5 110 Dichlorodifluoromethane <0.134 2.73 J 2.75 J 2.64 2.45 J 2.54 J 2.37 J <2.68 2.99 J 3.14 2.57 700 8,800 cis-1,2-Dichloroethene 4.47 <0.190 <0.190 <0.095 <0.095 <0.190 <0.095 <1.91 <0.190 <0.095 <0.095 NE NE 1,2-Dichloropropane 2.45 <0.409 <0.409 <0.205 <0.205 <0.409 2.16 J <4.10 <0.409 0.563 J <0.205 25 330 1,2-Dichlorotetrafluoroethane 58.5 <1.24 <1.24 <0.622 <0.622 <1.24 <0.622 <12.4 <1.24 <0.622 <0.622 NE NE Ethyl Acetate <0.136 2.83 J 3.79 3.15 0.799 J <0.271 2.21 <2.72 1.83 J 1.92 14.8 490 6,100 Ethylbenzene 24.7 4.57 4.49 0.998 J 0.694 J 1.53 J 0.351 J <2.12 <0.211 0.325 J 0.534 J 37 490 4-Ethyltoluene <0.128 1.14 J 1.03 J 0.584 J <0.128 <0.256 <0.128 <2.56 <0.256 <0.128 <0.128 NE NE Heptane 0.848 J 2.48 J 2.64 J 0.368 J 0.704 J 1.12 J 0.864 J <2.86 <0.286 0.651 J 0.356 J 2,800 35,000 n-Hexane 2.07 1.10 J 1.21 J <0.047 <0.047 <0.094 0.271 J <0.942 <0.094 1.67 J 0.437 J 4,900 61,000 2-Hexanone <0.285 1.98 J 1.87 J <0.285 1.34 J 5.75 2.47 <5.71 1.22 J <0.285 <0.285 210 2,600 Isopropyl Alcohol 289 30.4 31.9 13.9 22.3 103 16.2 21.6 J 8.43 J 7.90 3.48 J 1,400 18,000 Methyl Ethyl Ketone (MEK)1.76 295 253 842 1,160 3,780 2,020 630 1,170 141 274 35,000 440,000 Methyl tert-butyl ether (MTBE)0.407 J <0.067 <0.067 <0.033 <0.033 <0.067 <0.033 <0.672 <0.067 <0.033 <0.033 360 4,700 4-Methyl-2-Pentanone 0.356 J 1.05 J 0.950 J <0.121 0.512 J 1.45 J 0.696 J <2.42 <0.242 0.331 J <0.121 21,000 260,000 Methylene Chloride 3.84 <0.975 <0.975 <0.488 <0.488 <0.975 <0.488 <9.75 <0.975 4.93 <0.488 3,400 53,000 Naphthalene <0.183 <0.365 <0.365 <0.183 <0.183 <0.365 4.15 <3.66 <0.365 <0.183 <0.183 2.8 36 Styrene 4.60 1.76 J 1.89 J 0.796 J 2.28 5.95 1.19 J <2.48 <0.248 <0.124 <0.124 7,000 88,000 Tetrachloroethene 3.14 B, J <0.361 <0.361 1.70 J 40.2 3.64 J 1.10 J <3.62 <0.361 <0.181 <0.181 280 3,500 Tetrahydrofuran 22.2 3,690 3,840 1,910 1,840 4,180 3,070 14,000 4,860 375 601 14,000 180,000 Toluene 15.1 59.7 60.4 7.19 9.77 28.7 4.37 8.14 J 6.63 4.12 5.04 35,000 440,000 Trichloroethene 0.999 J <0.398 <0.398 <0.199 <0.199 <0.398 <0.199 <3.98 <0.398 <0.199 <0.199 14 180 Trichlorofluoromethane 20.2 1.84 J 1.88 J 2.10 J 1.89 J 2.72 J 2.33 J <2.60 3.16 J 4.26 2.00 J NE NE 1,2,4-Trimethylbenzene 1.27 J 4.51 J 4.58 J 2.66 1.05 J 2.03 J 0.884 J <2.20 <0.220 0.511 J 0.535 J 420 5,300 1,3,5-Trimethylbenzene <0.236 1.86 J 1.78 J 0.771 J <0.236 <0.472 <0.236 <4.72 <0.472 <0.236 <0.236 420 5,300 Vinyl Chloride <0.127 <0.254 <0.254 <0.127 <0.127 <0.254 <0.127 <2.54 <0.254 <0.127 <0.127 5.6 280 m,p-Xylene 33.2 22.3 21.9 5.64 J 3.39 J 7.61 J 2.33 J <4.34 3.16 J 2.13 J 2.34 J 700 8,800 o-Xylene 9.09 6.30 6.62 1.90 J 1.09 J 2.26 J 0.599 J <3.14 <0.313 0.503 J 0.673 J 700 8,800 DEQ Risk Calculator (2) Cumulative LICR ---- Cumulative HI ---- DEQ Risk Calculator (2) Cumulative LICR 1.1 x 10-6 2.8 x 10-8 Cumulative HI 0.0089 0.0015 Notes: 1)North Carolina Department of Environmental Quality (NCDEQ) Vapor Intrusion Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated January 2023 and based on a TCR of 1 x 10-6 and a THQ of 0.2. 2)NCDEQ Risk Calculator dated January 2023. EPA analytical method shown in parenthesis. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Compound concentrations are reported to the laboratory method detection limit. Only compounds detected in at least one sample and select chlorinated compounds are shown in the table above. Refer to laboratory analytical report for all compounds. Worst case risk calculations include highest concentration of any compound detected in any sample. Bold value indicates an exceedance of the Residential SGSL. VOCs = volatile organic compounds; TCR = target cancer risk; THQ = target hazard quotient; LICR = lifetime incremental cancer risk; HI = noncarcinogenic hazard index; NE = not established; -- = not applicable B = Analyte was detected in laboratory blank. J = Detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit resulting in a laboratory estimated value. 0.028 < 1.0 Worst Case Non-Residential - Soil Gas to Indoor Air Acceptable Risk Levels 9.4 x 10-7 < 1.0 x 10-4 Building 1 Acceptable Risk Levels SS-MP-2 / SS-MP-DUP Screening Criteria (1) 6/22/2023 Residential SGSLs Non-Residential SGSLs < 1.0 x 10-4 < 1.00.36 1.2 x 10-5 Worst Case Residential - Soil Gas to Indoor Air µg/m3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Lennar (LEN)/LEN-008 Verbena Assemblage/VIMS Post-Occupancy/Bld 1, Clubhouse, Maint/Tables/IA-SSV Data Tables 7/28/2023 Table 1 (Page 1 of 3)Hart & Hickman, PC Table 2 Summary of Building 1 Indoor Air Analytical Results Charlotte Van and Storage Co. Charlotte, North Carolina H&H Project No. LEN-008 Building ID Outdoor Air Sample ID IAS-1 IAS-2 IAS-BKG Sample Date Units VOCs (TO-15) Acetone 458 39.2 387 360 21.3 NE NE Benzene 0.836 B, J 0.559 B, J 0.721 J 0.690 B, J 0.485 B, J 0.36 1.6 Carbon Disulfide 0.909 B, J <0.060 1.18 J 0.688 B, J 0.295 B, J 150 610 Chloroform <0.086 0.854 J 0.786 J 0.800 J <0.086 0.12 0.53 Chloromethane 0.999 J 0.976 J 1.08 1.14 0.850 J 19 79 Dichlorodifluoromethane 2.65 18.1 2.43 J 2.59 2.59 21 88 Ethyl Acetate 1.20 J 0.428 J 2.55 3.09 <0.136 15 61 Ethylbenzene 2.26 0.369 J 3.07 3.23 <0.106 1.1 4.9 Heptane 7.48 0.762 J 5.45 5.36 <0.143 83 350 n-Hexane 2.65 0.764 J 1.85 2.04 <0.047 150 610 2-Hexanone 5.79 0.389 J 5.28 5.91 <0.285 6.3 26 Isopropyl Alcohol 56.5 6.94 134 122 2.09 J 42 180 Methyl Ethyl Ketone (MEK)30.0 3.81 41.1 43.9 2.08 1,000 4,400 4-Methyl-2-Pentanone 1.32 J <0.121 1.17 J 1.16 J <0.121 630 2,600 Methylene Chloride <0.488 0.562 J <0.488 <0.488 <0.488 100 530 Styrene 9.77 0.672 J 7.19 7.37 <0.124 210 880 Tetrachloroethene <0.181 <0.181 0.922 J 0.732 J <0.181 8.3 35 Tetrahydrofuran 17.3 0.693 J 20.6 21.7 <0.107 420 1,800 Toluene 57.0 4.17 B 57.3 57.1 1.02 B, J 1,000 4,400 Trichloroethene <0.199 <0.199 <0.199 <0.199 <0.199 0.42 1.8 Trichlorofluoromethane 1.73 J 35.4 1.54 J 1.57 J 1.52 J NE NE 1,2,4-Trimethylbenzene 4.42 2.40 J 3.80 5.05 <0.110 13 53 1,3,5-Trimethylbenzene 0.904 J <0.236 0.924 J 0.933 J <0.236 13 53 m,p-Xylene 8.34 1.92 J 13.2 13.7 <0.217 21 88 o-Xylene 2.58 0.377 J 3.92 4.07 <0.157 21 88 DEQ Risk Calculator (2) Cumulative LICR -- Cumulative HI -- DEQ Risk Calculator (2) Cumulative LICR -- Cumulative HI -- Notes:1) North Carolina Department of Environmental Quality (NCDEQ) Vapor Intrusion Indoor Air Screening Levels (IASLs) dated January 2023 and based on a TCR of 1 x 10-6 and a THQ of 0.2. 2) NCDEQ Risk Calculator dated January 2023. EPA analytical method shown in parenthesis. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Compound concentrations are reported to the laboratory method detection limit. Building 1 indoor air samples were collected over approximately 24-hours.The indoor air samples were analyzed for select compounds determined by the sub-slab soil vapor results and previous assessment results. Results for the select compounds are shown in the ta Building 1 worst case risk calculations include the highest concentration of any compound detected in any indoor air sample. Bold value indicates an exceedance of the Residential IASL or acceptable risk level. Underline value indicates an exceedance of the Non-Residential IASL. NE = not established; VOCs = volatile organic compounds; TCR = target cancer risk; THQ = target hazard quotient; LICR = lifetime incremental cancer risk; HI = noncarcinogenic hazard index B = Analyte was detected in laboratory blank. J = Detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit resulting in a laboratory estimated value. Worst Case Non-Residential - Indoor Air Acceptable Risk Levels 2.8 x 10-6 < 1.0 x 10-4 0.35 < 1.0 1.4 < 1.0 Building 1 Screening Criteria (1) IAS-3 / IAS-DUP Residential IASLs Non-Residential IASLs6/21/23 - 6/22/23 µg/m3 Worst Case Residential - Indoor Air Acceptable Risk Levels 1.2 x 10-5 < 1.0 x 10-4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Lennar (LEN)/LEN-008 Verbena Assemblage/VIMS Post-Occupancy/Bld 1, Clubhouse, Maint/Tables/IA-SSV Data Tables7/28/2023 Table 2 (Page 2 of 3) Hart & Hickman, PC Table 3 Comparison of Sub-Slab Soil Vapor and Indoor Air Analytical Results Building 1 Charlotte Van and Storage Co. Charlotte, North Carolina H&H Project No. LEN-008 Building ID Sample ID SS-MP-3 SS-MP-6 IAS-1 SS-MP-8 IAS-2 Sample Date 6/22/2023 6/22/2023 6/21/23 - 6/22/23 6/22/2023 6/21/23 - 6/22/23 Units VOCs (TO-15) Acetone 118 387 360 96.0 458 93.1 39.2 NE NE NE NE Benzene 0.396 J 0.721 J 0.690 B, J 0.287 J 0.836 B, J <0.146 0.559 B, J 12 160 0.36 1.6 Bromodichloromethane <0.150 <0.150 <0.150 <0.150 <0.150 1.23 J <0.150 2.5 33 0.076 0.33 Carbon Disulfide 1.60 J 1.18 J 0.688 B, J 0.965 J 0.909 B, J 0.741 J <0.060 4,900 61,000 150 610 Chloroform 22.1 0.786 J 0.800 J 40.2 <0.086 12.8 0.854 J 4.1 53 0.12 0.53 Chloromethane 0.877 J 1.08 1.14 <0.067 0.999 J 0.631 J 0.976 J 630 7,900 19 79 Dichlorodifluoromethane 2.64 2.43 J 2.59 2.37 J 2.65 2.99 J 18.1 700 8,800 21 88 1,2-Dichloropropane <0.205 <0.205 <0.205 2.16 J <0.205 <0.409 <0.205 25 330 0.76 3.3 Ethyl Acetate 3.15 2.55 3.09 2.21 1.2 J 1.83 J 0.428 J 490 6,100 15 61 Ethylbenzene 0.998 J 3.07 3.23 0.351 J 2.26 <0.211 0.369 J 37 490 1.1 4.9 4-Ethyltoluene 0.584 J <0.128 <0.128 <0.128 <0.128 <0.256 <0.128 NE NE NE NE Heptane 0.368 J 5.45 5.36 0.864 J 7.48 <0.286 0.762 J 2,800 35,000 83 350 n-Hexane <0.047 1.85 2.04 0.271 J 2.65 <0.094 0.764 J 4,900 61,000 150 610 2-Hexanone <0.285 5.28 5.91 2.47 5.79 1.22 J 0.389 J 210 2,600 6.3 26 Isopropyl Alcohol 13.9 134 122 16.2 56.5 8.43 J 6.94 1,400 18,000 42 180 Methyl Ethyl Ketone (MEK)842 41.1 43.9 2,020 30 1,170 3.81 35,000 440,000 1,000 4,400 4-Methyl-2-Pentanone <0.121 1.17 J 1.16 J 0.696 J 1.32 J <0.242 <0.121 21,000 260,000 630 2,600 Methylene Chloride <0.488 <0.488 <0.488 <0.488 <0.488 <0.975 0.562 J 3,400 53,000 100 530 Naphthalene <0.183 <0.183 <0.183 4.15 <0.183 <0.365 <0.183 2.8 36 0.083 0.36 Styrene 0.796 J 7.19 7.37 1.19 J 9.77 <0.248 0.672 J 7,000 88,000 210 880 Tetrachloroethene 1.70 J 0.922 J 0.732 J 1.10 J <0.181 <0.361 <0.181 280 3,500 8.3 35 Tetrahydrofuran 1,910 20.6 21.7 3,070 17.3 4,860 0.693 J 14,000 180,000 420 1,800 Toluene 7.19 57.3 57.1 4.37 57.0 6.63 4.17 B 35,000 440,000 1,000 4,400 Trichloroethene <0.199 <0.199 <0.199 <0.199 <0.199 <0.398 <0.199 14 180 0.42 1.8 Trichlorofluoromethane 2.10 J 1.54 J 1.57 J 2.33 J 1.73 J 3.16 J 35.4 NE NE NE NE 1,2,4-Trimethylbenzene 2.66 3.8 5.05 0.884 J 4.42 <0.220 2.4 J 420 5,300 13 53 1,3,5-Trimethylbenzene 0.771 J 0.924 J 0.933 J <0.236 0.904 J <0.472 <0.236 420 5,300 13 53 m,p-Xylene 5.64 J 13.2 13.7 2.33 J 8.34 3.16 J 1.92 J 700 8,800 21 88 o-Xylene 1.90 J 3.92 4.07 0.599 J 2.58 <0.313 0.377 J 700 8,800 21 88 Notes: 1) North Carolina Department of Environmental Quality (NCDEQ) Vapor Intrusion Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) and Indoor Air Screening Levels (IASLs) dated January 2023 and based on a TCR of 1 x 10-6 and a THQ of 0.2. EPA analytical method shown in parenthesis. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Compound concentrations are reported to the laboratory method detection limit. Only compounds detected in at least one sample and select chlorinated compounds are shown in the table above. Refer to laboratory analytical report for all compounds. Bold value indicates an exceedance of the Residential SGSL or Residential IASL. Underline value indicates an exceedance of the Non-Residential IASL. VOCs = volatile organic compounds; TCR = target cancer risk; THQ = target hazard quotient; NE = not established B = Analyte was detected in laboratory blank. J = Detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit resulting in a laboratory estimated value. IAS-3 / IAS-DUP 6/21/23 - 6/22/23 Residential SGSLs Non-Residential SGSLs μg/m3 Residential IASLs Non-Residential IASLs Building 1 Screening Criteria (1) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Lennar (LEN)/LEN-008 Verbena Assemblage/VIMS Post-Occupancy/Bld 1, Clubhouse, Maint/Tables/IA-SSV Data Tables 7/28/2023 Table 3 (Page 3 of 3) Hart & Hickman, PC USGS The National Map: National Boundaries Dataset, 3DEP Elevation Program, Geographic Names Information System, National Hydrography Dataset, National Land Cover Database, National Structures Dataset, and National Transportation Dataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S. Department of State Humanitarian Information Unit; and NOAA National Centers for Environmental Information, U.S. Coastal Relief Model. Data refreshed June, 2022. SITE LOCATION MAP CHARLOTTE VAN & STORAGE CO. VERBENA STREET AND GILEAD STREET CHARLOTTE, NORTH CAROLINA DATE: 8-2-2023 JOB NO: LEN-008 REVISION NO: 0 FIGURE NO: 1 2923 South Tryon Street - Suite 100 Charlotte, North Carolina 28203 704-586-0007 (p) 704-586-0373 (f) License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET SITE Path: S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\Final Grade Soil Sampling\Figures\Figure-1.mxdN U.S.G.S. QUADRANGLE MAP CHARLOTTE WEST, NORTH CAROLINA 2022 QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) LEGEND BROWNFIELDS PROPERTY BOUNDARY PARCEL BOUNDARY BAKER CONSTRUCTION CO. (129 VERBENA STREET) VACANT COMMERCIAL BUILDING (4516 NATIONS CROSSING ROAD) VE R B E N A S T R E E T YEO M A N R O A D CH A L M E R S S T R E E T UNDER CONSTRUCTION RESIDENTIAL LOWER LEFT BREWING CO. (4528 NATIONS CROSSING ROAD) NOTES: 1. AERIAL IMAGERY AND BASE DATA OBTAINED FROM MECKLENBURG COUNTY GIS (2023). PIEDMONT NATURAL GAS (112-338 VERBENA STREET) REVISION NO. 0 JOB NO. LEN-008 DATE: 8-2-2023 FIGURE NO. 2 CHARLOTTE VAN & STORAGE CO. VERBENA STREET AND GILEAD STREET CHARLOTTE, NORTH CAROLINA SITE MAP 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 GeologyGILEAD STREETUNDER CONSTRUCTION S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\Final Grade Soil Sampling\Figures\LEN.008_20221005.dwg, FIG 2, 5/17/2023 3:08:25 PM, shaynes Appendix A VIMS As-Built Drawings (VM-1, VM-2, VM-3 & VM-5) DATEREVISIONS:DATE:PROJECT:125 N. Harrington St.Charlotte, NC 28203704/333-7272ClineDesignAssoc.comLMC, A LENNAR COMPANY VERBENA STREET APARTMENTS CHARLOTTE, NC 219025VAPOR MITIGATIONSPECIFICATIONSVM-1 1/16" = 1'-0"1VAPOR MITIGATION - SPECIFICATIONSVAPOR INTRUSION MITIGATION SYSTEM (VIMS) SPECIFICATIONS1.THIS VAPOR INTRUSION MITIGATION PLAN WAS INTENDED FOR DIRECTION OF VIMS COMPONENT INSTALLATION ONLY AND WAS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOTRELATED TO THE VIMS. CONSTRUCTION CONTRACTOR WAS RESPONSIBLE FOR VERIFYING CONSISTENCY OF VIMS DETAILS WITH APPLICABLE STRUCTURAL, ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANSAND RESOLVE INCONSISTENCIES WITH THE DESIGN ENGINEER PRIOR TO VIMS INSTALLATION. THE CONTRACTOR WAS RESPONSIBLE FOR INSTALLING THE VIMS IN ACCORDANCE WITH APPLICABLE BUILDINGCODES.2.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS WERE INSTRUCTED TO USE "LOW OR NO VOC" PRODUCTS AND MATERIALS (INCLUDING NO TETRACHLOROETHENE AND TRICHLOROETHENE), WHENPOSSIBLE.3.VIMS VAPOR LINER IS VAPORBLOCK PLUS 20 VAPOR BARRIER MANUFACTURED BY RAVEN INDUSTRIES, INC. THE VAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATIONINSTRUCTIONS TO CREATE A CONTINUOUS LINER BELOW GROUND FLOOR SLABS. A BASE COURSE CONSISTING OF CLEAN #57 (OR SIMILAR HIGH PERMEABILITY STONE APPROVED BY THE ENGINEER) WASINSTALLED BENEATH THE VIMS VAPOR LINER. IN AREAS AROUND THE SUB-SLAB PIPING, THE BASE COURSE LAYER WAS INSTALLED TO COVER THE SUB-SLAB PIPING WITH A MINIMUM 1-INCH LAYER ABOVE ANDBELOW THE PIPING. IN AREAS WITHOUT PIPING, THE BASE COURSE WAS INSTALLED TO A MINIMUM OF 4 INCHES THICK.4.ALL PENETRATIONS WERE SEALED ACCORDING TO VAPOR LINER MANUFACTURER INSTALLATION INSTRUCTIONS AS FOUND IN THE MANUFACTURER INSTALLATION GUIDELINES., SMALL PUNCTURE HOLES WERESEALED WITH THE VAPORSEAL™TAPE, BUTYL SEALDOUBLE SIDED TAPE, POUR-N-SEAL™AND LARGER HOLES, TEARS, OR DAMAGE WERE REPAIRED USING A PATCH THAT OVERLAPS THE DAMAGED AREA ANDTHEN WAS TAPED ALONG THE SEAMS. IN AREAS WHERE UTILITY PENETRATIONS (I.E. PIPING, DUCTS, ETC) ARE PRESENT AND THE USE OF TAPING WAS NOT PRACTICAL OR DEEMED AS "INEFFECTIVE" BY THE DESIGNENGINEER, POUR-N-SEAL WAS POURED INTO FORM TO PATCH THE PENETRATION WITH AN AIRTIGHT SEAL.5.CONSTRUCTION CONTRACTORS AND SUB-CONTRACTORS WERE INSTRUCTED AVOID THE USE OF TEMPORARY FORM BOARDS THAT PENETRATE THE VAPOR LINER WHERE POSSIBLE. WHERE TEMPORARY FORMBOARDS WERE USED, THE SIZE AND NUMBER OF PENETRATIONS THROUGH THE VAPOR LINER WAS LIMITED AND SMALL DIAMETER STAKES (I.E. SOLID METAL STAKES) WERE USED. AS FORM BOARDS WEREREMOVED, THE CONTRACTOR OR SUB-CONTRACTORS WERE INSTRUCTED TO SEAL PENETRATIONS IN ACCORDANCE WITH VAPOR LINER MANUFACTURER INSTALLATION INSTRUCTIONS.6.VIMS BELOW AND ABOVE GRADE PIPING WAS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL (1% SLOPE) TO GRAVITY DRAIN. SOLID SECTIONS OF HORIZONTAL COLLECTION PIPE WERESUPPORTED, AS NEEDED, TO PREVENT PIPE SAG OR LOW POINT AND MAINTAIN 1% SLOPE TOWARD SLOTTED SECTIONS TO DRAIN CONDENSATION. HORIZONTAL COLLECTION PIPE CONSISTS OF 3" SCH 40 PVC.SUB-SLAB SLOTTED VAPOR COLLECTION PIPE IS THREADED FLUSH JOINT OR GLUE JOINT 3" SCH 40 PVC PIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. THE CONTRACTOR WAS RESPONSIBLE FOR INSTALLINGFOAM PIPE SLEEVES, OR SIMILAR, AROUND HORIZONTAL PORTIONS OF PIPES THAT PENETRATE CONCRETE FOOTERS AND WALLS PER APPLICABLE STRUCTURAL PLANS AND BUILDING CODES, OR AS OTHERWISEDIRECTED BY THE APPLICABLE PLANS AND CONSTRUCTION ENGINEERS. PIPE SLEEVES WERE SEALED TO PREVENT A PREFERENTIAL AIR PATHWAY FROM BELOW THE SLAB INTO THE BUILDING. PLEASE REFER TOSHEET S3.03 IN THE STRUCTURAL DRAWINGS FOR FOOTING DETAILS ADDRESSING VIMS PIPING.7.3" SCH 40 PVC RISER DUCT PIPING WAS INSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUST DISCHARGE POINT WITH A SYPHON VENTILATOR (SEE DETAIL #11). THECONTRACTOR WAS RESPONSIBLE FOR INSTALLING ABOVE-SLAB RISER DUCT PIPE RUNS BETWEEN THE SLAB PENETRATION AND THE ROOFTOP EXHAUST DISCHARGE PER APPLICABLE NORTH CAROLINA PLUMBINGAND BUILDING CODES AND AS SPECIFIED IN THE CONSTRUCTION DOCUMENTS AND DRAWINGS.8.RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF AND TERMINATES A MINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE. AN EMPIRE MODEL STAINLESS STEEL SYPHONVENTILATOR WAS INSTALLED ON THE EXHAUST DISCHARGE END OF EACH RISER DUCT PIPE. AN ADAPTOR COUPLINGWAS INSTALLED AT THE DISCHARGE END OF THE 3" RISER DUCT PIPE AND THE VENTILATORWAS SECURED TO THE PVC RISER IN A VERTICAL ORIENTATION. EXHAUST DISCHARGE LOCATIONS ARE MINIMUM OF 10 FT FROM ANY OPERABLE OPENING OR AIR INTAKE INTO THE BUILDING. AN ELECTRICALJUNCTION BOX (120V, 60Hz AC REQUIRED) WAS INSTALLED NEAR THE FAN LOCATION ON THE ROOFTOP FOR CONVERSION TO ELECTRIC FANS, IF REQUIRED. THE CONTRACTOR WAS RESPONSIBLE FOR INSTALLINGALL WIRING AND ELECTRICAL PER APPLICABLE BUILDING AND ELECTRICAL CODES..9.ABOVE-SLAB ACCESSIBLE RISER DUCT PIPING WAS PERMANENTLY IDENTIFIED BY MEANS OF A TAG OR STENCIL AT A MINIMUM OF ONCE EVERY 10-LINEAR FT WITH "VAPOR MITIGATION - CONTACT MAINTENANCE".THE SYPHON VENTILATOR WAS LABELED WITH "VAPOR MITIGATION SYSTEM - CONTACT MAINTENANCE IF DAMAGED".10.INSPECTIONS OF EACH COMPONENT OF THE VIMS WERE CONDUCTED BY THE ENGINEER, OR ENGINEER'S DESIGNEE, TO CONFIRM VIMS COMPONENTS WERE INSTALLED PER THE APPROVED DESIGN. THEINSPECTIONS INCLUDED: (1) INSPECTION OF SUB-SLAB PIPING LAYOUT AND GRAVEL PLACEMENT PRIOR TO INSTALLING VAPOR LINER; (2) INSPECTION OF VAPOR LINER PRIOR TO POURING CONCRETE; (3)INSPECTION OF ABOVE-GRADE PIPING LAYOUT; AND (4) INSPECTION OF FAN AND VENT PIPE CONNECTIONS.VAPOR MITIGATION PLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyJANUARY 12, 2023S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Install Reports\Bld 1, CH, Maintenance\As-builts\vimp-R1-As-Built-12.13.22.dwg, VM-1, SVincent VIMS VAPOR LINER AND BASE COURSE (TYP)1BASE COURSE - CLEAN #57 STONEMIN 4" THICK BENEATH VIMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #3)CONCRETE FLOOR SLABNTSVM2SUBBASEVIMS SLOTTED COLLECTION PIPE (TYP)23" SCH 40 THREADED FLUSH JOINTSLOTTED OR PERFORATED PVC PIPE SETWITHIN BASE COURSE - MIN THICKNESS TOCOVER PIPE WITH 1-INCH ABOVE AND BELOW(SEE SPECIFICATION #3 AND #6)VAPOR LINER (SEE SPECIFICATION #3)SUBBASENTSVM2SECTION THROUGH EXTERIOR WALLNTSVM2BRICK OR BUILDING SIDINGEXTERNAL WALL (NOTPRESENT AT ALL LOCATIONS)STUD WALLBASE COARSE(SEE SPECIFICATION #3)VAPOR LINER SEALED TO CONCRETE PERMANUFACTURER INSTRUCTIONS.SUBBASE3VAPOR LINER EXTENDS ALONGFOOTING EXTERIOR WHERE POSSIBLEAT LOCATIONS WHERE EXTERIORGRADE IS HIGHER THAN INTERIORGRADE4ANTSVM22" SCH 40 PVC 90 DEGREE ELBOWVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS2" VENT SCREEN ATEND OF PIPEEXTERNAL/STUD WALL(NOT PRESENT IN ALLLOCATIONS)2" SOLID SCH 40 PVCVACUUM MEASURING POINTPOSITION VACUUMMONITORING POINT SO VENTSCREEN IS AT LEAST 5 FT FROMAN EXTERNAL WALL2' MINEXTERNAL/STUD WALL(NOT PRESENT IN ALLLOCATIONS)FLOOR CLEANOUT, ADJUSTABLE,4" DIA ZURN INDUSTRIESMODEL #CO2450-PV4 (OR ENGINEERAPPROVED EQUIVALENT)FLUSH WITHFINISHED FLOOR4BNTSVM22" SCH 40 PVC 90 DEGREE ELBOWVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS2" VENT SCREEN ATEND OF PIPESTUD WALL(NOT PRESENT IN ALLLOCATIONS)VACUUM MEASURING POINT THROUGH THICKENED SLABFLOOR CLEANOUT, ADJUSTABLE,4" DIA ZURN INDUSTRIESMODEL #CO2450-PV4 (OR ENGINEERAPPROVED EQUIVALENT)FLUSH WITHFINISHED FLOOR2" SOLID SCH 40 PVC- INCLUDE PIPESLEEVES WHENAPPLICABLE; SEESPECIFICATION #6TYPICAL VIMS LINER AT ELEVATOR PIT9NTSVM2WATERPROOFING (SEESPECIFICATION #11)ELEVATOR SUMPCONTINUOUS VAPOR LINERSEALED PER MANUFACTURERINSTRUCTIONSVAPOR LINER SEALED TOWATERPROOFINGWATERPROOFING - POSTAPPLIEDGROUND FLOORINTERIOR SPACEBASEMENT LEVELHALLWAYSUB-BASECONCRETEFLOOR SLABBASE COURSE(SEE SPECIFICATION #3)VAPOR LINER(SEE SPECIFICATION #3)VAPOR LINER SEALED TO OUTSIDE OF CONCRETEAND WATERPROOFING/INSULATION (WHEREPRESENT) PER MANUFACTURER INSTRUCTIONS WATERPROOFING ANDRIGID INSULATIONDRAINSTUD/SHEARWALLVIMS AT RETAINING WALL10NTSVM2VIMS SYPHON VENTILATOR & EXHAUST (TYP)11VM2NTSELECTRICAL JUNCTION BOX FOR POTENTIALFUTURE VACUUM FAN (REFER TOSPECIFICATION #8) RISER DUCT PIPE THROUGH ROOFFLASHINGROOFTOP4" X3" HEAVYDUTY NO HUBCOUPLING4" SYPHON VENTILATOR (EMPIRE SYPHONVENTILATOR OR ENGINEER APPROVEDEQUIVALENT)VERTICAL RISER AT SLAB PENETRATION WITH 90 DEGREE ELBOWNTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS3" SCH 40 PVC 90 DEGREE ELBOWSTUD WALL3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #8 & #9)BASE COARSE(SEE SPECIFICATION #3)SOLID 3" SCH 40 PVC TO SLOTTED 3" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)THICKENED SLAB MAY NOT BE PRESENT INALL LOCATIONS3" SOLID SCH 40 PVC(SEE SPECIFICATION #7)VM27VIMS VACUUM MEASURING POINT - DETAIL VIEWNTSVM25FINISHED FLOOR SLAB2" SCH 40 PVC SET WITHIN GRAVEL LAYER(SEE DETAILS 4A & 4B)2" DRAIN EXPANSION TEST PLUGBASE COURSE(SEE SPECIFICATION #3)FLOOR CLEANOUT, ADJUSTABLE, 4" DIA ZURNINDUSTRIES MODEL #CO2450-PV4 (ORENGINEER APPROVED EQUIVALENT) FLUSHWITH FINISHED FLOOR4" x 2" FLUSH REDUCERBUSHINGVAPOR BARRIER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS2" SCH 40 PVC 90 DEGREE STREET ELBOWVAPOR LINER PENETRATION SEALEDTO PIPE PER MANUFACTURERINSTRUCTIONSSTUD WALL(NOT PRESENT IN ALL LOCATIONS)VAPOR LINERBENEATHTHICKENED SLABHORIZONTAL PIPE THROUGH THICKENED SLABTOP OF THICKENEDSLAB TURNDOWNFIRE WALL (NOT PRESENTIN ALL LOCATIONS)3" SOLID SCH 40 PVC -INCLUDE PIPE SLEEVESWHEN APPLICABLE; SEESPECIFICATION #66VM2NTSVERTICAL RISER AT SLAB PENETRATION WITH TEENTSVAPOR LINER PENETRATION SEALED TOPIPE PER MANUFACTURER INSTRUCTIONS3" SCH 40 PVC 90 DEGREE TEESTUD WALL3" SCH 40 PVC RISER DUCT PIPE(SEE SPECIFICATION #8 & #9)SOLID TO SLOTTED 3" SCH 40PVC PIPE TRANSITION (SLIP COUPLINGOR THREADED JOINT)THICKENED SLAB MAY NOT BE PRESENT IN ALLLOCATIONS3" SOLID SCH 40 PVC(SEE SPECIFICATION #5)8VM2SOLID TO SLOTTED 3" SCH 40 PVC PIPETRANSITION (SLIP COUPLINGOR THREADED JOINT)BASE COURSEWALL (VARIES)PROVIDE LOCKABLEWEATHERPROOF ENCLOSUREON OUTSIDE OF HOUSE WALL(OR SIMILAR). AFFIX LABEL ATBOX WITH "VAPOR MITIGATIONSYSTEM". PLACE REMOVABLEPIPE PLUG AT END OF 2" PIPE.VAPOR LINER SEALED TOCONCRETE PERMANUFACTURERSINSTRUCTIONS2" SCH 40 PVC 90 DEGREE ELBOW2" SOLID SCH 40 PVC PIPEINSTALLER SHALL SECUREPIPE TO PREVENT MOVEMENTOR DAMAGE TO PIPE DURINGTHE CONCRETE POUREXTERIOR GRADE (VARIES)BASE COURSEVAPOR LINERSLEEVE THROUGH FOOTING. ENLARGEFOOTING PER STRUCTURAL DRAWINGSWHERE PIPES PENETRATE FOOTINGVENT PIPE PROTECTIONSCREENSLEEVE FOR FULL LENGTH OFPROJECTION WITH SLEEVE 2" LARGERDIAMETER THAN PIPEEXTERIOR PERMANENT VACUUM MEASURING POINT (TYP)4CNTSVM2SUB-BASEVAPOR BARRIER(SEE SPECIFICATION #1)CONCRETE FLOOR SLABBASE COURSE(SEE SPECIFICATION #1)VAPOR PINSAMPLING BARBSILICONE SLEEVEVAPOR PIN BRASSSAMPLING DEVICEVIMS MONITORING POINT VAPOR PIN (TYP)12NTSVM2DATEREVISIONS:DATE:PROJECT:125 N. Harrington St.Charlotte, NC 28203704/333-7272ClineDesignAssoc.comLMC, A LENNAR COMPANY VERBENA STREET APARTMENTS CHARLOTTE, NC 219025VAPOR MITIGATIONSECTION DETAILSAS-BUILTVM-22VIMS LAYOUT - SECTION DETAILSVAPOR MITIGATION PLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyJANUARY 12, 2023S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Install Reports\Bld 1, CH, Maintenance\As-builts\vimp-R1-As-Built-12.13.22.dwg, VM-2, SVincent 2 HOUR FIRE BARRIER2 HOUR SHAFT WALL ENCLOSURE1 HOUR FIRE PARTITION2 HOUR FIRE WALLUNIT B21/A4.06UNIT B21/A4.06UNIT A11/A4.02UNIT S11/A4.01UNIT A11/A4.02UNIT A11/A4.02UNIT A11/A4.02UNIT A11/A4.02UNIT A31/A4.04UNIT A11/A4.02UNIT S11/A4.01UNIT B21/A4.06UNIT A11/A4.02UNIT A31/A4.04UNIT B11/A4.05UNIT S11/A4.01UNIT B11/A4.05UNIT B11/A4.05UNIT S11/A4.01UNIT B11/A4.05UNIT B11/A4.05UNIT A21/A4.03UNIT S11/A4.01UNIT A21/A4.0366'-0"242'-6 1/4"UNIT A11/A4.02UNIT A2 (TYPE A)1/A4.07ELEVSTAIR 101 STAIR102 MECHMETERCENTERMETERCENTERELECHOUSEPANELMETERCENTERTELECOMMDFCLOSETMECHTELELOBBYHOUSESTOR.75'-1 1/2"UNIT S11/A4.01UNIT S11/A4.01UNIT S11/A4.0160'-6"310'-0 1/4"127'-1" 203'-3"60'-4"DATEREVISIONS:DATE:PROJECT:125 N. Harrington St.Charlotte, NC 28203704/333-7272ClineDesignAssoc.comLMC, A LENNAR COMPANY VERBENA STREET APARTMENTS CHARLOTTE, NC 219025BLDG 01 GROUNDFLOOR SUB-SLABLAYOUT DESIGNVM-3KEY PLANRATED WALL LEGEND 1/16" = 1'-0"1BUILDING 01 - OVERALL GROUND FLOORBLDG 1BLDG 2CHE-6E-7E-2E-3E-8E-9E-4E-10E-5E-11E-12E-14E-131VM22VM22VM23VM23VM2VM24A4BVM24BVM26VM27VM27VM28VM28VM29VM2E-14BVM24BVM24BVM24BVM2VAPOR MITIGATION PLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologySUB-SLAB SAMPLE LOCATIONSUB-SLAB SAMPLE LOCATIONSUB-SLAB SAMPLE LOCATION SUB-SLAB SAMPLE LOCATIONSUB-SLAB SAMPLE LOCATIONSUB-SLAB SAMPLE LOCATION2VM21VM2LEGENDEXTENT OF VAPOR BARRIER3" SCH 40 PVC SLOTTED PIPE3" SCH 40 PVC SOLID PIPEVERTICAL RISER (3" SCH 40 PVC PIPE) AND EXHAUST LOCATIONVACUUM MEASURING POINT (2" SCH 40 PVC WITH OPEN END)TEMPORARY VACUUM MEASURING POINT (2" SCH 40 PVC WITH OPEN END)INDOOR AIR SAMPLE LOCATIONBACKGROUND AIR SAMPLE LOCATIONF-1MP-8MP-9MP-7TMP-1MP-6TMP-2MP-5MP-4TMP-3MP-2MP-3TMP-4MP-10TMP-5IAS-2IAS-1IAS-3BAS-1JANUARY 12, 2023S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Install Reports\Bld 1, CH, Maintenance\As-builts\vimp-R1-As-Built-12.13.22.dwg, VM-3, SVincent 2 HOUR FIRE BARRIER2 HOUR SHAFT WALL ENCLOSURE1 HOUR FIRE PARTITIONFDC10C11C09MAINTENANCE GARAGEMAINTENANCEE.W.BIKESTORAGESECURESTORAGE30" X 60" ATTICACCESS PANELABOVEHBCABINET STORAGEABOVE/BELOWCOUNTER TOP4'x8' PLYWOOD BLUEPRINTTABLE/FLEX SPACEC08DATEREVISIONS:DATE:PROJECT:125 N. Harrington St.Charlotte, NC 28203704/333-7272ClineDesignAssoc.comLMC, A LENNAR COMPANY VERBENA STREET APARTMENTS CHARLOTTE, NC 219025MAINTENANCE BLDGGROUND FLOORSUB-SLAB LAYOUTDESIGNVM-5KEY PLANRATED WALL LEGEND 1/16" = 1'-0"5MAINTENANCE BUILDINGBLDG 1BLDG 2CHLEGENDEXTENT OF VAPOR BARRIERSUB-SLAB MONITORING POINT (VAPOR PIN)1VM23VM212VM23VM2VAPOR MITIGATION PLAN PREPARED BY:2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyJANUARY 12, 2023SUB-SLAB SAMPLE LOCATIONMP-1S:\AAA-Master Projects\Lennar (LEN)\LEN-008 Verbena Assemblage\VIMS Install Reports\Bld 1, CH, Maintenance\As-builts\vimp-R1-As-Built-12.13.22.dwg, VM-5, SVincent Appendix B Field Forms INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present? Yes / No Sump pump? Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Verbena Street Apartments 23057-19-060 Ann Marie Lindley 6/22/23 Hat & Hickman, PC (704) 586-0007 2123 Verbena Street and 4607 & 4615 Gilead Street Patrick Foster Development Manager 704 998-0367 410 842-5303 Apartment Building 2021-2022 NA 0 4 00 Is there a whole house fan? Yes / No Septic system? Yes / Yes (but not used) / No Irrigation/private well? Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place? Yes / No active / passive Sub-slab vapor/moisture barrier in place? Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) NA Wood stove or fireplace NA New furniture / upholstery New carpeting / flooring NA Hobbies - glues, paints, etc. VaporBlock 20-mil natural gas station NE of Site low to moderate consrtucion traffic N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space? Yes / No If so, is a car usually parked in the garage? Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Yes / No Do the occupants of the building have their clothes dry cleaned? Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work? Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? Yes / No Have any pesticides/herbicides been applied around the building or in the yard? Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________and where?____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Analytical Method: TO-15 / TO-17 / other: _________ Cert. Laboratory: _________________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No If not, describe modifications: __________________________________________________________ January 2023 leasing, residential units, & hallways Ann Marie Lindley 919 606 Waypoint Analytical IAS 1 IAS 3/DUP IAS 2 IAS BKG Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: ___________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). 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Switch 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Revised Lab Report Number: 23-177-0008 Client Project Description: LEN-008 Dear Shannon Switch: Waypoint Analytical, LLC (Charlotte) received sample(s) on 6/26/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 100 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-177-0008 Page 2 of 100 Report Number: Sample Summary Table Client Project Description: 23-177-0008 LEN-008 Lab No Client Sample ID Matrix Date Collected Date Received 06/21/2023 11:02Air 99267 SS-MP-2 06/26/2023 13:57 06/22/2023Air 99268 SS-MP-DUP 06/26/2023 13:57 06/22/2023 16:41Air 99269 SS-MP-7 06/26/2023 13:57 06/22/2023 11:42Air 99270 SS-MP-3 06/26/2023 13:57 06/22/2023 13:28Air 99271 SS-MP-4 06/26/2023 13:57 06/22/2023 14:11Air 99272 SS-MP-6 06/26/2023 13:57 06/22/2023 10:04Air 99273 SS-MP-10 06/26/2023 13:57 06/22/2023 15:35Air 99274 SS-MP-8 06/26/2023 13:57 06/22/2023 13:04Air 99275 SS-MP-5 06/26/2023 13:57 06/22/2023 14:58Air 99276 SS-MP-9 06/26/2023 13:57 06/22/2023 09:20Air 99277 SS-MP-1 06/26/2023 13:57 06/21/2023 08:23Air 99278 IAS-3 06/26/2023 13:57 06/21/2023Air 99279 IAS-DUP 06/26/2023 13:57 06/21/2023 08:24Air 99280 IAS-1 06/26/2023 13:57 06/21/2023 08:25Air 99281 IAS-BKG 06/26/2023 13:57 06/21/2023 08:25Air 99282 IAS-2 06/26/2023 13:57 Page 3 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99267SS-MP-2 249 06/28/2023 22:01TO-15 Acetone µg/m3 10.1 J0.875 06/29/2023 06:05TO-15 Benzene µg/m3 0.146 J1.49 06/29/2023 06:05TO-15 Carbon Disulfide µg/m3 0.122 J2.97 06/29/2023 06:05TO-15 Chloroform µg/m3 0.172 2.14 06/29/2023 06:05TO-15 Chloromethane µg/m3 0.134 J2.73 06/29/2023 06:05TO-15 Dichlorodifluoromethane µg/m3 0.267 J2.83 06/29/2023 06:05TO-15 Ethyl Acetate µg/m3 0.271 4.57 06/29/2023 06:05TO-15 Ethylbenzene µg/m3 0.211 J1.14 06/29/2023 06:05TO-15 4-Ethyltoluene µg/m3 0.256 J2.48 06/29/2023 06:05TO-15 Heptane µg/m3 0.286 J1.10 06/29/2023 06:05TO-15 n-Hexane µg/m3 0.094 J1.98 06/29/2023 06:05TO-15 2-Hexanone µg/m3 0.570 30.4 06/29/2023 06:05TO-15 Isopropyl Alcohol µg/m3 0.277 295 06/29/2023 06:05TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.448 J1.05 06/29/2023 06:05TO-15 4-Methyl-2-Pentanone µg/m3 0.242 J1.76 06/29/2023 06:05TO-15 Styrene µg/m3 0.248 3690 06/28/2023 22:01TO-15 Tetrahydrofuran µg/m3 5.35 59.7 06/29/2023 06:05TO-15 Toluene µg/m3 0.180 J1.84 06/29/2023 06:05TO-15 Trichlorofluoromethane µg/m3 0.260 J4.51 06/29/2023 06:05TO-15 1,2,4-Trimethylbenzene µg/m3 0.220 J1.86 06/29/2023 06:05TO-15 1,3,5-Trimethylbenzene µg/m3 0.472 6.30 06/29/2023 06:05TO-15 o-Xylene µg/m3 0.313 22.3 06/29/2023 06:05TO-15 m,p-Xylene µg/m3 0.434 28.6 06/29/2023 06:05TO-15 Xylene (Total)µg/m3 0.313 V 99268SS-MP-DUP 252 06/28/2023 22:37TO-15 Acetone µg/m3 10.1 J1.06 06/29/2023 06:49TO-15 Benzene µg/m3 0.146 J2.50 06/29/2023 06:49TO-15 Carbon Disulfide µg/m3 0.122 J2.97 06/29/2023 06:49TO-15 Chloroform µg/m3 0.172 J2.75 06/29/2023 06:49TO-15 Dichlorodifluoromethane µg/m3 0.267 3.79 06/29/2023 06:49TO-15 Ethyl Acetate µg/m3 0.271 4.49 06/29/2023 06:49TO-15 Ethylbenzene µg/m3 0.211 J1.03 06/29/2023 06:49TO-15 4-Ethyltoluene µg/m3 0.256 J2.64 06/29/2023 06:49TO-15 Heptane µg/m3 0.286 J1.21 06/29/2023 06:49TO-15 n-Hexane µg/m3 0.094 J1.87 06/29/2023 06:49TO-15 2-Hexanone µg/m3 0.570 Page 4 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99268SS-MP-DUP 31.9 06/29/2023 06:49TO-15 Isopropyl Alcohol µg/m3 0.277 253 06/28/2023 22:37TO-15 Methyl Ethyl Ketone (MEK)µg/m3 11.2 J0.950 06/29/2023 06:49TO-15 4-Methyl-2-Pentanone µg/m3 0.242 J1.89 06/29/2023 06:49TO-15 Styrene µg/m3 0.248 3840 06/28/2023 22:37TO-15 Tetrahydrofuran µg/m3 5.35 60.4 06/29/2023 06:49TO-15 Toluene µg/m3 0.180 J1.88 06/29/2023 06:49TO-15 Trichlorofluoromethane µg/m3 0.260 J4.58 06/29/2023 06:49TO-15 1,2,4-Trimethylbenzene µg/m3 0.220 J1.78 06/29/2023 06:49TO-15 1,3,5-Trimethylbenzene µg/m3 0.472 6.62 06/29/2023 06:49TO-15 o-Xylene µg/m3 0.313 21.9 06/29/2023 06:49TO-15 m,p-Xylene µg/m3 0.434 28.5 06/29/2023 06:49TO-15 Xylene (Total)µg/m3 0.313 V 99269SS-MP-7 5970 06/28/2023 23:14TO-15 Acetone µg/m3 40.4 J4.61 06/27/2023 22:27TO-15 Carbon Disulfide µg/m3 1.22 J7.62 06/27/2023 22:27TO-15 Chloroform µg/m3 1.73 J21.6 06/27/2023 22:27TO-15 Isopropyl Alcohol µg/m3 2.78 630 06/27/2023 22:27TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 14000 06/28/2023 23:14TO-15 Tetrahydrofuran µg/m3 21.4 J8.14 06/27/2023 22:27TO-15 Toluene µg/m3 1.80 V 99270SS-MP-3 118 06/29/2023 00:08TO-15 Acetone µg/m3 0.202 J0.396 06/29/2023 00:08TO-15 Benzene µg/m3 0.073 J1.60 06/29/2023 00:08TO-15 Carbon Disulfide µg/m3 0.060 22.1 06/29/2023 00:08TO-15 Chloroform µg/m3 0.086 J0.877 06/29/2023 00:08TO-15 Chloromethane µg/m3 0.067 2.64 06/29/2023 00:08TO-15 Dichlorodifluoromethane µg/m3 0.134 3.15 06/29/2023 00:08TO-15 Ethyl Acetate µg/m3 0.136 J0.998 06/29/2023 00:08TO-15 Ethylbenzene µg/m3 0.106 J0.584 06/29/2023 00:08TO-15 4-Ethyltoluene µg/m3 0.128 J0.368 06/29/2023 00:08TO-15 Heptane µg/m3 0.143 13.9 06/29/2023 00:08TO-15 Isopropyl Alcohol µg/m3 0.139 842 06/27/2023 23:04TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 J0.796 06/29/2023 00:08TO-15 Styrene µg/m3 0.124 J1.70 06/29/2023 00:08TO-15 Tetrachloroethene µg/m3 0.181 1910 06/27/2023 23:04TO-15 Tetrahydrofuran µg/m3 2.14 Page 5 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99270SS-MP-3 7.19 06/29/2023 00:08TO-15 Toluene µg/m3 0.090 J2.10 06/29/2023 00:08TO-15 Trichlorofluoromethane µg/m3 0.130 2.66 06/29/2023 00:08TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.771 06/29/2023 00:08TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 J1.90 06/29/2023 00:08TO-15 o-Xylene µg/m3 0.157 J5.64 06/29/2023 00:08TO-15 m,p-Xylene µg/m3 0.217 J7.54 06/29/2023 00:08TO-15 Xylene (Total)µg/m3 0.157 V 99271SS-MP-4 134 06/27/2023 23:41TO-15 Acetone µg/m3 4.04 J0.373 06/29/2023 00:58TO-15 Benzene µg/m3 0.073 J0.971 06/29/2023 00:58TO-15 Carbon Disulfide µg/m3 0.060 9.83 06/29/2023 00:58TO-15 Chloroform µg/m3 0.086 J2.36 06/29/2023 00:58TO-15 Cyclohexane µg/m3 0.161 J2.45 06/29/2023 00:58TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.799 06/29/2023 00:58TO-15 Ethyl Acetate µg/m3 0.136 J0.694 06/29/2023 00:58TO-15 Ethylbenzene µg/m3 0.106 J0.704 06/29/2023 00:58TO-15 Heptane µg/m3 0.143 J1.34 06/29/2023 00:58TO-15 2-Hexanone µg/m3 0.285 22.3 06/29/2023 00:58TO-15 Isopropyl Alcohol µg/m3 0.139 1160 06/27/2023 23:41TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 J0.512 06/29/2023 00:58TO-15 4-Methyl-2-Pentanone µg/m3 0.121 2.28 06/29/2023 00:58TO-15 Styrene µg/m3 0.124 40.2 06/29/2023 00:58TO-15 Tetrachloroethene µg/m3 0.181 1840 06/27/2023 23:41TO-15 Tetrahydrofuran µg/m3 2.14 9.77 06/29/2023 00:58TO-15 Toluene µg/m3 0.090 J1.89 06/29/2023 00:58TO-15 Trichlorofluoromethane µg/m3 0.130 J1.05 06/29/2023 00:58TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J1.09 06/29/2023 00:58TO-15 o-Xylene µg/m3 0.157 J3.39 06/29/2023 00:58TO-15 m,p-Xylene µg/m3 0.217 J4.48 06/29/2023 00:58TO-15 Xylene (Total)µg/m3 0.157 V 99272SS-MP-6 96.0 06/29/2023 07:42TO-15 Acetone µg/m3 0.202 J0.287 06/29/2023 07:42TO-15 Benzene µg/m3 0.073 J0.965 06/29/2023 07:42TO-15 Carbon Disulfide µg/m3 0.060 40.2 06/29/2023 07:42TO-15 Chloroform µg/m3 0.086 J2.37 06/29/2023 07:42TO-15 Dichlorodifluoromethane µg/m3 0.134 Page 6 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99272SS-MP-6 J2.16 06/29/2023 07:42TO-15 1,2-Dichloropropane µg/m3 0.205 2.21 06/29/2023 07:42TO-15 Ethyl Acetate µg/m3 0.136 J0.351 06/29/2023 07:42TO-15 Ethylbenzene µg/m3 0.106 J0.864 06/29/2023 07:42TO-15 Heptane µg/m3 0.143 J0.271 06/29/2023 07:42TO-15 n-Hexane µg/m3 0.047 2.47 06/29/2023 07:42TO-15 2-Hexanone µg/m3 0.285 16.2 06/29/2023 07:42TO-15 Isopropyl Alcohol µg/m3 0.139 2020 06/29/2023 01:34TO-15 Methyl Ethyl Ketone (MEK)µg/m3 11.2 J0.696 06/29/2023 07:42TO-15 4-Methyl-2-Pentanone µg/m3 0.121 4.15 06/29/2023 07:42TO-15 Naphthalene µg/m3 0.183 J1.19 06/29/2023 07:42TO-15 Styrene µg/m3 0.124 J1.10 06/29/2023 07:42TO-15 Tetrachloroethene µg/m3 0.181 3070 06/29/2023 01:34TO-15 Tetrahydrofuran µg/m3 5.35 4.37 06/29/2023 07:42TO-15 Toluene µg/m3 0.090 J2.33 06/29/2023 07:42TO-15 Trichlorofluoromethane µg/m3 0.130 J0.884 06/29/2023 07:42TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.599 06/29/2023 07:42TO-15 o-Xylene µg/m3 0.157 J2.33 06/29/2023 07:42TO-15 m,p-Xylene µg/m3 0.217 J2.93 06/29/2023 07:42TO-15 Xylene (Total)µg/m3 0.157 V 99273SS-MP-10 76.0 06/29/2023 02:27TO-15 Acetone µg/m3 0.202 J0.759 06/29/2023 02:27TO-15 Carbon Disulfide µg/m3 0.060 J1.43 06/29/2023 02:27TO-15 Chloroform µg/m3 0.086 2.57 06/29/2023 02:27TO-15 Dichlorodifluoromethane µg/m3 0.134 14.8 06/29/2023 02:27TO-15 Ethyl Acetate µg/m3 0.136 J0.534 06/29/2023 02:27TO-15 Ethylbenzene µg/m3 0.106 J0.356 06/29/2023 02:27TO-15 Heptane µg/m3 0.143 J0.437 06/29/2023 02:27TO-15 n-Hexane µg/m3 0.047 J3.48 06/29/2023 02:27TO-15 Isopropyl Alcohol µg/m3 0.139 274 06/28/2023 00:55TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 601 06/28/2023 00:55TO-15 Tetrahydrofuran µg/m3 2.14 5.04 06/29/2023 02:27TO-15 Toluene µg/m3 0.090 J2.00 06/29/2023 02:27TO-15 Trichlorofluoromethane µg/m3 0.130 J0.535 06/29/2023 02:27TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.673 06/29/2023 02:27TO-15 o-Xylene µg/m3 0.157 J2.34 06/29/2023 02:27TO-15 m,p-Xylene µg/m3 0.217 Page 7 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99273SS-MP-10 J3.01 06/29/2023 02:27TO-15 Xylene (Total)µg/m3 0.157 V 99274SS-MP-8 93.1 06/29/2023 13:35TO-15 Acetone µg/m3 0.404 J1.23 06/29/2023 13:35TO-15 Bromodichloromethane µg/m3 0.299 J0.741 06/29/2023 13:35TO-15 Carbon Disulfide µg/m3 0.122 12.8 06/29/2023 13:35TO-15 Chloroform µg/m3 0.172 J0.631 06/29/2023 13:35TO-15 Chloromethane µg/m3 0.134 J2.99 06/29/2023 13:35TO-15 Dichlorodifluoromethane µg/m3 0.267 J1.83 06/29/2023 13:35TO-15 Ethyl Acetate µg/m3 0.271 J1.22 06/29/2023 13:35TO-15 2-Hexanone µg/m3 0.570 J8.43 06/29/2023 13:35TO-15 Isopropyl Alcohol µg/m3 0.277 1170 06/29/2023 03:04TO-15 Methyl Ethyl Ketone (MEK)µg/m3 11.2 4860 06/29/2023 03:04TO-15 Tetrahydrofuran µg/m3 5.35 6.63 06/29/2023 13:35TO-15 Toluene µg/m3 0.180 J3.16 06/29/2023 13:35TO-15 Trichlorofluoromethane µg/m3 0.260 J3.16 06/29/2023 13:35TO-15 m,p-Xylene µg/m3 0.434 J3.16 06/29/2023 13:35TO-15 Xylene (Total)µg/m3 0.313 V 99275SS-MP-5 763 06/29/2023 03:40TO-15 Acetone µg/m3 10.1 J0.523 06/29/2023 14:19TO-15 Benzene µg/m3 0.146 J1.25 06/29/2023 14:19TO-15 Carbon Disulfide µg/m3 0.122 22.5 06/29/2023 14:19TO-15 Chloroform µg/m3 0.172 J1.65 06/29/2023 14:19TO-15 Chloromethane µg/m3 0.134 J2.54 06/29/2023 14:19TO-15 Dichlorodifluoromethane µg/m3 0.267 J1.53 06/29/2023 14:19TO-15 Ethylbenzene µg/m3 0.211 J1.12 06/29/2023 14:19TO-15 Heptane µg/m3 0.286 5.75 06/29/2023 14:19TO-15 2-Hexanone µg/m3 0.570 103 06/29/2023 14:19TO-15 Isopropyl Alcohol µg/m3 0.277 3780 06/29/2023 03:40TO-15 Methyl Ethyl Ketone (MEK)µg/m3 11.2 J1.45 06/29/2023 14:19TO-15 4-Methyl-2-Pentanone µg/m3 0.242 5.95 06/29/2023 14:19TO-15 Styrene µg/m3 0.248 J3.64 06/29/2023 14:19TO-15 Tetrachloroethene µg/m3 0.361 4180 06/29/2023 03:40TO-15 Tetrahydrofuran µg/m3 5.35 28.7 06/29/2023 14:19TO-15 Toluene µg/m3 0.180 J2.72 06/29/2023 14:19TO-15 Trichlorofluoromethane µg/m3 0.260 J2.03 06/29/2023 14:19TO-15 1,2,4-Trimethylbenzene µg/m3 0.220 Page 8 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99275SS-MP-5 J2.26 06/29/2023 14:19TO-15 o-Xylene µg/m3 0.313 J7.61 06/29/2023 14:19TO-15 m,p-Xylene µg/m3 0.434 J9.87 06/29/2023 14:19TO-15 Xylene (Total)µg/m3 0.313 V 99276SS-MP-9 38.8 06/29/2023 04:32TO-15 Acetone µg/m3 0.202 J0.696 06/29/2023 04:32TO-15 Benzene µg/m3 0.073 J1.39 06/29/2023 04:32TO-15 Bromodichloromethane µg/m3 0.150 J1.26 06/29/2023 04:32TO-15 Carbon Disulfide µg/m3 0.060 26.7 06/29/2023 04:32TO-15 Chloroform µg/m3 0.086 J1.92 06/29/2023 04:32TO-15 Cyclohexane µg/m3 0.161 3.14 06/29/2023 04:32TO-15 Dichlorodifluoromethane µg/m3 0.134 J0.563 06/29/2023 04:32TO-15 1,2-Dichloropropane µg/m3 0.205 1.92 06/29/2023 04:32TO-15 Ethyl Acetate µg/m3 0.136 J0.325 06/29/2023 04:32TO-15 Ethylbenzene µg/m3 0.106 J0.651 06/29/2023 04:32TO-15 Heptane µg/m3 0.143 J1.67 06/29/2023 04:32TO-15 n-Hexane µg/m3 0.047 7.90 06/29/2023 04:32TO-15 Isopropyl Alcohol µg/m3 0.139 141 06/28/2023 02:45TO-15 Methyl Ethyl Ketone (MEK)µg/m3 4.48 J0.331 06/29/2023 04:32TO-15 4-Methyl-2-Pentanone µg/m3 0.121 4.93 06/29/2023 04:32TO-15 Methylene Chloride µg/m3 0.488 375 06/28/2023 02:45TO-15 Tetrahydrofuran µg/m3 2.14 4.12 06/29/2023 04:32TO-15 Toluene µg/m3 0.090 4.26 06/29/2023 04:32TO-15 Trichlorofluoromethane µg/m3 0.130 J0.511 06/29/2023 04:32TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.503 06/29/2023 04:32TO-15 o-Xylene µg/m3 0.157 J2.13 06/29/2023 04:32TO-15 m,p-Xylene µg/m3 0.217 J2.63 06/29/2023 04:32TO-15 Xylene (Total)µg/m3 0.157 V 99277SS-MP-1 46.5 06/30/2023 14:29TO-15 Acetone µg/m3 0.202 3.56 06/30/2023 14:29TO-15 Benzene µg/m3 0.073 J2.54 06/30/2023 14:29TO-15 Carbon Disulfide µg/m3 0.060 51.3 06/30/2023 14:29TO-15 Chloroform µg/m3 0.086 J3.19 06/30/2023 14:29TO-15 Cyclohexane µg/m3 0.161 J1.02 06/30/2023 14:29TO-15 1,4-Dichlorobenzene µg/m3 0.186 4.47 06/30/2023 14:29TO-15 cis-1,2-Dichloroethene µg/m3 0.095 2.45 06/30/2023 14:29TO-15 1,2-Dichloropropane µg/m3 0.205 Page 9 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99277SS-MP-1 58.5 06/30/2023 14:29TO-15 1,2-Dichlorotetrafluoroethane µg/m3 0.622 24.7 06/30/2023 14:29TO-15 Ethylbenzene µg/m3 0.106 J0.848 06/30/2023 14:29TO-15 Heptane µg/m3 0.143 2.07 06/30/2023 14:29TO-15 n-Hexane µg/m3 0.047 289 06/29/2023 23:33TO-15 Isopropyl Alcohol µg/m3 2.78 1.76 06/30/2023 14:29TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.407 06/30/2023 14:29TO-15 Methyl tert-butyl ether (MTBE)µg/m3 0.033 J0.356 06/30/2023 14:29TO-15 4-Methyl-2-Pentanone µg/m3 0.121 3.84 06/30/2023 14:29TO-15 Methylene Chloride µg/m3 0.488 4.60 06/30/2023 14:29TO-15 Styrene µg/m3 0.124 JB3.14 06/30/2023 14:29TO-15 Tetrachloroethene µg/m3 0.181 22.2 06/30/2023 14:29TO-15 Tetrahydrofuran µg/m3 0.107 15.1 06/30/2023 14:29TO-15 Toluene µg/m3 0.090 J0.999 06/30/2023 14:29TO-15 Trichloroethene µg/m3 0.199 20.2 06/30/2023 14:29TO-15 Trichlorofluoromethane µg/m3 0.130 J1.27 06/30/2023 14:29TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 9.09 06/30/2023 14:29TO-15 o-Xylene µg/m3 0.157 33.2 06/30/2023 14:29TO-15 m,p-Xylene µg/m3 0.217 42.3 06/30/2023 14:29TO-15 Xylene (Total)µg/m3 0.157 V 99278IAS-3 387 07/11/2023 11:24TO-15 Acetone µg/m3 4.04 J0.721 06/30/2023 00:22TO-15 Benzene µg/m3 0.073 J1.18 06/30/2023 00:22TO-15 Carbon Disulfide µg/m3 0.060 J0.786 06/30/2023 00:22TO-15 Chloroform µg/m3 0.086 1.08 06/30/2023 00:22TO-15 Chloromethane µg/m3 0.067 J2.43 06/30/2023 00:22TO-15 Dichlorodifluoromethane µg/m3 0.134 2.55 06/30/2023 00:22TO-15 Ethyl Acetate µg/m3 0.136 3.07 06/30/2023 00:22TO-15 Ethylbenzene µg/m3 0.106 5.45 06/30/2023 00:22TO-15 Heptane µg/m3 0.143 1.85 06/30/2023 00:22TO-15 n-Hexane µg/m3 0.047 5.28 06/30/2023 00:22TO-15 2-Hexanone µg/m3 0.285 134 07/11/2023 11:24TO-15 Isopropyl Alcohol µg/m3 2.78 41.1 06/30/2023 00:22TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.17 06/30/2023 00:22TO-15 4-Methyl-2-Pentanone µg/m3 0.121 7.19 06/30/2023 00:22TO-15 Styrene µg/m3 0.124 J0.922 06/30/2023 00:22TO-15 Tetrachloroethene µg/m3 0.181 Page 10 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99278IAS-3 20.6 06/30/2023 00:22TO-15 Tetrahydrofuran µg/m3 0.107 57.3 06/30/2023 00:22TO-15 Toluene µg/m3 0.090 J1.54 06/30/2023 00:22TO-15 Trichlorofluoromethane µg/m3 0.130 3.80 06/30/2023 00:22TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.924 06/30/2023 00:22TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 3.92 06/30/2023 00:22TO-15 o-Xylene µg/m3 0.157 13.2 06/30/2023 00:22TO-15 m,p-Xylene µg/m3 0.217 17.1 06/30/2023 00:22TO-15 Xylene (Total)µg/m3 0.157 V 99279IAS-DUP 360 07/11/2023 12:00TO-15 Acetone µg/m3 4.04 JB0.690 07/06/2023 22:28TO-15 Benzene µg/m3 0.073 JB0.688 07/06/2023 22:28TO-15 Carbon Disulfide µg/m3 0.060 J0.800 07/06/2023 22:28TO-15 Chloroform µg/m3 0.086 1.14 07/06/2023 22:28TO-15 Chloromethane µg/m3 0.067 2.59 07/06/2023 22:28TO-15 Dichlorodifluoromethane µg/m3 0.134 3.09 07/06/2023 22:28TO-15 Ethyl Acetate µg/m3 0.136 3.23 07/06/2023 22:28TO-15 Ethylbenzene µg/m3 0.106 5.36 07/06/2023 22:28TO-15 Heptane µg/m3 0.143 2.04 07/06/2023 22:28TO-15 n-Hexane µg/m3 0.047 5.91 07/06/2023 22:28TO-15 2-Hexanone µg/m3 0.285 122 07/11/2023 12:00TO-15 Isopropyl Alcohol µg/m3 2.78 43.9 07/06/2023 22:28TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.16 07/06/2023 22:28TO-15 4-Methyl-2-Pentanone µg/m3 0.121 7.37 07/06/2023 22:28TO-15 Styrene µg/m3 0.124 J0.732 07/06/2023 22:28TO-15 Tetrachloroethene µg/m3 0.181 21.7 07/06/2023 22:28TO-15 Tetrahydrofuran µg/m3 0.107 57.1 07/06/2023 22:28TO-15 Toluene µg/m3 0.090 J1.57 07/06/2023 22:28TO-15 Trichlorofluoromethane µg/m3 0.130 5.05 07/06/2023 22:28TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.933 07/06/2023 22:28TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 4.07 07/06/2023 22:28TO-15 o-Xylene µg/m3 0.157 13.7 07/06/2023 22:28TO-15 m,p-Xylene µg/m3 0.217 17.8 07/06/2023 22:28TO-15 Xylene (Total)µg/m3 0.157 V 99280IAS-1 458 07/11/2023 12:36TO-15 Acetone µg/m3 4.04 JB0.836 07/06/2023 23:19TO-15 Benzene µg/m3 0.073 Page 11 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99280IAS-1 JB0.909 07/06/2023 23:19TO-15 Carbon Disulfide µg/m3 0.060 J0.999 07/06/2023 23:19TO-15 Chloromethane µg/m3 0.067 2.65 07/06/2023 23:19TO-15 Dichlorodifluoromethane µg/m3 0.134 J1.20 07/06/2023 23:19TO-15 Ethyl Acetate µg/m3 0.136 2.26 07/06/2023 23:19TO-15 Ethylbenzene µg/m3 0.106 7.48 07/06/2023 23:19TO-15 Heptane µg/m3 0.143 2.65 07/06/2023 23:19TO-15 n-Hexane µg/m3 0.047 5.79 07/06/2023 23:19TO-15 2-Hexanone µg/m3 0.285 56.5 07/06/2023 23:19TO-15 Isopropyl Alcohol µg/m3 0.139 30.0 07/06/2023 23:19TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J1.32 07/06/2023 23:19TO-15 4-Methyl-2-Pentanone µg/m3 0.121 9.77 07/06/2023 23:19TO-15 Styrene µg/m3 0.124 17.3 07/06/2023 23:19TO-15 Tetrahydrofuran µg/m3 0.107 57.0 07/06/2023 23:19TO-15 Toluene µg/m3 0.090 J1.73 07/06/2023 23:19TO-15 Trichlorofluoromethane µg/m3 0.130 4.42 07/06/2023 23:19TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.904 07/06/2023 23:19TO-15 1,3,5-Trimethylbenzene µg/m3 0.236 2.58 07/06/2023 23:19TO-15 o-Xylene µg/m3 0.157 8.34 07/06/2023 23:19TO-15 m,p-Xylene µg/m3 0.217 10.9 07/06/2023 23:19TO-15 Xylene (Total)µg/m3 0.157 V 99281IAS-BKG 21.3 07/07/2023 00:07TO-15 Acetone µg/m3 0.202 JB0.485 07/07/2023 00:07TO-15 Benzene µg/m3 0.073 JB0.295 07/07/2023 00:07TO-15 Carbon Disulfide µg/m3 0.060 J0.850 07/07/2023 00:07TO-15 Chloromethane µg/m3 0.067 2.59 07/07/2023 00:07TO-15 Dichlorodifluoromethane µg/m3 0.134 J2.09 07/07/2023 00:07TO-15 Isopropyl Alcohol µg/m3 0.139 2.08 07/07/2023 00:07TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 JB1.02 07/07/2023 00:07TO-15 Toluene µg/m3 0.090 J1.52 07/07/2023 00:07TO-15 Trichlorofluoromethane µg/m3 0.130 V 99282IAS-2 39.2 07/07/2023 00:54TO-15 Acetone µg/m3 0.202 JB0.559 07/07/2023 00:54TO-15 Benzene µg/m3 0.073 J0.854 07/07/2023 00:54TO-15 Chloroform µg/m3 0.086 J0.976 07/07/2023 00:54TO-15 Chloromethane µg/m3 0.067 18.1 07/07/2023 00:54TO-15 Dichlorodifluoromethane µg/m3 0.134 Page 12 of 100 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-177-0008 Report Limit Project:LEN-008 V 99282IAS-2 J0.428 07/07/2023 00:54TO-15 Ethyl Acetate µg/m3 0.136 J0.369 07/07/2023 00:54TO-15 Ethylbenzene µg/m3 0.106 J0.762 07/07/2023 00:54TO-15 Heptane µg/m3 0.143 J0.764 07/07/2023 00:54TO-15 n-Hexane µg/m3 0.047 J0.389 07/07/2023 00:54TO-15 2-Hexanone µg/m3 0.285 6.94 07/07/2023 00:54TO-15 Isopropyl Alcohol µg/m3 0.139 3.81 07/07/2023 00:54TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.562 07/07/2023 00:54TO-15 Methylene Chloride µg/m3 0.488 J0.672 07/07/2023 00:54TO-15 Styrene µg/m3 0.124 J0.693 07/07/2023 00:54TO-15 Tetrahydrofuran µg/m3 0.107 B4.17 07/07/2023 00:54TO-15 Toluene µg/m3 0.090 35.4 07/07/2023 00:54TO-15 Trichlorofluoromethane µg/m3 0.130 J2.40 07/07/2023 00:54TO-15 1,2,4-Trimethylbenzene µg/m3 0.110 J0.377 07/07/2023 00:54TO-15 o-Xylene µg/m3 0.157 J1.92 07/07/2023 00:54TO-15 m,p-Xylene µg/m3 0.217 J2.30 07/07/2023 00:54TO-15 Xylene (Total)µg/m3 0.157 Page 13 of 100   Client: Hart & Hickman (Charlotte) CASE NARRATIVE Project: LEN-008 Lab Report Number: 23-177-0008 Date: 7/20/2023 Report Comments Revised Report: Revision 2 Summary of detections has been updated. Volatile Organic Compounds in Air- GC/MS Method TO-15 Sample 99269 (SS-MP-7) QC Batch No: V34774/V34773 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 99267 (SS-MP-2) QC Batch No: V34795/V34794 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 99268 (SS-MP-DUP) QC Batch No: V34795/V34794 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. High non-target compounds present. Sample 99272 (SS-MP-6) QC Batch No: V34795/V34794 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Analyte: 1,1,2,2-Tetrachloroethane QC Batch No: V34864/V34794 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Sample 99274 (SS-MP-8) QC Batch No: V34837/V34836 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 99275 (SS-MP-5) QC Batch No: V34837/V34836 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Page 14 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-2 99267 Matrix: 6/21/2023 11:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 249 µg/m3 10.1 238Acetone 50 06/28/23 22:01 V34795ENM 0.875 J µg/m3 0.146 3.19Benzene 2 06/29/23 06:05 V34795ENM <0.293 µg/m3 0.293 20.7Benzyl Chloride 2 06/29/23 06:05 V34795ENM <0.299 µg/m3 0.299 6.70Bromodichloromethane 2 06/29/23 06:05 V34795ENM <0.304 µg/m3 0.304 10.3Bromoform 2 06/29/23 06:05 V34795ENM <0.229 µg/m3 0.229 3.88Bromomethane 2 06/29/23 06:05 V34795ENM <0.653 µg/m3 0.653 2.211,3-Butadiene 2 06/29/23 06:05 V34795ENM 1.49 J µg/m3 0.122 12.5Carbon Disulfide 2 06/29/23 06:05 V34795ENM <0.309 µg/m3 0.309 6.29 Carbon Tetrachloride 2 06/29/23 06:05 V34795ENM <0.213 µg/m3 0.213 4.60Chlorobenzene 2 06/29/23 06:05 V34795ENM <0.416 µg/m3 0.416 8.52Chlorodibromomethane 2 06/29/23 06:05 V34795ENM <0.328 µg/m3 0.328 2.64Chloroethane 2 06/29/23 06:05 V34795ENM 2.97 J µg/m3 0.172 4.88Chloroform 2 06/29/23 06:05 V34795ENM 2.14 µg/m3 0.134 2.06Chloromethane 2 06/29/23 06:05 V34795ENM <0.321 µg/m3 0.321 6.88Cyclohexane 2 06/29/23 06:05 V34795ENM <0.301 µg/m3 0.301 7.68 1,2-Dibromoethane 2 06/29/23 06:05 V34795ENM <0.192 µg/m3 0.192 6.011,2-Dichlorobenzene 2 06/29/23 06:05 V34795ENM <0.348 µg/m3 0.348 24.11,3-Dichlorobenzene 2 06/29/23 06:05 V34795ENM <0.371 µg/m3 0.371 6.011,4-Dichlorobenzene 2 06/29/23 06:05 V34795ENM 2.73 J µg/m3 0.267 4.94Dichlorodifluoromethane 2 06/29/23 06:05 V34795ENM <0.202 µg/m3 0.202 4.051,1-Dichloroethane 2 06/29/23 06:05 V34795ENM <0.258 µg/m3 0.258 4.051,2-Dichloroethane 2 06/29/23 06:05 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-2 99267 Matrix: 6/21/2023 11:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.213 µg/m3 0.213 3.961,1-Dichloroethene 2 06/29/23 06:05 V34795ENM <0.190 µg/m3 0.190 3.96cis-1,2-Dichloroethene 2 06/29/23 06:05 V34795ENM <0.215 µg/m3 0.215 3.96trans-1,2-Dichloroethene 2 06/29/23 06:05 V34795ENM <0.409 µg/m3 0.409 4.621,2-Dichloropropane 2 06/29/23 06:05 V34795ENM <1.24 µg/m3 1.24 6.991,2-Dichlorotetrafluoroethane 2 06/29/23 06:05 V34795ENM <0.356 µg/m3 0.356 4.54cis-1,3-Dichloropropene 2 06/29/23 06:05 V34795ENM <0.356 µg/m3 0.356 4.54trans-1,3-Dichloropropene 2 06/29/23 06:05 V34795ENM <0.869 µg/m3 0.869 3.601,4-Dioxane 2 06/29/23 06:05 V34795ENM 2.83 J µg/m3 0.271 3.60 Ethyl Acetate 2 06/29/23 06:05 V34795ENM 4.57 µg/m3 0.211 4.34Ethylbenzene 2 06/29/23 06:05 V34795ENM 1.14 J µg/m3 0.256 4.924-Ethyltoluene 2 06/29/23 06:05 V34795ENM <1.12 µg/m3 1.12 7.661,1,2-Trichloro-1,2,2-trifluoroethane 2 06/29/23 06:05 V34795ENM 2.48 J µg/m3 0.286 4.10Heptane 2 06/29/23 06:05 V34795ENM <0.662 µg/m3 0.662 10.7Hexachlorobutadiene 2 06/29/23 06:05 V34795ENM 1.10 J µg/m3 0.094 3.52n-Hexane 2 06/29/23 06:05 V34795ENM 1.98 J µg/m3 0.570 4.10 2-Hexanone 2 06/29/23 06:05 V34795ENM 30.4 µg/m3 0.277 9.83Isopropyl Alcohol 2 06/29/23 06:05 V34795ENM 295 µg/m3 0.448 2.95Methyl Ethyl Ketone (MEK)2 06/29/23 06:05 V34795ENM <0.067 µg/m3 0.067 3.61Methyl tert-butyl ether (MTBE)2 06/29/23 06:05 V34795ENM 1.05 J µg/m3 0.242 4.104-Methyl-2-Pentanone 2 06/29/23 06:05 V34795ENM <0.975 µg/m3 0.975 3.47Methylene Chloride 2 06/29/23 06:05 V34795ENM <0.365 µg/m3 0.365 5.24Naphthalene 2 06/29/23 06:05 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 16 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-2 99267 Matrix: 6/21/2023 11:02 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.483 µg/m3 0.483 1.72Propene 2 06/29/23 06:05 V34795ENM 1.76 J µg/m3 0.248 4.26Styrene 2 06/29/23 06:05 V34795ENM <0.207 µg/m3 0.207 6.861,1,2,2-Tetrachloroethane 2 06/29/23 06:05 V34795ENM <0.361 µg/m3 0.361 6.78Tetrachloroethene 2 06/29/23 06:05 V34795ENM 3690 µg/m3 5.35 73.7Tetrahydrofuran 50 06/28/23 22:01 V34795ENM 59.7 µg/m3 0.180 3.77Toluene 2 06/29/23 06:05 V34795ENM <0.417 µg/m3 0.417 7.421,2,4-Trichlorobenzene 2 06/29/23 06:05 V34795ENM <0.288 µg/m3 0.288 5.461,1,1-Trichloroethane 2 06/29/23 06:05 V34795ENM <0.175 µg/m3 0.175 5.46 1,1,2-Trichloroethane 2 06/29/23 06:05 V34795ENM <0.398 µg/m3 0.398 4.30Trichloroethene 2 06/29/23 06:05 V34795ENM 1.84 J µg/m3 0.260 5.62Trichlorofluoromethane 2 06/29/23 06:05 V34795ENM 4.51 J µg/m3 0.220 4.921,2,4-Trimethylbenzene 2 06/29/23 06:05 V34795ENM 1.86 J µg/m3 0.472 4.921,3,5-Trimethylbenzene 2 06/29/23 06:05 V34795ENM <0.447 µg/m3 0.447 3.52Vinyl Acetate 2 06/29/23 06:05 V34795ENM <0.254 µg/m3 0.254 2.56Vinyl Chloride 2 06/29/23 06:05 V34795ENM 6.30 µg/m3 0.313 4.34 o-Xylene 2 06/29/23 06:05 V34795ENM 22.3 µg/m3 0.434 11.3m,p-Xylene 2 06/29/23 06:05 V34795ENM 28.6 µg/m3 0.313 4.34Xylene (Total)2 06/29/23 06:05 V34795 Surrogate: 4-Bromofluorobenzene 108 Limits: 70-130%06/29/23 06:052 ENM V34795 Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%06/28/23 22:0150 ENM V34795 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 17 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-DUP 99268 Matrix: 6/22/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 252 µg/m3 10.1 238Acetone 50 06/28/23 22:37 V34795ENM 1.06 J µg/m3 0.146 3.19Benzene 2 06/29/23 06:49 V34795ENM <0.293 µg/m3 0.293 20.7Benzyl Chloride 2 06/29/23 06:49 V34795ENM <0.299 µg/m3 0.299 6.70Bromodichloromethane 2 06/29/23 06:49 V34795ENM <0.304 µg/m3 0.304 10.3Bromoform 2 06/29/23 06:49 V34795ENM <0.229 µg/m3 0.229 3.88Bromomethane 2 06/29/23 06:49 V34795ENM <0.653 µg/m3 0.653 2.211,3-Butadiene 2 06/29/23 06:49 V34795ENM 2.50 J µg/m3 0.122 12.5Carbon Disulfide 2 06/29/23 06:49 V34795ENM <0.309 µg/m3 0.309 6.29 Carbon Tetrachloride 2 06/29/23 06:49 V34795ENM <0.213 µg/m3 0.213 4.60Chlorobenzene 2 06/29/23 06:49 V34795ENM <0.416 µg/m3 0.416 8.52Chlorodibromomethane 2 06/29/23 06:49 V34795ENM <0.328 µg/m3 0.328 2.64Chloroethane 2 06/29/23 06:49 V34795ENM 2.97 J µg/m3 0.172 4.88Chloroform 2 06/29/23 06:49 V34795ENM <0.134 µg/m3 0.134 2.06Chloromethane 2 06/29/23 06:49 V34795ENM <0.321 µg/m3 0.321 6.88Cyclohexane 2 06/29/23 06:49 V34795ENM <0.301 µg/m3 0.301 7.68 1,2-Dibromoethane 2 06/29/23 06:49 V34795ENM <0.192 µg/m3 0.192 6.011,2-Dichlorobenzene 2 06/29/23 06:49 V34795ENM <0.348 µg/m3 0.348 24.11,3-Dichlorobenzene 2 06/29/23 06:49 V34795ENM <0.371 µg/m3 0.371 6.011,4-Dichlorobenzene 2 06/29/23 06:49 V34795ENM 2.75 J µg/m3 0.267 4.94Dichlorodifluoromethane 2 06/29/23 06:49 V34795ENM <0.202 µg/m3 0.202 4.051,1-Dichloroethane 2 06/29/23 06:49 V34795ENM <0.258 µg/m3 0.258 4.051,2-Dichloroethane 2 06/29/23 06:49 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 18 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-DUP 99268 Matrix: 6/22/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.213 µg/m3 0.213 3.961,1-Dichloroethene 2 06/29/23 06:49 V34795ENM <0.190 µg/m3 0.190 3.96cis-1,2-Dichloroethene 2 06/29/23 06:49 V34795ENM <0.215 µg/m3 0.215 3.96trans-1,2-Dichloroethene 2 06/29/23 06:49 V34795ENM <0.409 µg/m3 0.409 4.621,2-Dichloropropane 2 06/29/23 06:49 V34795ENM <1.24 µg/m3 1.24 6.991,2-Dichlorotetrafluoroethane 2 06/29/23 06:49 V34795ENM <0.356 µg/m3 0.356 4.54cis-1,3-Dichloropropene 2 06/29/23 06:49 V34795ENM <0.356 µg/m3 0.356 4.54trans-1,3-Dichloropropene 2 06/29/23 06:49 V34795ENM <0.869 µg/m3 0.869 3.601,4-Dioxane 2 06/29/23 06:49 V34795ENM 3.79 µg/m3 0.271 3.60 Ethyl Acetate 2 06/29/23 06:49 V34795ENM 4.49 µg/m3 0.211 4.34Ethylbenzene 2 06/29/23 06:49 V34795ENM 1.03 J µg/m3 0.256 4.924-Ethyltoluene 2 06/29/23 06:49 V34795ENM <1.12 µg/m3 1.12 7.661,1,2-Trichloro-1,2,2-trifluoroethane 2 06/29/23 06:49 V34795ENM 2.64 J µg/m3 0.286 4.10Heptane 2 06/29/23 06:49 V34795ENM <0.662 µg/m3 0.662 10.7Hexachlorobutadiene 2 06/29/23 06:49 V34795ENM 1.21 J µg/m3 0.094 3.52n-Hexane 2 06/29/23 06:49 V34795ENM 1.87 J µg/m3 0.570 4.10 2-Hexanone 2 06/29/23 06:49 V34795ENM 31.9 µg/m3 0.277 9.83Isopropyl Alcohol 2 06/29/23 06:49 V34795ENM 253 µg/m3 11.2 73.7Methyl Ethyl Ketone (MEK)50 06/28/23 22:37 V34795ENM <0.067 µg/m3 0.067 3.61Methyl tert-butyl ether (MTBE)2 06/29/23 06:49 V34795ENM 0.950 J µg/m3 0.242 4.104-Methyl-2-Pentanone 2 06/29/23 06:49 V34795ENM <0.975 µg/m3 0.975 3.47Methylene Chloride 2 06/29/23 06:49 V34795ENM <0.365 µg/m3 0.365 5.24Naphthalene 2 06/29/23 06:49 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 19 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-DUP 99268 Matrix: 6/22/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.483 µg/m3 0.483 1.72Propene 2 06/29/23 06:49 V34795ENM 1.89 J µg/m3 0.248 4.26Styrene 2 06/29/23 06:49 V34795ENM <0.207 µg/m3 0.207 6.861,1,2,2-Tetrachloroethane 2 06/29/23 06:49 V34795ENM <0.361 µg/m3 0.361 6.78Tetrachloroethene 2 06/29/23 06:49 V34795ENM 3840 µg/m3 5.35 73.7Tetrahydrofuran 50 06/28/23 22:37 V34795ENM 60.4 µg/m3 0.180 3.77Toluene 2 06/29/23 06:49 V34795ENM <0.417 µg/m3 0.417 7.421,2,4-Trichlorobenzene 2 06/29/23 06:49 V34795ENM <0.288 µg/m3 0.288 5.461,1,1-Trichloroethane 2 06/29/23 06:49 V34795ENM <0.175 µg/m3 0.175 5.46 1,1,2-Trichloroethane 2 06/29/23 06:49 V34795ENM <0.398 µg/m3 0.398 4.30Trichloroethene 2 06/29/23 06:49 V34795ENM 1.88 J µg/m3 0.260 5.62Trichlorofluoromethane 2 06/29/23 06:49 V34795ENM 4.58 J µg/m3 0.220 4.921,2,4-Trimethylbenzene 2 06/29/23 06:49 V34795ENM 1.78 J µg/m3 0.472 4.921,3,5-Trimethylbenzene 2 06/29/23 06:49 V34795ENM <0.447 µg/m3 0.447 3.52Vinyl Acetate 2 06/29/23 06:49 V34795ENM <0.254 µg/m3 0.254 2.56Vinyl Chloride 2 06/29/23 06:49 V34795ENM 6.62 µg/m3 0.313 4.34 o-Xylene 2 06/29/23 06:49 V34795ENM 21.9 µg/m3 0.434 11.3m,p-Xylene 2 06/29/23 06:49 V34795ENM 28.5 µg/m3 0.313 4.34Xylene (Total)2 06/29/23 06:49 V34795 Surrogate: 4-Bromofluorobenzene 108 Limits: 70-130%06/29/23 06:492 ENM V34795 Surrogate: 4-Bromofluorobenzene 96.9 Limits: 70-130%06/28/23 22:3750 ENM V34795 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 20 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-7 99269 Matrix: 6/22/2023 16:41 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34773 06/27/23 09:00 V34794 06/28/23 09:00 5970 µg/m3 40.4 950Acetone 200 06/28/23 23:14 V34795ENM <1.46 µg/m3 1.46 31.9Benzene 20 06/27/23 22:27 V34774ENM <2.94 µg/m3 2.94 207Benzyl Chloride 20 06/27/23 22:27 V34774ENM <3.00 µg/m3 3.00 67.0Bromodichloromethane 20 06/27/23 22:27 V34774ENM <3.05 µg/m3 3.05 103Bromoform 20 06/27/23 22:27 V34774ENM <2.30 µg/m3 2.30 38.8Bromomethane 20 06/27/23 22:27 V34774ENM <6.53 µg/m3 6.53 22.11,3-Butadiene 20 06/27/23 22:27 V34774ENM 4.61 J µg/m3 1.22 125Carbon Disulfide 20 06/27/23 22:27 V34774ENM <3.10 µg/m3 3.10 62.9 Carbon Tetrachloride 20 06/27/23 22:27 V34774ENM <2.14 µg/m3 2.14 46.0Chlorobenzene 20 06/27/23 22:27 V34774ENM <4.16 µg/m3 4.16 85.2Chlorodibromomethane 20 06/27/23 22:27 V34774ENM <3.28 µg/m3 3.28 26.4Chloroethane 20 06/27/23 22:27 V34774ENM 7.62 J µg/m3 1.73 48.8Chloroform 20 06/27/23 22:27 V34774ENM <1.34 µg/m3 1.34 20.6Chloromethane 20 06/27/23 22:27 V34774ENM <3.22 µg/m3 3.22 68.8Cyclohexane 20 06/27/23 22:27 V34774ENM <3.02 µg/m3 3.02 76.8 1,2-Dibromoethane 20 06/27/23 22:27 V34774ENM <1.92 µg/m3 1.92 60.11,2-Dichlorobenzene 20 06/27/23 22:27 V34774ENM <3.48 µg/m3 3.48 2411,3-Dichlorobenzene 20 06/27/23 22:27 V34774ENM <3.72 µg/m3 3.72 60.11,4-Dichlorobenzene 20 06/27/23 22:27 V34774ENM <2.68 µg/m3 2.68 49.4Dichlorodifluoromethane 20 06/27/23 22:27 V34774ENM <2.02 µg/m3 2.02 40.51,1-Dichloroethane 20 06/27/23 22:27 V34774ENM <2.58 µg/m3 2.58 40.51,2-Dichloroethane 20 06/27/23 22:27 V34774ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 21 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-7 99269 Matrix: 6/22/2023 16:41 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34773 06/27/23 09:00 V34794 06/28/23 09:00 <2.14 µg/m3 2.14 39.61,1-Dichloroethene 20 06/27/23 22:27 V34774ENM <1.91 µg/m3 1.91 39.6cis-1,2-Dichloroethene 20 06/27/23 22:27 V34774ENM <2.16 µg/m3 2.16 39.6trans-1,2-Dichloroethene 20 06/27/23 22:27 V34774ENM <4.10 µg/m3 4.10 46.21,2-Dichloropropane 20 06/27/23 22:27 V34774ENM <12.4 µg/m3 12.4 69.91,2-Dichlorotetrafluoroethane 20 06/27/23 22:27 V34774ENM <3.56 µg/m3 3.56 45.4cis-1,3-Dichloropropene 20 06/27/23 22:27 V34774ENM <3.56 µg/m3 3.56 45.4trans-1,3-Dichloropropene 20 06/27/23 22:27 V34774ENM <8.69 µg/m3 8.69 36.01,4-Dioxane 20 06/27/23 22:27 V34774ENM <2.72 µg/m3 2.72 36.0 Ethyl Acetate 20 06/27/23 22:27 V34774ENM <2.12 µg/m3 2.12 43.4Ethylbenzene 20 06/27/23 22:27 V34774ENM <2.56 µg/m3 2.56 49.24-Ethyltoluene 20 06/27/23 22:27 V34774ENM <11.2 µg/m3 11.2 76.61,1,2-Trichloro-1,2,2-trifluoroethane 20 06/27/23 22:27 V34774ENM <2.86 µg/m3 2.86 41.0Heptane 20 06/27/23 22:27 V34774ENM <6.62 µg/m3 6.62 107Hexachlorobutadiene 20 06/27/23 22:27 V34774ENM <0.942 µg/m3 0.942 35.2n-Hexane 20 06/27/23 22:27 V34774ENM <5.71 µg/m3 5.71 41.0 2-Hexanone 20 06/27/23 22:27 V34774ENM 21.6 J µg/m3 2.78 98.3Isopropyl Alcohol 20 06/27/23 22:27 V34774ENM 630 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 06/27/23 22:27 V34774ENM <0.672 µg/m3 0.672 36.1Methyl tert-butyl ether (MTBE)20 06/27/23 22:27 V34774ENM <2.42 µg/m3 2.42 41.04-Methyl-2-Pentanone 20 06/27/23 22:27 V34774ENM <9.75 µg/m3 9.75 34.7Methylene Chloride 20 06/27/23 22:27 V34774ENM <3.66 µg/m3 3.66 52.4Naphthalene 20 06/27/23 22:27 V34774ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 22 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-7 99269 Matrix: 6/22/2023 16:41 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34773 06/27/23 09:00 V34794 06/28/23 09:00 <4.84 µg/m3 4.84 17.2Propene 20 06/27/23 22:27 V34774ENM <2.48 µg/m3 2.48 42.6Styrene 20 06/27/23 22:27 V34774ENM <2.08 µg/m3 2.08 68.61,1,2,2-Tetrachloroethane 20 06/27/23 22:27 V34774ENM <3.62 µg/m3 3.62 67.8Tetrachloroethene 20 06/27/23 22:27 V34774ENM 14000 µg/m3 21.4 295Tetrahydrofuran 200 06/28/23 23:14 V34795ENM 8.14 J µg/m3 1.80 37.7Toluene 20 06/27/23 22:27 V34774ENM <4.18 µg/m3 4.18 74.21,2,4-Trichlorobenzene 20 06/27/23 22:27 V34774ENM <2.88 µg/m3 2.88 54.61,1,1-Trichloroethane 20 06/27/23 22:27 V34774ENM <1.75 µg/m3 1.75 54.6 1,1,2-Trichloroethane 20 06/27/23 22:27 V34774ENM <3.98 µg/m3 3.98 43.0Trichloroethene 20 06/27/23 22:27 V34774ENM <2.60 µg/m3 2.60 56.2Trichlorofluoromethane 20 06/27/23 22:27 V34774ENM <2.20 µg/m3 2.20 49.21,2,4-Trimethylbenzene 20 06/27/23 22:27 V34774ENM <4.72 µg/m3 4.72 49.21,3,5-Trimethylbenzene 20 06/27/23 22:27 V34774ENM <4.48 µg/m3 4.48 35.2Vinyl Acetate 20 06/27/23 22:27 V34774ENM <2.54 µg/m3 2.54 25.6Vinyl Chloride 20 06/27/23 22:27 V34774ENM <3.14 µg/m3 3.14 43.4 o-Xylene 20 06/27/23 22:27 V34774ENM <4.34 µg/m3 4.34 113m,p-Xylene 20 06/27/23 22:27 V34774ENM <3.14 µg/m3 3.14 43.4Xylene (Total)20 06/27/23 22:27 V34774 Surrogate: 4-Bromofluorobenzene 113 Limits: 70-130%06/27/23 22:2720 ENM V34774 Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%06/28/23 23:14200 ENM V34795 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 23 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-3 99270 Matrix: 6/22/2023 11:42 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 118 µg/m3 0.202 4.75Acetone 1 06/29/23 00:08 V34795ENM 0.396 J µg/m3 0.073 1.60Benzene 1 06/29/23 00:08 V34795ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/29/23 00:08 V34795ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/29/23 00:08 V34795ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/29/23 00:08 V34795ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/29/23 00:08 V34795ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/29/23 00:08 V34795ENM 1.60 J µg/m3 0.060 6.23Carbon Disulfide 1 06/29/23 00:08 V34795ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/29/23 00:08 V34795ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/29/23 00:08 V34795ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/29/23 00:08 V34795ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/29/23 00:08 V34795ENM 22.1 µg/m3 0.086 2.44Chloroform 1 06/29/23 00:08 V34795ENM 0.877 J µg/m3 0.067 1.03Chloromethane 1 06/29/23 00:08 V34795ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/29/23 00:08 V34795ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/29/23 00:08 V34795ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/29/23 00:08 V34795ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/29/23 00:08 V34795ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/29/23 00:08 V34795ENM 2.64 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/29/23 00:08 V34795ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/29/23 00:08 V34795ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/29/23 00:08 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 24 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-3 99270 Matrix: 6/22/2023 11:42 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/29/23 00:08 V34795ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/29/23 00:08 V34795ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/29/23 00:08 V34795ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 06/29/23 00:08 V34795ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/29/23 00:08 V34795ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/29/23 00:08 V34795ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/29/23 00:08 V34795ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/29/23 00:08 V34795ENM 3.15 µg/m3 0.136 1.80 Ethyl Acetate 1 06/29/23 00:08 V34795ENM 0.998 J µg/m3 0.106 2.17Ethylbenzene 1 06/29/23 00:08 V34795ENM 0.584 J µg/m3 0.128 2.464-Ethyltoluene 1 06/29/23 00:08 V34795ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/29/23 00:08 V34795ENM 0.368 J µg/m3 0.143 2.05Heptane 1 06/29/23 00:08 V34795ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/29/23 00:08 V34795ENM <0.047 µg/m3 0.047 1.76n-Hexane 1 06/29/23 00:08 V34795ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 06/29/23 00:08 V34795ENM 13.9 µg/m3 0.139 4.92Isopropyl Alcohol 1 06/29/23 00:08 V34795ENM 842 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 06/27/23 23:04 V34855ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/29/23 00:08 V34795ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/29/23 00:08 V34795ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 06/29/23 00:08 V34795ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/29/23 00:08 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 25 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-3 99270 Matrix: 6/22/2023 11:42 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/29/23 00:08 V34795ENM 0.796 J µg/m3 0.124 2.13Styrene 1 06/29/23 00:08 V34795ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/29/23 00:08 V34795ENM 1.70 J µg/m3 0.181 3.39Tetrachloroethene 1 06/29/23 00:08 V34795ENM 1910 µg/m3 2.14 29.5Tetrahydrofuran 20 06/27/23 23:04 V34855ENM 7.19 µg/m3 0.090 1.88Toluene 1 06/29/23 00:08 V34795ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/29/23 00:08 V34795ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/29/23 00:08 V34795ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/29/23 00:08 V34795ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/29/23 00:08 V34795ENM 2.10 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/29/23 00:08 V34795ENM 2.66 µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/29/23 00:08 V34795ENM 0.771 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/29/23 00:08 V34795ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/29/23 00:08 V34795ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/29/23 00:08 V34795ENM 1.90 J µg/m3 0.157 2.17 o-Xylene 1 06/29/23 00:08 V34795ENM 5.64 J µg/m3 0.217 5.65m,p-Xylene 1 06/29/23 00:08 V34795ENM 7.54 J µg/m3 0.157 2.17Xylene (Total)1 06/29/23 00:08 V34795 Surrogate: 4-Bromofluorobenzene 115 Limits: 70-130%06/29/23 00:081 ENM V34795 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%06/27/23 23:0420 ENM V34855 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 26 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-4 99271 Matrix: 6/22/2023 13:28 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 134 µg/m3 4.04 95.0Acetone 20 06/27/23 23:41 V34855ENM 0.373 J µg/m3 0.073 1.60Benzene 1 06/29/23 00:58 V34795ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/29/23 00:58 V34795ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/29/23 00:58 V34795ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/29/23 00:58 V34795ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/29/23 00:58 V34795ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/29/23 00:58 V34795ENM 0.971 J µg/m3 0.060 6.23Carbon Disulfide 1 06/29/23 00:58 V34795ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/29/23 00:58 V34795ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/29/23 00:58 V34795ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/29/23 00:58 V34795ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/29/23 00:58 V34795ENM 9.83 µg/m3 0.086 2.44Chloroform 1 06/29/23 00:58 V34795ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/29/23 00:58 V34795ENM 2.36 J µg/m3 0.161 3.44Cyclohexane 1 06/29/23 00:58 V34795ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/29/23 00:58 V34795ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/29/23 00:58 V34795ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/29/23 00:58 V34795ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/29/23 00:58 V34795ENM 2.45 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/29/23 00:58 V34795ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/29/23 00:58 V34795ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/29/23 00:58 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 27 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-4 99271 Matrix: 6/22/2023 13:28 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/29/23 00:58 V34795ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/29/23 00:58 V34795ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/29/23 00:58 V34795ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 06/29/23 00:58 V34795ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/29/23 00:58 V34795ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/29/23 00:58 V34795ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/29/23 00:58 V34795ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/29/23 00:58 V34795ENM 0.799 J µg/m3 0.136 1.80 Ethyl Acetate 1 06/29/23 00:58 V34795ENM 0.694 J µg/m3 0.106 2.17Ethylbenzene 1 06/29/23 00:58 V34795ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/29/23 00:58 V34795ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/29/23 00:58 V34795ENM 0.704 J µg/m3 0.143 2.05Heptane 1 06/29/23 00:58 V34795ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/29/23 00:58 V34795ENM <0.047 µg/m3 0.047 1.76n-Hexane 1 06/29/23 00:58 V34795ENM 1.34 J µg/m3 0.285 2.05 2-Hexanone 1 06/29/23 00:58 V34795ENM 22.3 µg/m3 0.139 4.92Isopropyl Alcohol 1 06/29/23 00:58 V34795ENM 1160 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 06/27/23 23:41 V34855ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/29/23 00:58 V34795ENM 0.512 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/29/23 00:58 V34795ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 06/29/23 00:58 V34795ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/29/23 00:58 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 28 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-4 99271 Matrix: 6/22/2023 13:28 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/29/23 00:58 V34795ENM 2.28 µg/m3 0.124 2.13Styrene 1 06/29/23 00:58 V34795ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/29/23 00:58 V34795ENM 40.2 µg/m3 0.181 3.39Tetrachloroethene 1 06/29/23 00:58 V34795ENM 1840 µg/m3 2.14 29.5Tetrahydrofuran 20 06/27/23 23:41 V34855ENM 9.77 µg/m3 0.090 1.88Toluene 1 06/29/23 00:58 V34795ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/29/23 00:58 V34795ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/29/23 00:58 V34795ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/29/23 00:58 V34795ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/29/23 00:58 V34795ENM 1.89 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/29/23 00:58 V34795ENM 1.05 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/29/23 00:58 V34795ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/29/23 00:58 V34795ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/29/23 00:58 V34795ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/29/23 00:58 V34795ENM 1.09 J µg/m3 0.157 2.17 o-Xylene 1 06/29/23 00:58 V34795ENM 3.39 J µg/m3 0.217 5.65m,p-Xylene 1 06/29/23 00:58 V34795ENM 4.48 J µg/m3 0.157 2.17Xylene (Total)1 06/29/23 00:58 V34795 Surrogate: 4-Bromofluorobenzene 115 Limits: 70-130%06/29/23 00:581 ENM V34795 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%06/27/23 23:4120 ENM V34855 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 29 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-6 99272 Matrix: 6/22/2023 14:11 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 96.0 µg/m3 0.202 4.75Acetone 1 06/29/23 07:42 V34795ENM 0.287 J µg/m3 0.073 1.60Benzene 1 06/29/23 07:42 V34795ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/29/23 07:42 V34795ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/29/23 07:42 V34795ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/29/23 07:42 V34795ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/29/23 07:42 V34795ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/29/23 07:42 V34795ENM 0.965 J µg/m3 0.060 6.23Carbon Disulfide 1 06/29/23 07:42 V34795ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/29/23 07:42 V34795ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/29/23 07:42 V34795ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/29/23 07:42 V34795ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/29/23 07:42 V34795ENM 40.2 µg/m3 0.086 2.44Chloroform 1 06/29/23 07:42 V34795ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/29/23 07:42 V34795ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/29/23 07:42 V34795ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/29/23 07:42 V34795ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/29/23 07:42 V34795ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/29/23 07:42 V34795ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/29/23 07:42 V34795ENM 2.37 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/29/23 07:42 V34795ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/29/23 07:42 V34795ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/29/23 07:42 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 30 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-6 99272 Matrix: 6/22/2023 14:11 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/29/23 07:42 V34795ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/29/23 07:42 V34795ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/29/23 07:42 V34795ENM 2.16 J µg/m3 0.205 2.311,2-Dichloropropane 1 06/29/23 07:42 V34795ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/29/23 07:42 V34795ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/29/23 07:42 V34795ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/29/23 07:42 V34795ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/29/23 07:42 V34795ENM 2.21 µg/m3 0.136 1.80 Ethyl Acetate 1 06/29/23 07:42 V34795ENM 0.351 J µg/m3 0.106 2.17Ethylbenzene 1 06/29/23 07:42 V34795ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/29/23 07:42 V34795ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/29/23 07:42 V34795ENM 0.864 J µg/m3 0.143 2.05Heptane 1 06/29/23 07:42 V34795ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/29/23 07:42 V34795ENM 0.271 J µg/m3 0.047 1.76n-Hexane 1 06/29/23 07:42 V34795ENM 2.47 µg/m3 0.285 2.05 2-Hexanone 1 06/29/23 07:42 V34795ENM 16.2 µg/m3 0.139 4.92Isopropyl Alcohol 1 06/29/23 07:42 V34795ENM 2020 µg/m3 11.2 73.7Methyl Ethyl Ketone (MEK)50 06/29/23 01:34 V34795ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/29/23 07:42 V34795ENM 0.696 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/29/23 07:42 V34795ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 06/29/23 07:42 V34795ENM 4.15 µg/m3 0.183 2.62Naphthalene 1 06/29/23 07:42 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 31 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-6 99272 Matrix: 6/22/2023 14:11 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/29/23 07:42 V34795ENM 1.19 J µg/m3 0.124 2.13Styrene 1 06/29/23 07:42 V34795ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/29/23 07:42 V34795ENM 1.10 J µg/m3 0.181 3.39Tetrachloroethene 1 06/29/23 07:42 V34795ENM 3070 µg/m3 5.35 73.7Tetrahydrofuran 50 06/29/23 01:34 V34795ENM 4.37 µg/m3 0.090 1.88Toluene 1 06/29/23 07:42 V34795ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/29/23 07:42 V34795ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/29/23 07:42 V34795ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/29/23 07:42 V34795ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/29/23 07:42 V34795ENM 2.33 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/29/23 07:42 V34795ENM 0.884 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/29/23 07:42 V34795ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/29/23 07:42 V34795ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/29/23 07:42 V34795ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/29/23 07:42 V34795ENM 0.599 J µg/m3 0.157 2.17 o-Xylene 1 06/29/23 07:42 V34795ENM 2.33 J µg/m3 0.217 5.65m,p-Xylene 1 06/29/23 07:42 V34795ENM 2.93 J µg/m3 0.157 2.17Xylene (Total)1 06/29/23 07:42 V34795 Surrogate: 4-Bromofluorobenzene 109 Limits: 70-130%06/29/23 07:421 ENM V34795 Surrogate: 4-Bromofluorobenzene 96.9 Limits: 70-130%06/29/23 01:3450 ENM V34795 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 32 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-10 99273 Matrix: 6/22/2023 10:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 76.0 µg/m3 0.202 4.75Acetone 1 06/29/23 02:27 V34795ENM <0.073 µg/m3 0.073 1.60Benzene 1 06/29/23 02:27 V34795ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/29/23 02:27 V34795ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/29/23 02:27 V34795ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/29/23 02:27 V34795ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/29/23 02:27 V34795ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/29/23 02:27 V34795ENM 0.759 J µg/m3 0.060 6.23Carbon Disulfide 1 06/29/23 02:27 V34795ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/29/23 02:27 V34795ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/29/23 02:27 V34795ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/29/23 02:27 V34795ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/29/23 02:27 V34795ENM 1.43 J µg/m3 0.086 2.44Chloroform 1 06/29/23 02:27 V34795ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/29/23 02:27 V34795ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/29/23 02:27 V34795ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/29/23 02:27 V34795ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/29/23 02:27 V34795ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/29/23 02:27 V34795ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/29/23 02:27 V34795ENM 2.57 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/29/23 02:27 V34795ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/29/23 02:27 V34795ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/29/23 02:27 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 33 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-10 99273 Matrix: 6/22/2023 10:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/29/23 02:27 V34795ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/29/23 02:27 V34795ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/29/23 02:27 V34795ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 06/29/23 02:27 V34795ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/29/23 02:27 V34795ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/29/23 02:27 V34795ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/29/23 02:27 V34795ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/29/23 02:27 V34795ENM 14.8 µg/m3 0.136 1.80 Ethyl Acetate 1 06/29/23 02:27 V34795ENM 0.534 J µg/m3 0.106 2.17Ethylbenzene 1 06/29/23 02:27 V34795ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/29/23 02:27 V34795ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/29/23 02:27 V34795ENM 0.356 J µg/m3 0.143 2.05Heptane 1 06/29/23 02:27 V34795ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/29/23 02:27 V34795ENM 0.437 J µg/m3 0.047 1.76n-Hexane 1 06/29/23 02:27 V34795ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 06/29/23 02:27 V34795ENM 3.48 J µg/m3 0.139 4.92Isopropyl Alcohol 1 06/29/23 02:27 V34795ENM 274 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 06/28/23 00:55 V34855ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/29/23 02:27 V34795ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/29/23 02:27 V34795ENM <0.488 µg/m3 0.488 1.74Methylene Chloride 1 06/29/23 02:27 V34795ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/29/23 02:27 V34795ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 34 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-10 99273 Matrix: 6/22/2023 10:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34794 06/28/23 09:00 V34850 06/27/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/29/23 02:27 V34795ENM <0.124 µg/m3 0.124 2.13Styrene 1 06/29/23 02:27 V34795ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/29/23 02:27 V34795ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/29/23 02:27 V34795ENM 601 µg/m3 2.14 29.5Tetrahydrofuran 20 06/28/23 00:55 V34855ENM 5.04 µg/m3 0.090 1.88Toluene 1 06/29/23 02:27 V34795ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/29/23 02:27 V34795ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/29/23 02:27 V34795ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/29/23 02:27 V34795ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/29/23 02:27 V34795ENM 2.00 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/29/23 02:27 V34795ENM 0.535 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/29/23 02:27 V34795ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/29/23 02:27 V34795ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/29/23 02:27 V34795ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/29/23 02:27 V34795ENM 0.673 J µg/m3 0.157 2.17 o-Xylene 1 06/29/23 02:27 V34795ENM 2.34 J µg/m3 0.217 5.65m,p-Xylene 1 06/29/23 02:27 V34795ENM 3.01 J µg/m3 0.157 2.17Xylene (Total)1 06/29/23 02:27 V34795 Surrogate: 4-Bromofluorobenzene 112 Limits: 70-130%06/29/23 02:271 ENM V34795 Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%06/28/23 00:5520 ENM V34855 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 35 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-8 99274 Matrix: 6/22/2023 15:35 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 93.1 µg/m3 0.404 9.50Acetone 2 06/29/23 13:35 V34837ENM <0.146 µg/m3 0.146 3.19Benzene 2 06/29/23 13:35 V34837ENM <0.293 µg/m3 0.293 20.7Benzyl Chloride 2 06/29/23 13:35 V34837ENM 1.23 J µg/m3 0.299 6.70Bromodichloromethane 2 06/29/23 13:35 V34837ENM <0.304 µg/m3 0.304 10.3Bromoform 2 06/29/23 13:35 V34837ENM <0.229 µg/m3 0.229 3.88Bromomethane 2 06/29/23 13:35 V34837ENM <0.653 µg/m3 0.653 2.211,3-Butadiene 2 06/29/23 13:35 V34837ENM 0.741 J µg/m3 0.122 12.5Carbon Disulfide 2 06/29/23 13:35 V34837ENM <0.309 µg/m3 0.309 6.29 Carbon Tetrachloride 2 06/29/23 13:35 V34837ENM <0.213 µg/m3 0.213 4.60Chlorobenzene 2 06/29/23 13:35 V34837ENM <0.416 µg/m3 0.416 8.52Chlorodibromomethane 2 06/29/23 13:35 V34837ENM <0.328 µg/m3 0.328 2.64Chloroethane 2 06/29/23 13:35 V34837ENM 12.8 µg/m3 0.172 4.88Chloroform 2 06/29/23 13:35 V34837ENM 0.631 J µg/m3 0.134 2.06Chloromethane 2 06/29/23 13:35 V34837ENM <0.321 µg/m3 0.321 6.88Cyclohexane 2 06/29/23 13:35 V34837ENM <0.301 µg/m3 0.301 7.68 1,2-Dibromoethane 2 06/29/23 13:35 V34837ENM <0.192 µg/m3 0.192 6.011,2-Dichlorobenzene 2 06/29/23 13:35 V34837ENM <0.348 µg/m3 0.348 24.11,3-Dichlorobenzene 2 06/29/23 13:35 V34837ENM <0.371 µg/m3 0.371 6.011,4-Dichlorobenzene 2 06/29/23 13:35 V34837ENM 2.99 J µg/m3 0.267 4.94Dichlorodifluoromethane 2 06/29/23 13:35 V34837ENM <0.202 µg/m3 0.202 4.051,1-Dichloroethane 2 06/29/23 13:35 V34837ENM <0.258 µg/m3 0.258 4.051,2-Dichloroethane 2 06/29/23 13:35 V34837ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 36 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-8 99274 Matrix: 6/22/2023 15:35 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 <0.213 µg/m3 0.213 3.961,1-Dichloroethene 2 06/29/23 13:35 V34837ENM <0.190 µg/m3 0.190 3.96cis-1,2-Dichloroethene 2 06/29/23 13:35 V34837ENM <0.215 µg/m3 0.215 3.96trans-1,2-Dichloroethene 2 06/29/23 13:35 V34837ENM <0.409 µg/m3 0.409 4.621,2-Dichloropropane 2 06/29/23 13:35 V34837ENM <1.24 µg/m3 1.24 6.991,2-Dichlorotetrafluoroethane 2 06/29/23 13:35 V34837ENM <0.356 µg/m3 0.356 4.54cis-1,3-Dichloropropene 2 06/29/23 13:35 V34837ENM <0.356 µg/m3 0.356 4.54trans-1,3-Dichloropropene 2 06/29/23 13:35 V34837ENM <0.869 µg/m3 0.869 3.601,4-Dioxane 2 06/29/23 13:35 V34837ENM 1.83 J µg/m3 0.271 3.60 Ethyl Acetate 2 06/29/23 13:35 V34837ENM <0.211 µg/m3 0.211 4.34Ethylbenzene 2 06/29/23 13:35 V34837ENM <0.256 µg/m3 0.256 4.924-Ethyltoluene 2 06/29/23 13:35 V34837ENM <1.12 µg/m3 1.12 7.661,1,2-Trichloro-1,2,2-trifluoroethane 2 06/29/23 13:35 V34837ENM <0.286 µg/m3 0.286 4.10Heptane 2 06/29/23 13:35 V34837ENM <0.662 µg/m3 0.662 10.7Hexachlorobutadiene 2 06/29/23 13:35 V34837ENM <0.094 µg/m3 0.094 3.52n-Hexane 2 06/29/23 13:35 V34837ENM 1.22 J µg/m3 0.570 4.10 2-Hexanone 2 06/29/23 13:35 V34837ENM 8.43 J µg/m3 0.277 9.83Isopropyl Alcohol 2 06/29/23 13:35 V34837ENM 1170 µg/m3 11.2 73.7Methyl Ethyl Ketone (MEK)50 06/29/23 03:04 V34861ENM <0.067 µg/m3 0.067 3.61Methyl tert-butyl ether (MTBE)2 06/29/23 13:35 V34837ENM <0.242 µg/m3 0.242 4.104-Methyl-2-Pentanone 2 06/29/23 13:35 V34837ENM <0.975 µg/m3 0.975 3.47Methylene Chloride 2 06/29/23 13:35 V34837ENM <0.365 µg/m3 0.365 5.24Naphthalene 2 06/29/23 13:35 V34837ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 37 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-8 99274 Matrix: 6/22/2023 15:35 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 <0.483 µg/m3 0.483 1.72Propene 2 06/29/23 13:35 V34837ENM <0.248 µg/m3 0.248 4.26Styrene 2 06/29/23 13:35 V34837ENM <0.207 µg/m3 0.207 6.861,1,2,2-Tetrachloroethane 2 06/29/23 13:35 V34837ENM <0.361 µg/m3 0.361 6.78Tetrachloroethene 2 06/29/23 13:35 V34837ENM 4860 µg/m3 5.35 73.7Tetrahydrofuran 50 06/29/23 03:04 V34861ENM 6.63 µg/m3 0.180 3.77Toluene 2 06/29/23 13:35 V34837ENM <0.417 µg/m3 0.417 7.421,2,4-Trichlorobenzene 2 06/29/23 13:35 V34837ENM <0.288 µg/m3 0.288 5.461,1,1-Trichloroethane 2 06/29/23 13:35 V34837ENM <0.175 µg/m3 0.175 5.46 1,1,2-Trichloroethane 2 06/29/23 13:35 V34837ENM <0.398 µg/m3 0.398 4.30Trichloroethene 2 06/29/23 13:35 V34837ENM 3.16 J µg/m3 0.260 5.62Trichlorofluoromethane 2 06/29/23 13:35 V34837ENM <0.220 µg/m3 0.220 4.921,2,4-Trimethylbenzene 2 06/29/23 13:35 V34837ENM <0.472 µg/m3 0.472 4.921,3,5-Trimethylbenzene 2 06/29/23 13:35 V34837ENM <0.447 µg/m3 0.447 3.52Vinyl Acetate 2 06/29/23 13:35 V34837ENM <0.254 µg/m3 0.254 2.56Vinyl Chloride 2 06/29/23 13:35 V34837ENM <0.313 µg/m3 0.313 4.34 o-Xylene 2 06/29/23 13:35 V34837ENM 3.16 J µg/m3 0.434 11.3m,p-Xylene 2 06/29/23 13:35 V34837ENM 3.16 J µg/m3 0.313 4.34Xylene (Total)2 06/29/23 13:35 V34837 Surrogate: 4-Bromofluorobenzene 113 Limits: 70-130%06/29/23 13:352 ENM V34837 Surrogate: 4-Bromofluorobenzene 98.9 Limits: 70-130%06/29/23 03:0450 ENM V34861 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 38 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-5 99275 Matrix: 6/22/2023 13:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 763 µg/m3 10.1 238Acetone 50 06/29/23 03:40 V34861ENM 0.523 J µg/m3 0.146 3.19Benzene 2 06/29/23 14:19 V34837ENM <0.293 µg/m3 0.293 20.7Benzyl Chloride 2 06/29/23 14:19 V34837ENM <0.299 µg/m3 0.299 6.70Bromodichloromethane 2 06/29/23 14:19 V34837ENM <0.304 µg/m3 0.304 10.3Bromoform 2 06/29/23 14:19 V34837ENM <0.229 µg/m3 0.229 3.88Bromomethane 2 06/29/23 14:19 V34837ENM <0.653 µg/m3 0.653 2.211,3-Butadiene 2 06/29/23 14:19 V34837ENM 1.25 J µg/m3 0.122 12.5Carbon Disulfide 2 06/29/23 14:19 V34837ENM <0.309 µg/m3 0.309 6.29 Carbon Tetrachloride 2 06/29/23 14:19 V34837ENM <0.213 µg/m3 0.213 4.60Chlorobenzene 2 06/29/23 14:19 V34837ENM <0.416 µg/m3 0.416 8.52Chlorodibromomethane 2 06/29/23 14:19 V34837ENM <0.328 µg/m3 0.328 2.64Chloroethane 2 06/29/23 14:19 V34837ENM 22.5 µg/m3 0.172 4.88Chloroform 2 06/29/23 14:19 V34837ENM 1.65 J µg/m3 0.134 2.06Chloromethane 2 06/29/23 14:19 V34837ENM <0.321 µg/m3 0.321 6.88Cyclohexane 2 06/29/23 14:19 V34837ENM <0.301 µg/m3 0.301 7.68 1,2-Dibromoethane 2 06/29/23 14:19 V34837ENM <0.192 µg/m3 0.192 6.011,2-Dichlorobenzene 2 06/29/23 14:19 V34837ENM <0.348 µg/m3 0.348 24.11,3-Dichlorobenzene 2 06/29/23 14:19 V34837ENM <0.371 µg/m3 0.371 6.011,4-Dichlorobenzene 2 06/29/23 14:19 V34837ENM 2.54 J µg/m3 0.267 4.94Dichlorodifluoromethane 2 06/29/23 14:19 V34837ENM <0.202 µg/m3 0.202 4.051,1-Dichloroethane 2 06/29/23 14:19 V34837ENM <0.258 µg/m3 0.258 4.051,2-Dichloroethane 2 06/29/23 14:19 V34837ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 39 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-5 99275 Matrix: 6/22/2023 13:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 <0.213 µg/m3 0.213 3.961,1-Dichloroethene 2 06/29/23 14:19 V34837ENM <0.190 µg/m3 0.190 3.96cis-1,2-Dichloroethene 2 06/29/23 14:19 V34837ENM <0.215 µg/m3 0.215 3.96trans-1,2-Dichloroethene 2 06/29/23 14:19 V34837ENM <0.409 µg/m3 0.409 4.621,2-Dichloropropane 2 06/29/23 14:19 V34837ENM <1.24 µg/m3 1.24 6.991,2-Dichlorotetrafluoroethane 2 06/29/23 14:19 V34837ENM <0.356 µg/m3 0.356 4.54cis-1,3-Dichloropropene 2 06/29/23 14:19 V34837ENM <0.356 µg/m3 0.356 4.54trans-1,3-Dichloropropene 2 06/29/23 14:19 V34837ENM <0.869 µg/m3 0.869 3.601,4-Dioxane 2 06/29/23 14:19 V34837ENM <0.271 µg/m3 0.271 3.60 Ethyl Acetate 2 06/29/23 14:19 V34837ENM 1.53 J µg/m3 0.211 4.34Ethylbenzene 2 06/29/23 14:19 V34837ENM <0.256 µg/m3 0.256 4.924-Ethyltoluene 2 06/29/23 14:19 V34837ENM <1.12 µg/m3 1.12 7.661,1,2-Trichloro-1,2,2-trifluoroethane 2 06/29/23 14:19 V34837ENM 1.12 J µg/m3 0.286 4.10Heptane 2 06/29/23 14:19 V34837ENM <0.662 µg/m3 0.662 10.7Hexachlorobutadiene 2 06/29/23 14:19 V34837ENM <0.094 µg/m3 0.094 3.52n-Hexane 2 06/29/23 14:19 V34837ENM 5.75 µg/m3 0.570 4.10 2-Hexanone 2 06/29/23 14:19 V34837ENM 103 µg/m3 0.277 9.83Isopropyl Alcohol 2 06/29/23 14:19 V34837ENM 3780 µg/m3 11.2 73.7Methyl Ethyl Ketone (MEK)50 06/29/23 03:40 V34861ENM <0.067 µg/m3 0.067 3.61Methyl tert-butyl ether (MTBE)2 06/29/23 14:19 V34837ENM 1.45 J µg/m3 0.242 4.104-Methyl-2-Pentanone 2 06/29/23 14:19 V34837ENM <0.975 µg/m3 0.975 3.47Methylene Chloride 2 06/29/23 14:19 V34837ENM <0.365 µg/m3 0.365 5.24Naphthalene 2 06/29/23 14:19 V34837ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 40 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-5 99275 Matrix: 6/22/2023 13:04 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34836 06/29/23 09:00 V34860 06/28/23 09:00 <0.483 µg/m3 0.483 1.72Propene 2 06/29/23 14:19 V34837ENM 5.95 µg/m3 0.248 4.26Styrene 2 06/29/23 14:19 V34837ENM <0.207 µg/m3 0.207 6.861,1,2,2-Tetrachloroethane 2 06/29/23 14:19 V34837ENM 3.64 J µg/m3 0.361 6.78Tetrachloroethene 2 06/29/23 14:19 V34837ENM 4180 µg/m3 5.35 73.7Tetrahydrofuran 50 06/29/23 03:40 V34861ENM 28.7 µg/m3 0.180 3.77Toluene 2 06/29/23 14:19 V34837ENM <0.417 µg/m3 0.417 7.421,2,4-Trichlorobenzene 2 06/29/23 14:19 V34837ENM <0.288 µg/m3 0.288 5.461,1,1-Trichloroethane 2 06/29/23 14:19 V34837ENM <0.175 µg/m3 0.175 5.46 1,1,2-Trichloroethane 2 06/29/23 14:19 V34837ENM <0.398 µg/m3 0.398 4.30Trichloroethene 2 06/29/23 14:19 V34837ENM 2.72 J µg/m3 0.260 5.62Trichlorofluoromethane 2 06/29/23 14:19 V34837ENM 2.03 J µg/m3 0.220 4.921,2,4-Trimethylbenzene 2 06/29/23 14:19 V34837ENM <0.472 µg/m3 0.472 4.921,3,5-Trimethylbenzene 2 06/29/23 14:19 V34837ENM <0.447 µg/m3 0.447 3.52Vinyl Acetate 2 06/29/23 14:19 V34837ENM <0.254 µg/m3 0.254 2.56Vinyl Chloride 2 06/29/23 14:19 V34837ENM 2.26 J µg/m3 0.313 4.34 o-Xylene 2 06/29/23 14:19 V34837ENM 7.61 J µg/m3 0.434 11.3m,p-Xylene 2 06/29/23 14:19 V34837ENM 9.87 J µg/m3 0.313 4.34Xylene (Total)2 06/29/23 14:19 V34837 Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%06/29/23 14:192 ENM V34837 Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%06/29/23 03:4050 ENM V34861 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 41 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-9 99276 Matrix: 6/22/2023 14:58 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34838 06/28/23 09:00 V34850 06/27/23 09:00 38.8 µg/m3 0.202 4.75Acetone 1 06/29/23 04:32 V34842ENM 0.696 J µg/m3 0.073 1.60Benzene 1 06/29/23 04:32 V34842ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/29/23 04:32 V34842ENM 1.39 J µg/m3 0.150 3.35Bromodichloromethane 1 06/29/23 04:32 V34842ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/29/23 04:32 V34842ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/29/23 04:32 V34842ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/29/23 04:32 V34842ENM 1.26 J µg/m3 0.060 6.23Carbon Disulfide 1 06/29/23 04:32 V34842ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/29/23 04:32 V34842ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/29/23 04:32 V34842ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/29/23 04:32 V34842ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/29/23 04:32 V34842ENM 26.7 µg/m3 0.086 2.44Chloroform 1 06/29/23 04:32 V34842ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/29/23 04:32 V34842ENM 1.92 J µg/m3 0.161 3.44Cyclohexane 1 06/29/23 04:32 V34842ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/29/23 04:32 V34842ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/29/23 04:32 V34842ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/29/23 04:32 V34842ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/29/23 04:32 V34842ENM 3.14 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/29/23 04:32 V34842ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/29/23 04:32 V34842ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/29/23 04:32 V34842ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 42 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-9 99276 Matrix: 6/22/2023 14:58 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34838 06/28/23 09:00 V34850 06/27/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/29/23 04:32 V34842ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/29/23 04:32 V34842ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/29/23 04:32 V34842ENM 0.563 J µg/m3 0.205 2.311,2-Dichloropropane 1 06/29/23 04:32 V34842ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/29/23 04:32 V34842ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/29/23 04:32 V34842ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/29/23 04:32 V34842ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/29/23 04:32 V34842ENM 1.92 µg/m3 0.136 1.80 Ethyl Acetate 1 06/29/23 04:32 V34842ENM 0.325 J µg/m3 0.106 2.17Ethylbenzene 1 06/29/23 04:32 V34842ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/29/23 04:32 V34842ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/29/23 04:32 V34842ENM 0.651 J µg/m3 0.143 2.05Heptane 1 06/29/23 04:32 V34842ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/29/23 04:32 V34842ENM 1.67 J µg/m3 0.047 1.76n-Hexane 1 06/29/23 04:32 V34842ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 06/29/23 04:32 V34842ENM 7.90 µg/m3 0.139 4.92Isopropyl Alcohol 1 06/29/23 04:32 V34842ENM 141 µg/m3 4.48 29.5Methyl Ethyl Ketone (MEK)20 06/28/23 02:45 V34855ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/29/23 04:32 V34842ENM 0.331 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/29/23 04:32 V34842ENM 4.93 µg/m3 0.488 1.74Methylene Chloride 1 06/29/23 04:32 V34842ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/29/23 04:32 V34842ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 43 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-9 99276 Matrix: 6/22/2023 14:58 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34838 06/28/23 09:00 V34850 06/27/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/29/23 04:32 V34842ENM <0.124 µg/m3 0.124 2.13Styrene 1 06/29/23 04:32 V34842ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/29/23 04:32 V34842ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 06/29/23 04:32 V34842ENM 375 µg/m3 2.14 29.5Tetrahydrofuran 20 06/28/23 02:45 V34855ENM 4.12 µg/m3 0.090 1.88Toluene 1 06/29/23 04:32 V34842ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/29/23 04:32 V34842ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/29/23 04:32 V34842ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/29/23 04:32 V34842ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/29/23 04:32 V34842ENM 4.26 µg/m3 0.130 2.81Trichlorofluoromethane 1 06/29/23 04:32 V34842ENM 0.511 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/29/23 04:32 V34842ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/29/23 04:32 V34842ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/29/23 04:32 V34842ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/29/23 04:32 V34842ENM 0.503 J µg/m3 0.157 2.17 o-Xylene 1 06/29/23 04:32 V34842ENM 2.13 J µg/m3 0.217 5.65m,p-Xylene 1 06/29/23 04:32 V34842ENM 2.63 J µg/m3 0.157 2.17Xylene (Total)1 06/29/23 04:32 V34842 Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%06/29/23 04:321 ENM V34842 Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%06/28/23 02:4520 ENM V34855 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 44 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-1 99277 Matrix: 6/22/2023 9:20 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34863 06/30/23 09:00 V34907 06/29/23 09:00 46.5 µg/m3 0.202 4.75Acetone 1 06/30/23 14:29 V34864ENM 3.56 µg/m3 0.073 1.60Benzene 1 06/30/23 14:29 V34864ENM <0.147 µg/m3 0.147 10.4Benzyl Chloride 1 06/30/23 14:29 V34864ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/30/23 14:29 V34864ENM <0.153 µg/m3 0.153 5.17Bromoform 1 06/30/23 14:29 V34864ENM <0.115 µg/m3 0.115 1.94Bromomethane 1 06/30/23 14:29 V34864ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 06/30/23 14:29 V34864ENM 2.54 J µg/m3 0.060 6.23Carbon Disulfide 1 06/30/23 14:29 V34864ENM <0.155 µg/m3 0.155 3.15 Carbon Tetrachloride 1 06/30/23 14:29 V34864ENM <0.107 µg/m3 0.107 2.30Chlorobenzene 1 06/30/23 14:29 V34864ENM <0.208 µg/m3 0.208 4.26Chlorodibromomethane 1 06/30/23 14:29 V34864ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 06/30/23 14:29 V34864ENM 51.3 µg/m3 0.086 2.44Chloroform 1 06/30/23 14:29 V34864ENM <0.067 µg/m3 0.067 1.03Chloromethane 1 06/30/23 14:29 V34864ENM 3.19 J µg/m3 0.161 3.44Cyclohexane 1 06/30/23 14:29 V34864ENM <0.151 µg/m3 0.151 3.84 1,2-Dibromoethane 1 06/30/23 14:29 V34864ENM <0.096 µg/m3 0.096 3.011,2-Dichlorobenzene 1 06/30/23 14:29 V34864ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 06/30/23 14:29 V34864ENM 1.02 J µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/30/23 14:29 V34864ENM <0.134 µg/m3 0.134 2.47Dichlorodifluoromethane 1 06/30/23 14:29 V34864ENM <0.101 µg/m3 0.101 2.021,1-Dichloroethane 1 06/30/23 14:29 V34864ENM <0.129 µg/m3 0.129 2.021,2-Dichloroethane 1 06/30/23 14:29 V34864ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 45 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-1 99277 Matrix: 6/22/2023 9:20 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34863 06/30/23 09:00 V34907 06/29/23 09:00 <0.107 µg/m3 0.107 1.981,1-Dichloroethene 1 06/30/23 14:29 V34864ENM 4.47 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/30/23 14:29 V34864ENM <0.108 µg/m3 0.108 1.98trans-1,2-Dichloroethene 1 06/30/23 14:29 V34864ENM 2.45 µg/m3 0.205 2.311,2-Dichloropropane 1 06/30/23 14:29 V34864ENM 58.5 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/30/23 14:29 V34864ENM <0.178 µg/m3 0.178 2.27cis-1,3-Dichloropropene 1 06/30/23 14:29 V34864ENM <0.178 µg/m3 0.178 2.27trans-1,3-Dichloropropene 1 06/30/23 14:29 V34864ENM <0.435 µg/m3 0.435 1.801,4-Dioxane 1 06/30/23 14:29 V34864ENM <0.136 µg/m3 0.136 1.80 Ethyl Acetate 1 06/30/23 14:29 V34864ENM 24.7 µg/m3 0.106 2.17Ethylbenzene 1 06/30/23 14:29 V34864ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/30/23 14:29 V34864ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 06/30/23 14:29 V34864ENM 0.848 J µg/m3 0.143 2.05Heptane 1 06/30/23 14:29 V34864ENM <0.330 µg/m3 0.330 5.33Hexachlorobutadiene 1 06/30/23 14:29 V34864ENM 2.07 µg/m3 0.047 1.76n-Hexane 1 06/30/23 14:29 V34864ENM <0.285 µg/m3 0.285 2.05 2-Hexanone 1 06/30/23 14:29 V34864ENM 289 µg/m3 2.78 98.3Isopropyl Alcohol 20 06/29/23 23:33 V34909ENM 1.76 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/30/23 14:29 V34864ENM 0.407 J µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/30/23 14:29 V34864ENM 0.356 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/30/23 14:29 V34864ENM 3.84 µg/m3 0.488 1.74Methylene Chloride 1 06/30/23 14:29 V34864ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/30/23 14:29 V34864ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 46 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:SS-MP-1 99277 Matrix: 6/22/2023 9:20 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V34863 06/30/23 09:00 V34907 06/29/23 09:00 <0.242 µg/m3 0.242 0.860Propene 1 06/30/23 14:29 V34864ENM 4.60 µg/m3 0.124 2.13Styrene 1 06/30/23 14:29 V34864ENM <0.104 µg/m3 0.104 3.431,1,2,2-Tetrachloroethane 1 06/30/23 14:29 V34864ENM 3.14 JB µg/m3 0.181 3.39Tetrachloroethene 1 06/30/23 14:29 V34864ENM 22.2 µg/m3 0.107 1.47Tetrahydrofuran 1 06/30/23 14:29 V34864ENM 15.1 µg/m3 0.090 1.88Toluene 1 06/30/23 14:29 V34864ENM <0.209 µg/m3 0.209 3.711,2,4-Trichlorobenzene 1 06/30/23 14:29 V34864ENM <0.144 µg/m3 0.144 2.731,1,1-Trichloroethane 1 06/30/23 14:29 V34864ENM <0.087 µg/m3 0.087 2.73 1,1,2-Trichloroethane 1 06/30/23 14:29 V34864ENM 0.999 J µg/m3 0.199 2.15Trichloroethene 1 06/30/23 14:29 V34864ENM 20.2 µg/m3 0.130 2.81Trichlorofluoromethane 1 06/30/23 14:29 V34864ENM 1.27 J µg/m3 0.110 2.461,2,4-Trimethylbenzene 1 06/30/23 14:29 V34864ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/30/23 14:29 V34864ENM <0.224 µg/m3 0.224 1.76Vinyl Acetate 1 06/30/23 14:29 V34864ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 06/30/23 14:29 V34864ENM 9.09 µg/m3 0.157 2.17 o-Xylene 1 06/30/23 14:29 V34864ENM 33.2 µg/m3 0.217 5.65m,p-Xylene 1 06/30/23 14:29 V34864ENM 42.3 µg/m3 0.157 2.17Xylene (Total)1 06/30/23 14:29 V34864 Surrogate: 4-Bromofluorobenzene 92.5 Limits: 70-130%06/30/23 14:291 ENM V34864 Surrogate: 4-Bromofluorobenzene 94.7 Limits: 70-130%06/29/23 23:3320 ENM V34909 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 47 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-3 99278 Matrix: 6/21/2023 8:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35063 06/29/23 09:00 V35191 07/11/23 09:00 387 µg/m3 4.04 95.0Acetone 20 07/11/23 11:24 V35195ENM 0.721 J µg/m3 0.073 1.60Benzene 1 06/30/23 00:22 V35067ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 06/30/23 00:22 V35067ENM 1.18 J µg/m3 0.060 6.23Carbon Disulfide 1 06/30/23 00:22 V35067ENM 0.786 J µg/m3 0.086 2.44Chloroform 1 06/30/23 00:22 V35067ENM 1.08 µg/m3 0.067 1.03Chloromethane 1 06/30/23 00:22 V35067ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 06/30/23 00:22 V35067ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 06/30/23 00:22 V35067ENM 2.43 J µg/m3 0.134 2.47 Dichlorodifluoromethane 1 06/30/23 00:22 V35067ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 06/30/23 00:22 V35067ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 06/30/23 00:22 V35524ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 06/30/23 00:22 V35067ENM 2.55 µg/m3 0.136 1.80Ethyl Acetate 1 06/30/23 00:22 V35067ENM 3.07 µg/m3 0.106 2.17Ethylbenzene 1 06/30/23 00:22 V35067ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 06/30/23 00:22 V35067ENM 5.45 µg/m3 0.143 2.05 Heptane 1 06/30/23 00:22 V35067ENM 1.85 µg/m3 0.047 1.76n-Hexane 1 06/30/23 00:22 V35067ENM 5.28 µg/m3 0.285 2.052-Hexanone 1 06/30/23 00:22 V35067ENM 134 µg/m3 2.78 98.3Isopropyl Alcohol 20 07/11/23 11:24 V35195ENM 41.1 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 06/30/23 00:22 V35067ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 06/30/23 00:22 V35067ENM 1.17 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 06/30/23 00:22 V35067ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 48 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-3 99278 Matrix: 6/21/2023 8:23 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35063 06/29/23 09:00 V35191 07/11/23 09:00 <0.488 µg/m3 0.488 1.74Methylene Chloride 1 06/30/23 00:22 V35067ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 06/30/23 00:22 V35067ENM 7.19 µg/m3 0.124 2.13Styrene 1 06/30/23 00:22 V35067ENM 0.922 J µg/m3 0.181 3.39Tetrachloroethene 1 06/30/23 00:22 V35067ENM 20.6 µg/m3 0.107 1.47Tetrahydrofuran 1 06/30/23 00:22 V35067ENM 57.3 µg/m3 0.090 1.88Toluene 1 06/30/23 00:22 V35524ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 06/30/23 00:22 V35067ENM 1.54 J µg/m3 0.130 2.81Trichlorofluoromethane 1 06/30/23 00:22 V35067ENM 3.80 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 06/30/23 00:22 V35067ENM 0.924 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 06/30/23 00:22 V35067ENM 3.92 µg/m3 0.157 2.17o-Xylene 1 06/30/23 00:22 V35067ENM 13.2 µg/m3 0.217 5.65m,p-Xylene 1 06/30/23 00:22 V35067ENM 17.1 µg/m3 0.157 2.17Xylene (Total)1 06/30/23 00:22 V35067 Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%06/30/23 00:221 ENM V35067 Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%06/30/23 00:221 ENM V35524 Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%07/11/23 11:2420 ENM V35195 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 49 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-DUP 99279 Matrix: 6/21/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 V35230 07/11/23 09:00 360 µg/m3 4.04 95.0Acetone 20 07/11/23 12:00 V35233ENM 0.690 JB µg/m3 0.073 1.60Benzene 1 07/06/23 22:28 V35062ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 07/06/23 22:28 V35062ENM 0.688 JB µg/m3 0.060 6.23Carbon Disulfide 1 07/06/23 22:28 V35062ENM 0.800 J µg/m3 0.086 2.44Chloroform 1 07/06/23 22:28 V35062ENM 1.14 µg/m3 0.067 1.03Chloromethane 1 07/06/23 22:28 V35062ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 07/06/23 22:28 V35062ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 07/06/23 22:28 V35062ENM 2.59 µg/m3 0.134 2.47 Dichlorodifluoromethane 1 07/06/23 22:28 V35062ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 07/06/23 22:28 V35062ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 07/06/23 22:28 V35523ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 07/06/23 22:28 V35062ENM 3.09 µg/m3 0.136 1.80Ethyl Acetate 1 07/06/23 22:28 V35062ENM 3.23 µg/m3 0.106 2.17Ethylbenzene 1 07/06/23 22:28 V35062ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 07/06/23 22:28 V35062ENM 5.36 µg/m3 0.143 2.05 Heptane 1 07/06/23 22:28 V35062ENM 2.04 µg/m3 0.047 1.76n-Hexane 1 07/06/23 22:28 V35062ENM 5.91 µg/m3 0.285 2.052-Hexanone 1 07/06/23 22:28 V35062ENM 122 µg/m3 2.78 98.3Isopropyl Alcohol 20 07/11/23 12:00 V35233ENM 43.9 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 07/06/23 22:28 V35062ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 07/06/23 22:28 V35062ENM 1.16 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 07/06/23 22:28 V35062ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 50 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-DUP 99279 Matrix: 6/21/2023 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 V35230 07/11/23 09:00 <0.488 µg/m3 0.488 1.74Methylene Chloride 1 07/06/23 22:28 V35062ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 07/06/23 22:28 V35062ENM 7.37 µg/m3 0.124 2.13Styrene 1 07/06/23 22:28 V35062ENM 0.732 J µg/m3 0.181 3.39Tetrachloroethene 1 07/06/23 22:28 V35062ENM 21.7 µg/m3 0.107 1.47Tetrahydrofuran 1 07/06/23 22:28 V35062ENM 57.1 µg/m3 0.090 1.88Toluene 1 07/06/23 22:28 V35523ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 07/06/23 22:28 V35062ENM 1.57 J µg/m3 0.130 2.81Trichlorofluoromethane 1 07/06/23 22:28 V35062ENM 5.05 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 07/06/23 22:28 V35062ENM 0.933 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 07/06/23 22:28 V35062ENM 4.07 µg/m3 0.157 2.17o-Xylene 1 07/06/23 22:28 V35062ENM 13.7 µg/m3 0.217 5.65m,p-Xylene 1 07/06/23 22:28 V35062ENM 17.8 µg/m3 0.157 2.17Xylene (Total)1 07/06/23 22:28 V35062 Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%07/06/23 22:281 ENM V35062 Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%07/06/23 22:281 ENM V35523 Surrogate: 4-Bromofluorobenzene 94.1 Limits: 70-130%07/11/23 12:0020 ENM V35233 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 51 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-1 99280 Matrix: 6/21/2023 8:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 V35230 07/11/23 09:00 458 µg/m3 4.04 95.0Acetone 20 07/11/23 12:36 V35233ENM 0.836 JB µg/m3 0.073 1.60Benzene 1 07/06/23 23:19 V35062ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 07/06/23 23:19 V35062ENM 0.909 JB µg/m3 0.060 6.23Carbon Disulfide 1 07/06/23 23:19 V35062ENM <0.086 µg/m3 0.086 2.44Chloroform 1 07/06/23 23:19 V35062ENM 0.999 J µg/m3 0.067 1.03Chloromethane 1 07/06/23 23:19 V35062ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 07/06/23 23:19 V35062ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 07/06/23 23:19 V35062ENM 2.65 µg/m3 0.134 2.47 Dichlorodifluoromethane 1 07/06/23 23:19 V35062ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 07/06/23 23:19 V35062ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 07/06/23 23:19 V35523ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 07/06/23 23:19 V35062ENM 1.20 J µg/m3 0.136 1.80Ethyl Acetate 1 07/06/23 23:19 V35062ENM 2.26 µg/m3 0.106 2.17Ethylbenzene 1 07/06/23 23:19 V35062ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 07/06/23 23:19 V35062ENM 7.48 µg/m3 0.143 2.05 Heptane 1 07/06/23 23:19 V35062ENM 2.65 µg/m3 0.047 1.76n-Hexane 1 07/06/23 23:19 V35062ENM 5.79 µg/m3 0.285 2.052-Hexanone 1 07/06/23 23:19 V35062ENM 56.5 µg/m3 0.139 4.92Isopropyl Alcohol 1 07/06/23 23:19 V35062ENM 30.0 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 07/06/23 23:19 V35062ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 07/06/23 23:19 V35062ENM 1.32 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 07/06/23 23:19 V35062ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 52 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-1 99280 Matrix: 6/21/2023 8:24 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 V35230 07/11/23 09:00 <0.488 µg/m3 0.488 1.74Methylene Chloride 1 07/06/23 23:19 V35062ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 07/06/23 23:19 V35062ENM 9.77 µg/m3 0.124 2.13Styrene 1 07/06/23 23:19 V35062ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 07/06/23 23:19 V35062ENM 17.3 µg/m3 0.107 1.47Tetrahydrofuran 1 07/06/23 23:19 V35062ENM 57.0 µg/m3 0.090 1.88Toluene 1 07/06/23 23:19 V35523ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 07/06/23 23:19 V35062ENM 1.73 J µg/m3 0.130 2.81Trichlorofluoromethane 1 07/06/23 23:19 V35062ENM 4.42 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 07/06/23 23:19 V35062ENM 0.904 J µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 07/06/23 23:19 V35062ENM 2.58 µg/m3 0.157 2.17o-Xylene 1 07/06/23 23:19 V35062ENM 8.34 µg/m3 0.217 5.65m,p-Xylene 1 07/06/23 23:19 V35062ENM 10.9 µg/m3 0.157 2.17Xylene (Total)1 07/06/23 23:19 V35062 Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%07/06/23 23:191 ENM V35062 Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%07/06/23 23:191 ENM V35523 Surrogate: 4-Bromofluorobenzene 94.1 Limits: 70-130%07/11/23 12:3620 ENM V35233 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 53 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-BKG 99281 Matrix: 6/21/2023 8:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 21.3 µg/m3 0.202 4.75Acetone 1 07/07/23 00:07 V35062ENM 0.485 JB µg/m3 0.073 1.60Benzene 1 07/07/23 00:07 V35062ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 07/07/23 00:07 V35062ENM 0.295 JB µg/m3 0.060 6.23Carbon Disulfide 1 07/07/23 00:07 V35062ENM <0.086 µg/m3 0.086 2.44Chloroform 1 07/07/23 00:07 V35062ENM 0.850 J µg/m3 0.067 1.03Chloromethane 1 07/07/23 00:07 V35062ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 07/07/23 00:07 V35062ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 07/07/23 00:07 V35062ENM 2.59 µg/m3 0.134 2.47 Dichlorodifluoromethane 1 07/07/23 00:07 V35062ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 07/07/23 00:07 V35062ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 07/07/23 00:07 V35523ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 07/07/23 00:07 V35062ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 07/07/23 00:07 V35062ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 07/07/23 00:07 V35062ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 07/07/23 00:07 V35062ENM <0.143 µg/m3 0.143 2.05 Heptane 1 07/07/23 00:07 V35062ENM <0.047 µg/m3 0.047 1.76n-Hexane 1 07/07/23 00:07 V35062ENM <0.285 µg/m3 0.285 2.052-Hexanone 1 07/07/23 00:07 V35062ENM 2.09 J µg/m3 0.139 4.92Isopropyl Alcohol 1 07/07/23 00:07 V35062ENM 2.08 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 07/07/23 00:07 V35062ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 07/07/23 00:07 V35062ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 07/07/23 00:07 V35062ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 54 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-BKG 99281 Matrix: 6/21/2023 8:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 <0.488 µg/m3 0.488 1.74Methylene Chloride 1 07/07/23 00:07 V35062ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 07/07/23 00:07 V35062ENM <0.124 µg/m3 0.124 2.13Styrene 1 07/07/23 00:07 V35062ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 07/07/23 00:07 V35062ENM <0.107 µg/m3 0.107 1.47Tetrahydrofuran 1 07/07/23 00:07 V35062ENM 1.02 JB µg/m3 0.090 1.88Toluene 1 07/07/23 00:07 V35523ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 07/07/23 00:07 V35062ENM 1.52 J µg/m3 0.130 2.81Trichlorofluoromethane 1 07/07/23 00:07 V35062ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 07/07/23 00:07 V35062ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 07/07/23 00:07 V35062ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 07/07/23 00:07 V35062ENM <0.217 µg/m3 0.217 5.65m,p-Xylene 1 07/07/23 00:07 V35062ENM <0.157 µg/m3 0.157 2.17Xylene (Total)1 07/07/23 00:07 V35062 Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%07/07/23 00:071 ENM V35062 Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%07/07/23 00:071 ENM V35523 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 55 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-2 99282 Matrix: 6/21/2023 8:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 39.2 µg/m3 0.202 4.75Acetone 1 07/07/23 00:54 V35062ENM 0.559 JB µg/m3 0.073 1.60Benzene 1 07/07/23 00:54 V35062ENM <0.150 µg/m3 0.150 3.35Bromodichloromethane 1 07/07/23 00:54 V35062ENM <0.060 µg/m3 0.060 6.23Carbon Disulfide 1 07/07/23 00:54 V35062ENM 0.854 J µg/m3 0.086 2.44Chloroform 1 07/07/23 00:54 V35062ENM 0.976 J µg/m3 0.067 1.03Chloromethane 1 07/07/23 00:54 V35062ENM <0.161 µg/m3 0.161 3.44Cyclohexane 1 07/07/23 00:54 V35062ENM <0.186 µg/m3 0.186 3.011,4-Dichlorobenzene 1 07/07/23 00:54 V35062ENM 18.1 µg/m3 0.134 2.47 Dichlorodifluoromethane 1 07/07/23 00:54 V35062ENM <0.095 µg/m3 0.095 1.98cis-1,2-Dichloroethene 1 07/07/23 00:54 V35062ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 07/07/23 00:54 V35523ENM <0.622 µg/m3 0.622 3.501,2-Dichlorotetrafluoroethane 1 07/07/23 00:54 V35062ENM 0.428 J µg/m3 0.136 1.80Ethyl Acetate 1 07/07/23 00:54 V35062ENM 0.369 J µg/m3 0.106 2.17Ethylbenzene 1 07/07/23 00:54 V35062ENM <0.128 µg/m3 0.128 2.464-Ethyltoluene 1 07/07/23 00:54 V35062ENM 0.762 J µg/m3 0.143 2.05 Heptane 1 07/07/23 00:54 V35062ENM 0.764 J µg/m3 0.047 1.76n-Hexane 1 07/07/23 00:54 V35062ENM 0.389 J µg/m3 0.285 2.052-Hexanone 1 07/07/23 00:54 V35062ENM 6.94 µg/m3 0.139 4.92Isopropyl Alcohol 1 07/07/23 00:54 V35062ENM 3.81 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 07/07/23 00:54 V35062ENM <0.033 µg/m3 0.033 1.80Methyl tert-butyl ether (MTBE)1 07/07/23 00:54 V35062ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 07/07/23 00:54 V35062ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 56 of 100 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 23-177-0008 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Shannon Switch Charlotte Received : 06/26/2023 LEN-008 Revised Report Date: 07/20/2023 Original Report Date : 07/19/2023 Sample ID : Lab No : Sampled:IAS-2 99282 Matrix: 6/21/2023 8:25 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V35057 07/06/23 09:00 0.562 J µg/m3 0.488 1.74Methylene Chloride 1 07/07/23 00:54 V35062ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 07/07/23 00:54 V35062ENM 0.672 J µg/m3 0.124 2.13Styrene 1 07/07/23 00:54 V35062ENM <0.181 µg/m3 0.181 3.39Tetrachloroethene 1 07/07/23 00:54 V35062ENM 0.693 J µg/m3 0.107 1.47Tetrahydrofuran 1 07/07/23 00:54 V35062ENM 4.17 B µg/m3 0.090 1.88Toluene 1 07/07/23 00:54 V35523ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 07/07/23 00:54 V35062ENM 35.4 µg/m3 0.130 2.81Trichlorofluoromethane 1 07/07/23 00:54 V35062ENM 2.40 J µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 07/07/23 00:54 V35062ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 07/07/23 00:54 V35062ENM 0.377 J µg/m3 0.157 2.17o-Xylene 1 07/07/23 00:54 V35062ENM 1.92 J µg/m3 0.217 5.65m,p-Xylene 1 07/07/23 00:54 V35062ENM 2.30 J µg/m3 0.157 2.17Xylene (Total)1 07/07/23 00:54 V35062 Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%07/07/23 00:541 ENM V35062 Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%07/07/23 00:541 ENM V35523 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 57 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34774QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34773 Associated Lab Samples: 99269 LRB-V34773 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/27/23 11:101.600.073<0.073µg/m3Benzene 06/27/23 11:1010.40.147<0.147µg/m3Benzyl Chloride 06/27/23 11:103.350.150<0.150µg/m3Bromodichloromethane 06/27/23 11:105.170.153<0.153µg/m3Bromoform 06/27/23 11:101.940.115<0.115µg/m3Bromomethane 06/27/23 11:101.110.328<0.328µg/m31,3-Butadiene 06/27/23 11:106.230.060<0.060µg/m3Carbon Disulfide 06/27/23 11:103.150.155<0.155µg/m3Carbon Tetrachloride 06/27/23 11:102.300.107<0.107µg/m3Chlorobenzene 06/27/23 11:104.260.208<0.208µg/m3Chlorodibromomethane 06/27/23 11:101.320.164<0.164µg/m3Chloroethane 06/27/23 11:102.440.086<0.086µg/m3Chloroform 06/27/23 11:101.030.067<0.067µg/m3Chloromethane 06/27/23 11:103.440.161<0.161µg/m3Cyclohexane 06/27/23 11:103.840.151<0.151µg/m31,2-Dibromoethane 06/27/23 11:103.010.096<0.096µg/m31,2-Dichlorobenzene 06/27/23 11:1012.00.174<0.174µg/m31,3-Dichlorobenzene 06/27/23 11:103.010.186<0.186µg/m31,4-Dichlorobenzene 06/27/23 11:102.470.134<0.134µg/m3Dichlorodifluoromethane 06/27/23 11:102.020.101<0.101µg/m31,1-Dichloroethane 06/27/23 11:102.020.129<0.129µg/m31,2-Dichloroethane 06/27/23 11:101.980.107<0.107µg/m31,1-Dichloroethene 06/27/23 11:101.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/27/23 11:101.980.108<0.108µg/m3trans-1,2-Dichloroethene 06/27/23 11:102.310.205<0.205µg/m31,2-Dichloropropane 06/27/23 11:103.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane 06/27/23 11:102.270.178<0.178µg/m3cis-1,3-Dichloropropene Page 1 of 36Date:07/20/2023 10:03 AM Page 58 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34774QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34773 Associated Lab Samples: 99269 LRB-V34773 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/27/23 11:102.270.178<0.178µg/m3trans-1,3-Dichloropropene 06/27/23 11:101.800.435<0.435µg/m31,4-Dioxane 06/27/23 11:101.800.136<0.136µg/m3Ethyl Acetate 06/27/23 11:102.170.106<0.106µg/m3Ethylbenzene 06/27/23 11:102.460.128<0.128µg/m34-Ethyltoluene 06/27/23 11:103.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 06/27/23 11:102.050.143<0.143µg/m3Heptane 06/27/23 11:105.330.330<0.330µg/m3Hexachlorobutadiene 06/27/23 11:101.760.047<0.047µg/m3n-Hexane 06/27/23 11:102.050.285<0.285µg/m32-Hexanone 06/27/23 11:104.920.139<0.139µg/m3Isopropyl Alcohol 06/27/23 11:101.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/27/23 11:101.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/27/23 11:102.050.121<0.121µg/m34-Methyl-2-Pentanone 06/27/23 11:101.740.488<0.488µg/m3Methylene Chloride 06/27/23 11:102.620.183<0.183µg/m3Naphthalene 06/27/23 11:100.8600.242<0.242µg/m3Propene 06/27/23 11:102.130.124<0.124µg/m3Styrene 06/27/23 11:103.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 06/27/23 11:103.390.181<0.181µg/m3Tetrachloroethene 06/27/23 11:101.880.0900.335µg/m3Toluene 06/27/23 11:103.710.209<0.209µg/m31,2,4-Trichlorobenzene 06/27/23 11:102.730.144<0.144µg/m31,1,1-Trichloroethane 06/27/23 11:102.730.087<0.087µg/m31,1,2-Trichloroethane 06/27/23 11:102.150.199<0.199µg/m3Trichloroethene 06/27/23 11:102.810.130<0.130µg/m3Trichlorofluoromethane 06/27/23 11:102.460.110<0.110µg/m31,2,4-Trimethylbenzene Page 2 of 36Date:07/20/2023 10:03 AM Page 59 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34774QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34773 Associated Lab Samples: 99269 LRB-V34773 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/27/23 11:102.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/27/23 11:101.760.224<0.224µg/m3Vinyl Acetate 06/27/23 11:101.280.127<0.127µg/m3Vinyl Chloride 06/27/23 11:102.170.157<0.157µg/m3o-Xylene 06/27/23 11:105.650.217<0.217µg/m3m,p-Xylene 06/27/23 11:104-Bromofluorobenzene (S)93.2 70-130 LCS-V34773Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 97.515.616.0µg/m3Benzene 70-130 10727.825.9µg/m3Benzyl Chloride 70-130 97.932.833.5µg/m3Bromodichloromethane 70-130 97.450.451.7µg/m3Bromoform 70-130 10520.419.4µg/m3Bromomethane 70-130 97.210.811.1µg/m31,3-Butadiene 70-130 10316.015.6µg/m3Carbon Disulfide 70-130 97.730.831.5µg/m3Carbon Tetrachloride 70-130 10123.223.0µg/m3Chlorobenzene 70-130 98.842.142.6µg/m3Chlorodibromomethane 70-130 10113.313.2µg/m3Chloroethane 70-130 98.724.124.4µg/m3Chloroform 70-130 10010.310.3µg/m3Chloromethane 70-130 10017.217.2µg/m3Cyclohexane 70-130 10038.438.4µg/m31,2-Dibromoethane 70-130 10932.830.1µg/m31,2-Dichlorobenzene 70-130 10531.730.1µg/m31,3-Dichlorobenzene 70-130 Page 3 of 36Date:07/20/2023 10:03 AM Page 60 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34774QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34773 LCS-V34773Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10832.430.1µg/m31,4-Dichlorobenzene 70-130 10325.524.7µg/m3Dichlorodifluoromethane 70-130 10020.320.2µg/m31,1-Dichloroethane 70-130 98.519.920.2µg/m31,2-Dichloroethane 70-130 10520.719.8µg/m31,1-Dichloroethene 70-130 10120.019.8µg/m3cis-1,2-Dichloroethene 70-130 10320.419.8µg/m3trans-1,2-Dichloroethene 70-130 96.122.223.1µg/m31,2-Dichloropropane 70-130 10235.635.0µg/m31,2-Dichlorotetrafluoroethane 70-130 97.722.222.7µg/m3cis-1,3-Dichloropropene 70-130 97.722.222.7µg/m3trans-1,3-Dichloropropene 70-130 96.617.418.0µg/m31,4-Dioxane 70-130 98.317.718.0µg/m3Ethyl Acetate 70-130 99.521.621.7µg/m3Ethylbenzene 70-130 10225.124.6µg/m34-Ethyltoluene 70-130 10138.738.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 97.019.920.5µg/m3Heptane 70-130 98.152.353.3µg/m3Hexachlorobutadiene 70-130 10117.717.6µg/m3n-Hexane 70-130 97.520.020.5µg/m32-Hexanone 70-130 10212.512.3µg/m3Isopropyl Alcohol 70-130 99.314.714.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10118.118.0µg/m3Methyl tert-butyl ether (MTBE)70-130 97.019.920.5µg/m34-Methyl-2-Pentanone 70-130 10217.817.4µg/m3Methylene Chloride 70-130 10126.426.2µg/m3Naphthalene 70-130 97.98.438.61µg/m3Propene 70-130 Page 4 of 36Date:07/20/2023 10:03 AM Page 61 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34774QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34773 LCS-V34773Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 98.521.021.3µg/m3Styrene 70-130 99.734.234.3µg/m31,1,2,2-Tetrachloroethane 70-130 96.132.633.9µg/m3Tetrachloroethene 70-130 96.218.118.8µg/m3Toluene 70-130 10137.337.1µg/m31,2,4-Trichlorobenzene 70-130 98.927.027.3µg/m31,1,1-Trichloroethane 70-130 10127.727.3µg/m31,1,2-Trichloroethane 70-130 98.826.626.9µg/m3Trichloroethene 70-130 10529.428.1µg/m3Trichlorofluoromethane 70-130 10726.224.6µg/m31,2,4-Trimethylbenzene 70-130 10325.324.6µg/m31,3,5-Trimethylbenzene 70-130 10117.717.6µg/m3Vinyl Acetate 70-130 10112.912.8µg/m3Vinyl Chloride 70-130 98.621.421.7µg/m3o-Xylene 70-130 92.340.143.4µg/m3m,p-Xylene 70-130 97.74-Bromofluorobenzene (S)70-130 Page 5 of 36Date:07/20/2023 10:03 AM Page 62 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34795QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34794 Associated Lab Samples: 99267, 99268, 99269, 99270, 99271, 99272, 99273 LRB-V34794 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:294.750.202<0.202µg/m3Acetone 06/28/23 11:291.600.073<0.073µg/m3Benzene 06/28/23 11:2910.40.147<0.147µg/m3Benzyl Chloride 06/28/23 11:293.350.150<0.150µg/m3Bromodichloromethane 06/28/23 11:295.170.153<0.153µg/m3Bromoform 06/28/23 11:291.940.115<0.115µg/m3Bromomethane 06/28/23 11:291.110.328<0.328µg/m31,3-Butadiene 06/28/23 11:296.230.060<0.060µg/m3Carbon Disulfide 06/28/23 11:293.150.155<0.155µg/m3Carbon Tetrachloride 06/28/23 11:292.300.107<0.107µg/m3Chlorobenzene 06/28/23 11:294.260.208<0.208µg/m3Chlorodibromomethane 06/28/23 11:291.320.164<0.164µg/m3Chloroethane 06/28/23 11:292.440.086<0.086µg/m3Chloroform 06/28/23 11:291.030.067<0.067µg/m3Chloromethane 06/28/23 11:293.440.161<0.161µg/m3Cyclohexane 06/28/23 11:293.840.151<0.151µg/m31,2-Dibromoethane 06/28/23 11:293.010.096<0.096µg/m31,2-Dichlorobenzene 06/28/23 11:2912.00.174<0.174µg/m31,3-Dichlorobenzene 06/28/23 11:293.010.186<0.186µg/m31,4-Dichlorobenzene 06/28/23 11:292.470.134<0.134µg/m3Dichlorodifluoromethane 06/28/23 11:292.020.101<0.101µg/m31,1-Dichloroethane 06/28/23 11:292.020.129<0.129µg/m31,2-Dichloroethane 06/28/23 11:291.980.107<0.107µg/m31,1-Dichloroethene 06/28/23 11:291.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/28/23 11:291.980.108<0.108µg/m3trans-1,2-Dichloroethene 06/28/23 11:292.310.205<0.205µg/m31,2-Dichloropropane 06/28/23 11:293.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 6 of 36Date:07/20/2023 10:03 AM Page 63 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34795QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34794 Associated Lab Samples: 99267, 99268, 99269, 99270, 99271, 99272, 99273 LRB-V34794 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:292.270.178<0.178µg/m3cis-1,3-Dichloropropene 06/28/23 11:292.270.178<0.178µg/m3trans-1,3-Dichloropropene 06/28/23 11:291.800.435<0.435µg/m31,4-Dioxane 06/28/23 11:291.800.136<0.136µg/m3Ethyl Acetate 06/28/23 11:292.170.106<0.106µg/m3Ethylbenzene 06/28/23 11:292.460.128<0.128µg/m34-Ethyltoluene 06/28/23 11:293.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 06/28/23 11:292.050.143<0.143µg/m3Heptane 06/28/23 11:295.330.330<0.330µg/m3Hexachlorobutadiene 06/28/23 11:291.760.047<0.047µg/m3n-Hexane 06/28/23 11:292.050.285<0.285µg/m32-Hexanone 06/28/23 11:294.920.139<0.139µg/m3Isopropyl Alcohol 06/28/23 11:291.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/28/23 11:291.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/28/23 11:292.050.121<0.121µg/m34-Methyl-2-Pentanone 06/28/23 11:291.740.488<0.488µg/m3Methylene Chloride 06/28/23 11:292.620.183<0.183µg/m3Naphthalene 06/28/23 11:290.8600.242<0.242µg/m3Propene 06/28/23 11:292.130.124<0.124µg/m3Styrene 06/28/23 11:293.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 06/28/23 11:293.390.181<0.181µg/m3Tetrachloroethene 06/28/23 11:291.470.107<0.107µg/m3Tetrahydrofuran 06/28/23 11:291.880.0900.384µg/m3Toluene 06/28/23 11:293.710.209<0.209µg/m31,2,4-Trichlorobenzene 06/28/23 11:292.730.144<0.144µg/m31,1,1-Trichloroethane 06/28/23 11:292.730.087<0.087µg/m31,1,2-Trichloroethane 06/28/23 11:292.150.199<0.199µg/m3Trichloroethene Page 7 of 36Date:07/20/2023 10:03 AM Page 64 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34795QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34794 Associated Lab Samples: 99267, 99268, 99269, 99270, 99271, 99272, 99273 LRB-V34794 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:292.810.130<0.130µg/m3Trichlorofluoromethane 06/28/23 11:292.460.110<0.110µg/m31,2,4-Trimethylbenzene 06/28/23 11:292.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/28/23 11:291.760.224<0.224µg/m3Vinyl Acetate 06/28/23 11:291.280.127<0.127µg/m3Vinyl Chloride 06/28/23 11:292.170.157<0.157µg/m3o-Xylene 06/28/23 11:295.650.217<0.217µg/m3m,p-Xylene 06/28/23 11:294-Bromofluorobenzene (S)96.0 70-130 LCS-V34794Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10212.111.9µg/m3Acetone 70-130 10316.416.0µg/m3Benzene 70-130 11229.025.9µg/m3Benzyl Chloride 70-130 10334.433.5µg/m3Bromodichloromethane 70-130 10353.551.7µg/m3Bromoform 70-130 11021.419.4µg/m3Bromomethane 70-130 10011.111.1µg/m31,3-Butadiene 70-130 10616.515.6µg/m3Carbon Disulfide 70-130 10332.631.5µg/m3Carbon Tetrachloride 70-130 10724.723.0µg/m3Chlorobenzene 70-130 10645.042.6µg/m3Chlorodibromomethane 70-130 10313.613.2µg/m3Chloroethane 70-130 10525.524.4µg/m3Chloroform 70-130 10410.710.3µg/m3Chloromethane 70-130 10417.917.2µg/m3Cyclohexane 70-130 Page 8 of 36Date:07/20/2023 10:03 AM Page 65 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34795QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34794 LCS-V34794Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10640.838.4µg/m31,2-Dibromoethane 70-130 11835.430.1µg/m31,2-Dichlorobenzene 70-130 11233.830.1µg/m31,3-Dichlorobenzene 70-130 11534.530.1µg/m31,4-Dichlorobenzene 70-130 10626.324.7µg/m3Dichlorodifluoromethane 70-130 10421.120.2µg/m31,1-Dichloroethane 70-130 10320.920.2µg/m31,2-Dichloroethane 70-130 10721.219.8µg/m31,1-Dichloroethene 70-130 10320.419.8µg/m3cis-1,2-Dichloroethene 70-130 10620.919.8µg/m3trans-1,2-Dichloroethene 70-130 10123.423.1µg/m31,2-Dichloropropane 70-130 10536.635.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10223.122.7µg/m3cis-1,3-Dichloropropene 70-130 10223.122.7µg/m3trans-1,3-Dichloropropene 70-130 10218.318.0µg/m31,4-Dioxane 70-130 96.617.418.0µg/m3Ethyl Acetate 70-130 10622.921.7µg/m3Ethylbenzene 70-130 10926.724.6µg/m34-Ethyltoluene 70-130 10740.838.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 99.020.320.5µg/m3Heptane 70-130 10857.653.3µg/m3Hexachlorobutadiene 70-130 10318.217.6µg/m3n-Hexane 70-130 10321.120.5µg/m32-Hexanone 70-130 99.112.212.3µg/m3Isopropyl Alcohol 70-130 98.614.614.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10318.518.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10020.520.5µg/m34-Methyl-2-Pentanone 70-130 Page 9 of 36Date:07/20/2023 10:03 AM Page 66 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34795QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34794 LCS-V34794Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10718.617.4µg/m3Methylene Chloride 70-130 10728.126.2µg/m3Naphthalene 70-130 97.08.368.61µg/m3Propene 70-130 10622.521.3µg/m3Styrene 70-130 10736.834.3µg/m31,1,2,2-Tetrachloroethane 70-130 10234.733.9µg/m3Tetrachloroethene 70-130 98.614.514.7µg/m3Tetrahydrofuran 70-130 10118.918.8µg/m3Toluene 70-130 10840.237.1µg/m31,2,4-Trichlorobenzene 70-130 10328.227.3µg/m31,1,1-Trichloroethane 70-130 10729.327.3µg/m31,1,2-Trichloroethane 70-130 10327.826.9µg/m3Trichloroethene 70-130 10930.728.1µg/m3Trichlorofluoromethane 70-130 11327.824.6µg/m31,2,4-Trimethylbenzene 70-130 11127.224.6µg/m31,3,5-Trimethylbenzene 70-130 10318.217.6µg/m3Vinyl Acetate 70-130 10413.312.8µg/m3Vinyl Chloride 70-130 10622.921.7µg/m3o-Xylene 70-130 98.642.843.4µg/m3m,p-Xylene 70-130 1004-Bromofluorobenzene (S)70-130 Page 10 of 36Date:07/20/2023 10:03 AM Page 67 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34837QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34836 Associated Lab Samples: 99274, 99275 LRB-V34836 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:054.750.202<0.202µg/m3Acetone 06/29/23 11:051.600.073<0.073µg/m3Benzene 06/29/23 11:0510.40.147<0.147µg/m3Benzyl Chloride 06/29/23 11:053.350.150<0.150µg/m3Bromodichloromethane 06/29/23 11:055.170.153<0.153µg/m3Bromoform 06/29/23 11:051.940.115<0.115µg/m3Bromomethane 06/29/23 11:051.110.328<0.328µg/m31,3-Butadiene 06/29/23 11:056.230.060<0.060µg/m3Carbon Disulfide 06/29/23 11:053.150.155<0.155µg/m3Carbon Tetrachloride 06/29/23 11:052.300.107<0.107µg/m3Chlorobenzene 06/29/23 11:054.260.208<0.208µg/m3Chlorodibromomethane 06/29/23 11:051.320.164<0.164µg/m3Chloroethane 06/29/23 11:052.440.086<0.086µg/m3Chloroform 06/29/23 11:051.030.067<0.067µg/m3Chloromethane 06/29/23 11:053.440.161<0.161µg/m3Cyclohexane 06/29/23 11:053.840.151<0.151µg/m31,2-Dibromoethane 06/29/23 11:053.010.096<0.096µg/m31,2-Dichlorobenzene 06/29/23 11:0512.00.174<0.174µg/m31,3-Dichlorobenzene 06/29/23 11:053.010.186<0.186µg/m31,4-Dichlorobenzene 06/29/23 11:052.470.134<0.134µg/m3Dichlorodifluoromethane 06/29/23 11:052.020.101<0.101µg/m31,1-Dichloroethane 06/29/23 11:052.020.129<0.129µg/m31,2-Dichloroethane 06/29/23 11:051.980.107<0.107µg/m31,1-Dichloroethene 06/29/23 11:051.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/29/23 11:051.980.108<0.108µg/m3trans-1,2-Dichloroethene 06/29/23 11:052.310.205<0.205µg/m31,2-Dichloropropane 06/29/23 11:053.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 11 of 36Date:07/20/2023 10:03 AM Page 68 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34837QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34836 Associated Lab Samples: 99274, 99275 LRB-V34836 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:052.270.178<0.178µg/m3cis-1,3-Dichloropropene 06/29/23 11:052.270.178<0.178µg/m3trans-1,3-Dichloropropene 06/29/23 11:051.800.435<0.435µg/m31,4-Dioxane 06/29/23 11:051.800.136<0.136µg/m3Ethyl Acetate 06/29/23 11:052.170.106<0.106µg/m3Ethylbenzene 06/29/23 11:052.460.128<0.128µg/m34-Ethyltoluene 06/29/23 11:053.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 06/29/23 11:052.050.143<0.143µg/m3Heptane 06/29/23 11:055.330.330<0.330µg/m3Hexachlorobutadiene 06/29/23 11:051.760.047<0.047µg/m3n-Hexane 06/29/23 11:052.050.285<0.285µg/m32-Hexanone 06/29/23 11:054.920.139<0.139µg/m3Isopropyl Alcohol 06/29/23 11:051.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/29/23 11:052.050.121<0.121µg/m34-Methyl-2-Pentanone 06/29/23 11:051.740.488<0.488µg/m3Methylene Chloride 06/29/23 11:052.620.183<0.183µg/m3Naphthalene 06/29/23 11:050.8600.242<0.242µg/m3Propene 06/29/23 11:052.130.124<0.124µg/m3Styrene 06/29/23 11:053.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 06/29/23 11:053.390.181<0.181µg/m3Tetrachloroethene 06/29/23 11:051.880.090<0.090µg/m3Toluene 06/29/23 11:053.710.209<0.209µg/m31,2,4-Trichlorobenzene 06/29/23 11:052.730.144<0.144µg/m31,1,1-Trichloroethane 06/29/23 11:052.730.087<0.087µg/m31,1,2-Trichloroethane 06/29/23 11:052.150.199<0.199µg/m3Trichloroethene 06/29/23 11:052.810.130<0.130µg/m3Trichlorofluoromethane 06/29/23 11:052.460.110<0.110µg/m31,2,4-Trimethylbenzene Page 12 of 36Date:07/20/2023 10:03 AM Page 69 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34837QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34836 Associated Lab Samples: 99274, 99275 LRB-V34836 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:052.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/29/23 11:051.760.224<0.224µg/m3Vinyl Acetate 06/29/23 11:051.280.127<0.127µg/m3Vinyl Chloride 06/29/23 11:052.170.157<0.157µg/m3o-Xylene 06/29/23 11:055.650.217<0.217µg/m3m,p-Xylene 06/29/23 11:054-Bromofluorobenzene (S)98.0 70-130 LCS-V34836Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10812.911.9µg/m3Acetone 70-130 10116.216.0µg/m3Benzene 70-130 11529.925.9µg/m3Benzyl Chloride 70-130 10133.933.5µg/m3Bromodichloromethane 70-130 10252.751.7µg/m3Bromoform 70-130 11321.919.4µg/m3Bromomethane 70-130 10611.811.1µg/m31,3-Butadiene 70-130 10816.815.6µg/m3Carbon Disulfide 70-130 10232.031.5µg/m3Carbon Tetrachloride 70-130 10724.523.0µg/m3Chlorobenzene 70-130 10544.642.6µg/m3Chlorodibromomethane 70-130 10814.313.2µg/m3Chloroethane 70-130 10525.524.4µg/m3Chloroform 70-130 10711.010.3µg/m3Chloromethane 70-130 10618.217.2µg/m3Cyclohexane 70-130 10741.238.4µg/m31,2-Dibromoethane 70-130 11434.330.1µg/m31,2-Dichlorobenzene 70-130 Page 13 of 36Date:07/20/2023 10:03 AM Page 70 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34837QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34836 LCS-V34836Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11133.530.1µg/m31,3-Dichlorobenzene 70-130 11534.630.1µg/m31,4-Dichlorobenzene 70-130 10926.924.7µg/m3Dichlorodifluoromethane 70-130 10821.820.2µg/m31,1-Dichloroethane 70-130 10421.020.2µg/m31,2-Dichloroethane 70-130 11021.819.8µg/m31,1-Dichloroethene 70-130 10921.519.8µg/m3cis-1,2-Dichloroethene 70-130 11121.919.8µg/m3trans-1,2-Dichloroethene 70-130 10323.723.1µg/m31,2-Dichloropropane 70-130 10737.535.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10223.222.7µg/m3cis-1,3-Dichloropropene 70-130 10223.222.7µg/m3trans-1,3-Dichloropropene 70-130 10418.818.0µg/m31,4-Dioxane 70-130 10719.218.0µg/m3Ethyl Acetate 70-130 10723.221.7µg/m3Ethylbenzene 70-130 11027.024.6µg/m34-Ethyltoluene 70-130 10841.538.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 10220.920.5µg/m3Heptane 70-130 10556.253.3µg/m3Hexachlorobutadiene 70-130 11019.317.6µg/m3n-Hexane 70-130 10722.020.5µg/m32-Hexanone 70-130 11113.612.3µg/m3Isopropyl Alcohol 70-130 10719.318.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10421.320.5µg/m34-Methyl-2-Pentanone 70-130 11219.517.4µg/m3Methylene Chloride 70-130 10728.026.2µg/m3Naphthalene 70-130 1069.098.61µg/m3Propene 70-130 Page 14 of 36Date:07/20/2023 10:03 AM Page 71 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34837QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34836 LCS-V34836Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10722.721.3µg/m3Styrene 70-130 10636.334.3µg/m31,1,2,2-Tetrachloroethane 70-130 10134.233.9µg/m3Tetrachloroethene 70-130 10119.018.8µg/m3Toluene 70-130 10739.637.1µg/m31,2,4-Trichlorobenzene 70-130 10328.227.3µg/m31,1,1-Trichloroethane 70-130 10829.527.3µg/m31,1,2-Trichloroethane 70-130 10227.526.9µg/m3Trichloroethene 70-130 11131.128.1µg/m3Trichlorofluoromethane 70-130 11428.024.6µg/m31,2,4-Trimethylbenzene 70-130 11027.124.6µg/m31,3,5-Trimethylbenzene 70-130 10718.917.6µg/m3Vinyl Acetate 70-130 10813.812.8µg/m3Vinyl Chloride 70-130 10522.821.7µg/m3o-Xylene 70-130 98.842.943.4µg/m3m,p-Xylene 70-130 1004-Bromofluorobenzene (S)70-130 Page 15 of 36Date:07/20/2023 10:03 AM Page 72 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34842QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34838 Associated Lab Samples: 99276 LRB-V34838 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:294.750.202<0.202µg/m3Acetone 06/28/23 11:291.600.073<0.073µg/m3Benzene 06/28/23 11:2910.40.147<0.147µg/m3Benzyl Chloride 06/28/23 11:293.350.150<0.150µg/m3Bromodichloromethane 06/28/23 11:295.170.153<0.153µg/m3Bromoform 06/28/23 11:291.940.115<0.115µg/m3Bromomethane 06/28/23 11:291.110.328<0.328µg/m31,3-Butadiene 06/28/23 11:296.230.060<0.060µg/m3Carbon Disulfide 06/28/23 11:293.150.155<0.155µg/m3Carbon Tetrachloride 06/28/23 11:292.300.107<0.107µg/m3Chlorobenzene 06/28/23 11:294.260.208<0.208µg/m3Chlorodibromomethane 06/28/23 11:291.320.164<0.164µg/m3Chloroethane 06/28/23 11:292.440.086<0.086µg/m3Chloroform 06/28/23 11:291.030.067<0.067µg/m3Chloromethane 06/28/23 11:293.440.161<0.161µg/m3Cyclohexane 06/28/23 11:293.840.151<0.151µg/m31,2-Dibromoethane 06/28/23 11:293.010.096<0.096µg/m31,2-Dichlorobenzene 06/28/23 11:2912.00.174<0.174µg/m31,3-Dichlorobenzene 06/28/23 11:293.010.186<0.186µg/m31,4-Dichlorobenzene 06/28/23 11:292.470.134<0.134µg/m3Dichlorodifluoromethane 06/28/23 11:292.020.101<0.101µg/m31,1-Dichloroethane 06/28/23 11:292.020.129<0.129µg/m31,2-Dichloroethane 06/28/23 11:291.980.107<0.107µg/m31,1-Dichloroethene 06/28/23 11:291.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/28/23 11:291.980.108<0.108µg/m3trans-1,2-Dichloroethene 06/28/23 11:292.310.205<0.205µg/m31,2-Dichloropropane 06/28/23 11:293.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 16 of 36Date:07/20/2023 10:03 AM Page 73 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34842QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34838 Associated Lab Samples: 99276 LRB-V34838 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:292.270.178<0.178µg/m3cis-1,3-Dichloropropene 06/28/23 11:292.270.178<0.178µg/m3trans-1,3-Dichloropropene 06/28/23 11:291.800.435<0.435µg/m31,4-Dioxane 06/28/23 11:291.800.136<0.136µg/m3Ethyl Acetate 06/28/23 11:292.170.106<0.106µg/m3Ethylbenzene 06/28/23 11:292.460.128<0.128µg/m34-Ethyltoluene 06/28/23 11:293.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 06/28/23 11:292.050.143<0.143µg/m3Heptane 06/28/23 11:295.330.330<0.330µg/m3Hexachlorobutadiene 06/28/23 11:291.760.047<0.047µg/m3n-Hexane 06/28/23 11:292.050.285<0.285µg/m32-Hexanone 06/28/23 11:294.920.139<0.139µg/m3Isopropyl Alcohol 06/28/23 11:291.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/28/23 11:292.050.121<0.121µg/m34-Methyl-2-Pentanone 06/28/23 11:291.740.488<0.488µg/m3Methylene Chloride 06/28/23 11:292.620.183<0.183µg/m3Naphthalene 06/28/23 11:290.8600.242<0.242µg/m3Propene 06/28/23 11:292.130.124<0.124µg/m3Styrene 06/28/23 11:293.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 06/28/23 11:293.390.181<0.181µg/m3Tetrachloroethene 06/28/23 11:291.880.0900.384µg/m3Toluene 06/28/23 11:293.710.209<0.209µg/m31,2,4-Trichlorobenzene 06/28/23 11:292.730.144<0.144µg/m31,1,1-Trichloroethane 06/28/23 11:292.730.087<0.087µg/m31,1,2-Trichloroethane 06/28/23 11:292.150.199<0.199µg/m3Trichloroethene 06/28/23 11:292.810.130<0.130µg/m3Trichlorofluoromethane 06/28/23 11:292.460.110<0.110µg/m31,2,4-Trimethylbenzene Page 17 of 36Date:07/20/2023 10:03 AM Page 74 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34842QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34838 Associated Lab Samples: 99276 LRB-V34838 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:292.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/28/23 11:291.760.224<0.224µg/m3Vinyl Acetate 06/28/23 11:291.280.127<0.127µg/m3Vinyl Chloride 06/28/23 11:292.170.157<0.157µg/m3o-Xylene 06/28/23 11:295.650.217<0.217µg/m3m,p-Xylene 06/28/23 11:294-Bromofluorobenzene (S)96.0 70-130 LCS-V34838Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10212.111.9µg/m3Acetone 70-130 10316.416.0µg/m3Benzene 70-130 11229.025.9µg/m3Benzyl Chloride 70-130 10334.433.5µg/m3Bromodichloromethane 70-130 10353.551.7µg/m3Bromoform 70-130 11021.419.4µg/m3Bromomethane 70-130 10011.111.1µg/m31,3-Butadiene 70-130 10616.515.6µg/m3Carbon Disulfide 70-130 10332.631.5µg/m3Carbon Tetrachloride 70-130 10724.723.0µg/m3Chlorobenzene 70-130 10645.042.6µg/m3Chlorodibromomethane 70-130 10313.613.2µg/m3Chloroethane 70-130 10525.524.4µg/m3Chloroform 70-130 10410.710.3µg/m3Chloromethane 70-130 10417.917.2µg/m3Cyclohexane 70-130 10640.838.4µg/m31,2-Dibromoethane 70-130 11835.430.1µg/m31,2-Dichlorobenzene 70-130 Page 18 of 36Date:07/20/2023 10:03 AM Page 75 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34842QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34838 LCS-V34838Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11233.830.1µg/m31,3-Dichlorobenzene 70-130 11534.530.1µg/m31,4-Dichlorobenzene 70-130 10626.324.7µg/m3Dichlorodifluoromethane 70-130 10421.120.2µg/m31,1-Dichloroethane 70-130 10320.920.2µg/m31,2-Dichloroethane 70-130 10721.219.8µg/m31,1-Dichloroethene 70-130 10320.419.8µg/m3cis-1,2-Dichloroethene 70-130 10620.919.8µg/m3trans-1,2-Dichloroethene 70-130 10123.423.1µg/m31,2-Dichloropropane 70-130 10536.635.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10223.122.7µg/m3cis-1,3-Dichloropropene 70-130 10223.122.7µg/m3trans-1,3-Dichloropropene 70-130 10218.318.0µg/m31,4-Dioxane 70-130 96.617.418.0µg/m3Ethyl Acetate 70-130 10622.921.7µg/m3Ethylbenzene 70-130 10926.724.6µg/m34-Ethyltoluene 70-130 10740.838.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 99.020.320.5µg/m3Heptane 70-130 10857.653.3µg/m3Hexachlorobutadiene 70-130 10318.217.6µg/m3n-Hexane 70-130 10321.120.5µg/m32-Hexanone 70-130 99.112.212.3µg/m3Isopropyl Alcohol 70-130 10318.518.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10020.520.5µg/m34-Methyl-2-Pentanone 70-130 10718.617.4µg/m3Methylene Chloride 70-130 10728.126.2µg/m3Naphthalene 70-130 97.08.368.61µg/m3Propene 70-130 Page 19 of 36Date:07/20/2023 10:03 AM Page 76 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34842QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34838 LCS-V34838Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10622.521.3µg/m3Styrene 70-130 10736.834.3µg/m31,1,2,2-Tetrachloroethane 70-130 10234.733.9µg/m3Tetrachloroethene 70-130 10118.918.8µg/m3Toluene 70-130 10840.237.1µg/m31,2,4-Trichlorobenzene 70-130 10328.227.3µg/m31,1,1-Trichloroethane 70-130 10729.327.3µg/m31,1,2-Trichloroethane 70-130 10327.826.9µg/m3Trichloroethene 70-130 10930.728.1µg/m3Trichlorofluoromethane 70-130 11327.824.6µg/m31,2,4-Trimethylbenzene 70-130 11127.224.6µg/m31,3,5-Trimethylbenzene 70-130 10318.217.6µg/m3Vinyl Acetate 70-130 10413.312.8µg/m3Vinyl Chloride 70-130 10622.921.7µg/m3o-Xylene 70-130 98.642.843.4µg/m3m,p-Xylene 70-130 1004-Bromofluorobenzene (S)70-130 Page 20 of 36Date:07/20/2023 10:03 AM Page 77 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34855QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34850 Associated Lab Samples: 99270, 99271, 99273, 99276 LRB-V34850 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/27/23 11:104.750.202<0.202µg/m3Acetone 06/27/23 11:101.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/27/23 11:101.470.107<0.107µg/m3Tetrahydrofuran 06/27/23 11:104-Bromofluorobenzene (S)93.2 70-130 LCS-V34850Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10212.111.9µg/m3Acetone 70-130 99.314.714.8µg/m3Methyl Ethyl Ketone (MEK)70-130 97.914.414.7µg/m3Tetrahydrofuran 70-130 97.74-Bromofluorobenzene (S)70-130 Page 21 of 36Date:07/20/2023 10:03 AM Page 78 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34861QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34860 Associated Lab Samples: 99274, 99275 LRB-V34860 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/28/23 11:294.750.202<0.202µg/m3Acetone 06/28/23 11:291.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/28/23 11:291.470.107<0.107µg/m3Tetrahydrofuran 06/28/23 11:294-Bromofluorobenzene (S)96.0 70-130 LCS-V34860Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10212.111.9µg/m3Acetone 70-130 98.614.614.8µg/m3Methyl Ethyl Ketone (MEK)70-130 98.614.514.7µg/m3Tetrahydrofuran 70-130 1004-Bromofluorobenzene (S)70-130 Page 22 of 36Date:07/20/2023 10:03 AM Page 79 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34864QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34863 Associated Lab Samples: 99277 LRB-V34863 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/30/23 10:414.750.202<0.202µg/m3Acetone 06/30/23 10:411.600.073<0.073µg/m3Benzene 06/30/23 10:4110.40.147<0.147µg/m3Benzyl Chloride 06/30/23 10:413.350.150<0.150µg/m3Bromodichloromethane 06/30/23 10:415.170.153<0.153µg/m3Bromoform 06/30/23 10:411.940.115<0.115µg/m3Bromomethane 06/30/23 10:411.110.328<0.328µg/m31,3-Butadiene 06/30/23 10:416.230.060<0.060µg/m3Carbon Disulfide 06/30/23 10:413.150.155<0.155µg/m3Carbon Tetrachloride 06/30/23 10:412.300.107<0.107µg/m3Chlorobenzene 06/30/23 10:414.260.208<0.208µg/m3Chlorodibromomethane 06/30/23 10:411.320.164<0.164µg/m3Chloroethane 06/30/23 10:412.440.086<0.086µg/m3Chloroform 06/30/23 10:411.030.067<0.067µg/m3Chloromethane 06/30/23 10:413.440.161<0.161µg/m3Cyclohexane 06/30/23 10:413.840.151<0.151µg/m31,2-Dibromoethane 06/30/23 10:413.010.096<0.096µg/m31,2-Dichlorobenzene 06/30/23 10:4112.00.174<0.174µg/m31,3-Dichlorobenzene 06/30/23 10:413.010.186<0.186µg/m31,4-Dichlorobenzene 06/30/23 10:412.470.134<0.134µg/m3Dichlorodifluoromethane 06/30/23 10:412.020.101<0.101µg/m31,1-Dichloroethane 06/30/23 10:412.020.129<0.129µg/m31,2-Dichloroethane 06/30/23 10:411.980.107<0.107µg/m31,1-Dichloroethene 06/30/23 10:411.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/30/23 10:411.980.108<0.108µg/m3trans-1,2-Dichloroethene 06/30/23 10:412.310.205<0.205µg/m31,2-Dichloropropane 06/30/23 10:413.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane Page 23 of 36Date:07/20/2023 10:03 AM Page 80 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34864QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34863 Associated Lab Samples: 99277 LRB-V34863 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/30/23 10:412.270.178<0.178µg/m3cis-1,3-Dichloropropene 06/30/23 10:412.270.178<0.178µg/m3trans-1,3-Dichloropropene 06/30/23 10:411.800.435<0.435µg/m31,4-Dioxane 06/30/23 10:411.800.136<0.136µg/m3Ethyl Acetate 06/30/23 10:412.170.106<0.106µg/m3Ethylbenzene 06/30/23 10:412.460.128<0.128µg/m34-Ethyltoluene 06/30/23 10:413.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 06/30/23 10:412.050.143<0.143µg/m3Heptane 06/30/23 10:415.330.330<0.330µg/m3Hexachlorobutadiene 06/30/23 10:411.760.047<0.047µg/m3n-Hexane 06/30/23 10:412.050.285<0.285µg/m32-Hexanone 06/30/23 10:411.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/30/23 10:411.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/30/23 10:412.050.121<0.121µg/m34-Methyl-2-Pentanone 06/30/23 10:411.740.488<0.488µg/m3Methylene Chloride 06/30/23 10:412.620.183<0.183µg/m3Naphthalene 06/30/23 10:410.8600.242<0.242µg/m3Propene 06/30/23 10:412.130.124<0.124µg/m3Styrene 06/30/23 10:413.430.104<0.104µg/m31,1,2,2-Tetrachloroethane 06/30/23 10:413.390.1811.40µg/m3Tetrachloroethene 06/30/23 10:411.470.107<0.107µg/m3Tetrahydrofuran 06/30/23 10:411.880.090<0.090µg/m3Toluene 06/30/23 10:413.710.209<0.209µg/m31,2,4-Trichlorobenzene 06/30/23 10:412.730.144<0.144µg/m31,1,1-Trichloroethane 06/30/23 10:412.730.087<0.087µg/m31,1,2-Trichloroethane 06/30/23 10:412.150.199<0.199µg/m3Trichloroethene 06/30/23 10:412.810.130<0.130µg/m3Trichlorofluoromethane Page 24 of 36Date:07/20/2023 10:03 AM Page 81 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34864QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34863 Associated Lab Samples: 99277 LRB-V34863 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/30/23 10:412.460.110<0.110µg/m31,2,4-Trimethylbenzene 06/30/23 10:412.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/30/23 10:411.760.224<0.224µg/m3Vinyl Acetate 06/30/23 10:411.280.127<0.127µg/m3Vinyl Chloride 06/30/23 10:412.170.157<0.157µg/m3o-Xylene 06/30/23 10:415.650.217<0.217µg/m3m,p-Xylene 06/30/23 10:414-Bromofluorobenzene (S)91.0 70-130 LCS-V34863Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11213.311.9µg/m3Acetone 70-130 10917.416.0µg/m3Benzene 70-130 12331.925.9µg/m3Benzyl Chloride 70-130 11137.133.5µg/m3Bromodichloromethane 70-130 12062.151.7µg/m3Bromoform 70-130 12223.719.4µg/m3Bromomethane 70-130 11412.611.1µg/m31,3-Butadiene 70-130 11918.615.6µg/m3Carbon Disulfide 70-130 10834.131.5µg/m3Carbon Tetrachloride 70-130 11927.423.0µg/m3Chlorobenzene 70-130 12051.242.6µg/m3Chlorodibromomethane 70-130 11915.713.2µg/m3Chloroethane 70-130 11227.324.4µg/m3Chloroform 70-130 11712.010.3µg/m3Chloromethane 70-130 11119.117.2µg/m3Cyclohexane 70-130 12046.238.4µg/m31,2-Dibromoethane 70-130 Page 25 of 36Date:07/20/2023 10:03 AM Page 82 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34864QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34863 LCS-V34863Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 12938.930.1µg/m31,2-Dichlorobenzene 70-130 12738.130.1µg/m31,3-Dichlorobenzene 70-130 13039.130.1µg/m31,4-Dichlorobenzene 70-130 11829.224.7µg/m3Dichlorodifluoromethane 70-130 11623.420.2µg/m31,1-Dichloroethane 70-130 11022.220.2µg/m31,2-Dichloroethane 70-130 11723.219.8µg/m31,1-Dichloroethene 70-130 11522.719.8µg/m3cis-1,2-Dichloroethene 70-130 11623.019.8µg/m3trans-1,2-Dichloroethene 70-130 11025.423.1µg/m31,2-Dichloropropane 70-130 11841.435.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10824.622.7µg/m3cis-1,3-Dichloropropene 70-130 10824.622.7µg/m3trans-1,3-Dichloropropene 70-130 10919.618.0µg/m31,4-Dioxane 70-130 10919.718.0µg/m3Ethyl Acetate 70-130 11825.721.7µg/m3Ethylbenzene 70-130 12029.624.6µg/m34-Ethyltoluene 70-130 11744.938.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 10421.420.5µg/m3Heptane 70-130 12164.653.3µg/m3Hexachlorobutadiene 70-130 11620.517.6µg/m3n-Hexane 70-130 11623.720.5µg/m32-Hexanone 70-130 11016.314.8µg/m3Methyl Ethyl Ketone (MEK)70-130 11220.218.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10621.820.5µg/m34-Methyl-2-Pentanone 70-130 12020.817.4µg/m3Methylene Chloride 70-130 12031.426.2µg/m3Naphthalene 70-130 Page 26 of 36Date:07/20/2023 10:03 AM Page 83 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34864QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34863 LCS-V34863Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1099.358.61µg/m3Propene 70-130 12025.521.3µg/m3Styrene 70-130 134*45.934.3µg/m31,1,2,2-Tetrachloroethane 70-130 10836.633.9µg/m3Tetrachloroethene 70-130 10515.514.7µg/m3Tetrahydrofuran 70-130 10620.018.8µg/m3Toluene 70-130 12044.637.1µg/m31,2,4-Trichlorobenzene 70-130 11029.927.3µg/m31,1,1-Trichloroethane 70-130 12133.027.3µg/m31,1,2-Trichloroethane 70-130 11129.826.9µg/m3Trichloroethene 70-130 12033.628.1µg/m3Trichlorofluoromethane 70-130 12430.624.6µg/m31,2,4-Trimethylbenzene 70-130 12129.824.6µg/m31,3,5-Trimethylbenzene 70-130 11620.517.6µg/m3Vinyl Acetate 70-130 11915.212.8µg/m3Vinyl Chloride 70-130 11625.221.7µg/m3o-Xylene 70-130 11047.643.4µg/m3m,p-Xylene 70-130 1004-Bromofluorobenzene (S)70-130 Page 27 of 36* QC Fail Date:07/20/2023 10:03 AM Page 84 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V34909QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V34907 Associated Lab Samples: 99277 LRB-V34907 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:054.920.139<0.139µg/m3Isopropyl Alcohol 06/29/23 11:054-Bromofluorobenzene (S)98.0 70-130 LCS-V34907Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11113.612.3µg/m3Isopropyl Alcohol 70-130 1004-Bromofluorobenzene (S)70-130 Page 28 of 36Date:07/20/2023 10:03 AM Page 85 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35062,V35523QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35057 Associated Lab Samples: 99279, 99280, 99281, 99282 LRB-V35057 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 07/06/23 11:364.750.2021.47µg/m3Acetone 07/06/23 11:361.600.0730.571µg/m3Benzene 07/06/23 11:363.350.150<0.150µg/m3Bromodichloromethane 07/06/23 11:366.230.0600.520µg/m3Carbon Disulfide 07/06/23 11:362.440.086<0.086µg/m3Chloroform 07/06/23 11:361.030.067<0.067µg/m3Chloromethane 07/06/23 11:363.440.161<0.161µg/m3Cyclohexane 07/06/23 11:363.010.186<0.186µg/m31,4-Dichlorobenzene 07/06/23 11:362.470.134<0.134µg/m3Dichlorodifluoromethane 07/06/23 11:361.980.095<0.095µg/m3cis-1,2-Dichloroethene 07/06/23 11:362.310.205<0.205µg/m31,2-Dichloropropane 07/06/23 11:363.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane 07/06/23 11:361.800.136<0.136µg/m3Ethyl Acetate 07/06/23 11:362.170.106<0.106µg/m3Ethylbenzene 07/06/23 11:362.460.128<0.128µg/m34-Ethyltoluene 07/06/23 11:362.050.143<0.143µg/m3Heptane 07/06/23 11:361.760.047<0.047µg/m3n-Hexane 07/06/23 11:362.050.285<0.285µg/m32-Hexanone 07/06/23 11:364.920.139<0.139µg/m3Isopropyl Alcohol 07/06/23 11:361.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 07/06/23 11:361.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 07/06/23 11:362.050.121<0.121µg/m34-Methyl-2-Pentanone 07/06/23 11:361.740.488<0.488µg/m3Methylene Chloride 07/06/23 11:362.620.183<0.183µg/m3Naphthalene 07/06/23 11:362.130.124<0.124µg/m3Styrene 07/06/23 11:363.390.181<0.181µg/m3Tetrachloroethene 07/06/23 11:361.470.107<0.107µg/m3Tetrahydrofuran Page 29 of 36Date:07/20/2023 10:03 AM Page 86 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35062,V35523QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35057 Associated Lab Samples: 99279, 99280, 99281, 99282 LRB-V35057 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 07/06/23 11:361.880.0900.467µg/m3Toluene 07/06/23 11:362.150.199<0.199µg/m3Trichloroethene 07/06/23 11:362.810.130<0.130µg/m3Trichlorofluoromethane 07/06/23 11:362.460.110<0.110µg/m31,2,4-Trimethylbenzene 07/06/23 11:362.460.236<0.236µg/m31,3,5-Trimethylbenzene 07/06/23 11:362.170.157<0.157µg/m3o-Xylene 07/06/23 11:365.650.217<0.217µg/m3m,p-Xylene 07/06/23 11:364-Bromofluorobenzene (S)94.1 70-130 LCS-V35057Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11814.111.9µg/m3Acetone 70-130 11418.216.0µg/m3Benzene 70-130 11538.533.5µg/m3Bromodichloromethane 70-130 12419.315.6µg/m3Carbon Disulfide 70-130 11828.924.4µg/m3Chloroform 70-130 11912.310.3µg/m3Chloromethane 70-130 11619.917.2µg/m3Cyclohexane 70-130 12838.430.1µg/m31,4-Dichlorobenzene 70-130 12330.424.7µg/m3Dichlorodifluoromethane 70-130 11923.619.8µg/m3cis-1,2-Dichloroethene 70-130 11326.123.1µg/m31,2-Dichloropropane 70-130 12343.135.0µg/m31,2-Dichlorotetrafluoroethane 70-130 11821.218.0µg/m3Ethyl Acetate 70-130 12126.221.7µg/m3Ethylbenzene 70-130 12430.524.6µg/m34-Ethyltoluene 70-130 Page 30 of 36Date:07/20/2023 10:03 AM Page 87 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35062,V35523QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35057 LCS-V35057Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 11122.720.5µg/m3Heptane 70-130 12121.317.6µg/m3n-Hexane 70-130 11723.920.5µg/m32-Hexanone 70-130 11414.012.3µg/m3Isopropyl Alcohol 70-130 11517.014.8µg/m3Methyl Ethyl Ketone (MEK)70-130 11821.318.0µg/m3Methyl tert-butyl ether (MTBE)70-130 11323.220.5µg/m34-Methyl-2-Pentanone 70-130 12221.317.4µg/m3Methylene Chloride 70-130 12332.226.2µg/m3Naphthalene 70-130 12025.621.3µg/m3Styrene 70-130 11539.033.9µg/m3Tetrachloroethene 70-130 11016.114.7µg/m3Tetrahydrofuran 70-130 11221.118.8µg/m3Toluene 70-130 11531.026.9µg/m3Trichloroethene 70-130 12635.328.1µg/m3Trichlorofluoromethane 70-130 12029.524.6µg/m31,2,4-Trimethylbenzene 70-130 12430.524.6µg/m31,3,5-Trimethylbenzene 70-130 11925.921.7µg/m3o-Xylene 70-130 11248.643.4µg/m3m,p-Xylene 70-130 98.64-Bromofluorobenzene (S)70-130 Page 31 of 36Date:07/20/2023 10:03 AM Page 88 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35067,V35524QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35063 Associated Lab Samples: 99278 LRB-V35063 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:051.600.073<0.073µg/m3Benzene 06/29/23 11:053.350.150<0.150µg/m3Bromodichloromethane 06/29/23 11:056.230.060<0.060µg/m3Carbon Disulfide 06/29/23 11:052.440.086<0.086µg/m3Chloroform 06/29/23 11:051.030.067<0.067µg/m3Chloromethane 06/29/23 11:053.440.161<0.161µg/m3Cyclohexane 06/29/23 11:053.010.186<0.186µg/m31,4-Dichlorobenzene 06/29/23 11:052.470.134<0.134µg/m3Dichlorodifluoromethane 06/29/23 11:051.980.095<0.095µg/m3cis-1,2-Dichloroethene 06/29/23 11:052.310.205<0.205µg/m31,2-Dichloropropane 06/29/23 11:053.500.622<0.622µg/m31,2-Dichlorotetrafluoroethane 06/29/23 11:051.800.136<0.136µg/m3Ethyl Acetate 06/29/23 11:052.170.106<0.106µg/m3Ethylbenzene 06/29/23 11:052.460.128<0.128µg/m34-Ethyltoluene 06/29/23 11:052.050.143<0.143µg/m3Heptane 06/29/23 11:051.760.047<0.047µg/m3n-Hexane 06/29/23 11:052.050.285<0.285µg/m32-Hexanone 06/29/23 11:051.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 06/29/23 11:051.800.033<0.033µg/m3Methyl tert-butyl ether (MTBE) 06/29/23 11:052.050.121<0.121µg/m34-Methyl-2-Pentanone 06/29/23 11:051.740.488<0.488µg/m3Methylene Chloride 06/29/23 11:052.620.183<0.183µg/m3Naphthalene 06/29/23 11:052.130.124<0.124µg/m3Styrene 06/29/23 11:053.390.181<0.181µg/m3Tetrachloroethene 06/29/23 11:051.470.107<0.107µg/m3Tetrahydrofuran 06/29/23 11:051.880.090<0.090µg/m3Toluene 06/29/23 11:052.150.199<0.199µg/m3Trichloroethene Page 32 of 36Date:07/20/2023 10:03 AM Page 89 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35067,V35524QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35063 Associated Lab Samples: 99278 LRB-V35063 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 06/29/23 11:052.810.130<0.130µg/m3Trichlorofluoromethane 06/29/23 11:052.460.110<0.110µg/m31,2,4-Trimethylbenzene 06/29/23 11:052.460.236<0.236µg/m31,3,5-Trimethylbenzene 06/29/23 11:052.170.157<0.157µg/m3o-Xylene 06/29/23 11:055.650.217<0.217µg/m3m,p-Xylene 06/29/23 11:054-Bromofluorobenzene (S)98.0 70-130 LCS-V35063Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10116.216.0µg/m3Benzene 70-130 10133.933.5µg/m3Bromodichloromethane 70-130 10816.815.6µg/m3Carbon Disulfide 70-130 10525.524.4µg/m3Chloroform 70-130 10711.010.3µg/m3Chloromethane 70-130 10618.217.2µg/m3Cyclohexane 70-130 11534.630.1µg/m31,4-Dichlorobenzene 70-130 10926.924.7µg/m3Dichlorodifluoromethane 70-130 10921.519.8µg/m3cis-1,2-Dichloroethene 70-130 10323.723.1µg/m31,2-Dichloropropane 70-130 10737.535.0µg/m31,2-Dichlorotetrafluoroethane 70-130 10719.218.0µg/m3Ethyl Acetate 70-130 10723.221.7µg/m3Ethylbenzene 70-130 11027.024.6µg/m34-Ethyltoluene 70-130 10220.920.5µg/m3Heptane 70-130 11019.317.6µg/m3n-Hexane 70-130 10722.020.5µg/m32-Hexanone 70-130 Page 33 of 36Date:07/20/2023 10:03 AM Page 90 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35067,V35524QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35063 LCS-V35063Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10515.614.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10719.318.0µg/m3Methyl tert-butyl ether (MTBE)70-130 10421.320.5µg/m34-Methyl-2-Pentanone 70-130 11219.517.4µg/m3Methylene Chloride 70-130 10728.026.2µg/m3Naphthalene 70-130 10722.721.3µg/m3Styrene 70-130 10134.233.9µg/m3Tetrachloroethene 70-130 10315.114.7µg/m3Tetrahydrofuran 70-130 10119.018.8µg/m3Toluene 70-130 10227.526.9µg/m3Trichloroethene 70-130 11131.128.1µg/m3Trichlorofluoromethane 70-130 11428.024.6µg/m31,2,4-Trimethylbenzene 70-130 11027.124.6µg/m31,3,5-Trimethylbenzene 70-130 10522.821.7µg/m3o-Xylene 70-130 98.842.943.4µg/m3m,p-Xylene 70-130 1004-Bromofluorobenzene (S)70-130 Page 34 of 36Date:07/20/2023 10:03 AM Page 91 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35195QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35191 Associated Lab Samples: 99278 LRB-V35191 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 07/11/23 00:464.750.2021.52µg/m3Acetone 07/11/23 00:464.920.1390.707µg/m3Isopropyl Alcohol 07/11/23 00:464-Bromofluorobenzene (S)98.3 70-130 LCS-V35191Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 89.010.611.9µg/m3Acetone 70-130 87.810.812.3µg/m3Isopropyl Alcohol 70-130 98.84-Bromofluorobenzene (S)70-130 Page 35 of 36Date:07/20/2023 10:03 AM Page 92 of 100 Quality Control Data 23-177-0008Report No: Project Description: Client ID:Hart & Hickman (Charlotte) LEN-008 QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V35233QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V35230 Associated Lab Samples: 99279, 99280 LRB-V35230 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 07/11/23 00:464.750.2021.52µg/m3Acetone 07/11/23 00:464.920.1390.707µg/m3Isopropyl Alcohol 07/11/23 00:464-Bromofluorobenzene (S)98.3 70-130 LCS-V35230Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 89.010.611.9µg/m3Acetone 70-130 87.810.812.3µg/m3Isopropyl Alcohol 70-130 98.84-Bromofluorobenzene (S)70-130 Page 36 of 36Date:07/20/2023 10:03 AM Page 93 of 100 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-177-0008 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:06/26/2023 14:01:53 Special precautions or instructions included? Comments: Page 94 of 100 Page 95 of 100 Page 96 of 100 Page 97 of 100 Page 98 of 100 Page 99 of 100 Page 100 of 100 Appendix D DEQ Risk Calculators Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Building 1 Indoor Air Worst-Case North Carolina Department of Environmental Quality Risk Calculator Charlotte Van and Storage Co. 213 Verbena Street and 4607 Gilead Street, Charlotte, NC DWM Brownfields 23057-19-060 January 2023 November 2022 EPA RSL Table 7/13/2023 Prepared By:Hart & Hickman Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 458 IAS-1 67-64-1 Acetone ug/m3 0.836 IAS-1 71-43-2 Benzene ug/m3 1.18 IAS-3 75-15-0 Carbon Disulfide ug/m3 0.854 IAS-2 67-66-3 Chloroform ug/m3 1.14 IAS-DUP 74-87-3 Chloromethane ug/m3 18.1 IAS-2 75-71-8 Dichlorodifluoromethane ug/m3 3.09 IAS-DUP 141-78-6 Ethyl Acetate ug/m3 3.23 IAS-DUP 100-41-4 Ethylbenzene ug/m3 21.7 IAS-DUP 109-99-9 ~Tetrahydrofuran ug/m3 7.48 IAS-1 142-82-5 Heptane, N-ug/m3 2.65 IAS-1 110-54-3 Hexane, N-ug/m3 5.91 IAS-DUP 591-78-6 Hexanone, 2-ug/m3 134 IAS-3 67-63-0 Isopropanol ug/m3 43.9 IAS-DUP 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.32 IAS-1 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.562 IAS-2 75-09-2 Methylene Chloride ug/m3 9.77 IAS-1 100-42-5 Styrene ug/m3 0.922 IAS-3 127-18-4 Tetrachloroethylene ug/m3 57.3 IAS-3 108-88-3 Toluene ug/m3 35.4 IAS-2 75-69-4 Trichlorofluoromethane ug/m3 5.05 IAS-DUP 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.933 IAS-DUP 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 13.7 IAS-DUP 108-38-3 Xylene, m-ug/m3 4.07 IAS-DUP 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case CAS #Chemical Name: Indoor Air Concentration (ug/m3) IUR (ug/m3)-1 muta- gen V Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 RfC (mg/m3) Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 458 V - -71-43-2 Benzene 0.836 0.0000078 V 3.6E-01 3.00E-02 6.3E+00 2.3E-06 2.7E-0275-15-0 Carbon Disulfide 1.18 V -7.00E-01 1.5E+02 1.6E-03 67-66-3 Chloroform 0.854 0.000023 V 1.2E-01 9.80E-02 2.0E+01 7.0E-06 8.4E-03 74-87-3 Chloromethane 1.14 V -9.00E-02 1.9E+01 1.2E-02 75-71-8 Dichlorodifluoromethane 18.1 V -1.00E-01 2.1E+01 1.7E-01 141-78-6 Ethyl Acetate 3.09 V -7.00E-02 1.5E+01 4.2E-02 100-41-4 Ethylbenzene 3.23 0.0000025 V 1.1E+00 1.00E+00 2.1E+02 2.9E-06 3.1E-03109-99-9 ~Tetrahydrofuran 21.7 V -2.00E+00 4.2E+02 1.0E-02142-82-5 Heptane, N-7.48 V -4.00E-01 8.3E+01 1.8E-02110-54-3 Hexane, N-2.65 V -7.00E-01 1.5E+02 3.6E-03591-78-6 Hexanone, 2-5.91 V -3.00E-02 6.3E+00 1.9E-0167-63-0 Isopropanol 134 V -2.00E-01 4.2E+01 6.4E-01 78-93-3 Methyl Ethyl Ketone (2-Butanone)43.9 V -5.00E+00 1.0E+03 8.4E-03 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.32 V -3.00E+00 6.3E+02 4.2E-0475-09-2 Methylene Chloride 0.562 0.00000001 M V 1.0E+02 6.00E-01 1.3E+02 5.5E-09 9.0E-04 100-42-5 Styrene 9.77 V -1.00E+00 2.1E+02 9.4E-03 127-18-4 Tetrachloroethylene 0.922 0.00000026 V 1.1E+01 4.00E-02 8.3E+00 8.5E-08 2.2E-02 108-88-3 Toluene 57.3 V -5.00E+00 1.0E+03 1.1E-0275-69-4 Trichlorofluoromethane 35.4 V - -95-63-6 Trimethylbenzene, 1,2,4-5.05 V -6.00E-02 1.3E+01 8.1E-02108-67-8 Trimethylbenzene, 1,3,5-0.933 V -6.00E-02 1.3E+01 1.5E-02108-38-3 Xylene, m-13.7 V -1.00E-01 2.1E+01 1.3E-01 95-47-6 Xylene, o-4.07 V -1.00E-01 2.1E+01 3.9E-02 Cumulative:1.2E-05 1.4E+00 All concentrations are in ug/m3 Output Form 3C ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case CAS #Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 458 -- 71-43-2 Benzene 0.836 1.6E+00 2.6E+01 5.3E-07 6.4E-0375-15-0 Carbon Disulfide 1.18 -6.1E+02 3.8E-04 67-66-3 Chloroform 0.854 5.3E-01 8.6E+01 1.6E-06 2.0E-03 74-87-3 Chloromethane 1.14 -7.9E+01 2.9E-0375-71-8 Dichlorodifluoromethane 18.1 -8.8E+01 4.1E-02 141-78-6 Ethyl Acetate 3.09 -6.1E+01 1.0E-02 100-41-4 Ethylbenzene 3.23 4.9E+00 8.8E+02 6.6E-07 7.4E-04 109-99-9 ~Tetrahydrofuran 21.7 -1.8E+03 2.5E-03142-82-5 Heptane, N-7.48 -3.5E+02 4.3E-03 110-54-3 Hexane, N-2.65 -6.1E+02 8.6E-04 591-78-6 Hexanone, 2-5.91 -2.6E+01 4.5E-0267-63-0 Isopropanol 134 -1.8E+02 1.5E-01 78-93-3 Methyl Ethyl Ketone (2-Butanone)43.9 -4.4E+03 2.0E-03 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.32 -2.6E+03 1.0E-04 75-09-2 Methylene Chloride 0.562 1.2E+03 5.3E+02 4.6E-10 2.1E-04100-42-5 Styrene 9.77 -8.8E+02 2.2E-03 127-18-4 Tetrachloroethylene 0.922 4.7E+01 3.5E+01 2.0E-08 5.3E-03 108-88-3 Toluene 57.3 -4.4E+03 2.6E-03 75-69-4 Trichlorofluoromethane 35.4 -- 95-63-6 Trimethylbenzene, 1,2,4-5.05 -5.3E+01 1.9E-02108-67-8 Trimethylbenzene, 1,3,5-0.933 -5.3E+01 3.6E-03 108-38-3 Xylene, m-13.7 -8.8E+01 3.1E-02 95-47-6 Xylene, o-4.07 -8.8E+01 9.3E-03 Cumulative:2.8E-06 3.5E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Indoor Air Worst-Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.2E-05 1.4E+00 YES Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 2.8E-06 3.5E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Building 1 Sub-Slab Vapor Worst-Case North Carolina Department of Environmental Quality Risk Calculator Charlotte Van and Storage Co. 213 Verbena Street and 4607 Gilead Street, Charlotte, NC DWM Brownfields 23057-19-060 January 2023 November 2022 EPA RSL Table 7/13/2023 Prepared By:Hart & Hickman Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 5970 SS-MP-7 67-64-1 Acetone ug/m3 1.06 SS-MP-DUP 71-43-2 Benzene ug/m3 1.39 SS-MP-9 75-27-4 Bromodichloromethane ug/m3 4.61 SS-MP-7 75-15-0 Carbon Disulfide ug/m3 40.2 SS-MP-6 67-66-3 Chloroform ug/m3 2.14 SS-MP-2 74-87-3 Chloromethane ug/m3 2.36 SS-MP-4 110-82-7 Cyclohexane ug/m3 3.14 SS-MP-9 75-71-8 Dichlorodifluoromethane ug/m3 2.16 SS-MP-6 78-87-5 Dichloropropane, 1,2-ug/m3 3.79 SS-MP-DUP 141-78-6 Ethyl Acetate ug/m3 4.57 SS-MP-2 100-41-4 Ethylbenzene ug/m3 14000 SS-MP-7 109-99-9 ~Tetrahydrofuran ug/m3 2.64 SS-MP-DUP 142-82-5 Heptane, N-ug/m3 1.67 SS-MP-9 110-54-3 Hexane, N-ug/m3 5.75 SS-MP-5 591-78-6 Hexanone, 2-ug/m3 103 SS-MP-5 67-63-0 Isopropanol ug/m3 3780 SS-MP-5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.45 SS-MP-5 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 4.93 SS-MP-9 75-09-2 Methylene Chloride ug/m3 4.15 SS-MP-6 91-20-3 ~Naphthalene ug/m3 5.95 SS-MP-5 100-42-5 Styrene ug/m3 40.2 SS-MP-4 127-18-4 Tetrachloroethylene ug/m3 60.4 SS-MP-DUP 108-88-3 Toluene ug/m3 4.26 SS-MP-9 75-69-4 Trichlorofluoromethane ug/m3 4.58 SS-MP-DUP 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.86 SS-MP-2 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 22.3 SS-MP-2 108-38-3 Xylene, m-ug/m3 6.62 SS-MP-DUP 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 5970 179.1 -- 71-43-2 Benzene 1.06 0.0318 3.6E-01 6.3E+00 8.8E-08 1.0E-03 75-27-4 Bromodichloromethane 1.39 0.0417 7.6E-02 -5.5E-07 75-15-0 Carbon Disulfide 4.61 0.1383 -1.5E+02 1.9E-04 67-66-3 Chloroform 40.2 1.206 1.2E-01 2.0E+01 9.9E-06 1.2E-02 74-87-3 Chloromethane 2.14 0.0642 -1.9E+01 6.8E-04 110-82-7 Cyclohexane 2.36 0.0708 -1.3E+03 1.1E-05 75-71-8 Dichlorodifluoromethane 3.14 0.0942 -2.1E+01 9.0E-04 78-87-5 Dichloropropane, 1,2-2.16 0.0648 7.6E-01 8.3E-01 8.5E-08 1.6E-02 141-78-6 Ethyl Acetate 3.79 0.1137 -1.5E+01 1.6E-03 100-41-4 Ethylbenzene 4.57 0.1371 1.1E+00 2.1E+02 1.2E-07 1.3E-04 109-99-9 ~Tetrahydrofuran 14000 420 -4.2E+02 2.0E-01 142-82-5 Heptane, N-2.64 0.0792 -8.3E+01 1.9E-04 110-54-3 Hexane, N-1.67 0.0501 -1.5E+02 6.9E-05 591-78-6 Hexanone, 2-5.75 0.1725 -6.3E+00 5.5E-03 67-63-0 Isopropanol 103 3.09 -4.2E+01 1.5E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone)3780 113.4 -1.0E+03 2.2E-02 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.45 0.0435 -6.3E+02 1.4E-05 75-09-2 Methylene Chloride 4.93 0.1479 1.0E+02 1.3E+02 1.5E-09 2.4E-04 91-20-3 ~Naphthalene 4.15 0.1245 8.3E-02 6.3E-01 1.5E-06 4.0E-02 100-42-5 Styrene 5.95 0.1785 -2.1E+02 1.7E-04 127-18-4 Tetrachloroethylene 40.2 1.206 1.1E+01 8.3E+00 1.1E-07 2.9E-02 108-88-3 Toluene 60.4 1.812 -1.0E+03 3.5E-04 75-69-4 Trichlorofluoromethane 4.26 0.1278 -- 95-63-6 Trimethylbenzene, 1,2,4-4.58 0.1374 -1.3E+01 2.2E-03 108-67-8 Trimethylbenzene, 1,3,5-1.86 0.0558 -1.3E+01 8.9E-04 108-38-3 Xylene, m-22.3 0.669 -2.1E+01 6.4E-03 95-47-6 Xylene, o-6.62 0.1986 -2.1E+01 1.9E-03 Cumulative:1.2E-05 3.6E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 5970 59.7 -- 71-43-2 Benzene 1.06 0.0106 1.6E+00 2.6E+01 6.7E-09 8.1E-05 75-27-4 Bromodichloromethane 1.39 0.0139 3.3E-01 -4.2E-08 75-15-0 Carbon Disulfide 4.61 0.0461 -6.1E+02 1.5E-05 67-66-3 Chloroform 40.2 0.402 5.3E-01 8.6E+01 7.5E-07 9.4E-04 74-87-3 Chloromethane 2.14 0.0214 -7.9E+01 5.4E-05 110-82-7 Cyclohexane 2.36 0.0236 -5.3E+03 9.0E-07 75-71-8 Dichlorodifluoromethane 3.14 0.0314 -8.8E+01 7.2E-05 78-87-5 Dichloropropane, 1,2-2.16 0.0216 3.3E+00 3.5E+00 6.5E-09 1.2E-03 141-78-6 Ethyl Acetate 3.79 0.0379 -6.1E+01 1.2E-04 100-41-4 Ethylbenzene 4.57 0.0457 4.9E+00 8.8E+02 9.3E-09 1.0E-05 109-99-9 ~Tetrahydrofuran 14000 140 -1.8E+03 1.6E-02 142-82-5 Heptane, N-2.64 0.0264 -3.5E+02 1.5E-05 110-54-3 Hexane, N-1.67 0.0167 -6.1E+02 5.4E-06 591-78-6 Hexanone, 2-5.75 0.0575 -2.6E+01 4.4E-04 67-63-0 Isopropanol 103 1.03 -1.8E+02 1.2E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)3780 37.8 -4.4E+03 1.7E-03 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.45 0.0145 -2.6E+03 1.1E-06 75-09-2 Methylene Chloride 4.93 0.0493 1.2E+03 5.3E+02 4.0E-11 1.9E-05 91-20-3 ~Naphthalene 4.15 0.0415 3.6E-01 2.6E+00 1.2E-07 3.2E-03 100-42-5 Styrene 5.95 0.0595 -8.8E+02 1.4E-05 127-18-4 Tetrachloroethylene 40.2 0.402 4.7E+01 3.5E+01 8.5E-09 2.3E-03 108-88-3 Toluene 60.4 0.604 -4.4E+03 2.8E-05 75-69-4 Trichlorofluoromethane 4.26 0.0426 -- 95-63-6 Trimethylbenzene, 1,2,4-4.58 0.0458 -5.3E+01 1.7E-04 108-67-8 Trimethylbenzene, 1,3,5-1.86 0.0186 -5.3E+01 7.1E-05 108-38-3 Xylene, m-22.3 0.223 -8.8E+01 5.1E-04 95-47-6 Xylene, o-6.62 0.0662 -8.8E+01 1.5E-04 Cumulative:9.4E-07 2.8E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Building 1 Sub-Slab Vapor Worst-Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-05 3.6E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 9.4E-07 2.8E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Clubhouse Sub-Slab Vapor Worst-Case North Carolina Department of Environmental Quality Risk Calculator Charlotte Van and Storage Co. 213 Verbena Street and 4607 Gilead Street, Charlotte, NC DWM Brownfields 23057-19-060 January 2023 November 2022 EPA RSL Table 7/13/2023 Prepared By:Hart & Hickman Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Clubhouse Sub-Slab Vapor Worst-Case Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Clubhouse Sub-Slab Vapor Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Clubhouse Sub-Slab Vapor Worst-Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 76 67-64-1 Acetone ug/m3 0.759 75-15-0 Carbon Disulfide ug/m3 1.43 67-66-3 Chloroform ug/m3 2.57 75-71-8 Dichlorodifluoromethane ug/m3 14.8 141-78-6 Ethyl Acetate ug/m3 0.534 100-41-4 Ethylbenzene ug/m3 601 109-99-9 ~Tetrahydrofuran ug/m3 0.356 142-82-5 Heptane, N-ug/m3 0.437 110-54-3 Hexane, N-ug/m3 3.48 67-63-0 Isopropanol ug/m3 274 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 5.04 108-88-3 Toluene ug/m3 2 75-69-4 Trichlorofluoromethane ug/m3 0.535 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2.34 108-38-3 Xylene, m-ug/m3 0.673 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Clubhouse Sub-Slab Vapor Worst-Case CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 76 0.76 -- 75-15-0 Carbon Disulfide 0.759 0.00759 -6.1E+02 2.5E-06 67-66-3 Chloroform 1.43 0.0143 5.3E-01 8.6E+01 2.7E-08 3.3E-05 75-71-8 Dichlorodifluoromethane 2.57 0.0257 -8.8E+01 5.9E-05 141-78-6 Ethyl Acetate 14.8 0.148 -6.1E+01 4.8E-04 100-41-4 Ethylbenzene 0.534 0.00534 4.9E+00 8.8E+02 1.1E-09 1.2E-06 109-99-9 ~Tetrahydrofuran 601 6.01 -1.8E+03 6.9E-04 142-82-5 Heptane, N-0.356 0.00356 -3.5E+02 2.0E-06 110-54-3 Hexane, N-0.437 0.00437 -6.1E+02 1.4E-06 67-63-0 Isopropanol 3.48 0.0348 -1.8E+02 4.0E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)274 2.74 -4.4E+03 1.3E-04 108-88-3 Toluene 5.04 0.0504 -4.4E+03 2.3E-06 75-69-4 Trichlorofluoromethane 2 0.02 -- 95-63-6 Trimethylbenzene, 1,2,4-0.535 0.00535 -5.3E+01 2.0E-05 108-38-3 Xylene, m-2.34 0.0234 -8.8E+01 5.3E-05 95-47-6 Xylene, o-0.673 0.00673 -8.8E+01 1.5E-05 Cumulative:2.8E-08 1.5E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Clubhouse Sub-Slab Vapor Worst-Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.8E-08 1.5E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 7/13/2023 Prepared By:Hart & Hickman Hart & Hickman Maintenance Room Sub-Slab Vapor Worst-Case North Carolina Department of Environmental Quality Risk Calculator Charlotte Van and Storage Co. 213 Verbena Street and 4607 Gilead Street, Charlotte, NC DWM Brownfields 23057-19-060 January 2023 November 2022 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Maintenance Room Sub-Slab Vapor Worst-Case Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Maintenance Room Sub-Slab Vapor Worst-Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Maintenance Room Sub-Slab Vapor Worst-Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 46.5 67-64-1 Acetone ug/m3 3.56 71-43-2 Benzene ug/m3 2.54 75-15-0 Carbon Disulfide ug/m3 51.3 67-66-3 Chloroform ug/m3 3.19 110-82-7 Cyclohexane ug/m3 1.02 106-46-7 Dichlorobenzene, 1,4-ug/m3 4.47 156-59-2 Dichloroethylene, cis-1,2-ug/m3 2.45 78-87-5 Dichloropropane, 1,2-ug/m3 24.7 100-41-4 Ethylbenzene ug/m3 22.2 109-99-9 ~Tetrahydrofuran ug/m3 0.848 142-82-5 Heptane, N-ug/m3 2.07 110-54-3 Hexane, N-ug/m3 289 67-63-0 Isopropanol ug/m3 1.76 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.356 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.407 1634-04-4 Methyl tert-Butyl Ether (MTBE)ug/m3 3.84 75-09-2 Methylene Chloride ug/m3 4.6 100-42-5 Styrene ug/m3 3.14 127-18-4 Tetrachloroethylene ug/m3 15.1 108-88-3 Toluene ug/m3 0.999 79-01-6 Trichloroethylene ug/m3 20.2 75-69-4 Trichlorofluoromethane ug/m3 1.27 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 33.2 108-38-3 Xylene, m-ug/m3 9.09 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Maintenance Room Sub-Slab Vapor Worst-Case CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 46.5 0.465 -- 71-43-2 Benzene 3.56 0.0356 1.6E+00 2.6E+01 2.3E-08 2.7E-04 75-15-0 Carbon Disulfide 2.54 0.0254 -6.1E+02 8.3E-06 67-66-3 Chloroform 51.3 0.513 5.3E-01 8.6E+01 9.6E-07 1.2E-03 110-82-7 Cyclohexane 3.19 0.0319 -5.3E+03 1.2E-06 106-46-7 Dichlorobenzene, 1,4-1.02 0.0102 1.1E+00 7.0E+02 9.1E-09 2.9E-06 156-59-2 Dichloroethylene, cis-1,2-4.47 0.0447 -3.5E+01 2.6E-04 78-87-5 Dichloropropane, 1,2-2.45 0.0245 3.3E+00 3.5E+00 7.4E-09 1.4E-03 100-41-4 Ethylbenzene 24.7 0.247 4.9E+00 8.8E+02 5.0E-08 5.6E-05 109-99-9 ~Tetrahydrofuran 22.2 0.222 -1.8E+03 2.5E-05 142-82-5 Heptane, N-0.848 0.00848 -3.5E+02 4.8E-06 110-54-3 Hexane, N-2.07 0.0207 -6.1E+02 6.8E-06 67-63-0 Isopropanol 289 2.89 -1.8E+02 3.3E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.76 0.0176 -4.4E+03 8.0E-07 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0.356 0.00356 -2.6E+03 2.7E-07 1634-04-4 Methyl tert-Butyl Ether (MTBE)0.407 0.00407 4.7E+01 2.6E+03 8.6E-11 3.1E-07 75-09-2 Methylene Chloride 3.84 0.0384 1.2E+03 5.3E+02 3.1E-11 1.5E-05 100-42-5 Styrene 4.6 0.046 -8.8E+02 1.1E-05 127-18-4 Tetrachloroethylene 3.14 0.0314 4.7E+01 3.5E+01 6.7E-10 1.8E-04 108-88-3 Toluene 15.1 0.151 -4.4E+03 6.9E-06 79-01-6 Trichloroethylene 0.999 0.00999 3.0E+00 1.8E+00 3.3E-09 1.1E-03 75-69-4 Trichlorofluoromethane 20.2 0.202 -- 95-63-6 Trimethylbenzene, 1,2,4-1.27 0.0127 -5.3E+01 4.8E-05 108-38-3 Xylene, m-33.2 0.332 -8.8E+01 7.6E-04 95-47-6 Xylene, o-9.09 0.0909 -8.8E+01 2.1E-04 Cumulative:1.1E-06 8.9E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2023 Basis: November 2022 EPA RSL Table Site ID: 23057-19-060 Exposure Unit ID: Maintenance Room Sub-Slab Vapor Worst-Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.1E-06 8.9E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not modeled, user did not check this pathway as complete. 4. NC = Pathway not calculated, required contaminant migration parameters were not entered. DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator