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1101_Buncombe_MSWLF_April23GW_FID1815791_20230824
DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander. PG. RSM E-mail: andy.alexander(cDblecorp.com Phone: 864-288-1265 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Id Buncombe County Landfill 2726 Riverside Drive, Woodfin, NC, 1101-MSWLF .1600 April 12-17, 2023 28804 1979 0 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, PG RSM Consultant Hydrogeologist 864-288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number �� w a• �E,o•,....=a•d,a ®e,•o.owm, 2023-08-24 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal ``��\1111f11►����'' r > 1 5 cr d 100,1' W A�%,% % '��r►efillnt` WATER QUALITY REPORT FIRST SEMI-ANNUAL EVENT 2023 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. W10100353 Prepared For: Buncombe County, North Carolina BLE Project Number J22-14175-07 August 22, 2023 BLE North Carolina Business Licenses C-284 & C-1538 IM EJUNNELL LAMMEINS EN131NEERmr. 6004 Ponders Court I Greenville, 5C 29515 864.288.1265 �I 854.288,4330 0 Info@hl2corp.com BLECQRMOM � CANNONS ENGINEERING August 22, 2023 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Water Quality Report First Semi -Annual Event 2023 Old Buncombe County Landfill Woodfin, North Carolina DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. W10100353 BLE Project Number J22-14175-07 Dear Ms. Smith: Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J22-14175-07, dated July 6, 2022, BLE has prepared this water quality report for the first semi-annual sampling event of 2023 at the Old Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) and the North Carolina Division of Water Resources (DWR) approved monitoring program, sampling and analysis will be conducted twice in 2023. This report contains the information required by both the DWM and DWR to document the sampling and analysis activities for the first semi-annual sampling event of 2023 in the State's permanent project record. Sincerely, BUNNELL LAMMONs ENGINEERING INC. Thomas A. O'Shea Project Geologist Registered, NC # 2830 cc: Ms. Jaclynne Drummond — DWM-ARO Mr. Brett Laverty, P.G. — DWR-ARO Mr. Michael Rogers, P.G. — DWR-CO Mr. Riley Blais, G.I.T. — BLE a4l Andrew W. Ale der, P.G., RSM Consultant Hydrogeologist Registered, NC #1475 '6004 Panders Court, Greenvll€e, SC 29615 1,864,288.1265 r,-#864,288.4430 info@hleeorp,com BLECORP.COM 1s 1m 1i Water Quality Report — I sr Semi -Annual Event 2023 August 22, 2023 Old Buncombe County Landfill — Woodfin, North Carolina BLE Project No. J22-14175-07 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 2 5.0 METALS COMPLIANCE............................................................................................................3 6.0 CONCLUSIONS AND RECOMMENDATIONS....................................................................... 3 7.0 QUALIFICATIONS OF REPORT.............................................................................................. 3 8.0 CLOSING.......................................................................................................................................3 Tables Table 1 SWS Approved Groundwater Sampling and Analysis Matrix Table 2 SWS Approved Surface Water Sampling and Analysis Matrix Table 3 Well Construction and Monitoring Well Data Table 4 Range of Groundwater Flow Velocities Table 5 Groundwater VOCs Table 6 Groundwater Field Parameters and Total Metals Table 7 Surface Water VOCs Table 8 Surface Water Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 12-13, 2023 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Water Quality Report — I sr Semi -Annual Event 2023 August 22, 2023 Old Buncombe County Landfill — Woodfin, North Carolina BLE Project No. J22-14175-07 1.0 PROJECT INFORMATION Buncombe County provides post -closure care for the Pre -Subtitle D MSWLF (unlined) located at 2726 Riverside Drive, Woodfin, North Carolina (Figure 1). The county operated the facility as a municipal solid waste (MSW), industrial solid waste (ISW), and construction and demolition (C&D) landfill. The landfill is separated into four (4) waste areas labeled A through D. Waste areas A, B, and C stopped receiving waste before October 9, 1991, and waste area D stopped receiving waste on September 27, 1997. Groundwater and surface water monitoring is performed semi-annually at the site in general accordance with the following documents: • Corrective Action Plan (CAP) dated September 3, 2014 [FID 102260 (SCS Engineers File No 09204072.06)] prepared by SCS Engineers. • Request for Reduction of MNA Parameters dated November 30, 2016 [FID 583167 (SCS Engineers File No 09204072.14)] prepared by SCS Engineers. • Report of 1,4-Dioxane Sampling and Analysis November 2018 to April 2020 dated September 1, 2020 [FID 145059 (BLE Project No. J20-14175-04)] prepared by BLE. • Corrective Action Evaluation Report, Water Quality Data Through October 2021 dated March 30, 2022 [FID 1661864 (BLE Project No. J20-14175-03)] prepared by BLE. • Report of Limited Assessment of the MW-7 Area dated October 28, 2022 [FID 1740675 (BLE Project No. J22-14175-08)] prepared by BLE. The SWS approved sampling matrices are provided as Table 1 (groundwater) and Table 2 (surface water). As part of the corrective action at the facility, Buncombe County applied for, and was granted a permit for subsurface injection of materials for enhanced bioremediation of VOCs in groundwater. The Underground Injection Control (UIC) Permit (No WI0100353) was transmitted by the DWR on September 11, 2015. The permit issue date was September 15, 2015. The permit was renewed on September 21, 2020 and expires on August 31, 2025 (effective dates). The UIC permit requires groundwater monitoring and reporting. We understand that this semi-annual monitoring report prepared as part of the DWM approved sampling and analysis matrix is sufficient to meet the monitoring requirements of the UIC permit. The active groundwater monitoring network for the closed Buncombe County Landfill consists of one (1) upgradient (background) well and twenty-five (25) downgradient (compliance, performance, and sentinel) wells. There are a total of twelve (12) additional wells that are considered inactive for sampling purposes and are used for collecting water levels only (Table 1). Six (6) active surface water monitoring locations have been established for the facility to monitor surface water quality. The existing surface water locations consist of one (1) upstream (background) location and five (5) downstream (compliance) locations. Seven (7) inactive surface water monitoring locations have been established but are not sampled (Table 2). 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected on April 13 and 17, 2023 by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina. Groundwater samples were collected from 1 of 3 1s 1M 1i Water Quality Report — I s' Semi -Annual Event 2023 August 22, 2023 Old Buncombe County Landfill — Woodfin, North Carolina BLE Project No. J22-14175-07 twenty-five (25) of the twenty-six (26) active groundwater monitoring well locations. One (1) well (DPL-1) had an insufficient volume of water for sampling purposes. Additionally, the six (6) active surface water locations were sampled. The groundwater and surface water samples were delivered and analyzed in Pace's Columbia, South Carolina laboratory for the constituents in the approved matrices (Table 1 and Table 2). The field parameters of dissolved oxygen, ferrous iron, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on April 12-13, 2023 is presented in Table 3. Groundwater flow velocity estimates are presented in Table 4. A groundwater elevation contour map with generalized groundwater flow directions is presented as Figure 2. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized on Table 5 and Table 6 and the laboratory analytical data is included in Appendix B. Please refer to Table 5 and Table 6 for a summary of which groundwater constituents exceed North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included dissolved oxygen, ferrous iron, pH, redox potential, specific conductance, turbidity, and temperature. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized on Table 7 and Table 8 and the laboratory analytical data is included in Appendix B. Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. Please refer to Table 7 and Table 8 for a summary of which surface water constituents and field parameters exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. 'North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L .0202, April 1, 2022. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated July 26, 2022. 2 of 3 1s 1m 1i Water Quality Report — I s' Semi -Annual Event 2023 August 22, 2023 Old Buncombe County Landfill — Woodfin, North Carolina BLE Project No. J22-14175-07 5.0 METALS COMPLIANCE The SWS issued new groundwater metals standards (NC2Ls) on April 1, 2022. As part of the updated NC2L standards, all metals were removed from the Interim Maximum Allowable Concentrations (IMACs) list and added to the NC2L standards. This change has resulted in several metals compliance issues at the facility. BLE understands that solid waste facilities will be allowed to utilize alternate groundwater protection standards calculated from background wells, perform a limited ASD, or enter assessment monitoring per the solid waste regulations. BLE has evaluated the metals data through the October 2022 semi-annual sampling event. BLE conducted a virtual meeting with the SWS on February 21, 2023 to discuss solutions to each metal compliance issue. The SWS agreed that the facility should submit a standalone metals compliance report to document the findings. This report will be submitted under separate cover at a later date. 6.0 CONCLUSIONS AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the first semi-annual event of 2023 in general accordance with the SWS approved sampling matrices (Table 1 and Table 2). Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that semi-annual sampling continue in accordance the SWS approved sampling matrices. MNA parameters are scheduled to be collected and reported every five (5) years in accordance with the approved groundwater sampling matrix (Table 1). The next MNA sampling event will be performed during the Spring 2026 sampling event. 7.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the DWM and DWR) without BLE's prior written consent. 8.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 3 of 3 TABLES Table 1 SWS-Approved Groundwater Sampling and Analysis Matrix Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Standard Semi -Annual Laboratory Parameters Standard Semi -Annual Field Parameters Geochemical Parameters for MNA (Sampled Every 5 Years**) Monitoring Well Well Status Transect Number Appendix I VOCs (EPA 8260B) 1,4-dioxane (EPA 8260 SIM) Appendix H Full List (Various Methods) Appendix I Metals WL Turb Temp pH ORP DO SC Alkalinity DH VITA TOC BOD COD Chloride CO2 FeZ NO3 MEE SO4 Sulfide DPL-1 Active 5 Y Y O Y Y Y Y Y Y Y Y DPI-2 Injection 4 MW-A Inactive - Y MW-B Active 2 Y Y - Y Y Y Y Y Y Y Y MW-2 Active - Y O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-3 Active 3 Y Y - Y Y Y Y Y Y Y Y MW-4 Active 4 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-4A Active 1 Y Y - Y Y Y Y Y Y Y Y MW-5 Active 5 Y Y O Y Y Y Y Y Y Y Y MW-6 Active 5 Y Y O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y NM-6-192 Active 5 Y Y - Y Y Y Y Y Y Y Y MW-7 Active - Y Y Y Y Y Y Y Y Y MW-8 Active Y Y Y Y Y Y Y Y Y Y MW-9 Abandoned NW-10 Abandoned MW-12-10 Inactive - Y NM-12-25 Active 1 Y Y Y Y Y Y Y Y Y MW-13-10 Inactive - Y NM-13-35 Active 1 Y Y Y Y Y Y Y Y Y MW-13-132 Active 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-14 Inactive - Y MW-15 Active Y Y Y Y Y Y Y Y Y NM-16 Abandoned MW-17 Abandoned NM-17-60 Active 2 Y Y Y Y Y Y Y Y Y Y MW-17-137 Active 2 Y Y Y Y Y Y Y Y Y Y MW-17-310 Active - Y Y Y Y Y Y Y Y Y MW-18-3 Inactive - Y NW-18-78 Active 5 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-19-4 Inactive Y NM-19-75 Active 4 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-19-110 Active 4 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-20-3 Inactive - Y MW-20-32 Inactive Y MW-21-4 Inactive - Y MW-21-21 Active 3 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y NM-21-94 Active 3 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-22-78 Inactive - Y MW-22-143 Inactive Y MW-23-119 Active Y Y Y Y Y Y Y Y Y Y MW-23-186 Inactive - Y MW-24-45 Active 1 Y Y Y Y Y Y Y Y Y Y MW-24-160 Active 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Notes: Typical Events: April (Spring) and October (Fall) BOD = Biologic Oxygen Demand 0 =October (Fall) Only COD =Chemical Oxygen Demand VOCs = Volatile Organic Compounds 40 CFR Part 258 Appendix I - Constituents for Detection Monitoring (Organics and Inorganics) Matrix Approved by the SWS on November 3, 2022 40 CFR Part 258 Appendix 11- Constituents for Assessment Monitoring (Full List) ** 5 Year MNA sampling to be performed twice consecutively every 5 years. MNA sampling events are scheduled for Spring and Fall 2026, Spring and Fall 2031, Spring and Fall 2036, etc. WL = Water Level ORP = Oxidation Reduction Potential DO = Dissolved Oxygen SC = Specific Conductance DH = Dissolved Hydrogen VFA = Volatile Fatty Acids TOC = Total Organic Carbon FeZ = Iron 11 NO3 = Nitrate MEE = Methane/Ethene/Ethane SO4 = Sulfate CO2 = Carbon Dioxide Prepared By: RLB Tl APPROVED GIN Matrix of 14175-07B GW Tables Checked By: AWA Table 2 SWS-Approved Surface Water Sampling and Analysis Matrix Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Standard Semi -Annual Laboratory Parameters Standard Semi -Annual Field Parameters Surface Water Location Location Status Appendix I VOCs (EPA 8260B) 1,4-dioxane (EPA 8260 SIM) Appendix I Metals Turb Temp pH ORP DO SC SW-1 Active Y - Y Y Y Y Y Y Y SW-2 Active Y - Y Y Y Y Y Y Y SW-2A Active Y Y Y Y Y Y Y Y Y SW-3 Active Y Y Y Y Y Y Y Y Y SW-4 Active Y Y Y Y Y Y Y Y Y SW-5 Inactive - - - - - - - - - SW-6 Inactive - - - - - - - - - SW-7 Inactive - - - - - - - - - SW-8 Inactive - - - - - - - - - SW-9 Inactive - - - - - - - - - SW-10 Active Y Y Y Y Y Y Y Y Y SW-11 Inactive - - - - - - - - - SW-12 Inactive - - - - - - - - - Notes Typical Events: April (Spring) and October (Fall) VOCs = Volatile Organic Compounds Y = Yes 40 CFR Part 258 Appendix I - Constituents for Detection Monitoring (Organics and Inorganics) Matrix Approved by the SWS on November 3, 2022 T2 APPROVED SW Matrix of 14175-07B SW Tables ORP = Oxidation Reduction Potential DO = Dissolved Oxygen SC = Specific Conductance Prepared By: RLB Checked By: AWA Table 3 Well Construction and Monitoring Well Data Old Buncombe County Landfill WoodBn, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Monitoring Point Northing' Easting' Latitude' Longitude' TOC Elevation (ft)1 GS Elevation (ft)1 Depth to GW (ft) April 12-13, 2023 Groundwater Elevation (ft) Well Depth (ft)2 Screen Depth (below GS)2 Geology Monitored Well Status/Purpose DPL-1 714,361.18 928,456.44 35.659306 -82.608093 2038.80 2035.69 Dry Dry 65 55 65 Bedrock Com liance DPL-2 714,508.09 928,812.69 35.659745 -82.606912 2114.58 2111.20 A A 97 87 97 Bedrock Injection MW-A 714,653.61 931,067.65 35.660370 -82.599344 2061.86 2061.11 NM NM 33 23 33 Bedrock DNA MW-B 713,636.00 930,420.70 35.657511 -82.601396 1965.67 1962.74 3.60 1962.07 15 5 15 Bedrock Compliance MW-2 715,052.59 930,063.52 35.661365 -82.602771 2203.40 2201.91 109.39 2094.01 175 145 - 175 Bedrock Background MW-3 713,844.85 929,814.49 35.658024 -82.603461 1989.66 1988.90 62.93 1926.73 90 60 90 Bedrock Compliance MW-4 714,177.69 928,875.50 35.658844 -82.606660 2012.70 2011.45 72.04 1940.66 75 55 75 Bedrock Performance MW-4A 713,352.06 931,194.62 35.656809 -82.598758 2085.21 2081.93 70.50 2014.71 77 67 77 Bedrock Compliance MW-5 714,620.02 928,175.12 35.659989 -82.609071 2018.19 2017.29 52.07 1966.12 80 70 80 Bedrock Compliance MW-6 715,102.82 928,153.41 35.661312 -82.609203 2000.57 1999.07 0.00 2000.57 40 30 40 Bedrock Performance MW-6-192 715,146.26 928,114.53 35.661428 -82.609339 2007.66 2005.28 25.90 1981.76 192 182 - 192 Bedrock Compliance MW-7 715,603.34 930,534.26 35.662924 -82.601254 2107.19 2105.99 25.02 2082.17 29 14 29 Sa rolite Compliance MW-8 716,107.33 930,308.42 35.664285 -82.602075 2077.49 2075.79 25.01 2052.48 38 23 38 Sa rolite DNA MW-9 716,024.04 928,619.48 35.663888 -82.607748 2061.59 2060.00 A A 29 14 29 Sa rolite DNA MW-10 716,086.52 929,060.47 35.664104 -82.606272 2049.67 2047.40 A A 19 9 19 Saprolite DNA MW-12-10 713,233.47 931,366.96 35.656500 -82.598163 2026.18 2023.38 Dry Dry 8 4 8 Sa rolite DNA MW-12-25 713,259.03 931,352.62 35.656569 -82.598215 2028.30 2024.86 6.65 2021.65 26 16 26 Bedrock Compliance MW-13-10 713,000.86 931,279.38 35.655853 -82.598430 2012.10 2008.73 5.27 2006.83 10 4 10 Sa rolite DNA MW-13-35 713,023.75 931,236.48 35.655912 -82.598577 2015.33 2012.75 6.30 2009.03 35 25 35 Bedrock Compliance MW-13-132 712,998.15 931,273.45 35.655845 -82.598449 2011.10 2009.06 24.80 1986.30 132 122 - 132 Bedrock Performance MW-14 716,347.10 930,123.47 35.664925 -82.602727 2051.82 2048.25 8.43 2043.39 55 40 55 Bedrock DNA MW-15 716,993.75 929,508.90 35.666639 -82.604874 2026.42 2022.86 5.63 2020.79 72 62 72 Bedrock Compliance MW-16 716,170.02 929,107.21 35.664338 -82.606124 2048.13 2045.13 A A 94 84 94 Bedrock DNA MW-17A 713,217.57 930,151.76 35.656389 -82.602222 1902.27 1900.08 NM NM DNA DNA - DNA DNA DNA MW-17B 713,213.55 930,148.27 35.656324 -82.602261 1902.54 1899.99 NM NM DNA DNA - DNA DNA DNA MW-17-60 713,339.26 930,205.43 35.656675 -82.602084 1921.48 1918.77 22.18 1899.30 60 50 60 Bedrock Compliance MW-17-137 713,329.77 930,198.94 35.656648 -82.602105 1920.39 1917.85 20.88 1899.51 137 127 - 137 Bedrock Compliance MW-17-310 713,303.06 930,207.54 35.656576 -82.602072 1915.66 1913.61 0.00 1915.66 310 300 - 310 Bedrock Compliance MW-18-3 714,131.08 927,843.29 35.658613 -82.610127 1893.83 1890.82 Dry Dry 3 1 3 Flood Plain DNA MW-18-78 714,131.26 927,848.96 35.658614 -82.610108 1893.33 1890.63 6.60 1886.73 78 68 78 Bedrock Sentinel MW-19-4 713,953.98 928,939.49 35.658237 -82.606418 1900.58 1897.63 Dry Dry 4 2 4 Flood Plain DNA MW-19-75 713,948.98 928,950.27 35.658224 -82.606381 1899.14 1897.07 9.49 1889.65 75 65 75 Bedrock Compliance MW-19-110 713,951.75 928,942.64 35.658231 -82.606407 1899.96 1897.49 10.43 1889.53 110 100 - 110 Bedrock Sentinel MW-20-3 713,865.04 929,310.44 35.658029 -82.605159 1897.91 1895.48 Dry Dry 3 2 3 Flood Plain DNA MW-20-32 713,878.43 929,332.88 35.658068 -82.605085 1898.06 1895.76 NM NM 32 22 32 Bedrock DNA MW-21-4 713,810.54 929,567.53 35.657905 -82.604287 1898.68 1895.30 Dry Dry 4 2 4 Flood Plain DNA MW-21-21 713,826.68 929,581.80 35.657951 -82.604241 1898.83 1897.24 4.64 1894.19 21 11 21 Bedrock Performance MW-21-94 713,829.64 929,577.46 35.657959 -82.604256 1899.49 1897.35 9.03 1890.46 94 84 94 Bedrock Sentinel MW-22-78 716,369.71 930,379.80 35.665013 -82.601867 2066.63 2064.74 NM NM 79 69 79 Bedrock DNA MW-22-143 716,364.76 930,392.94 35.665001 -82.601823 2066.82 2064.90 44.01 2022.81 148 138 - 148 Bedrock DNA MW-23-119 716,013.17 930,475.78 35.664043 -82.601501 2075.12 2073.14 43.19 2031.93 120 110 - 120 Bedrock DNA MW-23-186 716,003.78 930,479.88 35.664018 -82.601486 2074.97 2073.07 52.20 2022.77 186 176 - 186 Bedrock DNA MW-24-45 711,430.70 931,036.63 35.651518 -82.599055 1930.19 1928.16 Dry Dry 45 35 45 Bedrock Compliance MW-24-160 711,436.32 931,042.55 35.651534 -82.599036 1931.81 1929.54 94.40 1837.41 160 150 - 160 Bedrock Sentinel 1 - Survey performed by Ed Holmes & Associates Land Surveyors, PA on August 31, 2022. 2 - Data from Table 1, Well Construction Summary, from Old Buncombe County Landfill Corrective Action Plan, by SCS Engineers, Dated September 3, 2014. TOC - Top of Casing. GS - Ground Surface. DNA - Data Not Available A - Abandoned NM - Not Measured 14175-07B GW Tables Prepared By: TAO Table 3 April 2023 Checked By: RLB Table 4 Range of Groundwater Flow Velocities Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Hydraulic Conductivity K(ft/min) K(cm/sec) K(ft/day) High Estimate 3.9E-02 2.0E-02 56.10 Low Estimate 3.3E-03 1.7E-03 4.80 Geometric Mean 1.1E-02 5.8E-03 16.41 Geometric Mean Hydraulic Conductivity K(ft/day) Hydraulic Grad. (ft/ft) Effective Porosity Flow Vel. (ft/day) Flow Vel. (ft/year) High Estimate 16.41 0.261 5% 85.62 31,250 Low Estimate 16.41 0.027 5% 8.75 3,194 Notes 1. Hydraulic conductivity and effeictive porosity values obtainted from the table titled April 2014 Groundwater Velocity Calculations from the report titled Old Buncombe County Landfill Corrective Action Plan prepared by SCS dated September 3, 2014. 3. The hydraulic gradients were measured from the April 12-13, 2023 groundwater elevation contour map (Figure 2). The high hydraulic gradient was measured between the 1900-ft & 1960-ft groundwater contours near MW-17-60 and MW-B. The low hydraulic gradient was measured between the 2040-ft & 2020-ft groundwater contours near MW-14 and MW-15. 4. Groundwater velocity derived from V = Ki/ne where: K = geometric mean hydraulic conductivity, i = hydraulic gradient, and ne = effective porosity. 5. The high and low velocity estimates are calculated using the geometric mean K and the high and low range of site hydraulic data obtained from SCS's Corrective Action Plan. The accuracy is limited by the references used. 14175-07B GW Tables Prepared By: TAO Table 4 GW Flow Vel. Checked By: RLB Table 5 Groundwater VOCs Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Sampled by Pace Analytical Services, LLC. April 13 & 17, 2023 TEST UNITS LOQ DL MCL MW B MW 2 MW-3 MW-4 MW-4A MW-5 MW-6 MW-6-192 MW-7 MW-8 MW-12-25 MW-13-35 MW-13-132 MW-15 MW-17-60 MW-17-137 MW-17-310 MW-18-78 MW-19-75 MW-19-110 MW-21-21 MW-21-94 MW-23-119 MW-24-45 MW-24-160 DPI-1 Acetone µg/l 20 5.0 6,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 9.1 J <5.0 5.5 JL 12 JL <5.0 18 JL <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 38 <5.0 6.0 JL Dry Acrylonitrile 119/1 20 0.80 NE <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 10.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 Dry Benzene µg/l 1.0 0.40 1.0 <0.40 <0.40 1.1 0.89 J 4.4 0.79 J 1.4 <0.40 1.1 <0.40 <0.40 1.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 2.0 <0.40 <0.40 <0.40 <0.40 Dry Bromochloromethane µg/1 1.0 0.40 NE <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Bromodichloromethane µg/l 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 10.40 <0.40 <0.40 <0.40 <0.40 Dry Bromoform µg/1 1.0 0.40 4.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Carbon Disulfide µg/l 1.0 0.40 700 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Bromomethane (Methylbromide) µg" 2.0 0.40 10 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Carbon tetrachloride 99/1 1.0 0.40 0.3 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Chlorobenzene (mono) 99/1 1.0 0.40 50 0.70 J 1.9 3.9 4.2 35 11 10 0.87 J 4.6 <0.40 <0.40 5.6 <0.40 <0.40 <0.40 <0.40 <0.40 1.6 2.8 0.86 J 5.2 1.0 0.70 J <0.40 <0.40 Dry Chloroethane µg/l 2.0 0.40 3,000 <0.40 <0.40 2.1 1.6 J <0.40 1.1 J 2.6 <0.40 0.97 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.74 J <0.40 2.3 <0.40 <0.40 <0.40 Dry Chloroform 119/1 1.0 0.40 70 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Chloromethane (Methylchlodde) µg/l 1.0 0.50 3.0 <0.5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Dry Dibromochloromethane µg" 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,2-Dibromo-3-chloropropane; DBCP 99/1 1.0 0.40 0.04 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,2-Dibromoethane; Ethylene dibromide pg/1 1.0 0.40 0.02 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Dibromomethane µg/1 1.0 0.40 70.0 (1) <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,2-Dichlorobenzene pg/1 1.0 0.40 20 <0.40 <0.40 0.66 J 0.59 J 3.8 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 3.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1.2 <0.40 <0.40 <0.40 <0.40 Dry 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 99/1 µg" 1.0 2.0 0.40 0.50 6.0 NE 1.0 <0.50 <0.40 <0.50 7.1 <0.50 4.2 <0.50 <0.50 4.1 <0.50 4.1 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 14 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 0.99 J <0.50 2.5 <0.50 015 J <0.50 <0.50 1.0 <0.50 <0.40 <0.50 <0.40 <0.50 <0.40 <0.50 Dry Dry 1,1-Dichloroethme 99/1 1.0 0.40 6.0 0.54 J <0.40 0.91 J 4.8 <0.40 <0.40 1.4 0.72 J 2.1 0.51 J <0.40 <0.40 1.0 <0.40 0.86 J 0.69 J <0.40 0.52 J 0.46 J <0.40 1.1 <0.40 0.66 J <0.40 <0.40 Dry 1,2-Dichloroethme µg" 1.0 0.40 0.4 <0.40 <0.40 <0.40 0.40 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,1-Dichloroethene(-ethylene) 99/1 1.0 0.40 350 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry cis-1,2-Dichloroethene (-ethylene) µg/l 1.0 0.40 70 6.1 <0.40 0.59 J 13 <0.40 <0.40 <0.40 <0.40 9.4 <0.40 <0.40 2.2 7.7 <0.40 1.2 <0.40 <0.40 <0.40 <0.40 0.78 J 1.8 0.79 J <0.40 <0.40 <0.40 Dry trans-1,2-Dichlor-then (-ylene) µg/l 1.0 0.40 100 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,2-Dichloropropane 99/1 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry cis-1,3-Dichloropropene (-propylene) µg/l 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry trans-1,3-Dichloropropene (-propylene) 99/1 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Ethylbenzene 99/1 1.0 0.40 600 <0.40 <0.40 <0.40 <0.40 1.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 2-Hexanone µg/l 10.0 2.0 40 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 Dry Iodomethane µg/l 5.0 0.40 NE <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Dichloromethane (Methylene chloride) µg" 1.0 0.40 5.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 2-Butanone (Methyl ethyl ketone) µg/l 10.0 2.0 4,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 Dry 4-Methyl-2-Pentanone pg/1 10.0 2.0 100 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 <.0 <2.0 Dry Styrene µg/l 1.0 0.41 70.0 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 Dry 1, 1, 1,2-Tetrachloroethane 99/1 1.0 0.40 1.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1, 1,2,2-Tetrachloroethane 99/1 1.0 0.40 0.2 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Tetrachloroethene (-ethylene) 99/1 1.0 0.40 0.7 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Toluene µg/l 1.0 0.40 600 <0.40 <0.40 <0.40 <0.40 0.84 J <0.40 0.42 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,1,1-Trichloroethane 119/1 1.0 0.40 200 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1, 1,2-Trichloroethane 99/1 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Trichloroethene (-ethylene) pg" 1.0 0.40 3.0 <0.40 <0.40 <0.40 0.61 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry Tdchlorofluoromethane µg/l 1.0 0.40 2,000 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,2,3-Trichloropropane 99/1 1.0 0.40 0.005 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 3.4 <0.40 3.2 <0.40 <0.40 <0.40 <0.40 Dry Vinyl acetate 99/1 5.0 1.2 88.0 (1) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Dry Vinyl chloride 119/1 1.0 0.40 0.03 5.1 <0.40 <0.40 2.4 0.40 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.57 J <0.40 <0.40 <0.40 <0.40 <0.40 1.3 1.2 <0.40 <0.40 <0.40 Dry Total Xylenes µg/l 1.0 0.40 500 <0.40 <0.40 0.69 J 10.40 2.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.65 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry 1,4-Dioxane 1 3.0 1.0 3.0 22 <1.0 87 15 5.6 86 41 6.4 NT <1.0 <1.0 <1.0 <1.0 <1.0 21 34 NT 21 53 31 66 1 39 <1.0 <1.0 NT Dry Diethylphthalate µg/1 4 0.5 6,000 NT <0.5 NT NT NT ND <0.5 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.5 <0.5 NT Dry Naphthalene µg/1 0.8 0.2 6 NT <0.2 NT NT NT NT <0.2 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.2 <0.2 NT Dry Other App. H Volatile Organic Compounds OC's Various Various Various Various NT ND NT NT NT ND ND NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT ND ND NT Dry gamma-BHC (Lindane) µg/1 0.040 0.017 0.03 NT <0.017 NT NT NT <0.017 <0.017 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.017 <0.017 NT Dry alpha-BHC µg/l 0.04 0.015 0.006 NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry beta-BHC µg/1 0.04 0.015 0.02 NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry cis -Chlordane µg/l 0.04 0.015 NE NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry trans -Chlordane µg/1 0.04 0.015 2 NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry 4,4'-DDE µg/l 0.04 0.020 NE NT <0.020 NT NT NT <0.020 <0.020 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.020 <0.020 NT Dry Endosulfan II pg/l 0.04 0.015 42 NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry Endrin aldehyde µg/l 0.04 0.015 2 NT <0.015 NT NT NT <0.015 <0.015 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.015 <0.015 NT Dry Other Or anochlorine Pesticides 1 Various Various Various NT ND NT NT NT ND ND NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT ND ND NT Dry Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENQ, Groundwater Classifications and Standards Section 15A NCAC 2L .0202. Updated April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quanlitation 7. DL = Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 10. "L"-flagged data denote LCS/LCSD failure. 11. "P"-flagged data denote RPD between two GC columns exceeds 40% 12. "Q"-flagged data denote surrogate failure 13. Appendix Il VOCs are only collected durign the fall sampling event 14175-07B GW Tables Prepared By: SG Table 5 VOC April 2023 Checked By: TAO Table 6 Groundwater Field Parameters and Total Metals Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Sampled by Pace Analytical Services, LLC. April 13 & 17, 2023 TEST UNITS LOQ DL MCL MW-B MW-2 MW-3 MW-4 MW4A MW-5 MW-6 MW-6-192 MW-7 MW-8 MW-12-25 MW-13-35 MW-13- 132 MW-15 MW-17-60 MW-17- 137 MW-17- 310 MW-18-78 MW-19-75 MW-19- 110 MW-21-21 MW-21-94 MW-23- 119 MW-2445 MW-24- 160 DPL-1 pH S.U. >6.5; <8.5 6.6 6.04 6.5 6.0 6.1 6.3 6.1 6.4 5.6 5.57 6.5 5.8 7.2 12.7 7.0 7.3 8.5 6.1 6.3 7.4 6.5 6.7 12.08 Dry 7.24 Dry Specific Conductance mmhos/cm NE 677 140 1,034 971 720 1,670 1,543 450.2 173.4 68.2 528.9 351.3 333.6 7,895 623 853 145.3 640 948 487.4 1,355 796 5112 Dry 199.4 Dry Temperature °C NE 15.2 17.0 16.4 17.3 20.3 25.5 15.9 20.9 29.7 14.8 18.5 20.8 20.8 15.6 21.2 15.0 12.3 15.0 16.7 16.6 19.6 18.6 15.1 Dry 16.8 Dry Turbidity NTU NE 8.9 9.92 4.9 1.6 4.4 4.2 0.8 1.8 5.8 6.03 6.1 2.6 4.9 2.3 1.6 0.5 3.3 3.0 0.3 0.5 27.1 0.4 7.12 Dry 96.18 Dry Dissolved Oxygen (DO) mg/L NE 0.2 2.41 0.7 0.8 3.9 2.1 0.5 0.8 0.5 211 3.2 4.3 0.5 6.0 0.6 0.4 0.4 0.8 0.3 0.4 0.3 0.3 0.90 Dry 0.17 Dry Redox mV NE -131.6 120.4 -70.0 -10.7 -86.1 27.3 -67.8 -95.2 35.2 159.6 81.3 199.5 192.9 -52.1 -81.0 -111.3 17.7 -140.7 -23.4 -105.4 -59 -70.8 122.0 Dry 23.8 Dry Total Antimony (Sb) µg/1 2.0 0.5 1.0 <0.50 <0.50 0.50 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.4 J Dry 0.57 J Dry Total Arsenic (As) µg/1 2.0 1.3 10 <1.30 <1.30 <1.30 <L30 <1.30 <1.30 <1.30 <L30 <1.30 <L30 <1.30 <1.30 <1.30 <1.30 <1.30 <L30 <1.30 <1.3 <1.30 <L30 <1.30 <1.30 <1.30 Dry <1.30 Dry Total Barium (Ba) µg/l 5.0 1.3 700 270 39 210 480 720 200 1,600 64 190 53 47 190 48 230 22 28 3.3 J 38 96 12 110 47 670 Dry 23 Dry Total Beryllium (Be) µg/1 0.40 0.15 4.0 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Dry 0.33 J Dry Total Cadmium (Cd) µg/l 0.50 0.13 2.0 <0.13 <0.13 <0.13 2.1 <0.1 <0.13 <0.13 <0.13 0.27 0.13 J 0.13 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.20 J <0.13 <0.13 <0.13 <0.13 <0.13 Dry <0.13 Dry Total Chromium (Cr) µg/l 5.0 1.3 10 30 16 <1.3 1.9 J <L3 <1.3 <1.3 <1.3 <L3 2.8 J 5.0 <L3 <1.3 14 <L3 <1.3 <L3 2.5 J 6.8 1.3 J 4.2 J <1.3 19 Dry 6.3 Dry Total Cobalt (Co) µg/l 5.0 1.3 1.0 <1.3 2.6 J 48 43 14 <L3 <1.3 150 <1.30 <L3 1.7 J <L3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 9.7 <1.3 1.5 J Dry <L3 Dry Total Copper (Cu) µg/1 5.0 1.3 1,000 <L3 9.0 <1.3 <1.30 4.3 J <L3 <1.30 <1.3 2.3 J 6.0 1.4 J <1.30 <1.30 <L3 <L3 <1.3 <L3 <1.3 <1.3 <1.3 <1.3 <1.3 1.8 J Dry 2.4 J Dry Total Lead (Pb) µg/l 1.0 0.25 15 <0.25 2.1 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 1.1 <0.25 <0.25 <0.25 1.5 <0.25 <0.25 0.30 J <0.25 <0.25 <0.25 <0.25 <0.25 0.70 J Dry 3.7 Dry Total Mercury (Hg) µg/l 0.20 0.091 1.0 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dry NT Dry Total Nickel (Ni) µg/l 5.0 1.3 100 15 18 34 72 7.3 29 11 1.3 J 39 3.4 J 19 5.0 <1.3 <1.3 1.3 J <1.3 <1.3 3.4 J 20 4.6 J 4.9 J 6.9 2.7 J Dry 8.1 Dry Total Selenium (Se) µg/l 5.0 1.3 20 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <L3 <1.3 <L3 <1.3 <1.3 <1.3 <1.3 Dry <1.3 Dry Total Silver (Ag) µg/l 1.0 0.25 20 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.44 J <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Dry <0.3 Dry Total Thallium (TI) µg/l 0.50 0.15 2 <0.2 <0.2 <0.2 0.16 J <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.22 J <0.2 <0.2 <0.2 <0.2 <0.2 Dry <0.2 Dry Total Tin (Sn) µg/l 20 5.0 2,000 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dry NT Dry Total Vanadium (V) µg/l 5.0 2.5 7 <2.5 3.9 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 3.8 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Dry <2.5 Dry Total Zinc Zn 1 10 2.5 1,000 <2.5 9.2 J <2.5 15 3.5 J 2.9 J 2.8 J <2.5 8.8 J 14 11 6.3 J 3.9 J 3.7 J <2.5 1 <2.5 3.1 J <2.5 6.6 J 2.7 J <2.5 <2.5 <2.5 Dry 19 Dry Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDEQ, Groundwater Classifications and Standards Section 15A NCAC 2L .0202. Updated April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ -Limit of Quantitation 7. DL -Detection Limit 8. NT -Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 14175-07B GW Tables Table 6 Metals April 2023 Prepared By: SG Checked By: TAO Table 7 Surface Water VOCs Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Sampled by Pace Analytical Services, LLC. April 13, 2023 TEST UNITS LOQ DL NC2B SW-1 SW-2 SW-2A SW-3 SW-4 SW-10 Acetone µg/l 20 5.0 2,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Acrylonitrile µg/l 20 0.80 420 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/l 1.0 0.40 51 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochloromethane µM 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µM 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µM 1.0 0.40 120 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 1.0 0.40 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µM 2.0 0.40 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µM 1.0 0.40 1.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µM 1.0 0.40 800 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µM 2.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µM 1.0 0.40 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µM 1.0 0.50 96 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µM 1.0 0.40 21 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µM 1.0 0.40 0.13 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µM 1.0 0.40 0.1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µM 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µg/l 1.0 0.40 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µM 1.0 0.40 900 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene µM 2.0 0.50 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane µM 1.0 0.40 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane µM 1.0 0.40 650 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene (-ethylene) µM 1.0 0.40 20,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µM 1.0 0.40 720 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µM 1.0 0.40 4,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/l 1.0 0.40 31.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µM 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µM 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µM 1.0 0.40 97 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone µM 10 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane µg/l 5.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/l 1.0 0.40 1,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/l 10 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µg/l 10 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/l 1.0 0.41 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroethane µg/l 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2,2-Tetrachloroethane µg/l 1.0 0.40 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/l 1.0 0.40 3.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/l 1.0 0.40 11 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1 -Trichloroethane µg/l 1.0 0.40 200,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/l 1.0 0.40 8.9 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µg/l 1.0 0.40 30 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg/l 1.0 0.40 67,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/l 1.0 0.40 0.001 <0.4 <0.4 <0.4 <0.4 3.1 <0.4 Vinyl acetate µg/l 5.0 1.2 NE <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µg/l 1.0 0.40 2.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Total Xylenes µg/l 1.0 0.40 670 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-dioxane 1 3.0 1.0 80 NT NT 7.8 32 35 1.0 J Notes: NC2B - North Carolina Surface Water Standards for Class B freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-21) NE - Not Established; North Carolina has not established a MCL NT = Not Tested DL = Detection Limit LOQ = Limit of Quantitation "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. Shaded cells indicated exceedances of NC2B Surface Water Standards 14175-07B SW Tables Prepared By: SG Table 7 SW VOC (4-13-23) Checked By: TAO Table 8 Surface Water Field Parameters and Total Metals Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-07 Sampled by Pace Analytical Services, LLC. April 13, 2023 TEST UNITS LOQ DL NC211 SW-1 NC211 SW-2 NC211 SW-2A NC211 SW-3 NC211 SW4 NC211 SW-10 PH S.U. (on -site) <6.0; >9.0 6.74 <6.0; >9.0 6.61 <6.0; >9.0 7.18 <6.0; >9.0 7.72 <6.0; >9.0 7.73 <6.0; >9.0 6.21 Specific Conductance µmhos/cm (on -site) NE 42.3 NE 51.1 NE 302.40 NE 535.1 NE 1036 NE 53 Temperature °C (on -site) 29.0 14.6 29.0 13.3 29.0 10.8 29.0 15.4 29.0 17.4 29.0 12.7 Turbidity NTU (on -site) 50.0 10.83 50.0 8.64 50.0 6.88 50.0 6.26 50.0 15.2 50.0 51.96 Hardness mg/L 10 2.0 NE ND NE NT NE NT NE NT NE NT NE NT Dissolved Oxygen mg/L - - <4.0 9.27 <4.0 8.48 <4.0 8.03 <4.0 8.03 <4.0 6 <4.0 <4.0 Redox mV - - NE 96.2 NE 74.1 NE 90.3 NE 49.5 NE 80 NE NE Total Antimony (Sb) µg/1 2.0 0.50 640 <0.50 640 <0.50 640 <0.50 640 1.11 640 <0.50 640 <0.50 Total Arsenic (As) µO 2.0 1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 Total Barium (Ba) µg/1 5.0 1.3 21,000 16 21,000 15 21,000 33 21,000 110 21,000 71 21,000 67 Total Beryllium (Be) µO 0.40 0.15 65.0 <0.15 65.0 <0.15 65.0 <0.15 65.0 <0.15 65.0 <0.15 65.0 <0.15 Total Cadmium (Cd) µg/1 0.50 0.13 0.43 <0.13 0.43 <0.13 2.98 <0.13 4.35 <0.13 8.95 <0.13 0.82 <0.13 Total Chromium (Cr) µO 5.0 1.3 100.36 <1.3 100.36 <1.3 616.02 <1.3 879.9 <1.3 1736.91 <1.3 183.07 <1.3 Total Cobalt (Co) µg/1 5.0 1.3 4.0 <1.3 4.0 <1.3 4.0 <1.3 4.0 2.6 J 4.0 1.8 J 4.0 <1.3 Total Copper (Cal µg/I 5.0 1.3 1.82 <1.3 1.82 <1.3 14.7 <1.3 22.16 <1.3 48.45 <1.3 3.64 1.6 J Total Lead (Pb) µg/1 1.0 0.25 6.04 0.49 J 6.04 0.47 J 71.63 <0.25 114.5 <0.25 273.64 <0.25 13.88 0.43 J Total Mercury (Hg) µg/I NT NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT Total Nickel (Ni) µg/1 5.0 1.3 77.88 <1.3 77.88 <1.3 507.55 1.8 J 733.54 4.2 J 1480.83 15 144.92 <1.3 Total Selenium (Se) µg/l 5.0 1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 Total Silver (Ag) µg/1 1.0 0.25 0.08 <0.25 0.08 <0.25 3.79 <0.25 8.01 <0.25 33.42 <0.25 0.30 <0.25 Total Thallium (TI) µg/l 0.5 0.15 2.0 <0.15 2.0 <0.15 2.0 <0.15 2.0 <0.15 2.0 <0.15 2.0 <0.15 Total Vanadium (V) µg/1 5.0 2.5 NE <2.5 NE <2.5 NE <2.5 NE <2.5 NE <2.5 NE <2.5 Total Zinc Zn 10 2.5 19.44 3.7 J 19.44 5.2 J 127.04 <2.5 183.7 <2.5 371.25 <2.5 36.20 8.6 J Notes: NC213 = North Carolina Surface Water Standards for Class B freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-2021) Measured values of hardness were utilized to calculate an acute standard at each surface water location (excluding SW-10) for metals highlighted in green. Hardness values were reported in Report of Water Quality Sampling and Analysis 1st Semi -Annual Event 2020 prepared by BLE, dated July 14, 2020 A hardness value of 25 mg/l was used to calculate the acute standards at SW-10 for metals highlighted in gree. NE = Not Established; North Carolina has not established a standard "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. Shaded cells indicated exceedances ofNC213 Surface Water Standards DL = Detection Limit LOQ = Limit of Quantitation NT = Not Tested DNA = Data Not Available 14175-07B SW Tables Table 8 SW Metals (4-13-23) Prepared By: SG Checked By: TAO FIGURES OLD, Q 25 .� 70 `7 � kl=Nmo�� o� < ODFIN rJ -UVLfASANT HQp d 251 % 4 Ashelawn Gardens ; of Memory Memorial Garden I Bus �'+°ench 6roac; �z000 �� --'-,---+---Olivette-Cem--i--�T, 19 S i i r 3 Av000 �o� --7 1 Z� �� ti�U w QOI J� �n0 �4�R0 AL7URq ploy C�Q P� Old �Macedoniia Gem\I J gUD000 DR 3 Jilt � a SSUODFIiN "a p a - ti10 o_ 13eave,� Milk, Moul EFERENCES: �- `USGS TOPOGRAPHIC MAP, 7.5 2000 1000 0 2000 4000 i MINUTE SERIES, WEAVERVILLE AND APPROXIMATE SCALE IN FEET LEICESTER. INC. QUADRANGLE 2019 DRAWN' KLW DATE. 3-9-23 FIGURE BUNNELL LAMMONS SITE LOCATION MAP � CHECKED: ZJD CAD: BCOLF07-SLM ENGINEERING CLOSED BUNCOMBE COUNTY LANDFILL 6004 Ponders Court, Greenville, SC 29615 WOODFIN, NORTH CAROLINA 1 APPROVED: AWA JOB NO: J22-14175-07 Phone: (864) 288-1265 Fax: (864) 288-4430 SW-1 A A10000 -ftN*40 0)0; — ao ACTIVE MONITORING WELLS INACTIVE MONITORING WELLS ABANDONED MONITORING WELLS ACTIVE SURFACE WATER SAMPLING LOCATIONS INACTIVE SURFACE WATER SAMPLING LOCATIONS MW-2 MW-12-10 MW-9 SW-1 SW-5 MW-3 MW-13-10 MW-10 SW-2 SW-6 MW-4 MW-14 MW-16 SW-3 SW-7 MW-4A MW-18-3 MW-17 SW-4 SW-8 MW-5 MW-19-4 DPL-2 SW-2A SW-9 MW-6 MW-20-3 SW-10 MW-6-192 MW-20-32 MW-7 MW-21-4 MW-8 MW-22-78 MW-12-25 MW-22-143 MW-13-35 MW-23-186 MW-13-132 MW-A MW-15 MW-17-60 MW-17-137 M W-17-310 MW-18-78 M W-19-75 MW-19-110 MW-21-21 M W-21-94 M W-23-119 M W-24-45 MW-24-160 DPL-1 MW-B NOTE: ACTIVE SAMPLING MONITORING WELLS AND SURFACE LOCATIONS ARE TO BE SAMPLED AND TESTED TWICE ANNUALLY. INACTIVE MONITORING WELLS ARE TO BE CHECKED FOR DEPTH TO GROUNDWATER ONLY. *WELL NOT USED FOR CONTOURING PURPOSES. NM - NOT MEASURED MW-2® ACTIVE GROUNDWATER MONITORING WELL MW-14® INACTIVE GROUNDWATER MONITORING WELL MW-9 ABANDONED GROUNDWATER MONITORING WELL SW-1- ACTIVE SURFACE WATER MONITORING LOCATION SW-54 INACTIVE SURFACE WATER MONITORING LOCATION PROPERTY BOUNDARY SURFACE WATER POTENTIOMETRIC CONTOUR :TION CONTOUR INTERVAL = 20 FEET ED BY GROUNDWATER FLOW DIRECTION WATER S LAN D TOPOGRAPHIC SURFACE CONTOUR IN FEET ABOVE MSL CONTOUR INTERVAL = 10 FEET 250 125 0 250 500 APPROXIMATE SCALE IN FEET REVISIONS No. DESCRIPTION BY DRAWN: KLW CHECKED: TAO APPROVED: RLB/AWA DATE: 8-16-23 CAD FILE: BCOLF-07POT041323 JOB NO: J22-14175-07 � LAMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fax: (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP — APRIL 12-13, 2023 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. Document Name: Field data Shaul Date Issued: March 9, 2019 CAfi<71yf1Ca/ ---- Page: 1 of J Document Number F-CAR-ET.D-0Ol-rev.03 - Issubig Authority: Pace Huntersville Quality Office Field Data Sheet Client: GLE Location: Woos. ft �_T}�!Project#: &LA (� Name and Affiliation (Sampler(s): OCA —Vd-O Field Data Sheet Review: Name and Affiliation (Inspector): Date: By: Well Information Well ID:Well Locked: YE / NO / Flushmount ) Well Diameter: Construction: O/Steel/Stainless Steel) Total Well Depth: QR(0. 05 ft MultiFactor*. Q> 03 r(ttadius/12)2x3.t4x7a8l Static Water Level: Wt.)A ft Casing Volume 6 ( gallons Height of Water Column: b - ', ft COL 3 Volumes: 0. 2) gallons Pump hntake: ft Purge Information Date Purged: Start : Finish, — Purge Rate: Purging Method: Total Volume Purged: (gallons/mis/L) - Sampling Information Date Collected: —�—� Time Collected;— - (am/pm) Sampling Equipment Used: Instrument ID: Bottle Type PreservationAnalysis Required Field Measurements/Observations e-I emp ime* __ ur r ity (ntu): line: Diss Oxy (mg/L) Time: Fe 2+ Specific Cond. (uS): Time; Res. CI (mg/L)/(µg/L): Time: Sample pH (sit.); - _ imea ReDox (mV): Time: Appearance: Time: Sampler Signature._ Stabilization Test 'V tAAC3. 1 HILU; i r,t 4t1-i" VDitAA�Q non /cloudy/rairry)Temp._(*F) Wind L:5 (n ph) Date: 11tl '' 13/a3 Time Purged Temp. (C) Diss Oxy. (mg/L) Spec Cond. (us) pH (s.u.) ReDox (mV) Turbidity Volume ved (gallons/mis/ L Water level (ft) Other Document Nanic Field data Sheet Date Issued.` March 8, 2019 ?C0 ArhllyfiC,II Page: 1 of a�- Dmumem Number. F•CAR-rl D-001-mv.0.3 Issuhig Authority: Pace FIuntersville Quality office Field Data Sheet ClIient,-(`,C-L Location: AS>Nt- Project #: cl oS� -t:.w� L c- Nance and Affiliation {Sampler(s): .A vl - P° Lc Field Data Sheet Review: Name and Affiliation (Inspector):_ IJ IL `1- i'i - z 3 M /L Well Information Date: l••4J�.11b''a By. NKa Well ID; Well Locked: { YY b f NO / Flushmount ) Well Diameter: vl Construction: ( C/Steel/Stairdess Steel) - Total Well Depth: ft MultiFactor*:; C)• I ["(Radius/12)2 x 3.11 x 7.481 Static Water Level:_ 3.CU ft Casing Vol me J.X gallons v9�/=, Height of Water Column, ' � fE Cal.3 Volumes: Gygallons of I2/aj Pump Intake: ^ ,i ft Purge Information Date Purged: Ll / V 3 / 2 5p Start, 0'5 U F'inishk ) o �O Purge Rate: /00-,c ^- P M h dpp • E' L IL urging eto �3r. ,n� TotalVolume Purged: IoD000 (gallons/ri /L) Sampling Information Date Collected: c) / / J 3 Time Collected, C Sampling Equipment Used: R) ;II,Z s�< Instrument ID: S' 075'I I VWrT 6C)=l Bottle Type 0) O) Field .Measurement sJQbservations Preservation I-/NU3 LIB � UCI Analysis Required LLI - � Sample Temp (°C): ) S . i Time:. I0 3 � 4 Turbidity (ntu): 6 c f Time; /U ) S- Diss Oxy (mg/L): O, i_ Time: Fe 2+ mg/L; /Jf,) Tune: J 0 3 S SpecificOond. (uS): 6 T -I Time: Res. CI (mg/Ly(gg/L): r Time: Sample pH (s.u.), G t Time: Odor:_._ �,u c,• _Time:.._�C75 ReDox (mV): Tiuiea __ C..�e-v—� pP 'time: _ . 10 35 _Appearance:— ReDox (EH value):YSI ProPlus+200mV G •`I Other: Time: — General/Weather Observations: Sampler Signature: Stabilization Teat 5 Wind '_(mph) Time Temp, , Diss Oxy. Spec. pH (s.u) ReDox Turbidity VO Ume removed Water Purged' (°C) (mg/L) (US)Cond „ {mV) (ntu) (gatlonsf�i l level (ft) Other L "S 3 s )c)) c i Si5o P 1i.3 c.s _ gekA `eArk7tytical _ Docu nt Name: Field Data Sheet Doa n=ent Issued: Marcia 8, 2019 Pagetof )- Dc,cument Nunihur: Issuehig Authority: F-CAR-FLD-001.rev.03. Pace Hwttersville Quality Office �y� Weti Diameter :Multiplication Factor' Client; @ 1L % 1 0.0408 Location: Iney,`I( I /yL- 1.2 0.0918 1.b25 01080 Project: C l�7 7 Ja cv 42 l 2 0.1630 Well ID: w , 3 0.3670 4 06530 Reviewed Date and By: 1 Id 23'' pnL= 6 1.4680 Stabilization Test 8 2.6100 Time Purged g Temp. a (G) Diss Oxy. (mg/L) Spec. Card: (US) pH (s;u.) ReDax (mV) Turbidity (ntu} Volume Re owed (gallons mi /L) circle one Water level {0) Other. 0c, 3c7ozi , I� cy;3o ©,-( 1 g000 e' 2`I - G1t) ^UcC� r1,1(� C�91 -N'.0 1S• �,COc) �9.G� filxi 11-I.1 0.9 G93 6,4 ' -))e,.5 )0ic7 1-I.Ll (0.j �7�`(I �.�' -, C. 6 W i �Ud� Iv.lS 0)C) ICI4s 0 j 6s1, GG 1 13-)L ('1 cw lots - 1Q�U h,I in l I Ci'I -130 I �_ PGc"(-)o 7S _ Document Name. Field data Sheet Date Issued: March S, 2019. }� ,e, 1 of z o7C@AtkllytiCa/ . Document Number. F-CAR-Pl.17-001-rev.OS Issuhig Authority: Pace Huntenville Quality _- P Office lient: N L Local l,Project #: M S Name and Affiliation (Sampler(s): /'?/'1 An .- Field Data Sheet Review: Name and Affiliation (Inspector): _ eL"a��3 V' Well Information Date: 1 I� I 1 By. Well ID: - /In 61 . t Well Locked: A / NO / Flushmount ) Well Diameter: Construction: INFO Steel) Total Well Depth: ) 7 61 it Multi Factor*: ' % 6 5 ('(Radius/ 12)2 x3.14 x z as] Static Water Level: /09, %`I ft Casing Volume )0, 3 /l3 P gallons Height of Water Column: (,3, > 1 ft Cal. 3 Volumes-.3 gallons 34-y,,,j Pure Information : Pump Intakeft w l d ;✓o j b.fl ✓rt TH�2 Date Purged: +/ 1% / Start: 1100 Finish: ) 310 Purge Rate: l'0 '%� 11 ,./ Purging Method: MO r✓f o o / Total Volume Purged: / 0 000 (gallons/ n// / L) Sampling Information Date Collected:_L-4 j t� /e- 3 Time Collected: 6 1J!:�_ (am/pm) Sampling Equipment Used: JLIo,✓loon/ InstrumentID: `9 S ::/�' OAJS /%// Bottle Type Preservation Analysis Required N44 5 --L /f _ C L 1/0 L 3 ✓,A� t N cL i ' J�t o)C,g.6i Field Measurenrents/Observations Sample Temp ('C): 17o Time: tJZ�__Ttubidify(ntu): q• Time: 0 DissOxy'(mg/L): -1H Time; )32r Fe2+mg/L �Tin2e Specific Cond. (uS): Time: 8 2; Res. Ct (ntg/L)/(µg/L): .rime: Sample pFl (s.u.): _6_� Time: i i -,- Odor: I%Dox (ntV)c 04 Lf Time: Appearance: LI 9_,2 Time: 1.37�- ReDox (EH value):YSI ProPlus +200mV 3 A 0,iL Other: Tmie General/WeatherObservations: Srr W 4 n /cloudy/rainy) Temp. O (°F) Wind 0-1.1 (mph) s Sampler Signature: I? c _ n l _Date: 4 7 , d ! Stabilization Test Spec. Volume Time Temp. o Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (Ing/L) (us) (mV) (ntu) (gallons/mis/ level (it) L 1110 i, r<? I f1.C7 s",9'f a$s- �s.I C)03 llLta ii�b i4 a 57 )'fL� 6,0 83.S 13.3,�v 3000 IYV,s�' 6,0 'F fY:4- II7. S' 1 l4poo Illalso Il4v Ir,s ,it 1�ZI 6•0s— L,13,0 1 log.7 I S000 Ild,iv P v,-,e IJ! ✓,5J Ip ) l.rD #,. ,o % 4, J 4 2 fQ 12,40 Document N me: Document Iasaed: IITncember 27, 2018 > �,� Field Data sheet page%ef _ r . n wai: Document Number: Issuelng Authority: F-CAR-FLD-OO1.rev.02 Pace Hwtersvffie Quality Office f.� w •J- `i-1 -7 Client: Location: � }fnW[. s OAZ d 4 Project: ' / 1 J,/ J Well ID: Reviewed Date and By: Stabilization Test NA aE �b Tift'e17.�isbs "Ml�ftl�,a4.�a��a�ar". 4 i ..EE gg����yy .L`h+M - L'IM �. Time purged Temp. o (C} DissOxy. (mg/0) Spec. . Cond. (us) p(s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons I circle Waterlevel (tt} Other oo, Iyss? rs:9 JZ,G 7001 Js 1b,I a.tL Jq- 6,06 1/0, 1 z�r.Z/ �.i aJ h,LF d 4s Mf �,,t riz,— 6, b i d J J /x so it / 6 0 �` I>G,�__ IIf 6 0-) TIk',,) 111 1 1.L" 900J 4) 31� 1�, 5 1 q6- 6,Jz. 115.7 0,Z `>J Cad, .I��.......__ S 1) 11( 4l(31z3 DalL Issued: March $12019 Document Naml I iakl data Sheet ' Peke: I of tssuutll Authority Pane Huntwsville Quality C Analytical Document Numbor:I C'AR-Fl..D-001-rev,Q3 Office Field Data Sheet Name and Affiliation (Sampler(s):- IaLt% A6P_ - Name and Affiliation (Inspector): Well Information Well 1D; _.. Pl/� ([4/ Well Diameter; Total Well Depth; (000 ft Static Water Level: ._-_ft Height of Water Column:_ ,2,Z, �qft Well Locked: Construction: IField Data -Sheet Review: FIIM I i-I /IH Iz3 Date:QtlllfIIV,� By:/�._� Steel) Multi ltactOY*:a LO [�(Raetius(72)2 x'y.Z4 x 7.g8] Casing Volume: 'a (:SAgallons Cal.3 Volumes:. tp o?') gallons Pumpintake: 'F,�-k/- ft Puree Information _ j �• Date Pm ed 3 `2`�r �__ Finch; U I Purge Rate: - j1[](�j ��ul, i°A ge .-./_ l . -/...- -.- _.. Start :- Purging Method:_ _C �.-- eg . Total Volume Purged: �yU(gallons/r it /L) Santp_lirm Information. DateCollectetj:�/_/ A3 Time Collected:_ (am/&i Sampling Equipment Used: R tc&� %P i instrument ID;T�5�� �- � � � � ��` � Bottle'rype _ . Field MeasurementalObservations Preservation -----------� .... Sample'renip Diss Oxy (mg/L); Dp �t'Time; Specific Cond. (as): —f v •,1%._ Tune: Sample pH (s.u.):..j�.5 Time: .----_..- ReDox (mV); Tune: ReDox (EH value):YSI ProPlus +200niV_13_� General/Weather Analysis Required if Ic�� `turbidity (ntu): _I Time; j—U 2+ me/ L: Time: Res. Ci (mg'/L)/(lig/L): �Tirne:. Odor:___ N O _._ :Tune; 16kO Appearance: ((-Pr h Time; l('SU Other; Time: (sumry/cloudy/may) Temp7��('F) WhtdC)•-5(mph) Sampler Signature:Date: Stabilization Test I'[me Purged Temp. Disc Dxy. Spec. Cored. pH (s.u.) ReDox Turbidity (ntu) o uine removed (gallons/r(FY Water level(ft) Other (C) (mg/L) (Its)(nV) 0 0("01 1622 G _ , ,) 7,0 Olaf )021 1 7 Gam, °`_ 7 Gf 0 3 III Lr -6 9 9 c� �- 7 G Q1 y -7 d o 1IS'lli-10315 z©C'G 1 If Dcxument Name. Field data Sheet ' pale Issued: March 9, 2619Ar aceN><7tytica!" Page: 1 of t rJocumentNunilr,F•CARFLi-0Ol-eeuQ3 Issuing Authority: Pace Htuttersville Quality e_ t Office 1Project #: Iftt �0. C�4b2� L;-YJ)7J Name and Affiliak on (Sampler(s): )�nNYUn - Pav Field Dat:Sheet Review: Name and Affiliation (Inspector): �—" 3y:Well InformationDate: 3 RMs Well IDi Itbli(1� Well Locked: YE / NO j Flushrnount) Well Diameter: `t Construction: (zV f Sfeelf Stainless Steel} Total Well Depth; 7(D•-5 It Multi Factor*; 61t`03 r(Radius/12)2x3,14x7A8l Static Water Level �d. ft Casing Volume: 0--7 gallons Height of Water Column: i�•�� ft Cal.3 Volumes: a. l gallons Pump Intake: `�_iA+(' ft Pure Information Date Purged: t of � d2% Start : � Y✓ Finish 1Nl 00 Purge Rate: U,11`� Purging Method: i"�R Total Volume Purged: __( (gallons/,®/ L) Sampling Information j(05 N((,ntj/t3/)3 DateColjected:4,__f{ �l (l��,, Time Collected:,�.___0/pm) 'y tdYu�Pi 11 Instrument ID:_ YS��Oq Ltc � �y2bJ Sampling Equipment Used: L Bottle Type Preservation Analysis Required l' 45D 01, aca� c 111�0� �itea� is 6-gP`a J clef A(A- 46C Field Measurements/Observations Sample Temp(°C); l Time:---jj6,5.._._Tmbidity(ntu): i,lQ Time; 1(4� DissOxy(mg/L): 09 Time: YAL(5 Fe2+mg/L; —Time: Specific Cond. (uS); Time: lWIS Res. CI (lsigjL)f(µgfL): V-PTime, : Sample pH (s ix.): _... ,Time: (�� Odor:_._ ^Time 05 ReDox(mV): 't(7.1 Time:Appearance: ClZ�r- linte: M5 ReDox (EH value):YST ProPlus +200mV AZ4.� Other: Time: Time Purged Temp. a { C) Diss Oxy. (mg/h) Spec. Cond. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gaitons tlfsf L Water 1QVe1(ft) Other D l'►_o D3 q (gi w..0 ouf ao Ltd Cl(9 (0_0 t1,' l l l y q 1,0 , Document Name: Field data Sheet Date Issued: March S, 2ing aCCMk7tyl/Ca1.. Page: 1of3 Document Number: F CAR-FCA-001-rev.03 Issuing:Autharitp Pace kuntereville neet r ilaC Project#• C(s Name and Affiliation (Sampler(s):.ALM-{)cam Field Data Sheet Revie Date: Name and Affiliation (Inspector): N I/a 4 •1 Y - a Z 3 WeII Information al )3 Well ID: Mw ``I A Well Locked! / NO / Flushmount, Quality Well Diameter:- I" Construction: {P /Steel/Stainless Steel) Total Well Depth: - CU it Multi Factor*:0.161 1*(Radius/12)2xs14x7.481 Static Water Level; AO.50 ft Casing Volume: U gallons Height of Water Column; . ft Cal. 3 Volumes:...& gallons Pump Intake: 1` �S ft Purge Information Date Purged; �1 ;;f 13 / t3 Start: iUuU_Finish: �yaS Purge Rate: I�tiS vhh Purging MethodTotal Volume Purged: (gallons) ril Sampling Information Date Collected: " / i J / -)-3 Time Collected; Sampling Equipment Used: &MUtf LIP InstrumentID:_YST14-633` 'jpX'JT1Go'1')- Bottle Type Preservation Analysis Required C 1) a s�^ Pl��t z j 1tic�� V oC �a ti c (rlo s IAC 1 IfHA it Field Measurements/Observations Sample Temp CC):_ ZrJ_ _T me: ICI '2' 0 Turbidityntu ; L L ( ) Time; Diss Oxy {mgJL}: Time: L Fe 2+ tug/L; p I) Time., . I�I�O Specific Cond. (uS):Time: Res. Cl Sample PH (s.u.): C Time: v" c Tin e: i�i')U ±- ReDox (mv) dt l Time; Appearance: 00w ' ,gI 0 - pP Time: l � ReDox (EH value);YSi ProPlus +2OOmV 33 'l Other: - Time: General/Weather Observations: Sampler Signature:�� a - Stabilization Test i I1 Wind y (mph) Time Temp. Diss Oxy: Spec, pH (s.u.) ReDox Turbidity o nme removed Water Purged (IC) (mg/1.) (US) u5) (mV) (ntu) (gallons/Vjn s/ level (£t) Other L CIO ' lu:°I �9 4J�El Jlq l 1 ? 5-0 J �c1.Ga 1 I`1i5 .0 y.O (.1)C1 10 - T)-`f (, L) LS�C1 G.1 O � - �<--I s-v 1 I.v .,).t �) (>' 1 u--).0 �j,') a--wu U — Document Nome: Field data Sheet I Date issued: March 8, FR19 I Page: 1 of t eAnalylicat Document Number F CAR-FLD-001-rev.03 Issuing Authority Oceee untersville Quality r Qn, 11�� Field Data Sheet CIient: LfLo ation: i-JO04 t�Y C Profect#: AL.U. Name and Affiliation (Sampler(s): T — Field Data Sheet Review: Name and Affiliation (Inspector): �/hI /?-3 bN�1 Date: By: Well Information ou it k (13 &Is - Well ID:IAVitl- 5 Well Locked: E / NO / Flushmount ) Well Diameter: 4u Construction: (V/Steet/StalnlessSteel,) Total Well Depth: zo,a' It Multl Factor*: 6 A05 r(Radius/12)2 x 3.l4 x 9,4s1 Static Water Level: c�--�ft Casing Volume: y gallons Height of Water Column: It Cal, 3 Volumes: gallons Pump Intake: 60` 1_ ft Purge Information f qJ S p Date Purged:�J (yJ /_4}'a_ Start :_1Finish: Purge Rate:_ 1�M 1 N utli/a3 Purging Method: RCCA& Total Volume Purged: 05LZ (gallons&/L): t,N- SampingInformation14)0 L013P3 Date Collected:U/d(� Sampling Equipment Used:— , EkO IV InstrmentID `a/JW W C? Bottle Type Preservation Analysis Required �- IL cow,( 0Var.5-- kerb: 4- a50A amw cu6r;' St craps `t'CP /Svoc' Field Measurenxents/O!bbseervatations Sample Temp (°C):Time: �L�t�. _Turbidity (ntu): Time; Diss Oxy (mg/L): Time. _I_r D — Fe 2+ mg/L: —^ Thee: Specific Cond. (uS): WO Time: H� Res. Cl (mg/L)/(ltg/L): 'rune: Sample pH (s,u.): l Time: ILbU Odor:_-._ 1tkTime: ReDox (mV): C Time: k��ab AppearanceG)�lCW.:G] a5'I'ime: Hh ReDox (EH value):YSI ProPlusQ,+200nzV 22 Other: Tinie: Stabilization Test Time Temp. Diss Oxy. Spec Cond. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged � (C) (mg/I) (US) (mV) (ntu) (gallo m level (it) L CIv�/ ��/ v .pOt-Yj .• I .1— 6/ItWlyl Date Issued: March S, 20t4 Page: t of I g Authority: Pace Huntersville Quality Office Name and Affiliation (Sampler(s): Field Data Sheet Review: Name; and Affiliation (Inspector): Li. Iq;23 y��� IvJy Well Information Date: By: Well ID' ��L 1- � Well Locked: NO / Flushmount) Well Diameter: Construction: (I6/5teetJSEainless Steel) Total Well Depth: Ft Multi Factor*; • ((� -3 [ (Radius/12)2 x 114 x 7 49, Document -Name: Field data Sheet Dmument Number. F CAR F[D-001-mv.03 lss"ol Field Data Sheet air._ ,H Static Water Level: (2- C) t Casing Volume: C, } fS gallons Height of Water Column: '-I It Cal. 3 Volumes: J-0 �`i gallons Pump Intake: S ft Purge Information Date Purged: CI / i� )-Start: 10'- Finish: 16yy Purge Rate: f 0Oro L u" - Purging Method: l�en3 lhz �4 g"yg �� fSUC) ) Total Volume Purged: (gallons/ 1i /L SamPlingInformation Date Collected: �-( / i 3 / 13 Time Collected: I G S . __ (am/ m) Sampling Equipment Used: 1 vj-)2'�-1 }'z i"�f Instrument ID: Y S < 0 0374 Bottle Type Preservation Analysis Required ll� )LsU�(- � _ H[,sv (c 1 c/o,,(- ikCc -T-_6 SQ ok- Cy.,) Field Measurement JObservations Sample Temp (°C): )s . � Time: � y. Turbidity (ntu): Time: (G c-i S Diss Oxy (mg/L): O . S Time: Fe 2+ mg/L: I c° Time: 6 y Specific'Cond. (uS): )� '(3 Time: Res. Cl (ing/L)J(µg/L): — 'rime: Sample pFI (s.u.): • )_ , _Time: , Odor:_ ✓w Time: ReDox (mV): Time; �... Appearance.. f e r Tune: ReDox (EH value):YSI ProPlus+200mV j4Y . -) Other: - Time: — Temp, 3 O .(OF) Sampler Signature Stabilization Test Time Temp. Diss Oxy. Spec. pH (s.u.) ReDox Turbidity o ume removed Water Purged (°C) (mgJl J (US) (mV) (rttu) (gallons/tly/ level (ft) Other L 15-Lrl, to _ I OSoo �u GCS S C7. IS�i� IC) oe�0S- t Document Name: Field data Sheet Date Issued: March &, 201 /eArkMytiC1/ Pa DUrument Number. F-CAR-ri.D-0pl-rev.03 lxsumg Agfharity: Pare Huntersvil Office Field Data SheeE Client: ULL' Location: % �c.�.iCe /�i Project# C la / o y� Name and Affiliation (Sampler(s):U" - Pe'- F LID)ate: taSheet Review: Name,and Affiliation (Inspector): Q j� Y • 1N -z3Well InformationLi Id i l � By: �a Well ID: /tiw - 1 I Well Locked: / NO / Flushznount ) Well Diameter: Construction: (e_W/Steel/Stainless Steel) Total Well Depth: i l . '� 5 €t Multi Factor*:()lG 3 r(aadiva/12)2 x 3:Y4 x 7:asj Static Water Level' J . u ft Casing Volume:.. 2 I •Oi gallons A"' Height of Water Column: S fE Cal. 3 Volumes: I 1'.(J 1 gallons t-1 i 131a3 Pump Intake: ft Puree Information: Date Purged:_ jl _/ 15 f l Start. 'S 3S` Finish: Purge Rate:�- ' ;c 11-1-1 Purging Method: " P U C 3���� t't"� Total Volume Purged: Sampling Information Date Collected: )o �—_/ / _ Time Collected: I V-; - (am/ 1 j}) Sampling Equipment Used: Qc r 37-t4vt (cwP Instrument ID: �5r�()31`I �{{V°w Bottle Type Preservation Analysis Required C31 zsv 6 t )ice U M (UM �< Li,c _ .... B) '(o�c 1,c1-A Field MeasurementalObservations Sample Temp (,q: O rl Time:. 1(P U O _ Turbidity (ntu): Time: ) C 0 0 Piss Oxy (mg/L): A Time: Fe 2+ mg/Lc Time: (G G 0 Specific Cond, (uS): 1 jSt Time: Res. Cl zit L L ( g/ )&g/) lime: -- Sample pH (s.u,)a (o •�i^_ -Time: Odor:-._ ReDox mV; (- ) -°IS 2_ Time: Appearance: dea�� Time: lGoo ReDox (EH value):YSI ProPlus +200ruV y 5 Other: -- Time: Wind---� —_(mph) Sampler Signature Stabilization TeAt Time Purged Temp: CC) Diss Oxy: Spec. Cond. pH(au.)allows Vo ume removed Water (mg/I) (us) ;ReDoxZTurbidity (g /�n1s/ level (ft)15i3j Other f`i G ti SZ � -XOU ict 55LJ 0' `-1e1a.6 G cl •- Y i5 �.`6 ""0')- I G-A I -`7)Q i• l �_ ys-0 15ilc j�i�dceAnatytrcal. Document Name: Field data Sheet. Document Number F-CAR-FLD-001-rev.03 Field Data Shee€ DateIsgued; March 8, 2019' LE Name and Affiliation (Sampler(s): Name and Affiliation (Inspector): Well Information Well ID: 11\-� Well Locked: Well Diameter: 2;-, Total )Krell Depth: ? `t ft Static Water Level: 2S0 ft Height of Water Column; 9 , u� ft Project#ate nc eCoGi,SQt\LF Id Data Sheet Review: �/IH/23 rl.lm Date: o4ltylt3 By. NO / Flushmount ) Construction (PV /Steel/ Stainless Steel) Multi Factor*:a,l0 C{Radius/12)2x3140.48) Casing Volume: V • L gallons Cal. 3 Volumes: 2 • (� gallons Panip Intake: ^ 11 ft Purge Information Date Purged: / 1 2 / "'- 3 Start: i o �l S Finish: l ty Purge hate:S� >hL � N Purging Method: 3l. c\�,-N�'y,n TotalVolume.Purged: (�S� (gallons 11s L) Sampling Information Date Collected: N / t ? 3 Time Collected:. l -1 t S (am4�) Sampling, Equipment Used: '3 --,w,�trument ID: Bottle Type `� � � � <� is U •,t.\ Field Measurements/Observations Preservation wzu Analysis Required Sample Temp ('C): L 9 1-1—Time: (7 t 5-------Turbidity (ntu): S Time: t'i \ S Diss Oxy (mg/L): s�L S Time: Fe 2+ mg/L Time: SpecificCond. (uS)W'r4T s- NTirne: Res. Cl (mg/L)/(gg/L):rime.—' Sample pF6 (s.u.): $ • (� -----Timer Odor:—_--_N-.._._._ Time: _i-7 IS, ReDox (mV): -'!S •Z Tune: Appearance 5�hr}�c i< ; rime: Vl kl ReDox (EH value):YSI ProPlus+200mV 2151•2 Other: — Time: - General/Weather Observations: (,cloudy/rainy) Temp. 31_.(°F) Windy-]� (mph) Sampler Signature Stabilization Test uijvz Spec. Volume. Time Temp, a Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (mg/I,} (US) (tarV) (ntu) (gallons( rls level (ft) L 5.6 ^� IS$.. S.e i�t,i S.E Cow laDS 2`t. ( 0. lic• i S:&; 20 �1 _S 1`':;q J ii 1 C.j t-r1..1 5- WA Document Name: Field date Sheet ➢ocummt Number: F-CAR-FLD-001-rev.02 Qv.., CL01zd L6 Name and Affiliation (Sampler(s): /�'(J. de7C(z Name and Affiliation (Inspector) Well Information well ll)� Well Diameter: Total Well Depth: 3 ' . ft Static Water Level: Ur' 0 ft. Height of Water Column: 13.9'l ft Well Locked: Office 1'1�110 s✓ -/ Id Data Sheet Review: N /Iq �Zs . Date: construction: Qy.C�Steel/Stairiless Steel) Multi Factor*: ''�� [(Radius/12)20.14x7.48) Casing V olume: 2 gallons Cal. 3 Volumes: `• ° 3 ;kz_galloils Pump Intake:—Nilc� q al ft .ti ,s•, M r AIM ' A/. rF Purees n ^ % b'l t Date Purged: / % / 2 3 Stait: Finish: 7 �U Purge Rate: Purging Metho(L oe 'l, , A J b%+i d4, Total Volume Purged: 0 (gall)ns/ s) Samyline information ! 7 0G /3 ;--p Time Collected: (am/) Date Collected:_./� � ,�,,,{{fi�e � 0 d J ?i 1a F A Sampling Equipment Used: � i L � �i 6 G4/at e ument ID: 4 V Bottle Type Preservation :p) Analysis Required >>/c ✓o� Yield MeasurementsMbservah0n 70� ! -Sample Temp.-(°C);-_—_t6 Time Tu bidity (ntr l _.._ - D� (I Time: %�0� Fe 2+mg/L: ^—'Fit< _ —�—.•�'' Diss Oxv (mK/L): /`�__ --- O0,4 L Specific Cond. (uS): E 2, I- Time: 1- 0, V Res. 0 (mg/LY(µg/ L): lime: P a n/e J i D Sample pH(s.u.): S'> 7 Time: /7J� Odor: f✓ Time: ReDox (mV): I Time: _ 7�f Appearance: t L ��� T me: 7 d� ReDox (EH value):YSIPxoPlus+200mV 1S9' b Other: un General/Weather, Observations S 7✓ �La r d y S c, G. y —, 6 K— (emu /c ou y/rainy) Temp.? ("F) W nd� �` (mph) ,: Date: `?4-- 3 " Sampler Signature: M J 6�� StabilUanon less -- - Time Temp. Diss Oxy: Spec pH (s.u.)Purged ReDox Turbidlyater (n�) el (ft) OtherCared. (°C) (mg/L) (yc) (mV) gremoved, .Ib1.,) S-7.6 �.Gs ,/3,Y/-7,S,b0 1 a'. C,X I.r, l 'E"�.b„� i6t.s �, 30D� Document Name: Document Issued: November 27, 2018 r Field Data Sheet Pa aft— Document Number: Issueing Authority: &CAR-FLAOol.rev.02 Pace Huntersville Quality Office Client: L_ Location: Project: L✓ s 7 Well ID: � d✓ G Reviewed Date and By: Stabilization Test pt-I 114 113 Q1y Y" 1. DOME. j 4 u.tis 5 Mi1'ITD Time Purged Temp. (°C) Diss Oxy. (mg/t) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/rds) circle one Waterlevel (ft) Other S^^,i6 /se 7,'C 0d') 2o,>J tY,6 ,II [ 8.1 3.3—> Ise, 3 D a.r.,5 Dmument-Name, Field data Sheet Date iasuezi: March g, 2019 EMr<71yfiGa7' Page: I of 1 r Document Number: F-CAR-fLD-ool-ray.o3 Issuing Authority: Pare Humersvitle Quality'. Dffice.. Field Data Sheet c Ilene; 1-A, Location: N I ¢nc f r 10 I Project#kCh�'-L Name and Affiliation (Sampler(s): AL/A- P",.A�_ Field Data Sheet Review: Name and Affiliation (Inspector):J y , t M • z3 /-tE 2 Well Information Date: y/ai�3 By:.�3 / Well 1D: � l W " i L" � Well Locked: ! I W ( f NO f Flushmourtt) Well Diameter; �' Construction: (V� (Steel/Stainless Steel) Total Well Depthz 30'( S £E MUIH Factor*: 0.I , 3 + [(Radiva/12)2x314x7.g81 Static Water level: 3 j gallons Height of Water Column: ft Cai.3 Volumes: (, U gallons Pump Intake: r" -2 c ft Purge' Information Date Purged: ci J 13 f 17 Start: i I Finish: 12OG Purge Rate: (�,w ✓ti Purging Method: A3�Z,_(irC Total Volume Purged: ILL (gallonsf��/I;) Sampling Information Date Collected: fi Ij -3 /—/ me Collected: IDS__. Ti_ (am/plx ) Sampling Equipment Used: P& 3�'...I Instrument ID: Y _)-4' c73cr Battle Type (I zS0 C PIC, — Preservation Analysis Required k L J Field Measurements/Observations Sample Temp : IS S P P ( °G ) Time: 00� -- —_Turbidity (niu). � . � Time: I�CS Diss Oxy (mg/L): Time: Fe 2+ mgfL: J kiN Time: 05 Specific Cond. (uS): o `l Time: Res. Cl (mg/L)/(ttg/L): = Time: — i Sample pH (s.u.); v`u, I OS IieDox (mV)c c� Time: T�Tirne: — -..— Appearance. �)e� .t me: I)i_Q` IieDox (EH value);YST Proplus:+200mV 2 i 3 Other: Time: — - CenAratlWn�tlra,.._-._- sutui /cloud Sampler Signature: �Z Stabilization Test Wind 7_(mph) (°C) Diss Oxy.Turbidity (mg/I,) Spec.a(sx.) Cond. o i e removed Water Other 4T[meTemp. (uS)) (ntu allons (g f / level (ft)7L)(o i . Z. �s.(�—. L I]cl t 3 3 S1(.4 I G S S.y Cr iSU� ,u �,i�BArrr<7h'fiCa1 Tier F OIL, Document -Name: Field data Shect. Date Issued: March 8, 2019 Page: i of 1 Document Number F-CAR-R.D-001-rev.03 wing Authority: Face Huntersutlle Quality Office Field Data Sheet n r.. I. Cl= Name and Affiliation (Sampler(s): ALJ^I Field Data Sheet Review: Name and Affiliation (Inspector): y .1 N , 23 MEN Well Information Date: 14 CAI43 By. N rv�- Well ID; j 4L >- 13 3 Well Locked: ( 3 / NO / Flushmount ) Well Diameter: Construction: (/Steel/Stainless Steel) Total Well Depth: `i� 1 `' ft Multi Factor*: (6 [ (Ra {ius(12}2 x3a4 z 7.4a) Static Water Level: % 9 ft Casing Volume: S S gallons Height of Water Column: ft Cal. 3 VOlumeS: 1 •i gallons Pump Intake.- ✓" 3 c, ft Purge Information L) Date Puiged-.j /�, 3 Start: 3J-U Finish:.15c)J Purge Rate: IaomLl—I PurgingMethod:Cn3)= lac /�?y —_,_Total J Volume Purged: (gallons Ii j'L) Sampling Information Date Collected: �I j l 5 / 3 Time Collected 1 ` S . _ (am/ in` Sampling Equipment Used: P�L''15i-z.. )tz J w %10 instrument ID: Battle Type Preservation Analysis Required' CSC ti[c�Af (Gsi t—(Cc N,UCi A%}-Jz ii Field MeasurementslObservations Sample Temp (oC) 22 �Tinter. 1j1-15 ---TurbidityFe (ntu): j. Time: 13)S Diss Oxy (mg/L—):`.1 .3 Time: 13 -f 5- 2+ mg/L: /Jn Time: Specific Cond. (uS): S 1' 3 Time: 13c15 Res. Cl (mg/L)/(µg/L): - Time: Sample pH(s.u.): ,b _Time: 13LIS Odor:_.,—....-._ vw--� Tune: 1 `! ReDoxmV ' I °I G) h (, }� Time: 13`i S' Appearance _C�-� 'Time:j3�S - — ReDox (EH value):YSI ProPlus+200rnV 3`}✓i Other: Time: Sampler Signature: L- Date: `I JIS /I 3 Stabilization Test Time Temp. Diss Oxy. Spec. pH(s.u.) ReDox Turbidity o i. me removed Water Purged cc) (mg/I,) (US)Cond. (mV) (ntu) (gallons/ Is/ level (ft) Other L 11Lcf v.5 27� (o.yU Doke T O' �i.5 1 I�.i.t.l _ 2- — Ci53. ( 1�.� N) t.0 j VDU 13,5111 C-Al Document Name: Field data Sheet Date Issued: March 8, 20t9 �!�BJLtalytlCal = Pa e: 1 off i Document Number; F-CAR-FI.D-001 rev.0,1 Issuing .Authmity: Ee f3' itersville Quality .Office.. Field Data Sheet Client: N !" Location: �C l�L ProjeCtt (�Jx ^ l cz /= Name and Affiliation (Sampler(s); At VA - Field Data Sheet Review: Name and Affiliation (Inspector): /J c1.1 t = 23 Well Information Date: 'iW111)3 By: )for - Well ID: M,W 13 -I3.+._ Well Locked: tySs / NO / Flushmount) Well Diameter: Z" Construction: (&/Steel/Stainless Steel) Total Well Depth: I �.. �i ft Multi Factor*:y (6 f r(Radius/12)2 x 114x 7.481 Static Water Levels `5d ft Casing Volume: L� �C gallons Height of Water Column:—) 6:1 ft Cal, 3 VoIumes gallons Pump Intake; Puree Information Date Purged: Start: 1 S� Finish: J 3OS Purge Rate: IoO,1 it, h Purging Method:__( `c �(/ Total Volume Purged: (gallons f n� f L) Sa-mplingInformation Date Collected: LI / J S � 5 Time Collected: 1 �} n p 13---_- (am/�ii Sampling Equipment Used; f t' 3I' { f t^^,P Instrument ID: y-)z 0o 6d` 73Yi F��s �i ��3 Bottle Type Preservation Analysis Required Field Measurements/Obseruations Sample Temp (°C)i 2c Y Time: I U _Turbidity (ntu); �I �7 Time: 13 ) DissOxy(mg/L) Q-4 Time: Fe2+m L: j)') gl Tune:. I31O Specific Cond. (us): 353.6 Time: Res. Cl (mg/L)&g/L): ' Tune: `- Sample PH (s.u): ,Z -- Time: Odor: v�Tune: _I_�1 u ReDox (mv): I Time: Appearance: GAe v' Time: 13y ReDox (EH value):YSI proPlus+2QpmV Z`l2. I Other: Time: General/Weather Observations:' /cloudy/rainy) Temp,,('P) Wind (mph) i Sampler Signature:�Z Stabilization Test Time Temp. Diss Oxy. Spec. (s.u.)V) Turbidity Vo ume removed Water Purged (°C) (mg/L) (uS)pH (ntu) (gallons// level (ft) ether �, 33,3,�. �,I ;RReDox `j L.v S UPC 33C.5i� loci ILA 'i lS�CJ }.SJ — i -)w C@}liki(f'(fCd(y � : Document -Name: Field data Sheet Date Issued:March &, 2019: Page: 1 of �— Dmument Nuanber: F-CAR-FID-001-rev.O3. tatting Authority: Pace Huntersville Quality Office Field Data Sheet h: A L Location: tvc,171) AI A- ef-( Name and Affiliation (Sampler(s): `% M-Cl' Name and Affiliation (Inspector): lktt Well Information Well ID: /'% V" _ 1 -) Well Locked: Well Diameter: r2l Total Well Depth: % -7 D ft Static Water Level: 5 ft Height of Water Columnft 70.07 roject#: G<bStin bt�co�r/�d,C LF, (Field Data Sheet Reviews u lai (%.a Date: `(11N 1)-3 Construction: V /SteelJStainlessSteel) Multi Factor*>: •!6 6g r(Radius/12)2x3.14x7.48j Casing Volume: 1 /, ? gallons Cal. 3 Volumes: 3Lf -2 � gallons Pump Intake.- -7 Purge Information ,�`� '� % 2 0J /4ilQ c Date Purged: Jq2�f �3 Stta/a//rt: /-7 X19 Finish: i$d) Purge Rate: % �V /^0� / QowT j° /tv Purging Method:10- � 4M/' Total Volume Purged: �7%t/ (gallons/�JL) Samolina Information Date Collected:_/dj I Time Collected;1!/ D _:.._ (amj Sampling Equipment Used:4eQL - P0(1N1P Instrument ID:_ ° /P1z�� Bottle Type Preservation Analysis Required 7 ti77 .�c l'143 ,t7 XT✓z- Ixko Gch/m 6tr7Tf )4GL C Field Measurements/Observations Sample Temp (°C) �ti (p Tim:..� e/V T Turbidity(ntu): • 3 Time:�J Diss Oxy (mg/L): O Time:Fe 2+ mg/L ^� Time: Specific Cond. (uS): ?`r°1a TimeRes. Cl (mg/L)J(µg/L): ~`Ihne: Sample PH (s.u.): ��- •�_, Time:Odor:_,___ ReDox (mV): - S 2, ) Time: Appearance: ReDox(EHvalue):YS11'roPlus+200mV Other: General/Weathertlhaervatinncr .4fw4✓'7-°f4 r% 12.1 -7 Sampler Time: Wind V _-� (mph) Time Temp. Diss Oxy. Spec. Cond.u�pH (s.u.) ReDox Turbidity Volume. removed Water Other Other (°C) (mgJi,) (niV) (ntu) (gallons] is level (ft), L I J,j Srzgr 0-4 TO -7 0'M mot• -7 >, 14, a'V 7 3 1q. I`t so ti �-b -7, 42. I 39 /a 5. --7 PLO II�-7 2 -17 a•(° r.r �17'4 � Document Name: Document Issued: March F 2019 c?Cf3f�tTs7/�lCr�l Field data Sheet Page -Of 1.. Document Number: F-CAR-FI.D-OOl.revd49 Issueing Authority: Pace Huntersville Quality Office }1 Client: / l SVell Diameter Multiplicatim Factor" /U L ®� — p Yt L-f- i s ✓> 3 1 0.0408 Location: wood f LAIIA c. 1.2 1.62$ 00[031$1080 Project: G1-05AD 64/LCO✓'t r 2 0.1630 Well D: Z4 �A/ h 3 0.3670 4 _ 0 6530 Reviewed Date and By: 4111111 AtW 6 14680 Stabilization Test G1 1LIP-S kt^, 8 i 2.6100 • 9 • Em ®®®®®®®®®® Document Name: Field data Sheet - eArk?6ftal r document Number: F-EAR-Fi.D-001-r,03 Field Data Sheet Name and Affiliation (Sampler(s): AT\..) �'k Name and Affiliation (Inspector): Well Information Well ID: _ kA\ 1 1 j Well Diameter: `L__-_,__-_� - Total Well Depth: - ft Static Water Level: 22 I ft Height of Water Column; 3?. 31 ft Well Locked: aid Data Sheet Review: iIm Date:. a4llglts Construction: PVC Steel/Stamless Steel) Multi Factor*b 2 1+(Radius/12)2x'3,14x 7.481 Casing Volume: i 6 gallons Cal• 3 Volumes:_ gallons (,-T QHr 2 �•)-3 By. CMS Pump Intake: '" S�_ft Furige Information Date Purged / 1=3 / 7 �S StartFinish: Purge urge Rate: t�rn L •j,,.\ , n Purging Method:_ T? 1 �Total Volume Purged; '2� a Z%'J (gallons/aL`1�s L} Sampling Information Date Collected: ' a/ ? Time Collected; I U Sampling Equipment Used: 1 .\ \cam - . 1 Instrument ID: Bottle Type Preservation k 2Sa,a,L Pi .L An 1 ' 3- uUrnL V--\ �x'iy + � Field MeasurementslObservations a ysrs Required \s----_----..-.-._.. Sample Temp (eC): -L { . ? Time; 1 1 i ^ t .�v--_Turbidity(ntu): b Time: lZ Diss Oxy (mg/L): , ----Z----_____Time: Fe 2+ mg/ L: l Specific Cond. (uS): (2 Time: Res. Cl (mg/L)((µg/L): _Time: ---- PH(s,u.): _j , Time: Odor: �I Ji) rime: ReDox (mV). - I. 73 --------__Time: -- - ----Time:..----- ReDox (EH value);YSI PznPlus g2OOmV Appearance:\2�� \ Appearance C i t'--'----------lime: \ 12 General/Weather Observationq! Other: — unn cloudy/rainy) Temp,_: (-F) Wind v-a SamplerSignature- ���(mph) Stabilization Test A _Date: (I'�<� t' s! Time Diss Oxy. Spec. p Vo me Purged (OC) {°e) (mg/L) "I I i (s.u.) ReDox Turbidity y removed Water `'1�,1117 A'N (US) l�f?� (inV) (ntu) (galloa� / / level (ft) Other 11-3"- �n i7,� III (T 14.> � -, , 11L.1 il.c � -7 5. �, Z,� cy (-1 ;145 1 _ �� a �,c Gas �•� `��:� 1,2, �lo;� 23.��... v >. O.: Inc ? 3 Document Name: Document Issued: Man 8 22919 ceA&3lyRicN, Field Data Sheet Page:Lof'L Document Number: F-CARFLD-0Ql.rev.0,4 Issueing. Authority: Pace Huntersville QualityOffice Client: J (_. 5 Location: alnnco=Mf , PC Project: nr rMo �o icSf, �= ys 7 C j 3 Well ID: Reviewed Date and By:,QyfLy z3 as Stabilization TestKNW f NM 'Multiplication Factor" 0.0403 0.0918 0.1080 i 0,1630� 0:3620 0,6580 IA680 2.6100 Time Purged g (Tem . pTurbidity o Cl JDissoxy. lmg/L} Spec, Cand. (US) pH (s.u.l '. ReDox (mV) (ntu}; Volume Removed (gallon I L ' ) circle one Water level (ft) Other H t Document Name: Field data Sheet Date Issued: March 8, 2019' Pages 1 of j Document Number: F CAR-Fl.n-001-rev.03 Issuing Authority: Pace Huntersville Office Field Data Sheet Client:. LocatiorrB-- „ o o e l 1J C Project #.ks n� e ' U� C -Se,k 1-7- Name and Affiliation (Sampler(s):. A T\-) - Pa a - Field Data Sheet Review: Name and Affiliation (Inspector): `— 1I /I�) /23 �µM Well Information Date: o411v�z1 By: p Well ID. rA\d Well Lacked: (YES J O)/ Flushmount) Well Diameter: i Construction: e/Steel/Stainless Steel) Total Well Depth: k3-1, C% It MURIF,1001*<C.((Radius/12)2x3:i4x7,48l Static Water Level: 20 • � ft Casing Volume: ! • c1 gallons Height of Water Column: !! 6. i2 ft Cal. 3 Volumes; S ko i gallons Pumpinhke: i3s ft Purge Information Date Purged: it J 1 / 2 1 Start: 7 SQ U Finish: 1 U SS Purge Rate: t C" Purging Method: ) i wi\ca r x, Total Volume Purged: `Z5 'v (gallons/ nls L) Sampling Information Date Collected: I ! ? 23 /_/ ThneCollected: ___pm) Sampling, Equipment Used: \cam �e r i r Z Instrument ID: �� S (D-). \\ f� 6 l^? Bottle Type Preservation Analysis Required 1x27pSc�wL I�tz.k, NuN�n �nLi ,L \j,�� HGL N-1� Field Measurements/Observations Sample Temp (aC): _ �=J Tinte: l t C)Turbidity (ntu)': Q S Time; \ Diss Oxy (mg/L): . ' ( Time, Fe 2+ mg/L: Time., Specific Cond. (uS): Time: Res. Cl Time: V 1�p3t7 1 Sample pH (s.u.); I �, � _ _'Pirne: ReDox(mV): . Odor .. Time: Appearance: e- Time. ReDox -�• ___ v ReDox (EH value);YSI ProPius +200mV 21. 7 Other: Time: General/Weather Observations; Wind C -> (mph) Sampler Signature Stabilization Test Spec. Volume Time Temp. a Diss Oxy. COnd. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (mg/I,), (US)(mV) (ntu) (gallons( his Level (kt) L 7.`i -15,3 v,`-I >c _, ^•i.i -7.� i/'„r!'r?GBfll7rRl1/ilCAl i Document .Name; Field data Sheet Document Numher: F-CAR-R.13-001-rev03 Date Issued: March Name and Affiliation (Sampler(s): ajj1 S Name and Affiliation (Inspector): Well Information Well ID: MW - v Well Diameter: Total Well Depth: 12, 29 It Static Water Level: i • (�s ft Height of Water Column: 3 i 2 ,14ft Purge Information Well Locked: Data Sheet Review: i j liq 03 Date:. Construction: PVC,Stee(/StairdessSteel) Multi Factor*.) Al 3 r(Radius/ 12)2 x 314 x 7.481 Casing Volume: S O • gallons Cal. 3 Volumes: { gallons Pump Intake: G It L-F• Atr l ?5 —y By: l }) ✓� Date Purged: Start Oq'-(5 Finish: t 0 Purge Rate:'LO'��l,;�,n'.� Purging Method: ? e -1 tk wt k Total Volume Purged: (gallons/ tls 1L) Samvline Information Date Collected: Ll / 1-1/ �-3 Time Collected: i V oEvpm) Sampling Equipment Used: 1�e>',ite\f instrument ID: 'ISM J \\ -T1 Ai i Bottle Type .ix Field Measurements/Observations Preservation Hk1 (o M _ Analysis -Required ..\ s Sample Temp (eC): t? ,? Time:!'v_tn_--.-__Turbidity(ntu): Time: 1 1L Diss Oxy (mg/L): . '( Time: Fe 2+ mg/L: Time. Specific Cond. (uS): 14 S . > Time: Res. C1(ii g/L)/(pg/L): Sample pH (s.u.): g • S --_-,—_Time: ReDox (mV); i -7 ,% Timer Appearance: C i r Time: 1 o S p ReDox (EH value)NSi ProPlus +200nrV I 1 i .1 Other: Time: General/Weather sunn /cloudy/rainy) Temp. s S ('P) Wind C; (mph) Sampler Signature: ��� __ �� �. `Date: ` k Ik-3 Stabilization Test Spec. Volume Time Temp. Diss Oxy, pH (s.u.) ReDox Turbidity removed Water Purged CC) (mg/L) (us)Cond (MV) (ntu) (gaIIpns/(P/ level (ft) Other L low =i.2 0 0 ^. jvS_y �a �2, 3.C3 200. i4. 3 G,i1 Itt>.3 y i7, 2.0 Sao CcxumentNome: Field data sheet Datelssued: March 8, 2(n9 xCeAnalyt ,111 Page: 1 of 3 ' Document Number F-CAR-FL.D-001-rev.03 Issuing Authority: Paceffuntersville Quality Office Field Data Sheet Client: tP Ll Location: 45SV-,,`ll aJ< Project#: (loVName and and Affiliation (Sampler(s): ALM- Field Data Sheet Review: Name and Affiliation (Inspector): {J I� M ' ty , 23 i 1E��pYL Well Information Dater �i/all�3 By: ._t-I% WellID: �l %S Well Locked: ( / NO Flushmount) Well Diameters . " Construction: (&V /Steel/stainless Steel) Total well Depth: L G 0 ft multi Factoe: e) I L 3 ('(Radius/12)20,14x7481 Static Water Level: G (o ft Casing Volume: gallons Height of Water Column:ft Cal. 3 Volumes: • Z3 gallons Pump Intake: f -4 `1 It Puree Information Date Purged: e1 (1� 23 Start: � Finish: 1 7'40 Purge Rate: 0 '�- V-- Purging Method: Pv'JSiAJ( n nq —Total Volume Purged: lt;bo (gai[ons/tn /L), Sampling Information' Date Collected: L1_/j3-/ 13 Time Collected: IJLir, (am/(m Sampling Equipment Used: P<1''5�- nn I I,Y 3" nD Instrument ID: I Sl$ 0 3 3` Pw t (oQy Bottle Type Preservation Analysis Required Field MeasurementsJObservations Sample Temp (°C): )S • () Tinter 13 - -- __Turbidity (ntu): . U Time: f �i S Diss Oxy (mg/L): O • � Tinier Fe 2+ mg/ Li /J Time: SpecificCond. (uS): GLt Time: Res. 0 (mg/L)/(µg/L): Tune Sample PH G- Time:, Odor:✓1R*^'L� Time: Pr/S ReDox (mV)': -) I Time: Appearance: C dew ^I/�kime: 1_71-15 ReDox. (EH value):YSI ProPlus..+200MV. S �I . 3 Other: — Time: Time Temp. Diss Oxy: Spec. Cord. H p (su) ReDox Turbidity Vo ume removed Water Purged (°C) (mg/L) (US) . (DIV) (ntu) (gallons/ 4 level (ft) Other L c iS,2 thxument IIyu �Ducument Numbed Name and Affiliation (Sampler : (s} Q-f w — j'0. c Name and Affiliation (Inspector); Well Inform-- xhun WellID: Well Locked: Well -Riamet 7 ' ice} rPidd7DataeetRevrON!/y/z3 er:� Construction: (PVC Steel/Stainless steel} , Total Well Depth: D � O� �--ft Mult9'pactor-s .t '� 1»Niaatue/i21aXs;lax7.:lsl Static Water Level: "-1 c� {t Casing Volume: 11 . j — - _ gallons Heightof Water Columni ��• S3 ft Ca1.3'lrolumesi -- —_ gallons 1 ntegyilte Quality `. lasac\ 1->; Ap � 2�2i )iHm I By: QM.T PurgerQe Info�tion Pump Intake_ C ft Date Purged: LA / i3 �3 1 Mart: I13�-1,..1S Purge Rate: Purging Method: ire ,', k c L' c Tptal Volume Purged; I2 SU -- __ (gallons�'L) 3arn lin Inf rmation Date Collected: L' /- "S / "z 1 Time C ll 1 � " Sampling Equipment Used: Bottle Type — U <\ o eeted;_ 3 �j (am/&) Preservation Hw N Ci„ Hcl Analysis Required 2 Field Measurements/Ob_sons Sample Temp Cq: -.--___._._____._Time:i 1-7 S U piss Oxy (mg/L): O ----------.-.-.____ Time: _ _Turbidity (ntu); 0 , [� Time: S G Specific Cond. (,US);: �� �, ------- Fe 2+ mg/ L:---� -----------_Tiute: Sample PH(s.u.}, 6 ._.Time: Res .CI(pg'/L)/(it /1 g ) lime:__— - --- :-' 'A_,._ Repox (mV): " 23 .Timer Odor: -- - 0D Tune: 1-7} U ReDox (EH value):YSI Proplus Time: +200 V Appearance:t c t' t leer s -- v16Other; Genera I/Weather Observations: Time: unn /cloudy/rainy) Temp, ✓12 (ap) W ind O -S Sampler Signaturefl®°_ 'r` : (mph) L t 5tabiliz____ ation Test pate: 1 t'> �� Time Temp. Diss Oxy: Purged (aC) (mg/I,) Spec• Cond. a unie pH (s.u.) ReDox Turbidity removed Water (US) (mV) (ntu) (gaitans/ ils level (ft) Omer i�S Q.a ig L { Document Name: Field data Sheet Date Issued: Manh 9, 20S f/CA1k�EyfiCal t Pa e: 2 of j Document. Number: F-CAR-Ft.t)_001-mv:03 Issuing Authority; hareliunte€svftL Client.-_. IjL Office Field D_ _ at�gheet Location: hco „p 7" Project� f C\uze Name and Affiliation ler: t} am s rx A Name and Affiliation (Inspector): Ffeld Data Sheet Review; Well n£°- r-- rn atio Date: Well ID: IA. . \,j - i q oy// //23 By: Well Diameter; � 2 'i Well Locked: YfiS O / / FI"ushmount)' _ - - Construction: PVC 'Steel/Stainless Steel) Total Well Depth; ) i . S ft Multi 'Factor*: `�, \ V3 (Radius/12)2 x3;14 7.481 Static Water Level: i J , 3 ft x Casing Volume t �, ii a Height of Water Column: 10 3,y ft gallons Cal. 3 Volumes: SG, Li i gallons Puree In€ormation Pump Intake: i%S _ft Date Purged: / i 3 / 3 Start: i V3 j l7 --_ Finish: Q� d Purge Rate: Purging Method:_ �Ie-,%S),�A Total Volume Purged: `Z-S G �j (gallons. urls I�) Sampling Information Date Collected: 'I /II/ 3 1"7t,-s Time Collected; _ (am/1B) Sampling Equipment Used: c r s 1 �----instrument 0.�k; e_ IA y 5 I `3?. i\ Bottle Type —�. Preservation `s i x 2 \�, - .3 Anal si Required y N N Q , 'clG -- �C Field Measurementsfobservations Sample Temp (0q: 16 . ( Tzme: '-7' S _ - _ _ Turbidtty (ntu): b , S t 'y S Diss Oxy (mg/L}: , �l Tone: Time; Fe 2+ mg/L. Specific Cond. (uS): 17 , y Time: — Time. -^ Sample pH (s.u.); i '� Res. CI (mg/L}/(µgf L): - Time. i , ReDox (mV): - I e, 5 1 Tune _.: Odor:_ Eu Time: i ,' - - _ Time: ReDox (EH value):ySI Proplus.+�20gmV �H L Appearance: 5 ` Y Fime: ll G S General/Weather Observations: , Other: Time: i Sampler Signature: �� --�`� (sunny/ oudy/rain Temp, i (aF) Wind-� (mph) Stabilization test v ,; Date: Time Temp, Diss Oxy: Purged (eC) m I O Spec. Cond. pH (s.u.) Vo ume ReDox Turbidity removed Water (us) (mV) (ntu)' (gallons/ sails level (ft) Other u IL 4.i `i7q.i i.s -7, 5>.IL 1iSU i .� U.`��,! 4L.2 2 s G Sto i1. J s f �V 6Ark744ical Document Name: Field data Sheet Document Number: F-CAWFL D-001-rev.08 Name and Affiliation (Sampler(s):. AT Vr - tic ce Name and Affiliation (Inspector): Well Information Well ID; Well Diameter: 1d Data Sheet Review: Date: II/ I'I By: ^j rl ✓1 Well Locked: (YES / �O}/ Flushmount )I Construction: W�V Steel/Stainless Steel) TotaiWellDepth: 1 ft Multi Fact0r*:©3 1k Q ("(Radiu6/12)2x,"4x7.48] r Static Water Level: H • b� ft Casing Volume: � gallons Height of Water Column;..' 7ft CaL 3 Volumes: :5 • gallons Pump Intake: r ) ft Purge Information Date Purge Start 1© Finish: (S o c Purge Rater Purging Method: 9 r, Total Volume Purged: S LI (gallous./fy�li / L) Sampling Information Date Collected: LI /13/ z- Time Collected: 1e� Sampling Equipment Used: s Instrument ID: Bottle Type 1 x 2S Q. w L Pt sA,t 3x L(b \J n\ 3x i-IO,nLU;h� Field Measurements/Observations Preservation SAW Z10 HG� Analysis Required Sample Temp (OC): c, 6 Time: I S_).- Turbidity(ntu)t 1-1, 1 Time: l j\ Diss Oxy(mg/L): } Time; Fe 2+ mg/L; - Time: Specific Cond. (uS): Time: Res. Cl (iig/L/(gg/L): Pone: Sample pH (&u.); S _._.----Time: Odor:___ro ReDox(mV): S Time: Appearance:Vs rime. ReDox (EH value);YSI ProPlus +200mV ) 1 1 Other: - Time: Sampler Signature Stabilization Test brainy) Temp. lz ,(T) Windy"' (mph) \A C1-�i Spec, Volume. Time Temp. Diss Oxy. Cored. pH (s,u.) ReDox Turbidity removed Water Other Purged (C) (mg/L.) (US) (mV) (ntu) (gallons/q ff level (ft) L au(� S.LA IN t. � 2l, 1 ; `� 135 '• .S -w 1�t.3 '�I.c� S �i S Document Name Document Issued: March 8,2019 Ce Analytical Field Data Sheet page 2of - .� Document Number: Issuemg: Authority: r F-CAR-FLD 001.cev,03 Pace Huntersviile Quality Office Client: Lgeation: �ti,nco,_,�i j.7C, Project: {�• �c.c �e ( Llc;f J L r A4or Well ID:� Reviewed Date and By: /5� J Stabilization Test 11 123 %M/I\ 1%Te11 Diameter Multiplication Factor" _ 1 0.0408 1.2 0.0918 1,625 01080 2 0.1630 3 0.3670 4 0.6330 6 146,80 $ 2.6100 Time Purged Temp, o C () Diss Oxy, (mg/L) Spec. Cond. (u5) pH (s.u.j ReDox (mV) _ Turbidity (ntu} Volume Removed (gallons mis Q circle one Water level (ft) Other H t3b5 i7:5 b2 .S 33 LA 13_%^Zh 19, 1 ,S G-7 '42,7 ly3f� 21.a 6: I3S (;.5 -�i,j zi.6 �1 % i44U =i,"3 0 ) 1363 S -42.-i 2,'1.S i1b,� ?`•5U 21,E O.�I I?� o,S -�`a,-�., -�8,3 S��,y ,M i> I"", I DocumenttName: Field data Sheet Date Issued: Mar c12 8, 2019 .�seRrtalj4kal - PaLe: i of _` Document Number: F-CAR-FID-00I-rev.03 tssuing Author T Fare Huntersville Quality.. OffiCe Name and Affiliation (Sampler(s) A:r) �^ e Field Data SheetReview: Name and Affiliation (Inspector):: 11 All / 23 Well Information Date: WellID:�-\' oy/�%/Z3 Well Locked: ( YES / " O Flushmount)' Well Diameter: n Construction: qsSteel/Stainless Steel) Total Well Depth: R" . I r it Muni Factor*: Sj, l Gr'3 [*(Radius/12)2 x3 14 x ,481 Static Water Level ft Casing Volume: 3. gallons Height of Water Column: S, i �b ft CaL 3 Volumes; gallons �\ 1-- �- A 1., v o 2r-t By: GNM 91;1r I'ump Intake- C4 U ft Purge Information Date Purged: �I / l � / 2.:3 Start: ISIS Finish: (ASS Purge 20 urge Rate: Purging Method:_ f�� Total Volume Purged: �G`�b (gallons oils L) SAMRIhIgInformation Date Collected: H / 13 / -3 Time Collected; I G S'U Sampling Equipment Used: ire,\ si ,W; c- instrument ID: i S G-zy Bottle Type _. lx2S'o-,L Plasi-,- 2kE14 ,t- \j •� AX 14C .-,L \)',..\ Field Measurements/Observations Preservation \4 Nei_ 14C �- Analysis Required �.Li-TI) Sample Temp Cq: _ 12 , c Time: i 6 C_ __—Turbidity (ntu): rU • `i Time: 16 L 3 Diss Oxy (mg/L): G Time: Fe 2+ mg/L: Time: Specific Cond. (uS): 9 E Time: Res. Cl (mg/L)/(µg/L): — 'rime; -- Sample pH.(s.u.): b••7 __..___Time: Odor:__ o• \_.__ Time: k�` e ReDox (mV): _ O , k Time: Time: ReDox (EH value):YSI ProPlus +20or11V �rLG ,2 Other: — Time: General/Weather Observations: Sampler Signature Stabilization Test M Iny) Temp. I (°F) Wind b,s (mph) Time Temp. Diss Oxy. Spec. Cored. pH (s.u.) ReDox Turbidity Vo ume removed Water Purged CC) (mg/L) (us) (mV) (ntu) level (ft) Other ii U.7eG [gallons,�m�, C ISN> 7qs 6`7 0 1 t7. �i 'be1.S i7,`'i gr CeAnafytical` Document Name: Field data Sheet [.late Issued: March 8, 20 Page Document Numtmr. F-CAR F1.D-0OYrev.03 Issuing. Authority: Pace Humeraville Quality Office t 19' Field Data Sheet Client: f F Location:✓�^ c�Ct�A 1� Project#: M�✓' Name and Affiliation (Sampler(s): /t't/J f r} c /•a' Field Data Sheet Review; Name and Affiliation (Inspector): —� Date: 4' j j%1 n j) By: b Well Information Well ID: "vt hr - 1 3 1 / 5 Well Locked: Y NO / Flushmount ) Well Diameter: J" Co trf l�%S 1 S " 1 • ns uc Ion. ( We f tam ess Steel) Total Well Depth: % I �1 Ft Multi Factor*: i / Z b [*(Radius/12)2 x 3.14x 7.481 Static Water Level: L{-1, 9 / It Casing Volume: % 2 1�'a gallons Height of Wafer Column: % ft Cal. 3 Vglumes: 3 �- 2 0 ?D gallons Pump Intake: -y ft Frame Information Date Purged: / 17 J Start: � 1 rFinish, /440 Purge Rake: Purging Method M��S � Total Volume Purged: 000 (gallons/ ls/ ,) Sampling Information Date Collected: / l_i f y� Time Collected: l �t ___ (am/prn Sampling; Equipment Used; Mo•, Joo. Instrument ID: Ye L. D 1 Bottle Type Preservation Analysis Required V,?�t 3 v,J L 5 y cL l,� �ioxs/nre Field Measurements/Observations �j Sample Temp (°C): I S �) Time;_. >-�" Turbidity (ntu): �, i � Time: Diss Ox m L : O , 0) -0 rune: - y ( gl } !' 6" Fe 2+ mg/ L;-•----Tyt�� Specific Cond. (uS): /y� Time: E{'tfa_ Res. Cl (trig/L)f(µgfL}: rime: Sample pH (s.u.)r � �n�:Time: 7 a Odor:_,_.. � _ ReDox mV : % J-1-• = _1 !4! ppy-Q-a- ( ) Time: Appearance: E"it. Ime: ReDox (EH value)NSl ProPlus +200rnV 11, t- o Other: General/Weatherflhcertratinna- .t ✓v✓.✓+. u/'., A(_ jafrnriy/cloudy/rawly) Temp. (,q— (*F) Wind 0 )J (mph) Sampler Signature: / '� /L A _ �--...DDate:. � /7,. 2j Stabilization Test Time Temp, Diss Oxy. Spec. Cond. Hsu. P (' ) ReDox Turbidity Volume remove Water Other Purged. (aC) (mg/L) (us) (mV) (ntu) (gallons is level (ft) L 'fit f I .U5 t EA1, 1'r. . 'L S'1'03 Z,a C 2 00� �f S. 7d � u ls,> .o�_ S�� 11,�a' IMI's ,4po asap q- q-,7 v a l 0 ,Cl✓ S 11'`f )Od 1 la3 L.rF� �u04 'F6 `�6 Document Name: Field data Sheet Page: 1 of 2GEAf3tp2 N Issuing Authority: Pace Huntersville Qaali y Document Number: &CAR-FLD-001-rev.02 Office F eId Data Sheet 0�OlYld fl ll a I II q� S c���j Client: e)L�_ LGocation: V)& k AQpSteel/Stairdess SProject#: Name and Affiliation (Sampler(s): L �� Review: Name and Affiliation (Inspector): N) I = M By: WellInformatioaWell ID: V Well Locked:o� Al Construction: Steel) fDV a hVS We11 Diameter: � ^' ^ � (y )L� Total Well Depth:�ft Multi Factor*:T1.kt02J [(Radius/12)2x3.14xz4a] p 1 /� gallons >S Static Water Level: arr,,,4��b'',,,,�rk. Casing Volume: g ��• Height of Water Column:lyl�ft Cal. 3 Volumes: 3a'D� gallons Pump Intake: ' 50 ft Pnr�e Infornlati®n pvtls/m;� Date Purged:4f_�/,/ / Stan: I V� Finish: LU_��.PurgeRate: PurgingMethod: 1 1(����)� Total Volume Purged: b� (gallons(mis ` SamVlin�oon Date Collected: Time Collected: (am pm) 1 Sampling Equipment Used: \�}� Instrumemll): S rl� QrAi ( v a4e,- bottle Type Preservation Analysis Required Field Measurements/Observations Sample Temp. (°C): j��➢—''D Time: �1�h,� O Turbidity (mu): D Time: v'L Diss Oxy (mg/L):�0 In Time: --u SL � —Fe 2+ mg/L Time: Specific Cond. (uS): `I)C) Time Res. Cl (mg/L)/(µg/L): Time: Sample pH (s.u.): Time: � Odor:_K)O"L Time: ReDox(mV): oi�J `D Tune:Q_I�_.P.ppearance:.�tQ_(�{� __Time: ReDox (EH value):YSI ProPlus +200mV o�3 • Other: Time: General/lNeather ®bservations: _ _ sunny cloudy/rany) Temp` CF) Wind � )1 {mph) Sampler Signature: 411 T t Stabilization es Time Temp. DissOxy. Spec. Cored. pH (s.u.) Re (mDax ) Turbidity ( ) Volume remove Watex level ft ( ) Other Purged_ (C) (mg/L) (US) (gano / I i 1.OU auto. I. 33,E a��•� O C)4.82 acl• Q 19AS . �15.3 5 , , r' aY� . Milt . a Document Name: Document Issued: November 27, 2018 r- ` 4 jrl Field Data Sheet Pagyf d'1 Doc=mtNumber: Issuetng Authority: F-CAR-FLD-001.rev.02 Pace Huntersville QuahtY Office 41�31�� client: Location: ]�L�n Project Weli ID: Reviewed Date and Stabilization Test - 1iW�i23 {yp 7_ 1.:6w� G:.1vS 93fi 7-0 r< 4 :•� �. circle on 'i1 �� �' .•�� � �.! � 1 Via`' �..�:� sl?2 b Data Issued: November 27, 2018 Document Name: Field data Sheet Page: 1 of-, r'-12leAroMbsl - Issuing Authority: Pace HUH Sville Quahty Document Number: F-CAR-PLD-001-rev.02 Office SLZ r1eia villa nneec Qucic 6 10,e.d-41Project#: -�WS Name and Affiliation (Sampler(s): N P'l C's Name and Affiliation (Inspector): Well Information Well Locke Well Di er: ConstructionTotalWellDep ft Multi Factor*; id Data Sheet Review: Date: 9 /) q / ?3 By: LO H Ill ( YES / NO) Steel) r(Radius/12)2 x 3.14 x 7.48] Static Water Level: ft Casing Volume: gallons Height of Water Column: ft Cal. 3 Vo es: allons Pump intake: ft Pvx elnfoam '011 Date Purged: / Start: Finish: Purge Rate: - Purgng Method. —_To al Volume Purged: (gallons/cols) ` sampiina Inforunation Date Collected:!' /Lb / Time Collected: j "o (am/0 Sampling Equipment Used: G-2h' � Instrument ID:, YS:r'D Bottle Type Preservation Analysis Required Mc l Field Measurements/®bservatiolis -Sample Tema (°C): --fir} G_._.� me:_ Turbid ty (nhf): Time: ----- - _ Diss Ox -tg/L) C! x 17 Time: % f/ D Fe 2+ mg/ L: Specific Cond. (uS): 20 Time: Res. CI (mg/L)/(µg/L). Tine: Sample pH (s.u.): �' � � Time: / y" / ° Odor: f 10^14 Time: . rn� .. - ReDox (mV): g � ' Tim�tey, y-7�"� � P ppearance: l�Nz- Time: ReDox (EH value):YSI ProPlus +200mV a 9 Other: General/Weathea Observations: S ✓�'� h y' If-"tr,'/n - (/cloudy/rainy) Temp. (°F) Wind 0"n(mph) 1, R Date: �j 3 Sampler Signature: � _ Jrd0nl'LallU11 Time Purged tent Temp. (°C) - D ss Oxy. Spec. Cond. ) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis) Water level (ft) Other OCBAI7.7(y([C&I Document NameField data sheet Date Issued: March 8, 2019 Page: I of i Documenf Numbei. P-CAR-PhD-pQ7-rev.6A : Issuing Authority: Pace HuntersvilleQuality Office Field Data Sheet Client: 6 L 4 Location: 8v-'c 6634c, d "' Project#• s� _ Name and Affiliation (Sampler(s): /,t i� fD�✓�F Field Data Sheet Review: Name and Affiliation (Inspector): _ � / 1`� /?-3 �H *1 Date: By: Well Information 4 IN N N 3 t� I We ID: Well Locked: ( YES / NO / Elushmount ) Well Dia eter: Constru 'on: (PVC/Steel/Stainless Steel) Total Well De It Multi Factor*: (*(Radius/12)2x3.14x7A8) Static Water Level: _ ft Casing Volume: gallons Height of Water Colum fE Cal, 3 Volumes; gallons , Pump 1nta It Purge Inform ton Date Purged: / Start: Finish: Purge Purging Method: Total Volume Purged: (gallons/cols/L) Sampling Information Date Collected: j!3/ 1 3 Time Collected: ��� 3 6z /pm) Sampling Equipment Used: s14 Instrument ID: j'S r7 D A 1 S , y% • A" `" ` Bottle Type Preservation Analysis Required 3 1/.4Lf Field Measurements/Observations Sample Temp CC): 5- } Tiute;� 3 J' Turl�idlty (ntu): bcl Time: Q/3 r— Diss Oxy(mg/L): 2 Time: 0 9 3 i Fe 2+ mg/L: Specific Cond. (uS): S /, (' Time:0 �J _c Res. CI (ring/L)/(gg/L): Time: Sample pl-I (s.u.): r /Time:99 3s Odor:__.._ _ Time: pg 3 ReDox (mV): f Time:0 Appearance: L" /z, 'Time: 01 ''7 ReDox (EH value):YSI ProPlus +2QQmV 7 Other: 1,11ne. General/Weather Observations: 1 I/.✓<v (&__�/cloudy/rainy) Temp.--' d— ff) Wind o' ,r— (mph) Sampler Signature: Date: ' Stabilization Test Time Purged: emp. ( Diss Oxy: (ing/l.) Spec. Conti. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other Document Nome: 10�• CBAttafyl%Cal ...• j Dmument Number: F= Field Da rr:p e, L st r ...._.___. /d _ .. Name and Affiliation (Sampler(s): ^7 i' -1 691.v Name and Affiliation (Inspector}: ___ Well Information; JID: SW-2 Shoed I DaU Quality;, --rev Quality Office d L i Project # S G✓S Pield Data Sheet Review: Date: '-I /)1-(/ )-3 By, li� M N/wl(Lj Arty ^_ vveu.LgcxeV(PVC/Steel/Stairdess Flushmount) Well Diameter: ConstructioSteel) Total Well Depth: ft Multi Factos/12)2x 3,14x 7481 Static Water Level: €f CasingVolgallons Height of Water Column:ft Cal. 3 Volugallons Pump lnE•ike: ft Pur a Inform Date Purged.:' -In_ / Start : Finish:. Purge Rake: Purging Method: Total Volume Purg _ ___ (gallons/cols/L); Sampling Information Date Collected: � /�/ 2 3 Time Collected:%�, r / -- /L, (, - t/ 's ,n j Sampling, Equipment Used: U21/ Instrument ID: hj= O''k o S jj, r- x I fi Bottle Type Preservation Analysis Required J t/,gcs C tom— A)Kr7Nr ^7q, 4 Field Measurements/Observation8 Sample Temp (eC); 19 (? Time: 1� '- Turbidity (ntu): 8 Time; / Diss Oxy(mg/t): Z'0'1 Time:"fig S Specific Cond. (uS):_ZZ 30i•`f Time:�� Sample pH (s.w}: _�. / d' .._ Tiine:y' r' Odor: A,10 ReDox (mV): 9 0 • S Time:a�J�� Appearance. 1: rime: d 3 ReDox (EH value)tySl ProPlus +200mV ?- O, 3 Other: tee; General/WeatherObservations, _ rVV,r , Sampler Signature;_ Stabilization Test Sty/cloudy/rainy) Temp? .(°F) Wind L)'0-- (mph) Dater 41' ° /3 • A y Time Purged' Temp: (°C) Diss Oxy: (mg/I•) Sec p. Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) o ume removed (gallons/mis/ L Water level (£t) Omer Document Name: Field date Sheet Fage: 1 of p Issujag Authotity: Pace Htrtexsville Quality Document Number: F-CAR-FLD-001-xev.02 Office Field Data Sheet 13 z� Client: Location: �y L C�'ae d 4`Project#: s� Affiliation (Sampler(s): /'�(' 1 i� Field Data Sheet Review: Name and Name and Affiliation (Inspector): —_. /M ) 23 By: H� Well Information Date: Li ILA (11 ATW Well S GJ " Wellked: ( YES / NO) Well Diamete Constracti (PVC/Steel/Stainless Steel) Total Well Depth: ft Multi Factor*: r(Radius/12)2x3.14x7.491 - Static Water Level: ft. Casing Volume: gallons Height of Water Column: ft Cal. 3 Volumes: gallons Pump Intake: ft Date Purged: /_ Start: Finish: Purge Rate: Purging Method: Total Volume (goons/mls) Samniin_ a�nation Date Collected: /� 3/ i 'Z Time Collected: /4 �7 (am/lla Sampling Equipment Used: 6- /L9 & L-vstrument ID: % .S G' 0 x 0g `,/ f to Bottle Tye nr 5 iF ' i5"'' 1 Preservation Analysis Required IQt91 `7Lh jV/4,1 L)PC VIAL dl G1_ -Sample Tem"— z_ _lime; 1uiu}ulry kry L— __ Diss Oxy�/L) if d Time: l Fe 2+ m g/ L: Specific Cond. (us): -�' 3s " / Time: o Res. Cl (mg/L)/(p Time: %-3l v Odor: Sample pH (s.u.): — ReDox(mv): `i"r Time: Appearance: (L� ReDox (EH value):YSI PTOPllls +200mV"r Other: General/Weather Observations: S 1/ !0 Time: It -7 rime: ( W/cloudy/rainy) Temp.? " (°F) Wmd " � ;mph) Sampler Signature: Date: stauiuzanon a esa V) T (ntu) iremoved mis) leve (ft) Other Ike MCoud. Date Issued: November 27, 2018 Document Name: Field data Sheet Pa 1 of ,�„✓'°�� Issuing Authority: Pace Hrurtersville Quality D.c ment Number:F-CAR-FLD.001-rev.02 Office Q� Field Data Sheet CL pe d l �A J dNccMb2 Client: Location: Project#:S�✓ Name and Affiliation (Sampler(s): Ans 19�? Field Data Sheet Review: _ Name and Affiliation (Inspector): H (I 12T R Date: By. Well Information L-I IM 113 Well ID: i t d- / Well Locke ( YES / NO) Well Diameter: Construction: ( VC/Steel/Stainless Steel) Total Well Depth: ft Multi Factor*: r(Radius/12)2x3.Lx7.48] Static Water Level: ft. Cas ng Volume: _ gallons Height of Water Column: ft Cal. 3 Volumes: gallons S L n Pump Intake: ft Pure Lnf® tion Date Purged: Stat: Fresh: Purge Rate Purging Method: 1nmeFur ged: (g�Dus/Mls) Samylin_ a� on Date Collected: f /�/ � �' — Time Collected: Samplinc,EquipmentUsed: �� InstrumentID: 'IS L Vjd3 / j h7 Bottle Type Preservation analysis Aeqused 6MEL, Vi c1 /�LL (fJL Field Measuremmenfs/Observations Sample Temp -(DC) — �� o T me; Turbidity (ntu) f ---Time. r)—, f--/r � V , -'�O Time: ls� g/ -- me: Fe 2 � m L: 1e: Specific Cored. (u5): SJI. I Time: I , ' Res. C1(mg/LU(µg/ L): 'T me: Sample PH S.u.: _ Time / ' Odor: �� Time: ReDox (mV�: S 3' -r Time: Appearance: Tune: ReDox (EH value):YSI ProPlus +200mV Other: — G al/Weattner Observations: jy--" ' ener ( usl�i y/cloudy/rainy) Tem]-- (°F) Wind{mph) -/3^ A Sampler Signature HIaUS1lLNLIDi1 T'11 Thus Purged ♦cva Ten . DssO L Spec cond: (.) PH (s.u.) ReDox (mV) Turbidity (n�) Volume removed ) a110i1S mis Water level (ft) Other --�e,�fydicsl Document Name: Field data Sheet Document Numbex: F-CAR-FLD-001-rev.02 Pace H Office L,4- Name and Affiliation (Sampler(s):� �9 C ....... --- Name and Affiliation (Inspector) Well Information SAi 7�ni. :S G✓ - /{' Well Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Column: ft Date Purged:_/ Purging Multi Factor*: Data Sheet Review. �' Date: I ` // 5 1 ly I eLg ( YES / NO) (PVC/Steel/Stainless Steel) Casing V olume: r(Radius/12)2 x 3.14 x 7.491 Cal. 3 Volumes: gallons Pump Intake: ft Purge Rate: By: Ate (galloris/cols) Samylina dnfrnmation _ Date Collected: Qf / /�_ T me Collected: � (am/) Sampling Equipment used: —InstrumentlD: �s Bottle Type Preservation Analysis Required k Ur Ls PILL ih�9+�2 t%!7L AlGL liy /oXdi✓c Field Measurements/Observations _-- Turbid Time: / SampieTemp (°�)--i_�, �--Tme:_ ---- - --- -- D ss Oxp (mg/4' J.? Time: Fe 2+ mg/ L: Specific Cond. (uS): / US 4 Time: / Y 1 'l xes. u (mg/ Ly lllg/ LY- 1 1m Sample pH 7.73 Tme /�-f2 Odor: NO?�� Tme: /((-ro e�k a2 +. It t ReD-ox(an U): _ Time: Appearance:—sfax nne: ReDox (EH value):YSI PTO Plus +200mV .a > 9, &� Other: T e' Genera .I/WeatherObservations: cloudy/rainy) Temp. 3 (°F) Wind. 0' `--imphl p �--Date: Sampler Signature: �"��`�- / btabiazatfon Time o reLy Temp. e Diss Oxy. (ntg/L) Spec. Cored. (US) pH (s. u.) V) T (ntu) Volume removed (gallons/mis) er Wat level (it) . Other Date Issued: March &, 2019 Docunieut Name: Field data Sbeet Page; 1 of 0 ,. 8CBA11r71y/ICal Issuing Authority: Pare Huntersvillo Quality Dmumebt Number: F-CAR-FI.D-001-revAB Office /�� Field ata Sheet Client: 6 L Location: L L 0 d L! Project Name and Affiliation (Sampler(s): 'r'1'/ n c d Field Data Sheet Review: Name and Affiliation (Inspector): ��-- )yl 123 �IIM � � By: Date: Well Information' oil l I q ) Z3 " Well ID: Well Locked: YES)/ NO /,Flushmaunt) Well Diameter: Construction: (PVQSteel/Stahiless Steel) Total Well Depth: 4 7 it Multi Factor*: / 1 (Radius/12)2 x 3.14 x 2.aa1 Static Water Level: 4- 6 t` ft Casing Volume: D r 0 H-o -71 gallons Height of Water Column: L' �It Cal. 3 Volumes; �) 1 a gallons I -�\ Pump Intake It Pur eg Infori3ration Date Purged: /"'Finish: Purge Rate: Purging Method:_ Total Volume Purge_ d: ®� (gallons/cols/1) Sampling Information Date Collected: 11 f�/ /1 Time Collected:_ _ (am/pin) Sampling, Equipment Used: trument ID, Bottle Type Preservation Analysis Required Sample Temp (aG) Time:_ ... _Turbidity (ntu): Time; Diss Oxy (mg/L): Time: Fe 2+ mg/ L: Tune: Specific Cond. (uS): Time: Res. Cl (ing/L)/(µg/L): Time:__,^ Sample pH (s.u.):_ _ y _ (ilia - Odor:_,-- l ReDox (mV): Time: ~ Appearance: 'rime: ReDox (EH value):YSI ProPlus +200�m�/V Other: Time: General/Weather Observations IN^ %/ -I-✓1`L'r�%7C/r+'=:-' ' (sunny/cloudy/rainy) Temp. (°F) Wind (mph) Sampler Signature!%/6ti�- Date: />- 3 �i4ahiliza4inn'TecF Time Purged Temp. � (°C) Diss Oxy. (rng/L� Spec,. Cond. (u�) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Monitoring Wells Project Number: J22-14175-07 Lot Number:YD14071 Date Completed:05/09/2023 05/10/2023 1:59 PM Approved and released by: Project Manager II: Lucas Odom PC. F O 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 105 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: YD14071 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. VOCs by GCMS The laboratory control sample (LCS) for analytical batch 73539 recovered outside acceptance criteria for the following analytes: 1,2-Dibromo-3-chloropropane (DBCP). An LOQ standard was analyzed, and the target analyte was detected. Since the associated samples were non -detect, no corrective action was taken. The laboratory control sample (LCS) for analytical batch 73677, 73762, 73764 exceeded acceptance criteria for the following analytes: Acetone. These analytes were biased high and were not detected in the samples affected. The following samples were received with headspace in the sample vial: YD14071-001, YD14071-003, YD 14071-006, YD 14071-009, YD 14071-013, YD 14071-015, YD 14071-017, YD 14071-020, YD 14071-023. The vial with the least amount of volume has been used for analysis. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 105 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD14071 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-B Aqueous 04/13/20231035 04/14/2023 002 MW-3 Aqueous 04/13/20231650 04/14/2023 003 MW-4 Aqueous 04/13/20231105 04/14/2023 004 MW-4A Aqueous 04/13/20231430 04/14/2023 005 MW-5 Aqueous 04/13/20231420 04/14/2023 006 MW-6 Aqueous 04/13/20231645 04/14/2023 007 MW-6-192 Aqueous 04/13/20231600 04/14/2023 008 MW-7 Aqueous 04/12/20231715 04/14/2023 009 MW-8 Aqueous 04/13/20231705 04/14/2023 010 MW-12-25 Aqueous 04/13/20231205 04/14/2023 011 MW-13-35 Aqueous 04/13/20231345 04/14/2023 012 MW-13-132 Aqueous 04/13/20231305 04/14/2023 013 MW-15 Aqueous 04/13/20231210 04/14/2023 014 MW-17-60 Aqueous 04/13/20231210 04/14/2023 015 MW-17-137 Aqueous 04/13/20231100 04/14/2023 016 MW-17-310 Aqueous 04/13/20231010 04/14/2023 017 MW-18-78 Aqueous 04/13/20231745 04/14/2023 018 MW-19-75 Aqueous 04/13/20231750 04/14/2023 019 MW-19-110 Aqueous 04/13/20231705 04/14/2023 020 MW-21-21 Aqueous 04/13/20231510 04/14/2023 021 MW-21-94 Aqueous 04/13/20231600 04/14/2023 022 MW-24-160 Aqueous 04/13/20231605 04/14/2023 023 Trip Blank Aqueous 04/13/2023 04/14/2023 (23 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 105 PACE ANALYTICAL SERVICES, LLC Sample Sample ID Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD14071 Matrix Parameter Method Result Q Units Page 001 MW-B Aqueous 1,4-Dioxane 8260D (SIM) 22 ug/L 15 001 MW-B Aqueous Chlorobenzene 8260D 0.70 J ug/L 15 001 MW-B Aqueous 1,4-Dichlorobenzene 8260D 1.0 ug/L 15 001 MW-B Aqueous 1,1-Dichloroethane 8260D 0.54 J ug/L 15 001 MW-B Aqueous cis- 1,2-Dichloroethene 8260D 6.1 ug/L 15 001 MW-B Aqueous Vinyl chloride 8260D 5.1 ug/L 16 001 MW-B Aqueous Barium 6020E 270 ug/L 16 001 MW-B Aqueous Chromium 6020E 30 ug/L 16 001 MW-B Aqueous Nickel 6020B 15 ug/L 16 002 MW-3 Aqueous 1,4-Dioxane 8260D (SIM) 87 ug/L 18 002 MW-3 Aqueous Benzene 8260D 1.1 ug/L 18 002 MW-3 Aqueous Chlorobenzene 8260D 3.9 ug/L 18 002 MW-3 Aqueous Chloroethane 8260D 2.1 ug/L 18 002 MW-3 Aqueous 1,2-Dichlorobenzene 8260D 0.66 J ug/L 18 002 MW-3 Aqueous 1,4-Dichlorobenzene 8260D 7.1 ug/L 18 002 MW-3 Aqueous 1,1-Dichloroethane 8260D 0.91 J ug/L 18 002 MW-3 Aqueous cis- 1,2-Dichloroethene 8260D 0.59 J ug/L 18 002 MW-3 Aqueous Xylenes (total) 8260D 0.69 J ug/L 19 002 MW-3 Aqueous Antimony 6020E 0.50 J ug/L 19 002 MW-3 Aqueous Barium 6020B 210 ug/L 19 002 MW-3 Aqueous Cobalt 6020B 15 ug/L 19 002 MW-3 Aqueous Nickel 6020E 34 ug/L 19 003 MW-4 Aqueous 1,4-Dioxane 8260D (SIM) 15 ug/L 21 003 MW-4 Aqueous Benzene 8260D 0.89 J ug/L 21 003 MW-4 Aqueous Chlorobenzene 8260D 4.2 ug/L 21 003 MW-4 Aqueous Chloroethane 8260D 1.6 J ug/L 21 003 MW-4 Aqueous 1,2-Dichlorobenzene 8260D 0.59 J ug/L 21 003 MW-4 Aqueous 1,4-Dichlorobenzene 8260D 9.2 ug/L 21 003 MW-4 Aqueous 1,1-Dichloroethane 8260D 4.8 ug/L 21 003 MW-4 Aqueous 1,2-Dichloroethane 8260D 0.40 J ug/L 21 003 MW-4 Aqueous cis- 1,2-Dichloroethene 8260D 13 ug/L 21 003 MW-4 Aqueous Trichloroethene 8260D 0.61 J ug/L 22 003 MW-4 Aqueous Vinyl chloride 8260D 2.4 ug/L 22 003 MW-4 Aqueous Barium 6020E 480 ug/L 22 003 MW-4 Aqueous Cadmium 6020B 2.1 ug/L 22 003 MW-4 Aqueous Chromium 6020B 1.9 J ug/L 22 003 MW-4 Aqueous Cobalt 6020E 48 ug/L 22 003 MW-4 Aqueous Nickel 6020E 72 ug/L 22 003 MW-4 Aqueous Thallium 6020B 0.16 J ug/L 23 003 MW-4 Aqueous Zinc 6020B 15 ug/L 23 004 MW-4A Aqueous 1,4-Dioxane 8260D (SIM) 5.6 ug/L 24 004 MW-4A Aqueous Benzene 8260D 4.4 ug/L 24 004 MW-4A Aqueous Chlorobenzene 8260D 35 ug/L 24 004 MW-4A Aqueous 1,2-Dichlorobenzene 8260D 3.8 ug/L 24 004 MW-4A Aqueous 1,4-Dichlorobenzene 8260D 13 ug/L 24 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 105 Detection Summary (Continued) Lot Number: YD14071 Sample Sample ID Matrix Parameter Method Result Q Units 004 MW-4A Aqueous Ethylbenzene 8260D 1.0 ug/L 004 MW-4A Aqueous Toluene 8260D 0.84 J ug/L 004 MW-4A Aqueous Vinyl chloride 8260D 0.40 J ug/L 004 MW-4A Aqueous Xylenes (total) 8260D 2.0 ug/L 004 MW-4A Aqueous Barium 6020B 720 ug/L 004 MW-4A Aqueous Cobalt 6020B 43 ug/L 004 MW-4A Aqueous Copper 6020E 4.3 J ug/L 004 MW-4A Aqueous Nickel 6020E 7.3 ug/L 004 MW-4A Aqueous Zinc 6020B 3.5 J ug/L 005 MW-5 Aqueous 1,4-Dioxane 8260D (SIM) 86 ug/L 005 MW-5 Aqueous Benzene 8260D 0.79 J ug/L 005 MW-5 Aqueous Chlorobenzene 8260D 11 ug/L 005 MW-5 Aqueous Chloroethane 8260D 1.1 J ug/L 005 MW-5 Aqueous 1,4-Dichlorobenzene 8260D 4.1 ug/L 005 MW-5 Aqueous Barium 6020E 200 ug/L 005 MW-5 Aqueous Cobalt 6020E 14 ug/L 005 MW-5 Aqueous Nickel 6020B 29 ug/L 005 MW-5 Aqueous Zinc 6020E 2.9 J ug/L 006 MW-6 Aqueous 1,4-Dioxane 8260D (SIM) 41 ug/L 006 MW-6 Aqueous Benzene 8260D 1.4 ug/L 006 MW-6 Aqueous Chlorobenzene 8260D 10 ug/L 006 MW-6 Aqueous Chloroethane 8260D 2.6 ug/L 006 MW-6 Aqueous 1,4-Dichlorobenzene 8260D 4.1 ug/L 006 MW-6 Aqueous 1,1-Dichloroethane 8260D 1.4 ug/L 006 MW-6 Aqueous Toluene 8260D 0.42 J ug/L 006 MW-6 Aqueous Barium 6020E 1600 ug/L 006 MW-6 Aqueous Nickel 6020E 11 ug/L 006 MW-6 Aqueous Zinc 6020B 2.8 J ug/L 007 MW-6-192 Aqueous 1,4-Dioxane 8260D (SIM) 6.4 ug/L 007 MW-6-192 Aqueous Chlorobenzene 8260D 0.87 J ug/L 007 MW-6-192 Aqueous 1,1-Dichloroethane 8260D 0.72 J ug/L 007 MW-6-192 Aqueous Barium 6020B 64 ug/L 007 MW-6-192 Aqueous Nickel 6020E 1.3 J ug/L 008 MW-7 Aqueous Acetone 8260D 9.1 J ug/L 008 MW-7 Aqueous Benzene 8260D 1.1 ug/L 008 MW-7 Aqueous Chlorobenzene 8260D 4.6 ug/L 008 MW-7 Aqueous 1,4-Dichlorobenzene 8260D 0.97 J ug/L 008 MW-7 Aqueous 1,1-Dichloroethane 8260D 2.1 ug/L 008 MW-7 Aqueous cis- 1,2-Dichloroethene 8260D 9.4 ug/L 008 MW-7 Aqueous Barium 6020B 190 ug/L 008 MW-7 Aqueous Cadmium 6020E 0.27 J ug/L 008 MW-7 Aqueous Cobalt 6020E 150 ug/L 008 MW-7 Aqueous Copper 6020B 2.3 J ug/L 008 MW-7 Aqueous Nickel 6020B 39 ug/L 008 MW-7 Aqueous Zinc 6020E 8.8 J ug/L 009 MW-8 Aqueous 1,1-Dichloroethane 8260D 0.51 J ug/L 009 MW-8 Aqueous Barium 6020B 53 ug/L 009 MW-8 Aqueous Cadmium 6020E 0.13 J ug/L Page 25 25 25 25 25 25 25 25 26 27 27 27 27 27 28 28 28 29 30 30 30 30 30 30 31 31 31 32 33 33 33 34 34 36 36 36 36 36 36 37 37 37 37 37 37 38 39 39 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 105 Detection Summary (Continued) Lot Number: YD14071 Sample Sample ID Matrix Parameter Method Result Q Units 009 MW-8 Aqueous Chromium 6020E 2.8 J ug/L 009 MW-8 Aqueous Copper 6020B 6.0 ug/L 009 MW-8 Aqueous Lead 6020E 1.1 ug/L 009 MW-8 Aqueous Nickel 6020E 3.4 J ug/L 009 MW-8 Aqueous Silver 6020B 0.44 J ug/L 009 MW-8 Aqueous Vanadium 6020B 3.8 J ug/L 009 MW-8 Aqueous Zinc 6020E 14 ug/L 010 MW-12-25 Aqueous Acetone 8260D 5.5 JL ug/L 010 MW-12-25 Aqueous Barium 6020B 47 ug/L 010 MW-12-25 Aqueous Cadmium 6020B 0.13 J ug/L 010 MW-12-25 Aqueous Chromium 6020E 5.0 ug/L 010 MW-12-25 Aqueous Copper 6020E 1.4 J ug/L 010 MW-12-25 Aqueous Nickel 6020B 19 ug/L 010 MW-12-25 Aqueous Zinc 6020B 11 ug/L 011 MW-13-35 Aqueous Acetone 8260D 12 JL ug/L 011 MW-13-35 Aqueous Benzene 8260D 1.4 ug/L 011 MW-13-35 Aqueous Chlorobenzene 8260D 5.6 ug/L 011 MW-13-35 Aqueous 1,2-Dichlorobenzene 8260D 3.0 ug/L 011 MW-13-35 Aqueous 1,4-Dichlorobenzene 8260D 14 ug/L 011 MW-13-35 Aqueous cis- 1,2-Dichloroethene 8260D 2.2 ug/L 011 MW-13-35 Aqueous Barium 6020B 190 ug/L 011 MW-13-35 Aqueous Cobalt 6020E 1.7 J ug/L 011 MW-13-35 Aqueous Nickel 6020E 5.0 ug/L 011 MW-13-35 Aqueous Zinc 6020B 6.3 J ug/L 012 MW-13-132 Aqueous 1,1-Dichloroethane 8260D 1.0 ug/L 012 MW-13-132 Aqueous cis- 1,2-Dichloroethene 8260D 7.7 ug/L 012 MW-13-132 Aqueous Barium 6020E 48 ug/L 012 MW-13-132 Aqueous Zinc 6020B 3.9 J ug/L 013 MW-15 Aqueous Acetone 8260D 18 JL ug/L 013 MW-15 Aqueous Barium 6020E 230 ug/L 013 MW-15 Aqueous Chromium 6020E 14 ug/L 013 MW-15 Aqueous Lead 6020B 1.5 ug/L 013 MW-15 Aqueous Zinc 6020E 3.7 J ug/L 014 MW-17-60 Aqueous 1,4-Dioxane 8260D (SIM) 21 ug/L 014 MW-17-60 Aqueous 1,1-Dichloroethane 8260D 0.86 J ug/L 014 MW-17-60 Aqueous cis- 1,2-Dichloroethene 8260D 1.2 ug/L 014 MW-17-60 Aqueous Vinyl chloride 8260D 0.57 J ug/L 014 MW-17-60 Aqueous Antimony 6020E 1.1 J ug/L 014 MW-17-60 Aqueous Barium 6020B 22 ug/L 014 MW-17-60 Aqueous Nickel 6020B 1.3 J ug/L 015 MW-17-137 Aqueous 1,4-Dioxane 8260D (SIM) 34 ug/L 015 MW-17-137 Aqueous 1,1-Dichloroethane 8260D 0.69 J ug/L 015 MW-17-137 Aqueous Xylenes (total) 8260D 0.65 J ug/L 015 MW-17-137 Aqueous Barium 6020B 28 ug/L 016 MW-17-310 Aqueous Barium 6020E 3.3 J ug/L 016 MW-17-310 Aqueous Lead 6020B 0.30 J ug/L 016 MW-17-310 Aqueous Zinc 6020B 3.1 J ug/L 017 MW-18-78 Aqueous 1,4-Dioxane 8260D (SIM) 21 ug/L Page 39 39 39 39 40 40 40 41 42 42 42 42 42 42 43 43 43 43 43 43 44 44 44 44 45 45 46 46 47 48 48 48 48 49 49 49 50 50 50 50 52 52 53 53 56 56 56 57 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 105 Detection Summary (Continued) Lot Number: YD14071 Sample Sample ID Matrix Parameter Method Result Q Units 017 MW-18-78 Aqueous Chlorobenzene 8260D 1.6 ug/L 017 MW-18-78 Aqueous 1,4-Dichlorobenzene 8260D 0.99 J ug/L 017 MW-18-78 Aqueous 1,1-Dichloroethane 8260D 0.52 J ug/L 017 MW-18-78 Aqueous Barium 6020E 38 ug/L 017 MW-18-78 Aqueous Cadmium 6020B 0.20 J ug/L 017 MW-18-78 Aqueous Chromium 6020B 2.5 J ug/L 017 MW-18-78 Aqueous Nickel 6020E 3.4 J ug/L 017 MW-18-78 Aqueous Thallium 6020E 0.22 J ug/L 018 MW-19-75 Aqueous 1,4-Dioxane 8260D (SIM) 53 ug/L 018 MW-19-75 Aqueous Chlorobenzene 8260D 2.8 ug/L 018 MW-19-75 Aqueous 1,4-Dichlorobenzene 8260D 2.5 ug/L 018 MW-19-75 Aqueous 1,1-Dichloroethane 8260D 0.46 J ug/L 018 MW-19-75 Aqueous 1,2,3-Trichloropropane 8260D 3.4 ug/L 018 MW-19-75 Aqueous Barium 6020B 96 ug/L 018 MW-19-75 Aqueous Chromium 6020E 6.8 ug/L 018 MW-19-75 Aqueous Nickel 6020E 20 ug/L 018 MW-19-75 Aqueous Zinc 6020B 6.6 J ug/L 019 MW-19-110 Aqueous 1,4-Dioxane 8260D (SIM) 31 ug/L 019 MW-19-110 Aqueous Chlorobenzene 8260D 0.86 J ug/L 019 MW-19-110 Aqueous Chloroethane 8260D 0.74 J ug/L 019 MW-19-110 Aqueous 1,4-Dichlorobenzene 8260D 0.65 J ug/L 019 MW-19-110 Aqueous cis- 1,2-Dichloroethene 8260D 0.78 J ug/L 019 MW-19-110 Aqueous Barium 6020E 12 ug/L 019 MW-19-110 Aqueous Chromium 6020B 1.3 J ug/L 019 MW-19-110 Aqueous Nickel 6020B 4.6 J ug/L 019 MW-19-110 Aqueous Zinc 6020E 2.7 J ug/L 020 MW-21-21 Aqueous 1,4-Dioxane 8260D (SIM) 66 ug/L 020 MW-21-21 Aqueous Benzene 8260D 2.0 ug/L 020 MW-21-21 Aqueous Chlorobenzene 8260D 5.2 ug/L 020 MW-21-21 Aqueous 1,2-Dichlorobenzene 8260D 1.2 ug/L 020 MW-21-21 Aqueous 1,4-Dichlorobenzene 8260D 11 ug/L 020 MW-21-21 Aqueous 1,1-Dichloroethane 8260D 1.1 ug/L 020 MW-21-21 Aqueous cis- 1,2-Dichloroethene 8260D 1.8 ug/L 020 MW-21-21 Aqueous 1,2,3-Trichloropropane 8260D 3.2 ug/L 020 MW-21-21 Aqueous Vinyl chloride 8260D 1.3 ug/L 020 MW-21-21 Aqueous Barium 6020B 110 ug/L 020 MW-21-21 Aqueous Chromium 6020E 4.2 J ug/L 020 MW-21-21 Aqueous Cobalt 6020E 9.7 ug/L 020 MW-21-21 Aqueous Nickel 6020B 4.9 J ug/L 021 MW-21-94 Aqueous 1,4-Dioxane 8260D (SIM) 39 ug/L 021 MW-21-94 Aqueous Chlorobenzene 8260D 1.0 ug/L 021 MW-21-94 Aqueous Chloroethane 8260D 2.3 ug/L 021 MW-21-94 Aqueous 1,4-Dichlorobenzene 8260D 1.0 ug/L 021 MW-21-94 Aqueous cis- 1,2-Dichloroethene 8260D 0.79 J ug/L 021 MW-21-94 Aqueous Vinyl chloride 8260D 1.2 ug/L 021 MW-21-94 Aqueous Barium 6020B 47 ug/L 021 MW-21-94 Aqueous Nickel 6020B 6.9 ug/L 022 MW-24-160 Aqueous Acetone 8260D 6.0 JL ug/L Page 57 57 57 58 58 58 58 59 60 60 60 60 61 61 61 61 62 63 63 63 63 63 64 64 64 65 66 66 66 66 66 66 66 67 67 67 67 67 67 69 69 69 69 69 70 70 70 72 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 105 Detection Summary (Continued) Lot Number: YD14071 Sample Sample ID Matrix Parameter Method Result Q Units Page 022 MW-24-160 Aqueous Antimony 6020E 0.57 J ug/L 73 022 MW-24-160 Aqueous Barium 6020B 23 ug/L 73 022 MW-24-160 Aqueous Beryllium 6020E 0.33 J ug/L 73 022 MW-24-160 Aqueous Chromium 6020E 6.3 ug/L 73 022 MW-24-160 Aqueous Copper 6020B 2.4 J ug/L 73 022 MW-24-160 Aqueous Lead 6020B 3.7 ug/L 73 022 MW-24-160 Aqueous Nickel 6020E 8.1 ug/L 73 022 MW-24-160 Aqueous Zinc 6020E 19 ug/L 73 (197 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-001 Description: MW-B Matrix: Aqueous Date Sampled:04/13/2023 1035 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/25/2023 2211 CDA 73638 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 22 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0312 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.70 J 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.0 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.54 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 6.1 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-001 Description: MW-B Matrix: Aqueous Date Sampled:04/13/2023 1035 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0312 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 5.1 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 92 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0155 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 270 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 30 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 15 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-001 Description: MW-B Matrix: Aqueous Date Sampled:04/13/2023 1035 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0155 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-002 Description: MW-3 Matrix: Aqueous Date Sampled:04/13/2023 1650 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2120 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 87 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 121 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0337 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.1 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 3.9 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.1 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.66 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 7.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.91 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.59 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-002 Description: MW-3 Matrix: Aqueous Date Sampled:04/13/2023 1650 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0337 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.69 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0215 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.50 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 210 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 15 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 34 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-002 Description: MW-3 Matrix: Aqueous Date Sampled:04/13/2023 1650 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0215 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-003 Description: MW-4 Matrix: Aqueous Date Sampled:04/13/2023 1105 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2144 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 15 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 121 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0402 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.89 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 4.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.6 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.59 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 9.2 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 4.8 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.40 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 13 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-003 Description: MW-4 Matrix: Aqueous Date Sampled:04/13/2023 1105 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0402 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.61 J 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 2.4 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 84 70-130 Toluene-d8 89 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0222 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 480 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 2.1 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.9 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 48 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 72 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-003 Description: MW-4 Matrix: Aqueous Date Sampled:04/13/2023 1105 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0222 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B 0.16 J 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 15 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-004 Description: MW-4A Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2207 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 5.6 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 121 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0427 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 4.4 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 35 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 3.8 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 13 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-004 Description: MW-4A Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0427 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D 1.0 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 0.84 J 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.40 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 2.0 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 77 70-130 Toluene-d8 84 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0229 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 720 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 43 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 7.3 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-004 Description: MW-4A Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0229 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-005 Description: MW-5 Matrix: Aqueous Date Sampled:04/13/2023 1420 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2232 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 86 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 120 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0452 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.79 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 11 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.1 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-005 Description: MW-5 Matrix: Aqueous Date Sampled:04/13/2023 1420 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0452 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 83 70-130 Toluene-d8 89 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0235 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 200 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 14 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 29 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-005 Description: MW-5 Matrix: Aqueous Date Sampled:04/13/2023 1420 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0235 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-006 Description: MW-6 Matrix: Aqueous Date Sampled:04/13/2023 1645 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2255 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 41 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 120 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0517 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.4 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 10 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.6 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND L 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.4 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-006 Description: MW-6 Matrix: Aqueous Date Sampled:04/13/2023 1645 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 0517 JMM2 73539 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 0.42 J 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 79 70-130 Toluene-d8 85 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0242 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 1600 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-006 Description: MW-6 Matrix: Aqueous Date Sampled:04/13/2023 1645 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0242 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-007 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2319 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.4 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 119 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1242 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.87 J 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.72 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-007 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1242 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0249 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 64 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.3 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-007 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0249 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-008 Description: MW-7 Matrix: Aqueous Date Sampled:04/12/2023 1715 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0213 CDA 73641 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 9.1 J 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.1 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 4.6 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 0.97 J 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 2.1 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 9.4 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-008 Description: MW-7 Matrix: Aqueous Date Sampled:04/12/2023 1715 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0213 CDA 73641 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0256 BNW 04/17/2023 1755 72771 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.27 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 150 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 39 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-009 Description: MW-8 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/26/2023 2344 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 121 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1305 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.51 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-009 Description: MW-8 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1305 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0316 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 53 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.13 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 6.0 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.1 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.4 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-009 Description: MW-8 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0316 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 0.44 J 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.8 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 14 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-010 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/13/2023 1205 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1327 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.5 JL 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-010 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/13/2023 1205 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1327 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 103 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0336 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 47 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.13 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 19 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-011 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/13/2023 1345 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1349 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 12 JL 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.4 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 5.6 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D 3.0 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 14 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 2.2 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-011 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/13/2023 1345 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1349 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0343 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.7 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.3 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-012 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/13/2023 1305 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231411 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.0 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 7.7 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-012 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/13/2023 1305 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231411 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0350 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 48 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-013 Description: MW-15 Matrix: Aqueous Date Sampled:04/13/2023 1210 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1433 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 18 JL 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-013 Description: MW-15 Matrix: Aqueous Date Sampled:04/13/2023 1210 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1433 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0356 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 230 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 14 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.5 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-014 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/13/2023 1210 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0008 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 21 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 120 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1456 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.86 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.2 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-014 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/13/2023 1210 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1456 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.57 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0430 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.1 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 22 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.3 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-014 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/13/2023 1210 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0430 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-015 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/13/2023 1100 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0031 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 34 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 120 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1518 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.69 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-015 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/13/2023 1100 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1518 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.65 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0437 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 28 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-015 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/13/2023 1100 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0437 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-016 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/13/2023 1010 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1540 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-016 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/13/2023 1010 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1540 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0457 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 3.3 J 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.30 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-017 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/13/2023 1745 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0056 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 21 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 120 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1602 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.6 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.99 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.52 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-017 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/13/2023 1745 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1602 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0504 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 38 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.20 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.4 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-017 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/13/2023 1745 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0504 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B 0.22 J 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-018 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/13/2023 1750 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0119 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 53 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 122 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 2321 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 2.8 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.5 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.46 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-018 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/13/2023 1750 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 2321 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 3.4 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0511 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 96 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 6.8 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 20 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-018 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/13/2023 1750 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0511 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-019 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0143 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 31 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 121 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1625 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.86 J 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.74 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.65 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.78 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-019 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1625 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0518 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 12 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.6 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-019 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/13/2023 1705 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0518 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-020 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/13/2023 1510 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0207 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 66 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 122 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 2343 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 2.0 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 5.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 1.2 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 11 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.1 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.8 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-020 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/13/2023 1510 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 2343 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 3.2 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.3 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0524 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.2 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 9.7 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.9 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-020 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/13/2023 1510 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0524 BNW 04/17/2023 1751 72772 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-021 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0231 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 39 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 124 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1647 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.0 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.3 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.0 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.79 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-021 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1647 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.2 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0612 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 47 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 6.9 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-021 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/13/2023 1600 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0612 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-022 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/13/2023 1605 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1709 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 6.0 JL 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-022 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/13/2023 1605 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1709 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 106 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0618 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.57 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 23 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.33 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 6.3 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 3.7 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.1 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 19 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-023 Description: Trip Blank Matrix: Aqueous Date Sampled:04/13/2023 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1135 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 105 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14071-023 Description: Trip Blank Matrix: Aqueous Date Sampled:04/13/2023 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1135 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 98 70-130 104 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 105 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73539-001 Matrix: Aqueous Batch: 73539 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/24/2023 2148 Acrylonitrile ND 1 20 0.80 ug/L 04/24/2023 2148 Benzene ND 1 1.0 0.40 ug/L 04/24/2023 2148 Bromochloromethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 Bromoform ND 1 1.0 0.40 ug/L 04/24/2023 2148 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/24/2023 2148 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/24/2023 2148 Carbon disulfide ND 1 1.0 0.40 ug/L 04/24/2023 2148 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/24/2023 2148 Chlorobenzene ND 1 1.0 0.40 ug/L 04/24/2023 2148 Chloroethane ND 1 2.0 0.40 ug/L 04/24/2023 2148 Chloroform ND 1 1.0 0.40 ug/L 04/24/2023 2148 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/24/2023 2148 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/24/2023 2148 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/24/2023 2148 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/24/2023 2148 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/24/2023 2148 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/24/2023 2148 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/24/2023 2148 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/24/2023 2148 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/24/2023 2148 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/24/2023 2148 Ethylbenzene ND 1 1.0 0.40 ug/L 04/24/2023 2148 2-Hexanone ND 1 10 2.0 ug/L 04/24/2023 2148 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/24/2023 2148 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/24/2023 2148 Methylene chloride ND 1 1.0 0.40 ug/L 04/24/2023 2148 Styrene ND 1 1.0 0.41 ug/L 04/24/2023 2148 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/24/2023 2148 Toluene ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 Trichloroethene ND 1 1.0 0.40 ug/L 04/24/2023 2148 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/24/2023 2148 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/24/2023 2148 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73539-001 Matrix: Aqueous Batch: 73539 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/24/2023 2148 Vinyl chloride ND 1 1.0 0.40 ug/L 04/24/2023 2148 Xylenes (total) ND 1 1.0 0.40 ug/L 04/24/2023 2148 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 109 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73539-002 Matrix: Aqueous Batch: 73539 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 105 60-140 04/24/2023 2020 Acrylonitrile 100 91 1 91 70-130 04/24/2023 2020 Benzene 50 49 1 98 70-130 04/24/2023 2020 Bromochloromethane 50 48 1 97 70-130 04/24/2023 2020 Bromodichloromethane 50 53 1 105 70-130 04/24/2023 2020 Bromoform 50 50 1 101 70-130 04/24/2023 2020 Bromomethane (Methyl bromide) 50 48 1 97 70-130 04/24/2023 2020 2-Butanone (MEK) 100 100 1 101 70-130 04/24/2023 2020 Carbon disulfide 50 57 1 114 70-130 04/24/2023 2020 Carbon tetrachloride 50 53 1 106 70-130 04/24/2023 2020 Chlorobenzene 50 49 1 99 70-130 04/24/2023 2020 Chloroethane 50 51 1 101 70-130 04/24/2023 2020 Chloroform 50 51 1 101 70-130 04/24/2023 2020 Chloromethane (Methyl chloride) 50 49 1 98 60-140 04/24/2023 2020 1,2-Dibromo-3-chloropropane (DBCP) 50 32 N 1 64 70-130 04/24/2023 2020 Dibromochloromethane 50 53 1 107 70-130 04/24/2023 2020 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 04/24/2023 2020 Dibromomethane (Methylene bromide) 50 47 1 93 70-130 04/24/2023 2020 trans- 1,4-Dichloro-2-butene 50 54 1 108 70-130 04/24/2023 2020 1,2-Dichlorobenzene 50 43 1 87 70-130 04/24/2023 2020 1,4-Dichlorobenzene 50 47 1 94 70-130 04/24/2023 2020 1,1-Dichloroethane 50 49 1 98 70-130 04/24/2023 2020 1,2-Dichloroethane 50 48 1 96 70-130 04/24/2023 2020 1,1-Dichloroethene 50 56 1 111 70-130 04/24/2023 2020 cis- 1,2-Dichloroethene 50 48 1 96 70-130 04/24/2023 2020 trans- 1,2-Dichloroethene 50 48 1 97 70-130 04/24/2023 2020 1,2-Dichloropropane 50 49 1 98 70-130 04/24/2023 2020 cis- 1,3-Dichloropropene 50 55 1 111 70-130 04/24/2023 2020 trans- 1,3-Dichloropropene 50 48 1 95 70-130 04/24/2023 2020 Ethylbenzene 50 51 1 103 70-130 04/24/2023 2020 2-Hexanone 100 100 1 101 70-130 04/24/2023 2020 Methyl iodide (lodomethane) 50 56 1 112 70-130 04/24/2023 2020 4-Methyl-2-pentanone 100 99 1 99 70-130 04/24/2023 2020 Methylene chloride 50 55 1 111 70-130 04/24/2023 2020 Styrene 50 54 1 108 70-130 04/24/2023 2020 1,1,1,2-Tetrachloroethane 50 50 1 100 70-130 04/24/2023 2020 1,1,2,2-Tetrachloroethane 50 50 1 99 70-130 04/24/2023 2020 Tetrachloroethene 50 49 1 98 70-130 04/24/2023 2020 Toluene 50 50 1 101 70-130 04/24/2023 2020 1,1,1-Trichloroethane 50 53 1 105 70-130 04/24/2023 2020 1,1,2-Trichloroethane 50 47 1 94 70-130 04/24/2023 2020 Trichloroethene 50 51 1 101 70-130 04/24/2023 2020 Trichlorofluoromethane 50 55 1 110 70-130 04/24/2023 2020 1,2,3-Trichloropropane 50 45 1 91 70-130 04/24/2023 2020 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73539-002 Matrix: Aqueous Batch: 73539 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 48 1 96 60-140 04/24/2023 2020 Vinyl chloride 50 51 1 102 70-130 04/24/2023 2020 Xylenes (total) 100 100 1 103 70-130 04/24/2023 2020 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 92 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 105 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ73638-001 Matrix: Aqueous Batch:73638 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/25/2023 2104 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 82 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 105 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ73638-002 Matrix: Aqueous Batch:73638 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 47 1 95 70-130 04/25/20231931 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 66 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 105 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: YQ73638-003 Matrix: Aqueous Batch:73638 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 47 1 95 0.44 70-130 20 04/25/20231955 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 65 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73641-001 Matrix: Aqueous Batch: 73641 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/26/2023 0001 Acrylonitrile ND 1 20 0.80 ug/L 04/26/2023 0001 Benzene ND 1 1.0 0.40 ug/L 04/26/2023 0001 Bromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 Bromoform ND 1 1.0 0.40 ug/L 04/26/2023 0001 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/26/2023 0001 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/26/2023 0001 Carbon disulfide ND 1 1.0 0.40 ug/L 04/26/2023 0001 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/26/2023 0001 Chlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 0001 Chloroethane ND 1 2.0 0.40 ug/L 04/26/2023 0001 Chloroform ND 1 1.0 0.40 ug/L 04/26/2023 0001 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/26/2023 0001 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/26/2023 0001 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/26/2023 0001 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/26/2023 0001 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/26/2023 0001 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 0001 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 0001 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 0001 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 0001 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 0001 Ethylbenzene ND 1 1.0 0.40 ug/L 04/26/2023 0001 2-Hexanone ND 1 10 2.0 ug/L 04/26/2023 0001 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/26/2023 0001 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/26/2023 0001 Methylene chloride ND 1 1.0 0.40 ug/L 04/26/2023 0001 Styrene ND 1 1.0 0.41 ug/L 04/26/2023 0001 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/26/2023 0001 Toluene ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 Trichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 0001 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/26/2023 0001 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 0001 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73641-001 Matrix: Aqueous Batch:73641 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/26/2023 0001 Vinyl chloride ND 1 1.0 0.40 ug/L 04/26/2023 0001 Xylenes (total) ND 1 1.0 0.40 ug/L 04/26/2023 0001 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73641-002 Matrix: Aqueous Batch: 73641 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 107 60-140 04/25/2023 1947 Acrylonitrile 100 97 1 97 70-130 04/25/2023 1947 Benzene 50 46 1 93 70-130 04/25/2023 1947 Bromochloromethane 50 46 1 93 70-130 04/25/2023 1947 Bromodichloromethane 50 46 1 91 70-130 04/25/2023 1947 Bromoform 50 46 1 93 70-130 04/25/2023 1947 Bromomethane (Methyl bromide) 50 44 1 88 70-130 04/25/2023 1947 2-Butanone (MEK) 100 110 1 105 70-130 04/25/2023 1947 Carbon disulfide 50 46 1 92 70-130 04/25/2023 1947 Carbon tetrachloride 50 47 1 94 70-130 04/25/2023 1947 Chlorobenzene 50 49 1 98 70-130 04/25/2023 1947 Chloroethane 50 48 1 97 70-130 04/25/2023 1947 Chloroform 50 45 1 90 70-130 04/25/2023 1947 Chloromethane (Methyl chloride) 50 46 1 93 60-140 04/25/2023 1947 1,2-Dibromo-3-chloropropane (DBCP) 50 49 1 98 70-130 04/25/2023 1947 Dibromochloromethane 50 48 1 96 70-130 04/25/2023 1947 1,2-Dibromoethane (EDB) 50 48 1 97 70-130 04/25/2023 1947 Dibromomethane (Methylene bromide) 50 47 1 95 70-130 04/25/2023 1947 trans- 1,4-Dichloro-2-butene 50 47 1 94 70-130 04/25/2023 1947 1,2-Dichlorobenzene 50 50 1 100 70-130 04/25/2023 1947 1,4-Dichlorobenzene 50 48 1 97 70-130 04/25/2023 1947 1,1-Dichloroethane 50 46 1 93 70-130 04/25/2023 1947 1,2-Dichloroethane 50 46 1 93 70-130 04/25/2023 1947 1,1-Dichloroethene 50 46 1 92 70-130 04/25/2023 1947 cis- 1,2-Dichloroethene 50 46 1 92 70-130 04/25/2023 1947 trans- 1,2-Dichloroethene 50 47 1 94 70-130 04/25/2023 1947 1,2-Dichloropropane 50 46 1 92 70-130 04/25/2023 1947 cis- 1,3-Dichloropropene 50 47 1 93 70-130 04/25/2023 1947 trans- 1,3-Dichloropropene 50 49 1 97 70-130 04/25/2023 1947 Ethylbenzene 50 49 1 98 70-130 04/25/2023 1947 2-Hexanone 100 98 1 98 70-130 04/25/2023 1947 Methyl iodide (lodomethane) 50 45 1 91 70-130 04/25/2023 1947 4-Methyl-2-pentanone 100 92 1 92 70-130 04/25/2023 1947 Methylene chloride 50 45 1 89 70-130 04/25/2023 1947 Styrene 50 49 1 98 70-130 04/25/2023 1947 1,1,1,2-Tetrachloroethane 50 49 1 97 70-130 04/25/2023 1947 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 04/25/2023 1947 Tetrachloroethene 50 50 1 99 70-130 04/25/2023 1947 Toluene 50 50 1 99 70-130 04/25/2023 1947 1,1,1-Trichloroethane 50 46 1 91 70-130 04/25/2023 1947 1,1,2-Trichloroethane 50 49 1 98 70-130 04/25/2023 1947 Trichloroethene 50 47 1 93 70-130 04/25/2023 1947 Trichlorofluoromethane 50 48 1 95 70-130 04/25/2023 1947 1,2,3-Trichloropropane 50 51 1 102 70-130 04/25/2023 1947 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73641-002 Matrix: Aqueous Batch:73641 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 46 1 92 60-140 04/25/2023 1947 Vinyl chloride 50 50 1 101 70-130 04/25/2023 1947 Xylenes (total) 100 99 1 99 70-130 04/25/2023 1947 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73677-001 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/26/2023 1009 Acrylonitrile ND 1 20 0.80 ug/L 04/26/2023 1009 Benzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromoform ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/26/2023 1009 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/26/2023 1009 Carbon disulfide ND 1 1.0 0.40 ug/L 04/26/2023 1009 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chloroethane ND 1 2.0 0.40 ug/L 04/26/2023 1009 Chloroform ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/26/2023 1009 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/26/2023 1009 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 1009 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Ethylbenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 2-Hexanone ND 1 10 2.0 ug/L 04/26/2023 1009 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/26/2023 1009 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/26/2023 1009 Methylene chloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Styrene ND 1 1.0 0.41 ug/L 04/26/2023 1009 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Toluene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Trichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 1009 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73677-001 Matrix: Aqueous Batch:73677 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/26/2023 1009 Vinyl chloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Xylenes (total) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73677-002 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 160 N 1 162 60-140 04/26/2023 0822 Acrylonitrile 100 98 1 98 70-130 04/26/2023 0822 Benzene 50 44 1 87 70-130 04/26/2023 0822 Bromochloromethane 50 44 1 89 70-130 04/26/2023 0822 Bromodichloromethane 50 45 1 90 70-130 04/26/2023 0822 Bromoform 50 48 1 95 70-130 04/26/2023 0822 Bromomethane (Methyl bromide) 50 45 1 91 70-130 04/26/2023 0822 2-Butanone (MEK) 100 120 1 115 70-130 04/26/2023 0822 Carbon disulfide 50 41 1 81 70-130 04/26/2023 0822 Carbon tetrachloride 50 42 1 83 70-130 04/26/2023 0822 Chlorobenzene 50 46 1 91 70-130 04/26/2023 0822 Chloroethane 50 50 1 100 70-130 04/26/2023 0822 Chloroform 50 43 1 86 70-130 04/26/2023 0822 Chloromethane (Methyl chloride) 50 49 1 98 60-140 04/26/2023 0822 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 97 70-130 04/26/2023 0822 Dibromochloromethane 50 49 1 98 70-130 04/26/2023 0822 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 04/26/2023 0822 Dibromomethane (Methylene bromide) 50 47 1 94 70-130 04/26/2023 0822 trans- 1,4-Dichloro-2-butene 50 52 1 104 70-130 04/26/2023 0822 1,2-Dichlorobenzene 50 48 1 96 70-130 04/26/2023 0822 1,4-Dichlorobenzene 50 47 1 94 70-130 04/26/2023 0822 1,1-Dichloroethane 50 43 1 87 70-130 04/26/2023 0822 1,2-Dichloroethane 50 46 1 92 70-130 04/26/2023 0822 1,1-Dichloroethene 50 40 1 80 70-130 04/26/2023 0822 cis- 1,2-Dichloroethene 50 43 1 87 70-130 04/26/2023 0822 trans- 1,2-Dichloroethene 50 43 1 85 70-130 04/26/2023 0822 1,2-Dichloropropane 50 45 1 89 70-130 04/26/2023 0822 cis- 1,3-Dichloropropene 50 46 1 92 70-130 04/26/2023 0822 trans- 1,3-Dichloropropene 50 49 1 98 70-130 04/26/2023 0822 Ethylbenzene 50 45 1 90 70-130 04/26/2023 0822 2-Hexanone 100 100 1 100 70-130 04/26/2023 0822 Methyl iodide (lodomethane) 50 42 1 84 70-130 04/26/2023 0822 4-Methyl-2-pentanone 100 92 1 92 70-130 04/26/2023 0822 Methylene chloride 50 43 1 86 70-130 04/26/2023 0822 Styrene 50 46 1 92 70-130 04/26/2023 0822 1,1,1,2-Tetrachloroethane 50 46 1 92 70-130 04/26/2023 0822 1,1,2,2-Tetrachloroethane 50 51 1 102 70-130 04/26/2023 0822 Tetrachloroethene 50 45 1 90 70-130 04/26/2023 0822 Toluene 50 46 1 92 70-130 04/26/2023 0822 1,1,1-Trichloroethane 50 42 1 84 70-130 04/26/2023 0822 1,1,2-Trichloroethane 50 48 1 97 70-130 04/26/2023 0822 Trichloroethene 50 43 1 86 70-130 04/26/2023 0822 Trichlorofluoromethane 50 49 1 98 70-130 04/26/2023 0822 1,2,3-Trichloropropane 50 49 1 97 70-130 04/26/2023 0822 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73677-002 Matrix: Aqueous Batch:73677 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 48 1 96 60-140 04/26/2023 0822 Vinyl chloride 50 53 1 105 70-130 04/26/2023 0822 Xylenes (total) 100 92 1 92 70-130 04/26/2023 0822 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73762-001 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/26/2023 2209 Acrylonitrile ND 1 20 0.80 ug/L 04/26/2023 2209 Benzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromoform ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/26/2023 2209 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/26/2023 2209 Carbon disulfide ND 1 1.0 0.40 ug/L 04/26/2023 2209 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chloroethane ND 1 2.0 0.40 ug/L 04/26/2023 2209 Chloroform ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/26/2023 2209 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/26/2023 2209 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 2209 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Ethylbenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 2-Hexanone ND 1 10 2.0 ug/L 04/26/2023 2209 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/26/2023 2209 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/26/2023 2209 Methylene chloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Styrene ND 1 1.0 0.41 ug/L 04/26/2023 2209 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Toluene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Trichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 2209 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 105 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73762-001 Matrix: Aqueous Batch:73762 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/26/2023 2209 Vinyl chloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Xylenes (total) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73762-002 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 170 N 1 166 60-140 04/26/2023 2035 Acrylonitrile 100 110 1 106 70-130 04/26/2023 2035 Benzene 50 52 1 104 70-130 04/26/2023 2035 Bromochloromethane 50 51 1 102 70-130 04/26/2023 2035 Bromodichloromethane 50 51 1 102 70-130 04/26/2023 2035 Bromoform 50 50 1 100 70-130 04/26/2023 2035 Bromomethane (Methyl bromide) 50 49 1 98 70-130 04/26/2023 2035 2-Butanone (MEK) 100 120 1 124 70-130 04/26/2023 2035 Carbon disulfide 50 54 1 107 70-130 04/26/2023 2035 Carbon tetrachloride 50 52 1 104 70-130 04/26/2023 2035 Chlorobenzene 50 53 1 107 70-130 04/26/2023 2035 Chloroethane 50 54 1 109 70-130 04/26/2023 2035 Chloroform 50 50 1 99 70-130 04/26/2023 2035 Chloromethane (Methyl chloride) 50 52 1 105 60-140 04/26/2023 2035 1,2-Dibromo-3-chloropropane (DBCP) 50 54 1 108 70-130 04/26/2023 2035 Dibromochloromethane 50 53 1 107 70-130 04/26/2023 2035 1,2-Dibromoethane (EDB) 50 53 1 105 70-130 04/26/2023 2035 Dibromomethane (Methylene bromide) 50 52 1 105 70-130 04/26/2023 2035 trans- 1,4-Dichloro-2-butene 50 51 1 101 70-130 04/26/2023 2035 1,2-Dichlorobenzene 50 55 1 110 70-130 04/26/2023 2035 1,4-Dichlorobenzene 50 53 1 105 70-130 04/26/2023 2035 1,1-Dichloroethane 50 51 1 102 70-130 04/26/2023 2035 1,2-Dichloroethane 50 52 1 104 70-130 04/26/2023 2035 1,1-Dichloroethene 50 53 1 105 70-130 04/26/2023 2035 cis- 1,2-Dichloroethene 50 52 1 104 70-130 04/26/2023 2035 trans- 1,2-Dichloroethene 50 53 1 105 70-130 04/26/2023 2035 1,2-Dichloropropane 50 51 1 103 70-130 04/26/2023 2035 cis- 1,3-Dichloropropene 50 51 1 102 70-130 04/26/2023 2035 trans- 1,3-Dichloropropene 50 53 1 107 70-130 04/26/2023 2035 Ethylbenzene 50 53 1 106 70-130 04/26/2023 2035 2-Hexanone 100 110 1 105 70-130 04/26/2023 2035 Methyl iodide (lodomethane) 50 52 1 103 70-130 04/26/2023 2035 4-Methyl-2-pentanone 100 100 1 100 70-130 04/26/2023 2035 Methylene chloride 50 52 1 104 70-130 04/26/2023 2035 Styrene 50 54 1 108 70-130 04/26/2023 2035 1,1,1,2-Tetrachloroethane 50 53 1 107 70-130 04/26/2023 2035 1,1,2,2-Tetrachloroethane 50 55 1 110 70-130 04/26/2023 2035 Tetrachloroethene 50 54 1 108 70-130 04/26/2023 2035 Toluene 50 55 1 109 70-130 04/26/2023 2035 1,1,1-Trichloroethane 50 52 1 104 70-130 04/26/2023 2035 1,1,2-Trichloroethane 50 54 1 107 70-130 04/26/2023 2035 Trichloroethene 50 51 1 103 70-130 04/26/2023 2035 Trichlorofluoromethane 50 53 1 106 70-130 04/26/2023 2035 1,2,3-Trichloropropane 50 57 1 115 70-130 04/26/2023 2035 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 105 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73762-002 Matrix: Aqueous Batch:73762 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 54 1 108 60-140 04/26/2023 2035 Vinyl chloride 50 57 1 114 70-130 04/26/2023 2035 Xylenes (total) 100 110 1 109 70-130 04/26/2023 2035 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 105 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ73764-001 Matrix: Aqueous Batch:73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/26/2023 2019 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 119 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 105 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ73764-002 Matrix: Aqueous Batch:73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 45 1 90 70-130 04/26/20231823 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 108 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 105 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: YQ73764-003 Matrix: Aqueous Batch:73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 43 1 85 5.3 70-130 20 04/26/20231931 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 102 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 105 ICP-MS Metals - MB Sample ID: YQ72771-001 Matrix: Aqueous Batch: 72771 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1755 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/20/2023 2340 Arsenic ND 1 2.0 1.3 ug/L 04/20/2023 2340 Barium ND 1 5.0 1.3 ug/L 04/20/2023 2340 Beryllium ND 1 0.40 0.15 ug/L 04/20/2023 2340 Cadmium ND 1 0.50 0.13 ug/L 04/20/2023 2340 Chromium ND 1 5.0 1.3 ug/L 04/20/2023 2340 Cobalt ND 1 5.0 1.3 ug/L 04/20/2023 2340 Copper ND 1 5.0 1.3 ug/L 04/20/2023 2340 Lead ND 1 1.0 0.25 ug/L 04/20/2023 2340 Nickel ND 1 5.0 1.3 ug/L 04/20/2023 2340 Selenium ND 1 5.0 1.3 ug/L 04/20/2023 2340 Silver ND 1 1.0 0.25 ug/L 04/20/2023 2340 Thallium ND 1 0.50 0.15 ug/L 04/20/2023 2340 Vanadium ND 1 5.0 2.5 ug/L 04/20/2023 2340 Zinc ND 1 10 2.5 ug/L 04/20/2023 2340 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 105 ICP-MS Metals - LCS Sample ID: YQ72771-002 Matrix: Aqueous Batch: 72771 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1755 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 110 80-120 04/20/2023 2347 Arsenic 100 100 1 104 80-120 04/20/2023 2347 Barium 100 110 1 106 80-120 04/20/2023 2347 Beryllium 100 100 1 102 80-120 04/20/2023 2347 Cadmium 100 100 1 104 80-120 04/20/2023 2347 Chromium 100 110 1 107 80-120 04/20/2023 2347 Cobalt 100 110 1 108 80-120 04/20/2023 2347 Copper 100 110 1 109 80-120 04/20/2023 2347 Lead 100 110 1 109 80-120 04/20/2023 2347 Nickel 100 110 1 105 80-120 04/20/2023 2347 Selenium 100 110 1 106 80-120 04/20/2023 2347 Silver 100 110 1 107 80-120 04/20/2023 2347 Thallium 100 100 1 105 80-120 04/20/2023 2347 Vanadium 100 100 1 105 80-120 04/20/2023 2347 Zinc 100 110 1 113 80-120 04/20/2023 2347 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 105 ICP-MS Metals - MB Sample ID: YQ72772-001 Matrix: Aqueous Batch: 72772 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1751 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/21/2023 0302 Arsenic ND 1 2.0 1.3 ug/L 04/21/2023 0302 Barium ND 1 5.0 1.3 ug/L 04/21/2023 0302 Beryllium ND 1 0.40 0.15 ug/L 04/21/2023 0302 Cadmium ND 1 0.50 0.13 ug/L 04/21/2023 0302 Chromium ND 1 5.0 1.3 ug/L 04/21/2023 0302 Cobalt ND 1 5.0 1.3 ug/L 04/21/2023 0302 Copper ND 1 5.0 1.3 ug/L 04/21/2023 0302 Lead ND 1 1.0 0.25 ug/L 04/21/2023 0302 Nickel ND 1 5.0 1.3 ug/L 04/21/2023 0302 Selenium ND 1 5.0 1.3 ug/L 04/21/2023 0302 Silver ND 1 1.0 0.25 ug/L 04/21/2023 0302 Thallium ND 1 0.50 0.15 ug/L 04/21/2023 0302 Vanadium ND 1 5.0 2.5 ug/L 04/21/2023 0302 Zinc ND 1 10 2.5 ug/L 04/21/2023 0302 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 105 ICP-MS Metals - LCS Sample ID: YQ72772-002 Matrix: Aqueous Batch: 72772 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1751 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 106 80-120 04/21/2023 0309 Arsenic 100 100 1 100 80-120 04/21/2023 0309 Barium 100 99 1 99 80-120 04/21/2023 0309 Beryllium 100 93 1 93 80-120 04/21/2023 0309 Cadmium 100 100 1 100 80-120 04/21/2023 0309 Chromium 100 100 1 103 80-120 04/21/2023 0309 Cobalt 100 100 1 101 80-120 04/21/2023 0309 Copper 100 100 1 102 80-120 04/21/2023 0309 Lead 100 95 1 95 80-120 04/21/2023 0309 Nickel 100 100 1 101 80-120 04/21/2023 0309 Selenium 100 99 1 99 80-120 04/21/2023 0309 Silver 100 100 1 100 80-120 04/21/2023 0309 Thallium 100 98 1 98 80-120 04/21/2023 0309 Vanadium 100 100 1 101 80-120 04/21/2023 0309 Zinc 100 100 1 104 80-120 04/21/2023 0309 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 105 ICP-MS Metals - MS Sample ID: YD14071-013MS Matrix: Aqueous Batch: 72772 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1751 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 112 75-125 04/21/2023 0403 Arsenic ND 100 110 1 106 75-125 04/21/2023 0403 Barium 230 100 350 1 110 75-125 04/21/2023 0403 Beryllium ND 100 96 1 96 75-125 04/21/2023 0403 Cadmium ND 100 100 1 103 75-125 04/21/2023 0403 Chromium 14 100 120 1 106 75-125 04/21/2023 0403 Cobalt ND 100 110 1 108 75-125 04/21/2023 0403 Copper ND 100 110 1 107 75-125 04/21/2023 0403 Lead 1.5 100 110 1 105 75-125 04/21/2023 0403 Nickel ND 100 110 1 106 75-125 04/21/2023 0403 Selenium ND 100 99 1 99 75-125 04/21/2023 0403 Silver ND 100 100 1 105 75-125 04/21/2023 0403 Thallium ND 100 100 1 104 75-125 04/21/2023 0403 Vanadium ND 100 110 1 105 75-125 04/21/2023 0403 Zinc 3.7 100 110 1 104 75-125 04/21/2023 0403 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 105 ICP-MS Metals - MSD Sample ID: YD14071-013MD Matrix: Aqueous Batch: 72772 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/17/2023 1751 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 110 1 111 0.69 75-125 20 04/21/2023 0410 Arsenic ND 100 100 1 104 1.6 75-125 20 04/21/2023 0410 Barium 230 100 350 1 111 0.32 75-125 20 04/21/2023 0410 Beryllium ND 100 95 1 95 1.1 75-125 20 04/21/2023 0410 Cadmium ND 100 100 1 102 0.96 75-125 20 04/21/2023 0410 Chromium 14 100 120 1 103 2.0 75-125 20 04/21/2023 0410 Cobalt ND 100 110 1 105 2.5 75-125 20 04/21/2023 0410 Copper ND 100 110 1 106 1.1 75-125 20 04/21/2023 0410 Lead 1.5 100 100 1 103 1.2 75-125 20 04/21/2023 0410 Nickel ND 100 100 1 104 2.0 75-125 20 04/21/2023 0410 Selenium ND 100 100 1 102 3.8 75-125 20 04/21/2023 0410 Silver ND 100 100 1 103 1.6 75-125 20 04/21/2023 0410 Thallium ND 100 100 1 103 1.6 75-125 20 04/21/2023 0410 Vanadium ND 100 100 1 103 2.0 75-125 20 04/21/2023 0410 Zinc 3.7 100 110 1 104 0.29 75-125 20 04/21/2023 0410 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 105 ICP-MS Metals - MB Sample ID: YQ72773-001 Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/21/2023 0558 Arsenic ND 1 2.0 1.3 ug/L 04/21/2023 0558 Barium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Beryllium ND 1 0.40 0.15 ug/L 04/21/2023 0558 Cadmium ND 1 0.50 0.13 ug/L 04/21/2023 0558 Chromium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Cobalt ND 1 5.0 1.3 ug/L 04/21/2023 0558 Copper ND 1 5.0 1.3 ug/L 04/21/2023 0558 Lead ND 1 1.0 0.25 ug/L 04/21/2023 0558 Nickel ND 1 5.0 1.3 ug/L 04/21/2023 0558 Selenium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Silver ND 1 1.0 0.25 ug/L 04/21/2023 0558 Thallium ND 1 0.50 0.15 ug/L 04/21/2023 0558 Vanadium ND 1 5.0 2.5 ug/L 04/21/2023 0558 Zinc ND 1 10 2.5 ug/L 04/21/2023 0558 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 105 ICP-MS Metals - LCS Sample ID: YQ72773-002 Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 112 80-120 04/21/2023 0605 Arsenic 100 110 1 106 80-120 04/21/2023 0605 Barium 100 100 1 105 80-120 04/21/2023 0605 Beryllium 100 100 1 101 80-120 04/21/2023 0605 Cadmium 100 110 1 105 80-120 04/21/2023 0605 Chromium 100 110 1 109 80-120 04/21/2023 0605 Cobalt 100 110 1 108 80-120 04/21/2023 0605 Copper 100 110 1 108 80-120 04/21/2023 0605 Lead 100 100 1 103 80-120 04/21/2023 0605 Nickel 100 110 1 106 80-120 04/21/2023 0605 Selenium 100 100 1 101 80-120 04/21/2023 0605 Silver 100 110 1 108 80-120 04/21/2023 0605 Thallium 100 100 1 104 80-120 04/21/2023 0605 Vanadium 100 110 1 107 80-120 04/21/2023 0605 Zinc 100 110 1 109 80-120 04/21/2023 0605 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 105 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 105 E3 z7,KceAnaiyffcal" r I Fyvacr Mamp rMsa r,+v, PACE ANALYTICAL SEIRVICES, LLC 1W Varitaon Point Drive, Wnst C-0tumbla, OC 29172 Numberleleptierroc W- kIQS A31 a,.Ml) Fax No. 8CG-791-9111 wtiwr_pavaia.�ss-aam � arer�S$r+sP;m9 Arnhf}^;r] ir5nc,?cat JIlIrGN9 sGaCaiariaede�l Srsre Lp ^.-ads I N i f'ifr:3d Karla SP,,m,q 6 1F I EBEcvF ; Rn jfrm %VgPou65;h LWkM3 li11111111111111i I P.a J%ra !,18Lr'k Jl7 ON?.le hr Qlha wx. 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Or8Tf7wfJnvx. vo-a o t & YtL LOW -Re r�ffr re .'mWfsroryr m*-5mv,Vfa1: F'h'-Flea� Cow �acxlrery &"brr hdEOL'NVI.01 PACE ANALYTICAL SERVICES, LLC XCP Title' r=W-FR1u1-V1COL•0296 V02—SaMPles Rm-mipt Check:ist (SRO FffP r.2',ue Data: 8f Zi2022 Sample receipt (:he ist (SRQ Cookibiwce4edtr'rdatU: CDR I04l14QQZ3 C7ie,u: 13:.a Lott' 'Yf}14071: 1vfe3-115 ofrcccipt: Pf'c {: mL ML CJPS �'cdJ _cr. El y yI.1�Tc i, weir cu$Tvdy $Lvds piNeseilr CHI the uuolm? Elyd Nw y / 1 ' 2. rEcuSt-od pent, were, tll "igcti5AIIL3koIam? !H Suip ID: 2: 250 ClS'silrilm Suip FD: Tcstrd bv_ 3 "R'-V Oylj al teW[-,a1m; nlltui rcteipr ,' DCrivcd (Cmvcted) rrlliperailUC L pOn feCCipC �00t d 1181} t np iU: " 3_3 /..a DC: 1.0 1 1.0 DC VA e MA we. NA f 4A *' ctlw�i elaperatluc f?l�rk❑ amst Llttde5 TR lllni ID: 3 - lit_ Gun COmI'ed0a i cw4 � DC z,ghodormolallt: W1 -We-,Ice )ire Patltii ❑ My kc Nose Yes ❑N+s DNA 3.Fel.'eaiicaolcrsLticivr(lt[eIna 6.fk'C?if11,v4'asPrajcctlVl:_rlafifyotified? 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(If #19 is no) ptE3d wel:; adjusted accard*- ' ill s&f& Fer.eiv?n�,.vi[h &,di1mn thicsul#ate (Na.,Z ,03) WiRk tynique M: N Cor>IuuCnt-3: QuaftirwY I D. 5060 Pawl Analytical S3"vic¢s, LLC Pale 1 of i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 105 PACE ANALYTICAL SERVICES, LLC Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name:Closed Buncombe County Landfill Project Number:J22-14175-07 Lot Number:YD18105 Date Completed:05/12/2023 Project Manager:Lucas J. Odom AJ" A B C R E 6 1 T E d B ODD FLAP This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: YD18105 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. ................ NCM .............. The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 73955 exceeded acceptance criteria for the following analytes: Acetone, 2-butanone. These analytes were biased high and were not detected in the samples affected: YD17054-011, YD18064-001, YD18064-002, YD18064-003, YD18064-005, YD18064-006, YD18064-007, YD18064-008, YD18064-009, YD18105-003, YD19033- 001, YD19033-002, YD19065-001. YD18105-003 (TVL BILK) (Run 1) (Analysis Batch 73955) Appendix I Volatiles (low-level) The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 73955 exceeded acceptance criteria for the following analytes: 2-Hexanone. These analytes were biased high and were not detected in the samples affected: YD17054-011, YD18064- 001, YD18064-002, YD18064-003, YD18064-005, YD18064-006, YD18064-007, YD18064-008, YD18064-009, YD18105-003, YD19065-001. YD18105-003 (TVL BLK) (Run 1) (Analysis Batch 73955) Appendix I Volatiles (low-level) The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 73955 exceeded acceptance criteria for the following analytes: Acylonitrile. These analytes were biased high and were not detected in the samples affected: YD18105-003. YD18105-003 (TVL BLK) (Run 1) (Analysis Batch 73955) Appendix I Volatiles (low-level) The continuing calibration verification (CCV) associated with analytical batch 73893 recovered outside acceptance criteria, low biased, for trans- 1,4-Dichloro-2-butene (-33%). An LOQ standard was analyzed, and the target analyte was detected. Since the associated samples were non - detect, no corrective action was taken. YD18105-001 (MW-2) (Run 1) (Analysis Batch 73893) Appendix I Volatiles (low-level) YD18105-002 (MW-23-119) (Run 1) (Analysis Batch 73893) Appendix I Volatiles (low-level) Due to the large number of spiked analytes, there is a high probability that one or more analytes will recover outside acceptance limits. The Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: YD18105 laboratory's SOP allows for 10% of analytes to recover marginally outside criteria. The following analytes recovered marginally outside LCS criteria: trans- 1,4-Dichloro-2-butene (67%). YD18105-001 (MW-2) (Run 1) (Analysis Batch 73893) Appendix I Volatiles (low-level) YD18105-002 (MW-23-119) (Run 1) (Analysis Batch 73893) Appendix I Volatiles (low-level) Reanalysis of the following sample(s) was performed outside of the analytical holding time for Chlorobenzene due to carryover: YD18105-001. —EXPLANATION REQUIRED» YD18105-001 (MW-2) (Run 2) (Analysis Batch 74981) Appendix I Volatiles (low-level) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD18105 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-2 Aqueous 04/17/20231325 04/18/2023 002 MW-23-119 Aqueous 04/17/20231445 04/18/2023 003 TVL BLK Aqueous 04/17/2023 0930 04/18/2023 (3 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com PACE ANALYTICAL SERVICES, LLC Sample Sample ID 001 MW-2 001 MW-2 001 MW-2 001 MW-2 001 MW-2 001 MW-2 001 MW-2 001 MW-2 001 MW-2 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 002 MW-23-119 (19 detections) Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD18105 Matrix Parameter Method Result Q Units Page Aqueous Chlorobenzene 8260D 1.9 ug/L 6 Aqueous Barium 6020B 39 ug/L 7 Aqueous Chromium 6020E 16 ug/L 7 Aqueous Cobalt 6020E 2.6 J ug/L 7 Aqueous Copper 6020B 9.0 ug/L 7 Aqueous Lead 6020B 2.1 ug/L 7 Aqueous Nickel 6020E 18 ug/L 8 Aqueous Vanadium 6020E 3.9 J ug/L 8 Aqueous Zinc 6020B 9.2 J ug/L 8 Aqueous Acetone 8260D 38 ug/L 9 Aqueous Chlorobenzene 8260D 0.70 J ug/L 9 Aqueous 1,1-Dichloroethane 8260D 0.66 J ug/L 9 Aqueous Antimony 6020B 1.4 J ug/L 10 Aqueous Barium 6020B 670 ug/L 10 Aqueous Chromium 6020E 19 ug/L 10 Aqueous Cobalt 6020E 1.5 J ug/L 10 Aqueous Copper 6020B 1.8 J ug/L 10 Aqueous Lead 6020E 0.70 J ug/L 11 Aqueous Nickel 6020E 2.7 J ug/L 11 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-001 Description: MW-2 Matrix: Aqueous Date Sampled:04/17/2023 1325 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/28/2023 1210 JWO 73956 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 99 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/2023 0249 CDA 73893 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.9 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND L 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-001 Description: MW-2 Matrix: Aqueous Date Sampled:04/17/2023 1325 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/2023 0249 CDA 73893 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 100 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/25/2023 0401 BNW 04/23/2023 1915 73233 2 3005A 6020B 1 04/28/2023 0815 BNW 04/23/2023 1915 73233 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 39 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 2 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 16 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.6 J 5.0 1.3 ug/L 2 Copper 7440-50-8 6020B 9.0 5.0 1.3 ug/L 2 Lead 7439-92-1 6020B 2.1 1.0 0.25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-001 Description: MW-2 Matrix: Aqueous Date Sampled:04/17/2023 1325 Date Received:04/18/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/25/2023 0401 BNW 04/23/2023 1915 73233 2 3005A 6020B 1 04/28/2023 0815 BNW 04/23/2023 1915 73233 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6020B 18 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.9 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 9.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-002 Description: MW-23-119 Matrix: Aqueous Date Sampled:04/17/2023 1445 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/28/2023 1234 JWO 73956 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/2023 0312 CDA 73893 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 38 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.70 J 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND L 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.66 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-002 Description: MW-23-119 Matrix: Aqueous Date Sampled:04/17/2023 1445 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/2023 0312 CDA 73893 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/25/2023 0412 BNW 04/23/2023 1915 73233 2 3005A 6020B 1 04/28/2023 0827 BNW 04/23/2023 1915 73233 3 3005A 6020B 5 04/28/2023 2045 BNW 04/23/2023 1915 73233 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.4 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 670 25 6.3 ug/L 3 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 2 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 19 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.5 J 5.0 1.3 ug/L 2 Copper 7440-50-8 6020B 1.8 J 5.0 1.3 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bun nell-Lammons Engineering, Inc. Laboratory ID: YD18105-002 Description: MW-23-119 Matrix: Aqueous Date Sampled:04/17/2023 1445 Date Received:04/18/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/25/2023 0412 BNW 04/23/2023 1915 73233 2 3005A 6020B 1 04/28/2023 0827 BNW 04/23/2023 1915 73233 3 3005A 6020B 5 04/28/2023 2045 BNW 04/23/2023 1915 73233 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Lead 7439-92-1 6020E 0.70 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020E 2.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020E ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020E ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020E ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020E ND 10 2.5 ug/L 1 LOCI = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-003 Description: TVL BILK Matrix: Aqueous Date Sampled:04/17/2023 0930 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/20231411 AMR2 73955 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND L 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD18105-003 Description: TVL BILK Matrix: Aqueous Date Sampled:04/17/2023 0930 Date Received:04/18/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/28/20231411 AMR2 73955 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 112 70-130 105 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73893-001 Matrix: Aqueous Batch: 73893 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/27/2023 2258 Acrylonitrile ND 1 20 0.80 ug/L 04/27/2023 2258 Benzene ND 1 1.0 0.40 ug/L 04/27/2023 2258 Bromochloromethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 Bromoform ND 1 1.0 0.40 ug/L 04/27/2023 2258 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/27/2023 2258 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/27/2023 2258 Carbon disulfide ND 1 1.0 0.40 ug/L 04/27/2023 2258 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/27/2023 2258 Chlorobenzene ND 1 1.0 0.40 ug/L 04/27/2023 2258 Chloroethane ND 1 2.0 0.40 ug/L 04/27/2023 2258 Chloroform ND 1 1.0 0.40 ug/L 04/27/2023 2258 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/27/2023 2258 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/27/2023 2258 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/27/2023 2258 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/27/2023 2258 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/27/2023 2258 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/27/2023 2258 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/27/2023 2258 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/27/2023 2258 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/27/2023 2258 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/27/2023 2258 Ethylbenzene ND 1 1.0 0.40 ug/L 04/27/2023 2258 2-Hexanone ND 1 10 2.0 ug/L 04/27/2023 2258 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/27/2023 2258 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/27/2023 2258 Methylene chloride ND 1 1.0 0.40 ug/L 04/27/2023 2258 Styrene ND 1 1.0 0.41 ug/L 04/27/2023 2258 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/27/2023 2258 Toluene ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 Trichloroethene ND 1 1.0 0.40 ug/L 04/27/2023 2258 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/27/2023 2258 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/27/2023 2258 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73893-001 Matrix: Aqueous Batch: 73893 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/27/2023 2258 Vinyl chloride ND 1 1.0 0.40 ug/L 04/27/2023 2258 Xylenes (total) ND 1 1.0 0.40 ug/L 04/27/2023 2258 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 108 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73893-002 Matrix: Aqueous Batch: 73893 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 100 1 100 60-140 04/27/2023 2016 Acrylonitrile 100 93 1 93 70-130 04/27/2023 2016 Benzene 50 47 1 94 70-130 04/27/2023 2016 Bromochloromethane 50 45 1 89 70-130 04/27/2023 2016 Bromodichloromethane 50 44 1 88 70-130 04/27/2023 2016 Bromoform 50 42 1 84 70-130 04/27/2023 2016 Bromomethane (Methyl bromide) 50 58 1 116 70-130 04/27/2023 2016 2-Butanone (MEK) 100 98 1 98 70-130 04/27/2023 2016 Carbon disulfide 50 49 1 98 70-130 04/27/2023 2016 Carbon tetrachloride 50 47 1 95 70-130 04/27/2023 2016 Chlorobenzene 50 46 1 92 70-130 04/27/2023 2016 Chloroethane 50 58 1 116 70-130 04/27/2023 2016 Chloroform 50 47 1 94 70-130 04/27/2023 2016 Chloromethane (Methyl chloride) 50 70 1 140 60-140 04/27/2023 2016 1,2-Dibromo-3-chloropropane (DBCP) 50 42 1 85 70-130 04/27/2023 2016 Dibromochloromethane 50 43 1 87 70-130 04/27/2023 2016 1,2-Dibromoethane (EDB) 50 47 1 93 70-130 04/27/2023 2016 Dibromomethane (Methylene bromide) 50 46 1 93 70-130 04/27/2023 2016 trans- 1,4-Dichloro-2-butene 50 33 N 1 67 70-130 04/27/2023 2016 1,2-Dichlorobenzene 50 45 1 89 70-130 04/27/2023 2016 1,4-Dichlorobenzene 50 43 1 86 70-130 04/27/2023 2016 1,1-Dichloroethane 50 45 1 89 70-130 04/27/2023 2016 1,2-Dichloroethane 50 45 1 90 70-130 04/27/2023 2016 1,1-Dichloroethene 50 50 1 100 70-130 04/27/2023 2016 cis- 1,2-Dichloroethene 50 45 1 91 70-130 04/27/2023 2016 trans- 1,2-Dichloroethene 50 46 1 91 70-130 04/27/2023 2016 1,2-Dichloropropane 50 46 1 93 70-130 04/27/2023 2016 cis- 1,3-Dichloropropene 50 47 1 94 70-130 04/27/2023 2016 trans- 1,3-Dichloropropene 50 46 1 91 70-130 04/27/2023 2016 Ethylbenzene 50 50 1 100 70-130 04/27/2023 2016 2-Hexanone 100 88 1 88 70-130 04/27/2023 2016 Methyl iodide (lodomethane) 50 47 1 93 70-130 04/27/2023 2016 4-Methyl-2-pentanone 100 100 1 100 70-130 04/27/2023 2016 Methylene chloride 50 52 1 104 70-130 04/27/2023 2016 Styrene 50 47 1 94 70-130 04/27/2023 2016 1,1,1,2-Tetrachloroethane 50 45 1 90 70-130 04/27/2023 2016 1,1,2,2-Tetrachloroethane 50 42 1 84 70-130 04/27/2023 2016 Tetrachloroethene 50 48 1 96 70-130 04/27/2023 2016 Toluene 50 48 1 97 70-130 04/27/2023 2016 1,1,1-Trichloroethane 50 46 1 93 70-130 04/27/2023 2016 1,1,2-Trichloroethane 50 44 1 88 70-130 04/27/2023 2016 Trichloroethene 50 48 1 96 70-130 04/27/2023 2016 Trichlorofluoromethane 50 61 1 121 70-130 04/27/2023 2016 1,2,3-Trichloropropane 50 44 1 88 70-130 04/27/2023 2016 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73893-002 Matrix: Aqueous Batch: 73893 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 44 1 89 60-140 04/27/2023 2016 Vinyl chloride 50 64 1 127 70-130 04/27/2023 2016 Xylenes (total) 100 100 1 102 70-130 04/27/2023 2016 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73955-001 Matrix: Aqueous Batch: 73955 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/28/2023 1141 Acrylonitrile ND 1 20 0.80 ug/L 04/28/2023 1141 Benzene ND 1 1.0 0.40 ug/L 04/28/2023 1141 Bromochloromethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 Bromoform ND 1 1.0 0.40 ug/L 04/28/2023 1141 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/28/2023 1141 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/28/2023 1141 Carbon disulfide ND 1 1.0 0.40 ug/L 04/28/2023 1141 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/28/2023 1141 Chlorobenzene ND 1 1.0 0.40 ug/L 04/28/2023 1141 Chloroethane ND 1 2.0 0.40 ug/L 04/28/2023 1141 Chloroform ND 1 1.0 0.40 ug/L 04/28/2023 1141 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/28/2023 1141 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/28/2023 1141 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/28/2023 1141 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/28/2023 1141 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/28/2023 1141 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/28/2023 1141 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/28/2023 1141 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/28/2023 1141 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/28/2023 1141 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/28/2023 1141 Ethylbenzene ND 1 1.0 0.40 ug/L 04/28/2023 1141 2-Hexanone ND 1 10 2.0 ug/L 04/28/2023 1141 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/28/2023 1141 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/28/2023 1141 Methylene chloride ND 1 1.0 0.40 ug/L 04/28/2023 1141 Styrene ND 1 1.0 0.41 ug/L 04/28/2023 1141 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/28/2023 1141 Toluene ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 Trichloroethene ND 1 1.0 0.40 ug/L 04/28/2023 1141 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/28/2023 1141 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/28/2023 1141 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73955-001 Matrix: Aqueous Batch: 73955 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/28/2023 1141 Vinyl chloride ND 1 1.0 0.40 ug/L 04/28/2023 1141 Xylenes (total) ND 1 1.0 0.40 ug/L 04/28/2023 1141 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 105 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73955-002 Matrix: Aqueous Batch: 73955 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 170 N 1 173 60-140 04/28/2023 1006 Acrylonitrile 100 130 N 1 131 70-130 04/28/2023 1006 Benzene 50 54 1 109 70-130 04/28/2023 1006 Bromochloromethane 50 50 1 99 70-130 04/28/2023 1006 Bromodichloromethane 50 57 1 113 70-130 04/28/2023 1006 Bromoform 50 48 1 96 70-130 04/28/2023 1006 Bromomethane (Methyl bromide) 50 51 1 102 70-130 04/28/2023 1006 2-Butanone (MEK) 100 150 N 1 152 70-130 04/28/2023 1006 Carbon disulfide 50 58 1 115 70-130 04/28/2023 1006 Carbon tetrachloride 50 59 1 119 70-130 04/28/2023 1006 Chlorobenzene 50 55 1 110 70-130 04/28/2023 1006 Chloroethane 50 55 1 110 70-130 04/28/2023 1006 Chloroform 50 53 1 107 70-130 04/28/2023 1006 Chloromethane (Methyl chloride) 50 61 1 122 60-140 04/28/2023 1006 1,2-Dibromo-3-chloropropane (DBCP) 50 55 1 111 70-130 04/28/2023 1006 Dibromochloromethane 50 58 1 117 70-130 04/28/2023 1006 1,2-Dibromoethane (EDB) 50 56 1 112 70-130 04/28/2023 1006 Dibromomethane (Methylene bromide) 50 51 1 103 70-130 04/28/2023 1006 trans- 1,4-Dichloro-2-butene 50 64 1 128 70-130 04/28/2023 1006 1,2-Dichlorobenzene 50 54 1 108 70-130 04/28/2023 1006 1,4-Dichlorobenzene 50 53 1 106 70-130 04/28/2023 1006 1,1-Dichloroethane 50 55 1 110 70-130 04/28/2023 1006 1,2-Dichloroethane 50 53 1 105 70-130 04/28/2023 1006 1,1-Dichloroethene 50 55 1 110 70-130 04/28/2023 1006 cis- 1,2-Dichloroethene 50 52 1 103 70-130 04/28/2023 1006 trans- 1,2-Dichloroethene 50 53 1 107 70-130 04/28/2023 1006 1,2-Dichloropropane 50 56 1 112 70-130 04/28/2023 1006 cis- 1,3-Dichloropropene 50 58 1 115 70-130 04/28/2023 1006 trans- 1,3-Dichloropropene 50 59 1 118 70-130 04/28/2023 1006 Ethylbenzene 50 57 1 114 70-130 04/28/2023 1006 2-Hexanone 100 140 N 1 137 70-130 04/28/2023 1006 Methyl iodide (lodomethane) 50 51 1 102 70-130 04/28/2023 1006 4-Methyl-2-pentanone 100 120 1 116 70-130 04/28/2023 1006 Methylene chloride 50 55 1 111 70-130 04/28/2023 1006 Styrene 50 59 1 118 70-130 04/28/2023 1006 1,1,1,2-Tetrachloroethane 50 57 1 114 70-130 04/28/2023 1006 1,1,2,2-Tetrachloroethane 50 60 1 120 70-130 04/28/2023 1006 Tetrachloroethene 50 54 1 108 70-130 04/28/2023 1006 Toluene 50 56 1 111 70-130 04/28/2023 1006 1,1,1-Trichloroethane 50 55 1 110 70-130 04/28/2023 1006 1,1,2-Trichloroethane 50 57 1 113 70-130 04/28/2023 1006 Trichloroethene 50 52 1 104 70-130 04/28/2023 1006 Trichlorofluoromethane 50 54 1 108 70-130 04/28/2023 1006 1,2,3-Trichloropropane 50 58 1 116 70-130 04/28/2023 1006 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73955-002 Matrix: Aqueous Batch: 73955 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 55 1 109 60-140 04/28/2023 1006 Vinyl chloride 50 61 1 121 70-130 04/28/2023 1006 Xylenes (total) 100 110 1 112 70-130 04/28/2023 1006 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 91 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ73956-001 Matrix: Aqueous Batch: 73956 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/28/20231102 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 98 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ73956-002 Matrix: Aqueous Batch: 73956 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 55 1 109 70-130 04/28/2023 0959 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 98 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals - MB Sample ID: YQ73233-001 Matrix: Aqueous Batch: 73233 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/23/2023 1915 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/25/2023 0326 Arsenic ND 1 2.0 1.3 ug/L 04/25/2023 0326 Barium ND 1 5.0 1.3 ug/L 04/25/2023 0326 Beryllium ND 1 0.40 0.15 ug/L 04/28/2023 0741 Cadmium ND 1 0.50 0.13 ug/L 04/25/2023 0326 Chromium ND 1 5.0 1.3 ug/L 04/25/2023 0326 Cobalt ND 1 5.0 1.3 ug/L 04/28/2023 0741 Copper ND 1 5.0 1.3 ug/L 04/28/2023 0741 Lead ND 1 1.0 0.25 ug/L 04/25/2023 0326 Nickel ND 1 5.0 1.3 ug/L 04/25/2023 0326 Selenium ND 1 5.0 1.3 ug/L 04/25/2023 0326 Silver ND 1 1.0 0.25 ug/L 04/25/2023 0326 Thallium ND 1 0.50 0.15 ug/L 04/25/2023 0326 Vanadium ND 1 5.0 2.5 ug/L 04/25/2023 0326 Zinc ND 1 10 2.5 ug/L 04/25/2023 0326 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals - LCS Sample ID: YQ73233-002 Matrix: Aqueous Batch: 73233 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/23/2023 1915 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 96 1 96 80-120 04/25/2023 0338 Arsenic 100 98 1 98 80-120 04/25/2023 0338 Barium 100 98 1 98 80-120 04/25/2023 0338 Beryllium 100 94 1 94 80-120 04/28/2023 0753 Cadmium 100 100 1 104 80-120 04/25/2023 0338 Chromium 100 110 1 112 80-120 04/25/2023 0338 Cobalt 100 120 1 117 80-120 04/28/2023 0753 Copper 100 110 1 114 80-120 04/28/2023 0753 Lead 100 100 1 103 80-120 04/25/2023 0338 Nickel 100 110 1 112 80-120 04/25/2023 0338 Selenium 100 86 1 86 80-120 04/25/2023 0338 Silver 100 110 1 106 80-120 04/25/2023 0338 Thallium 100 95 1 95 80-120 04/25/2023 0338 Vanadium 100 100 1 102 80-120 04/25/2023 0338 Zinc 100 97 1 97 80-120 04/25/2023 0338 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ,-0 o0 ro < v d ---I CHAIN-OF-CUSTODYA7alytICaIRio qumstDocu ant E+gUSE ONLY-fJlixWol'llorder/LoyfnLabalHaneacUatpace Work6fdd"MUM'Iglt'dr iv � . :MTJLLd�an hlW�lf Fkr4. . m J i�fi��j7Ctl� v v Chaln-f-�Zuaodx is a LEGAL dCUVMcNT . 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W Cd'C 8l1 CCxIIk'I $ i 1V Cl at 470 C10R' 6.{'i'�'? If 110, WaS PrUjCCt 1v1.K]1 1101fied? P�1 1 w l+foxift b}. pltouc f cmaii f iac po-f t:e �cirulr mej. `,'CS Lj NO I wr INA 1. 15 OV- C0117.011]e[6MI CU 41il..% Pi]CUBg A141 *14RC[1e;'C PO th15 fOD-11? V Vaq INO S. f7rc proper cT°s WY ou:diu s (i-elintlatshcdin-ce ved) f6Knved'7 5'Cs No 6, wCCs811111icMs. Iisrt(ti)afltr COC, and adssmilplCC-awlaiiaefs? 7. M15 cvllecdol) bate & bu1G fisted on the -COC and ail sminplc conrnilicH? Mes a 25 -NO S- ad all cn ilia u]Ka label iu5m-wafiDn (ID, date. D�Ik) agree with the C)OC? -LJ25 NL) 9- C -c tcs,S to be 11aRnilyd ILued on the COC° ©Yes I�I uTkl;: M Di(I all "savjpks arrive ju L1lC pirpeT caiitaftim.i .for esCh test aj&oy i1i s!QChd C Ml1jltl-,-�Jk (unbroken- lids inn, ctc)? — YC5 ❑A1(: 11. WILS adegltale suMle w1wite mifaWc? yes q hu �4 12, m tall samples received wkWii 0w hnldin2 time or 18 Min. Plle chcver cvuics bi5:" ❑YesNO ]3, Were N1Csdrllplos C€nlClllltirR 8C{41t11[ �1 fC71'.t (ItioFE71. !di4'tn.'CC2 5) 14. Were VOA. 8015C wid Rt -174' sullples free ofb`tJ>at cs >-ppa-size" (WbrCilia] it: {/ Yes ��Nte [—]NA in alivo�1lhC VDA vicl,? y Ci i NCF 1 1 K 1 f*, W21' ill 83C[filgnutders sans lrs i-ecei ed Fit a IH 01 < 7 7 Yc$ -�To ,/ lti e 1 G. W= all cyallidc S3 le-s 1Lrticivcd of a pT -- 12 .Fw1 st lfidc uuyks received at• a p)iE .> 9? r 1 F:s nl+a QNA l7. Were all hpphrati ti NH�lTr'I lc}�,>irlerl 1epQ 4 a,1/608.3 (� 0.5rni .samples tr O 1r-sdud clrlvrhloI u , si � I ❑ `18. Vss die tiww iiu11mlicr listed or� Eim coirj-r low? If }%!S, funk W jj`FmpLe Presekwlian (Mitst be co1>apletCd for ally Sstntple{sj iut_7m-txflYpre--;erved orwith Ns&pavt.) 11 531UpjC(5) NA wcrc Crowed =Luitxtlyprc! cmrcd arld wtie adjustor acc-ordjnly Lft $Al] pk i a:vior +Aft NA ]t1L of circle one: HS&N, ILN03, HC L NaOH mi ng Sly P NA _ lime of llr'e.4t:lvafior 1xa� . wi1'1drr dean one pre3nvaiive kiwgded, please note in the C{lflru1e11C5 brlew. wac roc ived wiTh bubbles ami if1 �iainm- S:;J11Lr�C (s) r]" were :'etieitrod � irh .1. , > 0.5 nlj* L �N4119 is F!d} a11il t�,'crc ngu^slcd accoAlingly in sample receiving with SD[ U111 thiosWflate (N12S,0] f Vvidl I illigil,-- rD- Clnr]]nents: qualbax ID, 55360 PaceO Aniolytic-ai Services, l.t.c_ raga 1 0= 1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Landfill Surface Water Project Number: J22-14175-07 Lot Number:YD14073 Date Completed:05/01/2023 05/04/2023 4:32 PM Approved and released by: Project Manager II: Lucas Odom PC. F O 24rA SOA / ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 39 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: YD14073 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Inorganic Metals The instrument blank for analytical batch 73268 contained Be greater than one-half the LOQ but less than the LOQ. Samples are ND. The data have been qualified and reported. VOCs by GUMS The laboratory control sample (LCS) for analytical batch 73677 exceeded acceptance criteria for Acetone. This analyte is biased high but not detected in the samples affected. Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 73764. An LCS/LCSD was run in lieu of an MS/MSD. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 39 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD14073 Sample Number Sample ID Matrix Date Sampled Date Received 001 SW-1 Aqueous 04/13/20231410 04/14/2023 002 SW-2 Aqueous 04/13/2023 0935 04/14/2023 003 SW-2A Aqueous 04/13/2023 0950 04/14/2023 004 SW-3 Aqueous 04/13/20231430 04/14/2023 005 SW-10 Aqueous 04/13/20231550 04/14/2023 006 SW-4 Aqueous 04/13/20231450 04/14/2023 (6 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 39 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: YD14073 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 SW-1 Aqueous Barium 6020E 16 ug/L 7 001 SW-1 Aqueous Lead 6020B 0.49 J ug/L 7 001 SW-1 Aqueous Zinc 6020E 3.7 J ug/L 7 002 SW-2 Aqueous Barium 6020E 15 ug/L 9 002 SW-2 Aqueous Lead 6020B 0.47 J ug/L 9 002 SW-2 Aqueous Zinc 6020B 5.2 J ug/L 9 003 SW-2A Aqueous 1,4-Dioxane 8260D (SIM) 7.8 ug/L 10 003 SW-2A Aqueous Barium 6020E 33 ug/L 11 003 SW-2A Aqueous Nickel 6020B 1.8 J ug/L 11 004 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 32 ug/L 13 004 SW-3 Aqueous Antimony 6020E 1.1 J ug/L 14 004 SW-3 Aqueous Barium 6020E 110 ug/L 14 004 SW-3 Aqueous Cobalt 6020B 2.6 J ug/L 14 004 SW-3 Aqueous Nickel 6020B 4.2 J ug/L 14 005 SW-10 Aqueous 1,4-Dioxane 8260D (SIM) 1.0 J ug/L 16 005 SW-10 Aqueous Barium 6020E 67 ug/L 17 005 SW-10 Aqueous Copper 6020B 1.6 J ug/L 17 005 SW-10 Aqueous Lead 6020E 0.43 J ug/L 17 005 SW-10 Aqueous Zinc 6020E 8.6 J ug/L 18 006 SW-4 Aqueous 1,4-Dioxane 8260D (SIM) 35 ug/L 19 006 SW-4 Aqueous 1,2,3-Trichloropropane 8260D 3.1 ug/L 20 006 SW-4 Aqueous Barium 6020E 71 ug/L 20 006 SW-4 Aqueous Cobalt 6020E 1.8 J ug/L 20 006 SW-4 Aqueous Nickel 6020B 15 ug/L 20 (24 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/13/2023 1410 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231731 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-001 Description: SW-1 Matrix: Aqueous Date Sampled:04/13/2023 1410 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231731 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0625 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 16 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.49 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/13/2023 0935 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1754 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-002 Description: SW-2 Matrix: Aqueous Date Sampled:04/13/2023 0935 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 1754 AMR2 73677 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0632 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 15 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.47 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/13/2023 0950 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0255 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.8 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 123 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0005 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/13/2023 0950 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0005 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0639 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 33 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.8 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-003 Description: SW-2A Matrix: Aqueous Date Sampled:04/13/2023 0950 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0639 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0318 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 32 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 123 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0028 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0028 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0726 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.1 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.6 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.2 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-004 Description: SW-3 Matrix: Aqueous Date Sampled:04/13/2023 1430 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0726 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-005 Description: SW-10 Matrix: Aqueous Date Sampled:04/13/2023 1550 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0343 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.0 J 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 124 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0050 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-005 Description: SW-10 Matrix: Aqueous Date Sampled:04/13/2023 1550 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0050 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 104 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0733 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 67 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.6 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.43 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-005 Description: SW-10 Matrix: Aqueous Date Sampled:04/13/2023 1550 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0733 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-006 Description: SW-4 Matrix: Aqueous Date Sampled:04/13/2023 1450 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/27/2023 0406 JMM2 73764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 35 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 125 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0112 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-006 Description: SW-4 Matrix: Aqueous Date Sampled:04/13/2023 1450 Date Received:04/14/2023 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 0112 CDA 73762 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 3.1 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 105 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0739 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 71 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 15 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 39 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:YD14073-006 Description: SW-4 Matrix: Aqueous Date Sampled:04/13/2023 1450 Date Received:04/14/2023 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/21/2023 0739 BNW 04/18/2023 1845 72773 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 39 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 39 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73677-001 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/26/2023 1009 Acrylonitrile ND 1 20 0.80 ug/L 04/26/2023 1009 Benzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromoform ND 1 1.0 0.40 ug/L 04/26/2023 1009 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/26/2023 1009 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/26/2023 1009 Carbon disulfide ND 1 1.0 0.40 ug/L 04/26/2023 1009 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chloroethane ND 1 2.0 0.40 ug/L 04/26/2023 1009 Chloroform ND 1 1.0 0.40 ug/L 04/26/2023 1009 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/26/2023 1009 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/26/2023 1009 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 1009 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 1009 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Ethylbenzene ND 1 1.0 0.40 ug/L 04/26/2023 1009 2-Hexanone ND 1 10 2.0 ug/L 04/26/2023 1009 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/26/2023 1009 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/26/2023 1009 Methylene chloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Styrene ND 1 1.0 0.41 ug/L 04/26/2023 1009 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Toluene ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 Trichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 1009 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/26/2023 1009 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 1009 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 39 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73677-001 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/26/2023 1009 Vinyl chloride ND 1 1.0 0.40 ug/L 04/26/2023 1009 Xylenes (total) ND 1 1.0 0.40 ug/L 04/26/2023 1009 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 39 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73677-002 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 160 N 1 162 60-140 04/26/2023 0822 Acrylonitrile 100 98 1 98 70-130 04/26/2023 0822 Benzene 50 44 1 87 70-130 04/26/2023 0822 Bromochloromethane 50 44 1 89 70-130 04/26/2023 0822 Bromodichloromethane 50 45 1 90 70-130 04/26/2023 0822 Bromoform 50 48 1 95 70-130 04/26/2023 0822 Bromomethane (Methyl bromide) 50 45 1 91 70-130 04/26/2023 0822 2-Butanone (MEK) 100 120 1 115 70-130 04/26/2023 0822 Carbon disulfide 50 41 1 81 70-130 04/26/2023 0822 Carbon tetrachloride 50 42 1 83 70-130 04/26/2023 0822 Chlorobenzene 50 46 1 91 70-130 04/26/2023 0822 Chloroethane 50 50 1 100 70-130 04/26/2023 0822 Chloroform 50 43 1 86 70-130 04/26/2023 0822 Chloromethane (Methyl chloride) 50 49 1 98 60-140 04/26/2023 0822 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 97 70-130 04/26/2023 0822 Dibromochloromethane 50 49 1 98 70-130 04/26/2023 0822 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 04/26/2023 0822 Dibromomethane (Methylene bromide) 50 47 1 94 70-130 04/26/2023 0822 trans- 1,4-Dichloro-2-butene 50 52 1 104 70-130 04/26/2023 0822 1,2-Dichlorobenzene 50 48 1 96 70-130 04/26/2023 0822 1,4-Dichlorobenzene 50 47 1 94 70-130 04/26/2023 0822 1,1-Dichloroethane 50 43 1 87 70-130 04/26/2023 0822 1,2-Dichloroethane 50 46 1 92 70-130 04/26/2023 0822 1,1-Dichloroethene 50 40 1 80 70-130 04/26/2023 0822 cis- 1,2-Dichloroethene 50 43 1 87 70-130 04/26/2023 0822 trans- 1,2-Dichloroethene 50 43 1 85 70-130 04/26/2023 0822 1,2-Dichloropropane 50 45 1 89 70-130 04/26/2023 0822 cis- 1,3-Dichloropropene 50 46 1 92 70-130 04/26/2023 0822 trans- 1,3-Dichloropropene 50 49 1 98 70-130 04/26/2023 0822 Ethylbenzene 50 45 1 90 70-130 04/26/2023 0822 2-Hexanone 100 100 1 100 70-130 04/26/2023 0822 Methyl iodide (lodomethane) 50 42 1 84 70-130 04/26/2023 0822 4-Methyl-2-pentanone 100 92 1 92 70-130 04/26/2023 0822 Methylene chloride 50 43 1 86 70-130 04/26/2023 0822 Styrene 50 46 1 92 70-130 04/26/2023 0822 1,1,1,2-Tetrachloroethane 50 46 1 92 70-130 04/26/2023 0822 1,1,2,2-Tetrachloroethane 50 51 1 102 70-130 04/26/2023 0822 Tetrachloroethene 50 45 1 90 70-130 04/26/2023 0822 Toluene 50 46 1 92 70-130 04/26/2023 0822 1,1,1-Trichloroethane 50 42 1 84 70-130 04/26/2023 0822 1,1,2-Trichloroethane 50 48 1 97 70-130 04/26/2023 0822 Trichloroethene 50 43 1 86 70-130 04/26/2023 0822 Trichlorofluoromethane 50 49 1 98 70-130 04/26/2023 0822 1,2,3-Trichloropropane 50 49 1 97 70-130 04/26/2023 0822 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 39 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73677-002 Matrix: Aqueous Batch: 73677 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 48 1 96 60-140 04/26/2023 0822 Vinyl chloride 50 53 1 105 70-130 04/26/2023 0822 Xylenes (total) 100 92 1 92 70-130 04/26/2023 0822 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 39 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73762-001 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 04/26/2023 2209 Acrylonitrile ND 1 20 0.80 ug/L 04/26/2023 2209 Benzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromodichloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromoform ND 1 1.0 0.40 ug/L 04/26/2023 2209 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 04/26/2023 2209 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/26/2023 2209 Carbon disulfide ND 1 1.0 0.40 ug/L 04/26/2023 2209 Carbon tetrachloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chloroethane ND 1 2.0 0.40 ug/L 04/26/2023 2209 Chloroform ND 1 1.0 0.40 ug/L 04/26/2023 2209 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 04/26/2023 2209 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Dibromochloromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 04/26/2023 2209 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 2209 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 2209 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Ethylbenzene ND 1 1.0 0.40 ug/L 04/26/2023 2209 2-Hexanone ND 1 10 2.0 ug/L 04/26/2023 2209 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/26/2023 2209 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/26/2023 2209 Methylene chloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Styrene ND 1 1.0 0.41 ug/L 04/26/2023 2209 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Tetrachloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Toluene ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 Trichloroethene ND 1 1.0 0.40 ug/L 04/26/2023 2209 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 04/26/2023 2209 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 04/26/2023 2209 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 39 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73762-001 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 04/26/2023 2209 Vinyl chloride ND 1 1.0 0.40 ug/L 04/26/2023 2209 Xylenes (total) ND 1 1.0 0.40 ug/L 04/26/2023 2209 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 39 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73762-002 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 170 N 1 166 60-140 04/26/2023 2035 Acrylonitrile 100 110 1 106 70-130 04/26/2023 2035 Benzene 50 52 1 104 70-130 04/26/2023 2035 Bromochloromethane 50 51 1 102 70-130 04/26/2023 2035 Bromodichloromethane 50 51 1 102 70-130 04/26/2023 2035 Bromoform 50 50 1 100 70-130 04/26/2023 2035 Bromomethane (Methyl bromide) 50 49 1 98 70-130 04/26/2023 2035 2-Butanone (MEK) 100 120 1 124 70-130 04/26/2023 2035 Carbon disulfide 50 54 1 107 70-130 04/26/2023 2035 Carbon tetrachloride 50 52 1 104 70-130 04/26/2023 2035 Chlorobenzene 50 53 1 107 70-130 04/26/2023 2035 Chloroethane 50 54 1 109 70-130 04/26/2023 2035 Chloroform 50 50 1 99 70-130 04/26/2023 2035 Chloromethane (Methyl chloride) 50 52 1 105 60-140 04/26/2023 2035 1,2-Dibromo-3-chloropropane (DBCP) 50 54 1 108 70-130 04/26/2023 2035 Dibromochloromethane 50 53 1 107 70-130 04/26/2023 2035 1,2-Dibromoethane (EDB) 50 53 1 105 70-130 04/26/2023 2035 Dibromomethane (Methylene bromide) 50 52 1 105 70-130 04/26/2023 2035 trans- 1,4-Dichloro-2-butene 50 51 1 101 70-130 04/26/2023 2035 1,2-Dichlorobenzene 50 55 1 110 70-130 04/26/2023 2035 1,4-Dichlorobenzene 50 53 1 105 70-130 04/26/2023 2035 1,1-Dichloroethane 50 51 1 102 70-130 04/26/2023 2035 1,2-Dichloroethane 50 52 1 104 70-130 04/26/2023 2035 1,1-Dichloroethene 50 53 1 105 70-130 04/26/2023 2035 cis- 1,2-Dichloroethene 50 52 1 104 70-130 04/26/2023 2035 trans- 1,2-Dichloroethene 50 53 1 105 70-130 04/26/2023 2035 1,2-Dichloropropane 50 51 1 103 70-130 04/26/2023 2035 cis- 1,3-Dichloropropene 50 51 1 102 70-130 04/26/2023 2035 trans- 1,3-Dichloropropene 50 53 1 107 70-130 04/26/2023 2035 Ethylbenzene 50 53 1 106 70-130 04/26/2023 2035 2-Hexanone 100 110 1 105 70-130 04/26/2023 2035 Methyl iodide (lodomethane) 50 52 1 103 70-130 04/26/2023 2035 4-Methyl-2-pentanone 100 100 1 100 70-130 04/26/2023 2035 Methylene chloride 50 52 1 104 70-130 04/26/2023 2035 Styrene 50 54 1 108 70-130 04/26/2023 2035 1,1,1,2-Tetrachloroethane 50 53 1 107 70-130 04/26/2023 2035 1,1,2,2-Tetrachloroethane 50 55 1 110 70-130 04/26/2023 2035 Tetrachloroethene 50 54 1 108 70-130 04/26/2023 2035 Toluene 50 55 1 109 70-130 04/26/2023 2035 1,1,1-Trichloroethane 50 52 1 104 70-130 04/26/2023 2035 1,1,2-Trichloroethane 50 54 1 107 70-130 04/26/2023 2035 Trichloroethene 50 51 1 103 70-130 04/26/2023 2035 Trichlorofluoromethane 50 53 1 106 70-130 04/26/2023 2035 1,2,3-Trichloropropane 50 57 1 115 70-130 04/26/2023 2035 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 39 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73762-002 Matrix: Aqueous Batch: 73762 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 54 1 108 60-140 04/26/2023 2035 Vinyl chloride 50 57 1 114 70-130 04/26/2023 2035 Xylenes (total) 100 110 1 109 70-130 04/26/2023 2035 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 39 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ73764-001 Matrix: Aqueous Batch: 73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/26/2023 2019 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 119 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 39 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ73764-002 Matrix: Aqueous Batch: 73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 45 1 90 70-130 04/26/20231823 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 108 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 39 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: YQ73764-003 Matrix: Aqueous Batch: 73764 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 43 1 85 5.3 70-130 20 04/26/20231931 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 102 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 39 ICP-MS Metals - MB Sample ID: YQ72773-001 Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/21/2023 0558 Arsenic ND 1 2.0 1.3 ug/L 04/21/2023 0558 Barium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Beryllium ND 1 0.40 0.15 ug/L 04/21/2023 0558 Cadmium ND 1 0.50 0.13 ug/L 04/21/2023 0558 Chromium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Cobalt ND 1 5.0 1.3 ug/L 04/21/2023 0558 Copper ND 1 5.0 1.3 ug/L 04/21/2023 0558 Lead ND 1 1.0 0.25 ug/L 04/21/2023 0558 Nickel ND 1 5.0 1.3 ug/L 04/21/2023 0558 Selenium ND 1 5.0 1.3 ug/L 04/21/2023 0558 Silver ND 1 1.0 0.25 ug/L 04/21/2023 0558 Thallium ND 1 0.50 0.15 ug/L 04/21/2023 0558 Vanadium ND 1 5.0 2.5 ug/L 04/21/2023 0558 Zinc ND 1 10 2.5 ug/L 04/21/2023 0558 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 39 ICP-MS Metals - LCS Sample ID: YQ72773-002 Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 112 80-120 04/21/2023 0605 Arsenic 100 110 1 106 80-120 04/21/2023 0605 Barium 100 100 1 105 80-120 04/21/2023 0605 Beryllium 100 100 1 101 80-120 04/21/2023 0605 Cadmium 100 110 1 105 80-120 04/21/2023 0605 Chromium 100 110 1 109 80-120 04/21/2023 0605 Cobalt 100 110 1 108 80-120 04/21/2023 0605 Copper 100 110 1 108 80-120 04/21/2023 0605 Lead 100 100 1 103 80-120 04/21/2023 0605 Nickel 100 110 1 106 80-120 04/21/2023 0605 Selenium 100 100 1 101 80-120 04/21/2023 0605 Silver 100 110 1 108 80-120 04/21/2023 0605 Thallium 100 100 1 104 80-120 04/21/2023 0605 Vanadium 100 110 1 107 80-120 04/21/2023 0605 Zinc 100 110 1 109 80-120 04/21/2023 0605 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 39 ICP-MS Metals - MS Sample ID: YD14073-003MS Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 110 1 112 75-125 04/21/2023 0645 Arsenic ND 100 110 1 106 75-125 04/21/2023 0645 Barium 33 100 140 1 106 75-125 04/21/2023 0645 Beryllium ND 100 94 1 94 75-125 04/21/2023 0645 Cadmium ND 100 110 1 106 75-125 04/21/2023 0645 Chromium ND 100 110 1 109 75-125 04/21/2023 0645 Cobalt ND 100 110 1 110 75-125 04/21/2023 0645 Copper ND 100 110 1 110 75-125 04/21/2023 0645 Lead ND 100 100 1 102 75-125 04/21/2023 0645 Nickel 1.8 100 110 1 105 75-125 04/21/2023 0645 Selenium ND 100 100 1 100 75-125 04/21/2023 0645 Silver ND 100 110 1 107 75-125 04/21/2023 0645 Thallium ND 100 100 1 104 75-125 04/21/2023 0645 Vanadium ND 100 110 1 108 75-125 04/21/2023 0645 Zinc ND 100 110 1 111 75-125 04/21/2023 0645 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 39 ICP-MS Metals - MSD Sample ID: YD14073-003MD Matrix: Aqueous Batch: 72773 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/18/2023 1845 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 110 1 109 2.1 75-125 20 04/21/2023 0652 Arsenic ND 100 100 1 104 1.6 75-125 20 04/21/2023 0652 Barium 33 100 130 1 98 5.7 75-125 20 04/21/2023 0652 Beryllium ND 100 95 1 95 1.0 75-125 20 04/21/2023 0652 Cadmium ND 100 100 1 105 1.5 75-125 20 04/21/2023 0652 Chromium ND 100 110 1 107 2.1 75-125 20 04/21/2023 0652 Cobalt ND 100 110 1 108 1.3 75-125 20 04/21/2023 0652 Copper ND 100 110 1 109 1.2 75-125 20 04/21/2023 0652 Lead ND 100 100 1 105 2.9 75-125 20 04/21/2023 0652 Nickel 1.8 100 110 1 103 2.0 75-125 20 04/21/2023 0652 Selenium ND 100 100 1 102 2.6 75-125 20 04/21/2023 0652 Silver ND 100 100 1 103 4.0 75-125 20 04/21/2023 0652 Thallium ND 100 100 1 102 2.4 75-125 20 04/21/2023 0652 Vanadium ND 100 110 1 106 2.0 75-125 20 04/21/2023 0652 Zinc ND 100 110 1 109 2.0 75-125 20 04/21/2023 0652 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 39 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 39 �0 CD CD vv m vv ° rn m v� <0 CD CD � r m n 0 o o _� v CD n d �; V <. 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