8106_DukeRogers_Q2_2023_CCPLF SemiAnnual Report_FID1815347_08162023

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Scott Spinner
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 573 Duke Power Road 8106 .0500 April 18-19, 2023
Roger's Energy Complex Mooresboro, North Carolina
Cliffside Steam Station
CCP Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ® Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Scott Spinner Project Manager [phone]
Facility Re esentative Name (Print) Title (Area Code) Telephone Number
.�,��-�7 8/11/2023 Affix NC Licensed/ Professional Geologist Seal
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
APRIL 2023 SAMPLING EVENT
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
CCP LANDFILL PHASES I THROUGH IV
f]:11N Moil MIMI181-1
TITLE: APRIL 2023 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: - I, , 0i r'W-iw_Date: August 11, 2023
Trevor Ludwick
Approved by: Date: August 11, 2023
Scott Spinner
Project Manager: Scott Spinner, NC LG
Licensed Geologist Seal:
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

L7
synTerra
Science & Enaineerina Consultants
synterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
APRIL 2023 SAMPLING EVENT
CCP LANDFILL PHASES I THROUGH IV
PERMIT No. 8106)
CLEVELAND AND RUTHERFORD COUNTIES
ROGERS ENERGY COMPLEX — CLIFFSIDE STEAM STATION
573 DUKE POWER ROAD
MOORESBORO, NORTH CAROLINA
AUGUST 11, 2023
PREPARED FOR
f
� DUKE
ENERGY..
CAROLINAS
DUKE ENERGY CAROLINAS, LLC
l� A
Kathryn W. Webb Trevor Ludwick
Senior Peer Reviewer Project Scientist
Scott Spinner, NC LG #2243
Project Manager

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0
INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1
Site and Landfill Information......................................................................................1-1
1.2
Hydrogeologic Setting................................................................................................1-1
1.3
Landfill Semiannual Monitoring Program...................................................................1-2
2.0
METHODS..................................................................................................................
2-1
2.1
Sampling and Analysis Methods.................................................................................2-1
2.2
Regulatory Criteria.....................................................................................................2-1
2.3
Statement of Work.....................................................................................................2-1
3.0
RESULTS.....................................................................................................................3-1
3.1
Site Groundwater Flow...............................................................................................3-1
3.2
Analytical Results.......................................................................................................3-1
3.3
Quality Assurance/Quality Control.............................................................................3-2
4.0
REFERENCES...............................................................................................................4-1
August 2023 Page i
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3A Groundwater Level Map — Surficial Flow Zone — April 2023
Figure 3B Groundwater Level Map — Bedrock Flow Zone — April 2023
LIST OF TABLES
Table 1 Monitoring Location Summary
Table 2 Well Construction Summary
Table 3 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 4 Groundwater Seepage Velocities
Table 5 Field Data Parameters
Table 6 Leachate Field Results and Analytical Detections
Table 7 Groundwater Field Results and Analytical Detections
Table 8 Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Table 9 Surface Water Field Results and Analytical Detections
Table 10 Field and Analytical Results that Equal or Exceed Surface Water Quality
Standards
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
August 2023 Page H
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF ACRONYMS
02L
Title 15A NCAC 02L .0202(g) Groundwater Quality Standards
02B
Title 15A NCAC 02B .0200 Surface Water and Wetland standards
CCP
Coal Combustion Products
CCR
Coal Combustion Residuals
Cliffside
Cliffside Steam Station
Duke Energy
Duke Energy Carolinas, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
HDPE
High -density polyethylene
landfill
CCP Landfill Phases I through IV
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
QA
Quality Assurance
QC
Quality Control
Site
Cliffside Steam Station
SW
Solid Waste
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
August 2023 Page iii
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
"KIMI►1f :1�]1�I� [�]►I_1 Ll:�_1�l:t�l:%1�1►L
This semiannual report pertains to the Duke Energy Carolinas, LLC (Duke Energy) Rogers Energy
Complex — Cliffside Steam Station (Cliffside, Site) Coal Combustion Products (CCP) Landfill
(landfill) and documents the results of the April 2023 groundwater, surface water, and leachate
monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates Cliffside, located at 573 Duke Power Road in Mooresboro,
North Carolina (Figure 1).
The CCP Landfill has been developed in four Phases (Phases I through IV) and comprises a total
area of approximately 71.7 acres. The CCP Landfill currently accepts coal combustion residual
(CCR) material generated during coal fired power generation and other CCR disposal needs for
the Site, which includes excavated CCR materials from the on -Site ash basins. The landfill
includes a liner system consisting of two geosynthetic barrier components (a 60-mil High -
density polyethylene (HDPE) geomembrane and a geosynthetic clay liner) between waste and
the groundwater beneath the landfill (SynTerra, 2022).
1.2 Hydrogeologic Setting
The Site is located in the Inner Piedmont Belt of the Piedmont Physiographic Province. The
Piedmont Physiographic Province in North Carolina is characterized by gentle to steep, hilly
terrain with small quantities of alluvium. The Inner Piedmont is bounded on the northwest by
the Brevard Fault zone, on the southeast by the Kings Mountain Belt, and by the faults and
shear zones that define the central Piedmont structure.
As typical in the Piedmont region, groundwater is present within the residuum, saprolite,
partially weathered rock, and fractured bedrock beneath the CCP Landfill. In general, surface
drainage from the CCP Landfill flows from the west to the north towards Duke Power Road, and
to the south and east towards Suck Creek. The highest elevations at the landfill are along the
western edge of the landfill.
Two streams are near the CCP Landfill. Suck Creek is located approximately 1,200 feet
southeast of the landfill and flows north to the Broad River. An unnamed tributary to the Broad
River is located approximately 1,100 feet west of the landfill. Surface waters draining to the
Broad River are classified as WS-IV per NC 15A NCAC Subchapter 02B. Based on evaluation of
local topography, shallow groundwater beneath the landfill liner is expected to discharge to
Suck Creek and the unnamed tributary.
The landfill and surrounding topographic and physiographic features are shown on Figure 2.
August 2023 Page 1-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
1.3 Landfill Semiannual Monitoring Program
The April 2023 sampling event and this Semiannual Water Quality Monitoring Report comply
with the Water Quality Monitoring Plan (WQMP), Revision 0 (SynTerra, 2022) submitted to the
North Carolina Department of Environmental Quality (NCDEQ) Division of Waste Management
(DWM), Solid Waste (SW) Section on March 31, 2022. The WQMP was subsequently approved
by the DWM on April 4, 2022. The landfill semiannual monitoring program, described in detail
in the WQMP, consists of 17 groundwater, 3 surface water, and 2 leachate monitoring locations
listed on Table 1 and shown on Figure 2. A summary of monitoring well construction
information is presented in Table 2 and analytical parameter coverage for the landfill
semiannual monitoring program is summarized in Table 3.
August 2023 Page 1-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling was performed by Pace Analytical Services
personnel (Pace Analytical, North Carolina Field Certification #5342) on April 18 and 19, 2023, in
accordance with the North Carolina SW Management Guidelines. Copies of the field sampling
forms are included in Appendix A. Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248) analyzed the reported parameters and constituents. The
laboratory report and chain -of -custody forms are included in Appendix B.
Duke Energy developed a list of parameters and constituents using guidance from the NCDEQ
DWM, SW Section. The samples were analyzed using the updated parameter and constituent
list, approved by NCDEQ on March 20, 2023. Dissolved selenium, not on the updated
constituent list as of the April 2023 sampling event, will be analyzed for surface water and
leachate samples in subsequent semiannual landfill sampling events. The monitoring
parameters, U.S. Environmental Protection Agency (USEPA) SW-846 analytical methods, and
applicable groundwater and surface water standards are present in Table 3.
2.2 Regulatory Criteria
Evaluation of the semiannual monitoring analytical results are compared to the following
regulatory criteria:
Groundwater
• 15A NCAC 02L .0202(g) Groundwater Quality standards (02L)
Surface Water
• 15A NCAC 02B .0200 Surface Water and Wetland standards (0213)
Leachate
• Not compared to water quality standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Groundwater, surface water, and leachate samples were collected by Pace Analytical on
April 18 and 19, 2023.
• Reviewed the laboratory analytical results pertaining to the parameters listed in Table 3.
• Compared groundwater analytical results to 02L and historical concentration ranges.
• Compared surface water analytical results to 02B and historical concentration ranges.
August 2023 Page 2-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
• Developed generalized groundwater surface contour maps using groundwater elevation
data provided by Duke Energy.
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Converted the laboratory provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of EDDs to the
NCDEQ DWM with this report.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
August 2023 Page 2-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
K311MG1*119W
3.1 Site Groundwater Flow
The predominant direction of groundwater flow at the Site is north toward the Broad River,
with a portion of groundwater in the central part of the Site flowing toward Suck Creek and
then north to the Broad River. Groundwater beneath CCP Landfill predominantly flows east or
southeast toward Suck Creek, with a portion of the groundwater flowing north/northeast
toward the Broad River or northwest toward an unnamed tributary of the Broad River.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCP Landfill are shown on Figure 3A for the surficial flow zone (shallow and deep
flow zones) and Figure 3B for the bedrock flow zone. These contours were developed by
calculating groundwater elevations in each monitoring well using the depth -to -water -level
measurements taken during the April 2023 monitoring event. Depth -to -water measurements
and calculated groundwater elevations are presented in Table 2. Calculated groundwater
seepage velocities are presented in Table 4. Calculated groundwater elevations, based on
depth -to -water measurements gauged during the April 2023 monitoring event, indicate
groundwater at the landfill generally flows to the east/southeast, consistent with historical Site
observations.
3.2 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table 5.
Analytical results and reference comparisons discussed below are summarized in Table 6
through Table 10. Sample locations are depicted on Figure 2.
Leachate
Leachate samples were collected from two discharge points (CCP-Leachate and CCP-Leachate-
34) located at the leachate pond. Analytical results are presented in Table 6. Leachate analytical
results are not compared to groundwater (02L) or surface water (02B) quality standards and are
provided for informational purposes only.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 7. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than 02L standards are noted in
Table 7 by bold font and grey cells. The laboratory analytical reports are included as
Appendix B. A summary of the downgradient groundwater field and analytical results that are
equal to or greater than comparison criteria are presented in Table 8. Groundwater samples
were not collected from monitoring wells CCPMW-3S, CCPMW-8, or CCPTW-2 due to
insufficient water volume in the wells. An evaluation to determine why these wells have gone
dry and whether replacement wells are needed has been initiated. Duke Energy will
August 2023 Page 3-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
communicate the results of that evaluation to NCDEQ in the next SW section semiannual
monitoring report.
Constituent concentrations in Table 7 which are identified as being equal or greater than their
applicable comparative criteria are not attributed to a release from the CCP Landfill.
Surface Water
Field and analytical results for surface water samples are presented in Table 9. The sample
locations are depicted on Figure 2. Analytical results for surface water samples are compared
with applicable 02B Class WS-IV surface water standards. Constituent concentrations greater
than 02B standards are noted in Table 9 by bold font and grey cells.
A summary of surface water analytical results equal to or greater than applicable comparison
criteria is presented in Table 10.
3.3 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of field blanks to evaluate if contamination was imparted to the samples by the sample
container, preservative, or other exogenous sources. Field duplicate samples were also
collected to estimate sampling and laboratory precision.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the EDD and in the lab report. Additional QA/QC data,
laboratory analyses, and chain -of -custody forms are included in Appendix B.
August 2023 Page 3-2
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
L111=04=440["i
SynTerra. (Rev 0, 2022). Water Quality Monitoring Plan, Rogers Energy Complex — Cliffside
Steam Station CCP Landfill Phases I Through IV, March 2022.
August 2023 Page 4-1
Project: 00.0092.67

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
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TOPOGRAPHY CONTOUR (10' INTERVAL)
NOTES;
1. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE
US ARMY CORPS OF ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP
IS NOT TO BE USED FOR JURISDICTIONAL DETERMINATION PURPOSES. THE
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2. ALL BOUNDARIES ARE APPROXIMATE.
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COLLECTED ON APR 2, 202D.
5. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE
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FIGURE 2
SAMPLE LOCATIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA
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PHASE III J6
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DUKE 1.50 asAPHIc sc 50 soo
' ENERGY
IIN FEET)
DRAWN Or B. MCGANN DATE" IW26/2022
REVISED BY. E. ORDEMANN DATE" O7/1912023
CHECKED BY: T. LUDWICK DATE 07, lW2023
_ APPROVED BY: S. SPINNER DATE'07/lW2023
AGER-$ SPINNER
synTerra PROJECT MAN ww R ntnrrArnrn r_nrn
LEGEND
Z SOLID WASTE SECTION MONITORING WELL
SOLID WASTE SECTION BACKGROUND MONITORING WELL
GROUNDWATER FLOW DIRECTION
-- INFERRED GROUNDWATER ELEVATION CONTOUR (FEET)
— - — LANDFILL COMPLIANCE BOUNDARY
— - — LANDFILL REVIEW BOUNDARY
LANDFILL LIMIT OF WASTE
ASH BASIN WASTE BOUNDARY
• DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
TOPOGRAPHY CONTOUR (10' INTERVAL)
—)N-- STREAM (AMEC NRTR)
® WETLANDS (AMEC NRTR)
NOTES:
1. WATER LEVELS WERE GAUGED ONAPRIL 1B, 2029.
2- ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF 1988 (NAVO
88).
3. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE US ARMY CORPS OF
ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP IS NOT TO BE USED FOR
JURIS DICTIOHAL DETERMINATION PURPOSES. THE WETLANDS AND STREAMS BOUNDARIES
WERE OBTAINED FROM STREAM AND WETLAND DELINEATION CONDUCTED BY AMEC FOSTER
WHEELER ENVIRONMENTAL AND INFRASTRUCTURE, INC- JUNE 2015-
4- ALL BOU N DAR PIES ARE A PPROXIMATE.
S PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROL INAS.
6- AERIAL IMACE RY IS A COMBINATION OF DUKE ENERGY PROPELLER PHOTOGRAPHY
COLLECTED ON APRIL 28, 2023 AND GOGGLE EARTH AERIAL PHOTOGRAPHY COLLECTED [I!
JUNE 8. 2022.
7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD89).
FIGURE 3B
GROUNDWATER LEVEL MAP - APRIL 2023
BEDROCK FLOW ZONE
SEMIANNUAL WATER QUALITY MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORSEBORO, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLES
tip
synTerra
Science & Engineering Consultants

TABLE 1
MONITORING LOCATION SUMMARY TABLE
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Media
Monitoring Location ID
Comments
CCR-CCPBG-1BR*
CCR-CCPBG-1BR was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCR-CCPBG-1D*
CCR-CCPBG-1D was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCPMW-IS*
CCPMW-IS was installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-1D*
CCPMW-1D was installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-2S
CCPMW-2S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-2D
CCPMW-2D was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3S
CCPMW-3S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3D
CCPMW-3D was installed for assessment, is located south and downgradient of the landfill.
Groundwater
CCPMW-4
CCPMW-4 was installed for assessment, is located northwest and downgradient of the landfill.
CCPMW-5
CCPMW-5 was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6S
CCPMW-6S was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6D
CCPMW-6D was installed for assessment, is located north and downgradient of the landfill.
CCPMW-7
CCPMW-7 was installed for assessment, is located north and downgradient of the landfill.
CCPMW-8
CCPMW-8 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-10
CCPMW-10 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-11
CCPMW-11 was installed for assessment, is located southeast and downgradient of the landfill.
CCPTW-2
CCPTW-2 was installed for assessment, is located south and downgradient of the landfill.
CCPSW-1
CCPSW-1 surface water monitoring location is south and upgradient of the landfill.
Surface Water
CCPSW-2
CCPSW-2 surface water monitoring location is east and downgradient of the landfill.
CCPSW-3
CCPSW-3 surface water monitoring location is west and downgradient of the landfill.
Leachate
CCP-Leachate
Leachate sample, representing leachate from Phases 1 and 2 of the landfill, collected from an in -line sampling point south and
downgradient of the landfill.
CCP-Leachate-34
Leachate sample, representing leachate from Phases 3 and 4 of the landfill, collected from an in -line sampling point south and
clowngradient of the landfill.
Note:
See Table 2 Well Construction Summary for monitoring well construction information.
* - Indicates background groundwater monitoring well.
CCP - Coal combustion products
Prepared by: TWL Checked by: CSM
Page 1 of 1

TABLE 2
WELL CONSTRUCTION SUMMARY
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(ft, BTOQ
Screened
Interval
(ft, BGS)
Measuring
Point TOC
(ft, NAVD 88)
Ground
Surface
(ft, NAVD 88)
Groundwater
Elevation
(ft, NAVD 88)
Depth
to Water
(ft, BTOC)
CCR-CCPBG-1BR*
7/23/2020
Bedrock
PVC
2
35.203831869
-81.775968852
98.75
91.0 - 96.0
889.02
886.52
835.74
53.28
CCR-CCPBG-1D*
7/17/2020
Deep
PVC
2
35.203856335
-81.775968875
50.74
43.0 - 48.0
889.28
886.26
841.96
47.32
CCPMW-1S*
2/23/2010
Deep
PVC
2
35.206702100
-81.774304900
42.45
30.0 - 40.0
875.58
873.24
838.88
36.70
CCPMW-1D*
2/24/2010
Bedrock
PVC
2
35.206713399
-81.774299699
56.95
49.0 - 54.0
875.89
873.33
838.47
37.42
CCPMW-2S
2/24/2010
Shallow
PVC
2
35.203550900
-81.772735000
44.30
32.0 - 42.0
842.24
840.26
802.96
39.28
CCPMW-2D
2/24/2010
Bedrock
PVC
2
35.203552399
-81.772721900
72.80
65.0 - 70.0
842.35
840.20
801.65
40.70
CCPMW-3S
6/27/2007
Shallow
PVC
2
35.203409300
-81.771019100
15.29
9.0 - 14.0
811.56
810.56
796.81
14.75
CCPMW-3D
7/16/2007
Bedrock
PVC
2
35.203408701
-81.771000500
35.41
26.0 - 31.0
811.74
810.47
793.12
18.62
CCPMW-4
10/26/2015
Bedrock
PVC
2
35.208929900
-81.774815100
68.31
50.0 - 65.0
845.95
843.29
819.84
26.11
CCPMW-5
10/23/2015
Bedrock
PVC
2
35.209926100
-81.772851900
75.42
62.5 - 72.5
858.63
855.87
817.52
41.11
CCPMW-6S
10/21/2015
Deep
PVC
2
35.208665599
-81.771117398
46.79
33.5 - 43.5
854.38
851.48
816.09
38.29
CCPMW-6D
10/26/2015
Bedrock
PVC
2
35.208653899
-81.771102700
63.00
50.0 - 60.0
854.35
851.45
816.10
38.25
CCPMW-7
7/8/2020
Shallow
PVC
2
35.207790757
-81.769444485
51.07
37.0 - 47.0
855.49
852.63
BTOP
BTOP
CCPMW-8
7/6/2020
Shallow
PVC
2
35.203717021
-81.769460949
49.05
35.0 - 45.0
831.52
828.24
782.89 (Eff. Dry)
48.63
CCPMW-10
7/7/2020
Shallow
PVC
2
35.203376929
-81.768415081
45.38
32.0 - 42.0
812.98
810.45
777.98
35.00
CCPMW-11
7/1/2020
Shallow
PVC
2
35.203812900
-81.766750379
33.75
20.0 - 30.0
803.32
800.24
779.18
24.14
CCPTW-2
2/25/2010
Shallow
PVC
2
35.203862801
1 -81.770429800
1 45.00
35.0 - 45.0
841.72
839.62
BTOP
BTOP
Notes:
Groundwater elevations are based on water level data collected on April 18-19, 2023.
* - Indicates background groundwater monitoring well.
BGS - Below ground surface
BTOC - Below top of casing
BTOP - Water level is below top of pump and not gauged.
CCP - Coal combustion products
Eff. Dry - Monitoring well effectively dry. Measured water level not representative of groundwater elevation. Groundwater elevation presented as "dry" on figure.
ft - Feet
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988
PVC - Polyvinylchloride
Prepared by: TWL Checked by: CSM
Page 1 of 1

TABLE 3
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
CCP LANDFILL PHASES I - IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Constituent
Analytical Methods
Units
15A NCAC 02L
Standards for
Groundwater
15A NCAC 02B
(Class WS-IV) Standards, ISTV, and
USEPA Criteria for Surface Water
In Situ Parameters
pH
Multi -Parameter Water Quality Meter
S.U.
6.5-8.5
6.0-9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
<_ 29
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
> 4
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
NE
NE
Turbidity
Turbidimeter
NTU
NE
Streams 5 50
Water Level
Water Level Meter
ft
NE
NE
Laboratory Analyses
Antimony
EPA 200.8/EPA 6020E
µg/L
1
5,300
Arsenic
EPA 200.8/EPA 6020E
µg/L
10
10
Barium
EPA 200.7/EPA 6010D
µg/L
700
1,000
Beryllium
EPA 200.7/EPA 6010D
µg/L
4
NE
Beryllium (dissolved)
EPA 200.7/SW 6010D
µg/L
NE
65�
Boron
EPA 200.7/EPA 6010D
µg/L
700
34,000#
Cadmium
EPA 200.8/EPA 6020E
µg/L
2
NE
Cadmium (dissolved)
EPA 200.8/SW 6020E
µg/L
NE
0.75A't
Calcium
EPA 200.7/SW 6010D
mg/L
NE
NE
Chloride
EPA 300.0/EPA 9056A
mg/L
250
230
Chromium
EPA 200.8/EPA 6020E
µg/L
10
NE
Chromium (dissolved)
EPA 200.8/SW 6020E
µg/L
NE
180A'x
Cobalt
EPA 200.8/EPA 6020E
µg/L
1
3$
Copper
EPA 200.7/EPA 6010D
µg/L
1,000
NE
Copper (dissolved)
EPA 200.7/SW 6010D
µg/L
NE
3.6A't
Fluoride
EPA 300.0/EPA 9056A
mg/L
2
1.8
Iron
EPA 200.7/EPA 6010D
µg/L
300
1,000*
Lead
EPA 200.8/EPA 6020E
µg/L
15
NE
Lead (dissolved)
EPA 200.8/SW 6020E
µg/L
NE
14A't
Lithium
EPA 200.8/SW 6020E
µg/L
NE
NE
Magnesium
EPA 200.8/SW 6020E
mg/L
NE
NE
Manganese
EPA 200.7/EPA 6010D
µg/L
50
50*
Mercury
EPA 7470A
µg/L
1
0.012
Molybdenum
EPA 200.8/SW 6020E
µg/L
NE
160$
Nickel
EPA 200.7/EPA 6010D
µg/L
100
25
Nickel (dissolved)
EPA 200.7/SW 6010D
µg/L
NE
140A't
Nitrate
EPA 300.0/EPA 9056A
mg-N/L
10
10
Selenium
EPA 200.8/EPA 6020E
µg/L
20
NE
Silver
EPA 200.8/EPA 6020E
µg/L
20
NE
Silver (dissolved)
EPA 200.8/SW 6020E
µg/L
NE
0.30A't
Sulfate
EPA 300.0/EPA 9056A
mg/L
250
250
Thallium
EPA 200.8/EPA 6020E
µg/L
2
2$
Total Dissolved Solids
SM 2540C
mg/L
500
500
Total Hardness
Calculation (2.497 (calcium) + 4.118 (magnesium))
mg/L
NE
100
Vanadium
EPA 200.8/EPA 6020E
µg/L
7
NE
Zinc
EPA 200.7/EPA 6010D
µg/L
1,000
NE
Zinc dissolved
EPA 200.7/SW 6010D
I ltg/L
NE
1 36"'t
Prepared by: TWL Checked by: SAS
Notes:
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
15A NCAC 02B Standards for Class WS-IV surface waters. Water quality standards applicable to Class C waters also apply to Class WS-IV waters.
North Carolina surface water and wetland standards (effective September 1, 2022).
ISTV - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
Total hardness and dissolved constituents are applicable to surface water analytical parameters only.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the
Aquatic Life & Secondary Recreation or Fish Consumption value, when applicable.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method.
An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided
for screening purposes only.
- Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
"- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
NE - Not established
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
EPA - US Environmental Protection Agency
ft- feet
mg/L - milligrams per liter
mg-N/L - Milligrams nitrogen per liter
mV - millivolts
NTU - nephelometric turbidity units
S.U. - Standard Units
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Well ID
Elevation
Elevation
(ft/day)'
(ft)
(ft)
Effective PorosityZ
Velocity
(ft/day)
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-8 to CCPMW-10
1 782.89
1 777.98
1 1.02
1 4.91
1 336
1 0.20
1 0.075
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective PorosityZ
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)3
(ft, NAVD 88)
(ft, NAVD 88)
CCPMW-1D to CCPMW-3D
838.47
793.12
1.30
45.35
1555
0.05
0.758
CCPMW-1D to CCPMW-6D
838.47
816.10
1.30
22.37
1188
0.05
0.490
Prepared by: TWL Checked by: CSM
Notes:
1- Values used are a calculated Geomean of hydraulic conductivities in paired wells. Hydraulic conductivity values are derived from slug test data presented in the Groundwater Monitoring Well
Installation Report (SynTerra, April 2021).
Z - Value taken from Updated Groundwater Flow and Transport Modeling Report for Cliffside Steam Station, Mooresboro, NC, December 2019 (SynTerra) .
s - Value represents an estimate of the velocity of groundwater through bedrock fractures.
ft - feet
ft/day - feet per day
Groundwater elevations are based on water level data collected on April 18-19, 2023.
Hydraulic gradients and groundwater velocities are approximate.
NAVD 88 - North American Vertical Datum of 1988
Page 1 of 1

TABLE 5
FIELD DATA PARAMETERS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Sample ID
Sample Date
Appearance
Odor
Purge Method
Average Pump Rate
mL min
( / )
Temp
De C
(Deg )
Specific
Conductance
(µmhos/cm)
pH
S.U.
( )
ORP
mV
( )
Dissolved Oxygen
m L
( g/)
Turbidity
NTU
( )
Groundwater
Elevation
A NAVD 88)
Depth to Water
ft, BTOC
( )
Groundwater Parameters
CCR-CCPBG-1D*
4/18/2023
Clear
None
Mega Monsoon
140
21
73
5.3
188
7.7
8.2
841.96
47.32
CCR-CCPBG-1BR*
4/18/2023
Clear
None
Bladder Pump
140
18
1,576
7.6
134
2.6
0.4
835.74
53.28
CCPMW-1S*
4/18/2023
Clear
None
Bladder Pump
160
20
25
4.9
49
10.5
1.5
838.88
36.70
CCPMW-1D*
4/18/2023
Clear
None
Bladder Pump
160
19
50
5.4
124
5.9
0.5
838.47
37.42
CCPMW-2S
4/18/2023
Clear
None
Bladder Pump
200
19
52
5.2
115
6.9
1.0
802.96
39.28
CCPMW-2D
4/18/2023
Clear
None
Mega Monsoon
1,000
19
122
8.4
53
3.8
1.1
801.65
40.70
CCPMW-3S
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
796.81
14.75
CCPMW-3D
4/18/2023
Clear
None
Peristaltic Pump
70
20
108
5.6
166
5.9
1.0
793.12
18.62
CCPMW-4
4/18/2023
Clear
None
Bladder Pump
100
17
172
8.2
9
0.4
1.4
819.84
26.11
CCPMW-5
4/18/2023
Small particulates
None
Mega Monsoon
250
20
289
11.0
62
4.7
7.4
817.52
41.11
CCPMW-6S
4/18/2023
Clear
None
Bladder Pump
180
20
56
4.6
127
10.9
6.2
816.09
38.29
CCPMW-6D
4/18/2023
Clear
None
Bladder Pump
160
21
53
5.3
98
6.4
0.1
816.10
38.25
CCPMW-7
4/19/2023
Small particulates
None
Bladder Pump
50
19
85
5.6
89
5.8
4.0
BTOP
BTOP
CCPMW-8
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
782.89 (Eff. Dry)
48.63
CCPMW-10
4/19/2023
Clear
None
Bladder Pump
140
18
47
5.0
61
5.2
1.7
777.98
35.00
CCPMW-11
4/19/2023
Clear
None
Peristaltic Pump
180
23
84
5.7
55
4.3
9.7
779.18
24.14
CCPTW-2
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
BTOP
BTOP
Surface Water Parameters
CCPSW-1
4/18/2023
Clear
None
Grab
NA
16
72
5.8
100
9.9
5.7
NA
NA
CCPSW-2
4/18/2023
Clear
Unknown#
Grab
NA
13
49
6.8
185
8.5
16.8
NA
NA
CCPSW-3
4/18/2023
Clear
None
Grab
NA
15
46
4.8
89
7.8
2.8
NA
NA
Leachate Collection Parameters
CCP-Leachate
4/19/2023
Clear
None
Grab
NA
18
33,389
4.5
161
9.8
0.3
NA
NA
CCP-Leachate-34
4/19/2023
Clear
None
Grab
NA
18
3,274
4.7
81
8.4
6.0
NA
NA
Notes:
* - Indicates background groundwater monitoring well.
# - Odor for surface water at sampling location is illegible in field log.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
Monitoring wells CCPMW-3S, CCPMW-8, and CCPTW-2 not sampled due to insufficient volume of water.
Water level data collected on April 18-19, 2023.
µmhos/cm - micromhos per centimeter
BTOC - Below top of casing
BTOP - Below top of Pump
Deg C - Degrees Celsius
Eff. Dry - Monitoring well effectively dry. Measured water level not representative of groundwater elevation. Groundwater elevation presented as "dry" on figure.
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - Not Applicable
NAVD88 - North American Vertical Datum of 1988
NS - Not Sampled
NTU - Nephelometric Turbidity Units
ORP - Oxidation Reduction Potential
S.U. - Standard units
Prepared by: TWL Checked by: AMH
Page 1 of 1

TABLE 6
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
CCP-Leachate
CCP-Leachate-34
pH
320
S.U.
4.5
4.7
-
Temperature
325
Deg C
18
18
-
Specific Conductance
323
µmhos/cm
33,389
3,274
-
Dissolved Oxygen
NE
mg/L
9.8
8.4
-
Oxidation Reduction Potential
336
mV
161
81
-
Eh
NE
mV
361
281
-
Turbidity
330
NTUs
0.3
6.0
-
Antimony
13
µg/L
0.233 J
0.285 J
0.104
Arsenic
14
µg/L
7.02
4.62
0.111
Barium
15
µg/L
370
58
2
Beryllium
23
µg/L
1.26 J
5.53
0.249
Beryllium (dissolved)
23
µg/L
0.79 J
5.55
0.249
Boron
428
µg/L
10,000
4,360
5
Cadmium
34
µg/L
1.76
1.64
0.032
Cadmium (dissolved)
34
µg/L
1.78
1.60
0.032
Calcium
375
mg/L
7,120
633
0.012
Chloride
301
mg/L
13,000
460
0.0154
Chromium
51
µg/L
0.44 J
2.50
0.185
Chromium (dissolved)
51
µg/L
0.475 J
2.48 J
0.185
Cobalt
53
µg/L
477
331
0.077
Copper
54
µg/L
32.0
115
0.787
Copper (dissolved)
54
µg/L
34.3
113
0.787
Fluoride
312
mg/L
0.11
0.34 J
0.0479
Iron
340
µg/L
290
126
4
Lead
131
µg/L
122
20.0
0.037
Lead (dissolved)
131
µg/L
119
19.3
0.037
Lithium
NE
µg/L
7,030
111
2
Magnesium
376
mg/L
48.6
83.5
0.008
Manganese
342
µg/L
10,200
11,600
1
Mercury
132
µg/L
0.04 J
0.02 J
0.01
Molybdenum
397
µg/L
306
1.72
0.18
Nickel
152
µg/L
98.2
243
0.256
Nickel (dissolved)
152
µg/L
99.1
237
0.256
Nitrate (as N)
303
mg-N/L
4.2 J
2.3
0.002
Selenium
183
µg/L
76.7
21.2
0.193
Silver
184
µg/L
0.111
0.056 J
0.035
Silver (dissolved)
184
µg/L
0.124 J
< 1
0.035
Sulfate
315
mg/L
850
1,400
0.0428
Thallium
194
µg/L
8.77
1.95
0.041
Total Dissolved Solids
1 311
mg/L
1 22,600
1 2,750
25
Page 1 of 2

TABLE 6
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
CCP-Leachate
CCP-Leachate-34
Total Hardness
NE
mg/L
18,000
1,920
-
Vanadium
209
µg/L
0.883 J
< 0.3
0.114
Zinc
213
µg/L
100
241
4
Zinc (dissolved)
213
µg/L
162
265
4
Prepared by: AMH Checked by: TWL CSM
Notes:
Samples collected by Pace Analytical personnel on April 19, 2023.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
Field duplicate sample collected at CCP-Leachate monitoring location.
<- Concentration not detected at or above the adjusted reporting limit.
A blank cell means there is no relevant information.
°C - degrees Celsius
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - Millivolts
NE - Not Established
NTUs - Nephelometric Turbidity Units
S.U. - Standard Units
SWS ID - Solid Waste Section Identification Number
Page 2 of 2

TABLE 7
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW
GWPS
15A NCAC
02L Standard
CCPMW-15
CCPMW-ID
CCPMW-2S
CCPMW-2D
CCPMW-35
CCPMW-3D
CCPMW-4
CCPMW-5
CCPMW-6S
CCPMW-6D
CCPMW-7
CCPMW-8
CCPMW-10
CCPMW-11
CCPTW-2
CCR-CCPBG-1D
CCR-CCPBG-1BR
pH
320
S.U.
4.9
5.4
5.2
8.4
NS
5.6
8.2
11.0
4.6
5.3
5.6
NS
5.0
5.7
NS
5.3
7.6
NE
6.5-8.5
Temperature
325
Deg C
20
19
19
19
NS
20
17
20
20
21
19
NS
18
23
NS
21
18
NE
NE
Specific Conductance
323
µmhos/cm
25
50
52
122
NS
108
172
289
56
53
85
NS
47
84
NS
73
1,576
NE
NE
Dissolved Oxygen
NE
mg/L
10.5
5.9
6.9
3.8
NS
5.9
0.4
4.7
10.9
6.4
5.8
NS
5.2
4.3
NS
7.7
2.6
NE
NE
Oxidation Reduction Potential
336
mV
49
124
115
53
NS
166
9
62
127
98
89
NS
61
55
NS
188
134
NE
NE
Eh
NE
mV
249
324
315
253
NS
366
209
262
327
298
289
NS
261
255
NS
388
334
NE
NE
Turbidity
330
NTUs
1.5
0.5
1.0
1.1
NS
1.0
1.4
7.4
6.2
0.1
4.0
NS
1.7
9.7
NS
8.2
0.4
NE
NE
Antimony
13
µg/L
< 1
< 1
0.113 J
< 1
NS
< 1
0.207 J
0.642 J
< 1
< 1
< 1
NS
< 1
< 1
NS
0.155 J
0.237 J
0.104
NE
1
Arsenic
14
µg/L
< 1
< 1
< 1
0.581 J
NS
< 1
0.356 J
2.84
< 1
< 1
< 1
NS
< 1
0.167 J
NS
< 1
1.22
0.111
NE
10
Barium
15
µg/L
18
16
30
9
NS
29
119
3 J
42
42
31
NS
49
38
NS
33
10
2
NE
700
Beryllium
23
µg/L
<1
<1
<1
<1
NS
<1
<1
<1
<1
<1
<1
NS
<1
<1
NS
<1
<1
0.249
NE
4
Boron
428
µg/L
5 J
7 J
10 J
< 50
NS
73
13 J
16 J
< 50
< 50
< 50
NS
6 J
13 J
NS
< 50
15 J
5
NE
700
Cadmium
34
µg/L
<1
<1
0.081
<1
NS
<1
<1
<1
0.04J
<1
<1
NS
<1
<1
NS
<1
<1
0.032
NE
2
Calcium
375
mg/L
0.129
2.68
2.75
14.8
NS
12.0
11.5
31.3
1.60
1.48
4.38 J
NS
1.68
3.09
NS
3.35
57.4
0.012
NE
NE
Chloride
301
mg/L
4.0
8.0
2.9
5.4
NS
6.0
1.7
4.8
4.8
5.6
11
NS
5.5
4.6
NS
9.5
210
0.0154
NE
250
Chromium
51
µg/L
1.48
0.238 J
1.38
1.79
NS
1.10
0.847 J
5.14
2.00
1.22
1.28
NS
1.09
1.72
NS
0.638 J
0.883 J
0.185
NE
10
Cobalt
53
µg/L
1.33
0.32 J
0.392 J
< 1
NS
< 1
0.089 J
0.105 J
2.10
1.13
0.196 J
NS
0.92 J
0.1111
NS
0.993 J
0.13 J
0.077
NE
1
Copper
54
µg/L
< 1
< 1
< 1
1.67
NS
< 1
< 1
1.50
< 1
< 1
< 1
NS
< 1
< 1
NS
< 1
< 1
0.787
NE
1,000
Fluoride
312
mg/L
< 0.1
< 0.1
< 0.1
< 0.1
NS
< 0.1
0.14
0.1
< 0.1
< 0.1
< 0.1
NS
< 0.1
< 0.1
NS
< 0.1
0.14 J
0.0479
NE
2
Iron
340
µg/L
69
18
28
91
NS
< 10J
23
168
229
8J
69
NS
82
635
NS
247
13
4
NE
300
Lead
131
µg/L
0.06 J
< 1
0.098 J
0.08 J
NS
< 1
< 1
0.297 J
0.168 J
< 1
0.071 J
NS
0.115 J
0.54 J
NS
0.126 J
< 1
0.037
NE
15
Lithium
NE
µg/L
<5
<5
<5
5J
NS
<5
37
<5
<5
<5
<5
NS
<5
<5
NS
<5
16
2
NE
NE
Magnesium
376
mg/L
0.515
1.41
1.89
0.916
NS
2.48
0.752
0.194
2.05
1.83
1.66
NS
1.73
1.54
NS
2.36
4.96
0.008
NE
NE
Manganese
342
µg/L
16
7
31
2J
NS
7
8
7
45
26
35
NS
17
12
NS
44
76
1
NE
50
Mercury
132
µg/L
0.05 J
0.011
0.02 J
0.02 J
NS
0.02 J
0.011
0.02 J
0.011
0.011
0.011
NS
0.05
0.02 J
NS
0.02 J
0.02 J
0.01
NE
1
Molybdenum
397
µg/L
< 1
< 1
< 1
0.5111
NS
< 1
7.89
1.25
< 1
< 1
0.205 J
NS
< 1
0.187 J
NS
< 1
39.1
0.18
NE
NE
Nickel
152
µg/L
0.644 J
0.87 J
0.482 J
0.512 J
NS
< 1
0.274 J
0.755 J
2.84
0.622 J
1.16
NS
0.663 J
1.60
NS
0.925 J
2.39
0.256
NE
100
Nitrate (as N)
303
mg-N/L
0.04
0.32
1.8
1.3
NS
1.0
0.16
0.90
3.5
2.5
2.2
NS
1.7
1.3
NS
3.6
1.2
0.002
NE
10
Selenium
183
µg/L
< 1
< 1
0.593 J
< 1
NS
0.423 J
< 1
0.286 J
< 1
< 1
< 1
NS
< 1
< 1
NS
< 1
< 1
0.193
NE
20
Silver
184
µg/L
<1
<1
0.05J
<1
NS
<1
<1
<1
<1
<1
<1
NS
0.058J
<1
NS
<1
<1
0.035
NE
20
Sulfate
315
mg/L
0.96
1.3
5.3
1 4.5
NS
24
29
20
1.7
0.30
0.56
NS
0.18
2.4
NS
1 0.38
300
0.0428
NE
250
Thallium
194
µg/L
0.041 J
< 0.2
0.099 J
< 0.2
NS
< 0.2
< 0.2
< 0.2
0.117 J
0.07 J
0.068 J
NS
0.063 J
0.086 J
NS
0.066 J
< 0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
< 25
34.0
35.0
87.0
NS
63.0
119
110
41.0
40.0
61.0
NS
36.0
62.0
NS
58.0
857
25
NE
500
Vanadium
209
µg/L
0.13 J
< 0.3
0.245 J
4.40
NS
0.169 J
0.269 J
15.1
0.325
< 0.3
0.258 J
NS
0.165 J
1.11
NS
0.383
1.05
0.114
NE
7
Zinc
213
µg/L
<5
<5
<5
<5
NS
<5
<5
<5
<5
_LL_j
<5
NS
<5
<5
NS
<5
<5
4
NE
1,000
Notes:
Bold and grey concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH, greater than or less than the 02L Standard range).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2022.
CCPMW-1S/D and CCR-CCPBG-1D/BR are background groundwater monitoring wells.
Field duplicate sample collected at CCPMW-3D.
Samples collected by Pace Analytical personnel on April 18 and 19, 2023
1 - Value is estimated. The result is below the reporting limit or potentially biased
based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples
not diluted by the laboratory during analysis.
SW GWPS -Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
Deg C - degrees Celsius
NCAC - North Carolina Administrative Code
µg/L - micrograms per liter
NE - Not Established
µmhos/cm - micromhos per centimeter
NS - Not Sampled
mg/L - milligrams per liter
NTUs - Nephelometric Turbidity Units
mg-N/L- milligrams nitrogen per liter
S.U. -Standard Units
mV - Millivolts
Prepared by: AMH Checked by: CSM TWL
Page 1 of 1

TABLE 8
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
Sample ID
April 2023 Concentration
Units
15A NCAC
02L Standard
Historical
Concentration Range
Cause and Significance
pH
CCPMW-1ST
4.9
S.U.
6.5 - 8.5
4.4 - 6.6
pH is consistent with the range of historical readings at CCPMW-1S
CCPMW-1D*
5.4
4.4 - 9.7
pH is consistent with the range of historical readings at CCPMW-1D
CCPMW-2S
5.2
4.4 - 6.4
pH is consistent with the range of historical readings at CCPMW-2S
CCPMW-3D
5.6
4.7 - 5.5
pH is greater than the range of historical readings at CCPMW-3D
CCPMW-5
11.0
8.1 - 11.0
pH is consistent with the range of historical readings at CCPMW-5
CCPMW-6S
4.6
4.7 - 5.8
pH is less than the range of historical readings at CCPMW-6S
CCPMW-6D
5.3
5.1- 5.4
pH is consistent with the range of historical readings at CCPMW-6D
CCPMW-7
5.6
4.7 - 5.8
pH is consistent with the range of historical readings at CCPMW-7
CCPMW-10
5.0
4.5 - 5.2
pH is consistent with the range of historical readings at CCPMW-10
CCPMW-11
5.7
5.3 - 5.8
pH is consistent with the range of historical readings at CCPMW-11
CCR-CCPBG-1D*
5.3
5.1- 5.4
pH is consistent with the range of historical readings at CCR-CCPBG-1D
Cobalt
CCPMW-1ST
1.33
µg/L
1
0.6 - 10.7
Cobalt is consistent with the range of historical concentrations at CCPMW-IS
CCPMW-6S
2.10
1.95 - 10.3
Cobalt is consistent with the range of historical concentrations at CCPMW-6S
CCPMW-6D
1.13
0.527 - 1.86
Cobalt is consistent with the range of historical concentrations at CCPMW-6D
Iron
CCPMW-11
635
µg/L
300
58 - 497
Iron is greater than the range of historical concentrations at CCPMW-11
Manganese
CCR-CCPBG-1BR*
76
µg/L
50
25 - 62
Manganese is greater than the range of historical concentrations at CCR-CCPBG-1BR
Sulfate
CCR-CCPBG-1BR*
300
mg/L
250
28 - 340
Sulfate is consistent with the range of historical concentrations at CCR-CCPBG-1BR
TDS
CCR-CCPBG-1BR*
857
mg/L
500
165 - 1,090
TDS is consistent with the range of historical concentrations at CCR-CCPBG-1BR
Vanadium
CCPMW-5
15.1
µg/L
7
7.54 - 17.1
Vanadium is consistent with the range of historical concentrations at CCPMW-5
Notes:
Historical ranges are based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting. Historical ranges exclude sample data with turbidity values greater than 10 NTUs.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
CCPMW-1S/D and CCR-CCPBG-1D/BR are background groundwater monitoring wells.
µg/L - micrograms per liter
mg/L - milligrams per liter
NCAC - North Carolina Administrative Code
NTUs - Nephelometric Turbidity Units
S.U. - Standard Units
TDS - total dissolved solids
Prepared by: AMH Checked by: CSM TWL
Page 1 of 1

TABLE 9
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Surface Water
Sample ID
MDI.
15A NCAC 02B
1
(Class WS-IV) Standards', ISTV,
and USEPA Criteria
CCPSW-1
CCPSW-2
CCPSW-3
pH
320
S.U.
5.8
6.8
4.8
-
6.0-9.0
Temperature
325
°C
16
13
15
-
<_ 29
Specific Conductance
323
µmhos/cm
72
49
46
-
NE
Dissolved Oxygen
NE
mg/L
9.9
8.5
7.8
-
>_ 4
Oxidation Reduction Potential
336
mV
100
185
89
-
NE
Eh
NE
mV
300
385
289
-
NE
Turbidity
330
NTUs
5.7
16.8
2.8
-
Streams <_ 50
Antimony
13
µg/L
< 1
< 1
< 1
0.104
5,300$
Arsenic
14
µg/L
0.243 J
0.242 J
< 1
0.111
10
Barium
15
µg/L
25
26
17
2
1,000
Beryllium
23
µg/L
< 1
< 1
< 1
0.249
NE
Beryllium (dissolved)
23
µg/L
< 1
< 1
< 1
0.249
65^
Boron
428
µg/L
6 J
6 J
9 J
5
34,000#
Cadmium
34
µg/L
< 1
< 1
< 1
0.032
NE
Cadmium (dissolved)
34
µg/L
< 1
0.128 J
< 1
0.032
0.75"t
Calcium
375
mg/L
2.39
2.59
2.34
0.012
NE
Chloride
301
mg/L
3.9
4.0
4.5
0.0154
230
Chromium
51
µg/L
0.708 J
0.709 J
0.647 J
0.185
NE
Chromium (dissolved)
51
µg/L
0.312 J
0.352 J
0.347 J
0.185
180^'x
Cobalt
53
µg/L
0.324 J
0.358 J
0.255 J
0.077
3$
Copper
54
µg/L
< 1
< 1
< 1
0.787
NE
Copper (dissolved)
54
µg/L
0.8211
3.99
3.65
0.787
3.6^'t
Fluoride
312
mg/L
< 0.1
< 0.1
< 0.1
0.0479
1.8
Iron
340
µg/L
1,150
1,200
245
4
1,000*
Lead
131
µg/L
0.259 J
0.312 J
0.205 J
0.037
NE
Lead (dissolved)
131
µg/L
0.123 J
0.161 J
0.098 J
0.037
14^'t
Lithium
NE
µg/L
< 5
< 5
< 5
2
NE
Magnesium
376
mg/L
1.27
1.34
1.48
0.008
NE
Manganese
342
µg/L
41
39
8
1
50*
Mercury
132
µg/L
0.02 J
0.02 J
0.03 J
0.01
0.012
Molybdenum
397
µg/L
< 1
< 1
< 1
0.18
160$
Nickel
152
µg/L
0.458 J
0.428 J
0.374 J
0.256
25
Nickel (dissolved)
152
µg/L
0.48 J
0.481 J
0.425 J
0.256
140"t
Nitrate (as N)
303
mg-N/L
0.45
0.46
0.06
0.002
10
Selenium
183
µg/L
< 1
< 1
< 1
0.193
NE
Silver
184
µg/L
< 1
< 1
< 1
0.035
NE
Silver (dissolved)
184
µg/L
< 1
< 1
< 1
0.035
0.30^'t
Sulfate
315
mg/L
1.6
2.0
3.0
0.0428
250
Thallium
194
µg/L
< 0.2
< 0.2
< 0.2
0.041
2$
Total Dissolved Solids
311
mg/L
34.0
32.0
33.0
25
500
Total Hardness
NE
mg/L
11.2
12.0
12.0
NA
100
Page 1 of 2

TABLE 9
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surface Water
15A NCAC 02B
Parameter
SWS ID
Units
Sample ID
MDL
(Class WS-IV) Standards', ISTV,
CCPSW-1
CCPSW-2
CCPSW-3
and USEPA Criteria
Vanadium
209
µg/L
0.669
0.822
0.565
0.114
NE
Zinc
213
µg/L
4 J
< 5
< 5
4
NE
Zinc (dissolved)
213
µg/L
5
11
< 5
4
36"t
Prepared byAMH Checked by: CSM
Notes:
Bold and grey concentrations are equal to or greater than the 15A NCAC 02B Standard (for pH, greater than or less than the 02B Standard range). Concentrations greater than other comparison criteria
are only bold.
Samples collected by Pace Analytical personnel on April 18, 2023.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
CCPSW-1 surface water sample location is upgradient of the CCP landfill.
ISTV - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For constituents with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
1- 15A NCAC 02B Standards for Class WS-IV surface water. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and wetland standards
(effective September 1, 2022).
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or Fish
Consumption value, when applicable.
- ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not
automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for
screening purposes only.
- Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
`- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
<- Concentration not detected at or above the adjusted reporting limit.
°C - degrees Celsius
CCP - Coal combustion products
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - Millivolts
NE - Not established
NA - Not applicable
NCAC - North Carolina Administrative Code
S.U. - Standard Units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
Page 2 of 2

TABLE 10
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED SURFACE WATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
Sample ID
April 2023
Concentration
Units
15A NCAC 02B
Standard
(Class WS-IV)1
Historical
Concentration
Range
Cause and Significance
CCPSW-1*
5.8
5.8 - 7.4
pH is consistent with the range of historical readings at CCPSW-1
pH
S.U.
6.0 - 9.0
CCPSW-3
4.8
5.5 - 6.2
pH is less than the range of historical readings at CCPSW-3
Mercury is consistent with the range of historical concentrations
CCPSW-1
0.02 J
0.009 - <0.05
at CCPSW-1.
Result is an estimated concentration.
Mercury is consistent with the range of historical concentrations
Mercury
CCPSW-2
0.02 J
µg/L
0.012
0.009 - <0.05
at CCPSW-2.
Result is an estimated concentration.
Mercury is consistent with the range of historical concentrations
L-
CCPSW-3
0.03 J
< 0.05
at CCPSW-3.
Result is an estimated concentration.
Prepared by: AMH Checked by: CSM TWL
Notes:
1- 15A NCAC 02B Standards for Class WS-IV surface waters. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and wetland
standards (effective September 1, 2022).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 07/23/2023.
CCPSW-1 surface water sample location is upgradient of the CCP landfill.
µg/L - micrograms per liter
CCP - Coal combustion products
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
NCAC - North Carolina Administrative Code
S.U. - Standard Units
Page 1 of 1

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex— Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
41P
synTerra
Science & Engineering Consultants

[�aCuns�nt't�lnn�e::l�i�l dato 5hect .
Age .1.0 :
COrir?!y(1C&1."
1?aeunus�k htunitiex; F-C.t�R FT l7-t)Oi-ray:(), .:
Ialitg:ltititttcu;iEyrPse.li%ii�kcsvii'IeQuaiity
f7 1.:CfP
:...:.:... .
cF
_Field i]aEa. SheeE ..:..: .......: ..: . o ,
:Tyrc�ii�ct
C
0Lnte
Time
Temp:
T7iss-oxy
Spec.
Cond.
pH: S.U.).
�
ei?Qx
(nV),
u
T rijdlty
(ntu)
r ov ed
(pl.I�sns
i�V�tex
F' :level. (£t).
Other
purged:
L' .
6a,
Cl

�S1CIt711C11�° Atll
Fie[sd ��€ta shut
�Ariflti(�11F SSUo 0.1 - 1
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of _
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i L`t1T2 FLl rt %f1 xev.o} .
:: pace+ I�uriEdr�viii� Quality C}ffice
:.>:.':
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RevieweiiDatesnd By: j�18 1�-�
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1Ep
tab11li 1 Test /'� Y� 23 aT41 ;.
i1:
Time
Temp
D�s's.OxL
qec,
Card:
qH (s ut
ReiJox (mVj
TurbJdIty
Volume Remgved
(gallon jl.}
Water level
0th r
.
...
wurged::
(�):
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,E -
.
(►tu}:
cPrcle .one "
(}
6
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arts'
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Ut mcnf N;;ino l7�eId data Sheet
.. . bate Issued mart
C@Allly!(CQI�
:
ni�un�er}k ur�iitttr .���� �I :.i,(ialYr�vQ�
lsaxi�lg_Autiia�xty %'arei3ttntersv£lleQiilE''.
Y
......... .
Ltica'tiori: �
..........:.
Natxxe.axtd A.Efilxahaty, �ampler:sj, N1
{
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' `Iris: t?ekaa`
Nne.and Ai f zak 0t1(.. p .
Date::.
Weil Iri£t�r�i Lion,
Vvii IL7: C ' ID,
N©/ FlushnQut.):
t
Well 2
i truetk�r[ti>; :, St6el :St lriless teat . .
T�kol Well Depth:
lk(1tadius/ 2}x.x:11 z0.
Z "- ft .
Static i+Veter bevel: °,,-
using Volume:: I iS gallons :.
1 I�'3gtit 0!.t,:�c'1• ��, �Q1UTfiII; �. � °.�,,:��.
�aI 3 UOluznes:: • '1 ':' gaUris :: ' : .
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:
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i�
atx� lin ;;E .ul. merit lJsed:�1 1 D, d d.
Vu. Ir<strw�rtettl::ID ] �.r� i0G 7 �
�:illa�
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r C
• { . 'Chxer
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p pe7rartce: ....:......... .
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P14. (s.n.
(
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Tigl dlty
ed
reil'{av::
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purged
(�'G)
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level {sty
]
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,
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. eAriyiFz1
i'ieYci Data sheet
Page ``'jai L
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5tbiliaatian 6t .
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Diss,Oxy;
;:(m lh}
Spec
Cotfd, ..:.
'(;s.u.:1
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Turbidity
Ufa : ...'
Volume Removed
(gall'o
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w6mrJeue11.
..-. .:
:.
l iZa
NAe
...
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Ttocainarii"I�ici�ae f laid daft Sher t Da#e ISued Match:B;
w G�r4fk7ly!%C$l
'
�:
t7cxunYent Ncam4er PAIL Fl arr.0�i
lasulaag Aiatlar�iy pace i IunEersvaUeQ�ialaty
t7fice
i~reld Dana SixerE. AIWAN: MERGE:!
•-:-.+.
,.; .::"." .._..LIQ%a.U�n
-.blame amiAf#iitaticari Samplers :. kAr
B�tQ :
Meld I ia.Sheetiteviewv:
Tame a'nd AffiHat�Qn {Inspector}
bell InFortnation
1NelI iD: M
aLo�k�d;
�Wetl
L(/2
;.
_ ......,
Y,
, / Ni},./ piusHrtaunt
1teli.Dierarefer, tl
Costruetccrn. (/teelJStainlessSteel)
Total tryell Depth :. {;
iYIultc Factor*, : vtf3Vtacl�xz)z.ic
Static Vi�aEer Level: �`� �g ft .
Casinolurne: gallons
Fleigltt of IA(ater Coluretxi ►bff';
dal 3 VQlurmes _ gilor�s
PVol ump Intlze , �Q ,.:..
i"ur�;e Iitftfrr�latioat
rtiate I d= . - — Pitlrskt' .-Urge R kaI4 x l)
'ua grogVietiroci'LLLLLLTotal
SltaIume Purrcl fo19 and
8arngIing iufor a ()n . `.
l�atQ CoJlected:�//
Tune Calleeterl: (�
am}slirtg Z;quipmettt Used'
instrument ID U-
Apr, Ya iClti Anais's [tegired
Field Measurerhe�ts/C}bset nations
dam le Tem °C :. �c .:::'
ime,
p TJL
T trirbtli nfiu
Re2am g
Specrfic Cord. {uS)Time _
:. Res CI {mgJL)/{u I, Trite:
Sample RH {s,u.}; try TimeTime
{ : ) Time
Appearance :. z s� Tim
IteDc�c { H value] YSI PioPI sA20t}rt7Qkhe Tines:
Generai/YYerit�,�:� Oba�rwatitrns.
'
Satoo or Signature ,.:
Date
5tabili�ataon.TeSt:
.
Tune
Temp. ;
C
its>.f
(uS) '.
Rel?ox
(zxtV�
Turbidity
{ntu
.
rm4vedPRO
{gallns; n%
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level {t)

date Shc' t
lia#�e�[ty,4tx�t4:;9C��tCri�
t�cun,ent Numbei � CtIR rt ta-�o��r�v.©� ,
issuhzg ArioriSy Pace FiunS'$rsVil�e-�#it�ity,. .
Fie1d.I3a#a S'heeE
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c L ocatioxt _ ; �"'v ��CiZ. rr�lect #: C 5 Cc�
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Name An Aff111AHonl am •��r s iz•A -. .�
c. p t)
X?ield Data Sheet IteviOW:
Name"a"nd Affilat�czi Ixts "ectr
p
iiVeil inf xtxtAWit ,
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* d (°(Radius/i j2 x 314 x 7 AB) .
l�+Iulh Farato ,
statzc water Levi; '-1 t7 '� :.:ft
usingjlurne.'.:,::.:
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,.. . , .. .:.
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8 �
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: Ttl .Volume Purled
Date Cctlected
SainpinU
su, C.
1B:oX#Xe e . pr�sarvariii?ri ....... ". l�,naixs Requited.
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Samplo Oro rttp.. { ..C){r�ti)�
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Dins ox�'
�/ . 3 : irrue°
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+�e�neral%Weather Qbserv#E"ione�`
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.%:cloud. :rain ` Tem '� U. (OF, ' inrl.. (m
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Stabili2ation Test
itxie .
Tem p
T l s'Qx:
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l?It�sk�xx�ount.�.
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Cansiructson: (1: /Meet/SEat t%ss. el)
TQltal 4i! Depf I. .� tt '
i lt�, aetor* / !� E1�a t,iu�j?) x 3I x 7, 8]
Static [ Ao Level �.� , fE.
casii�g alumer 7tI, `{ gallat
t`Iet �f 1Nater;Cglun �. -'1 `I lit :
.:
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..
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Caging 11�fethod �f Sir hG
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16,66,
8ampiing_In>~cirmatiQrt
.
late Qllected % �� j 23
T1ri1.e Cagected i3D (/Pm)
n
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p� ent Name r
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::.
1;6
i314iSQ
ProleCtt
LG-Pe ON; "
}i f." HIPJY
Kolb 'OW e. pate: ,and
tb3l�tatfoiiTes
yl?.$ 2`Z A'it,J "` ."..
° }
I
tl }suj
...
"ec: "'
:,'....:.:
Cpntl.
.: " .
;
t
1falu.e:Reove'd:
;...
l�t/ater f�vei:
Qther ..
-.
'.'..
. ..:..::'".'mV,'
ju5
{ft}
16s7,.3:.:...

ac��1t?F�IiQat"
"
unicnt l�Ibnxn I xctd date Sheet
i7ateIssu�d : �s�h,8r2U19.
Pa c of :1
Issuing Autl opy N eHu ltersvxlte Qts llty
r�lTi
kart _i�s� :i'gQ Rate
-
.g
Valume 'ur ed:
sarri tin g IniFo�ation:
I i p f � 5 S �-f
W'
et 1?4te C o Lle eci: 7 :....
Tune Collee pt
5ain}�ltrtg;EqujpmentUsed ..:i
.::::::.:::: trumentlU �% 21. 4
�d
a%ysis:;l f-quio
... :�p y�j..y�rtl�y spy yjI ♦ry., yq��f /�f�
. Reld'1T ggd M"t L Lilt om �6tjijmjn
\1�
.
Sa'ntple Temp (°C)::
3i
r:dity � Time;:.
lise
.�rite
.
2+:m
S '.ect£ic Card. u i:' .:
-C nz � u /
f gl �(" .. .
:
Sazt .le :1: s.:u.': �,- )aie:;
Qdr�xt trig:''
P. eararpm, c
NOW (pI rtatYSI. Po.Plus+2:tv .. 001
GObs.OrV.afibiaoc''
:
,V
( vlcioudvlraulul Temp milli C°Fl Wirid/3:, (M.
ar pler Si natuz e;I C1
3tab%li ation'Tea:
Time letup. Uss;Qsey I eDox
pec,
and.Ti
(us)

:.
DQeunteitk,IVame ° .:
Field bita SMe"i
................. .
gcc(o t3, 2€IT9 umenf ��e � iviar
Rage eaf
Dikomen N, Mr.
Issue n� Aufl�rsnty
Huritecsv Ue Qualityi6ee
.. :..
. , :
r �lfsiti , lieat�on.
Fsctot`►:",, ;:...:.; :.'"
€E�it:.....:.
1
U:
Ldcatron'
2
�1 C
CZ
a.16
:...................
.
5,30
k... ed,
5tAIR xklon TesiF :
4 �z �:%,3
..:6100
Tltne
Temp
a ss axy:
Spec
Land;
OH {s u );..
'`
Re 11 �t )
rur�I i y
vo urge Removed
(gallons/ I.)
'
water JLave C
?then :
Purged
(.)g/�intu)
(us)
c afe.one
v
on
�� �i

.:.,,
i�0 u*9 t, m me F: dtitaSheci
Late issued ; x $i 2(I�
t3CiCUR3CI1t NS17Yl�1t�C Ali � D
!0
Silt or Sz store, _
p
StabilbAtibn: Test
Trine
Pu.ge
Tent .
P
(°C
Diss Ox
fmg./L,�:
e�
p..
Cond.
pT.(s.u.}
i eDQ�€
Tor dit
Q ov
renxo rgo
wa.t x
Other
�znV:
(ntu�:.
igaiiz�ns> . s
level (£f'
t OIL
116A
-7,(
ly ... .
1°�.
1
S•
2s3.S
�.o
10.3
1.5
zS.00.
S.3

Two tOheet
C)oCUIttClttLtiit](ST:.
�3§t1C'iYt AlltlitYilt,. .
F C t'+I E1(iI CG'V:U
PAC@ t"FUEitT5Y1LIC�.QUd O1C'
t�'�ti L�saefiar �%fisits
If�iiiC%n Fsctox*
:
ioc�tiont
M��c4�ibotd,lJ.0
_
Pt4ij4Cty
G1.5r G:C'P L
W. Oil
kovrewed.:Q..' n"�3.By: �l�.�$ >� ALk
b
I. f:BCf....:
:����i�,liatian:Test-° -
Pt�t ed °
61ss;6xy
,:.
Cairtr ;:"" :
..pH (s u:j-
Repok :;
7iildit`"..:
"
" :::
(gstlonsJ )
WCr`tevet'.
"..:..".::
oth:
:..
::.. .
'Arsle.oe
..::......:..:..:..:.:..: .
-
"
11 e' .
iao.ta�
ITZ
..... .....:....:....::...::..
....:
8.:....: 7
`Z. 5:.. ...
5:�
'sops/':
20�
I'Ot
16b.0
208.5
q ::..
3oa.
z
t z
Z o. o
7, 8I.t
;..::...:.a.....
Oho
F~." `
(p
rig..
O S
t L
y.

Dncumen# Idnnir
ante l
p
.. of
l4it'ip11t7%yiHik��'
Isguu�� AutttaY�ty.lraseH4ct�t�r$YlpeQual�ty
(KURI@Ilk Number. F CAR'1 T I7 CIQ1^Y�Y.©i. .
,..
tiffi�e . ' .... ..
Stab%1azaEiori
Te t' p V k:.J
Time .
Pur eri.
Teiir "=
t°)
Ti ss 0v
y
On/%:)
Coed.
(uS):
H s ai
P t �
AeDo.x
(nV}
Turbjdlty'
(ntu) .
civae
. reiiiove.d
gallons/
U
water .
i:evd: (£i):
the r .
l i
5 ,
5,
La ,A
*5�',
---- .
6a,
L, I'LL
1 1-3
3010`a
�a .
1 � , b
'sue ,
y. 6
t �� ► �
'�, �
c� '
�
�----

P oeiut;IVant�st#itxikisu4t;'.I1�tai;2t}T9:
k
G8 j!lICc"�i
Pield DtitL 9heeE
Pa�;ea bf
[1 c untent Nun2ti r:
FCA .
Is&nein�; Autbibrity .
Pay 'Fibzit rsvaCle:Quality ( ff t. :
im
• -
PC . �
(�
������r
®■■tea

:.
CeAnlyP%t1a.
;[aoc�tnta<ni ntQ: Field
te:lssti'eeli.Marrki
1.
C7tycunienk l�lu�bcr... �.,�R.T'
c e:Huttersvi �t�uality
Offie'e
Field Measurements/Ubseryation
Tiane::_..1� ..-..1:��.W.� � Titrbidit , ptti:.;—O . P ......._...__.Tiri��:
i t
Liss Uxy..(mg jL}: - •' " Tua e: Fe ::iaitg��: t� tom. Tizrie: ' 1 � �i
f'
�12C1f1C.. Gild. (US): ��.T �/:�+J1���1'
ime� P Res. �I. � � .
(40
Sample.p.Ff s.u. 5 : T ittte: Odori
ReDox(izV}c,:.'ppe........ �';,���xr,
Time: 1.3 �/ o... ra�ice; t..3 l.ca .......... .
RiT3ax :(EH v:alue).YSl. prot?tus:-.F2i 0inV 23r.. 6( _ Other..: 'Tithe:.
GGeneraVWeather Observations:. .
(u �..:/.eloudy/'r 'iiny} Terrip: i ('%) [Nincl -(mph)
.s7sava:a.rcinaavaa.
a rasa
o ume
Time
i?ured..
Temp.
a, C).
Disc .y.
Ox
(rr►g�`f,).
Spe.
Cozad.
pH (s.u.}.
Re ''Dox
(zrtV}:
Turb idity
itu
{ )
xemoved
alTons .
(i7 %%
Water::
l.ev el {ft}
C7thei
i
... ).
L
....... ...
.:..
Vo `7 ..
.. 3�J a 4�
E o
zc-)
011
Z.(tC>Q
.t�

°: `'
�trCyn}cn#"IVtt�tc•Fiel<idat�+5h�tt
dt�
-
GG�irr�7lyxfF��'x
t7iium�trR Nun,her F CAR -fit
lsBuingAutfortty f't:iu��tervYlleQuaiity`
0ffite ,.. :. ...
r
.,�
�lie�tt'
`5 CC?
....,�. .
Nanxe.and A£f11xation (Sam p {} ; D IS1
rnnrl-. .cat
Meld Data Sheet Rew ewv:
.ter
Xaxne.and Aff..ilia#i0n. (I)a ve.croa. jA
!I. A :
B.
e
Vtlell I)iazanetere
C
tal Vlrcli`l3e}t€ij.
iultr' etnr*:. I*:tit thus t2}?;x..1, 4 77:. e!
Static VVa'ter i evel: " fE' . '
asing Vs�lume:
gl}t.of Water Coltiftu: ; �:...:':ft :
Ctl 3 V:olumes:'
Pitrte fxzoirnxal ion;, : ' . .
Date Puxged, �--
Itut e'RaEet
pugi letfxvd .
Ttstalolutte Pttz ecl:.....:
.... .:..:: .: ons�
5a�n lilt Inforimaticrn
Iale,CacteciaL`-i— 1T-3
,
dime Callected:Q a i
:
Sampling:.l~qui'pmettt'Used...." "b
Er�srtietEi':`JSTri,n c Ot�..M4sc
BotEie Type .
�'hCeser�aEian
Ai�a►;tya%s:R'equired
:
--
:Field Mdaa j urementsjpb—servatiazts
Sarrtpt ent °C : l S � _d ime. j0!4Q,.,.,_. _Turbz ity (nL )';; S �' _. ixxte:: I �Q C?
p ( ):
C1.�1 '': f. Fe 2 Yn'. L.
it/ 17 Tmet:,I
Diss'ax 1tt . L . Time. _. , g
5pecifi ortc� . uS): I'iri e � 0 b (pig/46L. G):. iiae:
Sample. Off (s;:u.).. .. ..,..z
lteDi�x' (zriU)'s .... `i (� I'iitte•'a_ Appearaiie;
[t'e3ox ()Jii vale):YSt:.I?rnPlus.2Q0.tu G ®.Hier: Mine: —�-
Gpneral/Weather Qbs+ervaifqns, (p F5 CQn:rr 5 t 1. b 5-4' ^i (° �A 6 .i 6 V vJ
u yJeloudy%rainy} Temp:. Wind3 --(mph)
5�riipler: Sig�t�tupe; 171te�" �l �� l�'3
volume
Time Teix� IN C)�c ( feel}ax Tug:l7 dity
SI?ee.. retnoveti Water .
' y' Cond. fi S-u- tither
,?urged' (9C) (rxt&%'I.) {uS)' p . ) ( (fatty. (11.1 i s/irtl5/' :tevel.(ffy :
,p

AC�AAm I rGAt
Do
eh 8s ?(119
Date T�s � � M of 1
- -
CkttumentNumber F CAiZ-l:1 D-0Ol;rev.4�
Issutg Atttlfotzty Pare Hunfersv�lle Qualcty
Office
Temp: (°F) .:Wind�3

�1C[?Afh'i44tCQ1�
iat�um�n# I�j9me l ict�i. data 5het
br to"iseue�li Mar
l7gcunl"enPF-CAR-Cl17-0Q1-rev l0.6
ssuln� eA�#horityI'ace fit tersvclie Qualety

'
€ :.:
I!C tllli4'iit,t�f.11�' 1jwo C1a{.'L i ,.%'T't
p� oasolk. 'Nia c€t �r T-
..
t' e 1Of
17aranien. t Nurritie� CAR=FI %i pQ3-cev.g31.Isuln
Autlianty Par:Htxntecsvtlle Qyr�l�Ey
Offke
-....
' Fie1d i?at� Shut
Client-: C I.ocatiort /::: (CSbp�
'-
.
kL Pro eat # ,�
�.. ) Svr 11
Naxxte oriel Affiliation (Stnpier{s)M
�) GM;� �'RG ;
geld Data SheetlZevie�v:
Name axid Affzltattr l (Inspectcar} :: /�%
�=1 �I� ��3 . .
bate :.
Vetl Tnformatton .
4 /Z.Iz
GVll iD. c,�-5- FD-'I
..,..
.. . .....
, . rr
Well,l�lxleter: ,
.......
.C=c�cccckrrttt� i>L Y
--y---:� r
°r .
�r .: `
...
Total GYe11 Depth ._ . °.::.. ,:.:-:., t .'`.
IIuTh 1~aetor '•
(�(Raciva/1 )2x: dx74$I
. ::..:.:,'
8't tic Vda' Irevei °. ".
Casirrg dlumes
.
g�+llozls
�..
l"Iexglitof.Water:Coll�rnr� l;.::
,: 1Wl oIutnes.
�` Bat ons
r. .::.: '
.1 tt tk `—
i
ft
'M
e E C ... $tart - l~iti*sh
i
..
' . Piirgntg Method;
Total iolurne i?,�xgea: callarts�ly
:..... Sarnpltrig tnoriitattan :;
'
:..
..:.. � ,
:... 1
'.:.:: ' >�4 Collected C
, Tiarte Cczllectecl:
030
�./ptn)
., :.:. ..: .., . .. ... •,
Satnplixtg E uiprY►enr U e :.:.:':: ' o ' .: Pn�
C: .:: ". : ' ::
.
5 'G tr �i�t a:
Qttr� �.....
ft#servaitart . ` :'`
:: Analysis itec uxre
. ..... .:..
•:..
G
. . _..
-...
. . . . : . b I i L , L : , L t : I L , , , , : . . . . . . . . . . . . . . , ' L ' I L ' I L ' L — L L ' LL LL " '
.
. . . I .
I . I I , . , , I ' L ' L . . . . I I :
' L ' L L L ' ' ' ' L : : : � : : , - . . : : : . � L � .' ,
. I . - I . I . . � . I I , . I .. ! : .
I . I I . I . . I I . I . I .. . I . I . 11 . .. .. I .. I I . I . . , . . _ --77�� ' : - . :- , - : . : . . .
, .: .: , . .
.
" d easvtre , ent O,bi "tine :. ' :. ...
.aTll�oT.. .:
'X`Iri12--
..
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*!'
;i s tax} i Sj ):; °
Tune. _
.
, 2+ tig L: J'i ne
.
p1, ecifia Coxlc�. 'tiS.:.... :..
p..... ) ...
:. . ,..
Time...es
t
Cl ng/)���tgJ.) Cirite
Sazxl ' le Hsu. ;
dame
:T' .
Uci _
crr:,�.� Tribe .
Remox (zVy:
Tfute<.
Appeatatle e
..
.. Re 3OX vatue).X i.I'zaPitts ar2al my:
_.
... .:,
. oti�ex . .:`. ' ,: Ts�tie:
. .
General/etther.C`fl�s,eruat Foils:
:
, . .: .. ... .
r� C ' . tv' .:
.. ...'. '...:., ... .
.
s %cio zdy/rain} Te.. g ; , (° } INincl (mph ..:.. .
`. .:.. . .
arrf let sr ahlre,.
$'... ...
. ::
:.:.::
.. , :. .
Date.: /l : Z 3:
.. ..
5rfabilizaEion
..
`Test ':
.
Tune
..:
Tem
...
x :
�!fC.
�y
l:oit
..
P.1 1 c}
ReDox
Tcubi�itty
Q ume ,
renlorred
.
C�Ilwter
.
..
Cithai
.
'
ri�� �a
P
(. c.`'
fins/ -I:
{u.
(ivy
{nt11)
gallons/ � /
ievei { :.:.:.
:
. .:
.
.:
, .
. t

T�iCunt�nf Nttntc i?ield data 5iter t
a
-':: ate Cssu"ei�: Maiit 8, 2f119
" ArtolytiCttt `.
'
X'�ge: 1 of• ;'
:l3ocuitient %uunifier: F=Chit fC I� AOl rev 03+
SSU61 i1Lit�tOY1
.irfl�@.
.
Fie-aai. Sheet
OI`xent; . Dam E�9 v : coca xr:'�es'b:Oro L':.. LtCA,.
E N s LL LF :.:
rroreiet #c �.2
Naxrte aizd A:Efiliatist . am. •.Itzr s:: R PAL Q..:.' .......
ew:
"
ameanciffdxafi%ri l ::er~to':::.:'....-1��;:.
'V1r`eIl Infvrtnation. ...
i:ti7
We11:L?ia[nri ier.:.. .:: �'-::..,'
cirst uction:
TYVeli'De
Slitt ,'Woter':Level: ft
asl�ng:;Valuzrie . --- " gel:l
`ETexcaiu�lt: '���. ft :
�c�1.3.Uolum�s
I, 0F.fie:. . Start ke:
:
7"c�tal'Voltirite I'tiFeel:....:-... ' �IO11S118,:
9BYY! xn
ID
TnneCaleeE�
Mn ixn' :.---�
uI' .meat' tJse * i! d.
Ins
BotEl.e.Type
sRr.v E'lon: n°a:lys. s':Ttegx irec
Durce:G�.� I�sncepq k; fi
Faelci Measurements/Observatibna'
Sairi 1i Texn
Tii'1bis3.fy �ittz � 'Time
Fe 2+ zxijL Tiui:, "
Speeific:.Cdnd,' (US) ._. Tune:.:
'.Iles::
TIme:..
Odor;
ili.De c. (EHEither:
°Time:
Gerirara, ..,eaih Observatxoos:. 1::.0
dL 4- eUVIAw -5, �0cOL4: a �1
Bunn_ cloud 'jriii } fiem 74 (°F' tilii rJ -5
SAmplet ig�ii Luxe _..Ryas R 4 . �-5 �; _Bate:
Stabilization Test
V O.Ct��tte
Tiia e' Temp.. D sp-Uxy: 5}�er': ReDcix. Tait e%itjr'.:. rr nacitre.el C!Vater, .
o'. C4rd:: pH (s...} L7ther.
i?urgerl' (0 (mg/ (iziV} {r ku . (gallons rimis% .level (ft)
(uS}
I .

.:
Hunt Name frael�t data shett
i]Ate issued M'ar�ti 8, 2px9
r74'B/b7rilyflCs7f`.p
rev
flc un�enk thin b r F Cr1it- ! Ci-0Q-3
lss►t�ng At�thoxtty�c:i Ituttersvlil Quality
,
Office:: .. :...:
vtY► .
Temp.
Ras .0
Cortd.
pH(s.u.
Reno :.
x1a ry.:.
O U'ino
rem ued
:water
O ..
.,
el• ft:
:her
7
0;
oi
"7 v .
7Z 0
5.
16 .
13`1 . '
7��' :
r1.32
—...fie.
�© .. 1...0

:.........: .
I
Tlticcuxitent;'Name<
Field Data Sheet
boc unzentIsstied: l4iarc h 8 2019'": "
P.ae2nf<'
Docantet tN tmbor
Issuepn Autki rtitX
F-C'AIi FC D-�[l1 xev U3:..
PAde Huntersville (uaizty C)fiice:
�' fX ,`YfcAktl
t
..:......
.
WWI
Ap�re12
�tt�l�
.0.1630
VkFeI,I" III:. ".0.3
".
R View Date ''an"d, 8V
St�blli:atic�n..'1'est'' '
4 fa 11%2 -Aril:..
.
1'lrCte ;.
F"u�'r ed
tetra .:
Diss£�xy:.
iSpe., .::...U.
C¢rtr�
pi I (S.u}Pox,{rYil%}
A.
Turbidity-
.er
Stu
RertiovecE'
sill:0[15 I» '
i1�ater, eve
: "fig
--...
;c 'rcIe.one
y/
G�
r
1.7
Lt�:
-
1 32
....:.....'
T
.
�.
M■

:..::. .
K
I?ncun�a,nt Ahini� Fycicf
mate Issu�d:Mao8; 2{it9 '
PaMol,
:Dix N4n3brr. F CAR-1 I,iMQi-rey 43
t$s►tliig Atltonty face Hux118GgvYlle'Quattty:
..: :...
OfEi�e
$Afl I tLlri.:.v Doti:
rn
Stalalixatibn Test`
Time
Purged
Temp.
(C)'
Ii59 Q CjT:
}.
Spcc.
Cond.
, .
pH ($.u.)
i�eDox
(xttV�:
Tirbirit
(a�tu.)..
o ume...
rert�ve.dV
(��1.1:onVHS
ate r
Ievei (ff)..
:Othet.
.(�n�%'I
M
�.
f �
7r
3
"70
G3,73
G
I
i 5
.a-
210
3.�
35.
�(30
53f b
7.4�
a,
i �0
:3�1;
a 0
53. :

1� pC�I711�4
Yield Date Shred
$Stl
Iaucu ttcant Idiii�li�er
1 su4 t AuiliarI jr.
C.AI+ i41:t3AM td 03:
Pace Huiifersvzlte Qualiry'f}ffiCe_: '
'
Vk��ll:.:l`3iar.640
Lava#Inh. Moom5bmr)
�`
09
JGIM
�i� L-i' �2�IM�i ��rrI�l�
P€aject' i��
•
#ss3{i
V.
.03.67
wl:Il lid.; .:..,:..:
-
RevruRate an ieed d
By
stab tli:at[onTest
H�zxr .: ate:
' .
Tinge
Temp..
PIss.Oxy.
spec:
Oand.;
H (s,u}
Refiiox {nVj`,
Turb djty
''°::::'
Vplurr�e Remived
gallgn rn s L}
ate€lave{
Other.
..
(ft}
Il.`d
,."..
55
1,
35OQ
sac
-
-0aa
�---
zapro6f
;
nogg

ace,ara�y�rr
�a ate f
Date:IseueLis:Marcii k,2
t9trcunient IJuntlier P CAYt-1 t D �10 revIssuing
�14 ioraiy,I�ace fltutteisvill. Quai�ty
me.
.R6DO.x (EH value).:YSI iPr plus +20 ©t`h '
irr'1�1 6�c�cJQ�'
tt' mN

w
DAte,sued
Aocun�e Number PICO
,
ftO . I
-Ace
samv'.le .
f Si$n ofute
Stabilization'Test
m
Wixid��(mph)'
Tiffs
Purged
Tem p
C)
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Time
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0 C)
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. Y,
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(US)
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(ntti)
Volume
removed
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L)
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level (ft)
Other

Semiannual Water Quality Monitoring Report — April 2023 Sampling Event
Rogers Energy Complex— Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
41P
synTerra
Science & Engineering Consultants

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J23030262
Project Name:
CLIFFSIDE - GW CCP LANDFILL
Task Code:
LF
Customer Name(s):
Bill Wylie,Bryan Moeller,Dee O Brien,Josh Stowe
Customer Address:
Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
Date: pate: 5/12/2023
(Signature)
Peggy endall
Program Comments:
Page 1 of 59
QC Note: CCPMW-7 calcium MS/MSD recoveries exceeded the QC limits. The blank and LCS were within the control limits.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 59
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023006170
CLIFFSIDE
18-Apr-23
11:35 AM
JJZ DMM
CLS_CCPMW-1S
2023006171
CLIFFSIDE
18-Apr-23
11:40 AM
JJZ DMM
CLS_CCPMW-1 D
2023006172
CLIFFSIDE
18-Apr-23
10:40 AM
NRA ALM
CLS_CCPMW-2S
2023006173
CLIFFSIDE
18-Apr-23
12:05 PM
NRA ALM
CLS_CCPMW-2D
2023006175
CLIFFSIDE
18-Apr-23
10:30 AM
JCM EHM
CLS_CCPMW-3D
2023006176
CLIFFSIDE
18-Apr-23
11:05 AM
SPW
CLS_CCPMW-4
2023006177
CLIFFSIDE
18-Apr-23
12:30 PM
RMB
CLS_CCPMW-5
2023006178
CLIFFSIDE
18-Apr-23
2:00 PM
JJZ DMM
CLS_CCPMW-6S
2023006179
CLIFFSIDE
18-Apr-23
1:40 PM
JJZ DMM
CLS_CCPMW-6D
2023006180
CLIFFSIDE
19-Apr-23
10:30 AM
NRA
CLS_CCPMW-7
2023006182
CLIFFSIDE
19-Apr-23
9:55 AM
JCM EHM
CLS_CCPMW-10
2023006183
CLIFFSIDE
19-Apr-23
1:30 PM
JJZ DMM
CLS_CCPMW-11
2023006185
CLIFFSIDE
19-Apr-23
9:40 AM
JJZ DMM
CLS_CCP-Leachate
2023006186
CLIFFSIDE
19-Apr-23
9:50 AM
JJZ DMM
CLS_CCP-LEACHATE-34
2023006187
CLIFFSIDE
18-Apr-23
10:00 AM
JJZ DMM
CLS_CCPSW-1
2023006188
CLIFFSIDE
18-Apr-23
9:40 AM
RMB SPW
CLS_CCPSW-2
2023006189
CLIFFSIDE
18-Apr-23
10:25 AM
JJZ DMM
CLS_CCPSW-3
2023006190
CLIFFSIDE
18-Apr-23
10:30 AM
JCM EHM
CLS_FD-20230418-1
2023006191
CLIFFSIDE
18-Apr-23
1:00 PM
RMB
CLS_FB-20230418-1300
2023006192
CLIFFSIDE
18-Apr-23
1:25 PM
JCM EHM
CLS_CCR-CCPBG-1D
2023006193
CLIFFSIDE
18-Apr-23
12:30 PM
JCM EHM
CLS_CCR-CCPBG-1BR
2023006194
CLIFFSIDE
19-Apr-23
JJZ DMM
CLS_FD-20230419-1
2023009450
CLIFFSIDE
19-Apr-23
9:40 AM
RMB TJD
CLS_FB-20230419-0940
23 Total Samples

Page 3 of 59
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
J❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/12/2023

Certificate of Laboratory Analysis Page 4 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-lS Sample #: 2023006170
Collection Date: 04/18/2023 11:35 AM Loc code: CLS CCPMW-1 S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 4.0 mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.17 mg/L
Nitrate as N 0.04 mg-N/L
Sulfate 0.96 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.05 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.018
mg/L
Boron (B)
0.005 J
mg/L
Calcium (Ca)
0.129
mg/L
Iron (Fe)
0.069
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.515
mg/L
Manganese (Mn)
0.016
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.48
ug/L
Cobalt (Co)
1.33
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.06 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.644 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 J
ug/L
Vanadium (V) Low Level
0.13 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 25 U mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 07:14
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 07:14
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 07:14
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 07:14
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 07:14
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:22
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 13:52
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 13:52
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 13:52
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 13:52
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 13:52
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 13:52
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 13:52
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 13:52
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:01
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:01
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:01
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:01
MHALL3
25
25
1
SM2540C
04/19/202310:09
SNEGLIA

Certificate of Laboratory Analysis Page 5 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-1 D Sample #: 2023006171
Collection Date: 04/18/2023 11:40 AM Loc code: CLS CCPMW-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 8.0 mg/L
Fluoride 0.0479 U mg/L
Nitrate 1.4 mg/L
Nitrate as N 0.32 mg-N/L
Sulfate 1.3 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.01 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.016
mg/L
Boron (B)
0.007 J
mg/L
Calcium (Ca)
2.68
mg/L
Iron (Fe)
0.018
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.41
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.238 J
ug/L
Cobalt (Co)
0.32 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.87 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 34.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 08:48
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 08:48
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 08:48
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 08:48
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 08:48
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:28
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:07
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:07
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:07
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:07
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:07
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:07
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:07
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:07
CELL106
1
0.104
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.111
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.249
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.032
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.185
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.077
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.787
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.037
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.18
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.256
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.193
1
SW 6020B
04/24/2023 19:19
MHALL3
1
0.035
1
SW 6020B
04/24/2023 19:19
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 19:19
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 19:19
MHALL3
25
25
1
SM2540C
04/19/202310:09
SNEGLIA

Certificate of Laboratory Analysis Page 6 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-2S Sample #: 2023006172
Collection Date: 04/18/2023 10:40 AM Loc code: CLS CCPMW-2S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 2.9 mg/L
Fluoride 0.0479 U mg/L
Nitrate 7.9 mg/L
Nitrate as N 1.8 mg-N/L
Sulfate 5.3 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.030
mg/L
Boron (B)
0.01 J
mg/L
Calcium (Ca)
2.75
mg/L
Iron (Fe)
0.028
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.89
mg/L
Manganese (Mn)
0.031
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.113 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.08 J
ug/L
Chromium (Cr)
1.38
ug/L
Cobalt (Co)
0.392 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.098 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.482 J
ug/L
Selenium (Se)
0.593 J
ug/L
Silver (Ag)
0.05 J
ug/L
Thallium (TI) Low Level
0.099 J
ug/L
Vanadium (V) Low Level
0.245 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 35.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 09:19
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 09:19
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 09:19
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 09:19
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 09:19
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:31
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:12
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:12
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:12
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:12
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:12
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:12
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:12
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:12
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:10
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:10
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:10
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:10
MHALL3
25
25
1
SM2540C
04/19/202310:10
SNEGLIA

Certificate of Laboratory Analysis Page 7 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-2D Sample #: 2023006173
Collection Date: 04/18/2023 12:05 PM Loc code: CLS CCPMW-2D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 5.4 mg/L
Fluoride 0.0479 U mg/L
Nitrate 5.5 mg/L
Nitrate as N 1.3 mg-N/L
Sulfate 4.5 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.009
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
14.8
mg/L
Iron (Fe)
0.091
mg/L
Lithium (Li)
0.005 J
mg/L
Magnesium (Mg)
0.916
mg/L
Manganese (Mn)
0.002 J
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.581 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.79
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
1.67
ug/L
Lead (Pb)
0.08 J
ug/L
Molybdenum (Mo)
0.511 J
ug/L
Nickel (Ni)
0.512 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
4.40
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 87.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 10:06
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 10:06
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 10:06
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 10:06
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 10:06
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:33
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:17
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:17
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:17
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:17
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:17
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:17
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:17
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:17
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:18
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:18
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:18
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:18
MHALL3
25
25
1
SM2540C
04/19/202310:10
SNEGLIA

Certificate of Laboratory Analysis Page 8 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-3D Sample #: 2023006175
Collection Date: 04/18/2023 10:30 AM Loc code: CLS CCPMW-3D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 6.0 mg/L
Fluoride 0.0479 U mg/L
Nitrate 4.5 mg/L
Nitrate as N 1.0 mg-N/L
Sulfate 24 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.029
mg/L
Boron (B)
0.073
mg/L
Calcium (Ca)
12.0
mg/L
Iron (Fe)
0.004 U
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.48
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.10
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.423 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.169 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 63.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 11:24
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 11:24
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 11:24
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 11:24
BGN9034
0.5
0.0428
5
EPA 9056A
04/19/2023 11:24
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:35
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:23
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:23
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:23
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:23
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:23
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:23
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:23
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:23
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:26
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:26
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:26
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:26
MHALL3
25
25
1
SM2540C
04/19/202310:10
SNEGLIA

Certificate of Laboratory Analysis Page 9 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-4 Sample #: 2023006176
Collection Date: 04/18/2023 11:05 AM Loc code: CLS CCPMW-4 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 1.7 mg/L
Fluoride 0.14 mg/L
Nitrate 0.70 mg/L
Nitrate as N 0.16 mg-N/L
Sulfate 29 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.01 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.119
mg/L
Boron (B)
0.013 J
mg/L
Calcium (Ca)
11.5
mg/L
Iron (Fe)
0.023
mg/L
Lithium (Li)
0.037
mg/L
Magnesium (Mg)
0.752
mg/L
Manganese (Mn)
0.008
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.207 J
ug/L
Arsenic (As)
0.356 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.847 J
ug/L
Cobalt (Co)
0.089 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
7.89
ug/L
Nickel (Ni)
0.274 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.269 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 119 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 11:40
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 11:40
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 11:40
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 11:40
BGN9034
0.5
0.0428
5
EPA 9056A
04/19/2023 11:40
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:37
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:28
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:28
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:28
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:28
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:28
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:28
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:28
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:28
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:35
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:35
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:35
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:35
MHALL3
25
25
1
SM2540C
04/19/202310:10
SNEGLIA

Certificate of Laboratory Analysis Page 10 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-5 Sample #: 2023006177
Collection Date: 04/18/2023 12:30 PM Loc code: CLS CCPMW-5 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 4.8 mg/L
Fluoride 0.1 J mg/L
Nitrate 4.0 mg/L
Nitrate as N 0.90 mg-N/L
Sulfate 20 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.003 J
mg/L
Boron (B)
0.016 J
mg/L
Calcium (Ca)
31.3
mg/L
Iron (Fe)
0.168
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
0.194
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.642 J
ug/L
Arsenic (As)
2.84
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
5.14
ug/L
Cobalt (Co)
0.105 J
ug/L
Copper (Cu)
1.50
ug/L
Lead (Pb)
0.297 J
ug/L
Molybdenum (Mo)
1.25
ug/L
Nickel (Ni)
0.755 J
ug/L
Selenium (Se)
0.286 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
15.1
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 110 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 11:56
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 11:56
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 11:56
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 11:56
BGN9034
0.5
0.0428
5
EPA 9056A
04/19/2023 11:56
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:40
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:33
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:33
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:33
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:33
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:33
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:33
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:33
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:33
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:43
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:43
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:43
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:43
MHALL3
25
25
1
SM2540C
04/19/202310:10
SNEGLIA

Certificate of Laboratory Analysis Page 11 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-6S Sample #: 2023006178
Collection Date: 04/18/2023 02:00 PM Loc code: CLS CCPMW-6S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 4.8 mg/L
Fluoride 0.0479 U mg/L
Nitrate 15 mg/L
Nitrate as N 3.5 mg-N/L
Sulfate 1.7 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.01 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.042
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.60
mg/L
Iron (Fe)
0.229
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.05
mg/L
Manganese (Mn)
0.045
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.04 J
ug/L
Chromium (Cr)
2.00
ug/L
Cobalt (Co)
2.10
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.168 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
2.84
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.117 J
ug/L
Vanadium (V) Low Level
0.325
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 41.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 13:13
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 13:13
BGN9034
0.5
0.0209
5
EPA 9056A
04/19/2023 13:13
BGN9034
0.115
0.002
5
EPA 9056A
04/19/2023 13:13
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 13:13
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:42
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:38
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:38
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:38
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:38
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:38
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:38
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:38
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:38
CELL106
1
0.104
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.111
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.249
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.032
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.185
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.077
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.787
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.037
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.18
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.256
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.193
1
SW 6020B
04/24/2023 20:52
MHALL3
1
0.035
1
SW 6020B
04/24/2023 20:52
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 20:52
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 20:52
MHALL3
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 12 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-6D Sample #: 2023006179
Collection Date: 04/18/2023 01:40 PM Loc code: CLS CCPMW-6D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 5.6 mg/L
Fluoride 0.0479 U mg/L
Nitrate 11 mg/L
Nitrate as N 2.5 mg-N/L
Sulfate 0.30 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.01 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.042
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
1.48
mg/L
Iron (Fe)
0.008 J
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.83
mg/L
Manganese (Mn)
0.026
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.22
ug/L
Cobalt (Co)
1.13
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.622 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.07 J
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 40.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 10:22
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 10:22
BGN9034
0.5
0.0209
5
EPA 9056A
04/19/2023 10:22
BGN9034
0.115
0.002
5
EPA 9056A
04/19/2023 10:22
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 10:22
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:44
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 14:43
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 14:43
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 14:43
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 14:43
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 14:43
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 14:43
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 14:43
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 14:43
CELL106
1
0.104
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.111
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.249
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.032
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.185
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.077
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.787
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.037
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.18
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.256
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.193
1
SW 6020B
04/24/2023 21:25
MHALL3
1
0.035
1
SW 6020B
04/24/2023 21:25
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 21:25
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 21:25
MHALL3
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 13 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-7 Sample #: 2023006180
Collection Date: 04/19/2023 10:30 AM Loc code: CLS CCPMW-7 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040254
Chloride 11 mg/L
Fluoride 0.0479 U mg/L
Nitrate 9.6 mg/L
Nitrate as N 2.2 mg-N/L
Sulfate 0.56 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.01 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.031
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
4.38
mg/L
Iron (Fe)
0.069
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.66
mg/L
Manganese (Mn)
0.035
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040263
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.28
ug/L
Cobalt (Co)
0.196 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.071 J
ug/L
Molybdenum (Mo)
0.205 J
ug/L
Nickel (Ni)
1.16
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.068 J
ug/L
Vanadium (V) Low Level
0.258 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040257
TDS 61.0 mg/L
Method Analysis Date/Time Analyst
0.5
0.0154
5
EPA 9056A
04/20/2023 11:29
BGN9034
0.1
0.0479
1
EPA 9056A
04/20/2023 11:29
BGN9034
0.5
0.0209
5
EPA 9056A
04/20/2023 11:29
BGN9034
0.115
0.002
5
EPA 9056A
04/20/2023 11:29
BGN9034
0.1
0.0428
1
EPA 9056A
04/20/2023 11:29
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:46
JAA5429
0.005
0.002
1
SW 6010D
04/21/2023 11:46
CELL106
0.05
0.005
1
SW 6010D
04/21/2023 11:46
CELL106
M 0.05
0.012
1
SW 6010D
04/21/2023 11:46
CELL106
0.01
0.004
1
SW 6010D
04/21/2023 11:46
CELL106
0.005
0.002
1
SW 6010D
04/21/2023 11:46
CELL106
0.02
0.008
1
SW 6010D
04/21/2023 11:46
CELL106
0.005
0.001
1
SW 6010D
04/21/2023 11:46
CELL106
0.005
0.004
1
SW 601OD
04/21/2023 11:46
CELL106
1
0.104
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.111
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.249
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.032
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.185
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.077
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.787
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.037
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.18
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.256
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.193
1
SW 6020B
04/25/2023 00:13
MHALL3
1
0.035
1
SW 6020B
04/25/2023 00:13
MHALL3
0.2
0.041
1
SW 6020B
04/25/2023 00:13
MHALL3
0.3
0.114
1
SW 6020B
04/25/2023 00:13
MHALL3
25
25
1
SM2540C
04/20/202311:07
SNEGLIA

Certificate of Laboratory Analysis Page 14 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-10 Sample #: 2023006182
Collection Date: 04/19/2023 09:55 AM Loc code: CLS CCPMW-10 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040254
Chloride 5.5 mg/L
Fluoride 0.0479 U mg/L
Nitrate 7.7 mg/L
Nitrate as N 1.7 mg-N/L
Sulfate 0.18 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.05 ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.049
mg/L
Boron (B)
0.006 J
mg/L
Calcium (Ca)
1.68
mg/L
Iron (Fe)
0.082
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.73
mg/L
Manganese (Mn)
0.017
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040263
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.09
ug/L
Cobalt (Co)
0.92 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.115 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.663 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.058 J
ug/L
Thallium (TI) Low Level
0.063 J
ug/L
Vanadium (V) Low Level
0.165 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040257
TDS 36.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/20/2023 08:53
BGN9034
0.1
0.0479
1
EPA 9056A
04/20/2023 08:53
BGN9034
0.1
0.0209
1
EPA 9056A
04/20/2023 08:53
BGN9034
0.023
0.002
1
EPA 9056A
04/20/2023 08:53
BGN9034
0.1
0.0428
1
EPA 9056A
04/20/2023 08:53
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 12:53
JAA5429
0.005
0.002
1
SW 6010D
04/21/2023 12:05
CELL106
0.05
0.005
1
SW 6010D
04/21/2023 12:05
CELL106
0.05
0.012
1
SW 6010D
04/21/2023 12:05
CELL106
0.01
0.004
1
SW 6010D
04/21/2023 12:05
CELL106
0.005
0.002
1
SW 6010D
04/21/2023 12:05
CELL106
0.02
0.008
1
SW 6010D
04/21/2023 12:05
CELL106
0.005
0.001
1
SW 6010D
04/21/2023 12:05
CELL106
0.005
0.004
1
SW 601OD
04/21/2023 12:05
CELL106
1
0.104
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.111
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.249
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.032
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.185
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.077
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.787
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.037
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.18
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.256
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.193
1
SW 6020B
04/24/2023 23:31
MHALL3
1
0.035
1
SW 6020B
04/24/2023 23:31
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 23:31
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 23:31
MHALL3
25
25
1
SM2540C
04/20/202311:07
SNEGLIA

Certificate of Laboratory Analysis Page 15 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPMW-11 Sample #: 2023006183
Collection Date: 04/19/2023 01:30 PM Loc code: CLS CCPMW-11 Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040254
Chloride 4.6 mg/L
Fluoride 0.0479 U mg/L
Nitrate 5.8 mg/L
Nitrate as N 1.3 mg-N/L
Sulfate 2.4 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.038
mg/L
Boron (B)
0.013 J
mg/L
Calcium (Ca)
3.09
mg/L
Iron (Fe)
0.635
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
1.54
mg/L
Manganese (Mn)
0.012
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040263
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.167 J
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.72
ug/L
Cobalt (Co)
0.111 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.54 J
ug/L
Molybdenum (Mo)
0.187 J
ug/L
Nickel (Ni)
1.60
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.086 J
ug/L
Vanadium (V) Low Level
1.11
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040257
TDS 62.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/20/2023 09:09
BGN9034
0.1
0.0479
1
EPA 9056A
04/20/2023 09:09
BGN9034
0.1
0.0209
1
EPA 9056A
04/20/2023 09:09
BGN9034
0.023
0.002
1
EPA 9056A
04/20/2023 09:09
BGN9034
0.1
0.0428
1
EPA 9056A
04/20/2023 09:09
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 13:00
JAA5429
0.005
0.002
1
SW 6010D
04/21/2023 12:11
CELL106
0.05
0.005
1
SW 6010D
04/21/2023 12:11
CELL106
0.05
0.012
1
SW 6010D
04/21/2023 12:11
CELL106
0.01
0.004
1
SW 6010D
04/21/2023 12:11
CELL106
0.005
0.002
1
SW 6010D
04/21/2023 12:11
CELL106
0.02
0.008
1
SW 6010D
04/21/2023 12:11
CELL106
0.005
0.001
1
SW 6010D
04/21/2023 12:11
CELL106
0.005
0.004
1
SW 601OD
04/21/2023 12:11
CELL106
1
0.104
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.111
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.249
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.032
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.185
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.077
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.787
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.037
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.18
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.256
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.193
1
SW 6020B
04/25/2023 11:23
MHALL3
1
0.035
1
SW 6020B
04/25/2023 11:23
MHALL3
0.2
0.041
1
SW 6020B
04/25/2023 11:23
MHALL3
0.3
0.114
1
SW 6020B
04/25/2023 11:23
MHALL3
25
25
1
SM2540C
04/20/202311:08
SNEGLIA

Certificate of Laboratory Analysis Page 16 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCP-Leachate
Sample #:
2023006185
Collection Date: 04/19/2023 09:40 AM
Loc code: CLS CCP-Leachate
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23040254
Chloride
13000
mg/L
200
0.0154
2000
EPA 9056A
04/20/2023 10:42
BGN9034
Fluoride
0.1 J
mg/L
20
0.0479
200
EPA 9056A
04/20/2023 10:42
BGN9034
Nitrate
18 J
mg/L
20
0.0209
200
EPA 9056A
04/20/2023 10:42
BGN9034
Nitrate as N
4.2 J
mg-N/L
4.6
0.002
200
EPA 9056A
04/20/2023 10:42
BGN9034
Sulfate
850
mg/L
20
0.0428
200
EPA 9056A
04/20/2023 10:42
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.04 J
ug/L
0.05
0.01
1
EPA 7470A
04/21/2023 13:02
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040258
Zinc (Zn)
0.162
mg/L
0.005
0.004
1
SW 6010D
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.370
mg/L
0.005
0.002
1
SW 6010D
04/21/2023 12:16
CELL106
Boron (B)
10.0
mg/L
0.05
0.005
1
SW 601OD
04/21/2023 12:16
CELL106
Calcium (Ca)
7120
mg/L
5
0.012
100
SW 6010D
04/21/2023 12:16
CELL106
Iron (Fe)
0.290
mg/L
0.01
0.004
1
SW 6010D
04/21/2023 12:16
CELL106
Lithium (Li)
7.03
mg/L
0.005
0.002
1
SW 6010D
04/21/2023 12:16
CELL106
Magnesium (Mg)
48.6
mg/L
0.02
0.008
1
SW 6010D
04/21/2023 12:16
CELL106
Manganese (Mn)
10.2
mg/L
0.005
0.001
1
SW 6010D
04/21/2023 12:16
CELL106
Total Hardness (Ca and Mg)
18000
mg/L
0.19
1
SW 601OD
04/21/2023 12:16
CELL106
(CaCO3)
Zinc (Zn)
0.100
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q23040262
Beryllium (Be)
0.79 J
ug/L
2
0.249
Cadmium (Cd)
1.78
ug/L
1
0.032
Chromium (Cr)
0.475 J
ug/L
1
0.185
Copper (Cu)
34.3
ug/L
1
0.787
Lead (Pb)
119
ug/L
1
0.037
Nickel (Ni)
99.1
ug/L
1
0.256
Silver (Ag)
0.124 J
ug/L
1
0.035
1 SW 6010D
04/21/2023 12:16
CELL106
2 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3
1 SW 6020B
04/25/2023 20:12
MHALL3

Certificate of Laboratory Analysis Page 17 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCP-Leachate
Sample #:
2023006185
Collection Date: 04/19/2023 09:40 AM
Loc code: CLS CCP-Leachate
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040263
Antimony (Sb)
0.233 J
ug/L
1
0.104
1
SW 6020B
04/25/2023 00:30
MHALL3
Arsenic (As)
7.02
ug/L
1
0.111
1
SW 6020B
04/25/2023 00:30
MHALL3
Beryllium (Be)
1.26
ug/L
1
0.249
1
SW 6020B
04/25/2023 00:30
MHALL3
Cadmium (Cd)
1.76
ug/L
1
0.032
1
SW 6020B
04/25/2023 00:30
MHALL3
Chromium (Cr)
0.44 J
ug/L
1
0.185
1
SW 6020B
04/25/2023 00:30
MHALL3
Cobalt (Co)
477
ug/L
1
0.077
1
SW 6020B
04/25/2023 00:30
MHALL3
Copper (Cu)
32.0
ug/L
1
0.787
1
SW 6020B
04/25/2023 00:30
MHALL3
Lead (Pb)
122
ug/L
1
0.037
1
SW 6020B
04/25/2023 00:30
MHALL3
Molybdenum (Mo)
306
ug/L
1
0.18
1
SW 6020B
04/25/2023 00:30
MHALL3
Nickel (Ni)
98.2
ug/L
1
0.256
1
SW 6020B
04/25/2023 00:30
MHALL3
Selenium (Se)
76.7
ug/L
1
0.193
1
SW 6020B
04/25/2023 00:30
MHALL3
Silver (Ag)
0.11 J
ug/L
1
0.035
1
SW 6020B
04/25/2023 00:30
MHALL3
Thallium (TI) Low Level
8.77
ug/L
0.2
0.041
1
SW 6020B
04/25/2023 00:30
MHALL3
Vanadium (V) Low Level
0.883
ug/L
0.3
0.114
1
SW 6020B
04/25/2023 00:30
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040298
TDS
22600
mg/L
500
25
1
SM2540C
04/21/202310:54
SNEGLIA

Certificate of Laboratory Analysis Page 18 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS
CCP-LEACHATE-34
Sample #:
2023006186
Collection Date: 04/19/2023 09:50 AM
Loc code:
CLS CCP-LEACHATE-34
Matrix:
GW RCRA
Analyte
Result
Units Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23040254
Chloride
460
mg/L
20
0.0154
200
EPA 9056A
04/20/2023 10:58
BGN9034
Fluoride
0.34 J
mg/L
2
0.0479
20
EPA 9056A
04/20/2023 10:58
BGN9034
Nitrate
10
mg/L
2
0.0209
20
EPA 9056A
04/20/2023 10:58
BGN9034
Nitrate as N
2.3
mg-N/L
0.46
0.002
20
EPA 9056A
04/20/2023 10:58
BGN9034
Sulfate
1400
mg/L
20
0.0428
200
EPA 9056A
04/20/2023 10:58
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040258
Zinc (Zn)
0.265
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.058
mg/L
0.005
0.002
Boron (B)
4.36
mg/L
0.05
0.005
Calcium (Ca)
633
mg/L
0.5
0.012
Iron (Fe)
0.126
mg/L
0.01
0.004
Lithium (Li)
0.111
mg/L
0.005
0.002
Magnesium (Mg)
83.5
mg/L
0.02
0.008
Manganese (Mn)
11.6
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
1920
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.241
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040262
Beryllium (Be)
5.55
ug/L
1
0.249
Cadmium (Cd)
1.60
ug/L
1
0.032
Chromium (Cr)
2.48
ug/L
1
0.185
Copper (Cu)
113
ug/L
1
0.787
Lead (Pb)
19.3
ug/L
1
0.037
Nickel (Ni)
237
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
1 EPA 7470A 04/21/2023 13:04 JAA5429
1 SW 6010D
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 601OD
04/21/2023 12:23
CELL106
10 SW 6010D
04/21/2023 12:23
CELL106
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 601OD
04/21/2023 12:23
CELL106
1 SW 6010D
04/21/2023 12:23
CELL106
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3
1 SW 6020B
04/25/2023 19:29
MHALL3

Certificate of Laboratory Analysis Page 19 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCP-LEACHATE-34
Sample #:
2023006186
Collection Date: 04/19/2023 09:50 AM
Loc code:
CLS CCP-LEACHATE-34
Matrix:
GW RCRA
Analyte
Result
Units Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040263
Antimony (Sb)
0.285 J
ug/L
1
0.104
1
SW 6020B
04/25/2023 00:38
MHALL3
Arsenic (As)
4.62
ug/L
1
0.111
1
SW 6020B
04/25/2023 00:38
MHALL3
Beryllium (Be)
5.53
ug/L
1
0.249
1
SW 6020B
04/25/2023 00:38
MHALL3
Cadmium (Cd)
1.64
ug/L
1
0.032
1
SW 6020B
04/25/2023 00:38
MHALL3
Chromium (Cr)
2.50
ug/L
1
0.185
1
SW 6020B
04/25/2023 00:38
MHALL3
Cobalt (Co)
331
ug/L
1
0.077
1
SW 6020B
04/25/2023 00:38
MHALL3
Copper (Cu)
115
ug/L
1
0.787
1
SW 6020B
04/25/2023 00:38
MHALL3
Lead (Pb)
20.0
ug/L
1
0.037
1
SW 6020B
04/25/2023 00:38
MHALL3
Molybdenum (Mo)
1.72
ug/L
1
0.18
1
SW 6020B
04/25/2023 00:38
MHALL3
Nickel (Ni)
243
ug/L
1
0.256
1
SW 6020B
04/25/2023 00:38
MHALL3
Selenium (Se)
21.2
ug/L
1
0.193
1
SW 6020B
04/25/2023 00:38
MHALL3
Silver (Ag)
0.056 J
ug/L
1
0.035
1
SW 6020B
04/25/2023 00:38
MHALL3
Thallium (TI) Low Level
1.95
ug/L
0.2
0.041
1
SW 6020B
04/25/2023 00:38
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
04/25/2023 00:38
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040298
TDS
2750
mg/L
100
25
1
SM2540C
04/21/202310:54
SNEGLIA

Certificate of Laboratory Analysis Page 20 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-1 Sample #: 2023006187
Collection Date: 04/18/2023 10:00 AM Loc code: CLS CCPSW-1 Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23040225
Chloride
3.9
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
2.0
mg/L
0.1
0.0209
Nitrate as N
0.45
mg-N/L
0.023
0.002
Sulfate
1.6
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040228
Zinc (Zn)
0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.025
mg/L
0.005
0.002
Boron (B)
0.006 J
mg/L
0.05
0.005
Calcium (Ca)
2.39
mg/L
0.05
0.012
Iron (Fe)
1.15
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
1.27
mg/L
0.02
0.008
Manganese (Mn)
0.041
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
11.2
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 J
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040235
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.312 J
ug/L
1
0.185
Copper (Cu)
0.821 J
ug/L
1
0.787
Lead (Pb)
0.123 J
ug/L
1
0.037
Nickel (Ni)
0.48 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
04/19/2023 10:37
BGN9034
1
EPA 9056A
04/19/2023 10:37
BGN9034
1
EPA 9056A
04/19/2023 10:37
BGN9034
1
EPA 9056A
04/19/2023 10:37
BGN9034
1
EPA 9056A
04/19/2023 10:37
BGN9034
1
EPA 7470A
04/21/2023 13:07
JAA5429
1
SW 6010D
04/20/2023 13:35
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 601OD
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 601OD
04/20/2023 14:48
CELL106
1
SW 6010D
04/20/2023 14:48
CELL106
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3
1
SW 6020B
04/25/2023 16:25
MHALL3

Certificate of Laboratory Analysis Page 21 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-1
Sample #:
2023006187
Collection Date: 04/18/2023 10:00 AM
Loc code: CLS CCPSW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040238
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/24/2023 21:34
MHALL3
Arsenic (As)
0.243 J
ug/L
1
0.111
1
SW 6020B
04/24/2023 21:34
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/24/2023 21:34
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
04/24/2023 21:34
MHALL3
Chromium (Cr)
0.708 J
ug/L
1
0.185
1
SW 6020B
04/24/2023 21:34
MHALL3
Cobalt (Co)
0.324 J
ug/L
1
0.077
1
SW 6020B
04/24/2023 21:34
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
04/24/2023 21:34
MHALL3
Lead (Pb)
0.259 J
ug/L
1
0.037
1
SW 6020B
04/24/2023 21:34
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
04/24/2023 21:34
MHALL3
Nickel (Ni)
0.458 J
ug/L
1
0.256
1
SW 6020B
04/24/2023 21:34
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/24/2023 21:34
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
04/24/2023 21:34
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/24/2023 21:34
MHALL3
Vanadium (V) Low Level
0.669
ug/L
0.3
0.114
1
SW 6020B
04/24/2023 21:34
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040226
TDS
34.0
mg/L
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 22 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-2 Sample #: 2023006188
Collection Date: 04/18/2023 09:40 AM Loc code: CLS CCPSW-2 Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23040225
Chloride
4.0
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
2.0
mg/L
0.1
0.0209
Nitrate as N
0.46
mg-N/L
0.023
0.002
Sulfate
2.0
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040228
Zinc (Zn)
0.011
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.026
mg/L
0.005
0.002
Boron (B)
0.006 J
mg/L
0.05
0.005
Calcium (Ca)
2.59
mg/L
0.05
0.012
Iron (Fe)
1.20
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
1.34
mg/L
0.02
0.008
Manganese (Mn)
0.039
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
12.0
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040235
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.128 J
ug/L
1
0.032
Chromium (Cr)
0.352 J
ug/L
1
0.185
Copper (Cu)
3.99
ug/L
1
0.787
Lead (Pb)
0.161 J
ug/L
1
0.037
Nickel (Ni)
0.481 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
04/19/2023 10:53
BGN9034
1
EPA 9056A
04/19/2023 10:53
BGN9034
1
EPA 9056A
04/19/2023 10:53
BGN9034
1
EPA 9056A
04/19/2023 10:53
BGN9034
1
EPA 9056A
04/19/2023 10:53
BGN9034
1
EPA 7470A
04/21/2023 13:09
JAA5429
1
SW 6010D
04/20/2023 13:49
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 601OD
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 601OD
04/20/2023 15:01
CELL106
1
SW 6010D
04/20/2023 15:01
CELL106
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3
1
SW 6020B
04/25/2023 16:00
MHALL3

Certificate of Laboratory Analysis Page 23 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-2
Sample #:
2023006188
Collection Date: 04/18/2023 09:40 AM
Loc code: CLS CCPSW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040238
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/24/2023 21:42
MHALL3
Arsenic (As)
0.242 J
ug/L
1
0.111
1
SW 6020B
04/24/2023 21:42
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/24/2023 21:42
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
04/24/2023 21:42
MHALL3
Chromium (Cr)
0.709 J
ug/L
1
0.185
1
SW 6020B
04/24/2023 21:42
MHALL3
Cobalt (Co)
0.358 J
ug/L
1
0.077
1
SW 6020B
04/24/2023 21:42
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
04/24/2023 21:42
MHALL3
Lead (Pb)
0.312 J
ug/L
1
0.037
1
SW 6020B
04/24/2023 21:42
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
04/24/2023 21:42
MHALL3
Nickel (Ni)
0.428 J
ug/L
1
0.256
1
SW 6020B
04/24/2023 21:42
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/24/2023 21:42
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
04/24/2023 21:42
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/24/2023 21:42
MHALL3
Vanadium (V) Low Level
0.822
ug/L
0.3
0.114
1
SW 6020B
04/24/2023 21:42
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040226
TDS
32.0
mg/L
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 24 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-3 Sample #: 2023006189
Collection Date: 04/18/2023 10:25 AM Loc code: CLS CCPSW-3 Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23040225
Chloride
4.5
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.24
mg/L
0.1
0.0209
Nitrate as N
0.06
mg-N/L
0.023
0.002
Sulfate
3.0
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.03 J
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040228
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.017
mg/L
0.005
0.002
Boron (B)
0.009 J
mg/L
0.05
0.005
Calcium (Ca)
2.34
mg/L
0.05
0.012
Iron (Fe)
0.245
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
1.48
mg/L
0.02
0.008
Manganese (Mn)
0.008
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
12.0
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040235
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.347 J
ug/L
1
0.185
Copper (Cu)
3.65
ug/L
1
0.787
Lead (Pb)
0.098 J
ug/L
1
0.037
Nickel (Ni)
0.425 J
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
04/19/2023 11:09
BGN9034
1
EPA 9056A
04/19/2023 11:09
BGN9034
1
EPA 9056A
04/19/2023 11:09
BGN9034
1
EPA 9056A
04/19/2023 11:09
BGN9034
1
EPA 9056A
04/19/2023 11:09
BGN9034
1
EPA 7470A
04/21/2023 13:11
JAA5429
1
SW 6010D
04/20/2023 13:54
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 601OD
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 601OD
04/20/2023 15:07
CELL106
1
SW 6010D
04/20/2023 15:07
CELL106
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3
1
SW 6020B
04/25/2023 16:33
MHALL3

Certificate of Laboratory Analysis Page 25 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCPSW-3
Sample #:
2023006189
Collection Date: 04/18/2023 10:25 AM
Loc code: CLS CCPSW-3
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040238
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
04/24/2023 21:50
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
04/24/2023 21:50
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
04/24/2023 21:50
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
04/24/2023 21:50
MHALL3
Chromium (Cr)
0.647 J
ug/L
1
0.185
1
SW 6020B
04/24/2023 21:50
MHALL3
Cobalt (Co)
0.255 J
ug/L
1
0.077
1
SW 6020B
04/24/2023 21:50
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
04/24/2023 21:50
MHALL3
Lead (Pb)
0.205 J
ug/L
1
0.037
1
SW 6020B
04/24/2023 21:50
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
04/24/2023 21:50
MHALL3
Nickel (Ni)
0.374 J
ug/L
1
0.256
1
SW 6020B
04/24/2023 21:50
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
04/24/2023 21:50
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
04/24/2023 21:50
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
04/24/2023 21:50
MHALL3
Vanadium (V) Low Level
0.565
ug/L
0.3
0.114
1
SW 6020B
04/24/2023 21:50
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040226
TDS
33.0
mg/L
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 26 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS_FD-20230418-1 Duplicate Sample #: 2023006190
Collection Date: 04/18/2023 10:30 AM Loc code: CLS FD Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 5.8 mg/L
Fluoride 0.0479 U mg/L
Nitrate 4.8 mg/L
Nitrate as N 1.1 mg-N/L
Sulfate 24 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.03 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.028
mg/L
Boron (B)
0.072
mg/L
Calcium (Ca)
12.0
mg/L
Iron (Fe)
0.019
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.47
mg/L
Manganese (Mn)
0.007
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
1.30
ug/L
Cobalt (Co)
0.077 U
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.256 U
ug/L
Selenium (Se)
0.469 J
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.195 J
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 72.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 08:02
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 08:02
BGN9034
0.1
0.0209
1
EPA 9056A
04/19/2023 08:02
BGN9034
0.023
0.002
1
EPA 9056A
04/19/2023 08:02
BGN9034
0.5
0.0428
5
EPA 9056A
04/19/2023 08:02
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 13:13
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 15:12
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 15:12
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 15:12
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 15:12
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 15:12
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 15:12
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 15:12
CELL106
0.005
0.004
1
SW 6010D
04/20/2023 15:12
CELL106
1
0.104
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.111
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.249
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.032
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.185
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.077
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.787
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.037
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.18
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.256
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.193
1
SW 6020B
04/24/2023 21:59
MHALL3
1
0.035
1
SW 6020B
04/24/2023 21:59
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 21:59
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 21:59
MHALL3
25
25
1
SM2540C
04/19/202310:11
SNEGLIA

Certificate of Laboratory Analysis Page 27 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS FB-20230418-1300 Field Blank Sample #: 2023006191
Collection Date: 04/18/2023 01:00 PM Loc code: CLS QA Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23040225
Chloride
0.0154 U
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.0209 U
mg/L
0.1
0.0209
Nitrate as N
0.002 U
mg-N/L
0.023
0.002
Sulfate
0.0428 U
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040228
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
Iron (Fe)
0.004 U
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040235
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.037 U
ug/L
1
0.037
Nickel (Ni)
0.256 U
ug/L
1
0.256
Silver (Ag)
0.035 U
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
04/19/2023 06:59
BGN9034
1
EPA 9056A
04/19/2023 06:59
BGN9034
1
EPA 9056A
04/19/2023 06:59
BGN9034
1
EPA 9056A
04/19/2023 06:59
BGN9034
1
EPA 9056A
04/19/2023 06:59
BGN9034
1
EPA 7470A
04/21/2023 13:16
JAA5429
1
SW 6010D
04/20/2023 13:58
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 601OD
04/20/2023 15:17
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 6010D
04/20/2023 15:17
CELL106
1
SW 601OD
04/20/2023 15:17
CELL106
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3
1
SW 6020B
04/25/2023 16:42
MHALL3

Certificate of Laboratory Analysis Page 28 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS FB-20230418-1300 Field Blank Sample #: 2023006191
Collection Date: 04/18/2023 01:00 PM Loc code: CLS QA Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040238
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
Analysis Date/Time
Analyst
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3
04/24/2023 22:07
MHALL3

Certificate of Laboratory Analysis Page 29 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCR-CCPBG-1 D Sample #: 2023006192
Collection Date: 04/18/2023 01:25 PM Loc code: CLS CCR-CCPBG-1 D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 9.5 mg/L
Fluoride 0.0479 U mg/L
Nitrate 16 mg/L
Nitrate as N 3.6 mg-N/L
Sulfate 0.38 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.033
mg/L
Boron (B)
0.005 U
mg/L
Calcium (Ca)
3.35
mg/L
Iron (Fe)
0.247
mg/L
Lithium (Li)
0.002 U
mg/L
Magnesium (Mg)
2.36
mg/L
Manganese (Mn)
0.044
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.155 J
ug/L
Arsenic (As)
0.111 U
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.638 J
ug/L
Cobalt (Co)
0.993 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.126 J
ug/L
Molybdenum (Mo)
0.18 U
ug/L
Nickel (Ni)
0.925 J
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.066 J
ug/L
Vanadium (V) Low Level
0.383
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 58.0 mg/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
04/19/2023 09:04
BGN9034
0.1
0.0479
1
EPA 9056A
04/19/2023 09:04
BGN9034
0.5
0.0209
5
EPA 9056A
04/19/2023 09:04
BGN9034
0.115
0.002
5
EPA 9056A
04/19/2023 09:04
BGN9034
0.1
0.0428
1
EPA 9056A
04/19/2023 09:04
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 13:18
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 15:22
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 15:22
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 15:22
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 15:22
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 15:22
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 15:22
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 15:22
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 15:22
CELL106
1
0.104
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.111
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.249
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.032
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.185
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.077
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.787
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.037
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.18
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.256
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.193
1
SW 6020B
04/24/2023 22:15
MHALL3
1
0.035
1
SW 6020B
04/24/2023 22:15
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 22:15
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 22:15
MHALL3
25
25
1
SM2540C
04/19/202310:12
SNEGLIA

Certificate of Laboratory Analysis Page 30 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS CCR-CCPBG-1 BR Sample #: 2023006193
Collection Date: 04/18/2023 12:30 PM Loc code: CLS CCR-CCPBG-1 BR Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q23040225
Chloride 210 mg/L
Fluoride 0.14 J mg/L
Nitrate 5.5 mg/L
Nitrate as N 1.2 mg-N/L
Sulfate 300 mg/L
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg) 0.02 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q23040231
Barium (Ba)
0.010
mg/L
Boron (B)
0.015 J
mg/L
Calcium (Ca)
57.4
mg/L
Iron (Fe)
0.013
mg/L
Lithium (Li)
0.016
mg/L
Magnesium (Mg)
4.96
mg/L
Manganese (Mn)
0.076
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS
- Q23040238
Antimony (Sb)
0.237 J
ug/L
Arsenic (As)
1.22
ug/L
Beryllium (Be)
0.249 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.883 J
ug/L
Cobalt (Co)
0.13 J
ug/L
Copper (Cu)
0.787 U
ug/L
Lead (Pb)
0.037 U
ug/L
Molybdenum (Mo)
39.1
ug/L
Nickel (Ni)
2.39
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
1.05
ug/L
TOTAL DISSOLVED SOLIDS
- Q23040226
TDS 857 mg/L
Method Analysis Date/Time Analyst
5
0.0154
50
EPA 9056A
04/19/2023 12:27
BGN9034
0.5
0.0479
5
EPA 9056A
04/19/2023 12:27
BGN9034
0.5
0.0209
5
EPA 9056A
04/19/2023 12:27
BGN9034
0.115
0.002
5
EPA 9056A
04/19/2023 12:27
BGN9034
5
0.0428
50
EPA 9056A
04/19/2023 12:27
BGN9034
0.05
0.01
1
EPA 7470A
04/21/2023 13:29
JAA5429
0.005
0.002
1
SW 6010D
04/20/2023 15:27
CELL106
0.05
0.005
1
SW 6010D
04/20/2023 15:27
CELL106
0.05
0.012
1
SW 6010D
04/20/2023 15:27
CELL106
0.01
0.004
1
SW 6010D
04/20/2023 15:27
CELL106
0.005
0.002
1
SW 6010D
04/20/2023 15:27
CELL106
0.02
0.008
1
SW 6010D
04/20/2023 15:27
CELL106
0.005
0.001
1
SW 6010D
04/20/2023 15:27
CELL106
0.005
0.004
1
SW 601OD
04/20/2023 15:27
CELL106
1
0.104
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.111
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.249
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.032
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.185
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.077
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.787
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.037
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.18
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.256
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.193
1
SW 6020B
04/24/2023 22:24
MHALL3
1
0.035
1
SW 6020B
04/24/2023 22:24
MHALL3
0.2
0.041
1
SW 6020B
04/24/2023 22:24
MHALL3
0.3
0.114
1
SW 6020B
04/24/2023 22:24
MHALL3
25
25
1
SM2540C
04/19/202310:12
SNEGLIA

Certificate of Laboratory Analysis Page 31 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS_FD-20230419-1 Duplicate
Sample #:
2023006194
Collection Date:
04/19/2023
Loc code: CLS
FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q23040254
Chloride
13000
mg/L
200
0.0154
2000
EPA 9056A
04/20/2023 11:13
BGN9034
Fluoride
0.0479 U
mg/L
20
0.0479
200
EPA 9056A
04/20/2023 11:13
BGN9034
Nitrate
20 J
mg/L
20
0.0209
200
EPA 9056A
04/20/2023 11:13
BGN9034
Nitrate as N
4.5 J
mg-N/L
4.6
0.002
200
EPA 9056A
04/20/2023 11:13
BGN9034
Sulfate
850
mg/L
20
0.0428
200
EPA 9056A
04/20/2023 11:13
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
04/21/2023 13:36
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23050128
Zinc (Zn)
0.131
mg/L
0.005
0.004
1
SW 6010D
05/09/2023 11:31
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.374
mg/L
0.005
0.002
1
SW 6010D
04/21/2023 12:28
CELL106
Boron (B)
11.3
mg/L
0.05
0.005
1
SW 601OD
04/21/2023 12:28
CELL106
Calcium (Ca)
7100
mg/L
5
0.012
100
SW 6010D
04/21/2023 12:28
CELL106
Iron (Fe)
0.274
mg/L
0.01
0.004
1
SW 6010D
04/21/2023 12:28
CELL106
Lithium (Li)
6.65
mg/L
0.005
0.002
1
SW 6010D
04/21/2023 12:28
CELL106
Magnesium (Mg)
50.2
mg/L
0.02
0.008
1
SW 6010D
04/21/2023 12:28
CELL106
Manganese (Mn)
11.1
mg/L
0.005
0.001
1
SW 6010D
04/21/2023 12:28
CELL106
Zinc (Zn)
0.114
mg/L
0.005
0.004
1
SW 601OD
04/21/2023 12:28
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23050134
Beryllium (Be)
0.741 J
ug/L
1
0.249
1
SW 6020B
05/09/2023 14:04
MHALL3
Cadmium (Cd)
2.10
ug/L
1
0.032
1
SW 6020B
05/09/2023 14:04
MHALL3
Chromium (Cr)
0.965 J
ug/L
1
0.185
1
SW 6020B
05/09/2023 14:04
MHALL3
Copper (Cu)
35.0
ug/L
1
0.787
1
SW 6020B
05/09/2023 14:04
MHALL3
Lead (Pb)
112
ug/L
10
0.037
10
SW 6020B
05/09/2023 14:04
MHALL3
Nickel (Ni)
106
ug/L
1
0.256
1
SW 6020B
05/09/2023 14:04
MHALL3
Silver (Ag)
0.217 J
ug/L
1
0.035
1
SW 6020B
05/09/2023 14:04
MHALL3

Certificate of Laboratory Analysis Page 32 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS_FD-20230419-1
Duplicate
Sample #:
2023006194
Collection Date: 04/19/2023
Loc code: CLS
FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040263
Antimony (Sb)
0.335 J
ug/L
1
0.104
1
SW 6020B
04/26/2023 12:27
MHALL3
Arsenic (As)
7.74
ug/L
1
0.111
1
SW 6020B
04/26/2023 12:27
MHALL3
Beryllium (Be)
0.625 J
ug/L
2
0.249
2
SW 6020B
04/26/2023 12:27
MHALL3
Cadmium (Cd)
1.81
ug/L
1
0.032
1
SW 6020B
04/26/2023 12:27
MHALL3
Chromium (Cr)
0.378 J
ug/L
1
0.185
1
SW 6020B
04/26/2023 12:27
MHALL3
Cobalt (Co)
514
ug/L
2
0.077
2
SW 6020B
04/26/2023 12:27
MHALL3
Copper (Cu)
33.9
ug/L
1
0.787
1
SW 6020B
04/26/2023 12:27
MHALL3
Lead (Pb)
119
ug/L
1
0.037
1
SW 6020B
04/26/2023 12:27
MHALL3
Molybdenum (Mo)
348
ug/L
1
0.18
1
SW 6020B
04/26/2023 12:27
MHALL3
Nickel (Ni)
102
ug/L
1
0.256
1
SW 6020B
04/26/2023 12:27
MHALL3
Selenium (Se)
83.5
ug/L
2
0.193
2
SW 6020B
04/26/2023 12:27
MHALL3
Silver (Ag)
0.128 J
ug/L
1
0.035
1
SW 6020B
04/26/2023 12:27
MHALL3
Thallium (TI) Low Level
9.31
ug/L
0.2
0.041
1
SW 6020B
04/26/2023 12:27
MHALL3
Vanadium (V) Low Level
1.26
ug/L
0.3
0.114
1
SW 6020B
04/26/2023 12:27
MHALL3
TOTAL DISSOLVED SOLIDS - Q23040298
TDS
23200
mg/L
500
25
1
SM2540C
04/21/202310:54
SNEGLIA

Certificate of Laboratory Analysis Page 33 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS FB-20230419-0940 Field Blank Sample #: 2023009450
Collection Date: 04/19/2023 09:40 AM Loc code: CLS QA Matrix: GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
INORGANIC IONS BY IC - Q23040254
Chloride
0.0154 U
mg/L
0.1
0.0154
Fluoride
0.0479 U
mg/L
0.1
0.0479
Nitrate
0.0209 U
mg/L
0.1
0.0209
Nitrate as N
0.002 U
mg-N/L
0.023
0.002
Sulfate
0.0428 U
mg/L
0.1
0.0428
MERCURY (COLD VAPOR) IN WATER - Q23040306
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23040258
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q23040260
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.042 J
mg/L
0.05
0.005
Calcium (Ca)
0.02 J
mg/L
0.05
0.012
Iron (Fe)
0.004 U
mg/L
0.01
0.004
Lithium (Li)
0.002 U
mg/L
0.005
0.002
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23040262
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.094 J
ug/L
1
0.032
Chromium (Cr)
0.33 J
ug/L
1
0.185
Copper (Cu)
0.787 U
ug/L
1
0.787
Lead (Pb)
0.176 J
ug/L
1
0.037
Nickel (Ni)
0.581 J
ug/L
1
0.256
Silver (Ag)
0.078 J
ug/L
1
0.035
DF
Method
Analysis Date/Time
Analyst
1
EPA 9056A
04/20/2023 07:21
BGN9034
1
EPA 9056A
04/20/2023 07:21
BGN9034
1
EPA 9056A
04/20/2023 07:21
BGN9034
1
EPA 9056A
04/20/2023 07:21
BGN9034
1
EPA 9056A
04/20/2023 07:21
BGN9034
1
EPA 7470A
04/24/2023 14:31
jaa5429
1 SW 6010D
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 601OD
04/21/2023 12:34
CELL106
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 6010D
04/21/2023 12:34
CELL106
1 SW 601OD
04/21/2023 12:34
CELL106
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3
1 SW 6020B
04/25/2023 20:20
MHALL3

Certificate of Laboratory Analysis Page 34 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Site: CLS FB-20230419-0940 Field Blank Sample #: 2023009450
Collection Date: 04/19/2023 09:40 AM Loc code: CLS QA Matrix: GW RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
TOTAL RECOVERABLE METALS BY ICP-MS - Q23040263
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
Analysis Date/Time
Analyst
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
04/25/2023 00:55
MHALL3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated Laboratory Control
Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 35 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040225 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.03
5.03
mg/L
1
0.0154
5
101
80
120
Fluoride
4.82
4.82
mg/L
1
0.0479
5
96.5
80
120
Nitrate
5.12
5.12
mg/L
1
0.0209
5
102
80
120
Sulfate
5.09
5.09
mg/L
1
0.0428
5
102
80
120
MS # 1
Parent Sample:
J23030262 -- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
6.95
6.95
mg/L
1
0.0154
3
99.1
80
120
Fluoride
2.87
2.87
mg/L
1
0.0479
3
95.6
80
120
Nitrate
3.17
3.17
mg/L
1
0.0209
3
99.9
80
120
Sulfate
4.04
4.04
mg/L
1
0.0428
3
103
80
120
MSD # 1
Parent Sample:
J23030262 -- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
6.99
6.99
mg/L
1
0.0154
3
100
80
120
1.17
Fluoride
2.91
2.91
mg/L
1
0.0479
3
96.9
80
120
1.35
Nitrate
3.21
3.21
mg/L
1
0.0209
3
101
80
120
1.19
Sulfate
4.09
4.09
mg/L
1
0.0428
3
104
80
120
1.48

Certificate of Laboratory Analysis Page 36 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040254 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
5.04
5.04
mg/L
1
0.0154
5
101
80
120
Fluoride
4.83
4.83
mg/L
1
0.0479
5
96.7
80
120
Nitrate
5.14
5.14
mg/L
1
0.0209
5
103
80
120
Sulfate
5.13
5.13
mg/L
1
0.0428
5
103
80
120
MS # 1
Parent Sample:
J23030262 -- 2023006180
Parameter
Measured
Final
Units
Di
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
3.1
15.5
mg/L
5
0.0154
5
98
80
120
Fluoride
4.73
4.73
mg/L
1
0.0479
5
94.3
80
120
Nitrate
2.86
14.3
mg/L
5
0.0209
5
94
80
120
Sulfate
5.55
5.55
mg/L
1
0.0428
5
99.7
80
120
MSD # 1
Parent Sample:
J23030262 -- 2023006180
Parameter
Measured
Final
Units
Dil
MDL
Sake
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
3.1
15.5
mg/L
5
0.0154
5
98.1
80
120
0.102
Fluoride
4.74
4.74
mg/L
1
0.0479
5
94.4
80
120
0.0848
Nitrate
2.83
14.2
mg/L
5
0.0209
5
90.8
80
120
3.46
Sulfate
5.57
5.57
mg/L
1
0.0428
5
100
80
120
0.38

Certificate of Laboratory Analysis Page 37 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040306 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.006
0.006
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.017
0.017
ug/L
1
0.01
0.05
> MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.017
0.017
ug/L
1
0.01
0.05
> MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
2.04
2.04
ug/L
1
0.01
2
102 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.08
2.08
ug/L
1
0.01
2
104
85 115
MS # 1
Parent Sample:
J23030262 -- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.07
1.07
ug/L
1
0.01
1
102
75 125
MSD # 1
Parent Sample:
J23030262 -- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
99.6
75 125 2.77
MS # 2
Parent Sample:
J23030262 -- 2023006182
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.06
1.06
ug/L
1
0.01
1
101
75 125
MSD # 2
Parent Sample:
J23030262 -- 2023006182
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.11
1.11
ug/L
1
0.01
1
105
75 125 4.17
MS # 3
Parent Sample:
J23030262 -- 2023006193
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.12
1.12
ug/L
1
0.01
1
110
75 125

Certificate of Laboratory Analysis Page 38 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040306 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3 Parent Sample: J23030262 -- 2023006193
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Mercury (Hg) 1.15 1.15 ug/L 1 0.01 1 113 75 125 2.86

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040228 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Page 39 of 59
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
0.0007
0.0007
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.2
5.2
mg/L
1
0.004
5
104
80
120
MS # 1
Parent Sample:
J23030262 -- 2023006187
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.23
5.23
mg/L
1
0.004
5
105
70
130
MSD # 1
Parent Sample:
J23030262 -- 2023006187
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.22
5.22
mg/L
1
0.004
5
104
70
130 0.329
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 40 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040258 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
0.0013
0.0013
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.08
5.08
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J23030262 -- 2023006185
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
4.96
4.96
mg/L
1
0.004
5
96
70
130
MSD # 1
Parent Sample:
J23030262 -- 2023006185
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
4.96
4.96
mg/L
1
0.004
5
96
70
130 0.00202
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 41 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23050128 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
LCS # 1
Parameter Measured Final
Zinc (Zn)-0.00146-0.00146
Parameter Measured Final
Zinc (Zn) 5.18 5.18
LCSD # 1
Parameter Measured Final
Zinc (Zn) 5.1 5.1
Units Dil MDL RDL Relative Concentration
mg/L 1 0.004 0.005 < MDL
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 0.004 5 104 80 120
Units Dil MDL Spike % Recovery LCL UCL
mg/L 1 0.004 5 102 80 120
Qualifier
Qualifier
RPD Qualifier
1.44

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040231 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000748
-0.000748
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00048
0.00048
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.0058
0.0058
mg/L
1
0.012
0.05
< MDL
Iron (Fe)
0.000294
0.000294
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.000862
-0.000862
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
-0.00224
-0.00224
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000108
-0.000108
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.0005
-0.0005
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 42 of 59
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.15
5.15
mg/L
1
0.002
5
103
80
120
Boron (B)
5.02
5.02
mg/L
1
0.005
5
100
80
120
Calcium (Ca)
4.98
4.98
mg/L
1
0.012
5
99.6
80
120
Iron (Fe)
5.01
5.01
mg/L
1
0.004
5
100
80
120
Lithium (Li)
5.11
5.11
mg/L
1
0.002
5
102
80
120
Magnesium (Mg)
5.01
5.01
mg/L
1
0.008
5
100
80
120
Manganese (Mn)
4.95
4.95
mg/L
1
0.001
5
98.9
80
120
Zinc (Zn)
4.98
4.98
mg/L
1
0.004
5
99.6
80
120
MS # 1
Parent Sample:
J23030262
-- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.2
5.2
mg/L
1
0.002
5
104
75
125
Boron (B)
4.96
4.96
mg/L
1
0.005
5
99.2
75
125
Calcium (Ca)
5.08
5.08
mg/L
1
0.012
5
98.9
75
125
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
99.9
75
125
Lithium (Li)
5.03
5.03
mg/L
1
0.002
5
100
75
125
Magnesium (Mg)
5.49
5.49
mg/L
1
0.008
5
99.5
75
125
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
99.2
75
125
Zinc (Zn)
4.97
4.97
mg/L
1
0.004
5
99.4
75
125
MSD # 1
Parent Sample:
J23030262
-- 2023006170
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.23
5.23
mg/L
1
0.002
5
104
75
125
0.575
Boron (B)
5.01
5.01
mg/L
1
0.005
5
100
75
125
0.922
Calcium (Ca)
5.12
5.12
mg/L
1
0.012
5
99.8
75
125
0.844
Iron (Fe)
5.1
5.1
mg/L
1
0.004
5
101
75
125
0.709
Lithium (Li)
5.08
5.08
mg/L
1
0.002
5
102
75
125
1.11
Magnesium (Mg)
5.53
5.53
mg/L
1
0.008
5
100
75
125
0.635
Manganese (Mn)
5.01
5.01
mg/L
1
0.001
5
99.8
75
125
0.581
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 43 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040231 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23030262 -- 2023006170
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 5.01 5.01 mg/L 1 0.004 5 100 75 125 0.737

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040260 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000773
-0.000773
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000118
0.000118
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.0126
0.0126
mg/L
1
0.012
0.05
> MDL
Iron (Fe)
0.000908
0.000908
mg/L
1
0.004
0.01
< MDL
Lithium (Li)
-0.000121
-0.000121
mg/L
1
0.002
0.005
< MDL
Magnesium (Mg)
0.000201
0.000201
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000072
-0.000072
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.00158
-0.00158
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 44 of 59
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.07
5.07
mg/L
1
0.002
5
101
80
120
Boron (B)
4.98
4.98
mg/L
1
0.005
5
99.6
80
120
Calcium (Ca)
5.04
5.04
mg/L
1
0.012
5
101
80
120
Iron (Fe)
5.04
5.04
mg/L
1
0.004
5
101
80
120
Lithium (Li)
4.91
4.91
mg/L
1
0.002
5
98.1
80
120
Magnesium (Mg)
5.02
5.02
mg/L
1
0.008
5
100
80
120
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
99.7
80
120
Zinc (Zn)
5.07
5.07
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J23030262
-- 2023006180
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
101
75
125
Boron (B)
4.96
4.96
mg/L
1
0.005
5
99.2
75
125
Calcium (Ca)
10.8
10.8
mg/L
1
0.012
5
128
75
125
Iron (Fe)
5.08
5.08
mg/L
1
0.004
5
100
75
125
Lithium (Li)
4.96
4.96
mg/L
1
0.002
5
99.2
75
125
Magnesium (Mg)
7.11
7.11
mg/L
1
0.008
5
109
75
125
Manganese (Mn)
4.97
4.97
mg/L
1
0.001
5
98.8
75
125
Zinc (Zn)
4.92
4.92
mg/L
1
0.004
5
98.4
75
125
MSD # 1
Parent Sample:
J23030262
-- 2023006180
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
101
75
125
0.137
Boron (B)
4.99
4.99
mg/L
1
0.005
5
99.8
75
125
0.603
Calcium (Ca)
10.7
10.7
mg/L
1
0.012
5
127
75
125
0.651
Iron (Fe)
5.07
5.07
mg/L
1
0.004
5
100
75
125
0.0394
Lithium (Li)
4.98
4.98
mg/L
1
0.002
5
99.5
75
125
0.282
Magnesium (Mg)
7.09
7.09
mg/L
1
0.008
5
109
75
125
0.31
Manganese (Mn)
4.95
4.95
mg/L
1
0.001
5
98.3
75
125
0.463
Qualifier
Qualifier
Qualifier
M
Qualifier
M

Certificate of Laboratory Analysis Page 45 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040260 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J23030262 -- 2023006180
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.91 4.91 mg/L 1 0.004 5 98.1 75 125 0.305
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.

Certificate of Laboratory Analysis Page 46 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040235 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
-0.021
-0.021
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.002
0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.014
0.014
ug/L
1
0.185
1
< MDL
Copper (Cu)
-0.007
-0.007
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.003
-0.003
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.029
-0.029
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.004
0.004
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Beryllium (Be)
51.7
51.7
ug/L
1
0.249
50
103
80
120
Cadmium (Cd)
51
51
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
51.4
51.4
ug/L
1
0.185
50
103
80
120
Copper(Cu)
51.9
51.9
ug/L
1
0.787
50
104
80
120
Lead (Pb)
51.5
51.5
ug/L
1
0.037
50
103
80
120
Nickel (Ni)
51.1
51.1
ug/L
1
0.256
50
102
80
120
Silver (Ag)
51.3
51.3
ug/L
1
0.035
50
103
80
120
Parent Sample:
J23030262 -- 2023006188
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Beryllium (Be)
48.8
48.8
ug/L
1
0.249
50
97.5
75
125
Cadmium (Cd)
50.2
50.2
ug/L
1
0.032
50
100
75
125
Chromium (Cr)
51.1
51.1
ug/L
1
0.185
50
101
75
125
Copper (Cu)
53.8
53.8
ug/L
1
0.787
50
99.6
75
125
Lead (Pb)
51.2
51.2
ug/L
1
0.037
50
102
75
125
Nickel (Ni)
50
50
ug/L
1
0.256
50
99.1
75
125
Silver (Ag)
50.2
50.2
ug/L
1
0.035
50
100
75
125
Parent Sample:
J23030262 -- 2023006188
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Beryllium (Be)
50.4
50.4
ug/L
1
0.249
50
101
75
125
3.29
Cadmium (Cd)
51.4
51.4
ug/L
1
0.032
50
103
75
125
2.44
Chromium (Cr)
52
52
ug/L
1
0.185
50
103
75
125
1.77
Copper (Cu)
55.3
55.3
ug/L
1
0.787
50
103
75
125
2.94
Lead (Pb)
52
52
ug/L
1
0.037
50
104
75
125
1.55
Nickel (Ni)
51
51
ug/L
1
0.256
50
101
75
125
1.83
Silver (Ag)
51.6
51.6
ug/L
1
0.035
50
103
75
125
2.85
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 47 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040262 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Beryllium (Be)
0.006
0.006
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.016
0.016
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.042
0.042
ug/L
1
0.185
1
< MDL
Copper (Cu)
0.023
0.023
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.008
0.008
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.014
-0.014
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Beryllium (Be)
49.8
49.8
ug/L
1
0.249
50
99.6
80
120
Cadmium (Cd)
50.2
50.2
ug/L
1
0.032
50
100
80
120
Chromium (Cr)
50.9
50.9
ug/L
1
0.185
50
102
80
120
Copper(Cu)
51.2
51.2
ug/L
1
0.787
50
102
80
120
Lead (Pb)
51.5
51.5
ug/L
1
0.037
50
103
80
120
Nickel (Ni)
50.7
50.7
ug/L
1
0.256
50
101
80
120
Silver (Ag)
50.8
50.8
ug/L
1
0.035
50
102
80
120
Parent Sample:
J23030262 -- 2023006186
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Beryllium (Be)
51.1
51.1
ug/L
1
0.249
50
91
75
125
Cadmium (Cd)
51.1
51.1
ug/L
1
0.032
50
99
75
125
Chromium (Cr)
52
52
ug/L
1
0.185
50
99.1
75
125
Copper (Cu)
159
159
ug/L
1
0.787
50
92.7
75
125
Lead (Pb)
71.1
71.1
ug/L
1
0.037
50
104
75
125
Nickel (Ni)
282
282
ug/L
1
0.256
50
90.1
75
125
Silver (Ag)
50.3
50.3
ug/L
1
0.035
50
100
75
125
Parent Sample:
J23030262 -- 2023006186
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Beryllium (Be)
48
48
ug/L
1
0.249
50
84.9
75
125
6.94
Cadmium (Cd)
51.7
51.7
ug/L
1
0.032
50
97.2
75
125
1.82
Chromium (Cr)
52
52
ug/L
1
0.185
50
92.1
75
125
7.28
Copper (Cu)
161
161
ug/L
1
0.787
50
94.9
75
125
2.42
Lead (Pb)
72
72
ug/L
1
0.037
50
102
75
125
1.77
Nickel (Ni)
283
283
ug/L
1
0.256
50
99.3
75
125
9.75
Silver (Ag)
50.8
50.8
ug/L
1
0.035
50
97
75
125
3.53
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 48 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23050134 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Beryllium (Be)
0.003
0.003
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.006
0.006
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.06
0.06
ug/L
1
0.185
1
< MDL
Copper (Cu)
0.006
0.006
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.001
-0.001
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.028
-0.028
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Beryllium (Be)
49.3
49.3
ug/L
1
0.249
50
98.5
80
120
Cadmium (Cd)
50.6
50.6
ug/L
1
0.032
50
101
80
120
Chromium (Cr)
50.4
50.4
ug/L
1
0.185
50
101
80
120
Copper(Cu)
52.2
52.2
ug/L
1
0.787
50
104
80
120
Lead (Pb)
51.9
51.9
ug/L
1
0.037
50
104
80
120
Nickel (Ni)
51.9
51.9
ug/L
1
0.256
50
104
80
120
Silver(Ag)
54
54
ug/L
1
0.035
50
108
80
120
LCSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD Qualifier
Beryllium (Be)
49.9
49.9
ug/L
1
0.249
50
99.8
80
120
1.28
Cadmium (Cd)
51.2
51.2
ug/L
1
0.032
50
102
80
120
1.12
Chromium (Cr)
50.8
50.8
ug/L
1
0.185
50
102
80
120
0.821
Copper (Cu)
52
52
ug/L
1
0.787
50
104
80
120
0.311
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
80
120
0.479
Nickel (Ni)
51.7
51.7
ug/L
1
0.256
50
103
80
120
0.301
Silver (Ag)
54.1
54.1
ug/L
1
0.035
50
108
80
120
0.217

Certificate of Laboratory Analysis Page 49 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040238 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.036
0.036
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.025
-0.025
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.013
0.013
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.005
0.005
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.021
0.021
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.003
0.003
ug/L
1
0.077
1
< MDL
Copper (Cu)
-0.003
-0.003
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.004
0.004
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.01
0.01
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.02
0.02
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.028
0.028
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0
0
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.009
-0.009
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
51.1
51.1
ug/L
1
0.104
50
102
80
120
Arsenic (As)
51.2
51.2
ug/L
1
0.111
50
102
80
120
Beryllium (Be)
50.4
50.4
ug/L
1
0.249
50
101
80
120
Cadmium (Cd)
50.9
50.9
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
50.5
50.5
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
51.5
51.5
ug/L
1
0.077
50
103
80
120
Copper(Cu)
51.8
51.8
ug/L
1
0.787
50
104
80
120
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
80
120
Molybdenum (Mo)
50
50
ug/L
1
0.18
50
100
80
120
Nickel (Ni)
51.4
51.4
ug/L
1
0.256
50
103
80
120
Selenium (Se)
51
51
ug/L
1
0.193
50
102
80
120
Silver (Ag)
50.5
50.5
ug/L
1
0.035
50
101
80
120
Thallium (TI) Low Level
50.4
50.4
ug/L
1
0.041
50
101
80
120
Vanadium (V) Low Level
50.7
50.7
ug/L
1
0.114
50
101
80
120
MS # 1
Parent Sample:
J23030262
-- 2023006171
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Antimony (Sb)
49.9
49.9
ug/L
1
0.104
50
99.6
75
125
Arsenic (As)
50
50
ug/L
1
0.111
50
100
75
125
Beryllium (Be)
52
52
ug/L
1
0.249
50
104
75
125
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
101
75
125
Chromium (Cr)
51.3
51.3
ug/L
1
0.185
50
102
75
125
Cobalt (Co)
50.6
50.6
ug/L
1
0.077
50
101
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040238 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
51.4
51.4
ug/L
1
0.787
50
Lead (Pb)
51.7
51.7
ug/L
1
0.037
50
Molybdenum (Mo)
49.5
49.5
ug/L
1
0.18
50
Nickel (Ni)
51.4
51.4
ug/L
1
0.256
50
Selenium (Se)
49.9
49.9
ug/L
1
0.193
50
Silver (Ag)
49.6
49.6
ug/L
1
0.035
50
Thallium (TI) Low Level
50.4
50.4
ug/L
1
0.041
50
Vanadium (V) Low Level
51
51
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
50.6
50.6
ug/L
1
0.104
50
Arsenic (As)
51
51
ug/L
1
0.111
50
Beryllium (Be)
52.1
52.1
ug/L
1
0.249
50
Cadmium (Cd)
51.6
51.6
ug/L
1
0.032
50
Chromium (Cr)
51.2
51.2
ug/L
1
0.185
50
Cobalt (Co)
50.8
50.8
ug/L
1
0.077
50
Copper (Cu)
51.7
51.7
ug/L
1
0.787
50
Lead (Pb)
52.5
52.5
ug/L
1
0.037
50
Molybdenum (Mo)
50.1
50.1
ug/L
1
0.18
50
Nickel (Ni)
52.4
52.4
ug/L
1
0.256
50
Selenium (Se)
51.3
51.3
ug/L
1
0.193
50
Silver (Ag)
50.3
50.3
ug/L
1
0.035
50
Thallium (TI) Low Level
50.9
50.9
ug/L
1
0.041
50
Vanadium (V) Low Level
51.4
51.4
ug/L
1
0.114
50
Page 50 of 59
Parent Sample: J23030262 -- 2023006171
% Recovery
LCL
UCL
102
75
125
103
75
125
98.9
75
125
101
75
125
99.8
75
125
99.2
75
125
101
75
125
102
75
125
Parent Sample: J23030262 -- 2023006171
% Recovery
LCL
UCL
RPD
101
75
125
1.44
102
75
125
1.82
104
75
125
0.177
103
75
125
1.66
102
75
125
0.145
101
75
125
0.47
103
75
125
0.722
105
75
125
1.64
100
75
125
1.12
103
75
125
1.93
103
75
125
2.8
101
75
125
1.42
102
75
125
1.06
103
75
125
0.731
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 51 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040263 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.022
0.022
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.011
0.011
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.064
0.064
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.121
0.121
ug/L
1
0.032
1
> MDL
Chromium (Cr)
0.055
0.055
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.154
0.154
ug/L
1
0.077
1
> MDL
Copper (Cu)
0.06
0.06
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.037
0.037
ug/L
1
0.037
1
= MDL
Molybdenum (Mo)
0.014
0.014
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.131
0.131
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.049
0.049
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.019
0.019
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.01
-0.01
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
50.2
50.2
ug/L
1
0.104
50
100
80
120
Arsenic (As)
50.8
50.8
ug/L
1
0.111
50
102
80
120
Beryllium (Be)
50.5
50.5
ug/L
1
0.249
50
101
80
120
Cadmium (Cd)
51
51
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
50.6
50.6
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
50.8
50.8
ug/L
1
0.077
50
102
80
120
Copper (Cu)
50.7
50.7
ug/L
1
0.787
50
101
80
120
Lead (Pb)
51.8
51.8
ug/L
1
0.037
50
104
80
120
Molybdenum (Mo)
50
50
ug/L
1
0.18
50
100
80
120
Nickel (Ni)
51
51
ug/L
1
0.256
50
102
80
120
Selenium (Se)
51
51
ug/L
1
0.193
50
102
80
120
Silver (Ag)
50.5
50.5
ug/L
1
0.035
50
101
80
120
Thallium (TI) Low Level
50.6
50.6
ug/L
1
0.041
50
101
80
120
Vanadium (V) Low Level
50.7
50.7
ug/L
1
0.114
50
101
80
120
MS # 1
Parent Sample:
J23030262
-- 2023006182
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Antimony (Sb)
50.9
50.9
ug/L
1
0.104
50
102
75
125
Arsenic (As)
50.7
50.7
ug/L
1
0.111
50
101
75
125
Beryllium (Be)
50.3
50.3
ug/L
1
0.249
50
100
75
125
Cadmium (Cd)
50.9
50.9
ug/L
1
0.032
50
102
75
125
Chromium (Cr)
52.1
52.1
ug/L
1
0.185
50
102
75
125
Cobalt (Co)
51.6
51.6
ug/L
1
0.077
50
101
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040263 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Copper (Cu)
51.5
51.5
ug/L
1
0.787
50
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
Molybdenum (Mo)
50.1
50.1
ug/L
1
0.18
50
Nickel (Ni)
51.4
51.4
ug/L
1
0.256
50
Selenium (Se)
49.9
49.9
ug/L
1
0.193
50
Silver (Ag)
50.2
50.2
ug/L
1
0.035
50
Thallium (TI) Low Level
50.1
50.1
ug/L
1
0.041
50
Vanadium (V) Low Level
51
51
ug/L
1
0.114
50
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
Antimony (Sb)
50.1
50.1
ug/L
1
0.104
50
Arsenic (As)
50.1
50.1
ug/L
1
0.111
50
Beryllium (Be)
51.2
51.2
ug/L
1
0.249
50
Cadmium (Cd)
50.6
50.6
ug/L
1
0.032
50
Chromium (Cr)
51.2
51.2
ug/L
1
0.185
50
Cobalt (Co)
50.6
50.6
ug/L
1
0.077
50
Copper (Cu)
50.8
50.8
ug/L
1
0.787
50
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
Molybdenum (Mo)
49.7
49.7
ug/L
1
0.18
50
Nickel (Ni)
50.4
50.4
ug/L
1
0.256
50
Selenium (Se)
48.7
48.7
ug/L
1
0.193
50
Silver (Ag)
49.8
49.8
ug/L
1
0.035
50
Thallium (TI) Low Level
50.1
50.1
ug/L
1
0.041
50
Vanadium (V) Low Level
50.3
50.3
ug/L
1
0.114
50
Page 52 of 59
Parent Sample: J23030262 -- 2023006182
% Recovery
LCL
UCL
102
75
125
104
75
125
100
75
125
101
75
125
99.5
75
125
100
75
125
100
75
125
102
75
125
Parent Sample: J23030262 -- 2023006182
% Recovery
LCL
UCL
RPD
100
75
125
1.6
100
75
125
1.28
102
75
125
1.79
101
75
125
0.621
100
75
125
1.72
99.4
75
125
1.97
101
75
125
1.4
103
75
125
1.2
99.2
75
125
0.801
99.6
75
125
1.81
97.2
75
125
2.43
99.6
75
125
0.778
100
75
125
0.0699
100
75
125
1.26
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 53 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040226 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 0
Parameter Measured Final
TDS 0
Duplicate # 1
Parameter Measured Final
TDS 269
Duplicate # 2
Parameter Measured Final
TDS 787
LCS # 1
LCS # 2
Parameter Measured Final
TDS 498
Parameter Measured Final
TDS 493
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23030049 -- 2023005258
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
2.26
Parent Sample:
J23040325 -- 2023009355
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.79
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
99.6
90
110
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.6
90
110

Certificate of Laboratory Analysis Page 54 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040257 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 0.1
Parameter Measured Final
TDS 0
Duplicate # 1
Parameter Measured Final
TDS 59
Duplicate # 2
Parameter Measured Final
TDS 398
LCS # 1
LCS # 2
Parameter Measured Final
TDS 494
Parameter Measured Final
TDS 490
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23030262 -- 2023006180
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
3.33
Parent Sample:
J23040350 -- 2023009489
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.8
90
110
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98
90
110

Certificate of Laboratory Analysis Page 55 of 59
This report shall not be reproduced, except in full.
Order # J23030262
Level II QC Summary
Q23040298 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Blank # 2
Parameter Measured Final
TDS 0
Parameter Measured Final
TDS 0
Duplicate # 1
Parameter Measured Final
TDS 315
Duplicate # 2
Parameter Measured Final
TDS 612
LCS # 1
LCS # 2
Parameter Measured Final
TDS 494
Parameter Measured Final
TDS 491
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
mg/L
1
25
25
< MDL
Parent Sample:
J23040374 -- 2023009581
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
1.57
Parent Sample:
J23040376 -- 2023009597
Units
Dil
MDL
RPD
Qualifier
mg/L
1
25
6.48
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.8
90
110
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
mg/L
1
25
500
98.2
90
110

CHAIN OF CUSTODY RECORD AND ANALYSIS REGUEST FORM
Page 56 of 59
Duke Energyli
DUKE MW c� moo jeaw" TON Order ill J 2303026 2
AnWical Laboratory Use Only
trial WATER
NG-Yl
Esc—
Page I of
'N" K". �ry �
H.M.-ak, N.
ENERGY, -- ­ -
17a
-110-."%. ft.
_2
1 DISTRIBUTION
purl r"M
!L-0--,
Thra
SAMPLE PROGRAM
ORIGANAL to LAB, COPY to CUENT
PmJ@Ct Name ROGERS CUFFSIDE CCP
w-dor
Ground Water X
Drinking Wafer
NPDES—
UST
,—
LANDFILL PER M ITO 61.06
t
RCRAWaste
Revised 3.1
Csient. BILL WYLIERYAN CZOP.
i
.... .....
—
EILYA�MOELLER, DEE 0? RIEN. JOSH STOWE
i Filtration (0.46 unl)
Unfiltered
Filtered
d
Operating LP nit: CSN PrPc*ss:NGRDWTR Account;
5
Preservatfye
ICE
ICE
Project: ACS56ONZ Activity ID: Faclifty ID: CLS
MT SWT
------
Container me lmL)
5:10
300
500
250
I EQ-i$ Teak Code: CLS Sub-Pmgr*mrrask Code:
1Program
; 7 M I
Cdnkairrer Type
HOPE
PET
PET
OPE
M ..'S
a
Metals Prep - TRM) I
Cl, F,
SING0100
12
Ctestompr to
cowpM� all app�priate nb—hade.d
IGP - SW SDI ODI ft.
8, '::a. Fe. Li, Mg. Mo.
NO3-N
ZnISW
--""-"'-""-"'-'"—'"3SOMP 10 D"cri pbOn o r I D
Zn 1611 Mg {SW 7470A}
(48,Hr
Hold
TDS
602o Be,
BC
Cd
i SAMPLE 10
coaecUon Information
t {IMS - sw 6020B} Sb,
Time).
C.: Pb.
i NUMBER
As, Be. Cd, Cr, Co
Pb, Mg. NI, s .. �g. Cu,I
SO4
Ni, Ag
Dim
Time
Printed Name
slanaturs tS7
TI(LLj, V 114
21523006170 j
C[S_CCIRMWAS
3
i 2023006171 i
CLS CCPM1W-1 D
qF15 ZA4
IN
-tt- bkm
x
3
L2023006172
CLS-CCPMW-25
F(7Tw Z
woo
mo ALM
202300611731
CU5-CCPWIN-2D
......
3
2OZ3MI74
ebRZQGRMVV48 -XAPS VOL
3
20230061176
CLS�-CCPMIN3D
Vrr S-TZ—M3
100
Zth E HfA
-3W
3
202308176
CLS CCPMW-4
NIETZ4
�ftz
x
3
2023006177
CLS CCPMW-6
U414k,&I
2023006178
CL5�_CCPMW-SS
4118*3
1400
3-31- Ntwvl
x
2023006179
CLS CCPMW-fiD
L
x
1
1
1
3
L2023006180 f
13,66-GOP1111011
x
1
1
1
3
12023006191
x
3
i
20230D6182
ClUt-LAW.3o
x
r2023006183 iI
eh&-CMW�.,
x
3
f 20230061"
3
20230061U 1
i
x
1
1
1
1
4
I
i2023006196 I
sks 96P hmem
x
4
R.HrIcillilbed By
I DO-M
etan,
AC d SYL
ZAZ�-
V
Requested Turnaround
,Z-2c,
N1 ?,3'('_& 1
5—
711
.,a
Relinquished By OaLaTims
Accepted By: Bedell
V
4- P
21 Days
Relinquished By DaftiTtmt
Accepted BY 081*7kne
14 Days
SeAVL..Imd By Dalell-mine
Saaled&m; Opened By DiftarrTme
5-E
'7 Days
a
Comments
Regulatory Agency!
NCDENrWDWm - SW Section
EQUIS REQUIRED? PERMIT # 81-0s f Include Total Hardness
for rCP-Le+chat, and CCP-Leachate-34
F
Other
Add. Cost Will Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 57 of 59
DUKE Dak■ En■rgy AnayMed u6oratnry - ;----------wA
ul a0r i i i Order 0 J 23030262
__..:ea r -�� one__--------'--
Malrk>< WATER
- -- -
nlC
-'-' .
i Pape _2_of 2
H iL >sn■
ENERGY. ""`"""'�"t"`
�w.. uaM.mvr.v_
DWRIBUt1oN-
i ILp�d
Pal totEra
FY�B�>I?!�a �
``11
y
r1"3.-
SAMPLE PROGRAM
ORIGINA410 LAB, COPY to CLIENT
l
----- .......... ... ............ _._------- _._._.__._i
Prgeet N>tme ROGER5 CLJFFSIOE CCP Plwr rv_ �UOndO`
LANDFILL PERM IT* 81-06 i
Client BILL WYLIE,RYAN CIOP, ippa
caetrr re
,.._.._.._..._.._. _.._.._..
Ground Watery
9nPkirig Water -
RCRA Wuele
_.._.._._.._.._.._.._._.._.._.._.._.._.._.--..--._.._.._._...-__.._
NPDES,�
UST —
—-
lrviseti
2023 R3-t0 ,
BRYAN MOELLER, DEE O-BRIEN, .POSH STOWS
k Filtration (OA5 um)
a
Unfiltered
0 Fiftered
Operating Unit CSM Pree■--:NBRDWTR Account
i Preservative
ICE
ICE HNO7
ProleaL, ACS660062 Activity io: Fag ilky 10: CLS
Container Volume (a1L)
Soo
300
500 500
Pngram 7 EOuiS Task Coda: CL3 Sub-ProgramlTask Code,
Container Type
HOPE
PET
PET HOPE
CCP7LFI
(Mows Prep -TRM) f
Cf, F,
C.1 �:omv�
fn cvmr.•1am an.nar�drlx[e
morn hadW arnos- q
11 CP - SW 6010o1 e., B,
Ca, Fe, Li, Mg, Mn, In
NO3-N
(48-lir
S~10D 2.n 1
SW 60208 Be.
................. � Sample Description or ID
Hnid
TDS Cd, CV, Cu, Pb,
Collection lnrvrmwlon
(IMSHSW 6W20Bj Shf,
Time],
NJ, Ad
a
SAMPLEID
!
C Ce,Cu,
ps, Be. Cd, r,
504
NUMBER
n
Pb, Me, W, Sa, Ag,
e
i i Data
Tkne
PrInt■d Noma
S tun U 0
TI 44 V ,i
~
•. 2023006187':
CLS_CCPSW-1
f000
x
,
1
1
i
4
i 2023006188 5
CLS_CCPSW-2
4 18104
0940
P1Mg
SPW
iy'. j
x
1
1
t
,
4
2023006189
CLS_CCPSwJ
4 ! "5
1pLS
-•
t-^
x
1
1
1
,
s
i 20
CW^_FD-4OLlPgII 1
K 1/1011
lo3o
SC,41
EHk
x
1
1
,
3
2023006191
CLS_F8-L0L30418-1300
411
130o
RMB
3
202 0630 19 '2
CLS_CCR-CCPBG-iD
4 i$ k93
} 3 LT
-'C-.M
F HM
x
1
,
,
3
! 2023MI93
CLS_CCR-CCPBG-1BR
r{ is jyt3
17,3o
3-QA%
t
1
1
3
M30p6194
666_FG
X1
I
r�
i
I i
i
I i
i
I
I i
! 1
i
1 1
1
R*Rnqulshod By
- - - H - rrkna
ll
Acce end B
D7
2
10
Requested Turnaround
IAI�
RNl"ulsked By ■
Ascopbd ey: Det■Jrkn■
m a
21 hays
^ e
ReOngdkmd By OwRim■
Acc■pt■d By: DaMfrkm
,d trays +L_
1n 3
•7
SealfLocWl By DaIrlTima
SUIedil-ock Opdk■d 6y
E
E
s
ra
Days
'Other
• Add- Cos! Will Apply
Comments
Regulatory Agency: NCDENRIDWm - SW Section EOUIS REQUIRED I PER MIT4 81.06 Include Total Hardness for CCPSVY-1.CCPSIM-2, CCPSW-3

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 58 of 59
. _ .... _ _.. Duke Erwrgy Arwtytkal Labaratary _� .— .�^.--�..�-w�� _^-.•-... — iral G-boratory Use Only
!Ordr#J23030262 Matrix WATER
-W.M tolR' ;ea--- -6�
C. "WR ILoedBy
lnsls�e-ax�a SAMPLE PROGRAM
Ground Water x NPDES
project Name ROGFRS CLSFFSIDE CCP Phi A1°r _ 'Verder Drinking Wafer,___ us7
LANDFILL PERM rM 81-06 RCRA Wafee
• Ceeler 7emP1�1..._..._.._.._.Y.._.Y.._._.._._._.._.._.._.._.._. .. _.._.
Client BILL WYUE,RYAN CLOP, PO!
BRYAN MOELLER, DEE O'BRIEN, JOSH STOWE Filtration (OAS um) 4 Unfiltered
Operating Unit: CS66 Process:NGRDWTR Account: _ Preservative ICE
Project ACSSSM2 Activity �$ vity ID: Fac6dy i0: CLS � Container Volume (mL) Soo 300
7
rogram I EQWS Tank Cods: CLS Sub-Programrrask Code: Container Type XOPe PET
CP1LF
w❑
r (Metals Prep • TRM)1 CI, F,
Co5ro-w t0 sompilete eil approipriale 6Ml hadad 2r s. J IICP - $W 6010DI Ea, NO3-N
B. Ca, Fe, Li, Mg. Piro, {48-Hr
- - -- �— Sample Description or ID Zn IaY Ng (sw �4TOAl Hord
Callacdon Irdarmatlon I (IMS - SW 60m) so, Timed,
SAMPLE ID As, Be, Cd, Cr, Co, Cu.Ni
NVMBETt Pb. Mo. Nl, Se, Ag, 304Data Time Printed Name Si nature TI LL V it
I.t.s
{
10E
SOO
PET
TDS
_1_ of 2_
aDUKEPage
DISTRIBUTION
ORIGINAL to LA9, COPY to CLIENT
b Filtered
2SO
HDPE
SW80,pp
Zn i SW
SOMB Be.
Cd, CF,
Cu, Pb,
Ag
@
c
o
0
f
i 2023006 Q
%
1
1
1
3
i 2023M171 i
i_
GuteePMaRi-=
x
1
1
1
3
1 2023006172 ;
CIt89PA4M1-i6
x
1
1
,
3
2023006173
OW)= ?MW.7p
x
1
t
,
3
2023006174
6i6C&PMW-9S
x
1
1
1
3
2023006175
0!�_BBPhANi-89
,
3
12023006176 ;
x
1
1
1
3
I
20230061"
Bh_6APM"
x
1
1
1
3
i 2D23006178 i
516-�
%
+
t
1
s
i —�
120230MITS !
B t):41 +1rf-0D
x
t
1
1
3
•. 2023006180
CLS_CCPMW-7
q11,143
I03o
/VA,4
x
1
7
1
3
202300,6181 '
9kFT,CSPMW4L .% wvL
x
,
,
,
3
2023006182
CLS_CCPMW-10
41 t3
p7.Y
3-c^ EWA
x
+
+
+
3
2023006183Ii'i
CLS_CCPMw-11
1 43
1330
�-Z�'1A
�� �
x
t
,
+
3
2023006194 ;
M-96�w-x xrvs rwL
x
,
,
,
3
2023006186 i
CLS_CCP-LEACHATE
1Y L3
d4�f0
�� ��1�1
x
1
7
7
7
i
20230061861
CLS_CCP-LEACHATE-34
ogsv
3-1z7 bj ,R
1
4
I
Relinquished By
jVV
1111- oata7rrne
ALCeBy: r�� Dal
�i`�-W .rCr
Requested Turnaround
g
Relinquished By Daterriime
Amapted By: Gault kne
9
c
m 3
c Q
21 Days
Relinquished By Date7Tdne
AccepLd By: DalelTma
c
v
14 Days x
aVt-ocked By Date✓riime
Sealedit mk Opened By Dataffi11e
'7 pays
E n
_ m
Comments
Regulatory Agency: NCDENPJDWm - SW Section
EQUIS REQUIRED I PERMIT A 81-0 1 Incf ude Total Hardness for CCP-Leac hate and CCP-L-aachate-3n
E
'Other
•Add. Cast WIl Apply
V

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 59 of 59
DUKE Dube Enrgy AnslyNcsl Lahoruory . i i
mil r0"M I��T" i iprq.r0 J23030262
Am— — La6araso Va On -•-..'._._.-._ ._._._._._._._._.�._'_—'—_•—_'_'_'_'-------
Metric WATER Ncx
;
Page 2� of T2_
ENERGY. I� H.D-F.rym i i
tnlaser*µk N- °nm
"""°"`""""" Wr
4
DISTRIBUTION
! .Lopped By
I._._._._._._._._._._._._ --- --- -_._._.___1n!3L.____._i I
rlerr tree
a IJnr��
/�
SAMPLE PRAM
Ground 4Vatar �x•, NPDES ___•
I
ORIGINAL to LAB. COPY to CLIENT
- ..-.—.-�---
Proiaet Name ROGERS CLIFFSIDE CCP ��"dO'
LANDFILL PERM ITS 91.06 i
l
CooNr Tam
Drinking water UST_
- RCRA yam_
Revised 3.1D•PD23
Client BILL WYUE,RYAN C7_OP, ipos
BRYAN MOELLER, DEE IYORIEN, JOSH STOWE
Fittra0ort;0.45 um}
0 Unfiltered
1} Filtered
OparNing Unit CS'R Prxess;NGROwrR Account: 1
i
-
} Preservative
ICE
ICE IHN00
Project: ACS560p6Z Ac6ft 1D: Fmillry to,. CLS
C onlainer Vol me
500
300
500TEST
500
W
Program I EquiS Task Code: CLS I Sup.Prog-rrdl- si Code;
CCP7LF
Container Type
HOPE
PET
PET
HOPE
rl-wh
(M etals Prep-TRMII
Cl, F,
Customer
to cdmplere aff apprvprlare norr-shaded""&
(ICP - SW Sol Do) Sa, B,
Ca, Fa, Li, Mg, Mn, Zn
NO3-N
Sw6010D 2,n 1
— - --- --� Sample Description or ID
(Blf Hg (SW74TOAI7
{48-tir
Hold
TDS
Sri66208Be.
Cd, Cc Cu. Pb,
i BANPLER I
r
Collection Information
Tn
IIM8-SW 60208)S6,
As, Ba, Cd, Cr, Co, Cu.
Tlme],
Ni, A9
c7
Y
NUMBER
P6, Me. Ni, Se, Ag.Dace
Time
Panted Name 8 nsturs
LL V 4141~
2023006157
GLS=cc+isYri+•
x
1
1
1
,
a
i 2023ON188 a
BE9=e6PeW-2
x
1
i
1
1
4
2023006189
0
x
1
1
1
1
4
�r
i 20230N19D
QL6 f9
x
1
1
1
3
2023ON191
91-F9
x
1
1
1
3
1 2023006192 1,
x
1
1
1
3
202300B193!
x
1
4
1
3
2023006194 !
CLS_FD -UL�Oq VT - f
t l fi q
-
s
x
1
1
1
r
cl s �8-7.�L3v�fta- 0140
0440
gQ i'S'D
g
L
1
1
i
i
i
i
j
i
Relinquished By
t
B
f.A
Daterr
1.
Em
c
Requested Turnaround4f
ReFrpuishesy Damrtnb
Acceptedg]': DarafTisx
a a
21 Days
'EL 2
Raknquistrad By DatNrme
Acmpted W DamfTine
-• E
e Y
If
14 Days x
SeaVLocked By Drtelrrrne
Sealeditock opened BY DateTme
0 E
'7 Days
E'm
Comments
Regulatory Agency:
NCO EN RfDWm - SW Section EQUI6 REQUIRED 7 PERM IT 81•06 Include Total Hardness for CC P5W-1,CCPSW-2, CCPSW-3
°
c�
�OOier
'Add Cost Will Apply