25087-21-092 Hammond CenterDr VI Assessment

AkUNITED
CONSULTING
REPORT
For NCDEQ Vapor Intrusion Assessment Report
Hammond Center Drive Site
Raleigh, Wake County,
North Carolina
NCBP# 25087-21-092

UNITED
CONSULTING
September 28, 2022
North Carolina Department of Environmental Quality
Division of Waste Management — Brownfields Program
1646 Mail Service Center
Raleigh, North Carolina 27699
Via Email: shristi.shrestha(a)ncdenr.gov; sharon.eckard(a-)ncdenr.gov
RE: Vapor Intrusion Assessment Report
Hammond Center Drive Site
100 Knowles Street
Raleigh, Wake County, North Carolina
Brownfields Project Number 25087-21-092
Dear Ms. Shrestha:
Vapor Intrusion Work Plan
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
United Consulting is pleased to submit this Vapor Intrusion Assessment Report on behalf of Maple Multi -
Family Land SE, LP (Prospective Developer) for the above referenced Brownfields property (herein
referred to as the "Site"). The purpose of this assessment was to further assess the potential risks for
vapor intrusion in the proposed development areas of the Site. Please contact us if you have any
questions or if we can be of further assistance.
United Consulting Group, Ltd is licensed to practice geology and engi
associated certification numbers of C-344 and C-1847, respectively.
r�
z
UNITED CONSULTING
�r _
Britton Bicker taff, LM
Senior Environmental Specialist
bbickerstaff(a)-unitedconsulting.com
Developer Contacts:
Mark Mathews — mmathews(aD-tcr.com
Sean Allen — sallen(a-)-tcr.com
Ctd&4,h Carolina, with
RusE-ell C Griebel, P ELL G
Executive Vice President/Chle C<
rgriebel(a�unitedconsulting.com
L
nsultant
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UNITED
CONSULTING
TABLE OF CONTENTS
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 3 of 9
1.0 INTRODUCTION..................................................................................................................4
2.0 SOIL GAS SAMPLING SCOPE............................................................................................6
3.0 EXTERIOR SOIL GAS SAMPLING.......................................................................................7
4.0 LABORATORY ANALYTICAL RESULTS.............................................................................8
5.0 CONCLUSIONS...................................................................................................................9
FIGURES
Figure 1 Topographic Map
Figure 2 Soil Gas Sampling Locations (Development Plan)
Figure 3 Soil Gas Sampling Locations (Aerial Photograph)
TABLES
Table 1 Summary of Soil Gas Analytical Results — Detections Only
APPENDICES
Appendix A DEQ Risk Calculator VISL Calculation Worksheets
Appendix B Chain of Custody/Laboratory Analytical Testing Data
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CONSULTING
1.0 INTRODUCTION
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 4 of 9
The Site consists of an approximate 35.77-acre parcel, Parcel ID 1702760750 with the referenced
address of 100 Knowles Street, Raleigh, Wake County, North Carolina. The Site was recently accepted
into the North Carolina Brownfields program and assigned Project No. 25087-21-092. The Site has
historically been undeveloped land and is currently undeveloped and vacant. A stream, Wildcat Branch,
is located on the eastern portion of the property which flows to the north. The Prospective Developer is
proposing to develop the Site with a multifamily apartment community which will consist of three multi-
story apartment buildings and a clubhouse. The buildings will be slab -on -grade with shallow foundations.
The proposed development is located on the western portion of the property, west of Wildcat Branch
creek. A site location/USGS topographic map is included as Figure 1.
Multiple subsurface investigations have been conducted at the Site to assess for impacts from the eastern
adjoining Raleigh Metals facility, as well as the northern adjoining Evergreen Packaging facility. Of note,
the groundwater sample previously collected from temporary monitoring well UCMW-2 in May of 2021
(collected from the eastern portion of the Site, across Wildcat Branch creek from the proposed
development area of the Site) identified tetrachloroethene at an estimated concentration of 2 micrograms
per liter (pg/L), which was below the residential and industrial DEQ Division of Waste Management
(DWM) Vapor Intrusion Groundwater Screening Level (GWSL) but above the DEQ 2L Standard.
Trichloroethene was also detected at an estimated concentration of 1.6 pg/L in UCMW-2, which was
below the DEQ 2L Standard and industrial GWSL, but above the residential GWSL. A low concentration
of cis-1,2-dichloroethene was also reported in the groundwater sample collected from UCMW-2 at that
time, which was below its DEQ 2L Standard and respective GWSLs.
No other volatiles were reported in the remaining groundwater samples collected from the Site at that
time or during our subsequent investigation conducted on the Site in October of 2021, which generally
included sampling locations across the Site. Based on the overall data, groundwater impacts detected
at the Site appear to be isolated to the eastern portion of the property, on the east side Wildcat Branch
creek and appear to have migrated onto the Site from the eastern adjoining Raleigh Metals facility.
Further, it appears that Wildcat Branch creek has created a hydraulic barrier at the Site as no groundwater
impacts have been detected west of the creek.
No soil impacts have been detected at the Site in excess of their respective residential Preliminary Soil
Remediation Goals (PSRGs), with exception of arsenic and hexavalent chromium. The detected arsenic
concentrations are consistent with published, naturally occurring background concentrations in the area.
No known source for the hexavalent chromium has been identified on the Site or adjoining properties.
The hexavalent chromium has been delineated and is proposed to be remediated from the Site.
Six soil gas samples were previously collected from the approximate footprints of the proposed buildings
and submitted for analysis of volatile organic compounds (VOCs) via EPA Method TO-15. Evaluation of
the soil gas data did not indicate further assessment or mitigation was warranted, in United Consulting's
opinion. All of the above data has been submitted to NCDEQ within previous reports.
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CONSULTING
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 5 of 9
Based on communications with NCDEQ Brownfields staff, NCDEQ questioned the integrity of the
previous soil gas samples, and such was therefore considered a Brownfields assessment data gap and
additional soil gas testing was required. United Consulting subsequently produced and submitted a
Vapor Intrusion Work Plan, report dated July 26, 2022, which was conditionally approved by the NCDEQ
Brownfields Program on August 3, 2022, with a revised version of the Work Plan officially approved on
August 29, 2022. United Consulting conducted this Vapor Intrusion Assessment in accordance with the
approved Vapor Intrusion Vapor Intrusion Work Plan.
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CONSULTING
2.0 SOIL GAS SAMPLING SCOPE
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 6 of 9
This soil gas sampling scope was developed in accordance with the North Carolina Division of Waste
Management (NCDWM) VI Guidance (March 2018), the NCDEQ Brownfields Program Vapor Intrusion
Assessment Workplan & Checklist (updated March 2022) and the Interstate Technical and Regulatory
Council's Vapor Intrusion: A Practical Guideline (2007) and Vapor Intrusion Pathway: Approaches for
Typical Scenarios (2007).
The scope of work generally included collecting ten exterior soil gas samples from the Site, including six
soil gas samples from within the footprint of the three proposed multifamily buildings, two per building
footprint, with one being collected from the approximate area of the proposed elevator locations. These
were designated UCSV-131 through UCSV-B6. Three exterior soil gas samples were also collected from
the locations of proposed utility corridors leading into the proposed development portion of the Site.
These were designated UCSV-U1 through UCSV-U3. One duplicate soil gas sample was also proposed
to be collected for QA/QC purposes but was not obtained.
The sampling locations are illustrated on Figures 2 and 3.
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3.0 EXTERIOR SOIL GAS SAMPLING
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 7 of 9
At each sampling location, a dedicated gas vapor probe tip with new dedicated tubing was attached to a
post -run tubing rod and driven to the sampling depth of 3 feet below the ground surface (bgs) using a
slide hammer. The sampler was then be opened by retracting the gas vapor probe extension rod by
approximately one inch. The samplers were left to equilibrate with the subsurface for a minimum of two
hours prior to sampling. Of note, recent geotechnical investigations at the Site indicate that groundwater
in the general area of the proposed buildings ranges from approximately 3 to 5.5 feet bgs, specifically in
the areas of Buildings 3 and 4 (the northernmost proposed buildings). Groundwater was not encountered
during the installation or sampling activities.
To test the viability of the sampling train and the vapor sampling point seals, a shut-in test and a helium
tracer test was performed at each sampling point. The shut-in test was conducted by attaching the
laboratory -supplied Summa canister and flow controller manifold to be used at each point to Teflon lined
tubing and a syringe. The syringe was used to create a vacuum within the flow controller manifold, at
which point, the manifold's shut-off valve was closed. The Summa canister and manifold were allowed to
sit sealed from the atmosphere for a minimum of five minutes and the pressure within the manifold at the
beginning and the end of the shut-in period was observed to assure that there was no loss of pressure
during the shut-in test period.
The tracer gas serves as a quality assurance/quality control (QA/QC) method to verify the integrity of the
soil vapor probe seal. The protocol for using a tracer gas is to enclose the tubing and ground interface
with a shroud and enrich the shroud atmosphere with helium (typically to approximately 15%). Three
volumes of the vapor point annulus and attached Teflon lined tubing were purged. The purge samples
were field -screened for helium after each purge volume to assess for the presence of leaks in the seal
and fittings using an MGD-2002 helium/hydrogen meter. Sample collection was conducted once the
tracer testing indicated helium concentrations in the vapor point were less than 10 percent of the helium
concentration in the shroud, indicating a sealed vapor point annulus.
Post purging activities, the soil gas samples were collected in a laboratory supplied, batch -certified 1-liter
Summa canisters with a flow controller set for to draw air at less than 200 milliliters per minute (mL/min).
The vacuum pressure of the sample canister was monitored and recorded at regular intervals throughout
the sampling period. United Consulting ceased sample collection prior to the vacuum pressure reaching
negative 5 inches mercury (residual vacuum).
Following completion of the sampling activities, the Summa canisters, along with chain -of -custody
documentation, were shipped to Eurofins Air Toxics for laboratory analysis of volatile organic compounds
(VOCs) by EPA Method TO-15.
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4.0 LABORATORY ANALYTICAL RESULTS
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 8 of 9
The soil gas analysis showed the presence of petroleum and solvent constituents and other chemicals
in the samples. The results were compared to the NCDEQ Division of Waste Management (DWM)
Residential Vapor Intrusion Sub -Slab and Exterior Soil Gas Screening Levels (SGSLs), dated July 2022.
Trichloroethene (TCE) was detected in the samples collected from UCSV-U1 and UCSV-B1 at
concentrations of 39 and 38 micrograms per cubic meter (pg/m3), which is above its residential SGSL of
14 pg/m3. No other constituents were identified at concentrations in excess of their SGSLs with exception
of 1,3-butadine, which was reported at 20 dig/m3, above its residential SGSL of 3.1 dig/m3.
Due to the SGSL exceedances, United Consulting utilized the NCDEQ Risk Calculator under a residential
and non-residential setting to further evaluate potential cumulative risks for vapor intrusion for the
proposed buildings. The cumulative risk was calculated using the highest concentration of each
constituent detected in the nine soil gas samples collected from the Site to model potential vapor intrusion
risk under a "worst case scenario."
The residential risk calculator determined a carcinogenic risk of 1.0E-05 and a hazard index of 0.86. The
non-residential risk calculator identified a carcinogenic risk of 7.3E-07 and a hazard index of 0.069, which
are both below the DWM screening/corrective action threshold of 1.0E-4 and a hazard index of 1.0. Based
on the Risk Calculator results, no residential or non-residential risk levels were exceeded.
The sampling locations are illustrated on Figures 2 and 3. Table 1 summarizes the soil vapor sample
analytical results. The DEQ Risk Calculator for the Site is included as Appendix A. Analytical data is
included in Appendix B.
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CONSULTING
5.0 CONCLUSIONS
Vapor Intrusion Assessment
Hammond Center Drive Site
Raleigh, Wake County, North Carolina
TMCRW-22-NC-05273-05
Page 9 of 9
Relatively low concentrations of petroleum and solvent constituents and other chemicals were identified
in the nine soil gas samples collected from the Site. TCE was reported above its residential SGSL in two
of the samples and 1,3-butadine was reported above its residential SGSL in one sample. However, the
NCDEQ Risk Calculator output indicates that the current concentrations do not pose a significant health
risk to future residential or non-residential uses at the Site as the calculated risks were below DWM
corrective action thresholds. As such, the results of this assessment should not warrant further
investigations or mitigation at this time.
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FIGURES
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UNITED N 0 500 1,000 Checked: BNB Project: Hammond Center Drive Site FIG.
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CONSULTING 1 inch = 750 feet Project No. 22-NC-05273-05
Date: 7/16/22 Client: Maple Multi -Family Land SE, LP

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UNITED
CONSULTING
625 Holcomb Bridge Road, Norcross, Georgia 30071
770-209-0029 Fax [phone] www.unitedconsulting.com
Project:
Hammond Center Drive Site
Client:
Maple Multi -Family Land SE, LP
Sheet Soil Gas Sampling Locations
Title: (Development Plan)
Scale: 0 25 50 100
1 inch = 100 feet
Prepared: S. Cox
Checked: B. Bickerstaff
Date: September 27, 2022
Project No. 22-NC-05273-05
Figure 2
A

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Sample Locations
UCSV-B2 UCSV-B4 UCSV-B6
0 = w— -
UCSV-U1 r y UCSV-U2 UCSV-U3
.+
• UNITED
CONSULTING
• i �/ 625 Holcomb Bridge Road, Norcross, Georgia 30071
770-209-0029 Fax [phone] www.unitedconsulting.com
• `�; i� :� . + +y. w Project:
• ti `� f+i�r' s I r , ��i Hammond Center Drive Site
s;
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At
' ; • Sheet Soil Gas Sampling Locations
v• 1 . �,' • • +,, Title: (Aerial Photograph)
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• 1 �
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is � � �•• y wo �' � _
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Checked: B. Bickerstaff
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+, 75,
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Figure 3
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TABLES
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TABLE 1: SUMMARY OF SOIL GAS ANALYTICAL RESULTS - DETECTIONS ONLY
' LiUCSV-U2 UCSV-U3 UCSV-B1
UCSV-62
r r
UCSV-B3 UCSV-B4 UCSV-B5 UCSV-B6
Volatile Organic Compounds in Air by TO-15 (VOCs) µg/m3
1,2,4-Trimethyl benzene
420
2.5 J
2.6 J
ND
3.6J
3.0 J
ND
ND
ND
ND
1,3,5-Trimethylbenzene
420
ND
ND
2.5 J
3.1 J
ND
ND
ND
ND
1,3-Butadine
3.1
2.0 J
20
ND
ND
ND
ND
ND
ND
ND
2-Butanone (methyl ethyl ketone)
35,000
25
22
5.8 J
15
8.4 J
ND
5.9 J
12 J
8.4 J
2-Proponal
1,400
40
14
11
75
14
5.9 J
7.7 J
15
13
4-Ethyltoluene
NE
1.8 J
ND
ND
ND
ND
ND
ND
ND
ND
4-Meth I-2-pentanone
21000
5.9
1.4 J
ND
2.4 J
1.4 J
18 J
ND
1.7 J
ND
Acetone
NE
310
160
58
120
26
ND
33
110
70
Benzene
12
2.6 J
5.8
1.5 J
NE
ND
ND
ND
3.5 J
1.2 J
Carbon Disulfide
4,900
7.3 J
5.1 J
ND
6.6 J
ND
12 J
5.6 J
5.6 J
Chloroform
4.1
ND
ND
3.0 J
3.8 J
ND
ND
ND
ND
3.0 J
Ethanol
NE
17 J
ND
ND
38
35
ND
ND
ND
24
Freon 12
NE
2.7J
2.8J
2.5J
4.2J
2.5J
3.0J
2.3J
2.6J
2.8J
Freon 113
NE
ND
ND
ND
2.2 J
ND
ND
ND
ND
ND
Heptane
2,800
ND
3.3 J
ND
ND
ND
ND
ND
ND
ND
Hexane
470
2.1 J
2.9 J
ND
ND
ND
ND
ND
ND
ND
Styrene
700
ND
69
ND
ND
ND
ND
ND
ND
ND
Tetrachloroethene
280
3.8 J
ND
ND
2.9 J
ND
ND
ND
ND
3.7 J
Toluene
3500
3.8 J
5.8
ND
ND
1.3 J
0.91 J
ND
1.9 J
ND
Trichloroethene
14
39
ND
ND
38
ND
ND
ND
ND
ND
X lenes
700
1.8 J
1.6 J
ND
ND
1.4
1 ND
ND
ND
ND
Notes:
xx - Exceeds North Carolina Department of Environmental Quality (DEQ) Vapor Intrusion Sub -Slab & Exterior Soil Gas Screening Levels (SGSLs) dated July 2022
NE - Not established
ND - Constituient not detected above the laboratory method detection limit (ND)
J - Estimated concentration detected between the laboratory method detection limit and reporting limit

APPENDIX A
DEQ Risk Calculator VISL Calculation Worksheets
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North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
July 2022
Basis:
May 2022 EPA RSL Table
Site Name:
Hammond Center Drive Site
Site Address:
100 Knowles Street
DEQ Section:
Division of Waste Management - Brownsfields Program
Site ID:
25087-21-092
Exposure Unit ID:
Site Wide Soil Gas - Hypothetical Worst Case
Submittal Date:
Prepared B.
Britton N. Bickerstaff, CHMM
Reviewed By:
Russell C. Griebel, P.G.
North Carolina DEQ Risk Calculator

Table of Contents
1
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID:
Site Wide Soil Gas - Hypothetical Worst Case
Form No.
Description
Check box
if included
DATA INPUT SHEETS
Input Section 1 - Exposure Pathways & Parameters
Input Form IA
Complete Exposure Pathways
0
Input Form 1B
Exposure Factors and Target Risks
0
Input Form I
Contaminant Migration Parameters
❑
Input Form 1D
Sample Statistics
❑
Input Section 2 - Exposure Point Concentrations
Input Form 2A
Soil Exposure Point Concentration Table
❑
Input Form 2B
Groundwater Exposure Point Concentration Table
❑
Input Form 2C
Surface Water Exposure Point Concentration Table
❑
Input Form 2D
Soil Gas Exposure Point Concentration Table
0
In ut Form 2E
Indoor Air Exposure Point Concentration Table
❑
DATA OUTPUT SHEETS
Output Section 1 - Summary Output for All Calculators
Output Form lA
Risk for Individual Pathways
0
Output Form 1B
Sitewide Risk
El
Output Section 2 - Direct Contact Soil and Groundwater Calculators
Output Form 2A
Resident Soil
❑
Output Form 2B
Resident Groundwater Use
❑
Output Form 2C
Non -Residential Worker Soil
❑
Output Form 2D
Non -Residential Worker Groundwater Use
❑
Output Form 2E
Construction Worker Soil
❑
Output Form 2F
Recreator/Trespasser Soil
❑
Output Form 2G
Recreator/Tres asser Surface Water
❑
Output Section 3 - Vapor Intrusion Calculators
Output Form 3A
Resident Groundwater to Indoor Air
❑
Output Form 3B
Resident Soil Gas to Indoor Air
0
Output Form 3C
Resident Indoor Air
❑
Output Form 31)
Non -Residential Worker Groundwater to Indoor Air
❑
Output Form 3E
Non -Residential Worker Soil Gas to Indoor Air
0
Output Form 3F
Non -Residential Worker Indoor Air
❑
Output Section 4 - Contaminant Migration Worksheets
Output Form 4A
Soil to Groundwater - Forward Mode
❑
Output Form 4B
Groundwater to Groundwater - Forward Mode
❑
Output Form 4C
Soil to Surface Water - Forward Mode
❑
Output Form 41)
Groundwater to Surface Water - Forward Mode
❑
Output Form 4E
Soil to Groundwater - Backward Mode
❑
Output Form 4F
Groundwater to Groundwater - Backward Mode
❑
Output Form 4G
Soil to Surface Water - Backward Mode
❑
Output Form 4H
Groundwater to Surface Water - Backward Mode
❑
North Carolina DEQ Risk Calculator

Complete Exposure Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Note: Risk output will only be calculated for complete exposure pathways.
Receptor
Pathway
Check box if
pathway
complete
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Soil
❑
Groundwater Use
❑
Non -Residential Worker
Soil
❑
Groundwater Use
❑
Construction Worker
Soil
❑
Recreator/Trespasser
Soil
❑
Surface Water
❑
VAPOR INTRUSION PATHWAYS
Resident
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
0
Indoor Air
❑
Non -Residential Worker
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
El
Indoor Air
❑
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Source Soil
❑
Source Groundwater
❑
Surface Water
Source Soil
❑
Source Groundwater
❑
North Carolina DEQ Risk Calculator

Exposure Factors and Target Risks
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Exposure Parameter
Default Value
Site Specific Value
Justification
General
Target Cancer Risk (individual)
1.0E-06
1.0E-06
Target Cancer Risk (cumulative)
1.0E-04
1.0E-04
Target Hazard Index (individual)
2.0E-01
2.0E-01
Target Hazard Index (cumulative)
1.0E+40
1.0E+00
Residential Child
Lifetime (LT) (years)
70
70
Body Weight(BW) (kg)
15
15
Exposure Duration (ED) (yr)
6
6
Exposure Frequency (EF) (d/yr)
350
350
Exposure Time (ET) (hr/d)
24
24
Skin Surface Area - Soil Exposure (SAg) (cm2)
2373
2373
Soil Adherence Factor (AF) (mg/cm2)
0.2
0.2
Soil Ingestion Rate (IRS) (mg/day)
200
200
Skin Surface Area - Water Exposure (SA,) (cm2)
6365
6365
Water Ingestion Rate (IRW) (L/d)
0.78
0.78
Water Exposure Time (ET,„_) (hr/event)
0.54
0.54
Water Event Frequency (EV) (events/day)
1
1
Residential Adult
Lifetime (LT) (years)
70
70
Body Weight(BW) (kg)
80
80
Exposure Duration (ED) (yr)
20
20
Exposure Frequency (EF) (d/yr)
350
350
Exposure Time (ET) (hr/d)
24
24
Skin Surface Area - Soil Exposure (SAg) (cm)
6032
6032
Soil Adherence Factor (AF) (mg/cm2)
0.07
0.07
Soil Ingestion Rate (IRS) (mg/day)
100
100
Skin Surface Area - Water Exposure (SA,) (Cm 2)
19652
19652
Water Ingestion Rate (IRW) (L/d)
2.5
2.5
Water Exposure Time (ET,_) (hr/event)
0.71
0.71
Water Event Frequency (EV) (events/day)
1
1
Non -Residential Worker
Lifetime (LT) (years)
70
70
Body Weight(BW) (kg)
80
80
Exposure Duration (ED) (yr)
25
25
Exposure Frequency (EF) (d/yr)
250
250
Exposure Time (ET) (hr/d)
8
8
Skin Surface Area - Soil Exposure (SAs) (cm)
3527
3527
Soil Adherence Factor (AF) (mg/cm2)
0.12
0.12
Soil Ingestion Rate (IR) (mg/day)
100
100
Skin Surface Area - Water Exposure (SA,) (Cm 2)
19652
19652
Water Ingestion Rate (IRW) (L/d)
0.83
0.83
Water Exposure Time (ET,„_) (hr/event)
0.67
0.67
Water Event Frequency (EV) (events/day)
1
1
Construction Worker
Lifetime (LT) (years)
70
70
Body Weight(BW) (kg)
80
80
Working Weeks (EW) (wk/yr)
50
50
Exposure Duration (ED) (yr)
1
1
Exposure Frequency (EF) (d/yr)
250
250
Exposure Time (ET) (hr/d)
8
8
Skin Surface Area - Soil Exposure (SAs) (Cm 2)
3527
3527
Soil Adherence Factor (AF) (mg/cm)
0.3
0.3
Soil Ingestion Rate (M) (mg/day)
330
330
North Carolina DEQ Risk Calculator

Exposure Factors and Target Risks
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Exposure Parameter
Default Value
Site Specific Value
Justification
User Defined Child
Recreator
Trespasser
Lifetime (LT) (years)
70
NA
Averaging Time (AT) (days/yr)
365
NA
365
Body Weight (BW) (kg)
15
NA
15
Exposure Duration 0-2 (ED) (yr)
2
NA
2
Exposure Duration 2-6 (ED) (yr)
4
NA
4
Exposure Frequency (EF) (d/yr)
195
NA
195
Exposure Time (ET) (hr/d)
2
NA
2
Skin Surface Area -Soil Exposure (SAg) (cm)
2373
NA
2373
Soil Adherence Factor (AF) (mg/cm2)
0.2
NA
0.2
Soil Ingestion Rate (IRS) (mg/day)
200
NA
200
Skin Surface Area -Water Exposure (SA,) (Cm Z)
6365
NA
6365
Water Ingestion Rate (IRW) (L/hr)
0.12
NA
0.12
Water Exposure Time (ET,_) (hr/event)
2
NA
2
Water Event Frequency (EV) (events/day)
1
NA
1
User Defined Adult
Recreator
Trespasser
Lifetime (LT) (years)
70
70
70
Body Weight(BW) (kg)
80
45
80
Exposure Duration 6-16 (ED) (yr)
10
10
10
Exposure Duration 16-26 (ED) (yr)
10
0
10
Exposure Frequency (EF) (d/yr)
195
90
195
Exposure Time (ET) (hr/d)
2
2
2
Skin Surface Area -Soil Exposure (SAs) (Cm Z)
6032
6032
6032
Soil Adherence Factor (AF) (mg/cm)
0.07
0.2
0.07
Soil Ingestion Rate (IRS) (mg/day)
100
200
100
Skin Surface Area -Water Exposure (SA,) (cm)
19652
19652
19652
Water Ingestion Rate (IRW) (L/hr)
0.11
0.11
0.11
Water Exposure Time (ET_j (hr/event)
2
2
2
Water Event Frequency (EV) (events/day)
1
1
1
NOM Carolina DEQ Risk Calculator

osure Point Concentrations
lion Date: July 2022
s: May 2022 EPA RSL Table
ID: 25087-21-092
osure Unit ID: Site Wide Soil Gas - Hvoothetical Worst Case
Soil Gas Exposure Point Concentration Table
Description of Exposure Point Concentration Selection:
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
It the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
Exposure Point
Minimum
Maximum
Location of
Range of
Concentration
ScreeningPotential
Potential
Rationale for
Concentration
Notes:
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
COPC Flagation
Selection or
(ug/m3)
(Qualifier)
(Qualifier)
Concentration
Frequency
Limits
Screening
Value
(Screening
Value
Source
(Y/N)
Deletion
Level) (n/c)
310
67-64-1
Acetone
ug/m3
5.8
1
71-43-2
Benzene
I u9/m3
20
106-99-0
Butadiene, 1,3-
119/1113
12
75-15-0
Carbon Disulfide
ug/m3
3.8
67-66-3
Chloroform
119/1113
38
111-77-3
Ethanol, 2-(2-methox ethox )-
ug/m3
3.3
142-82-5
Heptane, N-
119/1113
2.9
1
110-54-3
Hexane, N-
I u9/m3
25
78-93-3
Methyl Ethyl Ketone (2-Butanone)
119/1113
8.4
108-10-1
Methyl Isobutyl Ketone (4-meth 1-2- entanone)
u9/m3
69
100-42-5
Styrene
119/1113
3.8
127-18-4
Tetrachloroeth lene
u9/m3
5.8
108-88-3
Toluene
ug/m3
39
1
1 79-01-6
1 Trichloroeth lene
ug/m3
3.6
95-63-6
Trimethylbenzene, 1,2,4-
ug/m3
3.1
108-67-8
Trimeth lbenzene, 1,3,5-
ug/m3
1.8
1330-20-7
Xylenes
ug/m3
North Carolina DEQ Risk C.I.I.lnf

Risk for Individual Pathways
1
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
Pathway
CarcinogenicHazard
Risk
Index
Risk exceeded?
Resident
Soil
NC
NC
NC
NC
Groundwater Use*
NC
NC
Non -Residential Worker
Soil
NC
NC
NC
NC
Groundwater Use*
NC
NC
Construction Worker
Soil
NC
NC
NC
Recreator/Trespasser
Soil
NC
NC
NC
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
1.0E-05
8.6E-01
NO
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
7.3E-07
6.9E-02
NO
Indoor Air
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NC
Source Groundwater
Exceedence of 21, at Receptor?
NC
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NC
Source Groundwater
Exceedence of 2B at Receptor?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Sitewide Risk
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Exposure Unit ID: Site Wide Soil Gas - Hypothetical Worst Case
Resident - Current Scenario
Resident - Future Scenario
Non -Residential Worker - Current Scenario
Non -Residential Worker - Future Scenario
Construction Worker
Recreator/Trespasser
Receptor
Pathway
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
Check box to
include in site-
wide risk
calculations
Carcinogenic
Risk
Hazard Index
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Soil
NM
NM
NM
N1bI
NM
NM
NM
NM
Groundwater Use*
Non -Residential Worker
Soil
r
NM
NM
NM
NM
Groundwater Use*
F
NM
NM
NM
NM
Construction Worker
Soil
r
NM
NM
Recreator/Trespasser
Soil
r
NM
NM
Surface Water Use*
f NM
NM
VAPOR INTRUSION CALCULATORS
Groundwater to Indoor Air
r
NM
NM
r
NM
NM
Resident
Soil Gas to Indoor Air
r
NM
NM
F
1.0E-05
8.6E-01
Indoor Air
NM
NM
r
NM
NM
Groundwater to Indoor Air
r
NM
NM
r NM
NM
Non -Residential Worker
Soil Gas to Indoor Air
r
NM
NM
r 2.4E-07
4.6E-02
Indoor Air
r
NM
NM
r NM
NM
TOTAL SITEWIDE RISK FOR EACH RECEPTOR
0.0E+00
0.0E+00
1.0E-05
I 8.6E-01
0.0E+00
0.0E+00
2.4E-07
4.6E-02
0.0E+00
0.0E+00
0.0E+00
0.0E+00
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based closure.
3. NM —Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

DEQ Risk Calculator - Va or Intrusion -Resident Soil Gas to Indoor Air
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: 25087-21-092
Ex osure Unit ID: Site Wide Soil Gas - H othetical Worst Case
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
All concentrations are in u m3
Calculated
Target Indoor
Tar
CAS #
Chemical Name:
Soil Gas
Concentration
s
(ug/m)
Indoor Air
Concentration
(ug/m3)
Air Conc. for
Carcinogens @
TCR = 1 E-06
get Indoor Air
Conc. for Non -
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
310
9.3
-
-
71-43-2
Benzene
5.8
0.174
3.6E-01
6.3E+00
4.8E-07
5.6E-03
106-99-0
Butadiene, 1,3-
20
0.6
9.4E-02
4.2E-01
6.4E-06
2.9E-01
75-15-0
Carbon Disulfide
12
0.36
-
1.5E+02
4.9E-04
67-66-3
Chloroform
3.8
0.114
1.2E-01
2.0E+01
9.3E-07
1.1E-03
111-77-3
Ethanol, 2-(2-methox ethox )-
38
1.14
-
-
142-82-5
H tane, N-
3.3
0.099
-
8.3E+01
2.4E-04
110-54-3
Hexane, N-
2.9
0.087
-
1.5E+02
1.2E-04
78-93-3
Methyl Ethyl Ketone (2-Butanone)
25
0.75
-
1.0E+03
1.4E-04
108-10-1
Methyl Isobu 1 Ketone (4-meth 1-2- entanone)
8.4
0.252
-
6.3E+02
8.1E-05
100-42-5
Styrene
69
2.07
-
2.1E+02
2.0E-03
127-18-4
Tetrachloroethylene
3.8
0.114
1.1E+01
8.3E+00
I.IF.-08
2.7E-03
108-88-3
Toluene
5.8
0.174
-
1.0E+03
3.3E-05
79-01-6
Trichloroeth lene
39
1.17
4.8E-01
4.2E-01
2.4F,-06
5.6E-01
95-63-6
Trimeth lbenzene, 1,2,4-
3.6
0.108
-
1.3E+01
1.7E-03
108-67-8
Trimeth lbenzene, 1,3,5-
3.1
0.093
-
1.3E+01
1.5E-03
1330-20-7
X lenes
1.8
0.054
-
2.1E+01
5.2E-04
North Carolina DEQ Risk Calculator

Risk Calculator - Vapor Intrusion - Non -Residential Worker Soil Gas to Indoor Air
lion Date: July 2022
s: May 2022 EPA RSL Table
ID: 25087-21-092
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk,
no risk values are calculated for these chemicals.
All concentrations are in 11¢/m3
CAS #
Chemical Name:
Soil Gas
Concentration
s
(ug/m)
Calculated
Indoor Air
Concentration
(ug/ms)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non -
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
310
3.1
71-43-2
Benzene
5.8
0.058
1.6E+00
2.6E+01
3.7E-08
4.4E-04
106-99-0
Butadiene, 1,3-
20
0.2
4.1E-01
1.8E+00
4.9E-07
2.3E-02
75-15-0
Carbon Disulfide
12
0.12
6.1E+02
3.9E-05
67-66-3
Chloroform
3.8
0.038
5.3E-01
8.6E+01
7.1E-08
8.9E-05
111-77-3
Ethanol,2-(2-methoxyethoxy)-
38
0.38
142-82-5
He tane, N-
3.3
0.033
3.5E+02
1.9E-05
110-54-3
Hexane, N-
2.9
0.029
6.1E+02
9.5E-06
78-93-3
Methyl Ethyl Ketone (2-Butanone)
25
0.25
4.4E+03
1.1E-05
108-10-1
Methyl Isobutyl Ketone (4-methyl-2-pentanone)
8.4
0.084
2.6E+03
6.4E-06
100-42-5
Styrene
69
0.69
8.8E+02
1.6E-04
127-184
Tetrachloroethylene
3.8
0.038
4.7E+01
3.5E+01
8.1E-10
2.2E-04
108-88-3
Toluene
5.8
0.058
4.4E+03
2.6E-06
79-01-6
Trichloroethylene
39
0.39
3.0E+00
1.8E+00
1.3E-07
4.5E-02
95-63-6
1 Trimeth lbenzene, 1,2,4-
3.6
1 0.036
1
5.3E+01
1.4E-04
108-67-8
1 Trimethylbenzene, 1,3,5-
3.1
1 0.031
1
5.3E+01
1.2E-04
1330-20-7
1 X lens
1.8
1 0.018
1
8.8E+01
I
4.1E-05
Cumulative: 1 7.3E-07 1 6.9E-02
North Carolina DEQ Risk Calculator

APPENDIX B
Chain of Custody/Laboratory Analytical Testing Data
625 Holcomb Bridge Road, Norcross, GA 30071 • 770-209-0029 • unitedconsulting.com
We're here for you.

urofins
Environment Testing
America
ANALYTICAL REPORT
Eurofins Savannah
5102 LaRoche Avenue
Savannah, GA 31404
Tel: [phone]
Laboratory Job ID: 680-220595-1
Client Project/Site: Raleigh
Revision: 1
For:
Total Vapor Solutions
120 Nottaway Lane
Alpharetta, Georgia 30009
Attn: Jim Fineis
se'�J'�A
Authorized for release by:
9/13/2022 10:06:07 AM
David Fuller, Project Manager
[phone]
David. [e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI
requirements for accredited parameters, exceptions are noted in this report. This
report may not be reproduced except in full, and with written approval from the
laboratory. For questions please contact the Project Manager at the e-mail address or
telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic
signature is intended to be the legally binding equivalent of a traditionally handwritten
signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.

Sample Summary
Client: Total Vapor Solutions Job ID: 680-220595-1
Project/Site: Raleigh
Lab Sample ID
Client Sample ID
Matrix
Collected
Received
680-220595-1
VCSV-B2
Air
08/30/2214:10
09/02/2210:42
680-220595-2
VCSV-B1
Air
08/30/2214:25
09/02/2210:42
680-220595-3
VCSV-U2
Air
08/30/2214:45
09/02/2210:42
680-220595-4
VCSV-B3
Air
08/30/2214:59
09/02/2210:42
680-220595-5
VCSV-B4
Air
08/30/2215:15
09/02/2210:42
680-220595-6
VCSV-B5
Air
08/30/2215:24
09/02/2210:42
680-220595-7
VCSV-B6
Air
08/30/2216:01
09/02/2210:42
680-220595-8
VCSV-U3
Air
08/30/2216:22
09/02/2210:42
680-220595-9
VCSV-U1
Air
08/30/2213:53
09/02/2210:42
Page 2 of 47 Eur8h1*Zl`,�ZZ6H9 - 1)

Case Narrative C
Client: Total Vapor Solutions Job ID: 680-220595-1
Project/Site: Raleigh
Job ID: 680-220595-1
Laboratory: Eurofins Savannah
Narrative
Job Narrative
680-220595-1
Revision 1
The report being provided is a revision of the original report sent on 9/12/2022. The report (revision 1) is being revised in order to correct
the Sample IDs for 3 samples on Eurofins Air Toxics report..
Receipt
The samples were received on 9/2/2022 10:42 AM.
Subcontract Work
Method EPA TO-15: This method was subcontracted to Eurofins Air Toxics. The subcontract laboratory certification is different from that of
the facility issuing the final report.
Eurofins Savannah
Page 3 of 47 9/13/2022 (Rev. 1)

tiff e u rof i n s
Air Toxics
9/13/2022
Mr. David Fuller
Eurofins Test America C
5102 LaRoche
Savannah GA 31404
Project Name: Raleigh
Project #: 083022
Workorder #: 2209056R1
Dear Mr. David Fuller
The following report includes the data for the above referenced project for sample(s)
received on 9/2/2022 at Eurofins Air Toxics LLC.
The data and associated QC analyzed by TO-15 are compliant with the project
requirements or laboratory criteria with the exception of the deviations noted in the
attached case narrative.
Thank you for choosing Eurofins Air Toxics LLC. for your air analysis needs. Eurofins Air
Toxics Inc. is committed to providing accurate data of the highest quality. Please feel free
to contact the Project Manager: Brian Whittaker at 916-985-1000 if you have any
questions regarding the data in this report.
Regards,
Brian Whittaker
Project Manager
Eurotlns Air Toxics, LLC
180 Blue Ravine Road, 5ulte B
Folsom, CA 95630
T 9145-965-1000
F 916-351-8279
www.aiftoxics.corn
Page 1 of 43
Page 4 of 47 9/13/2022 (Rev. 1)

1%1 eurofins
Air Toxics
WORK ORDER #: 2209056R1
Work Order Summary
CLIENT:
Mr. David Fuller
BILL TO:
Accounts Payable
Eurofins Environment Testing
Eurofins Environment Testing
5102 LaRoche
4104 Shuffel St NW
Savannah, GA 31404
North Canton, OH 44720
PHONE:
912-354-7858
P.O. #
680-220595
FAX:
PROJECT #
083022 Raleigh
DATE RECEIVED:
09/02/2022
CONTACT:
Brian Whittaker
DATE COMPLETED:
09/12/2022
DATE REISSUED:
09/13/2022
RECEIPT
FINAL
FRACTION #
NAME
TEST
VAC./PRES.
PRESSURE
OIA
VCSV-B2
TO-15
7.3 "Hg
10 psi
02A
VCSV-B1
TO-15
7.1 "Hg
10 psi
03A
VCSV-U2
TO-15
6.1 "Hg
9.8 psi
04A
VCSV-B3
TO-15
5.3 "Hg
10 psi
05A
VCSV-B4 B4
TO-15
6.1 "Hg
9.9 psi
06A
VCSV-B5
TO-15
7.6 "Hg
9.8 psi
07A
VCSV-B6
TO-15
6.5 "Hg
10 psi
08A
VCSV-U3
TO-15
5.1 "Hg
9.9 psi
09A
VCSV-U1
TO-15
6.1 "Hg
10 psi
10A
Lab Blank
TO-15
NA
NA
11A
CCV
TO-15
NA
NA
12A
LCS
TO-15
NA
NA
12AA
LCSD
TO-15
NA
NA
CERTIFIED BY:
Technical Director
DATE: 09/13/22
Certification numbers: AZ Licensure AZ0775, FL NELAP — E87680, LA NELAP — 02089, NH NELAP - 209221, NJ NELAP - CAO 16,
NY NELAP - 11291, TX NELAP - T104704434-21-17, UT NELAP — CA009332021-13, VA NELAP - 10615, WA NELAP - C935
Name of Accreditation Body: NELAP/ORELAP (Oregon Environmental Laboratory Accreditation Program)
Accreditation number: CA300005-015, Effective date: 10/18/2021, Expiration date: 10/17/2022.
Eurofins Air Toxics, LLC certifies that the test results contained in this report meet all requirements of the NELAC standards
This report shall not be reproduced, except in full, without the written approval ofEurofins Air Toxics, LLC.
180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630
[phone] . [phone] . FAX [phone]
0
Page 2 of 43
Page 5 of 47 9/13/2022 (Rev. 1)

ti% eurofins C
Air Toxics
LABORATORY NARRATIVE
EPA Method TO-15
Eurofins Test America
Workorder# 2209056R1
Nine 1 Liter Summa Canister samples were received on September 02, 2022. The laboratory performed
analysis via EPA Method TO-15 using GUMS in the full scan mode.
Receiving Notes
According to the Chain of Custody (COC), sample VCSV-132 was collected on 08/30/22. However, the
date on the sample tag reflects a collection date of 08/30/21. Therefore the date on the COC was used to
calculate the sample holding time.
The Chain of Custody (COC) information for sample VCSV-B4 B4 did not match the entry on the sample
tag with regard to sample identification. The information on the COC was used to process and report the
sample.
The Chain of Custody (COC) information for samples VCSV-V3 and VCSV-V1 did not match the
information on the canister with regard to canister barcode. The sample labeled 3814 and 27314 on the
COC is labeled as 1L3514 and 1L3572 on the canister. The client was notified of the discrepancy and the
information on the canister was used to process and report the samples.
The Work Order was reissued per client request on September 13, 2022 to revise sample identifications.
Analytical Notes
As per client project requirements, the laboratory has reported estimated values for target compound hits
that are below the Reporting Limit but greater than the Method Detection Limit. Concentrations that are
below the level at which the canister was certified may be false positives.
Definition of Data Qualifying Flags
Ten qualifiers may have been used on the data analysis sheets and indicates as follows:
B - Compound present in laboratory blank greater than reporting limit (background subtraction not
performed).
J - Estimated value.
E - Exceeds instrument calibration range.
S - Saturated peak.
Q - Exceeds quality control limits.
U - Compound analyzed for but not detected above the reporting limit, LOD, or MDL value. See
data page for project specific U-flag definition.
UJ- Non -detected compound associated with low bias in the CCV
N - The identification is based on presumptive evidence.
M - Reported value may be biased due to apparent matrix interferences.
CN - See Case Narrative.
Page 3 of 43
Page 6 of 47 9/13/2022 (Rev. 1)

ti% eurofins C
Air Toxics
0
File extensions may have been used on the data analysis sheets and indicates
as follows:
a -File was requantified
b-File was quantified by a second column and detector
rl-File was requantified for the purpose of reissue
Page 4 of 43
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