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WithersRavenel
Our People. Your Success.
115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479
Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington
GROUNDWATER MONITORING REPORT
Pap’s Package Store
NCDEQ Incident # 13017
UST # WS‐3931
716 South Main Street
Randleman, Randolph County, North Carolina
WithersRavenel Project No. 23‐0307‐DM
Prepared for:
State of North Carolina
Department of Environmental Quality
Division of Waste Management
Underground Storage Tank Section
Federal & State Lead Program
1646 Mail Service Center
Raleigh, North Carolina 27699‐1646
Prepared by:
WithersRavenel
115 MacKenan Drive
Cary, North Carolina 27511
North Carolina Firm License No. F‐1479
June 5, 2023
WithersRavenel
Our People. Your Success.
115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479
Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington
June 5, 2023
State of North Carolina
Department of Environmental Quality
Federal & State Lead Program
Division of Waste Management‐Underground Storage Tank Section
1646 Mail Service Center
Raleigh, North Carolina 27699‐1646
Attn: Ms. Kristie Oseguera
Re: Groundwater Monitoring Report
Pap’s Package Store
716 South Main Street
Randleman, Randolph County, North Carolina
Groundwater Incident Number: 13017
UST Number: WS‐3931
WR Project Number: 23‐0307‐DM
Ms. Oseguera,
WithersRavenel, Inc. (WR) has completed this Groundwater Monitoring Report to document an
aggressive fluid and vapor recovery (AFVR) event, the installation and surveying of monitoring
wells MW‐2 and MW‐3, and the gauging and sampling of the site monitoring wells in association
with our proposal, numbered TA‐01, for the above referenced site, approved by the Federal &
State Lead Program on March 14, 2023.
WR appreciates the opportunity to be of service to the Federal & State Lead Program. Should you
have any questions regarding the attached, please contact us at (919) 469‐3340.
Cordially,
WithersRavenel
Cory Nobles Elizabeth A. Allyn, P.G.
Environmental Geologist II Environmental Project Geologist II
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
i
TABLE OF CONTENTS
SECTION A. SITE INFORMATION ..................................................................................................................... 1
SECTION B. EXECUTIVE SUMMARY ................................................................................................................ 3
SECTION C. SITE HISTORY AND CHARACTERIZATION ............................................................................ 5
SECTION D. AFVR EVENT – MARCH 2023 .................................................................................................... 6
SECTION E. MONITORING WELL INSTALLATION – MAY 2023 ............................................................. 7
SECTION F. GROUNDWATER SAMPLING – MAY 2023 ............................................................................ 7
SECTION G. CONCLUSIONS AND RECOMMENDATIONS ....................................................................... 8
FIGURES
Figure 1 General Location Map
Figure 2 Site Map
Figure 3 Potential Receptor Map
Figure 4 Groundwater Elevation Contour Map
Figure 5 Groundwater Analytical Map – May 2023
Figure 6 Dissolved Benzene Isoconcentration Map – May 2023
Figure 7 Dissolved MTBE isoconcentration Map – May 2023
Figure 8 Proposed Monitoring Well Location Map
TABLES
Table B‐1 Site History: UST/AST System & Other Release Information
Table B‐4 Summary of Groundwater Analytical Results
Table B‐5A Public & Private Water Supply Well Information
Table B‐7 Monitoring and Remediation Well Construction Information
Table B‐9 Current & Historical Groundwater Elevations & LNAPL Thickness
APPENDICES
Appendix A AFVR Calculations
Appendix B Field Notes & Photographic Record
Appendix C Certificates of Disposal & Manifests
Appendix D Boring Log & Well Construction Record
Appendix E Laboratory Analytical Report & Chain‐of‐Custody
Appendix F General Standard Operating Procedures
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
1
SECTION A. SITE INFORMATION
1. Site Identification
Date of Report: June 5, 2023
Facility I.D.: 00‐0‐0000019717
Incident No.: 13017
UST No.: WS‐3931
Site Risk: High
Site Rank: H187D
Land Use Category: Industrial
Site Name: Pap’s Package Store
Site Location: 716 South Main Street
Nearest City/Town: Randleman
County: Randolph
Description of Geographical Data Point: UST Basin
Location Method: UST Incidents Map
Latitude: 35.806120°
Longitude: ‐79.805390°
2. Contact Information
UST Owner: Banks “Pap” Kennedy (deceased)
Address:
Phone:
Property Owner: Clarence Ray Jernigan
Address: 100 S. Coble Street, Randleman, NC 27317
Phone: 336‐626‐2042
Property Occupant: Randleman Towing
Address: 716 South Main Street, Randleman, NC 27317
Phone: 336‐498‐2503
Consultant/Contractor: WithersRavenel
Address: 115 MacKenan Drive, Cary, NC 27511
Phone: 919‐469‐3340
Analytical Laboratory: Waypoint Analytical, Inc.
State Certification Number: ENV402
Address: 449 Springbrook Rd., Charlotte, NC 28217
Phone: 704‐529‐6364
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
3
SECTION B. EXECUTIVE SUMMARY
1. Summary of Activities Associated with Current TA
WithersRavenel, Inc. (WR) conducted an aggressive fluid and vapor recovery (AFVR) event,
supervised the installation of monitoring wells MW‐2 and MW‐3, surveyed the tops‐of‐casing for
MW‐2 and MW‐3, and gauged, and sampled MW‐1 through MW‐3 at the Pap’s Package Store
site located at 716 South Main Street, Randleman, Randolph County, North Carolina in association
with task authorization TA‐01 North Carolina Department of Environmental Quality (NCDEQ)
Contract #N70522‐C.
2. Soil, Groundwater and LNAPL Assessment Information
Soils
No soil samples were obtained in association with the monitoring activities conducted by WR as
part of TA‐01. During the underground storage tank (UST) system removal activities, the soil
sample collected from beneath the pump island contained Total Petroleum Hydrocarbons (TPH) –
Gasoline Range Organics (GRO) at 1,240 milligrams per kilogram (mg/kg), the soil sample collected
beneath the 550‐gallon gasoline UST in the western corner of the UST basin contained TPH‐GRO
at a concentration of 41 mg/kg, and the soil sample collected from beneath the product line
contained a TPH‐GRO concentration of 31 mg/kg. The remaining soil samples were below
detection limits. A Site Sensitivity Evaluation (SSE) was completed in November 1994. Soils
collected during the SSE indicated concentration of TPH‐GRO at 140 mg/kg in the sample
collected from 25‐27 feet below ground surface (bgs) in the vicinity of the pump island. Samples
collected from the former UST basin did not indicate concentrations of TPH‐GRO or TPH‐Diesel
Range Organics (DRO) above the laboratory detection limit.
Groundwater
WR sampled monitoring wells MW‐1 through MW‐3 on May 4, 2023. The collected groundwater
samples were submitted for laboratory analysis of volatile organic compounds (VOCs) by
SM6200B.
Laboratory analytical results revealed the following:
Monitoring well MW‐1 contained benzene above the Gross Contamination Levels (GCLs)
and several compounds above the North Carolina Groundwater Quality Standards (NC 2L
Standards).
Monitoring wells MW‐3 contained methyl tert‐butyl ether (MTBE) above the NC 2L
Standards.
Monitoring well MW‐2 did not contain compounds above the NC 2L Standards.
Light Non‐Aqueous Phase Liquid
Light non‐aqueous phase liquid (LNAPL) has not been detected at the site to date.
3. Receptor Information
As part of TA‐01 under NCDEQ Contract #N122019B, WR completed an updated receptor
survey. WR identified fifteen (15) water supply wells within a 1,000‐foot (ft) radius. The nearest
of these wells (SW‐1), which is inactive, is located approximately 500‐ft from the source area. The
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
4
closest active water supply well was SW‐4 located approximately 775 feet to the south‐southeast.
No surface water bodies were identified within 1,000 feet of the source area. Municipal water is
available to the site and surrounding area. Impacted groundwater is not expected to encounter
utilities as the average depth to water is 22 feet bgs.
4. Remediation Activities
Based on WR’s review of historical files available for the site, the following remedial activities have
been completed at the location:
In March 2023, WR supervised an AFVR event which removed approximately 241 gallons
of impacted groundwater and 1.39 pounds via emissions (0.22 gallons of gasoline).
5. Recommendations
Based on the results of assessment and monitoring activities conducted at the site in association
with this TA, WR recommends the following:
Installation of one monitoring well on the northeast corner of the site.
Conduct a soil assessment to determine the extent of soil impacts at the site.
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
5
SECTION C. SITE HISTORY AND CHARACTERIZATION
The following information summarizes the site history and characterization.
1. UST Information
Two 550‐gallon gasoline and one 2,000‐gallon gasoline underground storage tanks (USTs) were
installed at the site in 1970 and removed in July 1994. These USTs operated under facility ID 00‐
0‐0000019717. Historical UST information is provided in Table B‐1.
2. Description of Release/General Assessment History
The following summary of the assessment history is based on WR’s review of historical files for
the subject incident:
In 1994, three USTs were removed from the property including one 2,000‐gallon and two 550‐
gallon gasoline USTs. Soil samples collected during the UST closure activities ranged from below
detection limits to 1,240 ppm of TPH‐GRO with the highest concentration being beneath the
pump island. No soil excavation was performed.
In 1994, Bain and Palmer of Greensboro performed a Site Sensitivity Evaluation (SSE). As part of
the SSE, two borings were installed at the site to determine the depth of soil contamination and
the depth of groundwater or bedrock, whichever was encountered first. One boring was installed
in the former UST basin and the other was installed in the former pump island. Soil samples were
collected at 15, 20, and 25 feet bgs. The samples collected from the UST basin were below
detection limits and the soil sample collected from the pump island at 25 feet bgs was 140 ppm.
Groundwater was encountered at 23.57 feet in the UST basin boring. The groundwater was not
sampled.
As part of the Phase I Limited Site Assessment (LSA) activities in 2006, one Type II monitoring well
(MW‐1) was installed in the former pump island location. Soil samples were collected from three
intervals (4‐5 feet, 9‐10 feet, and 14‐15 feet bgs) during the installation of monitoring well MW‐
1. The sample collected from the 4–5‐foot interval exceeded the Residential MSCCs. The sampling
results indicated exceedances of the GCL for benzene and EDB in monitoring well MW‐1 and
several compounds above the NC 2L Standards. The LSA identified one active water supply well
approximately 850 feet from the site and four additional active water supply wells between 900
and 1,000 feet from the release.
In December 2022, WR conducted an updated receptor survey and sampled monitoring well MW‐
1. WR identified fifteen (15) water supply wells within a 1,000‐foot (ft) radius. The nearest of
these wells (SW‐1), which is inactive, is located approximately 500‐ft from the source area. The
closest active water supply well was SW‐4 located approximately 775 feet to the south‐southeast.
No surface water bodies were identified within 1,000 feet of the source area. Benzene was above
the GCL, and several additional compounds were present above the 2L Standards.
3. Brief Description of Site Characteristics
The property is located in a commercial/industrial/residential area of Randleman, Randolph
County, North Carolina (Figure 1). The property includes a single‐story wood framed structure,
reportedly constructed in 1930. The site is currently occupied by Randleman Towing, an
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
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automotive repair center and towing company. Surface coverings at the location include the site
structure, asphalt, or concrete areas. No grassy areas were observed at the site. A site map is
included as Figure 2. The Randolph County Geographic Information System (GIS) website
identifies the subject property as parcel number 55160 and Property Identification Number
7764191227.
4. Information on Receptors/Potential Receptors
As part of TA‐01 under NCDEQ Contract #N122019B, WR completed an updated receptor
survey. WR identified fifteen (15) water supply wells within a 1,000‐foot (ft) radius. The nearest
of these wells (SW‐1), which is inactive, is located approximately 500‐ft from the source area. The
closest active water supply well was SW‐4 located approximately 775 feet to the south‐southeast.
No surface water bodies were identified within 1,000 feet of the source area. Potential receptor
locations are shown on Figure 3. Municipal water is available to the site and surrounding area.
Impacted groundwater is not expected to encounter utilities as the average depth to water is 22
feet bgs.
5. Regional and Site Geology and Hydrology
The Geologic Map of North Carolina depicts the site as being within the Carolina Slate Belt of the
Piedmont Physiographic Region described as metamorphosed dacitic to rhyolitic flows and tuffs,
light gray to greenish gray; interbedded with mafic and intermediate metavolcanic rock, meta‐
argillite, and metamudstone.
According to the United States Department of Agricultural (USDA) Natural Resources
Conservation Service (NRCS) Web Soil Survey, the source area is underlain by Georgeville‐Urban
land complex (2 to 10 percent slopes). The Georgeville‐Urban land complex is well drained, found
on summits and shoulders of interfluves, and the parent material is residuum weathered from
metavolcanics and/or argillite. The 2006 LSA report indicated that soils encountered at the site
consists of silty clay to approximately 7 feet bgs and silt to approximately 21 feet bgs. Soil
encountered during the installation of MW‐2 and MW‐3 were characterized as silty clay from
ground surface to approximately 33 feet bgs. Refusal has not been encountered during site
investigations to date.
SECTION D. AFVR EVENT – MARCH 2023
On March 22, 2023, WR personnel along with Eastern Environmental Management (EEM)
mobilized to the site and proceeded with an AFVR event. Prior to performing the AFVR event,
WR personnel gauged the depth to water in well MW‐1. Depth to water was 24.65 feet below the
top‐of‐casing (BTOC) in MW‐1 and LNAPL was not detected prior to, or at the conclusion of, the
AFVR event. Groundwater elevation and LNAPL data is presented in Table B‐9.
The AFVR event included application vacuum for 8 hours on monitoring well MW‐1. Vacuum at
the well head averaged 19 inches of mercury. Air stream concentrations from the discharge of
the blower were measured using a field calibrated RAE Systems™ Mini RAE® 3000 Photo
Ionization Detector (PID). Measured concentrations ranged from 877 parts per million (ppm) to
above 15,000 ppm during the event. At the conclusion of the AFVR, approximately 241 gallons
WithersRavenel
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Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
7
of impacted groundwater were recovered. Emissions through volatilization of recovered product
were calculated to be approximately 1.39 pounds (0.22 gallons).
At the conclusion of the event, depth to water in MW‐1 was not measured to the depth of the
bottom of the well (30 feet bgs). LNAPL was not identified in MW‐1 at the conclusion of the AFVR
event. The disposal manifest and AFVR calculations are included in Appendix A and field notes are
provided in Appendix B. The certificate of disposal and manifest for the impacted groundwater
are included in Appendix C.
SECTION E. MONITORING WELL INSTALLATION – MAY 2023
On May 3, 2023, WR personnel along with Ameriprobe, LLC (Ameriprobe) mobilized to the site to
install two Type II monitoring wells (MW‐2 and MW‐3) at the site via hollow stem auger. Type II
monitoring wells MW‐2 and MW‐3 were installed with a 15‐ft length of 2‐inch diameter Schedule
40 PVC 10‐slot well screen and a 18‐ft length of Schedule 40 PVC 2‐inch diameter casing. The
wells were completed with a concrete collar/pad and 8‐inch diameter flush‐mount manway. The
boring logs and well construction records are included in Appendix D. Field notes and photographs
are included in Appendix B. The locations of the monitoring wells are shown on Figure 2. Well
construction details are included in Table B‐7. Following completion, the wells were developed by
purging at least five well volumes. The wells were surveyed into the monitoring well network
during the groundwater sampling event.
Due to the lack of an area to spread the drill cuttings, the cuttings were containerized in three
steel drums. These drums were removed by Eastern on May 17, 2023. The certificate of disposal
and manifest are included in Appendix C.
SECTION F. GROUNDWATER SAMPLING – MAY 2023
On May 4, 2023, WR mobilized to the site to collect groundwater samples from monitoring wells
MW‐1, MW‐2, and MW‐3. The depths to groundwater ranged from 21.08 feet in MW‐2 to 23.67
feet in MW‐1. Depth to water was within the screened interval for each monitoring well. Based
on the measured tops‐of‐casing and depths to water, groundwater at the site flows to the
northeast. A groundwater elevation map is included as Figure 4. The groundwater elevation
measurement and well construction information is presented in Table B‐7 and historical
groundwater elevation measurements are included in Table B‐9. Field notes are included in
Appendix B.
Following gauging, the monitoring wells were purged and sampled with a separate, disposable
polyethylene (PE) bailer. The samples were decanted into pre‐preserved laboratory provided
sample containers and submitted to Waypoint Analytical, Inc. for testing by Standard Method (SM)
6200B.
Laboratory Results
Analytical results for groundwater sample obtained from monitoring wells MW‐1 through MW‐3
on May 4, 2023 indicated the following:
Monitoring well MW‐1 contained benzene above the GCLs and several compounds above
the NC 2L Standards.
Monitoring wells MW‐3 contained MTBE above the NC 2L Standards.
WithersRavenel
Our People. Your Success.
Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
8
Monitoring well MW‐2 did not contain compounds above the NC 2L Standards.
Current and historical groundwater analytical results are summarized in Table B‐4. A map depicting
the data from May 2023 is included as Figure 5 and a benzene and MTBE isoconcentration contour
maps are included as Figures 6 and 7. A copy of the laboratory analytical report and chain‐of‐
custody is included in Appendix E. WR’s generalized standard operating procedures are provided
in Appendix F.
SECTION G. CONCLUSIONS AND RECOMMENDATIONS
This report documents the results of field activities conducted at the site for TA‐01, which included
conducting an AFVR event, the installation and surveying of MW‐2 and MW‐3, and the gauging
and sampling of the site monitoring wells.
Conclusions based on observations, analytical data and research relating to the release at the site
combined with historical information include the following:
The site is currently occupied by Randleman Towing, an automotive repair center and
towing company.
WR completed an updated receptor survey. WR identified fifteen (15) water supply wells
within a 1,000‐foot (ft) radius. Municipal water is available in the site and surrounding area.
In March 2023, WR supervised an AFVR event which removed approximately 241 gallons
of impacted groundwater and 1.39 pounds via emissions (0.22 gallons of gasoline).
MW‐2 and MW‐3 were installed to a depth of 33 feet bgs each on May 3, 2023.
MW‐1 contained benzene above the GCL and several additional compounds above the NC
2L Standard.
MW‐3 contained MTBE above the NC 2L Standard.
MW‐2 did not contain compounds above the NC 2L Standards.
Based on the results of assessment and monitoring activities conducted at the site in association
with this TA, WR recommends the following:
Installation of one monitoring well on the northeast corner of the site.
Conduct a soil assessment to determine the extent of soil impacts at the site.
WithersRavenel
Our People. Your Success.
FIGURES
MM
LA
DRAWN BY:
05/24/23 23-0307-DM
1
SCALE:FIGURE NO.:
PROJECT NO.:DATE:APPROVED BY:
PAP'S PACKAGE STORE
716 SOUTH MAIN STREET
RANDLEMAN, RANDOLPH COUNTY, NC
GENERAL LOCATION MAP
1"=500 '
500250 1000
WithersRavenel
Engineers | Planners | Surveyors
115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479
www.withersravenel.com
SUBJECT SITE
± 0.2 ACRES
J:\23\0307-DM-Pap's Package Store\Enviro\CAD\Paps Package Base Map - 2023.01.dwg- May 26, 2023 - LALLYN
0
GRAPHIC SCALE
1 inch = 500 feet
MW-1
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550 2000
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FORMER DISPENSER
ISLAND
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PRODUCT
LINES
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1 inch = 30 ft.
3015 600 MMLADRAWN BY:05/24/2323-0307-DM2SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:SITE MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC
1019
22
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SITE J:\23\0307-DM-Pap's Package Store\Enviro\CAD\Paps Package Base Map - 2023.01.dwg- June 2, 2023 - LALLYN1"=300 'GRAPHIC SCALE
1 inch = 300 ft.
300150 6000 DCVEAADRAWN BY:05/24/2323-0307-DM3SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:POTENTIAL RECEPTORMAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
ACTIVE WATER SUPPLY WELL LOCATION
INACTIVE WATER SUPPLY WELL LOCATION
NOTES:
1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC#
#
1,500' RADIUS
1,000' RADIUS
500' RADIUS
MW-1
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1 inch = 30 ft.
3015 600 MMLADRAWN BY:5/23/2323-0307-DM4SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:GROUNDWATERELEVATION CONTOURMAP - MAY 2023WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
GROUNDWATER ELEVATION (FT)
GROUNDWATER ELEVATION CONTOUR (FT)
GROUNDWATER FLOW DIRECTION
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC77.30
MW-1
S. MAIN STREETMc
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FORMER USTS
FORMER DISPENSER
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LINES
SITEMW-2
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1 inch = 30 ft.
3015 600 MMLADRAWN BY:5/23/2323-0307-DM5SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:GROUNDWATERANALYTICAL MAP - MAY2023WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC
MW-1
S. MAIN STREETMc
C
O
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U
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S
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T
550
550 2000
FORMER USTS
FORMER DISPENSER
ISLAND
FORMER
PRODUCT
LINES
SITEMW-2
13,100
<0.500
<0.500
MW-3
5,000 ug/L J:\23\0307-DM-Pap's Package Store\Enviro\CAD\Paps Package Base Map - 2023.01.dwg- May 26, 2023 - LALLYN1"=30 'GRAPHIC SCALE
1 inch = 30 ft.
3015 600 MMLADRAWN BY:5/23/2323-0307-DM6SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:DISSOLVED BENZENEISOCONCENTRATIONMAP - MAY 2023WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
DISSOLVED BENZENE CONCENTRATION (ug/L)
ESTIMATED EXTENT OF BENZENE IMPACTS
ABOVE GCL - DASHED WHERE INFERRED
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC13,100
MW-1
S. MAIN STREETMc
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FORMER USTS
FORMER DISPENSER
ISLAND
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LINES
SITEMW-2
6,280
31.2
<1.00
MW-3
20ug/L J:\23\0307-DM-Pap's Package Store\Enviro\CAD\Paps Package Base Map - 2023.01.dwg- May 26, 2023 - LALLYN1"=30 'GRAPHIC SCALE
1 inch = 30 ft.
3015 600 MMLADRAWN BY:5/23/2323-0307-DM7SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:DISSOLVED MTBEISOCONCENTRATIONMAP - MAY 2023WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
DISSOLVED MTBE CONCENTRATION (ug/L)
ESTIMATED EXTENT OF MTBE IMPACTS
ABOVE 2L STANDARDS - DASHED WHERE
INFERRED
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC31.2
MW-1
S. MAIN STREETMc
C
O
L
L
U
M
S
T
R
E
E
T
550
550 2000
FORMER USTS
FORMER DISPENSER
ISLAND
FORMER
PRODUCT
LINES
SITE
PROPOSED
MONITORING
WELL
MW-2
13,100
<0.500
<0.500
MW-3
5,000 ug/L J:\23\0307-DM-Pap's Package Store\Enviro\CAD\Paps Package Base Map - 2023.01.dwg- May 26, 2023 - LALLYN1"=30 'GRAPHIC SCALE
1 inch = 30 ft.
3015 600 MMLADRAWN BY:5/23/2323-0307-DM8SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:PROPOSED MONITORING WELL LOCATIONWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.comLEGEND
TYPE II MONITORING WELL LOCATION
DISSOLVED BENZENE CONCENTRATION (ug/L)
ESTIMATED EXTENT OF BENZENE IMPACTS
ABOVE GCL - DASHED WHERE INFERRED
NOTES:
1.) 2010 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.PAP'S PACKAGE STORENCDEQ INCIDENT # 13017716 SOUTH MAIN STREETRANDLEMAN, RANDOLPH COUNTY, NC13,100
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TABLES
UST IDNumberCurrent/LastContents*PreviousContents*Capacity(in gallons)ConstructionDetails**TankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUST***Was release associated with UST System? (Y/N)1 Gasoline Unknown 550Single‐walled steel46" x 74"Single‐walled steel piping5/9/1970Permanently Closed by Removal (7/28/1994)Y2 Gasoline Unknown 2,000Single‐walled steel5'4" x 12'Single‐walled steel piping5/9/1970Permanently Closed by Removal (7/28/1994)N3 Gasoline Unknown 550Single‐walled steel46" x 74"Single‐walled steel piping5/9/1970Permanently Closed by Removal (7/28/1994)NIncidentNumberMaterialReleasedDateofRelease13017 Gasoline UnknownNotes:1.)Table B‐1Site History: UST/AST System & Other Release InformationPap's Package StoreRelease identified during the UST removal activities conducted in 1994. TPH‐GRO was detected from beneath the pump island at 1,240 mg/kg, beneath the westernmost UST at 41 mg/kg, and beneath the product line at 31 mg/kg.Information regarding USTs was obtained from the UST Facility Database and the UST‐2 form available on Laserfiche.716 S. Main StreetRandleman, Randolph County, North CarolinaIncident Number: 13017Description of ReleaseFacility ID # 00‐0‐0000019717
CalculatedAcetoneBenzenen‐Butylbenzenesec‐Butylbenzene1,2‐Dibromoethane1,2‐DichloroethaneEthylbenzeneDi‐isopropyl etherIsopropylbenzenep‐Isopropyltoluene2‐Hexanone2‐Butanone (MEK)Methyl tert‐butyl ether4‐Methyl‐2‐pentanone (MIBK)Naphthalenen‐PropylbenzeneStyreneToluene1,2,4‐Trimethylbenzene1,3,5‐Trimethylbenzenem&p‐Xyleneso‐XyleneTotal Xylenes67‐64‐171‐43‐2 104‐51‐135‐98‐106‐93‐4 107‐06‐100‐41‐108‐20‐98‐82‐899‐87‐6 591‐78‐78‐93‐3 1634‐04‐108‐10‐91‐20‐3 103‐65‐100‐42‐108‐88‐95‐63‐6 108‐67‐1330‐20‐95‐47‐6NA5/9/2006NA12,000<50 <5070360 2,700 710 140NA NA NA12,000NA800 340<5051,000 2,600 690NR NR13,50012/19/20221,62012,40016.6 13.4<5.00 <5.002,460 973 108 11.5 457 882 7,700 338 490 259 7.74 30,300 2,050 445 7,100 3,470 10,6005/4/2023<100013,100<50.0 <498 <50.0 <50.02,960 1,150 145<50.01170 1,100 6,280<100692 365<50.025,200 2,570 684 8,140 4,030 12,200MW‐25/4/2023<10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <1.00 <1.00 <1.00 <0.500 <0.5002.63<0.500 <0.500 <1.00 <0.500 <0.500MW‐35/4/2023<10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.0031.2<1.00 <1.00 <0.500 <0.5000.715<0.500 <0.500 <1.00 <0.500 <0.5006000 1 70 70 0.02 0.4 600 70 70 25 40 4000 20 100 6 70 70 600 400 400 500 5005006,000,000 5,000 5,900 8,800 50 400 80,000 70,000 30,500 11,700 40,000 4,000,000 20,000 100,000 6,000 26,100 70,000 260,000 28,500 24,100 85,500 85,50050000Notes:1)2)3)NC 2L Standard - North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L4)NL= Not ListedND= Compound Not Detected.NR= Compound Not Reported By Previous ConsultantsResult= Result Exceeds Laboratory Detection LimitsResult= Result Exceeds 2L StandardResult= Result Exceeds GCL ValuePap's Package StoreIncident Number: 13017716 S. Main Street NC 2L Standard (μg/L)GCLs for Groundwater (μg/L)MW‐1TABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSRandleman, Randolph County, North CarolinaGCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for GroundwaterCompounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents. Sample ID CollectedLaboratory MethodAll results provided in ug/L (micrograms per liter) or parts per billionSM6200B
SW‐1 7764097693142 McCollum StreetRandleman, NCChristopher M. Cagle142 McCollum StreetRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 500 ft. NW Not determinedSW‐2 7764184863155 Kirkman PlaceRandleman, NCChad Ray Garner155 Kirkman PlaceRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 600 ft. SE Not determinedSW‐3 7764088653105 Melody Ln. & 726/728 S. Main St.Randleman, NCRichard L. Frazier, Sr.1064 Turner Dairy RoadRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 650 ft. SW Not determinedSW‐4 7764183612139 Homer LaneRandleman, NCKansas Akin139 Homer LnRandleman, NC 27317Potable (Active)Unknown Unknown 775 ft. SE Not determinedSW‐5 7764182471144 Homer LaneRandleman, NCZachary W. York144 Homer LaneRandleman, NC 27317Potable (Active)Unknown Unknown 800 ft. S Not determinedSW‐6 7764184664153 Homer LaneRandleman, NCJody Roger WilliamsonKaterna Tyrrell153 Homer LaneRandleman, NC 27317Potable (Active)Unknown Unknown 820 ft. SE Not determinedSW‐7 7764185424148 Homer LaneRandleman, NCKenneth Watford182 Homer LaneRandleman, NC 27317Potable (Active)Unknown Unknown 830 ft. SE Not determinedSW‐8 7764186604171 Homer LaneRandleman, NCTerri Boyd Walker171 Homer LaneRandleman, NCPotable (Active)Unknown Unknown 885 ft. SE Not determinedSW‐9 7764187453182 Homer LaneRandleman, NCKenneth Watford182 Homer LaneRandleman, NC 27317Potable (Active)Unknown Unknown 980 ft. SE Not determinedSW‐10 7764091167315 McCollum StreetRandleman, NCScotty Kinney315 McCollum StreetRandleman, NCPotable (Active)Unknown Unknown 981 ft. W Not determinedSW‐11 7764093612443 McCollum StreetRandleman, NCKathryn & Brandon Stillinger443 McCollum StreetRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 900 ft. WNW Not determinedSW‐12SW‐13SW‐147764093704427 McCollum StreetRandleman, NCJoey & Mary Lou Ball421 McCollum StreetRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 990 ft. WNW Not determinedSW‐15 7764091319312 McCollum StreetRandleman, NCSamuel E. Bailey312 McCollum StreetRandleman, NC 27317Potable (Active)Unknown Unknown 1000 ft. W Not determinedSW‐16 7764091546446 McCollum StreetRandleman, NCDiana Garcia1425 Elgin AvenueHigh Point, NC 27262Potable (Active)Unknown Unknown 1045 ft. WNW Not determinedSW‐17 7764182244141 Worthville RoadRandleman, NCEmeruwa O. Rose141 Worthville RoadRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 1045 ft. SSE Not determinedSW‐18 7764184201175 Worthville RoadRandleman, NCClarence Jernigan100 S. Coble StreetRandleman, NC 27317Inactive per property owner, indicated no well on propertyUnknown Unknown 1070 ft. SSE Not determinedSW‐19 7764090240317 McCollum StreetRandleman, NCMagnolia Homes of the Triad, LLCPO BOX 145Jamestown, NC 27282Potable (Active)Unknown Unknown 1080 ft. W Not determinedSW‐20 7765003060421 McCollum StreetRandleman, NCJoey & Mary Lou Ball Life Estates421 McCollum StreetRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 1080 ft. NE Not determinedSW‐21 7764185169177 Worthville RoadRandleman, NCVenita Lucas177 Worthville RoadRandleman, NC 27317Connected to Municipal Water (Inactive)Unknown Unknown 1175 ft. SSE Not determinedSW‐22 7764090795402 McCollum StreetRandleman, NCVerla M. Smith Life Estate402 McCollum StreetRandleman, NCConnected to Municipal Water (Inactive)Unknown Unknown 1245 ft. NW Not determinedSW‐23 7764090849409 McCollum StreetRandleman, NCPatricia Craven409 McCollum StreetRandleman, NCConnected to Municipal Water (Inactive)Unknown Unknown 1300 ft. NW Not determinedTABLE B‐5APUBLIC & PRIVATE WATER SUPPLY WELL INFORMATIONWell IDProperty OwnerParcelNumber 3.) See Figure 3 for water supply well locations. Notes: 1.) Well location addresses and property owner information was obtained from the Randolph County GIS DepartmentProperty AddressPap's Package StoreWell Depth(feet)Incident Number: 13017Well Screen Interval(feet)Well UseProperty Owner AddressWell Distance from Source Area(feet)Location Relative to Groundwater FlowRandleman, Randolph County, North Carolina 2.) Information regarding the water supply well's use and location was obtained from the July 26, 2006 Limited Site Assessment Report by Pyramid Environmental & Engineering, P.C. Locations of wells, ownership information, and additional wells were identified by WR in December 2022 during a Receptor Survey Update.716 S. Main StreetPage 1 of 1
MW‐1 5/5/2006 2 30 10 10 ‐ 30 100.00 5/4/2023 23.67 NM 76.33MW‐2 5/3/2023 2 33 18 18‐33 98.23 5/4/2023 21.08 NM 77.15MW‐2 5/3/2023 2 33 18 18‐33 99.70 5/4/2023 22.40 NM 77.30Pap's Package Store 2.) The Top‐of‐Casing elevations are relative to the approximate site elevation feet above mean sea level. 1.) Well construction information for MW‐1 was obtained from previous consultants reports.TABLE B‐7716 S. Main StreetMONITORING & REMEDIATION WELL CONSTRUCTION INFORMATIONWell Casing Diameter(inches)LNAPL Thickness(feet)Incident Number: 13017Randleman, Randolph County, North CarolinaWell Casing Depth (feet)Date InstalledTop‐of‐Casing Elevation (feet)Total Depth (feet)Date Water Level Measured 5.) NM = Not Measured.Notes: Well IDGroundwaterElevation (feet)Depth‐to‐Water from Top‐of‐Casing(feet)Screened Interval (feet) 3.) Groundwater elevation calculated by: (Top‐of‐Casing ‐ Depth‐to‐Water) + (LNAPL Thickness x 0.8581). 4.) N/A = Not Applicable.
Well IDTop‐of‐Casing Elevation (feet)Screened IntervalDate Water Level MeasuredDepth‐to‐LNAPL(feet)Depth‐to‐WaterUncorrected(feet)LNAPL Thickness(feet)Depth‐to‐WaterCorrected(feet)Groundwater SurfaceElevation (feet)5/9/2006 NM 25.46‐‐‐25.46 74.5412/19/2022 NM 28.59‐‐‐28.59 71.415/4/2023 NM 23.67‐‐‐23.67 76.33MW‐2 98.23 18‐33 5/4/2023 NM 21.08‐‐‐21.08 77.15MW‐3 99.70 18‐33 5/4/2023 NM 22.40‐‐‐22.40 77.30 5.) NS = Not Surveyed.Notes: 3.) NM = Not Measured. 4.) LNAPL = Light Non‐Aqueous Phase Liquid. 1.) Well construction information for MW‐1 was obtained from previous consultants reports. 2.) Groundwater elevation calculated by: (Top‐of‐Casing ‐ Depth‐to‐Water) + (LNAPL Thickness x 0.8581).TABLE B‐9CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & LNAPL THICKNESSPap's Package Store716 S. Main StreetRandleman, Randolph County, North Carolina100.00MW‐1Incident Number: 1301710‐30Page 1 of 1
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APPENDIX A
AFVR CALCULATIONS
AGGRESSIVE FLUID VAPOR RECOVERY EVENT
SITE NAME:Former Pap's Package Store
INCIDENT NUMBER:13017
AVERAGE DEPTH TO GROUNDWATER: MW‐1: 25 feet bgs
INDICATE AVERAGE HYDRAULIC CONDUCTIVITY (if known):‐
IDENTIFY THE WELL I.D. OF EACH WELL USED FOR AFVR: MW‐1 (2")
TOTAL GALLONS OF PRODUCT/WATER RECOVERED IN AFVR TRUCK TANK (gallons): 241
DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd)
Date Time Vacuum Velocity Pipe ID Temp Rel Humid Water Qstd(inches of Hg) (ft/min) (in) (°F) (%) Vapor (Vol%) (flow)
3/22/2023 8:15 15.00 70 4 58.3 100 0 6
8:30 20.00 82 4 58.9 100 0 7
8:45 20.00 141 4 64.5 99.7 0 12
9:00 20.00 135 4 80.2 89.3 0 12
9:15 20.00 114 4 80.5 98.2 0 10
9:30 20.00 146 4 84.8 99.8 0 12
9:45 20.00 163 4 73.4 100 0 14
10:00 20.00 159 4 99.7 100 0 13
10:15 20.00 153 4 112.8 100 0 12
10:45 19.00 165 4 118.2 100 0 13
11:15 19.00 156 4 118.5 100 0 12
11:45 18.00 250 4 128.3 100 0 20
12:15 18.00 323 4 139.4 100 0 25
12:45 18.00 351 4 108.2 100 0 28
13:15 18.00 346 4 110.9 100 0 28
13:45 18.00 334 4 119.1 100 0 27
14:15 19.00 237 4 118.2 100 0 19
14:45 19.00 175 4 122.1 100 0 14
15:15 19.00 205 4 125.6 100 0 16
15:45 19.00 231 4 130.6 100 0 18
16:15 19.00 235 4 129.4 100 0 18
NOTES
Qstd = Flow at DSCFM
Vacuum = The level of vacuum being applied should be recorded from the vacuum truck tank (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge piping (from the vacuum truck)
Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Bwsw = water vapor % by weight, i.e., pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity)
Bws = water vapor % by volume
EQUATIONS
Bws = (Bwsw/18 lb‐mole H20)/[(1/28.84 lb‐mole dry air) + (Bwsw/18 lb‐mole H2O)]
Qstd = (1‐Water Vapor) * velocity * (PI * (diameter/24)2) * (528°R/(Temp + 460))
Page 1 of 2
AGGRESSIVE FLUID VAPOR RECOVERY EVENT
SITE NAME:Former Pap's Package Store
INCIDENT NUMBER:13017
AVERAGE DEPTH TO GROUNDWATER: MW‐1: 25 feet bgs
INDICATE AVERAGE HYDRAULIC CONDUCTIVITY (if known):‐
IDENTIFY THE WELL I.D. OF EACH WELL USED FOR AFVR: MW‐1 (2")
TOTAL GALLONS OF PRODUCT/WATER RECOVERED IN AFVR TRUCK TANK (gallons): 241
EMISSION CALCULATIONS
Elapsed
Time Flow PPMmeasured PPMwet PPMdry K PPMconc Cc:m Cc PMRc PMRg PMR
(min) (DSCFM) (ppm) (#C ‐ gas)(mg/dsm3)(lb/dscf) (lb/hr) (lb/hr) (lb)
0 6 15000 15000 15000 4 60000 29938 0.00186901 0.70 0.81 0
15 7 4896 4896 4896 4 19584 9772 0.00061004 0.27 0.31 0.08
30 12 3575 3575 3575 4 14300 7135 0.00044545 0.33 0.38 0.10
45 12 2350 2350 2350 4 9400 4690 0.00029281 0.20 0.23 0.06
60 10 1156 1156 1156 4 4624 2307 0.00014404 0.08 0.10 0.02
75 12 2964 2964 2964 4 11856 5916 0.00036932 0.27 0.32 0.08
90 14 1169 1169 1169 4 4676 2333 0.00014566 0.12 0.14 0.04
105 13 1253 1253 1253 4 5012 2501 0.00015612 0.12 0.14 0.04
120 12 981 981 981 4 3924 1958 0.00012223 0.09 0.10 0.03
150 13 919 919 919 4 3676 1834 0.00011451 0.09 0.10 0.05
180 12 912 912 912 4 3648 1820 0.00011364 0.08 0.10 0.05
210 20 887 887 887 4 3548 1770 0.00011052 0.13 0.15 0.08
240 25 1552 877 877 4 3508 1750 0.00010927 0.16 0.19 0.09
270 28 1479 921 921 4 3684 1838 0.00011476 0.20 0.23 0.11
300 28 1043 918 918 4 3672 1832 0.00011438 0.19 0.22 0.11
330 27 1052 904 904 4 3616 1804 0.00011264 0.18 0.21 0.10
360 19 1641 967 967 4 3868 1930 0.00012049 0.14 0.16 0.08
390 14 1361 972 972 4 3888 1940 0.00012111 0.10 0.12 0.06
420 16 1845 977 977 4 3908 1950 0.00012173 0.12 0.14 0.07
450 18 1178 985 985 4 3940 1966 0.00012273 0.13 0.15 0.08
480 18 1423 991 991 4 3964 1978 0.00012348 0.14 0.16 0.08
Total emissions in pounds 1.39
Gallons of Gasoline Removed:
=Gallons = 0.74*8.34lbs/gallon
0.222708 Gallons of Gasoline Removed as Vapor
NOTES
PPMmeasured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
PPMwet = "wet" concentration
PPMdry = "dry" concentration
K = Number of carbons in calibration gas: (Methane K = 1, Propane K = 3, Isobutylene = 4, Hexane K = 6)
PPMc= PPMv, Volumetric concentration of VOC emissions as carbon, dry basis at STP
Cc:m = mg/dsm3, mass concentration of VOC emissions as carbon
Mc = 12.01 mg/mg‐mole, molecular weight of carbon
K3 = 24.07 dsm3/106 mg‐mole, mass to volume conversion factor at STP
Cc = lb/dcsf, mass concentration of VOC emissions as carbon, dry basis at STP
PMRc = lb/hr, pollutant mass removal rate of VOC's as carbon
PMRg = lb/hr, pollutant mass removal rate of of VOC's as gasoline
PMR = lb, pollutant mass removal of VOC's as gasolineEQUATIONS
PPMwet = PPMmeasured Cc = (Cc:m)(62.43x10‐9 lb‐m3/mg‐ft3)
PPMdry = (PPMwet)/(1‐Bws) PMRc = (Cc)(Qstd)(60 min/hr)
PPMc = (PPMd)(K) PMRg = (PMRc)(Mg/Mcg)
Cc:m = (PPMc)(Mc / K3) PMR = (PMRg)(#minutes/60)
Page 2 of 2
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APPENDIX B
FIELD NOTES & PHOTOGRAPHIC RECORD
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Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
PHOTO 1
March 2023 AFVR Event
PHOTO 2
Location of MW‐2
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Pap’s Package Store – NCDEQ Inc. #13017 WR Project # 23‐0307‐DM
Groundwater Monitoring Report June 2023
PHOTO 3
March 2023 AFVR Event
PHOTO 4
Location of 55‐gallon drums facing east
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APPENDIX C
CERTIFICATES OF DISPOSAL AND MANIFESTS
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APPENDIX D
BORING LOGS & WELL CONSTRUCTION RECORDS
Job Name:
Site Loc.:
Driller:
PID
(ppm)
---
---
---
---
0.0
---
---
---
---
2.1
---
---
---
---
6.6
---
---
---
---
18.7
---
---
---
---
---
---
---
---
---
---
---
---
---
Notes:
16-33 ft Clean-Washed Torpedo SAND
12-16 ft Bentonite
0-12 ft Concrete Grout
= Groundwater Level (Measured Beneath TOC)
10' - 15'
15'-33'
18-33 ft 2" Dia.
0.010-Slot PVC
Well Screen
2.) TOC - Top of Casing
Page 1 of 1
Red, tan silty clay, wet
22
23
115 MacKenan Drive Cary, North Carolina 27511 tel:919.469.3340 fax:919.467.6008 www.withersravenel.com
0-18 ft 2" Dia.
PVC Casing
31
32
Red, tan silty clay, dry
33
1.) BGS - Below Ground Surface
21
30
24
25
26
27
28
29
15
16
17
18
19
20
7
8
9
10
11
12
13
14
1
0' - 10'
2
3
4
5
6
Red, tan silty clay, moist
Approximate Latitude:35.806238 Approximate Longitude:-79.805552
Depth in
Feet Soil Description
(Field USCS Classification)
Well Construction
0 Ground Surface
Date:May 3, 2023 Randleman, NC TOC EL:98.23
WR Rep:S. Powell AmeriProbe LLC GW EL:77.15
WELL CONSTRUCTION LOG
Well ID:MW-2 Former Pap's Package Store Job #:23-0307-DM
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Job Name:
Site Loc.:
Driller:
PID
(ppm)
---
---
---
---
258.2
---
---
---
---
214.7
---
---
---
---
220.3
---
---
---
---
228.2
---
---
---
---
163.9
---
---
---
---
---
---
---
---
Notes:
= Groundwater Level (Measured Beneath TOC)
12-16 ft Bentonite
0-12 ft Concrete Grout
WELL CONSTRUCTION LOG
Well ID:MW-3 Former Pap's Package Store Job #:23-0307-DM
Date:May 3, 2023 Randleman, NC TOC EL:99.70
WR Rep:S. Powell AmeriProbe LLC GW EL:77.30
Approximate Latitude:35.806123 Approximate Longitude:-79.805377
Depth in
Feet Soil Description
(Field USCS Classification)
Well Construction
0 Ground Surface
1
0-18 ft 2" Dia.
PVC Casing
2
3
4
5
6
7
8
9
10
15' - 20'
11
12
13
14
15
16
17
18
27
20
21
22
23
16-33 ft Clean-Washed Torpedo SAND24
25
26
28
29
2.) TOC - Top of Casing
Page 1 of 1
30
31
32
33
18-33 ft 2" Dia.
0.010-Slot PVC
Well Screen
19
115 MacKenan Drive Cary, North Carolina 27511 tel:919.469.3340 fax:919.467.6008 www.withersravenel.com
Red, tan silty clay, moist, slight odor
Red, tan silty clay, moist to wet
Red, tan silty clay, wet
0' - 15'
20'-33'
1.) BGS - Below Ground Surface
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WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016
1. Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
□Agricultural □Municipal/Public
□Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared)
□Irrigation
Non-Water Supply Well:
□Monitoring □Recovery
Injection Well:
□Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier
□Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer
□Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: Well ID#
5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
N W
6. Is(are) the well(s): □Permanent or □Temporary
7. Is this a repair to an existing well: □Yes or □No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:
9. Total well depth below land surface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10. Static water level below top of casing: (ft.)
If water level is above casing, use “+”
11. Borehole diameter: (in.)
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN
FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary)
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS
22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well construction to the county health department of the county
where constructed.
John Allen
4196-B
AmeriProbe
TF# 13017
5/3/23 MW-2
Pap's Package
716 S Main St., Randleman, NC 27317
Randolph
35.8061206 79.8054466
33'
24'
8''
Auger
5/30/23
24 33
0 18 2''SCH40 PVC
18 33 2''0.010 SCH40 PVC
0
12
16
12
16
33
Neat Cement
Bentonite
#2 Sand Poured Through Augers
Poured Through Augers
See Consultant's Logs
2' X 2' Concrete Flushmount Pad
Print Form
Poured Through Augers
WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016
1. Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
□Agricultural □Municipal/Public
□Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared)
□Irrigation
Non-Water Supply Well:
□Monitoring □Recovery
Injection Well:
□Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier
□Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer
□Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: Well ID#
5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
N W
6. Is(are) the well(s): □Permanent or □Temporary
7. Is this a repair to an existing well: □Yes or □No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:
9. Total well depth below land surface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10. Static water level below top of casing: (ft.)
If water level is above casing, use “+”
11. Borehole diameter: (in.)
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN
FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary)
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS
22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well construction to the county health department of the county
where constructed.
John Allen
4196-B
AmeriProbe
TF# 13017
5/3/23 MW-3
Pap's Package
716 S Main St., Randleman, NC 27317
Randolph
35.8061937 79.8055522
33'
23'
8''
Auger
5/30/23
23 33
0 18 2''SCH40 PVC
18 33 2''0.010 SCH40 PVC
0
12
16
12
16
33
Neat Cement
Bentonite
#2 Sand Poured Through Augers
Poured Through Augers
See Consultant's Logs
2' X 2' Concrete Flushmount Pad
Print Form
Poured Through Augers
WithersRavenel
Our People. Your Success.
APPENDIX E
LABORATORY ANALYTICAL REPORT & CHAIN OF CUSTODY
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
5/12/2023
Withers & Ravenel Liz Allyn
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 23-125-0020 Client Project Description: Pap's Packaging Store
23-0307-DM
Dear Liz Allyn:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/5/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 30
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-125-0020
Page 2 of 30
Report Number:
Sample Summary Table
Client Project Description:
23-125-0020
Pap's Packaging Store
23-0307-DM
Lab No Client Sample ID Matrix Date Collected Date Received
05/04/2023 15:00Aqueous 95571 MW-1 05/05/2023 13:20
05/04/2023 16:35Aqueous 95572 MW-2 05/05/2023 13:20
05/04/2023 15:45Aqueous 95573 MW-3 05/05/2023 13:20
Page 3 of 30
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-125-0020
Report Limit
Project:Pap's Packaging Store
V 95571MW-1
13100 05/10/2023 19:376200BBenzeneµg/L 500
1150 05/10/2023 19:126200BDi-Isopropyl Ether (DIPE)µg/L 50.0
2960 05/10/2023 19:126200BEthylbenzeneµg/L 50.0
1170 05/10/2023 19:126200B2-Hexanone µg/L 100
145 05/10/2023 19:126200BIsopropylbenzeneµg/L 50.0
1100 05/10/2023 19:126200BMethyl Ethyl Ketone (MEK)µg/L 500
6280 05/10/2023 19:126200BMethyl tert-butyl ether (MTBE)µg/L 100
692 05/10/2023 19:126200BNaphthaleneµg/L 100
365 05/10/2023 19:126200Bn-Propylbenzene µg/L 50.0
25200 05/10/2023 19:376200BTolueneµg/L 500
2570 05/10/2023 19:126200B1,2,4-Trimethylbenzene µg/L 50.0
684 05/10/2023 19:126200B1,3,5-Trimethylbenzene µg/L 50.0
4030 05/10/2023 19:126200Bo-Xylene µg/L 50.0
8140 05/10/2023 19:126200Bm,p-Xylene µg/L 100
12200 05/10/2023 19:126200BXylene (Total)µg/L 50.0
V 95572MW-2
2.63 05/09/2023 22:056200BTolueneµg/L 0.500
V 95573MW-3
31.2 05/09/2023 22:326200BMethyl tert-butyl ether (MTBE)µg/L 1.00
0.715 05/09/2023 22:326200BTolueneµg/L 0.500
Page 4 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-1
95571 Matrix:
5/4/2023 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 µg/L 1000Acetone 100 05/10/23 19:12 6200BMSA
13100 µg/L 500Benzene 1000 05/10/23 19:37 6200BMSA
<50.0 µg/L 50.0Bromobenzene 100 05/10/23 19:12 6200BMSA
<100 µg/L 100Bromochloromethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Bromodichloromethane 100 05/10/23 19:12 6200BMSA
<500 µg/L 500Bromoform 100 05/10/23 19:12 6200BMSA
<100 µg/L 100Bromomethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0n-Butylbenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0sec-Butyl benzene 100 05/10/23 19:12 6200BMSA
<200 µg/L 200tert-Butyl benzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Carbon Tetrachloride 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Chlorobenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Chlorodibromomethane 100 05/10/23 19:12 6200BMSA
<100 µg/L 100Chloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Chloroform 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Chloromethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.02-Chlorotoluene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.04-Chlorotoluene 100 05/10/23 19:12 6200BMSA
<200 µg/L 2001,2-Dibromo-3-Chloropropane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2-Dibromoethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Dibromomethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2-Dichlorobenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,3-Dichlorobenzene 100 05/10/23 19:12 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 5 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-1
95571 Matrix:
5/4/2023 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<50.0 µg/L 50.01,4-Dichlorobenzene 100 05/10/23 19:12 6200BMSA
<500 µg/L 500Dichlorodifluoromethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2-Dichloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0cis-1,2-Dichloroethene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0trans-1,2-Dichloroethene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2-Dichloropropane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,3-Dichloropropane 100 05/10/23 19:12 6200BMSA
<200 µg/L 2002,2-Dichloropropane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloropropene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0cis-1,3-Dichloropropene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0trans-1,3-Dichloropropene 100 05/10/23 19:12 6200BMSA
<20000 µg/L 20000Ethanol 100 05/10/23 19:12 6200BMSA
2960 µg/L 50.0Ethylbenzene 100 05/10/23 19:12 6200BMSA
<300 µg/L 300Hexachlorobutadiene 100 05/10/23 19:12 6200BMSA
1150 µg/L 50.0Di-Isopropyl Ether (DIPE)100 05/10/23 19:12 6200BMSA
145 µg/L 50.0Isopropylbenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.04-Isopropyl toluene 100 05/10/23 19:12 6200BMSA
1170 µg/L 1002-Hexanone 100 05/10/23 19:12 6200BMSA
1100 µg/L 500Methyl Ethyl Ketone (MEK)100 05/10/23 19:12 6200BMSA
<200 µg/L 200Methylene Chloride 100 05/10/23 19:12 6200BMSA
6280 µg/L 100Methyl tert-butyl ether (MTBE)100 05/10/23 19:12 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-1
95571 Matrix:
5/4/2023 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 1004-Methyl-2-Pentanone 100 05/10/23 19:12 6200BMSA
692 µg/L 100Naphthalene 100 05/10/23 19:12 6200BMSA
365 µg/L 50.0n-Propylbenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Styrene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Tetrachloroethene 100 05/10/23 19:12 6200BMSA
25200 µg/L 500Toluene 1000 05/10/23 19:37 6200BMSA
<50.0 µg/L 50.01,2,3-Trichlorobenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2,4-Trichlorobenzene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1,1-Trichloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,1,2-Trichloroethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Trichloroethene 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Trichlorofluoromethane 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.01,2,3-Trichloropropane 100 05/10/23 19:12 6200BMSA
2570 µg/L 50.01,2,4-Trimethylbenzene 100 05/10/23 19:12 6200BMSA
684 µg/L 50.01,3,5-Trimethylbenzene 100 05/10/23 19:12 6200BMSA
<500 µg/L 500Vinyl Acetate 100 05/10/23 19:12 6200BMSA
<50.0 µg/L 50.0Vinyl Chloride 100 05/10/23 19:12 6200BMSA
8140 µg/L 100m,p-Xylene 100 05/10/23 19:12 6200BMSA
4030 µg/L 50.0o-Xylene 100 05/10/23 19:12 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-1
95571 Matrix:
5/4/2023 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
12200 µg/L 50.0Xylene (Total)100 05/10/23 19:12 6200B
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%05/10/23 19:12100 MSA V33045
Surrogate: Dibromofluoromethane 92.2 Limits: 70-130%05/10/23 19:12100 MSA V33045
Surrogate: 1,2-Dichloroethane - d4 92.0 Limits: 70-130%05/10/23 19:12100 MSA V33045
Surrogate: Toluene-d8 95.0 Limits: 70-130%05/10/23 19:12100 MSA V33045
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%05/10/23 19:371000 MSA V33045
Surrogate: Dibromofluoromethane 91.8 Limits: 70-130%05/10/23 19:371000 MSA V33045
Surrogate: 1,2-Dichloroethane - d4 89.2 Limits: 70-130%05/10/23 19:371000 MSA V33045
Surrogate: Toluene-d8 96.2 Limits: 70-130%05/10/23 19:371000 MSA V33045
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-2
95572 Matrix:
5/4/2023 16:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Benzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 05/09/23 22:05 6200BMSA
<5.00 µg/L 5.00Bromoform 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 05/09/23 22:05 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Chloroform 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 05/09/23 22:05 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 05/09/23 22:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 9 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-2
95572 Matrix:
5/4/2023 16:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 05/09/23 22:05 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 05/09/23 22:05 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 05/09/23 22:05 6200BMSA
<200 µg/L 200Ethanol 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 05/09/23 22:05 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 05/09/23 22:05 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 05/09/23 22:05 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 05/09/23 22:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 10 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-2
95572 Matrix:
5/4/2023 16:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Styrene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 05/09/23 22:05 6200BMSA
2.63 µg/L 0.500Toluene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 05/09/23 22:05 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 05/09/23 22:05 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 05/09/23 22:05 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 05/09/23 22:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 11 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-2
95572 Matrix:
5/4/2023 16:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 05/09/23 22:05 6200B
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%05/09/23 22:051 MSA V32988
Surrogate: Dibromofluoromethane 105 Limits: 70-130%05/09/23 22:051 MSA V32988
Surrogate: 1,2-Dichloroethane - d4 112 Limits: 70-130%05/09/23 22:051 MSA V32988
Surrogate: Toluene-d8 98.0 Limits: 70-130%05/09/23 22:051 MSA V32988
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 12 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-3
95573 Matrix:
5/4/2023 15:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Benzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 05/09/23 22:32 6200BMSA
<5.00 µg/L 5.00Bromoform 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 05/09/23 22:32 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Chloroform 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 05/09/23 22:32 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 05/09/23 22:32 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 13 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-3
95573 Matrix:
5/4/2023 15:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 05/09/23 22:32 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 05/09/23 22:32 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 05/09/23 22:32 6200BMSA
<200 µg/L 200Ethanol 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 05/09/23 22:32 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 05/09/23 22:32 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 05/09/23 22:32 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 05/09/23 22:32 6200BMSA
31.2 µg/L 1.00Methyl tert-butyl ether (MTBE)1 05/09/23 22:32 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 14 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-3
95573 Matrix:
5/4/2023 15:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Styrene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 05/09/23 22:32 6200BMSA
0.715 µg/L 0.500Toluene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 05/09/23 22:32 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 05/09/23 22:32 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 05/09/23 22:32 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 05/09/23 22:32 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 15 of 30
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-125-0020
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Liz Allyn
Cary
23-0307-DM Received : 05/05/2023
Pap's Packaging Store
Report Date : 05/12/2023
Sample ID :
Lab No :
Sampled:MW-3
95573 Matrix:
5/4/2023 15:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 05/09/23 22:32 6200B
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%05/09/23 22:321 MSA V32988
Surrogate: Dibromofluoromethane 105 Limits: 70-130%05/09/23 22:321 MSA V32988
Surrogate: 1,2-Dichloroethane - d4 110 Limits: 70-130%05/09/23 22:321 MSA V32988
Surrogate: Toluene-d8 96.4 Limits: 70-130%05/09/23 22:321 MSA V32988
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 16 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
Associated Lab Samples: 95572, 95573
LRB-V32987 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/09/23 16:1010.0< 10.0µg/LAcetone
05/09/23 16:100.500< 0.500µg/LBenzene
05/09/23 16:100.500< 0.500µg/LBromobenzene
05/09/23 16:101.00< 1.00µg/LBromochloromethane
05/09/23 16:100.500< 0.500µg/LBromodichloromethane
05/09/23 16:105.00< 5.00µg/LBromoform
05/09/23 16:101.00< 1.00µg/LBromomethane
05/09/23 16:100.500< 0.500µg/Ln-Butylbenzene
05/09/23 16:100.500< 0.500µg/Lsec-Butyl benzene
05/09/23 16:102.00< 2.00µg/Ltert-Butyl benzene
05/09/23 16:100.500< 0.500µg/LCarbon Tetrachloride
05/09/23 16:100.500< 0.500µg/LChlorobenzene
05/09/23 16:100.500< 0.500µg/LChlorodibromomethane
05/09/23 16:101.00< 1.00µg/LChloroethane
05/09/23 16:100.500< 0.500µg/LChloroform
05/09/23 16:100.500< 0.500µg/LChloromethane
05/09/23 16:100.500< 0.500µg/L2-Chlorotoluene
05/09/23 16:100.500< 0.500µg/L4-Chlorotoluene
05/09/23 16:102.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
05/09/23 16:100.500< 0.500µg/L1,2-Dibromoethane
05/09/23 16:100.500< 0.500µg/LDibromomethane
05/09/23 16:100.500< 0.500µg/L1,2-Dichlorobenzene
05/09/23 16:100.500< 0.500µg/L1,3-Dichlorobenzene
05/09/23 16:100.500< 0.500µg/L1,4-Dichlorobenzene
05/09/23 16:105.00< 5.00µg/LDichlorodifluoromethane
05/09/23 16:100.500< 0.500µg/L1,1-Dichloroethane
05/09/23 16:100.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 12Date:05/12/2023 10:25 AM
Page 17 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
Associated Lab Samples: 95572, 95573
LRB-V32987 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/09/23 16:100.500< 0.500µg/L1,1-Dichloroethene
05/09/23 16:100.500< 0.500µg/Lcis-1,2-Dichloroethene
05/09/23 16:100.500< 0.500µg/Ltrans-1,2-Dichloroethene
05/09/23 16:100.500< 0.500µg/L1,2-Dichloropropane
05/09/23 16:100.500< 0.500µg/L1,3-Dichloropropane
05/09/23 16:102.00< 2.00µg/L2,2-Dichloropropane
05/09/23 16:100.500< 0.500µg/L1,1-Dichloropropene
05/09/23 16:100.500< 0.500µg/Lcis-1,3-Dichloropropene
05/09/23 16:100.500< 0.500µg/Ltrans-1,3-Dichloropropene
05/09/23 16:10200< 200µg/LEthanol
05/09/23 16:100.500< 0.500µg/LEthylbenzene
05/09/23 16:103.00< 3.00µg/LHexachlorobutadiene
05/09/23 16:100.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
05/09/23 16:100.500< 0.500µg/LIsopropylbenzene
05/09/23 16:100.500< 0.500µg/L4-Isopropyl toluene
05/09/23 16:101.00< 1.00µg/L2-Hexanone
05/09/23 16:105.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
05/09/23 16:102.00< 2.00µg/LMethylene Chloride
05/09/23 16:101.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
05/09/23 16:101.00< 1.00µg/L4-Methyl-2-Pentanone
05/09/23 16:101.00< 1.00µg/LNaphthalene
05/09/23 16:100.500< 0.500µg/Ln-Propylbenzene
05/09/23 16:100.500< 0.500µg/LStyrene
05/09/23 16:100.500< 0.500µg/L1,1,1,2-Tetrachloroethane
05/09/23 16:100.500< 0.500µg/L1,1,2,2-Tetrachloroethane
05/09/23 16:100.500< 0.500µg/LTetrachloroethene
05/09/23 16:100.500< 0.500µg/LToluene
Page 2 of 12Date:05/12/2023 10:25 AM
Page 18 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
Associated Lab Samples: 95572, 95573
LRB-V32987 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/09/23 16:100.500< 0.500µg/L1,2,3-Trichlorobenzene
05/09/23 16:100.500< 0.500µg/L1,2,4-Trichlorobenzene
05/09/23 16:100.500< 0.500µg/L1,1,1-Trichloroethane
05/09/23 16:100.500< 0.500µg/L1,1,2-Trichloroethane
05/09/23 16:100.500< 0.500µg/LTrichloroethene
05/09/23 16:100.500< 0.500µg/LTrichlorofluoromethane
05/09/23 16:100.500< 0.500µg/L1,2,3-Trichloropropane
05/09/23 16:100.500< 0.500µg/L1,2,4-Trimethylbenzene
05/09/23 16:100.500< 0.500µg/L1,3,5-Trimethylbenzene
05/09/23 16:105.00< 5.00µg/LVinyl Acetate
05/09/23 16:100.500< 0.500µg/LVinyl Chloride
05/09/23 16:101.00< 1.00µg/Lm,p-Xylene
05/09/23 16:100.500< 0.500µg/Lo-Xylene
05/09/23 16:104-Bromofluorobenzene (S)99.4 70-130
05/09/23 16:10Dibromofluoromethane (S)105 70-130
05/09/23 16:101,2-Dichloroethane - d4 (S)110 70-130
05/09/23 16:10Toluene-d8 (S)96.0 70-130
LCS-V32987 LCSD-V32987Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.5 91.286.734.740.0µg/LAcetone 40-160 5.0 20.0
19.6 98.099.019.820.0µg/LBenzene 70-130 1.0 20.0
20.0 10010020.020.0µg/LBromobenzene 70-130 0.0 20.0
21.3 10711322.520.0µg/LBromochloromethane 70-130 5.4 20.0
21.8 10911022.020.0µg/LBromodichloromethane 70-130 0.9 20.0
Page 3 of 12Date:05/12/2023 10:25 AM
Page 19 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
LCS-V32987 LCSD-V32987Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.4 10711523.020.0µg/LBromoform 70-130 7.2 20.0
18.8 94.094.018.820.0µg/LBromomethane 60-140 0.0 20.0
18.8 94.095.019.020.0µg/Ln-Butylbenzene 70-130 1.0 20.0
19.7 98.597.019.420.0µg/Lsec-Butyl benzene 70-130 1.5 20.0
20.5 10310220.420.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
24.9 12512424.820.0µg/LCarbon Tetrachloride 70-130 0.4 20.0
19.9 99.510120.120.0µg/LChlorobenzene 70-130 1.0 20.0
22.8 11411222.420.0µg/LChlorodibromomethane 70-130 1.7 20.0
20.5 10310821.620.0µg/LChloroethane 60-140 5.2 20.0
21.0 10511522.920.0µg/LChloroform 70-130 8.6 20.0
17.4 87.089.517.920.0µg/LChloromethane 60-140 2.8 20.0
19.7 98.597.519.520.0µg/L2-Chlorotoluene 70-130 1.0 20.0
20.0 10010120.220.0µg/L4-Chlorotoluene 70-130 0.9 20.0
20.7 10410521.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.4 20.0
20.0 10010120.220.0µg/L1,2-Dibromoethane 70-130 0.9 20.0
20.9 10510621.120.0µg/LDibromomethane 70-130 0.9 20.0
19.3 96.597.519.520.0µg/L1,2-Dichlorobenzene 70-130 1.0 20.0
20.5 10310320.620.0µg/L1,3-Dichlorobenzene 70-130 0.4 20.0
19.1 95.597.019.420.0µg/L1,4-Dichlorobenzene 70-130 1.5 20.0
17.6 88.088.017.620.0µg/LDichlorodifluoromethane 60-140 0.0 20.0
21.3 10710621.220.0µg/L1,1-Dichloroethane 70-130 0.4 20.0
21.9 11011222.420.0µg/L1,2-Dichloroethane 70-130 2.2 20.0
22.3 11211522.920.0µg/L1,1-Dichloroethene 70-130 2.6 20.0
21.0 10510220.420.0µg/Lcis-1,2-Dichloroethene 70-130 2.8 20.0
21.0 10510921.720.0µg/Ltrans-1,2-Dichloroethene 70-130 3.2 20.0
19.4 97.098.019.620.0µg/L1,2-Dichloropropane 70-130 1.0 20.0
Page 4 of 12Date:05/12/2023 10:25 AM
Page 20 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
LCS-V32987 LCSD-V32987Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.9 94.595.019.020.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
23.1 11611522.920.0µg/L2,2-Dichloropropane 70-130 0.8 20.0
22.9 11511322.620.0µg/L1,1-Dichloropropene 70-130 1.3 20.0
21.3 10710320.620.0µg/Lcis-1,3-Dichloropropene 70-130 3.3 20.0
21.0 10510921.720.0µg/Ltrans-1,3-Dichloropropene 70-130 3.2 20.0
426 85.293.2466500µg/LEthanol 60-140 8.9 20.0
20.2 10110020.020.0µg/LEthylbenzene 70-130 0.9 20.0
22.1 11111021.920.0µg/LHexachlorobutadiene 70-130 0.9 20.0
19.4 97.097.519.520.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.5 20.0
20.6 10310320.520.0µg/LIsopropylbenzene 70-130 0.4 20.0
20.7 10410721.320.0µg/L4-Isopropyl toluene 70-130 2.8 20.0
17.4 87.085.517.120.0µg/L2-Hexanone 60-140 1.7 20.0
16.5 82.582.516.520.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0
20.2 10110020.020.0µg/LMethylene Chloride 70-130 0.9 20.0
21.0 10510521.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.0 20.0
17.5 87.588.017.620.0µg/L4-Methyl-2-Pentanone 60-140 0.5 20.0
16.5 82.578.515.720.0µg/LNaphthalene 70-130 4.9 20.0
19.4 97.097.519.520.0µg/Ln-Propylbenzene 70-130 0.5 20.0
20.5 10397.519.520.0µg/LStyrene 70-130 5.0 20.0
22.0 11011322.520.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.2 20.0
18.5 92.592.518.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.0 20.0
22.0 11010721.320.0µg/LTetrachloroethene 70-130 3.2 20.0
19.6 98.010120.220.0µg/LToluene 70-130 3.0 20.0
22.5 11310821.620.0µg/L1,2,3-Trichlorobenzene 70-130 4.0 20.0
20.3 10210020.020.0µg/L1,2,4-Trichlorobenzene 70-130 1.4 20.0
23.5 11812023.920.0µg/L1,1,1-Trichloroethane 70-130 1.6 20.0
Page 5 of 12Date:05/12/2023 10:25 AM
Page 21 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32988QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32987
LCS-V32987 LCSD-V32987Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.1 10198.519.720.0µg/L1,1,2-Trichloroethane 70-130 2.0 20.0
22.1 11110721.420.0µg/LTrichloroethene 70-130 3.2 20.0
22.7 11411422.820.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
20.7 10410521.020.0µg/L1,2,3-Trichloropropane 70-130 1.4 20.0
19.9 99.510220.320.0µg/L1,2,4-Trimethylbenzene 70-130 1.9 20.0
20.5 10310220.320.0µg/L1,3,5-Trimethylbenzene 70-130 0.9 20.0
18.5 92.510120.220.0µg/LVinyl Acetate 60-140 8.7 20.0
18.8 94.099.019.820.0µg/LVinyl Chloride 60-140 5.1 20.0
41.8 10510541.840.0µg/Lm,p-Xylene 70-130 0.0 20.0
20.4 10210320.620.0µg/Lo-Xylene 70-130 0.9 20.0
98.61014-Bromofluorobenzene (S)70-130
102107Dibromofluoromethane (S)70-130
1081091,2-Dichloroethane - d4 (S)70-130
96.696.0Toluene-d8 (S)70-130
Page 6 of 12Date:05/12/2023 10:25 AM
Page 22 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
Associated Lab Samples: 95571
LRB-V33044 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/10/23 14:1510.0< 10.0µg/LAcetone
05/10/23 14:150.500< 0.500µg/LBenzene
05/10/23 14:150.500< 0.500µg/LBromobenzene
05/10/23 14:151.00< 1.00µg/LBromochloromethane
05/10/23 14:150.500< 0.500µg/LBromodichloromethane
05/10/23 14:155.00< 5.00µg/LBromoform
05/10/23 14:151.00< 1.00µg/LBromomethane
05/10/23 14:150.500< 0.500µg/Ln-Butylbenzene
05/10/23 14:150.500< 0.500µg/Lsec-Butyl benzene
05/10/23 14:152.00< 2.00µg/Ltert-Butyl benzene
05/10/23 14:150.500< 0.500µg/LCarbon Tetrachloride
05/10/23 14:150.500< 0.500µg/LChlorobenzene
05/10/23 14:150.500< 0.500µg/LChlorodibromomethane
05/10/23 14:151.00< 1.00µg/LChloroethane
05/10/23 14:150.500< 0.500µg/LChloroform
05/10/23 14:150.500< 0.500µg/LChloromethane
05/10/23 14:150.500< 0.500µg/L2-Chlorotoluene
05/10/23 14:150.500< 0.500µg/L4-Chlorotoluene
05/10/23 14:152.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
05/10/23 14:150.500< 0.500µg/L1,2-Dibromoethane
05/10/23 14:150.500< 0.500µg/LDibromomethane
05/10/23 14:150.500< 0.500µg/L1,2-Dichlorobenzene
05/10/23 14:150.500< 0.500µg/L1,3-Dichlorobenzene
05/10/23 14:150.500< 0.500µg/L1,4-Dichlorobenzene
05/10/23 14:155.00< 5.00µg/LDichlorodifluoromethane
05/10/23 14:150.500< 0.500µg/L1,1-Dichloroethane
05/10/23 14:150.500< 0.500µg/L1,2-Dichloroethane
Page 7 of 12Date:05/12/2023 10:25 AM
Page 23 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
Associated Lab Samples: 95571
LRB-V33044 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/10/23 14:150.500< 0.500µg/L1,1-Dichloroethene
05/10/23 14:150.500< 0.500µg/Lcis-1,2-Dichloroethene
05/10/23 14:150.500< 0.500µg/Ltrans-1,2-Dichloroethene
05/10/23 14:150.500< 0.500µg/L1,2-Dichloropropane
05/10/23 14:150.500< 0.500µg/L1,3-Dichloropropane
05/10/23 14:152.00< 2.00µg/L2,2-Dichloropropane
05/10/23 14:150.500< 0.500µg/L1,1-Dichloropropene
05/10/23 14:150.500< 0.500µg/Lcis-1,3-Dichloropropene
05/10/23 14:150.500< 0.500µg/Ltrans-1,3-Dichloropropene
05/10/23 14:15200< 200µg/LEthanol
05/10/23 14:150.500< 0.500µg/LEthylbenzene
05/10/23 14:153.00< 3.00µg/LHexachlorobutadiene
05/10/23 14:150.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
05/10/23 14:150.500< 0.500µg/LIsopropylbenzene
05/10/23 14:150.500< 0.500µg/L4-Isopropyl toluene
05/10/23 14:151.00< 1.00µg/L2-Hexanone
05/10/23 14:155.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
05/10/23 14:152.00< 2.00µg/LMethylene Chloride
05/10/23 14:151.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
05/10/23 14:151.00< 1.00µg/L4-Methyl-2-Pentanone
05/10/23 14:151.00< 1.00µg/LNaphthalene
05/10/23 14:150.500< 0.500µg/Ln-Propylbenzene
05/10/23 14:150.500< 0.500µg/LStyrene
05/10/23 14:150.500< 0.500µg/L1,1,1,2-Tetrachloroethane
05/10/23 14:150.500< 0.500µg/L1,1,2,2-Tetrachloroethane
05/10/23 14:150.500< 0.500µg/LTetrachloroethene
05/10/23 14:150.500< 0.500µg/LToluene
Page 8 of 12Date:05/12/2023 10:25 AM
Page 24 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
Associated Lab Samples: 95571
LRB-V33044 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/10/23 14:150.500< 0.500µg/L1,2,3-Trichlorobenzene
05/10/23 14:150.500< 0.500µg/L1,2,4-Trichlorobenzene
05/10/23 14:150.500< 0.500µg/L1,1,1-Trichloroethane
05/10/23 14:150.500< 0.500µg/L1,1,2-Trichloroethane
05/10/23 14:150.500< 0.500µg/LTrichloroethene
05/10/23 14:150.500< 0.500µg/LTrichlorofluoromethane
05/10/23 14:150.500< 0.500µg/L1,2,3-Trichloropropane
05/10/23 14:150.500< 0.500µg/L1,2,4-Trimethylbenzene
05/10/23 14:150.500< 0.500µg/L1,3,5-Trimethylbenzene
05/10/23 14:155.00< 5.00µg/LVinyl Acetate
05/10/23 14:150.500< 0.500µg/LVinyl Chloride
05/10/23 14:151.00< 1.00µg/Lm,p-Xylene
05/10/23 14:150.500< 0.500µg/Lo-Xylene
05/10/23 14:154-Bromofluorobenzene (S)99.2 70-130
05/10/23 14:15Dibromofluoromethane (S)91.0 70-130
05/10/23 14:151,2-Dichloroethane - d4 (S)87.6 70-130
05/10/23 14:15Toluene-d8 (S)97.2 70-130
LCS-V33044 LCSD-V33044Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
34.2 85.577.230.940.0µg/LAcetone 40-160 10.1 20.0
23.3 11712124.220.0µg/LBenzene 70-130 3.7 20.0
21.2 10610921.820.0µg/LBromobenzene 70-130 2.7 20.0
23.2 11611523.020.0µg/LBromochloromethane 70-130 0.8 20.0
22.3 11211222.420.0µg/LBromodichloromethane 70-130 0.4 20.0
Page 9 of 12Date:05/12/2023 10:25 AM
Page 25 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
LCS-V33044 LCSD-V33044Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.2 10699.519.920.0µg/LBromoform 70-130 6.3 20.0
21.9 11010621.120.0µg/LBromomethane 60-140 3.7 20.0
21.4 10711222.420.0µg/Ln-Butylbenzene 70-130 4.5 20.0
20.8 10410821.520.0µg/Lsec-Butyl benzene 70-130 3.3 20.0
20.5 10310621.220.0µg/Ltert-Butyl benzene 70-130 3.3 20.0
21.8 10911723.320.0µg/LCarbon Tetrachloride 70-130 6.6 20.0
22.0 11011623.120.0µg/LChlorobenzene 70-130 4.8 20.0
22.0 11011122.120.0µg/LChlorodibromomethane 70-130 0.4 20.0
26.3 13212625.120.0µg/LChloroethane 60-140 4.6 20.0
23.3 11712124.120.0µg/LChloroform 70-130 3.3 20.0
22.5 11310821.620.0µg/LChloromethane 60-140 4.0 20.0
21.6 10810921.820.0µg/L2-Chlorotoluene 70-130 0.9 20.0
21.3 10711222.420.0µg/L4-Chlorotoluene 70-130 5.0 20.0
20.9 10599.019.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.4 20.0
22.3 11211523.020.0µg/L1,2-Dibromoethane 70-130 3.0 20.0
23.2 11611222.420.0µg/LDibromomethane 70-130 3.5 20.0
21.7 10911122.120.0µg/L1,2-Dichlorobenzene 70-130 1.8 20.0
20.9 10510721.320.0µg/L1,3-Dichlorobenzene 70-130 1.8 20.0
20.9 10510721.420.0µg/L1,4-Dichlorobenzene 70-130 2.3 20.0
23.4 11711222.420.0µg/LDichlorodifluoromethane 60-140 4.3 20.0
23.7 11912023.920.0µg/L1,1-Dichloroethane 70-130 0.8 20.0
22.7 11411122.120.0µg/L1,2-Dichloroethane 70-130 2.6 20.0
24.4 12211923.820.0µg/L1,1-Dichloroethene 70-130 2.4 20.0
22.9 11511723.420.0µg/Lcis-1,2-Dichloroethene 70-130 2.1 20.0
23.8 11912324.620.0µg/Ltrans-1,2-Dichloroethene 70-130 3.3 20.0
23.4 11711923.820.0µg/L1,2-Dichloropropane 70-130 1.6 20.0
Page 10 of 12Date:05/12/2023 10:25 AM
Page 26 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
LCS-V33044 LCSD-V33044Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.9 11011022.020.0µg/L1,3-Dichloropropane 70-130 0.4 20.0
23.8 11912024.020.0µg/L2,2-Dichloropropane 70-130 0.8 20.0
24.5 12312324.520.0µg/L1,1-Dichloropropene 70-130 0.0 20.0
23.4 11711923.820.0µg/Lcis-1,3-Dichloropropene 70-130 1.6 20.0
23.5 11811923.820.0µg/Ltrans-1,3-Dichloropropene 70-130 1.2 20.0
476 95.288.4442500µg/LEthanol 60-140 7.4 20.0
21.7 10911222.320.0µg/LEthylbenzene 70-130 2.7 20.0
21.3 10711723.420.0µg/LHexachlorobutadiene 70-130 9.3 20.0
23.0 11511522.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.4 20.0
21.5 10811422.720.0µg/LIsopropylbenzene 70-130 5.4 20.0
21.4 10711422.720.0µg/L4-Isopropyl toluene 70-130 5.8 20.0
21.1 10610120.220.0µg/L2-Hexanone 60-140 4.3 20.0
19.8 99.093.018.620.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.2 20.0
24.1 12112124.120.0µg/LMethylene Chloride 70-130 0.0 20.0
23.6 11811422.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.4 20.0
22.0 11010621.220.0µg/L4-Methyl-2-Pentanone 60-140 3.7 20.0
21.7 10911122.220.0µg/LNaphthalene 70-130 2.2 20.0
21.3 10711021.920.0µg/Ln-Propylbenzene 70-130 2.7 20.0
21.8 10911222.420.0µg/LStyrene 70-130 2.7 20.0
22.3 11211522.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.6 20.0
20.9 10510220.420.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.4 20.0
22.9 11511823.520.0µg/LTetrachloroethene 70-130 2.5 20.0
23.7 11912324.520.0µg/LToluene 70-130 3.3 20.0
23.7 11912525.020.0µg/L1,2,3-Trichlorobenzene 70-130 5.3 20.0
22.7 11411723.420.0µg/L1,2,4-Trichlorobenzene 70-130 3.0 20.0
22.7 11411523.020.0µg/L1,1,1-Trichloroethane 70-130 1.3 20.0
Page 11 of 12Date:05/12/2023 10:25 AM
Page 27 of 30
Quality Control Data
23-125-0020Report No:
Project Description:
Client ID:Withers & Ravenel
Pap's Packaging Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V33045QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V33044
LCS-V33044 LCSD-V33044Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.6 11811222.420.0µg/L1,1,2-Trichloroethane 70-130 5.2 20.0
22.6 11311522.920.0µg/LTrichloroethene 70-130 1.3 20.0
23.4 11711823.520.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
20.4 10299.519.920.0µg/L1,2,3-Trichloropropane 70-130 2.4 20.0
21.5 10811222.320.0µg/L1,2,4-Trimethylbenzene 70-130 3.6 20.0
21.1 10611222.320.0µg/L1,3,5-Trimethylbenzene 70-130 5.5 20.0
24.0 12011823.520.0µg/LVinyl Acetate 60-140 2.1 20.0
25.2 12611823.520.0µg/LVinyl Chloride 60-140 6.9 20.0
45.8 11511746.640.0µg/Lm,p-Xylene 70-130 1.7 20.0
21.8 10911122.120.0µg/Lo-Xylene 70-130 1.3 20.0
10099.24-Bromofluorobenzene (S)70-130
93.090.8Dibromofluoromethane (S)70-130
93.091.61,2-Dichloroethane - d4 (S)70-130
95.097.0Toluene-d8 (S)70-130
Page 12 of 12Date:05/12/2023 10:25 AM
Page 28 of 30
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-125-0020
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.2C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:05/05/2023 16:00:29
Special precautions or instructions included?
Comments:
Page 29 of 30
Page 30 of 30
WithersRavenel
Our People. Your Success.
APPENDIX F
GENERAL STANDARD OPERATING PROCEDURES
Generalized Standard Operating Procedures (Not All Inclusive)
WithersRavenel
Our People. Your Success.
Soil Sampling, Soil Boring and Monitor Well Installation, Well Development Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary
drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are
typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may be collected from drill cuttings associated with the boring or well installation. Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC
casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells). Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus
space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas where shallow groundwater is encountered, a variance to construction standards may be employed to ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are
secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at or above grade, and are abandoned within 24-hours of their installation. Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump, dependent upon site conditions. When wells are developed by the driller, they may be developed with
any of the methods outlined above, in addition to air or water injection. Soil boring logs and well construction details are typically prepared for presentation in a report appendix. Borings completed in bedrock may be drilled using air rotary, coring, or sonic drilling methods. Groundwater Depth to Water Measurements
Groundwater level measurements are typically obtained using an electronic water level indicator which registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot intervals into the well until the probe of the meter intersects the water surface. The measurement from
the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The
electronic water level indicator probe and exposed probe cable is decontaminated between measurement locations.
Generalized Standard Operating Procedures (Not All Inclusive)
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Free Product Level Measurements Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using
an electronic oil/water interface probe. The interface probe has both an audible and illuminating light
that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are
recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is decontaminated between measurement locations. Soil Sampling and Field Screening
Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling procedures are followed to protect the chemical integrity of the soil samples and minimize the potential for cross contamination between sample locations, including discarding of the exterior of the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling
equipment, and the thorough decontamination of sampling apparatus prior to use and between sample locations. Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples
from excavation equipment includes retrieving native soil from material that has not made contact with the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers as described above. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample
integrity and minimize the potential for cross contamination or field personnel exposure to contaminants.
Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or shovels, are decontaminated prior to their use in the collection of samples. Samples are placed within laboratory grade sample containers provided by the laboratory to which the
samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is
typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other portable screening device.
Screening of samples with a PID, FID or other field screening device is performed in accordance with
device manufacturer specifications for screening, following calibration of the instrument based on manufacturer recommended procedures.
Generalized Standard Operating Procedures (Not All Inclusive)
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Groundwater Sampling Groundwater samples are generally collected using one of three standard methods – through the use of a
dedicated, disposable bailer, a peristaltic pump or submersible electric pump.
When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to recover to within 80% of the original level measured prior to purging.
When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is emplaced into the screened section of the monitoring well, and the pump is used to extract water through the tubing. When using the either of these methods, general water quality measurements including but not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific
conductivity and turbidity may be used as methods for determining when an adequate purge of the well has been conducted. When water quality parameters are measured, the resulting data are included in well purge forms or field notes specific to each site and sampling point. Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of
monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater sample(s) are introduced directly into sample containers provided by the laboratory to which samples are ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-preserved container(s) provided by the laboratory.
Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination of samples or field personnel exposure to contaminants. Water Supply Well Sampling
Sampling of water supply wells is accomplished through the collection of a representative sample from an in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a point prior to any filtration or point of entry (POE) system which might be installed on a well. In some cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples
through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized
water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse. In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is
contained in laboratory grade sample containers as described in the previous section. Water quality
parameters may be (but are not necessarily) measured in association with the well purging. Supply wells without active power supplies are not generally sampled, as the well seal cannot be compromised by individuals not certified as a well contractor. However, in the case of a well with no
power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or
electric submersible pump.
Generalized Standard Operating Procedures (Not All Inclusive)
WithersRavenel
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Decontamination Procedures Decontamination procedures employed in the performance of field activities will vary dependent upon
the method(s) of sampling performed at any site, but will generally include the following:
• Remove excess soil/sludge from any sampling equipment as needed, • Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as necessary,
• Rinse thoroughly with tap water, • Rinse thoroughly with analyte-free water (deionized water),
Rinse thoroughly with isopropyl alcohol, • Allow the equipment to air dry,
• Prevent inadvertent contamination during storage and transport (accomplished through storage of equipment in foil or plastic bags/sheeting). In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may be decontaminated prior to their disposal. In general, no decontamination of these items is necessary
prior to their use in sampling.