AS-980_10873_CA_MRP_20230531

ENVIRONMENTAL | CIVIL | GEOTECHNICAL

MONITORING REPORT LITTLE CUBBARD 137 US HIGHWAY 64 RUTHERFORDTON, RUTHERFORD COUNTY, NC NCDEQ INCIDENT NO. 10873 RISK CLASSIFICATION: I0160D

MAY 31, 2023
NCDEQ CONTRACT NO. N122019D TASK AUTHORIZATION NO. 03 CATLIN PROJECT NO. 221064
PREPARED FOR:
MR. SCOTT RYALS NCDEQ, DWM, UST SECTION 1646 MAIL SERVICE CENTER RALEIGH, NC 27699-1646
PREPARED BY: CATLIN ENGINEERS AND SCIENTISTS 220 OLD DAIRY ROAD
WILMINGTON, NC 28405 [phone]
CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585
CORPORATE LICENSURE NO. FOR GEOLOGY SERVICES C-118

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023
TABLE OF CONTENTS
PAGE
1.0 SITE INFORMATION 1
2.0 EXECUTIVE SUMMARY 2
3.0 SCOPE OF SERVICES 3
4.0 SITE HISTORY AND CHARACTERIZATION 3
4.1 UST OWNER AND OPERATOR INFORMATION 3 4.2 UST INFORMATION 4 4.3 CONTAMINANT SOURCE INVENTORY 4 4.4 SITE CHARACTERISTICS 4 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE 4 4.6 RECEPTOR INFORMATION 5 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 5
5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 7
5.1 SOIL AND BEDROCK 7
5.2 HYDROGEOLOGY 7
6.0 SITE ASSESSMENT INFORMATION 7
6.1 RECOVERY WELL INSTALLATION 7 6.2 MMPE EVENT 8 6.3 GAUGING DATA 8 6.4 SAMPLING DATA 9 6.5 SUMMARY OF GROUNDWATER INFORMATION 10 6.6 EVALUATION OF ASSESSMENT INFORMATION 11
7.0 CONCLUSIONS AND RECOMMENDATIONS 11
8.0 STATEMENTS AND CERTIFICATION 12
9.0 LIMITATIONS 13
10.0 REFERENCES 13

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023
TABLES
TABLE 1 SITE HISTORY – UST AND OTHER RELEASE INFORMATION
TABLE 2 PUBLIC AND PRIVATE WATER SUPPLY WELLS WITH OTHER RECEPTOR INFORMATION
TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA
TABLE 4 SUMMARY OF GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B
TABLE 5 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B
FIGURES FIGURE 1 SITE VICINITY MAP
FIGURE 2 POTENTIAL RECEPTOR MAP
FIGURE 3 SITE MAP
FIGURE 4 GROUNDWATER ELEVATION – MAY 3, 2023
FIGURE 5 MONITORING WELL GROUNDWATER SAMPLE ANALYTICAL RESULTS –
MAY 3, 2023

APPENDICES APPENDIX A HISTORICAL DATA
APPENDIX B SITE PHOTOGRAPHS
APPENDIX C JOB HAZARD ANALYSES, SURVEY NOTES, AND FIELD DATA SHEETS
APPENDIX D WELL LOG AND WELL CONSTRUCTION RECORD
APPENDIX E MMPE REPORT AND DISPOSAL DOCUMENTS
APPENDIX F LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 1 May 2023
1.0 SITE INFORMATION
Site Identification
Date: 05/31/2023 Site Risk/Priority Rank: I0160D
UST Number: AS-980 Incident Number: 10873
Site Name: Little Cubbard Facility ID: 0-009299
Site Location: 137 US Highway 64
Nearest City/Town: Rutherfordton County: Rutherford
Description of Geographical Data Point: Former UST Basin
Location Method: Google Earth
Latitude (decimal degrees): 35.38431° Longitude (decimal degrees): -81.94739°
Contacts Information
UST Owner: Ray Thomas Petroleum Company, Inc.
Address: Unknown Phone: Unknown
UST Operator: Ray Thomas Petroleum Company, Inc.
Address: Unknown Phone: Unknown
Property Owner: Timothy and Lois Mace
Address: PO Box 640, Ellenboro, NC 28040 Phone: Unknown
Property Occupant: Vacant
Address: 137 US Highway 64, Rutherfordton, NC 28139 Phone: Not Applicable
Consultant: CATLIN Engineers and Scientists
Address: 220 Old Dairy Rd., Wilmington, NC 28405 Phone: [phone]
Corporate Licensure No. For Engineering Services: C-0585
Corporate Geology License No.: C-118
Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703
Address: 39 Spruce St., E. Longmeadow, MA 01028 Phone: [phone]
Release Information
Date Discovered: 05/31/1993
Estimated Quantity of Release: Unknown
Cause of Release: Leak in the UST system
Source of Release: UST system or associated fitting(s)
Sizes and contents of UST system(s) from which the release occurred:
• Two 2,000-gallon gasoline USTs
• One 1,000-gallon diesel UST
• One 550-gallon heating oil UST
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 2 May 2023
2.0 EXECUTIVE SUMMARY
The Little Cubbard site is located at 137 US Highway 64, Rutherfordton, Rutherford
County, North Carolina. Seven underground storage tanks (USTs) were previously
operated at the site. Four USTs (one 2,000-gallon gasoline, one 1,000-gallon gasoline, one 2,000-gallon diesel, and one 450-ggallon heating oil) were removed from the site in 1993. A petroleum release was discovered during tank closure activities. No potential receptors have been identified within 1,500 feet of the
release.
The purpose of this report is to document the latest monitoring well installation, remediation efforts, and groundwater sampling event. On March 1, 2023, CATLIN Engineers and Scientists (CATLIN) personnel advanced one boring for the
construction of a recovery well (MW-14) to 35 feet below land surface (BLS).
CATLIN coordinated a mobile multi-phase extraction (MMPE) event with Advanced Environmental Services, Inc. (AES) from March 20 to March 24, 2023. Monitoring wells MW-1 and MW-4, and recovery well MW-14, were utilized as extraction points.
A total of 890 gallons of impacted groundwater and light non-aqueous phase liquid (LNAPL; aka free product) were recovered. A calculated 523.17 pounds of petroleum vapors were emitted, equivalent to approximately 85.04 gallons of petroleum.
On May 3, 2023, CATLIN personnel returned to the site and measured groundwater at approximately 26 feet deep across the site. Groundwater samples from three wells (MW-1, MW-4, and MW-14) were collected. The samples were submitted for laboratory analysis of volatile organic compounds (VOCs) per Standard Method (SM) 6200B plus ethylene dibromide (EDB), methyl tert-butyl ether (MTBE), and
diisopropyl ether (DIPE).
Laboratory results indicted multiple dissolved petroleum constituents at concentrations greater than those established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards
(2L GWQS) in all monitoring well samples. Benzene was also above its GCL in all three samples, and MTBE was above GCL in the MW-1 and MW-14 samples.
Although contaminant concentrations have generally decreased since the previous sampling event (December 2022), petroleum constituent concentrations persist
above GCL at the site.
CATLIN recommends installing additional monitoring wells to delineate the GCL plume and consider conducting a six-month long MMPE event.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 3 May 2023
3.0 SCOPE OF SERVICES
The scope of services for this report was performed in general accordance with
CATLIN proposal number 221064.3P, dated February 15, 2023. Services were
authorized by the North Carolina Department of Environmental Quality’s (NCDEQ’s) Task Authorization (TA) #03, accepted on February 15, 2023, and Contract Number N122019D.
The approved scope of services for this Task Authorization included:
•Update the site-specific Health and Safety Plan (HASP) for drilling activities;
•Install one four-inch diameter recovery well (MW-14) up to 35 feet BLS;
•Survey the top of casing (TOC) elevation of the new recovery well relative toan existing well;
•Coordinate and oversee a MMPE event utilizing MW-1, MW-4, and MW-14
as extraction points;
•Approximately 30 days after the MMPE event, collect groundwater samplesfrom MW-1, MW-4, and MW-14;
•Analyze four water samples (two monitoring wells, one recovery well, and
one field blank) according to SM 6200B (including EDB, MTBE, and DIPE);and
•Prepare and submit a monitoring report summarizing the findings.
The scope of services were conducted in accordance with the approved TA.
4.0 SITE HISTORY AND CHARACTERIZATION
The Little Cubbard site is located at 137 US Highway 64, Rutherfordton, Rutherford
County, North Carolina (Figures 1 and 2). Summarized available historical sampling and gauging data from previous consultants are provided in Appendix A. Recent site photographs are presented in Appendix B.
4.1 UST OWNER AND OPERATOR INFORMATION
Ray Thomas Petroleum Company, Inc. (Thomas Petroleum), owned the USTs historically operated on-site. Thomas Petroleum filed for Chapter 11 Bankruptcy in 2013. The site was subsequently accepted in into the North
Carolina UST Section Trust Fund Branch State Lead Program (NCDEQ,
2015).
Available information regarding UST owners/operators and is presented on Table 1.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 4 May 2023
4.2 UST INFORMATION
Limited historical files available on the NCDEQ Waste Management Online
Database (aka Laserfiche) present conflicting information regarding the
former USTs. According to NCDEQ Department of Waste Management (DWM) memo (2015) and the NCDEQ Tanks Database, up to seven USTs were previously operated at the site. However, reports prepared by ECS Southeast, LLP (ECS) and the GW/UST-2 Form completed by Bruce Bridges
of Quality Petroleum Installation Service and submitted after UST removal
only reference four USTs (ECS, 2020; Bridges, 1993).
The GW/UST-2 form indicates that one 2,000-gallon gasoline UST, one 1,000-gallon gasoline UST, one 2,000 gallon-diesel UST, and one 250-gallon
heating oil UST were removed from the site in 1993 (Bridges, 1993). It is
likely that additional USTs were historically operated at the site, however their capacity, previous contents, and operation dates are unknown. Reportedly, all USTs have been removed from the site (ECS, 2019).
Available UST system information is presented in Table 1 and the
approximate former UST system locations are shown on Figure 3.
4.3 CONTAMINANT SOURCE INVENTORY
An on-site release was discovered in 1993 during tank closure activities.
According to NCDEQ records, elevated concentrations of benzene, toluene, ethylbenzene, and total xylenes (BTEX) compounds were detected in soil samples collected from beneath the former diesel and gasoline USTs (NCDEQ, 2015).
A site history summary is included in Appendix A.
4.4 SITE CHARACTERISTICS
The property is owned by Timothy and Lois Mace. The site has been razed
and the former structures are no longer present.
Site photographs are presented in Appendix B.
4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE
Properties in the site vicinity are mostly residences and businesses. Residences are located to the north, west, and east of the site. The Thermal
Belt Rail-Trail is located across Long Street, west of the site. A construction
field office is located to the northeast, across US Highway 64 from the site.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 5 May 2023
4.6 RECEPTOR INFORMATION
Conducting a receptor survey was outside the scope of this monitoring event.
A review of historical files available on the NCDEQ Waste Management
Online Database (aka Laserfiche) indicates that the last receptor survey update for the Little Cubbard site was conducted in 2020 by ECS.
According to previous reports, municipal water is available to the site vicinity.
ECS did not identify any receptors within 500 feet of the site but did indicate
there is potential that some properties located near the site utilize water supply wells.
No surface water bodies were identified within 1,500 feet of the site.
Potential receptors are illustrated on Figure 2 and receptor information obtained from ECS (2020) is shown on Table 2.
4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES
The release was discovered in 1993 during UST closure activities. Historical files available on Laserfiche do not fully elucidate the site history. However, according to the site history presented in a State Lead Referral Memo prepared by NCDEQ personnel, 120 cubic yards of contaminated soil were
removed with the USTs in 1993. Elevated concentrations of BTEX
compounds were reported in soil samples collected from beneath the gasoline and diesel USTs (NCDEQ, 2015).
Between 1993 and 1994, 13 Type II monitoring wells (MW-1 through MW-13)
were installed during Comprehensive Site Assessment (CSA) activities.
Several VOCs were reported above their respective 2L GWQS in samples collected from multiple wells during the CSA. LNAPL was measured in monitoring well MW-4. A soil sample collected during monitoring well installation reportedly contained elevated concentrations of Total Petroleum
Hydrocarbons (TPH) (NCDEQ, 2015).
Following the CSA, 0.45 gallons of LNAPL were recovered from MW-4 in February 1994 and a Corrective Action Plan (CAP) was submitted by CBM Environmental (CBM) in November 1994. The CAP reportedly recommended
LNAPL and impacted soil removal, and to remediate groundwater by
conducting groundwater recovery and treatment with soil-venting on-site. The CAP-proposed remedial actions were reportedly initated by July 20, 1996 and deep well TW-1 was installed by 2002 (NCDEQ, 2015).
Regular groundwater monitoring and LNAPL recovery events have been
conducted at the site since 1994. LNAPL has previously been measured in monitoring wells MW-1, MW-4, and TW-1. It is unclear how LNAPL was historically recovered from the wells and the total amount of LNAPL removed is unknown (NCDEQ, 2015). In 2019, ECS conducted an Aggressive Fluid
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 6 May 2023
Vapor Recovery (AFVR) event, using MW-4 as an extraction point. During the AFVR event, a calculated total of 0.0610 pounds of VOCs were emitted as vapor and approximately 278 gallons of petroleum-impacted groundwater
was recovered (ECS, 2019).
Groundwater samples previously obtained from monitoring wells MW-1, MW-4, MW-7, and TW-1 have reportedly contained petroleum constituents at concentrations above their respective GCL. Since 1995, the BTEX compound
concentrations have generally decreased in samples obtained from on-site
monitoring wells. During monitoring events conducted in 2019, groundwater samples were obtained from MW-1, MW-2, MW-3, MW-4, MW-6, MW-7, MW-9, MW-11, and TW-1. Laboratory analytical results revealed multiple petroleum constituents at concentrations above their 2L GWQS in samples
from MW-1, MW-4, MW-6, MW-7, MW-9, and TW-1. Benzene was reported
above its GCL in the samples collected from MW-1 and MW-4 in 2019 (ECS, 2020).
In 2020, Provectus ORS sleeve (ORS) remedial devices were deployed in
monitoring wells MW-1 and MW-4. However, groundwater samples were not
obtained six months after deployment (as recommended) to determine the efficacy of the ORS devices (ECS, 2020).
CATLIN conducted a groundwater monitoring event in June 2021. During the
site visit, TW-1 was observed as destroyed, MW-6 was obstructed, and wells
MW-3 and MW-7 could not be located and were presumed destroyed. The remaining monitoring wells were gauged and sampled. Laboratory results revealed multiple contaminants in the samples from MW-1, MW-2, and MW-4 at concentrations above 2L GWQS. Benzene and MTBE were above their
respective GCL in the sample from MW-1, and benzene was above GCL in
the MW-4 sample. No measurable thickness of LNAPL was present in any of the monitoring wells (CATLIN, 2021).
In November 2022, CATLIN supervised a MMPE event by AES utilizing
monitoring wells MW-1 and MW-4. Prior to the event, LNAPL was measured
in both MW-1 (0.02 feet thick) and MW-4 (0.25 feet thick). A total of 2,010 gallons of impacted groundwater and LNAPL were removed and approximately 2,699.07 pounds of petroleum vapors were emitted (equivalent to 438.73 gallons of petroleum). CATLIN returned to the site in December
2022 to gauge and sample MW-1 and MW-4. There was no measurable
thickness of LNAPL in the wells. Several petroleum constituents were reported at concentrations above 2L GWQS in both samples. Benzene, EDB, and MTBE were above their respective GCL in the sample from MW-1, and benzene was above GCL in the MW-4 sample (CATLIN, 2023).
Summarized historical data from ECS (2020) and a detailed site history prepared by NCDEQ personnel are presented in Appendix A.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 7 May 2023
5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY
5.1 SOIL AND BEDROCK
As defined in the Geologic Map of North Carolina, published by the North Carolina Department of Natural Resources and Community Development (1985), the site lies within the Piedmont physiographic province. The site is underlain by interlayered hornblende gneiss, metagabbro, mica schist, and
granitic rock of the Inner Piedmont belt.
The boring log from recovery well installation (MW-14) during this monitoring period indicates that silty clay is present to approximately 18 feet BLS. Sandy clay was encountered from approximately 18 to 33 feet BLS. White sand was
observed at further depths.
5.2 HYDROGEOLOGY
Groundwater - The 2020 Visual Hydrogeologic Framework – North Carolina
Hydrogeological Database did not identify sufficient boreholes near the site to
draw a cross-section. Sandy clay was recently encountered in the surficial aquifer.
Surface Water – ECS (2020) did not identify any surface water bodies within
1,500 feet of the site during the most recent receptor survey.
6.0 SITE ASSESSMENT INFORMATION
CATLIN conducted field activities in general accordance with the approved TA and
pre-prepared HASP. Field activities included recovery well (MW-14) installation, a
MMPE event, and groundwater sampling. Upon arrival at the site, potential hazards were evaluated before beginning field work and are documented on electronic Job Hazard Analysis (JHA) forms. The JHA forms are included in Appendix C. Photographs from the site visits are included in Appendix B. Well locations and site
features are shown on Figure 3 and well construction details are presented on
Table 3.
6.1 RECOVERY WELL INSTALLATION
On March 1, 2023, a boring was advanced to 35 feet BLS for recovery well construction by a North Carolina Certified Well Contractor, utilizing hollow stem augers and a Diedrich D-50 drill rig. Cuttings generated during drilling activities were spread on-site.
The well (MW-14) was constructed of new, threaded PVC casing and screen. No glues or cements were used in joining PVC components. New nitrile gloves were worn while handling all well materials. The monitoring well was constructed with a pointed PVC sediment trap, 20 feet of 4-inch diameter, 0.010-inch slotted PVC well screen and approximately 15 feet of 4-inch
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 8 May 2023
diameter solid PVC riser to the surface. The annular space was filled with coarse sand pack to approximately two feet above the well screen and bentonite chips to within one foot of the ground surface. The bentonite chips
were poured from the surface while simultaneously pouring water to facilitate
hydration. The well was finished with a locking well cap, a flush-mount steel wellhead, and a concrete pad. After installation, the well was developed by over-pumping. The TOC elevation was measured using traditional survey methods (Rod and Level) in relation to a preexisting monitoring well (MW-1).
Monitoring well construction information is summarized on Table 3 and a site map with monitoring well location is illustrated on Figure 3. Site photographs are presented in Appendix B. The well log and Well Construction Record were submitted to NCDEQ on March 6, 2023; copies are provided in
Appendix D.
6.2 MMPE EVENT
CATLIN mobilized to the site on March 20 and March 24, 2023 to supervise a
MMPE event conducted by AES. Prior to the event, CATLIN personnel
gauged monitoring wells MW-1 and MW-4, and recovery well MW-14 using an electronic groundwater interface probe and measured depth to water at approximately 26 feet below top of casing (BTOC). LNAPL was not measured.
The MMPE event was conducted for a duration of 96 hours, ending on March 24, 2023. Monitoring wells MW-1 and MW-4, and recovery well MW-14 were utilized as extraction points. A total of 890 gallons of impacted groundwater and LNAPL were removed from the subsurface. No measurable LNAPL was
observed. The vacuum at the recovery pump ranged from 17.0 to 20.5 inches
of mercury and stabilized at 17.0 inches of mercury. Airflow rates ranged from 2,800 to 3,300 feet per minute and stabilized at 3,300 feet per minute. The system temperature ranged from 102 to 132 degrees Fahrenheit, and humidity maintained and stabilized at 99%. Field-gauged VOCs decreased
from 24,000 parts per million (ppm) to 13,000 ppm throughout the event. A
calculated 523.17 pounds of petroleum vapors were emitted during this event, equivalent to approximately 85.04 gallons of petroleum. The average rate of liquid recovery was 9.27 gallons per hour. The MMPE report from AES, including material manifests and emissions calculations, is included in
Appendix E.
6.3 GAUGING DATA
Historically, depth to groundwater in the shallow wells has ranged from 4.75
feet BTOC (MW-10) to 29.71 feet BTOC (MW-11). Depth to groundwater in the deep well (TW-1) had ranged from 21.50 feet BTOC to 36.77 feet BTOC (ECS, 2020).
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 9 May 2023
During the May 2023 event, CATLIN personnel measured depth to water using an electronic water interface probe. To prevent cross contamination, the probe and cabling were decontaminated according to the manufacturer’s
recommendations between use in each well. Gauging data were recorded on
an electronic groundwater sampling form using a tablet device. Gauging procedures were performed in general accordance with North Carolina Department of Environmental and Natural Resources (NCDENR), and NCDEQ Guidelines, and Environmental Protection Agency (EPA) Region 4
Operating Procedures.
Depth to water ranged from 24.14 feet BTOC (MW-4) to 27.29 feet BTOC (MW-1). Based on groundwater elevations calculated for this monitoring period, groundwater flow direction is towards the northwest.

Monitoring well gauging results for events conducted by CATLIN are presented in Table 3. Groundwater elevation is illustrated on Figure 4 and groundwater sampling forms are provided in Appendix C.
6.4 SAMPLING DATA
Following gauging, the wells were sampled in general accordance with NCDENR and NCDEQ Guidelines, and EPA Region 4 Operating Procedures. Prior to obtaining representative groundwater samples, each monitoring well
was purged by removing a minimum of three well volumes using a new,
disposable bailer. Monitoring well groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua Troll 600 Multiparameter Sonde (Aqua Troll). Conductivity, pH, oxidation reduction potential (ORP), dissolved oxygen, and temperature measurements were
recorded utilizing the VuSitu mobile application (version 1.17.12).
Groundwater parameter data were transferred from the VuSitu mobile application to the electronic groundwater sampling forms. Copies of the groundwater sampling forms are available in Appendix C.
After a minimum of three well volumes were removed (or the well was bailed
dry), a groundwater sample was collected from each well and poured into appropriate laboratory-provided, pre-preserved glassware, labeled, and placed on ice in an insulated cooler. A field blank was collected by pouring distilled water from a new gallon jug into appropriate laboratory-provided,
pre-preserved glassware, labeled, and placed on ice in an insulated cooler.
The groundwater samples and field blank were submitted to Con-Test Analytical Laboratory (Certification NC 652 and NC-DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol
for analyses described in Section 3.0 Scope of Services. The COC is
included with the analytical report provided Appendix F.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 10 May 2023
6.5 SUMMARY OF GROUNDWATER INFORMATION
Historically, samples from monitoring wells MW-1 and MW-4 have contained
the highest petroleum constituent concentrations. During the previous
sampling event (December 2022), monitoring wells MW-1 and MW-4 contained several VOCs at concentrations above their 2L GWQS. Benzene, EDB, and MTBE were reported above GCL in the MW-1 sample, and benzene was above GCL in the sample from MW-4. LNAPL has been
previously detected in MW-1, MW-4, and TW-1. Historical information
prepared by other consultants is included in Appendix A.
The latest groundwater sampling laboratory results for SM 6200B analysis are summarized in Table 4. Historical results for events conducted by
CATLIN are included in Table 5. Monitoring well sample analytical results are
illustrated on Figure 5. A copy of the complete laboratory report and COC documentation are in Appendix F.
Monitoring/Recovery Wells
During the May 2023 monitoring event, three groundwater samples (MW-1, MW-4, and MW-14) were collected and submitted for analysis via SM 6200B (including EDB, MTBE, and DIPE). Benzene was reported above its GCL in all three samples, and MTBE was also above its GCL in the MW-1 and MW-4
samples. Analytical results reported the following constituents at
concentrations above their 2L GWQS in the samples:
•MW-1: benzene (GCL exceedance), DIPE, ethylbenzene,isopropylbenzene, MTBE (GCL exceedance), naphthalene, n-
propylbenzene, toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and total xylenes;
•MW-4: benzene (GCL exceedance), ethylbenzene, isopropylbenzene,MTBE, naphthalene, n-propylbenzene, toluene, 1,2,4-
trimethylbenzene, 1,3,4-trimethylbenzene, and total xylenes; and
•MW-14: benzene (GCL exceedance), DIPE, ethylbenzene,isopropylbenzene, MTBE (GCL exceedance), naphthalene, n-propylbenzene, toluene, 1,2,4-trimethylbenzene, 1,3,5-
trimethylbenzene, and total xylenes.
Field Blank
One field blank sample was submitted for analysis per SM 6200B (including
EDB, MTBE, and DIPE). An estimated (“J”-value) concentration of acetone, a
known laboratory artifact, was detected in the field blank sample. No other targeted analytes were detected.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 11 May 2023
6.6 EVALUATION OF ASSESSMENT INFORMATION
Extent of Contamination
Several petroleum constituents were detected above their respective 2L GWQS in samples from MW-1, MW-4, and MW-14. Samples from MW-1 and MW-14 contained concentrations of benzene and MTBE above their respective GCL. The MW-4 sample also revealed MTBE above its GCL. A
summary of monitoring well groundwater sample analytical results are
illustrated on Figure 5.
The highest petroleum constituent concentrations have historically been reported in samples from MW-1 and MW-4. Analytical results from the
previous monitoring event (December 2022) revealed several petroleum
constituents above 2L GWQS in multiple monitoring well samples. Benzene, EDB, and MTBE were reported above GCL in the sample from MW-1. Laboratory analysis for samples collected during this event indicate benzene and/or MTBE remain above GCL in samples from MW-1, MW-4, and MW-14,
although overall VOC concentrations have generally decreased since the
previous event (CATLIN, 2022).
Cleanup Levels Achieved
Soil – In October 1993, approximately 120 cubic yards of impacted soil were
removed from the site. Soil samples obtained from beneath the former USTs and MW-1 boring contained elevated BTEX and TPH concentrations (NCDEQ, 2015).
Groundwater – Groundwater contaminant concentrations are above 2L
GWQS at the site and benzene and MTBE were reported above GCL.
LNAPL – LNAPL was not measured during this monitoring period. LNAPL has been periodically measured at the site since 1994.
7.0 CONCLUSIONS AND RECOMMENDATIONS
Conclusions
Site activities for this period are summarized below:
•One four-inch recovery well (MW-14) was installed to 35 feet BLS.
•A MMPE event was conducted utilizing MW-1, MW-4, and MW-14 as
extraction points. A total of 890 gallons of impacted groundwater and LNAPLwere removed. A calculated 523.17 pounds of petroleum vapors wereemitted, equivalent to 85.04 gallons of petroleum.
•Approximately 30 days after the MMPE event, monitoring wells MW-1 and
MW-4, and recovery well MW-14 were sampled.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 12 May 2023
•Multiple VOCs were detected above 2L GWQS in the MW-1, MW-4, andMW-14 samples.
•Benzene and MTBE were detected above their GCL in the MW-1 and MW-14samples. Benzene was also detected above its GCL in the MW-4 sample.
•LNAPL was not measured during this monitoring event.
•The petroleum constituent concentrations in the monitoring well samples hasgenerally decreased since December 2022, but VOC concentrations persistabove GCL.
Recommendations
CATLIN recommends installing additional wells to delineate the GCL plume and consider conducting a six-month long MMPE event.
8.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. May 26, 2023 Will this report be submitted after the established due date? NO
This report was submitted on May 31, 2023, within the 10-day grace period.
2 Was any required information from the above template missing from this report? YES
No cross sections are provided. Adequate subsurface information is not available.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved in the Corrective Action Plan not be met? NA
The CAP is not publicly available on Laserfiche.
4 Does any known or suspected source zone soil contamination or free product remain outside of the assessed area that could be inhibiting natural attenuation? NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a potential new release from a separate onsite or offsite source? NO
6 Certification:
I, Benjamin J. Ashba, a Licensed Geologist for CATLIN Engineers and Scientists, do certify that the information contained in this report is correct and accurate to the best of my knowledge.
CATLIN Engineers and Scientists is licensed to practice geology in North Carolina. The certification number of the company or corporation is C-118.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 13 May 2023
9.0 LIMITATIONS
The groundwater samples analyzed as part of this investigation only provide isolated
data points and may not represent conditions at every location in the project area.
Analyses and conclusions of this report, being based on interpolation between data points at the project area, may not be completely representative of all site conditions. Conclusions and recommendations of this investigation and report are based on the best available data in an effort to comply with current regulatory
requirements.
10.0 REFERENCES
CATLIN Engineers and Scientists, Monitoring Report, Little Cubbard, 137 US
Highway 84, Ruth, Rutherford County, North Carolina, NCDEQ Incident No.
10873, Risk Classification: I0160D, July 9, 2021.
CATLIN Engineers and Scientists, Letter Report, Little Cubbard, 137 US Highway
64, Rutherfordton, NC 28040, Incident Number: 10873, Risk Classification: I0160D, CATLIN Project No. 221064, January 9, 2023.
ECS Southeast, LLP, Groundwater Monitoring Report, Little Cubbard, 137 US
Highway 64, Ruth, Rutherford County, North Carolina, December 19, 2019.
ECS Southeast, LLP, Receptor Survey Update and Provectus ORS Sleeve
Installation Letter Report, Little Cubbard Site, 137 US Highway 64, Ruth, Rutherford County, North Carolina, NCDEQ Incident: 10873, NCDEQ
Contract:N17006, ECS Project 9:8976-B, July 2, 2020.
NCDEQ, Division of Waste Management, Bob Davies and Kristin Hicklin, Memo,
Little Cubbard, Incident # 10873, 101 Morgantown Hwy, Rutherfordton, March 13, 2015.
NCDEQ, Division of Waste Management, Quality Petroleum Installation Services,
Bruce Bridges, GW/UST-2, Site Investigation Report For Permanent Closure
or Change-in-Service of U.S.T., July 7, 1993.
NCDEQ, Division of Water Resources, 2020 Visual Hydrogeologic Framework,
North Carolina Hydrogeological Database, ncwater.org/?page=350, accessed April 15, 2021.
NCDEQ, UST Section, North Carolina Department of Environmental Quality,
Division of Waste Management, Corrective Action Guidelines, January 19, 2021.
NCDENR, UST Section, North Carolina Department of Environment and Natural Resources, Division of Waste Management, Guidelines for Sampling,
December 1, 2013.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Site Checks, Tank Closure,
and Initial Response and Abatement, January 19, 2021.
North Carolina Department of Natural Resources and Community Development,
Geological Map of North Carolina, 1985.
NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 14 May 2023
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S.
EPA Report No. SESDPROC-206-R3, Effective Date December 18, 2015.
U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Level and Well Depth
Measurement, Striggow, B., U.S. EPA Report No. SESDPROC-105-R3, Effective Date November 3, 2016.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and
Ecosystem Support Division, Athens Georgia, Operating Procedure –
Groundwater Sampling, Striggow, B., U.S. EPA Report No. SESDPROC-301-R4, Effective Date April 26, 2017.
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and
Ecosystem Support Division, Athens Georgia, Operating Procedure – In Situ
Water Quality Monitoring, Chief, Field Services Branch, U.S. EPA Report No. SESDPROC-111-R4, Effective Date March 14, 2018.

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

TABLES
Page 1 of 1
TABLE 1
SITE HISTORY — UST AND OTHER RELEASE INFORMATION
Incident Name and No.: Little Cubbard - 10873
UST ID
Number
Name of Owner/
Operator
Last
Contents
Previous
Contents
Capacity
(gal)
Construction
Details
Tank
Dimensions
Installation
Date
(mm/dd/yy)
Date
Removed
(mm/dd/yy)
1 Gasoline Gasoline 10,000 Single Wall
Steel Unknown 02/24/71 04/28/20
2 Gasoline Gasoline 2,000 Single Wall
Steel 64" x 12'02/22/80 05/31/93
3 Gasoline Gasoline 1,000 Single Wall
Steel 48" x 10'02/24/71 05/31/93
3A Diesel Diesel 4,000 Single Wall
Steel Unknown 06/03/93 04/28/20
4 Gasoline Gasoline 8,000 Single Wall
FRP Unknown 02/24/71 04/28/20
5 Diesel Diesel 2,000 Single Wall
Steel 64" x 12'02/24/71 05/31/93
6 Heating Oil/
Diesel
Heating Oil/
Diesel 450 Single Wall
Steel Unknown 02/24/71 05/31/93
Incident
Number Material Released
Date Release
Discovered
(mm/dd/yy)
10873 Gasoline 05/31/93
Information obtained from the GW/UST-2 Form prepared by Bruce Bridges (1993), NCDEQ DWM (2015), and NCDEQ Tanks Database.
' = feet
" = inches
gal = gallons
Description of the Release
TPH concentrations above State Action Levels revealed in soil samples during UST removal activities.
Ray Thomas
Petroleum Co., Inc.
Dates of Ownership/
Operation
(mm/dd/yy)
02/24/71 - 05/31/93
02/24/71 - 05/31/93
02/24/71 - 04/28/20
06/03/93 - 04/28/20
02/24/71 - 05/31/93
02/22/80 - 05/31/93
02/24/71 - 04/28/20
NCDEQ; 10873_Little Cubbard; T1_Site History
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023
Page 1 of 1
TABLE 2
Incident Name and No.: Little Cubbard - 10873
Parcel ID Property Address Owner Name
(Last, First MI)
Owner Mailing
Address Well?Municipal
Water Status
1206798 137 US Highway 64
Rutherfordton, NC 28139
Mace, Timothy; Mace,
Lois
PO Box 640
Ellenbor, NC 28040 None Available -
connected
1206797 145 US Highway 64
Rutherfordton, NC 28139
Mace, Timothy; Mace,
Lois
PO Box 640
Ellenbor, NC 28040 Unknown
1202772 142 Long Street
Rutherfordton, NC 28139 Parker, Hattie S. 205 Ruffs Trail
Rutherfordton, NC 28139 None Available -
connected
1654034 US Highway 64
Rutherfordton, NC 28139 Ensley, Jennifer L. 171 US Highway 64
Rutherfordton, NC 28139 Unknown
1654035 159 US Highway 64
Rutherfordton, NC 28139
Department of
Transportation
1546 Mail Service Center
Raliegh, NC 27611 Unknown
1209550 SAME Perez, Maria G. & Calvillo, Francisco J.527 Long StreetRutherfordton, NC 28139 Unknown
1204467 SAME Faulkner, Donald R. &
Beverly A.
146 Long Street
Rutherfordton, NC 28139 Unknown
1204303 SAME Morrow, Travis &
Morrow, Michelle
519 Long Street
Rutherfordton, NC 28139 Unknown
1204466 Long Street
Rutherfordton, NC 28139
Faulkner, Donald R. &
Beverly A.
146 Long Street
Rutherfordton, NC 28139 Unknown
1654033 SAME Ensley, Jennifer L. 171 US Highway 64
Rutherfordton, NC 28139 Unknown
1204465 US Highway 64
Rutherfordton, NC 28139 Tabernacle, Bible 198 Youngs Drive
Rutherfordton, NC 28139 Unknown
1209900 189 US Highway 64
Rutherfordton, NC 28139 Tabernacle, Bible PO Box 233
Spindale, NC 28160 None Available -
connected
1628243 174 US Highway 64Rutherfordton, NC 28139 McSwain, Heath & McSwain, Erin 184 US Highway 64Rutherfordton, NC 28160 None Available - connected
1628244 SAME McSwain, Heath &
McSwain, Erin
184 US Highway 64
Rutherfordton, NC 28160 None Available -
connected
1600001 146 US Highway 64
Rutherfordton, NC 28139
McSwain, Heath &
McSwain, Erin
184 US Highway 64
Rutherfordton, NC 28160 None Available - not
connected
1619239 SAME Goforth, Sheila R. 126 Shady Woods Lane
Rutherfordton, NC 28139 Unknown
1619238 SAME Chavez, Jesse & Trejo, Daisy H. 110 Shady Woods LaneRutherfordton, NC 28139 Unknown
1634566 Shady Woods Lane
Rutherfordton, NC 28139 Town of Ruth PO Box 791
Rutherfordton, NC 28139 Unknown
1210374 124 Rock RoadRutherfordton, NC 28139 Department of Transportation 1546 Mail Service CenterRaliegh, NC 27611 Unknown
1606563 311 E. Mountain Street
Rutherfordton, NC 28139
Department of
Transportation
1546 Mail Service Center
Raliegh, NC 27611 Unknown
1637266 E. Mountain Street
Rutherfordton, NC 28139
Department of
Transportation
1546 Mail Service Center
Raliegh, NC 27611 Unknown
Information obtained from ECS (2020).
ft. = feet
PUBLIC AND PRIVATE WATER SUPPLY WELLS WITH OTHER RECEPTOR INFORMATION
NCDEQ; 10873_Little Cubbard.xlsx; T2_Receptor Info
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023
Page 1 of 2
TABLE 3
WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA
Incident Name and No.: Little Cubbard - 10873
Well ID
Date
Installed
(mm/dd/yy)*
Date Water
Level
Measured
(mm/dd/yy)
Well
Diameter
(inches)
Well
Casing
Depth
(ft. BLS)*
Screened
Interval
(x to y ft.
BLS)*
Bottom
of Well
(ft. BLS)*
Top of
Casing
Elevation*
(ft.)
Free-Phase
Product
Thickness**
Depth to
Groundwater
from Top of
Casing (ft.)
Groundwater
Elevation (ft.)Comments
06/02/21 NMT 20.88 1,002.65
11/14/22 0.02 29.27 994.28 Pre-MMPE
11/18/22 NMT 31.13 992.40 Post-MMPE
12/15/22 NMT 29.04 994.49
03/20/23 NMT 27.26 996.27 Pre-MMPE
03/24/23 NMT 30.02 993.51 Post-MMPE
05/03/23 NMT 27.29 996.24
MW-2 05/XX/93 06/02/21 2.0 15.0 15.0-30.0 30.0 1,021.45 NMT 21.29 1,000.16
MW-3 05/XX/93 06/02/21 2.0 14.0 14.0-29.0 29.0 1,013.04 Could not locate
06/02/21 NMT 16.54 1,001.10
11/14/22 0.25 26.25 991.60 Pre-MMPE
11/18/22 Post-MMPE
12/15/22 NMT 26.12 991.52
03/20/23 NMT 24.43 993.21 Pre-MMPE
03/24/23 NMT 26.43 991.21 Post-MMPE
05/03/23 NMT 24.14 993.50
MW-5 05/XX/93
MW-6 05/XX/93 06/02/21 2.0 15.0 15.0-30.0 30.0 1,021.15 Well cap stuck
MW-7 05/XX/93 06/02/21 2.0 15.5 15.5-30.5 30.5 1,024.47 Could not locate
MW-8 05/XX/93
MW-9 05/XX/93 06/02/21 2.0 14.0 14.0-29.0 29.0 1,007.02 NMT 13.37 993.65 Ɨ
MW-10 05/XX/93
MW-11 05/XX/93 06/02/21 2.0 20.0 20.0-30.0 30.0 1,017.52 NMT 19.64 997.88 Ɨ
MW-12 05/XX/93
MW-13 05/XX/93
16.12.005/XX/93MW-1
12.5-27.5 27.5 1,017.64
1,023.5331.116.1-31.1
MW-4 05/XX/93 2.0 12.5
NM
NM
NM
Presumed Destroyed
Dry
Presumed Destroyed
Destroyed
Presumed Destroyed
Destroyed
NCDEQ; 10873_Little Cubbard; T3_Well Construction & Gauging
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023
Page 2 of 2
TABLE 3
WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA
Incident Name and No.: Little Cubbard - 10873
Well ID
Date
Installed
(mm/dd/yy)*
Date Water
Level
Measured
(mm/dd/yy)
Well
Diameter
(inches)
Well
Casing
Depth
(ft. BLS)*
Screened
Interval
(x to y ft.
BLS)*
Bottom
of Well
(ft. BLS)*
Top of
Casing
Elevation*
(ft.)
Free-Phase
Product
Thickness**
Depth to
Groundwater
from Top of
Casing (ft.)
Groundwater
Elevation (ft.)Comments
03/01/23 NMT 27.13 994.80
03/20/23 NMT 27.01 994.92 Pre-MMPE
03/24/23 NMT 33.11 988.82 Post-MMPE
05/03/23 NMT 26.86 995.07
TW-1 05/XX/93 06/02/21 2.0 35.0 35.0-40.0 40.0 1,023.69 Destroyed
ft. BLS = feet Below Land Surface
XX = Exact date unknown.
NM = Not Measured
NMT = No Measurable Thickness
MMPE = Mobile Multi-Phase Extraction Event
Ɨ = Depth to water was measured above the screened interval.
* = Data for wells installed prior to 2023 obtained from ECS (2020).
** = if free-phase product is present in a well, ground water elevation should be calculated by : [top of casing elevation - depth to water]+ [free product thickness x specific gravity of the fuel type]
The total well depth of MW-1 and MW-4 were re-gauged by CATLIN personnel in December 2022.
MW-14 1,021.9335.020.0-35.020.04.003/01/23
NM
NCDEQ; 10873_Little Cubbard; T3_Well Construction & Gauging
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023
Page 1 of 1
TABLE 4
SUMMARY OF GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B
Incident Name and No.: Little Cubbard - 10873
Date
Collected
(mm/dd/yy)
05/03/23 2,300 J 30,000 1,200 J 470 2,700 160 J 28,000 870 380 44,000 3,200 740 18,300 BMDL
05/03/23 <800 9,400 780 J <81 ƚ 4,100 210 700 790 520 38,000 3,900 1,000 22,700 BMDL
05/03/23 4,300 J 30,000 2,700 J 890 3,700 190 J 77,000 800 450 J 59,000 2,900 650 18,400 BMDL
05/03/23 2.6 J <0.18 <1.7 <0.20 <0.22 <0.15 <0.17 <0.38 <0.12 <0.22 <0.20 <0.15 <0.73 BMDL
All results in micrograms per liter (µg/L).
< = Less than method detection limit
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
Bold results indicate concentrations above 2L GWQS.
Shaded results indicate concentrations above GCL.
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
GCL = Gross Contaminant Level
ƚ = The method detection limit is above the 2L GWQS.
J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag).EthylbenzeneWell/
Sample ID
AcetoneMW-4 2-Butanone (MEK)Field Blank
GCL (µg/L)
2L GWQS (µg/L)
5,000
1 Total Xylenes80,000
600
30,500
70
20,000
20
50,000
500Diisopropyl Ether (DIPE)70,000
70 1,3,5-TrimethylbenzeneIsopropylbenzene (Cumene)MW-14
MW-1
Contaminant of
Concern
Benzene6,000,000
6,000
Varies
Varies
6,000
6
26,100
70
260,000
600
28,500
400
24,100
400
4,000,000
4,000 All Other SM 6200B AnalytesToluene1,2,4-Trimethylbenzenen-PropylbenzeneMethyl tert-Butyl Ether (MTBE)Naphthalene NCDEQ; 10873_Little Cubbard; T4_GW Results (SM 6200B)
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023
Page 1 of 1
TABLE 5
SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B
Incident Name and No.: Little Cubbard - 10873
Date
Collected
(mm/dd/yy)
06/02/21 5,300 J 27,000 3,300 <70 ƚ <50 <75 ƚ 480 2,500 110 J <45 ƚ 34,000 600 270 45,000 2,800 720 20,700 BMDL
12/15/22 <1,000 32,000 <810 90 J <55 100 J 600 4,600 280 <49 ƚ 38,000 850 660 58,000 5,400 1,400 28,700 BMDL
05/03/23 2,300 J 30,000 1,200 J <60 <51 <64 ƚ 470 2,700 160 J <51 ƚ 28,000 870 380 44,000 3,200 740 18,300 BMDL
06/02/21 12 J 420 <9.4 2.4 J 2.0 J <0.75 ƚ 6.0 3.3 11 0.7 J 22 <0.75 3.0 2.8 52 7.4 108 BMDL
06/02/21 1,400 J 8,800 780 J 96 J <40 <60 ƚ <60 4,000 190 J <36 ƚ 510 960 490 45,000 4,300 1,000 24,100 BMDL
12/15/22 <1,000 8,400 <810 770 380 <85 ƚ <64 9,200 900 180 J 1,000 2,800 3,000 49,000 19,000 5,600 50,000 BMDL
05/03/23 <800 9,400 780 J <60 <51 <64 ƚ <81 ƚ 4,100 210 <51 ƚ 700 790 520 38,000 3,900 1,000 22,700 BMDL
06/02/21 2.8 J <0.13 <1.9 <0.14 <0.10 <0.15 ƚ <0.15 <0.090 <0.10 <0.090 <0.17 <0.15 <0.080 <0.11 <0.10 <0.10 <0.27 BMDL
06/02/21 3.9 J <0.13 <1.9 <0.14 <0.10 <0.15 ƚ <0.15 <0.090 <0.10 <0.090 <0.17 <0.15 <0.080 <0.11 <0.10 <0.10 <0.27 BMDL
05/03/23 4,300 J 30,000 2,700 J <150 ƚ <130 ƚ <160 ƚ 890 3,700 190 J <130 ƚ 77,000 800 450 J 59,000 2,900 650 18,400 BMDL
All results in micrograms per liter (µg/L).
< = Less than method detection limit
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
Bold results indicate concentrations above 2L GWQS.
Shaded results indicate concentrations above GCL.
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
GCL = Gross Contaminant Level
ƚ = The method detection limit is above the 2L GWQS.
J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag).
8,80070 1,2-Dibromoethane (EDB)500.02 Total XylenesAll Other SM 6200B AnalytesDiisopropyl Ether (DIPE)EthylbenzeneIsopropylbenzene (Cumene)p-Isopropyltoluene (p-Cymene)Methyl tert-Butyl Ether (MTBE)Naphthalene VariesVaries70,000 70 80,000600 30,50070 11,70025 n-PropylbenzeneToluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneContaminant of
Concern
AcetoneBenzene2-Butanone (MEK)n-ButylbenzeneWell/
Sample
ID sec-ButylbenzeneMW-1
5,900 70
MW-2
MW-9
MW-11
GCL (µg/L)
2L GWQS (µg/L)
6,000,000 6,000 5,0001 4,000,0004,000
MW-4
MW-14
24,100400 50,00050020,000 20 6,0006 26,10070 260,000600 28,500400
NCDEQ; 10873_Little Cubbard; T5_Historical GW
CATLIN Project No. 221064
CATLIN Engineers and Scientists
May 2023

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

FIGURES
FIGUREPROJECTTITLE
1SITE VICINITY MAP
SITE LOCATION
U S H W Y 64US 74 ALTCopyright:© 2013 National Geographic Society, i-cubed
2,000 0 2,000 4,0001,000
Feet
³
LITTLE CUBBARD137 US HWY 64RUTHERFORDTON, NC
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10873221064MAY 2023 AS SHOWN KMC/BJA
FIGUREPROJECTTITLE
2POTENTIAL RECEPTOR MAP
SITE LOCATION
1 ,5 0 0 F EET RADIUS
500F E ET RADIUS
US HWY 64
US 74 ALTSource: Esri, Maxar, Earthstar Geographics, and the GIS User Community
500 0 500 1,000250
Feet
³
LITTLE CUBBARD137 US HWY 64RUTHERFORDTON, NC
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10873221064MAY 2023 AS SHOWN KMC/BJA
FIGUREPROJECTTITLE
3SITE MAP
!>!(>!>
!>!>!>
!>!>!>!>!>
!>
!>US HWY 64MW-9
MW-3(CNL)
MW-4MW-6
MW-7(CNL)MW-1
TW-1
MW-2 MW-11
MW-5
MW-8
MW-12
APPROXIMATE LOCATIONOF FORMER UST BASIN
MW-14
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
60 0 60 12030
Feet
³
LITTLE CUBBARD137 US HWY 64RUTHERFORDTON, NC
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10873221064MAY 2023 AS SHOWN KMC/BJA
NOTES: 1. Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.2. The site has been razed; on-site structures shown on the map are not currently present.
Parcel Boundary
Monitoring Well
(Type II)!>
LEGEND
Destroyed Monitoring Well (Deep)!(>Destroyed Monitoring
Well (Type II)!>Approximate Locationof Former Pump Island
3. CNL = Could Not Locate4. MW-10 and MW-13 were destroyed
and the locations are unkown.
FIGUREPROJECTTITLE
4GROUNDWATER ELEVATION –MAY 3, 2023
!>
!>!>
!>
!>
!><US HWY 64MW-9
MW-4(993.50)
MW-1(996.24)
MW-2 MW-11
MW-14(995.07)994.00994.50995.00995.50Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
50 0 50 10025
Feet
³
LITTLE CUBBARD137 US HWY 64RUTHERFORDTON, NC
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10873221064MAY 2023 AS SHOWN KMC/BJA
NOTES: 1. Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.2. The groundwater elevation contour interval is 0.50 feet.
Parcel Boundary
Monitoring Well(Type II)!>
LEGEND
Gauged MonitoringWell (Type II)!>
Approximate Locationof Former Pump Island
Groundwater Flow Direction<Groundwater Elevation (Feet)(##)
Groundwater Contour
FIGUREPROJECTTITLE
5
MONITORING WELLGROUNDWATER SAMPLEANALYTICAL RESULTS –MAY 3, 2023
!>
!>!>
!>
!>
!>US HWY 64MW-9
MW-4
MW-1
MW-2 MW-11
MW-14
ESTIMATED HORIZONTALEXTENT OF GCLEXCEEDANCES
ESTIMATED HORIZONTALEXTENT OF 2L GWQSEXCEEDANCES
??
??Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
50 0 50 10025
Feet
³
LITTLE CUBBARD137 US HWY 64RUTHERFORDTON, NC
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY10873221064MAY 2023 AS SHOWN KMC/BJA
NOTE: Well and tank locations were obtained from previous reports prepared by other consultants and are approximate.
Parcel Boundary
Monitoring Well(Type II)!>
LEGEND
Sampled MonitoringWell (Type II)!>
Approximate Locationof Former Pump Island
Incident Name and No.: Little Cubbard - 10873
DateCollected
05/03/23 30,000 470 2,700 160 J 28,000 870 380 44,000 3,200 740 18,30005/03/23 9,400 <81 ƚ 4,100 210 700 790 520 38,000 3,900 1,000 22,70005/03/23 30,000 890 3,700 190 J 77,000 800 450 J 59,000 2,900 650 18,400
All results in micrograms per liter (µg/L).B o ld results are above 2L GWQS. Refer to Table 4 for all results and notes. Shaded results are above GCL.
50,00050028,500400260,00060030,50070 20,000 20 6,0006 26,10070
MW-14 24,100400
SampleID
70,000 70 80,000600
MW-1 Diisopropyl Ether (DIPE)Ethylbenzene5,0001BenzeneGCL (µg/L)2L GWQS (µg/L)
MW-4
SUMMARY OF GROUNDWATER LABORATORY RESULTS - STANDARD METHOD 6200B
Methyl tert-Butyl Ether (MTBE)Naphthalene n-PropylbenzeneToluene1,3,5-TrimethylbenzeneTotal XylenesIsopropylbenzene (Cumene)Contaminant of Concern
1,2,4-Trimethylbenzene

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDICES

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX A HISTORICAL DATA
Page 2 of 9Table 2Summary of Current and Historical Groundwater Analytical ResultsLittle Cubbard137 US Highway 65Ruth, Rutherford County, North CarolinaNCDEQ Incident: 10873NCDEQ Contract: N17006Volatile Organic Compounds by Standard Method 6200B or equivalentAcetoneBenzeneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChlorodibromoethaneChloroform1,2-Dibromoethane1,2-DichloroethaneDiisopropyl etherEthylbenzeneIsopropylbenzenep-IsopropyltolueneMethyl butyl ketoneMethyl ethyl ketoneMethyl tert butyl etherNaphthalenen-PropylbenzeneStyreneToluene1,2,4-Trimethlybenzene1,3,5-TrimethlybenzeneTotal XylenesNC2LGWQS 600010.670700.470 0.02 0.470600702540 4,000 2067070600 400 400 500GCL 6,000,000 5,000 NE 6,900 8,500 400 70,000 50400 70,000 84,500 25,000 11,700 40,000 4,000,000 20,000 6,000 30,000 70,000 260,000 28,500 25,000 85,50004/18/95---52,000---------------ND---ND6,000------------104,000ND------69,000------35,00008/09/95---48,000---------------ND---ND4,800------------145,0001,200--- ---53,000--- ---24,90011/10/96---49,000---------------ND--- <1,0003,400------------100,000ND------64,000------22,00003/20/96---51,000---------------ND---1,000 3,900------------79,000ND------62,000------19,00006/27/96---58,000---------------ND---1,400 3,100------------130,000ND------54,000------19,00004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03Free Product; Well Not Sampled06/25/15---15,000------ <0.05 ------ <0.2529.6 127 4,390 253---------6,690 792 63537.644,700 4,470 1,110 22,55005/06/19<12,0007,700<120 <120 <120 <120 <120 <120 <120 <1204,300 280<120 <1,200 <1,2002,300 1,700 760<12028,000 5,500 1,300 22,90012/06/19---9,100<125 <125 <125 <125 <125 <125 <125 <1253,250 247--- --- ---3,820 790 581<12525,700 3,970 994 17,12004/18/95---480--- --- --- --- --- ND --- ND12--- --- --- ---33--- --- ---38--- ---37008/09/95---520--- --- --- --- --- ND --- ND10--- --- --- ---10--- --- ---34--- ---14211/10/95---540--- --- --- --- --- ND ---5.0 10--- --- --- ---ND--- --- ---39--- ---43003/20/96---460--- --- --- --- --- ND ---6.0 15--- --- --- ---ND--- --- ---47--- ---30006/27/96---640--- --- --- --- --- ND --- ND9.0--- --- --- ---11--- --- ---32--- ---50004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03---65---------------------ND1.2------------11ND------2.7------10006/25/15---308------ <0.5------<0.251.53.000 1.33.2---------3.0 <0.5 1.2<0.55.99.72.2 72.305/06/19 13 J<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.504/18/95---11,000---------------ND---170 2,070------------210ND------11,800------10,80008/09/95---1,280---------------4.0---49330------------1266------1,240------1,68011/10/96---5.0---------------ND---ND2.0------------NDND------5.0------1003/20/96---ND---------------ND---NDND------------NDND------ND------ND06/26/96---ND---------------ND---NDND------------NDND------ND------6.004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03---ND---------------------ND3.0------------NDND------5.4------5.806/25/15---8.4------ <0.5------ <0.25 <0.5 <0.58.3 0.58---------<0.5 <0.50.94<0.59.6<0.5 <0.58.605/06/19<500.53<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.501.7 0.21 J<0.50 <5.0 <5.0 <0.50 <2.00.35 J<0.500.94<0.500.31 J 2.004/18/95Free Product; Well Not Sampled08/09/95Free Product; Well Not Sampled11/10/96Free Product; Well Not Sampled03/20/96Free Product; Well Not Sampled06/26/96---27,000---------------ND---ND3,700------------NDND------50,000------17,00004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03Free Product; Well Not Sampled06/25/15Free Product; Well Not Sampled05/06/19<2,50015,000<2562 32<25 <2530<25685,500 24016 J220 J360470 600 66023 J62,000 4,800 1,300 24,80012/06/19No Sample Collected - Well Access Obstructed04/18/95--- ND --- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- --- ND --- --- ND08/09/95---ND---------------ND---NDND------------NDND------ND------ND11/10/96Insufficient Volume of Groundwater; Well Not Sampled03/20/96Insufficient Volume of Groundwater; Well Not Sampled06/26/96Insufficient Volume of Groundwater; Well Not Sampled04/11/02Well Not Located06/25/15Well DestroyedMW-5MW-1MW-2MW-3MW-4Sample DateSample IDAPPENDIX A HISTORCIAL DATA NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064CATLIN Engineers and Scientists May 2023
Page 3 of 9Table 2Summary of Current and Historical Groundwater Analytical ResultsLittle Cubbard137 US Highway 65Ruth, Rutherford County, North CarolinaNCDEQ Incident: 10873NCDEQ Contract: N17006Volatile Organic Compounds by Standard Method 6200B or equivalentAcetoneBenzeneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChlorodibromoethaneChloroform1,2-Dibromoethane1,2-DichloroethaneDiisopropyl etherEthylbenzeneIsopropylbenzenep-IsopropyltolueneMethyl butyl ketoneMethyl ethyl ketoneMethyl tert butyl etherNaphthalenen-PropylbenzeneStyreneToluene1,2,4-Trimethlybenzene1,3,5-TrimethlybenzeneTotal XylenesNC2LGWQS 600010.670700.470 0.02 0.470600702540 4,000 2067070600 400 400 500GCL 6,000,000 5,000 NE 6,900 8,500 400 70,000 50400 70,000 84,500 25,000 11,700 40,000 4,000,000 20,000 6,000 30,000 70,000 260,000 28,500 25,000 85,500Sample DateSample ID04/18/95---1,180--- --- --- --- --- ND ---18 100--- --- --- ---35ND --- ---1,380--- ---48008/09/95---290--- --- --- --- --- ND ---14 48--- --- --- ---7.0ND --- ---510--- ---11011/10/96---660--- --- --- --- --- ND --- ND71--- --- --- ---NDND --- ---810--- ---35003/20/96---1,100--- --- --- --- --- ND --- ND150--- --- --- ---81ND --- ---1,900--- ---65006/26/96---840--- --- --- --- --- ND ---13 110--- --- --- ---ND120--- ---1,100--- ---52004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03 --- 100 --- ------ --- --- --- ---6.7 39--- --- --- ---117.1--- ---200--- ---23006/25/15--- <0.5 --- --- <0.5 --- --- <0.25 <0.5<0.5 <0.5 <0.5 --- --- --- <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.505/06/19 15 J<0.507.6<0.50 <0.500.6832<0.50 <0.5010<0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.504/18/95---7,620---------------ND---50200------------1,370ND------3,450------1,28008/09/95---3,600---------------ND---94320------------900ND------3,000------2,60011/10/96---2,800---------------ND---ND160------------420ND------1,900------1,50003/20/96---2,900---------------ND---73170------------1,500ND------2,000------2,20006/27/96---6,800---------------ND---ND400------------4,400ND------5,500------3,70004/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03---ND---------------------100ND------------2,000ND------ND------5106/25/15--- <0.5------ <0.5------ <0.250.687.5<0.5 <0.5---------741<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.505/06/19<50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.500.6810 0.26 J<0.50 <0.50 <5.0 <5.0690<2.0 <0.50 <0.50 <0.50 <0.500.31 J<1.512/06/19--- <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.54.6<2.5 <2.5---------511<10.0 <2.5 <2.5 <2.5 <2.5 <2.5 <7.504/18/95---ND---------------ND---NDND------------NDND------ND------ND08/09/95---ND---------------ND---NDND------------NDND------ND------ND11/10/95---ND---------------ND---NDND------------NDND------1.0------1003/20/96---ND---------------ND---NDND------------NDND------ND------ND06/27/96---ND---------------ND---NDND------------NDND------ND------ND04/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03---ND--------------- <0.25 ---NDND------------NDND------ND------ND06/25/15Well Not Located04/18/95---ND---------------ND---NDND------------NDND------ND------ND08/09/95---ND---------------ND---NDND------------NDND------ND------ND11/10/96---ND---------------ND---NDND------------NDND------ND------ND03/20/96---ND---------------ND---NDND------------NDND------ND------ND06/26/96---ND---------------ND---NDND------------NDND------ND------ND04/11/02---ND---------------------NDND------------NDND------ND------ND10/10/02---ND---------------------NDND------------NDND------ND------ND07/15/03---ND---------------------NDND------------NDND------ND------ND06/25/15--- <0.5------ <0.5--------- <0.5 <0.5 <0.5 <0.5--------- <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.505/06/19 10 J<0.507.5<0.50 <0.501.831<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.504/18/95---ND---------------ND---NDND------------NDND------ND------ND08/09/95---ND---------------ND---NDND------------NDND------ND------ND11/10/96---ND---------------ND---NDND------------NDND------ND------ND03/20/96---ND---------------ND---NDND------------NDND------ND------ND06/26/96---ND---------------ND---NDND------------NDND------ND------ND04/11/02Well Not Located06/25/15Well DestroyedMW-10MW-8MW-9MW-6MW-7APPENDIX A HISTORCIAL DATA NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064CATLIN Engineers and Scientists May 2023
Page 4 of 9Table 2Summary of Current and Historical Groundwater Analytical ResultsLittle Cubbard137 US Highway 65Ruth, Rutherford County, North CarolinaNCDEQ Incident: 10873NCDEQ Contract: N17006Volatile Organic Compounds by Standard Method 6200B or equivalentAcetoneBenzeneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChlorodibromoethaneChloroform1,2-Dibromoethane1,2-DichloroethaneDiisopropyl etherEthylbenzeneIsopropylbenzenep-IsopropyltolueneMethyl butyl ketoneMethyl ethyl ketoneMethyl tert butyl etherNaphthalenen-PropylbenzeneStyreneToluene1,2,4-Trimethlybenzene1,3,5-TrimethlybenzeneTotal XylenesNC2LGWQS 600010.670700.470 0.02 0.470600702540 4,000 2067070600 400 400 500GCL 6,000,000 5,000 NE 6,900 8,500 400 70,000 50400 70,000 84,500 25,000 11,700 40,000 4,000,000 20,000 6,000 30,000 70,000 260,000 28,500 25,000 85,500Sample DateSample ID04/18/95---3.0--- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- ---4.0--- --- ND08/09/95---3.0--- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- --- ND --- --- ND11/10/96---5.0--- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- ---2.0--- --- ND03/20/96---7.0--- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- ---3.0--- --- ND06/26/96Insufficient Volume of Groundwater; Well Not Sampled04/11/02--- ND --- --- --- --- --- --- --- ND ND --- --- --- --- ND ND --- ---1.0--- --- ND10/10/02---1.0--- --- --- --- --- --- --- ND ND --- --- --- --- ND ND --- ---2.2--- --- ND07/15/03---1.9--- --- --- --- --- --- --- ND ND--- --- --- --- ND ND --- --- ND --- --- ND06/25/15--- <0.5 --- --- <0.5 --- --- --- <0.5 <0.50.61<0.5 --- --- --- <0.5 <0.5 <0.5 <0.50.54<0.5 <0.5 <0.505/06/19<50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <2.0 <0.50 <0.50<0.50<0.50 <0.50 <1.504/18/95--- ND --- --- --- --- --- ND --- ND ND --- --- --- --- ND ND --- --- ND --- --- ND08/09/95---ND---------------ND---NDND------------NDND------ND------ND11/10/96---ND---------------ND---NDND------------NDND------ND------ND03/20/96---ND---------------ND---NDND------------NDND------ND------ND06/26/96---ND---------------ND---NDND------------NDND------ND------ND04/11/02Insufficient Volume of Groundwater; Well Not Sampled10/10/02Insufficient Volume of Groundwater; Well Not Sampled07/15/03---ND---------------------NDND------------NDND------ND------ND06/25/15Well Not Located04/18/95---ND---------------ND---NDND------------NDND------ND------ND08/09/95Insufficient Volume of Groundwater; Well Not Sampled11/10/96Insufficient Volume of Groundwater; Well Not Sampled03/20/96---ND---------------ND---NDND------------NDND------ND------ND06/27/96Well Not Located04/11/02Well Not Located06/25/15Well Destroyed04/18/95---1,930---------------ND---ND70------------190ND------1,900------24008/09/95---40,000---------------ND---800 6,000------------205,000500--- ---42,000--- ---28,00011/10/95---880--- --- --- --- --- ND ---6.0 180--- --- --- ---240 55------1,400------1,30003/20/96---1,400---------------ND---9.0 210------------320 320------2,700------1,40006/27/96---720---------------ND---ND52------------NDND------1,700------70004/11/02Free Product; Well Not Sampled10/10/02Free Product; Well Not Sampled07/15/03Free Product; Well Not Sampled06/25/15---503------16.4--------- <0.5 <0.5405 89.5---------302 264 162<0.53281,040<0.51,75505/06/19<5,000410<50 <50 <50 <50 <50 <50 <50 <50720 140<50 <500 <500 <50560 400<501,300 2,700 770 3,65012/06/19---1,120<25.0 <25.0 <25.0 <25.0 <25.0 <25.0 <25.0 <25.0840 79.8---------868 228 174<25.04,690 1,320 417 4,920Notes:All results presented in micrograms per liter or mg/LCompounds not listed were not detected at concentrations greater than laboratory method reporting limitsNC2LGWQS - North Carolina 2L Groundwater Quality Standard GCL - Gross Contamination LevelsND - Not Detected --- - Not Analyzed or previously reportedValue = concentration exceeds laboratory method reporting limitValue= concentration exceeds NC2LGWQSValue= concentration exceeds GCLTW-1MW-12MW-13MW-11APPENDIX A HISTORCIAL DATA NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENIDIX A
HISTORICAL DATA (NCDEQ; 2015)
NCDEQ; 10873_Little Cubbard; AppA CATLIN Project No. 221064
CATLIN Engineers and Scientists July 2021
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023
APPENDIX A
HISTORCIAL DATA
NCDEQ; 10873_Little Cubbard CATLIN Project No. 221064 CATLIN Engineers and Scientists May 2023

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX B SITE PHOTOGRAPHS
APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of the site, facing northeast.

View of the site, facing southwest.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of rig set up on MW-14, facing west.

View of completed MW-14, facing west.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of MMPE set-up, facing northwest.

View of MMPE trailer, facing west.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of MMPE set-up with MW-4 in the foreground, facing southwest.

View of MW-14 MMPE set-up, facing southwest.

MW-4
APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of MW-1 MMPE set-up, facing northwest.

View of TerraNova tanker pumping recovered fluids at conclusion of MMPE, facing north.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of site after MMPE equipment broken down, facing west.

View of the site prior to the groundwater sampling event, facing west-northwest.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of MW-1, facing southwest.

View of MW-4, facing south.

APPENDIX B SITE PHOTOGRAPHS – MARCH 1, 20, 24 AND MAY 3, 2023
NCDEQ; 10873_Little Cupboard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

View of MW-14, facing south.

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX C

JOB HAZARD ANALYSES, SURVEY NOTES,
AND FIELD DATA SHEETS
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Drill Rig N/A
tools and materials N/A
Drill Rig N/A
Drill Rig 85 dBA
Exposure Potential
Likely
Likely
Likely
Start Stop
7:45 8:45
8:45 9:00
9:00 16:00
16:00 16:30
16:30 16:45
16:45 17:15
Date and Time:
03/01/23 @ 09:00
03/01/23 @ 09:00
03/01/23 @ 09:00Sandra Miller / CATLIN
Equipment Used:PPE D/Oil-Water Interface Probe/Sampling Supplies/Generator/Pressure Washer/PID
PERSONNEL ONSITE
Name and Company (Print)Signature
Logan Hamilton / CATLIN Logan Hamilton
Tommy Chalmers / CATLIN
CATLIN departs site for hotel and completion of today's notes.
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac)surroundings
DAILY TASK
Vehicle #55
Mileage:Start: End:
Mob and travel to Little Cubbard site (from Carson Property site).
On-site Health and Safety Meeting covering proper PPE, weather, road safety, and rig precautions.
Set up, drilled with smaller augers and collected soil samples, went down with larger augers for 4" well
installation, installed 4"-diameter casing/screen, deconned equipment, and developed well. Final construcion of new well and well pad completed after drillers went to get supplies. Developed well.
Surveyed MW-14 using known elevation from MW-1.
Final deconning and cleanup of site. Packed augers back on rig in preparation for traveling.
Insect bites and stings surroundings
Drill Rig Operations Likely
Heavy Lifting/ Moving Likely
Rolling or Pinching Objects Likely
Noise Likely
Biological Hazards
Name of Biological Hazard Source
Cold Weather Operations Unlikely
Heat (ambient)Unlikely
Slips/Trips/Falls Likely
NAPHTHALENE ppm
* Gas and/or Diesel
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
ETHYL BENZENE ppm
Date(s) this JHA
Conducted:
03/01/2023
Employee Certifying this JHA
Print Name: Benjamin J. Ashba, P.G.Signature:
Weather:High overcast, breezy, mid-60's
Potential Chemicals Concentration
BENZENE ppm
Site-Specific Job Hazard Analysis
Operational Phase Task/Operation Location Where Task/Operation Performed
Monitoring Soil Boring/Well Installation Little Cubbard, Ruth, NC
Page 1 of 1
CLIENT'S CATLIN
NAME:PROJECT:
CATLIN PROJECT #:PHASE:
INSTRUMENT #:
ELEVATION (TBM):DATE:3/1/2023 ROD #:UNITS (FT./M): FEET
TOP
BOTTOM4.844.866.426.484.834.87
FIELD NOTES BY:DATE:3/1/2023 INSTRUMENT BY:
NOTES REDUCED BY:DATE:3/6/2023 ROD PERSON:
HI - (-) = ELEV.* A sketch must be provided with the level notes.
S. MILLER L. HAMILTON
G. HILL S. MILLER
0.00
(+) = MID at TBM or BM (TOP - BOTTOM) * 100 = DISTANCE
TBM + (+) = HI (TOP + BOTTOM)/2 = MID (-)
1028.38 0.00
30 0 1028.38
29 0
28 0 1028.38 0.00
0.00
27 0 1028.38 0.00
1028.38 0.00
26 0 1028.38
25 0
24 0 1028.38 0.00
0.00
23 0 1028.38 0.00
1028.38 0.00
22 0 1028.38
21 0
20 0 1028.38 0.00
0.00
19 0 1028.38 0.00
1028.38 0.00
18 0 1028.38
17 0
16 0 1028.38 0.00
0.00
15 0 1028.38 0.00
1028.38 0.00
14 0 1028.38
13 0
12 0 1028.38 0.00
0.00
11 0 1028.38 0.00
1028.38 0.00
10 0 1028.38
9 0
8 0 1028.38 0.00
0.00
7 0 1028.38 0.00
1028.38 0.00
6 0 1028.38
5 0
MW-1
4 0 1028.38 0.00
6.45 MW-14
3 0 -4 4.85 1023.53 4.85
1023.53 4.85 MW-1
2 240 -6 6.45 1021.93
HI ELEV. (feet)CHECK (T+B)/2 NOTES
1 0 -2 4.85 1028.38
1023.53
POINT ANGLE
(degrees)
DISTANCE
(feet)MID (-)(+)
REDUCED LEVEL NOTES
NCDEQ - SLP Little Cupboard
221064
BENCH MARK DESC.:MW-1
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Drill Rig 85 dBA
Exposure Potential
Unlikely
Unlikely
Unlikely
Start Stop
7:45 11:30
11:30 11:45
11:45 15:00
15:00 17:15
Date and Time:
03/20/23 @ 11:45Sandra Miller / CATLIN
Equipment Used:PPE D/Oil-Water Interface Probe/Tablet
Opened and gauged wells, observed MMPE set-up, noted depths of stingers/vacuum/PID readings, take pictures.
Travel to hotel in Waxhaw for next site.
PERSONNEL ONSITE
Name and Company (Print)Signature
On-site health and safety briefing. Watch for cars in driveway and going down the road. Wear safety vest when
near road. Watch for ants and spiders when in and around wells. Wear hearing protection and and be careful on
and around MMPE equipment.
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac)surroundings
DAILY TASK
Truck #55 Mileage:Start: End:
Mob and travel to site.
Insect bites and stings surroundings
Cold Weather Operations Likely
Heat (ambient)Unlikely
Slips/Trips/Falls Likely
Noise Likely
Biological Hazards
Name of Biological Hazard Source
NAPHTHALENE ppm
* Gas and/or Diesel
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
ETHYL BENZENE ppm
Date(s) this JHA
Conducted:
03-20-23
Employee Certifying this JHA
Print Name: Sean O'Neil, PE Signature:
Weather:Sunny, breezy, mid 40s
Chemical Hazards
Potential Chemicals Concentration
BENZENE ppm
Site-Specific Job Hazard Analysis
Operational Phase Task/Operation Location Where Task/Operation Performed
Monitoring Mobile Multi-Phase Extraction (MMPE) Start-Up Little Cupboard, Ruth, NC
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Drill Rig 85 dBA
Exposure Potential
Unlikely
Unlikely
Unlikely
Start Stop
7:30 11:15
11:15 11:30
11:30 13:45
13:45 19:15
Date and Time:
03/24/23 @ 11:30Sandra Miller / CATLIN
Equipment Used:PPE D/Oil-Water Interface Probe/Tablet
Observed MMPE final stages and collected notes/data from AE, observed liquid pump-off by TerraNova (890 gal), observed MMPE breakdown, closed wells, took pictures.
Travel to Raleigh office via Lexington to check on presence of equipment left on site several weeks ago, gas for
truck, demob
PERSONNEL ONSITE
Name and Company (Print)Signature
DAILY TASK
Truck #55 Mileage:Start: End:
Mob and travel to site.
On-site health and safety briefing. Watch for cars in driveway and going down the road. Wear safety vest when
near road. Watch for ants and spiders when in and around wells. Wear hearing protection and and be careful on
and around MMPE equipment.
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac)surroundings
Noise Likely
Biological Hazards
Name of Biological Hazard Source
Insect bites and stings surroundings
Cold Weather Operations Likely
Heat (ambient)Unlikely
Slips/Trips/Falls Likely
NAPHTHALENE ppm
* Gas and/or Diesel
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
Chemical Hazards
Potential Chemicals Concentration
BENZENE ppm
ETHYL BENZENE ppm
Date(s) this JHA
Conducted:
03-24-23
Employee Certifying this JHA
Print Name: Sean O'Neil, PE Signature:
Weather:Sunny, high 70s
Site-Specific Job Hazard Analysis
Operational Phase Task/Operation Location Where Task/Operation Performed
Monitoring Mobile Multi-Phase Extraction (MMPE) Break-Down Little Cupboard, Ruth, NC
Source Exposure Limit
Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH
Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH
Source Exposure Limit
atmosphere N/A
atmosphere N/A
surroundings N/A
Exposure Potential
Likely
Likely
Likely
Start Stop
7:15 11:15
11:15 11:30
11:30 14:30
14:30 19:15
Date and Time:
5/3/23 @ 11:30
Equipment Used:PPE D/Oil-Water Interface Probe/Sampling Supplies/Aqua Troll 600/Bailers
Van #59 Mileage:
Weather:
Mob equipment and travel to site
On site safety briefing. Watch for ants/spiders near wells. Be aware of slips, trip, and falls. Wear safety vest and
watch for trucks and cars.
Locate, open, gauge, photograph, and sample wells MW-1, MW-4, and MW-14. Had to wait for recharge on the
wells. Field blank collected at 11:52.
Biological Hazards
Name of Biological Hazard Source
Insect bites and stings
Cold Weather Operations Unlikely
Heat (ambient)Unlikely
Slips/Trips/Falls Likely
surroundings
Finish COC and got PO#, depart site for Raleigh office, ice for samples, gas for van, demob van.
Major construction traffic and stop/crawl on I40 due to accident.
Start:End:
DAILY TASK
Snakes surroundings
Poison Plants (Ivy, Oak, and/or Sumac)surroundings
PERSONNEL ONSITE
Name and Company (Print)Signature
Sandra Miller / CATLIN
Chemical Hazards
Sunny, Windy, Low 60's
Site-Specific Job Hazard Analysis
Location Where Task/Operation Performed
Little Cupboard, Ruth, NC
Task/Operation
Gauge and Sample Wells
Employee Certifying this JHA
Print Name: Benjamin J. Ashba, P.G.Signature:
Operational Phase
Monitoring
Date(s) this JHA
Conducted:
5/3/2023
Potential Chemicals Concentration
BENZENE ppm
ETHYL BENZENE ppm
TOLUENE ppm
XYLENE, ALL ISOMERS ppm
METHYL TERT-BUTYL ETHER ppm
NAPHTHALENE ppm
Physical Hazards
Name of Physical Hazard Exposure Level/ Potential
* Gas and/or Diesel
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
MW-1 3.71
27.29 0.605
NMT 1.816
31 3.027
2
Method:Bailer Purge Start Time:12:34
Required Bails for 3 Well Volumes:8 Purge Stop Time:12:42
Required Bails for 5 Well Volumes:13 Was Well Purged Dry?Yes
Number of Bails Removed:5 Sample Time:13:03
Groundwater Removed (gal):1.2
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
12:31 13.06 207.55 0.05 7.39 26.79
12:32 12.58 149.01 0.05 7.23 27.78
12:33 12.21 120.29 41.98 7.07 28.94
12:34 11.66 139.09 58.61 3.78 29.19
12:35 11.51 144.20 60.78 3.27 29.39
12:36 11.52 139.32 60.91 3.21 29.50
12:37 11.45 138.32 61.78 3.19 29.57
12:38 11.45 134.60 62.53 3.14 29.62
12:39 11.51 127.43 62.35 3.12 29.64
Laboratory:Con-Test Analysis:6200B
Laboratory Analysis Information
Geochemical Parameters
Depth to Water (ft below TOC)
GROUNDWATER SAMPLING FORM
Water Column (ft below TOC)
One Well Volume (gal)
Three Well Volumes (gal)
Five Well Volumes (gal)
NCDEQ-Scott Ryals
Monitoring Well Information
Sandy Miller
5/3/2023
Little Cubbard
221064.3
Mild turbidity; HCO. Bailed
dry twice. waited for
recharge to sample.
Aqua Troll 600
Turbidity and Additional
Sampling Notes
Well Diameter (inches)
Well Data
Well ID
Depth to Product (ft below TOC)
Total Well Depth (ft)
Purging Information Information
Volume of Groundwater in Well
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
MW-4 2.86
24.14 0.467
NMT 1.400
27 2.334
2
Method:Bailer Purge Start Time:12:18
Required Bails for 3 Well Volumes:6 Purge Stop Time:12:26
Required Bails for 5 Well Volumes:10 Was Well Purged Dry?Yes
Number of Bails Removed:5 Sample Time:12:49
Groundwater Removed (gal):1.2
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
12:14 12.99 230.27 0.00 7.34 28.12
12:15 12.69 244.98 0.00 7.21 28.13
12:16 11.81 211.19 6.09 7.20 28.45
12:17 11.65 211.34 69.69 2.85 28.99
12:18 11.65 211.88 66.69 2.95 29.05
12:19 11.63 216.33 67.03 3.18 29.12
12:20 11.68 214.67 69.67 3.04 29.15
12:21 11.66 218.56 70.73 3.82 29.17
12:22 11.68 220.55 71.56 4.09 29.23
Laboratory:Con-Test Analysis:
Mild turbidity; slightly
orange. HCO. Waited for
recharge to sample.
Laboratory Analysis Information
6200B
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua Troll 600
Turbidity and Additional
Sampling Notes
Depth to Water (ft below TOC)One Well Volume (gal)
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft)Five Well Volumes (gal)
NCDEQ-Scott Ryals
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
GROUNDWATER SAMPLING FORM
Little Cubbard Sandy Miller
221064.3 5/3/2023
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
MW-14 8.14
26.86 5.314
NMT 15.941
35 26.569
4
Method:Bailer Purge Start Time:13:13
Required Bails for 3 Well Volumes:67 Purge Stop Time:13 50
Required Bails for 5 Well Volumes:111 Was Well Purged Dry?Yes
Number of Bails Removed:53 Sample Time:13:56
Groundwater Removed (gal):12.7
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
13:29 11.62 267.72 45.45 3.52 25.14
13:30 11.69 267.13 44.86 3.92 25.16
13:31 11.70 269.81 43.60 3.70 25.10
13:32 11.56 280.69 40.78 3.63 25.10
13:33 11.68 274.98 43.18 3.59 25.04
13:34 11.67 275.56 42.46 4.24 25.14
13:35 11.61 284.30 41.30 3.36 24.64
13:36 11.67 282.20 40.66 3.60 24.61
13:37 11.65 284.22 39.89 4.42 24.48
13:38 11.64 286.28 39.77 3.62 24.50
13:39 11.57 291.97 38.36 3.64 24.39
13:40 11.63 288.86 37.94 3.69 24.37
13:41 11.63 290.26 37.33 3.87 24.33
13:42 11.65 291.18 36.82 3.74 23.76
13:43 11.61 294.40 36.27 3.90 23.52
13:44 11.61 294.63 36.06 4.14 23.76
13:45 11.64 292.88 35.78 4.01 23.64
13:46 11.65 290.47 35.73 4.02 23.60
13:47 11.73 281.00 35.84 3.90 24.19
Laboratory:Con-Test Analysis:
High turbidity; brownish-
red. HCO. Waited for
recharge to sample.
Laboratory Analysis Information
6200B
Well Diameter (inches)
Purging Information Information
Geochemical Parameters
Aqua Troll 600
Turbidity and Additional
Sampling Notes
Depth to Water (ft below TOC)One Well Volume (gal)
Depth to Product (ft below TOC)Three Well Volumes (gal)
Total Well Depth (ft)Five Well Volumes (gal)
NCDEQ-Scott Ryals
Monitoring Well Information
Well Data Volume of Groundwater in Well
Well ID Water Column (ft below TOC)
GROUNDWATER SAMPLING FORM
Little Cubbard Sandy Miller
221064.3 5/3/2023

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX D

WELL LOG AND
WELL CONSTRUCTION RECORD
35.0
0.0
5.0
10.0
15.0
20.0
25.0
30.0
33.0
3
4
7
6
6
5
5
10
4
1
2
3
3
3
3
0
3
4
4
5
5
5
5
6
2
2
3
4
4
4
3
5
35.0
15.0
35.0
0.0 1.0
13.0
35.04" Sch. 40 PVC4" Slot .010Sch. 40 PVCD
D
D
M
M
W
W
W
0.5
18.0
33.0
0.5
18.0
33.0
35.0
ASPHALT
(CL) - Dark red grading to reddish brown, Silty CLAY.
Mod. HCO
Orangish brown and red with black streaks and tr. mica
and/or quartz at 10.0' BLS
(CL) - Orangish red with black streaks with browns,
Sandy CLAY with tr. mica and/or quartz. Mod HCO
(SW) - White with tan and black, Cse. SAND with tr.
mica and/or quartz
BORING TERMINATED AT ELEVATION 986.9 ft in
Cse. SAND with quartz fragments
1021.4
1003.9
988.9
1021.4
1003.9
988.9
986.9
47.8
68.6
283
58.7
53.9
113
769
1556
DRILL MACHINE:Diedrich D-50 METHOD:HSA
COUNTY:RUTHERFORD
1121616 607849
T.O.C. ELEV.:
TOTAL DEPTH:
WELL DEPTH:
NC
SHEET
30.2
27.1
DEPTH
1
1021.93
35.0
35.0
0 HOUR DTW:
24 HOUR DTW:END DATE:3/1/23
OF1
BORING LOCATION: NE corner of Building
BLOW COUNT
0.5ft
START DATE:3/1/23
0.5ft
WELL ID:
STATE:
MW-14NORTHING:
LOGGED BY:
DRILLER:
CREW:
0.5ft0.5ft
EASTING:
PROJECT NO.:221064
SYSTEM:NCSP NAD 83 (USft)
Little CubbardPROJECT:S. Miller
D. T. Chalmers, JR
L. Hamilton
LOCATION:RUTHERFORDTON
ENVIRONMENTAL, CIVILGEOTECHNICAL
Wilmington, Raleigh, Washington,Charleston
CATLIN BORING LOG 221064_NCDEQ SLP LITTLE CUBBARD.GPJ CATLIN.GDT 3/6/23Portland Cement Bentonite Pellets #2 Medium Sand
0.0
WELL LOG
WELL
DETAIL
SOIL AND ROCK
DESCRIPTIONLAB.DEPTH
MOIS
0.0 LAND SURFACE
LOG ELEVATION
1021.9
OVA
(ppm)
221064
03/01/23
HSA
4146A
27.13
MW-14
-81.9474685
D. T. Chalmers, JR
35.384342
RUTHERFORD
1
X
3/6/2023
10.25
Surface Pour
CATLIN Engineers and Scientists
X
4 Slot .010
137 US Hwy 64, RUTHERFORDTON, 28139
Bent. Pellets13
15
Concrete
N/A
13 35 Torpedo Sand
35.0
X
1
1
0
15 35 PVC
4
Sch. 40
Surface Pour
0 Sch. 40 PVC
Well ID#:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
(if well field, one lat/long is sufficient)
N
6. Is (are) the well(s):
Yes
TemporaryPermanent or
or No7. Is this a repair to an existing well:
8. Number of wells constructed:
For multiple injection or non-water supply wells ONLY with the same construction, youcan submit one form.
9. Total well depth below land surface:
For multiple wells list all depths in different (example- 3@200' and 2@100')
W
(ft.)10. Static water level below top of casing:
If water level is above casing, use "+"
11. Borehole diameter:
MATERIAL
FROM
Residential Water Supply (shared)
Adapted from Form GW-1
ft.
ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.
ft.
(ft.)
(in.)
ft.
ft.ft.
ft.
ft.
ft.in.
in.
ft.
ft.
ft.ft.
ft.
ft.
13b. Disinfection type:
22. Certification:
Revised 2-22-2016
ft.NCDEQ-Little Cubbard
TO DIAMETER THICKNESS MATERIAL
FROM17. SCREEN DIAMETER SLOT SIZE MATERIALTHICKNESS
FROM TO MATERIAL
ft.ft.
ft.
ft.
FROM TO
18. GROUT
MATERIAL
19. SAND/GRAVEL PACK (if applicable)
1. Well Contractor Information:
This form can be used for single or multiple wells
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural
Non-Water Supply Well:
Monitoring
Geothermal (Heating/Cooling Supply)
Industrial/Commercial
Irrigation
15. INNER CASING OR TUBING (geothermal closed-loop)
Municipal/Public
Residential Water Supply (single)
ft.
ft.ft.
ft.ft.
ft.
ft.ft.
ft.
TO
EMPLACEMENT METHOD & AMOUNT
in.
in.
in.
EMPLACEMENT METHOD
Recovery
Injection Well:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of
this record has been provided to the well owner.
If this is a repair, fill out known well construction information and explain the nature ofthe repair under #21 remarks section or on the back of this form.
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
13a. Yield (gpm)
FOR WATER SUPPLY WELLS ONLY:
Method of test:
Amount:
For Internal Use ONLY:
14. WATER ZONES
FROM TO DESCRIPTION
FROM TO
24c. For Water Sypply & Injection Wells:Also submit one copy of this form within 30 days of completion of wellconstruction to the county health department of the county where constructed.
DIAMETER THICKNESS
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
21. REMARKS
20. DRILLING LOG (attach additional sheets if necessary)
5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees:
Signature of Certified Well Contractor Date
24a. For All Wells: Submit this form within 30 days of completion of wellconstruction to the following:
SUBMITTAL INSTRUCTIONS
Division of Water Resources, Information Processing Unit,1617 Mail Service Center, Raleigh, NC 27699-1617
Division of Water Resources, Underground Injection Control Program,1636 Mail Service Center, Raleigh, NC 27699-1636
16. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
North Carolina Department of Environment and Natural Resources - Division of Water Resources
24b. For Injection Wells ONLY: In addition to sending the form to theaddress in 24a above, also submit a copy of this form within 30 days ofcompletion of well construction to the following:
WELL CONSTRUCTION RECORD
23. Site diagram or additional well details:
Aquifer Recharge Groundwater Remediation
Stormwater Drainage
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling Return)
Salinity Barrier
Subsidence Control
Tracer
Other (explain under #21 Remarks)
4. Date Well(s) Completed:
5a. Well Location:SEE
ATTAC
H
E
D
0-009299
N/A

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX E

MMPE REPORT AND
DISPOSAL DOCUMENTS

www.AdvancedEnvironmental.com
"Your Environmental Solutions Partner"
ADVANCED ENVIRONMENTAL
SERVICES, INC.
PO Box 38218
Greensboro, NC 27438
[phone]
[e-mail]
www.AdvancedEnvironmental.com
INVOICE
BILL TO
Catlin Engineers &
Scientists
220 Old Dairy Farm Road
Wilmington, NC 28405
SHIP TO
Catlin Engineers &
Scientists
accounts.payable@catlinu
sa.com
INVOICE #2138
DATE 03/30/2023
DUE DATE 03/30/2023
TERMS Net 45

JOB#; NAME DATES OF SERVICE PO# OR PM
Little Cuppard *** 3/2 - 3/24, 2023 ***Ben Ashba, PG
TASK DESCRIPTION QTY RATE UNITS AMOUNT
7.420 MMPE system, power supply and mobe 1 2,500.00 week 2,500.00
7.420a Equipment 1 1,500.00 event 1,500.00
7.420c Fluids disposal 890 0.35 gallon 311.50
7.420d Time for MMPE prep., system setup,
supervision, operation and
maintenance, breakdown and non-
mobe travel
1 2,500.00 week 2,500.00
12.030 Per-diem 4 155.00 night 620.00

Thank you for your business! Past due amounts
are subject to finance charges of 1.5% per month
plus all applicable attorney's collection fees.
SUBTOTAL 7,431.50
TAX 0.00
TOTAL 7,431.50
BALANCE DUE $7,431.50

ADVANCED
ENVIRONMENTAL SERVICES, INC.
“Your Environmental Solutions Partner”

MOBILE
MULTI-PHASE
EXTRACTION REPORT

Site Location:

Little Cubbard
137 US Hwy 64
Rutherfordton, NC

Prepared for:

Catlin Engineers and Scientists
220 Old Dairy Rd.
Wilmington, NC 28405
PM – Ben Ashba, PG

March 28, 2023

TABLE OF CONTENTS

EVENT SUMMARY

MMPE FIELD LOG

MASS-REMOVAL CALCULATION

FIELD NOTES

DISPOSAL MANIFESTS

MOBILE MULTI-PHASE EXTRACTION
EVENT SUMMARY

March 28, 2023

Location: Little Cubbard
137 US Hwy 64
Rutherfordton, NC

Client: Catlin Engineers and Scientists
220 Old Dairy Rd.
Wilmington, NC 28405

Event Dates: March 20 - 24, 2023
Advanced Job # 03 - 2316

Advanced Personnel: Lee Heilig and Chad Widner

MMPE System: MMPE system rated 140 CFM at 24” hg
4’ discharge stack - 3” diameter
5,000 - gallon tanker
140’ piping 1.0” hose to 3 wells

Extraction Well: MW-1, MW-4 and MW-14

Well Initial FP / WL(ft) Final FP / WL(ft) Stinger depth(ft) Run Time
/ Changed To
MW-1 27.26 30.02 29’/30’ 93.0 hours
MW-4 24.43 26.43 26’/27’ 93.0 hours
MW-14 27.01 33.11 29’/34’ 96.0 hours

Description of Event:
The MMPE event ran from 13:05 March 20, through 13:05 March 24, 2023. The MMPE system
was active for 96.0 hours. During the event vacuum at the recovery pump ranged from 17.0 to
20.5 inches of mercury (hg) and stabilized at approximately 17.0 inches of mercury. Airflow
rates ranged from 2,800 to 3,300 feet per minute and stabilized at approximately 3,300 feet per
minute. System temperature ranged from 102 – 132 degrees F and humidity maintained 99
percent. Field gauged volatile organic compounds (VOC’s) decreased from 24,000 to 13,000
(PPM) throughout the event.

Groundwater / Product Mix Recovered:
During the event a total of 890 gallons of product/water mix were removed from the site and
properly disposed at a certified North Carolina disposal facility. No measurable free product
was recovered during the event. Total fluids recovered, was measured based on stick readings
conducted during and following the event. Based on 96.0 hours of operation and a total of 890
gallons recovered, the average groundwater recovery rate was calculated to be approximately
9.27 gallons per hour.

Events Results:
Based on mass-removal calculations 523.17 pounds or 85.04 gallons of VOC’s were removed as
vapor. Using Dwyer Magnehelic gauges, vacuum influence was monitored at MW-2. No
measurable vacuum influence was observed throughout the event. No measurable draw
down was observed throughout the event. Following the event, no free product was identified
in any well.

MMPE FIELD LOG:
CLIENT: Catlin Engineering
JOB NAME: Little Cubbard
LOCATION: Rutherfordton, NC
MMPE EVENT DATES: March 20 - 24, 2023
EXTRACTION POINTS: MW-1, MW-4 and MW-14
AES JOB NUMBER: 03 - 2316
DATE TIME FLOW (f/m) HUM.(%) TEMP. (F)VOC's(ppm)VAC. (hg")GALLONS STINGER/WL's EXTRACTION POINTS (hg")
MW-1 MW-4 MW-14
Start 13:05 Stinger(ft)29'/30'26'/27'29'/34'
Initial WL's 27.26 24.43 27.01
03/20/23 13:30 2,800 99 102 24,000 20.5 7.0 7.0 7.0
14:30 2,900 99 107 24,000 20.0 7.0 7.0 7.0
15:30 3,200 99 111 21,000 18.5 6.0 5.5 6.0
17:30 3,200 99 116 21,000 18.0 5.5 5.0 5.5
03/21/23 8:30 3,200 99 118 20,000 18.0 5.5 5.0 5.5
10:30 3,200 99 121 19,000 18.0 5.5 5.0 5.5
17:30 3,200 99 128 18,000 18.0 5.5 5.0 5.5
18:30 3,200 99 126 18,000 18.0 5.5 5.0 5.5
03/22/23 8:15 3,200 99 121 14,000 17.5 225 gal.5.0 5.0 5.0
10:15 3,200 99 122 14,000 17.5 5.0 5.0 5.0
15:45 3,200 99 124 17,000 17.5 5.0 5.0 5.0
17:30 3,300 99 123 17,000 17.5 5.0 5.0 5.0
03/23/23 8:15 3,300 99 125 15,000 17.0 400 gal. 5.0 5.0 5.0
10:15 3,300 99 127 14,000 17.0 5.0 5.0 5.0
16:00 3,300 99 128 14,000 17.0 5.0 5.0 5.0
17:30 3,300 99 123 14,000 17.0 5.0 5.0 5.0
03/24/23 8:15 3,300 99 127 14,000 17.0 525 gal. 5.0 5.0 5.0
11:00 3,000 99 132 13,000 17.0 5.0 5.0 5.0

END 13:05 Total fluids: 890 gal.Final WL's 30.02 26.43 33.11
Total free product:0.0
DATE TIME STINGER/WL's Vacuum Influence Well Gauging (ft)
MW-2 MW-2
Start 13:05

03/20/23 28.40

03/21/23 0.00 28.38

03/22/23 0.00 28.39

03/23/23 0.00 28.34

03/24/23 0.00 28.37

END 13:05 Final W/L 28.37
Page 1 of 1
MOBILE MULTI-PHASE EXTRACTION EVENT
SITE NAME: Little Cubbard CLIENT: Catlin Engineering
INCIDENT NUMBER:
AVERAGE DEPTH TO GROUNDWATER: 24 - 27 feet
DESCRIBE SOIL IN THE SATURATED ZONE:
AVERAGE HYDRAULIC CONDUCTIVITY (if known):
EXTRACTION WELLS USED FOR MMPE: MW-1, MW-4 and MW-14
SPECIFICATIONS OF THE MMPE SYSTEM (cfm @ in Hg): 140 cfm @ 24.0"Hg
DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd)
Date Hours Vacuum Velocity Pipe ID Temp Rel Humid Water Water Qstd(inches of Hg)(ft/min)(in)(°F)(%)Vapor (Wt%)Vapor (Vol%)(flow)
3/20/23 24.00 19.25 3025.00 3 109 99.0 0.051 0.076 127
3/21/23 48.00 18.00 3200.00 3 123 99.0 0.093 0.130 124
3/22/23 72.00 17.50 3300.00 3 123 99.0 0.093 0.130 128
3/23/23 96.00 17.00 3300.00 3 128 99.0 0.108 0.148 124
3/24/23
NOTES
Qstd = Flow at DSCFM
Vacuum = The level of vacuum being applied should be recorded from the MMPE system (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge piping (from the MMPE system)
Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Bwsw = water vapor % by weight, i.e., pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity)
Bws = water vapor % by volume
EQUATIONS
Bws = (Bwsw/18 lb-mole H20)/[(1/28.84 lb-mole dry air) + (Bwsw/18 lb-mole H2O)]
Qstd = (1-Water Vapor) * velocity * (PI * (diameter/24)2) * (528°R/(Temp + 460))
EMISSION CALCULATIONS
Elapsed
Time Flow PPMmeasured PPMwet PPMdry K PPMconc Cc:m Cc PMRc PMRg PMR
(hour)(DSCFM)(ppm)(#C - gas)(mg/dsm3)(lb/dscf)(lb/hour)(lb/hour)(lb)
24 127 22500 22500 24339 1 24339 12144 0.00075815 5.79 6.71 160.94
48 124 18750 18750 21544 1 21544 10750 0.000671095 4.99 5.77 138.47
72 128 15500 15500 17810 1 17810 8886 0.000554772 4.25 4.92 118.05
96 124 14000 14000 16423 1 16423 8194 0.000511565 3.81 4.40 105.72
Total emissions in pounds 523.17
Total emissions as gallons (pounds / 6.152)85.04
NOTES
PPMmeasured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
PPMwet = "wet" concentration
PPMdry = "dry" concentration
K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Hexane K = 6)
PPMc= PPMv, Volumetric concentration of VOC emissions as carbon, dry basis at STP
Cc:m = mg/dsm3, mass concentration of VOC emissions as carbon
Mc = 12.01 mg/mg-mole, molecular weight of carbon
K3 = 24.07 dsm3/106 mg-mole, mass to volume conversion factor at STP
Cc = lb/dcsf, mass concentration of VOC emissions as carbon, dry basis at STP
PMRc = lb/hr, pollutant mass removal rate of VOC's as carbon
PMRg = lb/hr, pollutant mass removal rate of of VOC's as gasoline
PMR = lb, pollutant mass removal of VOC's as gasoline
EQUATIONS
PPMwet = PPMmeasuredPPMdry = (PPMwet)/(1-Bws)
PPMc = (PPMd)(K)
Cc:m = (PPMc)(Mc / K3)
Cc = (Cc:m)(62.43x10-9 lb-m3/mg-ft3)
PMRc = (Cc)(Qstd)(60 minute/hour)
PMRg = (PMRc)(Mg/Mcg)
PMR = (PMRg)(#hours)
I C
MMPR. Field Log
Went:Cc,f/,'r:J . I SiteName: L i-tflelv. bb,..rof
ells: ""w -l M ~-'f, M "" -14
:oS
D~ D
: bf)
Page#_j_
Job J'1nmher. D 3-Z-31 4
Event Dates: 3 (z,,-o-2 '-f f2_oz3
'ov1~
MMPKField Log
Went:Ce< t/,·n L_ ,
SiteName:£...i'ftte. Cl,{bD'-lroi tJ
E'Xtlra~•Wells:Mv-1 1V1w-L1 Mw-h "'.2 . 3 / ) _;;;, 22 2. taA ,
: '
JobNwuber: D3-Z3I r;,
EventDates: 3 /-zi~ -2-~/202-3
I
I i I l I I I I I
I
MATERIAL ~p Manifest Document No.
Page of MANIFEST TERRA NOVA I /
EMERGENCY PHONE NO. POST OFFICE BOX 357 TEL [phone] Zebra Job No. •
[phone] HIGH POINT, NC 27261 FAX [phone]'<01/,./ < . ,"'
I GENERATOR INFORMATION I
Name r I; US EPA ID No.
I I ,,/, Ui'/ I / .(•I/ //'•' / /Y1( ,, ~/1 Street Address Maillng Address Phone No. .. ,/5'-:/ v s /.JIA.)~ l-V l~,.-:1{> .-,,,"71 -L/3'/J ,-""; ' ''.I''\ _)
Contact /7 ,/,, { -f:, .r;,;.,,,,1/ ... _,/ ; t, ,j
DESCRIPTION OF MATERIALS
USDOT Proper Shipping Name Hazard UN/NA Packing Containers Total Unit HM (Complete All Items for Hazardous Materials) Class or Div ID No. Group Qty. Type Quantity Wt.Nol.
a. I ;</t'A/ ,;J,., L . r-, • ---TT $() #Jill .--/(' /11,1?,;-) I
b. 0 t?'
c.
ADDITIONAL INFORMATION ERG No. Zebra Profile Code Facility Use
a.
/)/ j _) -b. I/ --" c. ,,/"_,,/'
GENERATOR'S CERTIFICATION
This is to certify that the above-described materials are properly classified, described, packaged, marked and labeled, and are in
proper condition for transportation according to the applicable regulations of the Department of Transportation. I further certify that
non~ of the materials described above are a hazardous waste as defined by EPA 40 CFR Part 261 or any applicable state law, and
unless specifically identified above, the materials contain less than 1,000 ppm total halogens and do not contain quantifiable levels
(2 ppm) of PCBs as defined by EPA 40 CFR Parts 279 and 761.
rinted ype Name _,, 1 ,; .
Transporter TN Solutions, Inc.
Address 901 East Springfield Road
High Point, NC 27263
gnature / _,
'/
Mo. Day r. JI---
TRANSPORTER INFORMATION
I hereby acknowledge receipt of the above-described materials for transport
fr~om the r ene.iJor site listed above. bv / I ;.!, ,., I ~-;:: ,)/ J( -:• ,.~ y'-,t' ', -z _,
Slgnaturr £' ,,-, )',J_Lft_, Shipment Date
I hereby acknowledge receipt of the above-described materials were received
""'T""ra_n_s-po_rt.,..e_r_o_r -----------r.u-,-n""'lt'"'N""~-----1----,from the generator site and Were transported to the facility listed below.
EPA ID No. NCO991302669 \ 1 -I
Phone [phone] Signature Delivery Date
' FACILITY INFORMATION
Facility TN Solutions, Inc. I hereby acknowledge receipt of the materials covered by this manifest
except for any discrepancy noted below.
Address
901 East Springfield Road
High Point, NC 27263 Signature Receipt Date
Dlscreoancles / Routlna Codes I Handlna Methods
Facility or NCO991302669 a.
EPAID No.
J Phone [phone] b. ..
Contact c. C
Bill Hunter ,,
ORIGINAL· Facility Retain COPY 2 • Return to Generator COPY 3 • Transporter Retain \.COPY 4 • Generator Retain ,fJ -•
l
I
I

NCDEQ; 10873_Little Cubbard CATLIN Engineers and Scientists
CATLIN Project No. 221064 May 2023

APPENDIX F

LABORATORY ANALYTICAL REPORT
AND CHAIN OF CUSTODY DOCUMENT

39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
May 17, 2023
Ben Ashba
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
Project Location: Ruth, NC
Client Job Number:
Project Number: 221064.3
Laboratory Work Order Number: 23E0926
Enclosed are results of analyses for samples as received by the laboratory on May 5, 2023. If you have any questions concerning
this report, please feel free to contact me.
Sincerely,
Kaitlyn A. Feliciano
Project Manager
Page 1 of 25
Table of Contents
Table of Contents
Sample Summary 3
Hits Only Report 4
Case Narrative 6
Sample Results 7
23E0926-01 7
23E0926-02 9
23E0926-03 11
23E0926-04 13
Sample Preparation Information 15
QC Data 16
Volatile Organic Compounds by GC/MS 16
B340060 16
Flag/Qualifier Summary 20
Certifications 21
Chain of Custody/Sample Receipt 23
Page 2 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
5/17/2023
CATLIN Engineers & Scientists
220 Old Dairy Road
Wilmington, NC 28405
ATTN: Ben Ashba
221064.3
23E0926
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Ruth, NC
230503-3
MW-1 23E0926-01 Ground Water SM21-23 6200B
MW-4 23E0926-02 Ground Water SM21-23 6200B
MW-14 23E0926-03 Ground Water SM21-23 6200B
FB Field Blank 23E0926-04 Field Blank SM21-23 6200B
[TOC_1]Sample Summary[TOC]
Page 3 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
[TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23E0926-01MW-1
DL
1,2,4-Trimethylbenzene 3200 200 g/L SM21-23 6200B80
1,3,5-Trimethylbenzene 740 200 g/L SM21-23 6200B60
2-Butanone (MEK)1200 2000 g/L SM21-23 6200BJ670
Acetone 2300 20000 g/L SM21-23 6200BJ800
Benzene 30000 200 g/L SM21-23 6200B74
Diisopropyl Ether (DIPE)470 200 g/L SM21-23 6200B81
Ethylbenzene 2700 200 g/L SM21-23 6200B88
Isopropylbenzene (Cumene)160 200 g/L SM21-23 6200BJ60
m+p Xylene 12000 400 g/L SM21-23 6200B200
Methyl tert-Butyl Ether (MTBE)28000 200 g/L SM21-23 6200B68
Naphthalene 870 200 g/L SM21-23 6200B150
n-Propylbenzene 380 200 g/L SM21-23 6200B50
o-Xylene 6300 200 g/L SM21-23 6200B97
Toluene 44000 200 g/L SM21-23 6200B89
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23E0926-02MW-4
DL
1,2,4-Trimethylbenzene 3900 200 g/L SM21-23 6200B80
1,3,5-Trimethylbenzene 1000 200 g/L SM21-23 6200B60
2-Butanone (MEK)780 2000 g/L SM21-23 6200BJ670
Benzene 9400 200 g/L SM21-23 6200B74
Ethylbenzene 4100 200 g/L SM21-23 6200B88
Isopropylbenzene (Cumene)210 200 g/L SM21-23 6200B60
m+p Xylene 15000 400 g/L SM21-23 6200B200
Methyl tert-Butyl Ether (MTBE)700 200 g/L SM21-23 6200B68
Naphthalene 790 200 g/L SM21-23 6200B150
n-Propylbenzene 520 200 g/L SM21-23 6200B50
o-Xylene 7700 200 g/L SM21-23 6200B97
Toluene 38000 200 g/L SM21-23 6200B89
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23E0926-03MW-14
DL
1,2,4-Trimethylbenzene 2900 500 g/L SM21-23 6200B200
1,3,5-Trimethylbenzene 650 500 g/L SM21-23 6200B150
2-Butanone (MEK)2700 5000 g/L SM21-23 6200BJ1700
Acetone 4300 50000 g/L SM21-23 6200BJ2000
Benzene 30000 500 g/L SM21-23 6200B180
Diisopropyl Ether (DIPE)890 500 g/L SM21-23 6200B200
Ethylbenzene 3700 500 g/L SM21-23 6200B220
Isopropylbenzene (Cumene)190 500 g/L SM21-23 6200BJ150
m+p Xylene 12000 1000 g/L SM21-23 6200B490
Methyl tert-Butyl Ether (MTBE)77000 500 g/L SM21-23 6200B170
Naphthalene 800 500 g/L SM21-23 6200B380
n-Propylbenzene 450 500 g/L SM21-23 6200BJ120
o-Xylene 6400 500 g/L SM21-23 6200B240
Toluene 59000 500 g/L SM21-23 6200B220
Client ID:Lab ID:
Analyte Results/Qual RL Units Method
23E0926-04FB Field Blank
DL
Acetone 2.6 50 g/L SM21-23 6200BJ2.0
Page 4 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary
section of this report. Users must review this report in its entirety to determine data usability and assessment.
Page 5 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method 6200B elevated reporting limits for samples 23E0926-01,02+03 due to elevated concentrations of target compounds.
[TOC_1]Case Narrative[TOC]
SM21-23 6200B
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
2,2-Dichloropropane
23E0926-01[MW-1], 23E0926-02[MW-4], 23E0926-03[MW-14], 23E0926-04[FB Field Blank], B340060-BLK1, B340060-BS1, B340060-BSD1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
Diisopropyl Ether (DIPE)
B340060-BSD1
Elevated reporting limit due to high concentration of target compounds.
Analyte & Samples(s) Qualified:
RL-11
23E0926-01[MW-1], 23E0926-02[MW-4], 23E0926-03[MW-14]
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Reporting Specialist
Page 6 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 5/3/2023 13:03
[TOC_2]23E0926-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
2300 20000 5/13/23 18:35 MFFg/L800 5/12/23SM21-23 6200B400JAcetone
30000 200 5/13/23 18:35 MFFg/L74 5/12/23SM21-23 6200B400Benzene
ND 200 5/13/23 18:35 MFFg/L59 5/12/23SM21-23 6200B400Bromobenzene
ND 200 5/13/23 18:35 MFFg/L110 5/12/23SM21-23 6200B400Bromochloromethane
ND 200 5/13/23 18:35 MFFg/L63 5/12/23SM21-23 6200B400Bromodichloromethane
ND 200 5/13/23 18:35 MFFg/L160 5/12/23SM21-23 6200B400Bromoform
ND 800 5/13/23 18:35 MFFg/L530 5/12/23SM21-23 6200B400Bromomethane
1200 2000 5/13/23 18:35 MFFg/L670 5/12/23SM21-23 6200B400J2-Butanone (MEK)
ND 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B400n-Butylbenzene
ND 200 5/13/23 18:35 MFFg/L51 5/12/23SM21-23 6200B400sec-Butylbenzene
ND 200 5/13/23 18:35 MFFg/L57 5/12/23SM21-23 6200B400tert-Butylbenzene
ND 200 5/13/23 18:35 MFFg/L65 5/12/23SM21-23 6200B400Carbon Tetrachloride
ND 200 5/13/23 18:35 MFFg/L48 5/12/23SM21-23 6200B400Chlorobenzene
ND 20000 5/13/23 18:35 MFFg/L8100 5/12/23SM21-23 6200B400Ethanol
ND 200 5/13/23 18:35 MFFg/L80 5/12/23SM21-23 6200B400Chlorodibromomethane
ND 200 5/13/23 18:35 MFFg/L140 5/12/23SM21-23 6200B400Chloroethane
ND 200 5/13/23 18:35 MFFg/L56 5/12/23SM21-23 6200B400Chloroform
ND 240 5/13/23 18:35 MFFg/L200 5/12/23SM21-23 6200B400Chloromethane
ND 200 5/13/23 18:35 MFFg/L62 5/12/23SM21-23 6200B4002-Chlorotoluene
ND 200 5/13/23 18:35 MFFg/L62 5/12/23SM21-23 6200B4004-Chlorotoluene
ND 200 5/13/23 18:35 MFFg/L64 5/12/23SM21-23 6200B4001,2-Dibromoethane (EDB)
ND 200 5/13/23 18:35 MFFg/L52 5/12/23SM21-23 6200B4001,2-Dichlorobenzene
ND 200 5/13/23 18:35 MFFg/L55 5/12/23SM21-23 6200B4001,3-Dichlorobenzene
ND 200 5/13/23 18:35 MFFg/L51 5/12/23SM21-23 6200B4001,4-Dichlorobenzene
ND 200 5/13/23 18:35 MFFg/L64 5/12/23SM21-23 6200B400Dichlorodifluoromethane (Freon 12)
ND 200 5/13/23 18:35 MFFg/L55 5/12/23SM21-23 6200B4001,1-Dichloroethane
ND 200 5/13/23 18:35 MFFg/L120 5/12/23SM21-23 6200B4001,2-Dichloroethane
ND 200 5/13/23 18:35 MFFg/L56 5/12/23SM21-23 6200B4001,1-Dichloroethylene
ND 200 5/13/23 18:35 MFFg/L56 5/12/23SM21-23 6200B400cis-1,2-Dichloroethylene
ND 200 5/13/23 18:35 MFFg/L69 5/12/23SM21-23 6200B400trans-1,2-Dichloroethylene
ND 200 5/13/23 18:35 MFFg/L77 5/12/23SM21-23 6200B4001,2-Dichloropropane
ND 200 5/13/23 18:35 MFFg/L46 5/12/23SM21-23 6200B4001,3-Dichloropropane
ND 200 5/13/23 18:35 MFFg/L140 5/12/23SM21-23 6200B400L-042,2-Dichloropropane
ND 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B4001,1-Dichloropropene
ND 200 5/13/23 18:35 MFFg/L65 5/12/23SM21-23 6200B400cis-1,3-Dichloropropene
ND 200 5/13/23 18:35 MFFg/L57 5/12/23SM21-23 6200B400trans-1,3-Dichloropropene
470 200 5/13/23 18:35 MFFg/L81 5/12/23SM21-23 6200B400Diisopropyl Ether (DIPE)
2700 200 5/13/23 18:35 MFFg/L88 5/12/23SM21-23 6200B400Ethylbenzene
ND 2000 5/13/23 18:35 MFFg/L480 5/12/23SM21-23 6200B4002-Hexanone (MBK)
160 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B400JIsopropylbenzene (Cumene)
ND 200 5/13/23 18:35 MFFg/L51 5/12/23SM21-23 6200B400p-Isopropyltoluene (p-Cymene)
28000 200 5/13/23 18:35 MFFg/L68 5/12/23SM21-23 6200B400Methyl tert-Butyl Ether (MTBE)
ND 2000 5/13/23 18:35 MFFg/L71 5/12/23SM21-23 6200B400Methylene Chloride
ND 2000 5/13/23 18:35 MFFg/L530 5/12/23SM21-23 6200B4004-Methyl-2-pentanone (MIBK)
[TOC_1]Sample Results[TOC]
Page 7 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 5/3/2023 13:03
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
870 200 5/13/23 18:35 MFFg/L150 5/12/23SM21-23 6200B400Naphthalene
380 200 5/13/23 18:35 MFFg/L50 5/12/23SM21-23 6200B400n-Propylbenzene
ND 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B400Styrene
ND 200 5/13/23 18:35 MFFg/L55 5/12/23SM21-23 6200B4001,1,2,2-Tetrachloroethane
ND 200 5/13/23 18:35 MFFg/L67 5/12/23SM21-23 6200B400Tetrachloroethylene
44000 200 5/13/23 18:35 MFFg/L89 5/12/23SM21-23 6200B400Toluene
ND 400 5/13/23 18:35 MFFg/L140 5/12/23SM21-23 6200B4001,2,3-Trichlorobenzene
ND 400 5/13/23 18:35 MFFg/L120 5/12/23SM21-23 6200B4001,2,4-Trichlorobenzene
ND 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B4001,1,1-Trichloroethane
ND 200 5/13/23 18:35 MFFg/L76 5/12/23SM21-23 6200B4001,1,2-Trichloroethane
ND 200 5/13/23 18:35 MFFg/L70 5/12/23SM21-23 6200B400Trichloroethylene
ND 200 5/13/23 18:35 MFFg/L62 5/12/23SM21-23 6200B400Trichlorofluoromethane (Freon 11)
ND 200 5/13/23 18:35 MFFg/L110 5/12/23SM21-23 6200B4001,2,3-Trichloropropane
3200 200 5/13/23 18:35 MFFg/L80 5/12/23SM21-23 6200B4001,2,4-Trimethylbenzene
740 200 5/13/23 18:35 MFFg/L60 5/12/23SM21-23 6200B4001,3,5-Trimethylbenzene
ND 8000 5/13/23 18:35 MFFg/L670 5/12/23SM21-23 6200B400Vinyl Acetate
ND 200 5/13/23 18:35 MFFg/L95 5/12/23SM21-23 6200B400Vinyl Chloride
12000 400 5/13/23 18:35 MFFg/L200 5/12/23SM21-23 6200B400m+p Xylene
6300 200 5/13/23 18:35 MFFg/L97 5/12/23SM21-23 6200B400o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 94.6 5/13/23 18:3570-130
Toluene-d8 97.8 5/13/23 18:3570-130
4-Bromofluorobenzene 94.2 5/13/23 18:3570-130
Page 8 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-02
Field Sample #: MW-4
Sample Matrix: Ground Water
Sampled: 5/3/2023 12:49
[TOC_2]23E0926-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
ND 20000 5/13/23 19:01 MFFg/L800 5/12/23SM21-23 6200B400Acetone
9400 200 5/13/23 19:01 MFFg/L74 5/12/23SM21-23 6200B400Benzene
ND 200 5/13/23 19:01 MFFg/L59 5/12/23SM21-23 6200B400Bromobenzene
ND 200 5/13/23 19:01 MFFg/L110 5/12/23SM21-23 6200B400Bromochloromethane
ND 200 5/13/23 19:01 MFFg/L63 5/12/23SM21-23 6200B400Bromodichloromethane
ND 200 5/13/23 19:01 MFFg/L160 5/12/23SM21-23 6200B400Bromoform
ND 800 5/13/23 19:01 MFFg/L530 5/12/23SM21-23 6200B400Bromomethane
780 2000 5/13/23 19:01 MFFg/L670 5/12/23SM21-23 6200B400J2-Butanone (MEK)
ND 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B400n-Butylbenzene
ND 200 5/13/23 19:01 MFFg/L51 5/12/23SM21-23 6200B400sec-Butylbenzene
ND 200 5/13/23 19:01 MFFg/L57 5/12/23SM21-23 6200B400tert-Butylbenzene
ND 200 5/13/23 19:01 MFFg/L65 5/12/23SM21-23 6200B400Carbon Tetrachloride
ND 200 5/13/23 19:01 MFFg/L48 5/12/23SM21-23 6200B400Chlorobenzene
ND 20000 5/13/23 19:01 MFFg/L8100 5/12/23SM21-23 6200B400Ethanol
ND 200 5/13/23 19:01 MFFg/L80 5/12/23SM21-23 6200B400Chlorodibromomethane
ND 200 5/13/23 19:01 MFFg/L140 5/12/23SM21-23 6200B400Chloroethane
ND 200 5/13/23 19:01 MFFg/L56 5/12/23SM21-23 6200B400Chloroform
ND 240 5/13/23 19:01 MFFg/L200 5/12/23SM21-23 6200B400Chloromethane
ND 200 5/13/23 19:01 MFFg/L62 5/12/23SM21-23 6200B4002-Chlorotoluene
ND 200 5/13/23 19:01 MFFg/L62 5/12/23SM21-23 6200B4004-Chlorotoluene
ND 200 5/13/23 19:01 MFFg/L64 5/12/23SM21-23 6200B4001,2-Dibromoethane (EDB)
ND 200 5/13/23 19:01 MFFg/L52 5/12/23SM21-23 6200B4001,2-Dichlorobenzene
ND 200 5/13/23 19:01 MFFg/L55 5/12/23SM21-23 6200B4001,3-Dichlorobenzene
ND 200 5/13/23 19:01 MFFg/L51 5/12/23SM21-23 6200B4001,4-Dichlorobenzene
ND 200 5/13/23 19:01 MFFg/L64 5/12/23SM21-23 6200B400Dichlorodifluoromethane (Freon 12)
ND 200 5/13/23 19:01 MFFg/L55 5/12/23SM21-23 6200B4001,1-Dichloroethane
ND 200 5/13/23 19:01 MFFg/L120 5/12/23SM21-23 6200B4001,2-Dichloroethane
ND 200 5/13/23 19:01 MFFg/L56 5/12/23SM21-23 6200B4001,1-Dichloroethylene
ND 200 5/13/23 19:01 MFFg/L56 5/12/23SM21-23 6200B400cis-1,2-Dichloroethylene
ND 200 5/13/23 19:01 MFFg/L69 5/12/23SM21-23 6200B400trans-1,2-Dichloroethylene
ND 200 5/13/23 19:01 MFFg/L77 5/12/23SM21-23 6200B4001,2-Dichloropropane
ND 200 5/13/23 19:01 MFFg/L46 5/12/23SM21-23 6200B4001,3-Dichloropropane
ND 200 5/13/23 19:01 MFFg/L140 5/12/23SM21-23 6200B400L-042,2-Dichloropropane
ND 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B4001,1-Dichloropropene
ND 200 5/13/23 19:01 MFFg/L65 5/12/23SM21-23 6200B400cis-1,3-Dichloropropene
ND 200 5/13/23 19:01 MFFg/L57 5/12/23SM21-23 6200B400trans-1,3-Dichloropropene
ND 200 5/13/23 19:01 MFFg/L81 5/12/23SM21-23 6200B400Diisopropyl Ether (DIPE)
4100 200 5/13/23 19:01 MFFg/L88 5/12/23SM21-23 6200B400Ethylbenzene
ND 2000 5/13/23 19:01 MFFg/L480 5/12/23SM21-23 6200B4002-Hexanone (MBK)
210 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B400Isopropylbenzene (Cumene)
ND 200 5/13/23 19:01 MFFg/L51 5/12/23SM21-23 6200B400p-Isopropyltoluene (p-Cymene)
700 200 5/13/23 19:01 MFFg/L68 5/12/23SM21-23 6200B400Methyl tert-Butyl Ether (MTBE)
ND 2000 5/13/23 19:01 MFFg/L71 5/12/23SM21-23 6200B400Methylene Chloride
ND 2000 5/13/23 19:01 MFFg/L530 5/12/23SM21-23 6200B4004-Methyl-2-pentanone (MIBK)
Page 9 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-02
Field Sample #: MW-4
Sample Matrix: Ground Water
Sampled: 5/3/2023 12:49
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
790 200 5/13/23 19:01 MFFg/L150 5/12/23SM21-23 6200B400Naphthalene
520 200 5/13/23 19:01 MFFg/L50 5/12/23SM21-23 6200B400n-Propylbenzene
ND 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B400Styrene
ND 200 5/13/23 19:01 MFFg/L55 5/12/23SM21-23 6200B4001,1,2,2-Tetrachloroethane
ND 200 5/13/23 19:01 MFFg/L67 5/12/23SM21-23 6200B400Tetrachloroethylene
38000 200 5/13/23 19:01 MFFg/L89 5/12/23SM21-23 6200B400Toluene
ND 400 5/13/23 19:01 MFFg/L140 5/12/23SM21-23 6200B4001,2,3-Trichlorobenzene
ND 400 5/13/23 19:01 MFFg/L120 5/12/23SM21-23 6200B4001,2,4-Trichlorobenzene
ND 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B4001,1,1-Trichloroethane
ND 200 5/13/23 19:01 MFFg/L76 5/12/23SM21-23 6200B4001,1,2-Trichloroethane
ND 200 5/13/23 19:01 MFFg/L70 5/12/23SM21-23 6200B400Trichloroethylene
ND 200 5/13/23 19:01 MFFg/L62 5/12/23SM21-23 6200B400Trichlorofluoromethane (Freon 11)
ND 200 5/13/23 19:01 MFFg/L110 5/12/23SM21-23 6200B4001,2,3-Trichloropropane
3900 200 5/13/23 19:01 MFFg/L80 5/12/23SM21-23 6200B4001,2,4-Trimethylbenzene
1000 200 5/13/23 19:01 MFFg/L60 5/12/23SM21-23 6200B4001,3,5-Trimethylbenzene
ND 8000 5/13/23 19:01 MFFg/L670 5/12/23SM21-23 6200B400Vinyl Acetate
ND 200 5/13/23 19:01 MFFg/L95 5/12/23SM21-23 6200B400Vinyl Chloride
15000 400 5/13/23 19:01 MFFg/L200 5/12/23SM21-23 6200B400m+p Xylene
7700 200 5/13/23 19:01 MFFg/L97 5/12/23SM21-23 6200B400o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 107 5/13/23 19:0170-130
Toluene-d8 101 5/13/23 19:0170-130
4-Bromofluorobenzene 94.6 5/13/23 19:0170-130
Page 10 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-03
Field Sample #: MW-14
Sample Matrix: Ground Water
Sampled: 5/3/2023 13:56
[TOC_2]23E0926-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
4300 50000 5/13/23 19:28 MFFg/L2000 5/12/23SM21-23 6200B1000JAcetone
30000 500 5/13/23 19:28 MFFg/L180 5/12/23SM21-23 6200B1000Benzene
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B1000Bromobenzene
ND 500 5/13/23 19:28 MFFg/L280 5/12/23SM21-23 6200B1000Bromochloromethane
ND 500 5/13/23 19:28 MFFg/L160 5/12/23SM21-23 6200B1000Bromodichloromethane
ND 500 5/13/23 19:28 MFFg/L410 5/12/23SM21-23 6200B1000Bromoform
ND 2000 5/13/23 19:28 MFFg/L1300 5/12/23SM21-23 6200B1000Bromomethane
2700 5000 5/13/23 19:28 MFFg/L1700 5/12/23SM21-23 6200B1000J2-Butanone (MEK)
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B1000n-Butylbenzene
ND 500 5/13/23 19:28 MFFg/L130 5/12/23SM21-23 6200B1000sec-Butylbenzene
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B1000tert-Butylbenzene
ND 500 5/13/23 19:28 MFFg/L160 5/12/23SM21-23 6200B1000Carbon Tetrachloride
ND 500 5/13/23 19:28 MFFg/L120 5/12/23SM21-23 6200B1000Chlorobenzene
ND 50000 5/13/23 19:28 MFFg/L20000 5/12/23SM21-23 6200B1000Ethanol
ND 500 5/13/23 19:28 MFFg/L200 5/12/23SM21-23 6200B1000Chlorodibromomethane
ND 500 5/13/23 19:28 MFFg/L340 5/12/23SM21-23 6200B1000Chloroethane
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B1000Chloroform
ND 600 5/13/23 19:28 MFFg/L500 5/12/23SM21-23 6200B1000Chloromethane
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B10002-Chlorotoluene
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B10004-Chlorotoluene
ND 500 5/13/23 19:28 MFFg/L160 5/12/23SM21-23 6200B10001,2-Dibromoethane (EDB)
ND 500 5/13/23 19:28 MFFg/L130 5/12/23SM21-23 6200B10001,2-Dichlorobenzene
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B10001,3-Dichlorobenzene
ND 500 5/13/23 19:28 MFFg/L130 5/12/23SM21-23 6200B10001,4-Dichlorobenzene
ND 500 5/13/23 19:28 MFFg/L160 5/12/23SM21-23 6200B1000Dichlorodifluoromethane (Freon 12)
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B10001,1-Dichloroethane
ND 500 5/13/23 19:28 MFFg/L300 5/12/23SM21-23 6200B10001,2-Dichloroethane
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B10001,1-Dichloroethylene
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B1000cis-1,2-Dichloroethylene
ND 500 5/13/23 19:28 MFFg/L170 5/12/23SM21-23 6200B1000trans-1,2-Dichloroethylene
ND 500 5/13/23 19:28 MFFg/L190 5/12/23SM21-23 6200B10001,2-Dichloropropane
ND 500 5/13/23 19:28 MFFg/L120 5/12/23SM21-23 6200B10001,3-Dichloropropane
ND 500 5/13/23 19:28 MFFg/L350 5/12/23SM21-23 6200B1000L-042,2-Dichloropropane
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B10001,1-Dichloropropene
ND 500 5/13/23 19:28 MFFg/L160 5/12/23SM21-23 6200B1000cis-1,3-Dichloropropene
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B1000trans-1,3-Dichloropropene
890 500 5/13/23 19:28 MFFg/L200 5/12/23SM21-23 6200B1000Diisopropyl Ether (DIPE)
3700 500 5/13/23 19:28 MFFg/L220 5/12/23SM21-23 6200B1000Ethylbenzene
ND 5000 5/13/23 19:28 MFFg/L1200 5/12/23SM21-23 6200B10002-Hexanone (MBK)
190 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B1000JIsopropylbenzene (Cumene)
ND 500 5/13/23 19:28 MFFg/L130 5/12/23SM21-23 6200B1000p-Isopropyltoluene (p-Cymene)
77000 500 5/13/23 19:28 MFFg/L170 5/12/23SM21-23 6200B1000Methyl tert-Butyl Ether (MTBE)
ND 5000 5/13/23 19:28 MFFg/L180 5/12/23SM21-23 6200B1000Methylene Chloride
ND 5000 5/13/23 19:28 MFFg/L1300 5/12/23SM21-23 6200B10004-Methyl-2-pentanone (MIBK)
Page 11 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-03
Field Sample #: MW-14
Sample Matrix: Ground Water
Sampled: 5/3/2023 13:56
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
800 500 5/13/23 19:28 MFFg/L380 5/12/23SM21-23 6200B1000Naphthalene
450 500 5/13/23 19:28 MFFg/L120 5/12/23SM21-23 6200B1000Jn-Propylbenzene
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B1000Styrene
ND 500 5/13/23 19:28 MFFg/L140 5/12/23SM21-23 6200B10001,1,2,2-Tetrachloroethane
ND 500 5/13/23 19:28 MFFg/L170 5/12/23SM21-23 6200B1000Tetrachloroethylene
59000 500 5/13/23 19:28 MFFg/L220 5/12/23SM21-23 6200B1000Toluene
ND 1000 5/13/23 19:28 MFFg/L340 5/12/23SM21-23 6200B10001,2,3-Trichlorobenzene
ND 1000 5/13/23 19:28 MFFg/L300 5/12/23SM21-23 6200B10001,2,4-Trichlorobenzene
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B10001,1,1-Trichloroethane
ND 500 5/13/23 19:28 MFFg/L190 5/12/23SM21-23 6200B10001,1,2-Trichloroethane
ND 500 5/13/23 19:28 MFFg/L170 5/12/23SM21-23 6200B1000Trichloroethylene
ND 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B1000Trichlorofluoromethane (Freon 11)
ND 500 5/13/23 19:28 MFFg/L280 5/12/23SM21-23 6200B10001,2,3-Trichloropropane
2900 500 5/13/23 19:28 MFFg/L200 5/12/23SM21-23 6200B10001,2,4-Trimethylbenzene
650 500 5/13/23 19:28 MFFg/L150 5/12/23SM21-23 6200B10001,3,5-Trimethylbenzene
ND 20000 5/13/23 19:28 MFFg/L1700 5/12/23SM21-23 6200B1000Vinyl Acetate
ND 500 5/13/23 19:28 MFFg/L240 5/12/23SM21-23 6200B1000Vinyl Chloride
12000 1000 5/13/23 19:28 MFFg/L490 5/12/23SM21-23 6200B1000m+p Xylene
6400 500 5/13/23 19:28 MFFg/L240 5/12/23SM21-23 6200B1000o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 79.0 5/13/23 19:2870-130
Toluene-d8 103 5/13/23 19:2870-130
4-Bromofluorobenzene 93.8 5/13/23 19:2870-130
Page 12 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-04
Field Sample #: FB Field Blank
Sample Matrix: Field Blank
Sampled: 5/3/2023 11:52
[TOC_2]23E0926-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
2.6 50 5/13/23 12:21 MFFg/L2.0 5/12/23SM21-23 6200B1JAcetone
ND 0.50 5/13/23 12:21 MFFg/L0.18 5/12/23SM21-23 6200B1Benzene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B1Bromobenzene
ND 0.50 5/13/23 12:21 MFFg/L0.28 5/12/23SM21-23 6200B1Bromochloromethane
ND 0.50 5/13/23 12:21 MFFg/L0.16 5/12/23SM21-23 6200B1Bromodichloromethane
ND 0.50 5/13/23 12:21 MFFg/L0.41 5/12/23SM21-23 6200B1Bromoform
ND 2.0 5/13/23 12:21 MFFg/L1.3 5/12/23SM21-23 6200B1Bromomethane
ND 5.0 5/13/23 12:21 MFFg/L1.7 5/12/23SM21-23 6200B12-Butanone (MEK)
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B1n-Butylbenzene
ND 0.50 5/13/23 12:21 MFFg/L0.13 5/12/23SM21-23 6200B1sec-Butylbenzene
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B1tert-Butylbenzene
ND 0.50 5/13/23 12:21 MFFg/L0.16 5/12/23SM21-23 6200B1Carbon Tetrachloride
ND 0.50 5/13/23 12:21 MFFg/L0.12 5/12/23SM21-23 6200B1Chlorobenzene
ND 50 5/13/23 12:21 MFFg/L20 5/12/23SM21-23 6200B1Ethanol
ND 0.50 5/13/23 12:21 MFFg/L0.20 5/12/23SM21-23 6200B1Chlorodibromomethane
ND 0.50 5/13/23 12:21 MFFg/L0.34 5/12/23SM21-23 6200B1Chloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B1Chloroform
ND 0.60 5/13/23 12:21 MFFg/L0.50 5/12/23SM21-23 6200B1Chloromethane
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B12-Chlorotoluene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B14-Chlorotoluene
ND 0.50 5/13/23 12:21 MFFg/L0.16 5/12/23SM21-23 6200B11,2-Dibromoethane (EDB)
ND 0.50 5/13/23 12:21 MFFg/L0.13 5/12/23SM21-23 6200B11,2-Dichlorobenzene
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B11,3-Dichlorobenzene
ND 0.50 5/13/23 12:21 MFFg/L0.13 5/12/23SM21-23 6200B11,4-Dichlorobenzene
ND 0.50 5/13/23 12:21 MFFg/L0.16 5/12/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12)
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B11,1-Dichloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.30 5/12/23SM21-23 6200B11,2-Dichloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B11,1-Dichloroethylene
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B1cis-1,2-Dichloroethylene
ND 0.50 5/13/23 12:21 MFFg/L0.17 5/12/23SM21-23 6200B1trans-1,2-Dichloroethylene
ND 0.50 5/13/23 12:21 MFFg/L0.19 5/12/23SM21-23 6200B11,2-Dichloropropane
ND 0.50 5/13/23 12:21 MFFg/L0.12 5/12/23SM21-23 6200B11,3-Dichloropropane
ND 0.50 5/13/23 12:21 MFFg/L0.35 5/12/23SM21-23 6200B1L-042,2-Dichloropropane
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B11,1-Dichloropropene
ND 0.50 5/13/23 12:21 MFFg/L0.16 5/12/23SM21-23 6200B1cis-1,3-Dichloropropene
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B1trans-1,3-Dichloropropene
ND 0.50 5/13/23 12:21 MFFg/L0.20 5/12/23SM21-23 6200B1Diisopropyl Ether (DIPE)
ND 0.50 5/13/23 12:21 MFFg/L0.22 5/12/23SM21-23 6200B1Ethylbenzene
ND 5.0 5/13/23 12:21 MFFg/L1.2 5/12/23SM21-23 6200B12-Hexanone (MBK)
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B1Isopropylbenzene (Cumene)
ND 0.50 5/13/23 12:21 MFFg/L0.13 5/12/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene)
ND 0.50 5/13/23 12:21 MFFg/L0.17 5/12/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE)
ND 5.0 5/13/23 12:21 MFFg/L0.18 5/12/23SM21-23 6200B1Methylene Chloride
ND 5.0 5/13/23 12:21 MFFg/L1.3 5/12/23SM21-23 6200B14-Methyl-2-pentanone (MIBK)
Page 13 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 5/5/2023
Work Order: 23E0926Sample Description:Project Location: Ruth, NC
Sample ID: 23E0926-04
Field Sample #: FB Field Blank
Sample Matrix: Field Blank
Sampled: 5/3/2023 11:52
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 5/13/23 12:21 MFFg/L0.38 5/12/23SM21-23 6200B1Naphthalene
ND 0.50 5/13/23 12:21 MFFg/L0.12 5/12/23SM21-23 6200B1n-Propylbenzene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B1Styrene
ND 0.50 5/13/23 12:21 MFFg/L0.14 5/12/23SM21-23 6200B11,1,2,2-Tetrachloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.17 5/12/23SM21-23 6200B1Tetrachloroethylene
ND 0.50 5/13/23 12:21 MFFg/L0.22 5/12/23SM21-23 6200B1Toluene
ND 1.0 5/13/23 12:21 MFFg/L0.34 5/12/23SM21-23 6200B11,2,3-Trichlorobenzene
ND 1.0 5/13/23 12:21 MFFg/L0.30 5/12/23SM21-23 6200B11,2,4-Trichlorobenzene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B11,1,1-Trichloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.19 5/12/23SM21-23 6200B11,1,2-Trichloroethane
ND 0.50 5/13/23 12:21 MFFg/L0.17 5/12/23SM21-23 6200B1Trichloroethylene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B1Trichlorofluoromethane (Freon 11)
ND 0.50 5/13/23 12:21 MFFg/L0.28 5/12/23SM21-23 6200B11,2,3-Trichloropropane
ND 0.50 5/13/23 12:21 MFFg/L0.20 5/12/23SM21-23 6200B11,2,4-Trimethylbenzene
ND 0.50 5/13/23 12:21 MFFg/L0.15 5/12/23SM21-23 6200B11,3,5-Trimethylbenzene
ND 20 5/13/23 12:21 MFFg/L1.7 5/12/23SM21-23 6200B1Vinyl Acetate
ND 0.50 5/13/23 12:21 MFFg/L0.24 5/12/23SM21-23 6200B1Vinyl Chloride
ND 1.0 5/13/23 12:21 MFFg/L0.49 5/12/23SM21-23 6200B1m+p Xylene
ND 0.50 5/13/23 12:21 MFFg/L0.24 5/12/23SM21-23 6200B1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 85.4 5/13/23 12:2170-130
Toluene-d8 99.3 5/13/23 12:2170-130
4-Bromofluorobenzene 94.2 5/13/23 12:2170-130
Page 14 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B-SM21-23 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B340060 05/12/230.0125 5.0023E0926-01 [MW-1]
B340060 05/12/230.0125 5.0023E0926-02 [MW-4]
B340060 05/12/230.005 5.0023E0926-03 [MW-14]
B340060 05/12/235 5.0023E0926-04 [FB Field Blank]
[TOC_1]Sample Preparation Information[TOC]
Page 15 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B340060 - SW-846 5030B
[TOC_3]B340060[TOC]
Blank (B340060-BLK1) Prepared: 05/12/23 Analyzed: 05/13/23
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L0.50ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L0.50ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L0.60ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L0.50ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50 L-04ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L1.0ND
1,2,4-Trichlorobenzene g/L0.50ND
[TOC_1]QC Data[TOC]
Page 16 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B340060 - SW-846 5030B
Blank (B340060-BLK1) Prepared: 05/12/23 Analyzed: 05/13/23
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L0.50ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 92.123.0
g/L 25.0 70-130Surrogate: Toluene-d8 99.424.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 93.123.3
LCS (B340060-BS1) Prepared: 05/12/23 Analyzed: 05/13/23
Acetone g/L50 100 70-13084.484.4
Benzene g/L0.50 10.0 70-13010010.0
Bromobenzene g/L0.50 10.0 70-13010210.2
Bromochloromethane g/L0.50 10.0 70-13097.69.76
Bromodichloromethane g/L0.50 10.0 70-13095.29.52
Bromoform g/L0.50 10.0 70-13082.58.25
Bromomethane g/L2.0 10.0 60-14012012.0
2-Butanone (MEK)g/L5.0 100 70-13093.193.1
n-Butylbenzene g/L0.50 10.0 70-13093.89.38
sec-Butylbenzene g/L0.50 10.0 70-13094.89.48
tert-Butylbenzene g/L0.50 10.0 70-13098.59.85
Carbon Tetrachloride g/L0.50 10.0 70-13087.58.75
Chlorobenzene g/L0.50 10.0 70-13010710.7
Ethanol g/L50 100 70-13079.679.6
Chlorodibromomethane g/L0.50 10.0 70-13094.49.44
Chloroethane g/L0.50 10.0 60-14089.98.99
Chloroform g/L0.50 10.0 70-13091.49.14
Chloromethane g/L0.60 10.0 60-14010910.9
2-Chlorotoluene g/L0.50 10.0 70-13010510.5
4-Chlorotoluene g/L0.50 10.0 70-13010210.2
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010410.4
1,2-Dichlorobenzene g/L0.50 10.0 70-13099.39.93
1,3-Dichlorobenzene g/L0.50 10.0 70-13010010.0
1,4-Dichlorobenzene g/L0.50 10.0 70-13010110.1
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14011011.0
1,1-Dichloroethane g/L0.50 10.0 70-13012012.0
1,2-Dichloroethane g/L0.50 10.0 70-13085.18.51
1,1-Dichloroethylene g/L0.50 10.0 70-13087.08.70
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13089.08.90
trans-1,2-Dichloroethylene g/L0.50 10.0 70-13093.49.34
1,2-Dichloropropane g/L0.50 10.0 70-13010210.2
1,3-Dichloropropane g/L0.50 10.0 70-13010210.2
2,2-Dichloropropane g/L0.50 10.0 L-0470-13062.4 *6.24
1,1-Dichloropropene g/L0.50 10.0 70-13094.99.49
cis-1,3-Dichloropropene g/L0.50 10.0 70-13093.99.39
trans-1,3-Dichloropropene g/L0.50 10.0 70-13092.79.27
Page 17 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B340060 - SW-846 5030B
LCS (B340060-BS1) Prepared: 05/12/23 Analyzed: 05/13/23
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13011411.4
Ethylbenzene g/L0.50 10.0 70-13010610.6
2-Hexanone (MBK)g/L5.0 100 70-13093.293.2
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13010310.3
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13094.59.45
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13094.79.47
Methylene Chloride g/L5.0 10.0 70-13092.59.25
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-13091.691.6
Naphthalene g/L0.50 10.0 70-13090.99.09
n-Propylbenzene g/L0.50 10.0 70-13010310.3
Styrene g/L0.50 10.0 70-13010310.3
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13091.19.11
Tetrachloroethylene g/L0.50 10.0 70-13010710.7
Toluene g/L0.50 10.0 70-13010510.5
1,2,3-Trichlorobenzene g/L1.0 10.0 70-13097.39.73
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13099.79.97
1,1,1-Trichloroethane g/L0.50 10.0 70-13090.19.01
1,1,2-Trichloroethane g/L0.50 10.0 70-13010410.4
Trichloroethylene g/L0.50 10.0 70-13010110.1
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13087.28.72
1,2,3-Trichloropropane g/L0.50 10.0 70-13011311.3
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13096.19.61
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13099.29.92
Vinyl Acetate g/L20 100 70-13090.890.8
Vinyl Chloride g/L0.50 10.0 60-14011311.3
m+p Xylene g/L1.0 20.0 70-13010521.0
o-Xylene g/L0.50 10.0 70-13010310.3
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 86.521.6
g/L 25.0 70-130Surrogate: Toluene-d8 10225.6
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.824.2
LCS Dup (B340060-BSD1) Prepared: 05/12/23 Analyzed: 05/13/23
Acetone g/L50 100 2570-13085.2 0.95685.2
Benzene g/L0.50 10.0 2570-13094.4 6.169.44
Bromobenzene g/L0.50 10.0 2570-13095.6 6.099.56
Bromochloromethane g/L0.50 10.0 2570-13094.0 3.769.40
Bromodichloromethane g/L0.50 10.0 2570-13093.0 2.349.30
Bromoform g/L0.50 10.0 2570-13087.0 5.318.70
Bromomethane g/L2.0 10.0 2560-140114 5.2911.4
2-Butanone (MEK)g/L5.0 100 2570-13091.7 1.5091.7
n-Butylbenzene g/L0.50 10.0 2570-13085.7 9.038.57
sec-Butylbenzene g/L0.50 10.0 2570-13087.6 7.898.76
tert-Butylbenzene g/L0.50 10.0 2570-13090.7 8.259.07
Carbon Tetrachloride g/L0.50 10.0 2570-13083.9 4.208.39
Chlorobenzene g/L0.50 10.0 2570-130100 6.2910.0
Ethanol g/L50 100 2570-13072.2 9.8372.2
Chlorodibromomethane g/L0.50 10.0 2570-13089.6 5.228.96
Chloroethane g/L0.50 10.0 2560-14086.7 3.628.67
Chloroform g/L0.50 10.0 2570-13086.7 5.288.67
Chloromethane g/L0.60 10.0 2560-14098.8 9.919.88
2-Chlorotoluene g/L0.50 10.0 2570-13094.4 11.09.44
4-Chlorotoluene g/L0.50 10.0 2570-13095.2 6.419.52
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Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B340060 - SW-846 5030B
LCS Dup (B340060-BSD1) Prepared: 05/12/23 Analyzed: 05/13/23
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13099.8 3.649.98
1,2-Dichlorobenzene g/L0.50 10.0 2570-13098.2 1.119.82
1,3-Dichlorobenzene g/L0.50 10.0 2570-13095.6 5.009.56
1,4-Dichlorobenzene g/L0.50 10.0 2570-13092.5 8.989.25
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-140101 8.1710.1
1,1-Dichloroethane g/L0.50 10.0 2570-130105 13.110.5
1,2-Dichloroethane g/L0.50 10.0 2570-13080.6 5.438.06
1,1-Dichloroethylene g/L0.50 10.0 2570-13081.3 6.778.13
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13082.2 7.948.22
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13091.7 1.849.17
1,2-Dichloropropane g/L0.50 10.0 2570-130100 1.2910.0
1,3-Dichloropropane g/L0.50 10.0 2570-13098.9 3.189.89
2,2-Dichloropropane g/L0.50 10.0 25 L-0470-13058.1 7.14*5.81
1,1-Dichloropropene g/L0.50 10.0 2570-13087.3 8.348.73
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13088.1 6.378.81
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13083.2 10.88.32
Diisopropyl Ether (DIPE)g/L0.50 10.0 25 L-0770-130131 14.0*13.1
Ethylbenzene g/L0.50 10.0 2570-13099.9 5.649.99
2-Hexanone (MBK)g/L5.0 100 2570-13089.5 3.9689.5
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13094.3 9.219.43
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13088.9 6.118.89
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-130108 13.110.8
Methylene Chloride g/L5.0 10.0 2570-13091.7 0.8699.17
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13091.2 0.42791.2
Naphthalene g/L0.50 10.0 2570-13084.1 7.778.41
n-Propylbenzene g/L0.50 10.0 2570-13095.6 7.269.56
Styrene g/L0.50 10.0 2570-130101 2.1610.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13091.4 0.3299.14
Tetrachloroethylene g/L0.50 10.0 2570-130102 4.8910.2
Toluene g/L0.50 10.0 2570-130101 4.3710.1
1,2,3-Trichlorobenzene g/L1.0 10.0 2570-13090.6 7.139.06
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-13094.1 5.789.41
1,1,1-Trichloroethane g/L0.50 10.0 2570-13086.3 4.318.63
1,1,2-Trichloroethane g/L0.50 10.0 2570-13096.9 6.789.69
Trichloroethylene g/L0.50 10.0 2570-130100 0.099510.0
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13083.9 3.868.39
1,2,3-Trichloropropane g/L0.50 10.0 2570-130109 3.5210.9
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13089.6 7.008.96
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13092.6 6.889.26
Vinyl Acetate g/L20 100 2570-13096.9 6.5096.9
Vinyl Chloride g/L0.50 10.0 2560-14098.6 13.79.86
m+p Xylene g/L1.0 20.0 2570-13096.0 8.9519.2
o-Xylene g/L0.50 10.0 2570-13095.9 7.149.59
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 86.221.5
g/L 25.0 70-130Surrogate: Toluene-d8 10025.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 96.524.1
Page 19 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
FLAG/QUALIFIER SUMMARY
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Elevated reporting limit due to high concentration of target compounds.RL-11
[TOC_1]Flag/Qualifier Summary[TOC]
Page 20 of 25
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-23 6200B in Water
NCAcetone
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCCarbon Tetrachloride
NCChlorobenzene
NCEthanol
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromoethane (EDB)
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiisopropyl Ether (DIPE)
NCEthylbenzene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
[TOC_1]Certifications[TOC]
Page 21 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-23 6200B in Water
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Acetate
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
The CON-TEST Environmental Laboratory operates under the following certifications and accreditations:
Code Description Number Expires
652North Carolina Div. of Water QualityNC 12/31/2023
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