MO-7343_36000_CA_MRP_20080520

Force Environmental Service Company, LLC
147 Vera Road Suite F, Lexington, South Carolina 29072 [phone] [phone].fax
May 20, 2008
Scott Ryals
Division of Waste Management
NCDENR
1637 Mail Service Center
Raleigh, NC 27699-1637
Re: Loves Grocery; NCDENR Incident #36000; Stanly County
20704 NC Hwy 24/27, Oakboro, North Carolina
Dear Mr. Ryals:
Force Environmental Service Company, LLC is pleased to submit the results of the
monitoring well and wat~fupply well (WSW) sampling event performed at the referenced
facility. On April 29, 20~yuonitoring wells MW-I (FP) and MW-I through MW-4 and water
supply well WSW-2 was sampled. Monitoring well MW-1 (FP) is located on the Frog Pond
service station property located northwest of the site. Water supply well WSW-1, located onsite,
was not sampled since it was dry. Water supply well WSW-3 was not sampled because the new
homeowner, Scott Heller, said his well is no longer in service, and municipal water has been
connected at the well head. Water supply well WSW-4 is also no longer in service and
municipal water has been connected at the well head, therefore, a sample was not collected.
The groundwater samples from the monitoring wells were collected with a disposable
bailer after at least three well volumes of groundwater were removed. The groundwater sample
from the water supply well was collected after the well was purged for approximately IO-minutes
from the closet spigot. The sample was collected from the same spigot after reducing the water
flow. The monitoring well and WSW information are presented in Tables 1 and 2, respectively.
a C : om ormg e an T bl 1 M 't . W ll d G roun wa er aa d t D t
Monitoring Screened Screen TOC Depth to Depth to GW
Interval Depth Elevation Water Product Elevation Well Number (feet) (feet bgs) (feet)* (ft btoc) (feet) (feet)
MW-1 (FP) 15 2 to 15 101.28 3.94 NA 97.34
MW-1 (loves) 20 10 to 20 100.00 5.53 NA 94.47
MW-2 20 10 to 20 100.22 11.20 NA 89.02
MW-3 15 5 to 15 98.76 2.94 NA 95.82
MW-4 15 5 to 15 100.49 3.32 NA 97.17
Loves Grocery 1 Force Environmental
a e : a er T bl 2 W t S upply e aa I WUDt
Figure 2 Water Well Owner/ Mailing Physical Well Supply Tax PIN# Comments designation Wells User Address Address Status/Use
20704 NC Hwy Site. inactive. 6" we!I. Static water
Donald Inactive level = 26.2'. Rock well. TD= 35'. Site WSW-1 Chapman 24/27 Same WSW 650502765933 No pump in well, sampled with a Oakboro, NC bailer.
17070 Frog Irrigation TD= 75-80'. Active. On county 1 -WSW-2 D.E. Murray Pond Road Same 650502766891
Oakboro, NC WSW water
17051 Frog Out-of-Public water connected at well 2 WSW-3 Scott Heller Pond Road Same service 650502765457 head Oakboro, NC
17042-A Frog Irrigation WSW--4 Marvin Smith Pond Road Same 650502768427 Inactive. Installed in 1961.
Oakboro, NC WSW
3 17042-B Frog
WSW-5 Marvin Smith Pond Road Same Irrigation 650502768427 Active. Installed in 1970.
Oakboro, NC WSW
Vance 17039 Frog Irrigation 4 WSW-6 Whitley Pond Road Same WSW 650502766360 Active. On county water.
Oakboro, NC
Grover and 17035 Frog Irrigation 5 WSW-7 Estelle Pond Road Same WSW 650502767072 Active. On county water.
Barbee Oakboro, NC
Kevin J. 20604A & B NC Active 6 WSW-8 Brickman Hwy 24/27 Same WSW 650502665411 Supplies water to two residences.
Oakboro, NC
7 WSW-9 Moir Lin PO Box262 Unknown Irrigation 650502677025 Active. On county water. Jones Oakboro, NC (see map) WSW
Douglas 17142 Frog Irrigation 8 WSW-10 Lorch Pond Road Same WSW 650502771522 Active. On county water.
Oakboro, NC
Judson 17151 Frog Out-of-Public water connected at well 9 WSW-11 Barbie Pond Road Same service 650502678469 head Oakboro, NC
Glenn and 17193-A Frog Active 10 WSW-12 Alice Hinson Pond Road Sarne WSW 650502675875 Well depth approximately 100'
Oakboro, NC -~--------------~-----~----
17202 Frog Irrigation 11 WSW-13 Floyd Hinson Pond Road Same WSW 650502687244 Active. On county water.
Oakboro, NC
Jerry Tucker -
owner 22831A, B, and Chris Clontz, Irrigation 12 WSW-14 Al Ross, and C Lorch Road Same WSW 650502784005 Inactive. On county water.
Dustin Furr -Oakboro, NC
renters
Jerome 18848 Graham Active 13 WSW-15 Whitley Road Same WSW 650502778827 Does not want water tested.
Oakboro, NC
18842 Graham Irrigation 14 WSW-16 Jimmy Burris Road Same 650502779703 Inactive. On county water.
Oakboro, NC WSW
20755 NC Hwy Irrigation WSW-17 M.A. Barbee 24/27 Same WSW 650502871532 Inactive. On county water.
15 Oakboro, NC
20755 NC Hwy Irrigation WSW-18 M.A. Barbee 24/27 Same WSW 650502871532 Active. On county water.
Oakboro, NC
Loves Grocery 2 Force Environmental
Figure 2 Water Well Owner/ Mailing Physical Well Supply Tax PIN# Comments designation Wells User Address Address Status/Use
Curtis H 20756 NC Hwy Irrigation 16 WSW-19 Smith 24/27 Same WSW 650502872137 Inactive. On county water.
Oakboro, NC
Inactive. On county water. 4" well.
John D. 20720A NC Hwy Irrigation Jet pump installed on top of
WSW-20 Whitley 24/27 Same WSW 650502870010 wellhead. No access & no power.
Oakboro, NC Located in brown bldg behind white
17 house.
Inactive. Located on hill in brown
John D. 20720A NC Hwy Irrigation bldg. On county water. Installed
WSW-21 Whitley 24/27 Same WSW 650502870010 1973 to 205' TD. Casing set at 21'.
Oakboro, NC Static water 22' bgs. 6" well. No
access, well seal rusted shut.
Not Not Not Pond/Stream system located
18 N/A Applicable Not Applicable Applicable Applicable Not Applicable approximately 400 feet west of the
site
Not Not Not Pond/Stream system located
19 N/A Applicable Not Applicable Applicable Applicable Not Applicable approximately 1300 feet east of the
site
Not Not Not Pond/Stream system located
20 N/A Applicable Not Applicable Applicable Applicable Not Applicable approximately 1100 feet northwest
of the site
The samples from the monitoring wells and water supply wells were placed in appropriately
labeled, laboratory supplied, 40-ml glass containers containing a hydrochloric acid preservative,
stored on wet ice, and shipped with the attached chain of custody to a North Carolina certified
laboratory for analysis by Standard Method 6230D. A new pair of disposable nitrile gloves was
worn during the collection of each sample. The analytical results are presented in Table 3.
a e : na1y11ca esu s T bl 3 A I f l R It
Coe (µg/1) NC 2l MW-1 (FP) MW-1 (loves)
Standards 1/8/07 3/22/07 9/17/07 4/29/08 1/8/07 3/22/07 9/17/07 4/29/08
Benzene 1.0 ND ND ND <0.5 76 690 89 51.3
Bromodichloromethane 0.56 ND ND ND <0.5 3.6 ND ND <10.0
n-Butylbenzene 70 ND ND ND <0.5 1.7 :ND ND <10.0
sec-Butyl benzene 70 ND ND ND <0.5 ND ND ND <10.0
Chloroform 0.19 <0.5 <0.5 <0.5 <0.5 18 <0.5 <0.5 <10.0
1,2-Dichloroethane 0.38 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <10.0
Dibromochloromethane NA ND ND ND <0.5 0.38J ND ND <10.0
Diisopropyl ether 70 1.8 1.3 1.0 1.2 7.5 350 398 343
Ethyl benzene 29 ND ND ND <0.5 36 7.3 ND <10.0
lsopropylbenzene 70 ND ND ND <0.5 2.6 0.89 ND <10.0
p-lsopropy ltol uene NA ND ND ND <0.5 ND ND ND <10.0
MTBE 200 5.0 3.6 3.1 2.6 26 2100 2080 2200
Naphthalene 21 ND ND ND <2.0 6.8 5.1 ND <40.0
n-Propylbenzene 70 ND ND ND <0.5 8.6 ND ND <10.0
Tetrachloroethene 0.70 0.47J ND ND <0.5 ND ND ND <10.0
Toluene 1000 ND ND ND <0.5 53 24 ND <10.0
1,2,4-Trimethylbenzene 350 ND ND ND <0.5 51 53 ND <10.0
1,3,5-Trimethylbenzene 350 ND ND ND <0.5 13 32 ND <10.0
Total Xylenes 530 ND ND ND ND 127 257 ND ND
Loves Grocery 3 Force Environmental
coc (µg/1) NC2L MW-2 MW-3
Standards 1/8/07 3/22/07 9/17/07 4/29/08 3/27/07 9/17/07 4/29/08
Benzene 1.0 3.2 ND ND <0.5 3.4 ND 14.4
Bromodichloromethane 0.56 ND ND ND <0.5 1.1 ND <0.5
n-Butylbenzene 70 ND ND ND <0.5 ND ND <0.5
sec-Butyl benzene 70 ND ND ND <0.5 ND ND <0.5
Chloroform 0.19 <0.5 <0.5 <0.5 <0.5 9.0 <0.5 <0.5
1,2-Dichloroethane 0.38 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Dibromochloromethane NA ND ND ND <0.5 ND ND <0.5
Diisopropyl ether 70 20 35 31.4 25.4 28 72.6 116
Ethylbenzene 29 1.5 ND ND <0.5 8.2 ND 2.1
lsopropylbenzene 70 ND ND ND <0.5 0.84 ND <0.5
p-lsopropyltoluene NA ND ND ND <0.5 ND ND <0.5
MTBE 200 25 40 32.2 29.0 12 26 43.6
Naphthalene 21 1.3J ND ND <2.0 2.3 ND 2.8
n-Propylbenzene 70 ND ND ND <0.5 9.9 ND 0.69
Tetrachloroethene 0.70 ND ND ND <0.5 ND ND <0.5
Toluene 1000 11 ND ND <0.5 0.32J ND <0.5
1,2,4-Trimethylbenzene 350 1.8 ND ND <0.5 7.2 ND 0.78
1,3,5-Trimethylbenzene 350 0.51 ND ND <0.5 ND ND <0.5
Total Xylenes 530 6.1 ND ND ND 2.5 ND 1.5
Coe (µg/1) NC2L MW-4
Standards 3/27/07 9/17/07 4/29/08
Benzene 1.0 ND ND <0.5
Bromodichloromethane 0.56 ND ND <0.5
n-Butylbenzene 70 ND ND <0.5
sec-Butyl benzene 70 ND ND <0.5
Chloroform 0.19 <0.5 <0.5 <0.5
1,2-Dichloroethane 0.38 <0.5 <0.5 <0.5
Dibromochloromethane NA ND ND <0.5
Diisopropyl ether 70 ND ND <0.5
Ethylbenzene 29 ND ND <0.5
lsopropylbenzene 70 ND ND <0.5
p-lsopropyltoluene NA ND ND <0.5
MTBE 200 ND ND <0.5
Naphthalene 21 0.35J ND <2.0
n-Propylbenzene 70 ND ND <0.5
Tetrach loroethene 0.70 ND ND <0.5
Toluene 1000 ND ND <0.5
1,2,4-Trimethylbenzene 350 ND ND <0.5
1,3,5-Trimethylbenzene 350 ND ND <0.5
Total Xylenes 530 ND ND ND
Loves Grocery 4 Force Environmental
NC2L WSW-1 WSW-2
Coe (µg/1) Standards 1/8/07 3/22/07 9/17/07 4/29/08 3/22/07 9/17/07 4/29/08
Benzene 1.0 ND ND NS NS ND ND <0.5
Bromodichloromethane 0.56 ND ND NS NS ND ND <0.5
Bromoform 0.19 ND ND NS NS ND ND <0.5
n-Butylbenzene 70 ND ND NS NS ND ND <0.5
sec-Butyl benzene 70 ND ND NS NS ND ND <0.5
Chloroform 0.19 <0.5 <0.5 NS NS <0.5 <0.5 <0.5
Di bromoch loromethane NA ND ND NS NS ND ND <0.5
1, 1-Dichloroethane 70 ND ND NS NS ND 1.3 <0.5
1,2-Dichloroethane 0.38 <0.5 <0.5 NS NS 0.55 0.79 <0.5
Diisopropyl ether NA ND ND NS NS 1.6 0.81 1.4
Ethyl benzene 29 ND ND NS NS ND ND <0.5
lsopropylbenzene 70 ND ND NS NS ND ND <0.5
p-lsopropyltoluene NA ND ND NS NS ND ND <0.5
MTBE 200 ND ND NS NS 4.1 2.4 4.6
n-Propylbenzene 70 ND ND NS NS ND ND <0.5
Naphthalene 21 ND ND NS NS ND ND <2.0
Toluene 1000 ND ND NS NS ND ND <0.5
1,2,4-Trimethylbenzene 350 ND ND NS NS ND ND <0.5
1,3,5-Trimethylbenzene 350 ND ND NS NS ND ND <0.5
Total Xylenes 530 ND ND NS NS ND ND ND
Loves Grocery 5 Force Environmental
Coe (µg/I) NC 2L WSW-3 WSW-11
Standards 3/22/07 9/17/07 4/29/08 1/8/07 3/22/07 9/17/07 4/29/08
Benzene 1.0 ND ND NS ND ND ND NS
Bromodichloromethane 0.56 5.9 14.4 NS 6.8 5.0 16 NS
Bromoform 0.19 ND ND NS 2.0 ND ND NS
n-Butylbenzene 70 ND ND NS ND ND ND NS
sec-Butylbenzene 70 ND ND NS ND ND ND NS
Chloroform 0.19 68 80.4 NS <0.5 55 72.6 NS
Dibromochloromethane NA 0.47J 2.7 NS 0.97 0.33J 3.1 NS
1, 1-Dichloroethane 70 ND ND NS ND ND ND NS
1,2-Dichloroethane 0.38 <0.5 <0.5 NS <0.5 <0.5 <0.5 NS
Diisopropyl ether NA ND ND NS ND ND ND NS
Ethylbenzene 29 ND ND NS ND ND ND NS
lsopropylbenzene 70 ND ND NS ND ND ND NS
p-lsopropyltoluene NA ND ND NS ND ND ND NS
MTBE 200 ND ND NS ND ND ND NS
n-Propylbenzene 70 ND ND NS ND ND ND NS
Naphthalene 21 ND ND NS ND ND ND NS
Toluene 1000 ND ND NS ND ND ND NS
1,2,4-Trimethylbenzene 350 ND ND NS ND ND ND NS
1,3,5-Trimethylbenzene 350 ND ND NS ND ND ND NS
Total Xylenes 530 ND ND NS ND ND ND NS
All data are provided in µg/1 (parts per billion). ND = Not detectable above the respective reporting limit
NA = Not available J = Estimated concentration
Bold print indicates that the NC 2L Standards were met or exceeded
The samples collected from monitoring well MW-1 (Loves) was mislabeled as MW-2. The samples
collected from monitoring well MW-2 were mislabeled as MW-1 (Loves).
The CoC detected in the analytical results above their respective NC2L Standard include:
benzene and diisopropyl ether in monitoring wells MW-1 (Loves) and MW-3; and MTBE in
monitoring well MW-1 (Loves)
The CoC detected at a concentration less than their respective NC 2L Standard include:
diisopropyl ether in monitoring wells MW-1 (FP) and MW-2 and water supply well WSW-2;
MTBE in monitoring wells MW-1 (FP), MW-2, and MW-3 and water supply well WSW-2;
ethylbenzene, naphthalene, n-propylbenzene, 1,2,4,-trimethylbenzene, and total xylenes in
monitoring well MW-3
Thank you for your assistance with this project. The site map, WSW location map,
analytical results, and field data sheets are attached for your review. If you have any questions
or require additional information, please do not hesitate to contact me toll free at 877-700-9012.
Sincerely,
Loves Grocery
Incident #36000
ENTAL SERVICE COMPANY, LLC
6 Force Environmental
Service Company, LLC
ATTACHMENT A
MAPS
) tv LEGEND FROG PONO SERVICE ST A TION ~;:;~.(FP)~ ,J'l MONITORING WELL LOCA llONS 95.31 WAllER TABLE ELEVATION FORMER SERVlCE STATION (MW ON-SITE) PLAN1ED FARM FIELD -(\ ~ Cl VACANT FIELD APPROXIMATE NCDOT EASEMENT NC HWY 24/27 HIGHWAY CONS1RUC110N \ APPROXIMATE PROPERTY LINE ~ E--=-== E:C:C=---~-=-~ )~ \\ \ 1'" \ I I FORMER DISPENSER lSLAND GRAVEL ASPHALT MW-3 '1'J 95.82' CONCRETE" 0 \ ON-SITE WSW (out of service) \,,,, ASPHALT ~ / ~ AREA OF GRAVEL \ (t) EXCAVATION \. \ ,\ TREE --------AREA OF \ SIDEWALL COLLAPSE \ 0:;"' \ ~;~; I. R'::S!OENTIAL / DONALD CHAPMAN PROPERTY (LOVE'S GROCERY) GRASS ~ / / ~ RESIDENTIAL ~ FORCE ENVIRONMENTAL SERVICE CO., LLC 147 VERA RD, SUITE F LEXINGTON SC 29072 (8032 359-3200 \ \TREE I \ J \ ·~ I '1' l '"· j AREA OF FORMER POND (FROG PONO) SITE MAP LOVES GROCERY 20704 NC HWY 24/27 OAKBORO, NC GRAPHIC SCALE 20 40 ~ 1 inch = 40± ft. SITE MAP
REFERENCE: Base plan for this drawing was taken from Staniy County, NC GIS Department
FORCE ENVIRONMENTAL
SERVICE COMPANY, LLC.
147 Vera Road, Suite F
Lexington, SC 29072
WSW LOCATION MAP LOVES GROCERY
20704 NC HWY 24/27
OAKBORO, NORTH CAROLINA
1--------------1 NCDENR INCIDENT# 36000
SCALE AS SHOWN
ATTACHMENT B
ANALYTICAL RESULTS
aAnatytica(
I . .,_,.,.,.,-
Pace Analytical Services, Inc.
2225 Riverside Dr.
! www.pacelabs.com Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] /
May 07, 2008
Mr. Greg Force
Force & Associates
147 Vera Road
Lexington, SC 29072
RE: Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Dear Mr. Force:
Enclosed are the analytical results for sample(s) received by the laboratory on April 30, 2008. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
~f< h~~ ~P JJ--c:s
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
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Page 1 of 22
Pace Analytical Services, Inc.
2225 Riverside Dr. ae Ar,afyticai'
I www.pacelabs.com
! I
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Charlotte Certification IDs
Florida/NELAP Certification Number: E87627
Kansas Certification Number: E-10364
Louisiana/LELAP Certification Number: 04034
North Carolina Drinking Water Certification Number: 37706
North Carolina Wastewater Certification Number: 12
Asheville Certification IDs
Florida/NELAP Certification Number: E87648
Louisiana/LELAP Certification Number: 03095
New Jersey Certification Number: NC011
North Carolina Drinking Water Certification Number: 37712
North Carolina Wastewater Certification Number: 40
North Carolina t1Ioa,;!,av Certification Number: 9
Eden Certification IDs
North Carolina Drinking Water Certification Number: 37738
Virginia Drinking Water Certification Number: 00424
CERTIFICATIONS
North Carolina Field Services Certification Number: 5342
South Carolina Certification Number: 990060001
South Carolina Bioassay Certification Number: 990060003
Tennessee Certification Number: 04010
Virginia Certification Number: 00213
Pennsylvania Certification Number: 68-03578
South Carolina Certification Number: 99030001
South Carolina Bioassay Certification Number: 99030002
Tennessee Certification Number: 2980
Virginia Certification Number: 00072
North Carolina Wastewater Certification Number: 633
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~t{~~~ ?JJelaQ';
Page 2 of 22
• ® eAnat11cal
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w.,w.pace/abs.com
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Lab ID Sample ID
9218385001 MW-2
9218385002 MW-1
9218385003 MW-3
9218385004 MW-4
9218385005 MW-1 FD
9218385006 WSW-2
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
SM 6210
SM 6210
SM 6210
SM 6210
SM 6210
SM 6210
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analysts
MCK
MCK
MCK
MCK
MCK
MCK
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Reported Laboratory
65 PASI-C
65 PASI-C
65 PASI-C
65 PASI-C
65 PASI-C
65 PASI-C
Page 3 of 22
I ' 1® a LI n!I 11':J vr111u~1ivu,
; www.pawlabs.com
I
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-2 LablD: 9218385001 Collected: 04/29/08 18:45 Received: 04/30/08 17:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6210 MSV Analytical Method: SM 6210
Benzene ND ug/L 0.50 05/02/08 18:06 71-43-2
Bromobenzene ND ug/L 0.50 05/02/08 18:06 108-86-1
Bromochloromethane ND ug/L 0.50 05/02/08 18:06 74-97-5
Bromodichloromethane ND ug/L 0.50 05/02/08 18:06 75-27-4
Bromoform ND ug/L 0.50 05/02/08 18:06 75-25-2
Bromomethane ND ug/L 1.0 05/02/08 18:06 74-83-9
n-Butylbenzene ND ug/L 0.50 05/02/08 18:06 104-51-8
sec-Butylbenzene ND ug/L 0.50 05/02/08 18:06 135-98-8
tert-Butylbenzene ND ug/L 0.50 05/02/08 18:06 98-06-6
Carbon tetrachloride ND ug/L 0.50 05/02/08 18:06 56-23-5
Chlorobenzene ND ug/L 0.50 05/02/08 18:06 108-90-7
Chloroethane ND ug/L 1.0 05/02/08 18:06 75-00-3
Chloroform ND ug/L 0.50 05/02/08 18:06 67-66-3
Chloromethane ND ug/L 1.0 05/02/08 18:06 74-87-3
2-Chlorotoluene ND ug/L 0.50 05/02/08 18:06 95-49-8
4-Chlorotoluene ND ug/L 0.50 05/02/08 18:06 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 05/02/08 18:06 96-12-8
Dibromochloromethane ND ug/L 0.50 05/02/08 18:06 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 0.50 05/02/08 18:06 106-93-4
Dibromomethane ND ug/L 0.50 05/02/08 18:06 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 05/02/08 18:06 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 05/02/08 18:06 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 05/02/08 18:06 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 05/02/08 18:06 75-71-8
1, 1-Dichloroethane ND ug/L 0.50 05/02/08 18:06 75-34-3
1,2-Dichloroethane ND ug/L 0.50 05/02/08 18:06 107-06-2
1, 1-Dichloroethene ND ug/L 0.50 05/02/08 18:06 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:06 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:06 156-60-5
1,2-Dichloropropane ND ug/L 0.50 05/02/08 18:06 78-87-5
1,3-Dichloropropane ND ug/L 0.50 05/02/08 18:06 142-28-9
2 ,2-Dichloropropane ND ug/L 0.50 05/02/08 18:06 594-20-7
1, 1-Dichloropropene ND ug/L 0.50 05/02/08 18:06 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:06 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:06 10061-02-6
Diisopropyl ether 25.4 ug/L 0.50 05/02/08 18:06 108-20-3
Ethylbenzene ND ug/L 0.50 05/02/08 18:06 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 05/02/08 18:06 87-68-3
lsopropylbenzene (Cumene) ND ug/L 0.50 05/02/08 18:06 98-82-8
p-lsopropyltoluene ND ug/L 0.50 05/02/08 18:06 99-87-6
Methylene Chloride ND ug/L 2.0 05/02/08 18:06 75-09-2
Methyl-tert-butyl ether 29.0 ug/L 0.50 05/02/08 18:06 1634-04-4
Naphthalene ND ug/L 2.0 05/02/08 18:06 91-20-3
n-Propylbenzene ND ug/L 0.50 05/02/08 18:06 103-65-1
Styrene ND ug/L 0.50 05/02/08 18:06 100-42-5
1, 1, 1,2-Tetrachloroelhane ND ug/L 0.50 05/02/08 18:06 630-20-6
1,1,2,2-·1e1rachloroethane ND ug/L 0.50 05/02/08 18:06 79-34-5
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS Page 4 of 22
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without the written consent of Pace Analytical Services, Inc ..
ffi~~"-. §; o~
~eAna/ytical • ; .. / , www.pacelebs.com I ! !
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 1 oo
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-2
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S}
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
LablD: 9218385001 Collected: 04/29/08 18:45 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: SM 6210
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
106 % 60-140
98 % 60-140
105 % 60-140
100 % 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analy1ical Services, Inc .. -"_~x·-~~~~~ .~.n~R'ZII"\".
Analyzed GAS No.
05/02/08 18:06 127-18-4
05/02/08 18:06 108-88-3
05/02/08 18:06 87-61-6
05/02/08 18:06 120-82-1
05/02/08 18:06 71-55-6
05/02/08 18:06 79-00-5
05/02/08 18:06 79-01-6
05/02/08 18:06 75-69-4
05/02/08 18:06 96-18-4
05/02/08 18:06 95-63-6
05/02/08 18:06 108-67-8
05/02/08 18:06 75-01-4
05/02/08 18:06 1330-20-7
05/02/08 18:06 95-47-6
05/02/08 18:06 17060-07-0
05/02/08 18:06 1868-53-7
05/02/08 18: 06 460-00-4
05/02/08 18:06 2037-26-5
Qual
Page 5 of 22
aAnalytica(
/ <raw.paoolabs.com
i
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-1 LablD: 9218385002 Collected: 04/29/08 18:50 Received: 04/30/08 17:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
6210 MSV Analytical Method: SM 6210
Benzene 51.3 ug/L 10.0 20 05/02/08 14:48 71-43-2
Bromobenzene ND ug/L 10.0 20 05/02/08 14:48 108-86-1
Bromochloromethane ND ug/L 10.0 20 05/02/08 14:48 74-97-5
Bromodichloromethane ND ug/L 10.0 20 05/02/08 14:48 75-27-4
Bromoform ND ug/L 10.0 20 05/02/08 14:48 75-25-2
Bromomethane ND ug/L 20.0 20 05/02/08 14:48 74-83-9
n-Butylbenzene ND ug/L 10.0 20 05/02/08 14:48 104-51-8
sec-Butylbenzene ND ug/L 10.0 20 05/02/08 14:48 135-98-8
tert-Butylbenzene ND ug/L 10.0 20 05/02/08 14:48 98-06-6
Carbon tetrachloride ND ug/L 10.0 20 05/02/08 14:48 56-23-5
Chlorobenzene ND ug/L 10.0 20 05/02/08 14:48 108-90-7
Chloroethane ND ug/L 20.0 20 05/02/08 14:48 75-00-3
Chloroform ND ug/L 10.0 20 05/02/08 14:48 67-66-3
Chloromethane ND ug/L 20.0 20 05/02/08 14:48 74-87-3
2-Chlorotoluene ND ug/L 10.0 20 05/02/08 14:48 95-49-8
4-Chlorotoluene ND ug/L 10.0 20 05/02/08 14:48 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 20.0 20 05/02/08 14:48 96-12-8
Dibromochloromethane ND ug/L 10.0 20 05/02/08 14:48 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 10.0 20 05/02/08 14:48 106-93-4
Dibromomethane ND ug/L 10.0 20 05/02/08 14 :48 74-95-3
1,2-Dichlorobenzene ND ug/L 10.0 20 05/02/08 14:48 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 20 05/02/08 14:48 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 20 05/02/08 14:48 106-46-7
Dichlorodifluoromethane ND ug/L 10.0 20 05/02/08 14:48 75-71-8
1, 1-Dichloroethane ND ug/L 10.0 20 05/02/08 14:48 75-34-3
1,2-Dichloroethane ND ug/L 10.0 20 05/02/08 14:48 107-06-2
1, 1-Dichloroethene ND ug/L 10.0 20 05/02/08 14:48 75-35-4
cis-1,2-Dichloroethene ND ug/L 10.0 20 05/02/08 14 :48 156-59-2
trans-1,2-Dichloroethene ND ug/L 10.0 20 05/02/08 14:48 156-60-5
1,2-Dichloropropane ND ug/L 10.0 20 05/02/08 14:48 78-87-5
1,3-Dich!oropropane ND ug/L 10.0 20 05/02/08 14 :48 142-28-9
2,2-Dichloropropane ND ug/L 10.0 20 05/02/08 14:48 594-20-7
1, 1-Dichloropropene ND ug/L . 10.0 20 05/02/08 14:48 563-58-6
cis-1,3-Dichloropropene ND ug/L 10.0 20 05/02/08 14:48 10061-01-5
trans-1,3-Dichloropropene ND ug/L 10.0 20 05/02/08 14:48 10061-02-6
Diisopropyl ether 343 ug/L 10.0 20 05/02/08 14:48 108-20-3
Ethylbenzene ND ug/L 10.0 20 05/02/08 14 :48 100-41-4
Hexachloro-1,3-butadiene ND ug/L 40.0 20 05/02/08 14:48 87-68-3
lsopropylbenzene (Cumene) ND ug/L 10.0 20 05/02/08 14:48 98-82-8
p-lsopropyltoluene ND ug/L 10.0 20 05/02/08 14:48 99-87-6
Methylene Chloride ND ug/L 40.0 20 05/02/08 14:48 75-09-2
Methyl-tert-butyl ether 2200 ug/L 10.0 20 05/02/08 14:48 1634-04-4
Naphthalene ND ug/L 40.0 20 05/02/08 14:48 91-20-3
n-Propylbenzene ND ug/L 10.0 20 05/02/08 14:48 103-65-1
Styrene ND ug/L 10.0 20 05/02/08 14:48 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/L 10.0 20 05/02/08 14:48 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 10.0 20 05/02/08 14:48 79-34-5
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS Page 6 of 22
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc ..
~" ," -§/ ~\
aAnalyticat'
/ www.pacel8bs.com
{
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-1
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3, 5-T rimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
Lab ID: 9218385002 Collected: 04/29/08 18:50 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit OF Prepared
Analytical Method: SM 6210
ND ug/L 10.0 20
ND ug/L 10.0 20
ND ug/L 40.0 20
ND ug/L 40.0 20
ND ug/L 10.0 20
ND ug/L 10.0 20
ND ug/L 10.0 20
ND ug/L 20.0 20
ND ug/L 10.0 20
ND ug/L 10.0 20
ND ug/L 10.0 20
ND ug/L 20.0 20
ND ug/L 20.0 20
ND ug/L 10.0 20
107 % 60-140 20
99 % 60-140 20
104 % 60-140 20
98 % 60-140 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~o ~~~n,:,..,
' -i 1
Analyzed GAS No.
05/02/08 14:48 127-18-4
05/02/08 14:48 108-88-3
05/02/08 14:48 87-61-6
05/02/08 14:48 120-82-1
05/02/08 14:48 71-55-6
05/02/08 14:48 79-00-5
05/02/08 14:48 79-01-6
05/02/08 14:48 75-69-4
05/02/08 14:48 96-18-4
05/02/08 14:48 95-63-6
05/02/08 14:48 108-67-8
05/02/08 14:48 75-01-4
05/02/08 14:48 1330-20-7
05/02/08 14:48 95-47-6
05/02/08 14:48 17060-07-0
05/02/08 14:48 1868-53-7
05/02/08 14:48 460-00-4
05/02/08 14:48 2037-26-5
Qual
Page 7 of 22
"7 . ® I ~P5ce Anal111cal / __,, ')'L•
1 www.pacelabs.com i l
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey /:we. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-3 LablD: 9218385003 Collected: 04/29/08 18:30 Received: 04/30/08 17:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
6210 MSV Analytical Method: SM 6210
Benzene 14.4 ug/L 0.50 05/02/08 18:29 71-43-2
Bromobenzene ND ug/L 0.50 05/02/08 18:29 108-86-1
Bromochloromethane ND ug/L 0.50 05/02/08 18:29 74-97-5
Bromodichloromethane ND ug/L 0.50 05/02/08 18:29 75-27-4
Bromoform ND ug/L 0.50 05/02/08 18:29 75-25-2
Bromomethane ND ug/L 1.0 05/02/08 18:29 74-83-9
n-Butylbenzene ND ug/L 0.50 05/02/08 18:29 104-51-8
sec-Butyl benzene ND ug/L 0.50 05/02/08 18:29 135-98-8
tert-Butylbenzene ND ug/L 0.50 05/02/08 18:29 98-06-6
Carbon tetrachloride ND ug/L 0.50 05/02/08 18:29 56-23-5
Chlorobenzene ND ug/L 0.50 05/02/08 18:29 108-90-7
Chloroethane ND ug/L 1.0 05/02/08 18:29 75-00-3
Chloroform ND ug/L 0.50 05/02/08 18:29 67-66-3
Chloromethane ND ug/L 1.0 05/02/08 18:29 74-87-3
2-Chlorotoluene ND ug/L 0.50 05/02/08 18:29 95-49-8
4-Chlorotoluene ND ug/L 0.50 05/02/08 18:29 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 05/02/08 18:29 96-12-8
Dibromochloromethane ND ug/L 0.50 05/02/08 18:29 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 0.50 05/02/08 18:29 106-93-4
Dibromomethane ND ug/L 0.50 05/02/08 18:29 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 05/02/08 18:29 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 05/02/08 18:29 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 05/02/08 18:29 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 05/02/08 18:29 75-71-8
1, 1-Dichloroethane ND ug/L 0.50 05/02/08 18:29 75-34-3
1,2-Dichloroethane ND ug/L 0.50 05/02/08 18:29 107-06-2
1, 1-Dichloroethene ND ug/L 0.50 05/02/08 18:29 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:29 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:29 156-60-5
1,2-Dichloropropane ND ug/L 0.50 05/02/08 18:29 78-87-5
1,3-Dichloropropane ND ug/L 0.50 05/02/08 18:29 142-28-9
2,2-Dichloropropane ND ug/L 0.50 05/02/08 18:29 594-20-7
1, 1-Dichloropropene ND ug/L 0.50 05/02/08 18:29 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:29 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:29 10061-02-6
Diisopropyl ether 116 ug/L 0.50 05/02/08 18:29 108-20-3
Ethylbenzene 2.1 ug/L 0.50 05/02/08 18:29 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 05/02/08 18:29 87-68-3
lsopropylbenzene (Cumene) ND ug/L 0.50 05/02/08 18:29 98-82-8
p-lsopropyltoluene ND ug/L 0.50 05/02/08 18:29 99-87-6
Methylene Chloride ND ug/L 2.0 05/02/08 18:29 75-09-2
Methyl-tert-butyl ether 43.6 ug/L 0.50 05/02/08 18:29 1634-04-4
Naphthalene 2.8 ug/L 2.0 05/02/08 18:29 91-20-3
n-Propylbenzene 0.69 ug/L 0.50 05/02/08 18:29 103-65-1
Styrene ND ug/L 0.50 05/02/08 18:29 100-42-5
1 , 1, 1,2-Tetrachloroethane ND ug/L 0.50 05/02/08 18:29 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 0.50 05/02/08 18:29 79-34-5
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS Page 8 of 22
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~ f ~1
~ • ® I ~PaceAnalytJcal I _ _,,, , W>\W.paooiabs.oom
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suiie 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-3
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
LablD: 9218385003 Collected: 04/29/08 18:30 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit OF Prepared
Analytical Method: SM 6210
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
0.78 ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
1.5 ug/L 1.0
ND ug/L 0.50
109 % 60-140
98 % 60-140
104 % 60-140
100 % 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No.
05/02/08 18:29 127-18-4
05/02/08 18:29 108-88-3
05/02/08 18:29 87-61-6
05/02/08 18:29 120-82-1
05/02/08 18:29 71-55-6
05/02/08 18:29 79-00-5
05/02/08 18:29 79-01-6
05/02/08 18:29 75-69-4
05/02/08 18:29 96-18-4
05/02/08 18:29 95-63-6
05/02/08 18:29 108-67-8
05/02/08 18:29 75-01-4
05/02/08 18:29 1330-20-7
05/02/08 18:29 95-47-6
05/02/08 18:29 17060-07-0
05/02/08 18:29 1868-53-7
05/02/08 18:29 460-00-4
05/02/08 18:29 2037-26-5
Qual
Page 9 of 22
&ce Anatyticat'
1 .. ---i .mw.pacelabs.com
/
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suiie i 00
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-4 LablD: 9218385004 Collected: 04/29/08 18:25 Received: 04/30/08 17:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
6210 MSV Analytical Method: SM 6210
Benzene ND ug/L 0.50 05/02/08 18:53 71-43-2
Bromobenzene ND ug/L 0.50 05/02/08 18:53 108-86-1
Bromochloromethane ND ug/L 0.50 05/02/08 18:53 74-97-5
Bromodichloromethane ND ug/L 0.50 05/02/08 18:53 75-27-4
Bromoform ND ug/L 0.50 05/02/08 18:53 75-25-2
Bromomethane ND ug/L 1.0 05/02/08 18:53 74-83-9
n-Butylbenzene ND ug/L 0.50 05/02/08 18:53 104-51-8
sec-Butylbenzene ND ug/L 0.50 05/02/08 18:53 135-98-8
tert-Butylbenzene ND ug/L 0.50 05/02/08 18:53 98-06-6
Carbon tetrachloride ND ug/L 0.50 05/02/08 18:53 56-23-5
Chlorobenzene ND ug/L 0.50 05/02/08 18:53 108-90-7
Chloroethane ND ug/L 1.0 05/02/08 18:53 75-00-3
Chloroform ND ug/L 0.50 05/02/08 18:53 67-66-3
Chloromethane ND ug/L 1.0 05/02/08 18:53 74-87-3
2-Chlorotoluene ND ug/L 0.50 05/02/08 18:53 95-49-8
4-Chlorotoluene ND ug/L 0.50 05/02/08 18:53 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 05/02/08 18:53 96-12-8
Dibromochloromethane ND ug/L 0.50 05/02/08 18:53 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 0.50 05/02/08 18:53 106-93-4
Dibromomethane ND ug/L 0.50 05/02/08 18:53 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 05/02/08 18:53 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 05/02/08 18:53 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 05/02/08 18:53 106--46-7
Dichlorodifluoromethane ND ug/L 0.50 05/02/08 18:53 75-71-8
1 , 1-Dichloroethane ND ug/L 0.50 05/02/08 18:53 75-34-3
1,2-Dichloroethane ND ug/L 0.50 05/02/08 18:53 107-06-2
1, 1-Dichloroethene ND ug/L 0.50 05/02/08 18:53 75•35-4
cis-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:53 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 05/02/08 18:53 156-60-5
1,2-Dichloropropane ND ug/L 0.50 05/02/08 18:53 78-87-5
1 ,3-Dichloropropane ND ug/L 0.50 05/02/08 18:53 142-28-9
2,2-Dichloropropane ND ug/L 0.50 05/02/08 18:53 594-20-7
1 , 1-Dichloropropene ND ug/L 0.50 05/02/08 18:53 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:53 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 05/02/08 18:53 10061-02-6
Diisopropyl ether ND ug/L 0.50 05/02/08 18:53 108-20-3
Ethylbenzene ND ug/L 0.50 05/02/08 18:53 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 05/02/08 18:53 87-68-3
lsopropylbenzene (Cumene) ND ug/L 0.50 05/02/08 18:53 98-82-8
p-lsopropyltoluene ND ug/L 0.50 05/02/08 18:53 99-87-6
Methylene Chloride ND ug/L 2.0 05/02/08 18:53 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 05/02/08 18:53 1634-04-4
Naphthalene ND ug/L 2.0 05/02/08 18:53 91-20-3
n-Propylbenzene ND ug/L 0.50 05/02/08 18:53 103-65-1
Styrene ND ug/L 0.50 05/02/08 18:53 100--42-5
1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 05/02/08 18:53 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 0.50 05/02/08 18:53 79-34-5
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS Page 10 of 22
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
-·tf~~ fr ea i
.7 ® I :-P5ce Analytical !/
1 WIIW.paceiabs.com
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-4
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
LablD: 9218385004 Collected: 04/29/08 18:25 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: SM 6210
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
107 % 60-140
100 % 60-140
105 % 60-140
99 % 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
05/02/08 18:53 127-18-4
05/02/08 18:53 108-88-3
05/02/08 18:53 87-61-6
05/02/08 18:53 120-82-1
05/02/08 18:53 71-55-6
05/02/08 18:53 79-00-5
05/02/08 18:53 79-01-6
05/02/08 18:53 75-69-4
05/02/08 18:53 96-18-4
05/02/08 18:53 95-63-6
05/02/08 18:53 108-67-8
05/02/08 18:53 75-01-4
05/02/08 18:53 1330-20-7
05/02/08 18:53 95-47-6
05/02/08 18:53 17060-07-0
05/02/08 18:53 1868-53-7
05/02/08 18:53 460-00-4
05/02/08 18:53 2037-26-5
Page 11 of 22
~ • ® ,/"' i£,.e·A n,,/11+1cl')1 I /'I ac., 11a'YL at I_,,.,-,/ i www.pacelabs.com l
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suiie iOO
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-1 FD
Parameters
6210 MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroelhane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-nichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Date: 05/07/2008 03:13 PM
LablD: 9218385005 Collected: 04/29/08 18:35 Received: 04/30/08 17:10 Matrix: Water
Results Units
Analytical Method: SM 6210
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
1.2 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
2.6 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
Report Limit
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
1.0
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
2.0
0.50
2.0
0.50
0.50
0.50
0.50
OF Prepared
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No.
05/02/0819:17 71-43-2
05/02/08 19: 17 108-86-1
05/02/08 19:17 74-97-5
05/02/08 19:17 75-27-4
05/02/08 19:17 75-25-2
05/02/08 19:17 74-83-9
05/02/08 19: 17 104-51-8
05/02/08 19:17 135-98-8
05/02/08 19: 17 98-06-6
05/02/08 19:17 56-23-5
05/02/08 19: 17 108-90-7
05/02/08 19:17 75-00-3
05/02/08 19:17 67-66-3
05/02/08 19:17 74-87-3
05/02/08 19:17 95-49-8
05/02/08 19:17 106-43-4
05/02/0819:17 96-12-8
05/02/08 19:17 124-48-1
05/02/08 19:17 106-93-4
05/02/08 19: 17 7 4-95-3
05/02/08 19:17 95-50-1
05/02/0819:17 541-73-1
05/02/08 19:17 106-46-7
05/02/08 19:17 75-71-8
05/02/08 19:17 75-34-3
05/02/08 19:17 107-06-2
05/02/08 19:17 75-35-4
05/02/08 19: 17 156-59-2
05/02/08 19: 17 156-60-5
05/02/08 19:17 78-87-5
05/02/08 19:17 142-28-9
05/02/08 19: 17 594-20-7
05/02/08 19:17 563-58-6
05/02/0819:17 10061-01-5
05/02/08 19: 17 10061-02-6
05/02/08 19: 17 108-20-3
05/02/08 19:17 100-41-4
05/02/08 19:17 87-68-3
05/02/08 19: 17 98-82-8
05/02/08 19:17 99-87-6
05/02/08 19:17 75-09-2
05/02/08 19: 17 1634-04-4
05/02/08 19:17 91-20-3
05/02/08 19:17 103-65-1
05/02/08 19:17 100-42-5
05/02/08 19:17 630-20-6
05/02/08 19:17 79-34-5
Qua!
Page 12 of 22
""' • ® r ~/\Cl An,.,,,",",,, 1 ,/, avv 11 a1'Yuva1 1---i www.pacelabs.com
I
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: MW-1 FD
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
LablD: 9218385005 Collected: 04/29/08 18:35 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: SM 6210
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
105 % 60-140
98 % 60-140
107 % 60-140
100 % 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~#.--~~~~ f!TIPmt"'\t
Analyzed GAS No. Qual
05/02/08 19:17 127-18-4
05/02/08 19:17 108-88-3
05/02/08 19: 17 87-61-6
05/02/08 19: 17 120-82-1
05/02/08 19:17 71-55-6
05/02/08 19: 17 79-00-5
05/02/08 19: 17 79-01-6
05/02/08 19:17 75-69-4
05/02/08 19: 17 96-18--4
05/02/08 19:17 95-63-6
05/02/08 19:17 108-67-8
05/02/08 19: 17 75-01-4
05/02/08 19: 17 1330-20-7
05/02/08 19: 17 95-47-6
05/02/08 19:17 17060-07-0
05/02/08 19: 17 1868-53-7
05/02/08 19: 17 460-00-4
05/02/08 19: 17 2037-26-5
Page 13 of22
~eAnalytica!' f -·-www.pacelabs.com
!
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: WSW-2 LablD: 9218385006 Collected: 04/29/08 19:05 Received: 04/30/08 17:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed GAS No. Qual
6210 MSV Analytical Method: SM 6210
Benzene ND ug/L 0.50 05/02/08 19:41 71-43-2
Bromobenzene ND ug/L 0.50 05/02/08 19:41 108-86-1
Bromochloromethane ND ug/L 0.50 05/02/08 19:41 74-97-5
Bromodichloromethane ND ug/L 0.50 05/02/08 19:41 75-27-4
Bromoform ND ug/L 0.50 05/02/08 19:41 75-25-2
Bromomethane ND ug/L 1.0 05/02/08 19:41 74-83-9
n-Butylbenzene ND ug/L 0.50 05/02/08 19:41 104-51-8
sec-Butylbenzene ND ug/L 0.50 05/02/08 19:41 135-98-8
tert-Butylbenzene ND ug/L 0.50 05/02/08 19:41 98-06-6
Carbon tetrachloride ND ug/L 0.50 05/02/08 19:41 56-23-5
Chlorobenzene ND ug/L 0.50 05/02/08 19:41 108-90-7
Chloroethane ND ug/L 1.0 05/02/08 19:41 75-00-3
Chloroform ND ug/L 0.50 05/02/08 19:41 67-66-3
Chloromethane ND ug/L 1.0 05/02/08 19:41 74-87-3
2-Chlorotoluene ND ug/L 0.50 05/02/08 19:41 95-49-8
4-Chlorotoluene ND ug/L 0.50 05/02/08 19:41 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 05/02/08 19:41 96-12-8
Dibromochloromethane ND ug/L 0.50 05/02/08 19:41 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 0.50 05/02/08 19:41 106-93-4
Dibromomethane ND ug/L 0.50 05/02/08 19:41 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 05/02/08 19:41 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 05/02/08 19:41 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 05/02/08 19:41 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 05/02/08 19:41 75-71-8
1 , 1-Dichloroethane ND ug/L 0.50 05/02/08 19:41 75-34-3
1,2-Dichloroethane ND ug/L 0.50 05/02/08 19:41 107-06-2
1, 1-Dichloroethene ND ug/L 0.50 05/02/08 19:41 75-35-4
cis-1,2-Dichloroelhene ND ug/L 0.50 05/02/08 19:41 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 05/02/08 19:41 156-60-5
1,2-Dichloropropane ND ug/L 0.50 05/02/08 19:41 78-87-5
1,3-Dichloropropane ND ug/L 0.50 05/02/08 19:41 142-28-9
2 ,2-Dichloropropane ND ug/L 0.50 05/02/08 19:41 594-20-7
1, 1-Dichloropropene ND ug/L 0.50 05/02/08 19:41 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 05/02/08 19:41 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 05/02/08 19:41 10061-02-6
Diisopropyl ether 1.4 ug/L 0.50 05/02/08 19:41 108-20-3
Ethylbenzene ND ug/L 0.50 05/02/08 19:41 100-41-4
Hexachloro-1,3-bu1adiene ND ug/L 2.0 05/02/08 19:41 87-68-3
lsopropylbenzene (Cumene) ND ug/L 0.50 05/02/08 19:41 98-82-8
p-lsopropyltoluene ND ug/L 0.50 05/02/08 19:41 99-87-6
Methylene Chloride ND ug/L 2.0 05/02/08 19:41 75-09-2
Methyl-tert-butyl ether 4.6 ug/L 0.50 05/02/08 19:41 1634-04-4
Naphthalene ND ug/L 2.0 05/02/08 19:41 91-20-3
n-Propylbenzene ND ug/L 0.50 05/02/08 19:41 103-65-1
Styrene ND ug/L 0.50 05/02/08 19:41 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 05/02/08 19:41 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 05/02/08 19:41 79-34-5
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS Page 14 of 22
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
1tt"-cco,,.
-"~ ff( 1
~e Af/atytica/'
/ __ / WIIW.paw/abs,com
f '
Pace Analytical Services, Inc,
2225 Riverside Dr,
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc,
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
Sample: WSW-2
Parameters
6210 MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
T rich lorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromotluorobenzene (S)
Toluene-dB (S)
Date: 05/07/2008 03:13 PM
LablD: 9218385006 Collected: 04/29/08 19:05 Received: 04/30/08 17:10 Matrix: Water
Results Units Report Limit OF Prepared
Analytical Method: SM 6210
ND ug/L 0,50
ND ug/L 0,50
ND ug/L 2,0
ND ug/L 2,0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0,50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
108 % 60-140
99 % 60-140
105 % 60-140
100 % 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc __
.6~~~"-. t(H Qi
Analyzed CAS No, Qual
05/02/08 19:41 127-18-4
05/02/08 19:41 108-88-3
05/02/08 19:41 87-61-6
05/02/08 19:41 120-82-1
05/02/08 19:41 71-55-6
05/02/08 19:41 79-00-5
05/02/08 19:41 79-01-6
05/02/08 19:41 75-69-4
05/02/08 19:41 96-18-4
05/02/08 19:41 95-63-6
05/02/08 19:41 '108-67-8
05/02/08 19:41 75-01-4
05/02/08 19:41 1330-20-7
05/02/08 19:41 95-47-6
05/02/08 19:41 17060-07-0
05/02/08 19:41 1868-53-7
05/02/08 19:41 460-00-4
05/02/08 19:41 2037-26-5
Page 15 of 22
a /Jno/J"iro/'
1 /• avv, u1a,fL1va,
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Pace Analytical Services, Inc.
???5 Riv,:)rsirlt> Dr
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
QC Batch: MSV/3284
QC Batch Method: SM 6210
Associated Lab Samples: 9218385002
METHOD BLANK: 108910
Associated Lab Samples: 9218385002
Parameter
1, 1, 1,2-Tetrachloroethane ug/L
1, 1, 1-Trichloroethane ug/L
1, 1,2,2-Tetrachloroethane ug/L
1, 1 ,2-Trichloroethane ug/L
1, 1-Dichloroethane ug/L
1, 1-Dichloroethene ug/L
1, 1-Dichloropropene ug/L
1,2,3-Trichlorobenzene ug/L
1,2,3-Trichloropropane ug/L
1,2,4-Trichlorobenzene ug/L
1,2,4-Trimethylbenzene ug/L
1,2-Dibromo-3-chloropropane ug/L
1,2-Dibromoethane (EDB) ug/L
1,2-Dichlorobenzene ug/L
1,2-Dichloroethane ug/L
1,2-Dichloropropane ug/L
1,3,5-Trimethylbenzene ug/L
1,3-Dichlorobenzene ug/L
1,3-Dichloropropane ug/L
1,4-Dichlorobenzene ug/L
2,2-Dichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorotoluene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichloroditluoromethane ug/L
Oiisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
Date: 05/07/2008 03:13 PM
Units
Analysis Method:
Analysis Description:
SM 6210
6210 MSV
Blank Reporting
Result Limit Qualifiers
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 2.0
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. {ff~i
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of22
aAnalytica(
I WIIW-pace/abs.com
(
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
METHOD BLANK: 108910
Associated Lab Samples: 9218385002
Parameter Units
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
p--lsopropyltoluene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
tert-Butylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
LABORATORY CONTROL SAMPLE: 108911
Parameter
1,1, 1,2-Tetrachloroethane
1,1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethane
·j ,1,2-Trichloroeihane
1, 1-Dichloroethane
1, 1-Dichloroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
Date: 05/07/2008 03:13 PM
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Blank Reporting
Result Limit Qualifiers
ND 1.0
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 1.0
106 60-140
105 60-140
99 60-140
99 60-140
Spike LCS LCS % Rec
Cone. Result % Rec Limits
10 11.7 117 60-140
10 11.2 112 60-140
10 10.5 105 60-140
10 10.9 109 60-140
10 10.2 102 60-140
10 10.4 104 60-140
10 11.0 110 60-140
10 10.8 108 60-140
10 11.3 113 60-140
10 10.3 103 60-140
10 10.6 106 60-140
10 11.4 114 60-140
10 11.8 118 60-140
10 10.9 109 60-140
10 11.8 118 60-140
10 10.5 105 60-140
10 10.7 107 60-140
10 10.7 107 60-140
10 10.9 109 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc ..
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Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 17 of 22
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
LABORATORY CONTROL SAMPLE: 108911
Parameter Units
1,4-Dichlorobenzene ug/L
2,2-Dichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorotoluene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichlorofl1elhane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
p-lsopropyltoluene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
iert-Buiylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
Date: 05/07/2008 03:13 PM
Pace Analytical Services, Inc.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Cone. Result % Rec Limits
10 10.5 105 60-140
10 11.2 112 60-140
10 10.4 104 60-140
10 10.7 107 60-140
10 10.5 105 60-140
10 9.7 97 60-140
10 11.6 116 60-140
10 11.9 119 60-140
10 12.0 120 60-140
10 11.2 112 60-140
10 13.0 130 60-140
10 11.3 113 60-140
10 11.0 110 60-140
10 11.7 117 60-140
10 9.7 97 60-140
10 10.6 106 60-140
10 12.4 124 60-140
10 11.4 114 60-140
10 11.8 118 60-140
10 10.5 105 60-140
10 10.7 107 60-140
10 10.7 107 60-140
10 10.7 107 60-140
10 11.3 113 60-140
20 21.9 109 60-140
10 11.5 115 60-140
10 10.9 109 60-140
10 10.7 107 60-140
10 10.3 103 60-140
10 11.3 113 60-140
10 11.0 110 60-140
10 11.2 112 60-140
10 10.5 105 60-140
10 11.6 116 60-140
10 10.7 107 60-140
10 9.8 98 60-140
10 10.4 104 60-140
10 10 100 60-140
10 12.6 126 60-140
10 11.2 112 60-140
10 11.5 115 60-140
10 11.3 113 60-140
108 60-140
104 60-140
98 60-140
101 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~
'<,<:>~-"-~-t()-1 <" . . !i ~
Pace Analytical Services, Inc.
9800 Kincey lwe. Suite 100
Qualifiers
Huntersville, NC 28078
[phone]
Page 18 of22
a Analytic.al'
Pace Analytical Services, Inc.
2225 Riverside Dr.
I W\\W.pacelabs.com I
Asheville, NC 28804
[phone] I
QUALITY CONTROL DATA
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
QC Batch: MSV/3285
QC Batch Method: SM 6210
Analysis Method:
Analysis Description:
SM 6210
6210 MSV
Associated Lab Samples: 9218385001, 9218385003, 9218385004, 9218385005, 9218385006
METHOD BLANK: 108912
Associated Lab Samples: 9218385001, 9218385003, 9218385004, 9218385005, 9218385006
Blank Reporting
Parameter Units Result Limit Qualifiers
1,1,1,2-Tetrachloroethane ug/L ND 0.50
1, 1, 1-Trichloroethane ug/L ND 0.50
1, 1,2,2-Tetrachloroethane ug/L ND 0.50
1, 1,2-Trichloroethane ug/L ND 0.50
1, 1-Dichloroethane ug/L ND 0.50
1, 1-Dichloroethene ug/L ND 0.50
1, 1-Dichloropropene ug/L ND 0.50
1,2,3-Trichlorobenzene ug/L ND 2.0
1,2, 3-Trich loropro pane ug/L ND 0.50
1,2,4-Trichlorobenzene ug/L ND 2.0
1,2,4-Trimethylbenzene ug/L ND 0.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0
1,2-Dibromoethane (EDB) ug/L ND 0.50
1,2-Dichlorobenzene ug/L ND 0.50
1,2-Dichloroethane ug/L ND 0.50
1,2-Dichloropropane ug/L ND 0.50
1,3, 5-T rimethylbenzene ug/L ND 0.50
1,3-Dichlorobenzene ug/L ND 0.50
1,3-Dichloropropane ug/L ND 0.50
1,4-Dichlorobenzene ug/L ND 0.50
2,2-Dichloropropane ug/L ND 0.50
2-Chlorotoluene ug/L ND 0.50
4-Chlorotoluene ug/L ND 0.50
Benzene ug/L ND 0.50
Bromobenzene ug/L ND 0.50
Bromochloromethane ug/L ND 0.50
Bromodichloromethane ug/L ND 0.50
Bromoform ug/L ND 0.50
Bromomethane ug/L ND 1.0
Carbon tetrachloride ug/L ND 0.50
Chlorobenzene ug/L ND 0.50
Chloroethane ug/L ND 1.0
Chloroform ug/L ND 0.50
Chloromethane ug/L ND 1.0
cis-1,2-Dichloroethene ug/L ND 0.50
cis-1,3-Dichloropropene ug/L ND 0.50
Dibromochloromethane ug/L ND 0.50
Dibromomethane ug/L ND 0.50
Dichlorodifluoromethane ug/L ND 0.50
Diisopropyl ether ug/L ND 0.50
Ethylbenzene ug/L ND 0.50
Hexachloro-1,3-butadiene ug/L ND 2.0
lsopropylbenzene (Cumene) ug/L ND 0.50
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
1,111.ccoR &~ . . ~( 1
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of22
aAnalyticat' Pace Analytical Services, Inc.
2225 Riverside Dr.
I W'>'w.pacelabs.com Asheville, NC 28804
[phone] i
QUALITY CONTROL DATA
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
METHOD BLANK: 108912
Associated Lab Samples: 9218385001, 9218385003, 9218385004, 9218385005, 9218385006
Blank Reporting
Parameter Units Result Limit Qualifiers
m&p-Xylene ug/L ND 1.0
Methyl-tert-butyl ether ug/L ND 0.50
Methylene Chloride ug/L ND 2.0
n-Butylbenzene ug/L ND 0.50
n-Propylbenzene ug/L ND 0.50
Naphthalene ug/L ND 2.0
o-Xylene ug/L ND 0.50
p-lsopropyltoluene ug/L ND 0.50
sec-Butylbenzene ug/L ND 0.50
Styrene ug/L ND 0.50
tert-Butylbenzene ug/L ND 0.50
Tetrachloroethene ug/L ND 0.50
Toluene ug/L ND 0.50
trans-1,2-Dichloroethene ug/L ND 0.50
trans-1,3-Dichloropropene ug/L ND 0.50
Trichloroethene ug/L ND 0.50
Trichlorofluoromethane ug/L ND 1.0
Vinyl chloride ug/L ND 1.0
1,2-Dichloroethane-d4 (S) % 106 60-140
4-Bromofluorobenzene (S) % 105 60-140
Dibromofluoromethane (S) % 99 60-140
Toluene-dB (S) % 99 60-140
LABORATORY CONTROL SAMPLE & LCSD: 108913 108914
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Cone. Result Result % Rec % Rec Limits
------------
1, 1, 1,2-Tetrachloroethane ug/L 10 11.7 10.8 117 108 60-140
1, 1, 1-Trichloroethane ug/L 10 11.2 10.2 112 102 60-140
1, 1,2,2-Tetrachloroethane ug/L 10 10.0 9.3 100 93 60-140
1,1 ,2-Trichloroethane ug/L 10 10.9 9.8 109 98 60-140
1, 1-Dichloroethane ug/L 10 10.5 9.3 105 93 60-140
1, 1-Dichloroethene ug/L 10 10.6 9.6 106 96 60-140
1, 1-Dichloropropene ug/L 10 11.3 10.3 113 103 60-140
1,2,3-Trichlorobenzene ug/L 10 10 9.5 100 95 60-140
1,2,3-Trichloropropane ug/L 10 11.5 10.6 115 106 60-140
1,2,4-Trichlorobenzene ug/L 10 10.2 9.4 102 94 60-140
1,2,4-Trimethylbenzene ug/L 10 10.7 9.8 107 98 60-140
1,2-Dibromo-3-chloropropane ug/L 10 11.0 10.1 110 101 60-140
1,2-Dibromoethane (EDB) ug/L 10 11.5 10.8 115 108 60-140
1,2-Dichlorobenzene ug/L 10 10.9 10.1 109 101 60-140
1,2-Dichloroethane ug/L 10 11.5 10.2 115 102 60-140
1,2-Dichloropropane ug/L 10 10.6 9.4 106 94 60-140
1,3,5-Trimethylbenzene ug/L 10 10.8 9.7 108 97 60-140
1,3-Dichlorobenzene ug/L 10 10.5 9.8 105 98 60-140
1,3-Dichloropropane ug/L 10 11.0 10.0 110 100 60-140
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~. ' ' fr . 1
RPO
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Max
RPO Qualifiers
8 30
9 30
7 30
11 30
13 30
10 30
9 30
5 30
8 30
8 30
9 30
9 30
6 30
8 30
13 30
12 30
10 30
7 30
9 30
Page 20 of 22
a~n~l,nical' Pace Analytical Services, Inc.
VT'll UIJU I 2225 Riverside Dr.
I www.pacelabs.com Asheville, NC 28804
f [phone]
QUALITY CONTROL DATA
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
LABORATORY CONTROL SAMPLE & LCSO: 108913 108914
Parameter Units
1,4-Oichlorobenzene ug/L
2,2-Oichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorotoluene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Oichloropropene ug/L
Oibromochloromethane ug/L
Oibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
p-lsopropyltoluene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
tert-Butylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Oichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Oichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
Date: 05/07/2008 03:13 PM
Spike LCS LCSO LCS LCSO
Cone. Result Result % Rec % Rec
10 10.3 9.6 103 96
10 11.3 10.2 113 102
10 10.5 9.6 105 96
10 10.7 9.8 107 98
10 'I0.7 9.6 107 96
10 9.8 9.1 98 91
10 11.4 10.4 114 104
10 11.9 10.8 119 108
10 12.2 11.0 122 110
10 11.5 10.5 115 105
10 13.4 12.0 134 120
'10 11.4 10.3 114 103
10 11.1 10.1 111 101
10 11.5 10.5 115 105
10 9.8 8.8 98 88
10 10.5 9.7 105 97
10 12.5 11.3 125 113
10 11.5 10.5 115 105
10 11.9 10.5 119 105
10 10.6 9.4 106 94
10 10.7 9.8 107 98
10 10.9 10.0 109 100
10 10.4 10.1 104 101
10 11.4 10.5 114 105
20 22.4 20.3 112 101
10 11.5 10.7 115 107
10 10.5 10.1 105 101
10 10.6 9.8 106 98
10 10.4 9.3 104 93
10 10.8 10.3 103 103
10 11.2 10.1 112 101
10 11.1 10.0 111 100
10 10.5 9.7 105 97
10 11.6 10.7 116 107
10 10.6 9.8 106 98
10 10.1 9.0 101 90
10 10.6 9.7 106 97
10 10.1 9.2 101 92
10 12.5 11.4 125 114
10 11.5 10.3 115 103
10 11.6 10.8 116 108
10 11.5 10.3 115 103
107 107
104 105
98 98
100 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
% Rec
Limits
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Max
RPO RPO Qualifiers
7 30
10 30
9 30
9 30
11 30
7 30
9 30
10 30
10 30
10 30
11 30
10 30
9 30
10 30
11 30
7 30
11 30
9 30
13 30
12 30
9 30
9 30
3 30
8 30
10 30
7 30
4 30
8 30
11 30
4 30
10 30
10 30
9 30
3 30
8 30
11 30
10 30
10 30
10 30
11 30
7 30
11 30
Page 21 of 22
a Analytical' Pace Analytical Services, Inc.
2225 Riverside Dr.
I w,.w.pace/abs.com
I
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: LOVES GROCERY 36000
Pace Project No.: 9218385
DEFINITIONS
DF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values.
LCS(D) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPO Relative Percent Difference
NC -Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PASI-C Pace Analytical Services -Charlotte
Date: 05/07/2008 03:13 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc ..
Page 22 of 22
ATTACHMENT C
FIELD DATA SHEETS
Site Name: Loves Grocery
Site Number: 36000
Monitoring MW-1
Well Number (FP)
Total Well
Depth 15.00
(ft btoc)
Depth to
Product NA
(ft btoc)
Depth to
Water 3.94
(ft btoc)
Well Volume 1.80 (gallons)
Purge Date 4/29/08
Purge Method Disposable
Bailer
Gallons 5.5 Purged
Date Sampled 4/29/08
Sampling Disposable
Method Bailer
Time of 1835 Sample
Comments
CNL = Couid Not Locate
MW-1
(Love's)
20.00
NA
5.53
2.36
4/29/08
Disposable
Bailer
7.0
4/29/08
Disposable
Bailer
1845
Ft btoc = feet below top of casing
NA = Not applicable
MW-2
20.00
NA
11.20
1.43
4/29/08
Disposable
Bailer
2.5
4/29/08
Disposable
Bailer
1850
Going dry
during 2na
vol.
MW-3 MW-4 WSW-1 WSW-2 WSW-3 WSW-11
15.00 15.00 35 75-80 Unknown Unknown
NA NA NA NA NA NA
2.94 3.32 Unknown Unknown Unknown Unknown
1.97 1.90 NA NA NA NA
4/29/08 4/29/08 NA 4/29/08 NA NA
Disposable Disposable NA Pump in NA NA Bailer Bailer well
6.0 5.75 NA -10 min NA NA
4/29/08 4/29/08 NA 9/17/07 NA NA
Disposable Disposable NA Spigot NA NA Bailer Bailer
1830 1825 NA 1905 NA NA
Not Not
On site Sampled Sampled
well -Dry --on -on
No sample public public
water water