WS-6081_22332_CA_RMR_20170630

MONITORING REPORT
TEXACO FOOD MART #2
17OO COTTON GROVE ROAD
LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA
INCIDENT NO. 22332
SHIELD PROJECT NO. 1001289
April 2016 throu gh M.ay 2017
Contact:
David Holding
[phone]
Site Risk ClassifÌcation: High Risk (H155D)
Land Use Category: Residential and commercial
Release Discovered: February 8, 1999
Potential Release Source(s): Unknown
Site Latitud e: 35"46'41" North
Site Longitude: 80"15'35" West
Quantity Released : Unknown
Release Cause: Unknown
Responsible Party:
Techno, LLC for Holding
Brothers, Inc
P.O.Drawer 647
Concord, NC 28026
Consultant:
Shield Engineering, Inc.
4301Taggart Creek Road
Charlotte, North Carolina 28208
Contact:
Matthew T. Smith
[phone]
Property Owner:
United Oil of the Carolinas, Inc.
P.O. Box 68
Gastonia, North Carolina 28053
Contact:
David Dulmage
(704) 7et-0123
.otí1lilíIilr,
David A.
Senior P
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Matthew T. Smith
Project Manager
June 30,2017
Registered N
TABLE OF CONTENTS
Page No.
1.0 DISCUSSION OF SAMPLING RESULTS
2.0 CONCLUSIONS
3.0 RECOMMENDATIONS
4.0 LIMITATIONS...
4
.4
Figure 1:
Figure 2:
Figure 3:
Figure 4:
Figure 5:
Figure 6:
Figure 7:
Table l:
Table 2:
Table 3:
LIST OF FIGURES
Site Location Map
Site Map
1500' Radius Map
Groundwater Elevation Contour Map
Benzene Isoconcentration Map
1,2-Dichloroethane (DCA) Isoconcentration Map
Ethylene Dibromide (EDB) Isoconcentration Map
LIST OF TABLES
Summary of Adjacent Property and Water Supply Well Owners
Summary of Well Construction and Historical Groundwater Elevation Data
Summary of Historical Analytical Results - Groundwater Samples
APPENDICES
Appendix A: Laboratory Report - Groundwater Samples
H.\Projects\2000\l 001 289 - TFM#2\Reporrs\2017-06 MR\MR June 2017.doc
Texaco Food Mart #2
Lexington, Davidson County, North Carolina
Incident#:22332
Monitoring Report
June 30,2017
Page I
1.0 DISCUSSION OF SAMPLING RESULTS
1.1 Site Monitoring Requirements:
Site Location Map
Site Map:
See Figure I
See Figure 2
Site Monitoring Requirements
Based on CAP and/or NORR
Sample Point
Type
Total Quantity of Previous
Sample Points and Their
Identification
Required by NCDEQ to be
Monitored and Sampled per CAP
and/or TA
Monitoring
V/ells
l0
(MW-l through MW-6, and T-1
through T-4)
6 (t)
(MW-l through MW-5 and T-1)
Water Supply
Wells
13 Q)
(WSV/-I through WSV/-1 3)
0
(1) Individual wells identified by the North Carolina Department of Environmental Quality (NCDEQ) for specific
sampling at this time.
(2) Number of wells located within I ,500 feet of site.
1.2 Summarv of Analvtical Results and Free Product Thickness(s):
1.2.1 Date(s) of Sampling Event: }i4ay 5,2017
1.2.2 Existing Area Receptors:
A receptor survey was conducted in 2001 as presented in the CSA report dated Il;4ay 2002
and the CAP dated October 2003.
Refer to the following Tables and Figure(s) for information and locations of area receptors
identified.
R"f", to Figure(s): Figure 3
Refe, to Tables(s): Table I
1.2.3 Groundwater Flow Direction:. The gtoundwater flow direction is to the north-northeast.
Curent and/or Historical Groundwater Elevation Data are included in the following Table
and Figure:
R"f", to Table:
R"f", to Figure.
Table 2
Figure 4
Texaco Food Maft #2
Lexington, Davidson County, North Carolina
lncident#:22332
Monitoring Report
iune 30, 201 7
Page 2
1.2.4 Free Product:
. Free Product Detected During this Reporting Period?: No
1.2.5 GroundwaterAnalytical Results:. Sampled Points and Analytical Methods
(l) Pre-Approval Task Authorization TA-22332-1 5
o Laboratory Used: Pace Anallical Services Inc. Huntersville, NC
o Current Groundwater Analytical Data:
The following monitoring wells and other points were sampled during this reporting
period.
On May 5,2017 groundwater samples were collected from monitoring wells MV/-l
through MW-5 and T-1. One or more concentrations of analytes including benzene,
ethylbenzene, toluene, total xylenes, methyl tert-butyl ether (MTBE), naphthalene,
isopropylb enzene, n-propylbenzene,l ,2-dichloroethane (1,2-DCA), ethylene dibromide
(EDB), 1,2,4-tnmethylbenzene, and 1,3,5-trimethylbenzene were detected at
concentrations above the 154 NCAC 2L Groundwater Standards (2L Standards) in wells
including MW-l, M'W-2, MW-3, MW-4, and T-1. Concentrations of analytes including
benzene,l,2-DCA, and EDB were detected above the North Carolina Department of
Environmental Quality (NCDEQ) gross contaminant levels (GCLs) in MW-2.
Refer to the following Table and Appendix for current groundwater analytical data.
R"f", to Figures
R"f", to Table:
R"f", to Appendix
Figures 5 through 7
Table 3
Appendix A
Sampled Points and Analytical Methods
for this Reporting Period
Based on CAP and Pre-Approval Task Authorization Sampling Requirements
Type Points Sampled during this
Reportins Period
Analytical Methods
Monitoring
V/ells
(6¡ t'r
(MW-l through MW-5 and T-1)
a EPA Method 62008
Texaco Food Marl #2
Lexington, Davidson County, North Carolina
lncident#:22332
Monitoring Report
June 30, 201 7
Page 3
a Historical Groundwater Analytical Data:
Total dissolved phase petroleum concentrations in monitoring wells MV/-1, MW-2,
MW-3, MW-4, and T-1 have increased in comparison to March 2O16 data. No dissolved
phase petroleum concentrations have been detected at or above the laboratory detection
limits in monitoring well MW-5 since the March 2009 sampling event.
Refer to the following table(s) for historical groundwater analytical data.
R"fer to Table(s).' Table 3
o Dissolved Phase Plume Size and Location:
The on-site dissolved phase plume is iregularly shaped and has an approximate length of
115 feet and width of 85 feet based on the benzene concentrations above 2L Standards.
The dissolved phase plume that is above the NCDEQ GCLs is approximately 16 feet by
10 (Figure 5). The plume maps for constituents that are above the GCLs are shown on
the following figures.
R"fe, Io Figure(s).' Figures 5 through 7
a Proximity of Plume to Nearest Receptor(s)
Based on the receptor survey conducted in200l, there were three (3) confirmed drinking
water supply wells and six (6) inactive supply wells located within 1,000 feet of the
source area. The closest drinking water supply well (WSV/-1) is located approximately
450 feet south (hydraulically upgradient) of the site. No surface water bodies were
observed in the field or on the topographic map within 500-feet of the source area.
R"f", to Figure
R"fe, to Table:
Figure 3
Table 1
a
1.2.6 Other Field Data Collected:. No additional held data was collected
Predictive Rate of Contaminant Transporl:
The contaminant plume has been fairly stable or immobile over the past several years,
and in general reducing in concentration.
R"f", to Table(s)Tables 2 and3
Texaco Food Mart #2
Lexington Davidson County, North Carolina
lncident#:22332
Monitoring Reporl
June 30, 201 7
Page 4
2.0 CONCLUSIONS
o Free product \üas not detected in site wells during this reporting period.
o Dissolved phase petroleum constituent compounds \ryere detected in concentrations above
2L Standards in monitoring wells MW-1 through MV/-4 and T-1.o Dissolved phase concentrations of benzene,l,2-DCA, and EDB were above the NCDEQ
GCLs in MW-2.. Dissolved phase petroleum constituent compound concentrations increased in monitoring
wells MW-l, MW-2, MV/-3, MW-4, and T-1 since March20l6.o MW-5 continues to show non-detect levels of contamination.o In 2007, three (3) privately owned drinking water supply wells were identified within a
1,000-foot radius of the source area with the nearest confirmed drinking water supply
well approximately 450 feet hydraulically upgradient from the source area.o Based on a conversation with Michael Rogers of the NCDEQ on November 76,2010,
since WSV/-I is approximately 450 feet upgradient of the site and the property owner
would not allow Shield oTNCDEQ to sample their supplywell, the Texaco Food Mart #2
site would likely be reduced to low risk if soil excavation was completed to remove as
much soil as feasibly possible in the area of SB-8 and if MV/-2 groundwater
concentrations were below GCLs.o Soil excavation around boring SB-8 was conducted on February 28, 2012 via over
drilling with 14-inch outside diameter hollow stem augers around the boring. Details of
the excavation were previously submitted to the NCDEQ in the Monitoring Report dated
October 23,2012.
3.0 RECOMMENDATIONS
It is recommended that bi-weekly air sparging be conducted to reduce the groundwater
concentrations to below GCLs, with NCDEQ and Trust Fund approval.
Shield also recommends that Mobile Multi-Phase Extraction (MMPE) events be
conducted at the site in order to expedite cleanup. Shield recommends conducting semi-
annual MMPE events, beginning in October 2017, along with follow-up sampling events
in order to monitor the effectiveness of the MMPE events.
Once MW-2 is below the GCLs, Shield will request a "no further action" determination
from the NCDEQ.
a
a
a
Texaco Food Maft #2
Lexington Davidson County, North Carolina
Incident#:22332
Monitoring Report
June 30,2017
Page 5
4.0 LIMITATIONS
Shield has performed environmental services at the subject site on behalf of Techno LLC for Holding
Brothers, Inc. Shield has performed this scope ofwork as an independent contractor/consultant using
reasonable care and skill in accordance and consistent with customary industry standards of
engineering, geology, and hydrogeologypractices. This standard of care is the sole and exclusive
standard of care that can be applied to measure Shield's performance of the work. No other
warranty, expressed or implied is made or intended by Shield.
The report has been prepared for the exclusive use by Techno LLC for Holding Brothers, Inc. All
recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's
knowledge, opinion and belief, based upon information obtained during this scope of Techno LLC
for Holding Brothers, Inc. and Shield. Conclusions are provided with the understanding that Shield
is presenting information and not rendering legal advice. If such advice is needed, legal counsel
should be consulted. It is the responsibility of Techno LLC for Holding Brothers, Inc. under advice
of its counsel to notify the appropriate federal, state, or local public agencies as required by law; or
otherwise to disclose in a timely manner, any information that may be necessary to prevent damage
to human health, safety, or the environment.
Compliance with recommendations provided as part of this report in no way assures compliance with
federal, state and/or local laws, regulations, and/or requirements. Analytical data has been obtained
from Pace Analytical Services Inc. This information, to the extent that it was relied on to generate
this report, is assumed to be correct and complete. The work performed in conjunction with this
report and the data developed are intended as a description of available information at the dates and
specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or
recommendations with respect to any conditions that were knowingly or unknowingly withheld,
concealed, hidden, or in any way not disclosed or observable at the time of this scope of work.
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AMOCO
RU5HCo #3
NoTEs: 1 - GROUNDWATER gAMPLES CoLLECTE0 oN 05/10/17
2. ALL LOCATIONS ARE APPROXIMÂTE,
3. CONTOUR tNftRVALS AS sHOWN.
PARKIÑG ARÉA
SCALE: 'l ln. = 30 ft.
(,
=ôñ
Id
=d
ô€N
oo
UÉf(,
L
N
ñF
o@N
oo
oooN
F(JroÉo
I
ê SHIELD iriiEtr*-M shieldeng¡nêsdqMENGINC.
ETHYLENE DIBROMIDE IEDB)
ISOCONCENTRATION ATAP,
TEXACO FOOD MART #2
ITOO COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA
sHlÊLD þ t001289
DATE: 06113/17 DRAWN BY: RBS
SCALE : AS SHOWN FIGURE : 7
6Þ
!g
1-4 VE-7(Ns)
vE.6
T$';io
ÂsPHALT
as-6o¡AS-5s¡O
REGULARusT
H,PREIIIE
U5T
REGULÁRUSTTANK
IEXACO
FOOD MART
F¡ VE.3
¿
AS-1
l¡w-¿ o )
(ND)
ASPHALl
o
KEROçÑE
AS-3
1-Z
(Ns)
DIESEL IJST
CONCRM PÁD
nw.¿ O
(NS)
VACANT LOT
DISPENSER orseenrsen.!
o,tttntt*!
!orseenrser
! orsrenrsrn
OISPENSER
!o'tr^n*
â
oÉ,U
oÉ,(9
z.o
Eo!¿€
UFfoÉ,Uz.
(D mw-z(Ns)
ìHt' o
GASOLIÑE Usf
zo
GASOLINE U5f
GASOLINE IJST(D rcnp-z o
(Ns)MW-'l(NS)
ACCESS ROAD CEDAR LANE ROAD O re¡,tp-t
(Ns)
LEGEND:
+ LIGHT POLE
ø PowER PoLE
ELECTRICAL LINE
SANITARY SEWER LINE
PRODUCf LINE MW.5
o
o
TEXACO FOOD MART MONITORING WELL
TEXACO FOOD MART DEEP MONITORINO WELL
(ND)
o A.A4OCO RUSHCO f3 MONITORING WELLALL 0ÀTA TAKEñ FRoM THE PHASE ll LIM¡TED slTE ASSES9ItENÌ
REPORT PREPARED BY CBM ENVIROMENÎAL SERVICEs, INC.DATED 4/lól0r.
O VE VAPOR EXTRACTION WELL
¡ AS AIRSPARGINGWEI.I(UglLI MICROGRAMS PER LITER
l'706I ETHYLENE DIBRoMIDE (EDBI CoNCENÍRATIoN (ug/L)
lNDl EÍHYLENE DIBROMIOE (EDB) CONCENIRATION NoT USED lN coNToURlñG (us/L)
EÍHYLENE 0lBRoMlDE (EDB) lsocoñctNTRATloñ LINE (us/LÌ
ETHYLENE DIBRoMIDE (EDBI lsocoNCENTRAT|oN LINE (us/L) EXCEEDING GROSS CoNTÂM|NANÌ LEVELS (GCLil
(NDI NOT DETECTED . BELOW LABORAIORY MEÍHOD OEIECTION LIMITS
(NSt NOT SAMPLEo APPROXIMATE GRAPHIC SCALE
0 15 30
AMOCO
RUSHCO #3
NOTES: I - GROUNoWATER SAMPLES COLLECTEo ON 05/10/17.
2. ÀLL LOCATIONS ARE APPROXIMAÍI.
3. CONIOUR INTERVALS A5 SHOWN,
PARKING AREA
scaLE: 1 ín. = 30 ft.
Table: ISummary of Adjacent Property and Water Supply'Well OwnersTexaco Food Mart#21700 Cotton Grove Road,Lexington, North CarolinaNCDENR Incident # 22332PublicWaterSystenrhook upNoYesYesNoYesYesYesNoYesUnkUnk.YesNoDistancefromsource areaof release(ft.)4s0'100'650'985'750',760'795t025'I 090'1 100'117 5'800'8s0'WellScreenInterval(¡toyft.BGS),l?]??)?I,)f21WellCasingDepth(ft. BGS),l,.1?,l),ì,.1I,l,l,l2?TypeofWell4")I)f,lÀ\1I,lI,l)IWellDepth(ftBcs)185?,lI,l,l,l>100,l2,)l,lDrinkingNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseIrrigationDrinkingPhone.Number336-357-2511336-3s7-5231336-357-2659336-357 -2916336-249-3266336-357 -2485336-357 -2565NANANANANANAP.O. Box 284 Lexington, NC104 Fuller Rd., Lexington, NC106 Fuller Rd., Lexington, NCI 15 Cedar Ln., Lexington, NC6 Mayfair Rd., Lexington, NC*Box 8 Mayfair Rd., Lexington,NCBox 100 Mayfair Rd.,Lexington, NCBox 108 Mayfair Rd.,Lexington, NCBox 107 Mayfair Rd,Lexington, NCBox I03 Mayfair Rd.,Lexington, NC1724 Southview Rd.,Lexington, NC102 Mayfair Rd., Lexington,NC104 Mayfair Rd., Lexington,NCWell Owner/ User (indicatewhich)Flowerest O. LoppPaul & Stella BakerMargaret H. FullerHoyle R. SmithEfird E. Jr. & Kay S.Wilson(owner)Abe CassidyMrs. Samuel C. DavisMaxine C. HouckThomas FrankJames G. HendersonRay S. & Irene MusgraveAubrey & Helen BrewerJohn T. TetterWell #wsw-tWSW-2wsw-3wsw-4WSW-5wsw-6WSW-7wsw-8wsw-gwsw-r0wsw-t Iwsw-r2wsw-r3Notes: Ft BCS: feet below ground sulface- Addless of well Property owner 's address is 500 Maegeo Dr., LexingtonOlthepropertyownerswithourPWShookups,onlyJohnTetterisinlerestedinbeaddedtothoPWs. Otherpropertyownersindicatedrhattheyarenotinteresredatall.NA - Not AccessibleH:\Projects\2000\1001289 - TFM#2\Reports\ARMR Aug 2014\Water Supply Well Infomation Table.doc
Table 2:
Summary o[ ]Vcll Construction and Historical Groundìvâtcr Elevation Dâtâ
Texaco Food Mzrtfl2
1700 Cotton Grovc Road, Lexington, North Carolina
NCDENR lncident # 22332
Well lD Dâte
I nsta lled
Top of
Casing
Elevation
(feet)
rrVcll
Diametcr
(inches)
As-built
Depth
(feet)
Screened
Interval (feet)
Ficld Mcasurements Field Calculations
Gauging Datc
Totâl
Depth
(fect)
Depth to
Static
Wâtcr
(feet)
Depth to
Frcc
Product
(fcet)
Diff. Betwccn
As-Built and
Measured Total
Depth (feet)
Ground-watcr
Elevation
(fect)
MW-t 01 /l I /0t ì 00.00 2 35 20-35 I U/t 0/ut J5.UO 24.0r)NA 0 75 9l
tJ4t22tU2 35.O0 22.t3 NA 0 77.87
t1t19to7 35.01 23.69 NA -0.01 t6.3 t
03/04/09 34.93 I 9.68 NA 0.07 80.32
tJ7D9D3 35.07 17.55 NA -o.ol 82.4507nul43 5.07 11.32 NA -0.07 82.6E
05t20il5 35 07 r8.60 NA -u.07 8ì.40
03tzut6 J5.U /16.48 NA -0.07 83.52
tJ5nlln7 35.07 20.08 NA -0.07 79.92
MW-Z ut/3t/0t t00 t9 2 35 20-35 I U/t U/Ut J5.UU '24.2¿NA 0 15.18
tJ4tzzttJz -15.0o 22.tJB NA 0 11.92
tUt9t07 34.15 23.84 NA 0.25 t6.35
03t04t09 34.6s 19.62 NA U,J 5 8U 57
06t28il2 J4.9 |tE.4u NA 0.09 81.71
tJ1n9n3 '34.94 11.53 NA 0.06 82.66
07nln4 34.94 t'7.28 NA U.UÓ E2.9t
05t20n5 34.94 I E.ó5 NA 0.06 81.54
o3tzut6 ')4.94 I 6.61 NA 0.06 83.58
05t10n7 34.94 20.26 NA 006 t9.93
MW-3 t u/uu/01 100.19 2 35 20-35 I U/lU/Ul J5.UU 24.2 t NA 0 75.92
tJ4t22ttJz 35.O0 2t.93 NA 0 78.26
tyt9t07 35.03 24.10 NA -0.03 /ó.u9
03t04/09 34.96 I 9.J5 NA u.04 80.84
07t19n3 J5.UE t] .21 NA -0.08 82.96
07^1/t4 35.08 t 7.05 NA -0.08 83.14
[5t20/l5 35.08 I 8.48 NA -0.0E 81.7t
03tzil16 35.08 l6.J I NA -(.)_0u 83.88
u5/ I 0/t ó 35.0u 20 I0 NA -0.08 80.09
MW-4 r o/u8/u I r.)9.4tJ 2 35 20-35 10t10tot J),UU 24.1l NA U 76.08
ù4122102 J5.OU 2t.91 NA 0 18.28
lU19ilJ1 34.8I 23.8 8 NA 0. r9 7 5.52
03t04t09 34.74 19.90 NA u.¿6 t9.51)
07t20n0 34.72 lE.5/NA o.2lJ 80.83
tI]n913 34.91)t7 .9tJ NA 0.10 8l .50[7nln4 34.90 17.60 NA 0.10 E I.EO
05t20n5 f4.90 r8.66 NA U.I U 80.14
03/21/16 34.91)t 6.3tJ NA 0.ì0 83.02
u5/ltJ/l7 )4 <)t)20.rJz NA 0. t0 19.38
MW-5 u4/tJ4tu2 I (X).:t9 2 35 20-35 $4t ¿¿tu¿J).UU ,¿J.J4 NA 0 76.85
lln9toT 35.07 24 76 NA -0.07 '75.63
tJ3ltJ4ltJg 35.09 2t.t7 NA -0.09 t9.22
07/t9/t3 35.12 19.02 NA 02 8t.37
07nln4 J5 t¿Iu 7u NA -o.12 8l .61
ù5t2ut5 35 t2 t9.90 NA -0.12 80.49
03t21t16 35.'t2 11.79 NA -u.I ¿tJ2.60
05t10t17 35.12 '¿t.05 NA -0 t2 79 34
M\ry-6 04/04t02 lu I .4¿'¿'¿5 t5-25 14t22tO2 25.00 23.02 NA U I t.t7
I I /19t07 25.00 NM NA U NM
03/04t09 NM NM NM NM NM
Sum of well conslruct¡on and histor¡cal eroundwater elevalion
Suntmary of Wcll Construction and Historical Groundrvater El€vâtion Data
Texaco Food Mart#2
1700 Cotton Grove Road, Lex¡ngton, North Carolina
NCDENR lncident# 22332
\ilell lD Date
I nstalled
Top of
Casing
Elevation
(feet)
'Well
Diameter
(inches)
As-built
Dcpth
(feet)
Screened
lnterval (feet)
Field Measurements Field Calculations
Gauging Date
Total
Depth
(fcet)
Depth to
Static
ìùater
(feet)
Depth to
Free
Product
(feet)
Diff. Between
As-Built and
Measured Total
Depth (feet)
Ground-wate¡
Elcvation
(feet)
tl to/tJ9trJt 100.35 2 90 ð5 5-yU I 0/t u/ul y0.u0 24.v]NA 0 75.26
I4t22^12 90.00 22.06 NA 0 78.r3lln9t0786.71 21.s9 NA 3.¿9 1tl.16
03104/09 05.u2 t9.52 NA 24.il4 80.83
tJ1^9n3 66.84 r8.ì4 NA 23.16 82.21
07nln4 66.84 18.58 NA 23.16 Et.'t1
05t20/l5 66.84 t9-J6 NA 2t.t6 80.99
tJStzlD6 66.84 I7.08 NA 23.t6 83.27
05ntJil1 66.84 20.03 NA 23.t6 80.3¿
l. NM : Not Measured
2. NA: Not Applicable
Pugc 2 of2Sum of well conslruclion and hislorical gtoundwaler eteva!¡on
Trblc 3
Sunrnrary of ll is(or¡câl Ânal¡,tical llcsul(s-Groundrvìter Sårìl)lcs
Tcxaco l'oorl ù'l art #2
I 700 Colton Grove Roatl, Lcx¡ngton, North Carolina
NCDENR lncidcnr # 22332
Analylicål Melhorl---->EPA Methorl 601/602
EP.\
lU el hod
504.1 o¡
62008
EP.\
M€r hod
625 or
62008
MADEP
VPH
MADEP VP]I &
EPII
I\IADEP
EPII
M,,\DEP VP}I &
EPH
ó F
X
F
q
¿
H @r
t
Èz
o
Q
il
Q
I
il
Q
Q
ol
I
il
()
U
il
()
o
E
t5A NCAC 2t..0202
Stan(lârd---->600 600 s00 20 70 0.4 0.02 6 400 ?00 I 0,000 c+d=
200
I 5A NCAC 2L.OI I5
Cross Conlån¡¡nal¡on
level--->
5,000 260,000 84,s00 85,500 20,000 ?0,000 400 50 6,000
l.ocrlion Dâre ur/L us/L rr/L ur,/1.ùD/L
MW-t o713ll0t ND 53 340 1,300 NR NR ND 0.9ó ?5 ND 3,470 ND 2,780
04t30t03 t2 r40 t3 I,4't0 NR ND ND NR 270 NR NR NR NR
t1il9t07 49.5 647 I't9 t,2r 0 ND ND ND ND t07 ND 665 Nt)825
03t04t09 53-7 284 165 827 ND ND ND ND 167 468 6,1 70 ND 2,200
01/ 19l t3 69.4 8't 4 2 767 't4 ND ND ND lt4 NR NR NR NR
01/ | t/ t4 71.2 0 t32 790 4'7 ND ND ND ilt NR NR NR NR
05t20il5 97.2 3 r45 816 52 ND 2 0.63 t43 NR NR NR NR
03t21il6 82.7 129 9 658 44 ND 2 ND 99.3 NR NR NR NR
05il0/t7 t26 9 164 899 36 ND 3.6 ND t20 NR NR NR NR
MW-2 0'1/3t/0t 13,000 38,000 3,600 t6,000 NR NR 1,200 720 NR 8l,000 28,000 NR 9,t00
04t30/03 12,000 29,000 2,800 16,700 NR ND 1,700 ND t,400 NR NR NR NR
lllt9/07 t4,900 34,200 3t090 18,400 6,090 ND t,150 ND r,090 60,t00 71,600 308 26,630
03t04t09 I t,700 21.200 2,250 t4.500 3,600 ND ND ND 238 59,300 s8,930 ND 8,340
06t28/l2 8,930 l?,800 I,'t60 I 0,950 7,420 144 t,090 635 914 NR NR NR NR
01t19n3 I 2,600 24,300 2,200 t3,380 7,550 194 1,330 1,260 NR NR NR NR
o't/|il4 10,300 2r 300 1,9t0 I r,980 7!040 142 t,2t0 66i 1,o'to NR NR NR NR
05/20/ts 6,410 12,600 989 6,460 4,830 90.9 713 4s1 898 NR NR NR NR
03t2t I t6 I 1,300 22,700 2,170 t3,200 6,240 t54 1,090 677 t,t 00 NR NR NR NR
05/10/t1 I 3,600 29,200 2,770 16,270 6,620 t8t 1,3t0 7t)6 t,t 80 NR NR NR NR
MVi/-3 I 0/ I 0/01 t20 4,300 1,800 8,600 NR NR ND 9.5 360 ND r r,990 ND tt,'110
04/30t03 r00 3,000 1,600 8,800 NR ND ND ND 660 NR NR NR NR
t)il9t07 ND 4,850 2,190 13,600 ND ND ND 1,2 5t3 NR 34ó0 ND 2,440
03t04t09 ND 3,430 2,090 I t,400 ND ND ND ND 1,520 5,560 40,926 ND r r,780
0'1 t19t t3 22 1,250 t,420 8,060 13 ND ND ND 744 NR NR NR NR
0'1/|tt4 55.r r,l 00 t,300 7,210 ND ND ND ND 83r NR NR NR NR
05/20/ t5 't7.2 954 t,250 6,710 94 ND ND ND 88r NR NR NR NR
03/21/t6 l7 854 1,090 5,870 ND ND ND ND 632 NR NR NR NR
05t t0t t1 21-6 t,630 ¡,680 9,510 ND ND ND ND 844 NR NR NR NR
MVr'_4 I 0/t0/0 I ND ND ND Nt)NR ND ND ND ND NR NR NR NR
04t30t03 ND ND ND ND NR ND ND NR Nt)NR NR NR NR
I I t9t01 Nt)ND ND ND 23 ND ND ND ND ND ND ND ND
0l/04/09 ND 5l ND 6 4l ND Nt)Nt)t23 ND t86 ND ND
01t20,l0 ND ND ND ND 87 ND ND ND ND ND ND ND ND
07/t9/t3 r.9 ND ND 46 40 Nt)ND ND ND NR NR NR NR
07il | t4 2.7 ND ND '1 2 65.9 ND ND ND ND NR NR NR NR
05t20t t5 2.7 ND ND 6'1 r06 Nt)ND ND ND NR NR NR NR
03t2t I t6 2.8 ND ND 64 ll6 ND ND ND ND NR NR NR NR
os/ t0/11 3.6 ND ND 91 213 ND ND ND ND NR NR NR NR
MW-5 04t30tol ND ND NI)ND NR NR ND NA ND NR NR NR NR
I I t9t07 ND ND ND ND ND ND ND ND 4l t44 ND ND Nt)
0t/04/09 ND t9 ND ND ND ND ND ND 29 ND ND ND ND
07t tgt 11 ND ND ND ND ND ND ND ND ND NR NR NR NR
01/| 1il4 ND ND Nt)ND ND ND ND ND ND NR NR NR NR
05t20t ts ND ND ND ND ND ND ND ND ND NR NR NR NR
llpgects\zM1n12Ao IFMiæepons\2'17 06 MÃStñ ol tltsrOR|CAL GW AnatytÈãl Page 1 oî 2
Tal¡le -f :
Sunrnrarv of llistorical Analvlical Resu¡ts-Groundtvatcr SaDlplcs
l'c\âco Foo(l l\lart #2
1700 Cotlon Grove Roarl, Lexington, North Cârol¡nâ
NCDENII lnciden. # 22332
Notes:
ug/l = Micrograms per liter ND = Below Method Detection Limit
NR = Ana lysis not requesl ed Bokl nu mbers exceed I 5 A NCAC 2 L 0202 standar ds
l5A NCAC2L0202=NCDEQStandardStatutelornonriskedbasedmaximumallowablecontainmentconcenlrâtioningroundwater
Other detecled ânalytes can be seen in the ¿nâlytical data
Analylicål Melhod---->EPA Method 601/602
EPA
Melhorl
504.1 or
62008
EPA
Melhod
625 or
62008
MADEP
VPH
MADEP VP}I &
EPH
MADEP
EPH
MADEP VPH &
EPII
É F
@
X
F
I
r @
o
Èz
o
U
il
(J
(J
il
(J
(,.)l
O
I
(,)
o
il
Q
I5A NCAC 2L.0202
Slandârd---->600 600 500 20 70 0.4 0.02 6 400 ?00 I 0,000 200
I5A NCAC 2L.OI I 5
Cross Contaminålion
level--->
5,000 260,000 84,s00 85,500 20,000 70,000 400 50 ó,000
Dale u o/L rtlL ùo/L ttll,rill,¡vll,ilr/1,ury'L
MW-5
CONT
03/21116 ND ND ND ND ND ND ND ND ND NR NR NR NR
05t10t l1 ND ND ND ND ND ND ND ND ND NR NR NR NR
T I 0/r 0/01 390 78 94 140 NR NR 44 2.8 24 8s0 2'10 ND 250
04/30t03 l7 28 ND t47 NR ND 8.1 ND 3l NR NR NR NR
I It9tl't 43.8 NT)ND ND 210 ND L'l ND ND ND ND ND ND
03t04t09 20.1 ND ND ND ND ND 25.7 NI)14.4 320 ND ND ND
071t9il3 t35 306 62 21 I 83 24 23,9 ND 7.'l NR NR NR NR
ï'ilt1/t4 I't2 059 55 l3 3 2t 2.8 43,7 ND 39 NR NR NR NR
05/20ils lls 054 75 t62 3.2 43.9 ND 38 NR NR NR NR
03t2lA6 l8.s ND 058 ND ND 078 l0.l ND ND NR NR NR NR
05110/ t'l tt7 053 l5 3 296 ND 1'l 28 ND 6.8 NR NR NR NR
Hptojæ¡s\2M1N1 289 IFMqMepf, s\201 7 06 M^Srn ol HtS I ORTCAL CW Anatfcat Page 2 ol 2
o
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.com
May 18,2017
Matt Smith
Shield Engineering
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project: Texaco Food Mart #2
Pace Project No.: 92340251
Dear Matt Smith:
Enclosed are the analytical results for sample(s) received by the laboratory on May 11,2017. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless othen¡¿ise noted in the body of the report.
lf you have any questions concerning this report, please feel free to contact me
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: James Gamertsfelder, Shield Engineering, lnc.
Mr. Tom Wtner, Shield Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not þe reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Serv¡ces, LLC Page 1 of 35
o
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.ctm
CERTIFICATIONS
Project:
Pace Project No.:
Texaco Food Mart #2
92340251
Charlotte Certif¡cat¡on lDs
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certifìcation #: 37706
North Carolina Field Services Certification #:5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certiflcation #: E87627
Kentucky UST Certificat¡on #: 84
VirginiaA/ELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the written consent of Pace Analytical Services, LLC Page 2 of 35
@
Pace Analyt¡cal Servicês, LLC
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.æm
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Texaco Food Marl#2
92340251
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
9234025100'.1
92340251002
92340251003
92340251004
92340251005
92340251006
92340251007
MW-1
MW-2
MW-3
MW.4
MW-5
T-l
Trip Blank
sM 62008
SM 62008
SM 6200B
SM 6200B
SM 62008
SM 62008
SM 62008
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLC
zDo
CAH
CAH
zDo
CAH
CAH
CAH
63
63
63
63
63
63
63
PASI-C
PASI-C
PASI.C
PASt-C
PASI-C
PASI-C
PASr-C
Page 3 of 35
@
Pace Analytical Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacielabs com
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food Mai#2
92340251
Sample: MW-1
Parameters
Lab lD: 92340251001
Results Units
Collected: 051101'17 11:13
Report Limit DF
Received: O5111117 12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichlorometha ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-D¡bromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-D¡chlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uorometha ne
1 ,1-D¡chloroethane
I ,2-Dichloroethane
1 ,1-Dichloroethene
cis-'1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,1-Dichloropropene
cis-1,3-Dichloropropene
trans-'1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro- 1 ,3-butad iene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
I ,1 ,1 ,2-fetachloroethane
1,1,2,2-Telr achloroethane
Tetrachloroethene
Analytical Method: SM 62008
126
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
164
ND
32.0
ND
3.6
120
54.4
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
12
1.2
12
1.2
1.2
12.5
1.2
12
1.2
1.2
1.2
2.5
't.2
2.5
12
1.2
2.5
1.2
1.2
12
1.2
12
1.2
1.2
1.2
1-2
1.2
1.2
12
12
1.2
't.2
1.2
1.2
1.2
12
1.2
5.0
12
50
12
50
1.2
1.2
't.2
12
12
25
2.5
2.5
2-5
2.5
2.5
2.5
2-5
2.5
25
25
2.5
25
2.5
2.5
2.5
25
2.5
2.5
2.5
2-5
2.5
2.5
2.5
25
2.5
2.5
2.5
2.5
25
2.5
2.5
2.5
2-5
2.5
2.5
2.5
25
2.5
25
25
25
25
2.5
2.5
2.5
2-5
05116117 19:54
05116117 19:54
051161'17 19:54
051161'17 19:54
05116117 19:54
O5116117 19:54
05116117 19:54
05116h7'19:54
05116117 19:54
05116117 19:54
05h6117 19:54
05116117 19:54
05116117 19:54
051'16117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
O5116117 19:54
051161'17 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
O5h6l17 19:54
05116117 19:54
051'16117 19154
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
051'16117 19:54
05116117 19:54
05116117 19:54
71-43-2
1 0B-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -B
1 35-98-8
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96- 1 2-B
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
'107-06-2
75-35-4
I 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061-01-5
I 0061-02-6
1 08-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-04-4
91-20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
L1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wrìtten consent of Pace Analytical Services, LLCDale: 05h 812017 02:45 PltA Page 4 of 35
@
Pace Analyt¡cal Services, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.con
ANALYTICAL RESULTS
Project:
Pace Project No
Texaco Food Marl#2
92340251
Sample: MW-l
Parameters
Lab lD: 92340251001
Results Units
Collected: 05110117 11i13
Report Limit DF
Received: 05111117 12:37 Matr¡x: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
1, 1,2-Trichloroethane
Tr¡chloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-D¡chloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Analytical Melhod: SM 62008
1',t9
ND
ND
ND
ND
ND
ND
ND
387
ND
ND
560
339
108
102
't04
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Yo
o/
%
1.2
5.0
5.0
1.2
1.2
1.2
2-5
1.2
't.2
1.2
2.5
2.5
1.2
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
25
2.5
2.5
2.5
2.5
05116117 19:54
05116117 19:54
05116117 19:54
05116117 19:54
O5l'16117 19:54
051'16l'17 19:54
05116117 19:54
05116117 19:54
05116h7 19:54
05116117'19:54
05116117 1954
051'16117 19:54
05116l'17 19:54
1 0B-BB-3
87-61 -6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-'18-4
95-63-6
1 08-67-8
75-01-4
17960't-23-1
95-47-6
70-130 2.5
70-130 2 5
70-130 2.5
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLC
05116117 19:54 17060-07-0
05116117 19:54 460-00-4
05116117 19:54 2037 -26-5
Dale: 0511812017 02:45 PM Page 5 of 35
@
Pace Analyt¡cal Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.æn
ANALYTICAL RESULTS
Project:
Pace Project No.:
Texaco Food Mart #2
92340251
Sample: MW-2
Parameters
Lab lD
Results
92340251002
Units
Collected: 05110117 1'l:19
Report Lim¡t DF
Received: 0511.1117 12:37 Matrix: Water
Prepared Analyzed CAS No Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
B ro mod ¡ch lo ro metha n e
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorod ifl u o rometh a ne
1 ,1 -Dichloroethane
I ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
I ,2-Dichloropropane
I ,3-Dichloropropane
2,2-Dichloropropane
1 ,1 -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-D¡chloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-Iet achlo roe th a ne
Tetrachloroethene
Analytical Method: SM 62008
I 3600
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
706
ND
ND
ND
ND
ND
ND
I 330
ND
ND
ND
ND
ND
ND
ND
ND
ND
18',1
2770
ND
ll9
ND
6620
1180
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
'100
100
100
100
100
1 000
100
100
100
100
100
200
100
200
100
100
200
100
100
'100
100
100
100
100
100
'100
100
100
100
100
100
100
100
'100
100
100
100
400
'100
400
'100
400
100
'100
'100
100
'100
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
05115117 20:42
05115117 20:42
051'15117 20:42
05115117 2O:42
05115117 2O:42
05115117 20:42
05115117 20:42
05115117 20:42
05115117 20:42
051151'17 20:42
051'15117 20:42
05115117 20:42
05115117 20:42
05115117 20:42
05115117 20:42
05115117 20:42
051151'17 2O:42
051'15117 20:42
051'15117 20:42
05115117 2042
05115117 2O:42
05115117 20:42
051151'17 20:42
05115117 20:42
05115117 20:42
051'15117 20:42
05115117 20:42
05115117 2O:42
05115117 20:42
O5115117 20:42
051151'17 20:42
051151'17 2O:42
05115117 20:42
051'15117 20:42
05115117 20:42
05115117 20:42
05115117 20:42
05115117 2O:42
051151'17 2O:42
05t15t17 20'42
05115117 20:42
05115117 20:42
O5115117 20:42
05115117 20.42
05115117 20:42
05115117 20:42
o5t15t17 20.42
71-43-2
1 0B-86-1
74-97-5
75-27-4
75-25-2
74-83-9
I 04-51 -B
1 35-98-8
9B-06-6
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
95-49-8
't06-43-4
96-'12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
1 06-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061-01-5
1 0061 -02-6
1 08-20-3
100-41-4
87-68-3
9B-82-8
75-O9-2
1634-O4-4
9 1 -20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 0511812017 02:45 P\A Page 6 of 35
Analytical
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]w.pacÊlabs.cgn
ANALYTICAL RESULTS
Project:
Pace Project No.:
Texaco Food Marl#2
92340251
Sample: MW-2
Parameters
Lab lD
Results
92340251002
Units
Collected: 05h0117 11:'19
Report Limit DF
Received: O5l1'll'17 12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2, 3-Trichloropropane
'1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
29200
ND
ND
ND
ND
ND
ND
ND
2580
ND
ND
10600
5670
'109
103
105
100
400
400
100
100
100
200
100
100
100
200
200
100
70-1 30
70-130
70-1 30
200
200
200
200
200
200
200
200
200
200
200
200
200
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
05!'15117 20:42
O5l'l5l'17 20:42
05115117 20:42
05115117 20:42
05115117 20:42
O5115117 20:42
05h5l17 20:42
05115117 20:42
051'15fi7 20:42
05115117 20:42
051'15117 2O:42
05115117 20:42
05h5l17 20:42
1 08-88-3
87-61 -6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
1 08-67-8
75-0't-4
179601-23-'l
95-47-6
Yo
o/o
Yo
200
200
200
05115117 20:42'17060-07-O
051 15117 2O:42 46O-00-4
051'15117 20:42 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDalet 05118120'17 02:45 PM Page 7 of 35
@
Pace Analytical Services, LLC
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
(704\875-9092
Analytical
www.pacÊlabs.mm
ANALYTICAL RESULTS
Project:
Pace Project No
Texaco Food Mai#2
9234025'l
Sample: MW-3
Parameters
Lab lD: 92340251003
Results Units
Collected: 0511O117 1'l:25
Report Limit DF
Received: 05111117 12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
B romod ich lorometh a ne
Bromoform
Bromomethane
n-Bulylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uorometha ne
1 ,1-Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
I ,3-Dichloropropane
2,2-Dichloropropane
1 ,1 -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Melhylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-fetachloroethane
1,1,2,2-Íelr achloroetha ne
Tetrachloroelhene
Analytical Method: SM 62008
27.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I 680
ND
128
ND
ND
844
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
12.5
12.5
12.5
12.5
125
125
12.5
12.5
12-5
12.5
12.5
25.0
'12 5
25.0
12.5
12.5
25.O
125
't2 5
125
12.5
12.5
125
125
12.5
125
12.5
12.5
12.5
12-5
125
125
12.5
12.5
12.5
12.5
12.5
500
125
500
12.5
50.0
12.5
12.5
12.5
125
12.5
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
05115117 20:59
05115117 20:59
05115117 20:59
05115117 20:59
051'l5l'17 20:59
O5l'l5l'17 20:59
O5115117 20:59
05115117 20:59
05115117 2059
O5115117 20:59
05115117 20:59
051',151',t7 20:59
O5115117 20:59
05115117 20:59
O5115117 2059
05115117 20:59
05115117 20:59
05115117 20:59
O5115117 20:59
O5l'15117 2O:59
05115117 2O:59
05h5117 2Ot59
05115117 2O:59
05h5117 20:59
O5115117 20:59
O5115117 20:59
05|l5l'17 2O:59
O5115117 2O:59
05115117 20:59
05h5h7 20:59
05115117 20i59
05115h7 20.59
05115117 20:59
O5l15l'17 20:59
O5|15117 2O:59
05115117 20:59
05115117 2O:59
05115117 20.59
05115117 20:59
05115117 20:59
O5115117 2O:59
05115117 2O:59
05115117 20:59
05115117 20:59
05115117 2O:59
05115h7 20:59
O5l'15117 2O:59
71-43-2
1 0B-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -8
1 35-98-8
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
1 56-59-2
I 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061-01-5
1 0061 -02-6
I 08-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-04-4
9'l-20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
wjthout the wrltten consent of Pace Analytical Seruices, LLCDate OSl18l2O'17 02:45 P\A Page B of 35
@
Pace Analytical Seruices, LLC
9800 Kincey Ave. Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
wwwpa^þlabs.cþn
ANALYTICAL RESULTS
Project:
Pace Project No.:
Texaco Food Marl#2
9234025',!
Sample: MW-3
Parameters
Lab lD
Results
92340251 003
Units
Collected: 051101'17 1'l:25
Report Limit DF
Received: O5l11l'17 12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 ,1 ,1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2, 3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogaúes
1,2-D¡chloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
I 630
ND
ND
ND
ND
ND
ND
ND
2470
ND
ND
6270
3240
108
103
106
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
12.5
50.0
50.0
12.5
12.5
't2.5
25.O
't2.5
12.5
12.5
25.0
25.0
12.5
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
05115117 20:59
O5115117 20:59
05115117 20:59
O5115117 20:59
05115117 20:59
05115117 20:59
051'15fi7 20:59
05115117 20:59
05115117 20:59
05115117 20:59
05115117 20:59
O5115117 20:59
05h5h7 20:59
'108-88-3
B7-61-6
120-82-',!
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
1 08-67-8
75-O1-4
179601-23-',!
95-47-6
Yo
o/o
Yo
70-1 30
70-1 30
70-1 30
O5l15l'17 20:59 17060-07-0
051'l5l'17 20:59 460-00-4
051'l5l 17 20:59 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Dale: O5l'1812017 02:45 PM Page 9 of 35
@
Pace Analytical Seryices, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacielabs ciþm
ANALYTICAL RESULTS
Project:
Pace Project No.:
Texaco Food Mart #2
9234025'l
Sample: MW-4
Parameters
Lab lD: 92340251004
Results Units
Collected: 05110117 11:35
Report Limit DF
Received: O5111117 12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
se c- B uly I be nze ne
tert-Butylbenzene
Carbon telrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromelhane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
D¡bromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
I ,2-Dichlorobenzene
1 ,3-D¡chlorobenzene
1 ,4-Dichlorobenzene
D ich lorod ifl uorome tha ne
I ,'l -Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,1 -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,'1,1,2-fet achloroethane
1,1,2,2-fet achloroeth a ne
Tetrachloroethene
Analytical Method: SM 62008
3.6
ND
ND
1.2
ND
ND
ND
ND
ND
ND
ND
ND
35.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
213
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugi L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
10
1.0
1.0
1.0
1.0
100
10
10
1.0
1.0
1.0
2.0
1.0
20
1.0
1.0
2.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
10
10
'1.0
1.0
1.0
1.0
1.0
10
10
40
1.0
4.O
'1.0
40
1.0
10
1.0
1.0
1.0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
z
2
2
05116117 2O:12
051'16117 2O:'12
051'16117 2O:12
051'16117 20i12
O5116117 20:12
O5h6r17 20i12
O5116117 2O:12
05116117 20:12
05116117 20:'12
051'16117 2O:'12
05116117 2O:12
O5h6l17 20:12
O5116117 20:12
O5116117 20:12
05116117 20:12
05116117 20:12
05116117 20:12
05116h7 20:12
051'16117 2O:12
O5116117 20:12
05116117 2O:12
05116117 20:12
05116117 20:12
O5116117 2O:12
05116117 2O:12
05116117 2O:12
O5116117 20:12
05116117 20:12
O'h6l'17 20:12
05116117 20:12
05116117 20:12
05116117 20:12
05116117 2O:12
05116h7 20:12
05116117 20:12
O5116117 2012
o5t16t17 20.12
05116117 20:12
O5116117 20:12
05116117 2O:12
05116117 2O:'12
05t16t17 20.12
05116117 20:12
O5116117 20:12
o5t16t't7 20.12
05116117 20:12
05116117 2O:12
71-43-2
1 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
I 04-51 -B
1 35-98-8
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
I 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-B
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061-01 -5
1 0061-02-6
1 0B-20-3
100-41-4
B7-68-3
98-82-8
75-09-2
1634-04-4
91 -20-3
'103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
L1
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, LLCDate: 05/1 8/2017 02:45 PM Page 10 of 35
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)87s-eos2
Analytical
www.pacêlabs crm
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food Mar.#2
9234025'l
Sample: MW-4
Parameters
Lab lD
Results
92340251 004
Un¡ts
Collected: 0511O117 11:35
Report L¡mit DF
Received: 05111117'12:37 Matrix:Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Tr¡chlorobenzene
1 ,1 ,1 -Tr¡chloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2, 3-Trichloropropane
'1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
ND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
3.0 ug/L
ND ug/L
ND ug/L
6.5 ug/L
2.8 ug/L
1.0
4.0
4.O
1.0
1.0
1.0
2.0
1.0
1.0
't.0
2.0
2.0
1.0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
05116117 20:12
05116117 20:12
05116117 20Í12
051'16117 20:12
05116117 20:12
05116117 2O:12
05116117 20:12
05116117 20:12
O5116117 20:12
05116117 20Í12
O5l16l'17 20:12
05116117 20:12
O5l16l'17 20:'12
I 0B-BB-3
87-61 -6
120-82-'l
71-55-6
79-00-5
79-01-6
75-69-4
96-l 8-4
95-63-6
1 08-67-B
75-01-4
1 79601 -23-1
95-47-6
105
99
105
70-130
70-1 30
70-130
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in tull,
without the wr¡tten consent of Pace Analytical Services, LLC.
05116117 2O:12'17060-07-0
051161'17 20:12 460-0O-4
051 161 17 2O:12 2O37 -26-5
%
%
Dale: 05h 812017 02:45 PM Page 11 of35
@
Pace Analytical Services, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
www.pacÊlabs con
ANALYTICAL RESULTS
Project:
Pace Project No.:
Texaco Food Maft#2
92340251
Sample: MW-S Lab lD: 92340251005
Results Units
Collected: 05l1Ol'17 10:58
Report Lim¡t DF
Received: 05111117 12:37 Matrix: Water
Prepared Analyzed CAS No.Parameters Qual
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uorometha ne
I ,1-Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
c¡s-1,2-Dichloroethene
trans-1,2-Dichloroethene
I ,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1 ,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-IeTr achloroethane
Tetrachloroethene
Analytical Method: SM 62008
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
0.50
050
0.50
0.50
5.0
0.50
0.50
0.50
0.50
050
1.0
050
1.0
0.50
0.50
1.0
0.50
050
050
0.50
0.50
0.50
0.50
0.50
0.50
0.50
050
0.50
050
050
0.50
0.50
0.50
050
0.50
0.50
20
050
20
0.50
2.0
050
0.50
0.50
050
0.50
05115117 18:59
05115117 18"59
05/15/17 18:59
05115117 18:59
05/15/17 1B:59
05115117'lB:59
05i15/17 1B:59
05115117 18:59
051'15117 18:59
05115117 18:59
05/15/17 18:59
05115117 18:59
05/15/17 18:59
05115117 18:59
05h5117 18:59
05115117 '18:59
05115117 18:59
05/15/17 1B:59
O5115117 18:59
O5115117 18:59
05115h7 18:59
05115117 18:59
05t15t17't8"59
05/15i17 18:59
05/15/17 18:59
05115117 18:59
051'15117 1859
051'l5l'17 18.59
05/15117 18:59
05|15117 18:59
O5115117 18:59
O5115117 18:59
05115117 18:59
05115117 18:59
05/15/17 18:59
05115117 1859
05115117 18:59
051151'17 18:59
O5l'15117 18:59
05/15/17 18:59
O5115117 18:59
05115117 18.59
05115117 18.55
05115117 18:59
05/15/17 1B:59
05115117 18:59
051151'17 18:59
71-43-2
'108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51-B
I 35-98-8
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96- 1 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-'l
1 06-46-7
75-71-B
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061-01-5
'10061-02-6
1 0B-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-O4-4
91 -20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0511812017 O2:45 PM Page 12 of 35
@
Pace Analytical Serv¡ces, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
www.paælabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food Marl#2
92340251
Sample: MW-S
Parameters
Lab lD
Results
92340251 005
Units
Collected: 05/10/1710:58 Received: 05111117 12:37 Matrix: Water
Report Limit DF Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 ,1 ,1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
'1, 2, 3-Trichlorop ropane
1,2,4-Trimethylbenzene
1,3,S-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
2.0
2-0
0.50
0.50
0.50
1.0
0.50
0.50
0.50
1.0
1.0
0.50
05115117 18:59
05115h7 18:59
05/'15/1718:59
05115117 18:59
05115117'lB:59
05115117 18:59
05/15/17 1B:59
05115117 18:59
051'15117 1859
05115h7 18:59
05/15/17 18:59
05/15/17 18:59
05/15/17 18:59
1 0B-88-3
87-61-6
120-82-'l
71-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
95-63-6
I 08-67-8
75-0't-4
179601-23-1
95-47-6
1'10
98
107
70-1 30
70-1 30
70-1 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
051151'17 l8:59 17060-07-0
05l'15117 1B:59 460-00-4
05115117 18:59 2037-26-5
o/o
To
o/o
'l
'l
1
Dale: OSl18l2O17 02:45 PM Page 13 of35
@
Pace Analytical Serv¡ces, LLC
9800 K¡ncey Ave Su¡te '100
Huntersville, NC 28078
[phone]
Analytical
ww.pacÊlabs.con
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food Mart #2
92340251
Sample: T-l Lab lD: 92340251006
Results Units
Collected: 05110117 11:06
Report Lim¡t DF
Received: O5111117 12:37 Matrix: Water
Prepared Analyzed CAS No.Parameters Qual
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichlorometha ne
Bromoform
Bromomethane
n-Butylbenzene
sec-BuÇlbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
D¡chlorodifl uoromethane
'l ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-'1,2-Dichloroethene
trans-'1,2-Dichloroethene
1 ,2-Dichloropropane
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,1 -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Di¡sopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyllert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-ïeî achloroeth a ne
Tetrachloroethene
Analytical Method: SM 62008
1',t7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
28.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.7
15.3
ND
1.7
ND
ND
6.8
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
0.50
0.50
0.50
0.50
5.0
050
050
050
050
0.50
1.0
0.50
1.0
0.50
0.50
10
0.50
0.50
0.50
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
050
050
050
050
0.50
0.50
050
0.50
20
050
2.0
0.50
2.O
0.50
0.50
0.50
050
0.50
05115117 21:51
05115117 21:51
O5115117 21:51
05t15t17 21 .51
O5115117 21:51
05115117 21:51
O5115117 21:51
05115117 21:51
05115117 21:51
05115117 2'l:51
051'15117 21:51
05115117 21:51
O5l'15117 21:51
05115117 21:51
051151'17 21:5'l
05115117 21:5'l
05115117 21:51
051'15117 2'l:51
051't5t17 2',t:51
05115117 21:51
051151'17 21:5'l
051151'17 21:51
05115117 21:51
05115117 21:5'l
OSl15h7 21:51
051'15117 21:51
051'15117 21i51
051'15117 21:51
051151'17 21:51
O5115117 21:51
05115117 21:51
05115117 21:51
OSl15h7 21:51
05115117 21:51
051'15117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21 .51
05115117 21:51
05115117 21:51
05115117 21:51
71-43-2
108-86-'l
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -8
1 35-98-B
9B-06-6
56-23-5
I 0B-90-7
75-00-3
67-66-3
74-87-3
95-49-8
1 06-43-4
96-1 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
54',t-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
7B-87-5
142-28-9
594-20-7
563-58-6
1 0061-01-5
1006'1-02-6
1 08-20-3
100-41-4
87-68-3
9B-82-8
75-09-2
1634-04-4
91-20-3
I 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLCDate: 05/1 8/2017 02:45 PM Page 14 of35
@
Pace Analyt¡cal Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.con
ANALYTICAL RESULTS
Projecl:
Pace Project No.
Texaco Food Mart #2
92340251
Sample: T-l Lab lD
Results
92340251 006
Units
Collected: 051'10117 11 06
Report Limit DF
Received: 0511'1117 12:37 Matrix: Water
Prepared Analyzed CAS No.Parameters Qual
62008 MSV
ïoluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 ,1 , 1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
'1,2, 3-Tr¡chloropropane
1,2,4-Trimethylbenzene
1,3,S-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
0.53
ND
ND
ND
ND
ND
ND
ND
8.8
ND
ND
20.6
9.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ugiL
ug/L
0.50
2.0
2.O
0.50
0.50
0.50
1.0
0.50
0.50
0.50
1.0
1.0
0.50
05115117 21:5'l
O5115117 21:51
051'15117 21:51
O5l'15117 21:51
O5l'15117 21:51
051151'17 2'l:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
05115117 21:51
051'15117 2'l:51
oít',t5t',t7 2',t:51
1 08-88-3
B7-61-6
120-82-1
71-55-6
79-00-5
79-01 -6
75-69-4
96-1 8-4
95-63-6
1 08-67-8
75-01-4
't79601-23-1
95-47-6
1',11
100
106
70-1 30
70-1 30
70-1 30
%
Yo
%
1
,|
1
O5l15l'17 21:51'17060-07-0
051151'17 2'l:51 460-00-4
05115|17 21:51 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: O511812017 O2:45 PM Page 15 of35
o
Pace Analytical Sery¡ces, LLC
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www-pacelabs com
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food Mad.#z
92340251
Sample: Trip Blank
Parameters
Lab lD: 92340251007
Results Units
Collected: 05/10/17 00:00
Report Limit DF
Received: 05111117 12:37 Matr¡x: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tertButylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
'1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
'1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorod ifl uoromethane
1 ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
c¡s-1,2-D¡chloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-fetachloroelhane
1,1,2,2-Telt achloroethane
Tetrachloroethene
Analytical Method: SM 62008
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
050
0.50
050
0.50
5.0
0.50
0.50
0.50
050
0.50
10
0.50
1.0
0.50
050
10
0.50
0.50
0.50
0.50
0.50
050
0.50
050
050
0.50
0.50
0.50
0.50
0.50
050
050
0.50
0.50
0.50
0.50
2.0
050
2.0
0.50
20
0.50
050
050
0.50
050
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
051'13117 11:54
O5l'13117 1'l:54
051'13117 1'l:54
05113117 11:54
05113117 11:54
051131'17 11:54
05/13117 11:54
05113117 11:54
O5l'13117 1'l:54
05113117 11:54
05113117 1'l:54
05113117 11:54
05113117 1'l:54
05113117 11:54
05113117 11:54
05113117 11i54
05113117 11:54
051'13117 11:54
o\t't3t17 11'.54
O5113117 11:54
O5113117 11:54
05113117'11:54
05h3117 11:54
05113117 11 54
05t13t17 11.54
05113117 11:54
O5113117 11:54
O5113117 11:54
05113117 11:54
05113117 11:54
O5113117 11:54
05113117'11:54
05t13t't7 11 .54
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
05113117 11:54
051131'17 11:54
05113117 11:54
71-43-2
108-86-'l
74-97-5
75-27-4
75-25-2
74-83-9
I 04-51 -8
1 35-98-8
9B-06-6
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-B
124-48-1
1 06-93-4
74-95-3
95-50-l
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
I 56-59-2
'156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1006'1-01-5
1 0061 -02-6
.108-20-3
100-41-4
87-68-3
9B-82-8
75-09-2
1634-O4-4
91-20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: O5h812017 02145 Pl,A Page 16 of 35
@
Pace Analytical Seruices, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
[phone]
Analytical
www.pac,-labs.ctn
ANALYTICAL RESULTS
Project:
Pace Project No.
Texaco Food îilañ#2
9234025'l
Sample: Trip Blank
Paramelers
Lab lD: 92340251007
Results Units
Collected: 05/10/17 00:00
Report Limit DF
Received: 051111'17'12:37 Matrix: Water
Prepared Analyzed CAS No.Qual
6200B MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 ,1 , 1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
'1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,s-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Melhod: SM 62008
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
To
o/o
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
050
2.0
2.0
0.50
0.50
0.50
1.0
0.50
0.50
0.50
1.0
1.0
0.50
05113117 11:54
05113117 11:54
05t13t17 11:54
05113117 1'l:54
05113117 1'l:54
05113117 11:54
05113117 11:54
051'13117'11:54
051131'17'11:54
05113117 11:54
05113117 11:54
O5113117 1'l:54
05113117 1'l:54
'108-88-3
B7-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
1 08-67-8
75-O1-4
179601-23-1
95-47-6
't07
98
105
70-1 30
70-l 30
70-1 30
05l'13117 11:54 17060-O7-O
051'13117 11:54 460-00-4
OSl13l17 11:54 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLC.Date: 05/18/2017 02:45 PM Page '17 of 35
@
Pace Analytical Services, LLC
9800 KinceyAve Su¡te 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacìêlabs ctm
QUALITY CONTROL DATA
Project:
Pace Project No.:
Texaco Food Mart #2
92340251
QC Batch: 360464
QC Batch Method: SM 62008
AssocialedLabSamples: 92340251007
Analysis Method:
Analysis Description:
SM 62008
62008 MSV
METHOD BLANK: 19992'14
AssociatedLabSamples: 92340251007
Parameter
Matrix: Water
Units
Blank
Result
Reporting
Limit Analyzed Qualifiers
1 ,1 ,1 ,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-lelrachloroethane
1, 1,2-Trichloroethane
1 ,1-D¡chloroethane
1 ,1 -Dichloroethene
1 ,1 -Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,S-Trimethylbenzene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromod¡chloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
050
2.O
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
0.50
050
0.50
0.50
5.0
0.50
0.50
10
0.50
10
0.50
0.50
050
0.50
050
0.50
0.50
05113117 11:36
051'13117 11:36
05113117 11:36
05113117 11:36
O5113117 11:36
O5l13h7 11:36
051131'17 11:36
051131'17 '11:36
051'13117 11:36
O5113117 '11:36
05113117 1'l:36
O5113117 11:36
05113117 11:36
05113117 11:36
05h3h7 1136
05113117 '11:36
051131'17'11:36
05113117 11:36
051'l3l'17 11:36
05113117 1'l:36
O5113117 11:36
05113117 11:36
05113117 11:36
05113117 11:36
05113117 1136
05113117 11:36
O5113117 11:36
05113117 11:36
O5113117 11:36
051'13fi7 11:36
O5113117 '11:36
05113117 1'l:36
05113117 11:36
05113117 11:36
05113117 1136
05113117 11:36
05113117 '11:36
05113117 '11:36
051't3117 11:36
O5113117 11:36
05/13/17 11:36
Results presented on th¡s page are ¡n the units ind¡cated by the "Un¡ts" column except where an alternate unlt ls presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not Þe reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, LLC.Dale: 0511812017 02:45 PM Page 18 of35
@
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacÊlabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food Marl#2
92340251
METHOD BLANK: 1999214
AssociatedLabSamples: 92340251007
Parameter
Matrix: Water
Units
Blank
Result
Report¡ng
Limit Analyzed Qualifiers
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chlor¡de
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans- 1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
Yo
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
105
9B
106
2.0
0.50
1.0
0.50
2.0
0.50
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0
1.0
70-1 30
70-130
70-1 30
05113117 11:36
05113117 11:36
05113117 11:36
05113117 11:36
O5l'13117 11:36
O5113117 11:36
05113117 1'l:36
05113117 1'l:36
05113117 11:36
05113117 11:36
05|13117 11:36
O5l'13117 11:36
05/13117 11:36
O5l13l'17 11:36
05/13/17 11:36
O5113117 1'l:36
O5113117 1'l:36
O5113117 11:36
05113117 11:36
O5113117 11:36
O5/13117 11:36
05l'13117 11:36
LABORATORY CONTROL SAMPLE:
Parameter
I 99921 5
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1 ,'l ,1 ,2-Telrachloroethane
1 ,1 ,1 -Trichloroethane
1,1,2,2-ferachloroethane
.1, 1,2-Trichloroethane
1 ,1-Dichloroethane
1 ,1-Dichloroethene
1 ,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
-l ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,S-Trimelhylbenzene
1 ,3-Dichlorobenzene
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
63.9
56.7
52.5
55.5
52.5
535
55.6
53.0
52.4
53.0
52-8
59.7
576
525
525
54.2
53.7
54.0
128
113
105
111
105
107
1't1
106
105
106
106
119
115
'105
105
108
107
108
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
Results presented on th¡s page are ¡n the un¡ts ¡nd¡cated by the "Unlts" column except where an alternate un¡t ¡s presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
w¡thout the wr¡tten consent of Pace Analytical Serv¡ces, LLCDate: 05/1 8/20'1 7 02:45 PM Page 19 of 35
Analytical
Pace Analytical Services, LLC
9800 KinceyAve. Su¡te '100
Huntersv¡lle, NC 28078
[phone]www.pacelaß cþn
QUALITY CONTROL DATA
Project:
Pace Project No :
Texaco Food Mart #2
92340251
LABORATORYCONTROLSAMPLE: 1999215
Parameter Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
D¡bromomethane
D ich lorod iflu orometh a ne
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Melhyl{ert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-'1,2-Dichloroethene
lrans-1,3-Dichloropropene
Tr¡chloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugi L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
Yo
o/"
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
55.4
545
659
54.7
545
EE 1
54.2
52.6
60.3
50.9
538
66.2
52.7
50.6
543
52.9
537
59.8
64.7
53.4
58.5
53.1
548
567
52.0
105
56.6
54.0
56.0
55.8
55.0
52.1
53.5
52.9
47.1
51 0
52.8
525
64.1
56.1
56.1
49.5
111
109
132
109
109
1't1
108
105
't21
102
108
132
105
10'l
109
106
107
120
129
107
117
106
110
113
104
105
113
108
112
112
110
104
107
'106
94
102
106
105
128
112
112
99
109
96
100
60-140
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-'t40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-140
70-'130
70-1 30
70-1 30
Results presented on thls page are ¡n the un¡ts ¡ndicated by the "Un¡ts" column except where an alternate unlt ¡s presented to the rlght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, LLCDale: 05h812017 02:45 PM Page 20 of 35
@
Pace Analytical Serv¡ces, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
(7O4t875-9092
Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.:
Texaco Food Marl#2
9234025',!
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1999216
Parameter
92340299003Un¡ts Result
MS
Spike
Conc
MSD
Spike
Conc.
1999217
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
1 ,1 ,1 ,2-Tetrachloroethane
'1 , 1 ,1-Trichloroethane
1,1,2,2-Tel¡ achloroethane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,'1 -Dichloroelhene
1 ,.1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1, 2,4-Trichlorobenzene
1, 2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,S-Trimethylbenzene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropane
'l ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
B rom od ich lorometh a ne
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
D ibro mochlo rometha ne
Dibromomethane
Dichlorod ifl uoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-.1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl ether
Methylene Chloride
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
548
ND
ND
ND
204
ND
ND
ND
ND
ND
ND
ND
ND
885
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
56900
ND
ND
ND
ND
ND
214
ND
ND
ND
ND
ND
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
.16000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
1 6000
8000
8000
9440
9340
8330
8060
8880
9'160
9360
7900
8270
7750
8640
8460
8290
8220
8600
8640
8320
8280
8430
8470
9340
8400
8270
9850
8350
9060
9440
81 80
8380
't 0800
8420
8780
BB90
9500
61 900
8770
9040
8280
1 0500
8450
9060
8380
8640
17100
891 0
8300
9370
9470
8290
8270
8820
9500
9360
8460
81 60
8270
8710
8970
8270
8200
8660
8760
8300
8450
8220
8390
9670
8600
8390
9840
841 0
91 00
9540
7890
8500
1 0800
8330
8880
8990
931 0
61 400
9000
9350
8430
1 0400
8630
9000
8780
8750
17400
8870
84',tO
118
117
104
101
111
115
117
oa
103
97
'101
106
104
103
105
108
104
103
105
'106
117
105
103
112
104
113
118
102
105
135
105
110
111
119
63
110
113
103
132
106
111
105
108
105
1't1
104
117
118
104
103
1'10
119
117
'106
102
103
102
112
103
'103
106
110
104
'106
103
'105
121
108
105
112
105
114
119
99
106
135
104
111
112
116
56
112
117
105
129
108
110
110
109
107
111
105
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60- 140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
1
1
1
3
1
4
0
7
1
6
1
b
0
0
1
1
0
2
2
,|
3
2
1
0
1
0
I
4
1
0
1
1
1
2
1Vì
3
3
2
2
2
I
5
1
1
0
1
Results presented on this page are in the units ¡ndicated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the r¡ght of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDate: 05/18/2017 02:45 PM Page 21 of 35
@
Pace Analytical Seru¡ces, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.:
Texaco Food Mart#2
9234025'l
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1999216
Parameter
92340299003
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
19992't7
Result
MSD
Resull
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans- 1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ND
ND
926
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
lo
Yo
o/o
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8000
8580
8510
9520
8790
8380
861 0
7550
7860
8710
BBlO
8670
8970
9870
8850
8500
8680
9270
8780
8430
8500
7650
7860
8980
9050
91 60
9320
9920
8890
107
106
107
107
105
't 08
94
9B
107
110
108
't12
123
108
110
97
101
106
108
104
107
105
106
96
98
110
113
115
117
't24
108
11',!
100
'101
60-140
60-140
60-140
60-140
60-140
ô0-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
70-'130
70-1 30
70-1 30
1
2
3
0
1
1
1
0
3
3
6
4
'l
0
Results presented on this page are ¡n the un¡ts ind¡cated by the "Un¡ts" column except where an alternate unit ¡s presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDale: 051 1 812017 O2:45 PM Page 22 of 35
rÐ
Pace Analytical Services, LLC
9800 Kincey Ave Suite '100
Huntersviìle, NC 28078
(7 04)87 s-9O92
Analytical
w.pacelabs com
QUALITY CONTROL DATA
Project:
Pace Project No
Texaco Food Mart #2
92340251
QC Batch: 360588 Analysis Method: SM 62008
QC Batch Method: SM 62008 Analysis Description: 62008 MSV
Associated Lab Samples: 923402510O2,92340251003, 92340251005,92340251006
METHOD BLANK: 1999890 Matrix: Waler
Associated Lab Samples: 92340251002,92340251003, 923402510O5,92340251006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1 , 1 ,1 ,2-Tetrachloroethane
1 ,I ,'l -Trichloroethane
1,1,2,2-f et achlo roethane
'1, 1,2-Trichloroelhane
'l ,1-Dichloroethane
1 ,'l-Dichloroethene
1 ,1 -Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
'1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,S-Trimethylbenzene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochlorometha ne
Dibromomethane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
050
0.50
050
050
0.50
0.50
0.50
2-O
050
2.0
050
1.0
0.50
0.50
050
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
050
050
050
0.50
0.50
5.0
050
0.50
1.0
050
10
0.50
050
050
0.50
050
0.50
0.50
05115117 14:57
05115h7 '14:57
05h5117 14:57
05115117 14:57
05115117 14:57
O5115117 14:57
051'15117 14:57
O5115117 14:57
05115117'14:57
05115117 14:57
05115117 14:57
05115117 14:57
05t15t17 14.57
05115117 14:57
O5115117 14:57
05115117 14:57
05115117 14:57
05115117 14:57
05h5117 14i57
O5115117 14:57
O5115117 14:57
05115117 14:57
O5115117 14:57
05115117'14:57
O5h5l17 14t57
05h5h7 14:57
05115117 14:57
05115117 14:57
O5115117 14:57
05115117 14:57
O5115117 14:57
05115117 14:57
05h5117 14:57
05115117 14:57
05115117 14"57
O5115117 14:57
O5115117'14:57
05115117 14:57
05115117 14:57
05115117 14:57
05115117 14.57
Results presented on thls page are ¡n the un¡ts ¡nd¡cated by the "Unlts" column except where an alternate un¡t ¡s presented to the r¡ght ot the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDale: 0511812017 02:45 PM Page 23 of 35
@
Pace Analyt¡cal Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pacalabs.con
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food Marl#2
92340251
METHOD BLANK: 1999890 Matr¡x: Water
Associated Lab Samples: 92340251002, 92340251003, 92340251O05,923402S1 006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifìers
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroelhene
Toluene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Yo
Yo
10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
't12
105
106
2.0
0.50
1.0
0.50
2.0
0.50
050
20
050
0.50
0.50
0.50
0.50
0.50
0.50
0.50
050
1.0
10
70-1 30
70-1 30
70-1 30
O5115117 14:57
05115117 14:57
OShíh7'14:57
05115117 14:57
051'15117 14:57
05115h7 14:57
05115117 14:57
O5115117 14:57
05115117 14:57
O5115117 '14:57
O5115117 '14:57
O5115117'14:57
05115117'14:57
05115117'14:57
051'15117 14:57
05115117 14:57
O5115117 14:57
05115117 14:57
O5115117 14:57
05115117 14:57
O5l15l'17 '14:57
051151',17 ',t4:57
LABORATORY CONTROL SAMPLE
Parameter
1 999891
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1,1,1,2-Telr achloroeth ane
1, 1, 1 -Trichloroelhane
1,1,2,2-Telrachloroethane
1, 1,2-Trichloroethane
'1 ,1-Dichloroethane
1 ,1-Dichloroethene
1 ,1 -Dichloropropene
1,2, 3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,s-Trimethylbenzene
1,3-Dichlorobenzene
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
59.4
56.3
50.4
5'l 2
52.2
55.2
55.5
49.0
50.3
48.2
489
55.9
54 I
47.6
51.5
51.2
48-2
49.2
119
113
101
102
't04
110
111
9B
101
96
9B
112
108
95
103
102
96
98
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
Results presented on th¡s page are ¡n the units ¡ndicated by the "Unlts" column except where an alternate unlt ls presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
ïh¡s report shall nol be reproduced, except in full,
w¡thout the wr¡ften consent of Pace Analyt¡cal Services, LLCDate: 0511812O17 02:45 PM Page 24 of 35
@
Pace Analyt¡cal Seruices, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
ww.pacelabs æn
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food May'.#2
92340251
LABORATORY CONTROL SAMPLE:
Parameter
I 999891
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
D ich lorod iflu oromelha ne
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl elher
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroelhene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugi L
ug/L
Yo
%
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
s',t.7
50.5
64.0
48.6
48.9
53.2
48.2
52-8
56.9
51.5
58.6
64.5
49.2
50.3
51.9
57 -1
52.1
59.'1
62.O
50.5
67.0
53.1
5'l 5
52.9
502
99.7
55.8
54.5
51.6
49.4
495
50.4
49.7
50.7
43.6
49.3
52-3
52.5
61 2
54.0
56.9
51.2
'103
101
128
97
98
106
96
106
114
103
117
't29
98
101
104
114
104
118
124
101
'134
106
103
106
100
100
't't2
109
103
99
99
101
99
101
87
99
105
105
122
108
114
102
112
100
102
60-1 40
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-'t40
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-'t40
60-140
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-'140
60-140
60-140
60-'140
60-140
60-140
60-1 40
60-140
70-1 30
70-'130
70-1 30
Results presented on this page are ¡n the un¡ts ¡ndlcated by the "un¡ts" column except where an alternate unit ¡s presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDale: O5h8l20'17 O2:45 PM Page 25 of 35
o
Pace Analytical Serv¡ces, LLG
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
[phone]
Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food Marl#2
92340251
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1999929
Parameter
92340299021Units Result
MS
Spike
Conc.
MSD
Spike
Conc
I 999930
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
1 ,1 ,1 ,2-Telrachloroethane
1 ,1 ,1 -Trichloroethane
1,1,2,2-fetachloroelhane
1, 1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
1 ,1 -Dichloropropene
'1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,5-Trimethylbenzene
1 ,3-Dichlorobenzene
'1 ,3-Dichloropropane
'l ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl ether
Methylene Chloride
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
232
24.3
21.3
21.2
23.0
25-1
24.0
198
21.2
19 6
21.8
20.5
21.7
20.8
22.0
222
21 3
21.4
22.2
22.2
25.0
21.7
21.3
23.3
21.4
23.9
238
20.2
17.3
27.1
21.7
23.5
23.2
25.7
233
22.5
24 1
21.3
30.3
22.O
23.1
21 8
22.2
449
23.0
22.2
245
239
21.6
2',t.o
23.O
23-8
24.0
208
21.8
21 I
222
227
22.7
22.O
22.1
22.6
21.9
22.3
22.6
22.4
249
224
223
23.3
22.4
22.9
25.4
20-8
196
27.8
21 I
22.4
230
255
23.3
23.1
24.5
21.7
29.4
22.0
23.4
232
227
454
22.8
21.7
116
121
106
106
115
't25
120
99
106
9B
109
103
108
104
'110
'11'l
106
107
1't1
111
125
109
107
117
107
'120
119
101
86
135
109
't17
116
128
117
113
't20
'106
151
110
116
109
111
112
115
111
123
119
108
105
115
119
120
'104
109
106
111
113
113
110
'111
113
1'to
112
1'13
't12
125
112
111
117
112
114
127
104
9B
139
110
112
1'15
127
117
116
123
109
147
110
't17
116
113
113
114
109
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
o
2
2
1
0
t
0
Ã
J
7
2
10
5
5
1
2
J
4
2
1
0
J
4
0
5
4
b
3
13
J
1
5
1
1
0
3
2
2
3M1
0
1
o
2
1
1
2
Results presented on thís page are in the un¡ts ¡ndicated by the "Units" column except where an alternate unit is presented to the r¡ght ol the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except ¡n full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLCDale'- OSl18l2O17 02'.45 Pl\A Page 26 of 35
o
Pace Analytical Services, LLC
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
(704')875-9092
Analytical
ww.pacelabs.æm
QUALITY CONTROL DATA
Project:
Pace Project No.:
Texaco Food Marl#2
92340251
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1999929
Parameter
92340299021Units Result
MS
Spike
Conc
MSD
Spike
Conc.
1 999930
Result
MSD
Result
MS
% Rec
MSD
% Rec
MS % Rec
Limits RPD Qual
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
22.3
22.2
20.9
22.7
22.0
21.9
19.5
206
23.7
23.6
21.7
23.7
26.5
23.8
23.3
229
21.5
23.O
22.9
22.1
19.9
21.3
24.0
23.3
230
24 1
25.9
22.7
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
To
Yo
%
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
11'l
11'l
105
113
110
109
98
103
118
118
109
118
132
119
11'l
102
103
117
115
107
115
114
11'l
100
107
120
116
115
120
129
114
107
101
102
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'t40
60-140
60-'140
60-140
60-140
60-140
70-1 30
70-1 30
70-'t 30
4
3
3
1
4
1
2
4
2
1
6
2
2
5
Results presented on thls page are in the un¡ts ¡ndlcated by the "Units" column except where an alternate unit ¡s presented to the r¡ght ot the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Services, LLCDaIe'. 0511812017 02:45 PM Page27 oÍ35
@
Pace Analyt¡cal Seruices, LLC
9800 K¡nceyAve Su¡te 100
Huntersv¡lle, NC 28078
(704)87 5-9092
Analytical
www.pacelabs com
QUALITY CONTROL DATA
Project:
Pace Project No :
Texaco Food Mart #2
9234025'l
QC Batch: 360762
QC Batch Method: SM 62008
Associated Lab Samples: 92340251001, 92340251004
Analysis Method:
Analysis Description:
SM 62008
62008 MSV
METHOD BLANK: 2000900
Associated Lab Samples
Parameter
923 4025 1 00 1, 9234025 1 004
Units
Matrix: Water
Blank
Result
Reporting
Lim¡t Analyzed Qualifìers
'l ,1 ,1 ,2-Tetrachloroethane
1 ,1 ,I -Trichloroethane
1,1,2,2-felr achlo roeth a n e
1,.1,2-Trichloroethane
1 ,1 -Dichloroethane
1 ,1 -Dichloroethene
I ,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
'1,2,4-Tr¡chlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
'1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,5-Trimethylbenzene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropane
I ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichlorometha ne
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-'1,2-Dichloroethene
cis-'1,3-Dichloropropene
D ibromochloromethane
Dibromomethane
D ich lorod ifl uorom eth a ne
Diisopropyl ether
Ethylbenzene
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
0.50
0.50
0.50
0.50
0.50
0.50
20
0.50
20
0.50
10
0.50
0.50
050
050
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
050
050
050
050
50
0.50
0.50
1.0
050
1.0
050
050
0.50
050
0.50
050
0.50
051161'17 16:28
05116117 16:28
05116|17 1628
05116117 16:28
O5116117 16:28
O5116117'16:28
05116117 16:28
05116117 16:28
05116117 16:28
05116117 16:28
05h6117 16:28
051161'17 16:28
05116117 16.28
05116117 16:28
O5116117 16:28
O5l'16117 16:28
O5l'16117 16:28
05116117 16:28
05116117 1628
051161'17 16:28
05116117 16:28
05116117 16:28
O5116117 16:28
05116117 16:28
O5116117 16:28
05116117'16:28
O5116117 16:28
05116117 16:28
05116117 16:28
05116117 16:28
051161'17 16:28
05116117 16:28
05116117 16:28
05116t17 16.28
O5116117 16:28
O5116117 16:28
o5t16t17 16'.28
05t16t17 16.28
05116117 16:28
05116117 16:28
O5h6l17 1628
Results presented on thls page are ln the units ¡nd¡cated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, LLCDate'. O511812017 02:45 Pl\A Page 28 of 35
@
Pace Analytical Seruices, LLC
9800 Kincey Ave Suite .100
Huntersville, NC 28078
(7O4r875-9092
Analytical
www.pacÊlaæ.con
QUALITY CONTROL DATA
Project:
Pace Project No :
Texaco Food Maft#2
92340251
METHOD BLANK: 2000900
Associated Lab Samples: 92340251 0O1, 92340251004
Parameter Units
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Reporting
Limit Analyzed Qualifiers
Matrix: Water
Blank
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
103
100
107
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
Yo
Yo
20
0.50
1.0
0.50
2.0
0.50
0.50
20
0.50
050
050
050
0.50
0.50
0.50
0.50
050
1.0
1.0
70-1 30
70-1 30
70-1 30
05116117 16:28
O5116l'17 16:28
05116|17 1628
05116117 16:28
O5l16l'17 16:28
05116117 16:28
05116117 16:28
05116117 16:28
051'16117 16:28
051'16117 16:28
051161'17 16:28
O5116l'17 16:28
O5116117 16:28
05116117 16:28
05116117 16:28
05116117 16:28
05116117 16:28
051'16117 16:28
05116117 16:28
051'16117 16:28
051161'17 16:28
O5116117 16:28
LABORATORY CONTROL SAMPLE:
Parameter
2000901
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1 ,1 ,1 ,2-Tetrachloroelhane
1 , 1 ,1-Trichloroethane
1,'1,2,2-fet achloroethane
1 ,I ,2-Trichloroetha ne
1 ,1 -Dichloroethane
'I ,1 -D¡chloroethene
1 ,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
'1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dlchloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1 .3-Dichlorobenzene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
62 1
56.4
52 1
536
526
55'1
56.1
51.4
53.0
50.1
51.6
587
559
506
52.4
529
5'1.0
522
124
'1.t 3
104
107
'105
110
112
103
106
100
103
117
112
10'l
105
106
102
104
60-'140
60-1 40
60-'140
60-140
60-'140
60-1 40
60-140
60-140
60-'140
60- 1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-140
60-140
60-140
60-140
Results presented on th¡s page are in the un¡ts ¡ndicated by the "Units" column except where an alternate unit ¡s presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLCDate: 051 1812017 02145 PM Page 29 of 35
@
Pace Analytical Services, LLC
9800 Kincey Ave Sulte '100
Huntersv¡lle, NC 28078
[phone]
Analytical
w.pacelabs.com
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food Marl#2
9234025'l
LABORATORY CONTROL SAMPLE:
Parameter
2000901
Un¡ts
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1 ,3-Dichloropropane
I ,4-Dichlorobenzene
2,2-D¡chloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromod ich lorometh a ne
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroelhane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
D ich lorod ifluorometha ne
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl ether
Methylene Chloride
n-Bulylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
lert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uorometha ne
Vinyl chloride
'1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
Yo
%
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
00
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
54.6
52.4
64.6
51.3
51.6
55.1
51.0
53.8
59.9
52.3
43.5
65.1
51.1
52.1
53.3
52-3
53.9
592
64.1
52.3
71.5
53.9
53.2
55.7
51 9
104
57.0
56.1
53.8
52.3
52.1
52.9
526
52.7
46-1
48.5
52.8
53.2
61.4
55.4
58.1
52.4
109
105
129
103
103
1',to
102
108
120
105
87
130
102
'l04
't07
105
108
1tB
128
105
't43
108
'106
't11
104
104
't14
112
108
105
104
106
105
105
92
97
106
106
123
111
116
105
108
102
102
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-140 L1
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-'t40
60-140
60-140
60-1 40
60-1 40
60-1 40
60-140
60-140
70-1 30
70-1 30
70-1 30
Results presented on th¡s page are ln the units lndlcated by the "Units" column except where an alternate unit ¡s presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, LLCDate: 05/1 8/2017 O2:45 P\Ii Page 30 of 35
@
Pace Analytical Serv¡ces, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
w.pacþlabs con
QUALITY CONTROL DATA
Project:
Pace Project No.
Texaco Food Mart#2
92340251
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2000902
Parameter
92340579008
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
2000903
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
1 ,1 ,1 ,2-Telrachloroethane
1, 1, 1 -Trichloroethane
1,1,2,2-fet achloroethane
1, 1,2-Tr¡chloroethane
I ,I -Dichloroethane
1 ,1 -Dichloroethene
1 , 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-D¡bromoethane (EDB)
1 ,2-Dichlorobenzene
I ,2-Dichloroethane
'1 ,2-Dichloropropane
1,3,5-Trimethylbenzene
1 ,3-Dichlorobenzene
1,3-Dichloropropane
I ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
D ib ro mo ch lo ro meth a ne
Dibromomethane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl{ert-butyl ether
Methylene Chloride
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
226
23.0
21.6
'18.7
2't.3
20.8
22.1
19 8
21 I
19.2
22.O
22.4
20.7
200
20.3
20.3
20.4
20.2
207
203
25.2
'19.7
20.1
21 3
20 1
21 5
22.8
20.8
17.1
26.2
20 1
19 3
21 2
21.4
21.4
2't 6
23.6
202
227
20.9
21.3
21.1
205
41 4
21.6
20.6
19.6
194
15.9
166
178
17.2
19.0
16.8
15.9
162
190
18.2
17.7
166
17.1
162
172
17.O
17.7
17.6
20.6
17 1
167
18.6
17.5
18.1
'18.2
178
146
22.6
17.3
16.2
18.3
1B 3
180
173
20.1
16.6
19.3
17.4
185
184
17.1
36.0
17.7
17.2
'113
115
108
94
107
104
110
99
109
96
101
112
103
100
102
102
100
101
104
102
126
99
101
106
100
107
114
't04
B6
131
'100
97
'106
107
107
108
'118
101
'113
105
107
106
102
102
108
103
9B
97
BO
83
89
86
95
84
79
81
86
91
89
83
B6
8'l
84
85
B9
88
103
85
84
93
8B
91
91
89
73
113
86
B1
91
91
90
87
101
83
97
Õt
93
92
85
88
89
B6
14
17
30
12
1B
19
't5
16
32 R1
17
15
21
15
19
't7
23
17
1B
16
't4
20
14
1B
14
14
't7
23
16
16
15
15
17
15
16
1B
22
16
20
'16
19
14
14
18
14
20
18
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-'t40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-'140
60-'140
Results presented on this page are ¡n the un¡ts ind¡cated by the "Units" column except where an alternate un¡t ¡s presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Seruices, LLCDale: O511812017 02:45 PM Page 31 of 35
@
Pace Analyt¡cal Services, LLC
9800 KìnceyAve Su¡te 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacÊlabs cam
QUALITY CONTROL DATA
Project:
Pace Project No.:
Texaco Food Mart #2
92340251
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2O0O902
Parameter
92340579008
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
2000903
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
L¡mits RPD Qual
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans- 1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
17.9
18.5
18.7
17.7
17.5
17.3
15.1
16.8
't7.5
18.3
19.0
18.3
188
17.9
14
12
'14
16
16
't6
17
'15
10
15
't0
't4
't2
15
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Yo
%
To
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20.7
20.8
2't.5
20.8
20.6
20.3
18.0
19.5
19.3
21 3
2',t 0
21.1
21.1
20.8
103
104
108
104
103
102
90
97
96
107
105
105
106
104
107
109
96
90
92
94
88
87
86
76
B4
87
91
95
92
94
90
106
98
9B
60-'t40
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
70-1 30
70-1 30
70-1 30
Results presented on this page are ln the units lndlcated by the "Units" column except where an alternale un¡t ¡s presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except ¡n full,
without the written consent of Pace Analyt¡cal Services, LLC.Date: 05/18/2017 0245 PM Page 32 of 35
o
Pace Analytical Services, LLC
9800 K¡nceyAve Su¡te 100
Huntersville. NC 28078
(704)87s-9092
Analytical
ww.pac?labs.con
QUALIFIERS
Project:
Pace Project No.
Texaco Food Ma¡1#2
92340251
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting l¡m¡t.
J - Estimated concentralion above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - lndicates the compound was analyzed fo¡ but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended ¡n SWB46 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte ¡s a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC lnstitute
LABORATORIES
PASI-C Pace Analytical Serv¡ces - Charlotte
ANALYTE QUALIFIERS
L1 Analyte recovery ¡n the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery
RPD value was outs¡de control limits.
M1
R1
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not þe reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Services, LLCDale: 0511812017 02:45 PM Page 33 of 35
@
Pace Analytical Services, LLC
9800 KinceyAve. Suite'100
Huntersv¡lle, NC 28078
(704)875-e092
Analytical
www.pacþlabs.cgm
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No
Texaco Food Ma¡l#2
92340251
Lab lD Sample lD QG Batch Method QC Batch Analytical Method
Analytical
Batch
92340251001
92340251002
92340251O03
92340251 004
92340251 005
92340251 006
92340251007
MW-I
MW-2
MW-3
MW-4
MW-5
T-l
Trip Blank
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
360762
360588
360588
360762
360588
360588
360464
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/18/2017 O2:45 PM Page 34 of 35
d')' y'retuctl¡a!CHAIN-OF-CUSTODY / Analytical Request Document
The Chain-of-custody is a LEGAL DOCUMENT All relevant lìelds musl be completed accurâtely.
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Page 35 of 35