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Home My WebLink AboutWS-6081_22332_CA_RMR_20160428MONITORING REPORT TEXACO FOOD MART #2 17OO COTTON GROVE ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA INCIDENT NO. 22332 SHIELD PROJECT NO. 1001289 August 2015 through March 2016 Responsible Party: Techno, LLC for Holding Brothers, Inc P.O. Drawer 647 Concord, NC 28026 Contact: David Holding (704) 786-4127 Flora J. D'Souza, CHMM Project Manager Site Risk Classification: High Risk (H155D) Land Use Category: Residentialand commercial Release Discovered: February 8, 1999 Potential Release Source(s): Unknown Consultant: Shield Engineering, Inc. 4301 Taggart Creek Road Charlotte, North Carolina 28208 Contact: Flora J. D'Souza (704) 394-69t3 Site Latitud e: 35"46'41" Nofth Site Longitude: 80o15'35" Vy'est Quantity Released : Unknown Release Cause: Unknown Property Owner: United Oil of the Carolinas, Inc. P.O. Box 68 Gastonia, North Carolina 28053 Contact: David Dulmage (704) 791-0123 ñt \\ cÁR É_ Â1,{ trttll?llfl;r, Jrr.^SÑuìt^f David A. Stoner, Senior Principal Registered NC #1 April28,2016 42 A !q,$l TABLE OF CONTENTS I.O DISCUSSION OF SAMPLING RESULTS 2,0 CONCLUSIONS.. 3.0 RECOMMENDATIONS......,.... 4.0 LIMITATIONS Figure l: Figure 2: Figure 3: Figure 4: Figure 5: Figure 6: Figure 7: Table l: Table2: Table 3: APPENDICES Appendix A: Laboratory Report - Groundwater Samples Page No. .4 ,4 .5 LIST OF FIGURES Site Location Map Site Map 1500'Radius Map Groundwater Elevation Contour Map Benzene Isoconcentration Map 1,2-Dichloroethane (DCA) Isoconcentration Map Ethylene Dibromide (EDB) Isoconcentration Map LIST OF TABLES Summary of Adjacent Property and Water Supply Well Owners Summary of 'ù/ell Construction and Historical Groundwater Elevation Data Summary of Historical Analytical Results - Groundwater Samples H :\Projects\2000\ I 00 1 289 - TFM#2\ReportsVRMR Apr 20 I 6VRMR Apri| 20 I 6.doc Texaco Food Mart #2 Lexington, Davidson County, North Carolina lncident#:22332 Monitoring Report April28,20l6 Page I 1.0 DISCUSSION OF SAMPLING RESULTS 1.1 Site Monitoring Requirements: Site Locqtion Map Site Map: See Figure I See Figure 2 Site Monitoring Requirements Based on CAP and/or NORR Sample Point Type Total Quantify of Previous Sample Points and Their Identification Required by NCDEQ to be Monitored and Sampled per CAP and/or TA Monitoring Wells 10 (MW-l through MW-6, and T-l through T-4) 6 {t) (MW-l through MV/-5 and T-l) Water Supply Wells 13 (2) (WSW- I through V/SW- 1 3) 0 (l) Individualwells identi/ìed by the North Carolina Department of Environmentat Quality QIICDEQ) for specific sampling at this îime. (2) Number of wells locqted within 1,500 feet of site. 1.2 Summary of Analytical Results and Free Product Thickness(s): 1.2.1 Date(s) of Sampling Event: March 21,2016 1.2.2 Existing Area Receptors: A receptor survey was conducted in 2001 as presented in the CSA report datedMay 2002 and the CAP dated October 2003. Refer to the following Tables and Figure(s) for information and locations of area receptors identihed. Refer to Figure(s).' Figure 3 Refer to Tables(s).' Table I 1.2.3 Groundwater Flow Direction:o The groundwater flow direction is to the north-northeast. Current and/or Historical Groundwater Elevation Data is included in the following Table and Figure: Rrft, to Table: Refer to Figure. Table2 Figure 4 Texaco Food Mart #2 Lexington, Davidson County, North Carolina lncidenf#:22332 Monitoring Repoft April28,2016 Page 2 1.2,4 Free Product:o Free Product Detected During this Reporting Period?: No 1.2,5 Groundwater Analytical Results:o Sampled Points and Analytical Methods: (l) Pre-Approvql Task Authorizqtion TA-22332-l 5 o Laboratory Used: Pace Analytical Services Inc. Huntersville, NC o Current Groundwater Analytical Data: The following monitoring wells and other points were sampled during this reporting period. On March 21,2016 groundwater samples were collected from monitoring wells MW-l through MW-5 and T-1. One or more concentrations of analytes including benzene, ethylbenzene, toluene, total xylenes, methyl tert-butyl ether (MTBE), naphthalene, isopropylbenzene, n-propylbenzene,l,2-dichloroethane (1 ,2-DCA), ethylene dibromide (EDB), 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene were detected at concentrations above the l5A NCAC 2L Groundwater Standards (2L Standards) in wells including MW-I, MW-2, M'W-3, MW-4, and T-l Concentrations of anal¡es including benzene, 1,2-DCA, and EDB were detected at concentrations above the North Carolina Department of Environmental Quality (NCDEQ), formerly known as theNorth Carolina Department of Environment andNatural Resources (NCDENR) gross contaminant levels (GCLs) in M'W-2. Refer to the following Table and Appendix for current groundwater analytical data Rrfu to Table: Table 3 Refer to Appendix.' Appendix A Historical Groundwater Anal¡ical Data: Total dissolved phase petroleum concentrations in monitoring well MV/-2 have increased in comparison to May 2015 data. Total dissolved phase petroleum concentrations have decreased in the deeper well T-l since May 2015. Based on CAP and Sampled Points and Analytical Methods for this Reporting Period Pre-Approval Task Authorization Sampling Requirements Type Points Sampled during this Reportins Period Analytical Methods Monitoring Wells (6¡ r'r (MW-l through MW-5 and T-l) o EPA Method 6200B o Texaco Food Mart #2 Lexington, Davidson County, North Carolina lncident#:22332 Monitoring Repoft April28,20l6 Page 3 Refer to the following table(s) for historical groundwater analytical data. Refer to Table(s).' Table 3 o Dissolved Phase Plume Size and Location: The on-site dissolved phase plume is irregularly shaped and has an approximate length of 120 feet and width of85 feet based on the benzene concentrations above 2L Standards. The dissolved phase plume that is above the NCDEQ GCLs is approximately 20 feet by l0 (Figure 5). The plume maps for constituents that are above the GCLs are shown on the following figures. Refe, to Figure(s).' Figures 5 through 7 Proximity of Plume to Nearest Receptor(s):a Based on the receptor survey conducted in 2001, there were three (3) confirmed drinking water supply wells and six (6) inactive supply wells located within 1,000 feet of the source area. The closest drinking water supply well ('WSW-1) is located approximately 450 feet south (hydraulically upgradient) of the site. No surface water bodies were observed in the field or on the topographic map within 500-feet of the source area. Rrfu to Figure Refer to Table: Figure 3 Table I a 1.2.6 Other Field Data Collected:o No additional field data was collected. Predictive Rate of Contaminant Transport: The contaminant plume has been fairly stable or immobile over the past several years, and in general reducing in concentration. Refer to Toble(s)Tables 2 and3 Texaco Food Malt #2 Lexington Davidson County, North Carolina Incidenf#:22332 Monitoring Report April28,20l6 Page 4 2.0 CONCLUSIONS o Free product was not detected in site wells during this reporting period. o Dissolved phase petroleum constituent compounds were detected in concentrations above 2L Standards in monitoring wells MV/-l through MV/-4 and T-1. o Dissolved phase concentrations of benzene, 1,2-DCA, and EDB were above the NCDEQ GCLs in MV/-2. o Dissolved phase petroleum constituent compound concentrations decreased in monitoring wells MW-I, MV/-3, and T-l since May 2015. Dissolved phase petroleum constituent compound concentrations have increased in monitoring wells MV/-2 and MV/-4 since May 2015. o MW-5 continues to show non-detect levels of contamination.o In 2007, three (3) privately owned drinking water supply wells were identified within a 1,000-foot radius of the source area with the nearest confirmed drinking water supply well approximately 450 feet hydraulically upgradient from the source area.o Based on a conversation with Michael Rogers of the NCDENR on November 16, 2010, since WS'W-1 is approximately 450 feet updradient of the site and the property owner would not allow Shield or NCDENR to sample their supply well, the Texaco Food Mart #2 site would likely be reduced to low risk if soil excavation was completed to remove as much soil as feasibly possible and if MV/-2 groundwater concentrations were below GCLs. o Soil excavation around boring SB-8 was conducted on February 28, 2012 via over drilling with l4-inch outside diameter hollow stem augers around the boring. Details of the excavation were previously submitted to the NCDENR in the Monitoring Report dated October 23,2012. 3.0 RECOMMENDATIONS It is recommended that bi-weekly air sparging be conducted to reduce the groundwater concentrations to below GCLs, with NCDEQ and Trust Fund approval. It is requested that the NCDEQ consider a Mobile Multi-Phase Extraction (MMPE) event at the site to expedite cleanup. Once M'W-2 is belowthe GCLs we will request a "no further action" determination from the NCDEQ. o a Texaco Food Mart #2 Lexington Davidson County, Nofth Carolina lncident#:22332 Monitoring Reporl April28,2016 Page 5 4.0 LIMITATIONS Shield has performed environmental services at the subject site on behalf of Techno LLC for Holding Brothers, Inc. Shield has performed this scope of work as an independent contractor/consultant using reasonable care and skill in accordance and consistent with customary industry standards of engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of care that can be applied to measure Shield's performance of the work. No other warranty, expressed or implied is made or intended by Shield. The report has been prepared for the exclusive use by Techno LLC for Holding Brothers, Inc. All recommendations, hndings, and conclusions, made by Shield have been made to the best of Shield's knowledge, opinion and belief, based upon information obtained during this scope of Techno LLC for Holding Brothers, Inc. and Shield. Conclusions are provided with the understanding that Shield is presenting information and not rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the responsibility of Techno LLC for Holding Brothers, Inc. under advice of its counsel to noti$, the appropriate federal, state, or local public agencies as required by law; or otherwise to disclose in a timely manner, any information that may be necessary to prevent damage to human health, safety, or the environment. Compliance with recommendations provided as part ofthis report in no way assures compliance with federal, state and/or local laws, regulations, andlor requirements, Analytical datahas been obtained from Pace Analytical Services Inc. This information, to the extent that it was relied on to generate this report, is assumed to be correct and complete. The work performed in conjunction with this report and the data developed are intended as a description of available information at the dates and specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or recommendations with respect to any conditions that were knowingly or unknowingly withheld, concealed, hidden, or in any way not disclosed or observable at the time of this scope of work. 1 001 289ADDEN1 - Locationa-.,""-"i:{,.:çeia" ;.- ìi. !-4.- --,::,("\)\ ,:ttñItU'c)rÈ¡lñ.Aooo4tlãlã€ã5El!tããz=ozFC)()olltzO-¡('0GtcÉã.ì_<=E '!i4üFÈÞot-=Eúl=Bo!(o{u(o@(¿)!l¡ìr-9f\Èf\ËNË t'rnÞìvi¡¡ Ë3e t -4ì NmdoLA=rflon-toz.=!pRI-.trn-)(PlÞzP rìsd8 vñz i -tl:ã9 P:4ô\Js=d e*EäFtè4+tF'.JÈ<È5ãzÇ)-¡ozr{(n:¡z(lcT=l>zQiÌoIrıllI-{rflAoo\toIÐã.¿_@:Irrlt.t1rìt-rn(lJ1-o=.¿--r'lc)cÐT (, =ô€ d. =d ô@Noo Uú,l9L N =LF oæN oo oooN F.(JU odÀ I F lJU Uô AMOCO RUSHCO #3 SB.5' AS-5EE@ EVE-ó T-4 VE 'sB-6 ffi:3l0 ASPHALT AS-ó¡ 7 REGULAR UST REGULAR UST SUPREME UST SUPREME U5T TANK PIT ùúoimrNn Fr ralplc Osa-z f SB.7 a 5B-8 TEXACO FOOD MART Ðf)fIoal{ 3 5B-9q VE -3 SB-aB-S 1+¡ AS-4 E AS VEo 3*:e-1 3 T GASOLINE UST ô ÀUFUÉ.Uz.o\J GASOLINE UST GASOLINE UST DISPENSER DISPENSERDISPENSER iuw-z O DISPENSER DISPENSER rw-r o o remp-z o MW-1 \,/ATER ME I s H I E L D åä"'+??Ê:r""::5i,'* ww shisldê.0¡nsonng @mINC. SITE MAP TEXACO FOOD MART #2 17OO COTTON GROVE ROAD LÐ(INGTON, NORTH CAROLINA SHIELD # 1001289 DATE: 04/20/16 DRAWN BY : KJC SCALE : AS SHOWN FIGURE : 2e) Mw-5 mw-o O VACANT LOT N DISPENSER ô oÉ. l¡J oÉ.(9 z.o Fo \¿ @+t l¡Jl-foú. rJz. mw-+ O NE DISPENSER ASPHALT al,i.i E ta-r¿ AS-2+'sB-1ó AS-3oT-2 KEROSENE + 'sB-15 LEGEND: + L|GHT POLE ø PowER PoLE ELECÏRICAL LINE SANITÀRY SEWER L¡NE PROOUCT LINE O tEXAco FooD MART MoNlroR¡NG WELL O TEXAco FooD ÀtaRT DEEP MoNtroRtNG wELL ACCESS ROAD CEDAR LANE ROAD fe,UP-l O o SITE AS5ESSMENT RV|CES, lNC.D^fED 4t16t01. ovE ¡as oo VAPOR EXTRACTION WELL AIR SPARGING WELL + SOIL BORING 5À!{PLE5 @ DEPTHS OF 214', 5!7' & 'IO'-12', ALL OTHER SOIL BORING SOIL BORINGS FOR ÂNALYSIS OF 82ó0, 8270, EPH &, VPH SOIL BORINGS FOR ANALYSIS OF 82óO ô VPH EXTRACIABLE PETROLEUM HYDROCAREONS ''LATTLE 'ETR.LEUM HyDRocaRBoNs WENDY'S PROPERTY EPH GRAPHIC SCALE0 5 101520t#t SCALE: I in. = 20 ft.VPH NOTEr ALL LOCATION5 ARE APPROXIMATE. ê SHIELD 4301 fAGGART CRÉEK ROAD CHARLOÍTE, NC 28208 704,304-6013 ENGINEERING, INC. 70{-394-6008 fd www shiôldonginosnns com 1,500' RADIUS MAP TEXACO FOOD MART #2 1 ZOO COTTON GROVE ROAD LEXINGTON, NORTH CAROLINA SH|ELD # t00t289 DATE: 08127/10 DRAWN BY : RBS SCALE : AS SHOWN FIGURE : 3 \ \ \ / \ \ $ wsw-r w5w-2 FU+ I I \ I T*r*-,' wsw-4 wsw-13++wsw-12 WSW-7+WSW-ó *r*-u44 -9 +wsw.ll .//./ l I I / / 500' N LEGEND: PROPERTY LINE - -¿ SïREAM -ll-t1*ll-ll_l-l-+.1-l- RAILRoAD rRAcKs + rNAclvE wATER SUPPLY wELL + ACTIVE WATER SUPPLY WELL RECEPTOR DATA FROM 2001, UPDATED AFTER 2003. NOTE: ALL LOCATIONS ARE APPROXIMATE. APPROXIMÄTE GRAPHIC SCALE 0 t50 225 300 1500'RAD SCALE: 'l in. = 300 ft. (, =ôci NN @o c 2ô doo UÉf(,tr N =Lt- 6óN oo oooN t-UU oÉÀ I (9 =ô I ú.ãÉ oød oo UÉf(9 I =LF o N oo oOoN FUU dda.I ê s H I E L D lllii;å:ir"?ãr'-- www shi€ldèngineedng com/NC. GROUNDWATER ELEVATION CONTOUR MAP TEXACO FOOD MART #2 17OO COTTON GROVE ROAD LE{INGTON, NORÏH CJROLINA SHIELD # t001289 DATE: 04/70/16 DRAWN BY: KJC SCALE : AS SHOWN FIGURE : 4 -'3t9q REGULARusl bl ı MW-3 ô(83.88)- ASPHALT o VE,6 TANK TEXACO \ FOODMART \\ O VE,3 EÀs-4 Eas-1 MW-2 58) T-1 læ.2n T-2I (NM)O \ ASPHALf ,/ KER05ENE / (83.52) dJ'4. ø Mw.4 \ (83.02) DIESEL UsI ,UW-¿ O (NM) VACAÑf LOT !OISPENSER !orsernrsen ! o,tr.rtr* DISPENSER !o,rrr*rr* o,tr."tr*! ô oÉu od(, o I-oL)€ Ut-ÐoÉ L)z. O uw-z (NM) i,i, o GASOLINE Usf ô zo GASOLINE USf GÂSOLINE USTO r¡up-z o (NM)(NM) AccEss'RùAq CEDAR LANE ROAD O r¡¡,tp-r (NM) LEGEN D:¿2.25.83. LIGHT POLE POWER POLE ELECTRICAL LINE SANITARY sEWER LINE PRODUCT L¡NE TEXÀCO FOOD MARI MONITORING WELL TEXACO FOOD MART OEEP MONIÎORING WELL 0. WEÑDY'S PROPERTY MW-5 (Ð o (82. o AMOCO RUSHCO #3 MONITORING WELL ÂLL DÂTÂ TÀKEN FROM THE PHASE ¡I LIMITED SITE ASSESSMENT REPORT PREPARED BY COM ENVIROMENfAL SERVICES, INC. DATED 4/1ólOI OVE 3as ( rt) (83.58) [8] 24 (NM) VAPOR EXTRACTION WELL AIR SPARCING WELL FEET GROUNOWAÍER ELEVATION CONÎOUR LINE (ft} GENERÂLIZED GROUNDWATER FLOW DIRECTION cRouNDwAtER ELEVATTON (rr) GROUNDWATER ELEVATION (fI) NOT USED IN CONTOURIN6 ÑOT MEASURED APPROXIMATE GRAPHIC SCALE 0 15 30 AMOCO RUSHCO f3 NOTES:I. DEPÍHSTO GROUNDWATER MEASURED03/2Il1ó. 2. ALL LOCATIONS ARE ÀPPROXIMATEl. CoNfOUR INTERVÂLS = 0 25 FOOT PARKIÑG AREA SCALE: 'l in. = 30 ft. (, =ôú ú. =d 6@N oo uÉ.=IL N =Lt-- o@N oo oooN t-UroÉ.ÀaI ê SHIELI)430,I TAGGART CREEK ROAD CHARLOTTE, NC 28208 704-394-4e13 704-394-6908 fdww shi6ld6nsin6ódns ømENG/NEER/NG INC. ISOCONCENTRATION MAP NZENE TEXACO FOOD MART #2 17OO COTTON GROVE ROAD LE(INGTON, NORTH CAROLINA SHIELD # 1001289 DATE: 04170/16 DRAWN BY: KJC SCALE : AS SHOWN FIGURE : 5 REGULÁRu5fB) !J SUPRE¡¿Eu5f a5-6¡ .1S @ VE-6 ÄSPHALT AS-5¡Oo1-4 VE-7 (Ns) /nw-t6./ (17.01- TANK P/I I I I I I I/ TEXÄCO FOOD MART \ II I I IIII VE-3 ¡ \- Às-4 \, ./-_/ ) DISPENSER I ASPHALT \al,Í:i \ KERostl¡ **å o (2.8) I DIESEL UST + ,UW-¿ O (Ns) VACANT LOl N !DISPENSER DIsPEÑSER !orsrrnrxn DISPENSER !o,rrr*rr* o,rrttt *!DISPENSÉR ô odU oÉ(, o FoU€ Ut-=oÉ Uz ^-&,ffi (D ¡¡w-z (Ns) i-1, o GASOLINE UST zo GASOLINE UST GASOLINE USTO r¡¡,rp-z (Ns) o MW-t (Ns) ACCESS ROAD CEDAR LANE ROAD O reup-r (Ns) LEGEND: + LIGHT PoLE ø PowER PoLE ELECTRICAL LINE SÀNITARY SEWER LINE PRODUCT LINE WENOY's PROPERÍY o o TEXACO FOOD MART MONITORING WELL TEXACO FOOD MÀRT DEEP MONITORING WELL MW-5 a ÀMOCO RUSHCO É3 MONITORING WELL ÀLL DAIA TAKEN FRoM THE PHA5E ll LIMITED slTE 455E59\4ENT REPORT PREPARED BY C8M ENVIROMENIAL SERVICES, INC. DATED 4t16101. I ue vaPoR EXTRÀcloN wELL I os a¡R SPARGTNG wELL (ug/L) MICROGRAMS PER LIÍER (1 1,300) EENZENE CONCENTRATION (ug/L) [18.5] BENZENE CONCENÍRATION NOT USED lN CoNIOURING (uglL) BENZENE ISOC0NCENTRÀTION LINE (uglL) BENZENE ISoCONCENfRATION LINE (u8/L) EXCEEDING GROSS CONTAMINANT LEVtLS (GCL5) (ND) NOT DETECTEO - BELOW LABORATORY METHOD OEÍECÍION LIMITS (N5) NOT SA]I¡PLED APPROXIÀ{ATE GRAPHIC sCALE 01530 SCALE: 1 in. = 30 ft. AMOCO RUSHCO TT3 NoTEs: 1- GROUñDWATER SAMPLES COLLECTEo 0N 03/21lló. 2- ALL LOCATIONS ARE APPROXIM,ATE]- CONTOUR INTERVALS AS SHOWN PARKING AREA It =q€ dãÉ oóNoo UÉf(,tr N LF ôóN oo oooN FL)U-oÉÀa,r ê SHIELD iI"'?55ð,** ww shiðldðnOinê€dng @mINC. 1 ),ISOCONCENTRATION .DICH ETHANE TEXACO FOOD MART #2,I7OO COTTON GROVE ROAD LEXINGTON, NORTH CAROLINA SHIELD t t001289 DATE: 04/20/16 DRAWN BY: KJC SCALE : AS SHOWN FIGURE : 6 hl ASPHALf til';io A5-5¡Oo1-4 VE-/(Ns) AS-óIo vE-6 REGULAR UST REGULARUST 5UPß4tsusf TANK TEXACO FOOD MART Þ EAS-4 torT VE-3 ll ,UW-+ (Ð ) (ND) ASPTIALT KEROSENE .AS-2 (Ns) or_,' DIESEL UST aôñaRFtF pÀD ,f,fW-¿ (Ð (Ns) VÄCANT LOT DISPENSER DISPENSER !!o,rr.rtr* DISPENSR DISPENSER DISPENSER DISPENSR ô oÉU oÉ(,zo F I€ UF oÉ L)z. O ,uw-z (Ns) 1ilt' o GASOLINE Usf ô b zo GASOUNE UsT GASOUNE Ust(D r¡¡r,tp-z (Ns) o MW-1 (Ns) ACCESS ROAD CEDAR LANE ROAD O r¡¡,rp.r (Ns) LEGEND: + LIGHT PoLE ø PowER PoLE ELECTRICAL L¡NE SANITARY SEWER LINE PRODUCT LINE O TEXAco FooD MÂRT MoNlroRlNG WELL O TEXAco FooD MART DEEP MoNtroRlNG wELL WENDY'S PROPERIY MW-5 (ND) o AMOCO RUSHCO Ë3 MONITORING WELL ALL DATA TAKEN FRoM THE PHAsE ll LIMITED S|TE A55ES9!'IENT REPORT PREPARED BY CBM ENVIROMENTAL SERVICES, INC. D^TED 4l16tO1 E vE VAPoR EXTRACTION WELL ¡ A5 AIRSPÀRGINGWELL (UglL) MICROGRAMS PER LITER (1,0901 1,2-DICHLORoETHANE(DCÂ)CONCENTRATION(ug/L) I0 rl 1,2-DICHLOROETHANE (DCÀ) CONCENTRATION NOT USED lN CONTOURING (ug/L) - I,2.DICHLOROETHANE (ocA) ISOCoNCENTRATION LINE (uglL) 1,2-DICHLOROEÍHANE (DCA) ISoCONCENTRATION LINE (ug/L) EXCEEDING GROSS CONTAMINANÏ LEVEts (GCL5) fND) NOT DETECT . BELOW LABORATORY METHOD DETECfION LIMITS (NS) NOT SAMPLED APPROXIMATE GRAPHIC ÍALE AMOCO RUSHCO #3 NOTES: 'l- GROUNDWATER SAMPLES CoLLECTED 0N 03/21l1ó 2- ALL LOCÀTIONS ARE APPROXIMAÍE 3. CONTOUR INTERVÀLS A5 5HOWÑ PARKIN6 ÁRil 01530l--+--i (9 =o <; ÉãÉ oóN oa UÉ.f(,tr N ãLF o@N oo oOoN F\Ju oÉÀaI ê SHIELD årJ"":5ffi** ENGINEERING'INc'wwwsh¡€ldonoin€onno@m ETHYLENE DIBROMIDE (EDB) I SOCO NC ENTRATI ON IY{AP TEXACO FOOD MART #2 ITOO COTTON GROVE ROAD LEXINGTON, NORTH CAROLINA SH|ELD I 1001289 DATE : 04/20/16 DMWN BY: KJC SCALE : AS SHOWN FIGURE : 7 DIESEL UST + ,ltW-A O (Ns) VACANT LOT N OISPENSER OISPENSER !orseeHsen DISPENSER !o'*rrr.*DISPENSER !DISPENSER â odU oÉ,(,zo FoU € UF =oú, Iz. O ¡,tw-z(Ns) ìilr' o GASOLINE UST ¡ zc GASOLINE UST GASOLINE USTo rEmp-z o (Ns)(Ns) ACCESS ROAD CEDAR LANE ROAD (D r¡,r,rp-r (Ns) LEGEND: + LIGHT PoLE ø PowER PoLE ELECTRICÂL LINE SANITARY SEWER LINE PRODUCT LINE O TEXAco FooD MARTMoNtToRtNG WELL O rEXAco FooD MART DEEP MoNlloRtNG WELL WENDY'5 PROPERIY MW-5 (ND) o AMOCO RUSHCO f3 MONITORING WELL ÂLL DÄTÀ TÂKEN FRoM THE PHASE ll LIMITED SITE ASSEs9\^ENT REPORT PREPARED BY CBM ENVIROMEÑTAL SERVICEs, INC.oAIED 4t16t01 O VE VAPOREXTRACTIONWELL E AS ÀIR sPÂRGING WELL (ug/L) MICROGRA¡¡s PER LITER 16771 ETHYLENE DIEROMIDE (EDBI CONCENTRAÍION (UglL) [NDl ETHYLENE DIBROMIDE (EDB) CONCENIRÀTION NOT USED lN CONTOURING (ugll) EfHYLENE DIBROMIDE (EDB) ISoCONCENTRATION LINE (uglL) - ETHYLENE DIEROMIDE (EDB) ISOCONCENTRATION L¡NE (uglL) EXCEEDING GROSS CONTAMINANT LEVELS (GCLS) (ND) NOT DETECTED - BELOW LABORAÍORY METHOD DETECTION LIMITS (NS) NOT SAMPLED APPROXIMATE GRAPHIC SCALE 0 15 30 AMOCO RUSHCO #3 hf REGUúR UST REGULARUST U5T TANK A5-5 A5-6o¡o E ¡VE-6 T-4 VE-7(Ns) ii';io ASPHALT SUPREMEu5T ÏEXACO FOOD MART lflfbll o vE.3 ) DISPEÑSER ASPHALl o KEROSENE ,ttW-¿ O (ND) 'r-2 (Ns) NoTEs: l- GROUNDWATER SAMPLES COLLECTED 0N 03/21l'16. 2- ALL LOCÀTIONS ARE APPROXIMATE 3- CONTOUR INTERVÂLS AS SHOWN. PARKING AREA scALE: I in. = 30 fr. Table: ISummary of Adjacent Property and Water Supply Well OwnersTexaco Food Mart #21700 Cotton Grove Road,iäi'ñiì::il:":iîl'äFt BGS = feet below ground surfaceAddress of well. Property owner's address is 500 Maegeo Dr-, LexingtonOfthepropertyownerswithoutPWShookups,onlyJohnTetterisinterestedinbeaddedtothePWS Otherpropertyownersindicatedthattheya¡enotinterestedatall.NA - Not AccessiblePublicWaterSystemhook upNoYesYesNoYesYesYesNoYesUnk.Unk.YesNoDistancefromsource areaofrelease(ft.)450700650'98s750'760'795't025'1090'I 100'l175'800'850'WellScreenInterval(¡toyft.BGS),|,.1,|,|,l,l,l,l,),|j,ljWellCasingDepth(ft. BGS),l2,),),.1,|,|,.1,l,7,l,l,lTypeofWetl,7,),l,|,),l4",l,l,7,),.1WellDepth(ftBGS)185,),l,ì,),.1,)> 100,,ì,|,ì,lWell UseDrinkingNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseIrrigationDrinkingPhoneNumber336-3s7-2511336-3s7-5231336-357-2659336-357-2916336-249-3266336-357-2485336-357-2565NANANANANANAAdd¡essP-O. Box 284 Lexington, NC104 Fuller Rd., Lexington, NC106 Fuller Rd., Lexington, NCI l5 Cedar Ln., Lexinglon, NC6 Mayfair Rd., Lexington, NC*Box 8 Mayfair Rd., Lexington,NCBox 100 Mayfair Rd.,Lexington, NCBox 108 Mayfair Rd.,Lexington, NCBox 107 Mayfair Rd,Lexington, NCBox 103 Mayfair Rd.,Lexington, NC1724 Southview Rd.,Lexington, NC102 Mayfair Rd., Lexington,NC104 Mayfair Rd., Lexington,NCWell Owner/ User (indicatewhich)Flowerest O. LoppPaul & Stella BakerMargaret H. FullerHoyle R. SmithEfird E. Jr. & Kay S.Wilson(owner)Abe CassidyMrs. Samuel C. DavisMaxine C. HouckThomas FrankJames G. HendersonRay S. & Irene MusgraveAubrey & Helen BrewerJohn T. TetterWell #wsw-1wsw-2wsw-3wsw-4wsw-5wsw-6wsw-7rwsw-8wsw-9wsw-10wsw-I1wsw-12wsw-13NotesH.\ProjecsV000\1001289 - TFM#2\Repors\ARMR Aug 2014\Water Supply Well Information Table doc Table 2: Summary of Well Consfruction ¡nd Hisforical Groundwater Elevation Data Texaco Food M^ttH2 1700 Cotfon Grove Road, Lexington, North Carolina NCDENR lncidenf # 22332 Field Calculafionsh-ield Measurements Dâte I nstalled Top of Casing Elevation ( feet) Well Diameter (i nches) As-buill Depth ( tee t) Sc reened lnterval (feet)Gauging Date Tofal Depth (feet) Depth to Static Water (feef) Depth to Free Product (feet) Diff, Befween As-Built and Measured Total Depth (feef) Ground-water Elevation (feet) Well lD tu/llt/ut J5 UU ¿4 09 NA U /5 vt ¿¿.tJ NA U ilEtu4tzzilJzJ5 00 t6 JtllÃ9tu7J5,U I '23 69 NA -UUI 03/u4l09 'J4 93 ì9 ó8 NA u07 80 J2 [7n9nJ 15,07 ì7,55 NA -0,07 82 45 07/lln4 35 07 17 32 NA -0 07 82 68 u5/¿ul I 5 J5 U/tð Õu NA -U,U /8ì40 uJt zlt 16 J5 U/tb 4ð NA -U U/83 5¿ '¿J5 ¿0-i5fvtw-t olt3tt0t t0u00 /5. /ðtu/tu/0ì J5 UO 24 ¿2 NA 0 t)4tzztuz J5 OU 22 0t\NA U ll9¿ II ilgt[7 34 75 2J 84 NA 025 't6 J5 03/04/09 34 65 t9 62 NA 035 80,57 06t2Eil2 34 9l ì8 48 NA 0,09 8t7t tJilIytJ J4 94 n53 NA 006 82 66 u1/lUl4 J+ 94 u¿E NA U.UO 82 9t u5/zult 5 J+ 94 lð ó5 U.UO ðt)4 tó ôt NA U,UÓ ðJ 5ð0Jt¿l/t6 34 94 20-i5MW-¿uil_|tut tuu,tv ¿J5 tu/tu/ut J) UU ¿+ ¿t NA (.)t5 9¿ 04t22t[2 35 00 2t 93 NA 0 78 26 lln9/01 35 0l 24.10 NA -0.01 16 09 uJtu4^t9 J4.96 t9.J5 NA 0.04 80 84 u1 I t9t t5 J5 UE U¿3 NA .U Uð E¿.96 uTnl/|4 J5 UE | /,05 NA -U Uð EJ 14 IE 4E NA -U UE Et /t05/20lì 5 J5 OE NA -O UE EJ EEuJtzlÃ6J 5,OU tóJl MW,J I U/UU/U I tuu,tv ¿J)¿U-J) I tt/tu/ul J) UU ¿4 ll NA 0 7Ó Uð 04t22t02 15 00 2t 9t NA 0 78 28 I lil9/u I 34 8t 23 88 NA 0. t9 15 52 uJtu4/lJ9 J4 t4 t9.ru NA 026 t9.50 u] I ¿0t lu J4 t¿lð.) /NA U¿E 80,83 tJl t l9t l5 54.9tJ l9u NA U IU ð1,)u t7,ôu NA U. IU ðtðuu7nUt434 9t) NA U IU E0 t4u5/20l15 14 90 IE ó6 tJStzyt6 34 gtJ ìó t8 NA 0 t0 öJ UZ MW-4 I U/Uð/U I 99.4U ¿J) u4t¿¿tu¿J) UU ¿J 5+NA U /o ð) I ltlv/tt't J) U/24.76 NA -0 07 75 63 UJIU4IU9 J) U9 2tl -U UY t9 22 u7 I t9t lJ J5 l¿t9 tJz NA U¿ðtJ/ IE /E NA -u l¿EtôttJ1I Ilil4 J5 t¿ us/zult 5 J5, tZ t9 90 NA -tJ t¿E0 49 tJStzlÃ6 J5 T2 t] 19 NA -u.t2 E2 60 MW-5 IJ4/IJ4IU¿IUU J9 ¿J)¿U-J' u4t zztu¿I).UU ¿J,U¿NA U tu19/07 25,00 NM NA 0 NM ItJitt4tuy NM NM NM NM NN4 04/u4t0¿tut 4¿¿¿tMW-ó tu/tu/ut 9U,UU ¿4 9i NA U 15 ¿6.IE IJtJ4tzztuz90 0u '¿2 U6 NA U tl/l9^17 8ó,71 zl.59 NA { rq 'tE't6 o3/u4tu9 65 82 t9 52 NA 24 t8 80 8l 07 t19/13 66.84 18.t4 NA 23.'t6 82 Zl 07nln4 66 84 ì8,58 NA 23 16 8t 11 05tztJ/15 66,84 t9 36 NA 23.16 80 99 uJt ¿l I tb 66.84 I /,Uð NA ¿J t6 83 27 I -l I 0/09/0 I IUO J5 ')90 E5 5-9U I NM : Not Measured 2 NA : Not Applicable Sum of well conslrucl¡on and h¡sloical grcundwater elevat¡on Table 3: Summary of Historical Analytical Results-Croundwater Samples Texaco Food Mart #2 1700 Cotton Grove Road, Lexington, North Carolina Analyticnl Method--->EPA Melhod 601/602 EPA Mefhod 504,1 or 62008 EPA Method 625 or 62008 MADEP VPH MADOP VPH & EPH MADEP f,PH MADEP VPH & EPH Ê F N a x Ê¡ Ê)È È â ce e z ¿ (J .9 ? il (.i L) Ê il ú (J è I9 (J È ? I d (J I ó U t5A NCAC 2L.0202 StÂndôrd---->I 600 600 500 20 70 0,4 0.02 6 400 700 10,000 c+d: 200 l 5A NCAC 2L.0t I s C¡oss Contam¡nRtior level---> 5,000 2ó0,000 E4,500 85,500 20,000 70,000 400 50 6,000 l,n.Âlinn Dåt€up/L ølL ¡plL oñ ue/L nsll,ue/L MW-r 0't 13 | /0t ND 5l )40 1,300 NR NR ND 0,96 75 ND 1,4'tO ND 2,780 041101o3 t2 140 ll t,4?0 NR ND ND NR 270 NR NR NR NR I lt9lo7 49,5 647 l'19 I,2l o ND ND ND ND t07 ND 665 ND 825 03l04t09 53.7 284 t65 821 ND ND ND ND t67 468 ó,170 ND 2,200 01^9/11 69.4 81 4 2 161 14 ND ND ND lt4 NR NR NR NR 01il t/14 11,2 0 t12 790 47 ND ND ND NR NR NR NR 051201 l5 93.2 l t45 816 ND 0.63 t43 NR NR NR NR oi/2v16 82.1 I 658 44 ND 2 ND 99.3 NR NR NR NR MW-2 0't 131/ot I J,000 38,000 3,ó00 16,000 NR NR I,200 720 NR 8l,o0o 28,000 NR 9,100 04t10/03 I 2,000 29,000 2,800 ló,700 NR ND t,700 ND 1,400 NR NR NR NR I l/ 19lo'1 I 4,900 34,200 J,090 18,400 6,090 ND l,t 50 ND I,090 60,t 00 7 1,600 108 2ó,630 03t04/09 I L700 z',t,20o 2,250 I 4,500 3,600 ND ND ND 238 59,300 58,930 ND 8,340 06t28t t2 8,930 I 7,800 1,760 10,950 1,420 t44 I ,090 63s 974 NR NR NR NR 011 t9/11 12,60(ì 24,300 2,200 13,J80 7,550 t94 |,33t)771 I,260 NR NR NR NR o'il |lt4 t0,800 2 I,300 1,910 I 1,980 7,040 142 I,2t0 663 1,070 NR NR NR NR 05/20115 6,4 ilt 12,600 989 6,460 4,830 90.9 451 898 NR NR NR NR 01t2t |6 I I,300 22,100 2,t10 t3,200 6,240 154 I,090 677 I,loo NR NR NR NR MW-l t0/t0i0t 120 4,300 I,800 E,600 NR NR ND 9,5 360 ND r t,990 ND I I,710 04130/03 ¡00 3,000 I,600 E,800 NR ND ND ND 660 NR NR NR NR I I lt 9l0'l ND 4,850 2,1 90 13,600 ND ND ND 1.2 513 NR 3460 ND 2,440 oy04l09 ND J,4Jo 2,090 t 1,400 ND ND ND ND ¡,520 5,560 40,926 ND I 1,780 o'iltgll1 22 |,250 t,420 8,0ó0 't3 ND ND ND 144 NR NR NR NR o'il |ll14 55.1 I,1 00 |,300 7,27O ND ND ND ND 831 NR NR NR NR o5/20lls 11,2 95¿1,250 ó,7t 0 94 ND ND ND 88t NR NR NR NR o3l2t lt6 t1 854 1,090 5,E70 ND ND ND ND 6t2 NR NR NR NR Ì\,f\,V-4 t0/t 0/01 ND ND ND ND NR ND ND ND ND NR NR NR NR 04/l0l03 Nt)ND ND ND NR ND ND NR ND NR NR NR NR t t/ t9/07 ND ND ND ND 23 ND ND ND ND ND ND ND ND 03104t09 ND 52 ND 6 4)ND ND ND 123 ND t86 ND ND 01/20t t0 ND ND ND ND 87 ND ND ND ND ND ND ND ND 071 t9/ t3 1.9 ND ND 46 40 ND ND ND ND NR NR NR NR 07lIvt4 2,1 ND ND 't2 65.9 ND ND ND ND NR NR NR NR 05/20/t5 ND ND 67 t06 ND ND ND ND NR NR NR NR 01t21/ t6 2.8 ND ND 64 ll6 ND ND ND ND NR NR NR NR MW-5 04130101 ND ND ND ND NR NR ND NA ND NR NR NR NR I l l9/o'l ND ND ND ND ND ND ND ND 4t 144 ND ND ND 0y04/09 ND l9 ND ND ND ND ND ND 29 ND ND ND ND o'ill9lt3 ND ND ND ND ND ND ND ND ND NR NR NR NR 01/|lt4 ND ND ND ND ND ND ND ND ND NR NR NR NR 051201t5 ND ND ND ND ND ND ND ND ND NR NR NR NR 0y21/16 ND ND ND ND ND ND ND ND ND NR NR NR NR H V,oloclsv000\1001 289 - ÍFW2WèponsVRMR Apt 2016ß!t ol HISIORICAL GW An¿lyb.l.xls PaOe 1 ol 2 <-3t7^ !¡?ÉXãF:- ã >Ênã*;9 ã >*E=!t:E<È=ı>*E+!=<P"BenzeneTolueneEthylbenzeneTobl Xylen6Methyl tert-butyl EtherDiisopropyl ether (lPE)1.2 DichloroethaneEthylene dibrom¡de (EDB)NapütheleneAliph¿tic (C5-C-E)Al¡phâtic (C9-C-12) = aAl¡ph¿t¡c (C9-C-rt) = bA.lipbatic (C194-36)Aromâtic (C9-C-10) = cAromâtic (Cll-C-22) = d{++IØ>gz: (){,ê2>_^z3u-ÈÞ--ÈÈèÈÈ-zzzz2úz/zzzFzf¡UzC'zzzzzUzC'zC'zt,z(,z(,zEz0l¡zzzz?zoz*2zF2zIzUzz2zC'zFzzzãzUI(fzzzzzzIIØ=3.¿ô _ì.ôr>F: ìi ã2.1i v= =6= +ãzã^êzôÉØ3ãY È - a# aãÈ>î>;ÈË=l<ã --à-=iå?-3ÈP - ^: =<- j o:E'4^Zeã3 ¡ ô? -3 aâii9ã X*EzÉ* -? IPb9:<*ò"xgrÍgäà *¡ 8Ã--l6Aııliu¡rir=ızñr'9=e's='zo':>=gê2aa39;ÊPò>>Ë966q--8Þ3.a95èa9=ãà5II6!¡¡:! @ Pace Analytical Services, lnc. 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)87s-e0s2 Analytical www.paælabs.com March 28,2016 Ms. Flora D'Souza Shield Engineering 4301 Taggart Creek Road Charlotte, NC 28208 RE: Project: TFM #2 Pace Project No.: 92290942 Dear Ms. D'Souza: Enclosed are the analytical results for sample(s) received by the laboratory on March 22,2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. lf you have any questions concerning this report, please feel free to contact me Sincerely, Nicole Gasiorowski n i cole. gasiorowski @pacela bs. com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc .Page 1 of31 ô Pace Analytical Services, lnc. 9800 K¡nceyAve, Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www,paælabs.com CERTIFICATIONS Project: Pace Project No TFM#2 92290942 Charlotte Gertification lDs 9800 KinceyAve. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certifìcation #:5342 North Carolina Wastewater Cefiification #: 12 South Carolina Certification #: 99006001 FloridaiNELAP Certification #'. 887 627 Kentucky UST Certification #: 84 Virg in |aA/ELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc .Page 2 of 31 o Pace Analytical Services, lnc. 9800 K¡nceyAve. Suite 100 Huntefsville, NC 28078 (704)875-9092 Analytical www.paælabs.con SAMPLE ANALYTE COUNT Project: Pace Project No.: TFM#2 92290942 Lab lD Sample lD Method Analysts Analytes Reported Laboratory 92290942001 92290942002 92290942003 92290942004 92290942005 92290942006 92290942007 MW-1 MW.2 MW-3 MW-4 MW-5 T-1 TRIP BLANK CAH CAH, GAW CAH CAH GAW GAW GAW PASI-C PASt-C PASt-C PASI.C PASI-C PASI-C PASt-C SM 62008 SM 62008 SM 62008 SM 62008 SM 62008 SM 62008 SM 62008 REPORT OF LABORATORY ANALYSIS Th¡s report shal¡ not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc. 63 63 63 63 OJ þJ 63 Page 3 of 31 o Pace Analytical Services, lnc. 9800 KinceyAve, Suite 100 Huntersville, NC 28078 (704)875-s092 Analytical www.pact,labs,com SUMMARY OF DETECTION Project: Pace Project No.: TFI\A #2 92290942 Lab Sample lD Method Client Sample lD Parameters Result Units Report Limit Analyzed Qualifiers 92290942001 SM 6200B SM 62008 SM 62008 SM 62008 SM 6200B SM 6200B SM 62008 SM 62008 SM 62008 SM 6200B SM 6200B SM 62008 SM 62008 SM 62008 92290942002 SM 62008 SM 62008 SM 62008 SM 6200B SM 62008 SM 62008 SM 62008 SM 62008 SM 62008 SM 6200B SM 62008 SM 62008 sM 62008 SM 62008 92290942003 SM 6200B SM 62008 SM 62008 sM 62008 SM 62008 SM 62008 SM 6200B SM 6200B SM 62008 SM 62008 MW.1 Benzene sec-Butylbenzene Chloroform 1,2-Dichloroethane Ethylbenzene lsopropylbenzene (Cumene) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Toluene 1,2,4-Trimethylbenzene 1,3,5-Trlmethylbenzene m&p-Xylene o-Xylene MW.2 Benzene 1,2-Dibromoethane (EDB) 1 ,2-Dichloroethane Diisopropyl ether Ethylbenzene lsopropylbenzene (Cumene) Methyl{ert-butyl ether Naphthalene n-Propylbenzene Toluene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene m&p-Xylene o-Xylene MW-3 Benzene Ethylbenzene lsopropylbenzene (Cumene) Naphthalene n-Propylbenzene Toluene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene m&p-Xylene o-Xylene MW-4 Benzene Bromodichloromethane Chloroform Methyl{ert-butyl ether 1,2,4-Trimethylbenzene 82.7 12.1 7.6 2.0 '119 26.4 4.4 99.3 43.5 72.9 325 17.4 398 260 11300 677 1 090 154 2170 93.0 6240 11 00 228 22700 2290 558 8550 4650 17.0 1 090 103 632 285 854 2040 525 3920 1 950 2.8 0.70 23.2 116 1.8 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 50.0 50.0 50.0 50.0 50.0 50.0 50.0 200 50.0 100 50.0 50.0 100 50.0 1.2 1.2 1.2 1.2 1.2 1.2 1.2 5.0 1.2 1.2 1.2 1.2 2.5 1.2 03/25116 09:15 03/2511 6 09:1 5 03/25116 09:15 03i25/'16 09:15 03/2511 6 09:1 5 03/2511 6 09:1 5 03/2511 6 09:1 5 03125116 09:15 03/25116 09:15 03/2511 6 09:1 5 03125h6 09115 03/25l'16 09:15 03/25116 09:15 03/25116 09:'15 03125116 08:41 03125116 08:41 03125116 08:41 03/25116 08:41 03125116 08:41 03/25116 08:41 03125116 08:41 03/25116 08:41 03125116 08:41 03128116 06:22 03125116 O8:41 03125/16 08i41 03125116 08:41 03125116 08:41 10.0 10.0 10.0 40.0 10.0 10.0 10.0 10.0 20.0 10.0 03t25t16 03125116 03125116 03t25t16 03t25t16 03t25t16 03125116 03125116 03t25t16 03t25t16 08:58 08:58 08:58 08:58 08:58 08:58 08:58 08:58 08:58 08:58 92290942004 SM 6200B SM 6200B SM 62008 sM 62008 SM 62008 03125116 06:42 03125116 06:42 03125116 0642 03125116 06:42 03125116 06:42 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc.. 0.50 0.50 0.50 0.50 0.50 Page 4 of 31 @ Pace Analytical Services, lnc, 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-90s2 Analytical www.paælabs.con SUMMARY OF DETECTION Project: Pace Project No TFM #2 92290942 Lab Sample lD Method Client Sample lD Parameters Result Units Report Limit Analyzed Qualifiers 92290942004 SM 62008 SM 62008 92290942006 SM 62008 sM 62008 SM 62008 sM 62008 sM 62008 MW-4 m&p-Xylene o-Xylene T-1 Benzene 1 ,2-Dichloroethane Diisopropyl ether Ethylbenzene lsopropylbenzene (Cumene) 4.6 1.8 ug/L ug/L ug/L ugiL ug/L ug/L ug/L 1.0 0.50 03125116 06:42 03125116 06:42 18.5 10.1 0.78 0.58 0.58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Serv¡ces, lnc.. 0.50 0.50 0.50 0.50 0.50 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 Page 5 of 31 @ Pace Analytical Serv¡ces, lnc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www,paælabs.com PROJECT NARRATIVE Project: Pace Project No.: TFM #2 92290942 Method: SM 62008 Description: 62008 MSV Client: Shield Date: March 28, 2016 General lnformation: 7 samples were analyzed for SM 62008. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/orthe sample condition upon receiptform (SCUR) attached atthe end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. lnitial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. lnternal Standards: All internal standards were within QC limits with any exceptions noted below. Surrogates: All surrogates were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc.,Page 6 of 3l @ Pace Analytical Services, lnc, 9800 K¡nceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pacelabs.com ANALYTICAL RESULTS Project: Pace Project No. TFM #2 92290942 Sample: MW-1 Parameters Lab lD: 92290942001 Results Units Collected: 03121116 13:00 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 6200B MSV Benzene Bromobenzene Bromoch loromethane Bromodich loromethane Bromoform Bromomethane n-Butylbenzene se c-B u ty I be nze ne te rt-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene '1,2-Dibromo-3-ch loropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1 ,2-Dichlorobenzene 1 ,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dichlorodifluoromethane 'l ,1 -Dichloroethane 1 ,2-Dichloroethane 1 ,1 -Dichloroethene cis-'1,2-Dichloroethene trans-1,2-Dichloroethene 1 ,2-Dich loropropane 1,3-Dichloropropane 2,2-Dichloropropane 1 ,1 -Dichloropropene cis- 1,3-Dichloropropene trans-1,3-Dich loropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2--let¡ achloroeth a ne 1,1,2,2-Telr achloroeth a ne Tetrach loroethene Analytical Method: SM 62008 82.7 ND ND ND ND ND ND 12.1 ND ND ND ND 7.6 ND ND ND ND ND ND ND ND ND ND ND ND 2.0 ND ND ND ND ND ND ND ND ND ND 119 ND 26.4 ND 4.4 99.3 43.5 ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 1.2 2.51.2 2.51.2 2.51.2 251.2 2.5 12.5 2.51.2 2.51.2 251.2 2.51.2 2.51,2 2.52.5 2.51.2 2.5 2.5 2.51.2 2.51.2 2.52.5 2.51.2 2.51.2 25 1.2 25 1.2 2.51.2 2.51,2 2.51.2 2.51.2 2.51.2 251.2 2.5 1.2 2,5 1.2 2.51.2 2.51.2 2.51.2 251.2 2.5 1.2 2.5 1.2 2.51.2 2.51.2 2.55.0 2.51.2 2.55.0 2,5 1.2 2.55.0 2,51.2 2.51.2 2,51.2 2.51.2 2.51.2 25 15 15 15 15 15 15 15 15 '15 l5 15 '15 15 15 15 15 '15 l5 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 '15 15 '15 15 15 l5 15 15 15 15 15 15 15 03/25116 09 03t25t16 09 03/25116 09 03/25116 09 03/25116 09 03i25/16 09 03i25/16 09 03/25116 09 03/25116 09 03/25116 09 03i25/16 09 03/25116 09 03/25116 09 03t25t16 09 03/25116 09 03/25116 09 03/2511 6 09 03i25/16 09 03125116 09 03125116 09 03/25116 09 03/2511 6 09 03t25t16 09 03/25116 09 03t25t16 09 03i25/16 09 03i25/1 6 09 03/2511 6 09 03/2511 6 09 03t25fl6 09 03i25/16 09 03/25116 09 03125í6 09 03i25/1 6 09 03/2511 6 09 03/2511 6 09 03/25116 09 03/25116 09 03/25116 09 03t25fi6 09 03t25t16 09 03/2511 6 09 03/2511 6 09 03125Í6 09 03/2511 6 09 03/2511 6 09 03/25116 09 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-5 1 -8 1 35-98-8 98-06-6 56-23-5 I 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-12-8 124-48-1 1 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061 -01 -5 1 0061 -02-6 '108-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Serv¡ces, lnc.Date: 0312812016 05:58 PM Page 7 of 31 @ Pace Analytical Services, lnc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www,pacelabs,cwtt ANALYTICAL RESULTS Project: Pace Project No TFM#2 92290942 Sample: MW-1 Lab lD: 92290942001 Results Units Collected: 03121 116 13:OO Report Limit DF Received: 031221'16 13:38 Matrix: Water Prepared Analyzed CAS No.Parameters Qual 62008 MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1, 1 -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,S-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-dB (S) Analytical Method: SM 62008 72.9 ND ND ND ND ND ND ND 325 17.4 ND 398 260 't.2 2.55.0 2.5 5.0 2.51,2 2.51.2 2.51.2 2.52.5 2,51.2 2.5 1.2 2.5 1.2 2.52.5 2.52.5 2.51.2 2.5 09:'l 5 09:1 5 09:1 5 09:1 5 09:1 5 09:1 5 09:1 5 09:1 5 09:1 5 09:15 09:'15 09:15 09:15 ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L 03t25t16 03125t16 03t25t16 03125t16 03t25t16 03t25t16 03125116 03125t16 03t25t16 03t25t16 03t25t16 03125116 03125t16 1 08-88-3 87-61-6 120-82-1 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 '108-67-8 75-01-4 179601-23-1 95-47-6 100 102 99 70-130 2,5 70-130 2.5 70-130 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc.. 031251'16 09:15 17060-07-0 031251'16 09:1 5 460-00-4 03125116 09:15 2037-26-5 -fo o/o % Date: 0312812016 05:58 PM Page 8 of 31 @ Pace Analytical Services, lnc, 9800 K¡nceyAve. Suite 100 Huntersv¡lle, NC 28078 (704)875-9092 Analytical v¡trw.pacþlsbs.com ANALYTICAL RESULTS Project: Pace Project No TFM #2 92290942 Sample: MW-2 Parameters Lab lD: 92290942002 Results Units Collected: 03121116 13:08 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 6200B MSV Benzene Bromobenzene Bromoch loromethane Bromodich loromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenze ne te rt-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene '1,2-Dibromo-3-ch loropropa ne D ibromoch lorometh a ne 1,2-Dibromoethane (EDB) Dibromomethane 1 ,2-Dichlorobenzene 1,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dich lorod ifluorometh a ne 1 ,1-Dichloroethane 1 ,2-Dichloroethane 1 ,1 -Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dich loroethene 1 ,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1 ,1-Dichloropropene cis-'1, 3-Dich loropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) Methylene Chloride Methyl{ert-butyl ether Naphthalene n-Propylbenzene Styrene 1 ,1 ,1 ,2-Tetrachloroethane 1,1,2,2-IeI¡ achloroetha n e Tetrach loroethene Analytical Method: SM 62008 'l1300 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 677 ND ND ND ND ND ND 1 090 ND ND ND ND ND ND ND ND ND 154 2170 ND 93.0 ND 6240 1100 228 ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 100 100 100 100 100 100 100 100 100 100 '100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 '100 100 100 100 100 '100 100 '100 100 100 100 100 100 100 100 100 100 100 50.0 50.0 50.0 50.0 50.0 500 50.0 50.0 50.0 50.0 50.0 100 50.0 100 50.0 50.0 100 50.0 50.0 50.0 50.0 50.0 50.0 50.0 500 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 s00 50.0 50.0 50.0 200 50.0 200 50.0 200 50.0 50.0 50.0 50.0 50.0 03125116 08:41 03125116 08:41 03125116 0841 03125116 08:41 03125116 08:41 03125/16 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 Q8:41 03125116 08:41 03t25t16 08',41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08141 03125116 08:41 03125116 0841 03/25116 08:41 03125116 08:41 03125116 0841 03125/16 0841 03125116 08:41 03125116 08:41 03125/16 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03/25116 0841 03125116 08:41 03125116 08:41 03125/16 08:41 03/25116 08:41 03125116 08:41 03125116 08:41 03125116 A8:41 03125116 08:41 A3125116 08:41 03125116 08:41 03t25t16 08.41 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-51 -8 1 35-98-B 98-06-6 56-23-5 1 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-1 2-8 124-48-1 1 06-93-4 74-95-3 oÃ_Ãô_.f 541-73-1 1 06-46-7 75-71-8 75-34-3 107-06-2 75-35-4 I 56-59-2 I 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 006 1 -01 -5 1 0061 -02-6 1 08-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except ¡n full, without the written consent of Pace Analytical Services, lnc.Dale: 0312812016 05:58 PM Page 9 of 31 @ Pace Analytical Services, lnc 98OO KinceyAve. Suite 1OO Huntersville, NC 28078 (704)875-e0e2 Analytical www.pacelabs,cwt ANALYTICAL RESULTS Project: Pace Project No. TFM#2 92290942 Sample: MW-2 Parameters Lab lD Results 92290942002 Units Collected: 03/21116 13:08 Report Limit DF Received: 03122116 1338 Matrix: Water Prepared Analyzed CAS No.Qual 620OB MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1,1 -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene Trich lorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Analytical Method: SM 62008 22700 ND ND ND ND ND ND ND 2290 558 ND 8550 4650 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 100 200 200 50.0 50.0 50.0 100 50.0 50.0 50.0 100 100 50.0 70-1 30 70-1 30 70-1 30 200 100 100 100 100 '100 100 100 100 100 100 100 100 O3l28l'16 06:22 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 031251'16 08:41 O3l25l'16 08:41 03125116 08:41 O3l25l'16 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 03125116 08:41 1 08-88-3 87-61 -6 120-82-1 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 1 08-67-8 75-01-4 179601-23-1 95-47-6 100 98 99 % To o/o 100 100 100 1 7060-07-0 460-00-4 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc..Dale 0312812016 05:58 PM Page 10 of 31 ó Pace Analytical Seruices, lnc. 9800 KinceyAve Suite'100 Huntersville, NC 28078 (704) 875-s092 Analytical www.pacelabs com ANALYTICAL RESULTS Project: Pace Project No. TFM#2 92290942 Sample: MW-3 Parameters Lab lD Results 92290942003 Units Collected: 03121116 13:16 Report Limit DF Received: 03122116 13i38 Matrix: Water Prepared Analyzed CAS No,Qual 62008 MSV Benzene Bromobenzene Bromoch lo rometha ne Bromodich loromeihane Bromoform Bromomethane n-Butylbenzene sec-Butylbenze ne iert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1, 2-Dibromo-3-ch loropropane Dibromoch lorometh a ne 1,2-Dibromoethane (EDB) Dibromomethane 1 ,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1 ,1-Dichloroethane 1 ,2-Dichloroethane 'l ,1 -Dichloroethene cis-1,2-Dich loroethene trans- 1,2-Dichloroethene 1 ,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1 ,1 -Dichloropropene cis-1,3-Dich loropropene trans-1, 3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butad iene lsopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Telr achloroetha ne 1,1,2,2-Telr achlo roetha n e Tetrach loroethene Analytical Method: SM 62008 17.0 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 1 090 ND 103 ND ND 632 285 ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 10.0 2010.0 20'10.0 20 10.0 20 10.0 20 100 20 10.0 20 10.0 2010.0 2010.0 20 10.0 20 20.0 20 10.0 2020.0 20 10.0 2010.0 20 20.0 20 10.0 20 10,0 20 10.0 20 10 0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 2010.0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 20 10.0 2010.0 20 40.0 20 10.0 20400 20100 20 40.0 20 10.0 2010.0 20 10.0 20'10.0 20'10.0 20 03/2511 6 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/2511 6 08:58 03/25i 1 6 08:58 03/2511 6 08:58 03/25i16 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/2511 6 08:58 03/2511 6 08:58 03/2511 6 08:58 03/2511 6 08:58 03/25l'16 08:58 03/25116 08:58 03/25116 08:58 03/25l16 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25l16 08:58 03/2511 6 08:58 03/2511 6 08:58 03/2511 6 08:58 03/2511 6 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/2511 6 08:58 03/25116 08:58 03/2511 6 08:58 03/2511 6 08:58 03/25l'16 08:58 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-51 -8 1 35-98-8 98-06-6 56-23-5 1 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-1 2-8 124-48-1 1 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061 -01 -5 1 0061 -02-6 1 08-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lncDate: 0312812016 05:58 PM Page 11 of31 o Pace Analytical Services, lnc 9800 KinceyAve Su¡te tOO Huntersville, NC 28078 (704)875-9092 Analytical www,paælabs.cun ANALYTICAL RESULTS Project: Pace Project No TFM #2 92290942 Sample: MW-3 Parameters Lab lD Results 92290942003 Units Collected: 03121116 13:16 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1, 1 -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene ïrich lorofl uoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1, 3,S-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Analytical Method: SM 62008 854 ND ND ND ND ND ND ND 2040 525 ND 3920 1 950 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 10.0 40.0 40.0 10.0 10.0 10.0 20.0 10.0 10.0 10.0 20.0 20.0 10.0 03/25116 08:58 03/25l'16 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/25116 08:58 03/2511 6 08:58 1 08-88-3 87-61 -6 120-82-1 71 -55-6 79-00-5 79-01-6 75-69-4 96-1 8-4 v5-bJ-b '108-67-8 75-01-4 179601-23-1 95-47-6 97 100 99 70-1 30 70-1 30 70-1 30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analyt¡cal Services, lnc.. 03125116 08:58 17060-07-0 03125116 08:58 460-00-4 03125116 08:58 2037-26-5 % % o/ Dale: 0312812016 05:58 PM Page 12 of 31 @ Pace Analytical Services, lnc. 9800 KinceyAve Suite'100 Huntersville, NC 28078 (704) 875-e0s2 Analytical www.pacþlabs.coîn ANALYTICAL RESULTS Project: Pace Project No TFM #2 92290942 Sample: MW-4 Parameters Lab lD: 92290942004 Results Units Collected: 03121116 13:22 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 6200B MSV Benzene Bromobenzene Bromoch lorometha ne Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-ch loropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1 ,2-Dichlorobenzene 1,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dich lorodifluoromeih a ne 1 ,1 -Dichloroethane 1 ,2-Dichloroethane 1 ,1 -Dich loroethene cis- 1,2-Dichloroethene trans-1,2-Dichloroethene 1 ,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1 ,1 -Dichloropropene cis-1,3-Dich loropropene trans-1,3-Dich loropropene Diisopropyl ether Ethylbenzene Hexachloro-1, 3-butadiene lsopropylbe nzene (Cumene) Methylene Chloride Methyl{ert-butyl ether Naphthalene n-Propylbenzene Styrene 1, 1, 1,2-Tetrachloroethane 1, 1,2,2-Tetr achloroeth a ne Tetrach loroethene Analytical Method: SM 62008 2.8 ND ND 0.70 ND ND ND ND ND ND ND ND 23.2 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 116 ND ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 0.50 0.50 0.50 0.50 0.50 5.0 0.50 0.50 0.50 0.50 0.50 1.0 0.50 1.0 0.50 0.50 '1.0 0.50 050 0.50 050 0.50 0.50 0.50 0.50 0.50 0.50 050 0.50 0.50 050 0,50 0.50 0.50 0.50 0.50 0.50 2.0 0.50 2.0 0.50 2.0 0.50 0.50 0.50 0.50 050 03125116 06:42 03125116 06:42 03125/16 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125/16 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03t25t16 06.42 03t25t16 06,42 03125116 06:42 03125116 06:42 03t25t16 06.42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125/16 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125/16 06:42 03125116 06:42 03125116 06:42 03125/16 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-51 -8 1 35-98-8 98-06-6 56-23-5 1 08-90-7 7s-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-1 2-8 124-48-1 I 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061 -01 -5 1 0061 -02-6 1 08-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc..Dale: 0312812016 05:58 PM Page 13 of 31 @ Pace Analytical Serv¡ces, lnc. 9800 KinceyAve Su¡te 100 Huntersville, NC 28078 (704)875-9092 Analytical www.paælabs.com ANALYTICAL RESULTS Project: Pace Project No. TFM #2 92290942 Sample: MW-4 Parameters Lab lD Results 92290942004 Units Collected: 03121 116 13'.22 Report Limit DF Received: 03122116 13'.38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1 ,1 ,1 -Trichloroethane 1, 1,2-ïrichloroethane Trichloroethene Trich loroflu orometha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogafes 1,2-Dichloroethane-d4 (S) 4-Bromofl uorobenzene (S) Toluene-d8 (S) Analytical Method: SM 62008 ND ugiL ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 1.8 ug/L ND ug/L ND ug/L 4.6 ug/L 1.8 ug/L 0.50 2.0 2.0 0.50 0.50 0.50 1.0 0.50 0.50 0.50 1.0 1.0 0.50 70-1 30 70-1 30 70-l 30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc. 031251'16 0642 03125116 06:42 03125116 06:42 03125116 06:42 03125116 O6:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 03125116 06:42 1 08-88-3 87-61 -6 120-82-1 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 1 08-67-8 75-01-4 179601-23-1 95-47-6 % To % 98 98 99 0312511606:42 17060-07-0 03125116 06:42 460-00-4 03125116 06:42 2037 -26-5 Date'. 0312812016 05:58 PM Page 14 of31 @ Pace Analytical Services, lnc. 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pacelabs com ANALYTICAL RESULTS Project: Pace Project No.: TFM #2 92290942 Sample: MW-S Parameters Lab lD Results 92290942005 Units Collected: 03121116 13:30 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV Benzene Bromobenzene Bromoch lorometh a ne Bromodichloromethane Bromoform Bromomethane n-Butylbenzene se c- B utyl be n ze n e tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane D ib romoch lo rometh a ne '1,2-Dibromoethane (EDB) Dibromomethane 1 ,2-Dichlorobenzene 1 ,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dichlorodifluoromethane 1 ,1 -Dichloroethane 1 ,2-Dichloroethane 1 ,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1 ,2-Dichloropropane 1 ,3-Dichloropropane 2,2-Dichloropropane 1 ,1 -Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dich loropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1 ,1 ,1 ,2-Tetrachloroethane 1,1,2,2-fetr achloroetha ne Tetrach loroethene Analytical Method: SM 62008 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L 0.50 0.50 050 0.50 0.50 5.0 0.50 0.50 0.50 0.50 0.50 1.0 0.50 1.0 0.50 0.50 1.0 0.50 0.50 0.50 0.50 0.50 050 0,50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 050 0.50 0.50 0.50 2.0 0.50 2.0 0.50 2.0 0,50 0.50 0.50 0.50 0.50 03128116 02:08 03/28/1 6 02:08 03128116 02:08 03128116 0208 03128116 02:08 03i28/16 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128h6 02108 03128116 02:08 03/28116 02:08 O3l28h6 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03/28116 02:08 03128116 02:08 03128/16 02:08 03128116 02:08 03128116 02:08 Q3128116 02:08 03128116 02:08 03/28/1 6 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:QB 03128116 02:08 03128116 02:08 03128116 0208 03/28116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02i08 03128116 02:08 03128116 0208 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 03128116 02:08 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-51 -8 1 35-98-8 98-06-6 56-23-5 1 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-1 2-8 124-48-1 1 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061-0'1 -5 1 006'1-02-6 1 08-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 I 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc.Dale: 0312812016 05:58 PM Page 15 of 31 Project: Pace Project No.: o TFM#2 92290942 Analytical Pace Analytical Services, lnc. 9800 K¡ncey Ave Suite 100 Huntersv¡lle, NC 28078 (704)875-9092www.pac,alabs.com ANALYTICAL RESULTS Sample: MW-S Parameters Lab lD: 92290942005 Results Units Collected: 03/21116'13:30 Repoñ Limit DF Received: 03122116 13:.38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1,1 -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene Trich lorofluorometh a ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogafes '1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Analytical Method: SM 62008 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND 0.50 2.0 2.0 0.50 0.50 0.50 1.0 0.50 0.50 0.50 1.0 1.0 0.50 08 08 08 08 08 08 08 08 08 08 08 08 08 03t28t16 02 03t28t16 02 03t28t't6 02 03128116 02 03128116 02 03t28t16 02 03t28t16 02 03t28t16 02 03128116 02 03128116 02 03128116 02 03t28t16 02 03t28t16 02 1 08-88-3 87-61 -6 120-82-'l 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 I 08-67-8 75-01-4 17960't-23-1 95-47-6 99 98 101 70-1 30 70-1 30 70-1 30 % % % 03128116 02:08 17060-07-0 03128116 02:08 460-00-4 03128116 02:08 2037 -26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc..Dale: 0312812016 05:58 PM Page 16 of 31 @ Pace Analytical Senrices, lnc. 9800 KinceyAve. Suite 100 Huntersv¡lle, NC 28078 (704)875-e0s2 Analytical www.pac,ølabs com ANALYTICAL RESULTS Project: Pace Project No. lFM#2 92290942 Sample: T-1 Lab lD: 92290942006 Results Units Collected: Q3121116 13:35 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No,Parameters Qual 6200B MSV Benzene Bromobenzene Bromoch loromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenze ne tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chloroioluene 1,2-Dibromo-3-ch loropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1 ,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dichlorodifluoromethane 1 ,'1 -Dichloroethane I ,2-Dichloroethane 'l ,1-Dichloroethene cis-'1,2-Dich loroethene trans-1,2-Dich loroethene 1 ,2-Dichloropropane 1 ,3-Dichloropropane 2,2-Dichloropropane '1 ,1-Dichloropropene cis- 1,3-Dichloropropene trans-1,3-Dich loropropene Diisopropyl ether Ethylbenzene Hexachloro-'1,3-butadiene lsopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene '1, 1,'1,2-Tetrachloroethane 1,1,2,2-Telr achloroeth a ne Tetrach lo roethe ne Analytical Method: SM 62008 18.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 10.1 ND ND ND ND ND ND ND ND ND 0.78 0.58 ND 0.58 ND ND ND ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 0.50 0.50 0.50 0.50 0.50 5.0 0.50 050 0.50 0.50 0.50 1.0 0.50 1.0 050 0.50 1.0 050 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 050 0.50 0.50 0.50 0.50 050 050 0.50 2.0 0.50 2.0 0.50 2.0 0.50 0.50 0.50 0.50 0.50 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 Q4:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 O4:23 03128116 04:23 03/28116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04i23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03t28t16 04.23 03t28t16 04.23 03128116 04:23 03t28t16 04.23 03128116 04:23 03128116 04,23 03128116 04'.23 03128116 04:23 03128116 04:23 03128116 04:23 03/28116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 03128116 04:23 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-51 -8 1 35-98-8 98-06-6 56-23-5 1 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 1 06-43-4 96-1 2-8 124-48-1 1 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061 -01 -5 1 0061 -02-6 '108-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc..Dafe: 03128/2016 05:58 PM Page 17 of 31 @ Pace Analyt¡cal Services, lnc. 9800 K¡nceyAve, Suite 100 Huntersville, NC 28078 (704)875-eos2 Analytical www.paceløbs.con ANALYTICAL RESULTS Project: Pace Project No.: TFM#2 92290942 Sample: T-1 Lab lD Results 92290942006 Units Collected: 03/21l16'13:35 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Parameters Qual 62008 MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene I ,1 ,1 -Trichloroethane 1, 1,2-Trichloroethane Trichloroethene Trich lorofl uoromethane '1,2,3-Trichloropropane '1,2,4-Trimethylbenzene '1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogafes 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) ïoluene-d8 (S) Analytical Method: SM 62008 ND ugiLND ug/LND ug/LND ug/L ND ug/LND ug/LND ug/LND ug/LND ug/LND ug/LND ug/L ND ug/LND ug/L 0.50 2.0 2,0 0.50 0.50 0.50 1.0 0.50 0.50 0.50 1.0 1.0 0.50 03t28t16 03128116 03t28t16 03t28t16 03128116 03t28t16 03128116 03t28t16 03128116 03128t16 03t28t16 03128116 03128t16 04:23 04:23 0423 04:23 04:23 04:23 04:23 04,23 04:23 04:23 04:23 04:23 04:23 1 08-88-3 87-61 -6 120-82-1 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 1 08-67-8 75-01-4 179601-23-1 95-47-6 99 99 101 70-1 30 70-1 30 70-1 30 To o/o oÂ 03128116 04:23 17060-07-0 03128116 04:23 460-00-4 03128116 04:23 2037 -26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lncDate: 03/28/2016 05:58 PM Page 18 of31 @ Pace Analytical Services, lnc. 9800 KinceyAve, Suite 100 Huntersv¡lle, NC 28078 (704)875-9092 Analytical wt'wt.pacelabs.cOn ANALYTICAL RESULTS Project: Pace Project No : TFM #2 92290942 Sample: TRIP BLANK Parameters Lab lD Results 92290942007 Units Collected: 03/21116 00:00 Report Limit DF Received: Q3122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene se c-B u ty I be nze ne te rt-Butylbe nzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-ch loropropane D ib romoch lorometh a ne 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1 ,4-Dichlorobenzene Dichlorodifluoromethane 1 ,l -Dichloroethane 1 ,2-Dichloroethane 1 ,1-Dichloroethene cis-1,2-Dich loroethene trans-1,2-Dich loroethene '1 ,2-Dichloropropane 1,3-Dichloropropane 2,2-Dich loropropane 1 ,1-Dichloropropene cis- 1,3-Dichloropropene trans-1, 3-Dich loropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) Methylene Chloride Methyl{ert-butyl ether Naphthalene n-Propylbenzene Styrene 1, 1,1,2-feû achloroeth a ne 1,1,2,2-Ietr achloroeth a ne Tetrach loroethene Analytical Method: SM 62008 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L 0.50 0.50 0.50 0.50 0.50 5.0 0.50 0.50 0.50 0.50 0.50 1.0 0.50 1.0 0.50 0.50 1.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 050 2.0 0.50 2.0 0.50 2.0 050 0.50 0.50 0.50 0.50 03128116 01 34 03t28t16 01 .34 03t28t16 01.34 03128116 01 34 03t28t16 01,34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 O1:34 03128116 01:34 03128116 01:34 03128116 01:34 03128/16 01:34 03128116 O1 34 03128116 01 34 03128116 01:34 03128116 01:34 Q3/28116 01:34 03/28i 16 01 :34 03/28116 01:34 03128116 01:34 03/28116 01 34 03128h6 01134 03128116 01:34 Q3128116 01:34 03128116 01:34 03128116 01 34 03t28t16 01.34 03128116 01 34 Q3128116 01 34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 O1 34 03128116 Q1 34 03t28t16 01.34 03/28116 01:34 03128116 01 ,34 03128116 01 .34 03128116 01:34 03t28t16 01.34 03128116 01:34 03128116 01:34 71-43-2 1 08-86-1 74-97-5 75-27-4 75-25-2 74-83-9 1 04-5 1 -8 1 35-98-8 98-06-6 56-23-5 I 08-90-7 75-00-3 67-66-3 74-87-3 95-49-8 106-43-4 96-1 2-8 124-48-1 1 06-93-4 74-95-3 95-50-1 541-73-1 106-46-7 75-71-8 75-34-3 107-06-2 75-35-4 1 56-59-2 1 56-60-5 78-87-5 142-28-9 594-20-7 563-58-6 1 0061 -01 -5 1 0061 -02-6 1 08-20-3 100-41-4 87-68-3 98-82-8 75-09-2 1634-04-4 91 -20-3 1 03-65-1 100-42-5 630-20-6 79-34-5 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lncDale: 0312812016 05:58 PM Page 19 of 31 @ Pace Analytical Services, lnc 9800 K¡nceyAve. Suite tOO Huntersville, NC 28078 (704)875-9092 Analytical wwwpac,elabs.com ANALYTICAL RESULTS Project: Pace Project No. TFM #2 92290942 Sample: TRIP BLANK Parameters Lab lD: 92290942007 Results Units Collected: 03/21l16 00:00 Report Limit DF Received: 03122116 13:38 Matrix: Water Prepared Analyzed CAS No.Qual 62008 MSV ïoluene '1,2,3-Trichlorobenzene '1,2,4-Trichlorobenzene 1, 1,1 -Trichloroethane I, 1,2-Trichloroethane ïrichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-dB (S) Analytical Method: SM 62008 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND 0.50 2.0 2.0 0.50 0.50 0.50 1,0 0.50 0.50 0.50 1.0 1.0 0.50 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 O1:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03128116 01:34 03/28116 01:34 I 08-88-3 87-61 -6 120-82-1 71 -55-6 79-00-5 79-01 -6 75-69-4 96-1 8-4 95-63-6 1 08-67-8 75-01-4 179601-23-1 95-47-6 98 97 100 70- 1 30 70-1 30 70-1 30 % % % 03128t16 01:34 17060-07-0 03128116 01:34 460-00-4 03128116 01 :34 2037 -26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except ¡n full, without the written consent of Pace Analytical Serv¡ces, lnc..Date'. 0312812016 05:58 PM Page 20 of 31 Project: Pace Project No @ TFM #2 92290942 Analytical Pace Analytical Services, lnc 98OO KinceyAve, Su¡te IOO Huntersville, NC 28078 (704)87 5-9092www.pacþlabs.com QUALITY CONTROL DATA QC Batch: MSV/36117 Analysis Method: SM 62008 QC Batch Method: SM 62008 Analysis Description: 62008 MSV Associated Lab Samples: 92290942001,92290942002, 92290942003,92290942004 METHOD BLANK: 1694501 Matrix: Water Associated Lab samples: 92290942001,92290942002,92290942003,92290942004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Ieú achlo roeth a ne '1 ,1 ,1 -Trichloroethane 1,1,2,2-Tetr achlo roeth a ne 1,1,2-Trichloroethane 1 ,1 -Dichloroethane 1 ,1 -Dichloroethene I ,1 -Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1 ,2-Dichlorobenzene I ,2-Dichloroethane 1 ,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 'l ,3-Dichloropropane 1 ,4-Dichlorobenzene 2,2-Dichloropropane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromoch lo rometh a ne Bromodich loromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorod ifluoromethane Diisopropyl ether Ethylbenzene ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.50 0.50 0.50 0.50 0.50 0.50 0.50 2.0 0.50 2.0 0.50 1.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0,50 0.50 0.50 0.50 0.50 050 5.0 0.50 0.50 1.0 0.50 1.0 0.50 0.50 0.50 0.50 0.50 0.s0 0.50 03/25116 03:35 03/2511 6 03:35 03/2511 6 03:35 03/25116 03:35 03/2511 6 03:35 03/2511 6 03:35 03/2511 6 03:35 03/2511 6 03:35 03/25116 03:35 03/2511 6 03:35 03/25116 03:35 03/25116 03:35 03/25l16 03:35 03/25l16 03:35 03/25l'16 03:35 03/25l'16 03:35 03/25116 03:35 03/25l16 03:35 03/25l16 03:35 03/25116 03:35 03/25l16 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/2511 6 03:35 03/25116 03:35 03/2511 6 03:35 03/2511 6 03:35 03/25l1 6 03:35 03/2511 6 03:35 03/2511 6 03:35 03/2511 6 03:35 03/25l1 6 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 Results presented on this page are ¡n the units indicated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the r¡ght of the result. REPORT OF LABORATORY ANALYSIS This report shail not be reproduced, except in full, without the written consent of Pace Analyt¡cal Services, lncDale. 0312812O16 05:58 PM Page 21 of31 Project: Pace Project No @ TFM#2 92290942 Analytical Pace Analytical Services, lnc, 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-9092www.pacelabs com QUALITY CONTROL DATA METHOD BLANK: 1694501 Matrix: Water Associated Lab Samples: 9229094200j,92290942002,92290942003,92290942004 Blank ReportingParameter Uniis Result Limit Analyzed Qualifiers Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene sec-Buty I benzene Styrene tert-Butylbenzene Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1, 3-Dichloropropene Trichloroethene ïrich lo rofluo rometh a ne Vinyl chloride '1,2-Dichloroeihane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 98 99 98 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % % % 2.0 0.50 1.0 0.50 2.0 0.50 0.50 2.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 1.0 1.0 70-1 30 70-1 30 70-1 30 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/2511 6 03:35 03/2511 6 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25l16 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25i 16 03:35 03/25116 03:35 03/25116 03:35 03/25116 03:35 03/25l'16 03:35 03/25l'16 03:35 LABORATORY CONTROL SAMPLE Parameter 1 694502 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetr achlo roeth a ne 1, 1,1 -Trichloroethane 1,1,2,2-Ielr achlo roeih a ne 1, 1,2-Trichloroethane 1 ,1 -Dich loroethane 1 ,1-Dich loroethene 1 ,1-Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane '1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1 ,2-Dichlorobenzene 1 ,2-Dichloroethane '1 ,2-Dichloropropane 1,3,5-Trimethylbenzene 1 ,3-Dichlorobenzene ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 91 93 85 89 89 95 93 90 87 92 9l 89 88 85 80 88 90 88 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 45.5 46.7 42.7 44.6 44.3 47,5 46.5 44.9 43.7 459 45.5 44.3 440 42.5 39.8 43.8 44.8 44.1 60-1 40 60-l 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 Results presented on th¡s page are in the units ind¡cated by the "Units" column except where an alternate unit is presentod to tho r¡ght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc..DaIe: 0312812016 05:58 PM Page 22 of 31 Project: Pace Project No.: @ TFM #2 92290942 Analytical Pace Analytical Services, lnc. 9800 K¡nceyAve Suite 100 Huntersville, NC 28078 (704)875-9092www.pacêlabs.cqn QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: Parameter 1694502 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1 ,3-Dichloropropane 1 ,4-Dichlorobenzene 2,2-Dichloropropane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromoch loromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene sec-Butylbenzene Styrene tert-Butylbe nzene Tetrach loroethene Toluene trans-1,2-Dichloroethene trans-1, 3-Dichloropropene Trichloroethene Trich lorofluoromethane Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L % o/o o/o 87 87 78 86 86 91 85 87 86 85 72 95 88 94 86 85 87 86 89 86 83 89 88 94 89 87 88 91 91 87 90 86 90 89 74 90 90 89 83 89 91 93 99 100 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 43.7 43.4 39.2 43.2 43.1 45.6 42.3 43.3 43.0 42.3 35.8 47.7 43.8 47.0 42.9 42.6 43.7 43.2 44.4 432 41.3 44.6 44.2 47,1 44.3 86,9 44.2 45.7 45.6 43.5 44.8 43.1 45.0 44.6 37.1 44.8 44.8 44.7 41 ,5 44.3 45.5 46.7 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-t 40 60-1 40 60-t 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-140 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-140 60-140 60-1 40 60-140 60-140 60-140 60-140 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-'140 60- 1 40 60-'140 70-1 30 70-1 30 70-1 30 Results presented on this page are ¡n the un¡ts ¡nd¡cated by the "Units" column except wheÍe an alternate unit is presented to tho r¡ght of tho result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, lnc,.Date: 03128120'16 05:58 PM Page 23 of 31 @ Pace Analytical Services, lnc. 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pacelabs.con QUALITY CONTROL DATA Project: Pace Project No. TFrVi#2 92290942 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1694503 Parameter 92291198010Units Result MS Spike Conc. MSD Spike Conc. I 694504 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual '1 ,1 ,1 ,2-ïetrachloroethane 1,'1, 1 -Trichloroethane 1,1,2,2-Telr achlo roeth a ne 1, 1,2-Trichloroethane 1 ,1-Dichloroethane 1 ,1 -Dichloroethene 1 ,1 -Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-T ¡ichlorobenze ne 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1 ,2-Dichlorobenzene '1 ,2-Dichloroethane 1 ,2-Dichloropropane 1,3,5-Trimethylbenzene 1 ,3-Dichlorobenzene 1 ,3-Dichloropropane 1 ,4-Dichlorobenzene 2,2-Dichloropropane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromoch lorometh a ne Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dich lorod ifluoromethane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride 16.2 17.0 15.6 16.2 16.4 17.1 17,2 15.6 17.4 15.9 16.6 17.4 16.9 15 5 14.6 15.8 16.4 16.1 16.4 157 15.7 16.0 16.0 16.4 16.4 15.6 15.8 14.6 18.4 17,4 16.5 17.1 16.3 18.4 to.z 15.8 15.8 16.5 15.0 16,9 '16.5 '16.9 16.4 32.3 15.1 15.6 19.1 20.5 19.3 19.6 19.5 20.7 20.9 20.2 21 .4 19.8 20.5 20.9 20.1 19.4 17.6 19 5 20.4 19.8 19.7 19.6 18.7 19.7 19.9 20.2 20.1 19.0 18.9 182 21.6 21.2 19.8 209 19.4 21.6 19.2 19.5 '18.8 20.0 17.9 20.3 19.9 21,0 19.9 39.0 1 9.1 18.6 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-'140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-'140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-'140 60-1 40 60-1 40 60-1 40 60-1 40 60-l 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 17 19 21 19 '18 19 19 25 20 22 21 18 17 22 18 21 22 21 18 22 17 21 22 21 21 20 18 22 16 20 18 20 17 16 17 21 17 19 17 18 19 22 19 19 ¿5 18 8l 85 78 81 82 86 86 78 87 80 83 87 84 78 72 79 óz 80 82 79 78 80 80 82 82 78 79 73 92 87 83 85 82 92 81 79 79 82 75 85 82 85 82 80 75 78 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 40 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 40 20 20 96 103 97 98 98 104 104 101 107 99 102 105 100 97 87 98 102 99 98 98 93 oo 100 101 101 95 94 91 107 106 99 104 97 108 vb 97 94 100 89 102 99 105 100 97 95 oa Results presented on th¡s page are ¡n the un¡ts ind¡cated by the "Units" column except where an alternate un¡t ¡s presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analyticâl Services, lncDate. 031281201 6 05:58 PM Page 24 of 31 @ Pace Analytical Services, lnc. 9800 KinceyAve, Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pactlabs.con QUALITY CONTROL DATA Project: Pace Project No.: TFM #2 92290942 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1694503 Parameter 92291 1 9801 0 Units Result MS Spike Conc. MSD Spike Conc. 1 694504 Result MSD Result MS % Rec MSD % Rec MS % Rec Limits RPD Qual n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene sec-Butylbenzene Styrene tert-Butylbenzene Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1, 3-Dichloropropene Trichloroethene Trich lo rofluorometha ne Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 15.8 16.1 16.1 15.9 16.2 15.4 13.5 16.2 16.7 16,2 15.7 15.8 17.5 18.2 20,0 20.0 20.1 19.1 20.0 18.8 16.7 19.7 20,2 19.9 18.9 19.2 20.9 21.6 79 80 81 79 8l 77 68 81 83 81 78 79 88 91 97 100 99 '100 100 101 96 100 94 84 98 101 100 95 96 104 108 96 100 97 23 22 22 19 21 20 21 19 19 21 19 19 17 17 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L % % o//o ND ND ND ND ND ND ND ND ND ND ND ND ND ND 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-l 40 60-1 40 60-1 40 70-1 30 70-1 30 70-l 30 Results presented on this page are in the un¡ts ¡ndicat€d by the "Units" column except where an alternate unit is presented to the r¡ght of the result. REPORT OF LABORATORY ANALYSIS Th¡s report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc..Date: 0312812Q16 05:58 PM Page 25 of 31 Project: Pace Project No.: @ 'tFM #2 92290942 Analytical Pace Analytical Services, Inc. 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-e0e2www.pacclabs.com QUALITY CONTROL DATA QC Batch: MSV/36160 Analysis Method: QC Batch Method: SM 62008 Analysis Description Associated Lab Samples: 92290942005, 92290942006, 92290942007 SM 6200B 6200B MSV METHOD BLANK: 1696048 Matrix: Water Associated Lab Samples: 9229094200s, 92290942006, 92290942007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1 ,1 ,1 ,2-Tetrachloroethane 1, 1,'1 -Trichloroethane 1,1,2,2-fet achlo roetha ne 1, 1,2-Trichloroethane 1 ,1-Dichloroethane 1 ,1 -Dichloroethene 1 ,1 -Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1 ,2-Dichlorobenzene 1 ,2-Dichloroethane 1 ,2-Dichloropropane 1,3, 5-Trimethylbenzene 1 ,3-Dichlorobenzene 1 ,3-Dichloropropane 1,4-Dlchlorobenzene 2,2-Dichloropropane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromoch loromethane Bromodich loromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis- 1,2-Dichloroethene cls- 1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorod ifluoromethane Diisopropyl ether Ethylbenzene ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.50 0.50 0.50 0.50 0.50 0.50 0.50 2.0 0.50 2.0 0.50 1.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 050 0.50 0.50 0.50 050 0.50 5.0 0.50 0.50 1.0 0.50 1.0 0.50 0.50 050 0.50 0.50 0.50 0.50 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128/16 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 0'l:17 03128116 01:17 03128h.6 01i17 03128116 01:17 03128116 01 17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01 17 03128116 01:17 03t28t16 01.17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 Ql:17 03128116 01:17 03128116 01:17 03128116 O1:17 031281'16 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128/16 01:17 03128116 01:17 03128116 01:17 03/28116 01:17 Results presented on this page are ¡n the un¡ts ¡nd¡cated by the "Un¡ts" column except where an alternate unit ¡s presented to the r¡ght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lncDate: 031281201 6 05:58 PM Page 26 of 31 @ Pace Analytical Services, lnc. 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pacelabs.com QUALITY CONTROL DATA Project: Pace Project No : TFM#2 92290942 METHOD BLANK: 1696048 Matrix Associated Lab Samples: 92290942005, 92290942006, 92290942007 Blank Parameter Units Result Water Reporting Limit Analyzed Qualifiers Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) m&p-Xylene Methyl-tert-buiyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene sec-Butyl benzene Styrene tert-Butylbenzene Tetrach loroethene Toluene trans-1,2-Dichloroethene trans-,1, 3-Dichloropropene ïrichloroethene Trich lo roflu oromethane Vinyl chloride '1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-dB (S) ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Yo % % ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 100 99 102 2.0 0.50 1.0 0.50 2.0 0,50 0.50 2.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 1.0 1.0 70-1 30 70-1 30 70- 1 30 03128116 01:17 03128116 01i17 03128116 01:17 O3128116 01 17 03128116 01117 03t28t16 01',17 03128116 Q1:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 O3128116 0'l:17 03128116 01:17 03128116 01:17 03128116 01:17 03128116 01:17 03128/16 01:17 03128116 01:17 03128116 01:17 LABORATORY CONTROL SAMPLE: Parameter 1 696049 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1, 1, 1,2-Tetrachloroethane 1, 1, 1 -Trichloroethane 1,1,2,2-Tetr achlo roetha ne 1, 1,2-Trichloroethane 1 ,1-Dichloroethane 1 ,1 -Dichloroethene I ,1 -Dichloropropene 1,2,3-Trich Iorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-ïrimethylbenzene 1,2-Dibromo-3-ch loropropane 1,2-Dibromoethane (EDB) '1 ,2-Dichlorobenzene 'l ,2-Dichloroethane 1 ,2-Dichloropropane 1, 3,5-Trimethylbenzene 1.3-Dichlorobenzene 47.5 50.3 46.2 47.3 47.8 48.5 50.6 47.0 492 47.2 47.9 48.7 48.0 45.6 43.1 46.6 47.5 46.9 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-l 40 60-1 40 60-l 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 95 101 92 95 96 97 101 94 98 94 96 97 96 9'l 86 93 oÃ 94 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Results pr€sented on this page are ¡n the units ¡ndicated by the "Units" column except where an alternate unit is presented to the r¡ght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Serv¡ces, lnc.Dale: 031281201 6 05:58 PM Page27 of31 @ Pace Analytical Services, lnc. 9800 K¡nceyAve Suite 100 Huntersv¡lle, NC 28078 (704)87s-9092 Analytical www.pacelabs.con QUALITY CONTROL DATA Project: Pace Project No.: TFM#2 92290942 LABORATORY CONTROL SAMPLE Parameter I 696049 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1 ,3-Dichloropropane 1 ,4-Dichlorobenzene 2,2-Dichloropropane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromoch lo romethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-'1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorod ifluoromethane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene lsopropylbenzene (Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene sec-Butylbe nzene Styrene tert-Butylbenzene Tetrach loroethene Toluene trans-1,2-Dichloroeihene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 1,2-Dich loroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 94 92 97 92 9t 95 95 oÃ 93 92 128 98 94 96 94 96 95 95 95 96 84 103 95 99 94 93 103 91 95 92 92 92 92 95 77 94 95 96 93 92 98 102 102 101 99 ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugiL ugiL ug/L ug/L o/o o/o % 46.9 46.0 48.4 46.2 45.6 47.5 47.3 47.5 46.7 45.9 64.1 49.0 47.0 48.0 47.1 48.0 47.7 47.5 47.6 48.2 42.2 51.3 47.3 49.4 47.1 93.4 51.5 45.4 47.6 45.9 46.2 45.9 45.8 47.7 38.6 46.8 47.5 48.0 46.3 45.9 49.0 50.9 60-1 40 60-1 40 60-140 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-'140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-l 40 60-140 60-140 60-140 60-140 60-140 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-l 40 60-l 40 60-l 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-1 40 60-140 60-140 60-1 40 60-140 60-1 40 60-1 40 70-1 30 70-1 30 70-l 30 Results presented on this page are ¡n the un¡ts ¡ndlcated by the "Units" column except where an alternat€ unit ¡s presented to ths r¡ght of the result. REPORT OF LABORATORY ANALYSIS Th¡s report shall not be reproduced, except in full, without the written consent of Pace Analytical Serv¡ces, lnc.Date: 0312812016 05:58 PM Page 28 of 31 @ Pace Analytical Services, lnc. 9800 K¡nceyAve Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical www.pacelabs com QUALIFIERS Project: Pace Project No. TFM #2 92290942 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentrat¡on above the adjusted method detection l¡mit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1 ,2-Diphenylhyd¡azine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used io calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Noi Calculable, SG - Silica Gel - Clean-Up U - lndicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. the result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the cunent list of accredited analytes, TNI - The NELAC lnstitute. LABORATORIES PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except ¡n full, w¡thout the written consent of Pace Analytical Services, lncDale. 031281201 6 05:58 PM Page 29 of 31 Analytical Pace Analyt¡cal Services, lnc. 9800 KinceyAve Suite 100 Huntersville, NC 28078 (704)875-9092www.pacêldbs.cotn QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: TFM #2 92290942 Lab lD Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92290942001 92290942002 92290942003 92290942004 MW-1 MW-2 MW.3 MW-4 MW-5 T-1 TRIP BLANK SM 62008 SM 62008 SM 6200B SM 6200B SM 6200B SM 62008 sM 62008 MSV/36'117 MSV/36117 MSV/36117 MSV/361t 7 MSV/36160 MSV/36160 MSV/36160 92290942005 92290942006 92290942007 REPORT OF LABORATORY ANALYSIS Th¡s report shall not be reproduced, except in full, without the wr¡tten consent of Pace Analytical Services, lnc.Date: 0312812016 05:58 PM Page 30 of 31 ,4FaæAnaMtcalC HAI N-O F-GUSTODY / Analytical Request Docum entThe Chain-of-Cuslody ¡s a LEGAL DOCUMENT. All relevant felds must bê compleled accuratelySeçtion Clnvoice lnlormãdon:(Ðo(oc)ooo_Secl¡on ASectíon B1Cl¡ent lnlol'mlion:Project lnfomat¡on:4321:ltEr¡lFII765121'l4301RædADDITþI,¡AL COI¡MENÍSMW-1SAMPLE IDOæ ChaÉcter per box.lÀ-z,o-st,-).Sample lds mÉr,b{¡ un¡qmUTRIX$r6dd@orñcooEwIOLo1lsTrio BlankT-1MW-5MW-4MW-3MW-2ùoooÉtsWTWTWTô=oooodooùÀÞWTWfWT-Ù., ¿¿/ÅDATETIMFSTARTDATEI/ll/,zt-pTIMEENOCOLLECTEDi):zztj;tl¡y,ttE:¿'atv:15t)'.30ToTFM #2*Ordtr#:TozItsoooùFc//LOATE4Ll71É@ztszoooztlqÞôoSIGNATURE ofofG,9.'t*.TIMEozI+To-LI+II-oz'woNaNoz6cIPreservativesÉoName of SAMPLER:z6ol-ao6-àocooN@()oxxxxxXxACCEPTED BY' AFFIUAT¡ONIÅtl tPaæMmags:Paæ OuoteAddress.Company Name:DATEiø-æTIMESAiIPLER NAME AND SIGNATUREz.g-9c(Jıpof2- t.().çùUFVcIsz& B¿^J;9ı=J,;oaRæulatorvAqenclNCf''påDoltzz9.2qzrn?D0 [,0ù5ootco3sÂ.uPtEcoNDmoNS.9hE=Ø a'-hl0$ i9229Ø942ililllllllllllIIll lll9223ø942