WS-6081_22332_CA_RMR_20150629

MONITORING REPORT
TEXACO FOOD MART #2
17OO COTTON GROVE ROAD
LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA
INCIDENT NO. 22332
SHIELD PROJECT NO. IOO1289
August 2014 through June 2015
Contact:
David Holding
(704) 786-4t27
Site Risk Classification: High Risk (Hl55D)
Land Use Category: Residential and commercial
Release Discovered: February 8, 1999
Potential Release Source(s): Unknown
Site Latitud ez 35o46'41" North
Site Longitude: 80"I5'35" West
Quantity Released: Unknown
Release Cause: Unknown
Responsible Party:
Techno, LLC for Holding
Brothers, Inc
P.O. Drawer 647
Concord, NC 28026
Consultant:
Shield Engineering, Inc.
4301 Taggart Creek Road
Charlotte, North Carolina 28208
Contact:
Flora J. D'Souza
[phone]
Property Owner:
United Oil of the Carolinas, Inc.
P.O. Box 68
Gastonia, North Carolina 28053
Contact:
David Dulmage
(704) 79r-0123
+.'2r
Flora J. D'Souza, CHMM
Project Manager i"
¡X¡ì
'í
June 25,2015
TABLE OF CONTENTS
1.0 DISCUSSION OF SAMPLING RESULTS
2,0 CONCLUSIONSANDRECOMMENDATIONS
3.0 RECOMMENDATIONS
4.0 LIMITATIONS
Page No.
I
4
4
5
Figure l:
Figure 2:
Figure 3:
Figure 4:
Figure 5:
Figure 6:
Figure 7:
LIST OF FIGURES
Site Location Map
Site Map
1500' Radius Map
Groundwater Elevation Contour Map
Benzene Isoconcentration Map
1,2-Dichloroethane (DCA) Isoconcentration Map
Ethylene Dibromide (EDB) Isoconcentration Map
LIST OF TABLES
Summary of Adjacent Property and Water Supply Well Owners
Summary of Well Construction and Historical Groundwater Elevation Data
Summary of Historical Analytical Results - Groundwater Samples
APPENDICES
Appendix A: Laboratory Report - Groundwater Samples
H:\Projects\2000\100 1289 - TFM#2\Reports\ARMR June 20I SVRMR June 201 5.doc
Table l:
Table2:
Table 3:
Texaco Food Marl #2
Lexington, Davidson County, North Carolina
lncident#:22332
Monitoring Reporl
June 25, 201 5
Page I
I.O DISCUSSION OF SAMPLING RESULTS
1.1 Site Monitorins Requirements:
Site Location Mqp.
Site Map:
See Figure I
See Figure 2
Site Monitoring Requirements
Based on CAP and/or NORR
Sample Point
Type
Total Quantity of Previous
Sample Points and Their
Identifïcation
Required by NCDENR to be
Monitored and Sampled per CAP
and/or TA
Monitoring
Wells
10
(MW-l through MW-6, and T-1
throueh T-4)
6 (t)
(MW-l through MW-5 and T-l)
Vy'ater Supply
V/ells
13 (r)
(WSV/- I through WSV/- I 3)
0
(l) Individualwells identified by NCDENRfoT specific sampling at this time.
(2) Number of wells located within I ,500 feet of site.
1,2 Summary of Analytical Results and Free Product Thickness(s):
1,2.1 Date(s) of Sampling Event: IliIay 20,2015
1.2.2 Existing Area Receptors:
A receptor survey was conducted in 2001 as presented in the CSA report datedMay 2002
and the CAP dated October 2003.
Refer to the following Tables and Figure(s) for information and locations of area receptors
identified.
Refer to Figure(s).' Figure 3
Rrfe, to Tables(s).' Table I
1,2.3 Groundwater Flow Direction:
o The groundwater flow direction is to the north-northeast.
Current andlor Historical Groundwater Elevation Data is included in the following Table and
Figure:
Refer to Tqble:
Refer to Figure
Table2
Figure 4
Texaco Food Mart #2
Lexington, Davidson County, Norlh Carolina
lncident#:22332
Monitoring Repoft
Iune 25,2015
Page 2
1,2,4 Free Product:o Free Product Detected During this Reporting Period?: No
1.2.5 Groundwater Analytical Results:
. Sampled Points and Analytical Methods:
(l) Pre-Approval Task Authorizqtion TA-22332-l 4
o Laboratory Used: Pace Analytical Services Inc. Huntersville, NC
o Current Groundwater Analytical Data:
The following monitoring wells and other points were sampled during this reporting
period.
During this monitoring period, Shield conducted bi-weekly air-sparging events in air
sparge wells AS-l and AS-4 using a portable air-sparging unit to facilitate reduction of
dissolved phase concentrations in MW-2. Air sparging was conducted on AS-l for
approximately 6 hours a day on February 23, March 10, March 24,March 31, April 16,
and May 5,2015. Air sparging could not safely be conducted in MW-2 during the air
sparging visits because those events were conducted during business hours and MV/-2 is
in a high traffic area neaÍ the dispenser island.
On May 20,2015 groundwater samples were collected from monitoring wells M'W-l
through MW-5 and T-1. One or more concentrations of analytes including benzene,
ethylbenzene, toluene, total xylenes, methyl tert-butyl ether (MTBE), naphthalene,
isopropylbenzene, n-propylbenzene,l,2-dichloroethane (1,2-DCA), ethylene dibromide
(EDB), 1,2,4-trimethylbenzene, and 1,3,5-trimethylbenzene were detected at
concentrations above the 154 NCAC 2L Groundwater Standards (2L Standards) in wells
including MV/-1, MVy'-2, MW-3, M'W-4, and T-1. Concentrations of analytes including
benzene, 1,2-DCA, and EDB were detected at concentrations above the North Carolina
Department of Environment and Natural Resources OICDENR) gross contaminant levels
(GCLs) in MW-2.
Sampled Points and Analytical Methods
for this Reporting Period
Based on CAP and Pre-Approval Task Authorization Sampling Requirements
Type Points Sampled during this
Reportinq Period
Analytical Methods
Monitoring
Wells
(6; r'r
(MW-l through MV/-5 and T-1)
o EPA Method 62008
Refer to the following Table and Appendix for current groundwater analytical data.
Texaco Food Mafi #2
Lexington, Davidson County, Nofih Carolina
lncident#:22332
Monitoring Repoft
June 25,2015
Page 3
Refer to Table: Table 3
Refer to Appendix.' Appendix A
Historical Groundwater Analytical Data:
Total dissolved phase petroleum constituent compounds concentrations in monitoring
well MW-2 have decreased in comparison to July 2014 data.
Refer to the following table(s) for historical groundwater analyti cal data.
Refer to Table(s).' Table 3
o Dissolved Phase Plume Size and Location:
The on-site dissolved phase plume is irregularly shaped and has an approximate length of
I 05 feet and width of I 20 feet based on the benzene concentrations above 2L Standards.
The dissolved phase plume that is above the NCDENR GCLs is approximately 25 feet by
20 (Figure 5). The plume for constituents that are above the GCLs is located as shown
on the following figures.
Refer to Figure(s).' Figures 5 through 7
Proximity of Plume to Nearest Receptor(s)a
Based on the receptor survey conducted in 2001, there were three (3) confirmed drinking
water supply wells and six (6) inactive supply wells located within 1,000 feet of the
source area. The closest drinking water supply well (WSV/-l) is located approximately
450 feet south (hydraulically upgradient) of the site. No surface water bodies were
observed in the field or on the topographic map within 5O0-feet of the source area.
Refer to Figure
Refe, to Table:
Figure 3
Table 1
o
1.2.6 Other Field Data Collected:o No additional field data was collected.
Predictive Rate of Contaminant Transport:
The contaminant plume has been fairly stable or immobile over the past several years,
and reducing in concentration.
Refu to Table(s)Tables 2 and3
Texaco Food Mart #2
Lexington Davidson County, North Carolina
lncident#:22332
Monitoring Report
June 25, 201 5
Page 4
2,0 CONCLUSIONS
o During this reporting period, air sparging was conducted on AS-1 and AS-4 for
approximately 6 hours per day on February 23,March 10, March 24,March 3 I , April I 6,
and May 5,2015.
o Free product was not detected in site wells during this reporting period,
¡ Dissolved phase petroleum constituent compounds were detected in concentrations above
2L Standards in monitoring wells MW-l through MV/-4 and T-l.
. Dissolved phase concentrations of benzene, 1,2-DCA, and EDB were above the
NCDENR GCLs in MW-2.
o Dissolved phase petroleum constituent compound concentrations decreased in
monitoring wells MV/-2, MVy'-3, and T-l since July 2014. Dissolved phase petroleum
constituent compound concentrations slightly increased in monitoring wells MW-l and
MW-4 since July 2014. The plume seems to be reducing in concentration.o In 2001, three (3) privately owned drinking water supply wells were identified within a
1,000-foot radius of the source area with the nearest confirmed drinking water supply
well approximately 450 feet hydraulically upgradient from the source area,
o Based on a conversation with Michael Rogers of the NCDENR on November 16, 2010,
since'WSV/-1 is approximately 450 feet updradient of the site and the property owner
would not allow Shield or NCDENR to sample their supply well, the Texaco Food Mart
#2 site would likely be reduced to low risk if soil excavation was completed to remove as
much soil as feasibly possible and if MW-2 groundwater concentrations were below
GCLs.o Soil excavation around boring SB-8 was conducted on February 28, 2012 via over
drilling with l4-inch outside diameter hollow stem augers around the boring. Details of
the excavation were previously submitted to the NCDENR in the Monitoring Report
dated October 23,2012.
3.0 RECOMMENDATIONS
It is recommended that bi-weekly air sparging be conducted to reduce the groundwater
concentrations to below GCLs, with NCDENR and Trust Fund approval.
It is requested that the NCDENR consider a Mobile Multi-Phase Extraction (MMPE)
event at the site to expedite cleanup.
Once MW-2 is below the GCLs we will request a "no further action" determination from
the NCDENR.
a
a
a
Texaco Food Maft #2
Lexington Davidson County, North Carolina
lncident#:22332
Monitoring Report
June 25, 20 I 5
Page 5
4,0 LIMITATIONS
Shield has performed environmental services at the subject site on behalf of Techno LLC for Holding
Brothers, Inc. Shield has performed this scope ofwork as an independent contractor/consultant using
reasonable care and skill in accordance and consistent with customary industry standards of
engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive
standard of care that can be applied to measure Shield's performance of the work. No other
warranty, expressed or implied is made or intended by Shield.
The report has been prepared for the exclusive use by Techno LLC for Holding Brothers, Inc. All
recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's
knowledge, opinion and belief, based upon information obtained during this scope of Techno LLC
for Holding Brothers, Inc, and Shield. Conclusions are provided with the understanding that Shield
is presenting information and not rendering legal advice. If such advice is needed, legal counsel
should be consulted. It is the responsibility of Techno LLC for Holding Brothers, Inc. under advice
of its counsel to noti$ the appropriate federal, state, or local public agencies as required by law; or
otherwise to disclose in a timely manner, any information that may be necessary to prevent damage
to human health, safety, or the environment.
Compliance with recommendations provided as part ofthis report in no way assures compliance with
federal, state and/or local laws, regulations, andlor requirements. Anal¡ical datahas been obtained
from Pace Analytical Services Inc. This information, to the extent that it was relied on to generate
this report, is assumed to be correct and complete, The work performed in conjunction with this
report and the data developed are intended as a description of available information at the dates and
specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or
recommendations with respect to any conditions that were knowingly or unknowingly withheld,
concealed, hidden, or in any way not disclosed or observable at the time of this scope of work.
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ê SHIELD ir."iFff*-tw sh¡6ld64iædqmINC.
ENTRATI
ETHYLENE
rsocoNc
IDE IEDB)
ON ù1AP
,
TEXACO FOOD MART #2
ITOO COTTON GROVE ROAD
LÐ(INGTON, NORTH CAROLINA
SHíELD # 100t289
DRAWN BY : RBSDATE: 06/03/15
FIGURE : 7SCALE : AS SHOWN
f
ASPHALT
mo
a5-5o¡O ovE-6 T.4 VE-7(Ns)
as-6¡
REGULARusf
REGULARUST
5UPK4EUST
TANK PIT
TEXACO
FOOD MART
VE.3
)
(ND)
ASPHALT
KEROSEÑE (Ns)
mw-+ o
or.r.
DIESEL Usf
nw.¿ O
(Ns)
VACANI LOf
!OISPEÑsER OI9ENSER !orsrrlsen
DIsPENSER
!o,rrr*** o'tt.***!!orrrrutrt
ô
d
U
oÉ(,zo
Fot)
æ
Ut-
=oÉ,
\Jz.
(D r,,tw-z(Ns)
lHj' o
GASOLINE UST
zo
GASOLINE USf
GÀSOLINE USfO r¡,ttp-z
(Ns)
o
MW-1(Ns)
ACCESS ROAD CEDAR LANE ROAD (D reup.r
(Ns)
LEGEND:
+ LIGHT POLE
ø PowER PoLE
ELECTRICAL LINE
SÀNITÂRY SEWER LINE
PRODUCT LINE
WENDY'S PROPERÍY
()
o
TEXÂCO FOOD MARI MONITORING WELL
ÍEXÀCO FOOD MART DEEP MONITORING WELL
o A!iOCO RUSHCO #3 MONITORING WELL
ALL DATA TAKEN FROM THE PHASE II LIMITED SITE ASSESsMENT
REPORT PREPARED BY CBM ENVIROMENIAL SERVICES, INC,
DATED 4/tól01.
O VE VAPOR EXTRACTION WELL
I AS ¡R SPÂRGING WELL
(uglL) MICROGRAMS PER LITER
14511 ETHYLENE OIBROMIDE (EDBI CONCENIRAIION (U3/L)
[NDl ETHYLENE DIBRoMIDE (EDB) coNcENTRATloñ ñoT USED lN coNToURING (usll)
ETHYLENE DlERoMlDE fEDB) lsocoNcENTRATloN LINE fug/L)
- ETHYLENE OIEROMIDE (EDB) ISOCONCENTRÂTION LINE (ug/L) EXCEEDING GRO55 CONT}!\,iINANT LEVELS (GCLSI
INDI NOT DETECTED . BELOW LABORATORY METHOD DETECTION LIMITS
(Ns) NOT SAMPLEo APPROXIMATE GRAPHIC SCALE
0 15 30
AMOCO
RUSHCO #3
NOTTS: 1- GROUNDWÂTER SAMPLES COLLECTEO ON 05/20115
2. ALL LOCATIONS ARE APPROXIMATE,
3. CONTOUR INTERVALS AS sHOWN,
PÀR(IÑG AREÀ
SCALE:1in.=30ft
Table: ISummary of Adjacent Property and Water Supply Well OwnersTexaco Food Mart#21700 Cotton Grove Road,Lexington, North CarolinaNCDENR Incident # 22332Notes: Ft BCS = fèetground suúàce- Addrcss of well. Property owner's address is 500 Maegeo Dr., Lexington- Of'the ploperty owners without PWS hook ups, only John Tetter is interested in be added to the P\ryS. Other properly owners indicated that they arc not interested at all.NA - Not AccessiblePublicWaterSystomhook upNoYesYesNoYesYesYesNoYesUnk.Unk.YesNoDistancefromsor¡rce areaofrelease(ft.)450700650'985',750','760'79s',1025',1090'I 100'tt'l 5'800'850',WellScreenInterval(¡toyfr.BGS)???,l??,l???),l?WellCasiugDepth(fr. BGS),|,|2???,l?,)),l,,|TÞeofWell4",|???,l,l4,l,,l?,WellDepth(ftBGS)185,l,|?,),l,|>100,ì,)?,l,ìWell UseDrinkingNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseDrinkingNot in UseNot in UseNot in UseIrrigationDrinkingPhoneNumber336-351-25lt336-357-5231336-357-2659336-3s1-2916336-249-3266336-357-248s336-357-2565NANANANANANAAddressP.O. Box 284 Lexington, NC104 Fuller Rd., Lexington, NC106 Fuller Rd., Lexington, NC115 Cedar Ln., Lexington, NC6 Mayfair Rd., Lexington, NC*Box 8 Mayfair Rd., Lexington,NCBox 100 Mayfair Rd.,Lexington, NCBox 108 Mayfair Rd.,Lexington, NCBox 107 Mayfair Rd,Lexington, NCBox 103 Mayfair Rd.,Lexington, NC1724 Southview Rd.,Lexington, NC102 Mayfair Rd., Lexington,NC104 Mayfair Rd., Lexington,NCWell Owner/ User (indicatewhich)Flowerest O. LoppPaul & Stella BakerMargaret H. FullerHoyle R. SmithEfird E. Jr. & Kay SWilson(owner)Abe CassidyMrs. Samuel C. DavisMaxine C. HouckThomas FrankJames G. HendersonRay S. & Irene MusgraveAubrey & Helen BrewerJohn T. TetterWell #wsw-lwsw-2wsw-3ws'w-4v/sw-5wsw-6wsw-7wsw-8v/sw-9v/sw-10wsw-11wsw-12wsv/-13H:\ProjectsV000\1001289 - TFM#2\Repots\ARMR Aug 2014\Water Supply Well Inf-onnation Table.doc
Table 2:
Summary of \ilell Construction and Historical Groundwater Elevation Data
Texaco Food Ma¡t#2
1700 Cotton Grove Road, Lexington, North Carolina
NCDENR lncidentfl22332
Field Measurements Field Calculations
\ilell ID Date
I nstalled
Top of
Casing
Elevation
(feet)
Well
Diameter
(inches)
As-built
Depth
(feet)Interval (feet)
Screened Gauging Date
Total
Depth
(feet)
Depth to
Static
Water
(feet)
Depth to
Free
Product
(feet)
Diff. Between
As-Built and
Measured Total
Depth (feet)
Ground-water
Elevation
(feet)
tu/lu/ul J5.UU ¿4.U9 NA U /).9 I
U I t.Et04t22^t2 J5 00 2¿ t3 NA
tl/t9/(17 35,01 2l,69 NA -U.U I t6 il
03tíJ4t[9 34 93 19,68 NA 007 StJ JZ
1l7n9n3 15 07 r7 55 NA -0.07 82.45
u'u tU t4 35.U t I t.3¿NA -0.07 82 68
uS/zulr5 J5 U/rð 0u NA -U.U /ül4u
MW-t 0ilJvut IUU.UU 2 J5 ¿u-35
t0/t0/01 J5 00 )L )')NA U 't5 tE
tJ4tzzttJZ 35,U0 22 tJ$NA U 't7 9',2
tln9/[7 34.75 23.84 NA f ) ?{76 35
uJ^14/t19 J4,ı)l9.6¿NA U.J)80,57
[MzAt lZ J4 9l tð 4E NA UU9 ðt /t
u7D9nJ J4 94 l't 53 NA UU6 E¿ 66
[1Ãl/I4 '34.94 t't,28 NA 0.06 82,9t
05/2t /15 34 94 ì8 65 NA 0.06 8ì 54
MW-Z uil3t/0t t0u t9 '¿J5 ')0-35
ru/ru/ur J).UU ¿4 2t NA U t5 9¿
lt4t22tlt2 J5 UU ¿l9J NA U lö 26
tUt9tuT J5 UJ '¿4 |)NA -0 0J t6 09
UJ/IJ4IIJ9 34,96 t9.35 NA 004 8U 84
07 n9t13 3 5,08 l1 23 NA -0 08 82.96
07^ln4 35 08 n05 NA -0 08 83 14
u5/¿ul I 5 J5.Uð lð 4ð NA -U,Uð EI
MW-J I U/Uð/U I IUU IY ¿J5 IU-J)
tu/tu/ul J5.UU ¿4 NA U /Ó UE
tJ4t22ilJZ J5 UO 2t 9t NA 0 't8.¿8
lUt9t|.|]34 8l 23.88 NA U ì9 75 52
[3^t4/l.19 34 74 19,90 NA rJ.26 79,50
[7/2[/Í)34.72 l8 57 NA U.¿E ðU ðJ
utItyttJ 34.9U I t.9U NA U. IU EI5Uu]il 1il4 34 9tJ I /,ôU NA u. t0 EIEO
u5/zul15 J4 9IJ IE óó NA 010 E0 74
IItW-4 I tr/t)¿llr., I 99.4U J5 ¿u-35
tJ4tzztuz J) UU 23 34 Niq.U /b, ð)
tln9t|.ì7 35 07 24.16 NA -0 07 t5 63
03/04t09 35 09 2t 17 NA -U UY
u il tvilJ J5 t¿19.U¿NA -u t¿ðl,J/
u7ilUt4 J5.t¿Ið /E NA -tJ t¿EIÓI
u5/zull 5 35 t2 ¡9 9U NA -0 t'¿ll0 49
MW-5 04t04t02 IUU 39 2 35 ZtJ-35
[qt ¿¿^J¿I).UU ¿J U¿NA U
rt/19t07 25 00 NM NA U NM
uJtu4tu,NM NM NM NM NM
MW-6 04to4t02 tuL4¿2 25 I 5-25
I U/t U/Ul 90 00 '¿4 93 NA ()15 26
u4tzzt[z 90 00 22,tJ6 NA 0 78 l3
tul9tlJ7 86 7t 2t 59 NA 3.29 18 76
03/04/09 65 8Z t9 52 NA 24 18 ðr.r. ¿lJ
tJ1/19n3 bo ð4 ð4 NA ¿3 t6 E¿ ¿I
vilIUl4 bo ð4 tð 5ð NA ¿J t6 Etu
u5/zul I 5 ôb ð4 I9 JÓ NA '¿J t6 EU 99
tutu9/utt-l IUU J5 ¿9U 85.5-9U
L NM = Not Measured
2. NA : Not Applicable
Sum of well conslruct¡on and historical groundwaler elevation
Table 3:
Summary of Historical Analytical Results-Groundwater Samples
Texaco Food Mart #2
1700 Cotton Crove Road, Lex¡ngtor, North Cârol¡na
NCDENR lncident # 22332
Analyt¡cal Method->f,PA Method 601/602
EPA
Method
504.1 or
62008
EPA
Mêthod
625 or
62008
MADEP
VPH
MADEP VPH &
EPH
IVIADEP
EPH
MADOP VPH &
EPH
Èó ts
X
F
c
à.
E
n
€
E z
O
Q
I
U
Q
?
il
Q
o
O
O
?
I
aåI
I
O
O
l5A NCAC 2L.0202
Standârd->I ó00 600 s00 20 7n 0.,t 0.02 6 400 åtb =
700 t0,000 Éd:
200
r5A NCAC 2L.0t 15
Cross Contâm¡natlon 5,000 260,000 84,500 E5,500 20,000 70,000 400 50 6,000
nplL nalL ug L us L
MW-l 01t3t/0t ND 53 .140 rJ00 NR NR ND 0.96 75 ND 3,470 ND 2,780
04/30/03 t2 t40 r3 t,4?0 NR ND ND NR 210 NR NR NR NR
l/19t0'l ¡19.5 647 t19 t,2 t0 ND ND NT)ND 107 ND 665 ND 825
03/04/{)9 53.7 2R4 t65 821 ND ND ND ND 161 4ó8 6,t70 ND 2,200
0't/t9/13 69.4 874 2 761 74 ND ND ND il4 NR NR NR NR
01/ I t/t4 17.2 0 t32 790 47 ND ND ND NR NR NR NR
05/20/ l5 3 145 8f6 52 ND 2 0.61 143 NR NR NR NR
MW-2 07/l t/0 I 13,000 38.000 3,600 t6,000 NR NR t,200 720 NR 8r,000 28,000 NR 9.100
04/:10/0:l r2,000 29,000 2,800 ló,700 NR ND r,700 ND 1,400 NR NR NR NR
I t/ t9/07 t4,900 34,200 3,090 rE,400 6,090 ND 1,t50 ND r,090 60,t00 7r,600 :108 2ó,630
03104/09 I 1,700 21,200 2,250 t4,500 1,600 ND ND ND 238 59,J00 58,930 ND 8J40
06/28il2 8,930 t?.800 1,7ó0 t0,950 1,120 144 t,090 635 914 NR NR NR NR
0ilt9/ t3 r2,600 24,300 2,200 ISJEO 7,550 194 r,330 773 1260 NR NR NR NR
07/IIl4 10,800 2 1,300 1,9r0 r r,980 7,{X0 142 I,2IO 663 r070 NR NR NR NR
OSt2O/ I 5 6,410,t2,600 989 ó.160 4,830 90.9 7t3 451 898 NR NR NR NR
MW-l l0/t0i0t 120 4,100 r,800 8,600 NR NR ND 95 360 ND I t,990 ND I 1,710
04/30/03 100 3,000 l,ó00 8,800 NR ND ND ND 660 NR NR NR NR
I t/t9101 ND 4,E50 2,t90 r 3,600 ND ND ND 1,2 5lJ NR 3460 ND 2,440
03/t)4/09 ND 3,430 2,090 r 1,400 ND ND ND ND r,520 5,5ó0 40,926 ND I 1,780
01/t9/t3 1,250 1,420 8.060 7l ND ND ND 144 NR NR NR NR
07/ | il4 55.r r,r00 r,100 1270 ND ND ND ND 831 NR NR NR NR
05/20/t5 t1.2 9s4 r,250 6,7r0 94 ND ND ND 88r NR NR NR NR
t0/t0/0t ND ND ND ND NR ND ND ND ND NR NR NR NR
04/10/03 ND ND ND ND NR ND ND NR ND NR NR NR NR
|il9t0'l ND ND ND ND 2l ND ND ND ND ND ND ND ND
t)3/04/09 ND 52 ND 6 43 ND ND ND 12 3 ND t86 ND ND
0t/20/lt)ND ND ND ND ND ND ND ND ND ND ND ND
01/ t9/l3 1.9 ND ND 46 40 ND ND ND ND NR NR NR NR
tJ1il t/14 2,7 ND ND 72 65.9 ND ND Nf)ND NR NR NR NR
05/20/ t5 2.1 ND ND 67 106 ND ND ND ND NR NR NR NR
MW5 04/30/03 ND ND ND ND NR NR ND NA ND NR NR NR NR
I t/ t9/07 ND ND ND ND ND ND ND ND 4l 144 ND ND ND
03104/09 ND t9 ND ND ND ND ND ND 29 ND ND ND ND
01/ t9/ t3 ND ND ND ND ND ND ND ND ND NR NR NR NR
01/|^4 ND Nf)ND ND ND ND ND ND ND NR NR NR NR
05/2tJ/15 ND ND ND ND ND ND ND ND ND NR NR NR NR
T I 0/ L0/0 l 390 78 94 140 NR NR 44 2.8 24 8s0 210 ND 250
04/10/01 l1 28 ND t41 NR ND 8.1 ND lr NR NR NR NR
Ivt9/01 43.8 ND ND ND 2r0 ND t.1 ND ND ND ND ND ND
03104/09 20.7 ND ND ND ND ND 25.7 ND r4..t 320 ND ND ND
01il9/ 13 r35 306 62 2tI 8l 24 23.9 ND 1.7 NR NR NR NR
07/IIt4 t12 059 55 ll3 2l 23 .t3.7 ND 39 NR NR NR NR
05/201 15 il5 054 t62 32 43.9 ND :Ì3 NR NR NR NR
Not6:
ugll = Mieogrm po lito. ND : Belolv Method Detætion Linit
NR = Analys¡s not rcquGted Bold numbeñ excæd t5A NCAC 2L 0202 standar.ds¡54 NCAC 2L 0202 = NCDENR Standard Ståtute lor nonrisked bsed mü¡mum âllowab¡e @ntainmflt @nmtrat¡on ¡n groundwatø
Itdl¡cized Bold ^Mhæ oxcæd Grcss Contminmt lads = As p6ølod in NCDENR icuidelin6 for Ass6smñt bd Com¡ivc Ac¡ion,' dated July 15, 2008, cfræ¡ivc Jmuary 2010
Other detected ilalytes can be seen in the an¿lylical data
H øopcßtMtû12êo - fFWfroNtsVRMR JilÙ 2O1^S¿ø ot HISÍORICAL GW Anart@t
@
Pace Analytical Seruices, lnc.
9800 K¡ncey Ave Suite 100
Huntersville, NC 28078
(704)87 5-9092
Analytical
www.paælabs.com
June 01 ,2015
Ms. Flora D'Souza
Shield Engineering
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project: TFM #2
Pace Project No.: 92250976
Dear Ms. D'Souza:
Enclosed are the analytical results for sample(s) received by the laboratory on May 21,2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
othen¡yise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless othenruise footnoted.
lf you have any questions concerning this report, please feel free to contact me
Sincerely,
t íx-./- ø^rr-- i(/ù 112'-
Laura J Cooper
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, lnc Page 1 of 28
o
Pace Analytical Services, lnc.
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
(704)875-e0s2
Analytical
www.pacÊlabs.con
CERTIFICATIONS
Project:
Pace Project No.:
TFM#2
92250976
Charlotte Certification lDs
9800 KinceyAve Ste 100, Huntersv¡lle, NC 28078
North Carolina Drinking Water Cert¡fìcation #: 37706
North Carolina Field Services Certification #:5342
North Carolina Wastewater Certifìcat¡on #: 12
South Carolina Certificat¡on #: 99006001
Florida/NELAP Cert¡fìcation #: E87627
Kentucky UST Certification #: 84
West Virginia Certifìcation #: 357
VirginiaA/ELAP Cert¡f¡cation #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, lnc Page 2 of 28
o
Pace Analyt¡cal Services, lnc.
9800 K¡ncey Ave. Suite 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pacelabs.con
SAMPLE ANALYTE COUNT
Project:
Pace Project No :
rFM#2
92250976
Lab lD Sample lD Method Analysts
Analytes
Reported Laboratory
92250976001
92250976002
92250976003
92250976004
92250976005
92250976006
92250976007
MW-I
MW-2
MW-3
MW-4
MW-5
T-1
TRIP BLANK
SM 62008
sM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except ¡n full,
w¡thout the wr¡tten consent of Pace Analytical Services, Inc
CAH
CAH
CAH
CAH
CAH
CAH
CAH
63
63
63
63
63
bJ
63
PASt-C
PASI-C
PASI-C
PASI-C
PASI-C
PASI-C
PASI-C
Page 3 of 28
o
Pace Analytical Seruices, lnc.
9800 Kincey Ave Suite 1 00
Huntersville, NC 28078
(704)875-90e2
Analytical
w.paælabsæm
SUMMARY OF DETECTION
Project:
Pace Project No.:
fFl\A#2
92250976
Lab Sample lD
l\4ethod
Client Sample lD
Parameters Result Units Report Limit Analyzed Qualifìers
922s0976001
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 6200B
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
sM 62008
92250976002
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 6200B
92250976003
SM 62008
SM 62008
SM 6200B
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
92250976004
SM 62008
MW-1
Benzene
Brom od ich lo ro meth ane
sec-Butylbenzene
Chloroform
1,2-Dibromoethane (EDB)
1 ,2-Dichloroethane
Ethylbenzene
lsopropylbenzene (Cumene)
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Toluene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
m&p-Xylene
o-Xylene
MW-2
Benzene
1,2-Dibromoethane (EDB)
1 ,2-Dichloroethane
Diisopropyl ether
Ethylbenzene
lsopropylbenzene (Cumene)
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Toluene
'1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
m&p-Xylene
o-Xylene
MW-3
Benzene
Ethylbenzene
lsopropylbenzene (Cumene)
Methyllert-butyl ether
Naphthalene
n-Propylbenzene
Toluene
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
m&p-Xylene
o-Xylene
MW.4
Benzene
932
0.92
161
8,7
063
2.0
145
35.7
52
143
466
113
379
21.2
480
336
64'10
451
713
90.9
989
46.4
4830
898
107
1 2600
9.8
1't20
268
3790
2670
172
1250
133
9.4
881
349
954
2330
611
4440
2270
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
050
2.0
050
0.50
12
0.50
2.5
1.2
O5l3Ol15 12:29
O5l3Ol15 12:29
05130115 12:29
05130115 12:29
05t30t15 12.29
O5130115 12:29
O5130115 12:29
O5l3ol15 12:29
05t30t't5't2:29
05130115 12:29
05130115 12:29
05130115 12:29
05/31/15 01:00
O5l3Ol15 12:29
05/31/1 5 01 :00
05/31/15 01:00
50.0
50
5.0
5.0
5.0
5.0
500
20.0
50
500
5.0
5.0
5.0
100
500
O5l3Ol15 17:17
05/30i15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
0513O115 17:17
05/30/1 5 09:43
05/30/15 09:43
05130115 17:17
05/30/1 5 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/'15 09:43
O5l3Ol15 17:17
05/30/15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/15 09:59
05/30/15 09:59
05130115 17:34
05/30/1 5 09:59
O5130115 17:34
O5l3Ol15 17:34
50
5.0
5.0
5.0
200
50
50
12.5
5.0
25.O
12.5
27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seruices, lnc
0 50 05/30/15 15:55
Page 4 of 28
o
Pace Analytical Services, lnc.
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.paælabs æm
SUMMARY OF DETECTION
Project:
Pace Project No.
lFM#2
92250976
Lab Sample lD
Method
Client Sample lD
Paramelers Result Units Report Lim¡t Analyzed Qualifiers
92250976004
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
MW-4
Bromodichloromethane
Chloroform
Methyl-tert-butyl ether
1,2,4-Trimethylbenzene
m&p-Xylene
o-Xylene
T-1
Benzene
I ,2-Dichloroethane
1 ,2-Dichloropropane
Di¡sopropyl ether
Ethylbenzene
lsopropylbenzene (Cumene)
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Toluene
1,2,4-Trimethylbenzene
m&p-Xylene
o-Xylene
0.72
22.9
106
1.9
4.9
1.8
115
43.9
0.68
3.2
75
42
1-1
3.8
0.56
0.54
4.0
11.3
4.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Services, Inc
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
050
0.50
050
1.0
0.50
05/30/1 5
05/30/15
05i30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
15:55
15:55
15:55
15:55
15:55
15:55
92250976006
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 6200B
SM 62008
SM 62008
SM 62008
SM 62OOB
0.50
0.50
0.50
050
0.50
050
0.50
2.0
0.50
0.50
050
1.0
0.50
O5130115 15'22
0513O115 15:22
0513O115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
051301'15 15:22
05130115 15:22
05130115 15:22
05130115 15:22
Page 5 of 28
@
Pace Analytical Seruices, lnc.
9800 KinceyAve Suite 100
Huntersville, NC 28078
(7041875-e0e2
Analytrcal
w.pacelabs.com
PROJECT NARRATIVE
Project:
Pace Project No
TFM#2
92250976
Method: SM 62008
Description: 62008 MSV
Client: Shield
Date: June 01. 2015
General lnformation:
7 samples were analyzed for SM 62008. All samples were received in acceptable cond¡t¡on with any exceptions noted below.
Hold Time:
The samples were analyzed within the method requ¡red hold times with any exceptions noted below
lnitial Calibrations (including MS Tune as applicable):
All criteria were within method requiremenls with any exceptions noted below.
Continuing Calibrat¡on:
All criteria were within method requirements w¡th any except¡ons noted below.
lnternal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below
Method Blank:
All analytes were below the report l¡mit in the method blank, where applicable, with any exceplions noted below
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below
Matrix Spikes:
All percent recoveries and relative percent differences (RPDS) were w¡thin acceptance criteria with any exceptions noted below.
QC Batch: MSV/31925
A matrix sp¡ke and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250861002
M'1: Matrix spike recovery exceeded QC limits Batch accepted based on laboratory control sample (LCS) recovery.
. MS (Lab lD: 1470893)
. Dichlorodifl uoromethane
. Tr¡chlorofl uoromethane
. MSD (Lab lD: 1470894)
. Carbon tetrachloride
. D¡chlorodifl uoromethane
. Hexachloro-1,3-butadiene
. Trichlorofl uoromethane
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except jn full,
without the written consent of Pace Analytical Services, lnc Page 6 of 28
@
Pace Analytical Seruices, lnc.
9800 Kincey Ave Suile 100
Huntersville, NC 28078
[phone]
Analytical
www.pacþlabs com
ANALYTICAL RESULTS
Project:
Pace Project No.:
rFM#2
92250976
Sample: MW-1
Parameters
Lab lD
Results
92250976001
Units
Collected: 0512O115 13:45
Report Limit DF
Received: 05121115 14:56 Matrix: Waler
Prepared Analyzed CAS No.Qual
62OOB MSV
Benzene
Bromobenzene
Bromochloromethane
B ro m od ichlorom eth a ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
te rt- B utylbe nze ne
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochlorometha ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1,4-Dichlorobenzene
D ich lorod ifl u orometh a ne
1 ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
.1 ,2-Dichloropropane
1 ,3-D¡chloropropa ne
2,2-Dichloropropane
1 ,'l -Dichloropropene
cis-1,3-Dichloropropene
trans- 1 ,3-D ichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,'1, 1,2-Tetrachloroethane
1,1,2,2-leI¡ achloroethane
Tetrachloroethene
Analytical Method: SM 62008
93.2
ND
ND
o.92
ND
ND
ND
16.1
ND
ND
ND
ND
8.7
ND
ND
ND
ND
ND
0.63
ND
ND
ND
ND
ND
ND
2.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
145
ND
35.7
ND
5.2
143
46.6
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
050
0.50
050
0.50
50
0.50
0.50
0.50
0.50
0.50
1.0
050
't.0
0.50
0.50
1.0
0.50
0.50
0.50
0.50
050
050
0.50
050
0.50
0.50
050
0.50
0.50
0.50
050
050
050
050
0.50
050
2.O
050
2-0
050
2.0
050
050
050
050
050
05130115 12:29
05130115 12:29
05130115 12:29
0513011512:29
O5l3Ol15 12:29
O513O11512:29
0513O115 12:29
05130115 12:29
0513O115 12:29
05130115 12:29
05130115 12:29
05130115 12:29
05130115 12:29
0513O11512:29
O513O11512:29
0513O115 12:29
0513O115 12:29
0513O11512:29
0513O115 12:29
05130115 12:29
05130115'12:29
05130115 12:29
05130115 12i29
0513O11512:29
0513O11512:29
0513O11512:29
0513011512:29
05130115 12:29
05l3ol'15 12:29
05130115 12:29
05130115 12:29
05l3jh5'12i29
05130t15 12.29
05130115 12:29
05130115 12:29
0513011512:29
0513O115 12:29
0513O115 12:29
05130115 12:29
05130115 12:25
0513011512:29
0513O11512:29
05130115 12:29
05130115 12:29
05130115 12:29
05130115 12:29
05130115 12:29
71-43-2
1 0B-86-1
74-97-5
75-27-4
75-25-2
74-83-9
I 04-51 -8
'135-98-8
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-1 2-8
124-48-1
I 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
'156-59-2
I 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1006'1-01-5
1 006 1 -02-6
1 08-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-04-4
91 -20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Seruices, lncDate: 06/0'1/2015 05:49 PM PageT of28
@
Pace Analytical Services, lnc.
9800 KinceyAve Su¡te 100
Huntersv¡lle, NC 28078
[phone]
Analytical
www.pa^Êlabs com
ANALYTICAL RESULTS
Project:
Pace Project No
rFM#2
92250976
Sample: MW-l
Parameters
Lab lD
Results
92250976001
Units
Collected: 05120115 13:45
Report Limit DF
Received: 05121115 14:.56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
-1,2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 ,1 ,'l -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
113
ND
ND
ND
ND
ND
ND
ND
379
21.2
ND
480
336
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
2.0
20
0.50
0.50
0.50
1.0
0.50
1.2
0.50
1.0
25
'1.2
2.5
1
,|
2.5
2.5
0513011512:29
0513011512:29
05130115 12:29
05130115 12:29
O5l3Ol'15 12:29
051301'15 12:29
O513O11512:29
0513011512:29
05/31/15 01:00
0513011512:29
05130115 12:29
05/3'1/15 01 :00
05/31/15 01:00
1 0B-BB-3
87-61-6
120-82-1
71 -55-6
79-00-5
79-01-6
75-69-4
96- 1 8-4
95-63-6
1 08-67-8
75-01-4
179601-23-'l
95-47-6
99
102
99
70-1 30
70-1 30
70-130
To
o/o
To
05/30/1 5'12:29 17O6O-07-0
05/30/15 12:29 460-00-4
05/30/15 12:29 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the writlen consent of Pace Analytical Services, lncDale: 06/0'112015 05:49 PM Page 8 of 28
Project:
Pace Project No
6
TFM #2
92250976
Analytical
Pace Analytical Services, lnc.
9800 Kincey Ave Su¡te 100
Huntersville, NC 28078
(7 04)87 5-9092M.paælabsæm
ANALYTICAL RESULTS
Sample: MW-2
Parameters
Lab lD: 92250976002
Results Units
Collected: 051201 15 13:40
Report Limit DF
Received: 05121h514:.56 Matr¡x: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochlorometha ne
Bromod ich lorom eth a ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochlorometha ne
1,2-Díbromoethane (EDB)
Dibromomethane
I ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
D ich lo rod ifl u orometh a ne
1 ,1 -Dichloroethane
'1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
I ,3-Dichloropropane
2,2-Dichloropropa ne
1 ,'l-Dichloropropene
cis- 1,3-Dichloropropene
tra ns- 1 ,3-D¡chloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyllert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,'1, 1,2-Tetrachloroethane
1, 1,2,2-Iet achloroeth a ne
Te tra ch I o roelhe ne
Analytical Method: SM 62008
641 0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
451
ND
ND
ND
ND
ND
ND
713
ND
ND
ND
ND
ND
ND
ND
ND
ND
90.9
989
ND
46.4
ND
4830
898
107
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
50.0
5.0
5.0
5.0
5.0
500
50
50
5.0
5.0
5.0
10.0
5.0
10.0
5.0
50
10.0
5.0
5.0
5.0
50
5.0
50
5.0
5.0
5.0
5.0
50
5.0
5.0
50
5.0
50
5.0
Ân
5.0
50
20.o
50
20.0
50.0
200
5.0
5.0
50
50
5.0
100
'10
10
10
10
10
10
10
10
'10
10
10
10
10
10
'10
'10
10
'10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
'100
10
10
10
'10
10
10
0513011517:17
05/30/1 5 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/,l5 09:43
05/30/15 09:43
05/30/'15 09:43
05/30/'15 09:43
05/30/'15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/15 09:43
05i30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05/30/'15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/'15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/'15 09:43
05/30/15 09:43
05/30/'15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05130115 17:17
05/30/1 5 09:43
05/30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/1 5 09:43
71-43-2
1 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
I 35-98-8
98-06-6
56-23-5
't 0B-90-7
75-00-3
t) / -bb-J
74-87-3
95-49-8
I 06-43-4
96-1 2-8
124-48-',|
1 06-93-4
74-95-3
95-50-1
541-73-1
I 06-46-7
75-71-8
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 0061 -01-5
1 0061-02-6
"t08-20-3
100-41-4
87-68-3
9B-82-8
75-09-2
1634-O4-4
91 -20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analyt¡cal Seruices, lncDate: 06/01/2015 05:49 PM Page I of 28
o
Pace Analyt¡cal Services, lnc.
9800 KinceyAve SuÌte 100
Huntersville, NC 28078
[phone]
Analytical
M.pacelabs con
ANALYTICAL RESULTS
Project:
Pace Project No.
fFM#2
92250976
Sample: MW-2
Parameters
Lab lD: 92250976002
Results Units
Collected: 05120h5 13:40
Report Limit DF
Received: 05121115 14:56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
'1,2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
1,'1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
'1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
r 2600
ND
ND
ND
ND
ND
ND
9.8
1120
268
ND
3790
2670
50.0
20.0
200
5.0
5.0
5.0
10.0
5.0
5.0
5.0
10.0
'10.0
50.0
100
10
10
10
10
10
'10
10
10
10
10
10
'100
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
%
Yo
%
101
100
99
05t30t1517.17
05/30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05i30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/15 09:43
05/30/15 09:43
05/30/15 09:43
05/30/1 5 09:43
05/30/1 5 09:43
05130115 17:17
1 08-88-3
87-61-6
't20-82-'l
71-55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
95-63-6
I 08-67-B
75-01-4
179601-23-1
95-47-6
70-1 30
70-1 30
70-'130
10
10
10
05/30/15 09:43 '1 7060-07-0
05/30/1509:43 460-00-4
05/30/1 5 09:43 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, lncDate: 06101 12015 05:49 PM Page 10 of 28
@
Pace Analytical Seruices, lnc.
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pac:elabs con
ANALYTICAL RESULTS
Project:
Pace Project No
rFM#2
92250976
Sample: MW-3
Parameters
Lab lD: 92250976003
Results Un¡ts
Collected: 05/20115 13:35
Report Limit DF
Received: 05121115 14:56 Matrix: Water
Prepared Analyzed CAS No Qual
62008 MSV
Benzene
Bromobenzene
Bromochlorometha ne
B ro mod ich lorom eth a ne
Bromoform
Bromomelhane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
'1,2-D¡bromo-3-chloropropane
D ib romoch lo rometha ne
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uoromethane
1 ,'l -Dichloroethane
1 ,2-Dichloroethane
'1 ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropa ne
1,3-Dichloropropane
2,2-D ichloropropane
1 ,1 -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1, 3-butadiene
lsopropylbenzene (Cumene)
Methylene Chlor¡de
Methylìert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,'1 ,1 ,2-Tetrachloroethane
1,1,2,2-IeIr achlo roeth a ne
Tetrachloroethene
Analytical Method: SM 62008
17.2 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/LND ug/L
1250 ug/LND ug/L
133 ug/LND ug/L
9.4 ug/L
881 ug/L
349 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
5.0
5.0
5.0
5.0
5.0
500
5.0
5.0
5.0
5.0
50
10.0
50
10.0
5.0
50
10.0
5.0
5.0
5.0
5.0
50
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
50
5.0
50
50
50
5.0
20.0
5.0
200
Ãn
200
50
5.0
50
50
50
10
10
10
10
10
10
10
10
10
10
10
10
'10
10
'10
10
10
10
'10
10
10
10
10
10
'10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
'10
'10
10
10
10
10
10
10
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/'15 09:59
05i30/1 5 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/15 09:59
05/30/1 5 09:59
05/30/15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/.15 09:59
05/30/'15 09:59
05/30/'15 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
7 1-43-2
1 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -8
1 35-98-8
98-06-6
56-23-5
'108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
1 06-43-4
96-1 2-B
't24-48-',\
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
'10061-0'1-5
I 0061 -02-6
1 08-20-3
100-41-4
87-68-3
98-82-B
75-09-2
1634-04-4
91 -20-3
'103-65-'1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Services, lncDale. 06101 12015 05:49 PM Page .l 1 of 28
@
Pace Analytical Services, lnc.
9800 K¡nceyAve Suite'100
Huntersv¡lle, NC 28078
[phone]
halytical
w.paælaß.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
TFM#2
92250976
Sample: MW-3 Lab lD
Results
92250976003
Units
Collected: 05120115 13:35
Report Limit DF
Received: 05121115 14:56 Matr¡x: Water
Prepared Analyzed CAS No.Parameters Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
't,2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
I, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Suffogates
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
954
ND
ND
ND
ND
ND
ND
ND
2330
611
ND
4440
2270
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
Yo
5.0
20.0
20.o
50
5.0
5.0
10.0
5.0
12.5
5.0
10.0
25.0
125
10
10
10
10
10
10
10
10
25
10
10
25
25
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/'15 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05/30/1 5 09:59
05130115'17:34
05/30/15 09:59
05/30/15 09:59
05130115 17:34
0513O11517:34
'108-88-3
87-61-6
't20-82-'l
71-55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
',l08-67-8
75-01-4
179601-23-'l
95-47-6
100
102
98
70-1 30
70-1 30
70-1 30
10
10
10
05/30/15 09:59 17060-07-0
05/30/15 09:59 460-00-4
05/30/15 09:59 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seruices, lncDate: 06/01/2015 05:49 PM Page 12 of 28
Project:
Pace Project No.
o
lFM#2
92250976
Analytical
Pace Analytical Seru¡ces, lnc.
9800 K¡ncey Ave Suite 1 00
Huntersville, NC 28078
[phone]M.pacelabs æm
ANALYTICAL RESULTS
Sample: MW-4
Parameters
Lab lD: 92250976004
Results Un¡ts
Collected: 05120115'13:30
Report Limit DF
Received: 05121115 14:56 Matrix: Waler
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochlorometha ne
B ro modich loromelh a ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochlorometha ne
1,2-Dibromoethane (EDB)
Dibromomelhane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifluoromethane
1 ,1-Dichloroethane
1 ,2-Dichloroethane
1 ,I -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroelhene
1 ,2-Dichloropropane
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl elher
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,1 ,1 ,2-Tetrachloroethane
1,1,2,2-letr achlo roeth a n e
Tetrachloroethene
Analytical Method: SM 62008
2.7
ND
ND
0.72
ND
ND
ND
ND
ND
ND
ND
ND
22.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
106
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
0.50
0.50
0.50
050
5.0
050
0.50
0.50
0.50
050
1.0
0.50
1.0
0.50
0.50
1.0
0.50
0.50
0.50
050
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
050
050
050
0.50
0.50
0.50
0.50
2.O
050
2.O
0.50
20
0.50
0.50
0.50
0.50
050
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/15 I 5:55
05/30/1 5 I 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/'1 5 15:55
05/30/1 5 1 5:55
05/30/15'15:55
05/30/15 15:55
05/30/1 5 I 5:55
05/30/1 5 1 5:55
05/30/1 5 I 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/15 15:55
05/30/1 5 I 5:55
05/30/1 5 1 5:55
05/30/15 15:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/15 15:55
05/30/"t5 'l 5:55
05/30/1 5 1 5:55
05/30/'15 15:55
05/30/15 '15:55
05/30/15 '15:55
05/30/'15 15:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/15 'l 5:55
05/30/'15 15:55
05/30/15 '15:55
05/30/1 5 1 5:55
05/30/15 '15:55
05/30/'1 5 15:55
05/30/'1 5 15:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/'1515:55
71-43-2
1 0B-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -8
1 35-98-8
9B-06-6
56-23-5
I 08-90-7
75-00-3
67-66-3
74-87-3
95-49-B
't 06-43-4
96-1 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-B
75-34-3
107-06-2
75-35-4
'156-59-2
I 56-60-5
7B-87-5
142-28-9
594-20-7
563-58-6
10061-0'1-5
1006'1-02-6
1 0B-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-O4-4
91-20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analytical Seruices, lncDate: 06/01/2015 05:49 PM Page 13 of 28
@
Pace Analytical Services, lnc.
9800 KinceyAve Su¡te 100
Huntersville, NC 28078
(704187 5-9092
Analytical
w.pacelabs.com
ANALYTICAL RESULTS
Project:
Pace Project No.:
lFM#2
92250976
Sample: MW-4
Parameters
Lab lD
Results
92250976004
Units
Collected: 05/20115 l3:30
Report Limit 'DF
Received: 05121115 14:56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1, 2,4-Tr¡chlorobenzene
1,'1, 1 -Trichloroethane
'1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Mnyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
o/o
Yo
ND
ND
ND
ND
ND
ND
ND
ND
1.9
ND
ND
4.9
1.8
9B
97
99
0.50
2.O
2.0
0.50
0.50
0.50
1.0
0.50
0.50
0.50
10
1.0
0.50
1
1
1
1
1
I
1
1
1
1
1
1
1
05/30/15 15:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30i15 15:55
05/30/1 5 1 5:55
05/30/15'15:55
05/30/15 15:55
05/30/15 15:55
05/30/1 5 1 5:55
05/30/1 5 1 5:55
05/30/15 15:55
05/30/1 5 '15:55
1 08-88-3
87-61-6
120-82-1
71 -55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
1 08-67-8
75-01-4
179601-23-',!
95-47-6
70-1 30
70-l 30
70-1 30
05/30/15 15:55 17060-07-0
05/30/15 15:55 460-00-4
05/30/15 15:55 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the wr¡tten consent of Pace Analytical Seruices, lncDate: 06/01/2015 05:49 PM Page 14 of 28
@
Pace Analyt¡cal Seruices, lnc.
9800 Klncey Ave Suite 1 00
Huntersville, NC 28078
(7 04)87 5-9os2
Analytical
w.paælabsæm
ANALYTICAL RESULTS
Project:
Pace Project No.:
TFM#2
92250976
Sample: MW-S
Parameters
Lab lD
Results
92250976005
Units
Collected: O5l2Ol15 13:25
Report Limit DF
Received: 0512111514:56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
Bromochloromethane
B ro modichlo rometh a ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochlorometha ne
'1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dich lo rod ifl uo romelh a ne
I ,1 -Dichloroethane
1 ,2-Dichloroethane
I , 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropa ne
1 ,3-Dichloropropane
2,2-Dichloropropane
1 ,'l -Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro- 1 ,3-butad iene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,Z-felrachloroethane
1,1,2,2-fet achloroethane
Telrachloroethene
Analytical Method: SM 62008
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
0.50
0.50
0.50
0.50
5.0
0.50
0.50
050
050
0.50
10
0.50
1.0
0.50
050
1.0
0.50
050
050
0.50
0.50
0.50
0.50
050
0.50
0.50
0.50
050
050
0.50
0.50
0.50
0.50
0.50
0.50
050
2.0
050
2.0
0.50
20
0.50
0.50
0.50
0.50
050
05130115 13:02
05/30/.15 '13:02
05/30/1 5 1 3:02
05/30/15 '13:02
05130115 13.02
05/30/1 5 I 3:02
05/30/15 'l 3:02
05/30/1 5 1 3:02
05/30/'15 'l 3:02
05/30/'15 13:02
05130115 13:02
05/30/1 5 1 3:02
05/30115 13:02
05130115 13:02
05/30/15 l3:02
05/30/1 5 1 3:02
05/30/1 5 1 3:02
O5l30l'1513:02
05/30/15 13:02
05/30/15 13:02
05/30/'1 5 13:02
05130115 13:02
05130115 13:02
05130115 13:02
05/30/1 5 1 3:02
05130115 13102
05/30/1 5 I 3:02
05/30/1 5 13:02
0513O115 13:02
0513O115 13:02
05/30/1 5 1 3:02
05130115 13:02
05/30/'15 '13:02
05130115 13:02
05130115 13:02
05/30/1 5 I 3:02
05t30115 13.02
05/30/15 '1 3:02
05/30/1 5 1 3:02
05/30/15 13:02
05/30/1 5 1 3:02
05/30/15 13:02
05t30t15 13.02
05130115 13:02
05/30/1 5 1 3:02
05/30/1 5 1 3:02
0513O115 13:O2
71-43-2
I 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51-8
1 35-98-B
98-06-6
56-23-5
1 08-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-'12-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
7 5-7 1-8
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
1 006 1 -01 -5
1 006 1 -02-6
I 08-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-04-4
91-20-3
1 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, lncDale: 0610112015 05:49 PM Page 15 of28
Project:
Pace Project No
@
TFM#2
92250976
Analytical
Pace Analyticâl Services, lnc.
9800 KinceyAve Suite 100
Huntersv¡lle, NC 28078
(704)87 5-e0e2w.pacelabs com
ANALYTICAL RESULTS
Sample: MW-S
Parameters
Lab lD
Results
92250976005
Units
Collected: O5120115 13:25 Received: 05121115 14:56 Matrix: Water
Report Limit DF Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroelhene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Mnyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
100
99
99
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
050
2.0
2.0
050
0.50
0.50
1.0
0.50
0.50
0.50
'1.0
1.0
0.50
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/'t 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
05/30/1 5
13:02
13:02
13:02
13:02
1302
13:02
13:02
13:O2
1302
13:02
13:02
'13:02
13:02
1 08-88-3
87-61-6
120-82-',|
7 1 -55-6
79-00-5
79-01-6
75-69-4
96-1 B-4
95-63-6
1 08-67-8
75-O1-4
179601-23-1
95-47-6
%
o/o
Yo
70-1 30
70-1 30
70-1 30
05/30/15 13:02 17060-07-0
05/30/15 13:02 460-00-4
05/30/'1 5 13:02 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Services, lncDale. 061O112O15 05:49 PM Page 16 of28
o
Pace Analyt¡cal Serv¡ces, lnc.
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
Analytrcal
w.pacÊlabs cYm
ANALYTICAL RESULTS
Project:
Pace Project No.
-tFM#2
92250976
Sample: T-1 Lab lD: 92250976006
Results Units
Collected: 05120h5 13:50
Report Limit DF
Received: 05121115'14:.56 Malrix: Water
Prepared Analyzed CAS No.Parameters Qual
62008 MSV
Benzene
Bromobenzene
B ro mochlorometh a ne
Bro modichlorometh a ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon telrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1 ,2-Dichlorobenzene
I ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uoromethane
I ,I -Dichloroethane
1 ,2-Dichloroethane
I ,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-'1,2-Dichloroethene
I ,2-Dichloropropane
I ,3-Dichloropropane
2,2-Dichloropropane
1 ,.1-Dichloropropene
cis-1,3-Dichloropropene
trans--1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-'1,3-buladiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-butyl ether
Naphthalene
n-Propylbenzene
Slyrene
'1 ,1 , '1 ,2-Tetrachloroethane
1, 1,2,2-fet achl oroeth a ne
Tetrachloroethene
Analytical Method: SM 62008
ll5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
43.9
ND
ND
ND
0.68
ND
ND
ND
ND
ND
3.2
7.5
ND
4.2
ND
't.1
3.8
0.56
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
050
050
050
050
0.50
5.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
1.0
050
0.50
1.0
0.50
0.50
0.50
0.50
050
0.50
050
050
0.50
0.50
0.50
0.50
0.50
050
0.50
050
0.50
0.50
0.50
050
2-0
0.50
2.0
0.50
20
0.50
050
0.50
0.50
0.50
05130115 15:22
0513011515:22
05t30t1515"22
0513011515'.22
051301151522
05130115 15:22
0513O115 15:22
05130115 15:22
05130115 15i22
05130115 15:22
05130115 15:22
0513011515:22
0513O11515:22
0513011515'.22
05130115 15:22
05130115 15:22
05130115 1522
05130115'15:22
05130115 15:22
05130115 15:22
0513011515:22
05130115 15:22
O513011515:22
0513011515:22
0513011515:22
0513O115 1522
05130115 15:22
05130115 15:22
05130t15 15"22
05130115'15:22
05130115 15:22
05130115 15:22
05t30t15 15.22
O513011515:22
05130115 15:22
0513O11515:22
0513011515'22
o5t30t15 15'.22
A5130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
05130115 15:22
0513011515:22
0513011515:22
0513O115 15:22
71-43-2
1 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -B
1 35-98-8
98-06-6
56-23-5
1 0B-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-1 2-8
124-48-'l
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
't07-06-2
75-35-4
1 56-59-2
'156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-0'1-5
I 0061 -02-6
'108-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-O4-4
91-20-3
I 03-65-1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wr¡tten consent of Pace Analyt¡cal Services, lncDate: 06/01/20'15 05:49 PM Page 17 of28
@
Pace Analytical Services, lnc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
(704187 5-eo92
Analytical
www.pacÊlabs c{m
ANALYTICAL RESULTS
Project:
Pace Project No.
ÏFM#2
92250976
Sample: T-1 Lab lD
Results
92250976006
Units
Collected: O5l2Ol15 13:50
Report Limit DF
Received: 0512'1115 14:56 Matrix: Water
Prepared Analyzed CAS No.Parameters Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1, 2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropane
1, 2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-dB (S)
Analytical Method: SM 62008
0.54
ND
ND
ND
ND
ND
ND
ND
4.0
ND
ND
11.3
4.9
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
2.0
2.O
0.50
0.50
0.50
1.0
0.50
0.50
0.50
1.0
1.0
0.50
05130115'15:22
05130115'15:22
05130115'15:22
0513O115 15:22
05130115 15:22
O513O11515:22
0513011515:22
O5130115 15:22
05130115 15:22
05130/15 15:22
051301'1515:22
05130115'15:22
0513O115 15:22
1 08-88-3
87-61-6
120-82-1
71 -55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
I 08-67-8
75-O1-4
179601-23-1
95-47-6
To
Yo
95
99
oo
70-l 30
70-1 30
70-1 30
05/30/1 5 15:22 17060-07-0
05/30/15 15:22 46O-0O-4
05/30/1 5 15:22 2037 -26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pâce Analytical Services, lncDate: 06/01/2015 05:49 PM Page l8 of28
@
Pace Analyt¡cal Seruices, lnc.
9800 Kincey Ave Suite '100
Huntersv¡lle, NC 28078
(704)87 5-9092
Analytical
Www.p9';elabs æm
ANALYTICAL RESULTS
Project:
Pace Project No
TFI\A#2
92250976
Sample: TRIP BLANK
Parameters
Lab lD
Results
92250976007
Un¡ts
Collected: 05/20l',l5 00:00
Report Limit DF
Received: 0512111514:56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Benzene
Bromobenzene
B ro mochlorometha ne
Bromodichlorometha ne
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
I ,2-Dichlorobenzene
'1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifl uoromethane
I ,1 -Dichloroethane
1 ,2-Dichloroethane
1 ,1 -Dichloroethene
cis- 1,2-Dichloroethene
trans-1,2-Dichloroethene
1 ,2-Dichloropropane
I ,3-Dichloropropane
2,2-Dichloropropane
1 ,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-'1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl{ert-bulyl ether
Naphthalene
n-Propylbenzene
Styrene
1 ,'1 ,1 ,2-Telrachloroelhane
1,1,2,2-fetr achlo roeth a ne
Tetrachloroethene
Analytical Method: SM 62008
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.50
050
0.50
0.50
0.50
5.0
0.50
0.50
0.50
050
0.50
1.0
0.50
1.0
0.50
0.50
1.0
050
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
0.50
0.50
0.50
050
0.50
0.50
0.50
050
0.50
0.50
0.50
2-O
0.50
2.0
0.50
2-O
050
0.50
0.50
050
050
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 0B:03
05/30/1 s 08:03
05/30/1 5 08:03
05/30/15 08:03
05/30/1 5 08:03
05/30/1 s 0B:03
05/30/1 5 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/15 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/'15 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/'15 08:03
05/30/1 5 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/'15 08:03
05/30/1 5 08:03
05/30/'l5 08:03
05/30/'15 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/15 08:03
71-43-2
1 08-86-1
74-97-5
75-27-4
75-25-2
74-83-9
1 04-51 -8
I 35-98-B
98-06-6
56-23-5
'108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
1 06-43-4
96-'t 2-8
124-48-1
1 06-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
1 56-59-2
1 56-60-5
78-87-5
142-28-9
594-20-7
563-58-6
I 0061-01-5
'l 0061-02-6
1 08-20-3
100-41-4
87-68-3
98-82-8
75-09-2
1634-04-4
91 -20-3
'103-65- 1
100-42-5
630-20-6
79-34-5
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ln full,
without the written consent of Pace Analytical Services, lncDate: 0610112015 05:49 PM Page 19 of28
Project:
Pace Project No.:
@
rFt¡.A #2
92250976
Analytical
Pace Analytical Serv¡ces, lnc.
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]www.pacelabs con
ANALYTICAL RESULTS
Sample: TRIP BLANK
Parameters
Lab lD: 92250976007
Results Units
Collected: 05/20115 00:00
Report Limit DF
Received: 05121115 14:56 Matrix: Water
Prepared Analyzed CAS No.Qual
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1 -Trichloroethane
1 ,1 ,2-Trichloroetha ne
Trichloroethene
Trichlorofl uoromelhane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogafes
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
Analytical Method: SM 62008
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/LND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
05/30/15 0B:03
05/30/1 5 08:03
05/30/1 5 0B:03
05/30/1 5 0B:03
05/30/1 5 0B:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/1 5 08:03
05/30/15 0B:03
05/30/15 08:03
05/30/15 08:03
05/30/1 5 08:03
05/30/'15 08:03
0.50
2.0
2.O
0.50
0.50
0.50
1.0
0.50
0.50
0.50
1.0
1.0
0.50
1 0B-88-3
87-6 1 -6
120-82-1
71 -55-6
79-00-5
79-01-6
75-69-4
96-1 8-4
95-63-6
1 0B-67-8
75-O1-4
179601-23-'l
95-47-6
102
100
99
70-1 30
70-1 30
70-1 30
To
%
%
05/30/15 08:03 17060-07-0
05/30/15 0B:03 460-00-4
05/30i15 08:03 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Seruices, IncDate: 06/01/20'15 05:49 PM Page 20 of 28
o
Pace Analytical Services, lnc.
9800 Kincey Ave Suite 100
Huntersv¡lle, NC 28078
(704t87 5-9092
Analytical
w.pacÊlabs.com
QUALITY CONTROL DATA
Project:
Pace Project No
rFM#2
92250976
QC Batch: MSV/31925 Analysis Method: SM 62008
QC Batch Method: SM 62008 Analysis Description: 62008 MSV
Associated Lab Samples: 92250976001 , 92250976002,92250976003, 92250976004,92250976005, 92250976006, 92250976007
METHOD BLANK: 1470891
Associated Lab Samples:
Parameter
Malrix: Water
92250976001 , 92250976002, 92250976003, 92250976004,92250976005, 92250976006, 92250976007
Blank Reporting
Units Result Limit Analyzed Qualifiers
1 ,1 ,1 ,2-Tetrachloroethane
'1 ,1 ,1 -Trichloroethane
'1,1,2,2-f et achloroe tha ne
1, 1,2-Tr¡chloroethane
1 , 'l -Dichloroethane
1 ,1-Dichloroethene
1 ,1 -Dichloropropene
1,2,3-Trichlorobenzene
'1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
I ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-'1,2-Dichloroethene
cis-'1,3-Dichloropropene
D ibro moch lorometh a ne
Dibromomethane
Dichlorodifl uoromethane
D¡¡sopropyl ether
Ethylbenzene
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
0.50
0.50
0.50
0.50
0.50
0.50
20
050
2.0
050
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
050
050
0.50
0.50
0.50
0.50
0.50
050
5.0
0.50
0.50
1.0
0.50
1.0
0.50
0.50
0.50
0.50
050
0.50
050
05130115 07:47
0513O115 07:47
05130115 07:47
05130115 07:47
05130115 07:47
0513O115 07:47
O5130115 07:47
O5l3Ol15 O7:47
O5130115 O7:47
05130115 07:47
O5l3Ol15 07:47
05130115 07:47
05130115 07:47
05130115 07:47
051301'15 07:47
05130115 07 47
05130115 07:47
05130115 07:47
05130115 07i47
05130h5 07:47
0513O115 07:47
0513O115 07:47
O5l3Ol15 07:47
05130115 07:47
0513O115 07:47
O5130115 07:47
05130115 07:47
O5l3Ol15 07:47
0513O115 07:47
0513O115 O7:47
O5130115 07:47
05130115 07:47
05130115 07:47
05t30t15 07'.47
05130115 07:47
05130115 Q7:47
05130115 07:47
05130115 07:47
05130115 07:47
O5130115 07:47
05130115 07 47
Results presented on th¡s page are ¡n the un¡ts ind¡cated by the "Un¡ts" column except where an alternate un¡t is presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not þe reproduced, except ¡n full,
without the wr¡tten consent of Pace Analytical Seruices, lncDate: 06/01/2015 05:49 PM Page21 of28
Analytical
Pace Analytical Serv¡ces, lnc.
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
[phone]ww.pacelabs crn
QUALITY CONTROL DATA
Project:
Pace Project No.:
rFM#2
92250976
METHOD BLANK: 1470891
Associated Lab Samples:
Parameter
Matrix: Water
92250976001 ,92250976002,92250976003, 92250976004, 92250976005, 92250976006, 92250976007
Blank ReportingUn¡ts Result Limit Analyzed Qualifìers
Hexachloro- 1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-D¡chloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
101
100
100
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
To
To
%
2.O
050
1.0
0.50
2.O
0.50
0.50
2.0
0.50
0.50
0.50
0.50
050
0.50
0.50
0.50
0.50
1.0
1.0
70-1 30
70-1 30
70-1 30
O5l3Ol15 07:47
O5l3Ol15 07:47
05130115 07:47
05130115 07:47
0513O115 07:47
05130115 07:47
051301'15 O7:47
O5l30l'15 07:47
O5l30l'15 O7:47
O5l3Ol15 O7:47
05130115 07:47
05130115 07i47
05130115 07:47
0513O115 07:47
O5l3Ol15 07:47
05130115 O7:47
05130115 O7:47
O5130115 07:47
05l30l'15 O7:47
O5l3Ol15 07:47
05130|15 07:47
0513O115 07 47
LABORATORY CONTROL SAMPLE:
Parameter
1470892
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1, 1, 1,2-Tetrachloroethane
1,'1,1-Trichloroethane
1,1,2,2-fet achl oroe tha n e
1,1,2-Trichloroethane
1 ,1 -Dichloroethane
I ,1 -Dichloroethene
1 ,1-Dichloropropene
'1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
'1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
1 ,2-Dichloroethane
'1 ,2-Dichloropropane
1,3,S-Trimethylbenzene
1 ,3-Dichlorobenzene
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
60.3
584
55.4
539
52.7
54.1
58.9
57.9
55.0
566
54.1
55.6
58.3
53.5
51.5
52.9
54.0
52.5
121
117
111
108
105
108
118
116
110
113
108
111
117
107
103
106
108
105
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-'140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-1 40
Results presented on th¡s page are in the units ind¡cated by lhe "Un¡ts" column except where an alternate un¡t is presented to the r¡ght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyt¡cal Serv¡ces, lncDale: 0610112015 05:49 PM Page 22 of 28
Æalytical
Pace Analytical Services, lnc.
9800 K¡nceyAve Su¡te 100
Huntersville, NC 28078
[phone]www.paciÊlabs.com
QUALITY CONTROL DATA
Project:
Pace Project No
TFtít#2
92250976
LABORATORY CONTROL SAMPLE:
Parameler
1470892
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifìers
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon letrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomelhane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
lrans-1,3-Dichloropropene
Tr¡chloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofl uorobenzene (S)
Toluene-d8 (S)
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ugiL
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ugiL
ug/L
ug/L
ug/L
ug/L
%
Yo
%
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
00
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
53.2
50.2
47.'l
52.5
51.9
53.8
57.',|
52.1
53.0
48.5
537
67.7
51.3
52.8
48.9
59.8
52.3
57.4
55.9
52.O
69.0
51.8
54.4
65.4
579
108
50.3
56.5
52.7
53.7
61.4
53.9
57.1
57.3
47.'l
53.2
52.5
51.8
579
50.8
61.2
58.3
106
100
94
105
104
108
114
't04
106
97
107
135
103
106
98
't20
105
115
1'12
104
138
't04
109
131
116
108
101
113
105
'107
123
108
114
115
94
106
105
't04
116
102
122
117
99
10'l
10.t
60-1 40
60-140
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60- 1 40
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-'140
60- t 40
60-140
60-1 40
60-140
60-140
60-140
60-140
60-'140
60-140
60-140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-'140
60-140
70-130
70-'130
70-1 30
Results presented on th¡s page are ¡n the un¡ts indicated by the "Un¡ts" column except where an alternate un¡t is presented to the rlght of the result.
REPORT OF LABORATORY ANALYSIS
Th¡s report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, lncDate: 06/01/2015 05:49 PM Page 23 of 28
@
Pace Analytical Seruices, lnc.
9800 Kincey Ave Suite '100
Huntersville, NC 28078
(704)875-eÙs2
Analytical
w.paælâhs com
QUALITY CONTROL DATA
Project:
Pace Project No
TFM #2
92250976
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470893
Parameter
92250861002
Units Result
IVIS
Spike
Conc.
MSD
Spike
Conc.
1470894
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits RPD Qual
1 ,'l ,'l ,2-Tetrachloroethane
1 ,1 ,1 -Trichloroethane
1,1,2,2-Telr achloroethane
1 , 1 ,2-Trichloroethane
1 ,1-Dichloroethane
1 ,1-Dichloroethene
'1,'l -Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1 ,2-Dichlorobenzene
'l ,2-Dichloroethane
1 ,2-Dichloropropane
1,3,5-Trimethylbenzene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropane
1 ,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
B rom od ich loro methane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochlorometha ne
Dibromomethane
Dichlorodifl uoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
40
20
20
246
258
23.9
23.4
23-4
25.1
27.O
24.8
246
243
24.3
22.6
24.4
233
220
23.8
24.3
22.9
23.3
227
22.1
23.6
23.3
240
236
234
22.1
19.8
22.4
282
23.2
24.1
21.8
27.7
232
23.5
222
225
305
22.5
24.6
29.1
26.3
48.9
22.1
21 I
117
125
115
113
116
123
129
1'19
120
111
't17
'113
119
112
112
114
112
108
114
108
105
111
110
116
112
114
106
94
104
130
110
124
108
135
116
1'l 3
106
112
152
'113
117
127
122
116
110
108
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
23-5
25.0
22-9
22.5
23.2
24.6
25.8
23.7
240
22.1
23.4
22.6
23.8
22-4
22.4
22.8
228
21.6
22.9
21 6
2't.0
22.2
22.0
23.2
22-4
22.9
21 2
188
20.8
25.9
22.0
248
21.5
27.1
23.2
22.6
21 .2
22.3
30.4
22.6
233
255
244
46.5
22.1
21 .7
123
129
119
117
117
126
135
124
123
122
122
113
122
116
110
119
'119
114
117
113
111
118
116
120
118
117
1'10
99
112
141
116
120
109
138
116
'118
111
112
152
112
123
146
131
122
110
109
60-'140
60-140
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-140
60-1 40
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-1 40
60-'140
60-'140
60-'140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-1 40
60-'140
60-'140
60-'140
60-140
60-140
60-'140
60-'140
60-'140
60-1 40
60-1 40
60-1 40
60-1 40
60-140
5
J
4
4
'l
2
5
4
J
I
4
0
2
4
1
4
6
6
2
5
5
b
rJ
J
5
2
4
5
7
8
Ã
3
1
2
0
4
5
1
0
I
5
13
7
5
0
1
M
M
M
Results presented on th¡s page are ¡n the un¡ts ¡ndicated by the "Un¡ts" column except where an alternate un¡t ¡s presented to the riqht of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not þe reproduced, except in full,
without the written consent of Pace Analytical Seruices, lncDale: 06101 12015 05:49 PM Page 24 of 28
o
Pace Analyt¡cal Seruices, lnc.
9800 K¡nceyAve Suite 100
Huntersville, NC 28078
(704).875-9092
Analytrcal
www.pac,elaß cgm
QUALITY CONTROL DATA
Project:
Pace Project No.
TFM#2
92250976
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470893
Parameter
92250861002
Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
'1470894
MS
Result
MSD
Result
MS
% Rec
MSD
o/o Rec
% Rec
Limits RPD Qual
n-Bulylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofl uoromethane
Vinyl chloride
1,2-D¡chloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
22.O
23.1
26.O
22.9
24.6
23.3
19.9
23.0
22.6
23-O
22.8
22.4
28.4
26.2
24.3
24.8
25.5
24.O
26 1
24.9
21.3
24.7
23.2
23.7
23.5
23.1
28.5
26.4
122
124
127
120
131
125
't 06
124
116
119
118
116
142
132
97
102
99
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Yo
Yo
o/o
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
110
115
130
114
123
1't7
100
115
113
115
114
112
'142
131
100
10'l
100
60-140
60-'140
60-1 40
60-140
60-140
60-140
60-140
60-140
60-140
60-1 40
60-1 40
60-1 40
60-1 40
60-140
70-1 30
70-1 30
70-1 30
10
7
2
5
6
7
b
7
J
3
J
3
0
I
M
Results presented on this page are in the un¡ts ind¡cated by the "Un¡ts" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Serv¡ces, lncDate: 06/01/2015 05:49 PM Page 25 01 28
@
Pace Analytical Seruices, lnc.
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
Analytreal
www.pac:elabs.con
QUALIFIERS
Project:
Pace Project No.
rFM#2
92250976
DEFINITIONS
DF - Dilution Factor, if reported, represents lhe factor applied to the reported data due to d¡lution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit
J - Est¡mated concentrat¡on above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent wilh EPA guidelines, unrounded data are displayed and have been used to calculale % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent D¡fference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - lndicates the compound was analyzed fo¡ but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate v¡al preserved to a pH of 4-5 ¡s recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylon¡trile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The resull reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC lnstitute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits Batch accepted based on laboratory control sample (LCS) recovery
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, lncDate: 06/01/2015 05:49 PM Page 26 of 28
@
Pace Analyt¡cal Seruices, lnc.
9800 KinceyAve- Suite 100
Huntersville, NC 28078
[phone]
Analytical
www.pa'iÊlabs con
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
rFM#2
92250976
Lab lD Sample lD QC Batch Method QG Batch Analytical Method
Analytical
Batch
9225097600't
92250976002
92250976003
92250976004
92250976005
92250976006
92250976007
MW.1
MW.2
MW-3
MW-4
MW-5
T-l
TRIP BLANK
SM 62008
SM 62008
sM 62008
SM 62008
SM 62008
SM 62008
SM 62008
MSV/31925
MSV/31925
MSV/31925
MSV/31925
MSV/31925
MSV/31925
MSV/31925
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w¡thout the written consent of Pace Analytical Services, lncDate 0610112015 05:49 PM Page27 of28
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