WS-6081_22332_CA_MRP_20130923

MONITORING REPORT
TEXACO FOOD MART #2
RECEIVED
N.C. D.ept. of ENR
SEP {3 1ml
Wln1ton-$alem
Reglon11 Office
1700 COTTON GROVE ROAD
LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA
INCIDENT NO. 22332
SHIELD PROJECT NO. 1001289
Responsible Party:
Techno, LLC for Holding
Brothers, Inc
P.O. Drawer 647
Concord, NC 28026
Contact:
David Holding
[phone]
March through July 2013
Consultant:
Shield Engineering, Inc.
4301 Taggart Creek Road
Charlotte, North Carolina 28208
Contact:
Flora J. D'Souza
[phone]
Property Owner:
United Oil of the Carolinas, Inc.
P.O. Box 68
Gastonia, North Carolina 28053
Contact:
David Dulmage
[phone]
Site Risk Classification: High Risk (HI 55D)
Land Use Category: Residential and commercial
Release Discovered: February 8, 1999
Site Latitude: 35°46'41" North
Potential Release Source(s): Unknown
-J-&wi,:r;~. (L
FloraJ. D'S'ciu~
Project Manager
Site Longitude: 80°15'35" West
Quantity Released: Unknown
Release Cause: Unknown
September 17, 2013
TABLE OF CONTENTS
Page No.
1.0 DISCUSSION OF SAMPLING RESULTS ........................................................................ 1
2.0 CONCLUSIONS AND RECOMMENDATIONS ............................................................. .4
3.0 RECOMMENDATIONS .................................................................................................... .4
4.0 LIMITATIONS .................................................................................................................... 5
Figure I:
Figure 2:
Figure 3:
Figure 4:
Figure 5:
Figure 6:
Figure 7:
Table I:
Table 2:
Table 3:
Site Location Map
Site Map
1500' Radius Map
LIST OF FIGURES
Groundwater Elevation Contour Map
Benzene Isoconcentration Map
1,2-Dichloroethane (DCA) Isoconcentration Map
Ethylene Dibromide (EDB) Isoconcentration Map
LIST OF TABLES
Summary of Adjacent Property and Water Supply Well Owners
Summary of Well Construction and Historical Groundwater Elevation Data
Summary of Historical Analytical Results -Groundwater Samples
APPENDICES
Appendix A: Laboratory Report -Groundwater Samples
H:\Projects\2000\I00/289-TFM#21Reports\ARMR Aug 2013\ARMR July2013.doc
Texaco Food Mart #2
Lexington, Davidson County, North Carolina
Incident#: 22332
1.0 DISCUSSION OF SAMPLING RESULTS
1.1 Site Monitoring Requirements:
Site Location Map:
Site Map:
See Figure I
See Figure 2
Site Monitoring Requirements
Based on CAP and/or NORR
Monitoring Report
September 17, 2013
Page 1
Sample Point Total Quantity of Previous Required by NCDENR to be
Type Sample Points and Their Monitored and Sampled per CAP
Identification
Monitoring 10
Wells (MW-I through MW-6, and T-1
through T-4)
Water Supply 13 (2)
Wells (WSW-I through WSW-13)
(I) Individual well identified by NCDENRfor specific sampling at this time.
(2) Number of wells located within 1,500/eet of site.
and/or TA
I (I)
(MW-2)
0
1.2 Summary of Analytical Results and Free Product Thickness(s):
1.2.1 Date(s) of Sampling Event: July 19, 2013
1.2.2 Existing Area Receptors:
A receptor survey was conducted in 200 I as presented in the CSA report dated May 2002
and the CAP dated October 2003.
Refer to the following Tables and Figure(s) for information and locations of area receptors
identified.
Refer to Figure(s):
Refer to Tables(s):
Figure 3
Table I
1.2.3 Groundwater Flow Direction:
• The groundwater flow direction is to the north-northeast.
Current and/or Historical Groundwater Elevation Data is included in the following Table and
Figure:
Refer to Table:
Refer to Figure:
Table 2
Figure 4
Texaco Food Mart #2 Monitoring Report
September 17, 2013
Page 2
Lexington, Davidson County, North Carolina
Incident#: 22332
1.2.4 Free Product:
• Free Product Detected During this Reporting Period?: No
1.2.5 Groundwater Analytical Results:
• Sampled Points and Analytical Methods:
The following monitoring wells and other points were sampled during this reporting
period.
Sampled Points and Analytical Methods
for this Reporting Period
Based on CAP and Pre-Annroval Task Authorization Samnline; Requirements
Type Points Sampled during this Analytical Methods
Reoortin!!' Period
Monitoring ( 6) (I) • EPA Method 6200B
Wells (MW-1 through MW-5 and T-1)
(I) Pre-Approval Task Authorization TA-22332-12
• Laboratory Used: Pace Analytical Services Inc. Huntersville, NC
• Current Groundwater Analytical Data:
Shield conducted bi-weekly air-sparging events in air sparge well AS-I using a portable
air-sparging unit to facilitate reduction of dissolved phase concentrations in MW-2. Air
sparging was conducted on AS-I for approximately 6 hours a day on March 19, April 3,
April 16, May I, May 14, and May 28, 2013. Air sparging could not safely be conducted
in MW-2 during the air sparging visits because those events were conducted during
business hours and MW-2 is in a high traffic area near the dispenser island.
On July 19, 2013 groundwater samples were collected from monitoring wells MW-I
through MW-5 and T-1. One or more concentrations of benzene, ethylbenzene, toluene,
total xylenes, MTBE, naphthalene, isopropylbenzene, n-propylbenzene, 1,2-
dichloroethane (1,2-DCA), ethylene dibromide (EDB), 1,2,4-trimethylbenzene, and
1,3,5-trimethylbenzene were detected at concentrations above the ISA NCAC 2L
Groundwater Standards (2L Standards) in MW-I, MW-2, MW-3, MW-4, and T-1.
Concentrations of benzene, 1,2-DCA, and EDB were detected at concentrations above
the North Carolina Department of Environment and Natural Resources (NCDENR) gross
contaminant levels (GCLs) in MW-2.
Refer to the following Table and Appendix for current groundwater analytical data.
Refer to Table:
Refer to Appendix:
Table 3
Appendix A
Texaco Food Mart #2
Lexington, Davidson County, North Carolina
Incident#: 22332
• Historical Groundwater Analytical Data:
Monitoring Report
September 17, 2013
Page 3
Total dissolved phase petroleum constituent compounds concentrations in monitoring
well MW-2 have increased in comparison to June 2012 data. It is likely that the increase
is related to the rise in the groundwater levels due to the increased rainfall that has
occurred during 2013.
Refer to the following table(s) for historical groundwater analytical data.
Refer to Table(s): Table 3
• Dissolved Phase Plume Size and Location:
The on-site dissolved phase plume is irregularly shaped and has an approximate length of
125 feet and width of 85 feet based on the benzene concentrations above 2L Standards.
The dissolved phase plume that is above the NCDENR GCLs is approximately 25 feet by
20 (Figure 5). The plume for constituents that are above the GCLs is located as shown
on the following figures.
Refer to Figure(s): Figures 5 through 7
• Proximity of Plume to Nearest Receptor(s):
Based on the receptor survey conducted in 2001, there are three (3) confirmed drinking
water supply wells and six (6) inactive supply wells located within 1,000 feet of the
source area. The closest drinking water supply well (WSW-1) is located approximately
450 feet south (hydraulically upgradient) of the site. No surface water bodies were
observed in the field or on the topographic map within 5 00-feet of the source area.
Refer to Figure:
Refer to Table:
Figure 3
Table 1
• Predictive Rate of Contaminant Transport:
The contaminant plume has been fairly immobile over the past several years.
Contaminant transport is typically in the same direction as groundwater flow, but with a
slower velocity.
Refer to Table(s): Tables 2 and 3
1.2.6 Other Field Data Collected:
• No additional field data was collected.
Texaco Food Mart #2
Lexington Davidson County, North Carolina
Incident#: 22332
2.0 CONCLUSIONS
Monitoring Report
September 17, 2013
Page 4
• Air sparging was conducted on AS-1 for approximately 6 hours per day on March 19,
April 3, April 16, May 1, May 14, and May 28, 2013.
• Free product was not detected in site wells during this reporting period.
• Dissolved phase petroleum constituent compounds were detected in concentrations above
21 Standards in monitoring wells MW-1 through MW-4 and T-1.
• Dissolved phase concentrations of benzene, 1,2-DCA, and EDB in MW-2 were above the
NCDENR GCLs.
• Dissolved phase petroleum constituent compound concentrations increased in monitoring
well MW-2 since June 2012. Dissolved phase petroleum constituent compound
concentrations also increased in monitoring wells MW-1, MW-4, and T-1 since March
2009, likely due to the rise in the groundwater level because of the increase in rainfall in
2013.
• Monitoring well MW-3 showed a decrease in contamination since March 2009.
• Three (3) privately owned drinking water supply wells were identified within a 1,000-
foot radius of the source area with the nearest confirmed drinking water supply well
approximately 450 feet upgradient from the source area. Based on a conversation with
Michael Rogers of the NCDENR on November 16,2010, since WSW-1 is approximately
450 feet updradient of the site and the property owner would not allow Shield or
NCDENR to sample their supply well, the Texaco Food Mart #2 site would likely be
reduced to low risk if soil excavation was completed to remove as much soil as feasibly
possible and ifMW-2 groundwater concentrations were below GCLs.
3.0 RECOMMENDATIONS
• It is recommended that bi-weekly air sparging be conducted to reduce the groundwater
concentrations to below GCLs, with NCDENR and Trust Fund approval.
• Once MW-2 is below the GCLs we will request a "no further action" determination from
theNCDENR.
Texaco Food Mart #2
Lexington Davidson County, North Carolina
Incident#: 22332
4.0 LIMITATIONS
Monitoring Report
September 17, 2013
Page 5
Shield has performed environmental services at the subject site on behalf ofTechno LLC for Holding
Brothers, Inc. Shield has performed this scope of work as an independent contractor/consultant using
reasonable care and skill in accordance and consistent with customary industry standards of
engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive
standard of care that can be applied to measure Shield's performance of the work. No other
warranty, expressed or implied is made or intended by Shield.
The report has been prepared for the exclusive use by Techno LLC for Holding Brothers, Inc. All
recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's
knowledge, opinion and belief, based upon information obtained during this scope ofTechno LLC
for Holding Brothers, Inc. and Shield. Conclusions are provided with the understanding that Shield
is presenting information and not rendering legal advice. If such advice is needed, legal counsel
should be consulted. It is the responsibility ofTechno LLC for Holding Brothers, Inc. under advice
of its counsel to notify the appropriate federal, state, or local public agencies as required by law; or
otherwise to disclose in a timely manner, any information that may be necessary to prevent damage
to human health, safety, or the environment.
Compliance with recommendations provided as part of this report in no way assures compliance with
federal, state and/or local laws, regulations, and/or requirements. Analytical data has been obtained
from Pace Analytical Services Inc. This information, to the extent that it was relied on to generate
this report, is assumed to be correct and complete. The work performed in conjunction with this
report and the data developed are intended as a description of available information at the dates and
specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or
recommendations with respect to any conditions that were knowingly or unknowingly withheld,
concealed, hidden, or in any way not disclosed or observable at the time of this scope of work.
1000
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4301 TAGGART CREEK ROAD
CHARLOTTE, NC 28206
704-3!14-fil113
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www.shioldonglnoenng.oom
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CHARLOTTE, NC 28208
704-394--6S13 704-394-6966tax
www.shielciengioeerfrg.com
SITE MAP
TEXACO FOOD MART #2
VPH VOLATILE PETROLEUM HYDROCARBONS WENDY'S PROPERTY
ill SCALE: 1 in. = 20 ft. DATE : 07 /25/13 DRAWN BY : RBS 6
0.": ,T, MW-
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1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA SHIELD# 1001289
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ACTIVE WATER SUPPLY WELL
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1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA
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VAPOR EXTRACTION WELL
AIR SPARGIMG WELL
FEET
GROUNDWATER ELEVATION CONTOUR LINE (ft)
GENERALIZED GROUNDWATER FLOW DIRECTION
GROUNDWATER ELEVATION (ft)
GROUNDWATER ELEVATION (ft) NOT USED IN CONTOURING
NOT MEASURED
NOTES: 1-DEPTHS TO GROUNDWATER MEASURED ffl/19/13.
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CONTOUR MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA SHIELD# 1001289
DATE: 07/25/13 DRAWN BY RBS
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AIR SPARGING WELL
MICROGRAMS PER UTER
(12,600) BENZENE CONCENTRATION (ug/L)
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S:! APPROXIMATE GRAPHIC SCALE ~~ ,0 1' 'i' DATE ·. 08/13/13 .... NOTES: 1· GROUNDWATER SAMPLES COLLECTED Ot-1 07/19/13. ;
1 -, 2-All LOCATIONS ARE APPROXIMATE. ~ 3-CONTOUR INTERVALS AS SHOWt-1. SCALE: 1 in.,. 30 ft. SCALE : AS SHOWN
1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA
SHIELD# 1001289
DRAWN BY RBS fl_ ____________________________ ~__,_..;...... __ ____. _______ _ FIGURE: 5
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~i~i§'.4~f!fo~~ED BY CBM ENVTROMENTAL SERVICES, INC.
VAPOR EXTRACTION WELL
AIR SPARGING WELL
MICROGRAMS PER LITER
1,2-DICHLOROETHANE (DCA) CONCENTRATION (11g/L)
1,2-DICHLOROETHANE {DCA) CONCENTRATION NOT USEC IN CONTOURING (11g/L)
--1,2-0ICHLOROETHAME {OCA) ISOCONCENTRATlON LINE (11g/L)
------1,2-□ICHLOROETHANE (OCA) ISOCONCEMTRATION LINE (11g/L) EXCEEDING GROSS CONTAMINANT LEVELS (GCls)
(NO) NOT DETECT· BELOW LABORATORY METHOD OETECTIOM LIMITS
(NS) NOT SAMPLED
@MW-5
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CONCRETE PAO
AMOCO RUSHCO #3
fi' MW-2
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• SYIELD 4301TAGGARTCREEKROAO
~ CHARLOTTE, NC 28208
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1,2-DICHLOROETHANE (DCA)
ISOCONCENTRA TION MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA
SHIELD# 1001289
i ~ -, NOTES: 1-GROUNDWATERSAMPLESCOLLECTEOON07/19/13. 0 15 •30
"'o,o 2-ALLLocAr10H5'"A?PRox"'"'· DATE: 08/13/13 DRAWN BY RBS
~ 3-CONTOUR IMTERVALS AS SHOWN. ;; .._ ______________________________________________________ _.:,:'CA..:LE:..' 1.,:'":..· ·_":..'';.,· ..... -1..:.S,::CA:;:L:::E:..:.: ...:,A:,:S.,:S:,:.H:::O~W!,!N;:_..L:F::.!l::G!!U~R=-E.:..: __ ,!!6 __ .J
~
~ I
LEGEND:
LIGHT POLE
POWER POLE
ELECTRICAL LINE
SANITARY SEWER LINE
~
N
MW-4@
(ND)
ASPHALT
----• PRODUCT LINE
Iii VE
TEXACO FOOD MART MONITORING WELL
TEXACO FOOD MART DEEP MONITORING WELL
AMOCO RUSHCO #3 MONITORING WELL ALL DATA TAKEN rROM THE PHASE II LIMITED SITE ASSESSMENT REPORT PREPARED BY CBM ENVIROMENTAL SERVICES, INC.
DATED 4/16/01.
VAPOR EXTRACTION WELL
AIR SPARGING WELL
MICROGRAMS PER LITER
ETHYLENE DIBROMlDE (EOB) CONCENTRATION (ug/L)
(ug/L)
(773)
[NO] ETHYLENE DI BROMIDE iEDB) CONCENTRATION NOT USED IN CONTOURING (ug/L)
----•ETHYLENE OtBROMIOE (EOB) l50CONCENTRAT10N LINE (ug/L)
2
'""""' / OISPENSffi~
------ETHYLENE OIBROMIOE (E06) ISOCONCENTFl:ATION LINE (ug/L) EXCEEDING GROSS CONTAMINANT LEVELS (GCLs)
(ND) NOT DETECTED • BELOW LABORATORY MET1iOD DETECTION LIMfTS
(NS) NOT SAMPLED
MW-6@
(NS)
VACANT LOT
REGULAR UST
I REGULAR
PITL __ uST __ __,
I SUPREME UST
SUPREME UST
TEXACO FOOD MART
TA
MW-3@
(ND)
ASPHALT
AS-5 AS-6
l!I BO Iii B VE-6 T-4 VE-7 (NS)
ClVCRHEAD E:LECTRIC
ACCESS ROAD
WENDY'S PROPERTY
@MW-5
(ND)-----------1
PARKINGARfA
D DISPENSER
□DISPENSER
0 TEMP-2.
(NS)
CEDAR LANE ROAD
DISPENSER □
DISPENSER □
TW,f 0 (NS)
0
MW-1 (NS)
2
~
I GASOLINE UST
~ I GASOLINE UST
8 I GASOLINE UST
Q!) TEMP-1
(NS)
OmsPENSER
□DISPENSER
DIESEL UST
CONCRETE PAD
'
' '
AMOCO
RUSHC0#3
Q!) MW-2
(NS)
• S'llIELD 4301 TAGGART CREEK ROAD
~ CHARLOTTE, NC 28208 ~,
-w ENGINEERING, INC. www.shi•ld•ngineerin;;.oom
ETHYLENE DIBROMIDE (EDB)
ISOCONCENTRATION MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTON, NORTH CAROLINA
SHIELD /11001289 ~ APPROXIMATE GRAPHIC SCALE
NOTES, 1-GROUNDW>TERSAMPLESCOLLEITTOON07/19/13. 15 JO DATE 08/13/13 DRAWN BY RBS ~ 2-ALL LOCATIONS ARE Af'PROXtMATE. :
c.. 3· CONTOUR INTERVALS AS SHOWN. f L.----------------------------------------------------------'CA_,_,,_, ;_, __ . '-"-'-__ L,.;;.SC:.A;.;L;;;E::..:..: _;A,;,;S;.;S:.;H.:.O:;.W:.:.:.:N_,L;,F.;.IG:.U~RE:;,.:.: __ ..:7 __ _,1
Table: 1
Summary of Adjacent Property and Water Supply Well Owners
Well# Wel!Owner/User(indicate ·1
which) .
WSW-I I Flowerest 0. Lopp
WSW-2 I Paul & Stella Baker
WS W-3 I Margaret H. Fuller
WSW-4 I Hoyle R. Smith
Efird E. Jr. & Kay S.
WSW-5 I Wilson
(owner)
WSW-6 I Abe Cassidy
WSW-7 I Mrs. Samuel C. Davis
WSW-8 I Maxine C. Houck
WSW-9 I Thomas Frank
WSW-10 I James G. Henderson
WSW-I I I Ray S. & Irene Musgrave
WSW-12 I Aubrey & Helen Brewer
WSW-13 I John '.f. '.fetter
Notes: Ft BGS = feet below ground surface
Texaco Food Mart #2
1700 Cotton Grove Road,
Lexington, North Carolina
NCDENR Incident# 22332
Address Phone
Number
;\1/eil
I Well u Iiepth '.fype se ..... . c.. (ft · .of
~
P.O. Box 284 Lexington, NC
I 04 Fuller Rd., Lexington, NC
I 06 Fuller Rd., Lexington, NC
115 Cedar Ln., Lexington, NC
6 Mayfair Rd., Lexington, NC*
Box 8 Mayfair Rd., Lexington,
NC
Box I 00 Mayfair Rd.,
Lexington, NC
Box 108 Mayfair Rd.,
Lexington, NC
Box I 07 Mayfair Rd,
Lexington, NC
Box 103 Mayfair Rd.,
Lexington, NC
1724 Southview Rd.,
Lexington, NC
I 02 Mayfair Rd., Lexington,
NC
l 04 Mayfair Rd., Lexington,
NC
-
336-357-
2511
336-357-
5231
336-357-
2659
336-357-
2916
336-249-
3266
336-357-
2485
336-357-
2565
NA
NA
NA
NA
NA
NA
BGSJ Well
Drinking 185 4"
Not in Use ? ?
Not in Use ? ?
Drinking ? ?
Not in Use ? ?
Not in Use ? ?
Not in Use ? ?
Drinking >100 4"
Not in Use ? ?
Not in Use ? ?
Not in Use ? ?
Irrigation ? ?
Drinking ? ?
Address of well. Property owner's address is 500 Maegeo Dr., Lexington
Well
Well Screen
Casing Jnterval
Depth fr to y ft. ·
(ft, BGS) · . BGSl
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
? ?
Of the property owners without PWS hook ups, only John Tetter is interested in be added to the PWS. Other property owners indicated that they are not interested at all.
NA -Not Accessible
Distlince
. ft-0m
Public
Water
source area Sy$tem,
ofrele!!Se hookilp
(fL)
450' No
700' Yes
650' Yes
985' No
750' Yes
760' Yes
795' Yes
1025' No
1090' Yes
1100' Unk.
1175' Unk.
800' Yes
850' No
H:\Projects\2000\1001289 ~ TFM#2\Reports\ARMR Aug 2013\Water Supply Well Information Table.doc
Date Well ID Installed
!Vll'l'-1 07/3 J/01
MW-2 U713 1101
MW-3 10/08101
,uu-4 IO/Oo/01
MW-5 04/04/02
MW-6 04104/02
T-1 1010,-01
Notes.
I. NM= Not Measured
2. NA= Not Applicable
Top of
Casing
Elevation
(feet)
JOO.Ou
JUU.b
100.1,
99.40
100.3,
101.4L
100.35
Table 2:
Summary of Well Construction and Historical Groundwater Elevation Data
Texaco Food Mart #2
Well
Diameter
(inches)
2
2
2
2
2
2
2
1700 Cotton Grove Road, Lexin2{on, North Carolina
NCDENR Incident# 22332
Field Measurements
As-built Total Depth to
Screened Static Depth Interval (feet) Gauging Date Depth Water (feet) (feet) (feet)
35 20-35 10/10/01 35.00 ?4.09
04/22/02 35.00 22.lJ
11/19/07 35.01 23.69
03/04/09 34.93 19.68
07/19/13 35.07 17.55
35 20-35 10/10/01 35.00 24.22
04/22/02 35.00 22.08
11/19/07 34.75 23.84
03/04/09 34.65 19.62
06/28/12 34.91 18.48
07/19/13 34.94 17.53
35 20-35 10110/01 3:J.00 24.27
04/22/02 35.00 21.93
11/19/07 35.03 24.10
03/04/09 34.96 19.35
07/19/13 35.08 17.23
35 .4v-35 10/10/01 3).00 24.11
04/22/02 35.00 21.91
11/19/07 34.81 23.88
03/04/09 34.74 19.90
07/20/10 34.72 18.57
07/19/13 34.90 17.90
35 20-35 04/22/02 1.5.00 23.34
11/19/07 35.07 24.76
03/04/09 35.09 21.17
07/19/13 35.12 19.02
25 15-25 04/22/02 ?5.00 23.fl2
11/19/07 25.00 NM
03/04/09 NM NM
90 85.5-90 10/10/01 90.00 24.93
04/22/02 90.00 22.06
11/19/07 86.71 21.59
03/04/09 65.82 19.52
07/19/13 66.84 18.14
sum of well construe/ion and historical groundwater elevation
Field Calculations
Depth to Diff. Between Ground-water Free As-Built and
Product Measured Total Elevation
(feet) (feet) Depth (feet)
NA 0 75.QJ
NA 0 77.87
NA -0.01 76.31
NA 0.07 80.32
NA -0.07 82.45
NA 0 75.78
NA 0 77.92
NA 0.25 76.35
NA 0.35 80.57
NA 0.09 81.71
NA 0.06 82.66
NA 0 75.92
NA 0 78.26
NA -0.03 76.09
NA 0.04 80.84
NA -0.08 82.96
NA 0 76.08
NA 0 78.28 NA 0.19 75.52 NA 0.26 79.50
NA 0.28 80.83
NA 0.10 81.50
NA 0 76.K5
NA -0.07 75.63
NA -0.09 79.22 NA -0.12 81.37
NA 0 77.17 NA 0 NM
NM NM NM
NA 0 75.26
NA 0 78.13
NA 3.29 78.76
NA 24.18 80.83
NA 23.16 82.21
Page I afJ
Analytical Methnd---->
' ! j
15A NCAC IL.0202 l ,oo Standard >
15A NCAC 2L.0ll5
Gross Co11ta111ioation 5,000 260,000
level->
Location Date • .
MW-I 07/31/0! ND SJ
04/30/03 " 340
Jl/!9/07 49.5 54.7
03/04/09 "·' 28.4
07/19/J3 69.4 87.4
MW-2 07131/01 /1,0/JO 38,000
04/30/03 12,000 29,000
IJ/19/07 U,9fJO 34,200
03/04/09 II,700 27,200
{16/28/12 8,930 17,800
07/l'J/13 11.600 24,300
MW-3 !0/!0/01 '" 4000
04130/03 JOO 3,000
11119/07 ND 4,850
03/04/09 NO 3,430
07/19/13 " 1,250
MW-< 10/10/0J ND ND
U413U/03 NO ND
ll/19/07 NO NO
03/04/09 ND 5.2
07/20/l() ND ND
07/19/13 '·' ND
MW,l 04t.l0/03 NO ND
1!1!9/07 ND ND
03104/09 ND ,.,
07/19/13 ND NO
T-l I0/10/01 "' '" 04130/03 17 2.8
tl/19/07 43.8 ND
03/04/(19 20.7 ND
07/19/13 )JS J0.6
N~,
Table 3:
Summary of Historical Analytical Re!lults-Groundwater Samples
Texaco Food Mart #2
1700 Cotton Grove Road, Lexington, North Carolina
NCDENR Incident# 22332
EPA EPA
EPA Melhnd 601/602 Method Method MADEP
;muor 62S or VPH
6200B 6200B
~ • • > Q
> " ~ • ! ' i ]; j 1 ~ i i t " .! :li • • ~ ' ~ J a i I " i ~ ::; !
600 500 " " ,., 0.02 ' 400
84,500 3S,500 20,000 70,000 400 so '·'""' -. • •·" . •·" • . ...
340 ,.,.. NR NR ND 0.96 " ND
13 1,470 NR ND ND NR "' NR
179 1,210 ND ND ND ND "' ND
'" '" ND ND ND ND '" "' "' "' '-4 ND NO ND ll4 NR
J,600 16,000 NR NR I,ZOO "" NR 81,0IHI
""' 16,700 NR ND 1,700 ND 1,400 NR
J,090 18,400 6,090 ND /,/50 ND 1,090 li0,100
2,250 14,500 J,600 ND ND ND '" 59,300
1,760 10,950 7,420 "' 1,090 "' '" NR
2,200 13,380 7,550 '" 1,110 m 1260 NR
1,800 8,600 NR NR ND 9.5 ,., ND
1,500 8,800 NR ND ND ND "' NR
2,190 13,600 ND ND ND ,., SJJ NR
2,090 11.400 ND ND ND NO J,520 5,560
1,.120 8,060 ,., ND ND NO 744 NR
NO ND NR ND ND ND ND NR
ND ND NR ND ND NR NO NR
ND ND 2,3 ND ND ND NO ND
ND Jl.6 4.3 ND ND NO 12.3 ND
NO ND '' ND NO ND ND NO
NO ,., 40 ND ND ND ND NR
ND NO NR NR ND NA NO NR
ND NO ND ND ND NO " M4
ND ND ND ND NO ND 2.9 NO
NO ND NO ND_ NO ND ND NR
94 "' NR NR 44 '·' 24 "'' ND !4.7 NR ND ,., NO 3.1 NR
ND ND "' ND ,., ND ND ND
NO ND ND ND 25.7 ND 14A 320
,.2 "' " , .• 23.9 ND '·' NR
ug/1; Micrograms per liter ND= Below Method Detection Limit
NR; Analysis not n:que.sted. Bold numi>ers e:<ceed !5A NCAC ZL.0202 standards
!5A NCAC 2L.0202; NCDENR Standard St11tute for non-risked based maximum allowable conlairummt concentration ingmundw~Ler
MADEPYPH& MADEP MADEPVPH&
EPH EPH EPH
. . 1 " " "' ~ ' ,. • ~ ~ g • t s Q. Q. -~ i -~ 1 ·i : E-a ' < < <
a+h~ &d•
'" I0,000 '" ... ... ... ..,, . •
3,470 ND 2,780
NR NR NR
66l ND "" 6,170 NO 2,200
NR NR NR
"·"" NR 9,100
NR NR NR
7l,600 '"" 26,630
58.930 ND 8,340
NR NR NR
NR NR NR
ll,990 ND 11,710
NR NR NR
34611 ND 2.440
40,926 ND 11,780
NR NR NR
NR NR NR
NR NR NR
ND ND ND
"' ND ND
ND ND ND
NR NR NR
NR NR NR
NO ND ND
ND ND ND
NR NR NR
"" NO 250
NR NR NR
ND ND ND
ND ND NO
NR NR NR
Itithctzed Bold numbers exooed, ~ Conl:aminiui!" Levels = As piesenfud 111 NCDENR ''Guidelines for Aase'ssment and ~ Action,." d.iled July 15, 2008, effective Januaiy 2010
Other detected analytes can be seen in the analytical data
Page 1 of 1
: ;2ceAnalyticat"
, www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] !
July 30, 2013
Ms. Flora D'Souza
Shield Engineering
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project Texaco Food Mart #2
Pace Project No.: 92165830
Dear Ms. D'Souza:
Enclosed are the analytical results for sample(s) received by the laboratory on July 19, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely, t~ "b~y
Jon D Bradley
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. Page 1 of 34
Pace Analytical Services, lnc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification#: 37706
North Carolina Field Services Certification#: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification#: 99006001
Florida/NELAP Certification #; E87627
Kentucky UST Certification #: 84
West Virginia Certification#: 357
VirginiaNELAP Certification#: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Lab ID Sample ID
92165830001 MW-1
92165830002 MW-2
92165830003 MW-3
92165830004 MW-4
92165830005 MW-5
92165830006 Trip Blank
92165830007 T-1
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical SeNices, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
SM 62008
SM 62008
SM 62008
SM 6200B
SM 6200B
SM 6200B
SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analysts
MCK
MCK
MCK
MCK
MCK
MCK
MCK
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Reported Laboratory
64 PASI-C
64 PASI-C
64 PASI-C
64 PASI-C
64 PASI-C
64 PASI-C
64 PASI-C
Page 3 of 34
Project:
Pace Project No.:
Lab Sample ID
Method
92165830001
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
92165830002
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
92165830003
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
SM 62008
92165830004
SM 62008
SM 6200B
SM 62008
SM 62008
SM 62008
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
HITS ONLY
Texaco Food Mart #2
92165830
Client Sample ID
Parameters Result Units
MW-1
Benzene 69.4 ug/L
Chloroform 8.4 ug/L
Ethylbenzene 121 ug/L
lsopropylbenzene (Cumene) 30.4 ug/L
Methyl-tert-butyl ether 7.4 ug/L
Naphthalene 114 ug/L
n-Propyfbenzene 35.9 ug/L
Toluene 87.4 ug/L
1,2,4-Trimethylbenzene 398 ug/L
1,3,5-Trimethylbenzene 24.0 ug/L
m&p-Xylene 449 ug/L
a-Xylene 318 ug/L
MW-2
Benzene 12600 ug/L
1,2-Dibromoethane (EDB) 773 ug/L
1,2-Dichloroethane 1330 ug/L
Diisopropyl ether 194 ug/L
Ethylbenzene 2200 ug/L
lsopropylbenzene (Cumene) 93.0 ug/L
Methyl-tert-butyl ether 7550 ug/L
Naphthalene 1260 ug/L
n-Propylbenzene 233 ug/L
Toluene 24300 ug/L
1,2,4-Trimethylbenzene 2330 ug/L
1,3,5-Trimethylbenzene 529 ug/L
m&p-Xylene 8540 ug/L
a-Xylene 4840 ug/L
MW-3
Benzene 22.0 ug/L
sec-Butylbenzene 22.4 ug/L
Ethyfbenzene 1420 ug/L
lsopropylbenzene (Cumene) 145 ug/L
Methyl-tert-butyl ether 7.3 ug/L
Naphthalene 744 ug/L
n-Propylbenzene 377 ug/L
Toluene 1250 ug/L
1,2,4-Trimethylbenzene 2630 ug/L
1,3,5-Triniethylbenzene 2460 ug/L
m&p-Xylene 5420 ug/L
a-Xylene 2640 ug/L
MW-4
Benzene 1.9 ug/L
Chloroform 6.0 ug/L
Methyl-tert-butyl ether 40.0 ug/L
1,2,4-Trimethylbenzene 1.6 ug/L
m&p-Xylene 3.5 ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Report Limit
2.5
2.5
2.5
2.5
2.5
10.0
2.5
2.5
2.5
2.5
5.0
2.5
250
25.0
25.0
25.0
25.0
25.0
25.0
100
25.0
250
25.0
25.0
50.0
25.0
0.50
0.50
50.0
0.50
0.50
200
50.0
50.0
50.0
50.0
100
50.0
0.50
0.50
0.50
0.50
1.0
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analyzed Qualifiers
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/23/13 22:13
07/24/1311:50
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/24/1311:50
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:30
07/23/13 22:46
07/23/13 22:46
07/24/13 12:06
07/23/13 22:46
07/23/13 22:46
07/24/13 12:06
07/24/13 12:06
07/24/1312:06
07/24/13 12:06
07/24/13 12:06
07/24/13 12:06
07/24/13 12:06
07/26/1316:56
07/26/13 16:56
07/26/13 16:56
07/26/13 16:56
07 /26/13 16:56
Page 4 of 34
Project:
Pace Project No.:
Lab Sample ID
Method
92165830004
SM6200B
92165830007
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Texaco Food Mart #2
92165830
Client Sample ID
Parameters Result Units
MW-4
o-Xylene 1.1 ug/L
T-1
Benzene 135 ug/L
1,2-Dichloroethane 23.9 ug/L
Diisopropyl ether 2.4 ug/L
Ethylbenzene 6.2 ug/L
lsopropylbenzene (Cumene) 1.8 ug/L
Methyl-tert-butyl ether 83.0 ug/L
Naphthalene 7.7 ug/L
n-Propylbenzene 0.62 ug/L
Toluene 30.6 ug/L
1,2,4-Trimethylbenzene 7.4 ug/L
1,3,5-Trimethylbenzene 1.3 ug/L
m&p-Xylene 16.7 ug/L
a-Xylene 10.4 ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Report Limit
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
0.50
0.50
1.0
0.50
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analyzed Qualifiers
07/26/13 16:56
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
07/23/13 23:36
Page 5 of 34
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Project: Texaco Food Mart #2
Pace Project No.; 92165830
Method: SM 62008
Description: 62008 MSV
Client: Shield
Date: July 30, 2013
General Information:
PROJECT NARRATIVE
Asheville, NC 28804
[phone]
7 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/23706
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 1015205)
• 1,2-Dibromo-3-chloropropane
QC Batch: MSV/23737
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 1017236)
• 1,2-Dibromo-3-chloropropane
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/23706
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92165837008
MO: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 1015206)
• 1,2-Dibromo-3-chloropropane
• MSD (Lab ID: 1015207)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. Page 6 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Method: SM 6200B
Description: 62008 MSV
Client: Shield
Date: July 30, 2013
QC Batch: MSV/23706
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92165837008
MO: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• 1,2-Dibromo-3-chloropropane
R1: RPO value was outside control limits.
• MSD (Lab ID: 1015207)
• Bromomethane
• Methyl-tert-butyl ether
QC Batch: MSV/23737
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92166062001
MO: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 1018572)
• Dichlorodifluoromethane
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 34
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Parameters
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chtorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichtoroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichforopropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-0ichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
Lab ID: 92165830001 Collected: 07/19/1311:35 Received: 07/19/1314:30 Matrix: Water
Results Units
Analytical Method: SM 6200B
69.4 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
8.4 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
121 ug/L
ND ug/L
30.4 ug/L
ND ug/L
7.4 ug/L
114 ug/L
35.9 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ugll
Report Limit DF Prepared
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
25.0 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
5.0 5
2.5 5
5.0 5
2.5 5
2.5 5
5.0 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
10.0 5
2.5 5
10.0 5
2.5 5
10.0 5
2.5 5
2.5 5
2.5 5
2.5 5
2.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fuU,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No.
07123113 22:13 71-43-2
07123/1322:13 108-86-1
07123113 22:13 74-97-5
07/23113 22:13 75-27-4
07123113 22:13 75-25-2
07123/13 22:13 74-83-9
07123/13 22:13 104-51-8
07123113 22: 13 135-98-8
07 /23113 22: 13 98-06-6
07/23113 22:13 56-23-5
07/23/13 22:13 108-90-7
07123/13 22:13 75-00-3
07/23113 22:13 67-66-3
07/23113 22:13 74-87-3
07123/13 22:13 95-49-8
07/23113 22:13 106-43-4
07/23/13 22:13 96-12-8
07/23/13 22:13 124-48-1
07/23/13 22:13 106-93-4
07/23/13 22:13 74-95-3
07 /23/13 22: 13 95-50-1
07/23113 22:13 541-73-1
07/23/13 22:13 106-46-7
07/23/13 22:13 75-71-8
07/23/13 22:13 75-34-3
07 /23/13 22: 13 107-06-2
07/23/13 22:13 75-35-4
07/23/13 22:13 156-59-2
07/23/13 22:13 156-60-5
07/23/13 22:13 78-87-5
07/23/13 22:13 142-28-9
07 /23/13 22: 13 594-20-7
07 /23/13 22: 13 563-58-6
07123113 22:13 10061-01-5
07123113 22:13 10061-02-6
07/23113 22:13 108-20-3
07/23/13 22:13 100-41-4
07 /23/13 22: 13 87-68-3
07/23/13 22:13 98-82-8
07/23/13 22:13 75-09-2
07 /23/13 22: 13 1634-04-4
07/23/13 22:13 91-20-3
07/23/13 22:13 103-65-1
07/23/13 22:13 100-42-5
07 /23/13 22: 13 630-20-6
07 /23/13 22: 13 79-34-5
07/23113 22:13 127-18-4
Qual
Page a of 34
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
{336)623-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-1
Parameters
6200B MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S}
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
Lab ID: 92165830001 Collected: 07/19/1311:35 Received: 07/19/1314:30 Matrix: Water
Results Units Rei:,ort Limit OF Prepared
Analytical Method: SM 6200B
87.4 ug/L 2.5 5
ND ug/L 10.0 5
ND ug/L 10.0 5
ND ug/L 2.5 5
ND ug/L 2.5 5
ND ug/L 2.5 5
ND ug/L 5.0 5
ND ug/L 2.5 5
398 ug/L 2.5 5
24.0 ug/L 2.5 5
ND ug/L 5.0 5
449 ug/L 5.0 5
318 ug/L 2.5 5
97 % 70-130 5
98 % 70-130 5
99 % 70-130 5
101 % 70-130 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CASNo. Qual
07 /23/13 22: 13 108-88-3
07/23/13 22:13 87-61-6
07/23/13 22:13 120-82-1
07/23/13 22:13 71-55-6
07/23/13 22:13 79-00-5
07/23/13 22:13 79--01-6
07 /23/13 22: 13 75-69-4
07/23/13 22:13 96-18-4
07/23/13 22:13 95-63-6
07/23/1322:13 108-67-8
07/23/13 22:13 75-01-4
07/23/13 22:13 179601-23-1
07/23/13 22:13 95-47-6
07/23/13 22:13 17060-07-0
07/23/13 22:13 1868-53-7
07/23/1322:13 460-00-4
07/23/13 22:13 2037-26-5
Page 9 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-2
Parameters
Pa Ce Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165830002 Collected: 07/19/1311:42 Received: 07/19/1314:30 Matrix: Water
Results Units RepOrt Limit DF Prepared Analyzed GAS No. Qual
6200BMSV Analytical Method: SM 6200B
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
12600 ug/L 250 500
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 250 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 50.0 50
ND ug/L 25.0 50
ND ug/L 50.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 50.0 50
ND ug/L 25.0 50
773 ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
1330 ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
194 ug/L 25.0 50
2200 ug/L 25.0 50
ND ug/L 100 50
93.0 ug/L 25.0 50
ND ug/L 100 50
7550 ug/L 25.0 50
1260 ug/L 100 50
233 ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ln full,
without the written consent of Pace Analytical Services, Inc ..
07 /24/13 11 :50 71-43-2
07 /23/13 22:30 108-86-1
07 /23/13 22:30 74-97-5
07 /23/13 22:30 75-27-4
07/23/13 22:30 75-25-2
07 /23/13 22:30 74-83-9
07/23/13 22:30 104-51-8
07/23/13 22:30 135-98-8
07/23/13 22:30 98-06-6
07 /23/13 22:30 56-23-5
07/23/13 22:30 108-90-7
07/23/13 22:30 75-00-3
07 /23/13 22:30 67-66-3
07/23/13 22:30 74-87-3
07/23/13 22:30 95-49-8
07 /23/13 22:30 106-43-4
07 /23/13 22:30 96-12-8
07 /23/13 22:30 124-48-1
07/23/13 22:30 106-93-4
07/23/13 22:30 74-95-3
07/23/13 22:30 95-50-1
07 /23/13 22:30 541-73-1
07 /23/13 22:30 106-46-7
07/23/13 22:30 75-71-8
07/23/13 22:30 75-34-3
07/23/13 22:30 107-06-2
07/23/13 22:30 75-35-4
07/23/13 22:30 156-59-2
07/23/13 22:30 156-60-5
07/23/13 22:30 78-87-5
07/23/13 22:30 142-28-9
07/23/13 22:30 594-20-7
07/23/13 22:30 563-58-6
07 /23/13 22:30 10061-01-5
07/23/13 22:30 10061-02-6
07/23/13 22:30 108-20-3
07 /23/13 22:30 100-41-4
07/23/13 22:30 87-68-3
07/23/13 22:30 98-82-8
07/23/13 22:30 75-09-2
07/23/13 22:30 1634-04-4
07/23/13 22:30 91-20-3
07/23/13 22:30 103-65-1
07/23/13 22:30 100-42-5
07/23/13 22:30 630-20-6
07/23/13 22:30 79-34-5
07/23/13 22:30 127-18-4
Page 10 of34
Project Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-2
Parameters
Pace· Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165830002 Collected: 07/19/1311:42 Received: 07/19/1314:30 Matrix: Water
Results Units Report.Limit DF Prepared Analyzed GAS No. Qual
6200B MSV Analytical Method: SM 6200B
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
24300 ugil 250 500
ND ug/L 100 50
ND ug/L 100 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 25.0 50
ND ug/L 50.0 50
ND ug/L 25.0 50
2330 ug/L 25.0 50
529 ug/L 25.0 50
ND ug/L 50.0 50
8540 ug/L 50.0 50
4840 ug/L 25.0 50
97 % 70-130 50
94 % 70-130 50
98 % 70-130 50
101 % 70-130 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except !n full,
without the written consent of Pace Analytical Services, Inc ..
07/24/1311:50 108-88-3
07 /23/13 22:30 87-61-6
07 /23/13 22:30 120-82-1
07/23/13 22:30 71-55-6
07/23/1322:30 79-00-5
07/23/13 22:30 79-01-6
07 /23/13 22:30 75-69-4
07 /23/13 22:30 96-18-4
07/23/13 22:30 95-63-6
07/23/13 22:30 108-67-8
07 /23/13 22:30 75-01-4
07 /23/13 22:30 179601-23-1
07/23/13 22:30 95-47-6
07 /23/13 22:30 17060-07-0
07/23/13 22:30 1868-53-7
07 /23/13 22:30 460-00-4
07/23/13 22:30 2037-26-5
Page 11 of 34
12~· Pace A·nalytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road -Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
I [phone] [phone] [phone]
I
ANALYTICAL RESULTS
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-3 Lab ID: 92165830003 Collected: 07/19/1311:47 Received: 07/19/13 14:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 62008
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chtoromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
22.0 ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 5.0
ND ug/L 0.50
22.4 ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
1420 ug/L 50.0 100
ND ug/L 2.0
145 ug/L 0.50
ND ug/L 2.0
7.3 ug/L 0.50
744 ug/L 200 100
377 ug/L 50.0 100
ND u9/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
07/23/13 22:46 71-43-2
07/23/13 22:46 108-86-1
07 /23/13 22:46 74-97-5
07 /23/13 22:46 75-27-4
07 /23/13 22:46 75-25-2
07 /23/13 22:46 74-83-9
07/23/13 22:46 104-51-8
07 /23/13 22:46 135-98-8
07 /23/13 22:46 98-06-6
07 /23/13 22:46 56-23-5
07/23/13 22:46 108-90-7
07/23/13 22:46 75-00-3
07 /23/13 22:46 67-66-3
07 /23/13 22:46 74-87-3
07/23/13 22:46 95-49-8
07 /23/13 22:46 106-43-4
07/23/13 22:46 96-12-8
07 /23/13 22:46 124-48-1
07/23/13 22:46 106-93-4
07 /23/13 22:46 74-95-3
07/23/13 22:46 95-50-1
07 /23/13 22:46 541-73-1
07/23/13 22:46 106-46-7
07/23/13 22:46 75-71-8
07/23/13 22:46 75-34-3
07/23/13 22:46 107-06-2
07 /23/13 22:46 75-35-4
07/23/13 22:46 156-59-2
07/23/13 22:46 156-60-5
07/23/13 22:46 78-87-5
07/23/13 22:46 142-28-9
07 /23/13 22:46 594-20-7
07/23/13 22:46 563-58-6
07 /23/13 22:46 10061-01-5
07 /23/13 22:46 10061-02-6
07/23/13 22:46 108-20-3
07/24/1312:06 100-41-4
07/23/13 22:46 87-68-3
07/23/13 22:46 98-82-8
07/23/13 22:46 75-09-2
07/23/13 22:46 1634-04-4
07/24/13 12:06 91-20-3
07/24/13 12:06 103-65-1
07/23/13 22:46 100-42-5
07/23/13 22:46 630-20-6
07/23/13 22:46 79-34-5
07/23/13 22:46 127-18-4
Page 12 of 34
;2ceAnalytica!"
1 www,pace/abs.com
!
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-3
Parameters
Pace Ana"lytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
{336)623-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165630003 Collected: 07/19/1311:47 Received: 07/19/1314:30 Matrix; Water
Results Units Report Limit OF Prepared Analyzed ____ c__ ___ _;_ ___ _ CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichtorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
1250 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
2630 ug/L
2460 ug/L
ND ug/L
5420 ug/L
2640 ug/L
97 %
97 %
104 %
102 %
50.0
2.0
2.0
0.50
0.50
0.50
1.0
0.50
50.0
50.0
1.0
100
50.0
70-130
70-130
70-130
70-130
100
100
100
1
100
100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
07/24/13 12:06 108-88-3
07/23/13 22:46 87-61-6
07/23/13 22:46 120-82-1
07 /23/13 22:46 71-55-6
07 /23/13 22:46 79-00-5
07/23/13 22:46 79-01-6
07/23/13 22:46 75-69-4
07/23/13 22:46 96-18-4
07/24/1312:06 95-63-6
07 /24/13 12:06 108-67-8
07 /23/13 22:46 75-01-4
07/24/13 12:06 179601-23-1
07/24/1312:06 95-47-6
07/23/13 22:46 17060-07-0
07/23/13 22:46 1868-53-7
07/23/13 22:46 460-00-4
07 /23/13 22:46 2037-26-5
Page 13 of34
Pace Analy.tical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-4
Parameters
6200BMSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichtoromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1 , 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichtoropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
Lab JD: 92165830004 Collected: 07/19/13 11 :52 Received: 07/19/13 14:30 Matrix: Water
Results Units Report Limit· DF Prepared Analyzed GAS No. Qual -------------------
Analytical Method: SM 62008
1.9 ug/L 0.50 07/26/1316:56 71-43-2
ND ug/L 0.50 07 /26/13 16:56 108-86-1
ND ug/L 0.50 07 /26/13 16:56 74.97.5
ND ug/L 0.50 07 /26/13 16:56 75-27-4
ND ug/L 0.50 07/26/1316:56 75-25-2
ND ug/L 5.0 07/26/1316:56 74-83-9
ND ug/L 0.50 07 /26/13 16:56 104-51-8
ND ug/L 0.50 07/26/1316:56 135-98-8
ND ug/L 0.50 07/26/1316:56 98-06-6
ND ug/L ·o.5o 07 /26/13 16:56 56-23-5
ND ug/L 0.50 07 /26/13 16:56 108-90-7
ND ug/L 1.0 07/26/13 16:56 75-00-3
6.0 ug/L 0.50 07/26/1316:56 67-66-3
ND ug/L 1.0 07/26/1316:56 74-87-3
ND ug/L 0.50 07 /26/13 16:56 95-49-8
ND ug/L 0.50 07/26/1316:56 106-43-4
ND ug/L 1.0 07/26/1316:56 96-12-8
ND ug/L 0.50 07 /26/13 16:56 124-48-1
ND ug/L 0.50 07/26/1316:56 106-93-4
ND ug/L 0.50 07 /26/13 16:56 74.95.3
ND ug/L 0.50 07 /26/13 16:56 95-50-1
ND ug/L 0.50 07 /26/13 16:56 541-73-1
ND ug/L 0.50 07/26/13 16:56 106-46-7
ND ug/L 0.50 07/26/13 16:56 75-71-8
ND ug/L 0.50 07/26/1316:56 75.34.3
ND ug/L 0.50 07/26/1316:56 107-06-2
ND ug/L 0.50 07/26/1316:56 75.35-4
ND ug/L 0.50 07/26/13 16:56 156-59-2
ND ug/L 0.50 07/26/13 16:56 156-60-5
ND ug/L 0.50 07 /26/13 16:56 78-87-5
ND ug/L 0.50 07 /26/13 16:56 142-28-9
ND ug/L 0.50 07 /26/13 16:56 594-20-7
ND ug/L 0.50 07/26/1316:56 563-58-6
ND ug/L 0.50 07/26/1316:56 10061-01-5
ND ug/L 0.50 07/26/13 16:56 10061-02-6
ND ug/L 0.50 07/26/13 16:56 108-20-3
ND ug/L 0.50 07/26/13 t6:56 100-41-4
ND ug/L 2.0 07/26/13 16:56 87-68-3
ND ug/L 0.50 07/26/13 16:56 98-82-8
ND ug/L 2.0 07/26/1316:56 75-09-2
40.0 ug/L 0.50 07/26/1316:56 1634-04-4
ND ug/L 2.0 07 /26/13 16:56 91-20-3
ND ug/L 0.50 07/26/1316:56 103-65-1
ND ug/L 0.50 07/26/13 16:56 100-42-5
ND ug/L 0.50 07/26/1316:56 630-20-6
ND ug/L 0.50 07/26/13 16:56 79.34.5
ND ug/L 0.50 07/26/13 t6:56 127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. Page 14 of34
Pace AnalytiCal Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Ashevme, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-4
Parameters
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichtoroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
Lab ID: 92165830004 Collected: 07/19/1311:52 Received: 07/19/1314:30 Matrix: Water
Results Units Report Limit OF Prepared
Analytical Method: SM 62008
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
1.6 ug/L 0.50
ND ug/L o."50
ND ug/L 1.0
3.5 ug/L 1.0
1.1 ug/L 0.50
101 % 70-130
99 % 70-130
96 % 70-130
99 % 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No. Qual
07/26/1316:56 108-88-3
07 /26/13 16:56 87-61-6
07/26/1316:56 120-82-1
07/26/13 16:56 71-55-6
07 /26/13 16:56 79-00-5
07 /26/13 16:56 79-01-6
07/26/13 16:56 75-69-4
07/26/1316:56 96-18-4
07 /26/13 16:56 95-63-6
07 /26/13 16:56 108-67-8
07/26/1316:56 75-01-4
07/26/1316:56 179601-23-1
07 /26/13 16:56 95-47-6
07/26/13 16:56 17060-07-0
07/26/13 16:56 1868-53-7
07 /26/13 16:56 460-00-4
07 /26/13 16:56 2037-26-5
Page 15 of34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-5
Parameters
Pace Analyticai Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165830005 Collected: 07/19/13 12:10 Received: 07/19/13 14:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed GAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
Bromobenzene
Bromochloromethane
Bromodfchloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichtorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichtoropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethytbenzene
Hexachloro-1,3-butadiene
Jsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 5.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fu!I,
without the written consent of Pace Analytlcal Services, Inc ..
07/26/1317:13 71-43-2
07/26/1317:13 108-86-1
07/26/1317:13 74-97-5
07/26/13 17:13 75-27-4
07/26/13 17:13 75-25-2
07/26/13 17:13 74-83-9
07/26/13 17:13 104-51-8
07/26/1317:13 135-98-8
07/26/1317:13 98-06-6
07/26/1317:13 56-23-5
07/26/1317:13 108-90-7
07/26/1317:13 75-00-3
07/26/1317:13 67-66-3
07/26/13 17:13 74-87-3
07/26/13 17:13 95-49-8
07/26/13 17:13 106-43-4
07/26/1317:13 96-12-8
07/26/1317:13 124-48-1
07/26/1317:13 106-93-4
07/26/13 17:13 74-95-3
07/26/13 17:13 95-50-1
07/26/13 17:13 541-73-1
07/26/13 17:13 106-46-7
07/26/13 17:13 75-71-8
07/26/13 17:13 75-34-3
07/26/13 17:13 107-06-2
07/26/13 17:13 75-35-4
07/26/1317:13 156-59-2
07/26/1317:13 156-60-5
07/26/1317:13 78-87-5
07/26/1317:13 142-28-9
07/26/13 17:13 5·94-20-7
07/26/13 17:13 563-58-6
07/26/13 17:13 10061-01-5
07/26/13 17:13 10061-02-6
07/26/13 17:13 108-20-3
07/26/1317:13 100-41-4
07/26/1317:13 87-68-3
07/26/1317:13 98-82-8
07/26/1317:13 75-09-2
07/26/1317:13 1634-04-4
07/26/1317:13 91-20-3
07/26/1317:13 103-65-1
07/26/13 17:13 100-42-5
07/26/13 17:13 630-20-6
07/26/13 17:13 79-34-5
07/26/1317:13 127-18-4
Page 16 of 34
, ;!!lceAnalytica!"
1 www.pacelabs.com
I
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: MW-5
Parameters
62008 MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
Lab ID: 92165830005 Collected: 07/19/1312:10 Received: 07/19/1314:30 Matrix: Water
Results Units Report Limit D.F Prepared
Analytical Method: SM 62008
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
99 % 70-130
98 % 70-130
95 % 70-130
99 % 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No. Qual
07/26/1317:13 108-88-3
07/26/1317:13 87-61-6
07/26/1317:13 120-82-1
07/26/13 17:13 71-55-6
07/26/1317:13 79-00-5
07/26/1317:13 79-01-6
07/26/13 17:13 75-69-4
07/26/1317:13 96-18-4
07/26/1317:13 95-63-6
07/26/1317:13 108-67-8
07/26/1317:13 75-01-4
07/26/13 17:13 179601-23-1
07/26/1317:13 95-47-6
07/26/1317:13 17060-07-0
07/26/1317:13 1868-53-7
07/26/1317:13 460-00-4
07/26/1317:13 2037-26-5
Page 17 of 34
Project Texaco Food Mart #2
Pace Project No.: 92165830
Sample: Trip Blank
Parameters
Pace Analytical sei-vlces, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
{336)623-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165830006 Collected: 07/19/13 00:00 Received: 07/19/13 14:30 Matrix: Water
Results Units Report Limit DF · Prepared Analyzed -----------'-------CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichtoropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 5.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50 1
ND ug/L 0.50 1
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
07/23/13 21:40 71-43-2
07/23/1321:40 108-86-1
07/23/13 21:40 74-97-5
07 /23/13 21 :40 75-27-4
07/23/13 21:40 75-25-2
07/23/13 21:40 74-83-9
07/23/1321 :40 104-51-8
07/23/13 21:40 135-98-8
07/23/13 21:40 98-06-6
07/23/13 21:40 56-23-5
07/23/13 21:40 108-90-7
07/23/13 21:40 75-00-3
07/23/1321:40 67-66-3
07/23/13 21:40 74-87-3
07/23/13 21:40 95-49-8
07/23/13 21:40 106-43-4
07/23/13 21:40 96-12-8
07/23/1321 :40 124-48-1
07/23/13 21:40 106-93-4
07/23/13 21:40 74-95-3
07/23/13 21:40 95-50-1
07/23/13 21:40 541-73-1
07/23/13 21:40 106-46-7
07/23/13 21:40 75-71-8
07/23/13 21:40 75-34-3
07/23/13 21:40 107-06-2
07/23/13 21:40 75-35-4
07 /23/13 21 :40 156-59-2
07 /23/13 21 :40 156-60-5
07 /23/13 21 :40 78-87-5
07/23/13 21:40 142-28-9
07/23/13 21:40 594-20-7
07/23/13 21:40 563-58-6
07/23/13 21:40 10061-01-5
07/23/13 21:40 10061-02-6
07/23/13 21:40 108-20-3
07/23/13 21:40 100-41-4
07/23/13 21:40 87-68-3
07/23/13 21:40 98-82-8
07/23/13 21:40 75-09-2
07/23/1321:40 1634-04-4
07/23/1321 :40 91-20-3
07/23/13 21:40 103-65-1
07/23/1321 :40 100-42-5
07/23/13 21:40 630-20-6
07/23/13 21:40 79-34-5
07/23/13 21:40 127-18-4
Page 18 of34
Pace Analytical Servfoes, Inc.
205 East Meadow Road • Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: Trip Blank
Parameters
6200B MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
Surrogates
1,2-Dichloroethane-d4 (S}
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
Lab ID: 92165830006 Collected: 07/19/13 00:00 Received: 07/19/1314:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: SM 62008
ND ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 1.0
ND ug/L 0.50
97 % 70-130
98 % 70-130
96 % 70-130
101 % 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No. Qual
07/23/1321:40 108-88-3
07/23/1321:40 87-61-6
07/23/13 21:40 120-82-1
07/23/13 21:40 71-55-6
07/23/1321 :40 79-00-5
07/23/13 21:40 79-01-6
07/23/13 21:40 75-69-4
07/23/1321:40 96-18-4
07/23/1321 :40 95-63-6
07/23/13 21:40 108-67-8
07/23/1321 :40 75-01-4
07/23/1321:40 179601-23-1
07/23/13 21:40 95-47-6
07 /23/13 21 :40 17060-07-0
07/23/1321:40 1868-53-7
07/23/13 21:40 460-00-4
07/23/1321 :40 2037-26-5
Page 19 of34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Parameters
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
{828)254-7176
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92165830007 Collected: 07/19/1312:00 Received: 07/19/1314:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual -----------------
62008 MSV Analytical Method: SM 62008
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n_-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichforoethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1, 1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 07/30/2013 04:41 PM
135 ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 5.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50 1
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
23.9 ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
2.4 ug/L 0.50
6.2 ug/L 0.50
ND ug/L 2.0
1.8 ug/L 0.50
ND ug/L 2.0
83.0 ug/L 0.50
7.7 ug/L 2.0
0.62 ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
07/23/13 23:36 71-43-2
07/23/13 23:36 108-86-1
07/23/13 23:36 74-97-5
07/23/13 23:36 75-27-4
07 /23/13 23:36 75-25-2
07/23/13 23:36 74-83-9
07/23/13 23:36 104-51-8
07/23/13 23:36 135-98-8
07 /23/13 23:36 98-06-6
07/23/13 23:36 56-23-5
07/23/13 23:36 108-90-7
07/23/13 23:36 75-00-3
07/23/13 23:36 67-66-3
07/23/13 23:36 74-87-3
07 /23/13 23:36 95-49-8
07/23/13 23:36 106-43-4
07/23/13 23:36 96-12-8
07 /23/13 23:36 124-48-1
07/23/13 23:36 106-93-4
07/23/13 23:36 74-95-3
07/23/13 23:36 95-50-1
07/23/13 23:36 541-73-1
07/23/13 23:36 106-46-7
07/23/13 23:36 75-71-8
07/23/13 23:36 75-34-3
07 /23/13 23:36 107-06-2
07/23/13 23:36 75-35-4
07/23/13 23:36 156-59-2
07/23/13 23:36 156-60-5
07/23/13 23:36 78-87-5
07/23/13 23:36 142-28-9
07/23/13 23:36 594-20-7
07/23/13 23:36 563-58-6
07/23/13 23:36 10061-01-5
07/23/13 23:36 10061-02-6
07/23/13 23:36 108-20-3
07/23/13 23:36 100-41-4
07 /23/13 23:36 87-68-3
07/23/13 23:36 98-82-8
07/23/13 23:36 75-09-2
07 /23/13 23:36 1634-04-4
07/23/13 23:36 91-20-3
07/23/13 23:36 103-65-1
07/23/13 23:36 100-42-5
07/23/13 23:36 630-20-6
07/23/13 23:36 79-34-5
07/23/13 23:36 127-18-4
Page 20 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Sample: T-1
Parameters
Pace Analytical Services; Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvi!Je, NC 28078
[phone]
Lab ID: 92165830007 Collected: 07/19/1312:00 Received: 07/19/1314:30 Matrix: Water
Results Units Report Limit OF Prepared Analyzed GAS No. Qual
6200B MSV Analytical Method: SM 62008
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Tric;:hlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xy/ene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
30.6 ug/L 0.50
ND ug/L 2.0
ND ug/L 2.0
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 0.50
ND ug/L 1.0
ND ug/L 0.50
7.4 ug/L 0.50
1.3 ug/L 0.50
ND ug/L 1.0
16.7 ug/L 1.0
10.4 ug/L 0.50
97 % 70-130
97 % 70-130
98 % 70-130
100 % 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
07/23/13 23:36 108-88-3
07 /23/13 23:36 87-61-6
07 /23/13 23:36 120-82-1
07 /23/13 23:36 71-55-6
07/23/13 23:36 79-00-5
07/23/13 23:36 79-01-6
07 /23/13 23:36 75-69-4
07 /23/13 23:36 96-18-4
07/23/13 23:36 95-63-6
07 /23/13 23:36 108-67-8
07 /23/13 23:36 75-01-4
07/23/13 23:36 179601-23-1
07/23/13 23:36 95-47-6
07 /23/13 23:36 17060-07-0
07/23/13 23:36 1868-53-7
07/23/13 23:36 460-00-4
07 /23/13 23:36 2037-26-5
Page 21 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
QC Batch: MSV/23706
Pace Analytical Services, Irie.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Seivices, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 62008
QC Batch Method: SM 62008 Analysis Description: 62008 MSV
Associated Lab Samples: 92165830001, 92165830002, 92165830003, 92165830006, 92165830007
METHOD BLANK: 1015204 Matrix: Water
Associated Lab Samples: 92165830001,92165830002, 92165830003,92165830006, 92165830007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1, 1, 1,2-Tetrachloroethane ug/L ND 0.50 07/23/13 21:23
1, 1, 1-Trichloroethane ug/L ND 0.50 07/23/13 21:23
1, 1,2,2-Tetrachloroethane ug/L ND 0.50 07/23/13 21:23
1, 1,2-Trichloroethane ug/L ND 0.50 07/23/13 21:23
1, 1-Dichloroethane ug/L ND 0.50 07/2_3/13 21:23
1, 1-Dichforoethene ug/L ND 0.50 07/23/13 21:23
1, 1-Dichloropropene ug/L ND 0.50 07/23/13 21:23
1,2,3-Trichlorobenzene ug/L ND 2.0 07/23/13 21:23
1,2,3-Trichloropropane ug/L ND 0.50 07/23/13 21:23
1,2,4-Trichlorobenzene ug/L ND 2.0 07/23/13 21:23
1,2,4-Trimethylbenzene ug/L ND 0.50 07/23/13 21:23
1 ,2-Dibromo-3-chloropropane ug/L ND 1.0 07/23/13 21:23
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/23/13 21:23
1,2-Dichlorobenzene ug/L ND 0.50 07/23/13 21:23
1,2-Dichloroethane ug/L ND 0.50 07/23/13 21:23
1,2-Dichloropropane ug/L ND 0.50 07/23/13 21:23
1,3,5-Trimethylbenzene ug/L ND 0.50 07/23/13 21:23
1,3-Dichlorobenzene ug/L ND 0.50 07/23/13 21:23
1,3-Dichloropropane ug/L ND 0.50 07/23/13 21:23
1,4-Dichlorobenzene ug/L ND 0.50 07/23/13 21:23
2,2-Dichloropropane ug/L ND 0.50 07/23/13 21:23
2-Chlorotoluene ug/L ND 0.50 07/23/13 21:23
4-Chforotoluene ug/L ND 0.50 07/23/13 21:23
Benzene ug/L ND 0.50 07/23/13 21:23
Bromobenzene ug/L ND 0.50 07/23/13 21:23
Bromochloromethane ug/L ND 0.50 07/23/13 21:23
Bromodichloromethane ug/L ND 0.50 07/23/13 21:23
Bromoform ug/L ND 0.50 07/23/13 21:23
Bromomethane ug/L ND 5.0 07/23/13 21:23
Carbon tetrachloride ug/L ND 0.50 07/23/13 21:23
Chlorobenzene ug/L ND 0.50 07 /23/13 21 :23
Chloroethane ug/L ND 1.0 07 /23/13 21 :23
Chloroform ug/L ND 0.50 07/23/13 21:23
Chloromethane ug/L ND 1.0 07/23/13 21:23
cis-1,2-Dichloroethene ug/L ND 0.50 07/23/1321 :23
cis-1,3-Dichloropropene ug/L ND 0.50 07/23/1321 :23
Dibromochloromethane ug/L ND 0.50 07/23/13 21:23
Dibromomethane ug/L ND 0.50 07 /23/13 21 :23
Dichlorodifluoromethane ug/L ND 0.50 07/23/13 21:23
Diisopropyl ether ug/L ND 0.50 07 /23/13 21 :23
Ethylbenzene ug/L ND 0.50 07/23/13 21:23
Hexachloro-1,3-butadiene ug/L ND 2.0 07/23/13 21:23
lsopropylbenzene (Cumene) ug/L ND 0.50 07/23/13 21:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/30/2013 04:41 PM wlthout the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
METHOD BLANK: 1015204
Paco Analytical Services, Inc:
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Matrix: Water
Associated Lab Samples: 92165830001,92165830002,92165830003,92165830006, 92165830007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
m&p-Xylene ug/L ND 1.0 07/23/13 21:23
Methyl-tert-butyl ether ug/L ND 0.50 07/23/13 21:23
Methylene Chloride ug/L ND 2.0 07/23/13 21:23
n-Butylbenzene ug/L ND 0.50 07/23/13 21:23
n-Propylbenzene ug/L ND 0.50 07/23/13 21:23
Naphthalene ug/L ND 2.0 07/23113 21:23
o-Xyler,e ug/L ND 0.50 07123113 21:23
sec-Butylbenzene ug/L ND 0.50 07/23113 21:23
Styrene ug/L ND 0.50 07123113 21:23
tert-Butylbenzene ug/L ND 0.50 07/23i13 21:23
Tetrachloroethene ug/L ND 0.50 07123113 21:23
Toluene ug/L ND 0.50 07/23113 21:23
trans-1,2-Dichloroethene ug/L ND 0.50 07123113 21 :23
trans-1,3-Dichloropropene ug/L ND 0.50 07123113 21:23
Trichloroethene ug/L ND 0.50 07123113 21:23
Trichlorofluoromethane ug/L ND 1.0 07/23113 21:23
Vinyl chloride ug/L ND 1.0 07123/13 21 :23
1,2-Dichloroethane-d4 (S) % 99 70-130 07123113 21 :23
4-Bromofluorobenzene (S) % 97 70-130 07/23113 21:23
Dibromofluoromethane (S) % 97 70-130 07123113 21:23
Toluene-dB (S) % 100 70-130 07123113 21:23
LABORATORY CONTROL SAMPLE: 1015205
Spike LCS LCS %Rec
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
{704)875-9092
Parameter Units Cone. Result %Rec Limits Qualifiers
1, 1, 1,2-Tetrachloroethane ug/L 50 52.9 106 60-140
1, 1, 1-Trichloroethane ug/L 50 55.7 111 60-140
1, 1,2,2-Tetrachloroethane ug/L 50 51.0 102 60-140
1, 1,2-Trichloroethane ug/L 50 54.3 109 60-140
1, 1-Dichloroethane ug/L 50 52.7 105 60-140
1, 1-Dichloroethene ug/L 50 50.9 102 60-140
1, 1-Dichloropropene ug/L 50 52.2 104 60-140
1,2,3-Trichlorobenzene ug/L 50 50.6 101 60-140
1,2,3-Trichloropropane ug/L 50 46.2 92 60-140
1,2,4-Trichlorobenzene ug/L so 50.2 100 60-140
1,2,4-Trimethylbenzene ug/L 50 52.0 104 60-140
1,2-Dibromo-3-chloropropane ug/L 50 76.8 154 60-140 CU,L3
1,2-Dibromoethane (EDB) ug/L 50 53.5 107 60-140
1,2•Dichlorobenzene ug/L 50 51.7 103 60-140
1,2-Dichloroethane ug/L 50 46.8 94 60-140
1,2-Dichloropropane ug/L 50 49.7 99 60-140
1,3,5-Trimethylbenzene ug/L 50 51.4 103 60-140
1,3-Dichlorobenzene ug/L 50 50.6 101 60-140
1,3-Dichloropropane ug/L 50 47.7 95 60-140
1 ,4-Dichlorobenzene ug/L 50 49.9 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/30/2013 04:41 PM without the written consent of Pace Analytical Services, Inc .. Page 23 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE: 1015205
Parameter
2,2-Dichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorototuene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromom·ethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachforo-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
tert-Butylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene u9/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
Date: 07/30/2013 04:41 PM
Spike LCS LCS
Units Cone. Result %Rec
50 47.1 94
50 50.3 101
50 52.2 104
50 50.9 102
50 50.1 100
50 54.2 108
50 53.2 106
50 46.1 92
50 43.3 87
50 57.3 115
50 50.2 100
50 49.1 98
50 50.0 100
50 43.2 86
50 50.9 102
50 45.1 90
50 46.1 92
50 54.5 109
50 37.2 74
50 52.8 106
50 50.0 100
50 49.7 99
50 52.4 105
100 102 102
50 66.1 132
50 55.0 110
50 51.6 103
50 50.7 101
50 55.1 110
50 51.2 102
50 53.1 106
50 54.3 109
50 50.4 101
50 50.2 100
50 50.1 100
50 47.8 96
50 45.6 91
50 48.4 97
50 41.8 84
50 46.3 93
99
100
101
101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
%Rec
Limits
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
70-130
70-130
70-130
70-130
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 2807B
[phone]
Qualifiers
Page 24 of 34
12~"!!.· Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road -Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
' ' {336)623-8921 [phone] [phone]
I
QUALITY CONTROL DATA
Project: Texaco Food Mart #2
Pace .Project No.: 92165830
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1015206 1015207
MS MSD
92165837008 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPO Qual
1, 1, 1,2-Tetrachforoethane ug/L <0.50 20 20 23.1 23.3 116 117 60-140 1
1, 1, 1-Trichloroethane ug/L <0.50 20 20 24.6 25.4 123 127 60-140 3
1, 1,2,2-Tetrachloroethane ug/L <0.50 20 20 21.9 21.5 110 107 60-140 2
1, 1,2-Trichloroethane ug/L <0.50 20 20 24.2 23.2 121 116 60-140 4
1, 1-Dichloroethane ug/L <0.50 20 20 24.0 23.8 120 119 60-140 1
1, 1-Dichloroethene ug/L <0.50 20 20 25.8 24.2 129 121 60-140 6
1, 1-Dichloropropene ug/L <0.50 20 20 24.6 24.1 123 120 60-140 2
1,2,3-Trictilorobenzene ug/L <2.0 20 20 21.6 21.1 108 105 60-140 2
1,2,3-Trichloropropane ug/L <0.50 20 20 20.2 19.7 101 99 60-140 2
1,2,4-Trichlorobenzene ug/L <2.0 20 20 21.3 20.9 106 104 60-140 2
1,2,4-Trimethylbenzene ug/L <0.50 20 20 23.7 23.4 119 117 60-140
1,2-Dibromo-3-chloropropane ug/L <1.0 20 20 29.7 28.5 148 143 60-140 4 MO
1,2-Dibromoethane (EDB) ug/L <0.50 20 20 22.4 22.8 112 114 60-140 1
1,2-Dichlorobenzene ug/L <0.50 20 20 23.1 22.6 116 113 60-140 2
1,2-Dichloroethane ug/L <0.50 20 20 21.1 20.5 105 102 60-140 3
1,2-Dichloropropane ug/L <0.50 20 20 22.6 21.8 113 109 60-140 3
1,3,5-Trimethylbenzene ug/L <0.50 20 20 24.0 23.3 120 117 60-140 3
1,3-Dichlorobenzene ug/L <0.50 20 20 22.9 22.7 114 113 60-140
1,3-Dichloropropane ug/L <0.50 20 20 20.8 20.6 104 103 60-140 1
1,4-Dichlorobenzene ug/L <0.50 20 20 22.6 21.9 113 110 60-140 3
2,2-Dichloropropane ug/L <0.50 20 20 14.7 19.8 74 99 60-140 29
2-Chlorotoluene ug/L <0.50 20 20 23.5 23.0 118 115 60-140 2
4-Chlorotoluene ug/L <0.50 20 20 24.1 23.2 121 116 60-140 4
Benzene ug/L <0.50 20 20 23.7 23.1 118 116 60-140 2
Bromobenzene ug/L <0.50 20 20 22.5 22.1 113 111 60-140 2
Bromochloromethane ug/L <0.50 20 20 25.3 24.5 127 122 60-140 3
Bromodichloromethane ug/L <0.50 20 20 22.2 22.6 111 113 60-140 2
Bromofom1 ug/L <0.50 20 20 18.4 18.8 92 94 60-140 2
Bromomethane ug/L <5.0 20 20 12.4 20.9 62 104 60-140 51 R1
Carbon tetrachloride ug/L <0.50 20 20 24.1 25.4 121 127 60-140 5
Chlorobenzene ug/L <0.50 20 20 23.4 22.7 117 114 60-140 3
Chloroethane ug/L <1.0 20 20 25.0 25.5 125 128 60-140 2
Chloroform ug/L <0.50 20 20 22.8 22.8 114 114 60-140 0
Chloromethane ug/L <1.0 20 20 16.4 15.9 82 79 60-140 3
cis-1,2-Dichloroethene ug/L <0.50 20 20 23.7 23.1 118 115 60-140 3
cis-1,3-Dichloropropene ug/L <0.50 20 20 17.0 18.5 85 92 60-140 8
Dibromochloromethane ug/L <0.50 20 20 19.0 19.7 95 98 60-140 3
Dibromomethane ug/L <0.50 20 20 23.8 23.2 119 116 60-140 2
Dichlorodifluoromethane ug/L <0.50 20 20 15.6 15.0 78 75 60-140 4
Diisopropyl ether ug/L <0.50 20 20 23.7 23.4 119 117 60-140 1
Ethylbenzene ug/L <0.50 20 20 23.9 23.2 119 116 60-140 3
Hexachloro-1,3-butadiene ug/L <2.0 20 20 21.6 22.2 108 111 60-140 3
lsopropylbenzene (Cumene) ug/L <0.50 20 20 24.7 24.1 124 121 60-140 2
m&p-Xylene ug/L <1.0 40 40 48.6 47.1 122 118 60-140 3
Methyl-tert-butyl ether ug/L <0.50 20 20 18.4 27.5 92 138 60-140 39 R1
Methylene Chloride ug/L <2.0 20 20 23.2 23.1 116 115 60-140 0
n-Butylbenzene ug/L <0.50 20 20 22.9 22.5 115 113 60-140 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ln full,
Date: 07/30/2013 04:41 PM without the written consent of Pace Analytical Services, Inc .. Page 25 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
{336)623-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
{828)254-7176
QUALITY CONTROL DATA
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1015206 1015207
Parameter
n-Propylbenzene
Naphthalene
o-Xytene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethane
Trichlorofluoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Brbmofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
MS MSD
92165837008 Spike Spike MS MSD
Units
u9/L
u9/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
Result Cone. Cone. Result Result
<0.50 20 20 24.1 23.4
<2.0 20 20 23.0 22.5
<0.50 20 20 24.0 23.2
<0.50 20 20 24.9 24.5
<0.50 20 20 24.3 23.4
<0.50 20 20 23.7 23.1
<0.50 20 20 24.0 23.3
<0.50 20 20 23.4 22.9
<0.50 20 20 22.9 22.2
<0.50 20 20 16.5 18.5
<0.50 20 20 23.0 22.0
<1.0 20 20 21.8 21.4
<1.0 20 20 22.0 21.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
MS
% Rec
120
115
120
125
121
119
120
117
114
83
115
109
110
97
100
98
100
MSD
%Rec
117
112
116
122
117
116
117
114
110
93
110
107
107
97
99
101
100
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits RPO Qual
60-140 3
60-140 2
60-140 3
60-140 2
60-140 4
60-140 3
60-140 3
60-140 2
60-140 3
60-140 11
60-140 5
60-140 2
60-140 3
70-130
70-130
70-130
70-130
Page 26 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
QC Batch: MSV/23737
QC Batch Method: SM 62008
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
. [phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 62008
Analysis Description: 62008 MSV
Associated Lab Samples: 92165830004,92165830005
METHOD BLANK: 1017235 Matrix: Water
Associated Lab Samples: 92165830004,92165830005
Parameter
1, 1, 1,2-Tetrachloroethane ug/L
1, 1, 1-Trichloroethane ug/L
1 , 1,2,2-Tetrachloroethane ug/L
1, 1,2-Trichloroethane ug/L
1, 1-Dichloroethane ug/L
1, 1 -Dichloroethene ug/L
1, 1-Dichloropropene ug/L
1,2,3-Trichlorobenzene ug/L
1,2,3-Trichloropropane ug/L
1,2,4-Trichlorobenzene ug/L
1,2,4-Trimethylbenzene ug/L
1,2-Dibromo-3-chloropropane ug/L
1,2-Dibromoethane (EDB) ug/L
1,2-Dichlorobenzene ug/L
1,2-Dichloroethane ug/L
1,2-Dichloropropane ug/L
1,3,5-Trimethylbenzene ug/L
1,3-Dichlorobenzene ug/L
1,3-Dichloropropane ug/L
1,4-Dichlorobenzene ug/L
2,2-Dichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorotoluene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bramoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
Date: 07/30/2013 04:41 PM
Blank Reporting
Units Result Limit Analyzed
ND a.so 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07 /26/13 13:54
ND 0.50 07 /26/13 13:54
ND 0.50 07/26/13 13:54
ND 2.0 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 2.0 07/26/1313:54
ND 0.50 07/26/1313:54
ND 1.0 07/26/13 13:54
ND a.so 07/26/1313:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 5.0 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 1.0 07/26/1313:54
ND 0.50 07/26/1313:54
ND 1.0 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 0.50 07/26/1313:54
ND 2.0 07/26/1313:54
ND 0.50 07/26/1313:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 34
Project: Texaco Food Mart #2
Pace Project No.: 92165830
METHOD BLANK: 1017235
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical Seivlces, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Matrix: Water
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Associated Lab Samples: 92165830004,92165830005
Parameter Units
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
tert-Butylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
LABORATORY CONTROL SAMPLE: 1017236
Parameter
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trichloroethane
1, 1-Dichforoethane
1, 1-Dichloroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trlmethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 2.0 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 2.0 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0,50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 0.50 07/26/13 13:54
ND 1.0 07/26/13 13:54
ND 1.0 07/26/13 13:54
100 70-130 07/26/13 13:54
97 70-130 07/26/1313:54
97 70-130 07/26/1313:54
99 70-130 07/26/1313:54
Spike LCS LCS %Rec
Cone. Result % Rec Limits Qualifiers
50 59.4 119 60-140
50 56.3 113 60--140
50 56.6 113 60-140
50 55.9 112 60-140
50 53.1 106 60-140
50 46.7 93 60-140
50 53.1 106 60-140
50 56.4 113 60-140
50 51.2 102 60-140
50 56.4 113 60-140
50 56.9 114 60--140
50 78.4 157 60-140 CU,F3,L3
50 57.2 114 60-140
50 55.4 111 60-140
50 47.7 95 60-140
50 49.6 99 60-140
50 55.6 111 60-140
50 54.4 109 60-140
50 51.0 102 60-140
50 53.8 108 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/30/2013 04:41 PM without the written consent of Pace Analytical Servlces, Inc .. Page 28 of 34
Project: Texaco Food Mart #2
Pace Project.No.: 92165830
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
(3~6)623-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE: 1017236
Parameter
2,2-Dichloropropane ug/L
2-Chlorotoluene ug/L
4-Chlorotoluene ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
lsopropylbenzene (Cumene) ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
n-Butylbenzene ug/L
n-Propylbenzene ug/L
Naphthalene ug/L
a-Xylene ug/L
sec-Butylbenzene ug/L
Styrene ug/L
tert-Butylbenzene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
Date: 07130/2013 04:41 PM
Spike LCS LCS
Units Cone. Result %Rec
50 48.7 97
50 55.3 111
50 56.8 114
50 51.2 102
50 52.1 104
50 51.1 102
50 56.2 112
50 49.8 100
50 64.5 129
50 59.6 119
50 53.7 107
50 44.9 90
50 51.4 103
50 54.2 108
50 52.0 104
50 46.9 94
50 50.0 100
50 53.9 108
50 44.0 88
50 53.8 108
50 55.4 111
50 58.1 116
50 59.0 118
100 114 114
50 54.2 108
50 50.3 101
50 58.5 117
50 55.3 111
50 63.0 126
50 56.4 113
50 58.6 117
50 59.8 120
50 55.5 111
50 54.5 109
50 51.8 104
50 49.0 98
50 46.5 93
50 49.7 99
50 42.1 84
50 54.1 108
98
101
102
99
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
%Rec
Limits
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
·60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
60-140
70-130
70-130
70-130
70-130
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 29 of 34
Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road -Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacefabs.com Eden, NC 27288 Ashevrfle, NC 28804 Huntersville, NC 28078
(336)_623-8921 [phone] [phone]
QUALITY CONTROL DATA
Project: Texaco Food Mart #2
Pace Project No.: 92165830
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1018572 1018573
MS MSD
92166062001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result % Rec %Rec Limits RPD Qual
1, 1, 1,2-Tetrachloroethane ug/L ND 20 20 18.0 22.5 90 112 60-140 22
1, 1, 1-Trichloroethane ug/L ND 20 20 18.6 22.8 93 114 60-140 21
1, 1,2,2-Tetrachloroethane ug/L ND 20 20 16.5 20.8 82 104 60-140 23
1, 1,2-Trichloroethane ug/L ND 20 20 16.8 21.2 84 106 60-140 23
1, 1-Dichloroethane ug/L ND 20 20 17.8 22.4 89 112 60-140 23
1, 1-Dichloroethene ug/L ND 20 20 17.1 21.9 85 109 60-140 25
1, 1-Dichloropropene ug/L ND 20 20 17.5 22.3 88 112 60-140 24
1,2,3-Trichlorobenzene ug/L ND 20 20 16.2 20.3 81 101 60-140 22
1,2,3-Trichloropropane ug/L ND 20 20 15.0 19.0 75 95 60-140 24
1,2,4-Trichlorobenzene ug/L ND 20 20 16.8 20.8 84· 104 60-140 21
1,2,4-Trimethylbenzene ug/L ND 20 20 18.0 22.7 90 114 60-140 23
1,2-Dibromo-3-chloropropane ug/L ND 20 20 20.5 26.5 102 132 60-140 26
1,2-Dibromoethane (EDB) ug/L ND 20 20 17.3 21.4 87 107 60-140 21
1,2-Dichlorobenzene ug/L ND 20 20 17.2 21.6 86 108 60-140 22
1,2-Dichloroethane ug/L ND 20 20 15.3 19.2 77 96 60-140 23
1,2-Dichloropropane ug/L ND 20 20 15.6 19.7 78 98 60-140 23
1,3,5-Trimethylbenzene ug/L ND 20 20 18.0 22.4 90 112 60-140 22
1,3-Dichlorobenzene ug/L ND 20 20 17.3 21.3 86 107 60-140 21
1,3-Dichloropropane ug/L ND 20 20 15.8 19.9 79 99 60-140 23
1,4-Dichlorobenzene ug/L ND 20 20 17.3 21.6 87 108 60-140 22
2,2-Dichloropropane ug/L ND 20 20 17.5 19.4 87 97 60-140 11
2-Chlorotoluene ug/L ND 20 20 17.5 21.9 88 109 60-140 22
4-Chlorotoluene ug/L ND 20 20 18.3 22.8 92 114 60-140 22
Benzene ug/L ND 20 20 16.4 21.1 82 105 60-140 25
Bromobenzene ug/L ND 20 20 16.3 21.0 81 105 60-140 25
Bromochloromethane ug/L ND 20 20 17.8 22.7 89 114 60-140 24
Bromodichloromethane ug/L ND 20 20 16.8 21.3 84 107 60-140 24
Bromoform ug/L ND 20 20 16.1 20.0 80 100 60-140 22
Bromomethane ug/L ND 20 20 17.4 20.0 87 100 60-140 14
Carbon tetrachloride ug/L ND 20 20 19.2 23.9 96 119 60-140 22
Chlorobenzene ug/L ND 20 20 17.1 21.5 86 108 60-140 23
Chforoethane ug/L ND 20 20 19.0 25.5 95 128 60-140 29
Chlorofom, ug/L ND 20 20 16.5 20.7 82 104 60-140 23
Chloromethane ug/L ND 20 20 15.1 18.5 75 93 60-140 20
cis-1,2-Dichloroethene ug/L ND 20 20 17.5 21.7 87 108 60-140 21
cis-1,3-Dichloropropene ug/L ND 20 20 15.3 18.9 77 94 60-140 21
Dibromochloromethane ug/L ND 20 20 16.4 20.0 82 100 60-140 20
Dibromomethane ug/L ND 20 20 16.3 20.9 81 104 60-140 25
Dichlorodifluoromethane ug/L ND 20 20 10.5 13.4 53 67 60-140 24 MO
Diisopropyl ether ug/L ND 20 20 17.4 22.1 87 110 60-140 23
Ethylbenzene ug/L ND 20 20 17.7 22.4 89 112 60-140 23
Hexachloro-1,3-butadiene ug/L ND 20 20 17.3 21.0 86 105 60-140 20
lsopropylbenzene (Cumene) ug/L ND 20 20 18.8 23.7 94 119 60-140 23
m&p-Xylene ug/L ND 40 40 36.8 44.7 92 112 60-140 19
Methyl-tert-butyl ether ug/L ND 20 20 16.0 17.3 80 86 60-140 8
Methylene Chloride ug/L ND 20 20 17.3 21.7 87 108 60-140 22
n-Butylbenzene ug/L ND 20 20 18.6 22.8 93 114 60-140 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/30/2013 04:41 PM without the written consent of Pace Analytical Services, Jnc .. Page 30 of 34
Project: Texaco Food Mart #2
Pace Project No.; 92165830
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
(336)6~3-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1018572 1018573
Parameter
n-Propylbenzene
Naphthalene
a-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-dB (S)
Date: 07/30/2013 04:41 PM
MS MSD
92166062001 Spike Spike MS MSD
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
Result Cone. Cone. Result Result
ND 20 20 18.4 22.9
ND 20 20 17.3 21.9
ND 20 20 17.4 22.1
ND 20 20 19.2 23.7
ND 20 20 17.2 23.2
ND 20 20 17.8 22.4
ND 20 20 17.5 21.7
ND 20 20 21.2 22.2
ND 20 20 17.2 21.4
ND 20 20 15.7 18.5
ND 20 20 15.7 20.2
ND 20 20 17.3 21.7
ND 20 20 17.8 21.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, !nc ..
MS
%Rec
92
87
87
96
86
89
87
104
85
79
79
87
89
99
99
102
100
MSD
% Rec
115
109
110
119
116
112
109
110
106
92
101
109
109
100
100
103
100
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
{704)875-9092
%Rec
Limits RPO Qual
60-140 22
60-140 23
60-140 23
60-140 21
60-140 30
60-140 23
60-140 22
60-140 5
60-140 22
60-140 16
60-140 25
60-140 23
60-140 21
70-130
70-130
70-130
70-130
Page 31 of 34
Pac·e Analytical Services, Inc.
2225 Riverside Dr. aeAnalyticat"
1 www.pacelabs.com
Pace Analytical Services, lnc.
205 East Meadow Road -Suite A
Eden, NC 27288
{336)623~8921
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvi11e, NC 28078
[phone] I
QUALIFIERS
Project: Texaco Food Mart #2
Pace Project No.: 92165830
DEFINITIONS
OF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL -Pace Reporting Limit.
RL -Reporting Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values.
LCS(D) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPO -Relative Percent Difference
NC -Not Calculable.
SG -Silica Gel -Clean-Up
U -Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services -Charlotte
ANALYTE QUALIFIERS
CU The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.
F3 The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
R1 RPO value was outside control limits.
REPORT OF LABORATORY ANALYSIS
Dale: 07/30/2013 04:41 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. Page 32 of 34
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
(336)623-8~21
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Texaco Food Mart #2
Pace Project No.: 92165830
Lab ID Sample ID
92165830001 MW-1
92165830002 MW-2
92165830003 MW-3
92165830004 MW-4
92165830005 MW-5
92165830006 Trip Blank
92165830007 T-1
Date: 07/30/2013 04:41 PM
QC Batch Method QC Batch
SM 6200B MSV/23706
SM 6200B MSV/23706
SM 6200B MSV/23706
SM 6200B MSV/23737
SM 6200B MSV/23737
SM 6200B MSV/23706
SM 6200B MSV/23706
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analytical
Analytical Method Batch
Page 33 of 34
,J'2ceMalytical
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Section A
R~qlJl~d Client Information:
Company· Shie!d Engineering
Address: 4301 Tag_gart Creek Roa_Q
Charlotte, NC 28208
Email To· -fdsouz ineering.com
Phone: ~7~0_4__,,,3~-=~~~
Request~d Due OateITAT. 1 a De.@.µ!!)__
SAMPLE ID
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(A..Z, 0-9/, -)
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CHAIN-OF-CUSTODY/ Analytical Request Document
The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section B
Required Project lnformatio11:
Report To: Flora O'Souza
C?PY To·
Purchase Order No. 1001289-12
Client Project 10: Texaco Food Mart #2
Container Order Number: 8157 4
MATRIX co~
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At\entioo: Flora D'Souza
~ompany Name: _ Shield Engineering
Address: 4301 Taggart Creek Road, Charlotte, N _.-.;.·;.,,,._;.:; ,,:,-~R"nijlllllt01;{Ag'en¢y· •.-._...,,,.
Pace Quote Reference:
Pace Project Manager: Bradley, Jon
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