WS-6081_22332_CA_MRP_20090429

MONITORING REPORT
TEXACO FOODMART #2
R.ECEIVE!> N,C, Dept. of ENI'/
APR 2 4 ?009
Winston.Salem
Regional Office
1700 COTTON GROVE ROAD
LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA
INCIDENT NO. 22332
Responsible Party:
Techno, LLC for Holding
Brothers, Inc
P.O. Drawer 647
Concord, NC 28026
Contact:
David Holding
[phone]
SHIELD PROJECT NO. 1001289
December 2007 -March 3, 2009
Consultant:
Shield Engineering, Inc.
4301 Taggart Creek Road
Charlotte, North Carolina 28208
Contact:
David A. Stoner
[phone]
Property Owner:
Holding Brothers, Inc.
P.O. Drawer 647
Concord, North Carolina 28208
Contact:
David Holding
[phone]
Site Risk Classification: High Risk (Hl55D)
Land Use Category: Residential and commercial
Release Discovered: February 8, 1999
Site Latitude: 35°46'41" North
Site Longitude: 80°15'35" West
Quantity Released: Unknown
Release Cause: Unknown Potential Release Source(s): Unknown
~ {'jpA~ /Cft
Project Manager
Registered NC #2077
April 14, 2009
TABLE OF CONTENTS
Page No.
1.0 DISCUSSION OF SAMPLING RESULTS ........................................................................ 1
2.0 CONCLUSIONS AND RECOMMENDATIONS .............................................................. 4
3.0 RECOMMENDATIONS .................................................................................................... 4
4.0 LIMITATIONS ................................................................................................................... 5
Figure 1:
Figure 2:
Figure 3:
Figure 4:
Figure 5:
Figure 6:
Figure 7:
Figure 8:
Figure 9:
Figure 10:
Figure 11:
Table 1:
Table 2:
Table 3:
Table 4:
Site Location Map
Site Map
1500' Radius Map
LIST OF FIGURES
Groundwater Elevation Contour Map
Benzene Isoconcentration Map
Toluene Isoconcentration Map
Ethylbenzene Isoconcentration Map
Total Xylenes Isoconcentration Map
MTBE Isoconcentration Map
1,2-Dichloroethane Isoconcentration Map
Naphthalene Isoconcentration Map
LIST OF TABLES
Summary of Adjacent Property and Water Supply Well Owners
Summary of Well Construction and Historical Groundwater Elevation Data
Summary of Analytical Results -Groundwater Samples
Summary of Historical Analytical Results -Groundwater Samples
APPENDICES
Appendix A: Mobile Multi-Phase Extraction Report
Appendix B: Field Measurements
Appendix C: Laboratory Report -Groundwater Samples
H:\Projects\2000\100/289\Reports\ARMR 4_09\ARMR April 2009.doc
Texaco Food Mart #2
Lexington, Davidson County, North Carolina
Incident#: 22332
1.0 DISCUSSION OF SAMPLING RESULTS
1.1 Site Monitoring Requirements:
Site Location Map:
Site Map:
See Figure I
See Figure 2
Site Monitoring Requirements
Based on CAP and/or NORR
Monitoring Report
April 14, 2009
Page I
Sample Point Total Quantity of Previous Required by NCDENR to be
Type Sample Points and Their Monitored and Sampled per CAP
Identification and/or TA
Monitoring 10 6 (!)
Wells (MW-I through MW-6, and T-1 (MW-I through MW-5, and T-1)
through T-4)
Water Supply 13 \SJ 0
Wells (WSW-I through WSW-13)
(I) Individual wells identified by NCDENRfor specific sampling at this time.
(2) Number of wells located within 1,500 feet of site.
1.2 Summary of Analytical Results and Free Product Thickness(s):
1.2.1 Date(s) of Sampling Event:
• Monitoring wells were sampled on March 4, 2009.
1.2.2 Existing Area Receptors:
A receptor survey was conducted in 2001 as presented in the CSA report dated May 2002
and the CAP dated October 2003. An unofficial receptor survey update was conducted after
2003 as presented herein.
Refer to the following Tables and Figure(s) for information and locations of area receptors
identified.
Refer to Figure(s):
Refer to Tables(s):
Figure 3
Table I
1.2.3 Groundwater Flow Direction:
• Current groundwater flow direction is to the north-northeast.
Current and Historical Groundwater Elevation Data is included in the following Table(s),
Figure(s) and Appendix:
Refer to Table(s):
Refer to Figure(s):
Refer to Appendix:
Table 2
Figure 4
Appendix A
Texaco Food Mart #2 Monitoring Report
April 14, 2009
Page2
Lexington, Davidson County, North Carolina
Incident#: 22332
1.2.4 Free Product:
• Free Product Detected During this Reporting Period?: No
1.2.5 Groundwater Analytical Results:
• Sampled Points and Analytical Methods:
The following monitoring wells and other points were sampled during this reporting
period.
Sampled Points and Analytical Methods
for this Reporting Period
Based on CAP and Pre-Approval Task Authorization Samnlin11 Reauirements
Type Points Sampled during this Analytical Methods
Reportine Period
Monitoring (6) (I) • EPA Method 60 I and 602
Wells (MW-l,MW-2,MW-3,MW-4, extended (+MTBE, IPE, Total
MW-5, and T-1) Xylenes, EDB, Naphthalene),
• MADEP Extractable
Petroleum Hydrocarbons
(EPH) and Volatile Petroleum
' Hydrocarbons (VPH)
• EPA Method 625
(1) Pre-Approval TaskAuthorzzatwn TA-22332-05 (10/23/07)
• Laboratory Used: Pace Analytical Services Inc. Huntersville, NC
• Current Groundwater Analytical Data:
A month long Mobile Multi Phase Extraction (MMPE) event was performed on
monitoring wells MW-2, MW-3 and T-1 from January 5 through 30, 2009. A total of
8,695 gallons of petroleum-impacted groundwater were recovered from the wells. Based
on mass removal calculations 32.48 gallons of volatile organic compounds (VOCs) (as
gasoline) were removed as vapor. The MMPE report is included as Appendix A.
On March 3, 2009 groundwater samples were collected from the six monitoring wells.
One or more concentrations of benzene, ethylbenzene, toluene, total xylenes, MTBE,
naphthalene, 1, 2-dichloroethane (1,2-DCA), aromatics and aliphatics below the Cl9 to
C36 range were detected at concentrations above the !SA NCAC 21 Groundwater
Standards (21 Standards) in four site monitoring wells (MW-1, MW-2, MW-3 and T-1 ).
Refer to the following Table(s) and Appendix for current groundwater analytical data.
Refer to Table(s): Tables 3 and 4
Refer to Appendix: Appendix B and Appendix C
Texaco Food Mart #2
Lexington, Davidson County, North Carolina
Incident#: 22332
• Historical Groundwater Analytical Data:
Monitoring Report
April 14, 2009
Page3
Total dissolved phase petroleum constituent compounds concentrations in monitoring
wells MW-1, MW-2, MW-3 and T-1 have generally decreased in comparison to
November 2007 data although some constituents have increased.
Refer to the following table(s) for historical groundwater analytical data.
Refer to Table(s): Table 4
• Dissolved Phase Plume Size and Location:
The dissolved phase naphthalene plume is the largest contaminant plume greater than the
15A NCAC 21 Groundwater Standards (21 Standards). It is elliptical in size and has an
approximate length of 120 feet and width of 70 feet. The isoconcentration maps can be
seen in the following Figures.
Refer to Figure(s): Figures 5 through 11
• Proximity of Plume to Nearest Receptor(s):
Based on the last receptor survey conducted in 2001, as well as an update conducted after
2003, there are three (3) confirmed drinking water supply wells and five (5) inactive
supply wells located within 1,000 feet of the source area. The closest drinking water
supply well (WSW-!) is located approximately 450 feet south of the site. No surface
water bodies were observed in the field or on the topographic map within 500-feet of the
source area.
Refer to Table: Table 1
• Predictive Rate of Contaminant Transport:
The contaminant plume has been fairly immobile over the past several years.
Contaminant transport is typically in the same direction as groundwater flow, but with a
slower velocity.
Refer to the following Table(s) and Figure(s):
Refer to Table(s):
Refer to Figure(s):
1.2.6 Other Field Data Collected:
Tables 2, 3 & 4
Figures 4 through 11
• Field measurement log is included in Appendix B.
Texaco Food Mart #2
Lexington Davidson County, North Carolina
Incident#: 22332
2.0 CONCLUSIONS
Monitoring Report
April 14, 2009
Page4
• Free product was not detected in site wells during this reporting period. The water table
depth has risen by as much as nearly 5 feet.
• A month long MMPE event was conducted on monitoring wells including MW-2, MW-3
and T-1 prior to the sampling event. A total of 8,695 gallons of petroleum impacted
groundwater and 32.48 gallons of VOCs as gasoline were extracted and
removed/disposed.
• Dissolved phase petroleum constituent compounds were detected in concentrations above
21 Standards in monitoring wells including MW-I, MW-2, MW-3 and T-1 during this
period. Extractable and volatile petroleum hydrocarbons were detected in concentrations
above the 21 Standards in monitoring well MW-I, MW-2, MW-3 and MW-5.
• Dissolved phase concentration of benzene in MW-2 was above the NCDENR Gross
Contaminant Levels (GCLs).
• Dissolved phase petroleum constituent compound concentrations generally decreased in
monitoring wells MW-1, MW-2, MW-3 and T-1 after the MMPE event in January 2009,
but not significantly enough to remediate the site below the 21 Standards or the GCLs.
• Three (3) privately owned drinking water supply wells were identified within a 1,000-
foot radius of the source area with one confirmed drinking water supply well within 450
feet of the source area. When last contacted, two of these drinking water supply well
owners were not interested in connecting to the municipal water supply.
3.0 RECOMMENDATIONS
• It is recommended that the Corrective Action Plan including the air sparing/soil vapor
extraction remediation system be implemented at the site to clean up soil and
groundwater contamination, with NCDENR and Trust Fund approval.
• A Jot of the subsurface portion of the remediation system has already been installed. It is
requested by Techno, LLC for Holding Brothers, Inc. to move an air sparging/soil vapor
extraction system from their recently cleaned up Crossroads Grocery site to this site, with
NCDENR and Trust Fund approval.
Texaco Food Mart #2
Lexington Davidson County, North Carolina
Incident#: 22332
4.0 LIMITATIONS
Monitoring Report
April 14, 2009
Page 5
Shield has performed environmental services at the subject site on behalf ofTechno LLC for Holding
Brothers, Inc. Shield has performed this scope of work as an independent contractor/consultant using
reasonable care and skill in accordance and consistent with customary industry standards of
engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive
standard of care that can be applied to measure Shield's performance of the work. No other
warranty, expressed or implied is made or intended by Shield.
The report has been prepared for the exclusive use by Techno LLC for Holding Brothers, Inc. All
recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's
knowledge, opinion and belief, based upon information obtained during this scope ofTechno LLC
for Holding Brothers, Inc. and Shield. Conclusions are provided with the understanding that Shield
is presenting information and not rendering legal advice. If such advice is needed, legal counsel
should be consulted. It is the responsibility ofTechno LLC for Holding Brothers, Inc. under advice
of its counsel to notify the appropriate federal, state, or local public agencies as required by law; or
otherwise to disclose in a timely marmer, any information that may be necessary to prevent damage
to human health, safety, or the environment.
Compliance with recommendations provided as part of this report in no way assures compliance with
federal, state and/or local laws, regulations, and/or requirements. Analytical data has been obtained
from Pace Analytical Services Inc. This information, to the extent that it was relied on to generate
this report, is assumed to be correct and complete. The work performed in conjunction with this
report and the data developed are intended as a description of available information at the dates and
specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or
recommendations with respect to any conditions that were knowingly or unknowingly withheld,
concealed, hidden, or in any way not disclosed or observable at the time of this scope of work.
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CEDAR LANE ROAD
DISPENSER□
DISPENSER□
TW-1 ~ (NS)
~
MW-1
(NS)
2 ~
I GASOLINE UST
11 GASOLINE UST
81 GASOLINE UST
0 TEMP-1
(NS)
□DISPENSER
□DISPENSER
I
I
I
I DIE5£LUST
r,..,,.RETEPAD
.
:
. :
l>JAOCO
RUSHCO l/3 .
. ·. . ..
.
'
.:
0 MW·2
{NS)
ETHYLBENZENE
ISOCONCENTRA TION MAP
TEXACO FOOD MART #2
lrl
~-
1-APPROXIMATE GRAPHIC SCALE NOTES: 1· GROUNDWATER SAMPLES COLLECTED ON 03/04/09.
1700 COTTON GROVE ROAD
LEXINGTON., _NORTH CAROLINA SHIEw 11 ,oo,zs9
2· ALLLOCATIONSAREAPPRO><IMATE. •0 15 ,o DATE: 04/07 /09 DRAWN BY : a 3. CONTOUR INTERVALS AS SHOWN, RBS
fl; SCALE, 11,. • 30ft. SCALE ; AS SHOWN FIGURE; ;;L _______________________________________________________________ ..._ ________ _._ ________ _. 7
ill
8 I
I
LEGEND:
i), LIGHT POLE
Jd POWER POLE
ELECTRICAL LINE
----SANITARY SEWER LINE
----PRODUCT LINE
w
w
w w
~
w
~
TEXACO FOOD MART MONITORING WELL
TEXACO FOOD MART DEEP MONITORING WEL1
AMOCO RUSHCO #3 MONITORING WELL
"'"
ASPHALT
AU. DATA TAKEN FROM THE PHASE ti LIMITEO Sil! ASSESSMENT REPORT PREPARED BY CBM EKVIROMENTAL SERVICES, JNC, DATED ◄/16101.
VAPOR ElCT'RACTION WELL
AIR SPARGING WELL
MICROGRAMS PER LITE!
TOTAL XYLENES CONCENTRATION (u11/LJ
VACANT LOT
~
u
I REGULAR ""
PITI "Bl\'-"'
I SUPREME UST
'"Ill"'
MW-4~
(11.6)
OVERHEAD ELECT~!~
ACCESS ROAD
WENDY'S PROPE!m'
MW-6 ~
(NS)
PARKING AREA
i
~ ii! "' z I
~
'" 5 ii!
u z
□ DISPENSER DISPENSER □
□DISPENSER DISPENSER□
TW-1 r;>J (NS)
r;>J r;>J TEMP-2
(NS) MW-1
(NS)
CEDAR LANE ROAD
1
~
I GASOLINE UST
11 GASOLINE UST
~1 GASOLINE UST
-' TEMP-1
(NS)
□DISPENSER
□DISPENSER
DIESEL UST
"'
. " ' '
~ :
..
AMOCO
RUSHCO#J :
:
,,-._,-:,•i ·. <·
-' MW·2
(NS)
• S'HI"ELD 4301TAGGARTCREEKROAD
CHARLOTTE, NC 28208
7D4-394-e913 7D4-394-M8 lu ENGINEERING, INC. --thltld,<1gl~a:ni
l!l VE
BAS
(u1/L)
(1◄,500)
(ND]
;;; TOT AL XYLENES
ill ISOCONCENTRATION MAP TOTALXYLENES CONCENTRATION NOT USED IN CONTOURING (u&IL)
.----TOTAL XYLENES ISOCONCENTR.ATION LINE (ug/LJ
8 (ND) NOTDITTcrED-BELOWLABDRATORYMETHODDETECTIONLJMO, TEXACO FOOD MART #2 6 INS) NOT SAMPLED 1700 COTTON GROVE ROAD
8 LEXINGTON, NORTH CAROLINA ~ APPROXIMATE GRAPHIC SCALE SHIELD II ,oo,2a9
~~
P. 0 1' ,o DATE ·. 04/07/09 ... NDm: 1-GROUNDWATERSAMPL£SCOLlECTEOON03/04/D9, J f I
2· Ali LOCATIONS ARE APPROXIMATE. 1 ■ '.
3-CONTOURINTERVAL5ASSHOWN. SCALE,1io.•3Dft. SCALE; AS SHOWN ;:L_ _________________________________ .___ _________ _
DRAWN BY: RBS
FIGURE: 8
~ !
I
i!i 8
I
i!i
8
LEGEND:
¢, LIGHTPOI..E
flf POWER POLE
ELECTRICAL LINE
SANITARY SEWER LINE
----PR0DUOUNE
TEXACO FOOD MART MONITORING WEU.
TEXACO FOOD MART DEEP MONITORING WELL
AMOCO RUSHCO #3 MONITORING WEU.
ASPHALT
ALL DATA TAKEN FROM THE PHASE ll LIMllED SITE ASSESSMENT REPORT PREPARED BY CBM ENVIROMENTAL SERVICES, INC. DAT!O 4/16/D1.
I!] VE
BAS
(us/LJ .,.,
(3,600)
VAPOR EXTRACTION WELL
AIR SPARGING WELL
MICROGRAMS PER LITER
METHYL TERT·BIJTYL ETHER
MTBE CONCENTRATION (us/L)
[ND] MTBE CONCENTRATION NOT USED IN COtITOURING (us/L)
---MTBE ISOCONCENTRATION LINE (ug/L)
MW-4~
(4.J)
(ND) NOT DETECTED· BELOW LABORATORY METHOD DETECTION LIMITS
{NS) NOT SAMPIB>
"
'2
GASOLINE/
DISPENSER~
I REGULAR
UST
PIT! REGuJl,LAR
I SUPREME UST
SU&~
VACAIITIDT
u
MW-6 ~
(NS)
MW•J~ (ND)
ASPHALT
AS·S AS-6
"'e© IE B
VE-6 T-4 VE·7 (NS)
OVERf1EAD ELECTRIC
ACCESS ROAD
WENDY'S PROPERTY
~MW·S (NDJ--------j
PARKING AREA
□ DISPENSER
□DISPENSER
i
~ 51 " z I
Ill
lg 0 TEMP-2
(NS) 51 u z
CEDAR LANE ROAD
DISPENSER□
DISPENSER□
1W-1 0 (NS)
0
MW-1
(NS)
1 ~
I GASOLINE UST
11 GASOLINE UST
§I GASOLINE UST
~ TEMP-1
(NS)
□DISPENSER
□DISPENSER
1-APPROXIMATE GRAPHIC SCALE
DIESEL UST
p
.. .
,'
AMOCO .'. RUSHCO#3
I· . :
~ MW·2
(NS)
• SUIE.'LD 4301TAGGAATCREEKR0AO
CHARLOTTE, NC 2&208 ...,,...,, ---. ENGINEERING, INC. www.,~~----
MTBE ISOCONCENTRATION MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTO~ ~ORTH CAROLINA SH/cw# 1001289 ;lrl-
Nora, ,. GROUNDWAT<RSAMPLESCOLLErnoONOl/04109. P '? ,
1
o DATE : 04/07 /09 DRAWN BY : RBS a Z· At1 LOCATIONS ARE APPROXIMAlE. 1 ■ ~
~ J.CONTOURINTERVAlSASSHOWN. SCALE,110.•JOtt. SCALE: AS SHOWN FIGURE: 9 :.L _________________________________________________________ ..i..;_,..=__,.;.;.;.~--------------------""""'
~ ~ I
~
N
LEGEND:
-1:) LIGHT POLE
id POWER POI.£
----ELECTRICAL UNE
----SANrT.ARY SEWcR LINE
~
~
~
~
~
w
w
----PRODUCT LINE 8 @ TEXACO FOOD MART MONITORING WEU.
m•
ASPHALT
i @ TEXACO FOOD MART DEEP MONITORING WEU.
C, ~ i~i\lfjJ,~iiill~sJWcts;5~ i DATED 4/16/01,
"'
,;;z~ 1!J VE VAPOR EKTRACTION WEll.
..., B AS AIR 5PARG1NG WEU.
(ug/L) MICROGRAMS PER UTER
~ (ND) 1,2-DICHLOROETHANE {DCA) CONCENTRATION (ug/L)
MW-4~
(ND)
8 [25.7] 1,2-DICHLOROETHANE (OCA) CONCENTRATION NOT IJSEO IN CONTOURING (1111/L)
,... (ND) NOT DETECT• BELOW LABORATORY METHOD DETECTION LIMITS ~ (NS) NOT SAMl'LED
2
DISPENSER GASOLINE~
MW-6 18
(NS)
VACAITT L.0T
RE<MAR UST MW-3@ -(ND)
"Iii\'-"'
ASPHALT
SUPREME AS-5 AS-6 UST IE "@ l!l " VE-6 T-4 VE-7 • '"&W" (NS)
·, '.._',.,,~,:::
T-3 MW·Z =~ TEXACO FOOD MART JNS)Q_ rffe (ND)
~-1 VEaS@T-1
[25.7]
" AS-1
E!IVE-3
,•,.'·<,'· S VER LINE
'
KEROSENE UST a
VATER METEJ
□VERHEAD ELECTRIC
ACCESS ROAD
WENDY'S PROPElm'
~MW-5
(NDl--------j
PARKING AREA
□ DISPENSER
ODtSPENSER
Q, TEMP-2
(NS)
CEDAR LANE ROAD
DISPENSER□
DISPENSER□
0
MW-1 (NS)
2 □DISPENSER
~ □ DISPEtiSER
I GASOLINE UST
!, I ~ • GASOLINE UST
~ :=I=~ • GASOLINE UST
~ TEMP-1
(NS)
DIESEL UST
. '
AMOCO RUSHCO#l
~ MW-2
(NS)
'
::
:·
:_
1,2-DICHLOROETHANE (DCA)
CONCENTRATION MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTOJi. ~ORTli CAROLINA SH/t.w 111001289
!!,
-5l~ APPROXIMATE GRAPHIC SCALE
• NOTES, 1· GROUNDWATERSAMPLESCOLLECTEOON03/04i... ? '? '1' DATE : 04/07 /09 DRAWN BY : RBS 2-AU. LOCATIONS ARE APPROXIMATE. 1 ■ ~
SCALE,110.•JOft. SCALE: AS SHOWN FIGURE: 10 ;;L.., ____________________________________________________________________________________________ ..
~ ~
I
~ 8 ~
! ffi
~
8
N
LEGEND:
-(:!-LIGHT POLE
flf POWER POLE
ELECTRICAL LINE
SANrTARY SEWER LINE
----PRODUCT LINE
w
w
w
w
w
w
w
~ TEtACO FOOD MART MONITORING WELL
@ TEXACO FOOD MART DEEP MONITORING WELL
AMOCO RUSH CO #3 MONITORING WEU.
'"
ASPHAI.T
0 *~8ttilt~EDFR~ch%El~~~~~r.,oo DATED4/16/01,
1!1 V£ VAPOR EXTRACTION WEU.
B AS AIR SPARGING WEU.
(u11/L) MICROGRAMS PER LIT!R
(1,520) NAPHTHALENE CONCENTRATION (ua/L)
MW-4~
(12.3)
[J.1] NAPHTHALENE CONCENlRATION NOT USED IN CONTOURING (USIL)
---NAPHTHALENE ISOCONCENTRATION LINE (u1/L)
{ND) NDT DETECTED -BELOW LABORATORY METI-100 DrncnON UMIT5
(NS) NOT SAMPLED
WENDY'S PRDl'ERTY
VACANT LOT
MW-6 ~
(NS)
DVE~I-IEAD ELECTRIC
ACCESS ROAD
~MW-5
(2,9)----------1
PARKING AREA
DfSPENSSI.□
□DISPENSER DISPENSER□
~ "' !;! a! " z
i TW-1 "' (NS)
I
5 " TEMP-2 "' (NS) MW-1
a! (NS)
u z
CEDAR LANE ROAD
I GASOLINE UST
~I GASOLINE UST
~I GASOLINE U!;J'
" TEMP-1 (NS)
□DISPENSER
□DISPENSER
DIESEL UST
CONC
AMOCO
RUSHC0#3
"MW-2
(NS)
• SHIELD ~f:J;Eii~~ROAO
ENG/NEERING, INC. www.ahlli<llr,al~.com
NAPHTHALENE
ISOCONCENTRATION MAP
TEXACO FOOD MART #2
1700 COTTON GROVE ROAD
LEXINGTOI!, ~ORTH CAROLINA
SH/ew 111001289 I APPROXIMATE GRAPHIC SCALE
-Norn, ,. GRou,owATERSAMPillCDLLECTEDDNDl/04109. 0 15 JO DATE: 04/07 /09 DRAWN BY : RBS i3 2-ALL LOCATIONS ARE APPROXIMA'TE. ~ 3-CDKTOURINTERVALS., SHOWN SCALE, ""· • JO ft. SCALE : AS SHOWN Fl GU RE : 11 "'L---------------------------------&..;.;;;.;~...;.;.:;.:;.;.;.;;.;.;.;.;......a...;..;.;;.;;.;.;;;..;.._.;.;.....___.
Table: 1
Summary of Adjacent Property and Water Supply Well Owners -Receptor Survey updated after 2003
WSW-I I Flowerest 0. Lopp
WSW-2 I Paul & Stella Baker
WSW-3 I Margaret H. Fuller
WSW-4 I Hoyle R. Smith
Efrrd E. Jr. & Kay S.
WSW-5 I Wilson
(owner)
WSW-6 I Abe Cassidy
WSW-7 I Mrs. Samuel C. Davis
WSW-8 I Maxine C. Houck
WSW-9 I Thomas Frank
WSW-IO I James G. Henderson
WSW-I I I Ray S. & Irene Musgrave
WSW-12 I Aubrey & Helen Brewer
WSW-13 Jobn T. Tetter
Notes: Ft BGS = feet below ground surface
Texaco Food Mart #2
1700 Cotton Grove Road,
Lexington, North Carolina
NCDENR Incident# 22332
I P.O. Box 284 Lexington, NC I 336-357-
2511 I Drinking I
I 104 Fuller Rd., Lexington, NC I 336-357-
5231 Not in Use
J 106 Fuller Rd., Lexington, NC I 336-357-
2659 Not in Use
--
115 Cedar Ln., Lexington, NC 336-357-I Drinking I 2916
336-249-6 Mayfair Rd., Lexington, NC* I Not in Use I 3266
Box 8 Mayfair Rd., Lexington, 336-357-I Not in Use I NC 2485
I Box 100 Mayfair Rd., 336-357-I Not in Use I Lexington, NC 2565
185 I
?
?
? I
? I
? I
? I
I Box I 08 Mayfair Rd.,
Lexingtou, NC INA I Drinking I >100 I
I Box I 07 Mayfair Rd,
Lexington, NC INA I NotinUse I ? I
I Box 103 Mayfair Rd.,
Lexington, NC INA I Not in Use I ? I
I 1724 Southview Rd.,
Lexington, NC INA I Not in Use I ? I
I 102 Mayfair Rd., Lexington,
NC INA I Irrigation I ? I
I 04 Mayfair Rd., Lexington, NA Drinking ? NC
Address of well. Property owner's address is 500 Maegeo Dr., Lexington
4" I ? I ?
? ? ?
? ? ?
? I ? I ?
? I ? I ?
? I ? I ?
? I ? I ?
4" I ? I ?
? I ? I ?
? I ? I ?
? I ? I ?
? I ? I ?
? ? ?
Of the property owners without PWS hook ups, only John Tetter is interested in be added to the PWS. Other property owners indicated that they are not interested at all.
NA-Not Accessible
I 450'
700'
650'
I 985'
I 750'
I 760'
I 795'
I 1025'
I 1090'
I 1100'
I 1175'
I 800'
850'
I No
Yes
Yes
I No
I Yes
I Yes
I Yes
I No
I Yes
I Unk.
I Unk.
I Yes
No
H:\Projects\2000\1001289\Reports\AruvfR 4_09\Water Supply Well Information Table.doc
--. ----------
Top of
Well ID Date Casing
Installed Elevation
(feet)
!VI VV·l 07/31/01 JOO.OU
!VJVV•:.l 07/31,ul 100.l'J
!VJVV-j 10/08/01 IOU.19
i>H•-4 10/08/UI 99.40
mn-~ 0410 .. ,02 100.J~
JVJn•b 04/04/02 101.42
T-1 10/09/01 100.3)
" Notes.
I. NM = Not Measured.
2. NA = Not Applicable.
Table 2:
Summary of Well Construction and Historical Groundwater Elevation Data
Texaco Food Mart #2
Well
Diameter
(inches)
2
2
2
2
2
2
2
1700 Cotton Grove Road, Lexington, North Carolina
NCDENR Incident# 22332
Field Measurements
As-built Total Depth to
Depth Screened Gauging Date Depth Static
(feet) Interval (feet) (feet) Water
(feet)
J5 20-JJ .1.Vl..1.U/U.I. 3).00 24.09
...., .. 2102 35.00 22.13
11/19/07 35.01 23.69 .. J4.~J l'::f.UO
3) 20-3) 3).00 24.2L
04/22/02 35.00 22.08
11/19/07 34.75 23.84
J4.UJ l'l.o_.
35 20-35 35.00 24.27
04/22/02 35.00 21.93
11/19/07 35.03 24.10
J4.~0 J').j)
35 20-35 3).00 24.11
04/22/02 35.00 21.91
11/19/07 34.81 23.88
04.{4 ,,.,
3) LU-35 3).00 23.34
11/19/07 35.07 24.76
JJ.U~ LI.I I
LJ 15-25 LJ.00 23.02
11/19/07 25.00 NM
mn mv1
'10 85.5-90 '"" 90.UO 24.9J
04/22/02 90.00 22.06
11/19/07 86.71 21.59
UJ.0.0 11:J.J.t,
Sum of well construction and historical groundwater elevation
Field Calculations
Depth to DilT. Between Ground-water Free As-Built and Elevation Product Measured Total (feet) (feet) Depth (feet)
NA 0 75.91
NA 0 77.87
NA -0.01 76.31
l~A U.u, ~U.jL
NA 0 7).78
NA 0 77.92
NA 0.25 76.35
"" U.JJ OU.J f
NA 0 75.92
NA 0 78.26
NA -0.03 76.09
"" U.U4 OU.O't
NA u 7fJ.08
NA 0 78.28
NA 0.19 75.52
"" V.LU 17.JV
NA 0 76.85
NA -0.07 75.63
NA -U.u~ I / • .l,£.
NA 0 77.17
NA 0 NM
NM NM NM
NA 0 7).2fJ
NA 0 78.13
NA 3.29 78.76
"" .04.l~ OU.OJ
Pnr,p Inf I
"' .. .. " =-.. .. .. s " " N .. .. " Well ID " N -§ ..
"' " ~ .. .!l ~ ~ ,s " Q J;'1
(ug/L) (ug/L) (ug/L)
15A NCAC 2L.0202
Standard···-> 1 1,000 550
15A NCAC 2L.0115
Gross Contamination •-_, ___ ... 5,000 257,500 84,500
MW-I 03/04/09 53.7 28.4 165
MW-2 03/04/09 11,700 27,200 2,250
MW-3 03/04/09 ND 3,430 2,090
MW-4 03/04/09 ND 5.2 ND
MW-5 03/04/09 ND 1.9 ND
T-1 03/04/09 20.7 ND ND
NOTES:
1. ug/1 = Micrograms per liter
2. Bold numbers exceed the NCAC 2L .0202 limit
Table: 3
Summary of Analytical Results • Groundwater Samples
Texaco Food Mart #2
1700 Cotton Grove Road
Lexington, North Carolina
NCDENR Incident#:22332
EPA Method 601/602
.. $ .. Q ,s .. .. [;:'. " .. .. ~ :; ,s " .. .. .. -= "' " " .. -.. .. ·e -; ~ = ~ 0 ,.Q .. 0 .:. 0 .. i 0
3 .. .. l ,.Q .. Q. :a Q. "I 0 " 0 ;:, i:i .. z ~ " ,s i5 "!. ..
i ... ;:, ,s
J;'1
(ug/L) (ug/L) (ug/L) (ug/L) (ug/L) (ug/L)
530 200 70 0.38 0.004 21
87,500 200,000 70,000 380 50 15,500
827 ND ND ND ND 167
14,500 3,600 ND ND ND ND
11,400 ND ND ND ND 1,520
11.6 4.3 ND ND ND 12.3
ND ND ND ND ND 2.9
ND ND ND 25.7 ND 3.1
,.Q " II II
00 .. ... ... u u a.. a.. 0 0 u ~ -~ ~ <; .= " " -= '3. .9' < = <
(ug/L) (ug/L)
(a-c) + b
4200
... . ..
6,170
58,930
40,926
186
ND
ND
3. ND= Not detected at or above the method detection limit specified in the laboratory report.
4. NR = Not requested ..
MADEP EPH-VPH EPA Method
625
<; "' ~ 00 II II '"' ~ ~ "' 0 u u 0 ~ ... .. a.. ~ u u " ... a.. ..:. ..
~ u "il 0 ... -~ u i ~ ~ i -~ -~ tl Q.
" <; " -= -= i .= z " Q. .9' s s :;;j < 0 0 .. .. < <
(ug/L) (ug/L) (ug/L) (ug/L) (ug/L)
c+d
42,000 420 210 21
... ··-. .. ··-15,500
ND 468 2,200 62.7
ND 59,300 8,340 238
ND 5560 11780 595
ND ND ND ND
ND ND ND ND
ND 320 ND 14.4
5. Italicized BOLD numbers exceed Gross Contaminant Levels as presented in the NCDENR "Guidelines for Assessment and Corrective Action" dated July 15, 2008 effective December 2008.
H:\Projectsl2000l 10012891Reports\ARMR 4_09\Groundwater Analytical Results-11_ 2007.xls
Analytical Method--··>
• 1 2 ! ..
ISA NCAC lL,0202 I 1,000 Standard---·>
ISA NCAC lL.0115
Gross Contamination 5,000 257,S00
level--.>
Location Date """ """
MW-I 07131/01 ND 53
04130/03 12 340
11/19/07 495 64,7
03104/09 53.7 28.4
MW-2 07131/01 JJ,000 38,000
04/30/03 12,000 29,000
11119/07 14,900 34,200
03104/09 11,700 27,200
MW-3 10/10/01 120 4,300
04/30/03 100 3,000
11119/07 ND 4,850
03104/09 ND 3,430
MW-4 10/10/01 ND ND
04/30/03 ND ND
11/19/07 ND ND
03/04/09 ND 5.2
MW-5 04130/03 ND ND
11/19/07 ND ND
03/04/09 ND 1.9
T,1 10/10/01 390 7.8
04130/03 l7 2.8
11119/07 433 ND
03/04/09 20.7 ND
Notes:
Table 4:
Summary or ffistorical Analytical Results-Groundwater Samples
Texaco Food Mart #2
1700 Cotton Grove Road, Lexington, North Carolina
NCDENR Incident# 22332
EPA EPA
EPA Method 601/602 Method Method MADEP
625or VPH . 504.1 601/602
I: ( 8 "' ~ • I!! ~ C ~ • .. f f 1 • a ! I ~ • ~
"' t ~ I ,s i 1 ~ ~ i ~ " e • I I z " .. " ::! ~ ~ "'
550 530 200 70 0.38 0.0004 21 420
84,SOO 87,500 200,000 70,000 380 50 15,SOO -·
""" " "'" "'" " "'"
340 1,300 NR NR ND 0.96 75 ND
13 1,470 NR ND ND NR 270 NR
179 1,210 ND ND ND ND 107 ND
165 827 ND ND ND ND 167 468
3,600 16,000 NR NR 1,200 720 NR 81,000
2800 16,700 NR ND 1,700 ND 1,400 NR
3,090 18,400 6,090 ND 1,150 ND 1090 60,IOO
2,250 14,500 3,600 ND ND ND 238 59,.l00
1,800 8,600 NR NR ND 9.5 360 ND
1,600 8,800 NR ND ND ND 660 NR
2,190 13,600 ND ND ND 1,2 513 NR
2,090 11,400 ND ND ND ND 1,520 5,560
ND ND NR ND ND ND ND NR
ND ND NR ND ND NR ND NR
ND ND 2.3 ND ND ND ND ND
ND 11.6 4.3 ND ND ND ]2.3 ND
ND ND NR NR ND NA ND NR
ND ND ND ND ND ND 41 144
ND ND ND ND ND ND 2.9 ND
9.4 140 NR NR 44 2.8 24 850
ND 14.7 NR ND 8.1 ND 3.1 NR
ND ND 210 ND 1.7 ND ND ND
'ND ND ND ND 25.7 ND 14.4 320
ug/1 = Micrograms per liter. ND= Below Method Detection Limit
NR = Analysis not requested. Bold numbers exceed 15A NCAC 2L.0202 standards.
MADEPVPH&
EPH
• ~
" " " .. 2: 2: ~ ~
~ ·i ~ ~ ~ " = "'
(a-c)+bm
4200
---
3,470
NR
665
6,170
28,000
NR
71,600
58,930
11,990
NR
3460
40,926
NR
NR
ND
186
NR
ND
ND
270
NR
ND
ND
15A. NCAC 2L.0202 = NCDENR Standard Statute for non-risked based maximum allowable containment concentration in groundwater
MADEP MADEPVPH&
EPH EPH
• ~ '-" " '? 8 " u 3 ~ !\ § :, :, • = • • • 'O ~ • ·o
~ ~ • ~ ~ ~
42,000 c+d=
210
------
ND 2,780
NR NR
ND 825
ND 2,200
NR 9,100
NR NR
308 26,630
ND 8,'411
ND 11,710
NR NR
ND 2,440
ND 11,780
NR NR
NR NR
ND ND
ND ND
NR NR
ND ND
ND ND
ND 250
NR NR
ND ND
ND ND
Italicized Bold numbers exceed Gross Contaminant Levels"' As presented in NCDENR "Guidelines for Assessment and Corrective Action," dated July 15, 2008, effective
H:1Projecls1200/Jl1(X}Jl891Repcr/s\ARMR 4_09IS/Jm of HISTORICAL GW Mlllyflcsl.x/s Paga 1 ol 1
• ADVANCED
ENVIRONMENTAL SERVICES, INC.
"Your Environmental Solutions Partner"
MOBILE
MULTI-PHASE
EXTRACTION REPORT
Site Location:
Texaco Food Mart #2
1700 Cotton Grove Road
Lexington, NC
Prepared for:
Shield Engineering
4301 Taggart Creek Road
Charlotte, NC 28208
Attn. Colleen Clark
February 23, 2008
TABLE OF CONTENTS
EVENT SUMMARY
MMPE FIELD LOGS 1 and 2
MASS-REMOVAL CALCULATION
FIELD NOTES
DISPOSAL MANIFESTS
MOBILE MULTI-PHASE EXTRACTION
EVENT SUMMARY
February 24, 2009
Location: Texaco Food Mart #2
1700 Cotton Grove Road
Lexington, NC
Client: Shield Engineering
430 I Taggart Creek Road
Charlotte, NC 28208
Event Dates: January 5 -30, 2009
Advanced Job # o 1-090 I
Advanced Personnel: Lee Heilig, Jason Johnson and Brandon Boyleston
MMPE System: MMPE system rated 20"hg at 130 CFM
4' discharge stack -2" diameter
8,000 -gallon tanker
275' piping 2" hose to 3 wells
Extraction Well: MW-2, MW-3 and T-1
Well Initial FP / WL(ft) Final FP / WL(ft) Stinger depth(ft)
/ Changed To
MW-2 20.34 32.79 22/24/26/32/34
MW-3 20.02 19.99 24/26/28
T-I 20.54 22.35 24
Description of Event:
Run Time
383.0 hours
20.0 hours
5.0 hours
The MMPE event ran Monday through Friday for a period of four weeks January 5 through January 30,
2009. The MMPE system was active for 384.0 hours. During the event monitoring well MW-2 was
online for a period of 383 hours, MW-3 was online intermittently for 20 hours and T-1 was online for a
period of 5 hours. Vacuum at the recovery pump ranged from 19.0 to 22.0 inches of mercury (hg). While
connected to MW-2 vacuum stabilized at approximately 20.0 inches of mercury. Airflow rates ranged
from 1,300 to 1,800 feet per minute. While connected to MW-2 running at 100% flow, airflow rates
stabilized at approximately 1,600 feet per minute. System temperature ranged from 65.0 -138.0 degrees
F and humidity maintained 99 percent. Field gauged volatile organic compound (VOC's) emissions
decreased from 18,000 to 7,500 parts per-million (PPM) throughout the event.
Groundwater / Product Mix Recovered:
During the event a total of 8,695 gallons of product/water mix were removed from the site in two loads
and properly disposed at a certified North Carolina disposal facility. No free product was identified in the
recovered fluids. Total fluids recovered, was measured based on stick readings conducted during and
following the event Based on 384 hours of operation and a total of 8,695 gallons recovered, the average
groundwater recovery rate was calculated to be approximately 22.65 gallons per hour.
Events Results:
Based on mass-removal calculations 203.01 pounds or 32.48 gallons of VOC's (as gasoline) were
removed as vapor. Using Dwyer magnehelic gauges, vacuum influence (inches of water) was measured at
monitoring points MW-1, MW-3 and MW-4. No measurable vacuum influence was obsen-ed at any
monitoring point. Maximum draw-down was identified in MW-1, MW-3 and MW-4 at 0.48, 0.09
and 0.09 feet respectively. Following the event, no free product was identified in any well.
MMPE FIELD LOG: 1
CLIENT: Shield Engineering, Inc.
JOB NAME: Texaco Food Mart#2
LOCATION: Lexington, NC
MMPE EVENT DATES: Jan. 5 • Jan. 30, 2009
EXTRACTION POINTS: MW-2 and MW-3
lilll'!l!~ ... iiililiiiil!li1!lili!lilHill
01/05/09 12:00 ;•~~~11111111111 11111:1t1MJ:':;•11111:111111111m•~~n11,
13:00 1,400 I 99.o I 110
16:00 1,30Q I 99.o I 110
01/06/09 10:00 1,300 99.0 102
11:00 1,300 99.0 108
13:00 1,300 99.0 108
01/07/09 10:00 1,500 99.0 124
11:00 1,500 99.0 126
12:00 1,500 99.0 124
01/08/09 11:00 1,500 99.0 128
12:00 1,600 99.0 126
13:00 1,600 99.0 132
01/09/09 10:00 1,500 l 99.0 l 120
11:00 1,500 I 99.0 I 120
Daily Notes:
-MW-3 online alone
JOB NUMBER: 01-0901
18,000
111ilD&lllili1/'8litl~!r•111m:11111111111r1111~1!1!!!llliilfll
20.0 0"
12,000 21.0
9,000 22.0 I 2"
6,000 22.0 8"
5,000 22.0
6,000 22.0
5,500 20.0 13"
5,300 20.0
5,000 20.0
5,200 20.0 17•
5,100 19.0
5,200 19.0
4,400 20.0 20.5"
1aoo-20.0
MMPE FIELD LOG: 1
CLIENT: Shield Engineering, Inc.
JOB NAME: Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: Jan. 5 -Jan. 30, 2009
EXTRACTION POINTS: MW-2 and MW-3
"l!!'~~~~:ll!l!;,jli1::1m~~~l!i,ilill1111111~mw:1~:ie1: .,........ ss:o••····•····•u+···•···•·•·••.•.•····es···"' ., ...... : .. 11!:!i!!i!fftllfflllll~Ili!!!l!!!!IDEHll!ll~EUll\":l!':1!
12:00 I 1,soo 99.o I 102
13:oo I 1,400 99.o I 114
01/13/09 10:30 1,500 99.0 130
11:30 1,700 99.0 124
12:30 1,500 99.0 118
01/14/09 10:30 1,500 99.0 124
11:30 1,600 99.0 108
12:30 1,500 99.0 116
01/15/09 10:30 1,500 99.0 128
11:30 1,500 99.0 120
12:30 1,500 99.0 122
01/16/09 6:30 1,500 l 99.0 l 104
9:30 1,500 I 99.0 I 106
Daily Notes:
*MW-3 online
** Dropped stingers in MW-2 to 33', VOC's increased
JOB NUMBER: 01-0901
6,800
5,600
6,800
6,800
5,000*
8,800-
9,000
6,000
9,000
10,000
10,000
10,000
10,000
10,000
IWIBIEMlil*~IJf
21.0
20.0
21.0
20.0
19.0
20.0
20.0
19.0
20.0
20.0
20.0
20.0
20.0
20.0
pump off
;!iiltll!Sllil:!ll~ISll:tiiiJ;1!11r:1n·
20.5"
29.0"
27.0"
30.0"
20.5"
4,292 gallons
No Free product
MMPE FIELD LOG: 1
CLIENT: Shield Engineering, Inc.
JOB NAME: Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: Jan. 5 -Jan. 30, 2009
EXTRACTION POINTS: MW-2 and MW-3
llF~~,~~::111:111:m l~~~~lllilUll,liilii~mw'i~Jl:ilillU .. '""'''''''99·:ohk .. •·u.,,,.,., ...... , .. , .. ,. ]8 .. c..,ub,.,.,,, r:i'!!iilim:JMIIIE$:i' ::n111,:r--•1BEJ!iili'i!I
12:30 I 1,600 99.0 I 98
13:30 I 1,soo 99.0 I 110
01/20/09 9:30 1,600 99.0 115
10:30 1,600 99.0 120
01/21/09 10:30 1,600 99.0 128
11:30 1,600 99.0 114
12:30 1,600 99.0 120
01/22/09 10:30 1,600 99.0 131
11:30 1,600 99.0 128
01/23/09 9:30 1,600 99.0 90
16:30 1,600 99.0 130
Daily Notes:
*MW-3 online
JOB NUMBER: 01-0901
6,600
8,000
10,000
7,800
8,000
9,000
6,800*
9,200
8,000
8,200
7,800
6,800
llli',$BIIMIIV'Bl
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
''''!l"""l!:'$1"!1!!:ltiii(*1 \is:;', __ :~•"',,,.,,, \. .. ,:~:,,,,_.~;dl~:
O"
a·
13"
18"
21.5"
MMPE FIELD LOG: 1
CLIENT: Shield Engineering, Inc.
JOB NAME: Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: Jan. 5 -Jan. 30, 2009
EXTRACTION POINTS: MW-2 and MW-3
i11111111a11111ii111mf 111111111:1r•1i1i11111111111~a111uj1
01/26/09 9:30 1,600 l1illlillffl•J~11!1!1111,illil~~~lli
14:30 I 1,600 99.o I 130
01/27/09 14:30 1,600 I 99.0 I 132
15:30 1,600 J 99.0 J 130
01/28/09 12:30 1,800 99.0 138
13:30 1,600 99.0 115
14:30 1,600 99.0 115
01/29/09 9:00 1,700 99.0 128
17:00 1,700 99.0 126
01/30/09 8:30 1,600 99.0 120
9:30 1,600 _ 99.0 120
Daily Notes:
*MW-3 online
JOB NUMBER: 01-0901
7,800 'ilillDIIM'l~~~l!l!llMOl!lilHl,IIIi!lillll~~l:~,~Wi•IUl'
6,800 20.0 22.5"
9,000 20.0 25.0
8,800 20.0
8,000 19.0 28.0
6,600* 20.0
8,900 20.0
8,000 19.0 31.0
8,000 19.0
7,400 20.0 34.0
7,500 20.0
First load 4,292 gallons
Second load 4,367 gallon
Total fluids 81695 gallons
no free product
MMPE FIELD LOG: 2
CLIENT: Shield Engineering, Inc.
JOB NAME:Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: January 5 -January 30, 2009
"'ii'i-&miili
initial wl's 11:00
01/05/09 12:00
16:00
01106/09 I 1 o:oo
11 :00
13:00
01101109 I 10:00
11:00
12:00
01108100 I 11 :oo
12:00
13:00
01100100 I 1 o:oo
11:00
final wl's
Daily Notes:
!: 1::1'irn!iU-llillN1-:ilil$!!
. MW-2 I MW-3 I T-1
20.34 I 20.02 I 20.54
20.0 I offline I 20.0
21.0 I " I 20.0
21.0 " offline
21.0 " "
21.0 "
19.0 " •
19.0 " "
19.0 "
19.0 " "
18.0 " "
18.0 " "
19.0 • 19.0
19.0 19.0 oflline
29.28 25.07 22.35
JOB NUMBER: 01-0901
f ... lllll'iltlf!Jli!llml$1~iilil81i!IUiiiiii l!i'~UliliB!Jl!l:llil~ii
MW-1 MW-3 MW-4 MW-1 MW-3
20.38 I 20.02 I 20.57
0.00 0.00 0.00
0.00 0.00 0.00 20.54 20.03 20.50
0.00 0.00 0.00 20.60 20.05 20.50
0.00 0.00 0.00 20.65 20.07 20.49
0.00 online 0.00 20.75 online 20.50
MMPE FIELD LOG: 2
CLIENT: Shield Engineering, Inc.
JOB NAME:Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: January 5 -January 30, 2009
'ilii'IIMni'ii 111mma1111 i!illiil'IEill;'flUiCMN:1■••111:111~
. MW-2 l · MW-3 i
initial wl's 20.40 I 18.19
01/12/09 I 11:00 20.0 I offline
12:00 20.0 I 19.o
13:00 20.0 I offline
01/13/09 I 10:30 19.0 offline
11:30 19.0 19.0
12:30 19.0 offline
01114109 I 10:30 19.0 offline
11:30 18.0 18.0
12:30 19.0 offline
01115109 I 10:30 19.0 "
11:30 19.0 "
12:30 19.0
01/16/091 8:30 19.0
9:30 19.0
final wl's 31.02 26.07
Daily Notes:
JOB NUMBER: 01-0901
iM§mu.tiilll:llU!ili!iEi~I■
MW-1 f MW-3 f MW-4
0.00 online 0.00
0.00 online 0.00
0.00 online 0.00
0.00 0.00 0.00
0.00 0.00 0.00
jl~~-r~:::1,;119-4
20.39 I 18.19 I 20.28
20.43 online 20.32
20.53 online 20.30
20.63 19.93 20.29
20.70 19.95 20.28
MMPE FIELD LOG: 2
CLIENT: Shield Engineering, Inc.
JOB NAME:Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: January 5 -January 30, 2009
'1i'!N&ii;!i,liUjlijelii,1iiliiilimiil&lm'IBINft$iiiltill1~
. MW-2 MW-3 I
initial wl's 20.20 I 19.69
01/19/09 11 :30 19.0 I offline
12:30 19.o I 19.o
13:30 19.0 I offline
01120109 I 9:30 19.0 "
10:30 19.0 "
01/21/09 l 10:30 19.0 •
11:30 19.0 19.0
12:30 19.0 offline
01/22/09110:30 19.0 "
11:30 19.0 19.0
12:30 19.0 offline
01/23/097 10:30 19.0 •
11 :30 19.0 •
final wl's I 31.79 19.89
Daily Notes:
JOB NUMBER: 01-0901
"Tw":1· 'i~::r ···r,rn,=;:; ,,,:,,i~MW~1-r Mw~i .. ''Mw-4 .... ,:;,1""Mi!'"'"'"' .... ""'"'E. 1 1'~, .. ,...~11111111il!'lilf 11~•111'11,1',"'""G .. ··IN·' 13:,,.,.,.~.,,1,•
0.00 0.00 0.00 20.22 19.69 20.14
0.00 0.00 0.00 20.40 19.78 20.16
0.00 0.00 0.00 20.61 online 20.20
0.00 0.00 0.00 20.65 online 20.21
0.00 0.00 0.00 20.70 online 20.20
MMPE FIELD LOG: 2
CLIENT: Shield Engineering, Inc.
JOB NAME:Texaco Food Mart #2
LOCATION: Lexington, NC
MMPE EVENT DATES: January 5 • January 30, 2009
JOB NUMBER: 01-0901
"""i'lalliiiiiiM iiiiMe!i, ii iililiiii!D!IU.DRillftll'n~ rim;,; ~IIUUMiJll'iffil'Q-liillil-lillliiiili i'MaiMUIIU'iiEJAt.11' ,
MW-2 MW-3 MW-1 MW-3 MW-4 MW-1 MW-3 MW-4
initial wl's
01/26/09 I 9:15 20.0 offline
20.41 I 19.92 I 20.20
16:30 19.0 " 0.00 0.00 0.00
01/27/09 I 14:30 19.0 " 0.00 0.00 0.00 20.52 na 20.24 15:30 19.0 "
01/28/091 !!1Q. 19.0 offline 0.00 0.00 0.00 20.63 na 20.26 12:30 20.0 20.0
13:30 20.0 offline
01/29/091 9:30 19.0 " 0.00 0.00 0.00 20.73 na 20.26 17:00 19.0
01/30/091 8:00 19.0 0.00 0.00 0.00 20.77 na 20.29 9:00 19.0
32.79 19.99
Daily Notes:
Page 1 of2
MOBILE MUL Tl-PHASE EXTRACTION EVENT
SITE NAME: Texaco Food Mart #2 CLIENT: Shield Engineering
INCIDENT NUMBER:
AVERAGE DEPTH TO GROUNDWATER: 19 -20 feet
DESCRIBE SOIL IN THE SATURATED ZONE:
AVERAGE HYDRAULIC CONDUCTIVITY (if known):
EXTRACTION WELLS USED FOR MMPE: MW-2, MW-3 and T-1
SPECIFICATIONS OF THE MMPE SYSTEM (cfm rm in Hg): 130 cfm@ 20.0"Hg
DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd)
Date Hours Vacuum Velocity Pipe ID Temp Rel Humid Water Water Qstd
(inches of Hg) (ft/min) (in) c·F) (%) Vaoor(Wt%) Vapor (Vol%) (flow)
1/9/2009 96.00 20.00 1450.00 2 116 99.0 0.070 0.101 26
1/16/2009 192.00 20.00 1507.00 2 113 99.0 0.064 0.093 27
1/23/2009 288.00 20.00 1600.00 2 114 99.0 0.066 0.096 29
1/30/2009 384.00 20.00 1636.00 2 122 99.0 0.062 0.090 29
NOTES
Qstd = Flow at DSCFM
Vacuum = The level of vacuum being applied should be recorded from the MMPE system (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge pipina (from the MMPE system}
Temperature = The temnArature of the air stream exiting the blower discharge pipina (dry bulb temp., in deg. 0F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
s_ = water vapor% by weight, i.e., pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity}
Bw. = water vapor% by volume
EQUATIONS
Bws = (Bw,_,/18 lb-mole H20}/((1/28.84 lb-mole dry air)+ (Bws_,118 lb-mole H20}]
Ostd = (1-Water Vapor} • velocity • (Pl • (diameter/24}') • (528°R/(Temp + 460}}
Page2 of2
EMISSION CALCULATIONS
Elapsed
Time Flow PPMmeasu""' PPM... PPMmv K PPMconc Cc:m Cc PMR., PMRg PMR
(hour) (DSCFM) (ppm) (#C -gas) (mg/dsm3> (lb/dscf) Ob/hour) (lb/hour) (lb)
96 26 7054 7054 7845 1 7845 3914 0.00024438 0.38 0.44 42.47
192 27 8333 8333 9187 1 9187 4584 0.00028619 0.47 0.55 52.42
288 29 8127 8127 8986 1 8986 4484 0.00027993 0.49 0.56 54.19
384 29 8020 8020 8817 1 8817 4399 0.00027464 0.49 0.56 53.92
Total emissions in pounds 203.01
Total emissions as gallons (pounds / 6.250) 32.48
NOTES
PPMmeasured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
PPM... = "wet" concentration
PPMdry = "dry" concentration
K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Hexane K = 6)
PPMc= PPM,,, Volumetric concentration of voe emissions as carbon, dry basis at STP
Cc:m = mg/dsm0 • mass concentration ofVOC emissions as carbon
Mc= 12.01 mg/mg-mole, molecular weight of carbon
K3 = 24.07 dsm0/10° mg-mole, mass to volume conversion factor at STP
Cc = lb/dcsf, mass concentration of voe emissions as carbon, dry basis at STP
PMR,, = lb/hr, pollutant mass removal rate of VOC's as carbon
PMR,, = lb/hr, pollutant mass removal rate of of VOC's as gasoline
PMR = lb, pollutant mass removal of VOC's as gasoline
EQUATIONS
PPMwet = PPMmeasured
PPMdry = (PPM..,,)/(1-B.,.)
PPMc = (PPMcJ)(K)
Cc m : (PPMJ(Mc / K3)
Cc = (Cc ml(62.43x1 O'" lb-m0 /mg-ft')
PMR0 = (C0)(Q51cJ)(60 minute/hour)
PMR9 = (PMRc)(M,/Mcg)
PMR = (PMRg)(#hours)
MMPE Field Log:
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--_____________._ .. _, __ --=-:::::...-.-----
1· I· ' '
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
(828)254~7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 20, 2009
Ms. Colleen Clark
Shield Engineering
4301 Taggart Creek Road
Charlotte, NC 28208
RE: Project: TEXACO FOOD MART#2 1001289
Pace Project No.: 9239316
Dear Ms. Clark:
Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2009. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
-f<.,,_,._;_, ;;,('~
Kevin Herring
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc: ..
~ ,M •~co~c
l~\
Page 1 of 35
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Charlotte Certification IDs
West Virginia Certification #: 357
Virginia Certification #: 00213
Tennessee Certification#: 04010
South Carolina Drinking Water Cert. #: 990060003
South Carolina Certification #: 990060001
Pennsylvania Certification #: 68-00784
Connecticut Certification #: PH-0104
Asheville Certification IDs
West Virginia Certification #: 356
Virginia Certification #: 00072
Connecticut Certification#: PH-0106
Florlda/NELAP Certification #: E87648
Tennessee Certification #: 2980
South Carolina Certification #: 99030001
South Carolina Bioassay Certification #: 99030002
Eden Certification IDs
North Carolina wastewater Certification #: 633
Virginia Drinking Water Certification #: 00424
Pace Analytical Services, Inc.
2225 Riverside Dr.
CERTIFICATIONS
Asheville, NC 28804
[phone]
North Carolina Field Services Certification #: 5342
North Carolina Drinking Water Certification#: 37706
New Jersey Certification#: NC012
Louisiana/LELAP Certification #: 04034
Kentucky UST Certification #: 84
Florida/NELAP Certification#: E87627
North Carolina Wastewater Certification #: 12
Pennsylvania Certification #: 68-03578
North Carolina wastewater Certification#: 40
North Carolina Drinking water Certification#: 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification#: NC011
Massachusetts Certification #: M-NC030
LouisianalLELAP Certification #: 03095
North Carolina Drinking Water Certification #: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical SeNices, Inc ..
lg~\
Pace Analytical Services, Inc.
9600 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 35
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Method: MADEP EPH
Description: MADEP EPH NC Water
Client: Shield Engineering
Date: April 20, 2009
General Information:
Pace Analytical Services, Inc.
2225 Riverside Dr.
PROJECT NARRATIVE
Asheville, NC 28804
{828)25-4-7176
PaceAnalytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
6 samples were analyzed for MADEP EPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP EPH with any exceptions noted below.
Initial Calibrations (Including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
AU analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
AH laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
AU duplicate sample results were within method acceptance criteria with any exceptions noted below.
Addlllonal Comments:
Analyte Comments:
QC Batch: OEXT/6080
2g: Surrogate recovery outside laboratory control limlts due to matrix interferences.
• MW-3 (Lab ID: 9239316003)
• 2-Bromonaphthalene (S)
REPORT OF LABORATORY ANALYSIS
This report shalt not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
i~~~~
Page 3 of 35
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Method: EPA 601/602
Description: 601/602 Volatiles
Client: Shield Engineering
Date: April 20, 2009
General Information:
Pace Analytical Services, Inc.
2225 Riverside Dr.
PROJECT NARRATIVE
Asheville, NC 28B04
{B28)254-7176
6 samples were analyzed for EPA 601 /602. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
H5: Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
• MW-1 (Lab ID: 9239316001)
• MW-2 (Lab ID: 9239316002)
• MW-3 (Lab ID: 9239316003)
• T-1 (Lab ID: 9239316006)
Initial Calibrations (Including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptlons noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Splkas:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: GCV/2992
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9239715001
MO: Matrix spike recovery was outside laboratory control limits.
• MS (Lab ID: 250285)
• o-Xylene
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc .. ,~ ~~~o., ~~«;:~~~ ff/a~c~.
Page 4 of 35
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Method: MADEP VPH
Description: VPH NC water
Client: Shield Engineering
Date: April 20, 2009
General Information:
Pace Analytical Services, Inc.
2225 Riverside Dr.
PROJECT NARRATIVE
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
6 samples were analyzed for MADEP VPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (Including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Su"ogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit In the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All dupllcate sar11>le results were within method acceptance criteria with any exceptions noted below.
Addltlonal Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~ ,~ .!~.E.o~o -, ff "'i
Page 5 of 35
Pace Analytical Services, Inc.
2225 Riverside Or.
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Method: EPA625
Description: 625 MSSV
Client: Shield Engineering
Date: April 20, 2009
General Information:
PROJECT NARRATIVE
Asheville, NC 28804
{828)254-7176
6 samples were analyzed for EPA 625. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 625 with any exceptions noted below.
Initial Calibrations (Including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All Internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All enalytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Balch: OEXT/6095
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
1 g: Sample was diluted due to the presence of high levels of non-target analytes or other matrix Interference resulting in elevated
reporting llmils.
• MW-2 (Lab ID: 9239316002)
• Naphthalene
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .?«·~~~~ ~!J1eltl"C~
Page 6 of 35
Pace Analytlcal Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
TEXACO FOOD MART#21001289
9239316
Sample: MW-1 Lab ID: 9239316001 Collected: 03/04/09 14:05 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic {C09-C18) ND ug/L 128 03/06/0912:30 03/12/09 03:19
Aliphatic {C19-C36) ND ug/L 128 03/06/0912:30 03/12/09 03: 19
Aromatic {C 11-C22) 550 ug/L 128 03/06/0912:30 03/12/09 03: 19
Nonatriacontane (S) 70 % 40-140 03/06/0912:30 03/12/09 03:19 7194-86-7
o-Terphenyl {S) 76 % 40-140 03/06/09 12:30 03/12/09 03:19 84-15-1
2-Fluorobiphenyl (S) 86 % 40-140 03106/0912:30 03/12/09 03: 19 321-60-8
2-Bromonaphthalene (S) 95 % 40-140 03/06/0912:30 03/12/09 03:19 580-13-2
601/602 Volatiles Analytical Method: EPA601/602
Benzene 53.7 ug/L 10.0 10 03119/09 19:59 71-43-2 HS
Bromodichloromethane ND ug/L 10.0 10 03/19/09 19:59 75-27-4
Bromoform ND ug/L 10.0 10 03/19/09 19:59 75-25-2
Bromomethane ND ug/L 10.0 10 03119/09 19:59 74-83-9
Carbon tetrachloride ND ug/L 10.0 10 03/19/09 19:59 56-23-5
Chlorobenzene ND ug/L 10.0 10 03/19/09 19:59 108-90-7
Chloroethane ND ug/L 10.0 10 03119/09 19:59 75-00-3
Chloroform ND ug/L 10.0 10 03/19/09 19:59 67-66-3
Chloromethane ND ug/L 20.0 10 03/19/0919:59 74-87-3
Dibromochloromethane ND ug/L 10.0 10 03/19/09 19:59 124-48-1
1,2-Dlbromoethane (EDB) ND ug/L 10.0 10 03/19/09 19:59 106-93-4
1,2-Dlchlorobenzene ND ug/L 10.0 10 03/19/0919:59 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 10 03/19/09 19:59 541-73-1
1,4-Dichlorobenzene ND ug/L 10.0 10 03/19/09 19:59 106-46-7
Dlchlorodlfluoromethane ND ug/L 10.0 10 03/19/09 19:59 75-71-8
1, 1-Dlchloroethane ND ug/L 10.0 10 03/19/09 19:59 75.34.3 HS
1,2-Dichloroethane ND ug/L 10.0 10 03/19/09 19:59 107-06-2
1, 1-Dlchloroethene ND ug/L 10.0 10 03/19/09 19:59 75.35-4
cls-1,2-Dichloroethene ND ug/L 10.0 10 03/19/09 19:59 156-59-2
trans-1,2-Dichloroethene ND ug/L 10.0 10 03/19/09 19:59 156-60-5
1,2-Dlchloropropane ND ug/L 10.0 10 03/19/09 19:59 78-87-5
cls-1,3-Dichloropropene ND ug/L 10.0 10 03/19/09 19:59 10061-01-5
trans-1,3-Dichloropropene ND ug/L 10.0 10 03/19/09 19:59 10061-02-6
Dilsopropyl ether ND ug/L 10.0 10 03/19/09 19:59 108-20-3
Ethyl benzene 165 ug/L 10.0 10 03119/09 19:59 100-41-4
Methylene Chloride ND ug/L 20.0 10 03119/09 19:59 75-09-2
Methyl-tert-butyl ether ND.ug/L 10.0 10 03119/09 19:59 1634-04-4
Naphthalene 167 ug/L 20.0 10 03/19/09 19:59 91-20-3
1, 1,2,2-Tetrachloroethane ND ug/L 10.0 10 03/19/09 19:59 79.34.5
Tetrachloroethene ND ug/L 10.0 10 03119/0919:59 127-18-4
Toluene 28.4 ug/L 10.0 10 03119/09 19:59 108-88-3
1, 1, 1-Trichloroethane ND ug/L 10.0 10 03/19/0919:59 71-55-6
1, 1,2-Trlchloroethane ND ug/L 10.0 10 03/19/0919:59 79-00-5
Trichloroethene ND ug/L 10.0 10 03/19/0919:59 79-01-6
Trlchlorofluoromethane ND ug/L 10.0 10 03/19/09 19:59 75-69-4
Vinyl chloride ND ug/L 10.0 10 03/19/09 19:59 75-01-4
Xylene (Total) 827 ug/L 20.0 10 03/19/09 19:59 1330-20-7
m&p-Xylene 520 ug/L 20.0 10 03/19/09 19:59 1330-20-7
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 7 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q~~ .it/ ~
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 2B804
[phone]
Pace Analytical Services, Inc.
9B00 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-1 LablD: 9239316001 Collected: 03/04/09 14:05 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
601/602 Volatiles Analytical Method: EPA 601/602
o-Xylene 306 ug/L 10.0 10 03/19/09 19:59 95-47-6
1-Chloro-3-fluorobenzene (S) 120 % 65-137 10 03/19/0919:59 625-98-9
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08) 468 ug/L 100 03/11/09 16:31
Aliphatic (C09-C12) 7820 ug/L 100 03/11/09 16:31
Aromatic (C09-C10) 1850 ug/L 100 03/11/09 16:31
2,5-Dibromotoluene (PID)(S) 105 % 70-130 03/11/09 16:31
2,5-Dibromotoluene (FID)(S) 112 % 70-130 03/11/09 16:31
625MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 83-32-9
Acenaphthylene ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 208-96-8
Anthracene ND ug/L 5.5 03/07/0910:45 03/10/09 13:05 120-12-7
Benzo(a)anthracene ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 56-55-3
Benzo(a)pyrene ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 50-32-8
Benzo(b)fluoranthene ND ug/L 5.5 03/07/0910:45 03/10/09 13:05 205-99-2
Benzo(g,h ,i)perylene ND ug/L 5.5 03/07/0910:45 03/10/0913:05 191-24-2
Benzo(k)fluoranthene ND ug/L 5.5 03/07/0910:45 03/10/09 13:05 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.5 03/07/0910:45 03/10/09 13:05 101-55-3
Butylbenzylphthalate ND ug/L 5.5 03/07/0910:45 03/10/0913:05 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.5 03/0710910:45 03/10/09 13:05 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 11.0 03/07109 10:45 03/10/09 13:05 111-91-1
bis(2-Chloroethyl) ether ND ug/L 5.5 03107/0910:45 03110/09 13:05 111-44-4
bis(2-Chloroisopropyt) ether ND ug/L 5.5 0310710910:45 03/10/0913:05 108-60-1
2-Chloronaphthalene ND ug/L 5.5 0310710910:45 03/10/09 13:05 91-58-7
2-Chlorophenol ND ug/L 5.5 03/0710910:45 03/10/0913:05 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.5 03/07109 10:45 03110/09 13:05 7005-72-3
Chrysene ND ug/L 5.5 03/07109 10:45 03/10/09 13:05 218-01-9
Dlbenz(a,h)anthracene ND ug/L 5.5 03/07109 10:45 03110/09 13:05 53-70-3
3,3'-Dlchlorobenzidlne ND ug/L 5.5 03/0710910:45 03110/0913:05 91-94-1
2 ,4-Dichlorophenol ND ug/L 5.5 03107109 10:45 03/10/09 13:05 120-83-2
Diethylphthalate ND ug/L 5.5 03107109 10:45 03110/09 13:05 84-66-2
2,4-Dimethylphenol ND ug/L 11.0 03/0710910:45 03/10/0913:05 105-67-9
Dimethylphthalate ND ug/L 5.5 03/07109 10:45 03/10/0913:05 131-11-3
Dl-n-butylphthalate ND ug/L 5.5 03/07109 10:45 03110/09 13:05 84-74-2
4,6-Dinilro-2-methylphenol ND ug/L 22.0 03/07109 10:45 03110/09 13:05 534-52-1
2,4-Dlnitrophenol ND ug/L 54.9 03107109 10:45 03/10/09 13:05 51-28-5
2 ,4-Dinltrotoluene ND ug/L 5.5 03107/09 10:45 03/10/0913:05 121-14-2
2,6-Dlnltrotoluene ND ug/L 5.5 03/07109 10:45 03110/09 13:05 606-20-2
Dl-n-octylphthalate ND ug/L 5.5 03/07109 10:45 03/10/0913:05 117-84-0
bls(2-Ethylhexyl)phlhalate ND ug/L 5.5 03/07109 10:45 03/10/0913:05 117-81-7
Fluoranthene ND ug/L 5.5 03/07109 10:45 03110/09 13:05 206-44-0
Ffuorene ND ug/L 5.5 03/07109 10:45 03110/0913:05 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.5 03/07109 10:45 03/10/0913:05 87-68-3
Hexachlorobenzene ND ug/L 5.5 03/07/09 10:45 03110/0913:05 118-74-1
Dale: 04120/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 8 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivlces, lnc ..
'" •_coa~ Q~~ t a~
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-1
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
Naphthalene
Nitro benzene
2-Nltrophenol
4-Nltrophenol
N-Nltrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Tnchlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Trlbromophenol (S)
Date: 04/20/2009 04:02 PM
LablD: 9239316001 Collected: 03/04/0914:05 Received: 03/05/09 15:30 Matnx: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L 11.0 03/07/0910:45 03/10/0913:05 77-47-4
ND ug/L 5.5 03/07/09 10:45 03/10/0913:05 67-72-1
ND ug/L 5.5 03/07/0910:45 03/10/0913:05 193-39-5
ND ug/L 11.0 03/07/09 10:45 03/10/0913:05 78-59-1
62.7 ug/L 5.5 03/07/0910:45 03/10/0913:05 91-20-3
ND ug/L 5.5 03/07/0910:45 03/10/0913:05 98-95-3
ND ug/L 5.5 03/07/09 10:45 03/10/0913:05 88-75-5
ND ug/L 54.9 03/07/0910:45 03/10/0913:05 100-02-7
ND ug/L 5.5 03/07/09 10:45 03/10/0913:05 62-75-9
ND ug/L 5.5 03/07/0910:45 03/10/0913:05 621-64-7
ND ug/L 11.0 03/07/09 10:45 03/10/09 13:05 86-30-6
ND ug/L 27.5 03/07/09 10:45 03/10/09 13:05 87-86-5
ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 85-01-8
ND ug/L 5.5 03/07/09 10:45 03/10/09 13:05 108-95-2
ND ug/L 5.5 03/07/0910:45 03/10/0913:05 129-00-0
ND ug/L 5.5 03/07/09 10:45 03/10/0913:05 120-82-1
ND ug/L 11.0 03/07/0910:45 03/10/0913:05 88-06-2
63 % 10-120 03/07/09 10:45 03/10/09 13:05 4165-60-0
56 % 15-120 03/07/09 10:45 03/10/09 13:05 321-60-8
75 % 11-131 1 03/07/09 10:45 03/10/09 13:05 1718-51-0
26 % 10-120 1 03/07/09 10:45 03/10/09 13:05
35 % 10-120 03/07/09 10:45 03/10/09 13:05
56 % 10-137 03/07/09 10:45 03/10/0913:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
~ ,~_ACCO~O
' . ff \
13127-88-3
367-12-4
118-79-6
Qual
Page 9 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-2 Lab ID: 9239316002 Collected: 03/04/0914:25 Received: 03/05/0915:30 Matrix: water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18) 1320 ug/L 220 2 03/06/0912:30 03/12/09 17:26
Aliphatic (C19-C36) ND ug/L 110 03/06/0912:30 03/12/09 03:52
Aromatic (C 11-C22) 1950 ug/L 110 03/06/0912:30 03/12/09 03:52
Nonatriacontane (S) 82 % 40-140 03/06/0912:30 03/12/09 03:52 7194-86-7
o-Terphenyl (S) 90 % 40-140 03/06/0912:30 03112/09 03:52 84-15-1
2-Fluorobiphenyl (S) 102 % 40-140 03/06/0912:30 03112/09 03:52 321-60-8
2-Bromonaphthalene (S) 110 % 40-140 03/06/0912:30 03/12/09 03:52 580-13-2
601/602 Volatiles Analytical Method: EPA601/602
Benzene 11700 ug/L 1000 1000 03/19/09 20:40 71-43-2 H5
Bromodichloromethane ND ug/L 1000 1000 03/19/09 20:40 75-27-4
Bromoform ND ug/L 1000 1000 03/19/09 20:40 75-25-2
Bromomethane ND ug/L 1000 1000 03/19/09 20:40 74-83-9
Carbon tetrachloride ND ug/L 1000 1000 03/19/09 20:40 56-23-5
Chlorobenzene ND ug/L 1000 1000 03119/09 20:40 108-90-7
Chloroethane ND ug/L 1000 1000 03119/09 20:40 75-00-3
Chloroform ND ug/L 1000 1000 03/19/09 20:40 67-66-3
Chloromethane ND ug/L 2000 1000 03/19/09 20:40 74-87-3
Dlbromochloromethane ND ug/L 1000 1000 03/19/09 20:40 124-48-1
1,2-Dlbromoethane (EDB) ND ug/L 1000 1000 03119/09 20:40 106-93-4
1,2-Dlchlorobenzene ND ug/L 1000 1000 03/19/09 20:40 95-50-1
1,3-Dichlorobenzene ND ug/L 1000 1000 03/19/09 20:40 541-73-1
1,4-Dlchlorobenzene ND ug/L 1000 1000 03/19/09 20:40 106-46-7
Dichlorodifluoromethane ND ug/L 1000 1000 03/19/09 20:40 75-71-8
1, 1-Dichloroethane ND ug/L 1000 1000 03/19/09 20:40 75-34-3 H5
1,2-Dlchloroethane ND ug/L 1000 1000 03/19/09 20:40 107-06-2
1, 1-Dlchloroethene ND ug/L 1000 1000 03/19/09 20:40 75-35-4
cis-1,2-Dichloroethene ND ug/L 1000 1000 03/19/09 20:40 156-59-2
trans-1,2-Dichloroethene ND ug/L 1000 1000 03/19/09 20:40 156-60-5
1,2-Dlchloropropane ND ug/L 1000 1000 03/19/09 20:40 78-87-5
cis-1,3-Dichloropropene · ND ug/L 1000 1000 03/19/09 20:40 10061-01-5
trans-1,3-Dichtoropropene ND ug/L 1000 1000 03/19/09 20:40 10061-02-6
Dllsopropyl ether ND ug/L 1000 1000 03/19/09 20:40 108-20-3
Ethylbenzene 2250 ug/L 1000 1000 03/19/09 20:40 100-41-4
Methylene Chloride ND ug/L 2000 1000 03/19/09 20:40 75-09-2
Methyl-tert-butyl ether 3600 ug/L 1000 1000 03/19/09 20:40 1634-04-4
Naphthalene ND ug/L 2000 1000 03/19/09 20:40 91-20-3
1, 1,2,2-Tetrachloroethane ND ug/L 1000 1000 03/19/09 20:40 79-34-5
Tetrachloroethene ND ug/L 1000 1000 03/19/09 20:40 127-18-4
Toluene 27200 ug/L 1000 1000 03/19/09 20:40 108-88-3
1, 1, 1-Trichloroethane ND ug/L 1000 1000 03/19/09 20:40 71-55-6
1, 1,2-Trichloroethane ND ug/L 1000 1000 03/19/09 20:40 79-00-5
Trichtoroethene ND ug/L 1000 1000 03/19/09 20:40 79-01-6
Trichlorofluoromethane ND ug/L 1000 1000 03/19/09 20:40 75-69-4
Vinyl chloride ND ug/L 1000 1000 03/19/09 20:40 75-01-4
Xylene (Total) 14500 ug/L 2000 1000 03/19/09 20:40 1330-20-7
m&p-Xylene 9890 ug/L 2000 1000 03/19/09 20:40 1330-20-7
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 10 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
t~i3t ~I , ...
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28604
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
TEXACO FOOD MART #2 1001289
9239316
Sample: MW-2 LablD: 9239316002 Collected: 03/04/0914:25 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
601/602 Volatiles Analytical Method: EPA601/602
a-Xylene 4660 ug/L 1000 1000 03/19/09 20:40 95-47-6
1-Chloro-3-fluorobenzene (S) 115 % 65-137 1000 03/19/09 20:40 625-98-9
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08) 59300 ug/L 100 03/11/09 17:00
Aliphatic (C09-C12) 64000 ug/L 100 03/11/09 17:00
Aromatic (C09-C10) 6390 ug/L 100 03/11 /09 17:00
2,5-Dibromotoluene (PID)(S) 101 % 70-130 03/11/09 17:00
2,5-Dibromotoluene (FID)(S) 110 % 70-130 03/11/09 17:00
625MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 28.7 5 03/07/0910:45 03/11/09 12:03 83-32-9
Acenaphthylene ND ug/L 28.7 5 03/07/09 10:45 03/11/0912:03 208-96-8
Anthracene ND ug/L 28.7 5 03/07/09 10:45 03/11/09 12:03 120-12-7
Benzo(a)anthracene ND ug/L 28.7 5 03/07/09 10:45 03/11/09 12:03 56-55-3
Benzo(a)pyrene ND ug/L 28.7 5 03/07/0910:45 03/11/0912:03 50-32-8
Benzo(b )fluoranthene ND ug/L 28.7 5 03/07/0910:45 03/11 /09 12:03 205-99-2
Benzo(g,h,l)perylene ND ug/L 28.7 5 03/07/09 10:45 03/11/09 12:03 191-24-2
Benzo(k)fluoranthene ND ug/L 28.7 5 03/07/0910:45 03/11 /09 12:03 207-08-9
4-Bromophenylphenyl ether ND ug/L 28.7 5 03/07/0910:45 03/11/09 12:03 101-55-3
Bulylbenzylphlhalate ND ug/L 28.7 5 03/07/0910:45 03/11/09 12:03 85-68-7
4-Chloro-3-methylphenol ND ug/L 28.7 5 03/0710910:45 03111/09 12:03 59-50-7
bls(2-Chloroethoxy)melhane ND ug/L 57.5 5 03/0710910:45 03/11 /09 12:03 111-91-1
bls(2-Chloroethyl) ether ND ug/L 28.7 5 03/07/0910:45 03111/09 12:03 111-44-4
bls(2-Chlorolsopropyl) ether ND ug/L 28.7 5 03/07/0910:45 03111/09 12:03 108-60.1
2-Chloronaphlhalene ND ug/L 28.7 5 03/07/0910:45 03111/0912:03 91-58-7
2-Chlorophenol ND ug/L 28.7 5 03/0710910:45 03/11/09 12:03 95-57-8
4-Chlorophenylphenyl ether ND ug/L 28.7 5 03/07/0910:45 03/11/09 12:03 7005-72-3
Chrysene ND ug/L 28.7 5 03/07109 10:45 03111 /09 12:03 218-01-9
Dlbenz(a,h)anthracene ND ug/L 28.7 5 03/0710910:45 03/11/09 12:03 53-70-3
3,3'-Dlchlorobenzldlne ND ug/L 28.7 5 03/07109 10:45 03/11/09 12:03 91-94-1
2,4-Dichlorophenol ND ug/L 28.7 5 03/07109 10:45 03/11/0912:03 120-83-2
Diethylphthalate ND ug/L 28.7 5 03/07/0910:45 03/11/09 12:03 84-66-2
2,4-Dlmethylphenol ND ug/L 57.5 5 03/0710910:45 03/11/09 12:03 105-67-9
Dlmethylphthalate ND ug/L 28.7 5 03/07109 10:45 03/11/0912:03 131-11-3
Di-n-butylphthalate ND ug/L 28.7 5 03/07109 10:45 03/11/09 12:03 84-74-2
4,6-Dlnltro-2-methylphenol ND ug/L 115 5 03/07109 10:45 03/11/0912:03 534-52-1
2,4-Dlnllrophenol ND ug/L 287 5 03/07109 10:45 03/11/0912:03 51-28-5
2,4-Dinitrotoluene ND ug/L 28.7 5 03/07109 10:45 03/11/0912:03 121-14-2
2,6-Dinitrotoluene ND ug/L 28.7 5 03/07/09 10:45 03/11/0912:03 606-20-2
Di-n-octylphlhalate ND ug/L 28.7 5 03/07/09 10:45 03/11/0912:03 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 28.7 5 03/07109 10:45 03111/0912:03 117-81-7
Fluoranthene ND ug/L 28.7 5 03/07109 10:45 03/11 /09 12:03 206-44-0
Fluorene ND ug/L 28.7 5 03/07109 10:45 03/11/0912:03 86-73-7
Hexachloro-1,3-butadlene ND ug/L 28.7 5 03/07/09 10:45 03/11/0912:03 87-68-3
Hexachlorobenzene ND ug/L 28.7 5 03/07109 10:45 03/11/0912:03 118-74-1
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 11 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytlcal Services, Inc ..
~~~~~ ff! Q\
Pace Analytical Service&, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9600 Kincey Ave. Suite 100
Huntersville, NC 26078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-2
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
Naphthalene
Nitrobenzene
2-Nltrophenol
4-Nltrophenol
N-Nitrosodimethylamlne
N-Nitroso-di-n-propylar'nlne
N-Nitrosodlphenylamlne
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Tnchlorophenol
Nitrobenzene-d5 (S)
2-Fluoroblphenyl (S)
Terphenyl-d 14 (S)
Phenol-d6 (S)
· 2-Fluorophenol (S)
2,4,6-Trlbromophenol (S)
Date: 04/20/2009 04:02 PM
Lab ID: 9239316002 Collected: 03/04/09 14:25 Received: 03/05/0915:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA 625 Preparalion Method: EPA 625
ND ug/L 57.5 5 03/07/09 10:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 57.5 5 03/07/0910:45
238 ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 287 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 57.5 5 03/07/0910:45
ND ug/L 144 5 03/07/09 10:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/0910:45
ND ug/L 28.7 5 03/07/09 10:45
ND ug/L 57.5 5 03/07/0910:45
28 % 10-120 5 03/07/09 10:45
29 % 15-120 5 03/07/0910:45
26 % 11-131 5 03/07/0910:45
15 % 10-120 5 03/07/0910:45
16 % 10-120 5 03/07/0910:45
19 % 10-137 5 03/07/0910:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
03/11/09 12:03 77-47-4
03/11/0912:03 67-72-1
03/11/09 12:03 193-39-5
03/11/09 12:03 78-59-1
03/11 /09 12:03 91-20-3 1g
03/11/09 12:03 98-95-3
03/11/0912:03 88-75-5
03/11/0912:03 100-02-7
03/11/09 12:03 62-75-9
03/11/09 12:03 621-64-7
03/11/09 12:03 66-30-6
03/11/09 12:03 87-86-5
03/11/0912:03 85-01-8
03/11/09 12:03 108-95-2
03/11/09 12:03 129-00-0
03/11/0912:03 120-82-1
03/11 /09 12:03 88-06-2
03/11/09 12:03 4165-60-0
03/11/09 12:03 321-60-8
03/11/09 12:03 1718-51-0
03/11/09 12:03 13127-88-3
03/11/09 12:03 367-12-4
03/11/09 12:03 118-79-6
Page 12 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Service&, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875,-9092
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-3 Lab ID: 9239316003 Collected: 03/04/0913:45 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18) 296 ug/L 115 03/06/0912:30 03/12/09 04:25
Aliphatic (C 19-C36) ND ug/L 115 03/06/09 12:30 03/12/09 04:25
Aromatic (C 11-C22) 1910 ug/L 115 03/06/09 12:30 03/12/09 04:25
Nonatriacontane (S) 77 % 40-140 03/06/0912:30 03/12/09 04:25 7194-86-7
o-Terphenyl (S) 85 % 40-140 03/06109 12:30 03112/09 04:25 84-15-1
2-Fluoroblphenyl (S) 120 % 40-140 03106109 12:30 03112/09 04:25 321-60-8
2-Bromonaphthalene (S) 177 % 40-140 03/06/0912:30 03112/09 04:25 580-13-2 2g
601/602 Volatllea Analytical Method: EPA 601/602
Benzene ND ug/L 250 250 03/19/09 22:03 71-43-2 HS
Bromodichloromethane ND ug/L 250 250 03/19/09 22:03 75-27-4
Bromoform ND ug/L 250 250 03119109 22:03 75-25-2
Bromomethane ND ug/L 250 250 03119/09 22:03 74-83-9
Carbon tetrachloride ND ug/L 250 250 03/19/09 22:03 56-23-5
Chlorobenzene ND ug/L 250 250 03119/09 22:03 108-90-7
Chloroethane ND ug/L 250 250 03/19/09 22:03 75-00-3
Chloroform ND ug/L 250 250 03/19109 22:03 67-66-3
Chloromethane ND ug/L 500 250 03/19109 22:03 74-87-3
Dlbromochloromethane ND ug/L 250 250 03119/09 22:03 124-48-1
1,2-Dlbromoethane (EDB) ND ug/L 250 250 03119/09 22:03 106-93-4
1,2-Dichlorobenzene ND ug/L 250 250 03/19/09 22:03 95-50-1
1,3-Dlchlorobenzene ND ug/L 250 250 03119/09 22:03 541-73-1
1,4-Dichlorobenzene ND ug/L 250 250 03119/09 22:03 106-46-7
Olchlorodlfluoromethane ND ug/L 250 250 03/19109 22:03 75-71-8
1, 1-Dichloroethane ND ug/L 250 250 03119/09 22:03 75-34-3 HS
1,2-Dlchloroethane ND ug/L 250 250 03/19/09 22:03 107-06-2
1, 1-0ichloroethene ND ug/L 250 250 03/19/09 22:03 75-35-4
cls-1,2-Dlchloroethene ND ug/L 250 250 03119/09 22:03 156-59-2
trans-1,2-0ichloroethene ND ug/L 250 250 03119109 22:03 156-60-5
1,2-Dlchloropropane ND ug/L 250 250 03/19109 22:03 78-87-5
cls-1,3-Dichloropropene ND ug/L 250 250 03/19/09 22:03 10061-01-5
trans-1,3-0ichloropropene ND ug/L 250 250 03119/09 22:03 10061-02-6
Dlisopropyl ether ND ug/L 250 250 03119/09 22:03 108-20-3
Ethylbenzene 2090 ug/L 250 250 03119/09 22:03 100-41-4
Methylene Chloride ND ug/L 500 250 03/19/09 22:03 75-09-2
Methyl-tert-butyl ether ND ug/L 250 250 03/19109 22:03 1634-04-4
Naphthalene 1520 ug/L 500 250 03/19109 22:03 91-20-3
1, 1,2,2-Tetrachloroethane ND ug/L 250 250 03/19/09 22:03 79-34-5
Tetrachloroethene ND ug/L 250 250 03119/09 22:03 127-18-4
Toluene 3430 ug/L 250 250 03119109 22:03 108-88-3
1, 1, 1-Trichloroethane ND ug/L 250 250 03119109 22:03 71-55-6
1, 1,2-Trlchloroethane ND ug/L 250 250 03/19109 22:03 79-00-5
Trichloroethene ND ug/L 250 250 03/19109 22:03 79-01-6
Trichlorofluoromethane ND ug/L 250 250 03/19/09 22:03 75-69-4
Vinyl chloride ND ug/L 250 250 03/19109 22:03 75-01-4
Xylene (Total) 11400 ug/L 500 250 03119/09 22:03 1330-20-7
m&p-Xylene 7730 ug/L 500 250 03119/09 22:03 1330-20-7
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 13 of 35
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
.... ~~~ .... f1 a~
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-3 Lab ID: 9239316003 Collected: 03/04/0913:45 Received: 03/05/0915:30 Matrix: Water
Parameters
601/602 Volatiles
a-Xylene
1-Chloro-3-fluorobenzene (S)
VPH NC Water
Aliphatic (COS-COB)
Aliphatic (C09-C12)
Aromatic (C09-C10)
2,5-Dibromotoluene (PID)(S)
2,5-Dlbromotoluene (FID)(S)
625 MSSV
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,l)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bis(2-Chloroethoxy)methane
bls(2-Chloroethyl) ether
bls(2-Chlorolsopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dlbenz(a,h)anthracene
3,3'-Dichlorobenzldlne
2,4-Dlchlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Dl-n-butylphthalate
4,6-Dinltro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinltrotoluene
2,6-Dlnltrotoluene
Dl-n-octylphthalate
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Date: 04/20/2009 04:02 PM
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 601/602
3690 ug/L 250 250 03/19/09 22:03 95-47-6
107 % 65-137 250 03/19/09 22:03 625-98-9
Analytical Method: MADEP VPH
5560 ug/L 100 03/11 /09 17:30
50500 ug/L 100 03/11/09 17:30
9870 ug/L 100 03/11/09 17:30
106 % 70-130 03/11/09 17:30
117 % 70-130 03/11 /09 17:30
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 83-32-9
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 208-96-8
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 120-12-7
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 56-55-3
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 50-32-8
ND ug/L 5.8 03/07109 10:45 03/10/09 14:32 205-99-2
ND ug/L 5.8 03/07109 10:45 03/10/09 14:32 191-24-2
ND ug/L 5.8 03/0710910:45 03/10/09 14:32 207-08-9
ND ug/L 5.8 03/0710910:45 03/10/09 14:32 101-55-3
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 85-68-7
ND ug/L 5.8 03107109 10:45 03110/09 14:32 59-50-7
ND ug/L 11.6 03/07109 10:45 03110/09 14:32 111-91-1
ND ug/L 5.8 03/0710910:45 03110/09 14:32 111-44-4
ND ug/L 5.8 03/0710910:45 03110/09 14:32 108-60-1
ND ug/L 5.8 03/07/0910:45 03110/09 14:32 91-58-7
ND ug/L 5.8 03/0710910:45 03110/0914:32 95-57-8
ND ug/L 5.8 03/0710910:45 03/10/09 14:32 7005-72-3
ND ug/L 5.8 03/0710910:45 03110/09 14:32 218-01-9
ND ug/L 5.8 03/07/0910:45 03110/09 14:32 53-70-3
ND ug/L 5.8 03107109 10:45 03110/0914:32 91-94-1
ND ug/L 5.8 03/07109 10:45 03/10/09 14:32 120-83-2
ND ug/L 5.8 0310710910:45 03110/09 14:32 84-66-2
ND ug/L 11.6 03/0710910:45 03110/09 14:32 105-67-9
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 131-11-3
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 84-74-2
ND ug/L 23.3 03107/09 10:45 03110/09 14:32 534-52-1
ND ug/L 58.1 03107109 10:45 03110/09 14:32 51-28-5
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 121-14-2
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 606-20-2
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 117-84-0
ND ug/L 5.8 03/07109 10:45 03/10/0914:32 117-81-7
ND ug/L 5.8 03/07109 10:45 03110/09 14:32 206-44-0
ND ug/L 5.8 03/07/0910:45 03110/0914:32 86-73-7
ND ug/L 5.8 03/07109 10:45 03/10/09 14:32 87-68-3
ND ug/L 5.8 03/07109 10:45 03/10/09 14:32 118-74-1
REPORT OF LABORATORY ANALYSIS Page 14 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
?{~~\~
Pace Analytlcal Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-3
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
Naphthalene
Nltrobenzene
2-Nltrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-dl-n-propylamlne
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Trlbromophenol (S)
Date: 04/20/2009 04:02 PM
LablD: 9239316003 Collected: 03/04/0913:45 Received: 03/05/0915:30 Matlix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L 11.6 03/07/0910:45 03/10/09 14:32 77-47-4
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 67-72-1
ND ug/L 5.8 03/07/0910:45 03/10/0914:32 193-39-5
ND ug/L 11.6 03/07/0910:45 03/10/09 14:32 78-59-1
595 ug/L 58.1 10 03/07/0910:45 03/11/09 12:25 91-20-3
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 98-95-3
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 88-75-5
ND ug/L 58.1 03/07/09 10:45 03/10/09 14:32 100-02-7
ND ug/L 5.8 03/07/09 10:45 03/10/09 14:32 62-75-9
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 621-64-7
ND ug/L 11.6 03/07/0910:45 03/10/09 14:32 86-30-6
ND ug/L 29.1 03/07/09 10:45 03/10/09 14:32 87-86-5
ND ug/L 5.8 03/07/09 10:45 03/10/09 14:32 85-01-8
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 108-95-2
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 129-00-0
ND ug/L 5.8 03/07/0910:45 03/10/09 14:32 120-82-1
ND ug/L 11.6 03/07/0910:45 03/10/09 14:32 88-06-2
94 % 10-120 03/07/09 10:45 03/10/09 14:32 4165-60-0
56 % 15-120 03/07/09 10:45 03/10/09 14:32 321-60-8
90 % 11-131 03/07/0910:45 03/10/09 14:32 1718-51-0
59 % 10-120 03/07/0910:45 03/10/0914:32 13127-88-3
37 % 10-120 03/07/0910:45 03/10/09 14:32 367-12-4
59 % 10-137 03/07/0910:45 03/10/09 14:32 118-79-6
REPORT OF LABORATORY ANALYSIS Page 15 0135
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.. Q,~-~.~£~ . , i \
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28076
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-4
Parameters
MADEP EPH NC Water
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
Nonatrlacontane (S)
o-Terphenyl (S)
2-Fluoroblphenyl ($)
2-Bromonaphthalene (S)
6011602 Volallles
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dlbromochloromethane
1,2-Dlbromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dlchlorobenzene
1,4-Dlchlorobenzene
Dlchlorodlfluoromethane
1, 1-Dlchloroethane
1,2-Dlchloroethane
1, 1-Dlchloroethene
cis-1,2-Dlchloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dlchloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethane
Trichlorofluoromethane
Vinyl chloride
Xylene (Total)
m&p-Xylene
Date: 0412012009 04:02 PM
LablD: 9239316004 Collected: 03104109 13:20 Received: 03/05/0915:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. ---·---------------
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
ND ug/L
ND ug/L
ND ug/L
74 %
93 %
101 %
104 %
Analytical Method: EPA601/602
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
4.3 ug/L
12,3 ugll
ND ug/L
ND ug/L
5,2 ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
11,6 ug/L
8,3 ug/L
123
123
123
40-140
40-140
40-140
40-140
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
2.0
03106109 t2:30 03112109 04:58
03/06/0912:30 03112109 04:58
03106/0912:30 03112109 04:58
03/06/0912:30 03112109 04:58 7194-86-7
03/06/0912:30 03112109 04:58 84-15-1
03/06/0912:30 03112109 04:58 321-60-8
03106109 t2:30 03112109 04:58 580-13-2
03117109 00:14 71-43-2
03117109 00:14 75-27-4
03117109 00:14 75-25-2
03117109 00:14 74-83-9
03117109 00:14 56-23-5
03117109 00:14 108-90-7
03117109 00:14 75-00-3
03117109 00:14 67-66-3
03117109 00:14 74-87-3
03117109 00:14 124-48-1
03117109 00:14 106-93-4
03117109 00:14 95-50-1
03117109 00:14 541-73-1
03117109 00:14 106-46-7
03117109 00:14 75-71-8
03117109 00:14 75-34-3
03117109 00:14 107-06-2
03117109 00:14 75-35-4
03117109 00:14 156-59-2
03117109 00:14 156-60-5
03117/09 00:14 76-87-5
03117109 00:14 10061-01-5
03117109 00:14 10061-02-6
03117109 00:14 106-20-3
03117109 00:14 100-41-4
03117109 00:14 75-09-2
03117109 00:14 1634-04-4
03117109 00:14 91-20-3
03117109 00:14 79-34-5
03117109 00:14 127-18-4
03117109 00:14 108-88-3
03117109 00:14 71-55-6
03117109 00:14 79-00-5
03117109 00:14 79-01-6
03117109 00:14 75-69-4
03117/09 00:14 75-01-4
03117109 00:14 1330-20-7
03117109 00:14 1330-20-7
Quat
REPORT OF LABORATORY ANALYSIS Page 16 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivlces, Inc ..
Pace AnalytJcal Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Project: TEXACO FOOD MART #21001289
Pace Project No.: 9239316
Sample: MW-4 Lab ID: 9239316004 Collected: 03/04/09 13:20 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual --------------------------·----------------
601/602 Volatiles
o•Xylene
1-Chloro-3-fluorobenzene (S)
VPH NC water
Aliphatic (COS-COS)
Aliphatic (C09-C12)
Aromatic (C09-C10)
2,5-Dlbromotoluene (PID)(S)
2,5-Dlbromotoluene (FID)(S)
625 MSSV
AC6naphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bls(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chlorolsopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dlbenz(a,h)anthracene
3,3'-Dichlorobenzldlne
2,4-Dlchlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dlmethylphthalate
Di-n-butylphthalate
4,6-Dlnltro-2-methylphenol
2,4~Dinitrophenol
2 ,4-Dinltrotoluene
2,6-Dinltrotoluene
Dl-n-octylphthalate
bls(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3--butadiene
Hexachlorobenzene
Dale: 04/20/2009 04:02 PM
Analyllcal Method: EPA 601/602
3.2 ug/L
116 %
Analytical Method: MADEP VPH
ND ug/L
186 ug/L
ND ug/L
99 %
107 %
1.0
65-137
100
100
100
70-130
70-130
03/17/09 00:14 95-47-6
03/17/09 00:14 625-98-9
03/11/09 17:59
03/11/09 17:59
03/11/09 17:59
03/11/0917:59
03/11/09 17:59
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
6.0 1
6.0 1
6.0
6.0
6.0
6.0
6.0
6.0
6.0
8.0
6.0
11.9
6.0 1
6.0 1
8.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
11.9
6.0
6.0 1
23.8 1
59.5
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
03/07/0910:45 03/10/09 14:54 83-32-9
03/07/0910:45 03/10/09 14:64 208-96-8
03/07/0910:45 03/10/09 14:54 120-12-7
03/07/0910:45 03/10/09 14:54 56-55-3
03/07/0910:45 03/10/09 14:64 50-32-8
03/07/0910:45 03/10/0914:54 205-99-2
03/07/0910:45 03/10/09 14:54 191-24-2
03/07/0910:45 03/10/09 14:64 207-08-9
03/07/0910:45 03/10/0914:54 101-55-3
03/07/0910:45 03/10/09 14:54 85-68-7
03/07/0910:45 03/10/09 14:64 59-50-7
03/07/0910:45 03/10/09 14:64 111-91-1
03/07/0910:45 03/10/09 14:54 111-44-4
03/07/0910:45 03/10/0914:54 108-60-1
03/07/0910:45 03/10/09 14:54 91-58-7
03/07/0910:45 03/10/09 14:54 95-57-8
03/07/0910:45 03110/0914:54 7005-72-3
03/07/0910:45 03/10/09 14:54 218-01-9
03/07/0910:45 03/10/09 14:64 53-70-3
03/0710910:45 03/10/09 14:54 91-94-1
03/0710910:45 03110109 14:64 120-83-2
03/07/0910:45 03/10/09 14:54 84-66-2
03/0710910:45 03/10/09 14:54 105-67-9
03/0710910:45 03/10/0914:54 131-11-3
03/07/09 10:45 03110/09 14:54 84-74-2
03/0710910:45 03110/09 14:54 534-52-1
03/0710910:45 03110/09 14:54 51-28-5
03/07/09 10:45 03110/09 14:54 121-14-2
03/07/09 10:45 03/10/09 14:54 606-20-2
03107109 10:45 03/10/0914:54 117-84-0
03/0710910:45 03/10/0914:54 117-81-7
03/07/09 10:45 03/10/09 14:54 206-44-0
03/07/09 10:45 03/10/09 14:54 86-73-7
03/07109 10:45 03/10/09 14:54 87-68-3
03/07/09 10:45 03/10/0914:54 118-74-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except ln full,
without the written consent of Pace Analytical Services, Inc ..
Page 17 of35
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28B04
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-4
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
Naphthalene
Nitro benzene
2-Nltrophenol
4-Nltrophenol
N-Nitrosodimethylamine
N-Nltroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenol
Nltrobenzene-d5 (S)
2-Fluoroblphenyl (S)
Terphenyi-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date: 04/20/2009 04:02 PM
Lab ID: 9239316004 Collected: 03/04/0913:20 Received: 03/05/09 15:30 Matrix: Water
Results Units Report Limit OF Prepared
Analytical Method: EPA625 Preparation Method: EPA625
ND ug/L 11.9 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 11.9 03107/09 10:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 6.0 03/07/09 10:45
ND ug/L 6.0 03/07/09 10:45
ND ug/L 59.5 03/07/09 10:45
ND ug/L 6.0 03107/0910:45
ND ug/L 6.0 03107/0910:45
ND ug/L 11.9 03/07/0910:45
ND ug/L 29.8 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 6.0 03/07/0910:45
ND ug/L 11.9 03/07/09 10:45
74 % 10-120 03/07/0910:45
64 % 15-120 03107/09 10:45
77 % 11-131 03/07/09 10:45
32 % 10-120 03/07/09 10:45
49 % 10-120 03/07/0910:45
58 % 10-137 03/07/0910:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
03/10/0914:54 77-47-4
03/10/0914:54 67-72-1
03/10/09 14:54 193-39-5
03110/0914:54 78-59-1
03/10/0914:54 91-20-3
03/10/0914:54 98-95-3
03/10/0914:54 88-75-5
03/10/0914:54 100-02-7
03/10/0914:54 62-75-9
03/10/09 14:54 621-64-7
03/10/09 14:54 86-30-6
03/10/09 14:54 87-86-5
03/10/09 14:54 85-01-8
03/10/0914:54 108-95-2
03/10/0914:54 129-00-0
03110/09 14:54 120-82-1
03/10/09 14:54 88-06-2
03/10/09 14:54 4165-60-0
03/10/09 14:54 321-60-8
03/10/09 14:54 1718-51-0
03110/09 14:54 13127-88-3
03/10/09 14:54 367-12-4
03/10/09 14:54 118-79-6
Page 18 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-5
Parameters
MADEP EPH NC Water
Aliphatic (C09-C18)
Aliphatic (C19-C36)
Aromatic (C11-C22)
Nonatriacontane (S)
o-Terphenyl (S)
2-Fluoroblphenyl (S)
2-Bromonaphthalene (S)
601/602 Volatiles
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chtoromethane
Dibromochloromethane
1,2-Dibromoethane (EDB)
1,2-Dlchlorobenzene
1,3-Dichlorobenzene
1,4-Dlchlorobenzene
Dichlorodlfluoromethane
1, 1-Dlchloroethane
1,2-Dlchloroethane
1, 1-Dichloroethene
cis-1,2-Dlchloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dlisopropyl ether
Ethylbenzene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1, 1, 1-Trlchloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylene (Total)
m&p-Xylene
Date: 04/20/2009 04:02 PM
LablD: 9239316005 Collected: 03/04/0915:00 Received: 03/05/0915:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
ND ug/L 125 03/06/09 12:30 03/12/09 05:31
ND ug/L 125 03/06/09 12:30 03/12/09 05:31
ND ug/L 125 03/06/09 12:30 03/12/09 05:31
81 % 40-140 03/06/09 12:30 03/12/09 05:31 7194-86-7
83 % 40-140 03/06/09 12:30 03/12/09 05:31 84-15-1
89 % 40-140 03/06/09 12:30 03/12/09 05:31 321-60-8
91 % 40-140 03/06/09 12:30 03/12/09 05:31 580-13-2
Analytical Method: EPA 601/602
ND ug/L 1.0 03/17/09 00:55 71-43-2
ND ug/L 1.0 03/17/09 00:55 75-27-4
ND ug/L 1.0 03/17/09 00:55 75-25-2
ND ug/L 1.0 03/17/09 00:55 74-83-9
ND ug/L 1.0 03/17/09 00:55 56-23-5
ND ug/L 1.0 03/17/09 00:55 108-90-7
ND ug/L 1.0 03/17/09 00:55 75-00-3
ND ug/L 1.0 03/17/09 00:55 67-66-3
ND ug/L 2.0 03/17/09 00:55 74-87-3
ND ug/L 1.0 03/17/09 00:55 124-48-1
ND ug/L 1.0 03/17/09 00:55 108-93-4
ND ug/L 1.0 03/17/09 00:55 95-50-1
ND ug/L 1.0 03/17/09 00:55 541-73-1
ND ug/L 1.0 03/17/09 00:55 106-46-7
ND ug/L 1.0 03/17/09 00:55 75-71-8
ND ug/L 1.0 03/17/09 00:55 75-34-3
ND ug/L 1.0 03/17/09 00:55 107-06-2
ND ug/L 1.0 03/17/09 00:55 75-35-4
ND ug/L 1.0 03/17/09 00:55 156-59-2
ND ug/L 1.0 03/17/09 00:55 156-60-5
ND ug/L 1.0 03/17/09 00:55 78-87-5
ND ug/L 1.0 03/17/09 00:55 10061-01-5
ND ug/L 1.0 03/17/09 00:55 10061-02-6
ND ug/L 1.0 03/17/09 00:55 108-20-3
ND ug/L 1.0 03/17/09 00:55 100-41-4
ND ug/L 2.0 03/17/09 00:55 75-09-2
ND ug/L 1.0 03/17/09 00:55 1634-04-4
2.9 ug/L 2.0 03/17/09 00:55 91-20-3
ND ug/L 1.0 03/17/09 00:55 79.34.5
ND ug/L 1.0 03/17/09 00:55 127-18-4
1,9 ug/L 1.0 03/17/09 00:55 108-88-3
ND ug/L 1.0 03/17/09 00:55 71-55-6
ND ug/L 1.0 03/17/09 00:55 79-00-5
ND ug/L 1.0 03/17/09 00:55 79-01-6
ND ug/L 1.0 03/17/09 00:55 75-69-4
ND ug/L 1.0 03/17/09 00:55 75-01-4
ND ug/L 2.0 03/17/09 00:55 1330-20-7
ND ug/L 2.0 03/17/09 00:55 1330-20-7
REPORT OF LABORATORY ANALYSIS Page 19 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivices, Inc .. ~:1y..~~~ f(netae\,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
(828)254·7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875•9092
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: MW-5
Parameters
601/602 Volatiles
o-Xylene
1-Chloro-3-fluorobenzene (S)
VPH NC Water
Aliphatic (COS-COB)
Aliphatic (C09-C12)
Aromatic (C09-C10)
2,5-Dlbromotoluene (PID)(S)
2,5-Dibromotoluene (FID)(S)
625MSSV
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,l)perylene
Benzo(k)fluoranlhene
4-Bromophenylphenyl ether
Butylbenzylphthalale
4-Chloro-3-methylphenol
bls(2-Chloroethoxy)methane
bls(2-Chloroethyl) ether
bis(2-Chlorolsopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dlbenz(a,h)anthracene
3,3'·0Ichlorobenzidine
2,4-Dichlorophenol
Dlethylphthalate
2,4-Dimethylphenol
Dlmethylphthalate
Di-n-butylphthalate
4,6-Dlnllro-2-methylphenol
2,4-Dlnllrophenol
2,4•Dinitrotoluene
2,6•Dinitrotoluene
Di-n-octylphthalate
bis(2-Elhylhexyl)phlhalate
Fluoranthene
Fluorene
Hexachloro-1,3•butadiene
Hexachlorobenzene
Date: 04/20/2009 04:02 PM
Lab ID: 9239316005 Collecled: 03/04/09 15:00 Received: 03/05/0915:30 Malrix: Water
Results Units
Analytical Method: EPA601/602
ND ug/L
112 %
Analytical Method: MADEP VPH
ND ug/L
ND ug/L
ND ug/L
98 %
106 %
Report Limll DF Prepared Analyzed CAS No. _____ ;._ ___ .:...,_ ____ _
1.0
65-137
100
100
100
70-130
70-130
03/17/09 00:55 95-47-6
03/17/09 00:55 625-98-9
03/11/09 18:29
03/11/09 18:29
03/11/09 18:29
03/11/09 18:29
03/11/09 18:29
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
12.3
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
12.3
6.2
6.2
24.7
61.7
6.2
6.2
6.2
6.2
6.2
6.2
6.2
6.2
03/07/0910:45 03/10/09 15:16 83-32-9
03/07/0910:45 03/10/09 15:16 208-96-8
03/07/0910:45 03/10/0915:16 120-12-7
03/07/0910:45 03/10/09 15:16 56-55-3
03/07/0910:45 03/10/09 15:16 50-32-8
03/07/09 10:45 03/10/09 15:16 205-99-2
03/07/0910:45 03/10/09 15:16 191-24-2
03/07/0910:45 03/10/09 15:16 207-08-9
03/07/0910:45 03/10/09 15:16 101-55-3
03/07/0910:45 03/10/0915:16 85-68-7
03/07/0910:45 03/10/09 15:16 59-50-7
03/07/0910:45 03/10/0915:16 111-91-1
03/07/09 10:45 03/10/09 15:16 111-44-4
03/07/0910:45 03/10/0915:16 108-60-1
03/07/09 10:45 03/10/09 15:16 91-58-7
03/07/09 10:45 03/10/09 15:16 95-57-8
03/07/0910:45 03/10/0915:16 7005-72-3
03/07/09 10:45 03/10/09 15:16 218-01-9
03/07/09 10:45 03/10/09 15:16 53-70-3
03/07/09 10:45 03/10/0915:16 91-94-1
03/07/0910:45 03/10/0915:16 120-83-2
03/07/0910:45 03/10/0915:16 84-66-2
03/07/09 10:45 03/10/0915:16 105-67-9
03/07/09 10:45 03/10/0915:16 131-11-3
03/07/0910:45 03/10/0915:16 84-74-2
03/07/09 10:45 03/10/09 15:16 534-52-1
03/07/09 10:45 03/10/0915:16 51-28-5
03/07/0910:45 03/10/0915:16 121-14-2
03/07/09 10:45 03/10/09 15:16 606-20-2
03/07/09 10:45 03/10/0915:16 117-84-0
03/07/09 10:45 03/10/0915:16 117-81-7
03/07/09 10:45 03/10/0915:16 206-44-0
03/07/09 10:45 03/10/0915:16 86-73-7
03/07/09 10:45 03/10/0915:16 87-68-3
03/07/09 10:45 03/10/0915:16 118-74-1
Qual
REPORT OF LABORATORY ANALYSIS Page 20 of 35
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
;Q}s~
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7178
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875•9092
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: MW-5
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone .
Naphthalene
Nitrobenzene
2-Nitrophenol
4•Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-dl-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenot
Nltrobenzene-d5 (S)
2-Fluoroblphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-TMbromophenol (S)
Date: 04/20/2009 04:02 PM
LabtD: 9239316005 Collected: 03/04/0915:00 Received: 03/05/0915:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L 12.3 03/0710910:45
ND ug/L 6.2 03/07/09 10:45
ND ug/L 6.2 03/07/0910:45
ND ug/L 12.3 03/07/09 10:45
ND ug/L 6.2 03/0710910:45
ND ug/L 6.2 03/07/0910:45
ND ug/L 6.2 03/07/0910:45
ND ug/L 61.7 03/0710910:45
ND ug/L 6.2 03/0710910:45
ND ug/L 6.2 03/0710910:45
ND ug/L 12.3 03/0710910:45
ND ug/L 30.9 03/07/09 10:45
ND ug/L 6.2 03/0710910:45
ND ug/L 6.2 03/07109 10:45
ND ug/L 6.2 03/07109 10:45
ND ug/L 6.2 03/0710910:45
ND ug/L 12.3 03/07109 10:45
91 % 10-120 03/07/09 10:45
74 % 15-120 03/07109 10:45
102 % 11-131 0310710910:45
11 % 10-120 03/07109 10:45
11 % 10-120 03/07109 10:45
42 % 10-137 03107109 10:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
g~)\\
Analyzed CAS No. Qua!
03/1010915:16 77-47-4
03110/09 15:16 67-72-1
03/10/09 15:16 193-39-5
03/10/09 15:16 78-59-1
03/10/0915:16 91-20-3
03/10/09 15:16 98-95-3
03/10/09 15: 16 88-75-5
03/1010915:16 100-02-7
03110/09 15:16 62-75-9
03/10/09 15:16 621-64-7
03/10/09 15: 16 86-30-6
03/10/0915:16 87-86-5
03110/09 15:16 85-01-8
03/10/0915:16 108-95-2
03/1010915:16 129-00-0
03110/09 15:16 120-82-1
03/10/09 15: 16 88-06-2
03/10/0915:16 4165-60-0
03110109 15:16 321-60-8
03110/0915:16 1718-51-0
03/10/0915:16 13127-88-3
03110/09 15:16 367-12-4
03/10/09 15:16 118-79-6
Page 21 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: T-1 LablD: 9239316006 Collected: 03/04/0914:40 Received: 03/05/0915:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CASNo. Qual
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18) ND ug/L 133 03/06/09 12:30 03/12/09 06:04
Aliphatic (C19-C36) ND ug/L 133 03/06/0912:30 03/12/09 06:04
Aromatic (C11-C22) ND ug/L 133 03/06/09 12 :30 03/12/09 06:04
Non.atriacontane ($) 85 % 40-140 03/06/0912:30 03/12/09 06:04 7194-86-7
o-Terphenyl (S) 102 % 40-140 03/06/0912:30 03/12/09 06:04 84-15-1
2-Fluorobiphenyl ($) 112 % 40-140 03/06/09 12:30 03/12/09 06:04 321-60-8
2-Bromonaphthalene (S) 113 % 40-140 03/06/0912:30 03/12/09 06:04 580-13-2
601/602 Volatiles Analytical Method: EPA601/602
Benzene 20.7 ug/L 1.0 03/19/09 22:45 71-43-2 HS
Bromodichloromethane ND u9/L 10.0 10 03/19/09 22:45 75-27-4
Bromoform ND u9/L 10.0 10 03/19/09 22:45 75-25-2
Bromomethane ND u9/L 10.0 10 03/19/09 22:45 74-83-9
Carbon tetrachloride ND u9/L 10.0 10 03/19/09 22:45 56-23-5
Chlorobenzene ND u9/L 10.0 10 03/19/09 22:45 108-90-7
Chloroethane ND ug/L 10.0 10 03/19/09 22:45 75-00-3
Chloroform ND ug/L 10.0 10 03/19/09 22:45 67-86-3
Chloromethane ND u9/L 20.0 10 03/19/09 22:45 74-87-3
Dlbromochloromethane ND ug/L 10.0 10 03/19/09 22:45 124-48-1
1,2-Dlbromoethane (EDS) ND ug/L 10.0 10 03/19/09 22:45 106-93-4
1,2-Dlchlorobenzene ND ug/L 10.0 10 03/19/09 22:45 95-50-1
1,3-Dichlorobenzene ND ug/L 10.0 10 03/19/09 22:45 541-73-1
1,4-Dlchlorobenzene ND u9/L 10.0 10 03/19/09 22:45 106-46-7
Dlchlorodifluoromethane ND u9/L 10.0 10 03/19/09 22:45 75-71-8
1, 1-Dichloroethane ND ug/L 10.0 10 03/19/09 22:45 75-34-3 HS
1,2-Dlchloroethane 25.7 ug/L 10.0 10 03/19/09 22:45 107-06-2
1, 1-Dichloroethene ND ug/L 10.0 10 03/19/09 22:45 75-35-4
cis-1,2-Dlchloroethene ND ug/L 10.0 10 03/19/09 22:45 156-59-2
trans-1,2-Dlchloroethene ND ug/L 10.0 10 03/19/09 22:45 156-60-5
1,2-Dichloropropane ND ug/L 10.0 10 03/19/09 22:45 78-87-5
cis-1,3-Dichloropropene ND u9/L 10.0 10 03/19/09 22:45 10061-01-5
trans-1,3-Dlchloropropene ND ug/L 10.0 10 03/19/09 22:45 10061-02-6
Dlisopropyl ether ND ug/L 1.0 03/19/09 22:45 108-20-3
Ethylbenzene ND ug/L 1.0 03/19/09 22:45 100-41-4
Methylene Chloride ND u9/L 20.0 10 03/19/09 22:45 75-09-2
Methyl-tert-bulyl ether ND u9/L 1.0 03/19/09 22:45 1634-04-4
Naphthalene 3.1 ug/L 2.0 03/19/09 22:45 91-20-3
1, 1,2,2-Tetrachloroethane ND ug/L 10.0 10 03/19/09 22:45 79-34-5
Tetrachloroethene ND u9/L 10.0 10 03/19/09 22:45 127-18-4
Toluene ND u9/L 1.0 03/19/09 22:45 108-88-3
1, 1, 1-Trlchloroethane ND ug/L 10.0 10 03/19/09 22:45 71-55-6
1, 1,2-Trlchloroethane ND ug/L 10.0 10 03/19/09 22:45 79-00-5
Trichloroethene ND ug/L 10.0 10 03/19/09 22:45 79-01-6
Trichlorofluoromethane ND ug/L 10.0 10 03/19/09 22:45 75-69-4
Vinyl chloride ND u9/L 10.0 10 03/19/09 22:45 75-01-4
Xylene (Total) ND ug/L 2.0 03/19/09 22:45 1330-20-7
m&p-Xylene ND ug/L 2.0 03/19/09 22:45 1330-20-7
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 22 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
lH2r~\
Pace Analytlcal Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
Sample: T-1
Parameters
601/602 Volallles
a-Xylene
1-Chloro-3-fluorobenzene (S)
VPH NC Water
Aliphatic (COS-COB)
Aliphatic (C09-C12)
Aromatic (C09-C10)
2,5-Dibromotoluene (PID)(S)
2,5-Dibromotoluene (FID)(S)
625 MSSV
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h ,l)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bls(2-Chlorolsopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a,h)anthracene
3,3'-Dlchlorobenzidine
2,4-Dichlorophenol
Dlethylphthalate
2,4-Dlmethylphenol
Dimethylphthalate
Dl-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dlnltrotoluene
2,6-Dlnitrotoluene
Dl-n-octylphthalate
bls(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadlene
Hexachlorobenzene
Date: 04/20/2009 04:02 PM
Lab ID: 9239316008 Collected: 03/04/0914:40 Received: 03/05/0915:30 Matrix: Water
Results Units
Analytical Method: EPA 601/602
ND ug/L
112 %
Analytical Method: MADEP VPH
320 ug/L
ND ug/L
ND ug/L
100 %
106 %
Report Limit DF
1.0
65-137 10
100
100
100
70-130
70-130
Prepared Analyzed CAS No.
03/19109 22:45 95-47-6
03119109 22:45 625-98-9
03/11109 18:58
03/11109 18:58
03/11109 18:58
03111/0918:58
03/11109 18:58
Analytical Method: EPA 625 Preparation Method: EPA 625
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
5.7
11,5
5,7
5.7
5.7
5.7
5,7
5.7
5.7
5,7
5.7
5.7
11,5
5,7
5.7
23.0
57.5
5,7
5.7
5.7
5.7
5.7
5.7
5,7
5,7
0310710910:45 03/10109 15:38 83-32-9
03/07/0910:45 0311010915:38 208-96-8
03107/0910:45 03/10/09 15:38 120-12-7
03/0710910:45 03/10/0915:38 56-55-3
03107/0910:45 03110/0915:38 50-32-8
03/0710910:45 03/10/09 15:38 205-99-2
03/07/0910:45 03/10109 15:38 191-24-2
03/0710910:45 03/10109 15:38 207-08-9
03/0710910:45 03/1010915:38 101-55-3
03/0710910:45 03/10109 15:38 85-68-7
03/07/0910:45 03/10/0915:38 59-50-7
03/0710910:45 03/10109 15:38 111-91-1
03/07/0910:45 03110/09 15:38 111-44-4
03/0710910:45 03/10/09 15:38 108-60-1
03/0710910:45 03/10109 15:38 91-58-7
03/0710910:45 03110/09 15:38 95-57-8
0310710910:45 03/10109 15:38 7005-72-3
03/0710910:45 03110/0915:38 218-01-9
03/0710910:45 03110109 15:38 53-70-3
03107/0910:45 03/10/0915:38 91-94-1
03/07109 10:45 03/10/09 15:38 120-83-2
03/0710910:45 03/10/0915:38 84-66-2
03107109 10:45 03/10/09 15:38 105-67-9
03/07/0910:45 03/10/0915:38 131-11-3
03/07/09 10:45 03/10/09 15:38 84-74-2
03/07/09 10:45 03/10/0915:38 534-52-1
0310710910:45 03/10/0915:38 51-28-5
03/07/09 10:45 03/10/0915:38 121-14-2
03/07/09 10:45 03/10/09 15:38 606-20-2
03/07/09 10:45 03/10/09 15:38 117-84-0
03/07/0910:45 03/10/0915:38 117-81-7
03/07/09 10:45 03/10/09 15:38 206-44-0
03/07109 10:45 03/10/0915:38 86-73-7
03/07/09 10:45 03/10/09 15:38 87-68-3
03/07/09 10:45 03/10/0915:38 118-74-1
Qual
REPORT OF LABORATORY ANALYSIS Page 23 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Sample: T-1
Parameters
625MSSV
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
Naphthalene
Nitrobenzene
2-Nltrophenol
4-Nltrophenol
N-Nttrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trlchlorobenzene
2,4,6--Trlchlorophenol
Nltrobenzene-d5 (S)
2-Fluoroblphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date: 04/20/2009 04:02 PM
Lab ID: 9239316006 Collected: 03/04/09 14:40 Received: 03/05/0915:30 Matrix: Water
Results Units Report limit DF Prepared
Analytical Method: EPA625 Preparation Method: EPA625
ND ug/L 11.5 03/07/09 10:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 11.5 03/07/09 10:45
14.4 ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 57.5 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 11.5 03/07/0910:45
ND ug/L 28.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 5.7 03/07/0910:45
ND ug/L 11.5 03/07/0910:45
85 % 10-120 03/07/0910:45
72 % 15-120 03/07/0910:45
104 % 11-131 03/07/0910:45
35 % 10-120 03/07/0910:45
52 % 10-120 03/07/09 10:45
82 % 10-137 03/07/09 10:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
.. ~ .. ~ ,,. ~~:.~~+
c. ''>.. , .... ~, C\
Analyzed CAS No. Qual
03/10/09 15:38 77-47-4
03/10/09 15:38 67-72-1
03/10/09 15:38 193-39-5
03/10/09 15:38 78-59-1
03/10/09 15:38 91-20-3
03/10/09 15:38 98-95-3
03/10/0915:38 88-75-5
03/10/0915:38 100-02-7
03/10/0915:38 62-75-9
03/10/0915:38 621-64-7
03/10/09 15:38 86-30-6
03/10/09 15:38 87-86-5
03/10/09 15:38 85-01-8
03/10/09 15:38 108-95-2
03/10/09 15:38 129-00-0
03/10/09 15:38 120-82-1
03/10/09 15:38 88-06-2
03/10/09 15:38 4165-60-0
03/10/09 15:38 321-60-8
03/10/0915:38 1718-51-0
03/10/0915:38 13127-88-3
03/10/0915:38 367-12-4
03/10/0915:38 118-79-6
Page 24 of 35
Pace Analytical Services, Inc.
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Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
QC Batch: OEXT/6095 Analysis Method: EPA 625
QC Batch Method: EPA625 Analysis Description: 625 MSS
Associated Lab Samples: 9239316001, 9239316002, 9239316003, 9239316004, 9239316005, 9239316006
METHOD BLANK: 246688 Matrix: water
Associated Lab Samples: 9239316001, 9239316002,9239316003,9239316004, 9239316005,9239316006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 03109109 16:27
2,4,6-Trichlorophenol ug/L ND 10.0 03/09109 16:27
2,4-Dichlorophenol ug/L ND 5.0 03/0910916:27
2,4-Dlmethylphenol ug/L ND 10.0 03/0910916:27
2,4-Dlnltrophenol ug/L ND 50.0 03/09/0916:27
2,4-Dinltrotoluene Ug/L ND 5.0 03/0910916:27
2,6-Dinltrotoluene ug/L ND 5.0 03/0910916:27
2-Chloronaphthalene ug/L ND 5.0 03/09/0916:27
2-Chlorophenol ug/L ND 5.0 03/09/0916:27
2-Nltrophenol ug/L ND 5.0 03/0910916:27
3,3'-Dlchlorobenzidine ug/L ND 5.0 0310910916:27
4,6-Dinitro-2-methylphenol ug/L ND 20.0 0310910916:27
4-Bromophenylphenyl ether ug/L ND 5.0 03/09109 16:27
4-Chloro-3-methylphenol ug/L ND 5.0 0310910916:27
4-Chlorophenylphenyl ether ug/L ND 5.0 0310910916:27
4-Nitrophenol ug/L ND 50.0 03/09/0916:27
Acenaphthene ug/L ND 5.0 03/09/0916:27
Acenaphthylene ug/L ND 5.0 03109109 16:27
Anthracene ug/L ND 5.0 03/09/0916:27
Benzo(a)anthracene ug/L ND 5.0 03/09/0916:27
Benzo(a)pyrene ug/L ND 5.0 03109109 16:27
Benzo(b )fluoranthene ug/L ND 5.0 03109/0916:27
Benzo(g,h,l)perylene ug/L ND 5.0 03/09/0916:27
Benzo(k)fluoranthene ug/L ND 5.0 03/09/0916:27
bls(2-Chloroethoxy)methane ug/L ND 10.0 03109/0916:27
bls(2-Chioroethyl) ether ug/L ND 5.0 03/09/0916:27
bis(2-Chloroisopropyl) ether ug/L ND 5.0 03/09/0916:27
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 0310910916:27
Butylbenzylphthaiate ug/L ND 5.0 03109/0916:27
Chrysene ug/L ND 5.0 03109/0916:27
Di-n-butylphthalate ug/L ND 5.0 03/0910916:27
Di-n-octylphthaiate ug/L ND 5.0 0310910916:27
Dlbenz(a,h)anthracene ug/L ND 5.0 03/09/0916:27
Dlethylphthalate ug/L ND 5.0 03/09/0916:27
Dimethylphthalate ug/L ND 5.0 03/09/0916:27
Fluoranthene ug/L ND 5.0 03109109 16:27
Fluorene ug/L ND 5.0 03109109 16:27
Hexachloro-1,3-butadlene ug/L ND 5.0 0310910916:27
Hexachlorobenzene ug/L ND 5.0 03109109 16:27
Hexachlorocyclopentadiene ug/L ND 10.0 03109109 16:27
Hexachloroethane ug/L ND 5.0 03109109 16:27
lndeno(1,2,3-cd)pyrene ug/L ND 5.0 03109109 16:27
lsophorone ug/L ND 10.0 03/0910916:27
Date: 04/2012009 04:02 PM REPORT OF LABORATORY ANALYSIS
This report shell not be reproduced, except In full,
without the written consent of Pace Analytical SeNices, Inc ..
~~Q~~ if -J\
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 35
Project: TEXACO FOOD MART #21001289
Pace Project No.: 9239316
METHOD BLANK: 246688
Pace Analytical Service,, Inc.
2225 Riverside Dr.
Ashevllle, NC 28804
[phone]
QUALITY CONTROL DATA
Matrix: Water
Associated Lab Samples: 9239316001, 9239316002,9239316003,9239316004,9239316005,9239316006
Blank Reporting
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Parameter Units Result Limit Analyzed Qualifiers
N-Nitroso-di-n-propylamlne ug/L
N-Nltrosodimethylamine ug/L
N-Nltrosodiphenylamine ug/L
Naphthalene ug/L
Nitrobenzene ug/L
Pentachlorophenol ug/L
Phenanthrene ug/L
Phenol ug/L
Pyrene ug/L
2,4,6-Tribromophenol (S) %
2-Fluoroblphenyl (S) %
2-Fluorophenol (S) %
Nltrobenzene-d5 (S) %
Phenol-d6 (S) %
Terphenyl-d14 (S) %
LABORATORY CONTROL SAMPLE: 246689
Parameter
1,2,4-Trlchlorobenzene
2,4,6-Trichlorophenol
2,4-Dlchlorophenol
2,4-Dlmethylphenol
2,4-Dlnltrophenol
2,4-Dlnltrotoluene
2,6-Dlnltrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Nltrophenol
3,3'-Dichlorobenzldlne
4,6-Dinltro-2-methylphenol
4-Bromophenylphenyl ether
4-Chloro-3-methylphenol
4-Chlorophenylphenyl ether
4-Nltrophenol
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g,h,l)perylene
Benzo(k)fluoranthene
bls(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Date: 04/20/2009 04:02 PM
ug/L
ug/L
ug/L
ug/L
Ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Units
Spike
Cone.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
ND
ND
ND
ND
ND
ND
ND
ND
ND
82
71
54
88
38
97
5.0
5.0
10.0
5.0
5.0
25.0
5.0
5.0
5.0
10-137
LCS
Result
15-120
10-120
10-120
10-120
11-131
26.7
41.5
34.9
35.5
44.2J
38.2
35.5
37.5
33.3
37.0
24.4
45.0
37.5
39.5
41.2
24.8J
40.4
44.7
41.2
42.7
45.4
47.1
34.9
44.3
40.7
45.1
03/09/09 16:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
03/09/0916:27
LCS
%Rec
% Rec
Limits
53
83
70
71
88
76
71
75
67
74
49
90
75
79
82
50
81
89
82
85
91
94
70
89
81
90
44-142
37-144
1-191
32-119
1-181
39-139
50-158
60-118
23-134
29-182
1-262
1-181
53-127
22-147
25-158
1-132
47-145
33-145
1-166
33-143
17-163
24-159
1-219
11-162
33-184
12-158
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~
.,~.,,~-~.cca,_0~+., • • ii \
Qualifiers
Page 26 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Ashevllle, NC 28804
[phone]
Project: TEXACO FOOD MART #2 1001289
Pace Project No.: 9239316
LABORATORY CONTROL SAMPLE:
Parameter
bls(2-Chlorolsopropyl) ether
bls(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dl-n-butylphthalate
Dl-n-octylphlhalate
Dlbenz(a,h)anthracene
Dlethylphthalate
Dimelhylphthalale
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane·
lndeno(1,2,3-cd)pyrene
lsophorone
N-Nitroso-dl-n-propylamine
N-Nitrosodimethylamine
N-Nltrosodlphenylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6-Tribromophenol (S)
2-Fluoroblphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-dB (S)
Terphenyl-d14 (S)
Date: 04/20/2009 04:02 PM
246689
Spike LCS LCS
Units Cone. Result %Rec
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
%
%
50 37.1 74
50 50.2 100
50 50.7 101
50 40.0 80
50 50.6 101
50 49.7 99
50 40.6 81
50 42.3 85
50 44.0 88
50 40.8 82
50 42.7 85
50 23.5 47
50 31.0 62
50 35.9 72
50 28.6 57
50 39.4 79
50 48.9 98
50 47.6 95
50 33.8 68
50 39.1 78
50 35.5 71
50 33.6 67
50 42.9 86
50 43.7 87
50 19.6 39
50 40.0 80
71
73
43
81
30
75
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
fQ~~-
% Rec
Limits
36-166
8-158
1-152
17-168
1-118
4-146
1-227
1-114
1-112
26-137
59-121
24-116
1-152
25-150
40-113
1-171
21-196
1-230
25-150
25-150
21-133
35-180
14-176
54-120
5-112
52-115
10-137
15-120
10-120
10-120
10-120
11-131
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 27 of 35
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239318
QC Batch: OEXT/6080
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: MADEP EPH
QC Batch Method: MADEP EPH Analysis Description: MADEP EPH NC water
Associated Lab Samples: 9239316001, 9239316002, 9239316003, 9239316004, 9239316005, 9239316006
METHOD BLANK: 245924 Matrix: Water
Associated Lab Samples: 9239316001,9239316002,9239316003,9239316004, 9239316005, 9239316006
Blank Reporting
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Parameter Units Result Limit Analyzed Qualifiers
Aliphatic (C09-C18) ug/L
Aliphatic (C 19-C36) ug/L
Aromatic (C11-C22) ug/L
2-Bromonaphthalene (S) %
2-Fluoroblphenyl (S) %
Nonatrlacontane (S) %
o-Terphenyl (S) %
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
Aliphatic (C09-C18) ug/L
Aliphatic (C19-C36) ug/L
Aromatic (C11-C22) ug/L
2-Bromonaphthalene (S) %
2-Fluoroblphenyl (S) %
Nonatrlacontane (S) %
o-Terphenyl (S) %
Date: 04/20/2009 04:02 PM
ND 100 03/11/0922:55
ND 100 03111/09 22:55
ND 100 03111/09 22:55
90 40-140 03/11/09 22:55
88 40-140 03/11/09 22:55
95 40-140 03/11/0922:55
85 40-140 03/11/0922:55
245925 245926
Units
Spike LCS LCSD LCS LCSD
Cone. Result Result % Rec %Rec
300 159 138 53
400 262 264 66
850 673 673 79
92
89
49
91
REPORT OF LABORATORY ANALYSIS
This report shall not ba reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
46
66
79
97
93
56
85
%Rec Max
Limits RPD RPO Qualifiers
40-140 14 50
40-140 .7 50
40-140 .02 50
40-140
40-140
40-140
40-140
Page 28 of 35
Pace Analytical Servlcea, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
QC Batch: GCV/2992 Analysis Method: EPA601/602
QC Batch Method: EPA 601/602 Analysis Description: 601/602 GCV water
Associated Lab Samples: 9239316001, 9239316002, 9239316003, 9239316004, 9239316005, 9239316006
METHOD BLANK: 250281
Associated Lab Samples:
Parameter
1, 1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethalle
1,1,2-Trlchloroethane
1, 1-Dichloroethane
1, 1-Dlchloroethene
1,2-Dlbromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dlchloroethane
1,2-Dichloropropane
1,3-Dlchlorobenzene
1,4-Dlchlorobenzene
Benzene
Bromodichloromethane
Bromofonn
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dtchloropropene
Dibromochloromethane
Dichlorodifluoromethane
Dllsopropyl ether
Ethylbenzene
m&p-Xytene
Methyl-tart-butyl ether
Methylene Chloride
Naphthalene
a-Xylene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dlchloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylene (Total)
1-Chloro-3-fluorobenzene (S)
Date: 04/2012009 04:02 PM
Matrix: Water
9239316001,9239316002,9239316003,9239316004, 9239316005,9239316006
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
Blank Reporting
Units Result Umit Analyzed
ND 1.0 03/16/0911 :41
ND 1.0 03/1610911 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/09 11 :42
ND 1.0 03/16/0911 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/0911:41
ND 1.0 03/16/0911 :41
ND 1.0 03/16/0911 :41
ND 2.0 03/16/0911:41
ND 1.0 03/16/0911:41
ND 1.0 03/16/0911 :41
ND 1.0 03116/0911:41
ND 1.0 03/16/0911:41
ND 1.0 03/16/09 11 :42
ND 1.0 03/16/0911 :42
ND 2.0 03/16/0911:42
ND 1.0 03/16/0911:42
ND 2.0 03/16/0911 :41
ND 2.0 03/16/0911:42
ND 1.0 03/16/09 11 :42
ND 1.0 03/16/0911:41
ND 1.0 03/16/09 11 :42
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911:41
ND 1.0 03/16/0911:41
ND 1.0 03/16/09 11 :41
ND 1.0 03/16/0911:41
ND 2.0 03/16/0911:42
106 65-137 03/16/0911:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Qualifiers
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 35
r~-Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
{828)254-7176 [phone]
QUALITY CONTROL DATA
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
LABORATORY CONTROL SAMPLE: 250282
Spike LCS LCS % Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
1,1, 1-T~chloroethane ug/L 20 16.3 81 41-138
1, 1,2,2-Tetrachloroethane ug/L 20 22.5 112 8-184 1, 1,2-Trichloroethane ug/L 20 18.9 95 39-136
1, 1-Dichloroethane ug/L 20 19.3 97 47-132 1, 1-Dlchloroethene ug/L 20 21.1 106 28-167
1,2-Dlbromoethane (EDB) ug/L 20 22.4 112 50-150 1,2-Dlchtorobenzene ug/L 20 19.5 97 1-208
1,2-Dlchloroethane ug/L 20 17.2 86 51-147
1,2-Dichloropropane ug/L 20 18.8 94 44-156
1,3-Dichlorobenzene ug/L 20 20.9 105 7-187
1,4-Dichlorobenzene ug/L 20 20.2 101 42-143 Benzene ug/L 20 20.9 104 39-150
Bromodlchloromethane ug/L 20 19.0 95 42-172 Bromoform ug/L 20 21.9 110 13-159
Bromomethane ug/L 20 26.7 134 1-144 Carbon tetrachloride ug/L 20 19.8 99 43-143 Chlorobenzene ug/L 20 18.8 94 38-150
Chloroethane ug/L 20 25.7 129 46-137 Chloroform ug/L 20 19.7 99 49-133
Chloromethane ug/L 20 26.1 130 1-193 cis-1,2-Dlchloroethene ug/L 20 19.3 96 38-155
cis-1,3-Dichloropropene ug/L 20 21.3 107 22-178 Dibromochloromethane ug/L 20 19.0 95 24-191
Dlchlorodifiuoromethane ug/L 20 24.4 122 48-157
Dllsopropyl ether ug/L 20 20,1 100 89-108
Ethylbenzene ug/L 20 21.3 107 32-160 m&p-Xylene ug/L 40 39.6 99 82-115
Methyl-tert-butyl ether ug/L 20 20,6 103 88-110
Methylene Chloride ug/L 20 22,0 110 25-162
Naphthalene ug/L 20 20.2 101 50-150
a-Xylene ug/L 20 21.9 109 91-110
Tetrachloroethene ug/L 20 19,6 98 26-162 Toluene ug/L 20 21,6 108 46-148 trans-1,2-Dlchloroethene ug/L 20 21.5 107 38-155
trans-1, 3-Dichloropropene ug/L 20 22.4 112 22-178 Trlchloroethene ug/L 20 21.0 105 35-146
Trlchlorofiuoromethane ug/L 20 23.6 118 21-156 Vinyl chlonde ug/L 20 25.0 125 28-163
Xylene (Total) ug/L 60 61.5 103 50-150 1-Chloro-3-fluorobenzene (S} % 103 65-137
MATRIX SPIKE SAMPLE: 250285
9239715001 Spike MS MS %Rec Parameter Units Result Cone. Result %Rec Limits Qualifiers
1, 1, 1~Trlchloroethane ug/L ND 20 19,9 100 41-138 1, 1,2,2-Tetrachloroethane ug/L ND 20 20.1 101 8-184 1, 1,2-Trichloroethane ug/L ND 20 20.1 100 39-136
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS Page 30 of 35
This report shall not be reproduced, except in futt,
without the written consent of Pace Analytical Services, Inc ..
.?~~~~ ff/ Ct
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
MATRIX SPIKE SAMPLE: 250285
9239715001 Spike MS MS
Parameter Units Result Cone. Result % Rec
1, 1-Dichloroethane ug/L ND 20 19.3 96
1,1-Dichloroethene ug/L ND 20 20.9 104
1,2-Dibromoethane (EDB) ug/L ND 20 21.5 108
1,2-Dichlorobenzene ug/L ND 20 19.2 96
1,2-Dichloroethane ug/L ND 20 20.7 103
1,2-Dichloropropane ug/L ND 20 19.7 98
1,3-Dlchlorobenzene ug/L ND 20 20.0 100
1,4-Dichlorobenzene ug/L ND 20 19.0 95
Benzene ug/L ND 20 21.3 107
Bromodichloromethane ug/L ND 20 20.9 104
Bromoforrn ug/L ND 20 20.4 102
Bromomethane ug/L ND 20 20.7 103
Carbon tetrachloride ug/L ND 20 20.9 104
Chlorobenzene ug/L ND 20 18.3 91
Chloroethane ug/L ND 20 20.4 102
Chlorofonm Ug/L ND 20 21.1 106
Chloromethane ug/L ND 20 25.2 126
cis-1,2-Dichloroethene ug/L ND 20 19.0 95
cis-1,3-Dichloropropene ug/L ND 20 19.9 100
Dlbromochloromethane ug/L ND 20 20.7 103
Dlchlorodifluoromethane ug/L ND 20 19.7 99
Dllsopropyl ether ug/L ND 20 18.9 95
Ethyl benzene ug/L ND 20 22.1 110
m&p-Xylene ug/L ND 40 45.8 114
Methyl-tert-butyl ether ug/L ND 20 19.0 95
Methylene Chloride ug/L ND 20 17.2 86
Naphthalene ug/L ND 20 20.0 100
a-Xylene ug/L ND 20 22.9 114
Tetrachloroethene ug/L ND 20 18.7 93
Toluene ug/L ND 20 22.2 111
trans-1,2-Dichloroethene ug/L ND 20 20.6 103
trans-1,3-Dlchloropropene ug/L ND 20 18.7 94
Trichloroethene ug/L ND 20 20.1 100
Trlchlorofluoromethane ug/L ND 20 21.5 108
Vinyl chloride ug/L ND 20 22.0 110
1-Chloro-3-fluorobenzene (S) % 105
SAMPLE DUPLICATE: 250284
9239316002 Dup
Parameter Units Result Result RPD Qualifiers
1, 1, 1-Trichloroethane ug/L ND ND
1, 1,2,2-Tetrachloroethane ug/L ND ND
1, 1,2-Tnchloroethane ug/L ND ND
1, 1-Dichloroethane ug/L ND ND HS
1.1-Dichloroethene ug/L ND ND
1,2-Dibromoethane (EDB) ug/L ND ND
1,2-Dlchlorobenzene ug/L ND ND
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace An&lytical Services, Inc ..
Q~~~ it C\~
Pace Analytlcal Services, Inc.
9800 Kincey Ave. Suite 100
Huntersv!He, NC 28078
[phone]
%Rec
Limits Qualifiers
47-132
28-167
50-150
1-208
51-147
44-156
7-187
42-143
39-150
42-172
13-159
1-144
43-143
38-150
46-137
49-133
1-193
38-155
22-178
24-191
48-157
89-108
32-160
82-115
88-110
25-162
50-150
91-110 MO
26-162
46-148
38-155
22-178
35-146
21-156
28-163
65-137
Page 31 of 35
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
SAMPLE DUPLICATE: 250284
Parameter
1,2-Dichloroethane ug/L
1.2-Dichloropropane ug/L
1,3-0lchlorobenzene ug/L
1,4-Dlchlorobenzene ug/L
Benzene ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cls-1,2-Dlchloroethene ug/L
cis-1,3-0ichloropropene ug/L
Dibromochloromethane ug/L
Dlchlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
Naphthalene ug/L
a-Xylene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dlchloroethene ug/L
trans-1,3-Dlchloropropene ug/L
Trlchloroethene ug/L
Trichlorofluoromethane ug/L
Vinyl chloride ug/L
Xylene (Total) ug/L
1-Chloro-3-fluorobenzene (S) %
Date: 04/20/2009 04:02 PM
9239316002 Dup
Units ResuJt Result RPO
ND ND
ND ND
ND ND
ND ND
11700 12000
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
2250 2290
9890 10100
3600 3580
ND ND
ND ND
4660 4710
ND ND
27200 27900
ND ND
ND ND
ND ND
ND ND
ND ND
14500 14900
115 115
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
~~:ik~~ ~;,nema~
Qualifiers
3 HS
2
3
.7
3
2
.5
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 35
Project: TEXACO FOOD MART #21001289
Pace Project No.: 9239316
QC Batch: GCV/2972
Pace Analytical Services, Inc.
2225 Riverside Dr.
Ashev'ille, NC 28804
{828)254-7176
QUALITY CONTROL DATA
Analysis Method: MADEPVPH
QC Batch Method: MADEP VPH Analysis Description: VPH NC Water
Associated Lab Samples: 9239316001, 9239316002, 9239316003, 9239316004, 9239316005, 9239316006
METHOD BLANK: 247852 Matrix: Water
Associated Lab Samples: 9239316001,9239316002,9239316003,9239316004,9239316005, 9239316006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aliphatic (C05-C08) ug/L
Aliphatic (C09-C12) ug/L
Aromatic (C09-C10) ug/L
2,5-Dibromotoluene (FID)(S) %
2,5-Dlbromotoluene (PID)(S) %
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
Aliphatic (C05-C08) ug/L
Aliphatic (C09-C12) ug/L
Aromatic (C09-C10) ug/L
2,5-Dibromotoluene (FID)(S) %
2,5-Dibromotoluene (PID)(S) %
Date: 04/20/2009 04:02 PM
ND 100 03/11/0912:05
ND 100 03/11/0912:05
ND 100 03/11/0912:05
105 70-130 03/11/0912:05
104 70-130 03/11/0912:05
247853 247854
Units
Spike LCS LCSD LCS LCSD
Cone. Result Result % Rec %Rec
300 304 312 101 104
300 332 340 111 113
100 106 109 106 109
95 101
97 102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
1M ~-f•o~
?~\
%Rec
Limits RPO
70-130
30-130
70-130
70-130
70-130
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Max
RPO Qualifiers
3 25
2 25
3 25
Page 33 of 35
Pace Analytical Servlcet, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: TEXACO FOOO MART #2 1001289
Pace Project No.: 9239316
DEFINITIONS
DF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes ln sample preparation, dilution of
the sample aliquot, or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate% recovery and RPO values.
LCS(D) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPD -Relative Percent Difference
NC -Not Calculable.
Pace Analytical Is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U -Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
1g
2g
H5
MO
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference resulting in
elevated reporting limits.
Surrogate recovery outside laboratory control limits due to matrix interferences.
Reanalysis conducted In excess of EPA method holding time. Results confirm original analysis performed ln hold time.
Matrlx spike recovery was outside laboratory control limits.
Date: 04/20/2009 04:02 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical_ Services, Inc ..
"~~\
Page 34 0135
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: TEXACO FOOD MART#21001289
Pace Project No.: 9239316
Lab ID Sample ID
9239316001 MW-1
9239316002 MW-2
9239316003 MW-3
9239316004 MW-4
9239316005 MW-5
9239316006 T-1
9239316001 MW-1
9239316002 MW-2
9239316003 MW-3
9239316004 MW-4
9239316005 MW-5
9239316006 T-1
9239316001 MW-1
9239316002 MW-2
9239316003 MW-3
9239316004 MW-4
9239316005 MW-5
9239316006 T-1
9239316001 MW-1
9239316002 MW-2
9239316003 MW-3
9239316004 MW-4
9239318005 MW-5
9239316006 T-1
Date: 04120/2009 04:02 PM
QC Batch Method QC Batch
MADEPEPH OEXT/6080
MADEPEPH OEXT/6080
MADEPEPH OEXT/6080
MADEPEPH OEXT/6080
MADEP EPH OEXT/6080
MADEPEPH OEXT/6080
EPA625 OEXT/6095
EPA625 OEXT/6095
EPA625 OEXT/6095
EPA625 OEXT/6095
EPA625 OEXT/6095
EPA625 OEXT/6095
MADEPVPH GCV/2972
MADEPVPH GCV/2972
MADEPVPH GCV/2972
MADEPVPH GCV/2972
MADEPVPH GCV/2972
MADEPVPH GCV/2972
EPA 601/602 GCV/2992
EPA601/602 GCV/2992
EPA601/602 GCV/2992
EPA601/602 GCV/2992
EPA601/602 GCV/2992
EPA601/602 GCV/2992
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc ..
Analytical
Analytlcal Method Batch
MADEPEPH GCSV/4926
MADEP EPH GCSV/4926
MADEPEPH GCSV/4926
MADEPEPH GCSV/4926
MADEPEPH GCSV/4926
MADEP EPH GCSV/4926
EPA625 MSSV/2541
EPA625 MSSV/2541
EPA625 MSSV/2541
EPA625 MSSV/2541
EPA625 MSSV/2541
EPA625 MSSV/2541
Page 35 of 35
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CHAIN-OF-CUSTODY / Analytical Request Document
The Chain-of-Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section a Section C
,Page: of
Required Client Information: fh;qufnid Project lnfonnalian: Invoice Information:
1""s'JJ1rt.~ ~~1Jltff:R/U(; 1·-T<r.~ ClAb::. -. ---------
IAttentioo: 1179257
IAdd~OI ~,.M:r Uf11$'1;:.. IJ> ICopyTo: ---------ieompa"YN•~tl,/t;W ~/!,_ !tEGU_l:A!Ort\'.,~Giii-jl:i:V':a c:,: : · ' /
Address: r NPDES r GROUND WATER r DRINKING WATER
OTHER Purchase Order No.: :== fX_ UST r RCRA
'RequeitadDueData/TAT": --IProjectNuinber:-/!!__~/l.,"tF)-IPacePmfile#: -:../-3 q -Yi
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;ReqQINdCllenl Information
SAMPLE ID
(A-Z, 0--9 / ,-)
Sample IDs MUST BE UNIQUE
Matrix Codes
MA,mpc / CODE
DrWong Waler ow
Water WT
Wasts Water WW
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Wipe WP
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Preservatives
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SAMPLE CONDITIONS
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ORIGINAL
•Wll'is!Hl!JW.'Mlri~~~,~¥' ,
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PRINT Name of SAMPLER:
SIGNATUREofSAMPl..21f:'Da ~ .. / DATE Signed
1MMIDO/YY):
"Important Nole: By aignlng this foon you are accepting Pace'll NET 30 day payment lemts and agreehg to late charges of 1.5% per month for ar:'; IIW!llces fiot '61d within 30 days.
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( Client Name&h,1--0 Jd Project#
Courier: D Fed Ex O UPS O USPS D Client D Commercial ,S.?ce Other __ _
Custody Seal on Cooler/Box Present: D yes 4'11" Seals intact: D yes ,.-Ej' no
Packing Material: 0 Bubble Wrap ,EjBubble Bags O None Oother ___ _
QptiO:fiaJ;);;,fi,Ii,
.;~~tiit~:~~!1~~.
Thermometer Used a060 Type ofl~ Blue None ~es on ice, cooling process Mas
Cooler Temperature· , \£) Siologica ssue is Frozen: Yes No NIA Date and 1~•3 r;
.i contents:
Temp should be above freezing to s~c Comments: '
Chain of Custody Present: ----,:(y., 0No □NIA 1.
Chain of Custody Filled Out: ~ □No □NIA 2.
Chain of Custody Relinquished: -t:1¼s □No □NIA 3.
Sampler Name & Signature on COC: ~□No □NIA 4.
Samples Arrived within Hold Time: ffies □No □NIA 5.
Short Hold Time Analysis (<72hr): □Yes ~ □NIA 6.
Rush Turn Around Tirne Requested: □Yes_ □No □NIA 7. ,,,.
Sufficient Volume: □Yes 0No □NIA 8.
Correct Containers Used: -6Yes □No □NIA 9.
-Pace Containers Used: fues □No· □NIA -Containers Intact: □Yes □No 01u1A 10.
Filtered volume received for DissoWed tes·ts □Yes □No □NIA 11.
Sample labels malch CDC: ~□No □NIA 12.
-Includes dale/time/ID/Analysis Matrix:
AU containers needing preservation have been checked,. rs 0No □NIA 13.
All containers needin9 preservation are found to be in ~ □No □NIA compliance with EPA recommen·dation, ---exceptions; VOA, coliform, TOC, O&G, Wl•DRD (water) □v~, 0No Initial when completed
Samples checked for dechlorination: 'o Yes 0No □NIA 14.
Headspace in VOA Vials ( >6mm): □Yes 0,.0 □NIA 15 .
Trip Blank Present: □Yes □No . 11'i,A 16.
Trip Blank Custody Seals Present □Yes □No ~A
Pace Trip Blank Lot# (if purchased): NIA
Client Notification/ Resolution: Field Data Required? Y / N I NIA
Person Contacted: Date/Time: --------------Comments/ Resolution: -------------------------------
Project Manager Review: ii#= Date:_3__.].__1,,...;~_W,..__ _ _,
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers)