WS-1024_30199_CA_LAB_20220823

 
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

8/23/2022
Withers & Ravenel David Vail
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 22-221-0003 Client Project Description: Moore's Exxon
02172214.68
Dear David Vail:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/9/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 35
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-221-0003
Page 2 of 35
Report Number:
Sample Summary Table
Client Project Description:
22-221-0003
Moore's Exxon
02172214.68
Lab No Client Sample ID Matrix Date Collected Date Received
08/05/2022 12:00Aqueous 96500 MW 5 08/09/2022 11:20
08/05/2022 12:30Aqueous 96501 MW 3 08/09/2022 11:20
08/05/2022 12:45Aqueous 96502 WSW 4 08/09/2022 11:20
08/05/2022 15:00Aqueous 96503 Field Blank 08/09/2022 11:20
Page 3 of 35
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-221-0003
Report Limit
Project:Moore's Exxon
V 96500MW 5
118 08/19/2022 16:386200BAcetoneµg/L 100
58.2 08/19/2022 16:386200BDi-Isopropyl Ether (DIPE)µg/L 5.00
33.7 08/19/2022 16:386200BEthylbenzeneµg/L 5.00
32.6 08/19/2022 16:386200B2-Hexanone µg/L 10.0
5.40 08/19/2022 16:386200BIsopropylbenzeneµg/L 5.00
49.2 08/19/2022 16:386200B4-Methyl-2-Pentanone µg/L 10.0
11.7 08/19/2022 16:386200BNaphthaleneµg/L 10.0
9.88 08/19/2022 16:386200BTolueneµg/L 5.00
362 08/19/2022 16:386200B1,3,5-Trimethylbenzene µg/L 5.00
139 08/19/2022 16:386200Bo-Xylene µg/L 5.00
139 08/19/2022 16:386200BXylene (Total)µg/L 5.00
28.0 08/12/2022 10:46EPA-504.1 1,2-Dibromoethane µg/L 2.08
V 96501MW 3
24.7 08/18/2022 20:476200BAcetoneµg/L 10.0
7.19 08/18/2022 20:476200Bsec-Butyl benzene µg/L 0.500
7.36 08/18/2022 20:476200Btert-Butyl benzene µg/L 2.00
7.10 08/18/2022 20:476200BDi-Isopropyl Ether (DIPE)µg/L 0.500
0.731 08/18/2022 20:476200B1,2-Dichloroethane µg/L 0.500
42.7 08/18/2022 20:476200BEthylbenzeneµg/L 0.500
9.52 08/18/2022 20:476200B2-Hexanone µg/L 1.00
14.7 08/18/2022 20:476200BIsopropylbenzeneµg/L 0.500
2.34 08/18/2022 20:476200B4-Isopropyl toluene µg/L 0.500
13.5 08/18/2022 20:476200BMethyl Ethyl Ketone (MEK)µg/L 5.00
9.74 08/18/2022 20:476200B4-Methyl-2-Pentanone µg/L 1.00
51.8 08/18/2022 20:476200BNaphthaleneµg/L 1.00
22.8 08/18/2022 20:476200Bn-Propylbenzene µg/L 0.500
14.4 08/18/2022 20:476200BTolueneµg/L 0.500
72.1 08/19/2022 16:106200B1,2,4-Trimethylbenzene µg/L 50.0
287 08/19/2022 16:106200B1,3,5-Trimethylbenzene µg/L 50.0
193 08/19/2022 16:106200Bo-Xylene µg/L 50.0
199 08/18/2022 20:476200Bm,p-Xylene µg/L 1.00
392 08/18/2022 20:476200BXylene (Total)µg/L 1.00
2.25 08/12/2022 11:08EPA-504.1 1,2-Dibromoethane µg/L 0.208
Page 4 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 5
96500 Matrix:
8/5/2022 12:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
28.0 µg/L 2.081,2-Dibromoethane 100 08/12/22 10:46 EPA-504.1JC1
118 µg/L 100Acetone 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Benzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Bromobenzene 10 08/19/22 16:38 6200BJLB
<10.0 µg/L 10.0Bromochloromethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Bromodichloromethane 10 08/19/22 16:38 6200BJLB
<50.0 µg/L 50.0Bromoform 10 08/19/22 16:38 6200BJLB
<10.0 µg/L 10.0Bromomethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00n-Butylbenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00sec-Butyl benzene 10 08/19/22 16:38 6200BJLB
<20.0 µg/L 20.0tert-Butyl benzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Carbon Tetrachloride 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Chlorobenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Chlorodibromomethane 10 08/19/22 16:38 6200BJLB
<10.0 µg/L 10.0Chloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Chloroform 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Chloromethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.002-Chlorotoluene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.004-Chlorotoluene 10 08/19/22 16:38 6200BJLB
<20.0 µg/L 20.01,2-Dibromo-3-Chloropropane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Dibromomethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2-Dichlorobenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,3-Dichlorobenzene 10 08/19/22 16:38 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 5 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 5
96500 Matrix:
8/5/2022 12:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<5.00 µg/L 5.001,4-Dichlorobenzene 10 08/19/22 16:38 6200BJLB
<50.0 µg/L 50.0Dichlorodifluoromethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1-Dichloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2-Dichloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1-Dichloroethene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00cis-1,2-Dichloroethene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00trans-1,2-Dichloroethene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2-Dichloropropane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,3-Dichloropropane 10 08/19/22 16:38 6200BJLB
<20.0 µg/L 20.02,2-Dichloropropane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1-Dichloropropene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00cis-1,3-Dichloropropene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00trans-1,3-Dichloropropene 10 08/19/22 16:38 6200BJLB
<2000 µg/L 2000Ethanol 10 08/19/22 16:38 6200BJLB
33.7 µg/L 5.00Ethylbenzene 10 08/19/22 16:38 6200BJLB
<30.0 µg/L 30.0Hexachlorobutadiene 10 08/19/22 16:38 6200BJLB
58.2 µg/L 5.00Di-Isopropyl Ether (DIPE)10 08/19/22 16:38 6200BJLB
5.40 µg/L 5.00Isopropylbenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.004-Isopropyl toluene 10 08/19/22 16:38 6200BJLB
32.6 µg/L 10.02-Hexanone 10 08/19/22 16:38 6200BJLB
<50.0 µg/L 50.0Methyl Ethyl Ketone (MEK)10 08/19/22 16:38 6200BJLB
<20.0 µg/L 20.0Methylene Chloride 10 08/19/22 16:38 6200BJLB
<10.0 µg/L 10.0Methyl tert-butyl ether (MTBE)10 08/19/22 16:38 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 5
96500 Matrix:
8/5/2022 12:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
49.2 µg/L 10.04-Methyl-2-Pentanone 10 08/19/22 16:38 6200BJLB
11.7 µg/L 10.0Naphthalene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00n-Propylbenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Styrene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1,1,2-Tetrachloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1,2,2-Tetrachloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Tetrachloroethene 10 08/19/22 16:38 6200BJLB
9.88 µg/L 5.00Toluene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2,3-Trichlorobenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2,4-Trichlorobenzene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1,1-Trichloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,1,2-Trichloroethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Trichloroethene 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Trichlorofluoromethane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2,3-Trichloropropane 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.001,2,4-Trimethylbenzene 10 08/19/22 16:38 6200BJLB
362 µg/L 5.001,3,5-Trimethylbenzene 10 08/19/22 16:38 6200BJLB
<50.0 µg/L 50.0Vinyl Acetate 10 08/19/22 16:38 6200BJLB
<5.00 µg/L 5.00Vinyl Chloride 10 08/19/22 16:38 6200BJLB
<10.0 µg/L 10.0m,p-Xylene 10 08/19/22 16:38 6200BJLB
139 µg/L 5.00o-Xylene 10 08/19/22 16:38 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 5
96500 Matrix:
8/5/2022 12:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
139 µg/L 5.00Xylene (Total)10 08/19/22 16:38 6200B
Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%08/19/22 16:3810 JLB V22996
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%08/19/22 16:3810 JLB V22996
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%08/19/22 16:3810 JLB V22996
Surrogate: Toluene-d8 98.0 Limits: 70-130%08/19/22 16:3810 JLB V22996
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 3
96501 Matrix:
8/5/2022 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
2.25 µg/L 0.2081,2-Dibromoethane 10 08/12/22 11:08 EPA-504.1JC1
24.7 µg/L 10.0Acetone 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Benzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Bromobenzene 1 08/18/22 20:47 6200BJLB
<1.00 µg/L 1.00Bromochloromethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Bromodichloromethane 1 08/18/22 20:47 6200BJLB
<5.00 µg/L 5.00Bromoform 1 08/18/22 20:47 6200BJLB
<1.00 µg/L 1.00Bromomethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500n-Butylbenzene 1 08/18/22 20:47 6200BJLB
7.19 µg/L 0.500sec-Butyl benzene 1 08/18/22 20:47 6200BJLB
7.36 µg/L 2.00tert-Butyl benzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Carbon Tetrachloride 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Chlorobenzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Chlorodibromomethane 1 08/18/22 20:47 6200BJLB
<1.00 µg/L 1.00Chloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Chloroform 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Chloromethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5002-Chlorotoluene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5004-Chlorotoluene 1 08/18/22 20:47 6200BJLB
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Dibromomethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 08/18/22 20:47 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 9 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 3
96501 Matrix:
8/5/2022 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 08/18/22 20:47 6200BJLB
<5.00 µg/L 5.00Dichlorodifluoromethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethane 1 08/18/22 20:47 6200BJLB
0.731 µg/L 0.5001,2-Dichloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,2-Dichloropropane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,3-Dichloropropane 1 08/18/22 20:47 6200BJLB
<2.00 µg/L 2.002,2-Dichloropropane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1-Dichloropropene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 08/18/22 20:47 6200BJLB
<200 µg/L 200Ethanol 1 08/18/22 20:47 6200BJLB
42.7 µg/L 0.500Ethylbenzene 1 08/18/22 20:47 6200BJLB
<3.00 µg/L 3.00Hexachlorobutadiene 1 08/18/22 20:47 6200BJLB
7.10 µg/L 0.500Di-Isopropyl Ether (DIPE)1 08/18/22 20:47 6200BJLB
14.7 µg/L 0.500Isopropylbenzene 1 08/18/22 20:47 6200BJLB
2.34 µg/L 0.5004-Isopropyl toluene 1 08/18/22 20:47 6200BJLB
9.52 µg/L 1.002-Hexanone 1 08/18/22 20:47 6200BJLB
13.5 µg/L 5.00Methyl Ethyl Ketone (MEK)1 08/18/22 20:47 6200BJLB
<2.00 µg/L 2.00Methylene Chloride 1 08/18/22 20:47 6200BJLB
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 08/18/22 20:47 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 10 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 3
96501 Matrix:
8/5/2022 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
9.74 µg/L 1.004-Methyl-2-Pentanone 1 08/18/22 20:47 6200BJLB
51.8 µg/L 1.00Naphthalene 1 08/18/22 20:47 6200BJLB
22.8 µg/L 0.500n-Propylbenzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Styrene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Tetrachloroethene 1 08/18/22 20:47 6200BJLB
14.4 µg/L 0.500Toluene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Trichloroethene 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Trichlorofluoromethane 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 08/18/22 20:47 6200BJLB
72.1 µg/L 50.01,2,4-Trimethylbenzene 100 08/19/22 16:10 6200BJLB
287 µg/L 50.01,3,5-Trimethylbenzene 100 08/19/22 16:10 6200BJLB
<5.00 µg/L 5.00Vinyl Acetate 1 08/18/22 20:47 6200BJLB
<0.500 µg/L 0.500Vinyl Chloride 1 08/18/22 20:47 6200BJLB
199 µg/L 1.00m,p-Xylene 1 08/18/22 20:47 6200BJLB
193 µg/L 50.0o-Xylene 100 08/19/22 16:10 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 11 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:MW 3
96501 Matrix:
8/5/2022 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
392 µg/L 1.00Xylene (Total)1 08/18/22 20:47 6200B
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%08/18/22 20:471 JLB V22913
Surrogate: Dibromofluoromethane 100 Limits: 70-130%08/18/22 20:471 JLB V22913
Surrogate: 1,2-Dichloroethane - d4 99.0 Limits: 70-130%08/18/22 20:471 JLB V22913
Surrogate: Toluene-d8 98.6 Limits: 70-130%08/18/22 20:471 JLB V22913
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%08/19/22 16:10100 JLB V22996
Surrogate: Dibromofluoromethane 101 Limits: 70-130%08/19/22 16:10100 JLB V22996
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%08/19/22 16:10100 JLB V22996
Surrogate: Toluene-d8 99.0 Limits: 70-130%08/19/22 16:10100 JLB V22996
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 12 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:WSW 4
96502 Matrix:
8/5/2022 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.0208 µg/L 0.02081,2-Dibromoethane 1 08/11/22 19:23 EPA-504.1JC1
<10.0 µg/L 10.0Acetone 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Benzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Bromobenzene 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00Bromochloromethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Bromodichloromethane 1 08/18/22 21:14 6200BJLB
<5.00 µg/L 5.00Bromoform 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00Bromomethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500n-Butylbenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500sec-Butyl benzene 1 08/18/22 21:14 6200BJLB
<2.00 µg/L 2.00tert-Butyl benzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Carbon Tetrachloride 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Chlorobenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Chlorodibromomethane 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00Chloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Chloroform 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Chloromethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5002-Chlorotoluene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5004-Chlorotoluene 1 08/18/22 21:14 6200BJLB
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Dibromomethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 08/18/22 21:14 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 13 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:WSW 4
96502 Matrix:
8/5/2022 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 08/18/22 21:14 6200BJLB
<5.00 µg/L 5.00Dichlorodifluoromethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2-Dichloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2-Dichloropropane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,3-Dichloropropane 1 08/18/22 21:14 6200BJLB
<2.00 µg/L 2.002,2-Dichloropropane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1-Dichloropropene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 08/18/22 21:14 6200BJLB
<200 µg/L 200Ethanol 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Ethylbenzene 1 08/18/22 21:14 6200BJLB
<3.00 µg/L 3.00Hexachlorobutadiene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Isopropylbenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5004-Isopropyl toluene 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.002-Hexanone 1 08/18/22 21:14 6200BJLB
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 08/18/22 21:14 6200BJLB
<2.00 µg/L 2.00Methylene Chloride 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 08/18/22 21:14 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 14 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:WSW 4
96502 Matrix:
8/5/2022 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00Naphthalene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500n-Propylbenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Styrene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Tetrachloroethene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Toluene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Trichloroethene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Trichlorofluoromethane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 08/18/22 21:14 6200BJLB
<5.00 µg/L 5.00Vinyl Acetate 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500Vinyl Chloride 1 08/18/22 21:14 6200BJLB
<1.00 µg/L 1.00m,p-Xylene 1 08/18/22 21:14 6200BJLB
<0.500 µg/L 0.500o-Xylene 1 08/18/22 21:14 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 15 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:WSW 4
96502 Matrix:
8/5/2022 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 08/18/22 21:14 6200B
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%08/18/22 21:141 JLB V22913
Surrogate: Dibromofluoromethane 100 Limits: 70-130%08/18/22 21:141 JLB V22913
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%08/18/22 21:141 JLB V22913
Surrogate: Toluene-d8 99.0 Limits: 70-130%08/18/22 21:141 JLB V22913
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 16 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:Field Blank
96503 Matrix:
8/5/2022 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Benzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Bromobenzene 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00Bromochloromethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Bromodichloromethane 1 08/18/22 21:41 6200BJLB
<5.00 µg/L 5.00Bromoform 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00Bromomethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500n-Butylbenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500sec-Butyl benzene 1 08/18/22 21:41 6200BJLB
<2.00 µg/L 2.00tert-Butyl benzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Carbon Tetrachloride 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Chlorobenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Chlorodibromomethane 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00Chloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Chloroform 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Chloromethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5002-Chlorotoluene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5004-Chlorotoluene 1 08/18/22 21:41 6200BJLB
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2-Dibromoethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Dibromomethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 08/18/22 21:41 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 17 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:Field Blank
96503 Matrix:
8/5/2022 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 08/18/22 21:41 6200BJLB
<5.00 µg/L 5.00Dichlorodifluoromethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2-Dichloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1-Dichloroethene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2-Dichloropropane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,3-Dichloropropane 1 08/18/22 21:41 6200BJLB
<2.00 µg/L 2.002,2-Dichloropropane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1-Dichloropropene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 08/18/22 21:41 6200BJLB
<200 µg/L 200Ethanol 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Ethylbenzene 1 08/18/22 21:41 6200BJLB
<3.00 µg/L 3.00Hexachlorobutadiene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Isopropylbenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5004-Isopropyl toluene 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.002-Hexanone 1 08/18/22 21:41 6200BJLB
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 08/18/22 21:41 6200BJLB
<2.00 µg/L 2.00Methylene Chloride 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 08/18/22 21:41 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 18 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:Field Blank
96503 Matrix:
8/5/2022 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00Naphthalene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500n-Propylbenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Styrene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Tetrachloroethene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Toluene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Trichloroethene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Trichlorofluoromethane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 08/18/22 21:41 6200BJLB
<5.00 µg/L 5.00Vinyl Acetate 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500Vinyl Chloride 1 08/18/22 21:41 6200BJLB
<1.00 µg/L 1.00m,p-Xylene 1 08/18/22 21:41 6200BJLB
<0.500 µg/L 0.500o-Xylene 1 08/18/22 21:41 6200BJLB
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 19 of 35
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
22-221-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
02172214.68 Received : 08/09/2022
Moore's Exxon
Report Date : 08/23/2022
Sample ID :
Lab No :
Sampled:Field Blank
96503 Matrix:
8/5/2022 15:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 08/18/22 21:41 6200B
Surrogate: 4-Bromofluorobenzene 98.6 Limits: 70-130%08/18/22 21:411 JLB V22913
Surrogate: Dibromofluoromethane 101 Limits: 70-130%08/18/22 21:411 JLB V22913
Surrogate: 1,2-Dichloroethane - d4 96.8 Limits: 70-130%08/18/22 21:411 JLB V22913
Surrogate: Toluene-d8 99.4 Limits: 70-130%08/18/22 21:411 JLB V22913
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 20 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
Associated Lab Samples: 96501, 96502, 96503
LRB-V22912 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 13:5810.0< 10.0µg/LAcetone
08/18/22 13:580.500< 0.500µg/LBenzene
08/18/22 13:580.500< 0.500µg/LBromobenzene
08/18/22 13:581.00< 1.00µg/LBromochloromethane
08/18/22 13:580.500< 0.500µg/LBromodichloromethane
08/18/22 13:585.00< 5.00µg/LBromoform
08/18/22 13:581.00< 1.00µg/LBromomethane
08/18/22 13:580.500< 0.500µg/Ln-Butylbenzene
08/18/22 13:580.500< 0.500µg/Lsec-Butyl benzene
08/18/22 13:582.00< 2.00µg/Ltert-Butyl benzene
08/18/22 13:580.500< 0.500µg/LCarbon Tetrachloride
08/18/22 13:580.500< 0.500µg/LChlorobenzene
08/18/22 13:580.500< 0.500µg/LChlorodibromomethane
08/18/22 13:581.00< 1.00µg/LChloroethane
08/18/22 13:580.500< 0.500µg/LChloroform
08/18/22 13:580.500< 0.500µg/LChloromethane
08/18/22 13:580.500< 0.500µg/L2-Chlorotoluene
08/18/22 13:580.500< 0.500µg/L4-Chlorotoluene
08/18/22 13:582.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
08/18/22 13:580.500< 0.500µg/L1,2-Dibromoethane
08/18/22 13:580.500< 0.500µg/LDibromomethane
08/18/22 13:580.500< 0.500µg/L1,2-Dichlorobenzene
08/18/22 13:580.500< 0.500µg/L1,3-Dichlorobenzene
08/18/22 13:580.500< 0.500µg/L1,4-Dichlorobenzene
08/18/22 13:585.00< 5.00µg/LDichlorodifluoromethane
08/18/22 13:580.500< 0.500µg/L1,1-Dichloroethane
08/18/22 13:580.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 13Date:08/23/2022 01:04 PM
Page 21 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
Associated Lab Samples: 96501, 96502, 96503
LRB-V22912 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 13:580.500< 0.500µg/L1,1-Dichloroethene
08/18/22 13:580.500< 0.500µg/Lcis-1,2-Dichloroethene
08/18/22 13:580.500< 0.500µg/Ltrans-1,2-Dichloroethene
08/18/22 13:580.500< 0.500µg/L1,2-Dichloropropane
08/18/22 13:580.500< 0.500µg/L1,3-Dichloropropane
08/18/22 13:582.00< 2.00µg/L2,2-Dichloropropane
08/18/22 13:580.500< 0.500µg/L1,1-Dichloropropene
08/18/22 13:580.500< 0.500µg/Lcis-1,3-Dichloropropene
08/18/22 13:580.500< 0.500µg/Ltrans-1,3-Dichloropropene
08/18/22 13:58200< 200µg/LEthanol
08/18/22 13:580.500< 0.500µg/LEthylbenzene
08/18/22 13:583.00< 3.00µg/LHexachlorobutadiene
08/18/22 13:580.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
08/18/22 13:580.500< 0.500µg/LIsopropylbenzene
08/18/22 13:580.500< 0.500µg/L4-Isopropyl toluene
08/18/22 13:581.00< 1.00µg/L2-Hexanone
08/18/22 13:585.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
08/18/22 13:582.00< 2.00µg/LMethylene Chloride
08/18/22 13:581.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
08/18/22 13:581.00< 1.00µg/L4-Methyl-2-Pentanone
08/18/22 13:581.00< 1.00µg/LNaphthalene
08/18/22 13:580.500< 0.500µg/Ln-Propylbenzene
08/18/22 13:580.500< 0.500µg/LStyrene
08/18/22 13:580.500< 0.500µg/L1,1,1,2-Tetrachloroethane
08/18/22 13:580.500< 0.500µg/L1,1,2,2-Tetrachloroethane
08/18/22 13:580.500< 0.500µg/LTetrachloroethene
08/18/22 13:580.500< 0.500µg/LToluene
Page 2 of 13Date:08/23/2022 01:04 PM
Page 22 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
Associated Lab Samples: 96501, 96502, 96503
LRB-V22912 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/18/22 13:580.500< 0.500µg/L1,2,3-Trichlorobenzene
08/18/22 13:580.500< 0.500µg/L1,2,4-Trichlorobenzene
08/18/22 13:580.500< 0.500µg/L1,1,1-Trichloroethane
08/18/22 13:580.500< 0.500µg/L1,1,2-Trichloroethane
08/18/22 13:580.500< 0.500µg/LTrichloroethene
08/18/22 13:580.500< 0.500µg/LTrichlorofluoromethane
08/18/22 13:580.500< 0.500µg/L1,2,3-Trichloropropane
08/18/22 13:580.500< 0.500µg/L1,2,4-Trimethylbenzene
08/18/22 13:580.500< 0.500µg/L1,3,5-Trimethylbenzene
08/18/22 13:585.00< 5.00µg/LVinyl Acetate
08/18/22 13:580.500< 0.500µg/LVinyl Chloride
08/18/22 13:581.00< 1.00µg/Lm,p-Xylene
08/18/22 13:580.500< 0.500µg/Lo-Xylene
08/18/22 13:584-Bromofluorobenzene (S)98.2 70-130
08/18/22 13:58Dibromofluoromethane (S)102 70-130
08/18/22 13:581,2-Dichloroethane - d4 (S)97.8 70-130
08/18/22 13:58Toluene-d8 (S)99.2 70-130
LCS-V22912 LCSD-V22912Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.0 97.596.038.440.0µg/LAcetone 40-160 1.5 20.0
19.6 98.010320.520.0µg/LBenzene 70-130 4.4 20.0
18.4 92.093.518.720.0µg/LBromobenzene 70-130 1.6 20.0
19.8 99.010320.620.0µg/LBromochloromethane 70-130 3.9 20.0
20.4 10210420.720.0µg/LBromodichloromethane 70-130 1.4 20.0
Page 3 of 13Date:08/23/2022 01:04 PM
Page 23 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
LCS-V22912 LCSD-V22912Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.1 11110420.720.0µg/LBromoform 70-130 6.5 20.0
20.9 10510721.320.0µg/LBromomethane 60-140 1.8 20.0
19.3 96.510220.320.0µg/Ln-Butylbenzene 70-130 5.0 20.0
20.2 10110520.920.0µg/Lsec-Butyl benzene 70-130 3.4 20.0
20.9 10510521.020.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
19.4 97.099.519.920.0µg/LCarbon Tetrachloride 70-130 2.5 20.0
20.0 10010520.920.0µg/LChlorobenzene 70-130 4.4 20.0
20.1 10110721.320.0µg/LChlorodibromomethane 70-130 5.7 20.0
20.2 10110721.420.0µg/LChloroethane 60-140 5.7 20.0
21.0 10510921.820.0µg/LChloroform 70-130 3.7 20.0
18.6 93.091.518.320.0µg/LChloromethane 60-140 1.6 20.0
19.2 96.010120.220.0µg/L2-Chlorotoluene 70-130 5.0 20.0
19.7 98.510320.620.0µg/L4-Chlorotoluene 70-130 4.4 20.0
21.1 10610921.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 3.2 20.0
20.8 10410821.620.0µg/L1,2-Dibromoethane 70-130 3.7 20.0
19.5 97.510420.720.0µg/LDibromomethane 70-130 5.9 20.0
20.7 10411122.120.0µg/L1,2-Dichlorobenzene 70-130 6.5 20.0
20.6 10310821.520.0µg/L1,3-Dichlorobenzene 70-130 4.2 20.0
20.0 10010120.220.0µg/L1,4-Dichlorobenzene 70-130 0.9 20.0
19.7 98.510320.520.0µg/LDichlorodifluoromethane 60-140 3.9 20.0
20.5 10310320.520.0µg/L1,1-Dichloroethane 70-130 0.0 20.0
19.1 95.594.018.820.0µg/L1,2-Dichloroethane 70-130 1.5 20.0
20.5 10310621.120.0µg/L1,1-Dichloroethene 70-130 2.8 20.0
20.3 10210120.120.0µg/Lcis-1,2-Dichloroethene 70-130 0.9 20.0
20.1 10110320.620.0µg/Ltrans-1,2-Dichloroethene 70-130 2.4 20.0
20.6 10310521.020.0µg/L1,2-Dichloropropane 70-130 1.9 20.0
Page 4 of 13Date:08/23/2022 01:04 PM
Page 24 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
LCS-V22912 LCSD-V22912Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.8 10410621.120.0µg/L1,3-Dichloropropane 70-130 1.4 20.0
19.6 98.010320.520.0µg/L2,2-Dichloropropane 70-130 4.4 20.0
21.2 10610420.820.0µg/L1,1-Dichloropropene 70-130 1.9 20.0
21.9 11011222.320.0µg/Lcis-1,3-Dichloropropene 70-130 1.8 20.0
21.9 11011222.320.0µg/Ltrans-1,3-Dichloropropene 70-130 1.8 20.0
561 11299.8499500µg/LEthanol 60-140 11.6 20.0
19.5 97.598.519.720.0µg/LEthylbenzene 70-130 1.0 20.0
21.3 10711522.920.0µg/LHexachlorobutadiene 70-130 7.2 20.0
20.9 10510621.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.4 20.0
20.0 10010320.620.0µg/LIsopropylbenzene 70-130 2.9 20.0
20.8 10410621.220.0µg/L4-Isopropyl toluene 70-130 1.9 20.0
16.8 84.091.018.220.0µg/L2-Hexanone 60-140 8.0 20.0
20.0 10010621.220.0µg/LMethyl Ethyl Ketone (MEK)60-140 5.8 20.0
19.8 99.010320.520.0µg/LMethylene Chloride 70-130 3.4 20.0
21.6 10811022.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.8 20.0
19.3 96.595.519.120.0µg/L4-Methyl-2-Pentanone 60-140 1.0 20.0
17.9 89.588.517.720.0µg/LNaphthalene 70-130 1.1 20.0
19.9 99.510320.520.0µg/Ln-Propylbenzene 70-130 2.9 20.0
20.1 10110220.320.0µg/LStyrene 70-130 0.9 20.0
19.8 99.099.519.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.5 20.0
20.1 10110420.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 3.4 20.0
21.5 10810821.520.0µg/LTetrachloroethene 70-130 0.0 20.0
20.0 10098.519.720.0µg/LToluene 70-130 1.5 20.0
20.4 10210721.320.0µg/L1,2,3-Trichlorobenzene 70-130 4.3 20.0
21.3 10710621.120.0µg/L1,2,4-Trichlorobenzene 70-130 0.9 20.0
21.3 10710721.420.0µg/L1,1,1-Trichloroethane 70-130 0.4 20.0
Page 5 of 13Date:08/23/2022 01:04 PM
Page 25 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22913QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22912
LCS-V22912 LCSD-V22912Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.1 10611122.220.0µg/L1,1,2-Trichloroethane 70-130 5.0 20.0
20.4 10210521.020.0µg/LTrichloroethene 70-130 2.8 20.0
22.0 11011222.420.0µg/LTrichlorofluoromethane 60-140 1.8 20.0
20.4 10211122.120.0µg/L1,2,3-Trichloropropane 70-130 8.0 20.0
20.3 10210420.820.0µg/L1,2,4-Trimethylbenzene 70-130 2.4 20.0
20.0 10010320.520.0µg/L1,3,5-Trimethylbenzene 70-130 2.4 20.0
19.6 98.010320.520.0µg/LVinyl Acetate 60-140 4.4 20.0
22.1 11111222.420.0µg/LVinyl Chloride 60-140 1.3 20.0
41.4 10410542.040.0µg/Lm,p-Xylene 70-130 1.4 20.0
19.6 98.010420.720.0µg/Lo-Xylene 70-130 5.4 20.0
97.299.64-Bromofluorobenzene (S)70-130
104103Dibromofluoromethane (S)70-130
99.699.01,2-Dichloroethane - d4 (S)70-130
98.098.2Toluene-d8 (S)70-130
Page 6 of 13Date:08/23/2022 01:04 PM
Page 26 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
Associated Lab Samples: 96500, 96501
LRB-V22994 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/19/22 14:4910.0< 10.0µg/LAcetone
08/19/22 14:490.500< 0.500µg/LBenzene
08/19/22 14:490.500< 0.500µg/LBromobenzene
08/19/22 14:491.00< 1.00µg/LBromochloromethane
08/19/22 14:490.500< 0.500µg/LBromodichloromethane
08/19/22 14:495.00< 5.00µg/LBromoform
08/19/22 14:491.00< 1.00µg/LBromomethane
08/19/22 14:490.500< 0.500µg/Ln-Butylbenzene
08/19/22 14:490.500< 0.500µg/Lsec-Butyl benzene
08/19/22 14:492.00< 2.00µg/Ltert-Butyl benzene
08/19/22 14:490.500< 0.500µg/LCarbon Tetrachloride
08/19/22 14:490.500< 0.500µg/LChlorobenzene
08/19/22 14:490.500< 0.500µg/LChlorodibromomethane
08/19/22 14:491.00< 1.00µg/LChloroethane
08/19/22 14:490.500< 0.500µg/LChloroform
08/19/22 14:490.500< 0.500µg/LChloromethane
08/19/22 14:490.500< 0.500µg/L2-Chlorotoluene
08/19/22 14:490.500< 0.500µg/L4-Chlorotoluene
08/19/22 14:492.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
08/19/22 14:490.500< 0.500µg/LDibromomethane
08/19/22 14:490.500< 0.500µg/L1,2-Dichlorobenzene
08/19/22 14:490.500< 0.500µg/L1,3-Dichlorobenzene
08/19/22 14:490.500< 0.500µg/L1,4-Dichlorobenzene
08/19/22 14:495.00< 5.00µg/LDichlorodifluoromethane
08/19/22 14:490.500< 0.500µg/L1,1-Dichloroethane
08/19/22 14:490.500< 0.500µg/L1,2-Dichloroethane
08/19/22 14:490.500< 0.500µg/L1,1-Dichloroethene
Page 7 of 13Date:08/23/2022 01:04 PM
Page 27 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
Associated Lab Samples: 96500, 96501
LRB-V22994 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/19/22 14:490.500< 0.500µg/Lcis-1,2-Dichloroethene
08/19/22 14:490.500< 0.500µg/Ltrans-1,2-Dichloroethene
08/19/22 14:490.500< 0.500µg/L1,2-Dichloropropane
08/19/22 14:490.500< 0.500µg/L1,3-Dichloropropane
08/19/22 14:492.00< 2.00µg/L2,2-Dichloropropane
08/19/22 14:490.500< 0.500µg/L1,1-Dichloropropene
08/19/22 14:490.500< 0.500µg/Lcis-1,3-Dichloropropene
08/19/22 14:490.500< 0.500µg/Ltrans-1,3-Dichloropropene
08/19/22 14:49200< 200µg/LEthanol
08/19/22 14:490.500< 0.500µg/LEthylbenzene
08/19/22 14:493.00< 3.00µg/LHexachlorobutadiene
08/19/22 14:490.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
08/19/22 14:490.500< 0.500µg/LIsopropylbenzene
08/19/22 14:490.500< 0.500µg/L4-Isopropyl toluene
08/19/22 14:491.00< 1.00µg/L2-Hexanone
08/19/22 14:495.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
08/19/22 14:492.00< 2.00µg/LMethylene Chloride
08/19/22 14:491.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
08/19/22 14:491.00< 1.00µg/L4-Methyl-2-Pentanone
08/19/22 14:491.00< 1.00µg/LNaphthalene
08/19/22 14:490.500< 0.500µg/Ln-Propylbenzene
08/19/22 14:490.500< 0.500µg/LStyrene
08/19/22 14:490.500< 0.500µg/L1,1,1,2-Tetrachloroethane
08/19/22 14:490.500< 0.500µg/L1,1,2,2-Tetrachloroethane
08/19/22 14:490.500< 0.500µg/LTetrachloroethene
08/19/22 14:490.500< 0.500µg/LToluene
08/19/22 14:490.500< 0.500µg/L1,2,3-Trichlorobenzene
Page 8 of 13Date:08/23/2022 01:04 PM
Page 28 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
Associated Lab Samples: 96500, 96501
LRB-V22994 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/19/22 14:490.500< 0.500µg/L1,2,4-Trichlorobenzene
08/19/22 14:490.500< 0.500µg/L1,1,1-Trichloroethane
08/19/22 14:490.500< 0.500µg/L1,1,2-Trichloroethane
08/19/22 14:490.500< 0.500µg/LTrichloroethene
08/19/22 14:490.500< 0.500µg/LTrichlorofluoromethane
08/19/22 14:490.500< 0.500µg/L1,2,3-Trichloropropane
08/19/22 14:490.500< 0.500µg/L1,2,4-Trimethylbenzene
08/19/22 14:490.500< 0.500µg/L1,3,5-Trimethylbenzene
08/19/22 14:495.00< 5.00µg/LVinyl Acetate
08/19/22 14:490.500< 0.500µg/LVinyl Chloride
08/19/22 14:491.00< 1.00µg/Lm,p-Xylene
08/19/22 14:490.500< 0.500µg/Lo-Xylene
08/19/22 14:494-Bromofluorobenzene (S)97.6 70-130
08/19/22 14:49Dibromofluoromethane (S)101 70-130
08/19/22 14:491,2-Dichloroethane - d4 (S)97.0 70-130
08/19/22 14:49Toluene-d8 (S)98.2 70-130
LCS-V22994 LCSD-V22994Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
37.8 94.595.738.340.0µg/LAcetone 40-160 1.3 20.0
20.0 10010020.020.0µg/LBenzene 70-130 0.0 20.0
19.0 95.093.018.620.0µg/LBromobenzene 70-130 2.1 20.0
20.8 10496.019.220.0µg/LBromochloromethane 70-130 8.0 20.0
20.1 10110020.020.0µg/LBromodichloromethane 70-130 0.4 20.0
20.8 10410420.820.0µg/LBromoform 70-130 0.0 20.0
Page 9 of 13Date:08/23/2022 01:04 PM
Page 29 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
LCS-V22994 LCSD-V22994Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.6 98.097.519.520.0µg/LBromomethane 60-140 0.5 20.0
20.4 10299.019.820.0µg/Ln-Butylbenzene 70-130 2.9 20.0
20.9 10510220.420.0µg/Lsec-Butyl benzene 70-130 2.4 20.0
21.0 10510320.520.0µg/Ltert-Butyl benzene 70-130 2.4 20.0
20.0 10010220.420.0µg/LCarbon Tetrachloride 70-130 1.9 20.0
20.6 10310320.620.0µg/LChlorobenzene 70-130 0.0 20.0
20.3 10210220.420.0µg/LChlorodibromomethane 70-130 0.4 20.0
21.6 10810420.820.0µg/LChloroethane 60-140 3.7 20.0
21.3 10710721.320.0µg/LChloroform 70-130 0.0 20.0
19.3 96.592.518.520.0µg/LChloromethane 60-140 4.2 20.0
20.2 10198.519.720.0µg/L2-Chlorotoluene 70-130 2.5 20.0
20.2 10199.019.820.0µg/L4-Chlorotoluene 70-130 2.0 20.0
19.7 98.510420.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.4 20.0
20.5 10310020.020.0µg/LDibromomethane 70-130 2.4 20.0
21.3 10710821.520.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
21.3 10710520.920.0µg/L1,3-Dichlorobenzene 70-130 1.8 20.0
20.2 10110020.020.0µg/L1,4-Dichlorobenzene 70-130 0.9 20.0
20.4 10210120.120.0µg/LDichlorodifluoromethane 60-140 1.4 20.0
20.2 10110120.120.0µg/L1,1-Dichloroethane 70-130 0.4 20.0
18.8 94.092.518.520.0µg/L1,2-Dichloroethane 70-130 1.6 20.0
21.4 10710621.220.0µg/L1,1-Dichloroethene 70-130 0.9 20.0
20.7 10410320.520.0µg/Lcis-1,2-Dichloroethene 70-130 0.9 20.0
20.8 10410420.720.0µg/Ltrans-1,2-Dichloroethene 70-130 0.4 20.0
20.6 10310821.520.0µg/L1,2-Dichloropropane 70-130 4.2 20.0
20.8 10410420.820.0µg/L1,3-Dichloropropane 70-130 0.0 20.0
20.5 10310420.820.0µg/L2,2-Dichloropropane 70-130 1.4 20.0
Page 10 of 13Date:08/23/2022 01:04 PM
Page 30 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
LCS-V22994 LCSD-V22994Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.0 10510420.820.0µg/L1,1-Dichloropropene 70-130 0.9 20.0
21.8 10911222.320.0µg/Lcis-1,3-Dichloropropene 70-130 2.2 20.0
21.8 10911222.320.0µg/Ltrans-1,3-Dichloropropene 70-130 2.2 20.0
502 100104519500µg/LEthanol 60-140 3.3 20.0
19.9 99.510020.020.0µg/LEthylbenzene 70-130 0.5 20.0
21.8 10911823.520.0µg/LHexachlorobutadiene 70-130 7.5 20.0
20.8 10410420.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.0 20.0
20.7 10410120.120.0µg/LIsopropylbenzene 70-130 2.9 20.0
21.6 10810320.520.0µg/L4-Isopropyl toluene 70-130 5.2 20.0
16.9 84.589.017.820.0µg/L2-Hexanone 60-140 5.1 20.0
21.6 10810721.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.3 20.0
20.3 10298.519.720.0µg/LMethylene Chloride 70-130 3.0 20.0
21.8 10910921.720.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.4 20.0
19.8 99.096.519.320.0µg/L4-Methyl-2-Pentanone 60-140 2.5 20.0
18.4 92.090.518.120.0µg/LNaphthalene 70-130 1.6 20.0
20.3 10210220.320.0µg/Ln-Propylbenzene 70-130 0.0 20.0
20.3 10210420.820.0µg/LStyrene 70-130 2.4 20.0
20.0 10010220.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.9 20.0
20.6 10310320.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.4 20.0
21.8 10910921.720.0µg/LTetrachloroethene 70-130 0.4 20.0
19.8 99.098.519.720.0µg/LToluene 70-130 0.5 20.0
21.3 10710721.320.0µg/L1,2,3-Trichlorobenzene 70-130 0.0 20.0
21.7 10910420.820.0µg/L1,2,4-Trichlorobenzene 70-130 4.2 20.0
21.7 10910821.520.0µg/L1,1,1-Trichloroethane 70-130 0.9 20.0
21.6 10810921.820.0µg/L1,1,2-Trichloroethane 70-130 0.9 20.0
20.2 10110320.620.0µg/LTrichloroethene 70-130 1.9 20.0
Page 11 of 13Date:08/23/2022 01:04 PM
Page 31 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V22996QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V22994
LCS-V22994 LCSD-V22994Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.3 11211222.320.0µg/LTrichlorofluoromethane 60-140 0.0 20.0
21.3 10710521.020.0µg/L1,2,3-Trichloropropane 70-130 1.4 20.0
20.9 10510120.120.0µg/L1,2,4-Trimethylbenzene 70-130 3.9 20.0
20.5 10310220.420.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0
20.5 10310220.420.0µg/LVinyl Acetate 60-140 0.4 20.0
22.8 11411222.320.0µg/LVinyl Chloride 60-140 2.2 20.0
41.8 10510542.040.0µg/Lm,p-Xylene 70-130 0.4 20.0
20.0 10010120.120.0µg/Lo-Xylene 70-130 0.4 20.0
98.297.24-Bromofluorobenzene (S)70-130
101102Dibromofluoromethane (S)70-130
97.697.61,2-Dichloroethane - d4 (S)70-130
97.897.6Toluene-d8 (S)70-130
Page 12 of 13Date:08/23/2022 01:04 PM
Page 32 of 35
Quality Control Data
22-221-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Moore's Exxon
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V22634QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V22588
Associated Lab Samples: 96500, 96501, 96502
LRB-V22588 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
08/11/22 13:080.0200< 0.0200µg/L1,2-Dibromoethane
LCS-V22588 LCSD-V22588Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.260 10498.40.2460.250µg/L1,2-Dibromoethane 70-130 5.5 20.0
V 96195-DUP-V22588Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 08/11/22 15:210.0< 0.00338< 0.0205µg/L1,2-Dibromoethane
V 96194-MS-V22588Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.217 82.80.262< 0.0209µg/L1,2-Dibromoethane 70-130
Page 13 of 13Date:08/23/2022 01:04 PM
Page 33 of 35
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-221-0003
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 3.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:08/09/2022 13:57:28
Special precautions or instructions included?
Comments:
Page 34 of 35
Page 35 of 35