WS-1024_30199_CA_LAB_20151008_Analytical_Data

#=CL#
October 08, 2015
LIMS USE: FR - LYNDAL BUTLER
LIMS OBJECT ID: 92270188
92270188
Project:
Pace Project No.:
RE:
Mr. Lyndal Butler
S&ME, Inc.
8646 West Market Street
Greensboro, NC 27409
Moore's Store 4305-15-159
Dear Mr. Butler:
Enclosed are the analytical results for sample(s) received by the laboratory on October 01, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Lab ID Sample ID Matrix Date Collected Date Received
92270188001 WSW-2 Water 09/28/15 17:02 10/01/15 13:02
92270188002 WSW-4 Water 09/28/15 17:02 10/01/15 13:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92270188001 WSW-2 EPA 504.1 3 PASI-CHSK
SM 6200B 63 PASI-CCAH
92270188002 WSW-4 EPA 504.1 3 PASI-CHSK
SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Method:
Client:S&ME - Greensboro
EPA 504.1
Date:October 08, 2015
Description:504 GCS EDB and DBCP
General Information:
2 samples were analyzed for EPA 504.1. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 504.1 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Method:
Client:S&ME - Greensboro
SM 6200B
Date:October 08, 2015
Description:6200B MSV
General Information:
2 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/33640
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92270188002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1573642)
• Hexachloro-1,3-butadiene
• MSD (Lab ID: 1573643)
• Hexachloro-1,3-butadiene
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Sample:WSW-2 Lab ID:92270188001 Collected:09/28/15 17:02 Received:10/01/15 13:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1504 GCS EDB and DBCP
1,2-Dibromo-3-chloropropane ND ug/L 10/07/15 13:51 96-12-810/06/15 15:090.048 0.048 1
1,2-Dibromoethane (EDB)ND ug/L 10/07/15 13:51 106-93-410/06/15 15:090.019 0.019 1
Surrogates
1-Chloro-2-bromopropane (S)103 %10/07/15 13:51 301-79-5610/06/15 15:0970-130 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 10/03/15 00:00 71-43-20.50 0.25 1
Bromobenzene ND ug/L 10/03/15 00:00 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 10/03/15 00:00 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 10/03/15 00:00 75-27-40.50 0.25 1
Bromoform ND ug/L 10/03/15 00:00 75-25-20.50 0.25 1
Bromomethane ND ug/L 10/03/15 00:00 74-83-95.0 0.50 1
n-Butylbenzene ND ug/L 10/03/15 00:00 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 10/03/15 00:00 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/03/15 00:00 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 10/03/15 00:00 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 10/03/15 00:00 108-90-70.50 0.25 1
Chloroethane ND ug/L 10/03/15 00:00 75-00-31.0 0.50 1
Chloroform ND ug/L 10/03/15 00:00 67-66-30.50 0.25 1
Chloromethane ND ug/L 10/03/15 00:00 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 10/03/15 00:00 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 10/03/15 00:00 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 10/03/15 00:00 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 10/03/15 00:00 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 10/03/15 00:00 106-93-40.50 0.25 1
Dibromomethane ND ug/L 10/03/15 00:00 74-95-30.50 0.25 1
1,2-Dichlorobenzene ND ug/L 10/03/15 00:00 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 10/03/15 00:00 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/03/15 00:00 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/03/15 00:00 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 10/03/15 00:00 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 10/03/15 00:00 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 10/03/15 00:00 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 10/03/15 00:00 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 10/03/15 00:00 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 10/03/15 00:00 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 10/03/15 00:00 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 10/03/15 00:00 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 10/03/15 00:00 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 10/03/15 00:00 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 10/03/15 00:00 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 10/03/15 00:00 108-20-30.50 0.25 1
Ethylbenzene ND ug/L 10/03/15 00:00 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 10/03/15 00:00 87-68-32.0 1.0 1
Isopropylbenzene (Cumene)ND ug/L 10/03/15 00:00 98-82-80.50 0.25 1
Methylene Chloride ND ug/L 10/03/15 00:00 75-09-22.0 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Sample:WSW-2 Lab ID:92270188001 Collected:09/28/15 17:02 Received:10/01/15 13:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methyl-tert-butyl ether ND ug/L 10/03/15 00:00 1634-04-40.50 0.25 1
Naphthalene ND ug/L 10/03/15 00:00 91-20-32.0 1.0 1
n-Propylbenzene ND ug/L 10/03/15 00:00 103-65-10.50 0.25 1
Styrene ND ug/L 10/03/15 00:00 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 10/03/15 00:00 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 10/03/15 00:00 79-34-50.50 0.25 1
Tetrachloroethene ND ug/L 10/03/15 00:00 127-18-40.50 0.25 1
Toluene ND ug/L 10/03/15 00:00 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 10/03/15 00:00 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 10/03/15 00:00 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 10/03/15 00:00 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 10/03/15 00:00 79-00-50.50 0.25 1
Trichloroethene ND ug/L 10/03/15 00:00 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 10/03/15 00:00 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 10/03/15 00:00 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene ND ug/L 10/03/15 00:00 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene ND ug/L 10/03/15 00:00 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 10/03/15 00:00 75-01-41.0 0.25 1
m&p-Xylene ND ug/L 10/03/15 00:00 179601-23-11.0 0.50 1
o-Xylene ND ug/L 10/03/15 00:00 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %10/03/15 00:00 17060-07-070-130 1
4-Bromofluorobenzene (S)101 %10/03/15 00:00 460-00-470-130 1
Toluene-d8 (S)99 %10/03/15 00:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Sample:WSW-4 Lab ID:92270188002 Collected:09/28/15 17:02 Received:10/01/15 13:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1504 GCS EDB and DBCP
1,2-Dibromo-3-chloropropane ND ug/L 10/07/15 14:11 96-12-810/06/15 15:090.049 0.049 1
1,2-Dibromoethane (EDB)ND ug/L 10/07/15 14:11 106-93-410/06/15 15:090.020 0.020 1
Surrogates
1-Chloro-2-bromopropane (S)95 %10/07/15 14:11 301-79-5610/06/15 15:0970-130 1
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 10/03/15 00:17 71-43-20.50 0.25 1
Bromobenzene ND ug/L 10/03/15 00:17 108-86-10.50 0.25 1
Bromochloromethane ND ug/L 10/03/15 00:17 74-97-50.50 0.25 1
Bromodichloromethane ND ug/L 10/03/15 00:17 75-27-40.50 0.25 1
Bromoform ND ug/L 10/03/15 00:17 75-25-20.50 0.25 1
Bromomethane ND ug/L 10/03/15 00:17 74-83-95.0 0.50 1
n-Butylbenzene ND ug/L 10/03/15 00:17 104-51-80.50 0.25 1
sec-Butylbenzene ND ug/L 10/03/15 00:17 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/03/15 00:17 98-06-60.50 0.25 1
Carbon tetrachloride ND ug/L 10/03/15 00:17 56-23-50.50 0.25 1
Chlorobenzene ND ug/L 10/03/15 00:17 108-90-70.50 0.25 1
Chloroethane ND ug/L 10/03/15 00:17 75-00-31.0 0.50 1
Chloroform ND ug/L 10/03/15 00:17 67-66-30.50 0.25 1
Chloromethane ND ug/L 10/03/15 00:17 74-87-31.0 0.50 1
2-Chlorotoluene ND ug/L 10/03/15 00:17 95-49-80.50 0.25 1
4-Chlorotoluene ND ug/L 10/03/15 00:17 106-43-40.50 0.25 1
1,2-Dibromo-3-chloropropane ND ug/L 10/03/15 00:17 96-12-81.0 0.50 1
Dibromochloromethane ND ug/L 10/03/15 00:17 124-48-10.50 0.25 1
1,2-Dibromoethane (EDB)ND ug/L 10/03/15 00:17 106-93-40.50 0.25 1
Dibromomethane ND ug/L 10/03/15 00:17 74-95-30.50 0.25 1
1,2-Dichlorobenzene ND ug/L 10/03/15 00:17 95-50-10.50 0.25 1
1,3-Dichlorobenzene ND ug/L 10/03/15 00:17 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/03/15 00:17 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/03/15 00:17 75-71-80.50 0.25 1
1,1-Dichloroethane ND ug/L 10/03/15 00:17 75-34-30.50 0.25 1
1,2-Dichloroethane ND ug/L 10/03/15 00:17 107-06-20.50 0.25 1
1,1-Dichloroethene ND ug/L 10/03/15 00:17 75-35-40.50 0.25 1
cis-1,2-Dichloroethene ND ug/L 10/03/15 00:17 156-59-20.50 0.25 1
trans-1,2-Dichloroethene ND ug/L 10/03/15 00:17 156-60-50.50 0.25 1
1,2-Dichloropropane ND ug/L 10/03/15 00:17 78-87-50.50 0.25 1
1,3-Dichloropropane ND ug/L 10/03/15 00:17 142-28-90.50 0.25 1
2,2-Dichloropropane ND ug/L 10/03/15 00:17 594-20-70.50 0.25 1
1,1-Dichloropropene ND ug/L 10/03/15 00:17 563-58-60.50 0.25 1
cis-1,3-Dichloropropene ND ug/L 10/03/15 00:17 10061-01-50.50 0.25 1
trans-1,3-Dichloropropene ND ug/L 10/03/15 00:17 10061-02-60.50 0.25 1
Diisopropyl ether ND ug/L 10/03/15 00:17 108-20-30.50 0.25 1
Ethylbenzene ND ug/L 10/03/15 00:17 100-41-40.50 0.25 1
Hexachloro-1,3-butadiene ND ug/L 10/03/15 00:17 87-68-3 M12.0 1.0 1
Isopropylbenzene (Cumene)ND ug/L 10/03/15 00:17 98-82-80.50 0.25 1
Methylene Chloride ND ug/L 10/03/15 00:17 75-09-22.0 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Sample:WSW-4 Lab ID:92270188002 Collected:09/28/15 17:02 Received:10/01/15 13:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methyl-tert-butyl ether ND ug/L 10/03/15 00:17 1634-04-40.50 0.25 1
Naphthalene ND ug/L 10/03/15 00:17 91-20-32.0 1.0 1
n-Propylbenzene ND ug/L 10/03/15 00:17 103-65-10.50 0.25 1
Styrene ND ug/L 10/03/15 00:17 100-42-50.50 0.25 1
1,1,1,2-Tetrachloroethane ND ug/L 10/03/15 00:17 630-20-60.50 0.25 1
1,1,2,2-Tetrachloroethane ND ug/L 10/03/15 00:17 79-34-50.50 0.25 1
Tetrachloroethene ND ug/L 10/03/15 00:17 127-18-40.50 0.25 1
Toluene ND ug/L 10/03/15 00:17 108-88-30.50 0.25 1
1,2,3-Trichlorobenzene ND ug/L 10/03/15 00:17 87-61-62.0 1.0 1
1,2,4-Trichlorobenzene ND ug/L 10/03/15 00:17 120-82-12.0 1.0 1
1,1,1-Trichloroethane ND ug/L 10/03/15 00:17 71-55-60.50 0.25 1
1,1,2-Trichloroethane ND ug/L 10/03/15 00:17 79-00-50.50 0.25 1
Trichloroethene ND ug/L 10/03/15 00:17 79-01-60.50 0.25 1
Trichlorofluoromethane ND ug/L 10/03/15 00:17 75-69-41.0 0.50 1
1,2,3-Trichloropropane ND ug/L 10/03/15 00:17 96-18-40.50 0.25 1
1,2,4-Trimethylbenzene ND ug/L 10/03/15 00:17 95-63-60.50 0.25 1
1,3,5-Trimethylbenzene ND ug/L 10/03/15 00:17 108-67-80.50 0.25 1
Vinyl chloride ND ug/L 10/03/15 00:17 75-01-41.0 0.25 1
m&p-Xylene ND ug/L 10/03/15 00:17 179601-23-11.0 0.50 1
o-Xylene ND ug/L 10/03/15 00:17 95-47-60.50 0.25 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %10/03/15 00:17 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %10/03/15 00:17 460-00-470-130 1
Toluene-d8 (S)102 %10/03/15 00:17 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33640
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92270188001, 92270188002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1573640
Associated Lab Samples:92270188001, 92270188002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/02/15 23:44
1,1,1-Trichloroethane ug/L ND 0.50 10/02/15 23:44
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/02/15 23:44
1,1,2-Trichloroethane ug/L ND 0.50 10/02/15 23:44
1,1-Dichloroethane ug/L ND 0.50 10/02/15 23:44
1,1-Dichloroethene ug/L ND 0.50 10/02/15 23:44
1,1-Dichloropropene ug/L ND 0.50 10/02/15 23:44
1,2,3-Trichlorobenzene ug/L ND 2.0 10/02/15 23:44
1,2,3-Trichloropropane ug/L ND 0.50 10/02/15 23:44
1,2,4-Trichlorobenzene ug/L ND 2.0 10/02/15 23:44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/02/15 23:44
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/02/15 23:44
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/02/15 23:44
1,2-Dichlorobenzene ug/L ND 0.50 10/02/15 23:44
1,2-Dichloroethane ug/L ND 0.50 10/02/15 23:44
1,2-Dichloropropane ug/L ND 0.50 10/02/15 23:44
1,3,5-Trimethylbenzene ug/L ND 0.50 10/02/15 23:44
1,3-Dichlorobenzene ug/L ND 0.50 10/02/15 23:44
1,3-Dichloropropane ug/L ND 0.50 10/02/15 23:44
1,4-Dichlorobenzene ug/L ND 0.50 10/02/15 23:44
2,2-Dichloropropane ug/L ND 0.50 10/02/15 23:44
2-Chlorotoluene ug/L ND 0.50 10/02/15 23:44
4-Chlorotoluene ug/L ND 0.50 10/02/15 23:44
Benzene ug/L ND 0.50 10/02/15 23:44
Bromobenzene ug/L ND 0.50 10/02/15 23:44
Bromochloromethane ug/L ND 0.50 10/02/15 23:44
Bromodichloromethane ug/L ND 0.50 10/02/15 23:44
Bromoform ug/L ND 0.50 10/02/15 23:44
Bromomethane ug/L ND 5.0 10/02/15 23:44
Carbon tetrachloride ug/L ND 0.50 10/02/15 23:44
Chlorobenzene ug/L ND 0.50 10/02/15 23:44
Chloroethane ug/L ND 1.0 10/02/15 23:44
Chloroform ug/L ND 0.50 10/02/15 23:44
Chloromethane ug/L ND 1.0 10/02/15 23:44
cis-1,2-Dichloroethene ug/L ND 0.50 10/02/15 23:44
cis-1,3-Dichloropropene ug/L ND 0.50 10/02/15 23:44
Dibromochloromethane ug/L ND 0.50 10/02/15 23:44
Dibromomethane ug/L ND 0.50 10/02/15 23:44
Dichlorodifluoromethane ug/L ND 0.50 10/02/15 23:44
Diisopropyl ether ug/L ND 0.50 10/02/15 23:44
Ethylbenzene ug/L ND 0.50 10/02/15 23:44
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
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Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1573640
Associated Lab Samples:92270188001, 92270188002
Matrix:Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 10/02/15 23:44
Isopropylbenzene (Cumene)ug/L ND 0.50 10/02/15 23:44
m&p-Xylene ug/L ND 1.0 10/02/15 23:44
Methyl-tert-butyl ether ug/L ND 0.50 10/02/15 23:44
Methylene Chloride ug/L ND 2.0 10/02/15 23:44
n-Butylbenzene ug/L ND 0.50 10/02/15 23:44
n-Propylbenzene ug/L ND 0.50 10/02/15 23:44
Naphthalene ug/L ND 2.0 10/02/15 23:44
o-Xylene ug/L ND 0.50 10/02/15 23:44
sec-Butylbenzene ug/L ND 0.50 10/02/15 23:44
Styrene ug/L ND 0.50 10/02/15 23:44
tert-Butylbenzene ug/L ND 0.50 10/02/15 23:44
Tetrachloroethene ug/L ND 0.50 10/02/15 23:44
Toluene ug/L ND 0.50 10/02/15 23:44
trans-1,2-Dichloroethene ug/L ND 0.50 10/02/15 23:44
trans-1,3-Dichloropropene ug/L ND 0.50 10/02/15 23:44
Trichloroethene ug/L ND 0.50 10/02/15 23:44
Trichlorofluoromethane ug/L ND 1.0 10/02/15 23:44
Vinyl chloride ug/L ND 1.0 10/02/15 23:44
1,2-Dichloroethane-d4 (S)%101 70-130 10/02/15 23:44
4-Bromofluorobenzene (S)%100 70-130 10/02/15 23:44
Toluene-d8 (S)%101 70-130 10/02/15 23:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1573641LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.750 101 60-140
1,1,1-Trichloroethane ug/L 55.250 110 60-140
1,1,2,2-Tetrachloroethane ug/L 51.550 103 60-140
1,1,2-Trichloroethane ug/L 50.250 100 60-140
1,1-Dichloroethane ug/L 53.350 107 60-140
1,1-Dichloroethene ug/L 53.850 108 60-140
1,1-Dichloropropene ug/L 52.550 105 60-140
1,2,3-Trichlorobenzene ug/L 47.450 95 60-140
1,2,3-Trichloropropane ug/L 47.750 95 60-140
1,2,4-Trichlorobenzene ug/L 47.950 96 60-140
1,2,4-Trimethylbenzene ug/L 52.150 104 60-140
1,2-Dibromo-3-chloropropane ug/L 51.850 104 60-140
1,2-Dibromoethane (EDB)ug/L 52.150 104 60-140
1,2-Dichlorobenzene ug/L 50.650 101 60-140
1,2-Dichloroethane ug/L 46.550 93 60-140
1,2-Dichloropropane ug/L 50.250 100 60-140
1,3,5-Trimethylbenzene ug/L 52.950 106 60-140
1,3-Dichlorobenzene ug/L 50.450 101 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
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Huntersville, NC 28078
[phone]
Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1573641LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 50.550 101 60-140
1,4-Dichlorobenzene ug/L 49.950 100 60-140
2,2-Dichloropropane ug/L 49.550 99 60-140
2-Chlorotoluene ug/L 51.750 103 60-140
4-Chlorotoluene ug/L 51.050 102 60-140
Benzene ug/L 52.850 106 60-140
Bromobenzene ug/L 50.550 101 60-140
Bromochloromethane ug/L 53.450 107 60-140
Bromodichloromethane ug/L 51.050 102 60-140
Bromoform ug/L 49.450 99 60-140
Bromomethane ug/L 45.950 92 60-140
Carbon tetrachloride ug/L 54.150 108 60-140
Chlorobenzene ug/L 50.250 100 60-140
Chloroethane ug/L 45.950 92 60-140
Chloroform ug/L 50.050 100 60-140
Chloromethane ug/L 55.550 111 60-140
cis-1,2-Dichloroethene ug/L 51.650 103 60-140
cis-1,3-Dichloropropene ug/L 51.650 103 60-140
Dibromochloromethane ug/L 51.650 103 60-140
Dibromomethane ug/L 51.650 103 60-140
Dichlorodifluoromethane ug/L 46.050 92 60-140
Diisopropyl ether ug/L 55.250 110 60-140
Ethylbenzene ug/L 52.150 104 60-140
Hexachloro-1,3-butadiene ug/L 67.850 136 60-140
Isopropylbenzene (Cumene)ug/L 56.350 113 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 53.850 108 60-140
Methylene Chloride ug/L 49.150 98 60-140
n-Butylbenzene ug/L 54.650 109 60-140
n-Propylbenzene ug/L 52.850 106 60-140
Naphthalene ug/L 50.750 101 60-140
o-Xylene ug/L 51.850 104 60-140
sec-Butylbenzene ug/L 56.250 112 60-140
Styrene ug/L 53.250 106 60-140
tert-Butylbenzene ug/L 44.850 90 60-140
Tetrachloroethene ug/L 49.950 100 60-140
Toluene ug/L 51.750 103 60-140
trans-1,2-Dichloroethene ug/L 52.450 105 60-140
trans-1,3-Dichloropropene ug/L 50.650 101 60-140
Trichloroethene ug/L 51.250 102 60-140
Trichlorofluoromethane ug/L 55.250 110 60-140
Vinyl chloride ug/L 56.950 114 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1573642MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92270188002
1573643
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 105 60-140104 1 3020ND20.9 20.7
1,1,1-Trichloroethane ug/L 20 130 60-140123 6 3020ND26.1 24.7
1,1,2,2-Tetrachloroethane ug/L 20 111 60-140110 1 3020ND22.3 22.0
1,1,2-Trichloroethane ug/L 20 109 60-140108 1 3020ND21.7 21.5
1,1-Dichloroethane ug/L 20 124 60-140119 4 3020ND24.7 23.7
1,1-Dichloroethene ug/L 20 130 60-140126 3 3020ND26.0 25.1
1,1-Dichloropropene ug/L 20 126 60-140119 6 3020ND25.3 23.8
1,2,3-Trichlorobenzene ug/L 20 101 60-14092 10 3020ND20.3 18.4
1,2,3-Trichloropropane ug/L 20 104 60-140104 0 3020ND20.8 20.7
1,2,4-Trichlorobenzene ug/L 20 105 60-14096 9 3020ND21.0 19.3
1,2,4-Trimethylbenzene ug/L 20 113 60-140111 2 3020ND22.6 22.2
1,2-Dibromo-3-
chloropropane ug/L 20 106 60-14099 7 3020ND21.1 19.8
1,2-Dibromoethane (EDB)ug/L 20 111 60-140111 0 3020ND22.2 22.2
1,2-Dichlorobenzene ug/L 20 110 60-140107 3 3020ND22.0 21.3
1,2-Dichloroethane ug/L 20 103 60-14099 3 3020ND20.6 20.0
1,2-Dichloropropane ug/L 20 113 60-140109 3 3020ND22.5 21.9
1,3,5-Trimethylbenzene ug/L 20 117 60-140114 3 3020ND23.5 22.7
1,3-Dichlorobenzene ug/L 20 112 60-140108 4 3020ND22.5 21.7
1,3-Dichloropropane ug/L 20 108 60-140109 1 3020ND21.6 21.8
1,4-Dichlorobenzene ug/L 20 111 60-140108 3 3020ND22.3 21.5
2,2-Dichloropropane ug/L 20 119 60-140105 13 3020ND23.9 21.0
2-Chlorotoluene ug/L 20 113 60-140109 3 3020ND22.5 21.8
4-Chlorotoluene ug/L 20 114 60-140111 3 3020ND22.9 22.2
Benzene ug/L 20 121 60-140116 5 3020ND24.3 23.1
Bromobenzene ug/L 20 111 60-140109 1 3020ND22.1 21.8
Bromochloromethane ug/L 20 119 60-140112 6 3020ND23.8 22.5
Bromodichloromethane ug/L 20 111 60-140106 5 3020ND22.2 21.2
Bromoform ug/L 20 98 60-14091 7 3020ND19.6 18.2
Bromomethane ug/L 20 115 60-140107 8 3020ND23.1 21.3
Carbon tetrachloride ug/L 20 127 60-140123 3 3020ND25.3 24.5
Chlorobenzene ug/L 20 112 60-140111 1 3020ND22.4 22.1
Chloroethane ug/L 20 114 60-140110 4 3020ND22.9 21.9
Chloroform ug/L 20 117 60-140110 6 3020ND23.6 22.2
Chloromethane ug/L 20 120 60-140121 1 3020ND24.0 24.2
cis-1,2-Dichloroethene ug/L 20 118 60-140114 4 3020ND23.5 22.7
cis-1,3-Dichloropropene ug/L 20 108 60-140100 8 3020ND21.6 20.0
Dibromochloromethane ug/L 20 105 60-140101 3 3020ND20.9 20.2
Dibromomethane ug/L 20 111 60-140106 4 3020ND22.3 21.3
Dichlorodifluoromethane ug/L 20 97 60-140113 14 3020ND19.5 22.5
Diisopropyl ether ug/L 20 123 60-140117 5 3020ND24.6 23.3
Ethylbenzene ug/L 20 116 60-140116 0 3020ND23.3 23.3
Hexachloro-1,3-butadiene ug/L M12017060-140143 17 3020ND33.9 28.6
Isopropylbenzene (Cumene)ug/L 20 124 60-140124 1 3020ND24.8 24.9
m&p-Xylene ug/L 40 115 60-140113 2 3040ND46.1 45.3
Methyl-tert-butyl ether ug/L 20 118 60-140112 5 3020ND23.5 22.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1573642MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92270188002
1573643
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 108 60-140101 6 3020ND21.6 20.3
n-Butylbenzene ug/L 20 117 60-140113 4 3020ND23.4 22.6
n-Propylbenzene ug/L 20 120 60-140116 3 3020ND23.9 23.2
Naphthalene ug/L 20 111 60-14095 16 3020ND22.2 19.0
o-Xylene ug/L 20 115 60-140114 1 3020ND23.0 22.7
sec-Butylbenzene ug/L 20 125 60-140122 3 3020ND25.1 24.4
Styrene ug/L 20 112 60-140113 0 3020ND22.5 22.5
tert-Butylbenzene ug/L 20 98 60-14096 2 3020ND19.7 19.3
Tetrachloroethene ug/L 20 114 60-140112 2 3020ND22.7 22.3
Toluene ug/L 20 118 60-140116 1 3020ND23.6 23.3
trans-1,2-Dichloroethene ug/L 20 123 60-140118 4 3020ND24.6 23.6
trans-1,3-Dichloropropene ug/L 20 107 60-140100 7 3020ND21.5 19.9
Trichloroethene ug/L 20 117 60-140114 2 3020ND23.4 22.8
Trichlorofluoromethane ug/L 20 133 60-140132 1 3020ND26.7 26.4
Vinyl chloride ug/L 20 133 60-140133 0 3020ND26.6 26.7
1,2-Dichloroethane-d4 (S)%101 70-13099
4-Bromofluorobenzene (S)%101 70-130101
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/38184
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92270188001, 92270188002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1575064
Associated Lab Samples:92270188001, 92270188002
Matrix:Water
Analyzed
1,2-Dibromo-3-chloropropane ug/L ND 0.050 10/07/15 11:11
1,2-Dibromoethane (EDB)ug/L ND 0.020 10/07/15 11:11
1-Chloro-2-bromopropane (S)%103 70-130 10/07/15 11:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1575065LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1575066
1,2-Dibromo-3-chloropropane ug/L 0.30.28 106 70-1301120.33 9 20
1,2-Dibromoethane (EDB)ug/L 0.25.28 88 70-130920.27 8 20
1-Chloro-2-bromopropane (S)%103 70-130106
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1575067MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92270183001
1575068
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dibromo-3-
chloropropane ug/L .28 112 65-135114 2 20.28<0.049 0.31 0.32
1,2-Dibromoethane (EDB)ug/L .28 90 65-13590 0 20.28<0.020 0.25 0.25
1-Chloro-2-bromopropane
(S)
%104 70-130101
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92270183002
1575069SAMPLE DUPLICATE:
1,2-Dibromo-3-chloropropane ug/L ND 20<0.049
1,2-Dibromoethane (EDB)ug/L ND 20<0.020
1-Chloro-2-bromopropane (S)%105 1103
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92270188
Moore's Store 4305-15-159
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92270188001 OEXT/38184 GCSV/22816WSW-2 EPA 504.1 EPA 504.1
92270188002 OEXT/38184 GCSV/22816WSW-4 EPA 504.1 EPA 504.1
92270188001 MSV/33640WSW-2 SM 6200B
92270188002 MSV/33640WSW-4 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 10/08/2015 03:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 20
Page 19 of 20
Page 20 of 20