WS_4900_16457_CA_MRP_20230623

MONITORING REPORT

Stephens Exxon

20655 NC Highway 88 West
Creston, Ashe County, North Carolina 28615
NCDEQ Incident #16457
ATC Project #STL1645701

Submittal Date:
June 23, 2023

Prepared For:
NCDEQ, DWM, UST Section (State Lead)
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Prepared By:
ATC Associates of North Carolina, P.C.
7606 Whitehall Executive Center Drive, Suite 800
Charlotte, North Carolina 28273
p: [phone] / f: [phone]
www.atcgroupservices.com

7606 Whitehall Executive Center Drive
Suite 800
Charlotte, NC 28273
Tel: [phone]
Fax: [phone]
www.oneatlas.com
N.C. Engineering License No. C-1598

June 23, 2023

Mr. Mark Petermann, P.G.
North Carolina Department of Environmental Quality
Division of Waste Management - Underground Storage Tank Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646

Re: Monitoring Report
Stephens Exxon
20655 North Carolina Highway 88 West
Creston, Ashe County, North Carolina 28615
NCDEQ Incident #16457
ATC Project #STL1645701
Task Authorization: TA-01

Dear Mr. Petermann:

ATC Associates of North Carolina, P.C. is submitting the enclosed Monitoring Report for
the Stephens Exxon site located at 20655 North Carolina Highway 88 West in Creston,
NC. The work was performed based on the April 12, 2023, Task Authorization (TA-01) by
the Trust Fund Branch of the Underground Storage Tank (UST) Section, Division of Waste
Management, North Carolina Department of Environmental Quality (NCDEQ). The work is
being performed as part of the State Lead Contract #N70522-B between NCDEQ and
ATC. If you have any questions or require additional information, please contact our office
at [phone].

Sincerely,

ATC Associates of North Carolina, P.C.

Vanessa Hunter Al Quarles, P.G.
Staff Scientist Senior Project Manager

Monitoring Report June 23, 2023
Stephens Exxon – NCDEQ Incident #16457 ATC Project #STL1645701

TABLE OF CONTENTS

1.0 SITE IDENTIFICATION .......................................................................... 1
2.0 EXECUTIVE SUMMARY ........................................................................ 2
3.0 SITE DESCRIPTION .............................................................................. 3
3.1 Site Characterization .................................................................... 3
3.2 Site Background ........................................................................... 3
3.3 Site and Regional Geology .......................................................... 5
3.4 Site and Regional Hydrogeology .................................................. 6
4.0 GROUNDWATER CHARACTERIZATION ............................................. 7
4.1 Water Supply Wells ...................................................................... 7
4.2 Groundwater Levels ..................................................................... 7
4.3 Groundwater Quality .................................................................... 8
5.0 CONCLUSIONS AND RECOMMENDATIONS ...................................... 9

TABLES
Table 1 Water Supply Well Information
Table 2 Recent Water Supply Well Analytical Data
Table 3 Historical Water Supply Well Analytical Data
Table 4 Monitoring Well Construction and Groundwater Elevation Data
Table 5 Field Parameters
Table 6 Recent Groundwater Analytical Data
Table 7 Historical Groundwater Analytical Data

FIGURES
Figure 1 Site Location Map
Figure 2 Site Vicinity Map with Water Supply Well Locations
Figure 3 Site Map
Figure 4 Groundwater Elevation Contour Map
Figure 5 Groundwater Quality Map

APPENDICES
Appendix A Conceptual Site Model
Appendix B Field Notes and Photographs
Appendix C Laboratory Report

MonitoringReportStephensExxon-NCDEQIncident#16457June23,2023ATCProject#STL16457011.0SITEIDENTIFICATION1.SiteIdentificationDateofReport:June23,2023FacilityI.D.:00-0-0000000453SiteRisk:HighSiteRank:0090DLandUseCategory:ResidentialSiteName:StephensExxonSiteStreetAddress:20655NCHighway88WestZipCode:28615County:AsheDescriptionofGeographicalDataPoint:CenterofsiteLocationMethod:GoogleEarthLatitude(decimaldegrees):36.40148Longitude(decimaldegrees):-81.69336USTIncidentNumber(ifknown):16457City/Town:Creston2.InformationaboutContactsAssociatedwiththeLeakingUSTSystemUSTOwner:SegravesOilCompany,Inc.Address:P.O.Box970,Jefferson.NorthCarolina28640USTOperator:NotListedAddress:NotAvailablePropertyOwner:VincentBoccardyandCourtneyCutilloAddress:420BarlowRoad,Creston.NC28615PropertyOwner:VincentBoccardyandCourtneyCutilloAddress:420BarlowRoad,Creston,NC28615Consultant/Contractor:ATCAssociatesofNorthCarolina.P.C.Address:7606WhitehallExecutiveCenterDrive,Charlotte.NC28273Tel.:[phone]AnalyticalLaboratory:PaceAnalyticalServices,LLCAddress:9800KinceyAvenue,Suite100Huntersville,NorthCarolinaTel:704-875-9092Tel.:UnknownTel.:UnknownTel.:[phone]Tel.:[phone]StateCertificationNo.123.InformationaboutReleaseDateDiscovered:October7,1996EstimatedQuantityofRelease:UnknownCauseofRelease:LeakingproductlinesSourceofRelease(Dispenser/Piping/UST):USTSystemSizesandcontentsofUSTsystem(s)fromwhichthereleaseoccurred:Three(3)2,000-gallongasolineUSTs,one560gallonKeroseneUST.CriteriaUsedtoClassifyRisk:HistoricalpresenceofLNAPLinmonitoringwellMW-11;potentialrisktositewatersupplywellWSW-8within60feetofwellMW-11,Exceedancesof2LStandardsand2BStandardsbymorethan10timeswithsurfacewaterwithin500feet.4.InformationabouttheMonitoringReportDateofGroundwaterMonitoringEvents:May15-16,20235.0CertificationI,AlQuarles,aProfessionalGeologistforATCAssociatesofNorthCarolina,P.C..docertifythattheinformationcontainedinthisreportiscorrectandaccuratetothebestofmyknowledge.ATCAssociatesofNorthCarolina,P.C.islicensedtopracticegeologyandengineeringinNorthCarolina.ThecertificationnumberofthecompanyorcorporationisC-1598forengineeringandC-294forgeology.1
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2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) has performed consulting services for
Stephens Exxon, located at 20655 North Carolina Highway 88 West, Creston, Ashe County, North
Carolina. The adjoining properties include residential with limited commercial use to the north and
west, with agricultural use to the south and east to a tributary of the North Fork River. This work
was performed based on the April 12, 2023 Task Authorization (TA-01) by the Trust Fund Branch
of the Underground Storage Tank (UST) Section, Division of Waste Management, North Carolina
Department of Environmental Quality (NCDEQ). The work was performed as part of the State Lead
Contract # N70522-B between NCDEQ and ATC.

As of May 2023, the site is used as a workshop by the current property owners (purchased May
18, 2021). According to previous reports, there appear to be two separate plumes at the site: a
gasoline plume located on the northeastern section of the site in the vicinity of MW-5R and a
kerosene plume located west of the on-site building near MW-11.

Former petroleum USTs at the site released petroleum product to the subsurface which was
reported during the removal of the USTs on October 7, 1996. Three 2,000-gallon gasoline USTs
and one 560-gallon kerosene UST were identified in the NCDEQ Registered UST Database.

During May 15 and 16, 2023, ATC sampled groundwater monitoring wells MW-2, MW-3, MW-5R,
MW-7, MW-11, MW-12, MW-13, MW-14, MW-16, and MW-17, air sparge well AS-1, and water
supply well WSW-8. All samples were analyzed for volatile organic compounds (VOCs) using
Standard Method (SM) 6200B and samples from wells MW-11, MW-13, AS-1, and WSW-8 were
also analyzed for semi-volatile organic compounds (SVOCs) using EPA Method 625. ATC also
measured the depth to groundwater and measured the top of casing elevations for all monitoring
wells accessible on May 15 and 16, 2023. Monitoring well MW-4 could not be sampled due to a
bent casing, monitoring wells MW-1, MW-6, MW-8, MW-9, and MW-10 could not be located, and
monitoring well MW-15 could not be accessed for sampling on May 16, 2023 due to vehicle parked
over the well. The following site conditions are noted based on the recent and historical
assessment activities and are listed in the Conceptual Site Model (Appendix A):

 Six water supply wells or springs are located within 1,000 feet of the source areas including
three wells within 500 feet of the source areas. The “most at risk wells” include the on-site
water supply well WSW-8 located approximately 60 feet from the kerosene release source
area and approximately 160 feet southwest of the gasoline release source area. The other
water supply wells do not appear to be at risk due to the locations and distances from the
source areas. Municipal water is not available to the area;
 Tributaries to the North Fork New River and the North Fork New River are located within
500 feet of the source areas;
 Recent monitoring well sampling results indicated exceedances of the 15A NCAC 02L
Groundwater Quality Standards (2L Standards) in wells MW-5R, MW-11, and MW-17, and
exceedances of the 15A NCAC 2B Surface Water Quality Standards (2B Standards) by
more than 10 times in well MW-5R. None of the reported concentrations of constituents
exceeded the Gross Contamination Levels (GCLs);
 Based on the groundwater level data, groundwater flow is generally to the southeast;
 Based on the recent and historical groundwater quality data, the extent of the two
contaminant plumes appear to be defined and stable. VOC concentrations in MW-5R have
generally decreased with time, and appear to be generally stable in wells MW-11 and MW-
17. Light non-aqueous phase liquid or LNAPL (kerosene) was previously observed in well
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MW-11, but has not been detected since April 19, 2022, following the May 2022 Mobile
Multi-Phase Extraction and Air Sparge (MMPE/AS) event.

Based on the information provided in this report, ATC recommends the following:
 Continue to sample selected monitoring wells (MW-4, MW-5R, MW-6, MW-11, MW-13,
MW-14, MW-15) and water supply well WSW-8. Evaluate results for plume stability based
on the previous Fate & Transport Model results;
 Conduct additional MMPE/AS events in the area of the two plumes to reduce VOC
concentrations in pursuit of closing the incident;
 Consider installation of a replacement water supply well for WSW-8, either on the source
property, the property to the east (owned by Joseph S. Stephens, Jr., a prior owner of the
source property), or the property to the south (owned by Joyce Stephens (L/E), a prior
owner of the source property); and
 Attempt to locate wells that could not be located in May 2023 and remeasure the top of
casings of the wells.

3.0 SITE DESCRIPTION
3.1 Site Characterization
The NCDEQ retained ATC to provide environmental consulting services for Stephens Exxon,
located at 20655 North Carolina Highway 88 West, Creston, Ashe County, North Carolina. Figure
1 depicts the site location on a topographic map. The site building serves as a personal workshop
and storage for the property owner. Three water supply wells have been previously identified within
1,000 feet of the site, with the on-site well WSW-8 located approximately 60 feet from the former
kerosene UST considered the only “at risk” well. Municipal water is not available to the site vicinity.
Figure 2 indicates the location of water supply wells in the site vicinity, and Table 1 provides the
water supply well information.

3.2 Site Background
The site formerly operated as Joe Stephen’s Exxon which utilized a UST system consisting of
three 2,000-gallon gasoline USTs and one 560-gallon kerosene UST. The gasoline USTs were
located near the northeast corner of the existing building. The kerosene UST was located along
the west side of the existing building. The gasoline USTs were installed on May 5, 1975 and
removed on October 7, 1996. The kerosene UST was installed May 4, 1976 and removed on
August 13, 1998. On may 18, 2021, Vincent Boccardy and Courtney D. Cutillo purchased the
source property from Richard J. and Linda O. Gouger, who purchased the source property from
Joyce Stephens (widow) on June 15, 2012.

Tank closure activities included the removal of the USTs and post-removal sampling. Soil
samples collected from the floor of the gasoline UST basin and near the former dispenser
location indicated total petroleum hydrocarbon gasoline-range organics (TPH-GRO) impact
above the North Carolina State Action Level. Monitoring well MW-1 was installed by Salem
Environmental on October 23, 1996.

Geonetics Corporation (Geonetics) completed a Comprehensive Site Assessment (CSA) on
July 18, 1997. According to CSA, shallow monitoring wells MW-2 through MW-6 and two
temporary wells (TW-2 and TW-3) were installed in March 1997 by Geonetics to further
delineate the petroleum impact at the site. A deep aquifer monitoring well, MW-7 was installed
on June 4, 1997. During subsequent groundwater monitoring events, petroleum impact was
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identified in samples collected from monitoring wells MW-1, MW-5, and TW-2 above 2L
Standards. The CSA also identified possible receptors within 1,500 feet of the site.

In March 1998, Geonetics installed two additional shallow monitoring wells MW-8 and MW-9.
On August 13, 1998, Geonetics completed the excavation and removal of the kerosene UST.
Approximately 7.3 cubic yards of contaminated soil was removed from the excavation. Soil
samples were collected from the bottom of the UST basin and below the dispenser location. A
composite sample was also collected from the excavated contaminated soil. Soil analysis
indicated contamination exceeding the Soil-to-Groundwater Maximum Soil Contaminant
Concentrations (MSCCs) in the samples collected from the UST basin and dispenser location.
None of the detected concentrations exceed residential MSCCs. Volatile and Semi-Volatile TPH
were detected in the excavated soil at concentrations of 265.8 parts per million (ppm) and 1,524
ppm, respectively. Geonetics concluded that groundwater contamination was due to releases
from the gasoline and kerosene UST systems. In 1998, Geonetics also submitted a Corrective
Action Plan (CAP) proposing remedial actions at the site. Geonetics proposed corrective action
alternatives including soil excavation, a soil vapor extraction system (SVE), and natural
attenuation.

Between June 30, 2003 and July 3, 2004 approximately 832.83 tons of contaminated soil was
removed from the areas of the gasoline USTs and the kerosene UST. Post-excavation sampling
indicated that contaminated soil had been removed except for soils beneath the water table and
underneath the site building. Remaining impact exceeded soil-to-groundwater MSCCs;
however, concentrations did not exceed residential MSCCs. During the time period, monitoring
wells MW-11 and MW-12 were installed to further delineate petroleum impact. In 2004,
Geonetics conducted groundwater monitoring of the site monitoring wells which indicated
petroleum impact above 2L Standards in monitoring wells MW-5 and MW-11. Post-excavation
soil samples were analyzed for petroleum constituents by Standard Method 8021 and MADEP
VPH Method.

In February 2011, Terraine Environmental (Terraine) conducted groundwater monitoring at the
site. Monitoring well MW-11 contained one foot of measurable LNAPL. Petroleum impact was
identified in monitoring wells MW-2, MW-3, MW-4, MW-7, and MW-12. Results from the
groundwater sampling event did not indicate impact above 2L Standards; however, monitoring
well MW-5 which historically contained impact, was not sampled. In August 2011, Terraine
completed an AFVR on monitoring well MW-11. A total of 175 gallons of petroleum impacted
water was removed from the well. Upon completion of the AFVR event, 0.2 feet of LNAPL was
remaining in well MW-11. A post-AFVR sampling event was conducted at the site which
indicated a decrease in impact in monitoring wells MW-4 and MW-12. Following the
groundwater monitoring event, a Universal Remediation, Inc., PRP® Well Boom was installed in
monitoring well MW-11 to aid in biodegradation of petroleum constituents.

Subsequent groundwater monitoring events were performed at the site in 2012 and 2013 by
Crawford Environmental Services. According to the GMR, LNAPL continued to be observed in
monitoring well MW-11. Monitoring wells MW-5 and MW-6 were reported as destroyed and
were not sampled. Detectable levels of one or more petroleum constituents were observed in
monitoring wells MW-3 and MW-12.

ATC completed a groundwater monitoring event in October 2014, during which time monitoring
well MW-5 was located. LNAPL was identified in monitoring well MW-11 at a thickness of 0.76
feet. Groundwater impact above 2L Standards was identified in monitoring well MW-5 for
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multiple constituents. No additional impact above 2L Standards was identified in the monitoring
well network.

ATC sampled groundwater monitoring wells MW-2, MW-3, MW-4, and MW-12 on August 9,
2018. During this sampling event, free-phase petroleum was identified in MW-11 at a thickness
of 1.18 feet. Monitoring wells MW-4 and MW-12 contained concentrations of isopropyl ether and
sec-butylbenzene, respectively, at concentrations below the 2L Standards. Monitoring wells MW-2
and MW-3 did not contain detectable concentrations of petroleum constituents.

On March 14, 2019, monitoring wells MW-5R and MW-13 were installed to delineate the petroleum
plume at the site. Monitoring well MW-5R replaced former well MW-5. Wells MW-5R and MW-13
were installed using hollow-stem auger technology to 14 feet below ground surface (ft bgs) and 12
ft bgs, respectively. During the monitoring well installation, the driller raised the access port of
monitoring well MW-11, which was previously beneath approximately eight inches of compacted
gravel. Well MW-11 was also finished with a flush mounted square well pad.

In August 2021, a Mobile Multi-Phase Extraction (MMPE) was conducted by Terracon Consultants,
Inc (Terracon) at monitoring well MW-7 and removed approximately 8 gallons of liquid free product
and 3.33 gallons of VOCs as vapor.

In April 2022, recovery well RW-1 and air sparge well AS-1 were installed by Terracon and
Environmental Drilling & Probing Services (EDPS) in the vicinity of the kerosene plume on the west
side of the on-site building. Following installation, Terracon performed a 96-hour MMPE/AS event
in May 2022, using well RW-1 as the extraction well while sparging in AS-1. Approximately 7.67
gallons of petroleum hydrocarbons were recovered as vapors, 6 gallons free product was
recovered as liquid, and 2,670 gallons of petroleum impacted groundwater were removed during
this event. A groundwater sampling event was performed post-MMPE/AS on May 10, 2022.
Terracon sampled groundwater monitoring wells MW-11, MW-13, and MW-14. LNAPL was not
detected, although a “petroleum odor” was noted from the MW-11 purge water. Terracon
concluded concentrations of VOCs have generally decreased in monitoring wells MW-11, MW-12,
and MW-14 since September 2021.

On September 26, 2022 Terracon sampled monitoring wells MW-4, MW-5R, MW-11, MW-13, MW-
15, and MW-17. MW-5R and MW-11 contained constituents above 2L Standards. Terracon also
conducted a fate and transport evaluation on both sources areas to determine the possibility for
migration to receptors WSW-8, WSW-9, and the North Fork of the New River. The fate and
transport model predicted that contaminant concentrations are not likely to exceed the 2L
Standards when steady state conditions are achieved, but may be impacted at levels below the 2L
standards.

3.3 Site and Regional Geology

According to the Geologic Map of North Carolina, produced by the State of North Carolina in
1985, the site lies in an area of unconformity in the Blue Ridge Belt of North Carolina. The rock
type at the site has been identified as biotite granitic gneiss. In most areas, the upper Blue
Ridge subsurface consists of unconsolidated residual soil, variously known as residuum,
saprolite, or partially weathered rock (PWR) that has developed from in-place weathering of the
underlying metamorphic bedrock. The residual soils vary in consistency and depth based on
local conditions. Bedrock can be found at depths ranging from the surface as outcrops down to
greater than 100 feet in areas of easily weathered rock types. Areas near streams and rivers in
the Blue Ridge may also contain alluvium deposited during flood events.
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According to available soil boring logs and excavation records for the site, soils encountered
consisted of 10 to 15 feet of silty sand to sandy silt (fill material) around the site building, 2 to 6
feet of sandy silt (alluvium), 0.5 feet to 2 feet of a reported cobble layer (reported as a 15-foot
layer of cobbles and gravel from 15 to 30 ft-bgs at the deep well MW-7), and bedrock
(amphibolite with quartz) at 30 ft-bgs. Monitoring well MW-7 was screened in the bedrock.
Auger refusal was reported in MW-13 at 12 feet, which may have been the cobble layer rather
than bedrock.

Based on the soil conditions observed during the installation of groundwater monitoring wells
MW-14, MW-15, MW-16 and MW-17, the “cobble” layer consists of a poorly sorted sandy silty
gravel with cobbles. The soil immediately above the gravel layer consists of a silty sand, which
appeared to contain more water than the “cobble” layer, and presumably more permeable that
the underlying “cobble” layer. The soil beneath the “cobble” layer consists of silt, likely residual
soil weathered from the underlying bedrock, and of lower permeability than the overlying
“cobble” layer.

3.4 Site and Regional Hydrogeology

The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and
rivers to as deep as 50 feet or more beneath upland surfaces in some parts of the Blue Ridge.
ATC encountered groundwater between 2.35 feet below the top of casings (ft-toc) in MW-17 to
12.00 ft-toc in MW-5R during the May 2023 monitoring event. Water in the alluvium or
unconsolidated residual material, including saprolite and PWR, usually behaves as an
unconfined aquifer, or water table, and will yield water with head elevation equivalent to the first
elevation where water was encountered. Permeability varies with lithology and is typically
relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Groundwater flow in residual soils or alluvium is usually in rough concurrence with local
topographic conditions and is toward local drainage features.

The bedrock fractures or other planar features of the Blue Ridge Physiographic Province
generally constitute the bedrock aquifer, with the surrounding rock material being effectively
impermeable. Along with fractures, contacts between rock bodies probably constitute zones of
significant groundwater occurrence in the bedrock. The surrounding material and overlying
residuum tend to make the bedrock aquifer a semi-confined aquifer. That is, the overlying water
and soil weight normally results in pressure that causes water in a borehole, which intersects a
fracture or other feature, to rise above the elevation of the fracture or feature. Most modern
water supply wells in the Blue Ridge consist of a casing set through the residual soils into the
upper bedrock followed by an open borehole into the bedrock where water-bearing fractures
were encountered during the drilling. Except for sampling of the site and nearby water supply
wells, evaluation of bedrock water quality or hydrology was beyond the scope of the GMR.

Based on recent and historical groundwater level measurements at the site, the groundwater
flow is to the southeast toward the North Fork New River (classified as Class C, Trout Waters,
Outstanding Resource Waters). The North Fork New River is located approximately 470 feet
from the former UST basin. Locally, a spring located north of monitoring well MW-2 is piped
approximately 500 feet underground to the east into surface water described as a “pool” by
Geonetics in the Comprehensive Site Assessment Report dated July 18, 1997. On the west side
of the site, two tributaries to the North Fork New River are located approximately 70 and 120
feet west and southwest of the kerosene release area. The tributaries converge approximately
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150 feet southwest of the kerosene source area then piped below ground to the southeast
toward the river. The location of this pipe at the river is not known. Older topographic maps
indicated that this tributary flowed to the east from the approximate beginning of the piped
section. There is also a septic drain field located southeast of the site building. The influence on
groundwater flow from these features has not been established; however, recent groundwater
level data do not suggest that the piped spring and tributaries are significantly impacting the
local groundwater surface.

Note that prior groundwater sampling data from monitoring wells MW-8 and MW-9 located
downgradient of the site and screened within the gravel (and possibly cobble) layer, did not
indicate groundwater impact exceeding 2L Standards. Excluding wells MW-8 and MW-9, it
considered likely that the groundwater surface is at a depth shallower than the cobble layer,
thus, it was thought that the cobble layer may be a preferential flow path of groundwater and
dissolved contaminants. However, based on soil conditions observed during the installation of
monitoring wells MW-14, MW-15, MW-16, and MW-17, it is not apparent that “cobble” layer is
more permeable than the overlying silty sand.

4.0 GROUNDWATER CHARACTERIZATION
4.1 Water Supply Wells
Three water supply wells or springs have been previously identified within 1,000 feet from the
site. Figure 2 depicts the locations of the water supply wells relative to the site. Table 1
summarizes water supply well and spring information, with all identified as WSW-#. Spring
WSW-6 and well WSW-7 are located approximately 600 and 890 feet south of the site,
respectively, and crossgradient to groundwater flow from the site. Thus, WSW-6 and WSW-7
are not likely at risk from the UST releases at the site. Well WSW-8 is located approximately 60
feet south of monitoring well MW-11 (with historical LNAPL). Springs WSW-9 and WSW-10 are
located within 500 feet upgradient of the source areas. The other water supply sources are
located upgradient or sidegradient of the source areas or across North Fork New River and are
not considered to be “at risk” wells or springs.

4.2 Groundwater Levels
On May 15, 2023, ATC measured the depth to groundwater for monitoring wells that were found
and accessible: MW-2, MW-3, MW-4, MW-5R, MW-7, MW-11, MW-12, MW-13, MW-14, MW-
15, MW-16, MW-17, RW-1, and AS-1. Monitoring wells MW-1, MW-6, MW-8, MW-9, and MW-
10 could not be located during the monitoring event, using a metal detector. Groundwater
monitoring wells MW-8 and MW-9 are located in an agricultural field and have not been located
and sampled since March 1998.

Figure 3 depicts a site map with the locations of the monitoring wells and former UST systems.
Monitoring well construction details and groundwater level data are included in Table 2. An
oil/water interface probe was used to measure the depth to groundwater from the top of well
casing (TOC). A groundwater contour map is presented in Figure 4 which depicts groundwater
flow generally to the southeast towards the North Fork New River.

On May 16, 2023, ATC measured the top of casing elevations of accessible and found wells,
relative to one another. A site benchmark was not established. The top of casing of well MW-2
was established as the “benchmark” with a relative elevation of 100 feet. Field notes from the
May 2023, groundwater monitoring event are presented in Appendix B.

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4.3 Groundwater Quality

On May 15 and 16, 2023, ATC collected groundwater samples from monitoring wells MW-2, MW-
3, MW-5R, MW-7, MW-11, MW-12, MW-13, MW-14, MW-16, MW-17, RW-1, and AS-1. A field
blank was also collected during this groundwater monitoring event. During sampling activities, a
three-volume well purge was conducted prior to groundwater sample collection to ensure a
representative groundwater sample. Water quality parameters were collected from each well once
the purging process was complete, and are summarized in Table 3. Monitoring well MW-4 was
unable to be sampled due to a bent casing. Monitoring well MW-15 was accessible on May 15,
2023 but not sampled on that day, and on May 16, 2023, a vehicle was parked over the well that
prevented the sampling of the well. On May 16, 2023, ATC collected a water sample from water
supply well WSW-8 after purging the well for approximately 15 minutes.

The water samples were collected in laboratory-supplied, preserved containers; entered into chain
of custody control; placed on ice; and shipped to North Carolina accredited Pace Analytical
Services, LLC in Huntersville, North Carolina. The groundwater samples were analyzed by SM
6200B for VOCs. Additionally, samples MW-13, MW-14, AS-1 and WSW-8 were analyzed by EPA
Method 625 for SVOCs. The analytical report is included in Appendix C.

Recent monitoring well analytical results are summarized in Table 4. Recent analytical results for
water supply well WSW-8 are summarized in Table 5. Historical monitoring well analytical results
are shown in Table 6. Historical water supply well analytical results are shown in Table 7. The
groundwater analytical results were compared to the 2L Standards, 2B Standards, and GCLs.
Groundwater analytical results indicated the following:

 Water supply well WSW-8 contained several VOCs at concentrations less than the 2L
Standards;
 Monitoring wells MW-5R, MW-11, and MW-17 contained one or more VOCs at
concentrations above the 2L Standards;
 Monitoring wells MW-5R contained toluene and naphthalene at concentrations exceeding
the 2B Standards by more than 10 times; and
 None of the detected concentrations of constituents exceeded GCLs.

Groundwater analytical results exceeding the 2L Standards and the 2B Standards by more than 10
times are depicted in Figure 5, along with estimated extent of the kerosene and gasoline
contaminant plumes.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the
laboratory reports was conducted. During the review, it was found that the samples were received
from the laboratory in acceptable condition and properly preserved. The samples were analyzed
within correct holding times and reported within the lab report, and the chain of custody was
properly completed by all parties. The laboratory QC report shows that an internal blank was
analyzed for each method that was used for the original samples. The laboratory fortified blank
(LFB) and laboratory control sample (LCS) data results were also provided for each analytical
method. A field blank was also collected during the groundwater monitoring event. No other
compounds were detected in the field blank. Refer to the laboratory reports in Appendix C for
details regarding QA results for the laboratory samples and any noted exceptions. Overall, ATC
concludes that the laboratory results are usable and any exceptions do not significantly impact the
conclusions presented in this report.

Monitoring Report June 23, 2023
Stephens Exxon – NCDEQ Incident #16457 ATC Project #STL1645701
9
5.0 CONCLUSIONS AND RECOMMENDATIONS
On behalf of the Trust Fund Branch of the UST Section, ATC has completed a Monitoring
Report documenting the May 2023 groundwater monitoring event for Stephens Exxon, located
at 20655 North Carolina Highway 88 West, Creston, Ashe County, North Carolina.

During May 15 and 16, 2023, ATC sampled groundwater monitoring wells MW-2, MW-3, MW-5R,
MW-7, MW-11, MW-12, MW-13, MW-14, MW-16, and MW-17, air sparge well AS-1, and water
supply well WSW-8. All samples were analyzed for volatile organic compounds (VOCs) using
Standard Method (SM) 6200B and samples from wells MW-11, MW-13, AS-1, and WSW-8 were
also analyzed for semi-volatile organic compounds (SVOCs) using EPA Method 625. ATC also
measured the depth to groundwater and measured the top of casing elevations for all monitoring
wells accessible on May 15 and 16, 2023. Monitoring well MW-4 could not be sampled due to a
bent casing, monitoring wells MW-1, MW-6, MW-8, MW-9, and MW-10 could not be located, and
monitoring well MW-15 could not be accessed for sampling on May 16, 2023 due to vehicle parked
over the well. The following site conditions are noted based on the recent and historical
assessment activities and are listed in the Conceptual Site Model (Appendix A):

 Six water supply wells or springs are located within 1,000 feet of the source areas including
three wells within 500 feet of the source areas. The “most at risk wells” include the on-site
water supply well WSW-8 located approximately 60 feet from the kerosene release source
area and approximately 160 feet southwest of the gasoline release source area. The other
water supply wells do not appear to be at risk due to the locations and distances from the
source areas. Municipal water is not available to the area;
 Tributaries to the North Fork New River and the North Fork New River are located within
500 feet of the source areas;
 Recent monitoring well sampling results indicated exceedances of the 2L Standards in
wells MW-5R, MW-11, and MW-17, and exceedances of the 2B Standards by more than
10 times in well MW-5R. None of the reported concentrations of constituents exceeded the
GCLs;
 Based on the groundwater level data, groundwater flow is generally to the southeast;
 Based on the recent and historical groundwater quality data, the extent of the two
contaminant plumes appear to be defined and stable. VOC concentrations in MW-5R have
generally decreased with time, and appear to be generally stable in wells MW-11 and MW-
17. LNAPL (kerosene) was previously observed in well MW-11, but has not been detected
since April 19, 2022, following the May 2022 MMPE/AS event.

Based on the information provided in this report, ATC recommends the following:
 Continue to sample selected monitoring wells (MW-4, MW-5R, MW-6, MW-11, MW-13,
MW-14, MW-15) and water supply well WSW-8. Evaluate results for plume stability based
on the previous Fate & Transport Model results;
 Conduct additional MMPE/AS events in the area of the two plumes to reduce VOC
concentrations in pursuit of closing the incident;
 Consider installation of a replacement water supply well for WSW-8, either on the source
property, the property to the east (owned by Joseph S. Stephens, Jr., a prior owner of the
source property), or the property to the south (owned by Joyce Stephens (L/E), a prior
owner of the source property); and
 Attempt to locate wells that could not be located in May 2023 and remeasure the top of
casings of the wells.

TABLES
TABLE 1
WATER SUPPLY WELL INFORMATION
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Well Owner Property Address Owner Address Well Use
Distance (ft) /
Direction from
Source
WSW-1 JIMMY DEAN POTTER
20473 NC HWY 88
WEST CRESTON, NC 28615
1197 FINGER BRIDGE RD
HICKORY, NC 28602 Potable Water, Spring 1,000 / EAST
WSW-2 MARY BELL WINEBARGER
19998 NC HWY 88
WEST CRESTON, NC
28615
1085 BRUSHY FORK RD
CRESTON, NC 28615 Potable Water, Spring 1,300 /
NORTHEAST
WSW-3 MARY BELL WINEBARGER
20410 NC HWY 88
WEST CRESTON, NC 28615
165 MEADOW RIDGE RD
BOONE, NC 28607 Potable Water, Well 1,100 /
NORTHEAST
WSW-4 CARL GRANT STEPHENS
20498 NC HWY 88
WEST CRESTON, NC 28615
20498 NC HWY 88
WEST CRESTON, NC 28615 Potable Water, Well 850 / NORTHEAST
WSW-5 EUGENE & FAYE M WARD
749 GREEN VALLEY RD
CRESTON, NC 28615
749 GREEN VALLEY RD
CRESTON, NC 28615 Potable Water, Spring 1,670 /
NORTHEAST
WSW-6 JACK PRICE 20794 NC HWY 88
WEST CRESTON, NC 28615
20794 NC HWY 88
WEST CRESTON, NC 28615 Potable Water, Spring 600 / SOUTH
WSW-7 BOB W & DARLENE J
CORNETT
20871 NC HWY 88
WEST CRESTON, NC 28615
20871 NC HWY 88
WEST CRESTON, NC 28615 Potable Water, Well 950 / SOUTH
WSW-8 VINCENT & COURTNEY
BOCCARDY
20655 NC HWY 88
WEST CRESTON, NC 28615
420 BARLOW RD
CRESTON, NC 28615 Potable Water, Well On-site
WSW-9 STEPHENS THOMAS EARL
166 GREEN VALLEY RD,
CRESTON, NC 28615
166 GREEN VALLEY RD
CRESTON, NC 28615 Potable Water, Spring 320 / NORTH
WSW-10 JIMMY R & SHIRLEY D
SORRELL
20700 NC HWY 88
WEST CRESTON, NC 28615
7220 DENLEE RD
RALEIGH, NC 27603 Potable Water, Spring 440 / NORTHWEST
WSW-11 ARTHUR EUGENE &
TRULA WARD
239 GREEN VALLEY RD,
CRESTON, NC 28615
749 GREEN VALLEY RD
CRESTON, NC 28615 Potable Water, Spring 1,250 /
NORTHWEST
Page 1 of 1
TABLE 2 RECENT WATER SUPPLY WELL ANALYTICAL RESULTSStephens Exxon20655 US Highway 88 West Creston, Ashe County, North Carolina NCDEQ Incident # 16457Well IDDate CollectedTolueneEthylbenzeneTotal XylenesMethyl-tert-Butyl EtherNapthalenen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene600 600 500 20 6 70 70 70 70 0.4 70 70 400 400260,000 84,500 85,500 20,000 6,000 6,900 8,500 15,000 70,000 400 25,000 30,000 28,500 25,000WSW-8 5/16/2023 0.83 0.85 4.8 <0.42 <1.7 <0.49 <0.40 <0.32 <0.43 <0.32 <0.33 <0.34 0.89 <0.33Notes:1) 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards).2) NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs).Only constituents detected above the reporting limit are shownConcentrations are reported in micrograms per liter (µg/L) or parts per billionConcentrations in bold exceed the 2L Standard"<" indicate the compound was below the laboratory reporting limit J = estimated concentration below the laboratory reporting limit 2L Standard (1)GCL Standard (2)Page 1 of 1
TABLE 3HISTORICAL WATER SUPPLY WELL ANALYTICAL RESULTSStephens Exxon20655 US Highway 88 West Creston, Ashe County, North Carolina NCDEQ Incident # 16457Well IDDate CollectedBenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-Butyl EtherIsopropyl EtherElthylene DibromideNapthaleneAcetonen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene4-IsopropyltolueneLeadC5-C8 AlyphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromatics1 600 600 500 20 70 0.02 6 6000 70 70 70 70 0.4 70 70 400 400 20 15 400 700 10000 2005,000 260,000 84,500 85,500 20,000 70,000 50 6,000 6,000,000 6,900 8,500 15,000 70,000 400 25,000 30,000 28,500 25,000 20,000 15,000 NE NE NE NE7/8/1997 ND ND ND ND 2 ND NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA NA08/11/1102/15/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND08/11/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND12/02/1106/22/12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND02/15/11 ND ND ND ND ND ND ND ND ND ND ND ND 0.71 ND ND ND ND ND ND 12 ND ND ND ND08/11/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND12/02/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA06/22/12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND01/29/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.094 <0.18 <0.10 <0.12 NA NA NA NA NA08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 <0.15 <0.12 <4.9 <0.15 <0.13 <0.12 <0.22 <0.19 <0.12 <0.13 <0.18 <0.13 <0.15 NA NA NA NA NA03/19/1902/15/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND08/11/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND12/02/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA06/22/12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.094 <0.18 <0.10 <0.12 NA NA NA NA NA08/09/1703/19/19 <0.19 <0.14 <0.13 <0.47 <0.25 <0.17 <0.19 <0.31 <3.8 <0.21 <0.19 <0.17 <0.17 <0.41 <0.17 <0.13 <0.18 <0.14 <0.20 NA NA NA NA NA12/02/1106/22/1201/19/1310/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.094 <0.18 <0.10 <0.12 NA NA NA NA NA08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 <0.15 <0.12 <4.9 <0.15 <0.13 <0.12 <0.22 <0.19 <0.12 <0.13 <0.18 <0.13 <0.15 NA NA NA NA NA03/19/19 <0.19 <0.14 <0.13 <0.47 <0.25 <0.17 <0.19 <0.31 <3.8 <0.21 <0.19 <0.17 <0.17 <0.41 <0.17 <0.13 <0.18 <0.14 <0.20 NA NA NA NA NA05/10/225/16/2023 <0.34 0.83 0.85 4.8 <0.42 NA NA <1.7 NA <0.49 <0.40 <0.32 <0.43 <0.32 <0.33 <0.34 0.89 <0.33 NA NA NA NA NA NANotes:1) 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards).2) NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs).Only constituents detected above the reporting limit are shownConcentrations are reported in micrograms per liter (µg/L) or parts per billionConcentrations in bold exceed the 2L Standard"<" indicate the compound was below the laboratory reporting limit J = estimated concentration below the laboratory reporting limit WSW-3NOT SAMPLEDWSW-6NOT SAMPLED - OCCUPANT ABSENTGCL Standard (2)2L Standard (1)WSW-7NOT SAMPLED - OCCUPANT ABSENTWSW-8NOT SAMPLED - SITE UNOCCUPIED - NO POWERNOT SAMPLED - SITE UNOCCUPIED - NO POWERNOT SAMPLED - SITE UNOCCUPIED - NO POWERNOT SAMPLED - SITE UNOCCUPIED - COULD NOT CONTACT PROPERTY OWNERNOT SAMPLEDWSW-1Page 1 of 1
TABLE 4
MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Installed
Well
Casing
Diameter
(in)
Well
Depth
(ft-bgs)
Screen
Interval
(ft-toc)
Top of
Casing
Elevation
(ft)
Date
Measured
Depth to
Groundwater
(ft-toc)
LNAPL
Thickness
(ft)
Groundwater
Elevation
(ft)
07/08/97 8.49 -- 91.51
03/06/98 8.01 -- 91.99
01/25/99 7.87 -- 92.13
06/22/12 6.62 -- 93.38
10/29/14 NM -- NM
08/09/17 NM -- NM
10/09/19
05/15/23
07/08/97 5.19 -- 95.12
03/06/98 4.33 -- 95.98
01/25/99 4.48 -- 95.83
04/27/04 3.76 -- 96.55
02/14/11 4.65 -- 95.66
10/29/14 4.35 -- 95.96
08/09/17 3.94 -- 96.37
03/19/19 2.66 -- 97.65
10/09/19 4.82 -- 95.49
05/10/22 3.89 -- 96.42
10/06/22 4.05 -- 96.26
100.00 05/15/23 4.50 -- 95.50
07/08/97 4.03 -- 96.36
03/06/98 3.58 -- 96.81
01/25/99 3.62 -- 96.77
04/27/04 3.01 -- 97.38
02/15/11 4.30 -- 96.09
12/02/11 3.76 -- 96.63
06/22/12 4.20 -- 96.19
01/29/13 2.98 -- 97.41
10/29/14 3.99 -- 96.40
08/09/17 3.38 -- 97.01
03/19/19 3.44 -- 96.95
10/09/19 4.32 -- 96.07
10/06/22 4.09 -- 96.30
100.03 05/15/23 4.11 -- 95.92
07/08/97 9.51 -- 90.96
03/06/98 8.42 -- 92.05
01/25/99 8.30 -- 92.17
04/27/04 8.14 -- 92.33
02/15/11 8.62 -- 91.85
08/11/11 9.65 -- 90.82
12/02/11 7.14 -- 93.33
06/22/12 8.65 -- 91.82
01/29/13 6.08 -- 94.39
10/29/14 8.61 -- 91.86
08/09/17 8.67 -- 91.80
03/19/19 8.12 -- 92.35
10/09/19 9.35 -- 91.12
09/26/22 8.33 -- 92.14
10/06/22 7.94 -- 92.53
100.07 05/15/23 9.21 -- 90.86
100.47
100.39
100.31
NOT LOCATED
MW-4 03/08/97 2.0 13.9 3.9-13.9
MW-2 03/07/97 2.0 15.3 5.3-15.3
MW-3 03/08/97
NOT LOCATED
MW-1 10/23/96 2.0 15.1
2.0 11.0
5.1-15.1 100.00
3.0-11.0
Page 1 of 4
TABLE 4
MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Installed
Well
Casing
Diameter
(in)
Well
Depth
(ft-bgs)
Screen
Interval
(ft-toc)
Top of
Casing
Elevation
(ft)
Date
Measured
Depth to
Groundwater
(ft-toc)
LNAPL
Thickness
(ft)
Groundwater
Elevation
(ft)
07/08/97 12.66 --88.91
03/06/98 12.64 --88.93
01/25/99 11.75 --89.82
04/27/04 12.02 --89.55
02/15/11 NM --NM
08/11/11 NM --NM
12/02/11
10/29/14 10.69 --90.88
08/09/17 NM --NM
08/09/17 9.65 --91.44
10/09/19 10.48 --90.61
09/26/21 NM --NM
09/26/22 10.00 --91.09
10/06/22 9.90 --91.19
100.80 05/15/23 12.00 --88.80
07/08/97 10.33 --88.55
03/06/98 10.92 --87.96
01/25/99 9.68 --89.20
09/03/03 9.21 --89.67
02/15/11 NM --NM
08/11/11 NM --NM
12/02/11
10/29/14
08/09/17
03/19/19 6.18 --92.70
10/09/19
05/15/23
07/08/97 8.10 --92.94
03/06/98 7.72 --93.32
01/25/99 7.36 --93.68
02/15/11 8.62 --92.42
10/09/19
100.72 05/15/23 6.62 --94.10
03/06/98 2.57 --83.79
10/09/19
05/15/23
03/06/98 2.63 --81.50
01/25/99 2.70 --81.43
02/15/11 NM --NM
08/11/11 NM --NM
12/02/11 NM --NM
10/29/14 NM --NM
08/09/17 NM --NM
10/09/19
05/15/23
01/25/99 6.10 --95.44
10/09/19
05/15/23
101.09
101.04
NOT LOCATED
MW-10 1/25/199 14.0
NOT LOCATED
MW-9 03/05/98 2.0 10.0 2.5-10.0 84.13
NOT LOCATED
NOT LOCATED
03/05/98 2.0 7.5 2.5-7.5 86.36 NOT LOCATED
41.5-46.546.52.006/04/97MW-7
NOT LOCATED
NOT LOCATED
NOT LOCATED
NOT LOCATED
NOT LOCATED
NOT LOCATED
03/14/19 2.0 14.0 4.0-14.0
MW-5 03/08/97 2.0 13.6
MW-5R
13.22.0
NOT LOCATED
NOT LOCATED
03/13/97MW-6
MW-8
4-14.0 101.54
3.6-13.6
2.4-13.2
2.0
98.88
101.57
Page 2 of 4
TABLE 4
MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Installed
Well
Casing
Diameter
(in)
Well
Depth
(ft-bgs)
Screen
Interval
(ft-toc)
Top of
Casing
Elevation
(ft)
Date
Measured
Depth to
Groundwater
(ft-toc)
LNAPL
Thickness
(ft)
Groundwater
Elevation
(ft)
04/27/04 6.27 ----
02/15/11 11.11 1.00 89.43
08/08/11 6.96 0.61 93.24
08/08/11 9.35 0.02 90.35
08/11/11 9.36 0.02 90.34
12/02/11 7.94 --91.74
06/22/12 8.94 0.21 90.92
01/29/13 6.99 0.21 92.87
10/29/14 8.76 0.76 91.57
08/09/17 8.59 1.18 92.10
03/19/19 7.89 0.39 92.12
10/09/19 9.76 1.20 90.95
09/26/21 NM 0.02 NM
04/19/22 NM 0.13 NM
05/10/22 7.49 --92.19
09/26/22 8.17 --91.51
10/06/22 7.95 --91.73
100.95 05/15/23 9.02 --91.93
04/27/04 6.17 --93.35
08/11/11 7.43 --92.09
12/02/11 6.19 --93.33
06/22/12 4.72 --94.80
01/29/13 4.49 --95.03
10/29/14 6.04 --93.48
08/09/17 5.47 --94.05
03/19/19 3.62 --95.90
10/09/19 6.20 --93.32
05/10/22 5.42 --94.10
10/06/22 5.22 --94.30
99.66 05/15/23 6.11 --93.55
03/19/19 4.85 --92.72
10/09/19 6.08 --91.49
09/26/21 6.30 --91.27
05/10/22 5.12 --92.45
09/26/22 5.00 --92.57
10/06/22 4.60 --92.97
97.29 05/15/23 5.67 --91.62
10/09/19 6.11 --91.28
09/26/21 5.75 --91.64
05/10/22 5.48 --91.91
10/06/22 5.50 --91.89
98.64 05/15/23 6.03 --92.61
10/09/19 7.80 --92.40
09/26/21 7.65 --92.55
09/26/22 7.43 --92.77
10/06/22 7.26 --92.94
05/15/23 8.68 --91.52
10/09/19 0.90 --86.63
09/26/21 1.25 --86.28
10/06/22 0.60 --86.93
89.12 05/15/23 2.48 --86.64
87.53
97.39
97.57
99.52
99.68
MW-15 10/07/19 2.0 20.0 5.0-20.0
MW-16 10/08/19 2.0 20.0 3.0-10.0
100.20
03/14/19 12.0 2.0-12.02.0
10/07/19 2.0 15.0
15.0 5-15.0
MW-13
MW-14 5.0-15.0
MW-11 07/14/03 2.0 14.0 4.0-14.0
MW-12 07/14/03 2.0
Page 3 of 4
TABLE 4
MONITORING WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Installed
Well
Casing
Diameter
(in)
Well
Depth
(ft-bgs)
Screen
Interval
(ft-toc)
Top of
Casing
Elevation
(ft)
Date
Measured
Depth to
Groundwater
(ft-toc)
LNAPL
Thickness
(ft)
Groundwater
Elevation
(ft)
10/09/19 1.16 --87.73
09/26/21 1.66 --87.23
09/26/22 0.40 --88.49
10/06/22 0.50 --88.39
90.40 05/15/23 2.35 --88.05
99.54 05/10/22 8.10 --91.44
100.88 05/15/23 9.00 --91.88
99.15 05/10/22 7.61 --91.54
100.41 05/15/23 8.54 --91.87
Notes:
in = inches
ft = feet
ft-toc = feet below top of casing
ft-bgs = feet below ground surface
NA = Not Applicable
NM = Not Measured
--- = No Light Non-Aqueous Phase Liquid (LNAPL) detected
MW-17 10/08/19 2.0 13.0 3.0-13.0
88.89
5.0-15.0
AS-1 04/19/22 2.0 16.0 13.0-16.0
RW-1 04/19/22 2.0 15.0
Well construction and water level data prior to May 2023 taken from a Groundwater Monitoring Report prepared by
Terracon, Inc. and dated October 19, 2022. ATC remeasured TOC elevations of accessible wells in May 2023.
Page 4 of 4
TABLE 5FIELD PARAMETERSStephens Exxon20655 US Highway 88 West Creston, Ashe County, North Carolina NCDEQ Incident #16457AS-105/15/2316.570.543.4-476.7MW-25/16/2316.050.195.22686.3MW-305/15/2316.950.6610.8967.4MW-5R 05/16/2316.010.284.1-576.3MW-705/16/2316.410.145.5505.6MW-11 05/15/2317.100.572.6-807.1MW-12 05/16/2315.380.3410.31246.2MW-13 05/15/2315.510.745.0-326.8MW-14 05/15/2315.771.191.6-646.0MW-16 05/16/2314.980.294.6-76.8MW-17 05/16/2314.980.123.6716.1Notes:°C = degrees CelsiusmS/cm = milliSiemens per centimetermg/L = milligrams per literORP = Oxidation-Reduction Potential in millivolts (mV)su = standard unitspH(su)ORP(mV)Well ID DateTemperature (°C)Conductivity (mS/cm)Dissolved Oxygen(mg/L)Page 1 of 1
TABLE 6
RECENT MONITORING WELL ANALYTICAL RESULTS
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Collected
BenzeneTolueneEthylbenzeneXylene (Total)Diisopropyl etherNaphthalenen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneIsopropylbenzene(Cumene)n-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneFluorene1 600 600 500 70 6 70 70 70 70 70 70 400 400 300
2B Standard 51 0.36 97 450 20000 12 3.9 NE NE 250 80 NE 390 215 30
5,000 260,000 80,000 50,000 70000 6,000 5,900 8,800 14,750 30,500 26,100 70,000 28,500 24,100 845
AS-1 05/15/23 <0.34 <0.24 <0.30 <0.34 <0.31 <0.64 <0.49 1.0 0.51 <0.33 <0.34 <0.29 <0.50 <0.33 <1.8
MW-1 05/16/23 Not sampled, could not locate
MW-2 05/16/23 <0.34 <0.24 <0.30 <0.34 <0.31 <0.64 <0.49 <0.40 <0.32 <0.33 <0.34 <0.29 <0.50 <0.33 N/A
MW-3 05/15/23 <0.34 <0.24 <0.30 <0.34 <0.31 <0.64 <0.49 <0.40 <0.32 <0.33 <0.34 <0.29 <0.50 <0.33 N/A
MW-4 05/15/23 Not sampled, bent casing
MW-5R 05/16/23 6.1 86.9 574 1,860 <3.1 185 <4.9 <4.0 <3.2 86.0 357 4.9J 1,950 588 N/A
MW-6 05/16/23 Not sampled, could not locate
MW-7 05/16/23 <0.34 <0.24 <0.30 <0.34 <0.31 <0.64 <0.49 <0.40 <0.32 <0.33 <0.34 <0.29 <0.50 <0.33 N/A
MW-8 05/16/23 Not sampled, could not locate
MW-9 05/16/23 Not sampled, could not locate
MW-10 05/16/23 Not sampled, could not locate
MW-11 05/15/23 <0.34 <0.24 0.92 0.38J <0.31 36.1 <0.49 11.7 2.6 5.1 7.2 <0.29 107 <0.33 3.0J
MW-12 05/16/23 <0.34 <0.24 <0.30 <0.34 0.90 <0.64 <0.49 <0.40 <0.32 <0.33 <0.34 <0.29 <0.50 <0.33 N/A
MW-13 05/15/23 <0.34 <0.24 <0.30 <0.34 <0.31 2.2 <0.49 2.5 <0.32 0.82 1.2 <0.29 10.6 <0.33 <2.1
MW-14 05/15/23 <0.34 <0.24 <0.30 <0.34 <0.31 <0.64 <0.49 <0.40 <0.32 <0.33 <0.34 <0.29 <0.50 <0.33 N/A
MW-15 05/16/23 Not sampled, could not access
MW-16 05/16/23 <0.34 <0.24 1.6 1.6 0.44J 3.9 1.2 <0.40 <0.32 4.8 8.5 <0.29 9.0 <0.33 N/A
MW-17 05/16/23 12.0 1.9 33.0 50.1 1.9 4.6 <0.49 <0.40 <0.32 1.7 5.9 <0.29 33.6 3.2 N/A
Notes:
2L Standards = 15A NCAC 02L .0202 Groundwater Quality Standard
2B Standard = 15A NCAC 02B Surface Water Quality Standards, including EPA National Recommended Water Quality Criteria and North Carolina In-Stream Target Values for the Class C, Trout, High Quality Waters stream
GCL = NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs).
Only constituents detected above the reporting limit are shown Concentrations are reported in micrograms per liter (µg/L)
J = estimated concentration below the laboratory reporting limit Concentrations in bold exceed the 2L Standard
NE = Not Established Concentrations in underlined exceed the 2B Standard by more than ten times.
2L Standard
GCL
Page 1 of 1
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Collected
BenzeneTolueneEthylbenzenTotal XylenesMethyl-tert-Butyl EtherDi-Isopropyl EtherElthylene DibromideNaphthaleneAcetonen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzene4-Isopropylbenzenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneLeadC5-C8 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromatics1 600 600 500 20 70 0.02 6 6,000 70 70 70 70 0 70 20 70 70 400 400 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 70,000 50 6,000 6,000,000 5,900 8,800 14,750 70,000 400 30,500 11,700 26,100 70,000 28,500 24,100 15,000 NE NE NE NE
07/08/97 408.0 642 250.0 843.0 1,773 370 NA NA NA NA NA NA NA 4 NA NA NA --NA NA 36 NA NA NA NA
03/06/98 653.0 1,158 512 1,436.0 614 565 NA 101 NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA 67 NA NA NA NA NA NA NA NA NA --NA NA NA NA 3,862 NA 947
06/22/12 ND ND ND ND ND 6 ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
10/29/14
08/09/17
10/09/19
07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA ND NA NA NA --NA NA ND NA NA NA NA
03/06/98 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND ND
04/27/04 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND ND
02/15/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND ND ND ND ND ND
06/22/12
10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.12 <0.094 <0.12 <0.18 <0.10 NA NA NA NA NA
08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 <0.15 <0.12 <4.9 <0.15 <0.13 <0.12 <0.22 <0.19 <0.12 <0.15 <0.13 <0.15 <0.18 <0.13 NA NA NA NA NA
03/19/19 <0.18 <0.14 <0.13 <0.47 <0.25 <0.17 <0.19 <0.31 <3.8 <0.21 <0.16 <0.17 <0.17 <0.41 <0.17 <0.20 <0.13 <0.11 <0.18 <0.14 NA NA NA NA NA
10/09/19
07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA ND NA NA NA --NA NA ND NA NA NA NA
03/06/98 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND ND
04/27/04 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND ND
02/15/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND 12 ND ND ND ND
12/02/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
06/22/12 ND ND ND ND ND ND ND ND ND ND 1 ND ND ND ND ND ND --ND ND NA NA NA NA NA
01/29/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --0.27 J ND NA NA NA NA NA
10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 10 J <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.12 <0.094 <0.12 <0.18 <0.10 NA NA NA NA NA
08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 <0.15 <0.12 <4.9 <0.15 <0.13 <0.12 <0.22 <0.19 <0.12 <0.15 <0.13 <0.15 <0.18 <0.13 NA NA NA NA NA
03/19/19 <0.18 <0.14 <0.13 <0.47 <0.25 <0.17 <0.19 <0.31 <3.8 0.30 J 1 0.23 J <0.17 <0.41 0.48 J <0.20 <0.13 <0.11 0.55 <0.14 NA NA NA NA NA
10/09/19
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
NOT SAMPLED
NOT SAMPLED
2L Standard (1)
GCL Standard (2)
MW-2
MW-1
MW-3
NOT SAMPLED
Page 1 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Collected
BenzeneTolueneEthylbenzenTotal XylenesMethyl-tert-Butyl EtherDi-Isopropyl EtherElthylene DibromideNaphthaleneAcetonen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzene4-Isopropylbenzenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneLeadC5-C8 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromatics1 600 600 500 20 70 0.02 6 6,000 70 70 70 70 0 70 20 70 70 400 400 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 70,000 50 6,000 6,000,000 5,900 8,800 14,750 70,000 400 30,500 11,700 26,100 70,000 28,500 24,100 15,000 NE NE NE NE
2L Standard (1)
GCL Standard (2)
07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA ND NA NA NA --NA NA ND NA NA NA NA
03/06/98 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA 318 396 36
04/27/04 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND ND
02/15/11 ND ND ND ND ND ND ND 1 2.5 J 1 1 ND ND ND ND ND ND --3.6 0.8 NA ND 98 J ND 42 J
08/11/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND NA ND ND ND ND
12/02/11 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
06/22/12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --0.27 J ND NA NA NA NA NA
01/29/13 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.12 <0.094 <0.12 <0.18 <0.10 NA NA NA NA NA
08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 <0.18 <0.15 <0.12 <4.9 <0.15 0.13 J <0.12 <0.22 <0.19 <0.12 <0.15 <0.13 <0.15 <0.18 <0.13 NA NA NA NA NA
03/19/19 <0.18 <0.14 <0.13 <0.47 <0.25 <0.17 <0.19 <0.31 7.5 J <0.21 <0.16 <0.17 <0.17 <0.41 <0.17 <0.20 <0.13 <0.11 <0.18 <0.14 NA NA NA NA NA
10/09/19
09/26/22 <1.00 <1.00 <1.00 <2.00 <1.00 <1.00 <1.00 <5.00 <50.0 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <1.00 NA <100 <100 <100 <100
07/08/97 393 1,016 519 1,578 97 23 NA NA NA NA NA NA NA ND NA NA NA --NA NA ND NA NA NA NA
03/06/98 573 5,162 1,112 6,253 232 127 NA 168 NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA 583 NA NA NA NA NA NA NA NA NA --NA NA NA NA 39,091 44.0 6,821
04/27/04 243 3,580 ND 6,270 2,299 ND NA 98 NA NA NA NA NA NA NA NA NA --NA NA NA 25,380 11,816 ND 42,580
02/15/11
08/11/11
12/02/11
10/29/14 42 120 240 1,140 4.4 J <3.6 <1.8 110 100 J 110 18 <1.9 4.4 J <3.9 28 17 110 16 690 230 NA NA NA NA NA
08/09/17
03/19/19 <7.2 470 2,000 7,600 <10 <6.8 <7.6 530 <150 350 100 <6.8 <6.8 <16 300 68 1,300 51 6,400 2,000 NA NA NA NA NA
10/08/19 <2.5 160 682 2,360 <2.5 <2.5 <2.5 195 NA <2.5 <2.5 <2.5 <25 <2.5 93 NA <2.5 13.5 1,790 543 NA NA NA NA NA
09/28/21 ND 48 249 737 ND ND ND ND ND 17 9 ND ND ND 42.0 ND ND 3.93 630 186 NA NA NA NA NA
09/26/22 <20.0 38 262 745 <20.0 <20.0 <20.0 <100 <1000 38 <20.0 <20.0 <100 <20.0 50.2 NA 205 <20.0 1,020 272 NA NA NA NA NA
07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA ND NA NA NA --NA NA ND NA NA NA NA
03/06/98 ND ND ND ND 12 ND ND ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA 62 ND 25
02/15/11
08/11/11
12/02/11
10/29/14
08/09/17
03/19/19 <0.18 <0.14 <0.13 <0.47 1.000 1.300 <0.19 <0.31 <3.8 <0.21 <0.16 <0.17 <0.17 <0.41 <0.17 <0.20 <0.13 <0.11 <0.18 <0.14 NA NA NA NA NA
10/09/19
07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA ND NA ND NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA ND ND 44
02/15/11 ND ND ND ND ND ND ND 11 ND 4.9 4 1 ND ND 1 3 3 --34 7 ND ND 3,930 ND 2,060
10/09/19
NOT SAMPLED
COULD NOT LOCATE
COULD NOT LOCATE
MW-4
MW-5
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
MW-7
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
MW-5R
COULD NOT LOCATE
COULD NOT LOCATEMW-6
Page 2 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Collected
BenzeneTolueneEthylbenzenTotal XylenesMethyl-tert-Butyl EtherDi-Isopropyl EtherElthylene DibromideNaphthaleneAcetonen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzene4-Isopropylbenzenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneLeadC5-C8 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromatics1 600 600 500 20 70 0.02 6 6,000 70 70 70 70 0 70 20 70 70 400 400 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 70,000 50 6,000 6,000,000 5,900 8,800 14,750 70,000 400 30,500 11,700 26,100 70,000 28,500 24,100 15,000 NE NE NE NE
2L Standard (1)
GCL Standard (2)
03/06/98 ND ND ND ND ND ND NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
10/09/19
03/06/98 ND ND ND ND ND ND ND 3 NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
01/25/99 NA NA NA NA NA NA NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA 45 ND 29
02/15/11
08/11/11
12/02/11
10/29/14
08/09/17
10/09/19
06/22/14 NA NA NA NA NA NA NA 6,720 NA NA NA NA NA NA NA NA NA NA NA NA NA 56,680 83 2,556
10/09/19
04/24/04 ND 136 ND 318 ND ND NA 180 NA NA NA NA NA NA NA NA NA --NA NA NA NA 28,000 ND 11,426
02/15/11
08/15/11
12/02/11 ND ND ND 0.93 J ND ND ND 44 ND ND 0.58 3.2 ND ND ND 4.2 ND --190 10 NA NA NA NA NA
06/22/12
01/29/13
10/29/14
08/09/17
03/19/19
10/09/19
09/28/21
04/19/22
05/10/22 <1.00 <1.00 <1.00 <2.00 <1.00 <1.00 <1.00 <5.00 <50.0 1.15 1.22 <1.00 <5.00 <1.00 <1.00 NA <1.00 <1.00 5.73 <1.00 NA NA NA NA NA
09/26/22 <10.0 <10.0 <10.0 <20.0 <10.0 <10.0 <10.0 3.52 <500 <10.0 <10.0 <10.0 <50.0 <10.0 <10.0 NA <10.0 <10.0 54.8 <10.0 NA <100 14,380 282 3,300
04/24/04 ND ND ND ND ND 2.7 NA ND NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
02/15/11 ND ND ND ND 1.1 11 ND ND ND ND ND ND ND ND ND ND ND --ND ND 74 49 J ND ND ND
08/15/11 ND ND ND ND 0.84 J 6.5 ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA ND ND ND
12/02/11 ND ND ND ND ND 4.5 ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
06/22/12 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
01/29/13 ND ND ND ND 0.30 J 3.4 ND ND ND ND ND ND ND ND ND ND ND --ND ND NA NA NA NA NA
10/29/14 <0.079 <0.090 <0.092 <0.29 0.27 J 2.2 <0.089 <0.12 37 J <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.12 <0.094 <0.12 <0.18 <0.10 NA NA NA NA NA
08/09/17 <0.12 <0.17 <0.13 <0.39 <0.090 1.5 <0.15 <0.12 <4.9 <0.15 <0.13 <0.12 <0.22 <0.19 <0.12 <0.15 <0.13 <0.15 <0.18 <0.13 NA NA NA NA NA
03/19/19 <0.18 <0.14 <0.13 <0.47 <0.25 6.2 <0.19 <0.31 9.0 J <0.21 <0.16 <0.17 <0.17 <0.41 <0.17 <0.20 <0.13 <0.11 <0.18 <0.14 NA NA NA NA NA
10/09/19
03/19/19 <0.18 6 1.7 6.3 <0.25 <0.17 <0.19 3.7 <3.8 2.8 2.7 0.58 <0.17 <0.41 1.3 1.3 2.2 <0.11 20 1.5 NA NA NA NA NA
10/08/19 <0.25 <0.25 <0.25 <0.50 <0.25 <0.25 <2.5 2.2 NA <0.25 2.5 0.55 <2.5 <2.5 0.84 NA 0.87 <0.25 10.9 <0.25 NA NA NA NA NA
09/28/21 ND ND ND ND ND ND ND ND ND 2 3 ND ND ND 1 ND ND ND 14 ND NA NA NA NA NA
05/10/22 <1.00 <1.00 <1.00 <2.00 <1.00 <1.00 <1.00 <5.00 <50.0 1.98 2.65 <1.00 <5.00 <1.00 1.09 NA 1.07 <1.00 11.8 <1.00 NA NA NA NA NA
09/26/22 <5.00 <5.00 <5.00 <10.0 <5.00 <5.00 <5.00 <25.0 <250 <5.00 <5.00 <5.00 <25.0 <5.00 <5.00 NA <5.00 <5.00 11.5 <5.00 NA <100 151 <100 142
10/08/19 <0.25 <0.25 <0.25 <0.50 <0.25 <0.25 <0.25 <1.0 NA <0.25 0.56 <0.25 <2.5 <0.25 <0.25 NA <0.25 <0.25 1 <0.25 NA NA NA NA NA
09/28/21 ND 48 309 845 ND ND ND ND ND 18 11 ND ND ND 41 ND 158 ND 797 214 NA NA NA NA NA
05/10/22 <1.00 <1.00 <1.00 <2.00 <1.00 <1.00 <1.00 <5.00 <50.0 <1.00 <1.00 <1.00 <5.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <1.00 NA NA NA NA NA
10/08/19 0.66 3.1 22.3 64 <0.25 <0.25 <0.25 6.1 NA 1.7 <0.25 <0.25 <2.5 <0.25 1.9 NA <0.25 <0.25 38.7 11.4 NA NA NA NA NA
09/28/21 ND 121 788 1,255 ND ND ND ND ND ND ND ND ND ND ND ND 101 ND 584 167 NA NA NA NA NA
09/26/22 <10.0 18.8 140 268 <10.0 <10.0 <10.0 <50.0 <500 <10.0 <10.0 <10.0 <50.0 <10.0 <10.0 NA 22.6 <10.0 134 34.4 NA NA NA NA NA
MW-12
NOT SAMPLED
MW-13
MW-14
MW-15
NOT SAMPLED - LNAPL (0.76 ft)
NOT SAMPLED - LNAPL (1.18 ft)
NOT SAMPLED - LNAPL (0.39 ft)
NOT SAMPLED - LNAPL (1.20 ft)
NOT SAMPLED - LNAPL (0.13 ft)
NOT SAMPLED - LNAPL (0.02 ft)
COULD NOT LOCATE
MW-8
MW-9
MW-10
MW-11
NOT SAMPLED
NOT SAMPLED
NOT SAMPLED - LNAPL (0.21 ft)
NOT SAMPLED - LNAPL (0.21 ft)
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
COULD NOT LOCATE
Page 3 of 4
TABLE 7
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
Stephens Exxon
20655 US Highway 88
West Creston, Ashe County, North Carolina
NCDEQ Incident #16457
Well ID Date
Collected
BenzeneTolueneEthylbenzenTotal XylenesMethyl-tert-Butyl EtherDi-Isopropyl EtherElthylene DibromideNaphthaleneAcetonen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneChloroform1,2-DichloroethaneIsopropylbenzene4-Isopropylbenzenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneLeadC5-C8 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 Aromatics1 600 600 500 20 70 0.02 6 6,000 70 70 70 70 0 70 20 70 70 400 400 15 400 700 10,000 200
5,000 260,000 80,000 50,000 20,000 70,000 50 6,000 6,000,000 5,900 8,800 14,750 70,000 400 30,500 11,700 26,100 70,000 28,500 24,100 15,000 NE NE NE NE
2L Standard (1)
GCL Standard (2)
10/09/19 0.27J 0.41J 1.8 4.5 <0.25 <0.25 <0.25 <1.0 NA 0.71 <0.25 <0.25 <2.5 <0.25 0.44J NA 1.8 <0.25 8.9 2.6 NA NA NA NA NA
09/28/21 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NA NA NA
10/09/19 3.5 14.1 210 487 <1.0 <1.0 <1.0 55.7 NA <1.0 <1.0 <1.0 <10.0 <1.0 17.2 NA 59.2 <1.0 353 74.3 NA NA NA NA NA
09/28/21 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2 ND NA NA NA NA NA
09/26/22 5.03 2.24 40.3 72.66 <1.00 1.14 <1.00 9.77 <50.0 <1.00 <1.00 <1.00 <5.00 <1.00 2.89 NA 8.36 <1.00 53.8 5.7 NA NA NA NA NA
TW-1 07/08/97 35.6 3.8 27.2 2.8 4 39.3 NA NA NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
TW-2 07/08/97 ND ND ND ND ND ND NA NA NA NA NA NA NA NA NA NA NA --NA NA NA NA NA NA NA
SW-1 10/29/14 <0.079 <0.090 <0.092 <0.29 <0.090 <0.18 <0.089 <0.12 <4.7 <0.054 <0.084 <0.096 <0.14 <0.19 <0.11 <0.12 <0.094 <0.12 <0.18 <0.10 NA NA NA NA NA
Notes:
2L Standards = 15A NCAC 02L .0202 Groundwater Quality Standard
2B Standard = 15A NCAC 02B Surface Water Quality Standards, including EPA National Recommended Water Quality Criteria and North Carolina In-Stream Target Values for the Class C, Trout, High Quality Waters stream
GCL = NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs).
Only constituents detected above the reporting limit are shown Concentrations are reported in micrograms per liter (µg/L)
J = estimated concentration below the laboratory reporting limit Concentrations in bold exceed the 2L Standard
NE = Not Established Concentrations in underlined exceed the 2B Standard by more than ten times.
MW-17
MW-16
Page 4 of 4

FIGURES
CAD FILE PREP. BY REV. BY SCALE PROJECT NO.
TITLE
DATE
REFERENCE: USGS 7.5-MINUTE MAP, BALDWIN GAP, NORTH
CAROLINA. DATED 2003
LATITUDE:ƒ1257+
LONGITUDE:ƒ:(67
SITE
1,000' RADIUS500' RADIUS1,500' RADIUSWSW-11WSW-4WSW-2WSW-3WSW-1WSW-10WSW-9WSW-8WSW-6WSW-7= WATER SUPPLY WELLNC HIGHWAY
88
WEST= WATER SUPPLY SPRINGNORTH FORK NEW RIVER
NC HIGHWAY 88 WESTMW-2MW-1MW-15MW-7MW-6MW-5RMW-17MW-3MW-16MW-8MW-4MW-13MW-14RW-1AS-1MW-12FORMERSTEPHEN'S
EXXONPROPERETY BOUNDARYKEROSENE USTGASOLINE USTWSW-8MW-11= MONITORING WELL LOCATION= WATER SUPPLY WELL LOCATION
NC HIGHWAY 88 WESTMW-2MW-1MW-15MW-7MW-6MW-5RMW-17MW-3MW-16MW-8MW-4MW-13MW-14RW-1AS-1MW-12FORMERSTEPHEN'S
EXXONPROPERETY BOUNDARYKEROSENE USTGASOLINE USTWSW-8MW-11= GROUNDWATER ELEVATION IN FEET= MONITORING WELL LOCATION= GROUNDWATER ELEVATION CONTOUR= GROUNDWATER FLOW DIRECTION82.87(DASHED WHERE INFERRED)1.GROUNDWATER ELEVATIONS MEASURED 05/16/2023= WATER SUPPLY WELL LOCATION86.64NLNLNL90.8691.9092.6195.9295.5093.5591.5288.8094.1095.0= NOT LOCATEDNL94.093.092.0
91.0
90.0
89.0
88.0
87.0 88.0591.9391.8891.87
NC HIGHWAY 88 WESTMW-2MW-1MW-15MW-7MW-6MW-5RMW-17MW-3MW-16MW-8MW-4MW-13MW-14RW-1AS-1MW-12FORMERSTEPHEN'S
EXXONPROPERETY BOUNDARYKEROSENE USTGASOLINE USTWSW-8MW-111. ONLY CONCENTRATIONS EXCEEDING 2L STANDARD ARE SHOWN2. CONCENTRATIONS IN MICROGRAMS PER LITRER (µg/L)3. 2L STANDARD: GROUNDWATER QUALITY STANDARD4. 2B STANDARD: SURFACE WATER QUALITY STANDARD5. GCL: GROSS CONTAMINANT LEVEL6. ESTIMATED PLUME EXTENT BASED ON RECENT AND HISTORICAL DATA= MONITORING WELL LOCATION= WATER SUPPLY WELL LOCATIONNLNLNLNL= NOT LOCATEDAPPROXIMATE EXTENT OF 2LOR 10x2B STANDARDS

APPENDIX A
CONCEPTUAL SITE MODEL
Site Name: Stephens Exxon Date:6/14/2023
Property Owner: V. Boccardy/C. Cutillo Last Field Event Date:5/16/2023
Site Name:Stephens Exxon Release Discovery Date: 10/1/1996
NCDEQ UST Incident No.: 16457 Source of Release: Leaking UST Systems
Facility ID No.: 00‐0‐0000000453 Estimated Volume of Release: Unknown
Risk Classification: High
Risk Rank:0090D Gasoline (leaded) 
Site Address:20655 NC Highway 88 West Gasoline (unleaded)Yes
Site City, ST ZIP:Creston, North Carolina 28615 Gasoline (ethanol blend)
Site County:Ashe Diesel
NCDEQ Regional Office:Winston‐Salem Kerosene Yes
Active UST Facility:No Heating Oil (#2)
USTs Present:No Heating Oil (>#2)
Motor Oil
Hydraulic Oil
Major Soil Type:Sandy Silt Used Oil
Surface Cover over impacted soil:Gravel
Utilities within plume (Y/N/U): N
>S‐W MSCCs (Y/N/U):N
>Residential MSCCs (Y/N/U): N Site (Current):Commercial
>Comm/Ind MSCCs (Y/N/U): N Site (Future):Commercial/Residential
North Adjacent:Residential
East Adjacent:Agricultural
Litho‐Tectonic Zone Blue Ridge South Adjacent:Agricultural
Geologic Formation West Adjacent:Undeveloped woodland
Rock Type biotite granite gneiss
Depth to Bedrock (ft bgs)~30 Municipal Water (Y/N/U):N
Active Potable Wells <1000 ft (#/U): Y
Active Potable Wells <500 ft (#/U): Y, 8 inc. Public well ~250 ft
Depth to water (ft‐bgs)1‐10 Impacted Wells (Y/N/U):No
Gradient (ft/ft):0.0184 to 0.0386 Any wells <250 ft (Y/N/U):Y, 3
Direction (N E S W combo):SE
Hydraulic Conductivity (ft/day): 30 <500 ft (Y/N):Y (SW ~65 and SE ~470 ft)
Total Porosity (%):0.38 Type of Surface Water:Stream
Effective Porosity (%):0.38 Name of Nearest Stream:North Fork New River
Flow Rate (ft/year):16 to 35 Stream Classification:Class C, Trout Waters, Outstanding 
Resource Waters
COCs >2L (Y/N/U):Y Impacted Surface Water (Y/N/U): Unknown, but not likely
COCs >2L Extent Defined (Y/N): Y
COCs >GCLs (Y/N/U):N
COCs >GCLs (Wells):NA >LEL in Structures:U
COCs >GCLs Extent Defined (Y/N): NA Vapors in Buildings:U
COCs >2B Standards by 10X (Y/N/U): Y (MW‐5R)Slab‐on‐grade or Crawlspace: Slab‐on‐grade
LNAPL (Y/N/U):N Dissolved VOCs <5 ft of Structures: Y
LNAPL (Max Thickness ft):NA LNAPL <15 ft of Structures:N
LNAPL (Wells):Historically in MW‐11, 4/19/22 Basement <30 ft of Dissolved COCs: N
LNAPL Extent Defined (Y/N): NA
LNAPL (<5 ft beneath buildings/U): NA
Utilities within plume (Y/N/U): N
Alternative Water Source:New water supply well
NORP:
Site Remediation:
Soil Excavation:
AFVR:
MMPE:Possible.
SVE/AS:Possible
Other:
Additional Support Documentation Available / Data Gaps:
An easement would be needed for a water supply well on the adjoining property.
Approach (general discussion):Possible new WSW or active 
remediation
Surface Water
Land Use / Zoning
Monitor MW‐1 for possible return of LNAPL;
Remediation efforts to reduce VOCs <2L Standards; or install replacement water 
supply well in the northeast corner of property or adjoining property to the east, to 
be more distant and sidegradient of the two source areas
CONCEPTUAL SITE MODEL 
Soil Information
Possible Path(s) to Closure
Site Information Release Information
Petroleum Type Released
Geologic Information
Groundwater Information
Comments:
Receptor Information
Water Supply
Vapor
Page 1 of 1

APPENDIX B
FIELD NOTES AND
PHOTOOGRAPHS
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 6/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 2: View of site facing southeast (5/16/2023)
Photo #1: View of site facing southwest toward the former Stephen’s Exxon building (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo #4: View behind the carport on site facing northwest (5/16/2023)
Photo #3: View behind the former Stephen’s Exxon building facing northeast (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo #6: View of MW-3 facing east (5/16/2023)
Photo #5: View of MW-2 facing southeast (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 8: Obstruction in MW-4 at approximately 1 foot below casing (5/15/2023)
Photo #7: View of MW-4 facing northwest (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo #10: View of MW-7 facing southeast (5/16/2023)
Photo #9: View of MW-5R facing north (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 12: View of MW-11 facing northeast (5/16/2023)
Photo #11: Missing manhole cover on MW-7 (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 14: View of MW-13 on a slope facing northwest (5/16/2023)
Photo #13: View of MW-12 facing southeast (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 16: View of MW-15 facing south (5/16/2023)
Photo #15: View of MW-14 facing northeast (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 18: View of MW-17 facing northwest (5/16/2023)
Photo #17: View of MW-16 facing west (5/16/2023)
ATC Associates of North Carolina, P.C.
7606 Whitehall Exec Ctr Dr, Ste 800
Charlotte, NC 28273
[phone]
PHOTOGRAPHS
ATC PROJECT NO: SLT1645701
REVIEWED BY: AQ SCALE: NTS DATE: 3/2023
Stephen’s Exxon
Incident No. 16457
20655 NC Highway 88
Creston, Ashe County, NC, 28615
Photo # 20: View of MW-11 (upper left), AS-1 (lower left) and RW-1 (right) facing northeast (5/16/2023)
Photo #19: AS-1 found under gravel using metal detector (5/16/2023)

APPENDIX C
LABORATORY REPORT
#=CL#
May 25, 2023
LIMS USE: FR - AL QUARLES
LIMS OBJECT ID: 92667997
92667997
Project:
Pace Project No.:
RE:
Al Quarles
ATC Group Services LLC
7606 Whitehall Executive Cente
Suite 800
Charlotte, NC 28273
16457 Stephen’s Exxon
Dear Al Quarles:
Enclosed are the analytical results for sample(s) received by the laboratory on May 17, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Lab ID Sample ID Matrix Date Collected Date Received
92667997001 MW-2 Water 05/16/23 09:10 05/17/23 15:10
92667997002 MW-3 Water 05/15/23 13:55 05/17/23 15:10
92667997003 MW-5R Water 05/16/23 11:05 05/17/23 15:10
92667997004 MW-7 Water 05/16/23 10:25 05/17/23 15:10
92667997005 MW-11 Water 05/15/23 13:25 05/17/23 15:10
92667997006 MW-12 Water 05/16/23 09:05 05/17/23 15:10
92667997007 MW-13 Water 05/15/23 14:30 05/17/23 15:10
92667997008 MW-14 Water 05/15/23 14:35 05/17/23 15:10
92667997009 MW-16 Water 05/16/23 09:45 05/17/23 15:10
92667997010 AS-1 Water 05/15/23 13:55 05/17/23 15:10
92667997011 WSW-8 Water 05/16/23 10:50 05/17/23 15:10
92667997012 MW-17 Water 05/16/23 10:15 05/17/23 15:10
92667997013 FB-1 Water 05/16/23 10:20 05/17/23 15:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92667997001 MW-2 SM 6200B 70 PASI-CSAS
92667997002 MW-3 SM 6200B 70 PASI-CSAS
92667997003 MW-5R SM 6200B 70 PASI-CSAS
92667997004 MW-7 SM 6200B 70 PASI-CSAS
92667997005 MW-11 EPA 625.1 58 PASI-CPKS
SM 6200B 70 PASI-CSAS
92667997006 MW-12 SM 6200B 70 PASI-CSAS
92667997007 MW-13 EPA 625.1 58 PASI-CPKS
SM 6200B 70 PASI-CSAS
92667997008 MW-14 SM 6200B 70 PASI-CSAS
92667997009 MW-16 SM 6200B 70 PASI-CSAS
92667997010 AS-1 EPA 625.1 58 PASI-CPKS
SM 6200B 70 PASI-CSAS
92667997011 WSW-8 EPA 625.1 58 PASI-CPKS
SM 6200B 70 PASI-CSAS
92667997012 MW-17 SM 6200B 70 PASI-CSAS
92667997013 FB-1 SM 6200B 70 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-2 Lab ID: 92667997001 Collected: 05/16/23 09:10 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/22/23 19:11 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/22/23 19:11 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/22/23 19:11 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/22/23 19:11 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/22/23 19:11 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/22/23 19:11 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/22/23 19:11 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/22/23 19:11 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/22/23 19:11 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/22/23 19:11 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/22/23 19:11 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/22/23 19:11 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/22/23 19:11 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/22/23 19:11 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/22/23 19:11 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/22/23 19:11 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/22/23 19:11 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/22/23 19:11 74-87-3 L11.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/22/23 19:11 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/22/23 19:11 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/22/23 19:11 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/22/23 19:11 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/22/23 19:11 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/22/23 19:11 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/22/23 19:11 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/22/23 19:11 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/22/23 19:11 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/22/23 19:11 75-71-8 IH,L10.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/22/23 19:11 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/22/23 19:11 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/22/23 19:11 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/22/23 19:11 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/22/23 19:11 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/22/23 19:11 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/22/23 19:11 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/22/23 19:11 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/22/23 19:11 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/22/23 19:11 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/22/23 19:11 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/22/23 19:11 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/22/23 19:11 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/22/23 19:11 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/22/23 19:11 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/22/23 19:11 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/22/23 19:11 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-2 Lab ID: 92667997001 Collected: 05/16/23 09:10 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/22/23 19:11 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/22/23 19:11 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/22/23 19:11 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/22/23 19:11 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/22/23 19:11 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/22/23 19:11 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/22/23 19:11 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/22/23 19:11 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/22/23 19:11 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/22/23 19:11 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/22/23 19:11 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/22/23 19:11 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/22/23 19:11 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/22/23 19:11 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/22/23 19:11 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/22/23 19:11 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/22/23 19:11 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/22/23 19:11 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/22/23 19:11 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/22/23 19:11 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/22/23 19:11 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/22/23 19:11 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)122 %05/22/23 19:11 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %05/22/23 19:11 460-00-470-130 1
Toluene-d8 (S)102 %05/22/23 19:11 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-3 Lab ID: 92667997002 Collected: 05/15/23 13:55 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 00:12 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 00:12 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/23/23 00:12 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 00:12 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 00:12 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 00:12 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 00:12 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 00:12 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 00:12 75-65-0 M150.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 00:12 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/23/23 00:12 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/23/23 00:12 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 00:12 762-75-4 P550.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 00:12 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 00:12 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 00:12 75-00-3 L1,M01.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 00:12 67-66-3 M10.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 00:12 74-87-3 M11.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 00:12 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 00:12 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 00:12 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 00:12 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 00:12 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 00:12 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 00:12 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 00:12 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 00:12 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 00:12 75-71-8 IH,L1,
M00.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/23/23 00:12 75-34-3 M10.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 00:12 107-06-2 M10.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 00:12 75-35-4 M10.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 00:12 156-59-2 M10.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 00:12 156-60-5 M10.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 00:12 78-87-5 M10.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 00:12 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 00:12 594-20-7 M10.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 00:12 563-58-6 M10.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:12 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:12 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/23/23 00:12 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 00:12 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/23/23 00:12 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 00:12 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 00:12 87-68-32.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-3 Lab ID: 92667997002 Collected: 05/15/23 13:55 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Isopropylbenzene (Cumene)<0.33 ug/L 05/23/23 00:12 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 05/23/23 00:12 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 00:12 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/23/23 00:12 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/23/23 00:12 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 00:12 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 00:12 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 00:12 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 00:12 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/23/23 00:12 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 00:12 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 00:12 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 00:12 71-55-6 M10.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 00:12 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 00:12 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 00:12 75-69-4 M11.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 00:12 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/23/23 00:12 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/23/23 00:12 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 00:12 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/23/23 00:12 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/23/23 00:12 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/23/23 00:12 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)124 %05/23/23 00:12 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %05/23/23 00:12 460-00-470-130 1
Toluene-d8 (S)102 %05/23/23 00:12 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-5R Lab ID: 92667997003 Collected: 05/16/23 11:05 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <364 ug/L 05/22/23 00:14 75-85-41000 364 10
tert-Amylmethyl ether <92.5 ug/L 05/22/23 00:14 994-05-8100 92.5 10
Benzene 6.1 ug/L 05/22/23 00:14 71-43-25.0 3.4 10
Bromobenzene <2.9 ug/L 05/22/23 00:14 108-86-15.0 2.9 10
Bromochloromethane <4.7 ug/L 05/22/23 00:14 74-97-55.0 4.7 10
Bromodichloromethane <3.1 ug/L 05/22/23 00:14 75-27-45.0 3.1 10
Bromoform <3.4 ug/L 05/22/23 00:14 75-25-25.0 3.4 10
Bromomethane <16.6 ug/L 05/22/23 00:14 74-83-950.0 16.6 10
tert-Butyl Alcohol <268 ug/L 05/22/23 00:14 75-65-0500 268 10
n-Butylbenzene <4.9 ug/L 05/22/23 00:14 104-51-85.0 4.9 10
sec-Butylbenzene <4.0 ug/L 05/22/23 00:14 135-98-85.0 4.0 10
tert-Butylbenzene <3.2 ug/L 05/22/23 00:14 98-06-65.0 3.2 10
tert-Butyl Formate <294 ug/L 05/22/23 00:14 762-75-4500 294 10
Carbon tetrachloride <3.3 ug/L 05/22/23 00:14 56-23-55.0 3.3 10
Chlorobenzene <2.8 ug/L 05/22/23 00:14 108-90-75.0 2.8 10
Chloroethane <6.5 ug/L 05/22/23 00:14 75-00-3 L110.0 6.5 10
Chloroform <4.3 ug/L 05/22/23 00:14 67-66-35.0 4.3 10
Chloromethane <5.4 ug/L 05/22/23 00:14 74-87-310.0 5.4 10
2-Chlorotoluene <3.2 ug/L 05/22/23 00:14 95-49-85.0 3.2 10
4-Chlorotoluene <3.2 ug/L 05/22/23 00:14 106-43-45.0 3.2 10
1,2-Dibromo-3-chloropropane <3.4 ug/L 05/22/23 00:14 96-12-810.0 3.4 10
Dibromochloromethane <3.6 ug/L 05/22/23 00:14 124-48-15.0 3.6 10
1,2-Dibromoethane (EDB)<2.7 ug/L 05/22/23 00:14 106-93-45.0 2.7 10
Dibromomethane <3.9 ug/L 05/22/23 00:14 74-95-35.0 3.9 10
1,2-Dichlorobenzene <3.4 ug/L 05/22/23 00:14 95-50-15.0 3.4 10
1,3-Dichlorobenzene <3.4 ug/L 05/22/23 00:14 541-73-15.0 3.4 10
1,4-Dichlorobenzene <3.3 ug/L 05/22/23 00:14 106-46-75.0 3.3 10
Dichlorodifluoromethane <3.5 ug/L 05/22/23 00:14 75-71-8 IH5.0 3.5 10
1,1-Dichloroethane <3.7 ug/L 05/22/23 00:14 75-34-35.0 3.7 10
1,2-Dichloroethane <3.2 ug/L 05/22/23 00:14 107-06-25.0 3.2 10
1,1-Dichloroethene <3.5 ug/L 05/22/23 00:14 75-35-45.0 3.5 10
cis-1,2-Dichloroethene <3.8 ug/L 05/22/23 00:14 156-59-25.0 3.8 10
trans-1,2-Dichloroethene <4.0 ug/L 05/22/23 00:14 156-60-55.0 4.0 10
1,2-Dichloropropane <3.6 ug/L 05/22/23 00:14 78-87-55.0 3.6 10
1,3-Dichloropropane <2.8 ug/L 05/22/23 00:14 142-28-95.0 2.8 10
2,2-Dichloropropane <3.9 ug/L 05/22/23 00:14 594-20-75.0 3.9 10
1,1-Dichloropropene <4.3 ug/L 05/22/23 00:14 563-58-65.0 4.3 10
cis-1,3-Dichloropropene <3.6 ug/L 05/22/23 00:14 10061-01-55.0 3.6 10
trans-1,3-Dichloropropene <3.6 ug/L 05/22/23 00:14 10061-02-65.0 3.6 10
Diisopropyl ether <3.1 ug/L 05/22/23 00:14 108-20-35.0 3.1 10
Ethanol <722 ug/L 05/22/23 00:14 64-17-52000 722 10
Ethylbenzene 574 ug/L 05/22/23 00:14 100-41-45.0 3.0 10
Ethyl-tert-butyl ether <32.4 ug/L 05/22/23 00:14 637-92-3100 32.4 10
Hexachloro-1,3-butadiene <15.3 ug/L 05/22/23 00:14 87-68-320.0 15.3 10
Isopropylbenzene (Cumene)86.0 ug/L 05/22/23 00:14 98-82-85.0 3.3 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-5R Lab ID: 92667997003 Collected: 05/16/23 11:05 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <19.5 ug/L 05/22/23 00:14 75-09-220.0 19.5 10
Methyl-tert-butyl ether <4.2 ug/L 05/22/23 00:14 1634-04-45.0 4.2 10
Naphthalene 185 ug/L 05/22/23 00:14 91-20-320.0 6.4 10
n-Propylbenzene 357 ug/L 05/22/23 00:14 103-65-15.0 3.4 10
Styrene 4.9J ug/L 05/22/23 00:14 100-42-55.0 2.9 10
1,1,1,2-Tetrachloroethane <3.1 ug/L 05/22/23 00:14 630-20-65.0 3.1 10
1,1,2,2-Tetrachloroethane <2.2 ug/L 05/22/23 00:14 79-34-55.0 2.2 10
Tetrachloroethene <2.9 ug/L 05/22/23 00:14 127-18-45.0 2.9 10
Toluene 86.9 ug/L 05/22/23 00:14 108-88-35.0 2.4 10
1,2,3-Trichlorobenzene <8.1 ug/L 05/22/23 00:14 87-61-620.0 8.1 10
1,2,4-Trichlorobenzene <6.4 ug/L 05/22/23 00:14 120-82-120.0 6.4 10
1,1,1-Trichloroethane <3.3 ug/L 05/22/23 00:14 71-55-65.0 3.3 10
1,1,2-Trichloroethane <3.2 ug/L 05/22/23 00:14 79-00-55.0 3.2 10
Trichloroethene <3.8 ug/L 05/22/23 00:14 79-01-65.0 3.8 10
Trichlorofluoromethane <3.0 ug/L 05/22/23 00:14 75-69-410.0 3.0 10
1,2,3-Trichloropropane <2.6 ug/L 05/22/23 00:14 96-18-45.0 2.6 10
1,2,4-Trimethylbenzene 1950 ug/L 05/22/23 00:14 95-63-65.0 5.0 10
1,3,5-Trimethylbenzene 588 ug/L 05/22/23 00:14 108-67-85.0 3.3 10
Vinyl chloride <3.9 ug/L 05/22/23 00:14 75-01-410.0 3.9 10
Xylene (Total)1860 ug/L 05/22/23 00:14 1330-20-710.0 3.4 10
m&p-Xylene 1560 ug/L 05/22/23 00:14 179601-23-110.0 7.1 10
o-Xylene 299 ug/L 05/22/23 00:14 95-47-65.0 3.4 10
Surrogates
1,2-Dichloroethane-d4 (S)117 %05/22/23 00:14 17060-07-070-130 10
4-Bromofluorobenzene (S)98 %05/22/23 00:14 460-00-470-130 10
Toluene-d8 (S)101 %05/22/23 00:14 2037-26-570-130 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-7 Lab ID: 92667997004 Collected: 05/16/23 10:25 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 00:30 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 00:30 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/23/23 00:30 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 00:30 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 00:30 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 00:30 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 00:30 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 00:30 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 00:30 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 00:30 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/23/23 00:30 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/23/23 00:30 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 00:30 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 00:30 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 00:30 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 00:30 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 00:30 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 00:30 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 00:30 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 00:30 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 00:30 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 00:30 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 00:30 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 00:30 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 00:30 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 00:30 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 00:30 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 00:30 75-71-8 IH,L10.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/23/23 00:30 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 00:30 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 00:30 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 00:30 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 00:30 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 00:30 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 00:30 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 00:30 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 00:30 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:30 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:30 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/23/23 00:30 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 00:30 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/23/23 00:30 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 00:30 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 00:30 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/23/23 00:30 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-7 Lab ID: 92667997004 Collected: 05/16/23 10:25 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/23/23 00:30 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 00:30 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/23/23 00:30 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/23/23 00:30 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 00:30 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 00:30 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 00:30 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 00:30 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/23/23 00:30 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 00:30 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 00:30 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 00:30 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 00:30 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 00:30 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 00:30 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 00:30 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/23/23 00:30 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/23/23 00:30 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 00:30 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/23/23 00:30 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/23/23 00:30 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/23/23 00:30 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)120 %05/23/23 00:30 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %05/23/23 00:30 460-00-470-130 1
Toluene-d8 (S)102 %05/23/23 00:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-11 Lab ID: 92667997005 Collected: 05/15/23 13:25 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene <1.7 ug/L 05/19/23 23:20 83-32-905/18/23 13:074.2 1.7 1
Acenaphthylene <1.6 ug/L 05/19/23 23:20 208-96-805/18/23 13:074.2 1.6 1
Anthracene <1.9 ug/L 05/19/23 23:20 120-12-705/18/23 13:074.2 1.9 1
Benzo(a)anthracene <2.2 ug/L 05/19/23 23:20 56-55-305/18/23 13:074.2 2.2 1
Benzo(a)pyrene <2.3 ug/L 05/19/23 23:20 50-32-805/18/23 13:074.2 2.3 1
Benzo(b)fluoranthene <2.2 ug/L 05/19/23 23:20 205-99-205/18/23 13:074.2 2.2 1
Benzo(g,h,i)perylene <2.4 ug/L 05/19/23 23:20 191-24-205/18/23 13:074.2 2.4 1
Benzo(k)fluoranthene <2.3 ug/L 05/19/23 23:20 207-08-905/18/23 13:074.2 2.3 1
4-Bromophenylphenyl ether <1.5 ug/L 05/19/23 23:20 101-55-305/18/23 13:074.2 1.5 1
Butylbenzylphthalate <2.6 ug/L 05/19/23 23:20 85-68-705/18/23 13:074.2 2.6 1
4-Chloro-3-methylphenol <2.8 ug/L 05/19/23 23:20 59-50-705/18/23 13:074.2 2.8 1
bis(2-Chloroethoxy)methane <1.5 ug/L 05/19/23 23:20 111-91-105/18/23 13:078.3 1.5 1
bis(2-Chloroethyl) ether <1.6 ug/L 05/19/23 23:20 111-44-405/18/23 13:074.2 1.6 1
2-Chloronaphthalene <1.4 ug/L 05/19/23 23:20 91-58-7 M105/18/23 13:074.2 1.4 1
2-Chlorophenol <1.0 ug/L 05/19/23 23:20 95-57-805/18/23 13:074.2 1.0 1
4-Chlorophenylphenyl ether <1.7 ug/L 05/19/23 23:20 7005-72-305/18/23 13:074.2 1.7 1
Chrysene <2.3 ug/L 05/19/23 23:20 218-01-905/18/23 13:074.2 2.3 1
Dibenz(a,h)anthracene <2.5 ug/L 05/19/23 23:20 53-70-305/18/23 13:074.2 2.5 1
3,3'-Dichlorobenzidine <6.8 ug/L 05/19/23 23:20 91-94-105/18/23 13:078.3 6.8 1
2,4-Dichlorophenol <1.2 ug/L 05/19/23 23:20 120-83-205/18/23 13:074.2 1.2 1
Diethylphthalate <1.7 ug/L 05/19/23 23:20 84-66-205/18/23 13:074.2 1.7 1
2,4-Dimethylphenol <1.4 ug/L 05/19/23 23:20 105-67-9 L1,M005/18/23 13:078.3 1.4 1
Dimethylphthalate <1.8 ug/L 05/19/23 23:20 131-11-305/18/23 13:074.2 1.8 1
Di-n-butylphthalate <1.8 ug/L 05/19/23 23:20 84-74-205/18/23 13:074.2 1.8 1
4,6-Dinitro-2-methylphenol <6.5 ug/L 05/19/23 23:20 534-52-105/18/23 13:078.3 6.5 1
2,4-Dinitrophenol <21.7 ug/L 05/19/23 23:20 51-28-505/18/23 13:0741.7 21.7 1
2,4-Dinitrotoluene <1.4 ug/L 05/19/23 23:20 121-14-205/18/23 13:074.2 1.4 1
2,6-Dinitrotoluene <1.4 ug/L 05/19/23 23:20 606-20-205/18/23 13:074.2 1.4 1
Di-n-octylphthalate <3.3 ug/L 05/19/23 23:20 117-84-005/18/23 13:074.2 3.3 1
bis(2-Ethylhexyl)phthalate <3.1 ug/L 05/19/23 23:20 117-81-705/18/23 13:074.2 3.1 1
Fluoranthene <1.8 ug/L 05/19/23 23:20 206-44-005/18/23 13:074.2 1.8 1
Fluorene 3.0J ug/L 05/19/23 23:20 86-73-705/18/23 13:074.2 1.7 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/19/23 23:20 87-68-3 M1,R105/18/23 13:074.2 1.5 1
Hexachlorobenzene <1.8 ug/L 05/19/23 23:20 118-74-105/18/23 13:074.2 1.8 1
Hexachlorocyclopentadiene <1.3 ug/L 05/19/23 23:20 77-47-4 R105/18/23 13:078.3 1.3 1
Hexachloroethane <1.2 ug/L 05/19/23 23:20 67-72-1 M1,R105/18/23 13:074.2 1.2 1
Indeno(1,2,3-cd)pyrene <2.4 ug/L 05/19/23 23:20 193-39-505/18/23 13:074.2 2.4 1
Isophorone <1.4 ug/L 05/19/23 23:20 78-59-105/18/23 13:078.3 1.4 1
Naphthalene 16.7 ug/L 05/19/23 23:20 91-20-305/18/23 13:074.2 1.7 1
Nitrobenzene <1.6 ug/L 05/19/23 23:20 98-95-305/18/23 13:074.2 1.6 1
2-Nitrophenol <1.2 ug/L 05/19/23 23:20 88-75-505/18/23 13:074.2 1.2 1
4-Nitrophenol <5.5 ug/L 05/19/23 23:20 100-02-705/18/23 13:078.3 5.5 1
N-Nitrosodimethylamine <1.6 ug/L 05/19/23 23:20 62-75-905/18/23 13:074.2 1.6 1
N-Nitroso-di-n-propylamine <1.1 ug/L 05/19/23 23:20 621-64-705/18/23 13:074.2 1.1 1
N-Nitrosodiphenylamine <2.5 ug/L 05/19/23 23:20 86-30-605/18/23 13:078.3 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-11 Lab ID: 92667997005 Collected: 05/15/23 13:25 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
2,2'-Oxybis(1-chloropropane)<0.96 ug/L 05/19/23 23:20 108-60-105/18/23 13:074.2 0.96 1
Pentachlorophenol <3.1 ug/L 05/19/23 23:20 87-86-505/18/23 13:078.3 3.1 1
Phenanthrene <1.7 ug/L 05/19/23 23:20 85-01-805/18/23 13:074.2 1.7 1
Phenol <1.1 ug/L 05/19/23 23:20 108-95-205/18/23 13:074.2 1.1 1
Pyrene <1.8 ug/L 05/19/23 23:20 129-00-005/18/23 13:074.2 1.8 1
1,2,4-Trichlorobenzene <1.4 ug/L 05/19/23 23:20 120-82-1 M1,R105/18/23 13:074.2 1.4 1
2,4,6-Trichlorophenol <1.3 ug/L 05/19/23 23:20 88-06-205/18/23 13:078.3 1.3 1
Surrogates
Nitrobenzene-d5 (S)86 %05/19/23 23:20 4165-60-005/18/23 13:0710-120 1
2-Fluorobiphenyl (S)76 %05/19/23 23:20 321-60-805/18/23 13:0715-120 1
Terphenyl-d14 (S)85 %05/19/23 23:20 1718-51-005/18/23 13:0711-131 1
Phenol-d6 (S)43 %05/19/23 23:20 13127-88-305/18/23 13:0710-120 1
2-Fluorophenol (S)48 %05/19/23 23:20 367-12-405/18/23 13:0710-120 1
2,4,6-Tribromophenol (S)85 %05/19/23 23:20 118-79-605/18/23 13:0710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 05:34 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 05:34 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/23/23 05:34 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 05:34 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 05:34 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 05:34 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 05:34 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 05:34 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 05:34 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 05:34 104-51-80.50 0.49 1
sec-Butylbenzene 11.7 ug/L 05/23/23 05:34 135-98-80.50 0.40 1
tert-Butylbenzene 2.6 ug/L 05/23/23 05:34 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 05:34 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 05:34 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 05:34 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 05:34 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 05:34 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 05:34 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 05:34 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 05:34 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 05:34 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 05:34 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 05:34 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 05:34 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 05:34 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 05:34 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 05:34 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 05:34 75-71-8 IH,L10.50 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-11 Lab ID: 92667997005 Collected: 05/15/23 13:25 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethane <0.37 ug/L 05/23/23 05:34 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 05:34 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 05:34 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 05:34 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 05:34 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 05:34 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 05:34 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 05:34 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 05:34 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 05:34 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 05:34 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/23/23 05:34 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 05:34 64-17-5200 72.2 1
Ethylbenzene 0.92 ug/L 05/23/23 05:34 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 05:34 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 05:34 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)5.1 ug/L 05/23/23 05:34 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 05/23/23 05:34 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 05:34 1634-04-40.50 0.42 1
Naphthalene 36.1 ug/L 05/23/23 05:34 91-20-32.0 0.64 1
n-Propylbenzene 7.2 ug/L 05/23/23 05:34 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 05:34 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 05:34 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 05:34 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 05:34 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/23/23 05:34 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 05:34 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 05:34 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 05:34 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 05:34 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 05:34 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 05:34 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 05:34 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 107 ug/L 05/23/23 05:34 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/23/23 05:34 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 05:34 75-01-41.0 0.39 1
Xylene (Total)0.38J ug/L 05/23/23 05:34 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/23/23 05:34 179601-23-11.0 0.71 1
o-Xylene 0.38J ug/L 05/23/23 05:34 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)121 %05/23/23 05:34 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %05/23/23 05:34 460-00-470-130 1
Toluene-d8 (S)102 %05/23/23 05:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-12 Lab ID: 92667997006 Collected: 05/16/23 09:05 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 00:47 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 00:47 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/23/23 00:47 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 00:47 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 00:47 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 00:47 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 00:47 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 00:47 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 00:47 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 00:47 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/23/23 00:47 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/23/23 00:47 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 00:47 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 00:47 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 00:47 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 00:47 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 00:47 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 00:47 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 00:47 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 00:47 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 00:47 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 00:47 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 00:47 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 00:47 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 00:47 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 00:47 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 00:47 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 00:47 75-71-8 IH,L10.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/23/23 00:47 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 00:47 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 00:47 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 00:47 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 00:47 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 00:47 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 00:47 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 00:47 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 00:47 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:47 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 00:47 10061-02-60.50 0.36 1
Diisopropyl ether 0.90 ug/L 05/23/23 00:47 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 00:47 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/23/23 00:47 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 00:47 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 00:47 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/23/23 00:47 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-12 Lab ID: 92667997006 Collected: 05/16/23 09:05 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/23/23 00:47 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 00:47 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/23/23 00:47 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/23/23 00:47 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 00:47 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 00:47 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 00:47 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 00:47 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/23/23 00:47 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 00:47 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 00:47 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 00:47 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 00:47 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 00:47 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 00:47 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 00:47 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/23/23 00:47 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/23/23 00:47 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 00:47 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/23/23 00:47 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/23/23 00:47 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/23/23 00:47 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)124 %05/23/23 00:47 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %05/23/23 00:47 460-00-470-130 1
Toluene-d8 (S)103 %05/23/23 00:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-13 Lab ID: 92667997007 Collected: 05/15/23 14:30 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene <2.0 ug/L 05/20/23 00:37 83-32-905/18/23 13:075.0 2.0 1
Acenaphthylene <2.0 ug/L 05/20/23 00:37 208-96-805/18/23 13:075.0 2.0 1
Anthracene <2.3 ug/L 05/20/23 00:37 120-12-705/18/23 13:075.0 2.3 1
Benzo(a)anthracene <2.7 ug/L 05/20/23 00:37 56-55-305/18/23 13:075.0 2.7 1
Benzo(a)pyrene <2.8 ug/L 05/20/23 00:37 50-32-805/18/23 13:075.0 2.8 1
Benzo(b)fluoranthene <2.6 ug/L 05/20/23 00:37 205-99-205/18/23 13:075.0 2.6 1
Benzo(g,h,i)perylene <2.8 ug/L 05/20/23 00:37 191-24-205/18/23 13:075.0 2.8 1
Benzo(k)fluoranthene <2.7 ug/L 05/20/23 00:37 207-08-905/18/23 13:075.0 2.7 1
4-Bromophenylphenyl ether <1.8 ug/L 05/20/23 00:37 101-55-305/18/23 13:075.0 1.8 1
Butylbenzylphthalate <3.1 ug/L 05/20/23 00:37 85-68-705/18/23 13:075.0 3.1 1
4-Chloro-3-methylphenol <3.3 ug/L 05/20/23 00:37 59-50-705/18/23 13:075.0 3.3 1
bis(2-Chloroethoxy)methane <1.8 ug/L 05/20/23 00:37 111-91-105/18/23 13:0710.0 1.8 1
bis(2-Chloroethyl) ether <1.9 ug/L 05/20/23 00:37 111-44-405/18/23 13:075.0 1.9 1
2-Chloronaphthalene <1.7 ug/L 05/20/23 00:37 91-58-705/18/23 13:075.0 1.7 1
2-Chlorophenol <1.2 ug/L 05/20/23 00:37 95-57-805/18/23 13:075.0 1.2 1
4-Chlorophenylphenyl ether <2.0 ug/L 05/20/23 00:37 7005-72-305/18/23 13:075.0 2.0 1
Chrysene <2.8 ug/L 05/20/23 00:37 218-01-905/18/23 13:075.0 2.8 1
Dibenz(a,h)anthracene <3.0 ug/L 05/20/23 00:37 53-70-305/18/23 13:075.0 3.0 1
3,3'-Dichlorobenzidine <8.1 ug/L 05/20/23 00:37 91-94-105/18/23 13:0710.0 8.1 1
2,4-Dichlorophenol <1.4 ug/L 05/20/23 00:37 120-83-205/18/23 13:075.0 1.4 1
Diethylphthalate <2.0 ug/L 05/20/23 00:37 84-66-205/18/23 13:075.0 2.0 1
2,4-Dimethylphenol <1.7 ug/L 05/20/23 00:37 105-67-9 L105/18/23 13:0710.0 1.7 1
Dimethylphthalate <2.1 ug/L 05/20/23 00:37 131-11-305/18/23 13:075.0 2.1 1
Di-n-butylphthalate <2.2 ug/L 05/20/23 00:37 84-74-205/18/23 13:075.0 2.2 1
4,6-Dinitro-2-methylphenol <7.8 ug/L 05/20/23 00:37 534-52-105/18/23 13:0710.0 7.8 1
2,4-Dinitrophenol <26.0 ug/L 05/20/23 00:37 51-28-505/18/23 13:0750.0 26.0 1
2,4-Dinitrotoluene <1.6 ug/L 05/20/23 00:37 121-14-205/18/23 13:075.0 1.6 1
2,6-Dinitrotoluene <1.7 ug/L 05/20/23 00:37 606-20-205/18/23 13:075.0 1.7 1
Di-n-octylphthalate <3.9 ug/L 05/20/23 00:37 117-84-005/18/23 13:075.0 3.9 1
bis(2-Ethylhexyl)phthalate <3.7 ug/L 05/20/23 00:37 117-81-705/18/23 13:075.0 3.7 1
Fluoranthene <2.2 ug/L 05/20/23 00:37 206-44-005/18/23 13:075.0 2.2 1
Fluorene <2.1 ug/L 05/20/23 00:37 86-73-705/18/23 13:075.0 2.1 1
Hexachloro-1,3-butadiene <1.8 ug/L 05/20/23 00:37 87-68-305/18/23 13:075.0 1.8 1
Hexachlorobenzene <2.2 ug/L 05/20/23 00:37 118-74-105/18/23 13:075.0 2.2 1
Hexachlorocyclopentadiene <1.6 ug/L 05/20/23 00:37 77-47-405/18/23 13:0710.0 1.6 1
Hexachloroethane <1.4 ug/L 05/20/23 00:37 67-72-105/18/23 13:075.0 1.4 1
Indeno(1,2,3-cd)pyrene <2.9 ug/L 05/20/23 00:37 193-39-505/18/23 13:075.0 2.9 1
Isophorone <1.7 ug/L 05/20/23 00:37 78-59-105/18/23 13:0710.0 1.7 1
Naphthalene <2.1 ug/L 05/20/23 00:37 91-20-305/18/23 13:075.0 2.1 1
Nitrobenzene <1.9 ug/L 05/20/23 00:37 98-95-305/18/23 13:075.0 1.9 1
2-Nitrophenol <1.4 ug/L 05/20/23 00:37 88-75-505/18/23 13:075.0 1.4 1
4-Nitrophenol <6.6 ug/L 05/20/23 00:37 100-02-705/18/23 13:0710.0 6.6 1
N-Nitrosodimethylamine <1.9 ug/L 05/20/23 00:37 62-75-905/18/23 13:075.0 1.9 1
N-Nitroso-di-n-propylamine <1.3 ug/L 05/20/23 00:37 621-64-705/18/23 13:075.0 1.3 1
N-Nitrosodiphenylamine <3.0 ug/L 05/20/23 00:37 86-30-605/18/23 13:0710.0 3.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-13 Lab ID: 92667997007 Collected: 05/15/23 14:30 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
2,2'-Oxybis(1-chloropropane)<1.2 ug/L 05/20/23 00:37 108-60-105/18/23 13:075.0 1.2 1
Pentachlorophenol <3.8 ug/L 05/20/23 00:37 87-86-505/18/23 13:0710.0 3.8 1
Phenanthrene <2.0 ug/L 05/20/23 00:37 85-01-805/18/23 13:075.0 2.0 1
Phenol <1.4 ug/L 05/20/23 00:37 108-95-205/18/23 13:075.0 1.4 1
Pyrene <2.2 ug/L 05/20/23 00:37 129-00-005/18/23 13:075.0 2.2 1
1,2,4-Trichlorobenzene <1.7 ug/L 05/20/23 00:37 120-82-105/18/23 13:075.0 1.7 1
2,4,6-Trichlorophenol <1.6 ug/L 05/20/23 00:37 88-06-205/18/23 13:0710.0 1.6 1
Surrogates
Nitrobenzene-d5 (S)66 %05/20/23 00:37 4165-60-005/18/23 13:0710-120 1
2-Fluorobiphenyl (S)58 %05/20/23 00:37 321-60-805/18/23 13:0715-120 1
Terphenyl-d14 (S)69 %05/20/23 00:37 1718-51-005/18/23 13:0711-131 1
Phenol-d6 (S)38 %05/20/23 00:37 13127-88-305/18/23 13:0710-120 1
2-Fluorophenol (S)50 %05/20/23 00:37 367-12-405/18/23 13:0710-120 1
2,4,6-Tribromophenol (S)80 %05/20/23 00:37 118-79-605/18/23 13:0710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/21/23 17:46 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/21/23 17:46 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/21/23 17:46 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/21/23 17:46 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/21/23 17:46 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/21/23 17:46 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/21/23 17:46 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/21/23 17:46 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/21/23 17:46 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/21/23 17:46 104-51-80.50 0.49 1
sec-Butylbenzene 2.5 ug/L 05/21/23 17:46 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/21/23 17:46 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/21/23 17:46 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/21/23 17:46 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/21/23 17:46 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/21/23 17:46 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/21/23 17:46 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/21/23 17:46 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/21/23 17:46 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/21/23 17:46 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/21/23 17:46 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/21/23 17:46 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/21/23 17:46 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/21/23 17:46 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/21/23 17:46 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/21/23 17:46 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/21/23 17:46 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/21/23 17:46 75-71-8 IH0.50 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-13 Lab ID: 92667997007 Collected: 05/15/23 14:30 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethane <0.37 ug/L 05/21/23 17:46 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/21/23 17:46 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/21/23 17:46 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/21/23 17:46 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/21/23 17:46 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/21/23 17:46 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/21/23 17:46 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/21/23 17:46 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/21/23 17:46 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:46 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:46 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/21/23 17:46 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/21/23 17:46 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/21/23 17:46 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/21/23 17:46 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/21/23 17:46 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.82 ug/L 05/21/23 17:46 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 05/21/23 17:46 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/21/23 17:46 1634-04-40.50 0.42 1
Naphthalene 2.2 ug/L 05/21/23 17:46 91-20-32.0 0.64 1
n-Propylbenzene 1.2 ug/L 05/21/23 17:46 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/21/23 17:46 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/21/23 17:46 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/21/23 17:46 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/21/23 17:46 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/21/23 17:46 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/21/23 17:46 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/21/23 17:46 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/21/23 17:46 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/21/23 17:46 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/21/23 17:46 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/21/23 17:46 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/21/23 17:46 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 10.6 ug/L 05/21/23 17:46 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/21/23 17:46 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/21/23 17:46 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/21/23 17:46 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/21/23 17:46 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/21/23 17:46 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)122 %05/21/23 17:46 17060-07-070-130 1
4-Bromofluorobenzene (S)95 %05/21/23 17:46 460-00-470-130 1
Toluene-d8 (S)103 %05/21/23 17:46 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-14 Lab ID: 92667997008 Collected: 05/15/23 14:35 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/21/23 17:10 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/21/23 17:10 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/21/23 17:10 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/21/23 17:10 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/21/23 17:10 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/21/23 17:10 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/21/23 17:10 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/21/23 17:10 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/21/23 17:10 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/21/23 17:10 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/21/23 17:10 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/21/23 17:10 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/21/23 17:10 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/21/23 17:10 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/21/23 17:10 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/21/23 17:10 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/21/23 17:10 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/21/23 17:10 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/21/23 17:10 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/21/23 17:10 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/21/23 17:10 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/21/23 17:10 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/21/23 17:10 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/21/23 17:10 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/21/23 17:10 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/21/23 17:10 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/21/23 17:10 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/21/23 17:10 75-71-8 IH0.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/21/23 17:10 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/21/23 17:10 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/21/23 17:10 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/21/23 17:10 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/21/23 17:10 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/21/23 17:10 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/21/23 17:10 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/21/23 17:10 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/21/23 17:10 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:10 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:10 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/21/23 17:10 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/21/23 17:10 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/21/23 17:10 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/21/23 17:10 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/21/23 17:10 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/21/23 17:10 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-14 Lab ID: 92667997008 Collected: 05/15/23 14:35 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/21/23 17:10 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/21/23 17:10 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/21/23 17:10 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/21/23 17:10 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/21/23 17:10 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/21/23 17:10 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/21/23 17:10 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/21/23 17:10 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/21/23 17:10 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/21/23 17:10 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/21/23 17:10 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/21/23 17:10 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/21/23 17:10 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/21/23 17:10 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/21/23 17:10 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/21/23 17:10 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/21/23 17:10 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/21/23 17:10 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/21/23 17:10 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/21/23 17:10 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/21/23 17:10 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/21/23 17:10 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)123 %05/21/23 17:10 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %05/21/23 17:10 460-00-470-130 1
Toluene-d8 (S)104 %05/21/23 17:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-16 Lab ID: 92667997009 Collected: 05/16/23 09:45 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/21/23 17:28 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/21/23 17:28 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/21/23 17:28 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/21/23 17:28 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/21/23 17:28 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/21/23 17:28 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/21/23 17:28 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/21/23 17:28 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/21/23 17:28 75-65-050.0 26.8 1
n-Butylbenzene 1.2 ug/L 05/21/23 17:28 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/21/23 17:28 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/21/23 17:28 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/21/23 17:28 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/21/23 17:28 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/21/23 17:28 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/21/23 17:28 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/21/23 17:28 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/21/23 17:28 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/21/23 17:28 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/21/23 17:28 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/21/23 17:28 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/21/23 17:28 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/21/23 17:28 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/21/23 17:28 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/21/23 17:28 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/21/23 17:28 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/21/23 17:28 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/21/23 17:28 75-71-8 IH0.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/21/23 17:28 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/21/23 17:28 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/21/23 17:28 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/21/23 17:28 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/21/23 17:28 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/21/23 17:28 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/21/23 17:28 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/21/23 17:28 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/21/23 17:28 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:28 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/21/23 17:28 10061-02-60.50 0.36 1
Diisopropyl ether 0.44J ug/L 05/21/23 17:28 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/21/23 17:28 64-17-5200 72.2 1
Ethylbenzene 1.6 ug/L 05/21/23 17:28 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/21/23 17:28 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/21/23 17:28 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)4.8 ug/L 05/21/23 17:28 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-16 Lab ID: 92667997009 Collected: 05/16/23 09:45 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/21/23 17:28 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/21/23 17:28 1634-04-40.50 0.42 1
Naphthalene 3.9 ug/L 05/21/23 17:28 91-20-32.0 0.64 1
n-Propylbenzene 8.5 ug/L 05/21/23 17:28 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/21/23 17:28 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/21/23 17:28 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/21/23 17:28 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/21/23 17:28 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/21/23 17:28 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/21/23 17:28 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/21/23 17:28 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/21/23 17:28 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/21/23 17:28 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/21/23 17:28 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/21/23 17:28 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/21/23 17:28 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 9.0 ug/L 05/21/23 17:28 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/21/23 17:28 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/21/23 17:28 75-01-41.0 0.39 1
Xylene (Total)1.6 ug/L 05/21/23 17:28 1330-20-71.0 0.34 1
m&p-Xylene 1.2 ug/L 05/21/23 17:28 179601-23-11.0 0.71 1
o-Xylene 0.39J ug/L 05/21/23 17:28 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)123 %05/21/23 17:28 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %05/21/23 17:28 460-00-470-130 1
Toluene-d8 (S)101 %05/21/23 17:28 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: AS-1 Lab ID: 92667997010 Collected: 05/15/23 13:55 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene <1.7 ug/L 05/20/23 01:02 83-32-905/18/23 13:074.3 1.7 1
Acenaphthylene <1.7 ug/L 05/20/23 01:02 208-96-805/18/23 13:074.3 1.7 1
Anthracene <2.0 ug/L 05/20/23 01:02 120-12-705/18/23 13:074.3 2.0 1
Benzo(a)anthracene <2.3 ug/L 05/20/23 01:02 56-55-305/18/23 13:074.3 2.3 1
Benzo(a)pyrene <2.4 ug/L 05/20/23 01:02 50-32-805/18/23 13:074.3 2.4 1
Benzo(b)fluoranthene <2.3 ug/L 05/20/23 01:02 205-99-205/18/23 13:074.3 2.3 1
Benzo(g,h,i)perylene <2.5 ug/L 05/20/23 01:02 191-24-205/18/23 13:074.3 2.5 1
Benzo(k)fluoranthene <2.4 ug/L 05/20/23 01:02 207-08-905/18/23 13:074.3 2.4 1
4-Bromophenylphenyl ether <1.5 ug/L 05/20/23 01:02 101-55-305/18/23 13:074.3 1.5 1
Butylbenzylphthalate <2.7 ug/L 05/20/23 01:02 85-68-705/18/23 13:074.3 2.7 1
4-Chloro-3-methylphenol <2.9 ug/L 05/20/23 01:02 59-50-705/18/23 13:074.3 2.9 1
bis(2-Chloroethoxy)methane <1.6 ug/L 05/20/23 01:02 111-91-105/18/23 13:078.7 1.6 1
bis(2-Chloroethyl) ether <1.7 ug/L 05/20/23 01:02 111-44-405/18/23 13:074.3 1.7 1
2-Chloronaphthalene <1.5 ug/L 05/20/23 01:02 91-58-705/18/23 13:074.3 1.5 1
2-Chlorophenol <1.0 ug/L 05/20/23 01:02 95-57-805/18/23 13:074.3 1.0 1
4-Chlorophenylphenyl ether <1.7 ug/L 05/20/23 01:02 7005-72-305/18/23 13:074.3 1.7 1
Chrysene <2.4 ug/L 05/20/23 01:02 218-01-905/18/23 13:074.3 2.4 1
Dibenz(a,h)anthracene <2.6 ug/L 05/20/23 01:02 53-70-305/18/23 13:074.3 2.6 1
3,3'-Dichlorobenzidine <7.1 ug/L 05/20/23 01:02 91-94-105/18/23 13:078.7 7.1 1
2,4-Dichlorophenol <1.2 ug/L 05/20/23 01:02 120-83-205/18/23 13:074.3 1.2 1
Diethylphthalate <1.8 ug/L 05/20/23 01:02 84-66-205/18/23 13:074.3 1.8 1
2,4-Dimethylphenol <1.5 ug/L 05/20/23 01:02 105-67-9 L105/18/23 13:078.7 1.5 1
Dimethylphthalate <1.9 ug/L 05/20/23 01:02 131-11-305/18/23 13:074.3 1.9 1
Di-n-butylphthalate <1.9 ug/L 05/20/23 01:02 84-74-205/18/23 13:074.3 1.9 1
4,6-Dinitro-2-methylphenol <6.8 ug/L 05/20/23 01:02 534-52-105/18/23 13:078.7 6.8 1
2,4-Dinitrophenol <22.6 ug/L 05/20/23 01:02 51-28-505/18/23 13:0743.5 22.6 1
2,4-Dinitrotoluene <1.4 ug/L 05/20/23 01:02 121-14-205/18/23 13:074.3 1.4 1
2,6-Dinitrotoluene <1.5 ug/L 05/20/23 01:02 606-20-205/18/23 13:074.3 1.5 1
Di-n-octylphthalate <3.4 ug/L 05/20/23 01:02 117-84-005/18/23 13:074.3 3.4 1
bis(2-Ethylhexyl)phthalate <3.2 ug/L 05/20/23 01:02 117-81-705/18/23 13:074.3 3.2 1
Fluoranthene <1.9 ug/L 05/20/23 01:02 206-44-005/18/23 13:074.3 1.9 1
Fluorene <1.8 ug/L 05/20/23 01:02 86-73-705/18/23 13:074.3 1.8 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/20/23 01:02 87-68-305/18/23 13:074.3 1.5 1
Hexachlorobenzene <1.9 ug/L 05/20/23 01:02 118-74-105/18/23 13:074.3 1.9 1
Hexachlorocyclopentadiene <1.4 ug/L 05/20/23 01:02 77-47-405/18/23 13:078.7 1.4 1
Hexachloroethane <1.2 ug/L 05/20/23 01:02 67-72-105/18/23 13:074.3 1.2 1
Indeno(1,2,3-cd)pyrene <2.5 ug/L 05/20/23 01:02 193-39-505/18/23 13:074.3 2.5 1
Isophorone <1.4 ug/L 05/20/23 01:02 78-59-105/18/23 13:078.7 1.4 1
Naphthalene <1.8 ug/L 05/20/23 01:02 91-20-305/18/23 13:074.3 1.8 1
Nitrobenzene <1.6 ug/L 05/20/23 01:02 98-95-305/18/23 13:074.3 1.6 1
2-Nitrophenol <1.2 ug/L 05/20/23 01:02 88-75-505/18/23 13:074.3 1.2 1
4-Nitrophenol <5.7 ug/L 05/20/23 01:02 100-02-705/18/23 13:078.7 5.7 1
N-Nitrosodimethylamine <1.6 ug/L 05/20/23 01:02 62-75-905/18/23 13:074.3 1.6 1
N-Nitroso-di-n-propylamine <1.2 ug/L 05/20/23 01:02 621-64-705/18/23 13:074.3 1.2 1
N-Nitrosodiphenylamine <2.6 ug/L 05/20/23 01:02 86-30-605/18/23 13:078.7 2.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: AS-1 Lab ID: 92667997010 Collected: 05/15/23 13:55 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
2,2'-Oxybis(1-chloropropane)<1.0 ug/L 05/20/23 01:02 108-60-105/18/23 13:074.3 1.0 1
Pentachlorophenol <3.3 ug/L 05/20/23 01:02 87-86-505/18/23 13:078.7 3.3 1
Phenanthrene <1.7 ug/L 05/20/23 01:02 85-01-805/18/23 13:074.3 1.7 1
Phenol <1.2 ug/L 05/20/23 01:02 108-95-205/18/23 13:074.3 1.2 1
Pyrene <1.9 ug/L 05/20/23 01:02 129-00-005/18/23 13:074.3 1.9 1
1,2,4-Trichlorobenzene <1.5 ug/L 05/20/23 01:02 120-82-105/18/23 13:074.3 1.5 1
2,4,6-Trichlorophenol <1.3 ug/L 05/20/23 01:02 88-06-205/18/23 13:078.7 1.3 1
Surrogates
Nitrobenzene-d5 (S)63 %05/20/23 01:02 4165-60-005/18/23 13:0710-120 1
2-Fluorobiphenyl (S)58 %05/20/23 01:02 321-60-805/18/23 13:0715-120 1
Terphenyl-d14 (S)81 %05/20/23 01:02 1718-51-005/18/23 13:0711-131 1
Phenol-d6 (S)37 %05/20/23 01:02 13127-88-305/18/23 13:0710-120 1
2-Fluorophenol (S)47 %05/20/23 01:02 367-12-405/18/23 13:0710-120 1
2,4,6-Tribromophenol (S)81 %05/20/23 01:02 118-79-605/18/23 13:0710-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 01:05 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 01:05 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/23/23 01:05 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 01:05 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 01:05 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 01:05 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 01:05 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 01:05 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 01:05 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 01:05 104-51-80.50 0.49 1
sec-Butylbenzene 1.0 ug/L 05/23/23 01:05 135-98-80.50 0.40 1
tert-Butylbenzene 0.51 ug/L 05/23/23 01:05 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 01:05 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 01:05 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 01:05 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 01:05 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 01:05 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 01:05 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 01:05 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 01:05 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 01:05 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 01:05 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 01:05 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 01:05 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 01:05 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 01:05 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 01:05 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 01:05 75-71-8 IH,L10.50 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: AS-1 Lab ID: 92667997010 Collected: 05/15/23 13:55 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethane <0.37 ug/L 05/23/23 01:05 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 01:05 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 01:05 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 01:05 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 01:05 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 01:05 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 01:05 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 01:05 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 01:05 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 01:05 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 01:05 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/23/23 01:05 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 01:05 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/23/23 01:05 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 01:05 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 01:05 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/23/23 01:05 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 05/23/23 01:05 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 01:05 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/23/23 01:05 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/23/23 01:05 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 01:05 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 01:05 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 01:05 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 01:05 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/23/23 01:05 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 01:05 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 01:05 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 01:05 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 01:05 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 01:05 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 01:05 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 01:05 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/23/23 01:05 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/23/23 01:05 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 01:05 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/23/23 01:05 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/23/23 01:05 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/23/23 01:05 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)123 %05/23/23 01:05 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %05/23/23 01:05 460-00-470-130 1
Toluene-d8 (S)102 %05/23/23 01:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: WSW-8 Lab ID: 92667997011 Collected: 05/16/23 10:50 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene <1.7 ug/L 05/23/23 19:06 83-32-905/22/23 13:324.2 1.7 1
Acenaphthylene <1.6 ug/L 05/23/23 19:06 208-96-805/22/23 13:324.2 1.6 1
Anthracene <1.9 ug/L 05/23/23 19:06 120-12-705/22/23 13:324.2 1.9 1
Benzo(a)anthracene <2.2 ug/L 05/23/23 19:06 56-55-305/22/23 13:324.2 2.2 1
Benzo(a)pyrene <2.3 ug/L 05/23/23 19:06 50-32-805/22/23 13:324.2 2.3 1
Benzo(b)fluoranthene <2.2 ug/L 05/23/23 19:06 205-99-205/22/23 13:324.2 2.2 1
Benzo(g,h,i)perylene <2.4 ug/L 05/23/23 19:06 191-24-205/22/23 13:324.2 2.4 1
Benzo(k)fluoranthene <2.3 ug/L 05/23/23 19:06 207-08-905/22/23 13:324.2 2.3 1
4-Bromophenylphenyl ether <1.5 ug/L 05/23/23 19:06 101-55-305/22/23 13:324.2 1.5 1
Butylbenzylphthalate <2.6 ug/L 05/23/23 19:06 85-68-705/22/23 13:324.2 2.6 1
4-Chloro-3-methylphenol <2.8 ug/L 05/23/23 19:06 59-50-705/22/23 13:324.2 2.8 1
bis(2-Chloroethoxy)methane <1.5 ug/L 05/23/23 19:06 111-91-105/22/23 13:328.3 1.5 1
bis(2-Chloroethyl) ether <1.6 ug/L 05/23/23 19:06 111-44-405/22/23 13:324.2 1.6 1
2-Chloronaphthalene <1.4 ug/L 05/23/23 19:06 91-58-7 L205/22/23 13:324.2 1.4 1
2-Chlorophenol <1.0 ug/L 05/23/23 19:06 95-57-805/22/23 13:324.2 1.0 1
4-Chlorophenylphenyl ether <1.7 ug/L 05/23/23 19:06 7005-72-305/22/23 13:324.2 1.7 1
Chrysene <2.3 ug/L 05/23/23 19:06 218-01-905/22/23 13:324.2 2.3 1
Dibenz(a,h)anthracene <2.5 ug/L 05/23/23 19:06 53-70-305/22/23 13:324.2 2.5 1
3,3'-Dichlorobenzidine <6.8 ug/L 05/23/23 19:06 91-94-105/22/23 13:328.3 6.8 1
2,4-Dichlorophenol <1.2 ug/L 05/23/23 19:06 120-83-205/22/23 13:324.2 1.2 1
Diethylphthalate <1.7 ug/L 05/23/23 19:06 84-66-205/22/23 13:324.2 1.7 1
2,4-Dimethylphenol <1.4 ug/L 05/23/23 19:06 105-67-905/22/23 13:328.3 1.4 1
Dimethylphthalate <1.8 ug/L 05/23/23 19:06 131-11-305/22/23 13:324.2 1.8 1
Di-n-butylphthalate <1.8 ug/L 05/23/23 19:06 84-74-205/22/23 13:324.2 1.8 1
4,6-Dinitro-2-methylphenol <6.5 ug/L 05/23/23 19:06 534-52-105/22/23 13:328.3 6.5 1
2,4-Dinitrophenol <21.7 ug/L 05/23/23 19:06 51-28-505/22/23 13:3241.7 21.7 1
2,4-Dinitrotoluene <1.4 ug/L 05/23/23 19:06 121-14-205/22/23 13:324.2 1.4 1
2,6-Dinitrotoluene <1.4 ug/L 05/23/23 19:06 606-20-205/22/23 13:324.2 1.4 1
Di-n-octylphthalate <3.3 ug/L 05/23/23 19:06 117-84-005/22/23 13:324.2 3.3 1
bis(2-Ethylhexyl)phthalate <3.1 ug/L 05/23/23 19:06 117-81-705/22/23 13:324.2 3.1 1
Fluoranthene <1.8 ug/L 05/23/23 19:06 206-44-005/22/23 13:324.2 1.8 1
Fluorene <1.7 ug/L 05/23/23 19:06 86-73-705/22/23 13:324.2 1.7 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 19:06 87-68-3 L205/22/23 13:324.2 1.5 1
Hexachlorobenzene <1.8 ug/L 05/23/23 19:06 118-74-105/22/23 13:324.2 1.8 1
Hexachlorocyclopentadiene <1.3 ug/L 05/23/23 19:06 77-47-4 L205/22/23 13:328.3 1.3 1
Hexachloroethane <1.2 ug/L 05/23/23 19:06 67-72-1 L205/22/23 13:324.2 1.2 1
Indeno(1,2,3-cd)pyrene <2.4 ug/L 05/23/23 19:06 193-39-505/22/23 13:324.2 2.4 1
Isophorone <1.4 ug/L 05/23/23 19:06 78-59-105/22/23 13:328.3 1.4 1
Naphthalene <1.7 ug/L 05/23/23 19:06 91-20-305/22/23 13:324.2 1.7 1
Nitrobenzene <1.6 ug/L 05/23/23 19:06 98-95-305/22/23 13:324.2 1.6 1
2-Nitrophenol <1.2 ug/L 05/23/23 19:06 88-75-505/22/23 13:324.2 1.2 1
4-Nitrophenol <5.5 ug/L 05/23/23 19:06 100-02-705/22/23 13:328.3 5.5 1
N-Nitrosodimethylamine <1.6 ug/L 05/23/23 19:06 62-75-905/22/23 13:324.2 1.6 1
N-Nitroso-di-n-propylamine <1.1 ug/L 05/23/23 19:06 621-64-705/22/23 13:324.2 1.1 1
N-Nitrosodiphenylamine <2.5 ug/L 05/23/23 19:06 86-30-605/22/23 13:328.3 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: WSW-8 Lab ID: 92667997011 Collected: 05/16/23 10:50 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
2,2'-Oxybis(1-chloropropane)<0.96 ug/L 05/23/23 19:06 108-60-105/22/23 13:324.2 0.96 1
Pentachlorophenol <3.1 ug/L 05/23/23 19:06 87-86-505/22/23 13:328.3 3.1 1
Phenanthrene <1.7 ug/L 05/23/23 19:06 85-01-805/22/23 13:324.2 1.7 1
Phenol <1.1 ug/L 05/23/23 19:06 108-95-205/22/23 13:324.2 1.1 1
Pyrene <1.8 ug/L 05/23/23 19:06 129-00-005/22/23 13:324.2 1.8 1
1,2,4-Trichlorobenzene <1.4 ug/L 05/23/23 19:06 120-82-1 L205/22/23 13:324.2 1.4 1
2,4,6-Trichlorophenol <1.3 ug/L 05/23/23 19:06 88-06-205/22/23 13:328.3 1.3 1
Surrogates
Nitrobenzene-d5 (S)0 %05/23/23 19:06 4165-60-0 1g,S005/22/23 13:3210-120 1
2-Fluorobiphenyl (S)6 %05/23/23 19:06 321-60-8 S005/22/23 13:3215-120 1
Terphenyl-d14 (S)86 %05/23/23 19:06 1718-51-005/22/23 13:3211-131 1
Phenol-d6 (S)0 %05/23/23 19:06 13127-88-3 S005/22/23 13:3210-120 1
2-Fluorophenol (S)0 %05/23/23 19:06 367-12-4 S005/22/23 13:3210-120 1
2,4,6-Tribromophenol (S)65 %05/23/23 19:06 118-79-605/22/23 13:3210-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/22/23 01:57 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/22/23 01:57 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/22/23 01:57 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/22/23 01:57 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/22/23 01:57 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/22/23 01:57 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/22/23 01:57 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/22/23 01:57 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/22/23 01:57 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/22/23 01:57 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/22/23 01:57 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/22/23 01:57 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/22/23 01:57 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/22/23 01:57 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/22/23 01:57 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/22/23 01:57 75-00-31.0 0.65 1
Chloroform <0.43 ug/L 05/22/23 01:57 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/22/23 01:57 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/22/23 01:57 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/22/23 01:57 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/22/23 01:57 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/22/23 01:57 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/22/23 01:57 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/22/23 01:57 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/22/23 01:57 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/22/23 01:57 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/22/23 01:57 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/22/23 01:57 75-71-80.50 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: WSW-8 Lab ID: 92667997011 Collected: 05/16/23 10:50 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethane <0.37 ug/L 05/22/23 01:57 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/22/23 01:57 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/22/23 01:57 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/22/23 01:57 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/22/23 01:57 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/22/23 01:57 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/22/23 01:57 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/22/23 01:57 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/22/23 01:57 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/22/23 01:57 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/22/23 01:57 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/22/23 01:57 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/22/23 01:57 64-17-5200 72.2 1
Ethylbenzene 0.85 ug/L 05/22/23 01:57 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/22/23 01:57 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/22/23 01:57 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/22/23 01:57 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 05/22/23 01:57 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/22/23 01:57 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/22/23 01:57 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/22/23 01:57 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/22/23 01:57 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/22/23 01:57 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/22/23 01:57 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/22/23 01:57 127-18-40.50 0.29 1
Toluene 0.83 ug/L 05/22/23 01:57 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/22/23 01:57 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/22/23 01:57 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/22/23 01:57 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/22/23 01:57 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/22/23 01:57 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/22/23 01:57 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/22/23 01:57 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 0.89 ug/L 05/22/23 01:57 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/22/23 01:57 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/22/23 01:57 75-01-41.0 0.39 1
Xylene (Total)4.8 ug/L 05/22/23 01:57 1330-20-71.0 0.34 1
m&p-Xylene 3.5 ug/L 05/22/23 01:57 179601-23-11.0 0.71 1
o-Xylene 1.4 ug/L 05/22/23 01:57 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %05/22/23 01:57 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %05/22/23 01:57 460-00-470-130 1
Toluene-d8 (S)103 %05/22/23 01:57 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-17 Lab ID: 92667997012 Collected: 05/16/23 10:15 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/23/23 04:58 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/23/23 04:58 994-05-810.0 9.2 1
Benzene 12.0 ug/L 05/23/23 04:58 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/23/23 04:58 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/23/23 04:58 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/23/23 04:58 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/23/23 04:58 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/23/23 04:58 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/23/23 04:58 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/23/23 04:58 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/23/23 04:58 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/23/23 04:58 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/23/23 04:58 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/23/23 04:58 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/23/23 04:58 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/23/23 04:58 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/23/23 04:58 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/23/23 04:58 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/23/23 04:58 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/23/23 04:58 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/23/23 04:58 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/23/23 04:58 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/23/23 04:58 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/23/23 04:58 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/23/23 04:58 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/23/23 04:58 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/23/23 04:58 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/23/23 04:58 75-71-8 IH,L10.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/23/23 04:58 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/23/23 04:58 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/23/23 04:58 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/23/23 04:58 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/23/23 04:58 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/23/23 04:58 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/23/23 04:58 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/23/23 04:58 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/23/23 04:58 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/23/23 04:58 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/23/23 04:58 10061-02-60.50 0.36 1
Diisopropyl ether 1.9 ug/L 05/23/23 04:58 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/23/23 04:58 64-17-5200 72.2 1
Ethylbenzene 33.0 ug/L 05/23/23 04:58 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/23/23 04:58 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/23/23 04:58 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)1.7 ug/L 05/23/23 04:58 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: MW-17 Lab ID: 92667997012 Collected: 05/16/23 10:15 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 05/23/23 04:58 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/23/23 04:58 1634-04-40.50 0.42 1
Naphthalene 4.6 ug/L 05/23/23 04:58 91-20-32.0 0.64 1
n-Propylbenzene 5.9 ug/L 05/23/23 04:58 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/23/23 04:58 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/23/23 04:58 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/23/23 04:58 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/23/23 04:58 127-18-40.50 0.29 1
Toluene 1.9 ug/L 05/23/23 04:58 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/23/23 04:58 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/23/23 04:58 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/23/23 04:58 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/23/23 04:58 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/23/23 04:58 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/23/23 04:58 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/23/23 04:58 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 33.6 ug/L 05/23/23 04:58 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 3.2 ug/L 05/23/23 04:58 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/23/23 04:58 75-01-41.0 0.39 1
Xylene (Total)50.1 ug/L 05/23/23 04:58 1330-20-71.0 0.34 1
m&p-Xylene 47.3 ug/L 05/23/23 04:58 179601-23-11.0 0.71 1
o-Xylene 2.8 ug/L 05/23/23 04:58 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)121 %05/23/23 04:58 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %05/23/23 04:58 460-00-470-130 1
Toluene-d8 (S)102 %05/23/23 04:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: FB-1 Lab ID: 92667997013 Collected: 05/16/23 10:20 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 05/22/23 23:54 75-85-4100 36.4 1
tert-Amylmethyl ether <9.2 ug/L 05/22/23 23:54 994-05-810.0 9.2 1
Benzene <0.34 ug/L 05/22/23 23:54 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 05/22/23 23:54 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 05/22/23 23:54 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 05/22/23 23:54 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 05/22/23 23:54 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 05/22/23 23:54 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 05/22/23 23:54 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 05/22/23 23:54 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 05/22/23 23:54 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 05/22/23 23:54 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 05/22/23 23:54 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 05/22/23 23:54 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 05/22/23 23:54 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 05/22/23 23:54 75-00-3 L11.0 0.65 1
Chloroform <0.43 ug/L 05/22/23 23:54 67-66-30.50 0.43 1
Chloromethane <0.54 ug/L 05/22/23 23:54 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 05/22/23 23:54 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 05/22/23 23:54 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 05/22/23 23:54 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 05/22/23 23:54 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 05/22/23 23:54 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 05/22/23 23:54 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 05/22/23 23:54 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 05/22/23 23:54 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 05/22/23 23:54 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 05/22/23 23:54 75-71-8 IH,L10.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 05/22/23 23:54 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 05/22/23 23:54 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 05/22/23 23:54 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 05/22/23 23:54 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 05/22/23 23:54 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 05/22/23 23:54 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 05/22/23 23:54 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 05/22/23 23:54 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 05/22/23 23:54 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 05/22/23 23:54 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 05/22/23 23:54 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 05/22/23 23:54 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 05/22/23 23:54 64-17-5200 72.2 1
Ethylbenzene <0.30 ug/L 05/22/23 23:54 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 05/22/23 23:54 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 05/22/23 23:54 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 05/22/23 23:54 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Sample: FB-1 Lab ID: 92667997013 Collected: 05/16/23 10:20 Received: 05/17/23 15:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride 6.0 ug/L 05/22/23 23:54 75-09-2 B,C02.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 05/22/23 23:54 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 05/22/23 23:54 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 05/22/23 23:54 103-65-10.50 0.34 1
Styrene <0.29 ug/L 05/22/23 23:54 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 05/22/23 23:54 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 05/22/23 23:54 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 05/22/23 23:54 127-18-40.50 0.29 1
Toluene <0.24 ug/L 05/22/23 23:54 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene <0.81 ug/L 05/22/23 23:54 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 05/22/23 23:54 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 05/22/23 23:54 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 05/22/23 23:54 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 05/22/23 23:54 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 05/22/23 23:54 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 05/22/23 23:54 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 05/22/23 23:54 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 05/22/23 23:54 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 05/22/23 23:54 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 05/22/23 23:54 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 05/22/23 23:54 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 05/22/23 23:54 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)124 %05/22/23 23:54 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %05/22/23 23:54 460-00-470-130 1
Toluene-d8 (S)103 %05/22/23 23:54 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
775917
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997007, 92667997008, 92667997009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026083
Associated Lab Samples:92667997007, 92667997008, 92667997009
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 05/21/23 13:550.31
1,1,1-Trichloroethane ug/L <0.33 0.50 05/21/23 13:550.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 05/21/23 13:550.22
1,1,2-Trichloroethane ug/L <0.32 0.50 05/21/23 13:550.32
1,1-Dichloroethane ug/L <0.37 0.50 05/21/23 13:550.37
1,1-Dichloroethene ug/L <0.35 0.50 05/21/23 13:550.35
1,1-Dichloropropene ug/L <0.43 0.50 05/21/23 13:550.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 05/21/23 13:550.81
1,2,3-Trichloropropane ug/L <0.26 0.50 05/21/23 13:550.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 05/21/23 13:550.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 05/21/23 13:550.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 05/21/23 13:550.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 05/21/23 13:550.27
1,2-Dichlorobenzene ug/L <0.34 0.50 05/21/23 13:550.34
1,2-Dichloroethane ug/L <0.32 0.50 05/21/23 13:550.32
1,2-Dichloropropane ug/L <0.36 0.50 05/21/23 13:550.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 05/21/23 13:550.33
1,3-Dichlorobenzene ug/L <0.34 0.50 05/21/23 13:550.34
1,3-Dichloropropane ug/L <0.28 0.50 05/21/23 13:550.28
1,4-Dichlorobenzene ug/L <0.33 0.50 05/21/23 13:550.33
2,2-Dichloropropane ug/L <0.39 0.50 05/21/23 13:550.39
2-Chlorotoluene ug/L <0.32 0.50 05/21/23 13:550.32
4-Chlorotoluene ug/L <0.32 0.50 05/21/23 13:550.32
Benzene ug/L <0.34 0.50 05/21/23 13:550.34
Bromobenzene ug/L <0.29 0.50 05/21/23 13:550.29
Bromochloromethane ug/L <0.47 0.50 05/21/23 13:550.47
Bromodichloromethane ug/L <0.31 0.50 05/21/23 13:550.31
Bromoform ug/L <0.34 0.50 05/21/23 13:550.34
Bromomethane ug/L <1.7 5.0 05/21/23 13:551.7
Carbon tetrachloride ug/L <0.33 0.50 05/21/23 13:550.33
Chlorobenzene ug/L <0.28 0.50 05/21/23 13:550.28
Chloroethane ug/L <0.65 1.0 05/21/23 13:550.65
Chloroform ug/L <0.43 0.50 05/21/23 13:550.43
Chloromethane ug/L <0.54 1.0 05/21/23 13:550.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 05/21/23 13:550.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 13:550.36
Dibromochloromethane ug/L <0.36 0.50 05/21/23 13:550.36
Dibromomethane ug/L <0.39 0.50 05/21/23 13:550.39
Dichlorodifluoromethane ug/L <0.35 0.50 IH05/21/23 13:550.35
Diisopropyl ether ug/L <0.31 0.50 05/21/23 13:550.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026083
Associated Lab Samples:92667997007, 92667997008, 92667997009
Matrix: Water
AnalyzedMDL
Ethanol ug/L <72.2 200 05/21/23 13:5572.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 05/21/23 13:553.2
Ethylbenzene ug/L <0.30 0.50 05/21/23 13:550.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 05/21/23 13:551.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 05/21/23 13:550.33
m&p-Xylene ug/L <0.71 1.0 05/21/23 13:550.71
Methyl-tert-butyl ether ug/L <0.42 0.50 05/21/23 13:550.42
Methylene Chloride ug/L <2.0 2.0 05/21/23 13:552.0
n-Butylbenzene ug/L <0.49 0.50 05/21/23 13:550.49
n-Propylbenzene ug/L <0.34 0.50 05/21/23 13:550.34
Naphthalene ug/L <0.64 2.0 05/21/23 13:550.64
o-Xylene ug/L <0.34 0.50 05/21/23 13:550.34
sec-Butylbenzene ug/L <0.40 0.50 05/21/23 13:550.40
Styrene ug/L <0.29 0.50 05/21/23 13:550.29
tert-Amyl Alcohol ug/L <36.4 100 05/21/23 13:5536.4
tert-Amylmethyl ether ug/L <9.2 10.0 05/21/23 13:559.2
tert-Butyl Alcohol ug/L <26.8 50.0 05/21/23 13:5526.8
tert-Butyl Formate ug/L <29.4 50.0 05/21/23 13:5529.4
tert-Butylbenzene ug/L <0.32 0.50 05/21/23 13:550.32
Tetrachloroethene ug/L <0.29 0.50 05/21/23 13:550.29
Toluene ug/L <0.24 0.50 05/21/23 13:550.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 05/21/23 13:550.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 13:550.36
Trichloroethene ug/L <0.38 0.50 05/21/23 13:550.38
Trichlorofluoromethane ug/L <0.30 1.0 05/21/23 13:550.30
Vinyl chloride ug/L <0.39 1.0 05/21/23 13:550.39
Xylene (Total)ug/L <0.34 1.0 05/21/23 13:550.34
1,2-Dichloroethane-d4 (S)%123 70-130 05/21/23 13:55
4-Bromofluorobenzene (S)%97 70-130 05/21/23 13:55
Toluene-d8 (S)%103 70-130 05/21/23 13:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026084LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.920 105 60-140
1,1,1-Trichloroethane ug/L 23.020 115 60-140
1,1,2,2-Tetrachloroethane ug/L 22.820 114 60-140
1,1,2-Trichloroethane ug/L 21.420 107 60-140
1,1-Dichloroethane ug/L 25.520 127 60-140
1,1-Dichloroethene ug/L 25.120 126 60-140
1,1-Dichloropropene ug/L 26.320 131 60-140
1,2,3-Trichlorobenzene ug/L 18.420 92 60-140
1,2,3-Trichloropropane ug/L 21.820 109 60-140
1,2,4-Trichlorobenzene ug/L 19.020 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026084LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 22.120 110 60-140
1,2-Dibromo-3-chloropropane ug/L 17.320 86 60-140
1,2-Dibromoethane (EDB)ug/L 21.720 109 60-140
1,2-Dichlorobenzene ug/L 21.120 106 60-140
1,2-Dichloroethane ug/L 23.720 119 60-140
1,2-Dichloropropane ug/L 23.820 119 60-140
1,3,5-Trimethylbenzene ug/L 22.820 114 60-140
1,3-Dichlorobenzene ug/L 21.620 108 60-140
1,3-Dichloropropane ug/L 22.320 112 60-140
1,4-Dichlorobenzene ug/L 20.920 105 60-140
2,2-Dichloropropane ug/L 24.520 122 60-140
2-Chlorotoluene ug/L 23.120 115 60-140
4-Chlorotoluene ug/L 23.020 115 60-140
Benzene ug/L 22.720 113 60-140
Bromobenzene ug/L 21.020 105 60-140
Bromochloromethane ug/L 22.520 112 60-140
Bromodichloromethane ug/L 20.420 102 60-140
Bromoform ug/L 16.220 81 60-140
Bromomethane ug/L 24.920 124 60-140
Carbon tetrachloride ug/L 19.820 99 60-140
Chlorobenzene ug/L 21.820 109 60-140
Chloroethane ug/L 35.6 L120178 60-140
Chloroform ug/L 24.820 124 60-140
Chloromethane ug/L 23.120 116 60-140
cis-1,2-Dichloroethene ug/L 24.420 122 60-140
cis-1,3-Dichloropropene ug/L 21.320 106 60-140
Dibromochloromethane ug/L 19.320 96 60-140
Dibromomethane ug/L 19.420 97 60-140
Dichlorodifluoromethane ug/L 26.2 IH20131 60-140
Diisopropyl ether ug/L 22.820 114 60-140
Ethanol ug/L 764800 96 60-140
Ethyl-tert-butyl ether ug/L 44.340 111 60-140
Ethylbenzene ug/L 21.820 109 60-140
Hexachloro-1,3-butadiene ug/L 19.820 99 60-140
Isopropylbenzene (Cumene)ug/L 21.420 107 60-140
m&p-Xylene ug/L 43.040 108 60-140
Methyl-tert-butyl ether ug/L 21.120 105 60-140
Methylene Chloride ug/L 22.820 114 60-140
n-Butylbenzene ug/L 24.120 121 60-140
n-Propylbenzene ug/L 23.220 116 60-140
Naphthalene ug/L 21.120 106 60-140
o-Xylene ug/L 21.020 105 60-140
sec-Butylbenzene ug/L 22.620 113 60-140
Styrene ug/L 21.620 108 60-140
tert-Amyl Alcohol ug/L 328400 82 60-140
tert-Amylmethyl ether ug/L 41.240 103 60-140
tert-Butyl Alcohol ug/L 176200 88 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026084LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 136160 85 60-140
tert-Butylbenzene ug/L 17.920 89 60-140
Tetrachloroethene ug/L 19.020 95 60-140
Toluene ug/L 20.820 104 60-140
trans-1,2-Dichloroethene ug/L 25.620 128 60-140
trans-1,3-Dichloropropene ug/L 20.220 101 60-140
Trichloroethene ug/L 21.420 107 60-140
Trichlorofluoromethane ug/L 23.420 117 60-140
Vinyl chloride ug/L 19.520 97 60-140
Xylene (Total)ug/L 64.060 107 60-140
1,2-Dichloroethane-d4 (S)%115 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026085MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667617004
4026086
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 140 60-140124 12 3020<0.31 28.0 24.9
1,1,1-Trichloroethane ug/L M12016360-140142 13 3020<0.33 32.6 28.5
1,1,2,2-Tetrachloroethane ug/L M12015060-140135 11 3020<0.22 30.1 27.0
1,1,2-Trichloroethane ug/L M12014460-140127 12 3020<0.32 28.8 25.4
1,1-Dichloroethane ug/L M12017960-140155 14 3020<0.37 35.8 31.0
1,1-Dichloroethene ug/L M12018160-140158 13 3020<0.35 36.1 31.6
1,1-Dichloropropene ug/L M12018860-140167 12 3020<0.43 37.6 33.4
1,2,3-Trichlorobenzene ug/L 20 114 60-140107 6 3020<0.81 22.8 21.5
1,2,3-Trichloropropane ug/L M12014360-140130 10 3020<0.26 28.6 25.9
1,2,4-Trichlorobenzene ug/L 20 119 60-140111 7 3020<0.64 23.9 22.2
1,2,4-Trimethylbenzene ug/L M12014560-140133 8 3020<0.50 28.9 26.7
1,2-Dibromo-3-
chloropropane ug/L 20 113 60-140106 7 3020<0.34 22.7 21.1
1,2-Dibromoethane (EDB) ug/L M12014560-140131 11 3020<0.27 29.0 26.1
1,2-Dichlorobenzene ug/L 20 137 60-140126 8 3020<0.34 27.3 25.2
1,2-Dichloroethane ug/L M12016560-140144 14 3020<0.32 33.0 28.7
1,2-Dichloropropane ug/L M12016360-140143 14 3020<0.36 32.7 28.5
1,3,5-Trimethylbenzene ug/L M12014860-140134 10 3020<0.33 29.6 26.8
1,3-Dichlorobenzene ug/L M12014160-140130 8 3020<0.34 28.2 25.9
1,3-Dichloropropane ug/L M12015060-140134 11 3020<0.28 30.1 26.9
1,4-Dichlorobenzene ug/L 20 135 60-140123 9 3020<0.33 26.9 24.5
2,2-Dichloropropane ug/L M12017560-140151 15 3020<0.39 35.1 30.3
2-Chlorotoluene ug/L M12015260-140141 7 3020<0.32 30.4 28.3
4-Chlorotoluene ug/L M12015360-140140 9 3020<0.32 30.6 28.0
Benzene ug/L M12015660-140137 13 3020<0.34 31.2 27.4
Bromobenzene ug/L 20 137 60-140126 8 3020<0.29 27.4 25.2
Bromochloromethane ug/L M12015460-140132 15 3020<0.47 30.8 26.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026085MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667617004
4026086
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 139 60-140120 15 3020<0.31 27.8 24.0
Bromoform ug/L 20 107 60-14096 11 3020<0.34 21.5 19.3
Bromomethane ug/L M12016460-140145 13 3020<1.7 32.9 29.0
Carbon tetrachloride ug/L 20 138 60-140121 13 3020<0.33 27.6 24.2
Chlorobenzene ug/L M12014460-140132 9 3020<0.28 28.9 26.4
Chloroethane ug/L M02026160-140231 12 3020<0.65 52.1 46.3
Chloroform ug/L M12016460-140143 14 3020<0.43 32.9 28.5
Chloromethane ug/L M12019560-140177 10 3020<0.54 39.0 35.4
cis-1,2-Dichloroethene ug/L M12017160-140150 13 3020<0.38 34.1 30.0
cis-1,3-Dichloropropene ug/L 20 139 60-140123 13 3020<0.36 27.9 24.5
Dibromochloromethane ug/L 20 131 60-140115 13 3020<0.36 26.3 23.0
Dibromomethane ug/L 20 132 60-140114 15 3020<0.39 26.4 22.7
Dichlorodifluoromethane ug/L IH,M12026660-140238 11 3020<0.35 53.2 47.7
Diisopropyl ether ug/L M12015860-140138 13 3020<0.31 31.6 27.7
Ethanol ug/L 800 137 60-140126 8 30800<72.2 1100 1010
Ethyl-tert-butyl ether ug/L M14015660-140137 13 3040<3.2 62.3 54.8
Ethylbenzene ug/L M12014860-140134 10 3020<0.30 29.5 26.8
Hexachloro-1,3-butadiene ug/L 20 126 60-140116 9 3020<1.5 25.3 23.2
Isopropylbenzene
(Cumene)ug/L M12014460-140129 11 3020<0.33 28.8 25.8
m&p-Xylene ug/L M14014660-140130 11 3040<0.71 58.4 52.0
Methyl-tert-butyl ether ug/L M12014360-140128 11 3020<0.42 29.1 26.0
Methylene Chloride ug/L M12015160-140135 12 3020<2.0 30.3 27.0
n-Butylbenzene ug/L M12015760-140142 10 3020<0.49 31.5 28.5
n-Propylbenzene ug/L M12015660-140142 10 3020<0.34 31.2 28.3
Naphthalene ug/L 20 134 60-140126 6 3020<0.64 26.9 25.3
o-Xylene ug/L 20 140 60-140127 9 3020<0.34 28.0 25.5
sec-Butylbenzene ug/L M12014960-140135 10 3020<0.40 29.9 27.1
Styrene ug/L M12014460-140130 11 3020<0.29 28.9 25.9
tert-Amyl Alcohol ug/L 400 111 60-140101 9 30400<36.4 442 406
tert-Amylmethyl ether ug/L M14014160-140124 13 3040<9.2 56.5 49.7
tert-Butyl Alcohol ug/L M120016260-140156 3 30200<26.8 323 313
tert-Butyl Formate ug/L M11604160-14021 30160<29.4 65.1 33.6J
tert-Butylbenzene ug/L 20 122 60-140111 9 3020<0.32 24.4 22.3
Tetrachloroethene ug/L 20 131 60-140118 10 3020<0.29 26.2 23.7
Toluene ug/L M12014160-140125 12 3020<0.24 28.2 25.0
trans-1,2-Dichloroethene ug/L M12018160-140160 13 3020<0.40 36.3 32.0
trans-1,3-Dichloropropene ug/L 20 138 60-140119 15 3020<0.36 27.6 23.9
Trichloroethene ug/L M12014860-140132 12 3020<0.38 29.6 26.3
Trichlorofluoromethane ug/L M12017960-140155 14 3020<0.30 35.8 31.0
Vinyl chloride ug/L M12016460-140143 13 3020<0.39 32.8 28.7
Xylene (Total)ug/L MS6014460-140129 11 3060<0.34 86.4 77.5
1,2-Dichloroethane-d4 (S) %120 70-130118
4-Bromofluorobenzene (S) %100 70-130100
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
775942
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026146
Associated Lab Samples:92667997011
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 05/21/23 22:210.31
1,1,1-Trichloroethane ug/L <0.33 0.50 05/21/23 22:210.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 05/21/23 22:210.22
1,1,2-Trichloroethane ug/L <0.32 0.50 05/21/23 22:210.32
1,1-Dichloroethane ug/L <0.37 0.50 05/21/23 22:210.37
1,1-Dichloroethene ug/L <0.35 0.50 05/21/23 22:210.35
1,1-Dichloropropene ug/L <0.43 0.50 05/21/23 22:210.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 05/21/23 22:210.81
1,2,3-Trichloropropane ug/L <0.26 0.50 05/21/23 22:210.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 05/21/23 22:210.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 05/21/23 22:210.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 05/21/23 22:210.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 05/21/23 22:210.27
1,2-Dichlorobenzene ug/L <0.34 0.50 05/21/23 22:210.34
1,2-Dichloroethane ug/L <0.32 0.50 05/21/23 22:210.32
1,2-Dichloropropane ug/L <0.36 0.50 05/21/23 22:210.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 05/21/23 22:210.33
1,3-Dichlorobenzene ug/L <0.34 0.50 05/21/23 22:210.34
1,3-Dichloropropane ug/L <0.28 0.50 05/21/23 22:210.28
1,4-Dichlorobenzene ug/L <0.33 0.50 05/21/23 22:210.33
2,2-Dichloropropane ug/L <0.39 0.50 05/21/23 22:210.39
2-Chlorotoluene ug/L <0.32 0.50 05/21/23 22:210.32
4-Chlorotoluene ug/L <0.32 0.50 05/21/23 22:210.32
Benzene ug/L <0.34 0.50 05/21/23 22:210.34
Bromobenzene ug/L <0.29 0.50 05/21/23 22:210.29
Bromochloromethane ug/L <0.47 0.50 05/21/23 22:210.47
Bromodichloromethane ug/L <0.31 0.50 05/21/23 22:210.31
Bromoform ug/L <0.34 0.50 05/21/23 22:210.34
Bromomethane ug/L <1.7 5.0 05/21/23 22:211.7
Carbon tetrachloride ug/L <0.33 0.50 05/21/23 22:210.33
Chlorobenzene ug/L <0.28 0.50 05/21/23 22:210.28
Chloroethane ug/L <0.65 1.0 05/21/23 22:210.65
Chloroform ug/L <0.43 0.50 05/21/23 22:210.43
Chloromethane ug/L <0.54 1.0 05/21/23 22:210.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 05/21/23 22:210.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 22:210.36
Dibromochloromethane ug/L <0.36 0.50 05/21/23 22:210.36
Dibromomethane ug/L <0.39 0.50 05/21/23 22:210.39
Dichlorodifluoromethane ug/L <0.35 0.50 05/21/23 22:210.35
Diisopropyl ether ug/L <0.31 0.50 05/21/23 22:210.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026146
Associated Lab Samples:92667997011
Matrix: Water
AnalyzedMDL
Ethanol ug/L <72.2 200 05/21/23 22:2172.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 05/21/23 22:213.2
Ethylbenzene ug/L <0.30 0.50 05/21/23 22:210.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 05/21/23 22:211.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 05/21/23 22:210.33
m&p-Xylene ug/L <0.71 1.0 05/21/23 22:210.71
Methyl-tert-butyl ether ug/L <0.42 0.50 05/21/23 22:210.42
Methylene Chloride ug/L <2.0 2.0 05/21/23 22:212.0
n-Butylbenzene ug/L <0.49 0.50 05/21/23 22:210.49
n-Propylbenzene ug/L <0.34 0.50 05/21/23 22:210.34
Naphthalene ug/L <0.64 2.0 05/21/23 22:210.64
o-Xylene ug/L <0.34 0.50 05/21/23 22:210.34
sec-Butylbenzene ug/L <0.40 0.50 05/21/23 22:210.40
Styrene ug/L <0.29 0.50 05/21/23 22:210.29
tert-Amyl Alcohol ug/L <36.4 100 05/21/23 22:2136.4
tert-Amylmethyl ether ug/L <9.2 10.0 05/21/23 22:219.2
tert-Butyl Alcohol ug/L <26.8 50.0 05/21/23 22:2126.8
tert-Butyl Formate ug/L <29.4 50.0 05/21/23 22:2129.4
tert-Butylbenzene ug/L <0.32 0.50 05/21/23 22:210.32
Tetrachloroethene ug/L <0.29 0.50 05/21/23 22:210.29
Toluene ug/L <0.24 0.50 05/21/23 22:210.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 05/21/23 22:210.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 22:210.36
Trichloroethene ug/L <0.38 0.50 05/21/23 22:210.38
Trichlorofluoromethane ug/L <0.30 1.0 05/21/23 22:210.30
Vinyl chloride ug/L <0.39 1.0 05/21/23 22:210.39
Xylene (Total)ug/L <0.34 1.0 05/21/23 22:210.34
1,2-Dichloroethane-d4 (S)%96 70-130 05/21/23 22:21
4-Bromofluorobenzene (S)%99 70-130 05/21/23 22:21
Toluene-d8 (S)%106 70-130 05/21/23 22:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026147LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.020 105 60-140
1,1,1-Trichloroethane ug/L 22.520 112 60-140
1,1,2,2-Tetrachloroethane ug/L 21.220 106 60-140
1,1,2-Trichloroethane ug/L 22.320 111 60-140
1,1-Dichloroethane ug/L 21.120 106 60-140
1,1-Dichloroethene ug/L 22.620 113 60-140
1,1-Dichloropropene ug/L 20.920 105 60-140
1,2,3-Trichlorobenzene ug/L 23.020 115 60-140
1,2,3-Trichloropropane ug/L 20.620 103 60-140
1,2,4-Trichlorobenzene ug/L 22.420 112 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026147LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 21.920 109 60-140
1,2-Dibromo-3-chloropropane ug/L 23.320 116 60-140
1,2-Dibromoethane (EDB)ug/L 21.820 109 60-140
1,2-Dichlorobenzene ug/L 21.120 106 60-140
1,2-Dichloroethane ug/L 21.320 106 60-140
1,2-Dichloropropane ug/L 21.720 108 60-140
1,3,5-Trimethylbenzene ug/L 21.420 107 60-140
1,3-Dichlorobenzene ug/L 21.720 108 60-140
1,3-Dichloropropane ug/L 20.720 104 60-140
1,4-Dichlorobenzene ug/L 20.720 103 60-140
2,2-Dichloropropane ug/L 22.320 112 60-140
2-Chlorotoluene ug/L 21.420 107 60-140
4-Chlorotoluene ug/L 21.520 108 60-140
Benzene ug/L 21.220 106 60-140
Bromobenzene ug/L 21.220 106 60-140
Bromochloromethane ug/L 23.320 116 60-140
Bromodichloromethane ug/L 21.420 107 60-140
Bromoform ug/L 20.820 104 60-140
Bromomethane ug/L 18.220 91 60-140
Carbon tetrachloride ug/L 22.720 114 60-140
Chlorobenzene ug/L 21.720 108 60-140
Chloroethane ug/L 18.820 94 60-140
Chloroform ug/L 21.120 106 60-140
Chloromethane ug/L 18.220 91 60-140
cis-1,2-Dichloroethene ug/L 21.820 109 60-140
cis-1,3-Dichloropropene ug/L 21.620 108 60-140
Dibromochloromethane ug/L 21.320 106 60-140
Dibromomethane ug/L 22.120 110 60-140
Dichlorodifluoromethane ug/L 17.820 89 60-140
Diisopropyl ether ug/L 20.320 102 60-140
Ethanol ug/L 793800 99 60-140
Ethyl-tert-butyl ether ug/L 40.040 100 60-140
Ethylbenzene ug/L 21.520 107 60-140
Hexachloro-1,3-butadiene ug/L 22.220 111 60-140
Isopropylbenzene (Cumene)ug/L 21.920 110 60-140
m&p-Xylene ug/L 42.640 106 60-140
Methyl-tert-butyl ether ug/L 20.220 101 60-140
Methylene Chloride ug/L 22.220 111 60-140
n-Butylbenzene ug/L 22.220 111 60-140
n-Propylbenzene ug/L 21.120 106 60-140
Naphthalene ug/L 24.120 121 60-140
o-Xylene ug/L 21.420 107 60-140
sec-Butylbenzene ug/L 21.220 106 60-140
Styrene ug/L 21.320 107 60-140
tert-Amyl Alcohol ug/L 428400 107 60-140
tert-Amylmethyl ether ug/L 41.440 103 60-140
tert-Butyl Alcohol ug/L 211200 106 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026147LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 164160 102 60-140
tert-Butylbenzene ug/L 17.720 89 60-140
Tetrachloroethene ug/L 22.220 111 60-140
Toluene ug/L 21.820 109 60-140
trans-1,2-Dichloroethene ug/L 22.320 112 60-140
trans-1,3-Dichloropropene ug/L 20.920 104 60-140
Trichloroethene ug/L 22.220 111 60-140
Trichlorofluoromethane ug/L 18.820 94 60-140
Vinyl chloride ug/L 15.820 79 60-140
Xylene (Total)ug/L 64.060 107 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026148MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667709001
4026149
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L R1209160-14061 40 3020ND18.3 12.2
1,1,1-Trichloroethane ug/L R12010160-14073 32 3020ND20.2 14.7
1,1,2,2-Tetrachloroethane ug/L R1209660-14067 35 3020ND19.2 13.4
1,1,2-Trichloroethane ug/L 20 89 60-14066 30 3020ND17.9 13.2
1,1-Dichloroethane ug/L 20 97 60-14072 29 3020ND19.4 14.5
1,1-Dichloroethene ug/L R12011360-14079 36 3020ND22.7 15.7
1,1-Dichloropropene ug/L 20 93 60-14070 28 3020ND18.6 14.0
1,2,3-Trichlorobenzene ug/L 20 94 60-14070 29 3020ND18.8 14.0
1,2,3-Trichloropropane ug/L R1209060-14063 34 3020ND18.0 12.7
1,2,4-Trichlorobenzene ug/L 20 94 60-14070 29 3020ND18.8 14.1
1,2,4-Trimethylbenzene ug/L R1209360-14068 31 3020ND18.6 13.5
1,2-Dibromo-3-
chloropropane ug/L 20 91 60-14067 30 3020ND18.2 13.4
1,2-Dibromoethane (EDB) ug/L 20 88 60-14065 30 3020ND17.5 12.9
1,2-Dichlorobenzene ug/L R1209060-14066 31 3020ND18.0 13.1
1,2-Dichloroethane ug/L R1209760-14070 31 3020ND19.3 14.1
1,2-Dichloropropane ug/L 20 96 60-14071 30 3020ND19.2 14.2
1,3,5-Trimethylbenzene ug/L R1209460-14067 34 3020ND18.8 13.3
1,3-Dichlorobenzene ug/L R1209460-14068 33 3020ND18.9 13.5
1,3-Dichloropropane ug/L R1209360-14064 37 3020ND18.6 12.8
1,4-Dichlorobenzene ug/L R1208860-14063 32 3020ND17.6 12.7
2,2-Dichloropropane ug/L R1209960-14072 31 3020ND19.8 14.5
2-Chlorotoluene ug/L 20 90 60-14068 28 3020ND18.1 13.7
4-Chlorotoluene ug/L R1209460-14069 31 3020ND18.7 13.8
Benzene ug/L 20 90 60-14068 28 3020ND18.0 13.5
Bromobenzene ug/L 20 89 60-14067 28 3020ND17.8 13.5
Bromochloromethane ug/L 20 90 60-14069 27 3020ND18.1 13.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026148MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667709001
4026149
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 91 60-14068 29 3020ND18.3 13.7
Bromoform ug/L R1208260-14060 31 3020ND16.4 12.1
Bromomethane ug/L M1,R1206760-14048 34 3020ND13.4 9.5
Carbon tetrachloride ug/L 20 103 60-14079 27 3020ND20.6 15.8
Chlorobenzene ug/L R1209360-14067 33 3020ND18.7 13.4
Chloroethane ug/L 20 102 60-14075 30 3020ND20.5 15.1
Chloroform ug/L 20 93 60-14070 27 30200.52 19.1 14.6
Chloromethane ug/L 20 101 60-14076 28 3020ND20.2 15.3
cis-1,2-Dichloroethene ug/L R1209760-14071 31 3020ND19.4 14.2
cis-1,3-Dichloropropene ug/L R1209460-14065 37 3020ND18.8 12.9
Dibromochloromethane ug/L R1209160-14065 34 3020ND18.2 13.0
Dibromomethane ug/L R1209160-14066 32 3020ND18.2 13.1
Dichlorodifluoromethane ug/L 20 130 60-14096 30 3020ND26.0 19.3
Diisopropyl ether ug/L R1208760-14061 35 3020ND17.4 12.2
Ethanol ug/L 800 90 60-14068 28 30800ND716 543
Ethyl-tert-butyl ether ug/L M1408160-14059 30 3040ND32.2 23.7
Ethylbenzene ug/L R1209760-14069 33 3020ND19.4 13.9
Hexachloro-1,3-butadiene ug/L 20 97 60-14075 26 3020ND19.4 15.0
Isopropylbenzene
(Cumene)ug/L R1209960-14070 35 3020ND19.8 13.9
m&p-Xylene ug/L R1409660-14067 35 3040ND38.3 26.9
Methyl-tert-butyl ether ug/L R1208460-14061 31 3020ND16.9 12.3
Methylene Chloride ug/L R1209660-14068 33 3020ND19.1 13.7
n-Butylbenzene ug/L 20 99 60-14074 29 3020ND19.8 14.7
n-Propylbenzene ug/L R1209460-14067 33 3020ND18.8 13.5
Naphthalene ug/L 20 96 60-14072 28 3020ND19.2 14.4
o-Xylene ug/L R1209260-14064 35 3020ND18.4 12.9
sec-Butylbenzene ug/L 20 96 60-14072 28 3020ND19.1 14.4
Styrene ug/L R1209360-14064 37 3020ND18.6 12.9
tert-Amyl Alcohol ug/L 400 92 60-14069 28 30400ND367 277
tert-Amylmethyl ether ug/L 40 86 60-14064 29 3040ND34.3 25.7
tert-Butyl Alcohol ug/L 200 101 60-14080 24 30200ND203 160
tert-Butyl Formate ug/L P51604560-14028 30160ND72.0 45.4J
tert-Butylbenzene ug/L M1,R1207860-14057 32 3020ND15.6 11.3
Tetrachloroethene ug/L R12010060-14069 37 3020ND19.9 13.7
Toluene ug/L 20 87 60-14067 26 30200.38J 17.8 13.7
trans-1,2-Dichloroethene ug/L 20 100 60-14076 28 3020ND20.0 15.1
trans-1,3-Dichloropropene ug/L R1209060-14066 31 3020ND17.9 13.1
Trichloroethene ug/L 20 93 60-14070 28 3020ND18.6 14.1
Trichlorofluoromethane ug/L 20 95 60-14074 26 3020ND19.0 14.7
Vinyl chloride ug/L 20 86 60-14064 30 3020ND17.3 12.8
Xylene (Total)ug/L RS609460-14066 35 3060ND56.7 39.8
1,2-Dichloroethane-d4 (S) %105 70-130108
4-Bromofluorobenzene (S) %102 70-130101
Toluene-d8 (S)%100 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
775965
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026157
Associated Lab Samples:92667997003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 05/21/23 21:350.31
1,1,1-Trichloroethane ug/L <0.33 0.50 05/21/23 21:350.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 05/21/23 21:350.22
1,1,2-Trichloroethane ug/L <0.32 0.50 05/21/23 21:350.32
1,1-Dichloroethane ug/L <0.37 0.50 05/21/23 21:350.37
1,1-Dichloroethene ug/L <0.35 0.50 05/21/23 21:350.35
1,1-Dichloropropene ug/L <0.43 0.50 05/21/23 21:350.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 05/21/23 21:350.81
1,2,3-Trichloropropane ug/L <0.26 0.50 05/21/23 21:350.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 05/21/23 21:350.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 05/21/23 21:350.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 05/21/23 21:350.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 05/21/23 21:350.27
1,2-Dichlorobenzene ug/L <0.34 0.50 05/21/23 21:350.34
1,2-Dichloroethane ug/L <0.32 0.50 05/21/23 21:350.32
1,2-Dichloropropane ug/L <0.36 0.50 05/21/23 21:350.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 05/21/23 21:350.33
1,3-Dichlorobenzene ug/L <0.34 0.50 05/21/23 21:350.34
1,3-Dichloropropane ug/L <0.28 0.50 05/21/23 21:350.28
1,4-Dichlorobenzene ug/L <0.33 0.50 05/21/23 21:350.33
2,2-Dichloropropane ug/L <0.39 0.50 05/21/23 21:350.39
2-Chlorotoluene ug/L <0.32 0.50 05/21/23 21:350.32
4-Chlorotoluene ug/L <0.32 0.50 05/21/23 21:350.32
Benzene ug/L <0.34 0.50 05/21/23 21:350.34
Bromobenzene ug/L <0.29 0.50 05/21/23 21:350.29
Bromochloromethane ug/L <0.47 0.50 05/21/23 21:350.47
Bromodichloromethane ug/L <0.31 0.50 05/21/23 21:350.31
Bromoform ug/L <0.34 0.50 05/21/23 21:350.34
Bromomethane ug/L <1.7 5.0 05/21/23 21:351.7
Carbon tetrachloride ug/L <0.33 0.50 05/21/23 21:350.33
Chlorobenzene ug/L <0.28 0.50 05/21/23 21:350.28
Chloroethane ug/L <0.65 1.0 05/21/23 21:350.65
Chloroform ug/L <0.43 0.50 05/21/23 21:350.43
Chloromethane ug/L <0.54 1.0 05/21/23 21:350.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 05/21/23 21:350.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 21:350.36
Dibromochloromethane ug/L <0.36 0.50 05/21/23 21:350.36
Dibromomethane ug/L <0.39 0.50 05/21/23 21:350.39
Dichlorodifluoromethane ug/L <0.35 0.50 IH05/21/23 21:350.35
Diisopropyl ether ug/L <0.31 0.50 05/21/23 21:350.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026157
Associated Lab Samples:92667997003
Matrix: Water
AnalyzedMDL
Ethanol ug/L <72.2 200 05/21/23 21:3572.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 05/21/23 21:353.2
Ethylbenzene ug/L <0.30 0.50 05/21/23 21:350.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 05/21/23 21:351.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 05/21/23 21:350.33
m&p-Xylene ug/L <0.71 1.0 05/21/23 21:350.71
Methyl-tert-butyl ether ug/L <0.42 0.50 05/21/23 21:350.42
Methylene Chloride ug/L <2.0 2.0 05/21/23 21:352.0
n-Butylbenzene ug/L <0.49 0.50 05/21/23 21:350.49
n-Propylbenzene ug/L <0.34 0.50 05/21/23 21:350.34
Naphthalene ug/L <0.64 2.0 05/21/23 21:350.64
o-Xylene ug/L <0.34 0.50 05/21/23 21:350.34
sec-Butylbenzene ug/L <0.40 0.50 05/21/23 21:350.40
Styrene ug/L <0.29 0.50 05/21/23 21:350.29
tert-Amyl Alcohol ug/L <36.4 100 05/21/23 21:3536.4
tert-Amylmethyl ether ug/L <9.2 10.0 05/21/23 21:359.2
tert-Butyl Alcohol ug/L <26.8 50.0 05/21/23 21:3526.8
tert-Butyl Formate ug/L <29.4 50.0 05/21/23 21:3529.4
tert-Butylbenzene ug/L <0.32 0.50 05/21/23 21:350.32
Tetrachloroethene ug/L <0.29 0.50 05/21/23 21:350.29
Toluene ug/L <0.24 0.50 05/21/23 21:350.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 05/21/23 21:350.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 05/21/23 21:350.36
Trichloroethene ug/L <0.38 0.50 05/21/23 21:350.38
Trichlorofluoromethane ug/L <0.30 1.0 05/21/23 21:350.30
Vinyl chloride ug/L <0.39 1.0 05/21/23 21:350.39
Xylene (Total)ug/L <0.34 1.0 05/21/23 21:350.34
1,2-Dichloroethane-d4 (S)%121 70-130 05/21/23 21:35
4-Bromofluorobenzene (S)%96 70-130 05/21/23 21:35
Toluene-d8 (S)%103 70-130 05/21/23 21:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026158LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.020 100 60-140
1,1,1-Trichloroethane ug/L 23.020 115 60-140
1,1,2,2-Tetrachloroethane ug/L 22.020 110 60-140
1,1,2-Trichloroethane ug/L 20.920 105 60-140
1,1-Dichloroethane ug/L 25.520 127 60-140
1,1-Dichloroethene ug/L 25.120 125 60-140
1,1-Dichloropropene ug/L 26.820 134 60-140
1,2,3-Trichlorobenzene ug/L 17.620 88 60-140
1,2,3-Trichloropropane ug/L 21.420 107 60-140
1,2,4-Trichlorobenzene ug/L 18.520 92 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026158LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 21.820 109 60-140
1,2-Dibromo-3-chloropropane ug/L 16.820 84 60-140
1,2-Dibromoethane (EDB)ug/L 21.020 105 60-140
1,2-Dichlorobenzene ug/L 20.520 102 60-140
1,2-Dichloroethane ug/L 24.220 121 60-140
1,2-Dichloropropane ug/L 23.620 118 60-140
1,3,5-Trimethylbenzene ug/L 22.320 112 60-140
1,3-Dichlorobenzene ug/L 21.420 107 60-140
1,3-Dichloropropane ug/L 21.920 109 60-140
1,4-Dichlorobenzene ug/L 20.520 102 60-140
2,2-Dichloropropane ug/L 24.920 124 60-140
2-Chlorotoluene ug/L 22.620 113 60-140
4-Chlorotoluene ug/L 22.920 114 60-140
Benzene ug/L 22.820 114 60-140
Bromobenzene ug/L 20.720 103 60-140
Bromochloromethane ug/L 22.620 113 60-140
Bromodichloromethane ug/L 20.220 101 60-140
Bromoform ug/L 15.020 75 60-140
Bromomethane ug/L 22.920 115 60-140
Carbon tetrachloride ug/L 19.020 95 60-140
Chlorobenzene ug/L 21.720 109 60-140
Chloroethane ug/L 37.2 L120186 60-140
Chloroform ug/L 25.020 125 60-140
Chloromethane ug/L 23.420 117 60-140
cis-1,2-Dichloroethene ug/L 24.720 124 60-140
cis-1,3-Dichloropropene ug/L 20.920 105 60-140
Dibromochloromethane ug/L 18.620 93 60-140
Dibromomethane ug/L 19.020 95 60-140
Dichlorodifluoromethane ug/L 25.8 IH20129 60-140
Diisopropyl ether ug/L 23.120 116 60-140
Ethanol ug/L 888800 111 60-140
Ethyl-tert-butyl ether ug/L 45.040 112 60-140
Ethylbenzene ug/L 21.820 109 60-140
Hexachloro-1,3-butadiene ug/L 18.920 94 60-140
Isopropylbenzene (Cumene)ug/L 21.420 107 60-140
m&p-Xylene ug/L 43.140 108 60-140
Methyl-tert-butyl ether ug/L 21.220 106 60-140
Methylene Chloride ug/L 23.520 118 60-140
n-Butylbenzene ug/L 23.120 115 60-140
n-Propylbenzene ug/L 23.020 115 60-140
Naphthalene ug/L 20.320 101 60-140
o-Xylene ug/L 21.320 106 60-140
sec-Butylbenzene ug/L 22.120 111 60-140
Styrene ug/L 21.520 107 60-140
tert-Amyl Alcohol ug/L 321400 80 60-140
tert-Amylmethyl ether ug/L 41.540 104 60-140
tert-Butyl Alcohol ug/L 175200 88 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026158LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 134160 84 60-140
tert-Butylbenzene ug/L 17.720 89 60-140
Tetrachloroethene ug/L 19.020 95 60-140
Toluene ug/L 20.820 104 60-140
trans-1,2-Dichloroethene ug/L 26.020 130 60-140
trans-1,3-Dichloropropene ug/L 19.520 97 60-140
Trichloroethene ug/L 21.420 107 60-140
Trichlorofluoromethane ug/L 23.820 119 60-140
Vinyl chloride ug/L 20.120 101 60-140
Xylene (Total)ug/L 64.460 107 60-140
1,2-Dichloroethane-d4 (S)%118 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026159MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667734002
4026160
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M12014460-140136 6 3020ND28.8 27.2
1,1,1-Trichloroethane ug/L M12016460-140156 5 3020ND32.8 31.1
1,1,2,2-Tetrachloroethane ug/L M12015560-140145 7 3020ND31.0 29.0
1,1,2-Trichloroethane ug/L M12014660-140138 5 3020ND29.2 27.6
1,1-Dichloroethane ug/L M12018360-140168 8 3020ND36.5 33.7
1,1-Dichloroethene ug/L M12018460-140171 7 3020ND36.9 34.2
1,1-Dichloropropene ug/L M12019060-140178 6 3020ND38.0 35.7
1,2,3-Trichlorobenzene ug/L 20 122 60-140113 8 3020ND24.5 22.7
1,2,3-Trichloropropane ug/L M12014960-140138 8 3020ND29.9 27.5
1,2,4-Trichlorobenzene ug/L 20 129 60-140119 8 3020ND25.8 23.7
1,2,4-Trimethylbenzene ug/L M12015560-140141 9 3020ND30.9 28.2
1,2-Dibromo-3-
chloropropane ug/L 20 123 60-140110 11 3020ND24.6 22.0
1,2-Dibromoethane (EDB) ug/L M12014760-140139 6 3020ND29.5 27.8
1,2-Dichlorobenzene ug/L M12014460-140131 9 3020ND28.9 26.3
1,2-Dichloroethane ug/L M12016760-140159 5 3020ND33.3 31.8
1,2-Dichloropropane ug/L M12016560-140155 6 3020ND33.0 31.0
1,3,5-Trimethylbenzene ug/L M12015960-140143 11 3020ND31.8 28.6
1,3-Dichlorobenzene ug/L M12015060-140134 11 3020ND30.0 26.9
1,3-Dichloropropane ug/L M12015460-140145 6 3020ND30.7 29.0
1,4-Dichlorobenzene ug/L M12014260-140130 9 3020ND28.5 25.9
2,2-Dichloropropane ug/L M12017860-140166 6 3020ND35.5 33.3
2-Chlorotoluene ug/L M12016460-140147 11 3020ND32.7 29.4
4-Chlorotoluene ug/L M12016160-140148 9 3020ND32.3 29.6
Benzene ug/L M12015860-140149 6 3020ND31.6 29.8
Bromobenzene ug/L M12014660-140133 9 3020ND29.2 26.7
Bromochloromethane ug/L M12015360-140147 3 3020ND30.5 29.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026159MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667734002
4026160
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 140 60-140132 5 3020ND27.9 26.5
Bromoform ug/L 20 110 60-140103 6 3020ND22.0 20.7
Bromomethane ug/L M12016460-140157 4 3020ND32.7 31.4
Carbon tetrachloride ug/L M12014160-140132 6 3020ND28.2 26.5
Chlorobenzene ug/L M12015060-140141 6 3020ND30.0 28.2
Chloroethane ug/L M02026560-140249 6 3020ND52.9 49.8
Chloroform ug/L M12016660-140163 1 3020ND33.1 32.7
Chloromethane ug/L M12020360-140197 3 3020ND40.5 39.5
cis-1,2-Dichloroethene ug/L M12017260-140163 6 3020ND34.5 32.5
cis-1,3-Dichloropropene ug/L M12014260-140134 6 3020ND28.4 26.8
Dibromochloromethane ug/L 20 135 60-140125 8 3020ND27.1 25.0
Dibromomethane ug/L 20 130 60-140123 6 3020ND26.1 24.5
Dichlorodifluoromethane ug/L IH,M12027360-140254 7 3020ND54.5 50.8
Diisopropyl ether ug/L M12016160-140151 6 3020ND32.2 30.2
Ethanol ug/L M180014560-140139 4 30800ND1160 1110
Ethyl-tert-butyl ether ug/L M14015860-140149 6 3040ND63.3 59.8
Ethylbenzene ug/L M12015360-140143 7 3020ND30.6 28.6
Hexachloro-1,3-butadiene ug/L 20 136 60-140120 12 3020ND27.2 24.0
Isopropylbenzene
(Cumene)ug/L M12015060-140140 7 3020ND29.9 28.0
m&p-Xylene ug/L M14015060-140141 6 3040ND59.9 56.5
Methyl-tert-butyl ether ug/L M12014760-140139 6 3020ND29.5 27.7
Methylene Chloride ug/L M12015460-140148 4 3020ND30.8 29.5
n-Butylbenzene ug/L M12016760-140151 10 3020ND33.4 30.1
n-Propylbenzene ug/L M12016460-140147 11 3020ND32.8 29.5
Naphthalene ug/L M12014360-140133 8 3020ND28.7 26.6
o-Xylene ug/L M12014460-140136 6 3020ND28.9 27.2
sec-Butylbenzene ug/L M12016160-140144 11 3020ND32.1 28.9
Styrene ug/L M12015060-140139 7 3020ND29.9 27.9
tert-Amyl Alcohol ug/L 400 116 60-140111 5 30400ND465 444
tert-Amylmethyl ether ug/L M14014360-140135 6 3040ND57.3 53.9
tert-Butyl Alcohol ug/L M120017660-140172 3 30200ND352 343
tert-Butyl Formate ug/L M11603160-14024 30160ND49.5J 38.8J
tert-Butylbenzene ug/L 20 126 60-140116 9 3020ND25.3 23.2
Tetrachloroethene ug/L 20 133 60-140123 8 3020ND26.7 24.6
Toluene ug/L M12014460-140137 5 3020ND28.8 27.5
trans-1,2-Dichloroethene ug/L M12018560-140173 7 3020ND37.0 34.5
trans-1,3-Dichloropropene ug/L 20 138 60-140131 5 3020ND27.5 26.2
Trichloroethene ug/L M12015060-140141 6 3020ND29.9 28.2
Trichlorofluoromethane ug/L M12017960-140166 7 3020ND35.7 33.2
Vinyl chloride ug/L M12016660-140157 5 3020ND33.1 31.4
Xylene (Total)ug/L MS6014860-140139 6 3060ND88.7 83.7
1,2-Dichloroethane-d4 (S) %117 70-130117
4-Bromofluorobenzene (S) %99 70-130102
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
776133
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026974
Associated Lab Samples:92667997001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 05/22/23 15:190.31
1,1,1-Trichloroethane ug/L <0.33 0.50 05/22/23 15:190.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 05/22/23 15:190.22
1,1,2-Trichloroethane ug/L <0.32 0.50 05/22/23 15:190.32
1,1-Dichloroethane ug/L <0.37 0.50 05/22/23 15:190.37
1,1-Dichloroethene ug/L <0.35 0.50 05/22/23 15:190.35
1,1-Dichloropropene ug/L <0.43 0.50 05/22/23 15:190.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 05/22/23 15:190.81
1,2,3-Trichloropropane ug/L <0.26 0.50 05/22/23 15:190.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 05/22/23 15:190.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 05/22/23 15:190.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 05/22/23 15:190.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 05/22/23 15:190.27
1,2-Dichlorobenzene ug/L <0.34 0.50 05/22/23 15:190.34
1,2-Dichloroethane ug/L <0.32 0.50 05/22/23 15:190.32
1,2-Dichloropropane ug/L <0.36 0.50 05/22/23 15:190.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 05/22/23 15:190.33
1,3-Dichlorobenzene ug/L <0.34 0.50 05/22/23 15:190.34
1,3-Dichloropropane ug/L <0.28 0.50 05/22/23 15:190.28
1,4-Dichlorobenzene ug/L <0.33 0.50 05/22/23 15:190.33
2,2-Dichloropropane ug/L <0.39 0.50 05/22/23 15:190.39
2-Chlorotoluene ug/L <0.32 0.50 05/22/23 15:190.32
4-Chlorotoluene ug/L <0.32 0.50 05/22/23 15:190.32
Benzene ug/L <0.34 0.50 05/22/23 15:190.34
Bromobenzene ug/L <0.29 0.50 05/22/23 15:190.29
Bromochloromethane ug/L <0.47 0.50 05/22/23 15:190.47
Bromodichloromethane ug/L <0.31 0.50 05/22/23 15:190.31
Bromoform ug/L <0.34 0.50 05/22/23 15:190.34
Bromomethane ug/L <1.7 5.0 05/22/23 15:191.7
Carbon tetrachloride ug/L <0.33 0.50 05/22/23 15:190.33
Chlorobenzene ug/L <0.28 0.50 05/22/23 15:190.28
Chloroethane ug/L <0.65 1.0 05/22/23 15:190.65
Chloroform ug/L <0.43 0.50 05/22/23 15:190.43
Chloromethane ug/L <0.54 1.0 05/22/23 15:190.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 05/22/23 15:190.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 05/22/23 15:190.36
Dibromochloromethane ug/L <0.36 0.50 05/22/23 15:190.36
Dibromomethane ug/L <0.39 0.50 05/22/23 15:190.39
Dichlorodifluoromethane ug/L <0.35 0.50 IH05/22/23 15:190.35
Diisopropyl ether ug/L <0.31 0.50 05/22/23 15:190.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026974
Associated Lab Samples:92667997001
Matrix: Water
AnalyzedMDL
Ethanol ug/L <72.2 200 05/22/23 15:1972.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 05/22/23 15:193.2
Ethylbenzene ug/L <0.30 0.50 05/22/23 15:190.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 05/22/23 15:191.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 05/22/23 15:190.33
m&p-Xylene ug/L <0.71 1.0 05/22/23 15:190.71
Methyl-tert-butyl ether ug/L <0.42 0.50 05/22/23 15:190.42
Methylene Chloride ug/L <2.0 2.0 05/22/23 15:192.0
n-Butylbenzene ug/L <0.49 0.50 05/22/23 15:190.49
n-Propylbenzene ug/L <0.34 0.50 05/22/23 15:190.34
Naphthalene ug/L <0.64 2.0 05/22/23 15:190.64
o-Xylene ug/L <0.34 0.50 05/22/23 15:190.34
sec-Butylbenzene ug/L <0.40 0.50 05/22/23 15:190.40
Styrene ug/L <0.29 0.50 05/22/23 15:190.29
tert-Amyl Alcohol ug/L <36.4 100 05/22/23 15:1936.4
tert-Amylmethyl ether ug/L <9.2 10.0 05/22/23 15:199.2
tert-Butyl Alcohol ug/L <26.8 50.0 05/22/23 15:1926.8
tert-Butyl Formate ug/L <29.4 50.0 05/22/23 15:1929.4
tert-Butylbenzene ug/L <0.32 0.50 05/22/23 15:190.32
Tetrachloroethene ug/L <0.29 0.50 05/22/23 15:190.29
Toluene ug/L <0.24 0.50 05/22/23 15:190.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 05/22/23 15:190.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 05/22/23 15:190.36
Trichloroethene ug/L <0.38 0.50 05/22/23 15:190.38
Trichlorofluoromethane ug/L <0.30 1.0 05/22/23 15:190.30
Vinyl chloride ug/L <0.39 1.0 05/22/23 15:190.39
Xylene (Total)ug/L <0.34 1.0 05/22/23 15:190.34
1,2-Dichloroethane-d4 (S)%119 70-130 05/22/23 15:19
4-Bromofluorobenzene (S)%97 70-130 05/22/23 15:19
Toluene-d8 (S)%104 70-130 05/22/23 15:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026975LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.720 104 60-140
1,1,1-Trichloroethane ug/L 22.720 113 60-140
1,1,2,2-Tetrachloroethane ug/L 22.120 110 60-140
1,1,2-Trichloroethane ug/L 20.620 103 60-140
1,1-Dichloroethane ug/L 25.020 125 60-140
1,1-Dichloroethene ug/L 24.920 124 60-140
1,1-Dichloropropene ug/L 25.720 129 60-140
1,2,3-Trichlorobenzene ug/L 18.920 95 60-140
1,2,3-Trichloropropane ug/L 21.320 106 60-140
1,2,4-Trichlorobenzene ug/L 19.120 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026975LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 21.620 108 60-140
1,2-Dibromo-3-chloropropane ug/L 18.920 94 60-140
1,2-Dibromoethane (EDB)ug/L 21.220 106 60-140
1,2-Dichlorobenzene ug/L 19.720 98 60-140
1,2-Dichloroethane ug/L 23.820 119 60-140
1,2-Dichloropropane ug/L 23.220 116 60-140
1,3,5-Trimethylbenzene ug/L 22.120 111 60-140
1,3-Dichlorobenzene ug/L 20.820 104 60-140
1,3-Dichloropropane ug/L 22.020 110 60-140
1,4-Dichlorobenzene ug/L 20.020 100 60-140
2,2-Dichloropropane ug/L 24.320 121 60-140
2-Chlorotoluene ug/L 21.920 110 60-140
4-Chlorotoluene ug/L 22.220 111 60-140
Benzene ug/L 22.320 112 60-140
Bromobenzene ug/L 20.120 100 60-140
Bromochloromethane ug/L 21.820 109 60-140
Bromodichloromethane ug/L 20.820 104 60-140
Bromoform ug/L 17.820 89 60-140
Bromomethane ug/L 25.320 126 60-140
Carbon tetrachloride ug/L 19.320 97 60-140
Chlorobenzene ug/L 21.120 106 60-140
Chloroethane ug/L 36.1 L120180 60-140
Chloroform ug/L 24.220 121 60-140
Chloromethane ug/L 28.6 L120143 60-140
cis-1,2-Dichloroethene ug/L 24.320 122 60-140
cis-1,3-Dichloropropene ug/L 21.320 107 60-140
Dibromochloromethane ug/L 20.620 103 60-140
Dibromomethane ug/L 18.820 94 60-140
Dichlorodifluoromethane ug/L 36.4 IH,L120182 60-140
Diisopropyl ether ug/L 22.520 112 60-140
Ethanol ug/L 815800 102 60-140
Ethyl-tert-butyl ether ug/L 44.340 111 60-140
Ethylbenzene ug/L 21.220 106 60-140
Hexachloro-1,3-butadiene ug/L 21.420 107 60-140
Isopropylbenzene (Cumene)ug/L 20.420 102 60-140
m&p-Xylene ug/L 42.540 106 60-140
Methyl-tert-butyl ether ug/L 20.820 104 60-140
Methylene Chloride ug/L 22.320 111 60-140
n-Butylbenzene ug/L 23.620 118 60-140
n-Propylbenzene ug/L 22.220 111 60-140
Naphthalene ug/L 21.520 107 60-140
o-Xylene ug/L 21.020 105 60-140
sec-Butylbenzene ug/L 21.420 107 60-140
Styrene ug/L 21.520 107 60-140
tert-Amyl Alcohol ug/L 327400 82 60-140
tert-Amylmethyl ether ug/L 41.540 104 60-140
tert-Butyl Alcohol ug/L 180200 90 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026975LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 133160 83 60-140
tert-Butylbenzene ug/L 17.420 87 60-140
Tetrachloroethene ug/L 18.820 94 60-140
Toluene ug/L 22.420 112 60-140
trans-1,2-Dichloroethene ug/L 25.820 129 60-140
trans-1,3-Dichloropropene ug/L 20.120 100 60-140
Trichloroethene ug/L 21.120 105 60-140
Trichlorofluoromethane ug/L 23.620 118 60-140
Vinyl chloride ug/L 22.120 111 60-140
Xylene (Total)ug/L 63.460 106 60-140
1,2-Dichloroethane-d4 (S)%116 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026976MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667432002
4026977
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 137 60-140136 1 3020ND27.5 27.2
1,1,1-Trichloroethane ug/L M12015960-140158 0 3020ND31.7 31.7
1,1,2,2-Tetrachloroethane ug/L M12014960-140151 2 3020ND29.8 30.3
1,1,2-Trichloroethane ug/L 20 138 60-140139 1 3020ND27.6 27.8
1,1-Dichloroethane ug/L M12017660-140174 1 3020ND35.2 34.8
1,1-Dichloroethene ug/L M12017360-140171 2 3020ND34.6 34.1
1,1-Dichloropropene ug/L M12018560-140182 1 3020ND36.9 36.5
1,2,3-Trichlorobenzene ug/L 20 119 60-140123 3 3020ND23.8 24.6
1,2,3-Trichloropropane ug/L M12014360-140145 1 3020ND28.6 28.9
1,2,4-Trichlorobenzene ug/L 20 129 60-140129 0 3020ND25.8 25.9
1,2,4-Trimethylbenzene ug/L M12015260-140150 2 3020ND30.4 29.9
1,2-Dibromo-3-
chloropropane ug/L 20 117 60-140120 3 3020ND23.3 24.0
1,2-Dibromoethane (EDB) ug/L M12014260-140144 2 3020ND28.3 28.8
1,2-Dichlorobenzene ug/L 20 137 60-140137 1 3020ND27.5 27.3
1,2-Dichloroethane ug/L M12016360-140166 2 3020ND32.5 33.2
1,2-Dichloropropane ug/L M12015860-140157 1 3020ND31.6 31.4
1,3,5-Trimethylbenzene ug/L M12015360-140150 2 30200.67 31.2 30.6
1,3-Dichlorobenzene ug/L M12014360-140140 2 3020ND28.5 27.9
1,3-Dichloropropane ug/L M12014860-140148 0 3020ND29.5 29.7
1,4-Dichlorobenzene ug/L 20 136 60-140134 1 3020ND27.1 26.8
2,2-Dichloropropane ug/L M12017560-140173 1 3020ND34.9 34.6
2-Chlorotoluene ug/L M12015760-140154 2 3020ND31.4 30.9
4-Chlorotoluene ug/L M12015460-140152 1 3020ND30.9 30.5
Benzene ug/L M12015360-140150 1 30203.1 33.6 33.1
Bromobenzene ug/L 20 137 60-140136 1 3020ND27.5 27.2
Bromochloromethane ug/L M12015160-140149 1 3020ND30.1 29.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026976MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667432002
4026977
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 133 60-140133 0 3020ND26.6 26.7
Bromoform ug/L 20 103 60-140105 1 3020ND20.7 21.0
Bromomethane ug/L M12015060-140147 3 3020ND30.0 29.3
Carbon tetrachloride ug/L 20 132 60-140130 1 3020ND26.3 26.0
Chlorobenzene ug/L M12014460-140142 1 3020ND28.8 28.4
Chloroethane ug/L M02023560-140230 2 3020ND47.1 46.0
Chloroform ug/L M12016860-140166 1 3020ND33.5 33.1
Chloromethane ug/L M02019060-140190 0 3020ND38.0 37.9
cis-1,2-Dichloroethene ug/L M12017160-140166 3 3020ND34.2 33.3
cis-1,3-Dichloropropene ug/L 20 135 60-140137 2 3020ND27.0 27.5
Dibromochloromethane ug/L 20 127 60-140128 0 3020ND25.5 25.6
Dibromomethane ug/L 20 124 60-140125 1 3020ND24.7 25.0
Dichlorodifluoromethane ug/L IH,M02022860-140227 0 3020ND45.6 45.4
Diisopropyl ether ug/L M12015960-140159 0 30201.2 33.1 32.9
Ethanol ug/L 800 135 60-140138 2 30800ND1080 1100
Ethyl-tert-butyl ether ug/L M14015560-140155 0 3040ND62.0 61.9
Ethylbenzene ug/L M12014860-140146 2 3020ND29.6 29.1
Hexachloro-1,3-butadiene ug/L 20 134 60-140135 0 3020ND26.8 27.0
Isopropylbenzene
(Cumene)ug/L M12014860-140143 4 3020ND29.7 28.6
m&p-Xylene ug/L M14014660-140144 2 30402.1 60.5 59.6
Methyl-tert-butyl ether ug/L M12014660-140150 2 302014.5 43.7 44.5
Methylene Chloride ug/L M12015360-140150 2 3020ND30.7 30.0
n-Butylbenzene ug/L M12016960-140164 3 3020ND33.8 32.7
n-Propylbenzene ug/L M12015660-140154 1 3020ND31.2 30.8
Naphthalene ug/L M12014860-140157 5 30208.9 38.6 40.4
o-Xylene ug/L M12014260-140142 0 30203.0 31.4 31.4
sec-Butylbenzene ug/L M12015460-140153 1 3020ND30.7 30.5
Styrene ug/L M12014460-140145 1 3020ND28.7 28.9
tert-Amyl Alcohol ug/L M140014160-140147 4 30400ND564 590
tert-Amylmethyl ether ug/L M14013960-140141 1 3040ND57.5 58.4
tert-Butyl Alcohol ug/L M120018360-140194 6 30200ND367 388
tert-Butyl Formate ug/L P51606260-14052 17 30160ND98.8 82.9
tert-Butylbenzene ug/L 20 124 60-140120 3 3020ND24.7 24.0
Tetrachloroethene ug/L 20 127 60-140127 0 3020ND25.4 25.5
Toluene ug/L M12014160-140135 4 30201.1 29.3 28.1
trans-1,2-Dichloroethene ug/L M12018260-140180 1 3020ND36.4 36.0
trans-1,3-Dichloropropene ug/L 20 135 60-140135 0 3020ND27.0 27.1
Trichloroethene ug/L M12014160-140142 0 3020ND28.3 28.4
Trichlorofluoromethane ug/L M12016460-140162 1 3020ND32.8 32.4
Vinyl chloride ug/L M12015360-140150 2 3020ND30.7 30.1
Xylene (Total)ug/L MS6014560-140143 1 30605.2 92.0 91.0
1,2-Dichloroethane-d4 (S) %119 70-130119
4-Bromofluorobenzene (S) %102 70-130103
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
776135
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997002, 92667997004, 92667997005, 92667997006, 92667997010, 92667997012, 92667997013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026978
Associated Lab Samples:92667997002, 92667997004, 92667997005, 92667997006, 92667997010, 92667997012, 92667997013
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 05/22/23 23:370.31
1,1,1-Trichloroethane ug/L <0.33 0.50 05/22/23 23:370.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 05/22/23 23:370.22
1,1,2-Trichloroethane ug/L <0.32 0.50 05/22/23 23:370.32
1,1-Dichloroethane ug/L <0.37 0.50 05/22/23 23:370.37
1,1-Dichloroethene ug/L <0.35 0.50 05/22/23 23:370.35
1,1-Dichloropropene ug/L <0.43 0.50 05/22/23 23:370.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 05/22/23 23:370.81
1,2,3-Trichloropropane ug/L <0.26 0.50 05/22/23 23:370.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 05/22/23 23:370.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 05/22/23 23:370.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 05/22/23 23:370.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 05/22/23 23:370.27
1,2-Dichlorobenzene ug/L <0.34 0.50 05/22/23 23:370.34
1,2-Dichloroethane ug/L <0.32 0.50 05/22/23 23:370.32
1,2-Dichloropropane ug/L <0.36 0.50 05/22/23 23:370.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 05/22/23 23:370.33
1,3-Dichlorobenzene ug/L <0.34 0.50 05/22/23 23:370.34
1,3-Dichloropropane ug/L <0.28 0.50 05/22/23 23:370.28
1,4-Dichlorobenzene ug/L <0.33 0.50 05/22/23 23:370.33
2,2-Dichloropropane ug/L <0.39 0.50 05/22/23 23:370.39
2-Chlorotoluene ug/L <0.32 0.50 05/22/23 23:370.32
4-Chlorotoluene ug/L <0.32 0.50 05/22/23 23:370.32
Benzene ug/L <0.34 0.50 05/22/23 23:370.34
Bromobenzene ug/L <0.29 0.50 05/22/23 23:370.29
Bromochloromethane ug/L <0.47 0.50 05/22/23 23:370.47
Bromodichloromethane ug/L <0.31 0.50 05/22/23 23:370.31
Bromoform ug/L <0.34 0.50 05/22/23 23:370.34
Bromomethane ug/L <1.7 5.0 05/22/23 23:371.7
Carbon tetrachloride ug/L <0.33 0.50 05/22/23 23:370.33
Chlorobenzene ug/L <0.28 0.50 05/22/23 23:370.28
Chloroethane ug/L <0.65 1.0 05/22/23 23:370.65
Chloroform ug/L <0.43 0.50 05/22/23 23:370.43
Chloromethane ug/L <0.54 1.0 05/22/23 23:370.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 05/22/23 23:370.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 05/22/23 23:370.36
Dibromochloromethane ug/L <0.36 0.50 05/22/23 23:370.36
Dibromomethane ug/L <0.39 0.50 05/22/23 23:370.39
Dichlorodifluoromethane ug/L <0.35 0.50 IH05/22/23 23:370.35
Diisopropyl ether ug/L <0.31 0.50 05/22/23 23:370.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026978
Associated Lab Samples:92667997002, 92667997004, 92667997005, 92667997006, 92667997010, 92667997012, 92667997013
Matrix: Water
AnalyzedMDL
Ethanol ug/L <72.2 200 05/22/23 23:3772.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 05/22/23 23:373.2
Ethylbenzene ug/L <0.30 0.50 05/22/23 23:370.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 05/22/23 23:371.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 05/22/23 23:370.33
m&p-Xylene ug/L <0.71 1.0 05/22/23 23:370.71
Methyl-tert-butyl ether ug/L <0.42 0.50 05/22/23 23:370.42
Methylene Chloride ug/L 2.0 2.0 05/22/23 23:372.0
n-Butylbenzene ug/L <0.49 0.50 05/22/23 23:370.49
n-Propylbenzene ug/L <0.34 0.50 05/22/23 23:370.34
Naphthalene ug/L <0.64 2.0 05/22/23 23:370.64
o-Xylene ug/L <0.34 0.50 05/22/23 23:370.34
sec-Butylbenzene ug/L <0.40 0.50 05/22/23 23:370.40
Styrene ug/L <0.29 0.50 05/22/23 23:370.29
tert-Amyl Alcohol ug/L <36.4 100 05/22/23 23:3736.4
tert-Amylmethyl ether ug/L <9.2 10.0 05/22/23 23:379.2
tert-Butyl Alcohol ug/L <26.8 50.0 05/22/23 23:3726.8
tert-Butyl Formate ug/L <29.4 50.0 05/22/23 23:3729.4
tert-Butylbenzene ug/L <0.32 0.50 05/22/23 23:370.32
Tetrachloroethene ug/L <0.29 0.50 05/22/23 23:370.29
Toluene ug/L <0.24 0.50 05/22/23 23:370.24
trans-1,2-Dichloroethene ug/L <0.40 0.50 05/22/23 23:370.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 05/22/23 23:370.36
Trichloroethene ug/L <0.38 0.50 05/22/23 23:370.38
Trichlorofluoromethane ug/L <0.30 1.0 05/22/23 23:370.30
Vinyl chloride ug/L <0.39 1.0 05/22/23 23:370.39
Xylene (Total)ug/L <0.34 1.0 05/22/23 23:370.34
1,2-Dichloroethane-d4 (S)%121 70-130 05/22/23 23:37
4-Bromofluorobenzene (S)%97 70-130 05/22/23 23:37
Toluene-d8 (S)%104 70-130 05/22/23 23:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026979LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 19.820 99 60-140
1,1,1-Trichloroethane ug/L 22.420 112 60-140
1,1,2,2-Tetrachloroethane ug/L 22.620 113 60-140
1,1,2-Trichloroethane ug/L 21.120 105 60-140
1,1-Dichloroethane ug/L 25.420 127 60-140
1,1-Dichloroethene ug/L 24.620 123 60-140
1,1-Dichloropropene ug/L 25.820 129 60-140
1,2,3-Trichlorobenzene ug/L 16.920 84 60-140
1,2,3-Trichloropropane ug/L 21.720 109 60-140
1,2,4-Trichlorobenzene ug/L 17.520 87 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026979LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 21.420 107 60-140
1,2-Dibromo-3-chloropropane ug/L 16.620 83 60-140
1,2-Dibromoethane (EDB)ug/L 21.420 107 60-140
1,2-Dichlorobenzene ug/L 20.320 101 60-140
1,2-Dichloroethane ug/L 24.520 123 60-140
1,2-Dichloropropane ug/L 23.120 116 60-140
1,3,5-Trimethylbenzene ug/L 21.720 108 60-140
1,3-Dichlorobenzene ug/L 20.720 103 60-140
1,3-Dichloropropane ug/L 21.920 110 60-140
1,4-Dichlorobenzene ug/L 20.020 100 60-140
2,2-Dichloropropane ug/L 22.120 111 60-140
2-Chlorotoluene ug/L 22.320 111 60-140
4-Chlorotoluene ug/L 22.820 114 60-140
Benzene ug/L 22.420 112 60-140
Bromobenzene ug/L 20.120 100 60-140
Bromochloromethane ug/L 22.520 112 60-140
Bromodichloromethane ug/L 19.920 99 60-140
Bromoform ug/L 14.920 74 60-140
Bromomethane ug/L 23.120 115 60-140
Carbon tetrachloride ug/L 18.620 93 60-140
Chlorobenzene ug/L 21.520 108 60-140
Chloroethane ug/L 35.8 L120179 60-140
Chloroform ug/L 24.220 121 60-140
Chloromethane ug/L 27.820 139 60-140
cis-1,2-Dichloroethene ug/L 24.120 121 60-140
cis-1,3-Dichloropropene ug/L 20.420 102 60-140
Dibromochloromethane ug/L 18.420 92 60-140
Dibromomethane ug/L 18.920 94 60-140
Dichlorodifluoromethane ug/L 34.4 IH,L120172 60-140
Diisopropyl ether ug/L 23.120 115 60-140
Ethanol ug/L 856800 107 60-140
Ethyl-tert-butyl ether ug/L 45.140 113 60-140
Ethylbenzene ug/L 21.420 107 60-140
Hexachloro-1,3-butadiene ug/L 17.020 85 60-140
Isopropylbenzene (Cumene)ug/L 20.720 103 60-140
m&p-Xylene ug/L 42.240 105 60-140
Methyl-tert-butyl ether ug/L 21.420 107 60-140
Methylene Chloride ug/L 23.720 119 60-140
n-Butylbenzene ug/L 21.920 110 60-140
n-Propylbenzene ug/L 22.020 110 60-140
Naphthalene ug/L 20.120 100 60-140
o-Xylene ug/L 20.820 104 60-140
sec-Butylbenzene ug/L 21.320 106 60-140
Styrene ug/L 21.220 106 60-140
tert-Amyl Alcohol ug/L 340400 85 60-140
tert-Amylmethyl ether ug/L 41.840 104 60-140
tert-Butyl Alcohol ug/L 187200 93 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026979LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 127160 80 60-140
tert-Butylbenzene ug/L 17.420 87 60-140
Tetrachloroethene ug/L 18.220 91 60-140
Toluene ug/L 20.520 102 60-140
trans-1,2-Dichloroethene ug/L 25.420 127 60-140
trans-1,3-Dichloropropene ug/L 19.120 95 60-140
Trichloroethene ug/L 20.920 105 60-140
Trichlorofluoromethane ug/L 23.120 116 60-140
Vinyl chloride ug/L 21.920 109 60-140
Xylene (Total)ug/L 63.060 105 60-140
1,2-Dichloroethane-d4 (S)%117 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667997002
4026981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 109 60-140120 10 3020<0.31 21.9 24.0
1,1,1-Trichloroethane ug/L M12013160-140142 9 3020<0.33 26.1 28.4
1,1,2,2-Tetrachloroethane ug/L 20 116 60-140129 11 3020<0.22 23.2 25.8
1,1,2-Trichloroethane ug/L 20 114 60-140122 7 3020<0.32 22.9 24.4
1,1-Dichloroethane ug/L M12014660-140157 7 3020<0.37 29.3 31.5
1,1-Dichloroethene ug/L M12014360-140156 9 3020<0.35 28.6 31.1
1,1-Dichloropropene ug/L M12015160-140165 9 3020<0.43 30.3 33.0
1,2,3-Trichlorobenzene ug/L 20 92 60-14097 5 3020<0.81 18.4 19.5
1,2,3-Trichloropropane ug/L 20 111 60-140125 12 3020<0.26 22.2 25.0
1,2,4-Trichlorobenzene ug/L 20 98 60-140104 6 3020<0.64 19.5 20.7
1,2,4-Trimethylbenzene ug/L 20 117 60-140128 8 3020<0.50 23.5 25.5
1,2-Dibromo-3-
chloropropane ug/L 20 87 60-14098 12 3020<0.34 17.4 19.6
1,2-Dibromoethane (EDB) ug/L 20 114 60-140125 9 3020<0.27 22.8 25.0
1,2-Dichlorobenzene ug/L 20 108 60-140117 8 3020<0.34 21.6 23.5
1,2-Dichloroethane ug/L M12013360-140145 9 3020<0.32 26.6 29.0
1,2-Dichloropropane ug/L M12013060-140141 8 3020<0.36 26.0 28.2
1,3,5-Trimethylbenzene ug/L 20 118 60-140129 9 3020<0.33 23.7 25.8
1,3-Dichlorobenzene ug/L 20 114 60-140122 6 3020<0.34 22.8 24.3
1,3-Dichloropropane ug/L 20 119 60-140131 9 3020<0.28 23.8 26.1
1,4-Dichlorobenzene ug/L 20 107 60-140118 10 3020<0.33 21.3 23.5
2,2-Dichloropropane ug/L M12014260-140154 8 3020<0.39 28.4 30.8
2-Chlorotoluene ug/L 20 123 60-140134 9 3020<0.32 24.5 26.8
4-Chlorotoluene ug/L 20 124 60-140134 8 3020<0.32 24.9 26.8
Benzene ug/L 20 125 60-140134 7 3020<0.34 25.0 26.8
Bromobenzene ug/L 20 110 60-140119 9 3020<0.29 21.9 23.9
Bromochloromethane ug/L 20 123 60-140131 6 3020<0.47 24.6 26.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667997002
4026981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 110 60-140118 7 3020<0.31 22.0 23.6
Bromoform ug/L 20 79 60-14090 12 3020<0.34 15.9 17.9
Bromomethane ug/L 20 127 60-140134 6 3020<1.7 25.3 26.9
Carbon tetrachloride ug/L 20 110 60-140119 8 3020<0.33 22.0 23.7
Chlorobenzene ug/L 20 116 60-140127 9 3020<0.28 23.3 25.5
Chloroethane ug/L M02018760-140208 10 3020<0.65 37.5 41.5
Chloroform ug/L M12013360-140142 6 3020<0.43 26.7 28.4
Chloromethane ug/L M12015960-140173 8 3020<0.54 31.9 34.5
cis-1,2-Dichloroethene ug/L M12014260-140151 6 3020<0.38 28.3 30.1
cis-1,3-Dichloropropene ug/L 20 112 60-140119 6 3020<0.36 22.4 23.8
Dibromochloromethane ug/L 20 102 60-140110 8 3020<0.36 20.3 22.0
Dibromomethane ug/L 20 101 60-140110 8 3020<0.39 20.3 21.9
Dichlorodifluoromethane ug/L IH,M02018860-140200 6 3020<0.35 37.6 40.1
Diisopropyl ether ug/L 20 127 60-140140 10 3020<0.31 25.4 28.0
Ethanol ug/L 800 106 60-140119 12 30800<72.2 847 952
Ethyl-tert-butyl ether ug/L 40 126 60-140136 8 3040<3.2 50.2 54.5
Ethylbenzene ug/L 20 119 60-140130 10 3020<0.30 23.7 26.1
Hexachloro-1,3-butadiene ug/L 20 99 60-140107 8 3020<1.5 19.8 21.5
Isopropylbenzene
(Cumene)ug/L 20 116 60-140128 10 3020<0.33 23.2 25.7
m&p-Xylene ug/L 40 116 60-140128 10 3040<0.71 46.5 51.2
Methyl-tert-butyl ether ug/L 20 116 60-140127 9 3020<0.42 23.2 25.4
Methylene Chloride ug/L 20 122 60-140133 9 3020<2.0 24.4 26.7
n-Butylbenzene ug/L 20 127 60-140137 8 3020<0.49 25.4 27.5
n-Propylbenzene ug/L 20 124 60-140135 8 3020<0.34 24.8 26.9
Naphthalene ug/L 20 110 60-140118 7 3020<0.64 21.9 23.6
o-Xylene ug/L 20 113 60-140122 8 3020<0.34 22.5 24.4
sec-Butylbenzene ug/L 20 121 60-140133 9 3020<0.40 24.3 26.5
Styrene ug/L 20 115 60-140127 9 3020<0.29 23.1 25.4
tert-Amyl Alcohol ug/L 400 83 60-14097 15 30400<36.4 333 386
tert-Amylmethyl ether ug/L 40 112 60-140121 8 3040<9.2 44.6 48.4
tert-Butyl Alcohol ug/L M120012060-140144 18 30200<26.8 239 287
tert-Butyl Formate ug/L P51604260-14036 14 30160<29.4 66.6 58.0
tert-Butylbenzene ug/L 20 98 60-140106 8 3020<0.32 19.6 21.2
Tetrachloroethene ug/L 20 102 60-140113 10 3020<0.29 20.4 22.6
Toluene ug/L 20 112 60-140122 8 3020<0.24 22.5 24.4
trans-1,2-Dichloroethene ug/L M12014960-140162 8 3020<0.40 29.8 32.3
trans-1,3-Dichloropropene ug/L 20 109 60-140116 6 3020<0.36 21.7 23.1
Trichloroethene ug/L 20 119 60-140129 8 3020<0.38 23.7 25.8
Trichlorofluoromethane ug/L M12013460-140147 9 3020<0.30 26.9 29.5
Vinyl chloride ug/L 20 124 60-140135 8 3020<0.39 24.8 27.0
Xylene (Total)ug/L 60 115 60-140126 9 3060<0.34 69.0 75.7
1,2-Dichloroethane-d4 (S) %119 70-130119
4-Bromofluorobenzene (S) %101 70-130103
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
775237
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997005, 92667997007, 92667997010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4022927
Associated Lab Samples:92667997005, 92667997007, 92667997010
Matrix: Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L <1.7 5.0 05/19/23 19:051.7
2,2'-Oxybis(1-chloropropane)ug/L <1.2 5.0 05/19/23 19:051.2
2,4,6-Trichlorophenol ug/L <1.6 10.0 05/19/23 19:051.6
2,4-Dichlorophenol ug/L <1.4 5.0 05/19/23 19:051.4
2,4-Dimethylphenol ug/L <1.7 10.0 05/19/23 19:051.7
2,4-Dinitrophenol ug/L <26.0 50.0 05/19/23 19:0526.0
2,4-Dinitrotoluene ug/L <1.6 5.0 05/19/23 19:051.6
2,6-Dinitrotoluene ug/L <1.7 5.0 05/19/23 19:051.7
2-Chloronaphthalene ug/L <1.7 5.0 05/19/23 19:051.7
2-Chlorophenol ug/L <1.2 5.0 05/19/23 19:051.2
2-Nitrophenol ug/L <1.4 5.0 05/19/23 19:051.4
3,3'-Dichlorobenzidine ug/L <8.1 10.0 05/19/23 19:058.1
4,6-Dinitro-2-methylphenol ug/L <7.8 10.0 05/19/23 19:057.8
4-Bromophenylphenyl ether ug/L <1.8 5.0 05/19/23 19:051.8
4-Chloro-3-methylphenol ug/L <3.3 5.0 05/19/23 19:053.3
4-Chlorophenylphenyl ether ug/L <2.0 5.0 05/19/23 19:052.0
4-Nitrophenol ug/L <6.6 10.0 05/19/23 19:056.6
Acenaphthene ug/L <2.0 5.0 05/19/23 19:052.0
Acenaphthylene ug/L <2.0 5.0 05/19/23 19:052.0
Anthracene ug/L <2.3 5.0 05/19/23 19:052.3
Benzo(a)anthracene ug/L <2.7 5.0 05/19/23 19:052.7
Benzo(a)pyrene ug/L <2.8 5.0 05/19/23 19:052.8
Benzo(b)fluoranthene ug/L <2.6 5.0 05/19/23 19:052.6
Benzo(g,h,i)perylene ug/L <2.8 5.0 05/19/23 19:052.8
Benzo(k)fluoranthene ug/L <2.7 5.0 05/19/23 19:052.7
bis(2-Chloroethoxy)methane ug/L <1.8 10.0 05/19/23 19:051.8
bis(2-Chloroethyl) ether ug/L <1.9 5.0 05/19/23 19:051.9
bis(2-Ethylhexyl)phthalate ug/L <3.7 5.0 05/19/23 19:053.7
Butylbenzylphthalate ug/L <3.1 5.0 05/19/23 19:053.1
Chrysene ug/L <2.8 5.0 05/19/23 19:052.8
Di-n-butylphthalate ug/L <2.2 5.0 05/19/23 19:052.2
Di-n-octylphthalate ug/L <3.9 5.0 05/19/23 19:053.9
Dibenz(a,h)anthracene ug/L <3.0 5.0 05/19/23 19:053.0
Diethylphthalate ug/L <2.0 5.0 05/19/23 19:052.0
Dimethylphthalate ug/L <2.1 5.0 05/19/23 19:052.1
Fluoranthene ug/L <2.2 5.0 05/19/23 19:052.2
Fluorene ug/L <2.1 5.0 05/19/23 19:052.1
Hexachloro-1,3-butadiene ug/L <1.8 5.0 05/19/23 19:051.8
Hexachlorobenzene ug/L <2.2 5.0 05/19/23 19:052.2
Hexachlorocyclopentadiene ug/L <1.6 10.0 05/19/23 19:051.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4022927
Associated Lab Samples:92667997005, 92667997007, 92667997010
Matrix: Water
AnalyzedMDL
Hexachloroethane ug/L <1.4 5.0 05/19/23 19:051.4
Indeno(1,2,3-cd)pyrene ug/L <2.9 5.0 05/19/23 19:052.9
Isophorone ug/L <1.7 10.0 05/19/23 19:051.7
N-Nitroso-di-n-propylamine ug/L <1.3 5.0 05/19/23 19:051.3
N-Nitrosodimethylamine ug/L <1.9 5.0 05/19/23 19:051.9
N-Nitrosodiphenylamine ug/L <3.0 10.0 05/19/23 19:053.0
Naphthalene ug/L <2.1 5.0 05/19/23 19:052.1
Nitrobenzene ug/L <1.9 5.0 05/19/23 19:051.9
Pentachlorophenol ug/L <3.8 10.0 05/19/23 19:053.8
Phenanthrene ug/L <2.0 5.0 05/19/23 19:052.0
Phenol ug/L <1.4 5.0 05/19/23 19:051.4
Pyrene ug/L <2.2 5.0 05/19/23 19:052.2
2,4,6-Tribromophenol (S)%82 10-137 05/19/23 19:05
2-Fluorobiphenyl (S)%65 15-120 05/19/23 19:05
2-Fluorophenol (S)%56 10-120 05/19/23 19:05
Nitrobenzene-d5 (S)%74 10-120 05/19/23 19:05
Phenol-d6 (S)%43 10-120 05/19/23 19:05
Terphenyl-d14 (S)%87 11-131 05/19/23 19:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4022928LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 41.350 83 44-142
2,2'-Oxybis(1-chloropropane)ug/L 40.350 81 36-166
2,4,6-Trichlorophenol ug/L 44.250 88 37-144
2,4-Dichlorophenol ug/L 42.650 85 1-191
2,4-Dimethylphenol ug/L 62.6 L150125 32-119
2,4-Dinitrophenol ug/L 219250 88 1-181
2,4-Dinitrotoluene ug/L 47.150 94 39-139
2,6-Dinitrotoluene ug/L 46.350 93 50-158
2-Chloronaphthalene ug/L 41.250 82 60-118
2-Chlorophenol ug/L 39.850 80 23-134
2-Nitrophenol ug/L 45.050 90 29-182
3,3'-Dichlorobenzidine ug/L 87.8100 88 1-262
4,6-Dinitro-2-methylphenol ug/L 101100 101 1-181
4-Bromophenylphenyl ether ug/L 45.150 90 53-127
4-Chloro-3-methylphenol ug/L 81.8100 82 22-147
4-Chlorophenylphenyl ether ug/L 41.750 83 25-158
4-Nitrophenol ug/L 127250 51 1-132
Acenaphthene ug/L 43.250 86 47-145
Acenaphthylene ug/L 42.550 85 33-145
Anthracene ug/L 41.750 83 1-166
Benzo(a)anthracene ug/L 45.150 90 33-143
Benzo(a)pyrene ug/L 44.550 89 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4022928LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 43.750 87 24-159
Benzo(g,h,i)perylene ug/L 44.750 89 1-219
Benzo(k)fluoranthene ug/L 44.950 90 11-162
bis(2-Chloroethoxy)methane ug/L 40.650 81 33-184
bis(2-Chloroethyl) ether ug/L 41.150 82 12-158
bis(2-Ethylhexyl)phthalate ug/L 47.950 96 8-158
Butylbenzylphthalate ug/L 49.850 100 1-152
Chrysene ug/L 44.850 90 17-168
Di-n-butylphthalate ug/L 47.250 94 1-118
Di-n-octylphthalate ug/L 48.550 97 4-146
Dibenz(a,h)anthracene ug/L 44.850 90 1-227
Diethylphthalate ug/L 44.250 88 1-114
Dimethylphthalate ug/L 43.550 87 1-112
Fluoranthene ug/L 47.250 94 26-137
Fluorene ug/L 44.050 88 59-121
Hexachloro-1,3-butadiene ug/L 39.850 80 24-116
Hexachlorobenzene ug/L 44.750 89 1-152
Hexachlorocyclopentadiene ug/L 43.250 86 25-150
Hexachloroethane ug/L 40.750 81 40-113
Indeno(1,2,3-cd)pyrene ug/L 45.250 90 1-171
Isophorone ug/L 42.450 85 21-196
N-Nitroso-di-n-propylamine ug/L 41.650 83 1-230
N-Nitrosodimethylamine ug/L 36.450 73 25-150
N-Nitrosodiphenylamine ug/L 43.150 86 25-150
Naphthalene ug/L 41.750 83 21-133
Nitrobenzene ug/L 39.850 80 35-180
Pentachlorophenol ug/L 94.5100 94 14-176
Phenanthrene ug/L 44.850 90 54-120
Phenol ug/L 26.450 53 5-112
Pyrene ug/L 46.450 93 52-115
2,4,6-Tribromophenol (S)%118 10-137
2-Fluorobiphenyl (S)%93 15-120
2-Fluorophenol (S)%67 10-120
Nitrobenzene-d5 (S)%94 10-120
Phenol-d6 (S)%52 10-120
Terphenyl-d14 (S)%108 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4022929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667997005
4022930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L M1,R183.3 43 44-14227 46 3083.3<1.4 35.5 22.3
2,2'-Oxybis(1-
chloropropane)ug/L 83.3 71 36-16661 14 3083.3<0.96 59.2 51.2
2,4,6-Trichlorophenol ug/L 83.3 88 37-14477 13 3083.3<1.3 73.3 64.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4022929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667997005
4022930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L 83.3 98 1-19179 22 3083.3<1.2 81.8 65.4
2,4-Dimethylphenol ug/L M083.3 125 32-119118 6 3083.3<1.4 104 98.1
2,4-Dinitrophenol ug/L 417 106 1-18190 16 30417<21.7 441 376
2,4-Dinitrotoluene ug/L 83.3 92 39-13985 8 3083.3<1.4 76.5 70.7
2,6-Dinitrotoluene ug/L 83.3 86 50-15881 6 3083.3<1.4 71.9 67.8
2-Chloronaphthalene ug/L M183.3 65 60-11855 16 3083.3<1.4 54.0 46.1
2-Chlorophenol ug/L 83.3 79 23-13470 13 3083.3<1.0 66.2 58.0
2-Nitrophenol ug/L 83.3 97 29-18284 15 3083.3<1.2 81.0 69.8
3,3'-Dichlorobenzidine ug/L 167 69 1-26262 9 30167<6.8 114 104
4,6-Dinitro-2-methylphenol ug/L 167 103 1-18189 15 30167<6.5 172 149
4-Bromophenylphenyl ether ug/L 83.3 85 53-12777 10 3083.3<1.5 70.9 64.0
4-Chloro-3-methylphenol ug/L 167 84 22-14773 14 30167<2.8 140 121
4-Chlorophenylphenyl ether ug/L 83.3 78 25-15868 14 3083.3<1.7 64.7 56.4
4-Nitrophenol ug/L 417 53 1-13249 7 30417<5.5 219 205
Acenaphthene ug/L 83.3 79 47-14566 17 3083.3<1.7 65.5 55.1
Acenaphthylene ug/L 83.3 75 33-14565 14 3083.3<1.6 62.8 54.6
Anthracene ug/L 83.3 79 1-16671 11 3083.3<1.9 66.0 59.1
Benzo(a)anthracene ug/L 83.3 84 33-14377 8 3083.3<2.2 70.0 64.5
Benzo(a)pyrene ug/L 83.3 83 17-16375 10 3083.3<2.3 69.2 62.6
Benzo(b)fluoranthene ug/L 83.3 84 24-15973 13 3083.3<2.2 70.0 61.2
Benzo(g,h,i)perylene ug/L 83.3 87 1-21977 12 3083.3<2.4 72.7 64.2
Benzo(k)fluoranthene ug/L 83.3 84 11-16275 11 3083.3<2.3 69.8 62.6
bis(2-
Chloroethoxy)methane ug/L 83.3 84 33-18470 19 3083.3<1.5 70.3 58.3
bis(2-Chloroethyl) ether ug/L 83.3 78 12-15871 9 3083.3<1.6 64.6 58.8
bis(2-Ethylhexyl)phthalate ug/L 83.3 87 8-15880 8 3083.3<3.1 72.8 66.9
Butylbenzylphthalate ug/L 83.3 89 1-15282 9 3083.3<2.6 74.2 68.1
Chrysene ug/L 83.3 84 17-16879 6 3083.3<2.3 69.7 65.5
Di-n-butylphthalate ug/L 83.3 89 1-11880 11 3083.3<1.8 74.4 66.7
Di-n-octylphthalate ug/L 83.3 87 4-14680 7 3083.3<3.3 72.3 67.1
Dibenz(a,h)anthracene ug/L 83.3 87 1-22776 13 3083.3<2.5 72.4 63.6
Diethylphthalate ug/L 83.3 85 1-11476 10 3083.3<1.7 70.6 63.6
Dimethylphthalate ug/L 83.3 84 1-11275 11 3083.3<1.8 69.9 62.6
Fluoranthene ug/L 83.3 92 26-13782 11 3083.3<1.8 76.3 68.2
Fluorene ug/L 83.3 82 59-12172 13 3083.33.0J 71.7 62.8
Hexachloro-1,3-butadiene ug/L M1,R183.3 33 24-11617 65 3083.3<1.5 27.2 13.8
Hexachlorobenzene ug/L 83.3 84 1-15274 12 3083.3<1.8 69.8 61.9
Hexachlorocyclopentadiene ug/L R183.3 45 25-15030 40 3083.3<1.3 37.6 25.1
Hexachloroethane ug/L M1,R183.3 33 40-11313 89 3083.3<1.2 27.7 10.7
Indeno(1,2,3-cd)pyrene ug/L 83.3 88 1-17178 12 3083.3<2.4 73.3 64.8
Isophorone ug/L 83.3 90 21-19675 18 3083.3<1.4 75.0 62.4
N-Nitroso-di-n-propylamine ug/L 83.3 86 1-23074 15 3083.3<1.1 71.9 61.9
N-Nitrosodimethylamine ug/L 83.3 73 25-15064 13 3083.3<1.6 60.6 53.4
N-Nitrosodiphenylamine ug/L 83.3 96 25-15077 21 3083.3<2.5 79.7 64.4
Naphthalene ug/L 83.3 47 21-13332 26 3083.316.7 55.9 43.1
Nitrobenzene ug/L 83.3 81 35-18068 18 3083.3<1.6 67.6 56.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4022929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92667997005
4022930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L 167 97 14-17685 14 30167<3.1 162 142
Phenanthrene ug/L 83.3 85 54-12077 10 3083.3<1.7 71.1 64.2
Phenol ug/L 83.3 49 5-11244 12 3083.3<1.1 41.1 36.6
Pyrene ug/L 83.3 85 52-11577 10 3083.3<1.8 71.0 64.1
2,4,6-Tribromophenol (S) %96 10-13783
2-Fluorobiphenyl (S)%67 15-12059
2-Fluorophenol (S)%55 10-12047
Nitrobenzene-d5 (S)%78 10-12070
Phenol-d6 (S)%43 10-12037
Terphenyl-d14 (S)%78 11-13169
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
776032
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples: 92667997011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026278
Associated Lab Samples:92667997011
Matrix: Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L <1.7 5.0 05/23/23 18:431.7
2,2'-Oxybis(1-chloropropane)ug/L <1.2 5.0 05/23/23 18:431.2
2,4,6-Trichlorophenol ug/L <1.6 10.0 05/23/23 18:431.6
2,4-Dichlorophenol ug/L <1.4 5.0 05/23/23 18:431.4
2,4-Dimethylphenol ug/L <1.7 10.0 05/23/23 18:431.7
2,4-Dinitrophenol ug/L <26.0 50.0 05/23/23 18:4326.0
2,4-Dinitrotoluene ug/L <1.6 5.0 05/23/23 18:431.6
2,6-Dinitrotoluene ug/L <1.7 5.0 05/23/23 18:431.7
2-Chloronaphthalene ug/L <1.7 5.0 05/23/23 18:431.7
2-Chlorophenol ug/L <1.2 5.0 05/23/23 18:431.2
2-Nitrophenol ug/L <1.4 5.0 05/23/23 18:431.4
3,3'-Dichlorobenzidine ug/L <8.1 10.0 05/23/23 18:438.1
4,6-Dinitro-2-methylphenol ug/L <7.8 10.0 05/23/23 18:437.8
4-Bromophenylphenyl ether ug/L <1.8 5.0 05/23/23 18:431.8
4-Chloro-3-methylphenol ug/L <3.3 5.0 05/23/23 18:433.3
4-Chlorophenylphenyl ether ug/L <2.0 5.0 05/23/23 18:432.0
4-Nitrophenol ug/L <6.6 10.0 05/23/23 18:436.6
Acenaphthene ug/L <2.0 5.0 05/23/23 18:432.0
Acenaphthylene ug/L <2.0 5.0 05/23/23 18:432.0
Anthracene ug/L <2.3 5.0 05/23/23 18:432.3
Benzo(a)anthracene ug/L <2.7 5.0 05/23/23 18:432.7
Benzo(a)pyrene ug/L <2.8 5.0 05/23/23 18:432.8
Benzo(b)fluoranthene ug/L <2.6 5.0 05/23/23 18:432.6
Benzo(g,h,i)perylene ug/L <2.8 5.0 05/23/23 18:432.8
Benzo(k)fluoranthene ug/L <2.7 5.0 05/23/23 18:432.7
bis(2-Chloroethoxy)methane ug/L <1.8 10.0 05/23/23 18:431.8
bis(2-Chloroethyl) ether ug/L <1.9 5.0 05/23/23 18:431.9
bis(2-Ethylhexyl)phthalate ug/L <3.7 5.0 05/23/23 18:433.7
Butylbenzylphthalate ug/L <3.1 5.0 05/23/23 18:433.1
Chrysene ug/L <2.8 5.0 05/23/23 18:432.8
Di-n-butylphthalate ug/L <2.2 5.0 05/23/23 18:432.2
Di-n-octylphthalate ug/L <3.9 5.0 05/23/23 18:433.9
Dibenz(a,h)anthracene ug/L <3.0 5.0 05/23/23 18:433.0
Diethylphthalate ug/L <2.0 5.0 05/23/23 18:432.0
Dimethylphthalate ug/L <2.1 5.0 05/23/23 18:432.1
Fluoranthene ug/L <2.2 5.0 05/23/23 18:432.2
Fluorene ug/L <2.1 5.0 05/23/23 18:432.1
Hexachloro-1,3-butadiene ug/L <1.8 5.0 05/23/23 18:431.8
Hexachlorobenzene ug/L <2.2 5.0 05/23/23 18:432.2
Hexachlorocyclopentadiene ug/L <1.6 10.0 05/23/23 18:431.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 4026278
Associated Lab Samples:92667997011
Matrix: Water
AnalyzedMDL
Hexachloroethane ug/L <1.4 5.0 05/23/23 18:431.4
Indeno(1,2,3-cd)pyrene ug/L <2.9 5.0 05/23/23 18:432.9
Isophorone ug/L <1.7 10.0 05/23/23 18:431.7
N-Nitroso-di-n-propylamine ug/L <1.3 5.0 05/23/23 18:431.3
N-Nitrosodimethylamine ug/L <1.9 5.0 05/23/23 18:431.9
N-Nitrosodiphenylamine ug/L <3.0 10.0 05/23/23 18:433.0
Naphthalene ug/L <2.1 5.0 05/23/23 18:432.1
Nitrobenzene ug/L <1.9 5.0 05/23/23 18:431.9
Pentachlorophenol ug/L <3.8 10.0 05/23/23 18:433.8
Phenanthrene ug/L <2.0 5.0 05/23/23 18:432.0
Phenol ug/L <1.4 5.0 05/23/23 18:431.4
Pyrene ug/L <2.2 5.0 05/23/23 18:432.2
2,4,6-Tribromophenol (S)%93 10-137 05/23/23 18:43
2-Fluorobiphenyl (S)%75 15-120 05/23/23 18:43
2-Fluorophenol (S)%62 10-120 05/23/23 18:43
Nitrobenzene-d5 (S)%78 10-120 05/23/23 18:43
Phenol-d6 (S)%51 10-120 05/23/23 18:43
Terphenyl-d14 (S)%90 11-131 05/23/23 18:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026279LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 5.7 L25011 44-142
2,2'-Oxybis(1-chloropropane)ug/L 24.950 50 36-166
2,4,6-Trichlorophenol ug/L 41.150 82 37-144
2,4-Dichlorophenol ug/L 38.850 78 1-191
2,4-Dimethylphenol ug/L 57.850 116 32-119
2,4-Dinitrophenol ug/L 255250 102 1-181
2,4-Dinitrotoluene ug/L 42.550 85 39-139
2,6-Dinitrotoluene ug/L 42.250 84 50-158
2-Chloronaphthalene ug/L 18.6 L25037 60-118
2-Chlorophenol ug/L 31.350 63 23-134
2-Nitrophenol ug/L 37.050 74 29-182
3,3'-Dichlorobenzidine ug/L 68.3100 68 1-262
4,6-Dinitro-2-methylphenol ug/L 98.4100 98 1-181
4-Bromophenylphenyl ether ug/L 39.350 79 53-127
4-Chloro-3-methylphenol ug/L 81.3100 81 22-147
4-Chlorophenylphenyl ether ug/L 36.250 72 25-158
4-Nitrophenol ug/L 133250 53 1-132
Acenaphthene ug/L 28.750 57 47-145
Acenaphthylene ug/L 27.650 55 33-145
Anthracene ug/L 36.550 73 1-166
Benzo(a)anthracene ug/L 41.150 82 33-143
Benzo(a)pyrene ug/L 40.450 81 17-163
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4026279LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 43.050 86 24-159
Benzo(g,h,i)perylene ug/L 36.850 74 1-219
Benzo(k)fluoranthene ug/L 42.550 85 11-162
bis(2-Chloroethoxy)methane ug/L 36.450 73 33-184
bis(2-Chloroethyl) ether ug/L 29.950 60 12-158
bis(2-Ethylhexyl)phthalate ug/L 44.750 89 8-158
Butylbenzylphthalate ug/L 46.550 93 1-152
Chrysene ug/L 40.450 81 17-168
Di-n-butylphthalate ug/L 43.350 87 1-118
Di-n-octylphthalate ug/L 45.650 91 4-146
Dibenz(a,h)anthracene ug/L 38.850 78 1-227
Diethylphthalate ug/L 40.850 82 1-114
Dimethylphthalate ug/L 39.750 79 1-112
Fluoranthene ug/L 42.850 86 26-137
Fluorene ug/L 37.350 75 59-121
Hexachloro-1,3-butadiene ug/L 3.0J L2506 24-116
Hexachlorobenzene ug/L 38.950 78 1-152
Hexachlorocyclopentadiene ug/L 5.6J L25011 25-150
Hexachloroethane ug/L 2.7J L2505 40-113
Indeno(1,2,3-cd)pyrene ug/L 38.650 77 1-171
Isophorone ug/L 39.850 80 21-196
N-Nitroso-di-n-propylamine ug/L 37.650 75 1-230
N-Nitrosodimethylamine ug/L 29.550 59 25-150
N-Nitrosodiphenylamine ug/L 36.650 73 25-150
Naphthalene ug/L 11.050 22 21-133
Nitrobenzene ug/L 29.950 60 35-180
Pentachlorophenol ug/L 91.0100 91 14-176
Phenanthrene ug/L 39.050 78 54-120
Phenol ug/L 22.550 45 5-112
Pyrene ug/L 42.650 85 52-115
2,4,6-Tribromophenol (S)%70 10-137
2-Fluorobiphenyl (S)%43 15-120
2-Fluorophenol (S)%40 10-120
Nitrobenzene-d5 (S)%55 10-120
Phenol-d6 (S)%35 10-120
Terphenyl-d14 (S)%71 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026280MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35800474001
4026281
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L M0,R1501644-14211 31 30501.7U 7.8 5.7
2,2'-Oxybis(1-
chloropropane)ug/L 50 41 36-16638 6 30501.2U 20.5 19.2
2,4,6-Trichlorophenol ug/L 50 60 37-14460 1 30501.6U 30.0 30.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026280MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35800474001
4026281
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L 50 61 1-19158 5 30501.4U 30.7 29.1
2,4-Dimethylphenol ug/L 50 94 32-119100 6 30501.7U 47.2 50.0
2,4-Dinitrophenol ug/L 250 95 1-18194 2 3025026.0U 238 234
2,4-Dinitrotoluene ug/L 50 83 39-13983 0 30501.6U 41.6 41.7
2,6-Dinitrotoluene ug/L 50 67 50-15864 4 30501.7U 33.4 32.2
2-Chloronaphthalene ug/L M0503260-11830 4 30501.7U 15.9 15.2
2-Chlorophenol ug/L 50 58 23-13457 0 30501.2U 28.8 28.7
2-Nitrophenol ug/L 50 72 29-18269 5 30501.4U 35.9 34.3
3,3'-Dichlorobenzidine ug/L 100 3 1-2628 301008.1U <8.1 <8.1
4,6-Dinitro-2-methylphenol ug/L 100 107 1-181106 1 301007.8U 107 106
4-Bromophenylphenyl ether ug/L 50 62 53-12760 3 30501.8U 31.1 30.1
4-Chloro-3-methylphenol ug/L 100 67 22-14764 5 301003.3U 67.2 64.2
4-Chlorophenylphenyl ether ug/L 50 51 25-15848 5 30502.0U 25.4 24.2
4-Nitrophenol ug/L 250 70 1-13270 0 302506.6U 174 175
Acenaphthene ug/L M1504547-14542 6 30502.0U 22.4 21.1
Acenaphthylene ug/L 50 43 33-14541 5 30502.0U 21.5 20.4
Anthracene ug/L 50 73 1-16673 0 30502.3U 36.6 36.7
Benzo(a)anthracene ug/L 50 96 33-14395 1 30502.7U 47.9 47.6
Benzo(a)pyrene ug/L 50 94 17-16391 4 30502.8U 47.2 45.6
Benzo(b)fluoranthene ug/L 50 103 24-15992 11 30502.6U 51.6 46.1
Benzo(g,h,i)perylene ug/L 50 96 1-21990 7 30502.8U 48.1 45.0
Benzo(k)fluoranthene ug/L 50 101 11-16295 6 30502.7U 50.3 47.5
bis(2-
Chloroethoxy)methane ug/L 50 61 33-18458 5 30501.8U 30.5 28.9
bis(2-Chloroethyl) ether ug/L 50 60 12-15861 2 30501.9U 29.8 30.3
bis(2-Ethylhexyl)phthalate ug/L 50 110 8-158110 0 30503.7U 54.9 54.8
Butylbenzylphthalate ug/L 50 115 1-152117 2 30503.1U 57.4 58.6
Chrysene ug/L 50 102 17-168102 0 30502.8U 51.2 51.1
Di-n-butylphthalate ug/L 50 100 1-118100 0 30502.2U 50.1 49.9
Di-n-octylphthalate ug/L 50 115 4-146112 2 30503.9U 57.4 56.0
Dibenz(a,h)anthracene ug/L 50 98 1-22791 7 30503.0U 49.2 45.6
Diethylphthalate ug/L 50 76 1-11474 2 30502.0U 37.8 37.1
Dimethylphthalate ug/L 50 58 1-11260 2 30502.1U 29.1 29.8
Fluoranthene ug/L 50 97 26-13795 2 30502.2U 48.5 47.5
Fluorene ug/L M1505359-12154 1 30502.1U 26.6 26.8
Hexachloro-1,3-butadiene ug/L M0501324-1169 30501.8U 6.7 4.5J
Hexachlorobenzene ug/L 50 68 1-15262 8 30502.2U 33.8 31.1
Hexachlorocyclopentadiene ug/L M0501425-15011 30501.6U 7.2J 5.3J
Hexachloroethane ug/L M0,R1501640-11311 37 30501.4U 8.1 5.6
Indeno(1,2,3-cd)pyrene ug/L 50 96 1-17190 6 30502.9U 47.9 44.9
Isophorone ug/L 50 67 21-19662 7 30501.7U 33.3 31.0
N-Nitroso-di-n-propylamine ug/L 50 66 1-23063 6 30501.3U 33.2 31.4
N-Nitrosodimethylamine ug/L 50 59 25-15058 2 30501.9U 29.4 28.8
N-Nitrosodiphenylamine ug/L 50 78 25-15077 2 30503.0U 39.2 38.3
Naphthalene ug/L M1502321-13318 21 30502.1U 11.3 9.2
Nitrobenzene ug/L 50 86 35-18078 9 30501.9U 43.0 39.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4026280MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35800474001
4026281
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L 100 101 14-17697 4 301003.8U 101 97.0
Phenanthrene ug/L 50 81 54-12078 4 30502.0U 40.6 39.1
Phenol ug/L 50 46 5-11244 5 30501.4U 23.2 22.1
Pyrene ug/L 50 102 52-115103 1 30502.2U 50.8 51.4
2,4,6-Tribromophenol (S) %70 10-13759
2-Fluorobiphenyl (S)%33 15-12028
2-Fluorophenol (S)%39 10-12035
Nitrobenzene-d5 (S)%50 10-12044
Phenol-d6 (S)%34 10-12029
Terphenyl-d14 (S)%91 11-13184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Re-extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.1g
Analyte was detected in the associated method blank.B
Result confirmed by second analysis.C0
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the
calculated result.MS
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
RPD value was outside control limits.R1
The RPD value in one of the constituent analytes was outside the control limits.RS
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92667997
16457 Stephen’s Exxon
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92667997005 775237 775583MW-11 EPA 625.1 EPA 625.1
92667997007 775237 775583MW-13 EPA 625.1 EPA 625.1
92667997010 775237 775583AS-1 EPA 625.1 EPA 625.1
92667997011 776032 776460WSW-8 EPA 625.1 EPA 625.1
92667997001 776133MW-2 SM 6200B
92667997002 776135MW-3 SM 6200B
92667997003 775965MW-5R SM 6200B
92667997004 776135MW-7 SM 6200B
92667997005 776135MW-11 SM 6200B
92667997006 776135MW-12 SM 6200B
92667997007 775917MW-13 SM 6200B
92667997008 775917MW-14 SM 6200B
92667997009 775917MW-16 SM 6200B
92667997010 776135AS-1 SM 6200B
92667997011 775942WSW-8 SM 6200B
92667997012 776135MW-17 SM 6200B
92667997013 776135FB-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/25/2023 01:49 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 75
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