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HomeMy WebLinkAbout4501_Henderson_MSWLF_CDLF_March23GW_FID1812417_20230728*ER USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form oU� form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): WSP USA Inc. on behalf of Henderson County Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Benjamin S. Draper, PG, PMP Phone: 336-852-4903 E-mail: benjamin.draper@wsp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Henderson County Closed Landfill 191 Transfer Station Drive 45-01 .1600/.0500 March 20 - 22, 2023 Hendersonville, NC 28791 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring a Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑X Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) MNA Monitoring Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Benjamin S. Draper, PG, PMP Assistant Vice President, Geologist 336-852-4903 Facility Title (Area Code) Telephone 4V z 6 Z3 Affix ze Date WSP USA Inc., 5B Oak Branch Drive, Greensboro, NC 27407 Facility Representative Address PG (C-557) / PE (F-0165) 67 J(, -2 ist Seal NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 �ffl REPORT First Semi -Annual 2023 Water Quality and Corrective Action Monitoring Report Closed Henderson County Landfill, Permit No. 45-01 Submitted to: Henderson County Solid Waste Division 191 Transfer Station Drive Stoney Mountain Drive Hendersonville, North Carolina 28791 Submitted by: \AIL+n 1 IL- A I. July 28, 2023 Distribution List GI-2014715721.102 Jaclynne Drummond, Hydrogeologist, Department of Environmental Quality, Division of Waste Management — Solid Waste Section, 2090 US Highway 70, Swannanoa, NC 28778. 828-296-4706. jaclynne.drummond@ncdenr.gov Marcus Jones, PE, Director of Engineering, Henderson County, 1 Historic Courthouse Square, Suite 6, Hendersonville, NC 28792. 828-694-6560. majones@hendersoncountync.org (electronic copy) Greg Wiggins, Director of Solid Waste Department, 191 Transfer Station Drive, Hendersonville, NC 28791. 828- 707-6232. gwiggins@hendersoncountync.org July 28, 2023 GL2014715721.102 EXECUTIVE SUMMARY On behalf of Henderson County, WSP USA Inc. (WSP), formerly Golder Associates NC, Inc. (Golder), is submitting this Water Quality Monitoring Report, which documents the results of the compliance monitoring and corrective action monitoring results from the March 20-22, 2023 water quality sampling event at the closed Henderson County landfill (the Site). The Site consists of a closed municipal solid waste (MSW) which is monitored under 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .1632 through .1636 and a closed construction and demolition (C&D) landfill which is monitored in accordance with 15A NCAC 13B .0545. Closed MSW Landfill Two (2) inorganic constituents, cobalt and mercury, were detected at concentrations above the laboratory quantitation limit (i.e., PQL) and the NC 2L Standard in samples collected from the MSW compliance monitoring well, MW-8, during the March 2023 sampling event. The statistically derived site -specific groundwater protection standard (GPS) of 24 ug/L was previously proposed for cobalt. The concentrations of cobalt observed in monitoring well, MW-8 (14.4 ug/L), were below this proposed GPS. The concentrations of mercury in monitoring well, MW-8, will be confirmed during the next sampling event. Mercury has historically been detected at similar concentrations in samples collected from MW-8 and in other monitoring wells at the site. One (1) inorganic constituent, cobalt, was also detected in compliance monitoring wells, MW-6, MW-7, and AMW- 1S, at estimated concentrations below the PQL but above the NC 2L Standard at the closed MSW landfill during the March 2023 sampling event, as it has been historically. Per 15A NCAC 02L .0202 (b)(1), "where the standard (i.e., the NC 2L Standard) for a substance is less than the practical quantitation limit (PQL), the detection of that substance at or above the PQL constitutes a violation of the standard." The NC 2L Standard for cobalt is 1 microgram per liter (ug/L) and the PQL is 10 ug/L. As presented, the estimated concentrations of cobalt mentioned above were reported below the PQL, therefore; no further action is warranted at this time. Additionally, a desktop study using the United State Geological Survey (USGS) National Geochemical Survey Database researched the prevalence of cobalt in soil and sediment in the general proximity of the Henderson County MSW Landfill was presented in the First Semi -Annual 2019 Water Quality and Corrective Action Monitoring Report dated July 15, 2019. The desktop study suggested that cobalt occurs naturally in stream sediment and is likely to occur in subsurface soil at the Henderson County landfill at concentrations similar to the concentrations currently observed in groundwater. Based on this data, the exceedance of cobalt observed in groundwater at the C&D landfill is believed to originate from the natural soils and rock at the site. Two (2) NC Appendix I listed organic constituents, the volatile organic compounds (VOCs), benzene and 1,4- dichlorobenzene, were detected at quantifiable concentrations above the NC 2L Standards in the samples collected from one or more downgradient well at the closed MSW landfill during the March 2023 sampling event. Benzene was detected at quantifiable concentration above the NC 2L Standard in samples collected from AMW 1D and 1,4-dichlorobenzene was detected in samples collected from MW-7. Two (2) NC Appendix I listed constituents, benzene and vinyl chloride, were also detected in samples collected from one or more downgradient monitoring wells at estimated concentrations below the PQL but above the NC 2L Standard during this event. Benzene was detected in samples collected from MW-6 and vinyl chloride was detected in samples collected from MW-7. The constituent, 1,4 dioxane, was detected at quantifiable concentrations above the NC 2L Standard in the samples collected from MW-6, MW-7, and AMW-1 D during the March 2023 sampling event. The constituent, July 28, 2023 GL2014715721.102 1,4 dioxane, was analyzed per the May 29, 2018 memorandum from the NC Department of Environmental Quality (DEQ) and is not currently part of the approved Water Quality Monitoring Plan (WQMP). One (1) NC Appendix II listed semi -volatile organic compound (SVOC), heptachlor epoxide, was detected at an estimated concentration above the NC 2L Standard in samples collected from monitoring well MW-7. This detection denotes the first detection of heptachlor epoxide in samples collected from MW-7 and in samples collected at this site. This detection will be verified during the next sampling event. Closed C&D Landfill No NC Appendix I inorganic constituents were reported at concentrations above the PQLs and the NC 2L Standards in the samples collected from downgradient monitoring wells during the March 2023 sampling event. Cobalt was detected in samples collected from MW-11 and MW-13 at estimated concentrations above the NC 2L Standard during the March 2023 sampling event. Per 15A NCAC 02L .0202 (b)(1), no further action is warranted at this time. Three (3) indicator parameters, iron, manganese, and total dissolved solids (TDS), were detected at quantifiable concentrations above the NC 2L Standard in samples collected from one or more downgradient monitoring wells during the March 2023 sampling event. Iron was reported at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring wells MW-11 and MW-13. Manganese was reported at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring wells MW-11, MW-12, and MW-13. The concentration of manganese in samples collected from monitoring well MW-11 (7,660 ug/L) also exceeded the proposed site -specific groundwater protection standard of (7,254 ug/L). TDS was reported at a quantifiable concentration above the NC 2L Standard in samples collected from the downgradient monitoring well MW-11 as it has been previously. The concentrations of these indicator parameters are believed to be naturally occurring and are similar to historical results for C&D facility monitoring wells. A desktop study of the prevalence of cobalt, iron, and manganese in soil and sediment in the general proximity of the Henderson County MSW Landfill using the USGS National Geochemical Survey Database was presented in the First Semi -Annual 2019 Water Quality and Corrective Action Monitoring Report dated July 15, 2019. The study showed that iron and manganese occur naturally in stream sediment and is likely to occur in subsurface soil at the Henderson County MSW Landfill at concentrations that would account for the concentrations of these constituents observed in groundwater. Therefore, the aforementioned exceedances likely originate from natural soils and rock. One (1) NC Appendix I listed organic constituent, vinyl chloride, was detected at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring well MW-12 at the C&D landfill during the March 2023 sampling event. Vinyl chloride was also detected at an estimated concertation above the NC 2L Standard in samples collected from the downgradient well MW-13 during the March 2023 sampling event at the closed C&D landfill, as it has been historically. The organic constituent, 1,4 dioxane, was detected at a quantifiable concentration above the NC 2L Standard in the samples collected from MW-13, as it has been historically. As presented, 1,4-dioxane, was analyzed per the May 29, 2018 memorandum from the NC Department of Environmental Quality (DEQ) and is not currently part of the approved monitoring plan. Surface Water No NC Appendix I organic or inorganic constituents were detected at quantifiable concentrations that exceeded applicable surface water standards in samples collected from the downgradient monitoring wells during the March July 28, 2023 GL2014715721.102 2023 sampling event. Two (2) inorganic constituents, cadmium and cobalt, were detected at estimated concentrations above applicable chronic surface water standards in samples collected from BR-2 and BR-3. Additionally, the constituent, 1,4-dioxane, was detected at a quantifiable concentration above the applicable surface water standard in the samples collected from BR-1, BR-2, BR-3, and SW-1, as it has been historically. Site -Specific Groundwater Protection Standards (GPS) Statistically calculated site -specific GPSs were previously proposed for select inorganic constituents and C&D indicator parameters. The following were the proposed GPSs for the MSW and C&D landfills: ■ Cobalt: 24.0 ug/L And, for the C&D landfill only: ■ Iron: 16,299 ug/L ■ Manganese: 7,254 ug/L ■ Sulfate:516 ■ TDS: 1,242 Per the email from NC DEQ dated January 13, 2023, approvals for site specific GPS have changed. Henderson County is still awaiting guidance from the Solid Waste Section to determine the best path forward with regards to site specific GPS for metals or other inorganic parameters Recommendations Due to the presence of VOCs above applicable groundwater standards, Henderson County will continue to monitor the uppermost aquifer beneath the MSW landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.1634. MNA monitoring events have been performed as outlined in the approved CAP. As presented, SAW pilot test injections are no longer required unless VOCs are detected above the NC 2L Standards in samples collected from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. As presented, benzene was detected at quantifiable concentrations above the NC 2L Standards in samples collected from AMW-1 D; however, there were quality concerns identified in the laboratory report with this sample. WSP proposes to verify this result during the next sampling event, tentatively scheduled for September 2023. As presented, one (1) NC Appendix I listed VOC, vinyl chloride, was detected at a quantifiable concentration above the NC 2L Standard in samples collected from the C&D downgradient monitoring well, MW-12 during the March 2023 sampling event. No NC Appendix I listed constituents were detected at concentrations above applicable surface water standards during the March 2023 sampling event. The indicator parameters iron, manganese, and TDS were detected at quantifiable concentrations exceeding the NC 2L Standards in one or more downgradient monitoring wells during the March 2023 monitoring event. With the exception of manganese, these constituents were all detected at concentrations below the previously proposed site -specific GPS. In response to the detections of manganese at concentrations exceeding the proposed site -specific GPS, the County plans to redevelop monitoring well MW-11 prior to the next sampling event. While the turbidity values of samples collected from MW-11 are relatively low (5-10 NTUs) the values are elevated when compared to the other downgradient monitoring wells (-1 NTU). July 28, 2023 GL2014715721.102 Based on the results summarized herein, the County will continue the implementation of groundwater corrective action at the MSW landfill in accordance with the approved CAP. The County will also continue monitoring the C&D landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.0545. The next compliance monitoring event for this facility is tentatively scheduled for September 2023. July 28, 2023 GL2014715721.102 Table of Contents EXECUTIVE SUMMARY 1.0 INTRODUCTION.............................................................................................................................................1 1.1 Site Description and Background.........................................................................................................1 1.2 Compliance Monitoring History............................................................................................................1 1.2.1 Closed MSW Landfill.......................................................................................................................2 1.2.2 Closed C&D Landfill........................................................................................................................3 1.3 Hydrogeologic Setting..........................................................................................................................3 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION.............................................................4 2.1 Visual Inspection Program...................................................................................................................4 2.2 Well Network and Groundwater Elevation Measurements..................................................................4 2.2.1 Closed MSW Landfill.......................................................................................................................4 2.2.2 Closed C&D Landfill........................................................................................................................5 2.2.3 Groundwater Elevation Measurements..........................................................................................5 2.3 March 2023 Water Quality Monitoring Event.......................................................................................5 2.4 Laboratory Analysis Program...............................................................................................................6 2.4.1 Closed MSW Landfill Compliance Monitoring.................................................................................6 2.4.2 Closed C&D Landfill Corrective Action Monitoring.........................................................................6 3.0 LABORATORY AND FIELD QA/QC..............................................................................................................6 4.0 DATA EVALUATION......................................................................................................................................7 4.1 North Carolina Groundwater and Surface Water Quality Standard Comparison for the Closed MSWLandfill........................................................................................................................................7 4.2 North Carolina Groundwater Standard Comparison for the Closed C&D Landfill...............................8 4.3 Summary of Proposed Site -Specific Groundwater Protection Standards............................................9 5.0 CORRECTIVE ACTION PERFORMANCE MONITORING..........................................................................10 5.1 Monitored Natural Attenuation...........................................................................................................10 5.1.1 Monitored Natural Attenuation Sampling Results.........................................................................10 5.1.2 Monitored Natural Attenuation Sampling Evaluation....................................................................10 xx"I) 5 July 28, 2023 GL2014715721.102 5.2 Super Aerated Water Pilot Test Sampling Results............................................................................11 6.0 CONCLUSIONS AND RECOMMENDATIONS............................................................................................11 7.0 REFERENCES..............................................................................................................................................12 TABLES Table 1 Summary of Historical Static Water Level Data Table 2 Summary of Estimated Horizontal Flow Velocities Table 3 Summary of Well Construction Information Table 4 Summary of Detected Constituents in MSW Monitoring Wells Table 5 Summary of Field Parameters for MSW Monitoring Wells Table 6 Summary of Detected Constituents in Surface Water Monitoring Points Table 7 Summary of Field Parameters for Surface Water Monitoring Points Table 8 Summary of Detected Constituents in C&D Monitoring Wells Table 9 Summary of Field Parameters for C&D Monitoring Wells Table 10 Summary of Geochemical Indicators Table 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points FIGURES Figure 1 Groundwater Surface Contour Map, March 20 - 22, 2023 APPENDICES Appendix A Groundwater and Surface Water Sampling Logs Appendix B March 2023 Water Quality Monitoring Certificates -of -Analysis, Chain -of -Custody Forms, and Laboratory Data Review Appendix C EPA Natural Attenuation Screening Protocol Forms and BIOCHLOR Monitored Natural Attenuation Analysis for March 2023 Sampling Event July 28, 2023 GL2014715721.102 1.0 INTRODUCTION This report summarizes the monitoring results from the March 20 — 22, 2023 water quality monitoring event at the closed Henderson County landfill (hereafter, referred to as the facility or the Site) in Henderson County, North Carolina (NC), NC solid waste permit no. 45-01 as issued by the NC Department of Environmental Quality (DEQ, formerly the Department of Environment and Natural Resources). The Henderson County landfill consists of a closed municipal solid waste (MSW) landfill which is monitored in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .1632 through .1636 and a closed construction and demolition (C&D) landfill which is monitored in accordance with 15A NCAC 13B .0545. 1.1 Site Description and Background The location of the facility is shown on the inlay on Figure 1. As presented, the closed Henderson County landfill is located approximately three (3) miles northwest of the city of Hendersonville, off of Stoney Mountain Road. The County maintains an approximately 120-acre landfill facility that consists of a closed unlined C&D landfill constructed over a MSW landfill; a closed unlined C&D facility; a closed unlined landfill formerly operated by the Tennessee Valley Authority (TVA); an active transfer station; and a convenience center for County residents. A white goods area, a yard waste disposal area, and a beneficial reuse area are also present on the property. Unpermitted waste was discovered along the eastern portion of the southern property boundary in 2011, during the construction of a road to the customer convenience center. The waste, which appears to consist of mainly C&D material, extends off -site to an adjacent parcel. The MSW landfill is subject to assessment monitoring with respect to water quality monitoring, which is performed in accordance with 15A NCAC 13B .1634 of the Solid Waste Management Rules (SWMR) and the Transition Plan for the facility. The C&D facility is subject to water quality monitoring in accordance with the January 1, 2007 revision to the C&D rules (.0544 and .0545 of the SWMR) and is currently in assessment monitoring. Water quality monitoring is also required for the adjacent TVA landfill. The facility has been in operation since the 1940s, beginning with the TVA landfill. In January 1998, the MSW landfill ceased accepting MSW waste and began placing C&D waste over the previously landfilled MSW waste. After closure of the C&D-over-MSW area, a new C&D landfill began operation on the southeastern portion of the facility property. For closure purposes, the C&D-over-MSW area was capped with a modified clay cap. The County ceased accepting waste at the stand-alone C&D landfill on June 30, 2008 and completed closure activities on June 30, 2009. The property is bounded to the north and east by residential and undeveloped wooded properties; to the south by Stoney Mountain Road, residential, and wooded properties; and to the west by a tributary of Mill Pond Creek, a NC Department of Transportation (DOT) maintenance yard, and a Henderson County School bus maintenance facility. Topographic relief at the landfill ranges from approximately 2170 to 2590 feet above mean sea level. Surface drainage from the facility is predominantly to the southwest toward several drainage features along the western and southern portions of the property. These features drain into Mill Pond Creek located southwest of the landfill. 1.2 Compliance Monitoring History The following sections summarize the compliance monitoring histories of the closed MSW landfill, the closed C&D landfill, and the closed TVA landfill. July 28, 2023 GL2014715721.102 1.2.1 Closed MSW Landfill Henderson County monitors water quality at the closed MSW landfill by sampling one (1) upgradient background monitoring well (MW-5), and three (3) downgradient monitoring wells (MW-6, MW-7, and MW-8) semi-annually. Samples from these wells have historically been analyzed for NC Appendix II listed constituents for the first semi- annual event and NC Appendix I listed constituents plus detects (e.g., mercury) during the second semi-annual event. Two (2) assessment monitoring wells (AMW-1 S and AMW-1 D) have also been monitored semi-annually since April 2002. Samples collected from the assessment wells have historically been analyzed for NC Appendix I listed constituents plus detects (e.g., mercury) during each semi-annual event. Based on the documented exceedances of applicable groundwater standards for volatile organic compounds (VOCs), the County submitted an Additional Groundwater Assessment Proposed Work Plan (Work Plan) to NC DEQ on September 26, 2008. NC DEQ approved the Work Plan on April 17, 2008, and the County submitted the Assessment Report on June 3, 2008. As part of the Assessment Report, assessment monitoring wells AMW-2S and AMW-2D were installed to further delineate the VOC plume. As part of this submittal, Camp Dresser & McKee (CDM) recommended that AMW-2S and AMW-2D continue to be sampled semi-annually. On September 17, 2009, representatives of the County and WSP USA Inc. (WSP), formerly known as Golder Associates NC, Inc. (Golder), met with NC DEQ and submitted a Groundwater Assessment Work Plan to NC DEQ to address continued assessment activities at the MSW and C&D facilities. During the meeting, it was verbally agreed that TVA well MW-9 would no longer be sampled and would remain for water level collection, and wells AMW-1 S, AMW-1 D, AMW-2S, and AMW-2D would be sampled for NC Appendix I listed constituents plus mercury. Follow-up emails were received on September 18, 2009 regarding approval to discontinue monitoring MW-9, and on February 2, 2010, regarding approval of reduced analytical parameters for the four (4) assessment monitoring wells. In a letter to the County dated May 12, 2011, NC DEQ requested that MW-9 be sampled on an annual basis for NC Appendix I constituents to monitor the closed TVA landfill; currently the well is sampled during the first semi-annual compliance event of each year. Four (4) downstream surface water monitoring locations BR-1, BR-2, BR-3, and SW-1 are also monitored semi-annually for NC Appendix I listed constituents. In July 2012, Henderson County submitted a Nature and Extent Study (NES) to NC DEQ with the purpose of delineating the vertical and horizontal extent of those constituents identified in the groundwater samples at concentrations above their respective groundwater standards. NC DEQ granted approval of the NES on October 18, 2012. The October 18, 2012, approval letter of the NES required the County to initiate an assessment of corrective measures (ACM) per the 15A NCAC 13B .1635 of the NC SWMR. An ACM was submitted to the NC DEQ on April 15, 2013. The ACM was approved by NC DEQ on May 22, 2013, and the County held a public hearing to discuss the ACM and potential remedies for the site on August 15, 2013. A Corrective Action Plan (CAP) was submitted to the NC DEQ on June 24, 2015 and was approved on July 13, 2015. As specified in the CAP, monitored natural attenuation (MNA) was implemented as the corrective action remedy along with a super aerated water (SAW) pilot test in the southwestern portion of the facility. A detailed description of the MNA remedy and required sampling parameters can be found in Section 2.4.2 of this report. A Corrective Action Evaluation Report (CAER) for the SAW pilot test was submitted to NC DEQ on October 25, 2019. The 2019 CAER proposed that methylene chloride be removed as a constituent of concern (COC) and that SAW injections cease unless VOCs are detected at concentrations above the NC 2L Groundwater Standard (NC 2L Standard) in samples collected from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. The 2019 CAER was approved by the NC DEQ on November 5, 2019. July 28, 2023 GL2014715721.102 A CAER for the MNA program was submitted to NC DEQ on September 4, 2020. The 2020 CAER proposed that tetrachloroethene and trichloroethene be removed as COCs. The 2020 CAER was approved by the NC DEQ on September 9, 2020. 1.2.2 Closed C&D Landfill The County monitors water quality at the C&D facility by sampling one (1) upgradient monitoring well (MW-10), and three (3) downgradient monitoring wells (MW-11, MW-12, and MW-13) semi-annually. Samples collected from the monitoring wells have been analyzed for NC Appendix I listed constituents plus mercury and indicator parameters. On September 28, 2010, the County submitted an Alternate Source Demonstration (ASD) to NC DEQ in response to VOCs detected in samples collected from the closed C&D landfill downgradient monitoring wells. Based on the data and evaluations from the ASD, it was apparent that leachate from the C&D disposal unit is not the likely source of the VOC detections. Additionally, the data suggest that the source of VOCs in samples collected from downgradient monitoring wells is likely due to landfill gas. On May 12, 2011, NC DEQ issued a letter to the County to initiate an assessment monitoring program at the C&D facility. The County submitted an Assessment Monitoring Work Plan to NC DEQ on September 21, 2011 and sampled the C&D landfill monitoring wells for NC Appendix II listed constituents during the September 2011 sampling event. Prior to the September 2011 compliance monitoring event, NC DEQ allowed the County to sample the C&D monitoring wells for NC Appendix I listed constituents plus detected NC Appendix II constituents (e.g., 2,4-D) after conducting two baseline sampling events. 1.3 Hydrogeologic Setting Geologically, the facility is located within the Chauga Belt of the Blue Ridge Physiographic Province of NC (NCGS, 1985 and 2004). The Chauga Belt is comprised of Cambrian intrusive metamorphic rocks of monzonitic to granodioritic origin. The Chauga Belt is considered a low-grade metamorphic part of the Inner Piedmont Belt and is bordered to the west by the Brevard thrust fault zone. The facility is underlain primarily by the Henderson Gneiss which is a medium -gray, biotite granite augen composed of microcline, oligoclase, quartz, biotite, and minor amounts of muscovite, epidote, and titanite (Butler and Secor, 1991). The topography of the area is characterized by rolling, rounded hills with broad valleys and moderately steep ravines typically containing streams. The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, metamorphic intrusive rock. Topographic relief at the site ranges from an elevation of approximately 2590 feet above mean sea level (AMSL) along the eastern property boundary and slopes downward to the southwest to an approximate elevation of 2170 feet AMSL along the western property boundary. As a result of the varying topographic relief at the site, groundwater occurs at depths of ranging from approximately 6 to 55 feet below grade. Depth -to -water measurements obtained during the March 2023 monitoring event are summarized in Table 1 and were used to prepare a groundwater surface contour map presented as an overlay on Figure 1. As presented, the groundwater flow in the uppermost aquifer beneath the site is generally toward the southwest toward a tributary of Mill Pond Creek, which is located along the western property boundary of the site. The groundwater contour map and interpreted flow directions are generally consistent with historical groundwater contour maps and flow directions. Based on the March 2023 groundwater surface contour map, the average hydraulic gradient in the shallow aquifer underlying the MSW landfill was calculated to be approximately 0.08 foot per foot (Table 2). The hydraulic July 28, 2023 GL2014715721.102 gradient underlying the C&D landfill was calculated to be approximately 0.30 foot per foot (Table 2). A hydraulic conductivity of 1.26E-04 centimeters/second is used based on an average of previous hydraulic conductivities calculated for specific wells (CDM, October 2008). An estimated effective porosity of 0.15 was used for the shallow aquifer to represent a range from saprolite to fractured rock (CDM, December 2008). Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Ki Vgw n e The average estimated linear groundwater flow velocity under the MSW landfill is approximately 68 feet/year, which is generally consistent with previous estimates (Table 2). The average estimated linear groundwater flow velocity under the C&D landfill is approximately 259 feet/year (Table 2). The difference between the horizontal flow velocities under each unit is primarily due to hydraulic gradient. The range of groundwater flow is expected to vary depending on the hydrogeologic unit in which it occurs. However, the linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this equation represents a simplified value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that are likely present in the uppermost aquifer at the facility. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted during the March 2023 water quality monitoring event are discussed in the following sections. 2.1 Visual Inspection Program To detect a potential release as early as possible, a visual inspection program is utilized by sampling personnel at the closed Henderson County landfills. This program includes inspection for physical indicators such as potential water table mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible signs of leachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other change to the environment that may be due to the waste management unit. During the compliance monitoring event, no physical indicators of a potential releases were observed in the vicinity of the waste management units. 2.2 Well Network and Groundwater Elevation Measurements The following sections summarize the current water quality networks and groundwater elevation measurement procedure and historical results for the closed MSW landfill, the closed C&D landfill, and the closed TVA landfill. 2.2.1 Closed MSW Landfill As presented, the current compliance groundwater monitoring network at the closed Henderson County MSW landfill consists of one (1) upgradient monitoring well (MW-5) and three (3) downgradient monitoring wells (MW-6, MW-7, and MW-8). Four (4) assessment monitoring wells (AMW-1 S, AMW-1 D, AMW-2S, and AMW-2D) are also monitored during each semi-annual monitoring event. Four (4) surface water monitoring points (BR-1, BR-2, BR-3, and SW-1) are monitored semi-annually. Monitoring well and surface water point locations are shown on Figure 1. July 28, 2023 GL2014715721.102 In addition to the compliance monitoring, the following wells are sampled semi-annually as part of the corrective action MNA remedy: compliance monitoring wells MW-5, MW-6, MW-7, and MW-8; assessment wells AMW-1 S and AMW-2S; and the corrective action monitoring well Old MW-2. Monitoring wells MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 are screened in the shallow, unconfined aquifer while monitoring wells AMW-1 D and AMW-2D are screened in fractured bedrock. Available groundwater monitoring well construction information is summarized in Table 3. As presented, the TVA Well, MW-9, is sampled annually (during each first semi-annual event) to monitor groundwater downgradient of the closed TVA landfill. The well is screened in the shallow, unconfined aquifer. 2.2.2 Closed C&D Landfill As presented, the current groundwater monitoring network at the closed C&D landfill consists of one (1) upgradient monitoring well, MW-10, and three (3) downgradient monitoring wells MW-11, MW-12, and MW-13. Downgradient monitoring wells MW-10, MW-11, and MW-12 are screened in the shallow, unconfined aquifer. Monitoring well MW-13 is screened in fractured bedrock. The four (4) wells are screened to target the preferential flow path for groundwater underlying the closed C&D waste management unit 2.2.3 Groundwater Elevation Measurements Depth -to -water measurements were recorded to the nearest 0.01 foot with an electronic water -level indicator prior to initiating groundwater purging and sampling activities. A summary of the current and available historical water level elevations is presented in Table 1. As presented, the data indicate that the hydraulic head level in the uppermost aquifer beneath the facility is consistent, with temporal variation from the long-term average ranging from approximately 2 to 12 feet (plus or minus). As expected, the range in fluctuation is greatest in the upgradient wells MW-5 and MW-10, as these wells are located in groundwater recharge areas. The range of fluctuation in downgradient compliance wells, which are located closer to groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge boundary. 2.3 March 2023 Water Quality Monitoring Event Personnel from WSP visited the facility on March 20 - 22, 2023, to purge and sample the fourteen (14) monitoring wells (Old MW-2, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, MW-12, MW-13, AMW-1 S, AMW-1 D, AMW-2S, and AMW-2D) and to sample the four (4) surface water monitoring locations (BR-1, BR-2, BR-3, and SW-1). Monitoring wells were purged and sampled using dedicated bladder pumps and low flow sampling procedures. Measurements of pH, specific conductivity, turbidity, dissolved oxygen (DO), temperature, and oxidation reduction potential (ORP) were recorded after each flow cell volume during the purge with field -calibrated instruments to monitor for stabilization of water quality parameters. When possible, the purge rate was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to water, up to a maximum purge rate of approximately 500 milliliters per minute. Purging was continued until stabilization as defined in the monitoring plan was achieved for each field parameter. The groundwater samples were collected directly from the bladder pump discharge line in labeled, laboratory - supplied, pre -preserved sample containers after purging was completed. Each sample container was labeled with July 28, 2023 GL2014715721.102 the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The surface water samples were collected by lowering the sample containers into the stream flow with the opening facing away from the current flow, taking care to prevent the overflow of the sample containers and to minimize sample -induced turbidity. Measurements of temperature, pH, specific conductivity, DO, ORP, and turbidity were recorded during the collection of the surface water samples. After collection, the water quality samples were placed in a cooler on ice, under chain -of -custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling location, sampling method, field observations, and water quality measurements. 2.4 Laboratory Analysis Program The majority of the March 2023 water quality samples were shipped to Eurofins Raleigh, formerly Environmental Conservation Laboratories (ENCO), in Cary, NC under chain -of -custody control. The initial samples collected in March 2023 were received at the laboratory on March 21 and March 22, 2023, in good condition and properly preserved. Additional MNA groundwater samples collected from MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 were shipped to Pace Analytical Gulf Coast, LLC (Pace) of Baton Rouge, Louisiana (LA) under chain -of - custody control to be analyzed for ferrous iron and dissolved hydrogen. These samples were received at the laboratory on March 22, 23, and 24 2023, in good condition and properly preserved. 2.4.1 Closed MSW Landfill Compliance Monitoring As presented, groundwater samples collected from the compliance MSW monitoring wells were analyzed for NC Appendix I listed constituents. Samples collected from the assessment monitoring wells were analyzed for NC Appendix I listed constituents and the previously detected NC Appendix II constituent, mercury. Surface water samples were analyzed for NC Appendix I listed constituents. In accordance with the May 29, 2018 memorandum from NC DEQ, all groundwater and surface water samples were also analyzed for 1,4 dioxane. 2.4.2 Closed C&D Landfill Corrective Action Monitoring Groundwater samples from the MNA monitoring wells MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 were also analyzed for the MNA parameters which included nitrate, nitrite, ferrous iron, sulfate, sulfide, alkalinity, chloride, methane, ethane, ethene, carbon dioxide, and hydrogen. The samples collected from Old MW-2 were also analyzed for the COCs identified in the CAP, which include benzene; 1,4-dichlorobenzene; 1,1- dichloroethane; and vinyl chloride. 3.0 LABORATORY AND FIELD QA/QC A field blank was collected by WSP personnel as part of the March 2023 water quality monitoring event. In addition to the field blank, laboratory -prepared trip blanks accompanied the volatile sample containers for the March 2023 sampling event to and from the laboratory. Eurofins Raleigh analyzed the field blank for NC Appendix I listed constituents plus: iron; manganese; 1,4-dioxane, and tetrahydrofuran. The trip blanks were analyzed for NC Appendix I VOCs plus: tetrahydrofuran; and 1,4-dioxane. %%%p July 28, 2023 GL2014715721.102 Reviews of the laboratory data were performed by WSP and are included with the Certificates -of -Laboratory Analysis included in Appendix B. Based on WSP's review of the laboratory data, estimated concentrations of acetone, beryllium, chloroform, cyanide, and methylene chloride were detected in the field blank. Estimated concentrations of chloroform and methylene chloride were also observed in the trip blank. Additionally, estimated concentrations of beryllium, chloroform, cis- 1,2-dichloroethene, hexachlorobutadiene, 1,2,4-trichlorobenzene, and methylene chloride were observed in one or more of the laboratory method blanks. Due to the blank detections summarized above, the following detections were flagged as blank qualified in samples collected from various compliance and/or assessment monitoring locations. Blank qualifications were determined by examining the concentrations of the target analytes in the blank and multiplying the concentrations by five or by ten for common laboratory contaminants (e.g., acetone, methylene chloride, etc.). Beryllium detected in samples collected from MW-6, MW-7, MW-9, MW-10, MW-11, MW-12, MW-13, MW-15, AMW-1S, AMW-1D, AMW-2S, AMW-2D, BR-1, BR-2, BR-3, and SW-1 were blank qualified. Chloroform detected in samples collected from BR-1, BR-2, BR-3, and SW-1 were blank qualified. Cis-1,2-dichloroethene detected in samples collected from MW-11, MW-12, AMW-1 D, and AMW-2S were blank qualified. Methylene chloride detected in samples collected from MW-7, MW-9, AMW-2S, BR-2, and BR-3 were blank qualified. Cyanide detected in samples collected from MW-5, MW-6, MW-7, and MW-8 were also blank qualified. 4.0 DATA EVALUATION The results of the reported analytical results and evaluations are presented in the following sections. 4.1 North Carolina Groundwater and Surface Water Quality Standard Comparison for the Closed MSW Landfill The results of the March 2023 water quality monitoring event at the closed MSW landfill are summarized in Table 4. Two (2) inorganic constituents, cobalt and mercury, were detected at concentrations above the laboratory quantitation limit (i.e., PQL) and the NC 2L Standard in samples collected from the compliance monitoring well, MW-8, during the March 2023 sampling event. One (1) inorganic constituent, cobalt, was also detected in compliance monitoring wells, MW-6, MW-7, and AMW-1 S, at estimated concentrations below the PQL but above the NC 2L Standard at the closed MSW landfill during the March 2023 sampling event, as it has been historically. Per 15A NCAC 02L .0202 (b)(1), "where the standard (i.e., the NC 2L Standard) for a substance is less than the practical quantitation limit (PQL), the detection of that substance at or above the PQL constitutes a violation of the standard." The NC 2L Standard for cobalt is 1 microgram per liter (ug/L) and the PQL is 10 ug/L. As presented, the estimated concentrations of cobalt mentioned above were reported below the PQL, therefore; no further action is warranted at this time. As detailed in Section 4.3 below, the statistically derived site -specific groundwater protection standard (GPS) of 24 ug/L was previously proposed for cobalt. The concentrations of cobalt observed in monitoring well, MW-8 (14.4 ug/L), were below this proposed GPS. The concentrations of mercury in monitoring well, MW-8, will be confirmed during the next sampling event. Mercury has historically been detected at similar concentrations in samples collected from MW-8 and in other monitoring wells at the site. A desktop study using the United State Geological Survey (USGS) National Geochemical Survey Database researched the prevalence of cobalt in soil and sediment in the general proximity of the Henderson County MSW Landfill was presented in the First Semi -Annual 2019 Water Quality and Corrective Action Monitoring Report dated July 15, 2019. The desktop study suggested that cobalt occurs naturally in stream sediment and is likely to occur in subsurface soil at the Henderson County landfill at concentrations similar to the concentrations currently July 28, 2023 GL2014715721.102 observed in groundwater. Based on this data, the exceedance of cobalt observed in groundwater at the MSW landfill is believed to originate from the natural soils and rock at the site. Two (2) NC Appendix I listed organic constituents, the volatile organic compounds (VOCs), benzene and 1,4- dichlorobenzene, were detected at quantifiable concentrations above the NC 2L Standards in the samples collected from one or more downgradient well at the closed MSW landfill during the March 2023 sampling event. Benzene was detected at quantifiable concentration above the NC 2L Standard in samples collected from AMW-1 D and 1,4-dichlorobenzene was detected in samples collected from MW-7. Two (2) NC Appendix I listed constituents, benzene and vinyl chloride, were also detected in samples collected from one or more downgradient monitoring wells at estimated concentrations below the PQL but above the NC 2L Standard during this event. Benzene was detected in samples collected from MW-6 and vinyl chloride was detected in samples collected from MW-7. The constituent, 1,4 dioxane, was detected at quantifiable concentrations above the NC 2L Standard in the samples collected from MW-6, MW-7, and AMW-1 D during the March 2023 sampling event. The constituent, 1,4-dioxane, was analyzed per the May 29, 2018 memorandum from the NC Department of Environmental Quality (DEQ) and is not currently part of the approved Water Quality Monitoring Plan (WQMP). One (1) NC Appendix II listed semi -volatile organic compound (SVOC), heptachlor epoxide, was detected at an estimated concentration above the NC 2L Standard in samples collected from monitoring well MW-7. This detection denotes the first detection of heptachlor epoxide in samples collected from MW-7 and in samples collected at this site. This detection will be verified during the next sampling event As presented in Table 6, no NC Appendix I organic or inorganic constituents were detected at quantifiable concentrations that exceeded applicable surface water standards in samples collected from the downgradient monitoring wells during the March 2023 sampling event. Two (2) inorganic constituents, cadmium and cobalt, were detected at estimated concentrations above applicable chronic surface water standards in samples collected from BR-2 and BR-3. Additionally, the constituent, 1,4-dioxane, was detected at a quantifiable concentration above the applicable surface water standard in the samples collected from BR-1, BR-2, BR-3, and SW-1, as it has been historically. 4.2 North Carolina Groundwater Standard Comparison for the Closed C&D Landfill As presented in Table 8, no NC Appendix I inorganic constituents were reported at concentrations above the PQLs and the NC 2L Standards in the samples collected from downgradient monitoring wells during the March 2023 sampling event. Cobalt was detected in samples collected from MW-11 and MW-13 at estimated concentrations above the NC 2L Standard during the March 2023 sampling event. Per 15A NCAC 02L .0202 (b)(1), no further action is warranted at this time. Three (3) indicator parameters, iron, manganese, and total dissolved solids (TDS), were detected at quantifiable concentrations above the NC 2L Standard in samples collected from one or more downgradient monitoring wells during the March 2023 sampling event. Iron was reported at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring wells MW-11 and MW-13. Manganese was reported at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring wells MW 11, MW-12, and MW-13. The concentration of manganese in samples collected from monitoring well MW-11 (7,660 ug/L) also exceeded the proposed site -specific groundwater protection standard of (7,254 ug/L). TDS was reported at a quantifiable concentration above the NC 2L Standard in samples collected from the July 28, 2023 GL2014715721.102 downgradient monitoring well MW-11 as it has been previously. The concentrations of these indicator parameters are believed to be naturally occurring and are similar to historical results for C&D facility monitoring wells. A desktop study of the prevalence of cobalt, iron, and manganese in soil and sediment in the general proximity of the Henderson County MSW Landfill using the USGS National Geochemical Survey Database was presented in the First Semi -Annual 2019 Water Quality and Corrective Action Monitoring Report dated July 15, 2019. The study showed that iron and manganese occur naturally in stream sediment and is likely to occur in subsurface soil at the Henderson County MSW Landfill at concentrations that would account for the concentrations of these constituents observed in groundwater. Therefore, the aforementioned exceedances likely originate from natural soils and rock. As presented in Table 8, one (1) NC Appendix I listed organic constituent, vinyl chloride, was detected at a quantifiable concentration above the NC 2L Standard in samples collected from downgradient monitoring well MW-12 at the C&D landfill during the March 2023 sampling event. Vinyl chloride was also detected at an estimated concertation above the NC 2L Standard in samples collected from the downgradient wells MW-13 during the March 2023 sampling event at the closed C&D landfill, as it has been historically. The organic constituent, 1,4 dioxane, was detected at a quantifiable concentration above the NC 2L Standard in the samples collected from MW-13, as it has been historically. As presented, 1,4-dioxane, was analyzed per the May 29, 2018 memorandum from the NC Department of Environmental Quality (DEQ) and is not currently part of the approved monitoring plan. 4.3 Summary of Proposed Site -Specific Groundwater Protection Standards Statistically calculated site -specific GPSs were previously proposed for select inorganic constituents and C&D indicator parameters. The following were the proposed GPSs for the MSW and C&D landfills: ■ Cobalt: 24.0 ug/L And, for the C&D landfill: ■ Iron: 16,299 ug/L ■ Manganese: 7,254 ug/L ■ Sulfate: 516 mg/L ■ TDS: 1,242 mg/L Per the email from NC DEQ dated January 13, 2023, approvals for site specific GPS have changed. Henderson County is still awaiting guidance from the Solid Waste Section to determine the best path forward with regards to site specific GPS for metals or other inorganic parameters. Based on these results, the County will continue the implementation of groundwater corrective action at the MSW landfill for the unconsolidated aquifer in accordance with the approved Corrective Action Plan. Also based on the results, the County will continue monitoring the C&D landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.0545. July 28, 2023 GL2014715721.102 5.0 CORRECTIVE ACTION PERFORMANCE MONITORING A Corrective Action Performance Monitoring Plan (CAPMP) was approved as part of the CAP by the NC DEQ on July 13, 2015. Per the CAPMP, MNA background sampling began during the September 2015 semi-annual water quality event and the sixteenth MNA background event was performed during the March 2023 semi-annual water quality event. A request to modify the MNA parameter list was submitted to the NC DEQ on July 26, 2017 and was approved on September 19, 2017. The modified MNA list consists of sampling alkalinity, carbon dioxide, chloride, ethane, ethene, methane, hydrogen, ferrous iron, nitrate, and sulfate semi-annually. Additionally, biological oxygen demand (BOD), chemical oxygen demand (COD), nitrite, sulfide, total organic carbon (TOC), and volatile fatty acids (VFAs) are sampled semi-annually every three years and were during the September 2022 and March 2023 sampling events. A CAER for the MNA program was submitted to the NC DEQ on September 4, 2020. The 2020 CAER proposed that tetrachloroethene and trichloroethene be removed as COCs. The 2020 CAER was approved by the NC DEQ on September 9, 2020. A CAER for the SAW pilot test was submitted to the NC DEQ on October 25, 2019. The CAER proposed that methylene chloride be removed as a COC and that SAW injections cease unless VOCs are detected above the NC 2L Standard in samples from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. The CAER was approved by the NC DEQ on November 5, 2019. 5.1 Monitored Natural Attenuation The MNA sampling results and evaluation are described below. 5.1.1 Monitored Natural Attenuation Sampling Results During the March 2023 event, the samples from MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 were analyzed for the modified MNA parameter summarized above. A summary of the MNA parameters is included as Table 10 and the certificates -of -analyses are included in Appendix B. The sample from Old MW-2 was also analyzed for the revised COC list, which include benzene; 1,4- dichlorobenzene; 1, 1 -dichloroethane; and vinyl chloride. These constituents were analyzed in the other wells as part of the NC Appendix I list of constituents for the routine semi-annual water quality monitoring. A summary of the COCs is included as Table 11 and the certificates -of -analyses are included in Appendix B. As presented on Table 11, one (1) constituent, 1,4-dichlorobenzene was the only COCs detected at a quantifiable concentration exceeding its NC 2L Standard in samples collected from monitoring well MW-7 during the March 2023 water quality monitoring event. Benzene and vinyl chloride were detected at estimated concentrations below the PQL but above the NC 2L Standard in samples collected from MW-7. No other COCs were detected at concentrations above the NC 2L Standards during the March 2023 sampling event. 5.1.2 Monitored Natural Attenuation Sampling Evaluation Monitoring wells MW-6, MW-7, MW-8, and Old MW-2 were selected for a performance evaluation of MNA processes to adhere to the NC DEQ guidance document titled MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities. These wells have been selected because they are located in the area identified for corrective action by MNA in the June 2015 CAP. The March 2023 analytical data for these wells were evaluated using the Environmental Protection Agency (EPA)'s Natural Attenuation Screening Protocol (1999). %%%p 10 July 28, 2023 GL2014715721.102 Based on the EPA's screening protocol, monitoring wells Old MW-2, MW-6, MW-7, and MW-8 received scores of 16, 21, 15, and 21, respectively indicating strong to adequate evidence for anaerobic biodegradation of chlorinated solvents. The natural attenuation screening protocol forms are included in Appendix C. Based on the results of the screening protocol, there is evidence that natural attenuation is occurring at the site; therefore, modelling was performed on the March 2023 data to simulate remediation by natural attenuation using a screening model called BIOCHLOR (EPA, 2000). Monitoring wells MW-6, MW-7, MW-8, and Old MW-2 were used in the model. Modelling parameters for advection, dispersion, and the modelled area were the same as previous models for the site, done as part of an MNA evaluation in the NES. A 63-year simulation period was selected for the model, representing the time at which waste was first placed in the landfill (the original source). The March 2023 results represent current conditions at the facility and therefore, the model was calibrated to the current sample results by adjusting the biotransformation data within a prescribed range specified by literature values within the BIOCHLOR program. Once the model was calibrated a forecasted model was created by changing the simulation period to 100 years to assess the size of the contaminant plume in the future. BIOCHLOR generates plots that compare concentrations of tetrachloroethene, trichloroethene, dichloroethane (cis- and trans-), vinyl chloride, and ethene over time with no degradation to concentrations where sequential 1st order decay is occurring. The plots are provided in Appendix D. The centerline plots can be used to forecast the contaminant plume size over time. Because tetrachloroethene; trichloroethene; and ethene were not detected in samples from downgradient monitoring wells MW-6, MW-7, MW-8, and Old MW-2 during the March 2023 monitoring event, the BIOCHLOR model could not be calibrated; however, the absence of tetrachloroethene; trichloroethene; and ethene in these downgradient samples could be considered evidence of biodegradation. The constituents, cis-1,2-dichloroethene was detected at a quantifiable concentration, and vinyl chloride was detected at an estimated concentration in samples collected from MW-7. The results from these plots indicate that natural attenuation is occurring at the site and that as long as conditions at the site continue to be strongly anaerobic, biodegradation will likely continue. According to the current data, it is likely that the plume size has stabilized, as indicated by the BIOCHLOR model. 5.2 Super Aerated Water Pilot Test Sampling Results The most recent SAW pilot test injection occurred in March 2019. SAW injections have ceased unless NC Appendix I VOCs are detected above the NC 2L Standards in samples collected from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer (AMW-1 D and AMW-2D). As presented in Table 11, the COC, benzene, was detected at concentrations above the groundwater standard in samples collected from AMW-1 D during the March 2023 sampling during the March 2023 event. Upon completion of the data review, there were multiple quality concerns identified with regards to VOC sample collected from AMW-1 D. WSP proposes to verify this detection of benzene during the next groundwater monitoring event, tentatively scheduled for September 2023. Should concentrations of benzene be confirmed in AMW-1 D, SAW injections will resume in this area. The certificates -of -analyses for each event are included in Appendix B. 6.0 CONCLUSIONS AND RECOMMENDATIONS Due to the presence of VOCs above applicable groundwater standards, Henderson County will continue to monitor the uppermost aquifer beneath the MSW landfill in accordance with the requirements of the Assessment %%%p 11 July 28, 2023 GL2014715721.102 Monitoring Program as outlined in Title 15A NCAC 13B.1634. MNA monitoring events have been performed as outlined in the approved CAP. As presented, SAW pilot test injections are no longer required unless VOCs are detected above the NC 2L Standards in samples collected from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. As presented, benzene was detected at quantifiable concentrations above the NC 2L Standards in samples collected from AMW-1 D; however, there were quality concerns identified in the laboratory report with this sample. WSP proposes to verify this result during the next sampling event, tentatively scheduled for September 2023. As presented, one (1) NC Appendix I listed VOC, vinyl chloride, was detected at a quantifiable concentration above the NC 2L Standard in samples collected from the C&D downgradient monitoring well, MW-12 during the March 2023 sampling event. No NC Appendix I listed constituents were detected at concentrations above applicable surface water standards during the March 2023 sampling event. The indicator parameters iron, manganese, and TDS were detected at quantifiable concentrations exceeding the NC 2L Standards in one or more downgradient monitoring wells during the March 2023 monitoring event. With the exception of manganese, these constituents were all detected at concentrations below the previously proposed site -specific GPS. In response to the detections of manganese at concentrations exceeding the proposed site -specific GPS, the County plans to redevelop monitoring well MW-11 prior to the next sampling event. While the turbidity values of samples collected from MW-11 are relatively low (5-10 NTUs) the values are elevated when compared to the other downgradient monitoring wells (-1 NTU). Based on the results summarized herein, the County will continue the implementation of groundwater corrective action at the MSW landfill in accordance with the approved CAP. The County will also continue monitoring the C&D landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.0545. The next compliance monitoring event for this facility is tentatively scheduled for September 2023. 7.0 REFERENCES Butler, J.R., and D.T. Secor, Jr., 1991. The Central Piedmont (Chapter 4) in J.W. Horton, Jr. and V.A. Zullo, eds., The Geology of the Carolinas (Carolina Geological Society Fiftieth Anniversary Volume): The University of Tennessee Press, pp. 2, 4, 24, 36, 44-45. Camp Dresser & McKee, December 2008. October 2008 Semi -Annual Sampling Report, Stoney Mountain Road Sanitary Landfill. Camp Dresser & McKee, June 3, 2008. Henderson County Closed Stoney Mountain Road Sanitary Landfill Additional Groundwater Assessment. Camp Dresser & McKee, May 9, 2008. April 2008 Semi -Annual Sampling Report, Stoney Mountain Road Sanitary Landfill. Camp Dresser & McKee, September 26, 2008. Henderson County Additional Groundwater Assessment Proposed Workplan. Golder Associates NC, Inc., September 17, 2009. Groundwater Assessment Work Plan; Closed Henderson County Landfill, Permit No. 45-01; Henderson County, North Carolina. %%%,I) 12 July 28, 2023 GL2014715721.102 Golder Associates NC, Inc., September 28, 2010. Alternate Source Demonstration: Anomalous Detections of Volatile Organic Compounds; Henderson County Closed Construction and Demolition Landfill, Permit No. 45 01. Golder Associates NC, Inc. 2012. Nature and Extent Study: Detections of Volatile Organic Compounds in Groundwater. Henderson County Close Municipal Solid Waste Landfill, Permit Number 45-01. July. Golder Associates NC, Inc. 2013. Assessment of Corrective Measures. Henderson County Closed Municipal Solid Waste Landfill, Permit Number 45-01. April. Golder Associates NC, Inc., 2015, Corrective Action Plan, Henderson County Closed Municipal Solid Waste Landfill, Permit45-01, June. Golder Associates NC, Inc., 2019, First Semi -Annual Water Quality and Corrective Action Monitoring Report, Henderson County Closed Municipal Solid Waste Landfill, Permit 45-01, July. Golder Associates NC, Inc., 2019, Corrective Action Evaluation Report, Henderson County Closed Municipal Solid Waste Landfill, Permit 45-01, October. Golder Associates NC, Inc., 2020, Corrective Action Evaluation Report, Henderson County Closed Municipal Solid Waste Landfill, Permit 45-01, September. North Carolina Geologic Survey, 1985. Geologic Map of North Carolina North Carolina Geologic Survey, 2004. Modified from 1991 Generalized Geologic Map (digital representation) United States Geologic Survey, 2019. National Geochemical Survey Database, https://mrdata.usgs.gov/geochem/ %%%,I) 13 July 28, 2023 Signature Page Sincerely, WSP USA, Inc. Nicola ada orre Assistant Consultant, Geologist NTT/BS D/bsd: NC Corporate Geology License. No. C-557 Benjamin S. Draper, PG, PMP Assistant Vice President, Geologist GL2014715721.102 https://golderassociates.sharepoint.com/sites/164139/project files/5 technical work/task 01 -water quality monitoring/2023- 1st sa wqm event/200 deliverables/draftlgl20l4715721-001-001-r- rev0-2nd_sa_wgmr_2022_draft-docx wsI) 14 TABLES July 2023 TABLE 1 GL2014715721-001 Summary of Historical Static Water Level Data Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 MSW Landfill Compliance Monitoring Wells MSW Landfill Assessment Monitoring Wells MSW Non -Compliance Wells MW-5 MW-6 MW-7 MW-8 AMW-1S AMWAD AMW-2S AMW-2D MWA (Old) MW-1 MW-2 (Old) MW-2 IWA TOC Elevation 2389.82 2204.24 2210.66 2235.87 2193.09 2190.77 2177.66 2177.58 2206.42 2205.76 2182.77 2182.07 2189.48 (ft AMSL) Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 10/04/06 2334.31 55.51 2191.02 13.22 2191.61 19.05 2209.54 26.33 2179.83 13.26 2176.67 14.10 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 03/21 /07 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 10/02/07 2331.55 58.27 2188.19 16.05 2189.95 20.71 2207.85 28.02 2176.63 16.46 2174.07 16.70 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 04/03/08 2326.17 63.65 2190.65 13.59 2190.63 20.03 2209.61 26.26 2180.41 12.68 2177.04 13.73 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 10/29/08 2322.17 67.65 2186.73 17.51 2188.87 21.79 2206.91 28.96 2175.87 17.22 2173.56 17.21 2168.25 9.41 2170.93 6.65 -- -- -- -- -- -- -- -- -- -- 03/24/09 2319.25 70.57 2188.30 15.94 2189.28 21.38 2208.43 27.44 2178.99 14.10 2176.04 14.73 2169.29 8.37 2172.05 5.53 -- -- -- -- -- -- -- -- -- -- 09/21-24/09 2326.37 63.45 2194.99 9.25 2190.56 20.10 2209.46 26.41 2180.79 12.30 2177.56 13.21 2170.17 7.49 2174.88 2.70 2200.47 5.95 2200.58 5.18 2174.92 7.85 2174.14 7.93 -- -- 03/22-23/10 2342.62 47.20 <2185.22 >19.02 2193.88 16.78 2208.53 27.34 2182.71 10.38 2178.32 12.45 2170.28 7.38 2173.33 4.25 2200.91 5.51 2201.11 4.65 2175.02 7.75 2164.27 17.8 -- -- 09/21-22/10 2338.34 51.48 2189.98 14.26 2191.49 19.17 2210.62 25.25 2177.74 15.35 2173.85 16.92 2171.40 6.26 2170.92 6.66 2199.72 6.70 2199.58 6.18 2163.77 19.00 2171.73 10.34 -- -- 03/15-16/11 2333.36 56.46 2194.83 9.41 2191.45 19.21 2211.13 24.74 2181.44 11.65 2176.77 14.00 2169.72 7.94 2171.74 5.84 2200.61 5.81 2200.72 5.04 2174.81 7.96 2173.04 9.03 -- -- 09/20-21/11 2331.91 57.91 2189.10 15.14 2190.61 20.05 2209.78 26.09 2177.42 15.67 2173.77 17.00 2168.40 9.26 2170.86 6.72 2199.74 6.68 2199.44 6.32 2173.97 8.8 2171.72 10.35 -- -- 03/20-22/12 2330.51 59.31 2189.49 14.75 2191.15 19.51 2210.25 25.62 2178.99 14.10 2175.58 15.19 2169.04 8.62 2171.08 6.50 2200.24 6.18 2200.13 5.63 2174.36 8.41 2172.34 9.73 -- -- 09/19-20/12 2328.67 61.15 2189.64 14.60 2190.07 20.59 2209.24 26.63 2177.89 15.20 2175.53 15.24 2169.33 8.33 2172.33 5.25 -- -- -- -- -- -- -- -- -- -- 03/20/13 2330.45 59.37 2189.68 14.56 2190.54 20.12 2210.79 25.08 2179.83 13.26 2176.77 14.00 2169.69 7.97 2173.50 4.08 2200.44 5.98 2200.45 5.31 2174.59 8.18 2172.83 9.24 -- -- 09/18/13 2342.55 47.27 2190.92 13.32 2191.97 18.69 2212.33 23.54 2179.38 13.71 2176.39 14.38 2168.98 8.68 2174.27 3.31 2198.04 8.38 2198.73 7.03 2174.20 8.57 2172.58 9.49 -- -- 03/26/14 2339.89 49.93 2190.53 13.71 2191.50 19.16 2211.92 23.95 2180.00 13.09 2176.92 13.85 2169.51 8.15 2174.24 3.34 2200.43 5.99 2200.54 5.22 2174.54 8.23 2172.73 9.34 -- -- 09/18/14 2336.72 53.10 2189.19 15.05 2190.44 20.22 2210.90 24.97 2178.02 15.07 2175.28 15.49 2168.67 8.99 2173.02 4.56 2200.33 6.09 2199.73 6.03 2174.10 8.67 2171.82 10.25 -- -- 03/17/15 2332.78 57.04 2189.98 14.26 2190.34 20.32 2210.90 24.97 2179.80 13.29 2176.77 14.00 2169.61 8.05 2173.51 4.07 2200.96 5.46 2200.62 5.14 2174.61 8.16 2172.62 9.45 -- -- 09/23/15 2328.66 61.16 2187.28 16.96 2188.93 21.73 2209.22 26.65 2175.97 17.12 2173.51 17.26 2167.94 9.72 2171.46 6.12 2198.30 8.12 2198.24 7.52 2173.77 9.00 2170.45 11.62 -- -- 03/15/16 2342.54 47.28 2191.02 13.22 2192.41 18.25 2213.36 22.51 2180.40 12.69 2177.45 13.32 2169.78 7.88 2174.97 2.61 2200.41 6.01 2199.98 5.78 2174.75 8.02 2173.27 8.80 2180.06 9.42 09/21/16 2335.83 53.99 2187.40 16.84 2189.75 20.91 2210.08 25.79 2177.10 15.99 2174.46 16.31 2168.30 9.36 2172.46 5.12 2200.08 6.34 2198.89 6.87 2172.84 9.93 -- -- 2176.86 12.62 03/22/17 2326.49 63.33 <2187.09 >17.15 2188.48 22.18 2208.65 27.22 2177.07 16.02 2174.75 16.02 2168.97 8.69 2171.56 6.02 2200.22 6.20 2199.15 6.61 2174.15 8.62 2171.10 10.97 2177.19 12.29 09/20/17 2329.64 60.18 <2186.84 >17.40 2189.65 21.01 2210.24 25.63 2178.54 14.55 2175.63 15.14 2169.10 8.56 2173.05 4.53 2200.71 5.71 2199.40 6.36 2174.00 8.77 2171.78 10.29 2178.19 11.29 03/21 /18 2336.18 53.64 2199.99 4.25 2190.89 19.77 2211.44 24.43 2179.69 13.40 2176.73 14.04 2169.65 8.01 2173.82 3.76 2201.21 5.21 2199.77 5.99 2174.32 8.45 2172.47 9.60 2179.40 10.08 09/24/18 2342.89 46.93 2189.73 14.51 2191.11 19.55 2212.25 23.62 2178.95 14.14 2176.03 14.74 2168.94 8.72 2173.73 3.85 2200.92 5.50 2199.52 6.24 2174.01 8.76 2172.05 10.02 2178.72 10.76 03/25/19 2349.70 40.12 2198.35 5.89 2193.91 16.75 2215.21 20.66 2181.26 11.83 2178.01 12.76 2170.40 7.26 2175.74 1.84 2201.90 4.52 2200.21 5.55 2174.42 8.35 2173.52 8.55 2180.90 8.58 09/18/19 2341.54 48.28 2190.00 14.24 2191.30 19.36 2211.82 24.05 2178.09 15.00 2175.29 15.48 2168.52 9.14 2173.37 4.21 2200.61 5.81 2199.24 6.52 2173.87 8.90 2171.69 10.38 2178.02 11.46 03/16/20 2341.51 48.31 2191.53 12.71 2192.66 18.00 2213.45 22.42 2180.46 12.63 2177.37 13.40 2169.71 7.95 2174.86 2.72 2201.46 4.96 2200.14 5.62 2174.35 8.42 2172.97 9.10 2180.19 9.29 09/23/20 2340.43 49.39 2200.02 4.22 2191.51 19.15 2212.13 23.74 2179.95 13.14 2176.85 13.92 2169.45 8.21 2174.25 3.33 2201.19 5.23 2199.62 6.14 2174.31 8.46 2172.52 9.55 2179.66 9.82 03/15/21 2341.50 48.32 2191.34 12.90 2192.35 18.31 2212.55 23.32 2180.39 12.70 2177.35 13.42 2169.67 7.99 2174.71 2.87 2201.32 5.10 2199.84 5.92 2174.38 8.39 2172.83 9.24 2180.69 8.79 09/20/21 2338.19 51.63 2189.24 15.00 2190.44 20.22 2210.87 25.00 2177.81 15.28 2175.09 15.68 2168.56 9.10 2172.64 4.94 2200.34 6.08 2199.07 6.69 2174.01 8.76 2171.49 10.58 -- -- 03/14/22 2331.63 58.19 2190.95 13.29 2190.00 20.66 2210.35 25.52 2179.70 13.39 2176.64 14.13 2169.69 7.97 2173.20 4.38 2200.91 5.51 2199.53 6.23 2174.47 8.30 2172.43 9.64 2179.33 10.15 9/19-9/20 2331.58 58.24 2189.09 15.15 2189.87 20.79 2210.64 25.23 2178.88 14.21 2175.94 14.83 2169.02 8.64 2173.23 4.35 2200.71 5.71 2199.25 6.51 2174.26 8.51 2172.26 9.81 2178.86 10.62 3/20-3/21 2332.75 57.07 2189.12 15.12 2190.71 19.95 2211.07 24.80 2179.58 13.51 2176.58 14.19 2169.41 8.25 2173.56 4.02 2200.95 5.47 2199.58 6.18 2174.34 8.43 2172.33 9.74 2179.31 10.17 MEAN 2334.51 55.31 2190.94 13.30 2190.86 19.80 2210.65 25.22 2179.08 14.01 2176.02 14.75 2169.32 8.35 2173.11 4.47 2200.49 5.93 2199.74 6.02 2173.89 8.88 2172.04 10.03 2179.08 10.38 MAXIMUM 2349.70 70.57 2200.02 17.51 2193.91 22.18 2215.21 28.96 2182.71 17.22 2178.32 17.26 2171.40 9.72 2175.74 6.72 2201.90 8.38 2201.11 7.52 2175.02 19.00 2174.14 17.80 2180.90 12.62 MINIMUM 2319.25 40.12 2186.73 4.22 2188.48 16.75 2206.91 20.66 2175.87 10.38 2173.51 12.45 2167.94 6.26 2170.86 1.84 2198.04 4.52 2198.24 4.65 2163.77 7.75 2164.27 7.93 2176.86 8.58 TVA Landfill Monitoring C&D Landfill Compliance Monitoring Wells Well MW-10 MW-11 MW-12 MW-13 MW-9 TOC Elevation 2404.55 2307.72 2300.09 2296.33 2259.59 ft AMSL Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date ft AMSL ft ft AMSL ft ft AMSL ft ft AMSL ft ft AMSL ft 10/04/06 -- -- -- -- -- -- -- -- 2244.64 15.37 03/21 /07 2371.42 33.13 2266.46 30.55 2250.25 49.84 2252.90 47.34 -- -- 10/02/07 -- -- -- -- -- -- -- -- 2244.08 15.93 04/03/08 -- -- -- -- -- -- -- -- 2244.03 15.98 10/29/08 2364.42 40.13 2258.56 38.45 2246.56 53.53 2245.91 54.33 2242.52 17.49 03/24/09 2363.04 41.51 2256.50 40.51 2244.43 55.66 2244.51 55.73 2242.21 17.80 09/21-24/09 2367.33 37.22 2258.97 38.04 2245.20 54.89 2245.56 54.68 2243.29 16.72 03/22-23/10 2376.31 28.24 2258.18 38.83 2250.60 49.49 2253.17 47.07 2236.04 23.97 09/21-22/10 2369.83 34.72 2267.16 29.85 2250.78 49.31 2253.84 46.4 2245.16 14.85 03/15-16/11 2367.12 37.43 2263.36 33.65 2248.90 51.19 2251.00 49.24 2245.10 14.91 09/20-21/11 2368.37 36.18 2260.95 46.77 2249.18 50.91 2250.57 45.76 2244.95 14.64 03/20-22/12 2367.47 37.08 2260.61 47.11 2248.24 51.85 2249.98 46.35 2244.54 15.05 09/19-20/12 2367.05 37.50 2260.07 47.65 2247.39 52.70 2249.08 47.25 -- -- 03/20/13 2367.57 36.98 2259.14 48.58 2247.66 52.43 2249.30 47.03 2244.43 15.16 09/18/13 2375.12 29.43 2265.42 42.30 2252.34 47.75 2255.88 40.45 2249.63 9.96 03/26/14 2372.14 32.41 2266.61 41.11 2253.04 47.05 2255.79 40.54 2247.08 12.51 09/18/14 2369.87 34.68 2265.38 42.34 2251.59 48.50 2254.33 42.00 -- -- 03/17/15 2367.64 36.91 2262.72 45.00 2249.97 50.12 2251.60 44.73 2245.25 14.34 09/23/15 2366.71 37.84 2259.50 48.22 2248.16 51.93 2249.76 46.57 2243.30 16.29 03/15/16 2374.71 29.84 2263.81 43.91 2253.18 46.91 2255.44 40.89 2247.00 12.59 09/21/16 2369.18 35.37 2263.94 43.78 2251.74 48.35 2253.68 42.65 2245.61 13.98 03/22/17 <2366.76 >37.79 2258.35 49.37 2247.61 52.48 2248.70 47.63 2243.07 16.52 09/20/17 2366.74 37.81 2257.41 50.31 2247.42 52.67 2249.08 47.25 2242.77 16.82 03/21/18 2368.44 36.11 2261.40 46.32 2249.49 50.60 2250.84 45.49 2244.53 15.06 09/25/18 2373.46 31.09 2265.79 41.93 2253.50 46.59 2256.04 40.29 2246.54 13.05 03/25/19 2379.31 25.24 2270.94 36.78 2259.00 41.09 2261.36 34.97 2250.01 9.58 09/18/19 2371.95 32.60 2273.88 33.84 2256.36 43.73 2257.79 38.54 2248.34 11.25 03/16/20 2371.81 32.74 2263.83 43.89 2254.30 45.79 2255.49 40.84 2247.29 12.30 09/23/20 2366.61 37.94 2263.72 44.00 2253.38 46.71 2254.92 41.41 2246.59 13.00 03/15/21 2373.02 31.53 2264.26 43.46 2254.24 45.85 2256.04 40.29 2247.14 12.45 09/21 /21 2366.60 37.95 2263.46 44.26 2252.74 47.35 2254.03 42.30 2245.74 13.85 03/14/22 2366.61 37.94 2258.69 49.03 2249.26 50.83 2249.92 46.41 2244.03 15.56 9/19-9/20 2366.74 37.81 2257.20 50.52 2249.55 50.54 2248.97 47.36 2242.72 16.87 3/20-3/21 <2366.76 >37.94 2258.31 49.41 2248.86 51.23 2249.21 47.12 2243.61 15.98 MEAN 2369.54 35.01 2262.41 42.90 2250.48 49.61 2252.09 45.13 2244.88 14.83 MAXIMUM 2379.31 41.51 2273.88 50.52 2259.00 55.66 2261.36 55.73 2250.01 23.97 MINIMUM 2363.04 25.24 2256.50 29.85 2244.43 41.09 2244.51 34.97 2236.04 9.58 Notes: DTW = depth to water ft = feet ft AMSL = feet above mean sea level. TOC = top of casing -- = no data available Historical data prior to March 2009 provided by Henderson County and CDM. The stick-ups on monitoring wells MW-9, MW-11, and MW-13 were modified prior to the September 2011 event and the TOC elevations for those wells were resurveyed. 1 of 1 July 2023 TABLE 2 Summary of Estimated Horizontal Flow Velocities Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 GL2014715721 March 2023 Gradient Calculation Gradient Segment Gradient Segment Horizontal Gradient Effective Hydraulic Velocity Segment Flow Direction Length Elevations (i, feet) Porosity Conductivity (VgW, feet/year) (feet) (feet) (ne) (K, cm/sec) i SW 1691 -------- -2320-------- 2180 0.0828 0.15 1.26E-04 72.11 i2 SSW 1937 _________2340 2200 0.0723 0.15 1.26E-04 62.95 i3 WSW 336 --------_2360 2260 0.2976 0.15 1.26E-04 259.27 Notes: Horizontal velocities based on the modified Darcy equation VgW = Ki/ne. Value for K is collected from the average of measured hydraulic conductivities from the December 2008 CDM Report. Value for ne is an estimated effective porosity used in previous CDM reports. 1 of 1 July 2023 TABLE 3 Summary of Well Construction Information Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 GL2014715721 Well Identification Construction Date Coordinates Ground Surface Elevation (ft AMSL) TOC Elevation (ft AMSL) Well Depth (ft) Well Diameter (in) Screened Interval (ft BGS) Screened Interval (ft AMSL) Geology of Screened Interval Well Status Northing Easting MW-5 10/21/1994 603077.23 958574.87 2386.79 2389.82 73.03 2 48.03 - 73.03 2341.79 - 2316.79 Saprolite MSW Compliance Background Well MW-6 10/20/1994 602152.02 956919.71 2202.39 2205.39 23.00 2 8.00 - 23.00 2197.39 - 2182.39 Saprolite MSW Compliance Well MW-7 10/17/1994 601949.28 957146.97 2207.77 2210.66 27.89 2 12.89 - 27.89 2197.77 - 2182.77 Saprolite MSW Compliance Well MW-8 10/18/1994 601765.86 957772.78 2232.97 2235.87 34.90 2 19.90 - 34.90 2215.97 - 2200.97 Saprolite MSW Compliance Well MW-9 10/18/1994 601664.26 958474.38 2256.95 2260.01 28.06 2 13.06 - 28.06 2246.95 - 2231.95 Saprolite TVA Monitoring Well AMW-1 S 10/15/2001 602112.51 956718.62 2190.20 2193.09 31.72 2 15 - 30 2175.20 - 2160.20 Saprolite MSW Assessment Well AMW-1 D 10/15/2001 602096.10 956704.70 2188.37 2190.77 62.65 2 50 - 60 2138.37 - 2128.37 PWR / Upper Fractured Rock MSW Assessment Well AMW-2S 4/2/2008 602098.59 956540.99 2168.25 2177.66 22.00 2 7.00 - 22.00 2161.25 - 2146.25 Saprolite MSW Assessment Well AMW-2D 4/2/2008 602116.88 956553.69 2170.93 2177.58 80.00 2 70.00 - 80.00 2100.93 - 2090.93 Fractured Rock MSW Assessment Well MW-10 NA 601790.07 959077.23 2402.63 2404.55 45.0 2 35 - 45 2367.63 - 2357.63 Saprolite / PWR C&D Compliance Background Well MW-11 NA 601946.06 958655.82 NA 2297.01 48.17 2 NA - 48.17 NA NA C&D Compliance Well MW-12 NA 601683.36 958608.18 2297.97 2300.09 60.0 2 50 - 60 2244.97 - 2234.97 Saprolite / PWR C&D Compliance Well MW-13 NA 601511.47 958653.36 NA 2300.24 92.0 2 77 - 92 2221.16 - 2206.16 Bedrock C&D Compliance Well MW-1 (OLD) NA 601264.43 957865.19 NA 2206.40 20.7 BTOC 2 NA NA Saprolite Non -Compliance Well MW-1 NA 601286.04 957837.08 NA 2206.80 70.2 BTOC 2 NA NA PWR Non -Compliance Well MW-2 (OLD) NA 601446.34 957142.17 NA 2182.10 20.6 BTOC 2 NA NA Saprolite / PWR Corrective Action Well MW-2 NA 601438.21 957125.15 NA 2182.80 67.6 BTOC 2 NA NA PWR / Upper Fractured Rock Corrective Action Well IW-1 1 3/9/2016 1 602096.76 956729.44 1 2189.96 1 2189.48 1 65.0 1 2 1 45 - 65 1 2144.96 - 2124.96 Bedrock I MSW Injection Well Notes: ft = feet in = inches AMSL = above mean sea level BGS = below ground surface BTOC = below top of casing Well construction information provided by Henderson County & CDM NA = Data is not available or not applicable PWR = Partially Weathered Rock Northings and eastings were taken from Drawing 1 and should be considered approximate. 1 of 1 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Antimony ug/L 12/05/94 -- -- 6 ND ND ND ND -- -- -- -- ND -- NC 2L = 1 ug/L ug/L 02/14/95 -- -- 6 ND ND ND ND -- -- -- -- ND -- EPA MCL = 6 ug/L ug/L 04/03/95 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- 6 ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- 6 ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- 6 ND ND 3 ND -- -- -- -- ND -- ug/L 05/14/98 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- 6 ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- 6 ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- 6 ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- 6 ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- 6 ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- 6 ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- 6 ND ND ND ND ND ND -- -- 0.91 J ND ug/L 10/02/07 -- -- 6 ND ND ND ND ND ND -- -- ND ND ug/L 04/03/08 -- -- 6 ND ND ND ND ND ND ND ND ND ND ug/L 10/29/08 -- -- 6 ND ND ND ND ND ND ND ND ND ND ug/L 03/24/09 0.68 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.073 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/22/10 0.22 2.00 6 ND Dry ND 0.441 J ND ND ND ND -- ND ug/L 09/23/10 0.22 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.22 2.00 6 0.226 J ND 0.286 J ND 0.460 J 0.382 J ND 0.365 J -- ND ug/L 09/21/11 0.22 2.00 6 ND 0.478 J 0.408 J 0.287 J ND ND ND ND -- ND ug/L 03/21/12 0.22 2.00 6 0.320 J ND ND 0.906 J ND 0.236 J ND ND ND ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.22 2.00 6 ND ND ND 0.621 J ND ND ND ND ND ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/27/14 0.22 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.22 2.00 6 0.319 J 0.275 J 0.874 J ND ND ND ND ND -- ND ug/L 03/18/15 0.22 2.00 6 ND ND ND 0.661 J ND ND ND ND ND ND ug/L 09/23/15 0.22 2.00 6 ND ND 2.64 J ND ND ND ND ND -- 0.331 J ug/L 03/17/16 0.22 2.00 6 0.861 J 0.517 J ND ND ND 0.333 J ND ND ND ND ug/L 09/21/16 0.22 2.00 6 ND ND 0.308 J ND ND ND ND ND -- ND ug/L 03/21/17 0.22 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/17 0.37 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 1.85 5.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.85 5.00 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.74 2.00 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.74 2.00 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.74 2.00 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.74 2.00 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.74 2.00 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.74 2.00 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.74 2.00 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.74 2.00 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.34 5.00 -- ND ND ND ND ND ND ND ND ND ND Arsenic ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 10 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 10 ug/L ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND 10.1 ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND 11.1 -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND 14.7 ND 21.3 ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND 0.84 J 0.94 J 0.46 J 1.13 J ND -- -- ND ND ug/L 10/02/07 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 04/03/08 -- -- -- 2.07 J 2.45 J 3.04 J 5.07 J ND ND 3.64 J 10.5 ND ND ug/L 10/29/08 -- -- -- ND 13.9 7.18 J ND ND 5.98 J 5.38 J 2.96 J ND ND ug/L 03/24/09 2.8 10.0 -- ND ND ND 3.1 J ND ND ND ND ND ND ug/L 09/22/09 2.8 10.0 -- ND 5.40 B 7.18 B ND ND ND ND ND -- 2.90 J ug/L 03/22/10 2.8 10.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 2.8 10.0 -- ND 5.27 J ND 4.58 J ND ND ND ND -- ND ug/L 03/16/11 2.8 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 2.8 10.0 -- ND ND 5.48 J 6.93 J ND ND 4.29 J 3.03 J -- ND ug/L 03/21/12 2.8 10.0 -- 3.80 J ND ND ND ND ND ND 4.00 J ND ND ug/L 09/20/12 2.8 10.0 -- ND ND ND ND ND ND ND ND -- 3.27 J ug/L 03/20/13 2.8 10.0 -- ND ND ND ND ND ND ND 3.04 J ND ND ug/L 09/18/13 5.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/27/14 5.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 5.4 10.0 -- ND ND ND ND 5.51 J ND ND ND -- ND ug/L 03/18/15 5.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 5.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 5.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 6.8 10.0 -- ND 14.1 ND 8.11 J ND ND ND ND -- ND ug/L 03/21/17 6.8 10.0 -- ND 8.43 B 10.6 B 11.7 B ND ND 14.4 B ND ND 9.82 J ug/L 09/20/17 6.8 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 6.8 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 7.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 7.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 7.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 7.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 7.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 7.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 7.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 7.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 7.6 10.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 6.4 20.0 -- ND ND ND ND ND ND ND ND ND ND Barium ug/L 12/05/94 -- -- -- 134 237 378 528 -- -- -- -- 207 -- NC 2L = 700 ug/L ug/L 02/14/95 -- -- -- ND 416 439 601 -- -- -- -- 205 -- EPA MCL = 2000 ug/L ug/L 04/03/95 -- -- -- 174 493 350 786 -- -- -- -- 197 -- ug/L 10/30/95 -- -- -- 348 539 230 835 -- -- -- -- 358 -- ug/L 04/08/96 -- -- -- 199 332 264 790 -- -- -- -- 140 -- ug/L 10/24/96 -- -- -- 300 -- 338 925 -- -- -- -- 285 -- ug/L 04/15/97 -- -- -- 180 -- 300 810 -- -- -- -- 360 -- ug/L 10/29/97 -- -- -- 200 700 500 700 -- -- -- -- 100 -- ug/L 05/14/98 -- -- -- ND ND ND 628 -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND 552 -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND 258 -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND 604 -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND 178 116 298 -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND 642 ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND 522 ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND 720 ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND 829 ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND 530 ND 866 ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND 982 ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND 687 ND 822 ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 562 ND 920 ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 47.5 J 136 294 992 306 27.2 J -- -- 49.9 J ND ug/L 10/02/07 -- -- -- 135 904 198 695 563 37.4 B -- -- 54.3 B 16.1 J ug/L 04/03/08 -- -- -- 87.8 J 86.8 J 144 714 476 20.3 B 44.3 B 39.4 B 65.9 J 10.1 J ug/L 10/29/08 -- -- -- 69.9 J 795 227 429 930 28.2 24.9 J 19.4 J 62.1 J ND ug/L 03/24/09 4.2 10.0 -- 26.2 J 54.5 J 203 517 221 19.0 J 15.4 J ND 56.7 J ND ug/L 09/22/09 1.0 10.0 -- 31.5 J 48.9 J 259 916 323 11.7 J 19.1 J 5.46 J -- ND ug/L 03/22/10 1.0 10.0 -- 28.2 J Dry 268 693 79.9 J 23.1 J 9.57 J 4.16 B -- 1.54 J ug/L 09/23/10 1.0 10.0 -- 34.3 J 335 302 1130 86.5 J 13.1 J 7.69 J 1.79 J -- ND ug/L 03/16/11 1.0 10.0 -- 71.3 J 39.4 J 417 414 216 8.14 J 85.4 J 2.71 J -- ND ug/L 09/21/11 1.0 10.0 -- 40.2 J 482 453 1370 214 12.2 J 14.0 J 2.07 J -- ND ug/L 03/21/12 1.0 10.0 -- 60.8 J 315 481 1070 412 14.5 J 7.28 J 1.64 J 180 ND ug/L 09/20/12 1.0 10.0 -- 28.9 J 58.9 J 464 454 390 12.2 J 12.9 J 2.15 J -- ND ug/L 03/20/13 1.0 10.0 -- 51.9 J 33.4 J 518 957 342 10.4 J 8.94 J 1.74 B 192 1.34 J ug/L 09/18/13 1.0 10.0 -- 57.7 J 218 590 787 400 11.3 J 26.6 J 2.75 B -- 1.08 J ug/L 03/27/14 1.0 10.0 -- 42.5 J 43.3 J 514 988 239 21.5 J 10.4 J 2.58 J 217 ND ug/L 09/18/14 1.0 10.0 -- 31.2 J 482 453 1050 306 16.5 J 5.60 B 2.15 B -- 1.96 J ug/L 03/18/15 1.0 10.0 -- 42.3 J 27.4 J 535 710 538 11.0 J 11.7 J 2.26 J 226 ND ug/L 09/23/15 1.0 10.0 -- 27.0 J 692 521 741 686 17.5 B 7.64 B 3.32 B -- 4.08 J ug/L 03/17/16 1.0 10.0 -- 50.7 J 131 618 530 388 8.55 J 7.16 J 2.96 J 118 ND ug/L 09/21/16 1.0 10.0 -- 39.9 J 838 628 699 338 8.38 J 8.46 J 3.92 J -- ND ug/L 03/21/17 1.0 10.0 -- 16.6 J 576 554 581 412 7.31 J 8.01 J 2.87 J 105 ND ug/L 09/20/17 1.0 10.0 -- 25.1 J 122 562 569 324 7.76 J 6.36 J 3.07 J -- ND ug/L 03/21/18 1.0 10.0 -- 51.5 J 54.5 J 566 575 491 8.61 J 7.04 J 3.23 J 122 ND ug/L 09/23/18 1.1 10.0 -- 36.0 159 518 543 338 15.3 5.36 J 2.60 J -- ND ug/L 03/26/19 1.1 10.0 -- 41.2 36 617 728 384 39.2 4.10 J 2.66 J 123 ND (dissolved) ug/L 03/26/19 1.1 10.0 -- -- -- -- 654 -- -- -- -- -- ND ug/L 09/18/19 1.1 10.0 -- 27.9 563 558 669 284 17.2 B 4.03 B 2.87 B -- 3.97 J ug/L 03/16/20 1.1 10.0 -- 21.1 92.6 559 634 464 20.9 3.31 J 2.46 J 140 ND ug/L 09/23/20 1.1 10.0 -- 29.9 73.5 639 551 300 22.7 3.68 J 3.44 J -- ND ug/L 03/15/21 1.1 10.0 -- 24.2 61.0 653 662 229 25.7 3.59 J 4.16 J 124 ND ug/L 09/20/21 1.1 10.0 -- 27.4 330 605 604 180 16.6 3.67 J 4.36 J -- ND ug/L 03/14/22 1.1 10.0 -- 23.5 71.1 595 814 390 9.81 J 4.60 J 3.74 J 149 ND ug/L 09/19/22 1.1 10.0 -- 19.6 93.4 659 628 260 38.9 4.87 J 3.29 J -- ND u /L 03/20/23 4.4 10.0 -- 23.3 185 575 581 228 14.2 ND ND 86.8 ND 1 of 13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Beryllium ug/L 12/05/94 -- -- -- ND ND 3 7 -- -- -- -- ND -- NC 2L = 4 ug/L ug/L 02/14/95 -- -- -- ND ND 4 5 -- -- -- -- ND -- EPA MCL = 4 ug/L ug/L 04/03/95 -- -- -- ND 2 3 9 -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND 5 -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND 4 -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND 4 -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND 8 -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 3 3 14 -- -- -- -- 1 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND 2.4 -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- 4.2 ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND ND ND 1.06 J 5.1 J ND -- -- ND ND ug/L 10/02/07 -- -- -- ND ND ND ND ND ND -- -- 22.8 B 6.01 ug/L 04/03/08 -- -- -- 1.07 2.8 6.28 ND 5.41 3.2 ND 2.33 1.54 ND ug/L 10/29/08 -- -- -- 4.60 5.96 2.23 10.2 10.7 5.45 10.7 2.23 11.2 ND ug/L 03/24/09 0.08 1.00 -- 0.35 J 0.20 J 0.82 J 3.02 1.30 ND 0.18 J ND 0.35 J ND ug/L 09/22/09 0.10 1.00 -- 0.438 J 0.299 J 0.771 J 1.26 0.438 J ND 0.470 J ND -- ND ug/L 03/22/10 0.10 1.00 -- ND Dry 0.635 J ND 0.631 J ND ND 0.247 J -- ND ug/L 09/23/10 0.10 1.00 -- 0.198 J ND 0.570 J ND 0.492 J ND ND ND -- ND ug/L 03/16/11 0.10 1.00 -- 0.208 J ND 0.422 J ND 1.06 ND 1.80 ND -- ND ug/L 09/21/11 0.10 1.00 -- ND 0.183 J 0.707 J 1.13 1.37 ND 0.138 J ND -- ND ug/L 03/21/12 0.10 1.00 -- 0.222 J ND 0.260 J 0.189 J 1.96 ND ND ND 1.37 ND ug/L 09/20/12 0.10 1.00 -- ND ND 0.298 J 0.443 J 1.68 ND ND ND -- ND ug/L 03/20/13 0.10 1.00 -- ND ND 0.258 J 0.327 J 0.420 J ND ND ND 1.68 ND ug/L 09/18/13 0.10 1.00 -- ND ND 0.105 J ND 0.484 J ND 0.331 J ND -- ND ug/L 03/27/14 0.10 1.00 -- ND ND 0.199 J ND 0.556 J ND ND ND 2.19 ND ug/L 09/18/14 0.10 1.00 -- 0.106 J ND 0.295 J ND 1.07 ND ND ND -- ND ug/L 03/18/15 0.10 1.00 -- 0.125 J ND 0.514 J 0.344 J 0.992 J ND ND ND 1.54 ND ug/L 09/23/15 0.10 1.00 -- ND ND 0.352 J 0.114 J 0.611 J ND ND ND -- ND ug/L 03/17/16 0.10 1.00 -- 0.134 J ND 0.130 J ND 1.04 ND ND ND 1.75 ND ug/L 09/21/16 0.10 1.00 -- 0.146 J ND 0.277 J ND 1.08 ND ND ND -- ND ug/L 03/21/17 0.10 1.00 -- ND ND 0.356 J 0.199 J 0.810 J ND ND ND 1.06 ND ug/L 09/20/17 0.10 1.00 -- ND ND ND ND 0.988 J ND ND ND -- ND ug/L 03/21/18 0.10 1.00 -- ND ND 0.273 J ND 1.61 ND ND ND 2.66 ND ug/L 09/23/18 0.16 1.00 -- 0.262 J ND 0.293 J ND 1.32 ND ND ND -- ND ug/L 03/26/19 0.16 1.00 -- 0.178 J ND 0.262 J 0.279 J 1.96 ND ND ND 2.02 ND ug/L 09/18/19 0.16 1.00 -- ND ND ND ND 1.66 ND ND ND -- ND ug/L 03/16/20 0.16 1.00 -- ND ND 0.245 J ND 1.79 ND ND ND 1.91 ND ug/L 09/23/20 0.16 1.00 -- ND ND 0.284 J ND 1.17 ND ND ND -- ND ug/L 03/15/21 0.16 1.00 -- ND ND ND ND 0.845 J ND ND ND 1.63 ND ug/L 09/20/21 0.16 1.00 -- ND ND 0.350 J ND 0.961 J ND ND ND -- ND ug/L 03/14/22 0.16 1.00 -- ND ND 0.273 J ND 1.02 ND ND ND 2.39 ND ug/L 09/19/22 0.16 1.00 -- ND ND 0.320 J ND 0.948 J ND ND ND -- ND u /L 03/20/23 0.30 4.00 -- ND 0.910 B 1.19 B ND 0.570 B 0.570 B 0.550 B 0.510 B 1.89 B 0.9400 1 Cadmium ug/L 12/05/94 -- -- -- ND ND 22 ND -- -- -- -- ND -- NC 2L = 2 ug/L ug/L 02/14/95 -- -- -- ND ND 3 ND -- -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 -- -- -- ND ND 1 ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 9 ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 5.6 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND 1.2 ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND 2.3 1.7 ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND 15 ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 3.2 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND 2 -- ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 2 ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND 2 ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND 1.35 ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 3.34 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND 11.6 ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND 1.31 1.28 1.08 1 ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 1.9 1.02 -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND 1.39 ND 2.57 ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 1.73 J 1.27 ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 1.57 J 0.65 J 2.35 J 2.08 J 2.5 J 1.38 J -- -- 1.4 J ND ug/L 10/02/07 -- -- -- ND ND 1.63 0.4 J ND ND -- -- ND ND ug/L 04/03/08 -- -- -- ND 0.2 J 0.9 J 0.47 J 0.29 J ND ND ND ND ND ug/L 10/29/08 -- -- -- ND 3.09 0.43 J 0.2 J ND ND ND ND ND ND ug/L 03/24/09 0.09 1.00 -- ND 0.22 J 0.18 J 1.06 0.61 J ND ND ND ND ND ug/L 09/22/09 0.36 1.00 -- 0.667 J ND 0.659 J 0.627 J ND ND 1.24 ND -- ND ug/L 03/22/10 0.36 1.00 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.36 1.00 -- ND ND 0.493 J 0.618 J 0.416 J ND ND ND -- ND ug/L 03/16/11 0.36 1.00 -- ND 0.517 J ND ND 1.07 ND ND ND -- ND ug/L 09/21/11 0.36 1.00 -- ND ND 0.666 J 0.441 J 0.841 J ND ND ND -- ND ug/L 03/21/12 0.36 1.00 -- ND ND 0.673 J ND 2.13 ND ND ND ND ND ug/L 09/20/12 0.36 1.00 -- ND ND 0.655 J ND 2.87 ND ND ND -- ND ug/L 03/20/13 0.36 1.00 -- ND ND 3.30 ND 1.20 ND ND ND ND ND ug/L 09/18/13 0.36 1.00 -- ND ND 0.785 J ND 0.669 J ND ND ND -- ND ug/L 03/27/14 0.36 1.00 -- ND ND 0.455 J ND 1.24 ND ND ND 0.453 J ND ug/L 09/18/14 0.36 1.00 -- ND ND 0.858 J ND 2.41 ND ND ND -- ND ug/L 03/18/15 0.36 1.00 -- ND ND 2.18 ND 1.63 ND ND ND ND ND ug/L 09/23/15 0.36 1.00 -- ND ND 0.627 J ND 1.05 ND ND ND -- ND ug/L 03/17/16 0.36 1.00 -- ND ND 0.456 J ND 2.00 ND ND ND ND ND ug/L 09/21/16 0.36 1.00 -- ND ND 0.360 J ND 1.67 ND ND ND -- ND ug/L 03/21/17 0.36 1.00 -- ND ND 1.27 B ND 2.28 B ND ND ND ND 0.591 J ug/L 09/20/17 0.36 1.00 -- ND ND 0.572 J ND 1.76 ND ND ND -- ND ug/L 03/21/18 0.36 1.00 -- ND ND 0.618 J ND 3.00 ND ND ND 0.360 J ND (verificaton event) ug/L 06/15/18 0.36 1.00 -- -- -- -- -- 3.44 -- -- -- -- ND (dissolved) ug/L 06/15/18 0.36 1.00 -- -- -- -- -- 3.14 -- -- -- -- ND ug/L 09/23/18 0.36 1.00 -- ND ND ND ND 1.97 ND ND ND -- ND ug/L 03/26/19 0.36 1.00 -- ND ND ND ND 2.72 ND ND ND ND ND ug/L 09/18/19 0.36 1.00 -- ND ND 0.387 J ND 1.97 ND ND ND -- ND ug/L 03/16/20 0.36 1.00 -- ND ND ND ND 2.74 ND ND ND ND ND ug/L 09/23/20 0.36 1.00 -- ND ND ND ND 1.06 ND ND ND -- ND ug/L 03/15/21 0.36 1.00 -- ND ND ND ND 0.902 J ND ND ND ND ND ug/L 09/20/21 0.36 1.00 -- ND ND ND ND 0.657 J ND ND ND -- ND ug/L 03/14/22 0.36 1.00 -- ND ND ND ND 0.704 J ND ND ND ND ND ug/L 09/19/22 0.36 1.00 -- ND ND 0.474 J ND ND ND ND ND -- ND u /L 03/20/23 0.44 5.00 -- ND ND 0.500 J ND 1.27 J ND ND ND ND ND Chromium ug/L 12/05/94 -- -- -- ND ND 56 ND -- -- -- -- ND -- NC 2L = 10 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 100 ug/L ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- 11 ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- 5 ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- 3 -- ND 2 -- -- -- -- 2 -- ug/L 10/29/97 -- -- -- 3 8 2 2 -- -- -- -- 1 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 20.1 ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND 14.9 ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND 11.4 ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 11.3 ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 3.33 J 3.81 J 6.01 J 4.12 J 2.7 J 1.29 J -- -- 1.44 J ND ug/L 10/02/07 -- -- -- 9.55 B 9.44 B 7.31 B 4.47 B 5.99 B 12.3 B -- -- 3.67 B 3.67 J ug/L 04/03/08 -- -- -- 6.54 B 4.93 B 4.18 B 4.42 B 4.18 B 3.31 B 4.18 B 130 2.45 B 2.94 J ug/L 10/29/08 -- -- -- 7.45 J 35.5 8.07 J 6.10 J 8.55 11.3 5.24 J 13.7 4.63 J ND ug/L 03/24/09 0.7 10.0 -- ND 1.0 J 1.6 J 4.0 J 1.2 J ND ND 1.5 J ND ND ug/L 09/22/09 1.0 10.0 -- 1.36 J ND 1.99 J 3.28 J 1.14 J ND 1.61 J 1.51 J -- ND ug/L 03/22/10 1.0 10.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 1.0 10.0 -- ND ND 1.50 J 4.38 J ND ND ND ND -- ND ug/L 03/16/11 1.0 10.0 -- 2.55 J 1.32 J 2.90 J 3.29 J 1.60 J ND 3.34 J ND -- ND ug/L 09/21/11 1.0 10.0 -- ND 6.75 J 5.20 J 12.4 ND ND ND ND -- ND ug/L 03/21/12 1.0 10.0 -- 2.15 J 3.60 J 2.25 J 4.57 J 3.36 J ND ND ND ND ND ug/L 09/20/12 1.0 10.0 -- ND ND 1.31 J 2.42 J 2.29 J ND ND ND -- ND ug/L 03/20/13 1.4 10.0 -- 2.48 J ND ND ND ND ND ND ND ND ND ug/L 09/18/13 1.4 10.0 -- ND 4.80 J 5.25 J 3.23 J ND ND ND ND -- ND ug/L 03/27/14 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 1.4 10.0 -- ND 5.15 J 1.95 J 2.65 J 1.68 J ND ND ND -- ND ug/L 03/18/15 1.4 10.0 -- ND ND 7.41 J 2.76 J 2.45 J ND ND ND ND ND ug/L 09/23/15 1.4 10.0 -- ND 2.61 J 2.70 J 2.87 J 3.81 J ND ND ND -- ND ug/L 03/17/16 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 1.4 10.0 -- ND ND ND ND ND ND 2.18 J ND 1.47 J ND ug/L 09/20/17 1.4 10.0 -- ND ND ND 1.51 J ND ND ND ND -- ND ug/L 03/21/18 1.4 10.0 -- ND ND ND ND 1.79 J ND ND ND ND ND ug/L 09/23/18 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 1.4 10.0 -- ND ND 1.54 J ND ND 2.04 J ND ND ND ND ug/L 09/18/19 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 1.4 10.0 -- ND ND 4.20 J 2.81 J 3.10 J 2.06 J ND ND -- ND ug/L 03/15/21 1.4 10.0 -- ND ND 2.60 J 3.25 J 3.01 J ND ND ND 1.63 J ND ug/L 09/20/21 1.4 10.0 -- ND 1.79 J 5.86 J 2.72 J 2.08 J 4.18 J ND ND -- ND ug/L 03/14/22 1.4 10.0 -- ND ND 4.11 J 3.68 J 6.03 J 1.76 J ND ND ND ND ug/L 09/19/22 1.4 10.0 -- ND ND 3.86 J 4.37 J 2.98 J 1.99 J ND ND -- ND u /L 03/20/23 1.1 10.0 -- ND 2.15 J ND ND 1.32 J ND ND ND ND ND 2of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Cobalt ug/L 12/05/94 -- -- -- ND 41 ND ND -- -- -- -- ND -- NC 2L = 1 ug/L ug/L 02/14/95 -- -- -- ND 48 ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 -- -- -- ND 38 ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND 34 ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND 32 ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- 2 -- 19 2 -- -- -- -- 3 -- ug/L 10/29/97 -- -- -- ND 19 7 ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 53.4 17.3 ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 52.3 11.5 ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND 12.5 ND 14.3 -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 14 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 17.9 ND ND 16.1 ND -- -- ND -- ug/L 10/01/02 -- -- -- ND 11.4 ND ND 11.7 ND -- -- ND -- ug/L 04/09/03 -- -- -- ND 13.1 ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 32.1 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND 94.9 16 ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND 120 18.5 ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 35.5 16.8 -- 13.4 ND -- -- ND -- ug/L 10/04/05 -- -- -- ND 23.5 16.2 ND 16.1 ND -- -- ND -- ug/L 04/25/06 -- -- -- ND 18.8 13.9 ND 16.1 ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 15.4 13.4 ND 18.9 ND -- -- ND ND ug/L 03/21/07 -- -- -- 1.13 J 11.3 12.6 1.5 J 16.2 ND -- -- ND ND ug/L 10/02/07 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 04/03/08 -- -- -- ND 12.4 ND ND 15.1 ND 12.5 ND ND ND ug/L 10/29/08 -- -- -- 3.55 J 35.9 5.16 J 3.74 J 24.8 ND 3.91 J ND ND ND ug/L 03/24/09 0.6 10.0 -- 0.6 J 3.1 J ND 5.8 J 10.7 ND 4.0 J ND ND ND ug/L 09/22/09 1.1 10.0 -- ND 4.81 J ND 2.50 J 10.8 ND ND ND -- ND ug/L 03/22/10 1.1 10.0 -- ND Dry ND 6.33 J 3.47 J ND ND ND -- ND ug/L 09/23/10 1.1 10.0 -- ND 2.13 J ND 9.21 J 3.42 J ND ND ND -- ND ug/L 03/16/11 1.1 10.0 -- ND ND ND 2.87 J 8.51 J ND 1.26 J ND -- ND ug/L 09/21/11 1.1 10.0 -- ND 3.73 J ND 7.48 J 9.15 J ND ND ND -- ND ug/L 03/21/12 1.1 10.0 -- ND 3.48 J ND 3.74 J 18.4 ND ND ND ND ND ug/L 09/20/12 1.1 10.0 -- ND ND ND 3.20 J 16.0 ND 1.33 J ND -- ND ug/L 03/20/13 1.1 10.0 -- 1.32 J ND ND 3.67 J 5.62 J ND ND ND ND ND ug/L 09/18/13 1.1 10.0 -- ND 43.8 18.7 2.44 J 4.83 J ND 2.33 J ND -- ND ug/L 03/27/14 1.1 10.0 -- ND 1.91 J ND 3.03 J 5.44 J ND 2.24 J ND 1.81 J ND ug/L 09/18/14 1.1 10.0 -- ND 5.56 J ND 5.11 J 9.65 J ND 1.23 J ND -- ND ug/L 03/18/15 1.1 10.0 -- ND ND 2.67 J 5.00 J 7.67 J ND 1.78 J ND 1.67 J ND ug/L 09/23/15 1.1 10.0 -- ND 1.34 J ND 2.89 J 7.86 J ND ND ND -- ND ug/L 03/17/16 1.1 10.0 -- ND 3.66 J 6.51 J 6.75 J 7.42 J ND ND ND 3.13 J ND ug/L 09/21/16 1.1 10.0 -- ND 1.75 J 4.61 J 9.16 J 7.40 J ND ND ND -- ND ug/L 03/21/17 1.1 10.0 -- ND 1.66 J ND 2.62 J 7.47 J ND ND ND ND ND ug/L 09/20/17 1.1 10.0 -- ND ND ND 10.4 6.94 J ND ND ND -- ND (verification event) ug/L 12/19/17 1.1 10.0 -- -- -- -- 10.3 -- -- -- -- -- ND (dissolved) ug/L 12/19/17 1.1 10.0 -- -- -- -- 10.5 -- -- -- -- -- ND ug/L 03/21/18 1.1 10.0 -- ND 2.32 J ND 9.96 J 9.52 J ND ND ND 2.10 J ND ug/L 09/23/18 1.4 10.0 -- ND ND 5.08 J 3.88 J 7.03 J ND ND ND -- ND ug/L 03/26/19 1.4 10.0 -- ND ND 8.52 J 17.0 7.38 J ND ND ND 2.32 J ND (dissolved) ug/L 03/26/19 1.4 10.0 -- -- -- -- 17.6 -- -- -- -- -- ND ug/L 09/18/19 1.4 10.0 -- ND ND 4.89 J 7.39 J 6.08 J ND ND ND -- ND ug/L 03/16/20 1.4 10.0 -- ND ND 5.48 J 5.77 J 10.3 ND ND ND 2.72 J ND ug/L 09/23/20 1.4 10.0 -- ND ND 2.44 J 7.61 J 6.36 J ND ND ND -- ND ug/L 03/15/21 1.4 10.0 -- ND ND 6.67 J 8.47 J 5.62 J ND ND ND 2.70 J ND ug/L 09/20/21 1.4 10.0 -- ND ND ND 14.8 4.48 J ND ND ND -- ND ug/L 03/14/22 1.4 10.0 -- ND ND ND 10.8 12.3 ND ND ND 1.96 J ND ug/L 09/19/22 1.4 10.0 -- ND ND ND 9.07 J 4.95 J ND ND ND -- ND u /L 03/20/23 1.4 10.0 -- ND 2.12 J 2.24 J 14.4 5.58 J ND ND ND ND ND Copper ug/L 12/05/94 -- -- -- ND ND 19 ND -- -- -- -- ND -- NC 2L = 1000 ug/L ug/L 02/14/95 -- -- -- 10 ND ND ND -- -- -- -- 16 -- EPA MCL = 1300 ug/L' ug/L 04/03/95 -- -- -- ND ND 13 12 -- -- -- -- 14 -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- 13 -- ND ND -- -- -- -- 10 -- ug/L 04/15/97 -- -- -- 20 -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- 20 ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 12.4 12.8 4.23 J 5.28 J 5.41 J 5.15 J -- -- 9.92 J ND ug/L 10/02/07 -- -- -- 33.9 16.7 B 6.61 B 7.24 B 9.14 B 6.91 B -- -- 5.94 B 6.41 J ug/L 04/03/08 -- -- -- 23.4 23.9 4.54 B 6.53 B 5.54 B 5.75 B 5.89 B 10.6 B 4.58 B 4.46 J ug/L 10/29/08 -- -- -- 16.5 145 7.91 J 8.17 J 8.61 9.49 6.93 J 7.82 J 6.28 J ND ug/L 03/24/09 0.81 10.0 -- 2.32 J 4.96 J ND ND ND ND ND ND ND ND ug/L 09/22/09 1.6 10.0 -- 5.15 J 6.17 J ND ND ND ND ND ND -- ND ug/L 03/22/10 1.6 10.0 -- 1.84 J Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 1.6 10.0 -- 1.77 J ND ND 9.93 J ND ND ND ND -- ND ug/L 03/16/11 1.6 10.0 -- 9.85 J 6.75 J ND 2.99 J 1.73 J 1.66 J 4.98 J ND -- ND ug/L 09/21/11 1.6 10.0 -- 4.10 J 12.8 ND 14.2 ND ND ND ND -- ND ug/L 03/21/12 1.6 10.0 -- 8.77 J ND ND 2.96 J ND ND ND ND ND ND ug/L 09/20/12 1.6 10.0 -- 1.77 J 3.29 J ND 2.54 J ND ND ND ND -- ND ug/L 03/20/13 1.6 10.0 -- 9.21 J 5.01 J 1.84 J 2.57 J ND 1.99 J ND ND ND ND ug/L 09/18/13 1.6 10.0 -- 5.69 J 9.55 J ND ND ND ND 1.99 J ND -- ND ug/L 03/27/14 1.6 10.0 -- ND 2.51 J ND 2.75 J ND ND ND ND ND ND ug/L 09/18/14 1.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 1.6 10.0 -- 2.54 B ND ND ND ND ND ND ND 2.90 B 1.74 J ug/L 09/23/15 1.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 1.6 10.0 -- ND ND ND ND ND ND ND ND ND 2.01 J ug/L 09/21/16 1.6 10.0 -- 1.65 B ND ND 4.19 B 1.94 B 2.20 B 1.73 B 1.95 B -- 3.37 J ug/L 03/21/17 1.6 10.0 -- ND ND ND ND ND ND ND ND ND 1.97 J ug/L 09/20/17 1.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 1.6 10.0 -- 1.72 B ND ND ND ND ND ND ND ND 1.87 J ug/L 09/23/18 1.6 10.0 -- ND ND ND ND 1.98 J ND ND ND -- ND ug/L 03/26/19 1.6 10.0 -- ND 2.42 J ND ND ND 2.66 J ND ND ND ND ug/L 09/18/19 1.6 10.0 -- 1.78 B 1.81 B ND ND 1.65 B 2.21 B ND ND -- 5.73 J ug/L 03/16/20 1.6 10.0 -- ND ND ND ND ND ND ND 3.88 B 1.82 B 2.00 ug/L 09/23/20 1.6 10.0 -- 2.14 B 1.73 B ND ND 3.13 B ND ND 1.81 B -- 2.42 J ug/L 03/15/21 1.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 1.6 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 1.6 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 1.6 10.0 -- ND ND ND ND ND ND ND ND -- 1.85 J u /L 03/20/23 3.2 20.0 -- ND 8.05 J ND ND ND ND ND ND 14.8 J ND Lead ug/L 12/05/94 -- -- -- ND 7 27 7 -- -- -- -- ND -- NC 2L = 15 ug/L ug/L 02/14/95 -- -- -- ND 10 5 ND -- -- -- -- ND -- EPA MCL = 15 ug/L' ug/L 04/03/95 -- -- -- ND 12 ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- 7 19 ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND 6 ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- 8 -- 7 ND -- -- -- -- 13 -- ug/L 04/15/97 -- -- -- 13 -- ND 12 -- -- -- -- 12 -- ug/L 10/29/97 -- -- -- 9 36 5 11 -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 14.4 ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 11.9 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- 24 ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND 61.3 ND 17.4 ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 11.9 ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 12.7 ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND 6.56 J 3.69 J ND 3.14 J ND -- -- 1.9 J ND ug/L 10/02/07 -- -- -- 69.2 J 7.18 J 1.39 B 0.9 B 0.80 B 0.56 B -- -- 0.57 B 0.49 J ug/L 04/03/08 -- -- -- 75.8 J 16.4 ND 8 J 6.43 J 3.78 J 6.16 J 12.5 6.23 J ND ug/L 10/29/08 -- -- -- 75.9 J 84.7 7.72 J 6.83 J 9.41 9.08 8.50 J 6.93 J 4.54 J ND ug/L 03/24/09 1.6 10.0 -- 3.3 J 5.6 J 1.6 J 6.2 J 2.5 J 1.6 J 3.1 J ND ND ND ug/L 09/22/09 1.9 10.0 -- 3.52 J 2.55 J ND 3.17 J 2.50 J ND 3.96 J 1.95 J -- ND ug/L 03/22/10 1.9 10.0 -- ND Dry ND 2.20 J ND ND ND ND -- ND ug/L 09/23/10 1.9 10.0 -- ND ND ND 12.2 ND ND ND ND -- ND ug/L 03/16/11 1.9 10.0 -- 4.92 J ND ND 3.40 J ND ND 25.6 2.69 J -- ND ug/L 09/21/11 1.9 10.0 -- ND 15.5 3.27 J 18.5 2.57 J ND ND ND -- ND ug/L 03/21/12 1.9 10.0 -- 4.38 J ND ND ND ND ND ND ND ND ND ug/L 09/20/12 1.9 10.0 -- 2.53 B 3.10 B 4.18 B 5.91 B 4.90 B 4.40 B 4.82 B 3.00 B -- 2.70 J ug/L 03/20/13 1.9 10.0 -- ND ND 3.46 J ND ND ND ND ND ND ND ug/L 09/18/13 2.1 10.0 -- ND 17.4 ND ND ND ND 6.58 J ND -- ND ug/L 03/27/14 2.1 10.0 -- ND 2.26 J ND 2.33 J ND ND ND ND ND ND ug/L 09/18/14 2.1 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 2.1 10.0 -- ND ND 3.32 J ND ND ND ND ND ND ND ug/L 09/23/15 2.1 10.0 -- ND ND ND ND 3.10 J ND 3.15 J ND -- ND ug/L 03/17/16 2.1 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 3.1 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 3.1 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/17 3.1 10.0 -- ND 3.45 J ND ND 3.75 J ND ND 3.40 J -- ND ug/L 03/21/18 3.1 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 3.1 10.0 -- ND ND ND ND ND ND ND ND -- 8.83 J ug/L 03/26/19 3.1 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 3.1 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 3.1 10.0 -- ND ND ND ND ND ND ND 4.32 J ND ND ug/L 09/23/20 3.1 10.0 -- ND ND ND 3.71 J ND ND ND ND -- ND ug/L 03/15/21 3.1 10.0 -- ND ND ND 3.21 J ND ND ND ND ND ND ug/L 09/20/21 3.1 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 3.1 10.0 -- 4.24 J ND ND ND ND ND ND ND ND ND ug/L 09/19/22 3.1 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/23 6.6 10.0 -- ND ND ND ND ND ND ND ND ND ND 3of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Mercury ug/L 10/30/95 -- -- -- 0.5 ND 0.9 0.9 -- -- -- -- 0.8 -- NC 2L = 1 ug/L ug/L 10/24/96 -- -- -- 0.7 -- ND ND -- -- -- -- ND -- EPA MCL = 2 ug/L ug/L 10/29/97 -- -- -- ND ND 1.9 0.8 -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND 2 0.2 -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND 0.2 -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND 0.5 ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND 0.4 ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND 1.0 ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND 0.4 ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND 0.3 0.3 -- ND -- -- 0.3 -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND 0.3 ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND 0.3 ND ND ND -- -- 0.3 -- ug/L 10/20/03 -- -- -- ND ND 0.45 ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND 0.73 0.258 ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND 0.91 ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND 0.72 -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND ND 0.134 J 0.242 J ND ND -- -- ND ND ug/L 10/02/07 -- -- -- ND ND ND 0.709 ND ND -- -- ND ND ug/L 04/03/08 -- -- -- ND ND ND 0.489 ND ND ND ND ND ND ug/L 10/29/08 -- -- -- ND 0.145 J ND 0.503 ND ND ND ND ND ND ug/L 03/24/09 0.11 0.200 -- ND ND ND 1.33 ND ND ND ND 0.14 J ND ug/L 09/22/09 0.054 0.200 -- ND ND 0.0926 J 0.419 -- -- -- -- -- ND ug/L 03/22/10 0.054 0.200 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.17 0.200 -- ND ND ND 0.371 ND ND ND ND -- ND (dissolved) ug/L 09/23/10 0.17 0.200 -- -- -- -- ND -- -- -- -- -- -- ug/L 03/16/11 0.17 0.200 -- ND ND ND ND ND ND 0.178 J ND -- ND ug/L 09/21/11 0.17 0.200 -- ND ND ND 0.683 ND ND 0.225 ND -- ND ug/L 03/21/12 0.17 0.200 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/20/12 0.17 0.200 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.17 0.200 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/18/13 0.17 0.200 -- ND ND ND ND ND ND 0.302 ND -- ND ug/L 03/27/14 0.17 0.200 -- ND ND ND ND ND ND 0.308 ND -- ND ug/L 09/18/14 0.17 0.200 -- ND ND ND ND ND ND 1.53 ND -- ND ug/L 03/18/15 0.17 0.200 -- ND ND ND ND ND ND 1.49 ND -- ND ug/L 09/23/15 0.17 0.200 -- ND ND ND ND ND ND 0.226 ND -- ND ug/L 03/17/16 0.17 0.200 -- ND ND ND ND ND ND 0.527 ND -- ND ug/L 09/21/16 0.17 0.200 -- ND ND ND ND ND ND 0.810 ND -- ND ug/L 03/21/17 0.17 0.200 -- ND ND ND ND ND ND 0.213 ND -- ND ug/L 09/20/17 0.0990 0.200 -- ND ND ND ND ND ND 0.474 ND -- ND ug/L 03/21/18 0.15 0.200 -- ND ND ND ND ND ND 1.12 ND -- ND (verification event) ug/L 06/15/18 0.15 0.200 -- -- -- -- -- -- -- 0.517 -- -- ND (dissolved) ug/L 06/15/18 0.15 0.200 -- -- -- -- -- -- -- ND -- -- ND ug/L 09/23/18 0.15 0.200 -- ND ND ND ND ND ND 0.313 ND -- ND ug/L 03/26/19 0.15 0.200 -- ND ND ND ND ND ND 0.379 ND 0.164 J ND ug/L 09/18/19 0.15 0.200 -- ND ND ND ND ND ND 0.487 ND -- ND ug/L 03/16/20 0.15 0.200 -- ND ND ND ND ND 0.156 J 0.268 ND -- ND ug/L 09/23/20 0.15 0.200 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.15 0.200 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/20/21 0.15 0.200 -- ND ND 0.189 J ND ND ND ND ND -- ND ug/L 03/14/22 0.15 0.200 -- ND ND ND ND ND ND 0.430 ND -- ND ug/L 09/19/22 0.15 0.200 -- ND ND ND ND ND ND 0.227 ND -- ND u /L 03/20/23 0.08 0.200 -- ND ND ND 1.04 ND ND ND ND -- ND Nickel ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 100 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND 1.61 J ND ND ND ND -- -- ND ND ug/L 10/02/07 -- -- -- 2.75 B 9.04 J 0.67 B 0.9 B 4.65 J 8.72 J -- -- 0.24 B 0.8 J ug/L 04/03/08 -- -- -- ND ND ND ND ND ND 5.89 J 7.09 J ND ND ug/L 10/29/08 -- -- -- ND 47.3 J ND ND 8.13 J 7.57 J 6.40 J 4.99 J ND ND ug/L 03/24/09 0.6 10.0 -- ND 3.9 J ND 2.8 J 2.5 J 0.9 J 2.2 J ND ND ND ug/L 09/22/09 1.8 10.0 -- ND 3.77 J ND ND 2.54 J 2.04 J ND ND -- ND ug/L 03/22/10 1.8 10.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 1.8 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 1.8 10.0 -- ND 2.28 J ND ND ND ND ND ND -- ND ug/L 09/21/11 1.8 10.0 -- ND 4.59 J ND ND 2.04 J ND ND ND -- ND ug/L 03/21/12 1.8 10.0 -- ND 3.62 J ND ND 3.14 J ND ND ND ND ND ug/L 09/20/12 1.8 10.0 -- ND ND ND ND 2.62 J ND ND ND -- ND ug/L 03/20/13 1.8 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 1.8 10.0 -- ND 8.99 J 4.74 J ND ND ND ND ND -- ND ug/L 03/27/14 1.8 10.0 -- ND 1.80 J ND ND ND ND ND ND ND ND ug/L 09/18/14 1.8 10.0 -- ND 6.47 J ND ND ND ND ND ND -- ND ug/L 03/18/15 1.8 10.0 -- ND ND 2.55 J ND 2.22 J ND ND ND ND ND ug/L 09/23/15 1.8 10.0 -- ND 6.60 B ND 3.03 B 2.84 B ND ND ND -- 2.22 J ug/L 03/17/16 1.8 10.0 -- ND 4.55 J ND ND ND ND ND ND ND ND ug/L 09/21/16 2.2 10.0 -- ND 2.93 J ND 4.55 J 2.21 J 2.87 J ND ND -- ND ug/L 03/21/17 2.2 10.0 -- 4.77 B 3.44 B 2.65 B 3.16 B 4.33 B 2.57 B 2.24 B 2.32 B 1.76 B 2.69 J ug/L 09/20/17 2.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 2.2 10.0 -- ND 3.42 J ND ND ND ND ND ND ND ND ug/L 09/23/18 2.2 10.0 -- ND ND ND 2.61 B 2.36 B ND ND ND -- 10.1 ug/L 03/26/19 2.2 10.0 -- ND 57.1 2.98 J ND 3.79 J ND ND ND ND ND ug/L 09/18/19 2.2 10.0 -- ND 4.32 J ND ND ND ND ND ND -- ND ug/L 03/16/20 2.2 10.0 -- ND ND ND ND 2.56 J 2.51 J ND 27.1 ND ND ug/L 09/23/20 2.2 10.0 -- ND ND ND ND 2.91 J ND ND 7.85 J -- ND ug/L 03/15/21 2.2 10.0 -- ND ND ND ND ND ND ND 2.99 J 5.01 J ND ug/L 09/20/21 2.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 2.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 2.2 10.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 3.3 40.0 -- ND 5.35 J ND ND ND ND ND ND ND ND Selenium ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 20 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 50 ug/L ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 61.1 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 24.7 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- 20.6 -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 25.3 ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND 26.6 ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND 23.4 ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 9.46 J 23.4 10.7 J ND ND ND -- -- ND ND ug/L 10/02/07 -- -- -- ND 7.49 J ND 11.1 ND ND -- -- 8.68 J ND ug/L 04/03/08 -- -- -- ND 10.7 ND ND 10.9 ND 9.54 J 7.51 J ND ND ug/L 10/29/08 -- -- -- ND 37.5 ND ND 1.94 ND ND ND ND ND ug/L 03/24/09 3.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 2.7 10.0 -- 6.68 B ND 8.38 B 4.55 B ND 7.33 B 4.11 B 5.98 B -- 6.41 J ug/L 03/22/10 0.83 1.00 -- ND Dry ND ND 0.962 J ND ND ND -- ND ug/L 09/23/10 5.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 2.7 10.0 -- ND ND ND ND 5.08 B ND ND ND -- 3.32 J ug/L 09/21/11 2.7 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/12 2.7 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 2.7 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 4.5 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 5.0 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/27/14 5.0 10.0 -- ND ND ND ND ND ND ND ND 5.67 (ND) J ND ug/L 09/18/14 5.0 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 5.0 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 5.0 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 5.0 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 6.2 10.0 -- ND ND ND ND ND ND ND ND ND 14.1 J ug/L 09/20/17 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 6.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 6.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 6.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 6.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 6.2 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 6.2 10.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 10.0 20.0 -- ND ND ND ND ND ND ND ND ND ND 4of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Silver ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 20 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- 11 -- EPA MCL = 100 ug/L ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- 0.9 -- 0.9 0.7 -- -- -- -- 0.3 -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 11.3 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND 0.64 J 3.42 J 0.5 J 1.14 J 0.46 J -- -- 3.18 J ND ug/L 10/02/07 -- -- -- ND 1.82 J 0.91 J ND 0.86 J ND -- -- ND ND ug/L 04/03/08 -- -- -- ND 0.97 J 2.04 J ND 0.94 J ND 1.48 J ND ND ND ug/L 10/29/08 -- -- -- 4.74 J 6.91 J 5.23 J 5.00 J 6.32 J 5.19 J 4.91 J 4.33 J 5.24 J ND ug/L 03/24/09 1.0 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 1.9 10.0 -- ND ND ND ND 2.24 J ND ND ND -- ND ug/L 03/22/10 1.9 10.0 -- ND Dry ND 3.34 J ND ND ND ND -- ND ug/L 09/23/10 1.9 10.0 -- ND 2.52 J ND 3.05 J ND ND ND ND -- ND ug/L 03/16/11 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 1.9 10.0 -- ND 3.73 J ND 2.33 J ND ND ND ND -- ND ug/L 03/21/12 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 1.9 10.0 -- ND ND 7.00 B 3.58 B 3.31 B ND 2.17 B ND ND 2.11 J ug/L 09/18/13 1.9 10.0 -- ND 2.92 J 4.35 J 2.07 J ND ND ND ND -- ND ug/L 03/27/14 1.9 10.0 -- ND ND 1.98 J ND ND ND ND ND ND ND ug/L 09/18/14 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 1.9 10.0 -- ND ND 4.00 J ND 2.05 J ND ND ND ND ND ug/L 09/23/15 1.9 10.0 -- ND 6.68 B 1.97 B 3.26 B ND ND ND ND -- 4.69 J ug/L 03/17/16 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.9 10.0 -- ND ND ND 9.23 J ND ND ND ND -- ND ug/L 03/21/17 1.9 10.0 -- ND ND 1.06 B 0.849 B ND 1.23 B ND ND 1.04 B 0.823 J ug/L 09/20/17 1.9 10.0 -- ND ND ND 2.26 J ND ND ND ND -- ND ug/L 03/21/18 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 1.9 10.0 -- ND ND ND 2.68 J ND ND ND ND ND ND ug/L 09/20/21 1.9 10.0 -- ND ND ND 11.4 ND ND ND ND -- ND ug/L 03/14/22 1.9 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 1.9 10.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 1.5 10.0 -- ND ND ND ND ND ND ND ND 1.59 J ND Thallium ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 2 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA IMAC= 2 ug/L ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- 1 1 1 1 -- -- -- -- 2 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- 13.7 ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/21/01 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 22.4 ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND 77.1 22 -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND 58.5 54.6 17.8 ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND 81.3 24.2 ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- ND ND 24 ND ND ND -- -- ND ND ug/L 10/02/07 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 04/03/08 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 10/29/08 -- -- -- ND 8.90 ND 6.97 9.61 ND -- -- ND ND ug/L 03/24/09 0.036 1.00 -- 0.051 B 0.090 B 0.080 B 0.242 B 0.280 B ND ND ND ND 0.092 J ug/L 09/22/09 0.11 1.00 -- ND ND ND 0.404 J 0.212 J ND ND ND -- ND ug/L 03/22/10 0.11 1.00 -- ND Dry 0.118 J 0.620 J 0.169 J ND ND ND -- ND ug/L 09/23/10 0.11 1.00 -- ND ND 0.124 J 1.18 J ND ND ND ND -- ND ug/L 03/16/11 0.11 1.00 -- ND ND 0.516 J 1.12 J 0.274 J 0.491 J 0.514 J ND -- ND ug/L 09/21/11 0.11 1.00 -- ND ND ND 1.53 J ND ND ND ND -- ND ug/L 03/21/12 0.11 1.00 -- ND ND 0.119 J 1.31 J 0.418 J ND ND ND ND ND ug/L 09/20/12 0.11 1.00 -- ND 0.144 J 0.155 J 1.09 J 0.512 J ND ND ND -- ND ug/L 03/20/13 0.11 1.00 -- 0.117 J ND 0.413 J 0.659 J 0.487 J ND ND ND ND ND ug/L 09/18/13 0.11 1.00 -- ND 0.127 B 0.604 B 0.609 B 0.459 B ND ND ND -- 0.142 J ug/L 03/27/14 0.11 1.00 -- ND 0.131 J 0.171 J 0.637 J 0.340 J ND ND ND ND ND ug/L 09/18/14 0.11 1.00 -- ND ND 0.145 J 0.815 J 0.663 J ND ND ND -- ND ug/L 03/18/15 0.11 1.00 -- ND ND 0.281 J 0.605 J 0.514 J ND ND ND ND ND ug/L 09/23/15 0.11 1.00 -- ND ND 0.225 J 0.907 J 0.550 J ND ND ND -- ND ug/L 03/17/16 0.11 1.00 -- ND ND 0.377 J 0.400 J 0.552 J ND ND ND ND ND ug/L 09/21/16 0.11 1.00 -- ND ND 0.427 J 0.553 J 0.699 J ND ND ND -- ND ug/L 03/21/17 0.11 1.00 -- 0.153 J 0.175 J 0.369 J 1.25 J 0.921 J 0.309 J 0.364 J 0.290 J 0.189 J ND ug/L 09/20/17 0.11 1.00 -- 0.386 J 0.281 J 0.446 J 0.896 J 0.945 J 0.392 J 0.409 J 0.329 J -- ND ug/L 03/21/18 0.55 5.00 -- ND ND ND 0.828 J 1.08 J ND ND ND ND ND ug/L 09/23/18 0.55 5.00 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.22 2.00 -- ND ND 0.565 J 0.344 J 0.547 J ND ND ND ND ND ug/L 09/18/19 0.22 2.00 -- ND ND 0.376 J 0.485 J 0.322 J ND ND ND -- ND ug/L 03/16/20 0.22 2.00 -- ND ND 0.489 J 0.539 J 0.533 J ND ND ND ND ND ug/L 09/23/20 0.22 2.00 -- ND ND 0.335 J 0.480 J 0.365 J ND ND ND -- ND ug/L 03/15/21 0.22 2.00 -- ND ND 0.406 J 0.426 J 0.292 J ND ND ND ND ND ug/L 09/20/21 0.22 2.00 -- ND ND 0.318 J 0.298 J 0.259 J ND ND ND -- ND ug/L 03/14/22 0.22 2.00 -- ND ND 0.240 J ND 0.353 J ND ND ND ND ND ug/L 09/19/22 0.22 2.00 -- ND ND 0.358 J ND 0.423 J ND ND ND -- ND u /L 03/20/23 0.26 1.00 -- ND ND 0.265 J ND 0.280 J ND ND ND ND ND Tin ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 2000 ug/L ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 10/29/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 03/24/09 1.1 10.0 -- ND ND 1.4 J 5.4 J 1.3 J 2.0 J 1.5 J ND ND ND ug/L 03/22/10 2.1 10.0 -- ND Dry ND 2.38 J -- -- -- -- -- ND ug/L 03/16/11 2.1 10.0 -- 2.50 J 3.17 J 5.65 J 7.24 J -- -- -- -- -- ND ug/L 03/21/12 2.1 10.0 -- ND 3.86 J 3.42 J 4.51 J -- -- -- -- -- ND ug/L 03/20/13 2.1 10.0 -- ND 3.86 J 3.79 J 6.88 J -- -- -- -- -- ND ug/L 03/27/14 2.1 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 2.1 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 2.1 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 2.1 10.0 -- ND 9.06 J 7.24 J 8.42 J -- -- -- -- -- ND ug/L 03/21/18 2.1 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 2.9 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/16/20 2.9 10.0 -- ND ND ND ND -- -- -- -- -- 4.38 J ug/L 03/15/21 2.9 10.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 2.9 10.0 -- ND ND ND ND - - - - - ND u /L 03/20/23 11.0 50.0 -- ND ND ND ND -- -- -- -- - ND Vanadium ug/L 12/05/94 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 7 ug/L ug/L 02/14/95 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- 13 -- ND 5 -- -- -- -- 6 -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 3.81 J 4.21 J ND 1.31 J ND ND -- -- ND ND ug/L 10/02/07 -- -- -- 17.1 J 12.9 J 5.6 J ND ND ND -- -- ND ND ug/L 04/03/08 -- -- -- 9.73 J 10.7 J ND ND ND ND ND 5.13 J ND ND ug/L 10/29/08 -- -- -- 4.88 J 88.9 10.3 J 0.52 J 1.37 J 3.74 J 0.86 J ND ND ND ug/L 03/24/09 0.7 10.0 -- 2.2 J 3.2 J 1.7 J 9.0 J ND ND 3.0 J 0.9 J 0.7 J ND ug/L 09/22/09 1.4 10.0 -- 3.31 J 1.97 J ND 5.45 J ND ND 6.35 J 1.52 J -- ND ug/L 03/22/10 1.4 10.0 -- 1.75 J Dry ND 1.76 J ND ND 1.78 J 1.42 J -- ND ug/L 09/23/10 1.4 10.0 -- ND ND ND 14.7 J ND ND 4.79 J ND -- ND ug/L 03/16/11 1.4 10.0 -- 4.98 J 2.77 J ND ND ND ND 15.3 J ND -- ND ug/L 09/21/11 1.4 10.0 -- 2.21 J 8.14 J 2.88 J 17.3 J ND ND 11.1 J ND -- ND ug/L 03/21/12 1.4 10.0 -- 4.72 J ND ND ND ND ND 1.70 J ND ND ND ug/L 09/20/12 1.4 10.0 -- 1.79 J 1.77 J ND 4.28 J ND ND 3.65 J ND -- ND ug/L 03/20/13 1.4 10.0 -- 5.60 J 2.36 J ND 2.47 J ND ND ND ND ND ND ug/L 09/18/13 1.4 10.0 -- 2.71 J 12.4 J ND ND ND ND 9.96 J ND -- ND ug/L 03/27/14 1.4 10.0 -- ND 1.93 J ND ND ND ND 5.88 J ND ND ND ug/L 09/18/14 1.4 10.0 -- ND ND ND ND ND ND 4.57 J ND -- ND ug/L 03/18/15 1.4 10.0 -- ND ND ND ND ND ND 7.02 J ND 1.53 J ND ug/L 09/23/15 1.4 10.0 -- 1.51 J 1.43 J ND ND ND ND 1.69 J 1.45 J -- ND ug/L 03/17/16 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.4 10.0 -- ND ND ND 3.10 J ND ND 2.05 J ND -- ND ug/L 03/21/17 1.4 10.0 -- 19.9 J 1.96 B ND 2.51 B 0.807 B ND 0.903 B 1.05 B ND 0.589 J ug/L 09/20/17 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 1.4 10.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 1.4 10.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 1.0 10.0 -- ND 5.52 J ND ND 3.32 J ND ND ND ND ND 5of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-11D AMW-2S AMW-2D MW-9 Zinc ug/L 12/05/94 -- -- -- 21 ND 33 20 -- -- -- -- 82 -- NC 2L = 1000 ug/L ug/L 02/14/95 -- -- -- 33 44 29 69 -- -- -- -- 113 -- EPA MCL = 5000 ug/L* ug/L 04/03/95 -- -- -- 29 48 26 29 -- -- -- -- 20 -- ug/L 10/30/95 -- -- -- 25 30 ND ND -- -- -- -- 23 -- ug/L 04/08/96 -- -- -- 44 63 22 67 -- -- -- -- 36 -- ug/L 10/24/96 -- -- -- 37 -- 22 18 -- -- -- -- 39 -- ug/L 04/15/97 -- -- -- 50 -- 50 30 -- -- -- -- 40 -- ug/L 10/29/97 -- -- -- ND 340 ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND 20.6 -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- -- 15.6 J 124 6.92 J 10.1 J 12.1 J 3.82 J -- -- 7.14 J ND ug/L 10/02/07 -- -- -- 44 49.1 12.6 J 5.43 J 6.23 J ND -- -- 4.53 J ND ug/L 04/03/08 -- -- -- 31.9 46 5.82 J 10.4 4.83 J 4.06 J 14.1 27.7 5.53 J ND ug/L 10/29/08 -- -- -- 20.1 380 29.0 6.90 J 5.37 J ND 5.37 J ND 6.63 J ND ug/L 03/24/09 3.4 10.0 -- 10.7 B 56.3 9.3 B 38.3 4.1 B 3.4 B 7.7 B ND 4.1 B 3.4 J ug/L 09/22/09 3.8 10.0 -- 13.8 12.3 4.56 J 12.8 7.02 J 5.92 J 18.0 8.77 J -- ND ug/L 03/22/10 3.8 10.0 -- 9.18 J Dry 8.52 J 36.7 15.6 7.21 J 11.2 7.25 J -- ND ug/L 09/23/10 3.8 10.0 -- ND ND 5.37 J 168 4.30 J 5.86 J ND ND -- ND ug/L 03/16/11 3.8 10.0 -- 17.6 36.7 7.03 J 611 4.64 J 17.5 44.8 4.77 J -- ND ug/L 09/21/11 3.8 10.0 -- 9.32 J 44.1 9.85 J 430 4.44 J 11.7 14.2 4.57 J -- ND ug/L 03/21/12 3.8 10.0 -- 14.9 28.8 ND 48.3 ND 6.06 J ND ND ND ND ug/L 09/20/12 3.8 10.0 -- 5.18 J 6.60 J ND 173 6.69 J 5.19 J 4.68 J 3.87 J -- ND ug/L 03/20/13 3.8 10.0 -- 21.3 12.5 6.76 J 60.1 9.19 J 6.32 J ND 5.00 J 12.0 ND ug/L 09/18/13 3.8 10.0 -- 12.0 45.7 5.04 J 40.5 4.40 J ND 27.3 ND -- ND ug/L 03/27/14 3.8 10.0 -- ND 11.3 ND 79.6 4.19 J 4.92 J 8.80 J ND ND ND ug/L 09/18/14 3.8 10.0 -- ND 8.37 J ND 16.8 ND 22.7 ND ND -- ND ug/L 03/18/15 3.8 10.0 -- 5.35 J 7.19 J 9.75 J 21.7 4.58 J 6.15 J 6.87 J ND 12.2 ND ug/L 09/23/15 3.8 10.0 -- ND ND ND 28.6 ND 5.53 J ND ND -- ND ug/L 03/17/16 3.8 10.0 -- ND 32.2 ND 117 5.20 J ND ND ND ND ND ug/L 09/21/16 4.4 10.0 -- ND ND ND 28.5 ND ND ND ND -- ND ug/L 03/21/17 4.4 10.0 -- ND ND ND 80.3 ND ND ND ND ND ND ug/L 09/20/17 4.4 10.0 -- ND ND 5.35 J 76.5 ND ND ND ND -- ND ug/L 03/21/18 4.4 10.0 -- 4.40 J 17.7 ND 169 ND ND ND ND ND ND ug/L 09/23/18 4.4 10.0 -- ND ND ND 131 B ND ND ND ND -- 64.2 ug/L 03/26/19 4.4 10.0 -- 7.04 J 319 ND 109 ND 4.83 J ND ND ND ND ug/L 09/18/19 4.4 10.0 -- ND 5.24 J 4.52 J 24.0 5.23 J 7.42 J ND ND -- ND ug/L 03/16/20 4.4 10.0 -- ND ND ND 60.0 4.89 J 4.60 J ND 257 6.48 J ND ug/L 09/23/20 4.4 10.0 -- ND ND ND 22.0 5.10 J 6.25 J ND ND -- ND ug/L 03/15/21 4.4 10.0 -- ND ND ND 55.6 ND ND ND ND ND ND ug/L 09/20/21 4.4 10.0 -- ND ND ND 12.2 ND 7.88 J ND ND -- ND ug/L 03/14/22 4.4 10.0 -- ND 7.60 J ND 12.3 ND 4.64 J ND ND ND ND ug/L 09/19/22 4.4 10.0 -- ND ND ND 18.8 ND 8.88 J 80.6 ND -- ND u /L 03/20/23 8.7 20.0 -- ND 19.3 J ND ND ND ND ND ND ND ND Acetone ug/L 12/05/94 100 100 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 6000 ug/L ug/L 02/14/95 100 100 -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 100 100 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 100 100 -- ND 50 ND ND -- -- -- -- ND -- ug/L 04/08/96 100 100 -- ND 98 ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 95 ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 330 ND ND -- -- -- -- ND -- ug/L 11/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 780 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND 190 ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 100 100 -- ND ND ND ND -- ND -- -- ND -- ug/L 04/25/02 100 100 -- ND 190 ND ND ND ND -- -- ND -- ug/L 10/01/02 100 100 -- ND 280 ND ND ND ND -- -- ND -- ug/L 04/09/03 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/21/03 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 03/25/04 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 100 100 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/06/05 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/26/06 100 100 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 100 100 -- ND ND ND ND ND ND -- -- ND ND ug/L 03/22/07 100 100 -- ND ND 4.34 J ND ND ND -- -- ND ND ug/L 10/02/07 100 100 -- ND 9.81 B ND ND 1.76 B ND -- -- ND 5.5 J ug/L 04/03/08 100 100 -- ND 10.1 J ND ND ND ND ND ND ND ND ug/L 10/30/08 100 100 -- ND 13.8 J ND ND 7.95 J ND ND ND ND ND ug/L 03/24/09 1.5 5.0 -- ND 280 ND ND ND ND ND ND ND ND ug/L 09/22/09 1.5 5.0 -- ND 9.0 J 13 J ND ND ND ND ND -- ND ug/L 03/22/10 1.5 5.0 -- ND Dry 55 J ND ND ND ND ND -- ND ug/L 09/23/10 1.5 5.0 -- ND 8.7 J ND ND ND ND ND ND -- ND ug/L 03/16/11 1.2 5.0 -- ND 16 J ND ND ND ND ND ND -- ND ug/L 09/21/11 1.2 5.0 -- ND 310 ND ND ND ND ND ND -- ND ug/L 03/21/12 1.2 5.0 -- ND 2700 3.6 J 13 J ND ND ND ND ND ND ug/L 09/20/12 1.2 5.0 -- ND ND ND 5.4 B ND ND ND ND -- 7.0 J ug/L 03/20/13 1.2 5.0 -- ND 21 J ND ND ND ND ND ND ND ND ug/L 09/18/13 1.2 5.0 -- ND 34 J ND ND ND ND ND ND -- ND ug/L 03/27/14 1.2 5.0 -- ND 77 B ND 6.2 B ND ND ND ND ND 19 J ug/L 09/18/14 1.2 5.0 -- ND 24 J ND ND ND ND ND ND -- ND ug/L 03/18/15 1.2 5.0 -- ND 29 J ND ND ND ND ND ND ND ND ug/L 09/23/15 1.2 5.0 -- ND ND ND 4.9 J ND ND ND ND -- ND ug/L 03/17/16 1.2 5.0 -- ND ND ND ND ND ND ND 4.5 J ND ND ug/L 09/21/16 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 10 20 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 10 20 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 10 20 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 10 20 -- ND ND 20 B ND ND ND ND ND ND 12 J ug/L 09/18/19 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 10 20 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 10 20 -- ND ND ND 17 B ND ND ND ND -- 16 J ug/L 03/15/21 10 20 -- ND ND 38 ND ND ND ND ND ND ND ug/L 09/20/21 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 10 20 -- ND ND ND ND ND ND ND ND ND 10 J ug/L 09/19/22 10 20 -- ND ND ND 16 J ND ND ND ND -- ND u /L 03/20/23 10 20 -- ND 288 ND ND ND ND ND ND ND ND Benzene ug/L 12/05/94 5 5 -- ND 11 ND ND -- -- -- -- ND -- NC 2L = 1 ug/L ug/L 02/14/95 5 5 -- ND 11 ND ND -- -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 5 5 -- ND 8 ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND 9 3.9 ND -- -- -- -- ND -- ug/L 10/24/96 5 5 -- ND -- 5 ND -- -- -- -- ND -- ug/L 04/15/97 5 5 -- ND -- 6.9 ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 5 6 ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 8 6 ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND 7 ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 8 6 ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 6 ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 7 ND ND ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND 6 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 7.19 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 7.61 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 6.23 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 6.8 ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 1.36 2.48 3.55 0.44 J 1.52 -- -- ND ND ug/L 10/02/07 5 5 -- ND 5.47 1.70 4.99 1.68 1.55 -- -- ND ND ug/L 04/03/08 5 5 -- ND 0.37 J 1.57 5.82 0.98 J 1.48 1.28 ND ND ND ug/L 10/29/08 5 5 -- ND 3.08 1.51 6.23 2.13 1.49 1.25 ND ND ND ug/L 03/24/09 0.20 1.0 -- ND ND ND 0.64 J ND ND ND ND ND ND ug/L 09/22/09 0.20 1.0 -- ND ND 1.4 4.2 0.44 J 1.3 1.2 ND -- ND ug/L 03/22/10 0.050 1.0 -- ND Dry 1.4 ND ND 1.1 0.75 J ND -- ND ug/L 09/23/10 0.20 1.0 -- ND 0.98 J ND ND ND ND ND ND -- ND ug/L 03/16/11 0.68 1.0 -- ND ND 1.6 ND ND 1.2 0.96 J ND -- ND ug/L 09/21/11 0.68 1.0 -- ND 4.6 1.4 0.85 J ND 1.2 0.82 J ND -- ND ug/L 03/21/12 0.15 1.0 -- ND ND 1.1 0.65 J 0.73 J 0.95 J 0.82 J ND ND ND ug/L 09/20/12 0.15 1.0 -- ND ND 0.94 J ND ND ND ND ND -- ND ug/L 03/20/13 0.15 1.0 -- ND ND 1.5 3.0 ND 1.2 1.2 ND ND ND ug/L 09/18/13 0.15 1.0 -- ND 2.9 1.7 0.89 J 0.56 J 1.1 0.86 J ND -- ND ug/L 03/27/14 0.15 1.0 -- ND ND 1.6 ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 -- ND 4.6 1.1 ND ND 1.1 0.58 J ND -- ND ug/L 03/18/15 0.15 1.0 -- ND ND 1.3 ND ND 1.2 0.60 J ND ND ND ug/L 09/23/15 0.15 1.0 -- ND 3.7 1.3 ND 1.1 0.83 J 0.66 J ND -- ND ug/L 03/17/16 0.15 1.0 -- ND 1.2 2.4 ND ND 1.2 0.45 J ND ND ND ug/L 09/21/16 0.15 1.0 -- ND 3.5 1.8 ND ND 1.1 0.41 J ND -- ND ug/L 03/21/17 0.15 1.0 -- ND 2.6 1.8 ND ND 0.97 J 0.64 J ND -- ND (re -sample) ug/L 05/03/17 0.15 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.15 1.0 -- ND ND 1.6 ND ND ND ND ND -- ND ug/L 03/21/18 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.15 1.0 -- ND ND ND ND ND 0.71 J ND ND -- ND ug/L 03/26/19 0.15 1.0 -- ND ND 2.5 ND ND 0.47 J ND ND ND ND ug/L 09/18/19 0.15 1.0 -- ND 4.3 ND ND ND 0.68 J ND ND -- ND ug/L 03/16/20 0.15 1.0 -- ND 0.96 J 1.1 ND ND ND ND ND ND ND ug/L 09/23/20 0.15 1.0 -- ND 0.53 J 1.3 ND ND ND ND ND -- ND ug/L 03/15/21 0.15 1.0 -- ND 0.65 J 2.1 ND ND 0.82 J ND ND ND ND ug/L 09/20/21 0.15 1.0 -- ND 2.3 1.4 ND ND 0.94 J ND ND -- ND ug/L 03/14/22 0.15 1.0 -- ND ND 0.93 J ND 1.0 0.60 J ND ND ND ND ug/L 09/19/22 0.15 1.0 -- ND 0.50 J 1.3 ND ND 0.66 J ND ND -- ND u /L 03/20/23 0.15 1.0 -- ND 1.64 J 0.994 J ND 0.226 J 1.05 0.189 J ND ND ND 6of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-11D AMW-2S AMW-2D MW-9 Chlorobenzene ug/L 12/05/94 5 5 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 50 ug/L ug/L 02/14/95 5 5 -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 100 ug/L ug/L 04/03/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 7 3 ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND 8 ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 7 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND 8 -- -- -- ND -- ug/L 11/07/00 -- -- -- ND 7 ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 6 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND 7 ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 6 ND ND 7 ND -- -- ND -- ug/L 10/01/02 -- -- -- ND 8 ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND 6 ND -- -- ND -- ug/L 10/20/03 5 5 -- ND 10 ND ND ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND 11 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 13 5 ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND 6 -- 6.12 ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 13.4 6 ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 10.8 6.02 ND 9.62 ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 9 6 ND 16.2 ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 1.34 5.89 0.59 J 2.83 4.62 -- -- ND ND ug/L 10/02/07 5 5 -- ND 6.16 5.95 0.83 J ND 5.13 -- -- ND ND ug/L 04/03/08 5 5 -- ND 0.30 J 5.72 1.14 J 11.3 5.01 4.50 ND ND ND ug/L 10/29/08 5 5 -- ND 8.02 5.41 1.11 J 23.8 5.09 1.86 J ND ND ND ug/L 03/24/09 0.27 1.0 -- ND ND 4.6 ND 0.46 J 3.8 2.0 J ND ND ND ug/L 09/22/09 0.27 1.0 -- ND ND 5.7 0.75 J 4.9 4.9 1.0 J ND -- ND ug/L 03/22/10 0.069 1.0 -- ND Dry 6.4 ND ND 4.6 0.97 J ND -- ND ug/L 09/23/10 0.27 1.0 -- ND 7.5 6.3 ND ND 4.2 0.55 J ND -- ND ug/L 03/16/11 0.74 1.0 -- ND ND 7.3 ND ND 4.5 1.2 J ND -- ND ug/L 09/21/11 0.74 1.0 -- ND 8.1 8.4 ND 1.4 J 4.6 1.2 J ND -- ND ug/L 03/21/12 0.17 1.0 -- ND ND 8.5 ND 5.5 3.6 1.7 J ND ND ND ug/L 09/20/12 0.17 1.0 -- ND ND 7.8 ND 1.7 J 1.8 J ND ND -- ND ug/L 03/20/13 0.17 1.0 -- ND ND 10 1.0 J 1.2 J 5.2 2.4 J ND ND ND ug/L 09/18/13 0.17 1.0 -- ND 4.8 8.0 0.43 J 4.1 5.2 1.8 J ND -- ND ug/L 03/27/14 0.17 1.0 -- ND ND 10 ND ND 4.9 1.2 J ND ND ND ug/L 09/18/14 0.17 1.0 -- ND 8.0 10 ND ND 5.6 0.88 J ND -- ND ug/L 03/18/15 0.17 1.0 -- ND ND 10 ND 1.4 J 6.4 2.2 J ND ND ND ug/L 09/23/15 0.17 1.0 -- ND 11 9.4 ND 4.2 5.2 1.5 J ND -- ND ug/L 03/17/16 0.17 1.0 -- ND 1.3 J 9.0 ND ND 6.6 0.86 J ND ND ND ug/L 09/21/16 0.17 1.0 -- ND 11 8.6 ND ND 6.3 0.97 J ND -- ND ug/L 03/21/17 0.17 1.0 -- ND 8.5 12 ND 0.92 J 5.4 1.6 J ND -- ND (re -sample) ug/L 05/03/17 0.17 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.17 1.0 -- ND ND 11 ND ND 4.3 1.6 J ND -- ND ug/L 03/21/18 0.17 1.0 -- ND ND 9.9 ND ND 5.3 1.1 J ND ND ND ug/L 09/23/18 0.17 1.0 -- ND 1.1 9.5 ND ND 4.9 ND ND -- ND ug/L 03/26/19 0.17 1.0 -- ND ND 10 ND ND 3.6 0.57 J ND ND ND ug/L 09/18/19 0.17 1.0 -- ND 8.4 8.3 ND ND 4.9 0.49 J ND -- ND ug/L 03/16/20 0.17 1.0 -- ND 1.2 8.3 ND ND 4.3 ND ND ND ND ug/L 09/23/20 0.17 1.0 -- ND ND 8.9 ND 0.95 J 4.6 ND ND -- ND ug/L 03/15/21 0.17 1.0 -- ND ND 10 ND ND 6.8 ND ND ND ND ug/L 09/20/21 0.17 1.0 -- ND 6.1 10 ND 1.4 8.3 ND ND -- ND ug/L 03/14/22 0.17 1.0 -- ND ND 8.4 ND 6.4 6.1 0.41 J ND ND ND ug/L 09/19/22 0.17 1.0 -- ND ND 10 ND 1.2 6.4 0.77 J ND -- ND u /L 03/20/23 0.17 1.0 -- ND ND 7.60 ND 0.789 J 9.73 0.677 J ND ND ND 1,2-Dichlorobenzene ug/L 12/05/94 0.27 5 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 20 ug/L ug/L 02/14/95 5 5 -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 600 ug/L ug/L 04/03/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 5 5 -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 5 5 -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 1 ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND 14 ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 7 ND 6 ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 6 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 12 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 10 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 10 ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 0.39 J ND 0.97 J ND 0.62 J -- -- ND ND ug/L 10/02/07 5 5 -- ND 2.52 J 0.56 J 0.94 J 0.44 J 0.67 J -- -- ND ND ug/L 04/03/08 5 5 -- ND ND 0.46 J 1.35 J 0.23 J 0.65 J 0.27 J ND ND ND ug/L 10/29/08 5 5 -- ND 1.98 J 0.45 J 1.12 J 0.52 J 0.63 J 0.29 J ND ND ND ug/L 03/24/09 0.27 1.0 -- ND ND ND 0.44 J ND 0.53 J ND ND ND ND ug/L 09/22/09 0.27 1.0 -- ND ND ND 0.66 J ND 0.46 J ND ND -- ND ug/L 03/22/10 0.052 1.0 -- ND Dry 0.49 J ND ND 0.64 J ND ND -- ND ug/L 09/23/10 0.27 1.0 -- ND 3.6 J 0.52 J ND ND 0.64 J ND ND -- ND ug/L 03/16/11 0.11 1.0 -- ND ND ND ND ND 0.71 J ND ND -- ND ug/L 09/21/11 0.11 1.0 -- ND 5.8 0.58 J ND ND 0.65 J ND ND -- ND ug/L 03/21/12 0.19 1.0 -- ND ND 0.56 J ND ND 0.62 J ND ND ND ND ug/L 09/20/12 0.19 1.0 -- ND ND 0.50 J 0.52 J ND 0.51 J ND ND -- ND ug/L 03/20/13 0.19 1.0 -- ND ND 0.76 J 1.3 J ND 0.90 J ND ND ND ND ug/L 09/18/13 0.19 1.0 -- ND 1.3 J 0.83 J ND ND 0.65 J ND ND -- ND ug/L 03/27/14 0.19 1.0 -- ND ND 0.76 J ND ND 0.55 J ND ND ND ND ug/L 09/18/14 0.19 1.0 -- ND 2.9 J 0.81 J ND ND 0.69 J ND ND -- ND ug/L 03/18/15 0.19 1.0 -- ND ND 0.77 J ND ND 0.71 J ND ND ND ND ug/L 09/23/15 0.19 1.0 -- ND 2.9 J 0.76 J ND ND 0.57 J ND ND -- ND ug/L 03/17/16 0.19 1.0 -- ND ND 0.78 J ND ND 0.77 J ND ND ND ND ug/L 09/21/16 0.19 1.0 -- ND 3.1 J 0.72 J ND ND 0.69 J ND ND -- ND ug/L 03/21/17 0.19 1.0 -- ND 1.5 J 0.87 J ND ND 0.57 J ND ND -- ND (re -sample) ug/L 05/03/17 0.19 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.19 1.0 -- ND ND 0.84 J ND ND 0.47 J ND ND -- ND ug/L 03/21/18 0.19 1.0 -- ND ND 0.76 J ND ND 0.48 J ND ND ND ND ug/L 09/23/18 0.19 1.0 -- ND 0.87 J 0.94 J ND ND 0.48 J ND ND -- ND ug/L 03/26/19 0.19 1.0 -- ND ND 0.81 J ND ND ND ND ND ND ND ug/L 09/18/19 0.19 1.0 -- ND 3.2 0.64 J ND ND 0.46 J ND ND -- ND ug/L 03/16/20 0.19 1.0 -- ND ND 0.55 J ND ND 0.49 J ND ND ND ND ug/L 09/23/20 0.19 1.0 -- ND 0.41 J 0.68 J ND ND 0.62 J ND ND -- ND ug/L 03/15/21 0.19 1.0 -- ND ND 0.80 J ND ND 0.58 J ND ND ND ND ug/L 09/20/21 0.19 1.0 -- ND 1.2 0.83 J ND ND 0.55 J ND ND -- ND ug/L 03/14/22 0.19 1.0 -- ND ND 0.67 J ND ND 0.45 J ND ND ND ND ug/L 09/19/22 0.19 1.0 -- ND ND 0.89 J ND ND 0.43 J ND ND -- ND u /L 03/20/23 0.19 1.0 -- ND ND 0.691 J ND ND 0.538 J ND ND ND ND 1,4-Dichlorobenzene ug/L 12/05/94 5 5 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 6 ug/L ug/L 02/14/95 5 5 -- ND -- ND ND -- -- -- -- ND -- EPA MCL = 75 ug/L ug/L 04/03/95 5 5 -- ND 11 ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND 10 5 ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND -- 9 ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- 8 ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- 24 ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 9 10 ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 18 22 ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND 18 ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 18 10 ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND 7 ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND 5 18 ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND 8 ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 14 6 ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND 12 7 ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 18 8 ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND 14 9 ND ND ND -- -- ND -- ug/L 04/09/03 5 5 -- ND ND 12 ND ND ND -- -- ND -- ug/L 10/20/03 5 5 -- ND 23 13 ND ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 20 19 ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND 17.8 -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 25.4 17 ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 24.3 16.4 ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 18.5 14.6 ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 1.67 J 17.1 2.79 J 1.37 2.86 J -- -- ND ND ug/L 10/02/07 5 5 -- ND 18.7 12.0 3.64 J 3.24 J 2.99 J -- -- ND ND ug/L 04/03/08 5 5 -- ND 0.38 J 8.37 4.50 J 1.57 J 2.77 J 2.11 J ND ND ND ug/L 10/29/08 5 5 -- ND 23.9 7.81 4.44 J 4.11 J 2.96 J 1.66 J ND ND ND ug/L 03/24/09 0.38 1.0 -- ND ND 6.4 1.3 0.57 J 2.6 1.4 ND ND ND ug/L 09/22/09 0.38 1.0 -- ND ND 6.8 2.4 1.4 2.1 1.0 ND -- ND ug/L 03/22/10 0.10 1.0 -- ND Dry 9.8 ND ND 3.2 1.2 ND -- ND ug/L 09/23/10 0.38 1.0 -- ND 15 8.8 ND ND 3.4 0.91 J ND -- ND ug/L 03/16/11 0.79 1.0 -- ND ND 10 ND ND 3.2 1.3 ND -- ND ug/L 09/21/11 0.79 1.0 -- ND 14 12 ND 0.93 J 4.2 1.2 ND -- ND ug/L 03/21/12 0.19 1.0 -- ND 5.4 J 12 0.49 J 2.9 3.7 1.4 ND ND ND ug/L 09/20/12 0.19 1.0 -- ND 0.77 J 11 1.0 2.0 3.8 1.2 ND -- ND ug/L 03/20/13 0.19 1.0 -- ND ND 14 3.8 ND 5.0 2.2 ND ND ND ug/L 09/18/13 0.19 1.0 -- ND 6.0 13 1.2 0.73 J 4.1 1.4 ND -- ND ug/L 03/27/14 0.19 1.0 -- ND ND 18 ND ND 3.1 0.73 J ND ND ND ug/L 09/18/14 0.19 1.0 -- ND 13 15 ND ND 4.3 0.86 J ND -- ND ug/L 03/18/15 0.19 1.0 -- ND ND 14 ND 0.46 J 4.0 1.4 ND ND ND ug/L 09/23/15 0.19 1.0 -- ND 21 13 ND 0.85 J 3.6 1.3 ND -- ND ug/L 03/17/16 0.19 1.0 -- ND 1.2 16 ND ND 4.2 0.90 J ND ND ND ug/L 09/21/16 0.19 1.0 -- ND 28 14 ND ND 4.2 0.87 J ND -- ND ug/L 03/21/17 0.19 1.0 -- ND 24 18 ND 0.44 J 4.1 1.4 ND -- ND (re -sample) ug/L 05/03/17 0.19 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.19 1.0 -- ND 2.9 16 ND ND 3.8 1.2 ND -- ND ug/L 03/21/18 0.19 1.0 -- ND ND 14 ND ND 3.4 1.1 ND ND ND ug/L 09/23/18 0.19 1.0 -- ND 5.4 16 ND ND 3.4 1.1 ND -- ND ug/L 03/26/19 0.19 1.0 -- ND ND 17 ND ND 2.3 0.59 J ND ND ND ug/L 09/18/19 0.19 1.0 -- ND 14 12 ND ND 2.8 ND ND -- ND ug/L 03/16/20 0.19 1.0 -- ND 0.92 J 14 ND ND 2.6 0.47 J ND ND ND ug/L 09/23/20 0.19 1.0 -- ND 1.4 14 ND ND 2.7 ND ND -- ND ug/L 03/15/21 0.19 1.0 -- ND ND 17 ND ND 3.7 ND ND ND ND ug/L 09/20/21 0.19 1.0 -- ND 9.5 16 ND ND 3.8 ND ND -- ND ug/L 03/14/22 0.19 1.0 -- ND ND 12 ND 0.97 J 2.5 0.53 J ND ND ND ug/L 09/19/22 0.19 1.0 -- ND 0.44 J 16 ND ND 3.0 0.86 J ND -- ND ug/L 03/20/23 0.19 1.0 -- ND ND 10 ND ND 3.7 0.715 J ND ND ND 7of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-11D AMW-2S AMW-2D MW-9 1,1-Dichloroethane ug/L 12/05/94 5 5 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 6 ug/L ug/L 02/14/95 5 5 -- ND ND 9 ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 5 5 -- ND -- 7 ND -- -- -- -- -- -- ug/L 10/30/95 5 5 -- ND ND 10 ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND 6 ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- 8 ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 1 7 ND -- -- -- -- 1 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND 6 ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND 5 6 -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND 5 ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND 6 -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND 14 -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND 11 -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND 25 ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND 17 ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND 24 ND ND -- -- ND -- ug/L 10/20/03 5 5 -- ND ND ND 18 ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND ND ND 10 ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND ND ND 13 ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND 6 ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND ND 1.69 7.8 ND 1.31 -- -- ND ND ug/L 10/02/07 5 5 -- ND 0.45 J 1.66 J 9.7 0.1 J 1.27 J -- -- ND ND ug/L 04/03/08 5 5 -- ND ND 1.72 J 13.1 ND 1.36 J 0.98 J ND ND ND ug/L 10/29/08 5 5 -- ND 0.40 J 1.32 J 13.5 ND 1.36 J 1.33 J ND 0.11 J ND ug/L 03/24/09 0.33 1.0 -- ND ND 0.83 J 3.6 J ND 1.2 J 1.1 J ND ND ND ug/L 09/22/09 0.33 1.0 -- ND ND 0.75 J 8.9 ND 1.0 J 1.3 J ND -- ND ug/L 03/22/10 0.050 1.0 -- ND Dry 0.64 J ND ND 0.76 J 0.90 J ND -- ND ug/L 09/23/10 0.33 1.0 -- ND ND 0.64 J ND ND 0.87 J 0.84 J ND -- ND ug/L 03/16/11 0.080 1.0 -- ND ND 0.56 J ND ND 0.91 J 1.0 J ND -- ND ug/L 09/21/11 0.080 1.0 -- ND ND 0.74 J 1.7 J ND 1.1 J 1.4 J ND -- ND ug/L 03/21/12 0.13 1.0 -- ND ND 0.63 J 0.94 J ND 0.74 J 1.1 J ND ND ND ug/L 09/20/12 0.13 1.0 -- ND ND 0.49 J 2.5 J ND 1.0 J 1.3 J ND -- ND ug/L 03/20/13 0.13 1.0 -- ND ND 0.71 J 6.9 ND 1.2 J 1.6 J ND ND ND ug/L 09/18/13 0.13 1.0 -- ND ND ND 1.7 J ND 0.71 J 1.0 J ND -- ND ug/L 03/27/14 0.13 1.0 -- ND ND ND ND ND 0.72 J 0.92 J ND ND ND ug/L 09/18/14 0.13 1.0 -- ND ND 0.43 J ND ND 0.54 J 0.96 J ND -- ND ug/L 03/18/15 0.13 1.0 -- ND ND 0.47 J ND ND 0.76 J 0.77 J ND ND ND ug/L 09/23/15 0.13 1.0 -- ND ND ND ND ND 0.62 J 1.1 J ND -- ND ug/L 03/17/16 0.13 1.0 -- ND ND ND ND ND 0.54 J 0.99 J 0.45 J ND ND ug/L 09/21/16 0.13 1.0 -- ND ND ND ND ND 0.51 J 0.94 J ND -- ND ug/L 03/21/17 0.13 1.0 -- ND ND ND ND ND 0.58 J 1.1 J ND -- ND (re -sample) ug/L 05/03/17 0.13 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.13 1.0 -- ND ND ND ND ND ND 0.87 J ND -- ND ug/L 03/21/18 0.13 1.0 -- ND ND ND ND ND ND 0.74 J ND ND ND ug/L 09/23/18 0.13 1.0 -- ND ND ND ND ND ND 0.89 J 0.53 J -- ND ug/L 03/26/19 0.13 1.0 -- ND ND ND ND ND ND 0.65 J ND ND ND ug/L 09/18/19 0.13 1.0 -- ND ND ND ND ND ND 0.58 J ND -- ND ug/L 03/16/20 0.13 1.0 -- ND ND ND ND ND ND 0.43 J ND ND ND ug/L 09/23/20 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.13 1.0 -- ND ND ND ND ND ND 0.42 J ND ND ND ug/L 09/19/22 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.13 1.0 -- ND ND ND ND ND 0.239 0.409 J 0.331 ND ND cis-1,2-Dichloroethene ug/L 12/05/94 5 5 -- ND -- 24 11 -- -- -- -- ND -- NC 2L = 70 ug/L ug/L 02/14/95 5 5 -- ND 9 ND 8 -- -- -- -- ND -- EPA MCL = 70 ug/L ug/L 04/03/95 5 5 -- ND 7 17 ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND 10 25 10 -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND 7 17 7 -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- 21 ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- 14 15 -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 4 20 3 -- -- -- -- 6 -- ug/L 05/14/98 -- -- -- ND ND 14 ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND 21 ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 6 17 ND -- -- -- -- 12 -- ug/L 10/29/99 -- -- -- ND ND 17 ND -- -- -- -- 26 -- ug/L 04/20/00 -- -- -- ND ND 13 ND ND -- -- -- 16 -- ug/L 11/07/00 -- -- -- ND ND 15 ND -- -- -- -- 12 -- ug/L 05/15/01 -- -- -- ND ND 14 7 -- -- -- -- 8 -- ug/L 10/16/01 -- -- -- ND ND 13 ND -- ND -- -- 10 -- ug/L 04/24/02 -- -- -- ND ND 15 11 ND ND -- -- 6 -- ug/L 10/01/02 -- -- -- ND ND 12 7 ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND 11 18 ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND 11 22 ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND ND 10 13 ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND ND 10.5 26.2 ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND 10.6 -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND ND 12.1 12.8 ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND 12.8 12.3 ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND 14.2 15.7 ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 0.48 J 12.7 22.1 ND 2.3 -- -- ND ND ug/L 10/02/07 5 5 -- ND 1.19 J 12.4 J 23.9 J 0.71 J 2.14 J -- -- ND ND ug/L 04/03/08 5 5 -- ND 0.05 J 12.2 30.6 0.35 J 2.25 J 1.85 J ND ND ND ug/L 10/29/08 5 5 -- ND 0.2 J 9.8 28.9 0.27 J 2.27 J 2.36 J ND 0.24 J ND ug/L 03/24/09 0.36 1.0 -- ND ND 4.9 J 7.4 ND 1.7 J 1.7 J ND ND ND ug/L 09/22/09 0.36 1.0 -- ND ND 6.1 19 ND 2.0 J 2.5 J ND -- ND ug/L 03/22/10 0.075 1.0 -- ND Dry 7.0 0.66 J ND 2.0 J 2.1 J ND -- ND ug/L 09/23/10 0.36 1.0 -- ND ND 5.2 ND ND 1.7 J 1.2 J ND -- ND ug/L 03/16/11 0.72 1.0 -- ND ND 6.4 0.89 J ND 2.6 J 2.0 J ND -- ND ug/L 09/21/11 0.72 1.0 -- ND ND 5.6 2.9 J ND 1.7 J 1.3 J ND -- ND ug/L 03/21/12 0.15 1.0 -- ND ND 5.2 2.6 J ND 1.5 J 1.6 J ND ND ND ug/L 09/20/12 0.15 1.0 -- ND ND 4.4 J 4.1 J ND 1.4 J 1.2 J ND -- ND ug/L 03/20/13 0.15 1.0 -- ND ND 5.6 13 ND 1.9 J 1.8 J ND ND ND ug/L 09/18/13 0.15 1.0 -- ND 0.53 J 5.3 4.1 J ND 1.4 J 1.5 J ND -- ND ug/L 03/27/14 0.15 1.0 -- ND ND 4.5 J ND ND 1.2 J 1.2 J ND ND ND ug/L 09/18/14 0.15 1.0 -- ND ND 5.0 ND ND 1.4 J 0.88 J ND -- ND ug/L 03/18/15 0.15 1.0 -- ND ND 5.3 0.63 J ND 1.2 J 1.2 J ND ND ND ug/L 09/23/15 0.15 1.0 -- ND ND 3.8 J ND ND 1.2 J 1.1 J ND -- ND ug/L 03/17/16 0.15 1.0 -- ND ND 3.6 J ND ND 1.2 J 0.95 J ND ND ND ug/L 09/21/16 0.15 1.0 -- ND ND 3.4 J ND ND 1.0 J 0.89 J ND -- ND ug/L 03/21/17 0.15 1.0 -- ND ND 3.7 J ND ND 0.90 J 1.0 J ND -- ND (re -sample) ug/L 05/03/17 0.15 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.15 1.0 -- ND ND 3.5 J ND ND 0.65 J 0.91 J ND -- ND ug/L 03/21/18 0.15 1.0 -- ND ND 2.7 J ND ND 0.68 J 0.76 J ND ND ND ug/L 09/23/18 0.15 1.0 -- ND ND 2.6 ND ND 0.56 J 0.91 J ND -- ND ug/L 03/26/19 0.15 1.0 -- ND ND 2.1 ND ND 0.51 J 0.61 J ND ND ND ug/L 09/18/19 0.15 1.0 -- ND ND ND ND ND 0.50 J 0.40 J ND -- ND ug/L 03/16/20 0.15 1.0 -- ND 0.44 J 2.1 ND ND 0.59 J ND ND ND ND ug/L 09/23/20 0.15 1.0 -- ND ND 2.7 ND ND ND ND ND -- ND ug/L 03/15/21 0.15 1.0 -- ND ND 2.7 ND ND ND ND ND ND ND ug/L 09/20/21 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.15 1.0 -- ND ND 1.9 ND ND ND ND ND -- ND u /L 03/20/23 0.15 1 -- ND 0.974 J 2.40 ND ND 0.878 B 0.273 B ND ND 0.1782 1 Ethylbenzene ug/L 12/05/94 5 5 -- ND 11 ND ND -- -- -- -- ND -- NC 2L = 600 ug/L ug/L 02/14/95 5 5 -- ND 14 ND ND -- -- -- -- ND -- EPA MCL = 700 ug/L ug/L 04/03/95 5 5 -- ND 8 ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND 10 ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND 9 ND ND -- -- -- -- ND -- ug/L 10/24/96 5 5 -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 5 5 -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 5 5 -- ND 3 ND 2 -- -- -- -- ND -- ug/L 05/14/98 5 5 -- ND 8 ND ND -- -- -- -- ND -- ug/L 10/11/98 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 5 5 -- ND 11 ND ND -- -- -- -- ND -- ug/L 10/29/99 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 5 5 -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 5 5 -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND 9 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 22.4 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 28 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 12.4 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 15.7 ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 0.96 J ND 1.04 ND ND -- -- ND ND ug/L 10/02/07 5 5 -- ND 3.46 ND 1.24 J ND ND -- -- ND ND ug/L 04/03/08 5 5 -- ND ND ND 1.37 J ND ND ND ND ND ND ug/L 10/29/08 5 5 -- ND 0.22 J ND 1.62 ND ND ND ND ND ND ug/L 03/24/09 0.20 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.20 1.0 -- ND ND ND 0.95 J ND ND ND ND -- ND ug/L 03/22/10 0.10 1.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.20 1.0 -- ND 2.1 ND ND ND ND ND ND -- ND ug/L 03/16/11 0.62 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.62 1.0 -- ND 2.3 ND ND ND ND ND ND -- ND ug/L 03/21/12 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 0.13 1.0 -- ND 0.79 J ND ND ND ND ND ND -- ND ug/L 03/27/14 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.13 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.13 1.0 -- ND 0.51 J ND ND ND ND ND ND -- ND ug/L 03/16/20 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.13 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/23 0.13 1.0 -- ND ND ND ND ND ND ND ND ND ND 8of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-11D AMW-2S AMW-2D MW-9 Methylene chloride ug/L 12/05/94 10 10 -- ND ND ND 7 -- -- -- -- ND -- NC 2L = 5 ug/L ug/L 10/30/95 10 10 -- ND ND 10 ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- 9 ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- 1 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND 52 -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND 38 -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND 87 ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND 44 ND ND -- -- ND -- ug/L 04/09/03 10 10 -- ND ND ND 54 ND ND -- -- ND -- ug/L 10/20/03 10 10 -- ND ND ND 27 ND ND -- -- ND -- ug/L 03/24/04 10 10 -- ND ND ND 30 ND ND -- -- ND -- ug/L 10/27/04 10 10 -- ND ND ND 42.1 ND ND -- -- ND -- ug/L 05/25/05 10 10 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 10 10 -- ND ND ND 13.4 ND ND -- -- ND -- ug/L 04/25/06 10 10 -- ND ND ND 13.9 ND ND -- -- ND -- ug/L 10/04/06 10 10 -- ND ND ND 15.1 ND ND -- -- ND ND ug/L 03/21/07 10 10 -- ND ND 0.35 J 23.3 ND 0.24 J -- -- ND ND ug/L 10/02/07 10 10 -- ND 0.57 B ND 22.0 ND ND -- -- ND 0.41 J ug/L 04/03/08 10 10 -- ND ND 0.34 B 34.2 ND ND ND 3.10 J ND 0.42 J ug/L 10/29/08 10 10 -- ND ND 0.27 J 33.7 ND 0.42 J 0.92 J ND 0.75 J ND ug/L 03/24/09 0.53 2.0 -- ND ND ND 11 ND ND ND ND ND ND ug/L 09/22/09 0.53 1.0 -- ND ND ND 21 ND ND ND ND -- ND ug/L 03/22/10 0.070 1.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.53 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.14 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.14 1.0 -- ND ND ND 3.4 ND ND ND ND -- ND ug/L 03/21/12 0.23 1.0 -- ND ND ND 1.8 ND ND ND ND ND ND ug/L 09/20/12 0.23 1.0 -- ND ND ND 2.4 ND ND ND ND -- ND ug/L 03/20/13 0.23 1.0 -- ND ND ND 11 ND ND ND ND ND ND ug/L 09/18/13 0.23 1.0 -- ND ND ND 1.0 ND ND ND ND -- ND ug/L 03/27/14 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.23 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.23 1.0 -- ND ND ND ND ND ND ND ND -- 0.43 J ug/L 03/26/19 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.23 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.23 1.0 -- ND 0.41 B ND ND ND ND ND ND ND 0.67 J ug/L 09/19/22 0.23 1.0 -- ND ND ND ND ND ND ND ND -- 0.47 J u /L 03/20/23 0.23 1.0 -- ND ND 0.267 B ND ND ND 0.308 B ND 0.294 B 0.47 1 Tetrachloroethene (PCE) ug/L 12/05/94 5 5 -- ND ND 6.6 9 -- -- -- -- ND -- NC 2L = 0.7 ug/L ug/L 02/14/95 5 5 -- ND ND 7 7 -- -- -- -- 6 -- EPA MCL = 5 ug/L ug/L 04/03/95 5 5 -- ND ND 6.3 ND -- -- -- -- 6 -- ug/L 10/30/95 5 5 -- ND ND ND ND -- -- -- -- 5 -- ug/L 04/08/96 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- 9 -- ug/L 04/15/97 -- -- -- ND -- ND 15 -- -- -- -- 16 -- ug/L 10/29/97 -- -- -- ND ND 4 4 -- -- -- -- 16 -- ug/L 05/14/98 -- -- -- ND ND ND 19 -- -- -- -- 13 -- ug/L 10/11/98 -- -- -- ND ND ND 15 -- -- -- -- 15 -- ug/L 06/04/99 -- -- -- ND ND ND 44 -- -- -- -- 27 -- ug/L 10/29/99 -- -- -- ND ND ND 27 -- -- -- -- 31 -- ug/L 04/20/00 -- -- -- ND ND ND 69 ND -- -- -- 30 -- ug/L 11/07/00 -- -- -- ND ND ND 54 -- -- -- -- 36 -- ug/L 05/15/01 -- -- -- ND ND ND 110 -- -- -- -- 24 -- ug/L 10/16/01 -- -- -- ND ND ND 44 -- ND -- -- 11 -- ug/L 04/24/02 -- -- -- ND ND ND 170 ND ND -- -- 24 -- ug/L 10/01/02 -- -- -- ND ND ND 110 ND ND -- -- 20 -- ug/L 04/09/03 -- -- -- ND ND ND 120 ND ND -- -- 11 -- ug/L 10/20/03 -- -- -- ND ND ND 61 ND ND -- -- 8 -- ug/L 03/24/04 -- -- -- ND ND ND 32 ND ND -- -- 8.12 -- ug/L 10/27/04 5 5 -- ND ND ND 52 ND ND -- -- 6.96 -- ug/L 05/25/05 5 5 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND 16.2 ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND 10 ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND 21 ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND ND ND 28.8 ND ND -- -- 2.17 ND ug/L 10/02/07 5 5 -- ND ND ND 42.1 ND ND -- -- 1.79 J ND ug/L 04/03/08 5 5 -- ND ND ND 47.9 ND ND ND ND 2.32 J ND ug/L 10/29/08 5 5 -- ND ND ND 48.5 ND ND ND ND 1.98 ND ug/L 03/24/09 0.36 1.0 -- ND ND ND 8.7 ND ND ND ND 2.7 ND ug/L 09/22/09 0.36 1.0 -- ND ND ND 25 ND ND ND ND -- ND ug/L 03/22/10 0.099 1.0 -- ND Dry ND 0.80 J ND ND ND ND -- ND ug/L 09/23/10 0.36 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.73 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.73 1.0 -- ND ND ND 2.8 ND ND ND ND -- ND ug/L 03/21/12 0.17 1.0 -- ND ND ND 1.7 ND ND ND ND ND ND ug/L 09/20/12 0.17 1.0 -- ND ND ND 3.9 ND ND ND ND -- ND ug/L 03/20/13 0.17 1.0 -- ND ND ND 11 ND ND ND ND ND ND ug/L 09/18/13 0.17 1.0 -- ND ND ND 2.8 ND ND ND ND -- ND ug/L 03/27/14 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.17 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.17 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND Toluene ug/L 12/05/94 5 5 -- ND 5 ND ND -- -- -- -- ND -- NC 2L = 600 ug/L ug/L 02/14/95 5 5 -- ND 7 ND ND -- -- -- -- ND -- EPA MCL = 1000 ug/L ug/L 04/03/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND 9 -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 150 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND 59 ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 11 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 5 5 -- ND 5 ND ND ND ND -- -- ND -- ug/L 03/24/04 5 5 -- ND 878 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 1220 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND 132 ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 16 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 12 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 0.3 J ND 1.05 ND ND -- -- ND ND ug/L 10/02/07 5 5 -- ND 1.08 J 0.11 J 1.62 J ND ND -- -- ND ND ug/L 04/03/08 5 5 -- ND 0.11 B ND 1.30 B ND ND ND ND ND 0.60 J ug/L 10/29/08 5 5 -- ND 4.33 ND 0.99 J ND ND ND ND ND ND ug/L 03/24/09 0.27 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.27 1.0 -- 0.98 J 1.6 0.48 J 0.96 J 0.42 J 0.93 J 0.63 J 1.3 -- ND ug/L 03/22/10 0.053 1.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.27 1.0 -- ND 3.1 ND ND ND ND ND ND -- ND ug/L 03/16/11 0.85 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.85 1.0 -- ND 2.8 ND ND ND ND ND ND -- ND ug/L 03/21/12 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 0.14 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 0.14 1.0 -- ND 3.8 ND ND ND ND ND ND -- ND ug/L 03/27/14 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.14 1.0 -- ND 75 ND ND ND 2.0 ND ND -- ND ug/L 03/18/15 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.14 1.0 -- ND 1.0 ND ND ND ND ND ND -- ND ug/L 03/17/16 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.14 1.0 -- ND 0.94 J ND ND ND ND ND ND -- ND ug/L 03/21/17 0.14 1.0 -- ND 0.86 J ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.14 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.14 1.0 -- ND 1.3 ND ND ND ND ND ND -- ND ug/L 03/21/18 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.14 1.0 -- ND 8.3 ND ND ND ND ND ND -- ND ug/L 03/26/19 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.14 1.0 -- ND 12 ND ND ND ND ND ND -- ND ug/L 03/16/20 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.14 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.14 1.0 -- ND 1.5 ND ND ND ND ND ND -- ND ug/L 03/14/22 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.14 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.14 1.0 -- ND ND ND ND ND ND ND ND ND ND 9of13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 1, 1, 1 -Trichloroethane ug/L 12/05/94 5 5 -- ND ND -- ND -- -- -- -- -- -- NC 2L = 200 ug/L ug/L 02/14/95 5 5 -- ND ND -- ND -- -- -- -- -- -- EPA MCL = 200 ug/L ug/L 04/03/95 5 5 -- ND ND -- ND -- -- -- -- -- -- ug/L 10/30/95 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 04/08/96 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 10/24/96 -- -- -- ND -- -- ND -- -- -- -- -- -- ug/L 04/15/97 -- -- -- ND -- -- ND -- -- -- -- -- -- ug/L 10/29/97 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 05/14/98 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 10/11/98 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 06/04/99 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 10/29/99 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 04/20/00 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 11/07/00 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 02/27/01 -- -- -- -- -- -- -- -- -- ug/L 05/15/01 -- -- -- ND ND -- 6 -- -- -- -- -- -- ug/L 10/16/01 -- -- -- ND ND -- 6 -- -- -- -- -- -- ug/L 04/24/02 -- -- -- ND ND -- 9 -- -- -- -- -- -- ug/L 10/01/02 -- -- -- ND ND -- 5 -- -- -- -- -- -- ug/L 04/09/03 -- -- -- ND ND -- ND -- -- -- -- -- -- ug/L 10/20/03 5 5 -- ND ND -- ND -- -- -- -- -- -- ug/L 03/24/04 5 5 -- ND ND -- ND -- -- -- -- -- -- ug/L 10/27/04 5 5 -- ND ND -- ND -- -- -- -- -- -- ug/L 05/25/05 5 5 -- ND ND -- -- -- -- -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND ND ug/L 10/02/07 5 5 -- ND ND ND 0.18 J ND ND -- -- ND ND ug/L 04/03/08 5 5 -- ND ND ND 0.23 J ND ND ND ND ND ND ug/L 10/29/08 5 5 -- ND ND ND 0.13 J ND ND ND ND ND ND ug/L 03/24/09 0.27 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.27 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/22/10 0.15 1.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.27 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.65 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.65 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/12 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 0.12 -- -- ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/27/14 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.12 -- -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.12 -- -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.12 -- -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.12 -- -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.12 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.12 -- -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.12 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.12 1.0 -- ND ND ND ND ND ND ND ND ND ND Trichloroethene ug/L 12/05/94 5 5 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 3 ug/L ug/L 02/14/95 5 5 -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 5 5 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND ND 2 ND -- -- -- -- 2 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND 6 ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND 14 -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND 8 -- -- -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND 20 ND -- -- -- ND -- ug/L 10/01/02 5 5 -- ND ND ND 13 ND -- -- -- ND -- ug/L 04/09/03 5 5 -- ND ND ND 27 ND -- -- -- ND -- ug/L 10/20/03 5 5 -- ND ND ND 26 ND -- -- -- ND -- ug/L 03/24/04 5 5 -- ND ND ND 13 ND -- -- -- ND -- ug/L 10/27/04 5 5 -- ND ND ND 17.5 ND -- -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND -- ND -- -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND 5 ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND 7 ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND ND 0.48 J 12 ND 0.31 J -- -- ND ND ug/L 10/02/07 5 5 -- ND ND 0.41 J 15.5 ND 0.3 J -- -- ND ND ug/L 04/03/08 5 5 -- ND ND 0.47 J 18.1 ND 0.28 J 0.30 J ND ND ND ug/L 10/29/08 5 5 -- ND ND 0.32 J 18.2 ND 0.33 J 0.45 J ND 0.16 J ND ug/L 03/24/09 0.38 1.0 -- ND ND ND 3.1 ND ND ND ND ND ND ug/L 09/22/09 0.38 1.0 -- ND ND ND 9.5 ND ND ND ND -- ND ug/L 03/22/10 0.13 1.0 -- ND Dry ND ND ND ND 0.44 J ND -- ND ug/L 09/23/10 0.38 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.72 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.72 1.0 -- ND ND ND 1.1 ND ND ND ND -- ND ug/L 03/21/12 0.15 1.0 -- ND ND ND 0.70 J ND ND ND ND ND ND ug/L 09/20/12 0.15 1.0 -- ND ND ND 1.6 ND ND ND ND -- ND ug/L 03/20/13 0.15 1.0 -- ND ND ND 3.9 ND ND ND ND ND ND ug/L 09/18/13 0.15 1.0 -- ND ND ND 1.3 ND ND ND ND -- ND ug/L 03/27/14 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.15 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.15 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND Vinyl chloride ug/L 12/05/94 10 10 -- ND ND ND ND -- -- -- -- ND -- NC 2L = 0.03 ug/L ug/L 02/14/95 10 10 -- ND ND ND ND -- -- -- -- ND -- EPA MCL = 2 ug/L ug/L 04/03/95 10 10 -- ND ND ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 2 5 2 -- -- -- -- 1 -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 10 10 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 10 10 -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 10 10 -- ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 10 10 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 10 10 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 10 10 -- ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 10 10 -- ND 0.43 J 2.35 ND ND 0.94 J -- -- ND ND ug/L 10/02/07 10 10 -- ND 1.03 J 2.68 J 0.31 J ND 0.89 J -- -- ND ND ug/L 04/03/08 10 10 -- ND ND 2.94 J ND ND 0.98 J 0.59 J ND ND ND ug/L 10/29/08 10 10 -- ND 0.25 J 2.36 0.49 J ND 0.82 J 0.57 J ND ND ND ug/L 03/24/09 0.30 1.0 -- ND ND 1.5 ND ND 0.60 J 0.53 J ND ND ND ug/L 09/22/09 0.30 1.0 -- ND ND 1.4 ND ND 0.67 J ND ND -- ND ug/L 03/22/10 0.083 1.0 -- ND Dry 1.2 ND ND 0.60 J ND ND -- ND ug/L 09/23/10 0.30 1.0 -- ND ND 1.2 ND ND ND ND ND -- ND ug/L 03/16/11 0.60 1.0 -- ND ND 1.3 ND ND ND ND ND -- ND ug/L 09/21/11 0.60 1.0 -- ND ND 1.5 ND ND 0.76 J ND ND -- ND ug/L 03/21/12 0.32 1.0 -- ND ND 0.88 J ND ND ND 0.55 J ND ND ND ug/L 09/20/12 0.32 1.0 -- ND ND ND ND ND 0.57 J 0.61 J ND -- ND ug/L 03/20/13 0.32 1.0 -- ND ND 1.0 0.77 J ND 0.50 J 0.49 J ND ND ND ug/L 09/18/13 0.32 1.0 -- ND ND 0.81 J ND ND 0.48 J 0.48 J ND -- ND ug/L 03/27/14 0.32 1.0 -- ND ND 1.1 ND ND 0.64 J ND ND ND ND ug/L 09/18/14 0.32 1.0 -- ND ND 1.1 ND ND 0.54 J ND ND -- ND ug/L 03/18/15 0.32 1.0 -- ND ND 0.88 J ND ND 0.46 J ND ND ND ND ug/L 09/23/15 0.32 1.0 -- ND ND 0.98 J ND ND ND ND ND -- ND ug/L 03/17/16 0.32 1.0 -- ND ND 0.93 J ND ND 0.46 J ND ND ND ND ug/L 09/21/16 0.32 1.0 -- ND ND 0.74 J ND ND ND ND ND -- ND ug/L 03/21/17 0.32 1.0 -- ND ND 0.92 J ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.32 1.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.32 1.0 -- ND ND 0.73 J ND ND ND ND ND -- ND ug/L 03/21/18 0.32 1.0 -- ND ND 0.51 J ND ND ND ND ND ND ND ug/L 09/23/18 0.32 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.32 1.0 -- ND ND 0.51 J ND ND ND ND ND ND ND ug/L 09/18/19 0.32 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.32 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.32 1.0 -- ND ND 0.74 J ND ND ND ND ND -- ND ug/L 03/15/21 0.32 1.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.32 1.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.32 1.0 -- ND ND 0.61 J ND ND ND ND ND ND ND ug/L 09/19/22 0.32 1.0 -- ND ND 0.84 J ND ND ND ND ND -- ND u /L 03/20/23 0.32 1.0 -- ND ND 0.81 J ND ND ND ND ND ND ND 10 of 13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-11D AMW-2S AMW-2D MW-9 Xylenes (Total) ug/L 12/05/94 5 5 -- ND 70 ND 130 -- -- -- ND -- NC 2L = 500 ug/L ug/L 02/14/95 5 5 -- ND 68 ND ND -- -- -- -- ND -- EPA MCL = 10000 ug/L ug/L 04/03/95 5 5 -- ND 45 ND 47 -- -- -- -- ND -- ug/L 10/30/95 5 5 -- ND 40 ND 40 -- -- -- -- ND -- ug/L 04/08/96 5 5 -- ND 46 ND 35 -- -- -- -- ND -- ug/L 10/24/96 -- -- -- ND -- ND 19 -- -- -- -- ND -- ug/L 04/15/97 -- -- -- ND -- ND 44 -- -- -- -- ND -- ug/L 10/29/97 -- -- -- ND 12 1 3 -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 65 ND 17 -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND 5 -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 55 ND 9 -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND 8 ND 6 -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND 10 ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/15/01 -- -- -- ND 27 ND ND -- -- -- -- ND -- ug/L 10/16/01 -- -- -- ND 17 ND ND -- ND -- -- ND -- ug/L 04/24/02 -- -- -- ND 40 ND 14 ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND 8 ND 9 ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND 15 ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 27 ND 14 ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND 48 ND 10 ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 70 ND 18 ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND 55 ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 81 ND 12 ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 48 ND 12 ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 59 ND 14 ND ND -- -- ND ND ug/L 03/21/07 5 5 -- ND 2.74 ND 29.5 ND ND -- -- ND ND ug/L 10/02/07 5 5 -- ND 4.54 ND 34 ND ND -- -- ND ND ug/L 04/03/08 5 5 -- ND ND ND 40.6 ND ND ND ND ND ND ug/L 10/29/08 5 5 -- ND 0.86 J ND 39.8 ND ND ND ND ND ND ug/L 03/24/09 0.40 1.0 -- ND ND ND 8.3 ND ND ND ND ND ND ug/L 09/22/09 0.40 1.0 -- ND ND ND 19 ND ND ND ND -- ND ug/L 03/22/10 0.22 1.0 -- ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.40 1.0 -- ND 5.4 ND ND ND ND ND ND -- ND ug/L 03/16/11 2.1 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 2.1 3.0 -- ND 3.6 J ND 2.5 J ND ND ND ND -- ND ug/L 03/21/12 0.45 3.0 -- ND ND ND 0.98 J ND ND ND ND ND ND ug/L 09/20/12 0.45 3.0 -- ND ND ND 2.2 J ND ND ND ND -- ND ug/L 03/20/13 0.45 3.0 -- ND ND ND 6.3 ND ND ND ND ND ND ug/L 09/18/13 0.45 3.0 -- ND 0.81 J ND 1.8 J ND ND ND ND -- ND ug/L 03/27/14 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.45 3.0 -- -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/16/20 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/23/20 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/15/21 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/20/21 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/14/22 0.45 3.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/19/22 0.45 3.0 -- ND ND ND ND ND ND ND ND -- ND u /L 03/20/23 0.45 3 -- ND ND ND ND ND ND ND ND ND ND 1,4-Dioxane ug/L 09/23/18 1.2 -- -- ND 11 18 ND ND 0.56 J 3.5 1.6 J -- ND NC 2L = 3 ug/L ug/L 03/26/19 1.2 2.0 -- ND 2.4 17 ND ND 7.2 2.1 ND ND ND ug/L 09/18/19 1.2 2.0 -- ND 35 13 1.9 J ND 8.5 2.6 2.2 -- ND ug/L 03/16/20 0.80 2.0 -- ND 5.1 22 1.1 J ND 8.8 2.0 1.3 J ND ND ug/L 09/23/20 0.80 2.0 -- ND ND 20 ND ND 9.7 1.8 J 1.3 J -- ND ug/L 03/15/21 0.80 2.0 -- ND 2.2 20 ND ND 7.7 1.5 J 1.3 J ND ND ug/L 09/20/21 0.80 2.0 -- ND 25 22 ND 1.4 J 12 1.8 J 1.5 J -- ND ug/L 03/14/22 0.80 2.0 -- ND ND 24 0.97 J 4.1 13 2.4 1.2 J ND ND ug/L 09/19/22 0.80 2.0 -- ND ND 24 ND 1.4 J 8.4 2.7 1.4 J -- ND u /L 03/20/23 0.32 0.5 -- ND 21.6 19.4 0.541 1.2 12.2 2.67 1.38 ND ND Diethylphthalate ug/L 12/05/94 5 5 -- -- -- -- -- -- -- -- -- -- -- NC 2L = 6000 ug/L ug/L 02/14/95 5 5 -- -- -- -- -- -- -- -- -- -- -- EPA MCL = No Standard ug/L 04/03/95 5 5 -- -- -- -- -- -- -- -- -- -- -- ug/L 10/30/95 5 5 -- -- -- -- -- -- -- -- -- -- -- ug/L 06/06/96 -- -- -- -- -- -- -- -- -- -- ug/L 10/24/96 -- -- -- -- -- -- -- -- -- -- -- -- -- ug/L 04/15/97 -- -- -- -- -- -- -- -- -- -- -- -- -- ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 02/27/01 -- -- -- -- -- -- -- -- -- -- -- -- -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 19 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 35.9 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND 140 ND ND ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 548 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 101 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 86.6 ND ND ND ND -- -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 -- -- -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 1.3 10 -- ND ND ND ND ND ND 1.5 J ND ND ND ug/L 09/22/09 -- -- -- -- -- -- -- -- -- -- -- -- -- ug/L 03/22/10 0.61 10 -- ND Dry ND ND -- -- -- -- -- ND ug/L 09/23/10 -- -- -- -- -- -- -- -- -- ug/L 03/16/11 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/21/11 -- 10 -- -- -- -- -- -- -- -- -- -- -- ug/L 03/21/12 2.1 10 -- ND 3.1 B ND ND -- -- -- -- -- ND ug/L 09/20/12 -- -- -- -- -- -- -- -- -- ug/L 03/20/13 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/13 2.1 10 -- -- -- -- -- -- -- -- -- -- -- ug/L 03/27/14 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/14 2.1 10 -- -- -- -- -- -- -- -- -- -- -- ug/L 03/18/15 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/23/15 2.1 10 -- -- -- -- -- -- -- -- -- -- -- ug/L 03/17/16 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 2.1 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 2.4 10 -- ND ND 27 ND -- -- -- -- -- ND ug/L 03/16/20 2.4 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/15/21 2.4 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 2.4 10 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 2.2 10 -- ND ND ND ND -- -- -- -- -- ND 2,4-dimethyl phenol ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 100 ug/L ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 19 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 35.9 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND 140 ND ND ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 548 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 101 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 86.6 ND ND ND ND -- -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 5 5 -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 3.0 10 -- ND ND ND ND ND ND ND ND ND ND ug/L 03/22/10 2.6 10 -- ND Dry ND ND -- -- -- -- -- ND ug/L 03/16/11 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/12 1.3 10 -- ND 4.0 J ND ND -- -- -- -- -- ND ug/L 03/20/13 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/27/14 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 1.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 2.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/16/20 2.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/15/21 2.3 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 2.3 10 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 3.0 10 -- ND ND ND ND -- -- -- -- -- ND 11 of 13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Bis(2-ethylhexyl)phthalate ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 3 ug/L ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 5 5 -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 1.9 5.0 -- ND ND ND ND ND ND ND ND ND ND ug/L 03/22/10 2.6 5.0 -- ND Dry ND ND -- -- -- -- -- ND ug/L 03/16/11 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/12 1.7 5.0 -- 1.8 B 7.0 B ND ND -- -- -- -- -- ND ug/L 03/20/13 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/27/14 1.7 5.0 -- ND 3.3 J ND ND -- -- -- -- -- ND ug/L 09/18/14 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/23/15 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 1.7 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 1.9 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/16/20 1.9 5.0 -- ND 2.1 J ND ND -- -- -- -- -- ND ug/L 03/15/21 1.9 5.0 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 1.9 5.0 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 3.0 10 -- ND ND ND ND - - - - -- ND Di-n-octylphthalate ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 100 ug/L ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 5 -- -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 2.0 10 -- ND ND ND ND ND ND ND ND ND ND ug/L 03/22/10 1.4 10 -- ND Dry ND ND -- -- -- -- -- ND ug/L 03/16/11 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/12 3.1 10 -- ND 6.6 J ND ND -- -- -- -- -- ND ug/L 03/20/13 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/27/14 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 3.1 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 3.1 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/16/20 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/15/21 3.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 3.1 10 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 2.8 10 -- ND ND ND ND -- -- -- -- -- ND 3 &4-methylphenol ug/L 12/05/94 5 5 -- -- -- -- -- -- -- -- -- -- -- NC 2L Standard = 400/40 ug/L ug/L 02/14/95 5 5 -- -- -- -- -- -- -- -- -- -- -- EPA MCL = No Standard ug/L 04/03/95 5 5 -- -- -- -- -- -- -- -- -- -- -- ug/L 10/30/95 5 5 -- -- -- -- -- -- -- -- -- -- -- ug/L 04/08/96 5 5 -- -- -- -- -- -- -- -- -- -- -- ug/L 05/29/96 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 06/06/96 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/24/96 -- -- -- -- -- -- -- -- -- ug/L 04/15/97 -- -- -- -- -- -- -- -- -- -- ug/L 10/29/97 -- -- -- ND 140 ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND 160 ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND 260 ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND 57 ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 02/27/01 -- -- -- -- -- ---- -- -- -- -- -- -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND 27 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND 1930 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 -- ND 2880 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 -- ND 398 ND ND ND ND -- -- ND -- ug/L 10/04/05 5 5 -- ND 109 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 -- ND 25.4 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 16.4 ND ND ND ND -- -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 5 -- -- ND 4.26 J ND ND ND ND ND ND ND -- ug/L 03/24/09 1.9 20 -- ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 -- -- -- -- -- -- -- -- -- ug/L 03/22/10 1.8 10 -- ND Dry ND ND -- -- -- -- -- ND ug/L 09/23/10 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 03/16/11 1.6 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/21/11 1.6 10 -- -- -- -- -- -- -- -- -- -- -- ug/L 03/21/12 1.6 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/20/12 1.6 -- -- -- -- -- -- -- -- -- -- ug/L 03/20/13 1.6 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/13 1.6 -- -- -- -- -- -- -- -- -- -- -- -- ug/L 03/27/14 1.6 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/14 1.6 -- -- -- -- -- -- -- -- ug/L 03/18/15 1.6 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 09/23/15 1.6 -- -- -- -- -- -- -- -- -- -- -- -- ug/L 03/17/16 1.6 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 1.6 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 1.6 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 2.1 10 -- ND ND 2.6 J ND -- -- -- -- -- ND ug/L 03/16/20 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/15/21 2.1 10 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 2.1 10 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 1.4 10 -- ND ND ND ND -- -- -- -- -- ND gamma-BHC ug/L 03/24/09 0.022 0.050 -- ND ND ND ND ND ND ND ND ND ND NC 2L = 0.03 ug/L ug/L 03/22/10 0.016 0.050 -- ND Dry ND ND -- -- -- -- -- ND EPA MCL = 0.2 ug/L ug/L 03/16/11 0.016 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/21/11 0.022 0.050 -- -- -- -- -- -- -- -- -- -- ND ug/L 03/21/12 0.034 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/20/13 0.034 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/13 -- -- -- -- -- -- -- -- -- -- -- -- ND ug/L 03/27/14 0.034 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/23/17 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 0.034 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 0.034 0.050 -- ND ND ND ND - - - - - ND ug/L 03/16/20 0.034 0.050 -- ND ND ND ND - - - - - ND ug/L 03/15/21 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 0.034 0.050 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 0.001 0.05 -- ND ND ND 0.00791 J -- -- -- -- -- ND Heptachlor epoxide ug/L 03/24/09 0.025 0.050 -- ND ND ND ND ND ND ND ND ND ND NC 2L = 0.004 ug/L ug/L 03/22/10 0.0089 0.050 -- ND Dry ND ND -- -- -- -- -- ND EPA MCL = 0.2 ug/L ug/L 03/16/11 0.0089 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/21/11 0.027 0.050 -- -- -- -- -- -- -- -- -- -- ND ug/L 03/21/12 0.037 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/20/13 0.037 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 09/18/13 -- -- -- -- -- -- -- -- -- -- -- -- ND ug/L 03/27/14 0.037 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/23/17 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 0.037 0.050 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 0.037 0.050 -- ND ND ND ND -- -- -- -- - ND ug/L 03/16/20 0.037 0.050 -- ND ND ND ND -- -- -- -- - ND ug/L 03/15/21 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 0.037 0.050 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 0.002 0.05 -- ND ND 0.00911 J ND -- -- -- -- -- ND 12 of 13 July 2023 TABLE 4 GL2014715721 Summary of Detected Constituents in MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Downgradient Compliance Wells Assessment Wells TVA Well Blanks Limit Well MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 2,4-D ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- NC 2L = 70 ug/L ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- EPA MCL = 70 ug/L ug/L 10/29/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/11/98 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 10/29/99 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/20/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 05/15/01 -- -- -- ND ND ND ND ND -- -- -- ND -- ug/L 10/16/01 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/24/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/01/02 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/09/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/27/04 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 05/25/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/05 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 03/21/07 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/02/07 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 04/03/08 -- -- -- ND ND ND ND ND ND -- -- ND -- ug/L 10/30/08 -- -- -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 0.091 0.50 -- ND ND ND ND ND ND ND ND ND ND ug/L 03/22/10 0.091 0.50 -- ND Dry ND ND -- -- -- -- -- ND ug/L 03/16/11 0.15 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/12 0.16 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/20/13 0.16 0.50 -- ND ND 0.75 J ND -- -- -- -- -- ND ug/L 03/27/14 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 0.27 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 0.27 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/17 0.27 -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/21/18 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/26/19 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/16/20 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/15/21 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/14/22 0.27 0.50 -- ND ND ND ND -- -- -- -- -- ND u /L 03/20/23 0.18 1.1 -- ND ND ND ND -- -- -- -- -- ND Cyanide ug/L 12/05/94 -- -- -- -- -- -- -- -- -- -- -- -- -- NC 2L = 70 ug/L ug/L 02/14/95 -- -- -- -- -- -- -- -- -- -- -- -- -- EPA MCL = 20 ug/L ug/L 04/03/95 -- -- -- -- -- -- -- -- -- -- -- -- -- ug/L 10/30/95 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 05/29/96 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 06/06/96 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/24/96 -- -- -- ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/29/97 -- -- -- 2 ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/11 /98 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 06/04/99 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/29/99 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 04/20/00 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 11/07/00 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 05/15/01 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 06/05/01 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 06/21 /01 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/16/01 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 04/24/02 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/01 /02 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 04/09/03 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/20/03 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 03/24/04 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/27/04 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 05/25/05 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/04/05 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 04/25/06 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/04/06 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 03/21 /07 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/02/07 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 04/03/08 -- -- -- -- ---- -- -- -- -- -- -- -- ug/L 10/29/08 -- -- -- -- ---- -- -- -- -- -- -- -- mg/L 03/24/09 0.0040 0.0050 -- ND ND ND ND ND ND ND ND ND ND mg/L 03/22/10 0.005 0.005 -- ND Dry ND ND -- -- -- -- -- ND mg/L 03/16/11 0.0039 0.005 -- ND ND ND ND -- -- -- -- -- ND mg/L 09/21/11 0.0000039 0.00001 -- -- -- -- -- -- -- -- -- -- ND mg/L 03/21/12 0.0039 0.01 -- ND ND ND ND -- -- -- -- -- ND mg/L 09/20/12 -- -- -- -- -- -- -- -- -- -- -- -- -- mg/L 03/20/13 0.0049 0.01 -- ND ND ND ND -- -- -- -- -- ND mg/L 09/18/13 -- -- -- -- -- -- -- -- -- -- -- -- -- mg/L 03/27/14 0.0049 0.01 -- ND ND ND ND -- -- -- -- -- ND ug/L 03/18/15 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/17/16 -- -- -- ND ND ND ND -- -- -- -- -- ND ug/L 03/23/17 -- -- -- ND ND ND ND -- -- -- -- -- ND mg/L 03/21/18 0.0049 0.01 -- ND ND ND ND -- -- -- -- -- ND mg/L 03/26/19 0.0049 0.01 -- ND ND ND ND - - - - - ND mg/L 03/16/20 0.0049 0.01 -- ND ND ND ND - - - - - ND ug/L 03/15/21 -- -- -- ND ND ND ND -- -- -- -- -- ND mg/L 03/14/22 0.0049 0.01 -- ND ND ND ND -- -- -- -- -- ND m /L 03/20/23 0.0025 0.01 -- 0.00402 B 0.00591 B 0.00344 B 0.00841 B -- -- -- -- -- 0.00445 1 Notes: ug/L = micrograms per liter mg/L = milligrams per liter ND = Not detected at the stated reporting limit J = estimated concentration B = Blank -qualified result -- = no data available MDL = laboratory method detection limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPOL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2022 event: Antimony and Thallium (2X) in all sample points 13 of 13 July 2023 GL2014715721 TABLE 5 Summary of Field Parameters for MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 Upgradient Downgradient Compliance Wells Assessment Wells TVA Well Detected Monitoring Parameter Units Date Compliance Well MW-5 MW-6 MW-7 MW-8 AMW-1 S AMW-1 D AMW-2S AMW-2D MW-9 pH (field) S.U. 10/04/06 5.81 6.06 5.54 5.90 6.17 6.15 -- -- 5.35 S.U. 10/02/07 5.60 5.88 5.28 5.23 5.81 5.90 -- -- 5.37 S.U. 04/03/08 5.76 6.05 5.30 5.63 6.00 5.95 6.24 7.35 4.93 S.U. 03/24/09 6.94 6.43 6.42 6.64 6.21 6.82 7.11 7.56 6.31 S.U. 09/22/09 5.58 5.32 5.60 5.72 5.87 5.91 5.92 6.27 -- S.U. 03/22/10 5.58 Dry 5.44 6.01 6.07 5.62 5.98 6.40 -- S.U. 09/23/10 5.48 6.00 5.67 6.04 5.27 5.79 5.85 6.26 -- S.U. 03/16/11 5.53 5.91 5.74 6.15 5.29 5.93 6.08 6.42 -- S.U. 09/21/11 5.65 6.01 5.92 5.88 5.11 5.88 6.38 6.44 -- S.U. 03/21/12 5.92 5.67 5.79 5.61 4.76 5.79 6.01 6.26 4.86 S.U. 09/20/12 5.94 6.81 7.20 5.39 6.20 6.62 7.38 7.69 -- S.U. 03/20/13 5.60 6.11 6.02 6.21 5.84 6.06 5.95 6.31 4.85 S.U. 09/18/13 5.79 6.02 6.19 6.25 6.30 6.16 6.17 6.56 -- S.U. 03/27/14 5.29 6.24 5.46 5.94 6.33 6.31 5.87 7.35 4.42 S.U. 09/18/14 6.49 6.63 6.50 6.14 6.15 6.49 7.40 6.77 -- S.U. 03/18/15 5.71 6.25 5.93 6.17 6.36 6.20 6.21 6.23 4.97 S.U. 09/23/15 5.63 6.19 5.95 5.96 6.03 6.09 5.94 6.39 -- S.U. 03/15/16 5.15 5.43 5.58 6.08 5.48 5.94 5.73 5.83 4.64 S.U. 09/21/16 4.74 6.21 6.10 6.12 5.67 6.19 6.28 6.53 -- S.U. 03/21/17 5.20 6.03 5.73 5.95 5.55 5.88 5.67 5.97 4.72 (re -sample) S.U. 05/03/17 -- -- -- -- -- -- -- -- 3.97 S.U. 09/20/17 5.78 5.58 5.96 6.17 5.37 6.02 6.00 6.33 -- (verification event) S.U. 12/19/17 -- -- -- 6.36 -- -- -- -- -- S.U. 03/21/18 5.63 5.90 6.05 6.84 5.94 6.53 6.52 6.65 4.78 (verification event) S.U. 06/15/18 -- -- -- -- 5.11 -- 5.91 -- -- S.U. 09/24/18 5.60 5.8 5.95 6.32 5.6 7.71 6.03 5.71 -- S.U. 03/25/19 5.63 5.98 6.01 6.04 5.28 6.18 6.06 6.13 4.93 S.U. 09/18/19 4.77 6.03 5.79 6.35 4.80 5.90 6.23 6.32 -- S.U. 03/16/20 5.41 5.85 5.68 6.28 5.39 6.09 6.21 6.20 4.78 S.U. 09/23/20 5.66 5.96 5.97 6.41 5.22 5.84 5.75 5.77 -- S.U. 03/15/21 5.36 5.69 5.86 6.28 5.29 5.98 6.13 6.26 4.91 S.U. 09/20/21 5.65 6.12 6.15 6.66 5.19 6.18 6.28 6.40 -- S.U. 03/14/22 5.59 5.69 5.91 6.36 5.28 6.04 6.05 6.12 4.73 S.U. 09/19/22 5.19 6.20 5.81 6.46 5.03 6.97 6.00 6.01 -- (re-sample) S.U. 11/09/22 5.56 6.13 5.86 6.41 5.24 -- 6.01 -- -- S.U. 03/20/23 5.79 6.25 6.03 6.44 5.60 6.19 6.24 6.36 5.13 Specific Conductivity (field) US/cm 10/04/06 90 953 319 530 531 395 -- -- 56 US/cm 10/02/07 115 451 189 319 715 597 -- -- 85 US/cm 04/03/08 98 250 197 552 597 585 243 140 59 US/cm 03/24/09 110 150 330 730 200 650 610 130 120 US/cm 09/22/09 101 125 340 661 441 675 277 111 -- US/cm 03/22/10 148 Dry 339 884 89 560 248 109 -- uS/cm 09/23/10 181 1262 451 999 93 603 219 124 -- uS/cm 03/16/11 166 92 431 529 140 589 259 119 -- uS/cm 09/21/11 146 1228 494 989 94 563 282 114 -- US/cm 03/21/12 124 992 455 845 188 504 251 93 127 US/cm 09/20/12 116 257 468 488 209 513 251 111 -- US/cm 03/20/13 90 147 510 863 211 479 238 82 113 US/cm 09/18/13 171 965 995 1022 598 646 314 136 -- US/cm 03/27/14 171 391 770 1047 254 694 290 176 195 US/cm 09/18/14 180 1797 649 605 200 749 347 114 -- US/cm 03/18/15 191 157 716 805 548 700 310 143 160 US/cm 09/23/15 128 1876 562 911 558 634 262 120 -- US/cm 03/15/16 228 389 790 967 264 764 219 152 154 US/cm 09/21/16 180 1640 659 1140 192 703 200 144 -- US/cm 03/21/17 100 1342 601 960 273 597 240 143 109 (re -sample) uS/cm 05/03/17 -- -- -- -- -- -- -- -- 139 US/cm 09/20/17 122 360 580 1141 144 644 235 153 -- (verification event) uS/cm 12/19/17 -- -- -- 1028 -- -- -- -- -- US/cm 03/21/18 207 242 582 1124 299 668 246 162 179 (verification event) uS/cm 06/15/18 -- -- -- -- 265 -- 245 -- -- US/cm 09/24/18 176 540 737 1047 239 670 224 193 -- US/cm 03/25/19 270 237 806 728 268 499 215 174 205 US/cm 09/18/19 168 1393 670 1126 160 646 202 178 -- US/cm 03/16/20 159 337 998 1203 368 575 204 204 231 US/cm 09/23/20 133 263 756 1044 245 660 196 198 -- US/cm 03/15/21 140 961 849 1357 203 679 198 220 251 US/cm 09/20/21 112 622 710 1131 163 690 187 207 -- US/cm 03/14/22 90 164 709 1148 274 720 205 194 216 US/cm 09/19/22 93 267 696 1079 161 740 215 215 -- (re-sample) uS/cm 11/09/22 85 1526 696 1079 167 -- 204 -- -- us/cm 03/20/23 103 799 793 1115 186 842 227 231 167 1 of 3 July 2023 GL2014715721 TABLE 5 Summary of Field Parameters for MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 Upgradient Downgradient Compliance Wells Assessment Wells TVA Well Detected Monitoring Parameter Units Date Compliance Well MW-5 MW-6 MW-7 MW-8 AMW-1 S AMW-1 D AMW-2S AMW-2D MW-9 Temperature (field) Celsius 10/04/06 13.8 16.6 18.0 15.7 15.4 14.7 -- -- 13.7 Celsius 10/02/07 14.1 17.4 17.9 16.0 15.1 14.8 -- -- 13.6 Celsius 04/03/08 13.2 12.1 16.5 15.5 13.0 12.4 13.01 15.30 13.1 Celsius 03/24/09 12.6 14.9 18.5 17.3 17.6 16.8 13.6 11.9 13.7 Celsius 09/22/09 16.7 19.95 19.91 22.78 17.31 16.68 17.22 17.47 -- Celsius 03/22/10 13.17 Dry 14.97 11.76 10.08 10.97 9.33 7.41 -- Celsius 09/23/10 14.92 19.69 18.65 18.77 16.25 15.78 17.11 18.35 -- Celsius 03/16/11 12.61 9.68 15.64 15.08 11.96 11.95 10.02 9.24 -- Celsius 09/21/11 14.32 17.37 17.38 16.06 16.29 15.85 17.06 17.34 -- Celsius 03/21/12 15.20 14.46 16.53 17.08 15.47 15.45 13.25 12.95 14.46 Celsius 09/20/12 14.11 17.35 17.30 15.92 16.86 17.05 16.76 18.16 -- Celsius 03/20/13 12.82 13.84 16.78 16.17 12.68 13.26 10.12 9.10 11.54 Celsius 09/18/13 14.3 16.7 16.6 16.2 15.9 14.6 14.6 14.0 -- Celsius 03/27/14 12.7 13.4 15.4 15.3 13.4 13.4 11.0 10.9 11.3 Celsius 09/18/14 14.5 18.6 17.7 16.8 17.2 17.4 18.6 19.2 -- Celsius 03/18/15 14.2 12.7 16.2 16.5 14.8 14.7 10.9 13.8 13.5 Celsius 09/23/15 15.0 16.5 17.6 17.1 16.5 16.2 14.7 15.5 -- Celsius 03/15/16 15.3 15.8 15.9 17.3 16.2 16.5 15.0 15.1 14.5 Celsius 09/21/16 15.0 17.9 17.7 17.8 16.9 17.0 16.3 15.4 -- Celsius 03/21/17 16.1 14.0 16.5 15.6 15.0 14.9 13.0 13.5 14.4 (re -sample) Celsius 05/03/17 -- -- -- -- -- -- -- -- 15.5 Celsius 09/20/17 15.24 21.61 18.02 18.02 18.25 17.38 16.46 16.98 -- (verification event) Celsius 12/19/17 -- -- -- 17.44 -- -- -- -- -- Celsius 03/21/18 11.90 11.7 15.6 15.09 14.01 13.89 11.51 11.61 13.40 (verification event) Celsius 06/15/18 -- -- -- -- 16.8 -- 16.7 -- -- Celsius 09/24/18 16.16 18.47 17.71 18.27 17.81 16.57 15.8 15.96 -- Celsius 03/25/19 14.0 13.1 16.3 16.0 13.6 14.4 11.9 12.0 12.3 Celsius 09/18/19 15.5 18.1 17.4 17.7 17.1 16.5 15.3 15.8 -- Celsius 03/16/20 13.3 12.9 16.0 15.3 15.6 14.5 12.1 12.5 14.8 Celsius 09/23/20 14.5 19.3 18.0 17.9 17.9 16.2 15.6 15.1 -- Celsius 03/15/21 13.7 9.7 12.4 15.9 11.1 9.8 9.1 8.4 12.9 Celsius 09/20/21 16.6 19.3 17.6 17.6 16.9 16.8 15.4 15.8 -- Celsius 03/14/22 13.9 11.9 16.9 16.2 15.3 15.3 12.8 13.1 13.3 Celsius 09/19/22 16.5 19.4 19.5 18.4 18.8 17.9 16.3 16.1 -- (re-sample) Celsius 11/09/22 15.7 16.5 16.8 16.5 16.3 -- 14.8 -- -- Celsius 03/20/23 12.9 15.9 15.1 15.4 14.6 14.2 12.1 13.2 13.3 Turbidity (field) NTU 03/24/09 59.0 60.5 29.1 83.9 18.8 4.37 41.1 17.2 9.04 NTU 09/22/09 39.1 11.6 23.7 97.6 20.2 6.68 91.0 46.0 -- NTU 03/22/10 73.8 Dry 17.0 33.8 19.0 9.68 24.8 18.4 -- NTU 09/23/10 48.4 11.0 24.3 51.1 12.8 4.35 34.2 6.63 -- NTU 03/16/11 51.7 38.9 5.93 30.8 12.4 0.77 14.2 5.17 -- NTU 09/21/11 40.1 140 64.9 280 10.3 2.18 64.9 3.41 -- NTU 03/21/12 88.2 54.9 8.27 15.5 6.71 4.33 6.57 4.51 24.9 NTU 09/20/12 257 30.2 82.8 90.0 85.1 16.7 163 6.46 -- NTU 03/20/13 107 93.6 71.4 89.5 5.15 1.74 5.25 1.08 4.20 NTU 09/18/13 66.1 >1000 27.2 60.7 72.4 19.3 192 25.3 -- NTU 03/27/14 2.18 47.4 1.67 99.4 1.66 1.48 36.5 2.02 2.83 NTU 09/18/14 0.75 65.4 0.58 1.80 1.41 0.55 4.41 0.63 -- NTU 03/18/15 71.3 28.5 61.2 23.1 31.8 2.43 43.2 3.15 12.1 NTU 09/23/15 21.8 3.77 21.9 3.72 26.3 0.34 9.15 8.69 -- NTU 03/15/16 3.21 8.53 1.77 25.4 26.5 0.46 17.8 1.78 1.65 NTU 09/21/16 8.72 5.92 1.97 24.5 11.3 1.93 18.6 1.60 -- NTU 03/21/17 11.1 2.29 0.64 20.3 7.68 0.78 12.5 1.27 (re -sample) NTU 05/03/17 -- -- -- -- -- -- -- -- 1.40 NTU 09/20/17 6.77 4.17 0.17 8.13 2.89 0.26 1.49 1.50 -- (verification event) NTU 12/19/17 -- -- -- 5.54 -- -- -- -- -- NTU 03/21/18 9.70 2.88 0.36 8.76 7.56 1.07 5.51 2.69 1.27 (verification event) NTU 06/15/18 -- -- -- -- 3.76 -- 1.83 -- -- NTU 09/24/18 8.32 8.73 0.53 5.10 4.64 0.94 1.67 0.60 -- NTU 03/25/19 2.92 2.95 4.78 5.68 4.16 5.46 1.21 0.61 0.62 NTU 09/18/19 8.45 3.40 2.84 8.00 0.02 1.95 1.21 1.43 -- NTU 03/16/20 1.21 1.50 4.51 7.18 2.39 4.20 0.45 0.01 0.84 NTU 09/23/20 2.82 9.15 1.18 9.78 1.43 1.90 0.59 0.01 -- NTU 03/15/21 4.31 9.76 2.49 2.88 5.31 3.22 1.60 8.42 1.10 NTU 09/20/21 47.40 6.54 2.13 4.78 4.01 1.08 1.19 1.55 -- NTU 03/14/22 51.66 9.34 3.99 7.26 4.00 1.49 1.01 1.23 0.47 NTU 09/19/22 3.71 5.90 1.08 1.76 2.96 2.97 0.25 1.22 -- (re-sample) NTU 11/09/22 2.83 4.78 2.84 5.48 3.44 -- 3.18 -- -- NTU 03/20/23 2.27 109 3.43 2.65 0.97 4.36 1.21 1.63 0.21 2of3 July 2023 GL2014715721 TABLE 5 Summary of Field Parameters for MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 Upgradient Downgradient Compliance Wells Assessment Wells TVA Well Detected Monitoring Parameter Units Date Compliance Well MW-5 MW-6 MW-7 MW-8 AMWAS AMW-1D AMW-2S AMW-2D MW-9 Oxidation Reduction Potential (field) mV 09/22/09 178.9 -30.3 76.2 132.5 20.5 39.0 30.4 88.8 -- mV 09/23/15 148.0 -26.1 90.7 103.1 18.8 42.9 69.5 36.2 -- mV 03/15/16 253.3 -32.9 52.4 -16.8 129.1 87.1 125.3 150.8 270.0 mV 09/21/16 318.0 -43.2 43.1 -26.6 121.7 77.8 60.9 56.0 -- mV 03/21/17 262.8 -38.6 378 75.9 133 -80.4 118.6 150.3 -59.0 (re -sample) mV 05/03/17 -- -- -- -- -- -- -- -- 464.2 mV 09/20/17 89.0 6.8 103.2 16.5 215.4 185.5 128.1 153.3 -- (verification event) mV 12/19/17 -- -- -- -6.2 -- -- -- -- -- mV 03/21/18 359.3 73.9 337.5 -19.5 115.6 69.5 70.4 66.4 364.1 (verification event) mV 06/15/18 -- -- -- -- 248.5 -- 362.1 -- -- mV 09/24/18 124.6 -55.2 55.6 5.2 67.4 -152.6 3.3 -16.8 -- mV 03/25/19 195.5 12.2 31.5 60.0 214.4 99.7 176.5 137.1 360.5 mV 09/18/19 192.4 -54.8 51.2 -35.5 150.0 54.2 93.9 80.2 -- mV 03/16/20 276.4 -169.3 241.4 153.8 145.3 94.9 125.7 133.2 271.0 mV 09/23/20 122.4 -75.5 41.4 -43.0 28.7 -110.9 2.4 -83.0 -- mV 03/15/21 223.7 24.9 91.7 -7.9 188.9 116.4 176.3 102.2 148.1 mV 09/20/21 197.7 -44.2 122.4 -66.6 242.8 136.7 192.4 159.9 -- mV 03/14/22 213.8 152.6 141.7 -27.1 112.1 93.8 233.5 282.2 298.5 mV 09/19/22 122.5 -102.1 134.7 -56.6 222.9 49.2 88.6 94.7 -- (re-sample) mV 11/09/22 148.1 -6.1 142.5 -54.1 169.0 -- 141.3 -- -- mV 03/20/23 40.7 27.3 115.1 -82.7 2.5 153.8 -11.3 160.6 62.0 Dissolved Oxygen (field) mg/L 09/22/09 7.85 1.49 1.18 1.31 1.66 1.21 1.03 3.11 -- mg/L 09/23/15 7.30 1.70 1.08 0.78 4.80 0.33 0.64 4.21 -- mg/L 03/15/16 8.78 0.14 0.46 0.12 0.35 0.35 0.11 1.27 0.55 mg/L 09/21/16 7.41 0.39 1.59 1.09 2.45 1.17 0.80 2.36 -- mg/L 03/21/17 9.45 0.98 0.30 1.39 0.40 0.48 1.41 2.78 0.92 (re -sample) mg/L 05/03/17 -- -- -- -- -- -- -- -- 2.78 mg/L 09/20/17 2.21 1.39 0.72 1.07 4.48 1.26 0.39 1.15 -- (verification event) mg/L 12/19/17 -- -- -- 1.51 -- -- -- -- -- mg/L 03/21/18 6.59 0.27 0.49 1.04 0.15 1.28 0.25 1.04 1.44 (verification event) mg/L 06/15/18 -- -- -- -- 2.01 -- 0.93 -- -- mg/L 09/24/18 7.37 0.15 0.18 0.59 3.3 1.49 2.25 2.61 -- mg/L 03/25/19 8.16 0.11 0.20 0.08 2.42 1.66 0.43 2.00 1.96 mg/L 09/18/19 7.28 3.66 1.47 0.71 1.00 0.45 1.44 1.83 -- mg/L 03/16/20 7.21 0.21 0.49 0.30 1.89 2.28 0.81 1.49 1.60 mg/L 09/23/20 8.30 0.12 0.70 0.05 2.47 0.58 1.35 1.41 -- mg/L 03/15/21 7.81 5.30 6.32 0.76 7.15 5.09 8.79 6.36 1.31 mg/L 09/20/21 6.80 0.29 1.05 0.85 1.30 0.47 0.82 6.40 -- mg/L 03/14/22 7.26 2.19 1.06 0.28 0.16 0.23 0.61 1.55 1.24 mg/L 09/19/22 7.69 0.20 0.14 0.31 3.09 0.50 0.26 1.40 -- (re-sample) mg/L 11/09/22 8.37 0.19 0.17 0.18 1.23 -- 0.60 -- -- mg/L 03/20/23 9.50 3.59 0.38 1.19 4.47 0.42 0.56 0.91 8.35 Notes: NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter S.U. = Standard Units mg/L = milligrams per liter mV = Millivolts -- = no data available 1) Historical data prior to March 2009 provided by Henderson County and CDM. 3of3 July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Antimony ug/L 12/05/94 30 30 6 ND ND ND ND -- -- -- Human Health = 640 ug/L ug/L 02/14/95 30 30 6 ND ND -- ND -- -- -- ug/L 04/03/95 30 30 6 ND ND ND ND -- -- -- ug/L 10/30/95 30 30 6 ND ND ND ND -- -- -- ug/L 04/08/96 30 30 6 -- -- -- ND -- -- -- ug/L 10/24/96 30 30 6 ND ND ND ND -- -- -- ug/L 04/15/97 30 30 6 ND ND ND 5 -- -- -- ug/L 10/29/97 30 30 6 18 ND ND ND -- -- -- ug/L 05/14/98 -- -- 6 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 6 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 6 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 6 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 6 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 6 -- -- ND ND -- -- -- ug/L 10/16/01 30 30 6 ND -- ND ND -- -- -- ug/L 04/24/02 30 30 6 ND -- ND ND -- -- -- ug/L 10/01/02 30 30 6 ND -- ND ND -- -- -- ug/L 04/09/03 30 30 6 ND -- ND ND -- -- -- ug/L 10/20/03 30 30 6 ND ND ND ND -- -- -- ug/L 03/24/04 30 30 6 ND ND ND ND -- -- -- ug/L 10/27/04 30 30 6 ND ND ND ND -- -- -- ug/L 05/25/05 30 30 6 ND ND ND ND -- -- -- ug/L 10/04/05 30 30 6 ND ND ND ND -- -- -- ug/L 04/25/06 30 30 6 ND ND ND ND -- -- -- ug/L 10/04/06 30 30 6 ND ND ND ND -- -- ND ug/L 03/21/07 6.00 6.00 6 ND ND ND ND -- -- ND ug/L 10/02/07 0.05 6.00 6 ND ND ND ND -- -- ND ug/L 04/03/08 0.68 2.00 6 ND ND ND ND -- -- ND ug/L 10/29/08 0.68 2.00 6 ND -- ND ND -- -- ND ug/L 03/24/09 0.68 2.00 6 ND ND ND ND -- -- ND ug/L 09/22/09 0.073 2.00 6 ND ND ND ND -- -- ND ug/L 03/22/10 0.22 2.00 6 ND ND 0.521 J ND -- -- ND ug/L 09/23/10 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/16/11 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 09/21/11 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/21/12 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/20/13 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/27/14 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 09/18/14 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/18/15 0.22 2.00 6 ND 0.681 J 0.230 J ND -- -- ND ug/L 09/23/15 0.22 2.00 6 ND ND ND ND -- -- 0.331 J ug/L 03/15/16 0.22 2.00 6 ND 0.334 J ND ND -- -- ND ug/L 09/20/16 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 03/21/17 0.22 2.00 6 ND ND ND ND -- -- ND ug/L 09/20/17 0.37 2.00 6 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 0.37 2.00 6 ND -- -- -- -- -- ND ug/L 03/21/18 0.37 5.00 6 ND ND ND ND -- -- ND ug/L 09/25/18 1.85 5.00 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 09/18/19 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 09/23/20 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.74 2.00 -- ND ND ND ND -- -- ND ug/L 09/19/22 0.74 2.00 -- ND ND ND ND -- -- ND u /L 03/20/23 0.34 5.00 -- ND ND ND ND -- -- ND Arsenic ug/L 12/05/94 10.0 10.0 10 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 10.0 10.0 10 ND ND -- ND -- -- -- Acute: 340 ug/L ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- -- -- Chronic : 150 ug/L ug/L 10/30/95 10.0 10.0 10 ND 12 ND ND -- -- -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 10 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 10 19 ND ND ND -- -- -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 10 10 10 ND -- ND ND -- -- -- ug/L 10/20/03 10 10 10 ND ND ND ND -- -- -- ug/L 03/24/04 10 10 10 ND ND ND ND -- -- -- ug/L 10/27/04 10 10 10 ND ND 11.7 ND -- -- -- ug/L 05/25/05 10 10 10 ND ND ND ND -- -- -- ug/L 10/04/05 10 10 10 ND ND ND ND -- -- -- ug/L 04/25/06 10 10 10 ND ND ND ND -- -- -- ug/L 10/04/06 10 10 10 ND ND ND ND -- -- ND ug/L 03/21/07 10 10 10 ND ND 0.56 J 1.57 J -- -- ND ug/L 10/02/07 10 10 10 ND ND ND ND -- -- ND ug/L 04/03/08 10 10 10 ND ND 4.8 J 2.52 J -- -- ND ug/L 10/29/08 10 10 10 2.5 J -- 4.65 J 4.14 J -- -- ND ug/L 03/24/09 2.8 10 10 ND ND ND ND -- -- ND ug/L 09/22/09 2.8 10 10 4.69 B 2.94 B 3.11 B ND -- -- 2.90 ug/L 03/22/10 2.8 10 10 ND ND ND ND -- -- ND ug/L 09/23/10 2.8 10 10 ND ND ND ND -- -- ND ug/L 03/16/11 2.8 10 10 ND ND ND ND -- -- ND ug/L 09/21/11 2.8 10 10 ND ND 4.96 J ND -- -- ND ug/L 03/21/12 2.8 10 10 ND 4.18 J ND ND -- -- ND ug/L 09/20/12 2.8 10 10 ND ND ND ND -- -- 3.27 ug/L 03/20/13 2.8 10 10 ND ND ND ND -- -- ND ug/L 09/18/13 5.4 10 10 ND ND ND ND -- -- ND ug/L 03/27/14 5.4 10 10 ND ND ND ND -- -- ND ug/L 09/18/14 5.4 10 10 ND ND ND ND -- -- ND ug/L 03/18/15 5.4 10 10 ND ND ND ND -- -- ND ug/L 09/23/15 5.4 10 10 ND ND ND ND -- -- ND ug/L 03/15/16 5.4 10 10 ND ND ND ND -- -- ND ug/L 09/20/16 6.8 10 10 ND ND ND ND -- -- ND ug/L 03/21/17 6.8 10 10 ND 9.55 B ND ND -- -- 9.82 J ug/L 09/20/17 6.8 10 10 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 6.8 10 10 ND -- -- -- -- -- ND ug/L 03/21/18 6.8 10 10 ND 7.70 J ND ND -- -- ND ug/L 09/25/18 7.6 10 -- ND ND ND ND -- -- ND ug/L 03/26/19 7.6 10 -- ND ND ND ND -- -- ND ug/L 09/18/19 7.6 10 -- ND ND ND ND -- -- ND ug/L 03/16/20 7.6 10 -- ND ND ND ND -- -- ND ug/L 09/23/20 7.6 10 -- ND ND ND ND -- -- ND ug/L 03/16/21 7.6 10 -- ND ND 78.5 ND -- -- ND (Verification Event) ug/L 06/15/21 7.6 10 -- ND ND ND ND -- -- ND ug/L 09/20/21 7.6 10 -- ND ND ND ND -- -- ND ug/L 03/14/22 7.6 10 -- ND ND ND ND -- -- ND ug/L 09/19/22 7.6 10 -- ND ND ND ND -- -- ND u /L 03/20/23 6.4 20 -- ND ND ND ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Barium ug/L 12/05/94 500 500 100 ND ND ND ND -- -- -- Human Health = 200000 ug/L ug/L 02/14/95 500 500 100 131 ND -- ND -- -- -- ug/L 04/03/95 500 500 100 ND ND ND ND -- -- -- ug/L 10/30/95 500 500 100 ND ND ND ND -- -- -- ug/L 04/08/96 500 500 100 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 100 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 100 130 220 ND ND -- -- -- ug/L 10/29/97 -- -- 100 400 ND ND ND -- -- -- ug/L 05/14/98 -- -- 100 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 100 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 100 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 100 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 100 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 100 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 100 ND -- 111 ND -- -- -- ug/L 04/24/02 -- -- 100 ND -- ND ND -- -- -- ug/L 10/01 /02 -- -- 100 ND -- ND ND -- -- -- ug/L 04/09/03 500 500 100 ND -- ND ND -- -- -- ug/L 10/20/03 500 500 100 ND ND ND ND -- -- -- ug/L 03/24/04 500 500 100 ND ND ND ND -- -- -- ug/L 10/27/04 500 500 100 ND ND ND ND -- -- -- ug/L 05/25/05 500 500 100 ND ND ND ND -- -- -- ug/L 10/04/05 500 500 100 ND 4310 ND ND -- -- -- ug/L 04/25/06 500 500 100 ND ND ND ND -- -- -- ug/L 10/04/06 500 500 100 ND ND ND ND -- -- ND ug/L 03/21/07 500 500 100 22.7 J 193 342 36.3 J -- -- ND ug/L 10/02/07 500 500 100 77.5 B 266 697 42.2 B -- -- 16.1 ug/L 04/03/08 500 500 100 64.6 J 171 504 47.9 B -- -- 10.1 ug/L 10/29/08 500 500 100 78.6 B -- 732 B 65.1 B -- -- ND ug/L 03/24/09 4.2 10 100 73.2 J 273 575 42.1 J -- -- ND J ug/L 09/22/09 1.0 10 100 75.6 J 130 253 64.8 J -- -- ND ug/L 03/22/10 1.0 10 100 62.7 J 144 83.3 J 58.1 J -- -- 1.54 ug/L 09/23/10 1.0 10 100 45.6 J 163 361 26.1 J -- -- ND ug/L 03/16/11 1.0 10 100 89.8 J 265 199 63.2 J -- -- ND ug/L 09/21/11 1.0 10 100 65.3 J 200 253 52.5 J -- -- ND ug/L 03/21/12 1.0 10 100 46.2 J 240 323 38.0 J -- -- ND ug/L 09/20/12 1.0 10 100 70.1 J 219 439 43.4 J -- -- ND ug/L 03/20/13 1.0 10 100 41.8 J 171 194 42.0 J -- -- 1.34 ug/L 09/18/13 1.0 10 100 49.8 J 220 162 35.1 J -- -- 1.08 J ug/L 03/27/14 1.0 10 100 53.9 J 168 183 47.2 J -- -- ND ug/L 09/18/14 1.0 10 100 25.0 J 128 185 30.2 J -- -- 1.96 J ug/L 03/18/15 1.0 10 100 49.7 J 251 169 41.0 J -- -- ND ug/L 09/23/15 1.0 10 100 69.6 J 120 186 19.0 B -- -- 4.08 ug/L 03/15/16 1.0 10 100 51.1 J 182 128 44.8 J -- -- ND ug/L 09/20/16 1.0 10 100 17.6 J 131 177 24.7 J -- -- ND ug/L 03/21/17 1.0 10 100 32.8 J 219 223 25.9 J -- -- ND ug/L 09/20/17 1.0 10 100 -- 363 150 35.5 J -- -- ND (Verification Event) ug/L 10/02/17 1.0 10 100 32.7 J -- -- -- -- -- ND ug/L 03/21/18 1.0 10 100 35.0 J 195 116 41.9 J -- -- ND ug/L 09/25/18 1.1 10 -- 34.1 185 115 31.2 -- -- ND ug/L 03/26/19 1.1 10 -- 47.9 171 72.6 44.4 -- -- ND ug/L 09/18/19 1.1 10 -- 38.1 168 103 29.6 -- -- 3.97 J ug/L 03/16/20 1.1 10 -- 35.7 165 88.2 41.8 -- -- ND ug/L 09/23/20 1.1 10 -- 49.8 206 222 39.0 -- -- ND ug/L 03/16/21 1.1 10 -- 92.0 125 53.2 58.1 -- -- ND ug/L 09/20/21 1.1 10 -- 34.8 246 281 31.5 -- -- ND ug/L 03/14/22 1.1 10 -- 40.2 186 205 39.8 -- -- ND ug/L 09/19/22 1.1 10 -- 64.5 190 338 38.7 -- -- ND u /L 03/20/23 4.4 10 -- 29.3 178 219 35.0 -- -- ND Beryllium ug/L 12/05/94 2.00 2.00 1 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 2.00 2.00 1 ND ND -- ND -- -- -- Acute = 65 ug/L ug/L 04/03/95 2.00 2.00 1 ND ND ND ND -- -- -- Chronic = 6.5 ug/L ug/L 10/30/95 2.00 2.00 1 ND ND ND ND -- -- -- ug/L 04/08/96 2.00 2.00 1 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 1 9 ND ND ND -- -- -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 1 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 1 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 1 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 1 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- -- -- ug/L 05/25/05 2.00 2.00 1 ND ND ND ND -- -- -- ug/L 10/04/05 2.00 2.00 1 ND 4.07 ND ND -- -- -- ug/L 04/25/06 2.00 2.00 1 ND ND ND ND -- -- -- ug/L 10/04/06 2.00 2.00 1 ND ND ND ND -- -- ND ug/L 03/21/07 2.00 2.00 1 ND ND ND ND -- -- ND ug/L 10/02/07 2.00 2.00 1 1.97 B 2.28 B 3.9 B 1.97 B -- -- 6.01 ug/L 04/03/08 2.00 2.00 1 1.93 5.01 2.80 2.73 -- -- ND ug/L 10/29/08 2.00 2.00 1 6.46 B -- 10.2 B 7.9 B -- -- ND ug/L 03/24/09 0.08 1.00 1 ND ND 1.01 ND -- -- ND ug/L 09/22/09 0.10 1.00 1 ND ND 0.656 J ND -- -- ND ug/L 03/22/10 0.10 1.00 1 ND ND 0.318 J ND -- -- ND ug/L 09/23/10 0.10 1.00 1 ND ND 0.820 J ND -- -- ND ug/L 03/16/11 0.10 1.00 1 ND ND 0.543 J ND -- -- ND ug/L 09/21/11 0.10 1.00 1 ND ND 0.362 J ND -- -- ND ug/L 03/21/12 0.10 1.00 1 ND ND 0.736 J ND -- -- ND ug/L 09/20/12 0.10 1.00 1 ND ND 0.694 J ND -- -- ND ug/L 03/20/13 0.10 1.00 1 ND ND 0.227 J ND -- -- ND ug/L 09/18/13 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 03/27/14 0.10 1.00 1 ND ND 0.222 J ND -- -- ND ug/L 09/18/14 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 03/18/15 0.10 1.00 1 ND ND 0.163 J ND -- -- ND ug/L 09/23/15 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 03/15/16 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 09/20/16 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 03/21/17 0.10 1.00 1 ND ND ND ND -- -- ND ug/L 09/20/17 0.13 1.00 1 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 0.13 1.00 1 0.173 B -- -- -- -- -- 0.233 J ug/L 03/21/18 0.13 1.00 1 ND ND 0.174 J ND -- -- ND ug/L 09/25/18 0.16 1.00 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.16 1.00 -- ND ND 0.191 J ND -- -- ND ug/L 09/18/19 0.16 1.00 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.16 1.00 -- ND ND ND ND -- -- ND ug/L 09/23/20 0.16 1.00 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.16 1.00 -- 0.248 J ND ND ND -- -- ND ug/L 09/20/21 0.16 1.00 -- ND ND 0.170 J ND -- -- ND ug/L 03/14/22 0.16 1.00 -- ND ND 1.35 ND -- -- ND ug/L 09/19/22 0.16 1.00 -- ND ND 2.05 ND -- -- ND u /L 03/20/23 0.30 4.00 -- 0.590 B 0.530 B 0.930 B 0.570 BI 0.640 1 July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Cadmium ug/L 12/05/94 1.00 1.00 1 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 1.00 1.00 1 ND ND -- ND -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 1.00 1.00 1 ND ND ND ND -- -- -- BR-1 = 3.60 ug/L 10/30/95 1.00 1.00 1 ND ND ND ND -- -- -- BR-2 = 2.76 ug/L 04/08/96 1.00 1.00 1 -- -- -- ND -- -- -- BR-3 = 2.28 ug/L 10/24/96 -- -- 1 ND ND ND ND -- -- -- SW-1 = 3.35 ug/L 04/15/97 -- -- 1 ND ND ND ND -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 1 11 ND ND ND -- -- -- BR-1 = 0.54 ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- BR-2 = 0.43 ug/L 11/11/98 -- -- 1 ND ND ND ND -- -- -- BR-3 = 0.36 ug/L 06/04/99 -- -- 1 ND -- ND ND -- -- -- SW-1 = 0.51 ug/L 10/29/99 -- -- 1 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 1 1.5 -- 1.7 1.2 -- -- -- ug/L 11/07/00 -- -- 1 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 1 1.5 -- 1.2 1.5 -- -- -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- -- -- ug/L 03/24/04 1.00 1.00 1 ND ND ND ND -- -- -- ug/L 10/27/04 1.00 1.00 1 ND ND ND ND -- -- -- ug/L 05/25/05 1.00 1.00 1 ND ND ND ND -- -- -- ug/L 10/04/05 1.00 1.00 1 ND 111 ND ND -- -- -- ug/L 04/25/06 1.00 1.00 1 ND ND 1.15 1.03 -- -- -- ug/L 10/04/06 1.00 1.00 1 ND ND ND ND -- -- ND ug/L 03/21/07 1.00 1.00 1 1.42 J 2.71 J 1.36 J 0.51 J -- -- ND ug/L 10/02/07 1.00 1.00 1 ND ND 1.31 ND -- -- ND ug/L 04/03/08 1.00 1.00 1 ND ND 1.10 ND -- -- ND ug/L 10/29/08 1.00 1.00 1 ND -- 1.83 ND -- -- ND ug/L 03/24/09 0.09 1.00 1 ND ND 1.12 ND -- -- ND ug/L 09/22/09 0.36 1.00 1 ND ND 0.716 J ND -- -- ND ug/L 03/22/10 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/23/10 0.36 1.00 1 ND ND 0.487 J ND -- -- ND ug/L 03/16/11 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/21/11 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 03/21/12 0.36 1.00 1 ND ND 0.468 J ND -- -- ND ug/L 09/20/12 0.36 1.00 1 ND ND 0.691 J ND -- -- ND ug/L 03/20/13 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/18/13 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 03/27/14 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/18/14 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 03/18/15 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/23/15 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 03/15/16 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/20/16 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 03/21/17 0.36 1.00 1 ND ND ND ND -- -- 0.591 J ug/L 09/20/17 0.36 1.00 1 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 0.36 1.00 1 ND -- -- -- -- -- ND ug/L 03/21/18 0.36 1.00 1 ND ND ND ND -- -- ND ug/L 09/25/18 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 43550.00 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 09/18/19 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 09/23/20 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.36 1.00 -- ND ND ND ND -- -- ND ug/L 09/19/22 0.36 1.00 -- ND ND ND ND -- -- ND u /L 03/20/23 0.44 5.00 -- ND ND 1.07 J ND -- -- ND Chromium ug/L 12/05/94 10.0 10.0 10 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 10.0 10.0 10 ND ND -- ND -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- -- -- BR-1 = 737.34 ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- -- -- BR-2 = 574.43 ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- -- -- BR-3 = 479.45 ug/L 10/24/96 10.0 10.0 10 ND ND ND ND -- -- -- SW-1 = 688.49 ug/L 04/15/97 -- -- 10 ND ND ND ND -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 10 10 1 ND ND -- -- -- BR-1 = 95.91 ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- BR-2 = 74.72 ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- BR-3 = 62.37 ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- SW-1 = 89.56 ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- -- -- ug/L 05/25/05 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/04/05 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/07 10.0 10.0 10 1.44 J 3.02 J 2.38 J 2.86 J -- -- ND ug/L 10/02/07 10.0 10.0 10 5.39 B 5.08 B 4.58 B 4.07 B -- -- 3.67 ug/L 04/03/08 10.0 10.0 10 5.05 B 4.06 B 4.06 B 3.31 B -- -- 2.94 ug/L 10/29/08 10.0 10.0 10 6.96 B -- 6.34 B 6.10 B -- -- ND ug/L 03/24/09 0.7 10.0 10 2.0 J 3.4 J 1.9 J 1.4 J -- -- ND ug/L 09/22/09 1.0 10.0 10 ND 1.83 J ND ND -- -- ND ug/L 03/22/10 1.0 10.0 10 ND ND ND ND -- -- ND ug/L 09/23/10 1.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/16/11 1.0 10.0 10 2.21 J 3.97 J 2.42 J 1.64 J -- -- ND ug/L 09/21/11 1.0 10.0 10 1.29 J 3.44 J 1.78 J 1.06 J -- -- ND ug/L 03/21/12 1.0 10.0 10 1.39 J 2.21 J 2.19 J 1.10 J -- -- ND ug/L 09/20/12 1.0 10.0 10 ND 1.93 J 1.38 J ND -- -- ND ug/L 03/20/13 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/13 1.4 10.0 10 ND 1.92 J ND ND -- -- ND ug/L 03/27/14 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/14 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 03/18/15 1.4 10.0 10 ND 2.23 J ND ND -- -- ND ug/L 09/23/15 1.4 10.0 10 2.11 J ND ND ND -- -- ND ug/L 03/15/16 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/16 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/17 1.4 10.0 10 ND ND ND 2.62 J -- -- ND ug/L 09/20/17 1.4 10.0 10 -- 1.88 J ND ND -- -- ND (Verification Event) ug/L 10/02/17 1.4 10.0 10 ND -- -- -- -- -- ND ug/L 03/21/18 1.4 10.0 10 ND ND ND ND -- -- ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 1.4 10.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 1.4 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 1.4 10.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 1.4 10.0 -- 2.31 J 3.34 J 3.34 J 1.73 J -- -- ND ug/L 03/16/21 1.4 10.0 -- 2.43 J 2.37 J ND 1.64 J -- -- ND ug/L 09/20/21 1.4 10.0 -- 1.66 J 2.38 J ND ND -- -- ND ug/L 03/14/22 1.4 10.0 -- ND 2.78 J 2.02 J 1.66 J -- -- ND ug/L 09/19/22 1.4 10.0 -- 2.07 J 2.07 J 2.45 J 2.48 J -- -- ND u /L 03/20/23 1.1 10.0 -- ND ND ND ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Cobalt ug/L 12/05/94 10.0 10.0 10 ND ND ND ND -- -- No SW Standard ug/L 02/14/95 10.0 10.0 10 11 ND -- ND -- -- -- ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 10 4 1 ND ND -- -- -- ug/L 10/29/97 -- -- 10 -- -- -- -- -- -- -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- 10.7 ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- 10.7 ND -- -- -- ug/L 04/09/03 10.0 10.0 10 ND -- ND ND -- -- -- ug/L 10/20/03 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 03/24/04 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/27/04 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 05/25/05 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/04/05 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/07 10.0 10.0 10 2.52 J 3.56 J 4.76 J ND -- -- ND ug/L 10/02/07 10.0 10.0 10 ND ND ND ND -- -- ND ug/L 04/03/08 10.0 10.0 10 ND 5.32 J 3.66 J ND -- -- ND ug/L 10/29/08 10.0 10.0 10 7.54 J -- 7.90 J ND -- -- ND ug/L 03/24/09 0.6 10.0 10 3.9 J 4.8 J 4.8 J 1.0 J -- -- ND ug/L 09/22/09 1.1 10.0 10 1.21 J 5.16 J 1.90 J ND -- -- ND ug/L 03/22/10 1.1 10.0 10 3.17 J 6.20 J 1.39 J 2.71 J -- -- ND ug/L 09/23/10 1.1 10.0 10 2.38 J 5.61 J 3.38 J ND -- -- ND ug/L 03/16/11 1.1 10.0 10 1.94 J 5.87 J 1.82 J 1.85 J -- -- ND ug/L 09/21/11 1.1 10.0 10 3.22 J 9.89 J 3.13 J 2.29 J -- -- ND ug/L 03/21/12 1.1 10.0 10 2.44 J 8.93 J 2.84 J 1.71 J -- -- ND ug/L 09/20/12 1.1 10.0 10 2.52 J 8.43 J 3.31 J 1.12 J -- -- ND ug/L 03/20/13 1.1 10.0 10 1.77 J 3.49 J 2.03 J ND -- -- ND ug/L 09/18/13 1.1 10.0 10 3.01 J 3.55 J 1.19 J 1.19 J -- -- ND ug/L 03/27/14 1.1 10.0 10 3.47 J 4.19 J 2.75 J 2.45 J -- -- ND ug/L 09/18/14 1.1 10.0 10 ND 1.96 J 1.58 J ND -- -- ND ug/L 03/18/15 1.1 10.0 10 2.58 J 5.51 J 2.75 J 1.62 J -- -- ND ug/L 09/23/15 1.1 10.0 10 6.17 J ND ND ND -- -- ND ug/L 03/15/16 1.1 10.0 10 2.67 J 3.70 J 2.22 J 1.70 J -- -- ND ug/L 09/20/16 1.1 10.0 10 ND 1.29 J 1.84 J ND -- -- ND ug/L 03/21/17 1.1 10.0 10 ND 3.58 J 3.18 J ND -- -- ND ug/L 09/20/17 1.1 10.0 10 -- 8.77 J 1.50 J ND -- -- ND (Verification Event) ug/L 10/02/17 1.1 10.0 10 ND -- -- -- -- -- ND ug/L 03/21/18 1.1 10.0 10 1.68 J 4.02 J 2.30 J ND -- -- ND ug/L 09/25/18 1.4 10.0 -- ND 2.52 J ND ND -- -- ND ug/L 03/26/19 1.4 10.0 -- 2.97 J 3.60 J ND 1.83 J -- -- ND ug/L 09/18/19 1.4 10.0 -- ND 1.55 J 1.45 J ND -- -- ND ug/L 03/16/20 1.4 10.0 -- ND 2.60 J ND ND -- -- ND ug/L 09/23/20 1.4 10.0 -- 3.00 J 2.93 J 2.91 J 1.59 J -- -- ND ug/L 03/16/21 1.4 10.0 -- 1.90 J 3.46 J 1.89 J 1.72 J -- -- ND ug/L 09/20/21 1.4 10.0 -- ND 2.39 J 1.42 J ND -- -- ND ug/L 03/14/22 1.4 10.0 -- ND 2.20 J 2.85 J ND -- -- ND ug/L 09/19/22 1.4 10.0 -- 2.84 J 1.84 J 3.81 J ND -- -- ND u /L 03/20/23 1.4 10.0 -- ND 2.36 J 3.22 J ND -- -- ND Copper ug/L 12/05/94 200 200 10 ND ND ND ND -- -- -- SW Standards ug/L 02/14/95 200 200 10 ND ND -- ND -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 200 200 10 ND ND ND ND -- -- -- BR-1 = 18.08 ug/L 10/30/95 200 200 10 ND ND ND ND -- -- -- BR-2 = 13.57 ug/L 04/08/96 200 200 10 -- -- -- ND -- -- -- BR-3 = 11.02 ug/L 10/24/96 200 200 10 ND ND ND ND -- -- -- SW-1 = 16.71 ug/L 04/15/97 200 200 10 ND ND ND ND -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 200 200 10 ND -- ND ND -- -- -- BR-1 = 11.72 ug/L 05/14/98 200 200 10 ND ND ND ND -- -- -- BR-2 = 9.03 ug/L 11/11/98 200 200 10 ND ND ND ND -- -- -- BR-3 = 7.48 ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- SW-1 = 10.91 ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- -- -- ug/L 05/25/05 200 200 10 ND ND ND ND -- -- -- ug/L 10/04/05 200 200 10 ND ND ND ND -- -- -- ug/L 04/25/06 200 200 10 ND ND ND ND -- -- -- ug/L 10/04/06 200 200 10 ND ND ND ND -- -- ND ug/L 03/21/07 200 200 10 4.32 J 4.93 J 3.97 J 4.23 J -- -- ND ug/L 10/02/07 200 200 10 5.94 B 6.24 B 5.64 B 6.01 B -- -- 6.41 ug/L 04/03/08 200 200 10 4.96 B 4.27 B 4.53 B 5.38 B -- -- 4.46 ug/L 10/29/08 200 200 10 6.95 B -- 5.85 B 10.3 B -- -- ND ug/L 03/24/09 0.81 10.0 10 ND ND ND ND -- -- ND ug/L 09/22/09 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 03/22/10 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 09/23/10 1.6 10.0 10 ND ND 2.15 J ND -- -- ND ug/L 03/16/11 1.6 10.0 10 9.17 J ND 4.73 J 2.13 J -- -- ND ug/L 09/21/11 1.6 10.0 10 ND 3.90 J 2.35 J ND -- -- ND ug/L 03/21/12 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/12 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 03/20/13 1.6 10.0 10 ND ND 1.60 J ND -- -- ND ug/L 09/18/13 1.6 10.0 10 5.72 J ND ND ND -- -- ND ug/L 03/27/14 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/14 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 03/18/15 1.6 10.0 10 ND ND ND ND -- -- 1.74 ug/L 09/23/15 1.6 10.0 10 ND ND ND ND -- -- ND ug/L 03/15/16 1.6 10.0 10 ND ND ND ND -- -- 2.01 ug/L 09/20/16 1.6 10.0 10 1.61 B ND 2.27 B ND -- -- 3.37 J ug/L 03/21/17 1.6 10.0 10 ND ND ND ND -- -- 1.97 J ug/L 09/20/17 1.6 10.0 10 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 1.6 10.0 10 2.89 B -- -- -- -- -- 2.75 J ug/L 03/21/18 1.6 10.0 10 ND ND ND ND -- -- 1.87 J ug/L 09/25/18 1.6 10.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 1.6 10.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 1.6 10.0 -- ND ND 2.45 B 2.23 B -- -- 5.73 J ug/L 03/16/20 1.6 10.0 -- 2.11 B 1.69 B 2.11 B ND -- -- 2.00 J ug/L 09/23/20 1.6 10.0 -- ND ND ND ND -- -- 2.42 J ug/L 03/16/21 1.6 10.0 -- 8.00 J ND ND 2.39 J -- -- ND ug/L 09/20/21 1.6 10.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 1.6 10.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 1.6 10.0 -- ND ND ND ND -- -- 1.85 u /L 03/20/23 3.2 20.0 -- ND ND ND ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Lead ug/L 12/05/94 10.0 10.0 10 ND 38 8 7 -- -- -- SW Standards* ug/L 02/14/95 10.0 10.0 10 ND 5 -- 7 -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- -- -- BR-1 = 90.83 ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- -- -- BR-2 = 65.28 ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- -- -- BR-3 = 51.30 ug/L 10/24/96 10.0 10.0 10 ND 110 ND ND -- -- -- SW-1 = 82.98 ug/L 04/15/97 10.0 10.0 10 ND ND ND ND -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 10 28 ND ND ND -- -- -- BR-1 = 3.54 ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- BR-2 = 2.54 ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- BR-3 = 2.00 ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- SW-1 = 3.23 ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 18.5 -- ND ND -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- J ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 10 ND ND 11.6 ND -- -- -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- -- -- ug/L 10/04/05 10.0 10.0 10 ND 242 ND ND -- -- -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- -- -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/07 10.0 10.0 10 ND 1.56 J ND ND -- -- ND ug/L 10/02/07 10.0 10.0 10 0.49 B 0.65 B 0.46 B 0.49 B -- -- 0.49 J ug/L 04/03/08 10.0 10.0 10 5.13 J 7.36 J ND ND -- -- ND ug/L 10/29/08 10.0 10.0 10 6.36 B -- 7.18 B 10.1 B -- -- ND ug/L 03/24/09 1.6 10.0 10 2.8 J 3.9 J 3.8 J 2.1 J -- -- ND ug/L 09/22/09 1.9 10.0 10 ND 2.33 J ND ND -- -- ND ug/L 03/22/10 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/23/10 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/16/11 1.9 10.0 10 4.31 J 2.33 J 3.29 J ND -- -- ND ug/L 09/21/11 1.9 10.0 10 ND 8.03 J 2.33 J ND -- -- ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/12 1.9 10.0 10 3.64 B ND 2.28 B 3.19 B -- -- 2.70 J ug/L 03/20/13 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/13 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 03/27/14 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/14 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 03/18/15 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 09/23/15 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 03/15/16 2.1 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/16 3.1 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/17 3.1 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/17 3.1 10.0 10 -- 5.42 J ND 3.29 J -- -- ND (Verification Event) ug/L 10/02/17 3.1 10.0 10 ND -- -- -- -- -- ND ug/L 03/21/18 3.1 10.0 10 ND ND ND ND -- -- ND ug/L 09/25/18 3.1 10.0 -- ND ND ND ND -- -- 8.83 J ug/L 03/26/19 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 3.1 10.0 -- ND 3.14 J ND ND -- -- ND ug/L 09/23/20 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 3.1 10.0 -- 24.9 3.75 J 5.86 J 10.0 -- -- ND (Verification Event) ug/L 06/15/21 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 3.1 10.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 3.1 10.0 -- ND ND ND ND -- -- ND u /L 03/20/23 6.6 10.0 -- ND ND ND ND -- -- ND Nickel ug/L 12/05/94 50 50 50 ND ND ND ND -- -- -- SW Standards ug/L 02/14/95 50 50 50 ND ND -- ND -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 50 50 50 ND ND ND ND -- -- -- BR-1 = 611.13 ug/L 10/30/95 50 50 50 ND ND ND ND -- -- -- BR-2 = 472.19 ug/L 04/08/96 -- -- 50 -- -- -- ND -- -- -- BR-3 = 391.78 ug/L 10/24/96 -- -- 50 ND ND ND ND -- -- -- SW-1 = 569.35 ug/L 04/15/97 -- -- 50 ND ND ND ND -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 50 ND -- ND ND -- -- -- BR-1 = 67.88 ug/L 05/14/98 -- -- 50 ND ND ND ND -- -- -- BR-2 = 52.45 ug/L 11/11/98 -- -- 50 ND ND ND ND -- -- -- BR-3 = 43.51 ug/L 06/04/99 -- -- 50 ND -- ND ND -- -- -- SW-1 = 63.24 ug/L 10/29/99 -- -- 50 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 50 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 50 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 50 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 50 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 50 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 50 ND -- ND ND -- -- -- ug/L 10/20/03 50 50 50 ND ND ND ND -- -- -- ug/L 03/24/04 50 50 50 ND ND ND ND -- -- -- ug/L 10/27/04 50 50 50 ND ND ND ND -- -- -- ug/L 05/25/05 50 50 50 ND ND ND ND -- -- -- ug/L 10/04/05 50 50 50 ND ND ND ND -- -- -- ug/L 04/25/06 50 50 50 ND ND ND ND -- -- -- ug/L 10/04/06 50 50 50 ND ND ND ND -- -- ND ug/L 03/21/07 50 50 50 0.61 J ND 5.04 J ND -- -- ND ug/L 10/02/07 50 50 50 2.25 B 3.79 B 7.68 J 1.67 B -- -- 0.8 ug/L 04/03/08 50 50 50 ND ND ND ND -- -- ND ug/L 10/29/08 50 50 50 ND -- 8.09 J ND -- -- ND ug/L 03/24/09 0.6 10.0 50 2.0 J 2.5 J 4.2 J 1.0 J -- -- ND ug/L 09/22/09 1.8 10.0 50 2.17 J 3.90 J 2.65 J ND -- -- ND ug/L 03/22/10 1.8 10.0 50 ND 3.21 J ND ND -- -- ND ug/L 09/23/10 1.8 10.0 50 ND 2.24 J ND ND -- -- ND ug/L 03/16/11 1.8 10.0 50 2.92 J ND 2.04 J ND -- -- ND ug/L 09/21/11 1.8 10.0 50 ND 2.97 J 2.71 J ND -- -- ND ug/L 03/21/12 1.8 10.0 50 ND 2.31 J 2.51 J ND -- -- ND ug/L 09/20/12 1.8 10.0 50 ND 1.82 J 2.80 J ND -- -- ND ug/L 03/20/13 1.8 10.0 50 ND ND 2.04 J ND -- -- ND ug/L 09/18/13 1.8 10.0 50 ND 2.51 J ND ND -- -- ND ug/L 03/27/14 1.8 10.0 50 ND 2.16 J 2.23 J ND -- -- ND ug/L 09/18/14 1.8 10.0 50 ND ND ND ND -- -- ND ug/L 03/18/15 1.8 10.0 50 ND 2.24 J 1.99 J ND -- -- ND ug/L 09/23/15 1.8 10.0 50 17.8 J ND ND ND -- -- 2.22 ug/L 03/15/16 1.8 10.0 50 ND ND ND ND -- -- ND ug/L 09/20/16 2.2 10.0 50 ND ND ND ND -- -- ND ug/L 03/21/17 2.2 10.0 50 ND 3.30 B ND 2.13 B -- -- 2.69 J ug/L 09/20/17 2.2 10.0 50 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 2.2 10.0 50 2.32 B -- -- -- -- -- 2.66 J ug/L 03/21/18 2.2 10.0 50 ND ND ND ND -- -- ND ug/L 09/25/18 2.2 10.0 -- ND 2.95 B ND ND -- -- 10.1 ug/L 03/26/19 2.2 10.0 -- ND ND 2.21 J ND -- -- ND ug/L 09/18/19 2.2 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 2.2 10.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 2.2 10.0 -- ND 2.25 J 3.24 J ND -- -- ND ug/L 03/16/21 2.2 10.0 -- ND 2.40 J 2.21 J ND -- -- ND ug/L 09/20/21 2.2 10.0 -- ND ND 5.02 J ND -- -- ND ug/L 03/14/22 2.2 10.0 -- ND ND 4.67 J ND -- -- ND ug/L 09/19/22 2.2 10.0 -- ND ND 6.22 J ND -- -- ND u /L 03/20/23 3.3 40.0 -- ND ND 6.16 1 ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Selenium ug/L 12/05/94 20 20 10 ND ND ND ND -- -- -- SW Standards ug/L 02/14/95 20 20 10 ND ND -- ND -- -- -- Acute = 5 ug/L ug/L 04/03/95 20 20 10 ND ND ND ND -- -- -- Chronic = 5 ug/L ug/L 10/30/95 20 20 10 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 10 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 10 18 ND ND 8 -- -- -- ug/L 10/29/97 -- -- 10 26 -- ND ND -- -- -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- 10 ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- J ug/L 10/27/04 20 20 10 ND ND ND ND -- -- -- ug/L 05/25/05 20 20 10 ND ND ND ND -- -- -- ug/L 10/04/05 20 20 10 ND ND ND ND -- -- -- J ug/L 04/25/06 20 20 10 ND ND ND ND -- -- -- ug/L 10/04/06 20 20 10 ND ND ND ND -- -- ND ug/L 03/21/07 20 20 10 ND ND ND ND -- -- ND ug/L 10/02/07 20 20 10 10.4 8.22 J ND 9.83 J -- -- ND ug/L 04/03/08 20 20 10 ND 7.73 J 7.75 J 8.67 J -- -- ND ug/L 10/29/08 20 20 10 ND -- ND ND -- -- ND ug/L 03/24/09 3.4 10.0 10 ND ND ND ND -- -- ND ug/L 09/22/09 2.7 10.0 10 3.17 B ND ND 6.01 B -- -- 6.41 ug/L 03/22/10 0.83 1.00 10 ND 2.75 J ND ND -- -- ND ug/L 09/23/10 5.2 10.0 10 ND ND ND ND -- -- ND ug/L 03/16/11 2.7 10.0 10 ND ND ND 3.09 B -- -- 3.32 ug/L 09/21/11 2.7 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/12 2.7 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/12 2.7 10.0 10 ND ND ND ND -- -- ND ug/L 03/20/13 4.5 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/13 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/27/14 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/14 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/18/15 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 09/23/15 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 03/15/16 5.0 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/16 6.2 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/17 6.2 10.0 10 ND ND ND ND -- -- 14.1 J ug/L 09/20/17 6.2 10.0 10 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 6.2 10.0 10 ND -- -- -- -- -- ND ug/L 03/21/18 6.2 10.0 10 ND ND ND ND -- -- ND ug/L 09/25/18 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 6.2 10.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 6.2 10.0 -- ND ND ND ND -- -- ND u /L 03/20/23 10.0 20.0 -- ND ND ND ND -- -- ND Silver ug/L 12/05/94 1.9 10.0 10 ND ND ND ND -- -- -- SW Standards ug/L 02/14/95 -- -- 10 ND ND -- ND -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 -- -- 10 ND ND ND ND -- -- -- BR-1 = 5.53 ug/L 10/30/95 -- -- 10 ND ND ND ND -- -- -- BR-2 = 3.27 ug/L 04/08/96 -- -- 10 -- -- -- ND -- -- -- BR-3 = 2.24 ug/L 10/24/96 -- -- 10 ND ND ND ND -- -- -- SW-1 = 4.79 ug/L 04/15/97 -- -- 10 ND 0.2 ND 0.3 -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 10 2 -- ND ND -- -- -- BR-1 = 0.06 ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- BR-2 = 0.06 ug/L 11/11/98 -- -- 10 ND ND ND ND -- -- -- BR-3 = 0.06 ug/L 06/04/99 -- -- 10 ND -- ND ND -- -- -- SW-1 = 0.06 ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 10 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 10 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 10 1.32 J 1.01 J 0.97 J 0.99 J -- -- ND ug/L 10/02/07 -- -- 10 ND 1.55 J 1.25 J ND -- -- ND ug/L 04/03/08 -- -- 10 1.03 J 1.41 J 1.64 J 1.25 J -- -- ND ug/L 10/29/08 -- -- 10 6.03 B -- 5.77 B 5.32 B -- -- ND ug/L 03/24/09 1.0 10.0 10 1.3 J 2.5 J 2.4 J 1.3 J -- -- ND ug/L 09/22/09 1.9 10.0 10 ND 2.23 J ND ND -- -- ND ug/L 03/22/10 1.9 10.0 10 ND 2.89 J ND ND -- -- ND ug/L 09/23/10 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/16/11 1.9 10.0 10 ND 2.81 J ND ND -- -- ND ug/L 09/21/11 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/20/13 1.9 10.0 10 1.94 B 2.72 B ND ND -- -- 2.11 J ug/L 09/18/13 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/27/14 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/18/14 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/18/15 1.9 10.0 10 ND 2.16 J ND ND -- -- ND ug/L 09/23/15 1.9 10.0 10 2.18 B 1.93 B 2.33 B ND -- -- 4.69 J ug/L 03/15/16 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/20/16 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 03/21/17 1.9 10.0 10 ND ND ND ND -- -- 0.823 J ug/L 09/20/17 1.9 10.0 10 -- ND ND ND -- -- ND (Verification Event) ug/L 10/02/17 1.9 10.0 10 ND -- -- -- -- -- ND ug/L 03/21/18 1.9 10.0 10 ND ND ND ND -- -- ND ug/L 09/25/18 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 1.9 10.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 1.9 10.0 -- ND ND ND ND -- -- ND u /L 03/20/23 1.5 10.0 -- ND ND ND ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Thallium ug/L 12/05/94 200 200 5.5 ND ND ND ND -- -- No SW Standard ug/L 02/14/95 200 200 5.5 ND ND -- ND -- -- -- ug/L 04/03/95 200 200 5.5 ND ND ND ND -- -- -- ug/L 10/30/95 200 200 5.5 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 5.5 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 5.5 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 5.5 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 5.5 206 1 2 1 -- -- -- ug/L 05/14/98 -- -- 5.5 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 5.5 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 5.5 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 5.5 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 5.5 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 5.5 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 5.5 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 5.5 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 5.5 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 5.5 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 5.5 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 5.5 ND ND ND ND -- -- -- ug/L 10/27/04 200 200 5.5 ND ND ND ND -- -- -- ug/L 05/25/05 200 200 5.5 ND ND ND ND -- -- -- ug/L 10/04/05 200 200 5.5 ND ND ND ND -- -- -- ug/L 04/25/06 200 200 5.5 ND ND ND ND -- -- -- ug/L 10/04/06 200 200 5.5 ND ND ND ND -- -- ND ug/L 03/21/07 200 200 5.5 ND ND ND ND -- -- ND J ug/L 10/02/07 200 200 5.5 ND ND ND ND -- -- ND ug/L 04/03/08 200 200 5.5 ND ND ND ND -- -- ND ug/L 10/29/08 200 200 5.5 7.25 -- ND ND -- -- ND ug/L 03/24/09 0.036 1.00 5.5 ND ND ND ND -- -- 0.092 ug/L 09/22/09 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/22/10 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/23/10 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/16/11 0.11 1.00 5.5 0.465 J 0.415 J 0.192 J 0.675 J -- -- ND ug/L 09/21/11 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/21/12 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/20/12 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/20/13 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/18/13 0.11 1.00 5.5 ND ND ND ND -- -- 0.142 ug/L 03/27/14 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/18/14 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/18/15 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/23/15 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/15/16 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 09/20/16 0.11 1.00 5.5 ND ND ND ND -- -- ND ug/L 03/21/17 0.11 1.00 5.5 0.183 J 0.185 J ND 0.321 J -- -- ND ug/L 09/20/17 0.11 1.00 5.5 -- 0.258 J 0.129 J 0.397 J -- -- ND (Verification Event) ug/L 10/02/17 0.11 1.00 5.5 0.540 B -- -- -- -- -- 0.233 J ug/L 03/21/18 0.11 5.00 5.5 ND ND ND ND -- -- ND ug/L 09/25/18 0.55 5.00 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 09/18/19 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.22 2.00 -- ND 0.230 J ND 0.318 J -- -- ND ug/L 09/23/20 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 09/19/22 0.22 2.00 -- ND ND ND ND -- -- ND ug/L 03/20/23 0.26 1.00 -- ND ND ND ND -- -- ND Vanadium ug/L 12/05/94 40 40 25 ND ND ND ND -- -- No SW Standard ug/L 02/14/95 40 40 25 ND ND -- ND -- -- -- ug/L 04/03/95 40 40 25 ND ND ND ND -- -- -- ug/L 10/30/95 40 40 25 ND ND ND ND -- -- -- ug/L 04/08/96 40 40 25 -- -- -- ND -- -- -- ug/L 10/24/96 -- -- 25 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 25 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 25 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 25 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 25 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 25 ND -- ND ND -- -- -- ug/L 10/29/99 -- -- 25 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 25 ND -- ND ND -- -- -- ug/L 11/07/00 -- -- 25 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 25 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 25 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 25 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 25 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 25 ND ND ND ND -- -- -- ug/L 03/24/04 40 40 25 ND ND ND ND -- -- -- ug/L 10/27/04 40 40 25 ND ND ND ND -- -- -- ug/L 05/25/05 40 40 25 ND ND ND ND -- -- -- ug/L 10/04/05 40 40 25 ND 60.5 ND ND -- -- -- ug/L 04/25/06 40 40 25 ND ND ND ND -- -- -- ug/L 10/04/06 40 40 25 ND ND ND ND -- -- ND J ug/L 03/21/07 40 40 25 ND ND ND ND -- -- ND ug/L 10/02/07 40 40 25 ND ND ND ND -- -- ND ug/L 04/03/08 40 40 25 ND 4.61 J ND ND -- -- ND ug/L 10/29/08 40 40 25 ND -- 2.04 J 2.59 J -- -- ND ug/L 03/24/09 0.7 10 25 ND ND ND ND -- -- ND ug/L 09/22/09 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/22/10 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/23/10 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/16/11 1.4 10 25 4.70 J ND ND ND -- -- ND ug/L 09/21/11 1.4 10 25 ND 8.61 J ND ND -- -- ND ug/L 03/21/12 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/20/12 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/20/13 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/18/13 1.4 10 25 ND ND ND ND -- -- 0.142 ug/L 03/27/14 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/18/14 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/18/15 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/23/15 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/15/16 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/20/16 1.4 10 25 ND ND ND ND -- -- ND ug/L 03/21/17 1.4 10 25 ND 0.563 B ND 0.737 B -- -- 0.589 J ug/L 09/20/17 1.4 10 25 -- ND ND ND -- -- ND (re -sample) ug/L 10/02/17 1.4 10 25 ND -- -- -- -- -- ND ug/L 03/21/18 1.4 10 25 ND ND ND ND -- -- ND ug/L 09/25/18 1.4 10 -- ND ND ND ND -- -- ND ug/L 03/26/19 1.4 10 -- ND ND ND ND -- -- ND ug/L 09/18/19 1.4 10 -- ND ND ND ND -- -- ND ug/L 03/16/20 1.4 10 -- ND ND ND ND -- -- ND ug/L 09/23/20 1.4 10 -- ND ND ND ND -- -- ND ug/L 03/16/21 1.4 10 -- 3.63 J ND ND ND -- -- ND ug/L 09/20/21 1.4 10 -- ND ND ND ND -- -- ND ug/L 03/14/22 1.4 10 -- ND ND ND ND -- -- ND ug/L 09/19/22 1.4 10 -- ND ND ND ND -- -- ND u /L 03/20/23 1.0 10 -- 1.06 1 ND ND ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Zinc ug/L 12/05/94 50 50 10 16 27 26 40 -- -- -- SW Standards ug/L 02/14/95 50 50 10 30 300 -- 71 -- -- -- Fresh Water Acute (ug/L) ug/L 04/03/95 50 50 10 10 ND 21 51 -- -- -- BR-1 = 153.00 ug/L 10/30/95 50 50 10 ND 11 31 ND -- -- -- BR-2 = 118.17 ug/L 04/08/96 50 50 10 -- -- -- 40 -- -- -- BR-3 = 98.02 ug/L 10/24/96 -- -- 10 28 ND 16 13 -- -- -- SW-1 = 142.53 ug/L 04/15/97 -- -- 10 20 20 40 30 -- -- -- Fresh Water Chronic (ug/L) ug/L 10/29/97 -- -- 10 20 ND ND ND -- -- -- BR-1 = 154.25 ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- BR-2 = 119.14 ug/L 11/11/98 -- -- 10 ND ND 144 ND -- -- -- BR-3 = 98.82 ug/L 06/04/99 -- -- 10 ND -- 118 ND -- -- -- SW-1 = 143.69 ug/L 10/29/99 -- -- 10 ND -- ND ND -- -- -- ug/L 04/20/00 -- -- 10 ND -- 394 ND -- -- -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- -- -- ug/L 10/16/01 -- -- 10 ND -- 26 ND -- -- -- J ug/L 04/24/02 -- -- 10 ND -- 132 ND -- -- -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 10 82.7 -- ND 63 -- -- -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- -- -- ug/L 10/04/05 50 50 10 ND 487 ND ND -- -- -- ug/L 04/25/06 50 50 10 ND ND 107 ND -- -- -- ug/L 10/04/06 50 50 10 ND ND ND ND -- -- ND ug/L 03/21/07 50 50 10 6.76 J 9.01 J 37 8.63 J -- -- ND ug/L 10/02/07 50 50 10 5.22 J 15.3 J 24.4 24 -- -- ND ug/L 04/03/08 50 50 10 6.29 J 5.45 J 52.5 10.6 -- -- ND ug/L 10/29/08 50 50 10 9.19 J -- 37.6 29.4 -- -- ND ug/L 03/24/09 3.4 10 10 5.5 B 5.6 B 35.6 3.6 B -- -- 3.4 ug/L 09/22/09 3.8 10 10 9.11 J 8.90 J 71.4 11.3 -- -- ND ug/L 03/22/10 3.8 10 10 11.4 6.16 J 24.9 9.02 J -- -- ND ug/L 09/23/10 3.8 10 10 ND 4.03 J 46.1 18.8 -- -- ND J ug/L 03/16/11 3.8 10 10 30.6 5.84 J 53.8 8.11 J -- -- ND ug/L 09/21/11 3.8 10 10 6.85 J 22.1 69.0 ND -- -- ND ug/L 03/21/12 3.8 10 10 ND ND 22.7 ND -- -- ND ug/L 09/20/12 3.8 10 10 ND 5.00 J 19.4 ND -- -- ND ug/L 03/20/13 3.8 10 10 ND 6.72 J 35.9 ND -- -- ND ug/L 09/18/13 3.8 10 10 9.22 J 4.03 J 12.5 ND -- -- ND ug/L 03/27/14 3.8 10 10 ND 4.30 J 25.9 ND -- -- ND ug/L 09/18/14 3.8 10 10 ND 5.11 J 9.98 J ND -- -- ND ug/L 03/18/15 3.8 10 10 ND 4.48 J 34.2 3.83 J -- -- ND ug/L 09/23/15 3.8 10 10 ND ND 7.06 J ND -- -- ND ug/L 03/15/16 3.8 10 10 ND ND 25.1 ND -- -- ND ug/L 09/20/16 4.4 10 10 ND ND 7.32 J ND -- -- ND ug/L 03/21/17 4.4 10 10 ND ND 33.2 ND -- -- ND ug/L 09/20/17 4.4 10 10 -- 30.3 15.4 ND -- -- ND (Verification Event) ug/L 10/02/17 4.4 10 10 ND -- -- -- -- -- ND ug/L 03/21/18 4.4 10 10 ND 5.64 J 32.2 ND -- -- ND ug/L 09/25/18 4.4 10 -- ND 4.90 B 20.5 B ND -- -- 64.2 ug/L 03/26/19 4.4 10 -- 5.40 J 5.09 J 21.5 ND -- -- ND ug/L 09/18/19 4.4 10 -- 4.89 J 4.93 J 15.8 4.64 J -- -- ND ug/L 03/16/20 4.4 10 -- ND 5.83 J 17.6 4.83 J -- -- ND ug/L 09/23/20 4.4 10 -- ND 25.3 34.7 ND -- -- ND ug/L 03/16/21 4.4 10 -- 37.2 23.9 36.2 18.5 -- -- ND (Verification Event) ug/L 06/15/21 4.4 10 -- ND -- -- ND -- -- ND ug/L 09/20/21 4.4 10 -- ND ND 34.8 ND -- -- ND ug/L 03/14/22 4.4 10 -- ND 4.91 J 48.8 ND -- -- ND ug/L 09/19/22 4.4 10 -- ND ND 68.2 13.9 -- -- ND ug/L 03/20/23 8.7 20 -- ND ND 39.7 12.6 J -- -- ND Acetone ug/L 12/05/94 100 100 100 ND ND ND ND -- -- -- SW Standard =2.0 mg/L ug/L 02/14/95 100 100 100 ND ND ND ND -- -- -- Human Health =1100 mg/L ug/L 04/03/95 100 100 100 ND ND ND ND -- -- -- ug/L 10/30/95 100 100 100 ND ND ND ND -- -- -- ug/L 04/08/96 100 100 100 -- ND ND ND -- -- -- ug/L 05/29/96 100 100 100 -- ND ND ND -- -- -- ug/L 06/06/96 100 100 100 -- ND ND ND -- -- -- ug/L 10/24/96 -- -- 100 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 100 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 100 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 100 ND ND ND ND -- -- -- J ug/L 11/11/98 -- -- 100 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 100 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 100 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 100 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 100 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 100 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 100 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 100 ND -- ND ND -- -- -- ug/L 04/09/03 100 100 100 ND -- ND ND -- -- -- ug/L 10/20/03 100 100 100 ND ND ND ND -- -- -- ug/L 03/24/04 100 100 100 ND ND ND ND -- -- -- J ug/L 10/27/04 100 100 100 ND ND ND ND -- -- -- ug/L 05/25/05 100 100 100 ND ND ND ND -- -- -- ug/L 10/04/05 100 100 100 ND ND ND ND -- -- -- J ug/L 04/25/06 100 100 100 ND ND ND ND -- -- -- ug/L 10/04/06 100 100 100 ND ND ND ND -- -- ND ug/L 03/21/07 100 100 100 ND ND ND ND -- -- ND ug/L 10/02/07 100 100 100 3.51 B 1.73 B ND ND -- -- 5.5 ug/L 04/03/08 100 100 100 ND ND ND ND -- -- ND ug/L 10/29/08 100 100 100 ND -- ND ND -- -- ND ug/L 03/24/09 1.5 5.0 100 ND ND ND ND -- -- ND ug/L 09/22/09 1.5 5.0 100 ND ND ND ND -- -- ND ug/L 03/22/10 1.5 5.0 100 2.3 J ND ND 2.5 J -- -- ND ug/L 06/03/10 1.5 5.0 100 -- -- -- -- 11 J 3.6 J ND ug/L 09/23/10 1.5 5.0 100 ND ND ND ND -- -- ND ug/L 03/16/11 1.2 5.0 100 ND 4.2 J 3.0 J ND 13 J ND ND ug/L 09/21/11 1.2 5.0 100 ND 7.0 J ND ND 5.5 J ND ND ug/L 03/21/12 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 09/20/12 1.2 5.0 100 ND 7.4 B ND ND dry 4.7 B 7.0 ug/L 03/20/13 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 09/18/13 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 03/27/14 1.2 5.0 100 ND ND 5.5 B 4.7 B dry ND 19 ug/L 09/18/14 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 03/18/15 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 09/23/15 1.2 5.0 100 ND ND ND ND dry ND ND ug/L 03/15/16 1.2 5.0 100 ND ND ND ND -- -- ND ug/L 09/20/16 10 20 100 ND ND ND ND -- -- ND ug/L 03/21/17 10 20 100 ND ND ND ND -- -- ND ug/L 09/20/17 10 20 100 ND 13 J ND ND -- -- ND ug/L 03/21/18 10 20 100 ND ND ND ND -- -- ND ug/L 09/25/18 10 20 -- ND ND ND ND -- -- ND ug/L 03/26/19 10 20 -- ND ND ND ND -- -- 12 J ug/L 09/18/19 10 20 -- ND ND ND ND -- -- ND ug/L 03/16/20 10 20 -- ND ND ND ND -- -- ND ug/L 09/23/20 10 20 -- ND ND ND ND -- -- 16 J ug/L 03/16/21 10 20 -- ND ND ND ND -- -- ND ug/L 09/20/21 10 20 -- ND ND ND ND -- -- ND ug/L 03/14/22 10 20 -- ND ND ND ND -- -- 10 J ug/L 09/19/22 10 20 -- ND ND ND ND -- -- ND u /L 03/20/23 10 20 -- ND ND ND ND -- -- 10 1 July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Benzene ug/L 12/05/94 0.2 1 1 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 -- -- 1 ND ND ND ND -- -- -- Human Health = 51 ug/L ug/L 04/03/95 -- -- 1 ND ND ND ND -- -- -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 1 -- ND ND ND -- -- -- ug/L 05/29/96 -- -- 1 -- ND ND ND -- -- -- ug/L 06/06/96 -- -- 1 -- ND ND ND -- -- -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 1 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 1 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- -- -- J ug/L 10/27/04 -- -- 1 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 1 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 1 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 1 ND 0.86 J ND ND -- -- ND ug/L 10/02/07 -- -- 1 0.16 J 0.76 J ND ND -- -- ND ug/L 04/03/08 -- -- 1 ND 0.39 J ND ND -- -- ND ug/L 10/29/08 -- -- 1 0.12 J -- ND ND -- -- ND ug/L 03/24/09 0.20 1.0 1 ND ND ND ND -- -- ND ug/L 09/22/09 0.20 1.0 1 ND ND ND ND -- -- ND ug/L 03/22/10 0.050 1.0 1 ND ND ND ND -- -- ND ug/L 09/23/10 0.20 1.0 1 ND ND ND ND -- -- ND ug/L 03/16/11 0.68 1.0 1 ND ND ND ND ND ND ND ug/L 09/21/11 0.68 1.0 1 ND ND ND ND ND ND ND ug/L 03/21/12 0.15 1.0 1 ND 0.46 J ND ND dry ND ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND ND dry ND 1.75 ug/L 03/27/14 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 09/23/15 0.15 1.0 1 ND ND ND ND dry ND ND ug/L 03/15/16 0.15 1.0 1 ND ND ND ND -- -- ND ug/L 09/20/16 0.15 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/17 0.15 1.0 1 ND ND ND ND -- -- ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND -- -- ND ug/L 09/25/18 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 0.15 1.0 -- ND ND ND ND -- -- ND ug/L 03/20/23 0.15 1.0 -- ND ND ND ND -- -- ND Chlorobenzene ug/L 12/05/94 0.27 1.0 3 ND ND ND ND -- -- -- SW Standard = 140 ug/L ug/L 02/14/95 -- -- 3 ND ND ND ND -- -- -- Human Health = 1.6 mg/L ug/L 04/03/95 -- -- 3 ND ND ND ND -- -- -- ug/L 10/30/95 -- -- 3 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 3 -- ND ND ND -- -- -- ug/L 05/29/96 -- -- 3 -- ND ND ND -- -- -- ug/L 06/06/96 -- -- 3 -- ND ND ND -- -- -- ug/L 10/24/96 -- -- 3 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 3 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 3 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 3 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 3 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 3 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 3 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 3 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 3 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 3 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 3 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 3 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 3 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 3 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 3 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 3 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 3 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 3 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 3 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 3 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 3 ND 1.69 ND ND -- -- ND ug/L 10/02/07 -- -- 3 0.86 J 2.2 J ND ND -- -- ND ug/L 04/03/08 -- -- 3 0.43 J 1.22 J ND ND -- -- ND ug/L 10/29/08 -- -- 3 0.86 J -- ND ND -- -- ND ug/L 03/24/09 0.27 1.0 3 0.53 J 0.72 J ND ND -- -- ND ug/L 09/22/09 0.27 1.0 3 ND 1.0 J ND ND -- -- ND ug/L 03/22/10 0.069 1.0 3 ND 0.77 J ND ND -- -- ND ug/L 06/03/10 0.069 1.0 3 -- -- -- -- ND ND ND ug/L 09/23/10 0.27 1.0 3 0.42 J 0.79 J ND ND -- -- ND ug/L 03/16/11 0.74 1.0 3 ND 1.1 J ND ND ND ND ND ug/L 09/21/11 0.74 1.0 3 ND ND ND ND ND ND ND ug/L 03/21/12 0.17 1.0 3 ND 2.2 J ND ND dry ND ND ug/L 09/20/12 0.17 1.0 3 ND ND ND ND dry ND ND ug/L 03/20/13 0.17 1.0 3 ND 0.46 J ND ND dry ND ND ug/L 09/18/13 0.17 1.0 3 ND 0.55 J ND ND dry ND ND ug/L 03/27/14 0.17 1.0 3 ND ND ND ND dry ND ND ug/L 09/18/14 0.17 1.0 3 ND ND ND ND dry ND ND ug/L 03/18/15 0.17 1.0 3 ND 0.70 J ND ND dry ND ND ug/L 09/23/15 0.17 1.0 3 1.3 J ND ND ND dry ND ND ug/L 03/15/16 0.17 1.0 3 ND ND ND ND -- -- ND ug/L 09/20/16 0.17 1.0 3 ND ND ND ND -- -- ND ug/L 03/21/17 0.17 1.0 3 ND ND ND ND -- -- ND ug/L 09/20/17 0.17 1.0 3 ND ND ND ND -- -- ND ug/L 03/21/18 0.17 1.0 3 ND ND ND ND -- -- ND ug/L 09/25/18 0.17 1.0 -- ND 0.44 J ND ND -- -- ND ug/L 03/26/19 0.17 1.0 -- ND 0.69 J ND ND -- -- ND ug/L 09/18/19 0.17 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.17 1.0 -- ND 0.51 J ND ND -- -- ND ug/L 09/23/20 0.17 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.17 1.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.17 1.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.17 1.0 -- ND ND ND ND -- -- ND ug/L 09/19/22 0.17 1.0 -- 0.75 J ND ND ND -- -- ND u /L 03/20/23 0.17 1.0 -- ND 0.541 1 0.210 1 ND -- -- ND July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks Chloroform ug/L 03/24/09 0.20 1.0 5 ND ND ND ND -- -- ND Human Health = 170 ug/L ug/L 09/22/09 0.20 1.0 5 ND ND ND ND -- -- ND ug/L 03/22/10 0.083 1.0 5 ND ND ND ND -- -- ND ug/L 06/03/10 0.083 1.0 5 -- -- -- -- ND ND ND ug/L 09/23/10 0.20 1.0 5 ND ND ND ND -- -- ND ug/L 03/16/11 0.70 1.0 5 ND ND ND ND ND ND ND ug/L 09/21/11 0.70 1.0 5 ND ND ND ND ND ND ND ug/L 03/21/12 0.18 1.0 5 ND ND ND ND dry ND ND ug/L 09/20/12 -- -- 5 ND ND ND ND dry ND ND ug/L 03/20/13 0.18 1.0 5 ND ND ND ND Dry ND ND ug/L 09/18/13 0.18 1.0 5 ND ND ND ND dry ND ND ug/L 03/27/14 0.18 1.0 5 ND ND ND ND dry ND ND ug/L 09/18/14 0.18 1.0 5 ND ND ND ND dry ND ND ug/L 03/18/15 5 ND ND ND ND ND ND ug/L 09/23/15 5 ND ND ND ND dry ND ND ug/L 03/15/16 5 ND ND ND ND -- -- ND ug/L 10/20/16 0.18 1.0 5 ND ND ND ND -- -- ND ug/L 03/21/17 5 ND ND ND ND -- -- ND ug/L 09/20/17 0.18 1.0 5 ND ND ND ND -- -- ND ug/L 03/21/18 0.18 1.0 5 ND ND ND ND -- -- ND ug/L 09/25/18 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.18 1 -- ND ND ND ND ND ug/L 09/18/19 0.18 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.18 1.0 -- ND ND ND ND ND ug/L 09/23/20 -- ND ND ND ND -- -- ND ug/L 03/16/21 ND ND ND ND -- -- ND ug/L 09/20/21 0.18 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.18 1.0 -- ND ND ND ND -- -- 0.47 J ug/L 09/19/22 0.18 1.0 -- ND ND ND ND -- -- ND u /L 03/20/23 0.18 1 -- 0.244 B 0.280 B 0.293 B 0.223 B -- -- 0.503 J 1,2-Dichlorobenzene ug/L 12/05/94 0.27 1 5 ND ND ND ND -- -- -- No SW Standard ug/L 02/14/95 -- -- 5 ND ND ND ND -- -- -- ug/L 04/03/95 -- -- 5 ND ND ND ND -- -- -- ug/L 10/30/95 -- -- 5 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 5 -- ND ND ND -- -- -- ug/L 05/29/96 -- -- 5 -- ND ND ND -- -- -- ug/L 06/06/96 -- -- 5 -- ND ND ND -- -- -- ug/L 10/24/96 -- -- 5 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 5 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 5 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 5 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 5 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 5 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 5 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 5 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 5 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 5 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 5 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 5 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 5 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 5 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 5 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 5 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 5 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 5 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 5 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 5 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 5 ND ND ND ND -- -- ND ug/L 10/02/07 -- -- 5 0.27 J 0.23 J ND ND -- -- ND ug/L 04/03/08 -- -- 5 0.12 J ND ND ND -- -- ND ug/L 10/29/08 -- -- 5 0.28 J -- ND ND -- -- ND ug/L 03/24/09 0.27 1.0 5 ND 0.49 J ND ND -- -- ND ug/L 09/22/09 0.27 1.0 5 ND ND ND ND -- -- ND ug/L 03/22/10 0.052 1.0 5 ND ND ND ND -- -- ND ug/L 06/03/10 0.052 1.0 5 -- -- -- -- ND ND ND ug/L 09/23/10 0.27 1.0 5 ND ND ND ND -- -- ND ug/L 03/16/11 0.11 1.0 5 ND 0.79 J ND ND ND ND ND ug/L 09/21/11 0.11 1.0 5 ND ND ND ND ND ND ND ug/L 03/21/12 0.19 1.0 5 ND 0.51 J ND ND dry ND ND ug/L 09/20/12 0.19 1.0 5 ND 0.59 J ND ND dry ND ND ug/L 03/20/13 0.19 1.0 5 ND ND ND ND dry ND ND ug/L 09/18/13 0.19 1.0 5 ND 0.48 J ND ND dry ND ND ug/L 03/27/14 0.19 1.0 5 ND ND ND ND dry ND ND ug/L 09/18/14 0.19 1.0 5 ND ND ND ND dry ND ND ug/L 03/18/15 0.19 1.0 5 ND 0.60 J ND ND dry ND ND ug/L 09/23/15 0.19 1.0 5 ND ND ND ND dry ND ND ug/L 03/15/16 0.19 1.0 5 ND ND ND ND -- -- ND ug/L 09/20/16 0.19 1.0 5 ND ND ND ND -- -- ND ug/L 03/21/17 0.19 1.0 5 ND ND ND ND -- -- ND ug/L 09/20/17 0.19 1.0 5 ND 0.50 J ND ND -- -- ND ug/L 03/21/18 0.19 1.0 5 ND ND ND ND -- -- ND ug/L 09/25/18 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 09/18/19 0.19 1.0 -- ND 0.29 J ND ND -- -- ND ug/L 03/16/20 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 09/23/20 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.19 1.0 -- ND 0.44 J ND ND -- -- ND ug/L 09/20/21 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.19 1.0 -- ND 0.41 J ND ND -- -- ND ug/L 09/19/22 0.19 1.0 -- ND ND ND ND -- -- ND u /L 03/20/23 0.19 1.0 -- ND 0.323 J ND ND -- -- ND 10 of 12 July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSW-1 TSW-2 Blanks 1,4-Dichlorobenzene ug/L 12/05/94 0.2 1 1 ND ND ND -- -- -- No SW Standard ug/L 02/14/95 -- -- 1 ND ND ND -- -- -- -- ug/L 04/03/95 -- -- 1 ND ND ND -- -- -- -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 1 -- ND ND -- -- -- -- ug/L 05/29/96 -- -- 1 -- ND ND -- -- -- -- ug/L 06/06/96 -- -- 1 -- ND ND -- -- -- -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 1 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 1 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 1 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 1 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 1 0.19 J 2.26 0.37 J ND -- -- ND ug/L 10/02/07 -- -- 1 0.87 J 3.57 ND ND -- -- ND ug/L 04/03/08 -- -- 1 0.39 J 1.55 J ND ND -- -- ND ug/L 10/29/08 -- -- 1 1.01 J -- ND ND -- -- ND ug/L 03/24/09 0.38 1.0 1 0.59 J 2.4 ND ND -- -- ND ug/L 09/22/09 0.38 1.0 1 ND 1.6 ND ND -- -- ND ug/L 03/22/10 0.10 1.0 1 ND 1.4 ND ND -- -- ND ug/L 06/03/10 0.10 1.0 1 -- -- -- -- ND ND ND ug/L 09/23/10 0.38 1.0 1 ND 3.0 ND ND -- -- ND ug/L 03/16/11 0.79 1.0 1 ND 2.8 ND ND ND ND ND ug/L 09/21/11 0.79 1.0 1 ND ND ND ND ND ND ND ug/L 03/21/12 0.19 1.0 1 ND 4.5 ND ND dry ND ND ug/L 09/20/12 0.19 1.0 1 0.40 J 5.9 ND ND dry ND ND ug/L 03/20/13 0.19 1.0 1 ND 1.4 ND ND dry ND ND ug/L 09/18/13 0.19 1.0 1 ND 1.7 ND ND dry ND ND ug/L 03/27/14 0.19 1.0 1 ND ND ND ND dry ND ND ug/L 09/18/14 0.19 1.0 1 ND 0.55 J ND ND dry ND ND ug/L 03/18/15 0.19 1.0 1 ND 2.2 ND ND dry ND ND ug/L 09/23/15 0.19 1.0 1 0.87 J ND ND ND dry ND ND ug/L 03/15/16 0.19 1.0 1 ND 0.93 J ND ND -- -- ND ug/L 09/20/16 0.19 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/17 0.19 1.0 1 ND ND ND ND -- -- ND ug/L 09/20/17 0.19 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/18 0.19 1.0 1 ND 1.3 ND ND -- -- ND ug/L 09/25/18 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/26/19 0.19 1.0 -- ND 1.4 ND ND -- -- ND ug/L 09/18/19 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/20 0.19 1.0 -- ND 1.3 ND ND -- -- ND ug/L 09/23/20 0.19 1.0 -- ND 1.3 ND ND -- -- ND ug/L 03/16/21 0.19 1.0 -- ND 1.5 ND ND -- -- ND ug/L 09/20/21 0.19 1.0 -- ND ND ND ND -- -- ND ug/L 03/14/22 0.19 1.0 -- ND 1.5 ND ND -- -- ND ug/L 09/19/22 0.19 1.0 -- 0.47 J ND ND ND -- -- ND u /L 03/20/23 0.19 1.0 -- ND 1.29 ND ND -- -- ND Methylene chloride ug/L 12/05/94 0.24 2 1 ND ND ND ND -- -- -- SW Standard ug/L 02/14/95 -- -- 1 ND ND ND ND -- -- -- Human Health = 590 ug/L ug/L 04/03/95 -- -- 1 ND ND ND ND -- -- -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- -- -- ug/L 04/08/96 -- -- 1 -- ND ND ND -- -- -- ug/L 05/29/96 -- -- 1 -- ND ND ND -- -- -- ug/L 06/06/96 -- -- 1 -- ND ND ND -- -- -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- -- -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/97 -- -- 1 ND ND ND ND -- -- -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- -- -- ug/L 06/04/99 -- -- 1 ND ND ND ND -- -- -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- -- -- ug/L 04/20/00 -- -- 1 ND ND ND ND -- -- -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- -- -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- -- -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- -- -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- -- -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- -- -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- -- -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- -- -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- -- -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/05 -- -- 1 ND ND ND ND -- -- -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- -- -- ug/L 10/04/06 -- -- 1 ND ND ND ND -- -- ND ug/L 03/21/07 -- -- 1 ND ND ND ND -- -- ND ug/L 10/02/07 -- -- 1 ND ND ND ND -- -- 0.41 ug/L 04/03/08 -- -- 1 ND ND ND ND -- -- 0.42 ug/L 10/29/08 0.44 5 1 ND -- ND 0.19 J -- -- ND ug/L 03/24/09 0.53 2.0 1 ND ND ND ND -- -- ND ug/L 09/22/09 0.53 1.0 1 ND ND ND ND -- -- ND ug/L 03/22/10 0.070 1.0 1 ND ND ND ND -- -- ND ug/L 06/03/10 0.070 1.0 1 -- -- -- -- ND ND ND ug/L 09/23/10 0.53 1.0 1 ND ND ND ND -- -- ND ug/L 03/16/11 0.14 1.0 1 ND ND ND ND ND ND ND ug/L 09/21/11 0.14 1.0 1 ND ND ND ND ND ND ND ug/L 03/21/12 0.23 1.0 1 ND ND ND ND dry ND ND ug/L 09/20/12 0.23 -- 1 ND ND ND ND dry ND ND ug/L 03/20/13 0.23 1.0 1 ND ND ND ND dry ND ND ug/L 09/18/13 0.23 1.0 1 ND ND ND ND dry ND ND ug/L 03/27/14 0.23 1.0 1 ND ND ND ND dry ND ND ug/L 09/18/14 0.23 1.0 1 ND ND ND ND dry ND ND ug/L 03/18/15 0.23 -- 1 ND ND ND ND dry ND ND ug/L 09/23/15 0.23 -- 1 ND ND ND ND dry ND ND ug/L 03/15/16 0.23 -- 1 ND ND ND ND -- -- ND ug/L 09/20/16 0.23 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/17 0.23 -- 1 ND ND ND ND -- -- ND ug/L 09/20/17 0.23 1.0 1 ND ND ND ND -- -- ND ug/L 03/21/18 0.23 1.0 1 ND ND ND ND -- -- ND ug/L 09/25/18 0.23 -- -- ND ND ND ND -- -- 0.43 J ug/L 03/26/19 0.23 1.0 -- ND ND ND ND ND ug/L 09/18/19 0.23 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.23 1.0 -- ND ND ND ND ND ug/L 09/23/20 0.23 1.0 -- ND ND ND ND -- -- ND ug/L 03/16/21 0.23 1.0 -- ND ND ND ND -- -- ND ug/L 09/20/21 0.23 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.23 1.0 -- ND ND ND ND -- -- 0.67 J ug/L 09/19/22 0.23 1.0 -- ND ND ND ND -- -- 0.47 ug/L 03/20/23 0.23 1.0 -- ND 0.486 B 0.256 B ND -- -- 0.470 J 11 of 12 July 2023 TABLE 6 GL2014715721 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 TSWA TSW-2 Blanks 1,4-Dioxane ug/L 09/25/18 1.2 2.0 -- 1.4 J 7.2 1.3 J 1.7 J -- -- ND SW Standard = 0.35 ug/L ug/L 03/26/19 1.2 2.0 -- ND 7.7 1.2 J 1.2 J -- -- ND ug/L 09/18/19 1.2 2.0 -- 2.1 8.0 1.8 J 2.8 -- -- ND ug/L 03/16/20 0.80 2.0 -- 1.1 J 6.6 1.3 J 1.6 J -- -- ND ug/L 09/23/20 0.80 2.0 -- 1.3 J 6.3 1.3 J 1.9 J -- -- ND ug/L 03/16/21 0.80 2.0 -- ND 2.8 ND ND -- -- ND ug/L 09/20/21 0.80 2.0 -- 1.1 J 7.9 1.2 J 2.3 -- -- ND ug/L 03/14/22 0.80 2.0 -- 0.96 J 7.6 1.2 J 1.8 J -- -- ND ug/L 09/19/22 0.80 2.0 -- 4.0 8.2 1.7 J 2.1 -- -- ND u /L 03/20/23 0.32 0.5 -- 0.794 7.78 0.989 1.63 -- -- ND Notes: mg/L = milligrams per liter ug/L = micrograms per liter ND = Not detected at the stated reporting limit uS/cm = microsiemens per centimeter J = Estimated concentration B = Blank -qualified result -- = no data available dry = there was no discernible flow and a sample was not collected. SW Standard = Surface Water Standard based on Freshwater Aquatic Life Classification unless otherwise noted 1) Surface Water Standards based on Fresh Water Aquatic Life Classification Blanks = field, trip and method blanks Bold = concentrations above the chronic SW Standards or Human Health Standards have been bolded Highlighted= concentrations above the acute SW Standards have been highlighted SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 (N) = Narrative Standard (AL) = Action Level Standard 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2022 event: antimony and thallium (2X) in all locations. * = Acute and Chronic surface water standards for Cadmium, Chromium, Copper, Lead, Nickel, Silver, and Zinc are based on hardness concentrations at each monitoring location. Hardness was 137 mg/L at BR-1, 101 mg/L at BR-2, 81 mg/L at BR-3, and 126 mg/L at SW-1 during the March 2021 event. 12 of 12 July 2023 GL2014715721 TABLE 7 Summary of Field Parameters for Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date BR-1 BR-2 BR-3 SW-1 pH (field) S.U. 10/05/06 5.90 6.62 6.74 6.80 S.U. 10/02/07 6.35 6.37 6.25 7.20 S.U. 04/01/08 6.61 6.41 6.35 7.32 S.U. 03/24/09 7.48 7.83 7.50 7.84 S.U. 09/22/09 6.94 6.81 7.06 7.01 S.U. 03/22/10 6.29 6.32 6.34 6.75 S.U. 09/23/10 7.27 7.17 6.55 7.44 S.U. 03/16/11 7.16 6.42 6.48 6.65 S.U. 09/21/11 6.95 7.51 6.65 7.41 S.U. 03/21/12 6.62 6.67 6.32 6.93 S.U. 09/20/12 7.18 5.24 7.69 7.75 S.U. 03/20/13 6.61 7.06 6.45 6.89 S.U. 09/18/13 7.23 7.17 6.83 7.18 S.U. 03/26/14 6.84 7.17 6.58 7.32 S.U. 09/18/14 7.57 6.54 6.85 6.31 S.U. 03/18/15 6.86 7.16 6.88 7.52 S.U. 09/23/15 6.71 7.06 7.13 6.49 S.U. 03/15/16 6.61 6.65 6.54 6.73 S.U. 09/20/16 6.76 6.02 6.64 5.41 S.U. 03/21/17 7.40 6.60 6.86 6.17 S.U. 09/20/17 6.55 7.15 6.89 7.55 (Verification Event) S.U. 10/02/17 7.55 -- -- -- S. U. 03/21/18 8.13 8.01 7.37 7.90 S.U. 09/25/18 7.26 7.09 6.62 7.05 S.U. 03/25/19 7.21 7.20 6.93 7.26 S.U. 09/18/19 7.06 7.21 7.06 7.37 S.U. 03/16/20 7.12 6.93 6.66 7.17 S.U. 09/24/20 6.73 6.57 6.22 7.33 S.U. 03/16/21 7.39 6.98 6.69 7.21 (Verification Event) S.U. 06/15/21 7.28 6.93 6.85 7.19 S.U. 09/20/21 7.40 7.30 6.62 7.32 S.U. 03/14/22 7.11 7.18 6.74 7.34 S.U. 09/19/22 6.18 6.92 6.78 6.97 S.U. 03/20/23 7.42 7.27 6.94 7.30 Specific Conductivity (field) US/cm 10/05/06 530 765 1512 184 US/cm 10/02/07 498 1029 3037 321 US/cm 04/01/08 400 932 2355 400 US/cm 03/24/09 620 810 3230 360 US/cm 09/22/09 388 845 1328 338 US/cm 03/22/10 343 783 403 317 US/cm 09/23/10 506 1217 2605 343 US/cm 03/16/11 357 715 2341 354 US/cm 09/21/11 484 863 2149 326 US/cm 03/21/12 347 1025 2466 250 US/cm 09/20/12 418 1017 3162 269 US/cm 03/20/13 171 456 1567 177 US/cm 09/18/13 356 738 1782 307 US/cm 03/26/14 339 685 2688 342 US/cm 09/18/14 401 691 2212 345 US/cm 03/18/15 323 366 2766 297 US/cm 09/23/15 505 561 2455 278 US/cm 03/15/16 316 666 1587 326 US/cm 09/20/16 264 542 1990 265 US/cm 03/21/17 423 700 6161 308 US/cm 09/20/17 386 785 1966 349 (Verification Event) uS/cm 10/02/17 365 -- -- -- US/cm 03/21/18 284 669 1869 292 US/cm 09/25/18 351 697 3302 311 US/cm 03/25/19 282 619 1346 334 US/cm 09/18/19 397 708 1863 376 US/cm 03/16/20 315 714 1796 354 US/cm 09/24/20 365 660 7060 346 US/cm 03/16/21 243 406 1705 242 (Verification Event) uS/cm 06/15/21 339 554 2193 325 US/cm 09/20/21 300 673 4303 367 US/cm 03/14/22 261 593 3663 281 US/cm 09/19/22 409 587 436 292 US/cm 03/20/23 229 641 436 230 1 of 3 July 2023 GL2014715721 TABLE 7 Summary of Field Parameters for Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date BR-1 BR-2 BR-3 SW-1 Temperature (field) Celsius 10/05/06 15.7 16.0 15.9 17.0 Celsius 10/02/07 13.6 14.9 15.30 14.9 Celsius 04/01/08 15.9 10.7 10.7 15.9 Celsius 03/24/09 13.4 14.8 8.2 14.4 Celsius 09/22/09 20.5 18.6 19.5 19.2 Celsius 03/22/10 6.8 8.1 7.7 7.8 Celsius 09/23/10 20.1 18.1 19.6 19.4 Celsius 03/16/11 8.1 11.2 11.3 7.1 Celsius 09/21/11 16.7 20.1 18.1 16.6 Celsius 03/21/12 13.4 17.0 17.7 14.4 Celsius 09/20/12 15.7 17.8 16.1 16.3 Celsius 03/20/13 2.4 10.3 7.8 7.7 Celsius 09/18/13 16.0 17.7 17.3 16.9 Celsius 03/26/14 10.6 6.9 10.7 3.9 Celsius 09/18/14 17.8 17.3 17.9 16.6 Celsius 03/18/15 12.7 13.0 14.0 9.0 Celsius 09/23/15 18.3 19.1 19.1 18.1 Celsius 03/15/16 8.5 10.0 16.3 8.9 Celsius 09/20/16 22.4 20.7 20.3 20.5 Celsius 03/21/17 15.0 17.0 15.5 16.5 Celsius 09/20/17 18.3 20.4 18.1 19.3 (Verification Event) Celsius 10/02/17 14.5 -- -- -- Celsius 03/21/18 9.00 10.47 9.35 9.03 Celsius 09/25/18 19.4 19.6 18.8 18.6 Celsius 03/25/19 8.3 11.7 8.0 8.3 Celsius 09/18/19 18.7 19.0 18.4 18.2 Celsius 03/16/20 11.1 12.0 10.6 10.4 Celsius 09/24/20 15.3 17.3 15.7 15.2 Celsius 03/16/21 4.7 6.8 4.6 5.5 (Verification Event) Celsius 06/15/21 17.7 18.1 18.1 17.5 Celsius 09/20/21 18.0 19.2 18.1 17.7 Celsius 03/14/22 6.3 9.8 6.7 6.9 Celsius 09/19/22 18.3 18.0 15.6 16.0 Celsius 03/20/23 6.9 10.4 7.9 7.6 Turbidity (field) NTU 03/24/09 34.2 12.7 3.02 6.58 NTU 09/22/09 69.3 29.7 24.9 9.06 NTU 03/22/10 29.6 12.6 10 23 NTU 09/23/10 54.2 6.72 11.3 3.51 NTU 03/16/11 74.6 8.59 23.6 20.7 NTU 09/21 /11 66.4 215 42.8 35.9 NTU 03/21 /12 27.7 97.4 17.0 11.4 NTU 09/20/12 67.0 30.2 12.5 67.0 NTU 03/20/13 40.7 19.1 10.1 9.60 NTU 09/18/13 23.4 24.9 14.3 16.9 NTU 03/26/14 24.9 6.90 14.7 9.87 NTU 09/18/14 2.32 4.95 1.46 2.84 NTU 03/18/15 10.40 6.35 3.19 11.10 NTU 09/23/15 20.2 1.05 0.90 1.01 NTU 03/15/16 17.9 10.5 5.01 4.75 NTU 09/20/16 5.73 2.78 2.03 3.71 NTU 03/21 /17 3.93 6.39 3.85 3.27 NTU 09/20/17 4.16 22.7 1.20 2.05 (Verification Event) NTU 10/02/17 -- -- -- -- NTU 03/21 /18 10.5 5.54 2.80 8.76 NTU 09/25/18 9.67 4.23 7.48 2.66 NTU 03/25/19 26.2 17.2 14.1 13.7 NTU 09/18/19 19.3 4.84 2.44 3.77 NTU 03/16/20 8.59 9.53 3.36 4.87 NTU 09/24/20 7.29 40.8 34.2 3.17 NTU 03/16/21 482 32.0 70.3 202 (Verification Event) NTU 06/15/21 12.3 9.81 9.53 3.73 NTU 09/20/21 14.7 11.11 3.74 2.19 NTU 03/14/22 6.98 8.43 3.59 4.40 NTU 09/19/22 6.47 7.65 9.41 2.65 NTU 03/20/23 10.81 8.83 10.7 7.60 2 of 3 July 2023 GL2014715721 TABLE 7 Summary of Field Parameters for Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date BR-1 BR-2 BR-3 SWA Oxidation Reduction Potential (field) mV 09/22/09 -27.9 -51.1 -35.1 26.6 mV 03/22/10 -9.7 -45.7 47.1 -29.0 mV 09/23/10 -27.2 -134.9 -2.0 30.2 mV 03/16/11 15.1 31.4 1.3 -1.6 mV 09/21/11 -34.1 -25.4 -18.9 -41.0 mV 03/21 /12 15.4 -51.4 11.0 7.71 mV 09/20/12 -180.3 1.0 -136.6 -129.5 mV 03/20/13 1.5 -42.3 9.7 -1.7 mV 09/18/13 14.2 -31.0 60.7 90.6 mV 03/26/14 -105.6 -120.6 -80.5 -75.0 mV 09/18/14 86.8 66.5 45.0 179.9 mV 03/18/15 26.8 -40.9 7.0 76.0 mV 09/23/15 -13.3 118.2 74.5 155.9 mV 03/15/16 7.3 -0.5 -2.3 37.3 mV 09/20/16 170.1 190.8 171.0 213.8 mV 03/21/17 -- -- -1.5 200.6 mV 09/20/17 3.00 -- -8.1 28.1 (Verification Event) mV 10/02/17 -- -- -- -- mV 03/21 /18 -29.4 -51.4 -4.4 -6.8 mV 09/25/18 -52.5 -89.4 4.6 42.9 mV 03/25/19 -45.2 -13.2 3.2 -14.8 mV 09/18/19 -21.1 2.4 -5.4 51.1 mV 03/16/20 -55.2 -43.5 -10.3 39.0 mV 09/24/20 -46.7 -70.9 -30.1 -53.3 mV 03/16/21 -1.7 20.8 46.5 49..6 (Verification Event) mV 06/15/21 -43.7 -14.0 -13.9 76.3 mV 09/20/21 28.8 -47.1 83.0 74.3 mV 03/14/22 -77.5 -77.8 -41.7 -62.4 mV 09/19/22 33.7 104.9 -4.3 37.0 mV 03/20/23 -48.1 -62.4 -21.4 -34.5 Dissolved Oxygen (field) mg/L 09/22/09 4.00 4.20 4.33 5.02 mg/L 03/22/10 10.99 9.49 9.03 10.47 mg/L 09/23/10 6.87 24.0 6.36 6.28 mg/L 03/16/11 14.68 13.44 8.76 10.47 mg/L 09/21 /11 7.42 6.32 6.90 8.74 mg/L 03/21 /12 8.37 6.04 7.23 13.9 mg/L 09/20/12 5.53 12.35 6.67 7.13 mg/L 09/18/13 8.19 5.36 6.09 5.86 mg/L 03/26/14 10.75 8.64 9.54 9.33 mg/L 09/18/14 6.17 5.45 6.38 6.12 mg/L 03/18/15 11.15 9.01 8.17 10.03 mg/L 09/23/15 4.77 4.18 5.09 4.93 mg/L 03/15/16 8.39 5.82 8.33 6.95 mg/L 09/20/16 7.91 4.18 6.84 6.32 mg/L 03/21 /17 -- -- 7.50 7.45 mg/L 09/20/17 6.37 -- 6.75 5.87 (Verification Event) mg/L 10/02/17 -- -- -- -- mg/L 03/21 /18 6.98 7.94 7.56 7.31 mg/L 09/25/18 6.67 4.00 7.43 5.71 mg/L 03/25/19 10.42 5.87 9.43 9.84 mg/L 09/18/19 5.27 3.17 7.43 5.39 mg/L 03/16/20 10.02 7.95 9.16 8.94 mg/L 09/24/20 7.48 5.62 6.56 7.41 mg/L 03/16/21 12.15 10.57 11.88 11.63 (Verification Event) mg/L 06/15/21 5.72 3.61 6.17 4.71 mg/L 09/20/21 7.26 4.04 6.01 4.61 mg/L 03/14/22 10.41 9.41 10.07 8.76 mg/L 09/19/22 10.41 9.41 10.07 8.76 m /L 03/20/23 10.41 9.41 10.46 8.76 Notes: mg/L = milligrams per liter S.U. = Standard Units NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter mV = Millivolts -- = no data available dry = there was no discernible flow and a sample was not collected. 1) Historical data prior to March 2009 provided by Henderson County and CDM. 3 of 3 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Antimony ug/L 03/24/09 0.68 2.00 6 ND ND ND ND ND NC 2L = 1 ug/L ug/L 09/22/09 0.073 2.00 6 ND ND 0.098 J ND ND EPA MCL = 6 ug/L ug/L 03/24/10 0.22 2.00 6 ND ND ND ND ND ug/L 09/22/10 0.22 2.00 6 ND ND ND ND ND ug/L 03/16/11 0.22 2.00 6 ND ND 0.248 J 0.360 J ND ug/L 09/21/11 0.22 2.00 6 0.255 J -- ND 0.609 J ND ug/L 03/21/12 0.22 2.00 6 0.365 J 0.965 J ND ND ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND ND ug/L 03/20/13 0.22 2.00 6 ND 0.323 J ND ND ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND ND ug/L 03/27/14 0.22 2.00 6 ND 0.870 J ND ND ND ug/L 09/18/14 0.22 2.00 6 0.335 J 0.893 J ND ND ND ug/L 03/18/15 0.22 2.00 6 0.653 J 0.742 J ND ND ND ug/L 09/23/15 0.22 2.00 6 ND ND ND ND 0.331 J ug/L 03/15/16 0.22 2.00 6 0.908 J ND ND ND ND ug/L 09/21/16 0.22 2.00 6 ND 0.282 J ND ND ND ug/L 03/23/17 0.22 2.00 6 Dry ND ND ND ND ug/L 09/20/17 0.22 2.00 6 ND ND ND ND ND ug/L 03/21/18 0.22 5.00 6 ND ND ND ND ND ug/L 09/25/18 1.85 5.00 -- ND ND ND ND ND ug/L 03/25/19 0.74 2.00 -- ND ND ND ND ND ug/L 09/19/19 0.74 2.00 -- ND ND ND ND ND ug/L 03/16/20 0.74 2.00 -- ND ND ND ND ND ug/L 09/24/20 0.74 2.00 -- ND ND ND ND ND ug/L 03/16/21 0.74 2.00 -- ND ND ND ND ND ug/L 09/20/21 0.74 2.00 -- ND ND ND ND ND ug/L 03/14/22 0.74 2.00 -- ND ND ND ND ND ug/L 09/19/22 0.74 2.00 -- ND ND ND ND ND ug/L 03/30/23 0.34 5.00 -- ND ND ND ND ND Arsenic ug/L 06/21/01 -- -- 10 ND ND ND ND -- NC 2L = 10 ug/L ug/L 04/24/02 -- -- 10 ND ND ND ND -- EPA MCL = 10 ug/L ug/L 10/01/02 -- -- 10 ND ND ND ND -- ug/L 04/10/03 -- -- 10 ND ND ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/05/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/05/06 -- -- 10 ND ND ND ND ND ug/L 03/21/07 -- -- 10 ND ND ND ND ND ug/L 10/02/07 -- -- 10 2.79 J ND ND 4.85 J ND ug/L 04/01 /08 -- -- 10 10.1 3.01 J 6.29 J 9.48 J ND ug/L 10/29/08 -- -- 10 ND ND ND ND ND ug/L 03/24/09 2.8 10.0 10 ND ND ND ND ND ug/L 09/22/09 2.8 10.0 10 ND 3.81 J 3.64 J ND ND ug/L 03/24/10 2.8 10.0 10 ND ND ND ND ND ug/L 09/22/10 2.8 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.8 10.0 10 ND ND ND ND ND ug/L 09/21/11 2.8 10.0 10 ND -- ND ND ND ug/L 03/21/12 2.8 10.0 10 ND ND ND ND ND ug/L 09/20/12 2.8 10.0 10 ND ND ND ND 3.27 J ug/L 03/20/13 2.8 10.0 10 ND ND 3.23 J ND ND ug/L 09/18/13 5.4 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.4 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.4 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.4 10.0 10 ND ND ND ND ND ug/L 09/21/16 5.4 10.0 10 ND ND ND ND ND ug/L 03/23/17 5.4 10.0 10 Dry ND ND ND ND ug/L 09/20/17 5.4 10.0 10 ND ND ND ND ND ug/L 03/21/18 5.4 10.0 10 ND ND ND ND ND ug/L 09/25/18 7.6 10.0 -- ND ND ND ND ND ug/L 03/25/19 7.6 10.0 -- ND ND ND ND ND ug/L 09/19/19 7.6 10.0 -- ND ND ND ND ND ug/L 03/16/20 7.6 10.0 -- ND ND ND ND ND ug/L 09/24/20 7.6 10.0 -- ND ND ND ND ND ug/L 03/16/21 7.6 10.0 -- ND ND ND ND ND ug/L 09/20/21 7.6 10.0 -- ND ND ND ND ND ug/L 03/14/22 7.6 10.0 -- ND ND ND ND ND ug/L 09/19/22 7.6 10.0 -- ND ND ND ND ND ug/L 03/30/23 6.4 20.0 -- ND ND ND ND ND Barium ug/L 06/21/01 -- -- 100 ND ND ND ND -- NC 2L = 700 ug/L ug/L 04/24/02 -- -- 100 278 ND 306 ND -- EPA MCL = 2000 ug/L ug/L 10/01/02 -- -- 100 ND ND ND ND -- ug/L 04/10/03 -- -- 100 ND ND ND ND -- ug/L 10/20/03 -- -- 100 ND ND ND ND -- ug/L 03/24/04 -- -- 100 ND ND ND ND -- ug/L 10/27/04 -- -- 100 ND ND ND ND -- ug/L 05/25/05 -- -- 100 ND ND ND ND -- ug/L 10/05/05 -- -- 100 ND ND ND ND -- ug/L 04/25/06 -- -- 100 ND ND ND ND -- ug/L 10/05/06 -- -- 100 ND ND ND ND ND ug/L 03/21 /07 -- -- 100 19.5 J 25.0 J 19.7 J 20.0 J ND ug/L 10/02/07 -- -- 100 12.0 J 24.7 J 15.6 J 28.2 J ND ug/L 04/01/08 -- -- 100 49.5 J 63.1 J 27.6 J 153 ND ug/L 10/29/08 -- -- 100 5.81 J 150 26.1 J 68.7 J ND ug/L 03/24/09 4.2 10.0 100 15.8 J 61.2 J 25.9 J 19.8 J ND ug/L 09/22/09 1.0 10.0 100 5.04 J 75.9 J 26.0 J 14.9 J ND ug/L 03/24/10 1.0 10.0 100 2.75 B 33.7 J 14.3 J 12.1 J 1.54 J ug/L 09/22/10 1.0 10.0 100 26.1 J 23.0 J 9.25 J 12.5 J ND ug/L 03/16/11 1.0 10.0 100 59.1 J 32.5 J 18.0 J 12.6 J ND ug/L 09/21/11 1.0 10.0 100 2.53 J -- 13.7 J 12.2 J ND ug/L 03/21/12 1.0 10.0 100 1.99 J 46.7 J 16.8 J 11.9 J ND ug/L 09/20/12 1.0 10.0 100 2.07 J 72.8 J 13.7 J 12.4 J ND ug/L 03/20/13 1.0 10.0 100 1.42 B 48.2 J 12.8 J 20.7 J 1.34 J ug/L 09/18/13 1.0 10.0 100 429 59.6 J 16.7 J 24.2 J 1.08 J ug/L 03/27/14 1.0 10.0 100 1.87 J 107 11.5 J 13.6 J ND ug/L 09/18/14 1.0 10.0 100 6.05 B 78.8 J 10.7 J 14.4 J 1.96 J ug/L 03/18/15 1.0 10.0 100 8.07 J 155 22.4 J 14.5 J ND ug/L 09/23/15 1.0 10.0 100 4.41 B 113 16.7 B 13.9 B 4.08 J ug/L 03/15/16 1.0 10.0 100 4.45 J 112 15.4 J 13.1 J ND ug/L 09/21/16 1.0 10.0 100 2.53 J 168 19.6 J 29.6 J ND ug/L 03/23/17 1.0 10.0 100 Dry 151 19.9 J 14.0 J ND ug/L 09/20/17 1.0 10.0 100 4.75 J 144 19.9 J 15.7 J ND ug/L 03/21/18 1.0 10.0 100 3.40 J 100 16.3 J 13.8 J ND ug/L 09/25/18 1.1 10.0 -- 2.75 J 86.4 15.5 12.6 ND ug/L 03/25/19 1.1 10.0 -- 2.04 J 124 21.7 13.1 ND ug/L 09/19/19 1.1 10.0 -- 2.47 B 121 30.1 14.2 B 3.97 J ug/L 03/16/20 1.1 10.0 -- 1.95 J 102 29.2 15.3 ND ug/L 09/24/20 1.1 10.0 -- 2.77 J 106 35.1 15.9 ND ug/L 03/16/21 1.1 10.0 -- 2.72 J 106 40.1 17.8 ND ug/L 09/20/21 1.1 10.0 -- 2.71 J 85.6 38.2 17.0 ND ug/L 03/14/22 1.1 10.0 -- 2.90 J 73.4 35.6 18.5 ND ug/L 09/19/22 1.1 10.0 -- 4.02 J 65.4 23.5 19.7 ND ug/L 03/30/23 4.4 10.0 -- ND 68.4 20.6 17.6 ND 1 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Beryllium ug/L 03/24/09 0.08 1.00 1 0.32 J 1.19 0.46 J 0.09 J ND NC 2L = 4 ug/L ug/L 09/22/09 0.10 1.00 1 0.190 B 1.02 0.682 J 0.117 B 0.113 EPA MCL = 4 ug/L ug/L 03/24/10 0.10 1.00 1 0.178 J 1.46 0.130 J ND ND ug/L 09/22/10 0.10 1.00 1 ND 0.882 J 0.120 J ND ND ug/L 03/16/11 0.10 1.00 1 0.753 J 0.941 J 0.117 J ND ND ug/L 09/21/11 0.10 1.00 1 ND -- ND ND ND ug/L 03/21/12 0.10 1.00 1 ND 0.869 J 0.118 J ND ND ug/L 09/20/12 0.10 1.00 1 ND 1.04 ND ND ND ug/L 03/20/13 0.10 1.00 1 ND 0.785 J 0.102 J ND ND ug/L 09/18/13 0.10 1.00 1 5.56 1.12 0.193 J ND ND ug/L 03/27/14 0.10 1.00 1 0.139 J 1.55 0.132 J ND ND ug/L 09/18/14 0.10 1.00 1 0.112 J 0.968 J ND ND ND ug/L 03/18/15 0.10 1.00 1 0.143 J 1.37 0.135 J ND ND ug/L 09/23/15 0.10 1.00 1 ND 0.451 J ND ND ND ug/L 03/15/16 0.10 1.00 1 0.115 J 0.951 J ND ND ND ug/L 09/21/16 0.10 1.00 1 ND 0.676 J ND ND ND ug/L 03/23/17 0.10 1.00 1 Dry 0.458 J ND ND ND ug/L 09/20/17 0.10 1.00 1 ND 0.644 J ND ND ND ug/L 03/21/18 0.13 1.00 1 0.211 J 0.426 J ND ND ND ug/L 09/25/18 0.16 1.00 -- 0.224 J 0.480 J 0.221 J ND ND ug/L 03/25/19 0.16 1.00 -- 0.220 J 0.462 J ND ND ND ug/L 09/19/19 0.16 1.00 -- ND 0.501 J ND ND ND ug/L 03/16/20 0.16 1.00 -- ND 0.257 J ND ND ND ug/L 09/24/20 0.16 1.00 -- ND 0.563 J ND ND ND ug/L 03/16/21 0.16 1.00 -- ND 0.511 J ND ND ND ug/L 09/20/21 0.16 1.00 -- ND 0.627 J ND ND ND ug/L 03/14/22 0.16 1.00 -- ND 0.411 J ND ND ND ug/L 09/19/22 0.16 1.00 -- ND 0.254 J ND ND ND ug/L 03/30/23 0.30 4.00 -- 1.08 B 1.13 B 1.02 B 0.840 B 0.640 J Cadmium ug/L 06/21/01 -- -- 1 ND ND ND ND -- NC 2L = 2 ug/L ug/L 04/24/02 -- -- 1 ND ND ND ND -- EPA MCL = 5 ug/L ug/L 10/01/02 -- -- 1 ND ND ND ND -- ug/L 04/10/03 -- -- 1 ND ND ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 0.750 J 1.31 J 2.31 J 2.15 J ND ug/L 10/02/07 -- -- 1 ND ND 2.90 J ND ND ug/L 04/01/08 -- -- 1 ND ND ND 0.53 J ND ug/L 10/29/08 -- -- 1 ND 0.35 J ND ND ND ug/L 03/24/09 0.09 1.00 1 ND 0.27 J 0.14 J ND ND ug/L 09/22/09 0.36 1.00 1 ND 1.15 0.461 J 1.00 ND ug/L 03/24/10 0.36 1.00 1 ND ND ND ND ND ug/L 09/22/10 0.36 1.00 1 ND ND ND ND ND ug/L 03/16/11 0.36 1.00 1 ND ND ND ND ND ug/L 09/21/11 0.36 1.00 1 ND -- 0.402 J ND ND ug/L 03/21/12 0.36 1.00 1 ND ND 0.774 J ND ND ug/L 09/20/12 0.36 1.00 1 ND ND ND ND ND ug/L 03/20/13 0.36 1.00 1 ND ND ND ND ND ug/L 09/18/13 0.36 1.00 1 ND ND ND ND ND ug/L 03/27/14 0.36 1.00 1 ND 1.05 ND ND ND ug/L 09/18/14 0.36 1.00 1 ND ND ND ND ND ug/L 03/18/15 0.36 1.00 1 ND ND ND ND ND ug/L 09/23/15 0.36 1.00 1 ND ND ND ND ND ug/L 03/15/16 0.36 1.00 1 ND ND ND ND ND ug/L 09/21/16 0.36 1.00 1 ND ND ND ND ND ug/L 03/23/17 0.36 1.00 1 Dry 0.573 B ND ND 0.508 J ug/L 09/20/17 0.36 1.00 1 ND ND ND ND ND ug/L 03/21/18 0.36 1.00 1 ND ND ND ND ND ug/L 09/25/18 0.36 1.00 -- ND ND ND ND ND ug/L 03/25/19 0.36 1.00 -- ND ND ND ND ND ug/L 09/19/19 0.36 1.00 -- ND ND ND ND ND ug/L 03/16/20 0.36 1.00 -- ND ND ND ND ND ug/L 09/24/20 0.36 1.00 -- ND ND ND ND ND ug/L 03/16/21 0.36 1.00 -- ND ND ND ND ND ug/L 09/20/21 0.36 1.00 -- ND ND ND ND ND ug/L 03/14/22 0.36 1.00 -- ND ND ND ND ND ug/L 09/19/22 0.36 1.00 -- ND ND ND ND ND ug/L 03/30/23 0.44 5.00 -- ND ND ND ND ND Chromium ug/L 06/21/01 -- -- 10 ND ND ND 23.8 -- NC 2L = 10 ug/L ug/L 04/24/02 -- -- 10 ND ND ND ND -- EPA MCL = 100 ug/L ug/L 10/01/02 -- -- 10 ND ND ND ND -- ug/L 04/10/03 -- -- 10 ND ND ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND 13.5 -- ug/L 03/24/04 -- -- 10 ND ND ND 12.8 -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/05/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/05/06 -- -- 10 ND ND ND ND ND ug/L 03/21 /07 -- -- 10 3.41 J 3.26 J 3.55 J 2.97 J ND ug/L 10/02/07 -- -- 10 2.28 J 1.17 J 2.08 J 3.80 J ND ug/L 04/01/08 -- -- 10 5.80 J 3.56 J 3.07 J 103 ND ug/L 10/29/08 -- -- 10 ND ND 1.77 J 19.0 ND ug/L 03/24/09 0.7 10.0 10 1.0 J ND 1.2 J 3.0 J ND ug/L 09/22/09 1.0 10.0 10 ND ND ND ND ND ug/L 03/24/10 1.0 10.0 10 ND ND ND ND ND ug/L 09/22/10 1.0 10.0 10 1.18 J ND ND ND ND ug/L 03/16/11 1.0 10.0 10 5.18 J ND ND ND ND ug/L 09/21/11 1.0 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.0 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.0 10.0 10 ND 1.80 J ND ND ND ug/L 03/20/13 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/13 1.4 10.0 10 12.6 ND ND 1.57 J ND ug/L 03/27/14 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 10 ND ND ND ND ND ug/L 09/23/15 1.4 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.4 10.0 10 ND ND ND ND ND ug/L 09/21/16 1.4 10.0 10 ND ND ND ND ND ug/L 03/23/17 1.4 10.0 10 Dry ND ND 4.79 J ND ug/L 09/20/17 1.4 10.0 10 ND ND ND ND ND ug/L 03/21/18 1.4 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.4 10.0 -- ND ND ND ND ND ug/L 09/19/19 1.4 10.0 -- ND ND ND ND ND ug/L 03/16/20 1.4 10.0 -- ND ND ND ND ND ug/L 09/24/20 1.4 10.0 -- ND 3.01 J 2.42 J ND ND ug/L 03/16/21 1.4 10.0 -- ND 2.92 J ND ND ND ug/L 09/20/21 1.4 10.0 -- 1.57 J 2.86 J 2.03 J ND ND ug/L 03/14/22 1.4 10.0 -- ND 6.23 J 1.58 J ND ND ug/L 09/19/22 1.4 10.0 -- ND 4.03 J 1.72 J ND ND ug/L 03/30/23 1.1 10.0 -- ND ND ND ND ND 2 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Cobalt ug/L 03/24/09 0.6 10.0 10 0.8 J ND 1.10 J ND ND NC 2L = 1 ug/L ug/L 09/22/09 1.1 10.0 10 ND ND 1.28 J ND ND EPA MCL = No Standard ug/L 03/24/10 1.1 10.0 10 ND 4.30 J ND ND ND ug/L 09/22/10 1.1 10.0 10 2.10 J 2.89 J 1.87 J ND ND ug/L 03/16/11 1.1 10.0 10 3.28 J 2.05 J ND ND ND ug/L 09/21/11 1.1 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.1 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.1 10.0 10 ND 1.37 J 1.55 J 1.11 J ND ug/L 03/20/13 1.1 10.0 10 ND 1.54 J ND 2.35 J ND ug/L 09/18/13 1.1 10.0 10 15.3 1.56 J ND ND ND ug/L 03/27/14 1.1 10.0 10 ND 6.98 J ND ND ND ug/L 09/18/14 1.1 10.0 10 ND 7.44 J ND ND ND ug/L 03/18/15 1.1 10.0 10 ND 1.29 J ND ND ND ug/L 09/23/15 1.1 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.1 10.0 10 ND 2.74 J ND ND ND ug/L 09/21/16 1.1 10.0 10 ND 4.39 J ND ND ND ug/L 03/23/17 1.1 10.0 10 Dry ND ND ND ND ug/L 09/20/17 1.1 10.0 10 ND 2.27 J ND 1.28 J ND ug/L 03/21/18 1.1 10.0 10 ND 2.93 J ND 1.32 J ND ug/L 09/25/18 1.4 10.0 -- ND 5.09 J ND ND ND ug/L 03/25/19 1.4 10.0 -- ND 3.18 J ND 1.93 J ND ug/L 09/19/19 1.4 10.0 -- ND 13.0 ND ND ND ug/L 03/16/20 1.4 10.0 -- ND ND ND 3.20 J ND ug/L 09/24/20 1.4 10.0 -- ND 2.17 J ND 2.01 J ND ug/L 03/16/21 1.4 10.0 -- ND 2.92 J ND 2.90 J ND ug/L 09/20/21 1.4 10.0 -- ND ND ND 2.58 J ND ug/L 03/14/22 1.4 10.0 -- ND 5.58 J ND 3.43 J ND ug/L 09/19/22 1.4 10.0 -- ND 2.36 J ND 2.49 J ND ug/L 03/30/23 1.4 10.0 -- ND 2.77 J ND 4.34 J ND Copper ug/L 03/24/09 0.81 10.0 10 3.42 J ND ND ND ND NC 2L =1000 ug/L ug/L 09/22/09 1.6 10.0 10 ND ND ND 1.82 J ND EPA MCL = 1300 ug/L ug/L 03/24/10 1.6 10.0 10 ND 2.76 J ND ND ND ug/L 09/22/10 1.6 10.0 10 3.49 J ND ND ND ND ug/L 03/16/11 1.6 10.0 10 15.9 2.55 J 3.09 J 4.85 J ND ug/L 09/21/11 1.6 10.0 10 ND -- ND 1.80 J ND ug/L 03/21/12 1.6 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.6 10.0 10 ND ND ND ND ND ug/L 03/20/13 1.6 10.0 10 ND ND 1.97 J ND ND ug/L 09/18/13 1.6 10.0 10 31.1 ND ND ND ND ug/L 03/27/14 1.6 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.6 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.6 10.0 10 ND 4.30 B 1.95 B ND 1.74 J ug/L 09/23/15 1.6 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.6 10.0 10 ND ND ND ND 2.01 J ug/L 09/21/16 1.6 10.0 10 3.22 B 2.80 B 5.34 B 2.15 B 3.37 J ug/L 03/23/17 1.6 10.0 10 Dry ND ND ND 1.97 J ug/L 09/20/17 1.6 10.0 10 3.20 B 4.13 B 2.70 B 2.55 B 2.35 J ug/L 03/21/18 1.6 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.6 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.6 10.0 -- ND 4.17 J ND ND ND ug/L 09/19/19 1.6 10.0 -- ND ND ND ND 5.73 J ug/L 03/16/20 1.6 10.0 -- 1.78 B 2.83 B 1.78 B ND 2.00 J ug/L 09/24/20 1.6 10.0 -- 2.33 B ND ND ND 2.42 J ug/L 03/16/21 1.6 10.0 -- ND ND ND ND ND ug/L 09/20/21 1.6 10.0 -- ND ND ND ND ND ug/L 03/14/22 1.6 10.0 -- ND ND ND ND ND ug/L 09/19/22 1.6 10.0 -- 2.24 B ND ND ND 1.85 J ug/L 03/30/23 3.2 20.0 -- 3.86 J ND ND ND ND Lead ug/L 06/21 /01 -- -- 10 14.2 ND ND 10.4 -- NC 2L = 15 ug/L ug/L 04/24/02 -- -- 10 ND ND ND ND -- EPA MCL = 15 ug/L ug/L 10/01/02 -- -- 10 ND ND ND ND -- ug/L 04/10/03 -- -- 10 ND ND ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 10.3 ND ND ND -- ug/L 10/05/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/05/06 -- -- 10 ND ND ND ND ND ug/L 03/21 /07 -- -- 10 3.32 J 3.57 J 2.12 J ND ND ug/L 10/02/07 -- -- 10 ND ND ND ND ND ug/L 04/01 /08 -- -- 10 13.1 9.16 J ND 25.1 ND ug/L 10/29/08 -- -- 10 6.51 J ND 8.35 J 9.00 J ND ug/L 03/24/09 1.6 10.0 10 4.4 J 3.7 J 3.1 J 3.9 J ND ug/L 09/22/09 1.9 10.0 10 2.40 J ND 3.84 J ND ND ug/L 03/24/10 1.9 10.0 10 ND ND 2.18 J ND ND ug/L 09/22/10 1.9 10.0 10 2.56 J ND ND ND ND ug/L 03/16/11 1.9 10.0 10 12.8 2.55 J ND 2.29 J ND ug/L 09/21/11 1.9 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND 2.70 J ug/L 03/20/13 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/13 2.1 10.0 10 37.6 ND ND ND ND ug/L 03/27/14 2.1 10.0 10 ND ND ND ND ND ug/L 09/18/14 2.1 10.0 10 ND ND ND ND ND ug/L 03/18/15 2.1 10.0 10 ND ND ND ND ND ug/L 09/23/15 2.1 10.0 10 ND ND ND ND ND ug/L 03/15/16 2.1 10.0 10 ND ND ND ND ND ug/L 09/21/16 2.1 10.0 10 ND ND ND ND ND ug/L 03/23/17 2.1 10.0 10 Dry ND ND ND ND ug/L 09/20/17 3.1 10.0 10 ND ND ND ND ND ug/L 03/21/18 3.1 10.0 10 ND 6.99 J ND ND ND ug/L 09/25/18 3.1 10.0 -- ND ND ND ND 8.83 ug/L 03/25/19 3.1 10.0 -- ND ND ND ND ND ug/L 09/19/19 3.1 10.0 -- ND ND ND ND ND ug/L 03/16/20 3.1 10.0 -- ND ND ND ND ND ug/L 09/24/20 3.1 10.0 -- ND ND ND ND ND ug/L 03/16/21 3.1 10.0 -- ND ND ND ND ND ug/L 09/20/21 3.1 10.0 -- ND ND ND ND ND ug/L 03/14/22 3.1 10.0 -- ND ND ND ND ND ug/L 09/19/22 3.1 10.0 -- ND ND ND ND ND ug/L 03/30/23 6.6 10.0 -- ND ND ND ND ND 3 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Mercury ug/L 06/21/01 -- -- 0.2 ND ND ND ND -- NC 2L = 1 ug/L ug/L 04/24/02 -- -- 0.2 ND ND ND ND -- EPA MCL = 2 ug/L ug/L 10/01/02 -- -- 0.2 ND ND ND ND -- ug/L 04/10/03 -- -- 0.2 ND ND ND ND -- ug/L 10/20/03 -- -- 0.2 ND ND ND ND -- ug/L 03/24/04 -- -- 0.2 ND ND ND ND -- ug/L 10/27/04 -- -- 0.2 ND ND ND ND -- ug/L 05/25/05 -- -- 0.2 ND ND ND ND -- ug/L 10/05/05 -- -- 0.2 ND ND ND ND -- ug/L 04/25/06 -- -- 0.2 ND ND ND ND -- ug/L 10/05/06 -- -- 0.2 ND ND ND ND ND ug/L 03/21/07 -- -- 0.2 ND ND 0.093 J ND ND ug/L 10/02/07 -- -- 0.2 ND ND 0.136 J ND ND ug/L 04/01/08 -- -- 0.2 ND ND 0.096 J ND ND ug/L 10/29/08 -- -- 0.2 ND ND 0.198 J ND ND ug/L 03/24/09 0.11 0.20 0.2 ND ND 0.54 ND ND ug/L 09/22/09 0.054 0.200 0.2 ND ND 0.172 J ND ND ug/L 03/24/10 0.054 0.200 0.2 ND 0.0586 J 0.144 J ND ND ug/L 09/22/10 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/16/11 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/21/11 0.17 0.200 0.2 ND -- ND ND ND ug/L 03/21/12 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/20/12 0.17 0.200 0.2 ND ND 0.253 ND ND ug/L 03/20/13 0.17 0.200 0.2 ND ND 0.199 J ND ND ug/L 09/18/13 0.17 0.200 0.2 ND ND ND 0.246 ND ug/L 03/27/14 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/18/14 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/18/15 0.17 0.200 0.2 ND ND 0.227 ND ND ug/L 09/23/15 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/15/16 0.17 0.200 0.2 ND ND ND 0.275 ND ug/L 09/21/16 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/23/17 0.17 0.200 0.2 Dry ND ND ND ND ug/L 09/20/17 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/21/18 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/25/18 0.15 0.200 -- ND ND ND ND ND ug/L 03/25/19 0.15 0.200 -- ND ND ND ND ND ug/L 09/19/19 0.15 0.200 -- ND ND ND ND ND ug/L 03/16/20 0.15 0.200 -- ND ND ND ND ND ug/L 09/24/20 0.15 0.200 -- ND ND ND ND ND ug/L 03/16/21 0.15 0.200 -- ND ND ND ND ND ug/L 09/20/21 0.15 0.200 -- ND ND ND ND ND ug/L 03/14/22 0.15 0.200 -- ND ND ND ND ND ug/L 09/19/22 0.15 0.200 -- ND ND ND ND ND ug/L 03/30/23 0.08 0.200 -- ND ND ND ND ND Nickel ug/L 03/24/09 0.6 10.0 50 0.7 J ND 1.1 J 1.0 J ND NC 2L = 100 ug/L ug/L 09/22/09 1.8 50.0 50 ND ND ND 1.88 J ND EPA MCL = No Standard ug/L 03/24/10 1.8 10.0 50 ND ND ND ND ND ug/L 09/22/10 1.8 10.0 50 ND ND ND ND ND ug/L 03/16/11 1.8 10.0 50 3.91 J ND ND ND ND ug/L 09/21/11 1.8 10.0 50 ND -- ND ND ND ug/L 03/21/12 1.8 10.0 50 ND ND ND ND ND ug/L 09/20/12 1.8 10.0 50 ND 3.07 J ND ND ND ug/L 03/20/13 1.8 10.0 50 ND ND ND ND ND ug/L 09/18/13 1.8 10.0 50 7.11 J ND ND ND ND ug/L 03/27/14 1.8 10.0 50 ND ND ND ND ND ug/L 09/18/14 1.8 10.0 50 ND ND ND ND ND ug/L 03/18/15 1.8 10.0 50 ND 14.3 J ND ND ND ug/L 09/23/15 1.8 10.0 50 ND 4.08 B ND ND 2.22 J ug/L 03/15/16 1.8 10.0 50 ND ND ND ND ND ug/L 09/21/16 1.8 10.0 50 ND ND ND 2.29 J ND ug/L 03/23/17 1.8 10.0 50 Dry 5.08 B 2.26 B 2.24 B 2.63 J ug/L 09/20/17 1.8 10.0 50 ND 3.23 J ND ND ND ug/L 03/21/18 1.8 10.0 50 ND ND ND ND ND ug/L 09/25/18 2.2 10.0 -- ND ND ND ND 10.1 ug/L 03/25/19 2.2 10.0 -- ND ND ND ND ND ug/L 09/19/19 2.2 10.0 -- ND ND ND ND ND ug/L 03/16/20 2.2 10.0 -- ND ND ND ND ND ug/L 09/24/20 2.2 10.0 -- 5.33 J ND ND ND ND ug/L 03/16/21 2.2 10.0 -- ND ND ND ND ND ug/L 09/20/21 2.2 10.0 -- ND ND 2.30 J ND ND ug/L 03/14/22 2.2 10.0 -- ND ND ND ND ND ug/L 09/19/22 2.2 10.0 -- ND ND ND ND ND ug/L 03/30/23 3.3 40.0 -- ND ND ND ND ND Selenium ug/L 06/21/01 -- -- 10 ND ND ND ND -- NC 2L = 20 ug/L ug/L 04/24/02 -- -- 10 ND ND ND ND -- EPA MCL = 50 ug/L ug/L 10/01/02 -- -- 10 ND ND ND ND -- ug/L 04/10/03 -- -- 10 ND ND ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/05/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/05/06 -- -- 10 ND ND ND ND ND ug/L 03/21/07 -- -- 10 ND ND ND 10.2 J ND ug/L 10/02/07 -- -- 10 ND ND ND ND ND ug/L 04/01/08 -- -- 10 ND ND ND 19.2 ND ug/L 10/29/08 -- -- 10 ND ND ND ND ND ug/L 03/24/09 3.4 10.0 10 ND ND ND ND ND ug/L 09/22/09 2.7 10.0 10 ND ND ND ND ND ug/L 03/24/10 0.83 1.00 10 ND ND ND ND ND ug/L 09/22/10 2.7 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.7 10.0 10 ND ND ND ND 3.32 J ug/L 09/21/11 0.83 1.00 10 ND -- ND ND ND ug/L 03/21/12 2.7 10.0 10 ND ND ND ND ND ug/L 09/20/12 2.7 10.0 10 ND ND ND ND ND ug/L 03/20/13 4.5 10.0 10 ND ND ND ND ND ug/L 09/18/13 5.0 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.0 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.0 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.0 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.0 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.0 10.0 10 ND ND ND ND ND ug/L 09/21/16 5.0 10.0 10 ND ND ND ND ND ug/L 03/23/17 5.0 10.0 10 Dry ND ND ND 14.1 J ug/L 09/20/17 5.0 10.0 10 ND ND ND ND ND ug/L 03/21/18 5.0 10.0 10 ND ND ND ND ND ug/L 09/25/18 6.2 10.0 -- ND ND ND ND ND ug/L 03/25/19 6.2 10.0 -- ND ND ND ND ND ug/L 09/19/19 6.2 10.0 -- ND ND ND ND ND ug/L 09/19/19 1.82 2.0 -- ND ND ND ND ND ug/L 03/16/20 6.2 10.0 -- ND ND ND ND ND ug/L 09/24/20 6.2 10.0 -- ND ND ND ND ND ug/L 03/16/21 6.2 10.0 -- ND ND ND ND ND ug/L 09/20/21 6.2 10.0 -- ND ND ND ND ND ug/L 03/14/22 6.2 10.0 -- ND ND ND ND ND ug/L 09/19/22 6.2 10.0 -- ND ND ND ND ND ug/L 03/30/23 10.0 20.0 -- ND ND ND ND ND 4 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Silver ug/L 06/21/01 -- -- 10 ND ND ND ND -- NC 2L = 20 ug/L ug/L 04/24/02 -- -- 10 ND ND ND ND -- EPA MCL = 100 ug/L ug/L 10/01/02 -- -- 10 ND ND ND ND -- ug/L 04/10/03 -- -- 10 ND ND ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/05/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/05/06 -- -- 10 ND ND ND ND ND ug/L 03/21/07 -- -- 10 3.49 J 3.41 J 3.04 J 2.96 J ND ug/L 10/02/07 -- -- 10 ND ND ND ND ND ug/L 04/01/08 -- -- 10 4.12 J 4.48 J 4.07 J 3.65 J ND ug/L 10/29/08 -- -- 10 1.57 B 1.80 B 1.40 B 1.52 B -- ug/L 03/24/09 1.0 10.0 10 ND 1.2 J ND ND ND ug/L 09/22/09 1.9 10.0 10 ND ND ND ND ND ug/L 03/24/10 1.9 10.0 10 ND ND ND ND ND ug/L 09/22/10 1.9 10.0 10 ND ND ND ND ND ug/L 03/16/11 1.9 10.0 10 ND ND ND ND ND ug/L 09/21/11 1.9 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND ND ug/L 03/20/13 1.9 10.0 10 ND ND ND ND 2.11 J ug/L 09/18/13 1.9 10.0 10 ND ND ND ND ND ug/L 03/27/14 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.9 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.9 10.0 10 ND ND ND ND ND ug/L 09/23/15 1.9 10.0 10 ND ND ND ND 4.69 J ug/L 03/15/16 1.9 10.0 10 ND ND ND ND ND ug/L 09/21/16 1.9 10.0 10 ND ND ND ND ND ug/L 03/23/17 1.9 10.0 10 Dry 1.63 B 0.902 B ND 0.823 J ug/L 09/20/17 1.9 10.0 10 ND ND ND ND ND ug/L 03/21/18 1.9 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.9 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.9 10.0 -- ND ND ND ND ND ug/L 09/19/19 1.9 10.0 -- ND ND ND ND ND ug/L 03/16/20 1.9 10.0 -- ND ND ND ND ND ug/L 09/24/20 1.9 10.0 -- 2.02 J ND ND ND ND ug/L 03/16/21 1.9 10.0 -- ND 2.21 J ND ND ND ug/L 09/20/21 1.9 10.0 -- ND ND ND ND ND ug/L 03/14/22 1.9 10.0 -- ND ND ND ND ND ug/L 09/19/22 1.9 10.0 -- ND ND ND ND ND ug/L 03/30/23 1.5 10.0 -- ND ND ND ND ND Thallium ug/L 03/24/09 0.036 1.00 5.5 ND ND 0.061 B ND 0.092 J NC 2L= 2 ug/L ug/L 09/22/09 0.11 1.00 5.5 ND ND ND ND ND EPA MCL 2 ug/L ug/L 03/24/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/22/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/16/11 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/21/11 0.11 1.00 5.5 ND -- ND ND ND ug/L 03/21/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/20/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/20/13 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/13 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/27/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/18/15 0.11 1.00 5.5 0.251 J 0.202 J ND ND ND ug/L 09/23/15 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/15/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/21/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/21/17 0.11 1.00 5.5 Dry 0.221 J 0.273 J 0.274 J ND ug/L 09/20/17 0.11 1.00 5.5 0.189 J 0.425 J 0.424 J 0.319 J ND ug/L 03/21/18 0.11 5.00 5.5 ND ND ND ND ND ug/L 09/25/18 0.55 5.00 -- ND ND ND ND ND ug/L 03/25/19 0.22 2.00 -- ND ND ND ND ND ug/L 09/19/19 0.22 2.00 -- ND ND ND ND ND ug/L 03/16/20 0.22 2.00 -- ND 0.242 J 0.239 J ND ND ug/L 09/24/20 0.22 2.00 -- ND ND ND ND ND ug/L 03/16/21 0.22 2.00 -- ND ND ND ND ND ug/L 09/20/21 0.22 2.00 -- ND ND ND ND ND ug/L 03/14/22 0.22 2.00 -- ND ND ND ND ND ug/L 09/19/22 0.22 2.00 -- ND ND ND ND ND ug/L 03/30/23 0.26 1.00 -- ND ND ND ND ND Vanadium ug/L 03/24/09 0.7 10.0 25 4.9 J 1.0 J 6.5 J 3.3 J ND NC 2L= 7 ug/L ug/L 09/22/09 1.4 10.0 25 2.01 J ND 6.20 J 2.01 J ND EPA MCL = No Standard ug/L 03/24/10 1.4 10.0 25 ND 2.62 J 1.57 J ND ND ug/L 09/22/10 1.4 10.0 25 7.06 J ND ND 1.64 J ND ug/L 03/16/11 1.4 10.0 25 19.5 J 1.76 J 3.03 J ND ND ug/L 09/21/11 1.4 10.0 25 ND -- 2.32 J ND ND ug/L 03/21/12 1.4 10.0 25 ND 2.19 J 3.02 J 1.52 J ND ug/L 09/20/12 1.4 10.0 25 ND 2.85 J ND ND ND ug/L 03/20/13 1.4 10.0 25 ND 2.34 J ND 1.91 J ND ug/L 09/18/13 1.4 10.0 25 75.0 1.86 J 1.72 J 3.22 J ND ug/L 03/27/14 1.4 10.0 25 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 25 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 25 1.62 J 2.39 J 1.87 J ND ND ug/L 09/23/15 1.4 10.0 25 2.11 J ND 1.83 J 1.53 J ND ug/L 03/15/16 1.4 10.0 25 ND ND ND ND ND ug/L 09/21/16 1.4 10.0 25 ND ND ND ND ND ug/L 03/21/17 1.4 10.0 25 Dry 2.15 B ND ND 0.589 J ug/L 09/20/17 1.4 10.0 25 ND 1.65 J ND ND ND ug/L 03/21/18 1.4 10.0 25 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.4 10.0 -- ND ND ND ND ND ug/L 09/19/19 1.4 10.0 -- ND ND ND ND ND ug/L 03/16/20 1.4 10.0 -- ND ND ND ND ND ug/L 09/24/20 1.4 10.0 -- ND ND ND ND ND ug/L 03/16/21 1.4 10.0 -- ND ND ND ND ND ug/L 09/20/21 1.4 10.0 -- ND ND ND ND ND ug/L 03/14/22 1.4 10.0 -- ND ND ND ND ND ug/L 09/19/22 1.4 10.0 -- ND ND ND ND ND ug/L 03/30/23 1.0 10.0 -- 1.38 J 1.70 J 1.74 J ND ND 5 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Zinc ug/L 03/24/09 3.4 10.0 10 8.0 B 9.0 B 17.9 7.2 B 3.4 NC 2L = 1000 ug/L ug/L 09/22/09 3.8 10.0 10 ND 32.4 17.3 12.0 ND EPA MCL = 5000 ug/L* ug/L 03/24/10 3.8 10.0 10 13.2 20.0 21.5 12.2 ND ug/L 09/22/10 3.8 10.0 10 14.8 7.45 J 6.78 J 10.5 ND ug/L 03/16/11 3.8 10.0 10 43.2 4.05 J 12.5 26.0 ND ug/L 09/21/11 3.8 10.0 10 ND -- 12.0 12.5 ND ug/L 03/21/12 3.8 10.0 10 ND 92.0 6.44 J ND ND ug/L 09/20/12 3.8 10.0 10 ND 22.2 ND ND ND ug/L 03/20/13 3.8 10.0 10 9.34 J 11.2 11.9 8.08 J ND ug/L 09/18/13 3.8 10.0 10 152 15.6 9.51 J 7.43 J ND ug/L 03/27/14 3.8 10.0 10 ND 13.7 ND 7.05 J ND ug/L 09/18/14 3.8 10.0 10 4.00 J 15.5 ND 5.45 J ND ug/L 03/18/15 3.8 10.0 10 ND 265 9.40 J 5.27 J ND ug/L 09/23/15 3.8 10.0 10 ND 3.93 J ND ND ND ug/L 03/15/16 3.8 10.0 10 ND 8.92 J ND ND ND ug/L 09/21/16 3.8 10.0 10 ND ND ND ND ND ug/L 03/21/17 3.8 10.0 10 Dry 16.6 ND ND ND ug/L 09/20/17 3.8 10.0 10 ND 56.0 ND ND ND ug/L 03/21/18 3.8 10.0 10 ND 36.4 ND ND ND ug/L 09/25/18 4.4 10.0 -- ND 10.7 B ND ND 64.2 ug/L 03/25/19 4.4 10.0 -- ND ND ND ND ND ug/L 09/19/19 4.4 10.0 -- ND 5.76 J 5.08 J ND ND ug/L 03/16/20 4.4 10.0 -- ND ND ND ND ND ug/L 09/24/20 4.4 10.0 -- ND 27.3 ND ND ND ug/L 03/16/21 4.4 10.0 -- ND 32.3 ND ND ND ug/L 09/20/21 4.4 10.0 -- ND 27.0 N D ND ND ug/L 03/14/22 4.4 10.0 -- ND 30.8 ND ND ND ug/L 09/19/22 4.4 10.0 -- ND 22.1 ND ND ND ug/L 03/30/23 8.7 20.0 -- ND ND ND ND ND Iron ug/L 03/24/09 31.0 50.0 300 2750 1400 4810 1670 ND NC 2L = 300 ug/L ug/L 09/22/09 22.0 50.0 300 684 1390 4450 735 ND EPA MCL = 300 ug/L ug/L 03/24/10 22.0 50.0 300 151 J 2050 830 564 27.6 ug/L 09/22/10 22.0 50.0 300 4690 630 841 658 ND ug/L 03/16/11 22.0 50.0 300 14200 1770 1600 462 ND ug/L 09/21/11 22.0 50.0 300 153 J -- 269 J 457 ND ug/L 03/21/12 22.0 50.0 300 81.3 B 4460 1260 245 J 44.0 J ug/L 09/20/12 22.0 50.0 300 36.2 J 4040 133 J 91.7 J ND ug/L 03/20/13 22.0 50.0 300 22.2 J 4530 594 2040 ND ug/L 09/18/13 22.0 50.0 300 52700 5170 1270 1770 ND ug/L 03/27/14 22.0 50.0 300 41.0 J 6590 126 J 35.9 J ND ug/L 09/18/14 22.0 50.0 300 425 6200 37.0 J 454 ND ug/L 03/18/15 22.0 50.0 300 659 5720 880 214 J ND ug/L 09/23/15 22.0 50.0 300 302 979 632 323 ND ug/L 03/15/16 22.0 50.0 300 192 J 2860 82.5 J 157 J ND ug/L 09/21/16 22.0 50.0 300 ND 6720 38.0 J 299 J ND ug/L 03/21/17 22.0 50.0 300 Dry 1250 51.1 B 676 29.4 J ug/L 09/20/17 22.0 50.0 300 334 4730 59.3 J 778 ND ug/L 03/21/18 22.0 50.0 300 ND 3880 150 J 895 ND ug/L 09/25/18 22.0 50.0 -- 30.4 J 9610 63.8 705 ND ug/L 03/25/19 22.0 50.0 -- 39.2 J 6580 104 1360 ND ug/L 09/19/19 22.0 50.0 -- ND 17100 154 1160 26.9 J ug/L 03/16/20 22.0 50.0 -- ND 1530 98.1 2090 ND ug/L 09/24/20 22.0 50.0 -- 25.9 J 3360 90.6 1180 ND ug/L 03/16/21 22.0 50.0 -- ND 1890 101 1650 ND ug/L 09/20/21 22.0 50.0 -- 33.2 J 3680 70.3 1420 ND ug/L 03/14/22 22.0 50.0 -- 80.8 2070 80.0 1670 ND ug/L 09/19/22 22.0 50.0 -- 95.4 3120 53.2 1210 ND ug/L 03/30/23 20.0 100 -- ND 3610 48.6 J 1510 ND Manganese ug/L 03/24/09 1.1 10.0 50 60.9 165 155 59.1 ND NC 2L = 50 ug/L ug/L 09/22/09 1.1 10.0 50 18.1 J 186 163 34.9 J 1.99 EPA MCL = 50 ug/L ug/L 03/24/10 1.1 10.0 50 4.51 B 1780 142 111 2.13 ug/L 09/22/10 1.1 10.0 50 121 923 743 58.4 3.27 J ug/L 03/16/11 1.1 10.0 50 356 349 389 116 3.57 J ug/L 09/21/11 1.1 10.0 50 8.27 J -- 239 66.2 ND ug/L 03/21/12 1.1 10.0 50 3.45 B 164 295 88.3 2.02 J ug/L 09/20/12 1.1 10.0 50 1.43 J 256 163 74.2 ND ug/L 03/20/13 1.1 10.0 50 2.22 B 262 285 286 7.96 J ug/L 09/18/13 1.1 10.0 50 1530 390 214 84.9 1.75 J ug/L 03/27/14 1.1 10.0 50 2.05 B 1690 285 64.7 3.64 J ug/L 09/18/14 1.1 10.0 50 16.9 J 1950 176 64.7 ND ug/L 03/18/15 1.1 10.0 50 24.4 J 593 124 74.0 ND ug/L 09/23/15 1.1 10.0 50 8.10 J 823 128 85.6 ND ug/L 03/15/16 1.1 10.0 50 5.96 J 1250 123 96.0 ND ug/L 09/21/16 1.1 10.0 50 1.78 J 2330 148 103 ND ug/L 03/21/17 1.1 10.0 50 Dry 1520 172 138 ND ug/L 09/20/17 1.1 10.0 50 9.55 J 2420 194 172 ND ug/L 03/21/18 1.1 10.0 50 2.29 J 2300 199 199 ND ug/L 09/25/18 1.5 10.0 -- 1.58 J 4010 130 153 ND ug/L 03/25/19 1.5 10.0 -- 2.05 J 5200 199 285 ND ug/L 09/19/19 1.5 10.0 -- ND 5950 407 247 1.59 J ug/L 03/16/20 1.5 10.0 -- ND 2820 523 506 ND ug/L 09/24/20 1.5 10.0 -- 1.70 J 3710 674 431 ND ug/L 03/16/21 1.5 10.0 -- ND 4860 879 631 ND ug/L 09/20/21 1.5 10.0 -- ND 3770 1040 614 ND ug/L 03/14/22 1.5 10.0 -- 9.90 J 10000 1330 720 ND ug/L 09/19/22 1.5 10.0 -- 4.78 J 7560 885 650 ND ug/L 03/30/23 1.3 10.0 -- 6.43 J 7660 914 831 ND Acetone ug/L 03/24/09 1.5 5.0 100 ND ND 3.8 J ND ND NC 2L = 6000 ug/L ug/L 09/22/09 1.5 5.0 100 ND ND ND ND ND EPA MCL = No Standard ug/L 03/24/10 1.5 5.0 100 ND 19 J 13 J ND ND ug/L 09/22/10 1.5 5.0 100 ND 4.5 J 2.7 J ND ND ug/L 03/16/11 1.2 5.0 100 ND 92 J 17 J ND ND ug/L 09/21/11 1.2 5.0 100 ND -- 18 J ND ND ug/L 03/21/12 1.2 5.0 100 ND 7.5 J 30 J ND ND ug/L 09/20/12 1.2 5.0 100 ND 4.3 B 9.9 B ND 7.0 J ug/L 03/20/13 1.2 5.0 100 ND ND 6.8 J ND ND ug/L 09/18/13 1.2 5.0 100 ND ND ND ND ND ug/L 03/27/14 1.2 5.0 100 ND 18 B ND ND 19 J ug/L 09/18/14 1.2 5.0 100 ND 4.9 J ND ND ND ug/L 03/18/15 1.2 5.0 100 ND 160 ND ND ND ug/L 09/23/15 1.2 5.0 100 ND ND ND ND ND ug/L 03/15/16 1.2 5.0 100 ND ND ND ND ND ug/L 09/21/16 1.2 5.0 100 ND 11 J ND ND ND ug/L 03/21/17 1.2 5.0 100 Dry 11 J ND ND ND ug/L 09/20/17 1.2 20 100 ND 39 J ND ND ND ug/L 03/21/18 1.2 20 100 ND ND ND ND ND ug/L 09/25/18 10 20 -- ND ND ND ND ND ug/L 03/25/19 10 20 -- ND 11 J ND ND ND ug/L 09/19/19 10 20 -- ND ND ND ND ND ug/L 03/16/20 10 20 -- ND ND ND ND ND ug/L 09/24/20 10 20 -- ND N D ND ND 16 J ug/L 03/16/21 10 20 -- ND ND ND ND ND ug/L 09/20/21 10 20 -- ND ND ND ND ND ug/L 03/14/22 10 20 -- ND ND ND ND 10 J ug/L 09/19/22 10 20 -- ND ND ND ND ND ug/L 03/30/23 10 20 -- ND ND N D ND 10.0 J 6 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Benzene ug/L 06/21/01 5.0 5.0 1 ND ND ND ND -- NC 2L = 1 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND -- EPA MCL = 5 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND -- ug/L 04/10/03 5.0 5.0 1 ND ND ND ND -- ug/L 10/20/03 5.0 5.0 1 ND ND ND ND -- ug/L 03/24/04 5.0 5.0 1 ND ND ND ND -- ug/L 10/27/04 5.0 5.0 1 ND ND ND ND -- ug/L 05/25/05 5.0 5.0 1 ND ND ND ND -- ug/L 10/05/05 5.0 5.0 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND ND ND ND ND ug/L 10/02/07 -- -- 1 ND ND 0.15 J ND ND ug/L 04/01/08 -- -- 1 ND ND 0.28 J ND ND ug/L 10/29/08 -- -- 1 ND ND 0.28 J ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND 0.50 J ND ND ND ug/L 03/24/10 0.050 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.20 1.0 1 ND ND ND ND ND ug/L 03/16/11 0.68 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.68 1.0 1 ND -- ND ND ND ug/L 03/21/12 0.15 1.0 1 ND ND ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND 0.47 J ND ND ug/L 03/27/14 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.15 1.0 1 ND 0.76 J 0.47 J ND ND ug/L 03/15/16 0.15 1.0 1 ND 0.72 J ND ND ND ug/L 09/21/16 0.15 1.0 1 ND 0.92 J ND ND ND ug/L 03/21/17 0.15 1.0 1 Dry 0.75 J ND ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.15 1.0 -- ND 0.74 J ND ND ND ug/L 03/25/19 0.15 1.0 -- ND 0.59 J 0.66 J ND ND ug/L 09/19/19 0.15 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.15 1.0 -- ND ND 0.64 J ND ND ug/L 09/24/20 0.15 1.0 -- ND 0.41 J 0.75 J ND ND ug/L 03/16/21 0.15 1.0 -- ND 0.44 J 0.92 J ND ND ug/L 09/20/21 0.15 1.0 -- ND 0.65 J 0.91 J ND ND ug/L 03/14/22 0.15 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.15 1.0 -- ND 0.66 J 0.48 J ND ND ug/L 03/30/23 0.15 1.0 -- ND 0.499 J 0.368 J 0.255 J ND 1,4-Dichlorobenzene ug/L 06/21/01 0.27 5.0 1 ND ND ND ND -- NC 2L = 6 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND -- EPA MCL = 75 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND -- ug/L 04/10/03 5.0 5.0 1 ND ND ND ND -- ug/L 10/20/03 5.0 5.0 1 ND ND ND ND -- ug/L 03/24/04 5.0 5.0 1 ND ND ND ND -- ug/L 10/27/04 5.0 5.0 1 ND ND ND ND -- ug/L 05/25/05 5.0 5.0 1 ND ND ND ND -- ug/L 10/05/05 5.0 5.0 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND ND 0.21 J ND ND ug/L 10/02/07 -- -- 1 ND ND 0.23 J 0.23 J ND ug/L 04/01/08 -- -- 1 ND ND 0.26 J ND ND ug/L 10/29/08 -- -- 1 ND ND 0.23 J ND ND ug/L 03/24/09 0.38 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND ND ND ND ug/L 03/24/10 0.10 1.0 1 ND 0.46 J ND 0.45 J ND ug/L 09/22/10 0.38 1.0 1 ND ND ND 0.57 J ND ug/L 03/16/11 0.79 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.79 1.0 1 ND -- ND ND ND ug/L 03/21/12 0.19 1.0 1 ND ND ND 0.64 J ND ug/L 09/20/12 0.19 1.0 1 ND ND ND 0.51 J ND ug/L 03/20/13 0.19 1.0 1 ND ND ND 0.41 J ND ug/L 09/18/13 0.19 1.0 1 ND ND ND 0.55 J ND ug/L 03/27/14 0.19 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.19 1.0 1 ND ND ND 0.52 J ND ug/L 03/18/15 0.19 1.0 1 ND ND ND 0.55 J ND ug/L 09/23/15 0.19 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.19 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.19 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.19 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.19 1.0 -- ND 1.0 ND ND ND ug/L 03/25/19 0.19 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.19 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.19 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.19 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.19 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.19 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.19 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.19 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.19 1.0 -- ND ND ND ND ND 1, 1 -Dichloroethane ug/L 06/21/01 5.0 5.0 5 ND ND ND ND -- NC 2L = 6 ug/L ug/L 04/24/02 5.0 5.0 5 ND ND ND ND -- EPA MCL = No Standard ug/L 10/01/02 5.0 5.0 5 ND ND ND ND -- ug/L 04/10/03 5.0 5.0 5 ND ND ND ND -- ug/L 10/20/03 -- -- 5 ND ND ND ND -- ug/L 03/24/04 -- -- 5 ND ND ND ND -- ug/L 10/27/04 -- -- 5 ND ND ND ND -- ug/L 05/25/05 -- -- 5 ND ND ND ND -- ug/L 10/05/05 -- -- 5 ND ND ND ND -- ug/L 04/25/06 -- -- 5 ND ND ND ND -- ug/L 10/05/06 -- -- 5 ND ND ND ND ND ug/L 03/21/07 -- -- 5 ND ND 0.71 J ND ND ug/L 10/02/07 -- -- 5 ND ND 0.79 J 0.09 J ND ug/L 04/01/08 -- -- 5 ND ND 0.99 J 0.12 J ND ug/L 10/29/08 -- -- 5 ND ND 1.01 J 0.15 J ND ug/L 03/24/09 0.33 1.0 5 ND ND 0.82 J ND ND ug/L 09/22/09 0.33 1.0 5 ND ND 0.70 J ND ND ug/L 03/24/10 0.050 1.0 5 ND ND 0.47 J ND ND ug/L 09/22/10 0.33 1.0 5 ND ND ND ND ND ug/L 03/16/11 0.080 1.0 5 ND ND 0.40 J ND ND ug/L 09/21/11 0.080 1.0 5 ND -- 0.51 J ND ND ug/L 03/21/12 0.13 1.0 5 ND ND ND ND ND ug/L 09/20/12 0.13 1.0 5 ND ND ND ND ND ug/L 03/20/13 0.13 1.0 5 ND ND ND 0.46 J ND ug/L 09/18/13 0.13 1.0 5 ND ND ND ND ND ug/L 03/27/14 0.13 1.0 5 ND ND ND ND ND ug/L 09/18/14 0.13 1.0 5 ND ND ND ND ND ug/L 03/18/15 0.13 1.0 5 ND ND ND ND ND ug/L 09/23/15 0.13 1.0 5 ND ND ND ND ND ug/L 03/15/16 0.13 1.0 5 ND ND ND ND ND ug/L 09/21/16 0.13 1.0 5 ND ND ND ND ND ug/L 03/21/17 0.13 1.0 5 Dry ND ND ND ND ug/L 09/20/17 0.13 1.0 5 ND ND ND ND ND ug/L 03/21/18 0.13 1.0 5 ND ND ND ND ND ug/L 09/25/18 0.13 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.13 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.13 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.13 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.13 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.13 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.13 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.13 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.13 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.13 1.0 -- ND ND ND ND ND 7 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit 1, 1 -Dichloroethene ug/L 03/24/09 0.24 1.0 5 ND ND ND ND ND NC 2L = 350 ug/L ug/L 09/22/09 0.24 1.0 5 ND ND ND ND ND EPA MCL = 7 ug/L ug/L 03/24/10 0.15 1.0 5 ND ND ND ND ND ug/L 09/22/10 0.24 1.0 5 ND ND ND ND ND ug/L 03/16/11 0.60 1.0 5 ND ND 3.3 J ND ND ug/L 09/21/11 0.60 1.0 5 ND -- ND ND ND ug/L 03/21/12 0.21 1.0 5 ND ND ND ND ND ug/L 09/20/12 0.21 1.0 5 ND ND ND ND ND ug/L 03/20/13 0.21 1.0 5 ND ND ND 3.1 J ND ug/L 09/18/13 0.21 1.0 5 ND ND ND ND ND ug/L 03/27/14 0.21 1.0 5 ND ND ND ND ND ug/L 09/18/14 0.21 1.0 5 ND ND ND ND ND ug/L 03/18/15 0.21 1.0 5 ND ND 1.7 J 2.4 J ND ug/L 09/23/15 0.21 1.0 5 ND ND ND ND ND ug/L 03/15/16 0.21 1.0 5 ND ND 1.0 J ND ND ug/L 09/21/16 0.21 1.0 5 ND ND ND ND ND ug/L 03/21/17 0.21 1.0 5 Dry ND ND ND ND ug/L 09/20/17 0.21 1.0 5 ND ND ND ND ND ug/L 03/21/18 0.21 1.0 5 ND ND ND ND ND ug/L 09/25/18 0.21 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.21 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.21 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.21 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.21 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.21 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.21 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.21 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.21 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.21 1.0 -- ND ND ND ND ND cis-1,2-Dichloroethene ug/L 06/21/01 5.0 5.0 5 ND ND ND ND -- NC 2L = 70 ug/L ug/L 04/24/02 5.0 5.0 5 ND ND ND ND -- EPA MCL = 70 ug/L ug/L 10/01/02 5.0 5.0 5 ND ND ND ND -- ug/L 04/10/03 5.0 5.0 5 ND 6 ND ND -- ug/L 10/20/03 5.0 5.0 5 ND ND ND ND -- ug/L 03/24/04 -- -- 5 ND ND ND ND -- ug/L 10/27/04 -- -- 5 ND ND ND ND -- ug/L 05/25/05 -- -- 5 ND ND ND ND -- ug/L 10/05/05 -- -- 5 ND ND ND ND -- ug/L 04/25/06 -- -- 5 ND ND ND ND -- ug/L 10/05/06 -- -- 5 ND ND ND ND ND ug/L 03/21/07 -- -- 5 ND ND 0.20 J ND ND ug/L 10/02/07 -- -- 5 ND ND 0.27 J 0.21 J ND ug/L 04/01 /08 -- -- 5 ND ND 0.39 J 0.30 J ND ug/L 10/29/08 -- -- 5 ND 0.11 J 0.44 J 0.35 J ND ug/L 03/24/09 0.36 1.0 5 ND ND ND ND ND ug/L 09/22/09 0.36 1.0 5 ND 5.7 ND ND ND ug/L 03/24/10 0.075 1.0 5 ND 5.3 ND 0.84 J ND ug/L 09/22/10 0.36 1.0 5 ND ND ND 0.78 J ND ug/L 03/16/11 0.72 1.0 5 ND ND 0.76 J 1.3 J ND ug/L 09/21/11 0.72 1.0 5 ND -- ND 1.1 J ND ug/L 03/21/12 0.15 1.0 5 ND 0.46 J 0.73 J 1.3 J ND ug/L 09/20/12 0.15 -- 5 ND ND 0.60 J 1.4 J ND ug/L 03/20/13 0.15 1.0 5 ND 0.94 J 0.86 J 1.6 J ND ug/L 09/18/13 0.15 1.0 5 ND 1.8 J 1.1 J 1.7 J ND ug/L 03/27/14 0.15 1.0 5 ND 1.2 J 0.64 J 2.3 J ND ug/L 09/18/14 0.15 1.0 5 ND ND 0.90 J 3.0 J ND ug/L 03/18/15 0.15 1.0 5 ND 0.53 J 1.6 J 2.5 J ND ug/L 09/23/15 0.15 1.0 5 ND ND 1.2 J 3.0 J ND ug/L 03/15/16 0.15 1.0 5 ND 2.4 J 1.3 J 3.6 J ND ug/L 09/21/16 0.15 1.0 5 ND 2.4 J 1.6 J 3.6 J ND ug/L 03/21/17 0.15 1.0 5 Dry 1.6 J 1.9 J 3.7 J ND ug/L 09/20/17 0.15 1.0 5 ND 1.7 J 1.4 J 3.4 J ND ug/L 03/21/18 0.15 1.0 5 ND 2.9 J 1.2 J 2.7 J ND ug/L 09/25/18 0.15 1.0 -- ND 6.7 0.76 J 2.1 ND ug/L 03/25/19 0.15 1.0 -- ND 4.8 1.6 3.1 ND ug/L 09/19/19 0.15 1.0 -- ND 1.3 1.7 3.0 ND ug/L 03/16/20 0.15 1.0 -- ND 0.66 J 1.3 2.9 ND ug/L 09/24/20 0.15 1.0 -- ND 0.85 J 1.1 3.0 ND ug/L 03/16/21 0.15 1.0 -- ND 0.90 J 1.3 2.7 ND ug/L 09/20/21 0.15 1.0 -- ND 0.80 J 1.1 2.5 ND ug/L 03/14/22 0.15 1.0 -- ND 0.65 J 1.3 2.4 ND ug/L 09/19/22 0.15 1.0 -- ND 1.0 0.93 J 2.0 ND ug/L 03/30/23 0.15 1.0 -- ND 0.438 J 0.875 J 1.45 ND Chloromethane ug/L 03/24/09 0.34 1.0 1 ND ND ND ND ND NC 2L = 3 ug/L ug/L 09/22/09 0.34 1.0 1 ND ND ND ND ND EPA MCL = No Standard ug/L 03/24/10 0.050 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.34 1.0 1 0.51 J 0.47 J 1.1 ND ND ug/L 03/16/11 0.55 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.55 1.0 1 ND -- ND ND ND ug/L 03/21/12 0.13 1.0 1 ND ND ND ND ND ug/L 09/20/12 0.13 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.13 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.13 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.13 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.13 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.13 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.13 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.13 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.13 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.13 1.0 1 Dry ND 2.4 ND ND ug/L 09/20/17 0.13 1.0 1 ND ND 5.1 ND ND ug/L 03/21/18 0.13 1.0 1 ND ND 8.3 ND ND ug/L 09/25/18 0.13 1.0 -- ND ND 1.7 ND ND ug/L 03/25/19 0.13 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.13 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.13 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.13 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.13 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.13 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.13 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.13 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.13 1.0 -- ND ND 0.908 J ND ND 8 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Methylene chloride ug/L 06/21/01 10.0 10.0 1 ND ND ND ND -- NC 2L = 5 ug/L ug/L 04/24/02 10.0 10.0 1 ND ND ND ND -- EPA MCL = 5 ug/L ug/L 10/01/02 10.0 10.0 1 ND ND ND ND -- ug/L 04/10/03 10.0 10.0 1 ND ND ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 0.20 B ND 2.08 B 0.38 B 0.39 ug/L 10/02/07 -- -- 1 ND ND 1.42 B ND 0.61 ug/L 04/01/08 -- -- 1 ND 0.52 B 2.83 J 0.48 B 0.54 ug/L 10/29/08 -- -- 1 ND ND 2.58 0.52 J ND ug/L 03/24/09 0.53 2.0 1 ND ND 0.53 J ND ND ug/L 09/22/09 0.53 1.0 1 ND ND 1.2 ND ND ug/L 03/24/10 0.070 1.0 1 ND ND 0.92 J ND ND ug/L 09/22/10 0.53 1.0 1 ND ND 0.70 J ND ND ug/L 03/16/11 0.14 1.0 1 ND ND 1.6 0.52 J ND ug/L 09/21/11 0.14 1.0 1 ND -- 1.0 ND ND ug/L 03/21/12 0.23 1.0 1 ND ND 0.87 J 0.62 J ND ug/L 09/20/12 0.23 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.23 1.0 1 ND ND 1.3 ND ND ug/L 09/18/13 0.23 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.23 1.0 1 ND ND 0.59 J 0.59 J ND ug/L 09/18/14 0.23 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.23 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.23 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.23 1.0 1 ND ND 0.62 J 0.59 J ND ug/L 09/21/16 0.23 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.23 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.23 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.23 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.23 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.23 1.0 -- ND ND ND 0.49 J ND ug/L 09/19/19 0.23 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.23 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.23 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.23 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.23 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.23 1.0 -- ND ND ND 0.49 B 0.67 J ug/L 09/19/22 0.23 1.0 -- ND ND ND ND 0.47 J ug/L 03/30/23 0.23 1.0 -- ND ND ND ND 0.362 J Tetrachloroethene ug/L 06/21/01 5.0 5.0 1 ND ND ND ND -- NC 2L = 0.7 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND -- EPA MCL = 5 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND -- ug/L 04/10/03 5.0 5.0 1 ND ND ND ND -- ug/L 10/20/03 5.0 5.0 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND ND 0.76 J ND ND ug/L 10/02/07 -- -- 1 ND ND 1.05 J 0.27 J ND ug/L 04/01 /08 -- -- 1 ND 0.12 J 1.22 J 0.32 J ND ug/L 10/29/08 -- -- 1 ND 0.36 J 1.21 0.33 J ND ug/L 03/24/09 0.36 1.0 1 ND 0.49 J 1.3 ND ND ug/L 09/22/09 0.36 1.0 1 ND 2.9 1.1 ND ND ug/L 03/24/10 0.099 1.0 1 ND 3.4 1.6 0.56 J ND ug/L 09/22/10 0.36 1.0 1 ND ND 1.7 ND ND ug/L 03/16/11 0.73 1.0 1 ND ND 1.4 ND ND ug/L 09/21/11 0.73 1.0 1 ND -- ND 0.75 J ND ug/L 03/21/12 0.17 1.0 1 ND ND 0.74 J 0.49 J ND ug/L 09/20/12 0.17 1.0 1 ND ND 0.73 J ND ND ug/L 03/20/13 0.17 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.17 1.0 1 ND 0.46 J 0.40 J ND ND ug/L 03/27/14 0.17 1.0 1 ND ND 1.2 0.5 J ND (Verification Event) ug/L 05/28/14 0.17 1.0 1 ND -- ND -- ND ug/L 09/18/14 0.17 1.0 1 ND ND 0.91 J 0.45 J ND ug/L 03/18/15 0.17 1.0 1 ND ND 0.46 J ND ND ug/L 09/23/15 0.17 1.0 1 ND ND 0.46 J ND ND ug/L 03/15/16 0.17 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.17 1.0 1 ND ND 0.42 J ND ND ug/L 03/21/17 0.17 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.17 1.0 1 ND ND ND 0.46 J ND ug/L 03/21/18 0.17 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.17 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.17 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.17 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.17 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.17 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.17 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.17 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.17 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.17 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.17 1.0 -- ND ND ND ND ND Trichloroethene ug/L 06/21/01 5 5 1 ND ND ND ND -- NC 2L = 3 ug/L ug/L 04/24/02 5 5 1 ND ND ND ND -- EPA MCL = 5 ug/L ug/L 10/01/02 5 5 1 ND ND ND ND -- ug/L 04/10/03 -- -- 1 ND ND ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND ND 0.24 J ND ND ug/L 10/02/07 -- -- 1 ND ND 0.27 J 0.18 J ND ug/L 04/01 /08 -- -- 1 ND ND 0.51 J 0.19 J ND ug/L 10/29/08 -- -- 1 ND ND 0.52 J 1.13 ND ug/L 03/24/09 0.38 1.0 1 ND ND 0.44 J ND ND ug/L 09/22/09 0.38 1.0 1 ND 0.64 J ND ND ND ug/L 03/24/10 0.13 1.0 1 ND 0.90 J 0.52 J ND ND ug/L 09/22/10 0.38 1.0 1 ND ND ND ND ND ug/L 03/16/11 0.72 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.72 1.0 1 ND -- 0.82 J ND ND ug/L 03/21/12 0.15 1.0 1 ND ND 0.46 J 0.41 J ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.15 1.0 1 ND ND 0.41 J ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND 0.41 J ND ug/L 09/23/15 0.15 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.15 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.15 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.15 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.15 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.15 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.15 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.15 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.15 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.15 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.15 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.15 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.15 1.0 -- ND ND ND ND ND 9 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Trichlorofluoromethane ug/L 06/21/01 5 5 1 ND ND ND ND -- NC 2L = 2000 ug/L ug/L 04/24/02 5 5 1 ND ND ND ND -- EPA MCL = No Standard ug/L 10/01/02 5 5 1 ND ND ND ND -- ug/L 04/10/03 5 5 1 ND ND ND ND -- ug/L 10/20/03 5 5 1 ND ND ND ND -- ug/L 03/24/04 5 5 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND 8.07 ND -- ug/L 04/25/06 -- -- 1 ND ND ND 23.1 -- ug/L 10/05/06 -- -- 1 ND ND 13.8 ND ND ug/L 03/21/07 -- -- 1 ND ND 11.3 ND ND ug/L 10/02/07 -- -- 1 ND ND 9.90 0.26 J ND ug/L 04/01/08 -- -- 1 ND ND 8.03 3.88 ND ug/L 10/29/08 -- -- 1 ND ND 6.83 2.71 ND ug/L 03/24/09 0.28 1.0 1 ND ND 4.3 1.5 ND ug/L 09/22/09 0.28 1.0 1 ND ND 2.0 ND ND ug/L 03/24/10 0.15 1.0 1 ND ND 2.6 1.0 ND ug/L 09/22/10 0.28 1.0 1 ND ND 2.0 0.87 J ND ug/L 03/16/11 0.66 1.0 1 ND ND 1.4 2.5 ND ug/L 09/21/11 0.66 1.0 1 ND -- 0.82 J 1.7 ND ug/L 03/21/12 0.24 1.0 1 ND ND 0.51 J ND ND ug/L 09/20/12 0.24 1.0 1 ND ND 0.80 J 0.76 J ND ug/L 03/20/13 0.24 1.0 1 ND ND ND 1.1 ND ug/L 09/18/13 0.24 1.0 1 ND ND ND 1.3 ND ug/L 03/27/14 0.24 1.0 1 ND ND ND 3.9 ND ug/L 09/18/14 0.24 1.0 1 ND ND ND 1.6 ND ug/L 03/18/15 0.24 1.0 1 ND ND ND 1.5 ND ug/L 09/23/15 0.24 1.0 1 ND ND ND 0.77 J ND ug/L 03/15/16 0.24 1.0 1 ND ND ND 0.72 J ND ug/L 09/21/16 0.24 1.0 1 ND ND ND 0.82 J ND ug/L 03/21/17 0.24 1.0 1 Dry ND ND 0.52 J ND ug/L 09/20/17 0.24 1.0 1 ND ND ND 0.46 J ND ug/L 03/21/18 0.24 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.24 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.24 1.0 -- ND ND ND ND ND ug/L 09/19/19 0.24 1.0 -- ND ND ND ND ND ug/L 03/16/20 0.24 1.0 -- ND ND ND ND ND ug/L 09/24/20 0.24 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.24 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.24 1.0 -- ND ND ND ND ND ug/L 03/14/22 0.24 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.24 1.0 -- ND ND ND ND ND ug/L 03/30/23 0.24 1.0 -- ND ND ND ND ND Vinyl Chloride ug/L 06/21/01 10 10 1 ND ND ND ND -- NC 2L = 0.03 ug/L ug/L 04/24/02 10 10 1 ND ND ND ND -- EPA MCL = 2 ug/L ug/L 10/01/02 10 10 1 ND ND ND ND -- ug/L 04/10/03 -- -- 1 ND ND ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/05/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/05/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND ND ND ND ND ug/L 10/02/07 -- -- 1 ND ND ND ND ND ug/L 04/01/08 -- -- 1 ND ND ND ND ND ug/L 10/29/08 -- -- 1 ND ND 0.56 J ND ND ug/L 03/24/09 0.30 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.30 1.0 1 ND 0.55 J ND ND ND ug/L 03/24/10 0.083 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.30 1.0 1 ND ND 0.42 J ND ND ug/L 03/16/11 0.60 1.0 1 ND ND ND 0.64 J ND ug/L 09/21/11 0.60 1.0 1 ND -- ND ND ND ug/L 03/21/12 0.32 1.0 1 ND ND 0.45 J ND ND ug/L 09/20/12 0.32 1.0 1 ND ND 0.57 J 0.56 J ND ug/L 03/20/13 0.32 1.0 1 ND 0.51 J 0.70 J 0.51 J ND ug/L 09/18/13 0.32 1.0 1 ND 0.83 J 0.79 J 0.72 J ND ug/L 03/27/14 0.32 1.0 1 ND 1.5 1.3 2.5 ND (Verification Event) ug/L 05/28/14 0.32 1.0 1 ND 0.72 J ND 1.8 ND ug/L 09/18/14 0.32 1.0 1 ND 0.97 J 0.92 J 2.0 ND ug/L 03/18/15 0.32 1.0 1 ND 0.85 J 0.86 J 2.5 ND ug/L 09/23/15 0.32 1.0 1 ND 0.78 J 1.2 2.6 ND ug/L 03/15/16 0.32 1.0 1 ND 1.3 0.98 J 2.2 ND ug/L 09/21/16 0.32 1.0 1 ND 1.5 1.3 2.5 ND ug/L 03/21/17 0.32 1.0 1 Dry 0.86 J 1.5 2.6 ND ug/L 09/20/17 0.32 1.0 1 ND 0.70 J 1.2 1.5 ND ug/L 03/21/18 0.32 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.32 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.32 1.0 -- ND 0.57 J 1.5 1.8 ND ug/L 09/19/19 0.32 1.0 -- ND ND 1.3 1.9 ND ug/L 03/16/20 0.32 1.0 -- ND ND 0.74 J 0.76 J ND ug/L 09/24/20 0.32 1.0 -- ND ND 0.57 J 1.8 ND ug/L 03/16/21 0.32 1.0 -- ND ND 0.75 J 1.6 ND ug/L 09/20/21 0.32 1.0 -- ND ND 0.89 J 1.5 ND ug/L 03/14/22 0.32 1.0 -- ND ND ND ND ND ug/L 09/19/22 0.32 1.0 -- ND ND 0.81 J 0.90 J ND ug/L 03/30/23 0.32 1.0 -- ND ND 1.04 0.596 J ND Xylenes (Total) ug/L 06/21/01 5 5 5 ND ND ND ND -- NC 2L = 500 ug/L ug/L 04/24/02 5 5 5 ND ND ND ND -- EPA MCL = 10000 ug/L ug/L 10/01/02 5 5 5 ND ND ND ND -- ug/L 04/10/03 5 5 5 ND ND ND ND -- ug/L 10/20/03 5 5 5 ND ND ND ND -- ug/L 03/24/04 -- -- 5 ND ND ND ND -- ug/L 10/27/04 -- -- 5 ND ND ND ND -- ug/L 05/25/05 -- -- 5 ND ND ND ND -- ug/L 10/05/05 -- -- 5 ND ND ND ND -- ug/L 04/25/06 -- -- 5 ND ND ND ND -- ug/L 10/05/06 -- -- 5 ND ND ND ND ND ug/L 03/21/07 -- -- 5 ND ND 0.17 J ND ND ug/L 10/02/07 -- -- 5 ND ND 0.17 J ND ND ug/L 04/01/08 -- -- 5 ND ND 0.28 J ND ND ug/L 10/29/08 -- -- 5 ND ND 0.25 J ND ND ug/L 03/24/09 0.40 1.0 5 ND ND ND ND ND ug/L 09/22/09 0.40 1.0 5 ND 0.72 J ND ND ND ug/L 03/24/10 0.22 1.0 5 ND 0.62 J ND ND ND ug/L 09/22/10 0.40 1.0 5 ND ND ND ND ND ug/L 03/16/11 2.1 3.0 5 ND ND ND ND ND ug/L 09/21/11 2.1 3.0 5 ND -- ND ND ND ug/L 03/21/12 0.45 3.0 5 ND ND ND ND ND ug/L 09/20/12 0.45 3.0 5 ND ND ND ND ND ug/L 03/20/13 0.45 3.0 5 ND ND ND ND ND ug/L 09/18/13 0.45 3.0 5 ND ND ND ND ND ug/L 03/27/14 0.45 3.0 5 ND ND ND ND ND ug/L 09/18/14 0.45 3.0 5 ND ND ND ND ND ug/L 03/18/15 0.45 3.0 5 ND ND ND ND ND ug/L 09/23/15 0.45 3.0 5 ND ND ND ND ND ug/L 03/15/16 0.45 3.0 5 ND ND ND ND ND ug/L 09/21/16 0.45 3.0 5 ND ND ND ND ND ug/L 03/21/17 0.45 3.0 5 Dry ND ND ND ND ug/L 09/20/17 0.45 3.0 5 ND ND ND ND ND ug/L 03/21/18 0.45 3.0 5 ND ND ND ND ND ug/L 09/25/18 0.45 3.0 -- ND ND ND ND ND ug/L 03/25/19 0.45 3.0 -- ND ND ND ND ND ug/L 09/19/19 0.45 3.0 -- ND ND ND ND ND ug/L 03/16/20 0.45 3.0 -- ND ND ND ND ND ug/L 09/24/20 0.45 3.0 -- ND ND ND ND ND ug/L 03/16/21 0.45 3.0 -- ND ND ND ND ND ug/L 09/20/21 0.45 3.0 -- ND ND ND ND ND ug/L 03/14/22 0.45 3.0 -- ND ND ND ND ND ug/L 09/19/22 0.45 3.0 -- ND ND ND ND ND ug/L 03/30/23 0.45 3.0 -- ND ND ND ND ND 10 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit 1,4-Dioxane ug/L 09/25/18 1.2 2.0 -- ND ND 3.3 1.9 J ND NC 2L = 3 ug/L ug/L 03/25/19 1.2 2.0 -- ND ND 8.7 1.9 J ND ug/L 09/19/19 1.2 2.0 -- ND ND 10 2.3 ND ug/L 03/16/20 0.80 2.0 -- ND ND 13 2.1 ND ug/L 09/24/20 0.80 2.0 -- ND ND 12 2.2 ND ug/L 03/16/21 0.80 2.0 -- ND ND 10 2.4 ND ug/L 09/20/21 0.80 2.0 -- ND 2.2 10 2.8 ND ug/L 03/14/22 0.80 2.0 -- ND 6.2 7.2 3.3 ND ug/L 09/19/22 0.80 2.0 -- ND 4.5 2.9 4.2 ND ug/L 03/30/23 0.32 0.5 -- ND 1.98 1.18 3.55 ND Tetrahydrofuran ug/L 03/16/11 0.80 1.0 -- ND ND 74 7.6 ND IMAC = 2000 ug/L ug/L 09/21/11 0.80 1.0 -- ND -- 39 8.2 ND EPA MCL = No Standard ug/L 03/21/12 0.80 1.0 -- ND ND 28 17 ND ug/L 09/20/12 0.80 1.0 -- ND ND 22 9.1 ND ug/L 03/20/13 0.80 1.0 -- ND ND 34 B 9.0 B 21 ug/L 09/18/13 0.80 1.0 -- ND 11 13 3.6 ND ug/L 03/27/14 0.80 1.0 -- ND 200 ND 8.0 ND ug/L 09/18/14 0.80 1.0 -- ND 21 ND 9.5 ND ug/L 03/18/15 0.80 1.0 -- ND 9.8 6.3 6.8 ND ug/L 09/23/15 0.80 1.0 -- ND 99 6.4 10 ND ug/L 03/15/16 0.80 1.0 -- ND 50 4.9 14 ND ug/L 09/21/16 0.80 1.0 -- ND ND 13 14 ND ug/L 03/21/17 0.80 1.0 -- Dry 48 14 9.4 ND ug/L 09/20/17 0.80 1.0 -- ND 9.9 4.8 5.7 ND ug/L 03/21/18 0.80 1.0 -- ND ND ND 5.8 ND ug/L 09/25/18 0.53 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.53 1.0 -- ND ND 12 ND ND ug/L 09/19/19 0.53 1.0 -- ND ND 32 2.1 ND ug/L 03/16/20 0.53 1.0 -- ND ND 29 ND ND ug/L 09/24/20 0.53 1.0 -- ND ND ND ND ND ug/L 03/16/21 0.53 1.0 -- ND ND ND ND ND ug/L 09/20/21 0.53 1.0 -- ND 6.1 24 6.6 ND ug/L 03/14/22 0.53 1.0 -- ND ND 25 13 ND ug/L 09/19/22 0.53 1.0 -- ND ND 6.4 16 ND ug/L 03/30/23 0.53 1.0 -- ND ND ND 14 ND 2,4-D ug/L 03/21/12 0.16 0.50 2 ND ND ND 0.80 J ND NC 2L = 70 ug/L ug/L 09/20/12 0.16 0.50 2 ND ND ND ND ND EPA MCL = 70 ug/L ug/L 03/20/13 0.16 0.50 2 ND ND ND 1.1 J ND ug/L 09/18/13 0.16 0.50 2 ND ND ND 1.3 J ND ug/L 03/27/14 0.27 0.50 2 ND ND ND 1.0 J ND ug/L 09/18/14 0.27 0.50 2 ND ND ND 0.85 J ND ug/L 03/18/15 0.27 0.50 2 ND ND ND 0.82 J ND ug/L 09/23/15 0.27 0.50 2 ND ND ND 0.54 J ND ug/L 03/15/16 0.27 0.50 2 ND ND ND ND ND ug/L 09/21/16 0.27 0.50 2 ND ND ND ND ND ug/L 03/21/17 0.27 0.50 2 Dry ND ND ND ND ug/L 09/20/17 0.27 0.50 2 ND ND ND ND ND ug/L 03/21/18 0.27 0.50 2 ND ND ND ND ND ug/L 09/25/18 0.27 0.50 -- ND ND ND ND ND ug/L 03/25/19 0.27 0.50 -- ND ND ND 1.0 ND ug/L 09/19/19 0.27 0.50 -- ND ND ND ND ND ug/L 03/16/20 0.27 0.50 -- ND ND ND ND ND ug/L 09/24/20 0.27 0.50 -- ND ND ND 1.5 ND ug/L 03/16/21 0.27 0.50 -- ND ND ND 0.56 ND ug/L 09/20/21 0.27 0.50 -- ND ND ND ND ND ug/L 03/14/22 0.27 0.50 -- ND ND ND 0.75 ND ug/L 09/19/22 0.27 0.50 -- ND ND ND 0.63 ND ug/L 03/30/23 0.18 1.10 -- ND ND ND 0.17 J ND Chloride mg/L 03/24/09 1.9 5.0 -- ND 8.8 4.1 J ND ND NC 2L = 250 mg/L mg/L 09/22/09 0.018 5.0 -- 3.1 J 8.1 8.7 3.6 J ND EPA MCL = 250 mg/L mg/L 03/24/10 1.2 5.0 -- ND 1.7 J 7.3 2.5 J ND mg/L 09/22/10 0.018 5.0 -- 3 J 4.7 J 4.8 J 5.1 ND mg/L 03/16/11 0.047 5.0 -- 3 J ND J 8.6 4.8 J ND mg/L 09/21/11 0.047 5.0 -- 2.6 B -- 17 4.4 B 1.5 J mg/L 03/21/12 0.43 5.0 -- 2.3 B 4.2 B 18 4.6 B 1.2 J mg/L 09/20/12 0.43 5.0 -- 2.6 B 6.3 B 16 6.3 B 1.5 mg/L 03/20/13 0.43 5.0 -- 2.6 B 6.6 B 14 7.3 B 1.5 mg/L 09/18/13 2.2 5.0 -- 2.4 J 5.0 13 5.9 ND mg/L 03/27/14 2.2 5.0 -- 2.4 J 23 3.7 J 5.2 ND mg/L 09/18/14 2.2 5.0 -- 2.6 J 8.9 3.1 J 5.4 ND mg/L 03/18/15 2.2 5.0 -- 2.3 J 60 19 5.6 ND mg/L 09/23/15 2.2 5.0 -- 2.6 J 20 15 5.8 ND mg/L 03/15/16 2.2 5.0 -- ND 14 10 5.1 ND mg/L 09/21/16 2.2 5.0 -- ND 32 18 5.5 ND mg/L 03/21/17 2.2 5.0 -- Dry 45 27 6.0 ND mg/L 09/20/17 2.2 5.0 -- ND 110 19 6.7 ND mg/L 03/21/18 2.2 5.0 -- ND 13 27 7.0 ND mg/L 09/25/18 2.2 5.0 -- ND 9.3 15.0 7.0 ND mg/L 03/25/19 2.2 5.0 -- ND 14 41 7.7 ND mg/L 09/19/19 2.2 5.0 -- ND 12 47 7.7 ND mg/L 03/16/20 2.2 5.0 -- 2.9 J 15 51 8.9 ND mg/L 09/24/20 2.2 5.0 -- 2.5 J 14 48 9.1 ND mg/L 03/16/21 2.2 5.0 -- 3.0 J 15 56 10 ND mg/L 09/20/21 2.2 5.0 -- 3.2 J 18 53 12 ND mg/L 03/14/22 2.2 5.0 -- 3.1 J 49 44 14 ND mg/L 09/19/22 2.2 5.0 -- 3.4 J 10 27 16 ND mg/L 03/30/23 0.2 0.5 -- 2.3 18 44 20 ND Total Dissolved Solids mg/L 03/24/09 10 10 -- 86 310 190 140 ND NC 2L = 500 mg/L mg/L 09/22/09 10 10 -- 66 280 160 130 ND EPA MCL = 500 mg/L mg/L 03/24/10 10 10 -- 22 110 170 140 ND mg/L 09/22/10 10 10 -- 40 110 160 190 ND mg/L 03/16/11 10 10 -- 46 ND 160 120 ND mg/L 09/21/11 10 10 -- 16 -- 200 140 ND mg/L 03/21/12 10 10 -- 18 190 190 140 ND mg/L 09/20/12 10 10 -- 200 170 120 110 ND mg/L 03/20/13 10 10 -- 46 270 260 260 ND mg/L 09/18/13 10 10 -- ND 110 180 180 ND mg/L 03/27/14 10 10 -- ND 300 110 170 ND mg/L 09/18/14 10 10 -- ND 180 98 180 ND mg/L 03/18/15 10 10 -- 38 330 210 150 ND mg/L 09/23/15 10 10 -- ND 400 190 160 ND mg/L 03/15/16 10 10 -- ND 360 190 170 ND mg/L 09/21/16 10 10 -- ND 720 150 120 ND mg/L 03/21/17 10 10 -- Dry 970 320 200 ND mg/L 09/20/17 10 50 -- ND 1000 270 210 ND mg/L 03/21/18 10 50 -- ND 540 210 170 ND mg/L 09/25/18 50 50 -- ND 390 160 140 ND mg/L 03/25/19 50 50 -- ND 750 390 200 ND mg/L 09/19/19 50 50 -- ND 570 510 240 ND mg/L 03/16/20 50 50 -- ND 600 480 180 ND mg/L 09/24/20 50 50 -- ND 550 500 180 ND mg/L 03/16/21 50 50 -- ND 660 600 220 ND mg/L 09/20/21 50 50 -- ND 630 580 200 ND mg/L 03/14/22 50 50 -- 120 860 570 210 ND mg/L 09/19/22 50 50 -- ND 600 ND 310 ND mg/L 03/30/23 50 50 -- ND 610 274 472 ND 11 of 12 July 2023 TABLE 8 GL2014715721 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SWS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Sulfate as SO4 mg/L 03/24/09 0.078 5.0 250 1.5 J 150 J 18 J 3.0 J ND NC 2L = 250 mg/L mg/L 09/22/09 0.078 5.0 250 1.7 J 100 J 17 J 3.9 J ND EPA MCL = 250 mg/L mg/L 03/24/10 0.12 5.0 250 ND 5.3 J 16 J 2.1 J ND mg/L 09/22/10 0.12 5.0 250 ND 4.8 J 5.4 J 4.9 J ND mg/L 03/16/11 0.02 5.0 250 1.9 J ND J 7.3 J 3.9 J ND mg/L 09/21/11 0.02 5.0 250 1.7 B -- 14 J 4.2 B 1.7 J mg/L 03/21/12 0.04 5.0 250 1.5 J 46 J 18 J 6.3 J ND mg/L 09/20/12 0.04 5.0 250 1.9 J 66 J 18 J 9.9 J ND mg/L 03/20/13 0.04 5.0 250 1.6 J 32 J 16 J 12 J ND mg/L 09/18/13 0.04 5.0 250 1.60 B 18.0 J 14.0 J 15.0 J 1.50 J mg/L 03/27/14 2.9 5.0 250 ND 83.0 J ND 14.0 J ND mg/L 09/18/14 2.9 5.0 250 ND 49 J ND 16 J ND mg/L 03/18/15 2.9 5.0 250 ND 78 J 25 J 17 J ND mg/L 09/23/15 2.9 5.0 250 ND 73 J 22 J 19 J ND mg/L 03/15/16 2.9 5.0 250 ND 98 J 14 J 17 J ND mg/L 09/21/16 2.9 5.0 250 ND 250 18 J 18 J ND mg/L 03/21/17 2.9 5.0 250 Dry 310 31 J 20 J ND mg/L 09/20/17 2.9 5.0 250 ND 460 27 J 24 J ND mg/L 03/21/18 2.9 5.0 250 ND 160 J 14 J 23 J ND mg/L 09/25/18 2.9 5.0 -- ND 96 16 20 ND mg/L 03/25/19 2.9 5.0 -- ND 190 46 19 ND mg/L 09/19/19 2.9 5.0 -- ND 140 54 18 ND mg/L 03/16/20 2.9 5.0 -- ND 46 61 22 ND mg/L 09/24/20 2.9 5.0 -- ND 240 62 22 ND mg/L 03/16/21 2.9 5.0 -- ND 290 87 23 ND mg/L 09/20/21 2.9 5.0 -- ND 270 56 24 ND mg/L 03/14/22 2.9 5.0 -- ND 68 93 22 ND mg/L 09/19/22 2.9 5.0 -- ND 210 53 25 ND mg/L 03/30/23 0.4 1.0 -- ND 172 36 28 ND Total Alkalinity mg/L 03/24/09 8.3 15 -- 17 18 80 65 ND NC 2L = No Standard mg/L 09/22/09 8.3 15 -- 12 J 41 76 68 ND EPA MCL = No Standard mg/L 03/24/10 8.0 15 -- 9.6 J 57 76 75 ND mg/L 09/22/10 8 15 -- ND 46 86 100 ND mg/L 03/16/11 12 15 -- ND ND 94 96 ND mg/L 09/21/11 12 15 -- ND -- 90 90 ND mg/L 03/21/12 12 15 -- 14 J 51 87 100 ND mg/L 09/20/12 12 15 -- 19 53 86 100 ND mg/L 03/20/13 12 15 -- 15 69 96 110 ND mg/L 09/18/13 14 15 -- ND 77.0 110 110 ND mg/L 03/27/14 14 15 -- ND 84.0 94.0 110 ND mg/L 09/18/14 14 15 -- ND 96 83 110 ND mg/L 03/18/15 14 15 -- 14 J 120 130 120 ND mg/L 09/23/15 14 15 -- 16 260 140 120 ND mg/L 03/15/16 14 15 -- 19 160 130 120 ND mg/L 09/21/16 14 15 -- ND 350 150 120 ND mg/L 03/21/17 14 15 -- Dry 370 170 120 ND mg/L 09/20/17 14 75 -- ND 330 170 120 ND mg/L 03/21/18 14 15 -- ND 240 140 110 ND mg/L 09/25/18 14 15 -- ND 230 160 120 ND mg/L 03/25/19 14 15 -- ND 370 190 130 ND mg/L 09/19/19 14 15 -- ND 300 280 140 ND mg/L 03/16/20 14 15 -- 16 300 240 130 ND mg/L 09/24/20 14 15 -- ND 170 310 130 ND mg/L 03/16/21 14 15 -- ND 140 290 130 ND mg/L 09/20/21 14 15 -- 17 170 310 130 ND mg/L 03/14/22 14 15 -- 18 300 280 140 ND mg/L 09/19/22 14 15 -- 21 290 180 140 ND mg/L 03/30/23 2.2 5.0 -- 27 319 152 136 ND Notes: ug/L = micrograms per liter mg/L = milligrams per liter ND = Not detected at the stated reporting limit J = The March 2019 event, J flags are estimated values between the MDL and PQL. Prior to the November B = Blank -qualified result -- = no data available # = EPA Action Level * = EPA Secondary MCL MDL = laboratory method detection limit PQL = practical quantitation limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007, ending in July 2018 EPA MCL = US Environmental Protection Agency Maximum Contaminant Level NC 2L = North Carolina 2L Groundwater Standard IMAC = Interim Maximum Allowable Concentration (under NC 2L Rules) 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2022 event: antimony and thallium in all wells (2x); Total alkalinity: (5x) at MW-7, MW-8, & MW-11; sulfate: (4x) at MW-11 12 of 12 July 2023 GL2014715721 TABLE 9 Summary of Field Parameters for C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Detected Monitoring Upgradient Well Downgradient Wells Units Date MW-10 MW-11 MW-12 MW-13 Constituent/Parameter pH (field) S. U. 03/21/07 5.23 5.29 5.52 5.78 S. U. 03/24/09 6.78 6.22 6.46 6.84 S. U. 09/22/09 7.37 5.41 5.59 5.90 S. U. 03/24/10 7.47 5.64 5.90 6.61 S. U. 09/22/10 5.80 5.27 5.39 5.81 S. U. 03/16/11 5.58 5.48 5.52 5.65 S. U. 09/21 /11 5.92 -- 5.38 5.87 S. U. 03/21/12 6.75 5.18 5.47 5.89 S. U. 09/20/12 6.34 5.72 5.07 6.16 S. U. 03/20/13 5.86 5.37 5.63 5.73 S. U. 09/18/13 5.83 5.40 5.76 6.06 S. U. 03/26/14 4.65 5.42 4.94 6.03 (Verification Event) S. U. 05/28/14 -- 5.46 5.96 6.12 S. U. 09/18/14 7.11 5.30 5.75 6.66 S. U. 03/18/15 6.31 5.27 5.70 5.73 S. U. 09/24/15 5.73 5.72 5.67 5.68 S. U. 03/15/16 4.86 5.58 5.45 5.48 S. U. 09/21/16 6.04 6.56 5.99 5.77 S. U. 03/21/17 Dry 5.87 5.55 5.41 S. U. 09/20/17 5.45 5.88 5.83 5.75 S. U. 03/21/18 5.69 6.12 5.92 5.85 S. U. 09/25/18 5.56 5.89 5.76 5.67 S. U. 03/25/19 5.51 6.10 5.93 5.76 S. U. 09/19/19 4.46 5.97 5.90 5.72 S. U. 03/16/20 4.99 5.94 5.74 5.46 S. U. 09/24/20 4.26 5.65 5.74 5.35 S. U. 03/16/21 5.63 5.85 6.01 5.70 S. U. 09/21 /21 5.75 6.15 6.25 5.72 S. U. 3/14/22 5.62 6.08 6.02 5.67 S. U. 09/19/22 4.59 6.26 5.83 5.50 S. U. 03/20/23 5.54 6.19 5.85 5.90 Specific Conductivity (field) PS/cm 03/21/07 35 73 135 87 PS/cm 03/24/09 50 450 150 230 PS/cm 09/22/09 58 404 240 156 PS/cm 03/24/10 42 170 249 191 PS/cm 09/22/10 37 144 230 316 PS/cm 03/16/11 46 138 256 220 PS/cm 09/21/11 44 -- 272 207 PS/cm 03/21/12 22 188 292 219 PS/cm 09/20/12 44 262 218 215 PS/cm 03/20/13 36 213 252 215 PS/cm 09/18/13 39 227 309 283 PS/cm 03/18/14 40 1034 367 277 PS/cm 03/26/14 54 493 227 310 (Verification Event) pS/cm 05/28/14 -- 430 211 307 PS/cm 09/18/14 63 407 221 318 PS/cm 09/24/15 36 691 318 259 PS/cm 03/15/16 42 749 324 295 PS/cm 09/21/16 32 1040 342 272 PS/cm 03/21/17 Dry 1167 405 264 PS/cm 09/20/17 88 1449 400 301 PS/cm 03/21/18 47 777 409 301 PS/cm 09/25/18 37 748 389 310 PS/cm 03/25/19 31 1148 614 320 PS/cm 09/19/19 31 845 784 348 PS/cm 03/16/20 32 930 768 335 PS/cm 09/24/20 32 851 845 329 PS/cm 03/16/21 38 1112 1091 392 PS/cm 09/21/21 30 892 891 409 PS/cm 03/14/22 36 1009 778 300 PS/cm 09/19/22 42 659 519 360 PS/cm 03/20/23 44 882 457 359 1 of 3 July 2023 GL2014715721 TABLE 9 Summary of Field Parameters for C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Detected Monitoring Upgradient Well Downgradient Wells Units Date MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Temperature (field) Celsius 03/21/07 14.1 15.5 13.5 13.1 Celsius 03/24/09 16.0 14.7 14.1 15.8 Celsius 09/22/09 15.68 15.92 14.99 14.90 Celsius 03/24/10 13.36 14.12 13.13 12.31 Celsius 09/22/10 15.22 15.42 14.36 14.61 Celsius 03/16/11 12.28 13.51 12.90 12.73 Celsius 09/21/11 13.97 -- 15.20 14.38 Celsius 03/21/12 14.35 17.52 15.18 16.65 Celsius 09/20/12 14.15 17.47 14.45 13.97 Celsius 03/20/13 9.27 13.86 12.44 13.00 Celsius 09/18/13 13.8 18.9 14.6 14.3 Celsius 03/26/14 11.5 14.8 13.8 13.5 (Verification Event) Celsius 05/28/14 -- 16.9 18.6 17.2 Celsius 09/18/14 13.9 21.9 14.9 14.5 Celsius 03/18/15 14.2 14.2 14.4 13.6 Celsius 09/24/15 15.0 16.6 15.2 15.6 Celsius 03/15/16 15.3 15.5 14.4 14.9 Celsius 09/21/16 16.1 17.1 17.0 15.3 Celsius 03/21/17 Dry 15.4 14.5 14.5 Celsius 09/20/17 22.2 22.1 18.0 19.4 Celsius 03/21/18 9.9 13.4 13.4 12.4 Celsius 09/25/18 16.4 19.9 16.7 16.9 Celsius 03/25/19 13.6 15.8 13.8 12.9 Celsius 09/19/19 14.4 17.8 15.7 15.4 Celsius 03/16/20 13.4 15.8 14.7 13.2 Celsius 09/24/20 14.3 17.5 15.5 15.5 Celsius 03/16/21 13.0 15.6 14.3 12.9 Celsius 09/21/21 14.6 17.8 15.9 16.0 Celsius 03/14/22 13.1 16.6 16.2 14.8 Celsius 09/19/22 14.8 19.6 16.3 15.7 Celsius 03/20/23 12.3 16.3 15.1 14.6 Turbidity (field) NTU 03/24/09 76.2 13.8 149 108 NTU 09/22/09 20.1 20.4 61.3 37.3 NTU 03/24/10 6.36 16.6 51.1 19.7 NTU 09/22/10 8.46 5.45 10.3 24.2 NTU 03/16/11 21.6 12.1 36.1 17.6 NTU 09/21/11 14.6 -- 27.6 26.4 NTU 03/21/12 45.0 45.8 13.5 27.5 NTU 09/20/12 42.3 35.0 32.4 25.2 NTU 03/20/13 4.86 11.9 12.2 20.4 NTU 09/18/13 >1000 26.5 47.1 81.5 NTU 03/26/14 4.60 15.5 1.93 2.55 (Verification Event) NTU 05/28/14 -- 13.0 44.6 121 NTU 09/18/14 1.78 8.31 1.01 16.0 NTU 03/18/15 14.20 46.9 43.2 11.7 NTU 09/24/15 17.6 3.7 19.7 17.2 NTU 03/15/16 7.53 2.91 1.44 0.38 NTU 09/21/16 1.70 2.09 2.12 2.17 NTU 03/21/17 Dry 4.36 1.54 0.87 NTU 09/20/17 8.49 7.09 0.38 0.25 NTU 03/21/18 0.71 6.34 1.41 0.96 NTU 09/25/18 1.89 5.64 3.74 1.36 NTU 03/25/19 1.48 2.28 1.16 0.44 NTU 09/19/19 0.39 0.00 2.16 1.62 NTU 03/16/20 1.33 1.02 0.54 1.04 NTU 09/24/20 1.05 1.93 0.01 0.01 NTU 03/16/21 1.34 1.71 0.83 0.21 NTU 09/21/21 0.88 6.94 1.66 0.69 NTU 03/14/22 1.88 7.70 1.28 1.02 NTU 09/19/22 6.63 5.81 1.05 0.77 NTU 03/20/23 0.97 6.84 0.39 1.00 Oxidation Reduction Potential (field) mV 09/18/13 -- 49.2 -- -- mV 03/27/14 -- -146 -- -- mV 09/18/14 -- 70.6 -- -- mV 03/18/15 -- 107 -- -- mV 09/24/15 95.8 72.0 99.3 91.0 mV 03/15/16 247 115 200 66.1 mV 03/21/17 Dry -80.4 -204 -73.0 mV 09/20/17 123 7.7 111 -65.5 mV 03/21/18 308 57.5 288 110 mV 09/25/18 206 -102 94.4 -41.9 mV 03/25/19 420 -41.6 384 130 mV 09/19/19 167 -57.9 37.3 -91.0 mV 03/16/20 357 -5.7 131 18.9 mV 09/24/20 131 -173 -157 -130 mV 03/16/21 318 8.5 172 12.8 mV 09/21/21 173 22.3 79.3 10.4 mV 03/14/22 187 -22.2 96.6 22.0 mV 09/19/22 171 -98.1 44.4 -30.1 mV 03/20/23 69.4 15.2 -11.1 -39.1 2 of 3 July 2023 GL2014715721 TABLE 9 Summary of Field Parameters for C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date Upgradient Well Downgradient Wells MW-10 MW-11 MW-12 MW-13 Dissolved Oxygen (field) mg/L 09/18/13 -- 0.33 -- -- mg/L 03/27/14 -- 0.24 -- -- mg/L 09/18/14 -- 0.55 -- -- mg/L 03/18/15 -- 0.44 -- -- mg/L 09/24/15 7.31 0.40 1.48 1.20 mg/L 03/15/16 6.47 0.08 0.42 0.16 mg/L 09/21/16 8.22 0.33 1.38 1.10 mg/L 03/21/17 Dry 0.60 0.63 0.54 mg/L 09/20/17 7.42 3.06 0.50 0.42 mg/L 03/21/18 4.53 0.36 0.40 0.39 mg/L 09/25/18 6.03 0.09 0.79 0.55 mg/L 03/25/19 7.80 0.13 0.80 0.29 mg/L 09/19/19 8.42 0.21 1.28 0.55 mg/L 03/16/20 7.88 1.02 0.34 2.24 mg/L 09/24/20 7.03 0.50 0.44 1.38 mg/L 03/16/21 7.63 0.37 0.53 2.24 mg/L 09/21/21 7.33 0.29 2.55 1.77 mg/L 03/14/22 7.84 0.18 0.55 1.53 mg/L 09/19/22 5.09 0.12 0.32 0.42 mg/L 03/20/23 9.10 0.22 5.26 8.92 Notes: NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter S.U. = Standard Units -- = no data available 1) Historical data prior to March 2009 provided by Henderson County and CDM. 3 of 3 July 2023 GL2014715721 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Background Detected Monitoring Units MDL PQL Date Reporting Well Monitored Natural Attenuation Monitoring Wells Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMWA S AMW-2S Old MW-2 Sulfide mg/L 0.031 0.1 09/24/09 1 ND 0.28 J ND ND -- -- 0.48 J ND mg/L 0.031 0.1 03/23/10 1 -- -- -- -- -- -- -- ND mg/L 0.01 0.1 09/24/15 1 ND 0.12 J ND ND ND ND ND ND mg/L 0.01 0.1 03/15/16 1 ND 0.30 J ND ND 0.360 J ND ND ND mg/L 0.01 0.1 09/21/16 1 ND ND ND ND ND ND ND ND mg/L 0.01 0.1 03/21/17 1 ND 0.098 J ND ND ND ND ND ND mg/L 0.01 0.1 09/20/17 1 -- -- -- -- -- -- -- -- mg/L 0.01 0.1 03/21/18 1 ND 0.69 J ND ND -- -- -- ND mg/L 0.01 0.1 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.01 0.1 03/16/20 -- ND 0.68 ND ND ND ND ND ND mg/L 0.01 0.1 03/15/21 -- 0.094 J ND 0.015 J ND -- -- -- ND mg/L 0.01 0.1 03/14/22 -- ND 0.063 J ND 0.017 J -- -- -- ND mg/L 0.01 0.1 09/19/22 -- ND 0.470 ND 0.029 J ND ND 0.052 J ND m /L 1.00 1.0 03/20/23 -- ND 0.470 ND ND ND ND ND ND Chloride mg/L 0.018 5 09/24/09 1 5.3 3.0 J 22 32 -- -- 7.8 ND mg/L 1.2 5 03/23/10 1 -- -- -- -- -- -- -- ND mg/L 2.2 5 09/24/15 1 4.3 J 0.18 J 39 5.8 4.3 J 14 16 ND mg/L 2.2 5 03/15/16 1 5.4 57 99 32 18 11 15 ND mg/L 2.2 5 09/21/16 1 6.1 190 67 19 23 12 19 ND mg/L 2.2 5 03/21/17 1 5.2 180 49 42 8.8 14 20 ND mg/L 2.2 5 09/20/17 1 5.8 4.7 J 53 30 14 14 21 ND mg/L 2.2 5 03/21/18 -- 8.5 3.2 J 57 57 62 14 21 ND mg/L 2.2 5 09/24/18 -- 4.4 54 95 24 44 14 22 ND mg/L 2.2 5 03/25/19 -- 7.0 12 100 33 58 13 24 ND mg/L 2.2 5 09/18/19 -- 5.3 190 J 76 33 16 13 25 ND mg/L 2.2 5 03/16/20 -- 5.0 17 110 37 62 14 27 ND mg/L 2.2 5 09/23/20 -- 4.4 J 4.2 J 92 19 25 13 27 ND mg/L 2.2 5 03/15/21 -- 4.8 J 18 140 27 22 14 29 ND mg/L 2.2 5 09/20/21 -- 4.6 J 120 98 18 18 14 30 ND mg/L 2.2 5 03/14/22 -- 4.1 J 3.6 J 12 35 27 14 30 ND mg/L 2.2 5 09/19/22 -- 4.0 J 4.6 J 110 28 32 15 29 ND m /L 0.20 0.50 03/20/23 -- 2.5 J 99 103 40 22 17 34 ND Nitrate as N mg/L 0.0056 0.1 09/24/09 10 3.9 J ND ND 0.055 J -- -- 0.017 J -- mg/L 0.021 0.1 03/23/10 10 -- -- -- -- -- -- -- -- mg/L 0.025 0.1 09/24/15 10 3.0 J 0.062 J ND 0.096 J 0.29 J ND 0.110 J ND mg/L 0.025 0.1 03/15/16 10 10 0.064 J ND ND 1.3 J ND ND ND mg/L 0.025 0.1 09/21/16 10 6.2 J 0.11 J ND 0.069 J 0.5 J ND 1.3 J ND mg/L 0.025 0.1 03/21/17 10 1.0 J 0.19 J ND 0.18 J 1.3 J ND 0.15 J ND mg/L 0.025 0.1 09/20/17 10 2.7 J 0.069 J ND 0.12 J 0.7 J ND 0.66 J ND mg/L 0.025 0.1 03/21/18 10 6.1 J 0.11 J ND 0.16 J 0.76 J ND 0.092 J ND mg/L 0.025 0.1 09/24/18 -- 2.9 0.16 0.083 J 0.16 0.29 0.051 J 2.0 ND mg/L 0.025 0.1 03/25/19 -- 1.0 ND ND 0.074 J 0.34 ND 0.067 J ND mg/L 0.025 0.1 09/18/19 -- 0.95 0.14 0.056 J 0.20 0.31 0.070 J 0.86 ND mg/L 0.041 0.1 03/16/20 -- 0.62 0.082 J 0.05 J 0.058 J 0.19 ND 0.095 J ND mg/L 0.200 0.5 09/23/20 -- 0.54 B 0.20 B 0.29 B 0.22 B 0.26 B 0.22 B 0.22 B 0.20 J mg/L 0.200 0.5 03/15/21 -- 0.34 ND 0.098 J 0.25 0.65 0.13 0.35 ND mg/L 0.041 0.1 09/20/21 -- 0.32 0.10 ND 0.12 0.25 0.15 0.92 ND mg/L 0.040 0.1 03/14/22 -- 0.19 0.19 ND 0.070 J 0.048 J 0.050 J 0.077 J ND mg/L 0.040 0.1 09/19/22 -- 0.23 0.060 J ND 0.096 J 0.32 0.17 0.62 ND m /L 0.025 0.5 03/20/23 -- ND ND ND ND 0.33 ND ND ND Nitrite as N mg/L 0.0056 0.1 09/24/09 1 0.0095 B 0.011 B 0.0062 B 0.013 B -- -- 0.0095 B 0.0086 J mg/L 0.0056 0.1 03/23/10 1 -- -- -- -- -- -- -- ND mg/L 0.017 0.1 09/24/15 1 ND ND ND ND ND ND ND ND mg/L 0.017 0.1 03/15/16 1 ND ND ND ND ND ND ND ND mg/L 0.017 0.1 03/21/17 1 ND ND ND ND ND ND ND ND mg/L 0.017 0.1 09/20/17 1 ND ND ND ND ND ND ND ND mg/L 0.017 0.1 03/21/18 1 ND ND ND ND ND ND ND ND mg/L 0.017 0.1 09/24/18 -- ND ND ND ND ND ND ND ND mg/L 0.017 0.1 03/25/19 -- ND 0.045 J 0.033 J ND ND ND 0.028 J ND mg/L 0.017 0.1 09/18/19 -- ND ND ND ND ND ND 0.045 J ND mg/L 0.017 0.1 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.008 0.1 09/23/20 -- ND ND ND ND ND ND 0.034 B 0.014 J mg/L 0.008 0.1 03/15/21 -- ND ND ND ND ND ND ND ND mg/L 0.017 0.1 09/20/21 -- ND ND ND ND ND ND ND ND mg/L 0.017 0.1 03/14/22 -- 0.023 B ND ND ND ND ND ND 0.017 J mg/L 0.017 0.1 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.017 0.1 03/20/23 -- ND ND ND ND ND ND ND ND Sulfate mg/L 0.078 5 09/24/09 250 3.2 J 7.3 J 4.8 J 6.3 J -- -- 2.6 J ND mg/L 0.12 5 03/23/10 250 -- -- -- -- -- -- -- ND mg/L 0.07 5 09/24/15 250 21 J ND 2.7 J 18 J 9.1 J 0.62 J 1.8 J ND mg/L 2.9 5 03/15/16 250 27 J 8.2 J 3.3 J 10 J 14 J ND 4.2 J ND mg/L 2.9 5 09/21/16 250 27 J ND 3.5 J 8 J 17 J ND 3.8 J ND mg/L 2.9 5 03/21/17 250 12 J ND 3.3 J 13 J 26 J ND 3.8 J ND mg/L 2.9 5 09/20/17 250 18 J ND ND 13 J 22 J ND 3.1 J ND mg/L 2.9 5 03/21/18 250 36 J 5.0 J ND 6.9 J 8.9 J ND 3.0 J ND mg/L 2.9 5 09/24/18 -- 38 ND ND 6.5 11 ND 3.4 J ND mg/L 2.9 5 03/25/19 -- 83 3.7 J ND 13 8.8 ND 3.3 J ND mg/L 2.9 5 09/18/19 -- 40 ND ND 13 24 ND 3.7 J ND mg/L 2.9 5 03/16/20 -- 30 ND ND 19 17 ND 3.7 J ND mg/L 2.9 5 09/23/20 -- 31 2.9 J 3.3 J 6.6 21 ND 3.4 J ND mg/L 2.9 5 03/15/21 -- 25 17 3.1 J 9.1 16 ND 4.5 J ND mg/L 2.9 5 09/20/21 -- 27 ND 3.4 J 4.7 J 17 ND 4.1 J ND mg/L 2.9 5 03/14/22 -- 20 5.2 4.0 J 7.4 12 ND 4.1 J ND mg/L 2.9 5 09/19/22 -- 22 ND 3.5 J 22 13 ND ND ND m /L 0.4 5 03/20/23 -- 31 ND 2.0 J 11 11 0.621 J 2.76 ND Biochemical Oxygen Demand mg/L 10 10 09/24/15 -- ND 3.9 ND ND ND ND ND ND mg/L 2 2 03/15/16 -- ND 4.3 ND ND ND ND ND ND mg/L 2 2 09/21/16 -- ND 4.6 ND ND ND ND ND ND mg/L 2 2 03/21/17 -- ND 6.4 ND ND ND ND ND ND mg/L 2 2 09/18/19 -- ND 6.2 ND 2.0 ND ND 2.1 ND mg/L 2 2 03/16/20 -- ND 2.9 2.5 ND ND ND ND ND mg/L 2 2 09/19/22 -- ND 2.0 ND ND ND ND ND ND m /L 2 2 03/20/23 -- ND 14 ND 3.8 B ND ND ND 0.834 Chemical Oxygen Demand mg/L 10 10 09/24/15 -- 15 140 28 130 38 19 25 ND mg/L 10 10 03/15/16 -- 10 39 48 95 22 ND ND ND mg/L 10 10 09/21/16 -- ND 110 37 93 18 12 14 ND mg/L 10 10 03/21/17 -- ND 110 26 110 45 20 22 ND mg/L 10 10 09/18/19 -- 11 130 32 68 ND ND 83 ND mg/L 10 10 03/16/20 -- ND 24 50 110 41 ND ND ND mg/L 10 10 09/19/22 -- 29 46 35 100 37 ND 31 ND m /L 10 10 03/20/23 -- 12 71 42 113 25 ND ND ND Total Alkalinity mg/L 8.3 15 09/24/09 -- ND 21 160 200 -- -- 150 ND mg/L 8.0 15 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 14 15 09/24/15 -- 30 670 220 400 250 120 120 ND mg/L 14 15 03/15/16 -- 17 190 300 460 72 94 81 ND mg/L 14 15 06/29/16 -- -- -- -- -- -- -- -- -- mg/L 14 15 09/21/16 -- 15 530 270 550 38 98 120 ND mg/L 14 15 12/19/16 -- -- -- -- -- -- -- -- -- mg/L 14 15 03/21/17 -- 19 470 250 350 83 110 140 ND mg/L 14 15 06/21/17 -- -- -- -- -- -- -- -- ND mg/L 14 15 09/20/17 -- ND 130 230 510 29 97 140 ND mg/L 14 15 12/19/17 -- -- -- -- -- -- -- -- ND mg/L 14 15 03/21/18 -- ND 91 230 520 18 100 130 ND mg/L 14 15 06/15/18 -- -- -- -- -- -- -- -- ND mg/L 14 15 09/24/18 -- ND 170 280 510 30 100 130 ND mg/L 14 15 12/20/18 -- -- -- -- -- -- -- -- -- mg/L 14 15 03/25/19 -- ND 79 230 320 ND 81 130 ND mg/L 14 15 09/18/19 -- 16 170 270 480 ND 78 160 ND mg/L 14 15 03/16/20 -- ND 130 270 510 57 90 150 ND mg/L 2 10 09/23/20 -- 14 100 239 476 40 61 149 ND mg/L 14 15 03/15/21 -- ND 130 260 590 32 71 160 ND mg/L 14 15 09/20/21 -- 15 260 250 560 36 77 170 ND mg/L 14 15 03/14/22 -- 14 75 250 630 98 96 170 ND mg/L 14 15 09/19/22 -- ND 130 240 660 33 95 180 ND m /L 2.2 5 03/20/23 -- 35 232 265 563 65 106 175 ND Total Organic Carbon mg/L 0.34 1 09/24/09 -- 0.64 J 10 3.4 18 -- -- 32 ND mg/L 0.34 1 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.34 1 09/24/15 -- 0.47 J 33 3.0 39 6.1 1.70 6.5 ND mg/L 0.34 1 03/15/16 -- 0.60 J 7.0 10 28 1.9 0.87 J 2.0 ND mg/L 0.34 1 09/21/16 -- 88 J 24 5.4 26 1.6 1.3 2.7 ND mg/L 0.34 1 03/21/17 -- 0.35 J 21 2.9 34 2.4 1.5 2.7 ND mg/L 0.34 1 09/18/19 -- 6.4 130 45 80 23 11 46 ND mg/L 0.34 1 03/16/20 -- 1.0 J 5.8 12 26 1.0 J 0.86 J 2.4 ND mg/L 0.34 1 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.34 1 09/20/21 -- -- -- -- -- -- -- -- -- mg/L 0.34 1 03/14/22 -- -- -- -- -- -- -- -- (re-sample) mg/L 0.34 1 11/09/22 -- ND 35 5.5 29 2.2 1.3 3.4 ND m /L 0.50 1 03/20/23 -- ND 22 4.9 28 2.4 1.0 2.9 ND July 2023 GL2014715721 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Background Detected Monitoring Monitored Natural Attenuation Monitoring Wells Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMWA S AMW-2S Old MW-2 Ethane mg/L 0.00040 0.0020 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.00040 0.0020 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.00047 0.0020 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.00047 0.0020 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 09/20/17 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 03/21/18 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 09/24/18 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 03/25/19 -- ND ND ND ND ND ND ND ND mg/L 0.0013 0.0020 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.0010 0.0020 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 09/23/20 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/15/21 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 09/20/21 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/14/22 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/19/22 -- ND ND ND ND ND ND ND ND (re -sample) mg/L 0.0051 0.0060 11/09/22 -- ND 1.4 ND ND ND ND ND ND m /L 0.00 0.0040 03/20/23 -- ND ND ND ND ND ND ND ND Ethene mg/L 0.00040 0.0020 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.00040 0.0020 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.00062 0.0030 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.00062 0.0030 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 09/20/17 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 03/21/18 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 09/24/18 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 03/25/19 -- ND ND ND ND ND ND ND ND mg/L 0.0015 0.0030 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.0010 0.0030 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 09/23/20 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/15/21 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 09/20/21 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/14/22 -- ND ND ND ND ND ND ND ND mg/L 0.0051 0.0060 03/19/22 -- ND ND ND ND ND ND ND ND (re -sample) mg/L 0.0051 0.0060 11/09/22 -- ND ND ND ND ND ND ND ND m /L 0.0016 0.0030 03/20/23 -- ND ND ND ND ND ND ND ND Methane mg/L 0.00020 0.0010 09/24/09 -- 0.002 0.640 0.654 1.45 -- -- 3.91 ND mg/L 0.00020 0.0010 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.00044 0.0010 09/24/15 -- ND 4.14 0.078 0.165 0.563 0.16 0.003 ND mg/L 0.00044 0.0010 03/15/16 -- 0.000516 J 8.5 0.418 0.150 0.0700 0.0910 0.021 ND mg/L 0.00044 0.0010 09/21/16 -- ND 3.71 0.0819 0.17 0.0167 0.093 0.253 ND mg/L 0.00044 0.0010 03/21/17 -- ND 2.1 0.128 0.136 0.122 0.246 0.061 ND mg/L 0.00044 0.0010 09/20/17 -- 0.000995 J 2.28 0.126 0.0737 0.057 0.143 0.0457 ND mg/L 0.00044 0.0010 03/21/18 -- 0.025 2.83 0.0843 0.190 0.0152 0.117 0.0392 ND mg/L 0.00045 0.0010 09/24/18 -- 0.028 3.16 0.199 0.118 0.0240 0.168 0.0540 ND mg/L 0.00045 0.0010 03/25/19 -- 0.002 2.82 0.282 0.190 0.00156 ND 0.139 ND mg/L 0.00045 0.0010 09/18/19 -- 0.00156 1.40 0.136 0.231 0.00526 0.0565 0.0539 ND mg/L 0.00045 0.0010 03/16/20 -- ND 3.27 0.157 0.0371 0.0146 0.0165 0.0321 ND mg/L 0.0040 0.0050 09/23/20 -- ND 3.04 0.116 0.2360 0.0304 0.0055 0.0536 ND mg/L 0.0040 0.0050 03/15/21 -- ND 0.298 0.0514 0.0113 0.0345 0.00845 ND ND mg/L 0.0040 0.0050 09/20/21 -- ND 6.39 0.115 0.491 0.109 ND 0.100 ND mg/L 0.0040 0.0050 03/14/22 -- 0.013 2.43 0.250 0.0691 0.580 ND 0.0156 ND (re -sample) mg/L 0.0040 0.0050 11/09/22 -- 0.038 11 0.200 0.260 0.080 0.077 0.580 ND m /L 0.0012 0.0020 03/20/23 -- 0.005 8.32 0.273 0.223 0.257 0.347 0.923 ND Carbon dioxide mg/L 0.780 2.50 09/24/09 -- 60.7 105 689 641 -- -- 181 ND mg/L 0.780 2.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.210 2.50 09/24/15 -- 92.3 927 649 861 487 293 469 ND mg/L 0.210 2.50 03/15/16 -- 117 841 795 790 249 220 338 ND mg/L 0.660 2.50 09/21/16 -- 74.0 731 542 699 111 155 413 ND mg/L 0.660 2.50 03/21/17 -- 50.5 376 603 949 260 213 184 ND mg/L 0.660 2.50 09/20/17 -- 67.4 176 643 793 179 186 323 ND mg/L 0.660 2.50 03/21/18 -- 88.9 257 646 706 147 205 212 ND mg/L 1.620 5.25 09/24/18 -- 90.8 523 558 521 166 200 300 ND mg/L 0.770 2.50 03/25/19 -- 165 321 480 583 171 180 290 ND mg/L 0.770 2.50 09/18/19 -- 74.1 482 517 465 209 170 1110 ND mg/L 1.80 2.50 03/16/20 -- 33.3 364 408 411 201 89.0 118 ND mg/L 2.07 2.50 09/23/20 -- 6.77 200 291 306 156 75.6 119 ND mg/L 2.07 2.50 03/15/21 -- 34.9 19.5 33.8 22.5 187 61.5 73.2 ND mg/L 2.07 2.50 09/20/21 -- 49.8 441 411 391 200 ND 438 ND mg/L 2.07 2.50 03/17/22 -- 17.9 193 309 301 425 7.42 299 ND (re -sample) mg/L 2.07 2.50 11/09/22 -- 44.0 600 530 450 270 160 450 ND m /L 5.00 10.00 03/20/23 -- 62.1 394 387 407 297 147 744 ND pH (field) S.U. -- -- 09/24/09 -- 5.58 5.32 5.60 5.72 -- -- 5.93 -- S.U. -- -- 03/23/10 -- 5.58 Dry 5.44 6.01 -- -- -- S. U. -- -- 09/24/15 -- 5.63 6.19 5.95 5.96 6.03 5.94 5.71 -- S.U. -- -- 03/15/16 -- 5.15 5.43 5.98 6.08 5.48 5.73 5.35 -- S.U. -- -- 06/29/16 -- -- -- -- -- -- -- -- S. U. -- -- 09/21/16 -- 4.74 6.21 6.10 6.12 5.67 6.28 5.68 -- S.U. -- -- 12/19/16 -- -- 6.28 -- -- -- -- -- S. U. -- -- 03/21/17 -- 5.20 6.03 5.73 5.95 5.55 5.67 5.97 -- S.U. -- -- 06/21/17 -- -- 5.64 -- -- -- -- -- S. U. -- -- 09/20/17 -- 5.78 5.58 5.96 6.17 5.37 6.00 5.43 -- S.U. -- -- 12/19/17 -- -- 5.99 -- -- -- -- -- S. U. -- -- 03/21/18 -- 5.63 5.90 6.05 6.84 5.94 6.52 6.34 -- S.U. -- -- 06/15/18 -- -- -- -- -- -- -- -- S. U. -- -- 09/25/18 -- 5.60 5.80 5.95 6.32 5.60 6.03 5.99 -- S.U. -- -- 12/20/18 -- -- -- -- -- -- -- -- S. U. -- -- 03/25/19 -- 5.63 5.98 6.01 6.04 5.28 6.06 6.17 -- S.U. -- -- 09/18/19 -- 4.77 6.03 5.79 6.35 4.80 6.23 5.94 -- S.U. -- -- 03/16/20 -- 5.41 5.85 5.68 6.28 5.45 6.21 6.32 -- S.U. -- -- 09/23/20 -- 5.66 5.96 5.97 6.41 5.22 5.75 6.01 -- S.U. -- -- 03/15/21 -- 5.36 5.69 5.86 6.28 5.29 6.13 6.29 -- S.U. -- -- 09/20/21 -- 5.65 6.12 6.15 6.66 5.19 6.28 5.74 -- S.U. -- -- 03/14/22 -- 5.59 5.69 5.91 6.36 5.28 6.05 6.09 -- S.U. -- -- 09/19/22 -- 5.19 6.20 5.81 6.46 5.03 6.00 5.89 -- (re-sample) S.U. -- -- 11/09/22 -- 5.56 6.13 5.86 6.41 5.24 6.01 5.79 -- S.U. -- -- 03/20/23 -- 5.79 6.25 6.03 6.44 5.6 6.24 5.79 -- Specific Conductivity (field) us/cm -- -- 09/24/09 -- 101 125 340 661 -- -- 374 -- us/cm -- -- 03/23/10 -- 148 Dry 339 884 -- -- -- us/cm -- -- 09/24/15 -- 128 1876 562 911 558 262 307 -- us/cm -- -- 03/15/16 -- 228 389 790 967 264 219 236 -- us/cm -- -- 06/29/16 -- -- -- -- -- -- -- -- us/cm -- -- 09/21/16 -- 180 1640 659 1140 192 200 306 -- us/cm -- -- 12/19/16 -- -- 1352 -- -- -- -- -- us/cm -- -- 03/21/17 -- 100 1342 601 960 273 240 331 -- us/cm -- -- 06/21/17 -- -- 658 -- -- -- -- -- us/cm -- -- 09/20/17 -- 122 360 580 1141 144 235 422 -- us/cm -- -- 12/19/17 -- -- 542 -- -- -- -- -- us/cm -- -- 03/21/18 -- 207 242 582 1124 299 246 336 -- us/cm -- -- 06/15/18 -- -- -- -- -- -- -- -- us/cm -- -- 09/25/18 -- 176 540 737 1047 239 224 355 -- us/cm -- -- 12/20/18 -- -- -- -- -- -- -- -- us/cm -- -- 03/25/19 -- 270 237 806 728 268 215 346 -- us/cm -- -- 09/18/19 -- 168 139 670 1126 160 202 402 -- us/cm -- -- 03/16/20 -- 159 337 998 1203 378 204 499 -- us/cm -- -- 09/23/20 -- 133 263 756 1044 245 196 413 -- us/cm -- -- 03/15/21 -- 140 961 849 1357 203 198 473 -- us/cm -- -- 09/20/21 -- 112 622 710 1131 163 187 396 -- us/cm -- -- 03/14/22 -- 90 164 709 1148 274 205 393 -- us/cm -- -- 09/19/22 -- 93 267 696 1079 161 215 401 -- (re-sample) uS/cm -- -- 11/09/22 -- 85 1526 696 1079 167 204 384 -- us/cm -- -- 03/20/23 -- 103 799 793 1115 186 227 417 -- Temperature (field) Celsius -- -- 09/24/09 -- 16.7 20.0 19.9 22.8 -- -- 21.1 -- Celsius -- -- 03/23/10 -- 13.2 Dry 15.0 11.8 -- -- -- Celsius -- -- 09/24/15 -- 15.0 16.5 17.6 17.1 16.5 14.7 15.7 -- Celsius -- -- 03/15/16 -- 15.3 15.8 15.9 17.3 16.2 15.0 13.9 -- Celsius -- -- 06/29/16 -- -- -- -- -- -- -- -- Celsius -- -- 09/21/16 -- 15.0 17.9 17.7 17.8 16.9 16.3 21.6 -- Celsius -- -- 12/19/16 -- -- 13.8 -- -- -- -- -- -- Celcius -- -- 03/21/17 -- 16.1 14.0 16.5 15.6 15.0 13.0 14.3 -- Celcius -- -- 06/21/17 -- -- 18.1 -- -- -- -- -- -- Celcius -- -- 09/20/17 -- 15.2 21.6 18.0 18.0 18.3 16.5 18.0 -- Celsius -- -- 12/19/17 -- -- 16.8 -- -- -- -- -- Celsius -- -- 03/21/18 -- 11.9 11.7 15.6 15.1 14.0 11.5 12.7 -- Celcius -- -- 06/15/18 -- -- -- -- -- -- -- -- -- Celcius -- -- 09/25/18 -- 16.2 18.5 17.7 18.3 17.8 15.8 17.3 -- Celcius -- -- 12/20/18 -- -- -- -- -- -- -- -- Celsius -- -- 03/25/19 -- 14.0 13.1 16.3 16.0 13.6 11.9 12.8 -- Celsius -- -- 09/18/19 -- 15.5 18.1 17.4 17.7 17.1 15.3 17.0 -- Celsius -- -- 03/16/20 -- 13.3 12.9 16.0 15.3 13.6 12.1 12.7 -- Celsius -- -- 09/23/20 -- 14.5 19.3 18.0 17.9 17.9 15.6 17.7 -- Celsius -- -- 03/15/21 -- 13.7 9.7 12.4 15.9 11.1 9.1 13.1 -- Celsius -- -- 09/20/21 -- 16.6 19.3 17.6 17.6 16.9 15.4 16.9 -- Celsius -- -- 03/14/22 -- 13.9 11.9 16.9 16.2 15.3 12.8 13.8 -- Celsius -- -- 09/19/22 -- 16.5 19.4 19.5 18.4 18.8 16.3 17.9 -- (re-sample) Celsius -- -- 11/09/22 -- 15.7 16.5 16.8 16.5 16.3 14.8 15.7 -- Celsius -- -- 03/20/23 -- 12.9 15.9 15.1 15.4 14.6 12.1 12.0 -- July 2023 GL2014715721 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Background Detected Monitoring Monitored Natural Attenuation Monitoring Wells Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMWA S AMW-2S Old MW-2 Turbidity (field) NTU -- -- 09/24/09 -- 39.1 11.6 23.7 97.6 -- -- 75.8 -- NTU -- -- 03/23/10 -- 73.8 Dry 17.0 33.8 -- -- -- NTU -- -- 09/24/15 -- 21.8 3.77 21.9 3.72 26.3 9.15 6.82 -- NTU -- -- 03/15/16 -- 3.21 8.53 1.77 25.4 26.5 17.8 1.43 -- NTU -- -- 06/29/16 -- -- -- -- -- -- -- -- NTU -- -- 09/21/16 -- 8.72 5.92 1.97 24.5 11.3 18.6 2.91 -- NTU -- -- 12/19/16 -- 12.6 -- -- -- -- -- NTU -- -- 03/21/17 -- 11.1 2.29 0.64 20.3 7.68 12.5 2.17 -- NTU -- -- 06/21/17 -- -- 9.60 -- -- -- -- -- NTU -- -- 09/20/17 -- 6.77 4.17 0.17 8.13 2.89 1.49 5.02 -- NTU -- -- 12/19/17 -- -- 2.78 -- -- -- -- -- NTU -- -- 03/21/18 -- 9.7 2.88 0.36 8.76 7.56 5.51 2.03 -- N T U -- -- 06/15/18 -- -- -- -- -- -- -- -- NTU -- -- 09/25/18 -- 8.32 8.73 0.53 5.10 4.64 1.67 9.28 -- NTU -- -- 12/20/18 -- -- -- -- -- -- -- -- NTU -- -- 03/25/19 -- 2.92 2.95 4.78 5.68 4.16 1.21 1.79 -- NTU -- -- 09/18/19 -- 8.5 3.40 2.84 8.00 0.02 1.21 1.78 -- NTU -- -- 03/16/20 -- 1.21 1.50 4.51 7.18 3.92 0.45 2.31 -- NTU -- -- 09/23/20 -- 2.82 9.15 1.18 9.78 1.43 0.59 4.94 -- NTU -- -- 03/15/21 -- 4.31 9.76 2.49 2.88 5.31 1.60 1.88 -- NTU -- -- 09/20/21 -- 47.4 6.54 2.13 4.78 4.01 1.19 18.8 -- NTU -- -- 03/14/22 -- 54.7 9.34 3.99 7.26 4.00 1.01 2.10 -- NTU -- -- 09/19/22 -- 3.71 5.90 1.08 1.76 2.96 0.25 2.10 -- (re-sample) NTU -- -- 11/09/22 -- 2.83 4.78 2.84 5.48 3.44 3.18 3.82 -- NTU -- -- 03/20/23 -- 2.27 109 3.43 2.65 0.97 1.21 2.10 -- Oxidation Reduction Potential (field) my -- -- 09/22/09 -- 179 -30.3 101 133 -- -- -132 -- mv -- -- 03/23/10 -- -- -- -- -- -- -- -- -- mv -- -- 09/24/15 -- 148 -26.1 90.7 103 18.8 69.5 61.2 -- mv -- -- 03/15/16 -- 253 -32.9 52.4 -16.8 129 125 180 -- mv -- -- 06/29/16 -- -- -- -- -- -- -- -- -- mv -- -- 09/21/16 -- 318 -43.2 43.1 -26.6 121.7 60.9 103 -- mv -- -- 12/19/16 -- -- -47.1 -- -- -- -- -- -- mv -- -- 03/21/17 -- 262.8 -38.6 378.0 75.9 133.0 5.67 125.8 -- mv -- -- 06/21/17 -- -- -32.0 -- -- -- -- -- -- mv -- -- 09/20/17 -- 89.0 6.8 103.2 16.5 215.4 128.1 132.3 -- mv -- -- 12/19/17 -- -- 16.6 -- -- -- -- -- -- mv -- -- 03/21/18 -- 359.3 75.9 337.5 -19.50 115.6 70.40 312.4 -- mv -- -- 06/15/18 -- -- -- -- -- -- -- -- -- mv -- -- 09/25/18 -- 125 -55.2 55.6 5.2 67.4 3.3 93.5 -- mv -- -- 12/20/18 -- -- -- -- -- -- -- -- -- mv -- -- 03/25/19 -- 195.5 12.2 31.5 60.0 214.4 176.5 308.0 -- mv -- -- 09/18/19 -- 192.4 -54.8 51.2 -33.5 150.0 93.9 47.0 -- mv -- -- 03/16/20 -- 276.4 -169.3 241.4 153.8 139.4 125.7 231.4 -- mv -- -- 09/23/20 -- 122.4 -75.5 41.4 -43.0 28.7 2.4 -27.6 -- mv -- -- 03/15/21 -- 223.7 24.9 91.7 -7.9 188.9 176.3 107.7 -- mv -- -- 09/20/21 -- 197.7 -44.2 122.4 -66.6 242.8 192.4 94.3 -- mv -- -- 03/14/22 -- 213.8 152.6 141.7 -27.1 112.1 233.5 69.9 -- mv -- -- 09/19/22 -- 122.5 -102.1 134.7 -56.6 222.9 88.6 -58.9 -- (re-sample) my -- -- 11/09/22 -- 148.1 -6.1 142.5 -54.1 169.0 141.3 57.5 -- mv -- -- 03/20/23 -- 40.7 27.3 115.1 -82.7 2.5 -11.3 48.1 -- Dissolved Oxygen (field) mg/L -- -- 09/22/09 -- 7.85 1.49 1.18 1.31 -- -- 1.07 -- mg/L -- -- 03/23/10 -- -- -- -- -- -- -- -- -- mg/L -- -- 09/24/15 -- 7.30 1.70 1.08 0.78 4.80 0.64 0.81 -- mg/L -- -- 03/15/16 -- 8.78 0.14 0.46 0.12 0.35 0.11 3.64 -- mg/L -- -- 06/29/16 -- -- -- -- -- -- -- -- -- mg/L -- -- 09/21/16 -- 7.41 0.39 1.59 1.09 2.45 0.80 3.26 -- mg/L -- -- 12/19/16 -- -- 1.85 -- -- -- -- -- -- mg/L -- -- 03/21/17 -- 9.45 0.98 0.30 1.39 0.40 1.41 3.89 -- mg/L -- -- 06/21/17 -- -- 0.27 -- -- -- -- -- -- mg/L -- -- 09/20/17 -- 2.21 1.39 0.72 1.07 4.48 0.39 2.41 -- mg/L -- -- 12/19/17 -- -- 0.92 -- -- -- -- -- -- mg/L -- -- 03/21/18 -- 6.59 0.27 0.49 1.04 0.15 0.25 3.75 -- mg/L -- -- 06/15/18 -- -- -- -- -- -- -- -- -- mg/L -- -- 09/25/18 -- 7.37 0.15 0.18 0.59 3.30 2.25 3.40 -- mg/L -- -- 12/20/18 -- -- -- -- -- -- -- -- -- mg/L -- -- 03/25/19 -- 8.16 0.11 0.20 0.08 2.42 0.43 4.53 -- mg/L -- -- 09/18/19 -- 7.28 3.66 1.47 0.71 1.00 1.44 1.81 -- mg/L -- -- 03/16/20 -- 7.21 0.21 0.49 0.30 2.91 0.81 3.68 -- mg/L -- -- 09/23/20 -- 8.30 0.12 0.70 0.05 2.47 1.35 0.33 -- mg/L -- -- 03/15/21 -- 7.81 5.30 6.37 0.76 7.15 8.79 4.53 -- mg/L -- -- 09/20/21 -- 6.80 0.29 1.05 0.85 1.30 0.82 1.45 -- mg/L -- -- 03/14/22 -- 7.26 2.19 1.06 0.28 0.16 0.61 3.62 -- mg/L -- -- 09/19/22 -- 7.69 0.20 0.14 0.31 3.09 0.26 0.41 -- (re-sample) mg/L -- -- 11/09/22 -- 8.37 0.19 0.17 0.18 1.23 0.62 0.30 -- m /L -- -- 03/20/23 -- 9.50 3.59 0.38 1.19 4.47 0.56 3.26 -- iso-Hexanoic Acid mg/L 0.51 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.41 1.00 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.44 0.50 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/15/16 -- ND ND 0.990 ND ND 0.610 ND ND mg/L 0.44 0.50 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/21/17 -- ND 1.80 ND ND ND ND ND ND mg/L 0.44 0.50 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.44 0.50 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.44 0.50 03/20/23 -- ND ND ND ND ND ND ND ND iso-Pentanoic Acid mg/L 0.13 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.13 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.18 0.50 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.18 0.20 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.18 0.20 03/20/23 -- 3.6 J 33.2 12.5 ND 9.0 2.55 J 5.19 ND Pentanoic Acid mg/L 0.18 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.18 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.11 0.20 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.11 0.20 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.11 0.20 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.11 0.20 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.14 0.20 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.14 0.20 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.14 0.20 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.14 0.20 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.14 0.50 03/20/23 -- ND ND ND ND ND ND ND ND Hexanoic Acid mg/L 0.32 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.32 1.00 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.26 0.50 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.26 0.50 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.26 0.50 03/20/23 -- ND ND ND ND ND ND ND ND Pyruvic Acid mg/L 0.020 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.020 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.012 0.070 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.012 0.070 03/15/16 -- ND ND ND ND 0.013 J 0.012 J ND ND mg/L 0.012 0.070 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.012 0.070 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.021 0.070 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.021 0.070 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.021 0.070 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.021 0.070 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.021 0.070 03/20/23 -- ND ND ND ND ND ND ND ND Lactic Acid/HIBA mg/L 0.088 0.50 09/24/09 -- ND ND ND ND -- -- ND ND (2-Hydroxyisobutyric Acid) mg/L 0.088 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.095 0.14 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.095 0.14 03/15/16 -- ND 5.7 9.9 ND 0.59 0.56 ND ND mg/L 0.095 0.14 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.095 0.14 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.13 0.14 09/18/19 -- ND 23 3.8 ND ND ND ND ND mg/L 0.13 0.14 03/16/20 -- ND ND 15 ND 0.16 0.28 ND ND mg/L 0.13 0.14 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.13 0.14 09/19/22 -- ND ND ND ND ND ND ND ND m /L 0.13 0.50 03/20/23 -- ND 19.9 12.5 ND ND 3.04 J ND ND Acetic Acid mg/L 0.071 0.50 09/24/09 -- 0.43 J ND 0.39 J ND -- -- ND ND mg/L 0.071 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.16 0.20 09/24/15 -- ND 18 ND ND ND ND ND ND mg/L 0.16 0.20 03/15/16 -- ND ND 7.2 ND 0.38 ND ND ND mg/L 0.16 0.20 09/21/16 -- ND 18 3.4 ND ND ND ND ND mg/L 0.16 0.20 03/21/17 -- ND 15 ND ND 0.33 0.49 ND ND mg/L 0.18 0.20 09/18/19 -- ND 18 1.4 ND ND ND ND ND mg/L 0.18 0.20 03/16/20 -- ND 1.1 4.2 ND ND ND 0.29 ND mg/L 0.18 0.20 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.18 0.20 09/19/22 -- ND ND ND ND ND ND 5.2 ND m /L 0.18 0.50 03/20/23 -- 3.7 J 25.1 7.8 ND ND ND 6.6 ND July 2023 GL2014715721 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Background Detected Monitoring Monitored Natural Attenuation Monitoring Wells Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1 S AMW-2S Old MW-2 Propionic Acid mg/L 0.054 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.054 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.065 0.10 09/24/15 -- ND 14.0 ND ND 2.40 ND ND ND mg/L 0.065 0.10 03/15/16 -- ND 2.30 3.50 ND 0.42 0.14 0.11 ND mg/L 0.065 0.10 09/21/16 -- ND 12.0 1.50 ND ND ND ND ND mg/L 0.065 0.10 03/21/17 -- ND 8.40 ND ND 0.12 ND ND ND mg/L 0.065 0.10 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.065 0.10 03/16/20 -- ND ND 7.40 ND ND ND ND ND mg/L 0.065 0.10 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.065 0.10 09/19/22 -- ND ND ND ND ND ND ND ND mg/L 0.065 0.50 03/20/23 -- ND ND ND ND ND ND ND ND Butyric Acid mg/L 0.16 0.50 09/24/09 -- ND ND ND ND -- -- ND ND mg/L 0.16 0.50 03/23/10 -- -- -- -- -- -- -- -- ND mg/L 0.089 0.10 09/24/15 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 03/15/16 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 03/21/17 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 09/18/19 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 03/16/20 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 03/15/21 -- -- -- -- -- -- -- -- -- mg/L 0.089 0.10 09/19/22 -- ND ND ND ND ND ND ND ND mg/L 0.089 0.10 03/20/23 -- ND ND ND ND ND ND ND ND Hydrogen nM -- 0.60 09/24/09 -- 1.3 1.9 1.3 1.4 -- -- 1.3 -- nM -- 0.60 03/23/10 -- -- -- -- -- -- -- -- nM 0.088 0.60 09/24/15 -- 21 21 25 2.6 27 4.5 21 -- nM 0.088 0.60 03/15/16 -- 3.1 3.2 2.7 4.2 3.4 3.4 3.2 -- nM 0.075 0.60 09/21/16 -- 2.5 2.6 2.4 2.8 2.4 2.9 2.4 -- nM 0.075 0.60 03/21/17 -- 2.3 2.5 2.4 2.2 2.9 2.4 2.8 -- nM 0.16 0.60 09/20/17 -- 2.6 3.2 2.5 2.6 2.5 2.7 3.1 -- nM 0.16 0.60 03/21/18 -- 2.2 1.7 2.2 1.6 1.9 1.6 1.8 ND nM 0.65 1.00 09/24/18 -- 2.7 2.1 2.8 3.1 2.4 3.1 2.7 ND nM 0.75 1.00 03/25/19 -- ND 1.6 3.1 15 2.4 1.5 1.3 -- nM 0.75 1.00 09/18/19 -- 24 120 64 84 98 170 110 -- nM 0.75 1.00 03/16/20 -- 2.4 4.3 4.9 5.6 6.4 4.0 2.9 -- nM 0.49 1.90 09/23/20 -- 0.71 J 0.71 J 0.66 J 1.0 J 1.0 J 0.62 J 0.60 J -- nM 0.49 1.90 03/15/21 -- 0.62 J 0.67 J 0.85 J 43 0.72 J 0.78 J 0.53 J -- nM 0.49 1.90 09/20/21 -- 2.8 2.0 2.6 2.4 3.5 J 2.0 2.3 -- nM 0.49 1.90 03/14/22 -- 0.73 J 0.56 J 0.86 J 0.80 J 1.1 J 0.70 J 0.70 J -- nM 0.49 1.90 09/19/22 -- 0.53 J 0.52 J 0.74 J ND J 0.78 J 1.1 J 1.7 J -- (field) mg/L -- -- 09/24/09 -- ND 0.8 2.3 ND -- -- 2.9 -- (field) mg/L -- -- 03/23/10 -- -- -- -- -- (field) mg/L -- -- 09/24/15 -- ND 3.5 ND ND 3.6 ND 1.0 -- (field) mg/L -- -- 03/15/16 -- ND 2.6 ND 4.2 1.0 ND ND -- mg/L 0.046 0.5 09/21/16 -- ND 44 5.3 16 0.79 ND 0.94 -- (field) mg/L -- -- 09/21/16 -- ND ND ND ND ND ND ND ND mg/L 0.046 0.5 03/21/17 -- ND 45 0.65 ND 0.87 ND ND -- mg/L 0.031 0.5 09/20/17 -- ND 11 ND 12 0.65 ND ND -- mg/L 0.031 0.5 03/21/18 -- ND 11 1 17 ND ND ND ND mg/L 0.040 0.5 09/24/18 -- ND 22 9.8 12 1.1 ND ND ND mg/L 0.120 0.5 03/25/19 -- ND 17 19 13 ND ND ND -- mg/L 0.120 0.5 09/18/19 -- ND 49 11 26 ND ND 1.5 -- mg/L 0.120 0.5 03/16/20 -- ND 13 20 28 1.1 ND ND -- mg/L 0.015 0.05 09/23/20 -- 0.04 J 15 6.2 26 1.5 ND 1.3 -- mg/L 0.015 0.05 03/15/21 -- 0.02 J 28 24 18 1.6 ND ND -- mg/L 0.015 0.05 09/20/21 -- ND 31 10 34 2.6 ND ND -- mg/L 0.014 0.05 03/14/22 -- ND 1.6 0.87 J 23 4.6 ND 0.06 -- m /L 0.014 0.05 09/19/22 -- ND 0.45 0.02 J 14 0.09 ND 0.11 -- July 2023 GL2014715721 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL pQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-11D AMW-2D MW-2 BR-3 Benzene ug/L 12/05/94 5.0 5.0 5 ND 11 ND ND -- -- -- -- -- -- -- ND -- NC 2L = 1 ug/L ug/L 02/14/95 5.0 5.0 5 ND 11 ND ND -- -- -- -- -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 5.0 5.0 5 ND 8 ND ND -- -- -- -- -- -- -- ND -- ug/L 10/30/95 5.0 5.0 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/08/96 5.0 5.0 5 ND 9 3.9 ND -- -- -- -- -- -- -- ND -- ug/L 10/24/96 5.0 5.0 5 ND -- 5 ND -- -- -- -- -- -- -- ND -- ug/L 04/15/97 5.0 5.0 5 ND -- 6.9 ND -- -- -- -- -- -- -- ND -- ug/L 10/29/97 -- -- 5 ND 5 6 ND -- -- -- -- -- -- -- ND -- ug/L 05/14/98 -- -- 5 ND 8 6 ND -- -- -- -- -- -- -- ND -- ug/L 10/11/98 -- -- 5 ND ND 7 ND -- -- -- -- -- -- -- ND -- ug/L 06/04/99 -- -- 5 ND 8 6 ND -- -- -- -- -- -- -- ND -- ug/L 10/29/99 -- -- 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/20/00 -- -- 5 ND ND ND ND ND -- -- -- -- -- -- ND -- ug/L 11/07/00 -- -- 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 02/27/01 -- -- 5 -- -- -- -- -- -- ND -- -- -- ND ND -- ug/L 05/15/01 -- -- 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/16/01 -- -- 5 ND ND ND ND -- -- -- -- ND -- -- ND -- ug/L 04/24/02 -- -- 5 ND 6 ND ND ND -- -- -- ND -- -- ND -- ug/L 10/01/02 -- -- 5 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 04/09/03 -- -- 5 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/20/03 -- -- 5 ND 7 ND ND ND -- -- -- ND -- -- ND -- ug/L 03/24/04 5.0 5.0 5 ND 6 ND ND ND -- -- -- ND -- -- ND -- ug/L 10/27/04 5.0 5.0 5 ND 7.19 ND ND ND -- -- -- ND -- -- ND -- ug/L 05/25/05 5.0 5.0 5 ND ND ND -- ND -- -- -- ND -- -- ND -- ug/L 10/04/05 5.0 5.0 5 ND 7.61 ND ND ND -- -- -- ND -- -- ND -- ug/L 04/25/06 5.0 5.0 5 ND 6.23 ND ND ND -- -- -- ND -- -- ND -- ug/L 10/04/06 5.0 5.0 5 ND 6.8 ND ND ND -- -- -- ND -- -- ND ND ug/L 03/21/07 5.0 5.0 5 ND 1.36 2.48 3.55 0.44 J -- -- -- 1.52 -- -- ND ND ug/L 10/02/07 5.0 5.0 5 ND 5.47 1.70 4.99 1.68 -- -- -- 1.55 -- -- ND ND ug/L 04/03/08 5.0 5.0 5 ND 0.37 J 1.57 5.82 0.98 J 1.28 0.880 J -- 1.48 ND -- ND ND ug/L 10/29/08 5.0 5.0 5 ND 3.08 1.51 6.23 2.13 1.25 -- -- 1.49 ND -- ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND 0.64 J ND ND -- -- ND ND -- ND ND ug/L 09/22/09 0.20 1.0 1 ND ND 1.4 4.2 0.44 J 1.2 ND -- 1.3 ND -- ND ND ug/L 03/22/10 0.05 1.0 1 ND Dry 1.4 ND ND 0.75 J -- -- 1.1 ND 0.91 J ND ND ug/L 09/23/10 0.20 1.0 1 ND 0.98 J ND ND ND ND -- -- ND ND -- ND ND ug/L 03/16/11 0.68 1.0 1 ND ND 1.6 ND ND 0.96 J -- -- 1.2 ND -- ND ND ug/L 09/21/11 0.68 1.0 1 ND 4.6 1.4 0.85 J ND 0.82 J -- -- 1.2 ND -- ND ND ug/L 03/21/12 0.15 1.0 1 ND ND 1.1 0.65 J 0.73 J 0.82 J -- -- 0.95 J ND -- ND ND ug/L 09/20/12 0.15 1.0 1 ND ND 0.94 J ND ND ND -- -- ND ND -- ND ND ug/L 03/20/13 0.15 1.0 1 ND ND 1.5 3.0 ND 1.2 -- -- 1.2 ND -- ND ND ug/L 09/18/13 0.15 1.0 1 ND 2.9 1.7 0.89 J 0.56 J 0.86 J -- -- 1.1 ND -- ND ND ug/L 03/27/14 0.15 1.0 1 ND ND 1.6 ND ND ND -- -- ND ND -- ND ND ug/L 09/18/14 0.15 1.0 1 ND 4.6 1.1 ND ND 0.58 J -- -- 1.1 ND -- ND ND ug/L 03/18/15 0.15 1.0 1 ND ND 1.3 ND ND 0.60 J -- -- 1.2 ND -- ND ND ug/L 09/23/15 0.15 1.0 1 ND 3.7 1.3 ND 1.1 0.66 J ND -- 0.83 J ND -- ND ND ug/L 03/15/16 0.15 1.0 1 ND 1.2 2.4 ND ND 0.45 J ND 0.91 J 1.2 ND 0.60 J ND ND ug/L 06/29/16 0.15 1.0 1 -- -- -- -- -- -- -- ND 0.91 J ND 0.46 J ND ND ug/L 09/21/16 0.15 1.0 1 ND 3.5 1.8 ND ND 0.41 J ND ND 1.1 ND -- ND ND ug/L 12/19/16 0.15 1.0 1 -- -- -- -- -- -- -- ND 0.68 J ND 0.40 J ND ND ug/L 03/21/17 0.15 1.0 1 ND 2.6 1.8 ND ND 0.64 J ND ND 0.97 J ND -- ND ND ug/L 06/21/17 0.15 1.0 1 -- -- -- -- -- -- -- ND 0.72 J ND 0.53 J ND ND ug/L 09/20/17 0.15 1.0 1 ND ND 1.6 ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.15 1.0 1 -- -- -- -- -- -- -- ND 0.80 J ND 0.46 J ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/15/18 0.15 1.0 1 -- -- -- -- -- -- -- ND 0.60 J ND ND ND ND ug/L 09/24/18 0.15 1.0 -- ND ND ND ND ND ND ND ND 0.71 J ND -- ND ND ug/L 12/20/18 0.15 1.0 -- -- -- -- -- -- -- -- ND 0.71 J ND ND ND ND ug/L 03/26/19 0.15 1.0 -- ND ND 2.5 ND ND ND ND ND 0.47 J ND -- ND ND ug/L 09/18/19 0.15 1.0 -- ND 4.3 ND ND ND ND ND -- 0.68 J ND -- ND ND ug/L 03/16/20 0.15 1.0 -- ND 0.96 J 1.1 ND ND ND ND -- ND ND -- ND ND ug/L 09/23/20 0.15 1.0 -- ND 0.53 J 1.3 ND ND ND ND -- ND ND -- ND ND ug/L 03/15/21 0.15 1.0 -- ND 0.65 J 2.1 ND ND ND ND -- 0.82 J ND -- ND ND ug/L 09/20/21 0.15 1.0 -- ND 2.3 1.4 ND ND ND ND -- 0.94 J ND -- ND ND ug/L 03/14/22 0.15 1.0 -- ND ND 0.93 J ND 1.0 ND ND -- 0.60 J ND -- ND ND ug/L 09/19/22 0.15 1.0 -- ND 0.50 J 1.3 ND ND ND ND -- 0.66 J ND -- ND ND ug/L 03/20/23 0.15 1.0 -- ND 1.64 J 0.99 J ND 0.23 J 0.19 J ND -- 1.1 ND -- ND ND July 2023 GL2014715721 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL pQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-11D AMW-2D MW-2 BR-3 1,4-Dichlorobenzene ug/L 12/05/94 5.0 5.0 5 ND ND ND ND -- -- -- -- -- -- -- ND -- NC 2L = 6 ug/L ug/L 02/14/95 5.0 5.0 5 ND -- ND ND -- -- -- -- -- -- -- ND -- EPA MCL = 75 ug/L ug/L 04/03/95 5.0 5.0 5 ND 11 ND ND -- -- -- -- -- -- -- ND -- ug/L 10/30/95 5.0 5.0 5 ND 10 5 ND -- -- -- -- -- -- -- ND -- ug/L 04/08/96 -- -- 5 ND -- 9 ND -- -- -- -- -- -- -- ND -- ug/L 10/24/96 -- -- 5 ND -- 8 ND -- -- -- -- -- -- -- ND -- ug/L 04/15/97 -- -- 5 ND -- 24 ND -- -- -- -- -- -- -- ND -- ug/L 10/29/97 -- -- 5 ND 9 10 ND -- -- -- -- -- -- -- ND -- ug/L 05/14/98 -- -- 5 ND 18 22 ND -- -- -- -- -- -- -- ND -- ug/L 10/11/98 -- -- 5 ND 18 ND ND -- -- -- -- -- -- -- ND -- ug/L 06/04/99 -- -- 5 ND 18 10 ND -- -- -- -- -- -- -- ND -- ug/L 10/29/99 -- -- 5 ND ND 7 ND -- -- -- -- -- -- -- ND -- ug/L 04/20/00 -- -- 5 ND 5 18 ND ND -- -- -- -- -- -- ND -- ug/L 11/07/00 -- -- 5 ND ND 8 ND -- -- -- -- -- -- -- ND -- ug/L 02/27/01 -- -- 5 -- -- -- -- -- -- ND -- -- -- ND ND -- ug/L 05/15/01 -- -- 5 ND 14 6 ND -- -- -- -- -- -- -- ND -- ug/L 10/16/01 -- -- 5 ND 12 7 ND -- -- -- -- ND -- -- ND -- ug/L 04/24/02 -- -- 5 ND 18 8 ND ND -- -- -- ND -- -- ND -- ug/L 10/01/02 -- -- 5 ND 14 9 ND ND -- -- -- ND -- -- ND -- ug/L 04/09/03 5.0 5.0 5 ND ND 12 ND ND -- -- -- ND -- -- ND -- ug/L 10/20/03 5.0 5.0 5 ND 23 13 ND ND -- -- -- ND -- -- ND -- ug/L 03/24/04 5.0 5.0 5 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/27/04 5.0 5.0 5 ND 20 19 ND ND -- -- -- ND -- -- ND -- ug/L 05/25/05 5.0 5.0 5 ND ND 17.8 -- ND -- -- -- ND -- -- ND -- ug/L 10/04/05 5.0 5.0 5 ND 25.4 17 ND ND -- -- -- ND -- -- ND -- ug/L 04/25/06 5.0 5.0 5 ND 24.3 16.4 ND ND -- -- -- ND -- -- ND -- ug/L 10/04/06 5.0 5.0 5 ND 18.5 14.6 ND ND -- -- -- ND -- -- ND ND ug/L 03/21/07 5.0 5.0 5 ND 1.67 J 17.1 2.79 J 1.37 -- -- -- 2.86 J -- -- 0.37 J ND ug/L 10/02/07 5.0 5.0 5 ND 18.7 12.0 3.64 J 3.24 J -- -- -- 2.99 J -- -- ND ND ug/L 04/03/08 5.0 5.0 5 ND 0.38 J 8.37 4.50 J 1.57 J 2.11 J 1.04 J -- 2.77 J ND -- ND ND ug/L 10/29/08 5.0 5.0 5 ND 23.9 7.81 4.44 J 4.11 J 1.66 J -- -- 2.96 J ND -- ND ND ug/L 03/24/09 0.38 1.0 1 ND ND 6.4 1.3 0.57 J 1.4 -- -- 2.6 ND -- ND ND ug/L 09/22/09 0.38 1.0 1 ND ND 6.8 2.4 1.4 1.0 ND -- 2.1 ND -- ND ND ug/L 03/22/10 0.10 1.0 1 ND Dry 9.8 ND ND 1.2 -- -- 3.2 ND 2.0 ND ND ug/L 09/23/10 0.38 1.0 1 ND 15 8.8 ND ND 0.91 J -- -- 3.4 ND -- ND ND ug/L 03/16/11 0.79 1.0 1 ND ND 10 ND ND 1.3 -- -- 3.2 ND -- ND ND ug/L 09/21/11 0.79 1.0 1 ND 14 12 ND 0.93 J 1.2 -- -- 4.2 ND -- ND ND ug/L 03/21/12 0.19 1.0 1 ND 5.4 J 12 0.49 J 2.9 1.4 -- -- 3.7 ND -- ND ND ug/L 09/20/12 0.19 1.0 1 ND 0.77 J 11 1.0 2.0 1.2 -- -- 3.8 ND -- ND ND ug/L 03/20/13 0.19 1.0 1 ND ND 14 3.8 ND 2.2 -- -- 5.0 ND -- ND ND ug/L 09/18/13 0.19 1.0 1 ND 6.0 13 1.2 0.73 J 1.4 -- -- 4.1 ND -- ND ND ug/L 03/27/14 0.19 1.0 1 ND ND 18 ND ND 0.73 J -- -- 3.1 ND -- ND ND ug/L 09/18/14 0.19 1.0 1 ND 13 15 ND ND 0.86 J -- -- 4.3 ND -- ND ND ug/L 03/18/15 0.19 1.0 1 ND ND 14 ND 0.46 J 1.4 -- -- 4.0 ND -- ND ND ug/L 09/23/15 0.19 1.0 1 ND 21 13 ND 0.85 J 1.3 1.0 -- 3.6 ND -- ND ND ug/L 03/15/16 0.19 1.0 1 ND 1.2 16 ND ND 0.90 J ND 2.4 4.2 ND 3.5 ND ND ug/L 06/29/16 0.19 1.0 1 -- -- -- -- -- -- -- ND 4.2 ND 4.0 ND ND ug/L 09/21/16 0.19 1.0 1 ND 28 14 ND ND 0.87 J 0.6 J ND 4.2 ND -- ND ND ug/L 12/19/16 0.19 1.0 1 -- -- -- -- -- -- -- ND 3.2 ND 4.1 ND ND ug/L 03/21/17 0.19 1.0 1 ND 24 18 ND 0.44 1.4 ND ND 4.1 ND -- ND ND ug/L 06/21/17 0.19 1.0 1 -- -- -- -- -- -- -- ND 2.8 ND ND ND ND ug/L 09/20/17 0.19 1.0 1 ND 2.9 16 ND ND 1.2 0.45 J ND 3.8 ND -- ND ND ug/L 12/19/17 0.19 1.0 1 -- -- -- -- -- -- -- ND 3.5 ND 4.2 ND ND ug/L 03/21/18 0.19 1.0 1 ND ND 14 ND ND 1.1 ND ND 3.4 ND -- ND ND ug/L 06/15/18 0.19 1.0 1 -- -- -- -- -- -- -- ND 2.8 ND 4.2 ND ND ug/L 09/24/18 0.19 1.0 -- ND 5.4 16 ND ND 1.1 ND ND 3.4 ND -- ND ND ug/L 12/20/18 0.19 1.0 -- -- -- -- -- -- -- -- ND 2.9 ND 4.4 ND ND ug/L 03/26/19 0.19 1.0 -- ND ND 17 ND ND 0.59 J ND ND 2.3 ND -- ND ND ug/L 09/18/19 0.19 1.0 -- ND 14 12 ND ND ND ND -- 2.8 ND -- ND ND ug/L 03/16/20 0.19 1.0 -- ND 0.92 J 14 ND ND 0.47 J ND -- 2.6 ND -- ND ND ug/L 09/23/20 0.19 1.0 -- ND 1.4 14 ND ND ND ND -- 2.7 ND -- ND ND ug/L 03/15/21 0.19 1.0 -- ND ND 17 ND ND ND ND -- 3.7 ND -- ND ND ug/L 09/20/21 0.19 1.0 -- ND 9.5 16 ND ND ND ND -- 3.8 ND -- ND ND ug/L 03/14/22 0.19 1.0 -- ND ND 12 ND ND ND ND -- 2.5 ND -- ND ND ug/L 09/19/22 0.19 1.0 -- ND 0.44 J 16 ND ND 0.86 J ND -- 3.0 ND -- ND ND ug/L 03/20/23 0.19 1.0 -- ND ND 10 ND ND 0.72 J ND -- 3.7 ND -- ND ND July 2023 GL2014715721 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL pQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-11D AMW-2D MW-2 BR-3 1, 1 -Dichloroethane ug/L 12/05/94 5.0 5.0 5 ND ND ND ND -- -- -- -- -- -- -- ND -- NC 2L = 6 ug/L ug/L 02/14/95 5.0 5.0 5 ND ND 9 ND -- -- -- -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 5.0 5.0 5 ND -- 7 ND -- -- -- -- -- -- -- ND -- ug/L 10/30/95 5.0 5.0 5 ND ND 10 ND -- -- -- -- -- -- -- ND -- ug/L 04/08/96 -- -- 5 ND ND 6 ND -- -- -- -- -- -- -- ND -- ug/L 10/24/96 -- -- 5 ND -- 8 ND -- -- -- -- -- -- -- ND -- ug/L 04/15/97 -- -- 5 ND -- ND ND -- -- -- -- -- -- -- ND -- ug/L 10/29/97 -- -- 5 ND 1 7 ND -- -- -- -- -- -- -- ND -- ug/L 05/14/98 -- -- 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/11/98 -- -- 5 ND ND 6 ND -- -- -- -- -- -- -- ND -- ug/L 06/04/99 -- -- 5 ND ND 5 6 -- -- -- -- -- -- -- ND -- ug/L 10/29/99 -- -- 5 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/20/00 -- -- 5 ND ND ND 5 ND -- -- -- -- -- -- ND -- ug/L 11/07/00 -- -- 5 ND ND ND 6 -- -- -- -- -- -- -- ND -- ug/L 02/27/01 -- -- 5 -- -- -- -- -- -- ND -- -- -- 7 ND -- ug/L 05/15/01 -- -- 5 ND ND ND 14 -- -- -- -- -- -- -- ND -- ug/L 10/16/01 -- -- 5 ND ND ND 11 -- -- -- -- ND -- -- ND -- ug/L 04/24/02 -- -- 5 ND ND ND 25 ND -- -- -- ND -- -- ND -- ug/L 10/01/02 -- -- 5 ND ND ND 17 ND -- -- -- ND -- -- ND -- ug/L 04/09/03 -- -- 5 ND ND ND 24 ND -- -- -- ND -- -- ND -- ug/L 10/20/03 5.0 5.0 5 ND ND ND 18 ND -- -- -- ND -- -- ND -- ug/L 03/24/04 5.0 5.0 5 ND ND ND 10 ND -- -- -- ND -- -- ND -- ug/L 10/27/04 5.0 5.0 5 ND ND ND 13 ND -- -- -- ND -- -- ND -- ug/L 05/25/05 5.0 5.0 5 ND ND ND -- ND -- -- -- ND -- -- ND -- ug/L 10/04/05 5.0 5.0 5 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 04/25/06 5.0 5.0 5 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/04/06 5.0 5.0 5 ND ND ND 6 ND -- -- -- ND -- -- ND ND ug/L 03/21/07 5.0 5.0 5 ND ND 1.69 7.8 ND -- -- -- 1.31 -- -- ND ND ug/L 10/02/07 5.0 5.0 5 ND 0.45 J 1.66 J 9.7 0.1 J -- -- -- 1.27 J -- -- ND ND ug/L 04/03/08 5.0 5.0 5 ND ND 1.72 J 13.1 ND 0.98 J 3.87 J -- 1.36 J ND -- ND ND ug/L 10/29/08 5.0 5.0 5 ND 0.40 J 1.32 J 13.5 ND 1.33 J -- -- 1.36 J ND -- ND ND ug/L 03/24/09 0.33 1.0 5 ND ND 0.83 J 3.6 J ND 1.1 J -- -- 1.2 J ND -- ND ND ug/L 09/22/09 0.33 1.0 5 ND ND 0.75 J 8.9 ND 1.3 J ND -- 1.0 J ND -- ND ND ug/L 03/22/10 0.050 1.0 5 ND Dry 0.64 J ND ND 0.90 J -- -- 0.76 J ND 3.9 J ND ND ug/L 09/23/10 0.33 1.0 5 ND ND 0.64 J ND ND 0.84 J -- -- 0.87 J ND -- ND ND ug/L 03/16/11 0.080 1.0 5 ND ND 0.56 J ND ND 1.0 J -- -- 0.91 J ND -- ND ND ug/L 09/21/11 0.080 1.0 5 ND ND 0.74 J 1.7 J ND 1.4 J -- -- 1.1 J ND -- ND ND ug/L 03/21/12 0.13 1.0 5 ND ND 0.63 J 0.94 J ND 1.1 J -- -- 0.74 J ND -- ND ND ug/L 09/20/12 0.13 1.0 5 ND ND 0.49 J 2.5 J ND 1.3 J -- -- 1.0 J ND -- ND ND ug/L 03/20/13 0.13 1.0 5 ND ND 0.71 J 6.9 ND 1.6 J -- -- 1.2 J ND -- ND ND ug/L 09/18/13 0.13 1.0 5 ND ND ND 1.7 J ND 1.0 J -- -- 0.71 J ND -- ND ND ug/L 03/27/14 0.13 1.0 5 ND ND ND ND ND 0.92 J -- -- 0.72 J ND -- ND ND ug/L 09/18/14 0.13 1.0 5 ND ND 0.43 J ND ND 0.96 J -- -- 0.54 J ND -- ND ND ug/L 03/18/15 0.13 1.0 5 ND ND 0.47 J ND ND 0.77 J -- -- 0.76 J ND -- ND ND ug/L 09/23/15 0.13 1.0 5 ND ND ND ND ND 1.1 J 2.2 J -- 0.62 J ND -- ND ND ug/L 03/15/16 0.13 1.0 5 ND ND ND ND ND 0.99 J 2.0 J 0.55 J 0.54 J 0.45 J 4.0 J ND ND ug/L 06/29/16 0.13 1.0 5 -- -- -- -- -- -- -- ND 0.44 J ND 2.6 J ND ND ug/L 09/21/16 0.13 1.0 5 ND ND ND ND ND 0.94 J 1.7 J ND 0.51 J ND -- ND ND ug/L 12/19/16 0.13 1.0 5 -- -- -- -- -- -- -- ND ND ND 3.2 J ND ND ug/L 03/21/17 0.13 1.0 5 ND ND ND ND ND 1.1 J 1.6 J ND 0.58 J ND -- ND ND ug/L 06/21/17 0.13 1.0 5 -- -- -- -- -- -- -- 0.49 J ND ND 3.3 J ND ND ug/L 09/20/17 0.13 1.0 5 ND ND ND ND ND 0.87 J 1.8 J ND ND ND -- ND ND ug/L 12/19/17 0.13 1.0 5 -- -- -- -- -- -- -- ND ND ND 2.3 J ND ND ug/L 03/21/18 0.13 1.0 5 ND ND ND ND ND 0.74 J 0.92 J ND ND ND -- ND ND ug/L 06/15/18 0.13 1.0 5 -- -- -- -- -- -- -- ND ND ND 2.5 J ND ND ug/L 09/24/18 0.13 1.0 -- ND ND ND ND ND ND 1.0 ND ND ND -- ND ND ug/L 12/20/18 0.13 1.0 -- -- -- -- -- -- -- -- ND ND ND 2.6 ND ND ug/L 03/26/19 0.13 1.0 -- ND ND ND ND ND 0.65 J 1.0 ND ND ND -- ND ND ug/L 09/18/19 0.13 1.0 -- ND ND ND ND ND 0.58 J 1.0 -- ND ND -- ND ND ug/L 03/16/20 0.13 1.0 -- ND ND ND ND ND 0.43 J 0.43 J -- ND ND -- ND ND ug/L 09/23/20 0.13 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/15/21 0.13 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 09/20/21 0.13 1.0 -- ND ND ND ND ND ND 0.77 J -- ND ND -- ND ND ug/L 03/14/22 0.13 1.0 -- ND ND ND ND ND 0.42 J 0.48 J -- ND ND -- ND ND ug/L 09/19/22 0.13 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/20/23 0.13 1.0 -- ND ND ND ND ND 0.41 J 0.25 J -- 0.24 0.33 J -- ND ND July 2023 GL2014715721 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL pQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-11D AMW-2D MW-2 BR-3 Methylene chloride ug/L 12/05/94 10 10 10 ND ND ND 7 -- -- -- -- -- -- -- ND -- NC 2L = 5 ug/L ug/L 02/14/95 10 10 10 -- -- -- -- -- -- -- -- -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 10 10 10 -- -- -- -- -- -- -- -- -- -- -- ND -- ug/L 10/30/95 10 10 10 ND ND 10 ND -- -- -- -- -- -- -- ND -- ug/L 04/08/96 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND -- 9 ND -- -- -- -- -- -- -- ND -- ug/L 04/15/97 -- -- 10 -- -- -- -- -- -- -- -- -- -- -- ND -- ug/L 10/29/97 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/11/98 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 06/04/99 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/29/99 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/20/00 -- -- 10 ND ND ND ND ND -- -- -- -- -- -- ND -- ug/L 11/07/00 -- -- 10 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 02/27/01 -- -- 10 -- -- -- -- -- -- ND -- -- -- ND ND -- ug/L 05/15/01 -- -- 10 ND ND ND 52 -- -- -- -- -- -- -- ND -- ug/L 10/16/01 -- -- 10 ND ND ND 38 -- -- -- -- ND -- -- ND -- ug/L 04/24/02 -- -- 10 ND ND ND 87 ND -- -- -- ND -- -- ND -- ug/L 10/01/02 -- -- 10 ND ND ND 44 ND -- -- -- ND -- -- ND -- ug/L 04/09/03 10 10 10 ND ND ND 54 ND -- -- -- ND -- -- ND -- ug/L 10/20/03 10 10 10 ND ND ND 27 ND -- -- -- ND -- -- ND -- ug/L 03/24/04 10 10 10 ND ND ND 30 ND -- -- -- ND -- -- ND -- ug/L 10/27/04 10 10 10 ND ND ND 42.1 ND -- -- -- ND -- -- ND -- ug/L 05/25/05 10 10 10 ND ND ND -- ND -- -- -- ND -- -- ND -- ug/L 10/04/05 10 10 10 ND ND ND 13.4 ND -- -- -- ND -- -- ND -- ug/L 04/25/06 10 10 10 ND ND ND 13.9 ND -- -- -- ND -- -- ND -- ug/L 10/04/06 10 10 10 ND ND ND 15.1 ND -- -- -- ND -- -- ND ND ug/L 03/21/07 10 10 10 ND ND 0.35 J 23.3 ND -- -- -- 0.24 J -- -- ND ND ug/L 10/02/07 10 10 10 ND 0.57 B ND 22.0 ND -- -- -- ND -- -- ND 0.41 J ug/L 04/03/08 10 10 10 ND ND 0.34 B 34.2 ND ND ND -- ND 3.10 J -- ND 0.42 J ug/L 10/29/08 10 10 10 ND ND 0.27 J 33.7 ND 0.92 J -- -- 0.42 J ND -- ND ND ug/L 03/24/09 0.53 2.0 1 ND ND ND 11 ND ND -- -- ND ND -- ND ND ug/L 09/22/09 0.53 1.0 1 ND ND ND 21 ND ND ND -- ND ND -- ND ND ug/L 03/22/10 0.070 1.0 1 ND Dry ND ND ND ND -- -- ND ND ND ND ND ug/L 09/23/10 0.53 1.0 1 ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 03/16/11 0.14 1.0 1 ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 09/21/11 0.14 1.0 1 ND ND ND 3.4 ND ND -- -- ND ND -- ND ND ug/L 03/21/12 0.23 1.0 1 ND ND ND 1.8 ND ND -- -- ND ND -- ND ND ug/L 09/20/12 0.23 1.0 1 ND ND ND 2.4 ND ND -- -- ND ND -- ND ND ug/L 03/20/13 0.23 1.0 1 ND ND ND 11 ND ND -- -- ND ND -- ND ND ug/L 09/18/13 0.23 1.0 1 ND ND ND 1.0 ND ND -- -- ND ND -- ND ND ug/L 03/27/14 0.23 1.0 1 ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 09/18/14 0.23 1.0 1 ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 03/18/15 0.23 1.0 1 ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 09/23/15 0.23 1.0 1 ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/15/16 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND ND ND ND ug/L 06/29/16 0.23 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/21/16 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/16 0.23 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/21/17 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/21/17 0.23 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/20/17 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.23 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/21/18 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/15/18 0.23 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/24/18 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/20/18 0.23 1.0 -- -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/26/19 0.23 1.0 -- ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 09/18/19 0.23 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/16/20 0.23 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 09/23/20 0.23 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/15/21 0.23 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 09/20/21 0.23 1.0 -- ND ND ND ND ND ND -- -- ND ND -- ND ND ug/L 03/14/22 0.23 1.0 -- ND 0.41 B ND ND ND ND -- -- ND ND -- ND 0.67 J ug/L 03/19/22 0.23 1.0 -- ND ND ND ND ND ND -- -- ND ND -- ND 0.47 J ug/L 03/20/23 0.23 1.0 -- ND ND 0.267 B ND ND 0.308 B -- -- ND ND -- 0.256 B 0.362 J July 2023 GL2014715721 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-1D AMW-2D MW-2 BR-3 Vinyl chloride ug/L 12/05/94 10 10 1 ND ND ND ND -- -- -- -- -- -- -- ND -- NC 2L = 0.03 ug/L ug/L 02/14/95 10 10 1 ND ND ND ND -- -- -- -- -- -- -- ND -- EPA MCL = 2 ug/L ug/L 04/03/95 10 10 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/08/96 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/24/96 -- -- 1 ND -- ND ND -- -- -- -- -- -- -- ND -- ug/L 04/15/97 -- -- 1 ND -- ND ND -- -- -- -- -- -- -- ND -- ug/L 10/29/97 -- -- 1 ND 2 5 2 -- -- -- -- -- -- -- ND -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/11/98 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 06/04/99 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 04/20/00 -- -- 1 ND ND ND ND ND -- -- -- -- -- -- ND -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 02/27/01 -- -- 1 -- -- -- -- -- -- ND -- -- -- ND ND -- ug/L 05/15/01 -- -- 1 ND ND ND ND -- -- -- -- -- -- -- ND -- ug/L 10/16/01 -- -- 1 ND ND ND ND -- -- -- -- ND -- -- ND -- ug/L 04/24/02 -- -- 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/01/02 -- -- 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 04/09/03 -- -- 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 03/24/04 10 10 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/27/04 10 10 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 05/25/05 10 10 1 ND ND ND -- ND -- -- -- ND -- -- ND -- ug/L 10/04/05 10 10 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 04/25/06 10 10 1 ND ND ND ND ND -- -- -- ND -- -- ND -- ug/L 10/04/06 10 10 1 ND ND ND ND ND -- -- -- ND -- -- ND ND ug/L 03/21/07 10 10 1 ND 0.43 J 2.35 ND ND -- -- -- 0.94 J -- -- ND ND ug/L 10/02/07 10 10 1 ND 1.03 J 2.68 J 0.31 J ND -- -- -- 0.89 J -- -- ND ND ug/L 04/03/08 10 10 1 ND ND 2.94 J ND 0.59 J 0.640 J -- 0.98 J ND -- ND ND ug/L 10/29/08 10 10 1 ND 0.25 J 2.36 0.49 J ND 0.57 J -- -- 0.82 J ND -- ND ND ug/L 03/24/09 0.30 1.0 1 ND ND 1.5 ND ND 0.53 J -- -- 0.60 J ND -- ND ND ug/L 09/22/09 0.30 1.0 1 ND ND 1.4 ND ND ND ND -- 0.67 J ND -- ND ND ug/L 03/22/10 0.083 1.0 1 ND Dry 1.2 ND ND ND -- -- 0.60 J ND 0.74 J ND ND ug/L 09/23/10 0.30 1.0 1 ND ND 1.2 ND ND ND -- -- ND ND -- ND ND ug/L 03/16/11 0.60 1.0 1 ND ND 1.3 ND ND ND -- -- ND ND -- ND ND ug/L 09/21/11 0.60 1.0 1 ND ND 1.5 ND ND ND -- -- 0.76 J ND -- ND ND ug/L 03/21/12 0.32 1.0 1 ND ND 0.88 J ND ND 0.55 J -- -- ND ND -- ND ND ug/L 09/20/12 0.32 1.0 1 ND ND ND ND ND 0.61 J -- -- 0.57 J ND -- ND ND ug/L 03/20/13 0.32 1.0 1 ND ND 1.0 0.77 J ND 0.49 J -- -- 0.50 J ND -- ND ND ug/L 09/18/13 0.32 1.0 1 ND ND 0.81 J ND ND 0.48 J -- -- 0.48 J ND -- ND ND ug/L 03/27/14 0.32 1.0 1 ND ND 1.1 ND ND ND -- -- 0.64 J ND -- ND ND ug/L 09/18/14 0.32 1.0 1 ND ND 1.1 ND ND ND -- -- 0.54 J ND -- ND ND ug/L 03/18/15 0.32 1.0 1 ND ND 0.88 J ND ND ND -- -- 0.46 J ND -- ND ND ug/L 09/23/15 0.32 1.0 1 ND ND 0.98 J ND ND ND ND -- ND ND -- ND ND ug/L 03/15/16 0.32 1.0 1 ND ND 0.93 J ND ND ND ND ND 0.46 J ND 0.56 J ND ND ug/L 06/29/16 0.32 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/21/16 0.32 1.0 1 ND ND 0.74 J ND ND ND ND ND ND ND -- ND ND ug/L 12/19/16 0.32 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/21/17 0.32 1.0 1 ND ND 0.92 J ND ND ND ND ND ND ND -- ND ND ug/L 06/21/17 0.32 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/20/17 0.32 1.0 1 ND ND 0.73 J ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.32 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/21/18 0.32 1.0 1 ND ND 0.51 J ND ND ND ND ND ND ND -- ND ND ug/L 06/15/18 0.32 1.0 1 -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 09/24/18 0.32 1.0 -- ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/20/18 0.32 1.0 -- -- -- -- -- -- -- -- ND ND ND ND ND ND ug/L 03/26/19 0.32 1.0 -- ND ND 0.51 J ND ND ND ND ND ND ND -- ND ND ug/L 09/18/19 0.32 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/16/20 0.32 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 09/23/20 0.32 1.0 -- ND ND 0.74 J ND ND ND ND -- ND ND -- ND ND ug/L 03/15/21 0.32 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 09/20/21 0.32 1.0 -- ND ND ND ND ND ND ND -- ND ND -- ND ND ug/L 03/14/22 0.32 1.0 -- ND ND 0.61 J ND ND ND ND -- ND ND -- ND ND ug/L 09/19/22 0.32 1.0 -- ND ND 0.84 J ND ND ND ND -- ND ND -- ND ND ug/L 03/20/23 0.320 1.00 -- ND ND 0.81 J ND ND ND ND -- ND ND -- ND ND Notes: J = Following the The November 2018 event, J flags are estimated values between the MDL and PQL. Prior to the November 2018 event, J flags are estimated values below the SWS Reporting limit. B = Blank -qualified result MDL = laboratory method detection limit PQL = practical quantitation limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 EPA MCL = US Environmental Protection Agency Maximum Contaminant Level NC 2L = North Carolina 2L Groundwater Standard FIGURES \\-' III //// ///// / \ 1 � ��`• \ //��J �/ �//��. -- �\= I \ \ \\ - \ I I I 1 I r/ `\�`\ `� � // I I II III IIII `•/i�riU /�. \ 1 1\ 1 •' \ 11l // \ \\ \ IIII/// / -___ - 'ill IIII 230 /`^ _' /'/-• '/'!// IIII ' II I111 1\ \\` Q ` `\` \` / // j'/'� _�\ \` \\ \\` \`\ l ,\\ \\ \ / \\\\ �\ ///'�i / /f/r//" /..�� ��/ '"' _ ___ _ q 1 MP-7/ 0P-9// III lilt \\�__�/ii i//I 111 I I, —x�x / , n l/,l l?� \ \�---_\ 6 \ \\\ \\ � �� �///� / , 1 1 II I.,. 11 \ \•' l// l l / \ \ IIII li' .//,, I11111111IIII/IIII/ /r�/ //'-�`` \\\\ \1\111111'1 O. \, \\\ _,./'/^ / // / / < \ 1 ( `TR-2 _ \ \ \ \ , ,/ / / \ TR-3 \ ( \ � \\ \ \\\\ \\ // / / // / // \ 1` II 111 \\\\ 1 `\\\\\1_-- / _ \\ \\ � ��_-.• \ �/ _ \` \ �_ \ / IIII , ,\\ \ \\\\ \\ \\``\ _ ,\0 2332.75,- /:-\`Illl�l _A��s I II II IIII Illll'l11 1 / /♦ / i ��%-�_____ � � --._ � _� `� `\� �\ , \`? 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APPROVED BSD LEGEND —x—x—x— O MW-8 2211.07 - MW-1 2199.58 AMP-8 EXISTING 10 FT. CONTOUR EXISTING 2 FT. CONTOUR PROPERTY LINE LIMITS OF WASTE STREAM BUFFER TREELINE EXISTING ROAD FENCE GROUNDWATER SURFACE CONTOURS APPROXIMATE GROUNDWATER FLOW SEGMENT USED TO CALCULATE GRADIENT COMPLIANCE GROUNDWATER MONITORING WELL AND IDENTIFICATION NON COMPLIANCE GROUNDWATER MONITORING WELL AND IDENTIFICATION COMPLIANCE METHANE MONITORING WELL AND IDENTIFICATION MP-6 ASSESSMENT COMPLIANCE METHANE MONITORING WELL AND IDENTIFICATION ❑ BR-1 SURFACE WATER MONITORING POINT AND IDENTIFICATION O IW-1 INJECTION WELL AND IDENTIFICATION 2179.31 NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 20 FEET 3. GROUNDWATER ELEVATIONS MEASURED ON MARCH 20 - 22, 2023. 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5. GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL 6. COORDINATE SYSTEM IS N.C. STATE PLANE GRID. 7. TOPOGRAPHIC DIVIDING LINE DIVIDES THE BASE MAP TOPOGRAPHIC CONTOURS FROM LANDSAT TOPOGRAPHIC CONTOURS. LANDSAT TOPOGRAPHIC CONTOURS HAVE A 5-CONTOUR INTERVAL. 8. LOCATION OF COMPLIANCE METHANE MONITORING WELL MP-4 IS APPROXIMATE. REFERENCES 1. BASE MAP PROVIDED BY CAMP DRESSER & McKEE FROM PREVIOUS WATER QUALITY MONITORING L REPORTS. ` c C L C L L L L r c F L L C L F C c 0 200 400 SCALE FEET C PROJECT HENDERSON COUNTY CLOSED MSW AND C&D LANDFILL PERMIT # 45-01 LC i L TITLE `- GROUNDWATER SURFACE CONTOUR MAP MARCH 20 - 227 2023 PROJECT NO. FIGURE 2014715721.001 0 0 APPENDIX GROUNDWATER AND SURFACE WATER SAMPLING LOGS Project Name: Well ID: Well Diameter: Depth to Bottom: Pumping Rate: Equipment: DATE: 3�2Z� 2b23 GROUNDWATER SAMPLING LOG �Z", y'P-\ C.� Lt Project No./Phase No.: Mw 25 Sampler(s): Nicolas Tejeda-Torres 2 inches Initial Depth to Water: 43.25 feet I-j,w feet Water Column Thickness: J(.,JS feet 25-b mUmin. System Volume: 1k3j_ mL Turbidimeter, YSI ProPlus, WL Meter Dedicated BP, MP-15 0 NONE ME M� 0 NONE Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ Weather: Signature: QA/QC Sign Off: Date: 3 Date: 3 t 2Z l 2uz-, Project Name: Well ID: Well Diameter: Depth to Bottom: Pumping Rate: DATE: 3 1 2I1 Z3 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: GL2014715721.001 AMW - 1 Cl Sampler(s): Johna a:r e_a �nesicslNicolas Tejeda-Torres 2 inches Initial Depth to Water: feet -'+2 feet Water Column Thickness: feet %b iZO mL/min. System Volume: \ZL4Z mL Equipment: Turbidimeter, YSI Pro Plus, WL Meter Dedicated BP, MP-15 Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis 02 (mg/L) Temp. (°C) ORP (millivolts) DTW (feet) c�25 2•DS �� 5.�6 � . 6 13,�i ��,Q �►•'�� l0719 Dyl ,1 0U2 �•o� .56 L .� zl?.9 \G•a0 \ �1.36 6.)a2 \,A 2 \53 Po ..05 1 Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ �O5- Weather: Signature: L/'—^' Date: 3 IL( (23 l ) QA/QC Sign Off: C Date: 3/Z 1 /2-3 Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: DATE: 1; ( 6 \ ( Z3 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: GL2014715721.001 AMw -Zo Sampler(s): Jotrnathar sgrencsi /Nicolas Tejeda-Torres 2 inches Initial Depth to Water: q.09 feet Op 6Z feet Water Column Thickness: 10.63 feet ZbG mL/min. System Volume: mL Equipment: Turbidimeter, YSI ProPlus, WL Meter Dedicated BP, MP-15 ®m� 1 n Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ �\ZIS Weather: Uo, Signature: Date: 3 f 4� I (?_3 QA/QC Sign Off: �.��� ��..., Date: .3 Z) /Z 3 DATE: I1 -\� ZJ, ZO 2 3 GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: VlVy - `j Sampler(s): Johnathan Serencsicsftcolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: S 4. G'4 feet Depth to Bottom: 3 U,-�_feet Water Column Thickness: 15 .y c"l feet Pumping Rate: J Z j mL/min. System Volume: 1' SD mL Equipment: Turbidimeter, YSI ProPlus, WL Meter Dedicated BP, MP-15 Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis 02 (mg/L) Temp. VC) ORP (millivolts) DTW (feet) (0. 15 y 1 L. 1 Q. Z 1 . I 7--) I - Li S� IL 51 .25 a O3 . A 3 (' 3 1Z 75�; 59 L.W T(O 9 1-5;- 1 22.1 S4 .zs 100 5. 00 I�s,O 2.,�,k .!�L Iz. � � Z`" Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ q3q Weather: ; low 3 v� Signature: Date: 3 I Zi QA/QC Sign Off: Gl--- Date: 5 yv 12023 Project Name: Henderson County LF Well ID: /NW -6 Well Diameter: 2 inches Depth to Bottom: (II.61b feet Pumping Rate: — mL/min. DATE: 3I Z0 Z 3 GROUNDWATER SAMPLING LOG Project No./Phase No.: GL2014715721.001 Sampler(s): J nathan�cs{{�icolas Teieda-Torres Initial Depth to Water: (y.y-- feet Water Column Thickness: y,6% feet System Volume: 620" mL Equipment: Turbidimeter, YS/ ProPlus, WL Meter SS , MP-f& p;sQo�aylc, 60i w Sp. Cond. Dis 02 Temp. Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ Y5o ra>n 31C& sJt; �p {aKun ba da 'A Weather: 6,,orv, k-f Signature: QA/QC Sign Off: Date: 3 (Z 11 Z3 Date: 3 /-Zt 2� Project Name: Well ID: Well Diameter: Depth to Bottom Pumping Rate: DATE: 31 Z 1 (23 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: GL2014715721.001 AAA -1 Sampler(s): na�ren- c es7Nicolas Tejeda-Torres 2 inches Initial Depth to Wa er: \IA5 feet ZT q4 feet Water Column Thickness: Tliq feet C"o mL/min. System Volume: -T\1 mL Equipment: Turbidimeter, YSl ProPlus, WL Meter Dedicated BP. MP-15 SID. Cond. Dim 02 ----_�- Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ SOO Weather: tinny ,U05 Signature: Date: 3 I Z I (Z3 QA/QC Sign Off: Date: 3Z'Zi 1'2-3 DATE: 31 Z o (2 3 GROUNDWATER SAMPLING LOG Project Name: Henderson CoUntX i.F Project No./Phase No.: GL2014715721.001 Well ID: Hu�_ _ U M5\ Sampler(s): Johnathan serencsics/Nicolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: 2-H ce'b feet Depth to Bottom: 3 .1L feet Water Column Thickness: S.1�2 feet Pumping Rate: 2 mL/min. System Volume:�mL Equipment: Turbidimeter, YSI Pro Plus, WL Meter Dedicated BP, MP-15 Sp. Cond. ®� Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ j (jq Weather: 5,,)NNJ 34>S Signature: QA/QC Sign Off: Date: `S 12-612s:, z Date: 2 [zoI-z OZ7 DATE: GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: ?NVJ 9 Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: -SS feet Depth to Bottom: pu feet Water Column Thickness: ',.` z feet Pumping Rate: ELLS mL/min. System Volume: gyp) , mL Equipment: Turbidimeter, YSI ProPI(IS, WL Meter Dedicated BP, MP-15 Sp. Cond. ------- -IMMUNE ----- Comments (weather onditions, color, type of sample, purge -water management, etc.): Begin Purge Weather: iZo LU n s Signature: QA/QC Sign Off: Date:. `2:Z(to'-t Date: 3172 / 2 c)z � NN %% I "", Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: Equipment: DATE: �� 21 ( LoZ 3 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: GL2014715721.001 L) ICE Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres 2 inches Initial Depth to Water: GU a qy feet Yl.(a t4 feet Water Column Thickness: j feet �VC� mL/min. System Volume: mL Turbidimeter, YSI ProPluS, WL Meter Dedicated BP, MP-15 Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis 02 (mg/L) Temp. (°C) ORP (millivolts) DTW (feet) vrc 9-6C154 �3.9 4. Sq 4q y 9J ,C� q 0)_ -4 4 1 r31vF 10 0A i -5.s- L.�,I '64ti I1 9 1009 L43-t 3:4- 16,Z.Ll )Z-Z ��•5 t1i 153 L4 4.to 2 ae 12 �I 5.5 `l3 `l 0 .91 `f.ip Z-3 >,`i. U EQtui Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ ' ( L{ H Weather: Signature: Date: QA/QC Sign Off: > � �� Date: _?[2i%2c23 DATE: 3 10117-3 GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: MW - t l Lmg A->0 N Sampler(s): : ,nat Ser a colas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: 5b,�-(, feet Depth to Bottom: 5-e,3w feet Water Column Thickness: '{.�$ feet Pumping Rate: IGO mL/min. System Volume: mL Equipment: Turbidimeter, YSI ProPlus, WL Meter Dedicated BP. MP-15 ®Sp. Cond. ® ' , • •-' Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ N 30 Weather: Signature: Date: 3 (Z l (23 QA/QC Sign Off: — Date: ?, )-1 i J 23 DATE: lki';j121�TD,1_ GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: V2_ Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: j (. feet Depth to Bottom: fo6J-L feet Water Column Thickness: �5,1p feet Pumping Rate: 115b, mL/min. System Volume: lumL Equipment: Turbidimeter, YSI ProPlus, WL Meter Dedicated BP, MP-15 ®Sp. Cond. • • •RP (millivolts): Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ IZ5C- Weather: r Signature: QA/QC Sign Off: Date: 0 12-I ( Zc,Z`, Date: 3� z 1 '2v-�3 DATE: �3I Z((.n GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: 6d--tom �'\W - ( S Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: eet Depth to Bottom: OS feet Water Column Thickness: �'�. r feet Pumping Rate: 4es3 I t5b mL/min. System Volume: { - mL Equipment: Turbidimeter, YSI ProPILIS, WL Meter Dedicated BP, MP-15 • ® . Cond. ® , / • .' WHOM — Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ �T7� Weather: Signature: Date: 3 Z� QA/QC Sign Off: Date: ? ) 21 / Z3 bo.'O' NO goo DATE: 3 6 �2,01,?, GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Well ID: () �{,� _ Z Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres Well Diameter: 2 inches Initial Depth to Water: -A feet Depth to Bottom: ? J Z feet Water Column Thickness: feet Pumping Rate: i2S .%>►oo mL/min. System Volume: (040 mL Equipment: Turbidimeter, YS/ ProPlus, WL Meter Dedicated BP, MP-15 Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis 02 (mg/L) Temp. VC) ORP (millivolts) DTW (feet) `1 qtJ' 33.q z.'t;0 iz.3 .. S.y q. bo a0A LS L4i8.-A L1.yC1 2-.2-4 1Z.-j -23• I to.10 A 16. (a o -Z , i • 12 .._ .. 11. 1 (a.02- g 14.1, a-ZA 2_40 2- 2-i2 iz..oZ 101 5_ I L{ t % -Z.Z 2-, K2- t 2- •L 7- ► 3 ; i5' 5. 8n Its . 01 Z . 3L 3 . to 1 z . O 13 ., - - 5.�3 26 12.E �IY� r 1�1-L1ty Comments (weather conditions, color, type of sample, purge -water management, etc.): Begin Purge @ -rSLi Weather: (y('J 3y5 QA/QC Sign Off: Date: %'20-Z'-? DATE: '3 �Zd-zdz3 SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Sample ID: Sampler(s): Johnathan Sere ncsics/Nicolas Tejeda-Torres Sampling Location: p� eta QA { 5(XAL& I ir'*4,AN suW. co��, Equipment: YSI, Turbidimeter Time qt5 pH s.u..� Sp. Cond. us/cm `L3e ti Turb. ntu 3 Dis. OZ mg/L Temp. oC ORP my 3�•S Surface Water Sampling Location Sketch X k k� Comments (sample methodology, weather conditions, color, silt, etc.): vadya.b Signature: QA/QC Sign Off: Date: J 2 �� Date: ?Z'22 J•Z0 Z 3 DATE: 312 7,613 SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Sample ID: bQ--1 Sampler(s): Johnathan Serencsics/Nicolas Teieda-Torres Sampling Location: �Prc'- VV-a,r QGI"- c4i (dalz Equipment: YSI, Turbidimeter Time R pH S.U. Sp. Cond. us/cm 'L n Turb. ntu 'L T"/ Dis. 02 mg/L Temp. oC--1 Q ORP my l Surface Water Sampling Location Sketch 091 Comments (sample methodology, weather conditions, color, silt, etc.): -V60o&- 3-tl "U— Signature: � Date: 3' ZZ 1 Z02-'S QA/QC Sign Off: Date: 3%Z z / z'0Z? DATE: 2, 7,120L SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Sample ID: '2. Sampler(s): Johnathan Serencsics/Nicolas Tejeda-Torres Sampling Location: bZsld- 5 Q Equipment: YSI, Turbidimeter Time pH s.u. Sp. Cond. us/cm I Tu rb. ntu �•�� Dis. 02 mg/L Temp. oC gyp. Li ORP my _ 1611 L---T Surface Water Sampling Location Sketch x •jt v S / Comments (sample methodology, weather conditions, color, silt, etc.): �Cu�e�SS'• 3'S� ,r•�o, I � Signature: QA/QC Sign Off: Date: nI zi� 3 Date: 3 1 •zz1 Zc'23 DATE: V '-v' 2-0-3 SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: GL2014715721.001 Sample ID: sV--3 Sampler(s): Johnathan Serencsics/Nicolas Teieda-Torres Sampling Location: Equipment: Time kuu S.U.pH L4 Sp. Cond. us/cm 4 Turb. ntu Dis. OZ mg/L �O-Wo Temp. `C ORP my YSI, Turbidimeter V L W--.3 Z'.� few - 20 &- 1kW'3- Z Surface Water Sampling Location Sketch )0 RM�'a 2ij 6r ANW - 2S Comments (sample methodology, weather conditions, color, silt, etc.): ttcz� : L1og r-,�►jc, Signature: e • • Date: 3�2�i2?�Z3 Date: 3) 2y23 APPENDIX B MARCH 2O23 WATER QUALITY MONITORING CERTI FICATE-OF-ANALYSIS, CHAIN -OF -CUSTODY FORMS AND LABORATORY DATA .y r • % eurofins Environment Testing ANALYTICAL REPORT C PREPARED FOR Attn: Benjamin Draper WSP USA Inc 5B Oak Branch Drive C Greensboro, North Carolina 27407 Generated 4/19/2023 5:32:46 PM JOB DESCRIPTION Henderson County Landfills Henderson County Spring JOB NUMBER 752-4652-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Generated 4/19/2023 5:32:46 PM Authorized for release by Amanda Gaines, Project Manager amanda.gaines(o)et.eurofinsus.com (919)677-1669 Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 242 4/19/2023 Client: WSP USA Inc Project/Site: Henderson County Landfills Table of Contents Laboratory Job ID: 752-4652-1 Cover Page .............................................. 1 Table of Contents ......................................... 3 Definitions/Glossary....................................... 4 Case Narrative ........................................... 6 Detection Summary ........................................ 11 Client Sample Results ...................................... 18 Surrogate Summary ....................................... 74 QC Sample Results ........................................ 83 QC Association Summary ................................... 164 Lab Chronicle ............................................ 181 Certification Summary ...................................... 191 Method Summary ......................................... 195 Sample Summary ......................................... 196 Chain of Custody .......................................... 197 Receipt Checklists ......................................... 227 Eurofins Raleigh Page 3 of 242 4/19/2023 Definitions/Glossary Client: WSP USA Inc Project/Site: Henderson County Landfills Qualifiers GC/MS VOA Qualifier Qualifier Description *- LCS and/or LCSD is outside acceptance limits, low biased. *+ LCS and/or LCSD is outside acceptance limits, high biased. *1 LCS/LCSD RPD exceeds control limits. B Compound was found in the blank and sample. F1 MS and/or MSD recovery exceeds control limits. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. GC/MS Semi VOA Job ID: 752-4652-1 Qualifier Qualifier Description *+ LCS and/or LCSD is outside acceptance limits, high biased. F1 MS and/or MSD recovery exceeds control limits. GC VOA Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. H Sample was prepped or analyzed beyond the specified holding time GC Semi VOA Qualifier Qualifier Description �+ LCS and/or LCSD is outside acceptance limits, high biased. *1 LCS/LCSD RPD exceeds control limits. F1 MS and/or MSD recovery exceeds control limits. F2 MS/MSD RPD exceeds control limits J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported. Si- Surrogate recovery exceeds control limits, low biased. HPLC/IC Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Metals Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. B Compound was found in the blank and sample. F1 MS and/or MSD recovery exceeds control limits. J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. General Chemistry Qualifier Qualifier Description F1 MS and/or MSD recovery exceeds control limits. F3 Duplicate RPD exceeds the control limit J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. a Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor Eurofins Raleigh Page 4 of 242 4/19/2023 Definitions/Glossary Client: WSP USA Inc Project/Site: Henderson County Landfills Glossary (Continued) Abbreviation These commonly used abbreviations may or may not be present in this report. DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRIES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Job ID: 752-4652-1 Eurofins Raleigh Page 5 of 242 4/19/2023 Case Narrative Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Laboratory: Eurofins Raleigh Narrative Job ID: 752-4652-1 0 Job Narrative 752-4652-1 Comments No additional comments. Receipt The samples were received on 3/21/2023 9:20 AM, 3/22/2023 10:00 AM and 3/23/2023 10:00 AM. Unless otherwise noted below, the samples arrived in good condition, and where required, properly preserved and on ice. The temperatures of the 5 coolers at receipt time were 1.01 C, 1.01 C, 1.00 C, 1.01 C and 1.01 C. GC/MS VOA Method 8260D SIM 14D: The following matrix spike duplicate (MSD) analyzed in batch 770731 was outside the method criteria for the 12 hour window by 10 minutes. The data integrity was not impacted and the data has been reported and addressed: 4501-MW8 (752-4652-3[MSD]). Method 8260D SIM 14D: The following matrix spike (MS) and matrix spike duplicate (MSD) analyzed in batch 770731 was outside the method criteria for the 12 hour window by 37 and 64 minutes. The data integrity was not impacted and the data has been reported and addressed: 4501-MW11 (752-4682-4[MS]) and 4501-MW11 (752-4682-4[MSD]). Method 8260D: The continuing calibration verification (CCV) associated with batch 752-2053 recovered above the upper control limit for Vinyl chloride. The samples associated with this CCV were non -detects for the affected analytes; therefore, the data have been reported. Method 8260D: The laboratory control sample and/or the laboratory control sample duplicate (LCS/LCSD) for analytical batch 752-2053 recovered outside control limits for the following analyte(s): Trichlorofluoromethane. Trichlorofluoromethane has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed. Method 8260D: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 752-2053 recovered outside control limits for the following analytes: Vinyl chloride. These analytes were biased high in the LCS and were not detected in the associated samples > RL; therefore, the data have been reported. Method 8260D: The matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 752-2053 exceeded control limits for the following analyte(s): Dichlorodifluoromethane and Trichlorofluoromethane, Note that this analyte is a known poor performer when analyzed using this method. Method 8260D: The 4501-MW8 (752-4652-3[MS]) and 4501-MW8 (752-4652-3[MSD]) was biased high for Vinyl chloride. The compound was a non -detect in the samples. The data were qualified and reported. 4501-MW8 (752-4652-3[MS]) and 4501-MW8 (752-4652-3[MSD]) Method 8260D: The continuing calibration verification (CCV) associated with batch 752-2107 recovered above the upper control limit for Vinyl chloride. Non -detections of the affected analytes are reported. Any detections are considered estimated. Method 8260D: The continuing calibration verification (CCV) associated with batch 752-2107 recovered above the upper control limit for Tetrahydrofuran. Non -detections of the affected analytes are reported. Any detections are considered estimated. Method 8260D: The laboratory control sample and/or the laboratory control sample duplicate (LCS/LCSD) for analytical batch 752-2107 recovered outside control limits for the following analyte(s): Dichlorodifluoromethane and Trichlorofluoromethane. Dichlorodifluoromethane and Trichlorofluoromethane have been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed. Eurofins Raleigh Page 6 of 242 4/19/2093 Case Narrative Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Job ID: 752-4652-1 (Continued) Laboratory: Eurofins Raleigh (Continued) . Method 8260D: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 752-2107 recovered outside control limits for the following analytes: Vinyl chloride. These analytes were biased high in the LCS and LCSD. All non -detect data were reported. Any detections > RL are considered estimated values. Method 8260D: The following sample was diluted to bring the concentration of target analytes within the calibration range: 4501-MW6 (752-4682-1). Elevated reporting limits (RLs) are provided. Method 8260D: The continuing calibration verification (CCV) associated with batch 752-2066 recovered above the upper control limit for Vinyl chloride. The samples associated with this CCV were non -detects for the affected analytes; therefore, the data have been reported. Method 8260D: The laboratory control sample and/or the laboratory control sample duplicate (LCS/LCSD) for analytical batch 752-2066 recovered outside control limits for the following analyte(s): Trichlorofluoromethane. Trichlorofluoromethane has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed. Method 8260D: The laboratory control sample duplicate (LCSD) for analytical batch 752-2066 recovered outside control limits for the following analytes: Vinyl chloride. These analytes were biased high in the LCSD and were not detected in the associated samples; therefore, the data have been reported. Method 8260D: The (LCS 752-2066/5) was biased low for: 1, 1 -Dichloroethane, 1,2-Dichloropropane, Benzene, Bromochloromethane, Chlorobenzene, Chloroform, Styrene and trans-1,2-Dichloroethene . All compounds were detected in a reporting limit (RL) sample. All non -detects are reported. Any detections are to be considered estimated values and are qualified. (LCS 752-2066/5) Method 8260D: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for analytical batch 752-2066 recovered outside control limits for several compounds. Method 8260D: The continuing calibration verification (CCV) associated with batch 752-2111 recovered outside acceptance criteria, low biased, for Bromoform, Chloromethane and lodomethane. A reporting limit (RL) standard was analyzed, and the target analytes are detected. Since the associated samples were non -detect for the analyte(s), the data are reported. Method 8260D: The method blank associated with analytical batch 752-2111 contained Chloroform greater than one-half the reporting limit (RL). The samples were not re -analyzed because there out of holding time. The sample results have been qualified and reported. Method 8260D: The method blank for 752-2118 contained Chloroform above the reporting limit (RL). None of the samples associated with this method blank contained the target compound; therefore, re -extraction and/or re -analysis of samples were not performed. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. GC/MS Semi VOA Methods 3510C, CWA_Prep: The following samples listed formed emulsions during the extraction procedure: 4501-MW5 (Background) (752-4652-2), 4501-MW8 (752-4652-3), 4501-MW8 (752-4652-3[MS]), 4501-MW8 (752-4652-3[MSD]), 4501-MW6 (752-4682-1) and 4501-MW7 (752-4682-2). The emulsions were broken up using Sodium Sulfate. Methods 3510C, 608: The following samples listed formed emulsions during the extraction procedure: 4501-MW6 (752-4682-1) and 4501-MW7 (752-4682-2). The emulsions were broken up using Sodium Sulfate. Method 8270D: The continuing calibration verification (CCV) analyzed in batch 680-769649 was outside the method criteria for the following surrogate: 2,4,6-Tribromophenol (Surr). The affected surrogate was however within the method defined surrogate control limits in the CCV. All associated batch QC and samples were also within control limits for this surrogate. Method 8270D: The continuing calibration verification (CCV) associated with batch 680-769649 recovered above the upper control limit for Eurofins Raleigh Page 7 of 242 4/19/2093 Case Narrative Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 (Continued) Job ID: 752-4652-1 Laboratory: Eurofins Raleigh (Continued) a2,4-Dinitrophenol, 2-Nitroaniline, 2-Nitrophenol and 4,6-Dinitro-2-methylphenol. The samples associated with this CCV were non -detects for the affected analytes; therefore, the data have been reported. Method 8270D: The laboratory control sample (LCS) for preparation batch 680-769544 and analytical batch 680-769649 recovered outside control limits for the following analyte: 2,4-Dinitrophenol. This analyte was biased high in the LCS and was not detected in the associated samples; therefore, the data have been reported. Methods 8270D, 8270E: The continuing calibration verification (CCV) analyzed in batch 680-769934 was outside the method criteria for the following surrogates: 2,4,6-Tribromophenol (Surr), 2-Fluorophenol (Surr) and Terphenyl-d14 (Surr). The affected surrogates were however within the method defined surrogate control limits in the CCV. All associated batch QC and samples were also within control limits for these surrogates. Methods 8270D, 8270E: The continuing calibration verification (CCV) associated with batch 680-769934 recovered above the upper control limit for 2,4-Dinitrophenol, 2-Nitrophenol, 4,6-Dinitro-2-methylphenol, 4-Nitrophenol and Butyl benzyl phthalate. The samples associated with this CCV were non -detects for the affected analytes; therefore, the data have been reported. Methods 8270D, 8270E: The continuing calibration verification (CCV) analyzed in batch 680-769934 was outside the method criteria for the following analyte(s): Hexachlorocyclopentadiene. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated. Methods 8270D, 8270E: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch 680-769804 and analytical batch 680-769934 recovered outside control limits for the following analytes: 2,4-Dinitrophenol and 4,6-Dinitro-2-methylphenol. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page HPLC/IC Methods 300.0, 9056A: The method blank for analytical batch 680-771548 contained sulfate above the method detection limit (MDL). Associated sample(s) were not re -analyzed because results were greater than 10X the value found in the method blank. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. GC VOA Method RSK-175: The following sample(s) was analyzed outside of analytical holding time due to failure of instruments auto -sampler. 4501-AMW1S (752-4652-1), 4501-MW5 (Background) (752-4652-2), 4501-MW8 (752-4652-3), 4501-MW8 (752-4652-3[MS]) and 4501-MW8 (752-4652-3[MSD]). Method RSK-175: The following samples were analyzed outside of analytical holding time due to needing a dilution: 4501-MW8 (752-4652-3), 4501-MW8 (752-4652-3[MS]) and 4501-MW8 (752-4652-3[MSD]). Method RSK-175: Reanalysis of the following sample was performed outside of the analytical holding time due to needing a dilution: 4501-Old MW2 (752-4682-7). Method RSK-175: Due to the high concentration of Co2, the matrix spike / matrix spike duplicate (MS/MSD) for analytical batch 200-189761 could not be evaluated for accuracy and precision. The associated laboratory control sample (LCS) met acceptance criteria. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Eurofins Raleigh Page 8 of 242 4/19/2093 Case Narrative Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 (Continued) Job ID: 752-4652-1 Laboratory: Eurofins Raleigh (Continued) GC Semi VOA I Methods 8081 B, 8081 B/8082A: The laboratory control sample (LCS) for preparation batch 680-769227 and analytical batch 680-769499 recovered outside control limits for the following analytes: beta-BHC, delta-BHC and Endrin. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. Methods 8081 B, 8081 B/8082A: Two surrogates are used for this analysis. The laboratory's SOP allows one of these surrogates to be outside acceptance criteria without performing re-extraction/re-analysis. The following sample contained an allowable number of surrogate compounds outside limits: (LCSD 680-769585/6-A). These results have been reported and qualified. Methods 8081 B, 8081 B/8082A: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for preparation batch 680-769585 and analytical batch 680-769834 recovered outside control limits for the following analytes: <AffectedAnalytes>. Method 8151A: Surrogate recovery was outside acceptance limits for the following matrix spike/matrix spike duplicate (MS/MSD) sample: 4501-MW11 (752-4682-4[MSD]). The parent sample's surrogate recovery was within limits. The MS/MSD sample has been qualified and reported Method 8151A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries and precision for preparation batch 680-769824 and analytical batch 680-770343 were outside control limits. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Metals Method 7470A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for preparation batch 680-769300 and analytical batch 680-769538 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference is suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Method 7470A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for preparation batch 680-770494 and analytical batch 680-770613 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference is suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. General Chemistry Methods 376.1, SM 4500 S2 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 680-769240 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 310.1, SM 2320B: The sample duplicate precision for the following sample associated with analytical batch 680-769846 was outside control limits: (680-232426-C-1 DU). The associated Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) precision met acceptance criteria. Methods 335.4, 9012A, 9012B, SM 4500 CN E: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for preparation batch 680-770468 and analytical batch 680-770561 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 353.2, SM4500 NO2 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-1984 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 353.2, SM 4500 NO3 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-1986 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Eurofins Raleigh Page 9 of 242 4/19/2093 Case Narrative C Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Job ID: 752-4652-1 (Continued) Laboratory: Eurofins Raleigh (Continued) Method SM 2540C: TDS/Conductivity ratio out of range 4501-MW10 (752-4682-3) Method SM 254OC: The sample duplicate precision for the following sample associated with analytical batch 752-1940 was outside control limits: 4501-MW12 (752-4682-5) and (752-4682-C-5 DU). The associated Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) precision met acceptance criteria. Method SM 2540C: TDS/Conductivity ratio out of range. 4501-MW13 (752-4682-6), (752-4682-C-4 DU) and (752-4682-C-5 DU) Methods 353.2, SM4500 NO2 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2027 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Method 353.2: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2034 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 353.2, SM 4500 NO3 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2160 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Organic Prep No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. VOA Prep No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. Eurofins Raleigh Page 10 of 242 4/19/2093 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-AMW1S Lab Sample ID: 752-4652-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 1.20 0.500 0.320 ug/L 1 8260 SIM Total/NA Benzene 0.226 J 1.00 0.150 ug/L 1 8260D Total/NA Chlorobenzene 0.789 J 1.00 0.170 ug/L 1 8260D Total/NA Carbon dioxide 297000 H 10000 5000 ug/L 1 RSK-175 Total/NA Methane 257 2.00 1.20 ug/L 1 RSK-175 Total/NA Sulfate 10.5 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 21.8 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Iso-Pentanoic Acid 9.00 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Barium 228 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.570 J 4.00 0.300 ug/L 1 6010D Total Recoverable Cadmium 1.27 J 5.00 0.440 ug/L 1 6010D Total Recoverable Chromium 1.32 J 10.0 1.10 ug/L 1 6010D Total Recoverable Cobalt 5.58 J 10.0 1.40 ug/L 1 6010D Total Recoverable Vanadium 3.32 J 10.0 1.00 ug/L 1 6010D Total Recoverable Thallium 0.280 J 1.00 0.260 ug/L 1 6020B Total Recoverable Alkalinity as CaCO3 to pH 4.5 64.5 5.00 2.20 mg/L 1 2320E-2011 Total/NA Nitrate as N 0.329 0.100 0.0250 mg/L 1 353.2 Total/NA Nitrate Nitrite as N 0.329 0.100 0.0410 mg/L 1 353.2 Total/NA Total Non-purgeable Organic Carbon 2.36 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Oxygen Demand 24.8 10.0 10.0 mg/L 1 SM 5220D Total/NA LChemical Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Carbon dioxide 62100 H 10000 5000 ug/L 1 RSK-175 Total/NA Methane 4.67 2.00 1.20 ug/L 1 RSK-175 Total/NA Sulfate 31.3 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 2.53 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Acetic acid 3.70 J 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Iso-Pentanoic Acid 3.60 J 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Barium 23.3 10.0 4.40 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 34.8 5.00 2.20 mg/L 1 2320B-2011 Total/NA Cyanide, Total 0.00402 J 0.0100 0.00250 mg/L 1 9012B Total/NA Chemical Oxygen Demand 12.2 10.0 10.0 mg/L 1 SM 5220D Total/NA Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.541 0.500 0.320 ug/L 1 8260 SIM Total/NA Methane 223 2.00 1.20 ug/L 1 RSK-175 Total/NA Carbon dioxide - DL 407000 H 2O000 10000 ug/L 2 RSK-175 Total/NA gamma-BHC (Lindane) 0.00791 J p 0.0488 0.000976 ug/L 1 8081B Total/NA Sulfate 11.4 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 39.7 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Barium 581 10.0 4.40 ug/L 1 6010D Total Recoverable This Detection Summary does not include radiochemical test results. Eurofins Raleigh Page 11 of 242 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW8 (Continued) Lab Sample ID: 752-4652-3 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Cobalt 14.4 10.0 1.40 ug/L 1 6010D Total Recoverable Mercury 1.04 F1 0.200 0.0800 ug/L 1 7470A Total/NA Alkalinity as CaCO3 to pH 4.5 563 5.00 2.20 mg/L 1 2320E-2011 Total/NA Total Non-purgeable Organic Carbon 28.0 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Cyanide, Total 0.00841 J F1 0.0100 0.00250 mg/L 1 9012E Total/NA Biochemical Oxygen Demand 3.83 2.00 2.00 mg/L 1 SM 5210B Total/NA Chemical Oxygen Demand 113 10.0 10.0 mg/L 1 SM 5220D Total/NA Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 C Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 21.6 0.500 0.320 ug/L 1 8260 SIM Total/NA Acetone 288 100 50.0 ug/L 5 8260D Total/NA Benzene 1.64 J 5.00 0.750 ug/L 5 8260D Total/NA cis-1,2-Dichloroethene 0.974 J 5.00 0.750 ug/L 5 8260D Total/NA Carbon dioxide 394000 10000 5000 ug/L 1 RSK-175 Total/NA Methane 8320 2.00 1.20 ug/L 1 RSK-175 Total/NA Chloride 98.9 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Acetic acid 25.1 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Iso-Pentanoic Acid 33.2 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Lactic Acid/HIBA (2-Hydroxyisobutyic 19.9 5.00 1.30 mg/L 10 VFA-HPLC Total/NA acid) Barium 185 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.910 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Chromium 2.15 J 10.0 1.10 ug/L 1 6010D Total Recoverable Cobalt 2.12 J 10.0 1.40 ug/L 1 6010D Total Recoverable Copper 8.05 J 20.0 3.20 ug/L 1 6010D Total Recoverable Nickel 5.35 J 40.0 3.30 ug/L 1 6010D Total Recoverable Vanadium 5.52 J 10.0 1.00 ug/L 1 6010D Total Recoverable Zinc 19.3 J 20.0 8.70 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 232 5.00 2.20 mg/L 1 2320E-2011 Total/NA Total Non-purgeable Organic Carbon 22.2 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Cyanide, Total 0.00591 J 0.0100 0.00250 mg/L 1 9012E Total/NA Biochemical Oxygen Demand 13.7 6.00 6.00 mg/L 1 SM 5210B Total/NA Chemical Oxygen Demand 71.1 10.0 10.0 mg/L 1 SM 5220D Total/NA Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 19.4 0.500 0.320 ug/L 1 8260 SIM Total/NA 1,2,4-Trichlorobenzene 1.14 1.00 0.140 ug/L 1 8260D Total/NA 1,2-Dichlorobenzene 0.691 J 1.00 0.190 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 10.2 1.00 0.190 ug/L 1 8260D Total/NA Benzene 0.994 J 1.00 0.150 ug/L 1 8260D Total/NA Chlorobenzene 7.60 1.00 0.170 ug/L 1 8260D Total/NA This Detection Summary does not include radiochemical test results. Page 12 of 242 Eurofins Raleigh 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW7 (Continued) Lab Sample ID: 752-4682-2 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type cis-1,2-Dichloroethene 2.40 1.00 0.150 ug/L 1 8260D Total/NA Methylene Chloride 0.267 J 1.00 0.230 ug/L 1 8260D Total/NA Vinyl chloride 0.805 J .+ 1.00 0.320 ug/L 1 8260D Total/NA Carbon dioxide 387000 10000 5000 ug/L 1 RSK-175 Total/NA Methane 273 2.00 1.20 ug/L 1 RSK-175 Total/NA Heptachlor epoxide 0.00911 J p 0.0475 0.00190 ug/L 1 8081 B Total/NA Sulfate 2.04 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 103 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Acetic acid 7.80 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Iso-Pentanoic Acid 12.5 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Lactic Acid/HIBA (2-Hydroxyisobutyic 12.5 5.00 1.30 mg/L 10 VFA-HPLC Total/NA acid) Barium 575 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 1.19 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cadmium 0.500 J 5.00 0.440 ug/L 1 6010D Total Recoverable Cobalt 2.24 J 10.0 1.40 ug/L 1 6010D Total Recoverable Thallium 0.265 J 1.00 0.260 ug/L 1 60206 Total Recoverable Alkalinity as CaCO3 to pH 4.5 265 5.00 2.20 mg/L 1 2320B-2011 Total/NA Total Non-purgeable Organic Carbon 4.88 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Cyanide, Total 0.00344 J 0.0100 0.00250 mg/L 1 9012B Total/NA Chemical Oxygen Demand 41.6 10.0 10.0 mg/L 1 SM 5220D Total/NA Client Sample ID: 4501-MW10 Lab Sample ID: 752-4682-3 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Chloride 2.28 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Beryllium 1.08 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Copper 3.86 J 20.0 3.20 ug/L 1 6010D Total Recoverable Manganese 6.43 J 10.0 1.30 ug/L 1 6010D Total Recoverable Vanadium 1.38 J 10.0 1.00 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 26.7 5.00 2.20 mg/L 1 2320E-2011 Total/NA Client Sample ID: 4501-MW11 Lab Sample ID: 752-4682-4 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 1.98 0.500 0.320 ug/L 1 8260 SIM Total/NA Benzene 0.499 J 1.00 0.150 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 0.438 J 1.00 0.150 ug/L 1 8260D Total/NA Sulfate 172 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 18.2 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Barium 68.4 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 1.13 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cobalt 2.77 J 10.0 1.40 ug/L 1 6010D Total Recoverable This Detection Summary does not include radiochemical test results. Page 13 of 242 Eurofins Raleigh 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW11 (Continued) Lab Sample ID: 752-4682-4 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Iron 3610 100 20.0 ug/L 1 6010D Total Recoverable Manganese 7660 10.0 1.30 ug/L 1 6010D Total Recoverable Vanadium 1.70 J 10.0 1.00 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 319 5.00 2.20 mg/L 1 2320E-2011 Total/NA Total Dissolved Solids 610 50.0 50.0 mg/L 1 SM 2540C Total/NA Client Sample ID: 4501-MW12 Lab Sample ID: 752-4682-5 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 1.18 0.500 0.320 ug/L 1 8260 SIM Total/NA Benzene 0.368 J 1.00 0.150 ug/L 1 8260D Total/NA Chloromethane 0.908 J 1.00 0.130 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 0.875 J 1.00 0.150 ug/L 1 8260D Total/NA Vinyl chloride 1.04 *+ 1.00 0.320 ug/L 1 8260D Total/NA Sulfate 36.0 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 44.3 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Barium 20.6 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 1.02 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Iron 48.6 J 100 20.0 ug/L 1 6010D Total Recoverable Manganese 914 10.0 1.30 ug/L 1 6010D Total Recoverable Vanadium 1.74 J 10.0 1.00 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 152 5.00 2.20 mg/L 1 2320E-2011 Total/NA Total Dissolved Solids 274 50.0 50.0 mg/L 1 SM 2540C Total/NA Client Sample ID: 4501-MW13 Lab Sample ID: 752-4682-6 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 3.55 0.500 0.320 ug/L 1 8260 SIM Total/NA Benzene 0.255 J 1.00 0.150 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 1.45 1.00 0.150 ug/L 1 8260D Total/NA Tetrahydrofuran 13.8 1.00 0.530 ug/L 1 8260D Total/NA Vinyl chloride 0.596 J *+ 1.00 0.320 ug/L 1 8260D Total/NA 2,4-D 0.173 J p 1.03 0.168 ug/L 1 8151A Total/NA Sulfate 27.7 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 19.9 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Barium 17.6 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.840 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cobalt 4.34 J 10.0 1.40 ug/L 1 6010D Total Recoverable Iron 1510 100 20.0 ug/L 1 6010D Total Recoverable Manganese 831 10.0 1.30 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 136 5.00 2.20 mg/L 1 2320B-2011 Total/NA Total Dissolved Solids 472 100 100 mg/L 1 SM 2540C Total/NA This Detection Summary does not include radiochemical test results. Eurofins Raleigh Page 14 of 242 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Old MW2 Lab Sample ID: 752-4682-7 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,1-Dichloroethane 0.248 J 1.00 0.130 ug/L 1 8260D Total/NA Methane 92.3 2.00 1.20 ug/L 1 RSK-175 Total/NA Carbon dioxide - DL 744000 H 40000 20000 ug/L 4 RSK-175 Total/NA Sulfate 2.76 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 34.3 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Acetic acid 6.60 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Iso-Pentanoic Acid 5.19 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Alkalinity as CaCO3 to pH 4.5 175 5.00 2.20 mg/L 1 2320B-2011 Total/NA Total Non-purgeable Organic Carbon 2.88 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Client Sample ID: 4501-AMW2S Lab Sample ID: 752-4748-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 2.67 0.500 0.320 ug/L 1 8260 SIM Total/NA 1,1-Dichloroethane 0.409 J 1.00 0.130 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 0.715 J 1.00 0.190 ug/L 1 8260D Total/NA Benzene 0.189 J 1.00 0.150 ug/L 1 8260D Total/NA Chlorobenzene 0.677 J 1.00 0.170 ug/L 1 8260D Total/NA Chloroform 0.315 J B 1.00 0.180 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 0.273 J 1.00 0.150 ug/L 1 8260D Total/NA Methylene Chloride 0.308 J B 1.00 0.230 ug/L 1 8260D Total/NA Carbon dioxide 147000 10000 5000 ug/L 1 RSK-175 Total/NA Methane 34.7 2.00 1.20 ug/L 1 RSK-175 Total/NA Sulfate 0.621 J 1.00 0.400 mg/L 1 300.0-1993 R2.1 Total/NA Chloride 17.4 0.500 0.200 mg/L 1 300.0-1993 R2.1 Total/NA Iso-Pentanoic Acid 2.55 J 5.00 1.80 mg/L 10 VFA-HPLC Total/NA Lactic Acid/HIBA (2-Hydroxyisobutyic 3.04 J 5.00 1.30 mg/L 10 VFA-HPLC Total/NA acid) Beryllium 0.550 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Alkalinity as CaCO3 to pH 4.5 106 5.00 2.20 mg/L 1 2320B-2011 Total/NA Total Non-purgeable Organic Carbon 1.02 1.00 0.500 mg/L 1 5310 B-2011 Total/NA Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Acetone 10.0 J 20.0 10.0 ug/L 1 8260D Total/NA Chloroform 0.260 J B 1.00 0.180 ug/L 1 8260D Total/NA Methylene Chloride 0.362 J B 1.00 0.230 ug/L 1 8260D Total/NA Beryllium 0.640 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cyanide, Total 0.00445 J 0.0100 0.00250 mg/L 1 9012B Total/NA Client Sample ID: 4501-AMW1D Lab Sample ID: 752-4750-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 12.2 0.500 0.320 ug/L 1 8260 SIM Total/NA 1,1-Dichloroethane 0.239 J*-*1 1.00 0.130 ug/L 1 8260D Total/NA 1,2-Dichlorobenzene 0.538 J *1 1.00 0.190 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 3.70 *1 1.00 0.190 ug/L 1 8260D Total/NA Benzene 1.05 *- *1 1.00 0.150 ug/L 1 8260D Total/NA Chlorobenzene 9.73 *- *1 1.00 0.170 ug/L 1 8260D Total/NA cis-1,2-Dichloroethene 0.878 J *1 B 1.00 0.150 ug/L 1 8260D Total/NA This Detection Summary does not include radiochemical test results. Eurofins Raleigh Page 15 of 242 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-AMW1D (Continued) Lab Sample ID: 752-4750-1 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Barium 14.2 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.570 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Client Sample ID: 4501-AMW2D Lab Sample ID: 752-4750-2 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 1.38 0.500 0.320 ug/L 1 8260 SIM Total/NA 1,1-Dichloroethane 0.331 J*-*1 1.00 0.130 ug/L 1 8260D Total/NA Beryllium 0.510 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Client Sample ID: 4501-BR1 Lab Sample ID: 752-4750-3 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.794 0.500 0.320 ug/L 1 8260 SIM Total/NA Chloroform 0.244 J B 1.00 0.180 ug/L 1 8260D Total/NA Barium 29.3 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.590 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Vanadium 1.06 J 10.0 1.00 ug/L 1 6010D Total Recoverable Client Sample ID: 4501-BR2 Lab Sample ID: 752-4750-4 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 7.78 0.500 0.320 ug/L 1 8260 SIM Total/NA 1,2-Dichlorobenzene 0.323 J 1.00 0.190 ug/L 1 8260D Total/NA 1,4-Dichlorobenzene 1.29 1.00 0.190 ug/L 1 8260D Total/NA Chlorobenzene 0.541 J 1.00 0.170 ug/L 1 8260D Total/NA Chloroform 0.280 J B 1.00 0.180 ug/L 1 8260D Total/NA Methylene Chloride 0.486 J B 1.00 0.230 ug/L 1 8260D Total/NA Barium 178 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.530 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cobalt 2.36 J 10.0 1.40 ug/L 1 6010D Total Recoverable Client Sample ID: 4501-BR3 Lab Sample ID: 752-4750-5 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 0.989 0.500 0.320 ug/L 1 8260 SIM Total/NA Chlorobenzene 0.210 J 1.00 0.170 ug/L 1 8260D Total/NA Chloroform 0.293 J B 1.00 0.180 ug/L 1 8260D Total/NA Methylene Chloride 0.256 J B 1.00 0.230 ug/L 1 8260D Total/NA Barium 219 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.930 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Cadmium 1.07 J 5.00 0.440 ug/L 1 6010D Total Recoverable Cobalt 3.22 J 10.0 1.40 ug/L 1 6010D Total Recoverable This Detection Summary does not include radiochemical test results. Page 16 of 242 Eurofins Raleigh 4/19/2023 Detection Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-BR3 (Continued) Lab Sample ID: 752-4750-5 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Nickel 6.16 J 40.0 3.30 ug/L 1 6010D Total Recoverable Zinc 39.7 20.0 8.70 ug/L 1 6010D Total Recoverable Client Sample ID: 4501-SW1 Lab Sample ID: 752-4750-6 Analyte Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 1,4-Dioxane 1.63 0.500 0.320 ug/L 1 8260 SIM Total/NA Chloroform 0.223 J B 1.00 0.180 ug/L 1 8260D Total/NA Barium 35.0 10.0 4.40 ug/L 1 6010D Total Recoverable Beryllium 0.570 J B 4.00 0.300 ug/L 1 6010D Total Recoverable Zinc 12.6 J 20.0 8.70 ug/L 1 601OD Total Recoverable Client Samplf Analyte Chloroform Methylene Chloride Barium Beryllium Copper Silver ID: 4501-MW9 Result Qualifier RL MDL Unit 0.262 J B 1.00 0.180 ug/L 0.294 J B 1.00 0.230 ug/L 86.8 10.0 4.40 ug/L 1.89 J B 4.00 0.300 ug/L 14.8 J 20.0 3.20 ug/L 1.59 J 10.0 1.50 ug/L V 11011L %20111 PM ILJ. "FJLI 1-1111J UIQI II% Analyte Result Qualifier RL MDL Unit Chloroform 0.503 J B 1.00 0.180 ug/L Methylene Chloride 0.470 J B 1.00 0.230 ug/L This Detection Summary does not include radiochemical test results. Lab Sample ID: 752-4750-7 Dil Fac D Method Prep Type 1 8260D Total/NA 1 8260D Total/NA 1 6010D Total Recoverable 1 6010D Total Recoverable 1 6010D Total Recoverable 1 6010D Total Recoverable Lab Sample ID: 752-4750-8 Dil Fac D Method Prep Type 1 8260D Total/NA 1 8260D Total/NA Eurofins Raleigh Page 17 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW1S Lab Sample ID: 752-4652-1 Date Collected: 03/20/23 15:54 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane 1.20 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 76 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene <0.190 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,4-Dichlorobenzene <0.190 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene 0.226 J 1.00 Bromochloromethane <0.480 1.00 Bromodichloromethane <0.170 1.00 Bromoform <0.220 1.00 Bromomethane <0.140 1.00 Carbon disulfide <1.50 5.00 Carbon tetrachloride <0.170 1.00 Chlorobenzene 0.789 J 1.00 Chloroethane <0.230 1.00 Chloroform <0.180 1.00 Chloromethane <0.130 1.00 cis-1,2-Dichloroethene <0.150 1.00 cis-1,3-Dichloropropene <0.200 1.00 Dibromochloromethane <0.170 1.00 Dibromomethane <0.270 1.00 Ethylbenzene <0.130 1.00 lodomethane <1.70 5.00 Methylene Chloride <0.230 1.00 Styrene <0.110 1.00 Tetrachloroethene <0.170 1.00 Toluene <0.140 1.00 trans- 1,2-Dichloroethene <0.210 1.00 trans- 1,3-Dichloropropene <0.150 1.00 trans- 1,4-Dichloro-2-butene <0.700 1.00 Trichloroethene <0.150 1.00 MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/31/2314:53 1 • Prepared Analyzed Dil Fac 03/31/23 14:53 1 MDL Unit D Prepared Analyzed Dil Fac C 0.170 ug/L 04/01/23 00:36 1 0.120 ug/L 04/01/23 00:36 1 0.280 ug/L 04/01/23 00:36 1 0.140 ug/L 04/01/23 00:36 1 0.130 ug/L 04/01/23 00:36 1 0.210 ug/L 04/01/23 00:36 1 0.490 ug/L 04/01/23 00:36 1 0.480 ug/L 04/01/23 00:36 1 0.660 ug/L 04/01/23 00:36 1 0.190 ug/L 04/01/23 00:36 1 0.210 ug/L 04/01/23 00:36 1 0.100 ug/L 04/01/23 00:36 1 0.190 ug/L 04/01/23 00:36 1 10.0 ug/L 04/01/23 00:36 1 0.880 ug/L 04/01/23 00:36 1 1.10 ug/L 04/01/23 00:36 1 10.0 ug/L 04/01/23 00:36 1 3.50 ug/L 04/01/23 00:36 1 0.150 ug/L 04/01/23 00:36 1 0.480 ug/L 04/01/23 00:36 1 0.170 ug/L 04/01/23 00:36 1 0.220 ug/L 04/01/23 00:36 1 0.140 ug/L 04/01/23 00:36 1 1.50 ug/L 04/01/23 00:36 1 0.170 ug/L 04/01/23 00:36 1 0.170 ug/L 04/01/23 00:36 1 0.230 ug/L 04/01/23 00:36 1 0.180 ug/L 04/01/23 00:36 1 0.130 ug/L 04/01/23 00:36 1 0.150 ug/L 04/01/23 00:36 1 0.200 ug/L 04/01/23 00:36 1 0.170 ug/L 04/01/23 00:36 1 0.270 ug/L 04/01/23 00:36 1 0.130 ug/L 04/01/23 00:36 1 1.70 ug/L 04/01/23 00:36 1 0.230 ug/L 04/01/23 00:36 1 0.110 ug/L 04/01/23 00:36 1 0.170 ug/L 04/01/23 00:36 1 0.140 ug/L 04/01/23 00:36 1 0.210 ug/L 04/01/23 00:36 1 0.150 ug/L 04/01/23 00:36 1 0.700 ug/L 04/01/23 00:36 1 0.150 ug/L 04/01/23 00:36 1 Eurofins Raleigh Page 18 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW1S Lab Sample ID: 752-4652-1 Date Collected: 03/20/23 15:54 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichlorofluoromethane <0.240 *+ 1.00 0.240 ug/L 04/01/23 00:36 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/01/23 00:36 1 �. Vinyl chloride <0.320 *+ 1.00 0.320 ug/L 04/01/23 00:36 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/01/23 00:36 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 114 53 - 136 04101123 00736 1 Dibromofluoromethane (Surr) 104 67- 129 04101123 00:36 1 Toluene-d8 (Surr) 102 59 - 134 04101123 00:36 1 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 297000 H 10000 5000 ug/L 03/28/23 07:58 1 Ethane <1.70 4.00 1.70 ug/L 03/29/2314:10 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2314:10 1 Methane 257 2.00 1.20 ug/L 03/29/2314:10 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac C Acetylene 84 50 - 150 03/29/23 14:10 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 10.5 1.00 0.400 mg/L 04/05/23 21:07 1 Chloride 21.8 0.500 0.200 mg/L 04/05/23 21:07 1 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid <1.80 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid 9.00 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA (2-Hydroxyisobutyic <1.30 5.00 1.30 mg/L 03/29/23 19:50 10 acid) Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Trimethylacetic Acid 03/29/23 19:50 10 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/31/2311:02 03/31/2319:34 1 Barium 228 10.0 4.40 ug/L 03/31/2311:02 03/31/2319:34 1 Beryllium 0.570 J 4.00 0.300 ug/L 03/31/2311:02 03/31/2319:34 1 Cadmium 1.27 J 5.00 0.440 ug/L 03/31/2311:02 03/31/2319:34 1 Chromium 1.32 J 10.0 1.10 ug/L 03/31/2311:02 03/31/2319:34 1 Cobalt 5.58 J 10.0 1.40 ug/L 03/31/2311:02 03/31/2319:34 1 Copper <3.20 20.0 3.20 ug/L 03/31/2311:02 03/31/2319:34 1 Lead <6.60 10.0 6.60 ug/L 03/31/2311:02 03/31/2319:34 1 Eurofins Raleigh Page 19 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW1S Lab Sample ID: 752-4652-1 Date Collected: 03/20/23 15:54 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) Analyte Result Qualifier RL MDL Unit Nickel <3.30 40.0 3.30 ug/L Selenium <10.0 20.0 10.0 ug/L Silver <1.50 10.0 1.50 ug/L Vanadium 3.32 J 10.0 1.00 ug/L Zinc <8.70 20.0 8.70 ug/L Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit Antimony <0.340 5.00 0.340 ug/L Thallium 0.280 J 1.00 0.260 ug/L Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit Mercury <0.0800 0.200 0.0800 ug/L General Chemistry Analyte Result Qualifier RL MDL Unit Alkalinity as CaCO3 to pH 4.5 (SM 64.5 5.00 2.20 mg/L 2320113-2011) Nitrate as N (EPA 353.2) 0.329 0.100 0.0250 mg/L Nitrate Nitrite as N (EPA 353.2) 0.329 0.100 0.0410 mg/L Nitrite as N (EPA 353.2) <0.0168 0.100 0.0168 mg/L Total Non-purgeable Organic 2.36 1.00 0.500 mg/L Carbon (SM 5310 B-2011) Chemical Oxygen Demand (SM 24.8 10.0 10.0 mg/L 5220D) Analyte Result Qualifier RL RL Unit Sulfide (SM 4500 S2 F-2011) <0.962 0.962 0.962 mg/L Biochemical Oxygen Demand (SM <2.00 2.00 2.00 mg/L 5210B) Client Sample ID: 4501-MW5 (Background) Date Collected: 03/20/23 10:09 Date Received: 03/21/23 09:20 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane <0.320 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 128 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 1.00 1,1-Dichloropropene <0.150 1.00 1,2,3-Trichloropropane <0.490 1.00 D Prepared Analyzed Dil Fac 03/31/2311:02 03/31/2319:34 1 03/31/2311:02 03/31/2319:34 1 03/31/2311:02 03/31/2319:34 1 03/31/2311:02 03/31/2319:34 1 03/31 /23 11:02 03/31 /23 19:34 1 D Prepared Analyzed Dil Fac 03/31/2311:02 04/03/2315:42 1 03/31/2311:02 04/03/2315:42 1 D Prepared Analyzed Dil Fac 04/03/2311:03 04/03/2318:38 1 D Prepared Analyzed Dil Fac 03/25/23 01:04 1 03/29/23 15:40 1 03/27/23 12:03 1 03/21/23 16:43 1 04/02/23 03:56 1 03/22/23 17:43 1 D Prepared Analyzed Dil Fac 03/23/23 10:41 1 03/21/23 15:12 1 Lab Sample ID: 752-4652-2 Matrix: Ground Water MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/29/23 22:15 1 Prepared Analyzed Dil Fac 03/29/23 22:15 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/01/23 01:05 1 0.120 ug/L 04/01/23 01:05 1 0.280 ug/L 04/01/23 01:05 1 0.140 ug/L 04/01/23 01:05 1 0.130 ug/L 04/01/23 01:05 1 0.210 ug/L 04/01/23 01:05 1 0.150 ug/L 04/01/23 01:05 1 0.490 ug/L 04/01/23 01:05 1 Eurofins Raleigh Page 20 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4-Trichlorobenzene <0.140 1.00 0.140 ug/L 04/01/23 01:05 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/01/23 01:05 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/01/23 01:05 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/01/23 01:05 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/01/23 01:05 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/01/23 01:05 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 04/01/23 01:05 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 04/01/23 01:05 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/01/23 01:05 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 04/01/23 01:05 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/01/23 01:05 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/01/23 01:05 1 3-Chloropropene <0.110 1.00 0.110 ug/L 04/01/23 01:05 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/01/23 01:05 1 Acetone <10.0 20.0 10.0 ug/L 04/01/23 01:05 1 Acetonitrile <5.00 10.0 5.00 ug/L 04/01/23 01:05 1 Acrolein <4.00 10.0 4.00 ug/L 04/01/23 01:05 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/01/23 01:05 1 Benzene <0.150 1.00 0.150 ug/L 04/01/23 01:05 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/01/23 01:05 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/01/23 01:05 1 Bromoform <0.220 1.00 0.220 ug/L 04/01/23 01:05 1 Bromomethane <0.140 1.00 0.140 ug/L 04/01/23 01:05 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/01/23 01:05 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/01/23 01:05 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/01/23 01:05 1 Chloroethane <0.230 1.00 0.230 ug/L 04/01/23 01:05 1 Chloroform <0.180 1.00 0.180 ug/L 04/01/23 01:05 1 Chloromethane <0.130 1.00 0.130 ug/L 04/01/23 01:05 1 Chloroprene <0.640 1.00 0.640 ug/L 04/01/23 01:05 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/01/23 01:05 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/01/23 01:05 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/01/23 01:05 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/01/23 01:05 1 Dichlorodifluoromethane <0.200 "+ 1.00 0.200 ug/L 04/01/23 01:05 1 Ethyl methacrylate <0.380 1.00 0.380 ug/L 04/01/23 01:05 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/01/23 01:05 1 Hexachlorobutadiene <0.220 1.00 0.220 ug/L 04/01/23 01:05 1 lodomethane <1.70 5.00 1.70 ug/L 04/01/23 01:05 1 Isobutyl alcohol <11.0 50.0 11.0 ug/L 04/01/23 01:05 1 Methacrylonitrile <4.90 10.0 4.90 ug/L 04/01/23 01:05 1 Methyl methacrylate <0.510 1.00 0.510 ug/L 04/01/23 01:05 1 Methylene Chloride <0.230 1.00 0.230 ug/L 04/01/23 01:05 1 Naphthalene <0.110 1.00 0.110 ug/L 04/01/23 01:05 1 Propionitrile <5.00 10.0 5.00 ug/L 04/01/23 01:05 1 Styrene <0.110 1.00 0.110 ug/L 04/01/23 01:05 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/01/23 01:05 1 Toluene <0.140 1.00 0.140 ug/L 04/01/23 01:05 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/01/23 01:05 1 0 Eurofins Raleigh Page 21 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/01/23 01:05 1 trans- l,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/01/23 01:05 1 �. Trichloroethene <0.150 1.00 0.150 ug/L 04/01/23 01:05 1 Trichlorofluoromethane <0.240 *+ 1.00 0.240 ug/L 04/01/23 01:05 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/01/23 01:05 1 Vinyl chloride <0.320 *+ 1.00 0.320 ug/L 04/01/23 01:05 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/01/23 01:05 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 110 53 - 136 04101123 01:05 1 Dibromofluoromethane (Surr) 106 67- 129 04101123 01:05 1 Toluene-d8 (Surr) 103 59 - 134 04101123 01:05 1 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4,5-Tetrachlorobenzene <4.28 9.51 4.28 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,3,4,6-Tetrachlorophenol <4.09 9.51 4.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4,5-Trichlorophenol <3.14 9.51 3.14 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4,6-Trichlorophenol <2.09 9.51 2.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4-Dichlorophenol <3.52 9.51 3.52 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4-Dimethylphenol <2.85 9.51 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4-Dinitrophenol <15.2 *+ 47.6 15.2 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,4-Dinitrotoluene <2.19 9.51 2.19 ug/L 03/24/23 14:39 03/25/23 22:10 1 2,6-Dinitrotoluene <2.66 9.51 2.66 ug/L 03/24/23 14:39 03/25/23 22:10 1 2-Chloronaphthalene <4.57 9.51 4.57 ug/L 03/24/23 14:39 03/25/23 22:10 1 2-Chlorophenol <3.04 9.51 3.04 ug/L 03/24/23 14:39 03/25/23 22:10 1 2-Methylphenol <1.71 9.51 1.71 ug/L 03/24/23 14:39 03/25/23 22:10 1 2-Nitroaniline <2.76 47.6 2.76 ug/L 03/24/23 14:39 03/25/23 22:10 1 2-Nitrophenol <3.71 9.51 3.71 ug/L 03/24/23 14:39 03/25/23 22:10 1 3 & 4 Methylphenol <1.33 9.51 1.33 ug/L 03/24/23 14:39 03/25/23 22:10 1 3,3'-Dichlorobenzidine <9.51 57.1 9.51 ug/L 03/24/23 14:39 03/25/23 22:10 1 3-Nitroaniline <2.85 47.6 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 4,6-Dinitro-2-methylphenol <5.04 47.6 5.04 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Bromophenyl phenyl ether <4.47 9.51 4.47 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Chloro-3-methylphenol <2.38 9.51 2.38 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Chloroaniline <0.951 19.0 0.951 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Chlorophenyl phenyl ether <5.04 9.51 5.04 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Nitroaniline <2.85 47.6 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 4-Nitrophenol <7.70 47.6 7.70 ug/L 03/24/23 14:39 03/25/23 22:10 1 Acenaphthene <4.18 9.51 4.18 ug/L 03/24/23 14:39 03/25/23 22:10 1 Acenaphthylene <3.42 9.51 3.42 ug/L 03/24/23 14:39 03/25/23 22:10 1 Acetophenone <2.09 9.51 2.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 Anthracene <3.42 9.51 3.42 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzo[a]anthracene <3.99 9.51 3.99 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzo[a]pyrene <2.66 9.51 2.66 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzo[k]fluoranthene <2.95 9.51 2.95 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzo[g,h,i]perylene <2.85 9.51 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzo[k]fluoranthene <2.76 9.51 2.76 ug/L 03/24/23 14:39 03/25/23 22:10 1 Benzyl alcohol <2.47 9.51 2.47 ug/L 03/24/23 14:39 03/25/23 22:10 1 bis (2-chloroisopropyl) ether <2.95 9.51 2.95 ug/L 03/24/23 14:39 03/25/23 22:10 1 Eurofins Raleigh Page 22 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Bis(2-chloroethoxy)methane <1.71 9.51 1.71 ug/L 03/24/23 14:39 03/25/23 22:10 1 Bis(2-chloroethyl)ether <3.42 9.51 3.42 ug/L 03/24/23 14:39 03/25/23 22:10 1 Bis(2-ethylhexyl) phthalate <2.85 9.51 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 Butyl benzyl phthalate <2.66 9.51 2.66 ug/L 03/24/23 14:39 03/25/23 22:10 1 Chrysene <3.61 9.51 3.61 ug/L 03/24/23 14:39 03/25/23 22:10 1 Dibenz(a,h)anthracene <2.85 9.51 2.85 ug/L 03/24/23 14:39 03/25/23 22:10 1 Dibenzofuran <1.81 9.51 1.81 ug/L 03/24/23 14:39 03/25/23 22:10 1 Diethyl phthalate <2.09 9.51 2.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 Di-n-butyl phthalate <2.19 9.51 2.19 ug/L 03/24/23 14:39 03/25/23 22:10 1 Di-n-octyl phthalate <2.66 9.51 2.66 ug/L 03/24/23 14:39 03/25/23 22:10 1 Fluoranthene <1.52 9.51 1.52 ug/L 03/24/23 14:39 03/25/23 22:10 1 Fluorene <3.23 9.51 3.23 ug/L 03/24/23 14:39 03/25/23 22:10 1 Hexachlorobenzene <1.52 9.51 1.52 ug/L 03/24/23 14:39 03/25/23 22:10 1 Hexachlorocyclopentadiene <3.33 9.51 3.33 ug/L 03/24/23 14:39 03/25/23 22:10 1 Hexachloroethane <3.42 9.51 3.42 ug/L 03/24/23 14:39 03/25/23 22:10 1 Indeno[1,2,3-cd]pyrene <4.09 9.51 4.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 Isophorone <1.90 9.51 1.90 ug/L 03/24/23 14:39 03/25/23 22:10 1 Nitrobenzene <3.33 9.51 3.33 ug/L 03/24/23 14:39 03/25/23 22:10 1 N-Nitrosodimethylamine <2.00 9.51 2.00 ug/L 03/24/23 14:39 03/25/23 22:10 1 N-Nitrosodi-n-propylamine <2.28 9.51 2.28 ug/L 03/24/23 14:39 03/25/23 22:10 1 N-Nitrosodiphenylamine <2.76 9.51 2.76 ug/L 03/24/23 14:39 03/25/23 22:10 1 Phenanthrene <4.09 9.51 4.09 ug/L 03/24/23 14:39 03/25/23 22:10 1 Phenol <1.43 9.51 1.43 ug/L 03/24/23 14:39 03/25/23 22:10 1 Pyrene <3.52 9.51 3.52 ug/L 03/24/23 14:39 03/25/23 22:10 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4, 6-Tribromophenol (Surr) 96 30 - 130 03/24/23 14:39 03/25/23 22:10 1 2-Fluorobiphenyl (Surr) 65 25 - 130 03124123 14:39 03125123 22:10 1 2-Fluorophenol (Surr) 40 10 - 130 03124123 14:39 03125123 22:10 1 Nitrobenzene-d5 (Surr) 69 30 - 130 03/24/23 14:39 03/25/23 22:10 1 Phenol-d5 (Surr) 28 10 - 130 03/24/23 14:39 03/25/23 22:10 1 Terphenyl-d 14 (Surr) 71 35 - 131 03/24/23 14:39 03/25/23 22:10 1 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 62100 H 10000 5000 ug/L 03/28/23 08:07 1 Methane 4.67 2.00 1.20 ug/L 03/29/2314:19 1 Ethane <1.70 4.00 1.70 ug/L 03/29/2314:19 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2314:19 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 87 50 - 150 03/29/23 14:19 1 Method: SW846 8081 B - Organochlorine Pesticides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00197 0.0494 0.00197 ug/L 03/23/2310:01 03/24/2319:59 1 4,4'-DDE <0.000987 0.0494 0.000987 ug/L 03/23/2310:01 03/24/2319:59 1 4,4'-DDT <0.000987 0.0494 0.000987 ug/L 03/23/2310:01 03/24/2319:59 1 Aldrin <0.00197 0.0494 0.00197 ug/L 03/23/2310:01 03/24/2319:59 1 alpha-BHC <0.000987 0.0494 0.000987 ug/L 03/23/2310:01 03/24/2319:59 1 Eurofins Raleigh Page 23 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8081 B - Organochlorine Pesticides (GC) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac beta-BHC <0.00197 *+ 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Chlordane (technical) <0.158 0.494 0.158 ug/L 03/23/23 10:01 03/24/23 19:59 1 Chlorobenzilate <0.632 2.96 0.632 ug/L 03/23/23 10:01 03/24/23 19:59 1 delta-BHC <0.00197 *+ 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Dieldrin <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Endosulfan I <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Endosulfan 11 <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Endosulfan sulfate <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Endrin <0.000987 *+ 0.0494 0.000987 ug/L 03/23/23 10:01 03/24/23 19:59 1 Endrin aldehyde <0.00395 0.0494 0.00395 ug/L 03/23/23 10:01 03/24/23 19:59 1 gamma-BHC (Lindane) <0.000987 0.0494 0.000987 ug/L 03/23/23 10:01 03/24/23 19:59 1 Heptachlor <0.000987 0.0494 0.000987 ug/L 03/23/23 10:01 03/24/23 19:59 1 Heptachlor epoxide <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Isodrin <0.0109 0.0494 0.0109 ug/L 03/23/23 10:01 03/24/23 19:59 1 Kepone <2.57 4.94 2.57 ug/L 03/23/23 10:01 03/24/23 19:59 1 Methoxychlor <0.00197 0.0494 0.00197 ug/L 03/23/23 10:01 03/24/23 19:59 1 Toxaphene <0.306 4.94 0.306 ug/L 03/23/23 10:01 03/24/23 19:59 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 96 30- 130 03/23/23 10:01 03/24/23 19:59 1 Tetrachloro-m-xylene 75 30 - 130 03/23/23 10:01 03/24/23 19:59 1 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac PCB-1016 <0.316 0.987 0.316 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1221 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1232 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1242 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1248 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1254 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 PCB-1260 <0.336 0.987 0.336 ug/L 03/23/23 10:01 03/24/23 19:59 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Tetrachloro-m-xylene 75 30 - 130 03/23/23 10:01 03/24/23 19:59 1 DCB Decachlorobiphenyl 96 30 - 130 03/23/23 10:01 03/24/23 19:59 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0226 0.246 0.0226 ug/L 03/23/23 09:39 03/28/23 04:41 1 Dinoseb <0.0983 0.492 0.0983 ug/L 03/23/23 09:39 03/28/23 04:41 1 Silvex (2,4,5-TP) <0.0944 0.836 0.0944 ug/L 03/23/23 09:39 03/28/23 04:41 1 2,4,5-T <0.138 0.836 0.138 ug/L 03/23/23 09:39 03/28/23 04:41 1 2,4-D <0.177 1.08 0.177 ug/L 03/23/23 09:39 03/28/23 04:41 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 110 26 - 137 03/23/23 09:39 03/28/23 04:41 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 31.3 1.00 0.400 mg/L 04/05/23 21:20 1 Chloride 2.53 0.500 0.200 mg/L 04/05/23 21:20 1 Eurofins Raleigh Page 24 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid 3.70 J 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 �. Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid 3.60 J 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA (2-Hydroxyisobutyic <1.30 5.00 1.30 mg/L 03/29/23 19:50 to acid) Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Trimethylacetic Acid 03/29/23 19:50 10 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/23/23 06:57 03/23/23 17:17 1 Barium 23.3 10.0 4.40 ug/L 03/23/23 06:57 03/23/23 17:17 1 Beryllium <0.300 4.00 0.300 ug/L 03/23/23 06:57 03/23/23 17:17 1 Cadmium <0.440 5.00 0.440 ug/L 03/23/23 06:57 03/23/23 17:17 1 Chromium <1.10 10.0 1.10 ug/L 03/23/23 06:57 03/23/23 17:17 1 Cobalt <1.40 10.0 1.40 ug/L 03/23/23 06:57 03/23/23 17:17 1 Copper <3.20 20.0 3.20 ug/L 03/23/23 06:57 03/23/23 17:17 1 Lead <6.60 10.0 6.60 ug/L 03/23/23 06:57 03/23/23 17:17 1 Nickel <3.30 40.0 3.30 ug/L 03/23/23 06:57 03/23/23 17:17 1 Selenium <10.0 20.0 10.0 ug/L 03/23/23 06:57 03/23/23 17:17 1 Silver <1.50 10.0 1.50 ug/L 03/23/23 06:57 03/23/23 17:17 1 Tin <11.0 50.0 11.0 ug/L 03/23/23 06:57 03/23/23 17:17 1 Vanadium <1.00 10.0 1.00 ug/L 03/23/23 06:57 03/23/23 17:17 1 Zinc <8.70 20.0 8.70 ug/L 03/23/23 06:57 03/23/23 17:17 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/23/23 06:57 03/23/23 20:30 1 Thallium <0.260 1.00 0.260 ug/L 03/23/23 06:57 03/23/23 20:30 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/23/2313:17 03/23/2319:11 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 34.8 5.00 2.20 mg/L 03/25/23 00:56 1 2320B-2011) Nitrate as N (EPA 353.2) <0.0250 0.100 0.0250 mg/L 03/29/23 15:40 1 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 0.0410 mg/L 03/27/23 12:08 1 Nitrite as N (EPA 353.2) <0.0168 0.100 0.0168 mg/L 03/21/23 16:44 1 Total Non-purgeable Organic Carbon <0.500 1.00 0.500 mg/L 04/02/23 04:14 1 (SM 5310 B-2011) Cyanide, Total (SW846 9012B) 0.00402 J 0.0100 0.00250 mg/L 03/30/23 08:29 03/30/23 12:28 1 Chemical Oxygen Demand (SM 12.2 10.0 10.0 mg/L 03/22/23 17:43 1 5220D) Eurofins Raleigh Page 25 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Analyte Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac Sulfide (SM 4500 S2 F-2011) <0.962 0.962 0.962 mg/L 03/23/23 10:41 1 Biochemical Oxygen Demand (SM <2.00 2.00 2.00 mg/L 03/21/23 15:07 1 5210B) • Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 0.541 0.500 0.320 ug/L 03/31/2315:20 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 88 70 - 130 03/31/23 15:20 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/01/23 01:34 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/01/23 01:34 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/01/23 01:34 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/01/23 01:34 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/01/23 01:34 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/01/23 01:34 1 1,1-Dichloropropene <0.150 1.00 0.150 ug/L 04/01/23 01:34 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/01/23 01:34 1 1,2,4-Trichlorobenzene <0.140 1.00 0.140 ug/L 04/01/23 01:34 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/01/23 01:34 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/01/23 01:34 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/01/23 01:34 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/01/23 01:34 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/01/23 01:34 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 04/01/23 01:34 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 04/01/23 01:34 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/01/23 01:34 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 04/01/23 01:34 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/01/23 01:34 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/01/23 01:34 1 3-Chloropropene <0.110 1.00 0.110 ug/L 04/01/23 01:34 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/01/23 01:34 1 Acetone <10.0 20.0 10.0 ug/L 04/01/23 01:34 1 Acetonitrile <5.00 10.0 5.00 ug/L 04/01/23 01:34 1 Acrolein <4.00 10.0 4.00 ug/L 04/01/23 01:34 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/01/23 01:34 1 Benzene <0.150 1.00 0.150 ug/L 04/01/23 01:34 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/01/23 01:34 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/01/23 01:34 1 Bromoform <0.220 1.00 0.220 ug/L 04/01/23 01:34 1 Bromomethane <0.140 1.00 0.140 ug/L 04/01/23 01:34 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/01/23 01:34 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/01/23 01:34 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/01/23 01:34 1 Chloroethane <0.230 1.00 0.230 ug/L 04/01/23 01:34 1 Eurofins Raleigh Page 26 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit Chloroform <0.180 1.00 0.180 ug/L Chloromethane <0.130 1.00 0.130 ug/L Chloroprene <0.640 1.00 0.640 ug/L cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L Dibromochloromethane <0.170 1.00 0.170 ug/L Dibromomethane <0.270 1.00 0.270 ug/L Dichlorodifluoromethane <0.200 `+ F1 1.00 0.200 ug/L Ethyl methacrylate <0.380 1.00 0.380 ug/L Ethylbenzene <0.130 1.00 0.130 ug/L Hexachlorobutadiene <0.220 1.00 0.220 ug/L lodomethane <1.70 5.00 1.70 ug/L Isobutyl alcohol <11.0 50.0 11.0 ug/L Methacrylonitrile <4.90 10.0 4.90 ug/L Methyl methacrylate <0.510 1.00 0.510 ug/L Methylene Chloride <0.230 1.00 0.230 ug/L Naphthalene <0.110 1.00 0.110 ug/L Propionitrile <5.00 10.0 5.00 ug/L Styrene <0.110 1.00 0.110 ug/L Tetrachloroethene <0.170 1.00 0.170 ug/L Toluene <0.140 1.00 0.140 ug/L trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L Trichloroethene <0.150 1.00 0.150 ug/L Trichlorofluoromethane <0.240 *+ F1 1.00 0.240 ug/L Vinyl acetate <0.950 5.00 0.950 ug/L Vinyl chloride <0.320 *+ F1 1.00 0.320 ug/L Xylenes, Total <0.450 3.00 0.450 ug/L Surrogate 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) D Prepared Analyzed Dil Fac 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 04/01/23 01:34 1 %Recovery Qualifier Limits Prepared Analyzed Dil Fac 111 53 - 136 04101123 01:34 1 107 67 - 129 04101123 01:34 1 102 59 - 134 04101123 01:34 1 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,2,4,5-Tetrachlorobenzene <4.80 10.7 4.80 ug/L 2,3,4,6-Tetrachlorophenol <4.59 10.7 4.59 ug/L 2,4,5-Trichlorophenol <3.52 10.7 3.52 ug/L 2,4,6-Trichlorophenol <2.35 10.7 2.35 ug/L 2,4-Dichlorophenol <3.95 10.7 3.95 ug/L 2,4-Dimethylphenol <3.20 10.7 3.20 ug/L 2,4-Dinitrophenol <17.1 F1 *+ 53.4 17.1 ug/L 2,4-Dinitrotoluene <2.46 10.7 2.46 ug/L 2,6-Dinitrotoluene <2.99 10.7 2.99 ug/L 2-Chloronaphthalene <5.12 10.7 5.12 ug/L 2-Chlorophenol <3.42 10.7 3.42 ug/L 2-Methylphenol <1.92 10.7 1.92 ug/L 2-Nitroaniline <3.10 53.4 3.10 ug/L D Prepared Analyzed Dil Fac 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 03/24/2314:39 03/25/2319:36 1 0 Eurofins Raleigh Page 27 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-Nitrophenol <4.16 10.7 4.16 ug/L 03/24/23 14:39 03/25/23 19:36 1 3 & 4 Methylphenol <1.49 10.7 1.49 ug/L 03/24/23 14:39 03/25/23 19:36 1 3,3'-Dichlorobenzidine <10.7 64.1 10.7 ug/L 03/24/23 14:39 03/25/23 19:36 1 3-Nitroaniline <3.20 53.4 3.20 ug/L 03/24/23 14:39 03/25/23 19:36 1 4,6-Dinitro-2-methylphenol <5.66 F1 53.4 5.66 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Bromophenyl phenyl ether <5.02 10.7 5.02 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Chloro-3-methylphenol <2.67 10.7 2.67 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Chloroaniline <1.07 21.4 1.07 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Chlorophenyl phenyl ether <5.66 10.7 5.66 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Nitroaniline <3.20 53.4 3.20 ug/L 03/24/23 14:39 03/25/23 19:36 1 4-Nitrophenol <8.65 53.4 8.65 ug/L 03/24/23 14:39 03/25/23 19:36 1 Acenaphthene <4.70 10.7 4.70 ug/L 03/24/23 14:39 03/25/23 19:36 1 Acenaphthylene <3.84 10.7 3.84 ug/L 03/24/23 14:39 03/25/23 19:36 1 Acetophenone <2.35 10.7 2.35 ug/L 03/24/23 14:39 03/25/23 19:36 1 Anthracene <3.84 10.7 3.84 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzo[a]anthracene <4.48 10.7 4.48 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzo[a]pyrene <2.99 10.7 2.99 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzo[b]fluoranthene <3.31 10.7 3.31 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzo[g,h,i]perylene <3.20 10.7 3.20 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzo[k]fluoranthene <3.10 10.7 3.10 ug/L 03/24/23 14:39 03/25/23 19:36 1 Benzyl alcohol <2.78 10.7 2.78 ug/L 03/24/23 14:39 03/25/23 19:36 1 bis (2-chloroisopropyl) ether <3.31 10.7 3.31 ug/L 03/24/23 14:39 03/25/23 19:36 1 Bis(2-chloroethoxy)methane <1.92 10.7 1.92 ug/L 03/24/23 14:39 03/25/23 19:36 1 Bis(2-chloroethyl)ether <3.84 10.7 3.84 ug/L 03/24/23 14:39 03/25/23 19:36 1 Bis(2-ethylhexyl) phthalate <3.20 10.7 3.20 ug/L 03/24/23 14:39 03/25/23 19:36 1 Butyl benzyl phthalate <2.99 10.7 2.99 ug/L 03/24/23 14:39 03/25/23 19:36 1 Chrysene <4.06 10.7 4.06 ug/L 03/24/23 14:39 03/25/23 19:36 1 Dibenz(a,h)anthracene <3.20 10.7 3.20 ug/L 03/24/23 14:39 03/25/23 19:36 1 Dibenzofuran <2.03 10.7 2.03 ug/L 03/24/23 14:39 03/25/23 19:36 1 Diethyl phthalate <2.35 10.7 2.35 ug/L 03/24/23 14:39 03/25/23 19:36 1 Di-n-butyl phthalate <2.46 10.7 2.46 ug/L 03/24/23 14:39 03/25/23 19:36 1 Di-n-octyl phthalate <2.99 10.7 2.99 ug/L 03/24/23 14:39 03/25/23 19:36 1 Fluoranthene <1.71 10.7 1.71 ug/L 03/24/23 14:39 03/25/23 19:36 1 Fluorene <3.63 10.7 3.63 ug/L 03/24/23 14:39 03/25/23 19:36 1 Hexachlorobenzene <1.71 10.7 1.71 ug/L 03/24/23 14:39 03/25/23 19:36 1 Hexachlorocyclopentadiene <3.74 10.7 3.74 ug/L 03/24/23 14:39 03/25/23 19:36 1 Hexachloroethane <3.84 10.7 3.84 ug/L 03/24/23 14:39 03/25/23 19:36 1 Indeno[1,2,3-cd]pyrene <4.59 10.7 4.59 ug/L 03/24/23 14:39 03/25/23 19:36 1 Isophorone <2.14 10.7 2.14 ug/L 03/24/23 14:39 03/25/23 19:36 1 Nitrobenzene <3.74 10.7 3.74 ug/L 03/24/23 14:39 03/25/23 19:36 1 N-Nitrosodimethylamine <2.24 10.7 2.24 ug/L 03/24/23 14:39 03/25/23 19:36 1 N-Nitrosodi-n-propylamine <2.56 10.7 2.56 ug/L 03/24/23 14:39 03/25/23 19:36 1 N-Nitrosodiphenylamine <3.10 10.7 3.10 ug/L 03/24/23 14:39 03/25/23 19:36 1 Phenanthrene <4.59 10.7 4.59 ug/L 03/24/23 14:39 03/25/23 19:36 1 Phenol <1.60 10.7 1.60 ug/L 03/24/23 14:39 03/25/23 19:36 1 Pyrene <3.95 10.7 3.95 ug/L 03/24/23 14:39 03/25/23 19:36 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4,6-Tribromophenol (Surr) 86 30- 130 03/24/23 14:39 03/25/23 19:36 1 2-Fluorobiphenyl (Surr) 68 25- 130 03/24/23 14:39 03/25/23 19:36 1 Eurofins Raleigh Page 28 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Client Sample ID: 4501-MW8 Date Collected: 03/20/23 12:15 Date Received: 03/21/23 09:20 Job ID: 752-4652-1 Lab Sample ID: 752-4652-3 Matrix: Ground Water Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) F__ Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2-Fluorophenol (Surr) 38 10 - 130 03/24/23 14:39 03/25/23 19:36 1 Nitrobenzene-d5 (Surr) 73 30 - 130 03/24/23 14:39 03/25/23 19:36 1 _ Phenol-d5 (Surr) 28 10 - 130 03/24/23 14:39 03/25/23 19:36 1 Terphenyl-04 (Surr) 67 35- 131 03/24/23 14:39 03/25/23 19:36 1 Method: RSK-175 - Dissolved Gases (GC) F Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Methane 223 2.00 1.20 ug/L 03/29/2314:28 1 Ethane <1.70 4.00 1.70 ug/L 03/29/2314:28 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2314:28 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 85 50 - 150 03/29/23 14:28 1 Method: RSK-175 - Dissolved Gases (GC) - DL Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 407000 H 2O000 10000 ug/L 03/28/23 11:39 2 Method: SW846 8081B - Organochlorine Pesticides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac L 4,4'-DDD <0.00195 F1 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 4,4'-DDE <0.000976 F1 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 4,4'-DDT <0.000976 F1 F2 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 Aldrin <0.00195 F2 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 alpha-BHC <0.000976 F2 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 beta-BHC <0.00195 *+ F1 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Chlordane (technical) <0.156 0.488 0.156 ug/L 03/23/23 10:01 03/24/23 20:18 1 Chlorobenzilate <0.625 2.93 0.625 ug/L 03/23/23 10:01 03/24/23 20:18 1 delta-BHC <0.00195 *+ F1 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Dieldrin <0.00195 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Endosulfan 1 <0.00195 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Endosulfan 11 <0.00195 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Endosulfan sulfate <0.00195 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Endrin <0.000976 *+ F1 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 Endrin aldehyde <0.00390 F1 0.0488 0.00390 ug/L 03/23/23 10:01 03/24/23 20:18 1 gamma-BHC (Lindane) 0.00791 J p 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 Heptachlor <0.000976 0.0488 0.000976 ug/L 03/23/23 10:01 03/24/23 20:18 1 Heptachlor epoxide <0.00195 F1 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Isodrin <0.0107 0.0488 0.0107 ug/L 03/23/23 10:01 03/24/23 20:18 1 Kepone <2.54 4.88 2.54 ug/L 03/23/23 10:01 03/24/23 20:18 1 Methoxychlor <0.00195 F1 F2 0.0488 0.00195 ug/L 03/23/23 10:01 03/24/23 20:18 1 Toxaphene <0.302 4.88 0.302 ug/L 03/23/23 10:01 03/24/23 20:18 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 75 30 - 130 03/23/23 10:01 03/24/23 20:18 1 Tetrachloro-m-xylene 70 30 - 130 03/23/23 10:01 03/24/23 20:18 1 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac PCB-1016 <0.312 0.976 0.312 ug/L 03/23/23 10:01 03/24/23 20:18 1 Eurofins Raleigh Page 29 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed PCB-1221 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 PCB-1232 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 PCB-1242 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 PCB-1248 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 PCB-1254 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 PCB-1260 <0.332 0.976 0.332 ug/L 03/23/23 10:01 03/24/23 20:18 Dil Fac 1 1 1 1 1 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Tetrachloro-m-xylene 70 30 - 130 03/23/23 10:01 03/24/23 20:18 1 DCB Decachlorobiphenyl 75 30 - 130 03/23/23 10:01 03/24/23 20:18 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0221 F1 0.241 0.0221 ug/L 03/23/23 09:39 03/27/23 22:11 1 Dinoseb <0.0962 0.481 0.0962 ug/L 03/23/23 09:39 03/27/23 22:11 1 Silvex (2,4,5-TP) <0.0924 0.818 0.0924 ug/L 03/23/23 09:39 03/27/23 22:11 1 2,4,5-T <0.135 0.818 0.135 ug/L 03/23/23 09:39 03/27/23 22:11 1 2,4-D <0.173 1.06 0.173 ug/L 03/23/23 09:39 03/27/23 22:11 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 91 26 - 137 03/23/23 09:39 03/27/23 22:11 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 11.4 1.00 0.400 mg/L 04/05/2317:23 1 Chloride 39.7 0.500 0.200 mg/L 04/05/2317:23 1 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid <1.80 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid <1.80 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA (2-Hydroxyisobutyic <1.30 5.00 1.30 mg/L 03/29/23 19:50 10 acid) Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Trimethylacetic Acid 03/29/23 19:50 10 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/23/23 06:57 03/23/23 17:08 1 Barium 581 10.0 4.40 ug/L 03/23/23 06:57 03/23/23 17:08 1 Beryllium <0.300 4.00 0.300 ug/L 03/23/23 06:57 03/23/23 17:08 1 Cadmium <0.440 5.00 0.440 ug/L 03/23/23 06:57 03/23/23 17:08 1 Chromium <1.10 10.0 1.10 ug/L 03/23/23 06:57 03/23/23 17:08 1 Cobalt 14.4 10.0 1.40 ug/L 03/23/23 06:57 03/23/23 17:08 1 Eurofins Raleigh Page 30 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) Analyte Result Qualifier RL MDL Unit Copper <3.20 20.0 3.20 ug/L Lead <6.60 10.0 6.60 ug/L Nickel <3.30 40.0 3.30 ug/L Selenium <10.0 20.0 10.0 ug/L Silver <1.50 10.0 1.50 ug/L Tin <11.0 50.0 11.0 ug/L Vanadium <1.00 10.0 1.00 ug/L Zinc <8.70 20.0 8.70 ug/L Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit Antimony <0.340 5.00 0.340 ug/L Thallium <0.260 1.00 0.260 ug/L Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit Mercury 1.04 F1 0.200 0.0800 ug/L General Chemistry Analyte Result Qualifier RL MDL Unit Alkalinity as CaCO3 to pH 4.5 (SM 563 5.00 2.20 mg/L 2320B-2011) Nitrate as N (EPA 353.2) <0.0250 0.100 0.0250 mg/L Nitrate Nitrite as N (EPA 353.2) <0.0410 F1 0.100 0.0410 mg/L Nitrite as N (EPA 353.2) <0.0168 F1 0.100 0.0168 mg/L Total Non-purgeable Organic 28.0 1.00 0.500 mg/L Carbon (SM 5310 B-2011) Cyanide, Total (SW846 9012B) 0.00841 J F1 0.0100 0.00250 mg/L Chemical Oxygen Demand (SM 113 10.0 10.0 mg/L 5220D) Analyte Result Qualifier RL RL Unit Sulfide (SM 4500 S2 F-2011) <0.926 F1 0.926 0.926 mg/L Biochemical Oxygen Demand (SM 3.83 2.00 2.00 mg/L 5210B) Client Sample ID: 4501-MW6 Date Collected: 03/21/23 12:30 Date Received: 03/22/23 10:00 D Prepared Analyzed Dil Fac 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 03/23/23 06:57 03/23/23 17:08 1 D Prepared Analyzed Dil Fac 03/23/23 06:57 03/23/23 20:09 1 03/23/23 06:57 03/23/23 20:09 1 D Prepared Analyzed Dil Fac 03/23/2313:17 03/23/2319:15 1 D Prepared Analyzed Dil Fac 03/25/23 01:18 1 03/29/23 15:40 1 04/03/23 13:24 1 03/21/23 16:28 1 04/02/23 04:30 1 03/30/23 08:29 03/30/23 12:28 1 03/22/23 17:45 1 D Prepared Analyzed Dil Fac 03/23/23 10:41 1 03/21/23 14:53 1 Lab Sample ID: 752-4682-1 Matrix: Ground Water Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 21.6 0.500 0.320 ug/L 03/31/2318:02 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 86 70 - 130 03/31/23 18:02 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.850 5.00 0.850 ug/L 04/04/2323:05 5 1,1,1-Trichloroethane <0.600 5.00 0.600 ug/L 04/04/2323:05 5 1,1,2,2-Tetrachloroethane <1.40 5.00 1.40 ug/L 04/04/2323:05 5 1,1,2-Trichloroethane <0.700 5.00 0.700 ug/L 04/04/2323:05 5 Eurofins Raleigh Page 31 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethane <0.650 5.00 0.650 ug/L 04/04/23 23:05 5 1,1-Dichloroethene <1.05 5.00 1.05 ug/L 04/04/23 23:05 5 1,1-Dichloropropene <0.750 5.00 0.750 ug/L 04/04/23 23:05 5 1,2,3-Trichloropropane <2.45 5.00 2.45 ug/L 04/04/23 23:05 5 1,2,4-Trichlorobenzene <0.700 5.00 0.700 ug/L 04/04/23 23:05 5 1,2-Dibromo-3-Chloropropane <2.40 5.00 2.40 ug/L 04/04/23 23:05 5 1,2-Dibromoethane <3.30 5.00 3.30 ug/L 04/04/23 23:05 5 1,2-Dichlorobenzene <0.950 5.00 0.950 ug/L 04/04/23 23:05 5 1,2-Dichloroethane <1.05 5.00 1.05 ug/L 04/04/23 23:05 5 1,2-Dichloropropane <0.500 5.00 0.500 ug/L 04/04/23 23:05 5 1,3-Dichlorobenzene <0.750 5.00 0.750 ug/L 04/04/23 23:05 5 1,3-Dichloropropane <0.800 5.00 0.800 ug/L 04/04/23 23:05 5 1,4-Dichlorobenzene <0.950 5.00 0.950 ug/L 04/04/23 23:05 5 2,2-Dichloropropane <1.40 5.00 1.40 ug/L 04/04/23 23:05 5 2-Butanone (MEK) <50.0 100 50.0 ug/L 04/04/23 23:05 5 2-Hexanone <4.40 25.0 4.40 ug/L 04/04/23 23:05 5 3-Chloropropene <0.550 5.00 0.550 ug/L 04/04/23 23:05 5 4-Methyl-2-pentanone (MIBK) <5.50 25.0 5.50 ug/L 04/04/23 23:05 5 Acetone 288 100 50.0 ug/L 04/04/23 23:05 5 Acetonitrile <25.0 50.0 25.0 ug/L 04/04/23 23:05 5 Acrolein <20.0 50.0 20.0 ug/L 04/04/23 23:05 5 Acrylonitrile <17.5 50.0 17.5 ug/L 04/04/23 23:05 5 Benzene 1.64 J 5.00 0.750 ug/L 04/04/23 23:05 5 Bromochloromethane <2.40 5.00 2.40 ug/L 04/04/23 23:05 5 Bromodichloromethane <0.850 5.00 0.850 ug/L 04/04/23 23:05 5 Bromoform <1.10 5.00 1.10 ug/L 04/04/23 23:05 5 Bromomethane <0.700 5.00 0.700 ug/L 04/04/23 23:05 5 Carbon disulfide <7.50 25.0 7.50 ug/L 04/04/23 23:05 5 Carbon tetrachloride <0.850 5.00 0.850 ug/L 04/04/23 23:05 5 Chlorobenzene <0.850 5.00 0.850 ug/L 04/04/23 23:05 5 Chloroethane <1.15 5.00 1.15 ug/L 04/04/23 23:05 5 Chloroform <0.900 5.00 0.900 ug/L 04/04/23 23:05 5 Chloromethane <0.650 5.00 0.650 ug/L 04/04/23 23:05 5 Chloroprene <3.20 5.00 3.20 ug/L 04/04/23 23:05 5 cis-1,2-Dichloroethene 0.974 J 5.00 0.750 ug/L 04/04/23 23:05 5 cis-1,3-Dichloropropene <1.00 5.00 1.00 ug/L 04/04/23 23:05 5 Dibromochloromethane <0.850 5.00 0.850 ug/L 04/04/23 23:05 5 Dibromomethane <1.35 5.00 1.35 ug/L 04/04/23 23:05 5 Dichlorodifluoromethane <1.00 *+ 5.00 1.00 ug/L 04/04/23 23:05 5 Ethyl methacrylate <1.90 5.00 1.90 ug/L 04/04/23 23:05 5 Ethylbenzene <0.650 5.00 0.650 ug/L 04/04/23 23:05 5 Hexachlorobutadiene <1.10 5.00 1.10 ug/L 04/04/23 23:05 5 lodomethane <8.50 25.0 8.50 ug/L 04/04/23 23:05 5 Isobutyl alcohol <55.0 250 55.0 ug/L 04/04/23 23:05 5 Methacrylonitrile <24.5 50.0 24.5 ug/L 04/04/23 23:05 5 Methyl methacrylate <2.55 5.00 2.55 ug/L 04/04/23 23:05 5 Methylene Chloride <1.15 5.00 1.15 ug/L 04/04/23 23:05 5 Naphthalene <0.550 5.00 0.550 ug/L 04/04/23 23:05 5 Propionitrile <25.0 50.0 25.0 ug/L 04/04/23 23:05 5 0 Eurofins Raleigh Page 32 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Styrene <0.550 5.00 0.550 ug/L 04/04/23 23:05 5 Tetrachloroethene <0.850 5.00 0.850 ug/L 04/04/23 23:05 5 �. Toluene <0.700 5.00 0.700 ug/L 04/04/23 23:05 5 trans- l,2-Dichloroethene <1.05 5.00 1.05 ug/L 04/04/23 23:05 5 trans- 1,3-Dichloropropene <0.750 5.00 0.750 ug/L 04/04/23 23:05 5 trans- 1,4-Dichloro-2-butene <3.50 5.00 3.50 ug/L 04/04/23 23:05 5 Trichloroethene <0.750 5.00 0.750 ug/L 04/04/23 23:05 5 Trichlorofluoromethane <1.20 *+ 5.00 1.20 ug/L 04/04/23 23:05 5 Vinyl acetate <4.75 25.0 4.75 ug/L 04/04/23 23:05 5 Vinyl chloride <1.60 *+ 5.00 1.60 ug/L 04/04/23 23:05 5 Xylenes, Total <2.25 15.0 2.25 ug/L 04/04/23 23:05 5 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 115 53 - 136 04104123 23:05 5 Dibromofluoromethane (Surr) 112 67- 129 04104123 23:05 5 Toluene-d8 (Surr) 108 59 - 134 04104123 23:05 5 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4,5-Tetrachlorobenzene <4.29 9.54 4.29 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,3,4,6-Tetrachlorophenol <4.10 9.54 4.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4,5-Trichlorophenol <3.15 9.54 3.15 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4,6-Trichlorophenol <2.10 9.54 2.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4-Dichlorophenol <3.53 9.54 3.53 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4-Dimethylphenol <2.86 9.54 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4-Dinitrophenol <15.3 '+ 47.7 15.3 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,4-Dinitrotoluene <2.19 9.54 2.19 ug/L 03/24/23 14:39 03/25/23 21:26 1 2,6-Dinitrotoluene <2.67 9.54 2.67 ug/L 03/24/23 14:39 03/25/23 21:26 1 2-Chloronaphthalene <4.58 9.54 4.58 ug/L 03/24/23 14:39 03/25/23 21:26 1 2-Chlorophenol <3.05 9.54 3.05 ug/L 03/24/23 14:39 03/25/23 21:26 1 2-Methylphenol <1.72 9.54 1.72 ug/L 03/24/23 14:39 03/25/23 21:26 1 2-Nitroaniline <2.77 47.7 2.77 ug/L 03/24/23 14:39 03/25/23 21:26 1 2-Nitrophenol <3.72 9.54 3.72 ug/L 03/24/23 14:39 03/25/23 21:26 1 3 & 4 Methylphenol <1.34 9.54 1.34 ug/L 03/24/23 14:39 03/25/23 21:26 1 3,3'-Dichlorobenzidine <9.54 57.2 9.54 ug/L 03/24/23 14:39 03/25/23 21:26 1 3-Nitroaniline <2.86 47.7 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 4,6-Dinitro-2-methylphenol <5.05 47.7 5.05 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Bromophenyl phenyl ether <4.48 9.54 4.48 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Chloro-3-methylphenol <2.38 9.54 2.38 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Chloroaniline <0.954 19.1 0.954 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Chlorophenyl phenyl ether <5.05 9.54 5.05 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Nitroaniline <2.86 47.7 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 4-Nitrophenol <7.72 47.7 7.72 ug/L 03/24/23 14:39 03/25/23 21:26 1 Acenaphthene <4.20 9.54 4.20 ug/L 03/24/23 14:39 03/25/23 21:26 1 Acenaphthylene <3.43 9.54 3.43 ug/L 03/24/23 14:39 03/25/23 21:26 1 Acetophenone <2.10 9.54 2.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 Anthracene <3.43 9.54 3.43 ug/L 03/24/23 14:39 03/25/23 21:26 1 Benzo[a]anthracene <4.01 9.54 4.01 ug/L 03/24/23 14:39 03/25/23 21:26 1 Benzo[a]pyrene <2.67 9.54 2.67 ug/L 03/24/23 14:39 03/25/23 21:26 1 Benzo[b]fluoranthene <2.96 9.54 2.96 ug/L 03/24/23 14:39 03/25/23 21:26 1 Eurofins Raleigh Page 33 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzo[g,h,i]perylene <2.86 9.54 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 Benzo[k]fluoranthene <2.77 9.54 2.77 ug/L 03/24/23 14:39 03/25/23 21:26 1 Benzyl alcohol <2.48 9.54 2.48 ug/L 03/24/23 14:39 03/25/23 21:26 1 bis (2-chloroisopropyl) ether <2.96 9.54 2.96 ug/L 03/24/23 14:39 03/25/23 21:26 1 Bis(2-chloroethoxy)methane <1.72 9.54 1.72 ug/L 03/24/23 14:39 03/25/23 21:26 1 Bis(2-chloroethyl)ether <3.43 9.54 3.43 ug/L 03/24/23 14:39 03/25/23 21:26 1 Bis(2-ethylhexyl) phthalate <2.86 9.54 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 Butyl benzyl phthalate <2.67 9.54 2.67 ug/L 03/24/23 14:39 03/25/23 21:26 1 Chrysene <3.62 9.54 3.62 ug/L 03/24/23 14:39 03/25/23 21:26 1 Dibenz(a,h)anthracene <2.86 9.54 2.86 ug/L 03/24/23 14:39 03/25/23 21:26 1 Dibenzofuran <1.81 9.54 1.81 ug/L 03/24/23 14:39 03/25/23 21:26 1 Diethyl phthalate <2.10 9.54 2.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 Di-n-butyl phthalate <2.19 9.54 2.19 ug/L 03/24/23 14:39 03/25/23 21:26 1 Di-n-octyl phthalate <2.67 9.54 2.67 ug/L 03/24/23 14:39 03/25/23 21:26 1 Fluoranthene <1.53 9.54 1.53 ug/L 03/24/23 14:39 03/25/23 21:26 1 Fluorene <3.24 9.54 3.24 ug/L 03/24/23 14:39 03/25/23 21:26 1 Hexachlorobenzene <1.53 9.54 1.53 ug/L 03/24/23 14:39 03/25/23 21:26 1 Hexachlorocyclopentadiene <3.34 9.54 3.34 ug/L 03/24/23 14:39 03/25/23 21:26 1 Hexachloroethane <3.43 9.54 3.43 ug/L 03/24/23 14:39 03/25/23 21:26 1 Indeno[1,2,3-cd]pyrene <4.10 9.54 4.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 Isophorone <1.91 9.54 1.91 ug/L 03/24/23 14:39 03/25/23 21:26 1 Nitrobenzene <3.34 9.54 3.34 ug/L 03/24/23 14:39 03/25/23 21:26 1 N-Nitrosodimethylamine <2.00 9.54 2.00 ug/L 03/24/23 14:39 03/25/23 21:26 1 N-N itrosod i-n-propylamine <2.29 9.54 2.29 ug/L 03/24/23 14:39 03/25/23 21:26 1 N-Nitrosodiphenylamine <2.77 9.54 2.77 ug/L 03/24/23 14:39 03/25/23 21:26 1 Phenanthrene <4.10 9.54 4.10 ug/L 03/24/23 14:39 03/25/23 21:26 1 Phenol <1.43 9.54 1.43 ug/L 03/24/23 14:39 03/25/23 21:26 1 Pyrene <3.53 9.54 3.53 ug/L 03/24/23 14:39 03/25/23 21:26 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4,6-Tribromophenol (Surr) 94 30- 130 03124123 14:39 03125123 21:26 1 2-Fluorobiphenyl (Surr) 50 25 - 130 03/24/23 14:39 03/25/23 21:26 1 2-Fluorophenol (Surr) 27 10 - 130 03/24/23 14:39 03/25/23 21:26 1 Nitrobenzene-d5 (Surr) 54 30 - 130 03/24/23 14:39 03/25/23 21:26 1 Phenol-d5 (Surr) 20 10 - 130 03/24/23 14:39 03/25/23 21:26 1 Terphenyl-d 14 (Surr) 62 35 - 131 03/24/23 14:39 03/25/23 21:26 1 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 394000 10000 5000 ug/L 03/28/23 13:25 1 Ethane <1.70 4.00 1.70 ug/L 03/29/2314:54 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2314:54 1 Methane 8320 2.00 1.20 ug/L 03/29/2314:54 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 83 50 - 150 03/29/23 14:54 1 Method: SW846 8081 B - Organochlorine Pesticides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00198 0.0495 0.00198 ug/L 03/27/2317:28 1 Eurofins Raleigh Page 34 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8081 B - Organochlorine Pesticides (GC) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDE <0.000991 0.0495 0.000991 ug/L 03/2712317:28 1 4,4'-DDT <0.000991 0.0495 0.000991 ug/L 03/27/23 17:28 1 Aldrin <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 alpha-BHC <0.000991 0.0495 0.000991 ug/L 03/27/23 17:28 1 alpha -Chlordane <0.00495 0.0495 0.00495 ug/L 03/27/23 17:28 1 beta-BHC <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Chlordane (technical) <0.159 0.495 0.159 ug/L 03/27/23 17:28 1 Chlorobenzilate <0.634 2.97 0.634 ug/L 03/27/23 17:28 1 delta-BHC <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Dieldrin <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Endosulfan 1 <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Endosulfan II <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Endosulfan sulfate <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Endrin <0.000991 0.0495 0.000991 ug/L 03/27/23 17:28 1 Endrin aldehyde <0.00396 0.0495 0.00396 ug/L 03/27/23 17:28 1 gamma-BHC (Lindane) <0.000991 0.0495 0.000991 ug/L 03/27/23 17:28 1 gamma -Chlordane <0.00595 0.0495 0.00595 ug/L 03/27/23 17:28 1 Heptachlor <0.000991 0.0495 0.000991 ug/L 03/27/23 17:28 1 Heptachlor epoxide <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Isodrin <0.0109 0.0495 0.0109 ug/L 03/27/23 17:28 1 Kepone <2.58 4.95 2.58 ug/L 03/27/23 17:28 1 Methoxychlor <0.00198 0.0495 0.00198 ug/L 03/27/23 17:28 1 Toxaphene <0.307 4.95 0.307 ug/L 03/27/23 17:28 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 69 30- 130 03/27/23 17.28 1 Tetrachloro-m-xylene ill 30- 130 03/27/23 17.28 1 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac PCB-1016 <0.317 *1 0.991 0.317 ug/L 03/27/23 17:28 1 PCB-1221 <0.337 0.991 0.337 ug/L 03/27/23 17:28 1 PCB-1232 <0.337 0.991 0.337 ug/L 03/27/23 17:28 1 PCB-1242 <0.337 0.991 0.337 ug/L 03/27/23 17:28 1 PCB-1248 <0.337 0.991 0.337 ug/L 03/27/23 17:28 1 PCB-1254 <0.337 0.991 0.337 ug/L 03/27/23 17:28 1 PCB-1260 <0.337 *1 0.991 0.337 ug/L 03/27/23 17:28 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac Tetrachloro-m-xylene ill 30- 130 03/27/23 17.28 1 DCB Decachlorobiphenyl 69 30 - 130 03/27/23 17:28 1 Method: SW846 8151A - Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0218 0.237 0.0218 ug/L 03/27/23 10:41 03/30/23 00:36 1 Dinoseb <0.0948 0.474 0.0948 ug/L 03/27/23 10:41 03/30/23 00:36 1 Silvex (2,4,5-TP) <0.0910 0.806 0.0910 ug/L 03/27/23 10:41 03/30/23 00:36 1 2,4,5-T <0.133 0.806 0.133 ug/L 03/27/23 10:41 03/30/23 00:36 1 2,4-D <0.171 1.04 0.171 ug/L 03/27/23 10:41 03/30/23 00:36 1 Eurofins Raleigh Page 35 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 65 p 26 - 137 03/27/23 10:41 03/30/23 00:36 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate <0.400 1.00 0.400 mg/L 04/11/2317:34 1 Chloride 98.9 0.500 0.200 mg/L 04/05/23 21:33 1 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid 25.1 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid 33.2 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA 19.9 5.00 1.30 mg/L 03/29/23 19:50 10 (2-Hydroxyisobutyic acid) Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Trimethylacetic Acid 03/29/23 19:50 10 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:17 1 Barium 185 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:17 1 Beryllium 0.910 J B 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:17 1 Cadmium <0.440 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:17 1 Chromium 2.15 J 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:17 1 Cobalt 2.12 J 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:17 1 Copper 8.05 J 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:17 1 Lead <6.60 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:17 1 Nickel 5.35 J 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:17 1 Selenium <10.0 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:17 1 Silver <1.50 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:17 1 Tin <11.0 50.0 11.0 ug/L 03/24/23 06:33 03/24/23 19:17 1 Vanadium 5.52 J 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:17 1 Zinc 19.3 J 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:17 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 15:56 1 Thallium <0.260 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 15:56 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/24/2310:01 03/24/2317:07 1 Eurofins Raleigh Page 36 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 General Chemistry Analyte Result Qualifier RL Alkalinity as CaCO3 to pH 4.5 (SM 232 5.00 2320B-2011) Nitrate as N (EPA 353.2) <0.0250 0.100 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 Nitrite as N (EPA 353.2) <0.0168 0.100 Total Non-purgeable Organic 22.2 1.00 Carbon (SM 5310 B-2011) Cyanide, Total (SW846 9012B) 0.00591 J 0.0100 Chemical Oxygen Demand (SM 71.1 10.0 5220D) Analyte Result Qualifier RL Sulfide (SM 4500 S2 F-2011) <0.962 0.962 Biochemical Oxygen Demand (SM 13.7 6.00 5210B) Client Sample ID: 4501-MW7 Date Collected: 03/21/23 15:03 Date Received: 03/22/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane 19.4 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 80 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 1.00 1,1-Dichloropropene <0.150 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2,4-Trichlorobenzene 1.14 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene 0.691 J 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,3-Dichlorobenzene <0.150 1.00 1,3-Dichloropropane <0.160 1.00 1,4-Dichlorobenzene 10.2 1.00 2,2-Dichloropropane <0.280 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 3-Chloropropene <0.110 1.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 MDL Unit D Prepared Analyzed Dil Fac 2.20 mg/L 03/25/23 03:24 1 0.0250 mg/L 03/29/2315:43 1 0.0410 mg/L 03/27/2312:17 1 0.0168 mg/L 03/22/2316:07 1 0.500 mg/L 04/02/23 05:20 1 0.00250 mg/L 03/30/23 08:29 03/30/23 12:28 1 10.0 mg/L 03/30/2310:08 1 RL Unit D Prepared Analyzed Dil Fac 0.962 mg/L 03/24/2310:13 1 6.00 mg/L 03/22/2317:01 1 Lab Sample ID: 752-4682-2 Matrix: Ground Water MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/31/2316:14 1 Prepared Analyzed Dil Fac 03/31/23 16:14 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/04/23 20:09 1 0.120 ug/L 04/04/23 20:09 1 0.280 ug/L 04/04/23 20:09 1 0.140 ug/L 04/04/23 20:09 1 0.130 ug/L 04/04/23 20:09 1 0.210 ug/L 04/04/23 20:09 1 0.150 ug/L 04/04/23 20:09 1 0.490 ug/L 04/04/23 20:09 1 0.140 ug/L 04/04/23 20:09 1 0.480 ug/L 04/04/23 20:09 1 0.660 ug/L 04/04/23 20:09 1 0.190 ug/L 04/04/23 20:09 1 0.210 ug/L 04/04/23 20:09 1 0.100 ug/L 04/04/23 20:09 1 0.150 ug/L 04/04/23 20:09 1 0.160 ug/L 04/04/23 20:09 1 0.190 ug/L 04/04/23 20:09 1 0.280 ug/L 04/04/23 20:09 1 10.0 ug/L 04/04/23 20:09 1 0.880 ug/L 04/04/23 20:09 1 0.110 ug/L 04/04/23 20:09 1 1.10 ug/L 04/04/23 20:09 1 10.0 ug/L 04/04/23 20:09 1 Eurofins Raleigh Page 37 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit Acetonitrile <5.00 10.0 5.00 ug/L Acrolein <4.00 10.0 4.00 ug/L Acrylonitrile <3.50 10.0 3.50 ug/L Benzene 0.994 J 1.00 0.150 ug/L Bromochloromethane <0.480 1.00 0.480 ug/L Bromodichloromethane <0.170 1.00 0.170 ug/L Bromoform <0.220 1.00 0.220 ug/L Bromomethane <0.140 1.00 0.140 ug/L Carbon disulfide <1.50 5.00 1.50 ug/L Carbon tetrachloride <0.170 1.00 0.170 ug/L Chlorobenzene 7.60 1.00 0.170 ug/L Chloroethane <0.230 1.00 0.230 ug/L Chloroform <0.180 1.00 0.180 ug/L Chloromethane <0.130 1.00 0.130 ug/L Chloroprene <0.640 1.00 0.640 ug/L cis-1,2-Dichloroethene 2.40 1.00 0.150 ug/L cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L Dibromochloromethane <0.170 1.00 0.170 ug/L Dibromomethane <0.270 1.00 0.270 ug/L Dichlorodifluoromethane <0.200 *+ 1.00 0.200 ug/L Ethyl methacrylate <0.380 1.00 0.380 ug/L Ethylbenzene <0.130 1.00 0.130 ug/L Hexachlorobutadiene <0.220 1.00 0.220 ug/L lodomethane <1.70 5.00 1.70 ug/L Isobutyl alcohol <11.0 50.0 11.0 ug/L Methacrylonitrile <4.90 10.0 4.90 ug/L Methyl methacrylate <0.510 1.00 0.510 ug/L Methylene Chloride 0.267 J 1.00 0.230 ug/L Naphthalene <0.110 1.00 0.110 ug/L Propionitrile <5.00 10.0 5.00 ug/L Styrene <0.110 1.00 0.110 ug/L Tetrachloroethene <0.170 1.00 0.170 ug/L Toluene <0.140 1.00 0.140 ug/L trans- l,2-Dichloroethene <0.210 1.00 0.210 ug/L trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L Trichloroethene <0.150 1.00 0.150 ug/L Trichlorofluoromethane <0.240 *+ 1.00 0.240 ug/L Vinyl acetate <0.950 5.00 0.950 ug/L Vinyl chloride 0.805 J *+ 1.00 0.320 ug/L Xylenes, Total <0.450 3.00 0.450 ug/L Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 116 53 - 136 Dibromofluoromethane (Surr) 108 67- 129 Toluene-d8 (Surr) 107 59 - 134 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit 1,2,4,5-Tetrachlorobenzene <4.39 9.74 4.39 ug/L D Prepared Analyzed Dil Fac 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 04/04/23 20:09 1 Prepared Analyzed Dil Fac 04104123 20:09 1 04104123 20:09 1 04104123 20:09 1 D Prepared Analyzed Dil Fac 03/24/23 14:39 03/25/23 21:48 1 0 Eurofins Raleigh Page 38 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2,3,4,6-Tetrachlorophenol <4.19 9.74 4.19 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4,5-Trichlorophenol <3.22 9.74 3.22 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4,6-Trichlorophenol <2.14 9.74 2.14 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4-Dichlorophenol <3.61 9.74 3.61 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4-Dimethylphenol <2.92 9.74 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4-Dinitrophenol <15.6 *+ 48.7 15.6 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,4-Dinitrotoluene <2.24 9.74 2.24 ug/L 03/24/23 14:39 03/25/23 21:48 1 2,6-Dinitrotoluene <2.73 9.74 2.73 ug/L 03/24/23 14:39 03/25/23 21:48 1 2-Chloronaphthalene <4.68 9.74 4.68 ug/L 03/24/23 14:39 03/25/23 21:48 1 2-Chlorophenol <3.12 9.74 3.12 ug/L 03/24/23 14:39 03/25/23 21:48 1 2-Methylphenol <1.75 9.74 1.75 ug/L 03/24/23 14:39 03/25/23 21:48 1 2-Nitroaniline <2.83 48.7 2.83 ug/L 03/24/23 14:39 03/25/23 21:48 1 2-Nitrophenol <3.80 9.74 3.80 ug/L 03/24/23 14:39 03/25/23 21:48 1 3 & 4 Methylphenol <1.36 9.74 1.36 ug/L 03/24/23 14:39 03/25/23 21:48 1 3,3'-Dichlorobenzidine <9.74 58.5 9.74 ug/L 03/24/23 14:39 03/25/23 21:48 1 3-Nitroaniline <2.92 48.7 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 4,6-Dinitro-2-methylphenol <5.16 48.7 5.16 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Bromophenyl phenyl ether <4.58 9.74 4.58 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Chloro-3-methylphenol <2.44 9.74 2.44 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Chloroaniline <0.974 19.5 0.974 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Chlorophenyl phenyl ether <5.16 9.74 5.16 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Nitroaniline <2.92 48.7 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 4-Nitrophenol <7.89 48.7 7.89 ug/L 03/24/23 14:39 03/25/23 21:48 1 Acenaphthene <4.29 9.74 4.29 ug/L 03/24/23 14:39 03/25/23 21:48 1 Acenaphthylene <3.51 9.74 3.51 ug/L 03/24/23 14:39 03/25/23 21:48 1 Acetophenone <2.14 9.74 2.14 ug/L 03/24/23 14:39 03/25/23 21:48 1 Anthracene <3.51 9.74 3.51 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzo[a]anthracene <4.09 9.74 4.09 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzo[a]pyrene <2.73 9.74 2.73 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzo[b]fluoranthene <3.02 9.74 3.02 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzo[g,h,i]perylene <2.92 9.74 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzo[k]fluoranthene <2.83 9.74 2.83 ug/L 03/24/23 14:39 03/25/23 21:48 1 Benzyl alcohol <2.53 9.74 2.53 ug/L 03/24/23 14:39 03/25/23 21:48 1 bis (2-chloroisopropyl) ether <3.02 9.74 3.02 ug/L 03/24/23 14:39 03/25/23 21:48 1 Bis(2-chloroethoxy)methane <1.75 9.74 1.75 ug/L 03/24/23 14:39 03/25/23 21:48 1 Bis(2-chloroethyl)ether <3.51 9.74 3.51 ug/L 03/24/23 14:39 03/25/23 21:48 1 Bis(2-ethylhexyl) phthalate <2.92 9.74 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 Butyl benzyl phthalate <2.73 9.74 2.73 ug/L 03/24/23 14:39 03/25/23 21:48 1 Chrysene <3.70 9.74 3.70 ug/L 03/24/23 14:39 03/25/23 21:48 1 Dibenz(a,h)anthracene <2.92 9.74 2.92 ug/L 03/24/23 14:39 03/25/23 21:48 1 Dibenzofuran <1.85 9.74 1.85 ug/L 03/24/23 14:39 03/25/23 21:48 1 Diethyl phthalate <2.14 9.74 2.14 ug/L 03/24/23 14:39 03/25/23 21:48 1 Di-n-butyl phthalate <2.24 9.74 2.24 ug/L 03/24/23 14:39 03/25/23 21:48 1 Di-n-octyl phthalate <2.73 9.74 2.73 ug/L 03/24/23 14:39 03/25/23 21:48 1 Fluoranthene <1.56 9.74 1.56 ug/L 03/24/23 14:39 03/25/23 21:48 1 Fluorene <3.31 9.74 3.31 ug/L 03/24/23 14:39 03/25/23 21:48 1 Hexachlorobenzene <1.56 9.74 1.56 ug/L 03/24/23 14:39 03/25/23 21:48 1 Hexachlorocyclopentadiene <3.41 9.74 3.41 ug/L 03/24/23 14:39 03/25/23 21:48 1 Hexachloroethane <3.51 9.74 3.51 ug/L 03/24/23 14:39 03/25/23 21:48 1 Eurofins Raleigh Page 39 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Indeno[1,2,3-cd]pyrene <4.19 9.74 4.19 ug/L 03/24/23 14:39 03/25/23 21:48 1 Isophorone <1.95 9.74 1.95 ug/L 03/24/23 14:39 03/25/23 21:48 1 �. Nitrobenzene <3.41 9.74 3.41 ug/L 03/24/23 14:39 03/25/23 21:48 1 N-Nitrosodimethylamine <2.05 9.74 2.05 ug/L 03/24/23 14:39 03/25/23 21:48 1 N-Nitrosodi-n-propylamine <2.34 9.74 2.34 ug/L 03/24/23 14:39 03/25/23 21:48 1 N-Nitrosodiphenylamine <2.83 9.74 2.83 ug/L 03/24/23 14:39 03/25/23 21:48 1 Phenanthrene <4.19 9.74 4.19 ug/L 03/24/23 14:39 03/25/23 21:48 1 Phenol <1.46 9.74 1.46 ug/L 03/24/23 14:39 03/25/23 21:48 1 Pyrene <3.61 9.74 3.61 ug/L 03/24/23 14:39 03/25/23 21:48 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4,6-Tribromophenol (Surr) 91 30- 130 03/24/23 14:39 03/25/23 21:48 1 2-Fluorobiphenyl (Surr) 60 25 - 130 03/24/23 14:39 03125123 21:48 1 2-Fluorophenol (Surr) 38 10 - 130 03/24/23 14:39 03125123 21:48 1 Nitrobenzene-d5 (Surr) 67 30 - 130 03124123 14:39 03/25/23 21:48 1 Phenol-d5 (Surr) 26 10 - 130 03124123 14:39 03/25/23 21:48 1 Terphenyl-d14 (Surr) 67 35- 131 03124123 14:39 03/25/23 21:48 1 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 387000 10000 5000 ug/L 03/28/23 13:34 1 Ethane <1.70 4.00 1.70 ug/L 03/29/2315:03 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2315:03 1 Methane 273 2.00 1.20 ug/L 03/29/2315:03 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 84 50 - 150 03/29/23 15:03 1 Method: SW846 8081 B - Organochlorine Pesticides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 4,4'-DDE <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 4,4'-DDT <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 Aldrin <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 alpha-BHC <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 alpha -Chlordane <0.00475 0.0475 0.00475 ug/L 03/27/23 17:44 1 beta-BHC <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Chlordane (technical) <0.152 0.475 0.152 ug/L 03/27/23 17:44 1 Chlorobenzilate <0.608 2.85 0.608 ug/L 03/27/23 17:44 1 delta-BHC <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Dieldrin <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Endosulfan I <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Endosulfan II <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Endosulfan sulfate <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Endrin <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 Endrin aldehyde <0.00380 0.0475 0.00380 ug/L 03/27/23 17:44 1 gamma-BHC (Lindane) <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 gamma -Chlordane <0.00570 0.0475 0.00570 ug/L 03/27/23 17:44 1 Heptachlor <0.000950 0.0475 0.000950 ug/L 03/27/23 17:44 1 Heptachlor epoxide 0.00911 J P 0.0475 0.00190 ug/L 03/27/23 17:44 1 Eurofins Raleigh Page 40 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8081 B - Organochlorine Pesticides (GC) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Isodrin <0.0105 0.0475 0.0105 ug/L 03/27/23 17:44 1 Kepone <2.47 4.75 2.47 ug/L 03/27/23 17:44 1 �. Methoxychlor <0.00190 0.0475 0.00190 ug/L 03/27/23 17:44 1 Toxaphene <0.295 4.75 0.295 ug/L 03/27/23 17:44 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 91 p 30- 130 03/27/23 17744 1 Tetrachloro-m-xylene 121 p 30 - 130 03/27/23 17:44 1 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac PCB-1016 <0.304 *1 0.950 0.304 ug/L 03/27/23 17:44 1 PCB-1221 <0.323 0.950 0.323 ug/L 03/27/23 17:44 1 PCB-1232 <0.323 0.950 0.323 ug/L 03/27/23 17:44 1 PCB-1242 <0.323 0.950 0.323 ug/L 03/27/23 17:44 1 PCB-1248 <0.323 0.950 0.323 ug/L 03/27/23 17:44 1 PCB-1254 <0.323 0.950 0.323 ug/L 03/27/23 17:44 1 PCB-1260 <0.323 *1 0.950 0.323 ug/L 03/27/23 17:44 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Tetrachloro-m-xylene 121 p 30 - 130 03/27/23 17:44 1 DCB Decachlorobiphenyl 91 p 30 - 130 03/27/23 17:44 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0223 0.243 0.0223 ug/L 03/27/23 10:41 03/30/23 00:58 1 Dinoseb <0.0970 0.485 0.0970 ug/L 03/27/23 10:41 03/30/23 00:58 1 Silvex (2,4,5-TP) <0.0932 0.825 0.0932 ug/L 03/27/23 10:41 03/30/23 00:58 1 2,4,5-T <0.136 0.825 0.136 ug/L 03/27/23 10:41 03/30/23 00:58 1 2,4-D <0.175 1.07 0.175 ug/L 03/27/23 10:41 03/30/23 00:58 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 55 p 26 - 137 03/27/23 10:41 03/30/23 00:58 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 2.04 1.00 0.400 mg/L 04/11/2317:48 1 Chloride 103 0.500 0.200 mg/L 04/06/23 09:25 1 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid 7.80 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid 12.5 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA 12.5 5.00 1.30 mg/L 03/29/23 19:50 10 (2-Hydroxyisobutyic acid) Eurofins Raleigh Page 41 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW7 Lab Sample ID: 752-4682-2 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Surrogate %Recovery Qualifier Limits Trimethylacetic Acid Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL Arsenic <6.40 20.0 Barium 575 10.0 Beryllium 1.19 J B 4.00 Cadmium 0.500 J 5.00 Chromium <1.10 10.0 Cobalt 2.24 J 10.0 Copper <3.20 20.0 Lead <6.60 10.0 Nickel <3.30 40.0 Selenium <10.0 20.0 Silver <1.50 10.0 Tin <11.0 50.0 Vanadium <1.00 10.0 Zinc <8.70 20.0 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL Antimony <0.340 5.00 Thallium 0.265 J 1.00 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL Mercury <0.0800 0.200 General Chemistry MDL Unit 6.40 ug/L 4.40 ug/L 0.300 ug/L 0.440 ug/L 1.10 ug/L 1.40 ug/L 3.20 ug/L 6.60 ug/L 3.30 ug/L 10.0 ug/L 1.50 ug/L 11.0 ug/L 1.00 ug/L 8.70 ug/L MDL Unit 0.340 ug/L 0.260 ug/L MDL Unit 0.0800 ug/L Analyte Result Qualifier RL MDL Unit Alkalinity as CaCO3 to pH 4.5 (SM 265 5.00 2.20 mg/L 2320B-2011) Prepared Analyzed Dil Fac 03/29/23 19:50 10 D Prepared Analyzed Dil Fac 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 03/24/23 06:33 03/24/23 19:21 1 D Prepared Analyzed Dil Fac 03/24/23 06:33 03/24/23 16:00 1 03/24/23 06:33 03/24/23 16:00 1 D Prepared Analyzed Dil Fac 03/24/23 10:01 03/24/23 17:10 1 D Prepared Analyzed Dil Fac 03/25/23 02:33 1 Nitrate as N (EPA 353.2) <0.0250 0.100 0.0250 mg/L 03/29/23 15:43 1 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 0.0410 mg/L 03/27/23 12:19 1 Nitrite as N (EPA 353.2) <0.0168 0.100 0.0168 mg/L 03/22/23 16:08 1 Total Non-purgeable Organic 4.88 1.00 0.500 mg/L 04/02/23 05:39 1 Carbon (SM 5310 B-2011) Cyanide, Total (SW846 9012B) 0.00344 J 0.0100 0.00250 mg/L 03/30/23 08:29 03/30/23 12:36 1 Chemical Oxygen Demand (SM 41.6 10.0 10.0 mg/L 03/30/23 10:08 1 5220D) Analyte Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac Sulfide (SM 4500 S2 F-2011) <0.926 0.926 0.926 mg/L 03/24/23 10:13 1 Biochemical Oxygen Demand (SM <2.00 2.00 2.00 mg/L 03/22/23 17:07 1 5210B) Client Sample ID: 4501-MW10 Lab Sample ID: 752-4682-3 Date Collected: 03/21/23 10:19 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D 1,4-Dioxane <0.320 0.500 0.320 ug/L Prepared Analyzed Dil Fac 03/31 /23 16:41 1 Eurofins Raleigh Page 42 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW10 Lab Sample ID: 752-4682-3 Date Collected: 03/21/23 10:19 Matrix: Ground Water Date Received: 03/22/23 10:00 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 77 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene <0.190 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,4-Dichlorobenzene <0.190 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene <0.150 1.00 Bromochloromethane <0.480 1.00 Bromodichloromethane <0.170 1.00 Bromoform <0.220 1.00 Bromomethane <0.140 1.00 Carbon disulfide <1.50 5.00 Carbon tetrachloride <0.170 1.00 Chlorobenzene <0.170 1.00 Chloroethane <0.230 1.00 Chloroform <0.180 1.00 Chloromethane <0.130 1.00 cis-1,2-Dichloroethene <0.150 1.00 cis-1,3-Dichloropropene <0.200 1.00 Dibromochloromethane <0.170 1.00 Dibromomethane <0.270 1.00 Ethylbenzene <0.130 1.00 lodomethane <1.70 5.00 Methylene Chloride <0.230 1.00 Styrene <0.110 1.00 Tetrachloroethene <0.170 1.00 Tetrahydrofuran <0.530 1.00 Toluene <0.140 1.00 trans- 1,2-Dichloroethene <0.210 1.00 trans- 1,3-Dichloropropene <0.150 1.00 trans- 1,4-Dichloro-2-butene <0.700 1.00 Trichloroethene <0.150 1.00 Trichlorofluoromethane <0.240+ 1.00 Vinyl acetate <0.950 5.00 Prepared Analyzed Dil Fac 03/31/23 16:41 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/04/23 20:38 1 0.120 ug/L 04/04/23 20:38 1 0.280 ug/L 04/04/23 20:38 1 0.140 ug/L 04/04/23 20:38 1 0.130 ug/L 04/04/23 20:38 1 0.210 ug/L 04/04/23 20:38 1 0.490 ug/L 04/04/23 20:38 1 0.480 ug/L 04/04/23 20:38 1 0.660 ug/L 04/04/23 20:38 1 0.190 ug/L 04/04/23 20:38 1 0.210 ug/L 04/04/23 20:38 1 0.100 ug/L 04/04/23 20:38 1 0.190 ug/L 04/04/23 20:38 1 10.0 ug/L 04/04/23 20:38 1 0.880 ug/L 04/04/23 20:38 1 1.10 ug/L 04/04/23 20:38 1 10.0 ug/L 04/04/23 20:38 1 3.50 ug/L 04/04/23 20:38 1 0.150 ug/L 04/04/23 20:38 1 0.480 ug/L 04/04/23 20:38 1 0.170 ug/L 04/04/23 20:38 1 0.220 ug/L 04/04/23 20:38 1 0.140 ug/L 04/04/23 20:38 1 1.50 ug/L 04/04/23 20:38 1 0.170 ug/L 04/04/23 20:38 1 0.170 ug/L 04/04/23 20:38 1 0.230 ug/L 04/04/23 20:38 1 0.180 ug/L 04/04/23 20:38 1 0.130 ug/L 04/04/23 20:38 1 0.150 ug/L 04/04/23 20:38 1 0.200 ug/L 04/04/23 20:38 1 0.170 ug/L 04/04/23 20:38 1 0.270 ug/L 04/04/23 20:38 1 0.130 ug/L 04/04/23 20:38 1 1.70 ug/L 04/04/23 20:38 1 0.230 ug/L 04/04/23 20:38 1 0.110 ug/L 04/04/23 20:38 1 0.170 ug/L 04/04/23 20:38 1 0.530 ug/L 04/04/23 20:38 1 0.140 ug/L 04/04/23 20:38 1 0.210 ug/L 04/04/23 20:38 1 0.150 ug/L 04/04/23 20:38 1 0.700 ug/L 04/04/23 20:38 1 0.150 ug/L 04/04/23 20:38 1 0.240 ug/L 04/04/23 20:38 1 0.950 ug/L 04/04/23 20:38 1 0 Eurofins Raleigh Page 43 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW10 Lab Sample ID: 752-4682-3 Date Collected: 03/21/23 10:19 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Vinyl chloride <0.320 *+ 1.00 0.320 ug/L 04/04/23 20:38 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/04/23 20:38 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 113 53 - 136 04104123 20:38 1 Dibromofluoromethane (Surr) 111 67- 129 04104123 20:38 1 Toluene-d8 (Surr) 108 59 - 134 04104123 20:38 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2,4-D <0.168 1.03 0.168 ug/L 03/27/23 10:41 03/30/23 01:20 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 102 p 26 - 137 03/27/23 10:41 03/30/23 01:20 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate <0.400 1.00 0.400 mg/L 04/11/2318:01 1 Chloride 2.28 0.500 0.200 mg/L 04/06/2310:07 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:24 1 Barium <4.40 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:24 1 Beryllium 1.08 J B 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:24 1 Cadmium <0.440 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:24 1 Chromium <1.10 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:24 1 Cobalt <1.40 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:24 1 Copper 3.86 J 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:24 1 Iron <20.0 100 20.0 ug/L 03/24/23 06:33 03/24/23 19:24 1 Lead <6.60 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:24 1 Manganese 6.43 J 10.0 1.30 ug/L 03/24/23 06:33 03/24/23 19:24 1 Nickel <3.30 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:24 1 Selenium <10.0 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:24 1 Silver <1.50 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:24 1 Vanadium 1.38 J 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:24 1 Zinc <8.70 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:24 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 16:04 1 Thallium <0.260 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 16:04 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/24/2310:01 03/24/2317:19 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 26.7 5.00 2.20 mg/L 03/25/23 02:15 1 23206-2011) Total Dissolved Solids (SM 2540C) <100 100 100 mg/L 03/27/23 10:55 1 Eurofins Raleigh Page 44 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW11 Lab Sample ID: 752-4682-4 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane 1.98 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 89 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene <0.190 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,4-Dichlorobenzene <0.190 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene 0.499 J 1.00 Bromochloromethane <0.480 1.00 Bromodichloromethane <0.170 1.00 Bromoform <0.220 1.00 Bromomethane <0.140 1.00 Carbon disulfide <1.50 5.00 Carbon tetrachloride <0.170 1.00 Chlorobenzene <0.170 1.00 Chloroethane <0.230 1.00 Chloroform <0.180 1.00 Chloromethane <0.130 1.00 cis-1,2-Dichloroethene 0.438 J 1.00 cis-1,3-Dichloropropene <0.200 1.00 Dibromochloromethane <0.170 1.00 Dibromomethane <0.270 1.00 Ethylbenzene <0.130 1.00 lodomethane <1.70 5.00 Methylene Chloride <0.230 1.00 Styrene <0.110 1.00 Tetrachloroethene <0.170 1.00 Tetrahydrofuran <0.530 1.00 Toluene <0.140 1.00 trans- 1,2-Dichloroethene <0.210 1.00 trans- 1,3-Dichloropropene <0.150 1.00 trans- 1,4-Dichloro-2-butene <0.700 1.00 MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/31/2315:47 1 • Prepared Analyzed Dil Fac 03/31/23 15:47 1 MDL Unit D Prepared Analyzed Dil Fac C 0.170 ug/L 04/04/23 21:08 1 0.120 ug/L 04/04/23 21:08 1 0.280 ug/L 04/04/23 21:08 1 0.140 ug/L 04/04/23 21:08 1 0.130 ug/L 04/04/23 21:08 1 0.210 ug/L 04/04/23 21:08 1 0.490 ug/L 04/04/23 21:08 1 0.480 ug/L 04/04/23 21:08 1 0.660 ug/L 04/04/23 21:08 1 0.190 ug/L 04/04/23 21:08 1 0.210 ug/L 04/04/23 21:08 1 0.100 ug/L 04/04/23 21:08 1 0.190 ug/L 04/04/23 21:08 1 10.0 ug/L 04/04/23 21:08 1 0.880 ug/L 04/04/23 21:08 1 1.10 ug/L 04/04/23 21:08 1 10.0 ug/L 04/04/23 21:08 1 3.50 ug/L 04/04/23 21:08 1 0.150 ug/L 04/04/23 21:08 1 0.480 ug/L 04/04/23 21:08 1 0.170 ug/L 04/04/23 21:08 1 0.220 ug/L 04/04/23 21:08 1 0.140 ug/L 04/04/23 21:08 1 1.50 ug/L 04/04/23 21:08 1 0.170 ug/L 04/04/23 21:08 1 0.170 ug/L 04/04/23 21:08 1 0.230 ug/L 04/04/23 21:08 1 0.180 ug/L 04/04/23 21:08 1 0.130 ug/L 04/04/23 21:08 1 0.150 ug/L 04/04/23 21:08 1 0.200 ug/L 04/04/23 21:08 1 0.170 ug/L 04/04/23 21:08 1 0.270 ug/L 04/04/23 21:08 1 0.130 ug/L 04/04/23 21:08 1 1.70 ug/L 04/04/23 21:08 1 0.230 ug/L 04/04/23 21:08 1 0.110 ug/L 04/04/23 21:08 1 0.170 ug/L 04/04/23 21:08 1 0.530 ug/L 04/04/23 21:08 1 0.140 ug/L 04/04/23 21:08 1 0.210 ug/L 04/04/23 21:08 1 0.150 ug/L 04/04/23 21:08 1 0.700 ug/L 04/04/23 21:08 1 Eurofins Raleigh Page 45 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW11 Lab Sample ID: 752-4682-4 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichloroethene <0.150 1.00 0.150 ug/L 04/04/23 21:08 1 Trichlorofluoromethane <0.240 *+ 1.00 0.240 ug/L 04/04/23 21:08 1 �. Vinyl acetate <0.950 5.00 0.950 ug/L 04/04/23 21:08 1 Vinyl chloride <0.320 *+ 1.00 0.320 ug/L 04/04/23 21:08 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/04/23 21:08 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 116 53 - 136 04104123 21:08 1 Dibromofluoromethane (Surr) 113 67- 129 04104123 21:08 1 Toluene-d8 (Surr) 106 59 - 134 04104123 21:08 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2,4-D <0.170 F1 1.04 0.170 ug/L 03/27/23 10:41 03/29/23 22:05 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 51 p 26 - 137 03/27/23 10:41 03/29/23 22:05 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 172 1.00 0.400 mg/L 04/06/2310:29 1 Chloride 18.2 0.500 0.200 mg/L 04/06/2310:29 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:08 1 Barium 68.4 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:08 1 Beryllium 1.13 J B 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:08 1 Cadmium <0.440 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:08 1 Chromium <1.10 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:08 1 Cobalt 2.77 J 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:08 1 Copper <3.20 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:08 1 Iron 3610 100 20.0 ug/L 03/24/23 06:33 03/24/23 19:08 1 Lead <6.60 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:08 1 Manganese 7660 10.0 1.30 ug/L 03/24/23 06:33 03/24/23 19:08 1 Nickel <3.30 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:08 1 Selenium <10.0 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:08 1 Silver <1.50 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:08 1 Vanadium 1.70 J 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:08 1 Zinc <8.70 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:08 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 15:44 1 Thallium <0.260 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 15:44 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 F1 0.200 0.0800 ug/L 03/24/2310:01 03/24/2317:22 1 Eurofins Raleigh Page 46 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW11 Lab Sample ID: 752-4682-4 Date Collected: 03/21/23 15:03 Matrix: Ground Water Date Received: 03/22/23 10:00 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 319 5.00 2.20 mg/L 03/25/23 03:13 1 2320B-2011) Total Dissolved Solids (SM 2540C) 610 50.0 50.0 mg/L 03/28/23 10:16 1 Client Sample ID: 4501-MW12 Lab Sample ID: 752-4682-5 Date Collected: 03/21/23 13:23 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM C Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 1.18 0.500 0.320 ug/L 03/31/2317:08 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 88 70 - 130 03131123 17:08 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/04/23 21:37 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/04/23 21:37 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/04/23 21:37 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/04/23 21:37 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/04/23 21:37 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/04/23 21:37 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/04/23 21:37 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/04/23 21:37 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/04/23 21:37 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 21:37 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/04/23 21:37 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/04/23 21:37 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 21:37 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/04/23 21:37 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/04/23 21:37 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/04/23 21:37 1 Acetone <10.0 20.0 10.0 ug/L 04/04/23 21:37 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/04/23 21:37 1 Benzene 0.368 J 1.00 0.150 ug/L 04/04/23 21:37 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/04/23 21:37 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/04/23 21:37 1 Bromoform <0.220 1.00 0.220 ug/L 04/04/23 21:37 1 Bromomethane <0.140 1.00 0.140 ug/L 04/04/23 21:37 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/04/23 21:37 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/04/23 21:37 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/04/23 21:37 1 Chloroethane <0.230 1.00 0.230 ug/L 04/04/23 21:37 1 Chloroform <0.180 1.00 0.180 ug/L 04/04/23 21:37 1 Chloromethane 0.908 J 1.00 0.130 ug/L 04/04/23 21:37 1 cis-1,2-Dichloroethene 0.875 J 1.00 0.150 ug/L 04/04/23 21:37 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/04/23 21:37 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/04/23 21:37 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/04/23 21:37 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/04/23 21:37 1 Eurofins Raleigh Page 47 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW12 Lab Sample ID: 752-4682-5 Date Collected: 03/21/23 13:23 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit lodomethane <1.70 5.00 1.70 ug/L Methylene Chloride <0.230 1.00 0.230 ug/L Styrene <0.110 1.00 0.110 ug/L Tetrachloroethene <0.170 1.00 0.170 ug/L Tetrahydrofuran <0.530 1.00 0.530 ug/L Toluene <0.140 1.00 0.140 ug/L trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L Trichloroethene <0.150 1.00 0.150 ug/L Trichlorofluoromethane <0.240 '+ 1.00 0.240 ug/L Vinyl acetate <0.950 5.00 0.950 ug/L Vinyl chloride 1.04 *+ 1.00 0.320 ug/L Xylenes, Total <0.450 3.00 0.450 ug/L Surrogate %Recovery Qualifier 4-Bromofluorobenzene (Surr) 113 Dibromofluoromethane (Surr) 112 Toluene-d8 (Surr) 110 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier 2,4-D <0.164 Surrogate DCAA D Prepared Analyzed Dil Fac 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 04/04/23 21:37 1 Limits Prepared Analyzed Dil Fac 53 - 136 04104123 21:37 1 67- 129 04104123 21:37 1 59 - 134 04104123 21:37 1 RL MDL Unit 1.01 0.164 ug/L %Recovery Qualifier Limits 57 p 26-137 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit Sulfate 36.0 1.00 0.400 mg/L Chloride 44.3 0.500 0.200 mg/L Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier Arsenic <6.40 Barium 20.6 Beryllium 1.02 J B Cadmium <0.440 Chromium <1.10 Cobalt <1.40 Copper <3.20 Iron 48.6 J Lead <6.60 Manganese 914 Nickel <3.30 Selenium <10.0 Silver <1.50 Vanadium 1.74 J Zinc <8.70 D Prepared Analyzed Dil Fac 03/27/23 10:41 03/30/23 01:41 1 Prepared Analyzed Dil Fac 03/27/23 10:41 03/30/23 01:41 1 D Prepared Analyzed Dil Fac 04/11 /23 18:14 1 04/11 /23 18:14 1 RL MDL Unit D Prepared Analyzed Dil Fac 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:27 1 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:27 1 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:27 1 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:27 1 100 20.0 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 1.30 ug/L 03/24/23 06:33 03/24/23 19:27 1 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:27 1 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:27 1 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:27 1 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:27 1 Page 48 of 242 Eurofins Raleigh 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW12 Lab Sample ID: 752-4682-5 Date Collected: 03/21/23 13:23 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 16:08 1 Thallium <0.260 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 16:08 1 �. Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/24/2310:01 03/24/2317:32 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 152 5.00 2.20 mg/L 03/25/23 02:43 1 2320B-2011) Total Dissolved Solids (SM 2540C) 274 50.0 50.0 mg/L 03/28/23 10:16 1 Client Sample ID: 4501-MW13 Lab Sample ID: 752-4682-6 Date Collected: 03/21/23 12:09 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 3.55 0.500 0.320 ug/L 03/31/2317:35 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 75 70 - 130 03/31/23 17:35 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/04/23 22:06 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/04/23 22:06 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/04/23 22:06 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/04/23 22:06 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/04/23 22:06 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/04/23 22:06 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/04/23 22:06 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/04/23 22:06 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/04/23 22:06 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 22:06 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/04/23 22:06 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/04/23 22:06 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 22:06 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/04/23 22:06 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/04/23 22:06 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/04/23 22:06 1 Acetone <10.0 20.0 10.0 ug/L 04/04/23 22:06 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/04/23 22:06 1 Benzene 0.255 J 1.00 0.150 ug/L 04/04/23 22:06 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/04/23 22:06 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/04/23 22:06 1 Bromoform <0.220 1.00 0.220 ug/L 04/04/23 22:06 1 Bromomethane <0.140 1.00 0.140 ug/L 04/04/23 22:06 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/04/23 22:06 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/04/23 22:06 1 Eurofins Raleigh Page 49 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW13 Lab Sample ID: 752-4682-6 Date Collected: 03/21/23 12:09 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit Chlorobenzene <0.170 1.00 0.170 ug/L Chloroethane <0.230 1.00 0.230 ug/L Chloroform <0.180 1.00 0.180 ug/L Chloromethane <0.130 1.00 0.130 ug/L cis-1,2-Dichloroethene 1.45 1.00 0.150 ug/L cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L Dibromochloromethane <0.170 1.00 0.170 ug/L Dibromomethane <0.270 1.00 0.270 ug/L Ethylbenzene <0.130 1.00 0.130 ug/L lodomethane <1.70 5.00 1.70 ug/L Methylene Chloride <0.230 1.00 0.230 ug/L Styrene <0.110 1.00 0.110 ug/L Tetrachloroethene <0.170 1.00 0.170 ug/L Tetrahydrofuran 13.8 1.00 0.530 ug/L Toluene <0.140 1.00 0.140 ug/L trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L Trichloroethene <0.150 1.00 0.150 ug/L Trichlorofluoromethane <0.240 «+ 1.00 0.240 ug/L Vinyl acetate <0.950 5.00 0.950 ug/L Vinyl chloride 0.596 J *+ 1.00 0.320 ug/L Xylenes, Total <0.450 3.00 0.450 ug/L Surrogate 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) D Prepared Analyzed Dil Fac 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 04/04/23 22:06 1 %Recovery Qualifier Limits Prepared Analyzed Dil Fac 118 53 - 136 04104123 22:06 1 109 67 - 129 04104123 22:06 1 105 59 - 134 04104123 22:06 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2,4-D 0.173 J p 1.03 0.168 ug/L 03/27/23 10:41 03/30/23 02:02 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 63 p 26 - 137 03/27/23 10:41 03/30/23 02:02 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 27.7 1.00 0.400 mg/L 04/11/2318:53 1 Chloride 19.9 0.500 0.200 mg/L 04/11/2318:53 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:30 1 Barium 17.6 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:30 1 Beryllium 0.840 J B 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:30 1 Cadmium <0.440 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:30 1 Chromium <1.10 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:30 1 Cobalt 4.34 J 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:30 1 Copper <3.20 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:30 1 Iron 1510 100 20.0 ug/L 03/24/23 06:33 03/24/23 19:30 1 0 Eurofins Raleigh Page 50 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW13 Lab Sample ID: 752-4682-6 Date Collected: 03/21/23 12:09 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) F__ Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Lead <6.60 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:30 1 Manganese 831 10.0 1.30 ug/L 03/24/23 06:33 03/24/23 19:30 1 Nickel <3.30 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:30 1 Selenium <10.0 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:30 1 Silver <1.50 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:30 1 Vanadium <1.00 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:30 1 Zinc <8.70 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:30 1 Method: SW846 6020E - Metals (ICP/MS) - Total Recoverable C Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 16:12 1 Thallium <0.260 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 16:12 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/24/2310:01 03/24/2317:35 1 General Chemistry F Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 136 5.00 2.20 mg/L 03/25/23 02:53 1 232013-2011) Total Dissolved Solids (SM 2540C) 472 100 100 mg/L 03/28/23 10:16 1 Client Sample ID: 4501-Old MW2 Lab Sample ID: 752-4682-7 Date Collected: 03/21/23 08:29 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1-Dichloroethane 0.248 J 1.00 0.130 ug/L 04/04/23 22:36 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 22:36 1 Benzene <0.150 1.00 0.150 ug/L 04/04/23 22:36 1 Vinyl chloride <0.320 *+ 1.00 0.320 ug/L 04/04/23 22:36 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 116 53 - 136 04104123 22:36 1 Dibromofluoromethane (Surr) 112 67 - 129 04104123 22:36 1 Toluene-d8 (Surr) 107 59 - 134 04104123 22:36 1 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethane <1.70 4.00 1.70 ug/L 03/29/2315:12 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2315:12 1 Methane 92.3 2.00 1.20 ug/L 03/29/2315:12 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed DU Fac Acetylene 87 50 - 150 03/29/23 15:12 1 Method: RSK-175 - Dissolved Gases (GC) - DL Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 744000 H 40000 20000 ug/L 03/29/23 11:59 4 Eurofins Raleigh Page 51 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills F Job ID: 752-4652-1 Client Sample ID: 4501-Old MW2 Lab Sample ID: 752-4682-7 Date Collected: 03/21/23 08:29 Matrix: Ground Water Date Received: 03/22/23 10:00 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 2.76 1.00 Chloride 34.3 0.500 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL Acetic acid 6.60 5.00 Butyric acid <0.890 5.00 Propionic acid <0.650 5.00 Pyruvic Acid <0.210 5.00 Hexanoic acid <2.60 5.00 Iso-Hexanoic Acid <4.40 5.00 Iso-Pentanoic Acid 5.19 5.00 Pentanoic acid <1.40 5.00 Lactic Acid/HIBA (2-Hydroxyisobutyic <1.30 5.00 acid) Surrogate %Recovery Qualifier Limits Trimethylacetic Acid General Chemistry Analyte Result Qualifier RL Alkalinity as CaCO3 to pH 4.5 (SM 175 5.00 232013-2011) Nitrate as N (EPA 353.2) <0.0250 0.100 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 Nitrite as N (EPA 353.2) <0.0168 0.100 Total Non-purgeable Organic 2.88 1.00 Carbon (SM 5310 B-2011) Chemical Oxygen Demand (SM <10.0 10.0 5220D) Analyte Result Qualifier RL Sulfide (SM 4500 S2 F-2011) <0.893 0.893 Biochemical Oxygen Demand (SM <2.00 2.00 5210B) Client Sample ID: 4501-AMW2S Date Collected: 03/22/23 13:22 Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane 2.67 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 86 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 MDL Unit D Prepared Analyzed Dil Fac 0.400 mg/L 04/11/2319:33 1 0.200 mg/L 04/11/2319:33 1 MDL Unit D Prepared Analyzed Dil Fac 1.80 mg/L 03/29/2319:50 10 0.890 mg/L 03/29/2319:50 10 0.650 mg/L 03/29/2319:50 10 0.210 mg/L 03/29/2319:50 10 2.60 mg/L 03/29/2319:50 10 4.40 mg/L 03/29/2319:50 10 1.80 mg/L 03/29/2319:50 10 1.40 mg/L 03/29/2319:50 10 1.30 mg/L 03/29/2319:50 10 Prepared Analyzed Dil Fac 03/29/23 19:50 10 MDL Unit D Prepared Analyzed Dil Fac 2.20 mg/L 03/25/23 03:02 1 0.0250 mg/L 03/29/2315:43 1 0.0410 mg/L 03/27/2312:21 1 0.0410 mg/L 03/27/2312:21 1 0.0168 mg/L 03/22/2316:09 1 0.500 mg/L 04/02/23 05:57 1 10.0 mg/L 03/30/2310:08 1 RL Unit D Prepared Analyzed Dil Fac 0.893 mg/L 03/24/2310:13 1 2.00 mg/L 03/22/2317:12 1 Lab Sample ID: 752-4748-1 Matrix: Ground Water MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/31/2318:29 1 Prepared Analyzed Dil Fac 03/31/23 18:29 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/05/2318:20 1 0.120 ug/L 04/05/2318:20 1 0.280 ug/L 04/05/2318:20 1 Eurofins Raleigh Page 52 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-AMW2S Lab Sample ID: 752-4748-1 Date Collected: 03/22/23 13:22 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/23 18:20 1 1,1-Dichloroethane 0.409 J 1.00 0.130 ug/L 04/05/23 18:20 1 1,1-Dichloroethene <0.210 "- 1.00 0.210 ug/L 04/05/23 18:20 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/23 18:20 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/23 18:20 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/23 18:20 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 18:20 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/23 18:20 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/23 18:20 1 1,4-Dichlorobenzene 0.715 J 1.00 0.190 ug/L 04/05/23 18:20 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 18:20 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 18:20 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 18:20 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 18:20 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 18:20 1 Benzene 0.189 J 1.00 0.150 ug/L 04/05/23 18:20 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 18:20 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 18:20 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 18:20 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 18:20 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 18:20 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 18:20 1 Chlorobenzene 0.677 J 1.00 0.170 ug/L 04/05/23 18:20 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 18:20 1 Chloroform 0.315 J B 1.00 0.180 ug/L 04/05/23 18:20 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 18:20 1 cis-1,2-Dichloroethene 0.273 J 1.00 0.150 ug/L 04/05/23 18:20 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 18:20 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 18:20 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 18:20 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 18:20 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 18:20 1 Methylene Chloride 0.308 J B 1.00 0.230 ug/L 04/05/23 18:20 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 18:20 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 18:20 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 18:20 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 18:20 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 18:20 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 18:20 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 18:20 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 18:20 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 18:20 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 18:20 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 18:20 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 97 53- 136 04105123 18:20 1 Dibromofluoromethane (Surr) 90 67- 129 04105123 18:20 1 Toluene-d8 (Surr) 94 59 - 134 04105123 18:20 1 0 Eurofins Raleigh Page 53 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW2S Lab Sample ID: 752-4748-1 Date Collected: 03/22/23 13:22 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: RSK-175 - Dissolved Gases (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Carbon dioxide 147000 10000 5000 ug/L 03/28/23 14:27 1 Ethane <1.70 4.00 1.70 ug/L 04/01/2313:23 1 �. Ethene <1.60 3.00 1.60 ug/L 04/01/2313:23 1 Methane 34.7 2.00 1.20 ug/L 04/01/2313:23 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 85 50 - 150 04101123 13:23 1 Method: MCAWW 300.0-1993 R2.1 - Anions, Ion Chromatography C Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 0.621 J 1.00 0.400 mg/L 04/13/2318:48 1 Chloride 17.4 0.500 0.200 mg/L 04/13/2318:48 1 Method: Lab SOP VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid <1.80 5.00 1.80 mg/L 03/29/23 19:50 10 Butyric acid <0.890 5.00 0.890 mg/L 03/29/23 19:50 10 Propionic acid <0.650 5.00 0.650 mg/L 03/29/23 19:50 10 Pyruvic Acid <0.210 5.00 0.210 mg/L 03/29/23 19:50 10 Hexanoic acid <2.60 5.00 2.60 mg/L 03/29/23 19:50 10 Iso-Hexanoic Acid <4.40 5.00 4.40 mg/L 03/29/23 19:50 10 Iso-Pentanoic Acid 2.55 J 5.00 1.80 mg/L 03/29/23 19:50 10 Pentanoic acid <1.40 5.00 1.40 mg/L 03/29/23 19:50 10 Lactic Acid/HIBA 3.04 J 5.00 1.30 mg/L 03/29/23 19:50 10 (2-Hydroxyisobutyic acid) Surrogate %Recovery Qualifier Limits Trimethylacetic Acid Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit Prepared D Prepared Analyzed 03/29/23 19:50 Analyzed Dil Fac 10 Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/27/23 19:16 1 Barium <4.40 10.0 4.40 ug/L 03/25/23 07:48 03/27/23 19:16 1 Beryllium 0.550 J B 4.00 0.300 ug/L 03/25/23 07:48 03/27/23 19:16 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/27/23 19:16 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/27/23 19:16 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/27/23 19:16 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/27/23 19:16 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/27/23 19:16 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/27/23 19:16 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/27/23 19:16 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/27/23 19:16 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/27/23 19:16 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/27/23 19:16 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 17:01 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 17:01 1 Eurofins Raleigh Page 54 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-AMW2S Lab Sample ID: 752-4748-1 Date Collected: 03/22/23 13:22 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/27/2314:22 03/28/2311:52 1 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Alkalinity as CaCO3 to pH 4.5 (SM 106 5.00 2.20 mg/L 03/28/23 21:01 1 232013-2011) Nitrate as N (EPA 353.2) <0.0250 0.100 0.0250 mg/L 03/29/23 15:43 1 Nitrate Nitrite as N (EPA 353.2) <0.0410 0.100 0.0410 mg/L 03/27/23 12:59 1 Nitrite as N (EPA 353.2) <0.0168 0.100 0.0168 mg/L 03/23/23 16:39 1 Total Non-purgeable Organic 1.02 1.00 0.500 mg/L 04/02/23 06:14 1 Carbon (SM 5310 B-2011) Chemical Oxygen Demand (SM <10.0 10.0 10.0 mg/L 03/30/23 10:08 1 5220D) Analyte Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac Sulfide (SM 4500 S2 F-2011) <1.00 1.00 1.00 mg/L 03/28/23 13:30 1 Biochemical Oxygen Demand (SM <2.00 2.00 2.00 mg/L 03/23/23 15:54 1 52106) Client Sample ID: 4501-Field Blank - Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.320 0.500 0.320 ug/L 03/31/2313:05 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 86 70 - 130 03/31/23 13:05 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/05/2319:18 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/05/2319:18 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/05/2319:18 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/2319:18 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/2319:18 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/2319:18 1 1,1-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/2319:18 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/2319:18 1 1,2,4-Trichlorobenzene <0.140 *+ 1.00 0.140 ug/L 04/05/2319:18 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/2319:18 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/2319:18 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/2319:18 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/2319:18 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/2319:18 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 04/05/2319:18 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 04/05/2319:18 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/2319:18 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 04/05/2319:18 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 19:18 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/2319:18 1 Eurofins Raleigh Page 55 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 3-Chloropropene <0.110 1.00 0.110 ug/L 04/05/23 19:18 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 19:18 1 Acetone 10.0 J 20.0 10.0 ug/L 04/05/23 19:18 1 Acetonitrile <5.00 10.0 5.00 ug/L 04/05/23 19:18 1 Acrolein <4.00 10.0 4.00 ug/L 04/05/23 19:18 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 19:18 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 19:18 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 19:18 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 19:18 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 19:18 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 19:18 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 19:18 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 19:18 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 19:18 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 19:18 1 Chloroform 0.260 J B 1.00 0.180 ug/L 04/05/23 19:18 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 19:18 1 Chloroprene <0.640 1.00 0.640 ug/L 04/05/23 19:18 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 19:18 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 19:18 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 19:18 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 19:18 1 Dichlorodifluoromethane <0.200 1.00 0.200 ug/L 04/05/23 19:18 1 Ethyl methacrylate <0.380 1.00 0.380 ug/L 04/05/23 19:18 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 19:18 1 Hexachlorobutadiene <0.220 1.00 0.220 ug/L 04/05/23 19:18 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 19:18 1 Isobutyl alcohol <11.0 50.0 11.0 ug/L 04/05/23 19:18 1 Methacrylonitrile <4.90 10.0 4.90 ug/L 04/05/23 19:18 1 Methyl methacrylate <0.510 1.00 0.510 ug/L 04/05/23 19:18 1 Methylene Chloride 0.362 J B 1.00 0.230 ug/L 04/05/23 19:18 1 Naphthalene <0.110 «+ 1.00 0.110 ug/L 04/05/23 19:18 1 Propionitrile <5.00 10.0 5.00 ug/L 04/05/23 19:18 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 19:18 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 19:18 1 Tetrahydrofuran <0.530 1.00 0.530 ug/L 04/05/23 19:18 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 19:18 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 19:18 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 19:18 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 19:18 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 19:18 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 19:18 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 19:18 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 19:18 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 19:18 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 93 53 - 136 04105123 19:18 1 Dibromofluoromethane (Surr) 84 67- 129 04105123 19:18 1 Toluene-d8 (Surr) 91 59 - 134 04105123 19:18 1 0 Eurofins Raleigh Page 56 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4,5-Tetrachlorobenzene <4.48 9.96 4.48 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,3,4,6-Tetrachlorophenol <4.28 9.96 4.28 ug/L 03/27/23 08:44 03/27/23 22:41 1 �. 2,4,5-Trichlorophenol <3.29 9.96 3.29 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,4,6-Trichlorophenol <2.19 9.96 2.19 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,4-Dichlorophenol <3.68 9.96 3.68 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,4-Dimethylphenol <2.99 9.96 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,4-Dinitrophenol <15.9 *+ 49.8 15.9 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,4-Dinitrotoluene <2.29 9.96 2.29 ug/L 03/27/23 08:44 03/27/23 22:41 1 2,6-Dinitrotoluene <2.79 9.96 2.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 2-Chloronaphthalene <4.78 9.96 4.78 ug/L 03/27/23 08:44 03/27/23 22:41 1 2-Chlorophenol <3.19 9.96 3.19 ug/L 03/27/23 08:44 03/27/23 22:41 1 2-Methylphenol <1.79 9.96 1.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 2-Nitroaniline <2.89 49.8 2.89 ug/L 03/27/23 08:44 03/27/23 22:41 1 2-Nitrophenol <3.88 9.96 3.88 ug/L 03/27/23 08:44 03/27/23 22:41 1 3 & 4 Methylphenol <1.39 9.96 1.39 ug/L 03/27/23 08:44 03/27/23 22:41 1 3,3'-Dichlorobenzidine <9.96 59.7 9.96 ug/L 03/27/23 08:44 03/27/23 22:41 1 3-Nitroaniline <2.99 49.8 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 4,6-Dinitro-2-methylphenol <5.28 "+ 49.8 5.28 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Bromophenyl phenyl ether <4.68 9.96 4.68 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Chloro-3-methylphenol <2.49 9.96 2.49 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Chloroaniline <0.996 19.9 0.996 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Chlorophenyl phenyl ether <5.28 9.96 5.28 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Nitroaniline <2.99 49.8 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 4-Nitrophenol <8.07 49.8 8.07 ug/L 03/27/23 08:44 03/27/23 22:41 1 Acenaphthene <4.38 9.96 4.38 ug/L 03/27/23 08:44 03/27/23 22:41 1 Acenaphthylene <3.58 9.96 3.58 ug/L 03/27/23 08:44 03/27/23 22:41 1 Acetophenone <2.19 9.96 2.19 ug/L 03/27/23 08:44 03/27/23 22:41 1 Anthracene <3.58 9.96 3.58 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzo[a]anthracene <4.18 9.96 4.18 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzo[a]pyrene <2.79 9.96 2.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzo[b]fluoranthene <3.09 9.96 3.09 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzo[g,h,i]perylene <2.99 9.96 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzo[k]fluoranthene <2.89 9.96 2.89 ug/L 03/27/23 08:44 03/27/23 22:41 1 Benzyl alcohol <2.59 9.96 2.59 ug/L 03/27/23 08:44 03/27/23 22:41 1 bis (2-chloroisopropyl) ether <3.09 9.96 3.09 ug/L 03/27/23 08:44 03/27/23 22:41 1 Bis(2-chloroethoxy)methane <1.79 9.96 1.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 Bis(2-chloroethyl)ether <3.58 9.96 3.58 ug/L 03/27/23 08:44 03/27/23 22:41 1 Bis(2-ethylhexyl) phthalate <2.99 9.96 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 Butyl benzyl phthalate <2.79 9.96 2.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 Chrysene <3.78 9.96 3.78 ug/L 03/27/23 08:44 03/27/23 22:41 1 Dibenz(a,h)anthracene <2.99 9.96 2.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 Dibenzofuran <1.89 9.96 1.89 ug/L 03/27/23 08:44 03/27/23 22:41 1 Diethyl phthalate <2.19 9.96 2.19 ug/L 03/27/23 08:44 03/27/23 22:41 1 Di-n-butyl phthalate <2.29 9.96 2.29 ug/L 03/27/23 08:44 03/27/23 22:41 1 Di-n-octyl phthalate <2.79 9.96 2.79 ug/L 03/27/23 08:44 03/27/23 22:41 1 Fluoranthene <1.59 9.96 1.59 ug/L 03/27/23 08:44 03/27/23 22:41 1 Fluorene <3.39 9.96 3.39 ug/L 03/27/23 08:44 03/27/23 22:41 1 Hexachlorobenzene <1.59 9.96 1.59 ug/L 03/27/23 08:44 03/27/23 22:41 1 Hexachlorocyclopentadiene <3.49 9.96 3.49 ug/L 03/27/23 08:44 03/27/23 22:41 1 Eurofins Raleigh Page 57 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Hexachloroethane <3.58 9.96 3.58 ug/L 03/27/23 08:44 03/27/23 22:41 1 Indeno[1,2,3-cd]pyrene <4.28 9.96 4.28 ug/L 03/27/23 08:44 03/27/23 22:41 1 �. Isophorone <1.99 9.96 1.99 ug/L 03/27/23 08:44 03/27/23 22:41 1 Nitrobenzene <3.49 9.96 3.49 ug/L 03/27/23 08:44 03/27/23 22:41 1 N-Nitrosodimethylamine <2.09 9.96 2.09 ug/L 03/27/23 08:44 03/27/23 22:41 1 N-Nitrosodi-n-propylamine <2.39 9.96 2.39 ug/L 03/27/23 08:44 03/27/23 22:41 1 N-Nitrosodiphenylamine <2.89 9.96 2.89 ug/L 03/27/23 08:44 03/27/23 22:41 1 Phenanthrene <4.28 9.96 4.28 ug/L 03/27/23 08:44 03/27/23 22:41 1 Phenol <1.49 9.96 1.49 ug/L 03/27/23 08:44 03/27/23 22:41 1 Pyrene <3.68 9.96 3.68 ug/L 03/27/23 08:44 03/27/23 22:41 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4, 6-Tribromophenol (Surr) 87 30 - 130 03/27/23 08:44 03/27/23 22:41 1 2-Fluorobiphenyl (Surr) 71 25 - 130 03/27/23 08:44 03/27/23 22:41 1 2-Fluorophenol (Surr) 39 10 - 130 03/27/23 08:44 03/27/23 22:41 1 Nitrobenzene-d5 (Surr) 72 30 - 130 03/27/23 08:44 03/27/23 22:41 1 Phenol-d5 (Surr) 26 10 - 130 03/27/23 08:44 03/27/23 22:41 1 Terphenyl-d14 (Surr) 101 35- 131 03/27/23 08:44 03/27/23 22:41 1 Method: SW846 8081 B - Organochlorine Pesticides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 4,4'-DDE <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 4,4'-DDT <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 Aldrin <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 alpha-BHC <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 beta-BHC <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Chlordane (technical) <0.168 0.526 0.168 ug/L 03/30/23 00:24 1 Chlorobenzilate <0.673 3.16 0.673 ug/L 03/30/23 00:24 1 delta-BHC <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Dieldrin <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Endosulfan 1 <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Endosulfan 11 <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Endosulfan sulfate <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Endrin <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 Endrin aldehyde <0.00421 0.0526 0.00421 ug/L 03/30/23 00:24 1 gamma-BHC (Lindane) <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 Heptachlor <0.00105 0.0526 0.00105 ug/L 03/30/23 00:24 1 Heptachlor epoxide <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Isodrin <0.0116 0.0526 0.0116 ug/L 03/30/23 00:24 1 Kepone <2.73 5.26 2.73 ug/L 03/30/23 00:24 1 Methoxychlor <0.00210 0.0526 0.00210 ug/L 03/30/23 00:24 1 Toxaphene <0.326 5.26 0.326 ug/L 03/30/23 00:24 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 69 30- 130 03/30/23 00:24 1 Tetrachloro-m-xylene 50 30 - 130 03/30/23 00:24 1 Eurofins Raleigh Page 58 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac PCB-1016 <0.337 1.05 0.337 ug/L 03/30/23 00:24 1 PCB-1221 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 PCB-1232 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 PCB-1242 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 PCB-1248 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 PCB-1254 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 PCB-1260 <0.358 1.05 0.358 ug/L 03/30/23 00:24 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac C Tetrachloro-m-xylene 50 30 - 130 03/30/23 00:24 1 DCB Decachlorobiphenyl 69 30- 130 03/30/23 00:24 1 Method: SW846 8151A- Herbicides (GC) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0220 0.239 0.0220 ug/L 03/27/23 10:41 03/29/23 21:43 1 Dinoseb <0.0955 0.477 0.0955 ug/L 03/27/23 10:41 03/29/23 21:43 1 Silvex (2,4,5-TP) <0.0917 0.812 0.0917 ug/L 03/27/23 10:41 03/29/23 21:43 1 2,4,5-T <0.134 0.812 0.134 ug/L 03/27/23 10:41 03/29/23 21:43 1 2,4-D <0.172 1.05 0.172 ug/L 03/27/23 10:41 03/29/23 21:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 81 p 26 - 137 03/27/23 10:41 03/29/23 21:43 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/27/23 19:19 1 Barium <4.40 10.0 4.40 ug/L 03/25/23 07:48 03/27/23 19:19 1 Beryllium 0.640 J B 4.00 0.300 ug/L 03/25/23 07:48 03/27/23 19:19 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/27/23 19:19 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/27/23 19:19 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/27/23 19:19 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/27/23 19:19 1 Iron <20.0 100 20.0 ug/L 03/25/23 07:48 03/27/23 19:19 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/27/23 19:19 1 Manganese <1.30 10.0 1.30 ug/L 03/25/23 07:48 03/27/23 19:19 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/27/23 19:19 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/27/23 19:19 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/27/23 19:19 1 Tin <11.0 50.0 11.0 ug/L 03/25/23 07:48 03/27/23 19:19 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/27/23 19:19 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/27/23 19:19 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 17:06 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 17:06 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/30/23 09:56 03/30/23 15:49 1 Eurofins Raleigh Page 59 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 General Chemistry Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DNI Fac Cyanide, Total (SW846 9012B) 0.00445 J 0.0100 0.00250 mg/L 03/30/23 08:30 03/30/23 12:36 1 Analyte Result Qualifier RL RL Unit D Prepared Analyzed DIN Fac • Sulfide (SM 4500 S2 F-2011) <0.962 0.962 0.962 mg/L 03/28/23 13:30 1 Client Sample ID: 4501-AMW1D Lab Sample ID: 752-4750-1 Date Collected: 03/21/23 10:45 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DNI Fac 1,4-Dioxane 12.2 0.500 0.320 ug/L 03/31/2318:56 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 87 70 - 130 03/31/23 18:56 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed DNI Fac 1,1,1,2-Tetrachloroethane <0.170 *1 1.00 0.170 ug/L 04/03/23 21:31 1 1,1,1-Trichloroethane <0.120 *1 1.00 0.120 ug/L 04/03/23 21:31 1 1,1,2,2-Tetrachloroethane <0.280 *1 1.00 0.280 ug/L 04/03/23 21:31 1 1,1,2-Trichloroethane <0.140 *1 1.00 0.140 ug/L 04/03/23 21:31 1 1,1-Dichloroethane 0.239 J *- *1 1.00 0.130 ug/L 04/03/23 21:31 1 1,1-Dichloroethene <0.210 *1 1.00 0.210 ug/L 04/03/23 21:31 1 1,2,3-Trichloropropane <0.490 *1 1.00 0.490 ug/L 04/03/23 21:31 1 1,2-Dibromo-3-Chloropropane <0.480 *1 1.00 0.480 ug/L 04/03/23 21:31 1 1,2-Dibromoethane <0.660 *1 1.00 0.660 ug/L 04/03/23 21:31 1 1,2-Dichlorobenzene 0.538 J *1 1.00 0.190 ug/L 04/03/23 21:31 1 1,2-Dichloroethane <0.210 *1 1.00 0.210 ug/L 04/03/23 21:31 1 1,2-Dichloropropane <0.100 *- *1 1.00 0.100 ug/L 04/03/23 21:31 1 1,4-Dichlorobenzene 3.70 *1 1.00 0.190 ug/L 04/03/23 21:31 1 2-Butanone (MEK) <10.0 *1 20.0 10.0 ug/L 04/03/23 21:31 1 2-Hexanone <0.880 *1 5.00 0.880 ug/L 04/03/23 21:31 1 4-Methyl-2-pentanone (MIBK) <1.10 *1 5.00 1.10 ug/L 04/03/23 21:31 1 Acetone <10.0 20.0 10.0 ug/L 04/03/23 21:31 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/03/23 21:31 1 Benzene 1.05 *- *1 1.00 0.150 ug/L 04/03/23 21:31 1 Bromochloromethane <0.480 *- *1 1.00 0.480 ug/L 04/03/23 21:31 1 Bromodichloromethane <0.170 *1 1.00 0.170 ug/L 04/03/23 21:31 1 Bromoform <0.220 1.00 0.220 ug/L 04/03/23 21:31 1 Bromomethane <0.140 1.00 0.140 ug/L 04/03/23 21:31 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/03/23 21:31 1 Carbon tetrachloride <0.170 *1 1.00 0.170 ug/L 04/03/23 21:31 1 Chlorobenzene 9.73 *- *1 1.00 0.170 ug/L 04/03/23 21:31 1 Chloroethane <0.230 1.00 0.230 ug/L 04/03/23 21:31 1 Chloroform <0.180 *- *1 1.00 0.180 ug/L 04/03/23 21:31 1 Chloromethane <0.130 1.00 0.130 ug/L 04/03/23 21:31 1 cis-1,2-Dichloroethene 0.878 J *1 B 1.00 0.150 ug/L 04/03/23 21:31 1 cis-1,3-Dichloropropene <0.200 *1 1.00 0.200 ug/L 04/03/23 21:31 1 Dibromochloromethane <0.170 *1 1.00 0.170 ug/L 04/03/23 21:31 1 Dibromomethane <0.270 *1 1.00 0.270 ug/L 04/03/23 21:31 1 Eurofins Raleigh Page 60 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW1D Lab Sample ID: 752-4750-1 Date Collected: 03/21/23 10:45 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethylbenzene <0.130 *1 1.00 0.130 ug/L 04/03/23 21:31 1 lodomethane <1.70 *1 5.00 1.70 ug/L 04/03/23 21:31 1 �. Methylene Chloride <0.230 *1 1.00 0.230 ug/L 04/03/23 21:31 1 Styrene <0.110 *- 1.00 0.110 ug/L 04/03/23 21:31 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/03/23 21:31 1 Toluene <0.140 *1 1.00 0.140 ug/L 04/03/23 21:31 1 trans- 1,2-Dichloroethene <0.210 *- *1 1.00 0.210 ug/L 04/03/23 21:31 1 trans- 1,3-Dichloropropene <0.150 *1 1.00 0.150 ug/L 04/03/23 21:31 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/03/23 21:31 1 Trichloroethene <0.150 *1 1.00 0.150 ug/L 04/03/23 21:31 1 Trichlorofluoromethane <0.240 *+ *1 1.00 0.240 ug/L 04/03/23 21:31 1 Vinyl acetate <0.950 *1 5.00 0.950 ug/L 04/03/23 21:31 1 Vinyl chloride <0.320 *+ *1 1.00 0.320 ug/L 04/03/23 21:31 1 Xylenes, Total <0.450 *1 3.00 0.450 ug/L 04/03/23 21:31 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 117 53 - 136 04103123 21:31 1 Dibromofluoromethane (Surr) 116 67 - 129 04103123 21.31 1 Toluene-d8 (Surr) 106 59 - 134 04103123 21:31 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:19 1 Barium 14.2 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:19 1 Beryllium 0.570 J B 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:19 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:19 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:19 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:19 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:19 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:19 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:19 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:19 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:19 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:19 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:19 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 20:13 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 20:13 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Mercury <0.0800 0.200 0.0800 ug/L 03/27/2314:22 03/28/2312:00 1 Eurofins Raleigh Page 61 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW2D Lab Sample ID: 752-4750-2 Date Collected: 03/21/23 11:55 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL 1,4-Dioxane 1.38 0.500 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 88 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 *1 1.00 1,1,1-Trichloroethane <0.120 *1 1.00 1,1,2,2-Tetrachloroethane <0.280 *1 1.00 1,1,2-Trichloroethane <0.140 *1 1.00 1,1-Dichloroethane 0.331 J *- *1 1.00 1,1-Dichloroethene <0.210 *1 1.00 1,2,3-Trichloropropane <0.490 *1 1.00 1,2-Dibromo-3-Chloropropane <0.480 *1 1.00 1,2-Dibromoethane <0.660 *1 1.00 1,2-Dichlorobenzene <0.190 *1 1.00 1,2-Dichloroethane <0.210 *1 1.00 1,2-Dichloropropane <0.100 *-*1 1.00 1,4-Dichlorobenzene <0.190 *1 1.00 2-Butanone (MEK) <10.0 *1 20.0 2-Hexanone <0.880 *1 5.00 4-Methyl-2-pentanone (MIBK) <1.10 *1 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene <0.150 *- *1 1.00 Bromochloromethane <0.480 *- *1 1.00 Bromodichloromethane <0.170 *1 1.00 Bromoform <0.220 1.00 Bromomethane <0.140 1.00 Carbon disulfide <1.50 5.00 Carbon tetrachloride <0.170 *1 1.00 Chlorobenzene <0.170 * *1 1.00 Chloroethane <0.230 1.00 Chloroform <0.180 * *1 1.00 Chloromethane <0.130 1.00 cis-1,2-Dichloroethene <0.150 *1 1.00 cis-1,3-Dichloropropene <0.200 *1 1.00 Dibromochloromethane <0.170 *1 1.00 Dibromomethane <0.270 *1 1.00 Ethylbenzene <0.130 *1 1.00 lodomethane <1.70 *1 5.00 Methylene Chloride <0.230 *1 1.00 Styrene <0.110 *- 1.00 Tetrachloroethene <0.170 1.00 Toluene <0.140 *1 1.00 trans- 1,2-Dichloroethene <0.210 *-*1 1.00 trans- 1,3-Dichloropropene <0.150 *1 1.00 trans- 1,4-Dichloro-2-butene <0.700 1.00 Trichloroethene <0.150 *1 1.00 MDL Unit D Prepared Analyzed Dil Fac 0.320 ug/L 03/31/2319:23 1 • Prepared Analyzed Dil Fac 03/31/23 19:23 1 MDL Unit D Prepared Analyzed Dil Fac C 0.170 ug/L 04/03/23 22:00 1 0.120 ug/L 04/03/23 22:00 1 0.280 ug/L 04/03/23 22:00 1 0.140 ug/L 04/03/23 22:00 1 0.130 ug/L 04/03/23 22:00 1 0.210 ug/L 04/03/23 22:00 1 0.490 ug/L 04/03/23 22:00 1 0.480 ug/L 04/03/23 22:00 1 0.660 ug/L 04/03/23 22:00 1 0.190 ug/L 04/03/23 22:00 1 0.210 ug/L 04/03/23 22:00 1 0.100 ug/L 04/03/23 22:00 1 0.190 ug/L 04/03/23 22:00 1 10.0 ug/L 04/03/23 22:00 1 0.880 ug/L 04/03/23 22:00 1 1.10 ug/L 04/03/23 22:00 1 10.0 ug/L 04/03/23 22:00 1 3.50 ug/L 04/03/23 22:00 1 0.150 ug/L 04/03/23 22:00 1 0.480 ug/L 04/03/23 22:00 1 0.170 ug/L 04/03/23 22:00 1 0.220 ug/L 04/03/23 22:00 1 0.140 ug/L 04/03/23 22:00 1 1.50 ug/L 04/03/23 22:00 1 0.170 ug/L 04/03/23 22:00 1 0.170 ug/L 04/03/23 22:00 1 0.230 ug/L 04/03/23 22:00 1 0.180 ug/L 04/03/23 22:00 1 0.130 ug/L 04/03/23 22:00 1 0.150 ug/L 04/03/23 22:00 1 0.200 ug/L 04/03/23 22:00 1 0.170 ug/L 04/03/23 22:00 1 0.270 ug/L 04/03/23 22:00 1 0.130 ug/L 04/03/23 22:00 1 1.70 ug/L 04/03/23 22:00 1 0.230 ug/L 04/03/23 22:00 1 0.110 ug/L 04/03/23 22:00 1 0.170 ug/L 04/03/23 22:00 1 0.140 ug/L 04/03/23 22:00 1 0.210 ug/L 04/03/23 22:00 1 0.150 ug/L 04/03/23 22:00 1 0.700 ug/L 04/03/23 22:00 1 0.150 ug/L 04/03/23 22:00 1 Eurofins Raleigh Page 62 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-AMW2D Lab Sample ID: 752-4750-2 Date Collected: 03/21/23 11:55 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Trichlorofluoromethane <0.240 *+ *1 1.00 0.240 ug/L 04/03/23 22:00 1 Vinyl acetate <0.950 *1 5.00 0.950 ug/L 04/03/23 22:00 1 ■:1 Vinyl chloride <0.320 *+ *1 1.00 0.320 ug/L 04/03/23 22:00 1 Xylenes, Total <0.450 *1 3.00 0.450 ug/L 04/03/23 22:00 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 111 53 - 136 04103123 22:00 1 Dibromofluoromethane (Surr) 114 67- 129 04/03/23 22:00 1 Toluene-d8 (Surr) 106 59 - 134 04/03/23 22:00 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:36 1 Barium <4.40 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:36 1 Beryllium 0.510 J B 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:36 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:36 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:36 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:36 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:36 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:36 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:36 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:36 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:36 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:36 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:36 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 20:33 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 20:33 1 Method: SW846 7470A - Mercury (CVAA) Analyte Result Qualifier Mercury <0.0800 Client Sample ID: 4501-BR1 Date Collected: 03/22/23 09:57 Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier 1,4-Dioxane 0.794 RL MDL Unit D Prepared Analyzed Dil Fac 0.200 0.0800 ug/L 03/27/2314:22 03/28/2312:02 1 RL MDL Unit 0.500 0.320 ug/L Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 95 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 Lab Sample ID: 752-4750-3 Matrix: Surface Water D Prepared Analyzed Dil Fac 03/31 /23 19:50 1 Prepared Analyzed Dil Fac 03/31/23 19:50 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/05/2319:47 1 0.120 ug/L 04/05/2319:47 1 0.280 ug/L 04/05/2319:47 1 Page 63 of 242 Eurofins Raleigh 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-BR1 Lab Sample ID: 752-4750-3 Date Collected: 03/22/23 09:57 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/23 19:47 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/23 19:47 1 1,1-Dichloroethene <0.210 "- 1.00 0.210 ug/L 04/05/23 19:47 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/23 19:47 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/23 19:47 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/23 19:47 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 19:47 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/23 19:47 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/23 19:47 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 19:47 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 19:47 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 19:47 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 19:47 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 19:47 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 19:47 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 19:47 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 19:47 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 19:47 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 19:47 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 19:47 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 19:47 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 19:47 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 19:47 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 19:47 1 Chloroform 0.244 J B 1.00 0.180 ug/L 04/05/23 19:47 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 19:47 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 19:47 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 19:47 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 19:47 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 19:47 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 19:47 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 19:47 1 Methylene Chloride <0.230 1.00 0.230 ug/L 04/05/23 19:47 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 19:47 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 19:47 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 19:47 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 19:47 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 19:47 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 19:47 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 19:47 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 19:47 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 19:47 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 19:47 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 19:47 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 95 53- 136 04105123 19:47 1 Dibromofluoromethane (Surr) 91 67- 129 04105123 19:47 1 Toluene-d8 (Surr) 95 59 - 134 04105123 19:47 1 0 Eurofins Raleigh Page 64 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-BR1 Lab Sample ID: 752-4750-3 Date Collected: 03/22/23 09:57 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier Arsenic <6.40 Barium 29.3 Beryllium 0.590 J B Cadmium <0.440 Chromium <1.10 Cobalt <1.40 Copper <3.20 Lead <6.60 Nickel <3.30 Selenium <10.0 Silver <1.50 Vanadium 1.06 J Zinc <8.70 RL MDL Unit D Prepared Analyzed Dil Fac 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:42 1 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:42 1 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:42 1 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:42 1 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:42 1 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:42 1 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:42 1 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:42 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 20:41 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 20:41 1 Client Sample ID: 4501-BR2 Lab Sample ID: 752-4750-4 Date Collected: 03/22/23 08:50 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane 7.78 0.500 0.320 ug/L 03/31/23 20:17 1 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 86 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 *- 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene 0.323 J 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,4-Dichlorobenzene 1.29 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene <0.150 1.00 Prepared Analyzed Dil Fac 03/31/23 20:17 1 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/05/23 20:16 1 0.120 ug/L 04/05/23 20:16 1 0.280 ug/L 04/05/23 20:16 1 0.140 ug/L 04/05/23 20:16 1 0.130 ug/L 04/05/23 20:16 1 0.210 ug/L 04/05/23 20:16 1 0.490 ug/L 04/05/23 20:16 1 0.480 ug/L 04/05/23 20:16 1 0.660 ug/L 04/05/23 20:16 1 0.190 ug/L 04/05/23 20:16 1 0.210 ug/L 04/05/23 20:16 1 0.100 ug/L 04/05/23 20:16 1 0.190 ug/L 04/05/23 20:16 1 10.0 ug/L 04/05/23 20:16 1 0.880 ug/L 04/05/23 20:16 1 1.10 ug/L 04/05/23 20:16 1 10.0 ug/L 04/05/23 20:16 1 3.50 ug/L 04/05/23 20:16 1 0.150 ug/L 04/05/23 20:16 1 Eurofins Raleigh Page 65 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-BR2 Lab Sample ID: 752-4750-4 Date Collected: 03/22/23 08:50 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 20:16 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 20:16 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 20:16 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 20:16 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 20:16 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 20:16 1 Chlorobenzene 0.541 J 1.00 0.170 ug/L 04/05/23 20:16 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 20:16 1 Chloroform 0.280 J B 1.00 0.180 ug/L 04/05/23 20:16 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 20:16 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 20:16 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 20:16 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 20:16 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 20:16 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 20:16 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 20:16 1 Methylene Chloride 0.486 J B 1.00 0.230 ug/L 04/05/23 20:16 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 20:16 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 20:16 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 20:16 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 20:16 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 20:16 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 20:16 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 20:16 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 20:16 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 20:16 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 20:16 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 20:16 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 93 53 - 136 04105123 20:16 1 Dibromofluoromethane (Surr) 89 67- 129 04105123 20:16 1 Toluene-d8 (Surr) 94 59 - 134 04105123 20:16 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:23 1 Barium 178 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:23 1 Beryllium 0.530 J B 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:23 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:23 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:23 1 Cobalt 2.36 J 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:23 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:23 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:23 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:23 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:23 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:23 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:23 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:23 1 0 Eurofins Raleigh Page 66 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-BR2 Lab Sample ID: 752-4750-4 Date Collected: 03/22/23 08:50 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit Antimony <0.340 5.00 0.340 ug/L Thallium <0.260 1.00 0.260 ug/L Client Sample ID: 4501-BR3 Date Collected: 03/22/23 10:30 Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit 1,4-Dioxane 0.989 0.500 0.320 ug/L Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 88 70 - 130 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 1,1-Dichloroethene <0.210 `- 1.00 0.210 ug/L 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 2-Hexanone <0.880 5.00 0.880 ug/L 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L Acetone <10.0 20.0 10.0 ug/L Acrylonitrile <3.50 10.0 3.50 ug/L Benzene <0.150 1.00 0.150 ug/L Bromochloromethane <0.480 1.00 0.480 ug/L Bromodichloromethane <0.170 1.00 0.170 ug/L Bromoform <0.220 1.00 0.220 ug/L Bromomethane <0.140 1.00 0.140 ug/L Carbon disulfide <1.50 5.00 1.50 ug/L Carbon tetrachloride <0.170 1.00 0.170 ug/L Chlorobenzene 0.210 J 1.00 0.170 ug/L Chloroethane <0.230 1.00 0.230 ug/L Chloroform 0.293 J B 1.00 0.180 ug/L Chloromethane <0.130 1.00 0.130 ug/L cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L Dibromochloromethane <0.170 1.00 0.170 ug/L Dibromomethane <0.270 1.00 0.270 ug/L Ethylbenzene <0.130 1.00 0.130 ug/L D Prepared Analyzed Dil Fac 03/25/23 07:48 03/27/23 20:17 1 03/25/23 07:48 03/27/23 20:17 1 Lab Sample ID: 752-4750-5 Matrix: Surface Water L D Prepared Analyzed Dil Fac C 03/31/23 20:44 1 Prepared Analyzed Dfl Fac 03/31/23 20:44 1 D Prepared Analyzed 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 04/05/23 20:45 Eurofins Raleigh Page 67 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-BR3 Lab Sample ID: 752-4750-5 Date Collected: 03/22/23 10:30 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit lodomethane <1.70 5.00 1.70 ug/L Methylene Chloride 0.256 J B 1.00 0.230 ug/L Styrene <0.110 1.00 0.110 ug/L Tetrachloroethene <0.170 1.00 0.170 ug/L Toluene <0.140 1.00 0.140 ug/L trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L Trichloroethene <0.150 1.00 0.150 ug/L Trichlorofluoromethane <0.240 1.00 0.240 ug/L Vinyl acetate <0.950 5.00 0.950 ug/L Vinyl chloride <0.320 1.00 0.320 ug/L Xylenes, Total <0.450 3.00 0.450 ug/L Surrogate 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) D Prepared Analyzed Dil Fac 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 04/05/23 20:45 1 %Recovery Qualifier Limits Prepared Analyzed Dil Fac 92 53 - 136 04105123 20:45 1 84 67- 129 04105123 20:45 1 89 59 - 134 04105123 20:45 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier Arsenic <6.40 Barium 219 Beryllium 0.930 J B Cadmium 1.07 J Chromium <1.10 Cobalt 3.22 J Copper <3.20 Lead <6.60 Nickel 6.16 J Selenium <10.0 Silver <1.50 Vanadium <1.00 Zinc 39.7 RL MDL Unit D Prepared Analyzed Dil Fac 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:32 1 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:32 1 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:32 1 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:32 1 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:32 1 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:32 1 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:32 1 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:32 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 20:21 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 20:21 1 Client Sample ID: 4501-SW1 Lab Sample ID: 752-4750-6 Date Collected: 03/22/23 09:15 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D 1,4-Dioxane 1.63 0.500 0.320 ug/L Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 83 70 - 130 Prepared Analyzed Dil Fac 03/31/23 21:10 1 Prepared Analyzed Dil Fac 03/31/23 21:10 1 Eurofins Raleigh Page 68 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-SW1 Lab Sample ID: 752-4750-6 Date Collected: 03/22/23 09:15 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL 1,1,1,2-Tetrachloroethane <0.170 1.00 1,1,1-Trichloroethane <0.120 1.00 1,1,2,2-Tetrachloroethane <0.280 1.00 1,1,2-Trichloroethane <0.140 1.00 1,1-Dichloroethane <0.130 1.00 1,1-Dichloroethene <0.210 *- 1.00 1,2,3-Trichloropropane <0.490 1.00 1,2-Dibromo-3-Chloropropane <0.480 1.00 1,2-Dibromoethane <0.660 1.00 1,2-Dichlorobenzene <0.190 1.00 1,2-Dichloroethane <0.210 1.00 1,2-Dichloropropane <0.100 1.00 1,4-Dichlorobenzene <0.190 1.00 2-Butanone (MEK) <10.0 20.0 2-Hexanone <0.880 5.00 4-Methyl-2-pentanone (MIBK) <1.10 5.00 Acetone <10.0 20.0 Acrylonitrile <3.50 10.0 Benzene <0.150 1.00 Bromochloromethane <0.480 1.00 Bromodichloromethane <0.170 1.00 Bromoform <0.220 1.00 Bromomethane <0.140 1.00 Carbon disulfide <1.50 5.00 Carbon tetrachloride <0.170 1.00 Chlorobenzene <0.170 1.00 Chloroethane <0.230 1.00 Chloroform 0.223 J B 1.00 Chloromethane <0.130 1.00 cis-1,2-Dichloroethene <0.150 1.00 cis-1,3-Dichloropropene <0.200 1.00 Dibromochloromethane <0.170 1.00 Dibromomethane <0.270 1.00 Ethylbenzene <0.130 1.00 lodomethane <1.70 5.00 Methylene Chloride <0.230 1.00 Styrene <0.110 1.00 Tetrachloroethene <0.170 1.00 Toluene <0.140 1.00 trans- 1,2-Dichloroethene <0.210 1.00 trans- 1,3-Dichloropropene <0.150 1.00 trans- 1,4-Dichloro-2-butene <0.700 1.00 Trichloroethene <0.150 1.00 Trichlorofluoromethane <0.240 1.00 Vinyl acetate <0.950 5.00 Vinyl chloride <0.320 1.00 Xylenes, Total <0.450 3.00 Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 92 53 - 136 MDL Unit D Prepared Analyzed Dil Fac 0.170 ug/L 04/05/23 21:14 1 0.120 ug/L 04/05/23 21:14 1 0.280 ug/L 04/05/23 21:14 1 0.140 ug/L 04/05/23 21:14 1 0.130 ug/L 04/05/23 21:14 1 0.210 ug/L 04/05/23 21:14 1 0.490 ug/L 04/05/23 21:14 1 0.480 ug/L 04/05/23 21:14 1 0.660 ug/L 04/05/23 21:14 1 0.190 ug/L 04/05/23 21:14 1 0.210 ug/L 04/05/23 21:14 1 0.100 ug/L 04/05/23 21:14 1 0.190 ug/L 04/05/23 21:14 1 10.0 ug/L 04/05/23 21:14 1 0.880 ug/L 04/05/23 21:14 1 1.10 ug/L 04/05/23 21:14 1 10.0 ug/L 04/05/23 21:14 1 3.50 ug/L 04/05/23 21:14 1 0.150 ug/L 04/05/23 21:14 1 0.480 ug/L 04/05/23 21:14 1 0.170 ug/L 04/05/23 21:14 1 0.220 ug/L 04/05/23 21:14 1 0.140 ug/L 04/05/23 21:14 1 1.50 ug/L 04/05/23 21:14 1 0.170 ug/L 04/05/23 21:14 1 0.170 ug/L 04/05/23 21:14 1 0.230 ug/L 04/05/23 21:14 1 0.180 ug/L 04/05/23 21:14 1 0.130 ug/L 04/05/23 21:14 1 0.150 ug/L 04/05/23 21:14 1 0.200 ug/L 04/05/23 21:14 1 0.170 ug/L 04/05/23 21:14 1 0.270 ug/L 04/05/23 21:14 1 0.130 ug/L 04/05/23 21:14 1 1.70 ug/L 04/05/23 21:14 1 0.230 ug/L 04/05/23 21:14 1 0.110 ug/L 04/05/23 21:14 1 0.170 ug/L 04/05/23 21:14 1 0.140 ug/L 04/05/23 21:14 1 0.210 ug/L 04/05/23 21:14 1 0.150 ug/L 04/05/23 21:14 1 0.700 ug/L 04/05/23 21:14 1 0.150 ug/L 04/05/23 21:14 1 0.240 ug/L 04/05/23 21:14 1 0.950 ug/L 04/05/23 21:14 1 0.320 ug/L 04/05/23 21:14 1 0.450 ug/L 04/05/23 21:14 1 Prepared Analyzed Dil Fac 04105123 21:14 1 0 Eurofins Raleigh Page 69 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-SW1 Lab Sample ID: 752-4750-6 Date Collected: 03/22/23 09:15 Matrix: Surface Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Dibromofluoromethane (Surr) 89 67- 129 04105123 21:14 1 Toluene-d8 (Surr) 89 59 - 134 04105123 21:14 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:45 1 Barium 35.0 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:45 1 Beryllium 0.570 J B 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:45 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:45 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:45 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:45 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:45 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:45 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:45 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:45 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:45 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:45 1 Zinc 12.6 J 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:45 1 Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 20:45 1 Thallium <0.260 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 20:45 1 Client Sample ID: 4501-MW9 Lab Sample ID: 752-4750-7 Date Collected: 03/22/23 11:43 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.320 0.500 0.320 ug/L 03/31/2321:37 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 83 70 - 130 03/31/23 21:37 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/05/2321:43 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/05/2321:43 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/05/2321:43 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/2321:43 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/2321:43 1 1,1-Dichloroethene <0.210 "- 1.00 0.210 ug/L 04/05/2321:43 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/2321:43 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/2321:43 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/2321:43 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/2321:43 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/2321:43 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/2321:43 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/2321:43 1 Eurofins Raleigh Page 70 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW9 Lab Sample ID: 752-4750-7 Date Collected: 03/22/23 11:43 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 21:43 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 21:43 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 21:43 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 21:43 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 21:43 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 21:43 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 21:43 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 21:43 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 21:43 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 21:43 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 21:43 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 21:43 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 21:43 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 21:43 1 Chloroform 0.262 J B 1.00 0.180 ug/L 04/05/23 21:43 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 21:43 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 21:43 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 21:43 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 21:43 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 21:43 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 21:43 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 21:43 1 Methylene Chloride 0.294 J B 1.00 0.230 ug/L 04/05/23 21:43 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 21:43 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 21:43 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 21:43 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 21:43 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 21:43 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 21:43 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 21:43 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 21:43 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 21:43 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 21:43 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 21:43 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 95 53 - 136 04/05/23 21:43 1 Dibromofluoromethane (Surr) 88 67- 129 04/05/23 21:43 1 Toluene-d8 (Surr) 92 59 - 134 04/05/23 21:43 1 Method: SW846 6010D - Metals (ICP) - Total Recoverable Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:39 1 Barium 86.8 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:39 1 Beryllium 1.89 J B 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:39 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:39 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:39 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:39 1 Copper 14.8 J 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:39 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:39 1 0 Eurofins Raleigh Page 71 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW9 Lab Sample ID: 752-4750-7 Date Collected: 03/22/23 11:43 Matrix: Ground Water Date Received: 03/23/23 10:00 Method: SW846 6010D - Metals (ICP) - Total Recoverable (Continued) Analyte Result Qualifier RL MDL Unit Nickel <3.30 40.0 3.30 ug/L Selenium <10.0 20.0 10.0 ug/L Silver 1.59 J 10.0 1.50 ug/L Vanadium <1.00 10.0 1.00 ug/L Zinc <8.70 20.0 8.70 ug/L Method: SW846 6020B - Metals (ICP/MS) - Total Recoverable Analyte Result Qualifier RL MDL Unit Antimony <0.340 5.00 0.340 ug/L Thallium <0.260 1.00 0.260 ug/L D Prepared Analyzed Dil Fac 03/25/23 07:48 03/28/23 00:39 1 03/25/23 07:48 03/28/23 00:39 1 03/25/23 07:48 03/28/23 00:39 1 03/25/23 07:48 03/28/23 00:39 1 03/25/23 07:48 03/28/23 00:39 1 D Prepared Analyzed Dil Fac 03/25/23 07:48 03/27/23 20:37 1 03/25/23 07:48 03/27/23 20:37 1 Client Sample ID: 4501-Trip Blank Lab Sample ID: 752-4750-8 Date Collected: 03/22/23 08:50 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8260 SIM - 1,4-Dioxane by SIM Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.320 0.500 0.320 ug/L 03/31/2314:26 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 90 70 - 130 03/31/23 14:26 1 Method: SW846 8260D - Volatile Organic Compounds by GC/MS Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/05/23 17:50 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/05/23 17:50 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/23 17:50 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/23 17:50 1 1,1-Dichloroethene <0.210 *- 1.00 0.210 ug/L 04/05/23 17:50 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/23 17:50 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/23 17:50 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/23 17:50 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 17:50 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/23 17:50 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/23 17:50 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 17:50 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 17:50 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 17:50 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 17:50 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 17:50 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 17:50 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 17:50 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 17:50 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 17:50 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 17:50 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 17:50 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 17:50 1 Eurofins Raleigh Page 72 of 242 4/19/2023 Client Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Trip Blank Lab Sample ID: 752-4750-8 Date Collected: 03/22/23 08:50 Matrix: Water Date Received: 03/23/23 10:00 Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chloroform 0.503 J B 1.00 0.180 ug/L 04/05/23 17:50 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 17:50 1 �. cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 17:50 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 17:50 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 17:50 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 17:50 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 17:50 1 Methylene Chloride 0.470 J B 1.00 0.230 ug/L 04/05/23 17:50 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 17:50 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 17:50 1 Tetrahydrofuran <0.530 1.00 0.530 ug/L 04/05/23 17:50 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 17:50 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 17:50 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 17:50 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 17:50 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 17:50 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 17:50 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 17:50 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 17:50 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 17:50 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 93 53 - 136 04/05/23 17:50 1 Dibromofluoromethane (Surr) 92 67- 129 04105123 17:50 1 Toluene-d8 (Surr) 93 59 - 134 04105123 17:50 1 Eurofins Raleigh Page 73 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260 SIM - 1,4-Dioxane by SIM Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB Lab Sample ID Client Sample ID (70-130) 752-4652-1 4501-AM W 1 S 76 752-4652-2 4501-MW5(Background) 128 752-4652-3 4501-MW8 88 752-4652-3 MS 4501-MW8 100 752-4652-3 MSD 4501-MW8 116 752-4682-1 4501-M W6 86 752-4682-2 4501-MW7 80 752-4682-3 4501-MW10 77 752-4682-4 4501-MW11 89 752-4682-4 MS 4501-MW11 107 752-4682-4 MSD 4501-MW11 93 752-4682-5 4501-MW12 88 752-4682-6 4501-MW13 75 752-4748-1 4501-AM W2S 86 752-4750-1 4501-AM W 1 D 87 752-4750-2 4501-AM W2 D 88 752-4750-7 4501-MW9 83 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Method: 8260 SIM - 1,4-Dioxane by SIM Matrix: Surface Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB Lab Sample ID Client Sample ID (70-130) 752-4750-3 4501-BR1 95 752-4750-4 4501-BR2 86 752-4750-5 4501-BR3 88 752-4750-6 4501-SW1 83 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Method: 8260 SIM - 1,4-Dioxane by SIM Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB Lab Sample ID Client Sample ID (70-130) 752-4749-1 4501-Field Blank 86 752-4750-8 4501-Trip Blank 90 LCS 680-770326/3 Lab Control Sample 87 LCS 680-770731/3 Lab Control Sample 88 LCSD 680-770326/4 Lab Control Sample Dup 98 LCSD 680-770731/4 Lab Control Sample Dup 85 MB 680-770326/6 Method Blank 116 MB 680-770731/6 Method Blank 83 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Eurofins Raleigh Page 74 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB DBFM TOL Lab Sample ID Client Sample ID (53-136) (67-129) (59-134) 752-4652-1 4501-AM W 1 S 114 104 102 752-4652-2 4501-MW5(Background) 110 106 103 752-4652-3 4501-MW8 111 107 102 752-4652-3 MS 4501-MW8 115 106 103 752-4652-3 MSD 4501-MW8 114 108 103 752-4682-1 4501-MW6 115 112 108 752-4682-2 4501-M W7 116 108 107 752-4682-3 4501-MW10 113 111 108 752-4682-4 4501-M W 11 116 113 106 752-4682-4 MS 4501-MW11 114 111 108 752-4682-4 MSD 4501-MW11 118 111 109 752-4682-5 4501-MW12 113 112 110 752-4682-6 4501-M W 13 118 109 105 752-4682-7 4501-Old MW2 116 112 107 752-4748-1 4501-AMW2S 97 90 94 752-4750-1 4501-AM W 1 D 117 116 106 752-4750-2 4501-AM W2 D 111 114 106 752-4750-7 4501-MW9 95 88 92 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D - Volatile Organic Compounds by GC/MS Matrix: Surface Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB DBFM TOL Lab Sample ID Client Sample ID (53-136) (67-129) (59-134) 752-4750-3 4501-BR1 95 91 95 752-4750-4 4501-BR2 93 89 94 752-4750-5 4501-BR3 92 84 89 752-4750-6 4501-SW1 92 89 89 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8260D - Volatile Organic Compounds by GC/MS Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) Lab Sample ID Client Sample ID BFB (53-136) DBFM (67-129) TOL (59-134) 752-4749-1 4501-Field Blank 93 84 91 752-4750-8 4501-Trip Blank 93 92 93 LCS 752-2053/5 Lab Control Sample 113 105 103 LCS 752-2066/5 Lab Control Sample 94 88 86 LCS 752-2107/5 Lab Control Sample 115 112 106 Eurofins Raleigh Page 75 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) BFB DBFM TOL Lab Sample ID Client Sample ID (53-136) (67-129) (59-134) LCS 752-2111/5 Lab Control Sample 91 87 94 LCS 752-2118/5 Lab Control Sample 119 115 109 LCSD 752-2053/6 Lab Control Sample Dup 111 104 103 LCSD 752-2066/6 Lab Control Sample Dup 118 108 105 LCSD 752-2107/6 Lab Control Sample Dup 117 111 107 LCSD 752-2111/6 Lab Control Sample Dup 89 89 92 LCSD 752-2118/6 Lab Control Sample Dup 113 111 109 MB 752-2053/8 Method Blank 108 103 99 MB 752-2066/8 Method Blank 110 107 105 MB 752-2107/8 Method Blank 114 110 106 MB 752-2111/9 Method Blank 95 89 95 MB 752-2118/9 Method Blank 115 111 105 MRL 752-2053/4 Lab Control Sample 111 102 102 MRL 752-2066/4 Lab Control Sample 110 108 104 MRL 752-2107/4 Lab Control Sample 117 112 105 MRL 752-2111/7 Lab Control Sample 97 84 92 MRL 752-2118/4 Lab Control Sample 111 115 107 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane (Surr) TOL = Toluene-d8 (Surr) Method: 8270D - Semivolatile Organic Compounds (GC/MS) Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TBP FBP 2FP NBZ PHL TPHL Lab Sample ID Client Sample ID (30-130) (25-130) (10-130) (30-130) (10-130) (35-131) 752-4652-2 4501-MW5(Background) 96 65 40 69 28 71 752-4652-3 4501-MW8 86 68 38 73 28 67 752-4652-3 MS 4501-MW8 81 57 34 63 23 67 752-4652-3 MSD 4501-MW8 81 54 31 57 23 67 752-4682-1 4501-MW6 94 50 27 54 20 62 752-4682-2 4501-MW7 91 60 38 67 26 67 Surrogate Legend TBP = 2,4,6-Tribromophenol (Surr) FBP = 2-Fluorobiphenyl (Surr) 2FP = 2-Fluorophenol (Surr) NBZ = Nitrobenzene-d5 (Surr) PHL = Phenol-d5 (Surr) TPHL = Terphenyl-d14 (Surr) Method: 8270D - Semivolatile Organic Compounds (GC/MS) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TBP FBP 2FP NBZ PHL TPHL Lab Sample ID Client Sample ID (30-130) (25-130) (10-130) (30-130) (10-130) (35-131) 752-4749-1 4501-Field Blank 87 71 39 72 26 101 LCS 680-769544/2-A Lab Control Sample 81 60 33 66 23 67 Eurofins Raleigh Page 76 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TBP FBP 2FP NBZ PHL TPHL Lab Sample ID Client Sample ID (30-130) (25-130) (10-130) (30-130) (10-130) (35-131) LCS 680-769804/2-A Lab Control Sample 88 69 34 65 24 101 LCSD 680-769804/3-A Lab Control Sample Dup 84 66 33 61 23 92 MB 680-769544/1-A Method Blank 73 63 33 68 23 75 MB 680-769804/1-A Method Blank 82 72 34 67 22 107 Surrogate Legend TBP = 2,4,6-Tribromophenol (Surr) FBP = 2-Fluorobiphenyl (Surr) 2FP = 2-Fluorophenol (Surr) NBZ = Nitrobenzene-d5 (Surr) PHL = Phenol-d5 (Surr) TPHL = Terphenyl-d14 (Surr) Method: RSK-175 - Dissolved Gases (GC) Matrix: Ground Water Prep Tvne: Total/NA Lab Sample ID Client Sample ID Percent Surrogate Recovery (Acceptance Limits) ACL1 (50-150) 752-4652-1 4501-AM W 1 S 84 752-4652-2 4501-MW5(Background) 87 752-4652-3 4501-MW8 85 752-4652-3 MS 4501-MW8 96 752-4652-3 MSD 4501-MW8 99 752-4682-1 4501-M W6 83 752-4682-2 4501-MW7 84 752-4682-7 4501-Old MW2 87 752-4748-1 4501-AM W2S 85 Surrogate Legend L ACL = Acetylene Method: RSK-175 - Dissolved Gases (GC) Matrix: Water Lab Sample ID LCS 200-189816/2 LCS 200-189906/2 LCSD 200-189906/22 MB 200-189816/3 MB 200-189906/3 Surrogate Legend ACL = Acetylene Client Sample ID Lab Control Sample Lab Control Sample Lab Control Sample Dup Method Blank Method Blank Pre Percent Surrogate Recovery (Acceptance Limits) ACL1 (50-150) 91 93 91 81 78 Total/NA Page 77 of 242 Eurofins Raleigh 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Ground Water Prep Type: Total/NA Lab Sample ID 752-4652-2 752-4652-3 MSD 752-4682-2 Surrogate Legend Percent Surrogate Recovery (Acceptance Limits) DCBP1 TCX1 Client Sample ID (30-130) (30-130) 4501-MW5 (Background) 96 75 4501-MW8 66 62 4501-MW7 91 p 121 p DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Ground Water 0 F Prep Type: Total/NA F Percent Surrogate Recovery (Acceptance Limits) DCBP1 TCX2 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4652-3 4501-MW8 75 70 752-4652-3 MS 4501-MW8 58 60 Surrogate Legend DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCBP2 TCX2 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4682-1 4501-M W6 69 111 Surrogate Legend DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Water Prep Type: Total/NA Lab Sample ID Client Sample ID DCBP1 (30-130) Percent Surrogate Recovery (Acceptance Limits) TCX1 (30-130) 752-4749-1 4501-Field Blank 69 50 LCS 680-769227/2-A Lab Control Sample 99 75 LCS 680-770015/2-A Lab Control Sample 93 58 LCS 680-770015/4-A Lab Control Sample 102 64 LCSD 680-770015/5-A Lab Control Sample Dup 84 65 MB 680-769227/1-A Method Blank 83 64 Surrogate Legend DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Eurofins Raleigh Page 78 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCBP2 TCX2 Lab Sample ID Client Sample ID (30-130) (30-130) LCS 680-769585/2-A Lab Control Sample 104 68 MB 680-770015/1-A Method Blank 93 58 Surrogate Legend DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Method: 8081 B - Organochlorine Pesticides (GC) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCBP2 TCX1 Lab Sample ID Client Sample ID (30-130) (30-130) LCS 680-769585/5-A Lab Control Sample 110 69 LCSD 680-769585/6-A Lab Control Sample Dup 49 22 S1- LCSD 680-770015/3-A Lab Control Sample Dup 90 61 MB 680-769585/1-A Method Blank 105 68 Surrogate Legend C DCBP = DCB Decachlorobiphenyl TCX = Tetrachloro-m-xylene Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TCX2 DCBP2 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4652-3 MSD 4501-MW8 61 42 p 752-4682-1 4501-M W6 111 69 Surrogate Legend TCX = Tetrachloro-m-xylene DCBP = DCB Decachlorobiphenyl Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TCX1 DCBP1 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4652-2 4501-MW5 (Background) 75 96 752-4682-2 4501-MW7 121 p 91 p Surrogate Legend TCX = Tetrachloro-m-xylene DCBP = DCB Decachlorobiphenyl Eurofins Raleigh Page 79 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TCX2 DCBP1 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4652-3 4501-MW8 70 75 752-4652-3 MS 4501-MW8 68 56 Surrogate Legend TCX = Tetrachloro-m-xylene DCBP = DCB Decachlorobiphenyl Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography C Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) TCX1 DCBP1 Lab Sample ID Client Sample ID (30-130) (30-130) 752-4749-1 4501-Field Blank 50 69 LCS 680-769227/5-A Lab Control Sample 62 84 MB 680-769227/1-A Method Blank 64 83 Surrogate Legend TCX = Tetrachloro-m-xylene C DCBP = DCB Decachlorobiphenyl Method: 8151A - Herbicides (GC) Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCPAA2 Lab Sample ID Client Sample ID (26-137) 752-4652-2 4501-MW5(Background) 110 752-4652-3 4501-MW8 91 752-4652-3 MS 4501-MW8 85 752-4652-3 MSD 4501-MW8 92 Surrogate Legend DCPAA= DCAA Method: 8151A - Herbicides (GC) Matrix: Ground Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCPAA1 Lab Sample ID Client Sample ID (26-137) 752-4682-1 4501-MW6 65 p 752-4682-2 4501-MW7 55 p 752-4682-3 4501-M W 10 102 p 752-4682-4 4501-MW11 51 p 752-4682-4 MS 4501-MW11 58 p 752-4682-4 MSD 4501-MW11 3 p S1- 752-4682-5 4501-MW12 57 p 752-4682-6 4501-MW13 63 p Surrogate Legend DCPAA = DCAA Eurofins Raleigh Page 80 of 242 4/19/2023 Surrogate Summary Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8151A - Herbicides (GC) Matrix: Water Lab Sample ID Client Sample ID 752-4749-1 4501-Field Blank LCS 680-769824/2-A Lab Control Sample MB 680-769824/1-A Method Blank Surrogate Legend L DCPAA = DCAA F Job ID: 752-4652-1 Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) DCPAAI (26-137) 81 p 89 p 67 p Method: 8151A - Herbicides (GC) Matrix: Water DCPAA2 Lab Sample ID Client Sample ID (26-137) LCS 680-769190/2-A Lab Control Sample 106 MB 680-769190/1-A Method Blank 99 Surrogate Legend DCPAA = DCAA Pre Percent Surrogate Recovery (Acceptance Limits) 0 F Total/NA F Method: VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Matrix: Ground Water Prep Type: Total/NA 1 09_1 Lab Sample ID Client Sample ID 752-4652-1 4501-AM W 1 S 752-4652-2 4501-MW5(Background) 752-4652-3 4501-MW8 752-4682-1 4501-M W6 752-4682-2 4501-MW7 752-4682-7 4501-Old MW2 752-4748-1 4501-AM W2S Surrogate Legend PVA = Trimethylacetic Acid Percent Surrogate Recovery (Acceptance Limits) Method: VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Matrix: Water Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) PVA Lab Sample ID Client Sample ID (50-150) LCS 670-28303/3 Lab Control Sample NaN LCSD 670-28303/4 Lab Control Sample Dup NaN Surrogate Legend PVA = Trimethylacetic Acid Page 81 of 242 Eurofins Raleigh 4/19/2023 Surrogate Summary Client: WSP USA Inc Project/Site: Henderson County Landfills Method: VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Matrix: Water PVA Lab Sample ID Client Sample ID MB 670-28303/5 Method Blank Surrogate Legend L PVA = Trimethylacetic Acid Job ID: 752-4652-1 Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) Eurofins Raleigh Page 82 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260 SIM - 1,4-Dioxane by SIM Lab Sample ID: MB 680-770326/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 770326 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.320 0.500 0.320 ug/L 03/29/2316:56 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 116 70 - 130 03/29/23 16:56 1 Lab Sample ID: LCS 680-770326/3 Client Sample ID: Lab Control Sample • Matrix: Water Prep Type: Total/NA Analysis Batch: 770326 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 10.0 9.328 ug/L 93 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 87 70 - 130 Lab Sample ID: LCSD 680-77032614 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 770326 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 10.0 9.272 ug/L 93 70 -130 1 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 98 70 - 130 Lab Sample ID: MB 680-770731/6 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 770731 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,4-Dioxane <0.320 0.500 0.320 ug/L 03/31/2312:38 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 83 70 - 130 03/31/23 12:38 1 Lab Sample ID: LCS 680-770731/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770731 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 10.0 9.618 ug/L 96 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 88 70 - 130 Page 83 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260 SIM - 1,4-Dioxane by SIM (Continued) Lab Sample ID: LCSD 680-770731/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 770731 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 10.0 9.507 ug/L 95 70 -130 1 30 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 85 70 - 130 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 • Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 770731 Sample Sample Spike MS Ms %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 0.541 10.0 10.68 ug/L 101 70-130 MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 100 70 - 130 Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 770731 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 0.541 10.0 11.85 ug/L 113 70-130 10 30 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 116 70 -130 Lab Sample ID: 752-4682-4 MS Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 770731 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits 1,4-Dioxane 1.98 10.0 12.30 ug/L 103 70 -130 MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 107 70 - 130 Lab Sample ID: 752-4682-4 MSD Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 770731 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 1,4-Dioxane 1.98 10.0 12.09 ug/L 101 70 -130 2 30 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 93 70 - 130 Eurofins Raleigh Page 84 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS Lab Sample ID: MB 752-2053/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2053 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 03/31/23 20:42 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 03/31/23 20:42 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 03/31/23 20:42 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 03/31/23 20:42 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 03/31/23 20:42 1 1,1-Dichloropropene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 03/31/23 20:42 1 1,2,4-Trichlorobenzene <0.140 1.00 0.140 ug/L 03/31/23 20:42 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 03/31/23 20:42 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 03/31/23 20:42 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 03/31/23 20:42 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 03/31/23 20:42 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 03/31/23 20:42 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 03/31/23 20:42 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 03/31/23 20:42 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 03/31/23 20:42 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 03/31/23 20:42 1 2-Hexanone <0.880 5.00 0.880 ug/L 03/31/23 20:42 1 3-Chloropropene <0.110 1.00 0.110 ug/L 03/31/23 20:42 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 03/31/23 20:42 1 Acetone <10.0 20.0 10.0 ug/L 03/31/23 20:42 1 Acetonitrile <5.00 10.0 5.00 ug/L 03/31/23 20:42 1 Acrolein <4.00 10.0 4.00 ug/L 03/31/23 20:42 1 Acrylonitrile <3.50 10.0 3.50 ug/L 03/31/23 20:42 1 Benzene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 Bromochloromethane <0.480 1.00 0.480 ug/L 03/31/23 20:42 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 Bromoform <0.220 1.00 0.220 ug/L 03/31/23 20:42 1 Bromomethane <0.140 1.00 0.140 ug/L 03/31/23 20:42 1 Carbon disulfide <1.50 5.00 1.50 ug/L 03/31/23 20:42 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 Chlorobenzene <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 Chloroethane <0.230 1.00 0.230 ug/L 03/31/23 20:42 1 Chloroform <0.180 1.00 0.180 ug/L 03/31/23 20:42 1 Chloromethane <0.130 1.00 0.130 ug/L 03/31/23 20:42 1 Chloroprene <0.640 1.00 0.640 ug/L 03/31/23 20:42 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 03/31/23 20:42 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 Dibromomethane <0.270 1.00 0.270 ug/L 03/31/23 20:42 1 Dichlorodifluoromethane <0.200 1.00 0.200 ug/L 03/31/23 20:42 1 Ethyl methacrylate <0.380 1.00 0.380 ug/L 03/31/23 20:42 1 Ethylbenzene <0.130 1.00 0.130 ug/L 03/31/23 20:42 1 Hexachlorobutadiene <0.220 1.00 0.220 ug/L 03/31/23 20:42 1 lodomethane <1.70 5.00 1.70 ug/L 03/31/23 20:42 1 Isobutyl alcohol <11.0 50.0 11.0 ug/L 03/31/23 20:42 1 0 Eurofins Raleigh Page 85 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-205318 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2053 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Methacrylonitrile <4.90 10.0 4.90 ug/L 03/31/23 20:42 1 Methyl methacrylate <0.510 1.00 0.510 ug/L 03/31/23 20:42 1 Methylene Chloride <0.230 1.00 0.230 ug/L 03/31/23 20:42 1 Naphthalene <0.110 1.00 0.110 ug/L 03/31/23 20:42 1 Propionitrile <5.00 10.0 5.00 ug/L 03/31/23 20:42 1 Styrene <0.110 1.00 0.110 ug/L 03/31/23 20:42 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 03/31/23 20:42 1 Toluene <0.140 1.00 0.140 ug/L 03/31/23 20:42 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 03/31/23 20:42 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 03/31/23 20:42 1 Trichloroethene <0.150 1.00 0.150 ug/L 03/31/23 20:42 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 03/31/23 20:42 1 Vinyl acetate <0.950 5.00 0.950 ug/L 03/31/23 20:42 1 Vinyl chloride <0.320 1.00 0.320 ug/L 03/31/23 20:42 1 Xylenes, Total <0.450 3.00 0.450 ug/L 03/31/23 20:42 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 108 53 - 136 03/31/23 20:42 1 Dibromofluoromethane (Surr) 103 67- 129 03/31/23 20:42 1 Toluene-d8 (Surr) 99 59 - 134 03/31/23 20:42 1 Lab Sample ID: LCS 752-2053/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2053 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 20.0 18.51 ug/L 93 71-120 1,1,1-Trichloroethane 20.0 18.45 ug/L 92 72-143 1,1,2,2-Tetrachloroethane 20.0 18.38 ug/L 92 59-133 1,1,2-Trichloroethane 20.0 18.00 ug/L 90 67-120 1,1-Dichloroethane 20.0 17.36 ug/L 87 79-141 1,1-Dichloroethene 20.0 18.30 ug/L 92 75-133 1,1-Dichloropropene 20.0 18.62 ug/L 93 70-129 1,2,3-Trichloropropane 20.0 17.09 ug/L 85 69-127 1,2,4-Trichlorobenzene 20.0 16.87 ug/L 84 59 -122 1,2-Dibromo-3-Chloropropane 20.0 17.08 ug/L 85 37-157 1,2-Dibromoethane 20.0 18.80 ug/L 94 66-123 1,2-Dichlorobenzene 20.0 18.89 ug/L 94 76 -120 1,2-Dichloroethane 20.0 19.08 ug/L 95 72 -151 1,2-Dichloropropane 20.0 18.29 ug/L 91 78 -125 1,3-Dichlorobenzene 20.0 19.35 ug/L 97 76 -120 1,3-Dichloropropane 20.0 17.45 ug/L 87 60 -129 1,4-Dichlorobenzene 20.0 18.42 ug/L 92 76 -122 2,2-Dichloropropane 20.0 18.38 ug/L 92 21 -167 2-Butanone (MEK) 40.0 34.97 ug/L 87 36 -135 2-Hexanone 40.0 39.16 ug/L 98 36 -191 3-Chloropropene 20.0 19.07 ug/L 95 17 -147 Eurofins Raleigh Page 86 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCS 752-2053/5 Matrix: Water Analysis Batch: 2053 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added LCS Result LCS Qualifier Unit D %Rec %Rec Limits 4-Methyl-2-pentanone (MIBK) 40.0 40.50 ug/L 101 56-166 Acetone 40.0 33.35 ug/L 83 10-158 Acetonitrile 20.0 23.11 ug/L 116 10 - 200 Acrolein 40.0 8.572 J ug/L 21 10 - 200 Acrylonitrile 60.0 51.00 ug/L 85 10 - 200 Benzene 20.0 18.24 ug/L 91 80 -134 Bromochloromethane 20.0 17.04 ug/L 85 74 -128 Bromodichloromethane 20.0 18.95 ug/L 95 72 -129 Bromoform 20.0 18.03 ug/L 90 73 -120 Bromomethane 20.0 22.24 ug/L ill 38 -189 Carbon disulfide 20.0 19.67 ug/L 98 65 -173 Carbon tetrachloride 20.0 21.09 ug/L 105 68 -142 Chlorobenzene 20.0 18.75 ug/L 94 80 -120 Chloroethane 20.0 30.41 ug/L 152 45 - 213 Chloroform 20.0 16.48 ug/L 82 78 -138 Chloromethane 20.0 20.22 ug/L 101 56 -171 Chloroprene 20.0 19.48 ug/L 97 33 -148 cis-1,2-Dichloroethene 20.0 16.40 ug/L 82 69 -120 cis-1,3-Dichloropropene 20.0 19.18 ug/L 96 63 -125 Dibromochloromethane 20.0 18.40 ug/L 92 73 -120 Dibromomethane 20.0 18.58 ug/L 93 76 -124 Dichlorodifluoromethane 20.0 51.86 .+ ug/L 259 25 -161 Ethyl methacrylate 20.0 20.02 ug/L 100 51 -120 Ethylbenzene 20.0 18.66 ug/L 93 68 -124 Hexachlorobutadiene 20.0 22.21 ug/L ill 63-120 Iodomethane 20.0 20.68 ug/L 103 34 -140 Isobutyl alcohol 20.0 20.62 J ug/L 103 10 - 200 Methacrylonitrile 20.0 17.71 ug/L 89 10 - 200 Methyl methacrylate 20.0 18.50 ug/L 92 48 -126 Methylene Chloride 20.0 16.65 ug/L 83 68 -128 Naphthalene 20.0 17.92 ug/L 90 50 -127 Styrene 20.0 16.53 ug/L 83 73 -120 Tetrachloroethene 20.0 21.22 ug/L 106 40 -181 Toluene 20.0 18.40 ug/L 92 71 -120 trans- 1,2-Dichloroethene 20.0 16.74 ug/L 84 75-139 trans- 1,3-Dichloropropene 20.0 21.93 ug/L 110 65-152 trans- 1,4-Dichloro-2-butene 20.0 19.16 ug/L 96 10-142 Trichloroethene 20.0 18.80 ug/L 94 74 -120 Trichlorofluoromethane 20.0 40.11 .+ ug/L 201 68 -183 Vinyl acetate 20.0 22.14 ug/L ill 10 -198 Vinyl chloride 20.0 30.15 .+ ug/L 151 49 -150 Xylenes, Total 60.0 56.27 ug/L 94 77 -121 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 113 53 -136 Dibromofluoromethane (Surr) 105 67-129 Toluene-d8 (Surr) 103 59 -134 0 Eurofins Raleigh Page 87 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2053/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2053 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 20.0 19.32 ug/L 97 71-120 4 16 1,1,1-Trichloroethane 20.0 18.27 ug/L 91 72-143 1 18 1,1,2,2-Tetrachloroethane 20.0 18.13 ug/L 91 59-133 1 16 1,1,2-Trichloroethane 20.0 19.04 ug/L 95 67-120 6 18 1,1-Dichloroethane 20.0 17.13 ug/L 86 79-141 1 19 1,1-Dichloroethene 20.0 18.69 ug/L 93 75-133 2 20 1,1-Dichloropropene 20.0 18.90 ug/L 95 70-129 2 17 1,2,3-Trichloropropane 20.0 18.00 ug/L 90 69-127 5 17 1,2,4-Trichlorobenzene 20.0 17.58 ug/L 88 59 -122 4 17 1,2-Dibromo-3-Chloropropane 20.0 17.94 ug/L 90 37-157 5 18 1,2-Dibromoethane 20.0 18.61 ug/L 93 66-123 1 15 1,2-Dichlorobenzene 20.0 19.21 ug/L 96 76 -120 2 16 1,2-Dichloroethane 20.0 19.39 ug/L 97 72 -151 2 16 1,2-Dichloropropane 20.0 18.26 ug/L 91 78 -125 0 19 1,3-Dichlorobenzene 20.0 19.50 ug/L 98 76 -120 1 17 1,3-Dichloropropane 20.0 17.95 ug/L 90 60 -129 3 16 1,4-Dichlorobenzene 20.0 18.59 ug/L 93 76 -122 1 16 2,2-Dichloropropane 20.0 17.48 ug/L 87 21 -167 5 20 2-Butanone (MEK) 40.0 40.25 ug/L 101 36 -135 14 19 2-Hexanone 40.0 39.72 ug/L 99 36 -191 1 17 3-Chloropropene 20.0 18.34 ug/L 92 17 -147 4 19 4-Methyl-2-pentanone (MIBK) 40.0 41.92 ug/L 105 56-166 3 19 Acetone 40.0 32.91 ug/L 82 10-158 1 78 Acetonitrile 20.0 19.43 ug/L 97 10 - 200 17 35 Acrolein 40.0 9.257 J ug/L 23 10 - 200 8 50 Acrylonitrile 60.0 52.81 ug/L 88 10 - 200 3 36 Benzene 20.0 18.30 ug/L 92 80 -134 0 17 Bromochloromethane 20.0 17.49 ug/L 87 74 -128 3 18 Bromodichloromethane 20.0 19.21 ug/L 96 72 -129 1 16 Bromoform 20.0 18.70 ug/L 94 73 -120 4 44 Bromomethane 20.0 21.18 ug/L 106 38 -189 5 27 Carbon disulfide 20.0 19.50 ug/L 97 65 -173 1 38 Carbon tetrachloride 20.0 20.87 ug/L 104 68 -142 1 17 Chlorobenzene 20.0 18.84 ug/L 94 80 -120 0 16 Chloroethane 20.0 32.24 ug/L 161 45 - 213 6 26 Chloroform 20.0 16.67 ug/L 83 78 -138 1 17 Chloromethane 20.0 20.76 ug/L 104 56 -171 3 28 Chloroprene 20.0 19.29 ug/L 96 33 -148 1 19 cis-1,2-Dichloroethene 20.0 16.68 ug/L 83 69 -120 2 18 cis-1,3-Dichloropropene 20.0 19.70 ug/L 98 63 -125 3 17 Dibromochloromethane 20.0 18.81 ug/L 94 73 -120 2 16 Dibromomethane 20.0 18.65 ug/L 93 76 -124 0 15 Dichlorodifluoromethane 20.0 52.76 .+ ug/L 264 25 -161 2 48 Ethyl methacrylate 20.0 20.19 ug/L 101 51 -120 1 24 Ethylbenzene 20.0 18.36 ug/L 92 68 -124 2 16 Hexachlorobutadiene 20.0 21.29 ug/L 106 63 -120 4 19 lodomethane 20.0 20.88 ug/L 104 34 -140 1 15 Isobutyl alcohol 20.0 18.82 J ug/L 94 10 - 200 9 20 0 Eurofins Raleigh Page 88 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2053/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2053 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Methacrylonitrile 20.0 18.29 ug/L 91 10 - 200 3 50 Methyl methacrylate 20.0 18.95 ug/L 95 48 -126 2 50 Methylene Chloride 20.0 17.14 ug/L 86 68 -128 3 17 Naphthalene 20.0 18.56 ug/L 93 50 -127 4 19 Styrene 20.0 16.32 ug/L 82 73 -120 1 23 Tetrachloroethene 20.0 21.16 ug/L 106 40 -181 0 26 Toluene 20.0 18.54 ug/L 93 71 -120 1 17 trans- 1,2-Dichloroethene 20.0 16.58 ug/L 83 75-139 1 19 trans- 1,3-Dichloropropene 20.0 21.90 ug/L 109 65-152 0 16 trans- 1,4-Dichloro-2-butene 20.0 19.88 ug/L 99 10-142 4 28 Trichloroethene 20.0 18.46 ug/L 92 74 -120 2 22 Trichlorofluoromethane 20.0 39.74 *+ ug/L 199 68 -183 1 22 Vinyl acetate 20.0 22.21 ug/L ill 10 -198 0 21 Vinyl chloride 20.0 30.59 *+ ug/L 153 49 -150 1 27 Xylenes, Total 60.0 56.45 ug/L 94 77 -121 0 16 LCSD LCSD C Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 111 53 - 136 Dibromofluoromethane (Surr) 104 67- 129 Toluene-d8 (Surr) 103 59 - 134 Lab Sample ID: MRL 752-2053/4 Matrix: Water Analysis Batch: 2053 Analyte Spike Added MRL Result MRL Qualifier Client Sample ID: Lab Control Sample Prep Type: Total/NA %Rec Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 1.00 0.9736 J ug/L 97 1,1,1-Trichloroethane 1.00 0.9338 J ug/L 93 1,1,2,2-Tetrachloroethane 1.00 1.024 ug/L 102 1,1,2-Trichloroethane 1.00 0.9436 J ug/L 94 1,1-Dichloroethane 1.00 0.8644 J ug/L 86 1,1-Dichloroethene 1.00 1.476 ug/L 148 1,1-Dichloropropene 1.00 1.042 ug/L 104 1,2,3-Trichloropropane 1.00 0.8766 J ug/L 88 1,2,4-Trichlorobenzene 1.00 1.772 ug/L 177 1,2-Dibromo-3-Chloropropane 1.00 0.9318 J ug/L 93 1,2-Dibromoethane 1.00 1.012 ug/L 101 1,2-Dichlorobenzene 1.00 1.107 ug/L ill 1,2-Dichloroethane 1.00 1.144 ug/L 114 1,2-Dichloropropane 1.00 1.062 ug/L 106 1,3-Dichlorobenzene 1.00 1.239 ug/L 124 1,3-Dichloropropane 1.00 1.076 ug/L 108 1,4-Dichlorobenzene 1.00 1.189 ug/L 119 2,2-Dichloropropane 1.00 0.9489 J ug/L 95 2-Butanone (MEK) 2.00 <10.0 ug/L 154 2-Hexanone 2.00 2.603 J ug/L 130 3-Chloropropene 1.00 1.035 ug/L 104 4-Methyl-2-pentanone (MIBK) 2.00 1.902 J ug/L 95 Eurofins Raleigh Page 89 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2053/4 Matrix: Water Analysis Batch: 2053 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added MRL Result MRL Qualifier Unit %Rec D %Rec Limits Acetone 2.00 <10.0 ug/L 0 Acetonitrile 10.0 14.80 ug/L 148 Acrolein 5.00 <4.00 ug/L 73 Acrylonitrile 5.00 4.670 J ug/L 93 Benzene 1.00 1.029 ug/L 103 Bromochloromethane 1.00 1.139 ug/L 114 Bromodichloromethane 1.00 0.9187 J ug/L 92 Bromoform 1.00 1.432 ug/L 143 Bromomethane 1.00 1.355 ug/L 135 Carbon disulfide 2.00 2.640 J ug/L 132 Carbon tetrachloride 1.00 1.002 ug/L 100 Chlorobenzene 1.00 1.095 ug/L 110 Chloroethane 1.00 0.9450 J ug/L 94 Chloroform 1.00 0.9020 J ug/L 90 Chloromethane 1.00 1.357 ug/L 136 Chloroprene 1.00 0.8587 J ug/L 86 cis-1,2-Dichloroethene 1.00 0.9540 J ug/L 95 cis-1,3-Dichloropropene 1.00 0.9287 J ug/L 93 Dibromochloromethane 1.00 0.9653 J ug/L 97 Dibromomethane 1.00 1.098 ug/L 110 Dichlorodifluoromethane 1.00 1.686 ug/L 169 Ethyl methacrylate 1.00 0.8711 J ug/L 87 Ethylbenzene 1.00 1.000 ug/L 100 Hexachlorobutadiene 1.00 1.576 ug/L 158 lodomethane 2.00 3.900 J ug/L 195 Isobutyl alcohol 20.0 17.60 J ug/L 88 Methacrylonitrile 10.0 9.802 J ug/L 98 Methyl methacrylate 1.00 0.7513 J ug/L 75 Methylene Chloride 1.00 1.166 ug/L 117 Naphthalene 1.00 1.854 ug/L 185 Styrene 1.00 1.282 ug/L 128 Tetrachloroethene 1.00 1.192 ug/L 119 Toluene 1.00 1.098 ug/L 110 trans- 1,2-Dichloroethene 1.00 1.305 ug/L 131 trans- 1,3-Dichloropropene 1.00 1.112 ug/L ill trans- 1,4-Dichloro-2-butene 1.00 1.078 ug/L 108 Trichloroethene 1.00 0.9658 J ug/L 97 Trichlorofluoromethane 1.00 1.445 ug/L 145 Vinyl acetate 2.00 1.691 J ug/L 85 Vinyl chloride 1.00 1.209 ug/L 121 Xylenes, Total 3.00 2.979 J ug/L 99 MRL MRL Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 111 53 - 136 Dibromofluoromethane (Surr) 102 67 - 129 Toluene-d8 (Surr) 102 59 - 134 0 Eurofins Raleigh Page 90 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2053 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane <0.170 20.0 19.65 ug/L 98 71-120 1,1,1-Trichloroethane <0.120 20.0 20.06 ug/L 100 72-143 1,1,2,2-Tetrachloroethane <0.280 20.0 18.87 ug/L 94 59-133 1,1,2-Trichloroethane <0.140 20.0 19.28 ug/L 96 67-120 1,1-Dichloroethane <0.130 20.0 18.53 ug/L 93 79-141 1,1-Dichloroethene <0.210 20.0 20.90 ug/L 105 75-133 1,1-Dichloropropene <0.150 20.0 19.45 ug/L 97 70-129 1,2,3-Trichloropropane <0.490 20.0 18.57 ug/L 93 1 -210 1,2,4-Trichlorobenzene <0.140 20.0 17.71 ug/L 89 59 -122 1,2-Dibromo-3-Chloropropane <0.480 20.0 19.50 ug/L 97 37-157 1,2-Dibromoethane <0.660 20.0 18.94 ug/L 95 66-123 1,2-Dichlorobenzene <0.190 20.0 19.02 ug/L 95 76 -120 1,2-Dichloroethane <0.210 20.0 20.60 ug/L 103 72 -151 1,2-Dichloropropane <0.100 20.0 18.98 ug/L 95 78 -125 1,3-Dichlorobenzene <0.150 20.0 19.56 ug/L 98 76 -120 1,3-Dichloropropane <0.160 20.0 17.81 ug/L 89 60 -129 1,4-Dichlorobenzene <0.190 20.0 18.41 ug/L 92 76 -122 2,2-Dichloropropane <0.280 20.0 16.22 ug/L 81 21 -167 2-Butanone (MEK) <10.0 40.0 37.37 ug/L 93 36 -135 2-Hexanone <0.880 40.0 43.84 ug/L 110 36 -191 3-Chloropropene <0.110 20.0 19.82 ug/L 99 17 -147 4-Methyl-2-pentanone (MIBK) <1.10 40.0 47.23 ug/L 118 56-166 Acetone <10.0 40.0 41.95 ug/L 105 10 -158 Acetonitrile <5.00 20.0 23.35 ug/L 117 10 - 200 Acrolein <4.00 40.0 9.460 J ug/L 24 10 - 200 Acrylonitrile <3.50 60.0 57.73 ug/L 96 10 - 200 Benzene <0.150 20.0 18.98 ug/L 95 80 -134 Bromochloromethane <0.480 20.0 18.75 ug/L 94 74 -128 Bromodichloromethane <0.170 20.0 20.07 ug/L 100 72 -129 Bromoform <0.220 20.0 18.56 ug/L 93 73 -120 Bromomethane <0.140 20.0 25.58 ug/L 128 38 -189 Carbon disulfide <1.50 20.0 21.34 ug/L 107 65 -173 Carbon tetrachloride <0.170 20.0 21.96 ug/L 110 68 -142 Chlorobenzene <0.170 20.0 19.05 ug/L 95 80 -120 Chloroethane <0.230 20.0 35.36 ug/L 177 45 - 213 Chloroform <0.180 20.0 18.35 ug/L 92 78 -138 Chloromethane <0.130 20.0 22.66 ug/L 113 56 -171 Chloroprene <0.640 20.0 21.74 ug/L 109 33 -148 cis-1,2-Dichloroethene <0.150 20.0 18.10 ug/L 90 69 -120 cis-1,3-Dichloropropene <0.200 20.0 18.74 ug/L 94 63 -125 Dibromochloromethane <0.170 20.0 19.03 ug/L 95 73 -120 Dibromomethane <0.270 20.0 19.38 ug/L 97 76 -124 Dichlorodifluoromethane <0.200 "+ F1 20.0 50.30 F1 ug/L 251 25 -161 Ethyl methacrylate <0.380 20.0 21.25 ug/L 106 51 -120 Ethylbenzene <0.130 20.0 18.10 ug/L 90 68 -124 Hexachlorobutadiene <0.220 20.0 21.45 ug/L 107 63 -120 lodomethane <1.70 20.0 20.24 ug/L 101 34 -140 Isobutyl alcohol <11.0 20.0 15.35 J ug/L 77 10 - 200 0 Eurofins Raleigh Page 91 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2053 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Methacrylonitrile <4.90 20.0 19.36 ug/L 97 10 - 200 Methyl methacrylate <0.510 20.0 20.19 ug/L 101 48 -126 Methylene Chloride <0.230 20.0 17.75 ug/L 89 68 -128 Naphthalene <0.110 20.0 19.97 ug/L 100 50 -127 Styrene <0.110 20.0 16.35 ug/L 82 73 -120 Tetrachloroethene <0.170 20.0 20.59 ug/L 103 40 -181 Toluene <0.140 20.0 18.35 ug/L 92 71 -120 trans- 1,2-Dichloroethene <0.210 20.0 17.76 ug/L 89 75-139 trans- 1,3-Dichloropropene <0.150 20.0 21.41 ug/L 107 65-152 trans- 1,4-Dichloro-2-butene <0.700 20.0 20.21 ug/L 101 10-142 Trichloroethene <0.150 20.0 19.11 ug/L 96 74 -120 Trichlorofluoromethane <0.240 .+ F1 20.0 43.62 F1 ug/L 218 68 -183 Vinyl acetate <0.950 20.0 23.62 ug/L 118 10 -198 Vinyl chloride <0.320 '+ F1 20.0 33.12 F1 ug/L 166 49 -150 Xylenes, Total <0.450 60.0 56.29 ug/L 94 77 -121 MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 115 53 - 136 Dibromofluoromethane (Surr) 106 67- 129 Toluene-d8 (Surr) 103 59 - 134 Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2053 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane <0.170 20.0 20.51 ug/L 103 71-120 4 16 1,1,1-Trichloroethane <0.120 20.0 20.67 ug/L 103 72-143 3 18 1,1,2,2-Tetrachloroethane <0.280 20.0 19.72 ug/L 99 59-133 4 16 1,1,2-Trichloroethane <0.140 20.0 19.89 ug/L 99 67-120 3 18 1,1-Dichloroethane <0.130 20.0 19.33 ug/L 97 79-141 4 19 1,1-Dichloroethene <0.210 20.0 21.87 ug/L 109 75-133 5 20 1,1-Dichloropropene <0.150 20.0 21.11 ug/L 106 70-129 8 17 1,2,3-Trichloropropane <0.490 20.0 18.59 ug/L 93 1 -210 0 17 1,2,4-Trichlorobenzene <0.140 20.0 18.45 ug/L 92 59 -122 4 17 1,2-Dibromo-3-Chloropropane <0.480 20.0 20.21 ug/L 101 37-157 4 18 1,2-Dibromoethane <0.660 20.0 19.96 ug/L 100 66-123 5 15 1,2-Dichlorobenzene <0.190 20.0 20.18 ug/L 101 76 -120 6 16 1,2-Dichloroethane <0.210 20.0 21.63 ug/L 108 72 -151 5 16 1,2-Dichloropropane <0.100 20.0 20.12 ug/L 101 78 -125 6 19 1,3-Dichlorobenzene <0.150 20.0 20.62 ug/L 103 76 -120 5 17 1,3-Dichloropropane <0.160 20.0 18.88 ug/L 94 60 -129 6 16 1,4-Dichlorobenzene <0.190 20.0 19.34 ug/L 97 76 -122 5 16 2,2-Dichloropropane <0.280 20.0 17.14 ug/L 86 21 -167 6 20 2-Butanone (MEK) <10.0 40.0 38.74 ug/L 97 36 -135 4 19 2-Hexanone <0.880 40.0 44.02 ug/L 110 36 -191 0 17 3-Chloropropene <0.110 20.0 20.43 ug/L 102 17 -147 3 19 4-Methyl-2-pentanone (MIBK) <1.10 40.0 46.20 ug/L 116 56-166 2 19 0 Eurofins Raleigh Page 92 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2053 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Acetone <10.0 40.0 43.42 ug/L 109 10 -158 3 78 Acetonitrile <5.00 20.0 27.97 ug/L 140 10 - 200 18 35 Acrolein <4.00 40.0 9.138 J ug/L 23 10 - 200 3 50 Acrylonitrile <3.50 60.0 56.03 ug/L 93 10 - 200 3 36 Benzene <0.150 20.0 20.31 ug/L 102 80 -134 7 17 Bromochloromethane <0.480 20.0 18.36 ug/L 92 74 -128 2 18 Bromodichloromethane <0.170 20.0 19.88 ug/L 99 72 -129 1 16 Bromoform <0.220 20.0 19.40 ug/L 97 73 -120 4 44 Bromomethane <0.140 20.0 24.40 ug/L 122 38 -189 5 27 Carbon disulfide <1.50 20.0 22.25 ug/L 111 65 -173 4 38 Carbon tetrachloride <0.170 20.0 23.52 ug/L 118 68 -142 7 17 Chlorobenzene <0.170 20.0 20.01 ug/L 100 80 -120 5 16 Chloroethane <0.230 20.0 34.41 ug/L 172 45 - 213 3 26 Chloroform <0.180 20.0 18.34 ug/L 92 78 -138 0 17 Chloromethane <0.130 20.0 22.52 ug/L 113 56 -171 1 28 Chloroprene <0.640 20.0 22.60 ug/L 113 33 -148 4 19 cis-1,2-Dichloroethene <0.150 20.0 18.43 ug/L 92 69 -120 2 18 cis-1,3-Dichloropropene <0.200 20.0 19.10 ug/L 96 63 -125 2 17 Dibromochloromethane <0.170 20.0 19.93 ug/L 100 73 -120 5 16 Dibromomethane <0.270 20.0 20.53 ug/L 103 76 -124 6 15 Dichlorodifluoromethane <0.200 "+ F1 20.0 53.49 F1 ug/L 267 25 -161 6 48 Ethyl methacrylate <0.380 20.0 21.30 ug/L 107 51 -120 0 24 Ethylbenzene <0.130 20.0 19.50 ug/L 97 68 -124 7 16 Hexachlorobutadiene <0.220 20.0 23.37 ug/L 117 63 -120 9 19 lodomethane <1.70 20.0 21.47 ug/L 107 34 -140 6 15 Isobutyl alcohol <11.0 20.0 18.50 J ug/L 93 10 - 200 19 20 Methacrylonitrile <4.90 20.0 21.02 ug/L 105 10 - 200 8 50 Methyl methacrylate <0.510 20.0 20.29 ug/L 101 48 -126 0 50 Methylene Chloride <0.230 20.0 18.41 ug/L 92 68 -128 4 17 Naphthalene <0.110 20.0 21.36 ug/L 107 50 -127 7 19 Styrene <0.110 20.0 16.86 ug/L 84 73 -120 3 23 Tetrachloroethene <0.170 20.0 22.45 ug/L 112 40 -181 9 26 Toluene <0.140 20.0 19.56 ug/L 98 71 -120 6 17 trans- 1,2-Dichloroethene <0.210 20.0 18.69 ug/L 93 75-139 5 19 trans- 1,3-Dichloropropene <0.150 20.0 22.58 ug/L 113 65-152 5 16 trans- 1,4-Dichloro-2-butene <0.700 20.0 20.98 ug/L 105 10-142 4 28 Trichloroethene <0.150 20.0 20.62 ug/L 103 74 -120 8 22 Trichlorofluoromethane <0.240 .+ F1 20.0 43.51 F1 ug/L 218 68 -183 0 22 Vinyl acetate <0.950 20.0 23.29 ug/L 116 10 -198 1 21 Vinyl chloride <0.320 .+ F1 20.0 34.45 F1 ug/L 172 49 -150 4 27 Xylenes, Total <0.450 60.0 59.52 ug/L 99 77 -121 6 16 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 114 53 - 136 Dibromofluoromethane (Surr) 108 67 - 129 Toluene-d8 (Surr) 103 59 - 134 Eurofins Raleigh Page 93 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-2066/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/03/23 17:36 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/03/23 17:36 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/03/23 17:36 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/03/23 17:36 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/03/23 17:36 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/03/23 17:36 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/03/23 17:36 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/03/23 17:36 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/03/23 17:36 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/03/23 17:36 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/03/23 17:36 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/03/23 17:36 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/03/23 17:36 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/03/23 17:36 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/03/23 17:36 1 Acetone <10.0 20.0 10.0 ug/L 04/03/23 17:36 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/03/23 17:36 1 Benzene <0.150 1.00 0.150 ug/L 04/03/23 17:36 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/03/23 17:36 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 Bromoform <0.220 1.00 0.220 ug/L 04/03/23 17:36 1 Bromomethane <0.140 1.00 0.140 ug/L 04/03/23 17:36 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/03/23 17:36 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 Chloroethane <0.230 1.00 0.230 ug/L 04/03/23 17:36 1 Chloroform <0.180 1.00 0.180 ug/L 04/03/23 17:36 1 Chloromethane <0.130 1.00 0.130 ug/L 04/03/23 17:36 1 cis-1,2-Dichloroethene 0.1782 J 1.00 0.150 ug/L 04/03/23 17:36 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/03/23 17:36 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/03/23 17:36 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/03/23 17:36 1 lodomethane <1.70 5.00 1.70 ug/L 04/03/23 17:36 1 Methylene Chloride <0.230 1.00 0.230 ug/L 04/03/23 17:36 1 Styrene <0.110 1.00 0.110 ug/L 04/03/23 17:36 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/03/23 17:36 1 Toluene <0.140 1.00 0.140 ug/L 04/03/23 17:36 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/03/23 17:36 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/03/23 17:36 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/03/23 17:36 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/03/23 17:36 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/03/23 17:36 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/03/23 17:36 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/03/23 17:36 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/03/23 17:36 1 0 Eurofins Raleigh Page 94 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-2066/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 MB MB L Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 110 53 - 136 04103123 17:36 1 Dibromofluoromethane (Surr) 107 67- 129 04103123 17:36 1 Toluene-d8 (Surr) 105 59 - 134 04103123 17:36 1 Lab Sample ID: LCS 752-2066/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 20.0 16.20 ug/L 81 71-120 1,1,1-Trichloroethane 20.0 15.54 ug/L 78 72-143 1,1,2,2-Tetrachloroethane 20.0 15.34 ug/L 77 59-133 1,1,2-Trichloroethane 20.0 16.20 ug/L 81 67-120 1,1-Dichloroethane 20.0 14.42 *- ug/L 72 79-141 1,1-Dichloroethene 20.0 15.45 ug/L 77 75-133 1,2,3-Trichloropropane 20.0 15.25 ug/L 76 69-127 1,2-Dibromo-3-Chloropropane 20.0 16.00 ug/L 80 37-157 1,2-Dibromoethane 20.0 15.92 ug/L 80 66-123 1,2-Dichlorobenzene 20.0 15.72 ug/L 79 76 -120 1,2-Dichloroethane 20.0 15.81 ug/L 79 72 -151 1,2-Dichloropropane 20.0 15.08 "- ug/L 75 78 -125 1,4-Dichlorobenzene 20.0 15.11 ug/L 76 76 -122 2-Butanone (MEK) 40.0 31.73 ug/L 79 36 -135 2-Hexanone 40.0 37.18 ug/L 93 36 -191 4-Methyl-2-pentanone (MIBK) 40.0 38.04 ug/L 95 56-166 Acetone 40.0 32.16 ug/L 80 10 -158 Acrylonitrile 60.0 47.42 ug/L 79 10 - 200 Benzene 20.0 15.46 ug/L 77 80 -134 Bromochloromethane 20.0 14.57 *- ug/L 73 74 -128 Bromodichloromethane 20.0 15.35 ug/L 77 72 -129 Bromoform 20.0 15.93 ug/L 80 73 -120 Bromomethane 20.0 17.44 ug/L 87 38 -189 Carbon disulfide 20.0 16.00 ug/L 80 65 -173 Carbon tetrachloride 20.0 17.60 ug/L 88 68 -142 Chlorobenzene 20.0 15.69 "- ug/L 78 80 -120 Chloroethane 20.0 25.47 ug/L 127 45 - 213 Chloroform 20.0 14.26 "- ug/L 71 78 -138 Chloromethane 20.0 16.82 ug/L 84 56 -171 cis-1,2-Dichloroethene 20.0 13.77 ug/L 69 69 -120 cis-1,3-Dichloropropene 20.0 16.09 ug/L 80 63 -125 Dibromochloromethane 20.0 15.73 ug/L 79 73 -120 Dibromomethane 20.0 15.14 ug/L 76 76 -124 Ethylbenzene 20.0 15.35 ug/L 77 68 -124 Iodomethane 20.0 16.79 ug/L 84 34 -140 Methylene Chloride 20.0 14.04 ug/L 70 68 -128 Styrene 20.0 13.78 '- ug/L 69 73 -120 Tetrachloroethene 20.0 17.85 ug/L 89 40 -181 Toluene 20.0 15.42 ug/L 77 71 -120 Eurofins Raleigh Page 95 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 752-2066/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits trans- 1,2-Dichloroethene 20.0 13.79 * ug/L 69 75-139 trans- 1,3-Dichloropropene 20.0 18.13 ug/L 91 65-152 trans- 1,4-Dichloro-2-butene 20.0 18.51 ug/L 93 10-142 Trichloroethene 20.0 15.08 ug/L 75 74 -120 Trichlorofluoromethane 20.0 31.10 ug/L 156 68 -183 Vinyl acetate 20.0 18.49 ug/L 92 10 -198 Vinyl chloride 20.0 23.90 ug/L 120 49 -150 Xylenes, Total 60.0 47.08 ug/L 78 77 -121 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 94 53 - 136 Dibromofluoromethane (Surr) 88 67 - 129 Toluene-d8 (Surr) 86 59 - 134 Lab Sample ID: LCSD 752-2066/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 20.0 20.21 *1 ug/L 101 71-120 22 16 1,1,1-Trichloroethane 20.0 19.38 *1 ug/L 97 72-143 22 18 1,1,2,2-Tetrachloroethane 20.0 20.03 *1 ug/L 100 59-133 27 16 1,1,2-Trichloroethane 20.0 19.70 *1 ug/L 99 67-120 20 18 1,1-Dichloroethane 20.0 18.65 *1 ug/L 93 79-141 26 19 1,1-Dichloroethene 20.0 19.43 *1 ug/L 97 75-133 23 20 1,2,3-Trichloropropane 20.0 19.53 *1 ug/L 98 69-127 25 17 1,2-Dibromo-3-Chloropropane 20.0 19.26 *1 ug/L 96 37-157 19 18 1,2-Dibromoethane 20.0 19.53 *1 ug/L 98 66-123 20 15 1,2-Dichlorobenzene 20.0 19.50 *1 ug/L 97 76-120 21 16 1,2-Dichloroethane 20.0 19.89 *1 ug/L 99 72 -151 23 16 1,2-Dichloropropane 20.0 19.15 *1 ug/L 96 78-125 24 19 1,4-Dichlorobenzene 20.0 19.19 *1 ug/L 96 76-122 24 16 2-Butanone(MEK) 40.0 43.01 *1 ug/L 108 36-135 30 19 2-Hexanone 40.0 48.69 *1 ug/L 122 36 -191 27 17 4-Methyl-2-pentanone (MIBK) 40.0 48.80 *1 ug/L 122 56-166 25 19 Acetone 40.0 36.68 ug/L 92 10 -158 13 78 Acrylonitrile 60.0 60.92 ug/L 102 10 - 200 25 36 Benzene 20.0 19.08 *1 ug/L 95 80 -134 21 17 Bromochloromethane 20.0 18.53 *1 ug/L 93 74 -128 24 18 Bromodichloromethane 20.0 19.30 *1 ug/L 97 72 -129 23 16 Bromoform 20.0 20.15 ug/L 101 73 -120 23 44 Bromomethane 20.0 22.65 ug/L 113 38 -189 26 27 Carbon disulfide 20.0 19.99 ug/L 100 65 -173 22 38 Carbon tetrachloride 20.0 21.96 *1 ug/L 110 68 -142 22 17 Chlorobenzene 20.0 19.42 *1 ug/L 97 80 -120 21 16 Chloroethane 20.0 32.67 ug/L 163 45 - 213 25 26 Chloroform 20.0 17.94 *1 ug/L 90 78 -138 23 17 Chloromethane 20.0 22.09 ug/L 110 56 -171 27 28 Eurofins Raleigh Page 96 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2066/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit cis-1,2-Dichloroethene 20.0 18.21 *1 ug/L 91 69-120 28 18 cis-1,3-Dichloropropene 20.0 20.41 `1 ug/L 102 63 -125 24 17 Dibromochloromethane 20.0 20.11 `1 ug/L 101 73 -120 24 16 Dibromomethane 20.0 18.88 `1 ug/L 94 76 -124 22 15 Ethylbenzene 20.0 19.03 "1 ug/L 95 68 -124 21 16 lodomethane 20.0 19.63 "1 ug/L 98 34 -140 16 15 Methylene Chloride 20.0 18.62 "1 ug/L 93 68 -128 28 17 Styrene 20.0 17.20 ug/L 86 73 -120 22 23 Tetrachloroethene 20.0 22.11 ug/L 111 40 -181 21 26 Toluene 20.0 18.82 "1 ug/L 94 71 -120 20 17 trans- 1,2-Dichloroethene 20.0 17.99 '1 ug/L 90 75-139 26 19 trans- 1,3-Dichloropropene 20.0 22.75 '1 ug/L 114 65-152 23 16 trans- 1,4-Dichloro-2-butene 20.0 23.94 ug/L 120 10-142 26 28 Trichloroethene 20.0 19.06 '1 ug/L 95 74 -120 23 22 Trichlorofluoromethane 20.0 41.04 '+ *1 ug/L 205 68 -183 28 22 Vinyl acetate 20.0 24.14 '1 ug/L 121 10 -198 27 21 Vinyl chloride 20.0 31.61 *+ "1 ug/L 158 49 -150 28 27 Xylenes, Total 60.0 59.14 `1 ug/L 99 77 -121 23 16 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 118 53 - 136 Dibromofluoromethane (Surr) 108 67- 129 Toluene-d8 (Surr) 105 59 - 134 Lab Sample ID: MRL 752-2066/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2066 Spike MRL MRL %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 1.00 1.219 ug/L 122 1,1,1-Trichloroethane 1.00 1.000 ug/L 100 1,1,2,2-Tetrachloroethane 1.00 1.105 ug/L ill 1,1,2-Trichloroethane 1.00 1.260 ug/L 126 1,1-Dichloroethane 1.00 1.079 ug/L 108 1,1-Dichloroethene 1.00 1.241 ug/L 124 1,2,3-Trichloropropane 1.00 1.217 ug/L 122 1,2-Dibromo-3-Chloropropane 1.00 1.376 ug/L 138 1,2-Dibromoethane 1.00 1.190 ug/L 119 1,2-Dichlorobenzene 1.00 1.123 ug/L 112 1,2-Dichloroethane 1.00 1.150 ug/L 115 1,2-Dichloropropane 1.00 1.036 ug/L 104 1,4-Dichlorobenzene 1.00 1.283 ug/L 128 2-Butanone (MEK) 2.00 <10.0 ug/L 184 2-Hexanone 2.00 2.595 J ug/L 130 4-Methyl-2-pentanone (MIBK) 2.00 2.321 J ug/L 116 Acetone 2.00 <10.0 ug/L 21 Acrylonitrile 5.00 6.001 J ug/L 120 Benzene 1.00 1.145 ug/L 115 Eurofins Raleigh Page 97 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2066/4 Matrix: Water Analysis Batch: 2066 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike MRL MRL %Rec Analyte Added Result Qualifier Unit D %Rec Limits Bromochloromethane 1.00 1.030 ug/L 103 Bromodichloromethane 1.00 1.011 ug/L 101 Bromoform 1.00 1.584 ug/L 158 Bromomethane 1.00 1.831 ug/L 183 Carbon disulfide 2.00 3.017 J ug/L 151 Carbon tetrachloride 1.00 1.016 ug/L 102 Chlorobenzene 1.00 1.176 ug/L 118 Chloroethane 1.00 1.670 ug/L 167 Chloroform 1.00 1.093 ug/L 109 Chloromethane 1.00 1.590 ug/L 159 cis-1,2-Dichloroethene 1.00 1.341 ug/L 134 cis-1,3-Dichloropropene 1.00 1.035 ug/L 104 Dibromochloromethane 1.00 1.078 ug/L 108 Dibromomethane 1.00 1.139 ug/L 114 Ethylbenzene 1.00 1.112 ug/L ill lodomethane 2.00 3.892 J ug/L 195 Methylene Chloride 1.00 1.455 ug/L 146 Styrene 1.00 1.367 ug/L 137 Tetrachloroethene 1.00 1.205 ug/L 120 Toluene 1.00 1.224 ug/L 122 trans- 1,2-Dichloroethene 1.00 1.326 ug/L 133 trans- 1,3-Dichloropropene 1.00 1.129 ug/L 113 trans- 1,4-Dichloro-2-butene 1.00 1.143 ug/L 114 Trichloroethene 1.00 1.196 ug/L 120 Trichlorofluoromethane 1.00 1.688 ug/L 169 Vinyl acetate 2.00 2.032 J ug/L 102 Vinyl chloride 1.00 1.698 ug/L 170 Xylenes, Total 3.00 3.283 ug/L 109 MRL MRL Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 110 53 -136 Dibromofluoromethane (Surr) 108 67-129 Toluene-d8 (Surr) 104 59 -134 Lab Sample ID: MB 752-2107/8 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/04/2319:39 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/04/2319:39 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/04/2319:39 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/04/2319:39 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/04/2319:39 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/04/2319:39 1 1,1-Dichloropropene <0.150 1.00 0.150 ug/L 04/04/2319:39 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/04/2319:39 1 1,2,4-Trichlorobenzene <0.140 1.00 0.140 ug/L 04/04/2319:39 1 0 Eurofins Raleigh Page 98 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-210718 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/04/23 19:39 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/04/23 19:39 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 19:39 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/04/23 19:39 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/04/23 19:39 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 04/04/23 19:39 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 04/04/23 19:39 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/04/23 19:39 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 04/04/23 19:39 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/04/23 19:39 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/04/23 19:39 1 3-Chloropropene <0.110 1.00 0.110 ug/L 04/04/23 19:39 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/04/23 19:39 1 Acetone <10.0 20.0 10.0 ug/L 04/04/23 19:39 1 Acetonitrile <5.00 10.0 5.00 ug/L 04/04/23 19:39 1 Acrolein <4.00 10.0 4.00 ug/L 04/04/23 19:39 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/04/23 19:39 1 Benzene <0.150 1.00 0.150 ug/L 04/04/23 19:39 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/04/23 19:39 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/04/23 19:39 1 Bromoform <0.220 1.00 0.220 ug/L 04/04/23 19:39 1 Bromomethane <0.140 1.00 0.140 ug/L 04/04/23 19:39 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/04/23 19:39 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/04/23 19:39 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/04/23 19:39 1 Chloroethane <0.230 1.00 0.230 ug/L 04/04/23 19:39 1 Chloroform <0.180 1.00 0.180 ug/L 04/04/23 19:39 1 Chloromethane <0.130 1.00 0.130 ug/L 04/04/23 19:39 1 Chloroprene <0.640 1.00 0.640 ug/L 04/04/23 19:39 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/04/23 19:39 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/04/23 19:39 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/04/23 19:39 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/04/23 19:39 1 Dichlorodifluoromethane <0.200 1.00 0.200 ug/L 04/04/23 19:39 1 Ethyl methacrylate <0.380 1.00 0.380 ug/L 04/04/23 19:39 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/04/23 19:39 1 Hexachlorobutadiene <0.220 1.00 0.220 ug/L 04/04/23 19:39 1 lodomethane <1.70 5.00 1.70 ug/L 04/04/23 19:39 1 Isobutyl alcohol <11.0 50.0 11.0 ug/L 04/04/23 19:39 1 Methacrylonitrile <4.90 10.0 4.90 ug/L 04/04/23 19:39 1 Methyl methacrylate <0.510 1.00 0.510 ug/L 04/04/23 19:39 1 Methylene Chloride <0.230 1.00 0.230 ug/L 04/04/23 19:39 1 Naphthalene <0.110 1.00 0.110 ug/L 04/04/23 19:39 1 Propionitrile <5.00 10.0 5.00 ug/L 04/04/23 19:39 1 Styrene <0.110 1.00 0.110 ug/L 04/04/23 19:39 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/04/23 19:39 1 Tetrahydrofuran <0.530 1.00 0.530 ug/L 04/04/23 19:39 1 Toluene <0.140 1.00 0.140 ug/L 04/04/23 19:39 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/04/23 19:39 1 Eurofins Raleigh Page 99 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-210718 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/04/23 19:39 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/04/23 19:39 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/04/23 19:39 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/04/23 19:39 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/04/23 19:39 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/04/23 19:39 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/04/23 19:39 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 114 53 - 136 04104123 19:39 1 Dibromofluoromethane (Surr) 110 67- 129 04104123 19:39 1 Toluene-d8 (Surr) 106 59 - 134 04104123 19:39 1 Lab Sample ID: LCS 752-2107/5 Matrix: Water Analysis Batch: 2107 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 20.0 19.21 ug/L 96 71-120 1,1,1-Trichloroethane 20.0 18.98 ug/L 95 72-143 1,1,2,2-Tetrachloroethane 20.0 19.19 ug/L 96 59-133 1,1,2-Trichloroethane 20.0 19.42 ug/L 97 67-120 1,1-Dichloroethane 20.0 18.87 ug/L 94 79-141 1,1-Dichloroethene 20.0 19.52 ug/L 98 75-133 1,1-Dichloropropene 20.0 19.40 ug/L 97 70-129 1,2,3-Trichloropropane 20.0 17.87 ug/L 89 69-127 1,2,4-Trichlorobenzene 20.0 18.00 ug/L 90 59 -122 1,2-Dibromo-3-Chloropropane 20.0 18.97 ug/L 95 37-157 1,2-Dibromoethane 20.0 18.44 ug/L 92 66-123 1,2-Dichlorobenzene 20.0 19.44 ug/L 97 76 -120 1,2-Dichloroethane 20.0 19.81 ug/L 99 72 -151 1,2-Dichloropropane 20.0 19.66 ug/L 98 78 -125 1,3-Dichlorobenzene 20.0 19.54 ug/L 98 76 -120 1,3-Dichloropropane 20.0 17.81 ug/L 89 60 -129 1,4-Dichlorobenzene 20.0 19.08 ug/L 95 76 -122 2,2-Dichloropropane 20.0 18.14 ug/L 91 21 -167 2-Butanone (MEK) 40.0 45.71 ug/L 114 36 -135 2-Hexanone 40.0 49.15 ug/L 123 36 -191 3-Chloropropene 20.0 19.83 ug/L 99 17 -147 4-Methyl-2-pentanone (MIBK) 40.0 50.70 ug/L 127 56-166 Acetone 40.0 38.92 ug/L 97 10 -158 Acetonitrile 20.0 25.49 ug/L 127 10 - 200 Acrolein 40.0 9.938 J ug/L 25 10 - 200 Acrylonitrile 60.0 62.87 ug/L 105 10 - 200 Benzene 20.0 19.08 ug/L 95 80 -134 Bromochloromethane 20.0 18.24 ug/L 91 74 -128 Bromodichloromethane 20.0 19.63 ug/L 98 72 -129 Bromoform 20.0 18.47 ug/L 92 73 -120 Eurofins Raleigh Page 100 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCS 752-2107/5 Matrix: Water Analysis Batch: 2107 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits Bromomethane 20.0 19.93 ug/L 100 38 -189 Carbon disulfide 20.0 19.70 ug/L 98 65 -173 Carbon tetrachloride 20.0 21.37 ug/L 107 68 -142 Chlorobenzene 20.0 18.73 ug/L 94 80 -120 Chloroethane 20.0 34.94 ug/L 175 45 - 213 Chloroform 20.0 17.79 ug/L 89 78 -138 Chloromethane 20.0 20.92 ug/L 105 56 -171 Chloroprene 20.0 21.07 ug/L 105 33 -148 cis-1,2-Dichloroethene 20.0 18.26 ug/L 91 69 -120 cis-1,3-Dichloropropene 20.0 19.98 ug/L 100 63 -125 Dibromochloromethane 20.0 18.68 ug/L 93 73 -120 Dibromomethane 20.0 18.78 ug/L 94 76 -124 Dichlorodifluoromethane 20.0 46.65 '+ ug/L 233 25 -161 Ethyl methacrylate 20.0 21.37 ug/L 107 51 -120 Ethylbenzene 20.0 18.28 ug/L 91 68 -124 Hexachlorobutadiene 20.0 22.09 ug/L 110 63 -120 lodomethane 20.0 18.73 ug/L 94 34 -140 Isobutyl alcohol 20.0 18.79 J ug/L 94 10 - 200 Methacrylonitrile 20.0 20.06 ug/L 100 10 - 200 Methyl methacrylate 20.0 21.39 ug/L 107 48 -126 Methylene Chloride 20.0 17.94 ug/L 90 68 -128 Naphthalene 20.0 21.38 ug/L 107 50 -127 Styrene 20.0 16.28 ug/L 81 73 -120 Tetrachloroethene 20.0 20.52 ug/L 103 40 -181 Tetrahydrofuran 20.0 24.86 ug/L 124 0 - 200 Toluene 20.0 18.62 ug/L 93 71 -120 trans- 1,2-Dichloroethene 20.0 17.12 ug/L 86 75-139 trans- 1,3-Dichloropropene 20.0 22.03 ug/L 110 65-152 trans- 1,4-Dichloro-2-butene 20.0 22.49 ug/L 112 10-142 Trichloroethene 20.0 19.07 ug/L 95 74 -120 Trichlorofluoromethane 20.0 40.95 .+ ug/L 205 68 -183 Vinyl acetate 20.0 23.74 ug/L 119 10 -198 Vinyl chloride 20.0 31.60 .+ ug/L 158 49 -150 Xylenes, Total 60.0 56.57 ug/L 94 77 -121 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 115 53 - 136 Dibromofluoromethane (Surr) 112 67 - 129 Toluene-d8 (Surr) 106 59 - 134 Lab Sample ID: LCSD 752-2107/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 20.0 20.56 ug/L 103 71-120 7 16 1,1,1-Trichloroethane 20.0 20.63 ug/L 103 72-143 8 18 1,1,2,2-Tetrachloroethane 20.0 20.13 ug/L 101 59-133 5 16 0 Eurofins Raleigh Page 101 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2107/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,2-Trichloroethane 20.0 21.29 ug/L 106 67-120 9 18 1,1-Dichloroethane 20.0 19.75 ug/L 99 79-141 5 19 1,1-Dichloroethene 20.0 20.75 ug/L 104 75-133 6 20 1,1-Dichloropropene 20.0 21.47 ug/L 107 70-129 10 17 1,2,3-Trichloropropane 20.0 19.11 ug/L 96 69-127 7 17 1,2,4-Trichlorobenzene 20.0 19.14 ug/L 96 59 -122 6 17 1,2-Dibromo-3-Chloropropane 20.0 21.19 ug/L 106 37-157 11 18 1,2-Dibromoethane 20.0 20.30 ug/L 102 66-123 10 15 1,2-Dichlorobenzene 20.0 20.70 ug/L 103 76 -120 6 16 1,2-Dichloroethane 20.0 20.95 ug/L 105 72 -151 6 16 1,2-Dichloropropane 20.0 20.16 ug/L 101 78 -125 2 19 1,3-Dichlorobenzene 20.0 21.18 ug/L 106 76 -120 8 17 1,3-Dichloropropane 20.0 19.29 ug/L 96 60 -129 8 16 1,4-Dichlorobenzene 20.0 19.97 ug/L 100 76 -122 5 16 2,2-Dichloropropane 20.0 19.27 ug/L 96 21 -167 6 20 2-Butanone (MEK) 40.0 44.88 ug/L 112 36 -135 2 19 2-Hexanone 40.0 50.30 ug/L 126 36 -191 2 17 3-Chloropropene 20.0 21.35 ug/L 107 17 -147 7 19 4-Methyl-2-pentanone (MIBK) 40.0 50.46 ug/L 126 56-166 0 19 Acetone 40.0 45.28 ug/L 113 10 -158 15 78 Acetonitrile 20.0 24.36 ug/L 122 10 - 200 5 35 Acrolein 40.0 9.769 J ug/L 24 10 - 200 2 50 Acrylonitrile 60.0 64.31 ug/L 107 10 - 200 2 36 Benzene 20.0 20.06 ug/L 100 80 -134 5 17 Bromochloromethane 20.0 19.88 ug/L 99 74 -128 9 18 Bromodichloromethane 20.0 20.43 ug/L 102 72 -129 4 16 Bromoform 20.0 19.59 ug/L 98 73 -120 6 44 Bromomethane 20.0 22.21 ug/L 111 38 -189 11 27 Carbon disulfide 20.0 20.64 ug/L 103 65 -173 5 38 Carbon tetrachloride 20.0 22.47 ug/L 112 68 -142 5 17 Chlorobenzene 20.0 20.53 ug/L 103 80 -120 9 16 Chloroethane 20.0 37.45 ug/L 187 45 - 213 7 26 Chloroform 20.0 19.15 ug/L 96 78 -138 7 17 Chloromethane 20.0 23.59 ug/L 118 56 -171 12 28 Chloroprene 20.0 22.80 ug/L 114 33 -148 8 19 cis-1,2-Dichloroethene 20.0 18.86 ug/L 94 69 -120 3 18 cis-1,3-Dichloropropene 20.0 20.94 ug/L 105 63 -125 5 17 Dibromochloromethane 20.0 20.18 ug/L 101 73 -120 8 16 Dibromomethane 20.0 20.32 ug/L 102 76 -124 8 15 Dichlorodifluoromethane 20.0 51.00 ,+ ug/L 255 25 -161 9 48 Ethyl methacrylate 20.0 23.01 ug/L 115 51 -120 7 24 Ethylbenzene 20.0 19.85 ug/L 99 68 -124 8 16 Hexachlorobutadiene 20.0 22.41 ug/L 112 63 -120 1 19 lodomethane 20.0 20.17 ug/L 101 34 -140 7 15 Isobutyl alcohol 20.0 17.96 J ug/L 90 10 - 200 5 20 Methacrylonitrile 20.0 23.18 ug/L 116 10 - 200 14 50 Methyl methacrylate 20.0 22.55 ug/L 113 48 -126 5 50 Methylene Chloride 20.0 19.35 ug/L 97 68 -128 8 17 Naphthalene 20.0 21.55 ug/L 108 50 -127 1 19 Eurofins Raleigh Page 102 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2107/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2107 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Styrene 20.0 17.48 ug/L 87 73 -120 7 23 Tetrachloroethene 20.0 22.53 ug/L 113 40 -181 9 26 Tetrahydrofuran 20.0 24.76 ug/L 124 0 - 200 0 50 Toluene 20.0 19.74 ug/L 99 71 -120 6 17 trans- 1,2-Dichloroethene 20.0 18.58 ug/L 93 75-139 8 19 trans- 1,3-Dichloropropene 20.0 24.00 ug/L 120 65-152 9 16 trans- 1,4-Dichloro-2-butene 20.0 23.13 ug/L 116 10-142 3 28 Trichloroethene 20.0 19.78 ug/L 99 74 -120 4 22 Trichlorofluoromethane 20.0 43.78 .+ ug/L 219 68 -183 7 22 Vinyl acetate 20.0 24.80 ug/L 124 10 -198 4 21 Vinyl chloride 20.0 34.28 .+ ug/L 171 49 -150 8 27 Xylenes, Total 60.0 60.36 ug/L 101 77 -121 6 16 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 117 53 -136 Dibromofluoromethane (Surr) 111 67-129 Toluene-d8 (Surr) 107 59 - 134 Lab Sample ID: MRL 752-2107/4 Matrix: Water Analysis Batch: 2107 Analyte Spike Added MRL Result MRL Qualifier Client Sample ID: Lab Control Sample Prep Type: Total/NA %Rec Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 1.00 1.033 ug/L 103 1,1,1-Trichloroethane 1.00 0.9662 J ug/L 97 1,1,2,2-Tetrachloroethane 1.00 1.222 ug/L 122 1,1,2-Trichloroethane 1.00 1.110 ug/L ill 1,1-Dichloroethane 1.00 1.072 ug/L 107 1,1-Dichloroethene 1.00 1.627 ug/L 163 1,1-Dichloropropene 1.00 1.028 ug/L 103 1,2,3-Trichloropropane 1.00 0.9153 J ug/L 92 1,2,4-Trichlorobenzene 1.00 2.103 ug/L 210 1,2-Dibromo-3-Chloropropane 1.00 1.329 ug/L 133 1,2-Dibromoethane 1.00 1.173 ug/L 117 1,2-Dichlorobenzene 1.00 1.199 ug/L 120 1,2-Dichloroethane 1.00 1.188 ug/L 119 1,2-Dichloropropane 1.00 1.002 ug/L 100 1,3-Dichlorobenzene 1.00 1.353 ug/L 135 1,3-Dichloropropane 1.00 1.024 ug/L 102 1,4-Dichlorobenzene 1.00 1.359 ug/L 136 2,2-Dichloropropane 1.00 1.145 ug/L 115 2-Butanone (MEK) 2.00 <10.0 ug/L 279 2-Hexanone 2.00 2.971 J ug/L 149 3-Chloropropene 1.00 1.127 ug/L 113 4-Methyl-2-pentanone (MIBK) 2.00 2.641 J ug/L 132 Acetone 2.00 <10.0 ug/L 90 Acetonitrile 10.0 13.09 ug/L 131 Acrolein 5.00 <4.00 ug/L 76 Eurofins Raleigh Page 103 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2107/4 Matrix: Water Analysis Batch: 2107 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added MRL Result MRL Qualifier Unit %Rec D %Rec Limits Acrylonitrile 5.00 5.746 J ug/L 115 Benzene 1.00 1.201 ug/L 120 Bromochloromethane 1.00 1.082 ug/L 108 Bromodichloromethane 1.00 1.134 ug/L 113 Bromoform 1.00 1.447 ug/L 145 Bromomethane 1.00 0.8091 J ug/L 81 Carbon disulfide 2.00 3.129 J ug/L 156 Carbon tetrachloride 1.00 1.138 ug/L 114 Chlorobenzene 1.00 1.194 ug/L 119 Chloroethane 1.00 1.830 ug/L 183 Chloroform 1.00 1.124 ug/L 112 Chloromethane 1.00 1.563 ug/L 156 Chloroprene 1.00 1.039 ug/L 104 cis-1,2-Dichloroethene 1.00 1.238 ug/L 124 cis-1,3-Dichloropropene 1.00 0.9959 J ug/L 100 Dibromochloromethane 1.00 1.068 ug/L 107 Dibromomethane 1.00 1.318 ug/L 132 Dichlorodifluoromethane 1.00 1.918 ug/L 192 Ethyl methacrylate 1.00 0.8307 J ug/L 83 Ethylbenzene 1.00 1.073 ug/L 107 Hexachlorobutadiene 1.00 1.806 ug/L 181 lodomethane 2.00 3.832 J ug/L 192 Isobutyl alcohol 20.0 21.66 J ug/L 108 Methacrylonitrile 10.0 12.20 ug/L 122 Methyl methacrylate 1.00 0.9145 J ug/L 91 Methylene Chloride 1.00 1.279 ug/L 128 Naphthalene 1.00 2.084 ug/L 208 Styrene 1.00 1.350 ug/L 135 Tetrachloroethene 1.00 1.290 ug/L 129 Tetrahydrofuran 1.00 1.203 ug/L 120 Toluene 1.00 1.210 ug/L 121 trans- 1,2-Dichloroethene 1.00 1.348 ug/L 135 trans- 1,3-Dichloropropene 1.00 1.190 ug/L 119 trans- l,4-Dichloro-2-butene 1.00 1.056 ug/L 106 Trichloroethene 1.00 1.235 ug/L 123 Trichlorofluoromethane 1.00 0.7654 J ug/L 77 Vinyl acetate 2.00 1.957 J ug/L 98 Vinyl chloride 1.00 1.578 ug/L 158 Xylenes, Total 3.00 3.124 ug/L 104 MRL MRL Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 117 53 - 136 Dibromofluoromethane (Surr) 112 67 - 129 Toluene-d8 (Surr) 105 59 - 134 0 Eurofins Raleigh Page 104 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: 752-4682-4 MS Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2107 L MS MS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 114 53 - 136 Dibromofluoromethane (Surr) 111 67 - 129 Toluene-d8 (Surr) 108 59 - 134 Lab Sample ID: 752-4682-4 MSD Client Sample ID: 4501-MW1161 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2107 MSD MSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 118 53 - 136 Dibromofluoromethane (Surr) 111 67- 129 Toluene-d8 (Surr) 109 59 - 134 Lab Sample ID: MB 752-2111/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2111 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/05/23 15:24 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/05/23 15:24 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/23 15:24 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/23 15:24 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 15:24 1 1,1-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/23 15:24 1 1,2,4-Trichlorobenzene 0.1973 J 1.00 0.140 ug/L 04/05/23 15:24 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/23 15:24 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/23 15:24 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 15:24 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/23 15:24 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/23 15:24 1 1,3-Dichlorobenzene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 1,3-Dichloropropane <0.160 1.00 0.160 ug/L 04/05/23 15:24 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 15:24 1 2,2-Dichloropropane <0.280 1.00 0.280 ug/L 04/05/23 15:24 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 15:24 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 15:24 1 3-Chloropropene <0.110 1.00 0.110 ug/L 04/05/23 15:24 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 15:24 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 15:24 1 Acetonitrile <5.00 10.0 5.00 ug/L 04/05/23 15:24 1 Acrolein <4.00 10.0 4.00 ug/L 04/05/23 15:24 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 15:24 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 15:24 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 Bromoform <0.220 1.00 0.220 ug/L 04/05/23 15:24 1 Eurofins Raleigh Page 105 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-2111/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2111 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 15:24 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 15:24 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 15:24 1 Chloroform 1.786 1.00 0.180 ug/L 04/05/23 15:24 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 15:24 1 Chloroprene <0.640 1.00 0.640 ug/L 04/05/23 15:24 1 cis-1,2-Dichloroethene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 15:24 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 15:24 1 Dichlorodifluoromethane <0.200 1.00 0.200 ug/L 04/05/23 15:24 1 Ethyl methacrylate <0.380 1.00 0.380 ug/L 04/05/23 15:24 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 15:24 1 Hexachlorobutadiene 0.4377 J 1.00 0.220 ug/L 04/05/23 15:24 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 15:24 1 Isobutyl alcohol <11.0 50.0 11.0 ug/L 04/05/23 15:24 1 Methacrylonitrile <4.90 10.0 4.90 ug/L 04/05/23 15:24 1 Methyl methacrylate <0.510 1.00 0.510 ug/L 04/05/23 15:24 1 Methylene Chloride 0.2792 J 1.00 0.230 ug/L 04/05/23 15:24 1 Naphthalene <0.110 1.00 0.110 ug/L 04/05/23 15:24 1 Propionitrile <5.00 10.0 5.00 ug/L 04/05/23 15:24 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 15:24 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 15:24 1 Tetrahydrofuran <0.530 1.00 0.530 ug/L 04/05/23 15:24 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 15:24 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 15:24 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 15:24 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 15:24 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 15:24 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 15:24 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 15:24 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 15:24 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 95 53 - 136 04/05/23 15:24 1 Dibromofluoromethane (Surr) 89 67- 129 04/05/23 15:24 1 Toluene-d8 (Surr) 95 59 - 134 04/05/23 15:24 1 Lab Sample ID: LCS 752-2111/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2111 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 20.0 17.25 ug/L 86 71-120 1,1,1-Trichloroethane 20.0 16.70 ug/L 83 72-143 Eurofins Raleigh Page 106 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCS 752-2111/5 Matrix: Water Analysis Batch: 2111 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits 1,1,2,2-Tetrachloroethane 20.0 18.44 ug/L 92 59-133 1,1,2-Trichloroethane 20.0 17.40 ug/L 87 67-120 1,1-Dichloroethane 20.0 17.28 ug/L 86 79-141 1,1-Dichloroethene 20.0 14.93 ug/L 75 75-133 1,1-Dichloropropene 20.0 16.50 ug/L 83 70-129 1,2,3-Trichloropropane 20.0 16.78 ug/L 84 69-127 1,2,4-Trichlorobenzene 20.0 26.39 .+ ug/L 132 59 -122 1,2-Dibromo-3-Chloropropane 20.0 23.44 ug/L 117 37-157 1,2-Dibromoethane 20.0 17.69 ug/L 88 66-123 1,2-Dichlorobenzene 20.0 22.77 ug/L 114 76 -120 1,2-Dichloroethane 20.0 17.91 ug/L 90 72 -151 1,2-Dichloropropane 20.0 18.71 ug/L 94 78 -125 1,3-Dichlorobenzene 20.0 22.80 ug/L 114 76 -120 1,3-Dichloropropane 20.0 16.71 ug/L 84 60 -129 1,4-Dichlorobenzene 20.0 21.61 ug/L 108 76 -122 2,2-Dichloropropane 20.0 16.71 ug/L 84 21 -167 2-Butanone (MEK) 40.0 46.41 ug/L 116 36 -135 2-Hexanone 40.0 40.75 ug/L 102 36 -191 3-Chloropropene 20.0 18.03 ug/L 90 17 -147 4-Methyl-2-pentanone (MIBK) 40.0 41.15 ug/L 103 56-166 Acetone 40.0 47.11 ug/L 118 10 -158 Acetonitrile 20.0 23.85 ug/L 119 10 - 200 Acrolein 40.0 7.486 J ug/L 19 10 - 200 Acrylonitrile 60.0 59.46 ug/L 99 10 - 200 Benzene 20.0 16.81 ug/L 84 80 -134 Bromochloromethane 20.0 18.79 ug/L 94 74 -128 Bromodichloromethane 20.0 17.96 ug/L 90 72 -129 Bromoform 20.0 21.46 ug/L 107 73 -120 Bromomethane 20.0 10.34 ug/L 52 38 -189 Carbon disulfide 20.0 17.03 ug/L 85 65 -173 Carbon tetrachloride 20.0 17.98 ug/L 90 68 -142 Chlorobenzene 20.0 17.70 ug/L 88 80 -120 Chloroethane 20.0 17.56 ug/L 88 45 - 213 Chloroform 20.0 19.23 ug/L 96 78 -138 Chloromethane 20.0 15.09 ug/L 75 56 -171 Chloroprene 20.0 16.22 ug/L 81 33 -148 cis-1,2-Dichloroethene 20.0 16.96 ug/L 85 69 -120 cis-1,3-Dichloropropene 20.0 18.43 ug/L 92 63 -125 Dibromochloromethane 20.0 17.37 ug/L 87 73 -120 Dibromomethane 20.0 18.87 ug/L 94 76 -124 Dichlorodifluoromethane 20.0 18.89 ug/L 94 25 -161 Ethyl methacrylate 20.0 17.33 ug/L 87 51 -120 Ethylbenzene 20.0 17.26 ug/L 86 68 -124 Hexachlorobutadiene 20.0 17.86 ug/L 89 63 -120 lodomethane 20.0 14.41 ug/L 72 34 -140 Isobutyl alcohol 20.0 33.09 J ug/L 165 10 - 200 Methacrylonitrile 20.0 20.57 ug/L 103 10 - 200 Methyl methacrylate 20.0 23.96 ug/L 120 48 -126 Methylene Chloride 20.0 17.99 ug/L 90 68 -128 0 Eurofins Raleigh Page 107 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCS 752-2111/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2111 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Naphthalene 20.0 30.92 .+ ug/L 155 50 -127 Styrene 20.0 20.78 ug/L 104 73 -120 Tetrachloroethene 20.0 16.89 ug/L 84 40 -181 Tetrahydrofuran 20.0 22.80 ug/L 114 0 - 200 Toluene 20.0 16.83 ug/L 84 71 -120 trans- 1,2-Dichloroethene 20.0 16.59 ug/L 83 75-139 trans- 1,3-Dichloropropene 20.0 19.11 ug/L 96 65-152 trans- 1,4-Dichloro-2-butene 20.0 16.27 ug/L 81 10-142 Trichloroethene 20.0 18.54 ug/L 93 74 -120 Trichlorofluoromethane 20.0 18.19 ug/L 91 68 -183 Vinyl acetate 20.0 19.35 ug/L 97 10 -198 Vinyl chloride 20.0 17.88 ug/L 89 49 -150 Xylenes, Total 60.0 53.14 ug/L 89 77 -121 LCS LCS Surrogate %Recovery Qualifier 4-Bromofluorobenzene (Surr) 91 Dibromofluoromethane (Surr) 87 Toluene-d8 (Surr) 94 Lab Sample ID: LCSD 752-2111/6 Matrix: Water Analysis Batch: 2111 Analyte Limits 53 - 136 67- 129 59 - 134 Spike Added LCSD Result Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD %Rec RPD Qualifier Unit D %Rec Limits RPD Limit 1,1,1,2-Tetrachloroethane 20.0 17.69 ug/L 88 71-120 3 16 1,1,1-Trichloroethane 20.0 16.91 ug/L 85 72-143 1 18 1,1,2,2-Tetrachloroethane 20.0 18.53 ug/L 93 59-133 0 16 1,1,2-Trichloroethane 20.0 18.63 ug/L 93 67-120 7 18 1,1-Dichloroethane 20.0 17.67 ug/L 88 79-141 2 19 1,1-Dichloroethene 20.0 14.61 *- ug/L 73 75-133 2 20 1,1-Dichloropropene 20.0 16.89 ug/L 84 70-129 2 17 1,2,3-Trichloropropane 20.0 18.92 ug/L 95 69-127 12 17 1,2,4-Trichlorobenzene 20.0 23.55 ug/L 118 59 -122 11 17 1,2-Dibromo-3-Chloropropane 20.0 23.44 ug/L 117 37-157 0 18 1,2-Dibromoethane 20.0 18.19 ug/L 91 66-123 3 15 1,2-Dichlorobenzene 20.0 21.23 ug/L 106 76 -120 7 16 1,2-Dichloroethane 20.0 18.27 ug/L 91 72 -151 2 16 1,2-Dichloropropane 20.0 17.92 ug/L 90 78 -125 4 19 1,3-Dichlorobenzene 20.0 20.77 ug/L 104 76 -120 9 17 1,3-Dichloropropane 20.0 16.44 ug/L 82 60 -129 2 16 1,4-Dichlorobenzene 20.0 20.16 ug/L 101 76 -122 7 16 2,2-Dichloropropane 20.0 16.86 ug/L 84 21 -167 1 20 2-Butanone (MEK) 40.0 43.72 ug/L 109 36 -135 6 19 2-Hexanone 40.0 42.77 ug/L 107 36 -191 5 17 3-Chloropropene 20.0 17.71 ug/L 89 17 -147 2 19 4-Methyl-2-pentanone (MIBK) 40.0 44.25 ug/L 111 56-166 7 19 Acetone 40.0 41.88 ug/L 105 10 -158 12 78 Acetonitrile 20.0 23.22 ug/L 116 10 - 200 3 35 Eurofins Raleigh Page 108 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2111/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2111 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Acrolein 40.0 12.23 ug/L 31 10 - 200 48 50 Acrylonitrile 60.0 60.07 ug/L 100 10 - 200 1 36 Benzene 20.0 16.47 ug/L 82 80 -134 2 17 Bromochloromethane 20.0 19.56 ug/L 98 74 -128 4 18 Bromodichloromethane 20.0 17.75 ug/L 89 72 -129 1 16 Bromoform 20.0 19.90 ug/L 99 73 -120 8 44 Bromomethane 20.0 10.78 ug/L 54 38 -189 4 27 Carbon disulfide 20.0 16.50 ug/L 83 65 -173 3 38 Carbon tetrachloride 20.0 17.86 ug/L 89 68 -142 1 17 Chlorobenzene 20.0 17.85 ug/L 89 80 -120 1 16 Chloroethane 20.0 17.24 ug/L 86 45 - 213 2 26 Chloroform 20.0 19.38 ug/L 97 78 -138 1 17 Chloromethane 20.0 14.67 ug/L 73 56 -171 3 28 Chloroprene 20.0 17.94 ug/L 90 33 -148 10 19 cis-1,2-Dichloroethene 20.0 17.49 ug/L 87 69 -120 3 18 cis-1,3-Dichloropropene 20.0 17.89 ug/L 89 63 -125 3 17 Dibromochloromethane 20.0 17.71 ug/L 89 73 -120 2 16 Dibromomethane 20.0 18.20 ug/L 91 76 -124 4 15 Dichlorodifluoromethane 20.0 17.32 ug/L 87 25 -161 9 48 Ethyl methacrylate 20.0 18.14 ug/L 91 51 -120 5 24 Ethylbenzene 20.0 17.22 ug/L 86 68 -124 0 16 Hexachlorobutadiene 20.0 18.17 ug/L 91 63 -120 2 19 lodomethane 20.0 14.70 ug/L 73 34 -140 2 15 Isobutyl alcohol 20.0 27.94 J ug/L 140 10 - 200 17 20 Methacrylonitrile 20.0 21.19 ug/L 106 10 - 200 3 50 Methyl methacrylate 20.0 22.34 ug/L 112 48 -126 7 50 Methylene Chloride 20.0 17.28 ug/L 86 68 -128 4 17 Naphthalene 20.0 27.90 >+ ug/L 139 50 -127 10 19 Styrene 20.0 19.31 ug/L 97 73 -120 7 23 Tetrachloroethene 20.0 17.90 ug/L 90 40 -181 6 26 Tetrahydrofuran 20.0 23.29 ug/L 116 0 - 200 2 50 Toluene 20.0 16.75 ug/L 84 71 -120 0 17 trans- l,2-Dichloroethene 20.0 16.37 ug/L 82 75-139 1 19 trans- 1,3-Dichloropropene 20.0 19.97 ug/L 100 65-152 4 16 trans- 1,4-Dichloro-2-butene 20.0 16.43 ug/L 82 10-142 1 28 Trichloroethene 20.0 17.79 ug/L 89 74 -120 4 22 Trichlorofluoromethane 20.0 17.76 ug/L 89 68 -183 2 22 Vinyl acetate 20.0 20.63 ug/L 103 10 -198 6 21 Vinyl chloride 20.0 18.12 ug/L 91 49 -150 1 27 Xylenes, Total 60.0 53.74 ug/L 90 77 -121 1 16 LCSD LCSD Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 89 53 -136 Dibromofluoromethane (Surr) 89 67-129 Toluene-d8 (Surr) 92 59 -134 Eurofins Raleigh Page 109 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2111/7 Matrix: Water Analysis Batch: 2111 Analyte 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Butanone (MEK) 2-Hexanone 3-Chloropropene 4-Methyl-2-pentanone (MIBK) Acetone Acetonitrile Acrolein Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethyl methacrylate Ethylbenzene Hexachlorobutadiene lodomethane Isobutyl alcohol Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added MRL Result MRL Qualifier Unit %Rec D %Rec Limits 1.00 1.067 ug/L 107 1.00 0.9590 J ug/L 96 1.00 1.216 ug/L 122 1.00 1.078 ug/L 108 1.00 0.9977 J ug/L 100 1.00 0.8420 J ug/L 84 1.00 0.9321 J ug/L 93 1.00 0.9946 J ug/L 99 1.00 3.075 ug/L 307 1.00 1.287 ug/L 129 1.00 1.146 ug/L 115 1.00 2.635 ug/L 263 1.00 1.030 ug/L 103 1.00 0.9370 J ug/L 94 1.00 2.510 ug/L 251 1.00 0.9757 J ug/L 98 1.00 2.492 ug/L 249 1.00 0.9312 J ug/L 93 2.00 <10.0 ug/L 123 2.00 2.691 J ug/L 135 1.00 0.6573 J ug/L 66 2.00 2.262 J ug/L 113 2.00 <10.0 ug/L 106 10.0 12.30 ug/L 123 5.00 5.207 J ug/L 104 5.00 5.295 J ug/L 106 1.00 0.9117 J ug/L 91 1.00 0.7127 J ug/L 71 1.00 1.130 ug/L 113 1.00 1.124 ug/L 112 1.00 0.7538 J ug/L 75 2.00 2.168 J ug/L 108 1.00 0.8812 J ug/L 88 1.00 1.417 ug/L 142 1.00 1.060 ug/L 106 1.00 2.381 ug/L 238 1.00 0.5719 J ug/L 57 1.00 0.7124 J ug/L 71 1.00 0.9950 J ug/L 100 1.00 0.8832 J ug/L 88 1.00 1.101 ug/L 110 1.00 0.8935 J ug/L 89 1.00 0.7157 J ug/L 72 1.00 0.7578 J ug/L 76 1.00 1.103 ug/L 110 1.00 2.173 ug/L 217 2.00 3.542 J ug/L 177 20.0 39.31 J ug/L 197 0 Page 110 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2111/7 Matrix: Water Analysis Batch: 2111 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike MRL MRL %Rec Analyte Added Result Qualifier Unit D %Rec Limits Methacrylonitrile 10.0 10.44 ug/L 104 Methyl methacrylate 1.00 0.7004 J ug/L 70 Methylene Chloride 1.00 1.184 ug/L 118 Naphthalene 1.00 4.851 ug/L 485 Styrene 1.00 2.817 ug/L 282 Tetrachloroethene 1.00 1.019 ug/L 102 Tetrahydrofuran 1.00 <0.530 ug/L 0 Toluene 1.00 1.283 ug/L 128 trans- 1,2-Dichloroethene 1.00 0.9916 J ug/L 99 trans- 1,3-Dichloropropene 1.00 0.9906 J ug/L 99 trans- 1,4-Dichloro-2-butene 1.00 1.667 ug/L 167 Trichloroethene 1.00 1.090 ug/L 109 Trichlorofluoromethane 1.00 0.7324 J ug/L 73 Vinyl acetate 2.00 1.634 J ug/L 82 Vinyl chloride 1.00 0.7722 J ug/L 77 Xylenes, Total 3.00 4.398 ug/L 147 MRL MRL Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 97 53 - 136 Dibromofluoromethane (Surr) 84 67- 129 Toluene-d8 (Surr) 92 59 - 134 Lab Sample ID: MB 752-2118/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2118 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,1,1,2-Tetrachloroethane <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 1,1,1-Trichloroethane <0.120 1.00 0.120 ug/L 04/05/23 16:45 1 1,1,2,2-Tetrachloroethane <0.280 1.00 0.280 ug/L 04/05/23 16:45 1 1,1,2-Trichloroethane <0.140 1.00 0.140 ug/L 04/05/23 16:45 1 1,1-Dichloroethane <0.130 1.00 0.130 ug/L 04/05/23 16:45 1 1,1-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 16:45 1 1,2,3-Trichloropropane <0.490 1.00 0.490 ug/L 04/05/23 16:45 1 1,2-Dibromo-3-Chloropropane <0.480 1.00 0.480 ug/L 04/05/23 16:45 1 1,2-Dibromoethane <0.660 1.00 0.660 ug/L 04/05/23 16:45 1 1,2-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 16:45 1 1,2-Dichloroethane <0.210 1.00 0.210 ug/L 04/05/23 16:45 1 1,2-Dichloropropane <0.100 1.00 0.100 ug/L 04/05/23 16:45 1 1,4-Dichlorobenzene <0.190 1.00 0.190 ug/L 04/05/23 16:45 1 2-Butanone (MEK) <10.0 20.0 10.0 ug/L 04/05/23 16:45 1 2-Hexanone <0.880 5.00 0.880 ug/L 04/05/23 16:45 1 4-Methyl-2-pentanone (MIBK) <1.10 5.00 1.10 ug/L 04/05/23 16:45 1 Acetone <10.0 20.0 10.0 ug/L 04/05/23 16:45 1 Acrylonitrile <3.50 10.0 3.50 ug/L 04/05/23 16:45 1 Benzene <0.150 1.00 0.150 ug/L 04/05/23 16:45 1 Bromochloromethane <0.480 1.00 0.480 ug/L 04/05/23 16:45 1 Bromodichloromethane <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 0 Eurofins Raleigh Page 111 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: MB 752-2118/9 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2118 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Bromoform <0.220 1.00 0.220 ug/L 04/05/23 16:45 1 Bromomethane <0.140 1.00 0.140 ug/L 04/05/23 16:45 1 Carbon disulfide <1.50 5.00 1.50 ug/L 04/05/23 16:45 1 Carbon tetrachloride <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 Chlorobenzene <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 Chloroethane <0.230 1.00 0.230 ug/L 04/05/23 16:45 1 Chloroform 1.526 1.00 0.180 ug/L 04/05/23 16:45 1 Chloromethane <0.130 1.00 0.130 ug/L 04/05/23 16:45 1 cis-1,2-Dichloroethene 0.1500 J 1.00 0.150 ug/L 04/05/23 16:45 1 cis-1,3-Dichloropropene <0.200 1.00 0.200 ug/L 04/05/23 16:45 1 Dibromochloromethane <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 Dibromomethane <0.270 1.00 0.270 ug/L 04/05/23 16:45 1 Ethylbenzene <0.130 1.00 0.130 ug/L 04/05/23 16:45 1 lodomethane <1.70 5.00 1.70 ug/L 04/05/23 16:45 1 Methylene Chloride <0.230 1.00 0.230 ug/L 04/05/23 16:45 1 Styrene <0.110 1.00 0.110 ug/L 04/05/23 16:45 1 Tetrachloroethene <0.170 1.00 0.170 ug/L 04/05/23 16:45 1 Toluene <0.140 1.00 0.140 ug/L 04/05/23 16:45 1 trans- 1,2-Dichloroethene <0.210 1.00 0.210 ug/L 04/05/23 16:45 1 trans- 1,3-Dichloropropene <0.150 1.00 0.150 ug/L 04/05/23 16:45 1 trans- 1,4-Dichloro-2-butene <0.700 1.00 0.700 ug/L 04/05/23 16:45 1 Trichloroethene <0.150 1.00 0.150 ug/L 04/05/23 16:45 1 Trichlorofluoromethane <0.240 1.00 0.240 ug/L 04/05/23 16:45 1 Vinyl acetate <0.950 5.00 0.950 ug/L 04/05/23 16:45 1 Vinyl chloride <0.320 1.00 0.320 ug/L 04/05/23 16:45 1 Xylenes, Total <0.450 3.00 0.450 ug/L 04/05/23 16:45 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 115 53 - 136 04105123 16:45 1 Dibromofluoromethane (Surr) 111 67- 129 04105123 16:45 1 Toluene-d8 (Surr) 105 59 - 134 04105123 16:45 1 Lab Sample ID: LCS 752-2118/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2118 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 20.0 19.10 ug/L 96 71-120 1,1,1-Trichloroethane 20.0 19.92 ug/L 100 72-143 1,1,2,2-Tetrachloroethane 20.0 19.98 ug/L 100 59-133 1,1,2-Trichloroethane 20.0 19.91 ug/L 100 67-120 1,1-Dichloroethane 20.0 19.58 ug/L 98 79-141 1,1-Dichloroethene 20.0 19.43 ug/L 97 75-133 1,2,3-Trichloropropane 20.0 19.16 ug/L 96 69-127 1,2-Dibromo-3-Chloropropane 20.0 20.81 ug/L 104 37-157 1,2-Dibromoethane 20.0 19.80 ug/L 99 66-123 1,2-Dichlorobenzene 20.0 19.13 ug/L 96 76 -120 1,2-Dichloroethane 20.0 21.04 ug/L 105 72 -151 Eurofins Raleigh Page 112 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: LCS 752-211815 Matrix: Water Analysis Batch: 2118 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits 1,2-Dichloropropane 20.0 20.51 ug/L 103 78 -125 1,4-Dichlorobenzene 20.0 18.81 ug/L 94 76 -122 2-Butanone (MEK) 40.0 41.69 ug/L 104 36 -135 2-Hexanone 40.0 52.21 ug/L 131 36 -191 4-Methyl-2-pentanone (MIBK) 40.0 54.99 ug/L 137 56-166 Acetone 40.0 43.44 ug/L 109 10 -158 Acrylonitrile 60.0 66.19 ug/L 110 10 - 200 Benzene 20.0 19.51 ug/L 98 80-134 Bromochloromethane 20.0 17.41 ug/L 87 74 -128 Bromodichloromethane 20.0 20.91 ug/L 105 72 -129 Bromoform 20.0 19.23 ug/L 96 73 -120 Bromomethane 20.0 23.13 ug/L 116 38 -189 Carbon disulfide 20.0 18.44 ug/L 92 65 -173 Carbon tetrachloride 20.0 22.16 ug/L 111 68 -142 Chlorobenzene 20.0 18.75 ug/L 94 80 -120 Chloroethane 20.0 36.03 ug/L 180 45 - 213 Chloroform 20.0 18.50 ug/L 93 78 -138 Chloromethane 20.0 23.17 ug/L 116 56 -171 cis-1,2-Dichloroethene 20.0 18.80 ug/L 94 69 -120 cis-1,3-Dichloropropene 20.0 21.09 ug/L 105 63 -125 Dibromochloromethane 20.0 19.65 ug/L 98 73 -120 Dibromomethane 20.0 20.32 ug/L 102 76 -124 Ethylbenzene 20.0 18.83 ug/L 94 68 -124 lodomethane 20.0 17.83 ug/L 89 34 -140 Methylene Chloride 20.0 18.33 ug/L 92 68 -128 Styrene 20.0 16.49 ug/L 82 73 -120 Tetrachloroethene 20.0 21.19 ug/L 106 40 -181 Toluene 20.0 18.31 ug/L 92 71 -120 trans- 1,2-Dichloroethene 20.0 17.16 ug/L 86 75-139 trans- 1,3-Dichloropropene 20.0 23.21 ug/L 116 65-152 trans- 1,4-Dichloro-2-butene 20.0 23.51 ug/L 118 10-142 Trichloroethene 20.0 18.72 ug/L 94 74 -120 Trichlorofluoromethane 20.0 43.58 *+ ug/L 218 68 -183 Vinyl acetate 20.0 25.16 ug/L 126 10 -198 Vinyl chloride 20.0 33.42 .+ ug/L 167 49 -150 Xylenes, Total 60.0 57.85 ug/L 96 77 -121 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 119 53 - 136 Dibromofluoromethane (Surr) 115 67 - 129 Toluene-d8 (Surr) 109 59 - 134 Lab Sample ID: LCSD 752-2118/6 Matrix: Water Analysis Batch: 2118 Spike Analyte Added 1,1,1,2-Tetrachloroethane 20.0 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD Result Qualifier Unit 19.27 ug/L %Rec RPD D %Rec Limits RPD Limit 96 71-120 1 16 Eurofins Raleigh 0 Page 113 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2118/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2118 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 1,1,1-Trichloroethane 20.0 19.87 ug/L 99 72-143 0 18 1,1,2,2-Tetrachloroethane 20.0 18.43 ug/L 92 59-133 8 16 1,1,2-Trichloroethane 20.0 19.61 ug/L 98 67-120 2 18 1,1-Dichloroethane 20.0 18.57 ug/L 93 79-141 5 19 1,1-Dichloroethene 20.0 18.59 ug/L 93 75-133 4 20 1,2,3-Trichloropropane 20.0 18.20 ug/L 91 69-127 5 17 1,2-Dibromo-3-Chloropropane 20.0 20.85 ug/L 104 37-157 0 18 1,2-Dibromoethane 20.0 18.43 ug/L 92 66-123 7 15 1,2-Dichlorobenzene 20.0 18.64 ug/L 93 76 -120 3 16 1,2-Dichloroethane 20.0 20.76 ug/L 104 72 -151 1 16 1,2-Dichloropropane 20.0 20.04 ug/L 100 78 -125 2 19 1,4-Dichlorobenzene 20.0 18.22 ug/L 91 76 -122 3 16 2-Butanone (MEK) 40.0 44.58 ug/L 111 36 -135 7 19 2-Hexanone 40.0 50.43 ug/L 126 36 -191 3 17 4-Methyl-2-pentanone (MIBK) 40.0 52.32 ug/L 131 56-166 5 19 Acetone 40.0 38.31 ug/L 96 10 -158 13 78 Acrylonitrile 60.0 64.06 ug/L 107 10 - 200 3 36 Benzene 20.0 18.67 ug/L 93 80 -134 4 17 Bromochloromethane 20.0 17.19 ug/L 86 74 -128 1 18 Bromodichloromethane 20.0 20.29 ug/L 101 72 -129 3 16 Bromoform 20.0 18.30 ug/L 91 73 -120 5 44 Bromomethane 20.0 23.63 ug/L 118 38 -189 2 27 Carbon disulfide 20.0 17.82 ug/L 89 65 -173 3 38 Carbon tetrachloride 20.0 21.15 ug/L 106 68 -142 5 17 Chlorobenzene 20.0 18.62 ug/L 93 80 -120 1 16 Chloroethane 20.0 36.84 ug/L 184 45 - 213 2 26 Chloroform 20.0 18.16 ug/L 91 78 -138 2 17 Chloromethane 20.0 24.02 ug/L 120 56 -171 4 28 cis-1,2-Dichloroethene 20.0 18.12 ug/L 91 69 -120 4 18 cis-1,3-Dichloropropene 20.0 20.36 ug/L 102 63 -125 4 17 Dibromochloromethane 20.0 18.71 ug/L 94 73 -120 5 16 Dibromomethane 20.0 19.75 ug/L 99 76 -124 3 15 Ethylbenzene 20.0 18.43 ug/L 92 68 -124 2 16 lodomethane 20.0 16.93 ug/L 85 34 -140 5 15 Methylene Chloride 20.0 17.35 ug/L 87 68 -128 5 17 Styrene 20.0 15.90 ug/L 79 73 -120 4 23 Tetrachloroethene 20.0 20.17 ug/L 101 40 -181 5 26 Toluene 20.0 17.77 ug/L 89 71 -120 3 17 trans- 1,2-Dichloroethene 20.0 16.36 ug/L 82 75-139 5 19 trans- 1,3-Dichloropropene 20.0 22.76 ug/L 114 65-152 2 16 trans- 1,4-Dichloro-2-butene 20.0 22.83 ug/L 114 10-142 3 28 Trichloroethene 20.0 18.15 ug/L 91 74 -120 3 22 Trichlorofluoromethane 20.0 44.48 .+ ug/L 222 68 -183 2 22 Vinyl acetate 20.0 24.02 ug/L 120 10 -198 5 21 Vinyl chloride 20.0 35.18 *+ ug/L 176 49 -150 5 27 Xylenes, Total 60.0 55.86 ug/L 93 77 -121 4 16 Eurofins Raleigh Page 114 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8260D - Volatile Organic Compounds by GUMS (Continued) Lab Sample ID: LCSD 752-2118/6 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 2118 Surrogate 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) LCSD LCSD %Recovery Qualifier Limits 113 53 - 136 111 67- 129 109 59 - 134 Lab Sample ID: MRL 752-2118/4 Matrix: Water Analysis Batch: 2118 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike MRL MRL %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,1,1,2-Tetrachloroethane 1.00 1.125 ug/L 112 1,1,1-Trichloroethane 1.00 1.025 ug/L 103 1,1,2,2-Tetrachloroethane 1.00 1.073 ug/L 107 1,1,2-Trichloroethane 1.00 1.195 ug/L 120 1,1-Dichloroethane 1.00 1.018 ug/L 102 1,1-Dichloroethene 1.00 1.571 ug/L 157 1,2,3-Trichloropropane 1.00 1.078 ug/L 108 1,2-Dibromo-3-Chloropropane 1.00 1.016 ug/L 102 1,2-Dibromoethane 1.00 1.130 ug/L 113 1,2-Dichlorobenzene 1.00 0.9575 J ug/L 96 1,2-Dichloroethane 1.00 1.152 ug/L 115 1,2-Dichloropropane 1.00 1.106 ug/L ill 1,4-Dichlorobenzene 1.00 1.188 ug/L 119 2-Butanone (MEK) 2.00 <10.0 ug/L 180 2-Hexanone 2.00 2.764 J ug/L 138 4-Methyl-2-pentanone (MIBK) 2.00 2.480 J ug/L 124 Acetone 2.00 <10.0 ug/L 109 Acrylonitrile 5.00 5.671 J ug/L 113 Benzene 1.00 1.104 ug/L 110 Bromochloromethane 1.00 1.038 ug/L 104 Bromodichloromethane 1.00 1.196 ug/L 120 Bromoform 1.00 1.455 ug/L 145 Bromomethane 1.00 1.707 ug/L 171 Carbon disulfide 2.00 2.326 J ug/L 116 Carbon tetrachloride 1.00 1.111 ug/L ill Chlorobenzene 1.00 1.007 ug/L 101 Chloroethane 1.00 1.482 ug/L 148 Chloroform 1.00 1.158 ug/L 116 Chloromethane 1.00 1.374 ug/L 137 cis-1,2-Dichloroethene 1.00 1.089 ug/L 109 cis-1,3-Dichloropropene 1.00 1.050 ug/L 105 Dibromochloromethane 1.00 1.050 ug/L 105 Dibromomethane 1.00 1.009 ug/L 101 Ethylbenzene 1.00 0.9208 J ug/L 92 Iodomethane 2.00 3.632 J ug/L 182 Methylene Chloride 1.00 1.331 ug/L 133 Styrene 1.00 1.243 ug/L 124 Tetrachloroethene 1.00 1.004 ug/L 100 Toluene 1.00 1.137 ug/L 114 Eurofins Raleigh Page 115 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8260D - Volatile Organic Compounds by GC/MS (Continued) Lab Sample ID: MRL 752-2118/4 Matrix: Water Analysis Batch: 2118 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike MRL MRL %Rec Analyte Added Result Qualifier Unit D %Rec Limits trans- 1,2-Dichloroethene 1.00 1.027 ug/L 103 trans- 1,3-Dichloropropene 1.00 1.017 ug/L 102 trans- 1,4-Dichloro-2-butene 1.00 <0.700 ug/L 51 Trichloroethene 1.00 1.174 ug/L 117 Trichlorofluoromethane 1.00 1.591 ug/L 159 Vinyl acetate 2.00 2.026 J ug/L 101 Vinyl chloride 1.00 1.409 ug/L 141 Xylenes, Total 3.00 2.762 J ug/L 92 MRL MRL Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 111 53 - 136 Dibromofluoromethane (Surr) 115 67 - 129 Toluene-d8 (Surr) 107 59 - 134 Method: 8270D - Semivolatile Organic Compounds (GC/MS) Lab Sample ID: MB 680-769544/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769649 Prep Batch: 769544 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4,5-Tetrachlorobenzene <4.50 10.0 4.50 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,3,4,6-Tetrachlorophenol <4.30 10.0 4.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4,5-Trichlorophenol <3.30 10.0 3.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4,6-Trichlorophenol <2.20 10.0 2.20 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4-Dichlorophenol <3.70 10.0 3.70 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4-Dimethylphenol <3.00 10.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4-Dinitrophenol <16.0 50.0 16.0 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,4-Dinitrotoluene <2.30 10.0 2.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 2,6-Dinitrotoluene <2.80 10.0 2.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 2-Chloronaphthalene <4.80 10.0 4.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 2-Chlorophenol <3.20 10.0 3.20 ug/L 03/24/23 14:39 03/25/23 17:46 1 2-Methylphenol <1.80 10.0 1.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 2-Nitroaniline <2.90 50.0 2.90 ug/L 03/24/23 14:39 03/25/23 17:46 1 2-Nitrophenol <3.90 10.0 3.90 ug/L 03/24/23 14:39 03/25/23 17:46 1 3 & 4 Methylphenol <1.40 10.0 1.40 ug/L 03/24/23 14:39 03/25/23 17:46 1 3,3'-Dichlorobenzidine <10.0 60.0 10.0 ug/L 03/24/23 14:39 03/25/23 17:46 1 3-Nitroaniline <3.00 50.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 4,6-Dinitro-2-methylphenol <5.30 50.0 5.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Bromophenyl phenyl ether <4.70 10.0 4.70 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Chloro-3-methylphenol <2.50 10.0 2.50 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Chloroaniline <1.00 20.0 1.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Chlorophenyl phenyl ether <5.30 10.0 5.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Nitroaniline <3.00 50.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 4-Nitrophenol <8.10 50.0 8.10 ug/L 03/24/23 14:39 03/25/23 17:46 1 Acenaphthene <4.40 10.0 4.40 ug/L 03/24/23 14:39 03/25/23 17:46 1 Acenaphthylene <3.60 10.0 3.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 Acetophenone <2.20 10.0 2.20 ug/L 03/24/23 14:39 03/25/23 17:46 1 Anthracene <3.60 10.0 3.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 0 Eurofins Raleigh Page 116 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: MB 680-769544/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769649 Prep Batch: 769544 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzo[a]anthracene <4.20 10.0 4.20 ug/L 03/24/23 14:39 03/25/23 17:46 1 Benzo[a]pyrene <2.80 10.0 2.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 Benzo[b]fluoranthene <3.10 10.0 3.10 ug/L 03/24/23 14:39 03/25/23 17:46 1 Benzo[g,h,i]perylene <3.00 10.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 Benzo[k]fluoranthene <2.90 10.0 2.90 ug/L 03/24/23 14:39 03/25/23 17:46 1 Benzyl alcohol <2.60 10.0 2.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 bis (2-chloroisopropyl) ether <3.10 10.0 3.10 ug/L 03/24/23 14:39 03/25/23 17:46 1 Bis(2-chloroethoxy)methane <1.80 10.0 1.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 Bis(2-chloroethyl)ether <3.60 10.0 3.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 Bis(2-ethylhexyl) phthalate <3.00 10.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 Butyl benzyl phthalate <2.80 10.0 2.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 Chrysene <3.80 10.0 3.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 Dibenz(a,h)anthracene <3.00 10.0 3.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 Dibenzofuran <1.90 10.0 1.90 ug/L 03/24/23 14:39 03/25/23 17:46 1 Diethyl phthalate <2.20 10.0 2.20 ug/L 03/24/23 14:39 03/25/23 17:46 1 Di-n-butyl phthalate <2.30 10.0 2.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 Di-n-octyl phthalate <2.80 10.0 2.80 ug/L 03/24/23 14:39 03/25/23 17:46 1 Fluoranthene <1.60 10.0 1.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 Fluorene <3.40 10.0 3.40 ug/L 03/24/23 14:39 03/25/23 17:46 1 Hexachlorobenzene <1.60 10.0 1.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 Hexachlorocyclopentadiene <3.50 10.0 3.50 ug/L 03/24/23 14:39 03/25/23 17:46 1 Hexachloroethane <3.60 10.0 3.60 ug/L 03/24/23 14:39 03/25/23 17:46 1 Indeno[1,2,3-cd]pyrene <4.30 10.0 4.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 Isophorone <2.00 10.0 2.00 ug/L 03/24/23 14:39 03/25/23 17:46 1 Nitrobenzene <3.50 10.0 3.50 ug/L 03/24/23 14:39 03/25/23 17:46 1 N-Nitrosodimethylamine <2.10 10.0 2.10 ug/L 03/24/23 14:39 03/25/23 17:46 1 N-N itrosod i-n-propylamine <2.40 10.0 2.40 ug/L 03/24/23 14:39 03/25/23 17:46 1 N-Nitrosodiphenylamine <2.90 10.0 2.90 ug/L 03/24/23 14:39 03/25/23 17:46 1 Phenanthrene <4.30 10.0 4.30 ug/L 03/24/23 14:39 03/25/23 17:46 1 Phenol <1.50 10.0 1.50 ug/L 03/24/23 14:39 03/25/23 17:46 1 Pyrene <3.70 10.0 3.70 ug/L 03/24/23 14:39 03/25/23 17:46 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4, 6-Tribromophenol (Surr) 73 30 - 130 03/24/23 14:39 03/25/23 17:46 1 2-Fluorobiphenyl (Surr) 63 25- 130 03/24/23 14:39 03/25/23 17:46 1 2-Fluorophenol (Surr) 33 10 - 130 03/24/23 14:39 03/25/23 17:46 1 Nitrobenzene-d5 (Surr) 68 30 - 130 03/24/23 14:39 03125123 17:46 1 Phenol-d5 (Surr) 23 10 - 130 03/24/23 14:39 03125123 17:46 1 Terphenyl-d14 (Surr) 75 35- 131 03/24/23 14:39 03125123 17:46 1 Lab Sample ID: LCS 680-769544/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769649 Prep Batch: 769544 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,2,4,5-Tetrachlorobenzene 200 127.1 ug/L 64 21-130 2,3,4,6-Tetrachlorophenol 200 174.3 ug/L 87 27 -130 2,4,5-Trichlorophenol 200 156.1 ug/L 78 26 -130 Eurofins Raleigh Page 117 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-769544/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769649 Prep Batch: 769544 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 2,4,6-Trichlorophenol 200 157.2 ug/L 79 28 -130 2,4-Dichlorophenol 200 140.0 ug/L 70 27 -130 2,4-Dimethylphenol 200 121.3 ug/L 61 26 -130 2,4-Dinitrophenol 400 591.7 .+ ug/L 148 23 -130 2,4-Dinitrotoluene 200 190.9 ug/L 95 37-130 2,6-Dinitrotoluene 200 185.3 ug/L 93 35-130 2-Chloronaphthalene 200 132.1 ug/L 66 25 -130 2-Chlorophenol 200 117.7 ug/L 59 24 -130 2-Methylphenol 200 108.7 ug/L 54 21 -130 2-Nitroaniline 200 195.7 ug/L 98 36 -130 2-Nitrophenol 200 174.2 ug/L 87 27 -130 3 & 4 Methylphenol 200 103.3 ug/L 52 19 -130 3,3'-Dichlorobenzidine 200 222.8 ug/L 111 35 -130 3-Nitroaniline 200 177.6 ug/L 89 14 -130 4,6-Dinitro-2-methylphenol 400 518.1 ug/L 130 38 -130 4-Bromophenyl phenyl ether 200 145.4 ug/L 73 34 -130 4-Chloro-3-methylphenol 200 158.7 ug/L 79 28 -130 4-Chloroaniline 200 122.1 ug/L 61 10 -130 4-Chlorophenyl phenyl ether 200 141.7 ug/L 71 31 -130 4-Nitroaniline 200 185.6 ug/L 93 36 -130 4-Nitrophenol 400 153.6 ug/L 38 10 -130 Acenaphthene 200 141.0 ug/L 71 28-130 Acenaphthylene 200 149.6 ug/L 75 31-130 Acetophenone 200 132.0 ug/L 66 28-130 Anthracene 200 150.5 ug/L 75 36-130 Benzo[a]anthracene 200 155.7 ug/L 78 34 -130 Benzo[a]pyrene 200 154.2 ug/L 77 36 -130 Benzo[b]fluoranthene 200 147.2 ug/L 74 35 -130 Benzo[g,h,i]perylene 200 154.8 ug/L 77 35-130 Benzo[k]fluoranthene 200 160.0 ug/L 80 34 -130 Benzyl alcohol 200 107.8 ug/L 54 21 -130 bis (2-chloroisopropyl) ether 200 114.6 ug/L 57 33 -130 Bis(2-chloroethoxy)methane 200 134.9 ug/L 67 31 -130 Bis(2-chloroethyl)ether 200 123.0 ug/L 62 30 -130 Bis(2-ethylhexyl) phthalate 200 161.5 ug/L 81 33 -138 Butyl benzyl phthalate 200 168.7 ug/L 84 35 -135 Chrysene 200 146.9 ug/L 73 33-130 Dibenz(a,h)anthracene 200 156.5 ug/L 78 35-130 Dibenzofuran 200 146.9 ug/L 73 31 -130 Diethyl phthalate 200 158.5 ug/L 79 36 -130 Di-n-butyl phthalate 200 166.7 ug/L 83 35 -130 Di-n-octyl phthalate 200 169.5 ug/L 85 34 -139 Fluoranthene 200 164.0 ug/L 82 35 -130 Fluorene 200 145.9 ug/L 73 33 -130 Hexachlorobenzene 200 143.0 ug/L 71 30-130 Hexachlorocyclopentadiene 200 109.6 ug/L 55 15 -130 Hexachloroethane 200 113.1 ug/L 57 12 -130 Indeno[1,2,3-cd]pyrene 200 162.2 ug/L 81 34-130 Isophorone 200 141.2 ug/L 71 27 -130 0 Eurofins Raleigh Page 118 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-769544/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769649 Prep Batch: 769544 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Nitrobenzene 200 138.0 ug/L 69 32 -130 N-Nitrosodimethylamine 200 78.04 ug/L 39 15-130 N-Nitrosodi-n-propylamine 200 133.2 ug/L 67 33-130 N-Nitrosodiphenylamine 200 148.8 ug/L 74 35-130 Phenanthrene 200 150.4 ug/L 75 36 -130 Phenol 200 52.82 ug/L 26 10 -130 Pyrene 200 151.9 ug/L 76 33 -130 Surrogate LCS LCS %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 81 30- 130 2-Fluorobiphenyl (Surr) 60 25 - 130 2-Fluorophenol (Surr) 33 10 - 130 Nitrobenzene-d5 (Surr) 66 30 - 130 Phenol-d5 (Surr) 23 10 - 130 Terphenyl-d14 (Surr) 67 35- 131 Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769649 Analyte Sample Result Sample Qualifier Spike Added MS Result MS Qualifier Unit 1,2,4,5-Tetrachlorobenzene <4.80 198 119.3 ug/L 2,3,4,6-Tetrachlorophenol <4.59 198 177.5 ug/L 2,4,5-Trichlorophenol <3.52 198 157.9 ug/L 2,4,6-Trichlorophenol <2.35 198 152.9 ug/L 2,4-Dichlorophenol <3.95 198 139.3 ug/L 2,4-Dimethylphenol <3.20 198 121.1 ug/L 2,4-Dinitrophenol <17.1 F1 '+ 396 605.2 F1 ug/L 2,4-Dinitrotoluene <2.46 198 191.3 ug/L 2,6-Dinitrotoluene <2.99 198 183.0 ug/L 2-Chloronaphthalene <5.12 198 127.2 ug/L 2-Chlorophenol <3.42 198 118.1 ug/L 2-Methylphenol <1.92 198 108.6 ug/L 2-Nitroaniline <3.10 198 195.5 ug/L 2-Nitrophenol <4.16 198 170.4 ug/L 3 & 4 Methylphenol <1.49 198 101.9 ug/L 3,3'-Dichlorobenzidine <10.7 198 107.9 ug/L 3-Nitroaniline <3.20 198 170.9 ug/L 4,6-Dinitro-2-methylphenol <5.66 F1 396 521.1 F1 ug/L 4-Bromophenyl phenyl ether <5.02 198 138.7 ug/L 4-Chloro-3-methylphenol <2.67 198 157.6 ug/L 4-Chloroaniline <1.07 198 115.3 ug/L 4-Chlorophenyl phenyl ether <5.66 198 132.9 ug/L 4-Nitroaniline <3.20 198 193.6 ug/L 4-Nitrophenol <8.65 396 157.4 ug/L Acenaphthene <4.70 198 133.4 ug/L Acenaphthylene <3.84 198 142.5 ug/L Acetophenone <2.35 198 124.3 ug/L Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769544 %Rec D %Rec Limits 60 21 -130 90 27-130 80 26-130 77 28-130 70 27-130 61 26-130 153 23-130 96 37-130 92 35-130 64 25-130 60 24-130 55 21 -130 99 36-130 86 27-130 51 19-130 54 35-130 86 14-130 131 38-130 70 34-130 79 28-130 58 10-130 67 31 -130 98 36-130 40 10-130 67 28-130 72 31 -130 63 28-130 0 Eurofins Raleigh Page 119 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769649 Sample Sample Spike MS MS Analyte Result Qualifier Added Result Qualifier Unit Anthracene <3.84 198 150.2 ug/L Benzo[a]anthracene <4.48 198 155.0 ug/L Benzo[a]pyrene <2.99 198 158.2 ug/L Benzo[k]fluoranthene <3.31 198 164.4 ug/L Benzo[g,h,i]perylene <3.20 198 156.4 ug/L Benzo[k]fluoranthene <3.10 198 151.2 ug/L Benzyl alcohol <2.78 198 108.6 ug/L bis (2-chloroisopropyl) ether <3.31 198 107.7 ug/L Bis(2-chloroethoxy)methane <1.92 198 128.1 ug/L Bis(2-chloroethyl)ether <3.84 198 119.4 ug/L Bis(2-ethylhexyl) phthalate <3.20 198 165.1 ug/L Butyl benzyl phthalate <2.99 198 173.3 ug/L Chrysene <4.06 198 151.6 ug/L Dibenz(a,h)anthracene <3.20 198 158.6 ug/L Dibenzofuran <2.03 198 141.4 ug/L Diethyl phthalate <2.35 198 156.9 ug/L Di-n-butyl phthalate <2.46 198 165.9 ug/L Di-n-octyl phthalate <2.99 198 173.4 ug/L Fluoranthene <1.71 198 163.8 ug/L Fluorene <3.63 198 142.4 ug/L Hexachlorobenzene <1.71 198 136.1 ug/L Hexachlorocyclopentadiene <3.74 198 101.7 ug/L Hexachloroethane <3.84 198 102.9 ug/L Indeno[1,2,3-cd]pyrene <4.59 198 161.4 ug/L Isophorone <2.14 198 131.4 ug/L Nitrobenzene <3.74 198 130.9 ug/L N-Nitrosodimethylamine <2.24 198 79.32 ug/L N-Nitrosodi-n-propylamine <2.56 198 123.2 ug/L N-Nitrosodiphenylamine <3.10 198 145.9 ug/L Phenanthrene <4.59 198 150.1 ug/L Phenol <1.60 198 53.73 ug/L Pyrene <3.95 198 154.1 ug/L MS MS Surrogate %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 81 30- 130 2-Fluorobiphenyl (Surr) 57 25- 130 2-Fluorophenol (Surr) 34 10 - 130 Nitrobenzene-d5 (Surr) 63 30 - 130 Phenol-d5 (Surr) 23 10 - 130 Terphenyl-d14 (Surr) 67 35- 131 Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769649 Sample Sample Spike MSD MSD Analyte Result Qualifier Added Result Qualifier Unit 1,2,4,5-Tetrachlorobenzene <4.80 198 116.1 ug/L 2,3,4,6-Tetrachlorophenol <4.59 198 176.1 ug/L Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch:769544 %Rec D %Rec Limits 76 36-130 78 34-130 80 36-130 83 35-130 79 35-130 76 34-130 55 21 -130 54 33-130 65 31 -130 60 30-130 83 33-138 87 35-135 76 33-130 80 35-130 71 31 -130 79 36-130 84 35-130 87 34-139 83 35-130 72 33-130 69 30-130 51 15-130 52 12-130 81 34-130 66 27-130 66 32-130 40 15-130 62 33-130 74 35-130 76 36-130 27 10-130 78 33-130 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch:769544 %Rec RPD D %Rec Limits RPD Limit 59 21-130 3 50 89 27-130 1 50 Eurofins Raleigh Page 120 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769649 Analyte Sample Result Sample Qualifier Spike Added MSD Result MSD Qualifier Unit 2,4,5-Trichlorophenol <3.52 198 155.0 ug/L 2,4,6-Trichlorophenol <2.35 198 148.4 ug/L 2,4-Dichlorophenol <3.95 198 128.8 ug/L 2,4-Dimethylphenol <3.20 198 108.1 ug/L 2,4-Dinitrophenol <17.1 F1.+ 397 627.2 F1 ug/L 2,4-Dinitrotoluene <2.46 198 190.5 ug/L 2,6-Dinitrotoluene <2.99 198 178.9 ug/L 2-Chloronaphthalene <5.12 198 120.3 ug/L 2-Chlorophenol <3.42 198 111.6 ug/L 2-Methylphenol <1.92 198 102.9 ug/L 2-Nitroaniline <3.10 198 189.6 ug/L 2-Nitrophenol <4.16 198 157.8 ug/L 3 & 4 Methylphenol <1.49 198 95.32 ug/L 3,3'-Dichlorobenzidine <10.7 198 92.92 ug/L 3-Nitroaniline <3.20 198 171.3 ug/L 4,6-Dinitro-2-methylphenol <5.66 F1 397 520.5 F1 ug/L 4-Bromophenyl phenyl ether <5.02 198 137.6 ug/L 4-Chloro-3-methylphenol <2.67 198 145.1 ug/L 4-Chloroaniline <1.07 198 103.8 ug/L 4-Chlorophenyl phenyl ether <5.66 198 130.0 ug/L 4-Nitroaniline <3.20 198 190.6 ug/L 4-Nitrophenol <8.65 397 160.9 ug/L Acenaphthene <4.70 198 128.6 ug/L Acenaphthylene <3.84 198 136.7 ug/L Acetophenone <2.35 198 116.1 ug/L Anthracene <3.84 198 150.3 ug/L Benzo[a]anthracene <4.48 198 156.4 ug/L Benzo[a]pyrene <2.99 198 156.6 ug/L Benzo[b]fluoranthene <3.31 198 161.4 ug/L Benzo[g,h,i]perylene <3.20 198 153.2 ug/L Benzo[k]fluoranthene <3.10 198 150.0 ug/L Benzyl alcohol <2.78 198 101.5 ug/L bis (2-chloroisopropyl) ether <3.31 198 104.0 ug/L Bis(2-chloroethoxy)methane <1.92 198 118.8 ug/L Bis(2-chloroethyl)ether <3.84 198 114.5 ug/L Bis(2-ethylhexyl) phthalate <3.20 198 166.6 ug/L Butyl benzyl phthalate <2.99 198 176.8 ug/L Chrysene <4.06 198 154.2 ug/L Dibenz(a,h)anthracene <3.20 198 156.6 ug/L Dibenzofuran <2.03 198 134.9 ug/L Diethyl phthalate <2.35 198 156.2 ug/L Di-n-butyl phthalate <2.46 198 164.9 ug/L Di-n-octyl phthalate <2.99 198 174.3 ug/L Fluoranthene <1.71 198 162.5 ug/L Fluorene <3.63 198 137.7 ug/L Hexachlorobenzene <1.71 198 133.5 ug/L Hexachlorocyclopentadiene <3.74 198 102.0 ug/L Hexachloroethane <3.84 198 104.3 ug/L Indeno[1,2,3-cd]pyrene <4.59 198 158.5 ug/L Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch:769544 %Rec RPD D %Rec Limits RPD Limit 78 26-130 2 50 75 28-130 3 50 65 27-130 8 50 54 26-130 11 50 158 23-130 4 50 96 37-130 0 50 90 35-130 2 50 61 25-130 6 50 56 24-130 6 50 52 21-130 5 50 96 36-130 3 50 80 27-130 8 50 48 19-130 7 50 47 35-130 15 50 86 14-130 0 50 131 38-130 0 50 69 34-130 1 50 73 28-130 8 50 52 10-130 10 50 66 31 -130 2 50 96 36-130 2 50 41 10-130 2 50 65 28-130 4 50 69 31-130 4 50 59 28-130 7 50 76 36-130 0 50 79 34-130 1 50 79 36-130 1 50 81 35-130 2 50 77 35-130 2 50 76 34-130 1 50 51 21-130 7 50 52 33-130 4 50 60 31-130 8 50 58 30-130 4 50 84 33-138 1 50 89 35-135 2 50 78 33-130 2 50 79 35-130 1 50 68 31-130 5 50 79 36-130 0 50 83 35-130 1 50 88 34-139 1 50 82 35-130 1 50 69 33-130 3 50 67 30-130 2 50 51 15-130 0 50 53 12-130 1 50 80 34-130 2 50 Eurofins Raleigh Page 121 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769649 Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch:769544 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Isophorone <2.14 198 121.6 ug/L 61 27-130 8 50 Nitrobenzene <3.74 198 121.9 ug/L 61 32-130 7 50 N-Nitrosodimethylamine <2.24 198 72.93 ug/L 37 15-130 8 50 N-Nitrosodi-n-propylamine <2.56 198 120.2 ug/L 61 33-130 3 50 N-Nitrosodiphenylamine <3.10 198 143.9 ug/L 73 35-130 1 50 Phenanthrene <4.59 198 147.2 ug/L 74 36-130 2 50 Phenol <1.60 198 54.02 ug/L 27 10-130 1 50 Pyrene <3.95 198 157.4 ug/L 79 33 -130 2 50 MSD MSD Surrogate %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 81 30- 130 2-Fluorobiphenyl (Surr) 54 25 - 130 2-Fluorophenol (Surr) 31 10 - 130 Nitrobenzene-d5 (Surr) 57 30 - 130 Phenol-d5 (Surr) 23 10- 130 Terphenyl-d14 (Surr) 67 35- 131 Lab Sample ID: MB 680-769804/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 1,2,4,5-Tetrachlorobenzene <4.50 10.0 4.50 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,3,4,6-Tetrachlorophenol <4.30 10.0 4.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4,5-Trichlorophenol <3.30 10.0 3.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4,6-Trichlorophenol <2.20 10.0 2.20 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4-Dichlorophenol <3.70 10.0 3.70 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4-Dimethylphenol <3.00 10.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4-Dinitrophenol <16.0 50.0 16.0 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,4-Dinitrotoluene <2.30 10.0 2.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 2,6-Dinitrotoluene <2.80 10.0 2.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 2-Chloronaphthalene <4.80 10.0 4.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 2-Chlorophenol <3.20 10.0 3.20 ug/L 03/27/23 08:44 03/27/23 19:44 1 2-Methylphenol <1.80 10.0 1.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 2-Nitroaniline <2.90 50.0 2.90 ug/L 03/27/23 08:44 03/27/23 19:44 1 2-Nitrophenol <3.90 10.0 3.90 ug/L 03/27/23 08:44 03/27/23 19:44 1 3 & 4 Methylphenol <1.40 10.0 1.40 ug/L 03/27/23 08:44 03/27/23 19:44 1 3,3'-Dichlorobenzidine <10.0 60.0 10.0 ug/L 03/27/23 08:44 03/27/23 19:44 1 3-Nitroaniline <3.00 50.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 4,6-Dinitro-2-methylphenol <5.30 50.0 5.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Bromophenyl phenyl ether <4.70 10.0 4.70 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Chloro-3-methylphenol <2.50 10.0 2.50 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Chloroaniline <1.00 20.0 1.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Chlorophenyl phenyl ether <5.30 10.0 5.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Nitroaniline <3.00 50.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 4-Nitrophenol <8.10 50.0 8.10 ug/L 03/27/23 08:44 03/27/23 19:44 1 Acenaphthene <4.40 10.0 4.40 ug/L 03/27/23 08:44 03/27/23 19:44 1 Acenaphthylene <3.60 10.0 3.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Eurofins Raleigh Page 122 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: MB 680-769804/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetophenone <2.20 10.0 2.20 ug/L 03/27/23 08:44 03/27/23 19:44 1 Anthracene <3.60 10.0 3.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzo[a]anthracene <4.20 10.0 4.20 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzo[a]pyrene <2.80 10.0 2.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzo[k]fluoranthene <3.10 10.0 3.10 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzo[g,h,i]perylene <3.00 10.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzo[k]fluoranthene <2.90 10.0 2.90 ug/L 03/27/23 08:44 03/27/23 19:44 1 Benzyl alcohol <2.60 10.0 2.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 bis (2-chloroisopropyl) ether <3.10 10.0 3.10 ug/L 03/27/23 08:44 03/27/23 19:44 1 Bis(2-chloroethoxy)methane <1.80 10.0 1.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 Bis(2-chloroethyl)ether <3.60 10.0 3.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Bis(2-ethylhexyl) phthalate <3.00 10.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 Butyl benzyl phthalate <2.80 10.0 2.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 Chrysene <3.80 10.0 3.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 Dibenz(a,h)anthracene <3.00 10.0 3.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 Dibenzofuran <1.90 10.0 1.90 ug/L 03/27/23 08:44 03/27/23 19:44 1 Diethyl phthalate <2.20 10.0 2.20 ug/L 03/27/23 08:44 03/27/23 19:44 1 Di-n-butyl phthalate <2.30 10.0 2.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 Di-n-octyl phthalate <2.80 10.0 2.80 ug/L 03/27/23 08:44 03/27/23 19:44 1 Fluoranthene <1.60 10.0 1.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Fluorene <3.40 10.0 3.40 ug/L 03/27/23 08:44 03/27/23 19:44 1 Hexachlorobenzene <1.60 10.0 1.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Hexachlorocyclopentadiene <3.50 10.0 3.50 ug/L 03/27/23 08:44 03/27/23 19:44 1 Hexachloroethane <3.60 10.0 3.60 ug/L 03/27/23 08:44 03/27/23 19:44 1 Indeno[1,2,3-cd]pyrene <4.30 10.0 4.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 Isophorone <2.00 10.0 2.00 ug/L 03/27/23 08:44 03/27/23 19:44 1 Nitrobenzene <3.50 10.0 3.50 ug/L 03/27/23 08:44 03/27/23 19:44 1 N-Nitrosodimethylamine <2.10 10.0 2.10 ug/L 03/27/23 08:44 03/27/23 19:44 1 N-N itrosod i-n-propylamine <2.40 10.0 2.40 ug/L 03/27/23 08:44 03/27/23 19:44 1 N-Nitrosodiphenylamine <2.90 10.0 2.90 ug/L 03/27/23 08:44 03/27/23 19:44 1 Phenanthrene <4.30 10.0 4.30 ug/L 03/27/23 08:44 03/27/23 19:44 1 Phenol <1.50 10.0 1.50 ug/L 03/27/23 08:44 03/27/23 19:44 1 Pyrene <3.70 10.0 3.70 ug/L 03/27/23 08:44 03/27/23 19:44 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 2,4,6-Tribromophenol (Surr) 82 30- 130 03/27/23 08:44 03/27/23 19:44 1 2-Fluorobiphenyl (Surr) 72 25 - 130 03/27/23 08:44 03/27/23 19:44 1 2-Fluorophenol (Surr) 34 10 - 130 03/27/23 08:44 03/27/23 19:44 1 Nitrobenzene-d5 (Surr) 67 30 - 130 03/27/23 08:44 03/27/23 19:44 1 Phenol-d5 (Surr) 22 10 - 130 03/27/23 08:44 03/27/23 19:44 1 Terphenyl-d14 (Surr) 107 35- 131 03/27/23 08:44 03/27/23 19:44 1 Lab Sample ID: LCS 680-769804/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 1,2,4,5-Tetrachlorobenzene 200 145.1 ug/L 73 21-130 Eurofins Raleigh Page 123 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-769804/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 2,3,4,6-Tetrachlorophenol 200 193.2 ug/L 97 27 -130 2,4,5-Trichlorophenol 200 164.9 ug/L 82 26 -130 2,4,6-Trichlorophenol 200 181.9 ug/L 91 28 -130 2,4-Dichlorophenol 200 156.2 ug/L 78 27 -130 2,4-Dimethylphenol 200 119.3 ug/L 60 26 -130 2,4-Dinitrophenol 400 561.0 .+ ug/L 140 23 -130 2,4-Dinitrotoluene 200 201.0 ug/L 100 37-130 2,6-Dinitrotoluene 200 187.0 ug/L 94 35-130 2-Chloronaphthalene 200 147.1 ug/L 74 25 -130 2-Chlorophenol 200 123.8 ug/L 62 24 -130 2-Methylphenol 200 106.5 ug/L 53 21 -130 2-Nitroaniline 200 191.4 ug/L 96 36 -130 2-Nitrophenol 200 179.6 ug/L 90 27 -130 3 & 4 Methylphenol 200 104.4 ug/L 52 19 -130 3,3'-Dichlorobenzidine 200 212.2 ug/L 106 35 -130 3-Nitroaniline 200 180.3 ug/L 90 14 -130 4,6-Dinitro-2-methylphenol 400 552.6 '+ ug/L 138 38 -130 4-Bromophenyl phenyl ether 200 169.3 ug/L 85 34 -130 4-Chloro-3-methylphenol 200 159.8 ug/L 80 28 -130 4-Chloroaniline 200 146.3 ug/L 73 10 -130 4-Chlorophenyl phenyl ether 200 164.1 ug/L 82 31 -130 4-Nitroaniline 200 177.0 ug/L 88 36 -130 4-Nitrophenol 400 163.8 ug/L 41 10 -130 Acenaphthene 200 169.7 ug/L 85 28-130 Acenaphthylene 200 166.8 ug/L 83 31-130 Acetophenone 200 143.0 ug/L 71 28-130 Anthracene 200 171.0 ug/L 86 36-130 Benzo[a]anthracene 200 216.8 ug/L 108 34 -130 Benzo[a]pyrene 200 199.5 ug/L 100 36-130 Benzo[b]fluoranthene 200 219.8 ug/L 110 35 -130 Benzo[g,h,i]perylene 200 194.8 ug/L 97 35-130 Benzo[k]fluoranthene 200 178.1 ug/L 89 34 -130 Benzyl alcohol 200 119.4 ug/L 60 21 -130 bis (2-chloroisopropyl) ether 200 137.5 ug/L 69 33 -130 Bis(2-chloroethoxy)methane 200 145.0 ug/L 72 31 -130 Bis(2-chloroethyl)ether 200 141.6 ug/L 71 30 -130 Bis(2-ethylhexyl) phthalate 200 220.1 ug/L 110 33 -138 Butyl benzyl phthalate 200 230.4 ug/L 115 35 -135 Chrysene 200 178.5 ug/L 89 33-130 Dibenz(a,h)anthracene 200 218.5 ug/L 109 35-130 Dibenzofuran 200 156.8 ug/L 78 31 -130 Diethyl phthalate 200 175.2 ug/L 88 36 -130 Di-n-butyl phthalate 200 203.7 ug/L 102 35 -130 Di-n-octyl phthalate 200 220.3 ug/L 110 34 -139 Fluoranthene 200 192.1 ug/L 96 35 -130 Fluorene 200 161.2 ug/L 81 33 -130 Hexachlorobenzene 200 167.7 ug/L 84 30-130 Hexachlorocyclopentadiene 200 64.85 ug/L 32 15 -130 Hexachloroethane 200 103.8 ug/L 52 12 -130 0 Eurofins Raleigh Page 124 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCS 680-769804/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Indeno[1,2,3-cd]pyrene 200 207.8 ug/L 104 34-130 Isophorone 200 148.4 ug/L 74 27 -130 Nitrobenzene 200 141.2 ug/L 71 32 -130 N-Nitrosodimethylamine 200 85.75 ug/L 43 15-130 N-Nitrosodi-n-propylamine 200 142.1 ug/L 71 33-130 N-Nitrosodiphenylamine 200 164.0 ug/L 82 35-130 Phenanthrene 200 167.4 ug/L 84 36 -130 Phenol 200 59.85 ug/L 30 10 -130 Pyrene 200 214.7 ug/L 107 33 -130 LCS LCS Surrogate %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 88 30- 130 2-Fluorobiphenyl (Surr) 69 25 - 130 2-Fluorophenol (Surr) 34 10 - 130 Nitrobenzene-d5 (Surr) 65 30 - 130 Phenol-d5 (Surr) 24 10- 130 Terphenyl-d14 (Surr) 101 35- 131 Lab Sample ID: LCSD 680-769804/3-A Matrix: Water Analysis Batch: 769934 Analyte Spike Added Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Prep Batch: 769804 LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 1,2,4,5-Tetrachlorobenzene 200 137.1 ug/L 69 21-130 6 50 2,3,4,6-Tetrachlorophenol 200 182.8 ug/L 91 27 -130 6 50 2,4,5-Trichlorophenol 200 162.7 ug/L 81 26 -130 1 50 2,4,6-Trichlorophenol 200 175.1 ug/L 88 28 -130 4 50 2,4-Dichlorophenol 200 151.9 ug/L 76 27 -130 3 50 2,4-Dimethylphenol 200 114.9 ug/L 57 26 -130 4 50 2,4-Dinitrophenol 400 542.4 *+ ug/L 136 23 -130 3 50 2,4-Dinitrotoluene 200 192.9 ug/L 96 37-130 4 50 2,6-Dinitrotoluene 200 173.5 ug/L 87 35-130 8 50 2-Chloronaphthalene 200 139.0 ug/L 69 25 -130 6 50 2-Chlorophenol 200 116.7 ug/L 58 24 -130 6 50 2-Methylphenol 200 101.5 ug/L 51 21 -130 5 50 2-Nitroaniline 200 176.0 ug/L 88 36 -130 8 50 2-Nitrophenol 200 176.6 ug/L 88 27 -130 2 50 3 & 4 Methylphenol 200 101.0 ug/L 50 19 -130 3 50 3,3'-Dichlorobenzidine 200 202.9 ug/L 101 35 -130 4 50 3-Nitroaniline 200 173.1 ug/L 87 14 -130 4 50 4,6-Dinitro-2-methylphenol 400 523.4 *+ ug/L 131 38 -130 5 50 4-Bromophenyl phenyl ether 200 159.7 ug/L 80 34 -130 6 50 4-Chloro-3-methylphenol 200 155.9 ug/L 78 28 -130 3 50 4-Chloroaniline 200 141.4 ug/L 71 10 -130 3 50 4-Chlorophenyl phenyl ether 200 151.9 ug/L 76 31 -130 8 50 4-Nitroaniline 200 170.2 ug/L 85 36 -130 4 50 4-Nitrophenol 400 149.5 ug/L 37 10 -130 9 50 Acenaphthene 200 157.2 ug/L 79 28 -130 8 50 Eurofins Raleigh Page 125 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: LCSD 680-769804/3-A Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 769934 Prep Batch: 769804 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Acenaphthylene 200 156.5 ug/L 78 31-130 6 50 Acetophenone 200 138.0 ug/L 69 28-130 4 50 Anthracene 200 159.9 ug/L 80 36-130 7 50 Benzo[a]anthracene 200 197.1 ug/L 99 34 -130 10 50 Benzo[a]pyrene 200 184.0 ug/L 92 36-130 8 50 Benzo[k]fluoranthene 200 206.0 ug/L 103 35 -130 6 50 Benzo[g,h,i]perylene 200 179.4 ug/L 90 35-130 8 50 Benzo[k]fluoranthene 200 162.6 ug/L 81 34 -130 9 50 Benzyl alcohol 200 121.4 ug/L 61 21 -130 2 50 bis (2-chloroisopropyl) ether 200 133.0 ug/L 67 33 -130 3 50 Bis(2-chloroethoxy)methane 200 140.0 ug/L 70 31 -130 4 50 Bis(2-chloroethyl)ether 200 134.7 ug/L 67 30 -130 5 50 Bis(2-ethylhexyl) phthalate 200 204.4 ug/L 102 33 -138 7 50 Butyl benzyl phthalate 200 216.4 ug/L 108 35 -135 6 50 Chrysene 200 164.8 ug/L 82 33 -130 8 50 Dibenz(a,h)anthracene 200 202.4 ug/L 101 35-130 8 50 Dibenzofuran 200 146.1 ug/L 73 31 -130 7 50 Diethyl phthalate 200 166.7 ug/L 83 36 -130 5 50 Di-n-butyl phthalate 200 194.0 ug/L 97 35 -130 5 50 Di-n-octyl phthalate 200 206.8 ug/L 103 34 -139 6 50 Fluoranthene 200 179.6 ug/L 90 35 -130 7 50 Fluorene 200 151.7 ug/L 76 33 -130 6 50 Hexachlorobenzene 200 159.2 ug/L 80 30 -130 5 50 Hexachlorocyclopentadiene 200 77.82 ug/L 39 15 -130 18 50 Hexachloroethane 200 91.48 ug/L 46 12 -130 13 50 Indeno[1,2,3-cd]pyrene 200 190.0 ug/L 95 34 -130 9 50 Isophorone 200 143.9 ug/L 72 27-130 3 50 Nitrobenzene 200 136.7 ug/L 68 32 -130 3 50 N-Nitrosodimethylamine 200 79.36 ug/L 40 15-130 8 50 N-Nitrosodi-n-propylamine 200 140.1 ug/L 70 33-130 1 50 N-Nitrosodiphenylamine 200 152.2 ug/L 76 35-130 7 50 Phenanthrene 200 157.9 ug/L 79 36-130 6 50 Phenol 200 56.86 ug/L 28 10 -130 5 50 Pyrene 200 199.1 ug/L 100 33-130 8 50 LCSD LCSD Surrogate %Recovery Qualifier Limits 2,4,6-Tribromophenol (Surr) 84 30- 130 2-Fluorobiphenyl (Surr) 66 25- 130 2-Fluorophenol (Surr) 33 10 - 130 Nitrobenzene-d5 (Surr) 61 30 - 130 Phenol-d5 (Surr) 23 10 - 130 Terphenyl-d 14 (Surr) 92 35 - 131 Eurofins Raleigh Page 126 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: RSK-175 - Dissolved Gases (GC) Lab Sample ID: MB 200-189739/28 Matrix: Water Analysis Batch: 189739 MB MB Analyte Result Qualifier Carbon dioxide <5000 Lab Sample ID: LCS 200-189739/26 Matrix: Water Analysis Batch: 189739 Analyte Carbon dioxide Lab Sample ID: LCSD 200-189739/27 Matrix: Water Analysis Batch: 189739 Analyte Carbon dioxide Lab Sample ID: MB 200-189761/4 Matrix: Water Analysis Batch: 189761 MB MB Analyte Result Qualifier Carbon dioxide <5000 Lab Sample ID: LCS 200-189761/2 Matrix: Water Analysis Batch: 189761 Analyte Carbon dioxide Lab Sample ID: LCSD 200-189761/3 Matrix: Water Analysis Batch: 189761 Analyte Carbon dioxide Lab Sample ID: MB 200-189814/4 Matrix: Water Analysis Batch: 189814 MB MB Analyte Result Qualifier Carbon dioxide <5000 Lab Sample ID: LCS 200-189814/2 Matrix: Water Analysis Batch: 189814 Analyte Carbon dioxide Job ID: 752-4652-1 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 10000 5000 ug/L 03/28/23 07:49 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 40000 39910 ug/L 100 70-130 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 40000 37190 ug/L 93 70-130 7 30 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 10000 5000 ug/L 03/28/2311:30 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 40000 38450 ug/L 96 70-130 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 40000 47280 ug/L 118 70-130 21 30 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 10000 5000 ug/L 03/29/2311:50 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 40000 38070 ug/L 95 70-130 Eurofins Raleigh Page 127 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: RSK-175 - Dissolved Gases (GC) Lab Sample ID: LCSD 200-189814/3 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 189814 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Carbon dioxide 40000 42670 ug/L 107 70 -130 11 30 Lab Sample ID: MB 200-189816/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 189816 MB MB � Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethane <1.70 4.00 1.70 ug/L 03/29/2313:00 1 Ethene <1.60 3.00 1.60 ug/L 03/29/2313:00 1 Methane <1.20 2.00 1.20 ug/L 03/29/2313:00 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Acetylene 81 50 - 150 03/29/23 13:00 1 Lab Sample ID: LCS 200-189816/2 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 189816 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Ethane 137 135.0 ug/L 99 70 -130 Ethene 127 125.1 ug/L 98 70 -130 Methane 72.8 76.20 ug/L 105 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits Acetylene 91 50 - 150 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 189816 Sample Sample Spike MS Ms %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Methane 223 72.8 297.1 ug/L 102 70 -130 Ethane <1.70 137 135.6 ug/L 99 70 -130 Ethene <1.60 127 127.0 ug/L 100 70 -130 MS MS Surrogate %Recovery Qualifier Limits Acetylene 96 50 - 150 Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 189816 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Methane 223 72.8 289.5 ug/L 92 70 -130 3 30 Ethane <1.70 137 135.2 ug/L 99 70 -130 0 30 Ethene <1.60 127 127.7 ug/L 100 70 -130 1 30 Page 128 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: RSK-175 - Dissolved Gases (GC) (Continued) Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 189816 MSD MSD Surrogate %Recovery Qualifier Limits Acetylene 99 50-150 Lab Sample ID: MB 200-189906/3 Matrix: Water Analysis Batch: 189906 MB MB Analyte Result Qualifier RL Ethane <1.70 4.00 Ethene <1.60 3.00 Methane <1.20 2.00 MB MB Surrogate %Recovery Qualifier Limits Acetylene 78 50 - 150 Lab Sample ID: LCS 200-189906/2 Matrix: Water Analysis Batch: 189906 F Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 1.70 ug/L 04/01/2313:14 1 1.60 ug/L 04/01/2313:14 1 1.20 ug/L 04/01/2313:14 1 Prepared Analyzed DU Fac 04101123 13:14 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Analyte Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits Ethane 137 121.6 ug/L 89 70-130 Ethene 127 116.0 ug/L 91 70 -130 Methane 72.8 69.23 ug/L 95 70 -130 LCS LCS Surrogate %Recovery Qualifier Limits Acetylene 93 50 - 550 Lab Sample ID: LCSD 200-189906/22 Matrix: Water Analysis Batch: 189906 Analyte Ethane Ethene Methane Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 137 123.2 ug/L 90 70 -130 1 30 127 116.8 ug/L 92 70-130 1 30 72.8 67.35 ug/L 92 70 - 130 3 30 LCSD LCSD Surrogate %Recovery Qualifier Acetylene 91 Method: RSK-175 - Dissolved Gases (G Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 189761 Sample Sample Analyte Result Qualifier Carbon dioxide - DL 407000 H Limits 50 - 150 - DL Spike MS MS Added Result Qualifier Unit 79900 545200 H 4 ug/L Client Sample ID: 4501-MW8 Prep Type: Total/NA %Rec D %Rec Limits 173 70-130 Page 129 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: RSK-175 - Dissolved Gases (GC) - DL (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 189761 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Carbon dioxide - DL 407000 H 79900 573600 H 4 ug/L 208 70 -130 5 30 Method: 8081 B - Oraanochlorine Pesticides (GC) Lab Sample ID: MB 680-769227/1-A Matrix: Water Analysis Batch: 769499 Client Sample ID: Method Blank Prep Type: Total/NA • Prep Batch: 769227 Analyte MB Result MB Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 4,4'-DDE <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 4,4'-DDT <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 Aldrin <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 alpha-BHC <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 beta-BHC <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Chlordane (technical) <0.160 0.500 0.160 ug/L 03/23/23 10:01 03/24/23 18:27 1 Chlorobenzilate <0.640 3.00 0.640 ug/L 03/23/23 10:01 03/24/23 18:27 1 delta-BHC <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Dieldrin <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Endosulfan 1 <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Endosulfan 11 <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Endosulfan sulfate <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Endrin <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 Endrin aldehyde <0.00400 0.0500 0.00400 ug/L 03/23/23 10:01 03/24/23 18:27 1 gamma-BHC (Lindane) <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 Heptachlor <0.00100 0.0500 0.00100 ug/L 03/23/23 10:01 03/24/23 18:27 1 Heptachlor epoxide <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Isodrin <0.0110 0.0500 0.0110 ug/L 03/23/23 10:01 03/24/23 18:27 1 Kepone <2.60 5.00 2.60 ug/L 03/23/23 10:01 03/24/23 18:27 1 Methoxychlor <0.00200 0.0500 0.00200 ug/L 03/23/23 10:01 03/24/23 18:27 1 Toxaphene <0.310 5.00 0.310 ug/L 03/23/23 10:01 03/24/23 18:27 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 83 30 - 130 03/23/23 10:01 03/24/23 18:27 1 Tetrachloro-m-xylene 64 30 - 130 03/23/23 10:01 03/24/23 18:27 1 Lab Sample ID: LCS 680-769227/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769499 Prep Batch: 769227 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 4,4'-DDD 0.0400 0.04831 J ug/L 121 30 -130 4,4'-DDE 0.0400 0.04383 J ug/L 110 30 -130 4,4'-DDT 0.0400 0.04833 J ug/L 121 30 -130 Aldrin 0.0400 0.03702 J ug/L 93 30 -130 alpha-BHC 0.0400 0.03992 J ug/L 100 30 -130 beta-BHC 0.0400 0.05506 .+ ug/L 138 30 -130 delta-BHC 0.0400 0.05535 ,+ ug/L 138 30 -130 Dieldrin 0.0400 0.04291 J ug/L 107 30 -130 Eurofins Raleigh Page 130 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) (Continued) Lab Sample ID: LCS 680-769227/2-A Client Sample ID Matrix: Water Analysis Batch: 769499 Spike LCS LCS Analyte Added Result Qualifier Unit D %Rec Endosulfan 1 0.0400 0.04109 J ug/L 103 Endosulfan 11 0.0400 0.04259 J ug/L 106 Endosulfan sulfate 0.0400 0.04742 J ug/L 119 Endrin 0.0400 0.05440 + ug/L 136 Endrin aldehyde 0.0400 0.03912 J ug/L 98 gamma-BHC (Lindane) 0.0400 0.04189 J ug/L 105 Heptachlor 0.0400 0.04024 J ug/L 101 Heptachlor epoxide 0.0400 0.04396 J ug/L 110 Methoxychlor 0.0400 0.04318 J p ug/L 108 LCS LCS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 99 30 - 130 Tetrachloro-m-xylene 75 30 - 130 Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769499 Analyte Sample Result Sample Qualifier Spike Added MS Result MS Qualifier Unit 4,4'-DDD <0.00195 F1 0.0417 0.04669 J ug/L 4,4'-DDE <0.000976 F1 0.0417 0.06248 F1 ug/L 4,4'-DDT <0.000976 F1 F2 0.0417 0.01141 J p F1 ug/L Aldrin <0.00195 F2 0.0417 0.03888 J ug/L alpha-BHC <0.000976 F2 0.0417 0.04255 J ug/L beta-BHC <0.00195 .+ F1 0.0417 0.06617 F1 ug/L delta-BHC <0.00195 .+ F1 0.0417 0.05639 F1 ug/L Dieldrin <0.00195 0.0417 0.04357 J ug/L Endosulfan 1 <0.00195 0.0417 0.04267 J ug/L Endosulfan II <0.00195 0.0417 0.03546 J ug/L Endosulfan sulfate <0.00195 0.0417 0.04470 J ug/L Endrin <0.000976 .+ F1 0.0417 0.05133 J ug/L Endrin aldehyde <0.00390 F1 0.0417 0.04174 J ug/L gamma-BHC (Lindane) 0.00791 J p 0.0417 0.04446 J ug/L Heptachlor <0.000976 0.0417 0.02684 J ug/L Heptachlor epoxide <0.00195 F1 0.0417 0.03620 J p ug/L Methoxychlor <0.00195 F1 F2 0.0417 0.01087 J p F1 ug/L MS MS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 58 30 - 130 Tetrachloro-m-xylene 60 30 - 130 Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769499 Sample Sample Spike MSD MSD Analyte Result Qualifier Added Result Qualifier Unit 4,4'-DDD <0.00195 F1 0.0402 0.06361 F1 ug/L 4,4'-DDE <0.000976 F1 0.0402 0.07016 F1 ug/L Job ID: 752-4652-1 Lab Control Sample Prep Type: Total/NA Prep Batch: 769227 %Rec Limits 30-130 30-130 30-130 30-130 30-130 30-130 � 30-130 30-130 30-130 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769227 %Rec D %Rec Limits 112 30-130 150 30-130 27 30-130 93 30-130 102 30-130 159 30-130 135 30-130 105 30-130 102 30-130 85 30-130 107 30-130 123 30-130 100 30-130 88 30-130 64 30-130 87 30-130 26 30-130 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769227 %Rec RPD D %Rec Limits RPD Limit 158 30-130 31 40 174 30-130 12 40 Eurofins Raleigh Page 131 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 769499 Prep Batch: 769227 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit 4,4'-DDT <0.000976 F1 F2 0.0402 0.006678 J p F1 F2 ug/L 17 30-130 52 40 Aldrin <0.00195 F2 0.0402 0.02464 J p F2 ug/L 61 30 -130 45 40 alpha-BHC <0.000976 F2 0.0402 0.02995 J p ug/L 74 30 -130 35 40 beta-BHC <0.00195 + F1 0.0402 0.05344 F1 ug/L 133 30 -130 21 40 delta-BHC <0.00195 .+ F1 0.0402 0.05048 ug/L 125 30 -130 11 40 Dieldrin <0.00195 0.0402 0.03999 J ug/L 99 30 -130 9 40 Endosulfan 1 <0.00195 0.0402 0.04765 J ug/L 118 30 -130 11 40 Endosulfan 11 <0.00195 0.0402 0.03511 J ug/L 87 30 -130 1 40 Endosulfan sulfate <0.00195 0.0402 0.05066 ug/L 126 30 -130 13 40 Endrin <0.000976 .+ F1 0.0402 0.05952 F1 ug/L 148 30 -130 15 40 Endrin aldehyde <0.00390 F1 0.0402 0.05332 F1 ug/L 133 30 -130 24 40 gamma-BHC (Lindane) 0.00791 J p 0.0402 0.04240 J ug/L 86 30 -130 5 40 Heptachlor <0.000976 0.0402 0.02372 J ug/L 59 30 -130 12 40 Heptachlor epoxide <0.00195 F1 0.0402 0.03931 J p ug/L 98 30 -130 8 40 Methoxychlor <0.00195 F1 F2 0.0402 0.01602 J p ug/L 40 30 -130 38 40 MSD MSD Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 66 30- 130 Tetrachloro-m-xylene 62 30 - 130 Lab Sample ID: MB 680-769585/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769834 Prep Batch: 769585 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 4,4'-DDE <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 4,4'-DDT <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 Aldrin <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 alpha-BHC <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 alpha -Chlordane <0.00500 0.0500 0.00500 ug/L 03/24/23 19:49 03/27/23 14:18 1 beta-BHC <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Chlordane (technical) <0.160 0.500 0.160 ug/L 03/24/23 19:49 03/27/23 14:18 1 Chlorobenzilate <0.640 3.00 0.640 ug/L 03/24/23 19:49 03/27/23 14:18 1 delta-BHC <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Dieldrin <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Endosulfan 1 <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Endosulfan 11 <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Endosulfan sulfate <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Endrin <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 Endrin aldehyde <0.00400 0.0500 0.00400 ug/L 03/24/23 19:49 03/27/23 14:18 1 gamma-BHC (Lindane) <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 gamma -Chlordane <0.00600 0.0500 0.00600 ug/L 03/24/23 19:49 03/27/23 14:18 1 Heptachlor <0.00100 0.0500 0.00100 ug/L 03/24/23 19:49 03/27/23 14:18 1 Heptachlor epoxide <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Isodrin <0.0110 0.0500 0.0110 ug/L 03/24/23 19:49 03/27/23 14:18 1 Kepone <2.60 5.00 2.60 ug/L 03/24/23 19:49 03/27/23 14:18 1 Methoxychlor <0.00200 0.0500 0.00200 ug/L 03/24/23 19:49 03/27/23 14:18 1 Eurofins Raleigh Page 132 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) (Continued) Lab Sample ID: MB 680-769585/1-A Matrix: Water Analysis Batch: 769834 MB MB Analyte Result Qualifier RL MDL Unit Toxaphene <0.310 5.00 0.310 ug/L MB MB Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 105 30- 130 Tetrachloro-m-xylene 68 30 - 130 Lab Sample ID: LCS 680-769585/2-A Matrix: Water Analysis Batch: 769834 Spike Analyte Added 4,4'-DDD 0.0400 4,4'-DDE 0.0400 4,4'-DDT 0.0400 Aldrin 0.0400 alpha-BHC 0.0400 alpha -Chlordane 0.0400 beta-BHC 0.0400 delta-BHC 0.0400 Dieldrin 0.0400 Endosulfan 1 0.0400 Endosulfan 11 0.0400 Endosulfan sulfate 0.0400 Endrin 0.0400 Endrin aldehyde 0.0400 gamma-BHC (Lindane) 0.0400 gamma -Chlordane 0.0400 Heptachlor 0.0400 Heptachlor epoxide 0.0400 Methoxychlor 0.0400 LCS LCS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 104 30 - 130 Tetrachloro-m-xylene 68 30 - 130 Lab Sample ID: LCS 680-769585/5-A Matrix: Water Analysis Batch: 769834 LCS LCS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 110 30 - 130 Tetrachloro-m-xylene 69 30 - 130 Job ID: 752-4652-1 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 769585 D Prepared Analyzed Dil Fac 03/24/2319:49 03/27/2314:18 1 Prepared Analyzed Dil Fac 0312412319:49 0312712314:18 1 0312412319:49 0312712314:18 1 ©. Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769585 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 0.04218 J ug/L 105 30 -130 0.04408 J ug/L 110 30 -130 0.04409 J ug/L 110 30 -130 0.03816 J ug/L 95 30 -130 0.03434 J ug/L 86 30 -130 0.04226 J ug/L 106 30 -130 0.04669 J ug/L 117 30 -130 0.05047 ug/L 126 30 -130 0.04441 J ug/L 111 30-130 0.04043 J ug/L 101 30 -130 0.04296 J ug/L 107 30 -130 0.04670 J ug/L 117 30 -130 0.05062 ug/L 127 30 -130 0.04066 J ug/L 102 30 -130 0.03785 J ug/L 95 30 -130 0.04038 J ug/L 101 30 -130 0.04714 J ug/L 118 30 -130 0.04267 J ug/L 107 30 -130 0.05200 ug/L 130 30 -130 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769585 Eurofins Raleigh Page 133 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) (Continued) Lab Sample ID: LCSD 680-769585/6-A Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 769834 Prep Batch: 769585 LCSD LCSD Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 49 30- 130 Tetrachloro-m-xylene 22 S1- 30- 130 Lab Sample ID: MB 680-770015/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 770371 Prep Batch: 770015 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 4,4'-DDD <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 4,4'-DDE <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 4,4'-DDT <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 Aldrin <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 alpha-BHC <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 beta-BHC <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Chlordane (technical) <0.160 0.500 0.160 ug/L 03/28/23 08:51 03/29/23 20:09 1 Chlorobenzilate <0.640 3.00 0.640 ug/L 03/28/23 08:51 03/29/23 20:09 1 delta-BHC <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Dieldrin <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Endosulfan 1 <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Endosulfan 11 <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Endosulfan sulfate <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Endrin <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 Endrin aldehyde <0.00400 0.0500 0.00400 ug/L 03/28/23 08:51 03/29/23 20:09 1 gamma-BHC (Lindane) <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 Heptachlor <0.00100 0.0500 0.00100 ug/L 03/28/23 08:51 03/29/23 20:09 1 Heptachlor epoxide <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Isodrin <0.0110 0.0500 0.0110 ug/L 03/28/23 08:51 03/29/23 20:09 1 Kepone <2.60 5.00 2.60 ug/L 03/28/23 08:51 03/29/23 20:09 1 Methoxychlor <0.00200 0.0500 0.00200 ug/L 03/28/23 08:51 03/29/23 20:09 1 Toxaphene <0.310 5.00 0.310 ug/L 03/28/23 08:51 03/29/23 20:09 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCB Decachlorobiphenyl 93 30 - 130 03/28/23 08:51 03/29/23 20:09 1 Tetrachloro-m-xylene 58 30 - 130 03/28/23 08:51 03/29/23 20:09 1 Lab Sample ID: LCS 680-770015/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770371 Prep Batch: 770015 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits 4,4'-DDD 0.0400 0.03841 J ug/L 96 30 -130 4,4'-DDE 0.0400 0.03474 J ug/L 87 30 -130 4,4'-DDT 0.0400 0.03929 J ug/L 98 30 -130 Aldrin 0.0400 0.03212 J ug/L 80 30 -130 alpha-BHC 0.0400 0.02845 J ug/L 71 30 -130 beta-BHC 0.0400 0.03857 J ug/L 96 30 -130 delta-BHC 0.0400 0.03786 J ug/L 95 30 -130 Dieldrin 0.0400 0.03537 J ug/L 88 30 -130 Eurofins Raleigh Page 134 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8081 B - Organochlorine Pesticides (GC) (Continued) Lab Sample ID: LCS 680-770015/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770371 Prep Batch: 770015 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Endosulfan 1 0.0400 0.03436 J ug/L 86 30 -130 Endosulfan 11 0.0400 0.03587 J ug/L 90 30 -130 Endosulfan sulfate 0.0400 0.04060 J ug/L 101 30 -130 Endrin 0.0400 0.04059 J ug/L 101 30 -130 Endrin aldehyde 0.0400 0.03566 J ug/L 89 30 -130 gamma-BHC (Lindane) 0.0400 0.02908 J ug/L 73 30 -130 Heptachlor 0.0400 0.03121 J ug/L 78 30 -130 Heptachlor epoxide 0.0400 0.03425 J ug/L 86 30 -130 Methoxychlor 0.0400 0.04487 J ug/L 112 30 -130 LCS LCS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 93 30 - 130 Tetrachloro-m-xylene 58 30 - 130 Lab Sample ID: LCS 680-770015/4-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770371 Prep Batch: 770015 LCS LCS Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 102 30 - 130 Tetrachloro-m-xylene 64 30 - 130 Lab Sample ID: LCSD 680-770015/3-A Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 770371 Prep Batch: 770015 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit 4,4'-DDD 0.0400 0.04297 J ug/L 107 30 -130 11 40 4,4'-DDE 0.0400 0.03976 J ug/L 99 30 -130 13 40 4,4'-DDT 0.0400 0.04437 J ug/L ill 30 -130 12 40 Aldrin 0.0400 0.03453 J ug/L 86 30 -130 7 40 alpha-BHC 0.0400 0.03348 J ug/L 84 30 -130 16 40 beta-BHC 0.0400 0.04199 J ug/L 105 30 -130 8 40 delta-BHC 0.0400 0.04351 J ug/L 109 30 -130 14 40 Dieldrin 0.0400 0.03939 J ug/L 98 30 -130 11 40 Endosulfan 1 0.0400 0.03879 J ug/L 97 30 -130 12 40 Endosulfan 11 0.0400 0.04013 J ug/L 100 30 -130 11 40 Endosulfan sulfate 0.0400 0.04271 J ug/L 107 30 -130 5 40 Endrin 0.0400 0.04582 J ug/L 115 30 -130 12 40 Endrin aldehyde 0.0400 0.03944 J ug/L 99 30 -130 10 40 gamma-BHC (Lindane) 0.0400 0.03333 J ug/L 83 30 -130 14 40 Heptachlor 0.0400 0.03325 J ug/L 83 30 -130 6 40 Heptachlor epoxide 0.0400 0.03836 J ug/L 96 30 -130 11 40 Methoxychlor 0.0400 0.05090 ug/L 127 30 -130 13 40 LCSD LCSD Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 90 30- 130 Tetrachloro-m-xylene 61 30 - 130 Eurofins Raleigh Page 135 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8081 B - Organochlorine Pesticides (GC) Lab Sample ID: LCSD 680-770015/5-A Matrix: Water Analysis Batch: 770371 LCSD LCSD Surrogate %Recovery Qualifier Limits DCB Decachlorobiphenyl 84 30 - 130 Tetrachloro-m-xylene 65 30 - 130 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Prep Batch: 770015 Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Lab Sample ID: MB 680-769227/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769502 Prep Batch: 769227 Analyte MB MB Result Qualifier PCB-1016 <0.320 PCB-1221 <0.340 PCB-1232 <0.340 PCB-1242 <0.340 PCB-1248 <0.340 PCB-1254 <0.340 PCB-1260 <0.340 MB MB Surrogate %Recovery Qualifier Tetrachloro-m-xylene 64 DCB Decachlorobiphenyl 83 Lab Sample ID: LCS 680-769227/5-A Matrix: Water Analysis Batch: 769502 Analyte PCB-1016 PCB-1260 LCS LCS Surrogate %Recovery Qualifier Tetrachloro-m-xylene 62 DCB Decachlorobiphenyl 84 Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769502 Analyte PCB-1016 PCB-1260 Surrogate Tetrachloro-m-xylene DCB Decachlorobiphenyl RL MDL Unit D Prepared Analyzed Dil Fac 1.00 0.320 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 1.00 0.340 ug/L 03/23/2310:01 03/24/2318:27 1 Limits 30-130 30-130 Prepared Analyzed Dil Fac 03/23/23 10: 01 03/24/23 18: 27 1 03/23/23 10: 01 03/24/23 18: 27 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769227 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 2.40 2.058 ug/L 86 30 -130 2.40 2.457 ug/L 102 30 -130 Limits 30 - 130 30 - 130 Sample Sample Spike MS MS Result Qualifier Added Result Qualifier Unit <0.312 2.39 2.076 ug/L <0.332 2.39 2.230 ug/L MS MS %Recovery Qualifier 68 56 Limits 30-130 30-130 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769227 %Rec D %Rec Limits 87 30-130 93 30-130 Page 136 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 769502 Prep Batch: 769227 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit PCB-1016 <0.312 2.64 2.219 ug/L 84 30 -130 8 40 PCB-1260 <0.332 2.64 2.671 ug/L 101 30 -130 18 40 MSD MSD Surrogate %Recovery Qualifier Limits Tetrachloro-m-xylene 61 30 - 130 • DCB Decachlorobiphenyl 42 p 30 - 130 Method: 8151A - Herbicides (GC) Lab Sample ID: MB 680-769190/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 769950 Prep Batch: 769190 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0230 0.250 0.0230 ug/L 03/23/23 09:39 03/27/23 21:27 1 Dinoseb <0.100 0.500 0.100 ug/L 03/23/23 09:39 03/27/23 21:27 1 Silvex (2,4,5-TP) <0.0960 0.850 0.0960 ug/L 03/23/23 09:39 03/27/23 21:27 1 2,4,5-T <0.140 0.850 0.140 ug/L 03/23/23 09:39 03/27/23 21:27 1 2,4-D <0.180 1.10 0.180 ug/L 03/23/23 09:39 03/27/23 21:27 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 99 26 - 137 03/23/23 09:39 03/27/23 21:27 1 Lab Sample ID: LCS 680-769190/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 769950 Prep Batch: 769190 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Pentachlorophenol 1.60 1.422 ug/L 89 32 -136 Dinoseb 6.40 4.960 ug/L 78 10 -141 Silvex (2,4,5-TP) 1.60 1.457 ug/L 91 31 -144 2,4,5-T 1.60 1.263 ug/L 79 11 -130 2,4-D 6.40 5.036 ug/L 79 21 -147 LCS LCS Surrogate %Recovery Qualifier Limits DCAA 106 26 - 137 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 769950 Prep Batch: 769190 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Pentachlorophenol <0.0221 F1 1.52 0.2693 F1 ug/L 18 32 -136 Dinoseb <0.0962 6.07 4.050 ug/L 67 10 -141 Silvex (2,4,5-TP) <0.0924 1.52 1.069 ug/L 70 31 -144 2,4,5-T <0.135 1.52 0.8791 ug/L 58 11 -147 2,4-D <0.173 6.07 4.305 ug/L 71 21 -130 Eurofins Raleigh Page 137 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 8151A - Herbicides (GC) (Continued) Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 769950 Prep Batch: 769190 MS MS Surrogate %Recovery Qualifier Limits DCAA 85 26 - 137 Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 769950 Prep Batch: 769190 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Pentachlorophenol <0.0221 F1 1.49 0.3120 F1 ug/L 21 32-136 15 50 Dinoseb <0.0962 5.96 4.489 ug/L 75 10 -141 10 50 Silvex (2,4,5-TP) <0.0924 1.49 1.179 ug/L 79 31 -144 10 50 2,4,5-T <0.135 1.49 0.9904 ug/L 66 11 _ 147 12 50 2,4-D <0.173 5.96 4.241 ug/L 71 21 _ 130 1 50 MSD MSD Surrogate %Recovery Qualifier Limits DCAA 92 26-137 Lab Sample ID: MB 680-769824/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 770343 Prep Batch: 769824 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Pentachlorophenol <0.0230 0.250 0.0230 ug/L 03/27/2310:41 03/29/2318:07 1 Dinoseb <0.100 0.500 0.100 ug/L 03/27/2310:41 03/29/2318:07 1 Silvex (2,4,5-TP) <0.0960 0.850 0.0960 ug/L 03/27/23 10:41 03/29/23 18:07 1 2,4,5-T <0.140 0.850 0.140 ug/L 03/27/2310:41 03/29/2318:07 1 2,4-D <0.180 1.10 0.180 ug/L 03/27/2310:41 03/29/2318:07 1 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac DCAA 67 p 26 - 137 03/27/23 10:41 03/29/23 18:07 1 Lab Sample ID: LCS 680-769824/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770343 Prep Batch: 769824 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Pentachlorophenol 1.60 1.376 ug/L 86 32 -136 Dinoseb 6.40 5.201 ug/L 81 10 -141 Silvex (2,4,5-TP) 1.60 1.429 ug/L 89 31 -144 2,4,5-T 1.60 1.396 ug/L 87 11 -130 2,4-D 6.40 5.264 ug/L 82 21 -147 LCS LCS Surrogate %Recovery Qualifier Limits DCAA 89 p 26-137 Eurofins Raleigh Page 138 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 8151A - Herbicides (GC) (Continued) Lab Sample ID: 752-4682-4 MS Matrix: Ground Water Analysis Batch: 770343 Sample Sample Spike Analyte Result Qualifier Added 2,4-D <0.170 F1 6.34 MS MS Surrogate %Recovery Qualifier Limits DCAA 58 p 26-137 Lab Sample ID: 752-4682-4 MSD Matrix: Ground Water Analysis Batch: 770343 F Job ID: 752-4652-1 Client Sample ID: 4501-MW11 Prep Type: Total/NA Prep Batch: 769824 MS MS %Rec Result Qualifier Unit D %Rec Limits 9.778 F1 ug/L 154 21-130 Sample Sample Spike MSD MSD Analyte Result Qualifier Added Result Qualifier Unit 2,4-D <0.170 F1 6.01 <0.169 F1 ug/L MSD MSD Surrogate %Recovery Qualifier Limits DCAA 3 p S1- 26- 137 Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Lab Sample ID: MB 680-771548/1015 Matrix: Water Analysis Batch: 771548 Client Sample ID: 4501-MW11 Prep Type: Total/NA Prep Batch: 769824 %Rec RPD D %Rec Limits RPD Limit 0 21 -130 NC 50 Client Sample ID: Method Blank Prep Type: Total/NA MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate <0.400 1.00 0.400 mg/L 04/05/2316:43 1 Chloride <0.200 0.500 0.200 mg/L 04/05/2316:43 1 Lab Sample ID: LCS 680-771548/16 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 771548 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 9.824 mg/L 98 90 -110 Chloride 10.0 10.24 mg/L 102 90 -110 Lab Sample ID: LCSD 680-771548/17 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 771548 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 9.862 mg/L 99 90 -110 0 15 Chloride 10.0 10.25 mg/L 102 90 -110 0 15 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771548 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 11.4 10.0 19.68 mg/L 83 80 -120 Chloride 39.7 10.0 50.68 mg/L 109 80 -120 Page 139 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 300.0-1993 R2.1 - Anions, Ion Chromatography (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771548 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 11.4 10.0 20.11 mg/L 87 80 -120 2 15 Chloride 39.7 10.0 50.86 mg/L 111 80 -120 0 15 Lab Sample ID: 752-4682-4 MS Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771548 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 172 10.0 183.1 4 mg/L 113 80 -120 Chloride 18.2 10.0 28.31 mg/L 101 80 -120 Lab Sample ID: 752-4682-4 MSD Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771548 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 172 10.0 178.8 4 mg/L 70 80 -120 2 15 Chloride 18.2 10.0 28.10 mg/L 99 80 -120 1 15 Lab Sample ID: MB 680-772611/1013 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 772611 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate <0.400 1.00 0.400 mg/L 04/11/2314:57 1 Chloride <0.200 0.500 0.200 mg/L 04/11/2314:57 1 Lab Sample ID: LCS 680-772611/14 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 772611 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 10.32 mg/L 103 90 -110 Chloride 10.0 10.48 mg/L 105 90 -110 Lab Sample ID: LCSD 680-772611/15 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 772611 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 10.16 mg/L 102 90 -110 2 15 Chloride 10.0 10.44 mg/L 104 90 -110 0 15 Lab Sample ID: 752-4682-6 MS Client Sample ID: 4501-MW13 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 772611 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 27.7 10.0 37.10 mg/L 94 80 -120 Chloride 19.9 10.0 30.07 mg/L 102 80 -120 Eurofins Raleigh Page 140 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 300.0-1993 R2.1 - Anions, Ion Chromatography Lab Sample ID: 752-4682-6 MSD Matrix: Ground Water Analysis Batch: 772611 Sample Sample Spike MSD MSD Analyte Result Qualifier Added Result Qualifier Unit Sulfate 27.7 10.0 38.26 mg/L Chloride 19.9 10.0 30.38 mg/L Lab Sample ID: MB 680-773150/1012 Matrix: Water Analysis Batch: 773150 MB MB Analyte Result Qualifier RL Sulfate <0.400 1.00 Chloride <0.200 0.500 Lab Sample ID: LCS 680-773150/13 Matrix: Water Analysis Batch: 773150 F Job ID: 752-4652-1 Client Sample ID: 4501-MW13 Prep Type: Total/NA %Rec RPD C D %Rec Limits RPD Limit 106 80-120 3 15 105 80-120 1 15 Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 0.400 mg/L 04/13/2314:31 1 0.200 mg/L 04/13/2314:31 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 10.00 mg/L 100 90 -110 Chloride 10.0 10.25 mg/L 103 90 -110 Lab Sample ID: LCSD 680-773150/14 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 773150 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 10.07 mg/L 101 90 -110 1 15 Chloride 10.0 10.32 mg/L 103 90 -110 1 15 Method: VFA-HPLC - Volatile Fatty Acids (HPLC/UV) Lab Sample ID: MB 670-28303/5 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 28303 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Acetic acid <0.180 0.500 0.180 mg/L 03/29/23 19:50 1 Butyric acid <0.0890 0.500 0.0890 mg/L 03/29/23 19:50 1 Propionic acid <0.0650 0.500 0.0650 mg/L 03/29/23 19:50 1 Pyruvic Acid <0.0210 0.500 0.0210 mg/L 03/29/23 19:50 1 Hexanoic acid <0.260 0.500 0.260 mg/L 03/29/23 19:50 1 Iso-Hexanoic Acid <0.440 0.500 0.440 mg/L 03/29/23 19:50 1 Iso-Pentanoic Acid <0.180 0.500 0.180 mg/L 03/29/23 19:50 1 Pentanoic acid <0.140 0.500 0.140 mg/L 03/29/23 19:50 1 Lactic Acid/HIBA (2-Hydroxyisobutyic <0.130 0.500 0.130 mg/L 03/29/23 19:50 1 acid) MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac Trimethylacetic Acid 03/29/23 19:50 1 Eurofins Raleigh Page 141 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: VFA-HPLC - Volatile Fatty Acids (HPLC/UV) (Continued) Lab Sample ID: LCS 670-28303/3 Matrix: Water Analysis Batch: 28303 Analyte Acetic acid Butyric acid Propionic acid Pyruvic Acid Hexanoic acid Iso-Hexanoic Acid Iso-Pentanoic Acid Pentanoic acid Lactic Acid/HIBA (2-Hydroxyisobutyic acid) LCS LCS Surrogate %Recovery Qualifier Trimethylacetic Acid NaN Lab Sample ID: LCSD 670-28303/4 Matrix: Water Analysis Batch: 28303 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added LCS LCS Result Qualifier Unit D %Rec %Rec Limits 20.0 20.39 mg/L 102 60 -140 20.0 17.43 mg/L 87 60 -140 20.0 20.49 mg/L 102 60 -140 20.0 20.70 mg/L 104 60 -140 20.0 18.76 mg/L 94 60 -140 20.0 12.91 mg/L 65 60 -140 20.0 23.87 mg/L 119 60 -140 20.0 22.26 mg/L ill 60 -140 40.0 40.01 mg/L 100 60 -140 Limits 50-150 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Acetic acid 20.0 20.27 mg/L 101 60 -140 1 25 Butyric acid 20.0 16.07 mg/L 80 60 -140 8 25 Propionic acid 20.0 19.98 mg/L 100 60 -140 3 25 Pyruvic Acid 20.0 20.70 mg/L 104 60 -140 0 25 Hexanoic acid 20.0 19.61 mg/L 98 60 -140 4 25 Iso-Hexanoic Acid 20.0 13.18 mg/L 66 60 -140 2 25 Iso-Pentanoic Acid 20.0 23.68 mg/L 118 60 -140 1 25 Pentanoic acid 20.0 22.14 mg/L 111 60 -140 1 25 Lactic Acid/HIBA 40.0 39.60 mg/L 99 60 -140 1 25 (2-Hydroxyisobutyic acid) LCSD LCSD Surrogate %Recovery Qualifier Limits Trimethylacetic Acid NaN 50 - 150 Method: 6010D - Metals (ICP) Lab Sample ID: MB 680-769164/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769407 Prep Batch: 769164 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/23/23 06:57 03/23/23 17:01 1 Barium <4.40 10.0 4.40 ug/L 03/23/23 06:57 03/23/23 17:01 1 Beryllium <0.300 4.00 0.300 ug/L 03/23/23 06:57 03/23/23 17:01 1 Cadmium <0.440 5.00 0.440 ug/L 03/23/23 06:57 03/23/23 17:01 1 Chromium <1.10 10.0 1.10 ug/L 03/23/23 06:57 03/23/23 17:01 1 Cobalt <1.40 10.0 1.40 ug/L 03/23/23 06:57 03/23/23 17:01 1 Copper <3.20 20.0 3.20 ug/L 03/23/23 06:57 03/23/23 17:01 1 Lead <6.60 10.0 6.60 ug/L 03/23/23 06:57 03/23/23 17:01 1 Nickel <3.30 40.0 3.30 ug/L 03/23/23 06:57 03/23/23 17:01 1 0 Page 142 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: MB 680-769164/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769407 Prep Batch: 769164 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Selenium <10.0 20.0 10.0 ug/L 03/23/23 06:57 03/23/23 17:01 1 Silver <1.50 10.0 1.50 ug/L 03/23/23 06:57 03/23/23 17:01 1 Tin <11.0 50.0 11.0 ug/L 03/23/23 06:57 03/23/23 17:01 1 Vanadium <1.00 10.0 1.00 ug/L 03/23/23 06:57 03/23/23 17:01 1 Zinc <8.70 20.0 8.70 ug/L 03/23/23 06:57 03/23/23 17:01 1 • Lab Sample ID: LCS 680-769164/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769407 Prep Batch: 769164 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Arsenic 100 96.47 ug/L 96 80 -120 Barium 100 101.5 ug/L 102 80-120 Beryllium 50.0 51.12 ug/L 102 80 -120 Cadmium 50.0 49.82 ug/L 100 80 -120 Chromium 100 103.3 ug/L 103 80 -120 Cobalt 50.0 50.33 ug/L 101 80 -120 Copper 100 107.1 ug/L 107 80 -120 Lead 505 513.6 ug/L 102 80-120 Nickel 100 98.84 ug/L 99 80 -120 Selenium 100 94.87 ug/L 95 80 -120 Silver 50.0 51.41 ug/L 103 80 -120 Tin 100 100.5 ug/L 101 80 -120 Vanadium 100 103.1 ug/L 103 80 -120 Zinc 100 104.5 ug/L 105 80 -120 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total Recoverable Analysis Batch: 769407 Prep Batch: 769164 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Arsenic <6.40 100 98.72 ug/L 99 75 -125 Barium 581 100 759.8 4 ug/L 179 75-125 Beryllium <0.300 50.0 50.48 ug/L 101 75 -125 Cadmium <0.440 50.0 47.86 ug/L 96 75 -125 Chromium <1.10 100 100.8 ug/L 101 75 -125 Cobalt 14.4 50.0 62.04 ug/L 95 75 -125 Copper <3.20 100 105.1 ug/L 105 75 -125 Lead <6.60 505 506.8 ug/L 100 75-125 Nickel <3.30 100 96.72 ug/L 97 75-125 Selenium <10.0 100 98.20 ug/L 98 75 -125 Silver <1.50 50.0 52.67 ug/L 105 75 -125 Tin <11.0 100 99.89 ug/L 100 75 -125 Vanadium <1.00 100 101.2 ug/L 101 75 -125 Zinc <8.70 100 104.7 ug/L 105 75 -125 Eurofins Raleigh Page 143 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total Recoverable Analysis Batch: 769407 Prep Batch: 769164 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Arsenic <6.40 100 97.50 ug/L 98 75 -125 1 20 Barium 581 100 820.1 4 ug/L 239 75-125 8 20 Beryllium <0.300 50.0 50.66 ug/L 101 75 -125 0 20 Cadmium <0.440 50.0 48.32 ug/L 97 75 -125 1 20 Chromium <1.10 100 102.1 ug/L 102 75 -125 1 20 Cobalt 14.4 50.0 62.04 ug/L 95 75 -125 0 20 Copper <3.20 100 106.2 ug/L 106 75 -125 1 20 Lead <6.60 505 510.1 ug/L 101 75-125 1 20 Nickel <3.30 100 96.74 ug/L 97 75 -125 0 20 Selenium <10.0 100 98.30 ug/L 98 75 -125 0 20 Silver <1.50 50.0 53.77 ug/L 108 75 -125 2 20 Tin <11.0 100 100.6 ug/L 101 75 -125 1 20 [Vanadium <1.00 100 102.6 ug/L 103 75 -125 1 20 Zinc <8.70 100 104.0 ug/L 104 75 -125 1 20 Lab Sample ID: MB 680-769391/1-A Matrix: Water Analysis Batch: 769727 Analyte MB MB Result Qualifier RL MDL Unit Client Sample ID: Method Blank C Prep Type: Total Recoverable Prep Batch: 769391 D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/24/23 06:33 03/24/23 19:01 1 Barium <4.40 10.0 4.40 ug/L 03/24/23 06:33 03/24/23 19:01 1 Beryllium 0.9400 J 4.00 0.300 ug/L 03/24/23 06:33 03/24/23 19:01 1 Cadmium <0.440 5.00 0.440 ug/L 03/24/23 06:33 03/24/23 19:01 1 Chromium <1.10 10.0 1.10 ug/L 03/24/23 06:33 03/24/23 19:01 1 Cobalt <1.40 10.0 1.40 ug/L 03/24/23 06:33 03/24/23 19:01 1 Copper <3.20 20.0 3.20 ug/L 03/24/23 06:33 03/24/23 19:01 1 Iron <20.0 100 20.0 ug/L 03/24/23 06:33 03/24/23 19:01 1 Lead <6.60 10.0 6.60 ug/L 03/24/23 06:33 03/24/23 19:01 1 Manganese <1.30 10.0 1.30 ug/L 03/24/23 06:33 03/24/23 19:01 1 Nickel <3.30 40.0 3.30 ug/L 03/24/23 06:33 03/24/23 19:01 1 Selenium <10.0 20.0 10.0 ug/L 03/24/23 06:33 03/24/23 19:01 1 Silver <1.50 10.0 1.50 ug/L 03/24/23 06:33 03/24/23 19:01 1 Tin <11.0 50.0 11.0 ug/L 03/24/23 06:33 03/24/23 19:01 1 Vanadium <1.00 10.0 1.00 ug/L 03/24/23 06:33 03/24/23 19:01 1 Zinc <8.70 20.0 8.70 ug/L 03/24/23 06:33 03/24/23 19:01 1 Lab Sample ID: LCS 680-769391/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769727 Prep Batch: 769391 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Arsenic 100 91.42 ug/L 91 80 -120 Barium 100 96.85 ug/L 97 80-120 Beryllium 50.0 51.14 ug/L 102 80 -120 Cadmium 50.0 48.65 ug/L 97 80 -120 Chromium 100 101.3 ug/L 101 80 -120 Cobalt 50.0 48.70 ug/L 97 80 -120 Copper 100 105.1 ug/L 105 80 -120 Eurofins Raleigh Page 144 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: LCS 680-769391/2-A Matrix: Water Analysis Batch: 769727 Analyte Iron Lead Manganese Nickel Selenium Silver Tin Vanadium Zinc Lab Sample ID: 752-4682-4 MS Matrix: Ground Water Analysis Batch: 769727 Sample Sample Analyte Result Qualifier Arsenic <6.40 Barium 68.4 Beryllium 1.13 J B Cadmium <0.440 Chromium <1.10 Cobalt 2.77 J Copper <3.20 Iron 3610 Lead <6.60 Manganese 7660 Nickel <3.30 Selenium <10.0 Silver <1.50 Vanadium 1.70 J Zinc <8.70 Lab Sample ID: 752-4682-4 MSD Matrix: Ground Water Analysis Batch: 769727 Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 769391 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 5000 4764 ug/L 95 80-120 505 500.4 ug/L 99 80 -120 400 395.8 ug/L 99 80 -120 100 96.49 ug/L 96 80 -120 100 91.52 ug/L 92 80-120 50.0 45.89 ug/L 92 80 -120 100 99.73 ug/L 100 80 -120 100 99.20 ug/L 99 80 -120 100 101.6 ug/L 102 80-120 Client Sample ID: 4501-MW11 Prep Type: Total Recoverable Prep Batch: 769391 Spike MS MS %Rec Added Result Qualifier Unit D %Rec Limits 100 94.68 ug/L 95 75 -125 100 162.3 ug/L 94 75 -125 50.0 51.06 ug/L 100 75 -125 50.0 47.51 ug/L 95 75 -125 100 99.78 ug/L 100 75 -125 50.0 49.90 ug/L 94 75-125 100 104.6 ug/L 105 75 -125 5000 8256 ug/L 93 75-125 505 498.7 ug/L 99 75 -125 400 7888 4 ug/L 58 75-125 100 94.81 ug/L 95 75 -125 100 94.52 ug/L 95 75 -125 50.0 46.64 ug/L 93 75 -125 100 100.8 ug/L 99 75 -125 100 99.87 ug/L 100 75 -125 Analyte Sample Result Sample Qualifier Spike Added MSD MSD Result Qualifier Unit Arsenic <6.40 100 96.41 ug/L Barium 68.4 100 164.5 ug/L Beryllium 1.13 J B 50.0 51.11 ug/L Cadmium <0.440 50.0 47.45 ug/L Chromium <1.10 100 100.3 ug/L Cobalt 2.77 J 50.0 49.86 ug/L Copper <3.20 100 104.8 ug/L Iron 3610 5000 8636 ug/L Lead <6.60 505 501.5 ug/L Manganese 7660 400 7664 4 ug/L Nickel <3.30 100 94.79 ug/L Selenium <10.0 100 95.00 ug/L Silver <1.50 50.0 46.34 ug/L Client Sample ID: 4501-MW11 Prep Type: Total Recoverable Prep Batch: 769391 %Rec RPD D %Rec Limits RPD Limit 96 75-125 2 20 96 75-125 1 20 100 75-125 0 20 95 75-125 0 20 100 75-125 1 20 94 75-125 0 20 105 75-125 0 20 100 75-125 4 20 99 75-125 1 20 2 75-125 3 20 95 75-125 0 20 95 75-125 1 20 93 75-125 1 20 0 Page 145 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: 752-4682-4 MSD Client Sample ID: 4501-MW11 Matrix: Ground Water Prep Type: Total Recoverable Analysis Batch: 769727 Prep Batch: 769391 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Vanadium 1.70 J 100 99.30 ug/L 98 75 -125 1 20 Zinc <8.70 100 112.4 ug/L 112 75 -125 12 20 Lab Sample ID: MB 680-769602/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769965 Prep Batch: 769602 • MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/28/23 00:03 1 Barium <4.40 10.0 4.40 ug/L 03/25/23 07:48 03/28/23 00:03 1 Beryllium 0.6200 J 4.00 0.300 ug/L 03/25/23 07:48 03/28/23 00:03 1 Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/28/23 00:03 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/28/23 00:03 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/28/23 00:03 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/28/23 00:03 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/28/23 00:03 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/28/23 00:03 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/28/23 00:03 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/28/23 00:03 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/28/23 00:03 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/28/23 00:03 1 Lab Sample ID: LCS 680-769602/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769965 Prep Batch: 769602 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Arsenic 100 92.92 ug/L 93 80 -120 Barium 100 95.64 ug/L 96 80-120 Beryllium 50.0 50.24 ug/L 100 80 -120 Cadmium 50.0 47.35 ug/L 95 80 -120 Chromium 100 96.32 ug/L 96 80 -120 Cobalt 50.0 47.59 ug/L 95 80 -120 Copper 100 100.4 ug/L 100 80 -120 Lead 505 485.7 ug/L 96 80 -120 Nickel 100 95.90 ug/L 96 80 -120 Selenium 100 88.69 ug/L 89 80 -120 Silver 50.0 46.76 ug/L 94 80 -120 Vanadium 100 97.98 ug/L 98 80 -120 Zinc 100 99.49 ug/L 99 80 -120 Lab Sample ID: MB 680-769603/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769965 Prep Batch: 769603 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/25/23 07:48 03/27/23 18:24 1 Barium <4.40 10.0 4.40 ug/L 03/25/23 07:48 03/27/23 18:24 1 Beryllium 0.6100 J 4.00 0.300 ug/L 03/25/23 07:48 03/27/23 18:24 1 Eurofins Raleigh Page 146 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: MB 680-769603/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769965 Prep Batch: 769603 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Cadmium <0.440 5.00 0.440 ug/L 03/25/23 07:48 03/27/23 18:24 1 Chromium <1.10 10.0 1.10 ug/L 03/25/23 07:48 03/27/23 18:24 1 Cobalt <1.40 10.0 1.40 ug/L 03/25/23 07:48 03/27/23 18:24 1 Copper <3.20 20.0 3.20 ug/L 03/25/23 07:48 03/27/23 18:24 1 Iron <20.0 100 20.0 ug/L 03/25/23 07:48 03/27/23 18:24 1 Lead <6.60 10.0 6.60 ug/L 03/25/23 07:48 03/27/23 18:24 1 Manganese <1.30 10.0 1.30 ug/L 03/25/23 07:48 03/27/23 18:24 1 Nickel <3.30 40.0 3.30 ug/L 03/25/23 07:48 03/27/23 18:24 1 Selenium <10.0 20.0 10.0 ug/L 03/25/23 07:48 03/27/23 18:24 1 Silver <1.50 10.0 1.50 ug/L 03/25/23 07:48 03/27/23 18:24 1 Tin <11.0 50.0 11.0 ug/L 03/25/23 07:48 03/27/23 18:24 1 Vanadium <1.00 10.0 1.00 ug/L 03/25/23 07:48 03/27/23 18:24 1 Zinc <8.70 20.0 8.70 ug/L 03/25/23 07:48 03/27/23 18:24 1 Lab Sample ID: LCS 680-769603/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769965 Prep Batch: 769603 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Arsenic 100 93.60 ug/L 94 80 -120 Barium 100 96.91 ug/L 97 80-120 Beryllium 50.0 50.79 ug/L 102 80 -120 Cadmium 50.0 48.32 ug/L 97 80 -120 Chromium 100 98.42 ug/L 98 80 -120 Cobalt 50.0 48.63 ug/L 97 80 -120 Copper 100 102.0 ug/L 102 80 -120 Iron 5000 4903 ug/L 98 80 -120 Lead 505 492.9 ug/L 98 80-120 Manganese 400 401.9 ug/L 100 80-120 Nickel 100 98.32 ug/L 98 80 -120 Selenium 100 86.00 ug/L 86 80 -120 Silver 50.0 46.18 ug/L 92 80 -120 Tin 100 95.90 ug/L 96 80 -120 Vanadium 100 99.32 ug/L 99 80 -120 Zinc 100 99.07 ug/L 99 80 -120 Lab Sample ID: MB 680-770757/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 770885 Prep Batch: 770757 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Arsenic <6.40 20.0 6.40 ug/L 03/31/2310:17 03/31/2319:13 1 Barium <4.40 10.0 4.40 ug/L 03/31/2310:17 03/31/2319:13 1 Beryllium <0.300 4.00 0.300 ug/L 03/31/2310:17 03/31/2319:13 1 Cadmium <0.440 5.00 0.440 ug/L 03/31/2310:17 03/31/2319:13 1 Chromium <1.10 10.0 1.10 ug/L 03/31/2310:17 03/31/2319:13 1 Cobalt <1.40 10.0 1.40 ug/L 03/31/2310:17 03/31/2319:13 1 Copper <3.20 20.0 3.20 ug/L 03/31/2310:17 03/31/2319:13 1 Lead <6.60 10.0 6.60 ug/L 03/31/2310:17 03/31/2319:13 1 Eurofins Raleigh Page 147 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: 6010D - Metals (ICP) (Continued) Lab Sample ID: MB 680-770757/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 770885 Prep Batch: 770757 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Nickel <3.30 40.0 3.30 ug/L 03/31/2310:17 03/31/2319:13 1 Selenium <10.0 20.0 10.0 ug/L 03/31/2310:17 03/31/2319:13 1 Silver <1.50 10.0 1.50 ug/L 03/31/2310:17 03/31/2319:13 1 Vanadium <1.00 10.0 1.00 ug/L 03/31/2310:17 03/31/2319:13 1 Zinc <8.70 20.0 8.70 ug/L 03/31/2310:17 03/31/2319:13 1 • Lab Sample ID: LCS 680-770757/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 770885 Prep Batch: 770757 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Arsenic 100 95.16 ug/L 95 80 -120 Barium 100 101.0 ug/L 101 80-120 Beryllium 50.0 51.18 ug/L 102 80 -120 Cadmium 50.0 49.64 ug/L 99 80 -120 Chromium 100 104.0 ug/L 104 80 -120 Cobalt 50.0 50.38 ug/L 101 80 -120 Copper 100 105.6 ug/L 106 80 -120 Lead 505 513.5 ug/L 102 80-120 Nickel 100 100.1 ug/L 100 80 -120 Selenium 100 93.62 ug/L 94 80 -120 Silver 50.0 48.80 ug/L 98 80 -120 Vanadium 100 101.1 ug/L 101 80 -120 Zinc 100 105.8 ug/L 106 80 -120 Method: 6020B - Metals (ICP/MS) Lab Sample ID: MB 680-769166/1-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769398 Prep Batch: 769166 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Antimony <0.340 5.00 0.340 ug/L 03/23/23 06:57 03/23/23 20:01 1 Thallium <0.260 1.00 0.260 ug/L 03/23/23 06:57 03/23/23 20:01 1 Lab Sample ID: LCS 680-769166/2-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total Recoverable Analysis Batch: 769398 Prep Batch: 769166 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Antimony 50.0 49.22 ug/L 98 80 -120 Thallium 50.0 47.69 ug/L 95 80-120 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total Recoverable Analysis Batch: 769398 Prep Batch: 769166 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Antimony <0.340 50.0 52.35 ug/L 105 75 -125 Thallium <0.260 50.0 50.92 ug/L 102 75-125 Eurofins Raleigh Page 148 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 6020B - Metals (ICP/MS) Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769398 Sample Sample Spike Analyte Result Qualifier Added Antimony <0.340 50.0 Thallium <0.260 50.0 Lab Sample ID: MB 680-769390/1-A Matrix: Water Analysis Batch: 769765 MB MB Analyte Result Qualifier Antimony <0.340 Thallium <0.260 Lab Sample ID: LCS 680-769390/2-A Matrix: Water Analysis Batch: 769765 Analyte Antimony Thallium Lab Sample ID: 752-4682-4 MS Matrix: Ground Water Analysis Batch: 769765 Sample Sample Analyte Result Qualifier Antimony <0.340 Thallium <0.260 Lab Sample ID: 752-4682-4 MSD Matrix: Ground Water Analysis Batch: 769765 Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total Recoverable Prep Batch: 769166 MSD MSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 53.31 ug/L 107 75 -125 2 20 53.24 ug/L 106 75 -125 4 20 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 769390 RL MDL Unit D Prepared Analyzed Dil Fac 5.00 0.340 ug/L 03/24/23 06:33 03/24/23 15:36 1 1.00 0.260 ug/L 03/24/23 06:33 03/24/23 15:36 1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 769390 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 50.0 47.41 ug/L 95 80 -120 50.0 46.58 ug/L 93 80 -120 Client Sample ID: 4501-MW11 Prep Type: Total Recoverable Prep Batch: 769390 Spike MS MS %Rec Added Result Qualifier Unit D %Rec Limits 50.0 48.62 ug/L 97 75 -125 50.0 47.73 ug/L 95 75 -125 Sample Sample Spike Analyte Result Qualifier Added Antimony <0.340 50.0 Thallium <0.260 50.0 Lab Sample ID: MB 680-769601/1-A Matrix: Water Analysis Batch: 769972 MB MB Analyte Result Qualifier Antimony <0.340 Thallium <0.260 Lab Sample ID: LCS 680-769601/2-A Matrix: Water Analysis Batch: 769972 Analyte Antimony Thallium Client Sample ID: 4501-MW11 Prep Type: Total Recoverable Prep Batch: 769390 MSD MSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 49.10 ug/L 98 75 -125 1 20 47.78 ug/L 96 75 -125 0 20 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 769601 RL MDL Unit D Prepared Analyzed Dil Fac 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 18:55 1 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 18:55 1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 769601 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 50.0 50.82 ug/L 102 80 -120 50.0 52.30 ug/L 105 80 -120 Page 149 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 6020B - Metals (ICP/MS) Lab Sample ID: MB 680-769604/1-A Matrix: Water Analysis Batch: 769972 MB MB Analyte Result Qualifier Antimony <0.340 Thallium <0.260 Lab Sample ID: LCS 680-769604/2-A Matrix: Water Analysis Batch: 769972 Spike Analyte Added Antimony 50.0 Thallium 50.0 Lab Sample ID: MB 680-770750/1-A Matrix: Water Analysis Batch: 771193 MB MB Analyte Result Qualifier Antimony <0.340 Thallium <0.260 Lab Sample ID: LCS 680-770750/2-A Matrix: Water Analysis Batch: 771193 Analyte Antimony Thallium Method: 7470A - Mercury (CVAA) Lab Sample ID: MB 680-769300/1-A Matrix: Water Analysis Batch: 769538 MB MB �Analyte Result Qualifier Mercury <0.0800 Lab Sample ID: LCS 680-769300/2-A Matrix: Water Analysis Batch: 769538 �Analyte Mercury FLab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769538 Sample Sample Analyte Result Qualifier Mercury 1.04 F1 Job ID: 752-4652-1 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 769604 RL MDL Unit D Prepared Analyzed Dil Fac 5.00 0.340 ug/L 03/25/23 07:48 03/27/23 15:24 1 1.00 0.260 ug/L 03/25/23 07:48 03/27/23 15:24 1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 769604 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 52.06 ug/L 104 80-120 53.06 ug/L 106 80 -120 Client Sample ID: Method Blank Prep Type: Total Recoverable Prep Batch: 770750 RL MDL Unit D Prepared Analyzed Dil Fac 5.00 0.340 ug/L 03/31/2310:17 04/03/2315:10 1 1.00 0.260 ug/L 03/31/2310:17 04/03/2315:10 1 Client Sample ID: Lab Control Sample Prep Type: Total Recoverable Prep Batch: 770750 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 50.0 52.25 ug/L 105 80 - 120 50.0 49.25 ug/L 99 80 -120 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 769300 RL MDL Unit D Prepared Analyzed Dil Fac 0.200 0.0800 ug/L 03/23/2313:17 03/23/2319:05 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769300 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 2.50 2.405 ug/L 96 80 -120 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769300 Spike MS MS %Rec Added Result Qualifier Unit D %Rec Limits 1.00 1.140 F1 ug/L 9 80-120 Page 150 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 7470A - Mercury (CVAA) (Continued) Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769538 Sample Sample Spike Analyte Result Qualifier Added Mercury 1.04 F1 1.00 Lab Sample ID: MB 680-769463/1-A Matrix: Water Analysis Batch: 769728 MB MB Analyte Result Qualifier Mercury <0.0800 Lab Sample ID: LCS 680-769463/2-A Matrix: Water Analysis Batch: 769728 Spike Analyte Added Mercury 2.50 Lab Sample ID: 752-4682-4 MS Matrix: Ground Water Analysis Batch: 769728 Sample Sample Spike Analyte Result Qualifier Added Mercury <0.0800 F1 1.00 Lab Sample ID: 752-4682-4 MSD Matrix: Ground Water Analysis Batch: 769728 Sample Sample Spike Analyte Result Qualifier Added Mercury <0.0800 F1 1.00 FLab Sample ID: MB 680-769876/1-A Matrix: Water Analysis Batch: 770099 Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 769300 MSD MSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 0.9842 F1 ug/L -6 80-120 15 20 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 769463 RL MDL Unit D Prepared Analyzed Dil Fac 0.200 0.0800 ug/L 03/24/2310:01 03/24/2316:05 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769463 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 2.312 ug/L 92 80 -120 MS MS Result Qualifier Unit 0.5442 F1 ug/L MSD MSD Result Qualifier Unit 0.5580 F1 ug/L MB MB Analyte Result Qualifier RL MDL Unit Mercury <0.0800 0.200 0.0800 ug/L Lab Sample ID: LCS 680-769876/2-A Matrix: Water Analysis Batch: 770099 Spike Analyte Added Mercury 2.50 Lab Sample ID: MB 680-770494/1-A Matrix: Water Analysis Batch: 770613 MB MB Analyte Result Qualifier Mercury <0.0800 Client Sample ID: 4501-MW11 Prep Type: Total/NA Prep Batch: 769463 %Rec D %Rec Limits 54 80-120 Client Sample ID: 4501-MW11 Prep Type: Total/NA Prep Batch: 769463 %Rec RPD D %Rec Limits RPD Limit 56 80-120 3 20 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 769876 D Prepared Analyzed Dil Fac 03/27/2314:22 03/28/2311:27 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 769876 LCS LCS %Rec Result Qualifier Unit D %Rec Limits 2.361 ug/L 94 80-120 RL MDL Unit 0.200 0.0800 ug/L Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 770494 D Prepared Analyzed Dil Fac 03/30/23 09:56 03/30/23 15:38 1 Eurofins Raleigh Page 151 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 7470A - Mercury (CVAA) Lab Sample ID: LCS 680-770494/2-A Matrix: Water Analysis Batch: 770613 Analyte Mercury Lab Sample ID: MB 680-771058/1-A Matrix: Water Analysis Batch: 771251 MB MB Analyte Result Qualifier Mercury <0.0800 Lab Sample ID: LCS 680-771058/2-A Matrix: Water Analysis Batch: 771251 Analyte Mercury Method: 2320B-2011 - Alkalinity, Total Lab Sample ID: MB 680-769846/4 Matrix: Water Analysis Batch: 769846 MB MB Analyte Result Qualifier Alkalinity as CaCO3 to pH 4.5 <2.20 Lab Sample ID: LCS 680-769846/6 Matrix: Water Analysis Batch: 769846 Analyte Alkalinity as CaCO3 to pH 4.5 Lab Sample ID: LCSD 680-769846/31 Matrix: Water Analysis Batch: 769846 Analyte Alkalinity as CaCO3 to pH 4.5 Lab Sample ID: 752-4682-3 DU Matrix: Ground Water Analysis Batch: 769846 Sample Sample Analyte Result Qualifier Alkalinity as CaCO3 to pH 4.5 26.7 F Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 770494 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 2.50 2.360 ug/L 94 80-120 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 771058 Iw RL MDL Unit D Prepared Analyzed Dil Fac 0.200 0.0800 ug/L 04/03/2311:03 04/03/2318:04 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Prep Batch: 771058 Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 2.50 2.468 ug/L 99 80 -120 (- - Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 5.00 2.20 mg/L 03/24/23 23:46 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 250 254.1 mg/L 102 90 -112 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD Added Result Qualifier Unit 250 254.8 mg/L DU DU Result Qualifier Unit 27.47 mg/L %Rec RPD D %Rec Limits RPD Limit 102 90-112 0 30 Client Sample ID: 4501-MW10 Prep Type: Total/NA RPD D RPD Limit 3 30 Page 152 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 2320B-2011 - Alkalinity, Total (Continued) Lab Sample ID: MB 680-770280/4 Matrix: Water Analysis Batch: 770280 MB MB Analyte Result Qualifier RL Alkalinity as CaCO3 to pH 4.5 <2.20 5.00 Lab Sample ID: LCS 680-770280/6 Matrix: Water Analysis Batch: 770280 Spike Analyte Added Alkalinity as CaCO3 to pH 4.5 250 Lab Sample ID: LCSD 680-770280/31 Matrix: Water Analysis Batch: 770280 Spike Analyte Added Alkalinity as CaCO3 to pH 4.5 250 Method: 353.2 - Nitrogen, Nitrite Lab Sample ID: MB 752-1984/11 Matrix: Water Analysis Batch: 1984 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Lab Sample ID: MB 752-1984/27 Matrix: Water Analysis Batch: 1984 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Lab Sample ID: LCS 752-1984/10 Matrix: Water Analysis Batch: 1984 Analyte Nitrite as N Lab Sample ID: LCSD 752-1984/39 Matrix: Water Analysis Batch: 1984 Analyte Nitrite as N F Job ID: 752-4652-1 - Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 2.20 mg/L 03/28/2319:40 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 249.4 mg/L 100 90 -112 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 255.4 mg/L 102 90 -112 2 30 (- Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0168 mg/L 03/21 /23 16:11 1 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0168 mg/L 03/21/2316:27 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 1.00 0.9820 mg/L 98 90 -110 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD Added Result Qualifier Unit 1.00 0.9985 mg/L %Rec RPD D %Rec Limits RPD Limit 100 90-110 2 10 Page 153 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 353.2 - Nitrogen, Nitrite (Continued) Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 1984 Sample Sample Spike Analyte Result Qualifier Added Nitrite as N <0.0168 F1 1.00 Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 1984 Sample Sample Spike Analyte Result Qualifier Added Nitrite as N <0.0168 F1 1.00 Lab Sample ID: MB 752-2027111 Matrix: Water Analysis Batch: 2027 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Lab Sample ID: MB 752-2027117 Matrix: Water Analysis Batch: 2027 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Lab Sample ID: LCS 752-2027/10 Matrix: Water Analysis Batch: 2027 Spike Analyte Added Nitrite as N 1.00 Lab Sample ID: LCSD 752-2027/47 Matrix: Water Analysis Batch: 2027 Spike Analyte Added Nitrite as N 1.00 Lab Sample ID: MB 752-2034/11 Matrix: Water Analysis Batch: 2034 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Lab Sample ID: MB 752-2034123 Matrix: Water Analysis Batch: 2034 MB MB Analyte Result Qualifier Nitrite as N <0.0168 Job ID: 752-4652-1 MS Result MS Qualifier Unit Client Sample ID: 4501-MW8 Prep Type: Total/NA %Rec D %Rec Limits 0.7722 F1 mg/L 77 90 -110 Client Sample ID: 4501-MW8 Prep Type: Total/NA MSD MSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 0.7854 F1 mg/L 79 90 -110 2 10 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0168 mg/L 03/22/2315:56 1 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0168 mg/L 03/22/2316:01 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 0.9844 mg/L 98 90 -110 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 0.9877 mg/L 99 90 -110 0 10 RL MDL Unit 0.100 0.0168 mg/L RL MDL Unit 0.100 0.0168 mg/L Client Sample ID: Method Blank Prep Type: Total/NA D Prepared Analyzed Dil Fac 03/23/23 16:12 1 Client Sample ID: Method Blank Prep Type: Total/NA D Prepared Analyzed Dil Fac 03/23/23 16:24 1 Page 154 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 353.2 - Nitrogen, Nitrite Lab Sample ID: LCS 752-2034/10 Matrix: Water Analysis Batch: 2034 Analyte Nitrite as N Lab Sample ID: LCSD 752-2034/39 Matrix: Water Analysis Batch: 2034 Analyte Nitrite as N Method: 353.2 - Nitrogen, Nitrate -Nitrite Lab Sample ID: MB 752-1986/10 Matrix: Water Analysis Batch: 1986 MB MB Analyte Result Qualifier Nitrate Nitrite as N <0.0410 FLab Sample ID: MB 752-1986/39 Matrix: Water Analysis Batch: 1986 MB MB Analyte Result Qualifier Nitrate Nitrite as N <0.0410 Lab Sample ID: MB 752-1986/73 Matrix: Water Analysis Batch: 1986 MB MB Analyte Result Qualifier Nitrate Nitrite as N <0.0410 Lab Sample ID: LCS 752-1986/11 Matrix: Water Analysis Batch: 1986 Analyte Nitrate Nitrite as N Lab Sample ID: LCS 752-1986/40 Matrix: Water Analysis Batch: 1986 Analyte Nitrate Nitrite as N F Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec C Added Result Qualifier Unit D %Rec Limits 1.00 0.9967 mg/L 100 90-110 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 1.00 0.9735 mg/L 97 90 -110 2 10 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0410 mg/L 03/27/2311:23 1 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0410 mg/L 03/27/2312:23 1 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 0.100 0.0410 mg/L 03/27/2313:56 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 1.25 1.287 mg/L 103 90 -110 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS Added Result Qualifier Unit 1.25 1.237 mg/L %Rec D %Rec Limits 99 90-110 Page 155 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 353.2 - Nitrogen, Nitrate -Nitrite (Continued) Lab Sample ID: LCSD 752-1986/94 Matrix: Water Analysis Batch: 1986 Spike Analyte Added Nitrate Nitrite as N 1.25 Lab Sample ID: MB 752-2160/10 Matrix: Water Analysis Batch: 2160 MB MB Analyte Result Qualifier RL Nitrate Nitrite as N <0.0410 0.100 Lab Sample ID: MB 752-2160125 Matrix: Water Analysis Batch: 2160 MB MB Analyte Result Qualifier RL Nitrate Nitrite as N <0.0410 0.100 Lab Sample ID: LCS 752-2160/11 Matrix: Water Analysis Batch: 2160 Spike Analyte Added Nitrate Nitrite as N 1.25 Lab Sample ID: LCS 752-2160/26 Matrix: Water Analysis Batch: 2160 Spike Analyte Added Nitrate Nitrite as N 1.25 Lab Sample ID: LCSD 752-2160/24 Matrix: Water Analysis Batch: 2160 Spike Analyte Added Nitrate Nitrite as N 1.25 Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 2160 Sample Sample Spike Analyte Result Qualifier Added Nitrate Nitrite as N <0.0410 F1 0.521 Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 2160 Sample Sample Spike Analyte Result Qualifier Added Nitrate Nitrite as N <0.0410 F1 0.521 Page 156 0 Job ID: 752-4652-1 f Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 1.306 mg/L 104 90 -110 1 10 Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 0.0410 mg/L 04/03/2311:05 1 Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac 0.0410 mg/L 04/03/2311:39 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 1.294 mg/L 104 90 -110 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 1.296 mg/L 104 90 -110 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 1.264 mg/L 101 90 -110 2 10 Client Sample ID: 4501-MW8 Prep Type: Total/NA MS MS %Rec Result Qualifier Unit D %Rec Limits 0.5984 F1 mg/L 115 90 -110 Client Sample ID: 4501-MW8 Prep Type: Total/NA MSD MSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 0.5563 mg/L 107 90 -110 7 10 Eurofins Raleigh 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 4500 S2 F-2011 - Sulfide, Total Lab Sample ID: MB 680-769240/1 Matrix: Water Analysis Batch: 769240 MB MB Analyte Result Qualifier Sulfide <1.00 Lab Sample ID: LCS 680-769240/2 Matrix: Water Analysis Batch: 769240 Analyte Sulfide Sulfide as 1-12S Lab Sample ID: LCSD 680-76924013 Matrix: Water Analysis Batch: 769240 Analyte Sulfide Sulfide as 1-12S Lab Sample ID: LLCS 680-769240/4 Matrix: Water Analysis Batch: 769240 Analyte Sulfide Sulfide as 1-12S Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 769240 Sample Sample Analyte Result Qualifier Sulfide <0.926 F1 Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 769240 Sample Sample Analyte Result Qualifier Sulfide <0.926 F1 Lab Sample ID: MB 680-769471/1 Matrix: Water Analysis Batch: 769471 MB MB Analyte Result Qualifier Sulfide <1.00 F Job ID: 752-4652-1 Client Sample ID: Method Blank Prep Type: Total/NA RL RL Unit D Prepared Analyzed Dil Fac 1.00 1.00 mg/L 03/23/2310:41 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 10.0 8.460 mg/L 85 75 -125 10.6 8.989 mg/L 85 75 -125 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 10.0 8.592 mg/L 86 75 -125 2 30 10.6 9.129 mg/L 86 75 -125 2 30 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LLCS LLCS %Rec Added Result Qualifier Unit D %Rec Limits 1.00 <1.00 mg/L 87 1.06 <1.10 mg/L 87 Client Sample ID: 4501-MW8 Prep Type: Total/NA Spike MS MS %Rec Added Result Qualifier Unit D %Rec Limits 8.57 6.019 F1 mg/L 70 75 -125 Client Sample ID: 4501-MW8 Prep Type: Total/NA Spike MSD MSD %Rec RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 9.24 6.187 F1 mg/L 67 75 -125 3 30 Client Sample ID: Method Blank Prep Type: Total/NA RL RL Unit D Prepared Analyzed Dil Fac 1.00 1.00 mg/L 03/24/2310:13 1 Eurofins Raleigh Page 157 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 4500 S2 F-2011 - Sulfide, Total (Continued) Lab Sample ID: LCS 680-769471/2 Matrix: Water Analysis Batch: 769471 Spike Analyte Added Sulfide 10.0 Sulfide as H2S 10.6 Lab Sample ID: LCSD 680-769471/3 Matrix: Water Analysis Batch: 769471 Spike Analyte Added Sulfide 10.0 Sulfide as H2S 10.6 [Lab Sample ID: 752-4682-1 DU Matrix: Ground Water Analysis Batch: 769471 Sample Sample Analyte Result Qualifier Sulfide <0.962 Lab Sample ID: MB 680-770092/1 Matrix: Water Analysis Batch: 770092 MB MB Analyte Result Qualifier RL Sulfide <1.00 1.00 FLab Sample ID: LCS 680-770092/2 Matrix: Water Analysis Batch: 770092 Spike Analyte Added Sulfide 10.0 Sulfide as H2S 10.6 Lab Sample ID: LCSD 680-770092/3 Matrix: Water Analysis Batch: 770092 Spike Analyte Added Sulfide 10.0 Sulfide as H2S 10.6 F Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec C Result Qualifier Unit D %Rec Limits 9.484 mg/L 95 75-125 10.08 mg/L 95 75 -125 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 9.335 mg/L 93 75-125 2 30 9.918 mg/L 93 75-125 2 30 Client Sample ID: 4501-MW6 Prep Type: Total/NA DU DU RPD Result Qualifier Unit D RPD Limit 0.9581 mg/L NC 30 Client Sample ID: Method Blank Prep Type: Total/NA RL Unit D Prepared Analyzed Dil Fac 1.00 mg/L 03/28/2313:30 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 10.61 mg/L 106 75 -125 11.27 mg/L 106 75-125 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA LCSD LCSD %Rec RPD Result Qualifier Unit D %Rec Limits RPD Limit 10.05 mg/L 101 75 -125 5 30 10.68 mg/L 101 75 -125 5 30 Method: 5310 B-2011 - Organic Carbon, Total (TOC) FLab Sample ID: MB 680-771279/2 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 771279 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Total Non-purgeable Organic Carbon <0.500 1.00 0.500 mg/L 04/02/23 02:31 1 Eurofins Raleigh Page 158 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Method: 5310 B-2011 - Organic Carbon, Total (TOC) (Continued) Lab Sample ID: LCS 680-771279/3 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 771279 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Total Non-purgeable Organic 20.0 19.20 mg/L 96 80 -120 Carbon TOC Result 1 20.0 19.26 mg/L 96 80 -120 TOC Result 2 20.0 19.11 mg/L 96 80 -120 TOC Result 3 20.0 19.24 mg/L 96 80 -120 TOC Result 4 20.0 19.30 mg/L 97 80 -120 Lab Sample ID: LCSD 680-771279/4 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 771279 Spike LCSD LCSD %Rec RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Total Non-purgeable Organic 20.0 19.32 mg/L 97 80 -120 1 25 Carbon TOC Result 1 20.0 19.25 mg/L 96 80 -120 0 25 TOC Result 2 20.0 19.42 mg/L 97 80 -120 2 25 TOC Result 3 20.0 19.30 mg/L 97 80 -120 0 25 TOC Result 4 20.0 19.59 mg/L 98 80 -120 1 25 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771279 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Total Non-purgeable Organic 28.0 20.0 50.96 mg/L 115 80 -120 Carbon Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 771279 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Total Non-purgeable Organic 28.0 20.0 50.61 mg/L 113 80 -120 1 25 Carbon Method: 9012B - Cyanide, Total andor Amenable Lab Sample ID: MB 680-770468/12-A Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 770561 Prep Batch: 770468 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Cyanide, Total <0.00250 0.0100 0.00250 mg/L 03/30/23 08:29 03/30/23 12:51 1 Lab Sample ID: LCS 680-770468/13-A Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 770561 Prep Batch: 770468 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Cyanide, Total 0.0500 0.04943 mg/L 99 85 -115 Page 159 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: 9012B - Cyanide, Total andor Amenable (Continued) Lab Sample ID: 752-4652-3 MS Matrix: Ground Water Analysis Batch: 770561 Sample Sample Spike MS MS Analyte Result Qualifier Added Result Qualifier Unit Cyanide, Total 0.00841 J F1 0.0500 0.04962 F1 mg/L Lab Sample ID: 752-4652-3 MSD Matrix: Ground Water Analysis Batch: 770561 Sample Sample Spike MSD MSD Analyte Result Qualifier Added Result Qualifier Unit Cyanide, Total 0.00841 J F1 0.0500 0.04818 F1 mg/L Method: SM 2540C - Solids, Total Dissolved (TD Lab Sample ID: MB 752-1928/1 Matrix: Water Analysis Batch: 1928 MB MB Analyte Result Qualifier Total Dissolved Solids <50.0 FLab Sample ID: LCS 752-1928/2 Matrix: Water Analysis Batch: 1928 Spike Analyte Added Total Dissolved Solids 1000 Lab Sample ID: MB 752-1940/1 Matrix: Water Analysis Batch: 1940 MB MB Analyte Result Qualifier Total Dissolved Solids <50.0 Lab Sample ID: LCS 752-1940/2 Matrix: Water Analysis Batch: 1940 Spike Analyte Added Total Dissolved Solids 1000 Lab Sample ID: 752-4682-4 DU Matrix: Ground Water Analysis Batch: 1940 Sample Sample Analyte Result Qualifier Total Dissolved Solids 610 F Job ID: 752-4652-1 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 770468 %Rec D %Rec Limits 82 85-115 Client Sample ID: 4501-MW8 Prep Type: Total/NA Prep Batch: 770468 Iw %Rec RPD D %Rec Limits RPD Limit 80 85-115 3 20 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 50.0 50.0 mg/L 03/27/2310:55 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 988.0 mg/L 99 90 -110 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 50.0 50.0 mg/L 03/28/2310:16 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS Result Qualifier Unit 958.0 mg/L DU DU Result Qualifier Unit 596.0 mg/L %Rec D %Rec Limits 96 90-110 Client Sample ID: 4501-MW11 Prep Type: Total/NA RPD D RPD Limit 2 10 Eurofins Raleigh Page 160 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued) Lab Sample ID: 752-4682-5 DU Matrix: Ground Water Analysis Batch: 1940 Sample Sample DU DU Analyte Result Qualifier Result Qualifier Unit Total Dissolved Solids 274 672.0 F3 mg/L Method: SM 5210B - BOD, 5-Day Lab Sample ID: SCB 752-1925/2 Matrix: Water Analysis Batch: 1925 SCB SCB Analyte Result Qualifier Biochemical Oxygen Demand 0.8340 Lab Sample ID: USB 752-1925/1 Matrix: Water Analysis Batch: 1925 USB USB Analyte Result Qualifier Biochemical Oxygen Demand <0.00000200 Lab Sample ID: LCS 752-1925/3 Matrix: Water Analysis Batch: 1925 Analyte Biochemical Oxygen Demand Lab Sample ID: 752-4652-3 DU Matrix: Ground Water Analysis Batch: 1925 F Job ID: 752-4652-1 Client Sample ID: 4501-MW12 Prep Type: Total/NA RPD C D RPD Limit 84 10 Client Sample ID: Method Blank Prep Type: Total/NA • RL RL Unit D Prepared Analyzed Dil Fac 0.0000020 0.0000020 mg/L 03/21/2314:40 1 0 0 Client Sample ID: Method Blank Prep Type: Total/NA RL RL Unit D Prepared Analyzed Dil Fac C 0.0000020 0.0000020 mg/L 03/21/2314:37 1 0 0 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec Added Result Qualifier Unit D %Rec Limits 198 182.0 mg/L 92 85-115 Client Sample ID: 4501-MW8 Prep Type: Total/NA Sample Sample DU DU RPD Analyte Result Qualifier Result Qualifier Unit D RPD Limit Biochemical Oxygen Demand 3.83 3.406 mg/L 12 30 FLab Sample ID: SCB 752-1929/2 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 1929 SCB SCB Analyte Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac Biochemical Oxygen Demand 0.8277 0.0000020 0.0000020 mg/L 03/22/23 15:19 1 0 0 Lab Sample ID: USB 752-1929/1 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 1929 USB USB Analyte Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac Biochemical Oxygen Demand 0.02000 0.0000020 0.0000020 mg/L 03/22/23 15:17 1 0 0 Page 161 of 242 Eurofins Raleigh 4/19/2023 QC Sample Results Client: WSP USA Inc Project/Site: Henderson County Landfills Method: SM 5210B - BOD, 5-Day (Continued) Lab Sample ID: LCS 752-1929/3 Matrix: Water Analysis Batch: 1929 Spike Analyte Added Biochemical Oxygen Demand 198 Lab Sample ID: SCB 752-1942/2 Matrix: Water Analysis Batch: 1942 Analyte SCB SCB Result Qualifier Biochemical Oxygen Demand 0.8037 Lab Sample ID: USB 752-1942/1 Matrix: Water Analysis Batch: 1942 USB USB Analyte Result Qualifier Biochemical Oxygen Demand <0.00000200 Lab Sample ID: LCS 752-1942/3 Matrix: Water Analysis Batch: 1942 F Job ID: 752-4652-1 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec L Result Qualifier Unit D %Rec Limits 186.3 mg/L 94 85 -115 Client Sample ID: Method Blank Prep Type: Total/NA RL RL Unit D Prepared Analyzed Dil Fac 0.0000020 0.0000020 mg/L 03/23/2313:52 1 0 0 Client Sample ID: Method Blank Prep Type: Total/NA RL RL Unit D Prepared Analyzed Dil Fac 0.0000020 0.0000020 mg/L 03/23/2313:50 1 0 0 Spike Analyte Added Biochemical Oxygen Demand 198 Client Sample ID: Lab Control Sample Prep Type: Total/NA LCS LCS %Rec Result Qualifier Unit D %Rec Limits 184.0 mg/L 93 85 -115 Method: SM 5220D - COD Lab Sample ID: MB 752-1893/2 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 1893 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chemical Oxygen Demand <10.0 10.0 10.0 mg/L 03/22/23 17:43 1 Lab Sample ID: LCS 752-1893/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 1893 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chemical Oxygen Demand 500 506.2 mg/L 101 95 -105 Lab Sample ID: 752-4652-3 MS Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 1893 Sample Sample Spike MS MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Chemical Oxygen Demand 113 500 588.2 mg/L 95 95 -105 Eurofins Raleigh Page 162 of 242 4/19/2023 QC Sample Results Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method: SM 5220D - COD (Continued) Lab Sample ID: 752-4652-3 MSD Client Sample ID: 4501-MW8 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 1893 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Chemical Oxygen Demand 113 500 596.6 mg/L 97 95 -105 1 5 Lab Sample ID: MB 752-2024/2 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 2024 MB MB � Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Chemical Oxygen Demand <10.0 10.0 10.0 mg/L 03/30/23 10:08 1 Lab Sample ID: LCS 752-2024/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 2024 Spike LCS LCS %Rec Analyte Added Result Qualifier Unit D %Rec Limits Chemical Oxygen Demand 500 502.0 mg/L 100 95 -105 Lab Sample ID: 752-4682-1 MS Client Sample ID: 4501-MW6 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2024 Sample Sample Spike Ms MS %Rec Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Chemical Oxygen Demand 71.1 500 571.3 mg/L 100 95 -105 Lab Sample ID: 752-4682-1 MSD Client Sample ID: 4501-MW6 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 2024 Sample Sample Spike MSD MSD %Rec RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Chemical Oxygen Demand 71.1 500 588.2 mg/L 103 95 -105 3 5 Page 163 of 242 Eurofins Raleigh 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills GC/MS VOA Analysis Batch: 2053 Job ID: 752-4652-1 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 8260D 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 8260D 752-4652-3 4501-MW8 Total/NA Ground Water 8260D MB 752-2053/8 Method Blank Total/NA Water 8260D LCS 752-2053/5 Lab Control Sample Total/NA Water 8260D LCSD 752-2053/6 Lab Control Sample Dup Total/NA Water 8260D MRL 752-2053/4 Lab Control Sample Total/NA Water 8260D 752-4652-3 MS 4501-MW8 Total/NA Ground Water 8260D 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 8260D Analysis Batch: 2066 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4750-1 4501-AMW1D Total/NA Ground Water 8260D 752-4750-2 4501-AMW2D Total/NA Ground Water 8260D MB 752-2066/8 Method Blank Total/NA Water 8260D LCS 752-2066/5 Lab Control Sample Total/NA Water 8260D LCSD 752-2066/6 Lab Control Sample Dup Total/NA Water 8260D MRL 752-2066/4 Lab Control Sample Total/NA Water 8260D Analysis Batch: 2107 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 8260D 752-4682-2 4501-MW7 Total/NA Ground Water 8260D 752-4682-3 4501-MW10 Total/NA Ground Water 8260D 752-4682-4 4501-MW11 Total/NA Ground Water 8260D 752-4682-5 4501-MW12 Total/NA Ground Water 8260D 752-4682-6 4501-MW13 Total/NA Ground Water 8260D 752-4682-7 4501-Old MW2 Total/NA Ground Water 8260D MB 752-2107/8 Method Blank Total/NA Water 8260D LCS 752-2107/5 Lab Control Sample Total/NA Water 8260D LCSD 752-2107/6 Lab Control Sample Dup Total/NA Water 8260D MRL 752-2107/4 Lab Control Sample Total/NA Water 8260D 752-4682-4 MS 4501-MW11 Total/NA Ground Water 8260D 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 8260D Analysis Batch: 2111 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 8260D 752-4749-1 4501-Field Blank Total/NA Water 8260D 752-4750-3 4501-BR1 Total/NA Surface Water 8260D 752-4750-4 4501-BR2 Total/NA Surface Water 8260D 752-4750-5 4501-BR3 Total/NA Surface Water 8260D 752-4750-6 4501-SW1 Total/NA Surface Water 8260D 752-4750-7 4501-MW9 Total/NA Ground Water 8260D 752-4750-8 4501-Trip Blank Total/NA Water 8260D MB 752-2111/9 Method Blank Total/NA Water 8260D LCS 752-2111/5 Lab Control Sample Total/NA Water 8260D LCSD 752-2111/6 Lab Control Sample Dup Total/NA Water 8260D MRL 752-2111/7 Lab Control Sample Total/NA Water 8260D 0 Eurofins Raleigh Page 164 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 GC/MS VOA Analysis Batch: 2118 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4750-1 4501-AMW1D Total/NA Ground Water 8260D 752-4750-2 4501-AMW2D Total/NA Ground Water 8260D MB 752-2118/9 Method Blank Total/NA Water 8260D LCS 752-2118/5 Lab Control Sample Total/NA Water 8260D LCSD 752-2118/6 Lab Control Sample Dup Total/NA Water 8260D MRL 752-2118/4 Lab Control Sample Total/NA Water 8260D Analysis Batch: 770326 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 8260 SIM MB 680-770326/6 Method Blank Total/NA Water 8260 SIM LCS 680-770326/3 Lab Control Sample Total/NA Water 8260 SIM LCSD 680-770326/4 Lab Control Sample Dup Total/NA Water 8260 SIM Analysis Batch: 770731 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4652-1 4501-AMW1S Total/NA Ground Water 8260 SIM 752-4652-3 4501-MW8 Total/NA Ground Water 8260 SIM 752-4682-1 4501-MW6 Total/NA Ground Water 8260 SIM 752-4682-2 4501-MW7 Total/NA Ground Water 8260 SIM 752-4682-3 4501-MW10 Total/NA Ground Water 8260 SIM 752-4682-4 4501-MW11 Total/NA Ground Water 8260 SIM 752-4682-5 4501-MW12 Total/NA Ground Water 8260 SIM 752-4682-6 4501-MW13 Total/NA Ground Water 8260 SIM 752-4748-1 4501-AMW2S Total/NA Ground Water 8260 SIM 752-4749-1 4501-Field Blank Total/NA Water 8260 SIM 752-4750-1 4501-AMW1D Total/NA Ground Water 8260 SIM 752-4750-2 4501-AMW2D Total/NA Ground Water 8260 SIM 752-4750-3 4501-BR1 Total/NA Surface Water 8260 SIM 752-4750-4 4501-BR2 Total/NA Surface Water 8260 SIM 752-4750-5 4501-BR3 Total/NA Surface Water 8260 SIM 752-4750-6 4501-SW1 Total/NA Surface Water 8260 SIM 752-4750-7 4501-MW9 Total/NA Ground Water 8260 SIM 752-4750-8 4501-Trip Blank Total/NA Water 8260 SIM MB 680-770731/6 Method Blank Total/NA Water 8260 SIM LCS 680-770731/3 Lab Control Sample Total/NA Water 8260 SIM LCSD 680-770731/4 Lab Control Sample Dup Total/NA Water 8260 SIM 752-4652-3 MS 4501-MW8 Total/NA Ground Water 8260 SIM 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 8260 SIM 752-4682-4 MS 4501-MW11 Total/NA Ground Water 8260 SIM 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 8260 SIM GUMS Semi VOA Prep Batch: 769544 Prep Batch a • Prep Batch Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 3510C 752-4652-3 4501-MW8 Total/NA Ground Water 3510C 752-4682-1 4501-MW6 Total/NA Ground Water 3510C 752-4682-2 4501-MW7 Total/NA Ground Water 3510C MB 680-769544/1-A Method Blank Total/NA Water 3510C Eurofins Raleigh Page 165 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills GC/MS Semi VOA (Continued) Prep Batch: 769544 (Continued) Lab Sample ID Client Sample ID LCS 680-769544/2-A Lab Control Sample 752-4652-3 MS 4501-MW8 752-4652-3 MSD 4501-MW8 Analysis Batch: 769649 Lab Sample ID Client Sample ID 752-4652-2 4501-MW5(Background) 752-4652-3 4501-MW8 752-4682-1 4501-M W6 752-4682-2 4501-MW7 MB 680-769544/1-A Method Blank LCS 680-769544/2-A Lab Control Sample 752-4652-3 MS 4501-MW8 752-4652-3 MSD 4501-MW8 Prep Batch: 769804 Lab Sample ID Client Sample ID 752-4749-1 4501-Field Blank MB 680-769804/1-A Method Blank LCS 680-769804/2-A Lab Control Sample LCSD 680-769804/3-A Lab Control Sample Dup Analysis Batch: 769934 Prep Type Matrix Total/NA Water Total/NA Ground Water Total/NA Ground Water Prep Type Matrix Total/NA Ground Water Total/NA Ground Water Total/NA Ground Water Total/NA Ground Water Total/NA Water Total/NA Water Total/NA Ground Water Total/NA Ground Water Prep Type Matrix Total/NA Water Total/NA Water Total/NA Water Total/NA Water Method 3510C 3510C 3510C Method 8270D 8270D 8270D 8270D 8270D 8270D 8270D 8270D Method 3510C 3510C 3510C 3510C Job ID: 752-4652-1 Prep Batch Prep Batch 769544 769544 769544 769544 769544 769544 769544 769544 Prep Batch Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4749-1 4501-Field Blank Total/NA Water 8270D 769804 MB 680-769804/1-A Method Blank Total/NA Water 8270D 769804 LCS 680-769804/2-A Lab Control Sample Total/NA Water 8270D 769804 LCSD 680-769804/3-A Lab Control Sample Dup Total/NA Water 8270D 769804 GC VOA Analysis Batch: 189739 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water RSK-175 752-4652-2 4501-MW5 (Background) Total/NA Ground Water RSK-175 752-4652-3 4501-MW8 Total/NA Ground Water RSK-175 MB 200-189739/28 Method Blank Total/NA Water RSK-175 LCS 200-189739/26 Lab Control Sample Total/NA Water RSK-175 LCSD 200-189739/27 Lab Control Sample Dup Total/NA Water RSK-175 752-4652-3 MS 4501-MW8 Total/NA Ground Water RSK-175 752-4652-3 MSD 4501-MW8 Total/NA Ground Water RSK-175 Analysis Batch: 189761 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-3 - DL 4501-MW8 Total/NA Ground Water RSK-175 752-4682-1 4501-MW6 Total/NA Ground Water RSK-175 752-4682-2 4501-MW7 Total/NA Ground Water RSK-175 752-4682-7 4501-Old MW2 Total/NA Ground Water RSK-175 752-4748-1 4501-AMW2S Total/NA Ground Water RSK-175 MB 200-189761/4 Method Blank Total/NA Water RSK-175 LCS 200-189761/2 Lab Control Sample Total/NA Water RSK-175 Eurofins Raleigh Page 166 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills GC VOA (Continued) Analysis Batch: 189761 (Continued) Job ID: 752-4652-1 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch LCSD 200-189761/3 Lab Control Sample Dup Total/NA Water RSK-175 752-4652-3 MS - DL 4501-MW8 Total/NA Ground Water RSK-175 752-4652-3 MSD - DL 4501-MW8 Total/NA Ground Water RSK-175 Analysis Batch: 189814 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-7 - DL 4501-Old MW2 Total/NA Ground Water RSK-175 MB 200-189814/4 Method Blank Total/NA Water RSK-175 LCS 200-189814/2 Lab Control Sample Total/NA Water RSK-175 LCSD 200-189814/3 Lab Control Sample Dup Total/NA Water RSK-175 Analysis Batch: 189816 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water RSK-175 752-4652-2 4501-MW5 (Background) Total/NA Ground Water RSK-175 752-4652-3 4501-MW8 Total/NA Ground Water RSK-175 752-4682-1 4501-MW6 Total/NA Ground Water RSK-175 752-4682-2 4501-MW7 Total/NA Ground Water RSK-175 752-4682-7 4501-Old MW2 Total/NA Ground Water RSK-175 MB 200-189816/3 Method Blank Total/NA Water RSK-175 LCS 200-189816/2 Lab Control Sample Total/NA Water RSK-175 752-4652-3 MS 4501-MW8 Total/NA Ground Water RSK-175 752-4652-3 MSD 4501-MW8 Total/NA Ground Water RSK-175 Analysis Batch: 189906 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water RSK-175 MB 200-189906/3 Method Blank Total/NA Water RSK-175 LCS 200-189906/2 Lab Control Sample Total/NA Water RSK-175 LCSD 200-189906/22 Lab Control Sample Dup Total/NA Water RSK-175 GC Semi VOA Prep Batch: 769190 Lab Sample ID Client Sample ID 752-4652-2 4501-MW5(Background) 752-4652-3 4501-MW8 MB 680-769190/1-A Method Blank LCS 680-769190/2-A Lab Control Sample 752-4652-3 MS 4501-MW8 752-4652-3 MSD 4501-MW8 Prep Batch: 769227 Lab Sample ID Client Sample ID 752-4652-2 4501-MW5(Background) 752-4652-3 4501-MW8 MB 680-769227/1-A Method Blank LCS 680-769227/2-A Lab Control Sample LCS 680-769227/5-A Lab Control Sample 752-4652-3 MS 4501-MW8 752-4652-3 MS 4501-MW8 Prep Type Matrix Method Total/NA Ground Water 8151A Total/NA Ground Water 8151A Total/NA Water 8151A Total/NA Water 8151A Total/NA Ground Water 8151A Total/NA Ground Water 8151A Prep Type Matrix Method Total/NA Ground Water 3510C Total/NA Ground Water 3510C Total/NA Water 3510C Total/NA Water 3510C Total/NA Water 3510C Total/NA Ground Water 3510C Total/NA Ground Water 3510C Prep Batch Prep Batch 0 Eurofins Raleigh Page 167 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills GC Semi VOA (Continued) Prep Batch: 769227 (Continued) Lab Sample ID Client Sample ID 752-4652-3 MSD 4501-MW8 752-4652-3 MSD 4501-MW8 Analysis Batch: 769499 Job ID: 752-4652-1 Prep Type Matrix Method Prep Batch Total/NA Ground Water 3510C Total/NA Ground Water 3510C Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 8081B 769227 752-4652-3 4501-MW8 Total/NA Ground Water 8081B 769227 MB 680-769227/1-A Method Blank Total/NA Water 8081B 769227 LCS 680-769227/2-A Lab Control Sample Total/NA Water 8081B 769227 752-4652-3 MS 4501-MW8 Total/NA Ground Water 8081B 769227 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 8081B 769227 Analysis Batch: 769502 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 8082A 769227 752-4652-3 4501-MW8 Total/NA Ground Water 8082A 769227 MB 680-769227/1-A Method Blank Total/NA Water 8082A 769227 LCS 680-769227/5-A Lab Control Sample Total/NA Water 8082A 769227 752-4652-3 MS 4501-MW8 Total/NA Ground Water 8082A 769227 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 8082A 769227 Prep Batch: 769585 Lab Sample ID Client Sample ID MB 680-769585/1-A Method Blank LCS 680-769585/2-A Lab Control Sample LCS 680-769585/5-A Lab Control Sample LCSD 680-769585/6-A Lab Control Sample Dup Prep Batch: 769824 Lab Sample ID 752-4682-1 752-4682-2 752-4682-3 752-4682-4 752-4682-5 752-4682-6 752-4749-1 MB 680-769824/1-A LCS 680-769824/2-A 752-4682-4 MS 752-4682-4 MSD Analysis Batch: 769834 Lab Sample ID 752-4682-1 752-4682-1 752-4682-2 752-4682-2 MB 680-769585/1-A LCS 680-769585/2-A LCS 680-769585/5-A Prep Type Matrix Method Prep Batch Total/NA Water 3510C Total/NA Water 3510C Total/NA Water 3510C Total/NA Water 3510C Client Sample ID Prep Type Matrix Method 4501-MW6 Total/NA Ground Water 8151A 4501-MW7 Total/NA Ground Water 8151A 4501-MW10 Total/NA Ground Water 8151A 4501-MW11 Total/NA Ground Water 8151A 4501-MW12 Total/NA Ground Water 8151A 4501-MW13 Total/NA Ground Water 8151A 4501-Field Blank Total/NA Water 8151A Method Blank Total/NA Water 8151A Lab Control Sample Total/NA Water 8151A 4501-MW11 Total/NA Ground Water 8151A 4501-MW11 Total/NA Ground Water 8151A Client Sample ID Prep Type Matrix Method 4501-MW6 Total/NA Ground Water 8081B 4501-MW6 Total/NA Ground Water 8082A 4501-MW7 Total/NA Ground Water 8081B 4501-MW7 Total/NA Ground Water 8082A Method Blank Total/NA Water 8081 B Lab Control Sample Total/NA Water 8081 B Lab Control Sample Total/NA Water 8081 B Prep Batch Prep Batch 769585 769585 769585 Page 168 of 242 Eurofins Raleigh 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills GC Semi VOA (Continued) Analysis Batch: 769834 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch LCSD 680-769585/6-A Lab Control Sample Dup Total/NA Water 8081B 769585 Analysis Batch: 769950 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 8151A 769190 752-4652-3 4501-MW8 Total/NA Ground Water 8151A 769190 MB 680-769190/1-A Method Blank Total/NA Water 8151A 769190 LCS 680-769190/2-A Lab Control Sample Total/NA Water 8151A 769190 752-4652-3 MS 4501-MW8 Total/NA Ground Water 8151A 769190 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 8151A 769190 Prep Batch: 770015 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch MB 680-770015/1-A Method Blank Total/NA Water 3510C LCS 680-770015/2-A Lab Control Sample Total/NA Water 3510C LCS 680-770015/4-A Lab Control Sample Total/NA Water 3510C LCSD 680-770015/3-A Lab Control Sample Dup Total/NA Water 3510C LCSD 680-770015/5-A Lab Control Sample Dup Total/NA Water 3510C Analysis Batch: 770343 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 8151A 769824 752-4682-2 4501-MW7 Total/NA Ground Water 8151A 769824 752-4682-3 4501-MW10 Total/NA Ground Water 8151A 769824 752-4682-4 4501-MW11 Total/NA Ground Water 8151A 769824 752-4682-5 4501-MW12 Total/NA Ground Water 8151A 769824 752-4682-6 4501-MW13 Total/NA Ground Water 8151A 769824 752-4749-1 4501-Field Blank Total/NA Water 8151A 769824 MB 680-769824/1-A Method Blank Total/NA Water 8151A 769824 LCS 680-769824/2-A Lab Control Sample Total/NA Water 8151A 769824 752-4682-4 MS 4501-MW11 Total/NA Ground Water 8151A 769824 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 8151A 769824 Analysis Batch: 770371 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4749-1 4501-Field Blank Total/NA Water 8081E 752-4749-1 4501-Field Blank Total/NA Water 8082A MB 680-770015/1-A Method Blank Total/NA Water 8081E 770015 LCS 680-770015/2-A Lab Control Sample Total/NA Water 8081B 770015 LCS 680-770015/4-A Lab Control Sample Total/NA Water 8081B 770015 LCSD 680-770015/3-A Lab Control Sample Dup Total/NA Water 8081B 770015 LCSD 680-770015/5-A Lab Control Sample Dup Total/NA Water 8081E 770015 HPLCAC Analysis Batch: 28303 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water VFA-HPLC 752-4652-2 4501-MW5 (Background) Total/NA Ground Water VFA-HPLC 752-4652-3 4501-MW8 Total/NA Ground Water VFA-HPLC 752-4682-1 4501-MW6 Total/NA Ground Water VFA-HPLC Eurofins Raleigh Page 169 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills HPLCAC (Continued) Analysis Batch: 28303 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-2 4501-MW7 Total/NA Ground Water VFA-HPLC 752-4682-7 4501-Old MW2 Total/NA Ground Water VFA-HPLC 752-4748-1 4501-AMW2S Total/NA Ground Water VFA-HPLC MB 670-28303/5 Method Blank Total/NA Water VFA-HPLC LCS 670-28303/3 Lab Control Sample Total/NA Water VFA-HPLC LCSD 670-28303/4 Lab Control Sample Dup Total/NA Water VFA-HPLC 752-4652-3 MS 4501-MW8 Total/NA Ground Water VFA-HPLC 752-4652-3 MSD 4501-MW8 Total/NA Ground Water VFA-HPLC Analysis Batch: 771548 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 300.0-1993 R2.1 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 300.0-1993 R2.1 752-4652-3 4501-MW8 Total/NA Ground Water 300.0-1993 R2.1 752-4682-1 4501-MW6 Total/NA Ground Water 300.0-1993 R2.1 752-4682-2 4501-MW7 Total/NA Ground Water 300.0-1993 R2.1 752-4682-3 4501-MW10 Total/NA Ground Water 300.0-1993 R2.1 752-4682-4 4501-MW11 Total/NA Ground Water 300.0-1993 R2.1 MB 680-771548/1015 Method Blank Total/NA Water 300.0-1993 R2.1 LCS 680-771548/16 Lab Control Sample Total/NA Water 300.0-1993 R2.1 LCSD 680-771548/17 Lab Control Sample Dup Total/NA Water 300.0-1993 R2.1 752-4652-3 MS 4501-MW8 Total/NA Ground Water 300.0-1993 R2.1 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 300.0-1993 R2.1 752-4682-4 MS 4501-MW11 Total/NA Ground Water 300.0-1993 R2.1 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 300.0-1993 R2.1 Analysis Batch: 772611 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 300.0-1993 R2.1 752-4682-2 4501-MW7 Total/NA Ground Water 300.0-1993 R2.1 752-4682-3 4501-MW10 Total/NA Ground Water 300.0-1993 R2.1 752-4682-5 4501-MW12 Total/NA Ground Water 300.0-1993 R2.1 752-4682-6 4501-MW13 Total/NA Ground Water 300.0-1993 R2.1 752-4682-7 4501-Old MW2 Total/NA Ground Water 300.0-1993 R2.1 MB 680-772611/1013 Method Blank Total/NA Water 300.0-1993 R2.1 LCS 680-772611/14 Lab Control Sample Total/NA Water 300.0-1993 R2.1 LCSD 680-772611/15 Lab Control Sample Dup Total/NA Water 300.0-1993 R2.1 752-4682-6 MS 4501-MW13 Total/NA Ground Water 300.0-1993 R2.1 752-4682-6 MSD 4501-MW13 Total/NA Ground Water 300.0-1993 R2.1 Analysis Batch: 773150 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 300.0-1993 R2.1 MB 680-773150/1012 Method Blank Total/NA Water 300.0-1993 R2.1 LCS 680-773150/13 Lab Control Sample Total/NA Water 300.0-1993 R2.1 LCSD 680-773150/14 Lab Control Sample Dup Total/NA Water 300.0-1993 R2.1 Eurofins Raleigh Page 170 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Metals Prep Batch: 769164 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total Recoverable Ground Water 3005A 752-4652-3 4501-MW8 Total Recoverable Ground Water 3005A MB 680-769164/1-A Method Blank Total Recoverable Water 3005A LCS 680-769164/2-A Lab Control Sample Total Recoverable Water 3005A 752-4652-3 MS 4501-MW8 Total Recoverable Ground Water 3005A 752-4652-3 MSD 4501-MW8 Total Recoverable Ground Water 3005A Prep Batch: 769166 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4652-2 4501-MW5 (Background) Total Recoverable Ground Water 3005A 752-4652-3 4501-MW8 Total Recoverable Ground Water 3005A MB 680-769166/1-A Method Blank Total Recoverable Water 3005A LCS 680-769166/2-A Lab Control Sample Total Recoverable Water 3005A 752-4652-3 MS 4501-MW8 Total Recoverable Ground Water 3005A 752-4652-3 MSD 4501-MW8 Total Recoverable Ground Water 3005A Prep Batch: 769300 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 7470A 752-4652-3 4501-MW8 Total/NA Ground Water 7470A MB 680-769300/1-A Method Blank Total/NA Water 7470A LCS 680-769300/2-A Lab Control Sample Total/NA Water 7470A 752-4652-3 MS 4501-MW8 Total/NA Ground Water 7470A 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 7470A Prep Batch: 769390 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4682-1 4501-MW6 Total Recoverable Ground Water 3005A 752-4682-2 4501-MW7 Total Recoverable Ground Water 3005A 752-4682-3 4501-MW10 Total Recoverable Ground Water 3005A 752-4682-4 4501-MW11 Total Recoverable Ground Water 3005A 752-4682-5 4501-MW12 Total Recoverable Ground Water 3005A 752-4682-6 4501-MW13 Total Recoverable Ground Water 3005A MB 680-769390/1-A Method Blank Total Recoverable Water 3005A LCS 680-769390/2-A Lab Control Sample Total Recoverable Water 3005A 752-4682-4 MS 4501-MW11 Total Recoverable Ground Water 3005A 752-4682-4 MSD 4501-MW11 Total Recoverable Ground Water 3005A Prep Batch: 769391 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4682-1 4501-MW6 Total Recoverable Ground Water 3005A 752-4682-2 4501-MW7 Total Recoverable Ground Water 3005A 752-4682-3 4501-MW10 Total Recoverable Ground Water 3005A 752-4682-4 4501-MW11 Total Recoverable Ground Water 3005A 752-4682-5 4501-MW12 Total Recoverable Ground Water 3005A 752-4682-6 4501-MW13 Total Recoverable Ground Water 3005A MB 680-769391/1-A Method Blank Total Recoverable Water 3005A LCS 680-769391/2-A Lab Control Sample Total Recoverable Water 3005A 752-4682-4 MS 4501-MW11 Total Recoverable Ground Water 3005A 752-4682-4 MSD 4501-MW11 Total Recoverable Ground Water 3005A Prep Batch a • Prep Batch Prep Batch Prep Batch Eurofins Raleigh Page 171 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Metals Analysis Batch: 769398 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total Recoverable Ground Water 6020B 769166 752-4652-3 4501-MW8 Total Recoverable Ground Water 6020B 769166 MB 680-769166/1-A Method Blank Total Recoverable Water 6020B 769166 LCS 680-769166/2-A Lab Control Sample Total Recoverable Water 6020B 769166 752-4652-3 MS 4501-MW8 Total Recoverable Ground Water 6020B 769166 752-4652-3 MSD 4501-MW8 Total Recoverable Ground Water 6020B 769166 Analysis Batch: 769407 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total Recoverable Ground Water 6010D 769164 752-4652-3 4501-MW8 Total Recoverable Ground Water 6010D 769164 MB 680-769164/1-A Method Blank Total Recoverable Water 6010D 769164 LCS 680-769164/2-A Lab Control Sample Total Recoverable Water 6010D 769164 752-4652-3 MS 4501-MW8 Total Recoverable Ground Water 6010D 769164 752-4652-3 MSD 4501-MW8 Total Recoverable Ground Water 6010D 769164 Prep Batch: 769463 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 7470A 752-4682-2 4501-MW7 Total/NA Ground Water 7470A 752-4682-3 4501-MW10 Total/NA Ground Water 7470A 752-4682-4 4501-MW11 Total/NA Ground Water 7470A 752-4682-5 4501-MW12 Total/NA Ground Water 7470A 752-4682-6 4501-MW13 Total/NA Ground Water 7470A MB 680-769463/1-A Method Blank Total/NA Water 7470A LCS 680-769463/2-A Lab Control Sample Total/NA Water 7470A 752-4682-4 MS 4501-MW11 Total/NA Ground Water 7470A 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 7470A Analysis Batch: 769538 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 7470A 769300 752-4652-3 4501-MW8 Total/NA Ground Water 7470A 769300 MB 680-769300/1-A Method Blank Total/NA Water 7470A 769300 LCS 680-769300/2-A Lab Control Sample Total/NA Water 7470A 769300 752-4652-3 MS 4501-MW8 Total/NA Ground Water 7470A 769300 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 7470A 769300 Prep Batch: 769601 Lab Sample ID Client Sample ID Prep Type Matrix Method 752-4750-1 4501-AMW1D Total Recoverable Ground Water 3005A 752-4750-2 4501-AMW2D Total Recoverable Ground Water 3005A 752-4750-3 4501-BR1 Total Recoverable Surface Water 3005A 752-4750-4 4501-BR2 Total Recoverable Surface Water 3005A 752-4750-5 4501-BR3 Total Recoverable Surface Water 3005A 752-4750-6 4501-SW1 Total Recoverable Surface Water 3005A 752-4750-7 4501-MW9 Total Recoverable Ground Water 3005A MB 680-769601/1-A Method Blank Total Recoverable Water 3005A LCS 680-769601/2-A Lab Control Sample Total Recoverable Water 3005A Prep Batch Eurofins Raleigh Page 172 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Metals Prep Batch: 769602 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4750-1 4501-AMW1D Total Recoverable Ground Water 3005A 752-4750-2 4501-AMW2D Total Recoverable Ground Water 3005A 752-4750-3 4501-BR1 Total Recoverable Surface Water 3005A 752-4750-4 4501-BR2 Total Recoverable Surface Water 3005A 752-4750-5 4501-BR3 Total Recoverable Surface Water 3005A 752-4750-6 4501-SW1 Total Recoverable Surface Water 3005A 752-4750-7 4501-MW9 Total Recoverable Ground Water 3005A MB 680-769602/1-A Method Blank Total Recoverable Water 3005A LCS 680-769602/2-A Lab Control Sample Total Recoverable Water 3005A Prep Batch: 769603 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total Recoverable Ground Water 3005A 752-4749-1 4501-Field Blank Total Recoverable Water 3005A MB 680-769603/1-A Method Blank Total Recoverable Water 3005A LCS 680-769603/2-A Lab Control Sample Total Recoverable Water 3005A Prep Batch: 769604 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total Recoverable Ground Water 3005A 752-4749-1 4501-Field Blank Total Recoverable Water 3005A MB 680-769604/1-A Method Blank Total Recoverable Water 3005A LCS 680-769604/2-A Lab Control Sample Total Recoverable Water 3005A Analysis Batch: 769727 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total Recoverable Ground Water 6010D 769391 752-4682-2 4501-MW7 Total Recoverable Ground Water 6010D 769391 752-4682-3 4501-MW10 Total Recoverable Ground Water 6010D 769391 752-4682-4 4501-MW11 Total Recoverable Ground Water 6010D 769391 752-4682-5 4501-MW12 Total Recoverable Ground Water 6010D 769391 752-4682-6 4501-MW13 Total Recoverable Ground Water 6010D 769391 MB 680-769391/1-A Method Blank Total Recoverable Water 6010D 769391 LCS 680-769391/2-A Lab Control Sample Total Recoverable Water 6010D 769391 752-4682-4 MS 4501-MW11 Total Recoverable Ground Water 6010D 769391 752-4682-4 MSD 4501-MW11 Total Recoverable Ground Water 6010D 769391 Analysis Batch: 769728 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 7470A 769463 752-4682-2 4501-MW7 Total/NA Ground Water 7470A 769463 752-4682-3 4501-MW10 Total/NA Ground Water 7470A 769463 752-4682-4 4501-MW11 Total/NA Ground Water 7470A 769463 752-4682-5 4501-MW12 Total/NA Ground Water 7470A 769463 752-4682-6 4501-MW13 Total/NA Ground Water 7470A 769463 MB 680-769463/1-A Method Blank Total/NA Water 7470A 769463 LCS 680-769463/2-A Lab Control Sample Total/NA Water 7470A 769463 752-4682-4 MS 4501-MW11 Total/NA Ground Water 7470A 769463 752-4682-4 MSD 4501-MW11 Total/NA Ground Water 7470A 769463 0 Eurofins Raleigh Page 173 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Metals Analysis Batch: 769765 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total Recoverable Ground Water 6020B 769390 752-4682-2 4501-MW7 Total Recoverable Ground Water 6020B 769390 752-4682-3 4501-MW10 Total Recoverable Ground Water 6020B 769390 752-4682-4 4501-MW11 Total Recoverable Ground Water 6020B 769390 752-4682-5 4501-MW12 Total Recoverable Ground Water 6020B 769390 752-4682-6 4501-MW13 Total Recoverable Ground Water 6020B 769390 MB 680-769390/1-A Method Blank Total Recoverable Water 6020B 769390 LCS 680-769390/2-A Lab Control Sample Total Recoverable Water 6020B 769390 752-4682-4 MS 4501-MW11 Total Recoverable Ground Water 6020B 769390 752-4682-4 MSD 4501-MW11 Total Recoverable Ground Water 6020B 769390 Prep Batch: 769876 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 7470A 752-4750-1 4501-AMW1D Total/NA Ground Water 7470A 752-4750-2 4501-AMW2D Total/NA Ground Water 7470A MB 680-769876/1-A Method Blank Total/NA Water 7470A LCS 680-769876/2-A Lab Control Sample Total/NA Water 7470A Analysis Batch: 769965 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total Recoverable Ground Water 6010D 769603 752-4749-1 4501-Field Blank Total Recoverable Water 6010D 769603 752-4750-1 4501-AMW1D Total Recoverable Ground Water 6010D 769602 752-4750-2 4501-AMW2D Total Recoverable Ground Water 6010D 769602 752-4750-3 4501-BR1 Total Recoverable Surface Water 6010D 769602 752-4750-4 4501-BR2 Total Recoverable Surface Water 6010D 769602 752-4750-5 4501-BR3 Total Recoverable Surface Water 6010D 769602 752-4750-6 4501-SW1 Total Recoverable Surface Water 6010D 769602 752-4750-7 4501-MW9 Total Recoverable Ground Water 6010D 769602 MB 680-769602/1-A Method Blank Total Recoverable Water 6010D 769602 MB 680-769603/1-A Method Blank Total Recoverable Water 6010D 769603 LCS 680-769602/2-A Lab Control Sample Total Recoverable Water 6010D 769602 LCS 680-769603/2-A Lab Control Sample Total Recoverable Water 6010D 769603 Analysis Batch: 769972 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total Recoverable Ground Water 6020E 769604 752-4749-1 4501-Field Blank Total Recoverable Water 6020E 769604 752-4750-1 4501-AMW1D Total Recoverable Ground Water 6020E 769601 752-4750-2 4501-AMW2D Total Recoverable Ground Water 6020B 769601 752-4750-3 4501-BR1 Total Recoverable Surface Water 6020B 769601 752-4750-4 4501-BR2 Total Recoverable Surface Water 6020B 769601 752-4750-5 4501-BR3 Total Recoverable Surface Water 6020B 769601 752-4750-6 4501-SW1 Total Recoverable Surface Water 6020B 769601 752-4750-7 4501-MW9 Total Recoverable Ground Water 6020B 769601 MB 680-769601/1-A Method Blank Total Recoverable Water 6020E 769601 MB 680-769604/1-A Method Blank Total Recoverable Water 6020E 769604 LCS 680-769601/2-A Lab Control Sample Total Recoverable Water 6020E 769601 LCS 680-769604/2-A Lab Control Sample Total Recoverable Water 6020B 769604 Eurofins Raleigh Page 174 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Metals Analysis Batch: 770099 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 7470A 769876 752-4750-1 4501-AMW1D Total/NA Ground Water 7470A 769876 752-4750-2 4501-AMW2D Total/NA Ground Water 7470A 769876 MB 680-769876/1-A Method Blank Total/NA Water 7470A 769876 LCS 680-769876/2-A Lab Control Sample Total/NA Water 7470A 769876 Prep Batch: 770494 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4749-1 4501-Field Blank Total/NA Water 7470A MB 680-770494/1-A Method Blank Total/NA Water 7470A LCS 680-770494/2-A Lab Control Sample Total/NA Water 7470A Analysis Batch: 770613 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4749-1 4501-Field Blank Total/NA Water 7470A 770494 MB 680-770494/1-A Method Blank Total/NA Water 7470A 770494 LCS 680-770494/2-A Lab Control Sample Total/NA Water 7470A 770494 Prep Batch: 770750 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total Recoverable Ground Water 3005A MB 680-770750/1-A Method Blank Total Recoverable Water 3005A LCS 680-770750/2-A Lab Control Sample Total Recoverable Water 3005A Prep Batch: 770757 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total Recoverable Ground Water 3005A MB 680-770757/1-A Method Blank Total Recoverable Water 3005A LCS 680-770757/2-A Lab Control Sample Total Recoverable Water 3005A Analysis Batch: 770885 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total Recoverable Ground Water 6010D 770757 MB 680-770757/1-A Method Blank Total Recoverable Water 6010D 770757 LCS 680-770757/2-A Lab Control Sample Total Recoverable Water 6010D 770757 Prep Batch: 771058 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 7470A MB 680-771058/1-A Method Blank Total/NA Water 7470A LCS 680-771058/2-A Lab Control Sample Total/NA Water 7470A Analysis Batch: 771193 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total Recoverable Ground Water 6020B 770750 MB 680-770750/1-A Method Blank Total Recoverable Water 6020B 770750 LCS 680-770750/2-A Lab Control Sample Total Recoverable Water 6020B 770750 Analysis Batch: 771251 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 7470A 771058 0 Eurofins Raleigh Page 175 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Metals (Continued) Analysis Batch: 771251 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch MB 680-771058/1-A Method Blank Total/NA Water 7470A 771058 LCS 680-771058/2-A Lab Control Sample Total/NA Water 7470A 771058 General Chemistry Analysis Batch: 1893 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water SM 5220D 752-4652-2 4501-MW5 (Background) Total/NA Ground Water SM 5220D 752-4652-3 4501-MW8 Total/NA Ground Water SM 5220D MB 752-1893/2 Method Blank Total/NA Water SM 5220D LCS 752-1893/4 Lab Control Sample Total/NA Water SM 5220D 752-4652-3 MS 4501-MW8 Total/NA Ground Water SM 5220D 752-4652-3 MSD 4501-MW8 Total/NA Ground Water SM 5220D Analysis Batch: 1925 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water SM 5210B 752-4652-2 4501-MW5 (Background) Total/NA Ground Water SM 5210B 752-4652-3 4501-MW8 Total/NA Ground Water SM 5210B SCB 752-1925/2 Method Blank Total/NA Water SM 5210B USB 752-1925/1 Method Blank Total/NA Water SM 5210B LCS 752-1925/3 Lab Control Sample Total/NA Water SM 5210B 752-4652-3 DU 4501-MW8 Total/NA Ground Water SM 5210B Analysis Batch: 1928 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-3 4501-MW10 Total/NA Ground Water SM 2540C MB 752-1928/1 Method Blank Total/NA Water SM 2540C LCS 752-1928/2 Lab Control Sample Total/NA Water SM 2540C Analysis Batch: 1929 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water SM 5210B 752-4682-2 4501-MW7 Total/NA Ground Water SM 5210B 752-4682-7 4501-Old MW2 Total/NA Ground Water SM 5210B SCB 752-1929/2 Method Blank Total/NA Water SM 5210B USB 752-1929/1 Method Blank Total/NA Water SM 5210B LCS 752-1929/3 Lab Control Sample Total/NA Water SM 5210B Analysis Batch: 1940 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-4 4501-MW11 Total/NA Ground Water SM 2540C 752-4682-5 4501-MW12 Total/NA Ground Water SM 2540C 752-4682-6 4501-MW13 Total/NA Ground Water SM 2540C MB 752-1940/1 Method Blank Total/NA Water SM 2540C LCS 752-1940/2 Lab Control Sample Total/NA Water SM 2540C LCSD 752-1940/20 Lab Control Sample Dup Total/NA Water SM 2540C 752-4682-4 DU 4501-MW11 Total/NA Ground Water SM 2540C 752-4682-5 DU 4501-MW12 Total/NA Ground Water SM 2540C 0 Eurofins Raleigh Page 176 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills General Chemistry Analysis Batch: 1942 Job ID: 752-4652-1 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water SM 5210B SCB 752-1942/2 Method Blank Total/NA Water SM 5210B USB 752-1942/1 Method Blank Total/NA Water SM 5210B LCS 752-1942/3 Lab Control Sample Total/NA Water SM 5210B Analysis Batch: 1984 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 353.2 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 353.2 752-4652-3 4501-MW8 Total/NA Ground Water 353.2 MB 752-1984/11 Method Blank Total/NA Water 353.2 MB 752-1984/27 Method Blank Total/NA Water 353.2 LCS 752-1984/10 Lab Control Sample Total/NA Water 353.2 LCSD 752-1984/39 Lab Control Sample Dup Total/NA Water 353.2 752-4652-3 MS 4501-MW8 Total/NA Ground Water 353.2 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 353.2 Analysis Batch: 1986 Lab Sample ID Client Sample ID 752-4652-1 4501-AM W 1 S 752-4652-2 4501-MW5(Background) 752-4682-1 4501-MW6 752-4682-2 4501-MW7 752-4682-7 4501-Old MW2 752-4748-1 4501-AMW2S MB 752-1986/10 Method Blank MB 752-1986/39 Method Blank MB 752-1986/73 Method Blank LCS 752-1986/11 Lab Control Sample LCS 752-1986/40 Lab Control Sample LCSD 752-1986/94 Lab Control Sample Dup Analysis Batch: 1993 Lab Sample ID 752-4652-1 752-4652-2 752-4652-3 752-4682-1 752-4682-2 752-4682-7 752-4748-1 Analysis Batch: 2024 Lab Sample ID 752-4682-1 752-4682-2 752-4682-7 752-4748-1 MB 752-2024/2 LCS 752-2024/4 752-4682-1 MS Client Sample ID 4501-AM W 1 S 4501-MW5(Background) 4501-MW8 4501-MW6 4501-MW7 4501-Old MW2 4501-AMW2S Prep Type Matrix Method Prep Batch Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Water 353.2 Total/NA Water 353.2 Total/NA Water 353.2 Total/NA Water 353.2 Total/NA Water 353.2 Total/NA Water 353.2 Prep Type Matrix Method Prep Batch Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Total/NA Ground Water 353.2 Client Sample ID Prep Type Matrix Method 4501-MW6 Total/NA Ground Water SM 5220D 4501-MW7 Total/NA Ground Water SM 5220D 4501-Old MW2 Total/NA Ground Water SM 5220D 4501-AMW2S Total/NA Ground Water SM 5220D Method Blank Total/NA Water SM 5220D Lab Control Sample Total/NA Water SM 5220D 4501-MW6 Total/NA Ground Water SM 5220D Prep Batch 0 Eurofins Raleigh Page 177 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills General Chemistry (Continued) Analysis Batch: 2024 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 MSD 4501-MW6 Total/NA Ground Water SM 5220D Analysis Batch: 2027 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 353.2 752-4682-2 4501-MW7 Total/NA Ground Water 353.2 752-4682-7 4501-Old MW2 Total/NA Ground Water 353.2 MB 752-2027/11 Method Blank Total/NA Water 353.2 MB 752-2027/17 Method Blank Total/NA Water 353.2 LCS 752-2027/10 Lab Control Sample Total/NA Water 353.2 LCSD 752-2027/47 Lab Control Sample Dup Total/NA Water 353.2 Analysis Batch: 2034 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 353.2 MB 752-2034/11 Method Blank Total/NA Water 353.2 MB 752-2034/23 Method Blank Total/NA Water 353.2 LCS 752-2034/10 Lab Control Sample Total/NA Water 353.2 LCSD 752-2034/39 Lab Control Sample Dup Total/NA Water 353.2 Analysis Batch: 2160 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-3 4501-MW8 Total/NA Ground Water 353.2 MB 752-2160/10 Method Blank Total/NA Water 353.2 MB 752-2160/25 Method Blank Total/NA Water 353.2 LCS 752-2160/11 Lab Control Sample Total/NA Water 353.2 LCS 752-2160/26 Lab Control Sample Total/NA Water 353.2 LCSD 752-2160/24 Lab Control Sample Dup Total/NA Water 353.2 752-4652-3 MS 4501-MW8 Total/NA Ground Water 353.2 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 353.2 Analysis Batch: 769240 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 4500 S2 F-2011 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 4500 S2 F-2011 752-4652-3 4501-MW8 Total/NA Ground Water 4500 S2 F-2011 MB 680-769240/1 Method Blank Total/NA Water 4500 S2 F-2011 LCS 680-769240/2 Lab Control Sample Total/NA Water 4500 S2 F-2011 LCSD 680-769240/3 Lab Control Sample Dup Total/NA Water 4500 S2 F-2011 LLCS 680-769240/4 Lab Control Sample Total/NA Water 4500 S2 F-2011 752-4652-3 MS 4501-MW8 Total/NA Ground Water 4500 S2 F-2011 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 4500 S2 F-2011 Analysis Batch: 769471 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 4501-MW6 Total/NA Ground Water 4500 S2 F-2011 752-4682-2 4501-MW7 Total/NA Ground Water 4500 S2 F-2011 752-4682-7 4501-Old MW2 Total/NA Ground Water 4500 S2 F-2011 MB 680-769471/1 Method Blank Total/NA Water 4500 S2 F-2011 LCS 680-769471/2 Lab Control Sample Total/NA Water 4500 S2 F-2011 LCSD 680-769471/3 Lab Control Sample Dup Total/NA Water 4500 S2 F-2011 0 Eurofins Raleigh Page 178 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills General Chemistry (Continued) Analysis Batch: 769471 (Continued) Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4682-1 DU 4501-MW6 Total/NA Ground Water 4500 S2 F-2011 Analysis Batch: 769846 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-1 4501-AMW1S Total/NA Ground Water 2320B-2011 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 2320B-2011 752-4652-3 4501-MW8 Total/NA Ground Water 2320B-2011 752-4682-1 4501-MW6 Total/NA Ground Water 2320B-2011 752-4682-2 4501-MW7 Total/NA Ground Water 2320B-2011 752-4682-3 4501-MW10 Total/NA Ground Water 2320B-2011 752-4682-4 4501-MW11 Total/NA Ground Water 2320B-2011 752-4682-5 4501-MW12 Total/NA Ground Water 2320B-2011 752-4682-6 4501-MW13 Total/NA Ground Water 2320B-2011 752-4682-7 4501-Old MW2 Total/NA Ground Water 2320B-2011 MB 680-769846/4 Method Blank Total/NA Water 2320B-2011 LCS 680-769846/6 Lab Control Sample Total/NA Water 2320B-2011 LCSD 680-769846/31 Lab Control Sample Dup Total/NA Water 2320B-2011 752-4682-3 DU 4501-MW10 Total/NA Ground Water 2320B-2011 Analysis Batch: 770092 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 4500 S2 F-2011 752-4749-1 4501-Field Blank Total/NA Water 4500 S2 F-2011 MB 680-770092/1 Method Blank Total/NA Water 4500 S2 F-2011 LCS 680-770092/2 Lab Control Sample Total/NA Water 4500 S2 F-2011 LCSD 680-770092/3 Lab Control Sample Dup Total/NA Water 4500 S2 F-2011 Analysis Batch: 770280 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4748-1 4501-AMW2S Total/NA Ground Water 2320B-2011 MB 680-770280/4 Method Blank Total/NA Water 2320B-2011 LCS 680-770280/6 Lab Control Sample Total/NA Water 2320B-2011 LCSD 680-770280/31 Lab Control Sample Dup Total/NA Water 2320B-2011 Prep Batch: 770468 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 9012B 752-4652-3 4501-MW8 Total/NA Ground Water 9012B 752-4682-1 4501-MW6 Total/NA Ground Water 9012B 752-4682-2 4501-MW7 Total/NA Ground Water 9012B 752-4749-1 4501-Field Blank Total/NA Water 9012B MB 680-770468/12-A Method Blank Total/NA Water 9012B LCS 680-770468/13-A Lab Control Sample Total/NA Water 9012B 752-4652-3 MS 4501-MW8 Total/NA Ground Water 9012B 752-4652-3 MSD 4501-MW8 Total/NA Ground Water 9012B Analysis Batch: 770561 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 752-4652-2 4501-MW5 (Background) Total/NA Ground Water 9012B 770468 752-4652-3 4501-MW8 Total/NA Ground Water 9012B 770468 752-4682-1 4501-MW6 Total/NA Ground Water 9012B 770468 0 Eurofins Raleigh Page 179 of 242 4/19/2023 QC Association Summary Client: WSP USA Inc Project/Site: Henderson County Landfills General Chemistry (Continued) Analysis Batch: 770561 (Continued) Lab Sample ID Client Sample ID 752-4682-2 4501-MW7 752-4749-1 4501-Field Blank MB 680-770468/12-A Method Blank LCS 680-770468/13-A Lab Control Sample 752-4652-3 MS 4501-MW8 752-4652-3 MSD 4501-MW8 Analysis Batch: 771279 Lab Sample ID Client Sample ID 752-4652-1 4501-AM W 1 S 752-4652-2 4501-MW5(Background) 752-4652-3 4501-MW8 752-4682-1 4501-M W6 752-4682-2 4501-MW7 752-4682-7 4501-Old MW2 752-4748-1 4501-AM W2S MB 680-771279/2 Method Blank LCS 680-771279/3 Lab Control Sample LCSD 680-771279/4 Lab Control Sample Dup 752-4652-3 MS 4501-MW8 752-4652-3 MSD 4501-MW8 Job ID: 752-4652-1 Prep Type Matrix Method Prep Batch Total/NA Ground Water 9012B 770468 Total/NA Water 9012B 770468 Total/NA Water 9012B 770468 Total/NA Water 9012B 770468 Total/NA Ground Water 9012B 770468 Total/NA Ground Water 9012B 770468 Prep Type Matrix Method Prep Batch Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Water 5310 B-2011 Total/NA Water 5310 B-2011 Total/NA Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Total/NA Ground Water 5310 B-2011 Eurofins Raleigh Page 180 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-AMW1S Lab Sample ID: 752-4652-1 Date Collected: 03/20/23 15:54 Matrix: Ground Water Date Received: 03/21/23 09:20 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 14:53 Total/NA Analysis 8260D 1 2053 RY EET ESC 04/01/23 00:36 Total/NA Analysis RSK-175 1 189739 MJZ EET BUR 03/28/23 07:58 Total/NA Analysis RSK-175 1 189816 RMG EET BUR 03/29/23 14:10 Total/NA Analysis 300.0-1993 R2.1 1 771548 GE EET SAV 04/05/23 21:07 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total Recoverable Prep 3005A 770757 RR EET SAV 03/31/23 11:02 Total Recoverable Analysis 6010D 1 770885 BCB EET SAV 03/31/23 19:34 Total Recoverable Prep 3005A 770750 RR EET SAV 03/31/23 11:02 m Total Recoverable Analysis 6020E 1 771193 BJB EET SAV 04/03/23 15:42 Total/NA Prep 7470A 771058 JKL EET SAV 04/03/23 11:03 Total/NA Analysis 7470A 1 771251 JKL EET SAV 04/03/23 18:38 Total/NA Analysis 2320B-2011 1 769846 PG EET SAV 03/25/23 01:04 Total/NA Analysis 353.2 1 1984 ME EET ESC 03/21/23 16:43 Total/NA Analysis 353.2 1 1986 ME EET ESC 03/27/23 12:03 Total/NA Analysis 353.2 1 1993 CB EET ESC 03/29/23 15:40 Total/NA Analysis 4500 S2 F-2011 1 769240 JAS EET SAV 03/23/23 10:41 Total/NA Analysis 5310 B-2011 1 771279 JU EET SAV 04/02/23 03:56 Total/NA Analysis SM 5210B 1 1925 JC EET ESC 03/21/23 15:12 Total/NA Analysis SM 5220D 1 1893 JC EET ESC 03/22/23 17:43 Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770326 RKJ EET SAV 03/29/23 22:15 Total/NA Analysis 8260D 1 2053 RY EET ESC 04/01/23 01:05 Total/NA Prep 3510C 769544 MR EET SAV 03/24/23 14:39 Total/NA Analysis 8270D 1 769649 OK EET SAV 03/25/23 22:10 Total/NA Analysis RSK-175 1 189739 MJZ EET BUR 03/28/23 08:07 Total/NA Analysis RSK-175 1 189816 RMG EET BUR 03/29/23 14:19 Total/NA Prep 3510C 769227 LA EET SAV 03/23/23 10:01 Total/NA Analysis 8081E 1 769499 JCK EET SAV 03/24/2319:59 Total/NA Prep 3510C 769227 LA EET SAV 03/23/23 10:01 Total/NA Analysis 8082A 1 769502 JCK EET SAV 03/24/23 19:59 Total/NA Prep 8151A 769190 KD EET SAV 03/23/23 09:39 Total/NA Analysis 8151A 1 769950 JCK EET SAV 03/28/23 04:41 Total/NA Analysis 300.0-1993 R2.1 1 771548 GE EET SAV 04/05/23 21:20 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total Recoverable Prep 3005A 769164 RR EET SAV 03/23/23 06:57 Total Recoverable Analysis 6010D 1 769407 BJB EET SAV 03/23/23 17:17 Eurofins Raleigh Page 181 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW5 (Background) Lab Sample ID: 752-4652-2 Date Collected: 03/20/23 10:09 Matrix: Ground Water Date Received: 03/21/23 09:20 Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Total Recoverable Prep 3005A 769166 RR Total Recoverable Analysis 6020B 1 769398 BJB Total/NA Prep 7470A 769300 JKL Total/NA Analysis 7470A 1 769538 JKL Total/NA Analysis 2320B-2011 1 769846 PG Total/NA Analysis 353.2 1 1984 ME Total/NA Analysis 353.2 1 1986 ME Total/NA Analysis 353.2 1 1993 CB Total/NA Analysis 4500 S2 F-2011 1 769240 JAS Total/NA Analysis 5310 B-2011 1 771279 JU Total/NA Prep 9012B 770468 JAS Total/NA Analysis 9012B 1 770561 JAS Total/NA Analysis SM 5210B 1 1925 JC Total/NA Analysis SM 5220D 1 1893 JC Client Sample ID: 4501-MW8 Date Collected: 03/20/23 12:15 Date Received: 03/21/23 09:20 Prepared Lab or Analyzed EET SAV 03/23/23 06:57 EET SAV 03/23/23 20:30 EET SAV 03/23/23 13:17 EET SAV 03/23/23 19:11 EET SAV 03/25/23 00:56 EET ESC 03/21/23 16:44 EET ESC 03/27/23 12:08 EET ESC 03/29/23 15:40 EET SAV 03/23/23 10:41 m EET SAV 04/02/23 04:14 EET SAV 03/30/23 08:29 EET SAV 03/30/23 12:28 EET ESC 03/21/23 15:07 EET ESC 03/22/23 17:43 Lab Sample ID: 752-4652-3 Matrix: Ground Water Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 15:20 Total/NA Analysis 8260D 1 2053 RY EET ESC 04/01/23 01:34 Total/NA Prep 3510C 769544 MR EET SAV 03/24/23 14:39 Total/NA Analysis 8270D 1 769649 OK EET SAV 03/25/23 19:36 Total/NA Analysis RSK-175 1 189739 MJZ EET BUR 03/28/23 08:16 Total/NA Analysis RSK-175 DL 2 189761 RMG EET BUR 03/28/23 11:39 Total/NA Analysis RSK-175 1 189816 RMG EET BUR 03/29/23 14:28 Total/NA Prep 3510C 769227 LA EET SAV 03/23/23 10:01 Total/NA Analysis 8081 B 1 769499 JCK EET SAV 03/24/23 20:18 Total/NA Prep 3510C 769227 LA EET SAV 03/23/23 10:01 Total/NA Analysis 8082A 1 769502 JCK EET SAV 03/24/23 20:18 Total/NA Prep 8151A 769190 KD EET SAV 03/23/23 09:39 Total/NA Analysis 8151A 1 769950 JCK EET SAV 03/27/23 22:11 Total/NA Analysis 300.0-1993 R2.1 1 771548 GE EET SAV 04/05/23 17:23 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total Recoverable Prep 3005A 769164 RR EET SAV 03/23/23 06:57 Total Recoverable Analysis 6010D 1 769407 BJB EET SAV 03/23/23 17:08 Total Recoverable Prep 3005A 769166 RR EET SAV 03/23/23 06:57 Total Recoverable Analysis 6020B 1 769398 BJB EET SAV 03/23/23 20:09 Total/NA Prep 7470A 769300 JKL EET SAV 03/23/23 13:17 Total/NA Analysis 7470A 1 769538 JKL EET SAV 03/23/23 19:15 Total/NA Analysis 2320E-2011 1 769846 PG EET SAV 03/25/23 01:18 Total/NA Analysis 353.2 1 1984 ME EET ESC 03/21/23 16:28 Eurofins Raleigh Page 182 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW8 Lab Sample ID: 752-4652-3 Date Collected: 03/20/23 12:15 Matrix: Ground Water Date Received: 03/21/23 09:20 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 353.2 1 1993 CB EET ESC 03/29/23 15:40 Total/NA Analysis 353.2 1 2160 ME EET ESC 04/03/23 13:24 Total/NA Analysis 4500 S2 F-2011 1 769240 JAS EET SAV 03/23/23 10:41 Total/NA Analysis 5310 B-2011 1 771279 JU EET SAV 04/02/23 04:30 Total/NA Prep 9012B 770468 JAS EET SAV 03/30/23 08:29 Total/NA Analysis 9012B 1 770561 JAS EET SAV 03/30/23 12:28 Total/NA Analysis SM 5210B 1 1925 JC EET ESC 03/21/23 14:53 Total/NA Analysis SM 5220D 1 1893 JC EET ESC 03/22/23 17:45 Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 18:02 Total/NA Analysis 8260D 5 2107 RY EET ESC 04/04/23 23:05 Total/NA Prep 3510C 769544 MR EET SAV 03/24/23 14:39 Total/NA Analysis 8270D 1 769649 OK EET SAV 03/25/23 21:26 Total/NA Analysis RSK-175 1 189761 RMG EET BUR 03/28/23 13:25 Total/NA Analysis RSK-175 1 189816 RMG EET BUR 03/29/23 14:54 Total/NA Analysis 8081 B 1 769834 JCK EET SAV 03/27/23 17:28 Total/NA Analysis 8082A 1 769834 JCK EET SAV 03/27/23 17:28 Total/NA Prep 8151A 769824 LA EET SAV 03/27/23 10:41 Total/NA Analysis 8151A 1 770343 JCK EET SAV 03/30/23 00:36 Total/NA Analysis 300.0-1993 R2.1 1 771548 GE EET SAV 04/05/23 21:33 Total/NA Analysis 300.0-1993 R2.1 1 772611 GE EET SAV 04/11/23 17:34 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total Recoverable Prep 3005A 769391 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6010D 1 769727 BCB EET SAV 03/24/23 19:17 Total Recoverable Prep 3005A 769390 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6020B 1 769765 BJB EET SAV 03/24/23 15:56 Total/NA Prep 7470A 769463 JKL EET SAV 03/24/23 10:01 Total/NA Analysis 7470A 1 769728 JKL EET SAV 03/24/23 17:07 Total/NA Analysis 2320E-2011 1 769846 PG EET SAV 03/25/23 03:24 Total/NA Analysis 353.2 1 2027 ME EET ESC 03/22/23 16:07 Total/NA Analysis 353.2 1 1986 ME EET ESC 03/27/23 12:17 Total/NA Analysis 353.2 1 1993 CB EET ESC 03/29/23 15:43 Total/NA Analysis 4500 S2 F-2011 1 769471 JAS EET SAV 03/24/23 10:13 Total/NA Analysis 5310 B-2011 1 771279 JU EET SAV 04/02/23 05:20 Total/NA Prep 9012B 770468 JAS EET SAV 03/30/23 08:29 Total/NA Analysis 9012B 1 770561 JAS EET SAV 03/30/23 12:28 Total/NA Analysis SM 5210B 1 1929 JC EET ESC 03/22/23 17:01 Eurofins Raleigh Page 183 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW6 Lab Sample ID: 752-4682-1 Date Collected: 03/21/23 12:30 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Prep Type Type Method Total/NA Analysis SM 5220D Client Sample ID: 4501-MW7 Date Collected: 03/21/23 15:03 Date Received: 03/22/23 10:00 Batch Batch Prep Type Type Method Total/NA Analysis 8260 SIM Total/NA Analysis 8260D Total/NA Prep 3510C Total/NA Analysis 8270D Total/NA Analysis RSK-175 Total/NA Analysis RSK-175 Total/NA Analysis 8081 B Total/NA Analysis 8082A Total/NA Prep 8151A Total/NA Analysis 8151A Total/NA Analysis 300.0-1993 R2.1 Total/NA Analysis 300.0-1993 R2.1 Total/NA Analysis VFA-HPLC Total Recoverable Prep 3005A Total Recoverable Analysis 6010D Total Recoverable Prep 3005A Total Recoverable Analysis 6020E Total/NA Prep 7470A Total/NA Analysis 7470A Total/NA Analysis 2320B-2011 Total/NA Analysis 353.2 Total/NA Analysis 353.2 Total/NA Analysis 353.2 Total/NA Analysis 4500 S2 F-2011 Total/NA Analysis 5310 B-2011 Total/NA Prep 9012E Total/NA Analysis 9012E Total/NA Analysis SM 5210B Total/NA Analysis SM 5220D Client Sample ID: 4501-MW10 Date Collected: 03/21/23 10:19 Date Received: 03/22/23 10:00 Dilution Run Factor 1 Dilution Run Factor 1 1 1 1 1 1 1 1 1 1 10 1 1 1 1 1 1 1 I Batch Prepared Number Analyst Lab or Analyzed 2024 JC EET ESC 03/30/23 10:08 Batch Number Analyst 770731 RKJ 2107 RY 769544 MR 769649 OK 189761 RMG 189816 RMG 769834 JCK 769834 JCK 769824 LA 770343 JCK 771548 GE 772611 GE 28303 ID 769391 RR 769727 BCB 769390 RR 769765 BJB 769463 JKL 769728 JKL 769846 PG 2027 ME 1986 ME 1993 CB 769471 JAS 771279 JU 770468 JAS 770561 JAS 1929 JC 2024 JC Lab Sample ID: 752-4682-2 Matrix: Ground Water Lab EET SAV EET ESC EET SAV EET SAV EET BUR EET BUR EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET ORL EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET ESC EET ESC EET ESC EET SAV EET SAV EET SAV EET SAV EET ESC EET ESC Prepared or Analyzed 03/31 /23 16:14 04/04/23 20:09 03/24/23 14:39 03/25/23 21:48 03/28/23 13:34 03/29/23 15:03 03/27/23 17:44 03/27/23 17:44 03/27/23 10:41 03/30/23 00:58 04/06/23 09:25 04/11 /23 17:48 03/29/23 19:50 03/24/23 06:33 03/24/23 19:21 03/24/23 06:33 03/24/23 16:00 03/24/23 10:01 03/24/23 17:10 03/25/23 02:33 03/22/23 16:08 03/27/23 12:19 03/29/23 15:43 03/24/23 10:13 04/02/23 05:39 03/30/23 08:29 03/30/23 12:36 03/22/23 17:07 03/30/23 10:08 Lab Sample ID: 752-4682-3 Matrix: Ground Water Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 16:41 Eurofins Raleigh Page 184 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Project/Site: Henderson County Landfills Job ID: 752-4652-1 Client Sample ID: 4501-MW10 Lab Sample ID: 752-4682-3 Date Collected: 03/21/23 10:19 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Prep Type Type Method Total/NA Analysis 8260D Total/NA Prep 8151A Total/NA Analysis 8151A Total/NA Analysis 300.0-1993 R2.1 Total/NA Analysis 300.0-1993 R2.1 Total Recoverable Prep 3005A Total Recoverable Analysis 6010D Total Recoverable Prep 3005A Total Recoverable Analysis 6020E Total/NA Prep 7470A Total/NA Analysis 7470A Total/NA Analysis 2320E-2011 Total/NA Analysis SM 2540C Client Sample ID: 4501-MW11 Date Collected: 03/21/23 15:03 Date Received: 03/22/23 10:00 Dilution Run Factor 1 1 1 1 1 1 1 1 1 Batch Number Analyst 2107 RY 769824 LA 770343 JCK 771548 GE 772611 GE 769391 RR 769727 BCB 769390 RR 769765 BJB 769463 JKL 769728 JKL 769846 PG 1928 CB Lab EET ESC EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET SAV EET ESC Prepared or Analyzed 04/04/23 20:38 03/27/23 10:41 03/30/23 01:20 04/06/23 10:07 04/11 /23 18:01 03/24/23 06:33 03/24/23 19:24 03/24/23 06:33 03/24/23 16:04 03/24/23 10:01 03/24/23 17:19 03/25/23 02:15 03/27/23 10:55 Lab Sample ID: 752-4682-4 C Matrix: Ground Water Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 15:47 Total/NA Analysis 8260D 1 2107 RY EET ESC 04/04/23 21:08 Total/NA Prep 8151A 769824 LA EET SAV 03/27/23 10:41 Total/NA Analysis 8151A 1 770343 JCK EET SAV 03/29/23 22:05 Total/NA Analysis 300.0-1993 R2.1 1 771548 GE EET SAV 04/06/23 10:29 Total Recoverable Prep 3005A 769391 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6010D 1 769727 BCB EET SAV 03/24/23 19:08 Total Recoverable Prep 3005A 769390 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6020E 1 769765 BJB EET SAV 03/24/23 15:44 Total/NA Prep 7470A 769463 JKL EET SAV 03/24/23 10:01 Total/NA Analysis 7470A 1 769728 JKL EET SAV 03/24/23 17:22 Total/NA Analysis 2320B-2011 1 769846 PG EET SAV 03/25/23 03:13 Total/NA Analysis SM 2540C 1 1940 CB EET ESC 03/28/23 10:16 Client Sample ID: 4501-MW12 Date Collected: 03/21/23 13:23 Date Received: 03/22/23 10:00 Lab Sample ID: 752-4682-5 Matrix: Ground Water Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 17:08 Total/NA Analysis 8260D 1 2107 RY EET ESC 04/04/23 21:37 Total/NA Prep 8151A 769824 LA EET SAV 03/27/23 10:41 Total/NA Analysis 8151A 1 770343 JCK EET SAV 03/30/23 01:41 Total/NA Analysis 300.0-1993 R2.1 1 772611 GE EET SAV 04/11/23 18:14 Eurofins Raleigh Page 185 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-MW12 Lab Sample ID: 752-4682-5 Date Collected: 03/21/23 13:23 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total Recoverable Prep 3005A 769391 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6010D 1 769727 BCB EET SAV 03/24/23 19:27 Total Recoverable Prep 3005A 769390 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6020B 1 769765 BJB EET SAV 03/24/23 16:08 Total/NA Prep 7470A 769463 JKL EET SAV 03/24/23 10:01 Total/NA Analysis 7470A 1 769728 JKL EET SAV 03/24/23 17:32 Total/NA Analysis 2320B-2011 1 769846 PG EET SAV 03/25/23 02:43 Total/NA Analysis SM 2540C 1 1940 CB EET ESC 03/28/23 10:16 Client Sample ID: 4501-MW13 Lab Sample ID: 752-4682-6 Date Collected: 03/21/23 12:09 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 17:35 Total/NA Analysis 8260D 1 2107 RY EET ESC 04/04/23 22:06 Total/NA Prep 8151A 769824 LA EET SAV 03/27/23 10:41 Total/NA Analysis 8151A 1 770343 JCK EET SAV 03/30/23 02:02 Total/NA Analysis 300.0-1993 R2.1 1 772611 GE EET SAV 04/11/23 18:53 Total Recoverable Prep 3005A 769391 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6010D 1 769727 BCB EET SAV 03/24/23 19:30 Total Recoverable Prep 3005A 769390 RR EET SAV 03/24/23 06:33 Total Recoverable Analysis 6020E 1 769765 BJB EET SAV 03/24/23 16:12 Total/NA Prep 7470A 769463 JKL EET SAV 03/24/23 10:01 Total/NA Analysis 7470A 1 769728 JKL EET SAV 03/24/23 17:35 Total/NA Analysis 2320B-2011 1 769846 PG EET SAV 03/25/23 02:53 Total/NA Analysis SM 2540C 1 1940 CB EET ESC 03/28/23 10:16 Client Sample ID: 4501-Old MW2 Lab Sample ID: 752-4682-7 Date Collected: 03/21/23 08:29 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260D 1 2107 RY EET ESC 04/04/23 22:36 Total/NA Analysis RSK-175 1 189761 RMG EET BUR 03/28/23 13:43 Total/NA Analysis RSK-175 DL 4 189814 RMG EET BUR 03/29/23 11:59 Total/NA Analysis RSK-175 1 189816 RMG EET BUR 03/29/23 15:12 Total/NA Analysis 300.0-1993 R2.1 1 772611 GE EET SAV 04/11/23 19:33 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total/NA Analysis 2320B-2011 1 769846 PG EET SAV 03/25/23 03:02 Total/NA Analysis 353.2 1 2027 ME EET ESC 03/22/23 16:09 Total/NA Analysis 353.2 1 1986 ME EET ESC 03/27/23 12:21 Total/NA Analysis 353.2 1 1993 CB EET ESC 03/29/23 15:43 Eurofins Raleigh Page 186 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Old MW2 Lab Sample ID: 752-4682-7 Date Collected: 03/21/23 08:29 Matrix: Ground Water Date Received: 03/22/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 4500 S2 F-2011 1 769471 JAS EET SAV 03/24/23 10:13 Total/NA Analysis 5310 B-2011 1 771279 JU EET SAV 04/02/23 05:57 Total/NA Analysis SM 5210B 1 1929 JC EET ESC 03/22/23 17:12 Total/NA Analysis SM 5220D 1 2024 JC EET ESC 03/30/23 10:08 Client Sample ID: 4501-AMW2S Lab Sample ID: 752-4748-1 C Date Collected: 03/22/23 13:22 Matrix: Ground Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared m Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 18:29 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 18:20 Total/NA Analysis RSK-175 1 189761 RMG EET BUR 03/28/23 14:27 Total/NA Analysis RSK-175 1 189906 RMG EET BUR 04/01/23 13:23 Total/NA Analysis 300.0-1993 R2.1 1 773150 GE EET SAV 04/13/23 18:48 Total/NA Analysis VFA-HPLC 10 28303 ID EET ORL 03/29/23 19:50 Total Recoverable Prep 3005A 769603 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/27/23 19:16 Total Recoverable Prep 3005A 769604 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020B 1 769972 BWR EET SAV 03/27/23 17:01 Total/NA Prep 7470A 769876 JKL EET SAV 03/27/23 14:22 Total/NA Analysis 7470A 1 770099 BJB EET SAV 03/28/23 11:52 Total/NA Analysis 2320E-2011 1 770280 PG EET SAV 03/28/23 21:01 Total/NA Analysis 353.2 1 2034 ME EET ESC 03/23/23 16:39 Total/NA Analysis 353.2 1 1986 ME EET ESC 03/27/23 12:59 Total/NA Analysis 353.2 1 1993 CB EET ESC 03/29/23 15:43 Total/NA Analysis 4500 S2 F-2011 1 770092 JAS EET SAV 03/28/23 13:30 Total/NA Analysis 5310 B-2011 1 771279 JU EET SAV 04/02/23 06:14 Total/NA Analysis SM 5210B 1 1942 JC EET ESC 03/23/23 15:54 Total/NA Analysis SM 5220D 1 2024 JC EET ESC 03/30/23 10:08 Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 13:05 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 19:18 Total/NA Prep 3510C 769804 LA EET SAV 03/27/23 08:44 Total/NA Analysis 8270D 1 769934 OK EET SAV 03/27/23 22:41 Total/NA Analysis 8081 B 1 770371 JCK EET SAV 03/30/23 00:24 Total/NA Analysis 8082A 1 770371 JCK EET SAV 03/30/23 00:24 Eurofins Raleigh Page 187 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-Field Blank Lab Sample ID: 752-4749-1 Date Collected: 03/22/23 14:02 Matrix: Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Prep 8151A 769824 LA EET SAV 03/27/23 10:41 Total/NA Analysis 8151A 1 770343 JCK EET SAV 03/29/23 21:43 Total Recoverable Prep 3005A 769603 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/27/23 19:19 Total Recoverable Prep 3005A 769604 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020B 1 769972 BWR EET SAV 03/27/23 17:06 Total/NA Prep 7470A 770494 JKL EET SAV 03/30/23 09:56 Total/NA Analysis 7470A 1 770613 JKL EET SAV 03/30/23 15:49 Total/NA Analysis 4500 S2 F-2011 1 770092 JAS EET SAV 03/28/23 13:30 m Total/NA Prep 9012B 770468 JAS EET SAV 03/30/23 08:30 Total/NA Analysis 9012E 1 770561 JAS EET SAV 03/30/23 12:36 Client Sample ID: 4501-AMW1D Lab Sample ID: 752-4750-1 Date Collected: 03/21/23 10:45 Matrix: Ground Water Date Received: 03/23/23 10:00 Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 18:56 Total/NA Analysis 8260D 1 2066 RY EET ESC 04/03/23 21:31 Total/NA Analysis 8260D 1 2118 RY EET ESC 04/05/23 20:25 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:19 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020E 1 769972 BWR EET SAV 03/27/23 20:13 Total/NA Prep 7470A 769876 JKL EET SAV 03/27/23 14:22 Total/NA Analysis 7470A 1 770099 BJB EET SAV 03/28/23 12:00 Client Sample ID: 4501-AMW2D Lab Sample ID: 752-4750-2 Date Collected: 03/21/23 11:55 Matrix: Ground Water Date Received: 03/23/23 10:00 Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 19:23 Total/NA Analysis 8260D 1 2066 RY EET ESC 04/03/23 22:00 Total/NA Analysis 8260D 1 2118 RY EET ESC 04/05/23 19:56 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:36 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020E 1 769972 BWR EET SAV 03/27/23 20:33 Total/NA Prep 7470A 769876 JKL EET SAV 03/27/23 14:22 Total/NA Analysis 7470A 1 770099 BJB EET SAV 03/28/23 12:02 Eurofins Raleigh Page 188 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Client Sample ID: 4501-BR1 Lab Sample ID: 752-4750-3 Date Collected: 03/22/23 09:57 Matrix: Surface Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 19:50 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 19:47 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:42 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020B 1 769972 BWR EET SAV 03/27/23 20:41 Client Sample ID: 4501-BR2 Lab Sample ID: 752-4750-4 Date Collected: 03/22/23 08:50 Matrix: Surface Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 20:17 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 20:16 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:23 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020B 1 769972 BWR EET SAV 03/27/23 20:17 Client Sample ID: 4501-BR3 Lab Sample ID: 752-4750-5 Date Collected: 03/22/23 10:30 Matrix: Surface Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 20:44 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 20:45 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:32 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020E 1 769972 BWR EET SAV 03/27/23 20:21 Client Sample ID: 4501-SW1 Lab Sample ID: 752-4750-6 Date Collected: 03/22/23 09:15 Matrix: Surface Water Date Received: 03/23/23 10:00 Prep Type Batch Type Batch Method Dilution Run Factor Batch Number Analyst Lab Prepared or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 21:10 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 21:14 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:45 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020E 1 769972 BWR EET SAV 03/27/23 20:45 Eurofins Raleigh Page 189 of 242 4/19/2023 Lab Chronicle Client: WSP USA Inc Project/Site: Henderson County Landfills F Job ID: 752-4652-1 Client Sample ID: 4501-MW9 Lab Sample ID: 752-4750-7 Date Collected: 03/22/23 11:43 Matrix: Ground Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 21:37 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 21:43 Total Recoverable Prep 3005A 769602 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6010D 1 769965 BJB EET SAV 03/28/23 00:39 Total Recoverable Prep 3005A 769601 RR EET SAV 03/25/23 07:48 Total Recoverable Analysis 6020B 1 769972 BWR EET SAV 03/27/23 20:37 Client Sample ID: 4501-Trip Blank Lab Sample ID: 752-4750-8 Date Collected: 03/22/23 08:50 Matrix: Water Date Received: 03/23/23 10:00 Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis 8260 SIM 1 770731 RKJ EET SAV 03/31/23 14:26 Total/NA Analysis 8260D 1 2111 OS EET ESC 04/05/23 17:50 Laboratory References: EET BUR = Eurofins Burlington, 530 Community Drive, Suite 11, South Burlington, VT 05403, TEL (802)660-1990 EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL (919)677-1669 EET ORL = Eurofins Orlando, 481 Newburyport Avenue, Altamonte Springs, FL 32701, TEL (407)339-5984 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Page 190 of 242 Eurofins Raleigh 4/19/2023 Accreditation/Certification Summary C Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Laboratory: Eurofins Raleigh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 591 12-31-23 The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 353.2 Ground Water Nitrate as N Laboratory: Eurofins Burlington All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program ANAB Dept. of Defense ELAP Connecticut State DE Haz. Subst. Cleanup Act (HSCA) State Florida NELAP Minnesota NELAP New Hampshire NELAP New Jersey NELAP New York NELAP Pennsylvania NELAP Rhode Island State US Fish & Wildlife US Federal Programs USDA US Federal Programs Vermont State Virginia NELAP Wisconsin State Identification Number Expiration Date L2336 02-25-26 PH-0751 04-05-23 N/A 05-17-23 E87467 06-30-23 050-999-436 12-31-23 2006 12-18-23 VT972 06-30-23 10391 04-01-24 68-00489 04-30-24 LA000298 12-30-23 058448 07-31-23 P330-17-00272 10-30-23 VT4000 02-10-24 460209 12-14-23 399133350 08-31-23 Laboratory: Eurofins Orlando All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date Alabama State 42800 06-30-23 Florida NELAP E83018 06-30-23 North Carolina (DW) State 12712 07-31-23 Texas NELAP T104704571 02-29-24 Laboratory: Eurofins Savannah Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina (WW/SW) State 269 12-31-23 The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 8270D 3510C Ground Water 1,2,4,5-Tetrachlorobenzene 8270D 3510C Ground Water 2,3,4,6-Tetrachlorophenol 8270D 3510C Ground Water 2,4,5-Trichlorophenol 8270D 3510C Ground Water 2,4,6-Trichlorophenol 8270D 3510C Ground Water 2,4-Dichlorophenol 8270D 3510C Ground Water 2,4-Dimethyl phenol 8270D 3510C Ground Water 2,4-Dinitrophenol Eurofins Raleigh Page 191 of 242 4/19/2023 Accreditation/Certification Summary C Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Laboratory: Eurofins Savannah (Continued) Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date The following analytes are included in this report, but the laboratory is not certified by the governing authority the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 8270D 3510C Ground Water 2,4-Dinitrotoluene 8270D 3510C Ground Water 2,6-Dinitrotoluene 8270D 3510C Ground Water 2-Chloronaphthalene 8270D 3510C Ground Water 2-Chlorophenol 8270D 3510C Ground Water 2-Methylphenol 8270D 3510C Ground Water 2-Nitroaniline 8270D 3510C Ground Water 2-Nitrophenol 8270D 3510C Ground Water 3 & 4 Methylphenol 8270D 3510C Ground Water 3,3'-Dichlorobenzidine 8270D 3510C Ground Water 3-Nitroaniline 8270D 3510C Ground Water 4,6-Dinitro-2-methylphenol 8270D 3510C Ground Water 4-Bromophenyl phenyl ether 8270D 3510C Ground Water 4-Chloro-3-methylphenol 8270D 3510C Ground Water 4-Chloroaniline 8270D 3510C Ground Water 4-Chlorophenyl phenyl ether 8270D 3510C Ground Water 4-Nitroaniline 8270D 3510C Ground Water 4-Nitrophenol 8270D 3510C Ground Water Acenaphthene 8270D 3510C Ground Water Acenaphthylene 8270D 3510C Ground Water Acetophenone 8270D 3510C Ground Water Anthracene 8270D 3510C Ground Water Benzo[a]anthracene 8270D 3510C Ground Water Benzo[a]pyrene 8270D 3510C Ground Water Benzo[b]fluoranthene 8270D 3510C Ground Water Benzo[g,h,i]perylene 8270D 3510C Ground Water Benzo[k]fluoranthene 8270D 3510C Ground Water Benzyl alcohol 8270D 3510C Ground Water bis (2-chloroisopropyl) ether 8270D 3510C Ground Water Bis(2-chloroethoxy)methane 8270D 3510C Ground Water Bis(2-chloroethyl)ether 8270D 3510C Ground Water Bis(2-ethylhexyl) phthalate 8270D 3510C Ground Water Butyl benzyl phthalate 8270D 3510C Ground Water Chrysene 8270D 3510C Ground Water Dibenz(a,h)anthracene 8270D 3510C Ground Water Dibenzofuran 8270D 3510C Ground Water Diethyl phthalate 8270D 3510C Ground Water Di-n-butyl phthalate 8270D 3510C Ground Water Di-n-octyl phthalate 8270D 3510C Ground Water Fluoranthene 8270D 3510C Ground Water Fluorene 8270D 3510C Ground Water Hexachlorobenzene 8270D 3510C Ground Water Hexachlorocyclopentadiene 8270D 3510C Ground Water Hexachloroethane 8270D 3510C Ground Water Indeno[1,2,3-cd]pyrene 8270D 3510C Ground Water Isophorone 8270D 3510C Ground Water Nitrobenzene 8270D 3510C Ground Water N-Nitrosodimethylamine This list may include analytes for which Eurofins Raleigh Page 192 of 242 4/19/2023 Accreditation/Certification Summary C Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Laboratory: Eurofins Savannah (Continued) Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date The following analytes are included in this report, but the laboratory is not certified by the governing authority the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 8270D 3510C Ground Water N-Nitrosodi-n-propylamine 8270D 3510C Ground Water N-Nitrosodiphenylamine 8270D 3510C Ground Water Phenanthrene 8270D 3510C Ground Water Phenol 8270D 3510C Ground Water Pyrene 8270D 3510C Water 1,2,4,5-Tetrachlorobenzene 8270D 3510C Water 2,3,4,6-Tetrachlorophenol 8270D 3510C Water 2,4,5-Trichlorophenol 8270D 3510C Water 2,4,6-Trichlorophenol 8270D 3510C Water 2,4-Dichlorophenol 8270D 3510C Water 2,4-Dimethylphenol 8270D 3510C Water 2,4-Dinitrophenol 8270D 3510C Water 2,4-Dinitrotoluene 8270D 3510C Water 2,6-Dinitrotoluene 8270D 3510C Water 2-Chloronaphthalene 8270D 3510C Water 2-Chlorophenol 8270D 3510C Water 2-Methylphenol 8270D 3510C Water 2-Nitroaniline 8270D 3510C Water 2-Nitrophenol 8270D 3510C Water 3 & 4 Methylphenol 8270D 3510C Water 3,3'-Dichlorobenzidine 8270D 3510C Water 3-Nitroaniline 8270D 3510C Water 4,6-Dinitro-2-methylphenol 8270D 3510C Water 4-Bromophenyl phenyl ether 8270D 3510C Water 4-Chloro-3-methylphenol 8270D 3510C Water 4-Chloroaniline 8270D 3510C Water 4-Chlorophenyl phenyl ether 8270D 3510C Water 4-Nitroaniline 8270D 3510C Water 4-Nitrophenol 8270D 3510C Water Acenaphthene 8270D 3510C Water Acenaphthylene 8270D 3510C Water Acetophenone 8270D 3510C Water Anthracene 8270D 3510C Water Benzo[a]anthracene 8270D 3510C Water Benzo[a]pyrene 8270D 3510C Water Benzo[b]fluoranthene 8270D 3510C Water Benzo[g,h,i]perylene 8270D 3510C Water Benzo[k]fluoranthene 8270D 3510C Water Benzyl alcohol 8270D 3510C Water bis (2-chloroisopropyl) ether 8270D 3510C Water Bis(2-chloroethoxy)methane 8270D 3510C Water Bis(2-chloroethyl)ether 8270D 3510C Water Bis(2-ethylhexyl) phthalate 8270D 3510C Water Butyl benzyl phthalate 8270D 3510C Water Chrysene 8270D 3510C Water Dibenz(a,h)anthracene 8270D 3510C Water Dibenzofuran This list may include analytes for which Eurofins Raleigh Page 193 of 242 4/19/2023 Accreditation/Certification Summary C Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Laboratory: Eurofins Savannah (Continued) Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date The following analytes are included in this report, but the laboratory is not certified by the governing authority the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 8270D 3510C Water Diethyl phthalate 8270D 3510C Water Di-n-butyl phthalate 8270D 3510C Water Di-n-octyl phthalate 8270D 3510C Water Fluoranthene 8270D 3510C Water Fluorene 8270D 3510C Water Hexachlorobenzene 8270D 3510C Water Hexachlorocyclopentadiene 8270D 3510C Water Hexachloroethane 8270D 3510C Water Indeno[1,2,3-cd]pyrene 8270D 3510C Water Isophorone 8270D 3510C Water Nitrobenzene 8270D 3510C Water N-N itrosod imethylam ine 8270D 3510C Water N-N itrosod i-n-propylamine 8270D 3510C Water N-N itrosod iphenylam ine 8270D 3510C Water Phenanthrene 8270D 3510C Water Phenol 8270D 3510C Water Pyrene This list may include analytes for which Eurofins Raleigh Page 194 of 242 4/19/2023 Method Summary Client: WSP USA Inc Job ID: 752-4652-1 Project/Site: Henderson County Landfills Method Method Description Protocol Laboratory 8260 SIM 1,4-Dioxane by SIM SW846 EET SAV 8260D Volatile Organic Compounds by GC/MS SW846 EET ESC 8270D Semivolatile Organic Compounds (GC/MS) SW846 EET SAV RSK-175 Dissolved Gases (GC) RSK EET BUR 8081 B Organochlorine Pesticides (GC) SW846 EET SAV 8082A Polychlorinated Biphenyls (PCBs) by Gas Chromatography SW846 EET SAV 8151A Herbicides (GC) SW846 EET SAV 300.0-1993 R2.1 Anions, Ion Chromatography MCAWW EET SAV VFA-HPLC Volatile Fatty Acids (HPLC/UV) Lab SOP EET ORL 6010D Metals (ICP) SW846 EET SAV 6020B Metals (ICP/MS) SW846 EET SAV 7470A Mercury (CVAA) SW846 EET SAV 2320B-2011 Alkalinity, Total SM EET SAV 353.2 Nitrate EPA EET ESC 353.2 Nitrogen, Nitrate -Nitrite EPA EET ESC 353.2 Nitrogen, Nitrite EPA EET ESC 4500 S2 F-2011 Sulfide, Total SM EET SAV 5310 B-2011 Organic Carbon, Total (TOC) SM EET SAV 9012B Cyanide, Total andorAmenable SW846 EET SAV SM 2540C Solids, Total Dissolved (TDS) SM EET ESC SM 5210B BOD, 5-Day SM EET ESC SM 5220D COD SM EET ESC 3005A Preparation, Total Recoverable or Dissolved Metals SW846 EET SAV 3510C Liquid -Liquid Extraction (Separatory Funnel) SW846 EET SAV 5030C Purge and Trap SW846 EET ESC 5030C Purge and Trap SW846 EET SAV 7470A Preparation, Mercury SW846 EET SAV 8151A Extraction (Herbicides) SW846 EET SAV 9012B Cyanide, Total and/orAmenable, Distillation SW846 EET SAV Protocol References: EPA= US Environmental Protection Agency Lab SOP = Laboratory Standard Operating Procedure MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions. RSK = Sample Prep And Calculations For Dissolved Gas Analysis In Water Samples Using A GC Headspace Equilibration Technique, RSKSOP-175, Rev. 0, 8/11/94, USEPA Research Lab SM = "Standard Methods For The Examination Of Water And Wastewater" SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: EET BUR = Eurofins Burlington, 530 Community Drive, Suite 11, South Burlington, VT 05403, TEL (802)660-1990 EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL (919)677-1669 EET ORL = Eurofins Orlando, 481 Newburyport Avenue, Altamonte Springs, FL 32701, TEL (407)339-5984 EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858 Eurofins Raleigh Page 195 of 242 4/19/2023 Client: WSP USA Inc Sample Summary Job ID: 752-4652-1 Project/Site: Henderson County Landfills Lab Sample ID Client Sample ID Matrix Collected Received 752-4652-1 4501-AMW1S Ground Water 03/20/2315:54 03/21/23 09:20 752-4652-2 4501-MW5 (Background) Ground Water 03/20/23 10:09 03/21/23 09:20 752-4652-3 4501-MW8 Ground Water 03/20/23 12:15 03/21/23 09:20 752-4682-1 4501-MW6 Ground Water 03/21/23 12:30 03/22/23 10:00 752-4682-2 4501-MW7 Ground Water 03/21/23 15:03 03/22/23 10:00 752-4682-3 4501-MW10 Ground Water 03/21/23 10:19 03/22/23 10:00 752-4682-4 4501-MW11 Ground Water 03/21/23 15:03 03/22/23 10:00 752-4682-5 4501-MW12 Ground Water 03/21/23 13:23 03/22/23 10:00 752-4682-6 4501-MW13 Ground Water 03/21/23 12:09 03/22/23 10:00 752-4682-7 4501-Old MW2 Ground Water 03/21/23 08:29 03/22/23 10:00 752-4748-1 4501-AMW2S Ground Water 03/22/23 13:22 03/23/23 10:00 752-4749-1 4501-Field Blank Water 03/22/23 14:02 03/23/23 10:00 752-4750-1 4501-AMW1D Ground Water 03/21/23 10:45 03/23/23 10:00 752-4750-2 4501-AMW2D Ground Water 03/21/23 11:55 03/23/23 10:00 752-4750-3 4501-BR1 Surface Water 03/22/23 09:57 03/23/23 10:00 752-4750-4 4501-BR2 Surface Water 03/22/23 08:50 03/23/23 10:00 752-4750-5 4501-BR3 Surface Water 03/22/23 10:30 03/23/23 10:00 752-4750-6 4501-SW1 Surface Water 03/22/23 09:15 03/23/23 10:00 752-4750-7 4501-MW9 Ground Water 03/22/23 11:43 03/23/23 10:00 752-4750-8 4501-Trip Blank Water 03/22/23 08:50 03/23/23 10:00 Page 196 of 242 Eurofin!04403 U O L 0 O T v N C O 4 O ON 9 O g N � p N N ON x N co CO cp Z m d d =Z¢Z22=1-0 alb o m E m E m E 0�zOo_Otrwr»3YN G O L) U U V Q j~S O YU'V v U ; v 4S� r U = O U O= V O >N Q L�e l •f '. 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N N to Z 7 m J° 0 ti w CD E L o c ° ° in � o m�� m J U >� o? 2G Q v n N n p 2 — v ° o o o N'3 a) m t Ec m U y` w 2 c n w 9a NSiI' X X X X X m Ud m C v O to�iso� sty Hsa x x x x x - z° 4 E " W " it ° Q -.� rn w vmv EQ y (n ON i* $*) (IswiSW(uu"d o � (oN io -,k) old Pa ally Pta! U) m d F c m w E y 3 E E E A C y U U U a o E 0. co V) a N a o t � 4 O. E C C c c w .. N N Y NH.. .t0 mO N mN �N (a `m y W W W W W U m � 0' m v y N C M N M N M N M N m N me `— « a N C) m` ry N a p it 4 N N N N N U �' E E E v m # v O A. m m m m m am- �'� E m E _ t ° O (�v v v vw w m •. o � v U C O J W a C a lC � o N r W.so m c y ;A U 0 ° O Z L N A N N c L (6 U rn 0 ro y�o > > , c - o �W O_ N 0) _ U% co rn a N C/) U U w w C cO J C cc C O m N M IN N W c E C 41 -O N L N (O VITIT (O (0 > O CZ C .. NNN O aoi m c •d (n m m m m°� o =�N N> aQ > E E N � 4N Ya O U o s -a o ' 4w m i u m u °jv«yO oE c (WUI <- nn0 t zoIN cL O W Page 214 of 242 4/19/2023 3/21/23, 5:02 PM FedEx Ship Manager - Print Your Label(s) X O r� Q IT! Z rn v 7 tV N X j w nm H J231023011101uv a O C oC � = ITI O s CO C r_ Z i 77 FIJ i 0 W 0 �+ m (n O C _ oa- Z O Z CO C Z jTC= Tv 1 N m �Cm mzZ G) 581 J7199E'FE2D After printing this label: 1. Use the 'Print button on this page to print your label to your laser or inkjet printer. 2. Fold the printed page along the horizontal line. 3. Place label in shipping pouch and affix it to your shipment so that the barcode portion of the label can be read and scanned. Warning Use only the printed original label for shipping Using a photocopy of this label for shipping purposes is fraudulent and could result in additional billing charges, along with the cancellation of your FedEx account number Use of this system constitutes your agreement to the service conditions in the current FedEx Service Guide, available on fedex.com.FedEx will not be responsible for any claim in excess of $100 per package, whether the result of loss, damage, delay, non-delivery,misdelivery,or misinformation, unless you declare a higher value, pay an additional charge, document your actual loss and file a timely claim.Limitations found in the current FedEx Service Guide apply. Your right to recover from FedEx for any loss, including intrinsic value of the package, loss of sales, income interest, profit, attorney's fees, costs, and other forms of damage whether direct, incidental, consequential, or special is limited to the greater of $100 or the authorized declared value. Recovery cannot exceed actual documented Ioss.Maximum for items of extraordinary value is $1,000, e.g. jewelry, precious metals, negotiable instruments and other items listed in our ServiceGuide. Written claims must be filed within strict time limits, see current FedEx Service Guide. https:/twww.fedex.com/shipping/shipmentConfirmationAction. hand le?method=doContinue Page 215 of 242 1/1 4/19/2023 14 fl v Z 0 m m G d m N Z NN N N(n UU n O $ O N N xz¢zzz2V-¢� MS r o v v '� C E E E N Z OaOtY u�rJ>}N a� E U U U a A Qin N C p Wa w NNc0 rvZ` 1N 0-ue w arm8¢=° WC rnN JSS x0 o>Oz[n U ik ZZm NZa¢ 0 O ¢m U❑ W W (72_� YJ O 1n m - y b _ 0 E = E v Q c m ai o. « E E E w = E w w C ° iL W Q N ❑ ❑ is H o o W J `o rn O` m w o T m° b m 0 N o y 0 E d O. U m N Z 7 a N N $ o O N co O O c m °Ha o � LO ` N' C cv o o N 0 m p W Ew 2 n a a E suHsa x x x m a)� r ZOO XOO9LNSH x x x c N H =o =mZ %w a"j E� d g g ILI: g xca Q � rn m ££ E t� CL °' iuN1C f1$W15NIuuo;ma vi m _ o co a to �8 E (oWjo ,k)Oldmje eMijoIm[j'- a c m E 5n U` LbN u" °i m is m 1Oz c c c 3�0 c. ant E my c U o U U o `o E a v m N E N NN Nap W N O W �m N d A W J C N m co co t m « p v 7L G N N N U 491° o. O .N O N m co f7 in a o v la- a � a` r vNi � F .� E Imo w E 10 0 d ❑ o 0 w � W 8 J a C W N O N .9; N J O° a Z _ w c > C C C N N > J T C i4 e e m e e10i C 1N N oo n` m Eca W D• C N d a) 11E m o m N T nv v a) — CL O Q ._ v P E c�'� o a m FF t o E o c m c ?: m v�i v�i o d N o c'Qj 'v U C)U(b OF ¢�n 6co in> am w a`S yS rn v v a z-O° 4 J 0 W 14 Page 216 of 242 4/19/2023 n�i, 3/22/23, 5 00 PM : FedEx Ship Manager - Print Your Label(s) CO CJI o� —1 '4 W ct� 4 CD 00 00 to C N a X j w n rn �g J231023011101uu M C O 'n Z Cn M z C m Z C) 3y m D ^ I W C r 581 J719982FE20 a o m NCO 0 Dim m w ^' CO N � O O IV m in COW 0 M After printing this label- 1. Use the 'Print' button on this page to print your label to your laser or inkjet printer. 2. Fold the printed page along the horizontal line. 3. Place label in shipping pouch and affix it to your shipment so that the barcode portion of the label can be read and scanned. Warning Use only the printed original label for shipping Using a photocopy of this label for shipping purposes is fraoiduient and could result !n additional billing charges along with the cancellation of your FedEx account number Use of this system constitutes your agreement to the service conditions in the current FedEx Service Guide, available on fedex.com.FedEx will not be responsible for any claim in excess of $100 per package, whether the result of loss, damage, delay, non-delivery,misdelivery,or misinformation, unless you declare a higher value, pay an additional charge, document your actual loss and file a timely claim. Limitations found in the current FedEx Service Guide apply. Your right to recover from FedEx for any loss, including intrinsic value of the package, loss of sales, income interest, profit, attorney's fees, costs, and other forms of damage whether direct, incidental, consequential, or special is limited to the greater of $100 or the authorized declared value. Recovery cannot exceed actual documented Ioss.Maximum for items of extraordinary value is $1,000, e.g. jewelry, precious metals, negotiable instruments and other items listed in our ServiceGuide. Written claims must be filed within strict time limits, see current -FedEx Service Guide. I� �'s'//www.fedex.com/shipping/shipmentConfirmationAction.handle?hktWgd2�""2 T 4/19/2623 z °oc K C ZUNN N Od N U Q,rEiL =z¢zzz SHQ� F= o � V O.� d � 0 m N N zoo i� n�»3rN U) L C E o U E E u o J 0 a, ik N S u ¢ 0 0 0) m a. 2UZNZ21QQ 01 2 — stapFIquoa yO18q N IB401 a E m C) N L a] E E Ov o R E w w m C£ ° y co m w m N 7 N m o LO n z m v) r N In F �+ gvo E U Q Ea o N m o o m 2 2 a a n V r 2 zoo lzo 5G6 NSb X a)) c a ca c 4 Z � o m U E rn v v E (aE cl (ON 1000.0 QSW(SW WiO}iaa (ON JO -A) Old-88 Pa-1a31!-JPIO!d a a c m n m E y a` a« E E `o E a a o m..;m . '--d It U) I Iom- � m � Y N EE m 16 F U) M T W a m m () ..�. to d �x w > _i rc i N O m N m E \V « N v ?k G N (q in m Z• m N W E N o O N vy w f # O O oN O E m �� E E « « « w a a' V F a a` r vOi N >, E o c d p om y � E m o m v U o J w a J d « c w m o m J �O n � ° r^ o V ygF v z W N t; N E L O U) O V ° p - > - c m 0 a ' [ - — o (n Un ((00 N N N .-. ` c c �O ip _ U V1 (9 V V N M ca C� .� N W C 'O "O U p a) ao m o N m N d N C O > _ ° v o.Eo v Q E F w cr C �Z L U J C m O U U) � a n N 0) to `m v y c rn 04 E vU m No 10 u°` v L�,- N 'ao d g Q u u in) c Y > L t? Q N 4 _ a a N w o o L v r a T= o N f a) «E (D o v v o - y O a o N a E - '- UUn a)o-i OF- ¢�n o UUn u) o am w2 NS m N v m zo o c a W 14 Page 218 of 242 4/19/2023 T 1 1 ORIGIN ID SOPA (919} 467-3090 SHIP DATE 23MAR23 RON FERTILE ACTWGT- 22.00 LB ENCO CAD: 2549389/INET4580 102A WOODWINDS INDdSTRIAL CT CARY, NC 27511 BILL SENDER a UNITED STATES US To DON DAWICKI x C I EUROFINS ENV. TESTING AMERICA- BURL � — - . 530 COMMUNITY DRIVE STE 11 SOUTH BURLINGTON VT 05403 51802) 923-1026 REF N PO DEPT III 1111111111101111111111111111111111111111111N I I III 1111111111111 � J i I r II 1� g m Expres • ._ 1 I E I I r '+ cu C _n' L in 4' X W _ w FRI.24 MAR 10:30A , = T0RK0# 7716 4671 5$37 PRIORITY OVERNIGHT 05403 NX BTVA VT-U$ BTV a 0o v �► _. N � e Page 219 of 242 4/19/2023 m z - o n- v� K�Z �5 =Z<Z�z�� 1": « �o o 0 " 2 z0a Oc fn N, d 1, " y o m U o U U a 0 ° C J N zrn O N N co « n o S m �x� S �< Z O¢c0 ��a N N c y m U N m O N - y SzNZ Z�QQ �p W = lL O�n U - r y d U sj8ul uO* jO jNulnN jew.j N N N N [ry c y E = L� w - E E E E o o a E m C z oow E a y c � t F 6 m a d a m O U inZ a O E U) m ir � H 0 sP!�V Aped algeloA /D3Md BIdH VdA X X X X X c y ° Z d a -� u ¢ ¢ ¢ om m c m v m d F (ON,o -A) asymn —vad o a o f y U d f d - a rn ION jo BOA) so-iis pa -um E o - o U o U U O. a m w L y g W -= c �E� huo u n p. � m £ a� O. d C E c dp c�- N c .d c N- -2-2 c m m i v N E ~ 0 y0 � yN m_ m- N yN m� - c N G d a (Q w w w w wCC U N m O a c it 1.- G N N N N N y E 16 Z' E m G N K x o 3 E m io m m m w w m C C o N U A (Ati E fn a O V Fa- a � a u o m U w LL pm O e w 1 U � _ m x u v o m y c N v r o Z m O L LL m J N 'a E L O fn V o' o > a a c C N 3 w ° O —_ ° 2 o y J D a m m m q W O .0 C j J J O .� O In N N m a w f0 O m N Q y ,� >, N Ol O V7 0 e m y G o C > q Oc > w O z C v i C J C w 9 O 0 N N N N o E o A Q Q y? .0 N a� N E N N N < v E L`0 Y o m z O � ¢ •� d N m C C C U L V: p J UW Op ¢c r GQ J yLL 0 a`v E w o N a`S Gl in2 U) v v v v y z v° R N E w ¢ 14 Page 220 of 242 4/19/2023 J1� 0 r c C m Nth p o N N << v N c z o o N N E y c `m a m¢ n c =zaz"z5 �S u 3 m G m o m 0 0 iri zOa Otr rnr»3>iv o m V U V C t m m0 U o — A Q 'm N o °! a a u v L `p N m VOCLco m 6 z � � t o¢_ior 3FQ E" m ❑o .. rn w om m C O O O1 m a m xzNzz�¢a uNi U 818Ul%U09 JO JGquJnN IvWl N N N w o o y ` e u2 m� c R E w E=c E E E t t z R „ o w E a 0 0 0 F R co toJ _ .2 o -� m a ` b m n� T 0 o m o N m O c m N u o ¢ O 10 umi E E 0 U c 0 2 R E w pm V G C u N V O E $ m r -PI-V kled allM-A l33Hd OldH VJA X X X c w .4 Z C K ¢ ¢ V o v o m E-E $ E y16 a (op io RGA) OSWISW WOYad a m a m E (ON im -A) 00-S P-WUd wu i a R E ` C c' c m E u E U E U E U n b E N a RF- u n a d E_m N U(� owv 5 u N m m c M c o mN c d v H m E ~ w� w d m tA° w� N a m rrM m N Q No ik M m N N N N N N _m t �E > 0 E E m m Q u 0 d N O G m N E E v d t in a E d 0 O 0 E 0 o - i U w L w v m w f0 J c 0 a o H o z m w E L 0 C t tm J O o j T a _ c 0-w C_ O 7 rn t3iz _ s N w GO w m « R z E C O r N N E o a R Q O" N 6 C ° O O m N .0 , W a m o rn Eo o m Ea E CU.G n E z �M ?� O N 0 w t E A vM ' _ - o c v c E v o .� E c c U _ o c m 2 �° o av E m v m R u�-, u�i c d �!V U W ¢O CJQ NLL w a`2 in2 fq v a e z°a° m d O W rc ¢ Page 221 of 242 4/19/2023 7 m Eurofil • , ' 102-A Web � trial�ourt Cary, NC 2 Phone 919-677.1689 Chain of Custddy- Record 0 ". I tim eurofins ; I u I'll T'oming Sampler Lab PM Carder Tracking No(s) COC No Client information Sub Contract Lab Gaines Amanda 752-386 1 Client Contact. Phone E-Mall Stale of Origin Page, Shipping/Receiving amanda gaines@et.eurofinsus com North Carolina Page 1 of 2 Company Accredilations Required (See note) Job #: Eurofins Environment Testing Southeast, - State - North Carolina (WW/SW) 752-4652-1 Address Due Dale Requested Preservation Codes 5102 LaRoche Avenue, 3/31/2023 Analysis Requested A HCL M Hexane N None 13 NaOH city TAT Requested (days) Savannah i O AsNa02 C Zn Acetate P Na204S D Nitric Acld State Zip; GA, 31404 O Na2S03 E NaHSO4 R Na2S203 S H2SO4 IF MeOHo' G Amchlor Phone PO #: 912-354-7858(Tel) 912-352-0165(Fax) x d o L° T TSP Dodecahydrate H Ascorbic Acld Ice U Acetone I Email WO # C. F o r°- J Di Water W PH�4 B o , c v c_ 'o yj : af' : 5 K EDTA Y Trizma L EDA Project Name Project #' Henderson County Landfills 75200302 2 v r ti a O o- a o o c o O ? ry v to c N x c a ¢ _ a C y Z other (specify) Other- Site Site SSOW# /county Landfills e a ¢ a o a 0 a °o ¢ w N dl LL U Z Z a .0 Ni e.t LL ¢ Z Sample Matrix, Type Sample (C=comp, o wa. os N c Sam le Identification - Client ID Lab ID Sample Date Time G=grab aT-Tha .A -Air iC t1 V ° u, O e N m M N O M m E N O O , 4 #., Special Instructions/Note Preservation. Code 4501 -AMW1 S (752-4652-1) 3/20/23 1564 Water X X X X X X X X 9' Eastern 4501 -MW5 (Background) (752-4652 2) 3/20/23 1009 Water X X X X X X X X X 19 Eastern 4501 MW8 (752-4652-3) 3/20/23 12 15 Water X X X X X X X X X 19' Eastern 4501 MW8 (752-4652-3MS) 3/20/23 12 15 Ms Water X X X X X X X X X 19 Eastern 4501-MW8 (752-4652-3MSD) 3/20/23 12 15 MSD Water X X X X X X X X X 19' Eastern Note Since laboratory accfeditalions are subject to change Eurofins Environment Testing Southeast, LLC places the ownership of method analyle 8 accreditation compliance upon our subcontract laboratories, This sample shipment Is forwarded under chain -of -custody If the laboratory does not currently maintain accreditation in the State of Origin listed above for analysis/tests/matrix being analyzed the samples must be shipped back to the Eurofins Environment Testing Southeast, LLC laboratory or other instructions will be provided Any changes to accreditation status should be brought to Eurofins Environment Testing Southeast, LLC attention Immediately if all requested accreditations are current to date return the signed Chain of Custody attesting to said compliance to Eurofins Environment Testing Southeast, LLC Possible Hazard Identification Sample Disposal (A fee may be assessed if samples are retained longer than 1 month) I Cl M Unconfirmed Return To Client Disposal By Lab Archive For Months Deliverable Requested 1 II III IV, Other (specify) Primary Deliverable Rank 2 Special Instructions/QC Requirements Empty Kit Relinquished by Date Time Method of Shipment. Relinquished by Dat el Company Received by Date/Time Company Relinquished by Dale a Company Received by Daterrim Company Relinquished by Daterfime Company Received by Daten-ime Company Custody Seals Intact Custody Seal No Cooler Temperature(s)'C and Other Remarks A Yes A No 14 \ u06 08 '021 Page 222 of 242 4/19/2023 IAO 0 r c 0 00 0 C 14 Z. z � z T z �c z < t Sc . . . r o v co) 100 El 1 CZ cli C-4 Lo 'j� x < No CL»5 U) 4) z C? C'I 6 a) z Z' M-w 0 to 1 r.- (L -E t -a w0ull"tio 10 Aqquifft4 jvJQ.L CD 0) 0) a, rn 6) to 3O118-00i-num X X E E'8 2 , W suoluv oml Auv (aow) jcjqz-WJE)8o-00c X X X x x x x x x 1. 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O NO M '0 N c o < n_ L O v 9 @ y lu)C7 N .m a c a c C a E @ o u) O N O N o ui 0 N o (@ O u) o N ui ,N=, ro0 N U C a ¢ E c c U t)U) U W ¢u) pcn qrn W a2 m2 y d v v a v d v v za N CL J A W a Page 226 of 242 4/19/2023 M Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4652 List Number: 1 Creator: Hyatt, Samantha Question List Source: Eurofins Raleigh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Eurofins Raleigh Page 227 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Login Number: 4652 List Number: 3 Creator: Reynolds, Jamie K Job Number: 752-4652-1 List Source: Eurofins Burlington List Creation: 03/22/23 03:29 PM Question Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A Lab does not accept radioactive samples. meter. The cooler's custody seal, if present, is intact. True 2188967 Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True 2.1°C COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A Received project as a subcontract. There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. N/A Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Check done at department level as required. Eurofins Raleigh Page 228 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4652 List Number: 4 Creator: Beck, Brent Question List Source: Eurofins Orlando List Creation: 03/24/23 10:59 AM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 229 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4652 List Number: 2 Creator: Padayao, Abigail Question List Source: Eurofins Savannah List Creation: 03/22/23 01:42 PM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. N/A Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 230 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4682 List Number: 1 Creator: Hyatt, Samantha Question List Source: Eurofins Raleigh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Eurofins Raleigh Page 231 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Login Number: 4682 List Number: 3 Creator: Reynolds, Jamie K Job Number: 752-4652-1 List Source: Eurofins Burlington List Creation: 03/23/23 04:44 PM Question Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A Lab does not accept radioactive samples. meter. The cooler's custody seal, if present, is intact. True 2188973 Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True 1.9°C COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A Received project as a subcontract. There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. N/A Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Check done at department level as required. Eurofins Raleigh Page 232 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4682 List Number: 4 Creator: Beck, Brent Question List Source: Eurofins Orlando List Creation: 03/24/23 10:59 AM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 233 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4682 List Number: 2 Creator: Harley, Tynisha Question List Source: Eurofins Savannah List Creation: 03/23/23 12:34 PM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is N/A <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 234 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4748 List Number: 1 Creator: Hyatt, Samantha Question List Source: Eurofins Raleigh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Eurofins Raleigh Page 235 of 242 4/19/2023 Client: WSP USA Inc Login Number: 4748 List Number: 4 Creator: Khudaier, Zahraa Question Login Sample Receipt Checklist Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Job Number: 752-4652-1 List Source: Eurofins Burlington List Creation: 03/24/23 05:11 PM Lab does not accept radioactive samples. 2088979 1.1°C Eurofins Raleigh Page 236 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4748 List Number: 2 Creator: Beck, Brent Question List Source: Eurofins Orlando List Creation: 03/24/23 11:24 AM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 237 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4748 List Number: 3 Creator: Padayao, Abigail Question List Source: Eurofins Savannah List Creation: 03/24/23 01:54 PM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is N/A <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 238 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4749 List Number: 1 Creator: Hyatt, Samantha Question List Source: Eurofins Raleigh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Eurofins Raleigh Page 239 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4749 List Number: 2 Creator: Padayao, Abigail Question List Source: Eurofins Savannah List Creation: 03/24/23 01:54 PM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is N/A <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 240 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4750 List Number: 1 Creator: Hyatt, Samantha Question List Source: Eurofins Raleigh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Eurofins Raleigh Page 241 of 242 4/19/2023 Login Sample Receipt Checklist Client: WSP USA Inc Job Number: 752-4652-1 Login Number: 4750 List Number: 2 Creator: Padayao, Abigail Question List Source: Eurofins Savannah List Creation: 03/24/23 02:03 PM Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? N/A There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is N/A <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins Raleigh Page 242 of 242 4/19/2023 WSP USA, Inc. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 5 Project Name: Henderson County Landfill (C&D, MNA, and MSW) Project Reference Number: GL2014715721.001 Sampling Event Date: March 20-22, 2023 Review Date: May 1, 2023 Initials: NTT Report #: 752-4652-1 QA/QC: BSD Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. WSP USA Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998 COMPLIANCE ANALYTE LIST(S) (check all that apply) _ NC Closed Facility List (.500 Rules) X NC C & D List (New Rules) _ NC Appendix I X NC Appendix I + 2,4-D X NC Appendix II + 1,4-Dioxane, Mercury NC Subtitle D Leachate List Other: MNA Parameters: Nitrate. Sulfate. Alkalinitv. Chloride. Metha Dioxide, and COCs (Old MW-2) 1.0 CHAIN OF CUSTODY (COC) REVIEW NTT COC was properly signed by all parties. NTT Correct project name and number are on the form. ➢ Incorrect Project number on COCs. Correct number is GL2014715721.001 NTT Sample receipt condition at laboratory was acceptable. NTT Each sample and blank submitted for analysis appears in the report. Ethene. Carbon WSP USA, Inc. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 5 2.0 SAMPLE HOLDING TIMES NTT Holding times for extraction and/or analysis were met for each analytical method (see below for reference). Review Criteria Method Anal tes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW NTT Laboratory analyzed at least one internal blank for each method, where applicable. NTT Laboratory blank is interference -free. Method 8260D: The method blank associated with analytical batch 752-2111 contained Chloroform greater than one-half the reporting limit (RL). The samples were not re -analyzed because there out of holding time. The sample results have been qualified and reported. NTT Surrogate recoveries are provided for each analytical method, where applicable. NTT Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). NTT MS/MSD/LCS data results are provided for each analytical method. Methods 353.2, SM4500 NO2 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2027 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Method 353.2: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2034 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 353.2, SM 4500 NO3 F: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 752-2160 were outside control limits for one or more analytes, see QC Sample Results for detail. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery is within acceptance limits. Methods 808113, 8081 B/8082A: The laboratory control sample (LCS) for preparation batch 680-769227 and analytical batch 680-769499 recovered outside control limits for the following analytes: beta- BHC, delta-BHC and Endrin. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported. WSP USA, Inc. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 5 Method 8260D: The method blank associated with analytical batch 752-2111 contained Chloroform greater than one-half the reporting limit (RL). The samples were not re -analyzed because there out of holding time. The sample results have been qualified and reported. NTT MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). The Method RSK-175: Due to the high concentration of Cot, the matrix spike / matrix spike duplicate (MS/MSD) for analytical batch 200-189761 could not be evaluated for accuracy and precision. The associated laboratory control sample (LCS) met acceptance criteria. 4.0 ANALYTE LISTS/METHODS NTT The proper number of constituents are present for each analyte list as identified above (including detects where applicable). NTT Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING NTT All analytical reporting associated with the event was performed by the contracted lab. NTT Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been 'flagged' with a `B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. Blank Detections: ➢ Field Blank: Acetone @ 10.0 ug/L (J), Methylene Chloride @ 0.362 ug/L (J); Chloroform @ 0.260 ug/L (J); Beryllium @ 0.640 ug/L (J); Cyanide @ 0.0045 ug/L (J) ➢ Trip Blank: Chloroform @ 0.503 ug/L (J), Methylene Chloride @ 0.470 ug/L (J) ➢ Method Blanks: 1,2,4-Trichlorobenzene @ 0.1973 ug/L (J), Hexachlorobutadiene @ 0.4377 ug/L (J), Methylene Chloride @ 0.2792 ug/L (J), Cis-1,2-Dichloroethene @ 0.1782 ug/L (J) (Highest), Choloform @ 1.526 ug/L, Beryllium @ 0.94 ug/L (J) (Highest) Blank Flags: Beryllium: MW-6, MW-7. MW-15, AMW-1S, AMW-1D, AMW-2S, AMW-2D, MW-9, BR-1, BR-2, BR-3, SW-1, MW-10, MW-11, MW-12, MW-13 ➢ Chloroform: BR-1, BR-2, BR-3, SW-1 Cis-1,2-Dichloroethene: AMW-1D, AMW-2S, MW-11, MW-12 Methylene Chloride: MW-7, AMW-2S, MW-9, BR-2, BR-3 Cyanide: MW-5, MW-6, MW-7, MW-8 NTT It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 1 Ox resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. VFAs (10x) on MW-5, MW-6, MW-7, MW-8, ➢ Carbon Dioxide (4x): MW-13, Old MW-2 AMW-1S, AMW-2S, and Old MW-2 ➢ VOCs (5x): MW-6 ➢ Carbon Dioxide (2x): MW-8 NTT No organic constituents were reported above their respective SWSLs, and no inorganic or WSP USA, Inc. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 4 of 5 organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. Concentrations above applicable Standards (i.e., NC 2L or NC 2B) • 1,4-Dioxane (NC2L = 3 ug/L) • MW-6 @ 21.6 ug/L • MW-7 @ 19.4 ug/L • MW-13 @ 3.55 ug/L • AMW-1D @ 12.2 ug/L Cobalt (NC2L = 1 uq/L) • MW-6 @ 2.12 ug/L (J) • MW-7 @ 2.24 ug/L (J) • MW-8 @ 14.4 ug/L • MW-11 @ 2.36 ug/L (J) • MW-13 @ 2.49 ug/L (J) • AMW-1S @ 5.58 ug/L (J) • Cobalt (NC ISTV (Chronic) = 1.6 ug/L) • BR-2 @ 2.36 ug/L (J) • BR-3 @ 3.22 ug/L (J) • Iron (NC2L = 300 ug/L) • MW-11 @ 3610 ug/L • MW-13 @ 1510 ug/L • Manganese (NC2L = 50 ug/L) • MW-11 @ 7660 ug/L • MW-12 @ 914 ug/L • MW-13 @ 831 ug/L • Total Dissolved Solids (NC2L = 500 m /L • MW-11 @ 610 mg/L • Benzene (NC 2L = 1 ug/L) • MW-6 @ 1.64 ug/L (J) • AMW-1D @ 1.1 ug/L • 1,4-Dichlorobenze (NC 2L =6 u /L • MW-7 @ 10 ug/L • Vinyl Chloride (NC 2L =0.03 ug/L) • MW-7 @ 0.81 ug/L (J) • MW-12 @ 1.04 ug/L • MW-13 @ 0.596 ug/L (J) • 1,4-Dioxane (SW Standard = 0.35 u /L • BR-1 @ 0.794 ug/L • BR-2 @ 7.78 ug/L • BR-3 @ 0.989 ug/L • SW-1 @ 1.63 ug/L • Mercury (NC 2L = 1 ug/L) • MW-8 @ 1.04 ug/L • Heptachlor Epoxide (NC 2L = 0.004 ug/L) • MW-7 @ 0.00911 ug/L (J) • Cadmium (SW standard Fresh water Chronic = 0.36ug/L) • BR-3 @ 1.07 ug/L (J) NTT No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). ➢ 15t time detection of gamma-BHC in MW-8 @ 0.00791 ug/L (J) y 15t time detection of Heptachlor Epoxide in MW-7 @ 0.00911 ug/L (J) above NC 2L (0.004 ug/L) NTT Other report issues/Communications with laboratory/etc.: Method 8260D: The (LCS 752-2066/5) was biased low for: 1,1-Dichloroethane, 1,2-Dichloropropane, Benzene, Bromochloromethane, Chlorobenzene, Chloroform, Styrene and trans-1,2-Dichloroethene . All compounds were detected in a reporting limit (RL) sample. All non -detects are reported. Any detections are to be considered estimated values and are qualified. Method RSK-175: The following sample(s) was analyzed outside of analytical holding time due to failure of instruments auto -sampler. WSP USA, Inc. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 5 of 5 aceAna lytical LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/31/2023 Report Y 223032356 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project Henderson Co GL201475722.101 Deliver To Benjamin Draper WSP 5B Oak Branch Dr Greensboro, NC 27407 Samples Collected 3/22/23 Additional Recipients NONE CCCR CERT # 6429.01 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 1 of 11 Report#: 223032356 aceAnarytical Project ID: Henderson Cc GL201475722.101 Report Date: 03/31/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. CA P__L dle_l Authorized Signature Pace Gulf Coast Report 223032356 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 2 of 11 Report#: 223032356 Project ID: Henderson Co GL201475722.101 Report Date: 03/31/2023 Certifications Certification Certification Number A2LA Accredited DoD ELAP-QSM 5.4 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 3 of 11 1 21'Analytical Report#: 223032356 Project ID: Henderson Co GL201475722.101 Report Date: 03/31/2023 Case Narrative Client: WSP- NC Report: 223032356 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 4 of 11 1 2.AruOical Report#: 223032356 Project ID: Henderson Co GL201475722.101 Report Date: 03/31/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303235601 AMW-2S Bubble Strip 22303235602 AMW-2S Water 3/22/23 13:22 3/23/23 09:48 3/22/23 13:22 3/23/23 09:48 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 5 of 11 Report#: 223032356 aceAnarytical Project ID: Henderson Cc GI-201475722.101 Report Date: 03/31/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303235601 AMW-2S Hydrogen nM 3.2 1 NA Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 6 of 11 aceAnalytica! Report#: 223032356 Project ID: Henderson Co GI-201475722.101 Report Date: 03/31/2023 Sample Results AMW-2S Collect Date 03/22/2023 13:22 Lab ID 22303235601 Receive Date 03/23/2023 09:48 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/27/23 08:35 762543 LMB NA CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 3.2 0.49 1.9 nM AMW-2S Collect Date 03/22/2023 13:22 Lab ID 22303235602 Receive Date 03/23/2023 09:48 Matrix Water SM 3500-Fe B-2011 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/2314:28 762401 RYC NA CAS# Parameter WET-045 Ferrous Iron Result DL LOQ 0.014U 0.014 0.050 Units mg/L Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 7 of 11 1 21'Analytical Report#: 223032356 Project ID: Henderson Co GI-201475722.101 Report Date: 03/31/2023 General Chemistry QC Summary Analytical Batch Client ID MB762401 LCS762401 LCSD762401 762401 Lab ID 2465363 2465364 2465365 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/23/23 14:27 03/23/23 14:26 03/23/23 14:27 Matrix Water Water Water SM 3500-Fe B-2011 Units mg/L Spike Result %R I Control Spike Result %R I RPD I RPD I Result DLI Added Limits%R 1 Added Limit Ferrous Iron WET-045 0.014U 0.014 1.00 0.966 97 89.5 - 110.5 1.00 1.03 103 7 20 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 8 of 11 1 21'Analytical Report#: 223032356 Project ID: Henderson Co GI-201475722.101 Report Date: 03/31/2023 General Chromatography QC Summary Analytical Batch Client ID MB762543 LCS762543 LCSD762543 762543 Lab ID 2466207 2466208 2466209 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/27/23 08:05 03/27/23 07:40 03/27/23 07:52 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 0.49 12 12 101 70 - 130 12 12 102 1 20 Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 9 of 11 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN-OF-CUSTOC Client ID: 5665 - WSP- NC WL�O 10775 Central Port Dr. 4810 Executive Park Court, Suite 111 102-A Woodwinds li Orlando, FL 32824 Jacksonville, FL 32216-6069 Cary, NC 27511 SDG: 223032356 (407) 826-5314 Fax (407) 850-6945 (904) 296-3007 Fax (904) 296-6210 (919) 467-3090 Fa Client Name Projerj Number Requested PM: RWe Lt`� Z2 t 1� I Imes Address project Name/Desc i ` Note :Rush requests subject to -Jy acceptance by the facility City/ST PO M /Billing Info i — rievns,00YU Vic, J--`` w- _ Standard Tel Fax Reporting Contact n _ Sampler(s) Name, Affiliation (Print) Billing Contact Expedited Due Sampler(s) Signature Sil ocalion/Time Zone Lab WDrkOrder �C7 125rd �4 Preservation (See Codes) (Combine as necessary) Collection Matrix Total # of Item If Sample to (Field Identification) Collection Date Time Comp / Grab (see codes) Containers Sample Comments w -- I" 13Z'L %i r l k AHW - z S 3122I -> M�2 G -1w ( Sample Kit Prepared By Sample Kit Prepared By Date/rime Relin - ^Dat /Time _ V Received By DateRme Comments/Special Reporting Requirements ` Relinquishe y Datefrriimel r113 Received By Date/Time qz Relinquished By Date rime Received By Date rime Matrix GW-GrnunAwalcr cn cna nw-nd—.,,, v,r.,.,.. ce c_.,:___, �... �...,___,.._._... Cooler #'a & Temps on Receipt `43 .... .... .... ... .. _ _.. ... ... _ Condition Upon Receipt Acceptable _ Unacceptable -- -._._.-.....__._.._._- - .... _ .,...... �......... ... .................r .- .,-r,.,.:.-nww -ncavv --Ivavn v-vmer tuerau m commemsf Note: All samples submitted to ENCO Labs are in accordance with the terms and conditions listed on the reverse of this form, unless prior written agreements exist Pace Gulf Coast Report#: 223032356 03/31/2023 16:01 Page 10 of 11 (,�'7aceAnalyfical'SAMPLE RECEIVING CHECKLIST IIIIIIIIIIII SAMPLE DELIVERY GROUP 223032356 CHECKLIST YES NO Client PM RWe Transport Method Samples received with proper thermal preservation? *❑ ❑ 5665 - MFL NC F®DC Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? ❑ *❑ ❑ ❑ Profile Number Received By 308726 N/bOune, Dodie K All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? *❑ 0 ❑ ❑ Line Item(s) Receive Date(s) 1 - Ferrous Iron 03/23/23 2- hydrogen Preservative added to any containers? ❑ *❑ If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? 0 ❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID E43 Temp °C None None 396095612895 0.7 NOTES Revision 1.6 Page 1 of 1 Pace Gulf Coast Report#: 223032356 03/31 /2023 16:01 Page 11 of 11 aceAna lytical LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/31/2023 Report Y 223032225 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project Henderson Co GL2014715722 Samples Collected 3/20/23 - 3/21/23 Deliver To Benjamin Draper WSP 5B Oak Branch Dr Greensboro, NC 27407 Additional Recipients NONE ACCR DITED CERT # 6429.01 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 1 of 12 Report#: 223032225 aceAnarytical Project ID: Henderson Cc GL2014715722 Report Date: 03/31/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. CA P__L dle_l Authorized Signature Pace Gulf Coast Report 223032225 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 2 of 12 Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 Certifications Certification Certification Number A2LA Accredited DoD ELAP-QSM 5.4 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 3 of 12 1 21'Analytical Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 Case Narrative Client: WSP- NC Report: 223032225 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 4 of 12 aceAnarytical Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303222501 MW-6 Water 3/21/23 12:30 3/22/23 10:11 22303222502 MW-7 Water 3/21/2315:03 3/22/23 10:11 22303222503 OLD MW-2 Water 3/21/23 08:29 3/22/23 10:11 22303222504 MW-5 Bubble Strip 3/20/23 10:06 3/22/23 10:11 22303222505 OLD MW-2 Bubble Strip 3/21/23 08:29 3/22/23 10:11 22303222506 MW-7 Bubble Strip 3/21/23 15:03 3/22/23 10:11 22303222507 MW-8 Bubble Strip 3/20/23 12:15 3/22/23 10:11 22303222508 AMW-15 Bubble Strip 3/21/23 15:54 3/22/23 10:11 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 5 of 12 Report#: 223032225 aceAnarytical Project ID: Henderson Cc GL2014715722 Report Date: 03/31/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable SM 3500-Fe B-2011 Lab ID Client ID Parameter Units Result Dil. %Moist 22303222501 MW-6 Ferrous Iron mg/L 25.2 25 NA 22303222502 MW-7 Ferrous Iron mg/L 0.485 1 NA 22303222503 OLD MW-2 Ferrous Iron mg/L 0.035J 1 NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303222504 MW-5 Hydrogen nM 1.01 1 NA 22303222505 OLD MW-2 Hydrogen nM 1.2J 1 NA 22303222506 MW-7 Hydrogen nM 0.96J 1 NA 22303222507 MW-8 Hydrogen nM 2.2 1 NA 22303222508 AMW-15 Hydrogen nM 0.98J 1 NA Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 6 of 12 aceAnalytica! Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 Sample Results MW-c Collect Date 03/21/2023 12:30 Lab ID 22303222501 v Receive Date 03/22/2023 10:11 Matrix Water SM 3500-Fe B-2011 *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 25 03/22/2313:32 762306 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 25.2 0.358 1.25 mg/L Collect Date 03/21/2023 15:03 Lab ID 22303222502 MW-7 Receive Date 03/22/2023 10:11 Matrix Water SM 3500-Fe B-2011 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/22/2313:33 762306 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 0.485 0.014 0.050 mg/L OLD MW-2 Collect Date 03/21/2023 08:29 Lab ID 22303222503 Receive Date 03/22/2023 10:11 Matrix Water SM 3500-Fe B-2011 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/22/2313:33 762306 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 0.035J 0.014 0.050 mg/L Collect Date 03/20/2023 10:06 Lab ID 22303222504 MW-G Receive Date 03/22/2023 10:11 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/23 07:35 762341 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 1.01 0.49 1.9 nM Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 7 of 12 Report#: 223032225 aceAr�alytrca! Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 Sample Results OLD MW-2 Collect Date 03/21/2023 08:29 Lab ID 22303222505 Receive Date 03/22/2023 10:11 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/23 07:47 762341 LMB NA CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 1.2,1 0.49 1.9 nM Collect Date 03/21/2023 15:03 Lab ID 22303222506 MW-7 Receive Date 03/22/2023 10:11 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/23 08:00 762341 LMB NA CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 0.96J 0.49 1.9 nM Collect Date 03/20/2023 12:15 Lab ID 22303222507 MW-Q Receive Date 03/22/2023 10:11 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/23 08:12 762341 LMB NA CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 2.2 0.49 1.9 nM AMW-15 Collect Date 03/21/2023 15:54 Lab ID 22303222508 Receive Date 03/22/2023 10:11 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/23/23 08:25 762341 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 0.981 0.49 1.9 nM Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 8 of 12 1 21'Analytical Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 General Chemistry QC Summary Analytical Batch Client ID MB762306 LCS762306 LCSD762306 762306 Lab ID 2464655 2464656 2464657 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/22/23 13:31 03/22/23 13:31 03/22/23 13:31 Matrix Water Water Water SM 3500-Fe B-2011 Units mg/L Spike Result I %R I Control I Spike Result %R I RPD I RPD I Result DL 1 Added Limits%R 1 Added Limit Ferrous Iron WET-045 0.014U 0.014 1.00 1.05 105 89.5 - 110.5 1.00 1.01 101 4 20 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 9 of 12 1 21'Analytical Report#: 223032225 Project ID: Henderson Co GL2014715722 Report Date: 03/31/2023 General Chromatography QC Summary Analytical Batch Client ID MB762341 LCS762341 LCSD762341 762341 Lab ID 2464941 2464942 2464943 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/23/23 07:23 03/23/23 06:53 03/23/23 07:11 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 1 0.491 121 11 1 90 1 70 - 130 1 121 10 188 1 2 1 20 Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 10 of 12 CHAIN -OF -CUSTODY Analytical Request Document FaceAnalytical' Chain -of -Custody is a LEGAL DOCUMENT -Complete all relevent fields LAB USE ONLY -Affix Wot Client ID: 5665 - WSP- NC ALL SHAE SDG: 223032225 Container PreservativeT, PM: RWe " Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric and, 14) sodium hydroxide, t5J 2111C dLek,ne, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate, (C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other Company: Billing Information: Address: J y 2� C{� t✓}/� tl/ Report To:ga_ Email Toatd�{{� J�Y� Ui. Copy To: Site Collection I " o/Address: Analyses Lab Profile/Line: Custom Project Name/Number: li\l 1I�'1 'L t�i -1 1 `Sta'te: 1 3L/ i�Yl i�-Y (fou'nty/City: I Time Zone Collected: fSVIr�[ ]PT[ ]MT( ]CT [r[jET 7- 1 11 � t \ Lab Sample Receipt checklist: Custody Seals Present/Intact Y N NA Custody Signatures Present Y N NA Collector Signature Present Y N NA Bottles Intact Y N NA Correct Bottles Y N NA Sufficient Volume Y N NA Samples Received on Ice Y N NA VOA - Headspace Acceptable Y N NA USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual chlorine Present Y N NA Cl Strips: Sample pH Acceptable Y N NA pH Strips: Sulfide Present Y N NA Lead Acetate Strips: LAB USE ONLY: Lab Sample # / Comments: Phone: Email: Site/Facility ID #: Compliance Monitoring? [ ] Yes [ ]No C II cted By (print M. Purchase Order M Quote M DW PWS ID #: DW Location Code: Collected B tur Turnaround Date Required: Immediately Packed on Ice: [ ]Yes [ )No Sample Disp I: [ J Dispose as appropriate [ j Return [ J Archive: [ )Hold: Rush: [ )Same Day [ ] Next Day [ ] 2 Day [ ] 3 Day ( ] 4 Day [ ] 5 Day (Expedite Charges Apply) Field Filtered (if applicable): [ ] Yes [ ] No Analysis: * Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID Matrix * Comp / Grab Collected (or Composite Start) Composite End Res CI # of Ctns Date Time Date Time ) 2 30 �! 1 Old t1w 2 -)w I I b?� 3 ►'' 3 20 7 1009 $46e�b- C) I% it All,L3 ` 11 1 X hw 1' AIL I x h1W `b t( 3IL�lr3 ill. - is Aa - 25 Customer Remarks / Special Conditions / Possible Hazards: n d /v11I,11r2, PqA "` Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours): Y N N/A Lab Sample Temperature Info: Temp Blank Received: Y N NA ThermID#: Cooler 1 Temp Upon Receipt: oc Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: oc Comments: oP r rfs3 Packing Material Used: /� �� 'Z �� Lab Tracking #: ^ � 0 ^ � � � LJl6J Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: FEDEX UPS Client Courier Pace Courier Relinquishe y/Compan ature) Date/R'73 ' ISy4 Received by/Company: (Signature) Date/Time: MTJL LAB USE ONLY Table #: Template Template: Prel gin: Relinquish d q y/ a y. (Signature) Da a/Time: / I ����� l (` Received by/Company: (Signature) 1 U-P- D�a/te�/�Ti%me: if /Lf 1✓ Trip Blank Received: Y N NA HCL McOH TSP Other Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: pB: Non Conformance(s): YES / NO Page: of: Pace Gulf Coast Report#: 223032225 03/31/2023 15:31 Page 11 of 12 (,�'7aceAnalyfical'SAMPLE RECEIVING CHECKLIST IIIIIIIIIIIII III SAMPLE DELIVERY GROUP 223032225 CHECKLIST YES NO Client PM RWe Transport Method Samples received with proper thermal preservation? *❑ ❑ 5665 - MFL NC FEDDC Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? ❑ *❑ ❑ ❑ Profile Number Received By 308726 N/bOune, Dodie K All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? *❑ 0 ❑ ❑ Line Item(s) Receive Date(s) 1 - Ferrous Iron 03/22/23 2- hydrogen Preservative added to any containers? ❑ *❑ If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? 0 ❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID E38 Temp °C None None 396049254505 0.1 NOTES Revision 1.6 Page 1 of 1 Pace Gulf Coast Report#: 223032225 03/31 /2023 15:31 Page 12 of 12 aceAna lytical LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/22/2023 Report Y 223032140 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project Henderson Co GL2014715722 Deliver To Benjamin Draper WSP 5B Oak Branch Dr Greensboro, NC 27407 Samples Collected 3/20/23 Additional Recipients NONE CCCR CERT # 6429.01 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 1 of 10 Report#: 223032140 aceAnarytical Project ID: Henderson Cc GL2014715722 Report Date: 03/22/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. CA P__L dle_l Authorized Signature Pace Gulf Coast Report 223032140 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 2 of 10 Report#: 223032140 Project ID: Henderson Co GL2014715722 Report Date: 03/22/2023 Certifications Certification Certification Number A2LA Accredited DoD ELAP-QSM 5.4 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 3 of 10 1 21'Analytical Report#: 223032140 Project ID: Henderson Co GL2014715722 Report Date: 03/22/2023 Case Narrative Client: WSP- NC Report: 223032140 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 4 of 10 Report#: 223032140 aceAnarytical Project ID: Henderson Co GL2014715722 Report Date: 03/22/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303214001 MW-5 Water 3/20/23 10:09 3/21/23 09:51 22303214002 MW-8 Water 3/20/23 12:15 3/21/23 09:51 22303214003 AMW-1S Water 3/20/2315:54 3/21/23 09:51 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 5 of 10 aceAnarytical Report#: 223032140 Project ID: Henderson Cc GL2014715722 Report Date: 03/22/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable SM 3500-Fe B-2011 Lab ID Client ID Parameter Units Result Dil. %Moist 22303214002 22303214003 MW-8 Ferrous Iron mg/L AMW-1S Ferrous Iron mg/L 36.7 0.272 25 1 NA NA Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 6 of 10 aceAnalytica! Report#: 223032140 Project ID: Henderson Co GL2014715722 Report Date: 03/22/2023 Sample Results Collect Date 03/20/2023 10:09 Lab ID 22303214001 MW-5 Receive Date 03/21/2023 09:51 Matrix Water SM 3500-Fe B-2011 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/21/2315:07 762225 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 0.014U 0.014 0.050 mg/L MW-Q Collect Date 03/20/2023 12:15 Lab ID 22303214002 v Receive Date 03/21/2023 09:51 Matrix Water SM 3500-Fe B-2011 *Results and limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 25 03/21/2315:07 762225 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 36.7 0.358 1.25 mg/L AMW-1 S Collect Date 03/20/2023 15:54 Lab ID 22303214003 Receive Date 03/21/2023 09:51 Matrix Water SM 3500-Fe B-2011 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 03/21/2315:08 762225 RYC NA CAS# Parameter Result DL LOQ Units WET-045 Ferrous Iron 0.272 0.014 0.050 mg/L Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 7 of 10 1 21'Analytical Report#: 223032140 Project ID: Henderson Co GL2014715722 Report Date: 03/22/2023 General Chemistry QC Summary Analytical Batch Client ID MB762225 LCS762225 LCSD762225 762225 Lab ID 2464279 2464280 2464281 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/21/23 15:06 03/21/23 15:05 03/21/23 15:06 Matrix Water Water Water SM 3500-Fe B-2011 Units mg/L Spike Result I %R I Control I Spike Result %R I RPD I RPD I Result DL 1 Added Limits%R 1 Added Limit Ferrous Iron WET-045 0.014U 0.014 1.00 1.03 103 89.5 - 110.5 1.00 1.08 108 5 20 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 8 of 10 y CHAIN -OF -CUSTODY Analytical Request Document FaceAnalyfical Chain -of -Custody is a LEGAL DOCUMENT- Complete all relevent fields LAB USE ONLY -Affix Wor c[ie ; m: 566E - VV-SP- nit ALL SHAE SDG: 223032140 Container Preservative T, PM: RWe '* Preservative Types: (1) nitric acid, (2) sultu..,...... t�i �rv�� ������� �� .", t�i— ..... .w �����, t�i �� ��_•�,_, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (8) ammonium sulfate, (C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other Company: W SP Billing Information: Address: (D( �� �� ` Report To: 6 Email To: -) ' Y"' Copy To: Site Collection In/Address: Analyses Lab Profile/Line: Customer Project Name/Number: �2 GV l 'J 2-1- State: County/City: Time Zone Collected: M"- / f [ ] PT [ ] MT [ ] CT [ Ll ET I` I, C ) Lab Sample Receipt checklist: Custody Seals Present/Intact Y N NA Custody signatures Present Y N NA Collector Signature Present Y N NA Bottles Intact Y N NA correct Bottles Y N NA Sufficient Volume Y N NA Samples Received on Ice Y N NA VOA - Headspace Acceptable Y N NA USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual Chlorine Present Y N NA Cl Strips: Sample pH Acceptable Y N NA pH Strips: Sulfide Present Y N NA Lead Acetate Strips: LAB USE ONLY: Lab Sample # / Comments; Phone: Email: Site/Facility ID #: Compliance Monitoring? [P Yes [ ]No Collected By (print): l •l� '� Purchase Order #: Quote #: DW PWS ID #: DW Location Code: Collected By (si t e): Turnaround Date Required: Immediately Packed on Ice: [Yes [ ]No Sample Dispos [ ] Dispose as apQ pri [ ] Return [ ] Archive: [ ]Hold: Rush: [ ] Same Day [ ] Next Day [ J 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day (Expedite Charges Apply) Field Filtered (if applicable): [ )Yes [ ] No Analysis:, * Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID Matrix * Comp / Grab Collected (or Composite Start) Composite End Res Cl # of Ctns Date Time Date Time too [ K Customer Remarks / Special Conditions / Possible Hazards: �� n ' �XI Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT (<72 hours): Y N N/A Lab Sample Temperature Info: Temp Blank Received: Y N NA Therm ID#: Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: oC Comments: Packing Material Used: t ,, r W� r L J Lab Tracking #: � � O ^ � � � LV. Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: FEDEX UPS Client Courier Pace Courier Relinquishe by/Co na ure)` r) SF1 Date/Time: ?_1ZJ25 1650 Vr�J Received by/Company: (Signature) Date/Time: MTJL LAB USE ONLY Table M Acctnum: Template: Prelogin: g; PB: Relin shedll q op:ignature) d1pd�7 Date/Time:� I Received by/Company: (Signature) ` IIU'� Date/Time: vl , 5 I -23 Trip Blank Received: Y N NA HCL McOH TSP Other Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: rnnformance(s): S / NO Page: of: Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 9 of 10 (,�'7aceAnalyfical'SAMPLE RECEIVING CHECKLIST IIIIIIIIYIIII SAMPLE DELIVERY GROUP 223032140 CHECKLIST YES NO Client PM RWe Transport Method Samples received with proper thermal preservation? *❑ ❑ 5665 - MFL NC F®DC Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? *❑ *❑ ❑ ❑ Profile Number Received By 308726 N/bCune, Dodie K All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? *❑ 0 ❑ ❑ Line Item(s) Receive Date(s) 1 - Ferrous Iron 03/21/23 Preservative added to any containers? ❑ I❑ If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? 0 ❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID E43 Temp °C None None 638510343451 2.1 NOTES Date of collection and relinquish dat recorded as 2/20/23 and should be 3/20/23 Revision 1.6 Page 1 of 1 Pace Gulf Coast Report#: 223032140 03/22/2023 16:31 Page 10 of 10 WSP xx % I QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Henderson County Landfill Project Reference Number: GL2014715721.001 Sampling Event Date: March 20-22, 2023 Review Date: May 1, 2023 Initials: NTT Report #: 223032356,223032225,223032140 QA/QC: BSD 11 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. WSP USA Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environ- mental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998 COMPLIANCE ANALYTE LIST(S) (check all that apply) _ NC Closed Facility List (.500 Rules) _ NC C & D List (New Rules) _ NC Appendix I NC Appendix I + Detects _ NC Appendix II NC Subtitle D Leachate List Other: Hydrogen & Ferrous Iron 1.0 CHAIN OF CUSTODY (COC) REVIEW NTT COC was properly signed by all parties. NTT Correct project name and number are on the form. NTT Sample receipt condition at laboratory was acceptable. NTT Each sample and blank submitted for analysis appears in the report. WSP QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES NTT Holding times for extraction and/or analysis were met for each analytical method (see below for reference). Review Criteria Method Anal tes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW NTT Laboratory analyzed at least one internal blank for each method, where applicable. NTT Laboratory blank is interference -free. NTT Surrogate recoveries are provided for each analytical method, where applicable. NTT Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). NTT MS/MSD/LCS data results are provided for each analytical method. NTT MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). 4.0 ANALYTE LISTS/METHODS NTT The proper number of constituents are present for each analyte list as identified above (including detects where applicable). NTT Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING NTT All analytical reporting associated with the event was performed by the contracted lab. NTT Trip, field, and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been 'flagged' with a 'B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. WSP QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 NTT It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. NTT The report provides the reporting limit for each constituent. NTT The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. n/a No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. n/a No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). n/a Other report issues/Communications with laboratory/etc.: APPENDIX C EPA NATURAL ATTENUATION SCREENING PROTOCOL FORMS AND BIOCH LOR MONITORED NATURAL ATTENUATION ANALYSIS FOR MARCH 2O23 SAMPLING EVENT Natural enua Ion Interpretation Score Screening Inadequate evidencefcranaerobobiodegradation* ofchIainatedorgan Oto5 Limited e+idenmfor anaerobic biodegradation`ofchi orirated organics 6to14 Protocol Score: 15 Thp'ipWrg istaim�nor' Np U�PAor"c1 IU5FPA, 19981 The re.ks d Nis xc�r'g prates h- " requiaory Adequate evidencefor anaerobic biodegradation` of chlorinated organics 15 to 20 g evi gra organics strap evidence for anaerohic biode dation' of chlorinated or >20 sig�ircarce. Scroll to End of Table Concentration in Points Analysis Most Contam. Zone Interpretation Yes No Awarded Oxygen* <0.5 i Tolerated, suppresses the reductive pathway at higher O 3 concentrations > 5mg1L Not tolerated; however, VC may be oxidized aerobically O O 0 Nitrate" <1 mg1L At higher concentrations may compete with reductive O © 0 pathway Iran II' >1 i Reductive pathway passible, VC may be oxidized under O O 0 Fe(I I I) -reducing conditions Sulfate' <20 i At higher concentrations may compete with reductive O 2 pathway Sulfide` >1 mg1L Reductive pathway possible O O 0 Methane' >0.5 mi Ultimate reductive daughter product, VC Accumulates O 0 0 Oxidation <50 millivolts (mi Reductive pathway possible O 0 Reduction Potential' (ORP) <-100mV Reductive pathway likely O 0 0 pH' 5 < pH < 9 Optimal range for reductive pathway 0 O 0 TOC >20 mi Carbon and energy source; drives dechlorination; can be O D 0 natural or anthro epic Temperature* >2G°C At T >20°C biochemical process is accelerated O 0 0 Carbon Dioxide >2x background Ultimate oxidative daughter product Q O 1 Alkalinity >2x background Results from interaction of carbon dioxide with aquifer O O 1 minerals Chloride' >2x background Daughter product of organic chlorineO O 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate O O 0 Volatile Fatty Acids >0.1 i Intermediates resulting from biodegradation of aromatic p O 2 compounds, carbon and energy source BTEX" >0.1 mi Carbon and energy source; drives dechlorination O 0 0 i Matenai released O OQ 0 TCE' Daughter product of PCE O G 0 DCE' Daughter product of TCE. If cis is greater than 80 of total DCE it is likely a daughter 2 Product of TCE'r;1,1-DCE can be a them. reaction product of TCA VC* Daughter product of Di O 2 1,1,1- Material released O 0 Trichlorcethani DCA Daughter product of TCA under reducing conditions O O 0 Carbon Material released O 0 0 Tetrachloride Chloroethane' Daughter product of DCA or VC under reducing conditions O OO 0 FthenelFthane >0.01 mg/L Daughter product of VC/ethene O © 0 >0.1 i Daughter product of VC/ethene O 0 Chloroform Daughter product of Carbon Tetrachloride O 0 Dichloromethane Daughter product of Chloroform O O 0 * required analysis. a/ Points awarded only if it can be shown that the compound is a daughter product (i.e., not a constituent ofthe source NAPL). DATE:7/12/2023 I Title: Proi GL2014715721.001 Prepared By: NTT Reviewed By: TJM SCORE Reset li MNA SCREENING March 2023 Henderson County Closed MSW Landfill, Permit No. 45-01 Appendix) C-1 Natural enua Ion Interpretation Score Screening inadequate evidence fur anaerobic hlodegradatiun` of chlo nated organics 0 to 5 Limited evidence for anaerobic biodegradation' of chlorinated organics 6 to 14 Protocol Score: 21 The rd1—g i.taa�hom meu Apia dtus�aa, leas) The rewl[s 6Nie scai io pioress hoe n' "J.131nry Adequate evidencefor anaerobic biodegradation` of chlorinated organics 15to20 Strong evidence for anaerobic biodegradation' of chiednated organics >20 ay�,cacs. Scroll to End of Table 'retluclive dechlane[im Concentration in Points Analysis Most Contam. Zone Interpretation Yes No Awarded Oxygen* <0.5 mi Tolerated, suppresses the reductive pathway at higher O Ui 0 concentrations > 5mg/L Not tolerated; however, VC may be oxidized aerobically U O D Nitrete* <1 ni At higher concentrations may compete with reductive OO O 2 pathway Iron II* >1 mg/L Reductive pathway possible; VC may be oxidized under O 0 3 Fe III) -reducing conditions Sulfate" <20 mglL At higher concentrations may compete with reductive O 2 pathway Sulfide* >1 ri Reductive pathway possible U 0 0 Methane >0.5 ri Ultimate reductive daughter product, VC Accumulates p 0 3 Oxidation <50 millivolts (mV) Reductive pathway possible p O 1 Reduction <-1DDmV Reductive pathway likely 0 0 D Potential* (ORP) 1 5 < i < 9 Optimal range for reductive pathway © O 0 TOC >20 mglL Carbon and energy source; drives dechlorination, can be O O 2 natural or anthropogenic Temperature* >20°C At T >20°C biochemical process is accelerated O OO 0 Carbon Dioxide >2x background Ultimate oxidative daughter product O O 1 Alkalinity >2x background Results from interaction of carbon diexide with aquifer O O 1 minerals Chloride' >2x background Daughter product of organic chlorine O 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate U 0 Volatile Fatty Acids >0.1 mi Intermediates resulting from biodegradation of aromatic p U 2 cam orris; carbon and energy source BTEX` >0.1 mi Carbon and energy source; drives dechlorination O © 0 PCE* Material released O © 0 TCE* Daughter product of PCE U 0 i Daughter product of TCE If cis is greater than BD % of total DCE it is likely a daughter Ui U 2 product of TCi 1,1-DCE can be a chem. reaction product of TCA VC* Daughter product of DCi O O D 1,1,1- Material released O 0 Trichloroethane* DCA Daughter product of TCA under reducing conditions O 0 Carbon Material released U O D Tetrachloride Chloroethane" Daughter product of DCA or VC under reducing conditions O 0 EthenelEthane >0.01 mglL Daughter product of VClethene O 0 >0.1 mi Daughter product of VClethene U 0 D Chloroform Daughter product of Carbon Tetrachloride O © 0 Dichloromethane Daughter product of Chloroform O © 0 • required analysis. al Points awarded only ifit can be shown that the compound is adaughter product (i.e., not aconstituent of the source NAPL). SCORE Reset DATE: 023 Title: MW-6 MNA SCREENING March 2023 Henderson County Closed MSW Landfill, Permit No. 45-01 Appendix C-2 Project #: GL2014L2014715721.001 Prepared By: NTT Reviewed By: TJM Natural enua Ion Interpretation Score Screening inadequate evidence fur anaerobic hlodegradatiun` of chlo nated organics 0 to 5 Limited evidence for anaerobic biodegradation' of chlorinated organics 6 to 14 Protocol Score: 21 The rd1—g i.taa�hom meu Apia dtus�aa, leas) The rewl[s 6Nie scai io pioress hoe n' "J.131nry Adequate evidencefor anaerobic biodegradation` of chlorinated organics 15to20 Strong evidence for anaerobic biodegradation' of chiednated organics >20 ay�,cacs. Scroll to End of Table 'retluclive dechlane[im Concentration in Points Analysis Most Contam. Zone Interpretation Yes No Awarded Oxygen* <0.5 mi Tolerated, suppresses the reductive pathway at higher O Ui 0 concentrations > 5mg/L Not tolerated; however, VC may be oxidized aerobically U O 0 Nitrete* <1 ni At higher concentrations may compete with reductive OO O 2 pathway Iron II* >1 mg/L Reductive pathway possible; VC may be oxidized under O 0 3 Fe III) -reducing conditions Sulfate" <20 mg/L At higher concentrations may compete with reductive O 2 pathway Sulfide* >1 ri Reductive pathway possible U 0 0 Methane >0.5 ri Ultimate reductive daughter product, VC Accumulates p 0 3 Oxidation <50 millivolts (mV) Reductive pathway possible p O 1 Reduction <-1DDmV Reductive pathway likely 0 0 0 Potential* (ORP) 1 5 < i < 9 Optimal range for reductive pathway © O 0 TOC >20 mglL Carbon and energy source; drives dechlorination, can be O O 2 natural or anthropogenic Temperature* >20°C At T >20°C biochemical process is accelerated O OO 0 Carbon Dioxide >2x background Ultimate oxidative daughter product O O 1 Alkalinity >2x background Results from interaction of carbon diexide with aquifer O O 1 minerals Chloride' >2x background Daughter product of organic chlorine O 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate U 0 Volatile Fatty Acids >0.1 mi Intermediates resulting from biodegradation of aromatic p U 2 cam orris; carbon and energy source BTEX` >0.1 mi Carbon and energy source; drives dechlorination O © 0 PCE* Material released O © 0 TCE* Daughter product of PCE U 0 DCE' Daughter product of TCE If cis is greater than BD % of total DCE it is likely a daughter Ui U 2 product of TCi 1,1-DCE can be a chem. reaction product of TCA VC* Daughter product of DCi O O 0 1,1,1- Material released O 0 Trichloroethane* DCA Daughter product of TCA under reducing conditions O 0 Carbon Material released U O 0 Tetrachloride Chloroethane" Daughter product of DCA or VC under reducing conditions O 0 EthenelEthane >0.01 mg/L- Daughter product of VC/ethene O 0 >0.1 mi Daughter product of VGethene U 0 0 Chloroform Daughter product of Carbon Tetrachloride O © 0 Dichloromethane Daughter product of Chloroform O © 0 ' required analysis. al Points awarded only ifit can be shown that the compound is adaughter product (i.e., not aconstituent of the source NAPL). SCORE R�9E't DATE:7/12/2023 Title: MW-8 MNA SCREENING March 2023 Henderson County Closed MSW Landfill, Permit No. 45-01 Appendix C-3 Project#: GL2014715721.001 Prepared By: NTT Reviewed By: TJM Natural nua Ion Interpretation Score Screening Inadequate evidence for anaerobic biodegradation' of chlorinated organics 0to5 Protocol mitetl evitlence Tor anaerobic hiatlegradaiian' of eHonnated organics 6 to 14 Score: 16 Adequate evidence for anaerobic biodegradation' or chlorinated organics 15 to 20 me Idiurin9 Is �dan trap me UTPA or�cd (UMMPA, Mgt theresins0T scam®o�ocsssnaena pewaoN sMihcmce. Scroll to End of Table Strong evidence for anaerobic biodegradation` ofchlorinated organics >20 a.�aim Concentration in •�a A-mchiPaints Analysis Most Contam Zone Interpretation Yes No Awarded Oxygen' <0 5 mg/L Tolerated, suppresses the reductive pathway at higher O 0 0 concentrations > 5mg/L Not tolerated, however, VC may be addlzed aerobically O O 0 Nitrate"' <1 mg/L At higher concentrations may compete with reductive O 2 athsra Iron II" >1 mg/L Reductive pathway possible, VC may be oxidized under O 0 0 Fe(Ill)-reducing conditions Sulfate* <20 mglL At higher concentrations may compete with reductive O 2 pathway SulFideY >1 mg/L Reductive pathway possible O O 0 Methane* >0.5 mg/L Ultimate reductive daughter product, VC Accumulates O 0 Oxidation <50 millivolts (mV) Reductive pathway possible O 0 1 Reduction Poterdial' (ORPj <-100mV Reductive pathway likely O © 0 1 5 < pH < 9 Optimal range for reductive pathway Q O 0 TOG >20 mg/L Carbon and energy source, drives dechlorinatien; can be O 0 0 natural or anthro enic Temperature` >2U'C At T >20'C biochemical process is accelerated O 0 Carbon Dioxide >2x background Ultimate oxidative daughter product O* O 1 Alkalinity >2x background Results from interaction of carbon dioxide with aquifer OO O 1 minerals Cl >2x background Daughter product of organic chlorine p O 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate p O 3 Volatile Fatty Acids >0.1 mg/L Intermediates resulting from biodegradation of aromatic p O 2 coon und% carbon and energy source BTl >0.1 mg/L Carbon and energy source; drives dechlorinatien O 0 PCE' Material released O 0 0 TCE* Daughter product of PCE O 0 DCE' Daughter product of TCE. If cis is greater than 8C% of total DCE it is likely a daughter O Oi 0 product of TCE°`; 1,1-DCE can be a Chem, reaction product of TCA VC' Daughter product of DCE" O 0 1,1,1- Material released O 0 Trichloroethane" DCA Daughter product of TCA under reducing conditions 0 O 2 Carbon Material released O 0 Tetrachloride Chloroethari Daughter product of DCA or VC under reducing conditions O 0 0 EthenelEthane >0.01 mg/L Daughter product of VGIethene O 0 0 >0.1 mg/L Daughter product of VC/ethene O 0 Chloroform Daughter product of Carbon Tetrachloride O 0 0 Dichloromethane Daughter product of Chloroform O O 0 * required analysis. a/ Points awarded only if it can be shown that the compound is a daughter product (i.c., not a constituent efthe source NAPL). End of F SCORE Reset DATE: 7/1212023 Title: Project#: GL2014715721.001 OLD MW-2 MNA SCREENING March 2023 Prepared By: NTT Henderson County Closed MSW Landfill, Permit No. 45-01 Reviewed By: TJM Appendix) C-4 BIOCHLOR Natural Attenuation Decision Support System Version 2.2 TYPE OF CHLORINATED SOLVENT: 1. ADVECTION Seepage Velocity* Vs or Hydraulic Conductivity K Hydraulic Gradient i Effective PorosV _______________ n _ 2. DISPERSION Alpha x* 47.5 (ft) (Alpha y) I (Alpha x)* 0.1 (-) (Alpha z) / (Alpha x)* 5.E-02 (-) 3. ADSORPTION Retardation Factor' or Soil Bulk Density, rho FractionOrganicCarbon, foc Partition Coefficient PCE TCE DCE VC ETH Common R 4. BIOTRANSFORMATION Zone 1 PCE TCF TCE DCE DCE VC VC ETH Zone 2 PCE TCE TCE -4 DCE DCE VC VC ETH Henderson County Data Input Instructions: Landfill 115 1. Enter value directly.... or Excel 2000 Run Name T or 2. Calculate by filling in gray Ethenes b. GENERAL 0.02 cells. Press Enter, then _ Ethanes 0_ _ Simulation Time* 63 (yr) ~ L -' (To restore formulas, hit "Restore Formulas" button ) Modeled Area Width* 370 (ft) W Variable* Data used direct) in model. 62.8 (ft/yr) Modeled Area Length* 550 (ft) 1 Test if Zone 1 Length* 550 (ft) Biotransformation Natural Attenuation 1.3E-04 (cm -Use c) Zone 2 Length* 0 (ft) Zone 2= is Occurr ng L Screening Protocol 0.0723 (fttft) L - Zone 1 0.15 �6. SOURCE DATA TYPE: Continuous Vertical Plane Source: Determine Source Well Calc. Source Options Single Planar Location and Input Solvent Concentrations Alpha x Source Thickness in Sat. Zone* = (ft) Y1 Width* (ft) 370 R ks" Conc. (mg/L)* C1 (1lyr) 1.7 (kglL) PCE .17 0 1.0E-4 (-) TCE .027 0 Koc y DCE .031 0 426 (Llkg) 1.48 (-) VC .005 0 130 (L/kg) 1.15 (-) ETH 0 0 125 (Llkg) 1.14 (-) 30(L/kg) 1.03 (-) 7. FIELD DATA FOR COMPARISON 302 (L/kg) 1.34 (-) PCE Conc. (mglL) .0 .0 .0 .0 sed in mode_Q* = 1.15 TCE Conc. (mglL) .0 .0 .0 .0 -1st Order Decay Coefficient* DCE Conc. (mg1L) .002 .001 .0 A 1/ r half-life rs Yield IVC Conc. (mglL) .001 .0 .0 A N FWO.45 0.79 ETH Conc. (mglL) 0.0 0.0 0.0 0.0 F0.74 Distance from Source (ft) 0 100 1000 1600 0.64 Date Data Collected 2023 F 8. CHOOSE TYPE OF OUTPUT TO SEE: 1/ r half-life rs 12.000 F 1.20 20.00o F 0.90 HELP 7R�NCENTERLINE RUN A:RREAY:7 1.o00 F 1.50 6.000 F 2.60 DATE: 7/12/2023 Prro ect# GL20147115 21.001 Prepared By: NTT Reviewed By: TJM View of Plume Looking Down Observed Centerline Conc. at Monitoring Wells Help[Restore] [RESET] SEE OUTPUT Paste Title: BIOCHLOR DATA ENTRY SHEET FOR WELLS MW-7, Appendix MW-6, MW-8, AND OLD MW-2 (63 YEAR SIMULATION) MARCH 2O23 C-5 Henderson County Closed MSW Landfill BIOCHLOR Natural Attenuation Decision Support System Version 2.2 TYPE OF CHLORINATED SOLVENT: 1. ADVECTION Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Effective Porosity 2. DISPERSION Alpha x* (Alpha y) / (Alpha x)* (Alpha z) I (Alpha x)* 3. ADSORPTION Retardation Factor* Vs I Ethenes 0 Ethanes O 62.8 (ftlyr) 1.3E-04 (cm/sec) 0.0723 (fUft) 0-15 ( ).._......W 47.5 (ft) Calc. Alpha x U. (-) 5. E-02 (-) R or Soil Bulk Density, rho 1.7 (kglL) FractionOrganicCarbon, foc 1.0E-4 (-) Partition Coefficient Koo y PCE 426 (Llkg) 1.48 (-) TCE 130 (L/kg) 1.15 (-) DCE 125 (L/kg) 1.14 (-) Excel 2000 5. GENERAL Simulation Time* Modeled Area Width* Modeled Area Length* Zone 1 Length* Zone 2 Length* S. SOURCE DATA Source Options Henderson County jData Input Instructions: Landfill Run Name 100 (yr) L � 370 (ft) W 550 (ft) 1 550 (ft) 0 (ft) Zone 2= L -Zone 1 TYPE: Continuous Single Planar Source Thickness in Sat. Zone* 55 (ft) 115 1. Enter value directly.. ..or T or 2. Calculate by filling in gray 0.02 cells. Press Enter, then J (To restore formulas, hit "Restore Formulas" button ) Variable* Data used directly in model. Test if Biotransformation Natural Attenuation is Occurrinq "-> Screening Protocol _j Vertical Plane Source: Determine Source Well Location and Input Solvent Concentrations Y 1 Width* (ft) 370 ks* Cone. (mg/L)* C1 (1/yr) PCE .17 0 TCE .027 0 View of Plume Looking Down DCE .031 0 VC .005 0 Observed Centerline Cone. at Monitoring Wells ETH 0 0 VC 30 (L/kg) 1.03 (-} 7. FIELD DATA FOR COMPARISON ETH 302 (L/kg) 1.34 (-} PCE Conc. (mg/L) .0 .0 Common R (used in model)* = 1.16 TCE Cone. (mglL) .0 .0 4. BIOTRANSFORMATION -1st Order Decay Coefficient* DCE Conc. (mg/L) .002 .001 Zone 1 11 r half-life rs Yield (VC Conc. (mg/L) .001 .0 PCE TCE 12.000 F 1.20 0.79 ETH Conc. (mg/L) 0.0 0.0 TCE DCE 20.000 F 0.00 0.74 Distance from Source (ft) 0 100 DCE VC 1.000 F 1,50 0.64 'Date Data Collected 2023 VC ETH 6.000 F 2,60 0.45 8. CHOOSE TYPE OF OUTPUT TO SEE: Zone 2 <::::� 1/ r half-life ( s) PCE -). TCE 12.0010 +- 1.20 TCE -� DCE 20.F 0.90 HELP RUN CENTERLINE DCE -i VC 1.0F 1,50 VC -3 ETH 6.0F 2.60 HelpLR�] RESET RUN ARRAY SEE OUTPUT Paste Dift nee Mmn Source 1 mo p r Su PCE m 9.. TCE � ❑4aa 5S0 9 Su DCE $0.010 sw Vc V owl a 200 Sw Sol] go low Inn 1400 11500 ,a00 Distance From Source (ft.) tins: Pnlpma AnimaH° UnPrdetl T.A. To Agar I Log 4� Linenr Sheet out DISSOLVED CHLORINATED SOLVENTCONCENTRATIONS ALONG PLUME CENTERLINE (mga.).[Z=0 Distance tram Source in) TCE I 0 I 55 I ... 185 220 2l5 330 3e5 440 4S5 55D xo on.datlon O.Wi 0.921 O.Oz1 0.026 9.025 0.024 P023 Owl 7., 0.020 0.019 &o4meramvtion .................................. 0.02T0 O.m1 O.Om O.m0 9m0 0.Ow O.Ow O.Om O.Om 0.0m 0.00( M.nih.ring wx Location. Oft) 0 loll 1 1❑w 18m m an n.Drmm 9a. 0m o oam . O.m0 0000 �x.orP.darmP.a.Ta, �s.mmral,aaaero«a,• nax walmn vh 1 roll Sa. PCE 2 E❑.100 bw TCE - sw ocE 5 0010 s5g SSu VC 11 S.. ETH 9.001 0 200 400 Boll 8m 1000 1N10 1400 1000 Iwo Distance From Source (N.) Tlmc Gill Yea•'s poled Prepare Animation I� Ta All To-- Lee G,�? Linear Bheel Input DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mgfL) atZ=Q Distance from Source (ft) DCE 0 55 110 165 Zm 275 330 3&5 440 495 5w H, Degradation n031 0031 0.031 0.021 O011 1121 1.011 0.O2S 0.024 0023 0.022 Bt.sansf.matim omlo Owl oow o. OUl5 U. Om4 Moot Oml Om1 Om0 __ ...... _ ....... MoriMring Wei Lo..f- (ft) 0 tm tom Iw0 FWd Dmiom Site Um2 0nt 0m0 0Dm -x.Depnmtndnm�m �mealao�,o®r = FmoanPanse Om See PCE J E O tm see TCE 0 i50 sea DCE a auto I �VC c D Om1 See ETH a 200 400 6m 000 1w0 Iwo 1400 two 1w0 Distance From Source (ft.) T Prepare AMnod., � US4.o� R Pu[tn T. All T.- DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mgfL) at 2=0 Vc low Sce PCE a E 0100 see TCE ° See DCE 0 0010 See YC ° 550 D Mm1 SeeETH 0 200 4m 600 Son 100 1200 11400 Iw0 11300 D"stance Fran Source (ft.) Time m: m Prepare AnimtiUr�prr Reo m TO All on TOA Unear Sheen input DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE {mgfL) at Z=0 Distance from Source (ft) E7K ❑ 55 11❑ 165 22❑ 275 3T0 355 440 495 i50 No De9mdzron cow .tiro 0.ma 2 m0 Dom O.wo Mm0 OOw Oam O.mO Om0 Biaransfonnatien 0.00110 0.016 0.028 o.o. 0.037 0.037 0.037 O.Ow 0.035 0.031 O.W3 Mmitaing Wei Locations (it) 0 IUD tow 1W0 FieldDC cow 0 coca 0000 -x.0egamrer�n�m �rurmealeomomr = ,.nomrmn� 0m -PCE ZI = 0.700 See TCE ° see DCE 0010 see vc !°1 owF_ Sce ETH 0 200 400 600 am Imo 1200 1400 1600 1" Distance Fram Source (ft.) T- 6O PrepareAnimmtion artL�4=�lrnwr TO All TO Amry Ol.0rce hour Soo M) PCE 0 55 110 185 220 1 2. 1 . 1 3R5 1 440 496 550 __ NO Cegrada,on 0.110 0.1]0 0.16] 0.182 O.155 0.140 0142 1 0.136 0.131 0.,25 0.121 Blotransl.rmation 0.17m one 0"O.W OWCmi) Oom 0000 ow0 0006 O❑m Moralwing Wea Locellon. (ft) 0 1n 7n0 16m FI.M IAta fran slN o goo now o aw a our -napw.ammaata4m �.an.rnn«n�o.r,r mxP.H�an aR O o S.. PCE J S.. TCE E 0.100 554 C aw DCE 1 0.0,0 sw VC U owl 0 Roll 4m ew an I300 1200 1403 1000 1w0 Distance From Source (ft.) TM.: 100 o Years m Pe.pve Arimetlan u"n'°te`I R.turn I To All To Amy Lag (? Linear Sheet In DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (.I of Z=0 Distnce ir.m Source (ft) TCE ❑ 35 110 Iw 220 225 3m 385 440 4J5 550 N.I egrxd.wn o627 O02i s.021 0026 0025 om, 0023 a.02z 0021 0020 Oo19 ahxmnsmmaaw 00270 000, coon ❑our cow ❑coo owo- bon Moro o000 0000 Monitoring Wei Locations lNl 0 1m om low Iwo ala rmmsae F;MDaom Moog Mown -xouev'+e3Fu�+a.e.so. �.nea�„aaa=u®r = wn gaar�..� loon See PCE E 0.700 Su TCE ° see DCE _ 550 12 � 001a Sce YC O owl 77- ee SETH mHIMroll 0 200 4am 9,Ino 1400 1fim 1000 Distance From Source M.) r 00❑ Years Prepare Animation TO All TO Amry DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mgfL) at Z=0 Distance from Source lft) DCE 0 1 55 Ile 1 165 1 220 275 330 395 440 495 550 No Degratlation 0.031 Mm1 Mm1 Oo29 o02S O027 0.026 0025 0624 00n ban Eiotranetamation 00310 owl OWo028 0.015 O. 0. Om2 Owl Maul (I Monitom° W.11 Lotion. Oft) -x.g.Paaa.wnad�..-s�a�ei,auae,g®, . r�r,gs.ra.� 1Ow See PCE J E 0100 see TCE 0 95i0 see DCE S 0, 0 see vc 0m, 7 seeEm 0 200 4m SonSon1" 1200 1400 lem 1. Distance From Source (ft) T : }a00 Unproecl Remmm Prepare Animation L��SUr�r Sheet InPN TO All TOAmy DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mgfL) m Z-0 Di.Mnce from Source (ft) Yc 0 55 11g 1pd 220 275 3m 305 440 495 550 NODegradation 0.Ow 0.005 0.m5 O.Om O.Ow 0.009 D.w4 0.004 0.004 9.w4 0.g14 Blotianfannation 00050 OOn low O0gi O. Om1 owl Dmg 0000 Ow0 low _.. _.. _. _... _. _.. _. _... Monitoring VM Locations (ft] 0 FieMDaoMP.,sm MnIOW 0 -xngeY.mo.a�a�.n �e.nn.a,.lo.e.g®r = nnnpan,mnsr ton -PCE A see TCE E Mica ° See DCE C 0010 u See YC 9550 U 0 mi See ETH 0 200 400 600 Bn 7m0 72n 1400 two two Distance From Source (ft.) T Remmm troll Prepare Animation Unprotect To-, L.9 �iLInl� sheet Inpu[ TOAmy DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mgfL) at 2=0 DmI from Source (ft) ETM 0 55 lIM 165 2N ZP5 33❑ 385 440 495 W No Degradation OOm O.mo Dom Oo00 O.mO Dow o.w0 two Dow O._ Dow nintramrwmatim Omm 001fi 0028 0034 Owl 0031 O.w0 Owfi 0035 Om4 oon Monitoring Well Locations (R) ❑ IN low lew r,ed Dffi M.m Site 0 no onto Own o0w -n.geenm.wnnamm 0w �,mnaln namrD.�r = Ran gaarmn sn see PCE m E D.tw see TCE ° See DCE 0010 see vc U D.wt see ETH 0 2m 4m fim Boo 1000 1200 1400 into two Distance From Source (ft.) Tine: im0 Years Unpruletl Prepare Animation Remm t.� To RII TOR L Linear Shoe, InPur wsp.com