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3901_Granville_Oxford_MSWLF_CDLF_Unit1_March23GW_FID1812285_20230728
hart '-4 hickman SMARTER ENVIRONMENTAL SOLUTIONS Via E-Mail sbray@garTett-moore.com July 25, 2023 Garrett & Moore, Inc. 1029 West South Street Raleigh, NC 27603 Attn: Mr. Stefan Bray, PE Re: Water Quality Monitoring Report — March 2023 Granville County Oxford Unit 1 Landfill Oxford, Granville County, NC Facility Permit No. 3 901 -CDLF- 1997 H&H Job No. GMI-004 Dear Stefan: Hart & Hickman, PC (H&H) is submitting the attached Water Quality Monitoring Report — March 2023 documenting sample results for the Oxford Unit 1 Landfill for the first semiannual sampling event of 2023. H&H appreciates the opportunity to work with you on this project. If you have any questions or require additional information, please do not hesitate to contact us at 704-586- 0007. Very truly yours, Hart & Hickman, PC Jason Soban, PG Project Manager Jeffrey 011ison Project Environmental Scientist 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 704.S86.0007 main 3921 Sunset Ridge Rd, Suite 307 Raleigh, NC 27607 www.harthickman.com 919.847.4241 main ENR USE ONLY ❑Pager Report ❑Electronic Data - Email CD (data loaded: Yes / No j Doc/Event #: INC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Garrett & Moore, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Stefan Bray Phone: 919-792-1903 E-mail: sbray@garrett-moore.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .164Q) October 20-24, 2006) Granville County 6854 Landfill Road 3901-CDLF-1997 1600 March 29-30, 2023 Oxford Landfill Unit 1 Oxford, NC 27565 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring X Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells ❑X Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) MNA Parameters Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Jason Soban, PG Consultant for Facility (704) 887-4622 Facility Representative Name (Print) Title (Area Code) Telephone Number �� r a��yes j� 3 Affix NC Licensed/ Professional Geologist Seal Signature ^ f Date 2923 S Tryon Street, Suite 100, Charlotte, NC 28203 Facility Representative Address C-1269 (Engineering) 245 (Geology) NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 ',���µu a r rprly!! .•a� , k CAR '�.. SIN Z SEAL 2318 s �: ON • • ,4440011 lrl!! N 6100 Water Quality Monitoring Report March 2023 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 July 25, 2023 GARRETT ►■ & MOORE / Engineering for the Power and Waste Industries hart 19 hickman SMARTER ENVIRONMENTAL SOLUTIONS 2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301 Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com 704.586.0007 main 919.847A241 main Water Quality Monitoring Report — March 2023 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 Table of Contents Section Pate 1.0 Introduction.................................................................................................................I 1.1 Site Information........................................................................................................1 1.2 Regulatory Status......................................................................................................2 1.3 Groundwater Monitoring Program...........................................................................4 1.4 Surface Water Monitoring Program.........................................................................5 2.0 Water Quality Monitoring Activities........................................................................7 2.1 Water Level Measurements......................................................................................7 2.2 Groundwater Sampling Methods..............................................................................7 2.3 Surface Water Sampling Methods............................................................................8 2.4 Sample Equipment Management..............................................................................9 2.5 Sample Handling and Laboratory Analyses.............................................................9 3.0 Water Quality Monitoring Results..........................................................................10 3.1 Groundwater Flow and Hydraulic Gradient...........................................................10 3.2 Groundwater Analytical Results.............................................................................11 3.3 Surface Water Analytical Results...........................................................................13 3.4 Quality Assurance/Quality Control Results............................................................14 4.0 Corrective Action Evaluation..................................................................................15 4.1 Monitored Natural Attenuation Parameters............................................................15 4.2 Evaluation of Plume Stability and Trends..............................................................15 5.0 Conclusions ................................................................................................................18 i https://harthick.sharepoint.com/sites/MasterFiles-t/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR March 2023.docx hart hickman SMARTER ENVIRONMENTAL SOLUTIONS List of Tables Table 1 Summary of Well Construction Details Table 2 Summary of Groundwater Elevations Table 3 Summary of Field Parameters Table 4 Summary of Groundwater Flow Velocity Table 5 Summary of Groundwater and Surface Water Constituent Detections Table 6 Summary of Monitored Natural Attenuation Parameters List of Figures Figure 1 Site Location Map Figure 2 Site Plan Figure 3 Groundwater Potentiometric Map (March 2023) List of Appendices Appendix A Groundwater and Surface Water Sampling Records Appendix B Laboratory Analytical Reports Appendix C Summary of Historical Groundwater Elevations Appendix D Summary of Historical Constituents in Groundwater Appendix E Summary of Historical Constituents in Surface Water Appendix F Summary of Historical Monitoring Natural Attenuation Parameters Appendix G Concentration vs. Time Charts ii Adhttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 hart First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx � k m a n h i SMARTER ENVIRONMENTAL SOLUT1ON5 Water Quality Monitoring Report — March 2023 Granville County Oxford Unit 1 Landfill Oxford, North Carolina Permit No. 3901-CDLF-1997 H&H Job No. GMI-004 1.0 Introduction This Water Quality Monitoring Report (Report) has been prepared by Hart & Hickman, PC (H&H) to document the methods and results of semi-annual groundwater and surface water monitoring activities conducted at the Granville County Oxford Unit 1 Landfill located at 6584 Landfill Road, Oxford, Granville County, North Carolina. A site location map is included as Figure 1. Water quality monitoring at the site was performed in general accordance with the Corrective Action Plan (May 2005) and Water Quality Monitoring Plan (March 2019) which were approved by the North Carolina Department of Environmental Quality (DEQ) Solid Waste Section (SWS). 1.1 Site Information The Granville County Oxford Landfill consists of two separate waste disposal units (Unit 1 and Unit 2). The facility is owned and operated by Granville County under Permit Numbers 3901- CDLF-1997 (Unit 1) and 3901-MSWLF-2012 (Unit 2) issued by DEQ SWS. The permitted facility consists of approximately 283 acres, of which approximately 29 acres constitutes the Unit 1 waste unit and 37.3 acres constitutes the Unit 2 waste unit. A site layout map that depicts the facility features is included as Figure 2. The subject Oxford Unit 1 Landfill is a former unlined municipal solid waste (MSW) landfill originally permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes. The Oxford Unit 1 Landfill was closed in 1997. Between 1997 and 2017, the facility disposed of construction and demolition (C&D) waste on top of the closed MSW landfill in accordance with the Transition Plan dated 1994. The Oxford Unit 2 Landfill is a Subtitle-D MSW landfill which was permitted to operate in February 2013 and began receiving waste in May 2013. This report covers water quality monitoring conducted at the Oxford Unit 1 Landfill. A separate Water Quality Monitoring Report will be submitted for the Oxford Unit 2 Landfill. 1 https://harthick.shmepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit 1_WQMR March 2023.docx hart hickman SMARTER ENVIRONMENTAL SOLUT10N5 1.2 Regulatory Status The Oxford Unit 1 Landfill has remained in an Assessment Monitoring Program since 1995 due to detections of volatile organic compounds (VOCs) above the North Carolina 2L Groundwater Standards (2L Standards). In 2003, benzene (MW-4R) and vinyl chloride (MW-5) were detected in site groundwater at concentrations above their respective 2L Standards. Benzene has not been detected above its 2L Standard since 2003. Vinyl chloride has been detected above its 2L Standard from 2003 to present. Granville County received a letter from DEQ dated August 20, 2003, that requested to proceed with assessment activities at the Oxford Unit 1 Landfill. An overview of the site regulatory status including changes to the monitoring program is provided below. 2003 through 2005 Nature and Extent Study and Assessment of Corrective Measures An Assessment of Corrective Measures (ACM) and Nature and Extent Study (NES) were initiated in 2003 due to 2L Standard exceedances of benzene (MW-4R) and vinyl chloride (MW-5R) in site groundwater. In May 2005, Granville County submitted an NES, ACM, and a Quantitative Risk Assessment (QRA) as required by DEQ. Granville County held a public meeting for the ACM on August 21, 2006. 2008 through 2010 Corrective Action Plan A Corrective Action Plan (CAP) was submitted in June 2008, with revisions in October 2008 and March 2009. The CAP proposed Monitored Natural Attenuation (MNA) as the primary remedy, supplemented with Control of Decomposition Gasses as a secondary remedy. The CAP was approved by DEQ on April 23, 2009. The gas interception trench was installed in July 2009. The last sampling event for the Baseline MNA was completed in December 2010. 2010 Alternate Source Demonstration for Iron and Manganese An Alternate Source Demonstration (ASD; dated October 26, 2010) for Iron and Manganese was submitted to DEQ after the requirements for additional constituent monitoring for C&D facilities showed elevated concentrations of iron and manganese across multiple site wells in June 2010. The ASD showed that the concentrations of iron and manganese were a result of natural occurrence 2 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 in site soil and not a release from the landfill. The ASD for Iron and Manganese was approved by DEQ on June 9, 2011. 2010 First Corrective Action Evaluation Report The first Corrective Action Evaluation Report (CAER) was submitted to DEQ on November 29, 2010, and approved by DEQ on January 27, 2011. Based on the data presented in the CAER, DEQ denied a request to remove some of the MNA parameters but approved a reduced alternate monitoring frequency as follows; carbon dioxide, ferrous iron, volatile fatty acids, total organic carbon (TOC), sulfide, and dissolved ethane and ethene for every third year on a semi-annual basis. DEQ also approved removing benzene and cis-1, 2-dichloroethene from the constituent of concern (COC) list and adding 1, 1 -dichloroethane. An ASD for chromium, thallium, and total dissolved solids (TDS) in MW-lA was included in the 2010 CAER and was also approved by DEQ. 2012 COC List Update In February 2012, beta-BHC was added to the COC list due to a confirmed exceedance during the December 2011 sampling event. 2014 Monitoring Program Changes Changes to the monitoring program were requested in a letter submitted to DEQ on May 22, 2014. The following changes were approved by DEQ in their June 3, 2014 response letter: monitoring wells MW-2, MW-3R, MW-4R, and MW-6R reverted back to detection monitoring (Appendix I constituents) from assessment monitoring (Appendix II constituents); NES-1S and NES-1D were removed from the groundwater corrective action monitoring network; and, sampling for MNA parameters in monitoring wells MW-3RR and MW-4R was discontinued. 2015 Second Corrective Action Evaluation Report The second CAER was submitted to DEQ on July 10, 2015, and approved by DEQ on July 30, 2015. The DEQ approval included the removal of 1,1-dichloroethane and beta-BHC from the COC list due to the lack of recent exceedances. This left vinyl chloride as the only COC for the facility. 3 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 2018 and 2019 Water Quality Monitoring. Plan A Water Quality Monitoring Plan (WQMP) for the Oxford Landfill Units 1 and 2 was submitted to DEQ in January 2018 and revised in March 2019. The WQMP describes the sampling protocols for groundwater and surface water monitoring at the site. The WQMP included 1,4-dioxane as a COC due to a confirmed exceedance during the August 2018 sampling event. 2020 Third Corrective Action Evaluation Report The third CAER was submitted to DEQ on June 5, 2020, and approved by DEQ on June 22, 2020. The DEQ approval included the removal of Biochlor modeling since site constituents have changed from anaerobic to aerobic, and the modification of the sampling frequency of the MNA parameters sulfide, volatile fatty acids, TOC, dissolved carbon dioxide, ferrous iron, ethane, and ethene to two events every five years corresponding to the two events immediately prior to the due date of the next five year CAER. 1.3 Groundwater Monitoring Program The groundwater monitoring program at the Oxford Unit 1 Landfill consists of the following six monitoring wells: MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, and MW-7. Monitoring well MW-7 is located southeast of the landfill and serves as a background location. The compliance network consists of monitoring wells MW-2, MW-3RR, MW-4R, MW-5R, and MW-6R which are situated around the perimeter of the landfill. Monitoring well MW-lA (a former background well) is only monitored for groundwater elevations. In addition, performance well NES-2S and sentinel well NES-213 are located downgradient of the landfill and sampled under the CAP for the facility. Monitoring well NES-2S is also a compliance well for the Oxford Unit 2 Landfill and MW-7 is a background well for Oxford Unit 2. The monitoring well locations and other site features are identified in Figure 2. A summary of well construction details is provided in Table 1. Groundwater samples are collected semi-annually (with the exception of NES-21) only sampled annually during the spring event) for select analyses per the WQMP. Sample analyses include North Carolina Solid Waste Management Rules Appendix I and/or Appendix II constituents 4 hart � hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 (hereafter referred to as Appendix I constituents and Appendix II constituents, respectively), select C&D parameters (alkalinity, chloride, iron, manganese, mercury, sulfate, total dissolved solids [TDS], tetrahydrofuran, pH, temperature, and specific conductance), and/or COCs (i.e., 1,4- dioxane and vinyl chloride). The required Appendix II sample analysis for select groundwater monitoring wells during the second half semi-annual event varies and is limited to those analytes detected in that well during the first half semi-annual event each year. As noted above, the site's full list of MNA parameters is collected during two events every five years corresponding to the two events immediately prior to the due date of the next five-year CAER (i.e., second half event 2024 and first half event 2025). However, a reduced list of MNA parameters (alkalinity, chloride, dissolved hydrogen, dissolved methane, nitrate, sulfate, pH, temperature, specific conductance, oxidation reduction potential [ORP], turbidity, and dissolved oxygen [DO]) are collected semi-annually from select monitoring wells (NES-2S, MW-5R, and MW-7) and annually from the sentinel well (NES-2D). A summary of the well locations and sample analyses for the semi-annual sampling events is provided below. Well ID Classification First Half Analyses Second Half Analyses MW-lA Observation Not Sampled Not Sampled MW-2 Compliance App. I, C&D App. I, C&D MW-3RR Compliance App. I, C&D App. I, C&D MW-4R Compliance App. I, C&D App. I, C&D MW-5R Compliance App. I, App. II, C&D, MNA App. I, Det. App. II, C&D, MNA MW-6R Compliance App. I, C&D App. I, C&D MW-7 Background App. I, App. II, C&D, MNA App. I, Det. App. II, C&D, MNA NES-2S Performance COCs, MNA COCs, MNA NES-2D Sentinel COCs, MNA Not Sampled App. I = Appendix I Constituent; App. II = Appendix II Constituent; Det. = Detected 1.4 Surface Water Monitoring Program The surface water monitoring program at the Oxford Unit 1 Landfill consists of collecting samples from two locations which are located upstream (SW-1) and downstream (SW-2) of the waste unit. 5 hart � hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 Sampling point SW-1 is located in a sedimentation basin near the upgradient southeast corner of Unit 1. Sampling point SW-2 is located downgradient and southeast of Unit 1 along an unnamed tributary to Little Grassy Creek. Little Grassy Creek is classified as a Class C (Aquatic Life and Secondary Recreation) stream. The locations of the surface water monitoring points are identified in Figure 2. Surface water samples are collected semi-annually and analyzed for Appendix I constituents plus 1,4-dioxane. 0 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 2.0 Water Quality Monitoring Activities 2.1 Water Level Measurements On March 29, 2023, H&H measured depth -to -water and total depths in monitoring wells MW-lA, MW-2, MW-3RR, MW-4R, MW-5R, MW-6R, MW-7, NES-2S, and NES-213. Depth -to -water measurements were collected from the top -of -casing utilizing a decontaminated electronic water level indicator. Depth -to -water measurements were made after the wells were opened for a sufficient period of time to allow water levels to equilibrate with atmospheric pressure. Water level measurements and calculated groundwater elevations are presented in Table 2. 2.2 Groundwater Sampling Methods On March 29 and 30, 2023, H&H collected groundwater samples from site monitoring wells MW- 2, MW-3RR, MW-4R, MW-5R, MW-6R, MW-7, NES-2S, and NES-213. Monitoring well MW- 7 serves as the upgradient background well for the facility, and monitoring wells MW-2, MW- 3RR, MW-4R, MW-5R, MW-6R, NES-2S, and NES-213 serve as compliance monitoring wells. In accordance with the WQMP, monitoring well NES-213 is sampled annually and sampling at this location completes its annual sampling requirement. The groundwater samples were collected and handled in general accordance with the sampling protocols included in the site WQMP as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water Sampling document. Monitoring wells were purged utilizing a peristaltic pump under low flow (< 200 milliliters/minute) conditions. Water levels were recorded during the purging process to ensure the pump rate did not cause significant drawdown of the water column, and samples were collected following the stabilization of field parameters over three consecutive readings. Field measurements of pH, temperature, specific conductance, ORP, and DO were measured using a YSI Pro Plus or YSI 556 water quality meter. Turbidity was measured using a HF Scientific Micro TPI or Hach 2100Q turbidity meter. A summary of the final field parameters recorded prior to sample collection are presented in Table 3. Copies of groundwater sampling forms containing 7 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 pertinent information recorded in the field during purging and sampling at each monitoring well are provided in Appendix A. The results of the field -measured water quality parameters indicate that the values measured in groundwater collected from site monitoring wells were generally within applicable stabilization criteria. The water levels generally exhibited slight or stable drawdown during the purging process; however, water levels in MW-4R and NES-21) were observed to continue to drawdown during low flow pumping conditions. As discussed in Section 3.2, the data indicate similar analytical results in comparison to prior sampling events, and the drawdown is not considered to affect the usability of the reported results. During future sampling events, additional time to achieve stable drawdown and/or alternative purge methods (volumetric purging) may be used to sample these locations. Groundwater at the site is slightly acidic to slightly basic based on the pH values measured in the field (5.24 to 7.61 Standard Units). Specific conductance values ranged from 63 (MW-2) to 998 (MW-6R) microsiemens per centimeter (µS/cm) in groundwater at site monitoring wells. Turbidity values ranged from <0.01 (MW-4R, NES-2S, and NES-21)) to 75.38 (MW-2) nephelometric turbidity units (NTUs). The collected groundwater sample from MW-2 exhibited a turbidity above the target level of 20 NTU; however, considerable time was spent purging the well at a low flow rate to achieve a lower turbidity sample, and the turbidity level was similar to historic sampling data at the time of collection. 2.3 Surface Water Sampling Methods On March 30, 2023, H&H collected surface water samples from sample locations SW-1 and SW- 2 (Figure 2). Surface water samples were collected in general accordance with the WQMP as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water Sampling document. Field parameters were measured during sample collection and copies of surface water sampling forms are provided in Appendix A. A summary of field parameters recorded prior to sample collection is provided in Table 3. https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx hart hickman SMARTER ENVIRONMENTAL SOLUPON5 2.4 Sample Equipment Management All reusable sampling equipment (e.g., water level indicator) was properly decontaminated between sampling locations with a non -phosphate soap and water wash, followed by multiple rinses with distilled water. New disposable nitrile gloves were worn during all sampling activities. Disposable sampling equipment/material was discarded after each use. 2.5 Sample Handling and Laboratory Analyses Upon sample collection, samples for laboratory analysis were placed directly into dedicated laboratory -supplied sample bottles, labeled, and placed into ice -filled coolers. A chain -of -custody record was completed and included sample description, analyses required, matrix, sample container information, and date and time of sample collection. The samples were transported on ice, under standard protocol, to Pace Analytical Services, LLC (Pace) a North Carolina -certified laboratory. The laboratory analytical reports and chain -of -custody records for the March 2023 sampling event are included in Appendix B. A summary of samples collected during the subject reporting period is provided below. The groundwater samples from monitoring wells MW-2R, MW-3RR, MW-4R, and MW-6R were analyzed for Appendix I constituents plus 1,4-dioxane and C&D parameters. The groundwater samples from monitoring wells MW-5R and MW-7 were analyzed for Appendix I constituents plus 1,4-dioxane, Appendix II constituents, C&D parameters, and MNA parameters. The groundwater samples from NES-2S and NES-213 were analyzed for COCs (i.e., vinyl chloride and 1,4-dioxane) and MNA parameters. The surface water samples from SW-1 and SW- 2 were analyzed for Appendix I constituents plus 1,4-dioxane and hardness. 0 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 3.0 Water Quality Monitoring Results Groundwater and surface water monitoring activities were conducted at the site on March 29 and 30, 2023. Groundwater and surface water samples were collected and analyzed in accordance with the DEQ approved CAP, changes to the CAP documented in DEQ approved CAERs (November 2010, July 2015, and June 2020), and the DEQ approved WQMP (March 2019). The monitoring results are discussed in the following sections. 3.1 Groundwater Flow and Hydraulic Gradient A summary of monitoring well gauging and water level elevation data is provided in Table 2. Historical groundwater elevation data is provided in Appendix C. Groundwater flow direction, average hydraulic gradient, and average interstitial flow velocity were derived from water -level measurements recorded during the March 2023 sampling event. A potentiometric map generated from the March 2023 gauging event is provided as Figure 3. The March 2023 water levels were similar to historical seasonal fluctuations observed at the site. Consistent with historical trends, the overall direction of shallow groundwater flow at the site is generally north to northeast towards an unnamed tributary to Little Grassy Creek. The hydraulic gradient in the vicinity of each well was derived by dividing the elevation difference between water table elevations measured at the monitoring wells and proximal potentiometric contour lines, by the perpendicular horizontal distance between the wells and potentiometric contours (Figure 3 and Table 4). The potentiometric contours indicate an average hydraulic gradient of approximately 0.025 ft/ft. Results of in -situ slug testing reported by others (LaBella Associates, 2021) indicate an average hydraulic conductivity value in the shallow surficial aquifer of approximately 7.31 x 10-2 feet/day (approximately 26.7 feet/year). Using the horizontal hydraulic gradient measurements, the individual estimate of hydraulic conductivity, and an assumed effective porosity of 0.31 (LaBella Associates, 2021), the range of average interstitial groundwater flow velocities for the shallow surficial aquifer was calculated using the following equation: Vx = (K/nc) x dh/dl. 10 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx Where: Vx = average interstitial groundwater flow velocity; K = hydraulic conductivity; nc = effective porosity; and, dh/d1= horizontal hydraulic gradient Average linear flow velocities are estimated to range between approximately 0.51 to 4.15 feet/year (approximately 0.001 to 0.011 feet/day), with a geometric mean of 2.14 feet/year (0.006 feet/day). These values are generally consistent with prior monitoring events. Table 4 summarizes the data used to calculate the average interstitial groundwater flow velocity in the vicinity of each monitoring well. 3.2 Groundwater Analytical Results Semi-annual groundwater sampling consisted of collecting samples from eight site monitoring wells. A summary of groundwater constituent detections from the March 2023 sampling event is provided in Table 5. Historical analytical results are presented in Appendix D. Consistent with the CAP and subsequent changes documented in DEQ approved CAERs, the primary COCs for the site include 1,4-dioxane and vinyl chloride. A summary of groundwater results for site COCs and other exceedances is provided below. Appendix I & II VOCs The analytical results indicate chlorobenzene, 1,1-dichloroethane, 1,2-dichlorobenzene, 1,4- dichlorobenzene, 1,4-dioxane, methylene chloride, and vinyl chloride were detected at concentrations above laboratory method detection limits (MDLs) in one or more wells during the March 2023 sampling event. 1,4-Dioxane (up to 58.6 µg/L) was detected at a concentration above its 2L Standard (3 µg/L) in monitoring wells MW-3RR, MW-4R, MW-5R, and MW-6R. The detections of 1,4-dioxane are consistent with historical detections at these locations. Vinyl chloride was detected at an estimated concentration above its North Carolina 2L Groundwater Standard (2L Standard; 0.03 µg/L) in monitoring well MW-5R (0.81 J µg/L). The estimated concentration of vinyl chloride includes a v3 flag which indicates the continuing calibration 11 hart !%im hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 verification was below the method acceptance limit, and any detection for the analyte in the associated samples may have low bias. However, as the estimated concentration of vinyl chloride is within the range of historical detections at this location the v3 flag does not impact the conclusions of this report. No other VOC constituents were detected above 2L Standards during the March 2023 sampling event. Appendix I & II Metals The analytical results indicate metals arsenic, barium, chromium, cobalt, copper, iron, manganese, nickel, vanadium, and zinc were detected at concentrations above MDLs in one or more wells during the March 2023 sampling event. Cobalt (up to 9.52 J µg/L) was detected at estimated concentrations above its 2L Standard (1 µg/L) in monitoring wells MW-2 and MW-3RR, and concentrations are consistent with historical detections at these locations. Iron (up to 6,320 µg/L) was detected at concentrations above its 2L Standard (300 µg/L) in monitoring wells MW-2, MW- 3RR, and MW-6R, and concentrations are consistent with historical detections at these locations. Manganese (up to 2,890 µg/L) was detected at concentrations above its respective 2L Standard (50 µg/L) in monitoring wells MW-2, MW-3RR, MW-4R, MW-5R, and MW-6R, and concentrations are consistent with historical detections at these locations. Metals iron and manganese have been demonstrated and approved to be naturally occurring at the site. Vanadium (7.11 J µg/L) was detected at an estimated concentration above its 2L Standard (7 µg/L ) in monitoring well MW-2, and concentrations are consistent with historical detections at this location. No other metal constituents were detected above 2L Standards during the March 2023 sampling event. Appendix II Additional Anal The analytical results indicate that Appendix II Semi-VOCs (SVOCs), pesticides, herbicides, and polychlorinated biphenyls (PCBs) were not detected above MDLs in the groundwater samples collected from MW-5R and MW-7 C&D Parameters C&D parameters alkalinity, chloride, and sulfate were detected at concentrations above MDLs in one or more wells during the March 2023 sampling event, and concentrations are consistent with historical detections. TDS was detected at a concentration above its 2L Standard (500,000 µg/L) 12 hart hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 in monitoring well MW-6R (647,000 µg/L), and concentrations are consistent with historical detections at this location. C&D parameters mercury and tetrahydrofuran were not detected above MDLs in groundwater samples collected during the March 2023 sampling event, and analytical results for iron and manganese are discussed in the metals section above. 3.3 Surface Water Analytical Results Semi-annual surface water sampling consisted of collecting samples from one upstream (SW-1) and one downstream (SW-2) location. A summary of surface water constituent detections from the March 2023 sampling event is provided in Table 5. Historical analytical results are presented in Appendix E. A summary of the surface water results in provided below. VOCs The analytical results indicate 1,4-dioxane was detected in SW-2 (0.89 J µg/L) at an estimated concentration above the laboratory MDL, and concentrations are consistent with historical detections at this location. North Carolina has not established a North Carolina 213 Water Quality Standard for Surface Water (213 Standard) for 1,4-dioxane; however, the results indicate the concentration is below the respective North Carolina In -Stream Target Value for Surface Water (ISTV). No other VOCs were detected above MDLs during the March 2023 sampling event. Metals The analytical results indicate arsenic, barium, chromium, cobalt, copper, nickel, vanadium, and zinc were detected above the laboratory MDL in one or both of the surface water samples collected during the March 2023 sampling event. The detected concentrations of arsenic, chromium, copper, nickel, and zinc do not exceed the 2B Standards and are generally consistent with historical data. Barium and cobalt do not have 213 Standards and the detected concentrations were compared to their respective North Carolina In -Stream Target Value for Surface Water (ISTV), and there were no exceedances. There are no screening criteria established for comparison of vanadium results. No other constituents were detected above MDLs during the March 2023 sampling event. 13 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 3.4 Quality Assurance/Quality Control Results Quality assurance procedures and protocols for sampling activities were conducted in general accordance with the DEQ approved CAP and WQMP. Quality assurance samples included the collection of trip blanks and a field blank sample. Samples were received by the lab in good condition and met holding times and preservation requirements. Based upon a review of the data packages, no significant quality assurance/quality control (QA/QC) issues were identified for the laboratory analyses. In summary, the QA/QC results indicate that the data collected during the semiannual monitoring event is suitable for its intended purpose. Trip Blanks Laboratory -filled trip blanks accompanied the sampling team during sampling and the transport of VOC samples to the laboratory. The trip blank samples serve as a QC check on potential external contamination and/or cross -contamination between VOC water samples during shipping and storage. The trip blank sample was analyzed for Appendix I VOCs and 1,4-dioxane. The results indicate methylene chloride was detected above MDLs in a trip blank sample at an estimated concentration of 2.0 J µg/L. Estimated detections of methylene chloride were also reported for samples collected from monitoring wells MW-2 and MW-4R. In addition, the methylene chloride detections reported for monitoring wells MW-2 and MW-4R we flagged with C9, L1, and vl indicators. These flags identify methylene chloride as a common laboratory contaminant and that the reported detections of this constituent in the monitoring wells may be biased high. No other constituents were detected above laboratory MDLs in trip blank samples. Fit-ld Rlnnkc A field blank sample was collected in the field by exposing laboratory -supplied deionized water to the sampling environment. The field blank is used to evaluate the potential for contamination of a sample by site contaminants from a source not associated with the samples collected. The field blank sample was analyzed for Appendix I constituents, Appendix II constituents, 1,4- dioxane, and C&D parameters. The results indicate no constituents were detected above laboratory MDLs. 14 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 4.0 Corrective Action Evaluation 4.1 Monitored Natural Attenuation Parameters Groundwater samples collected during the March 2023 sampling event from monitoring wells MW-5R, MW-7, NES-2S, and NES-21) were analyzed for MNA parameters. The groundwater NINA parameter results for the current sampling event are summarized in Table 6. Historical groundwater MNA parameter results are provided in Appendix F. A summary of the MNA parameters collected from the above locations is provided below: • NINA Field Parameters: temperature, pH, conductivity, ORP, turbidity, and DO. • MNA Laboratory Parameters: alkalinity, chloride, dissolved hydrogen, dissolved methane, nitrate, sulfate. Based on the June 22, 2020, response from DEQ to the CAER dated June 5, 2020, the MNA parameters including sulfide, volatile fatty acids, TOC, dissolved carbon dioxide, ferrous iron, ethane, and ethene will be analyzed for two events every five years, corresponding to the two events immediately preceding each CAER- The next CAER is due after the first half semi-annual sampling event of 2025. The MNA results from the current sampling event will supplement the comprehensive results collected for the five-year period to evaluate MNA as the remedy for this site, a discussion of the evaluation will be detailed in the next CAER. 4.2 Evaluation of Plume Stability and Trends As required by the CAP, this report includes an evaluation of plume stability and contaminant concentration trends based on analytical results obtained from performance well NES-2S. In addition, constituent exceedances at other compliance monitoring wells (i.e., MW-2, MW-3RR, MW-4R, MW-5R, and MW-6R) are discussed in this section. The March 2023 results indicate VOCs 1,4-dioxane and vinyl chloride; and metal compounds cobalt, iron, manganese, and vanadium are the only constituents detected in site groundwater at concentrations above 2L Standards. In addition, TDS was detected above its 2L Standard in one site well. As previously 15 hart � hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 noted, an ASD for the facility showed iron and manganese to be naturally occurring, and therefore, these compounds are not discussed in this section. Charts that depict constituent concentrations versus time for current (1,4-dioxane and vinyl chloride) and former (1, 1 -dichloroethane) site COCs are provided in Appendix G. A discussion of the concentration trends in site groundwater is provided below. 1,4-Dioxane As required by the DEQ SWS, beginning in 2018 groundwater and surface water samples collected at the site have been analyzed for 1,4-dioxane. Chart 1 presents a plot of 1,4-dioxane concentrations for monitoring wells with previous detections. The results of the March 2023 sampling event indicate 1,4-dioxane was detected above its 2L Standard in compliance monitoring wells MW-3RR, MW-4R, MW-5R, and MW-6R. As shown on the chart, the 1,4-dioxane concentrations are generally stable and current concentrations are consistent with historical detections at the site, with the exception of MW-3RR. In September 2022, a new landfill phase development at the Oxford Unit 2 landfill resulted in the abandonment of MW-3R and the installation of replacement well MW-3RR nearby (MW-3RR located approximately 100 ft south of former MW-3R). The results for the first completed sampling event of monitoring well MW-3RR indicated the highest detected concentration of 1,4- dioxane at the site to date (70.2 µg/L). However, the initial detected concentration of 1,4-dioxane in MW-3RR was similar to recent detections in site groundwater (up to 65.1 µg/L at MW-5R), and the most recent March 2023 detection concentration of 1,4-dioxane in monitoring well MW-3RR decreased to 20.2 µg/L and was similar to historic decisions in former MW-3R (ranged from 11.8 to 2 1. 0 µg/L). Site monitoring results indicate 1,4-dioxane exceedances are limited to compliance wells MW- 3RR, MW-4R, MW-5R, and MW-6R. The current results for locations downgradient of the landfill indicate 1,4-dioxane was not detected above the MDL in groundwater (NES-2S) and was detected below the 2B Standard in surface water (SW-2). This COC will continue to be monitored during future semi-annual sampling events. 16 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx Vinyl Chloride and 1, 1 -Dichloroethane Chart 2 and Chart 3 present a plot of vinyl chloride and 1,1-dichloroethane concentrations for monitoring well MW-5R, respectively. The charts demonstrate a continued decreasing trend for these constituents at MW-5R. DEQ approved the removal of 1,1-dichloroethane from the site COC list in 2015, and the current results indicate concentrations at this location continue to maintain a generally decreasing trend below its 2L Standard. The March 2023 results indicate that vinyl chloride concentrations at MW-5R (0.81 J µg/L) continue a generally decreasing trend but remain above its 2L Standard (0.03 µg/L). Site monitoring results indicate vinyl chloride detections and exceedances are limited to compliance monitoring well MW-5R. In addition, 1, 1 -dichloroethane was last detected above its 2L Standard in MW-5R during the June 2011 sampling event and concentrations have since generally decreased. Since there have been no detections of these compounds in samples collected from surface water at SW-2 or sentinel well NES-2S, there is no indication that the VOC impacts detected at MW-5R are migrating downgradient. These COCs will continue to be monitored during future semiannual sampling events. Cobalt and Vanadium The March 2023 sample results indicate cobalt (MW-2 and MW-3RR) and vanadium (MW-2) were detected above their respective 2L Standards. A review of historical data indicates current concentrations at these locations are comparable to prior detections at the site and the concentrations do not appear to be increasing. These metals were also previously detected in background well MW-7 at similar concentrations above the 2L Standard. As previously recommended, based on detections of these metals above 2L Standards, it is recommended that an ASD be conducted to establish background levels for cobalt and vanadium. Cobalt and vanadium will continue to be monitored during future semi-annual sampling events. 17 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx 5.0 Conclusions Semi-annual water quality monitoring activities were conducted at the site on March 29 and 30, 2023. The groundwater results indicate the landfill monitoring well network remains adequate to monitor the site. A review of plume stability and concentration trends indicates that the selected remedy of natural attenuation remains appropriate for the site. Based on the March 2023 results, trends for site COCs remain consistent with the prior sampling event and the facility will continue work in the Assessment Monitoring and Corrective Action programs. A summary of the results is provided below. • Consistent with historical trends, the overall direction of groundwater flow at the site is north to northeast towards an unnamed tributary to Little Grassy Creek. 1,4-Dioxane (MW-3RR, MW-4R, MW-5R, and MW-6R) was detected in groundwater at concentrations above its 2L Standard. The 1,4-dioxane concentrations are consistent with historical concentrations detected at each location, including replacement well MW-3RR where concentrations decreased and are consistent with historical results from nearby abandoned well MW-3R. • Vinyl chloride (MW-5R) was detected in groundwater at a concentration above its 2L Standard. The vinyl chloride concentration is consistent with historical concentrations at MW-5R and continue to show a generally decreasing trend. • Iron (MW-2, MW-3RR, and MW-6R) and manganese (MW-2, MW-3RR, MW-4R, MW- 5R, and MW-6R) were detected at concentrations above their respective 2L Standards; however, these metals have been demonstrated and approved to be naturally occurring at the site. The concentrations are consistent with historical detections at these locations. • Cobalt (MW-2 and MW-3RR) and vanadium (MW-2) were detected at concentrations above their respective 2L Standards, and the concentrations are consistent with historical detections at these locations. Based on consistent detections of these metals above 2L 18 hart � hickman https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx SMARTER ENVIRONMENTAL SOLUPON5 Standards, it is recommended that an ASD be conducted to establish background levels for cobalt and vanadium. • Surface water results indicate constituents were not detected at concentrations above their applicable surface water standards. 19 hart hickman SMARTER ENVIRONMENTAL SOLUPON5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/GMI.004 Granville County Oxford Unit l_WQMR March 2023.docx Table 1 Summary of Well Construction Details Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Ground TOC TOC Top of Bottom Total Depth Auger Screened Well ID Date Installed Northing Easting Elevation Elevation Screen Screen Refusal Comments (ft AGS) (ft BTOC) Lithology (ft AMSL) (ft AMSL) (ft BTOC) (ft BTOC) (ft BGS) MW-1A 952141.6930 2110755.3908 535.18 538.18 3.00` 10.00 25.00 25.00 > 22 Saprolite Not Sampled MW-2 -- 953940.0174 2110351.7384 517.00 518.62 1.62 14.12 29.12 29.12 21.00 Saprolite/Bedrock Unit 1 Compliance MW-3RR 9/8/2022 953933.99 2111630.18 500.82 503.37 2.55 21.97 26.55 26.55 25.00 Bedrock Unit 1 Compliance MW-4R 8/26/1999 954975.1334 2110797.9991 504.90 507.34 2.44 52.44 62.44 62.44 17.50 Bedrock Unit 1 Compliance MW-5R 8/25/1999 954947.2480 2111685.6720 487.24 489.95 2.71 29.71 39.71 39.71 22.00 Bedrock Unit 1 Compliance MW-6R 8/25/1999 954725.8325 2110287.6108 504.42 506.81 2.39 32.39 42.39 42.39 13.00 Bedrock Unit 1 Compliance NES-1S 5/1/2004 955167.9708 2111057.1915 514.35 516.93 2.58 21.08 36.08 36.58 27.00 Saprolite/Bedrock Not Sampled NES-1D 5/1/2004 955177.3548 2111054.7005 514.38 516.62 2.24 65.74 80.74 81.24 27.00 Bedrock Abandoned Unit 1 CAP NES-2S 5/1/2004 955091.290 2111945.3411 474.53 477.20 2.67 13.67 23.67 24.17 9.00 Saprolite Performance NES-2D 5/1/2004 955081.7805 2111946.7398 474.72 477.43 2.71 53.71 68.71 69.21 21.50 Bedrock Unit 1 CAP Sentinel Units 1 & 2 MW-7 7/28/2008 953292.1160 2112043.4480 531.24 534.24 3.00 22.5 37.50 37.50 34.50 Saprolite Background Well Notes: Well information obtained from LaBella Associates Water Quality Monitoring Report - February 2021 Event. MW-3RR survey data provided by Garrett & Moore, Inc. following the reinstallation of the well in September 2022. ft = feet; AMSL = above mean sea level; AGS = above ground surface TOC = top of casing; BTOC = below top of casing; ` = estimated value -- = unknown; CAP = corrective action plan Table 1 (Page 1 of /1) hltps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6.xlsx Hart & Hickman, Pl. Table 2 Summary of Groundwater Elevations Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Total Depth ( ft BTOC) TOC Elevation (ft AMSL) March 29, 2023 Depth to Groundwater (ft BTOC) Groundwater Elevation (ft AMSL) MW-1 A 25.00 538.18 6.47 531.71 M W-2 29.12 518.62 9.03 509.59 MW-3RR 26.55 503.37 14.14 489.23 MW-4R 62.44 507.34 9.06 498.28 MW-5R 39.71 489.95 19.89 470.06 MW-6R 42.39 506.81 7.05 499.76 M W-7 37.50 534.24 23.53 510.71 NES-2S 23.67 477.20 4.82 472.38 NES-2D 68.71 477.43 0.84 476.59 Notes: Well information obtained from LaBella Associates 2021 Water Quality Monitoring Report - February 2021 Event. TOC = top of casing; ft BTOC = feet below top of casing ft AMSL= feet above mean sea level Table 2 (Page 1 of 1) Hart & Hickman, PC hftps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWMlTables/Oxford Unit 1 Tables 1-6.xlsx Table 3 Summary of Field Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Sample ID Sample Date Field Parameter Result Unit Groundwater MW-2 3/30/2023 Conductivit 63PS/CM Dissolved Oxygen 0.68 m /I ORP 130.3 mV H 5.24 S.U. Temperature 14.32 °C Turbidity 75.38 NTU MW-3RR 3/29/2023 Conductivit 366.1PS/CM Dissolved Oxygen 0.94 m /I ORP -2.4 mV H 6.46 S.U. Temperature 14.0 °C Turbidity 8.22 NTU MW-4R 3/30/2023 Conductivit 750PS/CM Dissolved Oxygen 3.86 m /I ORP 78.3 mV H 7.61 S.U. Temperature 16.59 °C Turbidity <0.01 NTU MW-5R 3/29/2023 Conductivit 500.7PS/CM Dissolved Oxygen 0.41 m /I ORP 97.6 mV H 6.14 S.U. Temperature 14.6 °C Turbidity 2.26 NTU MW-6R 3/30/2023 Conductivit 998PS/CM Dissolved Oxygen 1.48 m /I ORP 41.9 mV H 6.83 S.U. Temperature 14.27 °C Turbidity 3.78 NTU MW-7 3/29/2023 Conductivit 362PS/CM Dissolved Oxygen 3.21 m /I ORP 91.8 mV H 5.95 S.U. Temperature 15.83 oC Turbidity 2.19 NTU NES-2S 3/29/2023 Conductivit 279.8PS/CM Dissolved Oxygen 0.34 m /I ORP 99.1 mV H 6.36 S.U. Temperature 15.1 °C Turbidity <0.01 NTU NES-2D 3/29/2023 Conductivit 356.EPS/CM Dissolved Oxygen 2.19 m /I ORP 99.8 mV H 7.31 S.U. Temperature 14.9 °C Turbidity <0.01 NTU Table 3 (Page 1 of 1) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1- 6.xlsx Table 3 Summary of Field Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Sample ID Sample Date Field Parameter Result Unit Groundwater Surface Water SW-1 3/30/2023 Conductivity 101PS/CM Dissolved Oxygen NA m /I ORP 88.6 mV H 7.81 S.U. Temperature 21.38 °C Turbidity 35.67 NTU SW-2 3/30/2023 Conductivit 112PS/CM Dissolved Oxygen NA m /I ORP 86.1 mV H 6.39 S.U. Temperature 15.50 °C Turbidity 21.99 NTU Notes: S.U. = standard units; °C = degrees Celsius; pS/cm = microsiemens per centimeter NTU = nephelometric turbidity unit; mg/L = milligrams per liter; mV = millivolts ORP = oxidation reduction potential; NA = not analyzed Table 3 (Page 2 of 1) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1- 6.xlsx Table 4 Summary of Groundwater Flow Velocity Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Hydraulic Conductivity(l)Elevation (ft/day) Groundwater (ft AMSL) Reference Elevation (ft AMSL) Delta Elevation (ft) Map Length (ft) Hydraulic Gradient (ft/ft) Effective Porosity �,� Groundwater Flow Velocity (ft/day) Groundwater Flow Velocity (ft/year) MW-1A 7.31E-02 531.71 530.00 1.71 101.90 0.017 0.310 0.004 1.44 MW-2 7.31 E-02 509.59 505.00 4.59 125.90 0.036 0.310 0.009 3.14 MW-3RR 7.31 E-02 489.23 485.00 4.23 280.69 0.015 0.310 0.004 1.30 MW-4R 7.31 E-02 498.28 495.00 3.28 68.08 0.048 0.310 0.011 4.15 MW-5R 7.31 E-02 470.06 475.00 4.94 138.70 0.036 0.310 0.008 3.07 MW-6R 7.31 E-02 499.76 495.00 4.76 114.02 0.042 0.310 0.010 3.59 MW-7 7.31 E-02 510.71 505.00 5.71 152.38 0.037 0.310 0.009 3.23 NES-2S 7.31E-02 472.38 475.00 2.62 438.04 0.006 0.310 0.001 0.51 Minimum -- -- -- -- 0.006 -- 0.001 0.51 Maximum -- -- -- -- 0.048 -- 0.011 4.15 Geometric Mean -- -- -- -- 0.025 -- 0.006 2.14 Notes: 1) Hydraulic conductivity and porosity values from Labella Associates Water Quality Monitoring Report - February 2021 Event Hydraulic conductivity was based on the geometric mean of values from slug tests conducted on saprolite wells at the facilit'. in 2019 and the effective porosity value was estimated at 31 % of the laboratory determined porosity for soil samples from the facility ft = feet; ft/day = feet per day; ft/year = feet per year AMSL = feet above mean sea level; -- = not applicable Vx = (K/ne) x dh/dl Vx = groundwater flow velocity K = hydraulic conductivity ne = effective porosity dh/dl = hydraulic gradient Table 4 (Page 1 of 1) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6 Hart & Hickman, Pl./ Table 5 Summary of Constituent Detections Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (Ng/L) (Ng/L) Standard Source (1 a 2) Groundwater MW-2 3/30/2023 Alkalinity 11,300 NE NE Barium 19.6 700 NC 2L Chromium 7.11 J 10 NC 2L Cobalt 9.52 J 1 NC 2L Copper 5.89 J 1,000 NC 2L Chloride 4,750 250,000 NC 2L Iron 6,320 300 NC 2L Manganese 198 50 NC 2L Methylene Chloride 4.0 J 5 NC 2L Nickel 4.97 J,B 100 NC 2L Sulfate 9,730 250,000 NC 2L Total Dissolved Solids 118,000 500,000 NC 2L Vanadium 7.11 J 7 NC 2L Zinc 8.24 J 1,000 NC 2L MW-3RR 3/29/2023 1,4-Dioxane 20.2 3 NC 2L Alkalinity 163,000 NE NE Barium 54.5 700 NC 2L Chloride 21,600 250,000 NC 2L Cobalt 3.64 J 1 NC 2L Copper 20.2 1,000 NC 2L Iron 2,940 300 NC 2L Manganese 2,890 50 NC 2L Nickel 3.25 J 100 NC 2L Sulfate 2,870 250,000 NC 2L Total Dissolved Solids 192,000 500,000 NC 2L Zinc 8.44 J 1,000 NC 2L MW-4R 3/30/2023 1,4-Dioxane 20.3 3 NC 2L Alkalinity 307,000 NE NE Arsenic 6.32 J 10 NC 2L Barium 33.8 700 NC 2L Chloride 70,000 250,000 NC 2L Chromium 1.83 J 10 NC 2L Copper 6.72 J 1,000 NC 2L Iron 20.1 J 300 NC 2L Manganese 70.5 50 NC 2L Methylene Chloride 4.0 J 5 NC 2L Nickel 3.82 J,B 100 NC 2L Sulfate 10,300 250,000 NC 2L Total Dissolved Solids 451,000 500,000 NC 2L Zinc 12.7 J 1,000 NC 2L MW-5R 3/29/2023 1,1-Dichloroethane 1.4 6 NC 2L 1,2-Dichlorobenzene 1.3 20 NC 2L 1,4-Dichlorobenzene 0.94 J 6 NC 2L 1,4-Dioxane 58.6 3 NC 2L Alkalinity 186,000 NE NE Barium 44.6 700 NC 2L Chloride 50,000 250,000 NC 2L Chlorobenzene 1.4 50 NC 2L Iron 292 300 NC 2L Manganese 102 50 NC 2L Nickel 2.16 J 100 NC 2L Sulfate 8,200 250,000 NC 2L Total Dissolved Solids 307,000 500,000 NC 2L Vinyl Chloride 0.81 J 1 0.03 1 NC 2L Table 5 (Page 1 of 2) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6 Table 5 Summary of Constituent Detections Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (Ng/L) (Ng/L) Standard Source (11 a 2) Groundwater MW-6R 3/30/2023 1,1-Dichloroethane 0.92 J 6 NC 2L 1,4-Dioxane 8.1 3 NC 2L Alkalinity 277,000 NE NE Barium 121 700 NC 2L Chloride 161,000 250,000 NC 2L Chromium 1.49 J 10 NC 2L Iron 3,550 300 NC 2L Manganese 274 50 NC 2L Nickel 3.98 J 100 NC 2L Sulfate 7,690 250,000 NC 2L Total Dissolved Solids 647,000 500,000 NC 2L MW-7 3/29/2023 Alkalinity 151,000 NE NE Barium 3.74 J 700 NC 2L Chloride 9,360 250,000 NC 2L Nickel 1.92 J 100 NC 2L Sulfate 47,700 250,000 NC 2L Total Dissolved Solids 252,000 500,000 NC 2L NES-2S 3/29/2023 Alkalinity 96,700 NE NE Chloride 11,300 250,000 NC 2L Sulfate 31,600 250,000 NC 2L NES-2D 3/29/2023 Alkalinity 132,000 NE NE Chloride 8,570 250,000 NC 2L Sulfate 42,000 250,000 NC 2L Surface Water SW-1 3/30/2023 Arsenic 5.38 J 340 NC 2B Barium 14.7 21,000 ISTV 13) Chromium 2.45 J 16 NC 2B Cobalt 1.68 J 16 ISTV )3) Copper 4.13 J 4.63 NC 2B 11) Nickel 4.16 J 179.75 NC 2B ') Zinc 29.7 J 44.92 NC 2B ') Hardness 35,300 NE NE SW-2 3/30/2023 1,4-Dioxane 0.89 J 80 ISTV )3) Barium 15.5 21,000 ISTV (3) Chromium 1.75 J 16 NC 2B Nickel 3.29 J 179.75 NC 2B ') Vanadium 5.23 J NE NE Zinc 13.0 J 44.92 NC 2B ') Hardness 36,500 NE NE Notes. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022. 15A NCAC 2B Water Quality Standards (213 Standards) for Surface Water (Class C) dated July 26, 2021. Bold concentrations exceed the NC 2L Standard for groundwater or NC 2B Standard for surface water. 1. 2B Standards for hardness -dependent metals are calculated using a mean value of 32.25 mg/L obtained from averaging hardness results reported for surface water locations SW-1 and SW-2 from September 2019 to March 2023. 2. No 2B Standard established, value shown is EPA Nationally Recommended Water Quality Criteria (NRWQC) for Aquatic Life & Human Health. 3. No 2B Standard established, value shown is North Carolina In -Stream Target Value for Surface Water (ISTV). J = Estimated value above laboratory method detection limit and below laboratory method quantitation limit. B = Analyte was detected in the associated method blank, result is expected to be biased high based on concentrations in the blank. ND = Non -Detect; NE = Not Established; -- = Not Applicable; pg/L = micrograms per liter Table 5 (Page 2 of 2) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6 Table 6 Summary of Monitored Natural Attenuation Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (µg/L) Standard /L MW-5R 3/29/2023 Alkalinity (total as CaCO3) 186,000 NE MW-7 3/29/2023 151,000 NE NES-2S 3/29/2023 96,700 NE NES-2D 3/29/2023 132,000 NE MW-5R 3/29/2023 Chloride 50,000 250,000 MW-7 3/29/2023 9,360 250,000 NES-2S 3/29/2023 11,300 250,000 NES-2D 3/29/2023 8,570 250,000 MW-5R 3/29/2023 Methane 31 NE MW-7 3/29/2023 <2.0 NE NES-2S 3/29/2023 120 NE NES-2D 3/29/2023 <2.0 NE MW-5R 3/29/2023 Ethane NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Ethene NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Nitrogen, Nitrate 17.6J 10,000 MW-7 3/29/2023 305 10,000 NES-2S 3/29/2023 32.7J 10,000 NES-2D 3/29/2023 98.5 10,000 MW-5R 3/29/2023 Sulfide NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Sulfate 8,200 250,000 MW-7 3/29/2023 47,700 250,000 NES-2S 9/29/2022 31,600 250,000 NES-2D 3/29/2023 42,000 250,000 MW-5R 3/29/2023 Dissolved Hydrogen 2 4.4 NE MW-7 3/29/2023 5.9 NE NES-2S 3/29/2023 3.5 NE NES-2D 3/29/2023 3.5 NE MW-5R 3/29/2023 Total Organic Carbon NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Acetic Acid NA 5,000 MW-7 3/29/2023 NA 5,000 NES-2S 3/29/2023 NA 5,000 NES-2D 3/29/2023 NA 5,000 Table 6 (Page 1 of 2) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6 Table 6 Summary of Monitored Natural Attenuation Parameters Granville County Oxford Unit 1 Landfill Oxford, North Carolina H&H Job No. GMI-004 Well ID Sample Date Parameter Result (µg/L) Standard /L MW-5R 3/29/2023 Butyric Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Formic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Hexanoic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 i-Hexanoic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 i-Pentanoic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Lactic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Pentanoic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Propionic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE MW-5R 3/29/2023 Pyruvic Acid NA NE MW-7 3/29/2023 NA NE NES-2S 3/29/2023 NA NE NES-2D 3/29/2023 NA NE Notes: 1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022. 2. Dissolved Hydrogen units shown in nanometers (nM). Bold concentrations exceed the NC 2L Standard for groundwater. ug/L = micrograms per liter; NS = Not Sampled; ND = Not Detected; NE = Not Established Table 6 (Page 2 of 2) Hart & Hickman, PC https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Tables 1-6 APPROXIMATE LIMITS OF WASTE UNIT 1 l 4 "Y j 4 ^^^^ERTY BOUNDARY APPROXIMATE SrERr (4_ LIMITS OF WASTE UNIT 2 i USGS The National Map: National Boundaries Dataset, 3DEP Elevation Program, Geographic Names Information System, National Hydrography Dataset, National Land Cover Database, National Structures Dataset, and National Transportation Dataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S. Department of State Humanitarian Information Unit; and NOAA National Centers for Environmental Information, U.S. Coastal Relief Model. Data refreshed August, 2021. TITLE o 2,000 4,000 SITE LOCATION MAP NPROJECT SCALE IN FEET OXFORD LANDFILL GRANVILLE COUNTY U.S.G.S. QUADRANGLE MAP OXFORD, NORTH CAROLINA 2923 South Tryon Street - Suite 100 BEREA, NORTH CAROLINA2019 hart hickman Charlotte, North Carolina28203 704-586-0007 (p) 704-586-0373 (t) OXFORD, NORTH CAROLINA 2019 SMARTER E NVrFro 7jMENT LL soLUVONs License # C-1269 / # C-245 Geology 3 QUADRANGLE DATE: 11-21-22 REVISION NO: 0 7.5 MINUTE SERIES (TOPOGRAPHIC) JOB NO: GMI-004 FIGURE NO: 1 T. 4661, GO 150' 7n 490 506 7 'o _ _ •r �/ // y � I I , _ • ��-•��-,� �90 �`.,.-� /��'�' J r /// /ram/1 // 1 r /- � ,� do 46 ib 16 ! ram... -� � I � 1 ��� •. I :�26 I \ ,� 1 \ � 1 j - \ '�.... Ig r li l I it \ ter/ � / // � r \ \ �'\ � ��✓ (/� � I 1 v\ ^\ 1 530 Appendix A Groundwater and Surface Water Sampling Records 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS hart', hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Job No: Well ID: Well Location: Facility Name: �A k,!& uw%& "* 1 Date: M-3 .o 64 I i.a �ti�c l-N 61 T� Top of Casing Elevation (ft rnsl)i19 Casing Material. t Y L Volume of Water Per Well Volume: Total Well Depth (fITOC)'1kjA ````` ��""�`� Depth to Water (ftTOC): Sampling Personnel + w _ Screen Inter Type of Pump: Tubing Material. a� Weather Conditions: slsh it C-� NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping Time Level Pumped Rate q � C■ �`�jrnl% A -1Qm\ — lCyo 51 It. w1 SIC30 m\ 1 ra0_Vsv\ w5bo Yh\ \ 5'LQ van\ 1C-ao r"A vt I DD�n _ `� lA(X)by+n1- I l O k \ 6] 5Tj rm_ `50WA IVA 1 o l to j z� - Ll)-7 150 o rni_ l%PAO. Other Sample Parameters: — Sampled at:—. Sample Delivered to —Li. CS��� gallons Well Diameter: �- il (ftTOC)7-6\ • 5 Pump/Tubing set at: _ ft DO Temp. S. Cond. pH ORP Turbidity IT1 II IS/cm SU � M V) \ f U) c' 115 A3 -1 &1 °i Wy q I 1 Cn I3,a13 I3 Li.q_ 1 . 5fl 5.11 6V t at . 5 1'L3 1 o3.% 1 Dy t95 5_1`e I z.4 \ 6!� . 1 LA 3 �'3 S .'i.L 1�. 1) k A "y l- y 1 lg'' C; 1% 46 1 . pia 05 5,z5 j-to,.,l tDl. tU Parameters taken with: by Field Filtration: ® Yes (F) No If yes, which sample parameters were field Sample Parameter Containers (Types, Number of Containers, Preservatives L� V\ t� . Mt ka�� �S o 1 Q t(01, \kn P� ik Ale, trill I gow, l QL%S �-f W C.�1�( VUYI `� at GI`C- W "S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form pdf' Last Updated: 2/14/2022 Stabilization criteria guidelines from the EPA SESD Operating Procedure for Groundwater Sampling, dated April 26, 2017- 2 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Job No: u'I1 v\a `Vb,--\ Turb. +/- 10% (<10 NTUs for metals) Well ID: ' Water Level: slight or stable drawdown duringpurgingWell Location: ( Y, Facility Name 6 T' "C Date: '-3if;0 LZ� Top of Casing Elevation (ft msl): Casing Material: �� L _ Volume of Water Per Well Volume: gallons Total Well Depth (fITOC): ���•S �Depth to Water (ftTOC): +U Well Diameter: 2 Sampling Personnel: nn i��"� Screen Interval (ftTOC) 1`'l•� %°�•S Type of Pump: W G x^► Tubing Material; (i�Q Pump/Tubing set at: ft Weather Conditions: 5" NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping 00 Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate {mq/I] Slcm fSSul mV NTU 1031 1 fl� °1� `4 wn1 �� 0 .Loeb L'�`- 5Uk \10 - _3 Other Sample ParamlI e(ersi }�►'7 Sampled at: L l Parameters taken with: h�jgo TQT Sample Delivered to: Q by t at Field Filtration: ()Yes E) No If yes, which sample parameters were field filtered: Ge.0 Sample Parameter Containers (Types, Number of Containers, Preservatives): Slop "S:\BBB Master Templates\Fonns - 2022 Forms\Low Flow Groundwater Sampling Form pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Facility Name: GA-�LWA kfAVIdlA, Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging .,�- Z Job No: C-A • l_Jl19 Well ID: 48W -212V_ Well Location: r x t W& I j C, Date: 312 Top of Casing Elevation (ft msl): 4�"U b 7'] Casing Material: -P\i (_ Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): Ck1 Depth to Water (ftTOC): ly Well Diameter: ZV Sampling Personnel: 5 Screen Interval (ftTOC): 2`� - Zia -'�6 Type of Pump:. Pe f 1 _ Tubing Material: r_ Pump/Tubing set at: 2-L1 ft Weather Conditions: ';c o I(UI 6 r NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumoed Rate m II (°C)(as/cm) (SU) mV NTU l S`3S _ � .1Z 1 Sarnl to �.bS I. �L.� 3-3g �a .(a� �. � `j`-1.-L 1 C�' 14 0 9 LA . -1 1 7 S-v LSU Milo l 1 _ f �i . u' � , — �6 3 •y '3t� . l 14 IR -61;co i5b,)4 t [ -- _ • Li u �,F ^_ l�'l1 _ ,in , .01 _ � A b ZLj .Z L(, _ _ [L, llJ J��� � I � 11 Orb l`-t •l 3lJy`�'l-' � -K"7 -� .1 � .�• I in t5 1 v, 7KOO w ,^Al iyn _b qi ► `1 .0 0 1 >co -�b I il, 0 cii Other Sample Parameters: Sampled at: \V�0 Parameters taken with: UjSj k -Z Cat: Sample Delivered to: �6LU- by -fO-C)L' at Field Filtration: © Yes G No If yes, which sample parameters were field filtered: N Sample Parameter Containers (Types, Number of Containers, L �roM� 4i*,L �\n 40 I z � ��sfi� VIA (.W06� "SABBB Master TemplatesTorms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' sraomzanon cnrena guioeimes from me ❑rr, ocou uperauny Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017, hart hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Facility Name: �C-t-a i ��. �;i� UJ`,-k L Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTLIs for metals) Water Level: slight or stable drawdown during purging Job No: 6�-Z - U 0� Well ID: /4 V — Ll k Well Location: U �flrr1 h] L Date: 3/a /"-Z 7 Top of Casing Elevation (ft msl): --3 Casing Material: VUC, Volume of Water Per Well Volume: Total Well Depth (ftTOC): Depth to Water (ftTOC): 'iJ 0C Well Diameter: 2 Sampling Personnel: /U O Screen Interval (ftTOC):. <Z -(,::, Type of Pump: �r K _ Tubing Material:.. _t ~~� P .� _ Pump/Tubing set at: 1--65 Weather Conditions: 0'-)�An'� � NOTES: gallons 6 ft GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate CQ S/cm SU m�V]. (NTU) IS`o t .. '-� •''('L 7 SS-3 t/ 7.Go 1 3e� 1.'2.-�J l C7b 1 D nzlnr� 73" 6. ;7S— 71/9 7 7Z, 7 <v_o 1�_�� I..�• �( isE7-LL", 3, f(,-S�7 7sD %, �Si( '78. <�G_6I Other Sample A /Parameters: Sampled at: ( 2'q 0 Parameters taken with: Sample Delivered to. N."—C k�6 V 11 i Q_ by _ ��: V�/ at Field Filtration: ® Yes @ No If yes, which sample parameters were field filtered: l mple Parameter Containers (Types, Number of Containers, Preservatives}: a K y0,,, L VOA1 L,) HrrCI K�D,, L Afe44(S ^SbµL 04s-k, La AfQ•A- Z, 6b'L ll"k, U S. l �ar. �$T�,r� lra uus. 3v1 "S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form_pdf' Stabilization criteria guidelines from the EPA SESO Operating Last Updated: 2/1412022 Procedure for Groundwater Sampling, dated April 26, 2017_ hart = hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging Facility Name: Job No: CAA. . C1&A Well ID: ,AAw - Well Location: o x Date: `'J 1 2C\ 1 %:5 Top of Casing Elevation (ft msl): `�`��• S Casing Material: Volume of Water Per Well Volume: gallons Total Well Depth (ftTOC): ,.� Depth to Water (ftTOC): l '��1 Well Diameter: 2 Sampling Personnel: Screen Interval (ftTOC): `Z(;\ -^ Type of Pump:_ �Q t Tubing Material: LQ -7 Pump/Tubing set at: Ys ft Weather Conditions: NOTES: t GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate [mall](as/cm) Lam) rLULUJI `25 I . %v �eA% l ,°� 5 i L1 [a • t-`i \I -I • Lk `?. 55Z 5 1 1 s1. Rya I1: Rw A vn E L l k U • 1 2,6 x\ (v 3 23`7i 0) 6L4119b mL U ' 1A \1, 5 Other Sample Parameters: Sampled at � LA Parameters taken with: Sample Delivered to: 9s�__ _ `re�•I\L� by _ at Field Filtration: © Yes e No If yes, which sample parameters were field filtered: ` Sample Parameter Containers (Types, Number of Containers, Preservatives):C`314u"V.Y1 `6146 x mi s�n 1fnoy, skA. 7 \dtA i„Q1�1 ��r1 C 5wl r r� \'LG m\ fit\ "S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' ('> <b\,VA\ VIV\ AP\(> G Q;�\ �yaawu. a irowcc � n criteria guidelines from the EPA SESD Operating for Groundwater Semolina. dated Aoril 26. 2017. 11 hart , -= hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Facility Name: U x6�1 Top of Casing Elevation (ft Total Well Depth (ftTOC) Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Job No: C.7 ivv/ Well ID: MvJ-(, (2, Well Location: © NrC_ Date: -- 1--Z-3 % ( Casing Material: '(T+ Volume of Water Per Well Volume: 11A curb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging tl yl l- V Depth to Water (UOC): "7 .0 S Well Diameter: %N Sampling Personnel: �U 5 Type of Pump: _ Tubing Material: Weather Conditions: Ja 15 gallons Screen Interval (ftTOC) - L-16 Pump/Tubing set aL S� ft NOTES' GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping D❑ Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate rn 11 L'Q _ tSlcfn �� mV NTU 1 13 e. 21 — 1SOml m 1� I�.SS q� _ �51 S� . o i�-1.`63 -7" r�l I CZN M Z. .Z7 d 'arn! n 2 Z r'� • �'� Q 4D l� ' `�i� �D - 1 1z46 -L _2z-5�'t,�I _10m1 m l ,1-►& 61c�% to �s3 3 .2- S6rnln ILI,0y ��t$ � `i2� Li,`67 �T Tv wi � �1°i� G. %3 ly1 •17 3.756 Other Sample Parameter tj�x Sampled at: 1 1 Parameters taken with: 3= , Sample Delivered to: by f c� at Field Filtration: © Yes 0 No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives)(S u 110 ro V0 V'n 1-410,10 3j(Ll 0 vo -, � n vA> �AfA�.A-, _ uMf j H QkILLNn, . tIn Al Y-A\kA", S ti5-6 +mil kAu� an rvu vk,) ( Igo Qkoo{ t un Svl 'SIBBB Master TemplatesTorrns - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization critens gwbeimes from me err, beau uperaung Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. hart hickman Job No:y /-l1-- � ccp� -�- ' C�� SMARTER ENVIRONMENTAL SOLUTIONS S. Cond. +/- 5% ORP +/- 20 mV ,{ Turb. +/- 10% (<10 NTLls for metals) Well ID: LOW -FLOW GROUNDWATER Water Level: slight or stable r SAMPLING RECORD drawdown during purging Well Location: (�7LTc�r l NC Facility Name: Date: 1 A'Q ,3 Top of Casing Elevation (ft msl): Casing Material: Pyc Volume of Water Per Well Volume: gallons 1-2 Total Well Depth (ftTOC): 33- s Depth to Water (ftTOC): Well Diameter: Sampling Personnel: L C. r��w ..H _ Screen Interval (ftTOC): / 1 • S' Type of Pump: e2�,S `�/ Tubing Material: �� _ Pump/Tubing set at: 3 a ft Weather Conditions: G r r l I U� NOTES: kn, H,1 3 7' S/ r- s. Kvd. 1,6z5- -/Gs a Stabilization Criteria Primary: Secondary: pH +1- 0.1 unit DO +1- 0.2 mg/L GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate (malt] L.1(AS/cm Lau-1 (mV) MUD I'1 ply 'Z'3.(v; 7 To' 7b q7. �. [. a. 1LlS-Y 23,E -z250 3. Z-cr s r g C, I , /Ifsq 25 C,7 54e�— rSr 5. IT Y51- Y7 I S"'o' 2 3 ('3 'gib /TLc (i 3. fc 31 3 r /5".<33 57 1:F '7 2. 2 I t Other Sample Parameters: du Sampled at: ��V� Parameters taken with: L S-S Hc—e,�, (W� Sample Delivered to: ��� �5 v� 1`0 _. by at Field Filtration: O Yes G No If yes, which sample parameters were field filtered: ample Parameter Containers (Types, Number of Containers, Preservatives): ') o^t t i -?X- �16n I G/t 1 - 1 rox. 123�1^ L 1144 G 4 C 4'1kr.1". r 5� "S:\BBB Master Templates\Fors - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' L a- ��yy;; ��75� �'� J (75W n'L J Stabilization criteria guidelines from the EPA SESD Operating Procedure for Groundwater Sampling, dated April 26, 2017. Last Updated. 2/1412022 \"' C /S,, Z Vsp; d,m- �Y d• r- 1 hart t� hickman W SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER SAMPLING RECORD Job No:`S- Well ID:� —2 Well Location: A�) C Facility Name: 0) xTQs l L t 1,-,.1- 1 'L Date: 3 Top of Casing Elevation (ft msl):- Casing Material: . f VC Volume of Water Per Well Volume: gallons Total Well Depth MTOC): `L I -s Depth to Water (ftTOC): G/• gZ Well Diameter: 2 Sampling Personnel: C' Cane Screen Interval (ftTOC): //. !T- - 2 r Type of Pump: r ; j k:(- Tubing Material' LDPE Pump/Tubing set at: �t ft Weather Conditions: � ,xm ', Q,), )Lt4 `" 1 U NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping DO 'temp. S. Cond. pH ORP Turbidity Time {rLevel Pumped Rate .e• n fs"U {mall] �[ Slcm { S' i� p�.+..S t �i � 'yrJCi �Z_ �7� LUG �� , v L � 1 Liz/. r}Z 1 Qr'7 • NTU 4 c). '<C \�, c •�.S U L G' - � .i i�'l.'L 4 _I s1 _ ��5o ISa G•3S �'S. L _ �_�fr� -2 ��_ G�' ❑ cc:._c i- ') I LI C� J(J C� • J Pf Other Sample Parameters: Sampled at: t,°-t—S-L Parameters taken with:_ Sample Delivered to: D by at Field Filtration: o Yes No If yes, which sample parameters were field filtered: Semple Parameter Containers (Types, Number of Containers, Preservatives): J k Ut;cv r ZSbnL�k► ci.tiaifi,n eritAria nuidslines from the EPA SESD Operating 'S:\BBB Master Templates\Fonns - 2022 Forms\Low Flow Groundwater Samp ing t-orm.por- Procedure for Groundwater Sampling, dated April 26, 2017. Last Updated: 2114/2022 hart' hickman SMARTER ENVIRONMENTAL SOLUTIONS LOW -FLOW GROUNDWATER I SAMPLING RECORD Facility Name: W G Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV Turb. +/- 10% (<10 NTUs for metals) Water Level: slight or stable drawdown during purging Job No- C, dLI WeIIID: Well Location: Date: Top of Casing Elevation (ft msl): Casing Material: r Volume of Water Per Well Volume: Total Well Depth (ftTOC): {��� • Depth to Water (ftTOC):__ Well Diameter: Sampling Personnel: G.f 5 Type of Pump: 'N Tubing Material Weather Conditions: AtA� r gallons Screen Interval (ftTOC): Pump/Tubing set at: -S ft NOTES: J -0 " f y-- %= Yo " ga— GROUNDWATER SAMPLING PARAMETERS Water Valuate Pumping. DO Temp. S. Cond. pH ORP Turbidity Time Level Pumped Rate m /I (Its/cm) L� L� NTU GILTS �•�� — fS n I S 1% , ,� t � �L�L� ��3 Q.•?- i 'p.qI I 3. 7 `$ 1 - L Is 7. R 43 Io mot. e l US ., w- ., � 1' Lod is- r �. f.,3 _ 61 Ll0 L { r A�- /J pg (I;rf. r7. CC:-G !� ut W po- ir, 5' 9 -7• (.b '?C'.-L cc. C'% lam^ } - 5'u 'U i -a / `/..; .591 -?3 3` 7`l 7 . S`9 a I C? 2, `l F_ o e t E'% c \ L L w. . . }13 1i`L 11. E-7 i U 1 � I q 1'�•'S 3773,9 — i _ Ck 3VISO 11 L�f , -L �ot7�twL ISOnLM� • F.-7� - SCOy'S 7S 7 lQr" GO• t7i Other Sample Parameters: Sampled at: I .2-b 37 Parameters taken with: [ Sample Delivered to: p Gc e Adw-AO, by 4 at Field Filtration: ® Yes 0 No If yes, which sample parameters were field filtered: Sample Parameter Containers (Types, Number of Containers, Preservatives): (3,c w'- L `�^ leS. r f 43)< g01'L � +a) kia v�� ��D L , D}.,� {� ;..�`re�. )k�I:1��r��Z��D.,L vL-c�c trrtsvc�. CGlon lr��� .�L�= ` �•, ' k "SABBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated. 2/1412022 Procedure for Groundwater Sampling, dated April 26, 2017. hart hickman SMARTER ENVIRONMENTAL SOLUTIONS I LOW -FLOW GROUNDWATER I SAMPLING RECORD Facility Name: Top of Casing Elevation (ft msl): Total Well Depth (ftTOC): Sampling Personnel:�A X,2S Type of Pump: 7 i � Weather Condition Stabilization Criteria Primary: Secondary: pH +/- 0.1 unit DO +/- 0.2 mg/L S. Cond. +/- 5% ORP +/- 20 mV 7 Job No: 61tj-f - `--'" Uf Turb. +/- 10% (<10 NTLIs for metals) Well ID: > — Z D Water Level: slight or stable drawdown during purging Well Location: c Casing Material: 49V C. Depth to Water (ftTOC): n) • � Lf Date: �7 9 / Z Volume of Water Per Well Volume: gallons Well Diameter: 2 Screen Interval (ftTOC): � 6, 5 - 5 f Tubing Material: U Q E Pump/Tubing set at: S 7 ft �o C f NOTES: GROUNDWATER SAMPLING PARAMETERS Water Volume Pumping D❑ Temp. S. Cond. pH ❑RP Turbidity Time Level Pumped Rate Lm q/�l L°� S/cm (SU) WD NTU 53 ^7. ,u xv 2.30 1"Ir. -s- `7 J +a 7• 3 /(,C). 161�1• S 10St -1' 1:Smoth. -7— 1 0 11. T 7 7.33 r Co-Gj Other Sample Parameters: _ l � Sampled at: Parameters taken with Sample Delivered to: �1 f`[.c�1� �_ by �"C� �} ' S � PrUP/us at 0 Field Filtration: © Yes I, No If yes, which sample parameters were field filtered. Sample Parameter Containers (Types, Number of Containers, Preservatives): S s p+ "S:\BBB Master TemplatesTorms - 2022 Forms\Low Flow Groundwater Sampling Form pdf' Stabilization criteria guidelines from the EPA SESD Operating Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017. _�l Surface Water Sampling Form hart E hickman SMARTER ENVIRONMENTAL SOLUTIONS GENERAL INFORMATION f Job No.: ` - !y� o0 q Location No.: S W Date: 1 � ��— Site Name:61�a Lr" l l t' U,l , 4— � Location: 6 � � fU — AZA NS Sample Type &Grab (❑) Composite (❑) Other L Sampling Equipment (❑) Dedicated (❑) Decontaminated (❑) Bailer (❑) Pump Material (❑) PVC (❑) Stainless Steel (❑) Teflon (❑) Other Decontamination Method: I V I �• LOCATION INFORMATION Coordinates: Sample Location Dimentions Width Depth to Stream Bed PURGING INFORMATION Time pH (SU) Temp. (°C) S. Cond. umhos/cm Redox Turbidity (NTU) Weather Sample Condition: (❑) Clear (t) Cloudy ((❑) Other. Field Filtration: (❑) Yes (14) No r Comments. Sample Collector: File: SW Sampling Log, SW Form Date: 2/20/2018 Odor. Date: Time: Surface Water Sampling Form hart = hickman SMARTER ENVIRONMENTAL SOLUTIONS GENERAL INFORMATION / Job No.: `i uy� � - Location No.: 5 Date: 1 U Site Name.&' "A Lv"(�u Location: OK"(N �L Sample Type (jj Grab (❑) Composite (❑) Other Sampling Equipment (❑) Dedicated (❑) Decontaminated (❑) Bailer (❑) Pump / V� Material (❑) PVC (❑) Stainless Steel (❑) Teflon (❑) Other T., NA A Decontamination Method: LOCATION INFORMATION Coordinates: Sample Location Dimentions Width Depth to Stream Bed PURGING INFORMATION Time pH (SU) Temp. (°C S. Cond. uMhos/cm) Redox Turbidity NTU 6 J 122 Z N Weather Conditions: Sample Condition: (�h Clear (❑) Cloudy (❑) Other: Odor:` Field Filtration: (❑) Yes (❑) No Containers (Types, Numbers, Preservatives): `'l`` 0%'n) vUAS -1 fiv' I vtivar I. -'n 1-ti 17 i �n1 C(,, L lA [ Comments: Sample Collector: File: SW Sampling Log, SW Form Date: 2/20/2018 Date: 3130 Time:__�� Appendix B Laboratory Analytical Reports 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 April 18, 2023 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004 Pace Project No.: 92659727 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: If you have any questions concerning this report, please feel free to contact me. Sincerely, `y] L�aru Angela Baioni for Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004 Pace Project No.: 92659727 Lab ID Sample ID Matrix Date Collected Date Received 92659727001 MW-5R Water 03/29/2314:05 03/30/2310:00 92659727002 MW-7 Water 03/29/2315:09 03/30/2310:00 92659727003 NES-2S Water 03/29/2312:32 03/30/2310:00 92659727004 NES-21) Water 03/29/2312:03 03/30/2310:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 t G p T A v _u Q N ti n ¢ o rL ro CL m CL o � n �2 m o 5� d +� o ' 1 x 9 p r �i" cm lavaceri VI fln C� - `�• ° 6 1 cr ✓� m os = O Q a a A (6 y G ry n; a HIV c70— ltN w y �, � a O a y_ 3 R v 7 Z ITm� � d � O •� CCC--V A � Tl n a a n c a i! -1 rp `C C a n o 9 Ov a N rt,'. 41 a rj o a roul n t— �', ro zo v q a < G] n rx Sv ° _ n rn r2 r f4 in j cS L+ E O p o C m 3 rro N -i VrrD CL - rc G + r ,. r w 3 v n v� pY'(Ik a 3 Y N� ciyc—T� pj 14 \i/ ter.; S ♦Z - ` �1 1 1r t - d I,i �, 41 :•i fl Rnn a. f e. rn: d m i- a r m•n p n f , '" ` m:: to ►r � a 7Wb4p �s m r rr u a a rod rn Y .i �' a 7 i 5{ r �` zC r C pl ly 1, ..suer pn• ^�: r:f 0, t� -r'3 ? F ':3.' to S�-r A O 0 �r''3 i_ i iF i�', tRyr:i1 liW:19A0fn�rlR��Y!o ilY ' �" 3,a ro•m � p- a ,n t boar+�a%�gg!a al Oj -� 0 .�:� _: l4, Fy-, �., M1; FS � .:9 - , � 1•� YT. .-.1R�- F• 44 17•�•W ri C-ro �o P Page 3 of 14 DC#-Tltle: ENV-FRM-HUN1-0083 V02 Sample Condition Upon Receipt !G-PLSSSifeiaS ---. _ _ re,Date:11/14/2022 $:18;30 AM *Check mark top half of Ebox.1f pH and/or deWorina.tlon is verified and wIthln the acceptance .range for preservation samples. Weptians: V'QA, conform, TM, all and Grea3.e, oRgMq!S (water) ©ac, LLHg **Bottom half of box into list number of bottles ***Check �Ll unpreserved,NItrates for chlorine Project 4 WO# : 92659727 PM: TMC Due Date: 04/13/23 CLIENT: 92—Hart_Ral =- y Z Z x N 2 ry a Z� � i. a 0 '^ z y n 7 N v u M I °: r' 17 g z? ` �Z. 2 rraVy ? m ° u 7 u z u � a Zz n r Y J3.1 a+;F S Z . - Yc G E <. a dQ < ¢. C7 qq .Q Y rz} ro C 5 _Ox E E 1 in a .� uzf¢in:ui 7 E E E ,��-- : c - 1 rV Nto . :� -:±±±+++��� . a Vr o r4, o-E o O i.El. S131 N N - [u ��! �Sr%rS T:•'� 7 jeM� :, m. _ m;: , : S;; , ; un-. t- °rr53 Of a . .'.. m . a ail , ¢- , .Q Q.: €1 r : • , :3r. -,1, ,��C... y . i In 1 - 2. \\N N\\ 3' N\\N N I 4 N; I \�Ls\ N 6 7 1 - a r 9 10 ' 11 lz "I pH Adjustment Log for Preserved Samples... . Sample IC -Type of Rresensatiae. pH upon receipt pate preservation adjusled Time. preservation Amount of preservative_ I Lot a e -- - ------- --' r-••_l",-+,•.'ba,.„•,a•v..nown,rn--eon=l1dMal a Kfulr,llitug {rlwill VCWRI10InBhoAnearorrnaOENHCrer.tillcatlonOf-ice(Le . Out of hoist; incorrect preservative, aut of te.np, incorrect containers. Page 4 of 14 aceAnalyfical LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 04/12/2023 Report Y 223033150 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project 92659727 G M 1.004 Samples Collected 3/29/23 Deliver To Additional Recipients Taylor Cannon NONE Pace Analytical 9800 Kincey Avenue Suite 100 Huntersville, NC 28078 704-875-9092 ACCR D1TED CERT # 6429.01 Pages 5 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 1 of 10 Report#: 223033150 ceAnaytical Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223033150 Pages 6 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 2 of 10 Report#: 223033150 ceAnaytical Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Certifications Certification Certification Number A2LA Accredited DoD ELAP-QSM 5.4 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pages 7 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 3 of 10 Report#: 223033150 ceAnaytical Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Case Narrative Client: Pace Analytical Services Report: 223033150 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Pages R of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 4 of 10 ceAnaytica! Report#: 223033150 Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22303315001 MW-5R Bubble Strip 3/29/23 14:05 3/31/23 09:38 22303315002 MW-7 Bubble Strip 3/29/23 15:09 3/31/23 09:38 22303315003 NES-2S Bubble Strip 3/29/23 12:32 3/31/23 09:38 22303315004 NES-2D Bubble Strip 3/29/23 12:03 3/31/23 09:38 Pages P of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 5 of 10 ceMaltica! Report#: 223033150 Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22303315001 MW-5R Hydrogen nM 4.4 1 NA 22303315002 MW-7 Hydrogen nM 5.9 1 NA 22303315003 NES-2S Hydrogen nM 3.5 1 NA 22303315004 NES-21D Hydrogen nM 3.5 1 NA Pages 10 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 6 of 10 Report#: 223033150 ceAnaytical Project ID: 92659727 GM1.004 Report Date: 04/12/2023 Sample Results MW-5R Collect Date 03/29/2023 14:05 Lab ID 22303315001 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2312:40 763091 LMB NA CAS# Parameter Result DL LOD LOQ Units 1333-74-0 Hydrogen 4.4 0.49 0.76 1.9 nM Collect Date 03/29/2023 15:09 Lab ID 22303315002 MW-7 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2312:52 763091 LMB NA CAS# Parameter Result DL LOD LOQ Units 1333-74-0 Hydrogen 5.9 0.49 0.76 1.9 nM N ES-2S Collect Date 03/29/2023 12:32 Lab ID 22303315003 Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2313:04 763091 LMB NA CAS# Parameter Result DL LOD LOQ Units 1333-74-0 Hydrogen 3.5 0.49 0.76 1.9 nM Collect Date 03/29/2023 12:03 Lab ID 22303315004 N ES-2D Receive Date 03/31/2023 09:38 Matrix Bubble Strip AM20GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/03/2313:16 763091 LMB NA CAS# Parameter 1333-74-0 Hydrogen Result DL LOD LOQ Units 3.5 0.49 0.76 1.9 nM Pages 11 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 7 of 10 ceAnaytica! Report#: 223033150 Project ID: 92659727 GM1.004 Report Date: 04/12/2023 General Chromatography QC Summary Analytical Batch Client ID MB763091 LCS763091 LCSD763091 763091 Lab ID 2468699 2468700 2468701 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/03/23 12:02 04/03/23 11:38 04/03/23 11:50 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R RPD RPD Result LOD 1 Added Limits%R 1 Added Limit Hydrogen 1333-74-0 0.76U 1 0.761 121 10 185 1 70 - 130 1 121 12199 1 14 1 20 Pages 1? of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 8 of 10 Client !c: 4397 - Pace Analyiica! Services Internal Transfer Gain of Custody IIIIJf� I�III f 1811I IIJI 1 Ifl III Pam: KD1 Samples Pre -Lagged into eCOC. State Of Origin; �1C Cert. Needed: � Yes " NO Wnrkarder: 92659727 VVorkorrfer Name: GMI (104 Owner Received date: V11191023 Rpsiilts RPnUia_gtod Rv• d11'A1207'4 Report To Suhconkaat 7o Requested Analysis Taylor M Cannon Pace Gulf Coast Pace Analytical Charkkdle 7979 Innovation Park Dr 9800 Kincey Ave. Suile 100 Baton Rouge, LA 70820 x Huntersville, INC 28078 Phone (225)7694900 ra N Phone (704)875-9092 a a PfeSefYBd GOr1tHIr12F5 0 a T � V O Sample collect ¢ 4 Clem Sample Id Type OaWTime Lab 10 Matrix 0 LAB USE ONLY 1 W-5R PS 1291202314:05 92659727001 Water 1 X 1 2 M4V-7 PS W291202315:49 92659727002 Water 1 X 3 PS-2S PS 31291202312:32 92659727003 Water 1 � X 4 MM PS 31291202312:03 92659727004 Water 1 X 5 Comments Transfers Released By pateMme Received By Datefrime 2 V-5 G_ f r 3 Cooler Temperature on Receipt °C CustodV Seal or N Received art Ice Y or Samples Intact Y or N —*In order to maintain client con{idenfiality, locationlname of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this irlformaVorl is available in the owner laboratory. (;Zo I (e 075 6-8-1 q Thursday. March 30, 2023 3:50:26 PM FMT-AIL-C-002rev.40 24March2009 Page 1 of 1 Pages 13 of 14 Pace Gulf Coast Report#: 223033150 04/12/2023 17:41 Page 9 of 10 ,rv�+'ceAnalyfical'SAMPLE RECEIVING CHECKLIST IIIIIIiVIIIIII SAMPLE DELIVERY GROUP 223033150 CHECKLIST YES NO Client PM 1,01 Transport Method Samples received with proper thermal preservation? *❑ ❑ 4367 - Pace Analytical Services F®DC Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? ❑ *❑ ❑ ❑ Profile Number Received By 299835 N/bO ine, Dodie K All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? *❑ 0 ❑ ❑ Line Item(s) Receive Date(s) 7 - Hydrogen 03/31/23 Preservative added to any containers? ❑ I❑ If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? ❑❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID NA Temp °C None None 620160758814 M NOTES Revision 1.6 Pace Gulf Coast Report#: 223033150 Page 1 of 1 Pages 14 of 14 04/12/2023 17:41 Page 10 of 10 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 April 18, 2023 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Lab ID Sample ID Matrix Date Collected Date Received 92659666001 NES-2S Water 03/29/2312:32 03/30/2310:00 92659666002 NES-21) Water 03/29/2312:03 03/30/2310:00 92659666003 TRIP BLANK Water 03/29/23 00:00 03/30/23 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659666001 NES-2S EPA 8260D SAS 4 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659666002 NES-21) EPA 8260D CL 4 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659666003 TRIP BLANK EPA 8260D SAS 4 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Sample: NES-2S Lab ID: 92659666001 Collected: 03/29/23 12:32 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 04/07/23 08:19 75-01-4 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 04/07/23 08:19 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 04/07/23 08:19 17060-07-0 Toluene-d8 (S) 105 % 70-130 1 04/07/23 08:19 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 04/04/23 22:51 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 81 % 67-130 1 04/04/23 22:51 17060-07-0 Toluene-d8 (S) 88 % 70-130 1 04/04/23 22:51 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 96700 ug/L 5000 5000 1 04/06/23 20:23 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 31600 ug/L 1000 500 1 04/01/23 03:35 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 32.7J ug/L 40.0 10.0 1 03/31/23 03:12 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 11300 ug/L 1000 500 1 04/05/2319:27 16887-00-6 Date: 04/18/2023 06:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Sample: NES-21) Lab ID: 92659666002 Collected: 03/29/23 12:03 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 04/07/23 06:47 75-01-4 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 04/07/23 06:47 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 04/07/23 06:47 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 04/07/23 06:47 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 04/06/23 01:45 123-91-1 H1,H5 Surrogates 1,2-Dichloroethane-d4 (S) 92 % 67-130 1 04/06/23 01:45 17060-07-0 Toluene-d8 (S) 91 % 70-130 1 04/06/23 01:45 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 132000 ug/L 5000 5000 1 04/07/23 16:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 42000 ug/L 1000 500 1 04/01/23 03:51 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 98.5 ug/L 40.0 10.0 1 03/31/23 03:10 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 8570 ug/L 1000 500 1 04/05/2319:28 16887-00-6 Date: 04/18/2023 06:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Sample: TRIP BLANK Parameters Lab ID: 92659666003 Collected: Report Results Units Limit 03/29/23 00:00 MDL DF Received: 03/30/23 10:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 04/07/23 04:05 75-01-4 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 04/07/23 04:05 460-00-4 1,2-Dichloroethane-d4 (S) 93 % 70-130 1 04/07/23 04:05 17060-07-0 Toluene-d8 (S) 108 % 70-130 1 04/07/23 04:05 2037-26-5 Date: 04/18/2023 06:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 765937 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659666002 METHOD BLANK: 3976888 Matrix: Water Associated Lab Samples: 92659666002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vinyl chloride ug/L ND 1.0 0.39 04/07/23 00:43 1,2-Dichloroethane-d4 (S) % 98 70-130 04/07/23 00:43 4-Bromofluorobenzene (S) % 100 70-130 04/07/23 00:43 Toluene-d8 (S) % 97 70-130 04/07/23 00:43 LABORATORY CONTROL SAMPLE: 3976889 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L 20 14.9 74 62-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 3976891 92659923009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L ND 20 18.4 92 61-163 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 3976890 92659670001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Vinyl chloride ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 99 102 4-Bromofluorobenzene (S) % 98 99 Toluene-d8 (S) % 97 96 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 766318 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659666001, 92659666003 METHOD BLANK: 3978973 Matrix: Water Associated Lab Samples: 92659666001, 92659666003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vinyl chloride ug/L ND 1.0 0.39 04/07/23 02:34 1,2-Dichloroethane-d4 (S) % 95 70-130 04/07/23 02:34 4-Bromofluorobenzene (S) % 95 70-130 04/07/23 02:34 Toluene-d8 (S) % 108 70-130 04/07/23 02:34 LABORATORY CONTROL SAMPLE: 3978974 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vinyl chloride ug/L 20 16.6 83 62-130 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8(S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978975 3978976 MS MSD 92659909002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vinyl chloride ug/L ND 20 20 15.1 16.8 76 84 61-163 11 30 v1 1,2-Dichloroethane-d4 (S) % 98 97 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 97 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 765904 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659666001 METHOD BLANK: 3976660 Matrix: Water Associated Lab Samples: 92659666001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/04/23 20:00 1,2-Dichloroethane-d4 (S) % 80 67-130 04/04/23 20:00 Toluene-d8 (S) % 87 70-130 04/04/23 20:00 LABORATORY CONTROL SAMPLE: 3976661 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 80 67-130 Toluene-d8 (S) % 88 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3976662 3976663 MS MSD 92659666001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 18.6 18.5 92 92 55-137 0 30 H1 1,2-Dichloroethane-d4 (S) % 84 85 67-130 30 Toluene-d8 (S) % 109 80 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 766180 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659666002 METHOD BLANK: 3978090 Matrix: Water Associated Lab Samples: 92659666002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/05/23 17:11 1,2-Dichloroethane-d4 (S) % 83 67-130 04/05/23 17:11 Toluene-d8 (S) % 87 70-130 04/05/23 17:11 LABORATORY CONTROL SAMPLE: 3978091 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 17.8 89 70-130 1,2-Dichloroethane-d4 (S) % 78 67-130 Toluene-d8 (S) % 86 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978092 3978093 MS MSD 92659941002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 0.89J 20 20 18.7 19.9 89 95 55-137 6 30 1,2-Dichloroethane-d4 (S) % 86 80 67-130 30 Toluene-d8 (S) % 108 106 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 766385 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659666001 METHOD BLANK: 3979186 Matrix: Water Associated Lab Samples: 92659666001 Blank Reporting Parameter Units Result Limit Alkalinity, Total as CaCO3 ug/L ND 5000 LABORATORY CONTROL SAMPLE: 3979187 Spike LCS Parameter Units Conc. Result Alkalinity, Total as CaCO3 ug/L 50000 51400 MDL Analyzed Qualifiers 5000 04/06/2317:11 LCS % Rec % Rec Limits Qualifiers 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979189 3979190 MS MSD 92659639004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 163000 50000 50000 218000 222000 110 117 80-120 2 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979191 3979192 MS MSD 92659666001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 96700 50000 50000 154000 155000 114 116 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 31 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 766516 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659666002 METHOD BLANK: 3980290 Matrix: Water Associated Lab Samples: 92659666002 Blank Reporting Parameter Units Result Limit Alkalinity, Total as CaCO3 ug/L ND 5000 LABORATORY CONTROL SAMPLE: 3980291 Spike LCS Parameter Units Conc. Result Alkalinity, Total as CaCO3 ug/L 50000 51800 LABORATORY CONTROL SAMPLE: 3980292 Spike LCS Parameter Units Conc. Result Alkalinity, Total as CaCO3 ug/L 50000 52600 MDL Analyzed Qualifiers 5000 04/07/2316:05 LCS % Rec % Rec Limits Qualifiers 104 80-120 LCS % Rec % Rec Limits Qualifiers 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980293 3980294 MS MSD 92659785001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 61.5 mg/L 50000 50000 111000 111000 99 100 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980295 3980296 MS MSD 92660170004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 27.8 mg/L 50000 50000 77000 77100 98 99 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 765128 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659666001, 92659666002 METHOD BLANK: 3972863 Matrix: Water Associated Lab Samples: 92659666001, 92659666002 Blank Reporting Parameter Units Result Limit Sulfate ug/L ND 1000 LABORATORY CONTROL SAMPLE: 3972864 Spike LCS Parameter Units Conc. Result Sulfate ug/L 50000 52400 MDL Analyzed Qualifiers 500 03/31 /23 21:12 LCS % Rec % Rec Limits Qualifiers 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972865 3972866 MS MSD 92659779003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 1.0 mg/L 50000 50000 53100 53400 104 105 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972867 3972868 MS MSD 92659639002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 47700 50000 50000 99900 95300 104 95 90-110 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 765064 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659666001, 92659666002 METHOD BLANK: 3972652 Matrix: Water Associated Lab Samples: 92659666001, 92659666002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 03/31/23 02:41 LABORATORY CONTROL SAMPLE: 3972653 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1490 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972654 3972655 MS MSD 92659779008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.85 mg/L 1500 1500 2400 2390 104 103 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972656 3972657 MS MSD 92659782006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.80 mg/L 1500 1500 2320 2320 101 102 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 31 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 QC Batch: 766156 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659666001, 92659666002 METHOD BLANK: 3977938 Matrix: Water Associated Lab Samples: 92659666001, 92659666002 Blank Reporting Parameter Units Result Limit Chloride ug/L ND 1000 LABORATORY CONTROL SAMPLE: 3977939 Spike LCS Parameter Units Conc. Result Chloride ug/L 20000 21000 MDL Analyzed Qualifiers 500 04/05/2318:48 LCS % Rec % Rec Limits Qualifiers 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977940 3977941 MS MSD 92659399002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 48.7 mg/L 10000 10000 57400 58000 87 93 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977942 3977943 MS MSD 92659463001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 78.8 mg/L 10000 10000 86800 86800 80 80 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS H1 Analysis conducted outside the EPA method holding time. H5 Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/18/2023 06:01 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 31 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659666 Lab ID Sample ID QC Batch Method QC Batch 92659666001 NES-2S EPA 8260D 766318 92659666002 NES-21) EPA 8260D 765937 92659666003 TRIP BLANK EPA 8260D 766318 92659666001 NES-2S EPA 8260D Mod. 765904 92659666002 NES-21) EPA 8260D Mod. 766180 92659666001 NES-2S SM 2320E-2011 766385 92659666002 NES-21) SM 2320E-2011 766516 92659666001 NES-2S EPA 300.0 Rev 2.1 1993 765128 92659666002 NES-21) EPA 300.0 Rev 2.1 1993 765128 92659666001 NES-2S EPA 353.2 Rev 2.0 1993 765064 92659666002 NES-21) EPA 353.2 Rev 2.0 1993 765064 92659666001 NES-2S SM 4500-CI-E-2011 766156 92659666002 NES-21) SM 4500-CI-E-2011 766156 Date: 04/18/2023 06:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 18 of 31 DC.# Titi : EAIV=FRM=HUNT-D083.:v02' S.4t tpld Condit] Upon Receipt. Inc . w;�e►t;ffiky ffctive Dat6,1Z2022 6;1tU EAM. .: i.aiil�r�[t€3t°�t'.r�C�t�liilg.5al1'Tit1e�,• jlegviilt3 .. " Gire�rriw:avd ❑ 'Nuts#ersyil[e.[] RONIO a M-hO irsvilleEl .Atianta0 IC mersvlileO Client iV.ameY 1a1::# Wp# : 92659666 ceawrier:. Feic —�PS . E1PS- nG L 4mmertial pace: ❑Otk�er:' - ..- � 92668BB6 O[sfvkseli.l i�eseni' �s ❑No 3sals llttaW. r' s' / PateJlni4iala:p raon F>teml0 a4briten#s G Rack[ng llnate+faF r P .. ' ❑None ❑ Other • t316tiiglcal Tll:�ue Frazert?'... ¢,ulible� Wxa Bobble $a Therrno►e r Yet' ❑Nrl' �I+1%A [R GumID; .wi ;' b 11iGQ Qf Ie e; 0 B_ lue 'CeriEcklml Eactof;' Caaler7ein�c AddjSutstract (`Cj :. ,'(� �, . iie�ier 3p:orcected.l'f USDA Rq-platid Si 1! 5N 4 watei �err{fllej 'A .irples -D r Ato In �.quarsrrtfrt0. 40+1ekWithin the U>'frel I :Si�tt13:.'CA, NY,."ar 5C {chezktna�7 .1�es ' � t�e7 - - . _ tiq: ''ik�l:l Y �i.W'�- •;�.•�,-'`'� Vk".i:lc"4iE:'�r:°r5�, ., -. Er: .. r::G. ._.+. ONarie . Temp.chould:tie•ot ljLt* freetln� to .c QI?ernplexomi t.tg..;p;r#v is3*p pies -011 lce�coangprtroess lias.6egiin _ . 13itf simples tirig%►atp from a tcesilintghi tW'ana IY, fitt9u�fing Ha�Yati yac�n,Qd�Prtc R{tta}}:!Yes : _ Fto .. 4l:• 'vn :yY,as e'"%C4iit17iH(i i'�e:Y� .. ..•bG.jIE :.i35'-$�41'.:6k.' . Sam loArOwd:whhln Hofr3:bme3 hex VNc ON/A_ 2.. StlssttAcIdT3me-Analysis 01*rj?xfyok©No ©lV1A 3: 456-'Ctsrt;:ArnWed ilrne Requested? ©VAS No E3MIX 4. 3ofticletEttrolurtie i' Yes ONa OW S: trortee" Conw"em weds .. I] No: 13 WA. 6: 1?ac "Ooritaiu rs Used? Yes . ©.Nrr ❑,N/q Yes []rlo nNfA. 7. t a tywa ;§nalysls:'Sgrttples-ffelcl Filtered? 7Yes ©tici . N A B.: npi `tabets M�tttf: CO '? ss r C Na: Ci WA 9. nuauw#vr-en vvn'veafs tab-t)rnmjt tJYe hYb' , ,.l]A�/A,:T Trip Blank Present?: Cl:tea 17.1'll4 irl glank;tsfntt :Seal;Preseas7'.z COM MENI5ISAMPLE DISCREPANCY 0.el40ata Requlretl? d'Yes-- Oo_ lot:ll):of split. Ontal'66(s, Ct:IENT WQvFjCAj1iOwgsOL.:.. ON 'Person contacted,: Date�Tirne: .. - - ftjeCt Manager°SCURF kevieial: Date;. Prof NipogerBRF Reviewl, Date, Page 19 of 31 ftndltlon Uporl Recalpt D.0 ........... L wo# 92659.666 Chock m arktapNO.of -box lf.pKandtor (s. ve.rjfiq� sod: Due Date: 04/13/23 TMC #�Of�404 q�gr: - PR 'LIENT. 92_Hart-RaL W*powm 400'Of 4o00;.td) 00 b40 r. .6that leg P 'H inuakfor .AlIvAtm Preierved...,L. amnl S O...-OfPreservativrf p1 upon re�e7lPtll %—tegresONA(an.adjusted I TFme-..nr.dseruAflidh . I A I naimt.Aiw*,:��ivmj. - 1. 7 AM W044 - - tv atman Nof m Ca rui in I camp ii eft& satb 0 1 es, a Cb py.oft h i % f0fFfLw I II be sent to Ehe 04( Ohaloj 1n;orreck, prLik;gry#tIgj. bUt f0i0o, Page 20 of 31 POWs Bo1 10 ul dIN31 m�s NuV113 dp +� Y'1!$09Z8xgsumAp6'L s 1 04LB dq opuolya jk!J ws-B Aq sueylsYY Panloesip Atlulle)Ol .. W � � � �� Z•£96 �q elo�LN �.., f a m eLell�B jC 4 p @ i � io - epl�oluO Lp Sitit p 1 R g }9 EOZSZeH x. Haul 0 {a7 m t i6 L EOHH J � U � • '� m r�� bOSiH nil E � CALL LL o saw V1Na� �o � H011731100 1YdW3131d ws LAU e F t� _ mf ' � �a id:vaa=a ava�.�] �a,tlalawvs 8 $ Sum a aevm p1lee ees3 M03 XIMN 4 'e h j _ so 3nma3�or c7 Ci m I3a#3S J1 if di CP 0.M01 + _ RSia h-( 39 or J2(1 to # Will S `'s'' m DTI iS' � ��1 aceAnalyfical LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 04/11/2023 Report Y 223040420 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project 92659666 G M 1.004 Oxford Samples Collected 3/29/23 Deliver To Additional Recipients Taylor Cannon NONE Pace Analytical 9800 Kincey Avenue Suite 100 Huntersville, NC 28078 704-875-9092 CCCR tD CERT # 6429.01 Papa 2? of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 1 of 10 Report#: 223040424 ceAnaytical Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 223040424 Papa 23 nf'41 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 2 of 10 Report#: 223040424 ceAnaytical Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Certifications Certification Certification Number A2LA Accredited DoD ELAP-QSM 5.4 6429.01 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pages 24 of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 3 of 10 Report#: 223040424 ceAnaytical Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Case Narrative Client: Pace Analytical Services Report: 223040424 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). PaQa 25) of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 4 of 10 .PaceAnalytica! Report#: 223040424 Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Sample Summary Lab ID Client ID Matrix Collect Date 22304042401 NES-2S Water 3/29/2312:32 22304042402 NES-21D Water 3/29/2312:03 Receive Date 4/04/23 09:45 4/04/23 09:45 PaQa 28 of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 5 of 10 Report#: 223040424 ceMaltica! Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable EPA RSK175 Lab ID Client ID Parameter Units Result Dil. %Moist 22304042401 NES-2S Methane ug/L 120 1 NA Pages 27 of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 6 of 10 Report#: 223040424 ceAnaytical Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 Sample Results N ES-2S Collect Date 03/29/2023 12:32 Lab ID 22304042401 Receive Date 04/04/2023 09:45 Matrix Water EPA RSK175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/10/23 08:57 763417 LIMB NA CAS# Parameter Result DL LOD LOQ Units 74-82-8 Methane 120 2.0 4.0 5.0 ug/L NES-2D Collect Date 03/29/2023 12:03 Lab ID 22304042402 Receive Date 04/04/2023 09:45 Matrix Water EPA RSK175 Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 04/10/23 09:13 763417 LMB NA CAS# Parameter Result DL LOD LOQ Units 74-82-8 Methane 4.OU 2.0 4.0 5.0 ug/L PaQa 29 of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 7 of 10 ceAnaytica! Report#: 223040424 Project ID: 92659666 GM1.004 Oxford Report Date: 04/11/2023 General Chromatography QC Summary Analytical Batch Client ID MB763417 LCS763417 LCSD763417 763417 Lab ID 2470311 2470312 2470313 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/10/23 07:24 04/10/23 06:52 04/10/23 07:08 Matrix Water Water Water EPA RSK175 Units ug/L Spike I Result %R Control Spike Result I %R RPD RPD I Result LOD 1 Added Limits%R 1 Added Limit Methane 74-82-8 4.OU 1 4.01 3801 280 173 1 70-130 1 3801 370198 1 29 1 30 PaQa ?P of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 8 of 10 Internal Transfer Chain of Custody II 1 �`II lEll IIIII1Il11111 II1I1 Samples Pre Lagged inioeCOC. Cent Nede& ❑ Yes �nr-.14�1'IA - 0,£r'naar, lAr ry 4 rd i i, f_Km nnh n)(Pripn I Arvr,pii I I INIT 9 nwnPr Prpiva[t nran. client!D-. 4357 - Pace Anatybcal fionrlCes SDG: 223040424 PM_ Me 111111111111111111111111111 :31100f]?S RP_SIllIS Renuested Bv: 411312023 Report To Subcontract To Requested Analysis Taylor M Cannon Pace Gulf Coast Paco Analytical Chartotte 7879 Innovation Park Cr 950D Kinsey Ave. Suite 100 Baton Rouge, LA 70B20 Huntersville, NC 28078 Phone (225)769-4900 Phone(704)875-9082 a a u E Preserved Contalners o o N Sample Collect a 0 Z Item Sample ID Type DateMme Lab 11) Malrlx 9 LAB 115E ONLY 1 ES-2s PS NM202312:32 92659666001 Water 3 x 1 2 %IES-2D PS 3129r202312:03 92659666002 Water 3 x 3 4 5 Comments Transfers Released By DMeMme Received By Daterrime 6'?)Ol 0 M?o y 3 Cooler Temperature on Receipt °C Custody Seal Y or N Received on Ice Y or IN samples Intact Y or N .**In order to maintain client confidentiality, tocationlname of the sampting site, sampler's name and signature may not be provided on this COC document. This chair)' of custody is considered complete as is since this information is available in the owner Laboratory. Thursday. Marti 30. 2023 4-30:36 PM FMT-ALL-C-002rev.00 24Marrh2009 Page t or 1 PaQa 30 of 31 Pace Gulf Coast Report#: 223040424 04/11/2023 17:31 Page 9 of 10 ,rv�+'ceAnalyfical'SAMPLE RECEIVING CHECKLIST IIIIIIIIIIII SAMPLE DELIVERY GROUP 223040424 CHECKLIST YES NO Client PM RIUe Transport Method Samples received with proper thermal preservation? *❑ ❑ 4367 - Pace Analytical Services F®DC Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? ❑ *❑ ❑ ❑ Profile Number Received E�y 299835 Perkins, Brennan All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? 0 0 ❑ ❑ Line Item(s) Receive Date(s) 2 - lvethane 04/04/23 Preservative added to any containers? ❑ I❑ If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? 0 ❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID E43 Temp °C None None 620160758880 5.8 NOTES Revision 1.6 Pace Gulf Coast Report#: 223040424 Page 1 of 1 Pages 31 of 31 04/11/2023 17:31 Page 10 of 10 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 April 12, 2023 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard for Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 46 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21LA 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Lab ID Sample ID Matrix Date Collected Date Received 92659873001 MW-2 Water 03/30/2310:31 03/31/2310:30 92659873002 MW-4R Water 03/30/2312:40 03/31/2310:30 92659873003 MW-6R Water 03/30/2311:43 03/31/2310:30 92659873004 TRIP BLANK 2 Water 03/30/23 00:00 03/31/23 10:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: GM1.004-OXFORD LANDFILL UNIT 1 92659873 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659873001 MW-2 EPA 601OD ABL 16 PAN EPA 6020E JPD 1 PAN EPA 7470A NDL 1 PAN EPA 8260D CL 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659873002 MW-4R EPA 601OD ABL 16 PAN EPA 6020E JPD 1 PAN EPA 7470A NDL 1 PAN EPA 8260D CL 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659873003 MW-6R EPA 601OD ABL 16 PAN EPA 6020E JPD 1 PAN EPA 7470A NDL 1 PAN EPA 8260D CL 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659873004 TRIP BLANK 2 EPA 8260D SAS 52 PASI-C EPA 8260D Mod. TEG 3 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-2 Lab ID: 92659873001 Collected: 03/30/23 10:31 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/05/23 08:56 04/05/23 23:20 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/05/23 08:56 04/05/23 23:20 7440-38-2 Barium 19.6 ug/L 5.00 0.736 1 04/05/23 08:56 04/05/23 23:20 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/05/23 08:56 04/05/23 23:20 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/05/23 08:56 04/05/23 23:20 7440-43-9 Chromium 7.11J ug/L 10.0 1.40 1 04/05/23 08:56 04/05/23 23:20 7440-47-3 J Cobalt 9.52J ug/L 10.0 0.840 1 04/05/23 08:56 04/05/23 23:20 7440-48-4 J Copper 5.89J ug/L 10.0 3.68 1 04/05/23 08:56 04/05/23 23:20 7440-50-8 J Iron 6320 ug/L 100 18.0 1 04/05/23 08:56 04/05/23 23:20 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/05/23 08:56 04/05/23 23:20 7439-92-1 Manganese 198 ug/L 10.0 0.934 1 04/05/23 08:56 04/05/23 23:20 7439-96-5 Nickel 4.97.1 ug/L 10.0 1.61 1 04/05/23 08:56 04/05/23 23:20 7440-02-0 B,J Selenium ND ug/L 10.0 7.35 1 04/05/23 08:56 04/05/23 23:20 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/05/23 08:56 04/05/23 23:20 7440-22-4 Vanadium 7.11J ug/L 20.0 4.99 1 04/05/23 08:56 04/05/23 23:20 7440-62-2 J Zinc 8.24.1 ug/L 50.0 6.52 1 04/05/23 08:56 04/05/23 23:20 7440-66-6 J Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 08:22 04/05/23 15:34 7440-28-0 Mercury 7470A Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet Mercury ND ug/L 0.200 0.100 1 04/06/23 09:46 04/07/23 14:06 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/07/23 08:51 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/07/23 08:51 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/07/23 08:51 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/07/23 08:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/07/23 08:51 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/07/23 08:51 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/07/23 08:51 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/07/23 08:51 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/07/23 08:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/07/23 08:51 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/07/23 08:51 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/07/23 08:51 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/07/23 08:51 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/07/23 08:51 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/07/23 08:51 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/07/23 08:51 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/07/23 08:51 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/07/23 08:51 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-2 Lab ID: 92659873001 Collected: 03/30/23 10:31 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 04/12/2023 08:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 04/07/23 08:51 95-50-1 ND ug/L 1.0 0.33 1 04/07/23 08:51 106-46-7 ND ug/L 1.0 0.56 1 04/07/23 08:51 110-57-6 v2 ND ug/L 1.0 0.37 1 04/07/23 08:51 75-34-3 ND ug/L 1.0 0.32 1 04/07/23 08:51 107-06-2 ND ug/L 1.0 0.35 1 04/07/23 08:51 75-35-4 ND ug/L 1.0 0.38 1 04/07/23 08:51 156-59-2 ND ug/L 1.0 0.40 1 04/07/23 08:51 156-60-5 ND ug/L 1.0 0.36 1 04/07/23 08:51 78-87-5 ND ug/L 1.0 0.36 1 04/07/23 08:51 10061-01-5 ND ug/L 1.0 0.36 1 04/07/23 08:51 10061-02-6 ND ug/L 1.0 0.30 1 04/07/23 08:51 100-41-4 ND ug/L 5.0 0.48 1 04/07/23 08:51 591-78-6 ND ug/L 20.0 9.7 1 04/07/23 08:51 74-88-4 IL,v2 4.OJ ug/L 5.0 2.0 1 04/07/23 08:51 75-09-2 B,C9, L1,v1 ND ug/L 5.0 2.7 1 04/07/23 08:51 108-10-1 ND ug/L 1.0 0.29 1 04/07/23 08:51 100-42-5 ND ug/L 1.0 0.31 1 04/07/23 08:51 630-20-6 ND ug/L 1.0 0.22 1 04/07/23 08:51 79-34-5 ND ug/L 1.0 0.29 1 04/07/23 08:51 127-18-4 ND ug/L 10.0 3.5 1 04/07/23 08:51 109-99-9 ND ug/L 1.0 0.24 1 04/07/23 08:51 108-88-3 ND ug/L 1.0 0.81 1 04/07/23 08:51 87-61-6 ND ug/L 1.0 0.33 1 04/07/23 08:51 71-55-6 ND ug/L 1.0 0.32 1 04/07/23 08:51 79-00-5 ND ug/L 1.0 0.38 1 04/07/23 08:51 79-01-6 ND ug/L 1.0 0.30 1 04/07/23 08:51 75-69-4 ND ug/L 1.0 0.26 1 04/07/23 08:51 96-18-4 ND ug/L 2.0 1.3 1 04/07/23 08:51 108-05-4 ND ug/L 1.0 0.39 1 04/07/23 08:51 75-01-4 ND ug/L 1.0 0.34 1 04/07/23 08:51 1330-20-7 96 % 70-130 1 04/07/23 08:51 460-00-4 113 % 70-130 1 04/07/23 08:51 17060-07-0 100 % 70-130 1 04/07/23 08:51 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 04/06/23 23:30 123-91-1 91 % 67-130 1 04/06/23 23:30 17060-07-0 97 % 70-130 1 04/06/23 23:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-2 Lab ID: 92659873001 Collected: 03/30/23 10:31 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 11300 ug/L 5000 5000 1 04/07/23 18:01 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 118 mg/L 25.0 25.0 1 03/31/23 20:05 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 9730 ug/L 1000 500 1 04/01/2319:05 14808-79-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 4750 ug/L 1000 500 1 04/05/2319:58 16887-00-6 Date: 04/12/2023 08:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-4R Lab ID: 92659873002 Collected: 03/30/23 12:40 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/05/23 08:56 04/05/23 23:23 7440-36-0 Arsenic 6.32J ug/L 10.0 4.40 1 04/05/23 08:56 04/05/23 23:23 7440-38-2 J Barium 33.8 ug/L 5.00 0.736 1 04/05/23 08:56 04/05/23 23:23 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/05/23 08:56 04/05/23 23:23 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/05/23 08:56 04/05/23 23:23 7440-43-9 Chromium 1.83J ug/L 10.0 1.40 1 04/05/23 08:56 04/05/23 23:23 7440-47-3 J Cobalt ND ug/L 10.0 0.840 1 04/05/23 08:56 04/05/23 23:23 7440-48-4 Copper 6.72J ug/L 10.0 3.68 1 04/05/23 08:56 04/05/23 23:23 7440-50-8 J Iron 20.1J ug/L 100 18.0 1 04/05/23 08:56 04/05/23 23:23 7439-89-6 J Lead ND ug/L 6.00 2.99 1 04/05/23 08:56 04/05/23 23:23 7439-92-1 Manganese 70.5 ug/L 10.0 0.934 1 04/05/23 08:56 04/05/23 23:23 7439-96-5 Nickel 3.82J ug/L 10.0 1.61 1 04/05/23 08:56 04/05/23 23:23 7440-02-0 B,J Selenium ND ug/L 10.0 7.35 1 04/05/23 08:56 04/05/23 23:23 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/05/23 08:56 04/05/23 23:23 7440-22-4 Vanadium ND ug/L 20.0 4.99 1 04/05/23 08:56 04/05/23 23:23 7440-62-2 Zinc 112.7.1 ug/L 50.0 6.52 1 04/05/23 08:56 04/05/23 23:23 7440-66-6 J Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 08:22 04/05/23 15:37 7440-28-0 Mercury 7470A Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet Mercury ND ug/L 0.200 0.100 1 04/06/23 09:46 04/07/23 14:09 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/07/23 09:09 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/07/23 09:09 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/07/23 09:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/07/23 09:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/07/23 09:09 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/07/23 09:09 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/07/23 09:09 74-83-9 v2 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/07/23 09:09 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/07/23 09:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/07/23 09:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/07/23 09:09 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/07/23 09:09 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/07/23 09:09 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/07/23 09:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/07/23 09:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/07/23 09:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/07/23 09:09 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/07/23 09:09 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-4R Lab ID: 92659873002 Collected: 03/30/23 12:40 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 04/12/2023 08:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 04/07/23 09:09 95-50-1 ND ug/L 1.0 0.33 1 04/07/23 09:09 106-46-7 ND ug/L 1.0 0.56 1 04/07/23 09:09 110-57-6 v2 ND ug/L 1.0 0.37 1 04/07/23 09:09 75-34-3 ND ug/L 1.0 0.32 1 04/07/23 09:09 107-06-2 ND ug/L 1.0 0.35 1 04/07/23 09:09 75-35-4 ND ug/L 1.0 0.38 1 04/07/23 09:09 156-59-2 ND ug/L 1.0 0.40 1 04/07/23 09:09 156-60-5 ND ug/L 1.0 0.36 1 04/07/23 09:09 78-87-5 ND ug/L 1.0 0.36 1 04/07/23 09:09 10061-01-5 ND ug/L 1.0 0.36 1 04/07/23 09:09 10061-02-6 ND ug/L 1.0 0.30 1 04/07/23 09:09 100-41-4 ND ug/L 5.0 0.48 1 04/07/23 09:09 591-78-6 ND ug/L 20.0 9.7 1 04/07/23 09:09 74-88-4 v2 4.OJ ug/L 5.0 2.0 1 04/07/23 09:09 75-09-2 B,C9, L1,v1 ND ug/L 5.0 2.7 1 04/07/23 09:09 108-10-1 ND ug/L 1.0 0.29 1 04/07/23 09:09 100-42-5 ND ug/L 1.0 0.31 1 04/07/23 09:09 630-20-6 ND ug/L 1.0 0.22 1 04/07/23 09:09 79-34-5 ND ug/L 1.0 0.29 1 04/07/23 09:09 127-18-4 ND ug/L 10.0 3.5 1 04/07/23 09:09 109-99-9 ND ug/L 1.0 0.24 1 04/07/23 09:09 108-88-3 ND ug/L 1.0 0.81 1 04/07/23 09:09 87-61-6 ND ug/L 1.0 0.33 1 04/07/23 09:09 71-55-6 ND ug/L 1.0 0.32 1 04/07/23 09:09 79-00-5 ND ug/L 1.0 0.38 1 04/07/23 09:09 79-01-6 ND ug/L 1.0 0.30 1 04/07/23 09:09 75-69-4 ND ug/L 1.0 0.26 1 04/07/23 09:09 96-18-4 ND ug/L 2.0 1.3 1 04/07/23 09:09 108-05-4 ND ug/L 1.0 0.39 1 04/07/23 09:09 75-01-4 ND ug/L 1.0 0.34 1 04/07/23 09:09 1330-20-7 96 % 70-130 1 04/07/23 09:09 460-00-4 109 % 70-130 1 04/07/23 09:09 17060-07-0 100 % 70-130 1 04/07/23 09:09 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 20.3 ug/L 2.0 0.86 1 04/06/23 23:49 123-91-1 91 % 67-130 1 04/06/23 23:49 17060-07-0 101 % 70-130 1 04/06/23 23:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-4R Lab ID: 92659873002 Collected: 03/30/23 12:40 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 307000 ug/L 5000 5000 1 04/07/23 19:39 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 451 mg/L 25.0 25.0 1 03/31/23 20:05 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 10300 ug/L 1000 500 1 04/01/2319:51 14808-79-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 70000 ug/L 3000 1500 3 04/05/23 20:41 16887-00-6 Date: 04/12/2023 08:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-6R Lab ID: 92659873003 Collected: 03/30/23 11:43 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/05/23 08:56 04/05/23 23:31 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/05/23 08:56 04/05/23 23:31 7440-38-2 Barium 121 ug/L 5.00 0.736 1 04/05/23 08:56 04/05/23 23:31 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/05/23 08:56 04/05/23 23:31 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/05/23 08:56 04/05/23 23:31 7440-43-9 Chromium 1.49J ug/L 10.0 1.40 1 04/05/23 08:56 04/05/23 23:31 7440-47-3 Cobalt ND ug/L 10.0 0.840 1 04/05/23 08:56 04/05/23 23:31 7440-48-4 Copper ND ug/L 10.0 3.68 1 04/05/23 08:56 04/05/23 23:31 7440-50-8 Iron 3550 ug/L 100 18.0 1 04/05/23 08:56 04/05/23 23:31 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/05/23 08:56 04/05/23 23:31 7439-92-1 Manganese 274 ug/L 10.0 0.934 1 04/05/23 08:56 04/05/23 23:31 7439-96-5 Nickel 3.98.1 ug/L 10.0 1.61 1 04/05/23 08:56 04/05/23 23:31 7440-02-0 Selenium ND ug/L 10.0 7.35 1 04/05/23 08:56 04/05/23 23:31 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/05/23 08:56 04/05/23 23:31 7440-22-4 Vanadium ND ug/L 20.0 4.99 1 04/05/23 08:56 04/05/23 23:31 7440-62-2 Zinc ND ug/L 50.0 6.52 1 04/05/23 08:56 04/05/23 23:31 7440-66-6 Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/2311:53 04/05/2316:40 7440-28-0 Mercury 7470A Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 04/12/2023 08:39 PM Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet ND ug/L 0.200 0.100 1 04/06/23 09:46 04/07/23 14:11 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 04/07/23 05:16 67-64-1 1.8 1 04/07/23 05:16 107-13-1 0.34 1 04/07/23 05:16 71-43-2 0.47 1 04/07/23 05:16 74-97-5 0.31 1 04/07/23 05:16 75-27-4 0.34 1 04/07/23 05:16 75-25-2 1.7 1 04/07/23 05:16 74-83-9 4.0 1 04/07/23 05:16 78-93-3 0.36 1 04/07/23 05:16 75-15-0 0.33 1 04/07/23 05:16 56-23-5 0.28 1 04/07/23 05:16 108-90-7 0.65 1 04/07/23 05:16 75-00-3 0.43 1 04/07/23 05:16 67-66-3 0.54 1 04/07/23 05:16 74-87-3 0.34 1 04/07/23 05:16 96-12-8 0.36 1 04/07/23 05:16 124-48-1 0.27 1 04/07/23 05:16 106-93-4 0.39 1 04/07/23 05:16 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. J B,J Page 11 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-6R Lab ID: 92659873003 Collected: 03/30/23 11:43 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 04/12/2023 08:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.92J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 100 % 70-130 100 % 70-130 98 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 8.1 ug/L 2.0 94 % 67-130 115 % 70-130 0.34 1 04/07/23 05:16 95-50-1 0.33 1 04/07/23 05:16 106-46-7 0.56 1 04/07/23 05:16 110-57-6 0.37 1 04/07/23 05:16 75-34-3 0.32 1 04/07/23 05:16 107-06-2 0.35 1 04/07/23 05:16 75-35-4 0.38 1 04/07/23 05:16 156-59-2 0.40 1 04/07/23 05:16 156-60-5 0.36 1 04/07/23 05:16 78-87-5 0.36 1 04/07/23 05:16 10061-01-5 0.36 1 04/07/23 05:16 10061-02-6 0.30 1 04/07/23 05:16 100-41-4 0.48 1 04/07/23 05:16 591-78-6 9.7 1 04/07/23 05:16 74-88-4 2.0 1 04/07/23 05:16 75-09-2 2.7 1 04/07/23 05:16 108-10-1 0.29 1 04/07/23 05:16 100-42-5 0.31 1 04/07/23 05:16 630-20-6 0.22 1 04/07/23 05:16 79-34-5 0.29 1 04/07/23 05:16 127-18-4 3.5 1 04/07/23 05:16 109-99-9 0.24 1 04/07/23 05:16 108-88-3 0.81 1 04/07/23 05:16 87-61-6 0.33 1 04/07/23 05:16 71-55-6 0.32 1 04/07/23 05:16 79-00-5 0.38 1 04/07/23 05:16 79-01-6 0.30 1 04/07/23 05:16 75-69-4 0.26 1 04/07/23 05:16 96-18-4 1.3 1 04/07/23 05:16 108-05-4 0.39 1 04/07/23 05:16 75-01-4 0.34 1 04/07/23 05:16 1330-20-7 1 04/07/23 05:16 460-00-4 1 04/07/23 05:16 17060-07-0 1 04/07/23 05:16 2037-26-5 0.86 1 8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 04/07/23 00:08 123-91-1 H 1, H5 04/07/23 00:08 17060-07-0 04/07/23 00:08 2037-26-5 Page 12 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: MW-6R Lab ID: 92659873003 Collected: 03/30/23 11:43 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 277000 ug/L 5000 5000 1 04/07/23 19:47 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 647 mg/L 25.0 25.0 1 03/31/23 20:05 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 7690 ug/L 1000 500 1 04/01/23 20:07 14808-79-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 161000 ug/L 5000 2500 5 04/05/23 20:42 16887-00-6 Date: 04/12/2023 08:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: TRIP BLANK 2 Lab ID: 92659873004 Collected: 03/30/23 00:00 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Date: 04/12/2023 08:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 04/07/23 05:17 67-64-1 ND ug/L 10.0 1.8 1 04/07/23 05:17 107-13-1 ND ug/L 1.0 0.34 1 04/07/23 05:17 71-43-2 ND ug/L 1.0 0.47 1 04/07/23 05:17 74-97-5 ND ug/L 1.0 0.31 1 04/07/23 05:17 75-27-4 ND ug/L 1.0 0.34 1 04/07/23 05:17 75-25-2 ND ug/L 2.0 1.7 1 04/07/23 05:17 74-83-9 ND ug/L 5.0 4.0 1 04/07/23 05:17 78-93-3 ND ug/L 2.0 0.36 1 04/07/23 05:17 75-15-0 ND ug/L 1.0 0.33 1 04/07/23 05:17 56-23-5 ND ug/L 1.0 0.28 1 04/07/23 05:17 108-90-7 ND ug/L 1.0 0.65 1 04/07/23 05:17 75-00-3 ND ug/L 1.0 0.43 1 04/07/23 05:17 67-66-3 ND ug/L 1.0 0.54 1 04/07/23 05:17 74-87-3 ND ug/L 2.0 0.34 1 04/07/23 05:17 96-12-8 ND ug/L 1.0 0.36 1 04/07/23 05:17 124-48-1 ND ug/L 1.0 0.27 1 04/07/23 05:17 106-93-4 ND ug/L 1.0 0.39 1 04/07/23 05:17 74-95-3 ND ug/L 1.0 0.34 1 04/07/23 05:17 95-50-1 ND ug/L 1.0 0.33 1 04/07/23 05:17 106-46-7 ND ug/L 1.0 0.56 1 04/07/23 05:17 110-57-6 ND ug/L 1.0 0.37 1 04/07/23 05:17 75-34-3 ND ug/L 1.0 0.32 1 04/07/23 05:17 107-06-2 ND ug/L 1.0 0.35 1 04/07/23 05:17 75-35-4 ND ug/L 1.0 0.38 1 04/07/23 05:17 156-59-2 ND ug/L 1.0 0.40 1 04/07/23 05:17 156-60-5 ND ug/L 1.0 0.36 1 04/07/23 05:17 78-87-5 ND ug/L 1.0 0.36 1 04/07/23 05:17 10061-01-5 ND ug/L 1.0 0.36 1 04/07/23 05:17 10061-02-6 ND ug/L 1.0 0.30 1 04/07/23 05:17 100-41-4 ND ug/L 5.0 0.48 1 04/07/23 05:17 591-78-6 ND ug/L 20.0 9.7 1 04/07/23 05:17 74-88-4 2.0.1 ug/L 5.0 2.0 1 04/07/23 05:17 75-09-2 ND ug/L 5.0 2.7 1 04/07/23 05:17 108-10-1 ND ug/L 1.0 0.29 1 04/07/23 05:17 100-42-5 ND ug/L 1.0 0.31 1 04/07/23 05:17 630-20-6 ND ug/L 1.0 0.22 1 04/07/23 05:17 79-34-5 ND ug/L 1.0 0.29 1 04/07/23 05:17 127-18-4 ND ug/L 10.0 3.5 1 04/07/23 05:17 109-99-9 ND ug/L 1.0 0.24 1 04/07/23 05:17 108-88-3 ND ug/L 1.0 0.81 1 04/07/23 05:17 87-61-6 ND ug/L 1.0 0.33 1 04/07/23 05:17 71-55-6 ND ug/L 1.0 0.32 1 04/07/23 05:17 79-00-5 ND ug/L 1.0 0.38 1 04/07/23 05:17 79-01-6 ND ug/L 1.0 0.30 1 04/07/23 05:17 75-69-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 14 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 Sample: TRIP BLANK 2 Parameters Lab ID: 92659873004 Results Units Collected: Report Limit 03/30/23 00:00 MDL DF Received: 03/31/23 10:30 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 04/07/23 05:17 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 04/07/23 05:17 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 04/07/23 05:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 04/07/23 05:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 04/07/23 05:17 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 04/07/23 05:17 17060-07-0 Toluene-d8 (S) 108 % 70-130 1 04/07/23 05:17 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 04/05/23 18:08 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 84 % 67-130 1 04/05/23 18:08 17060-07-0 Toluene-d8 (S) 88 % 70-130 1 04/05/23 18:08 2037-26-5 Date: 04/12/2023 08:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 2035980 Analysis Method: EPA 6010D QC Batch Method: 3015 Analysis Description: Metals (ICP) 6010D Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: R3909894-1 Matrix: Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Parameter Units Result Water Reporting Limit Antimony ug/L ND 10.0 Arsenic ug/L ND 10.0 Barium ug/L ND 5.00 Beryllium ug/L ND 2.00 Cadmium ug/L ND 2.00 Chromium ug/L ND 10.0 Cobalt ug/L ND 10.0 Copper ug/L ND 10.0 Iron ug/L ND 100 Lead ug/L ND 6.00 Manganese ug/L ND 10.0 Nickel ug/L 2.19J 10.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.00 Vanadium ug/L ND 20.0 Zinc ug/L ND 50.0 MDL Analyzed Qualifiers 4.30 04/05/23 22:25 4.40 04/05/23 22:25 0.736 04/05/23 22:25 0.330 04/05/23 22:25 0.479 04/05/23 22:25 1.40 04/05/23 22:25 0.840 04/05/23 22:25 3.68 04/05/23 22:25 18.0 04/05/23 22:25 2.99 04/05/23 22:25 0.934 04/05/23 22:25 1.61 04/05/23 22:25 J 7.35 04/05/23 22:25 1.54 04/05/23 22:25 4.99 04/05/23 22:25 6.52 04/05/23 22:25 LABORATORY CONTROL SAMPLE: Parameter R3909894-2 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 1000 969 96.9 80.0-120 Arsenic ug/L 1000 960 96.0 80.0-120 Barium ug/L 1000 1060 106 80.0-120 Beryllium ug/L 1000 973 97.3 80.0-120 Cadmium ug/L 1000 1010 101 80.0-120 Chromium ug/L 1000 989 98.9 80.0-120 Cobalt ug/L 1000 1040 104 80.0-120 Copper ug/L 1000 989 98.9 80.0-120 Iron ug/L 10000 10300 103 80.0-120 Lead ug/L 1000 996 99.6 80.0-120 Manganese ug/L 1000 928 92.8 80.0-120 Nickel ug/L 1000 995 99.5 80.0-120 Selenium ug/L 1000 958 95.8 80.0-120 Silver ug/L 200 187 93.5 80.0-120 Vanadium ug/L 1000 996 99.6 80.0-120 Zinc ug/L 1000 987 98.7 80.0-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: GM1.004-OXFORD LANDFILL UNIT 1 92659873 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909894-4 R3909894-5 MS MSD L1601556-04 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 1000 1000 981 980 98.1 98.0 75.0-125 0.108 20 Arsenic ug/L ND 1000 1000 972 957 97.2 95.7 75.0-125 1.51 20 Barium ug/L 120 1000 1000 1160 1150 104 103 75.0-125 0.534 20 Beryllium ug/L ND 1000 1000 971 969 97.1 96.9 75.0-125 0.284 20 Cadmium ug/L ND 1000 1000 1010 1010 101 101 75.0-125 0.233 20 Chromium ug/L 3.27 1000 1000 981 978 97.8 97.5 75.0-125 0.258 20 Cobalt ug/L ND 1000 1000 1030 1020 103 102 75.0-125 0.659 20 Copper ug/L ND 1000 1000 993 999 99.3 99.9 75.0-125 0.598 20 Iron ug/L 498 10000 10000 10500 10600 100 101 75.0-125 0.571 20 Lead ug/L ND 1000 1000 992 993 99.2 99.3 75.0-125 0.136 20 Manganese ug/L 48.1 1000 1000 965 963 91.7 91.5 75.0-125 0.204 20 Nickel ug/L 4.65 1000 1000 980 973 97.5 96.8 75.0-125 0.693 20 Selenium ug/L ND 1000 1000 972 992 97.2 99.2 75.0-125 2.07 20 Silver ug/L ND 200 200 188 188 94.2 93.9 75.0-125 0.232 20 Vanadium ug/L ND 1000 1000 1000 986 100 98.6 75.0-125 1.39 20 Zinc ug/L ND 1000 1000 968 967 96.8 96.7 75.0-125 0.039 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 2035938 Analysis Method: EPA 6020B QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659873001, 92659873002 METHOD BLANK: R3909560-1 Matrix: Water Associated Lab Samples: 92659873001, 92659873002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L 0.172J 2.00 0.121 04/05/2312:01 J LABORATORY CONTROL SAMPLE: R3909560-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 50.0 48.4 96.7 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909560-4 R3909560-5 MS MSD L1601349-02 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 50.0 50.0 48.2 50.0 96.5 100 75.0-125 3.58 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 2035977 Analysis Method: EPA 6020B QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659873003 METHOD BLANK: R3909766-1 Associated Lab Samples: 92659873003 Parameter Units Thallium ug/L LABORATORY CONTROL SAMPLE: R3909766-2 Parameter Units Thallium ug/L Matrix: Water Blank Reporting Result Limit ND 2.00 Spike LCS Conc. Result 50.0 46.9 MDL Analyzed Qualifiers 0.121 04/05/23 15:08 LCS % Rec % Rec Limits Qualifiers 93.8 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909766-4 R3909766-5 MS MSD L1601546-02 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 50.0 50.0 46.1 49.3 92.2 98.7 75.0-125 6.81 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 2036393 Analysis Method: EPA 7470A QC Batch Method: 7470A Analysis Description: Mercury 7470A Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: R3910690-1 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.200 0.100 04/07/2313:35 LABORATORY CONTROL SAMPLE: R3910690-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 3.00 2.92 97.3 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3910690-3 R3910690-4 MS MSD L1601848-02 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 3.00 3.00 2.96 3.01 98.7 100 75.0-125 1.68 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 765925 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659873001, 92659873002 METHOD BLANK: 3976787 Associated Lab Samples: 92659873001, 92659873002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/07/23 01:35 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/07/23 01:35 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/07/23 01:35 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/07/23 01:35 1,1-Dichloroethane ug/L ND 1.0 0.37 04/07/23 01:35 1,1-Dichloroethene ug/L ND 1.0 0.35 04/07/23 01:35 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 04/07/23 01:35 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/07/23 01:35 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/07/23 01:35 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/07/23 01:35 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/07/23 01:35 1,2-Dichloroethane ug/L ND 1.0 0.32 04/07/23 01:35 1,2-Dichloropropane ug/L ND 1.0 0.36 04/07/23 01:35 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/07/23 01:35 2-Butanone (MEK) ug/L ND 5.0 4.0 04/07/23 01:35 2-Hexanone ug/L ND 5.0 0.48 04/07/23 01:35 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/07/23 01:35 Acetone ug/L ND 25.0 5.1 04/07/23 01:35 Acrylonitrile ug/L ND 10.0 1.8 04/07/23 01:35 Benzene ug/L ND 1.0 0.34 04/07/23 01:35 Bromochloromethane ug/L ND 1.0 0.47 04/07/23 01:35 Bromodichloromethane ug/L ND 1.0 0.31 04/07/23 01:35 Bromoform ug/L ND 1.0 0.34 04/07/23 01:35 Bromomethane ug/L ND 2.0 1.7 04/07/23 01:35 v2 Carbon disulfide ug/L ND 2.0 0.36 04/07/23 01:35 Carbon tetrachloride ug/L ND 1.0 0.33 04/07/23 01:35 Chlorobenzene ug/L ND 1.0 0.28 04/07/23 01:35 Chloroethane ug/L ND 1.0 0.65 04/07/23 01:35 Chloroform ug/L ND 1.0 0.43 04/07/23 01:35 Chloromethane ug/L ND 1.0 0.54 04/07/23 01:35 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/07/23 01:35 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 01:35 Dibromochloromethane ug/L ND 1.0 0.36 04/07/23 01:35 Dibromomethane ug/L ND 1.0 0.39 04/07/23 01:35 Ethylbenzene ug/L ND 1.0 0.30 04/07/23 01:35 lodomethane ug/L ND 20.0 9.7 04/07/23 01:35 v2 Methylene Chloride ug/L 3.2J 5.0 2.0 04/07/23 01:35 C9,v1 Styrene ug/L ND 1.0 0.29 04/07/23 01:35 Tetrachloroethene ug/L ND 1.0 0.29 04/07/23 01:35 Tetrahydrofuran ug/L ND 10.0 3.5 04/07/23 01:35 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 METHOD BLANK: 3976787 Associated Lab Samples: 92659873001, 92659873002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 04/07/23 01:35 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/07/23 01:35 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 01:35 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 04/07/23 01:35 v2 Trichloroethene ug/L ND 1.0 0.38 04/07/23 01:35 Trichlorofluoromethane ug/L ND 1.0 0.30 04/07/23 01:35 Vinyl acetate ug/L ND 2.0 1.3 04/07/23 01:35 Vinyl chloride ug/L ND 1.0 0.39 04/07/23 01:35 Xylene (Total) ug/L ND 1.0 0.34 04/07/23 01:35 1,2-Dichloroethane-d4 (S) % 109 70-130 04/07/23 01:35 4-Bromofluorobenzene (S) % 98 70-130 04/07/23 01:35 Toluene-d8 (S) % 102 70-130 04/07/23 01:35 LABORATORY CONTROL SAMPLE: Parameter 3976788 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 19.8 99 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.8 104 70-130 1,1,2-Trichloroethane ug/L 20 19.8 99 70-130 1,1-Dichloroethane ug/L 20 19.2 96 70-130 1,1-Dichloroethene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 20.3 101 70-130 1,2,3-Trichloropropane ug/L 20 20.0 100 70-130 1,2-Dibromo-3-chloropropane ug/L 20 21.1 105 70-131 1,2-Dibromoethane (EDB) ug/L 20 20.2 101 70-130 1,2-Dichlorobenzene ug/L 20 20.0 100 70-130 1,2-Dichloroethane ug/L 20 19.8 99 70-130 1,2-Dichloropropane ug/L 20 20.5 102 70-130 1,4-Dichlorobenzene ug/L 20 19.7 99 70-130 2-Butanone (MEK) ug/L 40 42.0 105 70-134 2-Hexanone ug/L 40 44.7 112 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 43.2 108 70-130 Acetone ug/L 40 41.6 104 70-133 Acrylonitrile ug/L 100 99.4 99 70-130 Benzene ug/L 20 18.7 93 70-130 Bromochloromethane ug/L 20 19.8 99 70-130 Bromodichloromethane ug/L 20 18.9 94 70-130 Bromoform ug/L 20 18.5 92 70-130 Bromomethane ug/L 20 12.1 61 45-151 v3 Carbon disulfide ug/L 20 17.9 90 70-130 Carbon tetrachloride ug/L 20 17.6 88 70-130 Chlorobenzene ug/L 20 19.5 97 70-130 Chloroethane ug/L 20 21.6 108 39-152 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 LABORATORY CONTROL SAMPLE: 3976788 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Chloroform ug/L 20 19.7 99 70-130 Chloromethane ug/L 20 17.1 86 58-130 cis-1,2-Dichloroethene ug/L 20 19.4 97 70-130 cis-1,3-Dichloropropene ug/L 20 18.8 94 70-130 Dibromochloromethane ug/L 20 19.0 95 70-130 Dibromomethane ug/L 20 18.5 93 70-130 Ethylbenzene ug/L 20 19.2 96 70-130 lodomethane ug/L 40 22.9 57 53-141 v3 Methylene Chloride ug/L 20 36.6 183 66-130 L1,v1 Styrene ug/L 20 20.1 101 70-130 Tetrachloroethene ug/L 20 19.3 96 70-130 Tetrahydrofuran ug/L 200 205 103 70-130 Toluene ug/L 20 19.0 95 70-130 trans-1,2-Dichloroethene ug/L 20 19.3 97 70-130 trans- 1,3-Dichloropropene ug/L 20 18.6 93 70-130 trans-1,4-Dichloro-2-butene ug/L 20 20.2 101 57-185 v3 Trichloroethene ug/L 20 18.5 92 70-130 Trichlorofluoromethane ug/L 20 17.0 85 62-130 Vinyl acetate ug/L 40 40.6 102 70-144 Vinyl chloride ug/L 20 14.8 74 62-130 Xylene (Total) ug/L 60 57.7 96 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: Parameter 3976790 Units 92659909001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 22.9 115 70-141 1,1,1-Trichloroethane ug/L ND 20 21.9 109 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.1 121 69-142 1,1,2-Trichloroethane ug/L ND 20 23.2 116 70-138 1,1-Dichloroethane ug/L ND 20 21.9 110 70-150 1,1-Dichloroethene ug/L ND 20 22.7 113 70-156 1,2,3-Trichlorobenzene ug/L ND 20 24.0 120 70-148 1,2,3-Trichloropropane ug/L ND 20 23.3 117 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 24.0 120 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 23.0 115 70-138 1,2-Dichlorobenzene ug/L ND 20 23.5 117 70-141 1,2-Dichloroethane ug/L ND 20 22.3 111 69-143 1,2-Dichloropropane ug/L ND 20 23.2 116 68-156 1,4-Dichlorobenzene ug/L ND 20 23.4 117 70-142 2-Butanone (MEK) ug/L ND 40 47.1 118 60-157 2-Hexanone ug/L ND 40 50.9 127 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 49.1 123 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 MATRIX SPIKE SAMPLE: 3976790 92659909001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Acetone ug/L ND 40 44.1 110 58-157 Acrylonitrile ug/L ND 100 114 114 69-147 Benzene ug/L ND 20 21.6 108 70-142 Bromochloromethane ug/L ND 20 22.2 111 70-146 Bromodichloromethane ug/L ND 20 22.3 112 70-139 Bromoform ug/L ND 20 22.4 112 64-140 Bromomethane ug/L ND 20 14.7 73 28-192 v3 Carbon disulfide ug/L ND 20 21.0 105 70-151 Carbon tetrachloride ug/L ND 20 22.0 110 70-148 Chlorobenzene ug/L ND 20 22.7 114 70-141 Chloroethane ug/L ND 20 21.2 106 58-191 Chloroform ug/L ND 20 22.1 111 70-148 Chloromethane ug/L ND 20 16.3 82 43-162 cis-1,2-Dichloroethene ug/L ND 20 22.1 110 68-151 cis-1,3-Dichloropropene ug/L ND 20 22.0 110 70-139 Dibromochloromethane ug/L ND 20 22.5 113 70-144 Dibromomethane ug/L ND 20 20.9 104 70-139 Ethylbenzene ug/L ND 20 22.8 114 70-143 lodomethane ug/L ND 40 34.7 87 35-171 IL,v3 Methylene Chloride ug/L ND 20 27.3 118 62-149 v1 Styrene ug/L ND 20 23.5 118 70-143 Tetrachloroethene ug/L ND 20 21.9 109 70-145 Tetrahydrofuran ug/L ND 200 222 111 69-144 Toluene ug/L ND 20 22.1 110 70-142 trans-1,2-Dichloroethene ug/L ND 20 22.2 111 70-151 trans- 1,3-Dichloropropene ug/L ND 20 22.7 114 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 21.7 108 51-159 Trichloroethene ug/L ND 20 21.9 109 62-146 Trichlorofluoromethane ug/L ND 20 19.6 98 63-153 Vinyl acetate ug/L ND 40 45.9 115 61-162 Vinyl chloride ug/L ND 20 15.2 76 61-163 Xylene (Total) ug/L ND 60 69.0 115 70-143 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 3976789 92659873001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 46 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 SAMPLE DUPLICATE: 3976789 Parameter Units 92659873001 Result Dup Result RPD Max RPD Qualifiers 1,2,3-Trichlorobenzene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 301L,v2 Methylene Chloride ug/L 4.OJ ND 30 v1 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 113 111 4-Bromofluorobenzene (S) % 96 98 Toluene-d8 (S) % 100 100 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 765937 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659873003 METHOD BLANK: 3976888 Associated Lab Samples: 92659873003 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/07/23 00:43 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/07/23 00:43 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/07/23 00:43 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/07/23 00:43 1,1-Dichloroethane ug/L ND 1.0 0.37 04/07/23 00:43 1,1-Dichloroethene ug/L ND 1.0 0.35 04/07/23 00:43 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 04/07/23 00:43 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/07/23 00:43 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/07/23 00:43 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/07/23 00:43 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/07/23 00:43 1,2-Dichloroethane ug/L ND 1.0 0.32 04/07/23 00:43 1,2-Dichloropropane ug/L ND 1.0 0.36 04/07/23 00:43 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/07/23 00:43 2-Butanone (MEK) ug/L ND 5.0 4.0 04/07/23 00:43 2-Hexanone ug/L ND 5.0 0.48 04/07/23 00:43 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/07/23 00:43 Acetone ug/L ND 25.0 5.1 04/07/23 00:43 Acrylonitrile ug/L ND 10.0 1.8 04/07/23 00:43 Benzene ug/L ND 1.0 0.34 04/07/23 00:43 Bromochloromethane ug/L ND 1.0 0.47 04/07/23 00:43 Bromodichloromethane ug/L ND 1.0 0.31 04/07/23 00:43 Bromoform ug/L ND 1.0 0.34 04/07/23 00:43 Bromomethane ug/L ND 2.0 1.7 04/07/23 00:43 Carbon disulfide ug/L ND 2.0 0.36 04/07/23 00:43 Carbon tetrachloride ug/L ND 1.0 0.33 04/07/23 00:43 Chlorobenzene ug/L ND 1.0 0.28 04/07/23 00:43 Chloroethane ug/L ND 1.0 0.65 04/07/23 00:43 Chloroform ug/L ND 1.0 0.43 04/07/23 00:43 Chloromethane ug/L ND 1.0 0.54 04/07/23 00:43 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/07/23 00:43 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 00:43 Dibromochloromethane ug/L ND 1.0 0.36 04/07/23 00:43 Dibromomethane ug/L ND 1.0 0.39 04/07/23 00:43 Ethylbenzene ug/L ND 1.0 0.30 04/07/23 00:43 lodomethane ug/L ND 20.0 9.7 04/07/23 00:43 Methylene Chloride ug/L ND 5.0 2.0 04/07/23 00:43 Styrene ug/L ND 1.0 0.29 04/07/23 00:43 Tetrachloroethene ug/L ND 1.0 0.29 04/07/23 00:43 Tetrahydrofuran ug/L ND 10.0 3.5 04/07/23 00:43 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 METHOD BLANK: 3976888 Associated Lab Samples: 92659873003 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Toluene ug/L ND 1.0 0.24 04/07/23 00:43 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/07/23 00:43 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 00:43 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 04/07/23 00:43 Trichloroethene ug/L ND 1.0 0.38 04/07/23 00:43 Trichlorofluoromethane ug/L ND 1.0 0.30 04/07/23 00:43 Vinyl acetate ug/L ND 2.0 1.3 04/07/23 00:43 Vinyl chloride ug/L ND 1.0 0.39 04/07/23 00:43 Xylene (Total) ug/L ND 1.0 0.34 04/07/23 00:43 1,2-Dichloroethane-d4 (S) % 98 70-130 04/07/23 00:43 4-Bromofluorobenzene (S) % 100 70-130 04/07/23 00:43 Toluene-d8 (S) % 97 70-130 04/07/23 00:43 LABORATORY CONTROL SAMPLE: Parameter 3976889 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 20 21.2 106 70-130 1,1,1-Trichloroethane ug/L 20 19.0 95 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.2 106 70-130 1,1,2-Trichloroethane ug/L 20 20.5 102 70-130 1,1-Dichloroethane ug/L 20 18.4 92 70-130 1,1-Dichloroethene ug/L 20 18.2 91 70-130 1,2,3-Trichlorobenzene ug/L 20 22.1 111 70-130 1,2,3-Trichloropropane ug/L 20 20.5 102 70-130 1,2-Dibromo-3-chloropropane ug/L 20 20.8 104 70-131 1,2-Dibromoethane (EDB) ug/L 20 20.7 104 70-130 1,2-Dichlorobenzene ug/L 20 21.3 107 70-130 1,2-Dichloroethane ug/L 20 19.5 97 70-130 1,2-Dichloropropane ug/L 20 19.9 100 70-130 1,4-Dichlorobenzene ug/L 20 21.4 107 70-130 2-Butanone (MEK) ug/L 40 37.1 93 70-134 2-Hexanone ug/L 40 40.2 100 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 39.2 98 70-130 Acetone ug/L 40 31.1 78 70-133 Acrylonitrile ug/L 100 90.6 91 70-130 Benzene ug/L 20 19.5 98 70-130 Bromochloromethane ug/L 20 19.1 96 70-130 Bromodichloromethane ug/L 20 19.7 98 70-130 Bromoform ug/L 20 20.5 103 70-130 Bromomethane ug/L 20 15.2 76 45-151 Carbon disulfide ug/L 20 16.8 84 70-130 Carbon tetrachloride ug/L 20 19.7 99 70-130 Chlorobenzene ug/L 20 20.9 105 70-130 Chloroethane ug/L 20 17.9 90 39-152 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 LABORATORY CONTROL SAMPLE: Parameter 3976889 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 17.0 85 58-130 cis-1,2-Dichloroethene ug/L 20 18.6 93 70-130 cis-1,3-Dichloropropene ug/L 20 19.8 99 70-130 Dibromochloromethane ug/L 20 20.6 103 70-130 Dibromomethane ug/L 20 20.6 103 70-130 Ethylbenzene ug/L 20 20.4 102 70-130 lodomethane ug/L 40 36.3 91 53-141 Methylene Chloride ug/L 20 15.6 78 66-130 Styrene ug/L 20 21.0 105 70-130 Tetrachloroethene ug/L 20 20.1 100 70-130 Tetrahydrofuran ug/L 200 174 87 70-130 Toluene ug/L 20 19.6 98 70-130 trans-1,2-Dichloroethene ug/L 20 18.4 92 70-130 trans- 1,3-Dichloropropene ug/L 20 19.8 99 70-130 trans-1,4-Dichloro-2-butene ug/L 20 22.5 113 57-185 Trichloroethene ug/L 20 20.2 101 70-130 Trichlorofluoromethane ug/L 20 18.2 91 62-130 Vinyl acetate ug/L 40 38.7 97 70-144 Vinyl chloride ug/L 20 14.9 74 62-130 Xylene (Total) ug/L 60 61.3 102 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 3976891 Units 92659923009 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 25.7 129 70-141 1,1,1-Trichloroethane ug/L ND 20 20.6 103 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.5 122 69-142 1,1,2-Trichloroethane ug/L ND 20 22.3 111 70-138 1,1-Dichloroethane ug/L ND 20 18.7 94 70-150 1,1-Dichloroethene ug/L ND 20 21.5 107 70-156 1,2,3-Trichlorobenzene ug/L ND 20 27.8 139 70-148 1,2,3-Trichloropropane ug/L ND 20 23.9 120 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 25.2 126 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 25.2 126 70-138 1,2-Dichlorobenzene ug/L ND 20 26.2 131 70-141 1,2-Dichloroethane ug/L ND 20 21.3 106 69-143 1,2-Dichloropropane ug/L ND 20 22.2 111 68-156 1,4-Dichlorobenzene ug/L ND 20 25.7 128 70-142 2-Butanone (MEK) ug/L ND 40 42.4 106 60-157 2-Hexanone ug/L ND 40 48.5 121 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 43.7 109 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 MATRIX SPIKE SAMPLE: 3976891 92659923009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Acetone ug/L ND 40 37.5 94 58-157 Acrylonitrile ug/L ND 100 104 104 69-147 Benzene ug/L ND 20 22.3 112 70-142 Bromochloromethane ug/L ND 20 21.7 108 70-146 Bromodichloromethane ug/L ND 20 22.0 110 70-139 Bromoform ug/L ND 20 26.4 132 64-140 Bromomethane ug/L ND 20 19.0 95 28-192 Carbon disulfide ug/L ND 20 20.4 102 70-151 Carbon tetrachloride ug/L ND 20 22.5 112 70-148 Chlorobenzene ug/L ND 20 24.9 124 70-141 Chloroethane ug/L ND 20 24.2 121 58-191 Chloroform ug/L ND 20 20.5 103 70-148 Chloromethane ug/L ND 20 22.8 114 43-162 cis-1,2-Dichloroethene ug/L ND 20 20.5 102 68-151 cis-1,3-Dichloropropene ug/L ND 20 22.7 113 70-139 Dibromochloromethane ug/L ND 20 25.7 128 70-144 Dibromomethane ug/L ND 20 22.9 114 70-139 Ethylbenzene ug/L ND 20 23.9 119 70-143 lodomethane ug/L ND 40 45.1 113 35-171 Methylene Chloride ug/L ND 20 8.9 45 62-149 IK,M1,v3 Styrene ug/L ND 20 24.6 123 70-143 Tetrachloroethene ug/L ND 20 23.5 117 70-145 Tetrahydrofuran ug/L ND 200 177 88 69-144 Toluene ug/L ND 20 21.5 107 70-142 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-151 trans- 1,3-Dichloropropene ug/L ND 20 22.6 113 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 25.1 125 51-159 Trichloroethene ug/L ND 20 22.3 112 62-146 Trichlorofluoromethane ug/L ND 20 23.0 115 63-153 Vinyl acetate ug/L ND 40 39.9 100 61-162 Vinyl chloride ug/L ND 20 18.4 92 61-163 Xylene (Total) ug/L ND 60 72.3 121 70-143 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 3976890 92659670001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 SAMPLE DUPLICATE: 3976890 Parameter Units 92659670001 Result Dup Result RPD Max RPD 1,2,3-Trichlorobenzene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 v2 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 99 102 4-Bromofluorobenzene (S) % 98 99 Toluene-d8 (S) % 97 96 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 766318 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659873004 METHOD BLANK: 3978973 Associated Lab Samples: 92659873004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/07/23 02:34 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/07/23 02:34 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/07/23 02:34 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/07/23 02:34 1,1-Dichloroethane ug/L ND 1.0 0.37 04/07/23 02:34 1,1-Dichloroethene ug/L ND 1.0 0.35 04/07/23 02:34 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 04/07/23 02:34 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/07/23 02:34 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/07/23 02:34 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/07/23 02:34 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/07/23 02:34 1,2-Dichloroethane ug/L ND 1.0 0.32 04/07/23 02:34 1,2-Dichloropropane ug/L ND 1.0 0.36 04/07/23 02:34 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/07/23 02:34 2-Butanone (MEK) ug/L ND 5.0 4.0 04/07/23 02:34 2-Hexanone ug/L ND 5.0 0.48 04/07/23 02:34 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/07/23 02:34 Acetone ug/L ND 25.0 5.1 04/07/23 02:34 Acrylonitrile ug/L ND 10.0 1.8 04/07/23 02:34 Benzene ug/L ND 1.0 0.34 04/07/23 02:34 Bromochloromethane ug/L ND 1.0 0.47 04/07/23 02:34 Bromodichloromethane ug/L ND 1.0 0.31 04/07/23 02:34 Bromoform ug/L ND 1.0 0.34 04/07/23 02:34 Bromomethane ug/L ND 2.0 1.7 04/07/23 02:34 Carbon disulfide ug/L ND 2.0 0.36 04/07/23 02:34 Carbon tetrachloride ug/L ND 1.0 0.33 04/07/23 02:34 Chlorobenzene ug/L ND 1.0 0.28 04/07/23 02:34 Chloroethane ug/L ND 1.0 0.65 04/07/23 02:34 Chloroform ug/L ND 1.0 0.43 04/07/23 02:34 Chloromethane ug/L ND 1.0 0.54 04/07/23 02:34 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/07/23 02:34 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 02:34 Dibromochloromethane ug/L ND 1.0 0.36 04/07/23 02:34 Dibromomethane ug/L ND 1.0 0.39 04/07/23 02:34 Ethylbenzene ug/L ND 1.0 0.30 04/07/23 02:34 lodomethane ug/L ND 20.0 9.7 04/07/23 02:34 Methylene Chloride ug/L 2.5J 5.0 2.0 04/07/23 02:34 C9,v1 Styrene ug/L ND 1.0 0.29 04/07/23 02:34 Tetrachloroethene ug/L ND 1.0 0.29 04/07/23 02:34 Toluene ug/L ND 1.0 0.24 04/07/23 02:34 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 METHOD BLANK: 3978973 Associated Lab Samples: 92659873004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/07/23 02:34 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 02:34 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 04/07/23 02:34 Trichloroethene ug/L ND 1.0 0.38 04/07/23 02:34 Trichlorofluoromethane ug/L ND 1.0 0.30 04/07/23 02:34 Vinyl acetate ug/L ND 2.0 1.3 04/07/23 02:34 IK Vinyl chloride ug/L ND 1.0 0.39 04/07/23 02:34 Xylene (Total) ug/L ND 1.0 0.34 04/07/23 02:34 1,2-Dichloroethane-d4 (S) % 95 70-130 04/07/23 02:34 4-Bromofluorobenzene (S) % 95 70-130 04/07/23 02:34 Toluene-d8 (S) % 108 70-130 04/07/23 02:34 LABORATORY CONTROL SAMPLE: 3978974 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.9 95 70-130 1,1,1-Trichloroethane ug/L 20 18.5 93 70-130 1,1,2,2-Tetrachloroethane ug/L 20 19.8 99 70-130 1,1,2-Trichloroethane ug/L 20 19.5 97 70-130 1,1-Dichloroethane ug/L 20 17.4 87 70-130 1,1-Dichloroethene ug/L 20 17.8 89 70-130 1,2,3-Trichlorobenzene ug/L 20 23.4 117 70-130 1,2,3-Trichloropropane ug/L 20 19.2 96 70-130 1,2-Dibromo-3-chloropropane ug/L 20 18.9 95 70-131 1,2-Dibromoethane (EDB) ug/L 20 19.7 99 70-130 1,2-Dichlorobenzene ug/L 20 19.5 98 70-130 1,2-Dichloroethane ug/L 20 18.2 91 70-130 1,2-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2-Butanone (MEK) ug/L 40 40.6 102 70-134 2-Hexanone ug/L 40 44.0 110 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 42.1 105 70-130 Acetone ug/L 40 35.3 88 70-133 Acrylonitrile ug/L 100 96.7 97 70-130 Benzene ug/L 20 18.5 93 70-130 Bromochloromethane ug/L 20 17.3 87 70-130 Bromodichloromethane ug/L 20 18.0 90 70-130 Bromoform ug/L 20 18.2 91 70-130 Bromomethane ug/L 20 17.2 86 45-151 Carbon disulfide ug/L 20 15.6 78 70-130 Carbon tetrachloride ug/L 20 19.3 96 70-130 Chlorobenzene ug/L 20 18.8 94 70-130 Chloroethane ug/L 20 19.8 99 39-152 Chloroform ug/L 20 16.8 84 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 46 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 LABORATORY CONTROL SAMPLE: Parameter 3978974 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloromethane ug/L 20 18.7 94 58-130 cis-1,2-Dichloroethene ug/L 20 17.6 88 70-130 cis-1,3-Dichloropropene ug/L 20 20.2 101 70-130 Dibromochloromethane ug/L 20 18.1 90 70-130 Dibromomethane ug/L 20 18.5 93 70-130 Ethylbenzene ug/L 20 18.6 93 70-130 lodomethane ug/L 40 40.9 102 53-141 Methylene Chloride ug/L 20 39.2 196 66-130 L1,v1 Styrene ug/L 20 18.6 93 70-130 Tetrachloroethene ug/L 20 17.6 88 70-130 Toluene ug/L 20 18.8 94 70-130 trans-1,2-Dichloroethene ug/L 20 17.6 88 70-130 trans- 1,3-Dichloropropene ug/L 20 19.1 95 70-130 trans-1,4-Dichloro-2-butene ug/L 20 24.5 123 57-185 Trichloroethene ug/L 20 19.0 95 70-130 Trichlorofluoromethane ug/L 20 18.9 94 62-130 Vinyl acetate ug/L 40 34.3 86 70-144 IK Vinyl chloride ug/L 20 16.6 83 62-130 Xylene (Total) ug/L 60 55.4 92 70-130 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978975 MS 92659909002 Spike Parameter Units Result Conc. MSD Spike Conc. 3978976 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 24.0 27.3 120 136 70-141 13 30 1,1,1-Trichloroethane ug/L ND 20 20 21.7 24.2 108 121 70-150 11 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.3 25.6 112 128 69-142 14 30 1,1,2-Trichloroethane ug/L ND 20 20 22.5 25.7 113 129 70-138 13 30 1,1-Dichloroethane ug/L ND 20 20 20.5 22.8 102 114 70-150 10 30 1,1-Dichloroethene ug/L ND 20 20 20.9 23.2 105 116 70-156 10 30 1,2,3-Trichlorobenzene ug/L 24.8 27.1 9 30 1,2,3-Trichloropropane ug/L ND 20 20 21.9 25.4 110 127 70-140 15 30 1,2-Dibromo-3- ug/L ND 20 20 21.8 24.4 109 122 68-146 11 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 23.0 26.7 115 133 70-138 15 30 1,2-Dichlorobenzene ug/L ND 20 20 23.7 25.9 119 129 70-141 9 30 1,2-Dichloroethane ug/L ND 20 20 20.9 23.7 104 118 69-143 13 30 1,2-Dichloropropane ug/L ND 20 20 22.0 24.9 110 124 68-156 12 30 1,4-Dichlorobenzene ug/L ND 20 20 23.4 25.3 117 126 70-142 8 30 2-Butanone (MEK) ug/L ND 40 40 42.6 49.2 106 123 60-157 14 30 2-Hexanone ug/L ND 40 40 50.6 59.5 127 149 68-146 16 30 M1 4-Methyl-2-pentanone ug/L ND 40 40 45.6 53.0 114 133 70-141 15 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978975 3978976 MS MSD 92659909002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 38.5 45.1 96 113 58-157 16 30 Acrylonitrile ug/L ND 100 100 103 117 103 117 69-147 13 30 Benzene ug/L ND 20 20 21.3 23.9 107 120 70-142 12 30 Bromochloromethane ug/L ND 20 20 21.4 24.0 107 120 70-146 11 30 Bromodichloromethane ug/L ND 20 20 21.8 24.6 109 123 70-139 12 30 Bromoform ug/L ND 20 20 23.5 26.5 118 133 64-140 12 30 Bromomethane ug/L ND 20 20 11.8 12.5 59 63 28-192 6 30 v3 Carbon disulfide ug/L ND 20 20 20.1 22.1 100 110 70-151 10 30 Carbon tetrachloride ug/L ND 20 20 21.8 24.8 109 124 70-148 13 30 Chlorobenzene ug/L ND 20 20 23.1 25.8 116 129 70-141 11 30 Chloroethane ug/L ND 20 20 17.6 19.5 88 97 58-191 10 30 Chloroform ug/L ND 20 20 20.9 23.1 105 116 70-148 10 30 Chloromethane ug/L ND 20 20 17.7 19.7 89 98 43-162 10 30 cis-1,2-Dichloroethene ug/L ND 20 20 20.6 23.2 103 116 68-151 12 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.1 25.4 111 127 70-139 14 30 Dibromochloromethane ug/L ND 20 20 23.3 26.4 116 132 70-144 12 30 Dibromomethane ug/L ND 20 20 22.8 25.8 114 129 70-139 12 30 Ethylbenzene ug/L ND 20 20 22.6 25.3 113 126 70-143 11 30 lodomethane ug/L ND 40 40 37.4 40.1 93 100 35-171 7 30 Methylene Chloride ug/L ND 20 20 23.4 26.4 111 127 62-149 12 30 v1 Styrene ug/L ND 20 20 23.6 26.5 118 132 70-143 11 30 Tetrachloroethene ug/L ND 20 20 21.7 24.4 109 122 70-145 12 30 Toluene ug/L ND 20 20 21.0 23.6 105 118 70-142 11 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.2 23.5 106 118 70-151 10 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.3 26.4 117 132 70-139 12 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 28.4 33.9 142 170 51-159 18 30 IH,M1 Trichloroethene ug/L ND 20 20 22.7 25.5 113 128 62-146 12 30 Trichlorofluoromethane ug/L ND 20 20 18.2 20.4 91 102 63-153 12 30 Vinyl acetate ug/L ND 40 40 41.4 47.5 103 119 61-162 14 30 Vinyl chloride ug/L ND 20 20 15.1 16.8 76 84 61-163 11 30 v1 Xylene (Total) ug/L ND 60 60 68.5 77.1 114 128 70-143 12 30 1,2-Dichloroethane-d4 (S) % 98 97 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 97 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 766177 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659873004 METHOD BLANK: 3978071 Matrix: Water Associated Lab Samples: 92659873004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/05/23 17:11 1,2-Dichloroethane-d4 (S) % 83 67-130 04/05/23 17:11 Toluene-d8 (S) % 87 70-130 04/05/23 17:11 LABORATORY CONTROL SAMPLE: 3978072 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.3 92 70-130 1,2-Dichloroethane-d4 (S) % 84 67-130 Toluene-d8 (S) % 88 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978073 3978074 MS MSD 92659945007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.8 18.0 88 89 55-137 1 30 H1 1,2-Dichloroethane-d4 (S) % 79 83 67-130 30 Toluene-d8 (S) % 89 88 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 766432 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: 3979517 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/06/23 18:46 1,2-Dichloroethane-d4 (S) % 103 67-130 04/06/23 18:46 Toluene-d8 (S) % 101 70-130 04/06/23 18:46 LABORATORY CONTROL SAMPLE: 3979518 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 103 67-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979519 3979520 MS MSD 92659681001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 4.6 20 20 21.1 20.8 82 81 55-137 2 30 H1 1,2-Dichloroethane-d4 (S) % 103 103 67-130 30 Toluene-d8(S) % 121 120 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 766516 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: 3980290 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 04/07/23 16:05 LABORATORY CONTROL SAMPLE: 3980291 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 51800 104 80-120 LABORATORY CONTROL SAMPLE: 3980292 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 52600 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980293 3980294 MS MSD 92659785001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 61.5 mg/L 50000 50000 111000 111000 99 100 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3980295 3980296 MS MSD 92660170004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 27.8 mg/L 50000 50000 77000 77100 98 99 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 46 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 765313 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: 3973916 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit Total Dissolved Solids mg/L ND 25.0 LABORATORY CONTROL SAMPLE: 3973917 Spike LCS Parameter Units Conc. Result Total Dissolved Solids mg/L 251 264 SAMPLE DUPLICATE: 3973918 92659509001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 189 184 MDL Analyzed Qualifiers 25.0 03/31 /23 19:53 LCS % Rec % Rec Limits Qualifiers 105 90-110 Max RPD RPD Qualifiers 3 25 SAMPLE DUPLICATE: 3973919 92659750001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids mg/L 61.0 66.0 8 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 765354 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: 3974002 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 04/01/2314:27 LABORATORY CONTROL SAMPLE: 3974003 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 47800 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974004 3974005 MS MSD 92659920001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 4.9 mg/L 50000 50000 53400 56600 97 104 90-110 6 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974006 3974007 MS MSD 92659873001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 9730 50000 50000 60000 61200 101 103 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 46 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 QC Batch: 766159 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659873001, 92659873002, 92659873003 METHOD BLANK: 3977945 Matrix: Water Associated Lab Samples: 92659873001, 92659873002, 92659873003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 04/05/2319:33 LABORATORY CONTROL SAMPLE: 3977946 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 21200 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977947 MS MSD 92659750002 Spike Spike Parameter Units Result Conc. Conc. Chloride ug/L 4.1 mg/L 10000 10000 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977949 MS MSD 92659750003 Spike Spike Parameter Units Result Conc. Conc. Chloride ug/L 3.2 mg/L 10000 10000 3977948 MS MSD MS MSD % Rec Max Result Result % Rec % Rec Limits RPD RPD Qual 14800 14300 106 102 90-110 3 10 3977950 MS MSD MS MSD % Rec Max Result Result % Rec % Rec Limits RPD RPD Qual 13900 13700 108 105 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS Analyte was detected in the associated method blank. C9 Common Laboratory Contaminant. H1 Analysis conducted outside the EPA method holding time. H5 Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659873 ANALYTE QUALIFIERS v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 08:39 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GM1.004-OXFORD LANDFILL UNIT 1 92659873 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92659873001 MW-2 3015 2035980 EPA 6010D 2035980 92659873002 MW-4R 3015 2035980 EPA 6010D 2035980 92659873003 MW-6R 3015 2035980 EPA 6010D 2035980 92659873001 MW-2 3015 2035938 EPA 6020B 2035938 92659873002 MW-4R 3015 2035938 EPA 6020B 2035938 92659873003 MW-6R 3015 2035977 EPA 6020B 2035977 92659873001 MW-2 7470A 2036393 EPA 7470A 2036393 92659873002 MW-4R 7470A 2036393 EPA 7470A 2036393 92659873003 MW-6R 7470A 2036393 EPA 7470A 2036393 92659873001 MW-2 EPA 8260D 765925 92659873002 MW-4R EPA 8260D 765925 92659873003 MW-6R EPA 8260D 765937 92659873004 TRIP BLANK 2 EPA 8260D 766318 92659873001 MW-2 EPA 8260D Mod. 766432 92659873002 MW-4R EPA 8260D Mod. 766432 92659873003 MW-6R EPA 8260D Mod. 766432 92659873004 TRIP BLANK 2 EPA 8260D Mod. 766177 92659873001 MW-2 SM 2320B-2011 766516 92659873002 MW-4R SM 2320B-2011 766516 92659873003 MW-6R SM 2320B-2011 766516 92659873001 MW-2 SM 2540C-2015 765313 92659873002 MW-4R SM 2540C-2015 765313 92659873003 MW-6R SM 2540C-2015 765313 92659873001 MW-2 EPA 300.0 Rev 2.1 1993 765354 92659873002 MW-4R EPA 300.0 Rev 2.1 1993 765354 92659873003 MW-6R EPA 300.0 Rev 2.1 1993 765354 92659873001 MW-2 SM 4500-CI-E-2011 766159 92659873002 MW-4R SM 4500-CI-E-2011 766159 92659873003 MW-6R SM 4500-CI-E-2011 766159 Date: 04/12/2023 08:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 46 r DC# -,Title: EW FRMrHUNI-i0Q83,ampla_C.ondition Upon Receipt Laboratory: iece[tVln8,saritlpies.s= stQnD' Ofee:nuvaa�. ❑ Hurttor Ville. R tei tjCl M chanicsvi[(e❑ Minn �e +narsuil[aQ Client N.erne: WO# . 926598 1 3 t�raject" __._ 4kMaA eb�Ir er: -fix Li -pp-, Mir hi II I III I II II II II III III S 0 RIt:fC�Bi ❑PSLe'. Other, 92659873 uatvdy Sea) Present. �Y45 �hlu Seals intact ❑1Fea . 4.N9 �Qate f Enfttsis Aersnn., Et[amin�ng;�oRtr nts:,�,����� 'PaWc A mat Nkh bbfe Wrap Bubb. OTifgs - .,, D Rdhe �.,.: ❑ Other Sick nal TisSitb:Kro=dn? 7tiermorttr;ter El: Q h!o NJA �. lR Cutt: ID- :...,. (ype of'IcR, P�$Vet QBlue ler Tern �fi .a .. p: ,.:--.I��DA Re�uiatad 8oif (. �l �N1,9f water sarriplej .. . ;..': �r: Ctidinplsflrig€nate in a.�uaraniine t4r�e Hntitln the:°404ed:states 'Cl NY, orC checkrirap;}71re; i!ta 0 Nooe -Tsrri,p'Waifd be abm:freeairng to fa"G : :5 mplesoutofte. criterla.5arnplespnice;taafirgAiuceSs h85Ugun :fit{;�er�pi�sr.;t'��nate:(rc�m a.�ttreign;squr�p (I�tg�eal[p�taily; � r.,j. DT., � � k.. 40 4' �+tR 3G -, y-•„ -: ei ..-,. _ i?f i.. ; 'n-d]i_ a..:j , - , �+'bdRftieiit4"prep fesArr3yed�wlthin Huld,lirrle7` Yes ;C�.Iun � A z:. Shbrtfftif I Tame Ahalysis (e72 hr: byes :2100 f30IA 3 : Rusin iitrn-� %sjid lime, Re nested? 0 Ygs 'lea C)N{A 4�,. tumciefltl lirr►fe? Yea ' dNo f7r�(A 5. .. vrr�ect &ontatners,wed? Yes :OW. : TWA G� Fate;:c�uainers 1lsed7 peYes �:Na i�M{A WntaiOft tMad? Yes Na . ' ©WfA 7, „ ............................ . :.:..,:..; .:. Cissc I44 urlai pis: 5amPfes:gl.Qli! Filtered? �Us I No N/A 8, .... _ _........... _..-.,. �W.... ?rnFie. LaCr�Js Match: C[lc7 Q'fsa.. /11 6riy .....t./ v >�ri s,� inclfesl3atelilme{ipl+al. in :ttt4tix:.:.: __...:..: . *Wadi ace Irt VOA Vibla (>S-Rrnf�;� aIY.'OS p ii4 . OWA M. Trip elartk Present? Yes [nio. L7t�fA 1, Trt- 90MMMISISAMPLE'DISCREFANCY Field Data.Reoulred? D-Yes; = N.o.: , ' `kQ.t iD oFS f i# iantainers:. . - CLIEM1ITN0I'IEIC�ITIDN{RE19.F- ipN P.,ar�pn •cuu►ta ct+a�:� ... Datef Tiri eF• _. . Project Msriage! SC,lffi;is. E;eiiiawE Date. ffm l7KQJect M3119ger9'fiF. Reufew. Dates _ Page 44 of 46 90MMMISISAMPLE'DISCREFANCY Field Data.Reoulred? D-Yes; = N.o.: , ' `kQ.t iD oFS f i# iantainers:. . - CLIEM1ITN0I'IEIC�ITIDN{RE19.F- ipN P.,ar�pn •cuu►ta ct+a�:� ... Datef Tiri eF• _. . Project Msriage! SC,lffi;is. E;eiiiawE Date. ffm l7KQJect M3119ger9'fiF. Reufew. Dates _ Page 44 of 46 �}/�/� DG# 71t1e'F,VY-FRCS!-HUN1.0.D8':r►�2 Sample Corttlitibr+.11pon.Recsipt if�ctive�'Ola#e 11/9A/;WZ 8:38: :AM --------------- *Check m irk:tap ii, lf of bpx; If.. oil" 0/0jech.Inrinatawfi.1sve.rifled and Prgje,; -#: WO# : 92659873 withitlLthg gccefito0ce f';'aK�e its pr nratiorr$gm�ilesr pM: TMC Due Date: 04/14/23 FxC@Ptlb*wViDA, Caf#iorw, TC1C, Oil and Grease, DRQjaril5 {yyr ter brcrgJLF 6 ��. CLIENT: 82—HaMrt—Ral **B.aktono haif�af�hax Is.to.ltai�numi�t�of batftes ' "*; kaO al unPc60rved NittalW fot chlorine , m a. Z. icyA. 93 Ell z R d ' N �q qr a:. ;; Ln «"':' a ilE' iG': 'J`. ! �' {��ry. *!►} CC 1.-. p� . 'q} �j y[ }= lt►�iyi� tv ' .I.t,'; L..j iK 1 1 1 K. II i fi. Ell ins" NINE INDMIMMEBOLIMME on NNENSIME an so MEMO an SM M an No MONS00,12, 0 on o�iUMMUS�■��i iiina i 81,011MMEL L :��!Wtrr.>r nt Log -for Pre .prved'I :mp Sample iD iype.afFieagryative p 'Time.:p.� ervAilOW, a�Jit$tecE. A60dfit of Preservi&e ridded. Lot tF f; i l�ote:�hevdrfhere#s a di5el�paRCY at%tt€d� Na�t#i �rallria cbr�tlsliailce's�rripleS,�copy:a{this ftir�ti'h�, 711' �e'se'r�t to#�f� ititd�th r��i�a, C�l;f�1�.C+eCtiBcatlar� t�fFir:� $45 of 46 , :wu�_nr:ne�pf �nc�rr��x:.�rsservative out�t 4'eClilp� 1ncArl�EcC c¢ntainers, � � ' I 6 w �+ m @ E q C . a+ a :;s C� a c W a C G � U J FN O r C 0 w Z LJL � 0 CL Z u 5 cc U�c E Im 8 �8 $ . c a a a 'll 1C Y a �E W 81 12 m go Pp U v iNIA) &uliolgo lunplse» ,luere dl,l euecclq v' 6 W19 dIJA LIMOJIGHOwleri I ddy WIS 09N Aq euQUOP q' L .4I4-L449L9 Aq OOA I ddy Allulie w Sub, O'OOC Aq GIVOIS � RAI�Qf4� Javlo loueylelp 19 EObSLRN M F° HORN g IOH c IL CONH bOWH ti °- � � ADuessuduO 9k3rnalD,o�30# FCS,1'31i0�1V dW3A 3ldWY5 0 Cg.7 c (di4Q}� 9VMO=9) 3d�1137dN1V5 (Oa, al TOM AW sss) 3CIO9 XIkllYW D E $O3 iac�4¢�Q� 5� yy 41;3L 'CO #q 0 1-7 Li (NIA) losluj 6aldWeg Nth MMOD paleaS O W dwal Al Will Page 46 of 46 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 April 12, 2023 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21LA 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Lab ID Sample ID Matrix Date Collected Date Received 92659941001 92659941002 SW-1 SW-2 Water Water 03/30/2314:13 03/30/2313:55 03/31/2310:30 03/31/2310:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659941001 SW-1 EPA 601OD ZSA 14 PAN EPA 6020E JPD 1 PAN EPA 8260D CL 50 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM2340-97 ZSA 1 PAN 92659941002 SW-2 EPA 601OD ZSA 14 PAN EPA 6020E JPD 1 PAN EPA 8260D CL 50 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM2340-97 ZSA 1 PAN PAN = Pace National - Mt. Juliet PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Sample: SW-1 Lab ID: 92659941001 Collected: 03/30/23 14:13 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/05/23 07:27 04/05/23 11:58 7440-36-0 Arsenic 5.38J ug/L 10.0 4.40 1 04/05/23 07:27 04/05/23 11:58 7440-38-2 J Barium 14.7 ug/L 5.00 0.736 1 04/05/23 07:27 04/05/23 11:58 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/05/23 07:27 04/05/23 11:58 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/05/23 07:27 04/05/23 11:58 7440-43-9 Chromium 2.45J ug/L 10.0 1.40 1 04/05/23 07:27 04/05/23 11:58 7440-47-3 J Cobalt 1.68J ug/L 10.0 0.840 1 04/05/23 07:27 04/05/23 11:58 7440-48-4 J Copper 4.13J ug/L 10.0 3.68 1 04/05/23 07:27 04/05/23 11:58 7440-50-8 J Lead ND ug/L 6.00 2.99 1 04/05/23 07:27 04/05/23 11:58 7439-92-1 Nickel 4.16J ug/L 10.0 1.61 1 04/05/23 07:27 04/05/23 11:58 7440-02-0 B,J Selenium ND ug/L 10.0 7.35 1 04/05/23 07:27 04/05/23 11:58 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/05/23 07:27 04/05/23 11:58 7440-22-4 Vanadium ND ug/L 20.0 4.99 1 04/05/23 07:27 04/05/23 11:58 7440-62-2 Zinc 29.7J ug/L 50.0 6.52 1 04/05/23 07:27 04/05/23 11:58 7440-66-6 J Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 08:22 04/05/23 15:04 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/07/23 03:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/07/23 03:52 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/07/23 03:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/07/23 03:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/07/23 03:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/07/23 03:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/07/23 03:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/07/23 03:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/07/23 03:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/07/23 03:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/07/23 03:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/07/23 03:52 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/07/23 03:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/07/23 03:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/07/23 03:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/07/23 03:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/07/23 03:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/07/23 03:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/07/23 03:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/07/23 03:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/07/23 03:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/07/23 03:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/07/23 03:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/07/23 03:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Sample: SW-1 Lab ID: 92659941001 Collected: 03/30/23 14:13 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Calculated Results Hardness, Total(SM 234013) Date: 04/12/2023 07:35 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 95 % 70-130 105 % 70-130 103 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 97 % 67-130 120 % 70-130 0.38 1 04/07/23 03:52 156-59-2 0.40 1 04/07/23 03:52 156-60-5 0.36 1 04/07/23 03:52 78-87-5 0.36 1 04/07/23 03:52 10061-01-5 0.36 1 04/07/23 03:52 10061-02-6 0.30 1 04/07/23 03:52 100-41-4 0.48 1 04/07/23 03:52 591-78-6 9.7 1 04/07/23 03:52 74-88-4 2.0 1 04/07/23 03:52 75-09-2 L1,v1 2.7 1 04/07/23 03:52 108-10-1 0.29 1 04/07/23 03:52 100-42-5 0.31 1 04/07/23 03:52 630-20-6 0.22 1 04/07/23 03:52 79-34-5 0.29 1 04/07/23 03:52 127-18-4 0.24 1 04/07/23 03:52 108-88-3 0.33 1 04/07/23 03:52 71-55-6 0.32 1 04/07/23 03:52 79-00-5 0.38 1 04/07/23 03:52 79-01-6 0.30 1 04/07/23 03:52 75-69-4 0.26 1 04/07/23 03:52 96-18-4 1.3 1 04/07/23 03:52 108-05-4 0.39 1 04/07/23 03:52 75-01-4 v2 0.34 1 04/07/23 03:52 1330-20-7 1 04/07/23 03:52 460-00-4 1 04/07/23 03:52 17060-07-0 1 04/07/23 03:52 2037-26-5 0.86 1 8 04/07/23 01:05 123-91-1 H 1, H5 04/07/23 01:05 17060-07-0 04/07/23 01:05 2037-26-5 Analytical Method: SM2340-97 Preparation Method: SM2340B Pace National - Mt. Juliet 35300 ug/L 2500 198 1 04/05/23 11:58 04/05/23 11:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Sample: SW-2 Lab ID: 92659941002 Collected: 03/30/23 13:55 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/05/23 07:27 04/05/23 12:01 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/05/23 07:27 04/05/23 12:01 7440-38-2 Barium 15.5 ug/L 5.00 0.736 1 04/05/23 07:27 04/05/23 12:01 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/05/23 07:27 04/05/23 12:01 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/05/23 07:27 04/05/23 12:01 7440-43-9 Chromium 1.75J ug/L 10.0 1.40 1 04/05/23 07:27 04/05/23 12:01 7440-47-3 J Cobalt ND ug/L 10.0 0.840 1 04/05/23 07:27 04/05/23 12:01 7440-48-4 Copper ND ug/L 10.0 3.68 1 04/05/23 07:27 04/05/23 12:01 7440-50-8 Lead ND ug/L 6.00 2.99 1 04/05/23 07:27 04/05/23 12:01 7439-92-1 Nickel 3.29J ug/L 10.0 1.61 1 04/05/23 07:27 04/05/23 12:01 7440-02-0 B,J Selenium ND ug/L 10.0 7.35 1 04/05/23 07:27 04/05/23 12:01 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/05/23 07:27 04/05/23 12:01 7440-22-4 Vanadium 5.23J ug/L 20.0 4.99 1 04/05/23 07:27 04/05/23 12:01 7440-62-2 J Zinc 13.OJ ug/L 50.0 6.52 1 04/05/23 07:27 04/05/23 12:01 7440-66-6 J Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 08:22 04/05/23 15:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/07/23 04:11 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 04/07/23 04:11 107-13-1 Benzene ND ug/L 1.0 0.34 1 04/07/23 04:11 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/07/23 04:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/07/23 04:11 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/07/23 04:11 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/07/23 04:11 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/07/23 04:11 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/07/23 04:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/07/23 04:11 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/07/23 04:11 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/07/23 04:11 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/07/23 04:11 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/07/23 04:11 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/07/23 04:11 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/07/23 04:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/07/23 04:11 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/07/23 04:11 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/07/23 04:11 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/07/23 04:11 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/07/23 04:11 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/07/23 04:11 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/07/23 04:11 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/07/23 04:11 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 Sample: SW-2 Lab ID: 92659941002 Collected: 03/30/23 13:55 Received: 03/31/23 10:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Calculated Results Hardness, Total(SM 234013) Date: 04/12/2023 07:35 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 04/07/23 04:11 156-59-2 ND ug/L 1.0 0.40 1 04/07/23 04:11 156-60-5 ND ug/L 1.0 0.36 1 04/07/23 04:11 78-87-5 ND ug/L 1.0 0.36 1 04/07/23 04:11 10061-01-5 ND ug/L 1.0 0.36 1 04/07/23 04:11 10061-02-6 ND ug/L 1.0 0.30 1 04/07/23 04:11 100-41-4 ND ug/L 5.0 0.48 1 04/07/23 04:11 591-78-6 ND ug/L 20.0 9.7 1 04/07/23 04:11 74-88-4 ND ug/L 5.0 2.0 1 04/07/23 04:11 75-09-2 L1,v1 ND ug/L 5.0 2.7 1 04/07/23 04:11 108-10-1 ND ug/L 1.0 0.29 1 04/07/23 04:11 100-42-5 ND ug/L 1.0 0.31 1 04/07/23 04:11 630-20-6 ND ug/L 1.0 0.22 1 04/07/23 04:11 79-34-5 ND ug/L 1.0 0.29 1 04/07/23 04:11 127-18-4 ND ug/L 1.0 0.24 1 04/07/23 04:11 108-88-3 ND ug/L 1.0 0.33 1 04/07/23 04:11 71-55-6 ND ug/L 1.0 0.32 1 04/07/23 04:11 79-00-5 ND ug/L 1.0 0.38 1 04/07/23 04:11 79-01-6 ND ug/L 1.0 0.30 1 04/07/23 04:11 75-69-4 ND ug/L 1.0 0.26 1 04/07/23 04:11 96-18-4 ND ug/L 2.0 1.3 1 04/07/23 04:11 108-05-4 ND ug/L 1.0 0.39 1 04/07/23 04:11 75-01-4 v2 ND ug/L 1.0 0.34 1 04/07/23 04:11 1330-20-7 96 % 70-130 1 04/07/23 04:11 460-00-4 109 % 70-130 1 04/07/23 04:11 17060-07-0 103 % 70-130 1 04/07/23 04:11 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 0.89J ug/L 2.0 0.86 1 04/05/23 23:50 123-91-1 94 % 67-130 1 04/05/23 23:50 17060-07-0 98 % 70-130 1 04/05/23 23:50 2037-26-5 Analytical Method: SM2340-97 Preparation Method: SM2340B Pace National - Mt. Juliet 36500 ug/L 2500 198 1 04/05/2312:01 04/05/2312:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 QC Batch: 2035939 Analysis Method: EPA 6010D QC Batch Method: 3015 Analysis Description: Metals (ICP) 6010D Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659941001, 92659941002 METHOD BLANK: R3909657-1 Associated Lab Samples: 92659941001, 92659941002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 10.0 4.30 04/05/2311:37 Arsenic ug/L ND 10.0 4.40 04/05/2311:37 Barium ug/L ND 5.00 0.736 04/05/2311:37 Beryllium ug/L ND 2.00 0.330 04/05/2311:37 Cadmium ug/L ND 2.00 0.479 04/05/2311:37 Chromium ug/L ND 10.0 1.40 04/05/2311:37 Cobalt ug/L ND 10.0 0.840 04/05/2311:37 Copper ug/L ND 10.0 3.68 04/05/2311:37 Lead ug/L ND 6.00 2.99 04/05/2311:37 Nickel ug/L 2.32J 10.0 1.61 04/05/2311:37 J Selenium ug/L ND 10.0 7.35 04/05/2311:37 Silver ug/L ND 5.00 1.54 04/05/2311:37 Vanadium ug/L ND 20.0 4.99 04/05/2311:37 Zinc ug/L ND 50.0 6.52 04/05/2311:37 LABORATORY CONTROL SAMPLE: Parameter R3909657-2 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 1000 966 96.6 80.0-120 Arsenic ug/L 1000 905 90.5 80.0-120 Barium ug/L 1000 978 97.8 80.0-120 Beryllium ug/L 1000 950 95.0 80.0-120 Cadmium ug/L 1000 949 94.9 80.0-120 Chromium ug/L 1000 947 94.7 80.0-120 Cobalt ug/L 1000 949 94.9 80.0-120 Copper ug/L 1000 957 95.7 80.0-120 Lead ug/L 1000 944 94.4 80.0-120 Nickel ug/L 1000 943 94.3 80.0-120 Selenium ug/L 1000 929 92.9 80.0-120 Silver ug/L 200 175 87.7 80.0-120 Vanadium ug/L 1000 971 97.1 80.0-120 Zinc ug/L 1000 933 93.3 80.0-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: GM1.004-OXFORD LANDFILL UNIT 1 92659941 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909657-4 R3909657-5 MS MSD L1601527-01 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 1000 1000 967 982 96.7 98.2 75.0-125 1.62 20 Arsenic ug/L ND 1000 1000 940 925 94.0 92.5 75.0-125 1.68 20 Barium ug/L 43.7 1000 1000 1040 1030 99.7 99.0 75.0-125 0.718 20 Beryllium ug/L ND 1000 1000 965 957 96.5 95.7 75.0-125 0.867 20 Cadmium ug/L ND 1000 1000 975 965 97.5 96.5 75.0-125 1.04 20 Chromium ug/L ND 1000 1000 959 958 95.9 95.8 75.0-125 0.147 20 Cobalt ug/L ND 1000 1000 966 957 96.6 95.7 75.0-125 0.933 20 Copper ug/L 22.3 1000 1000 999 986 97.7 96.4 75.0-125 1.26 20 Lead ug/L ND 1000 1000 960 953 96.0 95.3 75.0-125 0.733 20 Nickel ug/L 3.28 1000 1000 957 950 95.4 94.7 75.0-125 0.753 20 Selenium ug/L ND 1000 1000 956 951 95.6 95.1 75.0-125 0.509 20 Silver ug/L ND 200 200 179 179 89.6 89.5 75.0-125 0.089 20 Vanadium ug/L ND 1000 1000 977 968 97.7 96.8 75.0-125 0.914 20 Zinc ug/L ND 1000 1000 948 938 94.8 93.8 75.0-125 1.04 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 QC Batch: 2035938 Analysis Method: EPA 6020B QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659941001, 92659941002 METHOD BLANK: R3909560-1 Matrix: Water Associated Lab Samples: 92659941001, 92659941002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L 0.172J 2.00 0.121 04/05/2312:01 J LABORATORY CONTROL SAMPLE: R3909560-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 50.0 48.4 96.7 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909560-4 R3909560-5 MS MSD L1601349-02 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 50.0 50.0 48.2 50.0 96.5 100 75.0-125 3.58 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 QC Batch: 766317 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659941001, 92659941002 METHOD BLANK: 3978969 Associated Lab Samples: 92659941001, 92659941002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/07/23 02:20 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/07/23 02:20 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/07/23 02:20 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/07/23 02:20 1,1-Dichloroethane ug/L ND 1.0 0.37 04/07/23 02:20 1,1-Dichloroethene ug/L ND 1.0 0.35 04/07/23 02:20 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/07/23 02:20 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/07/23 02:20 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/07/23 02:20 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/07/23 02:20 1,2-Dichloroethane ug/L ND 1.0 0.32 04/07/23 02:20 1,2-Dichloropropane ug/L ND 1.0 0.36 04/07/23 02:20 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/07/23 02:20 2-Butanone (MEK) ug/L ND 5.0 4.0 04/07/23 02:20 2-Hexanone ug/L ND 5.0 0.48 04/07/23 02:20 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/07/23 02:20 Acetone ug/L ND 25.0 5.1 04/07/23 02:20 Acrylonitrile ug/L ND 10.0 1.8 04/07/23 02:20 Benzene ug/L ND 1.0 0.34 04/07/23 02:20 Bromochloromethane ug/L ND 1.0 0.47 04/07/23 02:20 Bromodichloromethane ug/L ND 1.0 0.31 04/07/23 02:20 Bromoform ug/L ND 1.0 0.34 04/07/23 02:20 Bromomethane ug/L ND 2.0 1.7 04/07/23 02:20 Carbon disulfide ug/L ND 2.0 0.36 04/07/23 02:20 Carbon tetrachloride ug/L ND 1.0 0.33 04/07/23 02:20 Chlorobenzene ug/L ND 1.0 0.28 04/07/23 02:20 Chloroethane ug/L ND 1.0 0.65 04/07/23 02:20 Chloroform ug/L ND 1.0 0.43 04/07/23 02:20 Chloromethane ug/L ND 1.0 0.54 04/07/23 02:20 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/07/23 02:20 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 02:20 Dibromochloromethane ug/L ND 1.0 0.36 04/07/23 02:20 Dibromomethane ug/L ND 1.0 0.39 04/07/23 02:20 Ethylbenzene ug/L ND 1.0 0.30 04/07/23 02:20 lodomethane ug/L ND 20.0 9.7 04/07/23 02:20 Methylene Chloride ug/L ND 5.0 2.0 04/07/23 02:20 v1 Styrene ug/L ND 1.0 0.29 04/07/23 02:20 Tetrachloroethene ug/L ND 1.0 0.29 04/07/23 02:20 Toluene ug/L ND 1.0 0.24 04/07/23 02:20 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/07/23 02:20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 METHOD BLANK: 3978969 Associated Lab Samples: 92659941001, 92659941002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8(S) % 102 70-130 Analyzed 0.36 04/07/23 02:20 0.56 04/07/23 02:20 0.38 04/07/23 02:20 0.30 04/07/23 02:20 1.3 04/07/23 02:20 0.39 04/07/23 02:20 0.34 04/07/23 02:20 04/07/23 02:20 04/07/23 02:20 04/07/23 02:20 LABORATORY CONTROL SAMPLE: Parameter 3978970 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 20 19.8 99 70-130 1,1,1-Trichloroethane ug/L 20 20.2 101 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.8 109 70-130 1,1,2-Trichloroethane ug/L 20 21.2 106 70-130 1,1-Dichloroethane ug/L 20 19.5 98 70-130 1,1-Dichloroethene ug/L 20 19.5 97 70-130 1,2,3-Trichloropropane ug/L 20 20.6 103 70-130 1,2-Dibromo-3-chloropropane ug/L 20 20.0 100 70-131 1,2-Dibromoethane (EDB) ug/L 20 20.1 100 70-130 1,2-Dichlorobenzene ug/L 20 20.9 105 70-130 1,2-Dichloroethane ug/L 20 21.4 107 70-130 1,2-Dichloropropane ug/L 20 20.5 103 70-130 1,4-Dichlorobenzene ug/L 20 19.6 98 70-130 2-Butanone (MEK) ug/L 40 43.2 108 70-134 2-Hexanone ug/L 40 42.6 107 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 43.1 108 70-130 Acetone ug/L 40 42.2 106 70-133 Acrylonitrile ug/L 100 106 106 70-130 Benzene ug/L 20 19.6 98 70-130 Bromochloromethane ug/L 20 19.9 99 70-130 Bromodichloromethane ug/L 20 19.9 100 70-130 Bromoform ug/L 20 18.7 94 70-130 Bromomethane ug/L 20 16.0 80 45-151 Carbon disulfide ug/L 20 16.4 82 70-130 Carbon tetrachloride ug/L 20 18.1 90 70-130 Chlorobenzene ug/L 20 19.7 99 70-130 Chloroethane ug/L 20 20.4 102 39-152 Chloroform ug/L 20 20.9 104 70-130 Chloromethane ug/L 20 20.1 100 58-130 cis-1,2-Dichloroethene ug/L 20 20.1 100 70-130 Qualifiers v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 LABORATORY CONTROL SAMPLE: 3978970 Parameter QUALITY CONTROL DATA Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 20 18.9 95 70-130 Dibromochloromethane ug/L 20 19.4 97 70-130 Dibromomethane ug/L 20 19.0 95 70-130 Ethylbenzene ug/L 20 19.7 98 70-130 lodomethane ug/L 40 33.6 84 53-141 Methylene Chloride ug/L 20 30.2 151 66-130 L1,v1 Styrene ug/L 20 19.3 96 70-130 Tetrachloroethene ug/L 20 18.4 92 70-130 Toluene ug/L 20 19.9 100 70-130 trans-1,2-Dichloroethene ug/L 20 19.1 95 70-130 trans- 1,3-Dichloropropene ug/L 20 19.7 99 70-130 trans-1,4-Dichloro-2-butene ug/L 20 22.9 114 57-185 Trichloroethene ug/L 20 18.5 93 70-130 Trichlorofluoromethane ug/L 20 18.5 92 62-130 Vinyl acetate ug/L 40 41.6 104 70-144 Vinyl chloride ug/L 20 15.8 79 62-130 v3 Xylene (Total) ug/L 60 57.9 97 70-130 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: Parameter 3978972 Units 92659774022 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 22.0 110 70-141 1,1,1-Trichloroethane ug/L ND 20 21.5 108 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 23.2 116 69-142 1,1,2-Trichloroethane ug/L ND 20 22.0 110 70-138 1,1-Dichloroethane ug/L ND 20 21.7 109 70-150 1,1-Dichloroethene ug/L ND 20 22.2 111 70-156 1,2,3-Trichloropropane ug/L ND 20 22.4 112 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 23.2 116 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 22.6 113 70-138 1,2-Dichlorobenzene ug/L ND 20 23.0 115 70-141 1,2-Dichloroethane ug/L ND 20 21.8 109 69-143 1,2-Dichloropropene ug/L ND 20 22.4 112 68-156 1,4-Dichlorobenzene ug/L ND 20 22.8 114 70-142 2-Butanone (MEK) ug/L ND 40 44.8 112 60-157 2-Hexanone ug/L ND 40 49.4 123 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 46.3 116 70-141 Acetone ug/L ND 40 42.6 106 58-157 Acrylonitrile ug/L ND 100 107 107 69-147 Benzene ug/L ND 20 21.2 106 70-142 Bromochloromethane ug/L ND 20 21.9 110 70-146 Bromodichloromethane ug/L ND 20 21.1 105 70-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 MATRIX SPIKE SAMPLE: 3978972 92659774022 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L ND 20 21.2 106 64-140 Bromomethane ug/L ND 20 14.7 73 28-192 v3 Carbon disulfide ug/L ND 20 20.2 101 70-151 Carbon tetrachloride ug/L ND 20 21.3 106 70-148 Chlorobenzene ug/L ND 20 22.3 111 70-141 Chloroethane ug/L ND 20 22.0 110 58-191 Chloroform ug/L ND 20 21.2 106 70-148 Chloromethane ug/L ND 20 16.2 81 43-162 cis-1,2-Dichloroethene ug/L ND 20 21.7 108 68-151 cis-1,3-Dichloropropene ug/L ND 20 21.3 106 70-139 Dibromochloromethane ug/L ND 20 21.7 109 70-144 Dibromomethane ug/L ND 20 20.6 103 70-139 Ethylbenzene ug/L ND 20 22.0 110 70-143 lodomethane ug/L ND 40 28.8 72 35-171 IL,v3 Methylene Chloride ug/L ND 20 27.2 136 62-149 v1 Styrene ug/L ND 20 22.9 115 70-143 Tetrachloroethene ug/L ND 20 21.5 107 70-145 Toluene ug/L ND 20 21.6 108 70-142 trans-1,2-Dichloroethene ug/L ND 20 22.0 110 70-151 trans- 1,3-Dichloropropene ug/L ND 20 21.6 108 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 21.2 106 51-159 Trichloroethene ug/L ND 20 21.3 106 62-146 Trichlorofluoromethane ug/L ND 20 19.5 98 63-153 Vinyl acetate ug/L ND 40 44.9 112 61-162 Vinyl chloride ug/L ND 20 15.2 76 61-163 Xylene (Total) ug/L ND 60 67.1 112 70-143 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 3978971 92659945004 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 SAMPLE DUPLICATE: 3978971 Parameter Units 92659945004 Result 1,4-Dichlorobenzene ug/L ND 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 104 4-Bromofluorobenzene (S) % 97 Toluene-d8 (S) % 103 Dup Result RPD Max RPD Qualifiers ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 v2 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 I L, v2 ND 30 v1 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 107 98 101 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 QC Batch: 766180 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659941002 METHOD BLANK: 3978090 Matrix: Water Associated Lab Samples: 92659941002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/05/23 17:11 1,2-Dichloroethane-d4 (S) % 83 67-130 04/05/23 17:11 Toluene-d8 (S) % 87 70-130 04/05/23 17:11 LABORATORY CONTROL SAMPLE: 3978091 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 17.8 89 70-130 1,2-Dichloroethane-d4 (S) % 78 67-130 Toluene-d8 (S) % 86 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978092 3978093 MS MSD 92659941002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 0.89J 20 20 18.7 19.9 89 95 55-137 6 30 1,2-Dichloroethane-d4 (S) % 86 80 67-130 30 Toluene-d8 (S) % 108 106 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 QC Batch: 766432 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659941001 METHOD BLANK: 3979517 Matrix: Water Associated Lab Samples: 92659941001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/06/23 18:46 1,2-Dichloroethane-d4 (S) % 103 67-130 04/06/23 18:46 Toluene-d8 (S) % 101 70-130 04/06/23 18:46 LABORATORY CONTROL SAMPLE: 3979518 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 103 67-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979519 3979520 MS MSD 92659681001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 4.6 20 20 21.1 20.8 82 81 55-137 2 30 H1 1,2-Dichloroethane-d4 (S) % 103 103 67-130 30 Toluene-d8(S) % 121 120 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004-OXFORD LANDFILL UNIT 1 Pace Project No.: 92659941 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. WORKORDER QUALIFIERS WO: 92659941 [1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank. H1 Analysis conducted outside the EPA method holding time. H5 Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2023 07:35 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GM1.004-OXFORD LANDFILL UNIT 1 92659941 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92659941001 SW-1 3015 2035939 EPA 6010D 2035939 92659941002 SW-2 3015 2035939 EPA 6010D 2035939 92659941001 SW-1 3015 2035938 EPA 6020B 2035938 92659941002 SW-2 3015 2035938 EPA 6020B 2035938 92659941001 SW-1 EPA 8260D 766317 92659941002 SW-2 EPA 8260D 766317 92659941001 SW-1 EPA 8260D Mod. 766432 92659941002 SW-2 EPA 8260D Mod. 766180 92659941001 SW-1 SM2340B 2035939 SM2340-97 2035939 92659941002 SW-2 SM2340B 2035939 SM2340-97 2035939 Date: 04/12/2023 07:35 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 23 DC# Tide: ENWFRM-HUN-14083 402Lsample Condifibn Upon Rezelot Effftfte DAW. IAO$030'M A. tiboraWry taE] X6m6mvilhmM Ashey�flg it nE1 Gi"nWoodEl Huntemylil E] haW Vj ROWOEY Moe ioiileD Attan Client Name: Prpiect M Wp#:92659941 WTIL: LJ -.0 I idN upi� [-K Cu nt. �� �Il �� 1��� �1 y� l I�� Commeraai 0 Pace e Clothem: L 92559941 CusiodysatOressp;? O.v6s feats, fact?' irlyes L:" N;kirt,z 0 Ku6bitWev OSI Bub o . a,& - 0A-4 10 '!Y00 of Jee: WVIei Cooler Temp: h4l"at AddtSdbfr Iry Cwi& u mn*ttow, (OC-1. -5t4tes: Cx my, or st 'Ord's-M Ph ' !'S�.CAWI)afe quarant rf.q Jtbin ft.;United VrA ;Ll amplesve&ikw � om a for0p),.i.9arce. cb6m of CustodyTrItsent? ..... .. .. ....... YES 'dw SamplesArrived vvithim Hold Time? Shmt:Haft[Tima AnalWs-(Oi*!1 .0 Yes M ?D OW: Rush TurnAround-nine Requested? 'O'jes' No EJ W'A. 0 YM 12rra- A3WA 5. r th&O bftea comwftri: -face Chot6ftm used? Mlles *-r" 0 N6. QWO. GWA CIWA. ConWirkersiptact? Diso,Wd lhihjsis. -Sirhplet: Field Filtered? El yu. Sampie Lab&fs Notch. COP .YQ 70 spa 13-ym. 0 IVA. I Trip: Wank Present? L' 760-81aylk.4WOodV Se* Plre-te07 0 YeS ]p No Wb O:W. Ar QN/A 0. COMMSWIV-SAMPLE DISCREPANCY - Field Data Requltedi'ayei ON& Lot ID of split containers: Person contacted: mrpl:. Project ManagerSCORF Rev Sew Prqed MardfterSRIF Reviews Pate: Page 21 of 23 pQ^'M J of DC#—Tltle: tNV-FkWiu_W- afnOli CdMIC66 Ufim Rfteipt *Omsk mark wpr.halfof box If pli and/bftle�chjO.lna timv "is:vaelfied and. Onge preser"Uo"M 00001S (water) Dq Q, Lft h' A rat;hfaxis- t"c' b'sit, rfLttnbp-r of :blittj 2 6315. L Ch. Nitrates -for or no .140#: 92659941 PM: TMC Due Date: 04/07/23 CLIENT: 92-Hart-Ral V .2 -R Z ca EL z 00 Rl m en Z' to 0 Z m t4i m A% foll- .6, Aa W A S A 44 t E E. E E E wl In -N H �0 'n .9 K — 0_ E. 6 E_ LE E Z.4 > LQ 21 CL CL CL qF co 0 LO 5 Ie . M QM AD de 4c cl Of I' pH Adipstmentioglipr Preserved -Samples fWjpOf.pfeWrptAjePH'upoxtvecei p Pra0PrAft.rVadon l* 4 AmOnt of OM Jw. addeO Lot #SaM?(gjCL 4iwpyvT.rnis rarmwi n ne sent 0 Olft-Of ttmoincorred dicpq 'rS.L Page 22 of 23 nt-pamrsiv in AckgtA J3.=i64-9 M '7': �_ PIN .. saldumS ) 0 ' n U ' r `(r,Jg � �alocy� 8 z f3pi m (NW auuollk? lummsam + pe uea ay 3 � CL S! CP Q2 9 a Huel9 41. OVexulp V` E s Cm 9. MUMdy1 e E v I ddy m m INISfl9ZedVauelQrAb'I yc s Q9iSA9OpAIddb 7 F IWO y 4 0 G lsl�p :. V m Q � a � Mue41eVlI @ 2 _ COMM Q -0 „ ;� NOON D m c F 0 m IOH '^ f # OJgi]t EONH pm� F w c • • 7 vmzii a m ��. DOM S2rdup �..- � `a a+ 4 ¢ ✓� � a� a � S7i3NIalNO:J d0 @ � '� LL {J 037i0 1IV dCf3L 31dMS QZ A 4 a LIU to ° 13 z _ m = w `o F E m a w k 2 Z � r u a lu � w1 `a { wma) 3dAL3'Uvivs g i y� ei ("%semPilmeas) 2000XIaLVW p E mfn Q o m mH � mZia o C3�x'RoLi�a a L ma3 q m k � m Q a E 8 uj m C m A Ix i=E - +n m {� W m Q) U) O E I 43 o _ @ F7 E� a d u g . n ,. # W31� Page 23 of 23 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 24, 2023 Jeffrey 011ison Hart & Hickman 3921 Sunset Ridge Rd. Ste. 301 Raleigh, NC 27607 RE: Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Dear Jeffrey 011ison: Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Gulf Coast • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte A revised report is being issued on 5/24/23 to update qualifier assigned to the vinyl chloride result for sample 92659639- 001. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 76 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Pace Analytical Services National 12065 Lebanon Road, Mt. 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Page 2 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Lab ID Sample ID Matrix Date Collected Date Received 92659639001 MW-5R Water 03/29/2314:05 03/30/23 10:00 92659639002 MW-7 Water 03/29/2315:09 03/30/23 10:00 92659639003 FIELD BLANK UNIT 1 Water 03/29/23 16:45 03/30/23 10:00 92659639004 MW-3RR Water 03/29/2316:30 03/30/23 10:00 92659639005 TRIP BLANK Water 03/29/23 00:00 03/30/23 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: GM1.004 OXFORD LANDFILL UNIT 1 92659639 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92659639001 MW-5R EPA8151A NWH 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C RSK-175 LMB 1 GCLA EPA 601 OD SPL 17 PAN EPA 6020E JPD 1 PAN EPA 7470A SRT 1 PAN EPA 8270E PKS 111 PASI-C EPA 8260D Mod. TEG 3 PASI-C EPA 8260D CL 68 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 4500-CN-E-2016 ANM 1 PASI-A 92659639002 MW-7 EPA8151A NWH 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C RSK-175 LMB 1 GCLA EPA 601 OD SPL 17 PAN EPA 6020E JPD 1 PAN EPA 7470A SRT 1 PAN EPA 8270E PKS 111 PASI-C EPA 8260D Mod. TEG 3 PASI-C EPA 8260D CL 68 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 4500-CN-E-2016 ANM 1 PASI-A 92659639003 FIELD BLANK UNIT 1 EPA8151A NWH 5 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Lab ID Sample ID Method Analysts Analytes Reported Laboratory RSK-175 LMB 1 GCLA EPA 601 OD SPL 17 PAN EPA 6020E JPD 1 PAN EPA 7470A SRT 1 PAN EPA 8270E PKS 111 PASI-C EPA 8260D Mod. TEG 3 PASI-C EPA 8260D CL 68 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 4500-CN-E-2016 ANM 1 PASI-A 92659639004 MW-3RR EPA 601 OD SPL 16 PAN EPA 6020E JPD 1 PAN EPA 7470A AKB 1 PAN EPA 8260D CL 51 PASI-C EPA 8260D Mod. TEG 3 PASI-C SM 2320B-2011 SMS 1 PASI-A SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A 92659639005 TRIP BLANK EPA 8260D Mod. TEG 3 PASI-C EPA 8260D CL 67 PASI-C GCLA = Pace Analytical Gulf Coast PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151A Analytical Method: EPA 8151A Preparation Method: 8151A Pace National - Mt. Juliet 2,4-D ND ug/L 2.00 0.547 1 04/04/23 14:45 04/06/23 12:00 94-75-7 R1 Dinoseb ND ug/L 2.00 0.250 1 04/04/23 14:45 04/06/23 12:00 88-85-7 2,4,5-T ND ug/L 2.00 0.258 1 04/04/23 14:45 04/06/23 12:00 93-76-5 R1 2,4,5-TP (Silvex) ND ug/L 2.00 0.335 1 04/04/23 14:45 04/06/23 12:00 93-72-1 R1 Surrogates 2,4-DCAA (S) 80.2 % 14.0-158 1 04/04/23 14:45 04/06/23 12:00 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Aldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:05 309-00-2 alpha-BHC ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:05 319-84-6 beta-BHC ND ug/L 0.042 0.041 1 04/05/23 11:13 04/06/23 15:05 319-85-7 delta-BHC ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:05 319-86-8 gamma-BHC (Lindane) ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:05 58-89-9 Chlordane (Technical) ND ug/L 0.42 0.13 1 04/05/23 11:13 04/06/23 15:05 57-74-9 4,4'-DDD ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:05 72-54-8 4,4'-DDE ND ug/L 0.042 0.020 1 04/05/23 11:13 04/06/23 15:05 72-55-9 4,4'-DDT ND ug/L 0.042 0.022 1 04/05/23 11:13 04/06/23 15:05 50-29-3 Dieldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:05 60-57-1 Endosulfan I ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:05 959-98-8 Endosulfan II ND ug/L 0.042 0.013 1 04/05/23 11:13 04/06/23 15:05 33213-65-9 Endosulfan sulfate ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:05 1031-07-8 Endrin ND ug/L 0.042 0.015 1 04/05/23 11:13 04/06/23 15:05 72-20-8 Endrin aldehyde ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:05 7421-93-4 Heptachlor ND ug/L 0.042 0.016 1 04/05/23 11:13 04/06/23 15:05 76-44-8 Heptachlor epoxide ND ug/L 0.042 0.024 1 04/05/23 11:13 04/06/23 15:05 1024-57-3 Methoxychlor ND ug/L 0.12 0.035 1 04/05/23 11:13 04/06/23 15:05 72-43-5 Toxaphene ND ug/L 0.42 0.18 1 04/05/23 11:13 04/06/23 15:05 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 116 % 10-182 1 04/05/23 11:13 04/06/23 15:05 877-09-8 Decachlorobiphenyl (S) 131 % 10-200 1 04/05/23 11:13 04/06/23 15:05 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 0.42 0.18 1 04/14/23 11:02 04/17/23 14:45 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.42 0.19 1 04/14/23 11:02 04/17/23 14:45 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.42 0.19 1 04/14/23 11:02 04/17/23 14:45 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.42 0.21 1 04/14/23 11:02 04/17/23 14:45 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.42 0.24 1 04/14/23 11:02 04/17/23 14:45 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.42 0.18 1 04/14/23 11:02 04/17/23 14:45 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.42 0.13 1 04/14/23 11:02 04/17/23 14:45 11096-82-5 Surrogates Decachlorobiphenyl (S) 115 % 10-193 1 04/14/23 11:02 04/17/23 14:45 2051-24-3 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane 31 ug/L 5.0 2.0 1 04/10/23 09:29 74-82-8 Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/03/23 09:02 04/03/23 19:40 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/03/23 09:02 04/03/23 19:40 7440-38-2 Barium 44.6 ug/L 5.00 0.736 1 04/03/23 09:02 04/03/23 19:40 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/03/23 09:02 04/03/23 19:40 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/03/23 09:02 04/03/23 19:40 7440-43-9 Chromium ND ug/L 10.0 1.40 1 04/03/23 09:02 04/03/23 19:40 7440-47-3 Cobalt ND ug/L 10.0 0.840 1 04/03/23 09:02 04/03/23 19:40 7440-48-4 Copper ND ug/L 10.0 3.68 1 04/03/23 09:02 04/03/23 19:40 7440-50-8 Iron 292 ug/L 100 18.0 1 04/03/23 09:02 04/03/23 19:40 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/03/23 09:02 04/03/23 19:40 7439-92-1 Manganese 102 ug/L 10.0 0.934 1 04/03/23 09:02 04/03/23 19:40 7439-96-5 Nickel 2.16J ug/L 10.0 1.61 1 04/03/23 09:02 04/03/23 19:40 7440-02-0 Selenium ND ug/L 10.0 7.35 1 04/03/23 09:02 04/03/23 19:40 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/03/23 09:02 04/03/23 19:40 7440-22-4 Tin ND ug/L 50.0 4.87 1 04/03/23 09:02 04/03/23 19:40 7440-31-5 Vanadium ND ug/L 20.0 4.99 1 04/03/23 09:02 04/03/23 19:40 7440-62-2 Zinc ND ug/L 50.0 6.52 1 04/03/23 09:02 04/03/23 19:40 7440-66-6 Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 01:56 04/05/23 10:45 7440-28-0 Mercury 7470A Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet Mercury ND ug/L 0.200 0.100 1 04/04/23 08:56 04/04/23 19:30 7439-97-6 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Acenaphthene ND ug/L 8.3 1.7 1 04/04/2318:28 04/06/2319:44 83-32-9 Acenaphthylene ND ug/L 8.3 1.6 1 04/04/2318:28 04/06/2319:44 208-96-8 Acetophenone ND ug/L 8.3 1.2 1 04/04/2318:28 04/06/2319:44 98-86-2 2-Acetylaminofluorene ND ug/L 8.3 3.4 1 04/04/2318:28 04/06/2319:44 53-96-3 4-Aminobiphenyl ND ug/L 8.3 4.0 1 04/04/2318:28 04/06/2319:44 92-67-1 Anthracene ND ug/L 8.3 1.9 1 04/04/2318:28 04/06/2319:44 120-12-7 Benzo(a)anthracene ND ug/L 8.3 2.2 1 04/04/2318:28 04/06/2319:44 56-55-3 Benzo(a)pyrene ND ug/L 8.3 2.3 1 04/04/2318:28 04/06/2319:44 50-32-8 Benzo(b)fluoranthene ND ug/L 8.3 2.2 1 04/04/2318:28 04/06/2319:44 205-99-2 Benzo(g,h,i)perylene ND ug/L 8.3 2.4 1 04/04/2318:28 04/06/2319:44 191-24-2 Benzo(k)fluoranthene ND ug/L 8.3 2.3 1 04/04/2318:28 04/06/2319:44 207-08-9 Benzyl alcohol ND ug/L 16.7 2.4 1 04/04/23 18:28 04/06/23 19:44 100-51-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. J Page 8 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 4-Bromophenylphenyl ether ND ug/L 8.3 1.5 1 04/04/23 18:28 04/06/23 19:44 101-55-3 Butylbenzylphthalate ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 19:44 85-68-7 4-ChIoro-3-methyl phenol ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 19:44 59-50-7 4-Chloroaniline ND ug/L 16.7 3.0 1 04/04/23 18:28 04/06/23 19:44 106-47-8 Chlorobenzilate ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 19:44 510-15-6 bis(2-Chloroethoxy)methane ND ug/L 8.3 1.5 1 04/04/23 18:28 04/06/23 19:44 111-91-1 bis(2-Chloroethyl) ether ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 111-44-4 2-Chloronaphthalene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 19:44 91-58-7 2-Chlorophenol ND ug/L 8.3 1.0 1 04/04/23 18:28 04/06/23 19:44 95-57-8 4-Chlorophenylphenyl ether ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 19:44 7005-72-3 Chrysene ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 19:44 218-01-9 Diallate ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 19:44 2303-16-4 Dibenz(a,h)anthracene ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 19:44 53-70-3 Dibenzofuran ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 132-64-9 3,3'-Dichlorobenzidine ND ug/L 16.7 6.8 1 04/04/23 18:28 04/06/23 19:44 91-94-1 2,4-Dichlorophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 19:44 120-83-2 2,6-Dichlorophenol ND ug/L 8.3 3.5 1 04/04/23 18:28 04/06/23 19:44 87-65-0 Diethylphthalate ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 19:44 84-66-2 Dimethoate ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 19:44 60-51-5 P-Dimethylaminoazobenzene ND ug/L 4.2 2.0 1 04/04/23 18:28 04/06/23 19:44 60-11-7 IL 7,12-Dimethylbenz(a)anthracene ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 19:44 57-97-6 3,3'-Dimethylbenzidine ND ug/L 41.7 25.9 1 04/04/23 18:28 04/06/23 19:44 119-93-7 IH 2,4-Dimethylphenol ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 19:44 105-67-9 L1 Dimethylphthalate ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 131-11-3 Di-n-butylphthalate ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 16.7 6.5 1 04/04/23 18:28 04/06/23 19:44 534-52-1 v1 1,3-Dinitrobenzene ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 19:44 99-65-0 2,4-Dinitrophenol ND ug/L 41.7 21.7 1 04/04/23 18:28 04/06/23 19:44 51-28-5 2,4-Dinitrotoluene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 19:44 121-14-2 2,6-Dinitrotoluene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 19:44 606-20-2 Di-n-octylphthalate ND ug/L 8.3 3.3 1 04/04/23 18:28 04/06/23 19:44 117-84-0 Diphenylamine ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 19:44 122-39-4 Disulfoton ND ug/L 8.3 3.9 1 04/04/23 18:28 04/06/23 19:44 298-04-4 bis(2- Ethyl hexyl)phthalate ND ug/L 5.0 3.1 1 04/04/23 18:28 04/06/23 19:44 117-81-7 Ethyl methanesulfonate ND ug/L 16.7 2.5 1 04/04/23 18:28 04/06/23 19:44 62-50-0 Famphur ND ug/L 8.3 5.1 1 04/04/23 18:28 04/06/23 19:44 52-85-7 Fluoranthene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 206-44-0 Fluorene ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 19:44 86-73-7 Hexachlorobenzene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 118-74-1 Hexachlorocyclopentadiene ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 19:44 77-47-4 Hexachloroethane ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 19:44 67-72-1 Hexachloropropene ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 19:44 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 8.3 2.4 1 04/04/23 18:28 04/06/23 19:44 193-39-5 Isodrin ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 19:44 465-73-6 Isophorone ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 19:44 78-59-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Isosafrole ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 19:44 120-58-1 Kepone ND ug/L 16.7 11.8 1 04/04/23 18:28 04/06/23 19:44 143-50-0 Methapyrilene ND ug/L 41.7 14.2 1 04/04/23 18:28 04/06/23 19:44 91-80-5 IH,v1 3-Methylcholanthrene ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 19:44 56-49-5 Methyl methanesulfonate ND ug/L 4.2 2.6 1 04/04/23 18:28 04/06/23 19:44 66-27-3 2-Methylnaphthalene ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 91-57-6 Methyl parathion ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 19:44 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 8.3 1.0 1 04/04/23 18:28 04/06/23 19:44 15831-10-4 1-Naphthalenamine ND ug/L 8.3 5.0 1 04/04/23 18:28 04/06/23 19:44 134-32-7 2-Naphthalenamine ND ug/L 8.3 4.5 1 04/04/23 18:28 04/06/23 19:44 91-59-8 1,4-Naphthoquinone ND ug/L 4.2 3.7 1 04/04/23 18:28 04/06/23 19:44 130-15-4 2-Nitroaniline ND ug/L 16.7 2.5 1 04/04/23 18:28 04/06/23 19:44 88-74-4 3-Nitroaniline ND ug/L 16.7 3.1 1 04/04/23 18:28 04/06/23 19:44 99-09-2 4-Nitroaniline ND ug/L 16.7 4.2 1 04/04/23 18:28 04/06/23 19:44 100-01-6 Nitrobenzene ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 98-95-3 2-Nitrophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 19:44 88-75-5 4-Nitrophenol ND ug/L 41.7 5.5 1 04/04/23 18:28 04/06/23 19:44 100-02-7 5-Nitro-o-toluidine ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 19:44 99-55-8 N-Nitrosodiethylamine ND ug/L 8.3 1.9 1 04/04/23 18:28 04/06/23 19:44 55-18-5 N-Nitrosodimethylamine ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 19:44 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 8.3 1.1 1 04/04/23 18:28 04/06/23 19:44 621-64-7 N-Nitrosodiphenylamine ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 19:44 86-30-6 N-Nitrosomethylethylamine ND ug/L 8.3 6.2 1 04/04/23 18:28 04/06/23 19:44 10595-95-6 N-Nitrosopiperidine ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 19:44 100-75-4 N-Nitrosopyrrolidine ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 19:44 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 19:44 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 8.3 0.96 1 04/04/23 18:28 04/06/23 19:44 108-60-1 Parathion (Ethyl parathion) ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 19:44 56-38-2 Pentachlorobenzene ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 19:44 608-93-5 Pentachloronitrobenzene ND ug/L 8.3 2.7 1 04/04/23 18:28 04/06/23 19:44 82-68-8 Pentachlorophenol ND ug/L 16.7 3.1 1 04/04/23 18:28 04/06/23 19:44 87-86-5 Phenacetin ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 19:44 62-44-2 Phenanthrene ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 19:44 85-01-8 Phenol ND ug/L 8.3 1.1 1 04/04/23 18:28 04/06/23 19:44 108-95-2 p-Phenylenediamine ND ug/L 8.3 8.3 1 04/04/23 18:28 04/06/23 19:44 106-50-3 Phorate ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 19:44 298-02-2 Pronamide ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 19:44 23950-58-5 Pyrene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 19:44 129-00-0 Safrole ND ug/L 8.3 1.9 1 04/04/23 18:28 04/06/23 19:44 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 8.3 3.7 1 04/04/23 18:28 04/06/23 19:44 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 19:44 58-90-2 Thionazin ND ug/L 8.3 2.4 1 04/04/23 18:28 04/06/23 19:44 297-97-2 O-Toluidine ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 19:44 95-53-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 2,4,5-Trichlorophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 19:44 95-95-4 2,4,6-Trichlorophenol ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 19:44 88-06-2 1,3,5-Trinitrobenzene ND ug/L 8.3 4.6 1 04/04/23 18:28 04/06/23 19:44 99-35-4 v1 Surrogates Nitrobenzene-d5 (S) 69 % 10-138 1 04/04/23 18:28 04/06/23 19:44 4165-60-0 2-Fluorobiphenyl (S) 59 % 10-130 1 04/04/23 18:28 04/06/23 19:44 321-60-8 Terphenyl-d14 (S) 104 % 19-191 1 04/04/23 18:28 04/06/23 19:44 1718-51-0 Phenol-d6 (S) 39 % 10-130 1 04/04/23 18:28 04/06/23 19:44 13127-88-3 2-Fluorophenol (S) 49 % 10-130 1 04/04/23 18:28 04/06/23 19:44 367-12-4 2,4,6-Tribromophenol (S) 103 % 10-164 1 04/04/23 18:28 04/06/23 19:44 118-79-6 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 58.6 ug/L 2.0 0.86 1 04/05/23 01:42 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 80 % 67-130 1 04/05/23 01:42 17060-07-0 Toluene-d8 (S) 88 % 70-130 1 04/05/23 01:42 2037-26-5 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/01/23 07:04 67-64-1 Acetonitrile ND ug/L 50.0 24.8 1 04/01/23 07:04 75-05-8 Acrolein ND ug/L 10.0 8.5 1 04/01/23 07:04 107-02-8 Acrylonitrile ND ug/L 10.0 1.8 1 04/01/23 07:04 107-13-1 Allyl chloride ND ug/L 2.0 0.50 1 04/01/23 07:04 107-05-1 Benzene ND ug/L 1.0 0.34 1 04/01/23 07:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/01/23 07:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/01/23 07:04 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/01/23 07:04 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/01/23 07:04 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/01/23 07:04 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/01/23 07:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/01/23 07:04 56-23-5 Chlorobenzene 1.4 ug/L 1.0 0.28 1 04/01/23 07:04 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/01/23 07:04 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/01/23 07:04 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/01/23 07:04 74-87-3 Chloroprene ND ug/L 5.0 1.6 1 04/01/23 07:04 126-99-8 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/01/23 07:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/01/23 07:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/01/23 07:04 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/01/23 07:04 74-95-3 1,2-Dichlorobenzene 1.3 ug/L 1.0 0.34 1 04/01/23 07:04 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 04/01/23 07:04 541-73-1 1,4-Dichlorobenzene 0.94J ug/L 1.0 0.33 1 04/01/23 07:04 106-46-7 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/01/23 07:04 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 04/01/23 07:04 75-71-8 1,1-Dichloroethane 1.4 ug/L 1.0 0.37 1 04/01/23 07:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/01/23 07:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/01/23 07:04 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/01/23 07:04 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 04/01/23 07:04 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 04/01/23 07:04 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 04/01/23 07:04 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 04/01/23 07:04 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 04/01/23 07:04 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 07:04 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 07:04 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 04/01/23 07:04 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.28 1 04/01/23 07:04 97-63-2 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 04/01/23 07:04 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 04/01/23 07:04 591-78-6 lodomethane ND ug/L 20.0 9.7 1 04/01/23 07:04 74-88-4 Isobutanol ND ug/L 100 52.3 1 04/01/23 07:04 78-83-1 Methacrylonitrile ND ug/L 10.0 4.2 1 04/01/23 07:04 126-98-7 Methylene Chloride ND ug/L 5.0 2.0 1 04/01/23 07:04 75-09-2 Methyl methacrylate ND ug/L 2.0 0.32 1 04/01/23 07:04 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 04/01/23 07:04 108-10-1 Naphthalene ND ug/L 1.0 0.64 1 04/01/23 07:04 91-20-3 Propionitrile ND ug/L 20.0 3.6 1 04/01/23 07:04 107-12-0 Styrene ND ug/L 1.0 0.29 1 04/01/23 07:04 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 04/01/23 07:04 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 04/01/23 07:04 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 04/01/23 07:04 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.5 1 04/01/23 07:04 109-99-9 Toluene ND ug/L 1.0 0.24 1 04/01/23 07:04 108-88-3 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 04/01/23 07:04 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 04/01/23 07:04 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 04/01/23 07:04 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 04/01/23 07:04 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 04/01/23 07:04 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 04/01/23 07:04 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 04/01/23 07:04 108-05-4 Vinyl chloride 0.81J ug/L 1.0 0.39 1 04/01/23 07:04 75-01-4 v3 Xylene (Total) ND ug/L 1.0 0.34 1 04/01/23 07:04 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 04/01/23 07:04 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 04/01/23 07:04 17060-07-0 Toluene-d8 (S) 94 % 70-130 1 04/01/23 07:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-5R Lab ID: 92659639001 Collected: 03/29/23 14:05 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 186000 ug/L 5000 5000 1 04/06/23 19:17 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 307 mg/L 25.0 25.0 1 03/31/23 19:58 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 22.0 1 04/04/23 02:45 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 8200 ug/L 1000 500 1 04/01/23 01:19 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 17.6J ug/L 40.0 10.0 1 03/31/23 03:25 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 50000 ug/L 2000 1000 2 04/05/23 20:40 16887-00-6 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016 Pace Analytical Services -Asheville Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:04 57-12-5 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151A Analytical Method: EPA 8151A Preparation Method: 8151A Pace National - Mt. Juliet 2,4-D ND ug/L 2.00 0.547 1 04/04/23 14:45 04/06/23 12:11 94-75-7 R1 Dinoseb ND ug/L 2.00 0.250 1 04/04/23 14:45 04/06/23 12:11 88-85-7 2,4,5-T ND ug/L 2.00 0.258 1 04/04/23 14:45 04/06/23 12:11 93-76-5 R1 2,4,5-TP (Silvex) ND ug/L 2.00 0.335 1 04/04/23 14:45 04/06/23 12:11 93-72-1 R1 Surrogates 2,4-DCAA (S) 71.8 % 14.0-158 1 04/04/23 14:45 04/06/23 12:11 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Aldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:17 309-00-2 alpha-BHC ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:17 319-84-6 beta-BHC ND ug/L 0.042 0.041 1 04/05/23 11:13 04/06/23 15:17 319-85-7 delta-BHC ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:17 319-86-8 gamma-BHC (Lindane) ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:17 58-89-9 Chlordane (Technical) ND ug/L 0.42 0.13 1 04/05/23 11:13 04/06/23 15:17 57-74-9 4,4'-DDD ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:17 72-54-8 4,4'-DDE ND ug/L 0.042 0.020 1 04/05/23 11:13 04/06/23 15:17 72-55-9 4,4'-DDT ND ug/L 0.042 0.022 1 04/05/23 11:13 04/06/23 15:17 50-29-3 Dieldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:17 60-57-1 Endosulfan I ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:17 959-98-8 Endosulfan II ND ug/L 0.042 0.013 1 04/05/23 11:13 04/06/23 15:17 33213-65-9 Endosulfan sulfate ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:17 1031-07-8 Endrin ND ug/L 0.042 0.015 1 04/05/23 11:13 04/06/23 15:17 72-20-8 Endrin aldehyde ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:17 7421-93-4 Heptachlor ND ug/L 0.042 0.016 1 04/05/23 11:13 04/06/23 15:17 76-44-8 Heptachlor epoxide ND ug/L 0.042 0.024 1 04/05/23 11:13 04/06/23 15:17 1024-57-3 Methoxychlor ND ug/L 0.12 0.035 1 04/05/23 11:13 04/06/23 15:17 72-43-5 Toxaphene ND ug/L 0.42 0.18 1 04/05/23 11:13 04/06/23 15:17 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 96 % 10-182 1 04/05/23 11:13 04/06/23 15:17 877-09-8 Decachlorobiphenyl (S) 116 % 10-200 1 04/05/23 11:13 04/06/23 15:17 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 0.42 0.18 1 04/14/23 11:02 04/17/23 14:58 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.42 0.19 1 04/14/23 11:02 04/17/23 14:58 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.42 0.19 1 04/14/23 11:02 04/17/23 14:58 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.42 0.21 1 04/14/23 11:02 04/17/23 14:58 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.42 0.24 1 04/14/23 11:02 04/17/23 14:58 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.42 0.18 1 04/14/23 11:02 04/17/23 14:58 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.42 0.13 1 04/14/23 11:02 04/17/23 14:58 11096-82-5 Surrogates Decachlorobiphenyl (S) 149 % 10-193 1 04/14/23 11:02 04/17/23 14:58 2051-24-3 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane ND ug/L 5.0 2.0 1 04/10/23 09:45 74-82-8 Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/03/23 09:02 04/03/23 19:43 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/03/23 09:02 04/03/23 19:43 7440-38-2 Barium 3.74J ug/L 5.00 0.736 1 04/03/23 09:02 04/03/23 19:43 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/03/23 09:02 04/03/23 19:43 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/03/23 09:02 04/03/23 19:43 7440-43-9 Chromium ND ug/L 10.0 1.40 1 04/03/23 09:02 04/03/23 19:43 7440-47-3 Cobalt ND ug/L 10.0 0.840 1 04/03/23 09:02 04/03/23 19:43 7440-48-4 Copper ND ug/L 10.0 3.68 1 04/03/23 09:02 04/03/23 19:43 7440-50-8 Iron ND ug/L 100 18.0 1 04/03/23 09:02 04/03/23 19:43 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/03/23 09:02 04/03/23 19:43 7439-92-1 Manganese ND ug/L 10.0 0.934 1 04/03/23 09:02 04/03/23 19:43 7439-96-5 Nickel 1.92J ug/L 10.0 1.61 1 04/03/23 09:02 04/03/23 19:43 7440-02-0 Selenium ND ug/L 10.0 7.35 1 04/03/23 09:02 04/03/23 19:43 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/03/23 09:02 04/03/23 19:43 7440-22-4 Tin ND ug/L 50.0 4.87 1 04/03/23 09:02 04/03/23 19:43 7440-31-5 Vanadium ND ug/L 20.0 4.99 1 04/03/23 09:02 04/03/23 19:43 7440-62-2 Zinc ND ug/L 50.0 6.52 1 04/03/23 09:02 04/03/23 19:43 7440-66-6 Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 01:56 04/05/23 10:49 7440-28-0 Mercury 7470A Mercury 8270E APP9 RV Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzyl alcohol Date: 05/24/2023 01:13 PM Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet ND ug/L 0.200 0.100 1 04/04/23 08:56 04/04/23 19:32 7439-97-6 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 20:09 83-32-9 ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 208-96-8 ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 20:09 98-86-2 ND ug/L 8.3 3.4 1 04/04/23 18:28 04/06/23 20:09 53-96-3 ND ug/L 8.3 4.0 1 04/04/23 18:28 04/06/23 20:09 92-67-1 ND ug/L 8.3 1.9 1 04/04/23 18:28 04/06/23 20:09 120-12-7 ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 20:09 56-55-3 ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 20:09 50-32-8 ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 20:09 205-99-2 ND ug/L 8.3 2.4 1 04/04/23 18:28 04/06/23 20:09 191-24-2 ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 20:09 207-08-9 ND ug/L 16.7 2.4 1 04/04/23 18:28 04/06/23 20:09 100-51-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. J J Page 15 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 4-Bromophenylphenyl ether ND ug/L 8.3 1.5 1 04/04/23 18:28 04/06/23 20:09 101-55-3 Butylbenzylphthalate ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 20:09 85-68-7 4-ChIoro-3-methyl phenol ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 20:09 59-50-7 4-Chloroaniline ND ug/L 16.7 3.0 1 04/04/23 18:28 04/06/23 20:09 106-47-8 Chlorobenzilate ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 20:09 510-15-6 bis(2-Chloroethoxy)methane ND ug/L 8.3 1.5 1 04/04/23 18:28 04/06/23 20:09 111-91-1 bis(2-Chloroethyl) ether ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 111-44-4 2-Chloronaphthalene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 20:09 91-58-7 2-Chlorophenol ND ug/L 8.3 1.0 1 04/04/23 18:28 04/06/23 20:09 95-57-8 4-Chlorophenylphenyl ether ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 20:09 7005-72-3 Chrysene ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 20:09 218-01-9 Diallate ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 20:09 2303-16-4 Dibenz(a,h)anthracene ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 20:09 53-70-3 Dibenzofuran ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 132-64-9 3,3'-Dichlorobenzidine ND ug/L 16.7 6.8 1 04/04/23 18:28 04/06/23 20:09 91-94-1 2,4-Dichlorophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 20:09 120-83-2 2,6-Dichlorophenol ND ug/L 8.3 3.5 1 04/04/23 18:28 04/06/23 20:09 87-65-0 Diethylphthalate ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 20:09 84-66-2 Dimethoate ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 20:09 60-51-5 P-Dimethylaminoazobenzene ND ug/L 4.2 2.0 1 04/04/23 18:28 04/06/23 20:09 60-11-7 7,12-Dimethylbenz(a)anthracene ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 20:09 57-97-6 3,3'-Dimethylbenzidine ND ug/L 41.7 25.9 1 04/04/23 18:28 04/06/23 20:09 119-93-7 2,4-Dimethylphenol ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 20:09 105-67-9 Dimethylphthalate ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 131-11-3 Di-n-butylphthalate ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 16.7 6.5 1 04/04/23 18:28 04/06/23 20:09 534-52-1 1,3-Dinitrobenzene ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 20:09 99-65-0 2,4-Dinitrophenol ND ug/L 41.7 21.7 1 04/04/23 18:28 04/06/23 20:09 51-28-5 2,4-Dinitrotoluene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 20:09 121-14-2 2,6-Dinitrotoluene ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 20:09 606-20-2 Di-n-octylphthalate ND ug/L 8.3 3.3 1 04/04/23 18:28 04/06/23 20:09 117-84-0 Diphenylamine ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 20:09 122-39-4 Disulfoton ND ug/L 8.3 3.9 1 04/04/23 18:28 04/06/23 20:09 298-04-4 bis(2- Ethyl hexyl)phthalate ND ug/L 5.0 3.1 1 04/04/23 18:28 04/06/23 20:09 117-81-7 Ethyl methanesulfonate ND ug/L 16.7 2.5 1 04/04/23 18:28 04/06/23 20:09 62-50-0 Famphur ND ug/L 8.3 5.1 1 04/04/23 18:28 04/06/23 20:09 52-85-7 Fluoranthene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 206-44-0 Fluorene ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 20:09 86-73-7 Hexachlorobenzene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 118-74-1 Hexachlorocyclopentadiene ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 20:09 77-47-4 Hexachloroethane ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 20:09 67-72-1 Hexachloropropene ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 20:09 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 8.3 2.4 1 04/04/23 18:28 04/06/23 20:09 193-39-5 Isodrin ND ug/L 8.3 2.3 1 04/04/23 18:28 04/06/23 20:09 465-73-6 Isophorone ND ug/L 8.3 1.4 1 04/04/23 18:28 04/06/23 20:09 78-59-1 REPORT OF LABORATORY ANALYSIS IL IH L1 v1 This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Isosafrole ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 20:09 120-58-1 Kepone ND ug/L 16.7 11.8 1 04/04/23 18:28 04/06/23 20:09 143-50-0 Methapyrilene ND ug/L 41.7 14.2 1 04/04/23 18:28 04/06/23 20:09 91-80-5 IH,v1 3-Methylcholanthrene ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 20:09 56-49-5 Methyl methanesulfonate ND ug/L 4.2 2.6 1 04/04/23 18:28 04/06/23 20:09 66-27-3 2-Methylnaphthalene ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 91-57-6 Methyl parathion ND ug/L 8.3 3.1 1 04/04/23 18:28 04/06/23 20:09 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 8.3 1.0 1 04/04/23 18:28 04/06/23 20:09 15831-10-4 1-Naphthalenamine ND ug/L 8.3 5.0 1 04/04/23 18:28 04/06/23 20:09 134-32-7 2-Naphthalenamine ND ug/L 8.3 4.5 1 04/04/23 18:28 04/06/23 20:09 91-59-8 1,4-Naphthoquinone ND ug/L 4.2 3.7 1 04/04/23 18:28 04/06/23 20:09 130-15-4 2-Nitroaniline ND ug/L 16.7 2.5 1 04/04/23 18:28 04/06/23 20:09 88-74-4 3-Nitroaniline ND ug/L 16.7 3.1 1 04/04/23 18:28 04/06/23 20:09 99-09-2 4-Nitroaniline ND ug/L 16.7 4.2 1 04/04/23 18:28 04/06/23 20:09 100-01-6 Nitrobenzene ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 98-95-3 2-Nitrophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 20:09 88-75-5 4-Nitrophenol ND ug/L 41.7 5.5 1 04/04/23 18:28 04/06/23 20:09 100-02-7 5-Nitro-o-toluidine ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 20:09 99-55-8 N-Nitrosodiethylamine ND ug/L 8.3 1.9 1 04/04/23 18:28 04/06/23 20:09 55-18-5 N-Nitrosodimethylamine ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 8.3 1.6 1 04/04/23 18:28 04/06/23 20:09 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 8.3 1.1 1 04/04/23 18:28 04/06/23 20:09 621-64-7 N-Nitrosodiphenylamine ND ug/L 8.3 2.5 1 04/04/23 18:28 04/06/23 20:09 86-30-6 N-Nitrosomethylethylamine ND ug/L 8.3 6.2 1 04/04/23 18:28 04/06/23 20:09 10595-95-6 N-Nitrosopiperidine ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 20:09 100-75-4 N-Nitrosopyrrolidine ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 20:09 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 8.3 2.1 1 04/04/23 18:28 04/06/23 20:09 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 8.3 0.96 1 04/04/23 18:28 04/06/23 20:09 108-60-1 Parathion (Ethyl parathion) ND ug/L 8.3 3.2 1 04/04/23 18:28 04/06/23 20:09 56-38-2 Pentachlorobenzene ND ug/L 8.3 2.8 1 04/04/23 18:28 04/06/23 20:09 608-93-5 Pentachloronitrobenzene ND ug/L 8.3 2.7 1 04/04/23 18:28 04/06/23 20:09 82-68-8 Pentachlorophenol ND ug/L 16.7 3.1 1 04/04/23 18:28 04/06/23 20:09 87-86-5 Phenacetin ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 20:09 62-44-2 Phenanthrene ND ug/L 8.3 1.7 1 04/04/23 18:28 04/06/23 20:09 85-01-8 Phenol ND ug/L 8.3 1.1 1 04/04/23 18:28 04/06/23 20:09 108-95-2 p-Phenylenediamine ND ug/L 8.3 8.3 1 04/04/23 18:28 04/06/23 20:09 106-50-3 Phorate ND ug/L 8.3 3.0 1 04/04/23 18:28 04/06/23 20:09 298-02-2 Pronamide ND ug/L 8.3 2.6 1 04/04/23 18:28 04/06/23 20:09 23950-58-5 Pyrene ND ug/L 8.3 1.8 1 04/04/23 18:28 04/06/23 20:09 129-00-0 Safrole ND ug/L 8.3 1.9 1 04/04/23 18:28 04/06/23 20:09 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 8.3 3.7 1 04/04/23 18:28 04/06/23 20:09 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 20:09 58-90-2 Thionazin ND ug/L 8.3 2.4 1 04/04/23 18:28 04/06/23 20:09 297-97-2 O-Toluidine ND ug/L 8.3 2.2 1 04/04/23 18:28 04/06/23 20:09 95-53-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 2,4,5-Trichlorophenol ND ug/L 8.3 1.2 1 04/04/23 18:28 04/06/23 20:09 95-95-4 2,4,6-Trichlorophenol ND ug/L 8.3 1.3 1 04/04/23 18:28 04/06/23 20:09 88-06-2 1,3,5-Trinitrobenzene ND ug/L 8.3 4.6 1 04/04/23 18:28 04/06/23 20:09 99-35-4 v1 Surrogates Nitrobenzene-d5 (S) 52 % 10-138 1 04/04/23 18:28 04/06/23 20:09 4165-60-0 2-Fluorobiphenyl (S) 46 % 10-130 1 04/04/23 18:28 04/06/23 20:09 321-60-8 Terphenyl-d14 (S) 68 % 19-191 1 04/04/23 18:28 04/06/23 20:09 1718-51-0 Phenol-d6 (S) 32 % 10-130 1 04/04/23 18:28 04/06/23 20:09 13127-88-3 2-Fluorophenol (S) 40 % 10-130 1 04/04/23 18:28 04/06/23 20:09 367-12-4 2,4,6-Tribromophenol (S) 58 % 10-164 1 04/04/23 18:28 04/06/23 20:09 118-79-6 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 04/05/23 01:04 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 80 % 67-130 1 04/05/23 01:04 17060-07-0 Toluene-d8 (S) 89 % 70-130 1 04/05/23 01:04 2037-26-5 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/01/23 07:22 67-64-1 Acetonitrile ND ug/L 50.0 24.8 1 04/01/23 07:22 75-05-8 Acrolein ND ug/L 10.0 8.5 1 04/01/23 07:22 107-02-8 Acrylonitrile ND ug/L 10.0 1.8 1 04/01/23 07:22 107-13-1 Allyl chloride ND ug/L 2.0 0.50 1 04/01/23 07:22 107-05-1 Benzene ND ug/L 1.0 0.34 1 04/01/23 07:22 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/01/23 07:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/01/23 07:22 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/01/23 07:22 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/01/23 07:22 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/01/23 07:22 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/01/23 07:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/01/23 07:22 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/01/23 07:22 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/01/23 07:22 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/01/23 07:22 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/01/23 07:22 74-87-3 Chloroprene ND ug/L 5.0 1.6 1 04/01/23 07:22 126-99-8 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/01/23 07:22 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/01/23 07:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/01/23 07:22 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/01/23 07:22 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/01/23 07:22 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 04/01/23 07:22 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/01/23 07:22 106-46-7 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Lab ID: 92659639002 Collected: 03/29/23 15:09 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/01/23 07:22 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 04/01/23 07:22 75-71-8 M1 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/01/23 07:22 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/01/23 07:22 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/01/23 07:22 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/01/23 07:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 04/01/23 07:22 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 04/01/23 07:22 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 04/01/23 07:22 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 04/01/23 07:22 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 04/01/23 07:22 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 07:22 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 07:22 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 04/01/23 07:22 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.28 1 04/01/23 07:22 97-63-2 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 04/01/23 07:22 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 04/01/23 07:22 591-78-6 lodomethane ND ug/L 20.0 9.7 1 04/01/23 07:22 74-88-4 Isobutanol ND ug/L 100 52.3 1 04/01/23 07:22 78-83-1 Methacrylonitrile ND ug/L 10.0 4.2 1 04/01/23 07:22 126-98-7 Methylene Chloride ND ug/L 5.0 2.0 1 04/01/23 07:22 75-09-2 Methyl methacrylate ND ug/L 2.0 0.32 1 04/01/23 07:22 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 04/01/23 07:22 108-10-1 Naphthalene ND ug/L 1.0 0.64 1 04/01/23 07:22 91-20-3 Propionitrile ND ug/L 20.0 3.6 1 04/01/23 07:22 107-12-0 Styrene ND ug/L 1.0 0.29 1 04/01/23 07:22 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 04/01/23 07:22 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 04/01/23 07:22 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 04/01/23 07:22 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.5 1 04/01/23 07:22 109-99-9 Toluene ND ug/L 1.0 0.24 1 04/01/23 07:22 108-88-3 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 04/01/23 07:22 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 04/01/23 07:22 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 04/01/23 07:22 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 04/01/23 07:22 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 04/01/23 07:22 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 04/01/23 07:22 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 04/01/23 07:22 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 04/01/23 07:22 75-01-4 M1,v2 Xylene (Total) ND ug/L 1.0 0.34 1 04/01/23 07:22 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 04/01/23 07:22 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 04/01/23 07:22 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 04/01/23 07:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-7 Parameters Lab ID: 92659639002 Collected: Report Results Units Limit 03/29/23 15:09 MDL DF Received: 03/30/23 10:00 Matrix: Water Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 151000 ug/L 5000 5000 1 04/06/23 19:30 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 252 mg/L 25.0 25.0 1 03/31/23 19:58 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 22.0 1 04/04/23 02:46 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 47700 ug/L 1000 500 1 04/01/23 02:10 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 305 ug/L 40.0 10.0 1 03/31/23 03:33 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 9360 ug/L 1000 500 1 04/05/2319:15 16887-00-6 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016 Pace Analytical Services -Asheville Cyanide ND ug/L 40.0 30.0 5 04/03/23 18:41 04/03/23 22:16 57-12-5 D3 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151A Analytical Method: EPA 8151A Preparation Method: 8151A Pace National - Mt. Juliet 2,4-D ND ug/L 2.00 0.547 1 04/04/23 14:45 04/06/23 12:55 94-75-7 R1 Dinoseb ND ug/L 2.00 0.250 1 04/04/23 14:45 04/06/23 12:55 88-85-7 2,4,5-T ND ug/L 2.00 0.258 1 04/04/23 14:45 04/06/23 12:55 93-76-5 R1 2,4,5-TP (Silvex) ND ug/L 2.00 0.335 1 04/04/23 14:45 04/06/23 12:55 93-72-1 R1 Surrogates 2,4-DCAA (S) 66.2 % 14.0-158 1 04/04/23 14:45 04/06/23 12:55 19719-28-9 8081 OC Pesticides RVE Analytical Method: EPA 8081 B Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Aldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:30 309-00-2 alpha-BHC ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:30 319-84-6 beta-BHC ND ug/L 0.042 0.041 1 04/05/23 11:13 04/06/23 15:30 319-85-7 delta-BHC ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:30 319-86-8 gamma-BHC (Lindane) ND ug/L 0.042 0.010 1 04/05/23 11:13 04/06/23 15:30 58-89-9 Chlordane (Technical) ND ug/L 0.42 0.13 1 04/05/23 11:13 04/06/23 15:30 57-74-9 4,4'-DDD ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:30 72-54-8 4,4'-DDE ND ug/L 0.042 0.020 1 04/05/23 11:13 04/06/23 15:30 72-55-9 4,4'-DDT ND ug/L 0.042 0.022 1 04/05/23 11:13 04/06/23 15:30 50-29-3 Dieldrin ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:30 60-57-1 Endosulfan I ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:30 959-98-8 Endosulfan II ND ug/L 0.042 0.013 1 04/05/23 11:13 04/06/23 15:30 33213-65-9 Endosulfan sulfate ND ug/L 0.042 0.012 1 04/05/23 11:13 04/06/23 15:30 1031-07-8 Endrin ND ug/L 0.042 0.015 1 04/05/23 11:13 04/06/23 15:30 72-20-8 Endrin aldehyde ND ug/L 0.042 0.014 1 04/05/23 11:13 04/06/23 15:30 7421-93-4 Heptachlor ND ug/L 0.042 0.016 1 04/05/23 11:13 04/06/23 15:30 76-44-8 Heptachlor epoxide ND ug/L 0.042 0.024 1 04/05/23 11:13 04/06/23 15:30 1024-57-3 Methoxychlor ND ug/L 0.12 0.035 1 04/05/23 11:13 04/06/23 15:30 72-43-5 Toxaphene ND ug/L 0.42 0.18 1 04/05/23 11:13 04/06/23 15:30 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 70 % 10-182 1 04/05/23 11:13 04/06/23 15:30 877-09-8 Decachlorobiphenyl (S) 93 % 10-200 1 04/05/23 11:13 04/06/23 15:30 2051-24-3 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 0.45 0.19 1 04/11/23 14:07 04/12/23 19:27 12674-11-2 R1 PCB-1221 (Aroclor 1221) ND ug/L 0.45 0.21 1 04/11/23 14:07 04/12/23 19:27 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.45 0.21 1 04/11/23 14:07 04/12/23 19:27 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.45 0.23 1 04/11/23 14:07 04/12/23 19:27 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.45 0.26 1 04/11/23 14:07 04/12/23 19:27 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.45 0.19 1 04/11/23 14:07 04/12/23 19:27 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.45 0.14 1 04/11/23 14:07 04/12/23 19:27 11096-82-5 M1,R1 Surrogates Decachlorobiphenyl (S) 120 % 10-193 1 04/11/23 14:07 04/12/23 19:27 2051-24-3 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Biodegradation Indicator Gases Analytical Method: RSK-175 Pace Analytical Gulf Coast Methane ND ug/L 5.0 2.0 1 04/10/2310:01 74-82-8 Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/03/23 09:02 04/03/23 19:46 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/03/23 09:02 04/03/23 19:46 7440-38-2 Barium ND ug/L 5.00 0.736 1 04/03/23 09:02 04/03/23 19:46 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/03/23 09:02 04/03/23 19:46 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/03/23 09:02 04/03/23 19:46 7440-43-9 Chromium ND ug/L 10.0 1.40 1 04/03/23 09:02 04/03/23 19:46 7440-47-3 Cobalt ND ug/L 10.0 0.840 1 04/03/23 09:02 04/03/23 19:46 7440-48-4 Copper ND ug/L 10.0 3.68 1 04/03/23 09:02 04/03/23 19:46 7440-50-8 Iron ND ug/L 100 18.0 1 04/03/23 09:02 04/03/23 19:46 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/03/23 09:02 04/03/23 19:46 7439-92-1 Manganese ND ug/L 10.0 0.934 1 04/03/23 09:02 04/03/23 19:46 7439-96-5 Nickel ND ug/L 10.0 1.61 1 04/03/23 09:02 04/03/23 19:46 7440-02-0 Selenium ND ug/L 10.0 7.35 1 04/03/23 09:02 04/03/23 19:46 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/03/23 09:02 04/03/23 19:46 7440-22-4 Tin ND ug/L 50.0 4.87 1 04/03/23 09:02 04/03/23 19:46 7440-31-5 Vanadium ND ug/L 20.0 4.99 1 04/03/23 09:02 04/03/23 19:46 7440-62-2 Zinc ND ug/L 50.0 6.52 1 04/03/23 09:02 04/03/23 19:46 7440-66-6 Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 01:56 04/05/23 10:52 7440-28-0 Mercury 7470A Mercury 8270E APP9 RV Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzyl alcohol Date: 05/24/2023 01:13 PM Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet ND ug/L 0.200 0.100 1 04/04/23 08:56 04/04/23 19:34 7439-97-6 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 83-32-9 ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 208-96-8 ND ug/L 8.7 1.3 1 04/04/23 18:28 04/06/23 20:35 98-86-2 ND ug/L 8.7 3.5 1 04/04/23 18:28 04/06/23 20:35 53-96-3 ND ug/L 8.7 4.1 1 04/04/23 18:28 04/06/23 20:35 92-67-1 ND ug/L 8.7 2.0 1 04/04/23 18:28 04/06/23 20:35 120-12-7 ND ug/L 8.7 2.3 1 04/04/23 18:28 04/06/23 20:35 56-55-3 ND ug/L 8.7 2.4 1 04/04/23 18:28 04/06/23 20:35 50-32-8 ND ug/L 8.7 2.3 1 04/04/23 18:28 04/06/23 20:35 205-99-2 ND ug/L 8.7 2.5 1 04/04/23 18:28 04/06/23 20:35 191-24-2 ND ug/L 8.7 2.4 1 04/04/23 18:28 04/06/23 20:35 207-08-9 ND ug/L 17.4 2.5 1 04/04/23 18:28 04/06/23 20:35 100-51-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 4-Bromophenylphenyl ether ND ug/L 8.7 1.5 1 04/04/23 18:28 04/06/23 20:35 101-55-3 Butylbenzylphthalate ND ug/L 8.7 2.7 1 04/04/23 18:28 04/06/23 20:35 85-68-7 4-ChIoro-3-methyl phenol ND ug/L 8.7 2.9 1 04/04/23 18:28 04/06/23 20:35 59-50-7 4-Chloroaniline ND ug/L 17.4 3.2 1 04/04/23 18:28 04/06/23 20:35 106-47-8 Chlorobenzilate ND ug/L 8.7 3.3 1 04/04/23 18:28 04/06/23 20:35 510-15-6 bis(2-Chloroethoxy)methane ND ug/L 8.7 1.6 1 04/04/23 18:28 04/06/23 20:35 111-91-1 bis(2-Chloroethyl) ether ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 111-44-4 2-Chloronaphthalene ND ug/L 8.7 1.5 1 04/04/23 18:28 04/06/23 20:35 91-58-7 2-Chlorophenol ND ug/L 8.7 1.0 1 04/04/23 18:28 04/06/23 20:35 95-57-8 4-Chlorophenylphenyl ether ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 7005-72-3 Chrysene ND ug/L 8.7 2.4 1 04/04/23 18:28 04/06/23 20:35 218-01-9 Diallate ND ug/L 8.7 3.0 1 04/04/23 18:28 04/06/23 20:35 2303-16-4 Dibenz(a,h)anthracene ND ug/L 8.7 2.6 1 04/04/23 18:28 04/06/23 20:35 53-70-3 Dibenzofuran ND ug/L 8.7 1.8 1 04/04/23 18:28 04/06/23 20:35 132-64-9 3,3'-Dichlorobenzidine ND ug/L 17.4 7.1 1 04/04/23 18:28 04/06/23 20:35 91-94-1 2,4-Dichlorophenol ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 120-83-2 2,6-Dichlorophenol ND ug/L 8.7 3.7 1 04/04/23 18:28 04/06/23 20:35 87-65-0 Diethylphthalate ND ug/L 8.7 1.8 1 04/04/23 18:28 04/06/23 20:35 84-66-2 Dimethoate ND ug/L 8.7 3.2 1 04/04/23 18:28 04/06/23 20:35 60-51-5 P-Dimethylaminoazobenzene ND ug/L 4.3 2.1 1 04/04/23 18:28 04/06/23 20:35 60-11-7 7,12-Dimethylbenz(a)anthracene ND ug/L 8.7 2.6 1 04/04/23 18:28 04/06/23 20:35 57-97-6 3,3'-Dimethylbenzidine ND ug/L 43.5 27.0 1 04/04/23 18:28 04/06/23 20:35 119-93-7 2,4-Dimethylphenol ND ug/L 8.7 1.5 1 04/04/23 18:28 04/06/23 20:35 105-67-9 Dimethylphthalate ND ug/L 8.7 1.9 1 04/04/23 18:28 04/06/23 20:35 131-11-3 Di-n-butylphthalate ND ug/L 8.7 1.9 1 04/04/23 18:28 04/06/23 20:35 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 17.4 6.8 1 04/04/23 18:28 04/06/23 20:35 534-52-1 1,3-Dinitrobenzene ND ug/L 8.7 3.3 1 04/04/23 18:28 04/06/23 20:35 99-65-0 2,4-Dinitrophenol ND ug/L 43.5 22.6 1 04/04/23 18:28 04/06/23 20:35 51-28-5 2,4-Dinitrotoluene ND ug/L 8.7 1.4 1 04/04/23 18:28 04/06/23 20:35 121-14-2 2,6-Dinitrotoluene ND ug/L 8.7 1.5 1 04/04/23 18:28 04/06/23 20:35 606-20-2 Di-n-octylphthalate ND ug/L 8.7 3.4 1 04/04/23 18:28 04/06/23 20:35 117-84-0 Diphenylamine ND ug/L 8.7 2.6 1 04/04/23 18:28 04/06/23 20:35 122-39-4 Disulfoton ND ug/L 8.7 4.0 1 04/04/23 18:28 04/06/23 20:35 298-04-4 bis(2- Ethyl hexyl)phthalate ND ug/L 5.2 3.2 1 04/04/23 18:28 04/06/23 20:35 117-81-7 Ethyl methanesulfonate ND ug/L 17.4 2.6 1 04/04/23 18:28 04/06/23 20:35 62-50-0 Famphur ND ug/L 8.7 5.3 1 04/04/23 18:28 04/06/23 20:35 52-85-7 Fluoranthene ND ug/L 8.7 1.9 1 04/04/23 18:28 04/06/23 20:35 206-44-0 Fluorene ND ug/L 8.7 1.8 1 04/04/23 18:28 04/06/23 20:35 86-73-7 Hexachlorobenzene ND ug/L 8.7 1.9 1 04/04/23 18:28 04/06/23 20:35 118-74-1 Hexachlorocyclopentadiene ND ug/L 8.7 1.4 1 04/04/23 18:28 04/06/23 20:35 77-47-4 Hexachloroethane ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 67-72-1 Hexachloropropene ND ug/L 8.7 2.3 1 04/04/23 18:28 04/06/23 20:35 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 8.7 2.5 1 04/04/23 18:28 04/06/23 20:35 193-39-5 Isodrin ND ug/L 8.7 2.4 1 04/04/23 18:28 04/06/23 20:35 465-73-6 Isophorone ND ug/L 8.7 1.4 1 04/04/23 18:28 04/06/23 20:35 78-59-1 REPORT OF LABORATORY ANALYSIS IL IH L1 v1 This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Isosafrole ND ug/L 8.7 2.2 1 04/04/23 18:28 04/06/23 20:35 120-58-1 Kepone ND ug/L 17.4 12.3 1 04/04/23 18:28 04/06/23 20:35 143-50-0 Methapyrilene ND ug/L 43.5 14.8 1 04/04/23 18:28 04/06/23 20:35 91-80-5 IH,v1 3-Methylcholanthrene ND ug/L 8.7 3.3 1 04/04/23 18:28 04/06/23 20:35 56-49-5 Methyl methanesulfonate ND ug/L 4.3 2.7 1 04/04/23 18:28 04/06/23 20:35 66-27-3 2-Methylnaphthalene ND ug/L 8.7 1.6 1 04/04/23 18:28 04/06/23 20:35 91-57-6 Methyl parathion ND ug/L 8.7 3.2 1 04/04/23 18:28 04/06/23 20:35 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 8.7 1.6 1 04/04/23 18:28 04/06/23 20:35 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 8.7 1.1 1 04/04/23 18:28 04/06/23 20:35 15831-10-4 1-Naphthalenamine ND ug/L 8.7 5.2 1 04/04/23 18:28 04/06/23 20:35 134-32-7 2-Naphthalenamine ND ug/L 8.7 4.7 1 04/04/23 18:28 04/06/23 20:35 91-59-8 1,4-Naphthoquinone ND ug/L 4.3 3.8 1 04/04/23 18:28 04/06/23 20:35 130-15-4 2-Nitroaniline ND ug/L 17.4 2.6 1 04/04/23 18:28 04/06/23 20:35 88-74-4 3-Nitroaniline ND ug/L 17.4 3.3 1 04/04/23 18:28 04/06/23 20:35 99-09-2 4-Nitroaniline ND ug/L 17.4 4.4 1 04/04/23 18:28 04/06/23 20:35 100-01-6 Nitrobenzene ND ug/L 8.7 1.6 1 04/04/23 18:28 04/06/23 20:35 98-95-3 2-Nitrophenol ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 88-75-5 4-Nitrophenol ND ug/L 43.5 5.7 1 04/04/23 18:28 04/06/23 20:35 100-02-7 5-Nitro-o-toluidine ND ug/L 8.7 3.3 1 04/04/23 18:28 04/06/23 20:35 99-55-8 N-Nitrosodiethylamine ND ug/L 8.7 2.0 1 04/04/23 18:28 04/06/23 20:35 55-18-5 N-Nitrosodimethylamine ND ug/L 8.7 1.6 1 04/04/23 18:28 04/06/23 20:35 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 621-64-7 N-Nitrosodiphenylamine ND ug/L 8.7 2.6 1 04/04/23 18:28 04/06/23 20:35 86-30-6 N-Nitrosomethylethylamine ND ug/L 8.7 6.5 1 04/04/23 18:28 04/06/23 20:35 10595-95-6 N-Nitrosopiperidine ND ug/L 8.7 2.2 1 04/04/23 18:28 04/06/23 20:35 100-75-4 N-Nitrosopyrrolidine ND ug/L 8.7 2.7 1 04/04/23 18:28 04/06/23 20:35 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 8.7 2.2 1 04/04/23 18:28 04/06/23 20:35 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 8.7 1.0 1 04/04/23 18:28 04/06/23 20:35 108-60-1 Parathion (Ethyl parathion) ND ug/L 8.7 3.4 1 04/04/23 18:28 04/06/23 20:35 56-38-2 Pentachlorobenzene ND ug/L 8.7 3.0 1 04/04/23 18:28 04/06/23 20:35 608-93-5 Pentachloronitrobenzene ND ug/L 8.7 2.8 1 04/04/23 18:28 04/06/23 20:35 82-68-8 Pentachlorophenol ND ug/L 17.4 3.3 1 04/04/23 18:28 04/06/23 20:35 87-86-5 Phenacetin ND ug/L 8.7 3.1 1 04/04/23 18:28 04/06/23 20:35 62-44-2 Phenanthrene ND ug/L 8.7 1.7 1 04/04/23 18:28 04/06/23 20:35 85-01-8 Phenol ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 108-95-2 p-Phenylenediamine ND ug/L 8.7 8.7 1 04/04/23 18:28 04/06/23 20:35 106-50-3 Phorate ND ug/L 8.7 3.1 1 04/04/23 18:28 04/06/23 20:35 298-02-2 Pronamide ND ug/L 8.7 2.7 1 04/04/23 18:28 04/06/23 20:35 23950-58-5 Pyrene ND ug/L 8.7 1.9 1 04/04/23 18:28 04/06/23 20:35 129-00-0 Safrole ND ug/L 8.7 2.0 1 04/04/23 18:28 04/06/23 20:35 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 8.7 3.9 1 04/04/23 18:28 04/06/23 20:35 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 8.7 1.3 1 04/04/23 18:28 04/06/23 20:35 58-90-2 Thionazin ND ug/L 8.7 2.5 1 04/04/23 18:28 04/06/23 20:35 297-97-2 O-Toluidine ND ug/L 8.7 2.3 1 04/04/23 18:28 04/06/23 20:35 95-53-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 2,4,5-Trichlorophenol ND ug/L 8.7 1.2 1 04/04/23 18:28 04/06/23 20:35 95-95-4 2,4,6-Trichlorophenol ND ug/L 8.7 1.3 1 04/04/23 18:28 04/06/23 20:35 88-06-2 1,3,5-Trinitrobenzene ND ug/L 8.7 4.8 1 04/04/23 18:28 04/06/23 20:35 99-35-4 v1 Surrogates Nitrobenzene-d5 (S) 105 % 10-138 1 04/04/23 18:28 04/06/23 20:35 4165-60-0 2-Fluorobiphenyl (S) 90 % 10-130 1 04/04/23 18:28 04/06/23 20:35 321-60-8 Terphenyl-d14 (S) 105 % 19-191 1 04/04/23 18:28 04/06/23 20:35 1718-51-0 Phenol-d6 (S) 50 % 10-130 1 04/04/23 18:28 04/06/23 20:35 13127-88-3 2-Fluorophenol (S) 69 % 10-130 1 04/04/23 18:28 04/06/23 20:35 367-12-4 2,4,6-Tribromophenol (S) 115 % 10-164 1 04/04/23 18:28 04/06/23 20:35 118-79-6 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 04/04/23 22:13 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 80 % 67-130 1 04/04/23 22:13 17060-07-0 Toluene-d8 (S) 88 % 70-130 1 04/04/23 22:13 2037-26-5 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 04/01/23 06:27 67-64-1 Acetonitrile ND ug/L 50.0 24.8 1 04/01/23 06:27 75-05-8 Acrolein ND ug/L 10.0 8.5 1 04/01/23 06:27 107-02-8 Acrylonitrile ND ug/L 10.0 1.8 1 04/01/23 06:27 107-13-1 Allyl chloride ND ug/L 2.0 0.50 1 04/01/23 06:27 107-05-1 Benzene ND ug/L 1.0 0.34 1 04/01/23 06:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 04/01/23 06:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 04/01/23 06:27 75-27-4 Bromoform ND ug/L 1.0 0.34 1 04/01/23 06:27 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 04/01/23 06:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 04/01/23 06:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 04/01/23 06:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 04/01/23 06:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 04/01/23 06:27 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 04/01/23 06:27 75-00-3 Chloroform ND ug/L 1.0 0.43 1 04/01/23 06:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 04/01/23 06:27 74-87-3 Chloroprene ND ug/L 5.0 1.6 1 04/01/23 06:27 126-99-8 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 04/01/23 06:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 04/01/23 06:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 04/01/23 06:27 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 04/01/23 06:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 04/01/23 06:27 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 04/01/23 06:27 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 04/01/23 06:27 106-46-7 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level - Acrolein Analytical Method: EPA 8260D Pace Analytical Services - Charlotte trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 04/01/23 06:27 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 04/01/23 06:27 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 04/01/23 06:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 04/01/23 06:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 04/01/23 06:27 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 04/01/23 06:27 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 04/01/23 06:27 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 04/01/23 06:27 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 04/01/23 06:27 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 04/01/23 06:27 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 04/01/23 06:27 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 06:27 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 04/01/23 06:27 10061-02-6 Ethylbenzene ND ug/L 1.0 0.30 1 04/01/23 06:27 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.28 1 04/01/23 06:27 97-63-2 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 04/01/23 06:27 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 04/01/23 06:27 591-78-6 lodomethane ND ug/L 20.0 9.7 1 04/01/23 06:27 74-88-4 Isobutanol ND ug/L 100 52.3 1 04/01/23 06:27 78-83-1 Methacrylonitrile ND ug/L 10.0 4.2 1 04/01/23 06:27 126-98-7 Methylene Chloride ND ug/L 5.0 2.0 1 04/01/23 06:27 75-09-2 Methyl methacrylate ND ug/L 2.0 0.32 1 04/01/23 06:27 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 04/01/23 06:27 108-10-1 Naphthalene ND ug/L 1.0 0.64 1 04/01/23 06:27 91-20-3 Propionitrile ND ug/L 20.0 3.6 1 04/01/23 06:27 107-12-0 Styrene ND ug/L 1.0 0.29 1 04/01/23 06:27 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 04/01/23 06:27 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 04/01/23 06:27 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 04/01/23 06:27 127-18-4 Tetrahydrofuran ND ug/L 10.0 3.5 1 04/01/23 06:27 109-99-9 Toluene ND ug/L 1.0 0.24 1 04/01/23 06:27 108-88-3 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 04/01/23 06:27 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 04/01/23 06:27 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 04/01/23 06:27 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 04/01/23 06:27 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 04/01/23 06:27 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 04/01/23 06:27 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 04/01/23 06:27 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 04/01/23 06:27 75-01-4 v2 Xylene (Total) ND ug/L 1.0 0.34 1 04/01/23 06:27 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 04/01/23 06:27 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 04/01/23 06:27 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 04/01/23 06:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: FIELD BLANK UNIT 1 Lab ID: 92659639003 Collected: 03/29/23 16:45 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville Alkalinity, Total as CaCO3 ND ug/L 5000 5000 1 04/06/23 19:52 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids ND mg/L 25.0 25.0 1 03/31/23 19:58 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 22.0 1 04/04/23 02:46 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate ND ug/L 1000 500 1 04/01/23 03:02 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 03/31/23 03:41 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride ND ug/L 1000 500 1 04/05/2319:16 16887-00-6 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016 Pace Analytical Services -Asheville Cyanide ND ug/L 8.0 6.0 1 04/03/23 18:41 04/03/23 22:09 57-12-5 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-3RR Lab ID: 92659639004 Collected: 03/29/23 16:30 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Metals (ICP) 6010D Analytical Method: EPA 601 OD Preparation Method: 3015 Pace National - Mt. Juliet Antimony ND ug/L 10.0 4.30 1 04/03/23 09:02 04/03/23 19:48 7440-36-0 Arsenic ND ug/L 10.0 4.40 1 04/03/23 09:02 04/03/23 19:48 7440-38-2 Barium 54.5 ug/L 5.00 0.736 1 04/03/23 09:02 04/03/23 19:48 7440-39-3 Beryllium ND ug/L 2.00 0.330 1 04/03/23 09:02 04/03/23 19:48 7440-41-7 Cadmium ND ug/L 2.00 0.479 1 04/03/23 09:02 04/03/23 19:48 7440-43-9 Chromium ND ug/L 10.0 1.40 1 04/03/23 09:02 04/03/23 19:48 7440-47-3 Cobalt 3.64J ug/L 10.0 0.840 1 04/03/23 09:02 04/03/23 19:48 7440-48-4 J Copper 20.2 ug/L 10.0 3.68 1 04/03/23 09:02 04/03/23 19:48 7440-50-8 Iron 2940 ug/L 100 18.0 1 04/03/23 09:02 04/03/23 19:48 7439-89-6 Lead ND ug/L 6.00 2.99 1 04/03/23 09:02 04/03/23 19:48 7439-92-1 Manganese 2890 ug/L 10.0 0.934 1 04/03/23 09:02 04/03/23 19:48 7439-96-5 Nickel 3.25.1 ug/L 10.0 1.61 1 04/03/23 09:02 04/03/23 19:48 7440-02-0 J Selenium ND ug/L 10.0 7.35 1 04/03/23 09:02 04/03/23 19:48 7782-49-2 Silver ND ug/L 5.00 1.54 1 04/03/23 09:02 04/03/23 19:48 7440-22-4 Vanadium ND ug/L 20.0 4.99 1 04/03/23 09:02 04/03/23 19:48 7440-62-2 Zinc 8.44.1 ug/L 50.0 6.52 1 04/03/23 09:02 04/03/23 19:48 7440-66-6 J Metals (ICPMS) 6020B Analytical Method: EPA 6020E Preparation Method: 3015 Pace National - Mt. Juliet Thallium ND ug/L 2.00 0.121 1 04/05/23 01:56 04/05/23 10:55 7440-28-0 Mercury 7470A Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane Date: 05/24/2023 01:13 PM Analytical Method: EPA 7470A Preparation Method: 7470A Pace National - Mt. Juliet ND ug/L 0.200 0.100 1 04/05/23 10:35 04/05/23 21:54 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 04/07/23 02:32 67-64-1 1.8 1 04/07/23 02:32 107-13-1 0.34 1 04/07/23 02:32 71-43-2 0.47 1 04/07/23 02:32 74-97-5 0.31 1 04/07/23 02:32 75-27-4 0.34 1 04/07/23 02:32 75-25-2 1.7 1 04/07/23 02:32 74-83-9 4.0 1 04/07/23 02:32 78-93-3 0.36 1 04/07/23 02:32 75-15-0 0.33 1 04/07/23 02:32 56-23-5 0.28 1 04/07/23 02:32 108-90-7 0.65 1 04/07/23 02:32 75-00-3 0.43 1 04/07/23 02:32 67-66-3 0.54 1 04/07/23 02:32 74-87-3 0.34 1 04/07/23 02:32 96-12-8 0.36 1 04/07/23 02:32 124-48-1 0.27 1 04/07/23 02:32 106-93-4 0.39 1 04/07/23 02:32 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-3RR Lab ID: 92659639004 Collected: 03/29/23 16:30 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 05/24/2023 01:13 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.34 1 04/07/23 02:32 95-50-1 ND ug/L 1.0 0.33 1 04/07/23 02:32 106-46-7 ND ug/L 1.0 0.56 1 04/07/23 02:32 110-57-6 ND ug/L 1.0 0.37 1 04/07/23 02:32 75-34-3 ND ug/L 1.0 0.32 1 04/07/23 02:32 107-06-2 ND ug/L 1.0 0.35 1 04/07/23 02:32 75-35-4 ND ug/L 1.0 0.38 1 04/07/23 02:32 156-59-2 ND ug/L 1.0 0.40 1 04/07/23 02:32 156-60-5 ND ug/L 1.0 0.36 1 04/07/23 02:32 78-87-5 ND ug/L 1.0 0.36 1 04/07/23 02:32 10061-01-5 ND ug/L 1.0 0.36 1 04/07/23 02:32 10061-02-6 ND ug/L 1.0 0.30 1 04/07/23 02:32 100-41-4 ND ug/L 5.0 0.48 1 04/07/23 02:32 591-78-6 ND ug/L 20.0 9.7 1 04/07/23 02:32 74-88-4 ND ug/L 5.0 2.0 1 04/07/23 02:32 75-09-2 ND ug/L 5.0 2.7 1 04/07/23 02:32 108-10-1 ND ug/L 1.0 0.29 1 04/07/23 02:32 100-42-5 ND ug/L 1.0 0.31 1 04/07/23 02:32 630-20-6 ND ug/L 1.0 0.22 1 04/07/23 02:32 79-34-5 ND ug/L 1.0 0.29 1 04/07/23 02:32 127-18-4 ND ug/L 1.0 0.24 1 04/07/23 02:32 108-88-3 ND ug/L 1.0 0.81 1 04/07/23 02:32 87-61-6 ND ug/L 1.0 0.33 1 04/07/23 02:32 71-55-6 ND ug/L 1.0 0.32 1 04/07/23 02:32 79-00-5 ND ug/L 1.0 0.38 1 04/07/23 02:32 79-01-6 ND ug/L 1.0 0.30 1 04/07/23 02:32 75-69-4 ND ug/L 1.0 0.26 1 04/07/23 02:32 96-18-4 ND ug/L 2.0 1.3 1 04/07/23 02:32 108-05-4 ND ug/L 1.0 0.39 1 04/07/23 02:32 75-01-4 ND ug/L 1.0 0.34 1 04/07/23 02:32 1330-20-7 98 % 70-130 1 04/07/23 02:32 460-00-4 98 % 70-130 1 04/07/23 02:32 17060-07-0 97 % 70-130 1 04/07/23 02:32 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 20.2 ug/L 2.0 0.86 1 04/05/23 02:01 123-91-1 82 % 67-130 1 04/05/23 02:01 17060-07-0 88 % 70-130 1 04/05/23 02:01 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 163000 ug/L 5000 5000 1 04/06/2319:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: MW-3RR Parameters Lab ID: 92659639004 Collected: Report Results Units Limit 03/29/23 16:30 MDL DF Received: 03/30/23 10:00 Matrix: Water Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 192 mg/L 25.0 25.0 1 03/31/23 19:58 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 2870 ug/L 1000 500 1 04/01/23 03:18 14808-79-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 21600 ug/L 1000 500 1 04/05/2319:17 16887-00-6 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: TRIP BLANK Parameters 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV Low Level -Acrolein Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Date: 05/24/2023 01:13 PM ANALYTICAL RESULTS Lab ID: 92659639005 Collected: 03/29/23 00:00 Received: 03/30/23 10:00 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 04/04/23 22:32 123-91-1 83 % 67-130 89 % 70-130 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 10.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1 04/04/23 22:32 17060-07-0 1 04/04/23 22:32 2037-26-5 5.1 1 04/01/23 06:46 67-64-1 24.8 1 04/01/23 06:46 75-05-8 8.5 1 04/01/23 06:46 107-02-8 1.8 1 04/01/23 06:46 107-13-1 0.50 1 04/01/23 06:46 107-05-1 0.34 1 04/01/23 06:46 71-43-2 0.47 1 04/01/23 06:46 74-97-5 0.31 1 04/01/23 06:46 75-27-4 0.34 1 04/01/23 06:46 75-25-2 1.7 1 04/01/23 06:46 74-83-9 4.0 1 04/01/23 06:46 78-93-3 0.36 1 04/01/23 06:46 75-15-0 0.33 1 04/01/23 06:46 56-23-5 0.28 1 04/01/23 06:46 108-90-7 0.65 1 04/01/23 06:46 75-00-3 0.43 1 04/01/23 06:46 67-66-3 0.54 1 04/01/23 06:46 74-87-3 1.6 1 04/01/23 06:46 126-99-8 0.34 1 04/01/23 06:46 96-12-8 0.36 1 04/01/23 06:46 124-48-1 0.27 1 04/01/23 06:46 106-93-4 0.39 1 04/01/23 06:46 74-95-3 0.34 1 04/01/23 06:46 95-50-1 0.34 1 04/01/23 06:46 541-73-1 0.33 1 04/01/23 06:46 106-46-7 0.56 1 04/01/23 06:46 110-57-6 0.35 1 04/01/23 06:46 75-71-8 0.37 1 04/01/23 06:46 75-34-3 0.32 1 04/01/23 06:46 107-06-2 0.35 1 04/01/23 06:46 75-35-4 0.38 1 04/01/23 06:46 156-59-2 0.40 1 04/01/23 06:46 156-60-5 0.36 1 04/01/23 06:46 78-87-5 0.28 1 04/01/23 06:46 142-28-9 0.39 1 04/01/23 06:46 594-20-7 0.43 1 04/01/23 06:46 563-58-6 0.36 1 04/01/23 06:46 10061-01-5 0.36 1 04/01/23 06:46 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 Sample: TRIP BLANK Lab ID: 92659639005 Collected: 03/29/23 00:00 Received: 03/30/23 10:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level -Acrolein Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pentanone (MIBK) Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/24/2023 01:13 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.30 1 04/01/23 06:46 100-41-4 ND ug/L 1.0 0.28 1 04/01/23 06:46 97-63-2 ND ug/L 2.0 1.5 1 04/01/23 06:46 87-68-3 ND ug/L 5.0 0.48 1 04/01/23 06:46 591-78-6 ND ug/L 20.0 9.7 1 04/01/23 06:46 74-88-4 ND ug/L 100 52.3 1 04/01/23 06:46 78-83-1 ND ug/L 10.0 4.2 1 04/01/23 06:46 126-98-7 ND ug/L 5.0 2.0 1 04/01/23 06:46 75-09-2 ND ug/L 2.0 0.32 1 04/01/23 06:46 80-62-6 ND ug/L 5.0 2.7 1 04/01/23 06:46 108-10-1 ND ug/L 1.0 0.64 1 04/01/23 06:46 91-20-3 ND ug/L 20.0 3.6 1 04/01/23 06:46 107-12-0 ND ug/L 1.0 0.29 1 04/01/23 06:46 100-42-5 ND ug/L 1.0 0.31 1 04/01/23 06:46 630-20-6 ND ug/L 1.0 0.22 1 04/01/23 06:46 79-34-5 ND ug/L 1.0 0.29 1 04/01/23 06:46 127-18-4 ND ug/L 1.0 0.24 1 04/01/23 06:46 108-88-3 ND ug/L 1.0 0.64 1 04/01/23 06:46 120-82-1 ND ug/L 1.0 0.33 1 04/01/23 06:46 71-55-6 ND ug/L 1.0 0.32 1 04/01/23 06:46 79-00-5 ND ug/L 1.0 0.38 1 04/01/23 06:46 79-01-6 ND ug/L 1.0 0.30 1 04/01/23 06:46 75-69-4 ND ug/L 1.0 0.26 1 04/01/23 06:46 96-18-4 ND ug/L 2.0 1.3 1 04/01/23 06:46 108-05-4 ND ug/L 1.0 0.39 1 04/01/23 06:46 75-01-4 ND ug/L 1.0 0.34 1 04/01/23 06:46 1330-20-7 100 % 70-130 1 04/01/23 06:46 460-00-4 100 % 70-130 1 04/01/23 06:46 17060-07-0 93 % 70-130 1 04/01/23 06:46 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 32 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 2034529 Analysis Method: EPA 8151A QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151A Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: R3910270-1 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4-D ug/L ND 2.00 0.547 04/06/23 00:08 Dinoseb ug/L ND 2.00 0.250 04/06/23 00:08 2,4,5-T ug/L ND 2.00 0.258 04/06/23 00:08 2,4,5-TP (Silvex) ug/L ND 2.00 0.335 04/06/23 00:08 2,4-DCAA (S) % 59 14.0-158 04/06/23 00:08 LABORATORY CONTROL SAMPLE & LCSD: R3910270-2 R3910270-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D ug/L 5.00 2.84 3.51 56.8 70.2 50.0-120 21.1 20 P9,R1 Dinoseb ug/L 5.00 3.39 4.01 67.8 80.2 36.0-134 16.8 20 2,4,5-T ug/L 5.00 3.22 3.98 64.4 79.6 54.0-120 21.1 20 R1 2,4,5-TP (Silvex) ug/L 5.00 2.65 3.41 53.0 68.2 50.0-125 25.1 20 P9,R1 2,4-DCAA (S) % 66.4 83.4 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 763417 Analysis Method: RSK-175 QC Batch Method: RSK-175 Analysis Description: Biodegradation Indicator Gases Laboratory: Pace Analytical Gulf Coast Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 2470311 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 5.0 2.0 04/10/23 07:24 LABORATORY CONTROL SAMPLE & LCSD: 2470312 2470313 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 380 280 370 73 98 70-130 29 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 2034556 Analysis Method: EPA 6010D QC Batch Method: 3015 Analysis Description: Metals (ICP) 6010D Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: R3908792-1 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 10.0 4.30 04/03/2318:54 Arsenic ug/L ND 10.0 4.40 04/03/2318:54 Barium ug/L ND 5.00 0.736 04/03/2318:54 Beryllium ug/L ND 2.00 0.330 04/03/2318:54 Cadmium ug/L ND 2.00 0.479 04/03/2318:54 Chromium ug/L ND 10.0 1.40 04/03/2318:54 Cobalt ug/L ND 10.0 0.840 04/03/2318:54 Copper ug/L ND 10.0 3.68 04/03/2318:54 Iron ug/L ND 100 18.0 04/03/2318:54 Lead ug/L ND 6.00 2.99 04/03/2318:54 Manganese ug/L ND 10.0 0.934 04/03/2318:54 Nickel ug/L ND 10.0 1.61 04/03/2318:54 Selenium ug/L ND 10.0 7.35 04/03/2318:54 Silver ug/L ND 5.00 1.54 04/03/2318:54 Tin ug/L ND 50.0 4.87 04/03/2318:54 Vanadium ug/L ND 20.0 4.99 04/03/2318:54 Zinc ug/L ND 50.0 6.52 04/03/2318:54 LABORATORY CONTROL SAMPLE: R3908792-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 1000 966 96.6 80.0-120 Arsenic ug/L 1000 968 96.8 80.0-120 Barium ug/L 1000 1020 102 80.0-120 Beryllium ug/L 1000 949 94.9 80.0-120 Cadmium ug/L 1000 974 97.4 80.0-120 Chromium ug/L 1000 943 94.3 80.0-120 Cobalt ug/L 1000 978 97.8 80.0-120 Copper ug/L 1000 974 97.4 80.0-120 Iron ug/L 10000 9550 95.5 80.0-120 Lead ug/L 1000 968 96.8 80.0-120 Manganese ug/L 1000 901 90.1 80.0-120 Nickel ug/L 1000 953 95.3 80.0-120 Selenium ug/L 1000 1020 102 80.0-120 Silver ug/L 200 186 92.9 80.0-120 Tin ug/L 1000 984 98.4 80.0-120 Vanadium ug/L 1000 979 97.9 80.0-120 Zinc ug/L 1000 962 96.2 80.0-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: GM1.004 OXFORD LANDFILL UNIT 1 92659639 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3908792-4 R3908792-5 MS MSD L1600694-05 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 1000 1000 961 959 96.1 95.9 75.0-125 0.155 20 Arsenic ug/L ND 1000 1000 962 962 96.2 96.2 75.0-125 0.016 20 Barium ug/L 29.5 1000 1000 1040 1030 101 100 75.0-125 0.147 20 Beryllium ug/L ND 1000 1000 941 946 94.1 94.6 75.0-125 0.571 20 Cadmium ug/L ND 1000 1000 965 963 96.5 96.3 75.0-125 0.263 20 Chromium ug/L ND 1000 1000 931 928 93.1 92.8 75.0-125 0.348 20 Cobalt ug/L ND 1000 1000 957 955 95.7 95.5 75.0-125 0.243 20 Copper ug/L ND 1000 1000 965 963 96.5 96.3 75.0-125 0.178 20 Iron ug/L 34.9 10000 10000 9440 9470 94.0 94.4 75.0-125 0.375 20 Lead ug/L ND 1000 1000 954 950 95.4 95.0 75.0-125 0.398 20 Manganese ug/L 1.23 1000 1000 888 886 88.6 88.5 75.0-125 0.166 20 Nickel ug/L ND 1000 1000 933 928 93.3 92.8 75.0-125 0.536 20 Selenium ug/L ND 1000 1000 1010 1010 101 101 75.0-125 0.408 20 Silver ug/L ND 200 200 185 185 92.5 92.4 75.0-125 0.063 20 Tin ug/L ND 1000 1000 975 971 97.5 97.1 75.0-125 0.413 20 Vanadium ug/L ND 1000 1000 970 964 97.0 96.4 75.0-125 0.554 20 Zinc ug/L ND 1000 1000 945 946 94.5 94.6 75.0-125 0.105 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 2034561 Analysis Method: EPA 6020B QC Batch Method: 3015 Analysis Description: Metals (ICPMS) 6020B Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: R3909569-1 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 2.00 0.121 04/05/2310:26 LABORATORY CONTROL SAMPLE: R3909569-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 50.0 50.0 100 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909569-4 R3909569-5 MS MSD L1600881-01 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 4.02 50.0 50.0 54.3 53.6 101 99.1 75.0-125 1.46 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 2034660 Analysis Method: EPA 7470A QC Batch Method: 7470A Analysis Description: Mercury 7470A Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: R3909264-1 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.200 0.100 04/04/2318:46 LABORATORY CONTROL SAMPLE: R3909264-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 3.00 2.84 94.6 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909264-3 R3909264-4 MS MSD L1600626-07 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 3.00 3.00 2.91 2.86 96.8 95.3 75.0-125 1.58 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 2035866 Analysis Method: EPA 7470A QC Batch Method: 7470A Analysis Description: Mercury 7470A Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92659639004 METHOD BLANK: R3909862-1 Associated Lab Samples: 92659639004 Parameter Units Mercury ug/L LABORATORY CONTROL SAMPLE: R3909862-2 Parameter Units Mercury ug/L Matrix: Water Blank Reporting Result Limit ND 0.200 Spike LCS Conc. Result 3.00 3.24 MDL Analyzed Qualifiers 0.100 04/05/23 21:32 LCS % Rec % Rec Limits Qualifiers 108 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3909862-3 R3909862-4 MS MSD L1601546-04 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 3.00 3.00 3.26 3.30 109 110 75.0-125 1.22 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765937 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639004 METHOD BLANK: 3976888 Associated Lab Samples: 92659639004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 04/07/23 00:43 1,1,1-Trichloroethane ug/L ND 1.0 0.33 04/07/23 00:43 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 04/07/23 00:43 1,1,2-Trichloroethane ug/L ND 1.0 0.32 04/07/23 00:43 1,1-Dichloroethane ug/L ND 1.0 0.37 04/07/23 00:43 1,1-Dichloroethene ug/L ND 1.0 0.35 04/07/23 00:43 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 04/07/23 00:43 1,2,3-Trichloropropane ug/L ND 1.0 0.26 04/07/23 00:43 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 04/07/23 00:43 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 04/07/23 00:43 1,2-Dichlorobenzene ug/L ND 1.0 0.34 04/07/23 00:43 1,2-Dichloroethane ug/L ND 1.0 0.32 04/07/23 00:43 1,2-Dichloropropane ug/L ND 1.0 0.36 04/07/23 00:43 1,4-Dichlorobenzene ug/L ND 1.0 0.33 04/07/23 00:43 2-Butanone (MEK) ug/L ND 5.0 4.0 04/07/23 00:43 2-Hexanone ug/L ND 5.0 0.48 04/07/23 00:43 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 04/07/23 00:43 Acetone ug/L ND 25.0 5.1 04/07/23 00:43 Acrylonitrile ug/L ND 10.0 1.8 04/07/23 00:43 Benzene ug/L ND 1.0 0.34 04/07/23 00:43 Bromochloromethane ug/L ND 1.0 0.47 04/07/23 00:43 Bromodichloromethane ug/L ND 1.0 0.31 04/07/23 00:43 Bromoform ug/L ND 1.0 0.34 04/07/23 00:43 Bromomethane ug/L ND 2.0 1.7 04/07/23 00:43 Carbon disulfide ug/L ND 2.0 0.36 04/07/23 00:43 Carbon tetrachloride ug/L ND 1.0 0.33 04/07/23 00:43 Chlorobenzene ug/L ND 1.0 0.28 04/07/23 00:43 Chloroethane ug/L ND 1.0 0.65 04/07/23 00:43 Chloroform ug/L ND 1.0 0.43 04/07/23 00:43 Chloromethane ug/L ND 1.0 0.54 04/07/23 00:43 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 04/07/23 00:43 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 00:43 Dibromochloromethane ug/L ND 1.0 0.36 04/07/23 00:43 Dibromomethane ug/L ND 1.0 0.39 04/07/23 00:43 Ethylbenzene ug/L ND 1.0 0.30 04/07/23 00:43 lodomethane ug/L ND 20.0 9.7 04/07/23 00:43 Methylene Chloride ug/L ND 5.0 2.0 04/07/23 00:43 Styrene ug/L ND 1.0 0.29 04/07/23 00:43 Tetrachloroethene ug/L ND 1.0 0.29 04/07/23 00:43 Toluene ug/L ND 1.0 0.24 04/07/23 00:43 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 METHOD BLANK: 3976888 Associated Lab Samples: 92659639004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 04/07/23 00:43 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 04/07/23 00:43 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 04/07/23 00:43 Trichloroethene ug/L ND 1.0 0.38 04/07/23 00:43 Trichlorofluoromethane ug/L ND 1.0 0.30 04/07/23 00:43 Vinyl acetate ug/L ND 2.0 1.3 04/07/23 00:43 Vinyl chloride ug/L ND 1.0 0.39 04/07/23 00:43 Xylene (Total) ug/L ND 1.0 0.34 04/07/23 00:43 1,2-Dichloroethane-d4 (S) % 98 70-130 04/07/23 00:43 4-Bromofluorobenzene (S) % 100 70-130 04/07/23 00:43 Toluene-d8 (S) % 97 70-130 04/07/23 00:43 LABORATORY CONTROL SAMPLE: 3976889 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 21.2 106 70-130 1,1,1-Trichloroethane ug/L 20 19.0 95 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.2 106 70-130 1,1,2-Trichloroethane ug/L 20 20.5 102 70-130 1,1-Dichloroethane ug/L 20 18.4 92 70-130 1,1-Dichloroethene ug/L 20 18.2 91 70-130 1,2,3-Trichlorobenzene ug/L 20 22.1 111 70-130 1,2,3-Trichloropropane ug/L 20 20.5 102 70-130 1,2-Dibromo-3-chloropropane ug/L 20 20.8 104 70-131 1,2-Dibromoethane (EDB) ug/L 20 20.7 104 70-130 1,2-Dichlorobenzene ug/L 20 21.3 107 70-130 1,2-Dichloroethane ug/L 20 19.5 97 70-130 1,2-Dichloropropane ug/L 20 19.9 100 70-130 1,4-Dichlorobenzene ug/L 20 21.4 107 70-130 2-Butanone (MEK) ug/L 40 37.1 93 70-134 2-Hexanone ug/L 40 40.2 100 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 39.2 98 70-130 Acetone ug/L 40 31.1 78 70-133 Acrylonitrile ug/L 100 90.6 91 70-130 Benzene ug/L 20 19.5 98 70-130 Bromochloromethane ug/L 20 19.1 96 70-130 Bromodichloromethane ug/L 20 19.7 98 70-130 Bromoform ug/L 20 20.5 103 70-130 Bromomethane ug/L 20 15.2 76 45-151 Carbon disulfide ug/L 20 16.8 84 70-130 Carbon tetrachloride ug/L 20 19.7 99 70-130 Chlorobenzene ug/L 20 20.9 105 70-130 Chloroethane ug/L 20 17.9 90 39-152 Chloroform ug/L 20 19.2 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 76 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: Parameter 3976889 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloromethane ug/L 20 17.0 85 58-130 cis-1,2-Dichloroethene ug/L 20 18.6 93 70-130 cis-1,3-Dichloropropene ug/L 20 19.8 99 70-130 Dibromochloromethane ug/L 20 20.6 103 70-130 Dibromomethane ug/L 20 20.6 103 70-130 Ethylbenzene ug/L 20 20.4 102 70-130 lodomethane ug/L 40 36.3 91 53-141 Methylene Chloride ug/L 20 15.6 78 66-130 Styrene ug/L 20 21.0 105 70-130 Tetrachloroethene ug/L 20 20.1 100 70-130 Toluene ug/L 20 19.6 98 70-130 trans-1,2-Dichloroethene ug/L 20 18.4 92 70-130 trans- 1,3-Dichloropropene ug/L 20 19.8 99 70-130 trans-1,4-Dichloro-2-butene ug/L 20 22.5 113 57-185 Trichloroethene ug/L 20 20.2 101 70-130 Trichlorofluoromethane ug/L 20 18.2 91 62-130 Vinyl acetate ug/L 40 38.7 97 70-144 Vinyl chloride ug/L 20 14.9 74 62-130 Xylene (Total) ug/L 60 61.3 102 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 3976891 Units 92659923009 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 25.7 129 70-141 1,1,1-Trichloroethane ug/L ND 20 20.6 103 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 24.5 122 69-142 1,1,2-Trichloroethane ug/L ND 20 22.3 111 70-138 1,1-Dichloroethane ug/L ND 20 18.7 94 70-150 1,1-Dichloroethene ug/L ND 20 21.5 107 70-156 1,2,3-Trichlorobenzene ug/L ND 20 27.8 139 70-148 1,2,3-Trichloropropane ug/L ND 20 23.9 120 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 25.2 126 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 25.2 126 70-138 1,2-Dichlorobenzene ug/L ND 20 26.2 131 70-141 1,2-Dichloroethane ug/L ND 20 21.3 106 69-143 1,2-Dichloropropene ug/L ND 20 22.2 111 68-156 1,4-Dichlorobenzene ug/L ND 20 25.7 128 70-142 2-Butanone (MEK) ug/L ND 40 42.4 106 60-157 2-Hexanone ug/L ND 40 48.5 121 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 43.7 109 70-141 Acetone ug/L ND 40 37.5 94 58-157 Acrylonitrile ug/L ND 100 104 104 69-147 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 MATRIX SPIKE SAMPLE: Parameter 3976891 Units 92659923009 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Benzene ug/L ND 20 22.3 112 70-142 Bromochloromethane ug/L ND 20 21.7 108 70-146 Bromodichloromethane ug/L ND 20 22.0 110 70-139 Bromoform ug/L ND 20 26.4 132 64-140 Bromomethane ug/L ND 20 19.0 95 28-192 Carbon disulfide ug/L ND 20 20.4 102 70-151 Carbon tetrachloride ug/L ND 20 22.5 112 70-148 Chlorobenzene ug/L ND 20 24.9 124 70-141 Chloroethane ug/L ND 20 24.2 121 58-191 Chloroform ug/L ND 20 20.5 103 70-148 Chloromethane ug/L ND 20 22.8 114 43-162 cis-1,2-Dichloroethene ug/L ND 20 20.5 102 68-151 cis-1,3-Dichloropropene ug/L ND 20 22.7 113 70-139 Dibromochloromethane ug/L ND 20 25.7 128 70-144 Dibromomethane ug/L ND 20 22.9 114 70-139 Ethylbenzene ug/L ND 20 23.9 119 70-143 lodomethane ug/L ND 40 45.1 113 35-171 Methylene Chloride ug/L ND 20 8.9 45 62-149 IK,M1,v3 Styrene ug/L ND 20 24.6 123 70-143 Tetrachloroethene ug/L ND 20 23.5 117 70-145 Toluene ug/L ND 20 21.5 107 70-142 trans-1,2-Dichloroethene ug/L ND 20 20.7 103 70-151 trans- 1,3-Dichloropropene ug/L ND 20 22.6 113 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 25.1 125 51-159 Trichloroethene ug/L ND 20 22.3 112 62-146 Trichlorofluoromethane ug/L ND 20 23.0 115 63-153 Vinyl acetate ug/L ND 40 39.9 100 61-162 Vinyl chloride ug/L ND 20 18.4 92 61-163 Xylene (Total) ug/L ND 60 72.3 121 70-143 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 3976890 92659670001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichlorobenzene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 SAMPLE DUPLICATE: 3976890 Parameter Units 92659670001 Result Dup Result RPD Max RPD 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 v2 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 99 102 4-Bromofluorobenzene (S) % 98 99 Toluene-d8 (S) % 97 96 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765904 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004, 92659639005 METHOD BLANK: 3976660 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004, 92659639005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 04/04/23 20:00 1,2-Dichloroethane-d4 (S) % 80 67-130 04/04/23 20:00 Toluene-d8 (S) % 87 70-130 04/04/23 20:00 LABORATORY CONTROL SAMPLE: 3976661 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 80 67-130 Toluene-d8 (S) % 88 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3976662 3976663 MS MSD 92659666001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 18.6 18.5 92 92 55-137 0 30 H1 1,2-Dichloroethane-d4 (S) % 84 85 67-130 30 Toluene-d8 (S) % 109 80 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765322 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639005 METHOD BLANK: 3973928 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639005 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 03/31/23 22:54 1,1,1-Trichloroethane ug/L ND 1.0 0.33 03/31/23 22:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 03/31/23 22:54 1,1,2-Trichloroethane ug/L ND 1.0 0.32 03/31/23 22:54 1,1-Dichloroethane ug/L ND 1.0 0.37 03/31/23 22:54 1,1-Dichloroethene ug/L ND 1.0 0.35 03/31/23 22:54 1,1-Dichloropropene ug/L ND 1.0 0.43 03/31/23 22:54 1,2,3-Trichloropropane ug/L ND 1.0 0.26 03/31/23 22:54 1,2,4-Trichlorobenzene ug/L ND 1.0 0.64 03/31/23 22:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 03/31/23 22:54 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 03/31/23 22:54 1,2-Dichlorobenzene ug/L ND 1.0 0.34 03/31/23 22:54 1,2-Dichloroethane ug/L ND 1.0 0.32 03/31/23 22:54 1,2-Dichloropropane ug/L ND 1.0 0.36 03/31/23 22:54 1,3-Dichlorobenzene ug/L ND 1.0 0.34 03/31/23 22:54 1,3-Dichloropropane ug/L ND 1.0 0.28 03/31/23 22:54 1,4-Dichlorobenzene ug/L ND 1.0 0.33 03/31/23 22:54 2,2-Dichloropropane ug/L ND 1.0 0.39 03/31/23 22:54 2-Butanone (MEK) ug/L ND 5.0 4.0 03/31/23 22:54 2-Hexanone ug/L ND 5.0 0.48 03/31/23 22:54 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 03/31/23 22:54 Acetone ug/L ND 25.0 5.1 03/31/23 22:54 Acetonitrile ug/L ND 50.0 24.8 03/31/23 22:54 Acrolein ug/L ND 10.0 8.5 03/31/23 22:54 Acrylonitrile ug/L ND 10.0 1.8 03/31/23 22:54 Allyl chloride ug/L ND 2.0 0.50 03/31/23 22:54 Benzene ug/L ND 1.0 0.34 03/31/23 22:54 Bromochloromethane ug/L ND 1.0 0.47 03/31/23 22:54 Bromodichloromethane ug/L ND 1.0 0.31 03/31/23 22:54 Bromoform ug/L ND 1.0 0.34 03/31/23 22:54 Bromomethane ug/L ND 2.0 1.7 03/31/23 22:54 Carbon disulfide ug/L ND 2.0 0.36 03/31/23 22:54 Carbon tetrachloride ug/L ND 1.0 0.33 03/31/23 22:54 Chlorobenzene ug/L ND 1.0 0.28 03/31/23 22:54 Chloroethane ug/L ND 1.0 0.65 03/31/23 22:54 Chloroform ug/L ND 1.0 0.43 03/31/23 22:54 Chloromethane ug/L ND 1.0 0.54 03/31/23 22:54 Chloroprene ug/L ND 5.0 1.6 03/31/23 22:54 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 03/31/23 22:54 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 03/31/23 22:54 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 METHOD BLANK: 3973928 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639005 Blank Reporting Parameter Units Result Limit MDL Analyzed Dibromochloromethane ug/L ND 1.0 0.36 03/31/23 22:54 Dibromomethane ug/L ND 1.0 0.39 03/31/23 22:54 Dichlorodifluoromethane ug/L ND 1.0 0.35 03/31/23 22:54 Ethyl methacrylate ug/L ND 1.0 0.28 03/31/23 22:54 Ethylbenzene ug/L ND 1.0 0.30 03/31/23 22:54 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 03/31/23 22:54 lodomethane ug/L ND 20.0 9.7 03/31/23 22:54 Isobutanol ug/L ND 100 52.3 03/31/23 22:54 Methacrylonitrile ug/L ND 10.0 4.2 03/31/23 22:54 Methyl methacrylate ug/L ND 2.0 0.32 03/31/23 22:54 Methylene Chloride ug/L ND 5.0 2.0 03/31/23 22:54 Naphthalene ug/L ND 1.0 0.64 03/31/23 22:54 Propionitrile ug/L ND 20.0 3.6 03/31/23 22:54 Styrene ug/L ND 1.0 0.29 03/31/23 22:54 Tetrachloroethene ug/L ND 1.0 0.29 03/31/23 22:54 Tetrahydrofuran ug/L ND 10.0 3.5 03/31/23 22:54 Toluene ug/L ND 1.0 0.24 03/31/23 22:54 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 03/31/23 22:54 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 03/31/23 22:54 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 03/31/23 22:54 Trichloroethene ug/L ND 1.0 0.38 03/31/23 22:54 Trichlorofluoromethane ug/L ND 1.0 0.30 03/31/23 22:54 Vinyl acetate ug/L ND 2.0 1.3 03/31/23 22:54 Vinyl chloride ug/L ND 1.0 0.39 03/31/23 22:54 Xylene (Total) ug/L ND 1.0 0.34 03/31/23 22:54 1,2-Dichloroethane-d4 (S) % 98 70-130 03/31/23 22:54 4-Bromofluorobenzene (S) % 98 70-130 03/31/23 22:54 Toluene-d8 (S) % 100 70-130 03/31/23 22:54 LABORATORY CONTROL SAMPLE: Parameter 3973929 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 20 20.1 100 70-130 1,1,1-Trichloroethane ug/L 20 19.2 96 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.0 100 70-130 1,1,2-Trichloroethane ug/L 20 20.0 100 70-130 1,1-Dichloroethane ug/L 20 18.3 91 70-130 1,1-Dichloroethene ug/L 20 17.4 87 70-130 1,1-Dichloropropene ug/L 20 19.7 99 70-130 1,2,3-Trichloropropane ug/L 20 19.2 96 70-130 1,2,4-Trichlorobenzene ug/L 20 20.2 101 70-130 1,2-Dibromo-3-chloropropane ug/L 20 20.5 102 70-131 1,2-Dibromoethane (EDB) ug/L 20 20.3 102 70-130 1,2-Dichlorobenzene ug/L 20 19.7 98 70-130 Qualifiers v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: Parameter 3973929 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloroethane ug/L 20 19.0 95 70-130 1,2-Dichloropropane ug/L 20 19.4 97 70-130 1,3-Dichlorobenzene ug/L 20 19.6 98 70-130 1,3-Dichloropropane ug/L 20 19.0 95 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 17.5 88 68-135 2-Butanone (MEK) ug/L 40 34.3 86 70-134 2-Hexanone ug/L 40 37.7 94 70-131 4-Methyl-2-pentanone (MIBK) ug/L 40 37.3 93 70-130 Acetone ug/L 40 34.7 87 70-133 Acetonitrile ug/L 200 169 85 70-130 Acrolein ug/L 100 88.1 88 52-170 Acrylonitrile ug/L 100 89.1 89 70-130 Allyl chloride ug/L 20 17.4 87 70-130 Benzene ug/L 20 18.6 93 70-130 Bromochloromethane ug/L 20 20.1 101 70-130 Bromodichloromethane ug/L 20 19.0 95 70-130 Bromoform ug/L 20 19.0 95 70-130 Bromomethane ug/L 20 16.1 80 45-151 Carbon disulfide ug/L 20 16.2 81 70-130 Carbon tetrachloride ug/L 20 19.0 95 70-130 Chlorobenzene ug/L 20 19.3 97 70-130 Chloroethane ug/L 20 17.4 87 39-152 Chloroform ug/L 20 19.4 97 70-130 Chloromethane ug/L 20 17.5 87 58-130 Chloroprene ug/L 20 17.8 89 70-130 cis-1,2-Dichloroethene ug/L 20 18.2 91 70-130 cis-1,3-Dichloropropene ug/L 20 19.3 97 70-130 Dibromochloromethane ug/L 20 19.4 97 70-130 Dibromomethane ug/L 20 20.1 100 70-130 Dichlorodifluoromethane ug/L 20 19.7 98 54-133 Ethyl methacrylate ug/L 20 18.5 92 70-130 Ethylbenzene ug/L 20 18.9 94 70-130 Hexachloro-1,3-butadiene ug/L 20 19.8 99 70-135 lodomethane ug/L 40 35.4 88 53-141 Isobutanol ug/L 400 346 86 70-136 Methacrylonitrile ug/L 200 171 85 70-130 Methyl methacrylate ug/L 20 18.4 92 70-130 Methylene Chloride ug/L 20 16.6 83 66-130 Naphthalene ug/L 20 21.7 109 70-130 Propionitrile ug/L 200 181 91 70-130 Styrene ug/L 20 19.9 100 70-130 Tetrachloroethene ug/L 20 20.0 100 70-130 Tetrahydrofuran ug/L 200 173 86 70-130 Toluene ug/L 20 19.2 96 70-130 trans-1,2-Dichloroethene ug/L 20 18.5 93 70-130 trans- 1,3-Dichloropropene ug/L 20 19.5 97 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: Parameter 3973929 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers trans-1,4-Dichloro-2-butene ug/L 20 21.6 108 57-185 Trichloroethene ug/L 20 19.3 97 70-130 Trichlorofluoromethane ug/L 20 17.0 85 62-130 Vinyl acetate ug/L 40 34.4 86 70-144 Vinyl chloride ug/L 20 14.3 72 62-130 v3 Xylene (Total) ug/L 60 58.5 98 70-130 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3973930 MS 92659639002 Spike Parameter Units Result Conc. MSD Spike Conc. 3973931 MS Result MSD MS Result % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.7 21.8 113 109 70-141 4 30 H1 1,1,1-Trichloroethane ug/L ND 20 20 22.3 21.6 111 108 70-150 3 30 H1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.1 22.3 105 111 69-142 6 30 H1 1,1,2-Trichloroethane ug/L ND 20 20 22.8 22.1 114 110 70-138 3 30 H1 1,1-Dichloroethane ug/L ND 20 20 22.0 20.9 110 105 70-150 5 30 H1 1,1-Dichloroethene ug/L ND 20 20 18.6 17.4 93 87 70-156 6 30 H1 1,1-Dichloropropene ug/L ND 20 20 23.4 22.7 117 113 70-150 3 30 H1 1,2,3-Trichloropropane ug/L ND 20 20 20.8 21.2 104 106 70-140 2 30 H1 1,2,4-Trichlorobenzene ug/L ND 20 20 23.3 22.7 117 114 70-146 3 30 H1 1,2-Dibromo-3- ug/L ND 20 20 23.1 21.5 116 108 68-146 7 30 H1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.5 21.5 112 108 70-138 4 30 H1 1,2-Dichlorobenzene ug/L ND 20 20 22.5 20.9 113 104 70-141 8 30 H1 1,2-Dichloroethane ug/L ND 20 20 22.2 21.2 111 106 69-143 5 30 H1 1,2-Dichloropropane ug/L ND 20 20 22.8 21.5 114 108 68-156 6 30 H1 1,3-Dichlorobenzene ug/L ND 20 20 22.3 21.7 111 109 70-143 3 30 H1 1,3-Dichloropropane ug/L ND 20 20 21.9 20.9 109 104 70-138 5 30 H1 1,4-Dichlorobenzene ug/L ND 20 20 22.6 21.9 113 110 70-142 3 30 H1 2,2-Dichloropropane ug/L ND 20 20 22.6 22.7 113 114 52-170 1 30 H1 2-Butanone (MEK) ug/L ND 40 40 43.2 42.2 108 106 60-157 2 30 H1 2-Hexanone ug/L ND 40 40 46.4 45.5 116 114 68-146 2 30 H1 4-Methyl-2-pentanone ug/L ND 40 40 46.4 44.1 116 110 70-141 5 30 H1 (MIBK) Acetone ug/L ND 40 40 34.8 34.6 87 86 58-157 1 30 H1 Acetonitrile ug/L ND 200 200 199 197 100 99 66-153 1 30 H1,v3 Acrolein ug/L ND 100 100 89.7 87.5 90 87 10-200 3 30 H1,v3 Acrylonitrile ug/L ND 100 100 107 103 107 103 69-147 4 30 H1 Allyl chloride ug/L ND 20 20 18.9 18.3 95 92 65-153 3 30 H1 Benzene ug/L ND 20 20 21.5 20.5 107 102 70-142 5 30 H1 Bromochloromethane ug/L ND 20 20 22.7 22.1 113 111 70-146 2 30 H1 Bromodichloromethane ug/L ND 20 20 22.0 20.9 110 105 70-139 5 30 H1 Bromoform ug/L ND 20 20 21.4 21.6 107 108 64-140 1 30 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3973930 3973931 MS MSD 92659639002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromomethane ug/L ND 20 20 13.6 13.4 68 67 28-192 1 30 H1 Carbon disulfide ug/L ND 20 20 16.4 15.6 82 78 70-151 5 30 H1 Carbon tetrachloride ug/L ND 20 20 21.8 20.5 109 103 70-148 6 30 H1 Chlorobenzene ug/L ND 20 20 22.2 21.5 111 107 70-141 3 30 H1 Chloroethane ug/L ND 20 20 15.9 15.8 79 79 58-191 1 30 H1 Chloroform ug/L ND 20 20 22.9 21.5 114 107 70-148 6 30 H1 Chloromethane ug/L ND 20 20 11.0 10.7 55 53 43-162 3 30 H1 Chloroprene ug/L ND 20 20 21.8 21.0 109 105 69-158 4 30 H1 cis-1,2-Dichloroethene ug/L ND 20 20 22.0 21.1 110 105 68-151 4 30 H1 cis-1,3-Dichloropropene ug/L ND 20 20 22.9 21.7 114 109 70-139 5 30 H1 Dibromochloromethane ug/L ND 20 20 22.3 21.6 112 108 70-144 4 30 H1 Dibromomethane ug/L ND 20 20 21.9 21.0 109 105 70-139 4 30 H1 Dichlorodifluoromethane ug/L ND 20 20 7.6 7.3 38 37 39-171 4 30 H1,M1, v3 Ethyl methacrylate ug/L ND 20 20 23.0 21.7 115 109 70-140 6 30 H1 Ethylbenzene ug/L ND 20 20 22.3 21.5 112 108 70-143 4 30 H1 Hexachloro-1,3-butadiene ug/L ND 20 20 24.2 23.4 121 117 64-163 3 30 H1 lodomethane ug/L ND 40 40 29.8 30.4 75 76 35-171 2 30 H1,v3 Isobutanol ug/L ND 400 400 459 441 115 110 49-152 4 30 H1 Methacrylonitrile ug/L ND 200 200 212 205 106 103 66-145 3 30 H1 Methyl methacrylate ug/L ND 20 20 21.6 19.4 108 97 70-135 11 30 H1 Methylene Chloride ug/L ND 20 20 21.9 21.5 110 107 62-149 2 30 H1,v1 Naphthalene ug/L ND 20 20 25.1 24.4 125 122 67-147 3 30 H1 Propionitrile ug/L ND 200 200 216 210 108 105 69-143 3 30 H1 Styrene ug/L ND 20 20 21.9 22.3 110 111 70-143 2 30 H1 Tetrachloroethene ug/L ND 20 20 21.7 20.8 109 104 70-145 4 30 H1 Tetrahydrofuran ug/L ND 200 200 205 199 103 100 69-144 3 30 H1 Toluene ug/L ND 20 20 21.5 21.2 108 106 70-142 1 30 H1 trans-1,2-Dichloroethene ug/L ND 20 20 20.8 20.3 104 102 70-151 2 30 H1 trans-1,3-Dichloropropene ug/L ND 20 20 22.7 21.7 113 109 70-139 4 30 H1 trans-1,4-Dichloro-2-butene ug/L ND 20 20 22.0 23.7 110 118 51-159 7 30 H1 Trichloroethene ug/L ND 20 20 21.3 21.0 107 105 62-146 2 30 H1 Trichlorofluoromethane ug/L ND 20 20 16.8 15.9 84 80 63-153 5 30 H1,v3 Vinyl acetate ug/L ND 40 40 42.9 41.3 107 103 61-162 4 30 H1 Vinyl chloride ug/L ND 20 20 11.0 10.5 55 52 61-163 5 30 H1,M1, v3 Xylene (Total) ug/L ND 60 60 66.7 65.3 111 109 70-143 2 30 1,2-Dichloroethane-d4 (S) % 100 99 70-130 4-Bromofluorobenzene (S) % 94 102 70-130 Toluene-d8 (S) % 101 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 766042 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 3977305 Matrix: Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L ND 0.050 0.017 04/06/23 16:21 4,4'-DDE ug/L ND 0.050 0.024 04/06/23 16:21 4,4'-DDT ug/L ND 0.050 0.026 04/06/23 16:21 Aldrin ug/L ND 0.050 0.014 04/06/23 16:21 alpha-BHC ug/L ND 0.050 0.012 04/06/23 16:21 beta-BHC ug/L ND 0.050 0.049 04/06/23 16:21 Chlordane (Technical) ug/L ND 0.50 0.16 04/06/23 16:21 delta-BHC ug/L ND 0.050 0.014 04/06/23 16:21 Dieldrin ug/L ND 0.050 0.015 04/06/23 16:21 Endosulfan I ug/L ND 0.050 0.017 04/06/23 16:21 Endosulfan II ug/L ND 0.050 0.016 04/06/23 16:21 Endosulfan sulfate ug/L ND 0.050 0.015 04/06/23 16:21 Endrin ug/L ND 0.050 0.018 04/06/23 16:21 Endrin aldehyde ug/L ND 0.050 0.016 04/06/23 16:21 gamma-BHC (Lindane) ug/L ND 0.050 0.012 04/06/23 16:21 Heptachlor ug/L ND 0.050 0.020 04/06/23 16:21 Heptachlor epoxide ug/L ND 0.050 0.028 04/06/23 16:21 Methoxychlor ug/L ND 0.15 0.042 04/06/23 16:21 Toxaphene ug/L ND 0.50 0.22 04/06/23 16:21 Decachlorobiphenyl (S) % 97 10-200 04/06/23 16:21 Tetrachloro-m-xylene (S) % 87 10-182 04/06/23 16:21 LABORATORY CONTROL SAMPLE: 3977306 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.34 137 50-178 4,4'-DDE ug/L 0.25 0.34 134 43-164 4,4'-DDT ug/L 0.25 0.34 137 23-198 Aldrin ug/L 0.25 0.25 102 13-137 alpha-BHC ug/L 0.25 0.26 105 32-161 beta-BHC ug/L 0.25 0.28 111 54-180 delta-BHC ug/L 0.25 0.26 104 42-169 Dieldrin ug/L 0.25 0.31 126 42-173 Endosulfan I ug/L 0.25 0.29 115 44-168 Endosulfan II ug/L 0.25 0.27 109 45-176 Endosulfan sulfate ug/L 0.25 0.29 116 48-178 Endrin ug/L 0.25 0.34 135 46-178 Endrin aldehyde ug/L 0.25 0.36 142 35-168 gamma-BHC (Lindane) ug/L 0.25 0.27 107 38-162 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: 3977306 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor ug/L 0.25 0.29 116 25-153 Heptachlor epoxide ug/L 0.25 0.27 110 43-170 Methoxychlor ug/L 0.75 0.84 112 37-187 Decachlorobiphenyl (S) % 125 10-200 Tetrachloro-m-xylene (S) % 104 10-182 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977307 3977308 MS MSD 92659774007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 0.42 0.42 0.43 0.37 103 89 13-200 15 30 4,4'-DDE ug/L ND 0.42 0.42 0.42 0.36 102 86 10-182 17 30 4,4'-DDT ug/L ND 0.42 0.42 0.46 0.39 109 93 10-200 17 30 Aldrin ug/L ND 0.42 0.42 0.30 0.24 71 57 10-161 23 30 alpha-BHC ug/L ND 0.42 0.42 0.34 0.29 82 69 10-186 16 30 beta-BHC ug/L ND 0.42 0.42 0.35 0.31 83 75 10-200 11 30 delta-BHC ug/L ND 0.42 0.42 0.29 0.26 71 62 11-199 14 30 Dieldrin ug/L ND 0.42 0.42 0.37 0.34 88 81 10-185 8 30 Endosulfan I ug/L ND 0.42 0.42 0.35 0.32 83 76 10-191 10 30 Endosulfan II ug/L ND 0.42 0.42 0.35 0.31 84 74 10-200 14 30 Endosulfan sulfate ug/L ND 0.42 0.42 0.42 0.36 100 88 17-199 13 30 Endrin ug/L ND 0.42 0.42 0.43 0.37 103 88 11-193 15 30 Endrin aldehyde ug/L ND 0.42 0.42 0.53 0.40 128 96 10-198 29 30 gamma-BHC (Lindane) ug/L ND 0.42 0.42 0.33 0.29 79 68 10-190 14 30 Heptachlor ug/L ND 0.42 0.42 0.36 0.29 85 70 13-166 20 30 Heptachlor epoxide ug/L ND 0.42 0.42 0.33 0.30 80 71 10-200 12 30 Methoxychlor ug/L ND 1.2 1.2 1.2 1.0 97 81 10-200 17 30 Decachlorobiphenyl (S) % 90 73 10-200 Tetrachloro-m-xylene (S) % 86 69 10-182 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 767213 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639003 METHOD BLANK: 3983526 Matrix: Water Associated Lab Samples: 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.21 04/12/23 20:18 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.23 04/12/23 20:18 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.23 04/12/23 20:18 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.25 04/12/23 20:18 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.29 04/12/23 20:18 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.21 04/12/23 20:18 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.16 04/12/23 20:18 Decachlorobiphenyl (S) % 124 10-193 04/12/23 20:18 LABORATORY CONTROL SAMPLE: 3983527 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.8 95 34-137 PCB-1260 (Aroclor 1260) ug/L 5 5.0 99 39-145 Decachlorobiphenyl (S) % 82 10-193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3983528 3983529 MS MSD 92659639003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 9.1 9.1 10.3 6.3 113 69 10-153 48 30 R1 PCB-1260 (Aroclor 1260) ug/L ND 9.1 9.1 9.3 42.6 103 469 10-156 128 30 M1,R1 Decachlorobiphenyl (S) % 107 99 10-193 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 768105 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639001, 92659639002 METHOD BLANK: 3987883 Matrix: Water Associated Lab Samples: 92659639001, 92659639002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.21 04/17/23 09:16 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.23 04/17/23 09:16 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.23 04/17/23 09:16 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.25 04/17/23 09:16 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.29 04/17/23 09:16 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.21 04/17/23 09:16 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.16 04/17/23 09:16 Decachlorobiphenyl (S) % 113 10-193 04/17/23 09:16 LABORATORY CONTROL SAMPLE: 3987884 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.6 91 34-137 PCB-1260 (Aroclor 1260) ug/L 5 4.5 90 39-145 Decachlorobiphenyl (S) % 122 10-193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3987885 3987886 MS MSD 92660170001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 8.3 8.3 8.7 8.4 104 101 10-153 3 30 PCB-1260 (Aroclor 1260) ug/L ND 8.3 8.3 7.6 7.7 91 92 10-156 1 30 Decachlorobiphenyl (S) % 106 86 10-193 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765677 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 3975539 Matrix: Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 4.5 04/06/23 10:15 1,3,5-Trinitrobenzene ug/L ND 10.0 5.5 04/06/23 10:15 1,3-Dinitrobenzene ug/L ND 10.0 3.8 04/06/23 10:15 1,4-Naphthoquinone ug/L ND 5.0 4.4 04/06/23 10:15 1-Naphthalenamine ug/L ND 10.0 6.0 04/06/23 10:15 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.2 04/06/23 10:15 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.5 04/06/23 10:15 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 04/06/23 10:15 2,4,6-Trichlorophenol ug/L ND 10.0 1.6 04/06/23 10:15 2,4-Dichlorophenol ug/L ND 10.0 1.4 04/06/23 10:15 2,4-Dimethylphenol ug/L ND 10.0 1.7 04/06/23 10:15 2,4-Dinitrophenol ug/L ND 50.0 26.0 04/06/23 10:15 2,4-Dinitrotoluene ug/L ND 10.0 1.6 04/06/23 10:15 2,6-Dichlorophenol ug/L ND 10.0 4.2 04/06/23 10:15 2,6-Dinitrotoluene ug/L ND 10.0 1.7 04/06/23 10:15 2-Acetylaminofluorene ug/L ND 10.0 4.1 04/06/23 10:15 2-Chloronaphthalene ug/L ND 10.0 1.7 04/06/23 10:15 2-Chlorophenol ug/L ND 10.0 1.2 04/06/23 10:15 2-Methylnaphthalene ug/L ND 10.0 1.9 04/06/23 10:15 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.9 04/06/23 10:15 2-Naphthalenamine ug/L ND 10.0 5.4 04/06/23 10:15 2-Nitroaniline ug/L ND 20.0 3.0 04/06/23 10:15 2-Nitrophenol ug/L ND 10.0 1.4 04/06/23 10:15 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 04/06/23 10:15 3,3'-Dichlorobenzidine ug/L ND 20.0 8.1 04/06/23 10:15 3,3'-Dimethylbenzidine ug/L ND 50.0 31.1 04/06/23 10:15 3-Methylcholanthrene ug/L ND 10.0 3.7 04/06/23 10:15 3-Nitroaniline ug/L ND 20.0 3.8 04/06/23 10:15 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 7.8 04/06/23 10:15 4-Aminobiphenyl ug/L ND 10.0 4.7 04/06/23 10:15 4-Bromophenylphenyl ether ug/L ND 10.0 1.8 04/06/23 10:15 4-ChIoro-3-methyl phenol ug/L ND 10.0 3.3 04/06/23 10:15 4-Chloroaniline ug/L ND 20.0 3.6 04/06/23 10:15 4-Chlorophenylphenyl ether ug/L ND 10.0 2.0 04/06/23 10:15 4-Nitroaniline ug/L ND 20.0 5.1 04/06/23 10:15 4-Nitrophenol ug/L ND 50.0 6.6 04/06/23 10:15 5-Nitro-o-toluidine ug/L ND 10.0 3.8 04/06/23 10:15 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 3.0 04/06/23 10:15 Acenaphthene ug/L ND 10.0 2.0 04/06/23 10:15 Acenaphthylene ug/L ND 10.0 2.0 04/06/23 10:15 v1 IH v1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 METHOD BLANK: 3975539 Matrix: Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Acetophenone ug/L ND 10.0 1.5 04/06/23 10:15 Anthracene ug/L ND 10.0 2.3 04/06/23 10:15 Benzo(a)anthracene ug/L ND 10.0 2.7 04/06/23 10:15 Benzo(a)pyrene ug/L ND 10.0 2.8 04/06/23 10:15 Benzo(b)fluoranthene ug/L ND 10.0 2.6 04/06/23 10:15 Benzo(g,h,i)perylene ug/L ND 10.0 2.8 04/06/23 10:15 Benzo(k)fluoranthene ug/L ND 10.0 2.7 04/06/23 10:15 Benzyl alcohol ug/L ND 20.0 2.9 04/06/23 10:15 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 04/06/23 10:15 bis(2-Chloroethyl) ether ug/L ND 10.0 1.9 04/06/23 10:15 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 3.7 04/06/23 10:15 Butylbenzylphthalate ug/L ND 10.0 3.1 04/06/23 10:15 Chlorobenzilate ug/L ND 10.0 3.8 04/06/23 10:15 Chrysene ug/L ND 10.0 2.8 04/06/23 10:15 Di-n-butylphthalate ug/L ND 10.0 2.2 04/06/23 10:15 Di-n-octylphthalate ug/L ND 10.0 3.9 04/06/23 10:15 Diallate ug/L ND 10.0 3.4 04/06/23 10:15 Dibenz(a,h)anthracene ug/L ND 10.0 3.0 04/06/23 10:15 Dibenzofuran ug/L ND 10.0 2.1 04/06/23 10:15 Diethylphthalate ug/L ND 10.0 2.0 04/06/23 10:15 Dimethoate ug/L ND 10.0 3.7 04/06/23 10:15 Dimethylphthalate ug/L ND 10.0 2.1 04/06/23 10:15 Diphenylamine ug/L ND 10.0 3.0 04/06/23 10:15 Disulfoton ug/L ND 10.0 4.6 04/06/23 10:15 Ethyl methanesulfonate ug/L ND 20.0 3.0 04/06/23 10:15 Famphur ug/L ND 10.0 6.1 04/06/23 10:15 Fluoranthene ug/L ND 10.0 2.2 04/06/23 10:15 Fluorene ug/L ND 10.0 2.1 04/06/23 10:15 Hexachlorobenzene ug/L ND 10.0 2.2 04/06/23 10:15 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 04/06/23 10:15 Hexachloroethane ug/L ND 10.0 1.4 04/06/23 10:15 Hexachloropropene ug/L ND 10.0 2.7 04/06/23 10:15 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 2.9 04/06/23 10:15 Isodrin ug/L ND 10.0 2.8 04/06/23 10:15 Isophorone ug/L ND 10.0 1.7 04/06/23 10:15 Isosafrole ug/L ND 10.0 2.5 04/06/23 10:15 Kepone ug/L ND 20.0 14.1 04/06/23 10:15 Methapyrilene ug/L ND 50.0 17.0 04/06/23 10:15 Methyl methanesulfonate ug/L ND 5.0 3.1 04/06/23 10:15 Methyl parathion ug/L ND 10.0 3.7 04/06/23 10:15 N-Nitroso-di-n-butylamine ug/L ND 10.0 2.0 04/06/23 10:15 N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 04/06/23 10:15 N-Nitrosodiethylamine ug/L ND 10.0 2.3 04/06/23 10:15 N-Nitrosodimethylamine ug/L ND 10.0 1.9 04/06/23 10:15 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 04/06/23 10:15 Qualifiers IH,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 76 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 METHOD BLANK: 3975539 Matrix: Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers N-Nitrosomethylethylamine ug/L ND 10.0 7.5 04/06/23 10:15 N-Nitrosopiperidine ug/L ND 10.0 2.5 04/06/23 10:15 N-Nitrosopyrrolidine ug/L ND 10.0 3.1 04/06/23 10:15 Nitrobenzene ug/L ND 10.0 1.9 04/06/23 10:15 O,O,O-Triethylphosphorothioate ug/L ND 10.0 2.6 04/06/23 10:15 O-Toluidine ug/L ND 10.0 2.6 04/06/23 10:15 P-Dimethylaminoazobenzene ug/L ND 5.0 2.4 04/06/23 10:15 IL p-Phenylenediamine ug/L ND 10.0 10.0 04/06/23 10:15 Parathion (Ethyl parathion) ug/L ND 10.0 3.9 04/06/23 10:15 Pentachlorobenzene ug/L ND 10.0 3.4 04/06/23 10:15 Pentachloronitrobenzene ug/L ND 10.0 3.3 04/06/23 10:15 Pentachlorophenol ug/L ND 20.0 3.8 04/06/23 10:15 Phenacetin ug/L ND 10.0 3.6 04/06/23 10:15 Phenanthrene ug/L ND 10.0 2.0 04/06/23 10:15 Phenol ug/L ND 10.0 1.4 04/06/23 10:15 Phorate ug/L ND 10.0 3.6 04/06/23 10:15 Pronamide ug/L ND 10.0 3.1 04/06/23 10:15 Pyrene ug/L ND 10.0 2.2 04/06/23 10:15 Safrole ug/L ND 10.0 2.3 04/06/23 10:15 Thionazin ug/L ND 10.0 2.9 04/06/23 10:15 2,4,6-Tribromophenol (S) % 109 10-164 04/06/23 10:15 2-Fluorobiphenyl (S) % 94 10-130 04/06/23 10:15 2-Fluorophenol (S) % 73 10-130 04/06/23 10:15 Nitrobenzene-d5 (S) % 95 10-138 04/06/23 10:15 Phenol-d6 (S) % 60 10-130 04/06/23 10:15 Terphenyl-d14 (S) % 103 19-191 04/06/23 10:15 LABORATORY CONTROL SAMPLE: Parameter 3975540 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L 50 37.4 75 10-130 1,3,5-Trinitrobenzene ug/L 50 36.6 73 55-200 v1 1,3-Dinitrobenzene ug/L 50 46.9 94 48-176 1,4-Naphthoquinone ug/L 50 35.5 71 18-130 1-Naphthalenamine ug/L 50 44.9 90 29-149 2,2'-Oxybis(1-chloropropane) ug/L 50 45.5 91 21-135 2,3,4,6-Tetrachlorophenol ug/L 50 56.6 113 39-157 2,4,5-Trichlorophenol ug/L 50 54.0 108 38-147 2,4,6-Trichlorophenol ug/L 50 54.4 109 34-142 2,4-Dichlorophenol ug/L 50 52.9 106 36-136 2,4-Dimethylphenol ug/L 50 82.1 164 38-134 L1 2,4-Dinitrophenol ug/L 250 188 75 10-169 2,4-Dinitrotoluene ug/L 50 54.8 110 44-154 2,6-Dichlorophenol ug/L 50 44.3 89 37-145 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: Parameter 3975540 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2,6-Dinitrotoluene ug/L 50 56.6 113 44-156 2-Acetylaminofluorene ug/L 50 48.7 97 25-175 2-Chloronaphthalene ug/L 50 49.8 100 25-130 2-Chlorophenol ug/L 50 49.2 98 29-130 2-Methylnaphthalene ug/L 50 48.1 96 23-130 2-Methylphenol(o-Cresol) ug/L 50 50.1 100 31-130 2-Naphthalenamine ug/L 50 42.9 86 34-147 2-Nitroaniline ug/L 100 103 103 39-145 2-Nitrophenol ug/L 50 54.2 108 29-142 3&4-Methyl phenol (m&p Cresol) ug/L 50 47.7 95 30-130 3,3'-Dichlorobenzidine ug/L 100 116 116 44-158 3,3'-Dimethylbenzidine ug/L 100 183 183 38-2001H 3-Methylcholanthrene ug/L 50 46.1 92 46-153 3-Nitroaniline ug/L 100 111 111 45-152 4,6-Dinitro-2-methyl phenol ug/L 100 114 114 39-158 v1 4-Aminobiphenyl ug/L 50 45.1 90 30-144 4-Bromophenylphenyl ether ug/L 50 51.8 104 47-147 4-Chloro-3-methylphenol ug/L 100 104 104 40-138 4-Chloroaniline ug/L 100 99.9 100 35-130 4-Chlorophenylphenyl ether ug/L 50 50.0 100 36-139 4-Nitroaniline ug/L 100 107 107 46-157 4-Nitrophenol ug/L 250 177 71 17-130 5-Nitro-o-toluidine ug/L 50 49.7 99 50-182 7,12-Dimethylbenz(a)anthracene ug/L 50 51.1 102 46-157 Acenaphthene ug/L 50 50.3 101 34-135 Acenaphthylene ug/L 50 51.5 103 35-137 Acetophenone ug/L 50 49.6 99 30-137 Anthracene ug/L 50 48.0 96 47-146 Benzo(a)anthracene ug/L 50 53.8 108 48-160 Benzo(a)pyrene ug/L 50 53.0 106 47-165 Benzo(b)fluoranthene ug/L 50 57.6 115 49-171 Benzo(g,h,i)perylene ug/L 50 51.5 103 46-166 Benzo(k)fluoranthene ug/L 50 53.3 107 55-162 Benzyl alcohol ug/L 100 95.0 95 29-132 bis(2-Chloroethoxy)methane ug/L 50 49.3 99 33-136 bis(2-Chloroethyl) ether ug/L 50 48.9 98 30-142 bis(2-Ethylhexyl)phthalate ug/L 50 58.5 117 46-173 Butylbenzylphthalate ug/L 50 61.6 123 53-169 Chlorobenzilate ug/L 50 48.9 98 43-155 Chrysene ug/L 50 52.8 106 54-152 Di-n-butylphthalate ug/L 50 52.8 106 49-161 Di-n-octylphthalate ug/L 50 60.5 121 50-166 Diallate ug/L 50 39.2 78 47-136 Dibenz(a,h)anthracene ug/L 50 53.3 107 46-166 Dibenzofuran ug/L 50 49.8 100 37-136 Diethylphthalate ug/L 50 52.2 104 45-149 Dimethoate ug/L 50 44.7 89 49-145 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 76 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: Parameter 3975540 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Dimethylphthalate ug/L 50 51.8 104 43-145 Diphenylamine ug/L 50 51.3 103 49-142 Disulfoton ug/L 50 38.6 77 42-130 Ethyl methanesulfonate ug/L 50 40.1 80 26-135 Famphur ug/L 100 61.6 62 10-130 Fluoranthene ug/L 50 51.6 103 50-153 Fluorene ug/L 50 51.3 103 42-142 Hexachlorobenzene ug/L 50 50.7 101 44-138 Hexachlorocyclopentadiene ug/L 50 51.0 102 10-130 Hexachloroethane ug/L 50 33.8 68 10-130 Hexachloropropene ug/L 50 32.3 65 10-130 Indeno(1,2,3-cd)pyrene ug/L 50 53.1 106 46-166 Isodrin ug/L 50 38.9 78 48-141 Isophorone ug/L 50 53.1 106 36-135 Isosafrole ug/L 50 42.4 85 33-135 Kepone ug/L 100 46.1 46 10-130 Methapyrilene ug/L 50 55.9 112 10-1851H,v1 Methyl methanesulfonate ug/L 50 38.8 78 21-130 Methyl parathion ug/L 50 46.2 92 57-173 N-Nitroso-di-n-butylamine ug/L 50 36.0 72 28-130 N-Nitroso-di-n-propylamine ug/L 50 54.0 108 33-140 N-Nitrosodiethylamine ug/L 50 45.4 91 27-141 N-Nitrosodimethylamine ug/L 50 44.6 89 24-130 N-Nitrosodiphenylamine ug/L 50 51.3 103 46-144 N-Nitrosomethylethylamine ug/L 50 41.2 82 22-141 N-Nitrosopiperidine ug/L 50 45.5 91 36-141 N-Nitrosopyrrolidine ug/L 50 45.3 91 31-145 Nitrobenzene ug/L 50 50.5 101 33-133 O,O,O-Triethylphosphorothioate ug/L 50 40.1 80 30-152 O-Toluidine ug/L 50 43.5 87 30-131 P-Dimethylaminoazobenzene ug/L 50 23.0 46 23-130IL p-Phenylenediamine ug/L ND Parathion (Ethyl parathion) ug/L 50 48.0 96 52-169 Pentachlorobenzene ug/L 50 39.6 79 31-136 Pentachloronitrobenzene ug/L 50 54.2 108 59-177 Pentachlorophenol ug/L 100 110 110 21-163 Phenacetin ug/L 50 47.5 95 52-159 Phenanthrene ug/L 50 50.9 102 47-146 Phenol ug/L 50 33.2 66 19-130 Phorate ug/L 50 42.6 85 35-184 Pronamide ug/L 50 47.6 95 53-155 Pyrene ug/L 50 55.8 112 53-155 Safrole ug/L 50 42.3 85 31-130 Thionazin ug/L 50 41.8 84 46-148 2,4,6-Tribromophenol (S) % 121 10-164 2-Fluorobiphenyl (S) % 98 10-130 2-Fluorophenol (S) % 76 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 LABORATORY CONTROL SAMPLE: 3975540 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrobenzene-d5 (S) % 104 10-138 Phenol-d6 (S) % 64 10-130 Terphenyl-d14 (S) % 114 19-191 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975541 3975542 MS MSD 92659539007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 83.3 83.3 78.2 73.8 94 89 12-130 6 30 1,3,5-Trinitrobenzene ug/L ND 83.3 83.3 83.7 83.2 100 100 34-200 0 30 v1 1,3-Dinitrobenzene ug/L ND 83.3 83.3 103 97.6 123 117 34-183 5 30 1,4-Naphthoquinone ug/L ND 83.3 83.3 81.3 73.0 98 88 14-136 11 30 1-Naphthalenamine ug/L ND 83.3 83.3 86.6 82.4 104 99 10-173 5 30 2,2'-Oxybis(1- ug/L ND 83.3 83.3 68.2 64.8 82 78 11-143 5 30 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 83.3 83.3 90.2 90.1 108 108 10-180 0 30 2,4,5-Trichlorophenol ug/L ND 83.3 83.3 88.3 89.4 106 107 10-170 1 30 2,4,6-Trichlorophenol ug/L ND 83.3 83.3 84.9 86.4 102 104 10-166 2 30 2,4-Dichlorophenol ug/L ND 83.3 83.3 82.8 81.4 99 98 10-153 2 30 2,4-Dimethylphenol ug/L ND 83.3 83.3 129 124 154 149 20-147 3 30 MO 2,4-Dinitrophenol ug/L ND 417 417 403 423 97 101 10-172 5 30 2,4-Dinitrotoluene ug/L ND 83.3 83.3 87.9 86.3 105 104 30-164 2 30 2,6-Dichlorophenol ug/L ND 83.3 83.3 92.9 86.2 112 103 10-161 8 30 2,6-Dinitrotoluene ug/L ND 83.3 83.3 90.9 88.6 109 106 31-163 3 30 2-Acetylam inofl uorene ug/L ND 83.3 83.3 87.2 96.6 105 116 20-166 10 30 2-Chloronaphthalene ug/L ND 83.3 83.3 75.5 76.2 91 91 15-134 1 30 2-Chlorophenol ug/L ND 83.3 83.3 73.3 72.7 88 87 10-139 1 30 2-Methyl naphthalene ug/L ND 83.3 83.3 74.6 71.9 90 86 12-130 4 30 2-Methyl phenol(o-Cresol) ug/L ND 83.3 83.3 74.4 74.4 89 89 19-132 0 30 2-Naphthalenamine ug/L ND 83.3 83.3 89.3 86.4 107 104 10-164 3 30 2-Nitroaniline ug/L ND 167 167 163 160 98 96 23-154 1 30 2-Nitrophenol ug/L ND 83.3 83.3 84.0 83.4 101 100 10-159 1 30 3&4-Methylphenol(m&p ug/L ND 83.3 83.3 71.4 70.1 86 84 13-136 2 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 167 167 175 174 105 104 10-178 1 30 3,3'-Dimethylbenzidine ug/L ND 167 167 294 290 176 174 10-200 1 30 IH 3-Methylcholanthrene ug/L ND 83.3 83.3 96.8 93.2 116 112 36-158 4 30 3-Nitroaniline ug/L ND 167 167 179 173 107 104 20-166 3 30 4,6-Dinitro-2-methylphenol ug/L ND 167 167 179 186 108 112 10-187 4 30 v1 4-Aminobiphenyl ug/L ND 83.3 83.3 64.6 71.6 78 86 10-181 10 30 4-Bromophenylphenyl ether ug/L ND 83.3 83.3 78.2 81.9 94 98 31-157 5 30 4-Chloro-3-methylphenol ug/L ND 167 167 166 162 99 97 27-146 2 30 4-Chloroaniline ug/L ND 167 167 149 146 89 87 13-143 2 30 4-Chlorophenylphenyl ether ug/L ND 83.3 83.3 76.6 78.0 92 94 23-149 2 30 4-Nitroaniline ug/L ND 167 167 173 163 104 98 24-171 6 30 4-Nitrophenol ug/L ND 417 417 302 296 72 71 10-130 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975541 MS 92659539007 Spike Parameter Units Result Conc. MSD Spike Conc. 3975542 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 5-Nitro-o-toluidine ug/L ND 83.3 83.3 111 100 133 120 33-192 10 30 7,12- ug/L ND 83.3 83.3 108 105 129 127 36-161 2 30 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 83.3 83.3 78.0 78.1 94 94 21-147 0 30 Acenaphthylene ug/L ND 83.3 83.3 78.1 78.7 94 94 19-150 1 30 Acetophenone ug/L ND 83.3 83.3 74.7 73.5 90 88 22-145 2 30 Anthracene ug/L ND 83.3 83.3 73.4 75.2 88 90 36-152 2 30 Benzo(a)anth race ne ug/L ND 83.3 83.3 81.4 82.9 98 100 42-163 2 30 Benzo(a)pyrene ug/L ND 83.3 83.3 81.0 81.6 97 98 40-169 1 30 Benzo(b)fluoranthene ug/L ND 83.3 83.3 89.0 90.8 107 109 40-177 2 30 Benzo(g,h,i)perylene ug/L ND 83.3 83.3 80.2 77.5 96 93 38-174 3 30 Benzo(k)fluoranthene ug/L ND 83.3 83.3 81.4 83.7 98 100 41-171 3 30 Benzyl alcohol ug/L ND 167 167 143 142 86 85 18-141 1 30 bis(2- ug/L ND 83.3 83.3 76.7 73.8 92 89 19-146 4 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 83.3 83.3 73.4 71.2 88 85 19-151 3 30 bis(2- Ethyl hexyl)phthalate ug/L ND 83.3 83.3 87.3 91.1 105 109 42-168 4 30 Butylbenzylphthalate ug/L ND 83.3 83.3 92.6 97.4 111 117 42-177 5 30 Chlorobenzilate ug/L ND 83.3 83.3 117 102 141 122 36-158 14 30 Chrysene ug/L ND 83.3 83.3 79.3 80.9 95 97 43-159 2 30 Di-n-butylphthalate ug/L ND 83.3 83.3 81.8 82.3 98 99 42-160 1 30 Di-n-octylphthalate ug/L ND 83.3 83.3 92.8 92.8 111 111 42-171 0 30 Diallate ug/L ND 83.3 83.3 79.5 80.0 95 96 38-139 1 30 Dibenz(a,h)anthracene ug/L ND 83.3 83.3 82.6 80.3 99 96 40-171 3 30 Dibenzofuran ug/L ND 83.3 83.3 76.4 77.1 92 92 23-147 1 30 Diethylphthalate ug/L ND 83.3 83.3 83.7 81.0 100 97 33-157 3 30 Dimethoate ug/L ND 83.3 83.3 95.8 91.0 115 109 41-146 5 30 Dimethylphthalate ug/L ND 83.3 83.3 81.7 80.9 98 97 27-154 1 30 Diphenylamine ug/L ND 83.3 83.3 77.4 80.6 93 97 38-146 4 30 Disulfoton ug/L ND 83.3 83.3 80.1 78.9 96 95 39-130 1 30 Ethyl methanesulfonate ug/L ND 83.3 83.3 84.9 79.9 102 96 25-136 6 30 Famphur ug/L ND 167 167 85.1 85.1 51 51 10-130 0 30 Fluoranthene ug/L ND 83.3 83.3 79.3 78.6 95 94 42-157 1 30 Fluorene ug/L ND 83.3 83.3 80.4 80.6 96 97 25-155 0 30 Hexachlorobenzene ug/L ND 83.3 83.3 77.6 80.5 93 97 32-145 4 30 Hexachlorocyclopentadiene ug/L ND 83.3 83.3 77.5 76.9 93 92 10-130 1 30 Hexachloroethane ug/L ND 83.3 83.3 45.1 44.9 54 54 10-130 0 30 Hexachloropropene ug/L ND 83.3 83.3 73.4 64.3 88 77 10-130 13 30 Indeno(1,2,3-cd)pyrene ug/L ND 83.3 83.3 82.2 80.4 99 97 39-174 2 30 Isodrin ug/L ND 83.3 83.3 83.1 80.6 100 97 34-148 3 30 Isophorone ug/L ND 83.3 83.3 81.4 78.9 98 95 19-146 3 30 Isosafrole ug/L ND 83.3 83.3 90.6 85.6 109 103 25-139 6 30 Kepone ug/L ND 167 167 103 92.5 62 55 10-130 11 30 Methapyrilene ug/L ND 83.3 83.3 ND 36.1J 18 43 10-200 30 IH,v1 Methyl methanesulfonate ug/L ND 83.3 83.3 80.5 76.0 97 91 22-130 6 30 Methyl parathion ug/L ND 83.3 83.3 102 98.7 122 118 48-174 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975541 3975542 MS MSD 92659539007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual N-Nitroso-di-n-butylamine ug/L ND 83.3 83.3 75.3 71.7 90 86 19-130 5 30 N-Nitroso-di-n-propylamine ug/L ND 83.3 83.3 81.1 79.1 97 95 20-150 2 30 N-Nitrosodiethylamine ug/L ND 83.3 83.3 94.9 86.8 114 104 27-140 9 30 N-Nitrosodimethylamine ug/L ND 83.3 83.3 65.9 65.4 79 79 13-130 1 30 N-Nitrosodiphenylamine ug/L ND 83.3 83.3 77.4 80.6 93 97 33-149 4 30 N-Nitrosomethylethylamine ug/L ND 83.3 83.3 83.8 73.8 101 89 22-144 13 30 N-Nitrosopiperidine ug/L ND 83.3 83.3 97.8 90.3 117 108 31-144 8 30 N-Nitrosopyrrolidine ug/L ND 83.3 83.3 92.4 88.2 111 106 27-146 5 30 Nitrobenzene ug/L ND 83.3 83.3 76.3 74.5 92 89 19-145 2 30 0,0,0- ug/L ND 83.3 83.3 86.4 80.2 104 96 25-138 7 30 Triethylphosphorothioate O-Toluidine ug/L ND 83.3 83.3 84.2 80.8 101 97 24-133 4 30 P- ug/L ND 83.3 83.3 47.2 48.8 57 59 17-130 3 30 IL Dimethylaminoazobenzene p-Phenylenediamine ug/L ND ND ND 30 Parathion (Ethyl parathion) ug/L ND 83.3 83.3 104 99.3 125 119 46-168 5 30 Pentachlorobenzene ug/L ND 83.3 83.3 84.0 79.7 101 96 28-140 5 30 Pentachloronitrobenzene ug/L ND 83.3 83.3 111 108 133 130 46-177 2 30 Pentachlorophenol ug/L ND 167 167 181 182 108 109 10-188 1 30 Phenacetin ug/L ND 83.3 83.3 102 97.1 123 116 41-167 5 30 Phenanthrene ug/L ND 83.3 83.3 76.6 78.4 92 94 38-150 2 30 Phenol ug/L ND 83.3 83.3 48.3 49.7 58 60 10-130 3 30 Phorate ug/L ND 83.3 83.3 87.3 87.2 105 105 36-176 0 30 Pronamide ug/L ND 83.3 83.3 101 98.2 121 118 43-159 3 30 Pyrene ug/L ND 83.3 83.3 83.3 88.8 100 107 42-163 6 30 Safrole ug/L ND 83.3 83.3 86.4 79.6 104 96 26-134 8 30 Thionazin ug/L ND 83.3 83.3 94.6 87.7 113 105 37-152 8 30 2,4,6-Tribromophenol (S) % 102 107 10-164 2-Fluorobiphenyl (S) % 84 83 10-130 2-Fluorophenol (S) % 63 62 10-130 Nitrobenzene-d5 (S) % 89 86 10-138 Phenol-d6 (S) % 52 53 10-130 Terphenyl-d14 (S) % 94 100 19-191 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 766385 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: 3979186 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 04/06/23 17:11 LABORATORY CONTROL SAMPLE: 3979187 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 51400 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979189 3979190 MS MSD 92659639004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 163000 50000 50000 218000 222000 110 117 80-120 2 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979191 3979192 MS MSD 92659666001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 96700 50000 50000 154000 155000 114 116 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 76 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765313 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: 3973916 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit Total Dissolved Solids mg/L ND 25.0 LABORATORY CONTROL SAMPLE: 3973917 Spike LCS Parameter Units Conc. Result Total Dissolved Solids mg/L 251 264 SAMPLE DUPLICATE: 3973918 92659509001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 189 184 MDL Analyzed Qualifiers 25.0 03/31 /23 19:53 LCS % Rec % Rec Limits Qualifiers 105 90-110 Max RPD RPD Qualifiers 3 25 SAMPLE DUPLICATE: 3973919 92659750001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids mg/L 61.0 66.0 8 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765654 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 3975496 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 22.0 04/04/23 02:39 LABORATORY CONTROL SAMPLE: 3975497 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 508 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975498 3975499 MS MSD 92659613002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 491 491 97 97 80-120 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975500 3975501 MS MSD 92659613003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 486 511 97 102 80-120 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765128 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: 3972863 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 03/31/23 21:12 LABORATORY CONTROL SAMPLE: 3972864 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 52400 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972865 3972866 MS MSD 92659779003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 1.0 mg/L 50000 50000 53100 53400 104 105 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972867 3972868 MS MSD 92659639002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 47700 50000 50000 99900 95300 104 95 90-110 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765066 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 3972661 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 03/31/23 03:17 LABORATORY CONTROL SAMPLE: 3972662 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1440 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972663 3972664 MS MSD 92659588003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 2.5 mg/L 1500 1500 3920 3970 96 100 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3972665 3972666 MS MSD 92659588009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 4.8 mg/L 1500 1500 6220 6840 93 135 90-110 10 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 766156 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 METHOD BLANK: 3977938 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003, 92659639004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 04/05/2318:48 LABORATORY CONTROL SAMPLE: 3977939 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 21000 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977940 3977941 MS MSD 92659399002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 48.7 mg/L 10000 10000 57400 58000 87 93 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977942 3977943 MS MSD 92659463001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 78.8 mg/L 10000 10000 86800 86800 80 80 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 76 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 QC Batch: 765550 Analysis Method: SM 4500-CN-E-2016 QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92659639001, 92659639002, 92659639003 METHOD BLANK: 3975100 Matrix: Water Associated Lab Samples: 92659639001, 92659639002, 92659639003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide ug/L ND 8.0 6.0 04/03/23 21:49 LABORATORY CONTROL SAMPLE: 3975101 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide ug/L 100 103 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975102 3975103 MS MSD 92659555001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L ND 100 100 97.8 102 98 102 80-120 4 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975104 3975105 MS MSD 92659555002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L ND 100 100 89.7 87.6 89 87 80-120 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. WORKORDER QUALIFIERS WO: 92659639 [1] ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H1 Analysis conducted outside the EPA method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 76 Pace Analytical Services, LLC ceAnalytrcal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: GM1.004 OXFORD LANDFILL UNIT 1 Pace Project No.: 92659639 ANALYTE QUALIFIERS P9 RPD between the primary and confirmatory analysis exceeded 40%. R1 RPD value was outside control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GM1.004 OXFORD 92659639 LANDFILL UNIT 1 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92659639001 MW-5R 8151A 2034529 EPA 8151A 2034529 92659639002 MW-7 8151A 2034529 EPA 8151A 2034529 92659639003 FIELD BLANK UNIT 1 8151A 2034529 EPA 8151A 2034529 92659639001 MW-5R EPA 3510C 766042 EPA 8081 B 766417 92659639002 MW-7 EPA 3510C 766042 EPA 8081 B 766417 92659639003 FIELD BLANK UNIT 1 EPA 3510C 766042 EPA 8081 B 766417 92659639001 MW-5R EPA 3510C 768105 EPA 8082A 768338 92659639002 MW-7 EPA 3510C 768105 EPA 8082A 768338 92659639003 FIELD BLANK UNIT 1 EPA 3510C 767213 EPA 8082A 767466 92659639001 MW-5R RSK-175 763417 92659639002 MW-7 RSK-175 763417 92659639003 FIELD BLANK UNIT 1 RSK-175 763417 92659639001 MW-5R 3015 2034556 EPA6010D 2034556 92659639002 MW-7 3015 2034556 EPA6010D 2034556 92659639003 FIELD BLANK UNIT 1 3015 2034556 EPA6010D 2034556 92659639004 MW-3RR 3015 2034556 EPA6010D 2034556 92659639001 MW-5R 3015 2034561 EPA6020B 2034561 92659639002 MW-7 3015 2034561 EPA6020B 2034561 92659639003 FIELD BLANK UNIT 1 3015 2034561 EPA6020B 2034561 92659639004 MW-3RR 3015 2034561 EPA 6020B 2034561 92659639001 MW-5R 7470A 2034660 EPA 7470A 2034660 92659639002 MW-7 7470A 2034660 EPA 7470A 2034660 92659639003 FIELD BLANK UNIT 1 7470A 2034660 EPA 7470A 2034660 92659639004 MW-3RR 7470A 2035866 EPA 7470A 2035866 92659639001 MW-5R EPA 3510C 765677 EPA 8270E 766258 92659639002 MW-7 EPA 3510C 765677 EPA 8270E 766258 92659639003 FIELD BLANK UNIT 1 EPA 3510C 765677 EPA 8270E 766258 92659639004 MW-3RR EPA 8260D 765937 92659639001 MW-5R EPA 8260D Mod. 765904 92659639002 MW-7 EPA 8260D Mod. 765904 92659639003 FIELD BLANK UNIT 1 EPA 8260D Mod. 765904 92659639004 MW-3RR EPA 8260D Mod. 765904 92659639005 TRIP BLANK EPA 8260D Mod. 765904 92659639001 MW-5R EPA 8260D 765322 92659639002 MW-7 EPA 8260D 765322 92659639003 FIELD BLANK UNIT 1 EPA 8260D 765322 92659639005 TRIP BLANK EPA 8260D 765322 92659639001 MW-5R SM 2320B-2011 766385 92659639002 MW-7 SM 2320B-2011 766385 92659639003 FIELD BLANK UNIT 1 SM 2320E-2011 766385 92659639004 MW-3RR SM 2320B-2011 766385 92659639001 MW-5R SM 2540C-2015 765313 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/24/2023 01:13 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 76 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: GM1.004 OXFORD 92659639 LANDFILL UNIT 1 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92659639002 MW-7 SM 2540C-2015 765313 92659639003 FIELD BLANK UNIT 1 SM 2540C-2015 765313 92659639004 MW-3RR SM 2540C-2015 765313 92659639001 MW-5R SM 4500-S2D-2011 765654 92659639002 MW-7 SM 4500-S2D-2011 765654 92659639003 FIELD BLANK UNIT 1 SM 4500-S2D-2011 765654 92659639001 MW-5R EPA 300.0 Rev 2.1 1993 765128 92659639002 MW-7 EPA 300.0 Rev 2.1 1993 765128 92659639003 FIELD BLANK UNIT 1 EPA 300.0 Rev 2.1 1993 765128 92659639004 MW-3RR EPA 300.0 Rev 2.1 1993 765128 92659639001 MW-5R EPA 353.2 Rev 2.0 1993 765066 92659639002 MW-7 EPA 353.2 Rev 2.0 1993 765066 92659639003 FIELD BLANK UNIT 1 EPA 353.2 Rev 2.0 1993 765066 92659639001 MW-5R SM 4500-CI-E-2011 766156 92659639002 MW-7 SM 4500-CI-E-2011 766156 92659639003 FIELD BLANK UNIT 1 SM 4500-CI-E-2011 766156 92659639004 MW-3RR SM 4500-CI-E-2011 766156 92659639001 MW-5R SM 4500-CN-E-2016 765550 SM 4500-CN-E-2016 765649 92659639002 MW-7 SM 4500-CN-E-2016 765550 SM 4500-CN-E-2016 765649 92659639003 FIELD BLANK UNIT 1 SM 4500-CN-E-2016 765550 SM 4500-CN-E-2016 765649 Date: 05/24/2023 01:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 76 DC#Title: ENV-=FRM. HUNT- '083.vO; ample Canditlah U06 Floc#Ipt Eiiectiv`e 4411p. 3 ,X4j ► 18: ti,'. M ta-bomtory r!?cocing�siimpl6m, silQvtge xdt-n-cl Gre :pr�taI) 'f-uift9: sville [] [tateigh0 M ltg icsvitleQ. tl�ntal Ker+tie sville ] Cfient Name..: ....:.. ....... _ _. ,_:..: �-�,iother:_0. IWI4II# �I II9I�2� I 6I !�5� �9�� 639lbSPe$u.'r El Cmmertia: EWdCe. 92659639 tvii ly Self Present? r ❑Na Seals Intact7" 'EWS .Yes [,�.Nsi .. • date/IniEiai; PBksoA OPM46000O'ent',_e� , .C}f� . PakittgfatRteClal; $lyla'Wpbble:.tgs ❑N.orte :(]than ajofoglcalTfcsuEFroal�n? Theji*om OYas..dtJb WoferTsrrn� .. . �G r'� �i4ddj5uhiiett (°�} CaoterTerriR-CW'+®.d ('Cr. ''?.� t�i.� .�•�a.... ., USDA ttegi�f�atedr�5oi . � ::.. �W(Ar water sample j.: � � . Dld samples:arigindte:its a_quarantlnsa.. zonewIthlo theitinfiid;Siates: CA, 1A ©r sc ]Blue �Npr<e . 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Up YI 5 a s S113NIVINOO d0 p LL 9 ' N'L173110aIVdPI3131dViVS p� qq W Z F 3 m c c3 N lu LU n �, w id��evu�n] 3dAia7dwv9 �� ' ipalgss�cs�enees) 3d07XIULtlW IL p 9t " a gosda}a"aok 5I jLd2 SI A W . � CL Jog ►�R t `j 4C roNz FIR U?o o � � � � � ,�'" � • � � � � 7r of 76 a Q # IIV311Lu ANSI 9� a a �� Appendix C Summary of Historical Groundwater Elevations 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix C Summary of Historical Groundwater Elevations Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Groundwater Elevations (ft AMSL) Date Background Downgradient Performance/Sentinel MW-1 MW-1A MW-7 MW-2 MW-3RR' MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-21D 09/10/99 101.71 517.91 -- 507.76 481.40 493.62 467.65 496.53 -- -- -- 11 /16/99 105.76 522.86 -- 506.32 483.55 494.83 468.75 498.24 -- -- -- 05/10/00 109.47 527.66 -- 507.89 487.20 499.63 470.65 500.59 -- -- -- - 10/26/00 103.54 518.89 -- 504.12 480.86 495.21 467.39 496.95 -- -- -- -- 04/18/01 107.87 526.23 -- 508.01 486.62 498.50 470.79 500.21 -- -- -- -- 10/27/01 -- 514.65 -- 501.42 478.79 494.79 466.70 494.92 -- -- -- - 06/10/02 -- 515.06 -- 502.91 480.10 495.19 467.06 496.26 -- -- -- -- 11 /19/02 -- 518.61 -- 512.08 489.84 498.82 471.80 498.70 -- -- -- -- 06/27/03 -- 529.42 -- 508.76 488.69 500.79 471.72 501.38 -- -- -- -- 12/29/03 -- 528.91 -- 509.06 488.06 499.94 471.10 501.21 -- -- -- -- 06/29/04 -- 520.03 -- 505.24 481.10 497.84 467.72 499.21 -- -- -- -- 12/28/04 -- 526.73 -- 509.09 485.27 499.14 469.51 500.76 -- -- -- -- 06/29/05 -- 520.37 -- 504.64 481.10 497.60 467.63 499.15 -- -- -- -- 12/29/05 -- 519.54 -- 509.66 482.69 498.33 468.57 499.25 -- -- -- -- 06/27/06 -- 517.93 - 507.85 481.85 497.64 468.00 498.63 -- -- -- -- 12/27/06 -- 523.00 -- 511.07 489.81 499.43 471.76 500.83 493.70 -- 469.82 -- 07/12/07 -- 516.94 -- 502.49 479.84 497.17 467.18 497.59 -- -- -- -- 12/18/07 -- 510.35 -- 501.46 477.54 495.40 464.09 493.14 -- -- -- -- 07/07/08 -- 515.96 -- 501.99 479.52 497.04 466.79 496.71 -- -- -- -- 12/16/08 -- 532.53 - 509.80 487.98 498.08 470.11 499.29 489.19 488.63 469.47 472.71 07/07/09 -- 518.28 -- 505.37 481.57 497.43 467.88 499.36 490.38 490.07 467.73 470.91 12/14/09 -- 533.10 -- 511.89 491.93 500.61 473.65 501.48 494.70 493.21 470.98 467.14 06/22/10 -- 518.45 -- 506.72 485.92 499.94 469.67 499.68 493.47 493.07 468.97 471.53 12/13/10 -- 509.41 -- 507.89 482.82 498.20 467.87 496.65 488.89 -- 468.03 -- 06/20/11 -- 515.17 513.91 504.60 482.72 499.96 467.76 498.63 492.11 491.51 468.03 474.35 12/05/11 -- 513.35 507.92 507.44 484.94 498.29 468.45 497.17 488.15 487.45 468.25 464.93 06/13/12 -- 514.08 513.48 507.48 485.36 499.29 468.04 498.85 487.08 490.33 468.81 467.64 12/12/12 -- 511.34 506.86 503.10 481.55 497.24 466.90 494.83 486.84 486.26 467.26 461.41 04/29/13 -- 515.88 513.26 509.38 485.47 500.82 469.60 501.15 492.31 491.64 470.45 455.26 08/05/13 -- 517.21 514.33 505.98 484.47 500.29 468.65 500.83 494.12 -- 469.29 -- 02/25/14 -- 514.06 511.75 509.82 486.32 501.50 473.05 501.99 491.83 491.54 470.28 461.18 08/12/14 -- 519.34 511.98 507.52 485.44 499.25 468.90 499.30 491.92 491.41 470.29 460.31 03/11/15 -- 524.32 516.39 510.37 487.12 502.94 474.18 504.41 500.98 500.12 470.63 473.63 08/18/15 -- 516.53 512.39 503.47 482.97 500.94 466.45 498.81 492.38 -- 469.25 449.71 02/16/16 -- 526.03 515.79 510.07 486.93 501.84 475.45 503.66 500.23 -- 471.15 469.18 08/10/16 -- 520.07 514.29 507.08 484.07 500.34 468.20 500.89 491.95 - 470.40 453.23 02/14/17 -- 524.14 510.89 507.72 484.44 500.34 468.86 501.06 491.73 468.85 453.13 08/23/17 -- 523.08 508.84 506.59 482.82 497.02 467.19 498.16 491.68 - 469.80 452.94 02/06/18 -- 522.73 505.74 507.91 485.62 498.54 468.25 500.31 491.78 471.40 470.93 08/14/18 -- 514.72 510.22 504.44 484.15 498.36 467.48 498.66 -- -- 470.81 474.46 02/05/19 -- 529.50 515.74 509.70 488.03 502.08 472.38 503.41 472.18 475.98 08/07/19 -- 517.02 512.11 503.93 484.68 498.37 467.68 499.01 - 472.31 475.33 02/12/20 -- -- 511.37 510.52 488.77 500.56 473.66 501.32 - -- 472.76 -- 02/12/20 -- -- - 510.52 488.77 -- -- -- -- -- -- -- 02/13/20 -- -- -- -- 500.56 -- 501.32 -- -- -- -- 02/14/20 -- -- 511.37 -- -- -- 473.66 -- - -- 472.76 -- 02/17/20 -- -- 511.73 -- -- - 472.68 -- 472.60 -- 03/19/20 -- -- 512.69 -- -- 469.45 -- - -- 471.82 -- 05/18/20 - -- 513.94 -- -- -- 469.60 -- 471.35 475.83 08/25/20 -- 512.24 507.82 487.29 498.99 -- 499.46 -- -- -- -- 08/26/20 -- 519.93 -- -- -- 477.37 - -- 472.25 473.78 09/29/20 -- -- - 508.90 488.08 -- -- -- -- -- -- -- 09/30/20 -- -- -- -- -- -- 472.08 -- -- -- 02/10/21 -- 533.68 517.28 511.01 489.88 502.51 474.72 503.79 -- 472.06 474.72 08/18/21 -- 517.68 511.96 504.72 485.57 498.55 467.86 499.16 - -- 471.20 -- 02/15/22 -- 517.67 507.49 506.51 486.60 498.23 468.10 497.75 -- 471.26 474.68 09/29/22 -- 512.19 507.47 501.07 484.72 495.95 466.55 495.11 -- 471.55 472.99 03/29/23 -- 531.71 510.71 1 509.59 1 489.23 498.28 1 470.06 1 499.76 -- 472.38 1 476.59 Notes: Groundwater elevations from September 1999 through February 2021 obtained from LaBella Associates Water Quality Monitoring Report - February 2021 Event. Groundwater elevations from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event. 1. Monitoring well MW-3RR was installed in September 2022 to replace abandoned monitoring well MW-3R. Data shown in the table prior to the September 2022 monitoring event for MW-3RR was collected from abandoned monitoring well MW-3R. ft AMSL = ft above mean sea level-, -- = not applicable Appendix C (Page 1 of 11) https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-004 - Granville Co. Oxford LF Unit 1/2023 First Half GWM/Tables/Oxford Unit 1 Historic Tables.xlsx Hart & Hickman, Pl, Appendix D Summary of Historical Constituents in Groundwater 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDI I MVI-I M--2 M--4. M--R M--.. N--M, NIE-D Inorganics Antimony 09/14/94 NO NO 12/02/94 NO NO NC2L=IWJL 02/08/95 NO NO 03/02/95 NO NO 11/17/95 NO NO 05/23/96 NO NO 11/14/96 NO NO 06/18/97 NO NO 12/02/97 --- --- NO NO 05/27/98 NO NO 11/16/98 NO NO 09/10/99 NO NO NO NO 11/16/99 NO NO NO NO 05/10/00 NO NO NO 68 10/26/00 NO NO NO NO 04/18/01 NO NO NO NO 10/27/01 NO NO NO NO 06/13/02 NO NO NO NO 11/19/02 NO NO ND NO 06/27/03 NO NO NO NO 12/30/03 NO NO NO NO 06/30/04 NO NO NO NO 12/29/04 NO NO NO NO 06/29/05 NO NO NO NO 12/29/05 NO NO NO NO 06/28/06 NO NO NO NO 12/28/06 NO NO NO NO 07/02/07 NO NO NO NO 12/19/07 NO NO NO NO 07/08/08 NO NO NO NO 12/16/08 2.6 NO NO NO NO 07/08/09 2.6 NO NO NO NO 12/15/09 2.6 NO NO NO NO 06/23/10 2.6 NO NO NO NO 12/14/10 2.6 NO NO NO NO 06/21/11 5 NO NO NO ND NO 12/06/11 5 NO NO NO NO NO 06/13/12 5 NO NO NO NO NO 12/11/12 5 NO NO NO NO NO 04/29/13 5 NO NO NO NO NO 08/06/13 5 NO NO NO NO NO 02/25/14 5 NO NO NO NO NO 08/13/14 5 NO NO NO NO NO 03/12/15 3.8 NO NO NO NO NO 08/19/15 3.8 NO NO NO NO NO 02/18/16 3.8 NO NO NO NO NO 08/11/16 3.8 NO NO NO ND NO 02/15/17 3.9 NO NO NO NO NO 08/24/17 3.9 NO NO NO NO NO 02/07/18 3.9 NO NO NO NO NO 08/15/18 3.9 NO NO NO NO NO 02/06/19 3.9 NO NO NO NO NO 08/08/19 3 NO NO NO ND NO 02/14/20 3 NO NO NO ND NO 08/26/20 3 NO NO NO NO NO NO 02/10/21 4.7 NO 5.7 1 NO NO 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 ") 3 NO NO NO NO NO NO NA NS 03/29/23 p) 4.3 NO NO NO NO NO NO NA NA Arsenic 09/14/94 NO NO 12/02/94 NO NO NC 2L - 10 µg/L 02/08/95 NO NO 03/02/95 NO NO 11/17/95 NO NO 05/23/96 NO NO 11/14/96 NO NO 06/18/97 14 5 12/02/97 NO NO 05/27/98 NO NO 11/16/98 12 6 09/10/99 NO NO NO 11 11/16/99 NO NO NO NO 05/10/00 NO NO NO NO 10/26/00 NO NO NO NO 04/18/01 NO NO ND NO 10/27/01 NO NO NO NO 06/13/02 NO NO NO NO 11/19/02 NO NO NO NO 06/27/03 NO NO NO NO 12/30/03 NO NO NO NO 06/30/04 NO NO ND NO 12/29/04 NO NO NO NO 06/29/05 NO NO NO NO 12/29/05 NO NO ND NO 06/28/06 NO NO ND NO 12/28/06 NO NO NO NO 07/12/07 4.9 1 NO NO NO 12/19/07 2.9 1 NO NO NO 07/08/08 3.7 1 NO NO NO 12/16/08 2.7 NO NO NO NO 07/08/09 2.7 NO NO 4.9 1 NO 12/15/09 2.7 3.2 1 NO NO NO 06/23/10 2.7 2.7 1 NO 5.2 1 NO 12/14/10 2.7 NO NO 4.4 1 NO 06/21/11 5 NO NO NO NO NO 12/06/11 5 NO NO NO NO NO 06/13/12 5 NO NO NO NO NO 12/11/12 5 NO NO NO ND NO 04/29/13 5 NO NO NO NO NO 08/06/13 5 NO NO NO NO NO 02/25/14 5 NO NO NO NO NO 08/13/14 5 NO NO NO NO NO 03/12/15 2.5 NO 5.5 1 2.9 1 3.8 1 NO 08/19/15 2.5 NO NO NO NO NO 02/18/16 2.5 NO NO NO NO NO 08/11/16 2.5 NO 3.5 1 NO 3.2 1 NO 02/15/17 5 NO ND NO ND NO 08/24/17 5 NO NO NO NO NO 02/07/18 5 NO ND NO ND NO 08/15/18 5 NO 5.3 1 NO NO NO 02/06/19 5 NO NO NO NO NO 08/08/19 4.7 NO 5.5 1 NO NO NO 02/14/20 4.7 NO NO NO 5.4 1 NO 08/25/20 4.7 NO 5.5 1 7.1 1 NO NO 02/10/21 4.3 NO NO NO 4.9 1 08/18/21 4.7 9 1 --- --- --- --- --- --- 08/19/21 4.7 6.3 1 --- --- --- --- 02/15/22 4.7 5.4 1 --- --- --- --- --- 09/29/22 (2) 4.7 NO NO NO NO NO NO NA NS 03/29/23 (3) 4.4 NO NO NO 6.32 J , NO ND NA NA Appendix D (Page 1 of 23) 1-0 1-1 Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-6R NES-2S NES-21) Barium 09/14/94 -- -- 260 -- -- -- 1,740 -- -- 12/02/94 ___ ___ ND ___ ___ ___ ND NC 2L=700 pg/L 02/08/95 -- --- NO -- -- -- NO --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 -- - NO -- -- -- NO --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 -- --- 600 --- --- -- 21 --- -- 06/18/97 --- --- 280 --- --- --- 700 --- --- 12/02/97 --- --- 150 --- --- --- 260 --- -- 05/27/98 --- --- 95 --- --- --- 350 --- --- 11/16/98 --- --- 4,800 --- --- _- 5,900 --- __ 09/10/99 --- --- ND NO ND ND --- --- --- 11/16/99 --- --- NO ND NO ND --- --- -- 05/10/00 --- --- ND NO ND ND --- --- --- 10/26/00 -- -- NO ND NO ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 10/27/01 --- -- NO ND NO ND -- --- -- 06/13/02 --- --- ND ND ND ND --- --- --- 11/19/02 --- -- NO ND NO ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- -- NO ND NO ND --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- -- NO ND NO ND --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- -- NO ND NO ND --- --- -- 06/28/06 --- --- ND ND NO ND --- --- --- 12/28/06 --- --- 30.8 24.8 78.5 33.4 -- --- -- 07/12/07 --- --- 13.8 1 24.5 J 82.5 1 27.3 J --- --- --- 12/19/07 --- --- 14.7 B 20.1 B 28.7 B 27.2 B --- --- -- 07/08/08 --- --- 21.7 1 19.6 J 54.1 1 35.3 1 --- --- --- 12/16/08 0.2 --- 11.2 B 16.5 B 27.0 B 38.8 B --- --- -- 07/08/09 0.2 --- 11.9 B 26.6 B 74.6 B 34.2 B --- --- --- 12/15/09 0.2 --- 16.4 B 18.8 B 38.2 B 39.8 B --- --- -- 06/23/10 0.2 --- 12.0 B 17.7 B 107 B 36.7 B --- --- --- 12/14/30 0.2 --- 11.7 B 26.8 B 37.6 B 46.1 B --- --- -- 06/21/11 5 6.8 1 14.6 J 18.6 1 37.2 J 41.7 1 --- --- --- 12/06/11 5 16.2 1 13.2 1 27.8 1 38.4 1 43.3 1 --- --- -- 06/13/12 5 9.2 1 16.5 J 20.4 1 52.2 J 39 1 --- --- --- 12/11/12 5 5.2 1 12.6 1 17.2 1 32.1 1 47.3 1 --- --- -- 04/29/13 5 ND 14.7 J 19.6 1 37.6 J 42.2 1 --- --- --- 08/06/13 5 NO 19.7 1 18.7 1 39.8 1 43.1 1 --- --- -- 02/25/14 5 5.6 1 15.3 J 52.7 1 38 J 48 1 --- --- --- 08/13/14 5 NO 19 1 28.4 1 37.7 1 49.6 1 --- --- -- 03/12/15 2.5 12.4 1 13.3 J 28 1 38.6 J 38.9 1 --- --- --- 08/19/15 2.5 4.9 1 17.5 1 25.3 1 36.2 1 42.2 1 --- --- -- 02/18/16 2.5 4.4 1 12.1 J 15.7 1 36.4 J 36.7 1 --- --- --- 08/11/16 2.5 3.9 1 22.4 1 16.1 1 42.1 1 38.6 1 --- --- -- 02/15/17 2.5 6.1 1 18.2 J 18.6 1 37.2 J 38.9 1 --- --- --- 08/24/17 2.5 11.1 1 18 1 17.1 1 30.9 1 43.1 1 --- --- -- 02/07/18 2.5 3.9 1 15.4 J 18 1 44.6 J 48.7 1 --- --- --- 08/15/18 2.5 3.8 1 21.7 J 16.6 1 39.9 1 41.6 1 --- --- -- 02/06/19 2.5 4 1 15.8 17.4 39.1 52.8 --- --- --- 08/08/19 1 4.5 1 25 32.2 39.3 44.1 --- --- -- 02/14/20 1 11 15.7 23 36.3 45.8 --- --- --- 08/25/20 --- 8.8 63 34.8 37 50.6 124 --- -- 02/10/21 4.7 4.7 1 ND --- --- ND ND --- --- 08/18/21 3.5 40 10.3 17.2 --- 39.9 142 --- -- O8/19/21 3.5 --- --- --- 46.5 --- --- --- --- 02/15/22 3.5 --- 12.5 23 --- --- 147 --- --- 02/16/22 3.5 --- --- --- 62.6 --- --- --- --- 02/17/22 3.5 -- --- --- --- 40.8 --- --- --- 09/29/22 ") 3.5 4.3 J 10.5 43.5 40.1 56 155 NA NS 03 29 23 p) 1 0.736 3.74 J 1 19.6 54.5 33.8 1 44.6 121 1 NA NA Beryllium 09/14/94 --- --- NO --- --- -- NO --- --- 12/02/94 ___ ___ ND ___ ___ .__ ND NC 2L=4 pg/L 02/08/95 --- --- NO --- --- -- NO --- -- 03/02/95 ___ ___ ND ___ ___ .__ ND 11/17/95 --- --- NO --- --- -- NO --- -- 05/23/96 ___ ___ ND ___ ___ ___ ND 11/14/96 --- --- NO --- -- -- NO --- -- 06/18/97 ___ ___ 3 ___ ___ ___ 3 12/02/97 --- --- NO --- __ _- 1 --- __ 05/27/98 ___ ___ 2 ___ ___ ___ 3 11/16/98 --- --- 2 --- --- _- 4 --- __ 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- NO ND NO NO -- --- -- 05/10/00 --- --- ND ND NO ND --- --- --- 10/26/00 --- --- NO ND NO NO -- --- -- 04/18/01 --- --- ND ND NO ND --- --- --- 10/27/01 --- --- NO ND NO NO -- --- -- 06/10/02 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- NO ND NO NO --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- --- NO ND NO NO -- --- -- 12/30/03 --- --- ND ND ND ND --- --- --- 06/30/04 --- --- NO ND NO NO --- --- -- 12/29/04 --- --- ND ND ND ND --- --- --- 06/29/05 --- --- NO ND NO NO -- --- -- 12/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- NO ND NO NO -- --- -- 12/28/06 --- --- ND ND ND ND --- --- --- 07/12/07 --- --- NO ND NO NO --- --- -- 12/19/07 --- --- ND ND ND ND --- --- --- 07/08/08 --- --- 0.14 1 0.1 1 NO NO -- --- -- 12/16/08 0.1 --- ND ND ND 0.18 1 --- --- --- 07/08/09 0.1 --- NO ND NO NO --- --- -- 12/15/09 0.1 --- ND ND NO ND --- --- --- 06/23/30 0.1 --- NO ND NO ND -- --- -- 12/14/10 0.1 --- NO ND ND ND --- --- --- 06/21/11 1 NO ND NO ND NO -- --- -- 12/06/11 1 ND ND ND ND ND --- --- --- 06/13/12 1 NO ND NO ND NO --- --- -- 12/11/12 1 ND ND ND ND ND --- --- --- 04/29/13 1 NO ND NO ND NO -- --- -- O8/06/13 1 ND ND ND ND ND --- --- --- 02/25/14 1 NO ND NO ND NO --- --- -- O8/13/14 1 ND ND ND ND ND --- --- --- 03/12/15 0.5 NO ND NO ND NO -- --- -- O8/19/15 0.5 ND ND ND ND ND --- --- --- 02/18/16 0.5 NO ND NO ND NO --- --- -- O8/11/16 0.5 ND ND ND ND ND --- --- --- 02/15/17 0.5 NO ND NO ND NO -- --- -- O8/24/17 0.5 ND ND ND ND ND --- --- --- 02/07/18 0.5 NO ND NO ND NO -- --- -- O8/15/18 0.5 ND ND ND ND ND --- --- --- 02/06/19 0.5 NO ND NO ND NO --- --- -- O8/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 0.2 NO 0.28 1 NO ND NO --- --- -- 08/25/20 0.7 ND ND ND ND ND --- --- --- 02/10/21 9.5 NO ND --- --- NO ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22(2) 0.7 NO ND ND ND ND ND NA NS 03 29 231a1 0.330 ND ND ND ND ND ND NA NA Appendix D (Page 2 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c -I. co. o,ra,a uF W„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Cadmium 09/14/94 -- -- NO -- -- -- 1 -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=2 pg/L 02/08/95 -- --- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 -- - NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 -- --- NO -- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ 3 12/02/97 __ --- NO --- --- __ NO 05/27/98 ___ ___ NO ___ ___ ___ 1 11/16/98 --- --- NO --- --- --- 4 --- __ 09/10/99 --- --- NO 1 NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- 2 2 NO NO --- --- -- 06/10/02 --- --- NO 3 NO NO --- --- --- 06/13/02 --- --- NO 3 NO NO -- --- -- 11/19/02 --- --- 3 2 NO 1 --- --- --- 06/27/03 --- --- NO NO NO NO --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO 1 NO NO -- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO --- --- -- 12/28/06 --- --- NO NO ND NO --- --- --- 07/12/07 --- --- NO NO ND NO -- --- -- 12/19/07 --- --- NO NO NO NO --- --- --- 07/08/08 --- --- NO NO NO NO --- --- -- 12/16/08 0.5 --- NO NO ND NO --- --- --- 07/08/09 0.5 --- NO NO ND NO -- --- -- 12/15/09 0.5 --- NO NO NO NO --- --- --- 06/23/10 0.5 --- NO NO NO NO --- --- -- 12/14/10 0.5 --- NO NO NO NO --- --- --- 06/21/11 1 NO NO NO NO NO -- --- -- 12/06/11 1 NO NO NO ND NO --- --- --- 06/13/12 1 NO NO NO ND NO --- --- -- 12/11/12 1 NO NO NO ND NO --- --- --- 04/29/13 1 NO NO NO NO NO -- --- -- 08/06/13 1 NO NO NO NO NO --- --- --- 02/25/14 1 NO NO NO NO NO --- --- -- 08/13/14 1 NO NO NO NO NO --- --- --- 03/12/15 0.5 NO NO NO NO NO -- --- -- 08/19/15 0.5 NO NO NO NO NO --- --- --- 02/38/16 0.5 NO NO NO NO NO -- --- -- 08/11/16 0.5 NO NO NO NO NO --- --- --- 02/15/17 0.5 NO NO NO NO NO --- --- -- 08/24/17 0.5 NO NO NO NO NO --- --- --- 02/07/18 0.5 NO NO NO NO NO -- --- -- 08/15/18 0.5 NO NO NO ND NO --- --- --- 02/06/19 0.5 NO NO NO ND NO -- --- -- 08/08/19 0.4 NO NO NO NO NO --- --- --- 02/14/20 0.4 NO NO NO NO NO --- --- -- 08/25/20 0.4 NO NO NO NO NO --- --- --- 02/30/21 0.29 NO --- --- NO NO 0.92 1 --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 0.4 --- --- --- --- --- 0.47 1 --- -- 09/29/22"1 0.4 <1.0 <1.0 0.55 1 <1.0 <1.0 <1.0 NA NS 03 29 231a1 0.479 NO NO NO NO NO NO NA NA Chromium 09/14/94 --- --- 91 --- --- -- 177 --- -- 12/02/94 ___ ___ 88 ___ ___ ___ 24 NC 2L=10 µg/L 02/08/95 --- --- 56 --- --- -- 19 --- -- 03/02/95 ___ ___ 66 ___ ___ ___ 10 11/17/95 --- -- 53 --- --- -- NO --- -- 05/23/96 ___ ___ 34 ___ ___ ___ NO 11/14/96 --- __ 8 --- --- __ 8 --- __ 06/18/97 --- --- 100 --- --- --- 83 --- --- 12/02/97 --- --- 14 --- --- __ 26 --- __ 05/27/98 ___ ___ 31 ___ ___ ___ 40 11/16/98 --- 130 --- --- -- 260 --- -- 09/10/99 --- --- NO 40 NO NO --- --- --- 11/16/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO ND NO NO --- --- --- 10/26/00 --- --- NO NO NO NO --- --- -- 04/18/01 --- --- NO 13 NO NO --- --- --- 10/27/01 --- 16 56 10 NO -- --- -- 06/10/02 --- --- NO 13 NO NO --- --- --- 06/13/02 --- --- NO 17 NO NO --- --- -- 11/19/02 --- --- 12 ND NO NO --- --- --- 06/27/03 --- 13 NO ND 37 --- --- -- 12/30/03 --- --- NO ND ND NO --- --- --- 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- NO ND NO NO --- --- --- 06/29/05 --- --- NO NO NO NO --- --- -- 12/29/05 --- --- NO ND NO NO --- --- --- 06/28/06 --- --- NO 67 NO NO -- --- -- 12/28/06 --- --- 8.9 1 NO NO NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- 2.4 1 2.5 1 NO 2.4 1 --- --- --- 07/08/08 --- --- 8 1 2.8 1 NO 1.8 1 --- --- -- 12/06/08 0.4 --- 2 1 3.2 1 NO 1.9 1 --- --- --- 07/08/09 0.4 --- 3.3 1 7.2 1 NO 0.86 1 --- --- -- 12/15/09 0.4 --- 4.6 1 3.6 1 NO 0.64 1 --- --- --- 06/23/30 0.4 --- 4.1 1 2.6 B 0.9 B 1.3 B --- --- -- Resample 08/12/10 0.4 --- --- --- --- --- --- --- --- 12/14/30 0.4 --- 2.8 1 9.1 1 1 1 1.2 1 --- --- -- 06/21/11 5 NO NO NO NO NO --- --- --- 12/06/11 5 NO NO 11.6 NO NO --- --- -- Resample O1/25/12 5 --- --- 6.1 1 --- --- --- --- --- 06/13/12 5 NO 5.1 1 7.5 1 NO NO --- --- -- 12/11/12 5 NO NO NO NO NO --- --- --- 04/29/13 5 NO NO NO NO NO --- --- -- 08/06/13 5 NO 7.4 1 NO NO NO --- --- --- 02/25/14 5 NO NO 19.6 NO NO -- --- -- 08/13/14 5 NO 6.1 1 6.6 1 NO NO --- --- --- 03/12/15 2.5 NO 3.3 1 10.6 NO NO --- --- -- 08/19/15 2.5 NO 5.9 1 7.5 1 NO NO --- --- --- 02/18/16 2.5 NO NO NO NO NO -- --- -- 08/11/16 2.5 3.4 1 31 3.1 1 2.7 1 NO --- --- --- 02/15/17 2.5 NO 6.8 1 2.9 1 ND 3.1 1 - --- -- 08/24/17 2.5 NO 7.6 1 NO ND NO --- --- --- 02/07/18 2.5 NO 5.1 1 NO ND NO --- --- -- 08/15/18 2.5 NO 12.5 3.2 1 NO NO --- --- --- Resample 11/02/18 2.5 --- 4.1 1 --- --- -- --- --- -- 02/06/19 2.5 NO 4.4 1 3.3 1 NO 5.8 --- --- --- 08/08/19 1 NO 8.5 1.8 1 NO NO -- --- -- 02/14/20 1 3 1 5.1 NO NO 2.5 1 --- --- --- 08/25/20 3.7 NO 22.6 10.9 NO 4.2 1 --- --- -- Resample 09/29/20 3.7 --- 6 NO --- --- --- --- --- 02/10/21 0.2 NO -- --- NO 0.34 1 NO --- -- 08/18/21 3.7 ___ 4 1 ___ ___ ___ ___ ___ ___ 02/15/22 3.7 --- 4 1 --- --- --- --- --- _- 09/29/2212I 3.7 NO NO NO NO NO NO NA NS 03 29 231a1 1.40 NO 7.11 1 NO 1.83 J NO 1.49 J NA NA Appendix D (Page 3 of 23) �nr>,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a uF 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Cobalt 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ 53 ___ ___ ___ NO NC 2L=1 pg/L 02/08/95 -- -- NO -- -- -- 23 --- -- 03/02/95 ___ ___ 22 ___ ___ ___ 24 11/17/95 -- -- 31 -- -- -- 15 --- -- 05/23/96 ___ ___ 19 ___ ___ ___ 16 11/14/96 -- -- 55 -- --- -- 16 --- -- 06/18/97 ___ ___ 52 .__ ___ ___ 28 12/02/97 __ -_ 16 __ --- -- 14 --- __ 05/27/98 ___ ___ 13 ___ ___ ___ 18 11/16/98 __ __ 54 --- --- __ 45 --- __ 09/10/99 --- --- NO 32 NO NO --- --- --- 11/16/99 -- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO ND NO NO --- --- --- 10/26/00 --- --- 15 11 NO NO -- --- -- 04/18/01 --- --- NO 21 NO NO --- --- --- 10/27/01 --- --- NO 28 NO NO -- --- -- 06/10/02 --- --- 11 15 ND ND --- --- --- 06/13/02 --- --- 11 15 NO NO -- --- -- 11/19/02 --- --- NO NO NO ND --- --- --- 06/27/03 --- --- 12 NO NO NO --- --- -- 12/30/03 --- --- NO NO ND ND --- --- --- 06/30/04 --- NO NO NO NO - --- -- 12/29/04 --- --- 12 NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- 11 NO NO NO --- --- --- 06/28/06 --- --- NO 21.3 NO NO --- --- -- 12/28/06 --- --- 16.4 NO NO NO --- --- --- 07/12/07 --- --- 11.2 NO NO NO -- --- -- 12/19/07 --- --- 17 4.6 B 1.1 B 1.4 B --- --- --- 07/08/08 --- --- 35 B 4.2 B 3.1 B 5 B --- --- -- 12/16/08 0.6 --- 11 3.2 B 1.4 B 3.1 B --- --- --- 07/08/09 0.6 --- 10.6 NO NO NO --- --- -- 12/15/09 0.6 --- 8.8 1 NO NO NO --- --- --- 06/23/10 0.6 --- 11.8 NO NO NO --- --- -- Resample 08/12/10 0.6 --- --- --- --- --- --- --- --- 12/14/30 0.6 --- 10.9 3.7 B NO 3.1 B --- --- -- 06/21/11 5 NO 11.6 NO NO NO --- --- --- 12/06/11 5 5 1 9.3 1 NO NO NO -- --- -- 06/13/12 5 NO 10.7 ND NO NO --- --- --- 12/11/12 5 NO 10.1 NO ND NO --- --- -- 04/29/13 5 ND 13 ND NO NO --- --- --- 08/06/13 5 NO 20.5 NO NO NO -- --- -- 02/25/14 5 ND 13.9 11.4 NO NO --- --- --- 08/13/14 5 NO 9.5 1 NO NO NO --- --- -- 03/12/15 2.5 ND 8 1 ND NO NO --- --- --- 08/19/15 2.5 NO 11.8 NO NO NO -- --- -- 02/18/16 2.5 NO 7.5 1 NO NO NO --- --- --- 08/11/16 2.5 NO 12.7 NO NO NO --- --- -- 02/15/17 2.5 NO 11.3 NO NO ND --- --- --- 08/24/17 2.5 NO 14.1 NO NO NO --- --- -- 02/07/18 2.5 NO 6.5 1 NO NO NO --- --- --- 08/15/18 2.5 NO 11.6 NO NO NO -- --- -- 11/02/18 2.5 --- 8.3 1 --- --- --- --- --- --- 02/06/19 2.5 NO 10.2 NO NO NO --- --- -- Resample 03/14/19 2.5 --- 5.2 --- --- --- --- --- --- 08/08/19 1.1 NO 11.3 3 1 NO NO -- --- -- 02/14/20 1.1 2.7 1 8.2 NO 1.4 1 1.5 1 --- --- --- 08/25/20 3.6 NO 17.8 NO NO NO --- --- -- 02/10/21 0.3 NO --- --- NO 0.96 1 NO --- --- 08/18/21 3.6 --- 10.5 --- --- -- --- --- -- 02/15/22 3.6 --- 5.8 4.8 1 --- --- 5.8 --- --- 09/29/22121 3.6 NO NO 9.5 NO NO NO NA NS 03 29 231'I1 0.840 NO 9.52 1 3.64 1 NO NO NO NA NA Copper 09/14/94 --- --- 130 --- --- --- NO --- --- 12/02/94 --- --- NO --- ... __ NO NC 2L=1,000 pg/L 02/08/95 --- --- NO --- --- --- NO --- --- 03/02/95 --- --- NO --- --- -- NO --- -- 11/17/95 ___ ___ NO ___ ___ ___ NO 05/23/96 --- --- NO --- --- -- NO --- -- 11/14/96 ___ ___ 54 ___ ___ ___ 15 06/18/97 --- --- 97 --- --- __ 45 --- __ 12/02/97 ___ ___ 24 ___ ___ ___ 17 05/27/98 --- --- 26 --- --- --- 28 11/16/98 --- --- 150 --- --- --- 80 --- --- 09/10/99 --- --- NO NO NO NO --- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/10/00 --- -- NO NO NO NO --- --- -- 10/26/00 --- --- NO NO NO NO --- --- --- 04/18/01 --- --- NO NO NO NO -- --- -- 10/27/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 11/19/02 --- --- NO NO ND NO --- --- --- 06/27/03 --- --- NO NO NO NO --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- -- NO NO NO NO --- --- -- 12/29/04 --- --- NO NO ND NO --- --- --- 06/29/05 --- -- NO NO NO NO - --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- -- NO NO NO NO -- --- -- 12/28/06 --- --- 3.5 1 1.7 B 2.5 B 0.9 B --- --- --- 07/12/07 --- --- NO 2 1 NO NO --- --- -- 12/19/07 --- --- 4.6 B 3.8 B 0.56 B 1.9 B --- --- --- 07/08/08 --- --- 9.3 1 1.6 1 NO NO --- --- -- 12/16/08 0.3 --- 2.1 1 2.3 1 NO 6.9 1 --- --- --- 07/08/09 0.3 --- 1.6 1 3.3 J NO NO --- --- -- 12/15/09 0.3 --- 2.9 1 2.7 1 NO 2.1 1 --- --- --- 06/23/10 0.3 --- 2 1 1.1 1 NO 0.86 1 --- --- -- Resample 08/12/10 0.3 --- --- --- --- --- --- --- --- 12/14/10 0.3 --- 1.8 B 8.1 1 0.39 B 5.9 1 --- --- -- 06/21/11 5 NO NO NO ND NO --- --- --- 12/06/11 5 15.5 NO 10 NO NO -- --- -- 06/13/12 5 NO NO 5.6 1 NO NO --- --- --- 12/11/12 5 NO NO NO NO NO -- --- -- 04/29/13 5 NO NO NO NO NO --- --- --- 08/06/13 5 NO 6.6 1 NO ND NO --- --- -- 02/25/14 5 NO NO 14.7 ND 6.4 1 --- --- --- 08/13/14 5 NO NO NO NO NO -- --- -- 03/12/15 2.5 NO NO 7.6 1 NO NO --- --- --- 08/19/15 2.5 NO 5 1 6.8 1 NO NO -- --- -- 02/18/16 2.5 NO NO 3.6 1 NO NO --- --- --- 08/11/16 2.5 NO 7.8 1 NO NO NO -- --- -- 02/15/17 2.5 NO 6.3 1 NO NO NO --- --- --- 08/24/17 2.5 5.1 1 3.7 1 NO NO NO --- --- -- 02/07/18 2.5 NO 10 3.4 1 NO NO --- --- --- 08/15/18 2.5 NO 7.4 1 2.8 1 NO NO -- --- -- 02/06/19 2.5 NO NO NO NO 8.1 --- --- --- 08/08/19 2.1 2.5 1 7.1 4.9 1 5 NO -- --- -- 02/14/20 2.1 5.5 4.1 1 NO ND 7.5 --- --- --- 08/25/20 4.3 NO 23.5 13.2 NO 14.2 --- --- -- Resample 09/29/20 4.3 --- NO --- --- --- --- --- --- 02/30/21 0.2 NO 1 ND --- NO 0.91 1 NO - -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212) 4.3 NO NO NO NO NO NO NA NS 03 29 23 nl 3.68 NO 5.89 J 20.2 6.72 J NO NO NA NA Appendix D (Page 4 of 23) snr>,mann<k.snereo«�n�omn�revMa.,.��a.,,ssana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a ur 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MWAR MW-5R MW-6R NES-2S NES-21) Iron 06/23/10 14 -- 4150 1040 102 1 413 -- -- -- Resample 08/12/10 140 --- --- --- --- --- --- --- --- NC2L=300 pg/L 12/14/10 14 --- 3210 3880 141 1 877 --- --- -- 06/21/11 50 2190 6030 667 114 1 981 --- --- --- 12/06/11 50 8610 2680 5420 86.1 1 287 1 --- --- -- 06/13/12 50 1770 5610 3280 63.4 1 698 --- --- --- 12/11/12 50 1680 4020 1260 NO 545 -- --- -- 04/29/13 50 414 3500 1130 112 1 635 --- --- --- 08/06/13 50 397 8970 307 NO 378 --- --- -- 02/25/14 50 1040 7060 9750 102 1 2030 --- --- --- 08/13/14 50 209 1 5380 3030 107 1 904 --- --- -- 03/12/15 25 269 1 3680 6040 40.8 1 262 1 --- --- --- 08/19/15 25 156 1 7250 3780 34.9 1 58 1 --- --- -- 02/18/16 25 243 1 792 270 1 43 1 86 1 --- --- --- 08/11/16 25 292 1 10400 839 104 1 NO --- --- -- 02/15/17 25 633 6250 1400 104 1 30 1 --- --- --- 08/24/17 25 3680 9740 792 46.8 1 39 1 --- --- -- 02/07/18 25 323 6740 849 126 1 61 1 --- --- --- 08/15/18 25 340 14000 1200 75.5 1 NO --- --- -- 02/06/19 25 183 3960 1440 54.8 2070 --- --- --- 08/08/19 19.5 176 8240 1770 35.1 1 25 1 --- --- -- 02/14/20 19.5 3750 5050 317 22.4 1 1870 --- --- --- 08/25/20 41.5 1570 18800 6280 NO 2570 994 --- -- Resample 09/29/20 41.5 --- 6320 702 --- 286 --- --- --- 02/10/21 0.3 NO --- --- NO 0.69 1 NO --- -- 08/18/21 41.5 246 6480 241 --- 226 3290 --- --- 08/19/21 41.5 --- --- --- 169 02/15/22 41.5 --- 5110 351 --- --- 6030 --- --- 02/16/22 41.5 --- --- --- 662 -- -- --- -- 09/29/22"1 41.5 472 1840 3210 ND 116 5930 NA NS 03 29 23(31 1 18.0 NO 1 6320 2940 20.1 1 1 292 3550 1 NA NA Lead 09/14/94 --- 230 --- --- -- 190 --- -- 12/02/94 ___ ___ 26 ___ ___ .__ 31 NC 2L=15 µg/L 02/08/95 --- 23 --- --- -- 15 --- -- 03/02/95 ___ ___ 14 ___ ___ .__ NO 11/17/95 --- --- NO --- --- -- NO --- -- 05/23/96 ___ ___ 10 ___ ___ .__ NO 11/14/96 --- --- NO --- --- -- NO --- -- 06/18/97 ___ ___ 21 ___ ___ .._ 70 12/02/97 --- --- 20 --- --- __ 24 --- __ 05/27/98 ___ ___ 23 ___ ___ ___ 32 11/16/98 --- --- 33 --- --- -- 110 --- -- 09/10/99 --- --- NO 14 NO NO --- --- --- 11/16/99 --- --- NO NO NO 11 -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- 28 15 NO 18 --- --- -- 06/10/02 --- --- 13 NO NO NO --- --- --- 06/13/02 --- --- 13 NO NO NO --- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO 10 --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO -- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- NO NO NO NO --- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO --- --- -- 12/28/06 --- --- 2 1 NO NO NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- ND NO NO NO --- --- --- 07/08/08 --- --- NO NO NO NO - --- -- 12/16/08 4 --- NO NO NO NO --- --- --- 07/08/09 4 --- NO NO NO NO - --- -- 12/15/09 4 --- NO NO NO NO --- --- --- 06/23/10 4 --- NO NO NO NO -- --- -- 12/14/10 4 --- NO NO NO NO --- --- --- 06/21/11 5 NO NO NO NO NO --- --- -- 12/06/11 5 NO NO NO NO NO --- --- --- 06/13/12 5 NO NO NO NO NO -- --- -- 12/11/12 5 NO NO NO NO NO --- --- --- 04/29/13 5 NO NO NO NO NO --- --- -- 08/06/13 5 NO NO NO NO NO --- --- --- 02/25/14 5 NO NO NO NO NO -- --- --- 08/13/14 5 NO NO NO NO NO --- --- --- 03/12/15 2.5 NO NO NO NO NO --- --- -- 08/19/15 2.5 NO 2.9 1 NO NO NO --- --- --- 02/18/16 2.5 NO NO NO NO NO -- --- --- 08/11/16 2.5 NO 2.7 1 NO NO NO --- --- --- 02/15/17 2.5 NO NO NO NO NO --- --- -- O8/24/17 2.5 NO NO NO NO NO --- --- --- 02/07/38 2.5 NO 2.8 1 NO NO NO -- --- -- O8/15/18 2.5 NO NO NO NO NO --- --- --- 02/06/19 2.5 NO NO NO NO NO --- --- -- O8/08/19 1.6 NO NO NO NO NO --- --- --- 02/14/20 1.6 NO 2.4 1 2.1 1 NO NO --- --- -- O8/25/20 4.5 NO NO NO NO NO --- --- --- 02/30/21 3.5 4.1 1 --- --- NO NO NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212I 4.5 NO NO NO NO NO NO NA NS 03 29 2313) 2.99 NO NO NO NO NO NO NA NA Manganese 06/23/10 0.3 --- 217 44 B 513 127 -- --- -- Resample 08/12/10 3 --- --- --- --- --- --- --- --- NC2L=50 L 121430 0.3 --- 208 139 730 194 --- --- -- 06/21/11 5 38.2 1 245 36.9 1 833 130 --- --- --- 12/06/11 5 198 216 170 808 187 -- --- -- 06/13/12 5 41.7 1 226 95.8 760 125 --- --- --- 12/11/12 5 33.8 1 230 28.9 1 770 279 -- --- -- 04/29/13 5 14.2 1 193 47.3 1 724 139 --- --- --- 08/06/13 5 10.3 1 273 38.5 1 749 135 -- --- -- 02/25/14 5 29.8 1 222 340 897 154 --- --- --- 08/13/14 5 5.8 1 209 108 1230 125 --- --- -- 03/12/15 2.5 6 1 210 200 676 104 --- --- --- 08/19/15 2.5 4.3 1 288 199 802 103 --- --- -- 02/18/16 2.5 5.4 1 201 72.7 981 82.4 --- --- --- 08/11/16 2.5 5.9 1 336 122 1550 100 -- --- -- 02/15/17 2.5 15.5 1 234 246 1390 91.4 --- --- --- 08/24/17 2.5 94.7 344 116 999 98.3 --- --- -- 02/07/18 2.5 7.6 1 168 196 1160 158 --- --- --- 08/15/18 2.5 6.7 1 284 63.6 937 105 -- --- -- 02/06/19 2.5 5.5 226 79 1050 121 --- --- --- 08/08/19 0.9 6 272 995 1020 97.6 --- --- -- 02/14/20 0.9 85.8 175 606 983 117 --- --- --- 08/25/20 --- 35.2 356 407 764 117 2100 --- -- Resample 09/29/20 3.4 --- 186 --- --- --- --- --- --- 02/30/21 4.3 4.4 1 --- --- NO NO NO --- -- O8/18/21 3.4 82.4 262 470 --- 82 2310 --- --- 08/19/21 3.4 --- --- --- 864 -- --- --- -- 02/15/22 3.4 --- 192 1140 --- --- 2390 --- --- 02/16/22 3.4 --- --- --- 35.9 -- -- --- -- 02/17/22 3.4 --- --- --- --- 103 --- --- --- 09/29/2212I 3.4 20.9 175 3480 15.6 335 2180 NA NS 03 29 23131 1 0.934 1 NO 1 198 1 2890 1 70.5 1 102 1 274 1 NA I NA Appendix D (Page 5 of 23) bna>,mann<k.01 Pros«.acamna Moore,cMwoa11 wn 1=3 n9, 1,11cwMRemavom,3 urn, Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Mercury 11/17/95 -- -- NO -- -- -- NO -- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L = 1 µg/L 03/23/98 -- -- NO -- -- -- NO --- -- 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 -- -- NO --- --- -- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO --- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- --- --- --- 06/10/02 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO --- --- -- 11/19/02 --- --- --- --- --- ___ ___ ___ ___ 06/27/03 --- --- NO NO NO 0.78 -- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO --- --- -- 12/28/06 --- --- NO NO NO NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- NO NO NO NO --- --- --- 07/08/08 --- NO NO NO NO -- --- -- 12/16/08 0.09 --- NO NO NO NO --- --- --- 07/08/09 0.07 --- NO NO NO NO --- --- -- 12/15/09 0.07 --- NO NO NO NO --- --- --- 06/23/10 0.07 --- NO NO 0.094 1 NO -- --- -- 12/14/10 0.07 NO NO NO NO --- --- --- 06/21/11 0.1 NO NO NO NO NO --- --- -- 12/06/11 0.1 NO NO NO NO NO --- --- --- 06/13/12 0.1 NO NO NO NO NO -- --- -- 12/11/12 0.1 NO NO NO NO NO --- --- --- 04/29/13 0.1 NO NO NO NO NO --- --- -- 08/06/13 0.1 NO NO NO NO NO --- --- --- 02/25/14 0.1 NO NO NO NO NO -- --- -- 08/13/14 0.1 NO NO NO NO NO --- --- --- 03/12/15 0.1 NO NO NO NO NO --- --- -- 08/19/15 0.1 NO NO NO NO NO --- --- --- 02/18/16 0.1 NO NO NO NO NO -- --- -- 08/11/16 0.1 NO 0.11 J NO NO NO --- --- --- 02/15/17 0.1 NO ND NO NO NO --- --- -- 08/24/17 0.1 NO ND NO NO NO --- --- --- 02/07/18 0.1 NO 0.11 1 NO NO NO -- --- -- 08/15/18 0.1 NO NO NO NO NO --- --- --- 02/06/19 0.1 NO NO NO NO NO -- --- -- 08/08/19 0.1 NO NO NO NO NO --- --- --- 02/14/20 0.1 NO NO NO --- NO -- --- -- 08/25/20 0.12 NO 0.13 1 NO NO NO --- --- --- 02/30/21 0.26 NO NO --- --- -- -- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�I 0.12 NO NO NO NO NO NO NA NS 03 29 231a1 0.100 NO NO NO NO NO NO NA NA Nickel 09/14/94 --- --- NO --- --- --- NO - -- 12/02/94 --- --- 119 --- --- --- NO --- --- NC2L=100 pg/L 02/08/95 --- --- NO --- --- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 --- --- NO --- --- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 --- --- NO --- -- -- NO --- -- 06/18/97 ___ ___ 65 ___ ___ ___ NO 12/02/97 --- --- N0 --- __ __ N0 --- __ 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- --- NO --- -- --- ISO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO 59 NO NO -- --- -- 06/10/02 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO NO --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO -- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO --- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO -- --- -- 12/28/06 --- --- 7 1 7.2 1 2.4 1 NO --- --- --- 07/12/07 --- --- 3.2 1 2.5 1 NO NO --- --- -- 12/19/07 --- --- 3.2 1 5 NO 2.3 1 --- --- --- 07/08/08 --- --- 5.3 1 2.3 1 NO 1.7 1 --- --- -- 12/16/08 1.7 --- 2.3 B 2.5 B NO 2.7 B --- --- --- 07/08/09 1.7 --- 3.2 1 6 1 NO 1.8 1 --- --- -- 12/15/09 1.7 --- 3.6 B 4.4 B 2.1 B 2.6 B --- --- --- 06/23/10 1.7 --- 2.3 1 NO NO NO - --- -- 12/14/10 1.7 --- 1.8 B 2.6 B NO NO --- --- --- 06/21/11 5 NO NO NO NO NO -- --- -- 12/06/11 5 NO NO 6.4 1 NO NO --- --- --- 06/13/12 5 NO NO NO NO NO -- --- -- 12/11/12 5 NO ND NO ND NO --- --- --- 04/29/13 5 NO ND NO ND NO -- --- -- 08/06/13 5 NO ND NO ND NO --- --- --- 02/25/14 5 NO ND 11.3 1 NO NO -- --- -- 08/13/14 5 NO NO NO NO NO --- --- --- 03/12/15 2.5 NO NO 11.7 1 NO NO --- --- -- 08/19/15 2.5 NO 3.7 1 8.9 1 NO NO --- --- --- 02/18/16 2.5 NO NO 3.2 1 NO NO -- --- -- O8/11/16 2.5 NO 6.4 1 6.7 1 NO NO --- --- --- 02/15/17 2.5 NO 4.9 1 8.8 1 NO NO --- --- -- O8/24/17 2.5 3.3 1 5.6 1 4.6 1 NO NO --- --- --- 02/07/18 2.5 NO NO 4.8 1 NO NO -- --- -- O8/15/18 2.5 NO 5.5 1 3.4 1 NO NO --- --- --- 02/06/19 2.5 NO 2.9 1 3.1 1 NO 2.8 1 --- --- -- O8/08/19 0.9 0.93 1 4.3 1 9.8 1.1 1 1.3 1 --- --- --- 02/14/20 0.9 2.5 1 3.2 1 7.1 1.9 1 1.7 1 --- --- -- O8/25/20 3.5 NO 12.6 11.7 NO NO --- --- --- 02/10/21 3 NO NO --- NO NO NO --- -- O8/18/21 3.5 --- --- 8.4 --- --- --- --- --- 02/15/22 3.5 --- --- 7.3 --- --- 3.6 1 -- -- 09/29/2212I 3.5 NO NO NO NO NO NO NA NS 03 29 231a1 1 1.61 1.92 J 1 4.97 J,B 3.25 J 1 3.82 J,B 2.16 J 1 3.98 J,B NA NA Appendix D (Page 6 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a LF wn „�o:a F�9, x,�rcwMRemavom,n urn, ��awfi�.,n�.> Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-511 MW-6R NES-2S NES-21) Selenium 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=20 µg/L 02/08/95 -- -- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 -- -- NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 -- --- NO --- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 __ --- NO --- --- __ NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- --- NO --- --- -- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- NO ND NO NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO ND NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO ND NO NO --- --- --- 12/29/04 --- --- NO NO NO NO --- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO NO - --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- NO NO NO NO -- --- -- 07/12/07 --- --- NO NO NO NO --- --- --- 12/19/07 --- --- NO NO NO NO --- --- -- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 3.8 --- NO NO NO NO -- --- -- 07/08/09 3.8 --- NO NO NO NO --- --- --- 12/15/09 3.8 --- NO NO NO NO --- --- -- 06/23/10 3.8 --- NO NO NO NO --- --- --- 12/14/10 3.8 --- NO NO NO NO -- --- -- 06/21/11 10 NO NO NO NO NO --- --- --- 12/06/11 10 NO NO NO NO NO --- - -- 06/13/12 10 NO NO NO NO NO --- --- --- 12/11/12 10 NO NO NO NO NO -- --- --- 04/29/13 10 NO NO NO NO NO --- --- --- 08/06/13 10 NO NO NO NO NO --- --- -- 02/25/14 10 NO NO NO NO NO --- --- --- 08/13/14 30 NO NO NO ND NO -- --- --- 03/12/15 5 NO NO NO ND NO --- --- --- 08/19/15 5 NO NO NO NO NO --- --- -- 02/18/16 5 NO ND NO ND NO --- --- --- 08/11/16 5 NO NO NO NO NO -- --- -- 02/15/17 5 NO ND NO ND NO --- --- --- 08/24/17 5 NO NO NO NO NO -- --- -- 02/07/18 5 NO NO NO NO NO --- --- --- 08/15/18 5 NO NO NO NO NO -- --- -- 02/06/19 5 NO NO NO NO NO --- --- --- 08/08/19 4.7 NO NO NO NO NO -- --- -- 02/14/20 4.7 NO NO NO NO NO --- --- --- 08/25/20 4.7 NO NO NO NO 5.9 1 --- --- -- 02/10/21 0.7 NO NO --- NO --- NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 4.7 NO NO NO NO NO NO NA INS 03 29 23131 7.35 NO NO NO NO NO NO NA NA Silver 09/14/94 --- --- NO --- --- --- NO --- --- 12/02/94 --- --- NO --- --- -- NO --- -- NC2L=20 µg/L 02/08/95 --- --- NO --- --- --- NO --- --- 03/02/95 --- --- NO --- --- -- NO --- -- 11/17/95 ___ ___ NO ___ ___ ___ NO 05/23/96 --- --- NO --- --- -- NO --- -- 11/14/96 ___ ___ NO ___ ___ ___ NO 06/18/97 --- --- NO --- --- -- NO --- -- 12/02/97 ___ ___ NO ___ ___ ___ 4 05/27/98 --- --- NO --- --- -- NO --- __ 11/16/98 ___ ___ NO ___ ___ ___ NO 09/10/99 --- --- NO NO NO NO --- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/10/00 --- --- NO NO NO NO -- --- -- 10/26/00 --- --- NO NO NO NO --- --- --- 04/18/01 --- --- NO NO NO NO -- --- -- 10/27/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO --- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO NO --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO -- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- --- NO NO NO NO --- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- --- NO NO NO NO -- --- -- 12/28/06 --- --- NO NO NO NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- NO NO 0.26 1 NO --- --- --- 07/08/08 --- --- 0.27 1 0.41 1 0.83 1 0.39 1 --- --- -- 12/16/08 0.1 --- NO 0.25 1 0.53 1 0.4 1 --- --- --- 07/08/09 0.1 --- NO NO 0.17 1 NO --- --- -- 12/15/09 0.1 --- NO 0.32 1 0.64 1 0.53 1 --- --- --- 06/23/30 0.1 --- NO NO 0.13 1 0.13 1 --- --- -- 12/14/10 0.1 --- NO 0.24 B 0.58 B 0.34 B --- --- --- 06/21/11 5 NO NO NO NO NO --- --- -- 12/06/11 5 NO ND NO NO NO --- --- --- 06/13/12 5 NO NO NO NO NO -- --- -- 12/11/12 5 NO ND NO NO NO --- --- --- 04/29/13 5 NO NO NO NO NO -- --- -- O8/06/13 5 NO NO NO NO NO --- --- --- 02/25/14 5 NO NO NO NO NO --- --- --- 08/13/14 5 NO NO NO NO NO --- --- --- 03/12/15 2.5 NO NO NO NO NO --- --- -- O8/19/15 2.5 NO ND NO NO NO --- --- --- 02/18/16 2.5 NO NO NO NO NO -- --- -- O8/11/16 2.5 NO ND NO ND NO --- --- --- 02/15/17 2.5 NO NO NO NO NO --- --- -- O8/24/17 2.5 NO NO NO NO NO --- --- --- 02/07/18 2.5 NO NO NO NO NO -- --- -- 08/15/18 2.5 NO NO NO NO NO --- --- --- 02/06/19 2.5 NO NO NO NO NO -- --- -- 08/08/19 2.5 NO NO NO NO NO --- --- --- 02/14/20 2.5 NO NO NO NO NO --- --- -- 08/25/20 2.5 NO NO NO NO NO --- --- --- 02/10/21 0.4 NO NO --- NO --- NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212) 2.5 NO NO NO NO NO NO NA NS 03 29 23131 1.54 NO NO NO NO NO NO NA NA Appendix D (Page 7 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a uF 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-511 MW-6R NES-2S NES-2D Sulfide 11/17/95 -- --- NO -- -- -- NO -- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L=NE 03/23/98 --- 1000 -- -- -- 1400 --- -- 05/27/98 --- --- 1000 --- --- --- NO --- --- 11/16/98 --- 13000 --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- 17000 5000 47000 33000 --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/O1 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- --- --- --- --- ___ ___ ___ ___ 12/30/03 -- -- --- --- 06/30/04 --- --- NO 7 NO NO --- --- --- 12/29/04 --- --- --- --- --- 06/29/05 --- --- NO NO NO NO --- --- --- 12/29/05 --- -- NO NO 1700 B NO -- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- -- NO 500 1 NO NO --- --- -- 07/12/07 --- --- NO NO NO NO --- --- --- 12/19/07 --- -- NO NO ND NO -- --- -- 07/08/08 --- --- NO NO ND NO --- --- --- 12/16/08 100 --- NO 150 1 ND 141 1 --- --- -- 07/08/09 100 --- NO NO NO NO --- --- --- 12/15/09 100 --- NO NO NO NO --- --- -- 06/23/10 100 --- NO NO NO NO --- --- --- 12/14/10 100 --- NO NO NO NO -- --- -- 06/21/11 100 NO NO NO NO NO --- --- --- 12/06/11 100 NO NO NO NO NO -- --- -- 06/13/12 100 NO NO NO ND NO --- --- --- 12/11/12 100 NO NO NO ND 117 1 --- --- -- 04/29/13 100 NO NO NO ND NO --- --- --- 08/06/13 100 NO NO NO NO NO -- --- -- 02/25/14 100 NO NO 141 1 189 1 NO --- --- --- 08/13/14 50 NO --- --- --- NO -- --- -- 03/12/15 100 NO --- --- --- NO --- --- --- 08/19/15 100 NO --- --- --- NO --- --- -- 02/18/16 100 NO --- --- --- NO --- --- --- 08/11/16 100 NO -- --- --- NO -- --- -- 02/15/17 100 NO --- --- --- NO --- --- --- 08/24/17 100 NO -- --- --- NO --- --- -- 02/07/18 100 NO --- --- --- NO --- --- --- 02/06/19 50 NO - --- --- NO --- --- -- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 50 NO --- --- --- NO --- --- --- 02/10/21 50 NO --- --- --- NO --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22") NA NA NA NA NA NA NA NA NS 03 29 23 M 22.0 NO NA NA NA NO NA NA NA Thallium 09/14/94 --- --- NO --- --- --- NO --- --- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=2 pg/L 02/08/95 --- --- NO --- --- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 --- --- NO --- --- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 --- --- NO --- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 --- --- NO --- __ --- NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- --- NO --- -- --- NO --- -- 09/10/99 --- --- NO NO ND NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO ND NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO ND NO --- --- --- 10/27/01 --- --- NO NO ND NO --- --- -- 06/13/02 --- --- NO NO ND NO --- --- --- 11/19/02 --- --- NO NO ND NO -- --- -- 06/27/03 --- --- NO NO ND NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO NO ND NO --- --- --- 12/29/04 --- --- NO NO ND NO -- --- -- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- NO NO ND NO --- --- -- 06/28/06 --- --- NO NO ND NO --- --- --- 12/28/06 --- --- NO NO ND NO -- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- NO NO ND NO --- --- -- 07/08/08 --- --- 4.5 1 NO ND NO --- --- --- 12/16/08 3 --- NO NO ND NO -- --- -- 07/08/09 3 --- NO NO ND NO --- --- --- 12/15/09 3 --- NO NO ND 3.8 1 --- --- -- 06/23/10 3 --- NO NO ND NO --- --- --- Resample 08/12/10 30 --- --- --- -- -- --- --- -- 12/14/10 3 --- NO NO 8.1 NO --- --- --- 06/21/11 5.4 NO NO NO NO NO -- --- -- 12/06/11 5.4 NO NO NO NO NO --- --- --- 06/13/12 5.4 NO NO NO NO NO -- --- -- 12/11/12 5.4 NO NO NO NO NO --- --- --- 04/29/13 5.4 NO NO NO NO NO -- --- -- 08/06/13 5.4 NO NO NO NO NO --- --- --- 02/25/14 5.4 NO NO NO NO NO -- --- -- 08/13/14 5.4 NO NO NO NO NO --- --- --- 03/12/15 5 NO NO NO NO NO --- --- -- 08/19/15 5 NO NO NO NO NO --- --- --- 02/18/16 5 NO NO NO NO NO -- --- -- 08/11/16 5 NO NO NO NO NO --- --- --- 02/15/17 0.02 NO NO NO NO NO --- --- -- 08/24/17 0.02 NO NO NO NO NO --- --- --- 02/07/18 0.028 NO NO NO NO NO -- --- -- O8/15/18 0.02 NO NO NO NO NO --- --- --- 02/06/19 0.06 NO NO NO NO NO --- --- -- O8/08/19 0.11 NO NO NO NO NO --- --- --- 02/14/20 0.06 NO NO NO NO NO -- --- -- O8/25/20 0.05 NO 0.12 NO NO NO --- --- --- 02/30/21 0.24 NO NO --- --- --- --- --- -- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22(2) 0.05 NO NO NO NO NO NO NA NS 03 29 23 (3) 0.121 NO NO NO NO NO NO NA NA Tin 07 08 08 --- --- 1.9 1 3 1 3 1 3.6 1 -- --- -- 12/16/08 1.8 --- --- --- --- --- --- NC2L=2,000 µg/L 07/08/09 1.8 --- NO NO 1.8 1 NO --- --- - 12/15/09 ___ ___ ___ ___ ___ ___ ___ 06/23/10 1.8 --- NO NO 1.9 1 2.5 1 --- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 5 NO NO NO NO NO -- --- -- 12/06/11 5 --- --- --- --- --- --- 06/13/12 5 NO NO NO NO NO --- --- 12/11/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 5 NO NO NO NO NO --- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 5 NO NO NO NO NO -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 2.5 NO --- --- -- NO -- --- -- 02/18/16 2.5 NO --- --- --- NO --- --- --- 02/15/17 2.5 NO --- --- -- NO --- --- -- 08/24/17 2.5 NO --- --- --- NO --- --- --- 02/07/18 2.5 NO NO --- NO NO --- --- -- 02/06/19 2.5 NO NO NO NO NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.7 NO --- NO --- --- --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 i:1 NA NA NA NA NA NA NA NA NS 03 29 23 pl 4.87 NO NA NA NA NO NA NA NA Appendix D (Page 8 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.nwaa..Mes Pros«.,,camna Moo�.,cMww-c -I. co. o,ra,a uF W„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-SR MW-611 NES-2S NES-21) Total Cyanide 07/08/08 NO NO 6.2 1 NO 12/16/08 --- --- --- --- --- --- --- --- --- NC 2L NE 07/08/09 5 NO NO NO NO 12/15/09 --- --- --- --- --- --- --- --- --- 06/23/10 5 NO NO NO NO 12/14/10 --- --- --- --- --- --- --- --- --- 06/21/11 5 NO NO NO NO NO 12/06/11 --- --- --- --- --- --- --- --- --- 06/13/12 5 5.8 1 6.2 j 5.2 1 --- --- --- --- 12/11/12 --- --- --- --- --- --- --- --- --- 04/29/13 5 NO NO NO NO NO 08/06/13 --- --- --- --- --- --- --- --- --- 02/25/14 5 NO NO NO NO NO 08/13/14 --- --- --- --- --- --- --- --- --- 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 121 NA NA NA NA NA NA NA NA INS 03/29/23 (" 1 30.0 NO NA NA NA NO NA NA NA Total Dissolved Solids 06/23/10 250000 96200 184000 364000 237000 12/14/10 25000 100000 218000 372000 260000 NC 2L 500,000 WJL 06/21/11 5000 170000 89000 194000 374000 238000 12/06/11 174000 92000 168000 378000 242000 06/13/12 25000 189000 98000 184000 390000 253000 12/11/12 25000 199000 141000 199000 427000 274000 04/29/13 25000 170000 114000 183000 416000 276000 08/06/13 25000 179000 142000 175000 421000 291000 02/25/14 25000 173000 109000 206000 405000 281000 08/13/14 25000 172000 184000 187000 446000 319000 03/12/15 229000 113000 184000 430000 256000 08/19/15 217000 149000 172000 431000 303000 02/18/16 25000 162000 84000 140000 412000 237000 08/11/16 25000 213000 122000 171000 437000 301000 02/15/17 25000 233000 62000 154000 438000 277000 08/24/17 25000 226000 114000 160000 418000 270000 02/07/18 235000 124000 170000 444000 308000 08/15/18 25000 249000 238000 164000 458000 303000 02/06/19 25000 246000 124000 172000 468000 334000 08/08/19 25000 256000 228000 188000 469000 323000 02/14/20 25000 249000 141000 165000 468000 317000 08/25/20 262000 232000 196000 465000 357000 660000 02/10/21 271000 --- --- --- --- --- --- --- 08/18/21 259000 96000 168000 294000 562000 02/15/22 50000 117000 175000 732000 1g 02/16/22 50000 526000 --- --- --- --- 02/17/22 25000 268000 328000 09/29/22 25000 246000 148000 399000 517000 326000 668000 NA NS 03 29 231ai 25000 252000 1 118000 192000 451000 1 307000 647000 1 NA NA Tritium (Hydrogen-3) 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 0.49 --- --- --- --- 0.95 1 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) NA NA NA NA NA NA NA NA INS NC 2L= NE 03/29/23 ") I NA NA NA NA NA I NA NA NA NA Vanadium 09/14/94 390 340 12/02/94 233 NO NC 2L 7 ug/L 02/08/95 132 NO 03/02/95 173 NO 11/17/95 84 NO 05/23/96 103 NO 11/14/96 140 22 06/18/97 310 82 12/02/97 52 27 05/27/98 71 41 11/16/98 340 97 09/10/99 NO NO NO NO 11/16/99 NO NO NO NO 05/10/00 NO NO NO NO 10/26/00 NO NO NO NO 04/18/01 NO NO NO NO 10/27/01 67 53 NO 63 06/10/02 NO NO NO NO 06/13/02 NO NO NO NO 11/19/02 NO NO NO NO 06/27/03 NO NO NO 94 12/30/03 NO NO NO NO 06/30/04 NO NO NO NO 12/29/04 NO NO NO NO 06/29/05 NO NO NO NO 12/29/05 NO NO NO NO 06/28/06 NO 71.1 NO NO 12/28/06 28.4 NO NO 1.8 1 07/12/07 3.4 1 2.2 1 NO NO 12/19/07 7.6 3.2 1 1.1 a 0.82 B Resample 02/14/08 7.2 --- --- --- --- --- --- Filtered 07/08/08 21.9 1 2.2 1 0.94 B 0.78 B 12/16/08 0.2 4.9 1 3.4 1 0.84 B 6.1 1 07/08/09 0.2 10.6 1 8.3 1 1.7 B 1.9 B 12/15/09 0.2 12.1 1 3.8 1 1.3 B 2.3 B 06/23/10 0.2 10.7 1 2 j 0.51 1 1.2 j Resample 08/12/10 0.2 --- --- --- --- --- --- --- --- 12/14/10 0.2 7.3 1 8 1 1.2 B 4 j 06/21/11 5 5.9 1 14.6 1 NO NO NO 12/06/11 5 19.8 1 5.3 1 10 1 NO NO 06/13/12 5 5.2 1 13 1 6.5 1 NO NO 12/11/12 5 NO 7.4 1 NO NO NO 04/29/13 5 NO 8.4 1 NO NO NO 08/06/13 5 NO 27.6 NO NO NO 02/25/14 5 NO 18.6 j 19 1 NO 7 1 08/13/14 5 NO 15 1 7.2 1 NO NO 03/12/15 2.5 NO 9.5 j 14.8 1 NO 3.3 1 08/19/15 2.5 NO 19.2 1 8.3 1 NO NO 02/18/16 2.5 NO NO NO NO NO 08/11/16 2.5 NO 25.2 NO NO NO 02/15/17 2.5 NO 13.9 1 NO NO NO 08/24/17 2.5 10.3 1 23.7 1 NO NO NO 02/07/18 2.5 NO 18.1 j 2.6 1 NO NO 08/15/18 2.5 NO 34.5 2.6 1 NO NO Resample 11/02/18 2.5 13 1 --- --- --- --- --- --- 02/06/19 2.5 NO 10.4 3.5 1 NO 9.5 Resample 03/14/19 2.5 10 --- --- --- --- --- --- 08/08/19 1.3 2.2 1 23.4 4.8 1 NO NO 02/14/20 1.3 9.2 13.1 NO NO 9.3 08/25/20 3.9 4.4 1 53 13.5 NO 12.2 Resarnple 09/29/20 3.9 17.5 NO NO 02/10/21 4.3 NO NO NO NO 08/18/21 3.9 11.3 --- --- --- --- --- --- 02/15/22 3.9 12.5 --- --- --- --- --- --- 09/29/22 12) 3.9 NO 4.8 1 NO NO NO NO NA NS 1 03/29/23 (') 1 4.99 1 NO 1 7.11 J I NO I NO I NO I NO I NA I NA Appendix D (Page 9 of 23) 1-0 1-1 Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Zinc 09/14/94 -- -- 400 -- -- -- 640 -- -- 12/02/94 --- --- 380 --- --- --- 98 --- --- NC 2L=1,000 pg/L 02/08/95 -- -- 236 -- -- -- 108 --- -- 03/02/95 --- --- 102 --- --- --- NO --- --- 11/17/95 -- -- 154 -- -- -- NO --- -- 05/23/96 --- --- 116 --- --- --- NO --- --- 11/14/96 --- 140 --- --- -- 48 --- -- 06/18/97 --- --- 250 --- --- --- 190 --- --- 12/02/97 --- --- 110 --- --- --- 130 --- -- 05/27/98 --- --- 90 --- --- --- 110 --- --- 11/16/98 --- --- 3600 --- --- --- 3900 --- -- 09/10/99 --- --- NO 96 NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO 64 NO NO --- --- --- 10/27/01 --- --- 55 136 NO 32 --- --- -- 06/10/02 --- --- NO 72 NO NO --- --- --- 06/13/02 --- --- NO 72 NO NO --- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- NO NO NO 52 --- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- ND NO ND NO --- --- --- 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- ND NO ND NO --- --- --- 06/28/06 --- --- NO 126 NO NO -- --- -- 12/28/06 --- --- 14 7.8 1 NO NO --- --- --- 07/12/07 --- --- 3.6 1 6.5 1 NO NO --- --- -- 12/19/07 --- --- 0.4 B NO 4.5 B NO --- --- --- 07/08/08 --- --- 12.6 NO NO NO -- --- -- 12/16/08 0.4 --- 0.45 J 3.8 1 NO 12.3 --- --- --- 07/08/09 0.4 --- 0.67 1 7 1 NO NO -- --- -- 12/15/09 0.4 --- 5.5 B 6.9 B NO 1.9 B --- --- --- 06/23/10 0.4 --- 2.2 1 1 1 NO NO -- --- -- 12/14/10 0.4 --- 16.3 B 12.6 B NO NO --- --- --- 06/21/11 10 NO NO NO NO NO -- --- -- 12/06/11 10 21.8 B NO 21 B NO NO --- --- --- 06/13/12 10 NO NO 14 NO NO -- --- -- 12/11/12 10 NO NO NO NO NO --- --- --- 04/29/13 10 NO NO NO NO NO --- --- -- 08/06/13 10 NO NO NO NO NO --- --- --- 02/25/14 10 NO NO 31.9 NO NO -- --- -- 08/13/14 10 NO NO 24.1 NO NO --- --- --- 03/12/15 5 9.2 8 11.5 B 24.3 8 6.8 B 7.5 a --- --- -- 08/19/15 5 NO 7.2 B 16.3 B NO NO --- --- --- 02/18/16 5 14.8 NO ND 6.6 1 NO -- --- -- 08/11/16 5 NO 18.2 8.6 J NO ND --- --- --- 02/15/17 5 NO 14.7 8 1 NO NO -- --- -- 08/24/17 5 9.2 J 8.1 1 10.7 NO ND --- --- --- 02/07/18 5 NO NO NO NO NO -- --- -- 08/15/18 5 ND 15.3 6.6 J NO NO --- --- --- 02/06/19 5 NO NO NO NO NO -- --- -- 08/08/19 3.9 ND 7.2 1 6 J NO NO --- --- --- 02/14/20 3.9 9.6 1 5.8 1 NO NO 4.4 J --- --- -- 08/25/20 9.5 NO 32 20.6 NO NO --- --- --- 02/10/21 4.5 NO NO --- NO NO --- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22M 9.5 NO NO NO NO NO NO NA NS 03 29 23 (') 1 6.52 1 NO 8.24 1 1 8.44 J 1 12.7 J I NO NO NA NA Appendix D (Page 10 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a uF 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-SR MW-6R NES-25 NB-2D Organics 1,1-Dichloroethane 11/11/16/99 --- --- ND ND ND 6 --- --- --- 09/14/94 -- -- ND -- -- -- ND --- -- NC2L=6µg/L 12/02/94 --- --- ND --- --- --- ND --- --- 02/08/95 --- -- ND -- -- -- ND --- -- 03/02/95 ___ ___ ND ___ ___ ___ ND 11/17/95 --- --- ND -- -- -- ND --- -- 05/23/96 ___ ___ ND ___ ___ ___ 7 11/14/96 --- --- ND --- --- -- ND --- -- 06/18/97 ___ ___ ND ___ ___ ___ 9.7 12/02/97 --- --- ND --- --- __ ND --- __ 05/27/98 ___ ___ ND ___ ___ ___ 12 11/16/98 --- --- ND --- --- -- 5.2 --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 12/16/99 --- --- --- --- --- 5 --- --_ __ 05/10/00 --- --- ND ND ND 6 --- --- --- 10/26/00 --- --- ND ND ND 7 -- --- -- 04/18/01 --- --- ND ND ND 6 --- --- --- 10/27/01 --- --- ND ND ND 7 -- --- -- 06/10/02 --- --- ND ND ND 6 --- --- --- 06/13/02 --- --- ND ND ND 6 --- --- -- 11/19/02 --- --- ND ND ND ND --- --- --- 06/27/03 --- -- ND ND ND 7.2 --- --- -- 12/30/03 --- --- ND ND ND 6.3 --- --- --- 06/30/04 --- -- ND ND ND 6.5 -- --- -- 12/29/04 --- --- ND ND ND 6.9 --- --- --- 06/29/05 --- -- ND ND ND 7 -- --- -- 12/29/05 --- --- ND ND ND 6 --- --- --- 06/28/06 --- -- ND ND ND 6.6 --- --- -- 12/28/06 --- --- ND ND ND 5.3 --- --- --- 07/12/07 --- --- ND 0.33 1 ND 5.4 -- --- -- Resample 08/21/07 --- --- --- 0.4 1 --- --- --- --- --- 12/19/07 --- --- ND ND ND 6.2 --- --- -- 07/08/08 --- --- ND ND ND 5.1 --- --- --- 12/16/08 0.32 --- ND ND ND 3.4 1 -- --- -- 07/08/09 0.32 --- ND ND ND 9.3 --- --- --- 12/15/09 0.32 --- ND ND ND 6.4 --- --- -- 06/23/10 0.32 --- ND ND ND 6.5 --- --- --- 12/14/30 0.32 --- ND ND ND 3.9 1 --- --- -- 06/21/11 0.32 ND ND ND ND 6.7 --- --- --- 12/06/31 0.32 ND ND ND ND 3 1 --- --- -- 06/13/12 0.32 ND ND ND ND 3.7 1 --- --- --- 12/12/12 0.32 ND ND ND ND 2.5 1 --- --- -- 04/29/13 0.32 ND ND ND ND 5.8 --- --- --- 08/06/13 0.32 ND ND ND ND 5 --- --- -- 02/25/14 0.32 ND ND ND ND 4.5 1 --- --- --- 08/13/14 0.32 ND ND ND ND 3.4 1 --- --- -- 03/12/15 0.32 ND ND ND ND 4.2 1 --- --- --- 08/19/15 0.32 ND ND ND ND 3.7 1 --- --- -- 02/18/16 0.32 ND ND ND ND 3.4 1 --- --- --- 08/11/16 0.32 ND ND ND ND 3.4 1 --- --- -- 02/15/17 0.32 ND ND ND ND ND --- --- --- 08/24/17 0.32 ND ND ND ND 2.2 1 --- --- -- 02/07/18 0.32 ND ND ND ND 1.7 1 --- --- --- 08/16/18 0.32 ND ND ND ND 2.4 1 --- --- -- 02/06/19 0.27 ND ND ND ND 3 --- --- --- 08/07/19 0.27 ND ND ND ND 2.2 --- --- -- 02/14/20 0.27 ND ND ND ND 2.3 --- --- --- 08/25/20 0.27 ND ND ND ND 2 1.2 --- -- 02/10/21 0.62 ND ND --- ND ND ND --- --- 08/18/21 0.37 --- --- --- --- 1.6 1.3 --- -- 02/15/22 0.37 --- --- --- --- --- 1.4 --- --- 02/17/22 0.37 --- --- --- --- 1.4 --- --- -- 09/29/22121 0.37 <1.0 <1.0 <1.0 <1.0 1.1 1.4 NA NS 03 29 231a1 0.37 ND ND ND ND 1.4 0.92 J NA NA 1,2-Dichlorobemene 07/12/07 --- --- ND ND ND 0.6 1 --- --- -- 12/19/07 --- --- ND 0.32 1 ND 0.99 1 --- --- --- NC2L=20 µg/L 07/08/08 --- --- ND ND ND 1.3 1 --- --- -- 12/16/08 0.3 --- ND ND ND 0.73 1 --- --- --- 07/08/09 0.3 --- ND ND ND 1.1 1 --- --- -- 12/15/09 0.3 --- ND ND ND 0.99 1 --- --- --- 06/23/10 0.3 --- ND ND ND 1 1 --- --- -- 12/14/10 0.3 --- ND ND ND 0.78 1 --- --- --- 06/21/11 0.3 ND ND ND ND 1.1 1 --- --- -- 12/06/11 0.3 ND ND ND ND 0.74 1 --- --- --- 06/13/12 0.3 ND ND ND ND 1.1 1 --- --- -- 12/12/12 0.3 ND ND ND ND 1.1 1 --- --- --- 04/29/13 0.3 ND ND ND ND 1.2 1 --- --- -- 08/06/13 0.3 ND ND ND ND 1.2 1 --- --- --- 02/25/14 0.3 ND ND ND ND 1.1 1 --- --- -- 08/13/14 0.3 ND ND ND ND 1.1 1 --- --- --- 03/12/15 0.3 ND ND ND ND 0.89 1 --- --- -- 08/19/15 0.3 ND ND ND ND 1.2 1 --- --- --- 02/18/16 0.3 ND ND ND ND 1 1 --- --- -- 08/11/16 0.3 ND ND ND ND 1.2 1 --- --- --- 02/15/17 0.3 ND ND ND ND 1.1 1 --- --- -- 08/24/17 0.3 ND ND ND ND 1 1 --- --- --- 02/07/18 0.3 ND ND ND ND 1.1 1 --- --- -- 08/16/18 0.3 ND ND ND ND 1.2 1 --- --- --- 02/06/19 0.29 ND ND ND ND 1.4 --- --- -- 08/07/19 0.29 ND ND ND ND 0.82 1 --- --- --- 02/14/20 0.29 ND ND ND ND 1.1 --- --- -- 08/25/20 0.29 ND ND ND ND 1.1 --- --- --- 02/10/21 0.49 ND ND ND ND ND - --- -- 08/18/21 0.34 --- --- --- --- 0.87 1 --- --- --- 02/17/22 0.34 --- --- --- -- 0.99 1 -- --- -- 09/29/221�I 0.34 ND ND ND ND 1.4 ND NA NS 03 29 23131 0.34 ND ND ND ND 1.3 ND NA NA 1,2-Dichloroethane 08/06/13 0.12 ND ND 0.62 1 ND ND --- --- -- 02/25/14 0.12 ND ND ND ND ND --- --- --- NC2L=0.4 µg/L 08/13/14 0.12 ND ND ND ND ND -- --- -- 03/12/15 0.12 ND ND ND ND ND --- --- --- 08/19/15 0.24 ND ND ND ND ND -- --- -- 02/18/16 0.24 ND ND ND ND ND --- --- --- 08/11/16 0.24 ND ND ND ND ND -- --- -- 02/15/17 0.24 ND ND ND ND ND --- --- --- 08/24/17 0.24 0.24 1 ND ND ND 0.25 1 --- --- -- 02/07/18 0.24 ND ND ND ND ND --- --- --- 08/16/18 0.24 ND ND ND ND ND -- --- -- 02/06/19 0.34 ND ND ND ND ND --- --- --- 08/07/19 0.34 ND ND ND ND ND -- --- -- 02/14/20 0.34 ND ND ND ND ND --- --- --- 08/25/20 0.34 ND ND ND ND ND --- --- --- 02/10/21 2.3 ND ND --- ND ND ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) 0.32 ND ND ND ND ND ND NA NS 03 29 23 ") 0.32 ND ND ND ND ND ND NA NA Appendix D (Page 11 of 23) �nr>,mannEck.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a ur wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL MVI-7 MW-2 MW-3RR' MW-4R MW-SR MVI-611 NES-2S NES-2D 1,3-Dichlorobenzene 07/08/08 NO NO NO 0.29 1 12/16/08 --- --- --- --- --- --- --- --- --- NC 2L 200 pg/L 07/08/09 0.24 NO NO NO 0.38 1 12/15/09 --- --- --- --- --- --- --- --- --- 06/23/10 0.24 NO NO 0.35 j 12/14/10 --- --- --- --- --- --- --- --- --- 06/21/11 0.24 NO NO ND 0.32 1 12/06/11 --- --- --- --- --- --- --- --- --- 06/13/12 0.24 NO NO NO NO 0.29 1 12/12/12 --- --- --- --- --- --- --- --- --- 04/29/13 0.24 NO NO NO NO 0.36 1 08/06/13 --- --- --- --- --- --- --- --- --- 02/25/14 0.24 NO NO NO NO 0.29 1 08/13/14 --- --- --- --- --- --- --- --- --- 03/12/15 0.24 NO NO 02/18/16 0.24 NO --- --- --- 0.31 1 08/11/16 0.24 NO NO 02/15/17 0.24 NO 0.38 1 08/24/17 0.24 NO NO 02/07/18 0.24 NO --- --- --- NO 02/06/19 0.22 NO NO NO NO 0.37 1 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.51 NO NO 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 121 NA NA NA NA NA NA NA NA NS 03/29/23 (" 1 0.34 NO NA NA NA NO NA NA NA 1,4-Dichlorobemene 09/14/94 NO NO 12/02/94 NO NO NC 2L 6 WJL 02/08/95 NO NO 03/02/95 NO NO 11/17/95 NO NO 05/23/96 NO NO 11/14/96 NO NO 06/18/97 NO NO 12/02/97 NO NO 05/27/98 NO NO 11/16/98 NO 2.2 09/10/99 NO NO ND NO 11/16/99 NO NO NO NO 05/10/00 NO NO ND NO 10/26/00 NO NO NO NO 04/18/01 NO NO ND NO 10/27/01 NO NO NO NO 06/13/02 NO NO ND NO 11/19/02 NO NO NO NO 06/27/03 NO NO ND NO 12/30/03 NO NO NO NO 06/30/04 NO NO ND NO 12/29/04 NO NO NO NO 06/29/05 NO NO ND NO 12/29/05 NO NO NO NO 06/28/06 NO NO ND NO 12/28/06 NO NO NO NO 07/12/07 NO 0.32 1 ND NO Resample 08/21/07 0.3 1 --- --- --- --- --- 12/19/07 NO 0.52 1 NO 0.71 1 07/08/08 NO NO NO 0.96 1 12/16/08 0.33 NO NO ND 0.64 1 07/08/09 0.33 NO NO NO 0.84 1 12/15/09 0.33 NO NO NO 0.76 1 06/23/10 0.33 NO NO NO 0.79 1 12/14/10 0.33 NO NO NO 0.96 B 06/21/11 0.33 NO NO NO NO 1 12/06/11 0.33 NO NO NO NO 0.81 1 06/13/12 0.33 NO NO NO NO 017 1 12/12/12 0.33 NO NO NO NO 0.83 1 04/29/13 0.33 NO NO NO NO 1 08/06/13 0.33 NO NO NO NO 1 02/25/14 0.33 NO NO NO NO 0.82 1 08/13/14 0.33 NO NO NO NO 0.97 1 03/12/15 0.33 NO ND NO ND 0.86 1 08/19/15 0.33 NO NO NO NO 1 02/18/16 0.33 NO NO NO NO 0.92 1 08/11/16 0.33 NO NO NO NO 0.93 1 02/15/17 0.33 NO NO NO ND 1.1 08/24/17 0.33 NO NO NO ND 0.81 1 02/07/18 0.33 NO ND NO ND 0.81 1 08/16/18 0.33 NO ND NO ND 1.1 02/06/19 0.26 NO ND NO ND NO 08/07/19 0.26 NO ND NO ND NO 02/14/20 0.26 NO NO NO NO NO 08/25/20 0.26 NO ND NO ND 0.79 1 02/10/21 0.41 NO NO NO NO NO 08/18/21 NA NA NA NA NA NA NA NA NA 02/17/22 0.33 ... --- ... --- 0.71 1 09/29/22 (2) 0.33 NO NO NO NO 0.96 1 NO NA NS 03/29/23 (') , 0.33 NO NO NO NO 0.94 J NO NA NA Appendix D (Page 12 of 23) 1-0 1-1 Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D 1,4-Dioxane 08/16/18 1.9 NO NO 16.5 21.2 41.6 -- -- -- 02/06/19 1.9 NO NO 21 26.8 57.9 --- --- --- NC2L=3 µg/L 08/07/19 1.9 NO NO 15.7 23.1 44.5 --- --- -- 02/14/20 1.2 --- NO 13.8 23.6 44.2 --- --- --- 08/25/20 1.2 NO NO 14.6 27.7 47.4 6.1 --- -- 02/10/21 0.12 NO --- --- --- --- --- --- --- 08/18/21 0.86 --- 11.8 -- 36.6 7 --- -- 08/19/21 0.86 --- --- --- 25.1 --- --- --- --- 02/15/22 0.86 --- --- 14.2 --- -- 9.1 --- -- 02/16/22 0.86 --- --- --- 23.7 --- --- --- --- 02/17/22 0.86 --- --- --- --- 47.4 --- --- --- 09/29/22121 0.86 1.7 J NO 70.2 19.3 65.1 31 NO NS 03 29 23131 1 0.86 NO NO 20.2 20.3 1 58.6 8.1 1 NO NO 2-Hexanone 05/27/98 --- --- NO --- --- --- 61 --- --- 11/16/98 --- --- NO --- --- --- NO --- --- NC2L=NE 09/10/99 --- --- NO NO NO NO -- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/10/00 --- --- NO NO NO NO -- --- -- 10/26/00 --- --- NO NO ND NO --- --- --- 04/18/01 --- --- NO NO ND NO -- --- -- 10/27/01 --- --- NO NO ND NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO NO -- --- -- 12/30/03 --- --- NO NO NO NO --- --- --- 06/30/04 --- -- NO NO NO NO --- --- -- 12/29/04 --- --- NO NO NO NO --- --- --- 06/29/05 --- -- NO NO NO NO -- --- -- 12/29/05 --- --- NO NO NO NO --- --- --- 06/28/06 --- NO NO NO NO --- --- -- 12/28/06 --- --- NO NO NO NO --- --- --- 07/12/07 --- --- NO NO NO NO -- --- -- 12/19/07 --- --- NO NO NO NO --- --- --- 07/08/08 --- -- NO NO NO NO --- --- -- 12/16/08 0.46 --- NO NO NO NO --- --- --- 07/08/09 0.46 -- NO NO NO NO -- --- -- 12/15/09 0.46 --- NO NO ND NO --- --- --- 06/23/10 0.46 --- NO NO NO NO -- --- -- 12/14/10 0.46 --- NO NO NO NO --- --- --- 06/21/11 0.46 NO NO NO NO NO --- --- -- 12/06/11 0.46 NO NO NO NO NO --- --- --- 06/13/12 0.46 NO NO NO NO NO --- --- -- 12/12/12 0.46 NO NO NO NO NO --- --- --- 04/29/13 0.46 NO NO NO NO NO --- --- -- 08/06/13 0.46 NO NO 0.55 J NO NO --- --- --- 02/25/14 0.46 NO NO NO NO NO --- --- -- 08/13/14 0.46 NO NO NO NO NO --- --- --- 03/12/15 0.46 NO NO NO NO NO -- --- -- 08/19/15 0.46 NO NO NO ND NO --- --- --- 02/18/16 0.46 NO NO NO ND NO --- --- -- 08/11/16 0.46 NO NO NO NO NO --- --- --- 02/15/17 0.46 NO NO NO NO NO -- --- -- 08/24/17 0.46 NO NO NO NO NO --- --- --- 02/07/18 0.46 NO NO NO NO NO --- --- -- 08/16/18 0.46 NO NO NO NO NO --- --- --- 02/06/19 0.57 NO NO NO NO NO -- --- -- 08/07/19 0.57 NO NO NO NO NO --- --- --- 02/14/20 0.57 NO NO NO NO NO --- --- -- 08/25/20 0.57 NO NO NO NO NO --- --- --- 02/30/21 0.26 NO NO --- NO NO ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212I 0.48 NO NO NO NO NO NO NA NS 03 29 23(3) 0.48 NO NO NO NO NO NO NA NA 4.4'-DDT 06/23/10 0.0037 --- NO NO NO 0.016 J --- - --- 12/14/10 ___ ___ ___ ___ ___ NO NC 2L=0.1 pg/L 06/21/11 0.0036 NO NO NO NO NO --- --- -- 12/06/11 ___ ___ ___ ___ ___ NO 06/13/12 0.05 NO NO NO NO 0.09 1 -- --- -- 12/12/12 ___ ___ ___ ___ ___ NO 04/29/13 0.05 NO NO NO NO NO --- --- -- 08/06/13 ___ ___ ___ ___ ___ NO 02/25/14 0.05 NO NO NO NO NO --- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.05 NO -- --- --- NO -- --- -- 02/18/16 0.05 NO --- --- --- NO --- --- --- 08/11/16 0.05 --- -- --- --- --- 02/15/17 0.05 NO --- --- --- NO --- --- --- 02/07/18 0.053 NO -- --- --- NO --- --- -- 02/06/19 0.05 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 NA NA NA NA NA NA NA NA NS 03 29 23131 0.026 NO NA NA NA NO NA NA NA Acetone 12/15/09 2.2 --- NO NO NO NO --- --- --- 06/23/10 2.2 --- NO NO NO NO -- --- -- NC2L=6,000 pg/L 12/14/10 2.2 NO NO NO NO --- --- --- 06/21/11 2.2 NO 3.8 B 2.8 NO NO -- --- -- 12/06/11 2.2 NO NO NO NO NO --- --- --- 06/13/12 2.2 NO NO NO NO NO -- --- -- 12/12/12 10 NO NO NO NO NO --- --- --- 04/29/13 10 NO NO NO NO NO --- --- -- 08/06/13 10 NO NO NO NO NO --- --- --- 02/25/14 10 NO NO NO NO NO --- --- -- 08/13/14 10 NO NO NO NO NO --- --- --- 03/12/15 10 NO NO NO NO NO -- --- -- 08/19/15 10 NO NO NO NO NO --- --- --- 02/18/16 30 NO NO NO NO NO --- --- -- O8/11/16 10 NO NO NO NO NO --- --- --- 02/15/17 10 NO NO NO NO NO -- --- -- O8/24/17 10 NO NO NO NO NO --- --- --- 02/07/18 10 NO NO NO NO NO --- --- -- O8/16/18 10 NO NO NO NO NO --- --- --- 02/06/19 6.2 NO NO NO NO NO -- --- -- O8/07/19 6.2 NO NO NO NO NO --- --- --- 02/14/20 6.2 NO NO NO NO NO --- --- -- O8/25/20 6.2 NO NO NO NO NO --- --- --- 02/30/21 0.27 NO NO --- NO NO NO -- -- O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 5.1 NO NO NO NO NO NS NO NS 03 29 23(3) 5.1 NO NO NO NO NO NO NA NA Appendix D (Page 13 of 23) Ana>,mann<k.snereo«�i=omn�revMa.,.��a.,,s�ana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c�nN��a co. o,ra,a uF wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Aldrin 11/17/95 -- -- NO -- -- -- NO — -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L=0.002 pg/L 03/23/98 -- -- NO -- -- -- NO --- -- 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 -- -- NO --- --- --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 -- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 -- --- --- --- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 -- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- --- --- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 -- --- -- 07/08/09 0.05 --- NO NO ND NO --- --- --- 12/15/09 -- --- -- 06/23/10 0.00053 --- NO NO NO NO --- --- --- 12/14/10 --- --- --- --- 06/21/11 0.0005 NO NO NO ND NO --- --- --- 12/06/11 --- --- --- --- 06/13/12 0.05 NO NO NO ND NO --- --- --- 12/12/12 --- --- --- --- 04/29/13 0.05 NO NO NO ND NO --- --- --- 08/06/13 --- --- --- --- 02/25/14 0.05 NO NO NO ND NO --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.05 NO --- --- --- NO --- --- --- 02/18/16 0.05 NO -- --- -- NO -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 NO -- --- -- NO --- --- -- 02/07/18 0.053 NO --- --- --- NO --- --- --- 02/06/19 0.05 NO -- --- --- NO 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 NA NA NA NA NA NA NA NA NS 03 29 23 (') 0.012 NO NA NA NA NO NA NA NA Alpha-BHC 11/17/95 --- --- NO --- --- --- NO -- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L =0.006 µg/L 03/23/98 --- --- NO --- --- -- NO --- -- 05/27/98 --- --- NO --- --- --- 0.053 --- --- 11/16/98 --- --- NO --- --- -- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO ND NO --- --- -- 05/10/00 --- --- NO NO ND NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 -- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- --- --- --- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- --- --- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 -- --- -- 07/08/09 0.05 --- NO NO ND NO --- --- --- 12/15/09 --- --- -- 06/23/10 0.00032 --- NO NO ND NO --- --- --- 12/14/10 --- --- --- --- 06/21/11 0.0003 NO NO 0.054 ND NO --- --- --- Resample 07/28/11 0.0003 --- --- NO -- -- --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.05 NO NO NO NO NO --- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.05 NO NO NO NO NO -- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.05 NO NO NO NO NO --- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.05 NO --- --- --- NO — --- -- 02/18/16 0.05 NO --- --- --- NO --- --- --- 08/11/16 0.05 --- -- --- -- -- 02/15/17 0.05 NO --- --- --- NO --- --- --- 02/07/18 0.053 NO -- --- -- NO --- --- -- 02/06/19 0.05 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 NA NA NA NA NA NA NA NA NS 03 29 231'I 1 0.01 1 NO I NA I NA I NA I NO I NA I NA I NA Appendix D (Page 14 of 23) Ana>,mann<k.snereo«�i=omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a uF wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Benzene 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L = 1 µg/L 02/08/95 -- -- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 -- - NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 -- --- NO -- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 __ --- NO --- --- __ NO --- _- 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 --- --- NO --- --- --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/10/02 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO --- --- -- 11/19/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO 7 NO -- --- -- 12/30/03 --- --- NO NO 12 NO --- --- --- 06/30/04 --- --- NO NO NO NO - --- -- 12/29/04 --- --- NO NO ND NO --- --- --- 06/29/05 --- --- NO NO NO NO - --- -- 12/29/05 --- --- NO NO ND NO --- --- --- 06/28/06 --- --- NO NO NO NO -- --- -- 12/28/06 --- --- NO NO ND NO --- --- --- 07/12/07 --- --- NO NO NO 0.4 1 --- --- -- 12/19/07 --- --- NO NO ND 0.53 1 --- --- --- 07/08/08 --- NO NO NO 0.59 1 --- --- -- 12/16/08 0.25 --- NO NO ND 0.4 1 --- --- --- 07/08/09 0.25 --- NO NO ND 0.54 1 --- --- -- 12/15/09 0.25 --- NO NO ND 0.37 1 --- --- --- 06/23/10 0.25 --- NO NO ND 0.42 1 --- --- -- 12/14/10 0.25 --- NO NO ND NO --- --- --- 06/21/11 0.25 NO NO NO ND 0.39 1 --- --- -- 12/06/11 0.25 NO NO NO ND 0.4 1 --- --- --- 06/13/12 0.25 NO NO NO ND NO --- --- -- 12/12/12 0.25 NO NO NO ND 0.41 1 --- --- --- 04/29/13 0.25 NO NO NO ND 0.33 1 --- --- -- 08/06/13 0.25 NO NO NO ND 0.4 1 --- --- --- 02/25/14 0.25 NO NO NO ND 0.4 1 --- --- -- 08/13/14 0.25 NO NO NO ND 0.41 1 --- --- --- 03/12/15 0.25 NO NO NO ND NO --- --- -- 08/19/15 0.25 NO NO NO ND 0.35 1 --- --- --- 02/18/16 0.25 NO NO NO NO NO --- --- -- 08/11/16 0.25 NO NO NO NO 0.34 1 --- --- --- 02/15/17 0.25 NO NO NO NO NO --- --- -- 08/24/17 0.25 NO NO NO NO 0.3 1 --- --- --- 02/07/18 0.25 NO NO NO NO 0.31 1 --- --- -- 08/16/18 0.25 NO NO NO ND 0.35 1 --- --- --- 02/06/19 0.15 NO NO NO NO 0.43 1 --- --- -- 08/07/19 0.15 NO NO NO NO 0.36 1 --- --- --- 02/14/20 0.15 NO NO NO NO NO --- --- -- 08/25/20 0.15 NO NO NO NO NO --- --- --- 02/30/21 1.9 NO NO --- NO NO NO --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22(2) 0.34 NO NO NO NO 0.35 1 NO NA NS 03 29 231a1 1 0.34 NO NO NO NO NO NO NA NA Bemo(g,h,i)perylene 06/21/11 0.79 NO NO NO NO 1.1 --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ --- NC 2L 200 µg/L 06/13/12 0.38 NO NO NO NO NO --- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.38 NO NO NO NO NO -- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.38 NO NO NO NO NO -- --- -- 08/13/14 --- --- --- 03/12/15 0.45 NO -- --- --- NO --- --- 02/18/16 0.38 NO --- --- --- NO --- --- --- 08/11/16 0.38 --- -- --- --- --- 02/15/17 0.38 NO --- --- --- NO --- --- --- 08/24/17 2.1 NO -- --- --- NO -- --- -- 02/07/18 2.1 NO --- --- --- NO --- --- --- 02/06/19 1.8 NO --- --- --- NO --- --- -- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�I NA NA NA NA NA NA NA NA NS 03 29 23131 2.4 NO NA NA NA NO NA NA NA Beta-BHC 06/27/03 --- --- NO 0.068 NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- --- NC2L=0.02 µg/L 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- NO NO NO ND --- --- --- 06/29/05 --- --- NO NO NO ND --- --- -- 12/29/05 --- --- NO NO NO ND --- --- --- 06/28/06 --- --- NO NO NO NO --- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- NO NO NO ND -- --- -- 12/19/07 --- --- NO NO NO ND --- --- --- 07/08/08 --- --- NO NO NO ND --- --- -- 12/16/08 0.05 --- NO NO ND NO --- --- --- 07/08/09 0.05 --- NO NO NO ND -- --- -- 12/15/09 0.01 --- NO NO NO ND --- --- --- 06/23/10 0.00053 --- NO NO NO ND 12/14/10 0.0005 --- NO NO NO ND --- --- --- 06/21/11 0.0005 NO NO NO NO NO -- --- -- 12/06/11 0.05 NO NO NO NO 0.059 --- --- --- Resample O1/25/12 0.05 NO --- --- --- 0.082 --- --- -- 06/13/12 0.05 NO NO NO NO NO --- --- --- 12/12/12 0.05 NO NO NO NO 0.078 --- --- -- 04/29/13 0.05 NO NO NO NO ND --- --- --- 08/06/13 0.05 NO NO NO NO NO -- --- -- 02/25/14 0.05 NO NO NO ND 0.056 --- --- --- 08/13/14 0.05 NO --- --- -- ND --- --- -- 03/12/15 0.05 NO --- --- --- ND --- --- --- 08/19/15 0.05 NO -- --- -- ND -- --- -- 02/18/16 0.05 NO --- --- --- ND --- --- --- 08/11/16 0.05 NO -- --- - ND --- --- -- 02/15/17 0.05 NO --- --- --- ND --- --- --- 02/07/18 0.053 NO -- --- -- ND -- --- -- 02/06/19 0.05 NO --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 0.014 NO -- --- --- 0.066 Resample 09/29/20 0.014 --- --- --- --- NO --- --- --- 02/30/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�I NA NA NA NA NA NA NA NA NS 03 29 23131 0.041 1 NO NA NA NA NO NA NA NA Appendix D (Page 15 of 23) sna>,mann<k.snereo«�i=omn�revMa.,.��a.,,ssana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a LF wn „�o:a F�9, x,�rcwMRemavom,n urn, ��awfi�.,n�.> Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Bis(2-ethylhexyl)phthalate 06/21/11 0.79 NO 2.5 1 NO 4.5 NO -- - -- 12/06/11 --- --- --- --- --- ___ ___ ___ --- NC 2L 3 µg/L 06/13/12 0.79 NO NO NO NO NO --- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.79 NO NO NO NO NO --- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.79 NO NO 40.4 5 NO --- --- -- Resample 04/15/14 0.79 --- --- NO --- --- --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.49 NO --- --- --- NO --- --- --- 02/18/16 0.85 NO -- --- -- NO --- --- -- 08/11/16 0.85 --- --- --- --- --- --- 02/15/17 0.85 NO -- --- -- NO -- --- -- 08/24/17 2.3 NO --- --- --- NO --- --- --- 02/07/18 2.3 NO -- --- -- NO --- --- -- 02/06/19 1.4 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22(2) NA NA NA NA NA NA NA NA NS 03 29 231'I 3.1 NO NA NA NA NO NA NA NA Carbon Disulfide 06/18/97 --- --- NO --- --- --- 16 --- --- 12/02/97 --- --- NO --- --- __ 23 --- __ NC 2L = 700 µg/L 05/27/98 --- --- NO --- --- --- 46 --- --- 11/16/98 --- --- NO --- --- -- 33.5 --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO ND NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO --- --- -- 06/13/02 --- --- NO NO NO NO --- --- --- 11/19/02 --- --- NO NO NO NO - --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- NO NO NO NO --- --- -- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- NO NO ND NO -- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- NO NO NO NO --- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- NO NO ND NO -- --- -- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 1.2 --- NO NO NO NO --- --- -- 07/08/09 1.2 --- NO NO NO NO --- --- --- 12/15/09 1.2 --- NO NO NO NO -- --- -- 06/23/10 1.2 --- NO NO ND NO --- --- --- 12/14/10 1.2 --- NO NO ND NO --- --- -- 06/21/11 1.2 NO NO NO ND NO --- --- --- 12/06/11 1.2 NO NO NO NO NO -- --- --- 06/13/12 1.2 NO NO NO NO NO --- --- --- 12/12/12 1.2 NO NO NO NO NO --- --- -- 04/29/13 1.2 NO NO NO NO NO --- --- --- 08/06/13 1.2 NO NO NO NO NO -- --- -- 02/25/14 1.2 NO NO NO NO NO --- --- --- 08/13/14 1.2 NO NO NO NO NO --- --- -- 03/12/15 1.2 NO NO NO ND NO --- --- --- 08/19/15 1.2 NO NO NO NO NO - --- -- 02/18/16 1.2 NO NO NO NO NO --- --- --- 08/11/16 1.2 NO NO NO NO NO - --- -- 02/15/17 1.2 NO NO NO NO NO --- --- --- 08/24/17 1.2 NO NO NO NO NO --- --- -- 02/07/18 1.2 NO ND NO ND NO --- --- --- 08/16/18 1.2 NO NO NO NO NO -- --- -- 02/06/19 0.4 NO NO NO NO NO --- --- --- 08/07/19 0.4 NO NO NO NO NO --- --- -- 02/14/20 0.4 NO NO NO NO NO --- --- --- 08/25/20 0.4 NO NO NO NO NO -- --- --- 02/10/21 0.24 NO NO --- NO NO ND --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 i'i 0.36 NO NO NO NO NO NO NA NS 03 29 23 ") 0.36 NO NO NO NO NO NO NA NA Chloride 06/23/10 5000 --- NO 37400 40000 39700 --- --- --- 12/14/10 5000 --- 5100 38400 44500 39600 -- -- --- NC2L=250,000 pg/L 06/21/11 5000 8600 NO 35800 45300 41400 --- --- --- 12/06/11 5000 9340 NO 28600 49200 39200 -- --- -- 06/13/12 1000 9410 4540 29400 49300 46400 --- --- --- 12/11/12 1000 8570 5220 30800 50600 46600 --- --- -- 04/29/13 1000 9550 4120 30000 49800 22300 --- --- --- 08/06/13 1000 7590 5180 25700 50100 48700 -- --- -- 02/25/14 1000 9140 5510 33200 60300 57400 --- --- --- 08/13/14 500 8030 4070 21300 97600 43400 --- --- -- 03/12/15 500 8840 4350 20700 51700 42600 --- --- --- 08/19/15 500 9440 5160 23200 51500 48500 -- --- -- 02/18/16 500 17200 4600 20600 69500 49700 --- --- --- 08/11/16 S00 9410 4430 23200 57300 51300 --- --- -- 02/15/17 2500 10900 4970 29300 59100 49200 1,F --- --- --- 08/24/17 500 10500 4120 21700 59300 50300 --- --- -- 02/07/18 500 10000 4790 23000 60200 58600 --- --- --- 08/15/18 500 9620 --- --- --- --- -- --- 02/06/19 500 10300 5030 22300 64600 57800 --- --- --- 08/08/19 2500 10100 7030 20400 66500 M1 54400 --- --- -- 02/14/20 500 9070 4490 17200 62300 47700 --- --- --- 08/25/20 --- 9570 16400 19000 67100 47000 160000 --- -- 02/10/21 --- 10400 --- --- --- 45800 --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 2500 --- 3980 14600 --- --- 147000 --- --- 02/16/22 3000 --- --- --- 69200 --- --- --- --- 02/17/22 600 8600 --- --- --- 43600 --- 9700 5000 09/29/22(2) 600 7600 2500 41700 69400 52300 166000 10400 NS 03 29 231'I 1 500 1 9360 1 4750 1 21600 1 70000 1 50000 1 161000 1 11300 1 8570 Appendix D (Page 16 of 23) sna>,mann<k.snereo«�i=omn�revMa.,.��a.,,ssana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a ur wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D Chlorobenzene 11/16/98 -- -- NO --- -- -- ND -- -- 09/10/99 --- --- NO NO NO NO --- --- --- NC2L=50 µg/L 11/16/99 -- -- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 -- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO ND NO --- --- --- 10/27/01 --- --- NO NO ND NO -- --- -- 06/13/02 --- --- NO NO ND NO --- --- --- 11/19/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- -0.63 NO NO NO NO --- --- --- 12/30/03 --- --- NO NO NO NO -- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- NO NO NO NO --- --- -- 06/29/05 --- --- NO NO NO NO --- --- --- 12/29/05 --- --- NO NO NO NO -- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- NO NO NO NO --- --- -- 07/12/07 --- --- NO NO NO 0.34 1 --- --- --- 12/19/07 --- --- NO 0.64 1 NO 0.44 1 --- --- -- 07/08/08 --- --- NO NO NO 0.97 1 --- --- --- 12/16/08 0.23 --- NO NO NO 0.42 1 --- --- -- 07/08/09 0.23 --- NO 0.25 1 NO 0.57 1 --- --- --- 12/15/09 0.23 --- NO 0.25 1 NO 0.49 1 --- --- -- 06/23/10 0.23 --- NO 0.26 1 NO 0.53 1 --- --- --- 12/14/30 0.23 --- NO NO NO 0.93 B --- --- -- 06/21/11 0.23 NO NO 0.27 1 NO 0.65 1 --- --- --- 12/06/11 0.23 NO NO NO NO 0.63 1 --- --- -- 06/13/12 0.23 NO NO NO NO 0.55 1 --- --- --- 12/12/12 0.23 NO NO NO NO 1 1 --- --- -- 04/29/13 0.23 NO NO NO NO 0.7 1 --- --- --- 08/06/13 0.23 NO NO NO NO 0.83 1 --- --- -- 02/25/14 0.23 NO NO NO NO 0.78 1 --- --- --- 08/13/14 0.23 NO NO NO NO 0.87 1 --- --- -- 03/12/15 0.23 NO NO NO NO 0.64 1 --- --- --- 08/19/15 0.23 NO NO NO NO 0.89 1 --- --- -- 02/18/16 0.23 NO NO NO NO 0.79 1 --- --- --- 08/11/16 0.23 NO NO NO NO 0.96 1 --- --- -- 02/15/17 0.23 NO NO NO NO 0.9 1 --- --- --- 08/24/17 0.23 NO NO NO NO 0.78 1 --- --- -- 02/07/18 0.23 NO NO NO NO 0.91 1 --- --- --- 08/16/18 0.23 NO NO NO NO 1.1 1 --- --- -- 02/06/19 0.23 NO NO NO NO 1.3 --- --- --- 08/07/19 0.23 NO NO NO NO NO --- --- -- 02/14/20 0.23 NO NO NO NO NO --- --- --- 08/25/20 0.23 NO NO NO NO 1.1 --- --- -- 02/10/21 0.29 NO NO --- NO NO NO --- --- 08/18/21 0.28 --- --- --- --- 0.9 1 --- --- -- 02/17/22 0.28 --- --- --- --- 1.2 --- --- --- 09/29/22121 0.28 NO NO 0.51 1 NO 1.9 NO NA NS 03 29 231'I 1 0.28 NO NO NO NO 1.4 NO NA NA Chloroethane 09/14/94 --- --- NO --- --- --- NO --- --- 12/02/94 --- --- NO --- -_ __ NO --- __ NC 2L=3,000 µ8/L 02/08/95 --- --- NO --- --- --- 35 --- --- 03/02/95 --- --- NO --- -_ __ 24 --_ __- 11/17/95 ___ ___ NO ___ ___ ___ 27 05/23/96 --- --- NO --- -- -- 56 --- -- 11/14/96 ___ ___ NO ___ ___ ___ NO 06/18/97 --- --- NO --- -- --- 63 --- -- 12/02/97 ___ ___ NO ___ ___ ___ 64 05/27/98 --- --- NO --- __ --- 78 --- __ 11/16/98 --- --- NO --- --- --- 36.2 --- --- 09/10/99 --- --- NO NO NO NO -- --- -- 11/16/99 --- --- NO NO ND NO --- --- --- 05/10/00 --- --- NO NO NO NO -- --- -- 10/26/00 --- --- NO NO ND NO --- --- --- 04/18/01 --- --- NO NO NO NO -- --- -- 10/27/01 --- --- NO NO ND NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 11/19/02 --- --- NO NO ND NO --- --- --- 06/27/03 --- --- NO NO NO NO -- --- -- 12/30/03 --- --- NO NO ND NO --- --- --- 06/30/04 --- --- NO NO NO NO -- --- -- 12/29/04 --- --- NO NO ND NO --- --- --- 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- NO NO ND NO --- --- --- 06/28/06 --- --- NO NO ND NO --- --- -- 12/28/06 --- --- NO NO ND NO --- --- --- 07/12/07 --- --- NO NO ND NO -- - -- 12/19/07 --- --- NO NO ND NO --- --- --- 07/08/08 --- --- NO NO ND NO --- --- -- 12/16/08 0.54 --- NO NO ND NO --- --- --- 07/08/09 0.54 --- NO NO ND NO -- --- -- 12/15/09 0.54 --- NO NO ND NO --- --- --- 06/23/10 0.54 --- NO NO ND NO --- --- -- 12/14/10 0.54 --- NO NO ND NO --- --- --- 06/21/11 0.54 NO NO NO ND NO - --- -- 12/06/11 0.54 NO NO NO ND NO --- --- --- 06/13/12 0.54 NO NO NO NO NO --- --- -- 12/12/12 0.54 NO NO NO NO NO --- --- --- 04/29/13 0.54 NO NO NO NO NO --- --- -- 08/06/13 0.54 NO NO NO ND NO --- --- --- 02/25/14 0.54 NO NO NO ND NO -- --- -- 08/13/14 0.54 NO NO NO NO NO --- --- --- 03/12/15 0.54 NO NO NO NO NO --- --- -- 08/19/15 0.54 NO NO NO NO NO --- --- --- 02/18/16 0.54 NO NO NO NO NO -- --- -- 08/11/16 0.54 NO NO NO NO NO --- --- --- 02/15/17 0.54 NO NO NO NO NO --- --- -- 08/24/17 0.54 NO NO NO NO NO --- --- --- 02/07/18 0.54 NO NO NO NO NO -- --- -- 08/16/18 0.54 NO NO NO NO NO --- --- --- 02/06/19 0.49 NO NO NO NO 0.54 1 --- --- -- 08/07/19 0.49 NO NO NO NO NO --- --- --- 02/14/20 0.49 NO NO NO NO NO --- --- -- 08/25/20 0.49 NO NO NO NO NO NO --- --- 02/30/21 0.3 NO NO --- NO NO --- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212) 0.65 NO NO NO NO NO NO NA NS 03 29 23131 0.65 NO NO NO NO NO NO NA NA Chloromethane 06/23/10 0.11 --- NO 0.12 1 NO NO --- --- -- 12/14/10 0.11 --- NO NO NO NO --- --- --- NC2L=3 µg/L 06/21/11 0.11 NO NO NO NO NO --- --- -- 12/06/11 0.11 NO NO NO NO NO --- --- --- 06/13/12 0.11 NO NO NO NO NO -- --- -- 12/12/12 0.11 NO NO NO NO NO --- --- --- 04/29/13 0.11 NO NO NO NO NO -- --- -- 08/06/13 0.11 NO NO NO NO NO --- --- --- 02/25/14 0.11 NO NO NO NO NO --- --- -- 08/13/14 0.11 NO NO NO NO NO --- --- --- 03/12/15 0.11 NO NO NO NO NO -- --- -- 08/19/15 0.11 NO NO NO NO NO --- --- --- 02/18/16 0.11 NO NO NO NO NO --- --- -- 08/11/16 0.11 NO NO NO NO 0.12 1 --- --- --- 02/15/17 0.11 NO NO NO NO NO -- --- -- 08/24/17 0.11 NO NO NO NO NO --- --- --- 02/07/18 0.11 NO NO NO NO NO -- --- -- 08/16/18 0.11 NO NO NO NO NO --- --- --- 02/06/19 0.39 NO NO NO NO NO -- --- -- 08/07/19 0.39 NO NO NO NO NO --- --- --- 02/14/20 0.39 NO NO NO NO NO -- --- -- 08/25/20 0.39 NO NO NO ND NO --- --- --- 02/10/21 0.31 NO NO NO NO NO -- -- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212I 0.54 NO NO NO NO NO ND NA NS 03 29 23131 0.54 NO NO NO NO NO ND NA NA Appendix D (Page 17 of 23) Ana>,mann<k.snereo«�L=omn�revMa.,.��a.,,s�ana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c�nN��a co. o,ra,a Lr wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-511 MW-611 NES-2S NES-2D cis-1,2-Dichloroethene 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=70 µg/L 02/08/95 -- -- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ NO 11/17/95 -- - NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ NO 11/14/96 -- --- NO --- --- -- NO --- -- 06/18/97 ___ ___ NO ___ ___ ___ NO 12/02/97 __ --- NO --- --- __ NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ 5.8 11/16/98 -- --- NO --- --- --- 3.7 --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO 7 -- --- -- 12/16/99 ___ ___ ___ ___ ___ 7 O5/10/00 --- --- NO NO NO 8 -- --- -- 10/26/00 --- --- NO NO NO 9 --- --- --- 04/18/01 --- --- NO NO NO 7 --- --- -- 10/27/01 --- --- NO NO NO 13 --- --- --- 06/10/02 -- -- NO NO NO 8 --- --- -- 06/13/02 --- --- NO NO NO 8 --- --- --- 11/19/02 -- -- NO NO NO NO -- --- -- 06/27/03 --- --- NO NO NO 12 --- --- --- 12/30/03 --- -- NO NO NO 10 --- --- -- 06/30/04 --- --- NO NO ND 9.3 --- --- --- 12/29/04 --- --- NO NO NO 9.4 --- --- -- 06/29/05 --- --- NO NO NO 8 --- --- --- 12/29/05 --- --- NO NO NO 8 -- --- -- 06/28/06 --- --- NO NO NO 8.8 --- --- --- 12/28/06 --- --- NO NO NO 6 --- --- -- 07/12/07 --- --- NO NO NO 6.2 --- --- --- 12/19/07 --- --- NO NO NO 7.2 --- --- -- 07/08/08 --- --- NO NO NO 9.8 --- --- --- 12/16/08 1.9 --- NO NO 0.91 4.2 1 --- --- -- 07/08/09 0.19 --- NO NO NO 7.7 --- --- --- 12/15/09 0.19 --- NO NO NO 7.4 --- --- --- 06/23/10 0.19 --- NO NO NO 7.1 --- --- --- 12/14/10 0.19 --- NO NO NO NO -- --- -- 06/21/11 0.19 NO NO NO NO 6.4 --- --- --- 12/06/11 0.19 NO NO NO NO 3 1 --- --- --- 06/13/12 0.19 NO NO NO NO 4.3 1 --- --- --- 12/12/12 0.19 NO NO NO NO 3.3 1 --- --- -- 04/29/13 0.19 NO NO NO NO 4.8 1 --- --- --- 08/06/13 0.19 NO NO NO ND 3.6 1 --- --- --- 02/25/14 0.19 NO NO NO ND 3.7 1 --- --- --- 08/13/14 0.19 NO NO NO ND 2.8 1 --- --- -- 03/12/15 0.19 NO NO NO NO 2.6 1 --- --- --- 08/19/15 0.19 NO NO NO ND 3.1 1 --- --- -- 02/18/16 0.19 NO NO NO ND 2.5 1 --- --- --- 08/11/16 0.19 NO NO NO ND 2.7 1 --- --- -- 02/15/17 0.19 NO NO NO NO NO --- --- --- 08/24/17 0.19 NO NO NO NO 1.4 1 --- --- -- 02/07/18 0.19 NO NO NO NO 0.79 1 --- --- --- 08/16/18 0.19 NO NO NO NO 1.2 1 --- --- -- 02/06/19 0.29 NO NO NO NO 0.79 1 --- --- --- 08/07/19 0.29 NO NO NO NO 0.86 1 --- --- -- 02/14/20 0.29 NO NO NO NO 0.86 1 --- --- --- 08/25/20 0.29 NO NO NO NO 0.65 1 --- --- --- 02/10/21 3.3 NO --- --- NO NO NO --- --- 08/18/21 0.38 --- --- --- --- -- 0.83 1 --- -- 02/15/22 0.38 --- --- --- --- --- 0.82 1 --- --- 09/29/22i21 0.38 NO NO NO ND 1.9 0.97 1 NA NS 03 29 23 i'I1 0.38 NO NO NO NO NO NO NA NA Dibenz(a,h)anthracene 06/21/11 0.79 NO NO NO NO 1.2 1 --- --- --- 12/06/11 --- --- - --- ... NC2L=0.005 µg/L 06/13/12 0.55 NO ND NO NO NO --- --- --- 12/12/12 --- --- -- --- 04/29/13 0.55 NO ND NO NO NO --- --- --- 08/06/13 --- --- -- --- 02/25/14 0.55 NO ND NO ND NO --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.49 NO --- --- --- NO --- --- --- 02/18/16 0.55 NO -- --- -- NO --- --- -- 08/11/16 0.55 --- --- --- --- --- --- 02/15/17 0.55 NO -- -- -- NO -- --- -- 08/24/17 2 NO --- --- --- NO --- --- --- 02/07/18 2.1 NO --- -- --- NO --- --- -- 02/06/19 1.9 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 i21 NA NA NA NA NA NA NA NA NS 03 29 23 i'I 3.0 NO NA NA NA NO NA NA NA Dichlorodifluoromethane 11/17/95 --- --- NO --- --- --- NO --- --- 12/02/97 --- --- NO --- --- -_ NO --- __ NC 2L=1,000 µg/L 03/23/98 --- --- NO --- --- --- 6 --- --- 05/27/98 --- --- NO --- --- -- NO --- __ 11/16/98 --- --- NO --- --- --- NO --- --- 09/10/99 --- --- NO NO NO NO --- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/10/00 --- --- NO NO ND NO -- --- -- 10/26/00 --- --- NO NO ND NO --- --- --- 04/18/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- NO NO NO NO --- --- --- 06/27/03 --- --- NO NO NO NO --- --- -- 12/30/03 --- --- --- --- --- ___ ___ ___ ___ 06/30/04 --- --- NO NO NO NO --- --- -- 12/29/04 --- --- --- --- --- ___ ___ ___ ___ 06/29/05 --- --- NO NO NO NO -- --- -- 12/29/05 --- --- --- --- --- ___ ___ ___ ___ 06/28/06 --- --- NO NO NO NO --- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- NO NO NO NO --- --- -- 12/19/07 --- --- --- --- --- ___ ___ ___ ___ 07/08/08 --- --- NO NO NO NO --- --- -- 12/16/08 ___ ___ NO ___ ___ ___ ___ ___ ___ 07/08/09 0.21 --- NO NO NO 0.37 1 --- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/10 0.21 -- NO NO NO 0.29 1 --- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.21 NO NO NO NO 0.36 1 --- --- --- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.21 NO NO NO NO NO -- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.21 NO NO NO NO NO -- --- --- 08/06/13 --- --- --- --- --- ___ ___ ___ ___ 02/25/14 0.21 NO NO NO NO NO --- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.21 NO --- --- --- NO --- --- -- 02/18/16 0.21 NO --- --- --- NO --- --- --- 08/11/16 0.21 --- --- --- -- -- 02/15/17 0.21 NO --- --- --- NO --- --- --- 08/24/17 0.21 NO --- --- -- NO -- --- -- 02/07/18 0.21 NO --- --- --- NO --- --- --- 02/06/19 0.23 NO NO NO NO NO -- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.21 NO --- --- --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) NA NA NA NA NA NA NA NA NS 03 29 23 (') 0.35 NO NA NA NA NO NA NA NA Appendix D (Page 18 of 23) Ana>,mann<k.snereo«�i=omn�revMa.,.��a.,,s�ana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c�nN��a co. o,ra,a ur wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-511 MW-6R NES-2S NES-21) Dieldrin 11/17/95 -- --- ND -- -- -- ND - -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=0.002 µg/L 03/23/98 -- --- ND -- -- -- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 -- --- ND --- --- -- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND --- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND -- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 --- --- --- --- --- --- --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- -- 06/29/05 --- --- ND ND ND ND --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- ND ND ND ND --- --- --- 12/28/06 -- --- -- 07/12/07 --- --- ND ND ND ND --- --- --- 12/19/07 --- --- --- --- --- 07/08/08 --- --- ND ND ND ND --- --- --- 12/16/08 --- --- --- --- --- --- -- --- -- 07/08/09 0.05 --- ND ND ND ND --- --- --- 12/15/09 --- --- --- --- --- --- -- --- -- 06/23/10 0.00053 --- ND ND ND ND --- --- --- 12/14/10 --- --- --- --- 06/21/11 0.0005 ND ND ND ND ND --- --- --- 12/06/11 --- --- -- --- 06/13/12 0.05 ND ND ND ND ND --- --- --- 12/12/12 --- --- __ --- __ ND --- --- __ 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- --- __ --- __ ND 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND -- --- -- ND -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND -- --- - ND --- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND -- --- --- ND 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 NA NA NA NA NA NA NA NA NS 03 29 23131 0.012 ND NA NA NA ND NA NA NA Diethylphthalate 11/17/95 --- --- ND --- --- --- ND -- -- 12/02/97 ___ ___ ND ___ ___ ___ ND NC 2L=6,000 µel- 03/23/98 --- --- ND --- --- -- ND --- -- 05/27/98 ___ ___ ND ___ ___ ___ ND 11/16/98 --- --- ND --- -- -- ND --- -- 09/10/99 --- --- ND ND ND ND --- --- --- 11/16/99 --- --- ND ND ND ND -- --- -- 05/10/00 --- --- ND ND ND ND --- --- --- 10/26/00 --- --- ND ND ND ND -- --- -- 04/18/01 --- --- ND ND ND ND --- --- --- 06/13/02 --- --- ND ND ND ND --- --- -- 06/27/03 --- --- ND ND ND ND --- --- --- 12/30/03 -- --- --- -- 06/30/04 --- --- ND ND ND ND --- --- --- 12/29/04 --- --- --- --- 06/29/05 --- --- ND ND ND ND --- --- --- 06/28/06 --- --- ND ND ND ND -- --- -- 12/28/06 --- --- --- --- --- ___ ___ ___ ___ 07/12/07 --- --- ND ND ND ND --- --- -- 12/19/07 --- --- --- --- --- ___ ___ ___ ___ 07/08/08 --- --- ND ND ND ND -- --- -- 12/16/08 --- --- --- --- --- ___ ___ ___ ___ 07/08/09 2.7 --- --- ND ND ND --- --- -- 12/15/09 --- --- --- --- --- ___ ___ ___ ___ 06/23/10 3.9 --- ND ND ND ND -- --- -- 12/14/10 --- --- --- --- --- ___ ___ ___ ___ 06/21/11 0.58 ND ND ND ND ND --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ ___ 06/13/12 0.58 ND ND ND ND ND -- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ --- 04/29/13 0.58 ND ND ND ND ND --- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ --- 02/25/14 0.58 ND ND ND ND ND -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.91 ND -- --- -- ND --- --- -- 02/18/16 1.3 ND --- --- --- ND --- --- --- 08/11/16 1.3 --- -- --- -- -- 02/15/17 1.3 ND --- --- --- ND --- --- --- 08/24/17 1.6 ND -- --- --- ND --- --- -- 02/07/18 1.7 ND --- --- --- ND --- --- --- 02/06/19 2 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221'1 NA NA NA NA NA NA NA NA NS 03 29 23(3) 1.7 ND NA NA NA ND NA NA NA Endosulfan 1 06/21/11 0.0007 ND ND 0.52 ND ND --- --- -- Resample 07/28/11 0.0007 --- --- ND --- --- --- --- --- NC2L=40 µg/L 12/06/11 --- --- --- ND --- -- --- --- _- 06/13/12 0.05 ND ND 0.33 ND ND --- --- --- 12/12/12 0.05 ND ND 1.33 ND ND - --- -- 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 0.05 ND ND ND ND ND -- --- -- 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 0.05 ND --- --- --- ND 03/12/15 0.05 ND --- --- --- ND --- --- --- 08/19/15 0.05 ND -- --- --- ND --- --- -- 02/18/16 0.05 ND --- --- --- ND --- --- --- 08/11/16 0.05 ND -- --- --- ND 02/15/17 0.05 ND --- --- --- ND --- --- --- 02/07/18 0.053 ND -- --- --- ND 02/06/19 0.05 ND --- --- --- ND --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 0.0094 ND -- --- --- 0.036 J --- --- --- 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22M NA NA NA NA NA NA NA NA NS 03 29 23131 0.014 ND NA NA NA ND NA NA NA Endosulfan Sulfate 06/13/12 0.05 ND ND 0.09 1 ND ND --- --- --- 12/12/12 --- --- --- ND --- --- --- _- NC2L=40 µg/L 04/29/13 0.05 ND ND ND ND ND --- --- --- 08/06/13 --- --- --- --- --- ND 02/25/14 0.05 ND ND ND ND ND --- --- --- 08/13/14 --- --- --- --- 03/12/15 0.05 ND --- --- --- ND --- --- --- 02/18/16 0.05 ND --- --- -- ND -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 ND --- --- -- ND --- --- -- 02/07/18 0.053 ND --- --- --- ND --- --- --- 02/06/19 0.05 ND --- --- -- ND --- --- -- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�1 NA NA NA NA NA NA NA NA NS 03 29 23131 0.012 1 ND I NA I NA I NA I ND I NA I NA I NA Appendix D (Page 19 of 23) sna>,mann<k.snereo«�i=omn�revMa.,.��a.,,ssana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a ur 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-2D Heptachlor 11/17/95 -- --- NO -- -- -- NO -- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L=0.008 µg/L 03/23/98 -- --- NO -- -- -- NO --- -- 05/27/98 ___ ___ NO ___ ___ ___ NO 11/16/98 -- --- NO --- --- --- NO --- -- 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 -- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 -- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 06/13/02 -- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 -- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 _- --- --- --- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- NO NO NO NO --- --- --- 12/28/06 --- --- NO NO ND NO -- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- --- --- 07/08/08 --- --- NO NO NO NO --- --- --- 12/16/08 --- --- -- 07/08/09 0.05 --- NO NO ND NO --- --- --- 12/15/09 -- -- --- -- 06/23/10 0.0016 --- NO NO NO NO --- --- --- 12/14/10 --- --- --- --- ... _. 06/21/11 0.0015 NO NO NO NO NO --- --- --- 12/06/11 --- --- --- --- 06/13/12 0.05 NO NO NO ND NO --- --- --- 12/12/12 ... ... ... NO _- -- _- -- _- 04/29/13 0.05 NO NO NO NO NO --- --- --- 08/06/13 --- --- --- --- _- NO ... ... __ 02/25/14 0.05 NO NO NO ND NO --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.05 NO --- --- --- NO --- --- --- 02/18/16 0.05 NO -- --- -- NO -- --- -- 08/11/16 0.05 --- --- --- --- --- --- 02/15/17 0.05 NO -- --- -- NO --- --- -- 02/07/18 0.053 NO --- --- --- NO --- --- --- 02/06/19 0.05 NO -- --- --- NO 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/2212) NA NA NA NA NA NA NA NA NS 03 29 23(a) 0.016 NO NA NA NA NO NA NA NA Indeno(1,2,3-cd)pyrene 06/21/11 0.79 NO NO NO NO 1.2 1 --- --- -- 12/06/11 --- --- --- --- --- ___ ___ ___ --- NC 2L 0.05 µg/L 06/13/12 0.29 NO NO NO NO NO --- --- -- 12/12/12 --- --- --- --- --- ___ ___ ___ ___ 04/29/13 0.29 NO NO NO NO NO --- --- -- 08/06/13 --- --- --- --- --- ___ ___ ___ --- 02/25/14 0.29 NO -- NO NO NO -- --- -- 08/13/14 --- --- --- --- --- ___ ___ ___ ___ 03/12/15 0.53 NO -- --- --- NO --- --- -- 02/18/16 0.29 NO --- --- --- NO --- --- --- 08/11/16 0.29 --- -- --- -- -- 02/15/17 0.29 NO --- --- --- NO --- --- --- 08/24/17 2 NO -- --- -- NO -- --- -- 02/07/18 2.1 NO --- --- --- NO --- --- --- 02/06/19 1.7 NO -- --- -- NO -- --- -- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/08/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�1 NA NA NA NA NA NA NA NA NS 03 29 23131 2.4 NO NA NA NA NO NA NA NA Methane 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 3.4 --- --- --- --- 95 ... ... _. 02/10/21 3.4 NO --- --- --- 110 --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA NC 2L=NE 02/17/22 3.4 --- --- --- --- 81.6 --- 28.2 --- 09/29/22121 2 NO NA NA NA 63 NA 74 NS 03 29 231'I 2.0 NO NA NA NA 31 NA 120 NO Methoxychlor 11/17/95 --- --- NO --- --- --- NO --- --- 12/02/97 ... ... NO ... ... _. NO ... __ NC 2L=40 µg/L 03/23/98 --- --- NO --- --- --- NO --- --- 05/27/98 ... ... NO ... ... _. NO 11/16/98 ___ ___ NO ___ ___ ___ NO 09/10/99 --- --- NO NO ND NO --- --- -- 11/16/99 --- --- NO NO ND NO --- --- --- 05/10/00 --- --- NO NO ND NO -- --- -- 10/26/00 --- --- NO NO ND NO --- --- --- 04/18/01 --- --- NO NO ND NO -- --- -- 06/13/02 --- --- NO NO ND NO --- --- --- 12/30/03 --- --- -- 06/30/04 --- --- NO NO ND NO --- --- --- 12/29/04 --- --- --- --- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- NO NO ND NO --- --- --- 12/28/06 -- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 -- --- -- 07/08/08 --- --- NO NO ND NO --- --- --- 12/16/08 -- -- --- -- 07/08/09 0.5 --- NO NO ND NO --- --- --- 12/15/09 --- -- --- -- 06/23/10 0.0074 --- NO NO ND NO --- --- --- 12/14/10 --- --- --- --- 06/21/11 0.007 NO NO NO NO NO --- --- --- 12/06/11 --- --- --- --- 06/13/12 0.15 NO NO NO NO NO --- --- --- 12/12/12 ... ... ... NO _- --- --- --- _- 04/29/13 0.15 NO NO NO NO NO --- --- --- 08/06/13 --- --- _. --- _- NO 02/25/14 0.15 NO NO NO NO NO --- --- --- 08/13/14 --- --- --- --- 03/12/15 0.15 NO --- --- --- NO --- --- --- 02/18/16 0.15 NO -- --- --- NO -- --- -- 08/11/16 0.15 --- --- --- --- --- --- 02/15/17 0.15 NO -- --- --- NO --- --- -- 02/07/18 0.16 NO --- --- --- NO --- --- --- 02/06/19 0.15 NO -- --- --- NO --- --- -- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA O8/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA O8/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/221�1 NA NA NA NA NA NA NA NA NS 03 29 23131 0.035 NO NA NA NA NO NA NA NA Appendix D (Page 20 of 23) Ana>,mann<k.snereo«�i=omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a ur 0„ 1Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-511 MW-6R NES-2S NES-2D Methylene Chloride 09/14/94 -- -- NO -- -- -- NO -- -- 12/02/94 ___ ___ NO ___ ___ ___ NO NC 2L=5 µg/L 02/08/95 -- -- NO -- -- -- NO --- -- 03/02/95 ___ ___ NO ___ ___ ___ 6 11/17/95 -- -- NO -- -- -- NO --- -- 05/23/96 ___ ___ NO ___ ___ ___ 17 11/14/96 -- -- NO --- -- -- 8.2 --- -- 06/18/97 ___ ___ NO ___ ___ ___ 12 12/02/97 __ --- NO --- __ --- NO --- __ 05/27/98 ___ ___ NO ___ ___ ___ 15 11/16/98 -- -- NO --- -- --- NO --- -- 09/10/99 --- --- NO NO ND NO --- --- --- 11/16/99 --- --- NO NO ND NO --- --- -- 05/10/00 --- --- NO NO ND NO --- --- --- 10/26/00 --- --- NO NO ND NO -- --- -- 04/18/01 --- --- NO NO ND NO --- --- --- 10/27/01 --- --- NO NO ND NO -- --- -- 06/13/02 --- --- NO NO ND NO --- --- --- 11/19/02 --- --- NO NO ND NO --- --- -- 06/27/03 --- --- NO NO ND NO --- --- --- 12/30/03 --- --- NO NO ND NO --- --- -- 06/30/04 --- --- NO NO ND NO --- --- --- 12/29/04 --- --- NO NO ND NO -- --- -- 06/29/05 --- --- NO NO ND NO --- --- --- 12/29/05 --- --- NO NO ND NO -- --- -- 06/28/06 --- --- NO NO ND NO --- --- --- 12/28/06 --- --- NO NO ND NO --- --- -- 07/12/07 --- --- NO NO ND NO --- --- --- 12/19/07 --- --- NO NO ND NO -- --- -- 07/08/08 --- --- NO NO ND NO --- --- --- 12/16/08 0.97 --- NO NO ND NO --- --- -- 07/08/09 0.97 --- NO NO ND NO --- --- --- 12/15/09 0.97 --- NO NO ND NO -- --- -- 06/23/10 0.97 --- NO NO ND NO --- --- --- 12/14/10 0.97 --- NO NO ND NO --- --- -- 06/21/11 0.97 NO NO NO ND NO --- --- --- 12/06/11 0.97 NO NO NO ND NO -- --- -- 06/13/12 0.97 NO NO NO INC, NO --- --- --- 12/12/12 0.97 NO NO NO ND NO --- --- -- 04/29/13 0.97 NO NO NO ND NO --- --- --- 08/06/13 0.97 NO NO NO NO NO -- --- -- 02/25/14 0.97 NO NO NO NO NO --- --- --- 08/13/14 0.97 NO NO NO NO NO --- --- -- 03/12/15 0.97 NO NO NO NO NO --- --- --- 08/19/15 0.97 NO NO NO NO NO -- --- -- 02/18/16 0.97 NO NO NO NO NO --- --- --- 08/11/16 0.97 NO NO NO NO NO -- --- -- 02/15/17 0.97 NO NO NO ND NO --- --- --- 08/24/17 0.97 NO NO NO NO NO -- --- -- 02/07/18 0.97 NO ND NO NO NO --- --- --- 08/16/18 0.97 NO NO NO ND NO -- --- -- 02/06/19 3.7 NO ND NO NO NO --- --- --- 08/07/19 3.7 NO NO NO ND NO --- --- -- 02/14/20 3.7 NO ND NO ND NO --- --- 08/25/20 3.7 3.7 NO ND NO ND NO -- --- -- 02/10/21 0.24 NO --- --- ND NO ND --- --- 08/19/21 --- --- __ --- --- --- 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) 2 NO NO NO NO NO NO NA INS 03 29 231'I 2.0 NO 4.0 J,e NO 4.0 J,B NO NO NA NA Naphthalene 07/08/08 --- --- NO ND NO ND --- --- --- 12/16/08 --- --- -- NC2L=6 pg/L 07/08/09 0.24 --- NO NO NO NO --- --- --- 12/15/09 --- --- --- --- 06/23/10 0.24 --- NO NO NO ND --- --- --- 12/14/10 --- --- --- --- 06/21/11 0.24 NO NO NO NO ND --- --- --- 12/06/11 --- --- --- --- 06/13/12 0.24 NO NO NO NO NO --- --- --- 12/12/12 --- --- --- --- 04/29/13 0.24 NO NO NO NO NO --- --- --- 08/06/13 --- --- --- --- 02/25/14 0.24 ND NO NO ND NO --- --- --- 08/13/14 --- --- --- 03/12/15 0.24 NO --- --- --- NO --- --- --- 02/18/16 0.24 NO -- --- -- NO --- --- -- 08/11/16 0.24 --- --- --- --- --- --- 02/15/17 0.24 NO -- --- --- NO -- --- -- 08/24/17 0.24 NO --- --- --- NO --- --- --- 02/07/18 0.24 NO --- --- --- NO --- --- -- 02/06/19 0.35 NO NO NO NO NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 0.22 NO --- --- --- --- --- --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) NA NA NA NA NA NA NA NA INS 03 29 231'I 0.64 NO NA NA NA NO NA NA NA Phorate 11/17/95 --- --- NO --- --- --- NO --- --- 12/02/97 --- --- NO --- --- --- NO --- __ NC 2L=1 µg/L 11/16/98 --- --- NO --- --- --- NO --- --- 09/10/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO 1 NO 0.8 --- --- --- 10/26/00 --- --- NO 5.2 NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- --- --- --- --- --- --- -- 06/30/04 --- --- NO NO NO NO --- --- --- 12/29/04 --- --- --- --- --- 06/29/05 --- --- NO NO NO NO --- --- --- 12/29/05 --- --- -- 06/28/06 --- --- NO NO ND NO --- --- --- 12/28/06 -- --- -- 07/12/07 --- --- NO NO NO NO --- --- --- 12/19/07 -- --- -- 07/08/08 --- --- NO NO ND NO --- --- --- 12/16/08 --- --- -- 07/08/09 6.6 --- --- NO ND NO --- --- --- 12/15/09 --- --- -- 06/23/10 7.7 --- NO NO NO NO --- --- --- 12/14/10 --- --- --- --- --- 06/21/11 5.4 ND NO NO ND NO --- --- --- 12/06/11 --- --- --- --- 06/13/12 5.4 NO NO NO ND NO --- --- --- 12/12/12 --- --- --- --- --- 04/29/13 5.4 NO NO NO ND NO --- --- --- 08/06/13 --- --- --- --- 02/25/14 5.4 NO NO NO INC, NO --- --- --- 08/13/14 --- --- -- --- 03/12/15 0.83 NO --- --- --- NO --- --- --- 02/18/16 1.1 NO -- --- - NO -- --- -- 08/11/16 1.1 --- --- --- --- --- --- 02/15/17 1.1 NO -- --- --- NO --- --- -- 08/24/17 1.7 NO --- --- --- NO --- --- --- 02/07/18 1.8 NO --- --- --- NO --- --- -- 02/06/19 1.1 NO --- --- --- NO --- --- --- 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 (2) NA NA NA NA NA NA NA NA INS 03 29 231'I 3.0 NO NA NA NA NO NA NA NA Appendix D (Page 21 of 23) >,mann<k.snereo«�n�omn�revMa.,.��a.,,s�ana c«�m.�waa.Mes Pros«.,,camna Moo�.,cMww-c��N��a co. o,ra,a uF wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-4R MW-5R MW-6R NES-2S NES-21) Sulfate 06/23/10 -- -- 14800 7180 9140 ND -- -- -- 12/14/10 --- --- 14500 9210 9700 ND --- --- --- NC2L=250,000 pg/L 06/21/11 --- 24400 11400 7490 7740 NO -- -- -- 12/06/11 5000 39800 13800 8000 7730 NO --- --- --- 06/13/12 2000 25400 J 13700 1 8140 1 8400 1 2790 1 --- --- -- 12/11/12 2000 28000 J 14800 J 9120 J 10100 1 4420 1 --- --- --- 04/29/13 2000 26100 J 12300 1 9150 1 17100 J 2730 1 --- --- -- 08/06/13 2000 25300 J 7370 J 7830 1 11700 J 2760 1 --- --- --- 02/25/14 2000 28900 J 11200 1 8130 1 9550 1 2590 1 --- --- -- 08/13/14 1000 31900 J 9370 J 7910 1 11600 J 2450 1 --- --- --- 03/12/15 1000 32600 J 12100 J 8040 1 8340 1 3400 1 --- --- -- 08/19/15 10000 42900 J 10200 J 8110 1 10400 J 2890 1 --- --- --- 02/18/16 2000 39300 J 11200 J 7960 1 10300 J 3830 1 --- --- -- 08/11/16 5000 112000 J 8500 J 7700 J 10300 J 3100 1 --- --- --- 02/15/17 1000 47100 J 11200 J 7860 J 7940 1 3510 1 --- --- -- 08/24/17 500 49700 J 9940 J 8310 J 9260 1 6680 J --- --- --- 02/07/18 500 42800 J 7990 1 6650 J 6110 1 4000 1 --- --- -- 08/15/18 500 55200 J 7690 J 7130 J 6470 1 4200 1 --- --- --- 02/06/19 500 55700 12100 7360 9440 4350 -- --- -- 08/08/19 500 51500 9890 7450 7570 6710 --- --- --- 02/14/20 500 52000 8990 6370 9410 5960 - -- -- 08/25/20 500 53300 7420 6680 7850 7000 4610 --- --- 02/10/21 500 65500 --- --- --- 8500 --- --- -- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 500 --- 8380 6760 --- --- 6150 --- --- 02/16/22 500 --- --- --- 8370 --- --- --- --- 02/17/22 500 57500 --- --- --- 8500 --- 23300 50100 09/29/22121 1000 41200 6700 42400 23700 8500 8500 30100 INS 03 29 23 n1 500 47700 9730 2870 10300 8200 7690 31600 42000 Toluene 06/18/97 --- --- NO --- -- -- NO --- -- 12/02/97 ___ ___ NO ___ ___ ___ NO NC 2L=600 pg/L 05/27/98 --- --- NO --- --- -- NO --- -- 11/16/98 --- --- NO --- --- --- NO --- --- 09/10/99 --- --- 7 NO NO NO --- --- -- 10/19/99 ___ ___ NO ___ ___ ___ ___ ___ ___ 11/16/99 --- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- -- 04/18/01 --- --- NO NO NO NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- NO NO NO NO --- --- --- 11/19/02 --- --- NO NO NO NO --- --- -- 06/27/03 --- --- NO NO NO NO --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- ND NO ND NO --- --- --- 12/29/04 --- --- NO NO NO NO -- --- -- 06/29/05 --- --- ND NO ND NO --- --- --- 12/29/05 --- --- NO NO NO NO --- --- -- 06/28/06 --- --- ND NO ND NO --- --- --- 12/28/06 --- --- NO NO NO NO -- --- -- 07/12/07 --- --- ND NO ND NO --- --- --- 12/19/07 --- --- NO NO NO NO --- --- -- 07/08/08 --- --- NO NO ND NO --- --- --- 12/16/08 0.26 --- NO NO NO NO -- --- -- 07/08/09 0.26 --- ND NO ND NO --- --- --- 12/15/09 0.26 --- NO NO NO NO --- --- -- 06/23/10 0.26 --- NO NO NO NO --- --- --- 12/14/10 0.26 NO NO NO NO -- --- -- 06/21/11 0.26 NO NO NO NO NO --- --- --- 12/06/11 0.26 NO NO NO NO NO --- --- -- 06/13/12 0.26 NO NO NO NO NO --- --- --- 12/12/12 0.26 NO NO NO NO NO -- --- -- 04/29/13 0.26 NO NO NO NO NO --- --- --- 08/06/13 0.26 NO NO NO NO NO -- --- -- 02/25/14 0.26 NO NO NO NO NO --- --- --- 08/13/14 0.26 NO NO ND NO NO --- --- -- 03/12/15 0.26 NO NO ND NO ND --- --- --- 08/19/15 0.26 NO NO ND NO ND -- --- -- 02/18/16 0.26 NO NO ND NO ND --- --- --- 08/11/16 0.26 NO NO NO NO NO --- --- -- 02/15/17 0.26 NO NO ND NO ND --- --- --- 08/24/17 0.26 NO NO NO NO NO -- --- -- 02/07/18 0.26 NO NO NO NO NO --- --- --- 08/16/18 0.26 NO NO NO NO NO --- --- --- 02/06/19 0.24 NO NO NO NO ND --- --- --- 08/07/19 0.24 NO NO NO NO NO -- --- -- 02/14/20 0.24 NO NO NO NO ND --- --- --- 08/25/20 0.24 NO NO NO NO NO --- --- -- 02/10/21 0.26 NO --- --- NO ND NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 0.48 NO NO NO NO NO NO NA INS 03 29 231'I 0.24 NO NO NO NO NO NO NA NA Trans-1,4-Dichloro-2-Butene 05/27/98 --- --- NO --- --- --- 6.9 --- --- 11/16/98 --- --- NO --- --- --- NO --- -- NC2L=NE 09/10/99 --- --- NO NO NO NO --- --- --- 11/16/99 --- --- NO NO NO NO --- --- -- 05/10/00 --- --- NO ND NO NO --- --- --- 10/26/00 --- --- NO NO NO NO -- --- --- 04/18/01 --- --- NO ND NO NO --- --- --- 10/27/01 --- --- NO NO NO NO -- --- -- 06/13/02 --- --- NO ND NO NO --- --- --- 11/19/02 --- --- NO NO NO NO -- --- -- 06/27/03 --- --- NO ND NO ND --- --- --- 12/30/03 --- --- NO NO NO NO -- --- --- 06/30/04 --- --- NO ND NO NO --- --- --- 12/29/04 --- --- NO NO NO NO -- --- -- 06/29/05 --- --- NO ND NO NO --- --- --- 12/29/05 --- --- NO NO NO NO -- --- -- 06/28/06 --- --- NO ND NO NO --- --- --- 12/28/06 --- --- NO NO NO NO -- --- -- 07/12/07 --- --- NO ND NO NO --- --- --- 12/19/07 -- --- NO NO NO NO -- --- -- 07/08/08 --- --- NO ND NO NO --- --- --- 12/16/08 1 --- NO NO NO NO -- --- -- 07/08/09 1 --- NO ND NO NO --- --- --- 12/15/09 1 --- NO NO NO NO --- --- -- 06/23/10 1 --- NO ND NO NO --- --- --- 12/14/10 1 --- NO NO NO NO -- --- -- 06/21/11 1 NO NO ND NO NO --- --- --- 12/06/11 1 NO NO NO NO NO --- --- -- 06/13/12 1 NO NO NO NO NO --- --- --- 12/12/12 1 NO NO NO NO NO -- --- --- 04/29/13 1 NO NO NO NO NO --- --- --- 08/06/13 1 NO NO NO NO NO --- --- -- 02/25/14 1 NO NO NO NO ND --- --- --- 08/13/14 1 NO NO NO NO ND --- --- -- 03/12/15 1 ND NO NO NO NO --- --- --- 08/19/15 1 NO NO NO NO NO --- --- -- 02/18/16 1 ND NO ND NO NO --- --- --- 08/11/16 1 ND NO NO NO NO --- --- -- 02/15/17 1 ND NO ND NO NO --- --- --- 08/24/17 1 ND NO ND NO NO -- --- -- 02/07/18 1 NO NO ND NO NO --- --- --- 08/16/18 1 NO NO NO NO NO --- --- -- 02/06/19 0.54 NO NO NO NO NO --- --- --- 08/07/19 0.5 NO NO NO NO NO -- --- -- 02/14/20 0.54 NO NO NO NO NO --- --- --- 08/25/20 0.54 NO NO NO NO NO -- --- --- 02/10/21 0.9 ND --- --- NO NO NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22121 0.56 NO NO NO NO NO NO NA INS 03 29 231'I 0.56 NO NO NO NO NO NO NA NA Appendix D (Page 22 of 23) sna>,mann<k.snereo«�i=omn�revMa.,.��a.,,ssana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c�nN��a co. o,ra,a Lr wn Hart & Hickman, PC Appendix D Summary of Historical Constituents in Groundwater Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI.004 Analyte Sample Date MDL MW-7 MW-2 MW-3RR' MW-411 MW-5R MW-611 NES-2S NES-21D Trichloroethylene 12/02/97 -- -- NO -- -- -- NO - -- 05/27/98 ___ ___ NO ___ ___ ___ NO NC 2L=3 µg/L 11/16/98 -- -- NO -- -- -- 2.9 --- -- 09/10/99 --- --- NO NO NO ND --- --- --- 11/16/99 -- --- NO NO NO NO -- --- -- 05/10/00 --- --- NO NO ND ND --- --- --- 10/26/00 --- --- NO NO ND NO --- --- -- 04/18/01 --- --- NO NO NO ND --- --- --- 10/27/01 --- --- NO NO NO NO --- --- --- 06/13/02 --- --- NO NO ND ND --- --- --- 11/19/02 --- --- NO NO ND NO --- --- -- 06/27/03 --- --- NO NO NO ND --- --- --- 12/30/03 --- --- NO NO NO NO --- --- -- 06/30/04 --- --- NO NO NO ND --- --- --- 12/29/04 --- -- NO NO ND NO --- --- --- 06/29/05 --- --- NO NO ND ND --- --- --- 12/29/05 --- --- NO NO NO NO -- --- -- 06/28/06 --- --- NO NO NO ND --- --- --- 12/28/06 --- --- NO NO NO NO --- --- -- 07/12/07 --- --- NO NO NO 0.68 1 --- --- --- 12/19/07 --- --- NO NO NO 0.64 1 --- --- -- 07/08/08 --- --- NO NO NO 0.51 1 --- --- --- 12/16/08 0.47 --- NO NO NO NO --- --- -- 07/08/09 0.47 --- NO NO NO 0.53 1 --- --- --- 12/15/09 0.47 --- NO NO NO NO -- --- -- 06/23/10 0.47 --- NO NO NO ND --- --- --- 12/14/10 0.47 --- NO NO NO NO -- --- -- 06/21/11 0.47 NO NO NO NO NO --- --- --- 12/06/11 0.47 NO NO NO NO NO -- --- -- 06/13/12 0.47 NO NO NO NO NO --- --- --- 12/12/12 0.47 NO NO NO NO NO --- --- -- 04/29/13 0.47 NO NO NO NO NO --- --- --- 08/06/13 0.47 NO NO NO NO NO --- --- -- 02/25/14 0.47 NO NO NO NO NO --- --- --- 08/13/14 0.47 NO NO NO NO NO --- --- -- 03/12/15 0.47 NO NO NO ND NO --- --- --- 08/19/15 0.47 NO NO NO NO NO -- --- -- 02/18/16 0.47 NO ND NO ND NO --- --- --- 08/11/16 0.47 NO NO NO NO NO --- --- -- 02/15/17 0.47 NO ND NO ND NO --- --- --- 08/24/17 0.47 NO NO NO ND NO -- --- -- 02/07/18 0.47 NO ND NO ND NO --- --- --- 08/16/18 0.47 NO ND NO NO NO --- --- -- 02/06/19 0.22 NO ND NO NO NO --- --- --- 08/07/19 0.22 NO NO NO NO NO -- --- -- 02/14/20 0.22 NO NO NO NO NO --- --- --- 08/25/20 0.22 NO ND NO NO NO -- --- -- 02/10/21 0.26 NO --- --- ND NO NO --- --- 08/18/21 NA NA NA NA NA NA NA NA NA 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 I:I 0.38 NO NO NO NO NO NO NA NS 03 29 23 I'I 0.38 NO NO NO NO NO NO NA NA Vinyl Chloride 09/14/94 --- --- NO --- --- --- NO --- --- 12/02/94 --- --- NO --- --- __ NO NC 2L=0.03 µg/L 02/08/95 --- --- NO --- --- --- NO --- --- 03/02/95 --- --- NO --- --- -- NO --- -- 11/17/95 ___ ___ NO ___ ___ ___ NO 05/23/96 --- --- NO --- --- -- NO --- -- 11/14/96 ___ ___ NO ___ ___ ___ NO 06/18/97 --- --- NO --- -- --- NO --- -- 12/02/97 ___ ___ NO ___ ___ ___ NO 05/27/98 --- --- NO --- __ --- NO --- __ 11/16/98 ___ ___ NO ___ ___ ___ NO 09/10/99 --- --- NO NO NO NO --- --- -- 11/16/99 --- --- NO NO NO NO --- --- --- 05/30/00 --- --- NO NO ND 12 - --- -- 10/26/00 --- --- NO NO ND NO --- --- --- 04/18/01 --- --- NO NO ND NO -- --- -- 10/27/01 --- --- NO NO ND NO --- --- --- 06/10/02 --- --- NO NO ND NO -- --- -- 06/13/02 --- --- NO NO ND NO --- --- --- 11/19/02 --- --- NO NO ND NO -- --- -- 06/27/03 --- --- NO NO ND 26.9 --- --- --- 12/30/03 --- --- NO NO ND 10 -- --- -- 06/30/04 --- --- NO NO NO 11 --- --- --- 12/29/04 --- --- NO NO NO 12 -- --- --- 06/29/05 --- --- NO NO NO 14 --- --- --- 12/29/05 --- --- NO NO NO 15 -- --- -- 06/28/06 --- --- NO NO NO 12.5 --- --- --- 12/28/06 --- --- NO NO NO 8.9 --- --- -- 07/12/07 --- --- NO NO NO 8.3 --- --- --- 12/19/07 --- --- NO ND NO 8.4 --- --- -- 07/08/08 --- --- NO NO ND 10.6 --- --- --- 12/16/08 0.62 --- NO NO NO 5 -- --- -- 07/08/09 0.62 --- NO NO NO 13.3 --- --- --- 12/15/09 0.62 --- NO NO NO 9.9 --- --- -- 06/23/10 0.62 --- NO NO NO 11.2 --- --- --- 12/14/10 0.62 --- NO NO NO 8.4 -- --- -- 06/21/11 0.62 NO NO NO NO 10.5 --- --- --- 12/06/11 0.62 NO NO NO NO 4.1 -- --- -- 06/13/12 0.62 NO NO NO NO 6.6 --- --- --- 12/12/12 0.62 NO NO NO NO 3.3 --- --- -- 04/29/13 0.62 NO NO NO NO 7.6 --- --- --- 08/06/13 0.62 NO NO NO NO 9.1 -- --- -- 02/25/14 0.62 NO NO NO NO 6.8 --- --- --- 08/13/14 0.62 NO NO NO NO 5.4 --- --- -- 03/12/15 0.62 NO NO NO NO 5.1 --- --- --- 08/19/15 0.62 NO NO NO NO 5 -- --- -- 02/18/16 0.62 NO NO NO NO 5.4 --- --- --- 08/11/16 0.62 NO NO NO NO 5.6 --- --- -- 02/15/17 0.62 NO NO NO NO 1.4 --- --- --- 08/24/17 0.62 NO NO NO NO 2.1 -- --- -- 02/07/18 0.62 NO NO NO NO 1.8 --- --- --- 08/16/18 0.62 NO NO NO NO 3.5 --- --- -- 02/06/19 0.24 NO NO NO NO 4.9 --- --- --- 08/07/19 0.24 NO NO NO NO 2.8 -- --- --- 02/14/20 0.24 NO NO NO NO 2.1 --- --- --- 08/25/20 0.24 NO NO NO NO 1.9 --- --- -- 02/10/21 0.19 NO --- --- NO 2.0 NO --- --- 08/18/21 0.39 --- --- --- -- 1.3 --- --- -- 02/17/22 0.39 --- --- --- --- 0.88 1 --- --- --- 09/29/22121 0.39 NO NO NO ND 0.59 1 NO NO NS 03 29 23 I'I 0.39 NO NO NO ND 0.81 J NO NO ND xylene(Total) 02/06/19 NA NA NA NA NA NA NA NA NA 08/08/19 NA NA NA NA NA NA NA NA NA 02/14/20 NA NA NA NA NA NA NA NA NA 08/25/20 NA NA NA NA NA NA NA NA NA 02/10/21 NA NA NA NA NA NA NA NA NA 08/18/21 0.34 --- --- 1.5 --- --- 1.6 --- --- 02/15/22 NA NA NA NA NA NA NA NA NA 09/29/22 P) 0.34 NO NO NO NO ND NO NA NS NC 2L=500 µg/L 032923 p) 0.34 NO NO NO NO ND NO NA NA Notes: Analytical results from September 1994 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report- February 2021 Event. Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event. 1. Monitoring well MW-3RR was installed in September 2022 to replace abandoned monitoring well MW-3R. Data shown in the table prior to the September 2022 monitoring event for MW-3RR was collected from abandoned monitoring well MW-3R. 2. MW-2, MW-4R, and MW-6R samples collected on 10/05/22. 3. MW-2, MW-4R, and MW-6R samples collected on 3/30/23. NC 2L Standards are the Title 15A NCAC 02L.0202 Groundwater Standards dated April 1, 2022. Bold concentrations exceed the NC21- Standard for groundwater. All concentrations are in micrograms per liter (µg/L). 1= Estimated value between the MDL and MRL; B = Analyte was detected in the associated method blank, result is expected to be biased high based on concentrations in the blank NA = not analyzed/not reported; NO = not detected; NS = not sampled; NE = not established; --- = no data; MDL = laboratory method detection limit Appendix D (Page 23 of 23) sna>,mann<k.snereo«�i=omn�revMa.,.��a.,,ssana c«�m.nwaa.Mes Pros«.,,camna Moo�.,cMww-c�nN��a co. o,ra,a Lr wn Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Inorganics Antimony 06/23/10 2.6 2.8 J ND 12/14/10 2.6 ND Dry ISTV (2) = 5,300 pg/L 06/21/11 5 NO Dry 12/06/11 5 ND ND 06/13/12 5 ND ND 12/11/12 5 NO Dry 04/29/13 5 ND ND 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 3.8 ND ND 08/19/15 3.8 NO Dry 02/18/16 3.8 ND ND 08/11/16 3.8 ND ND 02/15/17 3.9 ND ND 08/24/17 3.9 NO --- 02/06/18 3.9 NO ND 08/16/18 3.9 NO ND 02/06/19 3.9 NO ND 08/08/19 3 ND ND 02/13/20 3 ND ND 08/26/20 3 3.3 J ND 02/10/21 4.5 ND --- 08/18/21 ND ND 02/15/22 3 ND ND 09/29/22 3 ND ND 03/30/23 4.3 ND ND Arsenic 12/19/07 NR 5.3 Dry 07/08/08 NR ND Dry NC2B = 340 pg/L 12/16/08 2.7 ND ND 07/08/09 2.7 ND Dry 12/15/09 2.7 ND 2.7 J 06/23/10 2.7 9.2 J ND 12/14/10 2.7 3.1 Dry 06/21/11 5 NO Dry 12/06/11 5 ND ND 06/13/12 5 6.5 J ND 12/11/12 5 ND Dry 04/29/13 5 ND ND 08/06/13 5 5.5 J NO 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 4.9 J 2.7 J 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 6.8 J 7.3 J 02/15/17 5 ND ND 08/24/17 5 ND --- 02/06/18 5 ND ND 08/16/18 5 ND ND 02/06/19 5 ND ND 08/08/19 4.7 5.1 J ND 02/13/20 5 ND ND 08/26/20 4.7 ND ND 02/10/21 3.5 ND --- 08/18/21 ND --- 02/15/22 4.7 ND ND 09/29/22 4.7 ND ND 03/30/23 4.4 5.38 J ND Barium 09/14/94 NR 160 ND 12/02/94 NR ND ND ISTV (21 = 21,000 pg/L 02/08/95 NR ND NO 03/02/95 NR ND ND 11/17/95 NR ND NO 05/23/96 NR ND ND 11/14/96 NR 69 29 06/18/97 NR 64 25 12/02/97 NR 61 41 05/27/98 NR 130 50 11/16/98 NR 93 100 09/10/99 NR ND ND 11/16/99 NR ND NO 05/10/00 NR ND ND 10/26/00 NR ND NO 04/18/01 NR ND ND 11/19/02 NR NS ND 06/27/03 NR ND ND 12/30/03 NR NO ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR NO ND 12/29/05 NR ND ND 06/28/06 NR NO ND 12/28/06 NR 40 47.2 07/12/07 NR 66.2 J Dry 12/19/07 NR 112 Dry 07/08/08 NR 89 J Dry 12/16/08 0.2 42.1 B 54.8 J 07/08/09 0.2 101 Dry 12/15/09 0.2 36.3 B 48.4 B 06/23/10 0.2 115 B 39.1 B 12/14/10 0.2 97.4 J Dry 06/21/11 5 66.3 J Dry 12/06/11 5 59.7 J 55.3 J 06/13/12 5 161 85.4 J 12/11/12 5 71.1 J Dry 04/29/13 5 43.5 J 43.5 J 08/06/13 5 80.3 J 23.8 02/25/14 5 63.9 J 61.8 J 08/13/14 5 47.4 J 43.9 J 03/11/15 2.5 28.5 J 42.0 J 08/19/15 2.5 37 J Dry 02/18/16 2.5 58.2 J 55 J 08/11/16 2.5 175 152 02/15/17 2.5 285 38.2 J 08/24/17 2.5 31.6 J --- 02/06/18 2.5 22.4 J 33.5 J 08/16/18 2.5 19.1 J 28.3 J 02/06/19 2.5 47.6 30.7 08/08/19 1 23 17.3 02/13/20 1 18.4 26.4 08/26/20 3.5 15.5 21.3 02/10/21 4.7 ND --- 08/18/21 3.5 20.9 18.4 02/15/22 3.5 16.7 23.2 08/18/21 3.5 20.9 18.4 02/15/22 3.5 16.7 23.2 09/29/22 3.5 23.5 25.3 03/30/23 0.736 14.7 15.5 Appendix E (Page 1 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/Gar,ft d Moore)GMI-0M-G-ille Co. OM,N LF Unit 112023 First Half GW MRabl,s O#,N Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Beryllium 11/16/98 NR 1 1 09/10/99 NR ND ND NC2B = 65 pg/L 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR NO ND 06/30/04 NR NO ND 12/29/04 NR NO ND 06/29/05 NR NO ND 12/29/05 NR ND ND 06/28/06 NR NO ND 12/28/06 NR NO ND 07/12/07 NR ND Dry 12/19/07 NR 0.93 J Dry 07/08/08 NR 0.47 J Dry 12/16/08 0.1 0.21 J 0.27 J 07/08/09 0.1 0.29 J Dry 12/15/09 0.1 0.27 J 0.22 J 06/23/10 0.1 1.2 ND 12/14/10 0.1 0.78 J Dry 06/21/11 1 ND Dry 12/06/11 1 ND ND 06/13/12 1 1.5 ND 12/11/12 1 ND Dry 04/29/13 1 ND ND 08/06/13 1 ND ND 02/25/14 1 NO ND 08/13/14 1 ND ND 03/11/15 0.5 ND ND 08/19/15 0.5 NO Dry 02/18/16 0.5 NO ND 08/11/16 0.5 1.9 1.7 02/15/17 0.5 ND ND 08/24/17 0.5 NO --- 02/06/18 0.5 NO ND 08/16/18 0.5 ND ND 02/06/19 0.5 NO ND 08/08/19 0.2 ND ND 02/13/20 0.2 NO 0.46 J,B 08/26/20 0.7 ND ND 02/10/21 4.3 4.7 J --- 08/18/21 ND ND 02/15/22 0.7 NO ND 09/29/22 0.7 ND ND 03/30/23 0.33 ND ND Cadmium 11/19/02 NR ND 1 06/27/03 NR ND ND NC2B (3) = 1.02 pg/L 12/30/03 NR ND ND 06/30/04 NR NO NO 12/29/04 NR ND ND 06/29/05 NR ND NO 12/29/05 NR ND ND 06/28/06 NR ND NO 12/28/06 NR ND ND 07/12/07 NR ND Dry 12/19/07 NR NO Dry 07/08/08 NR ND Dry 12/16/08 0.5 ND ND 07/08/09 0.5 ND Dry 12/15/09 0.5 ND ND 06/23/10 0.5 ND ND 12/14/10 0.5 NO Dry 06/21/11 1 ND Dry 12/06/11 1 NO ND 06/13/12 1 ND ND 12/11/12 1 ND Dry 04/29/13 1 ND ND 08/06/13 1 NO ND 02/25/14 1 ND ND 08/13/14 1 NO ND 03/11/15 0.5 ND ND 08/19/15 0.5 ND ND 02/18/16 0.5 ND ND 08/11/16 0.5 ND ND 02/15/17 0.5 ND ND 08/24/17 0.5 ND --- 02/06/18 0.5 ND ND 08/16/18 0.5 ND ND 02/06/19 0.5 NO ND 08/08/19 0.4 ND ND 02/13/20 0.4 ND ND 08/26/20 0.4 ND ND 02/10/21 3.9 ND --- 08/18/21 0.4 0.44 J --- 02/15/22 0.4 NO ND 09/29/22 0.4 NO ND 03/30/23 0.479 NO ND Appendix E (Page 2 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/Gar,ft d Moore)GMI-0M-G-ille Co. OM,N LF Unit 112023 First Half GW MRabl,s O#,N Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Chromium 26-Oct-00 NR NO ND 06/18/97 NR 12 ND NC213 = 16 pg/L 12/02/97 NR 8 ND 05/27/98 NR 15 ND 11/16/98 NR 30 31 09/10/99 NR 24 ND 11/16/99 NR ND ND 05/10/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR NO ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR NO ND 12/29/05 NR NO ND 06/28/06 NR 12.6 ND 12/28/06 NR 4.8 J 6.1 J 07/12/07 NR ND Dry 12/19/07 NR 27.9 Dry 07/08/08 NR 19.3 Dry 12/06/08 0.4 6.4 J 8.4 J 07/08/09 0.4 12.9 Dry 12/15/09 0.4 6 J 5 J 06/23/10 0.4 41.8 4.8 J 08/12/10 0.4 44.4 NS 12/14/10 0.4 32.4 Dry 06/21/11 5 12.1 Dry 12/06/11 5 11.8 7.5 J 06/13/12 5 46.1 20.7 12/11/12 5 19.1 Dry 04/29/13 5 5.8 J 5.8 J 08/06/13 5 ND ND 02/25/14 5 13.5 13.2 08/13/14 5 10.8 10 J 03/11/15 2.5 4 J 3.1 J 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 63 55.1 09/13/16 2.5 ND DRY 02/15/17 2.5 6.1 J 7.2 J 08/24/17 2.5 7 J --- 02/06/18 2.5 2.8 J 5.4 J 08/16/18 2.5 ND 3.2 J 02/06/19 2.5 3 J ND 08/08/19 1 2.6 J 2.1 J 02/13/20 1 2 J 3.6 J 08/26/20 3.7 ND ND 02/10/21 3 NO ND 8/18/201 ND NO 02/15/22 3.7 --- 3.7 J 09/29/22 3.7 ND ND 03/30/23 1.4 2.45 J 1.75 J Cobalt 11/14/96 NR 3 ND 06/18/97 NR 3 ND ISTV (21 = 16 pg/L 12/02/97 NR ND NO 05/27/98 NR 8 5 11/16/98 NR 4.9 5.9 09/10/99 NR ND ND 11/16/99 NR ND NO 05/10/00 NR ND ND 10/26/00 NR ND NO 04/18/01 NR ND ND 11/19/02 NR ND NO 06/27/03 NR ND ND 12/30/03 NR NO NO 06/30/04 NR ND ND 12/29/04 NR ND NO 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR NO ND 12/28/06 NR NO 2.8 J 07/12/07 NR ND Dry 12/19/07 NR 34.3 Dry 07/08/08 NR 10 B Dry 12/16/08 0.6 4.8 B 5.1 B 07/08/09 0.6 7.2 J Dry 12/15/09 0.6 1.6 J 1.3 J 06/23/10 0.6 23 2.7 J 08/12/10 0.6 30.5 NS 12/14/10 0.6 27 Dry 06/21/11 5 5.4 J Dry 12/06/11 5 ND ND 06/13/12 5 12.5 6.5 J 12/11/12 5 ND Dry 04/29/13 5 10.2 10.8 08/06/13 5 9 J ND 02/25/14 5 10.1 10.6 08/13/14 5 ND ND 03/11/15 2.5 ND ND 08/19/15 2.5 ND Dry 02/18/16 2.5 ND ND 08/11/16 2.5 16.7 12.7 02/15/17 2.5 4 J ND 08/24/17 2.5 ND --- 02/06/18 2.5 ND ND 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 1.1 1.4 J ND 02/13/20 1 ND ND 08/26/20 3.6 NO ND 02/10/21 4.7 --- ND 08/18/21 ND ND 02/15/22 3.6 ND ND 09/29/22 3.6 ND ND 03/30/23 0.84 1.68 J ND Appendix E (Page 3 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/G,rreV d MwWGMI-0M - Gill, Co. OM,N LF Unit 112023 First Half GW MRabl,s O#,N Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Copper 06/18/97 NR 11 ND 12/02/97 NR 11 ND NC213 l3) = 4.63 µg/L 05/27/98 NR 21 ND 11/16/98 NR 14 16 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR NS ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR NO ND 12/28/06 NR 3 B 3.9 07/12/07 NR ND Dry 12/19/07 NR 23.7 Dry 07/08/08 0.3 14.7 Dry 12/16/08 0.3 6.4 J 8 J 07/08/09 0.3 7 J Dry 12/15/09 0.3 5.2 J 4.4 J 06/23/10 0.3 23.9 2.7 J 08/12/10 0.3 25.9 ND 12/14/10 5 21.1 Dry 06/21/11 5 7.7 J Dry 12/06/11 5 12.5 7.7 J 06/13/12 5 34.5 14.8 12/11/12 5 16.4 Dry 04/29/13 5 7.7 J 7.4 J 08/06/13 5 5.5 J ND 02/25/14 5 11.2 10.3 08/13/14 2.5 9.6 J 7.7 J 03/11/15 2.5 3.1 J 2.6 J 08/19/15 2.5 ND Dry 02/18/16 2.5 6.3 J 5.7 J 08/11/16 2.5 39.9 34.5 09/13/16 2.5 9.3 B DRY 02/15/17 2.5 5.8 J 5.2 J 08/24/17 2.5 4.5 J --- 02/06/18 2.5 6.8 J 8 J 08/16/18 2.5 3.9 J 3 J 02/06/19 2.5 ND ND 08/08/19 2.1 4.4 J 3.6 J 02/13/20 2.1 3.7 J 4.4 J 08/26/20 4.3 ND ND 02/10/21 0.7 --- ND 08/18/21 ND ND 02/15/22 4.3 ND ND 09/29/22 4.3 ND ND 03/30/23 3.68 4.13 J NO Hardness, Total (SM 23408) 02/06/19 662 38800 55700 08/08/19 131 19800 26400 02/13/20 131 16900 29200 08/26/20 131 12500 29500 02/10/21 0 15300 33800 08/18/21 131 24700 46600 09/29/22 131 32700 62300 03/30/23 198 35300 36500 Iron 08/24/17 25 9760 -- 08/16/18 25 3320 2750 NRWQC I1I = 1,000 µg/L 02/10/21 3.7 ND 08/18/21 02/15/22 -- NA NA 09/29/22 NA NA NA 03/30/23 NA NA NA Lead 26-Oct-00 NR ND ND 12/02/97 NR ND 6 NC2B (3) = 18.48 µg/L 05/27/98 NR 8 ND 11/16/98 NR 7.3 8.9 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR ND ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR NO ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR ND 4.8 J 07/12/07 NR 3.2 J Dry 12/19/07 NR ND Dry 07/08/08 NR ND Dry 12/16/08 4 ND NO 07/08/09 4 ND Dry 12/15/09 4 ND NO 06/23/10 4 9.2 J ND 12/14/10 4 5.1 J Dry 06/21/11 5 ND Dry 12/06/11 5 ND NO 06/13/12 5 14.3 5.5 J 12/11/12 5 NO Dry 04/29/13 5 ND ND 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 ND ND 08/19/15 2.5 NO Dry 02/18/16 2.5 4 J 2.6 J 08/11/16 2.5 16.6 13.6 09/13/16 2.5 4.1 J DRY 02/15/17 2.5 2.5 J 2.5 J 08/24/17 2.5 2.5 J --- 02/06/18 2.5 ND ND 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 1.6 ND ND 02/13/20 1.6 ND ND 08/26/20 4.5 ND ND 02/10/21 3.6 --- ND 08/18/21 ND ND 02/15/22 4.5 ND ND 09/29/22 4.5 ND ND 03/30/23 2.99 ND ND Appendix E (Page 4 of 8) htlpsllM1a,iM1lck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/G,,,U & MwWGMI-0M - Gill, Co. OM,N LF Unit 112023 First Half GW MRabl,s O#,N Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Manganese 08/24/17 2.5 244 --- 08/16/18 2.5 176 45.2 J NRWQC I I = 100 µg/L 02/10/21 4.3 --- ND 08/18/21 --- 02/15/22 -- NA NA 09/29/22 NA NA NA 03/30/23 NA NA NA Nickel 12/28/06 NR 4.6 J 6.2 J 07/12/07 NR 4 J Dry NC213 (3)= 179.75 µg/L 12/19/07 NR 21.9 Dry 07/08/08 NR 12.1 J Dry 12/16/08 1.7 5.2 B 6.8 B 07/08/09 1.7 10 J Dry 12/15/09 1.7 4.8 4.7 B 06/23/10 1.7 21.5 J ND 12/14/10 1.7 14.4 J Dry 06/21/11 5 5.8 J Dry 12/06/11 5 7.2 J ND 06/13/12 5 17.1 J 7.5 J 12/11/12 5 7.6 J Dry 04/29/13 5 ND ND 08/06/13 5 NO ND 02/25/14 5 7.3 J 6.6 J 08/13/14 5 7.5 J 5.4 J 03/11/15 2.5 3 J 2.8 J 08/19/15 2.5 ND Dry 02/18/16 2.5 3.3 J 3 J 08/11/16 2.5 22.8 J 19.4 J 02/15/17 2.5 4.2 J 4.1 J 08/24/17 2.5 3.7 J --- 02/06/18 2.5 ND 3.2 J 08/16/18 2.5 ND NO 02/06/19 2.5 NO ND 08/08/19 0.9 2.9 J 1.8 J 02/13/20 0.9 2.5 J 3.2 J 08/26/20 3.5 ND ND 02/10/21 3 ND ND 08/18/21 ND ND 02/15/22 3.5 ND ND 09/29/22 3.5 ND ND 03/30/23 1.61 4.16 J 3.29 J,13 Selenium 12/19/07 NR 15.6 Dry 07/08/08 NR NO Dry NC213 = 5 µg/L 12/16/08 3.8 3.9 B ND 07/08/09 3.8 ND Dry 12/15/09 3.8 ND ND 06/23/10 3.8 NO ND 12/14/10 3.8 5.9 J Dry 06/21/11 10 NO Dry 12/06/11 10 ND ND 06/13/12 10 NO ND 12/11/12 10 ND Dry 04/29/13 10 NO ND 08/06/13 10 ND ND 02/25/14 10 ND ND 08/13/14 10 NO NO 03/11/15 5 ND ND 08/19/15 5 ND Dry 02/18/16 5 ND ND 08/11/16 5 ND 6 J 02/15/17 5 ND NO 08/24/17 5 NO --- 02/06/18 5 ND ND 08/16/18 5 ND ND 02/06/19 5 ND ND 08/08/19 4.7 ND ND 02/13/20 5 ND ND 08/26/20 4.7 ND ND 02/10/21 4.7 ND ND 08/18/21 ND ND 02/15/22 4.7 ND ND 09/29/22 4.7 ND ND 03/30/23 7.35 ND ND Silver 07/08/08 NR 0.22 J 0 12/16/08 0.1 ND Dry NC213 (3)= 0.46 µg/L 07/08/09 0.1 ND 0.11 J 12/15/09 0.1 ND Dry 06/23/10 0.1 ND 0.19 J 12/14/10 0.1 0.21 B ND 06/21/11 5 ND Dry 12/06/11 5 NO Dry 06/13/12 5 ND ND 12/11/12 5 ND ND 04/29/13 5 ND Dry 08/06/13 5 ND ND 02/25/14 5 ND ND 08/13/14 5 ND ND 03/11/15 2.5 NO ND 08/19/15 2.5 ND ND 02/18/16 2.5 ND Dry 08/11/16 2.5 ND ND 02/15/17 2.5 NO ND 08/24/17 2.5 ND ND 02/06/18 2.5 ND --- 08/16/18 2.5 ND ND 02/06/19 2.5 ND ND 08/08/19 2.5 ND ND 02/13/20 2.5 NO ND 08/26/20 2.5 ND ND 02/10/21 0.7 NO ND 08/18/21 ND ND 02/15/22 2.5 ND ND 09/29/22 2.5 ND ND 03/30/23 1.54 ND ND Appendix E (Page 5 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/G,rreV d MwWGMI-0M - Gill, Co. OMON LF Unit 112023 First Half GW MRabl,s O#oN Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Thallium 12/19/07 NR 5.1 J Dry 07/08/08 NR 5.2 J Dry ISTV (2) = 2 µg/L 12/16/08 3 ND ND 07/08/09 3 ND Dry 12/15/09 3 ND ND 06/23/10 3 ND ND 08/12/10 30 NS NS 12/14/10 3 6.5 Dry 06/21/11 5.4 8.2 Dry 12/06/11 5.4 ND ND 06/13/12 5.4 NO ND 12/11/12 5.4 ND Dry 04/29/13 5.4 ND ND 08/06/13 5.4 ND ND 02/25/14 5.4 ND ND 08/13/14 5.4 ND ND 03/11/15 5 ND ND 08/19/15 5 NO Dry 02/18/16 5 NO ND 08/11/16 5 NO ND 02/15/17 0.02 ND ND 08/24/17 0.02 NO --- 02/06/18 0.028 ND ND 08/16/18 0.02 ND ND 02/06/19 0.06 ND NO 08/08/19 0.11 ND NO 02/13/20 0.11 ND ND 08/26/20 0.05 ND NO 02/10/21 0.05 --- --- 08/18/21 ND ND 02/15/22 0.05 NO ND 09/29/22 0.05 ND ND 03/30/23 0.121 ND ND Vanadium 11/14/96 NR 11 5 06/18/97 NR 20 ND NC213 Not Established 12/02/97 NR 16 ND 05/27/98 NR 44 ND 11/16/98 NR 44 47 09/10/99 NR ND ND 11/16/99 NR NO ND 05/10/00 NR ND ND 10/26/00 NR NO ND 04/18/01 NR ND ND 11/19/02 NR NO ND 06/27/03 NR ND ND 12/30/03 NR NO ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR NO ND 06/28/06 NR ND ND 12/28/06 NR 8.6 J 10.7 07/12/07 NR 5.3 J ND 12/19/07 NR 41.2 ND 02/14/08 NR 12.4 Dry 07/08/08 NR 38.2 Dry 12/16/08 0.2 11.5 J 14.1 J 07/08/09 0.2 24.3 J Dry 12/15/09 0.2 10 J 7 J 06/23/10 0.2 63.4 8.3 J 08/12/10 0.2 67.9 NS 12/14/10 0.2 52.3 Dry 06/21/11 5 25.3 Dry 12/06/11 5 19.7 J 13 J 06/13/12 5 130 61.5 12/11/12 5 50.7 Dry 04/29/13 5 16.9 J 18.4 J 08/06/13 5 15.4 J ND 02/25/14 5 29.2 29.4 08/13/14 5 18 J 18.2 J 03/11/15 2.5 7.8 J 8.3 J 08/19/15 2.5 2.8 J Dry 02/18/16 2.5 6.4 J 6.1 J 08/11/16 2.5 160 144 02/15/17 2.5 18.2 J 20.8 J 08/24/17 2.5 20.5 J --- 02/06/18 2.5 6.9 J 14.4 J 08/16/18 2.5 7.6 J 5.8 J 02/06/19 2.5 6.5 4.9 J 08/08/19 1.3 8.5 6.7 02/13/20 1.3 4.1 J 8.1 08/26/20 3.9 ND 7.2 02/10/21 3.7 ND ND 08/18/21 ND ND 02/15/22 3.9 6.1 9.9 09/29/22 3.9 ND ND 03/30/23 4.99 ND 5.23 J Appendix E (Page 6 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/G,,,U d MwWGMI-0M - Gill, Co. OMON LF Unit 112023 First Half GW MRabl,s O#oN Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Zinc 09/14/94 NR NO ND 12/02/94 NR 61 ND NC213 (s) = 44.92 µg/L 02/08/95 NR ND ND 03/02/95 NR 64 ND 11/17/95 NR ND ND 05/23/96 NR NO ND 11/14/96 NR ND ND 06/18/97 NR 26 ND 12/02/97 NR 32 40 05/27/98 NR 57 28 11/16/98 NR 28 31 09/10/99 NR ND ND 11/16/99 NR ND ND 05/10/00 NR ND ND 10/26/00 NR ND ND 04/18/01 NR ND ND 11/19/02 NR NS ND 06/27/03 NR ND ND 12/30/03 NR ND ND 06/30/04 NR ND ND 12/29/04 NR ND ND 06/29/05 NR ND ND 12/29/05 NR ND ND 06/28/06 NR ND ND 12/28/06 NR 7.4 J 8.5 J 07/12/07 NR 10.2 Dry 12/19/07 NR 24.1 B Dry 07/08/08 NR 17.2 Dry 12/16/08 0.4 8.9 J 11.9 07/08/09 0.4 9.4 J Dry 12/15/09 0.4 8.3 B 8.5 B 06/23/10 0.4 29.3 4 J 12/14/10 0.4 25.1 B Dry 06/21/11 10 10.9 Dry 12/06/11 10 15 B 10.3 B 06/13/12 10 46.3 19.8 12/11/12 10 25.4 Dry 04/29/13 10 13.8 12.5 08/06/13 10 11.3 ND 02/25/14 10 15 14.8 B 08/13/14 10 14.3 NO 03/11/15 5 62.3 11.6 B 08/19/15 5 ND Dry 02/18/16 5 13 11 08/11/16 5 66.4 54.1 09/13/16 5 14.5 J, B DRY 02/15/17 5 11 9.6 J 08/24/17 5 7.6 J J --- 02/06/18 5 9.4 J J 6.8 J 08/16/18 5 6.2 J J ND 02/06/19 5 ND ND 08/08/19 3.9 7.3 J J ND 02/13/20 3.9 8.2 J J 7.7 J 08/26/20 9.5 ND ND 02/10/21 3.6 ND ND 08/18/21 9.5 11.7 --- 02/15/22 9.5 ND ND 09/29/22 9.5 ND ND 03/30/23 6.52 29.7 1 J 13.0 J Appendix E (Page 7 of 8) htlpsllbaMhlck.sM1arepoinLcomisiteslMasterFiles-1ISM1ared DocumentslAAA-Master Proled,/G,rreV d MwWGMI-0M - Gill, Co. OM,N LF Unit 112023 First Half GW MRabl,s O#,N Unit 1 Historic Tables Hart & Hickman, PC Appendix E Summary of Historical Constituents in Surface Water Granville County Oxford Unit 1 Landfill Oxford North Carolina H&H Job No. GMI-004 Analyte Sample Date MDL SW-1 SW-2 Organics 1,4-Dioxane 08/16/18 1.9 ND 4.5 02/06/19 1.9 NO 5.9 ISTV (2)= 80 µg/L 08/08/19 1.2 ND 2.6 02/13/20 1.2 ND ND 08/26/20 1.2 ND 4.1 02/10/21 0.1 --- --- 08/18/21 0.86 --- 4.8 02/15/22 0.86 ND 5.2 09/29/22 0.86 ND ND 03/30/23 0.86 ND 0.89 J 2-Hexanone 06/23/10 0.46 1.5 J ND 12/14/10 0.46 NO Dry NC213 Not Established 06/21/11 0.46 ND Dry 12/06/11 0.46 ND ND 06/13/12 0.46 ND ND 12/12/12 0.46 0.47 J Dry 04/29/13 0.46 ND ND 08/06/13 0.46 ND ND 02/25/14 0.46 ND ND 08/13/14 0.46 ND ND 03/11/15 0.46 ND ND 08/19/15 0.46 ND Dry 02/18/16 0.46 ND ND 08/11/16 0.46 1.2 J ND 02/15/17 0.46 NO NO 08/24/17 0.46 NO --- 02/06/18 0.46 ND ND 08/16/18 0.46 ND ND 02/06/19 0.57 ND ND 08/08/19 0.57 ND ND 02/13/20 0.57 ND NO 08/26/20 0.57 ND ND 02/10/21 0.54 ND --- 08/18/21 ND ND 02/15/22 0.48 NO ND 09/29/22 0.48 ND ND 03/30/23 0.48 NO ND Acetone 12/15/09 2.2 3.9 B 3.2 B 06/23/10 2.2 5.4 B 2.2 B ISTV (21= 2,000 pg/L 12/14/10 2.2 ND Dry 06/21/11 2.2 3.4 B Dry 12/06/11 2.2 ND ND 06/13/12 2.2 2.2 B ND 12/12/12 10 ND Dry 04/29/13 10 ND ND 08/06/13 10 ND ND 02/25/14 10 ND ND 08/13/14 10 ND ND 03/11/15 10 ND ND 08/19/15 10 ND Dry 02/18/16 10 ND ND 08/11/16 10 NO ND 02/15/17 10 ND ND 08/24/17 10 ND --- 02/06/18 10 ND ND 08/16/18 10 ND ND 02/06/19 6.2 NO ND 08/08/19 6.2 ND ND 02/13/20 6.2 NO ND 08/26/20 6.2 ND ND 02/10/21 0.2 NO ND 08/18/21 ND ND 02/15/22 5.1 ND ND 09/29/22 5.1 ND ND 03/30/23 5.1 ND ND Methylene Chloride 04/29/13 0.97 0.98 J ND 08/06/13 0.97 NO ND ISTV (2I= 11,000 pg/L 02/25/14 0.97 NO ND 08/13/14 0.97 ND ND 03/11/15 0.97 ND ND 08/19/15 0.97 NO Dry 02/18/16 0.97 ND ND 08/11/16 0.97 ND ND 02/15/17 0.97 NO ND 08/24/17 0.97 ND --- 02/06/18 0.97 ND ND 08/16/18 0.97 NO ND 02/06/19 3.7 NO ND 08/08/19 3.7 NO ND 02/13/20 3.7 ND ND 08/26/20 3.7 NO ND 02/10/21 4.5 ND ND 08/18/21 02/15/22 2 NO ND 09/29/22 2 ND ND 03/30/23 2 ND ND Notes: Analytical results from November 1996 through February 2021 obtained from LaBelle Associates Water Quality Monitoring Report - February 2021 Event. Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event. 15A NCAC 213 Water Quality Standards (2B Standards) for Surface Water (Class C) dated July 26, 2021. Bold concentrations exceed the NC 2B Standard. 1. No 2B Standard established, value shown is EPA Nationally Recommended Water Quality Criteria (NRWQC) for AquaticLife & Human Health. 2. No 2B Standard or NWQC established, value shown is North Carolina In -Stream Target Values for Surface Waters (ISTV). 3. 2B Standards for hardness -dependent metals are calculated using a mean value of 32.25 mg/L obtained from averaging hardness results reported for surface water locations SW-1 and SW-2 from September 2019 to March 2023. All concentrations are in micrograms per liter (Ng/L). J = Estimated concentration above the adjusted method detection limit and below the adjusted method reporting limit; B = blank -qualified data; result is expected to be biased high based on concentrations in the blanks; MDL = laboratory method detection limit; DRY = Surface water point considered to be dry; NR = Not Reported; NE= Not established; --- = Not Sampled/ Data not available; ND = Not detected above laboratory method reporting limit Appendix E (Page 8 of 8) hfp,l/h,dh,,k.,h,rep,int.c,,/s,te/M,drFil,,-llSh,,d D-mentslAAA-Master Proled,/Ga tl&MwWGMI-0M-GranvilleCo.OMON LF Unit 112023 First HalfGWMRabl,s O#oN Unit 1 Historic Tables Hart & Hickman, !C Appendix F Summary of Historical Monitoring Natural Attenuation Parameters 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® Appendix F (Page 1 d 8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ®® MOM ��o®®000moo ��o®®000moo ��o®®000moo ��o®®000moo ��®o®000moo ��®o®000®oo ��®o®®momom ��®o®®momoo ��®o®®momoo ��me®®me®ee �mmmmmmmmmm em�mmmmmmmmm® �m�mmmmmmmmmm ��mm®�mm®mm ��mm®mm�®om ��mm®®mom®mm ®gym®®®m®®®m ��mm®®mm®mm ��mm®gym®®mm ��m®®mmm®mm ��mm®®mm®om ��mee®eeeee �mmmmmmmmmm em�mmmmmmmmm® �m�mmmmmmmmmm Appendix F (Page 2 0l8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ®m®mmm�m�m �®m�mmm®mom ems®m�mmm�m�m ��m�®®mom®gym Appendix F (Page 3 0l8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ��m�mmmmmmm ��m�mmmmmm� em��m�mmm�m�m ®gym®m®m®®mm �emmmmmmmmm �emmmmmmmmm em�emmmmmmmm® �m�emmmmmmmmm ��m�®®mom®gym ��m®®®mom®gym Appendix F (Page 4 d 8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ��m®�mmmmmm ��m®�mmmmmm ��®��mmmmmm ��®m�mmmmmm �emmmmmmmmm �emmmmmmmmm em�emmmmmmmm® �m�emmmmmmmmm ®gym®®®m®®®m ��m�®®mom®gym ��mmmmmmmmm ��mmmmm®mom em��mmmmmmmmm �m��mmmmmmmmm ��m®®®mom®gym Appendix F (Page 5 0l8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ��®m�mmmmmm ��m®®mmm®mm ��m®®mmm®mm ��m®®mmm®mm ��m®®mmm®mm ��®m�mmmmmm ��mm®®mo®mm ��mm®®mom®mm ��mmmmm�m�m ��mmmmm�m�m em��mmmmm�m�m �m��mmmmm�m�m Appendix F (Page 8 d 8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford unit 1 Landfill Oxford North Carolina H&H Job No. GM1404 ®®®®®®®®®®® ��m®®mmm®mm ��m®®mmm®mm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm ��m®®mmm®mm ��m®®mmm®mm ��®m�mmmmm® ���®mmmmmmmm ��m®®mmm®mm ��m®®mmm®mm ��®�mmmmm�m ���®mmmmmmm® ���®mmmmmmmm Appendix F (Page 7 d 8) Hart & Htckmoa, PC Appendix F Summary of Historical Monitored Natural Attenuation Granville County Oxford Unit 1 Landfill Oxford Nortb Carolina H&H Job No. GMI404 ®®®®®®®®®®® ��m®®mmm®mm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm ��m®®mmm®mm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm H.on.k Add ��®mmmmm�m ���®mmmmmmm® ���®mmmmmmmm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm ��®mmmmmmmm ���®mmmmmmm® ���®mmmmmmmm Toni Wed, F,tty Add, ��®mmmmmmm® ���®mmmmmmmm ��®mmmmmmmm ��®mmmmmmm® ����®mmmmmmmm Notes; Results from 2003 through February MM obtained from —ell. Associates Water Quality Monitoring Report- February 2022 Event. Results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2022 Event. 1. Monitoring well M W-3RR was I -el led in September 2022 to replace abandoned monitoring well M W-3R. Data shown in he table prior, to he September 2021 monitoring event for M W-3RR was colleR d from abandoned monitoring well 2. M W-2, M W-0R, and MW-6R samples collected on 10/O6/22. 3. M W-2, M W-0R, and MW-6R samples collected on 3/30/23. 1= Estimated concentration above the method detection limit and below the method reporting limit; PR-18= Headspace present in sample container; H-03 = Sample received after recommended holding dme was exceeded; H-09 = Sample received by leb—, with insufficient dme remaining to perform analysis within the re—endedholding Hme; mg/L= milligrams per liter; pg/L= micrograms per liter; nM = nanometers; ---= Not applicable and/or Not Reported; ND = Not Detected; S.U. =standard units; °C = degrees Celsius; µg/cm = microsiemens per centimeter; -=millivolts; NA = not analyzed; NS = not sampled; NI = Well not yet Installed; Appendix F (Page 8 0l8) Hart & Htnkmoa, PC Appendix G Concentration vs. Time Charts 14 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS E11011 70.0 J 50.0 ho 0 20.0 0111iA I1FA Chart 1 114-Dioxane Concentrations vs. Time MW-3R/3RR, MW-4R, MW-5R, & MW-6R 0.0 07/19/18 02/04/19 08/23/19 03/10/20 09/26/20 04/14/21 Date Note: Non -detect values are graphed equal to the method detection limit. 10/31/21 05/19/22 12/05/22 06/23/23 * MW-3R f M W-3RR MW-4R MW-5R MW-6R 2L Standard (3 µg/L) Chart 2 Vinyl Chloride vs. Time MW-5R 30 25 20 J _ 0 15 f MW-5R 21L Standard (0.03µg/L) 0 U 10 5 V A 0 1. 03/20/03 06/22/05 09/25/07 12/28/09 04/01/12 07/05/14 10/07/16 01/10/19 04/14/21 07/18/23 Date Note: Non -detect values are graphed equal to the method detection limit. Chart 3 1,1-Dichloroethane vs. Time MW-SR 10 9 8 7 J 0.0 -A/ /VV w I c 0 5 BMW-5R c u' 21L Standard (6 µg/L) 0 4 U 3 2 1 0 1. 05/20/99 12/10/02 07/02/06 01/22/10 08/14/13 03/06/17 09/26/20 04/18/24 Date Note: Non -detect values are graphed equal to the method detection limit.