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HomeMy WebLinkAbout1302_Cabarrus_MSWLF_Unit1_April23GW_FID1811024_20230717Cabarrus County Sanitary Landfill — Unit 1 Semi -Annual Sampling Report Facility Permit # 1302-MSWLF-1974 (April 2023 Sampling Event) Prepared July 2023 Division of Waste Management -Solid Waste R-.. _....._. epor._.9 _....a epOltln Fprtyl Not": This form and any information attached to it are "Public Remade as defined in NC Geneml StabIIe 132-1. As such, these documents am. available for inspection and examination by any person upon request (NC General Slatule 132-6). Instructions: Prepare one form for each Individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, of&aite source, preexisting condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(1). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner) Consultant - CDM Smith Inc. Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name: Met Colon, Phone: (919) 325-3569 E-mail: colonemfibodmsmih.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 20-24, 2006) Camms County Landfill Unit 1 _ 4441 Irish Potato Read Concord, NorthCarolina 28025 I- 1302-11JSWIF- 1974 Ll '119-21, 2023 - Environmental Status: (Check all that apply) Indial/Background Monitoring ® Detection Monitoring ❑ Assessment Morioing ❑ Comective Action Type of data submitted: (Check all that apply) lll—�yl Gmundwater monitoring data from monitoring wells ❑ Methane gas monitoring data Groundwater monitoring data from private water supply walls ❑ Corrective action data (specify) Leachate monitoring data H Surface, water monitoring data ❑ O1her(speuly) Notification attached? ®No. No groundwater or surface water standards wem exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the intomstion reported and statements made on Nis data submittal and attachments are true and cortect. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Mathew Colon. Consultant (919) 325-3500 Facilew n (Print) Title (Area Cede)Telephone Num �ese-:waaq� "'lp7 July 17, 2023 AKx NC Li 3 l Reri'v - of ist Seal F Signature Date"f'tQ+t 5400 Glenwood Avenue, Suite 400, Raleigh, North Cantina 27812 Facility Representative Address 2623 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 F. u,t ' r (P23 Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 July 17, 2023 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: April 2023 Semi -Annual Sampling Report Cabarrus County Unit 1 Landfill Facility Permit No. 1302-MSWLF-1974 Dear Ms. Drummond: CDM Smith Inc., on behalf of Cabarrus County, is submitting an electronic copy of the April 2023 semi- annual sampling report for the recent event completed at the Cabarrus County Unit 1 Landfill (Unit 1 Landfill). This letter report constitutes the first semi-annual sampling event for 2023. The approved monitoring well network consists of compliance wells MW-5, -7, -8A, -10, -11, and background wells CD-1s and -1d. The monitoring network also includes surface water sample locations SW-1 and -2. Field activities and sampling results for the groundwater and surface water samples are discussed below. Field Activities Groundwater and surface water samples from the Unit 1 Landfill were collected on April 19-21, 2023. Groundwater samples were collected from the monitoring wells by use of a peristaltic pump or disposable, laboratory decontaminated bailers. Monitoring well and surface water sample locations for the Unit 1 Landfill are provided on Figure 1. Groundwater elevations were measured at each well on April 17, 2023, prior to sampling and are presented in Table 1. Well construction details for each monitoring well are also provided in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. After depth to groundwater was measured, each well was purged prior to sampling to provide fresh formation water within the well water column. Each purge volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen, and oxidation-reduction potential using a YSI-SS6 multi -parameter water quality meter and a HANNA HI 98703 turbidity meter. The water quality parameters at the time of sampling are presented in Table 2. 0 WATER + ENVIRONMENT+ TRANSPORTATION+ ENERGY + FACILITIES Smith Ms. Jaclynne Drummond July 17, 2023 Page 2 Sampling Results Pace Analytical Services, LLC, located in West Columbia, South Carolina, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs) and metals. In a letter dated May 28, 2019, the Solid Waste Section (SWS) requested that all groundwater and surface water samples collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On July 1, 2019, the SWS approved the removal of 1,4-dioxane from the sampling program for CD-1s and -1d due to two consecutive non -detect events (January and May 2019). Samples were collected from MW-5, -7, -8A, -10, and -11 during the April 2023 sampling event and analyzed for 1,4-dioxane due to previous detections of 1,4-dioxane. Sample results are provided below. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the limit of quantitation (LOQ). All monitoring wells for the Unit 1 Landfill had detections of analytes above the MDL but below the LOQ. These detections were qualified as estimated or "J" flags. Samples collected from MW-5 also had a detection of acetone with an "L" flag, indicating a laboratory control sample/laboratory control sample duplicate failure. The following list indicates the VOCs and metals detected above the LOQ at each sampling location. No "J" flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Standard or Interim Maximum Allowable Concentration (IMAC). A complete summary of all detected and estimated concentrations from the May 2012 through the April 2023 sampling events is presented in Table 3. The laboratory data report is provided in Appendix A. CD -Is (Background) Metals: Volatile Organic Compounds: CD-1d (Background) Metals: Volatile Organic Compounds: MW-5 Metals: Barium, Vanadium None Detected Barium, Vanadium None Detected Barium, Cobalt, Nickel Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane M W-7 Metals: Arsenic, Barium, Cobalt, Nickel, Selenium Volatile Organic Compounds: Benzene, Chlorobenzene, 1,2-Dichlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane Smith Ms. Jaclynne Drummond July 17, 2023 Page 3 M W-8A Metals: Volatile Organic Compounds: Barium, Cobalt, Copper, Lead, Nickel, Zinc None Detected MW-10 Metals: Arsenic, Barium, Cobalt, Nickel Volatile Organic Compounds: Benzene, Chlorobenzene, 1,2-Dichlorobenzene, 1,4-Dichlorobenzene, IA-Dioxane MW-11 Metals: Barium, Cobalt, Nickel, Zinc Volatile Organic Compounds: 1,4-Dioxane SW-1 Metals: Barium Volatile Organic Compounds: 1,4-Dioxane SW-2 Metals: Barium Volatile Organic Compounds: 1,4-Dioxane Equipment and trip blanks were analyzed for quality control. A duplicate sample was also analyzed for quality control. There were no detections in the trip blank above the MDLs. The equipment blank had an estimated detection of 2-butanone with an 'T' flag below its NC 2L Groundwater Standard. The duplicate sample, identified as DUP, was collected from MW-10, and had similar analyte concentrations as those detected in MW-10. Metals detected above the standards are likely naturally occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. VOCs detected above the standards in several of the compliance wells will continue to be monitored. Table 4 presents a summary of all analytes detected during the April 2023 sampling event that exceeded the NC 2L Groundwater Standards or IMACs. The next semi-annual sampling event will be completed in the fall of 2023. 0 Smith Ms. Jaclynne Drummond July 17, 2023 Page 4 If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Sincerely, 1�& IL-e� Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County 0 Table 1 Monitoring Well Construction Summary and Groundwater Elevations April 2023 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock Smith Page 1 of 1 July 2023 Table 2 Water Quality Measurements April 2023 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Water Quality Measurements Facility Permit Monitoring Well .. Number pH Conductivity Temperature .. .• Oxygen CD-1s 1302-MSWLF-1974 5.76 136 17.4 9 5.99 146.2 (background well) CD-1d 1302-MSWLF-1974 5.88 111 17.5 60 4.30 148.4 (background well) 1302-MSWLF-1974 MW-5 6.10 1 663 16.0 22 1.44 95.3 1302-MSWLF-1974 MW-7 5.39 2,898 15.6 30 4.39 49.5 1302-MSWLF-1974 MW-8A 5.88 365 15.2 9 4.89 90.0 1302-MSWLF-1974 MW-10 6.60 1,405 15.7 10 1.02 12.3 1302-MSWLF-1974 MW-11 Surface 6.11 Water 483 Sample Locations 14.9 9 5.23 96.7 1302-MSWLF-1974 SW-1 7.08 356 20.0 16 8.45 109.1 1302-MSWLF-1974 SW-2 6.94 367 20.0 24 9.44 75.7 Notes: 1. Water quality measurements were collected on April 18-21, 2023. 2. µS/cm - Microsiemens per centimeter 3. mg/L - Milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. NTUs - Nephelometric Turbidity Units 6. mVs - Millivolts 7. S.U. -Standard Units Smith Page 1 of 1 July 2023 Table 3a Detected Groundwater Constituents - Metals April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North o Carolina 2L 1 r rr r 000 „ r r rrr CD-1s 9-Nov-11 59.7J 0.25B-01,1 4.46J 2.67J 12.4 1.901 4.41J 0.081 11.2J 18.2 CD-1s 28-Nov-12 63.8J 0.111 5.65J 3.05J 11.6 1.43J 4.66J 17.11 16.9 CD-1s 7-May-13 0.941 2.4081 35.6J 0.881 0.67J 4.04J 0.39J 1.78J 0.13J 6.06J 5.081 CD-1s 5-Nov-13 46.8J 0.12J 3.59J 1.63J 10.2 1.35J 3.50J 15.413 3.40J CD-1s 6-May-14 28.81 4.14BJ 1.48J 0.111 1.03J 0.31J 2.98BJ CD-1s 4-Nov-14 28.7J 0.13J 1.31J 0.06J 1.04J 0.111 2.57E-03,J 1.581 CD-1s 5-May-15 1.63J 29.513-01,1 1,331 0.15J 1.171 2.401 2.75E-01,J CD-1s 27-Oct-15 1.00 28.4J 0.801 0.39J 0.75J 0.12J 1.21J 4.19CN,J 0.15J 4.10J 3.36E-03,J CD-1s 17-May-16 29.31 0.94J 0,991 0.12J 1.01J 4.70J 1.93J CD-1s 1-Nov-16 30.5J 1.23J 1.36J 0.28J 1.35J 4.301 CD-1s 9-May-17 34.3J 1.17J 1.26J 0.20J 0.97J 6.69J 1.82J 1302-MSWLF-1974 CD-1s 31-Oct-17 0.52J 36.3J 1.811 0.54J 2.87J 0.37J 1.41J 6.91J 4.OJ CD-1s 11-Jun-18 28.9J 4.31 4.4J CD-1s 17-13ec-18 26.7J 0.60J 3.6J 15.OJ 7.OJ 9.51 CD-1s 7-May-19 29.8 1.3J 7.OJ 5.1J CD-1s 6-Nov-19 31.9 1.01 1.8JB 0.070J 0.73J 5.01 7.3JB CD-1s 18-May-20 0.46) 34.5 2.2J 0.92J 0.23J 1.41 6.41 6.9J CD-1s 23-Sep-20 34 1.3J 1.5J 4.9J 4.2J CD-1s 17-Mar-21 42 1.3J 4.11 5.81 CD-1s 17-Nov-21 34 4.OJ 34 CD-1s 26-Apr-22 32 4.OJ CD -Is 18-Oct-22 31 1.3J 1.4J 5.3 CD-1s 19-Apr-23 37 5.3 3.5J CD-1d 8-Nov-11 74.5J 0.51J 4.081 26.8 2.84J 5.68J 24.6J 26.3 0.94J CD-1d 28-Nov-12 0.331 37.7J 0.071 2.38J 12.6 1.14J 2.50J 8.901 13 CD-1d 8-May-13 0.891 1.02BJ 31.2J 0.07J 0.78J 4.50J 0.49J 1.92J 6.18J 13.1 CD-1d 5-Nov-13 35.OJ 0.86J 4.34J 1.13J 1.901 17.IB1 10.8E CD-1d 6-May-14 1.14J 37.8J 0.07J 0.05J 3.22BJ 1.161 7.34J 0.811 2.74J 0.12J 6.16J 9.4181 CD-1d 4-Nov-14 43.1J 0.16J 0.111 2.25J 9.091 0.87J 2.88J 10.2E-01,1 10.7 CD-1d 5-May-15 34.513-01,1 0.84J 3.63J 0.39J 1.42J 5.18J 3.68B-01,J CD-1d 27-Oct-15 0.421 42.3J 0.13J 1.87J 2.15J 8.181 0.97J 2.49J 4.37CN,J 0.061 10.91 14.0E-01 CD-1d 17-May-16 81.3J 0.46J 4.86J 7.42J 26.0 3.13J 7.11J 2.11J 0.07J 29.3 29.7 CD-1d 1-Nov-16 32.6J 1.191 0.77J 2.82J 0.33J 1.241 J177.96J 4.291 CD-Sd 9-May-17 33.9J 1.27J 0.52J 1.811 6.92J 1.091 6.95J 3.121 1302-MSWLF-1974 CD-1d 31-Oct-17 29.5J 0.68J 0.61J O.I11 0.641 5.381 1.241 CD-Sd 12-Jun-18 32.4J 2.5J 1.01 6.9J 3.2J CD-1d 17-Dec-18 31.91 9.3J 2.3J 0.41J 3.OJ 6.8J 4.1J CD-Sd 7-May-19 30.7 1.4J 7.41 2.9J CD-1d 5-Nov-19 0.48J 30.1 1.91 1.1JB 0.13J 1.81 4.7J 8.2JB CD-1d 18-May-20 29.1 0.64J 0.33J 5.61 2.OJ CD-1d 22-Sep-20 0.67J 38 1.91 8.6 0.991 4.2J 8.8 36 CD-Sd 16-Mar-21 27 4.8J 3.11 CD-1d 17-Nov-21 33 2.41 0.42J 1.51 6.0 5.81 CD-Sd 27-Apr-22 30 1.4J 5.1 S. CD-1d 20-Oct-22 0.871 28 3.OJ 4.OJ 4.41 4.5J CD-Sd 20-Apr-23 31 2.8J 0.30J 1.3J 5.7J 6.5J MW-5 8-Nov-11 1.98J 108 0.19151 0.111 0.54J 12 4.39J 0.38J 37.7J 3.43J 10.1 MW-5 9-May-12 0.191 29.2J 0.14J 3.22B1 0.78J 5.9581 0.811 6.22J 0.92J 2.40J 9.6481 MW-5 28-Nov-12 0.291 4.57J 173 0.081 21.8 2.85J 0.13J 46.2J 3.45J 6.661 MW-5 10-May-13 34.3J 0.15J 0.07J 1.94J 6.001 4.61J 0.46J 16.4J 5.15J 4.12J 6.791 MW-5 5-Nov-13 3A2J 160 0.081 26.6 2.881 0.40J 39.81 2.83J 5.9091 MW-5 6-May-14 2.41J 91.81 0.051 0.091 11.8 2.841 0.34B1 23.11 8.851 5.261 MW-5 4-Nov-14 5.38J 173 29.5 2.611 0.41J 52.2 3.881 3.771 3.16E-01,J MW-5 5-May-15 2.39J 93.213-01,J 19.8 2.591 0.41J 29.11 3.91J 3.83E-01,1 MW-5 27-Oct-15 5.49J 163 0.101 26.3 1.971 0.33J 47.91 2.72J 3.O1CN,J 2.181 3.22J MW-5 (dup) 27-0ct-15 5.601 174 0.161 16.5 2.321 0.64J 48.41 3.38J 3.53CN,J 3.35J 5.0&1 MW-5 17-May-16 1.40J 158 0.74J 28.7 1.17J 0.181 36.31 1.001 2.42J MW-5 1-Nov-16 1.75J 166 1.091 19.3 0.63J 0.20J 47.11 3.281 1302-MSWLF-1974 MW-5 9-May-17 0.95J 91.01 0.151 0.081 1.59J 2.221 0.77J 26.51 1.56J 3.671 3.83J MW-5 31-0ct-17 1.981 165 1.14J 19.4 1.101 0.33J 43.51 5.1&1 MW-5 6-Jun-18 2.41 198 0.069J 26.9 0.28J 46.61 4.31 MW-5 20-Dec-18 102 14.5 2.2J 0.32J 24.31 5.91 MW-5 8-May-19 0.62J 144 0.131 0.901 29.3 4.8J 0.29J 41.3 1.7J 9.5JB MW-5 5-Nov-19 0.70J 1.11 164 0.951 19.1 1.2JB 0.25J 46.3 1.6J 7.6JB MW-5 19-May-20 1.31B 161 0.861 27.5 0.841 0.24J 43.5 1.11 4.7J MW-5 25-Sep-20 0.92J 2.0 55 0.53 5.0 3.5J 6.3 2.5 12 2.8J 12 20 MW-5 16-Mar-21 150 8.6 2.3J 0.37J 35 5.9 3.3J MW-5 18-Nov-21 2.0 170 0.191 1.41 12 1.581 1.0 46 11 4.5J 3.4J MW-5 28-Apr-22 86 0.191 3.4J 5.2 5.2 1.7 19 7.3 11 MW-5 20-Oct-22 1.71 23 0.38J 3.31 1.91 5.8 1.9 6.7 1.9J 8.6 11 MW-5 21-Apr-23 140 0.181 13 1.5J 37 1.3J 7.01 Smith 1 of 7 July 2023 Table 3a Detected Groundwater Constituents - Metals April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L 1 r 700 4 2 10 1 1,000 15 100 20 20 2 7 1 1,000 MW-7 8-Nov-11 0.16BJ 0.07B1 62.1 1.70J 13.0J72.71J 0.081 6.97J MW-7 9-May-12 0.231 9.141 0.301 0.30J 0.74BJ 29.5 3.15BJ 1.111 85.5 6.031 17.7B MW-7 28-Nov-12 0.531 9.85J 437 45.9 1.27J 30.4J 5.011 MW-7 10-May-13 6.73J 300 0.081 49.1 1.96J 0.46J 11.010.091 6.36J MW-7 5-Nov-13 448 0.12J 0.411 45.4 2.57J 1.33J 33.2J 13.5J 6.79BJ MW-7 6-May-14 9.34J 460 0.20J 0.79J 2.2381 47.6 4.391 4.55BJ 44.4J 16 17.3 MW-7 4-Nov-14 5.74J 391 0.131 46.0 1.54J 0.41J 31.9J 1.69J 0.991 1.98E-01,J MW-7 5-May-15 5.77J 398B-01,1 0.31J 49.4 2.35J 1.21J 31.2J 3.52J 3.23E-01,J MW-7 27-Oct-15 323 48.2 0.67J 0.09J 11.9J 1.25CN,J 0.07J 3.54J 11111111 3.90J MW-7 17-May-16 0.26J 646 0.33J 1.38 6.26J 45.2 5.79J 7.01J 76.8 3.46J 0.13J 23.2 12.4 MW-7 (dup) 17-May-16 0.261 4.08J 604 0.32J 1.37 5.64J 47.6 5.73J 6.13J 63.1 3.03J 0.13J 21.3 13.1 MW-7 1-Nov-16 2.33J 390 0.14J 52.9 0.27J 27.41 2.24J 3.08J MW-7 9-May-17 2.86J 0.36J 48.8 0.30J 0.38J 18.4J 2.32J 0.091 1302-MSWLF-1974 MW-7 31-Oct-17 3.17J 383 0.70J 42.3 0.43J 0.45J 25.0J 0.07J 2.041 MW-7 6-Jun-18 4.0J 551 42.1 0.76J 45.7J 5.81 MW-7 20-Dec-18 3.1J 451 43.5 37.8J 11.5 MW-7 8-May-19 1.61 606 0.61J 35.1 0.35J 0.12J 77.6 1.11 4.6JB MW-7(dup) 8-May-19 1.21 603 0.85J 34.0 0.75J 0.27J 77.1 1.7J 1.81 7.2JB MW-7 4-Nov-19 0.32J 5.0 320 0.44J 40.2 0.24JB 0.065J 9.9 0.066J 6.8JB MW.7(dup) 4-Nov-19 4.1J 304 38.3 0.067J 9.4 0.060J 6.8JB MW-7 19-May-20 1.61 646 1.01 35.0 0.78J 0.32J 82.6 2.9J 0.086J 4.4J MW-7 24-Sep-20 2.8 610 27 77 64 2.6J MW-7 16-Mar-21 2.0 25 110 9-14.3J MW-7 18-Nov-21 0.521 2.8 31 130 130 3.6J MW-7 28-Apr-22 8.9 35 110 29 5.2 MW-7 20-Oct-22 2.0 680 25 0.331 99 83 4.1J MW-7 21-Apr-23 5.4 430 30 22 26 MW-8A 8-Nov-11 0.4211 112 0.07BJ 0.95J 16.3 24.1 0.46J 52.5 1.59J 178 MW-8A 9-May-12 0.30J 59.4J 1.121 13.2 5.78J 0.47J 34.6J 93.6E MW-8A 28-Nov-12 80.11 0.38J 5.45J 5.17J 0.35J 10.7J 1.82J 5.80J 28.6 0.30J MW-8A 7-May-13 1.08B1 48.7J 0.20J 7.54J 6.18J 0.29J 9.811 5.16J 31.4 MW-8A 5-Nov-13 0.34J 64.6J 0.20J 5.64J 6.72J 0.39J 10.6J 2.21J 24.113 MW-8A 6-May-14 41.71 0.071 7.88J 3.84J 0.08B1 6.001 1.87J 4.27J 13.1 MW-SA 4-Nov-14 64.6J 0.17J 5.76J 8.181 0.27J 11.4J 5.66J 4.62J 17.28-01 MW-8A 5-May-15 31.4B-01,J 5.881 3.51J 5.911 2.86J 7.418-01,J MW-SA 27-Oct-15 54.4J 0.181 11.2 10.4 0.12J 17.5J 2.17J 2.80CN,J 47.8 MW-8A 17-May-16 35.81 0.121 8.081 4.03J 9.051 27.2 MW-SA 1-Nov-16 61.81 0.14J 18.7 4.40J 0.181 27.9J 119 MW-8A(dup) 1-Nov-16 64.41 0.161 20.1 4.341 0.15J 28.5J 125 MW-SA 9-May-17 3.841 1.161 66.01 0.66J 12.9 58.5 80.7 6.40J 247 11111111 0.871 13.5 1302-MSWLF-1974 MW-8A 31-Oct-17 1.991 2.77J 88.71 0.67J 13.0 29.3 30.5J 0.06J 3.65J 241 MW-8A 6-Jun-18 2.7J 0.94J 65.5J 0.0591 0.59J 11.1 29.0 3.0J 84.5 4.41 490 MW-8A(dup) 6-Jun-18 2.8J 1.0J 69.7J 0.075J 0.861 10.9 30.5 3.41 86.6 5.4J 530 MW-SA 21-Dec-18 2.6J 2.71 104 1.1 8.01 25.9 7.5J 45.0J 4.41 246 MW-8A 8-May-19 3.5J 2.3J 77.9 0.67 6.1 11.8 2.2 33.2 3.6J 88.1 MW-8A 5-Nov-19 1.51 173 0.111 13.3 28.16 1.9 189 0.086J 4.0J 671 11111111 0.241 MW-8A 19-May-20 4.3J 0.62J 91.1 0.93J 8.3 22.1 2.5 94.7 0.16J 2.0J 260 MW-8A(dup) 19-May-20 4.0J 0.57J 91.8 0.23J 0.79J 8.7 21.0 2.9 96.5 0.069J 2.5J 277 MW-8A 24-Sep-20 0.76J 1.5J 120 0.311 16 13 1.7 90 2.6J 15 MW-SA 18-Mar-21 94 12 1.4J 0.25J 59 6.2J MW-8A 18-Nov-21 110 8.8 2.7131 0.901 34 2.7J 3.9J MW-IA 28-Apr-22 0.51J 1.31 58 0.431 21 29 2.6 570 16 MW-8A 20-Oct-22 70 1.41 1.61 3.61 0.551 3.9J 10 MW-8A 20-Apr-23 0.521 76 0.20J 15 18 1.4 130 Smith 2 of July 2023 Table 3a Detected Groundwater Constituents - Metals April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 ,,, 1 15 1 100 20 20 2 7 1 1,000 MW-10 8-Nov-11 0.25BJ 14.7 219 0.4781 25.1 4.09J 123 6.66J 5.22J MW-10 9-May-12 0.23J 24.5 194 0.40J 0.78J 36.8 3.59J 0.131 168 9.44J 6.20B1 MW-10 28-Nov-12 0.33J 16.8 193 0.411 0.721 25.9 3.26J 0.25J 129 8.601 2.33J MW-10 10-May-13 0.25J 16.7 174 0.51J 1.981 32.6 4.10J 0.37J 253 7.771 FO.O7J ;2M.1 5.101 MW-10 5-Nov-13 0.37J 10.6 195 0.49J 22.8 3.64J 0.301 131 6.99J 5.2811 MW-10 6-May-14 15.4 165 0.41J 33.8 3.09J 0.21BJ 246 8.011 2.421 MW-10 4-Nov-14 16.2 166 0.531 1.31E-01,J 25.5 3.59J 1.27J 122 7.15J 5.77E-01,J MW-10 5-May-15 17.1 157B-01 0.48J 29.2 2.64J 0.42J 240 10.4 2.768-01,1 MW-10 27-Oct-15 0.251 12.8 167 0.52J 25.2 2.52J 0.26J 122 6.91J 2.56CN,J 0.101 2.96J 2.47J MW-10 17-May-16 16.7 166 0.39J 1.67J 32.6 0.72J 0.21J 247 1.06J 3.21J 2.88J MW-10 1-Nov-16 14.6 157 0.49J 1.98 32.2 0.71J 0.27J 146 3.71J 1AW-10 9-May-17 7.93J 138 0.29J 1.811 20.9 1.28J 0.35J 92.0 1.63J 0.06J 2.87J 2.741 MW-10 31-0ct-17 15.7 162 0.54J 2.82J 27.1 0.56J 133 0.101 1302-MSWLF-1974 MW-10 6-Jun-18 15.5 170 0.35J 3.6J 26.1 0.67J 120 8.2J MW-10 20-Dec-18 23.5J 3.71 8.01 3.1J MW-10(dup) 20-Dec-18 22.1J 3.4J 7.6J 2.5J MW-10 8-May-19 14.1 116 0.22J 1.3J 20.9 3.6J 0.101 123 1.61 4.OJB MW-10 5-Nov-19 12.0 172 0.38J 1.6J 22.6 0.47J 0.21J 95.3 0.068J 4.5J 8.4J MW-10 19-May-20 15.4 131 0.36J 1.31 27.0 0.49J 0.151 126 0.054J 2.11 2.4J MW-10 24-Sep-20 27 140 0.35J 1.7J 27 0.61J 130 4.6J 2.8J MW-10(dup) 24-Sep-20 27 140 0.45 1.81 27 0.581 130 4.8J 2.9J MW-10 16-Mar-21 36 130 0.75 2.8J 28 2.OJ 0.82J 120 4.OJ 4.7J 4.21 MW-10 18-Nov-21 0.53J 27 130 0.66 3.2J 27 1.6BJ 0.911 130 5.7 3.5J 3.OJ MW-10 28-Apr-22 41 150 0.74 6.1 27 2.1J 1.2 130 2.3J 6.9 8.2J MW-10 20-Oct-22 26 130 0.64 3.4J 25 1.7J 0.981 120 3.9J 6.1 3.7J MW-10 20-Apr-23 18 130 0.39J 2.2J 25 1.7J 0.75J 110 3.5J 3.6J 5.5J MW-10(dup) 20-Apr-23 1 19 1 120 0.46 1 1 2.5J 24 2.OJ 0.89J 110 3.2J 4.1J 4.8J MW-11 8-Nov-11 0.29BJ 509 0.06BJ 0.12J 24.2 27.2 0.20J 37.9J 7.701 10.6 MW-11 9-May-12 79.5J 18.2 3.79J 0.42J 10.61 1.101 1.96J 50.1E MW-11 28-Nov-12 494 0.15J 35.8 6.62J 0.30J 38.1J 9.36J SAW MW-11 10-May-13 52.9J 2.561 o.43J 1.71J 2.56J 1.101 55.7 MW-11 5-Nov-13 1.321 503 0.06J 34.5 11.9 0.47J 38.7J 8.26J 0.31J 5.79BJ 11.713 MW-11 6-May-14 1.75J 144 0.071 6.721 3.92J 0.17B1 13.OJ 5.161 5.12J 23.1 MW-11 4-Nov-14 4.001 449 35.1 11.3 0.37J 39.8J 3.54J 4.09J 2.38E-01,J MW-11 5-May-15 218B-01 13.0 11.9 0.54J 20.6J 9.53J 39.58-01 MW-11 27-0ct-15 2.12J 503 37.0 16.4 0.62J 44.8J 3.77J 2.89CN,J 2.41J 4.681 MW-11 17-May-16 163 10.9 2.12J 11.7J 5.56J 19.4 MW-11 1-Nov-16 455 0.111 41.7 15.2 0.56J 40.4J 5.71J MW-11 9-May-17 151 7.921 3.19J 0.091 10.81 2.79J 18.9 MW-11 9-May-17 150 0.081 7.85J 3.20J 0.101 10.7J 2.90J 19.5 MW-11 31-Oct-17 515 0.181 35.7 8.44J 0.29J 37.8J 1302-MSWLF-1974 MW-11(dup) 31-0ct-17 0.87J 498 0.16J 1.181 34.7 7.60J 0.32J 37.OJ 3.301 MW-11 6-Jun-18 1.3J 438 27.1 6.5J 32.9J 15.0 MW-11 20-Dec-18 101 3.51 1.6J 4.3J 26.1 MW-11 9-May-19 191 0.084J 12.5 1.6J 0.191 12.8 8.11B MW-11 5-Nov-19 530 34.4 3.9J 0.41J 36.0 1.11 8.3J MW-11 19-May-20 189 0.47J 18.0 2.2J 0.28J 11.3 12.5 MW-11 24-Sep-20 250 15 0.26J 17 2.9J 2.6J MW-11 16-Mar-21 91 5.7 0.70J 4.1J 4.3J 4.5J MW-11(dup) 16-Mar-21 82 5.4 0.411 3.7J 3.01 3.6J MW-11 18-Nov-21 430 30 33 4.01 MW-11(dup) 18-Nov-21 430 31 34 3.7J MW-11 28-Apr-22 140 8.7 1.7J 8.6 25 MW-11(dup) 28-Apr-22 140 9.2 1.4J 8.2 24 MW-11 20-Oct-22 420 27 2.2J 0.50J 33 2.31 MW-11 "up) 20-Oct-22 430 27 2.1J 0.43J 33 3.OJ MW-11 20-Apr-23 140 9.9 7.0 16 Notes: 1. All units are in micrograms per liter (parts per billion). 2. dup - Duplicate Sample 3. J - Indicates the analytical result is an established concentration between the method detection limit and the adjusted reporting limit. 4. B, B-01- The analyte concentration detected in the method blank was greater than the method detection limit. 5. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 21.). - Indicates the result is below the detection limit. Smith 3 of 7 July 2023 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L or IMAC 304 0 0� 2,00W 0. M I.. CD 8-Nov-11 CD-ls 27-Nov-12 0.4J 0.21 CD-ls 7-May-13 CD-ls 5-Nov-13 CD-ls 6-May-14 CD-ls 4-Nov-14 CD-ls 5-May-15 CD-ls 27-Oct-15 CD-ls 17-May-16 CD-ls 1-Nov-16 CD-ls 9-May-17 1302-MSWLF-1974 CD-ls 31-Oct-17 CD-ls 11-Jun-18 CD-ls 17-Dec-18 1.2 CD-ls 7-May-19 CD -Is 6-Nov-19 CD -Is 18-May-20 CD -Is 23-Sep-11 CD - Is 17-Mar-21 CD -Is 17-Nov-21 CD -Is 26-Apr-22 CD -Is 18-Oct-22 CD -Is 19-A r-23 CD -Id 8-Nov-I1 CD - Id 27-Nov-12 CD -Id 7-May-13 CD -Id 5-Nov-13 CD -Id 6-May-14 CD -Id 4-Nov-14 CD -Id 5-May-15 CD -Id 27-0ct-15 CD -Id 17-May-16 CD -Id I-Nov-16 1302-MSWLF-1974 CD -Id 31-Oct-17 CD -Id 12-Jun-18 CD -Id 17-Dec-18 CD -Id 7-May-19 CD -Id 5-Nov-19 CD -Id 18-May-20 CD -Id 22-Sep-20 CD-ld 16-Mar-21 CD-ld 17-Nov-21 CD-ld 26-Ap122 CD-ld 20-0ct-22 CD-ld 19-Apr-23 MW-5 7-Nov-11 0.81 7.6 6.2 MW-5 8-May-12 0.31 MW-5 27-Nov-12 1.3 18 0.6B1 14 0.31 MW-5 9-May-13 1.71 0.31 4.2 3.4 MW-5 4-Nov-13 1.5 18 0.61 13 MW-5 5-May-14 I.01 11 0.31 7.4 MW-5 3-Nov-14 1.6 23 0.71 16 0.21 MW-5 4-May-15 0.91 16 0.51 30 MW-5 26-Oct-15 1.2 21 0.61 14 MW-5 (dup) 26-Oct-15 1.0 20 0.61 13 MW-5 16-May-16 1.2 19 0.51 12 MW-5 31-Oct-16 1.4 26 0.71 15 2.61 1302-MSWLF-1974 MW-5 8-May-17 0.81 16 9.1 MW-5 30-Oct-17 1.2 23 0.51 14 MW-5 6-Jun-18 1.1 21.6 0.60J 12.3 1.5 MW-5 20-Dec-18 0.52J 12.4 5.9 87.7 MW-5 7-May-19 1.2 18.2 9.9 142 MW-5 4-Nov-19 1.5 29.2 0.61 14.1 142 5.11 MW-5 19-May-20 0.62J 126 3.2J MW-5 25-Sep-20 0.79 0 441 15 M W-5 16-Mar-21 1.6 075 70 MW-5 18-Nov-21 17 6.8 130 MW-5 28-Apr-22 4.8 2.4 42 MW-5 20-Oct-22 8.3 MW-5 21-Apr-23 8.1JL 0.481 10 5A 77 Smith 4 of 7 July 2023 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 North Carolina 2L or IMAC .. on 1 401) 21) 1. 0� 41. 12.. MW-7 7-Nov-11 2.3 24 0.8J 13 0.81 0.51 0.61 1.11 MW-7 8-May-12 0.91 11 0.81 8.5 1.0) 0.61 0.41 MW-7 27-Nov-12 2.3 29 0.8BJ 14 0.3) 0.71 0.4J 0.51 MW-7 9-May-13 1.81 2.2 24 0.81 15 0.71 0.3J 0.4J 6.3 MW-7 5-Nov-13 1.4 17 0.81 IS 0.51 0.61 0.4J MW-7 5-May-14 1.7 16 0.61 13 0.41 0.71 0.31 MW-7 3-Nov-14 1.6 29 0.91 14 0.51 02J MW-7 4-May-15 1.6 33 0.8) 0.31 MW-7 26-0ct-15 1.9 38 0.91 16 0.3J MW-7 16-May-16 1.0 19 0.71 12 0.61 MW-7 (dup) 16-May-16 0.81 17 0.81 IS 0.61 0.61 MW-7 31-Oct-16 1.4 31 0.91 14 0.4J 2.51 MW-7 8-May-17 1.5 32 0.801 14.0 1302-MSWLF-1974 MW-7 30-Oct-17 1.5 29 0.901 13.0 MW-7 6-Jun-18 1.9 32.2 0.961 22.7 0.971 MW-7 20-Dec-18 1.5 16.7 4.8 76.6 MW-7 7-May-19 1.0 20.9 0.741 9.80 0.541 1.7 130 9.71 MW-7(dup) 7-May-19 1.2 21.1 0.831 20.3 0.541 1.4 131 9.41 MW-7 4-Nov-19 2 45.8 0.961 14.8 66.5 13.9 0.861 MW-7 (dup) 4-Nov-19 2.7 0.531 0.851 16.5 61.5 12.1 0.47 MW-7 19-May-20 0.861 0.621 0.511 105 MW-7 24-5ep-20 1.2 26 0.68 10 93 MW-7 16-Mar-21 0.53 23 0.71 8.2 0.451 120 MW-7 18-Nov-21 0.70 27 0.62 7.2 0.431 120 MW-7 28-Apr-22 1.1 28 0.72 8.0 ISO MW-7 20-Oct-22 0.461 22 0.83 5.3 120 MW-7 21-A r-23 1 1.2 1 18 1 1 0.59 7.2 1 1 72 MW-8A 7-Nov-Il MW-BA 8-May-12 MW-8A 27-Nov-12 MW-8A 6-May-13 MW-8A 4-Nov-13 MW-8A 5-May-14 MW-8A 3-Nov-14 MW-8A 4-May-15 3.81 MW-BA 26-Oct-I5 MW-BA 16-May-16 MW-BA 31-0ct-16 MW-BA (dup) 31-Oct-16 MW-BA 8-May-17 1302-MSWLF-1974 MW-BA 30-Oct-17 MW-BA 6-Jun-18 0.731 MW-BA)dup) 6-Jun-18 MW-BA 20-Dec-18 MW-BA 7-May-19 2.4 MW-BA 4-Nov-19 MW-BA 19-May-20 MW-BA)dup) 19-May-20 MW-BA 24-Sep-20 MW-BA 18-Mar-21 MW-BA 18-Nov-21 MW-8A 28-APr-22 MW-BA 20-Oct-22 MW-BA 20-Apr-23 MW-10 7-Nov-11 8.2J 1.3 31 0.81 8.4 MW-10 8-May-12 1.3 32 1.01 8.9 0.21 MW-10 27-Nov-12 1.3 35 I.IBJ 9.5 0.31 MW-10 9-May-13 5.01 1.1 6.01 31 0.91 8.2 MW-10 4-Nov-13 73J 1.2 4.21 39 1.11 30 0.91 5-May-14 1.1 7.91 39 1.21 10 0.51 -10 3-Nov-14 23J 1.3 42 1.31 11 0.41 MW-10 4-May-15 8.51 1.1 40 1.21 11 0.41 MW-10 26-Oct-IS 1.2 41 1.11 9.8 0.31 MW-10 I6-May-16 1.0 39 1.01 9.6 MW-10 31-Oct-16 1.2 44.0 1.31 10 0.41 MW-10 8-May-17 I.OI 41.0 1.21 9.2 0.31 MW-10 30-Oct-17 1.0 1.01 9.0 1302-MSWLF-1974 MW-10 6-Jun-18 1.2 41.7 1.11 8.7 10.21 MW-10 20-Dec-18 1.41 MW-10 dup 20-Dec-18 8-May-19 1.1 43.8 1.1 8.6 104 24.6 -10 4-Nov-19 1.4 1.4 10.2 85.6 31.5 33.6 MW-10 19-May-20 0.931 0.941 82.8 MW-10 24-5ep-20 1.5 40 0.86 6.9 76 MW-10 (dup) 24-5ep-20 1.5 40 0.96 7.1 79 MW-10 16-Mar-21 0.96 26 0.58 4.1 63 MW-10 18-Nov-21 1.1 39 0.87 6.6 7.5 MW-10 28-AP122 1 31 0.75 4.8 71 MW-10 20-Oct-22 0.93 25 0.491 3.7 60N MW-10 20-Apr-23 1.2 30 0.58 4.4 59 MW-10(dup) 20-Apr-23 1.1 34 0.66 4.9 51 Smith 5 of 7 July 2023 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 NEW.. North Carolina 2L or IMAC � W4.. C 03 20. W�� 1. 304.01 2,000' 100 0.0 W. MW-11 7-Nov-11 1.3 13 7.6 0.41 031 0.51 MW-11 8-May-12 MW-11 27-Nov-12 1.3 18 0.7B1 8A 0.3J 0.4J MW-11 9-May-13 1.01 MW-11 4-14ov-13 1.1 16 0.51 7.6 MW-11 5-May-14 0.41 4.5 1.7 MW-11 3-Nov-14 1.4 19 0.7I 9A 0.51 MW-11 4-May-15 0.41 6.0 1.8 MW-11 26-Oct-15 0.91 16 0.61 9.0 0.41 MW-11 16-May-16 0.31 4.6 1.6 MW-11 31-Oct-16 1.2 18 0.7J 8.8 2.5J MW-11 8-May-17 3.8 MW-11)dup) 8-May-17 2.9) MW-11 30-Oct-17 1.2 18 0.11 8.6 1302-MSWLF-1974 MW-11(dup) 30-Oct-17 1.1 16 0.71 8.0 MW-11 6-Jun-18 13.51 0.901 14.0 5.5 MW-I1 20-Dec-18 2.1 MW-I1 8-May-19 0.571 6.8 2.1 26.2 3AJ MW-Il 4-14ov-19 1.2 18.6 0.751 0.671 7A 46.2 10.8 MW-Il 19-May-20 12.1 MW-I1 24-Sep-20 5.2 1.7 20 MW-I1 16-Mar-21 MW-11(dup) 16-Mar-21 MW-11 18-Nov-21 0.94 11 0.441 4.7 45 MW-11(dup) 18-Nov-21 0.98 11 0.41J 4.6 45 MW-11 28-Apr-22 5.1 MW-11(dup) 28-Apr-22 4.2 MW-11 20-Oct-22 0.87 13 0.63 6.0 48 MW-11)dup) 20-Oct-22 0.91 13 0.63 6.0 49 MW-I1 20-Apr-23 11 Notes: 1. All units are in micrograms per liter (parts per billion). 2.' -Inter Maximum Allowable Concentration (IMAC) 3. dup -Duplicate Sample 4.1- Indicates the analytical result !,an established concentration between the method detection limit and the adjusted reporting limit. 5. B - The analyte concentration detected in the method blank was greater than the method detection limit. 6. L - Laboratory control sample/laboratory control sample duplicate failure. ]. H -The analyte was analyzed outside of hold time. Concentration exceeds the ISA NCAC 02L.0202 (North Carolina 2L) or IMAC. - Indicates the result is below the detection limit. Smith 6 of 7 July 2023 Table 3c Detected Surface Water Constituents - Metals and Volatile Organic Compounds April 2023 Semi -Annual Sampling Event Cabarrus County Unit 1 Landfill Facility Permit Number 1302-MSWLF-1974 I 94.01 I 0.771 2.601 0.23J 5.321 1.74J I Aq .tic Life or Fish 1302-MSWLF-1974 Consumption SW-1 SW-1 SW-1 W.1 SW SW-1 SW-1 SW-1 SW-1 SW SW-1 5W-1 SW-1 SW-1 SW-1 SW SW-1 5W-1 SW SW SW-1 5W-1 5W-1 Standa rd 9-Nov-11 9-May-12 28-Nov-12 10-May-13 5-Nov- 14 3-Nov-14 5-May-IS 29-Oct-15 19-May-16 1-Nov-16 30-May-17 31-Oct-17 7-Jun-18 18-Dec-18 9-May-19 6-Nov-19 19-May-20 25-Sep-20 19-Mar-21 17-Nov-21 28-Apr-22 20-Oct-22 19-Apr-23 DRY DRY DRY 61 01 82. 139 146 0.371 -06J3.79J 9.521 31.7 .DRY 20 1.751 6.341 0.16J 0.091 3.5861 6.3 85 9.79111 2.05J 2851 2.831 121 14.4 4.931 . 20SW 0.31 DRY DRV DRY DRY 0.891 3.521 69.2J 157 1.44 37.2 1.01J 15.6 1.72J 25.1 14.g 5.091 17.21 4.391 5.331 2.93CN,J 0.081 65.2 2.371 64.0 DRY DRY 66.6J 3.691 2.041 1.04J 0.07J 5.92J DRY DRY DRY DRY 0.701 57.61 66.9 59.1 65.4 49 61 0.0521 0.24J 1.81 0.76J 0.71J 4.51 2.9J 2.61 3.0J 0.38J 1,11 1.91 1.71 2.01 1.3J 5.0B 1.11 7.2 4.31 0.341 0.161 0.0641E 0.111 2.4 1.3 4.41 5.1 2.91 4.51 4.51 7.4 0.0581 3.21 1.3J 8.6 3.5J 4.9J 3.9JB 6.51E 3.1I 13 19 4.4 8.7 5.9 9.9 1.2J 2.1 DRY DRY DRY DRY DRY DRY 46 1 1 4.4J 8.3 1302-MSWLF-1974 SW-2 SW SW SW SW SW-2 SW SW SW SW SW SW SW-2 SW-2 SW-2 5W-2 SW-2 SW-2 SW-2 SW SW SW-2 SW-2 SW-2 9-Nov-11 9-May-12 28-Nov-12 10-May-13 5-Nov-13 6-May-14 3-Nov-14 5-May-15 29-0ct-15 19-May-16 1-Nov-16 10-May-17 31-0ct-17 7-Jun-18 18-Dec-18 10-May-19 6-Nov-19 19-May-20 25-Sep-20 19-Mar-21 17-Nov-21 28-Apr-22 20-Oct-22 19-Apr-23 DRY DRY 65.3J 1.061 0.881 1.681 0.85J 3.331 1.33J DRY DRY 0.97J 78.91 0,63) 2.53J 2.20J 0.841 6.36J 3.021 6.051 DRY DRY 1.45J 1.881 1.681 2.35J 137 67.0J 73.2B-01) 81.11 89.01 0.051 0.10J 0.941 12.2 3.29J 12.7 3.161 0.69J 7.21J 3.65J 0.571 1.211 3.64J 12.9 1.528J 0.05J 0.951 8.731 6.991 1.421 6.34J 4.601 8.33J 3.681 1.081 3.40J 6.501 3.401 3.2BCN,l 7.11J 1.931 32.7 24.5 5.15E-01,J 1.36J 5.48J 35.0 6.0J 1.8 DRY DRY 94.7J 2.22I 0.89J 0.311 4.81J DRY DRY 0.62J 0.991 0.63J 0.691 2.7 42.9J 71.81 83.8 83.9 100 91 37 0.111 0.23J 0.77 0.301 1.91 0.66J 3.5J 25 2.6J 1.81 2.31 0.35J 3.21 4.81 1.41 1.91 1.71 3.31E 4.11 18 9.8 0.371 0.91J 0.221B 2.2 8.8 1.4 2.51 3.11 5.1 2.7J 5.4 8.8 2.4J 1.7J 2.7J 4.3J 1.3J B.61 33 7.1 3.6J 2.81B 7.1JB 10.2 34 5.2I 2.5 7.3 3.8 6.7 1.8 DRY DRY DRY DRY DRY DRV 51 1 1 1 1.31 1 1 4.7J 3.51 8.3 Notes. 1. All units are in micrograms per liter (parts per billion). 2. NS- No Standard 3. I3I- A Standard for total chromium has not been established. The value provided is for chromium (III). 4. (0I- North Carolina 15A NCAC 02B INC 2B) Fish Consumption Standard 5. IsI - North Carolina In -Stream Target Value Freshwater Aquatic Life Standard 6. ISI- NC 2B Freshwater Aquatic Life Standard 7. pI- North Carolina In -Stream Target Value Fish Consumption Standard 8. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation. 9. B - The analyte concentration detected in the method blank was greater than the method detection limit. 10. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid. Concentration exceeds the NC 2B or In -Stream Target Value Freshwater Aquatic Life or Fish Consumption Standard for Class C Waters - July 2021 - Indicates the result is below the detection limit. Smith of July 2023 Table 4 Constituents Detected Above Standards April 2023 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Monitoring Well Parameters Exceeding North Carolina 2L Standard Facility Permit Number .. April CD-1s 1302-MSWLF-1974 None Detected (background well) CD-1d 1302-MSWLF-1974 None Detected (background well) 1302-MSWLF-1974 MW-5 Cobalt, 1,4-Dioxane 1302-MSWLF-1974 MW-7 Cobalt, Benzene, 1,4-Dichlorobenzene, 1,4-Dioxane 1302-MSWLF-1974 MW-8A Cobalt, Nickel 1302-MSWLF-1974 MW-10 Arsenic, Cobalt, Nickel, Benzene, 1,4-Dioxane 1302-MSWLF-1974 MW-11 Cobalt, 1,4-Dioxane Smith Page 1 of 1 July 2023 N w + E s MW-X 700.78 MGW-1 733.51 'MGW-14' SW-3 ��\ 'i733.28 ,20 CD-4 Rep 3� \ C&D 1 731.70 1 ' CD-2\ 7z1s1 ,Landfill < 710� 706.09. 05.43 ��'. Unit 2 i A t-------_ Unit MGW-17,Mw-8F 710.71 A MW-J ' /MW-1 �710, -. 701.43. MGW-2 689.33 ` MW-10 - �```—,I / 693.79 / M\ / I 695.59 ADO MW-A / /MW-G MW-5 � f 704.50 / / 685.72 681.27 / MW - 90 -B s Unit 3 �7916 MGW-3 A MW 694. 6g0 MW-C /- 689.37 MW-y( / 682.49 AMW-lde / 673.71 / 672.58 AMW-1s / MW-H deep 672.22 AMW-2s 671.29 670 Scale in Feet 0 500 1000 Map Data Source: 2019 Aerial Photograph, Cahartus County; North Carolina OneMap. 673.95 , AMW-2d / 671.72 6� MW L 6 657.80 \680 SW-1 MW-11 678.92 LEGEND Groundwater Monitoring Well Surface Water Sample Location ® Landfill Gas Well Location Potentiometric Contour 680 — (dashed where inferred) Contour Interval = 10 Feet Appendix A aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Cabarrus County LF Background Lot Number:YD20011 Date Completed:05/24/2023 06/16/2023 1:35 PM Approved and released by: Project Manager II: Cathy S. Dover =w�4 aecRFo���A4W- TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 53 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: YD20011 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. VOA 8260D Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 73639. An LCS/LCSD was run in lieu of an MS/MSD. The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 73639 exceeded acceptance criteria for the following analytes: Chloromethane (143%,141%%), Vinyl Chloride (131 %). These analytes were biased high and were not detected in the associated samples: YD20011-001, YD20011-002, and YD20011-004. YD20011-001 (CD-1d) (Run 1) (Analysis Batch 73639) YD20011-002 (CD-1s) (Run 1) (Analysis Batch 73639) YD20011-004 (Trip Blank) (Run 1) (Analysis Batch 73639) Dissolved Gases (RSK 175) The method blank associated with batch 74385 had Methane detected at a concentration that was above the DL but below the LOQ. All samples associated with this method blank that have detections for Methane have been flagged with a "B". If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 53 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: YD20011 Project Name: Cabarrus County LF Background Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 CD-1d Aqueous 04/19/20231435 04/20/2023 002 CD-1s Aqueous 04/19/20231500 04/20/2023 003 CD-1s Aqueous 04/19/20231525 04/20/2023 004 Trip Blank Aqueous 04/19/2023 04/20/2023 (4 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 53 Inorganic non-metals Client:CDM Smith Laboratory ID:YD20011-001 Description: CD-1d Matrix: Aqueous Date Sampled:04/19/2023 1435 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/28/2023 2126 JJM 74152 1 (Chloride) 9056A 1 05/03/2023 2234 SJL 74432 1 (Sulfate) 9056A 1 05/03/2023 2234 SJL 74436 1 (TDS) SM 2540C-2015 1 04/26/2023 2127 CBP 73738 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 53 20 20 mg CaCO3/L 1 9056A 3.3 1.0 0.25 mg/L 1 9056A 2.1 1.0 0.25 mg/L 1 SM 254OC-2015 120 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-001 Description: CD-1d Matrix: Aqueous Date Sampled:04/19/2023 1435 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0154 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D ND 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND L 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-001 Description: CD-1d Matrix: Aqueous Date Sampled:04/19/2023 1435 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0154 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND L 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 117 70-130 Toluene-d8 111 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 53 Inorganic non-metals Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 04/28/2023 2133 JJM 74152 1 (Chloride) 9056A 1 04/21/2023 0129 SJL 73294 1 (CO2 (calcula) SM 4500-CO2 D 1 04/28/2023 2133 JJM 1 (COD) SM 5220D-2011 1 05/11/2023 1635 GGC 75097 1 (Nitrate - N) 9056A 1 04/21/2023 0129 SJL 73299 1 (Sulfate) 9056A 1 04/21/2023 0129 SJL 73300 1 (Sulfide) SM 4500-S2 F-2011 1 04/26/2023 1052 CVR 73684 1 (TDS) SM 2540C-2015 1 04/26/2023 2127 CBP 73738 2 (TOC) SM 531 OC-2014 1 05/05/2023 2131 DMA 74595 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 50 20 20 mg CaCO3/L 1 Chloride 9056A 9.0 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CO2 D 71 27 27 mg/L 1 COD SM 5220D-2011 ND 20 20 mg/L 1 Nitrate - N 9056A 0.22 0.020 0.0050 mg/L 1 Sulfate 9056A 0.53 J 1.0 0.25 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 ND 1.0 1.0 mg/L 1 TDS SM 254OC-2015 120 25 25 mg/L 1 TOC SM 531OC-2014 1.5 1.0 1.0 mg/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0218 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D ND 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND L 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/2023 0218 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND L 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 120 70-130 Toluene-d8 109 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 53 Dissolved Gases Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/03/2023 1434 JWG 74385 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane Ethene Methane 74-84-0 RSK - 175 ND 10 2.5 ug/L 1 74-85-1 RSK - 175 ND 10 2.5 ug/L 1 74-82-8 RSK - 175 5.9 BJ 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 53 CVAA Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/01/2023 1915 KJEW 05/01/2023 0325 74037 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 53 ICP-MS Metals Client:CDM Smith Laboratory ID:YD20011-002 Description: CD-1s Matrix: Aqueous Date Sampled:04/19/2023 1500 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2023 0056 BNW Prep Date Batch 04/23/2023 1915 73235 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 37 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 620 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 17 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.3 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-004 Description: Trip Blank Matrix: Aqueous Date Sampled:04/19/2023 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 2313 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D ND 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND L 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 53 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD20011-004 Description: Trip Blank Matrix: Aqueous Date Sampled:04/19/2023 Project Name: Cabarrus County LF Date Received:04/20/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/25/2023 2313 CDA 73639 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND L 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 114 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 53 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD20011 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 53 Inorganic non-metals - MB Sample ID: YQ73294-001 Matrix: Aqueous Batch: 73294 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 04/20/2023 2303 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ73294-002 Matrix: Aqueous Batch: 73294 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 20 1 101 80-120 04/20/2023 2323 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ73299-001 Matrix: Aqueous Batch: 73299 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N ND 1 0.020 0.0050 mg/L 04/20/2023 2303 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ73299-002 Matrix: Aqueous Batch: 73299 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.80 1 99 80-120 04/20/2023 2323 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ73300-001 Matrix: Aqueous Batch:73300 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 04/20/2023 2303 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ73300-002 Matrix: Aqueous Batch:73300 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 102 80-120 04/20/2023 2323 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ73684-001 Matrix: Aqueous Batch:73684 Analytical Method: SM 4500-S2 F-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfide ND 1 1.0 1.0 mg/L 04/26/20231052 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ73684-002 Matrix: Aqueous Batch:73684 Analytical Method: SM 4500-S2 F-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfide 10 9.4 1 94 80-120 04/26/20231052 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ73738-001 Matrix: Aqueous Batch:73738 Analytical Method: SM 2540C-2015 Parameter Result Q Dil LOQ DL Units Analysis Date TDS ND 1 25 25 mg/L 04/26/2023 2127 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ73738-002 Matrix: Aqueous Batch:73738 Analytical Method: SM 2540C-2015 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 50 48 1 96 90-110 04/26/2023 2127 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ74152-002 Matrix: Aqueous Batch: 74152 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 99 1 99 90-110 04/28/2023 2031 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ74432-001 Matrix: Aqueous Batch:74432 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.25 mg/L 05/03/20231635 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ74432-002 Matrix: Aqueous Batch:74432 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 20 1 100 80-120 05/03/20231654 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MS Sample ID: YD2001 1 -001 MS Matrix: Aqueous Batch:74432 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 3.3 10 13 1 100 80-120 05/03/2023 2253 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MSD Sample ID: YD20011-001MID Matrix: Aqueous Batch:74432 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 3.3 10 13 1 101 0.48 80-120 20 05/03/2023 2312 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ74436-001 Matrix: Aqueous Batch:74436 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.25 mg/L 05/03/20231635 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ74436-002 Matrix: Aqueous Batch:74436 Analytical Method: 9056A Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 99 80-120 05/03/20231654 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MS Sample ID: YD2001 1 -001 MS Matrix: Aqueous Batch:74436 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 2.1 10 12 1 94 80-120 05/03/2023 2253 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MSD Sample ID: YD20011-001MID Matrix: Aqueous Batch:74436 Analytical Method: 9056A Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 2.1 10 12 1 96 0.98 80-120 20 05/03/2023 2312 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ74595-001 Matrix: Aqueous Batch: 74595 Analytical Method: SM 531 OC-2014 Parameter Result Q Dil LOQ DL Units Analysis Date TOC ND 1 1.0 1.0 mg/L 05/05/2023 2020 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ74595-002 Matrix: Aqueous Batch: 74595 Analytical Method: SM 531 OC-2014 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 40 39 1 98 90-110 05/05/2023 2031 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - MB Sample ID: YQ75097-001 Matrix: Aqueous Batch: 75097 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD ND 1 20 20 mg/L 05/11/20231633 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 53 QC Data for Lot Number: YD20011 Inorganic non-metals - LCS Sample ID: YQ75097-002 Matrix: Aqueous Batch: 75097 Analytical Method: SM 5220D-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 40 41 1 103 95-105 05/11/20231633 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 53 QC Data for Lot Number: YD20011 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73639-001 Matrix: Aqueous Batch: 73639 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 10 4.0 ug/L 04/25/2023 2115 Acrylonitrile ND 1 5.0 0.80 ug/L 04/25/2023 2115 Benzene ND 1 0.50 0.40 ug/L 04/25/2023 2115 Bromochloromethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Bromodichloromethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Bromoform ND 1 0.50 0.40 ug/L 04/25/2023 2115 Bromomethane (Methyl bromide) ND 1 0.50 0.40 ug/L 04/25/2023 2115 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/25/2023 2115 Carbon disulfide ND 1 0.50 0.40 ug/L 04/25/2023 2115 Carbon tetrachloride ND 1 0.50 0.40 ug/L 04/25/2023 2115 Chlorobenzene ND 1 0.50 0.40 ug/L 04/25/2023 2115 Chloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Chloroform ND 1 0.50 0.40 ug/L 04/25/2023 2115 Chloromethane (Methyl chloride) ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,2-Dibromo-3-chloropropane (DBCP) ND 1 0.50 0.40 ug/L 04/25/2023 2115 Dibromochloromethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,2-Dibromoethane (EDB) ND 1 0.50 0.40 ug/L 04/25/2023 2115 Dibromomethane (Methylene bromide) ND 1 0.50 0.40 ug/L 04/25/2023 2115 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.40 ug/L 04/25/2023 2115 1,2-Dichlorobenzene ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,4-Dichlorobenzene ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,1-Dichloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,2-Dichloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,1-Dichloroethene ND 1 0.50 0.40 ug/L 04/25/2023 2115 cis- 1,2-Dichloroethene ND 1 0.50 0.40 ug/L 04/25/2023 2115 trans- 1,2-Dichloroethene ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,2-Dichloropropane ND 1 0.50 0.40 ug/L 04/25/2023 2115 cis- 1,3-Dichloropropene ND 1 0.50 0.40 ug/L 04/25/2023 2115 trans- 1,3-Dichloropropene ND 1 0.50 0.40 ug/L 04/25/2023 2115 Ethylbenzene ND 1 0.50 0.40 ug/L 04/25/2023 2115 2-Hexanone ND 1 10 2.0 ug/L 04/25/2023 2115 Methacrylonitrile ND 1 5.0 2.0 ug/L 04/25/2023 2115 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/25/2023 2115 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/25/2023 2115 Methylene chloride ND 1 0.50 0.40 ug/L 04/25/2023 2115 Styrene ND 1 0.50 0.41 ug/L 04/25/2023 2115 1,1,1,2-Tetrachloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,1,2,2-Tetrachloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Tetrachloroethene ND 1 0.50 0.40 ug/L 04/25/2023 2115 Tetrahydrofuran ND 1 5.0 1.0 ug/L 04/25/2023 2115 Toluene ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,1,1-Trichloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,1,2-Trichloroethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Trichloroethene ND 1 0.50 0.40 ug/L 04/25/2023 2115 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 53 QC Data for Lot Number: YD20011 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73639-001 Matrix: Aqueous Batch:73639 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichlorofluoromethane ND 1 0.50 0.40 ug/L 04/25/2023 2115 1,2,3-Trichloropropane ND 1 0.50 0.40 ug/L 04/25/2023 2115 Vinyl acetate ND 1 5.0 1.2 ug/L 04/25/2023 2115 Vinyl chloride ND 1 0.50 0.40 ug/L 04/25/2023 2115 Xylenes (total) ND 1 1.0 0.40 ug/L 04/25/2023 2115 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 105 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 110 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD20011 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 53 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73639-002 Matrix: Aqueous Batch: 73639 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 110 60-140 04/25/2023 1901 Acrylonitrile 100 96 1 96 70-130 04/25/2023 1901 Benzene 50 49 1 99 70-130 04/25/2023 1901 Bromochloromethane 50 47 1 94 70-130 04/25/2023 1901 Bromodichloromethane 50 47 1 95 70-130 04/25/2023 1901 Bromoform 50 49 1 99 70-130 04/25/2023 1901 Bromomethane (Methyl bromide) 50 61 1 121 70-130 04/25/2023 1901 2-Butanone (MEK) 100 100 1 103 70-130 04/25/2023 1901 Carbon disulfide 50 47 1 93 70-130 04/25/2023 1901 Carbon tetrachloride 50 50 1 99 70-130 04/25/2023 1901 Chlorobenzene 50 50 1 99 70-130 04/25/2023 1901 Chloroethane 50 59 1 119 70-130 04/25/2023 1901 Chloroform 50 49 1 99 70-130 04/25/2023 1901 Chloromethane (Methyl chloride) 50 72 N 1 143 60-140 04/25/2023 1901 1,2-Dibromo-3-chloropropane (DBCP) 50 46 1 93 70-130 04/25/2023 1901 Dibromochloromethane 50 49 1 99 70-130 04/25/2023 1901 1,2-Dibromoethane (EDB) 50 51 1 101 70-130 04/25/2023 1901 Dibromomethane (Methylene bromide) 50 48 1 96 70-130 04/25/2023 1901 trans- 1,4-Dichloro-2-butene 50 46 1 91 70-130 04/25/2023 1901 1,2-Dichlorobenzene 50 47 1 94 70-130 04/25/2023 1901 1,4-Dichlorobenzene 50 46 1 92 70-130 04/25/2023 1901 1,1-Dichloroethane 50 46 1 93 70-130 04/25/2023 1901 1,2-Dichloroethane 50 47 1 95 70-130 04/25/2023 1901 1,1-Dichloroethene 50 50 1 100 70-130 04/25/2023 1901 cis- 1,2-Dichloroethene 50 48 1 96 70-130 04/25/2023 1901 trans- 1,2-Dichloroethene 50 48 1 96 70-130 04/25/2023 1901 1,2-Dichloropropane 50 48 1 96 70-130 04/25/2023 1901 cis- 1,3-Dichloropropene 50 53 1 105 70-130 04/25/2023 1901 trans- 1,3-Dichloropropene 50 52 1 104 70-130 04/25/2023 1901 Ethylbenzene 50 56 1 111 70-130 04/25/2023 1901 2-Hexanone 100 98 1 98 70-130 04/25/2023 1901 Methacrylonitrile 250 260 1 103 70-130 04/25/2023 1901 Methyl iodide (lodomethane) 50 46 1 92 70-130 04/25/2023 1901 4-Methyl-2-pentanone 100 110 1 107 70-130 04/25/2023 1901 Methylene chloride 50 52 1 104 70-130 04/25/2023 1901 Styrene 50 51 1 102 70-130 04/25/2023 1901 1,1,1,2-Tetrachloroethane 50 48 1 96 70-130 04/25/2023 1901 1,1,2,2-Tetrachloroethane 50 45 1 89 70-130 04/25/2023 1901 Tetrachloroethene 50 54 1 107 70-130 04/25/2023 1901 Tetrahydrofuran 50 48 1 96 70-130 04/25/2023 1901 Toluene 50 53 1 106 70-130 04/25/2023 1901 1,1,1-Trichloroethane 50 47 1 95 70-130 04/25/2023 1901 1,1,2-Trichloroethane 50 47 1 95 70-130 04/25/2023 1901 Trichloroethene 50 52 1 103 70-130 04/25/2023 1901 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 53 QC Data for Lot Number: YD20011 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73639-002 Matrix: Aqueous Batch:73639 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichlorofluoromethane 50 62 1 123 70-130 04/25/2023 1901 1,2,3-Trichloropropane 50 46 1 91 70-130 04/25/2023 1901 Vinyl acetate 50 46 1 92 60-140 04/25/2023 1901 Vinyl chloride 50 65 N 1 131 70-130 04/25/2023 1901 Xylenes (total) 100 110 1 113 70-130 04/25/2023 1901 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 113 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 109 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD20011 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 53 Volatile Organic Compounds by GC/MS - LCSD Sample ID: YQ73639-003 Matrix: Aqueous Batch: 73639 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Acetone 100 110 1 106 4.4 60-140 20 04/25/2023 1948 Acrylonitrile 100 94 1 94 1.8 70-130 40 04/25/2023 1948 Benzene 50 48 1 97 2.0 70-130 20 04/25/2023 1948 Bromochloromethane 50 48 1 95 1.1 70-130 20 04/25/2023 1948 Bromodichloromethane 50 46 1 93 1.8 70-130 20 04/25/2023 1948 Bromoform 50 47 1 93 6.0 70-130 20 04/25/2023 1948 Bromomethane (Methyl bromide) 50 61 1 121 0.033 70-130 20 04/25/2023 1948 2-Butanone (MEK) 100 99 1 99 4.8 70-130 20 04/25/2023 1948 Carbon disulfide 50 48 1 97 3.8 70-130 20 04/25/2023 1948 Carbon tetrachloride 50 49 1 97 1.7 70-130 20 04/25/2023 1948 Chlorobenzene 50 48 1 96 3.2 70-130 20 04/25/2023 1948 Chloroethane 50 59 1 118 0.086 70-130 20 04/25/2023 1948 Chloroform 50 50 1 100 0.95 70-130 20 04/25/2023 1948 Chloromethane (Methyl chloride) 50 71 N 1 141 1.6 60-140 20 04/25/2023 1948 1,2-Dibromo-3-chloropropane (DBCP) 50 48 1 97 4.3 70-130 20 04/25/2023 1948 Dibromochloromethane 50 47 1 95 4.0 70-130 20 04/25/2023 1948 1,2-Dibromoethane (EDB) 50 49 1 98 3.0 70-130 20 04/25/2023 1948 Dibromomethane (Methylene bromide) 50 47 1 94 2.0 70-130 20 04/25/2023 1948 trans- 1,4-Dichloro-2-butene 50 43 1 86 6.2 70-130 20 04/25/2023 1948 1,2-Dichlorobenzene 50 48 1 97 2.6 70-130 20 04/25/2023 1948 1,4-Dichlorobenzene 50 47 1 93 0.88 70-130 20 04/25/2023 1948 1,1-Dichloroethane 50 47 1 94 0.78 70-130 20 04/25/2023 1948 1,2-Dichloroethane 50 47 1 94 0.51 70-130 20 04/25/2023 1948 1,1-Dichloroethene 50 51 1 102 1.7 70-130 20 04/25/2023 1948 cis- 1,2-Dichloroethene 50 49 1 97 0.87 70-130 20 04/25/2023 1948 trans- 1,2-Dichloroethene 50 48 1 96 0.11 70-130 20 04/25/2023 1948 1,2-Dichloropropane 50 47 1 94 1.8 70-130 20 04/25/2023 1948 cis- 1,3-Dichloropropene 50 51 1 102 3.6 70-130 20 04/25/2023 1948 trans- 1,3-Dichloropropene 50 52 1 103 0.71 70-130 20 04/25/2023 1948 Ethylbenzene 50 54 1 108 2.7 70-130 20 04/25/2023 1948 2-Hexanone 100 88 1 88 10 70-130 20 04/25/2023 1948 Methacrylonitrile 250 250 1 101 2.0 70-130 20 04/25/2023 1948 Methyl iodide (lodomethane) 50 49 1 97 5.4 70-130 20 04/25/2023 1948 4-Methyl-2-pentanone 100 99 1 99 8.1 70-130 20 04/25/2023 1948 Methylene chloride 50 55 1 110 5.4 70-130 20 04/25/2023 1948 Styrene 50 49 1 99 3.2 70-130 20 04/25/2023 1948 1,1,1,2-Tetrachloroethane 50 48 1 96 0.34 70-130 20 04/25/2023 1948 1,1,2,2-Tetrachloroethane 50 44 1 89 0.067 70-130 20 04/25/2023 1948 Tetrachloroethene 50 52 1 103 3.8 70-130 20 04/25/2023 1948 Tetrahydrofuran 50 46 1 93 3.1 70-130 20 04/25/2023 1948 Toluene 50 52 1 104 1.7 70-130 20 04/25/2023 1948 1,1,1-Trichloroethane 50 48 1 96 1.2 70-130 20 04/25/2023 1948 1,1,2-Trichloroethane 50 46 1 92 2.4 70-130 20 04/25/2023 1948 Trichloroethene 50 51 1 102 0.95 70-130 20 04/25/2023 1948 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 53 QC Data for Lot Number: YD20011 Volatile Organic Compounds by GC/MS - LCSD Sample ID: YQ73639-003 Matrix: Aqueous Batch:73639 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Trichlorofluoromethane 50 63 1 127 2.6 70-130 20 04/25/2023 1948 1,2,3-Trichloropropane 50 46 1 91 0.48 70-130 20 04/25/2023 1948 Vinyl acetate 50 47 1 94 1.6 60-140 20 04/25/2023 1948 Vinyl chloride 50 64 1 128 1.7 70-130 20 04/25/2023 1948 Xylenes (total) 100 110 1 110 3.1 70-130 20 04/25/2023 1948 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 107 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD20011 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 53 Dissolved Gases - MB Sample ID: YQ74385-001 Matrix: Aqueous Batch: 74385 Analytical Method: RSK - 175 Parameter Result Q Dil LOQ DL Units Analysis Date Ethane ND 1 10 2.5 ug/L 05/03/20231132 Ethene ND 1 10 2.5 ug/L 05/03/20231132 Methane 2.9 J 1 10 2.5 ug/L 05/03/20231132 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 53 QC Data for Lot Number: YD20011 Dissolved Gases - LCS Sample ID: YQ74385-002 Matrix: Aqueous Batch: 74385 Analytical Method: RSK - 175 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Ethane 550 580 1 104 70-130 05/03/20231038 Ethene 520 530 1 102 70-130 05/03/20231038 Methane 300 280 1 95 70-130 05/03/20231038 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 53 QC Data for Lot Number: YD20011 ICP-MS Metals - MB Sample ID: YQ73235-001 Matrix: Aqueous Batch: 73235 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/23/2023 1915 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/28/20231947 Arsenic ND 1 2.0 1.3 ug/L 04/28/20231947 Barium ND 1 5.0 1.3 ug/L 04/28/20231947 Beryllium ND 1 0.40 0.15 ug/L 04/28/20231947 Cadmium ND 1 0.50 0.13 ug/L 04/28/20231947 Chromium ND 1 5.0 1.3 ug/L 04/28/20231947 Cobalt ND 1 5.0 1.3 ug/L 04/28/20231947 Copper ND 1 5.0 1.3 ug/L 04/28/20231947 Iron ND 1 50 13 ug/L 04/28/20231947 Lead ND 1 1.0 0.25 ug/L 04/28/20231947 Manganese ND 1 5.0 1.3 ug/L 04/28/20231947 Nickel ND 1 5.0 1.3 ug/L 04/28/20231947 Selenium ND 1 5.0 1.3 ug/L 04/28/20231947 Silver ND 1 1.0 0.25 ug/L 04/28/20231947 Thallium ND 1 0.50 0.15 ug/L 04/28/20231947 Vanadium ND 1 5.0 2.5 ug/L 04/28/20231947 Zinc ND 1 10 2.5 ug/L 04/28/20231947 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 53 QC Data for Lot Number: YD20011 ICP-MS Metals - LCS Sample ID: YQ73235-002 Matrix: Aqueous Batch: 73235 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/23/2023 1915 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 101 80-120 04/28/20231959 Arsenic 100 100 1 102 80-120 04/28/20231959 Barium 100 100 1 103 80-120 04/28/20231959 Beryllium 100 98 1 98 80-120 04/28/20231959 Cadmium 100 110 1 106 80-120 04/28/20231959 Chromium 100 110 1 111 80-120 04/28/20231959 Cobalt 100 120 1 117 80-120 04/28/20231959 Copper 100 110 1 112 80-120 04/28/20231959 Iron 1000 1100 1 114 80-120 04/28/20231959 Lead 100 110 1 110 80-120 04/28/20231959 Manganese 100 100 1 104 80-120 04/28/20231959 Nickel 100 110 1 112 80-120 04/28/20231959 Selenium 100 91 1 91 80-120 04/28/20231959 Silver 100 110 1 112 80-120 04/28/20231959 Thallium 100 110 1 108 80-120 04/28/20231959 Vanadium 100 100 1 105 80-120 04/28/20231959 Zinc 100 100 1 104 80-120 04/28/20231959 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 53 QC Data for Lot Number: YD20011 CVAA -MB Sample ID: YQ74037-001 Matrix: Aqueous Batch:74037 Prep Method: Analytical Method: 7470A Prep Date: 05/01/2023 0325 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00020 0.000091 mg/L 05/01/20231848 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 53 QC Data for Lot Number: YD20011 CVAA - LCS Sample ID: YQ74037-002 Matrix: Aqueous Batch:74037 Prep Method: Analytical Method: 7470A Prep Date: 05/01/2023 0325 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0020 1 98 80-120 05/01/20231851 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 53 QC Data for Lot Number: YD20011 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 53 PACE ANALYTICAL SERVICES, LLC LO �r S- z tiL �a, F yy�� y ;iY C'•aj'.'4 is Y.'�L15?� lp wl� I .17 r � iL r, QF. V c Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 53 PACE ANALYTICAL SERVICES, LLC fDC#_7ir!e: ENV F RM WCOL-0281i vG2_SmT1ple5 fieaeirrt4�hedkt fJ1Cj Effecdve Date. 8 A022 Sample Receipt ChPCIdist ( RU) cl;C:lr; CDh1 aRaltfl nnser 'i7s 7ectad Eaw;�j �[r= '' f K4 Ql 3 LOT A: YMCOL aids ofre�eipr: FT Pnce cht- l[ Lips ,{ }adF% Otlbrt; L_ iaJere rtrg-o SC`Afs pa>a•sratit ov �ft� cooJat± ?. Lf "c tody seals wwQ Nvrt Aieyiv#act and IM H Ship FO: =�''�k C:�rinriite Strip ID: Dx 7esiedty' A' FL lil:ti temp rahlre [�llrrr receipt 17Je:i�'e[t ('cnrec'fc[I} trla[pen,r:.a'e lyioai rece;pf '''uS01id Snal){Y[p JD;2 r 4.2 PC NA ± NA er. NA fN!t ,C NA iN cC arhv3.. ©� artlgl Mts7Ta Mznl- g,ttnst 1f310f1J9! IR char ID etiwdofcoolaztt: i W, Ic IceRi M Dr, ice F1 done [a Yss E7NQ 11NA I Vdr.ie all cuoler6 ieeeiverl at or bewy? 15.0°c? If a u, lwas Peoject I�.Tiiapr imfi fiod? PM-6vas NofiHcd b}. plume l ent9ii 1 frle�?u-hre (eiicle ❑nr). Yes i�o N4 4, 11 f:ie coaunlerciaJ cn1h'iel''S tki17hj[L� Sip nttc.Ch" to 1. ',& f*IM7 { V er NO *5_ Karr g, v r castadyproccxi,:[cs (1rJuulreis)se{,5+eoei%-ed) followed' lJ' Yes No 5, W=v &inmplc Mr. listzrl on Hitt COC ,uiL,all samnle eontaiam? I( Yes NO 7_ Was cofiecriali cja;�- & iiuic lisfed uri IFre CUC aed all sur'iple enortakne s.1 'e9f A. Thai n2l Ccuitariaier Ael infommion (1D. date, risk) agree mid1 dw CO'C? ,{ 77 .No J_ 4tr"e *M& 10 t-t performed Uved cast Ore 00CG' IDY,6 FIND [Or Did all saiig33es arrive in slue proper {-u tj&L:i71 :or cmLi w9t ffl&o' it gWd MiifitTM {11r[Ixiv%aL 1aCJb ❑il, �t�_},� 11_ Wa[e arlixJuara 5ampieialtlf a alldiri rle';ts E esr Ido No I2r Wue Al samples r6mival- �.IWa M #ireJhr[�l&g f a-.Lr yr 45 hvltirs, wllicJ � C conies first QYrs [:]No ] 3. )Vefe ye116M-UP]U'v Cau'Miaiera aCC0unted foaQ (Na rrglSFutg'eXGeS3) [AY-51i1! [:]RA14. Were Vf)A. L'0UC and RSK 175 �'aLllple-, f72c' ofLOCOS >`VQS-y17e$ tip,-CH-6111-'.5 P'I dl& meter) ki any of rlre VGA yje Yet Ido INA 15. Wei+- M11 DRO+tratalsknurdegr of a Pxf of- 2? Yes No I IAA 11. Wf:1'2 all Cyuiitle sat ec reeeia-�M Q; El y=1-- 12 and aul.f de sauv)J!ee race i w et: rr s PH > 4' 17. INdit ail a pp ica a �r'f17Muyn13idttuUx- w11EZ:1. 1i _3 (t Gl arsr�e:aJ cIY3 I' ❑Yes QNo ©-NA 1R. WM-k tlxe quid: [b uauaT listed on Else cmmire. lal:vcr if yam. glrote 1; ample PjLesers-.qfian (lyhrsl Lc completed fo: COY SUBPle(s) iE=1-icrily T)FLMI'Ved If With Lexrkpace_) n,pk(,) � VWe a�ecrived :.aieGrmctlypfewcved at:3 Were adjrr57er,1 acomdintily sWOk Lett%aarg Vr fll ail of63'ck ❑rc_ H2SO4. IWO3. IJCI_ NaOT-F 1isin� 9R+r !YA F. Fime r f rescn atiorrMA_ IfUWMM ttau one ,a"2�ied, P1Casenfxe ill Th12 mMkT*11ts 1~eknV -NA ware r-eceived wifli buEsbles >6 Taut 41 diaaw r, k4t) "" zvcra recce-,l Wil TRC } 0.4 Il1ar [, (if it 14 is Irv) Maud VRIV flitusted arcarduig]y ua Sawfilc r&G6%-idg w:1h sadrnuk thiowince {i�;fl;S:O�} v<'4dl TJoique IUD: Nk C nmanty. Q1JFkItfaXkIp:56360 Pare AnalirtfcafSer�iC2}, LL� 1-'ti..,e'1 a:;' i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 53 aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Cabarrus County LF-Unit 1 Lot Number:YD21009 Date Completed:05/10/2023 05/16/2023 10:48 PM Approved and released by: Project Manager II: Cathy S. Dover =w�4 aecRFo���A4W- TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 43 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: YD21009 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. VOA 8260D The continuing calibration verification (CCV) associated with analytical batch 73688 recovered outside acceptance criteria, low biased, for Dichlorodifluoromethane (-24%). An LOQ standard was analyzed, and the target analyte was detected. Since the associated samples were non -detect, no corrective action was taken. The laboratory control sample (LCS) for analytical batch 73688 exceeded acceptance criteria for the following analytes: Acetone (195%) and 2-Butanone (149%). These analytes were biased high and were not detected in the associated sample: YD21009-005. YD21009-005 (EQ Blank) (Run 1) (Analysis Batch 73688) The laboratory control sample (LCS) for analytical batch 73820 exceeded acceptance criteria for the following analytes: Acetone, 2-Butanone, Acrylonitrile, 2-Hexanone and Methacrylonitrile. These analytes were biased high and were not detected in the associated samples: YD21009-001, YD21009-002, YD21009-003, and YD21009-004. YD21009-001 (MW-10) (Run 1) (Analysis Batch 73820) YD21009-002 (MW-11) (Run 1) (Analysis Batch 73820) YD21009-003 (MW-8a) (Run 1) (Analysis Batch 73820) YD21009-004 (DUP) (Run 1) (Analysis Batch 73820) The following sample had an air bubble >6mm in the sample vial: YD21009-002. YD21009-002 (MW-11) (Run 1) (Analysis Batch 73820) Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 43 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 The method blank associated with batch 73820 had Bromomethane detected at a concentration that was above the LOQ. All sample(s) associated with this method blank were non -detect for Bromomethane. 1,4-Dioxane SIM 8260D Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 74185. An LCS/LCSD was run in lieu of an MS/MSD. YD21009-001 (MW-10) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD21009-002 (MW-11) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD21009-003 (MW-8a) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD21009-004 (DUP) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD21009-005 (EQ Blank) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate The following samples had an air bubble in the sample vial: YD21009-001 and YD21009-002. YD21009-001 (MW-10) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD21009-002 (MW-11) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 3 of 43 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: YD21009 Project Name: Cabarrus County LF-Unit 1 Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-10 Aqueous 04/20/20231115 04/21/2023 002 MW-11 Aqueous 04/20/20231245 04/21/2023 003 MW-8a Aqueous 04/20/20231405 04/21/2023 004 DUP Aqueous 04/20/2023 0800 04/21/2023 005 EQ Blank Aqueous 04/20/2023 1600 04/21/2023 (5 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-001 Description: MW-10 Matrix: Aqueous Date Sampled:04/20/2023 1115 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1606 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 UL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 UL 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.2 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 UL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 30 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.58 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.4 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 UL 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 UL 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-001 Description: MW-10 Matrix: Aqueous Date Sampled:04/20/2023 1115 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1606 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 96 70-130 115 70-130 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 43 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD21009-001 Description: MW-10 Matrix: Aqueous Date Sampled:04/20/2023 1115 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0340 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 59 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 114 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21009-001 Description: MW-10 Matrix: Aqueous Date Sampled:04/20/2023 1115 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1439 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 18 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.39 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.2 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 25 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.7 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.75 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 110 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 3.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-002 Description: MW-11 Matrix: Aqueous Date Sampled:04/20/2023 1245 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/20231631 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 UL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 UL 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 UL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 UL 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 UL 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-002 Description: MW-11 Matrix: Aqueous Date Sampled:04/20/2023 1245 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/20231631 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 115 70-130 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 43 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD21009-002 Description: MW-11 Matrix: Aqueous Date Sampled:04/20/2023 1245 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0404 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 11 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21009-002 Description: MW-11 Matrix: Aqueous Date Sampled:04/20/2023 1245 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1451 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 9.9 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 7.0 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 16 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-003 Description: MW-8a Matrix: Aqueous Date Sampled:04/20/2023 1405 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1656 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 UL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 UL 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 UL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 UL 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 UL 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-003 Description: MW-8a Matrix: Aqueous Date Sampled:04/20/2023 1405 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1656 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 117 70-130 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 43 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD21009-003 Description: MW-8a Matrix: Aqueous Date Sampled:04/20/2023 1405 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0428 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 115 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21009-003 Description: MW-8a Matrix: Aqueous Date Sampled:04/20/2023 1405 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1548 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.52 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 76 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.20 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 15 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 18 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.4 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 120 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 110 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-004 Description: DUP Matrix: Aqueous Date Sampled:04/20/2023 0800 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/20231721 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 UL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 UL 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.1 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 UL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 34 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.66 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.9 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 UL 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 UL 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-004 Description: DUP Matrix: Aqueous Date Sampled:04/20/2023 0800 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/20231721 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 112 70-130 104 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 43 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD21009-004 Description: DUP Matrix: Aqueous Date Sampled:04/20/2023 0800 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0453 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 51 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21009-004 Description: DUP Matrix: Aqueous Date Sampled:04/20/2023 0800 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1559 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 18 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.46 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020E 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 24 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.0 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.89 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 110 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 3.2 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 4.1 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-005 Description: EQ Blank Matrix: Aqueous Date Sampled:04/20/2023 1600 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231328 JM1 73688 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 UL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 5.2 JIL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 43 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD21009-005 Description: EQ Blank Matrix: Aqueous Date Sampled:04/20/2023 1600 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/26/20231328 JM1 73688 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 115 70-130 105 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 43 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD21009-005 Description: EQ Blank Matrix: Aqueous Date Sampled:04/20/2023 1600 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0228 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21009-005 Description: EQ Blank Matrix: Aqueous Date Sampled:04/20/2023 1600 Project Name: Cabarrus County LF-Unit 1 Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1611 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 5.0 U 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 43 ICP-MS Metals Client:CDM Smith Laboratory ID:YD21008-007 Description: CD-1d Matrix: Aqueous Date Sampled:04/20/2023 1535 Project Name: Cabarrus County LF-C&D Date Received:04/21/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1342 BNW Prep Date Batch 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 31 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.8 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 650 50 13 ug/L 1 Lead 7439-92-1 6020B 0.30 J 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 17 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 1.3 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.7 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 68 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD21009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 43 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73688-001 Matrix: Aqueous Batch: 73688 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 04/26/2023 1056 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 04/26/2023 1056 Benzene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Bromoform 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 04/26/2023 1056 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Chloroethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Chloroform 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 04/26/2023 1056 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 1,2-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 04/26/2023 1056 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 2-Hexanone 10 U 1 10 2.0 ug/L 04/26/2023 1056 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 04/26/2023 1056 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 04/26/2023 1056 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 04/26/2023 1056 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Styrene 0.50 U 1 0.50 0.41 ug/L 04/26/2023 1056 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Toluene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Trichloroethene 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73688-001 Matrix: Aqueous Batch:73688 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 04/26/2023 1056 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 04/26/2023 1056 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 04/26/2023 1056 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD21009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 43 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73688-002 Matrix: Aqueous Batch: 73688 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 200 N 1 195 60-140 04/26/2023 1006 Acrylonitrile 100 120 1 116 70-130 04/26/2023 1006 Benzene 50 47 1 94 70-130 04/26/2023 1006 Bromochloromethane 50 45 1 90 70-130 04/26/2023 1006 Bromodichloromethane 50 50 1 100 70-130 04/26/2023 1006 Bromoform 50 42 1 85 70-130 04/26/2023 1006 Bromomethane (Methyl bromide) 50 46 1 91 70-130 04/26/2023 1006 2-Butanone (MEK) 100 150 N 1 149 70-130 04/26/2023 1006 Carbon disulfide 50 48 1 96 70-130 04/26/2023 1006 Carbon tetrachloride 50 51 1 101 70-130 04/26/2023 1006 Chlorobenzene 50 47 1 93 70-130 04/26/2023 1006 Chloroethane 50 49 1 98 70-130 04/26/2023 1006 Chloroform 50 47 1 94 70-130 04/26/2023 1006 Chloromethane (Methyl chloride) 50 56 1 112 60-140 04/26/2023 1006 1,2-Dibromo-3-chloropropane (DBCP) 50 47 1 94 70-130 04/26/2023 1006 Dibromochloromethane 50 51 1 101 70-130 04/26/2023 1006 1,2-Dibromoethane (EDB) 50 50 1 100 70-130 04/26/2023 1006 Dibromomethane (Methylene bromide) 50 47 1 95 70-130 04/26/2023 1006 trans- 1,4-Dichloro-2-butene 50 52 1 105 70-130 04/26/2023 1006 1,2-Dichlorobenzene 50 46 1 93 70-130 04/26/2023 1006 1,4-Dichlorobenzene 50 44 1 89 70-130 04/26/2023 1006 1,1-Dichloroethane 50 47 1 94 70-130 04/26/2023 1006 1,2-Dichloroethane 50 49 1 98 70-130 04/26/2023 1006 1,1-Dichloroethene 50 47 1 94 70-130 04/26/2023 1006 cis- 1,2-Dichloroethene 50 45 1 90 70-130 04/26/2023 1006 trans- 1,2-Dichloroethene 50 45 1 91 70-130 04/26/2023 1006 1,2-Dichloropropane 50 50 1 99 70-130 04/26/2023 1006 cis- 1,3-Dichloropropene 50 50 1 100 70-130 04/26/2023 1006 trans- 1,3-Dichloropropene 50 51 1 101 70-130 04/26/2023 1006 Ethylbenzene 50 47 1 94 70-130 04/26/2023 1006 2-Hexanone 100 130 1 125 70-130 04/26/2023 1006 Methacrylonitrile 250 290 1 116 70-130 04/26/2023 1006 Methyl iodide (lodomethane) 50 44 1 88 70-130 04/26/2023 1006 4-Methyl-2-pentanone 100 100 1 103 70-130 04/26/2023 1006 Methylene chloride 50 50 1 99 70-130 04/26/2023 1006 Styrene 50 50 1 100 70-130 04/26/2023 1006 1,1,1,2-Tetrachloroethane 50 48 1 96 70-130 04/26/2023 1006 1,1,2,2-Tetrachloroethane 50 51 1 102 70-130 04/26/2023 1006 Tetrachloroethene 50 44 1 88 70-130 04/26/2023 1006 Toluene 50 46 1 93 70-130 04/26/2023 1006 1,1,1-Trichloroethane 50 46 1 92 70-130 04/26/2023 1006 1,1,2-Trichloroethane 50 50 1 100 70-130 04/26/2023 1006 Trichloroethene 50 45 1 90 70-130 04/26/2023 1006 Trichlorofluoromethane 50 47 1 94 70-130 04/26/2023 1006 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73688-002 Matrix: Aqueous Batch:73688 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 50 1 100 70-130 04/26/2023 1006 Vinyl acetate 50 48 1 97 60-140 04/26/2023 1006 Vinyl chloride 50 54 1 107 70-130 04/26/2023 1006 Xylenes (total) 100 94 1 94 70-130 04/26/2023 1006 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 87 70-130 Toluene-d8 86 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD21009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 43 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73820-001 Matrix: Aqueous Batch: 73820 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 04/27/2023 1035 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 04/27/2023 1035 Benzene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Bromoform 1.1 1 0.50 0.40 ug/L 04127/20231035 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 04/27/2023 1035 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Chloroethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Chloroform 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 04/27/2023 1035 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 04/27/2023 1035 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 2-Hexanone 10 U 1 10 2.0 ug/L 04/27/2023 1035 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 04/27/2023 1035 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 04/27/2023 1035 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 04/27/2023 1035 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Styrene 0.50 U 1 0.50 0.41 ug/L 04/27/2023 1035 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Toluene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Trichloroethene 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73820-001 Matrix: Aqueous Batch:73820 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 04/27/2023 1035 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 04/27/2023 1035 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 04/27/2023 1035 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD21009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 43 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73820-002 Matrix: Aqueous Batch: 73820 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 190 N 1 195 60-140 04/27/2023 0856 Acrylonitrile 100 140 N 1 143 70-130 04/27/2023 0856 Benzene 50 59 1 117 70-130 04/27/2023 0856 Bromochloromethane 50 53 1 107 70-130 04/27/2023 0856 Bromodichloromethane 50 60 1 120 70-130 04/27/2023 0856 Bromoform 50 50 1 100 70-130 04/27/2023 0856 Bromomethane (Methyl bromide) 50 46 1 92 70-130 04/27/2023 0856 2-Butanone (MEK) 100 160 N 1 162 70-130 04/27/2023 0856 Carbon disulfide 50 62 1 124 70-130 04/27/2023 0856 Carbon tetrachloride 50 64 1 129 70-130 04/27/2023 0856 Chlorobenzene 50 57 1 114 70-130 04/27/2023 0856 Chloroethane 50 49 1 99 70-130 04/27/2023 0856 Chloroform 50 58 1 116 70-130 04/27/2023 0856 Chloromethane (Methyl chloride) 50 49 1 97 60-140 04/27/2023 0856 1,2-Dibromo-3-chloropropane (DBCP) 50 58 1 115 70-130 04/27/2023 0856 Dibromochloromethane 50 61 1 121 70-130 04/27/2023 0856 1,2-Dibromoethane (EDB) 50 59 1 118 70-130 04/27/2023 0856 Dibromomethane (Methylene bromide) 50 55 1 110 70-130 04/27/2023 0856 trans- 1,4-Dichloro-2-butene 50 56 1 112 70-130 04/27/2023 0856 1,2-Dichlorobenzene 50 55 1 ill 70-130 04/27/2023 0856 1,4-Dichlorobenzene 50 54 1 108 70-130 04/27/2023 0856 1,1-Dichloroethane 50 59 1 118 70-130 04/27/2023 0856 1,2-Dichloroethane 50 58 1 115 70-130 04/27/2023 0856 1,1-Dichloroethene 50 59 1 119 70-130 04/27/2023 0856 cis- 1,2-Dichloroethene 50 56 1 112 70-130 04/27/2023 0856 trans- 1,2-Dichloroethene 50 57 1 114 70-130 04/27/2023 0856 1,2-Dichloropropane 50 60 1 121 70-130 04/27/2023 0856 cis- 1,3-Dichloropropene 50 60 1 120 70-130 04/27/2023 0856 trans- 1,3-Dichloropropene 50 61 1 122 70-130 04/27/2023 0856 Ethylbenzene 50 58 1 117 70-130 04/27/2023 0856 2-Hexanone 100 140 N 1 139 70-130 04/27/2023 0856 Methacrylonitrile 250 340 N 1 134 70-130 04/27/2023 0856 Methyl iodide (lodomethane) 50 54 1 109 70-130 04/27/2023 0856 4-Methyl-2-pentanone 100 120 1 123 70-130 04/27/2023 0856 Methylene chloride 50 60 1 120 70-130 04/27/2023 0856 Styrene 50 61 1 121 70-130 04/27/2023 0856 1,1,1,2-Tetrachloroethane 50 59 1 118 70-130 04/27/2023 0856 1,1,2,2-Tetrachloroethane 50 60 1 121 70-130 04/27/2023 0856 Tetrachloroethene 50 55 1 111 70-130 04/27/2023 0856 Toluene 50 58 1 116 70-130 04/27/2023 0856 1,1,1-Trichloroethane 50 59 1 118 70-130 04/27/2023 0856 1,1,2-Trichloroethane 50 59 1 117 70-130 04/27/2023 0856 Trichloroethene 50 55 1 110 70-130 04/27/2023 0856 Trichlorofluoromethane 50 49 1 99 70-130 04/27/2023 0856 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73820-002 Matrix: Aqueous Batch:73820 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 60 1 120 70-130 04/27/2023 0856 Vinyl acetate 50 57 1 115 60-140 04/27/2023 0856 Vinyl chloride 50 51 1 101 70-130 04/27/2023 0856 Xylenes (total) 100 120 1 116 70-130 04/27/2023 0856 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD21009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 43 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ74185-001 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 05/02/2023 0051 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 113 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ74185-002 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 44 1 88 70-130 05/01/2023 2253 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 104 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 43 QC Data for Lot Number: YD21009 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: YQ74185-003 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 57 + 1 113 26 70-130 20 05/02/2023 0004 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 117 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 43 QC Data for Lot Number: YD21009 ICP-MS Metals - MB Sample ID: YQ73746-001 Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 2.0 U 1 2.0 0.50 ug/L 05/02/20231159 Arsenic 2.0 U 1 2.0 1.3 ug/L 05/02/20231159 Barium 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Beryllium 0.40 U 1 0.40 0.15 ug/L 05/02/20231159 Cadmium 0.50 U 1 0.50 0.13 ug/L 05/02/20231159 Chromium 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Cobalt 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Copper 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Lead 1.0 U 1 1.0 0.25 ug/L 05/02/20231159 Nickel 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Selenium 5.0 U 1 5.0 1.3 ug/L 05/02/20231159 Silver 1.0 U 1 1.0 0.25 ug/L 05/02/20231159 Thallium 0.50 U 1 0.50 0.15 ug/L 05/02/20231159 Vanadium 5.0 U 1 5.0 2.5 ug/L 05/02/20231159 Zinc 10 U 1 10 2.5 ug/L 05/02/20231159 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 43 QC Data for Lot Number: YD21009 ICP-MS Metals - LCS Sample ID: YQ73746-002 Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 93 1 93 80-120 05/02/20231210 Arsenic 100 98 1 98 80-120 05/02/20231210 Barium 100 99 1 99 80-120 05/02/20231210 Beryllium 100 99 1 99 80-120 05/02/20231210 Cadmium 100 94 1 94 80-120 05/02/20231210 Chromium 100 100 1 103 80-120 05/02/20231210 Cobalt 100 100 1 105 80-120 05/02/20231210 Copper 100 110 1 107 80-120 05/02/20231210 Lead 100 100 1 101 80-120 05/02/20231210 Nickel 100 110 1 106 80-120 05/02/20231210 Selenium 100 89 1 89 80-120 05/02/20231210 Silver 100 99 1 99 80-120 05/02/20231210 Thallium 100 100 1 100 80-120 05/02/20231210 Vanadium 100 100 1 100 80-120 05/02/20231210 Zinc 100 96 1 96 80-120 05/02/20231210 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 43 QC Data for Lot Number: YD21009 ICP-MS Metals - MS Sample ID: YD21009-002MS Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 0.0 100 94 1 94 75-125 05/02/20231502 Arsenic 0.0 100 100 1 102 75-125 05/02/20231502 Barium 140 100 240 1 96 75-125 05/02/20231502 Beryllium 0.0 100 100 1 104 75-125 05/02/20231502 Cadmium 0.0 100 97 1 97 75-125 05/02/20231502 Chromium 0.0 100 100 1 103 75-125 05/02/20231502 Cobalt 9.9 100 110 1 103 75-125 05/02/20231502 Copper 0.0 100 100 1 104 75-125 05/02/20231502 Lead 0.0 100 95 1 95 75-125 05/02/20231502 Nickel 7.0 100 110 1 101 75-125 05/02/20231502 Selenium 0.0 100 96 1 96 75-125 05/02/20231502 Silver 0.0 100 97 1 97 75-125 05/02/20231502 Thallium 0.0 100 93 1 93 75-125 05/02/20231502 Vanadium 0.0 100 100 1 101 75-125 05/02/20231502 Zinc 16 100 110 1 96 75-125 05/02/20231502 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 43 QC Data for Lot Number: YD21009 ICP-MS Metals - MSD Sample ID: YD21009-002MD Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony 0.0 100 94 1 94 0.49 75-125 20 05/02/20231514 Arsenic 0.0 100 100 1 101 1.4 75-125 20 05/02/20231514 Barium 140 100 240 1 95 0.50 75-125 20 05/02/20231514 Beryllium 0.0 100 100 1 102 1.7 75-125 20 05/02/20231514 Cadmium 0.0 100 95 1 95 1.6 75-125 20 05/02/20231514 Chromium 0.0 100 100 1 101 2.2 75-125 20 05/02/20231514 Cobalt 9.9 100 110 1 102 1.2 75-125 20 05/02/20231514 Copper 0.0 100 100 1 102 1.8 75-125 20 05/02/20231514 Lead 0.0 100 95 1 95 0.66 75-125 20 05/02/20231514 Nickel 7.0 100 110 1 99 1.7 75-125 20 05/02/20231514 Selenium 0.0 100 95 1 95 1.4 75-125 20 05/02/20231514 Silver 0.0 100 96 1 96 1.3 75-125 20 05/02/20231514 Thallium 0.0 100 93 1 93 0.65 75-125 20 05/02/20231514 Vanadium 0.0 100 99 1 99 2.6 75-125 20 05/02/20231514 Zinc 16 100 110 1 94 1.7 75-125 20 05/02/20231514 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 43 QC Data for Lot Number: YD21009 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 43 PACE ANALYTICAL SERVICES, LLC C.l F _ z u MI � L] _ w T ~ r, c z LLJ p= r 3 d CD a U 1� 4wi dI W w f k L4 7 O} 4 L G} 5 Ln l�l � L � L Z ) �I Arm crs I I-' E 4 I r � w � U Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 43 PACE ANALYTICAL SERVICES, LLC DC#TWO: ErfV-=-'1 WOdCOL-0296 v07_Sam pies R"�ceipt G ieei kl (5RQ Effactive aa1E: $/Z/2022 Sample Receipt Cb.tcUst ( RC) Client: MIA `idw.Lh a :ncler ln; 41 ed byiclLit:: XT)ZV° : ti LM.'aff33 I n, fi; Yliy2li;U9 mx9'AT9CeJpt, Pace C1ltiil UH FedEx Oghpr f Yes �To 1. �4'ela C ast+xly staL[5 lneseet 4u ll,e [L o1c1 d Y:s f10 NA 2, if ous9ud y seals ;ire Premmt,'a+trc t iW.1CI and LubrffJaen? pRStrip 117: #i9- Clilarn]le Strap A): t A 'tested ,y; >w GSrirtuyl terll eraravr tlpn_a (Co-mded) knrye mm UpOUEecript %did Snap-Ctrlr ID: NA 2.7 3.7 nix irxA a NA +Vrl NArrA cC Methacl: 01'Cn>ixIvi�ture Blank [t.0 p si Eutllt!v II tR Gan 1: ! 8 IR I411 C orrGUEOU iethnd Of ewAxit:. 91 'N'a l+ c ke packs I ! Ory Ice n Tfrnlc 3. Wi;:4:zU covt12-_3 [OGI ij -ed [9i Ortelow 6.OeC7 If uo. was 7'rojec[ Y'HM! rr Iw[it=ed? Pli4•,ras Notif:edty- pLouelcinsilIface-to-kcc (cirote I if yesl UNC4A 4. Is ffic cnmrr-rar-iai L:uurarT`s pf c%pg slip'4llac$erl tq tlus foau? Yes Nrr S. Wana rA+51]er cusloriy frnceriures {rclin tusCiedlreccived} SaElowcti9 YcA No 6 'A — S=Vla Ms U slcdoLs Cie! COO and all S7n4)le cLnr[aitccrs? Yes No 7. Map coUeLLion dl tc Sc lhLt ks tt3 nit file COO MIA smo 1pte can#ain:r-E? Yea 1ti o $. Did all eutr[aitrer label iufvnnstinn (IT1, dotr, title) p�tnee Xtilq, the COC;^: �! FeR NTj I 9, Wffa lasts tit he lm om eel iist:,d as file C'OC7 �, Ys5 ON(3 10- Did all sa npks the props coLttAwrs for naclt aasr awkicir iu gcud cmulitiwi 0 -shrot eo, lick ar, e,c.)7 Yes I1. :Vau, JWC U111pk' VUluvlc.l-vaiIMite? — Yes No 1?. Weru e11 setnple3 I%ect!E ,ed taititir, s, d3r Wit g tiulte or 4B bogus, wbidwer -mic& first? o U- b OM -'Ill SRUIPics contairers accoi ied fa:? CNlo mis6inJrscc5s) Ql-e4 []r u © .q I �-. V: ,J* VOA- Wl{C andRSy-- 175 samAes- flee dEmbb.es >'))ea_aixa" (W'Cr Gwwt ill dillMeleL) in a Uy of t LR� VCLi. vwls'] F[Elyea N, 15. Were all ]�RO1uur m13l nutrient t=Pks rec6-nd 0 i5 �11 of 4 2? In , N 16. )ffrrr rd) cyauide 67t]Ipit_6 received at a pF = 12 owl st4J.fut� € inples re,5eir�1 al a µPi f'r? QT]u �SriA .7. l t— r applicable :They. ni p,.;,4w11525.fi646? C< .5nw,r1,.};;atiotn free of i+esej,at -Z111ori[w? No t'A 1 S, -V ras Tltit OWE! Likls er E-Atl' an tac ixmitaiaer label? Tf }�. w)[e +r 5:Ilagle 1kr@SPM':Kfiort (MU'A br M11PIC#eel faraYV Eample(s) iocoi.rclly yrQSet't-ed 4r with hcatlspace.' al 1ple(s) uA were iweik-%�d Eitenircctlyrpfeyoui led ILLS IVCtC sd.Ll—Ve 1 e,4ticuEli IILAY Ln Sr10111)k wjIh "7 urL afcircle oi:e' IL9 s, 'Q,i. I{tvl. NaUH 1351o8 SR I? — itueof presci1-tioL _ It`n�ate tl=au CHie pT45erLlli.� is lucded. PleaSeLLMM ill the conijn@ills be"- Sanspiefaj a �nael a reoe;ti cxi wiTl1 bulabtes -�6 jum in diez cicr- r,FP1CSlsj "' Were receh-er.1 Mi1l.'TJt4C' ::- 0.5 vrg;L (If U19 xe no -I find we4'e A'25t'wI aticatxii1,Wy in sample recei;iugmillh sorliuLn lhimitlfste (N ,S;031 wit11 Ut1ig4Yr:1D. NA, C4:nutrL1t%: L,'ual�t] Ya oP' Arn]yti[ai }ervi ce>, LLC 133ge 1 of I Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 43 aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Cabarrus County LF-Unit 1 Lot Number:YD22002 Date Completed:05/15/2023 05/16/2023 10:41 PM Approved and released by: Project Manager II: Cathy S. Dover =w�4 aecRFo���A4W- TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 28 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: YD22002 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. VOA 8260D The laboratory control sample (LCS) for analytical batch 73820 exceeded acceptance criteria for the following analytes: Acetone, 2-Butanone, Acrylonitrile, 2-Hexanone and Methacrylonitrile. These analytes were biased high and were not detected in the associated samples: YD22002-001, YD22002-002, and YD22002-003. YD22002-001 (MW-5) (Run 1) (Analysis Batch 73820) YD22002-002 (MW-7) (Run 1) (Analysis Batch 73820) YD22002-003 (Trip Blank) (Run 1) (Analysis Batch 73820) The following sample was received with an air bubble in the sample vial: YD22002-003. YD22002-003 (Trip Blank) (Run 1) (Analysis Batch 73820) The method blank associated with batch 73820 had Bromoform detected at a concentration that was above the LOQ. All samples associated with this method blank were non -detect for Bromoform. 1,4-Dioxane SIM 8260D Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 74185. An LCS/LCSD was run in lieu of an MS/MSD. YD22002-001 (MW-5) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate YD22002-002 (MW-7) (Run 1) (Analysis Batch 74185) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 28 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: YD22002 Project Name: Cabarrus County LF-Unit 1 Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-5 Aqueous 04/21/2023 0920 04/22/2023 002 MW-7 Aqueous 04/21/2023 0930 04/22/2023 003 Trip Blank Aqueous 04/21/2023 04/22/2023 (3 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-001 Description: MW-5 Matrix: Aqueous Date Sampled:04/21/2023 0920 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1746 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 8.1 JL 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND L 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.48 J 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 10 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 5.4 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND L 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-001 Description: MW-5 Matrix: Aqueous Date Sampled:04/21/2023 0920 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1746 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 113 70-130 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 28 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD22002-001 Description: MW-5 Matrix: Aqueous Date Sampled:04/21/2023 0920 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0517 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 77 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 28 ICP-MS Metals Client:CDM Smith Laboratory ID:YD22002-001 Description: MW-5 Matrix: Aqueous Date Sampled:04/21/2023 0920 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/12/2023 1623 BNW Prep Date Batch 05/11/2023 2011 74284 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.18 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 13 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 37 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-002 Description: MW-7 Matrix: Aqueous Date Sampled:04/21/2023 0930 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1812 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND L 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 1.2 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 18 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.59 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 7.2 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND L 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-002 Description: MW-7 Matrix: Aqueous Date Sampled:04/21/2023 0930 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1812 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 113 70-130 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 28 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:YD22002-002 Description: MW-7 Matrix: Aqueous Date Sampled:04/21/2023 0930 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2023 0542 CDA 74185 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 72 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 113 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 28 ICP-MS Metals Client:CDM Smith Laboratory ID:YD22002-002 Description: MW-7 Matrix: Aqueous Date Sampled:04/21/2023 0930 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/02/2023 1657 BNW 6020B 5 05/10/2023 1837 BNW Prep Date Batch 05/02/2023 0400 73746 05/02/2023 0400 73746 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 5.4 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 430 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 30 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 22 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 26 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-003 Description: Trip Blank Matrix: Aqueous Date Sampled:04/21/2023 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1310 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND L 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D ND 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D ND L 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D ND 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 0.40 ug/L 1 Toluene 108-88-3 8260D ND 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 28 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:YD22002-003 Description: Trip Blank Matrix: Aqueous Date Sampled:04/21/2023 Project Name: Cabarrus County LF-Unit 1 Date Received:04/22/2023 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 04/27/2023 1310 AMR2 73820 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 91 70-130 114 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 28 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD22002 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 28 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73820-001 Matrix: Aqueous Batch: 73820 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 10 4.0 ug/L 04/27/2023 1035 Acrylonitrile ND 1 5.0 0.80 ug/L 04/27/2023 1035 Benzene ND 1 0.50 0.40 ug/L 04/27/2023 1035 Bromochloromethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Bromodichloromethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Bromoform 1.1 1 0.50 0.40 ug/L 04127/20231035 Bromomethane (Methyl bromide) ND 1 0.50 0.40 ug/L 04/27/2023 1035 2-Butanone (MEK) ND 1 10 2.0 ug/L 04/27/2023 1035 Carbon disulfide ND 1 0.50 0.40 ug/L 04/27/2023 1035 Carbon tetrachloride ND 1 0.50 0.40 ug/L 04/27/2023 1035 Chlorobenzene ND 1 0.50 0.40 ug/L 04/27/2023 1035 Chloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Chloroform ND 1 0.50 0.40 ug/L 04/27/2023 1035 Chloromethane (Methyl chloride) ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dibromo-3-chloropropane (DBCP) ND 1 0.50 0.40 ug/L 04/27/2023 1035 Dibromochloromethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dibromoethane (EDB) ND 1 0.50 0.40 ug/L 04/27/2023 1035 Dibromomethane (Methylene bromide) ND 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.40 ug/L 04/27/2023 1035 1,2-Dichlorobenzene ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,4-Dichlorobenzene ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,1-Dichloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dichloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,1-Dichloroethene ND 1 0.50 0.40 ug/L 04/27/2023 1035 cis- 1,2-Dichloroethene ND 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,2-Dichloroethene ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,2-Dichloropropane ND 1 0.50 0.40 ug/L 04/27/2023 1035 cis- 1,3-Dichloropropene ND 1 0.50 0.40 ug/L 04/27/2023 1035 trans- 1,3-Dichloropropene ND 1 0.50 0.40 ug/L 04/27/2023 1035 Ethylbenzene ND 1 0.50 0.40 ug/L 04/27/2023 1035 2-Hexanone ND 1 10 2.0 ug/L 04/27/2023 1035 Methacrylonitrile ND 1 5.0 2.0 ug/L 04/27/2023 1035 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 04/27/2023 1035 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 04/27/2023 1035 Methylene chloride ND 1 0.50 0.40 ug/L 04/27/2023 1035 Styrene ND 1 0.50 0.41 ug/L 04/27/2023 1035 1,1,1,2-Tetrachloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,2,2-Tetrachloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Tetrachloroethene ND 1 0.50 0.40 ug/L 04/27/2023 1035 Toluene ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,1-Trichloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 1,1,2-Trichloroethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Trichloroethene ND 1 0.50 0.40 ug/L 04/27/2023 1035 Trichlorofluoromethane ND 1 0.50 0.40 ug/L 04/27/2023 1035 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 28 QC Data for Lot Number: YD22002 Volatile Organic Compounds by GC/MS - MB Sample ID: YQ73820-001 Matrix: Aqueous Batch:73820 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 1,2,3-Trichloropropane ND 1 0.50 0.40 ug/L 04/27/2023 1035 Vinyl acetate ND 1 5.0 1.2 ug/L 04/27/2023 1035 Vinyl chloride ND 1 0.50 0.40 ug/L 04/27/2023 1035 Xylenes (total) ND 1 1.0 0.40 ug/L 04/27/2023 1035 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD22002 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 28 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73820-002 Matrix: Aqueous Batch: 73820 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 190 N 1 195 60-140 04/27/2023 0856 Acrylonitrile 100 140 N 1 143 70-130 04/27/2023 0856 Benzene 50 59 1 117 70-130 04/27/2023 0856 Bromochloromethane 50 53 1 107 70-130 04/27/2023 0856 Bromodichloromethane 50 60 1 120 70-130 04/27/2023 0856 Bromoform 50 50 1 100 70-130 04/27/2023 0856 Bromomethane (Methyl bromide) 50 46 1 92 70-130 04/27/2023 0856 2-Butanone (MEK) 100 160 N 1 162 70-130 04/27/2023 0856 Carbon disulfide 50 62 1 124 70-130 04/27/2023 0856 Carbon tetrachloride 50 64 1 129 70-130 04/27/2023 0856 Chlorobenzene 50 57 1 114 70-130 04/27/2023 0856 Chloroethane 50 49 1 99 70-130 04/27/2023 0856 Chloroform 50 58 1 116 70-130 04/27/2023 0856 Chloromethane (Methyl chloride) 50 49 1 97 60-140 04/27/2023 0856 1,2-Dibromo-3-chloropropane (DBCP) 50 58 1 115 70-130 04/27/2023 0856 Dibromochloromethane 50 61 1 121 70-130 04/27/2023 0856 1,2-Dibromoethane (EDB) 50 59 1 118 70-130 04/27/2023 0856 Dibromomethane (Methylene bromide) 50 55 1 110 70-130 04/27/2023 0856 trans- 1,4-Dichloro-2-butene 50 56 1 112 70-130 04/27/2023 0856 1,2-Dichlorobenzene 50 55 1 ill 70-130 04/27/2023 0856 1,4-Dichlorobenzene 50 54 1 108 70-130 04/27/2023 0856 1,1-Dichloroethane 50 59 1 118 70-130 04/27/2023 0856 1,2-Dichloroethane 50 58 1 115 70-130 04/27/2023 0856 1,1-Dichloroethene 50 59 1 119 70-130 04/27/2023 0856 cis- 1,2-Dichloroethene 50 56 1 112 70-130 04/27/2023 0856 trans- 1,2-Dichloroethene 50 57 1 114 70-130 04/27/2023 0856 1,2-Dichloropropane 50 60 1 121 70-130 04/27/2023 0856 cis- 1,3-Dichloropropene 50 60 1 120 70-130 04/27/2023 0856 trans- 1,3-Dichloropropene 50 61 1 122 70-130 04/27/2023 0856 Ethylbenzene 50 58 1 117 70-130 04/27/2023 0856 2-Hexanone 100 140 N 1 139 70-130 04/27/2023 0856 Methacrylonitrile 250 340 N 1 134 70-130 04/27/2023 0856 Methyl iodide (lodomethane) 50 54 1 109 70-130 04/27/2023 0856 4-Methyl-2-pentanone 100 120 1 123 70-130 04/27/2023 0856 Methylene chloride 50 60 1 120 70-130 04/27/2023 0856 Styrene 50 61 1 121 70-130 04/27/2023 0856 1,1,1,2-Tetrachloroethane 50 59 1 118 70-130 04/27/2023 0856 1,1,2,2-Tetrachloroethane 50 60 1 121 70-130 04/27/2023 0856 Tetrachloroethene 50 55 1 111 70-130 04/27/2023 0856 Toluene 50 58 1 116 70-130 04/27/2023 0856 1,1,1-Trichloroethane 50 59 1 118 70-130 04/27/2023 0856 1,1,2-Trichloroethane 50 59 1 117 70-130 04/27/2023 0856 Trichloroethene 50 55 1 110 70-130 04/27/2023 0856 Trichlorofluoromethane 50 49 1 99 70-130 04/27/2023 0856 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 28 QC Data for Lot Number: YD22002 Volatile Organic Compounds by GC/MS - LCS Sample ID: YQ73820-002 Matrix: Aqueous Batch:73820 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,2,3-Trichloropropane 50 60 1 120 70-130 04/27/2023 0856 Vinyl acetate 50 57 1 115 60-140 04/27/2023 0856 Vinyl chloride 50 51 1 101 70-130 04/27/2023 0856 Xylenes (total) 100 120 1 116 70-130 04/27/2023 0856 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD22002 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 28 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: YQ74185-001 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/02/2023 0051 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 113 40-170 ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 28 QC Data for Lot Number: YD22002 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: YQ74185-002 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 44 1 88 70-130 05/01/2023 2253 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 104 40-170 ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 28 QC Data for Lot Number: YD22002 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: YQ74185-003 Matrix: Aqueous Batch: 74185 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 57 + 1 113 26 70-130 20 05/02/2023 0004 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 117 40-170 ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 28 QC Data for Lot Number: YD22002 ICP-MS Metals - MB Sample ID: YQ73746-001 Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/02/20231159 Arsenic ND 1 2.0 1.3 ug/L 05/02/20231159 Barium ND 1 5.0 1.3 ug/L 05/02/20231159 Beryllium ND 1 0.40 0.15 ug/L 05/02/20231159 Cadmium ND 1 0.50 0.13 ug/L 05/02/20231159 Chromium ND 1 5.0 1.3 ug/L 05/02/20231159 Cobalt ND 1 5.0 1.3 ug/L 05/02/20231159 Copper ND 1 5.0 1.3 ug/L 05/02/20231159 Lead ND 1 1.0 0.25 ug/L 05/02/20231159 Nickel ND 1 5.0 1.3 ug/L 05/02/20231159 Selenium ND 1 5.0 1.3 ug/L 05/02/20231159 Silver ND 1 1.0 0.25 ug/L 05/02/20231159 Thallium ND 1 0.50 0.15 ug/L 05/02/20231159 Vanadium ND 1 5.0 2.5 ug/L 05/02/20231159 Zinc ND 1 10 2.5 ug/L 05/02/20231159 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 28 QC Data for Lot Number: YD22002 ICP-MS Metals - LCS Sample ID: YQ73746-002 Matrix: Aqueous Batch: 73746 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/02/2023 0400 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 93 1 93 80-120 05/02/20231210 Arsenic 100 98 1 98 80-120 05/02/20231210 Barium 100 99 1 99 80-120 05/02/20231210 Beryllium 100 99 1 99 80-120 05/02/20231210 Cadmium 100 94 1 94 80-120 05/02/20231210 Chromium 100 100 1 103 80-120 05/02/20231210 Cobalt 100 100 1 105 80-120 05/02/20231210 Copper 100 110 1 107 80-120 05/02/20231210 Lead 100 100 1 101 80-120 05/02/20231210 Nickel 100 110 1 106 80-120 05/02/20231210 Selenium 100 89 1 89 80-120 05/02/20231210 Silver 100 99 1 99 80-120 05/02/20231210 Thallium 100 100 1 100 80-120 05/02/20231210 Vanadium 100 100 1 100 80-120 05/02/20231210 Zinc 100 96 1 96 80-120 05/02/20231210 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 28 QC Data for Lot Number: YD22002 ICP-MS Metals - MB Sample ID: YQ74284-001 Matrix: Aqueous Batch: 74284 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/11/2023 2011 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/12/20231610 Arsenic ND 1 2.0 1.3 ug/L 05/12/20231610 Barium ND 1 5.0 1.3 ug/L 05/12/20231610 Beryllium ND 1 0.40 0.15 ug/L 05/12/20231610 Cadmium ND 1 0.50 0.13 ug/L 05/12/20231610 Chromium ND 1 5.0 1.3 ug/L 05/12/20231610 Cobalt ND 1 5.0 1.3 ug/L 05/12/20231610 Copper ND 1 5.0 1.3 ug/L 05/12/20231610 Lead ND 1 1.0 0.25 ug/L 05/12/20231610 Nickel ND 1 5.0 1.3 ug/L 05/12/20231610 Selenium ND 1 5.0 1.3 ug/L 05/12/20231610 Silver ND 1 1.0 0.25 ug/L 05/12/20231610 Thallium ND 1 0.50 0.15 ug/L 05/12/20231610 Vanadium ND 1 5.0 2.5 ug/L 05/12/20231610 Zinc ND 1 10 2.5 ug/L 05/12/20231610 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 28 QC Data for Lot Number: YD22002 ICP-MS Metals - LCS Sample ID: YQ74284-002 Matrix: Aqueous Batch: 74284 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/11/2023 2011 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 05/12/20231617 Arsenic 100 100 1 104 80-120 05/12/20231617 Barium 100 99 1 99 80-120 05/12/20231617 Beryllium 100 86 1 86 80-120 05/12/20231617 Cadmium 100 100 1 100 80-120 05/12/20231617 Chromium 100 100 1 104 80-120 05/12/20231617 Cobalt 100 110 1 106 80-120 05/12/20231617 Copper 100 110 1 106 80-120 05/12/20231617 Lead 100 100 1 100 80-120 05/12/20231617 Nickel 100 100 1 104 80-120 05/12/20231617 Selenium 100 100 1 100 80-120 05/12/20231617 Silver 100 100 1 101 80-120 05/12/20231617 Thallium 100 100 1 101 80-120 05/12/20231617 Vanadium 100 100 1 102 80-120 05/12/20231617 Zinc 100 110 1 105 80-120 05/12/20231617 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 28 QC Data for Lot Number: YD22002 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 28 PACE ANALYTICAL SERVICES, LLC JL rk� h—J 4 iL Sf104 far � Ff 7g lk sa v65x t `JI r`t [-I C L IFS Y Y 15 a 5A f5� T 4 �p y 2. -41 r_ IE Ii,�- I� k 1 4.y1 a �� Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 28 PACE ANALYTICAL SERVICES, LLC DC#_Tk1u_- ENV-FKM-VOCOL-0296 w02_Sarnples Rocoilpt Chjqckilst {SFc{1 Effective Data: 2/2/24211 Sample Receipt CheckJbt (SRC) Iiznit' Cd�d Suuai� COQlu Iuspccticj IryVdatc_ r Cll, : 2023 L'to_ YD2--0112 Vlcans a r roewIItT k t! iC I If_"n I Ur"s yj r aar }i OtIK : Yes Nol I l_ %V"!rc C119tcittyRMIS resrlil ontix coolnr? ,I Yrs o ETA 12. 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O;d all conmiuer lalbel iilfor:lraiioia [f•ij, da: ,tithe) agatime vt71h the COC? o 19- wetm tests 40 be Dafq=d list d alp the C4fJ ? ycsI 110. Did all Smiplcs arrive ill the jrVet cantaiuers for each test w1ivor ill goud CMAd iolt II *bro;DDm Lids ou. e=.)4 M4 L JN0 11_ Alas axle ualle sait:ple :'oldie available? ,a 12_ rere rill Mxilalcs receive WiIlelt «slx holding rimy or 4B doors. whichcvrr CAomrs f45V ,❑v+ 3 E]'To 13. Were aft sa;ilpls canlaillub aocmuittd 160 tNo asussy��e�cess] Yes NO NA 14. Vd� VOA. S015C: abet R XS-175 samples tite of bubbles >"pe�l-5iZe" (%'10r 6]uul iu Q &wit -W yr my of Tl= VOA vials^ Yc. T OA 15. Weile all ORMIlemis mluiclil saa'_1111es received Sk ale PEI of ;r Yes E:1RSo1 16. V4txrc all crruur[e samples received nt a H> 12 a¢.d �itlfick 521np[a5 received al :1 pH -.- 9? 17. Wur all RPVhC,1ble ,!H c}.1m 1 o1{G3i_1J6CI _3 (< 0.5ing/L) samples free or Yes 0 No 71NAI residual ciitarhie? 18. Vans lhr quote hunter listed on dirt corn iiier rebel? if �vA, {dote 4 d Yn Elmo UNA �rASc► >stwpk' Pres enTarlolt ( usl Na completed for ozy saDcplers) iucorrlxlly pLT:scrw-d or %aidi lteadspace-) i3L]ple(5) MA were recehed iticor outlypuvewnwd mid weliv adj u4U1 8CCUTdiD. n &cA14le rccciving 4-1f11 '� 31If, of cu'cle one, H2SO4„ HNO3, HCL M10H Lung SR N '�A lime Of preStivxlian NA _ lfmarc thauene pre-mvativc is ncevdtd_ pease tote iii the cowmen(s belwx_ Were r+ecei{red vAiLb brlblM : 6 MM in clirultclr,'_ Prud vrd %%A TRC > 0-5 11tglJr. {1f#i9 is )ro) goad were justad a cord try �a sanpx[c recta', iag wiitl se(hum rlliostm' Ic(Na-S'03) with Utl=gue U. NA Colrnfn+�; Qualtr�xCD. li3fifi Pace$Analyiicai.5eMces, LLC rage 1 of S Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 28