Loading...
HomeMy WebLinkAboutNCD980602163_19951018_Warren County PCB Landfill_SERB C_Water Monitoring, 1978 - 1995-OCRState of North Carolina Department of Environment, Health and Natural Resources Division of Solid Waste Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary William L. Meyer, Director October 18, 1995 Mr. Gary R. Chirlin, PhD., P.G. Chirlin & Associates, Inc. 16623 Bethayres Road Rockville, MD 20855 Dear Mr. Chirlin: NA DEHNR. The Joint Warren County State PCB Landfill Working Group (YI orking Group) has requested that I submit information to you concerning the existing landfill groundwater monitoring systems. There is consensus among members of the Working Group that the existing monitoring system should be evaluated and upgraded if appropriate. The staff of the Division of Solid Waste Management (Division) has proposed recommendations for upgrading the existing monitoring system. In order to move forward on a final proposal for upgrading the monitoring system, the Working Group has requested a peer review, external to the State, of the State's recommendations. Chirlin and Associates was recommended as a peer reviewer that has the confidence of the members of the Working Group. I am enclosing two documents, which the Division staff sent to another independent professional geologist, for your consideration for peer review and recommendations. If you need additional information or have any technical questions, please contact Bob Glaser, staff hydrogeologist, at (919) 733-2178, ext. 300. The Working Group has previously received peer review gratuitously. If Chirlin and Associates anticipates compensation for the requested peer review, please let me know. In addition, I would like to know a schedule for responding to this request. P.O. Box 27687, Raleigh, North Carolina 27611-7687 Telephone 919-733-4996 FAX 919-715-3605 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post-consumer paper Gary Chirlin October 18, 1995 Page 2 Please call me at (919) 733-4996, ext. 202 if you need any further explanation or assistance in this process. I look forward to a response and working with you on this issue. Sincerely, \ I t0~c1~~ William L. Meyer WLM/cb cc: Bob Glaser -w/o enclosures H,nry Lancaster -w/o enclosures .Jfm Warren -w/o enclosures Enclosures North Carolina Department of Environment, Health, and Natural Resources @ PrintedonRe~ledPaper State of North Carolina Department of Environment, Health and Natural Resources Division of Solid Waste Management James B. Hunt, Jr., Governor Jonbthan B. Howes, Secretary William L. Meyer, Director Mr. George Bain 3966 Bachelor Creek Road Asheboro, North Carolina 27203 October 9, 1995 RE: Ground Water Monitoring System for the PCB Landfill Dear Mr. Bain: .NA DEHNR I am in receipt of the September 25, 1995 letter regarding the additional material needed to complete your evaluation. The material attached to this letter should address most of your requests. Some of the items you requested were not available. The material I have included is: 1. boring logs for the original test borings for the site characterization; 2. a copy of the construction plans for the PCB landfill; 3. elevation of the bottom of each well; 4. aerial photograph of the site (please return it when you are finished); 5. elevation of the water in the landfill; 6. well records for each of the wells; and 7. copies of memos, reports, and other applicable correspondence pertaining to the PCB Landfill. In addition to the material specified above, I have included a table with water level data for well MW-4. The data sent to you previously included an incorrect measuring point elevation and incorrect water table elevations. If there are any questions please call me at (919) 733-2178 extension 300. Respectfully, f 7 /) 171·; }J /) .---._Qf_,.~,Ylf J~1.,,:.__,l "\./ Robert Glaser, Hydrogeologist Remediation Branch Hazardous Waste Section P.O. Box 27687, Raleigh, North Carolina 27611-7687 Telephone 919-733-4996 FAX 919-715-3605 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post-c onsumer paper PCB Landfill Measurements The following water level and well depth measurements were taken on October 5, 1995 by Larry Rose, hydrologic technician with the State's Solid Waste Section, and Bob Glaser. Well# MW-1 MW-2 MW-3 MW-4 Landfill Well Measuring Point Elevation 343.99 329.98 325.12 322.82 357.67 (ft) Well Depth below Measuring 51.88 46.86 40.80 38.48 Point (ft) Static Water Level below Measuring 45.23 38.25 26.38 23.48 20.43* Point (ft) Water Table 298.76 291.73 298.74 299.34 Elevation (ft) Water Level Elevation in 337.24 Landfill *measurement made on July 21, 1995 The elevation of the bottom of the leachate collection system is approximately 321 feet above mean sea level. H:\BOB-G\G-BAIN2.WPD 0~-------.,;_1200FEET • Sw(e,ca WM« M--.1 Swiae ....... In-Mile ... dun -c---•·ll':·• @ I ,__ T -r-c-•a-.---•_,... r,t ,..__.. ._ • "'-'it i< ,.,... • ,..,.,,, - State of North Carolina Department of Environment, Health and Natural Resources Division of Solid Waste Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary William L. Meyer, Director l\ffiMORANDUM TO: FROM: Bill Meyer, Director, Division of Solid Waste Management ~ Ed Mussler,E.I.T., Solid Waste Section, Division of Solid Waste Manageme ~ Greg Eades,E.I. T., Solid Waste Section, Division of Solid Waste Management 7 l RE: Volume of Soil Estimated in the PCB Landfill The approximate volume of soil in the PCB landfill has been calculated. There is approximately 36,500 cubic yards of material in the landfill. Assuming an average weight of 1.5 tons per cubic yard, there are approximately 54,750 tons of material in the landfill. The volume and weight of the wet and dry soil that may be available was determined. The amount of wet and dry soils in the landfill are conservatively estimated as: Volume of Dry Soil-21,500 cubic yards Volume of Wet Soil-15,000 cubic yards METHODOLOGY The average-end-area method of calculating the volume was employed. This method tends to over estimate the actual volume, so it should represent a maximum amount of soil in the landfill. The supplied drawings were consulted. It was assumed that the final contours were as depicted and that the grading plan was the subgrade. Five feet were subtracted from the top elevations to account for the closure cap system, and 7 feet were added to the grading plan elevations to account for the leak detection layer, clay barrier layer and leachate collection· system. Seven cross sections were chosen and the geometry plotted. Given the simple nature of this design we were able to determine the area of right triangles. These areas were summed and multiplied by two to account for the entire cross section of the landfill. The volume of soil was estimated using the following formula: V = L (Al+ A2)/ 2 (27ft3 per yd3) The weight of the soil was conservatively estimated by assuming that the soil has a unit weight of 1.5 tons per cubic yard. The cross sections and calculations are attached. Water level measurements in the landfill are available from two measurement points, the leachate sump pipe and the gas vent well. The water level readings from the two points were obtained and translated into an elevation. The two measurements are within six inches of each P.O. Box 27687. Raleigh, North Carolina 27611-7687 Telephone 919-733-4996 FAX 919-715-3605 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post-consumer paper other. The top nineteen feet (at the maximum point of the landfill) is dry, and the maximum depth of saturated soil is ten feet. The approximate volume and weight of soil which may be recovered from four cased wells, each two feet in diameter was also determined. The wells were assumed to be evenly spaced across the flat bottom portion of the landfill (i.e. no wells were located over sideslope portions). Each well could yield: Volume of soil in two foot diameter well,-91.11 cubic feet Dry Weight of soil per well-89.48 pounds per cubic foot Total Dry Weight of Soil from four wells -4 tons per well The soil was assumed to have a dry denisty of 111 pounds per cubic foot. The weight of saturated soil was adjusted to its dry weight equivalent. The adjusted density per well is 89 .48 pounds per cubic foot. LIMITATIONS The information and numbers generated herein are based upon commonly accepted engineering methods. All of the drawings and measurements have been supplied by others and the resulting information is as correct as the data supplied to us. The actual conditions and amount of saturated and unsaturated soil within the landfill may vary, dependent upon the variance of the actual conditions in the landfill. A reasonable dry weight and density of the soil was assumed for computational purposes; the actual soil is highly variable. If there are any questions, please do not hesitate to call on us. Environmental Engineer Solid Waste Section C:\WPDOCS\COMMENTS\PCBVOLl .DOC J,, • . -l ; I . NORTH CAROLINA DMSION OF SOLID WASTE MANAGEMENT SOLID WASTE SECTION CALCULATION SHEET i I i I i ! \ i I i I ! I I I I i I I I I ; i ! i s1: I ~loP4 . I i I I ! l I i i I ' i ; I ' ' I ! ! ! ! l I i i ! , , • I ! ! : ' I ! A-i_= Y,: f i+'/n.b'J!( I ' I i ! ; i i I i ' ' ' i -i i ~ ,.,' i ! i i I I i ! I ' i i 32.s' ' ' ' ; I I i ; ! ' I ' ' ' ; , I J4S-'. LF {vMe --r (_,... Date: tu/{,b ~ Date: 1c/;/;. /fr r, . NORTH CAROLINA DMSION OF SOLID WASTE MANAGE:MENT SOLID WASTE SECTION CALCULATION SHEET i i i i I I ~ i l 1 ; ' I 1· I 1' I i 1 1 I , 1 ... , i I I i ! l I ; i i i I I l j . I l i ! 54-' i I i 1 ! i ~ ! i j , ___ · __ 5± I ; i I I I ! i I ! i i .I I I I ! '2i i' 1 I ! ! I ! • v;:: '3S' l i. 1 2.p +: 13-_z._,.o ...... ) _-= -----'-'2,,_,, g."-': =r<-.;r'---+t-#7...c...i -----'--'--'----'--...;___-'--i---'!-----'---'-~--'---'--+--'--;-!i __;___;____;__'---I S4-. . : ! ! I ~------.-___,..-------~----_._~ ..... T~; ···-1 -------;-------...--1 -'---'---'----1 ' I i ! I I i : : . --~--~:~o~k~U. ~±V~LtJp-±-4_±~~ ~ J 1 l 4:b ~ c}ff~\-=-.:56__,• I--'----+---+-----'----'--- ! t ,5a.! 3,)()o~ le.~ ! -f"()f~( 'So~"{ ; v?' . : : I i --.----~ I ' i : : : I ! . ' i ! ' Project Title: --Pc-a LF Volv,sfe 1Zi774 l- By: iii Date: /111&/45" Checked By: $~ Date: /b/~/n- Sheet -2:_ of_±::_ ' : : ' i : I ' l j l I i ' · NORTH CAROLINA DMSION OF SOLID WASTE MANAGE1\1ENT SOLID WASTE SECTION CALCULATION SHEET I ; i • i I I ' ! l I 1 i I I I i I ! I -i I i ' j 1 , ! I I : . i l ! . i i i ! I ! : : . I i • . ! • i '; I i ! ! ! I I I I 1 . _. I I I Ii tJk.f ! ! I ! ' ; I • Ii : 1'-' " i'' _ I .1 ! i I ! i I i l i I i i i i ! i ! ! ! ! I . . • ' i I ! ! ; I ' I : i i : : ' i 1---"-----~--+-1 ___ ,;...-.. i. --..;.... ---"-~----+-------------"---'---1---'--~--l--'-~---'----• . ! i : . --·· i i : I i ! . ' ; I , I i i I : ! I I I I I Project Title: ?ci3 LF · iUE!"vh-1-oc YJ/( - By: ijj;_ Di\te: /v G ,,- Checked By:i<[_ Date: 10 6 1 ---- Sheet _J__ of _J__ . . I : I ' I i • i : i ! . . NORTH CAROLINA DIVISION OF SOLID WASTE MANAGEMENT SOLID WASTE SECTION i i l . l I l . i A~:= CALCULATION SHEET : I 1 1 I I I i ! ,..i I i i I i I i ! ! I I l ! ! ! I ! I i I ! I ! I ! I ! 1 I ! ! i ! i ' I I ! ' I I I l I ! I ! ! ! I I • I i , i I ' ! . . ; • ' ! : ! ' i : i i i ! -~_\{J .,_· 50 (o+•H,6l 54 ; ; ! ' I ~ -=. /{;(J ( yl/lt (2.00) :! 6400c. : S'4 : : 1 : , i i '\ i v' ! _4: ! i i l'3o ( l;to<i+l~~o) ~ 6(;4-4:c ' , 54 1 •: i : I i I i ! I i : I i i ' i \ i ! i I I i I I l I r i i I ! I I I I i ! i : • ! ' : ; : i ' i I I 1 'To~~I : ~ "t"' \/'7:-+ r/.4. + v ... i:: /1-944 c>,~: l/5,z. is-, boo C-t., .-" ' I ' ! ! ; i i :-D. rt-= °14{4:( Vol,.---ti ~ 1.vCf ~clvr. e ~: ! 3~1000 <-¼ ~. 15.bo~ <~:: : 2.,, ~0:0~1,( ,_;.../ : : • , • 1 1 : : · ! ! , I : , · / !U : ' 1 : :/J , . i I U, . • llol/-c_l Vo{:v...;4-!:) _1{. oo<l c.r,-~n~ AA~-i ,s -i 'E'fo/J Dr.., I ,_~ ___ __,__D_ ... __,_1>' : 1/1.Jt ... --e. \-: l 2.( td11 / c..~ / ! ! : I 41 o/o l 1,Ua.+' Wtif l V~/v i.~ { lts-J oho l du"'+ / i i : i I i ...______,_.._.. _____ ____.__,.;_,--4:__;____.l..1,I~·· I i i Project Title: ~kh"\.e.5A T1.Ji2A il::7) 5oc'l · --:Pc. E By: JI~ Checked By: ·f?~ Sheet_/_of_/_ Date: to/6-7,( Date: iO/b /<is- ' l, L-F . I I I i ' I ' ' . i . NORTH CAROLINA DIVISION OF SOLID WASTE MANAGEMENT SOLID WASTE SECTION CALCULATION SHEET ! , i I i 1 i I i : I ~ . ,tJ I i i I I ! I i ! ,; I I ' I : i I I I I ,I I I i1 ' i I '" I l/ I i I ! ! -l-I I r I i I I I , /! / A I I i ,, . . I 20.s i ; l . i ! I i I i I ' I • -h , I -: I TT· +I ' ! 1 ,-i 1 ! I ! ! V i i i I ,. 7" l ' I i I ! ! : : ! i : ~-+------+----4-----'-,-----'----'----'-----'---4--_;__..._l___,, __ ,___;_·___;_:---'-,--+---'-__;----'----'---l ! T I I ! I . I ! ! I l ll : ' i ! ' ' ! 7': /=1 i T i ! i : l ' : ! Project Title: By: /f4 L E ttc. ft14. TF LEVEL-, -?cB L F Checked By: 1pn£ Sheet _i__ of _l__ Date: ''-i'h" Date: 1o/(e/~J,,... FI ! i 1 I : ' ' i : Warren County PCB Landfill Environmental Sampling Data August, 1994 Sample ?. SampJe 409cition· •. ·· · · ·•· Lab ID •• ·Chemical ••·•· . . . .·. . · Name ·•··•. •·•··•· · NGr11bet Parameter ··•.· ,.· :· WL-001-SS Leachate Pond -Ravine 013921 Barium outlet II II 013921 Chromium WL-003-SS Leachate Pond -middle 942752 PCB WL-004-SS Leachate P. -filter outfall 942753 PCB WL-028-SS Leachate P. -filter out -942781 PCB duplicate WL-029-SS Surface Soil Background 942782 PCB WL-001-LC Dry Landfill Contents 942796 PCB II II 942795 Chlorobenzene II II 942795 1 ,4 Di-chloro- benzene WL-002-LC Wet Landfill Contents 942799 PCB II II 942797 Chlorobenzene II II 942797 1 ,4 Di-chloro- benzene II II 013919 Arsenic II II 013919 Barium II II 013919 Chromium II II 013919 Lead WL-001-LE Landfill Leachate 013909 Barium WL-001-GW Monitoring Well No. 1 013914 Barium WL-004-GW Monitoring Well No. 4 013917 Barium Mon. Well No. 4 -duplicate 013918 Barium WL-002-SD Richneck Ck-OS sediment 013920 Barium WL-005-SS West side Landfill -seep 013922 Arsenic II II 013922 Barium II II 013922 Chromium WL-006-SS Air Vent Area Soil Grid 14-3 013923 Barium II II 013923 Chromium ~:c TCLP results for this element did not exceed standards. North Carolina Department of Environment, Health, and Natural Resources Division of Solid Waste Management Results .· 88 ppm* 12 ppm* 0.53 ppm 1.15 ppm 1.45 ppm 0.22 ppm 301.4 ppm 62 ppb 23 ppb 151.8 ppm 60 ppb 48 ppb 2 ppm>:< 23 ppm >:< 12 ppm* 35 ppm>:< 0.23 ppm * 0.05 ppm>:< 0.08 ppm* 0.08 ppm>:< 16 ppm* 2 ppm* 94 ppm* 12 ppm>:< 72 ppm* 16 ppm>:< State of North Carolina Department of Environment, Health and Natural Resources Division of Solid Waste Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary William L. Meyer, Director NA DEHNR April 26, 1994 MEMORANDUM TO: FROM: Members of the joint Warren County and State PCB Landfill working group Bill Meye& SUBJECT: Sampling Analysis, and Leachate Removal Activity 1982-1993 Enclosed is a summary of sampling and analysis of groundwater monitoring wells, surface stream water, stream sediment, leachate and miscellaneous samples. This report does not include approximately 35 private water supply wells sampled and analyzed in 1982-83 or the recent well testing conducted by the Warren County Health Department. None of the wells tested positive for PCB's. There are also approximately 120 blood samples taken the last quarter of 1982 to establish a background PCB blood level. The blood samples are preserved and will be analyzed if there is a release from the landfill. If you have any questions please contact me at (919) 733-4996. WLM:aw Attachment P.O. Box 27687. Raleigh. North Carolina 27611 -7687 Telephone 919-733-4996 FAX 919-71&-3605 An Equal Opportunity Affirmative Action Employer 50% recycled/ 1 O't post-consumer paper LEACHATE REMOVAL, SAMPLING AND ANALYSIS OF PCB LANDFILL 1982-1993 TABLE OF CONTENTS PAGE I. PCB LANDFILL-SUMMARY OF LEACHATE REMOVAL, SAMPLING AND ANALYSIS EVENTS FOR PCB 1982-1993 1 II. PCB LANDFILL, LEACHATE REMOVAL AND ANALYSIS 1983-1993 2-5 III. MONITORING WELLS, SURFACE WATER STREAM SEDIMENT SAMPLES 1982-1993 IV. MISCELLANEOUS SAMPLES 1983-1993 V. PRIVATE WATER SUPPLY WELLS 1982-1990 6 7 8 PCB LANDFILL SUMMARY OF LEACHATE REMOVAL, SAMPLING AN ANALYSIS FOR PCB'S LEACHATE PRIVATE MONITORING SURFACE STEAM REMOVAL ANALYSIS WATER DATE WELL WATER SEDIMENT 1· E* Well SOIL OTHER 1982 8 8 8 1983 16 16 16 33 35 26 4(( 1984 8 16 16 11 10 9 1985 16 16 16 11 10 2 1986 16 16 16 3 3 1 1987 4 4 4 1988 8 8 8 1989 8 8 8 1 1 1 (2* 1990 8 8 8 7 6 6 1 5 6 (3* 1991 8 8 8 10 0 3 1 1992 8 8 8 11 1 1993 5 2 2 1 (4* *1) Air Samples; 2) Lagoon.sediment basin water; 3) Grass.treatment system; 4) Lagoon sediment basin sediment LEACHATE* REMOVAL ANALYSIS E 82 83 33 33 26 84 11 10 9 85 11 10 9 86 3 3 1 87 0 0 0 88 0 0 0 89 1 1 90 7 6 6 91 10 0 3 92 11 1 93 5 2 2 * I= influent * E = effluent Page 2 PCB LANDFILL LEACHATE SAMPLES DATE GALLONS INFLUENT EFFLUENT 03-07-83 0.42 PPB 0.24 PPB 03-07-83 0.44 PPB 03-08-83 0.34 PPB 0.28 PPB 03-08-83 0.25 PPB 0.043 PPB 03-08-83 2.80 PPB 0.062 PPB 03-14-83 <1.0 PPB 03-16-83 <1.0 PPB <1. 0 PPB 03-21-83 2.471 PPB 0.184 PPB 03-22-83 1.408 PPB 0.294 PPB 03-23-83 1.349 PPB 0.107 PPB 03-24-83 <0.1 PPB <0.1 PPB 03-28-83 <0.1 PPB <0.1 PPB 03-30-83 0.279 PPB <0.1 PPB 04-01-83 0.10 PPB <0.1 PPB 04-05-83 0.40 PPB 0.10 PPB 04-07-83 0.20 PPB 04-11-83 0.20 PPB <0.1 PPB 04-12-83 0.50 PPB <0.1 PPB 04-13-83 1.114 PPB 0.708 PPB 04-14-83 0.708 PPB 0.196 PPB 14-18-83 <0.1 PPB <0.1 PPB 04-19-83 0.22 PPB 0.21 PPB 04-20-83 0.27 PPB 0.24 PPB 04-25-83 0.60 PPB <0.1 PPB Page 3 DATE GALLONS INFLUENT EFFLUENT 04-26-83 0.20 PPB <0.1 PPB 04-27-83 <0.1 PPB 05-10-83 0.20 PPB <0.1 PPB 05-25-83 0.10 PPB <0.1 PPB 06-01-83 <0.1 PPB 07-20-83 1.63 PPB 07-29-83 <0.1 PPB 01-21-83 <0.1 PPB <0.1 PPB 11-29-83 <0.1 PPB <0.1 PPB 01-26-84 0.30 PPB <0.1 PPB 03-07-84 <0.1 PPB <0.1 PPB 04-03-84 0.60 PPB <0.1 PPB 05-03-84 0.60 PPB <0.1 PPB 06-06-84 100 <0.1 PPB <0.1 PPB 07-17-84 90 0.30 PPB <0.1 PPB 08-16-84 90 <0.1 PPB 09-11-84 135 0.20 PPB <0.1 PPB 10-10-84 135 11-05-84 140 0.20 PPB <0.1 PPB 12-11-84 135 =690 <0.1 PPB <0.1 PPB 02-18-85 90 <0.1 PPB 03-26-85 90 <0.1 PPB <0.1 PPB 04-23-85 112 <0.1 PPB <0.1 PPB 05-24&25-85 90 <0.1 PPB <0.1 PPB 06-27-85 90 <0.1 PPB <0.1 PPB 07-16-85 90 <0.1 PPB <0.1 PPB '. Page 4 DATE GALLONS INFLUENT EFFLUENT 08-13-85 90 <0.1 PPB <0.1 PPB 09-18-85 90 <0.1 PPB <0.1 PPB 10-24-85 90 <0.1 PPB <0.1 PPB 11-13-85 135 = 967 <0.1 PPB <0.1 PPB 03-04-86 90 <0.1 PPB <0.1 PPB 04-24-86 5 <0.1 PPB 05-06-86 5 = 95 0.18 PPB 03-21-89 <0.1 PPB 02-26-90 22 04-19-90 100 <0. lppb <0. lppb 05-03-90 105 <0.lppb <0.lppb 05-08-90 100 <0.lppb <0.lppb 08-28-90 130 <0. lppb <0.lppb 09-27-90 120 <0.20ppb <0. lppb 10-25-90 75 = 652 gallons <0.lppb <0.lppb0 03-20-91 75 + 85 04-24-91 75 04-25-91 85 <0.1 ppb 5-30-91 75 + 85 <0. lppb 06-27-91 110 07-26-91 125 + 95 09-11-91 120 09-30-91 55 10-29-91 100 <0.lppb 11-27-91 165 = 1250 gallons 01-31-92 160 Page 5 DATE GALLONS INFLUENT EFFLUENT 02-28-92 160 03-27-92 160 04-29-92 160 06-26-92 160 07-30-92 160 08-28-92 160 09-29-92 160 10-27-92 160 <0.lppb 11-24-92 160 12-23-92 160 = 1780 gallons 01-26-93 160 <0. lppb <0. lppb 02-26-93 160 03-26-93 160 04-23-93 160 05-21-93 160 = 800 gallons <O.l]2J2b <0.lJ2J2b PPB -PARTS PER BILLION PCB'S INFLUENT -LEACHATE PRIOR TO ENTERING TREATMENT WORKS FILTRATION SYSTEM EFFLUENT -LEACHATE AFTER DISCHARGE FROM TREATMENT WORKS FILTRATION SYSTEM .- PCB tJ\NOf1U. SAMPUNG DJ\ TA DATE MONITORING WELL SAMPLES SURFACE WATER SAMPLES 1982 11 -29 <0.1 PPB (8 SAMPLES) <0.1 Pf'B (8 SAMPLES) 1983 <0.1PrB (8 S.I\MrLES) <0.1 Pre (8 S.I\MPLES) 05-05 11 -21 <0.1 PPB (8 SAMPLES) < 0. 1 PPB (8 SAMPLES) 1984 06-06 <0.1 PPB (4 SAMPLES) < 0. 1 PPB (8 SAMPLES) 12-11 <0.1 PPB (4 SAMPLES) <0.1 PPB (8 SAMPLES) 1985 05-24 < 0.1 PPB (8 SAMPLES) <0.1 PPB (8 SAMPLES) 11-13 < 0. 1 PPB (8 SAMPLES) < 0.1 PPB (8 SAMPLES) 1986 05-06 <0 1 PPB (8 SAMPLES) < 0. 1 PPB (8 SAMPLES) 11-18 <0.1 PPB (8 SAMPLES) <0.1 PPB (8 SAMPLES) 1987 06-04 <0.1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 1988 02-02 <0.1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 07-06 <0.1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 1989 03-21 < 0 .1 PPB (4 SAMPLES) < 0. 1 PPB (4 SAMPLES) 10-25 <0.1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 1990 04-19 < 0 .1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 10-25 < 0 . 1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 1991 04-24 < 0 .1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 10-28 < 0 .1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 1992 05-13 < 0 .1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) 11-24 < 0 .1 PPB (4 SAMPLES) <0.1 PPB (4 SAMPLES) PPB = PARTS PER BILLION PCB'S PPM = PARTS PER MILLION PCB'S STREAM SEDIMENT SAMPLES <"0.1 PPB (8 SAMPLESl <0.1 PPB {g SAMPLES' <0.1 1'PB (8 SAMPLES) < 0.1 PPM (8 SAMPLES) <0.1 PPM (8 SAMPLES) <0.1 PPM (8 SAMPLES) < 0.1 PPM (8 SAMPLES) < 0. 1 PPM (8 SAMPLES) <0.1 PPM (8 SAMPLES) <0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) < 0. 1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) < 0.1 PPM (4 SAMPLES) < 0.1 PPM (4 SAMPLES) <0.1 PPM (4 SAMPLES) The PCB Landfill has 4 monitoring wells, 4 surface waler sampling sites and 4 stream sediment sampling sites that are currently sampled semi-annually. .... PCB LANDFILL MISCELLANEOUS SAMPLES DATE 01-06-83 01-06-83 01-12-83 01-12-83 08-28-89 05-03-90 04-18-90 04-18-90 04-18-90 04-18-90 10-29-91 02-26-93 PPB -PARTS PER BILLION PCB'S PPM -PARTS PER MILLION PCB'S ND -NONE DETECTED SAMPLE LOCATION GAS VENT EXHAUST LEACHATE COLLECTION PIPE EXHAUST AMBIENT AIR SAMPLES GAS VENT EXHAUST LEACHATE LAGOON WATER SOIL SAMPLE GRASS (4 SAMPLE SITES) SOIL (4 SAMPLE SITES) CHARCOAL FROM TREATMENT WORKS LEACHATE LAGOON SEDIMENT SOIL LEACHATE LAGOON SEDIMENT RESULTS 3.00 PPB <1.0 PPB ND 2.00 PPB <0.1 PPB <0.1 PPM <0.1 PPM <0.1 PPM <0.1 PPM 0.27 PPM <0.1 PPM 0.12 PPM DATE 08-24-82 08-24-82 01-13/19-83 07-16-85 03-16-90 PPB -PARTS PER BILLION PCB'S PRIVATE WATER WELL SAMPLES SAMPLE LOCATION PRIVATE RESIDENCE WELL PRIVATE RESIDENCE WELL PRIVATE RESIDENCE WELL (35 WELLS FOR 45 RESIDENCES) PRIVATE RESIDENCE WELL PRIVATE RESIDENCE WELL RESULTS <1.0 PPB <1.0 PPB <1.0 PPB <0.1 PPB <0.1 PPB Landfill Leachate Samples The original design of the landfill included a piping system inside the landfill liner at the bottom of the PCB-contaminated soils that are in the landfill. Water that has separated from those original materials and water that fell into the landfill while it was under construction has flowed into this pipes. Samples of this leachate water will be taken and analyzed by methods similar to those for landfill's solid soil samples. This Leachate Collection System was originally design for future sampling and no unusual techniques are required beyond normal sampling safety precautions. Groundwater Samples When the landfill was built, four wells were installed around the landfill, so that samples of groundwater could be taken frequently. Samples of groundwater have been collected and analyzed for PCBs throughout the lifetime of the landfill. During this sampling event, the state proposes to take groundwater samples for PCB and dioxin analysis. In addition, the depth to the surface of the groundwater will be measured. This measurement will allow us to know in which direction the groundwater is flowing in the area under and around the landfill. Surface Water Samples Two stream pass by the landfill. Richneck creek passes several hundred yards to the north. An unnamed tributary of Fishing Creed passes several hundred yards to the south. The state has two permanent sampling locations on each creek. One upstream of the landfill, and one downstream. During this sampling effort, samples will be taken of the water in each of the four locations and analyzed for PCBs, dioxins, and other organic contamination. CHEMICAL TESTING PLAN Modern chemistry laboratories can measure very, very small amounts of the chemicals we must know about at the Warren County PCB landfill. These measures may be as small as one part of a chemical to one billion parts of other materials. These very sophisticated chemistry tests are done only in laboratories that are approved for such tests. All chemical tests to be done on these soil and water samples will be done in approved laboratories operated by the state or by private companies. All samples collected will be tested to see how much and what kind of dioxins and PCBs they may contain. Other special chemical and physical tests will be done for many of the samples An outline of each type of sample and the tests that will be used on them are listed below, , . ~,,..,,__ _,;~~ i'. ~.._ll. t-,·,',<a fJP•~f .,•'~ j,r ed. ,.. tf QUALITY ASSURANCE PLAN _-{JJ~t~~:;..;; 5•:;-;:-;/-~,f~ / ,i..o "'to' fl.• ..---; J.yU-V,._,. 'lV t; ,-/J•N"f7jJ: f ~e).l-4 -SITE SAFETY PLAN ; ! ' fC/7;? _ff~ ______________________ L _0-~ _,y_o : _____ ··---__ _ -----· ~---~ ~ f:_'!_<;_l~":!':7 e. -.. fo~_/::? ______ . -.. --c) _,, S-3 -. --·-·--····~ 9 _l_[ ?:.7.!iL --~ ... --~ _____ L_lf:./J:£/#.J::riZ, ________ .Po ~JJ _ __ _ _____ _ _ _ J,,_, ,;-__ _ _ __________ / __ C/_ l/ Z_7 S > ____ ./' ____ _ _ . v_ ··-·• L -~--1-~ . .!:!4£C ________ !:'!~ JJ_ ·-. _ -------... _ .. I , L./_5' _ --. _ ---~ 9 V Z_ 7 S-__ ) __ -~---· _ . __ . _________ tf ~_r__s__uJ_~----__ . _ . _____ _ __ . __ _ _ __ _ ____ C?, z. __ -z.. . _ _ _ __. __ .. ~ _ 9 Y.z zg -z-_____ . _ -------------Dr-1-L• ,,,_h_,c,_j_1__ ____ _ . . 3_ o I. '1 ; . _ ~CJ'! Z._lf__(e ___ _ ___ _ ,t-Je,J· f 0 --. h .__f ~_ _ ____ D-1,__'1.__ ___ c:D_~'!_~ z 7 i 1 __ _ ______ 'tl_~W~/L-----__________ tJ > _LJ ll YZ. ____________ q ff,t..~J-1 ____________ _ _ _____ _______________ _ d /b_u.f.y_Lf h_flt _~j_qf-0 ___ .=_ _ .M J tftJC?__ //J} __ . . _ _ . _ .. _ . __ .. __________________ _ _ __ -------~~-{c?--.. ~f6_y_/b_~~1JJ1A.thtf_l w . ~) lJl_l/l) _____ --------------------------------- . ____________ (!) /rt l:-___ Q-3 ______ ~g:/(_ ___ )u~L _____ /~_(o _c) _ _ __ .... --····-(J) __ _fj) __ Jl[)_1-(f)_ __ _cci--, £~n-u_d ___ ~--___ 9::._r/1J1._5-__ l,/£~------fl.;v_/,1_ ___ 4.h_AJy S{_~ ------. _________ (j)__......f2/L--f.l✓-_~_L./_ __ 1 ___ 4._f / ___ d_t:J_/~ ___ /_o o )L 7 ____ -c~_o-_{_ -j~-' --~-:/~'------ --------_______ hg--_aLLJ,r __ & ______ pe,-s .,, .... ~ _ , . ___ _ _ _ __ _ __ _ _____ _ --·----------·--·----------··---·----~---·----··---------------... ·-·--···----·-------------·--------· -~h.~~) ___ _h_ /;_..z__~----·---~---~------..... ·----------····-··---------------------------- ____________ u)__ ~_J):f -c ,-~~ ~----~---~-~~-, ~~-~ ... ;)o.S , __ f"--~--=s"--, __ ----W.: "R.ss, U S:--1ac-L,A;-. ON---~~--~--~Qs/h v; 5 \ ______ (])_-:f__~_±h f ✓~ __ d~-c.C.. t,.,,v..1_~_#(._,,-f. ~-__ '! ... ____________ . __ _ _ ___ _______ _ __ ------------ _________________ l}y-_-f: _______ -f)y_ ... pi~r~.f~s __ ./~ftv l-r'_V:,~~-t,-1 ~-_ t;v; __ _ ___________ ____ ___ _______d ~ f ~ v,,.,,,, :t,A .• J--,rn:. 7 _____ __ ___ _ _ _ ___________________________________________ _ ------------·-··------·--·------•--·---------·-----·-·---------··-·----·-··• -··---·--- . ----------...... -------.. ----- ' f. July 6, 1992 -~----'--· --WARREN COUNT'i PCB LANDFILL WATER EXTRACTION 1. llectrical Power 2. Site Survey 3. Drilling, Well Inatallation 4. Soil Cutting• -Teetlng & Disposal 5. Liner Repair, Certification 6. Three (3) Tank Storage System with Saddles & Primer Paint (10,000 Gallon Tanks) 7 . Concrete Containment Arca (2 or 3 tank system) 8. NPDES Permit 9. Quality Control Person for System Set-up & Follow-up Fleet Year only (Division of Solid Waste Management) (26 weeks) 10. Pump 11. Wiring, Piping & Pump Installation for Automate Pumping System (Including stand-by for periodic maintenance & adjuetment or pump replacement, 1 day per month, first year only) 12. Engineering, Drafting & Project Management for rump Automate System 13. Divieion of Solid Waste Management personnel (under Quality Control Supervisor) Responsible for testi11g, !valuation, Release of clean or treated extracted landfill water (13 to 26 weeks/yr) 14. Sand , Carbon Filter Diaphragm 15. Incidentals, Miscellaneous additional costs $ 22,600.00 $ 2,000.00 $ 4,100.00 $ 2,000.00 to 12,000.00 $ 1,500.00 $ 12,400.00 to 19,000.00 $ 12,000.00 to 16,000.00 $ 400.00 $ 26,000.00 $ 1,000.00 $ 7,000.00 to 9,000.00 $ 4,000 .00 to 6,000.00 $ 8,062.00 to 16,123.00 $ 16,000.00 $ 11,906.00 to 15,172 .00 - I I I I I I I I I I I I I I I I I I I collection system, il appears that an additional evacuation and treatment system may take I lo greater than 5 years lo complete at a recovery rate of I to 3 GPM . This time frame may be more precisely determined after the Evacuation System is installed and in operation for several months . 3 . r I I . TOTAL COST FOR INSTALLATION, OPERATIOU FIRST YEAR $ 130,968.00 to 166,895.00 THE FOLLOWING ARI ANNUAL OR PERIODIC COST FOR THE LIFE OF TIIE PROJECT -Quality Control after first year to Honitor, Control Sy•t•m Operation ■, Testing, , Disposal of extracted landfill water, Contract additional work as required (10 to 20 w••k•/yr) -Subcontract Chemical Laboratory to Sample, Teet Extracted Landfill Water on weekly or bi-weekly basis (PCB, PH, CONDUCTIVITY) -Diviaion of Solid Waste HanagQment personnel (under Quality Control Supervisor) Responsible for testing review, Evaluation, Release of clean or treated extracted landfill water (13 to 26 weeks/yr) -Additional Sand, Carbon r :lter Diaphragms -Diaposal of contaminated Sand & Carbon Filter Diaphragm -NPD!S Permit, Annual Honitoring Fee -Contractor atand-by for periodic maintenance & adjustme11t of automate pumping system (l day per month) $ 10,000.00 to 20,000.00 $ 16,400.00 to 32,800.00 $ 8,062.00 to 16,123.00 $ 0.00 to 16,000.00 $ 0.00 to 17,000.00 $ 300.00 to 1,125.00 $ 2000.00 -Incident ah , Hiscellaneous adJ i tlona 1 costs $ 3,676.00 to 10,SOS,OO TOTAL ANNUAL COSTS AFTER FIRST YEI\R UUTIL EVACUATIOU IS COMPLETE $ 40,438.00 to 115.553.00 NOTE: Portions of the work listed above may be performed by the Diviaion of Solid Waste Management or other state Departments in order to minimi~• contractor costs. The coordination and implementation of the inter-departmental work should be performed in the planning etage. 2 f Warren County PCB Landfill Environmental Sampling Data August, 1994 .. /Sanipl~.• :>:::.·:::. , ••••••••.••••••••••••••••••••••••• ~.f i]JIS••·•L0C:9·t·i i·~•0••i••••·••·•······················ ····•~i~~~:••············· ••chernicah··•··· •••••••••• I ~jss'fr \ >Name < ·•·p13ri!m;Jer\••·· ...... ". WL-001-SS Leachate Pond -Ravine 013921 Barium 88 ppm * outlet JI JI 013921 Chromium 12 ppm* WL-003-SS Leachate Pond -middle 942752 PCB 0.53 ppm WL-004-SS Leachate P. -filter outfall 942753 PCB 1 . 15-wln WL-028-SS Leachate P. -filter out -942781 PCB / -1 .4/ ppm duplicate / WL-029-SS Surface Soil Background 942782 PC~J/ 0 . .2 2 ppm WL-001-LC Dry Landfill Contents 942~ PCE / 30 1.4 ppm " " 94t795\ Chlo '6benzene 62 ppb " " () 94'' ~795 1 1,4 I )i-chloro-23 ppb / benzene WL-002-LC Wet Landfill ContE n!,S 94. ~9 PCB 151.8 ppm JI ~II / 94. 1 797 Chlorobenzene 60 ppb \ JI ( \ \1 \~ 94~1 797 1,4 Di-chloro-48 ppb I benzene II \ .~ \ 013919 Arsenic 2 ppm* I II \ / II 013919 Barium 23 ppm * II II 013919 Chromium 12 ppm* JI II 013919 Lead 35 ppm * ------ WL-001-LE Landfill Leachate 013909 Barium 0.23 ppm * WL-001 -GW Monitoring Well No. 1 013914 Barium WL-004-GW Monitoring Well No. 4 013917 Barium Mon. Well No. 4 -duplicate 013918 Barium WL-002-SD Richneck Ck-OS sediment 013920 Barium WL-005-SS West side Landfill -seep 013922 Arsenic JI II 013922 Barium II JI 013922 Chromium WL-006-SS Air Vent Area Soil Grid 14-3 013923 Barium JI II 013923 Chromium * TCLP results for this element did not exceed standards. North Carolina Department of Environment, Health, and Natural Resources Division of Solid Waste Management 0.05 ppm* 0.08 ppm* 0.08 ppm * 16 ppm * 2 ppm * 94 ppm * 12 ppm * 72 ppm * 16 ppm * n ' ( State of North Carolina Department of Environment, Health and Natural Resources Division of Epidemiology James B. Hunt. Jr., Governor Jonathan B. Howes. Secretary r~-~ ~---• a n DEHNA September 12, 1994 MEMORANDUM TO: William Meyer, Director Division of Solid Waste Management THROUGH: John I. Freeman, D.V.M., M.P.H., Environmental Epidemiology Secti FROM: Kenneth Rudo, Ph.D., Toxicologi V,ltf,2. Environmental Epidemiology Section SUBJECT: Health Risk Evaluation Warren County Landfill Samples This memo is a follow-up to the September 7, 1994 memo that evaluated PCB and chromium contamination in the Warren County Landfill. In addition to the compounds commented on previously, the following chemicals were identified: 013921 -88 ppm barium -Leachate pond 942795 -62 ppb chlorobenzene -dry landfill contents 23 ppb 1,4-dichlorobenzene 942797 and 013919 -wet landfill contents 60 ppb chlorobenzene 48 ppb 1,4-dichlorobenzene 2 ppm arsenic 23 ppm barium 35 ppm lead 013909-0.23 ppm barium -landfill leachate 013914 -0.05 ppm barium -monitoring well #1 013917 -0.08 ppm barium -monitoring well *4 013918 -0.08 ppm barium -monitoring well *4 duplicate 013920 -16 ppm barium -Richneck CK-DS sediment 013922 - 2 ppm arsenic -west side landfill 94 ppm barium 013923 -72 ppm barium -air vent area soil The levels of barium, arsenic, lead, chlorobenzene, and 1,4- dichlorobenzene in all the above soil and sediment samples should not pose any increased health risks upon prolonged exposure. P.O. Box 27687, Raleigh. Norfh Carolina 27611-7687 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post-consumer paper I I William Meyer Page 2 September 12, 1994 The EPA MCL for barium is 2 ppm and the North Carolina groundwater standard is 1 ppm. Barium levels detected in the monitoring wells are below both standards and should not pose any increased health risks if this groundwater source was utilized for consumption. If you have any further questions, please feel free to contact me at 733-3410. KR:td cc: Grover Nicholson John Neal .. OCT-20-95 FRI 02:34 BC GeoLo9ic,lnc 91 (':1 879 269E, P.01 (_\_ J. /3,·1 I IO-d-3 -9 5 J966 Bachelor Creek Road Asheboro, NC 27203 (910) 879-2696 FAX (910) 879-2696 To: Company: Location: Fax Number: From: Company: Date: Subject BC GeoLogic, LLC. E.m,iron,nent.tl Cc,mu/r.-mts FAX TRANSMITTAL SHEET Total number of pages transmitted, including this Transmittal Sheet: h MESSAGE OCT-20-95 FRI 02:35 BC GeoLogic,Inc BC GeoLogic, LLC Environmental Consultants Robert Glaser, Hydrologist Hazardous Waste Section Division of Solid Waste Management P.O. Box 27687 Raleigh, North Carolina 27611-7687 Dear Bob: 910 879 2696 October 19, 1995 Attached is the requested peer review of the Division's plan for upgrading the PCB landfill groundwater monitoring network. Thanks for sending the additional infom1ation which allowed me to finally understand what the likely groundwater in situ flow regimen looks like. Having done that, it is my strong recommendation that additional monitoring wells are also needed near the landfill in what, according to the data from the auger holes, is the upgradient part. To do otherwise will leave us v.i th a rather incomplete monitoring scheme and no possibility of defining likely flow paths. Please call me if you wish to discuss any part of this report. Sincerely yours, Attachment cc: William Meyer P.02 OCT-20-95 FRI 02:35 BC GeoLo9ic,Inc PEER REVIEW PROPOSED PCB GROUNDWATER MONITORING SYSTEM INTRODUCTION At the request or'Bill Meyer of the North Carolina Division of Solid and Hazardous Waste, for peer review of a supplemental ground water monitoring system for the State's PCB land fill, I have reviewed the follov.ing: 1. Correspondence from Glaser to Bain dated 09/07/95 2. Internal memo from Glaser to Meyer dated 04/06/95 outlining plans for the monitoring system upgrade 3. Various site maps contained in item 2, above 4. Table of site water level measurements from 11/92 to 3/95, also contained in item 2, above 5. Table of site landfill elevations and a copy of part of the USGS topographic map covering the site 6. Internal memo from David Lo\vn to Sharon Rogers on PCB waste thicknesses. Finding a need for additional information to complete my review, I requested any as-built dra-w"ings, detailed site topo maps, PCB fluid elevations, ge.ologic logs, etc.. These were received on October 10. I have since reviewed the following : 1. Revised water level elevation information for MW4 2. Engineering soil classification logs for the four wells and the eight initi.al auger holes 3. As-built topographic maps and construction details for the PCB site 4. A large obUque aerial photo of the landfill site 5. Recent (October 5, 1995) water level elevations for the site 6. Various well construction diagrams, driller's logs, auger hole location maps, and various reports and correspondence from 1978 through 1983. ·OCT-20-95 FRI 02:36 BC GeoLo,ic,Inc 910 879 269E, REVIEW AND EVALUATION As is my normal practice in assessing the quality of ground,...-ater monitoring networks> I first attempted to construct a potential groundwater flow diredion map for the site in order to determine whether the existing wells were p]aced in geographically strategic positions best suited for detection of any fugitive PCB discharge .. This exercise led to the discovery that the resulting groundwater contour map didn't make good hydrologic sense ,,,hen compared to the site topography. The principal problem appeared to be that the monitoring well with the lowest measuring point (MP) elevation (from the table of water level elevations) had the highest water level elevation. Since receipt of the additional information, it is apparent that the MP elevation for MW 4 js correct on the various maps but is incorrect on the current table of water level elevations. Subsequently, I have used the revised water level elevations along with water level data from three initial auger holes to construct a generic water table map for the site (Figure 1). CONCLUSIONS Proposed State Plan The DSWM Plan is essenria/ly as follows. 1. Install tvv·o additional wells to deeper depths at sites W2 and W3 to detennine the vertical component of flow. 2. Install four additional wells (two sets of nested wells --one deep and one shallow) at two locations in the northeast quadrant of the landfill site. On review of the State Plan and examination of the additional material submitted to me, I find the following. 1. The locations of the existing monitoring wells, relative to the Jandfill as plotted on various maps and to elevations from the site detailed topographic map, are internally consistent. 2. Groundwater in each of the monitoring wells, as recorded in tables furnished to me, fluctuates several feet each year in response to seasonal precipitation and evapotranspiration demand. There appears to be no doubt that each is a functioning monitoring well. 3. I concur v.-ith the DSWM that there is a need for additional spatial coverage and also with the concept of addition of deeper monitoring well installations at the locations of the existing wells to better define the vertical component of flow. P.04 4. The elevation of the water in the waste cell (337 feet) when compared to the average site water level near the cell (299 feet), although not proof that the site is not leaking, is evidence that, if it is, it is doing so at a very low rate. 5. Plotting of groundwater levels from the existing network, supplemented by information on water levels from auger holes located near the crest of the knoll from the initial investigation, show that the present net does not do an adequate job of defining the shape of the upper surface of saturated rock and soil (i.e., the water table) in the immediate vicinity of the PCB landfill. That is, there is not good definition of the upgradient part of this site. 6. In addition, well MW4, even with a c-0rrected MP elevation, has a water level that appears to be anomalously high if only water levels from the existing network are used to construct a water level contour map. 7. The addition of water levels from the initial auger holes (although not the best of good science since they are not from the same period of time) causes the water levels from the existing network to make more hydrologic sense . See Figure 1. When a water table contour map is constructed with the addition of auger hole water levels, upgradient is directly beneath the cell and possibly both to the southwest and southeast, principally along the small ridges in those directions. Discharge is to the northwest and northeast, toward Richneck Creek and possibly south toward the unnamed tributary. 8. Since one cannot evaluate flow direction and/or the hydraulic effect of the landfill on the local hydraulic regime, better definition of both the site water table and the vertical component of groundwater flow is required. Recommended Alternate Plan Therefore, I recommend: 1. Addition of one more well at site MW 4 at a deeper interval to document vertical groundwater movement at this point, as well as to solve any ambiguity as to the representativeness of data gathered there to date. 2. Install three shallow top-of-water-table monitoring wells at former auger sites 4a, 3, and IA (Sheet 3, Suerdrup and Parcel, 8/12/81) to document the upgradient part of the site water table and so that adequate groundwater flow maps can be draVrn. 3. Install the three shallow monitoring wells (item 2, above) first, to construct a more accurate site vvater table map from which on-site adjustments can be made, as necessary, in the location of the two new well nests proposed for the northeast quadrant. 3 ·OCT-20-95 FRI 02:37 BC GeoLo,ic,Inc 910 879 2696 4. Strongly consider the addition of a two-well nest immediately south of the cell at a location based on the new groundwater flow map (item 3, above). 5. CoJlect geologic data, as weJI as soils engineering data, from any new holes drilled for construction of the monitoring wells. -· 6. Finally, I wish to caution that my recommendations for the number of wells and their locations are based on current acceptable practice for monitoring systems in granular materiaJs and should be adequate for monitoring the change in groundwater head across this site, as well as the potential flux of groundwater. There is no affordable monitoring system, in my opinion, that will guarantee 100% early detection of any contaminant in a fractured rock system such as W1derlies this site. The location, attitude, direction, aperature width, nwnber, and degree of interconnection of rock fractures arc essentially unknowable below the ground surface or beyond the edge of a borehole. Therefore, the placement of monitoring wells for early detection of contaminant release is an exercise in the chance interception of the critical fracture(s). Thus, the practicing science, as here, is reduced to making the best educated guess as to the most probable discharge locations: hence, the need for the best possible growidwater potential flow map. Hopefully, any discharge from sites such as this will occur aJong the soil/weathered rock interface which is much easier to monitor for contaminant discharge. 4 P.05 BC GeoLogic, LLC Environmental Consultants Robert Glaser, Hydrologist Hazardous Waste Section Division of Solid Waste Management P.O. Box 27687 Raleigh, North Carolina 27611-7687 October 19, 1995 Attached is the requested peer review of the Division's plan for upgrading the PCB landfill groundwater monitoring network. Thanks for sending the additional information which allowed me to finally understand what the likely groundwater in situ flow regimen looks like. Having done that, it is my strong recommendation that additional monitoring wells are also needed near the landfill in what, according to the data from the auger holes, is the upgradient part. To do otherwise will leave us with a rather incomplete monitoring scheme and no possibility of defining likely flow paths. Please call me if you wish to discuss any part of this report. Sincerely yours, la GeorgeL.B~ A cc William Meyer 3966 Bachelor Creek Road, Asheboro, NC 27203 • (910) 879-2696 PEER REVIEW PROPOSED PCB GROUNDWATER MONITORING SYSTEM INTRODUCTION At the request of Bill Meyer of the North Carolina Division of Solid and Hazardous Waste, for peer review of a supplemental ground water monitoring system for the State's PCB land fill, I have reviewed the following: 1. Correspondence from Glaser to Bain dated 09/07 /95 2. Internal memo from Glaser to Meyer dated 04/06/95 outlining plans for the monitoring system upgrade 3. Various site maps contained in item 2, above 4. Table of site water level measurements from 11/92 to 3/95, also contained in item 2, above 5. Table of site landfill elevations and a copy of part of the USGS topographic map covering the site 6. Internal memo from David Lown to Sharon Rogers on PCB waste thicknesses. Finding a need for additional information to complete my review, I requested any as-built drawings, detailed site topo maps, PCB fluid elevations, geologic logs, etc. These were received on October 10. I have since reviewed the following: 1. Revised water level elevation information for MW 4 2. Engineering soil classification logs for the four wells and the eight initial auger holes 3. As-built topographic maps and construction details for the PCB site 4. A large oblique aerial photo of the landfill site 5. Recent (October 5, 1995) water level elevations for the site 6. Various well construction diagrams, driller's logs, auger hole location maps, and various reports and correspondence from 1978 through 1983. REVIEW AND EVALUATION As is my normal practice in assessing the quality of groundwater monitoring networks, I first attempted to construct a potential groundwater flow direction map for the site in order to determine whether the existing wells were placed in geographically strategic positions best suited for detection of any fugitive PCB discharge. This exercise led to the discovery that the resulting groundwater contour map didn't make good hydrologic sense when compared to the site topography. The principal problem appeared to be that the monitoring well with the lowest measuring point (MP) elevation (from the table of water level elevations) had the highest water level elevation. Since receipt of the additional information, it is apparent that the MP elevation for MW 4 is correct on the various maps but is incorrect on the current table of water level elevations. Subsequently, I have used the revised water level elevations along with water level data from three initial auger holes to construct a generic water table map for the site (Figure 1). CONCLUSIONS Proposed State Plan The DSWM Plan is essentially as follows. 1. Install two additional wells to deeper depths at sites W2 and W3 to determine the vertical component of flow. 2. Install four additional wells (two sets of nested wells --one deep and one shallow) at two locations in the northeast quadrant of the landfill site. On review of the State Plan and examination of the additional material submitted to me, I find the following. 1. The locations of the existing monitoring wells, relative to the landfill as plotted on various maps and to elevations from the site detailed topographic map, are internally consistent. 2. Groundwater in each of the monitoring wells, as recorded in tables furnished to me, fluctuates several feet each year in response to seasonal precipitation and evapotranspiration demand. There appears to be no doubt that each is a functioning monitoring well. 3. I concur with the DSWM that there is a need for additional spatial coverage and also with the concept of addition of deeper monitoring well installations at the locations of the existing wells to better define the vertical component of flow. 2 4. The elevation of the water in the waste cell (337 feet) when compared to the average site water level near the cell (299 feet), although not proof that the site is not leaking, is evidence that, if it is, it is doing so at a very low rate. 5. Plotting of groundwater levels from the existing network, supplemented by information on water levels from auger holes located near the crest of the knoll from the initial investigation, show that the present net does not do an adequate job of defining the shape of the upper surface of saturated rock and soil (i.e., the water table) in the immediate vicinity of the PCB landfill. That is, there is not good definition of the upgradient part of this site. 6. In addition, well MW4, even with a corrected MP elevation, has a water level that appears to be anomalously high if only water levels from the existing network are used to construct a water level contour map. 7. The addition of water levels from the initial auger holes (although not the best of good science since they are not from the same period of time) causes the water levels from the existing network to make more hydrologic sense. See Figure 1. When a water table contour map is constructed with the addition of auger hole water levels, upgradient is directly beneath the cell and possibly both to the southwest and southeast, principally along the small ridges in those directions. Discharge is to the northwest and northeast, toward Richneck Creek and possibly south toward the unnamed tributary. 8. Since one cannot evaluate flow direction and/or the hydraulic effect of the landfill on the local hydraulic regime, better definition of both the site water table and the vertical component of groundwater flow is required. Recommended Alternate Plan Therefore, I recommend: 1. Addition of one more well at site MW 4 at a deeper interval to document vertical groundwater movement at this point, as well as to solve any ambiguity as to the representativeness of data gathered there to date. 2. Install three shallow top-of-water-table monitoring wells at former auger sites 4a, 3, and 1 A (Sheet 3, Suerdrup and Parcel, 8/12/81) to document the up gradient part of the site water table and so that adequate groundwater flow maps can be drawn. 3. Install the three shallow monitoring wells (item 2, above) first, to construct a more accurate site water table map from which on-site adjustments can be made, as necessary, in the location of the two new well nests proposed for the northeast quadrant. 3 4. Strongly consider the addition of a two-well nest immediately south of the cell at a location based on the new groundwater flow map (item 3, above). 5. Collect geologic data, as well as soils engineering data, from any new holes drilled for construction of the monitoring wells. 6. Finally, I wish to caution that my recommendations for the number of wells and their locations are based on current acceptable practice for monitoring systems in granular materials and should be adequate for monitoring the change in groundwater head across this site, as well as the potential flux of groundwater. There is no affordable monitoring system, in my opinion, that will guarantee 100% early detection of any contaminant in a fractured rock system such as underlies this site. The location, attitude, direction, aperature width, number, and degree of interconnection of rock fractures are essentially unknowable below the ground surface or beyond the edge of a borehole. Therefore, the placement of monitoring wells for early detection of contaminant release is an exercise in the chance interception of the critical fracture(s). Thus, the practicing science, as here, is reduced to making the best educated guess as to the most probable discharge locations: hence, the need for the best possible groundwater potential flow map. Hopefully, any discharge from sites such as this will occur along the soil/weathered rock interface which is much easier to monitor for contaminant discharge. 4 o::::e: .-:is; :D ::0 -rri ~ :z: i2: ::, c-:> nc:::> -c=: -:z: ---j --< 0 (a=-t-U,H) ■ (a.~ 11-1. s~ 0 (EL" l'U ,501 0 (_a.a 1i1.ss) z· 0 (a=-ft.~') 1·,~Wt'f I $~~Ill t. "'t. hl~p ·-l • • NORTH CAROLINA DEPARTMENT OF CRIME CONTROL AND PUBLIC SAFETY FINAL REPORT . PCB WASTE DISPOSAL SITE WARREN COUNTY, N.C. SEPTEMBER, 1983 Prepared By: SOLID AND HAZARDOUS WASTE MANAGEMENT BRANCH ENVIRONMENTAL HEALTH SECTION DIVISION OF HEALTH SERVICES NORTH CAROLINA DEPARTMENT OF HUMAN RESOURCES Introduction FINAL REPORT PCB WASTE DISPOSAL SITE WARREN COUNTY The decision to remove the approximately 40,000 cubic yards of PCB contaminated aoil along public roads by the state of North Carolina was based upon the availability of a secure disposal facility. Such a facility is regulated under the Toxic Substances Control Act (TSCA) administered by the United States Environmental Protection Agency. The State of North Carolina applied for permission to utilize a 140-acre tract of land, owned by the State and located in Warren County, to construct, operate, and maintain an Annex 11 PCB Landfill. The site and operational J plans were approved conditionally by the Environmental Protection Agency in correspondence dated June 4, 1979. Additional conditions were added on December 14, 1981. Pre-Operation Phaae Activitie• The North Carolina Solid and Hazardous Waste Management Branch was chosen by the PCB Remedial Action Project coordinators in the Department of Crime Control and Public Safety to ensure construction and environmental monitoring compliance with the Environmental Protection Agency's approval conditions. This was made clear in a pre-construction meeting located at the site on June 10, 1982. Of primary importance in pre~operation activities was the establishment of background data on groundwater and surface water around the site. This is imperative for any long-term environmental monitoring program associated with such disposal facilities. The initial groundwater monitoring wells were constructed according to the Environmental Protection Agency approved standards when general site construction started (June 21, 1982). These wells were found to be unsatisfactory by the North Carolina Division of Environmental Management and replacement wells were installed, with the Environmental Protection Agency's approval the first week of July. One of these replacement wells was vandalized on August 5, 1982, and was again reinstalled. The Environmental Protection Agency stated that the "closing out" of unusable groundwater monitoring using cement would not jeopardize the collection of representative groundwater samples from monitoring wells in the immediate vicinity. Groundwater and surface water background chemical data was collected using the Environmental Protection Agency-approved methodologies and analytical techniques (see attachment I). Vandals damaged the 30-mil PVC liner on August 21 or August 22, 196,r.-Z.. Repairs were made and certified by a representative of the liner supplier. The Environmental Protection Agency inspected the repair work on August 27, 1982, and gave verbal approval at that time to continue construction. Inspections by the North .Carolina Division of Environmental Management to ensure compliance with North Carolina Sedimentation and Erosion Control Laws were conducted on August 3, 1982, and August 25, 1982 (see attachments 11 and III). I I Ronald H. Levine, M.O., M.P.H. DIVISION OF HEALTH SERVICES P.O. Box 2091 Raleigh, N.C. 27602-2091 MEMORANDUM TO: FROM: SUBJECT: June 30, 1983 0. W. Strickland, Head Solid & Hazardous Waste Management Branch Environmental Health Section Thomas C. Kamoski, Environmental Engineer )C~ Solid & Hazardous Waste Management Branch Environmental Health Section Environmental Monitoring of the PCB Disposal Facility ST A TE HEAL TH DIRECTOR Environmental monitoring of the PCB disposal facility to identify releases from the landfill consiam of select sampling and analyses of groundwater, surface water, and surface water sediments. Analytical parameters dictated by EPA are pH, specific conductivity, and total PCB for groundwater and surface water and total PCB for surface water sediments. All sampling, analytical, ·and security chain of·· custody procedures rigidly follow EPA and N. C. Division of Health Services accepted methodologies. Locations of the four groundwater monitoring wells were designated by EPA a1 were the four 1urface water and surface water sediment sampling points (1ee attachment). · The following identifies the dates that environmental monitoring events took place: Pre-Operation Monitoring of Groundwater to Determine Background Quality August 20, 1982 August 30, 1982 September 6, 1982 Pre-Operational Monitoring of Surface Water and Surface Water Sediments to Determine Background Quality July 7, 1982 August 3, 1982 August 10, 1982 Operational Phase Monitoring of Groundwater, Surface Water and Surface Water Sediments ' October 5, 1982 ' October 28, 1982 '--~:::::::..:::..:__:_::.!-.:.::.,:_ _____________ ~ Jome, 8 Hunt Jr / Sarah T Morrow, M 0, MPH ~ · ncn.-n,,,c,,, l"'\C u,,,, • .,., occn,,orcc -· ' i ' . Memorandum Page 2 June 30, 1983 AttadtUlt:!llL i Poat-Operational Phase Monitoring of Groundwater, Surface Water, and Surface Water Sediment ■ (to occur indefinitely twice each year) November 29, 1982 May 16, 1983 To date, all monitoring activity has indicated no release of PCB's are occurring at the disposal facility. All analytical data is available as a part of public record. A functional aspect of the landfill's design is a mechanism to remove free liquid from the waste mass and hence eliminate material that has migration (or release) potential. Pumping of the leachate collection system commenced on March 7, 1983 and continued at various intervals through June 1, 1983. I Approximately S,000 gallons of free liquids were removed from the landfill and treated at the landfill'• treatment works. Below are dates where water analytical work was .conducted on influent and effluent water of the treat- ment system: March April May June 7, 11, 1, s, 10, 2S 1 14, 16, 21, 22, 23, 24, 28, 29, 30 7, 11, 12, 13, 14, 18, 19, 20, 25, 26, 27 .. . ., . The highest concentration of PCB's detected in the influent water was 2.47 ppb /J..47 (10-7)% by ·we,ght]. All effluent analyses show PCB concentrations less than .1 ppb D.(10-)% by weight}. Attached are allowable concentrations of PCB's in food and feed products according to 29 CFR 109(B). Effluent from the treatment works meets EPA drinking water standards. Over fifty-five private drinking water wells from resident• in the area around the landfill were ■ampled in January of 1983. All analytical data 1howed no detectable levels of PCB'■• TCK:ct Attachments Measurements of in-place saturated hydraulic conductivities of the clay liner were taken on September 12, 1982, in accordance with Environmental Protection Agency permit conditions. All measurements showed the liner to meet or exceed regulatory requirement (see attachment IV). Operation Ph••• Activities [ Placement of the contaminated soil into the prepared landfill commenced on September 15, 1982. The last load of contaminated soil was delivered on November 17, 1982. The total volume of contaminated soil was estimated at just under the projected 40,000 cubic yards. An attempt to calculate the average concentrations of PCB in the contaminated soil was made on October 7, 1982, following advice given by Mr. Ralph Jennings, Toxic Substances Section, Environmental Protection Agency. Composite samples were collected at six locations in the contaminated soil fill. Each sample consisted of a composite of material from six foot deep borings. The average concentration of PCB's in the landfill as determined by the October 7, 1982, sampling event was 135 ppm (see attachment V). Operational phase monitoring of groundwater, surface water, and surface water sediments was conducted on October 5, 1982, and October 28, 1982 (see attachment I). Post-Operational Phase Activities Final placement of the topsoil covering over the clay and PVC cap was impeded by wet weather conditions. The North Carolina Division of Environmental Management inspected the landfill for compliance with erosion control regulations on November 5, 1982 and November 17, 1982 (see attachment II). The lack of an adequate stabilized topsoil cover resulted in the uncovering of the PVC cap due to accelerated erosion during January, 1983. The lack of the topsoil covering's weight on the PVC cap allowed decomposition gases to accumulate in bubbles under the PVC cap instead of being forced through the gas vent located at a single location at the center of the landfill. These bubbles were pierced and temporary venting pipes installed to prevent gas buildup until weather conditions allowed the contractor to repair the PVC cap and finish the placement of topsoil. Analyses of gases venting from the single permanent vent and the temporary vents by the North Carolina Department of Human Resources and the United States Environmental Protection Agency showed them to consist primarily of methane with concentrations of PCB's far below OSHA standards. Post-operational phase environmental monitoring of groundwater, surface water, and surface water sediments was permformed on November 29, 1982, and May 16, 1983. Identical monitoring events will occur each November and May until the United States Environmental Protection Agency Regional Administrator and appropriate authorities of North Carolina determine otherwise. 1 ./ The pumping of the landfill' s leachate collection system to remove --, V' rainwater that accumulated during the operational phase commenced on March 7, (( 1983. Over 5,000 gallons of water were removed and treated in the site's treatment works by June 1, 1983. Any effluent from the treatment works met } the Environmental Protection Agency's drinking water standards for PCB's. _,,, 2 Final con1tructlon of the landfill was completed on July 14, 1983. The State of North Carolina accepted the site conditionally on July 15, 1983. All k1y1 to lock• at th1 faci~ity ar1 in the cu ■tody of the North Carolina Solid and Hazardous Waste Management Branch. The Environmental Protection Agency permit conditions identifying po1t-clo1ure maintenance of the PCB landfill specify month¼f inspectioDJLof the phy1tcal atructure• at the landfill and the leachate c~lection/detection sumps in addition to the twice a year environmens!! monitorig& .. Program. The Solid and Hazardous Waste Management Branch retains responsibility for these I actions until directed otherwise by th~ Secretary of the Department of Ruman Resources. 3 \ . ·.:::··,. --~ ~ ;: .-~ ~ .... _ ;:~~-i" .... :! .\ ;• ::" .: . .-.. :.,)~/:-:-: . ' ,, ' •. •·· ',! _r'.:.::,- , ' : ~ -~: .. ~-/ •-f.' ·. • .. ·;,·_;. .. "/. •: .. :..'· '. ----• A_~_O_N~-UL-r_Tla_N_O_~_Ol_Ne_EEH_ir_s __ -~-[E_lt:_~_F:Rs_A.._~-s-~-!-.~---t_e_s_,_I_n_c_. _____________ _ A CIVIL ENOINEERJNo • srnucTURAL EN01:sE1:.-nr:.o • GEoTEcus1caL ENGINEERING • l!ATEIIIALs TESTL'-:G SERvicEs 401 GLENWOOD AVE .• P. 0. Box 12447. RALElGll. N. C. 2760~ 919/828-0801 March 7, 1983 North Carolina Department of Natural Resources & Community Development Raleigh Regional Office 3800 Barrett Drive Post Office Box 27687 Raleigh, North Carolina 27687 Attention: Mr. Edward L. Berry, Hydrologist Re: Monitoring Wells PCB Landfill Warren County, North Carolina Dear Mr. Berry: hAt.r.iUH nEGIONAL OFFICE As requested by Jim Lineberger Grading & Paving, Inc., of Gastonia, North Carolina, Ezra Meir Associates, Inc. constructed four (4) moni- toring wells around the PCB Landfill in Warren County, North Carolina. The wells were constructed in August 1982 under the direction of Mr . . Daniel H. Biechler, of Sverdrup & Parcel, Consu~ting Engineers, Greens- boro, North Carolina. On August 25, 1982, Mr. Biechler accepted the construction of the monitoring wells and the grouting of all open holes. Effective on August 25, 1982, it is our understanding that the State of North Carolina assumed responsibility of the wells. Attached, please find monitoring well construction records and one (1) copy of the well specifications. If you need any further information in this regard, please let us know. Very truly yours, EZRA MEIR ASSOCIATES, INC. Y-✓ ..,f( 1~ ~ Edward G. Aguirre Enclosure EGA:sam I . •. DIVISION OF ENVIRONMENTAL HANAGEMENI Bz~a Meir Associates, Inc. P. 0. Box 12 4 4 7 Ralei~h, NC 27605 ATTENTION Mr. Edward G. A~uirre Dear Mr. Aguirre: RE: Monitoring Wells In Warren Co./ and DEM Groundwster Re~ulatio t I am writing to infer~ you that we have received the well construc- tion information on the four Warren County wells and to tha~k you for your prompt action. I would also like to inform vou and vour corporation that any wells that you construct for groundw3ter information 3hould oe reported to us regardless of who they ape for~~ what groundwater information is being sought. If the information i 3 ~f 3 confidential nature. send 3 letter requesting confidentiaility q l~n~ witt1 sts~~d r~~sn~3 to have us restrict ~nv release of t n8 in f□rmatia:1 for som~ so~c ~f i ed time oeriod. Again thank vou for yo~r c~o ~~~~~i0 n ~n -j cont~ct m~ i f I can be of helo. EB:bch Sinc::!relv , Edw,H·d Berry H v d r· o 1 o g i s t SH££1. ). Of" · c ·o·M,..uTATloNs FOR MotJ1roRJNG WeU-S OATEJUt."( 9,1982- CHKO r- 1 'N5L No I z 3 ~ ---- L --- - - To/? ELEV ------------ :?·}2 --- 328 ·-- 3ZZ ---- 326 ------- --=--3-~_:.vi__''-------~----~ l:.f',CH Ot.12!:Crt~,,.J I . . 4 . · .. · . 4 "°' • A. --.g:.--.-. • V ·, L--y---------- . CON C S l-AB . ·. ------,-.-------Borro/V? SC€£:;A..J ELEV ,_ ~ ~·':1 ~TI-L ---. ·-----·- 'l9/ CO I 281 Za' ,___ 281 Zu' --·- 251 'lo' I c5TEGL C,qp H/Nt:;fiO~ ,l,oc.t...~,,-J1.£ I 8" S TECL P/Pli' SCHG'O<..>Le °4-0 z•,I," L,o,.;,:; l i d"4@u'' t:Ar-t-1 01-RknoAJ, o R C. ,c4, ><:. 4/1-WW P NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT WELL RECORD DIVISION ut' ENVIRONMENTAL MANAGEMENT P.O.Box27687 -RAL,El~,N.C.27611 919·733·2020 DRILLING CONTRACTOR E2~tf'/,f!:' ,,..IS~Y//i~ NO. WELL CONS'_'f1.UCTION PERMIT NO. 1. WELL LOCATION: (Show sketch of the location below);,;!/ Nearest Town: ~~,,v~.A/' /v, C:, D33 YI County: Wt'}U/.N Lek ,v z{/ 7 ____ ........;._,...------,~--e--=----,.--:-:--...,.....----0-uadrangle No. ////b,A./ · L/.S &,~. (Road,Coaununity or Subdivision and Lot No. l /97' / • 2. OWNER:$/ :f¼U' ,,/"~RTh &; ... -?.5J/;;./'4'. RILLING LOG i ·, 3. ADDRESS:;..... ____________________ _ DEPTH FRO-M--TO FORMATION DESCRIPTION 4. TOPOGRAPHY: draw,valley,slope,hilltop,flat(circle one) · s. usE oF WELL: /J/cv.1:-/,.e.hv.:; DATE, a -18 ·B .3 ..J 6. DOES THIS WELL REPLACE AN EXISTING WELL? . VIS I . I 7. TOTAL DEPTH, S/ RIG TYPE OR METHOD: ------ 8. FORMATION SAMPLES COLLECTED: YES NO_-'X__,__ __ 9. CASING: Depth Inside Dia. fr~31/Zto2'13 ft_L\:.....;:q_•_ Wall thick. type or weight/ft. II SI ::SC-IIE/,1.dE .t,10 ,,lVG 10. GROUT: Depth Material Method From~to~O~ ft _ _..3..-....;;..S_' __ 11. SCREEN1 Depth Dia. Type & Opening If adaitional space is needed, use back of form From;03to1i}_ft __ f .... 0_1_ ~twT✓/.IPOP.:!> SL() 1 LOCATION SKETCH (Sho~ distance to nUll'bered roads, or other map reference point&) 12. GRAVEL: Depth Size Material From.,?O3 to 2 Ci( ft :!. 2Z 13. WATER ZONES(depth) : _____________ _ 14. STATIC WATER LEVEL1 __ ft.:~~::top of casing Casing is ft. above land surface ELEV: 15. YIELD(gpm) : _____ METHOD OF TESTING: ___ _ 16. PUMPING WATER LEVEL: ________ ft. after ____ hours at ______ gpo. 17. CHLORINATION: Type _____ -'Amount ____ _ 18. WATER QUALITY: TU1PERATURE (OF) __ 19. PERMANENT PUMP: Date Installed'----------- Typec..-. _____ Capacity _____ (gp~)HP __ _ Hake __________ Intake Depth ____ _ Airline Depth _____ _ 20. HAS THE OWNER BEEN PROVIDED A COPY OF THIS RECORD AND WFOR!'.ED OF THE DEPARTME?JTS REQ:JIRE~~!;TS }I.NO RECOMMENDATIONS? 21. REl'.A.IU<S -------:----------------------------I do hereby certify that this well was constructed in accordance with N.C. nell Construction Regulations and Standards and that this well record is true and exact. NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT WELL RECOl:D OIVISl()N 01' ENVIRONMENTAL MANAGEMENT P. 0. Box 27687 -RAL,EI~, N.C. 27611 919·733·2020 DRILLING CONTRACTOR £2~~ /,ft' t"'/S'~Y//;~ NO. WELL CONS'_'II.UCTION PERMIT NO. 1. WELL LOCATION: (Show sketch of the location below)~/ Nearest Town: ~~.,vll;'\/"' Iv,~. D33 YI County: W~}UL°N Lti~--vz!v A ~Al ;;_ ~ ./ .,.,,, _ _____________________________ Quadrangle No._,_rT....:..;.•r-=-/_,.~-:--c:-~'-'=·~=~=.::::.::.!... __ _ (Road,Community or Subdivision and Lot No.) /9'7 I • 2. OWNER:$/ ~z:1;-t2 c~«Vh c:::::;. .. -?~/4;./_.,, : RILLING LOG 3. ADDRESS: _____________________ _ 4. TOPOGRAPHY: draw,valley,slope,hilltop,flat(circle one) . S. USE OF WELL: ;7/~;-/,,.e//',A9 0ATE1 8-/8 ·B3 ..J . 6. DOES THIS WELL REPLACE AN EXISTING WELL? VIS I . I 7. TOTAL DEPTH: S/ RIG TYPE OR METHOD: ------ 8. FORMATION SAMPLES COLLECTED: YES NO _ __.X:c....1.---- 9. CASING: Depth Inside Dia. ;}t 3qz to 2Ci 3 ft_'\:....,'1._1_ Wall thick. type or weight/ft. II r :so1Eb1 .. dE .:.,10 ,,2vL. 10. GROUT: Depth Material Method From~to~oq ft ___ 3oc..=:.S_' __ 11. SCREEN: Depth Dia. Type, Opening DEPTH FRO-M--TO FORMATION DESCRIPTION If adaitional space is needed, use back of form Fr0111303to1i1.._ft __ fL.0_1_ a,,v71;,.11,1()p~ SL() I LOCATION SKETCH (She~ distance to numbered roads, or other map refereoce point•) 12. GRAVEL: Depth Size Material From,'?O3 to 2. 'i. / ft ::t 2Z 13. WATER ZONES (depth): _____________ _ 14. STATIC WATER LEVEL: __ ft.~~~~=top of casing Casing is ft. above land surface ELEV: 15. YIELD(gpm) : _____ METHOD OF TESTING: ___ _ 16. PUMPING WATER LEVEL: _______ f.t .. after ____ hours at ______ gpr.i. 17. CHLORINATION: Type ______ .Arnount ____ _ 18. WATER QUALITY: TEMPERATURE (°F) __ 19. PERMANENT PUMP: Date Installed'---------- Type ______ Capacity _____ (gp~)HP __ _ Make __________ Intake Depth ____ _ Airline Depth _____ _ 20. HAS THE owi;ER BEEN PROVIDED A COPY OF THIS RECORD AND lllFOR..".ED OF THE DEPARTME!>TS RI:Q:.JIR!:~!£!;Ts AND RECOMMENDATIONS? 21. REl'.AIU<S ---~---:----------------------------I do hereby certify that this well was constructed in accordance with N.C. ~ell Construction Regulations and Standards and that this well record is tnie and exact. NORTH CAROLINA DE.PARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT WELL RECOr.o DIVISION OF ENVIRONMENTAL MANAGEMENT P. 0 . Box 27687 -RALEIGH, N.C. 27611 919-733-2020 DRILLING CONTRACTOR eZ.,e.f fffi/-' /4.:,~_,//1/(REG. NO. WELL CONSTRUCTION PERMIT NO. l. WELL LOCATION: (Show sketch of the location below)#,2 D34U2 Nearest Town : _ _::;.?_0...;':4..:....:;:.&=-::...•·-=-~•.c.;;.--<·/4...;:;,:,;::;.;..'//:..-'-'-1\./.~, J..l''-'.'-----------Coun ty: ~.,-;c' //41 6..-A/;,{/ A .c~a..-,7 __________________________ Quadrangle No. /Tr / • rv VS 6-_5 (Road,Community or Subdivision and Lot No.) /97/ 2. OWNER: ..5/4 z{: C,/ /4,E$ u,-42,,(;.._,,...-? DRILLING LOG 3. ADDRESS: DEPTH FRO-M--TO 4. TOPOGRAPHY: draw,valley,slope,hilltop,flat(circle one) FORMATION DESCRIPTION .. t s. USE OF WELL: 4,;v.,"z/,e/:-V,; DATE: 8· 10-BZ. 6. DoEs THis WELL REPLAcr{N EXISTING wELL? Vc-3'. 7. TOTAL DEPTH1 -¥7' RIG TYPE OR METHOD: 8. FORMATION SAMPLES COLLECTED: YES NO x 9. CASING: Depth Inside Wall thick. type Dia. or weight/ft. E/4- From3Z13 to 2.13/ ft ~s/ ¥~c./'/.dv_i"/ ~",P;--c. lO. GROUT: Depth Material Method From328 ta504/ft -t ~+'" 11. SCREEN: Depth Dia. Type, Opening From 303 to~ft zo' 12. GRAVEL: Depth Size Material From303 to..l...E/ ft_~Z;;._2_1_ 13. hATER ZONES(depth): _____________ _ 14. STATIC WATER LEVEL: ft abovetop of casing 0 below Casing is ft. above land surface ELEV: 15. YIELD(gpm) 1 ME'l'HOD OF TESTING: ___ _ 16. PUMPING WATER LEVEL: ________ ft. after _____ hours at ______ gpr:i. 17. CHLORIIIATION: Type ______ Amount _____ _ 18. W/,7Ert QU/,LITY: ________ TE;MPERATURE (0 F) __ _ 19. PER:1.J..NEllT Pl,'}\P: Date Installed --------- Type ______ Capacity _____ (gprn) HP ___ _ ~:ake ___________ In take Depth;__ ____ _ Airline Depth _____ _ ,</.? .ezc.-e-p..-Y.a~/4--:.-o-<( . If aodicional space is needed, use back ot form LOCATION SKETCH (Show distance to nwcbered roads, or other map reference points) 20. P.AS T!!E o;-:i:ER EEEN PROVICED A COPY OF ';iilS lu:CORD ;..:;o 1,;FO:<.~:::o 01;' 'i"i:E DEFr.!<'i"J-1..:::;,s REQUIREl-'..Er;,s A!-,D REcm::1.EllDATIO!IS? 21. REl-~P.;<S ---------------------------------------I do hereby certify that this well was ccnstructed in accorddnce ~ith ll.C . ~ell Construction Regulations and Standards and that this well tecord is true and exact. NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT WELL RECOl:D DIVISION OF ENVIRONl,\E..'HAL MANAGEMENT P.O.Box27687 -RALEIGH,N.C.27611 919-733-2020 DRILLING ':ONTRACToR-fY.4 /?.?..ac:, /l'~f:S REG. NO. WELL CONSTRUCTION PERMIT NO • .....,;- 1. WELL L('CATION: (Show sketch of the location below) -3 D JJ./-u ~ Nearest Town1 t-,/..4.e.-v...v;:;2V/ //, C, County: M~;,V .:::::;w-v•1{,, ___ .;.;.::a=...;._;_"--....;....,.._~~.....;...---------/ -------------------c _____ Ouadrangle No. /rr7Cvt/ . V .<; 6-~ (Roa'.S,Co111111unity or Subdivision and Lot No.) /'17/ 2. OWNER:_~,; .::5/4k ~//"Utd ~M:.V-4 DRILLING LOG 3. ADDRESS1 ---------------------- 4. TOPOGRAJ•HY: draw ,valley, slope,hilltop, flat (circle one) 5. USE OF '~ELL:,,.%,✓,'6..,e.:,r",;:r DATE: 8-ri-82., 6. DOES THIS WELL REPLAC~ EXISTING WELL? W-:S, 7 7. TOTAL DEPTH1 f'/ ; RIG TYPE OR METHOD: _____ _ 8. FORMATION SAMPLES COLLECTED: YES NO 9. CASING: Depth Inside Dia. Wall thick. or weight/ft. X type 37 1 // -,.l r ~CL';!'oo/ 10. GROUT: Depth Material Method .f.30y _j / e I Fro~to ft ____ _ 11. SCREEN: Depth Dia. Type, Opening DEPTH FRO-M--TO FORMATION DESCRIYTION If aod1t1onal space is needea, use back of !orm Fro:u 303 to 283 ft zo I C..ti,,✓7✓-,.!./t);j_-<, .5Lor LOCATION SKETCH 12. GRAVEL: 9epth Size Material From3D3to 28/ ft! 22 13. WATER ZONES (depth): _____________ _ 14. STATIC 1•;ATER LEVEL: ft a~ovetop of casing 'below Casing is ft. above land s•.irface ELEV: 15. YIELD(gpm) : _____ METHOD OF TESTING: __ _ 16. PUMPING WATER LEVEL: ft. ------- after ____ hours at ______ gpr:1. 17. CHLORINATION: Type ______ Ar:iount ____ _ 18. WATER QUALITY: _______ TE:MPERATliF.E (oF~-- 19. PER!-IANENT PL'!-:?: Date Installed Type ______ Capacity _____ (gf~)HP __ _ Make __________ Intake Depth ____ _ Airline Depth _____ _ (Show distance to numbered roads, or other -e reference painta) 20. HAS THE OWNER oEEN PROVIDED A COP\' OF THIS !'.ECORD ~;o r::,·c:-.'-'.£D OF T::E DE?.0.::::-:'.::I\TS R:.QUI!s."'.!'.E:::-s r,•;o RECO!'-V.E!WATio:;s? 21. REMAl'J(S ---------------------------------------------1 do hereby certify that this well was constructed in ac==r~ance with N.C. ~ell Con~truction Regulations and Standards and that this well record is tr~e and exact. . . NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT WELL RECOl:O DIVISION OF ENVIRONMENT AL MANAGF.i-,icNT P. 0. Box 27687 -RALEIGH, N.C. 27611 919-733-2020 . DRILLING CONTRACTORL'Ud ~/ .-4~6 REG. NO. WELL CONSTRUCTION PERMIT NO. 1. WELL LOCATION: (Show sketch of the location below)~ -y' D 34 U + . Nearest Town1._--=W-~r.a;;;:f~;.;;;v-:i:..y.:_;v;-;___:_/.::;~.:;;_""'.:;./.....,_,.LM..J;..;,_c_. _________ county: Mtc&°/V £~.v/v Quadrangle No. 4/;?2',./ /1,,/5&5, _(_Ro_a_d ___ C_o_mm_u_n.,.1i-t.tJ __ o_r_S_ub_d_1-· v-i""a_i.,..o_n_a_n_d_. _Lo_t_N_o ___ ) ______ ,/7 / 2. OWNERv¥i ::(/4Zf ,t,/ ~ 4,:.'~/✓Ji/,1 DRILLING LOG 3. ADDRESS1;.. _____________________ _ 4. TOPOGRAPHY: draw,valley,slope,hilltop,flat(circle one) s. USE OF WF.LL:4-✓✓k✓.:v,? DATE: 8-l":>-82 6. DOES THIS WELL REPLA~ EXISTING WELL? y1/°~, J 7. TOTAL DEPTH: __,3..::.<9°_✓_ RIG TYPE OR METHOD: _____ _ 8. YORMATION SAMPLES COLLECTED: YES NO X 9. CASING: Depth Inside Wall thick. type Ea From 32D to 7$3 ft Dia. or weight/ft. 31' .Y~-,/eU/U-I"~ ?Y-C:. 10. CROUT: Depth Material Method From 32D fo 30"tt :t I°&/ ----- 11. SCREEN: Depth Dia. From3o3 to 26J ft w' DEPTH FRO_M_·_TO FORMATION DESCRIPTION If additional space is needea, use back ot form LOCATION SKETCH Type, Opening C.,:J,vT,,;,,,,vDu:5 3Lor (Show distance to nu:,bercd roads, or other ac.ap reference points) .I. ____._ 12. GRAVEL: Depth Size Material From3O3 to 28/ ft ±zz ----- 13. WATER ZONES(depth): 14. STATIC WATER LEVEL: ft.~~~~:top of casing Casing is __ ft. above land surface ELEV: 15. YIELD(gpm):. _____ METHOD OF TESTING: ___ _ 16. PUMPIUC WATER LEVEL: ______ ___:ft. after ___ .-hours at ______ gpr:i. 17. CHLORINATION: Type ______ /\..~o~~t ____ _ 18. i,;ATER QUT>.LITY : ______ __,TUIPERATURE (OF) __ 19. PERM.•~"IEllT PL'MP: Date Installed : Type_·--~--' Capacit'y _____ (qpm) HP __ _ Make ___ -'-______ lntake Dept;.h ____ _ Airline Depth _____ _ 20. HAS THE OWNi:R BEE!I PROVIDED A CO?'i OF 'l"r.IS RECORD J.2lD It,FOF-'SD OF 7i:iE DEPhR'!ME!ITS REQUI?-EHE!-TS AllO RECOMMENDATI0!-lS? 21. REMA:u<S ----:--------------------------------1 do hereby certify that this well was constructed in accorda~cc with N.C. ~ell Construction Regulations and Sta,idards and that this .,,.ell record is true and exact. c. Estimated Waste Volume The landfill site will be conatructed to accommodate up to 40,000 cubic yards of soil contaminated with PCBs. E. ·nescription of Environmental Setting 1. Roadside The discharge of material containing PCBs occurred on approximately 211 shoulder miles of North Carolina highways. The PCB spills have been identified in 14 counties. See Figure 1 for a general location of the spill areas. The discharge of material containing PCBs occurred mainly in rural areas on the roadway shoulder within 24 . inches of the pavement edge. 2. Disposal Site a. Location and General Description The proposed disposal site is located in the northeastern North Carolina Piedmont Plateau of Warren County, approximately four miles south of Warrenton. See Figur·e 2 for a county map showing the site location. The proposed disposal site consists of ap- proximately 142 acres of which about five acres will be used for the actual disposal of the soil contaminated with PCBs. The remaining acreage will serve as a buffer zone for the disposal area. b. Hydrology-Topography Surface water discharges are controlled by the topographic position of the land. The proposed disposal area occupies the crest of a gently sloping upland ridge which has 70 to 80 feet of relief. Surface water discharge from the site is toward seven draws located in a radial pattern around the site. See Figure 7 for surface drainage patterns. Two large draws immediately Northeast, and West of the site receive the major portion of surface run-off. Exposed clayey subsoils, topogra- phic position and side slop.es tend to minimize . surface water infiltration and maximize surface water run-off. 15 ~Qgl/ .. 7 . --------:=~ r. II -----\j ....__ ... ......-......,.......T"""T"T"~~........-----.::c=------y,--•·· . I V "-.u-111""'II, ,~ l \./\. '\ "'-// _ '" I SURFACE DRAINGE FROM PCB DISPOSAL AREA . '. ' - . v" ... A_ :r\.. $_~ LEGEND · ~ : ... J • SOIL BORING LOCATIONJ.11 7 _.. SURFACE DRAINAGE ~ · ~~(( \ \ \ ~ 1/r~J -~ -SCA LE. .. ;.:;001 -. Surface water discharge is to Richneck Creek and an unnamed tributary to Richneck Creek via draws around the site. Richneck Creek discharges to Fishing Creek. The confluence of Richneck and Fishing Creek is approximately 3 miles downstream and Southeast of the Warrenton raw water intake. Stream classifications for Richneck Creek and Fishin9 Creek in the discharge area is class c. Approximately 40 miles separate the site discharge area and the closest raw water intake. U. s. Geological Survey Flood Records of N. c. streams indicate that the 100-year flood eleva- tion is not more than 8 feet above average water levels in Richneck Creek and its tributaries. The site is 70 to 80 feet above these streams and not subject to flooding. · Recharge of groundwater ~esulting from su+- face water infiltration and percolation is esti- mated to be low. There should be no significant fluctuation in water table elevations beneath the ridge occupied by the disposal site. All features on the site which enhance surface run-off reduce groundwater recharge. Rapid run-off and t4e rela- tivelf small area of gently sloping ridge crest minimizes the volume _of precipitation available for infiltration and recharge. The close proximity of 2 deep draws for ground water discharge and the relative low retention and water storage capacity of deep subsurface weathered rock (silty sand and sandy silt) indicates a low potential for buildup of any significant hydraulic head or water table below the ridge. The net effect of constructing impermeable barriers on the ridge crest and divert- ing any off-site surface water will be to further reduce the potent;al for mounding of groundwater below the site. . Precipitation aata from the u. s. Weather Bureau Station at Arcola in Warren County indicated, that at the time of the September study, rainfall in Warren County was approximately SX greater than the preceding S year average. There were no observed evidence of reduced soil colors or mottling of soil colors to jndicate the presence of a permanent water table. At the time of the boring, no water table was observed at the 42 foot depth. It is concluded that the water encountered in the September study was a result of normal vertical movement of percolating surface water rather than ground water tables. 16 Representative Hydrographs of wells in Warren County indicate that during September ground water levels are declining. Ground water levels are at maximum elevations during the period from January to April. Borings performed during Februarr 1, 1979 by the consulting firm of Soil & Material Engineers Inc. indicated a static water level of ~pproximately 303' to 306' in elevation or 37 to 32 feet below land surface. Boring depths were 45' below land surface. In the Warren Section of the report title "Geology and Ground Water Resources in the Raleigh Area", compiled by the U. s. Geolo- gical Survey, the static water level of well number 122 was measured to be 47' below land surface. For location of well number 122 see Figure 3. This well is similar to the disposal site borings with respect to elevation, topographic position and time of water level recordation. Hydrographs of observations wells in Warren County show ground water fluctuations from approximately 5 to 11 feet. The study conducted by the firm Soils & Materials Engineers Inc. was carried out during the middle portion of maximum seasonal fluctuation of 9round water.· The measured elevation of groundwater 1n February, 1979, was 303 to 306 feet. Ground water elevations could be predicted to rise an additional 5 to 6 feet. The predicted highest ground water elevation would be 309 to 312 feet. Maximum surface elevation in the disposal area is 343 feet. The highest predicted water table elevation is 31 feet below land surface which would allow a maximum excavation depth. of 24' to remain 7 1 from the high water table elevations. Construction of a clay liner would afford a 14 foot separation from the high water elevation. c. Soil Conditions Soils on the site are characterized within the standardized engineering concept of surficial earth materials. Procedures established by the American Association of State Highway Officials (AASHO) and the American Society for Testing Materials (ASTM) were utilized for soil evaluation. The N. c. De~artment of Transportation and Soil & Material Engineers, Inc. independently evaluated site conditions and performed pertinent field and laboratory analysis on materials obtained from 19 soil borings in the disposal area .. Surficial soils on the site consists of red-brown silty clays. The top soil on the site is significantly eroded but where present extends to a depth of 3 to 6 inches. Subsoils are clayey 17 and silty and extend to depths of 38 to 45 feet. In general, a gradual transition exist between upper silty clays and deeper clayey silts. Obser- vations of soil borings on site indicate that the clayey silts grade into sandy silts and silty sands. The general stratifications of clays overlying silts which grade to fine sands is typi- cal of the Piedmont province. Detailed analysis of the soil materials were performed by the N. c. Department of Transpor~atian laboratory and Soil & Material Engineers, I~c. ~he two laboratory analysis indicated an upper layer of clayey soils ranging in depth from Oto 38 feet below land surface. Soils at the 45' maximum drilling depth were classified as silty sands and sandy silts. Standard Engineer11m~-::rTvoratory tests for maximum density at optimum moisture and permeabi- lity at 95 and 100 percent maximum density were performed on the soils. At 9~% maximum density the permeability of l.9 x 10-cm/sec and minimum permeability of l.8 x 10-~ cm/sec . At 100 percent maximum ~,nsity no permeability was ireater tjlan 1.0 x 10 gn/s9c. ~be 8 acres encompassed by de- tailed soil borings and analysis demonstrates that SO,oou to 75 oo cubic ards of cla e materials e avai able to cons 1g y e soil d. nv1ronmental Profile The proposed disposal site occurs on open, rolling cultivated land presently utilized for soybean production. In addition to the soybeans, various weeds and grasses have been obse~ed growing on the proposed disposal site and include such species as foxtail, ground cherry, thistle, braomsedge, ragweed, aster, and horseweed. Mixed deciduous hardwoods in association with pine occur on the periphery of the soybean field. Oaks in- cluding white, southern red, blac, and post, red maple, sweetgum, tulip poplar, hickory and loblolly pine are the major canopy species present. Under- story species consists of redbud, dogwood, American holly, red cedar, and winged sumac scattered among small shrubs, saplings and vines -primarily honeysuckle. 18 II. ALTERNATIVES TO THE PROPOSED ACTION AND THEIR POTENT I AL U1P .~CTS A. Procedures Utilized to Evaluate Alternative Disposal site Locations The North Carolina Department of Suman Resources, Division of Health Services conducted a site search for potential land areas that would be suitable for the permanent storage of the PCB contaminated soil. The objective of the investigati-:n was to evaluate available State and offered priv.ate property for potential usage as disposal sites. It was ,1nticipated that several suitable sites could be located. A set. of general guidelines was developed ·· to assist in the evaluation of potential sites. The following is an outline of general site criteria and EPA technical requirements utilized in the location and evall.lation of potential disposal sites for the PCB contami- nated soil. 1. General Area of Potential Site Locations The search for potential disposal sites was gen- erally limited to an area bounded by the counties where the PCB spills had occurred•. Areas east of the spills were generally eliminated due to evidence of seasonal high ground water levels relatively close to land sur- face. Potential sites in areas of the western portion ,,f the State were given a low priority due to the long haul distances. :?. General Site Screening & Evaluation Procedures (a) Site Relief A PCB chemical waste landfill should be loca- ted in an area that provides low to mode,rte tAPAr-xrafhic relief to prevent landslides ors umping. eriai photographs,· U. s. Geological survey topo- graphy maps and field measured elevations were utilized to evaluate site relief suitability. Sites with potential of land slumping resulting from required construction activity were rejected. (b) Topographic Position Hill, flat, slope and draw are the four basic topographic positions for surface features. Wells installed on hill or ridge positions normally exhibit the lowest average yield of 9round water per foot of well. Bill or ridge positions are also amenable to diversion of surface water and control of local recharge to ground water by 19 minimizing areas available for recharge. Hilltop and ridge were assigned a high ~riority for topo- graphic position. Sites predominated by draws or difficult to manage slope position were rejected. U. s. Geological Survey topographic maps and on-site evaluations were used to determine topogra- phic position suitability. (c) Soils Surficial soils are formed by weathering of subsurface geological rock formations. The charac- teristics of the surficial soils are determined by the chemical and physical properties of underlying rock formations. Therefore, detailed geological maps of specific areas and State and County soil surveys were used to delineate sites with poten- tially suitable soils. Site specific surface evaluations, soil borings and field & laboratory testing of soil materials were performed on sites with reasonable probability of meeting the hi~h silt and clay content parameters for PCB chemical waste landfills. Sites with sandy surface soils, rock outcrops or exposed boulders, surficial soils with shallow depth to bed rock and insufficient on-site soils for clay liners were rejected. Surficial soils contained within the landfill site which could not meet the following EPA technical requirements were rejected. · (1) permeability 1.0 x 10-7 cm/sec. (2) percent passing no. 200 seive230 (3) plasticity index~lS (d) Hydrology Potential contamination of ground or surface water were major considerations for screening all sites. Any site that could not be designed to prevent hydraulic cbnnection ·between the PCB con-taminated soils and surface streams or springs and ground water was rejected. Sites within the 100-year floodplain, within close proximity of a class I or II reservoir utilized as a public water supply or within½ mile of an A-II stream as de- signated by the D.E.M. were rejected. A separa- tion distance of 500 feet from the site and water supply wells was used as a ·site screening para- ·meter. The depth to ground water would limit the depth of excavation and total storage volume of a given site. The standard for site evaluations with respect to ground water separation was SO feet . It was acknowledge during the site evalua- tion process that the probability of locating 20 sites with ground water levels below 50' from land surface would be difficult if not impossible~ Therefore, sites were screened according to the predicted or measured minimum depth from land surface to the upper limits of iround water tables. Transmissivity, gradients and discharge areas for ground water were considered in site evaluations. Ground water fluctuations were predicted from data generated by U. s. Geological Survey publi- . cations on geology and ground water resources and field observations or measurements. Predicted, observed or measured upward fluctuation of ground water resulting in relatively shallow water tables would cause a site to be rejected. Rainfall and evaporation data from the U. s. Weather Bureau in combination with U. s. Geological Re~orts and field measurements were used to predict the maximum . upper fluctuation from the measured static water levels on sites that were drilled. (e) Site Size The disposal site for the PCB contaminated soil should be large enough to allow adequate con- struction and protection of the disposal area. Considerations for sizing a site include: con- struction of disposal pit; storage area for stock- piling borrow materials to allow separation of earth liner, topsoils, leachate collection and spoil materials; access and turn around area for haul vehicles, separate sedimentation ponds for runoff from disposal pit and soil stockpile areas; areas for installation of monitoring wells up gradient and down gradient of disposal pit; berms or ditching for diversion of surface water and a buffer and security zone. A minimum 16-20 acres in a fairly regular configuration was the rejection criteria for site size. (f) Access Sites with deeded right-of-ways were assigned higher priority than sites with no road ~rontage, no deeded right-of-ways or property access by easement. Consideration was also given to the length and construction difficulty of access roads from state maintained roads to the disposal pit. (g) Isolation of Site Population densities within 1 mile of proposed sites and sites which would require transportation of the PCB contaminated soil through highly popu- 21 - B. lated areas were considered for site evaluations. The objective of this standard was to locate ·sites which would impact the least number of citizens during transportation and disposal~ Alternative Sites Evaluated 1. Total Sites Evaluated The above outlined standards were utilized to evaluate approximately 90 sites in 20 counties. Every available tract of state-owned land considered to be a possible candidate as a site to receive PCB contaminated soil was investigated. These included properties assigned to the National Guard, institutions, tower sites, prison property experimental farms, state parks, state forests, utility-owned property and properties under Department of Transportation jurisdiction. Federal property on the Fort Bragg military reservation was also evaluated. The remaining sites were offered for evaluation by private individuals and corporations, and county govern- ments. 2. Site Rejection Approximately 90 percent of all potential sites were eliminated due to violation of one or a combination of evaluation standards. A majority of the sites were eliminated due to the location with respect to private or public water supply reservoirs, intakes and wells; high water tables and unsuitable soil characteristics. The range of site evaluations included sites from 1.5 to 1300 acres; soils from highly impermeable saturated marine clay materials in Wilson County and impermeable clay stone pits in the Triassic Basin to sand dune sur- ficial deposits on the Fort Bragg Military Reservation. Water table elevations varied from 3' to greater than 40' below land surface.· Topographic positions varied from relatively flat areas to areas with greater than 30 degree side slopes and population densities from a few homes per square mile to hundreds within a mile of the site. Eleven of the total available sites were considered to have a high probability for meeting the criteria for PCB chemical landfills. Detailed soil borings and sub- surface investigations were made on these eleven sites. Table II lists these eleven sites. Sites in Franklin County, the Nash County Prison Site, the Wake County Prison Site, Chatham County Brick Plant site and the Harnett County O.O.T. Borrow Pit site were rejected from subsurface investigations. The remaining 6 sites 22 in Person, Warren, Nash, Wake, Chatham and Granville Counties were evaluated by EPA and State personnel. Consideration was given to multiple site distribution by development of these sites; however 4 of the sites were rejected and more detailed subsurface analysis were required on the Chatham and Warren sites. Maximum density, ~ermeability at 95% maximum dry density and optimum moisture tests, volume of material suitable for clayey liners and water table monitoring test were performed on the Chatham and Warren sites. Both sites afforded essentially equivalent evaluations. The Chatham County site was unavailable for purchase by the State for development as a PCB chemical landfill and therefore rejected from further considerations. In order to increase the disposal site alternatives requests were made by the State to County Boards of Commissioners for permission to evaluate existing sani- tary landfill sites as potential sites for disposal of the PCB contaminated soil. Table III illustrates the result of subsurface evaluations for suitable soil materials and water table elevat~ons. The sanitary landfill sites were either unsuitable for development or were unavailable for deyelopment as a PCB chemical landfill. 3. Selected Site Of the six most suitable sites located in Nash, Person, Wake, Granville, Chatham and Warren counties the Warren County site on SR 1604 demonstrated the least restrictions and the greatest degree of protec- tion of the public health and environment. Additional tests were performed by an independent consulting firm to confirm the state's evaluation of the site. Appli- cation was made to EPA for site approval for this site to be developed into a disposal site for the PCB con-· taminated soil. Site and conceptual plan approval was granted. 23 DIVISION OF HEALTH SERVICES - P.O. Box 2091 Raleigh, N.C. 27602-2091 James H. Scarbrough, Chief Residuals Management Branch EPA, Region IV 345 Courtland Street, N.E. Atlanta, Georgia 30365 Dear Mr. Scarbrough: Ronald H. Levine, M.D., M.P.H. STATE HEALTH DIRECTOR October 11 , 1982 The original groundwater monitoring wells for the Warren County PCB Landfill were identified according to the well numbers on the engineering drawings. Specifics are as follows: Coordinates From Surface Wel 1# Engineering Drawing Elevation (ft.) 1 10112 N 341.6 10146 E 2 10667 N 327 .8 9667 E 3 10235 N 322.5 9454 E 4 9662 N 320. 5 9669 E A request to install replacement monitoring wells was made on July 2, 1982. These replacement wells were completed on August 18, 1982. While exact coordinates were not detennined, they are located within 10 feet of the original wells. These replacement wells retain the identifying numbers of the original wells. The original well casings were filled with cement from the bottom to the ground surface. On August 6, 1982 it was discovered that the half finished well 12 had been vandalized with creosoted lumber. This vandalized hole was closed out by filling it with cement from the bottom to the ground surface. The second replacement well 12 was installed within 10 feet of the original well. If you have further questions, please advise. Sincerely, ~G'!str~ Solid Hazardous Waste Management Branch Envt nmental Health Section Jomes B Hunt, Jr Sarah T Morrow MD MPH STATE OF NORTH CAROUNA --··---·--DEPARTMENT OF HUMAN RESOURCES ··--··· '.. ' North Carolina Department of Crime Control .I~ & Public Safety 512 N. Salisbury Street P. 0. Box 2'/687 R<1lei!Jl1 2/611 7687 (919) '/3.'32126 James B. Hunt, Jr., Governor September 8, 1982 I le111.1n R Cl,1rk, Sc'.crel.iry {) f I Mr. Al Hanke Environmental Scientist EPA, Region IV 345 Courtland St., NE Atlanta, GA 30365 Re: PCB landfill Warren County Dear Al: Enclosed are the results of the background water monitoring conducted by the Division of Health Services, N. C. Department of Human Resources. I trust.this meets with your approval. WWPjr:jj Enc. cc: 0. W. Strickland Tom Karnoski Jim Scarborough Gary D. Babb .,,,,.,,,- Sincerely, .ff'~ ~A 1~-11, 1,,. ~ 11 lam W. Phil lips, r. Assistant to the Secretary GROUNDWATER & SURFACE WATER IDNITORING All groundwater, surface water and stream sediment samples were analyzed for PCB by gas chromatograph utilizing electronic capture detector as specified by E.P.A. Samples were collected at the following frequencies: Groundwater August 20, 1982 August 30, 1982 September 6, 1982 Surface Water July 23, 1982 August 3, 1982 August 10, 1982 Stream Sediment July 23, 1982 August 3, 1982 August 10, 1982 All samples showed less than 1.0 part per billion PCB. This is the detection limit of the analy.tical equipment used. .. --·~ GROUNDWATER K>NITORING H s ecific Conductivit August 20 1 1982 Well 1 9.6 80 Replicate 10.0 80 Well 2 5.9 450 Replicate 5.9 470 Well 3 5.1 160 Replicate 5.1 160 Well 4 5.4 170 Replicate 5.3 160 August 30 1 1982 Well 1 5.1 250 Replicate 5.2 260 Well 2 5.0 400 Replicate _5.0 400 Well 3 4.4 110 Replicate 4.6 110 Well 4 5.7 60 Replicate 5.6 65 Se2tember 61 1982 Well 1 5.4 465 Replicate 5.3 465 Well 2 · 5.8 450 Replicate 5.9 455 Well j 5.0 65 Replicate 5.0 66 Well 4 5.8 63 Replicate 5.8 63 ' , July 23 1 1982 UT-DS Replicate UT-US Replicate RC-DS Replicate RC-US Replicate August 31 1982 UT-DS Replicate UT-US Replicate RC-DS Replicate RC-US Replicate August 10 1_ 1982 UT-DS Replicate UT-US Replicate RC-DS Replicate RC-US Replicate SURFACE WATER OONITORING H S ecific Conductivit 6.2 65 6.2 70 6.3 65 6.3 70 6.0 70 6.1 70 6.1 65 6.1 65 7.4 77 7.5 76 7.3 76 7.5 76 7.3 78 7.4 78 7.2 74 7.2 73 7.3 67 7.2 69 7.2 64 7.2 63 7.0 68 7.3 67 7.1 62 7.1 63 -· ... ,,_, ........... :... .. ,-;: _...., •• ~ ... ,, ....... a_ .... . . •·· •-i~ ...... .,~ ·:·.· ....... -i."! ..... ~ ••~r-• ,,_.._-:. ~~•.t ; • .. :~Jl"•·,, .......... . ·",~:·•,C .. ·.~1.. (:·:·•.,.• . .... ~ .·· ...• -... : L.,. ··· .•. ,;: -. . ·•·---~-- ·• . .J.--· ............ ., .. · .... I I I r [ r r r f f r r r r f .- ... :• .; 1 I GENERAL DESCRIPTION· FINAL REPORT PCB WASTE DISPOSAL SITE . WARREN COUNTY The PCB Waste Disposal Site is a hazardous waste · landfill, ' t containing approximately 40,000 cubic yards of polychlorinated biphenyl (PCB) contaminated ■oil, located in Warren County, North Carolina. PERTINENT DATED Contractor'■ bids for the construction of the site were opened on January 21, 1982, and the contract was awarded to Jim Lineberger'& Grading & Paving Inc., of Gastonia, NC on May 28, 1982. Construction work began on June 21, 1982. Continuous heavy rains and vandalism of the groundwater monitoring wells and the 30-mil PVC liner curtailed job progress throughout the month of AugQst, and construction was not completed to the stage necessary for PCB placement until September 15, J . 1982. NC DOT trucks began hauling PCB contaminated soil on from Fort I Bragg on October 6, 1982, and finished on October 27, 1982. Construction work was completed on July 14, 1983. The final inspection of the completed project was conducted on July 15, 1983 and final acceptance was on that date. , ·,: CONSTRUCTION SEQUENCE AND DESCRIPTION Initially four groundwater monitoring wells were installed, located north, south, east, and west of the landfill. These wells were I . determined to be unsatisfactory, as designed and installed, by the NC Department of Natural Resources and Community Development. Four -1- North Carolina Department of Crime Control.I~ & Public Safety 512 N. Salisbury Street P. 0. Box 27687 Rolei~/12'i611 7687 (919) 73.'12126 James 8. Hunt, Jr., Governor September 8, 1982 0 f I Mr. Al Hanke Environmental Scientist EPA, Region IV 345 Courtland St., NE Atlanta, GA 30365 Re: PCB landfill Warren County Dear Al: Enclosed are the results of the background water monitoring conducted by the Division of Health Services, N. C. Department of Human Resources. I trust.this meets with your approval. WWPjr:jj Enc. cc: 0. W. Strickland Tom Karnoski Jim Scarborough Gary D. Babb ,_,,/" Sincerely, .-r!!f' ~ ~A 1~-71, Ir· ~lliam W. Phillips, r. Assistant to the Secretary GROUNDWATER & SURFACE WATER KJNITORING All groundwater, surface water and stream sediment samples were analyzed for PCB by gas chromatograph utilizing electronic capture detector as specified by E.P.A. Samples were collected at the following frequencies: Groundwater August 20, 1982 August 30, 1982 September 6, 1982 Surface Water July 23, 1982 August 3, 1982 August 10, 1982 Stream Sediment July 23, 1982 August 3, 1982 August 10, 1982 All samples showed less than 1.0 part per billion PCB. This is the detection limit of the analytical equipment used. ·• ··-~. ., .. GROUNDWATER IDNITORING H s ecific Conduc ti vi t August 20 1 1982 Well 1 9.6 80 Replicate 10.0 80 Well 2 5.9 450 Replicate 5.9 470 Well 3 5.1 160 Replicate 5.1 160 Well 4 5.4 170 Replicate 5.3 160 August 30 1 1982 Well 1 5.1 250 Replicate 5.2 260 Well 2 5.0 400 Replicate ,5.0 400 Well 3 4.4 110 Replicate 4.6 110 Well 4 5.7 60 Replicate 5.6 65 Se~tember 61 1982 Well 1 5.4 465 Replicate 5.3 465 Well 2 · 5.8 450 Replicate 5.9 455 Well j 5.0 65 Replicate 5.0 66 Well 4 5.8 63 ; Replicate 5.8 63 I ... • 4 SURFACE WATER K>NITORING H S ecific Conductivit July 23 1 1982 UT-DS 6.2 65 Replicate 6.2 70 UT-US 6.3 65 Replicate 6.3 70 RC-DS 6.0 70 Replicate 6.1 70 RC-US 6.1 65 Replicate 6.1 65 August 31 1982 UT-DS 7.4 77 Replicate 7.5 76 UT-US 7.3 76 Replicate 7.5 76 RC-DS 7.3 78 Replicate 7.4 78 RC-US 7.2 74 Replicate 7.2 73 August 101. 1982 UT-DS 7.3 67 Replicate 7.2 69 UT-US 7.2 64 Replicate 7.2 63 RC-DS 7.0 68 Replicate 7.3 67 RC-US 7.1 62 Replicate 7.1 63 Disposal Site The proposed disposal site is located in the northeastern North Carolina Piedmont Plateau of Warren County, approximately four miles south of Warrenton. (See Maps). The proposed disposal site consists of approximately 142 acres of which about five acres will be used for the actual disposal of the soil contaminated with PCBs. The remaining acreage will serve as a buffer zone for the disposal area. Surface water discharges are controlled by the topographic position of the land. The proposed disposal area occupies the crest of a gently sloping upland ridge which has 70 to 80 feet of relief. Surface water discharge from the site is toward seven draws located in a radial pattern around the site. Two large draws immediately Northeast, and West of the site receive the major portion of surface run-off. Exposed clayey subsoils, topographic position and side slopes tend to minimize surface water infiltration and maximize surface water run-off. Surface water discharge is to Richneck Creek and an unnamed tributary to Richneck Creek via draws around the site. Richneck Creek discharges to Fishing Creek. The confluence of Richneck and Fishing Creek is approximately 3 miles downstream and Southeast of the Warrenton raw water intake. Stream classifications for Richneck Creek and Fishing Creek in the discharge area is class C. Approximately 40 miles separate the site discharge area and the closest raw water intake. U.S. Geological Survey Flood Records of N. C. streams indicate that the 100-year flood elevation is not more than 8 feet above average water levels in Richneck Creek and its tributaries. The site is 70 to 80 feet above these streams and not subject to flooding. Recharge of ground-water resulting from eurface water infiltration and percolation is estimated to be low. There ■hould be no signficant fluctuation in water table elevations beneath the ridge occupied by the disposal site. All features on the site which enhance surface run-off reduce ground-water recharge. Rapid run-off and the relatively small area of gently sloping ridge crest minimizes the volume of precipitation available for infiltration and recharge. The cloee proximity of 2 deep draws for ground-water discharge and the relative low retention and water storage capacity of deep subsurface weathered rock (silty sand and ■andy silt) indicates a low potential for build- up of any ■ignificant hydraulic head or water table below the ridge. The net effect of constructing impermeable barriers on the ridge crest and diverting any off-site surface water will be to further reduce the potential for mounding of ground-water below the aite. Subsurface boring• performed during February 1, 1979 by the conaulting firm of Soil & Material Engineer ■, Inc. indicated a ■tatic water level of approximately 303' to 306' in elevation or 37 to 32 feet below land surface. The study conducted by the firm Soils & Materials Engineer■, Inc. was carried out during the middle portion of maximum sea■onal fluctuation of ground-water. The measured elevation of ground-water in February, 1979, was 303 to 306 feet. 25 Ground-water elevations could be predicted to rise an additional 5 to 6 feet. The predicted highest ground-water elevation would be 309 to 312 feet. Maximum surface elevation in the disposal area is 343 feet. The highest predicted water table elevation is 31 feet below land surface which would allow a maximum excavation depth of 24' to remain 7' from the high water table elevations. Construction of a clay liner would afford a 14 foot separation from the high water elevation. Surficial soils on the site consists of red-brown silty clays. The top soil on the site is significantly eroded but where present extends to a depth . of 3 to 6 inches. Subsoils are clayey and silty and extend to depths of 38 to 45 feet. In general, a gradual transition exist between upper silty clays and deeper clayey silts. Observations of soil borings on site indicate that the clayey silts which grade to fine sands is typical of the Piedmont province. Detailed analyses of the soil materials were performed by the N.C. Department of Transportation laboratory and Soil & Material Engineers, Inc. The two laboratory analyses indicated an upper layer of clayey soils ranging in depth from Oto 38 feet below land surface. Soils at the 45' maximum drilling depth were classified as silty sands and sandy silts. Standard Engineering laboratory tests for maximum density at optimum moisture and permeability at 95 and 100 percent maximum density were performed on the soils. At 95% maximum density the permeability of 1.9 x 10-7 cm/sec and minimum permeability of 1.8 x 10-8 cm/sec. At 100% maximum density no permeability was greater than 1.0 x 10-7 cm/sec. The 8 acres encompassed by detailed soil borings and analysis demonstrates that 50,000 to 75,000 cubic yards of clayey materials are available to construct highly impermeable soil liners. 26 #' ! ' i .• ( ·-·~----7 ... . . . .. • I • iARREN COUNT.Y. • \ • \ "'-· . -&Ill 27 I. •• , ' ., 0 B. > '. Background Information The first deliberate discharge of what was later identified as PCB liquid . materials took place the last week of June, 1978, on remote roads of the Fort Bragg Military Reservation. The discharge was investigated by Fort Bragg personnel who secured liquid samples of the material. The next discharge occurred on July 27 and July 29 on the roadway shoulders on NC 58, north of Centerville in \~arren County. This discharge was reported by prfvate citizens to the N, C, Highway Patrol, who alerted the Division of Health Services, Water Supply Branch. Water Supply Branch personnel notified Division of Environmental Management, Water Quality Program personnel in the Raleigh Field Office of the spills. Raleigh Field Office personnel investigated the spill on July 31 as an oil spill and on finding no oil ponded or evidence in surface waters, returned to their office without taking further action. On August 2, the Water Quality Operations Br■Dch, Division of Environmental Management, received a call from a Johnston County farmer concerning a spill on NC 210 in front of his farm. Because of the description of the odor and the effects on field workers being reported, a staff chemist was immediately dispatched to investigate the spill and to take appropriate samples. Grass, soil, and water samples were hand delivered to the Division of Environmental Management Laboratory for analysis later that afternoon, August 2. The same chemist who investigated the Johnston County spill encountered a similar spill near Snow Camp, North Carolina on SR 1004, Alamance County, while returning to his home. A sample was taken from the spill area and hand delivered to the laboratory the follewing morning for analysis. On August 4, the Laboratory's Analytical Section Chief notified the Water Quality Operations Branch that the material spilled in Johnston County ap~ared to be Aroclor-1260, a Polychlorin~ted Biphenyl {PCB) substance. The Water Quality Operations Branch immediately notified the Chief of the Environmental Protection Agency, Region IV, Emergency Response Branch, of the Laboratory's findings. After briefing the Director, Division of Environmental Management, a meeting was called with representatives of the Attorney General'• Office, the Department of Crime Control and Public Safety, and Public Information representatives of the Secretary of the Dep8rtment of Natural Resources and Comnunity Development. A notification to all all enforcement officials was prepared and sent over the Police Information Network system during the late evening hours of August 4, A news release was prepared and 1ent to local newspapers for publication in the Saturday morning newspaper. The same day, the laboratory confirmed material discharged in Alamance and Chatham Counties was Aroclor-1260, the same form of PCB material found in Johnston and Harnett Counties. Also on August 4, the N .• C. Highway Patrol delivered s6il •amples obtained from Chatham County to EPA. The results of the EPA laboratory analysis were reported to SBI on August 8, On August S, Water Quality Operations Branch met with concerned citizens in Johnston County, investigated the spill areas in Johnston and Harnett Counties, and eon .. •Ced a·,door-to-door coetact vith people reai.41111 alqn& NC 210. lecause of concern by some reaident1 along NC 210, the Division or ~i&hway, Department of Transportation wa1 reque1ted to cover the spill with a layer of 1and in order· to 1uppre1a the noxiou1 odors present. Thi• was completed in late afternoon August S and continued on August 6. 29 ~cency, National Institute of Occupational -Safety and Health, Nat1ona1 - lnstitute of Environmental Health Sciences, and the Center for Disease Control. State personnel in attendance were from the Division of Health Services, Natural Resources and Community Development, Department of Agriculture, and the Department of Transportation. Industrial users of PCBs were represented by a person from Carolina Power and Light. The purpose of this meeting was to assess the immediate risks to the persons who live along the spill routes and to discuss the safety of those persons who would be participating in the removal and storage of the PCB contaminated soil. On September 6, 13, and 19 alternative methods of removing soil from the roadway shoulders were conducted on noncontaminated sections of roadway shoulders . ~'hen the soil removal procedure had been formulated a test removal operation was conducted. The test removal operation was performed on October 5, 1978 on a one mile PCB contaminated section of NC 58 near Inez on Warren County. The PCB contaminated soil obtained during the test removal operation has been temporarily stored at a disposal site in Harren County. The purpose of the test was to examine the practicality of picking up the contaminated material as well as any possible health or environmental effects. On November 6, test results indicated that the pick up of contaminated shoulder material was not harmful to the environment or personnel. On September 29, 1978, Governor James B. Hunt's request for assistance from the Federal District Assistance Administration, Department of Housing and Urban Development was denied. On October 4, North Carolina officials were notified by the Federal Highway Administration, U. S. Department of Transportation, that the request for emergency relief funds was denied. During the month of December a Draft Negative Declaration was prepared pursuant to the North Carolina Environmental Policy Act. The statement was sent to State Clearinghouse on December 21, 1q7s for circulation. Comments received on the Draft Negative Declaration requested an EIS be prepared. Therefore, a Final Negative Declaration was not prepared. On December 12, an application was filed with EPA for approval of the Warren County site for placement of contaminated PCB material. On January 4, 1979 a hearing was held on the Warren County site at the National Guard Armory. During the period January 25-31, 1979 additional soil Aamples were taken by the Division of Environmental Management to substantiate the location of the contaminated material and determine if any migration had occurred. Test results indicated that the material was present and had not migrated. On January 29, 1979, a meeting was held in Washington, D. C. between representa- tives of the State of North Carolina and EPA officials to discuss the current PCB regulations and to discuss alternative solutions. On February 6, the state of North Carolina filed petition with EPA to amend the rules under the Toxic Substances Control Act to allow consideration of alternate methods of treatment, On February 15, 1979, a test was run on a contaminated section of NC 210 in Johnston County and on March 22, on a contaminated section of SR 1004 in Alamance County to determine the feasibility of utilizing the theory of fCB fixation with activated carbon. 31 On June 4, 1979, the EPA Administrator, Douglas Castle, ruled against the petition of February 6 to change the regulations to allow consideration of alternate methods of treatment. The Region IV EPA Administrator. John White. on June 4. 1979 approved the State's application to construct a land- fill in Warren County for disposal of the PCB contaminated soil. Definition of PCBs 1 PCBs (polychlorinated biphenyls) are a class of chlorinated. aromatic compounds which have found widespread application because of their general stabilities and dielectric properties. PCBs have been prepared industrially since 1929 and are now produced in many foreign industrial countries. The Monsanto Company's preparations of PCBs were termed ''the Aroclors''. Produc- tion of PCBs ceased in the United States in mid 1977. The outstanding physical and chemical characteristics of PCBs are their thermal stabilities. resistance to oxidation. acid. bases. and other chemical agents as well as their excellent dielectric (electrically insulating) proper- ties. These ~nd other properties have led to numerous uses of PCB such as dielectric fluids (in capacitors and transformers). industrial fluids (use in hydraulic systems. gas turbines. and vacuum pumps). and plasticizers (adhesives, textiles. surface coating, sealants. printing. and copy paper). PCBs were prepared industrially by the chlorination of biphenyls with anhydrous chlorine. using iron filing or ferric chloride as catalysts. The crude product was generally purified to remove color, traces of hydrogen chloride, and catalyst which was usually achieved by treatment with alkali and distillation. The resulting product was a complicated mixture of chloro- phenyls with different numbers of chlorine atoms per molecule. (This fact is responsible for the physical state of PCB preparations). Most individual chlorophenyls are solid at room temperature whereas commercial mixtures are mobile oils. The most important physical properties of PCBs from an envoronmental point-of-view are solubility and vapor pressure. The solubility of PCBs in water is low and decreases with increasing chlorine content. Values given by Monsanto are 200 ppb (parts per billion) for Aroclor 1242, 100 ppb for Aroclor 1248, 40 ppb for Aroclor 1254, and 25 ppb for Aroclor 1260. Studies on the solubility of PCB in water are complicated by the fact that these compounds are strongly eorbed onto various surfaces. PCB has been shown to sorb relatively rapidly onto charcoal, plastic. glass, and silt or soil particles. PCBs have a high epecific gravity (Aroclor 1260/1.500~ and a relatively high density (Aroclor 1260 weighs 13.50 lbs./gallon at 25 C). Loss of PCB by evaporation 1• extremely ■low, i.e. Aroclor 1260 exposed to l00°C for six 1 Hutzinger o. et. al., Chemistry of PCBs 1 enc Pres Cleveland, Ohio, 1974. 32 8. Landfill Monitoring Four groundwater monitoring wells will be constructed and located North, South, East, and West of the landfill. The groundwater wells will be monitored in accordance with 44 FR 761.41(6) standards. Base line groundwater quality will be established by sampling the groundwater wells on one week intervals for 3 weeks. Groundwater Base line groundwater quality will be determined during construction and prior to receiving contaminated soil. Four permanent surface water monitoring stations will be located to determine water quality. Two receiving streams will be. monitored, Richard Creek on the northern site perimeter and an unamed ttibutary to Richard Creek on the southern perimeter. Two stations, one on each stream, will be located up gradient from any site surface run-off event. Two stations, one on each stream, will be located immediately down gradient from the site and through which all flow from surface runoff events will pass. Representative surface water and sediment samples will be monitored at each station in accordance with 44 FR 761.41 (6) parameters. txcluded from analyses are chlorinated organics as indicated in a letter to Governor Hunt from John White (EPA Regional Administrator) dated 4, June, 1979. Twelve groundwater, 12 surface water, and 12 sediment samples will be monitored for base line data. Three sets of samples will be obtained from each ground and surface water monitoring point on 30-day intervals during construction. Each set will consist of 1 sample from each groundwater well and 2 (water and sediment) from each surface water station. 47 I • I '!,J .bmes 11. Hunt, ,Jr., Governor July 2, 1982 I leman H. Cl,.111-, Svcrc t,11 y () t j Mr. Charles Jeter Regional Administrator EPA, Region IV 345 Courtland Street Atlanta, GA 30365 Re: N. C. Superfund Project PCB Landfill Deviation from Approved Construction Plans Dear Mr. Jeter: ·tt ~ JUL '1 198 Groundwater monitoring wells have recently been installed at the Warren County PCB Landfill as part of its construction activity. While apparently meeting EPA standards, they do not conform to North Carolina Standards which require additional grouting and use of a bentonite seal above the well screen. I am requesting that North Carolina be al- lowed to install four additional groundwater monitoring wells to replace the four existing unsatisfactory groundwater monitoring wells. These replacement wells will be: 1) Installed within 10 feet of the existing wells. 2) Installed with a bentonite seal above the well screen. 3) Installed with grout extending from land surface to the top of the bentonite seal. 4) Screened so as to provide monitoring capability for at least the top ten feet of the surficial saturated zone at its lowest expected elevation . 5) Developed using drilling mud or revert as approved on June 24, 1982 via field letter (Tom Karnoski -N. C. Solid and Hazardous Waste Management Branch to Robert Boone -Sverdrup & Parcel). 6) Installed as soon as possible. Mr. Charles Jeter Page 2 July 2, 1982 7) Wells will be clearly labeled as monitor wells, not to be used as a source of water supply. 8) Sampled (2 replicates) to assure background quality data is similar to background samples collected from the original wells prior to any waste disposal . If background water quality deviates from that of the original wells, a new background water quality data base line must be established for the new wells as originally required and prior to any waste disposal. Upon acceptance of the new wells, the original wells will be abandoned in accordance with North Carolina standards. If you have any questions, please contact me. HHPjr:jj cc: Jim Scarborough 0. W. Strickland Perry Nelson Gene Roberts Frank Rainey Jack Reavis Bill Raney Bob Jansen Tom Karnoski ~ AUG 19 198 North Camli11a Uepartment of Crin1e Control .11117# & Public Safety 512 N. Slllisb111y S11el'I I'. 0 . Box 2/637 U11/ei11l1 21611-7687 (919) 733-21:!,i James B. Hunt, Jr., Governor August 17, 1982 • ieman R. Clark, SeGel,.uy C 0 f r Mr. Charles R. Jeter Regional Administrator EPA, Region IV 345 Courtland St .• NE Atlanta, GA 30365 . Attn: James H. Scarbrough Re: N.C. Superfund Project -PCB landfill Dear Mr. Jeter: The installation of four replacen~nt groundwater monitoring wells as requested by my letter of July 2, 1982 is currently being completed. On the morning of August 6 the well driller discovered the open hole that extended into the groundwater and was to replace monitoring well #2 had been vandalized. The vandalism consisted of the placement of dried cement, creosote treated lumber, and other foreign matter into the open hole and the saturated zone. Efforts to retrieve these materials were unsuccessful and the well driller relocated in close proximity to the original well as required in condition #1 of the July 2 request. On August 10 Tom Karnoski of the Solid and Hazardous Waste Management Branch, North Carolina Department of Human Resources con- tacted Don Hunter of your staff to determine if this vandalized hole could affect the sampling integrity of monitoring well #2. It was Mr. Hunter's opinion that the backfilling of the hole with cement to the ground surface would minimize any impact on the replacement well. This remedial action would also satisfy North Carolina Regulations concerning abandonment of wells. Instructions have been given to the well driller to close the hole. Mr. Jeter Page 2 August 17, 1982 We would appreciate a written reply to this situation so that the integrity of the PCB landfill future groundwater monitoring pro- gram will not be in question. If further information is needed, please let me know . WWPjr:jj cc: Bill Raney 0. W. Strickland Tom Karnoski v Frank Rainey Perry Nelson Jack Reavis . ' , PCB LANDFILL MONITORING CODE RC -Richneck Creek UT -Unnamed Tributary DS -Downstream US -Upstream SW-CON -Spring Discharge 30 feet above UT SW-HEAD -Spring Discharge 500 feet Wl -Groundwater Monitoring Well W2 -Groundwater Monitoring W3 -Groundwater Monitoring W4 -Groundwater Monitoring A -Replicate A B -Replicate B Well Well Well 11 112 /13 114 above UT _ ~ . }II ,,. -, Su ,ef,4, E _,,.1,,e S/9'1 P'-G .S .Sfon,,;7:, 9 e c.. us 19 Re tiS a fl c b.S A flC ll! It ? lJ• u.s 19 ~ u-,-os B u, OJ~ (J TtJSjl 6 Lt/ ·WI 19- W IIS Lve'4 u28 '-" .l A 'v l B "" 't~ w l({l • l~Olt J=,,1Ct/ (. t ~c.J\O ..../A~/"" ~E~'--,fCc: lOCKj ~~T l:6~I 11ft~ .4 IIDtJJ /'tJo;-o 6~~~rl~ i .. JAMES 8. HUNT, JR. GOVERNOR THOMAS W. BRADSHAW, JR. SECRETARY STATE OF NORTH CAROLINA DEPARTMENT OF TRANSPORTATION RALEIGH 27611 September 20, 1978 DIVISION OF HIGHWAY~ MEM:>RANDUM TO: Mr. M.C. Adam:5 1 Maintenance Unit Head W .D. Bingham, Head o! Geotechnical Unit SUBJECT: Investigation for Disposal Site !or PCB (W.O. 4-5401101) · Attached are boring logs and sketch of a site we have investigated tor PCB disposal in Warren Cotmty. The sito was drilled and :sampled to a depth ranging from 28 f'eet to 41 feet. Twenty (20) samples were delivered to -the Department or Transportation Labqratory-to be te:sted tor: Minus 200 material, Plastic Index, Liquid Limit and pH values. I! we can be of further help in this matter please let us know. WDB:nah Attachments , . . \ PROJECT . 4.540llOl ll. C •. DEPAR'ft4ENT QF TRANSPORTATION · Division of Hi~h1-1a:13 PCB .PIT BORING I.CG COUNTY Warren ___________ DATE 9-18-78 ROUTE _________ RES •. ENGINEER __________ PIT NO. _P.._C"""'B .... 11--.4._ __ _ ~UIP. USED _2_3_7....()(YJ __ 1 ___ 6_•_• _A_uge_r ___ INVESTIGATED BY _ ..... J-1LalSu.,-'Br=-i .... tt ___________ _ w/rock teeth • i&i DEP'llfS. e!f!i REMARKS: i.e. groundwater data H i:Q FP.e '1-, i:Q ·DESCRIPTION OF MATERIAL §~ F~ TO ~~ moisture content; etc. 1 o.o 11.0 1-A Red-Brown Mica. -F~andy clay Dry 1 11.0 ,o.o 1-B Brown Mica. Clayey silt Moist@ 20.0' 1 10.0 tn.S 1-C Brown Mica:. Silty sand ·1 1.n. s li.1.2 Soft. weathered rocL Practical auger retwsal @ 41 .2' .. Groundwat~r; .. 0 Hr.-Dry caved in @ 28. 51 ·. ... ~ hours-caved in O 28 .5 ,: .. - 2 o.o 8.0 ·2-1 Red-brown mica. tine sandy clay 2 8.0 38.0 2-B Brown highly ad.ca. sandy clay silt Wet @ 30' Groundwater: 0-Hr. -Orv caved in@ 35.0 . 24 Hr.-34.2 3 o.o 3.0 3-A Red-brown mica. -F-sandy clay Dry 3 3.0 28.0 t3-B Brown· mica. sandy clayey silt Moist @ 19.0 Groundwater: 0 Hr. -Drv caved in @ 23. 5' 2L. Hr:3.-22.9' 4 o.o 10.0 4,-A Red-brown mica. -F-sandy cl~y · Drv 4 ~o.o 33.0 4,-B Brown mica. clayey sandy silt Wet@ 27.0' ,-Groundwater: O Hr.-Drv . 24 Hr.-Dry - ... -- r \ . :. · Pen· . . NORTH CAROLINA DEPARTMENT OF TRANSPORTAT-~r.;;;r~n.r!,..__ DIVISION 0,. HIGHWAYS MATERIALS Ai TESTS UNIT SOILS LABORATORY Rel. ProJ. ···-···---··--·-·····-·-·--··· ·---DEPARTMENT OF TRAt,SPORT~mm OIVJSION OF HIGHWAYS GEclTECHNIC-;t U~IT BEPORT ON SA)IPLES OF .SoJ.l_ f.Qr __ Qwui_tJ_J,_p.}i_________________ I Project ___________ 4_._.540llal .. _. ___________ Count, -·-----------\ia:crJ:D .. ____________ Owner _____________ _ Date: Sampled •• 9:-18-78 ------·----------------Received ---~---=!~_-:?8 ---·----------Rcport«J -~-2~_:--7~---- Sai:npled from --~~_;_f! __ . _______________________ Br .l~-~~-Br!,!t; ________ _ Submitted b1 ----W !-D :.J!!~!:!-----------~---------------------------·----------19.,E_ Standard Specillcatlona 396732-396751 TEST RESULTS J)..;} · ?3' _J• Proj. Sample ND-lA 1B Lab. S11U1ple No. 396732 396733 Retained :.a S !eve ,~ - - Paisini: :10 Sieve ,. 100 100 Pusin,r :40 Sieve ,.. 99 99 Passina :200 Sievo "· 74 54 tl c.,.,.. S-d-Z.O '- 1 e.:1 ,..,.. R..._ :ao ,.. 4 9' J j )"la. Saad-0.U lo ,. 24 42 .. ,.u ..... Ret. nto 'i • .. C Sil&--0.06 22 33 ~ . -.,. a: ,.. "" t.oo, ...... ~ -!£ Clai,-t-. 50 16 -l .:a ,. I th~• 0.001 .,. ... .I r...in. • -a ~ s1 .... CJ. - Pk•in,r CJ. --::OQII.,.• LL 64 48 P. I. 34 NP . AASHO ·Classification A-7-5(20 A-5(5) Tenure Station Hole No. 1 1 Depth (ft.) 0 1.1 . to 11 30 ph 6.26 6.36 cc: • •1• M. c. Adams Air. W. D. Bingham Soil:s File '. le 2A 2D 3A 38 4A ' 396734 396735 396736 396737 396i38 396739 -l 1 --- 100 98 98 100 100 100 99 96 95 99 98 98 . 48 74 63 78 70 77 7 7 11 3 . 7 4 53 21 30 22 29 24 24 24 33 29 42 24 16 48 26 46 22 48 . - ----' - --- --I- 36 64 47 58 I SJ 58 9 36. 19 24 14 29 ~-7-6(20) 1 A-7-6(1( ' :)A-7-6(19 A-4(3) )A-7-5(lq)A-7-5(1J . 1 2 2 3 3 4 30 0 8' 0 3 0 40.5 8 38 1 3 28 1 10 6.75 6.53 6.35 6.4-3 6.29 5.98 . ) . ----·-·••·--·• .. Rel. • • I • NORTH CAROLINA DEPARTMENT OF TRANSPORTATION 01Vl510N Of" HIGHWAYS MATERIALS a. T~STS UNIT 501L5 LABORATORY ProJ. -------------------------------- REPORl' ON SAMPLES OF ___ s~u __ f9_i:_~~J.Att_§'_..2ti_ ______________ _ r ,,; . M • T For• ,o:a ll•l•U Project ----------Au~l0llOl. ______________ Count)o ---------------------------------Owner ______ _ Date: Sampled ---------------------------------Rcc1lved -------------------------Reported ________ _ Sampled from ___ fCiL .. Pi.t..l:l _______________________ a, ----------------------- Submitted bJ -------~-----------------------------~------------------19 ______ Standard Sp.cification~ 396 732-396 7 51 TEST RESULTS -~;) -~ cl Proi. Sample No. 4B SA 5B SC 6A 6B 6C 7A . ' Lab. Sample No. 396740 396741 396742 396743 396744 396745 396746 396747 l(etained :~ Sieve ,~ -12 -1 1 2 -- . Paasinr t:10 Sieve ,. 99 84 99 96 90 97 100 100 Puainir :,o-Si..,e 'Ji, 97 80 96 93 86 92 97 99 62 . I 81 Paainsr ~00 SI,.,.. 'Ji, 64 64 48 65 59 so 1,,t c-... SaaJ-t.o 1e I 0.21 .... K9'. :ao .,_ 7 9 9 7 8 10· 11 2 J j Fl11• S• ... -.!S LO "' 36 20 33 51 23 35 41 14 'C :; O.lo6 """· Ret. :Tl ~-• i Sil&-0.0$ 3.'i . ;:: ;a I• ta 1.oos """· 'Ji, 31 38 28 21 35 24 30 ~ -.!E .. l .a ci.,-i-. ,. 2,; ":l" 2f\ H. .d.A 20 18 54 u, ... t .011$ ..... j r .... , •• • a :JO 111-'Ji, -------- r ... , ... ~ ,_ cw, ... _ --- ---- L. L. 41 62 45 28 64 43 34 67 P. J. 9 27 . 14 4 . 29 s 6 31 AASHO A-5(6) 4_7_c;(l4 A-7-5(8) A-4(3) A-7-S(U ,)A-5( S) !\-4(3) ~-7-5(20) Classific11tion •· , Texture StaUon I Hole No. 4 a; s 5 6 6 6 7 De1>th (ft.) ln n n -_a; 'l c; 0 7 12 1A . 't 't h a:1 ? c;I 331 7 121 33 + .... ph 5.89 6.05 5.91 6.31 5.73 5.78 5.89 S.72 . cc: " N. c: DEPAR'IMENT QF TRANSPORTATION · Division of Highways PCB PIT BORnn LOO G-5 1-78 PROJECT __ 4_.5_40_1l_O_l_· _____ comrrr · _ w_ar_re_n _______ DATE 9-18-78 ROUTE _________ RES •. ENGINEEa PIT NO. __ PC_B_t1_4 ___ _ ~UIP • USED __ ...,2:3.,..7~.ooo ....... ~l ------6-"_A_uge_r __ INVESTIGA'I'ED BY __ J_._s_._Bri_·_t_t ________ _ W /rock teeth .. ~f;i i~~s. ~&; · . · · DESCRIPTION OF MATERIAL RDURKS: i.e. groundwater data Hill 11. Ill ~~ ~; ~oistu;re content; etc. FRCM TO . 5 0.0 6. 5 . 5-A Red-brown mica. -F-· 5andy clay Dry W /auartz lenses 'i 6. 5 25.0 'i-B Brown mica. 5andy 5ilt ·• Moist @ 25.0' 'i 25.0 11.0 'i-C Tan nd.ca. silty -F-5aod Wet@ 29.0' . Groundwater: .. ~Hr • -Dry-caved in @ J0.0' 24 Hrs.-Dry-caved in@ JO.O ..I 0.0 7.0 6-A Red~brown mica -F-sandy clay W / Dry quartz lenses •. . 6 7~0 l~.O 6-B Brown mica. sandy silt Drv 6 12.0 33.0 6-c Tan mica. silty -F-sand WPt@ 26_()1 .. · 'Groundwater: O Hr~ -Drv caved in @ 29.io . 2L. Hr. -drv caved in @ 29. □ 7 o.o 10.0 7-A Red-brown mica.· -F-sandy clay Drv 7 10.0 20.0 7-B Brown.;.tan -F-sandy clay Moist@ 20.01 7 20.0 33.0 7-C &own -F-aandy silt Wet @ 25~0' Grnundwater: o ·Hr.-dry caved in@ ·20. 7 1 21 Hrs.~ t-;::ived in @ 26.7• . 8 o.o 9.0 8-A Red-brown mica-i'ine sandy clay Dry 8 9.0 38.0 8-B &own nd.ca. :sandy silt Moist@ 26.o• r · -1.1 ... +. @ ':I('\ • 0' Groundwater: 0 Hr. --drv caved in @ 33 .2' 21... Hrs. drv caved in @ 33 • · -F--f"in.,. --.. ' ' I• r .... ~ o. ---r----.-'--_,,.;..----------=-=""',-------,~._.,,-,-------- · ~·-;~-)::_.,·.,.: 0:: V) ., ;· \· • 6 : :· •• ;· .. • . · .... •""! ••• - SCALE 1• Jlef. .. -. . . NORTH CAROLINA DEPARTMENT OF TRANSPORTATION DIVISION OY HIGHWAYS MATi:RIALS Oi TESTS UNIT SOILS UBOR'°'TORY ProJ. ············--·---------------··-· iMiW &f?ii&i%7 M 6 T t'or"' 11-1-11 Project ________ 4 • .540l.1Ql _______________ County-------------------------------------Owner ___________ _ Date: Sampled --------------------------------Recci•.d ----:-------··---------------Report.cl ______ _ Sampled from ••• 1.~!\ __ !1_~_f.:l, _______________________ B1 ---------------------------------- SYbmiu.d bF --------------------------------------------------------- 19 ____ Stand.ard Specifiealion, 396732-396751 TEST RESULTS ~,:) · t :;; Prof. ~mole No. Lab. Siunple No. Ket.ained :, Sieve PaNinir :10 Sieve Paaalnw :.ao Sieve Pasafnir :200 Sina ·t c-... l&nci-1.0 le I 0.21 .... Ret. :&O J j t1n• s.11,-4.JS to ~ I .Ila m111. Rot. i:ne 1 • .. i Sll_..o, · ... .a lo lo '·°"' ...... ~ ... --u Clair-t...• .. ~P' ..... t .001 .... !I .! raaain• :a :ae s,..,, • ,,. .... , ... ,. ::1111:11- LL P. (. AASHO Cluslfiaition Texture Sution Hole No. Deotb (ft.) -1-n nh cc: ,-- f .. .. ~ ··' :., ;,- ·.• ........ --.,-. -------- ,;. ,. ,. " ~ ,,. ., . ,:. • 7D 7C SA 8B . 396748 396749 3967SO 396751 . ---- 99 99 100 100 97 97 99 97 67 55 80 -58 4 7 3 8 . 38 . 45 20 43 38 30 23 31 20 18 54 18 -------- 38 39 66 45" 8 8 23 4 . A-4(6) A-4(4) A-7-S(17) A-5(5) I I 7 7 8 8 10 20 0 9 20f 331 gr 39, I i; 77 6.0] .-;_ F-1' 5.90 ,,.... Unitt:cl Stutes l)q,:irt111u1t u( the lnt:crior _tlr. Jerry C. P.:lrkins, Head (;Ft,llO,,l('\I 'd l~\l.'i' \I~ O. l:o~ 211~/ l'wllcJ.~h, t:c Vu02 Solid llasce nnd V~ct:or Control llranch IHvision of llealch Scrvlcc:;1 t:. c. D~rilrtmcmc of Uuman RenoUL'C('.~ P.O. Dox 27687 Ralcich, No:th Carolina 27611 Dear Mr. Perkin~: lhc rroj'o:rn<l l'C_iS Ji:.;110:;,d :d.tc loc<1tl:ll in 1:.,c·•·a C,,l1nl:)' ;,t 1;:! j l.l1dc J6.20'1J", lon&itud~ 1a•o9•5a", .iti al.iovc the lJll-:,,1..:ar Uciocl )c:vd. . . • The sttc i:; located on a hi.lllllop li.!L11c:cn ltici,,,,!c'.-: Cr<:1.:I: ;,nJ c111e: <1( .l:..s lributaric:,. ,1 c:itlm::.Lc, IJ;:i!:~·d <lit (load 1,:cucd!i ,·oll,:c:t:c,l at: ~c•rlh C,H·olin.1 r.tcc.?ms, th.it tho l00-}·1•ar floud h::;li>lat i:. not 1r.on: l'hc1n 8 !a<!t. aunvc avcratc u.1ter level in thcr.c cre,,t-u. Th:! proposC:!<l t..itc: ir. .i11pro;,imatcly 80 !ect ai:>ovc Lhc:;c: creel;:. .ind not :;ubjcct: to (.loc1dinr., Sincerely yuu.::., .../:.-N. ll. J,1ck:.un, Jr. / llydroloc:;bt -.------.. ' . .,, --~ . . . . . . ... -· 0 . ' C:, 9 ~ ~/ 0 '1§°-:J. 0 \ :t l.. ? r~ 1• .s, \ ~ tr\ ±, ~ '!A • 0 J f tf\ /I ~ / -\ z. /f ~ / i / ~ ./ ~' // 1 // 1// 1./' \ } )01 0 (E.L"" lU .03) t~ z_ ·3 CJ 0 lt-L" 1,u,4;') :L E -n ■ (u-~ l'Ll. ~-~ I F o (a""-11.1 .so'i \ I vs) 0 (a=-1-Zi.SS) :l ' ftg V' O (a= 4(..) r?Je~ f f,t ' i: ':t ..,_;;/ ' -J._' ---..,,,.. --~---·+-..... __, --- 1-,~~f I ~,,,~,,, c. ~ l 1-n~p ,.,.,. 4';,fe# 9-.,